Interplay of late Cenozoic siliciclastic supply and carbonate response on the southeast Florida platform

USGS Publications Warehouse

Cunningham, K.J.; Locker, S.D.; Hine, A.C.; Bukry, D.; Barron, J.A.; Guertin, L.A.

2003-01-01

High-resolution seismic-reflection data collected along the length of the Caloosahatchee River in southwestern Florida have been correlated to nannofossil biostratigraphy and strontium-isotope chemostratigraphy at six continuously cored boreholes. These data are interpreted to show a major Late Miocene(?) to Early Pliocene fluvial-deltaic depositional system that prograded southward across the carbonate Florida Platform, interrupting nearly continuous carbonate deposition since early in the Cretaceous. Connection of the platform top to a continental source of siliciclastics and significant paleotopography combined to focus accumulation of an immense supply of siliciclastics on the southeastern part of the Florida Platform. The remarkably thick (> 100 m), sand-rich depositional system, which is characterized by clinoformal progradation, filled in deep accommodation, while antecedent paleotopography directed deltaic progradation southward within the middle of the present-day Florida Peninsula. The deltaic depositional system may have prograded about 200 km southward to the middle and upper Florida Keys, where Late Miocene to Pliocene siliciclastic form the foundation of the Quaternary carbonate shelf and shelf margin of the Florida Keys. These far-traveled siliciclastic deposits filled accommodation on the southeastern part of the Florida Platform so that paleobathymetry was sufficiently shallow to allow Quaternary recovery of carbonate sedimentation in the area of southern peninsular Florida and the Florida Keys.

Early diagenetic dolomitization and dedolomitization of Late Jurassic and earliest Cretaceous platform carbonates: A case study from the Jura Mountains (NW Switzerland, E France)

NASA Astrophysics Data System (ADS)

Rameil, Niels

2008-12-01

Early diagenetic dolomitization is a common feature in cyclic shallow-water carbonates throughout the geologic record. After their generation, dolomites may be subject to dedolomitization (re-calcification of dolomites), e.g. by contact with meteoric water during emersion. These patterns of dolomitization and subsequent dedolomitization frequently play a key role in unravelling the development and history of a carbonate platform. On the basis of excellent outcrops, detailed logging and sampling and integrating sedimentological work, high-resolution sequence stratigraphic interpretations, and isotope analyses (O, C), conceptual models on early diagenetic dolomitization and dedolomitization and their underlying mechanisms were developed for the Upper Jurassic / Lower Cretaceous Jura platform in north-western Switzerland and eastern France. Three different types of early diagenetic dolomites and two types of dedolomites were observed. Each is defined by a distinct petrographic/isotopic signature and a distinct spatial distribution pattern. Different types of dolomites are interpreted to have been formed by different mechanisms, such as shallow seepage reflux, evaporation on tidal flats, and microbially mediated selective dolomitization of burrows. Depending on the type of dolomite, sea water with normal marine to slightly enhanced salinities is proposed as dolomitizing fluid. Based on the data obtained, the main volume of dolomite was precipitated by a reflux mechanism that was switched on and off by high-frequency sea-level changes. It appears, however, that more than one dolomitization mechanism was active (pene)contemporaneously or several processes alternated in time. During early diagenesis, percolating meteoric waters obviously played an important role in the dedolomitization of carbonate rocks that underlie exposure surfaces. Cyclostratigraphic interpretation of the sedimentary succession allows for estimates on the timing of early diagenetic (de

C-isotope stratigraphy and paleoenvironmental changes across OAE2 (mid-Cretaceous) from shallow-water platform carbonates of southern Mexico

NASA Astrophysics Data System (ADS)

Elrick, Maya; Molina-Garza, Roberto; Duncan, Robert; Snow, Laura

2009-01-01

The stratigraphic and geochemical record of the mid-Cretaceous (Cenomanian-Turonian) Oceanic Anoxic Event 2 (OAE2) has been studied in numerous Tethyan and proto-Atlantic hemi-pelagic/pelagic successions, but little data comes from nearshore carbonate successions from the proto-Pacific region. Here we present the results of a combined stratigraphic and δ13C study of C-T platform carbonates from southern Mexico, which were deposited within the proto-Pacific. Two scales of sedimentary cyclicity are recognized. High-frequency peritidal and subtidal cycles (0.4-8 m) display little evidence of cycle-capping subaerial exposure and are not correlative between sections; these relationships suggest that the amplitudes of high-frequency sea-level changes were minimal during the peak mid-Cretaceous greenhouse. Longer-term transgressive-regressive sequences (18-40 + m) are correlated between sections, and using δ13C trends, can be correlated with sequences developed in northern Europe and India. The Mexican successions were sampled at a high resolution (~ 10 ky) for stable isotopes (inorganic, organic carbon and oxygen), total organic carbon, insoluble residues, and trace metals. The δ13C carb curve matches global trends (including 6 distinct isotopic stages) permitting identification of OAE2 despite the lack of characteristic anoxic facies. Using the δ13C carb trends, we tie the previously identified ammonite, planktonic foram, and nannofossil biostratigraphy from England and the Western Interior seaway of Colorado into the Mexican sections. The initiation of OAE2, defined by an abrupt positive 3-4‰ δ13C shift, coincides with a long-term sea-level rise, though the sedimentary expression of the deepening is no greater than that observed for any of the other sea-level events across the studied interval. OAE2 termination (transition from gradually decreasing to background δ13C values) is not associated with a particular sea-level trend. Stratigraphic changes in insoluble

Shelf architectures of an isolated Late Cretaceous carbonate platform margin, Galala Mountains (Eastern Desert, Egypt)

NASA Astrophysics Data System (ADS)

Scheibner, C.; Marzouk, A. M.; Kuss, J.

2001-12-01

An asymmetrical carbonate platform margin to basin transect has been investigated in the Upper Campanian-Maastrichtian succession of the Galala Mountains, northern Egypt. Identification of systems tracts and their lateral correlation was possible in slope sections only, whereas the monotonous chalk-marl alternations of the basinal sections could not be subdivided with respect to sequence stratigraphic terminology. The platform asymmetry is expressed by varying large-scale depositional architectures exhibiting a rimmed platform with a sigmoidal slope curvature in south-easterly dip-sections and a ramp with a linear slope curvature in south-westerly dip-sections. The rimmed platform is subdivided into a gentle upper slope and a steep lower slope. The platform formed as a result of the initial topography that was controlled by the tectonic uplift of the Northern Galala/Wadi Araba Syrian Arc structure. The calculated angles of the steep lower slope of the rimmed part range from 5 to 8°, whereas the ramp part has an angle of less than 0.1°.

Carbonate sedimentation in an extensional active margin: Cretaceous history of the Haymana region, Pontides

NASA Astrophysics Data System (ADS)

Okay, Aral I.; Altiner, Demir

2016-10-01

The Haymana region in Central Anatolia is located in the southern part of the Pontides close to the İzmir-Ankara suture. During the Cretaceous, the region formed part of the south-facing active margin of the Eurasia. The area preserves a nearly complete record of the Cretaceous system. Shallow marine carbonates of earliest Cretaceous age are overlain by a 700-m-thick Cretaceous sequence, dominated by deep marine limestones. Three unconformity-bounded pelagic carbonate sequences of Berriasian, Albian-Cenomanian and Turonian-Santonian ages are recognized: Each depositional sequence is preceded by a period of tilting and submarine erosion during the Berriasian, early Albian and late Cenomanian, which corresponds to phases of local extension in the active continental margin. Carbonate breccias mark the base of the sequences and each carbonate sequence steps down on older units. The deep marine carbonate deposition ended in the late Santonian followed by tilting, erosion and folding during the Campanian. Deposition of thick siliciclastic turbidites started in the late Campanian and continued into the Tertiary. Unlike most forearc basins, the Haymana region was a site of deep marine carbonate deposition until the Campanian. This was because the Pontide arc was extensional and the volcanic detritus was trapped in the intra-arc basins and did not reach the forearc or the trench. The extensional nature of the arc is also shown by the opening of the Black Sea as a backarc basin in the Turonian-Santonian. The carbonate sedimentation in an active margin is characterized by synsedimentary vertical displacements, which results in submarine erosion, carbonate breccias and in the lateral discontinuity of the sequences, and differs from blanket like carbonate deposition in the passive margins.

Relative sea level changes during the Cretaceous in Israel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Flexer, A.; Rosenfeld, A.; Lipson-Benitah, S.

1986-11-01

Detailed lithologic, microfaunal, and biometric investigations, using relative abundances, diversity indexes, and duration charts of ostracods and foraminifera, allowed the recognition of sea level changes during the Cretaceous of Israel. Three major transgressive-regressive sedimentation cycles occur on the northwest margins of the Arabian craton. These cycles are the Neocomian-Aptian, which is mostly terrigenous sediments; the Albian-Turonian, which is basin marls and platform carbonates; and the Senonian, which is uniform marly chalks. The cycles are separated by two major regional unconformities, the Aptian-Albian and Turonian-Coniacian boundaries. The sedimentary cycles are related to regional tectonic and volcanic events and eustatic changes. Themore » paleodepth curve illustrates the gradual sea level rise, reaching its maximum during the Late Cretaceous, with conspicuous advances during the late Aptian, late Albian-Cenomanian, early Turonian, early Santonian, and early Campanian. Major lowstands occur at the Aptian-Albian, Cenomanian-Turonian, Turonian-Coniacian, and Campanian-Maastrichtian boundaries. This model for Israel agrees well with other regional and global sea level fluctuations. Four anoxic events (black shales) accompanying transgressions correspond to the Cretaceous oceanic record. They hypothesize the presence of mature oil shales in the present-day eastern Mediterranean basin close to allochthonous reef blocks detached from the Cretaceous platform. 11 figures.« less

Growth and demise of a Paleogene isolated carbonate platform of the Offshore Indus Basin, Pakistan: effects of regional and local controlling factors

NASA Astrophysics Data System (ADS)

Shahzad, Khurram; Betzler, Christian; Ahmed, Nadeem; Qayyum, Farrukh; Spezzaferri, Silvia; Qadir, Anwar

2018-03-01

Based on high-resolution seismic and well datasets, this paper examines the evolution and drowning history of a Paleocene-Eocene carbonate platform in the Offshore Indus Basin of Pakistan. This study uses the internal seismic architecture, well log data as well as the microfauna to reconstruct factors that governed the carbonate platform growth and demise. Carbonates dominated by larger benthic foraminifera assemblages permit constraining the ages of the major evolutionary steps and show that the depositional environment was tropical within oligotrophic conditions. With the aid of seismic stratigraphy, the carbonate platform edifice is resolved into seven seismic units which in turn are grouped into three packages that reflect its evolution from platform initiation, aggradation with escarpment formation and platform drowning. The carbonate factory initiated as mounds and patches on a Cretaceous-Paleocene volcanic complex. Further, the growth history of the platform includes distinct phases of intraplatform progradation, aggradation, backstepping and partial drownings. The youngest succession as late-stage buildup records a shift from benthic to pelagic deposition and marks the final drowning in the Early Eocene. The depositional trend of the platform, controlled by the continuing thermal subsidence associated with the cooling of volcanic margin lithosphere, was the major contributor of the accommodation space which supported the vertical accumulation of shallow water carbonate succession. Other factors such as eustatic changes and changes in the carbonate producers as a response to the Paleogene climatic perturbations played secondary roles in the development and drowning of these buildups.

The origin and evolution of saline formation water, Lower Cretaceous carbonates, south-central Texas, U.S.A.

NASA Astrophysics Data System (ADS)

Land, Lynton S.; Prezbindowski, Dennis R.

1981-12-01

Systematic chemical variation exists in formation water collected from a dip section through Lower Cretaceous rocks of south-central Texas. Chemical variation can be explained by an interactive water-rock diagenetic model. The cyclic Lower Cretaceous shelf carbonates of the Edwards Group dip into the Gulf of Mexico Coast "geosyncline", and can be considered, to a first approximation, as part of a complex aquifer contained by Paleozoic basement beneath, and by relatively impermeable Upper Cretaceous clay and chalk above. The hydrodynamic character of this carbonate system is strongly controlled by major fault systems. Major fault systems serve as pathways for vertical movement of basinal brines into the Lower Cretaceous section. Formation water movement in this sytem has strong upfault and updip components. The "parent" Na/1bCa/1bCl brine originates deep in the Gulf of Mexico basin, at temperatures between 200 and 250°C, by the reaction: halite + detrital plagioclase + quartz + water → albite + brine Other dissolved components originate by reaction of the fluid with the sedimentary phases, K-feldspar, calcite, dolomite, anhydrite, celestite, barite and fluorite. Significant quantities of Pb, Zn and Fe have been mobilized as well. As the brine moves updip out of the overpressured deep Gulf of Mexico basin, and encounters limestones of the Stuart City Reef Trend (the buried platform margin), small amounts of galena precipitate in late fractures. Continuing to rise upfault and updip, the brine becomes progressively diluted. On encountering significant quantities of dolomite in the backreef facies, the Ca-rich brine causes dedolomitization. Although thermochemical consideration suggests that small amounts of several authigenic phases should precipitate, most have yet to be found. Minor amounts of several kinds of calcite spar are present, however. As the brine evolves by dilution and by cooling, no systematic changes in any cation/Cl ratio occur, except for regular

Chemical Remagnetization of Jurassic Carbonates and a Primary Paleolatitude of Lower Cretaceous Volcaniclastic Rocks of the Tibetan Himalaya

NASA Astrophysics Data System (ADS)

Huang, W.; Van Hinsbergen, D. J. J.; Dekkers, M. J.; Garzanti, E.; Dupont Nivet, G.; Lippert, P. C.; Li, X.; Maffione, M.; Langereis, C. G.; Hu, X.; Guo, Z.; Kapp, P. A.

2014-12-01

Paleolatitudes for the Tibetan Himalaya Zone based on paleomagnetic inclinations provide kinematic constraints of the passive northern Indian margin and the extent of 'Greater India' before the India-Asia collision. Here, we present a paleomagnetic investigation of the Jurassic (carbonates) to Lower Cretaceous (volcaniclastic rocks) Wölong section of the Tibetan Himalaya in the Everest region. The carbonates yield positive fold tests, suggesting that the remanent magnetizations have a pre-folding origin. However, detailed paleomagnetic analyses, rock magnetic tests, end-member modeling of acquisition curves of isothermal remanent magnetization, and petrographic studies reveal that the magnetic carrier of the Jurassic carbonates is authigenic magnetite, whereas the dominant magnetic carrier of the Lower Cretaceous volcaniclastic rocks is detrital magnetite. We conclude that the Jurassic carbonates were remagnetized, whereas the Lower Cretaceous volcaniclastics retain a primary remanence. We hypothesize that remagnetization of the Jurassic carbonates was probably caused by the oxidation of early diagenetic pyrite to magnetite within the time interval at ~86-84 Ma during the latest Cretaceous Normal Superchron and earliest deposition of Cretaceous oceanic red beds in the Tibetan Himalaya. The remagnetization of the limestones prevents determining the size of 'Greater India' during Jurassic time. Instead, a paleolatitude of the Tibetan Himalaya of 23.8±2.1° S at ~86-84 Ma is suggested. This value is lower than the expected paleolatitude of India from apparent polar wander path (APWP). The volcaniclastic rocks with the primary remanence, however, yielded a Lower Cretaceous paleolatitude of Tibetan Himalaya of 55.5±3° S, fitting well with the APWP of India.

Cretaceous shales from the western interior of North America: sulfur/carbon ratios and sulfur-isotope composition.

USGS Publications Warehouse

Gautier, D.L.

1986-01-01

Sulphur/carbon ratios in cores of selected Cretaceous marine shales average 0.67, a value greater than that observed in recent marine sediments and much higher than global values calculated for the Cretaceous. This may be ascribed to generally low levels of bioturbation and enhanced efficiency of sulphate reduction due to low oxygen levels in Cretaceous seaways. Isotopic compositions of pyrite sulphur vary systematically with level of oxygenation of the depositional environment and therefore with organic carbon abundance and type of organic matter. Samples with >4% organic carbon are extremely depleted in 34S (mean delta 34S -31per mille) and contain hydrogen-rich organic matter. Samples containing <1.5% organic carbon display relatively 'heavy' but wide-ranging delta 34S values (-34.6 to +16.8per mille) and contain hydrogen-poor organic matter. Samples with intermediate amounts of organic carbon have average delta 34S of -25.9per mille and contain both types of organic matter. Relations between the nature of these shales, and their sedimentation rate and depositional environment are discussed.-L.C.H.

Mid-Cretaceous carbon cycle perturbations and Oceanic Anoxic Events recorded in southern Tibet

NASA Astrophysics Data System (ADS)

Zhang, Xiaolin; Chen, Kefan; Hu, Dongping; Sha, Jingeng

2016-12-01

The organic carbon isotope (δ13Corg) curve for ~1.7-km-thick mid-Cretaceous strata of the Chaqiela section in Gamba area, southern Tibet is presented in this study. C-isotopic chemostratigraphic correlation combined with biostratigraphic constraints show that the Chaqiela section spans early Aptian through early Campanian period, and that almost all of the carbon cycle perturbations and Oceanic Anoxic Events during the mid-Cretaceous period are well recorded in the continental margin area of the southeastern Tethys Ocean. Significantly, two levels of methane-derived authigenic carbonates were identified at the onset of OAE1b near the Aptian-Albian boundary. We suggest that an increase in methane release from gas hydrates, potentially driven by sea-level fall and bottom water temperature increase, may have contributed to the large negative δ13Corg excursions and global warming during OAE1b.

Stratigraphic and structural relationships between Meso-Cenozoic Lagonegro basin and coeval carbonate platforms in southern Apennines, Italy

NASA Astrophysics Data System (ADS)

Pescatore, Tullio; Renda, Pietro; Schiattarella, Marcello; Tramutoli, Mariano

1999-12-01

Stratigraphic studies and facies analysis integrated with a new geological and structural survey of the Meso-Cenozoic units outcropping in the Campania-Lucania Apennines, southern Italy, allowed us to restore the palaeogeographic pattern and the tectonic evolution of the chain during Oligo-Miocene times. The southern Apennines are a N150°-striking and NE-verging fold-and-thrust belt mainly derived from the deformation of the African-Apulian passive margin. Four wide belts with different features have been recognized in the chain area. From east to west the following units outcrop: (a) successions characterized by basinal to marginal facies, ranging in age from Cretaceous to Miocene, tectonically lying on Plio-Pleistocene foredeep deposits; (b) successions characterized by shallow-water, basinal and shelf-margin facies, ranging in age from middle Triassic to Miocene ('Lagonegro units'), overthrust on the previous ones; (c) Triassic to Miocene carbonate platform successions ('Apenninic platform units'), overthrust on the Lagonegro units; (d) Jurassic-Cretaceous to Miocene deep-water successions (ophiolite-bearing or 'internal' units and associated siliciclastic wedges), outcropping along the Tyrrhenian belt and the Calabria-Lucania boundary, overthrust on the Apenninic platform units. All these units tectonically lie on the buried Apulian platform which is covered, at least in the eastern sector of the chain, by Pliocene to Pleistocene foredeep deposits. Stratigraphic patterns of the Cretaceous to lower Miocene Lagonegro successions are coherent with the platform margin ones. Calcareous clastics of the Lagonegro basin are in fact supplied by an adjacent western platform, as inferred by several sedimentological evidences (slump and palaeocurrent directions and decreasing grain size towards the depocentre of the basin). Tectonic relationships among the different units of the chain — with particular emphasis on the Lagonegro and Apenninic platform units of the

Preliminary results in larger benthic foraminifera assemblage in a mixed siliciclastic-carbonate platform from the Upper Cretaceous of the External Prebetic Domain (Valencia province, SE Spain)

NASA Astrophysics Data System (ADS)

Robles-Salcedo, Raquel; Vicedo, Vicent

2016-04-01

In the External Prebetic Domain (Betic Mountain Range, Valencia province, SE Spain) it is difficult to find good outcrops to study larger benthic foraminifera (LBF), particularly in the Upper Cretaceous deposits, because of three main reasons. During the Upper Cretaceous, the complex paleogeography in the northern Prebetic Domain developed a complex system of shallow-water platforms. This is directly linked to the complexity in the distribution of the facies observed nowadays, which may change drastically in lateral, closely related outcrops having a special negative impact in the lateral extension of stratigraphical levels containing LBF. The second reason is the nature of the shallow water environments in which the larger foraminifera lived. The local continental influence derived in the establishment of very complex mixed platforms. Thus, there is not a complete register through carbonate rocks, but an alternation of microconglomerates, sandstones, calcarenites and carbonates that can be observed in the stratigraphic series of the Upper Cretaceous. This affects negatively in observing changes in the evolutionary trends of taxa. The third reason difficulting the study of LBF in northern localities of the Prebetic Domain is diagenetic. Dolomitization affects a huge part of the Mesozoic rocks deleting all fossil microfauna in the affected rocks. Such three reasons are behind the difficulty in developing correlations and having a comprehensive understanding of the biostratigraphy and phylogeny of the taxa involved. However, after several field trips developed in the northern Prebetic area, an excellent reference section for the study of the LBF in the Prebetic Domain has been identified in the surroundings of the Pinet village (Valencia province). Here, a relatively continuous section with scarce dolomitization and good conditions of accessibility exists. The larger foraminifera assemblages appering in the Pinet section will be compared with other paleobiogeographic

Middle Cretaceous to Oligocene rise of the Middle American landbridge - documented by south-eastwards younging shallow water carbonates

NASA Astrophysics Data System (ADS)

Baumgartner-Mora, Claudia; Baumgartner, Peter O.; Barat, Flore

2013-04-01

Basements of Southern Central America are oceanic in origin, including the southern half of the classical "Chortis Block" formed by subduction/accretion mélanges named Mesquito Composite Oceanic Terrane (MCOT). The rise of these oceanic basements into the photic zone and eventual emergence was controlled by convergent, collision tectonics, and/or arc development. In this context, shallow carbonate palaeo-environments were short-lived and formed not only on uplifted basements and arcs, but also on (now accreted) volcanic edifices of Pacific oceanic seamounts. From Northern Nicaragua (NW) to Eastern Panama (SE) we observe a systematic younging of the first shallow water carbonate facies encroaching on basements and/or older deep-water formations: In the Siuna area (NE-Nicaragua) Aptian-Albian shallow water limestones dated by rudists and Orbitolina texana rest unconformably on the Jurassic/Early Cretaceous Siuna Serpentinite Mélange, part of the MCOT. In N-Costa Rica, the assembly of several terranes (Santa Elena Ultramafic Unit, Nicoya Complex s. s., Matambu and Manzanillo Terranes) is overlapped by Late Campanian-Maastrichtian shallow water facies dated by rudists and Larger Foraminifera, such as Pseudorbitoides rutteni, Pseudorbitoides israelski, Sulcoperculina sp. and Sulcoperculina globosa. Reworked Campanian-Maastrichtian shallow water material including Larger Foraminifera was found in the Herradura Promontory (central Pacific coast of Costa Rica). It could be derived from an accreted seamount. No shallow carbonates are known so far from the early Palaeocene. The Tempisque Basin (N-Costa Rica) hosts the Barra Honda carbonate Platform (originally >900 km2) dated as late Palaeocene (Thanetian) by planktonic Foraminifera, 87Sr / 86Sr ratios and Ranikothalia spp. Other late Palaeocene shallow carbonates documented in S-Costa Rica/W-Panama (Quepos, Burica) are interpreted as insular carbonate shoals (atolls?) on now accreted seamounts. To the SE of the S

Lower Cretaceous-Upper Jurassic carbonate complex of southern margin of Florida-Bahama platform in northern Cuba

DOE Office of Scientific and Technical Information (OSTI.GOV)

Winston, G.O.

Examination of core samples and cuttings from seven wells in northern Cuba has shown that the southern margin of the Florida-Bahama platform is composed largely of dolomitized carbonate mound and talus material. Dolomitization is possibly due to reflux of the highly saline waters from the South Florida evaporite basin to the north. At least four separate episodes of mound construction are present, accompanied by seaward talus material. South of the dolomitized carbonate complex, three wells penetrated a deeper water continental slope facies consisting principally of light-colored limestone with uncommon beds of shale and radiolarian limestone. Zones of shallower facies appearmore » to be intercalated. Farther to the south beyond the scope of this study, volcanics and serpentine are reported in the literature. The northernmost wells on the island are cut by one or more high-angle thrust faults. Intense crumpling and faulting are present in the deeper water facies between the continental margin complex and the oceanic volcanic-serpentine province. The intense crumpling was probably caused as the deep-water sediments were scraped off by the subduction of an oceanic plate from the south beneath the continental crust of the Florida-Bahama platform. Certain beds in the northern Cuba carbonate complex can be correlated with the standard section in Florida, as exhibited in the Cay Sal well to the north. Three anhydrite beds in the Cayo Coco well appear to correlate with thick anhydrites in the Punto Gorda, Pumpkin Bay, and Bone Island formations. In the Collazo well to the south, a limestone-anhydrite section appears to correlate with the Pumpkin Bay. Three limestone intervals in the Blanquizal well seem to correlate with portions of the Rattlesnake Hammock, Pumpkin Bay, and Bone Island formations in the Cay Sal well.« less

Rudist bivalve shells as palaeoenvironmental archive: assessing ecological boundary conditions of Barremian subtropical carbonate platform ecosystems

NASA Astrophysics Data System (ADS)

Huck, Stefan; Heimhofer, Ulrich

2013-04-01

Mid-Cretaceous shoal-water ecosystems have been proven to show characteristic response modes (microencruster blooms, carbonate platform drowning) to major climatic and environmental changes that finally culminated in so-called oceanic anoxic events (OAEs). During most OAEs, the widespread burial of unusual amounts of organic matter in pelagic basins caused a strong carbon-cycle perturbation, expressed as prominent positive carbon-isotope excursion. Stratigraphically, the Aptian OAE1a is marked by a well-defined carbon-isotope pattern (negative spike and subsequent positive anomaly). Judging from high-resolution chemostratigraphic (C, Sr) studies, the observed neritic response modes are diachronous in nature and certain biotic changes (orbitolinid-rich sediments, Lithocodium blooms, carbonate platform drowning) clearly predate the deposition of OAE1a black-shales. The perturbations observed in the neritic realm underline the previously quoted progressive nature of Late Barremian-Early Aptian environmental change. Considering the observed time lag between the earliest biotic perturbations and widespread oceanic anoxia, a volcanic scenario related to the release of large volumes of CO2 during the formation of the Ontong Java large igneous province seems at least likely. The aim of the current project is to reconstruct the evolution of carbonate platform ecosystems in the northern subtropical realm during the early onset of enhanced (submarine) volcanic activity. A Late Barremian carbonate platform succession (Sausset-les-Pins section), deposited on a proximal part of the Provence platform (Marseille area, SE France), has been investigated applying high-resolution chemostratigraphy and detailed sedimentological analysis. The 60-m thick section is composed of peloidal to bioclastic packstones and grainstones rich in rudist bivalves (Urgonian limestones sensu stricto) and subordinate mudstones and wackestones. In order to obtain information on the palaeoecological and

Iron-sulfur-carbon relationships in organic-carbon-rich sequences I: Cretaceous Western Interior seaway

USGS Publications Warehouse

Dean, W.E.; Arthur, M.A.

1989-01-01

Cretaceous marine strata deposited in shallow to intermediate depths in the Western Interior seaway of North America show considerable variation in organic-carbon enrichment and degree of pyrite formation. The extreme range of paleoceanographic and depositional conditions that occurred in this seaway provide a unique opportunity to examine the effects of iron-, carbon-, and sulfur-limitation on pyrite formation in one region over about 30 my. Ternary diagrams of the system Fe-S-OC, together with some measure of the reactivity of organic matter (pyrolysis hydrogen index), provide a rapid means of recognizing iron-, carbon-, and sulfur-limitation on pyrite formation in a series of samples from a single lithologic unit. Iron limitation is indicated by a concentration of data along a line of constant S/Fe ratio on a Fe-S-OC ternary diagram. Carbon limitation is indicated by a concentration of data along a line of constant S/OC ratio. Sulfur-limitation is suggested by the lack of a systematic Fe-S-OC relationship and residual organic matter that is high in abundance and reactivity. -from Authors

Sedimentary Record of the Back-Arc Basins of South-Central Mexico: an Evolution from Extensional Basin to Carbonate Platform.

NASA Astrophysics Data System (ADS)

Sierra-Rojas, M. I.; Molina-Garza, R. S.; Lawton, T. F.

2015-12-01

The Lower Cretaceous depositional systems of southwestern Oaxaquia, in south-central Mexico, were controlled by tectonic processes related to the instauration of a continental arc and the accretion of the Guerrero arc to mainland Mexico. The Atzompa Formation refers to a succession of conglomerate, sandstone, siltstone, and limestone that crop out in southwestern Mexico with Early Cretaceous fauna and detrital zircon maximum depositional ages. The sedimentary record shows a transition from early fluvial/alluvial to shallow marine depositional environments. The first stage corresponds to juvenile fluvial/alluvial setting followed by a deep lacustrine depositional environment, suggesting the early stages of an extensional basin. The second stage is characterized by anabranched deposits of axial fluvial systems flowing to the NE-SE, showing deposition during a period of rapid subsidence. The third and final stage is made of tidal deposits followed, in turn, by abrupt marine flooding of the basin and development of a Barremian-Aptian carbonate ramp. We interpret the Tentzo basin as a response to crustal extension in a back-arc setting, with high rates of sedimentation in the early stages of the basin (3-4 mm/m.y), slower rates during the development of starved fluvial to tidal systems and carbonate ramps, and at the top of the Atzompa Formation an abrupt deepening of the basin due to flexural subsidence related to terrane docking and attendant thrusting to the west. These events were recorded in the back-arc region of a continental convergent margin (Zicapa arc) where syn-sedimentary magmatism is indicated by Early Cretaceous detrital and volcanic clasts from alluvial fan facies west of the basin. Finally, and as a response to the accretion of the Guerrero superterrane to Oaxaquia during the Aptian, a carbonate platform facing toward the Gulf of Mexico was established in central to eastern Oaxaquia.

Footwall progradation in syn-rift carbonate platform-slope systems (Early Jurassic, Northern Apennines, Italy)

NASA Astrophysics Data System (ADS)

Fabbi, Simone; Santantonio, Massimo

2012-12-01

The so-called Umbria-Marche Domain of Northern Apennines represents a vast depositional system, also stretching across the Adriatic Sea subsurface, that was characterized by dominantly pelagic sedimentation through most of its Jurassic to Oligocene/Early Miocene history. The pelagic succession is underlain by Hettangian shallow-water carbonates (Calcare Massiccio Fm.), constituting a regional carbonate platform that was subjected to tectonic extension due to rifting of the Adria/African Plate in the earliest Jurassic. While tectonic subsidence of the hangingwalls drove the drowning of the platform around the Hettangian/Sinemurian boundary, the production of benthic carbonate on footwall blocks continued parallel to faulting, through a sequence of facies that was abruptly terminated by drowning and development of condensed pelagites in the early Pliensbachian. By then rifting had ceased, so that the Pliensbachian to Early Cretaceous hangingwall deposits represent a post-rift basin-fill succession onlapping the tectonically-generated escarpment margins of the highs. During the early phases of syndepositional faulting, the carbonate factories of footwall blocks were still temporarily able to fill part of the accommodation space produced by the normal faults by prograding into the incipient basins. In this paper we describe for the first time a relatively low-angle (< 10°) clinoform bed package documenting such an ephemeral phase of lateral growth of a carbonate factory. The clinoforms are sigmoidal, and form low-relief (maximum 5-7 m) bodies representing a shallow-water slope that was productive due to development of a Lithocodium-dominated factory. Continued faulting and hangingwall subsidence then decoupled the slope from the platform top, halting the growth of clinoforms and causing the platform margin to switch from accretionary to bypass mode as the pre-rift substrate became exposed along a submarine fault escarpment. The downfaulted clinoform slope was then

Carbonate concretions as a significant component of ancient marine carbon cycles: Insights from paired organic and inorganic carbon isotope analyses of a Cretaceous shale

NASA Astrophysics Data System (ADS)

Loyd, S. J.

2014-12-01

Carbonate concretions often occur within fine-grained, organic-rich sedimentary rocks. This association reflects the common production of diagenetic minerals through biologic cycling of organic matter. Chemical analysis of carbonate concretions provides the rare opportunity to explore ancient shallow diagenetic environments, which are inherently transient due to progressive burial but are an integral component of the marine carbon cycle. The late Cretaceous Holz Shale (~80 Ma) contains abundant calcite concretions that exhibit textural and geochemical characteristics indicative of relatively shallow formation (i.e., near the sediment-water interface). Sampled concretions contain between 5.4 and 9.8 wt.% total inorganic carbon (TIC), or ~45 and 82 wt.% CaCO3, compared to host shale values which average ~1.5 wt.% TIC. Organic carbon isotope compositions (δ13Corg) are relatively constant in host and concretion samples ranging from ­-26.3 to -24.0‰ (VPDB). Carbonate carbon isotope compositions (δ13Ccarb) range from -22.5 to -3.4‰, indicating a significant but not entirely organic source of carbon. Concretions of the lower Holz Shale exhibit considerably elevated δ13Ccarb values averaging -4.8‰, whereas upper Holz Shale concretions express an average δ13Ccarb value of -17.0‰. If the remaining carbonate for lower Holz Shale concretions is sourced from marine fluids and/or dissolved marine carbonate minerals (e.g., shells), a simple mass balance indicates that ~28% of concretion carbon was sourced from organic matter and ~72% from late Cretaceous marine inorganic carbon (with δ13C ~ +2.5‰). Upper Holz Shale calculations indicate a ~73% contribution from organic matter and a ~27% contribution from inorganic carbon. When normalized for carbonate, organic contents within the concretions are ~2-13 wt.% enriched compared to host contents. This potentially reflects the protective nature of cementation that acts to limit permeability and chemical destruction of

The geology and petroleum potential of the North Afghan platform and adjacent areas (northern Afghanistan, with parts of southern Turkmenistan, Uzbekistan and Tajikistan)

NASA Astrophysics Data System (ADS)

Brookfield, Michael E.; Hashmat, Ajruddin

2001-10-01

The North Afghan platform has a pre-Jurassic basement unconformably overlain by a Jurassic to Paleogene oil- and gas-bearing sedimentary rock platform cover, unconformably overlain by Neogene syn- and post-orogenic continental clastics. The pre-Jurassic basement has four units: (1) An ?Ordovician to Lower Devonian passive margin succession developed on oceanic crust. (2) An Upper Devonian to Lower Carboniferous (Tournaisian) magmatic arc succession developed on the passive margin. (3) A Lower Carboniferous (?Visean) to Permian rift-passive margin succession. (4) A Triassic continental magmatic arc succession. The Mesozoic-Palaeogene cover has three units: (1) A ?Late Triassic to Middle Jurassic rift succession is dominated by variable continental clastics. Thick, coarse, lenticular coal-bearing clastics were deposited by braided and meandering streams in linear grabens, while bauxites formed on the adjacent horsts. (2) A Middle to Upper Jurassic transgressive-regressive succession consists of mixed continental and marine Bathonian to Lower Kimmeridgian clastics and carbonates overlain by regressive Upper Kimmeridgian-Tithonian evaporite-bearing clastics. (3) A Cretaceous succession consists of Lower Cretaceous red beds with evaporites, resting unconformably on Jurassic and older deposits, overlain (usually unconformably) by Cenomanian to Maastrichtian shallow marine limestones, which form a fairly uniform transgressive succession across most of Afghanistan. (4) A Palaeogene succession rests on the Upper Cretaceous limestones, with a minor break marked by bauxite in places. Thin Palaeocene to Upper Eocene limestones with gypsum are overlain by thin conglomerates, which pass up into shales with a restricted brackish-water ?Upper Oligocene-?Lower Miocene marine fauna. The Neogene succession consists of a variable thickness of coarse continental sediments derived from the rising Pamir mountains and adjacent ranges. Almost all the deformation of the North Afghan

Altered carbon cycling and coupled changes in Early Cretaceous weathering patterns: Evidence from integrated carbon isotope and sandstone records of the western Tethys

NASA Astrophysics Data System (ADS)

Wortmann, Ulrich Georg; Herrle, Jens Olaf; Weissert, Helmut

2004-03-01

In this study we investigate if a major perturbation of the Early Cretaceous carbon cycle was accompanied by altered weathering and erosion rates. The large Aptian carbon isotope anomaly records the response of the biosphere to widespread volcanic activity and probably resulting changes in atmospheric pCO2 levels. Elevated pCO2 levels should also result in an accelerated hydrological cycle and increased silicate weathering, creating a negative feedback loop removing CO2 from the atmosphere. We propose to interpret the widespread occurrence of quartz sandstones in the Tethys-Atlantic seaway as a result of altered weathering and erosion rates in the wake of the Aptian carbon cycle excursion. We challenge the traditional notion that these are 'flysch' deposits associated with Early Cretaceous orogenic movements in the western Tethys. We propose that these sandstones were most likely part of a large conveyor belt system, acting along the Iberian and European margin of the Tethys seaway. Using chemostratigraphic correlations, we show that the activity of this system was only short-lived and coeval with changes in coastal ecology and the Aptian carbon cycle perturbations. We tentatively relate the existence of this system to a transient climate regime, characterized by fluctuating pCO2 levels.

Cretaceous shelf-sea chalk deposits

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hattin, D.E.

1988-01-01

The word ''chalk'' is linked etymologically to the Cretaceous, but chalky facies neither dominate that system nor are confined to it. As used commonly, the term ''chalk'' refers to a variety of marine limestone that is white to light gray very fine grained, soft and friable, porous, and composed predominantly of calcitic skeletal remains, especially those derived from coccolithophores. No simple definition suffices to embrace all Cretaceous chalks, which include sandy, marly, shelly, phospatic, glauconitic, dolomitic, pyritic and organic-rich lithotypes. Most of the world's exposed Cretaceous chalk deposits were formed at shelf depths rather than in the deep sea. Cretaceousmore » shelf-sea chalks are developed most extensively in northern Europe, the U.S. Gulf Coastal Plain and Western Interior, and the Middle East, with lesser occurrences alo in Australia. Most Cretaceous shelf-sea chalks formed in the temperature zones, and in relatively deep water. Cretaceous chalks deposited on well-oxygenated sea floors are bioturbated and massive where deficient in terrigenous detritus, or bioturbated and rhythmically interbedded with argillaceous units where influx of terrigenous detritus varied systematically with climate changes. Accumulation of sufficient pelagic mud to form vast deposits of Cretaceous shelf-sea chalk required (1) sustained high productivity of calareous plankton, (2) extensive development of stable shelf and continental platform environments, (3) highstands of seal level, (4) deficiency of aragonitic skeletal material in chalk-forming sediments, and (5) low rates of terrigenous detrital influx. These conditions were met at different times in different places, even within the same general region.« less

Recent carbonate sedimentation on Balearic platform: model for temperate-climate carbonate shelves

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fornos, J.; Rodriguez-Perea, A.; Massuti, C.

Existing models for carbonate sedimentation on continental platforms are derived from the study of modern carbonate platforms in tropical climates. The Balearic platform in the western Mediterranean provides a new model for carbonate sedimentation in a temperature, semiarid climate. On most of the continental shelf around the Balearic Islands, modern sediments are exclusively bioclastic carbonates. Shoreline carbonate sediments are bioclastic sands and muds accumulating in beach-dune systems without significant tidal influence (there are no astronomical tides in the western Mediterranean ). From the upper shoreface to 35 m deep, the sandy bottom is extensively colonized by sea grass (Posidonia oceanica),more » the rhizomes and roots of which form a rigid entrapment that retains the sediment derived from calcareous organisms living within the sea grass and from calcareous epiphytes living on the stems and leaves. Archeological dating establishes a rate of vertical accretion in this zone of 10/sup 3/ Bubnoff units (1 Bubnoff unit = 1 mm/1000 years). Between depths of 40 and 60 m, carbonate sands are composed predominantly or red-algal fragments. Intensely bioturbated wave ripples occur in environments dominated by laminar red algae (Lithothamnium and Phymatolithon). Below depths of 60 m, coarse sediment produced by rhodolitic and ramose red algae is deposited in areas of tens to hundreds of meters in size. Biogenic buildups up to 2 m high occur in sandy areas as well as in deeper muddy areas. At the same depth in open-platform zones, the bottom topography is characterized by large hummocks several hundred meters across. From the horizontal distribution of facies, it is possible to construct the probable vertical sequence of lithofacies which would characterize carbonates accumulating on a temperate-climate carbonate shelf. Many of these lithofacies are recognized in upper Miocene limestones on the Balearic Islands.« less

A revised inoceramid biozonation for the Upper Cretaceous based on high-resolution carbon isotope stratigraphy in northwestern Hokkaido, Japan

NASA Astrophysics Data System (ADS)

Hayakawa, Tatsuya; Hirano, Hiromichi

2013-06-01

Hayakawa, T., Hirano, H. 2013. A revised inoceramid biozonation for the Upper Cretaceous based on high-resolution carbon isotope stratigraphy in northwestern Hokkaido, Japan. Acta Geologica Polonica, 63 (2), 239-263. Warszawa. Biostratigraphic correlations of inoceramid bivalves between the North Pacific and Euramerican provinces have been difficult because the inoceramid biostratigraphy of the Japanese strata has been based on endemic species of the northwest Pacific. In this study, carbon stable isotope fluctuations of terrestrial organic matter are assembled for the Upper Cretaceous Yezo Group in the Haboro and Obira areas, Hokkaido, Japan, in order to revise the chronology of the inoceramid biozonation in Japan. The carbon isotope curves are correlated with those of marine carbonates in English and German sections with the aid of age-diagnostic taxa. According to the correlations of the carbon isotope curves, 11 isotope events are recognised in the sections studied. As a result of these correlations, the chronology of the inoceramid biozones of the Northwest Pacific has been considerably revised. The revised inoceramid biozones suggest that the timing of the origination and extinction of the inoceramids in the North Pacific biotic province is different from the stage/substage boundaries defined by inoceramids, as used in Europe and North America.

Iberian-Europe convergence: evolution of the Cretaceous and Eocene basins in Pyrenees and Provence

DOE Office of Scientific and Technical Information (OSTI.GOV)

Muller, J.; Ducassel, L.; Guieu, G.

1988-08-01

During Cretaceous time the geodynamic evolution of Northern and Western Pyrenean basins was related to scissors-shaped rifting which evolved as a passive margin filled by thick flysch deposits. In Provence, the carbonate platform was marked since the late Albian by the arrival of significant detrital flows originated from an uplifted Paleozoic block situated in the Gulf of Lion. In Provence the northward migration of the basin from Cenomanian to Eocene and Oligocene indicates the growing of the Gulf of Lion-South Provence crustal uplift and its northward displacement. The Cretaceous opening of the western Pyrenean, Parentis, and Bay of Biscay basinsmore » is synchronous with the first stages of compression in the Gulf of Lion. These features are induced by the rotation of Iberia. During the Eocene the compression, resulting from the Iberian-Europe convergence, affected nearly the whole Pyrenean-Provencal area. In the southern part of the Pyrenees east of the Pamplona fault, the successive dislocations of carbonate platforms, migration of reefs, and filling of foreland basins became the signature of the intracontinental subduction of Iberia. The transform fault pattern, still well preserved in spite of the Eocene compression, prevents any important strike-slip movement between Europe and Iberia, especially along the so-called North Pyrenean fault zone, which shows several discontinuities in the western part of Pyrenees. The final evolution of Gulf of Lion crustal uplift generated a gliding of its cover (Provence overthrusts) and, during Oligocene, the opening of the Ligurian-Provencal basin by a propagating rift process.« less

Carbonate Platform Development and Stromatolite Morphogenesis: Constraints on Environmental and Biological Evolution

NASA Technical Reports Server (NTRS)

Grotzinger, John P.

2003-01-01

Work has been completed on the digital mapping of a terminal Proterozoic reef complex in Namibia. This complex formed an isolated carbonate platform developed downdip on a carbonate ramp of the Nama Group. The stratigraphic evolution of the platform was digitally reconstructed from an extensive dataset that was compiled by using digital surveying technologies. The platform comprises three accommodation cycles in which each subsequent cycle experienced progressively greater influence of a long-term accommodation increase. Aggradation and progradation during the first cycle resulted in a flat, uniform, sheet-like platform. The coarsening and shallowing-upward sequence representing the first cycle is dominated by columnar stromatolitic thrombolites and massive dolostones with interbedded mudstone-grainstone at the base of the sequence grading into cross-bedded dolostones. The second cycle features aggradation, formation of a distinct margin containing thrombolite mounds and domes, and the development of a bucket geometry. Columnar stromatolitic thrombolites dominate the platform interior. The final stage of platform development shows a deepening trend with initial aggradation and formation of well-bedded, thin deposits in the interior and mound development at the margins. While the interior drowned, the platform margin kept up with rising sea level and a complex pinnacle reef formed containing fused and coalesced thrombolite mounds flanked by bioclastic grainstones (containing Cloudina and Namacalathus fossils) and collapse breccias. A set of isolated large thrombolite mounds flanked by shales indicate the final stage of the carbonate platform. During a progressive increase in accommodation, a flat-topped isolated carbonate platform becomes aerially less extensive by either backstepping or formation of smaller pinnacles or a combination of both. The overall geometric evolution of the studied platform from flat-topped to bucket with elevated margins is recorded in many

Paleoenvironments of the Jurassic and Cretaceous Oceans: Selected Highlights

NASA Astrophysics Data System (ADS)

Ogg, J. G.

2007-12-01

There are many themes contributing to the sedimentation history of the Mesozoic oceans. This overview briefly examines the roles of the carbonate compensation depth (CCD) and the associated levels of atmospheric carbon dioxide, of the evolution of marine calcareous microplankton, of major transgressive and regressive trends, and of super-plume eruptions. Initiation of Atlantic seafloor spreading in the Middle Jurassic coincided with an elevated carbonate compensation depth (CCD) in the Pacific-Tethys mega-ocean. Organic-rich sediments that would become the oil wealth of regions from Saudi Arabia to the North Sea were deposited during a continued rise in CCD during the Oxfordian-early Kimmeridgian, which suggests a possible increase in carbon dioxide release by oceanic volcanic activity. Deep-sea deposits in near-equatorial settings are dominated by siliceous shales or cherts, which reflect the productivity of siliceous microfossils in the tropical surface waters. The end-Jurassic explosion in productivity by calcareous microplankton contributed to the lowering of the CCD and onset of the chalk ("creta") deposits that characterize the Tithonian and lower Cretaceous in all ocean basins. During the mid-Cretaceous, the eruption of enormous Pacific igneous provinces (Ontong Java Plateau and coeval edifices) increased carbon dioxide levels. The resulting rise in CCD terminated chalk deposition in the deep sea. The excess carbon was progressively removed in widespread black-shale deposits in the Atlantic basins and other regions - another major episode of oil source rock. A major long-term transgression during middle and late Cretaceous was accompanied by extensive chalk deposition on continental shelves and seaways while the oceanic CCD remained elevated. Pacific guyots document major oscillations (sequences) of global sea level superimposed on this broad highstand. The Cretaceous closed with a progressive sea-level regression and lowering of the CCD that again enabled

Community replacement instead of drowning: Evolution of proto-North Atlantic carbonate-platform production in the run-up to of the Early Aptian OAE1a

NASA Astrophysics Data System (ADS)

Huck, Stefan; Stein, Melody; Adatte, Thierry; Föllmi, Karl B.; Immenhauser, Adrian; Heimhofer, Ulrich

2014-05-01

(palaeonutrient fluxes) on the carbonate platform ecosystems, with special focus on the transition from Urgonian-type rudist-nerinid towards orbitolinid-oyster-serpulid dominated limestones; and (3) to compare the considered proto-North Atlantic platform evolution with the coeval punctuated carbonate platform breakdown as observed along the Northern Tethyan margin. Burla, S., Heimhofer, U., Hochuli, P.A., Weissert, H., Skelton, P., 2008. Changes in sedimentary patterns of coastal and deep sea successions from the North Atlantic (Portugal) linked to Early Cretaceous environmental change: Palaeogeography, Palaeoclimatology, Palaeoecology 257 (1-2), 38-57. Godet, A., 2013. Drowning unconformities: Palaeoenvironmental significance and involvement of global processes. Sedimentary Geology 293, 45-66. Invited Review Paper. Huck, S., Heimhofer, U., Immenhauser, A., 2012. Early Aptian algal bloom in a neritic proto-North Atlantic setting: Harbinger of global change related to OAE1a? GSA Bulletin 124 (11-12), 1810-1825.

Early-mid-Cretaceous evolution in Tethyan reef communities and sea level

DOE Office of Scientific and Technical Information (OSTI.GOV)

Scott, R.W.

1988-01-01

The replacement of corals by rudists in Early Cretaceous reefal communities spanned a 30-m.y. period when sea level rose and drowned continental shelves. During this time corals formed communities in the deeper parts of reefs and rudists occupied the shallow, high-energy habitats. By Aptian time rudists dominated reefs that fringed interior shelf basins and corals formed reefs with rudists on the outer shelf margins. By late Albian coral communities had virtually disappeared, presumably because of complex environmental changes and cycles of organic productivity. Two important events of eustatic sea level rise are represented by unconformities separating carbonate depositional sequences onmore » the Arabian platform that correlate with sequence boundaries on the Gulf Coast platform. Graphic correlation techniques test the synchroneity of these events. A composite standard time scale dates these sea level rises at 115.8 Ma and 94.6 Ma; a third, intra-Albian event at 104.3 Ma is present in many places and may also be eustatic. Associated with these sea level rises were apparent changes in ocean water chemistry as evidenced by changes in isotopes and trace elements, where diagenetic effects can be discounted. During this time the climate became more humid and atmospheric CO/sub 2/ increased. The concomitant environmental changes in the oceanic conditions presumably stressed the deeper coral communities on reefs. The emergence of rudists as reef contributors had a profound effect on Late Cretaceous depositional conditions and the development of hydrocarbon reservoirs.« less

Early-mid-Cretaceous evolution in Tethyan reef communities and sea level

DOE Office of Scientific and Technical Information (OSTI.GOV)

Scott, R.W.

1988-02-01

The replacement of corals by rudists in Early Cretaceous reefal communities spanned a 30-m.y. period when sea level rose and drowned continental shelves. During this time corals formed communities in the deeper parts of reefs and rudists occupied the shallow, high-energy habitats. By Aptian time rudists dominated reefs that fringed interior shelf basins and corals formed reefs with rudists on the outer shelf margins. By late Albian coral communities had virtually disappeared, presumably because of complex environmental changes and cycles of organic productivity. Two important events of eustatic sea level rise are represented by unconformities separating carbonate depositional sequences onmore » the Arabian platform that correlate with sequence boundaries on the Gulf Coast platform. Graphic correlation techniques test the synchroneity of these events. A composite standard time scale dates these sea level rises at 115.8 Ma and 94.6 Ma; a third, intra-Albian event at 104.3 Ma is present in many places and may also be eustatic. Associated with these sea level rises were apparent changes in ocean water chemistry as evidenced by changes in isotopes and trace elements, where diagenetic effects can be discounted. During this time the climate became more humid and atmospheric CO/sub 2/ increased. The concomitant environmental changes in the oceanic conditions presumably stressed the deeper coral communities on reefs. The emergence of rudists as reef contributors had a profound effect on Late Cretaceous depositional conditions and the development of hydrocarbon reservoirs.« less

Assessing the duration of drowning episodes during the Early Cretaceous

NASA Astrophysics Data System (ADS)

Godet, A.; Föllmi, K. B.

2013-12-01

Drowning unconformities are stratigraphic key surfaces in the history of carbonate platforms. They mostly consist in the deposition of deep marine facies on top of shallow marine limestones. Although large-scale depositional geometries mimic lowstand systems track architecture, these sedimentary turnovers are developed in relation with major sea level rise, inducing an increase in the rate of creation of accommodation space that outpaces the capacity of carbonate to keep up. This so-called paradox of carbonate platform drowning implies that other parameters than purely eustatic fluctuations are involved in the demise of shallow marine ecosystems. Worldwide and at different time during Earth history, in-depth studies of drowning unconformities revealed that changes in nutrient input, clastic delivery, temperature, or a combination of them may be responsible for a decrease in light penetration in the water column and the progressive suffocation and poisoning of photosynthetic carbonate producers. The examination of such case examples from various stratigraphic intervals and palaeogeographical settings thus helps in identifying and hierarchizing potential triggering mechanisms for drowning unconformities. This is complemented by new data from Early Cretaceous successions from the Helvetic Alps. During this time period, the Helvetic carbonate platform developed along the northern Tethyan margin using both photozoan and heterozoan communities. Phases of healthy production were interrupted by several drowning episodes. The latter are marked in the sedimentary record by condensation and associated phosphogenesis and glauconitisation. From the earliest Valanginian to the early to late Barremian, three drowning unconformities reflect the intermittent installation of a more humid climate and subsequent enhanced trophic conditions, which first induced a switch from photozoan to heterozoan communities and then to long-lasting drowning phases. The latter encompass several sea

Modeling the Impact of Forest and Peat Fires on Carbon-Isotopic Compositions of Cretaceous Atmosphere and Vegetation

NASA Astrophysics Data System (ADS)

Finkelstein, D. B.; Pratt, L. M.

2004-12-01

Prevalence of wildfires or peat fires associated with seasonally dry conditions in the Cretaceous is supported by recent studies documenting the widespread presence of pyrolytic polycyclic aromatic hydrocarbons and fusinite. Potential roles of CO2 emissions from fire have been overlooked in many discussions of Cretaceous carbon-isotope excursions (excluding K-P boundary discussions). Enhanced atmospheric CO2 levels could increase fire frequency through elevated lightning activity. When biomass or peat is combusted, emissions of CO2 are more negative than atmospheric CO2. Five reservoirs (atmosphere, vegetation, soil, and shallow and deep oceans), and five fluxes (productivity, respiration, litter fall, atmosphere-ocean exchange, and surface-deep ocean exchange) were modeled as a closed system. The size of the Cretaceous peat reservoir was estimated by compilation of published early Cretaceous coal resources. Initial pCO2 was assumed to be 2x pre-industrial atmospheric levels (P.A.L.). Critical variables in the model are burning efficiency and post-fire growth rates. Assuming 1% of standing terrestrial biomass is consumed by wildfires each year for ten years (without combustion of peat), an increase of atmospheric CO2 (from 2.0 to 2.2x P.A.L.) and a negative carbon isotope excursion (-1.2 ‰ ) are recorded by both atmosphere and new growth. Net primary productivity linked to the residence time of the vegetation and soil reservoirs results in a negative isotope shift followed by a broad positive isotope excursion. Decreasing the rate of re-growth dampens this trailing positive shift and increases the duration of the excursion. Post-fire pCO2 and new growth returned to initial values after 72 years. Both negative and positive isotope excursions are recorded in the model in surface ocean waters. Exchange of CO2 with the surface- and deep-ocean dampens the isotopic shift of the atmosphere. Excursions are first recorded in the atmosphere (and new growth), followed by

Carbonate-platform response to the Toarcian Oceanic Anoxic Event in the southern hemisphere: Implications for climatic change and biotic platform demise

NASA Astrophysics Data System (ADS)

Han, Zhong; Hu, Xiumian; Kemp, David B.; Li, Juan

2018-05-01

The Toarcian Oceanic Anoxic Event (T-OAE, ∼183 Ma) was a profound short-term environmental perturbation associated with the large-scale release of 13C-depleted carbon into the global ocean-atmosphere system, which resulted in a significant negative carbon-isotope excursion (CIE). The general lack of characteristic T-OAE records outside of the northern hemisphere means that the precise environmental effects and significance of this event are uncertain. Many biotic carbonate platforms of the northern hemisphere western Tethys drowned or shifted to non-skeletal platforms during the early Toarcian. However, southern hemisphere records of Toarcian carbonate platforms are rare, and thus the extent and significance of biotic platform demise during the T-OAE is unclear. Here we present high-resolution geochemical and sedimentological data across two Pliensbachian-Toarcian shallow-water carbonate-platform sections exposed in the Tibetan Himalaya. These sections were located paleogeographically on the open southeastern tropical Tethyan margin in the southern hemisphere. The T-OAE in the Tibetan Himalaya is marked by a negative CIE in organic matter. Our sedimentological analysis of the two sections reveals an abundance of storm deposits within the T-OAE interval, which emphasizes a close link between warming and tropical storms during the T-OAE event, in line with evidence recently provided from western Tethyan sections of the northern hemisphere. In addition, our analysis also reveals extensive biotic carbonate-platform demise by drowning or changing to non-skeletal carbonates coincident with the onset of the CIE. Taken together, our results suggest that rapid and pervasive seawater warming in response to carbon release likely played a significant role in sudden biotic carbonate platform demise, and suppression/postponement of biotic platform re-development along the whole tropical/subtropical Tethyan margin.

Early environmental effects of the terminal Cretaceous impact

NASA Technical Reports Server (NTRS)

Gilmour, Iain; Wolbach, Wendy S.; Anders, Edward

1988-01-01

The environmental aftereffects of the terminal Cretaceous impact are examined on the basis of the carbon and nitrogen geochemistry in the basal layer of the K-T boundary clay at Woodside Creek, New Zealand. It is shown that organic carbon and nitrogen at this level are enriched by 15 and 20 times Cretaceous values, respectively. Also, it is found that the N abundances and, to a lesser extent, the organic C abundances are closely correlated with the Ir abundances. The changes in carbon and nitrogen content through the basal layer are outlined, focusing on the possible environmental conditions which could have caused enrichment. In addition, consideration is given to the soot and pyrotoxin content. Possible scenarios for the K-T event and the importance of selective extinction are discussed.

Fluid-flow, diagenesis and generation of secondary porosity-permeability in the Cretaceous Jandaira Formation, Brazil - an analogue of karstified carbonate reservoirs

NASA Astrophysics Data System (ADS)

Bezerra, F. H.; Cazarin, C. L.; Srivastava, N. K.

2017-12-01

This study investigates the diagenetic processes that generated secondary porosity-permeability in carbonates. Our study area is the Jandaira Formation, a post-rift unit, 50-700 m thick, which occurs over an area of 70 x 260 km in the Potiguar Basin, Equatorial margin of Brazil. The Jandaira Formation formed in the Turonian-Campanian and is the major exposed Cretaceous carbonate platform in the eastern continental margin of South America. Little folding and nearly flat-lying layers characterize this unit. We used a multidisciplinary approach, which included drone imagery, petrographic, petrophysical, petrological, and structural studies. Our results indicate that several levels of dissolution occurred in mudstone, grainstone, and wackestone facies along faults, fractures, and bedding planes. Fracture and faults provided vertical leaching pathways and sedimentary bedding provided horizontal pathways of increased secondary porosity and permeability. Dissolution resulted in a multi-scale karst system that could reach voids 5 m wide and 1 km long. Dissolution mostly affect the dolomitized sedimentary facies in the form of vugular, moldic, interparticular, and intercrystalline porosity. It also generated a new modified facies that we defined as karstified facies. Dissolution increased permeability in carbonate rocks from primary values of 0.0-0.94 mD to as much as 1370.11 mD. Micritization, lixiviation of evaporites, meteoric water infiltration and dolomitization during late diagenesis could have triggered dissolution processes. The Jandaira Formation serves as an analog of fractured and karstified carbonate reservoirs, where faults, joints, and bedding acted as pathways of high permeability.

Diagenesis of lower Cretaceous pelagic carbonates, North Atlantic: Paleoceanographic signals obscured

USGS Publications Warehouse

Frank, T.D.; Arthur, M.A.; Dean, W.E.

1999-01-01

The stable isotope and minor element geochemistry of Neocomian (Lower Cretaceous) pelagic carbonates of the North Atlantic Basin (Deep Sea Drilling Project Sites 105, 367, 387, 391, and 603) was examined to develop a diagenetic model for pelagic limestones. In particular, we hoped to test the fidelity of whole-rock geochemical records as paleoceanographic indicators for pelagic deposits of pre-Aptian age, in which individual microfossils are not available for analysis. Data indicate that in addition to depth of burial, rhythmic variations in primary carbonate content have strongly controlled diagenetic patterns and associated geochemical signatures in these Neocomian sequences. Samples become increasingly depleted in Sr and 18O with increasing CaCO3 content. Within individual sedimentary sections, substantial decreases in Sr/Ca ratios and ??18O values are evident over a range of 4 to 98% CaCO3. However, even over a relatively narrow range of 50 to 98% CaCO3 a 2.5%c variation in ??18O values and a change of a factor of 1.7 in Sr/Ca ratios are observed. Carbon isotope compositions do not vary as extensively with CaCO3 content, but carbonate-rich intervals tend to be relatively depleted in 13C. Petrographic analysis reveals that these geochemical patterns are related to the transfer of CaCO3 from carbonate-poor intervals (calcareous shales and marlstones) to adjacent carbonate-rich intervals (limestones) during burial compaction and pressure solution. This process results in the addition of diagenetic cement to carbonate-rich intervals to produce a bulk composition that is relatively depleted in Sr and 18O and, at the same time, enables the retention of more-or-less primary carbonate that is relatively enriched in Sr and 18O in adjacent carbonate-poor intervals. Thus, although cyclic variations in CaCO3 content are primary in the Neocomian sequences examined, measured variations in Sr/Ca ratios and ??18O values are not and, as such, do not provide reliable proxies for

Early dolomitization in the Lower Cretaceous shallow-water carbonates of Southern Apennines (Italy): Clues about palaeoclimatic fluctuations in western Tethys

NASA Astrophysics Data System (ADS)

Vinci, Francesco; Iannace, Alessandro; Parente, Mariano; Pirmez, Carlos; Torrieri, Stefano; Giorgioni, Maurizio

2017-12-01

A multidisciplinary study of the dolomitized bodies present in the Lower Cretaceous platform carbonates of Mt. Faito (Southern Apennines - Italy) was carried out in order to explore the connection between early dolomite formation and fluctuating climate conditions. The Berriasian-Aptian investigated succession is 466 m thick and mainly consists of shallow-water lagoonal limestones with frequent dolomite caps. The dolomitization intensity varies along the succession and reaches its peak in the upper Hauterivian-lower Barremian interval, where it is present a completely dolomitized interval about 100-m-thick. Field relations, petrography, mineralogy, and geochemistry of the analyzed dolomite bodies allowed identifying two populations of early dolomites, a fine-medium crystalline (FMdol) and a coarse crystalline dolomite (Cdol), both interpreted as the product of mesohaline water reflux. According to our interpretation, FMdol precipitated from concentrated brines in the very early stage of the reflux process, producing typical sedimentary features as dolomite caps. In the successive step of the process, the basin-ward 'latent' reflux precipitated Cdol from less concentrated brines. A peculiar feature of the studied succession is the great consistency between stratigraphic distribution of dolomite bodies and their geochemical signature. The completely dolomitized Hauterivian-Barremian interval, in fact, is characterized by geochemical values suggesting an origin from distinctly saltier brines. Considering that the observed near-surface dolomitization process is controlled by physical and chemical parameters reflecting the paleoenvironmental and paleoclimatic conditions during dolomite formation, we propose that the stratigraphically controlled dolomitization intensity reflects periodic fluctuations in the salinity of dolomitizing fluid, in turn controlled by long-term climate oscillations. The present work highlights that the stratigraphic distribution of early

Jurassic-Cretaceous history of Cuba: implications for the evolution of the southern margin of the North American plate

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barros, J.A.; Rosencrantz, E.

The oldest Cuban sedimentary rocks, clastics of the Bajocian San Cayetano Fm. provide the earliest record of North American-Gondwana rifting as seen in Cuba. A similar clastic sequence is seen below the carbonates of the Bahamas platform. In the Pinar del Rio area, the San Cayetano is succeeded by Oxfordian limestones, the shallow water Jagua Fm. to the south and deeper water Francisco Fm. to the north. Both contain basaltic pillow lavas, related either to rifting or to leaky transform motion parallel to the margin. The Oxfordian units are overlain by Kimmeridgian to Tithonian pelagic limestones, the Guasasa and Artemisamore » Fms. The later interfingers with northerly derived calci-turbidites. North of the Escambray, silici-clastic fragments in late Jurassic pelagic limestones suggests that a basement high existed south of the platform until the Berriasian. The carbonate platform continues to shed debris along its southern edge throughout the Cretaceous. To the south an Aptian-Albian episode of turbidite deposition suggests that South America-Africa rifting caused tectonic disturbances in the Caribbean. Southerly derived volcanoclastics deposited during the Maastrichtian marks the start of the Cuban orogeny.« less

Evaluating the use of amber in palaeoatmospheric reconstructions: The carbon-isotope variability of modern and Cretaceous conifer resins

NASA Astrophysics Data System (ADS)

Dal Corso, Jacopo; Schmidt, Alexander R.; Seyfullah, Leyla J.; Preto, Nereo; Ragazzi, Eugenio; Jenkyns, Hugh C.; Delclòs, Xavier; Néraudeau, Didier; Roghi, Guido

2017-02-01

Stable carbon-isotope geochemistry of fossilized tree resin (amber) potentially could be a very useful tool to infer the composition of past atmospheres. To test the reliability of amber as a proxy for the atmosphere, we studied the variability of modern resin δ13C at both local and global scales. An amber δ13C curve was then built for the Cretaceous, a period of abundant resin production, and interpreted in light of data from modern resins. Our data show that hardening changes the pristine δ13C value by causing a 13C-depletion in solid resin when compared to fresh liquid-viscous resin, probably due to the loss of 13C-enriched volatiles. Modern resin δ13C values vary as a function of physiological and environmental parameters in ways that are similar to those described for leaves and wood. Resin δ13C varies between plant species and localities, within the same tree and between different plant tissues by up to 6‰, and in general increases with increasing altitudes of the plant-growing site. We show that, as is the case with modern resin, Cretaceous amber δ13C has a high variability, generally higher than that of other fossil material. Despite the high natural variability, amber shows a negative 2.5-3‰ δ13C trend from the middle Early Cretaceous to the Maastrichtian that parallels published terrestrial δ13C records. This trend mirrors changes in the atmospheric δ13C calculated from the δ13C and δ18O of benthic foraminiferal tests, although the magnitude of the shift is larger in plant material than in the atmosphere. Increasing mean annual precipitation and pO2 could have enhanced plant carbon-isotope fractionation during the Late Cretaceous, whereas changing pCO2 levels seem to have had no effect on plant carbon-isotope fractionation. The results of this study suggest that amber is a powerful fossil plant material for palaeoenvironmental and palaeoclimatic reconstructions. Improvement of the resolution of the existing data coupled with more detailed

Preliminary vitrinite and bitumen reflectance, total organic carbon, and pyrolysis data for samples from Upper and Lower Cretaceous strata, Maverick Basin, south Texas

USGS Publications Warehouse

Hackley, Paul C.; Dennen, Kristin O.; Gesserman, Rachel M.; Ridgley, Jennie L.

2009-01-01

The Lower Cretaceous Pearsall Formation, a regionally occurring limestone and shale interval of 500-600-ft maximum thickness (Rose, 1986), is being evaluated as part of an ongoing U.S. Geological Survey (USGS) assessment of undiscovered hydrocarbon resources in onshore Lower Cretaceous strata of the northern Gulf of Mexico. The purpose of this report is to release preliminary vitrinite and bitumen reflectance, total organic carbon, and pyrolysis data for Pearsall Formation, Glen Rose Formation, Hosston Formation, Austin Group, and Eagle Ford Group samples from the Maverick Basin in south Texas in order to aid in the characterization of these strata in this area. The preliminary nature of this report and the data contained herein reflect that the assessment and characterization of these samples is a work currently in progress. Pearsall Formation subdivisions are, in ascending stratigraphic order, the Pine Island Shale, James Limestone, and Bexar Shale Members (Loucks, 2002). The Lower Cretaceous Glen Rose Formation is also part of the USGS Lower Cretaceous assessment and produces oil in the Maverick Basin (Loucks and Kerans, 2003). The Hosston Formation was assessed by the USGS for undiscovered oil and gas resources in 2006 (Dyman and Condon, 2006), but not in south Texas. The Upper Cretaceous Austin Group is being assessed as part of the USGS assessment of undiscovered hydrocarbon resources in the Upper Cretaceous strata of the northern Gulf of Mexico and, along with the Upper Cretaceous Eagle Ford Group, is considered to be an important source rock in the Smackover-Austin-Eagleford Total Petroleum System (Condon and Dyman, 2006). Both the Austin Group and the Eagle Ford Group are present in the Maverick Basin in south Texas (Rose, 1986).

Dissolution Rates of Biogenic Carbonate Sediments from the Bermuda Platform

NASA Astrophysics Data System (ADS)

Finlay, A. J.; Andersson, A. J.

2016-02-01

The contribution of biogenic carbonate sediment dissolution rates to overall net reef accretion/erosion (under both present and future oceanic pCO2 levels) has been strikingly neglected, despite experimental results indicating that sediment dissolution might be more sensitive to ocean acidification (OA) than calcification. Dissolution of carbonate sediments could impact net reef accretion rates as well as the formation and preservation of valuable marine and terrestrial ecosystems. Bulk sediment dissolution rates of samples from the Bermuda carbonate platform were measured in natural seawater at pCO2 values ranging from approximately 3500 μatm to 9000 μatm. This range of pCO2 levels incorporates values currently observed in porewaters on the Bermuda carbonate platform as well as a potential future increase in porewater pCO2 levels due to OA. Sediment samples from two different stations on the reef platform were analyzed for grain size and mineralogy. Dissolution rates of sediments in the dominant grain size fraction of the platform (500-1000 μm) from both stations ranged between 16.25 and 47.19 (± 0.27 to 0.79) μmoles g-1 hr-1 and are comparable to rates previously obtained from laboratory experiments on other natural carbonate sediments. At a pCO2 of 3500 μatm, rates from both samples were similar, despite their differing mineralogy. However, at pCO2 levels above 3500 μatm, the sediment sample with a greater weight percent of Mg-calcite had slightly higher dissolution rates. Despite many laboratory studies on biogenic carbonate dissolution, a significant disparity still exists between laboratory measurements and field observations. Performing additional controlled, laboratory experiments on natural sediment may help to elucidate the reasons for this disparity.

Calpionellid distribution and microfacies across the Jurassic/ Cretaceous boundary in western Cuba (Sierra de los Órganos)

NASA Astrophysics Data System (ADS)

López-Martínez, Rafael; Barragán, Ricardo; Reháková, Daniela; Cobiella-Reguera, Jorge Luis

2013-06-01

A detailed bed-by-bed sampled stratigraphic section of the Guasasa Formation in the Rancho San Vicente area of the "Sierra de los Órganos", western Cuba, provides well-supported evidence about facies and calpionellid distribution across the Jurassic/Cretaceous boundary. These new data allowed the definition of an updated and sound calpionellid biozonation scheme for the section. In this scheme, the drowning event of a carbonate platform displayed by the facies of the San Vicente Member, the lowermost unit of the section, is dated as Late Tithonian, Boneti Subzone. The Jurassic/Cretaceous boundary was recognized within the facies of the overlying El Americano Member on the basis of the acme of Calpionella alpina Lorenz. The boundary is placed nearly six meters above the contact between the San Vicente and the El Americano Members, in a facies linked to a sea-level drop. The recorded calpionellid bioevents should allow correlations of the Cuban biozonation scheme herein proposed, with other previously published schemes from distant areas of the Tethyan Domain.

Drowned carbonate platforms in the Huon Gulf, Papua New Guinea

NASA Astrophysics Data System (ADS)

Webster, Jody M.; Wallace, Laura; Silver, Eli; Applegate, Bruce; Potts, Donald; Braga, Juan Carlos; Riker-Coleman, Kristin; Gallup, Christina

2004-11-01

The western Huon Gulf, Papua New Guinea, is an actively subsiding foreland basin dominated by drowned carbonate platforms. We investigated these platforms using new high-resolution multibeam, side-scan sonar and seismic data, combined with submersible observations and previously published radiometric and sedimentary facies data. The data reveal 14 distinct drowned carbonate platforms and numerous pinnacles/banks that increase in age (˜20-450 kyr) and depth (0.1-2.5 km) NE toward the Ramu-Markham Trench. Superimposed on this overall downward flexing of the platforms toward the trench is a systematic tilting of the deep platforms 15 m/km toward the NW and the shallow platforms 2 m/km toward the SE. This may reflect the encroaching thrust load from the NW (Finisterre Range) and spatial variations in the flexural rigidity of the underlying basement. The drowned platforms form a complex system of promontories and reentrants, with abundant pinnacles and banks preserved at similar depths seaward of the main platforms. This configuration closely mimics the present-day Huon coastline and its seaward islands fringed by modern coral reefs. The platforms retain structural, morphologic, and sedimentary facies evidence of primary platform growth, drowning, and subsequent backstepping, despite some lateral erosion of the platform margins (<100 m slope defacement) by mass wasting. Both platforms and pinnacles are composite features containing multiple terrace levels and notches, corresponding to multiple phases of growth, emergence, and drowning in response to rapid climatic and sea level changes during the evolution of each structure. On the basis of all observational and numerical modeling data, we propose a chronology for the initiation, growth, and drowning of the 14 platforms. Over shorter timescales (≤100 kyr) the rate and amplitude of eustatic sea level changes are critical in controlling initiation, growth, drowning or subaerial exposure, subsequent reinitiation, and

Stratigraphic correlation of the Late Cretaceous Simsima Formation United Arab Emirates and Akveren Formation, northwest Turkey

NASA Astrophysics Data System (ADS)

Abdelghany, O.; Abu Saima, M.; Ramazanoglu, S.; Arman, H.

2015-11-01

Latest Cretaceous (Campanian-Maastrichtian) microfossils are used to correlate the carbonate rocks of the Simsima Formation in the northeastern part of the Arabian Peninsula (Northern Oman Mountains, United Arab Emirates and Oman) with the Akveren Formation in Kandira (northwest Turkey, near Black Sea region). Both formations have characteristically rich planktonic foraminiferal and calcareous nannofossil faunal assemblages that permit the recognition of the Globotruncanella havanensis Zone and Quadrum sissinghii Zone CC22. The palaeontological data is used to build an appropriate palaeoenvironmental model for the latest Cretaceous Aruma Group in the Oman Mountains foreland basin. The study reveals that the Late Cretaceous formations of UAE and Turkey can be divided into an open marine carbonate shelf facies (planktonic foraminifera/calcareous nannofossil biomicrite) and a shallow-marine carbonate facies (rudistids, coralline algal foraminiferal biomicrite).

The role of ocean currents for carbonate platform stratigraphy (Invited)

NASA Astrophysics Data System (ADS)

Betzler, C.; Lindhorst, S.; Luedmann, T.; Eberli, G. P.; Reijmer, J.; Huebscher, C. P.

2013-12-01

Breaks and turnovers in carbonate bank growth and development record fluctuations in sea-level and environmental changes. For the carbonate banks of the Bahamas, the Maldives, the Queensland, and the Marion Plateau, sea-level changes and synchronous oceanographic and atmospheric circulation events were recorded through compositional and architectural changes. Most of these major carbonate edifices contain drift deposits, indicating that oceanic currents were a major driver of carbonate-bank evolution. It is proposed that such currents have a larger imprint on the growth patterns and the stratigraphic packaging of carbonates than previously thought. In the Bahamas, slope facies of carbonate banks exposed to deep oceanic currents are not arranged into sediment-texture controlled and depth-dependant strike-continuous facies belts. Facies patterns are controlled by the interplay of shallow-water input, succeeding sediment sorting as well as redistribution and erosion processes. This complements the classical windward - leeward classification of carbonate platform slopes and accounts for the significant and potentially dominant process of alongslope sediment transport and dispersal. Deep oceanic currents also have the potential to steepen the carbonate bank slopes, through sediment winnowing at the distal slope, such as for example in the Maldives. This process can be enhanced as the bank grows and expands in size which may accelerate currents. Oceanic current onset or amplification, however, may also account for slope steepening as an externally, i.e. climate-driven agent, thus forcing the banks into an aggradation mode of growth which is not a response to sea-level fluctuations or a result of the windward / leeward exposure of the bank edge. Ignorance of the impact of currents on platforms and platform slopes may lead to an erroneous conclusion that changes in sediment production, distribution, and morphologies of sediment bodies are features solely related to sea

North American nonmarine climates and vegetation during the Late Cretaceous

USGS Publications Warehouse

Wolfe, J.A.; Upchurch, G.R.

1987-01-01

?? latitude is inferred. Equability was high: a mean annual range of temperature of about 8??C is inferred for paleolatitude 51-56??N during the Campanian. Most Late Cretaceous plants evolved in a climate characterized by absence of freezing and low to moderate amounts of precipitation. A brief, low-temperature excursion and a major, long-lasting increase in precipitation occurred at the Cretaceous-Tertiary boundary. In megathermal climates, these events selected for plants that could exist in rainforest environments. In mesothermal climates, deciduousness and contamitant structural adaptations were selected. The events at the Cretaceous-Tertiary boundary had a major and long-lasting impact on the evolution of land plants and their ecosystems. Low precipitation at low to middle Late Cretaceous latitudes is suggested to be the result of high levels of atmospheric CO2, which, in turn, are probably related to inability of warm, saline oceans to store large amounts of carbon. Conditions appear to have rapidly changed at the Cretaceous-Tertiary boundary, when oceanic circulation and stratification may have been fundamentally altered. After the boundary, the oceans were apparently able to store much greater amounts of carbon, and the oceans withdrew large amounts of CO2 from the atmosphere. In turn, more precipitation fell at low to middle latitudes; the resulting high-biomass vegetation formed a second major carbon reservoir to keep atmospheric CO2 low relative to the Late Cretaceous. Changes in oceanic and atmospheric circulation probably resulted from some factor external to the ocean-atmosphere system. ?? 1987.

Deep-Water Resedimented Carbonate Exploration Play Types: Controls and Models

NASA Astrophysics Data System (ADS)

Minzoni, M.; Janson, X.; Kerans, C.; Playton, T.; Winefield, P.; Burgess, P. M.

2016-12-01

Deepwater resedimented deposits have been described in both modern and ancient carbonate sequences, many with good reservoir potential, for example the giant Cretaceous Poza Rica field in Mexico ( 40 MMBoe), the Mississippian Tangiz field in Kazakhstan, and several fields in the U.S. Permian basin (several Tcf gas). Nevertheless, carbonate slope and basin systems remain poorly understood when compared to their siliciclastic counterparts. Legacy published and unpublished work, combined with a global database of surface and sub-surface examples of resedimented carbonates, has highlighted that downslope resedimentation of carbonate material is in large part controlled by the evolution of the parent platform margin, which in turn is best characterized in terms of various controlling processes such as the carbonate factory type, tectonic setting, eustatic variations, and prevailing wind direction and ocean current patterns. Two generic play types emerge: (i) attached carbonate slope play -developed immediately adjacent to the parent carbonate platform and dominated by rock fall and platform collapse deposits or in situ boundstone; and (ii) detached carbonate slope play - deposited further from the platform margin via channelized turbidity currents and other mass-flow processes. High-rising, steep, bypass platform margins with collapse scars and grain-dominated factories have the highest potential to generate channelized and detached deep-water reservoirs with high initial porosity and permeability. Best reservoirs are aragonitic grainstones transported from the platform into the adjacent basin, and undergoing dissolution in submarine undersaturated water with early formation of secondary porosity to further enhance reservoir properties. Any exploration model aiming at identifying potential resedimented carbonate plays should be based on carbonate platform configurations and factory types favorable for re-sedimentation of large sedimentary bodies and preservation or

Accumulation of organic matter in Cretaceous oxygen-deficient depositional environments in the central Pacific Ocean

USGS Publications Warehouse

Dean, W.E.; Claypool, G.E.; Thide, J.

1984-01-01

and intercepts of C-S regression lines however, are different for each site and all are different from regression lines for samples from modern anoxic marine sediments and from Black Sea cores. The organic-carbon-rich limestones on Hess Rise, the Mid-Pacific Mountains, and other plateaus and seamounts in the Pacific Ocean are not synchronous but do occur within the same general middle Cretaceous time period as organic-carbon-rich lithofacies elsewhere in the world ocean, particularly in the Atlantic Ocean. Strata of equivalent age in the deep basins of the Pacific Ocean are not rich in organic carbon, and were deposited in oxygenated environments. This observation, together with the evidence that the plateau sites were considerably shallower and closse to the equator during the middle Creataceous suggests that local tectonic and hydrographic conditions may have resulted in high surface-water productivity and the preservation of organic matter in an oxygen-deficient environment where an expanded mid-water oxygen minimum developed and impinged on elevated platforms and seamounts. ?? 1984.

Impact of tectonic and volcanism on the Neogene evolution of isolated carbonate platforms (SW Indian Ocean)

NASA Astrophysics Data System (ADS)

Courgeon, S.; Jorry, S. J.; Jouet, G.; Camoin, G.; BouDagher-Fadel, M. K.; Bachèlery, P.; Caline, B.; Boichard, R.; Révillon, S.; Thomas, Y.; Thereau, E.; Guérin, C.

2017-06-01

Understanding the impact of tectonic activity and volcanism on long-term (i.e. millions years) evolution of shallow-water carbonate platforms represents a major issue for both industrial and academic perspectives. The southern central Mozambique Channel is characterized by a 100 km-long volcanic ridge hosting two guyots (the Hall and Jaguar banks) and a modern atoll (Bassas da India) fringed by a large terrace. Dredge sampling, geophysical acquisitions and submarines videos carried out during recent oceanographic cruises revealed that submarine flat-top seamounts correspond to karstified and drowned shallow-water carbonate platforms largely covered by volcanic material and structured by a dense network of normal faults. Microfacies and well-constrained stratigraphic data indicate that these carbonate platforms developed in shallow-water tropical environments during Miocene times and were characterized by biological assemblages dominated by corals, larger benthic foraminifera, red and green algae. The drowning of these isolated carbonate platforms is revealed by the deposition of outer shelf sediments during the Early Pliocene and seems closely linked to (1) volcanic activity typified by the establishment of wide lava flow complexes, and (2) to extensional tectonic deformation associated with high-offset normal faults dividing the flat-top seamounts into distinctive structural blocks. Explosive volcanic activity also affected platform carbonates and was responsible for the formation of crater(s) and the deposition of tuff layers including carbonate fragments. Shallow-water carbonate sedimentation resumed during Late Neogene time with the colonization of topographic highs inherited from tectonic deformation and volcanic accretion. Latest carbonate developments ultimately led to the formation of the Bassas da India modern atoll. The geological history of isolated carbonate platforms from the southern Mozambique Channel represents a new case illustrating the major

Changes in carbonate sedimentation and faunal assemblages in the Tunisian carbonate platform around the Cenomanian-Turonian boundary

NASA Astrophysics Data System (ADS)

Touir, Jamel; Mechi, Chefia; Haj Ali, Hajer

2017-05-01

In Tunisia the Cenomanian-Turonian boundary coincides with the transition between two carbonate deposits: the Late Cenomanian Bahloul Formation at the bottom and the Early Turonian Gattar Member at the top. According to field study and microscope examination of the studied Formations throughout Tunisia, the Bahloul Formation consists of a deep-water condensed carbonate platform largely extended throughout Tunisia. Detailed analysis shows a particular richness in planktonic microfauna and ammonites. Thin bedded limestones within the Upper part exhibits a high TOC ratio and commonly called the black shales, whereas the Gattar Member displayed a rudist-bearing carbonate ramp which pinches northward while being progressively relayed by hemipelagic marls forming the so-called Annaba Member. The Cenomanian-Turonian transition was marked by relevant changes the main features of which are well recorded in the Tunisian carbonate platform. The changes consist of consecutive (i) shutdown and recovery of the carbonate factory and (ii) extinction, development and diversification of many faunal species. As matter of fact, during Late Cenomanian many planktonic foraminifers (Rotaliporidae) and rudists (Caprinidae) were extinct, and simultaneously the carbonate production rate fallen into 0.003-0.017 m k y -1. During Early Turonian the carbonate platform recovered contemporaneously with the development and diversification of many planktonic foraminifera and rudists (Hippuritidae); the carbonate productivity rose to 0.125 m k y -1 in average. The whole previous changes are to be linked with the significant sea-level fluctuation and the contemporaneous oceanic anoxic event (OAE2) having occurred at the Cenomanian-Turonian boundary.

Numerical analysis of seawater circulation in carbonate platforms: I. Geothermal convection

USGS Publications Warehouse

Sanford, W.E.; Whitaker, F.F.; Smart, P.L.; Jones, G.

1998-01-01

Differences in fluid density between cold ocean water and warm ground water can drive the circulation of seawater through carbonate platforms. The circulating water can be the major source of dissolved constituents for diagenetic reactions such as dolomitization. This study was undertaken to investigate the conditions under which such circulation can occur and to determine which factors control both the flux and the patterns of fluid circulation and temperature distribution, given the expected ranges of those factors in nature. Results indicate that the magnitude and distribution of permeability within a carbonate platform are the most important parameters. Depending on the values of horizontal and vertical permeability, heat transport within a platform can occur by one of three mechanisms: conduction, forced convection, or free convection. Depth-dependent relations for porosity and permeability in carbonate platforms suggest circulation may decrease rapidly with depth. The fluid properties of density and viscosity are controlled primarily by their dependency on temperature. The bulk thermal conductivity of the rocks within the platform affects the conductive regime to some extent, especially if evaporite minerals are present within the section. Platform geometry has only a second-order effect on circulation. The relative position of sealevel can create surface conditions that range from exposed (with a fresh-water lens present) to shallow water (with hypersaline conditions created by evaporation in constricted flow conditions) to submerged or drowned (with free surface water circulation), but these boundary conditions and associated ocean temperature profiles have only a second-order effect on fluid circulation. Deep, convective circulation can be caused by horizon tal temperature gradients and can occur even at depths below the ocean bottom. Temperature data from deep holes in the Florida and Bahama platforms suggest that geothermal circulation is actively

The global Cretaceous-Tertiary fire: Biomass or fossil carbon

NASA Technical Reports Server (NTRS)

Gilmour, Iain; Guenther, Frank

1988-01-01

The global soot layer at the K-T boundary indicates a major fire triggered by meteorite impact. However, it is not clear whether the principal fuel was biomass or fossil carbon. Forests are favored by delta value of C-13, which is close to the average for trees, but the total amount of elemental C is approximately 10 percent of the present living carbon, and thus requires very efficient conversion to soot. The PAH was analyzed at Woodside Creek, in the hope of finding a diagnostic molecular marker. A promising candidate is 1-methyl-7-isopropyl phenanthrene (retene,), which is probably derived by low temperature degradation of abietic acid. Unlike other PAH that form by pyrosynthesis at higher temperatures, retene has retained the characteristic side chains of its parent molecule. A total of 11 PAH compounds were identified in the boundary clay. Retene is present in substantial abundance. The identification was confirmed by analysis of a retene standard. Retene is characteristic of the combustion of resinous higher plants. Its formation depends on both temperature and oxygen access, and is apparently highest in oxygen-poor fires. Such fires would also produce soot more efficiently which may explain the high soot abundance. The relatively high level of coronene is not typical of a wood combustion source, however, though it can be produced during high temperature pyrolysis of methane, and presumably other H, C-containing materials. This would require large, hot, low O2 zones, which may occur only in very large fires. The presence of retene indicates that biomass was a significant fuel source for the soot at the Cretaceous-Tertiary boundary. The total amount of elemental C produced requires a greater than 3 percent soot yield, which is higher than typically observed for wildfires. However, retene and presumably coronene imply limited access of O2 and hence high soot yield.

Late Cretaceous- Cenozoic history of deciduousness and the terminal Cretaceous event.

USGS Publications Warehouse

Wolfe, J.A.

1987-01-01

Deciduousness in mesic, broad-leaved plants occurred in disturbed, middle-latitude environments during the Late Cretaceous. Only in polar environments in the Late Cretaceous was the deciduous element dominant, although of low diversity. The terminal Cretaceous event resulted in wide-spread selection for plants of deciduous habit and diversification of deciduous taxa, thus leaving a lasting imprint on Northern Hemisphere vegetation. Various environmental factors have played important roles in subsequent diversification of mesic, broad-leaved deciduous taxa and in origination and decline of broad-leaved deciduous forests. Low diversity and rarity of mesic deciduous plants in the post-Cretaceous of the Southern Hemisphere indicate that the inferred 'impact winter' of the terminal Cretaceous event had little effect on Southern Hemisphere vegetation and climate. -Author

A critical evaluation of carbon isotope stratigraphy and biostratigraphic implications for Late Cretaceous global correlation

NASA Astrophysics Data System (ADS)

Wendler, Ines

2013-11-01

Climate variability is driven by a complex interplay of global-scale processes and our understanding of them depends on sufficient temporal resolution of the geologic records and their precise inter-regional correlation, which in most cases cannot be obtained with biostratigraphic methods alone. Chemostratigraphic correlation based on bulk sediment carbon isotopes is increasingly used to facilitate high-resolution correlation over large distances, but complications arise from a multitude of possible influences from local differences in biological, diagenetic and physico-chemical factors on individual δ13C records that can mask the global signal. To better assess the global versus local contribution in a δ13C record it is necessary to compare numerous isotopic records on a global scale. As a contribution to this objective, this paper reviews bulk sediment δ13Ccarb records from the Late Cretaceous in order to identify differences and similarities in secular δ13C trends that help establish a global reference δ13C record for this period. The study presents a global-scale comparison of twenty δ13C records from sections representing various palaeo-latitudes in both hemispheres and different oceanic settings from the Boreal, Tethys, Western Interior, Indian Ocean and Pacific Ocean, and with various diagenetic overprinting. The isotopic patterns are correlated based on independent dating with biostratigraphic and paleomagnetic data and reveal good agreement of the major isotope events despite offsets in absolute δ13C values and variation in amplitude between the sites. These differences reflect the varying local influences e.g. from depositional settings, bottom water age and diagenetic history, whereas the concordant patterns in δ13C shifts might represent δ13C fluctuations in the global seawater dissolved inorganic carbon. The latter is modulated by variations in organic matter burial relative to re-mineralization, in the global-scale formation of authigenic

Facies interfingering and synsedimentary tectonics on late Ladinian-early Carnian carbonate platforms (Dolomites, Italy)

NASA Astrophysics Data System (ADS)

Keim, Lorenz; Brandner, Rainer

2001-11-01

A stratigraphic model for carbonate platform evolution in the Dolomites during the late Ladinian-early Carnian is presented. New light on pre-Raibl growth of individual carbonate platforms of the western Dolomites was shed by biostratigraphic data combined with a revised lithostratigraphy. At the Schlern, Langkofel and Sella, the carbonate factory (Upper Schlern Dolomite) remained productive into the lowermost Carnian (Cordevolian = Aon Zone), and caused a levelling-out of the former steep platform-to-basin relief. In the eastern Dolomites, platforms were producing till basal Julian 2 (Austriacum Zone). At the Sella and Langkofel, the sedimentation pattern after deposition of the Upper Schlern Dolomite was strongly influenced by synsedimentary tectonics. A first phase of extensional tectonics led to local fissures, block-tilting, graben structures and breccia deposits. Composition and fabric of the reworked clasts argue for local-source sediments and short transport distances. The extensional structures are sealed by sediments of Lower Carnian age. Two facies belts (Schlernplateau beds and Dürrenstein Dolomite), which interfinger at the western side of the Sella, reflect the shallow marine environment with terrigenous-volcanoclastic input in the western Dolomites. A second generation of breccias at the Sella documents local fracturing of the Dürrenstein and Upper Schlern Dolomite. Depositional environments across the western and eastern Dolomites were largely dependent on differential subsidence. The sediments of early Carnian age on top of the Schlern platform are a few metres thick only, whereas, in the eastern Dolomite, up to 400-m-thick carbonate sediments ('Richthofen reef' and Settsass platform) were deposited. The most incomplete stratigraphic record is present at the Mendel platform in the west, where Ladinian volcanics are unconformably overlain by late Carnian 'Raibl beds'. The increase in sediment thickness towards the eastern Dolomites becomes partly

North-South Gradients in Carbon Isotopic Compositions of Atlantic Ocean Black Shales: Evidence for Paleohydrologic Influences on Mid-Cretaceous Black Shale Deposition

NASA Astrophysics Data System (ADS)

Meyers, P. A.

2013-12-01

Organic del13C values of organic-carbon-rich Albian-Cenomanian-Turonian black shales from a north-south transect of the Atlantic Ocean have been compiled to explore for possible existence of latitudinal patterns. Black shales at equatorial sites have mean del13C values of -28 per mil, whereas black shales at mid-latitude sites have mean del13C values around -25 per mil. The mid-Cretaceous del13C values are routinely lower than those of modern marine sediments. The more negative Cretaceous del13C values generally reflect concentrations of atmospheric CO2 that were four to six times higher than today, but the geographic differences imply a regional overprint on this global feature. Latitudinal differences in oceanic temperature might be a factor, but a low thermal gradient from the poles to the equator during the mid-Cretaceous makes this factor not likely to be significant. Instead, a correspondence between the geographic differences in the organic del13C values of black shales with the modern latitudinal precipitation pattern suggests that differences in precipitation are a more likely factor. Establishment of a strongly salinity-stratified near-surface ocean and magnified delivery of land-derived phosphorus by continental runoff during this time of a magnified hydrologic cycle were evidently significant to deposition of marine black shales. A likely scenario is that the stratification resulted in blooms of nitrogen-fixing bacteria that become the dominant photoautotrophs and thereby stimulated primary production of organic matter. Regional differences in precipitation resulted in different amounts of runoff, consequent stratification, enhancement of primary production, and therefore the different carbon isotopic compositions of the black shales.

Exhumation History Of Brasilian Highlands After Late Cretaceous Alcaline Magmatism

NASA Astrophysics Data System (ADS)

Doranti Tiritan, Carolina; Hackspacher, Peter Christian; Carina Siqueira Ribeiro, Marli; Glasmacher, Ulrich Anton; Françoso de Godoy, Daniel

2017-04-01

The southeast Brazilian margin recorded a long history of tectonic and magmatic events after the Gondwana continent break up. The drifting of the South American Platform over a thermal anomaly generated a series of alkaline intrusions that are distributed from the interior to the coast from west to east. Several exhumation events are recorded on the region and we are providing insights on the landscape evolution of the region since Late Cretaceous, comparing low temperature thermochronology results from two alkaline intrusions regions. Poços de Caldas Alkaline Massif (PCAM), is lied in the interior, 300km from the coastline, covering over 800km2 intruding the Precambrian basement around 83Ma, nepheline syenites, phonolites and tinguaites intruded in a continuous and rapid sequence lasting between 1 to 2 Ma. São Sebastião Island (SSI) on the other hand is located at the coast, 200 km southeast of São Paulo. It is characterized by an intrusion in Precambrian/Brazilian orogen and intruded by Early Cretaceous sub-alkaline basic and acid dykes, as well as by Late Cretaceous alkaline stocks (syenites) and dykes (basanite to phonolite). Will be presenting the apatite fission track (AFT) and (U-Th)/He results that shows the main difference between the areas is that PCAM region register older history then the coastal area of SSI, where thermal history starts register cooling event after the South Atlantic rifting process, while in the PCAM area register a previous history, since Carboniferous. The results are giving support to studies that indicate the development of the relief in Brazil being strongly influenced by the local and regional tectonic movements and the lithological and structural settings. The landscape at the Late Cretaceous was witness of heating process between 90 and 60Ma due the intense uplift of South American Platform. The elevation of the isotherms is associated with the mantellic plumes and the crustal thickness that caused thermal anomalies due

Sedimentologic Expression of the Cretaceous OAEs in a Tropical Epicontinental Sea

NASA Astrophysics Data System (ADS)

Silva-Tamayo, J. C.; Eisenhauer, A.

2015-12-01

The acidification and deoxygention of modern oceans are major environmental concerns to the international community. The effects of ocean acidification and deoxigention in the biogeochemical cycles of modern tropical oceans are poorly constrained mainly due to the lack of empirical and quantitative data. The Cretaceous World witnessed several period of potential ocean acidification and deoxygenation, which resulted from the rapid additions of volcanic derived CO2 to the atmosphere. The effects of ocean acidification and deoxygenation on the Cretaceous biogeochemical cycles are evidenced mainly by major global C-isotope anomalies. These anomalies parallel the occurrence of organic rich black shales as well as major decreases in the deposition of shallow marine carbonates worldwide. Here we use detailed C- and Sr- chemostratigraphy as well as published bioestratigraphic information and volcanic zircon U-Pb ages to precisely constrain the geochemical and sedimentologic expression of the Cretaceous OAES along a tropical epicontinental sea, the La Luna Sea. Our multi-pronged approach allows identifying the occurrence of several of the Cretaceous Oceanic Anoxic Events (OAEs) in carbonate units paleogeographically located along the northern most part of the La Luna Sea, i.e. Weissert-OAE-(Palanz and Rosablanca Formations), Faraoni-(Rosablanca Formation), AOE1a-(Paja and Fomeque Formations, Cogollo Group), OAE1c-(Cogollo Group), OAE2-(Cogollo Group), OAE3-(La Luna Formation). These events are preserved in highly euxinic - organic rich "black shales" successions deposited along the deepest part of the seaway at the Middle Magdalena Valley and Cundinamarca Basin; Weiser-OAE-(Lutitas de Macanal Formation), OAE1a-(Paja Formation, Fomeque Formation), OAE1C-(San Gil Formation). Regional changes in depositional settings and sedimentary facies preserving the different Cretaceous OAEs were likely the result of the combined action of regional changes in paleogeography and tectonic

Cambrian Series 3 carbonate platform of Korea dominated by microbial-sponge reefs

NASA Astrophysics Data System (ADS)

Hong, Jongsun; Lee, Jeong-Hyun; Choh, Suk-Joo; Lee, Dong-Jin

2016-07-01

Metazoans have been considered as negligible components of Cambrian Series 3 and Furongian microbial-dominated reefs, in contrast to their presence in earlier Terreneuvian-Cambrian Series 2 microbial-archaeocyath reefs. However, recent discoveries of sponges in Cambrian Series 3-Furongian reefs of Australia, China, Iran, USA, and Korea have raised question regarding their contribution in terms of carbonate platform development, which have never been assessed. This study examines Cambrian Series 3 deposits of the Daegi Formation, Korea to elucidate this question. The 100-m-thick middle part of the Daegi Formation is dominated by boundstone facies, which occupies 45% of the study interval, as well as bioclastic wackestone to packstone, bioclastic grainstone, and ooid packstone to grainstone facies. The Daegi reefs are primarily thrombolitic in composition, with 90% (n = 26/29) of the reefs containing an average of 9% sponges in aerial percentage calculated from thin sections. Lithistid sponges composed of peloidal fabrics, some desma spicules, and spicule networks commonly occupy the interstitial space in microbial clusters, are encrusted by mesoclots and Epiphyton, and are surrounded by micrite. Subordinate non-lithistid demosponges occur within clusters of microbial elements. The middle Daegi Formation can be largely subdivided into shoal environment dominated by grainstone to packstone facies and shallow subtidal platform interior environment located behind shoal with wackestone to packstone facies. The microbial-sponge reefs mainly developed around platform interior as patch reefs. The current study indicates that metazoans in the form of lithistid and non-lithistid demosponges are nearly ubiquitously incorporated in Daegi reefs and contributed greatly to the formation of microbial-sponge reefs as well as carbonate platform during the time. Study of these microbial-sponge reefs and their distribution within the carbonate platform may help us to understand how

Depletion of 13C in Cretaceous marine organic matter: Source, diagenetic, or environmental sigal?

USGS Publications Warehouse

Dean, W.E.; Arthur, M.A.; Claypool, G.E.

1986-01-01

Geochemical studies of Cretaceous strata rich in organic carbon (OC) from Deep Sea Drilling Project (DSDP) sites and several land sections reveal several consistent relationships among amount of OC, hydrocarbon generating potential of kerogen (measured by pyrolysis as the hydrogen index, HI), and the isotopic composition of the OC. First, there is a positive correlation between HI and OC in strata that contain more than about 1% OC. Second, percent OC and HI often are negatively correlated with carbon isotopic composition (?? 13C) of kerogen. The relationship between HI and OC indicates that as the amount of organic matter increases, this organic matter tends to be more lipid rich reflecting the marine source of the organic matter. Cretaceous samples that contain predominantly marine organic matter tend to be isotopically lighter than those that contain predominantly terrestrial organic matter. Average ?? 13C values for organic matter from most Cretaceous sites are between -26 and -28???, and values heavier than about -25??? occur at very few sites. Most of the ?? 13C values of Miocene to Holocene OC-rich strata and modern marine plankton are between -16 to -23???. Values of ??13C of modern terrestrial organic matter are mostly between -23 and -33???. The depletion of terrestial OC in 13C relative to marine planktonic OC is the basis for numerous statements in the literature that isotopically light Cretaceous organic matter is of terrestrial origin, even though other organic geochemical and(or) optical indicators show that the organic matter is mainly of marine origin. A difference of about 5??? in ?? 13C between modern and Cretaceous OC-rich marine strata suggests either that Cretaceous marine planktonic organic matter had the same isotopic signature as modern marine plankton and that signature has been changed by diagenesis, or that OC derived from Cretaceous marine plankton was isotopically lighter by about 5??? relative to modern plankton OC. Diagenesis does

Carbon Dioxide Observational Platform System (CO-OPS), feasibility study

NASA Technical Reports Server (NTRS)

Bouquet, D. L.; Hall, D. W.; Mcelveen, R. P.

1987-01-01

The Carbon Dioxide Observational Platform System (CO-OPS) is a near-space, geostationary, multi-user, unmanned microwave powered monitoring platform system. This systems engineering feasibility study addressed identified existing requirements such as: carbon dioxide observational data requirements, communications requirements, and eye-in-the-sky requirements of other groups like the Defense Department, the Forestry Service, and the Coast Guard. In addition, potential applications in: earth system science, space system sciences, and test and verification (satellite sensors and data management techniques) were considered. The eleven month effort is summarized. Past work and methods of gathering the required observational data were assessed and rough-order-of magnitude cost estimates have shown the CO-OPS system to be most cost effective (less than $30 million within a 10 year lifetime). It was also concluded that there are no technical, schedule, or obstacles that would prevent achieving the objectives of the total 5-year CO-OPS program.

High resolution carbon isotope stratigraphy and glendonite occurrences of the Christopher Formation, Sverdrup Basin (Axel Heiberg Island, Canada): implications for mid Cretaceous high latitude climate change

NASA Astrophysics Data System (ADS)

Herrle, Jens O.; Schröder-Adams, Claudia J.; Galloway, Jennifer M.; Pugh, Adam T.

2013-04-01

Understanding the evolution of Canada's Arctic region, as a crucial component of Earth's climate system, is fundamental to assess short and long-term climate, environmental, and paleogeographic change. However, the stratigraphy and paleoenvironmental evolution of the Cretaceous Arctic is poorly constrained and a detailed bio- and chemostratigraphic correlation of major mid-Cretaceous paleoceanographic turning points such as Oceanic Anoxic Events, cold snaps, and biotic turnovers with key locations of the high- and low latitudes is missing. Here we present for the first time a high resolution bio- and carbon isotope stratigraphy of the Arctic Albian Christopher Formation of the Sverdrup Basin at Glacier Fiord in the southern part of Axel Heiberg Island, Canadian High Arctic. By using these techniques we developed a high temporal framework to record major environmental changes as it is indicated by the occurrence of glendonites and sandstone intervals of our studied Albian succession. The Albian Christopher Formation is a shale dominated marine unit with a thickness of approximately 1200 m. Several transgressive/ regressive cycles can be recognized by prograding shoreface units that break up mudrock deposition. In addition, glendonites are mainly found in the lower part of the Christopher Formation. Glendonites are pseudomorphs of calcite, after the metastable mineral ikaite, and have been often described from high latitude Permian, Jurassic and Cretaceous marine environments from the Canadian Arctic, Spitsbergen and Australia. The formation of glendonites takes place in the uppermost layer of the sediment and requires near-freezing temperatures, high salinity, and orthophosphate-rich bottom water. Although the presence of glendonites implies a range of paleoenvironmental conditions there is a consensus in the scientific literature that they reflect cooler paleoenvironmental conditions. Preliminary bio- and carbon isotope stratigraphic results suggest that the

Deep-Sea Carbonate Accumulation and Surface Ocean Saturation State in the Aftermath of the Cretaceous-Paleogene extinction

NASA Astrophysics Data System (ADS)

Pruss, S. B.; Higgins, J. A.; Bush, A. M.; Leckie, R. M.; Deeg, C.; Getzin, B. L.

2016-12-01

The role of the K-Pg extinction on biogeochemical cycling has been intensively studied in recent years. However, it remains unknown how extinctions in marine pelagic calcifiers impacted carbon cycling in the ocean. Low accumulation rates of microfossils in the aftermath of the extinction have been attributed to lowered production, which triggered a reduction in carbonate delivery to the seafloor. Interestingly, although microfossil abundance is lower and foraminifera are significantly smaller than in the latest Cretaceous, carbonate accumulated on the seafloor in the earliest Paleogene even in areas that should have been below the CCD. One such deep-water site in the South Pacific (U1370) was cored during IODP Expedition 329 in November 2010. We examined 16 samples from an anomalous carbonate layer provisionally assigned to lower Paleocene planktonic foraminiferal Zones P1a and P1b that preserves benthic and planktonic foraminifera. Carbon isotope values of the benthic species Nuttalies orealis range from 1.45 to 1.95‰ VPDB in the 16 samples. The planktonic species Parasubbotina pseudobulloides was only abundant enough for analysis in 4 samples, and these values range from 1.41 to 1.91‰ VPDB. We note, as others have, that no carbon isotope gradient existed between the benthic and planktonic foraminifera during the deposition of this carbonate layer, perhaps due to reduced primary production and/or export of organic carbon. The presence of this carbonate layer in the deep ocean and its preservation of a collapsed isotopic gradient are both consistent with a reduction in the surface-to-deep water gradient in carbonate saturation state during the unusual oceanographic conditions that followed the extinction. We speculate that this was associated with a sustained reduction in surface ocean saturation state with adverse consequences for neritic carbonate producers in the aftermath of the K-T extinction.

A Multiproxy Record of the Toarcian Oceanic Anoxic Event in Shallow-Water Carbonates from the Dinaric Carbonate Platform, Slovenia

NASA Astrophysics Data System (ADS)

Ettinger, N. P.; Martindale, R. C.; Kosir, A.; Thibodeau, A. M.

2016-12-01

Oceanic anoxic events (OAEs) have been shown to have an intimate influence on source rock deposition, marine extinctions, and the reorganization of carbonate factories throughout geologic time. Today, the possibility of environmental deterioration such as warming, acidification, and decreased oxygenation in modern oceans has increased the importance of ancient analogues. Therefore, studies of ancient rapid environmental change, such as the Toarcian Oceanic Anoxic Event, can inform our understanding of how marine ecosystems will respond to similar stresses in the future. The Toarcian OAE coincides with a marine mass extinction and the deposition of deep-water black shales; the putative cause of the OAE is the emplacement of the Karoo-Ferrar-Chon Aike Large Igneous Province. Although black shales are the hallmark of oceanic anoxic events, the contemporaneous shallow marine response to anoxia and other stresses is subtler and poorly documented by comparison. We will present a record of Pliensbachian-Toarcian aged shallow-water carbonates from the Dinaric Carbonate Platform in Slovenia. This platform provides a key record of the Toarcian OAE, as it is one of the few platforms from the Tethys Ocean that experienced nearly continuous sedimentation throughout the Pliensbachian and Toarcian as a result of tectonic quiescence. Sedimentological, geochemical, and paleontological data from two sections of the Trnovski Gozd karst plateau are used to assess the timing of volcanism and the response of biotic and abiotic carbonates to environmental changes associated with the OAE. Benthic forams, dasycladacean algae, and oncolitic packstones dominate diverse skeletal assemblages in the Pliensbachian record. The stage boundary coincides with anomalies in redox-sensitive elements, a hiatus in carbonate production represented by marine firmgrounds, and an anomalous increase in mercury content. The early Toarcian record is dominated by crinoidal-oolitic packstones and grainstones

A New Platform for Managing Soil Carbon and Soil Health

DOE Office of Scientific and Technical Information (OSTI.GOV)

Loisel, Julie; Malhotra, Avni; Phillips, Claire

International Soil Carbon Network Workshop; Stanford, California, 27 February to 3 March 2017. Here, workshop participants recognized the need to identify vulnerabilities and opportunities for linking SOM-C science and the societal mandate to manage soils and ecosystems for productivity and carbon sequestration in future decades. Lastly, we outlined a path to gain support for the ISCN vision of a collective soil data platform from stakeholders and partners through engagement in coming years.

A New Platform for Managing Soil Carbon and Soil Health

DOE PAGES

Loisel, Julie; Malhotra, Avni; Phillips, Claire

2017-08-25

International Soil Carbon Network Workshop; Stanford, California, 27 February to 3 March 2017. Here, workshop participants recognized the need to identify vulnerabilities and opportunities for linking SOM-C science and the societal mandate to manage soils and ecosystems for productivity and carbon sequestration in future decades. Lastly, we outlined a path to gain support for the ISCN vision of a collective soil data platform from stakeholders and partners through engagement in coming years.

Petroleum systems of the Southeast Tertiary basins and Marbella area, Southeast Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fuentes, F.

1996-08-01

This study was done in an area where insufficient organic-rich rocks were available for a reliable oil-source rock correlation. However, oil-rock correlations, molecular characteristics of key horizons, paleofacies maps, maturation and potential migration pathways suggest the Tithonian as a major source rock. Moreover, there is good evidence of high quality source rocks in Oxfordian, Kimmeridgian, Middle-Upper Cretaceous and Paleogene (mainly in the Eocene). Plays were identified in Upper Jurassic oolitic sequences, Early-Middle Cretaceus carbonate platform rocks and breccias, Late Cretaceous basinal fracture carbonates, Paleogene carbonates and breccias, Early-Middle Miocene mounds and submarine fans and isolated carbonate platform sediments and Miocene-Recentmore » turbidites. Seal rocks are shaly carbonates and anhydrites from Tithonian, basinal carbonates and anhydrites from Middle-Upper Cretaceous, basinal carbonates and marls from Upper Cretaceous and Paleogene shales, and bathyal shales from Early Miocene-Recent. The first phase of oil migration from upper Jurassic-Early Cretaceous source rocks occurred in the Early-Middle Cretaceous. In the Upper Cretaceous the Chortis block collided with Chiapas, and as a result mild folding and some hydrocarbons were emplaced to the structural highs. The main phase of structuration and folding of the Sierra de Chiapas started in the Miocene, resulting in well-defined structural traps. Finally, in Plio-Pleistocene the Chortis block was separated, the major compressional period finished and the southern portion of Sierra de Chiapas was raised isostatically. As a result of major subsidence, salt withdrawal and increased burial depth, conditions were created for the generation of liquid hydrocarbons from the Paleogene shales.« less

Global fire at the Cretaceous-Tertiary boundary

NASA Technical Reports Server (NTRS)

Wolbach, Wendy S.; Gilmour, Iain; Anders, Edward; Orth, Charles J.; Brooks, Robert R.

1988-01-01

Cretaceous-Tertiary boundary clays rich in iridium from five sites in Europe and New Zealand were investigated. The clays are found to be 100-10,000-fold-enriched in elemental carbon (mainly soot), which is isotopically uniform and apparently comes from a single global fire. The soot layer coincides with the iridium layer, suggesting that the fire was triggered by meteorite impact and began before the ejecta had settled.

Major wildfires at the Cretaceous-Tertiary boundary

NASA Technical Reports Server (NTRS)

Anders, Edward; Wolbach, Wendy S.; Gilmour, Iain

1991-01-01

The current status of the reconstruction of major biomass fire events at the Cretaceous-Tertiary boundary is discussed. Attention is given to the sources of charcoal and soot, the identification of biomass and fossil carbon, and such ignition-related problems as delated fires, high atmospheric O2 content, ignition mechanisms, and the greenhouse-effect consequences of fire on the scale envisioned. Consequences of these factors for species extinction patterns are noted.

Characteristics of depositional environment and evolution of Upper Cretaceous Mishrif Formation, Halfaya Oil field, Iraq based on sedimentary microfacies analysis

NASA Astrophysics Data System (ADS)

Zhong, Yuan; Zhou, Lu; Tan, Xiucheng; Guo, Rui; Zhao, Limin; Li, Fei; Jin, Zhimin; Chen, Yantao

2018-04-01

As one of the most important carbonate targets in the Middle East, Upper Cretaceous Mishrif Formation has been highlighted for a long time. Although consensus has been reached on the overall sedimentary background, disputes still exist in understanding the sedimentary environment changes among sub-regions due to relatively limited research, rare outcrop, and incomplete drilled core, which hinders the analysis on sedimentary environment and thus the horizontal and vertical correlation. In this study, taking the Halfaya Oil Field as an example, the sedimentary microfacies analysis method was introduced to comprehensively characterize the cored interval of Mishrif Formation, including Single Layers MC1-1 to MA2. A total of 11 sedimentary microfacies are identified through system identification of sedimentary microfacies and environmental analysis, with reference to the standard microfacies classification in the rimmed carbonate platform. Then three kinds of environments are identified through microfacies assemblage analysis, namely restricted platform, open platform, and platform margin. Systematic analyses indicate that the deposits are mainly developed in the open platform and platform margin. Meanwhile, rock-electricity interpretation model is established according to the electricity response to cored intervals, and is then employed to interpret the uncored intervals, which finally helps build the sedimentary evolution pattern through horizontal and vertical correlation. It is proposed that the Single Layers MC1-1 to MB2-3 were deposited in the open platform featured by low water level, including sub-environments of low-energy shoal within platform and inter-shoal sea; Single Layers MB2-2 to MB1-2B were deposited in the open platform and platform margin, including sub-environments of high-energy shoal on the platform margin, low-energy shoal within platform, inter-shoal sea, and open sea; and Single Layers MB1-2A to MA2 were again deposited in the open platform

Upper Cretaceous sequences and sea-level history, New Jersey Coastal Plain

USGS Publications Warehouse

Miller, K.G.; Sugarman, P.J.; Browning, J.V.; Kominz, M.A.; Olsson, R.K.; Feigenson, M.D.; Hernandez, J.C.

2004-01-01

We developed a Late Cretaceous sealevel estimate from Upper Cretaceous sequences at Bass River and Ancora, New Jersey (ODP [Ocean Drilling Program] Leg 174AX). We dated 11-14 sequences by integrating Sr isotope and biostratigraphy (age resolution ??0.5 m.y.) and then estimated paleoenvironmental changes within the sequences from lithofacies and biofacies analyses. Sequences generally shallow upsection from middle-neritic to inner-neritic paleodepths, as shown by the transition from thin basal glauconite shelf sands (transgressive systems tracts [TST]), to medial-prodelta silty clays (highstand systems tracts [HST]), and finally to upper-delta-front quartz sands (HST). Sea-level estimates obtained by backstripping (accounting for paleodepth variations, sediment loading, compaction, and basin subsidence) indicate that large (>25 m) and rapid (???1 m.y.) sea-level variations occurred during the Late Cretaceous greenhouse world. The fact that the timing of Upper Cretaceous sequence boundaries in New Jersey is similar to the sea-level lowering records of Exxon Production Research Company (EPR), northwest European sections, and Russian platform outcrops points to a global cause. Because backstripping, seismicity, seismic stratigraphic data, and sediment-distribution patterns all indicate minimal tectonic effects on the New Jersey Coastal Plain, we interpret that we have isolated a eustatic signature. The only known mechanism that can explain such global changes-glacio-eustasy-is consistent with foraminiferal ??18O data. Either continental ice sheets paced sea-level changes during the Late Cretaceous, or our understanding of causal mechanisms for global sea-level change is fundamentally flawed. Comparison of our eustatic history with published ice-sheet models and Milankovitch predictions suggests that small (5-10 ?? 106 km3), ephemeral, and areally restricted Antarctic ice sheets paced the Late Cretaceous global sea-level change. New Jersey and Russian eustatic estimates

Coupling carbon isotopes with astrochronology and correlation techniques for Late Cretaceous chronostratigraphic refinement and paleoclimate reconstruction

NASA Astrophysics Data System (ADS)

Jones, M. M.; Sageman, B. B.; Meyers, S. R.

2016-12-01

Late Cretaceous carbon isotope ratios (δ13C) recorded in organic matter and marine carbonates preserve an archive of the global carbon cycle in a greenhouse climate state. Due to excellent connectivity among surface carbon reservoirs and the low residence time of carbon in them, excursions in the δ13C that record changes in fluxes serve as widely correlative chronostratigraphic markers. In this study, floating astronomical time scales (ATS) from an organic carbon-rich marine Turonian succession at Demerara Rise (tropical N. Atlantic) are combined with high-resolution δ13C chemostratigraphy to estimate CIE timing and duration for refinement of the geologic time scale. In addition, a Gaussian kernel smoothing technique for objective correlation of astronomically tuned δ13C records is developed. Correlation with three coeval Turonian sections (Western Interior Basin, Texas, & Europe) shows consistency in astronomical and radioisotopic time scale ages for CIEs. In particular, a mid-Turonian sea level fall is demonstrated to be synchronous within 100 ka uncertainty. Spectral analyses of δ13Corg, %TOC, %Carbonate, and C/N time series provide insights into astronomical forcings influencing paleoclimate and paleoceanographic conditions in the tropical proto-North Atlantic upwelling zone. The stable long eccentricity cycle ( 405 ka) is robustly recorded in all geochemical data, and has the highest amplitude in %TOC, %Carbonate, and C/N time series. However, δ13C from Demerara Rise is dominated by a 1 Myr cycle resembling long obliquity, suggesting a dynamic organic carbon reservoir and/or climate feedback originating in high-latitudes was prominent during the Turonian greenhouse carbon cycle. This investigation emphasizes δ13C chemostratigraphy and astrochronology are useful chronostratigraphic methods for importing high-resolution time control into disparate basins to answer questions regarding sea level records, paleoclimate, and mass extinction on a global scale

Use of synthetic sonic logs derived from seismic data in interpretation of stratigraphic variation in cretaceous carbonates of North field area, Qatar

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aves, H.S.; Tappmeyer, D.M.

This study uses geologic and synthetic sonic sections to evaluate the hydrocarbon potential of the Lower and middle Cretaceous Thamama Group carbonates of the Mishrif, Nahr, Umr, Shuaiba, and Kharaib Formations in the North Field, Qatar. The North field area, a regional high throughout Lower and middle Cretaceous time, is document by depositional thinning and by higher energy carbonate facies development. Oil and gas accumulations are found on the crestal portions of this paleohigh in structural/stratigraphic traps. Three factors affect the interval velocities on both a regional and local basis. These are (1) variation of carbonate facies-higher energy wackestone/packstone andmore » possibly grainstones flanked by predominantly mudstones, (2) secondary porosity developed near the top of unconformity surfaces, and (3) the existence of hydrocarbons in the reservoir. Many local lateral and vertical variations in interval velocities were noted on the synthetic sonic sections that would have otherwise been undetected, such as areas of tight or porous reservoir development, permeability barriers, and subtle faulting. In these studied formations, there are many examples of low interval velocity zones that are known to contain hydrocarbons whereas equivalent higher interval velocity zones on the seismic sections at other well site locations do not contain hydrocarbons. In many places, these variations are of sufficient magnitude to be mapped as intraformational permeability barriers. These variations were useful in explaining the occurrence of different oil-water and gas-water contacts within the same formation that could not be explained solely on structural criteria.« less

The Role of Faulting on the Growth of a Carbonate Platform: Evidence from 3D Seismic Analysis and Section Restoration

NASA Astrophysics Data System (ADS)

Nur Fathiyah Jamaludin, Siti; Pubellier, Manuel; Prasad Ghosh, Deva; Menier, David; Pierson, Bernard

2014-05-01

Tectonics in addition to other environmental factors impacts the growth of carbonate platforms and plays an important role in shaping the internal architecture of the platforms. Detailed of faults and fractures development and healing in carbonate environment have not been explored sufficiently. Using 3D seismic and well data, we attempt to reconstruct the structural evolution of a Miocene carbonate platform in Central Luconia Province, offshore Malaysia. Luconia Province is located in the NW coast of Borneo and has become one of the largest carbonate factories in SE Asia. Seismic interpretations including seismic attribute analysis are applied to the carbonate platform to discern its sedimentology and structural details. Detailed seismic interpretations highlight the relationships of carbonate deposition with syn-depositional faulting. Branching conjugate faults are common in this carbonate platform and have become a template for reef growth, attesting lateral facies changes within the carbonate environments. Structural restoration was then appropriately performed on the interpreted seismic sections based on sequential restoration techniques, and provided images different from those of horizon flattening methods. This permits us to compensate faults' displacement, remove recent sediment layers and finally restore the older rock units prior to the fault motions. It allows prediction of platform evolution as a response to faulting before and after carbonate deposition and also enhances the pitfalls of interpretation. Once updated, the reconstructions allow unravelling of the un-seen geological features underneath the carbonate platform, such as paleo-structures and paleo-topography which in turn reflects the paleo-environment before deformations took place. Interestingly, sections balancing and restoration revealed the late-phase (Late Oligocene-Early Miocene) rifting of South China Sea, otherwise difficult to visualize on seismic sections. Later it is shown that

New biosensing platforms based on the layer-by-layer self-assembling of polyelectrolytes on Nafion/carbon nanotubes-coated glassy carbon electrodes.

PubMed

Rivas, Gustavo A; Miscoria, Silvia A; Desbrieres, Jacques; Barrera, Gustavo D

2007-01-15

We are proposing for the first time the use of a Nafion/multi-walled carbon nanotubes dispersion deposited on glassy carbon electrodes (GCE) as a new platform for developing enzymatic biosensors based on the self-assembling of a chitosan derivative and different oxidases. The electrodes are obtained by deposition of a layer of Nafion/multi-wall carbon nanotubes dispersion on glassy carbon electrodes, followed by the adsorption of a chitosan derivative as polycation and glucose oxidase, l-aminoacid oxidase or polyphenol oxidase, as polyanions and biorecognition elements. The optimum configuration for glucose biosensors has allowed a highly sensitive (sensitivity=(0.28+/-0.02)muAmM(-1), r=0.997), fast (4s in reaching the maximum response), and highly selective (0% interference of ascorbic acid and uric acid at maximum physiological levels) glucose quantification at 0.700V with detection and quantification limits of 0.035 and 0.107mM, respectively. The repetitivity for 10 measurements was 5.5%, while the reproducibility was 8.4% for eight electrodes. The potentiality of the new platform was clearly demonstrated by using the carbon nanotubes/Nafion layer as a platform for the self-assembling of l-aminoacid oxidase and polyphenol oxidase. Therefore, the platform we are proposing here, that combines the advantages of nanostructured materials with those of the layer-by-layer self-assembling of polyelectrolytes, opens the doors to new and exciting possibilities for the development of enzymatic and affinity biosensors using different transdution modes.

Late Cretaceous seasonal ocean variability from the Arctic.

PubMed

Davies, Andrew; Kemp, Alan E S; Pike, Jennifer

2009-07-09

The modern Arctic Ocean is regarded as a barometer of global change and amplifier of global warming and therefore records of past Arctic change are critical for palaeoclimate reconstruction. Little is known of the state of the Arctic Ocean in the greenhouse period of the Late Cretaceous epoch (65-99 million years ago), yet records from such times may yield important clues to Arctic Ocean behaviour in near-future warmer climates. Here we present a seasonally resolved Cretaceous sedimentary record from the Alpha ridge of the Arctic Ocean. This palaeo-sediment trap provides new insight into the workings of the Cretaceous marine biological carbon pump. Seasonal primary production was dominated by diatom algae but was not related to upwelling as was previously hypothesized. Rather, production occurred within a stratified water column, involving specially adapted species in blooms resembling those of the modern North Pacific subtropical gyre, or those indicated for the Mediterranean sapropels. With increased CO(2) levels and warming currently driving increased stratification in the global ocean, this style of production that is adapted to stratification may become more widespread. Our evidence for seasonal diatom production and flux testify to an ice-free summer, but thin accumulations of terrigenous sediment within the diatom ooze are consistent with the presence of intermittent sea ice in the winter, supporting a wide body of evidence for low temperatures in the Late Cretaceous Arctic Ocean, rather than recent suggestions of a 15 degrees C mean annual temperature at this time.

Environmental change during the Late Berriasian - Early Valanginian: a prelude to the late Early Valanginian carbon-isotope event?

NASA Astrophysics Data System (ADS)

Morales, Chloé; Schnyder, Johann; Spangenberg, Jorge; Adatte, Thierry; Westermann, Stephane; Föllmi, Karl

2010-05-01

European basins show that the climate became more humid during the Late Berriasian (Hallam et al., 1991, Schnyder et al., 2009). The aim of this project is to precisely characterize and date paleoenvironmental and paleoclimatic change during the latest Berriasian-Early Valanginian time interval in order to decipher if they can be viewed as precursor events, linked with the late Early Valanginian δ13C event. Three key sections have been studied: Capriolo (N Italy), Montclus (SE France) and Musfallen (E Switzerland) located in the Lombardian and Vocontian basins and on the Helvetic platform, respectively. Phosphorus and stable-isotope analyses have been performed, in addition to clay-mineralogy and facies determinations. The three sections show similar and comparable trends: The phosphorus content (in ppm) is higher in Late Berriasian sediments (compared to Early Berriasian and Valanginian deposits) and this period is also characterised by a decrease in δ13C values. This is interpreted as the result of enhanced continental weathering, which would be coeval with a change to a more humid climate during the Late Berriasian (Schnyder et al., 2009). References: Bornemann, A. and Mutterlose, J. (2008). "Calcareous nannofossil and d13C records from the Early Cretaceous of the Western Atlantic ocean: evidence of enhanced fertilization accross the Berriasian-Valanginian transition." palaios 23: 821-832. Duchamp-Alphonse, S., Gardin, S., Fiet, N., Bartolini, A., Blamart, D. and Pagel, M. (2007). "Fertilization of the northwestern Tethys (Vocontian basin, SE France) during the Valanginian carbon isotope perturbation: Evidence from calcareous nannofossils and trace element data." Palaeogeography, Palaeoclimatology, Palaeoecology 243(1-2): 132-151. Föllmi, K.B., Weissert, H., Bisping, M. & Funk, H. 1994: Phosphogenesis, carbon-isotope stratigraphy, and carbonate-platform evolution along the Lower Cretaceous northern tethyan margin. Geological Society of America, Bulletin 106, 729

Rainfall seasonality on the Indian subcontinent during the Cretaceous greenhouse.

PubMed

Ghosh, Prosenjit; Prasanna, K; Banerjee, Yogaraj; Williams, Ian S; Gagan, Michael K; Chaudhuri, Atanu; Suwas, Satyam

2018-05-31

The Cretaceous greenhouse climate was accompanied by major changes in Earth's hydrological cycle, but seasonally resolved hydroclimatic reconstructions for this anomalously warm period are rare. We measured the δ 18 O and CO 2 clumped isotope Δ 47 of the seasonal growth bands in carbonate shells of the mollusc Villorita cyprinoides (Black Clam) growing in the Cochin estuary, in southern India. These tandem records accurately reconstruct seasonal changes in sea surface temperature (SST) and seawater δ 18 O, allowing us to document freshwater discharge into the estuary, and make inferences about rainfall amount. The same analytical approach was applied to well-preserved fossil remains of the Cretaceous (Early Maastrichtian) mollusc Phygraea (Phygraea) vesicularis from the nearby Kallankuruchchi Formation in the Cauvery Basin of southern India. The palaeoenvironmental record shows that, unlike present-day India, where summer rainfall predominates, most rainfall in Cretaceous India occurred in winter. During the Early Maastrichtian, the Indian plate was positioned at ~30°S latitude, where present-day rainfall and storm activity is also concentrated in winter. The good match of the Cretaceous climate and present-day climate at ~30°S suggests that the large-scale atmospheric circulation and seasonal hydroclimate patterns were similar to, although probably more intense than, those at present.

Hydrocarbons related to early Cretaceous source rocks, reservoirs and seals, trapped in northeastern Neuqun basin, Argentina

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gulisano, C.; Minniti, S.; Rossi, G.

1996-08-01

The Jurassic-Cretaceous backarc Neuqun Basin, located in the west central part of Argentina, is currently the most prolific oil basin of the country. The primary objective of this study is to evaluate an Early Cretaceous to Tertiary petroleum system in the northeastern portion of the basin, where oil and gas occurrences (e.g., Puesto Hernandez, Chihuido de la Sierra Negra, El Trapial and Filo Morado oil fields, among others) provide 82 MMBO/yr comprising 67% of the basin oil production and 31% of Argentina. The source rocks are represented by two thick sections of basinal kerogen type I and II organic-rich shales,more » deposited during transgressive peaks (Agrio Formation), with TOC content up to 5.1%. Lowstand sandstones bodies, 10 to 100 m thick, are composed of eolian and fluvial facies with good reservoir conditions (Avil and Troncoso Sandstones). The seals are provided by the organic-rich shales resting sharply upon the Avil Sandstone and a widespread Aptian-Albian evaporitic event (Huitrin Formation) on top of the Troncoso reservoir. Tertiary structural traps (duplex anticlines) are developed in the outer foothills, whereas structural, combined and stratigraphic traps are present in the adjacent stable structural platform. Oil-to-source rock and oil-to-oil correlation by chromatographic and biomarker fingerprints, carbon isotopic composition and the geological evidences support the proposed oil system.« less

Biofunctionalized 3-D Carbon Nano-Network Platform for Enhanced Fibroblast Cell Adhesion

NASA Astrophysics Data System (ADS)

Chowdhury, A. K. M. Rezaul Haque; Tavangar, Amirhossein; Tan, Bo; Venkatakrishnan, Krishnan

2017-03-01

Carbon nanomaterials have been investigated for various biomedical applications. In most cases, however, these nanomaterials must be functionalized biologically or chemically due to their biological inertness or possible cytotoxicity. Here, we report the development of a new carbon nanomaterial with a bioactive phase that significantly promotes cell adhesion. We synthesize the bioactive phase by introducing self-assembled nanotopography and altered nano-chemistry to graphite substrates using ultrafast laser. To the best of our knowledge, this is the first time that such a cytophilic bio-carbon is developed in a single step without requiring subsequent biological/chemical treatments. By controlling the nano-network concentration and chemistry, we develop platforms with different degrees of cell cytophilicity. We study quantitatively and qualitatively the cell response to nano-network platforms with NIH-3T3 fibroblasts. The findings from the in vitro study indicate that the platforms possess excellent biocompatibility and promote cell adhesion considerably. The study of the cell morphology shows a healthy attachment of cells with a well-spread shape, overextended actin filaments, and morphological symmetry, which is indicative of a high cellular interaction with the nano-network. The developed nanomaterial possesses great biocompatibility and considerably stimulates cell adhesion and subsequent cell proliferation, thus offering a promising path toward engineering various biomedical devices.

Giddings Edwards (Cretaceous) field, south Texas: carbonate channel or elongate buildup

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lomando, A.J.; Mazzullo, S.J.

1989-03-01

Giddings Edwards field, located in Fayette County, Texas, is situated on the broad Cretaceous (Albian) shallow shelf, approximately 20 mi north of the main Edwards shelf-margin reef trend. The Giddings field produces gas from an elongate stratigraphic trap approximately 9.5 mi long and 1.8 mi wide, encased in argillaceous lime mudstones and shales; the field is oriented normal to the contiguous Edwards reef trend. Available cores and cuttings samples from the central portion of the field indicate that the field reservoir is composed of biopackstones and grainstones interpreted to have been deposited in a high-energy shelf environment. The facies systemmore » is characterized by stacked reservoirs having a maximum gross pay thickness of over 100 ft, containing primary interparticle and secondary biomoldic porosity, both of which have been modified slightly by chemical compaction and partial occlusion by sparry calcite and saddle dolomite cements. Despite reasonable subsurface sample and mechanical log control within and surrounding the field, its depositional origin remains equivocal. Such uncertainty has important bearing on predictive models for the exploration for additional Edwards shelfal hydrocarbon reservoirs. The elongate, biconvex geometry of the productive carbonate sands, their northward thinning, and apparent updip bifurcation suggest deposition in a shallow-shelf channel system. By contrast, an alternative correlation and interpretation based on geometry and facies is that of an elongate in-situ carbonate buildup. A number of modern analogs of elongate buildups normal to major reef systems are available from which to compare and model the depositional system of Giddings Edwards field. The evaluation of this field serves as an example of using a multiple working hypothesis to develop an accurate exploration model.« less

Terrestrial biota and climate during Cretaceous greenhouse in NE China

NASA Astrophysics Data System (ADS)

Wan, X.

2016-12-01

Northeast China offers a unique opportunity to perceive Cretaceous stratigraphy and climate of terrestrial settings. The sediments contain variegated clastic and volcanic rocks, diverse terrestrial fossils, and important coal and oil resources. Four Cretaceous biotas of Jehol, Fuxin, Songhuajiang and Jiayin occurred in ascending order. For scientific purpose, a coring program (SK1 & 2) provides significant material for Cretaceous research. The SK1 present a continuous section of Upper Cretaceous non-marine fossil, magnetochron successions and chronostratigraphic events. These chronostratigraphic events are integrated with marine events by an X/Y graphic plot between the core data and a global database of GSSP and key reference sections. More precisely, age interpolation based on CA-ID-TIMS U-Pb zircon dates and the calibrated cyclostratigraphy places the end of the Cretaceous Normal Superchon at 83.07 ±0.15Ma. This date also serves as an estimate for the Santonian-Campanian stage boundary. It also places the K/Pg boundary within the upper part of the Mingshui Formation. The terrestrial and marine life and the analysis of elemental composition, δ13Corg, biomarkers show that lake water salinity changed along with a Coniacian-Santonian marine incursion. High lake-level coincides with the sea transgression during the time. High salinity resulted in the development of periodic anoxic environments of the basin. One of these times of deposition of organic-rich mud correlates with the mangnetochron of C34N/C33R and Coniacian-Santonian planktic foraminifera. This marine flooding correlates with OAE 3 and it is possible that the global oceanic anoxic event may have influenced organic carbon burial in the Songliao Basin for this brief period. The evolution of 4 biotas corresponds to the Cretaceous climate change. We tentatively interpret the terrestrial record to reflect the changes in both global climate and regional basin evolution.

Global research on the Cretaceous

NASA Astrophysics Data System (ADS)

Ginsburg, Robert N.

Cretaceous Resources, Events and Rhythms, a new international research effort on the global aspects of Cretaceous sedimentary geology, is underway. This Global Sedimentary Geology Project (GSGP) is organized by the Commission on Global Sedimentary Geology of the International Union of Geological Sciences (IUGS). The GSGP secretariat is at the University of Miami, Florida (Fisher Island, Miami Beach, FL 33139, tel. 305-672-1840, RNGINSBURG/KOSMOS).Cretaceous time was selected for this pilot research project because Cretaceous sea levels and climates can provide a vision of Earth in its “greenhouse state,” because there is an established geochronology for the era's wide-spread deposits, and because there are extensive resources of hydrocarbons, coal, bauxite and other minerals in Cretaceous rocks.

Kilop Cretaceous Hardground (Kale, Gümüshane, NE Turkey):description and origin

NASA Astrophysics Data System (ADS)

Eren, Muhsin; Tasli, Kemal

2002-06-01

A hardground surface is well exposed in the Kilop area of Kale (Gümüshane, NE Turkey) which forms part of the Eastern Pontides. Here, the hardground is underlain by shallow water Lower Cretaceous limestones, and overlain by Upper Cretaceous red limestones/marls which contains a planktonic microfauna including Globotruncanidae. In the field, the recognition of the hardground is based on the presence of extensive burrows (especially vertical burrows), the encrusting rudistid bivalve Requienia, neptunian-dykes with infills of pelagic sediments and synsedimentary faults. Skolithos and Thalassinoides-type burrows are present. Some burrow walls show iron hydroxide-staining. The extensive burrowing occurred prior to lithification. On the other hand, the neptunian-dykes and synsedimentary faults, which cut the hard ground, occurred after the lithification. These features indicate the progressive hardening of the substrate. The burrowed limestone consists of an intrabioclastic peloidal grainstone which was deposited in an intertidal to shallow, subtidal, moderate to relatively high energy environment. The peloidal limestone shows little or no evidence of submarine cementation, characterized by only scarce relics of isopachous cement rims of bladed calcite spar. The grainstone cement is composed predominantly of blocky calcite and overgrowth calcite cements on the echinoid-fragments. The origin of this cement is controversial. Biostratigraphic analysis of the limestones demonstrates that there is a marked stratigraphic gap (hiatus), spanning the Aptian to the Santonian, in the Cretaceous of the Kilop area. The formation of the Kilop Hardground is related to the break-up and subsidence of the Eastern Pontides carbonate platform during the formation of the Black Sea backarc basin. Hardground development was initiated in a shallow marine environment of slow sedimentation and with moderate to high energy indicating slow subsidence. Later, the hardground subsided abruptly, as

Tracing Carbon Cycling in the Atmosphere and Oceans During the Cretaceous Ocean Anoxic Event 2 (OAE2, 94Ma)

NASA Astrophysics Data System (ADS)

Moran, S. A. M.; Boudinot, F. G.; Dildar, N.; Sepúlveda, J.

2017-12-01

We present a high-resolution record of compound-specific stable carbon isotope data from short-chain—aquatic algae—and long-chain n-alkanes—terrestrial plants—preserved in sedimentary sequences from the Smokey Hollow #1 (SH1) core in the Grand Staircase Escalante National Monument in southern Utah. The study area covered by SH1 core was situated at the western margin of the Western Interior Seaway during the Cretaceous Ocean Anoxic Event (OAE2, 94Ma.), and was characterized by high sedimentation rates and enhanced preservation of both marine and terrestrial organic matter. Short- and long-chain n-alkanes were isolated and purified from branched and cyclic aliphatic hydrocarbons using an optimized urea adduction protocol, and δ13Cn-alkane was measured using a Thermo MAT253 GC-C-IR-MS. We use the δ13Cn-alkane from aquatic and terrestrial sources to better understand carbon cycle interactions in the oceanic and atmospheric carbon pools across this event. Our results indicate that the δ13C of terrestrial plants experienced a faster and more pronounced positive carbon isotope excursion compared to marine sources. We will discuss how these results can inform models of carbon cycle interactions between the ocean and the atmosphere during greenhouse climates, and how they can be used to trace possible sources of CO2.

Chicxulub Impact Crater and Yucatan Carbonate Platform - Stratigraphy and Petrography of PEMEX Borehole Cores

NASA Astrophysics Data System (ADS)

Gutierrez-Cirlos, A. G.; Perez-Drago, G.; Perez-Cruz, L.; Urrutia-Fucugauchi, J.

2008-12-01

Chicxulub impact crater is the best preserved of the three large multi-ring structures documented in the terrestrial record. Chicxulub, formed 65 Ma ago, is associated with the Cretaceous/Tertiary (K/T) boundary layer and the impact related to the organism extinctions and events marking the boundary. The crater is buried under Tertiary sediments in the Yucatan carbonate platform in the southern Gulf of Mexico. The structure was initially recognized from gravity and magnetic anomalies in the PEMEX exploration surveys of the northwestern Yucatan peninsula. The exploration program included eight deep boreholes completed from 1952 through the 1970s. The investigations showing Chicxulub as a large complex impact crater formed at the K/T boundary have relayed on the PEMEX decades-long exploration program. However, despite frequent use of PEMEX information and core samples, significant parts of the database and cores remain to be evaluated, analyzed and incorporated with results from recent efforts. Access to PEMEX Core Repository has permitted to study the cores and collect new samples from some of the boreholes. We analyzed cores from Yucatan-6, Chicxulub-1, Sacapuc-1, Ticul-1, Yucatan-1 and Yucatan-4 boreholes to make new detailed stratigraphic correlations and petrographic characterization, using information from PEMEX database and the recent studies. In C-1 cores, breccias show 4-8 cm clasts of fine grained altered melt dispersed in a medium to coarse grained matrix composed of pyroxene and feldspar with little macroscopic alteration. Clasts contain 0.2 to 0.1 cm fragments of silicate material (basement) that show variable degrees of digestion. Melt samples from C-1 N10 comes from interval 1,393-1,394 m, and show a fine-to-medium grained coherent microcrystalline groundmass. Melt and breccias in Y-6 extend from about 1,100 m to more than 1,400 m. Sequence is well sorted, with an apparent gradation in both the lithic and melt clasts. In this presentation we report on

Geological evolution of the Iraqi Mesopotamia Foredeep, inner platform and near surroundings of the Arabian Plate

NASA Astrophysics Data System (ADS)

Sissakian, Varoujan K.

2013-08-01

source and reservoir rocks in the central and southern parts of Iraq. The Cenozoic sequence consists of Paleogene open marine carbonates, which grades upwards into Neogene lagoonal marine; of Early Miocene and evaporitic rocks; of Middle Miocene age, followed by thick molasses of continental clastics that attain 3500 m in thickness; starting from Late Miocene. The Quaternary sediments are very well developed in the Mesopotamia Plain and they thicken southwards to reach about 180 m near Basra city; in the extreme southeastern part of Iraq. The Iraqi Inner Platform (stable shelf) is a part of the Arabian Plate, being less affected by tectonic disturbances; it covers the area due to south and west of the Euphrates River. The main tectonic feature in this zone that had affected on the geology of the area is the Rutbah Uplift; with less extent is the Ga'ara High. The oldest exposed rocks within the Inner Platform belong to Ga'ara Formation of Permian age; it is exposed only in the Ga'ara Depression. The Permian rocks are overlain by Late Triassic rocks; represented by Mulussa and Zor Hauran formations, both of marine carbonates with marl intercalations. The whole Triassic rocks are absent west, north and east of Ga'ara Depression. Jurassic rocks, represented by five sedimentary cycles, overlie the Triassic rocks. Each cycle consists of clastic rocks overlain by carbonates, being all of marine sediments; whereas the last one (Late Jurassic) consists of marine carbonates only. All the five formations are separated from each other by unconformable contacts. Cretaceous rocks, represented by seven sedimentary cycles, overlie the Jurassic rocks. Marine clastics overlain by marine carbonates. Followed upwards (Late Cretaceous) by continental clastics overlain by marine carbonates; then followed by marine carbonates with marl intercalations, and finally by marine clastics overlain by carbonates; representing the last three cycles, respectively. The Paleocene rocks form narrow belt

Warm Middle Jurassic-Early Cretaceous high-latitude sea-surface temperatures from the Southern Ocean

NASA Astrophysics Data System (ADS)

Jenkyns, H. C.; Schouten-Huibers, L.; Schouten, S.; Sinninghe Damsté, J. S.

2012-02-01

Although a division of the Phanerozoic climatic modes of the Earth into "greenhouse" and "icehouse" phases is widely accepted, whether or not polar ice developed during the relatively warm Jurassic and Cretaceous Periods is still under debate. In particular, there is a range of isotopic and biotic evidence that favours the concept of discrete "cold snaps", marked particularly by migration of certain biota towards lower latitudes. Extension of the use of the palaeotemperature proxy TEX86 back to the Middle Jurassic indicates that relatively warm sea-surface conditions (26-30 °C) existed from this interval (∼160 Ma) to the Early Cretaceous (∼115 Ma) in the Southern Ocean, with a general warming trend through the Late Jurassic followed by a general cooling trend through the Early Cretaceous. The lowest sea-surface temperatures are recorded from around the Callovian-Oxfordian boundary, an interval identified in Europe as relatively cool, but do not fall below 25 °C. The early Aptian Oceanic Anoxic Event, identified on the basis of published biostratigraphy, total organic carbon and carbon-isotope stratigraphy, records an interval with the lowest, albeit fluctuating Early Cretaceous palaeotemperatures (∼26 °C), recalling similar phenomena recorded from Europe and the tropical Pacific Ocean. Extant belemnite δ18O data, assuming an isotopic composition of waters inhabited by these fossils of -1‰ SMOW, give palaeotemperatures throughout the Upper Jurassic-Lower Cretaceous interval that are consistently lower by ∼14 °C than does TEX86 and the molluscs likely record conditions below the thermocline. The long-term, warm climatic conditions indicated by the TEX86 data would only be compatible with the existence of continental ice if appreciable areas of high altitude existed on Antarctica, and/or in other polar regions, during the Mesozoic Era.

Modern sediments and Pleistocene reefs from isolated carbonate platforms (Iles Eparses, SW Indian Ocean): A preliminary study

NASA Astrophysics Data System (ADS)

Jorry, Stéphan J.; Camoin, Gilbert F.; Jouet, Gwénaël; Roy, Pascal Le; Vella, Claude; Courgeon, Simon; Prat, Sophie; Fontanier, Christophe; Paumard, Victorien; Boulle, Julien; Caline, Bruno; Borgomano, Jean

2016-04-01

Isolated carbonate platforms occur throughout the geologic record, from Archean to present. Although the respective roles of tectonics, sediment supply and sea-level changes in the stratigraphical architecture of these systems are relatively well constrained, the details of the nature and controls on the variability of sedimentological patterns between and within individual geomorphologic units on platforms have been barely investigated. This study aims at describing and comparing geomorphological and sedimentological features of surficial sediments and fossil reefs from three isolated carbonate platforms located in the SW Indian Ocean (Glorieuses, Juan de Nova and Europa). These carbonate platforms are relatively small and lack continuous reef margins, which have developed only on windward sides. Field observations, petrographic characterization and grain-size analyses are used to illustrate the spatial patterns of sediment accumulation on these platforms. The internal parts of both Glorieuses and Juan de Nova platforms are blanketed by sand dunes with medium to coarse sands with numerous reef pinnacles. Skeletal components including coral, green algae, and benthic foraminifera fragments prevail in these sediments. Europa platform exhibits a similar skeletal assemblage dominated by coral fragments, with the absence of wave-driven sedimentary bodies. Fossil reefs from the Last interglacial (125,000 years BP) occur on the three platforms. At Glorieuses, a succession of drowned terraces detected on seismic lines is interpreted as reflecting the last deglacial sea-level rise initiated 20,000 years ago. These findings highlight the high potential of these platforms to study past sea-level changes and the related reef response, which remain poorly documented in the SW Indian Ocean.

15N/14N variations in Cretaceous Atlantic sedimentary sequences: implication for past changes in marine nitrogen biogeochemistry

USGS Publications Warehouse

Rau, G.H.; Arthur, M.A.; Dean, W.E.

1987-01-01

At two locations in the Atlantic Ocean (DSDP Sites 367 and 530) early to middle Cretaceous organic-carbon-rich beds ("black shales") were found to have significantly lower ??15N values (lower 15N/14N ratios) than adjacent organic-carbon-poor beds (white limestones or green claystones). While these lithologies are of marine origin, the black strata in particular have ??15N values that are significantly lower than those previously found in the marine sediment record and most contemporary marine nitrogen pools. In contrast, black, organic-carbon-rich beds at a third site (DSDP Site 603) contain predominantly terrestrial organic matter and have C- and N-isotopic compositions similar to organic matter of modern terrestrial origin. The recurring 15N depletion in the marine-derived Cretaceous sequences prove that the nitrogen they contain is the end result of an episodic and atypical biogeochemistry. Existing isotopic and other data indicate that the low 15N relative abundance is the consequence of pelagic rather than post-depositional processes. Reduced ocean circulation, increased denitrification, and, hence, reduced euphotic zone nitrate availability may have led to Cretaceous phytoplankton assemblages that were periodically dominated by N2-fixing blue-green algae, a possible source of this sediment 15N-depletion. Lack of parallel isotopic shifts in Cretaceous terrestrially-derived nitrogen (Site 603) argues that the above change in nitrogen cycling during this period did not extend beyond the marine environment. ?? 1987.

Astrochronology of the Valanginian Stage (Early Cretaceous) : implications for the origin of the Weissert Event

NASA Astrophysics Data System (ADS)

Martinez, Mathieu; Deconinck, Jean-François; Pellenard, Pierre; Reboulet, Stéphane; Riquier, Laurent

2013-04-01

�13C measurements in the Maiolica Formation (Central Italy). By anchoring this proposed astrochronology with available radioisotopic ages for the Berriasian-Hauterivian interval, it appears that the Paraná-Etendeka activity started ~2 myr after the onset of the Weissert Event and therefore can not have induced the carbon-isotope excursion. Instead, following Westermann et al. (2010), we propose that continental carbon organic storage accompanied by carbonate-platform drownings are responsible for the first major carbon-isotope shift of the Cretaceous. Bibliography : Westermann, S., Föllmi, K.B., Adatte, T., Matera, V., Schnyder, J., Fleitmann, D., Fiet, N., Ploch, I., Duchamp-Alphonse, S., 2010. The Valanginian δ13C excrusion may no be an expression of a global oceanic anoxic event. EPSL 290, 118-131.

Imaging of karsts on buried carbonate platform in Central Luconia Province, Malaysia

NASA Astrophysics Data System (ADS)

Nur Fathiyah Jamaludin, Siti; Mubin, Mukhriz; Latiff, Abdul Halim Abdul

2017-10-01

Imaging of carbonate rocks in the subsurface through seismic method is always challenging due to its heterogeneity and fast velocity compared to the other rock types. Existence of karsts features on the carbonate rocks make it more complicated to interpret the reflectors. Utilization of modern interpretation software such as PETREL and GeoTeric® to image the karsts morphology make it possible to model the karst network within the buried carbonate platform used in this study. Using combination of different seismic attributes such as Variance, Conformance, Continuity, Amplitude, Frequency and Edge attributes, we are able to image the karsts features that are available in the proven gas-field in Central Luconia Province, Malaysia. The mentioned attributes are excellent in visualize and image the stratigraphic features based on the difference in their acoustic impedance as well as structural features, which include karst. 2D & 3D Karst Models were developed to give a better understanding on the characteristics of the identified karsts. From the models, it is found that the karsts are concentrated in the top part of the carbonate reservoir (epikarst) and the middle layer with some of them becomes extensive and create karst networks, either laterally or vertically. Most of the vertical network karst are related to the existence of faults that displaced all the horizons in the carbonate platform.

Response of proto-North Atlantic carbonate-platform ecosystems to OAE1a-related stressors

NASA Astrophysics Data System (ADS)

Huck, Stefan; Stein, Melody; Immenhauser, Adrian; Skelton, Peter W.; Christ, Nicolas; Föllmi, Karl B.; Heimhofer, Ulrich

2014-11-01

Integrated biostratigraphic-chemostratigraphic studies provide evidence that the proto-North Atlantic realm witnessed major changes in carbonate platform production in the run-up of the Early Aptian oceanic anoxic event (OAE) 1a. Whereas pervasive growth of Lithocodium microencrusters represents an early harbinger of OAE1a-related environmental perturbation, the subsequent replacement of oligotrophic rudist-coral-nerineid by mesotrophic orbitolinid-oyster communities was clearly associated with the event itself. In order to test the supra-regional relevance of this major community replacement, two shallow-water sections in the southern Lusitanian Basin (Portugal) are investigated by means of geochemistry (carbon and oxygen isotopes), cement petrography and detailed sedimentological analysis. The focus is on a regional, prominent discontinuity surface (S4) at the transition between oligotrophic and mesotrophic carbonate platform production, which might indicate that the major biotic change could have been associated with a phase of non-sedimentation and possibly erosion. The studied sections (São Julião, Crismina) provide evidence that the major Early Aptian biotic turnover was preceded by numerous subordinate but significant changes in platform ecology, which mirrored a series of progressive short-term environmental changes in the course of OAE1. Several transient mass occurrences of orbitolinids indicate repeated phases of ecological stress arguably due to enhanced nutrient input and deepening. Small-scale sea-level changes at parasequence level below the major discontinuity surface are revealed by alternations of rudist assemblages dominated by clinger or recumbent forms as well as intercalated hardground and subaerial exposure stages. Expanded phases of subaerial exposure, however, can be largely ruled out following the geochemical and cement-petrographic data presented here. Enhanced continent-derived siliciclastic input characterising the lower orbitolinid

Functional Carbon Quantum Dots: A Versatile Platform for Chemosensing and Biosensing.

PubMed

Feng, Hui; Qian, Zhaosheng

2018-05-01

Carbon quantum dot has emerged as a new promising fluorescent nanomaterial due to its excellent optical properties, outstanding biocompatibility and accessible fabrication methods, and has shown huge application perspective in a variety of areas, especially in chemosensing and biosensing applications. In this personal account, we give a brief overview of carbon quantum dots from its origin and preparation methods, present some advance on fluorescence origin of carbon quantum dots, and focus on development of chemosensors and biosensors based on functional carbon quantum dots. Comprehensive advances on functional carbon quantum dots as a versatile platform for sensing from our group are included and summarized as well as some typical examples from the other groups. The biosensing applications of functional carbon quantum dots are highlighted from selective assays of enzyme activity to fluorescent identification of cancer cells and bacteria. © 2018 The Chemical Society of Japan & Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Mississippian carbonate buildups and development of cool-waterlike carbonate platforms in the Illinois Basin, Midcontinent U.S.A.

USGS Publications Warehouse

Lasemi, Z.; Norby, R.D.; Utgaard, J.E.; Ferry, W.R.; Cuffey, R.J.; Dever, G.R.

2005-01-01

Numerous biohermal buildups occur in Mississippian (Lower Carboniferous) strata in the Illinois Basin and adjacent regions. They developed as mud mounds, biodetrital calcisiltite mounds, and bryozoan frame thickets (fenestrate-frame coquina or rudstone) during the Kinderhookian and early Meramecian (Tournaisian and early Visean), and as microbial mud mounds, microbial- serpulidbryozoanboundstones, and solenoporoid (red algal) boundstones during the Chesterian (late Visean and Serpukhovian). True Waulsortian mounds did not develop in the Illinois Basin, but echinoderm (primarily crinoids)-bryozoan carbonate banks and bryozoan frame thickets generally occupied the same niche during the Kinderhookian-early Meramecian. Nutrient availability and the resulting increase in the productivity of echinoderms and bryozoans were apparently detrimental to Waulsortian mound development. Deposition of crinoidal-bryozoan carbonates during the Kinderhookian-Osagean initially occurred on a ramp setting that later evolved into a platform with a relatively steep margin through sediment aggradation and progradation. By mid-Osagean-early Meramecian, two such platforms, namely the Burlington Shelf and the Ullin Platform, developed adjacent to a deep, initially starved basin. Sedimentologic and petrographic characteristics of the Kinderhookian-earliest Meramecian carbonates resemble the modern cool-water Heterozoan Association. This is in contrast with post-earliest Meramecian carbonates, which are typically oolitic and peloidal with common peri tidal facies. The post-earliest Meramecian carbonates, therefore, resemble those of the warm-water Photozoan Association. The prevalence of Heterozoan carbonates in the Illinois Basin correlates with a rapid increase in the rate of subsidence and a major second-order eustatic sea-level rise that resulted in deep-water starved basins at this time. In the starved Illinois Basin, deposition was initially limited to a thin phosphatic shale that was

Spatial patterns of diagenesis during geothermal circulation in carbonate platforms

USGS Publications Warehouse

Wilson, A.M.; Sanford, W.; Whitaker, F.; Smart, P.

2001-01-01

Geothermal convection of seawater deep in carbonate platforms could provide the necessary supply of magnesium for dolomitization at temperatures high enough to overcome kinetic limitations. We used reactive-transport simulations to predict the rates and spatial patterns of dolomitization during geothermal convection in a platform that was 40 km across and 2 km thick. In the simulations, porosity and permeability decrease with depth to account for sediment compaction. Dolomitization of a platform consisting of medium grained (???0.05 mm) sediments occurred in a broad band ranging from ???2.5 km depth near the margin to ???1.5 km depth near the platform center. The area of dolomitization is deep enough that temperatures exceed ???50??C but not so deep that low permeabilities restrict mass transport. Complete dolomitization in the center of this zone is estimated to require at least 60 my. Incorporation of permeability contrasts, permeable beds, and reactive beds focused dolomitization strongly and reduced the estimated time required for dolomitization by as much as 50 percent. Dolomitization created magnesium-depleted, calcium-rich fluids in less than 10 ky, and results support a link between dolomitization and anhydrite precipitation where adequate sulfate is available.

Facies analysis of an Upper Jurassic carbonate platform for geothermal reservoir characterization

NASA Astrophysics Data System (ADS)

von Hartmann, Hartwig; Buness, Hermann; Dussel, Michael

2017-04-01

The Upper Jurassic Carbonate platform in Southern Germany is an important aquifer for the production of geothermal energy. Several successful projects were realized during the last years. 3D-seismic surveying has been established as a standard method for reservoir analysis and the definition of well paths. A project funded by the federal ministry of economic affairs and energy (BMWi) started in 2015 is a milestone for an exclusively regenerative heat energy supply of Munich. A 3D-seismic survey of 170 square kilometer was acquired and a scientific program was established to analyze the facies distribution within the area (http://www.liag-hannover.de/en/fsp/ge/geoparamol.html). Targets are primarily fault zones where one expect higher flow rates than within the undisturbed carbonate sediments. However, since a dense net of geothermal plants and wells will not always find appropriate fault areas, the reservoir properties should be analyzed in more detail, e.g. changing the viewpoint to karst features and facies distribution. Actual facies interpretation concepts are based on the alternation of massif and layered carbonates. Because of successive erosion of the ancient land surfaces, the interpretation of reefs, being an important target, is often difficult. We found that seismic sequence stratigraphy can explain the distribution of seismic pattern and improves the analysis of different facies. We supported this method by applying wavelet transformation of seismic data. The splitting of the seismic signal into successive parts of different bandwidths, especially the frequency content of the seismic signal, changed by tuning or dispersion, is extracted. The combination of different frequencies reveals a partition of the platform laterally as well as vertically. A cluster analysis of the wavelet coefficients further improves this picture. The interpretation shows a division into ramp, inner platform and trough, which were shifted locally and overprinted in time by other

System study of the carbon dioxide observational platform system (CO-OPS): Project overview

NASA Technical Reports Server (NTRS)

Stephens, J. Briscoe; Thompson, Wilbur E.

1987-01-01

The resulting options from a system study for a near-space, geo-stationary, observational monitoring platform system for use in the Department of Energy's (DOE) National Carbon Dioxide Observational Platform System (CO-OPS) on the greenhouse effect are discussed. CO-OPS is being designed to operate continuously for periods of up to 3 months in quasi-fixed position over most global regional targets of interest and could make horizon observations over a land-sea area of circular diameter up to about 600 to 800 statute miles. This affords the scientific and engineering community a low-cost means of operating their payloads for monitoring the regional parameters they deem relevant to their investigations of the carbon dioxide greenhouse effect at one-tenth the cost of most currently utilized comparable remote sensing techniques.

An Albian demise of the carbonate platform in the Manín Unit (Western Carpathians, Slovakia)

NASA Astrophysics Data System (ADS)

Fekete, Kamil; Soták, Ján; Boorová, Daniela; Lintnerová, Otília; Michalík, Jozef; Grabowski, Jacek

2017-10-01

The production of platform carbonates of the Manín Unit (Manín Straits, Central Western Carpathians) belonging to the Podhorie and Manín formations and formed by remains of rudists and benthic foraminifers (Urgonian-type carbonates), was previously assumed to terminate during the Aptian. First, we show that these deposits were primarily formed on the upper slope (Podhorie Formation) and in a fore-reef environment (Manín Formation). Second, biostratigraphic data indicate that the shallow-water production persisted up to the Albian, just as it did in another succession of the Manín Unit. The Podhorie Fm contains colomiellids (Colomiella recta, C. mexicana) and calcareous dinoflagellates (Calcisphaerula innominata) that indicate the Albian age. It also contains planktonic foraminifers (Ticinella roberti, Ticinella cf. primula, Ticinella cf. madecassiana, Ticinella cf. praeticinensis) of the Albian Ticinella primula Zone. The Podhorie Formation passes upwards into peri-reefal facies of the Manín Fm where we designate the Malý Manín Member on the basis of rudists shell fragments and redeposited orbitolinids. Microfacies associations share similarities with the Urgonian-type microfacies from Mediterranean Tethys and allow us to restrict the growth and the demise of the carbonate platform. δ13C and δ18O isotopes change over a broad range of both formations: δ13C is in the range +1.03 to +4.20 ‰ V-PDB and δ18O is in the range -0.14 to -5.55 ‰ V-PDB. Although a close correlation between δ13C and δ18O indicates diagenetic overprint, a long-term increase of δ13C can indicate a gradual increase in the aragonite production and/or increasing effects of oceanic water masses in the course of the Albian, prior to the final platform drowning. Carbonate platform evolution was connected with submarine slumps and debris flows leading to redeposition and accumulation of carbonate lithoclasts and bioclastic debris on the slope. Our study confirms that the growth of

Cretaceous rocks from southwestern Montana to southwestern Minnesota, northern Rocky Mountains, and Great Plains

USGS Publications Warehouse

Dyman, T.S.; Cobban, W.A.; Fox, J.E.; Hammond, R.H.; Nichols, D.J.; Perry, W.J.; Porter, K.W.; Rice, D.D.; Setterholm, D.R.; Shurr, G.W.; Tysdal, R.G.; Haley, J.C.; Campen, E.B.

1994-01-01

In Montana, Wyoming, North and South Dakota, and Minnesota, Cretaceous strata are preserved in the asymmetric Western Interior foreland basin. More than 5,200 m (17,000 ft) of Cretaceous strata are present in southwestern Montana, less than 300 m (1,000 ft) in eastern South Dakota. The asymmetry resulted from varying rates of subsidence due to tectonic and sediment loading. The strata consist primarily of sandstone, siltstone, mudstone, and shale. Conglomerate is locally abundant along the western margin, whereas carbonate is present in most areas of the eastern shelf. Sediment was deposited in both marine and nonmarine environments as the shoreline fluctuated during major tectonic and eustatic cycles.A discussion of Cretaceous strata from southwestern to east-central Montana, the Black Hills, eastern South Dakota, and southwestern Minnesota shows regional stratigraphy and facies relations, sequence, boundaries, and biostratigraphic and radiometric correlations. The thick Cretaceous strata in southwestern Montana typify nonmarine facies of the rapidly subsiding westernmost part of the basin. These strata include more than 3,000 m (10,000 ft) of synorogenic conglomerate of the Upper Cretaceous part of the Beaverhead Group. West of the Madison Range, sequence boundaries bracket the Kootenai (Aptian and Albian), the Blackleaf (Albian and Cenomanian), and the Frontier Formations (Cenomanian and Turonian); sequence boundaries are difficult to recognize because the rocks are dominantly non-marine. Cretaceous strata in east-central Montana (about 1,371 m; 4,500 ft thick) lie at the approximate depositional axis of the basin and are mostly marine terrigenous rocks. Chert-pebble zones in these rocks reflect stratigraphic breaks that may correlate with sequence boundaries to the east and west. Cretaceous rocks of the Black Hills region consist of a predominantly marine clastic sequence averaging approximately 1,524 m (5,000 ft) thick. The Cretaceous System in eastern South

Upper Cretaceous (Campanian) phosphorites in Jordan: implications for the formation of a south Tethyan phosphorite giant

NASA Astrophysics Data System (ADS)

Pufahl, Peir K.; Grimm, Kurt A.; Abed, Abdulkader M.; Sadaqah, Rushdi M. Y.

2003-10-01

A record of sedimentary, authigenic, and biological processes are preserved within the Upper Cretaceous (Campanian) Alhisa Phosphorite Formation (AP) in central and northern Jordan. The AP formed near the eastern extremity of the south Tethyan Phosphorite Province (STPP), a carbonate-dominated Upper Cretaceous to Eocene "phosphorite giant" that extends from Colombia, North Africa to the Middle East. Multidisciplinary research of the AP and associated cherts, chalks, and oyster buildups indicate that phosphatic strata formed on a highly productive, storm-dominated, east-west trending epeiric platform along the south Tethyan margin. The onset of phosphogenesis and the accumulation of economic phosphorite coincided with a rise in relative sea level that onlapped peritidal carbonates of the Ajlun Group. Pristine phosphates are associated with well-developed micrite concretionary horizons and contain abundant non-keeled spiral planktic foraminifera and a low diversity benthic assemblage of Buliminacean foraminifera, suggesting that pristine phosphates are a condensed facies and phosphogenesis was stimulated by the effects of a highly productive surface ocean and the suboxic diagenesis of sedimentary organic matter. The bulk sediment composition and absence of Fe-bearing authigenic phases such as glauconite, pyrite (including pyrite molds), siderite, and goethite within pristine phosphates suggests that deposition and authigenesis occurred under conditions of detrital starvation and that "iron-pumping" played a minimal role in phosphogenesis. Authigenic precipitation of phosphate occurred in a broad array of sedimentary environments—herein termed a "phosphorite nursery"—that spanned the entire platform. This is a non-uniformitarian phenomenon reflecting precipitation of sedimentary apatite across a wide depositional spectrum in a variety of depositional settings, wherever the conditions were suitable for phosphogenesis. Sedimentologic data indicate that pristine

Semi-isolated, flat-topped carbonate platform (Oligo-Miocene, Sardinia, Italy): Sedimentary architecture and processes

NASA Astrophysics Data System (ADS)

Andreucci, Stefano; Pistis, Marco; Funedda, Antonio; Loi, Alfredo

2017-11-01

The Chattian-Aquitanian carbonate system of Isili sub-basin (SE Sardinia, Italy) were studied to better understand the hydrodynamic processes controlling the formation of landward-downlapping, rhodolith-rich, giant clinoforms. The studied flat-topped platform was attached to an island (semi-isolated) and migrated onshore (landward) over a shallow marine, protected embayment. The depositional profile is characterized by four, sea to land, zones: seaward slope, flat-topped platform (submerged flat), landward slope and mixed siliciclastic-carbonate embayment. In particular, these zones record different levels, from high to moderate, of hydrodynamic energy and persistency. The paleodepth of the studied succession, based on T/D test on Amphistegina specimens, red-algal genera and geometric reconstruction of the overall system, ranges from - 10 to - 30 m for the platform up to around - 40 m for the landward slope base. Thus, the flat-topped platform was permanently submerged and an extensive carbonate (sea grass, algal and bryozoan-algal) factory along with oyster framestones developed. The widespread presence in the barren zones of rhodolith-to-shell rich small to very small compound dunes (high-energy zone) suggests that the flat-topped platform was periodically swept by unidirectional, landward-directed currents. These currents allow the formation of large-scale, rhodolith-rich clinobeds along the landward slope (washover fan-like system). The presence of rodolith pavements developed along the flat-topped platform at or slightly below the fairweather wave base suggests that clinobeds were formed in a nearshore, shallow subtidal setting. Finally, the shallow marine, protected embayment (moderate-energy zone) represents the widening distal reaches of the currents flowing or along the clinoforms or from the coast basinward (river floods and/or ebb tidal currents). Despite few tidal-related sedimentary structures such as bi-directional ripples and small compound dunes

Masirah Graben, Oman: A hidden Cretaceous rift basin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Beauchamp, W.H.; Ries, A.C.; Coward, M.P.

1995-06-01

Reflection seismic data, well data, geochemical data, and surface geology suggest that a Cretaceous rift basin exists beneath the thrusted allochthonous sedimentary sequence of the Masirah graben, Oman. The Masirah graben is located east of the Huqf uplift, parallel to the southern coast of Oman. The eastern side of the northeast-trending Huqf anticlinorium is bounded by an extensional fault system that is downthrown to the southeast, forming the western edge of the Masirah graben. This graben is limited to the east by a large wedge of sea floor sediments and oceanic crust, that is stacked as imbricate thrusts. These sediments/ophiolitesmore » were obducted onto the southern margin of the Arabian plate during the collision of the Indian/Afghan plates at the end of the Cretaceous. Most of the Masirah graben is covered by an allochthonous sedimentary sequence, which is complexly folded and deformed above a detachment. This complexly deformed sequence contrasts sharply with what is believed to be a rift sequence below the ophiolites. The sedimentary sequence in the Masirah graben was stable until further rifting of the Arabian Sea/Gulf of Aden in the late Tertiary, resulting in reactivation of earlier rift-associated faults. Wells drilled in the Masirah graben in the south penetrated reservoir quality rocks in the Lower Cretaceous Natih and Shuaiba carbonates. Analyses of oil extracted from Infracambrian sedimentary rocks penetrated by these wells suggest an origin from a Mesozoic source rock.« less

Controls on facies and sequence stratigraphy of an upper Miocene carbonate ramp and platform, Melilla basin, NE Morocco

USGS Publications Warehouse

Cunningham, K.J.; Collins, Luke S.

2002-01-01

Upwelling of cool seawater, paleoceanographic circulation, paleoclimate, local tectonics and relative sea-level change controlled the lithofacies and sequence stratigraphy of a carbonate ramp and overlying platform that are part of a temporally well constrained carbonate complex in the Melilla basin, northeastern Morocco. At Melilla, from oldest to youngest, a third-order depositional sequence within the carbonate complex contains (1) a retrogradational, transgressive, warm temperate-type rhodalgal ramp; (2) an early highstand, progradational, bioclastic platform composed mainly of a temperate-type, bivalve-rich molechfor facies; and (3) late highstand, progradational to downstepping, subtropical/tropical-type chlorozoan fringing Porites reefs. The change from rhodalgal ramp to molechfor platform occurred at 7.0??0.14 Ma near the Tortonian/Messinian boundary. During a late stage in the development of the bioclastic platform a transition from temperate-type molechfor facies to subtropical/tropical-type chlorozoan facies occurred and is bracketed by chron 3An.2n (??? 6.3-6.6 Ma). Comparison to a well-dated carbonate complex in southeastern Spain at Cabo de Gata suggests that upwelling of cool seawater influenced production of temperate-type limestone within the ramp and platform at Melilla during postulated late Tortonian-early Messinian subtropical/tropical paleoclimatic conditions in the western Paleo-Mediterranean region. The upwelling of cool seawater across the bioclastic platform at Melilla could be related to the beginning of 'siphoning' of deep, cold Atlantic waters into the Paleo-Mediterranean Sea at 7.17 Ma. The facies change within the bioclastic platform from molechfor to chlorozoan facies may be coincident with a reduction of the siphoning of Atlantic waters and the end of upwelling at Melilla during chron 3An.2n. The ramp contains one retrogradational parasequence and the bioclastic platform three progradational parasequences. Minor erosional surfaces

Linkages Between Cretaceous Forearc and Retroarc Basin Development in Southern Tibet

NASA Astrophysics Data System (ADS)

Orme, D. A.; Laskowski, A. K.

2015-12-01

Integrated provenance and subsidence analysis of forearc and retroarc foreland basin strata were used to reconstruct the evolution of the southern margin of Eurasia during the Early to Late Cretaceous. The Cretaceous-Eocene Xigaze forearc basin, preserved along ~600 km of the southern Lhasa terrane, formed between the Gangdese magmatic arc and accretionary complex as subduction of Neo-Tethyan oceanic lithosphere accommodated the northward motion and subsequent collision of the Indian plate. Petrographic similarities between Xigaze forearc basin strata and Cretaceous-Eocene sedimentary rocks of the northern Lhasa terrane, interpreted as a retroarc foreland basin, were previously interpreted to record N-S trending river systems connecting the retro- and forearc regions during Cretaceous time. New sandstone petrographic and U-Pb detrital zircon provenance analysis of Xigaze forearc basin strata support this hypothesis. Qualitative and statistical provenance analysis using cumulative distribution functions and Kolmogorov-Smirnov (K-S) tests show that the forearc basin was derived from either the same source region as or recycled from the foreland basin. Quartz-rich sandstones with abundant carbonate sedimentary lithic grains and rounded, cobble limestone clasts suggests a more distal source than the proximal Gangdese arc. Therefore, we interpret that the northern Lhasa terrane was a significant source of Xigaze forearc detritus and track spatial and temporal variability in the connection between the retro- and forearc basin systems during the Late Cretaceous. A tectonic subsidence curve for the Xigaze forearc basin shows a steep and "kinked" shape similar to other ancient and active forearc basins. Initial subsidence was likely driven by thermal relaxation of the forearc ophiolite after emplacement while additional periods of rapid subsidence likely result from periods of high flux magmatism in the Gangdese arc and changes in plate convergence rate. Comparison of the

Development of a carbonate platform with potential for large discoveries - an example from Vietnam

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mayall, M.; Bent, A.; Dale, B.

1996-01-01

In offshore central and southern Vietnam a number of carbonate accumulations can be recognized. Platform carbonates form basin-wide units of carbonate characterized by strong, continuous parallel seismic reflectors. Facies are dominated by bioclastic wackestones with poor-moderate reservoir quality. On the more isolated highs, large buildups developed. These are typically 5-10 km across and 300 m thick. They unconformably overlie the platform carbonate facies which are extensively karstified. In places these are pinnacles, typically 2-5 km across, 300 m+ thick with chaotic or mounded internal seismic facies. The large carbonate buildups are characterized by steep sided slopes with talus cones, reef-marginmore » rims usually developed around only part of the buildup, and a prominent back-stepping geometry. Buildup interior facies form the main potential reservoirs They are dominated by fine to coarse grained coralgal packstones. Fine grained carbonates are associated with deeper water events and multiple karst surfaces can also be identified. Reservoir quality is excellent, largely controlled by extensive dissolution and dolomitization believed to be related to the exposure events. Gas has been found in a number of reservoirs. Heterogeneities can be recognized which could potentially effect production. These include the extensive finer grained facies, cementation or open fissures associated with the karst surfaces, a more cemented reef rim, shallowing upwards facies cycles and faults.« less

Development of a carbonate platform with potential for large discoveries - an example from Vietnam

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mayall, M.; Bent, A.; Dale, B.

1996-12-31

In offshore central and southern Vietnam a number of carbonate accumulations can be recognized. Platform carbonates form basin-wide units of carbonate characterized by strong, continuous parallel seismic reflectors. Facies are dominated by bioclastic wackestones with poor-moderate reservoir quality. On the more isolated highs, large buildups developed. These are typically 5-10 km across and 300 m thick. They unconformably overlie the platform carbonate facies which are extensively karstified. In places these are pinnacles, typically 2-5 km across, 300 m+ thick with chaotic or mounded internal seismic facies. The large carbonate buildups are characterized by steep sided slopes with talus cones, reef-marginmore » rims usually developed around only part of the buildup, and a prominent back-stepping geometry. Buildup interior facies form the main potential reservoirs They are dominated by fine to coarse grained coralgal packstones. Fine grained carbonates are associated with deeper water events and multiple karst surfaces can also be identified. Reservoir quality is excellent, largely controlled by extensive dissolution and dolomitization believed to be related to the exposure events. Gas has been found in a number of reservoirs. Heterogeneities can be recognized which could potentially effect production. These include the extensive finer grained facies, cementation or open fissures associated with the karst surfaces, a more cemented reef rim, shallowing upwards facies cycles and faults.« less

Climate change and carbon-cycling during the latest Cretaceous-Early Paleogene; a new 13.5 million year-long, orbital-resolution, stable isotope record from the South Atlantic

NASA Astrophysics Data System (ADS)

Barnet, J.; Littler, K.; Kroon, D.; Leng, M. J.; Westerhold, T.; Roehl, U.; Zachos, J. C.

2017-12-01

The "greenhouse" world of the latest Cretaceous-Early Paleogene ( 70-34 Ma) was characterised by multi-million year variability in climate and the carbon-cycle. Throughout this interval the pervasive imprint of orbital-cyclicity, particularly eccentricity and precession, is visible in elemental and stable isotope data obtained from multiple deep-sea sites. Periodic "hyperthermal" events, occurring largely in-step with these orbital cycles, have proved particularly enigmatic, and may be the closest, albeit imperfect, analogues for anthropogenic climate change. This project utilises CaCO3-rich marine sediments recovered from ODP Site 1262 at a paleo-depth of 3600 m on the Walvis Ridge, South Atlantic, of late Maastrichtian-mid Paleocene age ( 67-60 Ma). We have derived high-resolution (2.5-4 kyr) carbon and oxygen isotope data from the epifaunal benthic foraminifera species Nuttallides truempyi. Combining the new record with the existing Late Paleocene-Early Eocene record generated from the same site by Littler et al. (2014), yields a single-site reference curve detailing 13.5 million years of orbital cyclicity in paleoclimate and carbon cycle from the latest Cretaceous to near the peak warmth of the Early Paleogene greenhouse. Spectral analysis of this new combined dataset allows us to identify long (405-kyr) eccentricity, short (100-kyr) eccentricity, and precession (19-23-kyr) as the principle forcing mechanisms governing pacing of the background climate and carbon-cycle during this time period, with a comparatively weak obliquity (41-kyr) signal. Cross-spectral analysis suggests that changes in climate lead the carbon cycle throughout most of the record, emphasising the role of the release of temperature-sensitive carbon stores as a positive feedback to an initial warming induced by changes in orbital configuration. The expression of comparatively understudied Early Paleocene events, including the Dan-C2 Event, Latest Danian Event, and Danian/Selandian Transition

Source rock potential of middle cretaceous rocks in Southwestern Montana

USGS Publications Warehouse

Dyman, T.S.; Palacas, J.G.; Tysdal, R.G.; Perry, W.J.; Pawlewicz, M.J.

1996-01-01

The middle Cretaceous in southwestern Montana is composed of a marine and nonmarine succession of predominantly clastic rocks that were deposited along the western margin of the Western Interior Seaway. In places, middle Cretaceous rocks contain appreciable total organic carbon (TOC), such as 5.59% for the Mowry Shale and 8.11% for the Frontier Formation in the Madison Range. Most samples, however, exhibit less than 1.0% TOC. The genetic or hydrocarbon potential (S1+S2) of all the samples analyzed, except one, yield less than 1 mg HC/g rock, strongly indicating poor potential for generating commercial amounts of hydrocarbons. Out of 51 samples analyzed, only one (a Thermopolis Shale sample from the Snowcrest Range) showed a moderate petroleum potential of 3.1 mg HC/g rock. Most of the middle Cretaceous samples are thermally immature to marginally mature, with vitrinite reflectance ranging from about 0.4 to 0.6% Ro. Maturity is high in the Pioneer Mountains, where vitrinite reflectance averages 3.4% Ro, and at Big Sky Montana, where vitrinite reflectance averages 2.5% Ro. At both localities, high Ro values are due to local heat sources, such as the Pioneer batholith in the Pioneer Mountains.

Environmental drivers of crocodyliform extinction across the Jurassic/Cretaceous transition

PubMed Central

Mannion, Philip D.; Upchurch, Paul

2016-01-01

Crocodyliforms have a much richer evolutionary history than represented by their extant descendants, including several independent marine and terrestrial radiations during the Mesozoic. However, heterogeneous sampling of their fossil record has obscured their macroevolutionary dynamics, and obfuscated attempts to reconcile external drivers of these patterns. Here, we present a comprehensive analysis of crocodyliform biodiversity through the Jurassic/Cretaceous (J/K) transition using subsampling and phylogenetic approaches and apply maximum-likelihood methods to fit models of extrinsic variables to assess what mediated these patterns. A combination of fluctuations in sea-level and episodic perturbations to the carbon and sulfur cycles was primarily responsible for both a marine and non-marine crocodyliform biodiversity decline through the J/K boundary, primarily documented in Europe. This was tracked by high extinction rates at the boundary and suppressed origination rates throughout the Early Cretaceous. The diversification of Eusuchia and Notosuchia likely emanated from the easing of ecological pressure resulting from the biodiversity decline, which also culminated in the extinction of the marine thalattosuchians in the late Early Cretaceous. Through application of rigorous techniques for estimating biodiversity, our results demonstrate that it is possible to tease apart the complex array of controls on diversification patterns in major archosaur clades. PMID:26962137

Sedimentology and carbon-isotope stratigraphy of the Late Cretaceous Chalk Group in the Höllviken-1 core (SW Sweden)

NASA Astrophysics Data System (ADS)

Bøttger, Dorthe; Thibault, Nicolas; Anderskouv, Kresten

2016-04-01

The Höllviken-1 borehole is situated on the Skåne peninsula (SW Sweden) which was part of the Danish Basin in the Late Cretaceous. 1415 meters have been cored among which ca. 1100 meters cover the complete Upper Cretaceous to lower Danian Chalk Group. Besides the publication of a synthetic log and detailed foraminifer biozonation, supplemented by a number of rare macrofossil findings and description of a number of foraminifer holotypes (Brötzen, 1944), very few studies of the core have actually been performed, since the mid 1940s. A new project has thus been undertaken aiming at improving the stratigraphy of the Chalk Group in the Höllviken-1 core. The data presented here comprise the description of the interval 837-489 m covering a large part of the Campanian and the lower Maastrichtian. Two intervals with the presence of sand are noted in the Campanian and two intervals showing possibly progradational sequences of arenaceous marls to sand are present in the Maastrichtian. The purpose of this new study is to revise the foraminifer biostratigraphy of Brötzen and complement it with high-resolution carbon-isotope stratigraphy in order to establish a new age-model for the core and better constrain the timing of siliciclastic input into the Danish Basin. In addition, high-resolution sedimentological data will be used as a preliminary test for cyclostratigraphy of the chalk-marl intervals.

Vertically Aligned Carbon Nanofiber based Biosensor Platform for Glucose Sensor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Al Mamun, Khandaker A.; Tulip, Fahmida S.; MacArthur, Kimberly

2014-03-01

Vertically aligned carbon nanofibers (VACNFs) have recently become an important tool for biosensor design. Carbon nanofibers (CNF) have excellent conductive and structural properties with many irregularities and defect sites in addition to exposed carboxyl groups throughout their surfaces. These properties allow a better immobilization matrix compared to carbon nanotubes and offer better resolution when compared with the FET-based biosensors. VACNFs can be deterministically grown on silicon substrates allowing optimization of the structures for various biosensor applications. Two VACNF electrode architectures have been employed in this study and a comparison of their performances has been made in terms of sensitivity, sensingmore » limitations, dynamic range, and response time. The usage of VACNF platform as a glucose sensor has been verified in this study by selecting an optimum architecture based on the VACNF forest density. Read More: http://www.worldscientific.com/doi/abs/10.1142/S0129156414500062« less

New Evidence for opening of the Black Sea; U-Pb analysis of detrital zircons and paleocurrent measurements of the Early Cretaceous turbidites

NASA Astrophysics Data System (ADS)

Akdoğan, Remziye; Okay, Aral I.; Sunal, Gürsel; Tari, Gabor; Kylander-Clark, Andrew R. C.

2015-04-01

Shelf to submarine turbidite fan deposits of the Early Cretaceous crop out over a large area along the southern coast of the Black Sea. Early Cretaceous turbidites have a thickness of over 2000 meters in the Central Pontides. The shelf of this turbidite basin, represented by shallow marine clastics and carbonates, crops out along the Black Sea coast between Zonguldak and Amasra. Paleocurrent directions in the Lower Cretaceous turbidites were measured in 90 localities using mostly flute and groove casts and to a lesser extend cross-beds. At the eastern part of the basin, the paleocurrents were from north to south. It is scattered in the west of the basin, however, the main paleocurrent directions were from the north. Detrital zircons were analyzed using LA-ICP-MS in eleven samples from the turbiditic sandstones and two samples from the shelf sandstones. Four samples are from the western part (two samples from shelf sediments), four samples from the central part and five samples from the eastern part of the Lower Cretaceous basin. 1085 of 1348 zircon analyses are concordant with rates of 95-105% and the zircon ages range between 141 ± 4 Ma (Berriasian) and 3469 ± 8 Ma (Paleoarchean). 22% of the detrital zircon ages are Paleoproterozoic, 20% Archean, 16% Carboniferous, 13% Neoproterozoic, 8% Permian, 6% Triassic, 5% Mesoproterozoic and 11% other ages. In the western part of the basin the Carboniferous zircons constitute the main population with a less dominant peak at Ordovician, Cambrian and Late Neoproterozoic. The zircons from the center of the basin show scattered distribution with dominant populations in the Triassic, Permian, Carboniferous, Silurian, Paleoproterozoic, Early Neoproterozoic-Late Mesoproterozoic, and minor peak at Late Neoarchean. On the other hand, zircons from the eastern most part of the basin, show dominant peaks in the Paleoproterozoic, Mesoarchean and Permian with minor peaks in Triassic, Carboniferous and Silurian. Anatolia and the Balkans

What controls diffuse fractures in platform carbonates? Insights from Provence (France) and Apulia (Italy)

NASA Astrophysics Data System (ADS)

Lavenu, Arthur P. C.; Lamarche, Juliette

2018-03-01

Fractures are widespread in rocks and regional opening-mode arrays are commonly ascribed to major tectonic events. However, fractures occur in otherwise undeformed rocks. Some of these are early-developed features independent of tectonics and forming a background network at regional scale. To overcome this lack of understanding, two hydrocarbon reservoir analogues from platform carbonates have been targeted: the Provence (SE France), and the Apulian platform (SE Italy). In both areas, an early fracturing stage has been observed, made of high-angle-to-bedding opening-mode fractures, and bed-parallel stylolites. These features developed synchronously during the first burial stages and prior to major tectonic events. The fracture sets are not genetically related to the present-day layering. Contrarily, fractures developed in a brittle media where facies transitions were not sharp and did not act as mechanical discontinuities. Carbonate facies distribution and early diagenetic imprint constrained the mechanical stratigraphy when fractures occurred. In addition, we observed that fractures related to late tectonic inversion were partly inhibited. Indeed, rock mechanical properties change through time. Characterizing the temporal evolution of carbonate rocks has revealed that diagenesis and sedimentary facies are the prime actors for brittleness and mechanical layering in carbonates.

An atmospheric pCO2 reconstruction across the Cretaceous-Tertiary boundary from leaf megafossils

PubMed Central

Beerling, D. J.; Lomax, B. H.; Royer, D. L.; Upchurch, G. R.; Kump, L. R.

2002-01-01

The end-Cretaceous mass extinctions, 65 million years ago, profoundly influenced the course of biotic evolution. These extinctions coincided with a major extraterrestrial impact event and massive volcanism in India. Determining the relative importance of each event as a driver of environmental and biotic change across the Cretaceous-Tertiary boundary (KTB) crucially depends on constraining the mass of CO2 injected into the atmospheric carbon reservoir. Using the inverse relationship between atmospheric CO2 and the stomatal index of land plant leaves, we reconstruct Late Cretaceous-Early Tertiary atmospheric CO2 concentration (pCO2) levels with special emphasis on providing a pCO2 estimate directly above the KTB. Our record shows stable Late Cretaceous/Early Tertiary background pCO2 levels of 350–500 ppm by volume, but with a marked increase to at least 2,300 ppm by volume within 10,000 years of the KTB. Numerical simulations with a global biogeochemical carbon cycle model indicate that CO2 outgassing during the eruption of the Deccan Trap basalts fails to fully account for the inferred pCO2 increase. Instead, we calculate that the postboundary pCO2 rise is most consistent with the instantaneous transfer of ≈4,600 Gt C from the lithic to the atmospheric reservoir by a large extraterrestrial bolide impact. A resultant climatic forcing of +12 W⋅m−2 would have been sufficient to warm the Earth's surface by ≈7.5°C, in the absence of counter forcing by sulfate aerosols. This finding reinforces previous evidence for major climatic warming after the KTB impact and implies that severe and abrupt global warming during the earliest Paleocene was an important factor in biotic extinction at the KTB. PMID:12060729

Discordant mid-Cretaceous paleomagnetic pole from the Zaza Terrane of central Cuba

DOE Office of Scientific and Technical Information (OSTI.GOV)

Renne, P.R.; Doppelhammer, S.K.; Hargraves, R.B.

Thermal demagnetization of samples from five sites in mid-Cretaceous volcaniclastic and carbonate rocks of south-central Cuba reveals two or more components of magnetization. A pre-folding magnetite borne component is recognized in all, but was difficult to isolate from secondary components in many specimens. Remagnetization circle analysis, using data for 42 specimens from all five sites, yields a pole at 30.7{degree}N Lat., 193.3{degree}E Long. This pole is discordant with respect to the North American APWP, indicating 43{degree} {plus minus} 16{degree} of anticlockwise rotation and 8{degree} {plus minus} 6{degree} of northward displacement since the mid-Cretaceous. This result suggests that part or allmore » of Cuba was transported on the Caribbean plate before accretion to North America in the Eocene.« less

Response of shallow-water carbonates and reef systems to the Toarcian Ocean Anoxic Event (183 Ma) on the Dinaric Carbonate Platform (Slovenia)

NASA Astrophysics Data System (ADS)

Martindale, R. C.; Kosir, A.; Schaller, M. F.

2015-12-01

With rising concerns regarding the persistence of coral reefs through the 21st century, there is a crucial need to understand how these ecosystems will respond to future environmental deterioration (e.g. ocean warming, acidification, and decreased oxygenation). Several ancient events have been identified as good analogues for modern ecological changes, however, most of these correspond to mass extinction events. By studying carbon cycle perturbations that caused more minor ecosystem collapse, such as the Toarcian Ocean Anoxic Event (T-OAE), the key physiological, ecological, and environmental features that correlate with species and community survival can be assessed. The Dinaric Carbonate Platform, which extends from northeastern Italy to northwestern Albania, is one of the few platforms in Europe that captures an almost continuous shallow-water record of Pliensbachian and Toarcian strata. Specifically, this comparatively poorly studied platform captures the T-OAE in shallow-water carbonates. One such outcrop on the Trnovski Gozd karst plateau in western Slovenia contains both Pleinsbachian lithiotid (bivalve) biostromes and coral bioherms (i.e. coral reefs). The occurrence of both lithiotid and coral buildups in one section is extremely rare and provides the opportunity to study the response of both communities, as well as the carbonate system as a whole, to the T-OAE. This research focuses on the lithology and chemostratigraphy from this locality, particularly identifying the T-OAE horizon more precisely. Additionally, (micro)facies analyses and paleontological analyses of the reefs themselves will be presented. These data will establish the paleoenvironmental conditions that favored reef growth in the Pliensbachian, as well as what conditions changed at the stage boundary and T-OAE to cause the collapse of the shallow-water carbonates and reef systems.

Severity of ocean acidification following the end-Cretaceous asteroid impact

PubMed Central

Tyrrell, Toby; Armstrong McKay, David Ian

2015-01-01

Most paleo-episodes of ocean acidification (OA) were either too slow or too small to be instructive in predicting near-future impacts. The end-Cretaceous event (66 Mya) is intriguing in this regard, both because of its rapid onset and also because many pelagic calcifying species (including 100% of ammonites and more than 90% of calcareous nannoplankton and foraminifera) went extinct at this time. Here we evaluate whether extinction-level OA could feasibly have been produced by the asteroid impact. Carbon cycle box models were used to estimate OA consequences of (i) vaporization of up to 60 × 1015 mol of sulfur from gypsum rocks at the point of impact; (ii) generation of up to 5 × 1015 mol of NOx by the impact pressure wave and other sources; (iii) release of up to 6,500 Pg C as CO2 from vaporization of carbonate rocks, wildfires, and soil carbon decay; and (iv) ocean overturn bringing high-CO2 water to the surface. We find that the acidification produced by most processes is too weak to explain calcifier extinctions. Sulfuric acid additions could have made the surface ocean extremely undersaturated (Ωcalcite <0.5), but only if they reached the ocean very rapidly (over a few days) and if the quantity added was at the top end of literature estimates. We therefore conclude that severe ocean acidification might have been, but most likely was not, responsible for the great extinctions of planktonic calcifiers and ammonites at the end of the Cretaceous. PMID:25964350

Severity of ocean acidification following the end-Cretaceous asteroid impact.

PubMed

Tyrrell, Toby; Merico, Agostino; Armstrong McKay, David Ian

2015-05-26

Most paleo-episodes of ocean acidification (OA) were either too slow or too small to be instructive in predicting near-future impacts. The end-Cretaceous event (66 Mya) is intriguing in this regard, both because of its rapid onset and also because many pelagic calcifying species (including 100% of ammonites and more than 90% of calcareous nannoplankton and foraminifera) went extinct at this time. Here we evaluate whether extinction-level OA could feasibly have been produced by the asteroid impact. Carbon cycle box models were used to estimate OA consequences of (i) vaporization of up to 60 × 10(15) mol of sulfur from gypsum rocks at the point of impact; (ii) generation of up to 5 × 10(15) mol of NOx by the impact pressure wave and other sources; (iii) release of up to 6,500 Pg C as CO2 from vaporization of carbonate rocks, wildfires, and soil carbon decay; and (iv) ocean overturn bringing high-CO2 water to the surface. We find that the acidification produced by most processes is too weak to explain calcifier extinctions. Sulfuric acid additions could have made the surface ocean extremely undersaturated (Ωcalcite <0.5), but only if they reached the ocean very rapidly (over a few days) and if the quantity added was at the top end of literature estimates. We therefore conclude that severe ocean acidification might have been, but most likely was not, responsible for the great extinctions of planktonic calcifiers and ammonites at the end of the Cretaceous.

High Arctic paleoenvironmental and Paleoclimatic changes in the Mid-Cretaceous

NASA Astrophysics Data System (ADS)

Herrle, Jens; Schröder-Adams, Claudia; Selby, David; Du Vivier, Alice; Flögel, Sascha; McAnena, Alison; Davis, William; Pugh, Adam; Galloway, Jennifer; Hofmann, Peter; Wagner, Thomas

2014-05-01

Although major progress in Cretaceous (145-66 Ma) paleoclimate and paleoceanography has been made during the last decades (e.g., Hay, 2008, 2011; Föllmi, 2012 and references therein), our knowledge of high latitudinal environmental change remains largely unknown compared to low- and mid-latitude marine and terrestrial environments. Drilling the Arctic Ocean remains challenging and expensive, whereas the Sverdrup Basin provides excellent exposures on land. To fully understand the climate and paleoceanographic dynamics of the warm, equable greenhouse world of the Cretaceous Period it is important to determine polar paleotemperatures and to study paleoceanographic changes in a well-established and continuous bio- and chemostratigraphic context. Exceptional exposures of Cretaceous sediments on the central to southern part of Axel Heiberg Island at a Cretaceous paleolatitude of about 71°N (Tarduno et al., 1998) provide a unique window on the Cretaceous Arctic paleoenvironment and climate history (Schröder-Adams et al., 2014). Here we present high-resolution records combining sedimentological studies, U-Pb zircon geochronology, marine organic carbon isotopes and initial 187Os/188Os data, TEX86-derived sea-surface temperatures (SST) and climate modelling, that constrain the timing and magnitude of major Oceanic Anoxic Events (OAEs) and climate events constructed from a ~1.8 km sedimentary succession exposed on Axel Heiberg and Ellef Ringnens islands in the Canadian Arctic Archipelago. The first high latitude application of initial 187Os/188Os data are agreeable with global profiles (Du Vivier et al., 2014) indicating the widespread magmatic pulse of the Caribbean Large Igneous Province (LIP) at the onset of OAE2 but also record the emplacement of local High Arctic LIP prior to the OAE2 in the Sverdrup Basin. Initial SST data suggest a slightly lower meridional temperature gradient during the Middle/Late Albian compared to present and a similar to the present one during

Significance of the giant Lower Cretaceous paleoweathering event

NASA Astrophysics Data System (ADS)

Thiry, Médard; Ricordel-Prognon, Caroline; Schmitt, Jean-Michel

2010-05-01

Weathering profiles typically develop at the interface with the atmosphere, and thus, record the fluctuations in the paleoatmosphere's chemistry and climatic conditions. Consequently they are one of the main archives to upgrade our understanding on paleoclimate and the Earth's environmental history. In this presentation, we will focus on the linking between paleoatmosphere compositions, weathering rates, and their impact on the subsequent sedimentary records. Distribution of the Lower Cretaceous lateritic weathering facies. During the Early Cretaceous, sea level drops and wide exondations lead to development of deep "lateritic" weathering profiles. Thick kaolinitic weathering profiles occured on the Hercynian basements and diverse kaolinitic and ferruginous weathering products covered the Jurassic limestone platforms. This major lateritic event is not restricted to Europe but also well know in North-America (up to Canada), South-America (down to Argentina), and in Australia. Moreover, recent paleomagnetic and radiometric datations revealed that numerous kaolinitic and ferruginous formations, which classically were ascribed to Tertiary ages, date back to the Lower Cretaceous period (Thiry et al., 2006). Additionally, the Bonherz iron ore deposits in the paleokarsts of the Jurassic limestone plateform of the Paris Basin also have to be reconsidered as of Cretaceous age, probably as well as the Tertiary age of the Swiss and Bavarian Jura Bonherz. Paleoclimatic interpretation. During a long time, the interpretation of these paleoweathering features has been a major palaeoclimatic argument. The spreading out of deep kaolinitic weathering profiles (from the Scandinavian and Canadian shields to southern Argentina and Australia, which was still situated close to Antarctica at that time) has lead to considerations, that during this period a warm and wet climate prevailed globally, with very little latitudinal differentiation. These paleoclimatic interpretations stand in

Cretaceous polar climates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ziegler, A.M.; Horrell, M.A.; Lottes, A.L.

1988-02-01

The Cretaceous, like most Phanerozoic periods, was characterized by ice-free poles. Some still argue that the glaciers and sea ice were there, and that the tillites, etc, have been eroded or remain undiscovered. However, diverse floras, dense forests, and coal-forming cypress swamps, and dinosaurs, crocodilians, and lungfish are known from areas that were certainly at 75/degree/-80/degree/ north and south paleolatitude in the Cretaceous, implying that the coastal basins did not experience hard freezes. No deep marine connections to the North Pole existed in the Cretaceous, so oceanic polar heat transport can be discounted. However, the five north-south trending epeiric ormore » rift-related seaways that connected or nearly connected the Tethys to the Arctic would have dampened the seasonal temperature cycle, bring maritime climates deep into the North American and Eurasian continents and, more importantly, would have served as an energy source and channel for winter storms, much as the Gulf Stream does today. Cyclones have a natural tendency to move poleward, because of the increase in the Coriolis Parameter, and they transport both sensible and latent heat. The coastal regions of the relatively warm polar ocean in the Cretaceous would have received continuous precipitation during the winter because cyclones would be entering from as many as five directions. Coastal rainfall would also have been abundant in the summer but for a different reason; the land-sea temperature profile would reverse, with the warm land surface drawing in moisture, while clear ice-free conditions over the ocean would allow for solar warming.« less

Cretaceous polar climates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ziegler, A.M.; Horrell, M.A.; Lottes, A.L.

1988-01-01

The Cretaceous, like most Phanerozooic periods, was characterized by ice-free poles. Some still argue that the glacier and sea ice were there, and that the tillites, etc, have been eroded or remain undiscovered. However, diverse floras, dense forests, coal-forming cypress swamps, and dinosaurs, crocodilians, and lungfish are known from areas that were certainly at 75/sup 0/-80/sup 0/ north and south paleolatitude in the Cretaceous, implying that the coastal basins did not experience hard freezes. No deep marine connections to the North Pole existed in the Cretaceous, so oceanic polar heat transport can be discounted. However, the five north-south trending epeiricmore » or rift-related seaways that connected or nearly connected the Tethys to the Arctic would have dampened the seasonal temperature cycle, bringing maritime climates deep into the North American and Eurasian continents and, more importantly, would have served as an energy source and channel for winter storms, much as the Gulf Stream does today. Cyclones have a natural tendency to move poleward, because of the increase in the Coriolis Paramteter, and they transport both sensible and latent heat. The coastal regions of the relatively warm polar ocean in the Cretaceous would have received continuous precipitation during the winter because cyclones would be entering from as many as five directions. Coastal rainfall would also have been abundant in the summer but for a different reason; the land-sea temperature profile would reverse, with the warm land surface drawing in moisture, while clear ice-free conditions over the ocean would allow for solar warming.« less

A microfluidic chip platform with electrochemical carbon nanotube electrodes for pre-clinical evaluation of antibiotics nanocapsules.

PubMed

Hong, Chien-Chong; Wang, Chih-Ying; Peng, Kuo-Ti; Chu, I-Ming

2011-04-15

This paper presents a microfluidic chip platform with electrochemical carbon nanotube electrodes for preclinical evaluation of antibiotics nanocapsules. Currently, there has been an increasing interest in the development of nanocapsules for drug delivery applications for localized treatments of diseases. So far, the methods to detect antibiotics are liquid chromatography (LC), high performance liquid chromatography (HPLC), mass spectroscopy (MS). These conventional instruments are bulky, expensive, not ease of access, and talented operator required. In order to help the development of nanocapsules and understand drug release profile before planning the clinical experiments, it is important to set up a biosensing platform which could monitor and evaluate the real-time drug release profile of nanocapsules with high sensitivity and long-term measurement ability. In this work, a microfluidic chip platform with electrochemical carbon nanotube electrodes has been developed and characterized for rapid detection of antibiotics teicoplanin nanocapsules. Multi-walled carbon nanotubes are used to modify the gold electrode surfaces to enhance the performance of the electrochemical biosensors. Experimental results show that the limit of detection of the developed platform using carbon nanotubes electrodes is 0.1 μg/ml with a linear range from 1 μg/ml to 10 μg/ml. The sensitivity of the developed system is 0.023 mA ml/μg at 37°C. The drug release profile of teicoplanin nanocapsules in PBS shows that the antibiotics nanocapsules significantly increased the release of drug on the 4th day, measuring 0.4858 μg/(ml hr). The release of drug from the antibiotics nanocapsules reached 34.98 μg/ml on the 7th day. The results showed a similar trend compared with the measurement result using the HPLC instrument. Compared with the traditional HPLC measurements, the electrochemical sensing platform we developed measures results with increased flexibility in controlling experimental

Evaluating Late Cretaceous OAEs and the influence of marine incursions on organic carbon burial in an expansive East Asian paleo-lake

NASA Astrophysics Data System (ADS)

Jones, Matthew M.; Ibarra, Daniel E.; Gao, Yuan; Sageman, Bradley B.; Selby, David; Chamberlain, C. Page; Graham, Stephan A.

2018-02-01

Expansive Late Cretaceous lacustrine deposits of East Asia offer unique stratigraphic records to better understand regional responses to global climate events, such as oceanic anoxic events (OAEs), and terrestrial organic carbon burial dynamics. This study presents bulk organic carbon isotopes (δ13Corg), elemental concentrations (XRF), and initial osmium ratios (187Os/188Os, Osi) from the Turonian-Coniacian Qingshankou Formation, a ∼5 Ma lacustrine mudstone succession in the Songliao Basin of northeast China. A notable δ13Corg excursion (∼ + 2.5‰) in organic carbon-lean Qingshankou Members 2-3 correlates to OAE3 in the Western Interior Basin (WIB) of North America within temporal uncertainty of high-precision age models. Decreases in carbon isotopic fractionation (Δ13C) through OAE3 in the WIB and Songliao Basin, suggest that significantly elevated global rates of organic carbon burial drew down pCO2, likely cooling climate. Despite this, Osi chemostratigraphy demonstrates no major changes in global volcanism or weathering trends through OAE3. Identification of OAE3 in a lake system is consistent with lacustrine records of other OAEs (e.g., Toarcian OAE), and underscores that terrestrial environments were sensitive to climate perturbations associated with OAEs. Additionally, the relatively radiogenic Osi chemostratigraphy and XRF data confirm that the Qingshankou Formation was deposited in a non-marine setting. Organic carbon-rich intervals preserve no compelling Osi evidence for marine incursions, an existing hypothesis for generating Member 1's prolific petroleum source rocks. Based on our results, we present a model for water column stratification and source rock deposition independent of marine incursions, detailing dominant biogeochemical cycles and lacustrine organic carbon burial mechanisms.

Sedimentology of Upper Cretaceous Coffee sands in north-central Mississippi

DOE Office of Scientific and Technical Information (OSTI.GOV)

Webb, E.J.

1984-09-01

The Upper Cretaceous Coffee Group within the Desha basin of Mississippi is composed of two major lithologies, a light to dark marlstone and a series of white, fine to medium-grained siltstones and sandstones. The two source areas for the sands are the Sharkey platform to the south and the southern Appalachians. The presence of hydrocarbons has been described at the outcrop and in subsurface cuttings and cores. Depositional environments in the shallow shelf consist of lagoons, barrier island bars, offshore bars, and surge channel deposits. Southwest regional dip of approximately 40 ft/mi (8 m/km) is reflected on all Upper Cretaceousmore » horizons.« less

Sedimentology and stratigraphy of the middle Eocene Guara carbonate platform near Arguis, South-West Pyrenean foreland: Implications for basin physiography

NASA Astrophysics Data System (ADS)

Huyghe, D.; Castelltort, S.; Serra-Kiel, J.; Filleaudeau, P.-Y.; Emmanuel, L.; Mouthereau, F.; Renard, M.

2009-04-01

The Pyrenees results from the collision between Spain and Europe and developed between the upper Cretaceous (Santonian) and the Miocene. Its foreland basins are characterised by a thick fill of detrital and carbonate sediments. The diversity of Eocene deposits in the southern Pyrenean foreland basin is of particular use in facies sedimentology due to their exceptional outcropping quality and well established stratigraphic framework and has been taken as type examples of many different sedimentary environments. Most studies have concerned facies sedimentology of detrital series in turbiditic environments, meandering and braided rivers, alluvial fans, and deltas. In contrast, the Eocene carbonate series have attracted less attention. The marine Guara limestones are a formation of lower to middle Eocene age deposited on the southern border of the western Pyrenean foreland basin (Jaca basin). They were deposited as a retrogradational carbonate platform dominated by large benthic foraminifers near or at the flexural forebulge of the foreland basin as the Pyrenean orogen developed. This formation represents the last episode of carbonate platform in the Pyrenees and remains poorly studied. In the present work our aim is to provide a detailed facies analysis and physiographic reconstructions of the Guara carbonate platform. This is crucial to unravel the respective influences of tectonics, climate and rheology of the lithosphere on the foreland basin tectonic and stratigraphic development, and it brings new constraints on the paleoenvironments and paleogeography during the Lutetian, i.e. at the beginning of the major phase of activity of the Pyrenean orogenesis. Two outcrops were studied in the Sierras Marginales at the localities of Arguis and Lusera. The Lusera section once restored in its initial position is located to the North of the Arguis section in a basinward direction such that comparing time-equivalent facies between these two sections helps us reconstructing

Nanofilter platform based on functionalized carbon nanotubes for adsorption and elimination of Acrolein, a toxicant in cigarette smoke

NASA Astrophysics Data System (ADS)

Yoosefian, Mehdi; Pakpour, Atef; Etminan, Nazanin

2018-06-01

This paper discusses the use of carboxylated single-walled carbon nanotube as a general nanofilter platform for the removal of acrolein carcinogen from cigarette smoke. The analyses carried out in the detailed study of the electronic and structural effects of the adsorption of acrolein onto COOH loaded on single-walled carbon nanotube under the density functional theory framework. The results of Bader theory of atoms in molecules, natural bond orbital, molecular potential electron surface and density of state confirm the potential application of the suggested nanofilter platform.

Spectroscopic studies of wood fossils from the Crato Formation, Cretaceous Period.

PubMed

da Silva, J H; Freire, P T C; Abagaro, B T O; Silva, J A F; Saraiva, G D; de Lima, F J; Barros, O A; Bantim, R A; Saraiva, A A F; Viana, B C

2013-11-01

In this work we study two types of wood fossils (Gymnosperms, Araucariaceae) from the Crato Formation of Araripe Basin in Brazil, from the Cretaceous Period. The samples were characterized by Raman and infrared spectroscopies, X-ray diffraction and scanning electron microscopy. The results obtained by different techniques showed that although the rocks surrounding the fossils have predominantly the same constitution - calcite - however, the formation processes of these types of wood fossils are quite different. One of the fossils, denominated as light wood, is predominantly composed of gypsum, while the other fossil, the dark wood, is rich in amorphous carbon, possibly the kerogen type. Implications relative to the environment where the plants lived millions years ago are also given. Finally, the results highlight the constitution of one of the most important paleontological sites of the Cretaceous Period in the South America. Copyright © 2013 Elsevier B.V. All rights reserved.

Seismic structure and stratigraphy of northern edge of Bahaman-Cuban collision zone

USGS Publications Warehouse

Ball, M.M.; Martin, R.G.; Bock, W.D.; Sylwester, R.E.; Bowles, R.M.; Taylor, D.; Coward, E.L.; Dodd, J.E.; Gilbert, L.

1985-01-01

Common-depth-point (CDP) seismic reflection data in the southwestern Bahamas reveal the northern edge of the tectonized zone that resulted from the late Mesozoic-early Cenozoic collision of Cuba and the Bahamas. Two seismic facies are present. A 10-km broad anticline occurs at the south end of Santaren Channel. Platform carbonates in the core of this structure overlie Early Cretaceous and older basinal carbonate deposits and are onlapped by Late Cretaceous and Cenozoic basinal facies. The structure is inferred to be a hanging-wall anticline at the northern limit of the Cuban fold-thrust belt formed in the Late Cretaceous. A deeper water embayment extended northward into the Straits of Florida, around northern Cay Sal Bank, and back into Santaren Channel during the Early Cretaceous.

Paleomagnetic Investigations on the Tectonic Evolution of the Southeastern Anatolian Ophiolites in Late Cretaceous

NASA Astrophysics Data System (ADS)

Cengiz Cinku, M.; Karabulut, S.; Parlak, O.; Cabuk, B. S.; Ustaömer, T.; Hisarli, M. Z.

2016-12-01

Two E-W trending ophiolite belts crop out in SE Turkey, The southerly located ophiolites (Hatay, Koçali) were emplaced onto the Arabian Platform in Late Cretaceous whereas the northerly located ophiolites (Göksun, İspendere, Kömürhan, Guleman) were underthrust the S Tauride margin (i.e. Malatya-Keban Platform) in Late Cretaceous. Here we report our first paleomagnetic results from 155 different sites which was was focused on to the sheeted dyke complex, cumulate gabbros and extrusive sequences of each ophiolite from the N and S belts, while the cover units where sampled to distinguish emplacement related tectonic rotations from post-emplacement tectonic rotations. Rock magnetic experiments showed evidence of magnetite/titanomagnetite as the main magnetic carriers at the majority of sites. Progressive thermal and alternating demagnetization revealed that the characteristic remanent component is removed between 500 and 580 °C or 30-100 mT, respectively. Our new paleomagnetic results from the ophiolitic rocks emplaced in Arabian platform and the SE Anatolia show important implications to the spreading centre of the former ocean (s). Large counterclockwise rotations up to 100° are obtained from the sheeded dykes of the Hatay ophiolite in the Arabian plate with a paleolatitude of 16°, in contrast to the sheeded dykes of the Göksun ophiolite emplaced in the SE Anatolian with clockwise rotation of 90° and a paleolatitude of 22°. The relative movement of the ophiolitic series show their emplacement in the different zones. This study was financially supported by the project of the Scientific and Technical Research Council of Turkey (TUBITAK) with Project number 114R024.

Dinosaurs and the Cretaceous Terrestrial Revolution

PubMed Central

Lloyd, Graeme T; Davis, Katie E; Pisani, Davide; Tarver, James E; Ruta, Marcello; Sakamoto, Manabu; Hone, David W.E; Jennings, Rachel; Benton, Michael J

2008-01-01

The observed diversity of dinosaurs reached its highest peak during the mid- and Late Cretaceous, the 50 Myr that preceded their extinction, and yet this explosion of dinosaur diversity may be explained largely by sampling bias. It has long been debated whether dinosaurs were part of the Cretaceous Terrestrial Revolution (KTR), from 125–80 Myr ago, when flowering plants, herbivorous and social insects, squamates, birds and mammals all underwent a rapid expansion. Although an apparent explosion of dinosaur diversity occurred in the mid-Cretaceous, coinciding with the emergence of new groups (e.g. neoceratopsians, ankylosaurid ankylosaurs, hadrosaurids and pachycephalosaurs), results from the first quantitative study of diversification applied to a new supertree of dinosaurs show that this apparent burst in dinosaurian diversity in the last 18 Myr of the Cretaceous is a sampling artefact. Indeed, major diversification shifts occurred largely in the first one-third of the group's history. Despite the appearance of new clades of medium to large herbivores and carnivores later in dinosaur history, these new originations do not correspond to significant diversification shifts. Instead, the overall geometry of the Cretaceous part of the dinosaur tree does not depart from the null hypothesis of an equal rates model of lineage branching. Furthermore, we conclude that dinosaurs did not experience a progressive decline at the end of the Cretaceous, nor was their evolution driven directly by the KTR. PMID:18647715

Reinterpreting the Early Cretaceous Sulfur Isotope Records: Implications for the Evolution of Seawater Chemistry

NASA Astrophysics Data System (ADS)

Mills, J. V.; Gomes, M. L.; Sageman, B. B.; Jacobson, A. D.; Hurtgen, M. T.

2013-12-01

The geologic record of the Cretaceous is punctuated by several periods of high organic carbon burial interpreted to represent global Ocean Anoxic Events (OAEs). In addition to the short-term (<1-Myr) changes in carbon (C) cycling associated with OAEs, evidence from a number of geochemical proxies has been interpreted to represent large-scale changes in ocean chemistry during the period. Specifically, the sulfur (S) isotope composition of early Cretaceous seawater sulfate as recorded in marine barite exhibits an ~5 permil shift in d34Ssulfate that persists for ~15Myr before returning to pre-excursion values. Superimposed upon this long-term shift in S-isotopes is OAE1a, the second major anoxic event recognized in the Cretaceous. Two hypotheses have been proposed to explain this S isotope perturbation: (1) massive evaporite deposition associated with rifting during the opening of the South Atlantic and a corresponding decrease in pyrite burial rates and (2) increased inputs of volcanic-derived S due to extensive LIP-volcanism. While there is geologic evidence for both evaporite deposition and enhanced hydrothermal activity, the relative influence of these potential driving factors remains largely unconstrained. Variation in the strontium (Sr) isotope composition of marine carbonates provides a tool for distinguishing between these influences. We examine the S isotope composition of carbonate-associated sulfate (CAS) spanning the Barremian through Aptian from Resolution Guyot (ODP Site 866) and compare the S isotope record to time equivalent records of carbon and strontium isotopes. Correlative changes in the C, S, and Sr cycles are observed: an ~5 permil shift in d34Ssulfate, which begins at the onset of OAE1a and continues after the positive d13Ccarb excursion, is accompanied by a contemporaneous, parallel shift in 87Sr/86Sr to unradiogenic values. The tight coupling observed between S and Sr throughout the interval is highly suggestive of a common driving mechanism

Isotope and elemental geochemistry of Cretaceous fossiliferous concretions (Santana Formation, Brazil)

NASA Astrophysics Data System (ADS)

Heimhofer, Ulrich; Meister, Patrick; Bernasconi, Stefano M.; Ariztegui, Daniel; Martill, David M.; Schwark, Lorenz

2014-05-01

Exceptional three-dimensional fossil preservation (incl. phosphatization of soft-tissues) within organic carbon-rich mudstones is often associated with the formation of a protective carbonate shell surrounding the fossil specimen. Examples for this type of preservation are the Early Cretaceous fishes, turtles and pterosaurs from the Brazilian Santana Formation. Numerous studies proposed different conceptual models for concretion formation. Having new state-of-the-art geochemical tools at hand we revisited these models for the Santana Formation as an exemplary case. Differential compaction clearly indicates early precipitation of micritic calcite surrounding a central cavity containing the still decomposing fossil. The presence of pyrite forming a circular rim around the fossil and carbonate with negative carbon isotope compositions suggest intense sulphate reduction whereby the production of ammonium from the decay of proteins led to an increased alkalinity, which induced early carbonate precipitation. By means of micro-XRF scanning we found that pyrite is absent from the interior part of the concretions and that total iron content is very low, which indicate absence of sulphate reduction at the center of the concretions and possibly local onset of methanogenesis. We postulate that the central cavity may even have been filled with methane gas that evolved from the decaying animal. Methane diffusing outward was anaerobically oxidized in the surrounding sulphate reduction zone. Carbonate clumped isotopes revealed that micritic calcite formed early, but that these early precipitates are overprinted by two different late diagenetic cements precipitated at elevated temperatures. The occurrence of an outermost "cone-in-cone" calcite rim can be associated with burial showing temperatures of up to 60°C. Strontium-isotope ratios of matrix calcite and cement phases show radiogenic values (0.710416 to 0.712465), which are significantly higher than typical marine Cretaceous

Recognition of Fossil Prokaryotes in Cretaceous Methane Seep Carbonates: Relevance to Astrobiology

NASA Astrophysics Data System (ADS)

Shapiro, Russell Scott

2004-12-01

Recovery of prokaryotic body fossils from methane seep carbonates such as those of the Cretaceous Tepee Buttes of Colorado serves as a model for sampling in future astrobiological missions. The fossils, found primarily at the interface between paragenetic fabrics, suggest a sharp physicochemical gradient. Evidence of these microbial fossils occurs at a variety of scales. In the field, microbialite is found as meter-scale thrombolitic zones and centimeterscale stromatolitic crusts lining voids inferred to be the sites of ancient methane seepage. Petrographic fabrics suggestive of microbialite include indistinct peloids (0.1-1 mm in diameter) and crusts of authigenic micrite. Primary evidence obtained from scanning electron microscopy coupled with energy-dispersive x-ray spectroscopy analysis comprises pinnate bacteria (0.3 µm in diameter and 1-1.5 µm long), sheaths (2-4 µm in diameter), coccoids (0.5-1 µm in diameter, up to 40 per cluster), and the presence of framboidal pyrite (6-8 µm in diameter). These results are in agreement with studies of other ancient and modern seeps and suggest a morphological conservatism of microbial form that can be incorporated into studies of extraterrestrial environments where it is presumed that reduced gases drive the metabolic activity of prokaryote-like organisms. Target areas that could serve as conduits for reduced gas seeps include tectonic or impact-driven faulting, zones of cryosphere melting, or other disruptions in crustal coherence. Ancient seeps, preserved as localized anomalous evaporite deposits in the sedimentary cover, could be detected by remote sensing. Astrobiology 4, 438-449.

Monolithic carbon structures including suspended single nanowires and nanomeshes as a sensor platform

PubMed Central

2013-01-01

With the development of nanomaterial-based nanodevices, it became inevitable to develop cost-effective and simple nanofabrication technologies enabling the formation of nanomaterial assembly in a controllable manner. Herein, we present suspended monolithic carbon single nanowires and nanomeshes bridging two bulk carbon posts, fabricated in a designed manner using two successive UV exposure steps and a single pyrolysis step. The pyrolysis step is accompanied with a significant volume reduction, resulting in the shrinkage of micro-sized photoresist structures into nanoscale carbon structures. Even with the significant elongation of the suspended carbon nanowire induced by the volume reduction of the bulk carbon posts, the resultant tensional stress along the nanowire is not significant but grows along the wire thickness; this tensional stress gradient and the bent supports of the bridge-like carbon nanowire enhance structural robustness and alleviate the stiction problem that suspended nanostructures frequently experience. The feasibility of the suspended carbon nanostructures as a sensor platform was demonstrated by testing its electrochemical behavior, conductivity-temperature relationship, and hydrogen gas sensing capability. PMID:24256942

Functionalization and characterization of pyrolyzed polymer based carbon microstructures for bionanoelectronics platforms

NASA Astrophysics Data System (ADS)

Hirabayashi, Mieko; Mehta, Beejal; Vahidi, Nasim W.; Khosla, Ajit; Kassegne, Sam

2013-11-01

In this study, the investigation of surface-treatment of chemically inert graphitic carbon microelectrodes (derived from pyrolyzed photoresist polymer) for improving their attachment chemistry with DNA molecular wires and ropes as part of a bionanoelectronics platform is reported. Polymer microelectrodes were fabricated on a silicon wafer using standard negative lithography procedures with negative-tone photoresist. These microelectrode structures were then pyrolyzed and converted to a form of conductive carbon that is referred to as PP (pyrolyzed polymer) carbon throughout this paper. Functionalization of the resulting pyrolyzed structures was done using nitric, sulfuric, 4-amino benzoic acids (4-ABA), and oxygen plasma etching and the surface modifications confirmed with Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, and electron dispersion x-ray spectroscopy (EDS). Post surface-treatment analysis of microelectrodes with FTIR and Raman spectroscopy showed signature peaks characteristics of carboxyl functional groups while EDS showed an increase in oxygen content in the surface-treatment procedures (except 4-ABA) indicating an increase in carboxyl functional group. These functional groups form the basis for peptide bond with aminated oligonucleotides that in turn could be used as molecular wires and interconnects in a bionanoelectronics platform. Post-pyrolysis analysis using EDS showed relatively higher oxygen concentrations at the edges and location of defects compared to other locations on these microelectrodes. In addition, electrochemical impedance measurements showed metal-like behavior of PP carbon with high conductivity (|Z| <1 KΩ) and no detectable detrimental effect of oxygen plasma surface-treatment on electrical characteristic. In general, characterization results—taken together—indicated that oxygen plasma surface-treatment produced more reliable, less damaging, and consistently repeatable generation of carboxyl functional

Characterizing Cretaceous Glaciation Events: K-Ar Ages of Southern Ocean Sediments

NASA Astrophysics Data System (ADS)

Wright, M. A.; Hemming, S. R.; Barbeau, D. L.; Torfstein, A.; Pierce, E. L.; Williams, T.; McManus, J. F.; Gombiner, J.

2012-12-01

Evidence from paleosols and carbonate weathering models suggest that the Late Cretaceous had a supergreenhouse climate due to atmospheric CO2 concentrations two to four times greater than modern levels, tropical sea surface temperatures exceeding 35°C, and high-latitude temperatures exceeding 20°C. Despite this warmth, the Late Cretaceous was apparently punctuated by large (>25 m) and rapid (<<1 million year) sea-level changes, as recorded by marginal marine stratigraphic architectures and pelagic stable isotope compositions. The magnitude and tempo of these changes suggest a glacio-eustatic control, presumably from the growth and decay of continental ice sheets on Antarctica. Because continental glaciation tends to increase the weathering of bedrock and production of sediment delivered to the oceans, circum-Antarctic marine sediment flux would be expected to increase during periods of glaciation. In order to identify a Late Cretaceous glaciation signal from such marine records, we must first constrain the compositional signal of continental detritus in marine sediments. Here we report the results of downcore K-Ar analysis of the terrigenous sediments of Quaternary Weddell Sea cores PS1170-1 and PS1388-3 in order to identify the compositional signature of continent-derived detritus deposited in the Weddell Sea during a known glacial period. Further, we use our K-Ar analyses of circum-Antarctic Quaternary sediment cores to pinpoint potential sediment source areas. Having constrained this glaciation signal, we also present preliminary K-Ar and Sm-Nd analysis of the Campanian-Maastrictian boundary event (69 Ma) at Ocean Drilling Project site 690C to assess the controversial hypothesis of Late Cretaceous glaciation of Antarctica.

Palaeoredox conditions and sequence stratigraphy of the Cretaceous storm-dominated, mixed siliciclastic-carbonate ramp in the Eastern Cordillera Basin (Colombia): Evidence from sedimentary geochemical proxies and facies analysis

NASA Astrophysics Data System (ADS)

Rivera, Huber A.; Le Roux, Jacobus P.; Sánchez, L. Katherine; Mariño-Martínez, Jorge E.; Salazar, Christian; Barragán, J. Carolina

2018-10-01

The Cretaceous black shales of Colombia are among the most important successions in the north of South America and have attracted the attention of many geoscientists and exploration companies over the last few decades, because of their high hydrocarbon potential and the presence of emerald deposits. However, many uncertainties still remain with regard to their tectonic setting, sequence stratigraphy, depositional environments, palaeoxygenation conditions, and organic matter preservation. In order to develop a more integrated picture of these different processes and conditions, we conducted a detailed sedimentological, inorganic geochemical (U, V, Ni, Zn, Mn, Fe, Ti, Mo, Cu, Cr, Cd, Ba) and sequence stratigraphic analysis of the Cretaceous black shales in the Magdalena-Tablazo Sub-Basin (Eastern Cordillera Basin) of Colombia. Eleven lithofacies and five lithofacies associations of a storm-dominated, siliciclastic-carbonate ramp were identified, which range from basin to shallow inner ramp environments. These facies were grouped into six third-order stratigraphic sequences showing high-order cycles of marine transgression with constrained regressive pulses during the late Valanginian to early Coniacian. The black shales succession represents deposition under anoxic bottom water with some intervals representing dysoxic-suboxic conditions. The evolution of the sedimentary environments and their palaeoxygenation history reflect tectonic and eustatic sea-level controls that 1) produced a variable orientation and position of the coastline throughout the Cretaceous; 2) conditioned the low-gradient ramp geometry (<0.3°) and 3) modified the oxygenation conditions in the Magdalena-Tablazo Sub-Basin. An improved understanding of the sedimentary setting during deposition of the Cretaceous black shales in the Magdalena-Tablazo Sub-Basin assists in highlighting the interplay between the mechanism of sedimentation and continuum anoxic conditions prevailing in a basin, as well the

Correlation of aptian-albian carbon isotope excursions in continental strata of the cretaceous Foreland Basin, Eastern Utah, U.S.A.

USGS Publications Warehouse

Ludvigson, Greg A.; Joeckel, R.M.; Gonzalez, Luis A.; Gulbranson, E.L.; Rasbury, E.T.; Hunt, G.J.; Kirkland, J.I.; Madsen, S.

2010-01-01

Nodular carbonates ("calcretes") in continental foreland-basin strata of the Early Cretaceous Cedar Mountain Formation (CMF) in eastern Utah yield ??13C and ??O records of changes in the exogenic carbon cycle related to oceanic anoxic events (OAEs), and terrestrial paleoclimate. Chemostratigraphic profiles of both forebulge and foredeep sections show two prominent positive ??13C excursions, each with a peak value of -3% VPDB, and having background ??13C values of about -6% VPDB. These excursions correlate with the global early Aptian (Ap7) and late Aptian-early Albian (Apl2-All) carbon isotope excursions. Aptian-Albian positive ??13C excursions in the CMF also correspond to 3-4 per mil increases in carbonate ??18O. These phenomena record local aridification events. The chemostratigraphic profile on the thinner forebulge section of the CMF is calibrated, for the first time, by a radiogenic U-Pb date of 119.4 ?? 2.6 Ma on a carbonate bed, and by detrital zircon U-Pb dates on two bounding sandstone units (maximum depositional ages of 146 Ma and 112 Ma). P??trographie observations and diagenetic analyses of micritic to microsparitic carbonates from nodules indicate palustrine origins and demonstrate that they crystallized in shallow early meteoric phreatic environments. Meteoric calcite lines derived from CMF carbonates have ??18O values ranging between -8.1 to -7.5%o VPDB, supporting an estimate of zonal mean groundwater ??18O of -6% VSMOW for an Aptian-Albian paleolatitude of 34?? N. Furthermore, our two chemostratigraphic profiles exhibit a generally proportionate thinning of correlative strata from the foredeep on to the forebulge, suggesting that there were consistently lower rates of accumulation on the forebulge during the Aptian-Albian. Identification of the global Aptian-Albian ??13C excursions in purely continental strata, as demonstrated in this paper, opens a new avenue of research by identifying specific stratigraphie intervals that record the terrestrial

Impact of CO2 and continental configuration on Late Cretaceous ocean dynamics

NASA Astrophysics Data System (ADS)

Puceat, Emmanuelle; Donnadieu, Yannick; Moiroud, Mathieu; Guillocheau, François; Deconinck, Jean-François

2014-05-01

The Late Cretaceous period is characterized by a long-term climatic cooling (Huber et al., 1995; Pucéat et al., 2003; Friedrich et al., 2012) and by major changes in continental configuration with the widening of the Atlantic Ocean, the initiation of the Tethyan ocean closure, and the deepening of the Central Atlantic Gateway. The Late Cretaceous also marks the end of the occurrence of Oceanic Anoxic Events (OAEs), that are associated to enhanced organic carbon burial, to major crises of calcifying organisms, and to possible ocean acidification (Jenkyns, 2010). It has been suggested that the evolution in continental configuration and climate occurring during the Late Cretaceous could have induced a reorganization in the oceanic circulation, that may have impacted the oxygenation state of the oceanic basins and contributed to the disappearance of OAEs (Robinson et al., 2010; Robinson and Vance, 2012). Yet there is no consensus existing on the oceanic circulation modes and on their possible evolution during the Late Cretaceous, despite recent improvement of the spatial and temporal coverage of neodymium isotopic data (ɛNd), a proxy of oceanic circulation (MacLeod et al., 2008; Robinson et al., 2010; Murphy and Thomas, 2012; Robinson and Vance, 2012; Martin et al., 2012; Moiroud et al., 2012). Using the fully coupled ocean-atmosphere General Circulation Model FOAM, we explore in this work the impact on oceanic circulation of changes in continental configuration between the mid- and latest Cretaceous. Two paleogeography published by Sewall et al. (2007) were used, for the Cenomanian/Turonian boundary and for the Maastrichtian. For each paleogeography, 3 simulations have been realized, at 2x, 4x, and 8x the pre-industrial atmospheric CO2 level, in order to test the sensitivity of the modelled circulation to CO2. Our results show for both continental configurations a bipolar mode for the oceanic circulation displayed by FOAM. Using the Cenomanian/Turonian land-sea mask

Impact of middle Cretaceous (Albian to Turonian) climatic changes in the eastern sub-equatorial marginal Pacific region

NASA Astrophysics Data System (ADS)

Navarro Ramirez, Juan Pablo; Bodin, Stéphane; Heimhofer, Ulrich; Immenhauser, Adrian

2015-04-01

A new Albian-Turonian carbon isotope (δ13Ccarb and δ13Corg) curve based on epeiric-neritic carbonate successions from Peru is reported. The study was carried out to test the hypothesis that mid-Cretaceous OAEs, which are well-documented in the Tethys and Atlantic realm, are equally recorded in the epeiric-neritic realm of the eastern sub-equatorial Pacific as exposed in Northern and Central Peru. Depositional environments range from shallow subtidal inner ramp to outer ramp settings. For this purpose, we combined chemostratigraphic and sedimentological information from expanded and well-exposed sections in NW Peru. The geochemical data provide evidence for the record of the OAE1b set, the OAE1c, the OAE1d, as well as the Cenomanian-Turonian Boundary Event (OAE2), known as one of the most extreme carbon cycle perturbation. The new δ13C record is constrained by biostratigraphic evidence and 87Sr/86Sr isotope stratigraphy using well-preserved oyster shells. Sedimentological observations, combined with the δ13C stratigraphic record, were used to elucidate the complex interplay of climate changes, nutrient supply and platform drowning. These observations indicate: (1) A late Aptian-early Albian change from siliciclastic- to carbonate-dominated sedimentation that may be coeval with the placement of the Kilian event. (2) Incipient platform-drowning during the early Albian probably linked to the impact of the Paquier event. (3) An early middle Albian demise of neritic carbonate production that coincides with the Leenhardt Level, followed by middle Albian condensed sedimentation that reports prominent negative values in δ13Ccarb. (4) Renewed carbonate ramp production during the late Albian-middle Cenomanian. (5) An upper Cenomanian-middle Turonian transition interval with the OAE2 represented by a 44-m-thick sedimentary succession characterized by rhythmically bedded marls, marly limestones and limestones. Despite the scarcity of significant amount of organic matter (a

Cretaceous gastropods: contrasts between tethys and the temperate provinces.

USGS Publications Warehouse

Sohl, N.F.

1987-01-01

During the Cretaceous Period, gastropod faunas show considerable differences in their evolution between the Tethyan Realm (tropical) and the Temperate Realms to the north and south. Like Holocene faunas, prosobranch, gastropods constitute the dominant part of Cretaceous marine snail faunas. Entomotaeneata and opisthobranchs usually form all of the remainder. In Tethyan faunas the Archaeogastropoda form a consistent high proportion of total taxa but less than the Mesogastropoda throughout the period. In contrast, the Temperate faunas beginning in Albian times show a decline in percentages of archaeogastropod taxa and a significant increase in the Neogastropoda, until they constitute over 50 percent of the taxa in some faunas. The neogastropods never attain high diversity in the Cretaceous of the Tethyan Realm and are judged to be of Temperate Realm origin. Cretaceous Tethyan gastropod faunas are closely allied to those of the 'corallien facies' of the Jurassic and begin the period evolutionarily mature and well diversified. Three categories of Tethyan gastropods are analyzed. The first group consists of those of Jurassic ancestry. The second group orginates mainly during the Barremian and Aptian, reaches a climax in diversification during middle Cretaceous time, and usually declines during the latest Cretaceous. The third group originates late in the Cretaceous and consists of taxa that manage to either survive the Cretaceous-Tertiary crisis or give rise to forms of prominence among Tertiary warm water faunas. Temperate Realm gastropod faunas are less diverse than those of Tethys during the Early Cretaceous. They show a steady increase in diversity, primarily among the Mesogastropoda and Neogastropoda. This trend culminates in latest Cretaceous times when the gastropod assemblages of the clastic provinces of the inner shelf contain an abundance of taxa outstripping that of any other part of the Cretaceous of either realm. Extinction at the Cretaceous

Non-marine carbonate facies, facies models and palaeogeographies of the Purbeck Formation (Late Jurassic to Early Cretaceous) of Dorset (Southern England).

NASA Astrophysics Data System (ADS)

Gallois, Arnaud; Bosence, Dan; Burgess, Peter

2015-04-01

Non-marine carbonates are relatively poorly understood compared with their more abundant marine counterparts. Sedimentary facies and basin architecture are controlled by a range of environmental parameters such as climate, hydrology and tectonic setting but facies models are few and limited in their predictive value. Following the discovery of extensive Early Cretaceous, non-marine carbonate hydrocarbon reservoirs in the South Atlantic, the interest of understanding such complex deposits has increased during recent years. This study is developing a new depositional model for non-marine carbonates in a semi-arid climate setting in an extensional basin; the Purbeck Formation (Upper Jurassic - Lower Cretaceous) in Dorset (Southern England). Outcrop study coupled with subsurface data analysis and petrographic study (sedimentology and early diagenesis) aims to constrain and improve published models of depositional settings. Facies models for brackish water and hypersaline water conditions of these lacustrine to palustrine carbonates deposited in the syn-rift phase of the Wessex Basin will be presented. Particular attention focusses on the factors that control the accumulation of in-situ microbialite mounds that occur within bedded inter-mound packstones-grainstones in the lower Purbeck. The microbialite mounds are located in three units (locally known as the Skull Cap, the Hard Cap and the Soft Cap) separated by three fossil soils (locally known as the Basal, the Lower and the Great Dirt Beds) respectively within three shallowing upward lacustrine sequences. These complex microbialite mounds (up to 4m high), are composed of tabular small-scale mounds (flat and long, up to 50cm high) divided into four subfacies. Many of these small-scale mounds developed around trees and branches which are preserved as moulds (or silicified wood) which are surrounded by a burrowed mudstone-wackestone collar. Subsequently a thrombolite framework developed on the upper part only within

Paired carbon stable-isotope records for the Cenomanian Stage (100.5 -93.9 Ma): correlation tool and Late Cretaceous pCO2 record?

NASA Astrophysics Data System (ADS)

Jarvis, Ian; Gröcke, Darren; Laurin, Jiří; Selby, David; Roest-Ellis, Sascha; Miles, Andrew; Lignum, John; Gale, Andrew; Kennedy, Jim

2016-04-01

Carbon stable-isotope stratigraphy of marine carbonates (δ13Ccarb) provides remarkable insights into past variation in the global carbon cycle, and has become firmly established as a powerful global correlation tool. Continuous δ13Ccarb time series are becoming increasingly available for much of the geological record, including the Upper Cretaceous. However, our knowledge of stratigraphic variation in the carbon isotopic composition of sedimentary organic matter (δ13Corg) is much poorer, and is generally restricted to organic-rich sedimentary successions and/or key boundary intervals. Close coupling exists between the global isotopic composition of the reduced and oxidised carbon reservoirs on geological time scales, but the stratigraphic resolution of most long-term δ13Corg Mesozoic records is inadequate to identify leads and lags in the responses of the two reservoirs to carbon cycle perturbations. Cenomanian times (100.5-93.9 Ma) represent perhaps the best documented episode of eustatic rise in sea level in Earth history and the beginning of the Late Mesozoic thermal maximum, driving global expansion of epicontinental seas and the onset of widespread pelagic and hemipelagic carbonate deposition. Significant changes occurred in global stable-isotope records, including two prominent perturbations of the carbon cycle - the Mid-Cenomanian Event I (MCEI; ~96.5-96.2 Ma) and Oceanic Anoxic Event 2 (OAE2; ~94.5-93.8 Ma). OAE2, one of two truly global Cretaceous OAEs, was marked by the widespread deposition of black shales, and a global positive carbon stable-isotope excursion of 2.0 - 2.5‰ δ13Ccarb, and up to 7‰ in the sulphur-bound phytane biomarker. MCEI, by contrast, shows a <1‰ δ13Ccarb excursion and no associated black shales in most areas. Here, we present detailed paired δ13Ccarb and δ13Corg stable-isotope records for the entire Cenomanian Stage, based on an Upper Albian - Lower Turonian composite reference section from the Vocontian Basin of SE

A critical transition in leaf evolution facilitated the Cretaceous angiosperm revolution.

PubMed

de Boer, Hugo Jan; Eppinga, Maarten B; Wassen, Martin J; Dekker, Stefan C

2012-01-01

The revolutionary rise of broad-leaved (flowering) angiosperm plant species during the Cretaceous initiated a global ecological transformation towards modern biodiversity. Still, the mechanisms involved in this angiosperm radiation remain enigmatic. Here we show that the period of rapid angiosperm evolution initiated after the leaf interior (post venous) transport path length for water was reduced beyond the leaf interior transport path length for CO2 at a critical leaf vein density of 2.5-5 mm mm(-2). Data and our modelling approaches indicate that surpassing this critical vein density was a pivotal moment in leaf evolution that enabled evolving angiosperms to profit from developing leaves with more and smaller stomata in terms of higher carbon returns from equal water loss. Surpassing the critical vein density may therefore have facilitated evolving angiosperms to develop leaves with higher gas exchange capacities required to adapt to the Cretaceous CO2 decline and outcompete previously dominant coniferous species in the upper canopy.

Origin of Cretaceous phosphorites from the onshore of Tamil Nadu, India

NASA Astrophysics Data System (ADS)

Purnachandra Rao, V.; Kessarkar, Pratima M.; Nagendra, R.; Babu, E. V. S. S. K.

2007-12-01

Cretaceous phosphorites from the onshore of Tamil Nadu have been investigated for their origin and compared with those in the offshore. Cretaceous phosphorites occur as light brown to yellowish brown or white nodules in Karai Shale of the Uttatur Group in the onshore Cauvery basin. Nodules exhibit phosphatic nucleus encrusted by a chalky shell of carbonate. The nucleus of the nodules consists of light and dark coloured laminae, phosphate peloids/coated grains and detrital particles interspersed between the laminae. Scanning electron microscope (SEM) studies reveal trapping and binding activity of microbial filaments. A mat structure with linearly arranged microbial filaments and hollow, cell-based coccoid cyanobacterial mat are present. Nodules contain abundant carbonate fluorapatite, followed by minor calcite, quartz and feldspar. The P2O5 content of the phosphorites ranges from 18 to 26%. The CaO/P2O5, Sr and F contents are higher than that of pure carbonate fluorapatite. Concentrations of Si, Al, K, Fe, and Ti are low. We suggest that the nuclei of the nodules represent phosphate clasts related to phosphate stromatolites formed at intertidal conditions. At high energy levels the microbial mats were disintegrated into phosphate clasts, coated with carbonate and then reworked into Karai Shale. On the other hand, Quaternary phosphorites occur as irregular to rounded, grey coloured phosphate clasts at water depths between 180 and 320m on the continental shelf of Tamil Nadu. They exhibit grain-supported texture. Despite Quaternary in age, they also resemble phosphate stromatolites of intertidal origin and reworked as phosphate clasts onto the shelf margin depressions. Benthic microbial mats probably supplied high phosphorus to the sediments. Availability of excess phosphorus seems to be a pre-requisite for the formation of phosphate stromatolites.

Vegetation-induced warming of high-latitude regions during the Late Cretaceous period

NASA Astrophysics Data System (ADS)

Otto-Bliesner, Bette L.; Upchurch, Garland R.

1997-02-01

Modelling studies of pre-Quaternary (>2 million years ago) climate implicate atmospheric carbon dioxide concentrations1, land elevation2 and land-sea distribution3-5 as important factors influencing global climate change over geological timescales. But during times of global warmth, such as the Cretaceous period and Eocene epoch, there are large discrepancies between model simulations of high-latitude and continental-interior temperatures and those indicated by palaeotemperature records6,7. Here we use a global climate model for the latest Cretaceous (66 million years ago) to examine the role played by high- and middle-latitude forests in surface temperature regulation. In our simulations, this forest vegetation warms the global climate by 2.2 °C. The low-albedo deciduous forests cause high-latitude land areas to warm, which then transfer more heat to adjacent oceans, thus delaying sea-ice formation and increasing winter temperatures over coastal land. Overall, the inclusion of some of the physical and physiological climate feedback effects of high-latitude forest vegetation in our simulations reduces the existing discrepancies between observed and modelled climates of the latest Cretaceous, suggesting that these forests may have made an important contribution to climate regulation during periods of global warmth.

Rise and demise of the Bahama-Grand Banks gigaplatform, northern margin of the Jurassic proto-Atlantic seaway

USGS Publications Warehouse

Poag, C. Wylie

1991-01-01

An extinct, > 5000-km-long Jurassic carbonate platform and barrier reef system lies buried beneath the Atlantic continental shelf and slope of the United States. A revised stratigraphic framework, a series of regional isopach maps, and paleogeographic reconstructions are used to illustrate the 42-m.y. history of this Bahama-Grand Banks gigaplatform from its inception in Aalenian(?) (early Middle Jurassic) time to its demise and burial in Berriasian-Valanginian time (early Early Cretaceous). Aggradation-progradation rates for the gigaplatform are comparable to those of the familiar Capitan shelf margin (Permian) and are closely correlated with volumetric rates of siliciclastic sediment accumulation and depocenter migration. Siliciclastic encroachment behind the carbonate tracts appears to have been an important impetus for shelf-edge progradation. During the Early Cretaceous, sea-level changes combined with eutrophication (due to landward soil development and seaward upwelling) and the presence of cooler upwelled waters along the outer shelf appear to have decimated the carbonate producers from the Carolina Trough to the Grand Banks. This allowed advancing siliciclastic deltas to overrun the shelf edge despite a notable reduction in siliciclastic accumulation rates. However, upwelling did not extend southward to the Blake-Bahama megabank, so platform carbonate production proceeded there well into the Cretaceous. Subsequent stepwise carbonate abatement characterized the Blake Plateau Basin, whereas the Bahamas have maintained production to the present. The demise of carbonate production on the northern segments of the gigaplatform helped to escalate deep-water carbonate deposition in the Early Cretaceous, but the sudden augmentation of deep-water carbonate reservoirs in the Late Jurassic was triggered by other agents, such as global expansion of nannoplankton communities. ?? 1991.

Upper Cretaceous subsurface stratigraphy and structure of coastal Georgia and South Carolina

USGS Publications Warehouse

Valentine, Page C.

1982-01-01

Upper Cretaceous subsurface stratigraphy and structure of coastal Georgia and South Carolina is based on the study of 24 wells along two transects, one extending across the seaward-dipping sedimentary basin termed the 'Southeast Georgia Embayment' northeastward to the crest of the Cape Fear Arch, and the other alined east-west, parallel to the basin axis and including the COST GE-l well on the Outer Continental Shelf. A new biostratigraphic analysis, using calcareous nannofossils, of the Fripp Island, S.C., well and reinterpretations of the Clubhouse Crossroads corehole 1, South Carolina, and other wells in South Carolina, Georgia, and northernmost Florida have made possible the comparison and reevaluation of stratigraphic interpretations of the region made by G. S. Gohn and others in 1978 and 1980 and by P. M. Brown and others in 1979. The present study indicates that within the Upper Cretaceous section the stratigraphic units formerly assigned a Cenomanian (Eaglefordian and Woodbinian) age are Coniacian (Austinian) and Turonian (Eaglefordian) in age. A previously described hiatus encompassing Coniacian and Turonian time is not present. More likely, a hiatus is probably present in the upper Turonian, and major gaps in the record are present within the Cenomanian and between the Upper Cretaceous and the pre-Cretaceous basement. After an erosional episode in Cenomanian time that affected the section beneath eastern Georgia and South Carolina, Upper Cretaceous marine clastic and carbonate rocks were deposited on a regionally subsiding margin that extended to the present Blake Escarpment. In contrast, during Cenozoic time, especially in the Eocene, subsidence and sedimentation rates were uneven across the margin. A thick progradational sequence of carbonate rocks accumulated in the Southeast Georgia Embayment and also built the present Continental Shelf, whereas farther offshore a much thinner layer of sediments was deposited on the Blake Plateau. There is no general

Electrochemical sensing platform based on the highly ordered mesoporous carbon-fullerene system.

PubMed

Zhou, Ming; Guo, Jidong; Guo, Li-ping; Bai, Jing

2008-06-15

In this paper, we report a novel all-carbon two-dimensionally ordered nanocomposite electrode system on the basis of the consideration of host-guest chemistry, which utilizes synergistic interactions between a nanostructured matrix of ordered mesoporous carbon (OMC) and an excellent electron acceptor of nanosized fullerene (C 60) to facilitate heterogeneous electron-transfer processes. The integration of OMC-C 60 by covalent interaction, especially its electrochemical applications for electrocatalysis, has not been explored thus far. Such integration may even appear to be counterintuitive because OMC and C 60 provide opposite electrochemical benefits in terms of facilitating heterogeneous electron-transfer processes. Nevertheless, the present work demonstrates the integration of OMC and C 60 can provide a remarkable synergistic augmentation of the current. To illuminate the concept, eight kinds of inorganic and organic electroactive compounds were employed to study the electrochemical response at an OMC-C 60 modified glassy carbon (OMC-C 60/GC) electrode for the first time, which shows more favorable electron-transfer kinetics than OMC/GC, carbon nanotube modified GC, C 60/GC, and GC electrodes. Such electrocatalytic behavior at OMC-C 60/GC electrode could be attributed to the unique physicochemical properties of OMC and C 60, especially the unusual host-guest synergy of OMC-C 60, which induced a substantial decrease in the overvoltage for NADH oxidation compared with GC electrode. The ability of OMC-C 60 to promote electron transfer not only suggests a new platform for the development of dehydrogenase-based bioelectrochemical devices but also indicates a potential of OMC-C 60 to be of a wide range of sensing applications because the electrocatalysis of different electroactive compounds at the OMC-C 60/GC electrode in this work should be a good model for constructing a novel and promising electrochemical sensing platform for further electrochemical detection of

All-carbon suspended nanowire sensors as a rapid highly-sensitive label-free chemiresistive biosensing platform.

PubMed

Thiha, Aung; Ibrahim, Fatimah; Muniandy, Shalini; Dinshaw, Ignatius Julian; Teh, Swe Jyan; Thong, Kwai Lin; Leo, Bey Fen; Madou, Marc

2018-06-01

Nanowire sensors offer great potential as highly sensitive electrochemical and electronic biosensors because of their small size, high aspect ratios, and electronic properties. Nevertheless, the available methods to fabricate carbon nanowires in a controlled manner remain limited to expensive techniques. This paper presents a simple fabrication technique for sub-100 nm suspended carbon nanowire sensors by integrating electrospinning and photolithography techniques. Carbon Microelectromechanical Systems (C-MEMS) fabrication techniques allow fabrication of high aspect ratio carbon structures by patterning photoresist polymers into desired shapes and subsequent carbonization of resultant structures by pyrolysis. In our sensor platform, suspended nanowires were deposited by electrospinning while photolithography was used to fabricate support structures. We have achieved suspended carbon nanowires with sub-100 nm diameters in this study. The sensor platform was then integrated with a microfluidic chip to form a lab-on-chip device for label-free chemiresistive biosensing. We have investigated this nanoelectronics label-free biosensor's performance towards bacterial sensing by functionalization with Salmonella-specific aptamer probes. The device was tested with varying concentrations of Salmonella Typhimurium to evaluate sensitivity and various other bacteria to investigate specificity. The results showed that the sensor is highly specific and sensitive in detection of Salmonella with a detection limit of 10 CFU mL -1 . Moreover, this proposed chemiresistive assay has a reduced turnaround time of 5 min and sample volume requirement of 5 µL which are much less than reported in the literature. Copyright © 2018 Elsevier B.V. All rights reserved.

Cretaceous-Tertiary findings, paradigms and problems

NASA Technical Reports Server (NTRS)

Officer, C. B.; Drake, C. L.

1988-01-01

The asteroid hypothesis has stimulated numerous studies of the paleontological record at Cretaceous/Tertiary time as well as of geological indicators of environmental crisis preserved in the rock record. Both extinctions and geological anomalies often occur at times that do not appear to be synchronous or instantaneous. The record includes paleontological indicators of dinosaurs, terrestrial flora, marine planktonic organisms, and shallow water marine macrofauna and geological phenomena include occurrences of iridium and other platinum metals, trace elements, clay mineralogy, shocked minerals, soot, microspherules, and isotopes of osmium, strontium and carbon. These findings are reviewed in the context of the alternate hypotheses of an exogenic cause, involving either a single asteroid impact or multiple commentary impacts, and an endogenic cause, involving intense global volcanism and major sea level regression.

Island life in the Cretaceous - faunal composition, biogeography, evolution, and extinction of land-living vertebrates on the Late Cretaceous European archipelago

PubMed Central

Csiki-Sava, Zoltán; Buffetaut, Eric; Ősi, Attila; Pereda-Suberbiola, Xabier; Brusatte, Stephen L.

2015-01-01

Abstract The Late Cretaceous was a time of tremendous global change, as the final stages of the Age of Dinosaurs were shaped by climate and sea level fluctuations and witness to marked paleogeographic and faunal changes, before the end-Cretaceous bolide impact. The terrestrial fossil record of Late Cretaceous Europe is becoming increasingly better understood, based largely on intensive fieldwork over the past two decades, promising new insights into latest Cretaceous faunal evolution. We review the terrestrial Late Cretaceous record from Europe and discuss its importance for understanding the paleogeography, ecology, evolution, and extinction of land-dwelling vertebrates. We review the major Late Cretaceous faunas from Austria, Hungary, France, Spain, Portugal, and Romania, as well as more fragmentary records from elsewhere in Europe. We discuss the paleogeographic background and history of assembly of these faunas, and argue that they are comprised of an endemic ‘core’ supplemented with various immigration waves. These faunas lived on an island archipelago, and we describe how this insular setting led to ecological peculiarities such as low diversity, a preponderance of primitive taxa, and marked changes in morphology (particularly body size dwarfing). We conclude by discussing the importance of the European record in understanding the end-Cretaceous extinction and show that there is no clear evidence that dinosaurs or other groups were undergoing long-term declines in Europe prior to the bolide impact. PMID:25610343

Carbonate Formation And Diagenesis In Pastos Grandes Laguna (Bolivia): Modern Analog For The South Atlantic Cretaceous Presalt Travertinoid Deposits

NASA Astrophysics Data System (ADS)

Muller, E.; Ader, M.; Gérard, E.; Virgone, A.; Gaucher, E.; Bougeault, C.; Durlet, C.; Moreira, M. A.; Virgile, R.; Vennin, E.; Agogué, H.; Hugoni, M.

2017-12-01

The Cretaceous Presalt travertinoid deposits of the South Atlantic are usually considered as "strange deposits" having poor equivalents in modern environments. Pastos Grandes Laguna, which is located in a 2.9 Ma caldera on the andean-bolivian Altiplano (at 4450 m), is intersected by active faults with hydrothermal fluids and presents a spherulitic plateform with similar sedimentological facies to the Presalt: halite and bedded evaporites, shrub-shaped calcites, ooids, pisolites and various stromatolites. Pastos Grandes Laguna is certainly one of the best modern analog of the Presalt for investigating the on going processes of carbonate deposition and diagenesis and the influence of biology. During two expeditions, we recovered samples of gas, water and microbial mats from the hydrothermal sources to the evaporating zones on the spherulitic plateform. These samples are being analyzed to determine 1) the influence of the gases emitted at the hydrothermal sources (chemical and isotopic composition) on the chemistry of the Laguna and the mineralogy of its sediments and 2) the role of ecosystems that develop in this environment on carbonate formation. Preliminary results on gas composition, corrected for the atmospheric contribution, indicates a magmatic source of CO2 partly mantellic associated with a small crustal contribution. Other initial results have so far indicated that CO2 gas emissions, evaporation, as well as photosynthesis and respiration play a role on water chemistry and carbonate precipitation. This study will contribute to the overall understanding of the role of organisms in sedimentation and the predictive diagenetic evolution of hydrothermal and lacustrine deposits.

Paleomagnetic results from Northeast Anatolia: remagnetization in Late Cretaceous sandstones and tectonic rotation at the Eastern extension of the Izmir-Ankara-Erzincan suture zone

NASA Astrophysics Data System (ADS)

Cengiz Çinku, Mualla

2017-12-01

Paleomagnetic results obtained from Upper Cretaceous sandstones in Northeastern Anatolia demonstrate that the entire area from Erzincan to Kars has been remagnetised. The remagnetisation was acquired before the Middle Eocene collision between the Eastern Pontides and the Arabian Platform because Middle Eocene sandstones carry primary natural remanent magnetisations. The post-folding in situ mean direction of the Upper Cretaceous sandstones is compared with mean directions of younger, Middle Eocene to present rock formations. As a result, a two-stage antagonistic rotation mechanism is proposed. First, the collision between the Pontides and the Taurides between Late Cretaceous and Middle Eocene was associated by clockwise rotation of 26°. In the second stage between Middle Eocene and Middle Miocene and beyond, counterclockwise rotations up to 52° of the Pontide and Anatolide blocks and clockwise rotations of the Van Block were characterised by regional shortening and westward escape.

Distribution and tectonic implications of Cretaceous-Quaternary sedimentary facies in Solomon Islands

NASA Astrophysics Data System (ADS)

Turner, C. C.; Hughes, G. W.

1982-08-01

Sedimentary rocks of the Solomon Islands-Bougainville Arc are described in terms of nine widespread facies. Four facies associations are recognised by grouping facies which developed in broadly similar sedimentary environments. A marine pelagic association of Early Cretaceous to Miocene rocks comprises three facies. Facies Al: Early Cretaceous siliceous mudstone, found only on Malaita, is interpreted as deep marine siliceous ooze. Facies A2: Early Cretaceous to Eocene limestone with chert, overlies the siliceous mudstone facies, and is widespread in the central and eastern Solomons. It represents lithified calcareous ooze. Facies A3: Oligocene to Miocene calcisiltite with thin tuffaceous beds, overlies Facies A2 in most areas, and also occurs in the western Solomons. This represents similar, but less lithified calcareous ooze, and the deposits of periodic andesitic volcanism. An open marine detrital association of Oligocene to Recent age occurs throughout the Solomons. This comprises two facies. Facies B1 is variably calcareous siltstone, of hemipelagic origin; and Facies B2 consists of volcanogenic clastic deposits, laid down from submarine mass flows. A third association, of shallow marine carbonates, ranges in age from Late Oligocene to Recent. Facies C1 is biohermal limestone, and Facies C2 is biostromal calcarenite. The fourth association comprises areally restricted Pliocene to Recent paralic detrital deposits. Facies D1 includes nearshore clastic sediments, and Facies D2 comprises alluvial sands and gravels. Pre-Oligocene pelagic sediments were deposited contemporaneously with, and subsequent to, the extrusion of oceanic tholeiite. Island arc volcanism commenced along the length of the Solomons during the Oligocene, and greatly influenced sedimentation. Thick volcaniclastic sequences were deposited from submarine mass flows, and shallow marine carbonates accumulated locally. Fine grained graded tuffaceous beds within the marine pelagic association are

Early cretaceous dinosaurs from the sahara.

PubMed

Sereno, P C; Wilson, J A; Larsson, H C; Dutheil, D B; Sues, H D

1994-10-14

A major question in Mesozoic biogeography is how the land-based dinosaurian radiation responded to fragmentation of Pangaea. A rich fossil record has been uncovered on northern continents that spans the Cretaceous, when continental isolation reached its peak. In contrast, dinosaur remains on southern continents are scarce. The discovery of dinosaurian skeletons from Lower Cretaceous beds in the southern Sahara shows that several lineages of tetanuran theropods and broad-toothed sauropods had a cosmopolitan distribution across Pangaea before the onset of continental fragmentation. The distinct dinosaurian faunas of Africa, South America, and Asiamerica arose during the Cretaceous by differential survival of once widespread lineages on land masses that were becoming increasingly isolated from one another.

Late cretaceous pelagic sediments, volcanic ASH and biotas from near the Louisville hotspot, Pacific Plate, paleolatitude ∼42°S

USGS Publications Warehouse

Ballance, Peter F.; Barron, John A.; Blome, Charles D.; Bukry, David; Cawood, Peter A.; Chaproniere, George C.H.; Frisch, Robyn; Herzer, Richard H.; Nelson, Campbell S.; Quinterno, Paula; Ryan, Holly F.; Scholl, David W.; Stevenson, Andrew J.; Tappin, David G.; Vallier, Tracy L.

1989-01-01

Dredging on the deep inner slope of the Tonga Trench, immediately north of the intersection between the Louisville Ridge hotspot chain and the trench, recovered some Late Cretaceous (Maestrichtian) slightly tuffaceous pelagic sediments. They are inferred to have been scraped off a recently subducted Late Cretaceous guyot of the Louisville chain. In the vicinity of the Louisville hotspot (present location 50°26′S, 139°09′W; Late Cretaceous location ∼42°S, longitude unknown) Late Cretaceous rich diatom, radiolarian, silicoflagellate, foraminiferal and coccolith biotas, accumulated on the flanks of the guyot and are described in this paper. Rich sponge faunas are not described. ?Inoceramus prisms are present. Volcanic ash is of within-plate alkalic character. Isotope ratios in bulk carbonate δ18O − 2.63 to + 0.85, δ13C + 2.98 to 3.83) are normal for Pacific Maestrichtian sediments. The local CCD may have been shallower than the regional CCD, because of high organic productivity. In some samples Late Cretaceous materials have been mixed with Neogene materials. Mixing may have taken place on the flanks of the guyot during transit across the western Pacific, or on the trench slope during or after subduction and offscraping about 0.5 Ma.

Short Polarity Albian Events in the Cretaceous Normal Superchron - Magnetostratigraphy of the Morelos and Tlayua Formations (Mexico)

NASA Astrophysics Data System (ADS)

Benammi, M.; Urrutia-Fucugauchi, J.

2007-12-01

Interest in the long period of normal polarity in the Cretaceous has continued to increase since the early study of Helsley and Steiner (1969), who suspected that it corresponded to vast stretches of relatively low amplitude behaviour in the sea-floor magnetic anomaly profiles known informally as the "Cretaceous quiet zone". Since these first studies, paleomagnetists have continued to explore what is now known as the Cretaceous Normal Superchron, an interval of prolonged normal polarity from 118 to 84 Ma. Paleomagnetic data from sediment cores from the DSDP Holes 369, 386, and 364, were interpreted as brief reverse intervals (Keating and Helsley, 1978, 1979). Relatively fewer studies have been reported for land-based sections of pelagic and platform limestones; reports include studies in northern and central Italy (Vandenberg et al., 1978; Tarduno et al., 1992; Tarduno, 1990; Cronin et al., 2001) and Mexico (Urrutia-Fucugauchi, 1988; Benammi et al., 2006). We present here new magnetostratigraphic data for limestone sequences in central and southern Mexico from the Cretaceous Morelos and Tlayua Formations, which record short intervals of reversed polarity during the K normal superchron. The Morelos Formation has been revisited in Guerrero, southern Mexico, where the sequence of platform limestones with almost horizontal thick beds is well-exposed. The magnetostratigraphy shows dominant normal polarity for the sampled sections, with the occurrence of three short reverse polarity intervals corresponding to the Albian, which have been re-sampled and studied in additional detail for magnetic mineralogy and remanent acquisition. The Tlayua Formation is sampled in Tepeji de Rodriguez area, which is known for its rich and well-preserved fossil contents. Age control has mainly been provided from studies on ammonites, belemnites and benthic foraminifera (Cantu, 1987; Seibertz and Buitron, 1987; Kashiyama et al., 2003). Nine polarity intervals are documented in the Tlayua

Impact of stylolitization on diagenesis of a Lower Cretaceous carbonate reservoir from a giant oilfield, Abu Dhabi, United Arab Emirates

NASA Astrophysics Data System (ADS)

Paganoni, Matteo; Al Harthi, Amena; Morad, Daniel; Morad, Sadoon; Ceriani, Andrea; Mansurbeg, Howri; Al Suwaidi, Aisha; Al-Aasm, Ihsan S.; Ehrenberg, Stephen N.; Sirat, Manhal

2016-04-01

Bed-parallel stylolites are a widespread diagenetic feature in Lower Cretaceous limestone reservoirs, Abu Dhabi, United Arab Emirates (UAE). Diagenetic calcite, dolomite, kaolin and small amounts of pyrite, fluorite, anhydrite and sphalerite occur along and in the vicinity of the stylolites. Petrographic observations, negative δ18OVPDB, fluid inclusion microthermometry, and enrichment in 87Sr suggest that these cements have precipitated from hot basinal brines, which migrated along the stylolites and genetically related microfractures (tension gashes). Fluid migration was presumably related to lateral tectonic compression events related to the foreland basin formation. The low solubility of Al3 + in formation waters suggests that kaolin precipitation was linked to derivation of organic acids during organic matter maturation, probably in siliciclastic source rocks. The mass released from stylolitization was presumably re-precipitated as macro- and microcrystalline calcite cement in the host limestones. The flanks of the oilfield (water zone) display more frequent presence and higher amplitude of stylolites, lower porosity and permeability, higher homogenization temperatures and more radiogenic composition of carbonates compared to the crest (oil zone). This indicates that oil emplacement retards diagenesis. This study demonstrates that stylolitization plays a crucial role in fluid flow and diagenesis of carbonate reservoirs during basin evolution.

The Hunt for Pristine Cretaceous Astronomical Rhythms at Demerara Rise (Cenomanian-Coniacian)

NASA Astrophysics Data System (ADS)

Ma, C.; Meyers, S. R.

2014-12-01

Rhythmic Upper Cretaceous strata from Demerara Rise (ODP leg 207) preserve a strong astronomical signature, and this attribute has facilitated the development of continuous astrochronologies to refine the geologic time scale and calibrate Late Cretaceous biogeochemical events. While the mere identification of astronomical rhythms is a crucial first step in many deep-time paleoceanographic investigations, accurate evaluation of often subtle amplitude and frequency modulations are required to: (1) robustly constrain the linkage between climate and sedimentation, and (2) evaluate the plausibility of different theoretical astrodynamical models. The availability of a wide range of geophysical, lithologic and geochemical data from multiple sites drilled at Demerara Rise - when coupled with recent innovations in the statistical analysis of cyclostratigraphic data - provides an opportunity to hunt for the most pristine record of Cretaceous astronomical rhythms at a tropical Atlantic location. To do so, a statistical metric is developed to evaluate the "internal" consistency of hypothesized astronomical rhythms observed in each data set, particularly with regard to the expected astronomical amplitude modulations. In this presentation, we focus on how the new analysis yields refinements to the existing astrochronologies, provides constraints on the linkages between climate and sedimentation (including the deposition of organic carbon-rich sediments at Demerara Rise), and allows a quantitative evaluation of the continuity of deposition across sites at multiple temporal scales.

New Australian sauropods shed light on Cretaceous dinosaur palaeobiogeography

PubMed Central

Poropat, Stephen F.; Mannion, Philip D.; Upchurch, Paul; Hocknull, Scott A.; Kear, Benjamin P.; Kundrát, Martin; Tischler, Travis R.; Sloan, Trish; Sinapius, George H. K.; Elliott, Judy A.; Elliott, David A.

2016-01-01

Australian dinosaurs have played a rare but controversial role in the debate surrounding the effect of Gondwanan break-up on Cretaceous dinosaur distribution. Major spatiotemporal gaps in the Gondwanan Cretaceous fossil record, coupled with taxon incompleteness, have hindered research on this effect, especially in Australia. Here we report on two new sauropod specimens from the early Late Cretaceous of Queensland, Australia, that have important implications for Cretaceous dinosaur palaeobiogeography. Savannasaurus elliottorum gen. et sp. nov. comprises one of the most complete Cretaceous sauropod skeletons ever found in Australia, whereas a new specimen of Diamantinasaurus matildae includes the first ever cranial remains of an Australian sauropod. The results of a new phylogenetic analysis, in which both Savannasaurus and Diamantinasaurus are recovered within Titanosauria, were used as the basis for a quantitative palaeobiogeographical analysis of macronarian sauropods. Titanosaurs achieved a worldwide distribution by at least 125 million years ago, suggesting that mid-Cretaceous Australian sauropods represent remnants of clades which were widespread during the Early Cretaceous. These lineages would have entered Australasia via dispersal from South America, presumably across Antarctica. High latitude sauropod dispersal might have been facilitated by Albian–Turonian warming that lifted a palaeoclimatic dispersal barrier between Antarctica and South America. PMID:27763598

New Australian sauropods shed light on Cretaceous dinosaur palaeobiogeography.

PubMed

Poropat, Stephen F; Mannion, Philip D; Upchurch, Paul; Hocknull, Scott A; Kear, Benjamin P; Kundrát, Martin; Tischler, Travis R; Sloan, Trish; Sinapius, George H K; Elliott, Judy A; Elliott, David A

2016-10-20

Australian dinosaurs have played a rare but controversial role in the debate surrounding the effect of Gondwanan break-up on Cretaceous dinosaur distribution. Major spatiotemporal gaps in the Gondwanan Cretaceous fossil record, coupled with taxon incompleteness, have hindered research on this effect, especially in Australia. Here we report on two new sauropod specimens from the early Late Cretaceous of Queensland, Australia, that have important implications for Cretaceous dinosaur palaeobiogeography. Savannasaurus elliottorum gen. et sp. nov. comprises one of the most complete Cretaceous sauropod skeletons ever found in Australia, whereas a new specimen of Diamantinasaurus matildae includes the first ever cranial remains of an Australian sauropod. The results of a new phylogenetic analysis, in which both Savannasaurus and Diamantinasaurus are recovered within Titanosauria, were used as the basis for a quantitative palaeobiogeographical analysis of macronarian sauropods. Titanosaurs achieved a worldwide distribution by at least 125 million years ago, suggesting that mid-Cretaceous Australian sauropods represent remnants of clades which were widespread during the Early Cretaceous. These lineages would have entered Australasia via dispersal from South America, presumably across Antarctica. High latitude sauropod dispersal might have been facilitated by Albian-Turonian warming that lifted a palaeoclimatic dispersal barrier between Antarctica and South America.

Geology of the offshore Southeast Georgia Embayment, U.S. Atlantic continental margin, based on multichannel seismic reflection profiles

USGS Publications Warehouse

Buffler, Richard T.; Watkins, Joel S.; Dillon, William P.

1979-01-01

The sedimentary section is divided into three major seismic intervals. The intervals are separated by unconformities and can be mapped regionally. The oldest interval ranges in age from Early Cretaceous through middle Late Cretaceous, although it may contain Jurassic rocks where it thickens beneath the Blake Plateau. It probably consists of continental to nearshore clastic rocks where it onlaps basement and grades seaward to a restricted carbonate platform facies (dolomite-evaporite). The middle interval (Upper Cretaceous) is characterized by prograding clinoforms interpreted as open marine slope deposits. This interval represents a Late Cretaceous shift of the carbonate shelf margin from the Blake Escarpment shoreward to about its present location, probably due to a combination of co tinued subsidence, an overall Late Cretaceous rise in sea level, and strong currents across the Blake Plateau. The youngest (Cenozoic) interval represents a continued seaward progradation of the continental shelf and slope. Cenozoic sedimentation on the Blake Plateau was much abbreviated owing mainly to strong currents.

Carbonate platform, slope, and basinal deposits of Upper Oligocene, Kalimantan, Indonesia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Armin, R.A.; Cutler, W.G.; Mahadi, S.

1987-05-01

Upper Oligocene platform carbonates (Berai Formation) occur extensively on the Barito shelf in southeastern Kalimantan (Borneo) and are flanked northward by coeval slope and basinal deposits (Bongan Formation) which accumulated in the southwestern part of the Kutei basin. Isolated carbonate buildups equivalent to the Berai Formation also occur within the Kutei basin and were probably deposited on basement highs. The distribution of these facies is fairly well constrained by the study of outcrops, wells, and seismic profiles. The Berai Formation consists of diverse limestone types with a wide range of textures and with dominant skeletal components of large foraminifera, redmore » algae, and corals. Deposition of the Berai Formation occurred in moderate- and high-energy shallow-marine conditions. Slope and basin facies occur in extensional basins adjacent to the shelfal carbonates and peripheral to isolated carbonate buildups. Slope deposits consist of hemipelagic claystone, debris-flow conglomerate, calciturbidite, and volcaniclastic intervals. syndepositional downslope transport of slope deposits was an important process, as indicated by intervals containing redeposited debris flows, intraformational truncation surfaces, slide blocks, and associated shear planes. Recurrent movement on basin-margin faults and local volcanism probably perpetuated instability of slope deposits. Basinal deposits consist of calcareous claystone with intercalated thin, distal calciturbidite and volcaniclastic beds.« less

Lower Cretaceous Puez key-section in the Dolomites - towards the mid-Cretaceous super-greenhouse

NASA Astrophysics Data System (ADS)

Lukeneder, A.; Halásová, E.; Rehákova, D.; Józsa, Š.; Soták, J.; Kroh, A.; Jovane, L.; Florindo, F.; Sprovieri, M.; Giorgioni, M.; Lukeneder, S.

2012-04-01

Investigations on different fossil groups in addition to isotopic, paleomagnetic and geochemical analysis are combined to extract the Early Cretaceous history of environmental changes, as displayed by the sea level and climate changes. Results on biostratigraphy are integrated with other dating methods as magnetostraigraphy, correlation and cyclostratigraphy. The main investigation topics of the submitted project within the above-described framework are the biostratigraphic (Lukeneder and Aspmair, 2006, 2012), palaeoecological (Lukeneder, 2008, 2012), palaeobiogeographic, lithostratigraphic (Lukeneder, 2010, 2011), cyclostratigraphic and magnetostratigraphic development of the Early Cretaceous in the Puez area. The main sections occur in expanded outcrops located on the southern margin of the Puez Plateau, within the area of the Puez-Geisler Natural Park, in the northern part of the Dolomites (South Tyrol, North Italy). The cephalopod, microfossil and nannofossil faunas and floras from the marly limestones to marls here indicates Hauterivian to Albian/Cenomanian age. Oxygen isotope values from the Lower Cretaceous Puez Formation show a decreasing trend throughout the log, from -1.5‰ in the Hauterivian to -4.5‰ in the Albian/Cenomanian. The decreasing values mirror an increasing trend in palaeotemperatures from ~ 15-18°C in the Hauterivian up to ~25-30 °C in the Albian/Cenomanian. The trend probably indicates the positive shift in temperature induced by the well known Mid Cretaceous Ocean warming (e.g., Super-Greenhouse). The cooperative project (FWF project P20018-N10; 22 international scientists): An integrative high resolution project. Macro- and microfossils, isotopes, litho-, cyclo-, magneto-and biostratigraphy as tools for investigating the Lower Cretaceous within the Dolomites (Southern Alps, Northern Italy) -The Puez area as a new key region of the Tethyan Realm), is on the way since 2008 by the Natural History Museum in Vienna and the 'Naturmuseum S�

Mid-Eocene (Bartonian) larger benthic foraminifera from southeastern Turkey and northeastern Egypt: New evidence for the palaeobiogeography of the Tethyan carbonate platforms

NASA Astrophysics Data System (ADS)

Sallam, Emad S.; Erdem, Nazire Özgen; Sinanoğlu, Derya; Ruban, Dmitry A.

2018-05-01

Larger benthic foraminiferal assemblages from the mid-Eocene (Bartonian) sedimentary successions of the Tethyan carbonate platforms have been studied in southeastern Turkey and northeastern Egypt. In the Hazro-Diyarbakir section (SE Turkey), small-medium miliolids and textularinids are identified from the lower intervals of the Hoya Formation, whereas alveolinids and soritids (porcellaneous) and orbitolinids (agglutinated) increase in diversity and abundance in the upper intervals. The Dictyoconus aegyptiensis (Chapman) and Somalina stefaninii Silvestri are recorded for the first time from the Hoya Formation. The larger benthic foraminiferal assemblage from the Hoya Formation shows a significant similarity to those reported from the Observatory Formation (coeval with the Sannor Formation) in the Cairo-Suez district (NE Egypt). The studied foraminiferal assemblages imply restricted lagoonal-tidal flat palaeoenvironments. Palaeobiogeographically, the larger benthic foraminiferal assemblages recorded in southeastern Turkey and northeastern Egypt carbonate platforms display a strong affinity to the Arabian, Middle East and African platforms. The position of the global sea-level and the plate tectonic organization of the studied region during the Bartonian were the main factors that facilitated faunal exchange within the carbonate platforms.

The Oligocene carbonate platform of the Zagros Basin, SW Iran: An assessment of highly-complex geological heritage

NASA Astrophysics Data System (ADS)

Habibi, Tahereh; Ruban, Dmitry A.

2017-05-01

North Africa and the Middle East possess rich geological heritage, but the latter is yet to be fully identified and described. The Oligocene carbonate platform of the Zagros Basin in southwest Iran, which corresponds to the lower part of the Asmari Formation, has significant potential for geoconservation and geotourism. The types of the geological heritage, their value, and the possible geosites have been assessed. The studied deposits are interesting because of lithology (carbonate rocks), fossils (larger foraminifera, other microfossils, diverse marine invertebrates, fish microremains, and trace fossils), biostratigraphical developments, facies (homoclinal carbonate ramp) and signature of global events (glacioeustatic fluctuations), and outstanding hydrocarbon resources. The five main geological heritage types are sedimentary, palaeontological, stratigraphical, palaeogeographical, and economical, from which the palaeontological, palaeogeographical, and economical types are of global rank. The Khollar and Kavar sections in the Fars Province of Iran are recommended as geosites suitable for research, education, and tourism. The high complexity of the geological heritage linked to the Oligocene carbonate platform of the Zagros Basin implies the phenomenon of geodiversity should be understood with regard to the relationships between types and their values.

Resolving carbonate platform geometries on the Island of Bonaire, Caribbean Netherlands through semi-automatic GPR facies classification

NASA Astrophysics Data System (ADS)

Bowling, R. D.; Laya, J. C.; Everett, M. E.

2018-07-01

The study of exposed carbonate platforms provides observational constraints on regional tectonics and sea-level history. In this work Miocene-aged carbonate platform units of the Seroe Domi Formation are investigated on the island of Bonaire, located in the Southern Caribbean. Ground penetrating radar (GPR) was used to probe near-surface structural geometries associated with these lithologies. The single cross-island transect described herein allowed for continuous mapping of geologic structures on kilometre length scales. Numerical analysis was applied to the data in the form of k-means clustering of structure-parallel vectors derived from image structure tensors. This methodology enables radar facies along the survey transect to be semi-automatically mapped. The results provide subsurface evidence to support previous surficial and outcrop observations, and reveal complex stratigraphy within the platform. From the GPR data analysis, progradational clinoform geometries were observed on the northeast side of the island which support the tectonics and depositional trends of the region. Furthermore, several leeward-side radar facies are identified which correlate to environments of deposition conducive to dolomitization via reflux mechanisms.

Resolving Carbonate Platform Geometries on the Island of Bonaire, Caribbean Netherlands through Semi-Automatic GPR Facies Classification

NASA Astrophysics Data System (ADS)

Bowling, R. D.; Laya, J. C.; Everett, M. E.

2018-05-01

The study of exposed carbonate platforms provides observational constraints on regional tectonics and sea-level history. In this work Miocene-aged carbonate platform units of the Seroe Domi Formation are investigated, on the island of Bonaire, located in the Southern Caribbean. Ground penetrating radar (GPR) was used to probe near-surface structural geometries associated with these lithologies. The single cross-island transect described herein allowed for continuous mapping of geologic structures on kilometer length scales. Numerical analysis was applied to the data in the form of k-means clustering of structure-parallel vectors derived from image structure tensors. This methodology enables radar facies along the survey transect to be semi-automatically mapped. The results provide subsurface evidence to support previous surficial and outcrop observations, and reveal complex stratigraphy within the platform. From the GPR data analysis, progradational clinoform geometries were observed on the northeast side of the island which supports the tectonics and depositional trends of the region. Furthermore, several leeward-side radar facies are identified which correlate to environments of deposition conducive to dolomitization via reflux mechanisms.

Cretaceous Vertebrate Tracksites - Korean Cretaceous Dinosaur Coast World Heritage Nomination Site

NASA Astrophysics Data System (ADS)

Huh, M.; Woo, K. S.; Lim, J. D.; Paik, I. S.

2009-04-01

South Korea is one of the best known regions in the world for Cretaceous fossil footprints, which are also world-renowned. Korea has produced more scientifically named bird tracks (ichnotaxa) than any other region in the world. It has also produced the world's largest pterosaur tracks. Dinosaur tracksites also have the highest frequency of vertebrate track-bearing levels currently known in any stratigraphic sequence. Among the areas that have the best track records, and the greatest scientific significance with best documentation, Korea ranks very highly. Objective analysis of important individual tracksites and tracksite regions must be based on multiple criteria including: size of site, number of tracks, trackways and track bearing levels, number of valid named ichnotaxa including types, number of scientific publications, quality of preservation. The unique and distinctive dinosaur tracksites are known as one of the world's most important dinosaur track localities. In particular, the dinosaur track sites in southern coastal area of Korea are very unique. In the sites, we have excavated over 10,000 dinosaur tracks. The Hwasun sites show diverse gaits with unusual walking patterns and postures in some tracks. The pterosaur tracks are the most immense in the world. The longest pterosaur trackway yet known from any track sites suggests that pterosaurs were competent terrestrial locomotors. This ichnofauna contains the first pterosaur tracks reported from Asia. The Haenam Uhangri pterosaur assigns to a new genus Haenamichnus which accomodates the new ichnospecies, Haenamichnus uhangriensis. At least 12 track types have been reported from the Haman and Jindong Formations (probably late Lower Cretaceous). These include the types of bird tracks assigned to Koreanornis, Jindongornipes, Ignotornis and Goseongornipes. In addition the bird tracks Hwangsanipes, Uhangrichnus, the pterosaur track Haenamichnus and the dinosaur tracks, Brontopodus, Caririchnium, Minisauripus and

Geologic assessment of undiscovered oil and gas resources in Aptian carbonates, onshore northern Gulf of Mexico Basin, United States

USGS Publications Warehouse

Hackley, Paul C.; Karlsen, Alexander W.

2014-01-01

Carbonate lithofacies of the Lower Cretaceous Sligo Formation and James Limestone were regionally evaluated using established U.S. Geological Survey (USGS) assessment methodology for undiscovered conventional hydrocarbon resources. The assessed area is within the Upper Jurassic–Cretaceous–Tertiary Composite total petroleum system, which was defined for the assessment. Hydrocarbons reservoired in carbonate platform Sligo-James oil and gas accumulations are interpreted to originate primarily from the Jurassic Smackover Formation. Emplacement of hydrocarbons occurred via vertical migration along fault systems; long-range lateral migration also may have occurred in some locations. Primary reservoir facies include porous patch reefs developed over paleostructural salt highs, carbonate shoals, and stacked linear reefs at the carbonate shelf margin. Hydrocarbon traps dominantly are combination structural-stratigraphic. Sealing lithologies include micrite, calcareous shale, and argillaceous lime mudstone. A geologic model, supported by discovery history analysis of petroleum geology data, was used to define a single regional assessment unit (AU) for conventional reservoirs in carbonate facies of the Sligo Formation and James Limestone. The AU is formally entitled Sligo-James Carbonate Platform Oil and Gas (50490121). A fully risked mean undiscovered technically recoverable resource in the AU of 50 million barrels of oil (MMBO), 791 billion cubic feet of natural gas (BCFG), and 26 million barrels of natural gas liquids was estimated. Substantial new development through horizontal drilling has occurred since the time of this assessment (2010), resulting in cumulative production of >200 BCFG and >1 MMBO.

On the age of the Jurassic-Cretaceous boundary

NASA Astrophysics Data System (ADS)

Lena, Luis; Ramos, Victor; Pimentel, Marcio; Aguirre-Urreta, Beatriz; Naipauer, Maximiliano; Schaltegger, Urs

2017-04-01

Calibrating the geologic time is of utmost importance to understanding geological and biological processes throughout Earth history. The Jurassic-Cretaceous boundary has proven to be one of the most problematic boundaries to calibrate in the geologic time. The present definition of the Jurassic-Cretaceous boundary still remains contentious mainly because of the dominant endemic nature of the flora and fauna in stratigraphic sections, which hinders an agreement on a GSSP. Consequently, an absolute and precise age for the boundary is yet to meet an agreement among the community. Additionally, integrating chemical, paleomagnetic or astronomical proxies to aid the definition of the boundary has also proven to be difficult because the boundary lacks any abrupt geochemical changes or recognizable geological events. However, the traditional Berriasella jacobi Subzone is disregarded as a primary marker and the use of calpionellids has been gaining momentum for defining the boundary. The Jurassic Cretaceous boundary in the Vaca Muerta Fm. in the Nuequen Basin of the Andes is a potential candidate for the boundary stratotype because of its high density of ammonites, nannofossils and interbedded datable horizons. Consequently, the Jurassic-Cretaceous boundary is very well defined in the Vaca Muerta Fm. On the basis of both ammonites and nannofossils. Here we present new high-precision U-Pb age determinations from two volcanic ash beds that bracket the age of the Jurassic-Cretaceous boundary: 1) ash bed LLT_14_9, with a 206Pb/238U age of 139.7 Ma, which is 2 meters above Jurassic-Cretaceous boundary based on the Argetiniceras noduliferum (Early Berriasian ) and Substeueroceras Koeneni (Late Tithonian) ammonites zone; and 2) bed LLT_14_10, with an age of 140.1 Ma, located 3m below the J-K boundary based on last occurrence of the nannofossils N. kamptneri minor and N. steinmanni minor. Therefore, we propose that the age of the Jurassic-Cretaceous boundary should be close to 140

DCO-VIVO: A Collaborative Data Platform for the Deep Carbon Science Communities

NASA Astrophysics Data System (ADS)

Wang, H.; Chen, Y.; West, P.; Erickson, J. S.; Ma, X.; Fox, P. A.

2014-12-01

Deep Carbon Observatory (DCO) is a decade-long scientific endeavor to understand carbon in the complex deep Earth system. Thousands of DCO scientists from institutions across the globe are organized into communities representing four domains of exploration: Extreme Physics and Chemistry, Reservoirs and Fluxes, Deep Energy, and Deep Life. Cross-community and cross-disciplinary collaboration is one of the most distinctive features in DCO's flexible research framework. VIVO is an open-source Semantic Web platform that facilitates cross-institutional researcher and research discovery. it includes a number of standard ontologies that interconnect people, organizations, publications, activities, locations, and other entities of research interest to enable browsing, searching, visualizing, and generating Linked Open (research) Data. The DCO-VIVO solution expedites research collaboration between DCO scientists and communities. Based on DCO's specific requirements, the DCO Data Science team developed a series of extensions to the VIVO platform including extending the VIVO information model, extended query over the semantic information within VIVO, integration with other open source collaborative environments and data management systems, using single sign-on, assigning of unique Handles to DCO objects, and publication and dataset ingesting extensions using existing publication systems. We present here the iterative development of these requirements that are now in daily use by the DCO community of scientists for research reporting, information sharing, and resource discovery in support of research activities and program management.

Lateral variations of carbonate platform facies and cycles: The Dachstein Limestone (Late Triassic, Northern Calcareous Alps, Austria)

NASA Astrophysics Data System (ADS)

Samankassou, Elias; Enos, Paul

2017-04-01

The driving mechanisms of cyclic patterns in shallow-water platform carbonates remain controversial. The focus of the present paper is to quantify lateral facies variations for a long stratigraphic record in an extensive, continuous, well-exposed cliff of the Dachstein platform that is composed, as many other Phanerozoic carbonate platforms, of peritidal deposits. We noted the lateral continuity of the beds to the degree permitted by the outcrop, generally a few tens or hundreds of meters; exceptionally up to 1.7 km. The study demonstrates the importance of quantification to evaluate origins of sedimentary cycles. The upper 885 m of the Triassic Dachstein platform limestone at Steinernes Meer, Saalfelden, Austria, includes 241 peritidal cycles overlain by 275 m of subtidal, non-cyclic and weakly cyclic limestone. Of 558 subtidal and intertidal beds measured, 121 (21.7%) disappear laterally. An additional 74 beds (13.3%) show significant (>10%) lateral variations in thickness. Mean thickness variation is 50%. Both lateral variations and discontinuities appear to lack a spatial vector. Disappearances toward the inferred platform interior (west), total 10.4% of the beds. East toward the inferred platform margin 11.3% of the beds disappear. Thickness changes occur in 6.6% of beds in each direction. The lack of lateral continuity of beds is consistent with a non-eustatic component to stratification. Erosion of intertidal intervals is the process that can be most readily documented. Erosion, transport, and non-uniform distribution of sediments, superposed on stratigraphic sequences driven by eustacy, are the likely processes which produced the complex, randomly recorded cycle patterns. Cycle duration may not be exclusively determined by Milankovitch processes, as suggested by the discrepancies in the cycle duration and interpretation among stratigraphers of the Dachstein, as well as other Phanerozoic carbonate platforms. Signals deduced from linearly measured sections

Carbon dots rooted agarose hydrogel hybrid platform for optical detection and separation of heavy metal ions.

PubMed

Gogoi, Neelam; Barooah, Mayuri; Majumdar, Gitanjali; Chowdhury, Devasish

2015-02-11

A robust solid sensing platform for an on-site operational and accurate detection of heavy metal is still a challenge. We introduce chitosan based carbon dots rooted agarose hydrogel film as a hybrid solid sensing platform for detection of heavy metal ions. The fabrication of the solid sensing platform is centered on simple electrostatic interaction between the NH3+ group present in the carbon dots and the OH- groups present in agarose. Simply on dipping the hydrogel film strip into the heavy metal ion solution, in particular Cr6+, Cu2+, Fe3+, Pb2+, Mn2+, the strip displays a color change, viz., Cr6+→yellow, Cu2+→blue, Fe3+→brown, Pb2+→white, Mn2+→tan brown. The optical detection limit of the respective metal ion is found to be 1 pM for Cr6+, 0.5 μM for Cu2+, and 0.5 nM for Fe3+, Pb2+, and Mn2+ by studying the changes in UV-visible reflectance spectrum of the hydrogel film. Moreover, the hydrogel film finds applicability as an efficient filtration membrane for separation of these quintet heavy metal ions. The strategic fundamental feature of this sensing platform is the successful capability of chitosan to form colored chelates with transition metals. This proficient hybrid hydrogel solid sensing platform is thus the most suitable to employ as an on-site operational, portable, cheap colorimetric-optical detector of heavy metal ion with potential skill in their separation. Details of the possible mechanistic insight into the colorimetric detection and ion separation are also discussed.

The origin and early evolution of metatherian mammals: the Cretaceous record.

PubMed

Williamson, Thomas E; Brusatte, Stephen L; Wilson, Gregory P

2014-01-01

Metatherians, which comprise marsupials and their closest fossil relatives, were one of the most dominant clades of mammals during the Cretaceous and are the most diverse clade of living mammals after Placentalia. Our understanding of this group has increased greatly over the past 20 years, with the discovery of new specimens and the application of new analytical tools. Here we provide a review of the phylogenetic relationships of metatherians with respect to other mammals, discuss the taxonomic definition and diagnosis of Metatheria, outline the Cretaceous history of major metatherian clades, describe the paleobiology, biogeography, and macroevolution of Cretaceous metatherians, and provide a physical and climatic background of Cretaceous metatherian faunas. Metatherians are a clade of boreosphendian mammals that must have originated by the Late Jurassic, but the first unequivocal metatherian fossil is from the Early Cretaceous of Asia. Metatherians have the distinctive tightly interlocking occlusal molar pattern of tribosphenic mammals, but differ from Eutheria in their dental formula and tooth replacement pattern, which may be related to the metatherian reproductive process which includes an extended period of lactation followed by birth of extremely altricial young. Metatherians were widespread over Laurasia during the Cretaceous, with members present in Asia, Europe, and North America by the early Late Cretaceous. In particular, they were taxonomically and morphologically diverse and relatively abundant in the Late Cretaceous of western North America, where they have been used to examine patterns of biogeography, macroevolution, diversification, and extinction through the Late Cretaceous and across the Cretaceous-Paleogene (K-Pg) boundary. Metatherian diversification patterns suggest that they were not strongly affected by a Cretaceous Terrestrial Revolution, but they clearly underwent a severe extinction across the K-Pg boundary.

Oman's low latitude "Snowball Earth" pole revisited: Late Cretaceous remagnetisation of Late Neoproterozoic carbonates in Northern Oman

NASA Astrophysics Data System (ADS)

Rowan, C. J.; Tait, J.

2010-12-01

Glaciogenic diamictites and associated ‘cap’ carbonates within the Neoproterozoic Huqf Supergroup of Oman record a period of extreme, possibly global, glaciations between 750-635 Ma (the "Snowball Earth"). We have performed high-resolution paleomagnetic sampling of two sections through ~635 Ma cap carbonates in the Jebel Akhdar region of northern Oman. Stepwise thermal demagnetisation reveals a low temperature component carried by goethite, and a high temperature component carried by haematite, that are both aligned with the modern dipole field direction. Occasional reversed polarity directions antipodal to the present day field indicate pervasive weathering of these outcrops over timescales of at least 1 Ma. Between these two overprints an intermediate component with typical unblocking temperatures of 300-550 C, probably carried by magnetite, can also be isolated in most samples. A robust fold test clearly demonstrates that this component was acquired after Paleozoic folding of the carbonates, and was most likely acquired during exhumation associated with emplacement of the Semail ophiolite during the Late Cretaceous (95-68 Ma). In geographic co-ordinates, the intermediate component has an almost horizontal NNW or SSE direction, similar to directions previously reported from outcrops of the ophiolite close to the Jebel Akhdar region, and from thermally altered basement rocks in the the Saih Hatat window further to the east [Feinberg et al. 1999]. Hints of an older, Permian, remagnetisation of the carbonates, which is also observed in the Saih Hatat basement rocks, have also produced a false polarity stratigraphy in one of the sampled sections. Our results contrast with the previously reported low latitude pole from the Huqf Supergroup [Kilner et al., 2005], which was considered to be amongst the more reliable paleomagnetic data supporting glaciations extending to low latitudes during the late Neoproterozoic. However, this interpretation was made on the basis

Mineralogy of Cretaceous/Tertiary boundary clays in the Chicxulub structure in northern Yucatan

NASA Technical Reports Server (NTRS)

Ming, D. W.; Sharpton, Virgil L.; Schuraytz, B. C.

1991-01-01

The Cretaceous/Tertiary (K/T) boundary clay layer is thought to be derived from ejecta material from meteorite impact, based on the anomalous concentrations of noble metals in the layer. Because of recent findings of a half-meter thick ejecta deposit at the K/T boundary in Haiti, efforts have focused on locating a large impact feature in the Caribbean and the Gulf of Mexico. One of the leading candidates for the site of a large impact is the Chicxulub structure located on the northern Yucatan Peninsula in Mexico. The Chicxulub structure is a subsurface zone of upper Cretaceous igneous rocks, carbonates, and breccias. The structure has been interpreted to be a 200 km diameter; however, there is some question to the size of the structure or to the fact that it even is an impact feature. Little is known about the mineralogy of this structure; the objective of this study was to determine the clay mineralogy of core samples from within the Chicxulub structure.

Diatom microfossils from cretaceous and eocene sediments contain native silica precipitating long-chain polyamines.

PubMed

Bridoux, M C; Ingalls, A E

2013-05-01

Organic molecules from known biological sources (biomarkers) that are preserved over geological time are critical tools in the study of past conditions and events on earth. Polar molecules are typically recycled rapidly in marine environments and do not survive burial within aquatic sediments in unambiguously recognizable form. As such, geological biomarkers are formed almost exclusively from precursor biomolecules that have been altered, limiting their utility as paleoproxies. Here, we report that nitrogen-rich aliphatic long-chain polyamines (LCPAs), biosynthesized by diatoms in species-specific assemblages for the precipitation of nanopatterned siliceous cell walls (frustules), are preserved unaltered in the oldest available diatom fossils dating to the Lower Cretaceous (early Albian, 115-110 Ma). We further show that the cumulative LCPA pool accounts for 60% of the total C and 80% of the total N preserved in the Cretaceous age sediments. We suggest that silica glass formation by diatoms constitutes an important preservation mechanism for source-specific, polar biomolecules, protecting them indefinitely by encapsulation within the silicified frustule. LCPAs are a unique, source-specific carbon and nitrogen archive of diatom biomass, offering a promising tool for reconstruction of global cycles of carbon and nitrogen over geological timescales. © 2013 Blackwell Publishing Ltd.

Carbon nanostructures as immobilization platform for DNA: A review on current progress in electrochemical DNA sensors.

PubMed

Rasheed, P Abdul; Sandhyarani, N

2017-11-15

Development of a sensitive, specific and cost-effective DNA detection method is motivated by increasing demand for the early stage diagnosis of genetic diseases. Recent developments in the design and fabrication of efficient sensor platforms based on nanostructures make the highly sensitive sensors which could indicate very low detection limit to the level of few molecules, a realistic possibility. Electrochemical detection methods are widely used in DNA diagnostics as it provide simple, accurate and inexpensive platform for DNA detection. In addition, the electrochemical DNA sensors provide direct electronic signal without the use of expensive signal transduction equipment and facilitates the immobilization of single stranded DNA (ssDNA) probe sequences on a wide variety of electrode substrates. It has been found that a range of nanomaterials such as metal nanoparticles (MNPs), carbon based nanomaterials, quantum dots (QDs), magnetic nanoparticles and polymeric NPs have been introduced in the sensor design to enhance the sensing performance of electrochemical DNA sensor. In this review, we discuss recent progress in the design and fabrication of efficient electrochemical genosensors based on carbon nanostructures such as carbon nanotubes, graphene, graphene oxide and nanodiamonds. Copyright © 2017 Elsevier B.V. All rights reserved.

Metre-scale cyclicity in Middle Eocene platform carbonates in northern Egypt: Implications for facies development and sequence stratigraphy

NASA Astrophysics Data System (ADS)

Tawfik, Mohamed; El-Sorogy, Abdelbaset; Moussa, Mahmoud

2016-07-01

The shallow-water carbonates of the Middle Eocene in northern Egypt represent a Tethyan reef-rimmed carbonate platform with bedded inner-platform facies. Based on extensive micro- and biofacies documentation, five lithofacies associations were defined and their respective depositional environments were interpreted. Investigated sections were subdivided into three third-order sequences, named S1, S2 and S3. Sequence S1 is interpreted to correspond to the Lutetian, S2 corresponds to the Late Lutetian and Early Bartonian, and S3 represents the Late Bartonian. Each of the three sequences was further subdivided into fourth-order cycle sets and fifth-order cycles. The complete hierarchy of cycles can be correlated along 190 km across the study area, and highlighting a general "layer-cake" stratigraphic architecture. The documentation of the studied outcrops may contribute to the better regional understanding of the Middle Eocene formations in northern Egypt and to Tethyan pericratonic carbonate models in general.

Cool episode and platform demise in the Early Aptian: New insights on the links between climate and carbonate production

NASA Astrophysics Data System (ADS)

Bonin, Aurélie; Pucéat, Emmanuelle; Vennin, Emmanuelle; Mattioli, Emanuela; Aurell, Marcos; Joachimski, Michael; Barbarin, Nicolas; Laffont, Rémi

2016-01-01

The Early Aptian encountered several crises in neritic and pelagic carbonate production, major perturbations in the carbon cycle, and an oceanic anoxic event (OAE1a). Yet the causal links between these perturbations and climate changes remain poorly understood, partly because temperature records spanning the Early Aptian interval are still scant. We present new δ18O data from well-preserved bivalves from a carbonate platform of the Galve subbasin (Spain) that document a major cooling event postdating most of OAE1a. Our data show that cooling postdates the global platform demise and cannot have triggered this event that occurred during the warmest interval. The warmest temperatures coincide with the time equivalent of OAE1a and with platform biotic assemblages dominated by microbialites at Aliaga as well as on other Tethyan platforms. Coral-dominated assemblages then replace microbialites during the subsequent cooling. Nannoconids are absent during most of the time equivalent of the OAE1a, probably related to the well-known crisis affecting this group. Yet they present a transient recovery in the upper part of this interval with an increase in both size and abundance during the cool interval portion that postdates OAE1a. An evolution toward cooler and drier climatic conditions may have induced the regional change from microbial to coral assemblages as well as nannoconids size and abundance increase by limiting continent-derived input of nutrients.

The Zambezi sedimentary system (coastal plain - deep sea fan): a record of the vertical movements of the Mozambican margin since Cretaceous times.

NASA Astrophysics Data System (ADS)

Ponte, Jean Pierre; Robin, Cecile; Guillocheau, Francois; Baby, Guillaume; Dall'Asta, Massimo; Popescu, Speranta; Suc, Jean Pierre; Droz, Laurence; Rabineau, Marina; Moulin, Maryline

2016-04-01

The Mozambique margin is an oblique to transform margin which feeds one of the largest African turbiditic system, the Zambezi deep-sea fan (1800 km length and 400 km wide; Droz and Mougenot., AAPG Bull., 1987). The Zambezi sedimentary system is characterized by (1) a changing catchment area through time with evidences of river captures (Thomas and Shaw, J. Afr. Earth. Sci, 1988) and (2) a delta, storing more than 12 km of sediment, with no gravitary tectonics. The aim of this study is to carry out a source to sink study along the Zambezi sedimentary system and to analyse the margin evolution (vertical movements, climate change) since Early Cretaceous times. The used data are seismic lines (industrial and academic) and petroleum wells (with access to the cuttings). Our first objective was to perform a new biochronostratigraphic framework based on nannofossils, foraminifers, pollen and spores on the cuttings of three industrial wells. The second target was to recognize the different steps of the growth of the Zambezi sedimentary systems. Four main phases were identified: • Late Jurassic (?) - early Late Cretaceous: from Neocomian to Aptian times, the high of the clinoforms is getting higher, with the first occurrence of contouritic ridges during Aptian times. • Late Cretaceous - Early Paleocene: a major drop of relative sea-level occurred as a consequence of the South African Plateau uplift. The occurrence of two depocenters suggests siliciclastic supplies from the Bushveld and from the North Mozambique domain. • Early Paleocene - Eocene: growth of carbonate platforms and large contouritic ridges. • Oligocene - Present-day: birth of the modern Zambezi Delta, with quite low siliciclastic supply during Oligocene times, increasing during Miocene times. As previously expected (Droz and Mougenot) some sediments of the so-called Zambezi fans are coming from a feeder located east of the Davie Ridge. This study was founded by TOTAL and IFREMER in the frame of the

Are glendonites reliable indicators of cold conditions? Evidence from the Lower Cretaceous of Spitsbergen

NASA Astrophysics Data System (ADS)

Vickers, Madeleine; Price, Gregory; Watkinson, Matthew; Jerrett, Rhodri

2017-04-01

Glendonites are pseudomorphs after the mineral ikaite, and have been found in marine sediments throughout geological time. Ikaite is a metastable, hydrated form of calcium carbonate, which is only stable under specific conditions: between -2 and +5 °C, and with high alkalinity and phosphate concentrations. Glendonites are often associated with cold climates due to the strong temperature control on ikaite growth, and the coincidence in the geological record with episodes of global cooling. Glendonites are found in the Lower Cretaceous succession in Spitsbergen. During the Early Cretaceous, Spitsbergen was at a palaeolatitude of 60°N, and was part of a shallow epicontinental sea that formed during the Mesozoic as Atlantic rifting propagated northwards. Though the Early Cretaceous was generally characterised by greenhouse climate conditions, episodic cold snaps occurred during the Valanginian (the "Weissert Event") and during Aptian-Albian. Using high resolution carbon-isotope stratigraphy, we show that the first occurrences of glendonites are in the upper Lower Hauterivian and in the very upper Upper Hauterivian, stratigraphically higher than the Valanginian cooling event. Glendonites are also found in horizons in the Upper Aptian, coincident with the Aptian-Albian cold snap. Petrological analysis of the glendonite structure reveals differences between the Hauterivian and Aptian glendonites, with evidence for multiple diagenetic phases of growth in the Hauterivian glendonites, suggesting oscillating chemical conditions. This evidence suggests that local environmental conditions may have a stronger control on glendonite formation and preservation than global climate. We present a new model for ikaite growth and slow transformation to glendonite in marine sediments, which points to a more complex suite of diagenetic transformations than previously modelled. Furthermore, we critically assess whether such pseudomorphs after marine sedimentary ikaite may be indicators

The origin and early evolution of metatherian mammals: the Cretaceous record

PubMed Central

Williamson, Thomas E.; Brusatte, Stephen L.; Wilson, Gregory P.

2014-01-01

Abstract Metatherians, which comprise marsupials and their closest fossil relatives, were one of the most dominant clades of mammals during the Cretaceous and are the most diverse clade of living mammals after Placentalia. Our understanding of this group has increased greatly over the past 20 years, with the discovery of new specimens and the application of new analytical tools. Here we provide a review of the phylogenetic relationships of metatherians with respect to other mammals, discuss the taxonomic definition and diagnosis of Metatheria, outline the Cretaceous history of major metatherian clades, describe the paleobiology, biogeography, and macroevolution of Cretaceous metatherians, and provide a physical and climatic background of Cretaceous metatherian faunas. Metatherians are a clade of boreosphendian mammals that must have originated by the Late Jurassic, but the first unequivocal metatherian fossil is from the Early Cretaceous of Asia. Metatherians have the distinctive tightly interlocking occlusal molar pattern of tribosphenic mammals, but differ from Eutheria in their dental formula and tooth replacement pattern, which may be related to the metatherian reproductive process which includes an extended period of lactation followed by birth of extremely altricial young. Metatherians were widespread over Laurasia during the Cretaceous, with members present in Asia, Europe, and North America by the early Late Cretaceous. In particular, they were taxonomically and morphologically diverse and relatively abundant in the Late Cretaceous of western North America, where they have been used to examine patterns of biogeography, macroevolution, diversification, and extinction through the Late Cretaceous and across the Cretaceous-Paleogene (K-Pg) boundary. Metatherian diversification patterns suggest that they were not strongly affected by a Cretaceous Terrestrial Revolution, but they clearly underwent a severe extinction across the K-Pg boundary. PMID:25589872

Mid-Mesozoic (Mid-Jurassic to Early Cretaceous) evolution of the Georges Bank Basin, U.S. North Atlantic outer continental shelf: Sedimentology of the Conoco 145-1 well

USGS Publications Warehouse

Poppe, L.J.; Poag, C.W.; Stanton, R.W.

1992-01-01

The Conoco 145-1 exploratory well, located in the southeastern portion of the Georges Bank Basin, was drilled to a total depth of 4303 m below the sea floor. The oldest sedimentary rocks sampled are of Middle Jurassic age (Late Bathonian-Callovian). A dolomite-limestone-evaporite sequence dominates the section below 3917 m; limestone is the predominant lithology in the intervals of 3271-3774 m, 2274-3158 m, and 1548-1981 m. Siliciclastics dominate the remainder of the drilled section. Calcite tightly cements most of the rocks below 1548 m; dolomite, silica, siderite, and diagenetic clay cements are locally important. Restricted inner marine environments, representing lagoonal and tidal flat conditions, prevailed at the wellsite during much of the deposition recorded by the Callovian-Bathonian age Iroquois Formation. These environments gave way to a carbonate platform, which formed part of the > 5,000 km long Bahama-Grand Banks gigaplatform that lasted through the end of the Late Jurassic (encompassing the uppermost portion of the Iroquois Formation and the Scatarie Limestone and Bacarro Limestone Members of the Abenaki Formation). The absence of a skeletal-reef association and the dominance of muddy limestone fabrics are evidence that the 145-1 wellsite was located on the platform interior. Major periods of siticiclastic deposition interrupted carbonate deposition, and they are recorded by stratigraphic equivalents of the Mohican Formation, Misaine Shale Member of the Abenaki Formation, and the Mohawk and Mic Mac Formations. A series of sustained prograding delta systems, the earliest of which is preserved as the Missisauga Formation, buried the carbonate platform following its drowning in the Early Cretaceous (Berriasian-Valanginian). The sparser, primarily allochthonous lignite content and better-sorted, glauconite-bearing sands of the Missisauga strata at the 145-1 wellsite suggest that shallow marine or barrier-bar environments were more prevalent than the low

Stratigraphy, sedimentology and tectonic evolution of the Upper Cretaceous/Paleogene succession in north Eastern Desert, Egypt

NASA Astrophysics Data System (ADS)

El Ayyat, Abdalla M.; Obaidalla, Nageh A.

2013-05-01

The stratigraphy, sedimentology and syn-depositional tectonic events (SdTEs) of the Upper Cretaceous/Paleogene (K-P) succession at four localities in north Eastern Desert (NED) of Egypt have been studied. These localities are distributed from south-southwest to north-northeast at Gebel Millaha, at North Wadi Qena, at Wadi El Dakhal, and at Saint Paul Monastery. Lithostratigraphically, four rock units have been recorded: Sudr Formation (Campanian-Maastrichtian); Dakhla Formation (Danian-Selandian); Tarawan Formation (Selandian-Thanetian) and Esna Formation (Thanetian-Ypresian). These rock units are not completely represented all over the study area because some of them are absent at certain sites and others have variable thicknesses. Biostratigrapgically, 18 planktonic foraminiferal zones have been recorded. These are in stratigraphic order: Globotruncana ventricosa Zone (Campanian); Gansserina gansseri, Contusotruncana contusa, Recimguembelina fructicosa, Pseudohastigerina hariaensis, Pseudohastigerina palpebra and Plummerita hantkenenoides zones (Maastrichtian); Praemurica incostans, Praemurica uncinata, Morozovella angulata and Praemurica carinata/Igorina albeari zones (Danian); Igorina albeari, Globanomanlina pseudomenradii/Parasubbotina variospira, Acarinina subsphaerica, Acarinina soldadoensis/Globanomanlina pseudomenardii and Morozovella velascoensis zones (Selandian/Thantian); and Acarinina sibaiyaensis, Pseudohastigerina wilcoxensis/Morozovella velascoensis zones (earliest Ypresian). Sedimentologically, four sedimentary facies belts forming southwest gently-dipping slope to basin transect have been detected. They include tidal flats, outer shelf, slumped continental slope and open marine hemipelagic facies. This transect can be subdivided into a stable basin plain plus outer shelf in the extreme southwestern parts; and an unstable slope shelf platform in the northeastern parts. The unstable slope shelf platform is characterized by open marine hemipelagic

Disentangling the control of tectonics, eustasy, trophic conditions and climate on shallow-marine carbonate production during the Aalenian-Oxfordian interval: From the western France platform to the western Tethyan domain

NASA Astrophysics Data System (ADS)

Andrieu, Simon; Brigaud, Benjamin; Barbarand, Jocelyn; Lasseur, Eric; Saucède, Thomas

2016-11-01

The objective of this work is to improve our understanding of the processes controlling changes in the architecture and facies of intracontinental carbonate platforms. We examined the facies and sequence stratigraphy of Aalenian to Oxfordian limestones of western France. Seventy-seven outcrop sections were studied and thirty-one sedimentary facies identified in five depositional environments ranging from lower offshore to backshore. Platform evolution was reconstructed along a 500 km cross-section. Twenty-two depositional sequences were identified on the entire western France platform and correlated with European third-order sequences at the biozone level, demonstrating that eustasy was the major factor controlling the cyclic trend of accommodation. The tectonic subsidence rate was computed from accommodation measurements from the Aalenian to the Oxfordian in key localities. Tectonism controlled the sedimentation rate and platform architecture at a longer time scale. Tectonic subsidence triggered the demise of carbonate production at the Bathonian/Callovian boundary while the uplift made possible the recovery of carbonate platform from Caen to Le Mans during the mid Oxfordian. Topography of the Paleozoic basement mainly controlled lateral variations of paleodepth within the western France platform until the mid Bathonian. A synthesis of carbonate production in the western Tethyan domain at that time was conducted. Stages of high carbonate production during the Bajocian/Bathonian and the middle to late Oxfordian are synchronous with low δ13C, high eccentricity intervals, and rather dry climate promoting (1) evaporation and carbonate supersaturation, and (2) oligotrophic conditions. Periods of low carbonate production during the Aalenian and from the middle Callovian to early Oxfordian correlate with high δ13C and low eccentricity intervals, characterized by wet climate and less oligotrophic conditions. Such conditions tend to diminish growth potential of carbonate

Coeval gravity-driven and thick-skinned extensional tectonics in the mid-Cretaceous of the western Pyrenees

NASA Astrophysics Data System (ADS)

Bodego, Arantxa; Agirrezabala, Luis M.

2010-05-01

The Mesozoic Basque-Cantabrian Basin in the western Pyrenees constitutes a peri-cratonic basin originated by rifting related to the Cretaceous opening of the Bay of Biscay. During the mid-Cretaceous the basin experienced important extensional/transtensional tectonics, which controlled the deposition of thick sedimentary successions. Many extensional structures have been documented in the basin but their thin-skinned/thick-skinned character is an unresolved question. In this field-based study, we characterize contemporaneous thin-skinned and thick-skinned deformations that took place during the filling of the mid-Cretaceous Lasarte sub-basin, located in the northeastern margin of the Basque-Cantabrian Basin (western Pyrenees). Most of these extensional structures and associated growth strata are preserved and allow us to characterize and date different deformation phases. Moreover, verticalization and overturning of the successions during Tertiary compression allow mapping the geometry of the extensional structures at depth. The Lasarte sub-basin constitutes a triangular sag bordered by three major basement-involved faults, which trend N, E and NE, respectively. These trends, common in the Variscan fault pattern of Pyrenees, suggest that they are old faults reactivated during the mid-Cretaceous extension. Stratigraphy of the area shows very thin to absent Aptian-Albian (and older) deposits above the upward border blocks, whereas on the downward blocks (sub-basin interior) contemporaneous thick successions were deposited (up to 1500 m). The sub-basin fill is composed of different sedimentary systems (from alluvial to siliciclastic and carbonate platforms) affected by syndepositional extensional faults (and related folds). These faults die out in a southwestward dipping (~4°) detachment layer composed of Triassic evaporites and clays. A NE-SW cross-section of the sub-basin shows NW- to N-trending six planar and two listric extensional faults and associated folds

Minor-element composition and organic carbon content of marine and nonmarine shales of Late Cretaceous age in the western interior of the United States

USGS Publications Warehouse

Tourtelot, H.A.

1964-01-01

The composition of nonmarine shales of Cretaceous age that contain less than 1 per cent organic carbon is assumed to represent the inherited minor-element composition of clayey sediments delivered to the Cretaceous sea that occupied the western interior region of North America. Differences in minor-element content between these samples and samples of 1. (a) nonmarine carbonaceous shales (1 to 17 per cent organic carbon), 2. (b) nearshore marine shales (less than 1 per cent organic carbon), and 3. (c) offshore marine shales (as much as 8 per cent organic carbon), all of the same age, reveal certain aspects of the role played by clay minerals and organic materials in affecting the minor-element composition of the rocks. The organic carbon in the nonmarine rocks occurs in disseminated coaly plant remains. The organic carbon in the marine rocks occurs predominantly in humic material derived from terrestrial plants. The close similarity in composition between the organic isolates from the marine samples and low-rank coal suggests that the amount of marine organic material in these rocks is small. The minor-element content of the two kinds of nonmarine shales is the same despite the relatively large amount of organic carbon in the carbonaceous shales. The nearshore marine shales, however, contain larger median amounts of arsenic, boron, chromium, vanadium and zinc than do the nonmarine rocks; and the offshore marine shales contain even larger amounts of these elements. Cobalt, molybdenum, lead and zirconium show insignificant differences in median content between the nonmarine and marine rocks, although as much as 25 ppm molybdenum is present in some offshore marine samples. The gallium content is lower in the marine than in the nonmarine samples. Copper and selenium contents of the two kinds of nonmarine rocks and the nearshore marine samples are the same, but those of the offshore samples are larger. In general, arsenic, chromium, copper, molybdenum, selenium, vanadium

Brazilian continental cretaceous

NASA Astrophysics Data System (ADS)

Petri, Setembrino; Campanha, Vilma A.

1981-04-01

Cretaceous deposits in Brazil are very well developed, chiefly in continental facies and in thick sequences. Sedimentation occurred essentially in rift-valleys inland and along the coast. Three different sequences can be distinguished: (1) a lower clastic non-marine section, (2) a middle evaporitic section, (3) an upper marine section with non-marine regressive lithosomes. Continental deposits have been laid down chiefly between the latest Jurassic and Albian. The lower lithostratigraphic unit is represented by red shales with occasional evaporites and fresh-water limestones, dated by ostracods. A series of thick sandstone lithosomes accumulated in the inland rift-valleys. In the coastal basins these sequences are often incompletely preserved. Uplift in the beginning of the Aptian produced a widespread unconformity. In many of the inland rift-valleys sedimentation ceased at that time. A later transgression penetrated far into northeastern Brazil, but shortly after continental sedimentation continued, with the deposition of fluvial sandstones which once covered large areas of the country and which have been preserved in many places. The continental Cretaceous sediments have been laid down in fluvial and lacustrine environments, under warm climatic conditions which were dry from time to time. The fossil record is fairly rich, including besides plants and invertebrates, also reptiles and fishes. As faulting tectonism was rather strong, chiefly during the beginning of the Cretaceous, intercalations of igneous rocks are frequent in some places. Irregular uplift and erosion caused sediments belonging to the remainder of this period to be preserved only in tectonic basins scattered across the country.

Dinosaur morphological diversity and the end-Cretaceous extinction.

PubMed

Brusatte, Stephen L; Butler, Richard J; Prieto-Márquez, Albert; Norell, Mark A

2012-05-01

The extinction of non-avian dinosaurs 65 million years ago is a perpetual topic of fascination, and lasting debate has focused on whether dinosaur biodiversity was in decline before end-Cretaceous volcanism and bolide impact. Here we calculate the morphological disparity (anatomical variability) exhibited by seven major dinosaur subgroups during the latest Cretaceous, at both global and regional scales. Our results demonstrate both geographic and clade-specific heterogeneity. Large-bodied bulk-feeding herbivores (ceratopsids and hadrosauroids) and some North American taxa declined in disparity during the final two stages of the Cretaceous, whereas carnivorous dinosaurs, mid-sized herbivores, and some Asian taxa did not. Late Cretaceous dinosaur evolution, therefore, was complex: there was no universal biodiversity trend and the intensively studied North American record may reveal primarily local patterns. At least some dinosaur groups, however, did endure long-term declines in morphological variability before their extinction.

A Platform to Optimize the Field Emission Properties of Carbon Nanotube Based Fibers (Postprint)

DTIC Science & Technology

2016-08-25

University of Dayton Research Institute 300 College Park Ave., Dayton, OH 45469 6) AFRL /RD, Kirtland AFB, Albuquerque, NM 8717... AFRL -RX-WP-JA-2017-0351 A PLATFORM TO OPTIMIZE THE FIELD EMISSION PROPERTIES OF CARBON-NANOTUBE-BASED FIBERS (POSTPRINT) Steven B...Fairchild AFRL /RX M. Cahay and W. Zhu University of Cincinnati K.L. Jensen Naval Research Laboratory R.G. Forbes University of Surrey

Integrating facies and structural analyses with subsidence history in a Jurassic-Cretaceous intraplatform basin: Outcome for paleogeography of the Panormide Southern Tethyan margin (NW Sicily, Italy)

NASA Astrophysics Data System (ADS)

Basilone, Luca; Sulli, Attilio; Gasparo Morticelli, Maurizio

2016-06-01

We illustrate the tectono-sedimentary evolution of a Jurassic-Cretaceous intraplatform basin in a fold and thrust belt present setting (Cala Rossa basin). Detailed stratigraphy and facies analysis of Upper Triassic-Eocene successions outcropping in the Palermo Mts (NW Sicily), integrated with structural analysis, restoration and basin analysis, led to recognize and describe into the intraplatform basin the proximal and distal depositional areas respect to the bordered carbonate platform sectors. Carbonate platform was characterized by a rimmed reef growing with progradational trends towards the basin, as suggested by the several reworked shallow-water materials interlayered into the deep-water succession. More, the occurrence of thick resedimented breccia levels into the deep-water succession suggests the time and the characters of synsedimentary tectonics occurred during the Late Jurassic. The study sections, involved in the building processes of the Sicilian fold and thrust belt, were restored in order to obtain the original width of the Cala Rossa basin, useful to reconstruct the original geometries and opening mechanisms of the basin. Basin analysis allowed reconstructing the subsidence history of three sectors with different paleobathymetry, evidencing the role exerted by tectonics in the evolution of the narrow Cala Rossa basin. In our interpretation, a transtensional dextral Lower Jurassic fault system, WNW-ESE (present-day) oriented, has activated a wedge shaped pull-apart basin. In the frame of the geodynamic evolution of the Southern Tethyan rifted continental margin, the Cala Rossa basin could have been affected by Jurassic transtensional faults related to the lateral westward motion of Africa relative to Europe.

Geologic evolution and sequence stratigraphy of the offshore Pelotas Basin, southeast Brazil

DOE Office of Scientific and Technical Information (OSTI.GOV)

Abreu, V.S.

1996-01-01

The Brazilian marginal basins have been studied since the beginning of the 70s. At least nine large basins are distributed along the entire Eastern continental margin. The sedimentary infill of these basins consists of lower Cretaceous (continental/lacustrine) rift section underlying marine upper Cretaceous (carbonate platforms) and marine upper Cretaceous/Tertiary sections, corresponding to the drift phase. The sedimentary deposits are a direct result of the Jurassic to lower Cretaceous break-up of the Pangea. This study will focus on the geologic evolution and sequence stratigraphic analysis of the Pelotas basin (offshore), located in the Southeast portion of the Brazilian continental margin betweenmore » 28[degrees] and 34[degrees] S, covering approximately 50,000 Km[sup 2]. During the early Cretaceous, when the break-up of the continent began in the south, thick basaltic layers were deposited in the Pelotas basin. These basalts form a thick and broad wedge of dipping seaward reflections interpreted as a transitional crust. During Albian to Turonian times, due to thermal subsidence, an extensive clastic/carbonate platform was developed, in an early drift stage. The sedimentation from the upper Cretaceous to Tertiary was characterized by a predominance of siliciclastics in the southeast margin, marking an accentuate deepening of the basin, showing several cycles related to eustatic fluctuations. Studies have addressed the problems of hydrocarbon exploration in deep water setting within a sequence stratigraphic framework. Thus Pelotas basin can provide a useful analogue for exploration efforts worldwide in offshore passive margins.« less

Geologic evolution and sequence stratigraphy of the offshore Pelotas Basin, southeast Brazil

DOE Office of Scientific and Technical Information (OSTI.GOV)

Abreu, V.S.

1996-12-31

The Brazilian marginal basins have been studied since the beginning of the 70s. At least nine large basins are distributed along the entire Eastern continental margin. The sedimentary infill of these basins consists of lower Cretaceous (continental/lacustrine) rift section underlying marine upper Cretaceous (carbonate platforms) and marine upper Cretaceous/Tertiary sections, corresponding to the drift phase. The sedimentary deposits are a direct result of the Jurassic to lower Cretaceous break-up of the Pangea. This study will focus on the geologic evolution and sequence stratigraphic analysis of the Pelotas basin (offshore), located in the Southeast portion of the Brazilian continental margin betweenmore » 28{degrees} and 34{degrees} S, covering approximately 50,000 Km{sup 2}. During the early Cretaceous, when the break-up of the continent began in the south, thick basaltic layers were deposited in the Pelotas basin. These basalts form a thick and broad wedge of dipping seaward reflections interpreted as a transitional crust. During Albian to Turonian times, due to thermal subsidence, an extensive clastic/carbonate platform was developed, in an early drift stage. The sedimentation from the upper Cretaceous to Tertiary was characterized by a predominance of siliciclastics in the southeast margin, marking an accentuate deepening of the basin, showing several cycles related to eustatic fluctuations. Studies have addressed the problems of hydrocarbon exploration in deep water setting within a sequence stratigraphic framework. Thus Pelotas basin can provide a useful analogue for exploration efforts worldwide in offshore passive margins.« less

Tribosphenic mammal from the North American Early Cretaceous.

PubMed

Cifelli, R L

1999-09-23

The main groups of living mammals, marsupials and eutherians, are presumed to have diverged in the Early Cretaceous, but their early history and biogeography are poorly understood. Dental remains have suggested that the eutherians may have originated in Asia, spreading to North America in the Late Cretaceous, where an endemic radiation of marsupials was already well underway. Here I describe a new tribosphenic mammal (a mammal with lower molar heels that are three-cusped and basined) from the Early Cretaceous of North America, based on an unusually complete specimen. The new taxon bears characteristics (molarized last premolar, reduction to three molars) otherwise known only for Eutheria among the tribosphenic mammals. Morphometric analysis and character comparisons show, however, that its molar structure is primitive (and thus phylogenetically uninformative), emphasizing the need for caution in interpretation of isolated teeth. The new mammal is approximately contemporaneous with the oldest known Eutheria from Asia. If it is a eutherian, as is indicated by the available evidence, then this group was far more widely distributed in the Early Cretaceous than previously appreciated. An early presence of Eutheria in North America offers a potential source for the continent's Late Cretaceous radiations, which have, in part, proven difficult to relate to contemporary taxa in Asia.

Multiple episodes of dolomitization and dolomite recrystallization during shallow burial in Upper Jurassic shelf carbonates: eastern Swabian Alb, southern Germany

NASA Astrophysics Data System (ADS)

Reinhold, C.

1998-10-01

The Upper Jurassic of the eastern Swabian Alb is composed of oolitic platform sands with associated microbe-siliceous sponge mounds at the platform margins. They are surrounded by argillaceous or calcareous mudstones and marl-limestone alternations, deposited in adjacent marl basins. Partial to complete dolomitization is predominantly confined to the mound facies. Six types of dolomite, as well as one type of ankerite, document a complex diagenetic history during shallow burial with multiple episodes of dolomite formation and recrystallization. The earliest massive matrix dolomitization is Ca-rich, has slightly depleted oxygen isotope values relative to Late Jurassic seawater, and carbon isotopic values in equilibrium with Late Jurassic seawater. This initial massive matrix dolomitization occurred during latest Jurassic to earliest Cretaceous and is related to pressure dissolution during very shallow burial at temperatures of at least 50°C. Hydrologic conditions and mass-balance calculations indicate that burial compaction provided sufficient fluids for dolomitization. Mg is derived from negligibly modified seawater, that was expelled from the adjacent off-reef strata into the mound facies. Position of the mounds along the platform margins controlled the distribution of the shallow-burial dolomite. Covariant trends between textural modification, increasing stoichiometry, partial changes in trace element content (Mn, Fe, Sr) and depletion in stable isotopes as well as distinctive CL pattern illustrate two recrystallization phases of the precursor matrix dolomite during further burial at elevated temperatures. Strong Sr enrichment of the second phase of recrystallized dolomite is ascribed to Sr-rich meteoric waters descending from overlying aragonite-bearing reef limestones or evaporite-bearing peritidal carbonates. Late-stage coarsely crystalline dolomite cements occur as vug and fracture fillings and formed during burial. Ankerite, associated with sulphide and

The impact of the Cretaceous-Paleogene (K-Pg) mass extinction event on the global sulfur cycle: Evidence from Seymour Island, Antarctica

NASA Astrophysics Data System (ADS)

Witts, James D.; Newton, Robert J.; Mills, Benjamin J. W.; Wignall, Paul B.; Bottrell, Simon H.; Hall, Joanna L. O.; Francis, Jane E.; Alistair Crame, J.

2018-06-01

The Cretaceous-Paleogene (K-Pg) mass extinction event 66 million years ago led to large changes to the global carbon cycle, primarily via a decrease in primary or export productivity of the oceans. However, the effects of this event and longer-term environmental changes during the Late Cretaceous on the global sulfur cycle are not well understood. We report new carbonate associated sulfate (CAS) sulfur isotope data derived from marine macrofossil shell material from a highly expanded high latitude Maastrichtian to Danian (69-65.5 Ma) succession located on Seymour Island, Antarctica. These data represent the highest resolution seawater sulfate record ever generated for this time interval, and are broadly in agreement with previous low-resolution estimates for the latest Cretaceous and Paleocene. A vigorous assessment of CAS preservation using sulfate oxygen, carbonate carbon and oxygen isotopes and trace element data, suggests factors affecting preservation of primary seawater CAS isotopes in ancient biogenic samples are complex, and not necessarily linked to the preservation of original carbonate mineralogy or chemistry. Primary data indicate a generally stable sulfur cycle in the early-mid Maastrichtian (69 Ma), with some fluctuations that could be related to increased pyrite burial during the 'mid-Maastrichtian Event'. This is followed by an enigmatic +4‰ increase in δ34SCAS during the late Maastrichtian (68-66 Ma), culminating in a peak in values in the immediate aftermath of the K-Pg extinction which may be related to temporary development of oceanic anoxia in the aftermath of the Chicxulub bolide impact. There is no evidence of the direct influence of Deccan volcanism on the seawater sulfate isotopic record during the late Maastrichtian, nor of a direct influence by the Chicxulub impact itself. During the early Paleocene (magnetochron C29R) a prominent negative excursion in seawater δ34S of 3-4‰ suggests that a global decline in organic carbon burial

Fossil evidence for Cretaceous escalation in angiosperm leaf vein evolution.

PubMed

Feild, Taylor S; Brodribb, Timothy J; Iglesias, Ari; Chatelet, David S; Baresch, Andres; Upchurch, Garland R; Gomez, Bernard; Mohr, Barbara A R; Coiffard, Clement; Kvacek, Jiri; Jaramillo, Carlos

2011-05-17

The flowering plants that dominate modern vegetation possess leaf gas exchange potentials that far exceed those of all other living or extinct plants. The great divide in maximal ability to exchange CO(2) for water between leaves of nonangiosperms and angiosperms forms the mechanistic foundation for speculation about how angiosperms drove sweeping ecological and biogeochemical change during the Cretaceous. However, there is no empirical evidence that angiosperms evolved highly photosynthetically active leaves during the Cretaceous. Using vein density (D(V)) measurements of fossil angiosperm leaves, we show that the leaf hydraulic capacities of angiosperms escalated several-fold during the Cretaceous. During the first 30 million years of angiosperm leaf evolution, angiosperm leaves exhibited uniformly low vein D(V) that overlapped the D(V) range of dominant Early Cretaceous ferns and gymnosperms. Fossil angiosperm vein densities reveal a subsequent biphasic increase in D(V). During the first mid-Cretaceous surge, angiosperm D(V) first surpassed the upper bound of D(V) limits for nonangiosperms. However, the upper limits of D(V) typical of modern megathermal rainforest trees first appear during a second wave of increased D(V) during the Cretaceous-Tertiary transition. Thus, our findings provide fossil evidence for the hypothesis that significant ecosystem change brought about by angiosperms lagged behind the Early Cretaceous taxonomic diversification of angiosperms.

Chevron starts U.S. gulf`s first Lower Cretaceous flow

DOE Office of Scientific and Technical Information (OSTI.GOV)

Petzet, G.A.

1998-06-15

Chevron plans to start production from its Mobile 991 No. 1 well this month. The trend`s first producer is the Viosca Knoll 68 No. 2 well, which went on line April 26 at the anticipated rate of about 15 MMcfd of gas. Chevron has also tested its Viosca Knoll 114 discovery well, drilled in August 1997. Five gas discoveries since 1994 in a trend that extends now Mobile Block 991 to Viosca Knoll Block 252 have recoverable reserve potential of over 600 bcf (gross trend) of natural gas. The paper describes the carbonate trend and exploring the Lower Cretaceous Jamesmore » deposit.« less

Time scales of critical events around the Cretaceous-Paleogene boundary.

PubMed

Renne, Paul R; Deino, Alan L; Hilgen, Frederik J; Kuiper, Klaudia F; Mark, Darren F; Mitchell, William S; Morgan, Leah E; Mundil, Roland; Smit, Jan

2013-02-08

Mass extinctions manifest in Earth's geologic record were turning points in biotic evolution. We present (40)Ar/(39)Ar data that establish synchrony between the Cretaceous-Paleogene boundary and associated mass extinctions with the Chicxulub bolide impact to within 32,000 years. Perturbation of the atmospheric carbon cycle at the boundary likely lasted less than 5000 years, exhibiting a recovery time scale two to three orders of magnitude shorter than that of the major ocean basins. Low-diversity mammalian fauna in the western Williston Basin persisted for as little as 20,000 years after the impact. The Chicxulub impact likely triggered a state shift of ecosystems already under near-critical stress.

Paleoceanographic changes during the Albian-Cenomanian in the Tethys and North Atlantic and the onset of the Cretaceous chalk

NASA Astrophysics Data System (ADS)

Giorgioni, Martino; Weissert, Helmut; Bernasconi, Stefano M.; Hochuli, Peter A.; Keller, Christina E.; Coccioni, Rodolfo; Petrizzo, Maria Rose; Lukeneder, Alexander; Garcia, Therese I.

2015-03-01

During the mid-Cretaceous the Earth was characterized by peculiar climatic and oceanographic features, such as very high temperatures, smooth thermal meridional gradient, long-term rising sea level, and formation of oceanic gateways and seaways. At that time widespread deposition of micritic pelagic limestones, generally called chalk, occurred in deep pelagic settings as well as in epeiric seas, both at tropical and at high latitudes. The origin of such extensive chalk deposition in the mid-Cretaceous is a complex and still controversial issue, which involves the interaction of several different factors. In this work we address this topic from the paleoceanographic perspective, by investigating the contribution of major oceanic circulation changes. We characterize several stratigraphic sections from the Tethys and North Atlantic with litho-, bio-, and carbon isotope stratigraphy. Our data show a change between two different oceanic circulation modes happening in the Late Albian. The first is an unstable mode, with oceanographic conditions fluctuating frequently in response to rapid environmental and climatic changes, such as those driven by orbital forcing. The second mode is more stable, with better connection between the different oceanic basins, a more stable thermocline, more persistent current flow, better defined upwelling and downwelling areas, and a more balanced oceanic carbon reservoir. We propose that under the mid-Cretaceous paleogeographic and paleoclimatic conditions this change in oceanic circulation mode favored the beginning of chalk sedimentation in deep-water settings.

CRETACEOUS CLIMATE SENSITIVITY STUDY USING DINOSAUR & PLANT PALEOBIOGEOGRAPHY

NASA Astrophysics Data System (ADS)

Goswami, A.; Main, D. J.; Noto, C. R.; Moore, T. L.; Scotese, C.

2009-12-01

The Early Cretaceous was characterized by cool poles and moderate global temperatures (~16° C). During the mid and late Cretaceous, long-term global warming (~20° - 22° C) was driven by increasing levels of CO2, rising sea level (lowering albedo) and the continuing breakup of Pangea. Paleoclimatic reconstructions for four time intervals during the Cretaceous: Middle Campanian (80 Ma), Cenomanian/Turonian (90 Ma), Early Albian (110 Ma) and Barremian-Hauterivian (130Ma) are presented here. These paleoclimate simulations were prepared using the Fast Ocean and Atmosphere Model (FOAM). The simulated results show the pattern of the pole-to-Equator temperature gradients, rainfall, surface run-off, the location of major rivers and deltas. In order to investigate the effect of potential dispersal routes on paleobiogeographic patterns, a time-slice series of maps from Early - Late Cretaceous were produced showing plots of dinosaur and plant fossil distributions. These Maps were created utilizing: 1) plant fossil localities from the GEON and Paleobiology (PBDB) databases; and 2) dinosaur fossil localities from an updated version of the Dinosauria (Weishampel, 2004) database. These results are compared to two different types of datasets, 1) Paleotemperature database for the Cretaceous and 2) locality data obtained from GEON, PBDB and Dinosauria database. Global latitudinal mean temperatures from both the model and the paelotemperature database were plotted on a series of latitudinal graphs along with the distributions of fossil plants and dinosaurs. It was found that most dinosaur localities through the Cretaceous tend to cluster within specific climate belts, or envelopes. Also, these Cretaceous maps show variance in biogeographic zonation of both plants and dinosaurs that is commensurate with reconstructed climate patterns and geography. These data are particularly useful for understanding the response of late Mesozoic ecosystems to geographic and climatic conditions that

Diagenesis in coastal carbonates related to Pleistocene sea level, Bermuda Platform

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vollbrecht, R.; Meischner, D.

1996-01-01

Pleistocene glacioeustatic sea-level oscillation on the stable Bermuda Platform is expressed in a succession of shallow-water carbonates interrupted by lowstand unconformities. In Bermuda, the maximum highstands of the last 400,000 yr ranged within 10 m around the present level. Coastal carbonates of various highstands are exposed along the present shoreline. These carbonates were penetrated by meteoric and marine pore waters during lowstands and highstands following on deposition. Two representative Pleistocene shoreline sections were studied to see whether early diagenesis has recorded these pore-water changes. The sediments of both sections show multiple generations of cement. Optical and scanning electron microscopy, cathodoluminescencemore » microscopy, X-ray diffraction, microprobe studies and stable-isotope analyses were used to determine the diagenetic environments involved. Regardless of the degree of substrate cementation, freshwater alteration was mainly vadose whereas marine cementation was either phreatic or vadose or both. Early diagenetic oscillation is easier recorded in coastal successions than in lagoonal sediments, mainly because marine cementation is more active nearshore.Because the coastal environment is prone to wave destruction, the potential for preserving these diagenetic features is usually low. Data published on tectonically unstable areas suggest that early diagenetic oscillation may characterize stable coastlines.« less

Hydrogeology and preliminary assessment of regional flow in the upper Cretaceous and adjacent aquifers in the northern Mississippi embayment

USGS Publications Warehouse

Brahana, J.V.; Mesko, T.O.

1988-01-01

On a regional scale, the groundwater system of the northern Mississippi embayment is composed of a series of nonindurated clastic sediments that overlie a thick sequence of Paleozoic carbonate, sandstones, and shales. The units that comprise the geohydrologic framework of this study are the alluvium-lower Wilcox Aquifer the Midway confining unit, the Upper Cretaceous aquifer, the Cretaceous-Paleozoic confining unit, and the Ozark-St. Francois aquifer. The Upper Cretaceous aquifer of Late Cretaceous age is the primary focus of this investigation; the study is part of the Gulf Coast Regional Aquifer-System Analysis. A four layer finite-difference groundwater flow model enabled testing of alternative boundary concepts and provide a refined definition of the hydrologic budget of the deep aquifers. The alluvium-lower Wilcox aquifer, the Upper Cretaceous aquifer, and the Ozark-St. Francois aquifer form layers 2 through 4, respectively. Layer 1 is an inactive layer of constant heads representing shallow water levels, which are a major control on recharge to and discharge from the regional system. A matrix of leakance values simulates each confining unit, allowing vertical interchange of water between different aquifers. The model was calibrated to 1980 conditions by using the assumption that 1980 was near steady-state conditions; it was calibrated to simulate observed heads were found to be most sensitive to pumping, and least sensitive to the leakance. By using all available water quality and water level data, alternative boundary conditions were tested by comparing model simulated heads to observed heads. The results of the early modeling effort also contribute to a better understanding of the regional hydrologic budget, indicating that: upward leakage from the Ozark-St. Francois aquifer to the Upper Cretaceous aquifer is about 43 cu ft/sec; upward recharge of about 68 cu ft/sec occurs to the lower Wilcox-alluvium aquifer from the Upper Cretaceous aquifer; and the

Evidence For Volcanic Initiation Of Cretaceous Ocean Anoxic Events (Invited)

NASA Astrophysics Data System (ADS)

Sageman, B. B.; Hurtgen, M. T.; McElwain, J.; Adams, D.; Barclay, R. S.; Joo, Y.

2010-12-01

Increasing evidence from studies of Cretaceous ocean anoxic events (OAE’s) has suggested that major changes in volcanic activity may have played a significant role in their genesis. Numerous specific mechanisms of have been proposed, including increases in atmospheric CO2 and surface temperature, leading to enhanced chemical weathering and terrestrial nutrient release, or increases in reduced trace metal fluxes, leading to oxygen depletion and possibly providing micronutrients for enhanced primary production. An additional pathway by which the byproducts of enhanced volcanic activity may have contributed to OAE genesis involves relationships between the biogeochemical cycles sulfur, iron, and phosphorus. Recent analysis of S-isotope data from carbonate-associated sulfate and pyrite collected across the Cenomanian-Turonian OAE2 in the Western Interior basin suggest that increases in sulfate to an initially sulfate-depleted ocean preceded onset of the event. Modern lake data support the idea that increases in sulfate concentration drive microbial sulfate reduction, leading to more efficient regeneration of P from sedimentary organic matter. If the early Cretaceous opening of the South Atlantic was accompanied by evaporite deposition sufficient to draw down global marine sulfate levels, and widespread anoxia leading to elevated pyrite burial helped maintain these low levels for the succeeding 30 myr, during which most Cretaceous OAE’s are found, perhaps pulses of volcanism that rapidly introduced large volumes of sulfate may have played a key role in OAE initiation. The eventually burial of S in the form of pyrite may have returned sulfate levels to a low background, thus providing a mechanism to terminate the anoxic events. This talk will review the evidence for volcanic initiation of OAE’s in the context of the sulfate-phosphorus regeneration model.

Definition of Greater Gulf Basin Lower Cretaceous and Upper Cretaceous Lower Cenomanian Shale Gas Assessment Unit, United States Gulf of Mexico Basin Onshore and State Waters

USGS Publications Warehouse

Dennen, Kristin O.; Hackley, Paul C.

2012-01-01

An assessment unit (AU) for undiscovered continuous “shale” gas in Lower Cretaceous (Aptian and Albian) and basal Upper Cretaceous (lower Cenomanian) rocks in the USA onshore Gulf of Mexico coastal plain recently was defined by the U.S. Geological Survey (USGS). The AU is part of the Upper Jurassic-Cretaceous-Tertiary Composite Total Petroleum System (TPS) of the Gulf of Mexico Basin. Definition of the AU was conducted as part of the 2010 USGS assessment of undiscovered hydrocarbon resources in Gulf Coast Mesozoic stratigraphic intervals. The purpose of defining the Greater Gulf Basin Lower Cretaceous Shale Gas AU was to propose a hypothetical AU in the Cretaceous part of the Gulf Coast TPS in which there might be continuous “shale” gas, but the AU was not quantitatively assessed by the USGS in 2010.

Slope and basinal deposits adjacent to isolated carbonate platforms in the Indian Ocean: Sedimentology, geomorphology, and a new 1.2 Ma record of highstand shedding

NASA Astrophysics Data System (ADS)

Counts, J. W.; Jorry, S.; Jouet, G.

2017-12-01

Newly analyzed bathymetric, seismic, and core data from carbonate-topped seamounts in the Mozambique Channel reveals a variety of depositional processes and products operating on platform slopes and adjacent basins. Mass transport complexes (including turbidites and debrites), leveed channel systems with basin-floor fans, and contourites are imaged in high resolution in both seafloor maps and cross-section, and show both differences and similarities compared with platform slopes in the Bahamas and elsewhere. In some, though not all, platforms, increased sedimentation can be observed on the leeward margins, and slope rugosity may be asymmetric with respect to prevailing wind direction. Deposition is also controlled by glacial-interglacial cycles; cores taken from the lower slopes (3000+ m water depth) of carbonate platforms reveal a causative relationship between sea level and aragonite export to the deep ocean. δ18O isotopes from planktonic and benthic foraminifera of two 27-meter cores, reveal a high-resolution, continuous depositional record of carbonate sediment dating back to 1.2 Ma. Sea level rise, as determined by correlation with the LR04 benthic stack, is coincident with increased aragonite flux from platform tops. Gravity flow deposits are also affected by platform flooding—the frequency of turbidite/debrite deposits on pinnacle slopes increases during highstand, although such deposits are also present during glacial episodes. The results reported here are the first record of highstand shedding in the southern Indian Ocean, and provide the longest Quaternary sediment record to date in the region, including the Mid-Brunhes transition (MIS 11) that serves as an analog for the current climate conditions. In addition, this is the first study to describe sedimentation on the slopes of these platforms, providing an important point of comparison that has the potential to influence source-to-sink carbonate facies models.

Magnetostratigraphy of displaced Upper Cretaceous strata in southern California

NASA Astrophysics Data System (ADS)

Fry, J. Gilbert; Bottjer, David J.; Lund, Steve P.

1985-09-01

A magnetostratigraphic study of Upper Cretaceous marine strata from the Santa Ana Mountains in southern California has identified a Campanian reversed magnetozone. This reversed interval, corresponding to marine magnetic anomaly 33 34 (Chron 33r) of Campanian age, can be correlated with a Campanian reversed magnetozone that has been reported from strata of the Great Valley Sequence in central California. The Late Cretaceous paleolatitude of the Santa Ana Mountains is estimated from this study to be 26.6°N. This is significantly different from the region's expected Cretaceous paleolatitude of 43.8°N as part of the North American stable craton, and indicates that this region (part of the Peninsular Ranges terrane) was 1900 km farther south in Cretaceous time relative to the stable craton. *Present address: Mobil Oil Corp., P.O. Box 900, Dallas, Texas 75221

Low-magnesium calcite produced by coralline algae in seawater of Late Cretaceous composition

PubMed Central

Stanley, Steven M.; Ries, Justin B.; Hardie, Lawrence A.

2002-01-01

Shifts in the Mg/Ca ratio of seawater driven by changes in midocean ridge spreading rates have produced oscillations in the mineralogy of nonskeletal carbonate precipitates from seawater on time scales of 108 years. Since Cambrian time, skeletal mineralogies of anatomically simple organisms functioning as major reef builders or producers of shallow marine limestones have generally corresponded in mineral composition to nonskeletal precipitates. Here we report on experiments showing that the ambient Mg/Ca ratio actually governs the skeletal mineralogy of some simple organisms. In modern seas, coralline algae produce skeletons of high-Mg calcite (>4 mol % MgCO3). We grew three species of these algae in artificial seawaters having three different Mg/Ca ratios. All of the species incorporated amounts of Mg into their skeletons in proportion to the ambient Mg/Ca ratio, mimicking the pattern for nonskeletal precipitation. Thus, the algae calcified as if they were simply inducing precipitation from seawater through their consumption of CO2 for photosynthesis; presumably organic templates specify the calcite crystal structure of their skeletons. In artificial seawater with the low Mg/Ca ratio of Late Cretaceous seas, the algae in our experiments produced low-Mg calcite (<4 mol % MgCO3), the carbonate mineral formed by nonskeletal precipitation in those ancient seas. Our results suggest that many taxa that produce high-Mg calcite today produced low-Mg calcite in Late Cretaceous seas. PMID:12399549

Similarity and Differences of Cretaceous Magmatism in the Arctic Region

NASA Astrophysics Data System (ADS)

Peyve, A. A.

2018-03-01

The paper considers Cretaceous magmatism at the continental margin of the Arctic Region. It is shown that Cretaceous igneous rocks of this region are rather heterogeneous in age, composition, and geodynamic formation setting. This differentiates them from rocks of typical large igneous provinces (LIPs). Local areas of magmatic activity, their substantial remoteness them from one another, and significant distinctions in age, composition of rocks, and formation conditions prevent us from unreservedly combining all occurrences of Cretaceous magmatism at the continental margin of the Arctic Region into a common igneous province. The stage of tholeiitic magmatism in the Svalbard Archipelago, Franz Josef Land, Arctic Canada, and the Alpha-Mendeleev Rise, which can be considered an LIP, began in the Early Cretaceous and continued for a long time, at least until the Campanian. The magmatism apparently had a plume source and was caused by extension during opening of the Canada Basin. Tholeiitic magmatism gave way to the alkaline magmatism stage from the Campanian to the onset of the Paleocene, related to continental rifting at the initial stage of formation of Eurasian Basin in the Arctic Region. No convincing evidence for a genetic link between Early Cretaceous tholeiitic and Late Cretaceous alkaline magmatism is known at present, nor for the alkaline magmatism belonging to a plume source.

Carbonate aquifers

USGS Publications Warehouse

Cunningham, Kevin J.; Sukop, Michael; Curran, H. Allen

2012-01-01

Only limited hydrogeological research has been conducted using ichnology in carbonate aquifer characterization. Regardless, important applications of ichnology to carbonate aquifer characterization include its use to distinguish and delineate depositional cycles, correlate mappable biogenically altered surfaces, identify zones of preferential groundwater flow and paleogroundwater flow, and better understand the origin of ichnofabric-related karst features. Three case studies, which include Pleistocene carbonate rocks of the Biscayne aquifer in southern Florida and Cretaceous carbonate strata of the Edwards–Trinity aquifer system in central Texas, demonstrate that (1) there can be a strong relation between ichnofabrics and groundwater flow in carbonate aquifers and (2) ichnology can offer a useful methodology for carbonate aquifer characterization. In these examples, zones of extremely permeable, ichnofabric-related macroporosity are mappable stratiform geobodies and as such can be represented in groundwater flow and transport simulations.

The Cretaceous-Paleogene boundary unit in the Gulf of Mexico: Large-scale oceanic basin response to the Chicxulub impact

NASA Astrophysics Data System (ADS)

Sanford, J. C.; Gulick, S. P.; Snedden, J.

2013-12-01

The prevailing theory for the Cretaceous-Paleogene (K-Pg) extinction event cites the Chicxulub asteroid impact on the Yucatán Peninsula as the catalyst for the global climatologic and ecologic crisis. This theory has been corroborated by a multitude of K-Pg boundary deposits observed globally in both boreholes and outcrops. The change in character of these deposits with proximity to the crater, from a millimeter-scale clay layer to a hectometer-scale carbonate sequence, supports a causal link between the boundary unit and the asteroid impact. Due to its passive marine setting and proximity to the Chicxulub crater, the Gulf of Mexico is the premier locale in which to study the near-field geologic effect of a massive bolide impact. Until recently, investigation of the K-Pg boundary deposit within the Gulf has been largely confined to outcrops and boreholes on the periphery of the basin due to the difficulty of observation of the boundary unit in the deep water. However, hydrocarbon exploration in the past decade has yielded significant borehole and seismic data that can be used to better understand the deep-water response to the impact and to gain a comprehensive regional understanding impact-related processes in the Gulf. Based on roughly 100 offshore and 300 onshore Cretaceous well penetrations, the K-Pg boundary is interpreted to range from a strictly erosional surface in shallow-water and coastal regimes to a mass transport deposit up to ~400 meters thick. Depth-converted seismic data throughout the Gulf corroborate such thicknesses and reveal that the deposit is virtually ubiquitous throughout the deep water. For the first time, the K-Pg boundary deposit has been tied from the central Gulf to the Chicxulub crater, further establishing a causative link between the two. Biostratigraphic data in wells confirm the age of the deposit and document the presence of the 'K-Pg boundary cocktail.' Seismic data reveals areas of extensive debris flows and slump deposits on

High resolution chronology of late Cretaceous-early Tertiary events determined from 21,000 yr orbital-climatic cycles in marine sediments

NASA Technical Reports Server (NTRS)

Herbert, Timothy D.; Dhondt, Steven

1988-01-01

A number of South Atlantic sites cored by the Deep Sea Drilling Project (DSDP) recovered late Cretaceous and early Tertiary sediments with alternating light-dark, high-low carbonate content. The sedimentary oscillations were turned into time series by digitizing color photographs of core segments at a resolution of about 5 points/cm. Spectral analysis of these records indicates prominent periodicity at 25 to 35 cm in the Cretaceous intervals, and about 15 cm in the early Tertiary sediments. The absolute period of the cycles that is determined from paleomagnetic calibration at two sites is 20,000 to 25,000 yr, and almost certainly corresponds to the period of the earth's precessional cycle. These sequences therefore contain an internal chronometer to measure events across the K/T extinction boundary at this scale of resolution. The orbital metronome was used to address several related questions: the position of the K/T boundary within magnetic chron 29R, the fluxes of biogenic and detrital material to the deep sea immediately before and after the K/T event, the duration of the Sr anomaly, and the level of background climatic variability in the latest Cretaceous time. The carbonate/color cycles that were analyzed contain primary records of ocean carbonate productivity and chemistry, as evidenced by bioturbational mixing of adjacent beds and the weak lithification of the rhythmic sequences. It was concluded that sedimentary sequences that contain orbital cyclicity are capable of providing resolution of dramatic events in earth history with much greater precision than obtainable through radiometric methods. The data show no evidence for a gradual climatic deterioration prior to the K/T extinction event, and argue for a geologically rapid revolution at this horizon.

Contributions of Volcanic Carbon Emissions to Environmental Change at the Cretaceous-Paleogene and Paleocene-Eocene Boundaries: Observational and Theoretical Constraints

NASA Astrophysics Data System (ADS)

Zachos, J. C.; Penman, D. E.; Ridgwell, A.

2017-12-01

The terminations of both the Cretaceous Period (K-Pg) and Paleocene Epoch (P-E) coincided with episodes of extensive flood basalt/rift volcanism, the Deccan Traps (DT) and North Atlantic Igneous Province (NAIP), respectively. The latest radiometric data confirm that the main phases of magma extrusion of both DT and NAIP were concentrated over relatively short intervals (<<0.5 myr) further bolstering speculation on the role of volcanic C and other emissions in driving the observed environmental and biotic events of those terminations. Much of the speculation regarding C emissions has been derived from observations of changes in climate and/or ocean chemistry. Indeed, to drive detectable global warming and/or ocean acidification, C emissions would have to be significantly elevated over "typical" magmatic emission levels, thus requiring supplemental sources of C, most likely from intrusion driven combustion of organic matter and/or carbonate-rich crust. Here we compare marine geochemical records spanning both boundaries and with numerical models assess implications for C emissions and relations to the key environmental changes associated with each event. This assessment benefits from the recent development of high-fidelity (i.e., astronomically-tuned) proxy records of the climate and ocean carbon chemistry (e.g., SST, δ13C, pH) across both time intervals from globally distributed, stratigraphically complete marine sections. In the case of the K-Pg transition, the timing of changes in climate and ocean carbon chemistry along with other data indicate a comparatively inconsequential role of elevated C emissions on the major biotic event (i.e., extinction) marking that boundary. In contrast, with the P-E boundary, North Atlantic volcanism now appears to have been primary trigger/driver of climatic change, though positive feedbacks involving reduced C reservoirs (e.g., hydrates, permafrost) might have accelerated C emission rates at the onset of that event.

Chapter 2: 2003 Geologic Assessment of Undiscovered Conventional Oil and Gas Resources in the Upper Cretaceous Navarro and Taylor Groups, Western Gulf Province, Texas

USGS Publications Warehouse

Condon, S.M.; Dyman, T.S.

2006-01-01

The Upper Cretaceous Navarro and Taylor Groups in the western part of the Western Gulf Province were assessed for undiscovered oil and gas resources in 2003. The area is part of the Smackover-Austin-Eagle Ford Composite Total Petroleum System. The rocks consist of, from youngest to oldest, the Escondido and Olmos Formations of the Navarro Group and the San Miguel Formation and the Anacacho Limestone of the Taylor Group (as well as the undivided Navarro Group and Taylor Group). Some units of the underlying Austin Group, including the 'Dale Limestone' (a term of local usage that describes a subsurface unit), were also part of the assessment in some areas. Within the total petroleum system, the primary source rocks comprise laminated carbonate mudstones and marine shales of the Upper Jurassic Smackover Formation, mixed carbonate and bioclastic deposits of the Upper Cretaceous Eagle Ford Group, and shelf carbonates of the Upper Cretaceous Austin Group. Possible secondary source rocks comprise the Upper Jurassic Bossier Shale and overlying shales within the Upper Jurassic to Lower Cretaceous Cotton Valley Group, Lower Cretaceous marine rocks, and the Upper Cretaceous Taylor Group. Oil and gas were generated in the total petroleum system at different times because of variations in depth of burial, geothermal gradient, lithology, and organic-matter composition. A burial-history reconstruction, based on data from one well in the eastern part of the study area (Jasper County, Tex.), indicated that (1) the Smackover generated oil from about 117 to 103 million years ago (Ma) and generated gas from about 52 to 41 Ma and (2) the Austin and Eagle Ford Groups generated oil from about 42 to 28 Ma and generated gas from about 14 Ma to the present. From the source rocks, oil and gas migrated upsection and updip along a pervasive system of faults and fractures as well as along bedding planes and within sandstone units. Types of traps include stratigraphic pinchouts, folds, faulted

"Days of future passed" - climate change and carbon cycle history (Jean Baptiste Lamarck Medal Lecture)

NASA Astrophysics Data System (ADS)

Weissert, Helmut

2013-04-01

With the beginning of the fossil fuel age in the 19th century mankind has become an important geological agent on a global scale. For the first time in human history action of man has an impact on global biogeochemical cycles. Increasing CO2 concentrations will result in a perturbation of global carbon cycling coupled with climate change. Investigations of past changes in carbon cycling and in climate will improve our predictions of future climate. Increasing atmospheric CO2 concentrations will drive climate into a mode of operation, which may resemble climate conditions in the deep geological past. Pliocene climate will give insight into 400ppm world with higher global sea level than today. Doubling of pre-industrial atmospheric CO2 levels will shift the climate system into a state resembling greenhouse climate in the Early Cenozoic or even in the Cretaceous. Carbon isotope geochemistry serves as tool for tracing the pathway of the carbon cycle through geological time. Globally registered negative C-isotope anomalies in the C-isotope record are interpreted as signatures of rapid addition (103 to a few 104 years) of CO2 to the ocean-atmosphere system. Positive C-isotope excursions following negative spikes record the slow post-perturbation recovery of the biosphere at time scales of 105 to 106 years. Duration of C-cycle perturbations in earth history cannot be directly compared with rapid perturbation characterizing the Anthropocene. However, the investigation of greenhouse pulses in the geological past provides insight into different climate states, it allows to identify tipping points in past climate systems and it offers the opportunity to learn about response reactions of the biosphere to rapid changes in global carbon cycling. Sudden injection of massive amounts of carbon dioxide into the atmosphere is recorded in C-isotope record of the Early Cretaceous. The Aptian carbon cycle perturbation triggered changes in temperature and in global hydrological cycling

Trace element and isotope geochemistry of Cretaceous-Tertiary boundary sediments: identification of extra-terrestrial and volcanic components

NASA Technical Reports Server (NTRS)

Margolis, S. V.; Doehne, E. F.

1988-01-01

Trace element and stable isotope analyses were performed on a series of sediment samples crossing the Cretaceous-Tertiary (K-T) boundary from critical sections at Aumaya and Sopelano, Spain. The aim is to possibly distinguish extraterrestrial vs. volcanic or authigenic concentration of platinum group and other elements in K-T boundary transitional sediments. These sediments also have been shown to contain evidence for step-wise extinction of several groups of marine invertebrates, associated with negative oxygen and carbon isotope excursions occurring during the last million years of the Cretaceous. These isotope excursions have been interpreted to indicate major changes in ocean thermal regime, circulation, and ecosystems that may be related to multiple events during latest Cretaceous time. Results to date on the petrographic and geochemical analyses of the Late Cretaceous and Early Paleocene sediments indicate that diagenesis has obviously affected the trace element geochemistry and stable isotope compositions at Zumaya. Mineralogical and geochemical analysis of K-T boundary sediments at Zumaya suggest that a substantial fraction of anomalous trace elements in the boundary marl are present in specific mineral phases. Platinum and nickel grains perhaps represent the first direct evidence of siderophile-rich minerals at the boundary. The presence of spinels and Ni-rich particles as inclusions in aluminosilicate spherules from Zumaya suggests an original, non-diagenetic origin for the spherules. Similar spherules from southern Spain (Caravaca), show a strong marine authigenic overprint. This research represents a new approach in trying to directly identify the sedimentary mineral components that are responsible for the trace element concentrations associated with the K-T boundary.

Multi-stage metamorphism in the South Armenian Block during the Late Jurassic to Early Cretaceous: Tectonics over south-dipping subduction of Northern branch of Neotethys

NASA Astrophysics Data System (ADS)

Hässig, M.; Rolland, Y.; Sahakyan, L.; Sosson, M.; Galoyan, G.; Avagyan, A.; Bosch, D.; Müller, C.

2015-04-01

The geologic evolution of the South Armenian Block (SAB) in the Mesozoic is reconstructed from a structural, metamorphic, and geochronologic study including U-Pb and 40Ar/39Ar dating. The South Armenian Block Crystalline Basement (SABCB) outcrops solely in a narrow tectonic window, NW of Yerevan. The study of this zone provides key and unprecedented information concerning closing of the Northern Neotethys oceanic domain north of the Taurides-Anatolides platform from the Middle Jurassic to the Early Cretaceous. The basement comprises of presumed Proterozoic orthogneiss overlain by metamorphosed pelites as well as intrusions of granodiorite and leucogranite during the Late Jurassic and Early Cretaceous. Structural, geochronological and petrological observations show a multiphased evolution of the northern margin of the SAB during the Late Jurassic and Early Cretaceous. A south-dipping subduction under the East Anatolian Platform-South Armenian Block (EAP-SAB) is proposed in order to suit recent findings pertaining emplacement of relatively hot subduction related granodiorite as well as the metamorphic evolution of the crystalline basement in the Lesser Caucasus area. The metamorphism is interpreted as evidencing: (1) M1 Barrovian MP-MT conditions (staurolite-kyanite) at c. 157-160 Ma and intrusion of dioritic magmas at c. 150-156 Ma, (2) near-adiabatic decompression is featured by partial melting and production of leucogranites at c. 153 Ma, followed by M2 HT-LP conditions (andalusite-K-feldspar). A phase of shearing and recrystallization is ascribed to doming at c. 130-150 Ma and cooling at 400 °C by c. 123 Ma (M3). Structural observations show (1) top to the north shearing during M1 and (2) radial extension during M2. The extensional event ends by emplacement of a thick detrital series along radial S, E and W-dipping normal faults. Further, the crystalline basement is unconformably covered by Upper Cretaceous-Paleocene series dated by nannofossils, evolving from

Total petroleum systems of the Pelagian Province, Tunisia, Libya, Italy, and Malta; the Bou Dabbous, Tertiary and Jurassic-Cretaceous composite

USGS Publications Warehouse

Klett, T.R.

2001-01-01

Undiscovered conventional oil and gas resources were assessed within total petroleum systems of the Pelagian Province (2048) as part of the U.S. Geological Survey World Petroleum Assessment 2000. The Pelagian Province is located mainly in eastern Tunisia and northwestern Libya. Small portions of the province extend into Malta and offshore Italy. Although several petroleum systems may exist, only two ?composite? total petroleum systems were identified. Each total petroleum system comprises a single assessment unit. These total petroleum systems are called the Bou Dabbous?Tertiary and Jurassic-Cretaceous Composite, named after the source-rock intervals and reservoir-rock ages. The main source rocks include mudstone of the Eocene Bou Dabbous Formation; Cretaceous Bahloul, Lower Fahdene, and M?Cherga Formations; and Jurassic Nara Formation. Known reservoirs are in carbonate rocks and sandstone intervals throughout the Upper Jurassic, Cretaceous, and Tertiary sections. Traps for known accumulations include fault blocks, low-amplitude anticlines, high-amplitude anticlines associated with reverse faults, wrench fault structures, and stratigraphic traps. The estimated means of the undiscovered conventional petroleum volumes in total petroleum systems of the Pelagian Province are as follows: [MMBO, million barrels of oil; BCFG, billion cubic feet of gas; MMBNGL, million barrels of natural gas liquids] Total Petroleum System MMBO BCFG MMBNGL Bou Dabbous?Tertiary 667 2,746 64 Jurassic-Cretaceous Composite 403 2,280 27

Genèse des séquences sédimentaires du Crétacé supérieur des Aurès (Algérie). Rôle de l'eustatisme, de la tectonique, de la subsidence: une mise au pointSedimentary sequences in the Upper Cretaceous of Aures Mountains (Algerie). Eustatsy, tectonics and subsidence: a development.

NASA Astrophysics Data System (ADS)

Herkat, Missoum; Delfaud, Jean

2000-06-01

The Upper Cretaceous of Aurès has been studied using a sedimentological approach to characterize the sequential organisation and deposits distribution in the basin. The sequential chain which was observed has been correlated to eustatic cycles defined on a global scale. Palaeogeographic reconstruction shows a basin with its south margin corresponding to a proximal platform domain with essentially carbonate deposits and toward the northeast, marly sedimentation of pelagic nature. The influence of NW-SE to WNW-ESE accidents on sedimentation control has been found preponderant. Therefore a system of tilted blocks toward the south characterizes a large part of the basin. The subsidence evolution through Upper Cretaceous is marked by a recovery of a tectonic distension during some phases (Late Albian and Lower Turonian) and an essentially thermic subsidence during the other periods. Finally some precocious tectonic phases appeared as early as the Santonian-Campanian transition. The evolution of the basin was thus controlled by the drift of the African plate during the expansion of the Atlantic ocean and also the tectonic influence which began to appear in north Alpine domain.

Paleosols of the Mid-Cretaceous: A Report from Zhejiang and Fujian, SE China

NASA Astrophysics Data System (ADS)

LI, Xianghui; CHEN, Sidun; CAO, Ke; CHEN, Yunhua; XU, Baoliang; JI, Yannan

An investigation on the mid-Cretaceous continental sediments was recently conducted in both SW Zhejiang and SW Fujian Provinces, SE China. It is the first time the Cretaceous paleosols in mainland China have been reported. Three types of paleosols are recognized, such as, argillisol, calcisol, and oxisol on the basis of observation on eleven cross sections and stops in the field. The argillisol is characterized by burrow and root trace within reddish (silty) mudrock, the calcisol marks by pedogenic carbonate concretion within pale purple calcareous mudrock, and the oxisol is the association of ferric tegument and concretion within reddish purple, grayish orange siltstone, and mudrock. According to climate direction of paleosol types, it is proposed that it could have been in aridity or semiaridity of subtropic climate during the Aptian-Albian epoch of the mid-Cretaceous in SW Zhejiang, where the calcisols were recorded in the Hengshan Formation, Zhongdai Formation, Jinhua Formation, Guantou Formation, and Chaochuan Formation; at the same time, it was in semiaridity of tropic climate in SW Fujian which was recorded by oxisols within the Bantou Formation, Junkou Formation, and Shaxian Formation. In the Cenomanian, it could become more moist in SW Zhejiang as evidenced by the production of the argillisol within the Quxian Formation with abundant organic activities, whereas the paleoclimate in SW Fujian in the Cenomanian might be similar with that in the Aptian-Albian even if the sediments were transformed to huge thick conglomerates (so-called "Danxia Landform") by tectonic uplift processes.

Novel Insect Leaf-Mining after the End-Cretaceous Extinction and the Demise of Cretaceous Leaf Miners, Great Plains, USA

PubMed Central

Donovan, Michael P.; Wilf, Peter; Labandeira, Conrad C.; Johnson, Kirk R.; Peppe, Daniel J.

2014-01-01

Plant and associated insect-damage diversity in the western U.S.A. decreased significantly at the Cretaceous-Paleogene (K-Pg) boundary and remained low until the late Paleocene. However, the Mexican Hat locality (ca. 65 Ma) in southeastern Montana, with a typical, low-diversity flora, uniquely exhibits high damage diversity on nearly all its host plants, when compared to all known local and regional early Paleocene sites. The same plant species show minimal damage elsewhere during the early Paleocene. We asked whether the high insect damage diversity at Mexican Hat was more likely related to the survival of Cretaceous insects from refugia or to an influx of novel Paleocene taxa. We compared damage on 1073 leaf fossils from Mexican Hat to over 9000 terminal Cretaceous leaf fossils from the Hell Creek Formation of nearby southwestern North Dakota and to over 9000 Paleocene leaf fossils from the Fort Union Formation in North Dakota, Montana, and Wyoming. We described the entire insect-feeding ichnofauna at Mexican Hat and focused our analysis on leaf mines because they are typically host-specialized and preserve a number of diagnostic morphological characters. Nine mine damage types attributable to three of the four orders of leaf-mining insects are found at Mexican Hat, six of them so far unique to the site. We found no evidence linking any of the diverse Hell Creek mines with those found at Mexican Hat, nor for the survival of any Cretaceous leaf miners over the K-Pg boundary regionally, even on well-sampled, surviving plant families. Overall, our results strongly relate the high damage diversity on the depauperate Mexican Hat flora to an influx of novel insect herbivores during the early Paleocene, possibly caused by a transient warming event and range expansion, and indicate drastic extinction rather than survivorship of Cretaceous insect taxa from refugia. PMID:25058404

Autonomous observing platform CO2 data shed new light on the Southern Ocean carbon cycle

NASA Astrophysics Data System (ADS)

Olsen, Are

2017-06-01

While the number of surface ocean CO2 partial pressure (pCO2) measurements has soared the recent decades, the Southern Ocean remains undersampled. Williams et al. (2017, https://doi.org/10.1002/2016GB005541) now present pCO2 estimates based on data from pH-sensor equipped Bio-Argo floats, which have been measuring in the Southern Ocean since 2014. The authors demonstrate the utility of these data for understanding the carbon cycle in this region, which has a large influence on the distribution of CO2 between the ocean and atmosphere. Biogeochemical sensors deployed on autonomous platforms hold the potential to shape our view of the ocean carbon cycle in the coming decades.

Peculiar macrophagous adaptations in a new Cretaceous pliosaurid

PubMed Central

Arkhangelsky, Maxim S.; Stenshin, Ilya M.; Uspensky, Gleb N.; Zverkov, Nikolay G.

2015-01-01

During the Middle and Late Jurassic, pliosaurid plesiosaurs evolved gigantic body size and a series of craniodental adaptations that have been linked to the occupation of an apex predator niche. Cretaceous pliosaurids (i.e. Brachaucheninae) depart from this morphology, being slightly smaller and lacking the macrophagous adaptations seen in earlier forms. However, the fossil record of Early Cretaceous pliosaurids is poor, concealing the evolution and ecological diversity of the group. Here, we report a new pliosaurid from the Late Hauterivian (Early Cretaceous) of Russia. Phylogenetic analyses using reduced consensus methods recover it as the basalmost brachauchenine. This pliosaurid is smaller than other derived pliosaurids, has tooth alveoli clustered in pairs and possesses trihedral teeth with complex serrated carinae. Maximum-likelihood ancestral state reconstruction suggests early brachauchenines retained trihedral teeth from their ancestors, but modified this feature in a unique way, convergent with macrophagous archosaurs or sphenacodontoids. Our findings indicate that Early Cretaceous marine reptile teeth with serrated carinae cannot be unequivocally assigned to metriorhynchoid crocodylomorphs. Furthermore, they extend the known diversity of dental adaptations seen in Sauropterygia, the longest lived clade of marine tetrapods. PMID:27019740

Biogeochemical significance of pelagic ecosystem function: an end-Cretaceous case study

PubMed Central

Penman, Donald E.; Rae, James W. B.

2016-01-01

Pelagic ecosystem function is integral to global biogeochemical cycling, and plays a major role in modulating atmospheric CO2 concentrations (pCO2). Uncertainty as to the effects of human activities on marine ecosystem function hinders projection of future atmospheric pCO2. To this end, events in the geological past can provide informative case studies in the response of ecosystem function to environmental and ecological changes. Around the Cretaceous–Palaeogene (K–Pg) boundary, two such events occurred: Deccan large igneous province (LIP) eruptions and massive bolide impact at the Yucatan Peninsula. Both perturbed the environment, but only the impact coincided with marine mass extinction. As such, we use these events to directly contrast the response of marine biogeochemical cycling to environmental perturbation with and without changes in global species richness. We measure this biogeochemical response using records of deep-sea carbonate preservation. We find that Late Cretaceous Deccan volcanism prompted transient deep-sea carbonate dissolution of a larger magnitude and timescale than predicted by geochemical models. Even so, the effect of volcanism on carbonate preservation was slight compared with bolide impact. Empirical records and geochemical models support a pronounced increase in carbonate saturation state for more than 500 000 years following the mass extinction of pelagic carbonate producers at the K–Pg boundary. These examples highlight the importance of pelagic ecosystems in moderating climate and ocean chemistry. PMID:27114586

Biospheric effects of a large extraterrestrial impact: Case study of the cretaceous/tertiary boundary crater

NASA Technical Reports Server (NTRS)

Pope, Kevin O.

1995-01-01

The Chicxulub impact crater, buried in the Yucatan carbonate platform in Mexico, is the site of the impact purported to have caused mass extinctions at the Cretaceous/Tertiary (K/T) boundary. A recently discovered Chicxulub ejecta deposit in Belize contains evidence of carbonate vaporization and precipitation from the vapor plume. Sulfate clasts are almost absent in the Belize ejecta, but are abundant in the coarse ejecta near the crater rim, hwich may reflect the greater abundance of sulfates deep in the target section. The absence of sulfate precipitates in Belize may indicate that most of the vaporized sulfur was deposited in the upper atmosphere. Hydrocode modeling of the impact indicates that between 0.4 to 7.0 x 10(exp 17) g of sulfur were vaporized by the impact in sulfates. Laser experiments indicate that SO2, SO3, and SO4 are produced, and that complex chemical reactions between plume constituents occur during condensation. The sulfur released as SO3 or SO4 converted rapidly into H2HO4 aerosol. A radiative transfer model coupled with a model of coagulation predicts that the aerosol prolonged the initial blackout period caused by impact dust only if it contained impurities. The sulfur released as SO2 converted to aerosol slowly due to the rate limiting oxidation of SO2. Radiative transfer calculations combined with rates of acid production, coagulation, and diffusion indicate that solar transmission was reduced to 10-20 percent of normal for a period of 8-13 years. This reduction produced a climate forcing (cooling) of -300 Wm(exp -2), which far exceeded the +8 Wm(exp -2) greenhouse warming caused by the CO2 released through the vaporization of carbonates, and therefore produced a decade of freezing and near-freezing temperatures. Several decades of moderate warming followed the decade of severe cooling due to the long residence time of CO2. The prolonged impact winter may have been a major cause of the K/T extinctions.

Impact of the terminal Cretaceous event on plant–insect associations

PubMed Central

Labandeira, Conrad C.; Johnson, Kirk R.; Wilf, Peter

2002-01-01

Evidence for a major extinction of insect herbivores is provided by presence–absence data for 51 plant–insect associations on 13,441 fossil plant specimens, spanning the Cretaceous/Paleogene boundary in southwestern North Dakota. The most specialized associations, which were diverse and abundant during the latest Cretaceous, almost disappeared at the boundary and failed to recover in younger strata even while generalized associations regained their Cretaceous abundances. These results are consistent with a sudden ecological perturbation that precipitated a diversity bottleneck for insects and plants. PMID:11854501

Carbon isotope geochemistry and geobiology

NASA Technical Reports Server (NTRS)

Desmarais, D.

1985-01-01

Carbon isotope fractionation values were used to understand the history of the biosphere. For example, plankton analyses confirmed that marine extinctions at the end of the Cretaceous period were indeed severe (see Hsu's article in Sundquist and Broeker, 1984). Variations in the isotopic compositions of carbonates and evaporitic sulfates during the Paleozoic reflect the relative abundances of euxinic (anoxic) marine environments and organic deposits from terrestrial flora. The carbon isotopic composition of Precambrian sediments suggest that the enzyme ribulose bisphosphate carboxylase has existed for perhaps 3.5 billion years.

Preliminary magnetostratigraphy and environmental magnetism of the Lower Cretaceous from the Italian Dolomites

NASA Astrophysics Data System (ADS)

Savian, J. F.; Jovane, L.; Florindo, F.; Lukeneder, A.

2011-12-01

The Lower Cretaceous (~146 to 100 Ma) represents an enigmatic time interval for paleoclimatic, paleogeography and paleomagnetic evolution of the Earth's history. The climatic changes include global oceanic anoxic events (OAEs), biotic changes, global excursions of carbon and strontium isotopes, rises in eustatic sea level and paleotemperature. Paleoceanography was marked by a rapid rate of ocean spreading in the Atlantic. The opening of the Atlantic Ocean was wide enough to allow significant circulation of masses of waters across the equator. This period is furthermore important for the oceanographic events occurring at the base of the Aptian (Selli Level). This period also present one of the most intriguing geomagnetic events: the long normal Cretaceous superchron, lasted for almost 40 million years. We study here the lower Cretaceous deposits of the Puez section in the Dolomites (northern Italy) which represents a continuous section during this period. The samples collected represent marine sedimentary materials of the Biancone and Puez formations. The Puez section consists essentially of green-grey to red limestones and calcareous marls. We present preliminary results of integrated magnetostratigraphic analysis, including a detailed lithostratigraphy and environmental magnetism. We recognize magnetic behavior that are relative to normal polarity (the normal Cretaceous superchron), with a short reverse interval that might represent the M-1r event. We also recognize a series of normal and reverse polarities (below the normal Cretaceous superchron) which can be referred to the magnetozones M1/M5. The environmental magnetic data consists of magnetic susceptibility (χ), natural remanent magnetization (NRM), anhysteretic remanent magnetization (ARM), isothermal remanent magnetization (IRM) at 900 mT and backfield isothermal remanent magnetization (BIRM) at 100 mT and 300 mT. Derived parameters, such as S-ratio (S300=BIRM300/IRM900) and hard isothermal remanent

Late Cretaceous vicariance in Gondwanan amphibians.

PubMed

Van Bocxlaer, Ines; Roelants, Kim; Biju, S D; Nagaraju, J; Bossuyt, Franky

2006-12-20

Overseas dispersals are often invoked when Southern Hemisphere terrestrial and freshwater organism phylogenies do not fit the sequence or timing of Gondwana fragmentation. We used dispersal-vicariance analyses and molecular timetrees to show that two species-rich frog groups, Microhylidae and Natatanura, display congruent patterns of spatial and temporal diversification among Gondwanan plates in the Late Cretaceous, long after the presumed major tectonic break-up events. Because amphibians are notoriously salt-intolerant, these analogies are best explained by simultaneous vicariance, rather than by oceanic dispersal. Hence our results imply Late Cretaceous connections between most adjacent Gondwanan landmasses, an essential concept for biogeographic and palaeomap reconstructions.

Morphology-dependent Electrochemical Enhancements of Porous Carbon as Sensitive Determination Platform for Ascorbic Acid, Dopamine and Uric Acid

NASA Astrophysics Data System (ADS)

Cheng, Qin; Ji, Liudi; Wu, Kangbing; Zhang, Weikang

2016-02-01

Using starch as the carbon precursor and different-sized ZnO naoparticles as the hard template, a series of porous carbon materials for electrochemical sensing were prepared. Experiments of scanning electron microscopy, transmission electron microscopy and Nitrogen adsorption-desorption isotherms reveal that the particle size of ZnO has big impacts on the porous morphology and surface area of the resulting carbon materials. Through ultrasonic dispersion of porous carbon and subsequent solvent evaporation, different sensing interfaces were constructed on the surface of glassy carbon electrode (GCE). The electrochemical behaviors of ascorbic acid (AA), dopamine (DA) and uric acid (UA) were studied. On the surface of porous carbon materials, the accumulation efficiency and electron transfer ability of AA, DA and UA are improved, and consequently their oxidation signals enhance greatly. Moreover, the interface enhancement effects of porous carbon are also controlled by the particle size of hard template. The constructed porous carbon interface displays strong signal amplification ability and holds great promise in constructing a sensitive platform for the simultaneous determination of AA, DA and UA.

Cretaceous extinctions - Evidence for wildfires and search for meteoritic material

NASA Technical Reports Server (NTRS)

Wolbach, W. S.; Lewis, R. S.; Anders, E.

1985-01-01

The results of analyses of the contents of deposits in the Cretaceous-Ternary (K-T) transition at three sites worldwide are discussed. The study was undertaken to examine the composition of the object which may have struck the earth, causing widespread biotic extinction. The data indicate that most of the parent body was destroyed on impact, a condition which would also hold true for comets, suggesting that comets were not a source of prebiotic life. A four-orders-of-magnitude excess of carbon in the K-T layer is considered in terms of its source, which is suspected to be deposits from wildfires. The consequent extinctions of species are regarded as possibly making the current nuclear winter scenarios too optimistic.

COCAP - A compact carbon dioxide analyser for airborne platforms

NASA Astrophysics Data System (ADS)

Kunz, Martin; Lavrič, Jošt V.; Jeschag, Wieland; Bryzgalov, Maksym; Hök, Bertil; Heimann, Martin

2014-05-01

Airborne platforms are a valuable tool for atmospheric trace gas measurements due to their capability of movement in three dimensions, covering spatial scales from metres to thousands of kilometres. Although crewed research aircraft are flexible in payload and range, their use is limited by high initial and operating costs. Small unmanned aerial vehicles (UAV) have the potential for substantial cost reduction, but require lightweight, miniaturized and energy-efficient scientific equipment. We are developing a COmpact Carbon dioxide analyser for Airborne Platforms (COCAP). It contains a non-dispersive infrared CO2sensor with a nominal full scale of 3000 μmol/mol. Sampled air is dried with magnesium perchlorate before it enters the sensor. This enables measurement of the dry air mole fraction of CO2, as recommended by the World Meteorological Organization. During post-processing, the CO2 measurement is corrected for temperature and pressure variations in the gas line. Allan variance analysis shows that we achieve a precision of better than 0.4 μmol/mol for 10 s averaging time. We plan to monitor the analyser's stability during flight by measuring reference air from a miniature gas tank in regular intervals. Besides CO2, COCAP measures relative humidity, temperature and pressure of ambient air. An on-board GPS receiver delivers accurate timestamps and allows georeferencing. Data is both stored on a microSD card and simultaneously transferred over a wireless serial interface to a ground station for real-time review. The target weight for COCAP is less than 1 kg. We deploy COCAP on a commercially available fixed-wing UAV (Bormatec Explorer) with a wingspan of 2.2 metres. The UAV has high payload capacity (2.5 kg) as well as sufficient space in the fuselage (80x80x600 mm3). It is built from a shock-resistant foam material, which allows quick repair of minor damages in the field. In case of severe damage spare parts are readily available. Calculations suggest that the

Subseafloor fluid mixing and fossilized microbial life in a Cretaceous 'Lost City'-type hydrothermal system at the Iberian Margin

NASA Astrophysics Data System (ADS)

Klein, F.; Humphris, S. E.; Guo, W.; Schubotz, F.; Schwarzenbach, E. M.; Orsi, W.

2015-12-01

Subseafloor mixing of reduced hydrothermal fluids with seawater is believed to provide the energy and substrates needed to support autotrophic microorganisms in the hydrated oceanic mantle (serpentinite). Despite the potentially significant implications for the distribution of microbial life on Earth and other water-bearing planetary bodies, our understanding of such environments remains elusive. In the present study we examined fossilized microbial communities and fluid mixing processes in the subseafloor of a Cretaceous 'Lost City'-type hydrothermal system at the passive Iberia Margin (ODP Leg 149, Hole 897D). Brucite and calcite co-precipitated from mixed fluids ca. 65m below the Cretaceous palaeo-seafloor at temperatures of 32±4°C within steep chemical gradients (fO2, pH, CH4, SO4, ΣCO2, etc) between weathered, carbonate-rich serpentinite breccia and serpentinite. Mixing of oxidized seawater and strongly reducing hydrothermal fluid at moderate temperatures created conditions capable of supporting microbial activity within the oceanic basement. Dense microbial colonies are fossilized in brucite-calcite veins that are strongly enriched in organic carbon but depleted in 13C. We detected a combination of bacterial diether lipid biomarkers, archaeol and archaeal tetraethers analogous to those found in brucite-carbonate chimneys at the active Lost City hydrothermal field. The exposure of mantle rocks to seawater during the breakup of Pangaea fueled chemolithoautotrophic microbial communities at the Iberia Margin during the Cretaceous, possibly before the onset of seafloor spreading in the Atlantic. 'Lost City'-type serpentinization systems have been discovered at mid-ocean ridges, in forearc settings of subduction zones and at continental margins. It appears that, wherever they occur, they can support microbial life, even in deep subseafloor environments as demonstrated in the present study. Because equivalent systems have likely existed throughout most of Earth

Subseafloor fluid mixing and fossilized microbial life in a Cretaceous 'Lost City'-type hydrothermal system at the Iberian Margin

NASA Astrophysics Data System (ADS)

Klein, F.; Humphris, S. E.; Guo, W.; Schubotz, F.; Schwarzenbach, E. M.; Orsi, W.

2014-12-01

Subseafloor mixing of reduced hydrothermal fluids with seawater is believed to provide the energy and substrates needed to support autotrophic microorganisms in the hydrated oceanic mantle (serpentinite). Despite the potentially significant implications for the distribution of microbial life on Earth and other water-bearing planetary bodies, our understanding of such environments remains elusive. In the present study we examined fossilized microbial communities and fluid mixing processes in the subseafloor of a Cretaceous 'Lost City'-type hydrothermal system at the passive Iberia Margin (ODP Leg 149, Hole 897D). Brucite and calcite co-precipitated from mixed fluids ca. 65m below the Cretaceous palaeo-seafloor at temperatures of 32±4°C within steep chemical gradients (fO2, pH, CH4, SO4, ΣCO2, etc) between weathered, carbonate-rich serpentinite breccia and serpentinite. Mixing of oxidized seawater and strongly reducing hydrothermal fluid at moderate temperatures created conditions capable of supporting microbial activity within the oceanic basement. Dense microbial colonies are fossilized in brucite-calcite veins that are strongly enriched in organic carbon but depleted in 13C. We detected a combination of bacterial diether lipid biomarkers, archaeol and archaeal tetraethers analogous to those found in brucite-carbonate chimneys at the active Lost City hydrothermal field. The exposure of mantle rocks to seawater during the breakup of Pangaea fueled chemolithoautotrophic microbial communities at the Iberia Margin during the Cretaceous, possibly before the onset of seafloor spreading in the Atlantic. 'Lost City'-type serpentinization systems have been discovered at mid-ocean ridges, in forearc settings of subduction zones and at continental margins. It appears that, wherever they occur, they can support microbial life, even in deep subseafloor environments as demonstrated in the present study. Because equivalent systems have likely existed throughout most of Earth

Paleoenvironmental reconstruction and evolution of an Upper Cretaceous lacustrine-fluvial-deltaic sequence in the Parecis Basin, Brazil

NASA Astrophysics Data System (ADS)

Rubert, Rogerio R.; Mizusaki, Ana Maria Pimentel; Martinelli, Agustín G.; Urban, Camile

2017-12-01

The Cretaceous in the Brazilian Platform records events of magmatism, tectonism and sedimentation coupled to the Gondwana breakup. Some of these events are registered as sedimentary sequences in interior basins, such as in the Cretaceous sequence of the Alto Xingu Sub-basin, Parecis Basin, Central Brazil. This article proposes the faciologic characterization and paleoenvironmental reconstruction of the Cretaceous sequence of the eastern portion of the Parecis Basin and its relation with some reactivated structures as, for instance, the Serra Formosa Arch. Based on both data from outcrops and core drillings a paleoenvironmental and evolutionary reconstruction of the sequence is herein presented. The base of the studied section is characterized by chemical and low energy clastic sedimentation of Lake Bottom and Shoreline, in a context of fast initial subsidence and low sedimentation rate. As the subsidence process decreased, a deltaic progradation became dominant with deposition in a prodelta environment, followed by a deltaic front and deltaic plain interbedded with fluvial plain, and aeolian deposition completing the sequence. The inferred Coniacian-Santonian age is based on vertebrate (fishes and notosuchians) and ostracod fossils with regional chrono-correlates in the Adamantina (Bauru Group), Capacete (Sanfranciscana Basin), and Bajo de la Carpa (Neuquén Group, in Argentina) formations. The formation of a Coniacian depocenter in the Alto Xingu Sub-basin is associated to the Turonian-Coniacian reactivation event in the Peruvian Orogenic Phase of the Andean Orogeny, with the transference of stresses to interplate setting, reactivating Proterozoic structures of the basement.

The sequence stratigraphy, sedimentology, and economic importance of evaporite carbonate transitions: a review

NASA Astrophysics Data System (ADS)

Sarg, J. F.

2001-04-01

-energy, shallow water grainstones and packstones to nonporous evaporitic lagoonal dolomite and sabkha anhydrite occurs in the Upper Permian San Andres/Grayburg sequences of the Permian basin. This facies change provides the trap for secondary oil pools on the basinward flanks of fields that are productive from highstand facies identical to the lowstand dolograinstones. Type 2 lowstand systems, like the Smackover Limestone of the Gulf of Mexico, show a similar relationship. Commonly, these evaporite systems are a facies mosaic of salina and sabkha evaporites admixed with wadi siliciclastics. They overlie and seal highstand carbonate platforms containing reservoir facies of shoalwater nonskeletal and skeletal grainstones. Further basinward these evaporites change facies into similar porous platform facies, and contain separate hydrocarbon traps. Transgressions in arid settings over underfilled platforms (e.g. Zechstein (Permian) of Europe; Ferry Lake Anhydrite (Cretaceous), Gulf of Mexico) can result in deposition of alternating cyclic carbonates and evaporites in broad, shallow subaqueous hypersaline environments. Evaporites include bedded and palmate gypsum layers. Mudstones and wackestones are deposited in mesosaline, shallow subtidal to low intertidal environments during periodic flooding of the platform interior. Highstand systems tracts are characterized by thick successions of m-scale, brining upward parasequences in platform interior settings. The Seven Rivers Formation (Guadalupian) of the Permian basin typifies this transition. An intertonguing of carbonate and sulfates is interpreted to occur in a broad, shallow subaqueous hypersaline shelf lagoon behind the main restricting shelf-edge carbonate complex. Underlying paleodepositional highs appear to control the position of the initial facies transition. Periodic flooding of the shelf interior results in widespread carbonate deposition comprised of mesosaline, skeletal-poor peloid dolowackestones/mudstones. Progressive

A New Hadrosauroid Dinosaur from the Early Late Cretaceous of Shanxi Province, China

PubMed Central

Wang, Run-Fu; You, Hai-Lu; Xu, Shi-Chao; Wang, Suo-Zhu; Yi, Jian; Xie, Li-Juan; Jia, Lei; Li, Ya-Xian

2013-01-01

Background The origin of hadrosaurid dinosaurs is far from clear, mainly due to the paucity of their early Late Cretaceous close relatives. Compared to numerous Early Cretaceous basal hadrosauroids, which are mainly from Eastern Asia, only six early Late Cretaceous (pre-Campanian) basal hadrosauroids have been found: three from Asia and three from North America. Methodology/Principal Findings Here we describe a new hadrosauroid dinosaur, Yunganglong datongensis gen. et sp. nov., from the early Late Cretaceous Zhumapu Formation of Shanxi Province in northern China. The new taxon is represented by an associated but disarticulated partial adult skeleton including the caudodorsal part of the skull. Cladistic analysis and comparative studies show that Yunganglong represents one of the most basal Late Cretaceous hadrosauroids and is diagnosed by a unique combination of features in its skull and femur. Conclusions/Significance The discovery of Yunganglong adds another record of basal Hadrosauroidea in the early Late Cretaceous, and helps to elucidate the origin and evolution of Hadrosauridae. PMID:24204734

A new hadrosauroid dinosaur from the early late cretaceous of Shanxi Province, China.

PubMed

Wang, Run-Fu; You, Hai-Lu; Xu, Shi-Chao; Wang, Suo-Zhu; Yi, Jian; Xie, Li-Juan; Jia, Lei; Li, Ya-Xian

2013-01-01

The origin of hadrosaurid dinosaurs is far from clear, mainly due to the paucity of their early Late Cretaceous close relatives. Compared to numerous Early Cretaceous basal hadrosauroids, which are mainly from Eastern Asia, only six early Late Cretaceous (pre-Campanian) basal hadrosauroids have been found: three from Asia and three from North America. Here we describe a new hadrosauroid dinosaur, Yunganglong datongensis gen. et sp. nov., from the early Late Cretaceous Zhumapu Formation of Shanxi Province in northern China. The new taxon is represented by an associated but disarticulated partial adult skeleton including the caudodorsal part of the skull. Cladistic analysis and comparative studies show that Yunganglong represents one of the most basal Late Cretaceous hadrosauroids and is diagnosed by a unique combination of features in its skull and femur. The discovery of Yunganglong adds another record of basal Hadrosauroidea in the early Late Cretaceous, and helps to elucidate the origin and evolution of Hadrosauridae.

Late cretaceous extensional tectonics and associated igneous activity on the northern margin of the Gulf of Mexico Basin

NASA Technical Reports Server (NTRS)

Bowen, R. L.; Sundeen, D. A.

1985-01-01

Major, dominantly compressional, orogenic episodes (Taconic, Acadian, Alleghenian) affected eastern North America during the Paleozoic. During the Mesozoic, in contrast, this same region was principally affected by epeirogenic and extensional tectonism; one episode of comparatively more intense tectonic activity involving extensive faulting, uplift, sedimentation, intrusion and effusion produced the Newark Series of eposits and fault block phenomena. This event, termed the Palisades Disturbance, took place during the Late Triassic - Earliest Jurassic. The authors document a comparable extensional tectonic-igneous event occurring during the Late Cretaceous (Early Gulfian; Cenomanian-Santonian) along the southern margin of the cratonic platform from Arkansas to Georgia.

Preliminary geologic mapping of Cretaceous and Tertiary formations in the eastern part of the Little Snake River coal field, Carbon County, Wyoming

USGS Publications Warehouse

Haacke, Jon E.; Barclay, C. S. Venable; Hettinger, Robert D.

2016-09-30

In the 1970s and 1980s, C.S. Venable Barclay conducted geologic mapping of areas primarily underlain by Cretaceous coals in the eastern part of the Little Snake River coal field (LSR) in Carbon County, southwest Wyoming. With some exceptions, most of the mapping data were never published. Subsequently, after his retirement from the U.S. Geological Survey (USGS), his field maps and field notebooks were archived in the USGS Field Records. Due to a pending USGS coal assessment of the Little Snake River coal field area and planned geological mapping to be conducted by the Wyoming State Geological Survey, Barclay’s mapping data needed to be published to support these efforts. Subsequently, geologic maps were scanned and georeferenced into a geographic information system, and project and field notes were scanned into Portable Document Format (PDF) files. Data for seventeen 7½-minute quadrangles are presented in this report. This publication is solely intended to compile the mapping data as it was last worked on by Barclay and provides no interpretation or modification of his work.

Quantification of a greenhouse hydrologic cycle from equatorial to polar latitudes: The mid-Cretaceous water bearer revisited

USGS Publications Warehouse

Suarez, M.B.; Gonzalez, Luis A.; Ludvigson, Greg A.

2011-01-01

This study aims to investigate the global hydrologic cycle during the mid-Cretaceous greenhouse by utilizing the oxygen isotopic composition of pedogenic carbonates (calcite and siderite) as proxies for the oxygen isotopic composition of precipitation. The data set builds on the Aptian-Albian sphaerosiderite ??18O data set presented by Ufnar et al. (2002) by incorporating additional low latitude data including pedogenic and early meteoric diagenetic calcite ??18O. Ufnar et al. (2002) used the proxy data derived from the North American Cretaceous Western Interior Basin (KWIB) in a mass balance model to estimate precipitation-evaporation fluxes. We have revised this mass balance model to handle sphaerosiderite and calcite proxies, and to account for longitudinal travel by tropical air masses. We use empirical and general circulation model (GCM) temperature gradients for the mid-Cretaceous, and the empirically derived ??18O composition of groundwater as constraints in our mass balance model. Precipitation flux, evaporation flux, relative humidity, seawater composition, and continental feedback are adjusted to generate model calculated groundwater ??18O compositions (proxy for precipitation ??18O) that match the empirically-derived groundwater ??18O compositions to within ??0.5???. The model is calibrated against modern precipitation data sets.Four different Cretaceous temperature estimates were used: the leaf physiognomy estimates of Wolfe and Upchurch (1987) and Spicer and Corfield (1992), the coolest and warmest Cretaceous estimates compiled by Barron (1983) and model outputs from the GENESIS-MOM GCM by Zhou et al. (2008). Precipitation and evaporation fluxes for all the Cretaceous temperature gradients utilized in the model are greater than modern precipitation and evaporation fluxes. Balancing the model also requires relative humidity in the subtropical dry belt to be significantly reduced. As expected calculated precipitation rates are all greater than modern

Fossil bryophytes as recorders of ancient CO2 levels: Experimental evidence and a Cretaceous case study

NASA Astrophysics Data System (ADS)

Fletcher, Benjamin J.; Beerling, David J.; Brentnall, Stuart J.; Royer, Dana L.

2005-09-01

Biological and geochemical CO2 proxies provide critical constraints on understanding the role of atmospheric CO2 in driving climate change during Earth history. As no single existing CO2 proxy is without its limitations, there is a clear need for new approaches to reconstructing past CO2 concentrations. Here we develop a new pre-Quaternary CO2 proxy based on the stable carbon isotope composition (δ13C) of astomatous land plants. In a series of CO2-controlled laboratory experiments, we show that the carbon isotope discrimination (Δ13C) of a range of bryophyte (liverwort and moss) species increases with atmospheric CO2 across the range 375 to 6000 ppm. Separate experiments establish that variations in growth temperature, water content and substrate type have minor impacts on the Δ13C of liverworts but not mosses, indicating the greater potential of liverworts to faithfully record past variations in CO2. A mechanistic model for calculating past CO2 concentrations from bryophyte Δ13C (White et al., 1994) is extended and calibrated using our experimental results. The potential for fossil liverworts to record past CO2 changes is investigated by analyzing the δ13C of specimens collected from Alexander Island, Antarctica dating to the "greenhouse" world of the mid-Cretaceous. Our analysis and isotopic model yield mid-Cretaceous CO2 concentrations of 1000-1400 ppm, in general agreement with independent proxy data and long-term carbon cycle models. The exceptionally long evolutionary history of bryophytes offers the possibility of reconstructing CO2 concentrations back to the mid-Ordovician, pre-dating all currently used quantitative CO2 proxies.

Geological history of the west Libyan offshore and adjoining regions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Benniran, M.M.; Taleb, T.M.; McCrossan, R.G.

1988-08-01

The continental margin of the African plate north of Libya is separated from the Saharan platform to the south by a major Variscan fault system running along the coastline. The structural evolution of three sedimentary basins within the margin is discussed. The Jeffara basin, onshore western Libya-southern Tunisia, formed as a right-lateral pull-part late in the Variscan event. When the strike-slip motion ceased in the Late Permian, the basin continued to subside thermally. The Sabratah (Tripolitanian) basin, offshore western Libya-southern Tunisia, and the Benghazi basin in the Sirte rise were both formed as left-lateral pull-aparts in the Late Triassic-Early Jurassic.more » From the Middle Jurassic to the present they have subsided thermally. Onshore the lower Mesozoic is characterized by continental and nearshore clastics, separated by an evaporite sequence of Late Triassic-Early Jurassic age. Offshore this sequence is thought to grade northward into open marine carbonates. Uplift along the edge of the Saharan platform during the Early Cretaceous sourced coarse clastics, which grade northward into a thick sequence of shallow-water carbonates. Throughout the Late Cretaceous and early Tertiary, high-energy carbonates were deposited around the flanks of the Sabratah basin, grading into deeper-water, fine-grained clastics and carbonates toward the center of the basin. The late Tertiary succession is dominated by clastics derived from the growing Tellian Atlas to the northwest. During the Mesozoic and Tertiary a thick sequence of carbonates was deposited on the Pelagian platform to the north of the Sabratah basin. Periodically the platform was exposed subaerially.« less

A basal thunnosaurian from Iraq reveals disparate phylogenetic origins for Cretaceous ichthyosaurs

PubMed Central

Fischer, Valentin; Appleby, Robert M.; Naish, Darren; Liston, Jeff; Riding, James B.; Brindley, Stephen; Godefroit, Pascal

2013-01-01

Cretaceous ichthyosaurs have typically been considered a small, homogeneous assemblage sharing a common Late Jurassic ancestor. Their low diversity and disparity have been interpreted as indicative of a decline leading to their Cenomanian extinction. We describe the first post-Triassic ichthyosaur from the Middle East, Malawania anachronus gen. et sp. nov. from the Early Cretaceous of Iraq, and re-evaluate the evolutionary history of parvipelvian ichthyosaurs via phylogenetic and cladogenesis rate analyses. Malawania represents a basal grade in thunnosaurian evolution that arose during a major Late Triassic radiation event and was previously thought to have gone extinct during the Early Jurassic. Its pectoral morphology appears surprisingly archaic, retaining a forefin architecture similar to that of its Early Jurassic relatives. After the initial latest Triassic radiation of early thunnosaurians, two subsequent large radiations produced lineages with Cretaceous representatives, but the radiation events themselves are pre-Cretaceous. Cretaceous ichthyosaurs therefore include distantly related lineages, with contrasting evolutionary histories, and appear more diverse and disparate than previously supposed. PMID:23676653

Numerical analysis of seawater circulation in carbonate platforms: II. The dynamic interaction between geothermal and brine reflux circulation

USGS Publications Warehouse

Jones, G.D.; Whitaker, F.F.; Smart, P.L.; Sanford, W.E.

2004-01-01

Density-driven seawater circulation may occur in carbonate platforms due to geothermal heating and / or reflux of water of elevated salinity. In geothermal circulation lateral contrasts in temperature between seawater and platform groundwaters warmed by the geothermal heat flux result in upward convective flow, with colder seawater drawn into the platform at depth. With reflux circulation, platform-top waters concentrated by evaporation flow downward, displacing less dense underlying groundwaters. We have used a variable density groundwater flow model to examine the pattern, magnitude and interaction of these two different circulation mechanisms, for mesosaline platform-top waters (50???) and brines concentrated up to saturation with respect to gypsum (150???) and halite (246???). Geothermal circulation, most active around the platform margin, becomes restricted and eventually shut-off by reflux of brines from the platform interior towards the margin. The persistence of geothermal circulation is dependent on the rate of brine reflux, which is proportional to the concentration of platform-top brines and also critically dependent on the magnitude and distribution of permeability. Low permeability evaporites can severely restrict reflux whereas high permeability units in hydraulic continuity enhance brine transport. Reduction in permeability with depth and anisotropy of permeability (kv < < kh) focuses flow laterally in the shallow subsurface (<1 km), resulting in a horizontally elongated brine plume. Aquifer porosity and dispersivity are relatively minor controls on reflux. Platform brines can entrain surficial seawater when brine generating conditions cease but the platform-top remains submerged, a variant of reflux we term "latent reflux". Brines concentrated up to gypsum saturation have relatively long residence times of at least 100 times the duration of the reflux event. They thus represent a long-term control on post-reflux groundwater circulation, and

Predatory Dinosaurs from the Sahara and Late Cretaceous Faunal Differentiation

PubMed

Sereno; Dutheil; Iarochene; Larsson; Lyon; Magwene; Sidor; Varricchio; Wilson

1996-05-17

Late Cretaceous (Cenomanian) fossils discovered in the Kem Kem region of Morocco include large predatory dinosaurs that inhabited Africa as it drifted into geographic isolation. One, represented by a skull approximately 1.6 meters in length, is an advanced allosauroid referable to the African genus Carcharodontosaurus. Another, represented by a partial skeleton with slender proportions, is a new basal coelurosaur closely resembling the Egyptian genus Bahariasaurus. Comparisons with Cretaceous theropods from other continents reveal a previously unrecognized global radiation of carcharodontosaurid predators. Substantial geographic differentiation of dinosaurian faunas in response to continental drift appears to have arisen abruptly at the beginning of the Late Cretaceous.

3D stratigraphic forward modelling of Shu'aiba Platform stratigraphy in the Bu Hasa Field, Abu Dhabi, United Arab Emirates.

NASA Astrophysics Data System (ADS)

Hu, J.; Lokier, S. W.

2012-04-01

This paper presents the results of three dimensional sequence stratigraphic forward modelling of the Aptian age Shu'aiba Formation from Abu Dhabi, United Arab Emirates (UAE). The Shu'aiba Formation lies within the uppermost part of the Lower Cretaceous Thamama Group and forms one of the most prolific hydrocarbon reservoir intervals of the Middle East with production dating back to the 1960's. The Shu'aiba Formation developed as a series of laterally-extensive shallow-water carbonate platforms in an epeiric sea that extended over the northern margin of the African-Arabian Plate. This shallow sea was bounded by the Arabian Shield to the west and the passive margin with the Neo-Tethys Ocean towards the north and east (Droste, 2010). The exposed Arabian Shield acted as a source of siliciclastic sediments to westernmost regions, however, more offshore areas were dominated by shallow-water carbonate deposition. Carbonate production was variously dominated by Lithocodium-Baccinella, orbitolinid foraminifera and rudist bivalves depending on local conditions. While there have been numerous studies of this important stratigraphic interval (for examples see van Buchem et al., 2010), there has been little attempt to simulate the sequence stratigraphic development of the formation. During the present study modelling was undertaken utilising the CARBONATE-3D stratigraphic forward modelling software (Warrlich et al., 2008; Warrlich et al., 2002)) thus allowing for the control of a diverse range of internal and external parameters on carbonate sequence development. This study focuses on platform development in the onshore Bu Hasa Field - the first giant oilfield to produce from the Shu'aiba Formation in Abu Dhabi. The carbonates of the Bu Hasa field were deposited on the southwest slope of the intra-shelf Bab Basin, siliciclastic content is minor. Initially these carbonates were algal dominated with rudist mounds becoming increasingly important over time (Alsharhan, 1987

Mass Wasting during the Cretaceous/Tertiary Transition in the North Atlantic: Relationship to the Chicxulub Impact?

NASA Astrophysics Data System (ADS)

Mateo, Paula; Keller, Gerta; Adatte, Thierry; Spangenberg, Jorge

2015-04-01

Deep-sea sections in the North Atlantic are claimed to contain the most complete sedimentary records and ultimate proof that the Chicxulub impact is Cretaceous-Tertiary boundary (KTB) in age and caused the mass extinction. A multi-disciplinary study of North Atlantic DSDP Sites 384, 386 and 398, based on high-resolution planktonic foraminiferal biostratigraphy, carbon and oxygen stable isotopes, clay and whole-rock mineralogy and granulometry, reveals the age, stratigraphic completeness and nature of sedimentary disturbances. Results show a major KTB hiatus at Site 384 with zones CF1, P0 and P1a missing, spanning at least ~540 ky, similar to other North Atlantic and Caribbean localities associated with tectonic activity and Gulf Stream erosion. At Sites 386 and 398, discrete intervals of disturbed sediments with mm-to-cm-thick spherule layers have previously been interpreted as KTB age impact-generated earthquakes destabilizing continental margins prior to settling of impact spherules. However, improved age control based on planktonic foraminifera indicates deposition in the early Danian zone P1a(2) (upper Parvularugoglobigerina eugubina zone) more than 100 ky after the KTB. At Site 386, two intervals of white chalk contain very small (<63 μm) early Danian zone P1a(2) (65%) and common reworked Cretaceous (35%) species, in contrast to the in situ red-brown and green abyssal clays that are devoid of carbonate. In addition, high calcite, mica and kaolinite and upward-fining are observed in the chalks, indicating downslope transport from shallow waters and sediment winnowing via distal turbidites. At Site 398, convoluted red to tan sediments with early Danian and reworked Cretaceous species represent slumping of shallow water sediments as suggested by dominance of mica and low smectite compared to in situ deposition. We conclude that mass wasting was likely the result of earthquakes associated with increased tectonic activity in the Caribbean and the Iberian Peninsula

The Boquillas Formation of the Big Bend National Park, Texas, USA, a reference Cenomanian through Santonian (Upper Cretaceous) carbonate succession at the southern end of the Western Interior Seaway

NASA Astrophysics Data System (ADS)

Cooper, Dee Ann; Cooper, Roger W.; Stevens, James B.; Stevens, M. S.; Cobban, William A.; Walaszczyk, Ireneusz

2017-12-01

The upper lower Cenomanian through middle Santonian (Upper Cretaceous) of the Boquillas Formation in the Big Bend Region of Trans-Pecos Texas consists of a marine carbonate succession deposited at the southern end of the Western Interior Seaway. The Boquillas Formation, subdivided into the lower, c. 78 m thick limestone-shale Ernst Member, and the upper, c. 132 m thick limestone/chalk/marl San Vicente Member, was deposited in a shallow shelf open marine environment at the junction between the Western Interior Seaway and the western margins of the Tethys Basin. Biogeographically, the area was closely tied with the southern Western Interior Seaway. The richly fossiliferous upper Turonian, Coniacian and lower Santonian parts of the Boquillas Formation are particularly promising for multistratigraphic studies.

Upper Cretaceous Shannon Sandstone reservoirs, Powder River Basin, Wyoming: evidence for organic acid diagenesis?

USGS Publications Warehouse

Hansley, P.L.; Nuccio, V.F.

1992-01-01

Comparison of the petrology of shallow and deep oil reservoirs in the Upper Cretaceous Shannon Sandstone Beds of the Steele Member of the Cody Shale strongly suggests that organic acids have had a more significant impact on the diagenetic alteration of aluminosilicate grains and carbonate cements in the deep reservoirs than in the shallow reservoirs. Vitrinite reflectance and Rock-Eval measurements, as well as the time-temperature index and kinetic modeling, indicate that deep reservoirs have been subjected to maximum temperatures of approximately 110-120??C, whereas shallow reservoirs have reached only 75??C. -from Authors

The Cretaceous/Tertiary Extinction Controversy.

ERIC Educational Resources Information Center

McCartney, Kevin

1984-01-01

The cause of the Cretaceous/Tertiary extinction has become a major geologic controversy. Current evidence for the two opposing views is reviewed to provide an introduction to the controversy and to form the basis for a seminar of discussion topic. (Author/JN)

Into the deep: A coarse-grained carbonate turbidite thalweg generated by gigantic submarine chutes

NASA Astrophysics Data System (ADS)

Mulder, Thierry; Gillet, Hervé; Reijmer, John; Droxler, André; cavailhes, Thibault; Hanquiez, Vincent; Fauquembergue, Kelly; Bujan, Stéphane; Blanck, David; bashah, Sara; Guiastrennec, Léa; Fabregas, Natacha; Recouvreur, Audrey; Seibert, Chloé

2017-04-01

New high-resolution multibeam mapping, in the Southeastern Bahamas, images in exquisite details the southern part of Exuma Sound, and its unchartered transition area to the deep abyssal plain of the Western North Atlantic bounded by the Bahama Escarpment (BE) between San Salvador Island and Samana Cay, referred here to the San Salvador abyssal plain. The transition area is locally referred to as Crooked Island Passage, loosely delineated by Crooked, Long, and Conception Islands, Rum and Samana Cays. Surprisingly in such a pure carbonate landscape, the newly established map reveals the detailed and complex morphology of a giant valley formed by numerous gravity flows originated in Exuma Sound itself, in addition to many secondary slope gullies and smaller tributaries draining the surrounding upper slopes. The valley referred here as the Exuma canyon system starts with a perched valley with low sinuosity, characterized by several flow restrictions and knickpoints initiated by the presence of drowned isolated platforms and merging tributaries. The valley abruptly transforms itself into a deep incised canyon, rivaling the depth of the Colorado Grand Canyon, through two major knickpoints with outsized chutes exceeding several hundred of meters in height, a total of 1600-1800 m. The sudden transformation of the wide valley into a deep narrow canyon, occurring when the flows incised deep into an underlying lower Cretaceous drowned carbonate platform, generates a huge hydraulic jump and creates an enormous plunge pool and related deposits with mechanisms comparable to the ones operating along giant subaerial waterfalls. The high kinetic flow energy, constrained by this narrow and deeply incised canyon, formed, when it is released at its mouth in the abyssal plain, a wide deep-sea channel with well-developed levees and fan, made of coarse-grained carbonate defined layers separated by fine carbonate sediments mixed with fine siliciclastics transported along the BE by the

Late Cretaceous-Early Palaeogene tectonic development of SE Asia

NASA Astrophysics Data System (ADS)

Morley, C. K.

2012-10-01

The Late Cretaceous-Early Palaeogene history of the continental core of SE Asia (Sundaland) marks the time prior to collision of India with Asia when SE Asia, from the Tethys in the west to the Palaeo-Pacific in the east, lay in the upper plate of subduction zones. In Myanmar and Sumatra, subduction was interrupted in the Aptian-Albian by a phase of arc accretion (Woyla and Mawgyi arcs) and in Java, eastern Borneo and Western Sulawesi by collision of continental fragments rifted from northern Australia. Subsequent resumption of subduction in the Myanmar-Thailand sector explains: 1) early creation of oceanic crust in the Andaman Sea in a supra-subduction zone setting ~ 95 Ma, 2) the belt of granite plutons of Late Cretaceous-Early Palaeogene age (starting ~ 88 Ma) in western Thailand and central Myanmar, and 3) amphibolite grade metamorphism between 70 and 80 Ma seen in gneissic outcrops in western and central Thailand, and 4) accretionary prism development in the Western Belt of Myanmar, until glancing collision with the NE corner of Greater India promoted ophiolite obduction, deformation and exhumation of marine sediments in the early Palaeogene. The Ranong strike-slip fault and other less well documented faults, were episodically active during the Late Cretaceous-Palaeogene time. N to NW directed subduction of the Palaeo-Pacific ocean below Southern China, Vietnam and Borneo created a major magmatic arc, associated with rift basins, metamorphic core complexes and strike-slip deformation which continued into the Late Cretaceous. The origin and timing of termination of subduction has recently been explained by collision of a large Luconia continental fragment either during the Late Cretaceous or Palaeogene. Evidence for such a collision is absent from the South China Sea well and seismic reflection record and here collision is discounted. Instead relocation of the subducting margin further west, possibly in response of back-arc extension (which created the Proto

Post Cretaceous cooling trend documented in the gastropods (Turritella Sp.) from the Cenozoic startigraphic successions of India

NASA Astrophysics Data System (ADS)

Banerjee, Y.; Ghosh, P.; Halder, K.; Malarkodi, N.; Pathak, P.

2017-12-01

The aftermath of the Himalyan orogeny and subsequent cooling is documented in the deep sea sedimentary record from the Oceanic realm (1). Here we attempt to reconstruct the temperature pattern based on marine gastropods i.e. Turritella sp. which became abundant during the post Cretaceous period and have successfully been used for the reconstruction of climate by measuring the stable isotopic composition (2,3,4). Well preserved specimens of Cretaceous Turritella from the Rajamundry Infratrappean beds and those from the Miocene, Holocene succession of Kutch, western India were analysed along with specimen from the modern time scale (also from Kutch). The Cretaceous, early to mid Miocene, early Holocene and modern shells recorded δ13C variability from 0.36 to 4.94‰, -1.83 to -4.83‰, -3.26 to 0.40‰, -1.47 to -4.70‰ respectively suggesting drop in the productivity during mid Miocene and subsequent period of rapid growth. The Variability in terms of δ18O ranges from -2.28 to -4.99‰, -2.66 to -7.06‰, -2.86 to 0.96‰, -1.05 to -3.23‰ for the Cretaceous, early to mid Miocene, early Holocene and modern shells respectively. Corbula sp. collected from the same strata with that of the early to mid Holocene Turritella showed a similar δ13C and δ18O values denoting similar environmental condition during deposition. Absence of any significant correlation between δ13C vs δ18O support equilibrium precipitation of shell growth bands. We used Epstein oxygen isotope thermometry to derive temperature from the oxygen isotope of carbonate and adopted water isotopic composition (1‰ for the Cretaceous and -0.7‰ for the Miocene) from the literature. Our observation captured an overall cooling trend from the Cretaceous to the Holocene time period (especially in between mid Miocene to Holocene) and a subsequent warming trend in modern time. Validation with other thermometry method will be displayed at the time of presentation. References: [1] Zachos et al., 2001

Highly specialized mammalian skulls from the Late Cretaceous of South America.

PubMed

Rougier, Guillermo W; Apesteguía, Sebastián; Gaetano, Leandro C

2011-11-02

Dryolestoids are an extinct mammalian group belonging to the lineage leading to modern marsupials and placentals. Dryolestoids are known by teeth and jaws from the Jurassic period of North America and Europe, but they thrived in South America up to the end of the Mesozoic era and survived to the beginnings of the Cenozoic. Isolated teeth and jaws from the latest Cretaceous of South America provide mounting evidence that, at least in western Gondwana, dryolestoids developed into strongly endemic groups by the Late Cretaceous. However, the lack of pre-Late Cretaceous dryolestoid remains made study of their origin and early diversification intractable. Here we describe the first mammalian remains from the early Late Cretaceous of South America, including two partial skulls and jaws of a derived dryolestoid showing dental and cranial features unknown among any other group of Mesozoic mammals, such as single-rooted molars preceded by double-rooted premolars, combined with a very long muzzle, exceedingly long canines and evidence of highly specialized masticatory musculature. On one hand, the new mammal shares derived features of dryolestoids with forms from the Jurassic of Laurasia, whereas on the other hand, it is very specialized and highlights the endemic, diverse dryolestoid fauna from the Cretaceous of South America. Our specimens include only the second mammalian skull known for the Cretaceous of Gondwana, bridging a previous 60-million-year gap in the fossil record, and document the whole cranial morphology of a dryolestoid, revealing an unsuspected morphological and ecological diversity for non-tribosphenic mammals.

A new lineage of Cretaceous jewel wasps (Chalcidoidea: Diversinitidae).

PubMed

Haas, Michael; Burks, Roger A; Krogmann, Lars

2018-01-01

Jewel wasps (Hymenoptera: Chalcidoidea) are extremely species-rich today, but have a sparse fossil record from the Cretaceous, the period of their early diversification. Three genera and three species, Diversinitus attenboroughi gen. & sp. n. , Burminata caputaeria gen. & sp. n. and Glabiala barbata gen. & sp. n. are described in the family Diversinitidae fam. n., from Lower Cretaceous Burmese amber. Placement in Chalcidoidea is supported by the presence of multiporous plate sensilla on the antennal flagellum and a laterally exposed prepectus. The new taxa can be excluded from all extant family level chalcidoid lineages by the presence of multiporous plate sensilla on the first flagellomere in both sexes and lack of any synapomorphies. Accordingly, a new family is proposed for the fossils and its probable phylogenetic position within Chalcidoidea is discussed. Morphological cladistic analyses of the new fossils within the Heraty et al. (2013) dataset did not resolve the phylogenetic placement of Diversinitidae, but indicated its monophyly. Phylogenetically relevant morphological characters of the new fossils are discussed with reference to Cretaceous and extant chalcidoid taxa. Along with mymarid fossils and a few species of uncertain phylogenetic placement, the newly described members of Diversinitidae are among the earliest known chalcidoids and advance our knowledge of their Cretaceous diversity.

A Flexible Platform Containing Graphene Mesoporous Structure and Carbon Nanotube for Hydrogen Evolution

PubMed Central

Zhang, Rujing; Li, Xiao; Zhang, Li; Lin, Shuyuan

2016-01-01

It is of great significance to design a platform with large surface area and high electrical conductivity for poorly conductive catalyst for hydrogen evolution reaction (HER), such as molybdenum sulfide (MoSx), a promising and cost‐effective nonprecious material. Here, the design and preparation of a free‐standing and tunable graphene mesoporous structure/single‐walled carbon nanotube (GMS/SWCNT) hybrid membrane is reported. Amorphous MoSx is electrodeposited on this platform through a wet chemical process under mild temperature. For MoSx@GMS/SWCNT hybrid electrode with a low catalyst loading of 32 μg cm−2, the onset potential is near 113 mV versus reversible hydrogen electrode (RHE) and a high current density of ≈71 mA cm−2 is achieved at 250 mV versus RHE. The excellent HER performance can be attributed to the large surface area for MoSx deposition, as well as the efficient electron transport and abundant active sites on the amorphous MoSx surface. This novel catalyst is found to outperform most previously reported MoSx‐based HER catalysts. Moreover, the flexibility of the electrode facilitates its stable catalytic performance even in extremely distorted states. PMID:27980998

Astronomically Forced Hydrology of the Late Cretaceous Sub-tropical Potosí Basin, Bolivia

NASA Astrophysics Data System (ADS)

Tasistro-Hart, A.; Maloof, A. C.; Schoene, B.; Eddy, M. P.

2017-12-01

Orbital forcings paced the ice ages of the Pleistocene, demonstrating that periodic variations in the latitudinal distribution of insolation amplified by ice-albedo feedbacks can guide global climate. How these forcings operate in the hot-houses that span most of the planet's history, however, is unknown. The lacustrine El Molino formation of the late Cretaceous-early Paleogene Potosí Basin in present-day Bolivia contains carbonate-mud parasequences that record fluctuating hydrological conditions from 73 to 63 Ma. This study presents the first cyclostratigraphic analysis using high-resolution drone-derived imagery and 3D elevation models, combined with conventional stratigraphic measurements and magnetic susceptibility data. The drone-derived data are integrated over the entire outcrop at two field areas using a novel application of stratigraphic potential field modeling that increases signal-to-noise ratios prior to spectral analysis. We demonstrate that these parasequences exhibit significant periodicities consistent with eccentricity (400 and 100 kyr), obliquity (50 kyr, 40 kyr, and 29 kyr), precession (17-23 kyr), and semi-precession (9-11 kyr). New U-Pb ID-TIMS zircon ages from intercalacted ash beds corroborate the interpreted sedimentation rates at two sites, indicating that the Potosí Basin contains evidence for hot-house astronomical forcing of sub-tropical lacustrine hydrology. Global climate simulations of late Cretaceous orbital end-member configurations demonstrate precessional-eccentricity and obliquity driven modulation of basin hydrology. In model simulations, the forcings drive long-term shifts in the location of the intertropical convergence zone, changing precipitation along the northern extent of the Potosí Basin's catchment area. This study is the first to demonstrate orbital forcing of a lacustrine system during the Maastrichtian and could ultimately contribute to a precise age for the Cretaceous-Paleogene boundary.

Constraining the rate of oceanic deoxygenation leading up to a Cretaceous Oceanic Anoxic Event (OAE-2: ~94 Ma)

PubMed Central

Ostrander, Chadlin M.; Owens, Jeremy D.; Nielsen, Sune G.

2017-01-01

The rates of marine deoxygenation leading to Cretaceous Oceanic Anoxic Events are poorly recognized and constrained. If increases in primary productivity are the primary driver of these episodes, progressive oxygen loss from global waters should predate enhanced carbon burial in underlying sediments—the diagnostic Oceanic Anoxic Event relic. Thallium isotope analysis of organic-rich black shales from Demerara Rise across Oceanic Anoxic Event 2 reveals evidence of expanded sediment-water interface deoxygenation ~43 ± 11 thousand years before the globally recognized carbon cycle perturbation. This evidence for rapid oxygen loss leading to an extreme ancient climatic event has timely implications for the modern ocean, which is already experiencing large-scale deoxygenation. PMID:28808684

Macrofossil extinction patterns at Bay of Biscay Cretaceous-Tertiary boundary sections

NASA Technical Reports Server (NTRS)

Ward, Peter D.; Macleod, Kenneth

1988-01-01

Researchers examined several K-T boundary cores at Deep Sea Drilling Project (DSDP) core repositories to document biostratigraphic ranges of inoceramid shell fragments and prisms. As in land-based sections, prisms in the deep sea cores disappear well before the K-T boundary. Ammonites show a very different extinction pattern than do the inoceramids. A minimum of seven ammonite species have been collected from the last meter of Cretaceous strata in the Bay of Biscay basin. In three of the sections there is no marked drop in either species numbers or abundance prior to the K-T boundary Cretaceous strata; at the Zumaya section, however, both species richness and abundance drop in the last 20 m of the Cretaceous, with only a single ammonite specimen recovered to date from the uppermost 12 m of Cretaceous strata in this section. Researchers conclude that inoceramid bivalves and ammonites showed two different times and patterns of extinction, at least in the Bay of Biscay region. The inoceramids disappeared gradually during the Early Maestrichtian, and survived only into the earliest Late Maestrichtian. Ammonites, on the other hand, maintained relatively high species richness throughout the Maestrichtian, and then disappeared suddenly, either coincident with, or immediately before the microfossil extinction event marking the very end of the Cretaceous.

SU-C-BRC-06: OpenCL-Based Cross-Platform Monte Carlo Simulation Package for Carbon Ion Therapy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Qin, N; Tian, Z; Pompos, A

2016-06-15

Purpose: Monte Carlo (MC) simulation is considered to be the most accurate method for calculation of absorbed dose and fundamental physical quantities related to biological effects in carbon ion therapy. Its long computation time impedes clinical and research applications. We have developed an MC package, goCMC, on parallel processing platforms, aiming at achieving accurate and efficient simulations for carbon therapy. Methods: goCMC was developed under OpenCL framework. It supported transport simulation in voxelized geometry with kinetic energy up to 450 MeV/u. Class II condensed history algorithm was employed for charged particle transport with stopping power computed via Bethe-Bloch equation. Secondarymore » electrons were not transported with their energy locally deposited. Energy straggling and multiple scattering were modeled. Production of secondary charged particles from nuclear interactions was implemented based on cross section and yield data from Geant4. They were transported via the condensed history scheme. goCMC supported scoring various quantities of interest e.g. physical dose, particle fluence, spectrum, linear energy transfer, and positron emitting nuclei. Results: goCMC has been benchmarked against Geant4 with different phantoms and beam energies. For 100 MeV/u, 250 MeV/u and 400 MeV/u beams impinging to a water phantom, range difference was 0.03 mm, 0.20 mm and 0.53 mm, and mean dose difference was 0.47%, 0.72% and 0.79%, respectively. goCMC can run on various computing devices. Depending on the beam energy and voxel size, it took 20∼100 seconds to simulate 10{sup 7} carbons on an AMD Radeon GPU card. The corresponding CPU time for Geant4 with the same setup was 60∼100 hours. Conclusion: We have developed an OpenCL-based cross-platform carbon MC simulation package, goCMC. Its accuracy, efficiency and portability make goCMC attractive for research and clinical applications in carbon therapy.« less

Potential cretaceous play in the Rharb basin of northern Morocco

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jobidon, G.P.

1993-09-01

The autochthonous Cretaceous in the Rharb basin of northern Morocco is located underneath a cover of neogene sediments and of the Prerif nappe olistostrome, which was emplaced during the Tortonian 7 m.y. The presence of infranappe Cretaceous sediments is documented in a few onshore wells in the Rharb basin and in the adjacent Prerif Rides area, as well as in the Rif Mountains. Their presence in the deeper portion of the Rharb basin is difficult to detail because of poor seismic resolution data beneath dispersive prerif nappe. A recent study of offshore seismic data acquired by PCIAC in 1987 indicatesmore » that the infranappe interval can be more than 1500 m thick in some of the offshore Kenitra area. These sediments have seismic signatures that would correspond to Middle Cretaceous transgressions, culminating with a Turonian highstand. Their deposition systems were located on the northern and western flanks of the Meseta and were followed by a hiatus lasting until the Miocene. Regional studies of gravity and magnetic data provide and additional understanding of the Rif province, its evolution, and the possible presence of autochthonous Cretaceous sediments below the prerif nappe cover. The infranappe of Rharb basin has a good potential to develop into a major hydrocarbon play with the presence of middle Cretaceous reservoir rocks, Turonian-Cenomanian black shale source rocks, as well as the timely combination of trap formation, source rock maturation, and hydrocarbon migration.« less

Sedimentary features of the Blackhawk formation (Cretaceous) at Sunnyside, Carbon County, Utah

USGS Publications Warehouse

Maberry, John O.

1968-01-01

The Blackhawk Formation at Sunnyside, Utah, was deposited along the western margin of the Western Interior Cretaceous sea during southeastward withdrawal of the sea. Sand was the dominant type of land-derived sediment deposited in the Sunnyside district during the regressive phases. Sand bodies prograded seaward in response to changing sediment supply from a source west of Sunnyside. Where conditions were favorable for the accumulation of vegetable material, peat deposits formed and were later changed to bituminous Coal by diagenesis. Studies of the coal bed show that the coals were formed from accumulation of small, low-growing plants and plant debris that was transported into the area of accumulation. Remains of large plants in the coals are rare. Trace fossils, which are tracks, trails and burrows formed by organisms and preserved in the rock, are extremely abundant in the Blackhawk rocks. These biogenic sedimentary structures are common in Cretaceous deposits throughout the western United States. Trace fossil distribution in the rocks is controlled by the depositional environment preferred by their creators. A study of the trace fossils of a. locality allows a more precise determination of the conditions during deposition of the sediments. Water depth, bottom conditions, salinity, current velocity and amount of suspended nutrients in the water are some of the environmental factors that may be reconstructed by studying trace fossils. The Blackhawk Formation at Sunnyside comprises the members, the Kenilworth Member and the Sunnyside Member. Field studies show that the formation may be further subdivided in the Sunnyside district., according to the precepts of units of mappable thickness and similar lithologic characteristics. The Blackhawk pinches out eastward and north. ward into the Mancos Shale, and names for submembers become meaningless. Names are of value in the region of interest, however, because of the prominence of the named units. Coal mining is the

Multiscale fracture network characterization and impact on flow: A case study on the Latemar carbonate platform

NASA Astrophysics Data System (ADS)

Hardebol, N. J.; Maier, C.; Nick, H.; Geiger, S.; Bertotti, G.; Boro, H.

2015-12-01

A fracture network arrangement is quantified across an isolated carbonate platform from outcrop and aerial imagery to address its impact on fluid flow. The network is described in terms of fracture density, orientation, and length distribution parameters. Of particular interest is the role of fracture cross connections and abutments on the effective permeability. Hence, the flow simulations explicitly account for network topology by adopting Discrete-Fracture-and-Matrix description. The interior of the Latemar carbonate platform (Dolomites, Italy) is taken as outcrop analogue for subsurface reservoirs of isolated carbonate build-ups that exhibit a fracture-dominated permeability. New is our dual strategy to describe the fracture network both as deterministic- and stochastic-based inputs for flow simulations. The fracture geometries are captured explicitly and form a multiscale data set by integration of interpretations from outcrops, airborne imagery, and lidar. The deterministic network descriptions form the basis for descriptive rules that are diagnostic of the complex natural fracture arrangement. The fracture networks exhibit a variable degree of multitier hierarchies with smaller-sized fractures abutting against larger fractures under both right and oblique angles. The influence of network topology on connectivity is quantified using Discrete-Fracture-Single phase fluid flow simulations. The simulation results show that the effective permeability for the fracture and matrix ensemble can be 50 to 400 times higher than the matrix permeability of 1.0 · 10-14 m2. The permeability enhancement is strongly controlled by the connectivity of the fracture network. Therefore, the degree of intersecting and abutting fractures should be captured from outcrops with accuracy to be of value as analogue.

Tyrant dinosaur evolution tracks the rise and fall of Late Cretaceous oceans.

PubMed

Loewen, Mark A; Irmis, Randall B; Sertich, Joseph J W; Currie, Philip J; Sampson, Scott D

2013-01-01

The Late Cretaceous (∼95-66 million years ago) western North American landmass of Laramidia displayed heightened non-marine vertebrate diversity and intracontinental regionalism relative to other latest Cretaceous Laurasian ecosystems. Processes generating these patterns during this interval remain poorly understood despite their presumed role in the diversification of many clades. Tyrannosauridae, a clade of large-bodied theropod dinosaurs restricted to the Late Cretaceous of Laramidia and Asia, represents an ideal group for investigating Laramidian patterns of evolution. We use new tyrannosaurid discoveries from Utah--including a new taxon which represents the geologically oldest member of the clade--to investigate the evolution and biogeography of Tyrannosauridae. These data suggest a Laramidian origin for Tyrannosauridae, and implicate sea-level related controls in the isolation, diversification, and dispersal of this and many other Late Cretaceous vertebrate clades.

One hundred million year old ergot: psychotropic compounds in the Cretaceous?

USDA-ARS?s Scientific Manuscript database

A fungal sclerotium similar to sclerotia of the genus Claviceps, commonly known as ergot, was found infecting a grass kernel in Early Cretaceous Myanmar amber. This represents the first fossil record of ergot dating as far back as the Cretaceous period. The fungus, described as Palaeoclaviceps para...

The Cretaceous/Tertiary Extinction Controversy Reconsidered.

ERIC Educational Resources Information Center

McCartney, Kevin; Nienstedt, Jeffrey

1986-01-01

Reviews varying positions taken in the Cretaceous/Tertiary (K/Y) extinction controversy. Analyzes and contests the meteoritic impact theory known as the Alvarez Model. Presents an alternative working hypothesis explaining the K/T transition. (ML)

Highly-sensitive electrochemical sensing platforms for food colourants based on the property-tuning of porous carbon.

PubMed

Cheng, Qin; Xia, Shanhong; Tong, Jianhua; Wu, Kangbing

2015-08-05

It is very challenging to develop highly-sensitive analytical platforms for toxic synthetic colourants that widely added in food samples. Herein, a series of porous carbon (PC) was prepared using CaCO3 nanoparticles (nano-CaCO3) as the hard template and starch as the carbon precursor. Characterizations of scanning electron microscopy and transmission electron microscopy indicated that the morphology and porous structure were controlled by the weight ratio of starch and nano-CaCO3. The electrochemical behaviours of four kinds of widely-used food colourants, Sunset yellow, Tartrazine, Ponceau 4R and Allura red, were studied. On the surface of PC samples, the oxidation signals of colourants enhanced obviously, and more importantly, the signal enhancement abilities of PC were also dependent on the starch/nano-CaCO3 weight ratio. The greatly-increased electron transfer ability and accumulation efficiency were the main reason for the enhanced signals of colourants, as confirmed by electrochemical impedance spectroscopy and chronocoulometry. The prepared PC-2 sample by 1:1 starch/nano-CaCO3 weight ratio was more active for the oxidation of food colourtants, and increased the signals by 89.4-fold, 79.3-fold, 47.3-fold and 50.7-fold for Sunset yellow, Tartrazine, Ponceau 4R and Allura red. As a result, a highly-sensitive electrochemical sensing platform was developed, and the detection limits were 1.4, 3.5, 2.1 and 1.7 μg L(-1) for Sunset yellow, Tartrazine, Ponceau 4R and Allura red. The practical application of this new sensing platform was demonstrated using drink samples, and the detected results consisted with the values that obtained by high-performance liquid chromatography. Copyright © 2015 Elsevier B.V. All rights reserved.

Late Cretaceous restructuring of terrestrial communities facilitated the end-Cretaceous mass extinction in North America.

PubMed

Mitchell, Jonathan S; Roopnarine, Peter D; Angielczyk, Kenneth D

2012-11-13

The sudden environmental catastrophe in the wake of the end-Cretaceous asteroid impact had drastic effects that rippled through animal communities. To explore how these effects may have been exacerbated by prior ecological changes, we used a food-web model to simulate the effects of primary productivity disruptions, such as those predicted to result from an asteroid impact, on ten Campanian and seven Maastrichtian terrestrial localities in North America. Our analysis documents that a shift in trophic structure between Campanian and Maastrichtian communities in North America led Maastrichtian communities to experience more secondary extinction at lower levels of primary production shutdown and possess a lower collapse threshold than Campanian communities. Of particular note is the fact that changes in dinosaur richness had a negative impact on the robustness of Maastrichtian ecosystems against environmental perturbations. Therefore, earlier ecological restructuring may have exacerbated the impact and severity of the end-Cretaceous extinction, at least in North America.

Late Cretaceous restructuring of terrestrial communities facilitated the end-Cretaceous mass extinction in North America

PubMed Central

Roopnarine, Peter D.; Angielczyk, Kenneth D.

2012-01-01

The sudden environmental catastrophe in the wake of the end-Cretaceous asteroid impact had drastic effects that rippled through animal communities. To explore how these effects may have been exacerbated by prior ecological changes, we used a food-web model to simulate the effects of primary productivity disruptions, such as those predicted to result from an asteroid impact, on ten Campanian and seven Maastrichtian terrestrial localities in North America. Our analysis documents that a shift in trophic structure between Campanian and Maastrichtian communities in North America led Maastrichtian communities to experience more secondary extinction at lower levels of primary production shutdown and possess a lower collapse threshold than Campanian communities. Of particular note is the fact that changes in dinosaur richness had a negative impact on the robustness of Maastrichtian ecosystems against environmental perturbations. Therefore, earlier ecological restructuring may have exacerbated the impact and severity of the end-Cretaceous extinction, at least in North America. PMID:23112149

Sedimentology, stratigraphy, and extinctions during the Cretaceous-Paleogene transition at Bug Creek, Montana

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fastovsky, D.E.; Dott, R.H. Jr.

1986-04-01

Bug Creek Valley, the source of an unusual and controversial Cretaceous-Paleogene coincidence of mammals, dinosaurs, pollen, and iridium, exemplifies the importance of depositional process in the reconstruction of evolutionary events. Five sedimentary facies are recognized at Bug Creek: a cross-stratified sandstone, a green and purple siltstone, a lateral accretionary sandstone, a coal, and a variegated siltstone. Repeated fluvial channeling restricts the accuracy of lateral correlations, and the relationship of the fossil assemblage to the presumed Cretaceous-Paleogene boundary cannot be established. Sedimentologically, the Cretaceous-Paleogene transition is represented here by Cretaceous meandering channels that gave way initially to Paleogene swamp deposition. 13more » references, 4 figures.« less

Composition and depositional environment of concretionary strata of early Cenomanian (early Late Cretaceous) age, Johnson County, Wyoming

USGS Publications Warehouse

Merewether, E.A.; Gautier, Donald L.

2000-01-01

Unusual, concretion-bearing mudrocks of early Late Cretaceous age, which were deposited in an early Cenomanian epeiric sea, have been recognized at outcrops in eastern Wyoming and in adjoining areas of Montana, South Dakota, Nebraska, and Colorado. In Johnson County, Wyo., on the western flank of the Powder River Basin, these strata are in the lower part of the Belle Fourche Member of the Frontier Formation. At a core hole in south-central Johnson County, they are informally named Unit 2. These strata are about 34 m (110 ft) thick and consist mainly of medium- to dark-gray, noncalcareous, silty shale and clayey or sandy siltstone; and light-gray to grayish-red bentonite. The shale and siltstone are either bioturbated or interlaminated; the laminae are discontinuous, parallel, and even or wavy. Several ichnogenera of deposit feeders are common in the unit but filter feeders are sparse. The unit also contains marine and continental palynomorphs and, near the top, a few arenaceous foraminifers. No invertebrate macrofossils have been found in these rocks. Unit 2 conformably overlies lower Cenomanian shale in the lowermost Belle Fourche Member, informally named Unit 3, and is conformably overlain by lower and middle Cenomanian shale, siltstone, and sandstone within the member, which are informally named Unit 1. The mineral and chemical composition of the three Cenomanian units is comparable and similar to that of shale and siltstone in the Upper Cretaceous Pierre Shale, except that these units contain more SiO2 and less CaO, carbonate carbon, and manganese. Silica is generally more abundant and CaO is generally less abundant in river water than in seawater. The composition of Unit 2 contrasts significantly with that of the underlying and overlying units. Unit 2 contains no pyrite and dolomite and much less sulfur than Units 1 and 3. Sulfate is generally less abundant in river water than in seawater. Unit 2 also includes sideritic and calcitic concretions, whereas Units

Cambrian–Ordovician of the central Appalachians:Correlations and event stratigraphy of carbonate platform andadjacent deep-water deposits

USGS Publications Warehouse

Brezinski, David K.; Taylor, John F.; Repetski, John E.; Loch, James D.

2015-01-01

deposited within the Pennsylvania and Maryland portion of the Great American Carbonate Bank. From the Early Cambrian (Dyeran) through Late Ordovician (Turinan), the Laurentian paleocontinent was rimmed by an extensive carbonate platform. During this protracted period of time, a succession of carbonate rock, more than two miles thick, was deposited in Maryland and Pennsylvania. These strata are now exposed in the Nittany arch of central Pennsylvania; the Great Valley of Pennsylvania, Maryland, and Virginia; and the Conestoga and Frederick Valleys of eastern Pennsylvania and Maryland. This fi eld trip will visit key outcrops that illustrate the varied depositional styles and environmental settings that prevailed at different times within the Pennsylvania reentrant portion of the Great American Carbonate Bank. In particular, we will contrast the timing and pattern of sedimentation in off-shelf (Frederick Valley), outer-shelf (Great Valley), and inner-shelf (Nittany arch) deposits. The deposition was controlled primarily by eustasy through the Cambrian and Early Ordovician (within the Sauk megasequence), but was strongly infl uenced later by the onset of Taconic orogenesis during deposition of the Tippecanoe megasequence.

Magnetic porous carbon nanocomposites derived from metal-organic frameworks as a sensing platform for DNA fluorescent detection.

PubMed

Tan, Hongliang; Tang, Gonge; Wang, Zhixiong; Li, Qian; Gao, Jie; Wu, Shimeng

2016-10-12

Metal-organic frameworks (MOFs) have emerged as very fascinating functional materials due to their tunable nature and diverse applications. In this work, we prepared a magnetic porous carbon (MPC) nanocomposite by employing iron-containing MOFs (MIL-88A) as precursors through a one-pot thermolysis method. It was found that the MPC can absorb selectively single-stranded DNA (ssDNA) probe to form MPC/ssDNA complex and subsequently quench the labelled fluorescent dye of the ssDNA probe, which is resulted from the synergetic effect of magnetic nanoparticles and carbon matrix. Upon the addition of complementary target DNA, however, the absorbed ssDNA probe could be released from MPC surface by forming double-stranded DNA with target DNA, and accompanied by the recovery of the fluorescence of ssDNA probe. Based on these findings, a sensing platform with low background signal for DNA fluorescent detection was developed. The proposed sensing platform exhibits high sensitivity with detection limit of 1 nM and excellent selectivity to specific target DNA, even single-base mismatched nucleotide can be distinguished. We envision that the presented study would provide a new perspective on the potential applications of MOF-derived nanocomposites in biomedical fields. Copyright © 2016 Elsevier B.V. All rights reserved.

Geochronologic evidence for Late Cretaceous and Miocene tectonism in northern New England

NASA Astrophysics Data System (ADS)

Amidon, W. H.; Barr, M.; Walcott, C.; Kylander-Clark, A. R.

2017-12-01

The persistence of mountainous relief in the northeastern U.S. suggests post-rift tectonic rejuvenation has occurred, although specific mechanisms and timing have been difficult to identify. Here we present direct evidence for significant tectonism in New Hampshire and Vermont during the Late-Cretaceous ( 85-65 Ma) and Miocene periods ( 20-5 Ma). Low temperature thermochronology from a drill core in the White Mountains of New Hampshire suggests 2-3 km of accelerated exhumation during the Late Cretaceous. This exhumation is synchronous with compressional thrusting and rapid exhumation on many other Atlantic margins and also with a change in spreading direction in the Atlantic from 85-65 Ma. Recently obtained U-Pb ages of vein calcite from faults and fractures in the Champlain Valley of New York and Vermont suggest significant brittle fracturing occurred during the Late Cretaceous and also during the Miocene. Although many questions remain, this evidence points to tectonic rejuvenation by lateral tectonic stresses in the latest Cretaceous and possibly in the Miocene. The Late Cretaceous seems to have been a particularly significant tectonic episode in northern New England and elsewhere in the circum-Atlantic region.

A primitive therizinosauroid dinosaur from the Early Cretaceous of Utah

USGS Publications Warehouse

Kirkland, J.I.; Zanno, L.E.; Sampson, S.D.; Clark, J.M.; DeBlieux, D.D.

2005-01-01

Therizinosauroids are an enigmatic group of dinosaurs known mostly from the Cretaceous period of Asia, whose derived members are characterized by elongate necks, laterally expanded pelves, small, leaf-shaped teeth, edentulous rostra and mandibular symphyses that probably bore keratinized beaks. Although more than a dozen therizinosauroid taxa are known, their relationships within Dinosauria have remained controversial because of fragmentary remains and an unusual suite of characters. The recently discovered 'feathered' therizinosauroid Beipiaosaurus from the Early Cretaceous of China helped to clarify the theropod affinities of the group. However, Beipiaosaurus is also poorly represented. Here we describe a new, primitive therizinosauroid from an extensive paucispecific bonebed at the base of the Cedar Mountain Formation (Early Cretaceous) of east-central Utah. This new taxon represents the most complete and most basal therizinosauroid yet discovered. Phylogenetic analysis of coelurosaurian theropods incorporating this taxon places it at the base of the clade Therizinosauroiden, indicating that this species documents the earliest known stage in the poorly understood transition from carnivory to herbivory within Therizinosauroidea. The taxon provides the first documentation, to our knowledge, of therizinosauroids in North America during the Early Cretaceous.

Selectivity of end-Cretaceous marine bivalve extinctions

NASA Technical Reports Server (NTRS)

Jablonski, D.; Raup, D. M.

1995-01-01

Analyses of the end-Cretaceous or Cretaceous-Tertiary mass extinction show no selectivity of marine bivalve genera by life position (burrowing versus exposed), body size, bathymetric position on the continental shelf, or relative breadth of bathymetric range. Deposit-feeders as a group have significantly lower extinction intensities than suspension-feeders, but this pattern is due entirely to low extinction in two groups (Nuculoida and Lucinoidea), which suggests that survivorship was not simply linked to feeding mode. Geographically widespread genera have significantly lower extinction intensities than narrowly distributed genera. These results corroborate earlier work suggesting that some biotic factors that enhance survivorship during times of lesser extinction intensities are ineffectual during mass extinctions.

The origin of oil in the Cretaceous succession from the South Pars Oil Layer of the Persian Gulf

NASA Astrophysics Data System (ADS)

Rahmani, Omeid; Aali, Jafar; Junin, Radzuan; Mohseni, Hassan; Padmanabhan, Eswaran; Azdarpour, Amin; Zarza, Sahar; Moayyed, Mohsen; Ghazanfari, Parviz

2013-07-01

The origin of the oil in Barremian-Hauterivian and Albian age source rock samples from two oil wells (SPO-2 and SPO-3) in the South Pars oil field has been investigated by analyzing the quantity of total organic carbon (TOC) and thermal maturity of organic matter (OM). The source rocks were found in the interval 1,000-1,044 m for the Kazhdumi Formation (Albian) and 1,157-1,230 m for the Gadvan Formation (Barremian-Hauterivian). Elemental analysis was carried out on 36 samples from the source rock candidates (Gadvan and Kazhdumi formations) of the Cretaceous succession of the South Pars Oil Layer (SPOL). This analysis indicated that the OM of the Barremian-Hauterivian and Albian samples in the SPOL was composed of kerogen Types II and II-III, respectively. The average TOC of analyzed samples is less than 1 wt%, suggesting that the Cretaceous source rocks are poor hydrocarbon (HC) producers. Thermal maturity and Ro values revealed that more than 90 % of oil samples are immature. The source of the analyzed samples taken from Gadvan and Kazhdumi formations most likely contained a content high in mixed plant and marine algal OM deposited under oxic to suboxic bottom water conditions. The Pristane/nC17 versus Phytane/nC18 diagram showed Type II-III kerogen of mixture environments for source rock samples from the SPOL. Burial history modeling indicates that at the end of the Cretaceous time, pre-Permian sediments remained immature in the Qatar Arch. Therefore, lateral migration of HC from the nearby Cretaceous source rock kitchens toward the north and south of the Qatar Arch is the most probable origin for the significant oils in the SPOL.

Tyrant Dinosaur Evolution Tracks the Rise and Fall of Late Cretaceous Oceans

PubMed Central

Loewen, Mark A.; Irmis, Randall B.; Sertich, Joseph J. W.; Currie, Philip J.; Sampson, Scott D.

2013-01-01

The Late Cretaceous (∼95–66 million years ago) western North American landmass of Laramidia displayed heightened non-marine vertebrate diversity and intracontinental regionalism relative to other latest Cretaceous Laurasian ecosystems. Processes generating these patterns during this interval remain poorly understood despite their presumed role in the diversification of many clades. Tyrannosauridae, a clade of large-bodied theropod dinosaurs restricted to the Late Cretaceous of Laramidia and Asia, represents an ideal group for investigating Laramidian patterns of evolution. We use new tyrannosaurid discoveries from Utah—including a new taxon which represents the geologically oldest member of the clade—to investigate the evolution and biogeography of Tyrannosauridae. These data suggest a Laramidian origin for Tyrannosauridae, and implicate sea-level related controls in the isolation, diversification, and dispersal of this and many other Late Cretaceous vertebrate clades. PMID:24223179

Neovenatorid theropods are apex predators in the Late Cretaceous of North America.

PubMed

Zanno, Lindsay E; Makovicky, Peter J

2013-01-01

Allosauroid theropods were a diverse and widespread radiation of Jurassic-Cretaceous megapredators. Achieving some of the largest body sizes among theropod dinosaurs, these colossal hunters dominated terrestrial ecosystems until a faunal turnover redefined apex predator guild occupancy during the final 20 million years of the Cretaceous. Here we describe a giant new species of allosauroid--Siats meekerorum gen. et sp. nov.--providing the first evidence for the cosmopolitan clade Neovenatoridae in North America. Siats is the youngest allosauroid yet discovered from the continent and demonstrates that the clade endured there into the Late Cretaceous. The discovery provides new evidence for ecologic sympatry of large allosauroids and small-bodied tyrannosauroids. These data support the hypothesis that extinction of Allosauroidea in terrestrial ecosystems of North America permitted ecological release of tyrannosauroids, which went on to dominate end-Cretaceous food webs.

Early Cretaceous greenhouse pumped higher taxa diversification in spiders.

PubMed

Shao, Lili; Li, Shuqiang

2018-05-24

The Cretaceous experienced one of the most remarkable greenhouse periods in geological history. During this time, ecosystem reorganizations significantly impacted the diversification of many groups of organisms. The rise of angiosperms marked a major biome turnover. Notwithstanding, relatively little remains known about how the Cretaceous global ecosystem impacted the evolution of spiders, which constitute one of the most abundant groups of predators. Herein, we evaluate the transcriptomes of 91 taxa representing more than half of the spider families. We add 23 newly sequenced taxa to the existing database to obtain a robust phylogenomic assessment. Phylogenetic reconstructions using different datasets and methods obtain novel placements of some groups, especially in the Synspermiata and the group having a retrolateral tibial apophysis (RTA). Molecular analyses indicate an expansion of the RTA clade at the Early Cretaceous with a hunting predatory strategy shift. Fossil analyses show a 7-fold increase of diversification rate at the same period, but this likely owes to the first occurrences spider in amber deposits. Additional analyses of fossil abundance show an accumulation of spider lineages in the Early Cretaceous. We speculate that the establishment of a warm greenhouse climate pumped the diversification of spiders, in particular among webless forms tracking the abundance of insect prey. Our study offers a new pathway for future investigations of spider phylogeny and diversification. Copyright © 2018. Published by Elsevier Inc.

Late Cretaceous - Paleogene forearc sedimentation and accretion of oceanic plateaus and seamounts along the Middle American convergent margin (Costa Rica)

NASA Astrophysics Data System (ADS)

Baumgartner, Peter O.; Baumgartner-Mora, Claudia; Andjic, Goran

2016-04-01

The Late Cretaceous-Paleogene sedimentation pattern in space and time along the Middle American convergent margin was controlled by the accretion of Pacific plateaus and seamounts. The accretion of more voluminous plateaus must have caused the temporary extinction of the arc and tectonic uplift, resulting in short lived episodes of both pelagic and neritic biogenic sedimentation. By the Late Eocene, shallow carbonate environments became widespread on a supposed mature arc edifice, that is so far only documented in arc-derived sediments. In northern Costa Rica forearc sedimentation started during the Coniacian-Santonian on the Aptian-Turonian basement of the Manzanillo Terrane. The arrival and collision of the Nicoya Terrane (a CLIP-like, 139-83 Ma Pacific plateau) and the Santa Elena Terrane caused the extinction of the arc during late Campanian- Early Maastrichtian times, indicated by the change to pelagic limestone sedimentation (Piedras Blancas Formation) in deeper areas and shallow-water rudistid - Larger Benthic Foraminfera limestone on tectonically uplifted areas of all terranes. Arc-derived turbidite sedimentation resumed in the Late Maastrichtian and was again interrupted during the Late Paleocene - Early Eocene, perhaps due to the underplating of a yet unknown large seamount. The extinction of the arc resulted in the deposition of the siliceous pelagic Buenavista Formation, as well as the principally Thanetian Barra Honda carbonate platform on a deeply eroded structural high in the Tempisque area. In southern Costa Rica the basement is thought to be the western edge of the CLIP. It is Santonian-Campanian in age and is only exposed in the southwestern corner of Herradura. Cretaceous arc-forearc sequences are unknown, except for the Maastrichtian-Paleocene Golfito Terrane in southeastern Costa Rica. The distribution and age of shallow/pelagic carbonates vs. arc-derived detrital sediments is controlled by the history of accretion of Galápagos hot spot

Carbonate rocks of the Seward Peninsula, Alaska: Their correlation and paleogeographic significance

USGS Publications Warehouse

Dumoulin, Julie A.; Harris, Alta; Repetski, John E.

2014-01-01

associated calcareous metaturbidites of Ordovician age as well as shallow-water Silurian dolostones. Scattered metacarbonate rocks are chiefly Cambrian, Ordovician, Silurian, and Devonian dolostones that formed in shallow, warm-water settings with locally restricted circulation and marbles of less constrained Paleozoic age. Carbonate metaturbidites occur on the northeast and southeast coasts and yield mainly Silurian and lesser Ordovician and Devonian conodonts; the northern succession also includes debris flows with meter-scale clasts and an argillite interval with Late Ordovician graptolites and lenses of radiolarian chert. Mafic igneous rocks at least partly of Early Devonian age are common in the southern succession. Carbonate rocks on Seward Peninsula experienced a range of deformational and thermal histories equivalent to those documented in the Brooks Range. Conodont color alteration indices (CAIs) from Seward Peninsula, like those from the Brooks Range, define distinct thermal provinces that likely reflect structural burial. Penetratively deformed high-pressure metamorphic rocks of the Nome Complex (CAIs ≥5) correspond to rocks of the Schist belt in the southern Brooks Range; both record subduction during early stages of the Jurassic–Cretaceous Brooks Range orogeny. Weakly metamorphosed to unmetamorphosed strata of the York terrane (CAIs mainly 2–5), like Brooks Range rocks in the Central belt and structural allochthons to the north, experienced moderate to shallow burial during the main phase of the Brooks Range orogeny. The nature of the contact between the York terrane and the Nome Complex is uncertain; it may be a thrust fault, an extensional surface, or a thrust fault later reactivated as an extensional fault. Lithofacies and biofacies data indicate that, in spite of their divergent Mesozoic histories, rocks of the York terrane and protoliths of the Nome Complex formed as part of the same lower Paleozoic carbonate platform. Stratigraphies in both

Continental Arcs as Both Carbon Source and Sink in Regulating Long Term Climate

NASA Astrophysics Data System (ADS)

Jiang, H.; Lee, C. T.

2017-12-01

The long-term variability of atmospheric pCO2 is determined by the balance between the rate of geologic inputs of CO­­2 (e.g., magmatic/metamorphic degassing, carbonate weathering) and the rate of carbonate precipitation driven by silicate weathering. The Late Cretaceous-Early Cenozoic was characterized by elevated atmospheric pCO2 and greenhouse climate, likely due to increased magmatic flux from mid-ocean ridges and, in particular, continental arcs. However, it has been suggested that continental arc magmatism is accompanied by rapid uplift and erosion due to magmatic/tectonic thickening of the crust, thus continental arcs likely enhance the chemical weathering flux, in turn increasing the carbon sink. To assess the contribution of continental arcs to global carbon inputs and sinks, we conducted a case study in the Cretaceous Peninsular Ranges batholith (PRB) and associated forearc basin in southern California, USA, representing one segment of the Cretaceous Cordillera arc-forearc system. Arc magmatism occurred between 170-85 Ma, peaking at 100 Ma, but erosion of the arc continues into the early Eocene, with forearc sediments representing this protracted arc unroofing. During magmatism, we estimate the CO2 degassing flux from the PRB was at least 5-25*105 mol·km-2·yr-1. By calculating the depletion of Ca and Mg in the forearc sediments relative to their arc protoliths, we estimate the silicate weathering/carbonate precipitation flux to be 106 mol·km-2·yr-1 during Late Cretaceous magmatism, decreasing to 105 mol·km-2·yr-1 by the Early Eocene. We show that during active continental arc magmatism, the CO2 degassing flux is comparable to CO2 consumption driven by silicate weathering in the arc. However, after magmatism ends, a regional imbalance arises in which the arc no longer contributes to CO2 inputs but continued silicate weathering of the arc drives carbonate precipitation such that the arc indirectly becomes CO2 sink. We propose that the development of

The Sredne-Amursky basin: A migrating cretaceous depocenter for the Amur river, eastern Siberia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Light, M.; Maslanyj, M.; Davidson, K.

1993-09-01

Recently acquired seismic, well, and regional geological data imply favorable conditions for the accumulation of oil and gas in the 20,000 km[sup 2] Sredne-Amursky basin. Major graben and northeast-trending sinistral wrench-fault systems are recognized in the basin. Lower and Upper Cretaceous sediments are up to 9000 and 3000 m thick, respectively. Paleogeographic reconstructions imply that during the Late Triassic-Early Cretaceous the Sredne-Amursky basin was part of a narrow marine embayment (back-arc basin), which was open to the north. During the Cretaceous, the region was part of a foreland basin complicated by strike-slip, which produced subsidence related to transtension during obliquemore » collision of the Sikhote-Alin arc with Eurasian margin. Contemporaneous uplift also related to this collision migrated from south to north and may have sourced northward-directed deltas and alluvial fans, which fed northward into the closing back-arc basin between 130 and 85 Ma. The progradational clastic succession of the Berriasian-Albian and the Late Cretaceous fluvial, brackish water and paralic sediments within the basin may be analogous to the highly productive late Tertiary clastics of the Amur River delta in the northeast Sakhalin basin. Cretaceous-Tertiary lacustrine-deltaic sapropelic shales provide significant source and seal potential and potential reservoirs occur in the Cretaceous and Tertiary. Structural plays were developed during Cretaceous rifting and subsequent strike-slip deformation. If the full hydrocarbon potential of the Sredne-Amursky basin is to be realized, the regional appraisal suggests that exploration should be focused toward the identification of plays related to prograding Cretaceous deltaic depositional systems.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kauffman, E.G.

Throughout the Mesozoic, shallow-water carbonate ramps and platforms of the circumequatorial Tethyan Ocean were characterized by extensive development of reef ecosystems, especially during times of eustatic highstand, expansion of the Tropics, and warm equable global climates. The greatest reef development was north of the paleoequator in the Caribbean and Indo-Mediterranean provinces. These reefs and associated debris facies comprise major petroleum reservoirs, in some cases with remarkable porosity and permeability normally attributed to a combination of sedimentologic, tectonic, and diagenetic factors. The biological evolution of Mesozoic reefs also has had an important, and in some cases dominant, role in determining reservoirmore » quality. Three major biological factors are critical to mesozoic reef-associated reservoir development: (1) the replacement/competitive displacement of coral-algal dominated, highly integrated reef ecosystems by loosely packed rudistid bivalve-dominated reef ecosystems in the Barremian-Albian; (2) the evolution of dominantly aragonitic, highly porous shells among framework-building rudistids in the middle and Late Cretaceous; and (3) competitive strategies among rudistids that effectively prevented widespread biological binding of Cretaceous reefs, leading to the production of large marginal fans that comprise major carbonate reservoirs. Detailed studies of these evolutionary trends in reef/framework development and of the distribution of different groups of bioconstructors on reefs lead to predictive modeling for primary and secondary porosity development in mesozoic carbonate reservoirs. The competitive displacement of coral-algal communities by rudistids on Cretaceous reefs was so effective that, even after Maastrichtian mass extinction of rudistids and other important groups comprising Mesozoic reef/carbonate platform ecosystems, coral-algal reef-building communities did not evolve again until the late Eocene.« less

Late Cretaceous Extreme Polar Warmth recorded by Vertebrate Fossils from the High Canadian Arctic

NASA Astrophysics Data System (ADS)

Vandermark, D.; Tarduno, J. A.; Brinkman, D.

2006-12-01

A vertebrate fossil assemblage from Late Cretaceous (Coniacian-Turonian, ~92 to 86 Ma) rocks on Axel Heiberg Island in the High Canadian Arctic reflects what was once a diverse community of freshwater fishes and reptiles. Paleomagnetic data indicate a paleolatitude of ~71° N for the site; the fossils are from non-migratory fauna, so they can provide insight into Late Cretaceous polar climate. The fossil assemblage includes large (> 2.4 m long) champsosaurs (extinct crocodilelike reptiles). The presence of large champsosaurs suggests a mean annual temperature > 14 °C (and perhaps as great as 25 °C). Here we summarize findings and analyses following the discovery of the fossil-bearing strata in 1996. Examination of larger fish elements, isolated teeth and SEM studies of microstructures indicates the presence of lepisosteids, amiids and teleosts (Friedman et al., 2003) Interestingly, the only other known occurrence of amiids and lepisosteids, fossil or recent, are from intervals of extreme warmth during the Tertiary. Turtles present in the assemblage include Boreralochelys axelheibergensis, a generically indeterminate eucryptodire and a trioychid (Brinkman and Tarduno, 2005). The level of turtle diversity is also comparable to mid-latitude assemblages with a mean annual paleotemperature of at least 14 °C. A large portion of the champsosaur fossil assemblage is comprised of elements from subadults. This dominance of subadults is similar to that seen from low latitude sites. Because of the sensitivity of juveniles to ice formation, the make-up of the Arctic champsosaur population further indicates that the Late Cretaceous saw an interval of extreme warmth and low seasonality. We note the temporal coincidence of these fossils with volcanism at large igneous provinces (including high Arctic volcanism) and suggest that a pulse in volcanic carbon dioxide emissions helped cause the global warmth.

Exceptionally well-preserved Cretaceous microfossils reveal new biomineralization styles.

PubMed

Wendler, Jens E; Bown, Paul

2013-01-01

Calcareous microplankton shells form the dominant components of ancient and modern pelagic sea-floor carbonates and are widely used in palaeoenvironmental reconstructions. The efficacy of these applications, however, is dependent upon minimal geochemical alteration during diagenesis, but these modifying processes are poorly understood. Here we report on new biomineralization architectures of previously unsuspected complexity in calcareous cell-wall coverings of extinct dinoflagellates (pithonellids) from a Tanzanian microfossil-lagerstätte. These Cretaceous 'calcispheres' have previously been considered biomineralogically unremarkable but our new observations show that the true nature of these tests has been masked by recrystallization. The pristine Tanzanian fossils are formed from fibre-like crystallites and show archeopyles and exquisitely constructed opercula, demonstrating the dinoflagellate affinity of pithonellids, which has long been uncertain. The interwoven fibre-like structures provide strength and flexibility enhancing the protective function of these tests. The low-density wall fabrics may represent specific adaptation for oceanic encystment life cycles, preventing the cells from rapid sinking.

The Oligocene-Miocene stratigraphic evolution of the Majella carbonate platform (Central Apennines, Italy)

NASA Astrophysics Data System (ADS)

Brandano, Marco; Cornacchia, Irene; Raffi, Isabella; Tomassetti, Laura

2016-03-01

The stratigraphic architecture of the Bolognano Formation documents the evolution of the Majella carbonate platform in response to global and local changes that affected the Mediterranean area during the Oligocene-Miocene interval. The Bolognano Formation consists of a homoclinal ramp that developed in a warm, subtropical environment. Five different lithofacies associations have been identified: Lepidocyclina calcarenites, cherty marly limestones, bryozon calcarenites, hemipelagic marls and marly limestones, and Lithothamnion limestones. Each association corresponds to a single lithostratigraphic unit except for the Lepidocyclina calcarenites that form two distinct lithostratigraphic units (Lepidocyclina calcarenites 1 and 2). These six units reflect alternation of shallow-water carbonate production and drowning. Specifically, two of the three stages of shallow-water carbonate production regard the development of wide dune fields within the middle ramp, one stage dominated by red algae and a sea-grass carbonate factory, whereas the two drowning phases are represented by marly cherty limestones and calcareous marls. A new biostratigraphic framework for Bolognano Formation is presented, based on high-resolution analysis of calcareous nannofossil assemblages, which proved to be very useful for biostratigraphic constraints also in shallow-water settings. Using this approach, we have linked the first drowning phase, late Chattian-Aquitanian p.p. in age, to western Mediterranean volcanism and the Mi-1 event, and the second drowning phase, late Burdigalian-Serravallian in age, to the closure of the Indo-Pacific passage and the occurrence of the global Monterey event. These results permit a new deciphering, in terms of sequence stratigraphy, of the Bolognano Formation that is interpreted as a 2nd-order super-sequence that can be subdivided into 3 transgressive-regressive sequences.

Evolution of volcanically-induced palaeoenvironmental changes leading to the onset of OAE1a (early Aptian, Cretaceous)

NASA Astrophysics Data System (ADS)

Keller, Christina E.; Hochuli, Peter A.; Giorgioni, Martino; Garcia, Therese I.; Bernasconi, Stefano M.; Weissert, Helmut

2010-05-01

During the Cretaceous, several major volcanic events occurred that initiated climate warming, altered marine circulation and increased marine productivity, which in turn often resulted in the widespread black shale deposits of the Oceanic Anoxic Events (OAE). In the sediments underlying the early Aptian OAE1a black shales, a prominent negative carbon isotope excursion is recorded. Its origin had long been controversial (e.g. Arthur, 2000; Jahren et al., 2001) before recent studies attributed it to the Ontong Java volcanism (Méhay et al., 2009; Tejada et al., 2009). Therefore the negative C-isotope excursion covers the interval between the time, when volcanic activity became important enough to be recorded in the C-isotope composition of the oceans to the onset of widespread anoxic conditions (OAE1a). We chose this interval at the locality of Pusiano (N-Italy) to study the effect of a volcanically-induced increase in pCO2 on the marine palaeoenvironment and to observe the evolving palaeoenvironmental conditions that finally led to OAE1a. The Pusiano section (Maiolica Formation) was deposited at the southern continental margin of the alpine Tethys Ocean and has been bio- and magnetostratigraphically dated by Channell et al. (1995). We selected 18 samples from 12 black shale horizons for palynofacies analyses. Palynofacies assemblages consist of several types of particulate organic matter, providing information on the origin of the organic matter (terrestrial/marine) and conditions during deposition (oxic/anoxic). We then linked the palynofacies results to high-resolution inorganic and organic C-isotope values and total organic carbon content measurements. The pelagic Pusiano section consists of repeated limestone-black shale couplets, which are interpreted to be the result of changes in oxygenation of bottom waters. Towards the end of the negative C-isotope excursion we observe enhanced preservation of the fragile amorphous organic matter resulting in increased

Giant Upper Cretaceous oysters from the Gulf coast and Caribbean

USGS Publications Warehouse

Sohl, Norman F.; Kauffman, Erle G.

1964-01-01

Two unusually massive ostreid species, representing the largest and youngest Mesozoic members of their respective lineages, occur in Upper Cretaceous sediment of the gulf coast and Caribbean areas. Their characteristics and significance, as well as the morphologic terminology of ostreids in general, are discussed. Crassostrea cusseta Sohl and Kauffman n. sp. is the largest known ostreid from Mesozoic rocks of North America; it occurs sporadically in the Cusseta Sand and rarely in the Blufftown Formation of the Chattahoochee River region in Georgia and Alabama. It is especially notable in that it lacks a detectable posterior adductor muscle scar on large adult shells. C. cusseta is the terminal Cretaceous member of the C. soleniscus lineage in gulf coast sediments; the lineage continues, however, with little basic modification, throughout the Cenozoic, being represented in the Eocene by C. gigantissima (Finch) and probably, in modern times, by C. virginica (Gmelin). The C. soleniscus lineage is the first typically modern crassostreid group recognized in the Mesozoic. Arctostrea aguilerae (Böse) occurs in Late Campanian and Early Maestrichtian sediments of Alabama, Mississippi, Texas(?), Mexico, and Cuba. The mature shell of this species is larger and more massive than that of any other known arctostreid. Arctostrea is well represented throughout the Upper Jurassic and Cretaceous of Europe, but in North America, despite the great numbers and diversity of Cretaceous oysters, only A. aguilerae and the Albian form A. carinata are known. The presence of A. aquilerae in both the Caribbean and gulf coast faunas is exceptional, as the Late Cretaceous faunas of these provinces are generally distinct and originated in different faunal realms.

The late Cretaceous Arman flora of Magadan oblast, Northeastern Russia

NASA Astrophysics Data System (ADS)

Herman, A. B.; Golovneva, L. B.; Shczepetov, S. V.; Grabovsky, A. A.

2016-12-01

The Arman flora from the volcanogenic-sedimentary beds of the Arman Formation is systematically studied using materials from the Arman River basin and the Nelkandya-Khasyn interfluve (Magadan oblast, Northeastern Russia). Seventy-three species of fossil plants belonging to 49 genera are described. They consist of liverworts, horsetails, ferns, seed ferns, cycadaleans, bennettitaleans, ginkgoaleans, czekanowskialeans, conifers, gymnosperms of uncertain systematic affinity, and angiosperms. The Arman flora shows a unique combination, with relatively ancient Early Cretaceous ferns and gymnosperms occurring alongside younger Late Cretaceous plants, primarily angiosperms. The similarity of the Arman flora to the Penzhina and Kaivayam floras of northwestern Kamchatka and the Tylpegyrgynai flora of the Pekul'nei Ridge allows the Arman flora to be dated as Turonian and Coniacian (Late Cretaceous), which is corroborated by isotopic (U-Pb and 40Ar/39Ar) age determination for the plant-bearing layers.

Diatom life cycles and ecology in the Cretaceous.

PubMed

Jewson, David H; Harwood, David M

2017-06-01

The earliest known diatom fossils with well-preserved siliceous frustules are from Lower Cretaceous neritic marine deposits in Antarctica. In this study, we analyzed the cell wall structure to establish whether their cell and life cycles were similar to modern forms. At least two filamentous species (Basilicostephanus ornatus and Archepyrgus melosiroides) had girdle band structures that functioned during cell division in a similar way to present day Aulacoseira species. Also, size analyses of cell diameter indicated that the cyclic process of size decline and size restoration used to time modern diatom life cycles was present in five species from the Lower Cretaceous (B. ornatus, A. melosiroides, Gladius antiquus, Ancylopyrgus reticulatus, Kreagra forfex) as well as two species from Upper Cretaceous deposits (Trinacria anissimowii and Eunotogramma fueloepi) from the Southwest Pacific. The results indicate that the "Diatom Sex Clock" was present from an early evolutionary stage. Other ecological adaptations included changes in mantle height and coiling. Overall, the results suggest that at least some of the species in these early assemblages are on a direct ancestral line to modern forms. © 2017 Phycological Society of America.

Small Theropod Teeth from the Late Cretaceous of the San Juan Basin, Northwestern New Mexico and Their Implications for Understanding Latest Cretaceous Dinosaur Evolution

PubMed Central

Williamson, Thomas E.; Brusatte, Stephen L.

2014-01-01

Studying the evolution and biogeographic distribution of dinosaurs during the latest Cretaceous is critical for better understanding the end-Cretaceous extinction event that killed off all non-avian dinosaurs. Western North America contains among the best records of Late Cretaceous terrestrial vertebrates in the world, but is biased against small-bodied dinosaurs. Isolated teeth are the primary evidence for understanding the diversity and evolution of small-bodied theropod dinosaurs during the Late Cretaceous, but few such specimens have been well documented from outside of the northern Rockies, making it difficult to assess Late Cretaceous dinosaur diversity and biogeographic patterns. We describe small theropod teeth from the San Juan Basin of northwestern New Mexico. These specimens were collected from strata spanning Santonian – Maastrichtian. We grouped isolated theropod teeth into several morphotypes, which we assigned to higher-level theropod clades based on possession of phylogenetic synapomorphies. We then used principal components analysis and discriminant function analyses to gauge whether the San Juan Basin teeth overlap with, or are quantitatively distinct from, similar tooth morphotypes from other geographic areas. The San Juan Basin contains a diverse record of small theropods. Late Campanian assemblages differ from approximately co-eval assemblages of the northern Rockies in being less diverse with only rare representatives of troodontids and a Dromaeosaurus-like taxon. We also provide evidence that erect and recurved morphs of a Richardoestesia-like taxon represent a single heterodont species. A late Maastrichtian assemblage is dominated by a distinct troodontid. The differences between northern and southern faunas based on isolated theropod teeth provide evidence for provinciality in the late Campanian and the late Maastrichtian of North America. However, there is no indication that major components of small-bodied theropod diversity were lost

Small theropod teeth from the Late Cretaceous of the San Juan Basin, northwestern New Mexico and their implications for understanding latest Cretaceous dinosaur evolution.

PubMed

Williamson, Thomas E; Brusatte, Stephen L

2014-01-01

Studying the evolution and biogeographic distribution of dinosaurs during the latest Cretaceous is critical for better understanding the end-Cretaceous extinction event that killed off all non-avian dinosaurs. Western North America contains among the best records of Late Cretaceous terrestrial vertebrates in the world, but is biased against small-bodied dinosaurs. Isolated teeth are the primary evidence for understanding the diversity and evolution of small-bodied theropod dinosaurs during the Late Cretaceous, but few such specimens have been well documented from outside of the northern Rockies, making it difficult to assess Late Cretaceous dinosaur diversity and biogeographic patterns. We describe small theropod teeth from the San Juan Basin of northwestern New Mexico. These specimens were collected from strata spanning Santonian - Maastrichtian. We grouped isolated theropod teeth into several morphotypes, which we assigned to higher-level theropod clades based on possession of phylogenetic synapomorphies. We then used principal components analysis and discriminant function analyses to gauge whether the San Juan Basin teeth overlap with, or are quantitatively distinct from, similar tooth morphotypes from other geographic areas. The San Juan Basin contains a diverse record of small theropods. Late Campanian assemblages differ from approximately coeval assemblages of the northern Rockies in being less diverse with only rare representatives of troodontids and a Dromaeosaurus-like taxon. We also provide evidence that erect and recurved morphs of a Richardoestesia-like taxon represent a single heterodont species. A late Maastrichtian assemblage is dominated by a distinct troodontid. The differences between northern and southern faunas based on isolated theropod teeth provide evidence for provinciality in the late Campanian and the late Maastrichtian of North America. However, there is no indication that major components of small-bodied theropod diversity were lost

Isotopic composition of low-latitude paleoprecipitation during the Early Cretaceous

USGS Publications Warehouse

Suarez, M.B.; Gonzalez, Luis A.; Ludvigson, Greg A.; Vega, F.J.; Alvarado-Ortega, J.

2009-01-01

The response of the hydrologic cycle in global greenhouse conditions is important to our understanding of future climate change and to the calibration of global climate models. Past greenhouse conditions, such as those of the Cretaceous, can be used to provide empirical data with which to evaluate climate models. Recent empirical studies have utilized pedogenic carbonates to estimate the isotopic composition of meteoric waters and calculate precipitation rates for the AptianAlbian. These studies were limited to data from mid(35??N) to high (75??N) paleolatitudes, and thus future improvements in accuracy will require more estimates of meteoric water compositions from numerous localities around the globe. This study provides data for tropical latitudes (18.5??N paleolatitude) from the Tlayua Formation, Puebla, Mexico. In addition, the study confirms a shallow nearshore depositional environment for the Tlayua Formation. Petrographic observations of fenestral fabrics, gypsum crystal molds, stromatolitic structures, and pedogenic matrix birefringence fabric support the interpretation that the strata represent deposition in a tidal flat environment. Carbonate isotopic data from limestones of the Tlayua Formation provide evidence of early meteoric diagenesis in the form of meteoric calcite lines. These trends in ??18O versus ??13C were used to calculate the mean ??18O value of meteoric water, which is estimated at -5.46 ?? 0.56??? (Vienna Standard Mean Ocean Water [VSMOW]). Positive linear covariant trends in oxygen and carbon isotopic values from some horizons were used to estimate evaporative losses of vadose groundwater from tropical exposure surfaces during the Albian, and the resulting values range from 8% to 12%. However, the presence of evaporative mineral molds indicates more extensive evaporation. The added tropical data improve latitudinal coverage of paleoprecipitation ??18O estimates. The data presented here imply that earlier isotope mass balance models most

Evolution and palaeoenvironment of the Bauru Basin (Upper Cretaceous, Brazil)

NASA Astrophysics Data System (ADS)

Fernandes, Luiz Alberto; Magalhães Ribeiro, Claudia Maria

2015-08-01

The Bauru Basin was one of the great Cretaceous desert basins of the world, evolved in arid zone called Southern Hot Arid Belt. Its paleobiological record consists mainly of dinosaurs, crocodiles and turtles. The Bauru Basin is an extensive region of the South American continent that includes parts of the southeast and south of Brazil, covering an area of 370,000 km2. It is an interior continental basin that developed as a result of subsidence of the central-southern part of the South-American Platform during the Late Cretaceous (Coniacian-Maastrichtian). This sag basin is filled by a sandy siliciclastic sequence with a preserved maximum thickness of 480 m, deposited in semiarid to desert conditions. Its basement consists of volcanic rocks (mainly basalts) of the Lower Cretaceous (Hauterivian) Serra Geral basalt flows, of the Paraná-Etendeka Continental Flood Basalt Province. The sag basin was filled by an essentially siliciclastic psammitic sequence. In lithostratigraphic terms the sequence consists of the Caiuá and Bauru groups. The northern and northeastern edges of the basin provide a record of more proximal original deposits, such as associations of conglomeratic sand facies from alluvial fans, lakes, and intertwined distributary river systems. The progressive basin filling led to the burial of the basaltic substrate by extensive blanket sand sheets, associated with deposits of small dunes and small shallow lakes that retained mud (such as loess). Also in this intermediate context between the edges (more humid) and the interior (dry), wide sand sheet areas crossed by unconfined desert rivers (wadis) occurred. In the central axis of the elliptical basin a regional drainage system formed, flowing from northeast to southwest between the edges of the basin and the hot and dry inner periphery of the Caiuá desert (southwest). Life in the Bauru Basin flourished most in the areas with the greatest water availability, in which dinosaurs, crocodiles, turtles, fish

Cretaceous biostratigraphy in the Wyoming thrust belt

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nichols, D.J.; Jacobson, S.R.

Biostratigraphy is essential to exploration for oil and gas in the Wyoming thrust belt because fossils provide a temporal framework for interpretation of events of faulting, erosion, sedimentation, and the development of hydrocarbon traps and migration pathways. In the Cretaceous section, fossils are especially useful for dating and correlating repetitive facies of different ages in structurally complex terrain. The biostratigraphic zonation for the region is based on megafossils (chiefly ammonites), which permit accurate dating and correlation of outcrop sections, and which have been calibrated with the radiometric time scale for the Western Interior. Molluscan and vertebrate zone fossils are difficultmore » to obtain from the subsurface, however, and ammonities are restricted to rocks of margin origin. Palynomorphs (plant microfossils) have proven to be the most valuable fossils in investigations of stratigraphy and structures in the subsurface of the thrust belt because palynomorphs can be recovered from drill cuttings. Palynomorphs also are found in both marine and nonmarine rocks and can be used for correlation between facies. In this paper, stratigraphic ranges of selected Cretaceous marine and nonmarine palynomorphs in previously designated reference sections in Fossil Basin, Wyoming, are correlated with the occurrence of ammonities and other zone fossils in the same sections. These correlations can be related to known isotopic ages, and they contribute to the calibration of palynomorph ranges in the Cretaceous of the Western Interior.« less

Incrusting and boring bryozoans from the Dessau Chalk Formation (Cretaceous), Little Walnut Creek, Austin, Texas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Morris, P.A.

1990-09-01

Four sections were measured along a 1/4 mi length of Little Walnut Creek. The first section was 165 ft north of the US. 290 bridge while the fourth was 1/4 mi upstream. Structurally, the stream follows the fault in this section. Small faults can be found perpendicular to the primary fault and apparently account not only for minor variation in local dip (8{degrees}SE, parallel to 5{degrees}NW) but also for the placement of at least one tributary. Megainvertebrate exoskeletons were found to have been inhabited by incrusting bryozoans, boring bryozoans, and sponges. These fossils were found on both interior and exteriormore » surfaces of Exogyra laeviuscula E tigrina, and interior surfaces of Inoceramus. A low-energy environment allowed exposure of megainvertebrate exoskeletons after death but also prevented fracturing. Low siltation rates also extended exoskeleton availability after organismic death. The nonboring bryozoans are cheilostomes and at least one species, Pyripora, has been described from the Kansas Cretaceous as well as European Cretaceous sites. The boring bryozoans are primarily represented by Terebripora sp. In conclusion, this section of Dessau Chalk Formation, Upper Austin Group, was mostly a low-energy environment, shallow, limy mud platform. This substrate was probably not stable enough for bryozoan colonization as unattached colonies have not been found in sediments. Therefore, bryozoan substrates were limited to living and dead Exogyra sp. and dead Inoceramus sp. exoskeletons.« less

Plant microfossil record of the terminal Cretaceous event in the western United States and Canada

NASA Technical Reports Server (NTRS)

Nichols, D. J.; Fleming, R. F.

1988-01-01

Plant microfossils, principally pollen grains and spores produced by land plants, provide an excellent record of the terminal Cretaceous event in nonmarine environments. The record indicates regional devastation of the latest Cretaceous vegetation with the extinction of many groups, followed by a recolonization of the earliest Tertiary land surface, and development of a permanently changed land flora. The regional variations in depositional environments, plant communities, and paleoclimates provide insight into the nature and effects of the event, which were short-lived but profound. The plant microfossil data support the hypothesis that an abruptly initiated, major ecological crisis occurred at the end of the Cretaceous. Disruption of the Late Cretaceous flora ultimately contributred to the rise of modern vegetation. The plant microfossils together with geochemical and mineralogical data are consistent with an extraterrestrial impact having been the cause of the terminal Cretaceous event.

An isotopic study of biogeochemical relationships between carbonates and organic carbon in the Greenhorn Formation

NASA Technical Reports Server (NTRS)

Hayes, J. M.; Popp, Brian N.; Takigiku, Ray; Johnson, Marcus W.

1989-01-01

Carbon-isotopic compositions of total carbonate, inoceramid carbonate, micritic carbonate, secondary cements, total organic carbon, and geoporphyrins have been measured in 76 different beds within a 17-m interval of a core through the Greenhorn Formation, an interbedded limestone and calcareous shale unit of Cretaceous age from the Western Interior Seaway of North America. Results are considered in terms of variations in the processes of primary production and in secondary processes. It is shown that the porphyrin isotopic record reflects primary isotopic variations more closely than the TOC isotopic record and that, in these sediments, TOC is enriched in C-13 relative to its primary precursor by 0.6 to 2.8 percent. This enrichment is attributed to isotope effects within the consumer foodweb and is associated with respiratory heterotrophy. Variation in this secondary enrichment are correlated with variations in the isotopic composition of marine carbonate.

Composition, Age, and Origin of Cretaceous Granitic Magmatism on the Eastern Chukchi Peninsula

NASA Astrophysics Data System (ADS)

Luchitskaya, M. V.; Sokolov, S. D.; Pease, V.; Miller, E.; Belyatsky, B. V.

2018-05-01

New geochronological and isotopic geochemical data are given, which make it possible to recognize two types of granitic rocks on the eastern Chukchi Peninsula. Early Cretaceous Tkachen and Dolina granitic plutons with zircon ages (U-Pb SIMS) of 119-122 and 131-136 Ma are related to the first type. They cut through Devonian-Lower Carboniferous basement rocks and are overlain by the Aptian-Albian Etelkuyum Formation. Basal units of the latter contain fragments of granitic rocks. Late Cretaceous Provideniya and Rumilet granitic plutons, which contain zircons with ages of 94 and 85 Ma (U-Pb SIMS), respectively, belong to the second type. They cut through volcanic-sedimentary rocks of the Etelkuyum and Leurvaam formations pertaining to the Okhotsk-Chukotka Volcanic Belt. In petrographic and geochemical features, the Early Cretaceous granitic rocks of the Tkachen Pluton are commensurable with I-type granites, while Late Cretaceous granite of the Rumilet Pluton is comparable to A2-type granite. The Sr-Nd isotopic data provide evidence that from the Early Cretaceous Tkachen and Dolina plutons to the Late Cretaceous Provideniya and Rumilet plutons, the degree of crustal assimilation of suprasubduction mantle-derived melts increases up to partial melting of heterogeneous continental crust enriched in rubidium. An unconformity and various degrees of secondary alteration of volcanic-sedimentary rocks have been established in the Okhotsk-Chukotka Volcanic Belt, and this was apparently caused by transition of the tectonic setting from suprasubduction to a transform margin with local extension.

Shallow magnetic inclinations in the Cretaceous Valle Group, Baja California: remagnetization, compaction, or terrane translation?

NASA Astrophysics Data System (ADS)

Smith, Douglas P.; Busby, Cathy J.

1993-10-01

Paleomagnetic data from Albian to Turonian sedimentary rocks on Cedros Island, Mexico (28.2° N, 115.2° W) support the interpretation that Cretaceous rocks of western Baja California have moved farther northward than the 3° of latitude assignable to Neogene oblique rifting in the Gulf of California. Averaged Cretaceous paleomagnetic results from Cedros Island support 20 ± 10° of northward displacement and 14 ± 7° of clockwise rotation with respect to cratonic North America. Positive field stability tests from the Vizcaino terrane substantiate a mid-Cretaceous age for the high-temperature characteristic remanent magnetization in mid-Cretaceous strata. Therefore coincidence of characteristic magnetization directions and the expected Quaternary axial dipole direction is not due to post mid-Cretaceous remagnetization. A slump test performed on internally coherent, intrabasinal slump blocks within a paleontologically dated olistostrome demonstrates a mid-Cretaceous age of magnetization in the Valle Group. The in situ high-temperature natural remanent magnetization directions markedly diverge from the expected Quaternary axial dipole, indicating that the characteristic, high-temperature magnetization was acquired prior to intrabasinal slumping. Early acquisition of the characteristic magnetization is also supported by a regional attitude test involving three localities in coherent mid-Cretaceous Valle Group strata. Paleomagnetic inclinations in mudstone are not different from those in sandstone, indicating that burial compaction did not bias the results toward shallow inclinations in the Vizcaino terrane.

A small azhdarchoid pterosaur from the latest Cretaceous, the age of flying giants.

PubMed

Martin-Silverstone, Elizabeth; Witton, Mark P; Arbour, Victoria M; Currie, Philip J

2016-08-01

Pterosaur fossils from the Campanian-Maastrichtian of North America have been reported from the continental interior, but few have been described from the west coast. The first pterosaur from the Campanian Northumberland Formation (Nanaimo Group) of Hornby Island, British Columbia, is represented here by a humerus, dorsal vertebrae (including three fused notarial vertebrae), and other fragments. The elements have features typical of Azhdarchoidea, an identification consistent with dominance of this group in the latest Cretaceous. The new material is significant for its size and ontogenetic stage: the humerus and vertebrae indicate a wingspan of ca 1.5 m, but histological sections and bone fusions indicate the individual was approaching maturity at time of death. Pterosaurs of this size are exceedingly rare in Upper Cretaceous strata, a phenomenon commonly attributed to smaller pterosaurs becoming extinct in the Late Cretaceous as part of a reduction in pterosaur diversity and disparity. The absence of small juveniles of large species-which must have existed-in the fossil record is evidence of a preservational bias against small pterosaurs in the Late Cretaceous, and caution should be applied to any interpretation of latest Cretaceous pterosaur diversity and success.

Increased thermohaline stratification as a possible cause for an ocean anoxic event in the Cretaceous period.

PubMed

Erbacher, J; Huber, B T; Norris, R D; Markey, M

2001-01-18

Ocean anoxic events were periods of high carbon burial that led to drawdown of atmospheric carbon dioxide, lowering of bottom-water oxygen concentrations and, in many cases, significant biological extinction. Most ocean anoxic events are thought to be caused by high productivity and export of carbon from surface waters which is then preserved in organic-rich sediments, known as black shales. But the factors that triggered some of these events remain uncertain. Here we present stable isotope data from a mid-Cretaceous ocean anoxic event that occurred 112 Myr ago, and that point to increased thermohaline stratification as the probable cause. Ocean anoxic event 1b is associated with an increase in surface-water temperatures and runoff that led to decreased bottom-water formation and elevated carbon burial in the restricted basins of the western Tethys and North Atlantic. This event is in many ways similar to that which led to the more recent Plio-Pleistocene Mediterranean sapropels, but the greater geographical extent and longer duration (approximately 46 kyr) of ocean anoxic event 1b suggest that processes leading to such ocean anoxic events in the North Atlantic and western Tethys were able to act over a much larger region, and sequester far more carbon, than any of the Quaternary sapropels.

Evaluation of clumped isotope paleotemperatures across carbon isotope excursions from lacustrine strata of the Aptian Xiagou Formation, China

NASA Astrophysics Data System (ADS)

Suarez, M. B.; Gonzalez, L. A.; Ludvigson, G. A.; You, H.

2014-12-01

Carbon cycle perturbations associated with Ocean Anoxic Event 1a have been implicated in global climate and environmental changes in the Early Aptian, in particular evidence for high sea surface temperatures (SST) and carbonate platform drowning. Records of environmental changes in the terrestrial realm remain sparse. This study provides additional data on clumped isotope derived temperatures (T(Δ47)) from lacustrine carbonates of the Xiagou Formation, Gansu Province, China. In addition, Vitrinite reflectance and the Rock-Eval parameter Tmax were used to evaluate the potential for 13C-18O bonds in the carbonates to have experienced reordering. Clumped isotope derived temperatures range from 28.8 °C to 45.9°C. Vitrinite reflectance values range from 0.67 to 0.72 and Tmax ranges from 429 °C to 443 °C. The warmest temperature, derived from a very fine-grained calcareous sandstone, is at the upper limit of known modern Earth surface temperatures, and prompts concern that the T(Δ47) may be shifted to warmer temperatures as a result of burial diagenesis. Vitrinite reflectance and Tmax values indicate the samples have reached early maturity for oil generation (oil window from 60 °C to 150°C), so may have reached the lower end of temperatures for bond reordering to have occurred (~100 °C for ~100 million years). Despite this, the T(Δ47) are consistent with summer temperatures in a warm Cretaceous. In addition, temperature variations are similar to TEX86 records, especially from SST of the tropical Pacific. Two temperature increases and decreases occur, with the first peak in temperature occurring at the negative carbon isotope excursion (C3) associated with the initiation of the Selli Event (OAE1a). This study provides evidence that climate variations occurring during the Selli Event were experienced in terrestrial environments, and provides maximum summer temperatures for this part of the Asian continent during the Cretaceous. While it was intended that thermal

Carbon Electrode-Molecule Junctions: A Reliable Platform for Molecular Electronics.

PubMed

Jia, Chuancheng; Ma, Bangjun; Xin, Na; Guo, Xuefeng

2015-09-15

. At the molecular level, to form robust covalent bonds between electrodes and molecules and improve device stability, we developed a reliable system to immobilize individual molecules within a nanoscale gap of either SWCNTs or graphene through covalent amide bond formation, thus affording two classes of carbon electrode-molecule single-molecule junctions. One unique feature of these devices is the fact that they contain only one or two molecules as conductive elements, thus forming the basis for building new classes of chemo/biosensors with ultrahigh sensitivity. We have used these approaches to reveal the dependence of the charge transport of individual metallo-DNA duplexes on π-stacking integrity, and fabricate molecular devices capable of realizing label-free, real-time electrical detection of biological interactions at the single-event level, or switching their molecular conductance upon exposure to external stimuli, such as ion, pH, and light. These investigations highlight the unique advantages and importance of these universal methodologies to produce functional carbon electrode-molecule junctions in current and future researches toward the development of practical molecular devices, thus offering a reliable platform for molecular electronics and the promise of a new generation of multifunctional integrated circuits and sensors.

Evolution of salt structures and Cretaceous uplift in westernmost Mississippi Salt basin, Madison Parish, Louisiana

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alam, A.H.M.S.; Pilger, R.H. Jr.

1988-09-01

Subsurface structures were interpreted from seismic images and well logs in the westernmost Mississippi Salt basin, Madison Parish, Louisiana. Structural and stratigraphic relations indicate that salt structures (Duckport, North Tallulah, South Coleman, Tallulah, and Walnut domes) have evolved through pillow, diapir, and postdiapir stages. Withdrawal synclines associated with each stage of growth occur adjacent to salt domes and are characterized by overthickening of sediments. Synclines associated with Walnut dome are particularly well recognized in the seismic data. Primary withdrawal synclines and present day turtle structure anticlines involve the deepest recorded reflections (possibly Jurassic carbonates) above seismically transparent Paleozoic basement andmore » overlying remnant salt. Similar early (Late Jurassic) salt mobility has recently been documented in North Louisiana and East Texas Salt basins. Secondary withdrawal synclines (Cotton Valley) are exceptionally overthickened and their axes are closer to the dome than the axes of primary synclines. Tertiary synclines are broad and appear to be active at present. North-south seismic sections that cross the approximate northwest boundary of the Mississippi Salt basin display post-middle Cretaceous upwarp (the Monroe Uplift) involving basement. Successively older Lower Cretaceous reflections are truncated to the north beneath an erosional surface. Upwarp apparently continued well into the Cenozoic.« less

Diverse dinosaur-dominated ichnofaunas from the Potomac Group (Lower Cretaceous) Maryland

USGS Publications Warehouse

Stanford, Ray; Lockley, Martin G.; Weems, Robert E.

2007-01-01

Until recently fossil footprints were virtually unknown from the Cretaceous of the eastern United States. The discovery of about 300 footprints in iron-rich siliciclastic facies of the Patuxent Formation (Potomac Group) of Aptian age is undoubtedly one of the most significant Early Cretaceous track discoveries since the Paluxy track discoveries in Texas in the 1930s. The Patuxent tracks include theropod, sauropod, ankylosaur and ornithopod dinosaur footprints, pterosaur tracks, and miscellaneous mammal and other vertebrate ichnites that collectively suggest a diversity of about 14 morphotypes. This is about twice the previous maximum estimate for any known Early Cretaceous vertebrate ichnofauna. Among the more distinctive forms are excellent examples of hypsilophodontid tracks and a surprisingly large mammal footprint. A remarkable feature of the Patuxent track assemblage is the high proportion of small tracks indicative of hatchlings, independently verified by the discovery of a hatchling-sized dinosaur. Such evidence suggests the proximity of nest sites. The preservation of such small tracks is very rare in the Cretaceous track record, and indeed throughout most of the Mesozoic.This unusual preservation not only provides us with a window into a diverse Early Cretaceous ecosystem, but it also suggests the potential of such facies to provide ichnological bonanzas. A remarkable feature of the assemblage is that it consists largely of reworked nodules and clasts that may have previously been reworked within the Patuxent Formation. Such unusual contexts of preservation should provide intriguing research opportunities for sedimentologists interested in the diagenesis and taphonomy of a unique track-bearing facies.

Lithological and Petrographic Analyses of Carbonates and Sandstones From the Southern Gulf of Mexico

NASA Astrophysics Data System (ADS)

Garcia-Avendaño, A.; Urrutia-Fucugauchi, J.

2012-04-01

We present results of sedimentological and petrological studies of drill cores from the Bay of Campeche in the southern Gulf of Mexico. Based on reports on drill cores obtained from oil exploratory wells in the Cantarell Complex located 80 kilometres offshore in the Bay of Campeche and studies related to regional geology composite simplified stratigraphic columns for offshore Campeche region have been constructed up to depths of approximately 5000 m. The stratigraphic column is formed by a thick sediment sequence of Middle Jurassic age (evaporites, Callovian), Late Jurassic (terrigenous, calcareous clays and calcareous layers), Lower Cretaceous (carbonates), Upper Cretaceous-Paleogene (calcareous breccias), Paleogene-Neogene (terrigenous-carbonates intercalations) and Quaternary (terrigenous). The core samples studied come from wells in the Sihil and Akal fields in Cantarell. Analysis of reports on lithological descriptions indicates that these wells sample dolomitized sedimentary breccias from the Upper Cretaceous-Paleocene and fine-grained sandstones from the Late Jurassic Tithonian, respectively. Based on results of petrographic studies, the texture, cementing material and porosity of the units have been documented. The thin sections for carbonates were classified based on their texture according to Dunham (1962) for carbonate rocks, classified according to their components using the ternary diagrams of Folk (1974). Percentages refer to the data presented in tables, which were obtained by point-counting technique (with a total 250). Photomicrographs of scanning electron microscope (SEM) provide magnification for easy documentation of crystalline arrangements and description of micro-porous for different types of carbonates such as dolomite, in addition to the morphology of authigenic clays. Results of these studies and previous works in the area permit characterization of diagenetic processes of the carbonate sediments in the Campeche Bay, and provide

Progress in Late Cretaceous planktonic foraminiferal stable isotope paleoecology and implications for paleoceanographic reconstructions

NASA Astrophysics Data System (ADS)

Petrizzo, Maria Rose; Falzoni, Francesca; Huber, Brian T.; MacLeod, Kenneth G.

2015-04-01

Paleoecological preferences proposed for Cretaceous planktonic foraminiferal taxa have traditionally been based on morphological analogies with depth-stratified modern species, on biofacies comparison in continental margin and deepwater settings, and limited oxygen and carbon stable isotope data. These studies concluded that large-sized, keeled and heavily calcified planktonic foraminifera generally lived at deeper levels in the surface waters than small-sized, thinner-walled non-keeled species. Stable isotope data have been used to infer information on paleotemperature, paleoceanography and paleoproductivity of ancient oceans and constrain biological paleo-activities (i.e. photosymbiosis and respiration) of fossil species. These studies have suggested that the depth-distribution model based on analogy with modern taxa might not be fully applicable for Cretaceous species, and found particularly 13C-enriched values in some Maastrichtian multiserial taxa that have been related to the activity of photosymbionts. We have collected about 1500 δ18O and δ13C species-specific analyses on glassy preserved planktonic foraminifera from Tanzania (Tanzania Drilling Project TDP sites 23, 28 and 32) and well-preserved planktonic foraminifera from other mid-low latitude localities (Shatsky Rise, northwestern Pacific Ocean, ODP Leg 198 Hole 1210B; Exmouth Plateau, eastern Indian Ocean, ODP Leg 122, Hole 762C; Eratosthenes Seamount, eastern Mediterranean, ODP Leg 160, Hole 967E; Blake Nose, central Atlantic Ocean, ODP Leg 171B, holes 1050C and 1052E) to investigate Late Cretaceous species paleoecological preferences, life strategies and depth distribution in the surface water column. Our results indicates that several large-sized (> 500 μm) double-keeled species belonging to the genera Dicarinella, Marginotruncana and Contusotruncana, generally interpreted as deep to thermocline dwellers, instead occupied shallow/warm layers of the water column, whilst not all biserial species

Paleomagnetism of the Cretaceous Galula Formation and implications for vertebrate evolution

NASA Astrophysics Data System (ADS)

Widlansky, Sarah J.; Clyde, William C.; O'Connor, Patrick M.; Roberts, Eric M.; Stevens, Nancy J.

2018-03-01

This study uses magnetostratigraphy to help constrain the age of the paleontologically important Galula Formation (Rukwa Rift Basin, southwestern Tanzania). The formation preserves a Cretaceous vertebrate fauna, including saurischian dinosaurs, a putative gondwanatherian mammal, and notosuchian crocodyliforms. With better dating, the Galula Formation and its fossils help fill a temporal gap in our understanding of vertebrate evolution in continental Africa, enabling better evaluation of competing paleobiogeographic hypotheses concerning faunal exchange throughout Gondwana during the Cretaceous. Paleomagnetic samples for this study were collected from the Namba (higher in section) and Mtuka (lower in section) members of the Galula Formation and underwent stepwise thermal demagnetization. All samples displayed a strong normal magnetic polarity overprint, and maximum unblocking temperatures at approximately 690 °C. Three short reversed intervals were identified in the Namba Member, whereas the Mtuka Member lacked any clear reversals. Given the relatively limited existing age constraints, one interpretation correlates the Namba Member to Chron C32. An alternative correlation assigns reversals in the Namba Member to recently proposed short reversals near the end of the Cretaceous Normal Superchron (Chron C34), a time that is traditionally interpreted as having stable normal polarity. The lack of reversals in the Mtuka Member supports deposition within Chron C34. These data suggest that the Namba Member is no older than Late Cretaceous (Cenomanian-Campanian), with the Mtuka Member less well constrained to the middle Cretaceous (Aptian-Cenomanian). The paleomagnetic results are supported by the application of fold and reversal tests for paleomagnetic stability, and paleomagnetic poles for the Namba (246.4°/77.9°, α95 5.9°) and Mtuka (217.1°/72.2°, α95 11.1°) members closely matching the apparent polar wander path for Africa during the Late Cretaceous. These

The efficiency of seismic attributes to differentiate between massive and non-massive carbonate successions for hydrocarbon exploration activity

NASA Astrophysics Data System (ADS)

Sarhan, Mohammad Abdelfattah

2017-12-01

The present work investigates the efficiency of applying volume seismic attributes to differentiate between massive and non-massive carbonate sedimentary successions on using seismic data. The main objective of this work is to provide a pre-drilling technique to recognize the porous carbonate section (probable hydrocarbon reservoirs) based on seismic data. A case study from the Upper Cretaceous - Eocene carbonate successions of Abu Gharadig Basin, northern Western Desert of Egypt has been tested in this work. The qualitative interpretations of the well-log data of four available wells distributed in the study area, namely; AG-2, AG-5, AG-6 and AG-15 wells, has confirmed that the Upper Cretaceous Khoman A Member represents the massive carbonate section whereas the Eocene Apollonia Formation represents the non-massive carbonate unit. The present work have proved that the most promising seismic attributes capable of differentiating between massive and non-massive carbonate sequences are; Root Mean Square (RMS) Amplitude, Envelope (Reflection Strength), Instantaneous Frequency, Chaos, Local Flatness and Relative Acoustic Impedance.

Impact production of CO2 by the Cretaceous/Tertiary extinction bolide and the resultant heating of the earth

NASA Technical Reports Server (NTRS)

O'Keefe, John D.; Ahrens, Thomas J.

1989-01-01

Various observations and data demonstrate that sea level at the end of the Cretaceous was 150-200 m higher than at present, suggesting the possibility that the extinction bolide struck a shallow marine carbonate-rich sedimentary section. It is shown here that the impact of such a bolide (about 5 km in radius) onto a carbonate-rich terrane would increase the CO2 content of the atmosphere by a factor of two to ten. Additional dissolution of CO2 from the ocean's photic zone could release much larger quantities of CO2. The impact-induced release of CO2, by itself, would enhance atmospheric greenhouse heating and give rise to a worldwide increase in temperature from 2 K to 10 K for periods of 10,000 to 100,000 years.

Bacterial Cellulose: A Robust Platform for Design of Three Dimensional Carbon-Based Functional Nanomaterials.

PubMed

Wu, Zhen-Yu; Liang, Hai-Wei; Chen, Li-Feng; Hu, Bi-Cheng; Yu, Shu-Hong

2016-01-19

Three dimensional (3D) carbon nanomaterials exhibit great application potential in environmental protection, electrochemical energy storage and conversion, catalysis, polymer science, and advanced sensors fields. Current methods for preparing 3D carbon nanomaterials, for example, carbonization of organogels, chemical vapor deposition, and self-assembly of nanocarbon building blocks, inevitably involve some drawbacks, such as expensive and toxic precursors, complex equipment and technological requirements, and low production ability. From the viewpoint of practical application, it is highly desirable to develop a simple, cheap, and environmentally friendly way for fabricating 3D carbon nanomaterials in large scale. On the other hand, in order to extend the application scope and improve the performance of 3D carbon nanomaterials, we should explore efficient strategies to prepare diverse functional nanomaterials based on their 3D carbon structure. Recently, many researchers tend to fabricate high-performance 3D carbon-based nanomaterials from biomass, which is low cost, easy to obtain, and nontoxic to humans. Bacterial cellulose (BC), a typical biomass material, has long been used as the raw material of nata-de-coco (an indigenous dessert food of the Philippines). It consists of a polysaccharide with a β-1,4-glycosidic linkage and has a interconnected 3D porous network structure. Interestingly, the network is made up of a random assembly of cellulose nanofibers, which have a high aspect ratio with a diameter of 20-100 nm. As a result, BC has a high specific surface area. Additionally, BC hydrogels can be produced on an industrial scale via a microbial fermentation process at a very low price. Thus, it can be an ideal platform for design of 3D carbon-based functional nanomaterials. Before our work, no systematic work and summary on this topic had been reported. This Account presents the concepts and strategies of our studies on BC in the past few years, that is

Dramatic nano-fluidic properties of carbon nanotube membranes as a platform for protein channel mimetics

NASA Astrophysics Data System (ADS)

Hinds, Bruce

2013-03-01

Carbon nanotubes have three key attributes that make them of great interest for novel membrane applications: 1) atomically flat graphite surface allows for ideal fluid slip boundary conditions and extremely fast flow rates 2) the cutting process to open CNTs inherently places functional chemistry at CNT core entrance for chemical selectivity and 3) CNT are electrically conductive allowing for electrochemical reactions and application of electric fields gradients at CNT tips. Pressure driven flux of a variety of solvents (H2O, hexane, decane ethanol, methanol) are 4-5 orders of magnitude higher than conventional Newtonian flow [Nature 2005, 438, 44] due to atomically flat graphite planes inducing nearly ideal slip conditions. However this is eliminated with selective chemical functionalization [ACS Nano 2011 5(5) 3867-3877] needed to give chemical selectivity. These unique properties allow us to explore the hypothesis of producing ``Gatekeeper'' membranes that mimic natural protein channels to actively pump through rapid nm-scale channels. With anionic tip functionality strong electroosmotic flow is induced by unimpeded cation flow with similar 10,000 fold enhancements [Nature Nano 2012 7(2) 133-39]. With enhanced power efficiency, carbon nanotube membranes were employed as the active element of a switchable transdermal drug delivery device that can facilitate more effective treatments of drug abuse and addiction. Recently methods to deposit Pt monolayers on CNT surface have been developed making for highly efficient catalytic platforms. Discussed are other applications of CNT protein channel mimetics, for large area robust engineering platforms, including water purification, flow battery energy storage, and biochemical/biomass separations. DOE EPSCoR (DE-FG02-07ER46375) and DARPA, W911NF-09-1-0267

Marine reptiles from the Late Cretaceous of northern Patagonia

NASA Astrophysics Data System (ADS)

Gasparini, Z.; Casadio, S.; Fernández, M.; Salgado, L.

2001-04-01

During the Campanian-Maastrichtian, Patagonia was flooded by the Atlantic and reduced to an archipelago. Several localities of northern Patagonia have yielded marine reptiles. Analysis of several assemblages suggests that the diversity and abundance of pelagic marine reptiles in northern Patagonia was higher by the end of the Cretaceous than previously thought. Several plesiosaurids, including Aristonectes parvidens and the polycotylid Sulcusuchus, and the first remains of mosasaurinae have been found. The Cretaceous marine reptile record from South America is scanty. Nevertheless, materials described here suggest that Tethyan and Weddelian forms converged in northern Patagonia, as seen with invertebrates.

Late Cretaceous terrestrial vertebrate fauna, North Slope, Alaska

DOE Office of Scientific and Technical Information (OSTI.GOV)

Clemens, W.A.; Allison, C.W.

1985-01-01

Closely related terrestrial vertebrates in Cretaceous mid-latitude (30/sup 0/ to 50/sup 0/) faunas of North America and Asia as well as scattered occurrences of footprints and skin impressions suggested that in the Late Mesozoic the Alaskan North Slope supported a diverse fauna. In 1961 abundant skeletal elements of Cretaceous, Alaskan dinosaurs (hadrosaurids) were discovered by the late R.L. Liscomb. This material is being described by K.L. Davies. Additional fossils collected by E.M. Brouwers and her associates include skeletal elements of hadrosaurid and carnosaurian (.tyrannosaurid) dinosaurs and other vertebrates. The fossil locality on the North Slope is not at about 70/supmore » 0/N. In the Late Cretaceous the members of this fauna were subject to the daylight regime and environment at a paleolatitude closer to 80/sup 0/N. Current hypotheses attributing extinctions of dinosaurs and some other terrestrial vertebrates to impact of an extraterrestrial object cite periods of darkness, decreased temperature (possibly followed by extreme warming) and acid rain as the direct causes of their demise. Unless members of this North Slope fauna undertook long-distance migrations, their high latitude occurrence indicates groups of dinosaurs and other terrestrial vertebrates regularly tolerated months of darkness.« less

A complete skull of an early cretaceous sauropod and the evolution of advanced titanosaurians.

PubMed

Zaher, Hussam; Pol, Diego; Carvalho, Alberto B; Nascimento, Paulo M; Riccomini, Claudio; Larson, Peter; Juarez-Valieri, Rubén; Pires-Domingues, Ricardo; da Silva, Nelson Jorge; Campos, Diógenes de Almeida

2011-02-07

Advanced titanosaurian sauropods, such as nemegtosaurids and saltasaurids, were diverse and one of the most important groups of herbivores in the terrestrial biotas of the Late Cretaceous. However, little is known about their rise and diversification prior to the Late Cretaceous. Furthermore, the evolution of their highly-modified skull anatomy has been largely hindered by the scarcity of well-preserved cranial remains. A new sauropod dinosaur from the Early Cretaceous of Brazil represents the earliest advanced titanosaurian known to date, demonstrating that the initial diversification of advanced titanosaurians was well under way at least 30 million years before their known radiation in the latest Cretaceous. The new taxon also preserves the most complete skull among titanosaurians, further revealing that their low and elongated diplodocid-like skull morphology appeared much earlier than previously thought.

Tracking the migration of the Indian continent using the carbonate clumped isotope technique on Phanerozoic soil carbonates

PubMed Central

Ghosh, Prosenjit; Vasiliev, Mikhail V.; Ghosh, Parthasarathi; Sarkar, Soumen; Ghosh, Sampa; Yamada, Keita; Ueno, Yuichiro; Yoshida, Naohiro; Poulsen, Christopher J.

2016-01-01

Approximately 140 million years ago, the Indian plate separated from Gondwana and migrated by almost 90° latitude to its current location, forming the Himalayan-Tibetan system. Large discrepancies exist in the rate of migration of Indian plate during Phanerozoic. Here we describe a new approach to paleo-latitudinal reconstruction based on simultaneous determination of carbonate formation temperature and δ18O of soil carbonates, constrained by the abundances of 13C-18O bonds in palaeosol carbonates. Assuming that the palaeosol carbonates have a strong relationship with the composition of the meteoric water, δ18O carbonate of palaeosol can constrain paleo-latitudinal position. Weighted mean annual rainfall δ18O water values measured at several stations across the southern latitudes are used to derive a polynomial equation: δ18Ow = −0.006 × (LAT)2 − 0.294 × (LAT) − 5.29 which is used for latitudinal reconstruction. We use this approach to show the northward migration of the Indian plate from 46.8 ± 5.8°S during the Permian (269 M.y.) to 30 ± 11°S during the Triassic (248 M.y.), 14.7 ± 8.7°S during the early Cretaceous (135 M.y.), and 28 ± 8.8°S during the late Cretaceous (68 M.y.). Soil carbonate δ18O provides an alternative method for tracing the latitudinal position of Indian plate in the past and the estimates are consistent with the paleo-magnetic records which document the position of Indian plate prior to 135 ± 3 M.y. PMID:26931069

Establishing a green platform for biodiesel synthesis via strategic utilization of biochar and dimethyl carbonate.

PubMed

Lee, Jechan; Jung, Jong-Min; Oh, Jeong-Ik; Sik Ok, Yong; Kwon, Eilhann E

2017-10-01

To establish a green platform for biodiesel production, this study mainly investigates pseudo-catalytic (non-catalytic) transesterification of olive oil. To this end, biochar from agricultural waste (maize residue) and dimethyl carbonate (DMC) as an acyl acceptor were used for pseudo-catalytic transesterification reaction. Reaction parameters (temperature and molar ratio of DMC to olive oil) were also optimized. The biodiesel yield reached up to 95.4% under the optimal operational conditions (380°C and molar ratio of DMC to olive oil (36:1)). The new sustainable environmentally benign biodiesel production introduced in this study is greener and faster than conventional transesterification reactions. Copyright © 2017 Elsevier Ltd. All rights reserved.

Chicxulub ejecta at the Cretaceous-Paleogene (K-P) boundary in Northeastern Mexico

NASA Astrophysics Data System (ADS)

Schulte, Peter; Kontny, Agnes

2005-04-01

The combined petrological and rock magnetic study of the Cretaceous-Paleogene (K-P) boundary in northeastern Mexico revealed compositionally and texturally complex Chicxulub ejecta deposits. The predominant silicic ejecta components are Fe-Mg-rich chlorite and Si-Al-K-rich glass spherules with carbonate inclusions and schlieren. Besides these silica phases, the most prominent ejecta component is carbonate. Carbonate occurs as lithic clasts, accretionary lapilli, melt globules (often with quench textures), and as microspar. The composition of the spherules provides evidence for a range of target rocks of mafic to intermediate composition, presumably situated in the northwestern sector of the Chicxulub impact structure. The abundance of carbonate ejecta suggests that this area received ejecta mainly from shallow, carbonate-rich lithologies. Rare µm-sized metallic and sulfidic Ni-Co-rich inclusions in the spherules indicate a possible contamination by meteoritic material. This complex composition underlines the similarities of ejecta in NE Mexico to Chicxulub ejecta from K-P sections worldwide. Although the ejecta display a great variability, the magnetic susceptibility, remanence, and hysteresis properties of the ejecta deposits are fairly homogeneous, with dominantly paramagnetic susceptibilities and a weak ferromagnetic contribution from hematite and goethite. The absence of spinels and the ubiquitous presence of hematite and goethite points to high oxygen fugacity during the impact process. The microfacies and internal texture of the ejecta deposits show welding and fusing of components, as well as evidence for liquid immiscibility between silicic and carbonate melts. No evidence for binary mixing of ejecta phases was found. Therefore, Chicxulub ejecta in NE Mexico probably derived from less energetic parts of the ejecta curtain. However, welding features of ejecta particles and enclosed marl clasts and/or benthic foraminifera from a siliciclastic environment

Nannofossil carbonate fluxes during the Early Cretaceous: Phytoplankton response to nutrification episodes, atmospheric CO2, and anoxia

NASA Astrophysics Data System (ADS)

Erba, Elisabetta; Tremolada, Fabrizio

2004-03-01

Greenhouse episodes during the Valanginian and Aptian correlate with major perturbations in the C cycle and in marine ecosystems, carbonate crises, and widespread deposition of Corg-rich black shales. Quantitative analyses of nannofossil micrite were conducted on continuous pelagic sections from the Southern Alps (northern Italy), where high-resolution integrated stratigraphy allows precise dating of Early Cretaceous geological events. Rock-forming calcareous nannofloras were quantified in smear slides and thin sections to obtain relative and absolute abundances and paleofluxes that are interpreted as the response of calcareous phytoplankton to global changes in the ocean-atmosphere system. Increased rates of volcanism during the formation of Ontong Java and Manihiki Plateaus and the Paranà-Etendeka large igneous province (LIP) are proposed to have caused the geological responses associated with early Aptian oceanic anoxic event (OAE) 1a and the Valanginian event, respectively. Calcareous nannofloras reacted to the new conditions of higher pCO2 and fertility by drastically reducing calcification. The Valanginian event is marked by a 65% reduction in nannofossil paleofluxes that would correspond to a 2-3 times increase in pCO2 during formation of the Paranà-Endenteka LIP. A 90% reduction in nannofossil paleofluxes, which occurred in a 1.5 myr-long interval leading into OAE1a, is interpreted as the result of a 3-6 times increase in pCO2 produced by emplacement of the giant Ontong Java and Manihiki Plateaus. High pCO2 was balanced back by an accelerated biological pump during the Valanginian episode, but not during OAE1a, suggesting persisting high levels of pCO2 in the late Aptian and/or the inability of calcareous phytoplankton to absorb excess pCO2 above threshold values.

New Age of Fishes initiated by the Cretaceous-Paleogene mass extinction

NASA Astrophysics Data System (ADS)

Sibert, Elizabeth C.; Norris, Richard D.

2015-07-01

Ray-finned fishes (Actinopterygii) comprise nearly half of all modern vertebrate diversity, and are an ecologically and numerically dominant megafauna in most aquatic environments. Crown teleost fishes diversified relatively recently, during the Late Cretaceous and early Paleogene, although the exact timing and cause of their radiation and rise to ecological dominance is poorly constrained. Here we use microfossil teeth and shark dermal scales (ichthyoliths) preserved in deep-sea sediments to study the changes in the pelagic fish community in the latest Cretaceous and early Paleogene. We find that the Cretaceous-Paleogene (K/Pg) extinction event marked a profound change in the structure of ichthyolith communities around the globe: Whereas shark denticles outnumber ray-finned fish teeth in Cretaceous deep-sea sediments around the world, there is a dramatic increase in the proportion of ray-finned fish teeth to shark denticles in the Paleocene. There is also an increase in size and numerical abundance of ray-finned fish teeth at the boundary. These changes are sustained through at least the first 24 million years of the Cenozoic. This new fish community structure began at the K/Pg mass extinction, suggesting the extinction event played an important role in initiating the modern "age of fishes."

New Age of Fishes initiated by the Cretaceous-Paleogene mass extinction.

PubMed

Sibert, Elizabeth C; Norris, Richard D

2015-07-14

Ray-finned fishes (Actinopterygii) comprise nearly half of all modern vertebrate diversity, and are an ecologically and numerically dominant megafauna in most aquatic environments. Crown teleost fishes diversified relatively recently, during the Late Cretaceous and early Paleogene, although the exact timing and cause of their radiation and rise to ecological dominance is poorly constrained. Here we use microfossil teeth and shark dermal scales (ichthyoliths) preserved in deep-sea sediments to study the changes in the pelagic fish community in the latest Cretaceous and early Paleogene. We find that the Cretaceous-Paleogene (K/Pg) extinction event marked a profound change in the structure of ichthyolith communities around the globe: Whereas shark denticles outnumber ray-finned fish teeth in Cretaceous deep-sea sediments around the world, there is a dramatic increase in the proportion of ray-finned fish teeth to shark denticles in the Paleocene. There is also an increase in size and numerical abundance of ray-finned fish teeth at the boundary. These changes are sustained through at least the first 24 million years of the Cenozoic. This new fish community structure began at the K/Pg mass extinction, suggesting the extinction event played an important role in initiating the modern "age of fishes."

Chicxulub Impact Crater and Yucatan Carbonate Platform - PEMEX Oil Exploratory Wells Revisited

NASA Astrophysics Data System (ADS)

Pérez-Drago, G.; Gutierrez-Cirlos, A. G.; Pérez-Cruz, L.; Urrutia-Fucugauchi, J.

2008-12-01

Geophysical oil exploration surveys carried out by PEMEX in the 1940's revealed occurrence of an anomalous pattern of semi-circular concentric gravity anomalies. The Bouguer gravity anomalies covered an extensive area over the flat carbonate platform in the northwestern Yucatan Peninsula; strong density contrasts were suggestive of a buried igneous complex or basement uplift beneath the carbonates, which was referred as the Chicxulub structure. The exploration program carried out afterwards included a drilling program, starting with Chicxulub-1 well in 1952 and comprising eight deep boreholes through the 1970s. An aeromagnetic survey in late 1970's showed high amplitude anomalies in the gravity anomaly central sector. Thus, research showing Chicxulub as a large complex impact crater formed at the K/T boundary was built on the PEMEX decades-long exploration program. Despite frequent reference to PEMEX information and samples, original data and cores have not been openly available for detailed evaluation and integration with results from recent investigations. Core samples largely remain to be analyzed and interpreted in the context of recent marine, aerial and terrestrial geophysical surveys and the drilling/coring projects of UNAM and ICDP. In this presentation we report on the stratigraphy and paleontological data for PEMEX wells: Chicxulub- 1 (1582m), Sacapuc-1 (1530m), Yucatan-6 (1631m), Ticul-1 (3575m) Yucatan-4 (2398m), Yucatan-2 (3474m), Yucatan-5A (3003m) and Yucatan-1 (3221m). These wells remain the deepest drilled in Chicxulub, providing samples of impact lithologies, carbonate sequences and basement, which give information on post- and pre-impact stratigraphy and crystalline basement. We concentrate on stratigraphic columns, lateral correlations and integration with UNAM and ICDP borehole data. Current plans for deep drilling in Chicxulub crater target the peak ring and central sector, with offshore and onshore boreholes proposed to the IODP and ICDP

Origin of phosphatic stromatolites in the Upper Cretaceous condensed sequence of the Polish Jura Chain

NASA Astrophysics Data System (ADS)

Krajewski, K. P.; Leśniak, P. M.; Łącka, B.; Zawidzki, P.

2000-10-01

The Turonian stromatolite-bearing condensed sequence in the Polish Jura Chain (the European epicontinental basin) provides good insight into the environment of formation of Cretaceous phosphatic stromatolites, owing to their purely phosphatic development and negligible post-depositional alteration. The sequence developed as a result of slow pelagic sedimentation and microbial mat phosphatization on a submarine swell surrounded by local basins with non-condensed carbonate deposition. Diagenesis of organic matter and dissolution of biogenic apatite were the major sources of reactive phosphorus for the microbial mat phosphatization. Stromatolite growth occurred due to pulses of amorphous or poorly ordered calcium phosphate precipitation followed by crystallization of carbonate fluorapatite (CFA). The phosphogenic environment left an imprint on the isotopic composition of limestone carbon and lattice-bound carbon and sulphur in CFA, and on the light rare-earth element (LREE) distribution in CFA. The δ13C of the stromatolite-bearing sequence shows a negative excursion (-1 to -3‰), standing in marked contrast to positive carbon values of the surrounding basinal carbonate. Most of the δ34S values of CFA (+20 to +21‰) fit the value range of the coeval seawater sulphate, and the LREE distribution shows a well-defined seawater pattern. This geochemical signature is indicative of intense diagenesis of organic matter at the seafloor, pelagic carbonate dissolution, and prolonged exposure of the deposited phosphate towards the water column. The enhanced deposition and diagenesis of organic phosphorus in the stromatolitic environment reflects elevated levels of the epicontinental basin nutrification related to sea-level rises and the associated oceanographic and geochemical changes.

Paleobiological implications of dinosaur egg-bearing deposits in the Cretaceous Gyeongsang Supergroup of Korea

NASA Astrophysics Data System (ADS)

Paik, In Sung; Kim, Hyun Joo; Huh, Min

2010-05-01

Dinosaur egg-bearing deposits in the Cretaceous Gyeongsang Basin in Korea is described in taphonomic aspect, their paleoenvironments are interpreted, and geobiological implications of dinosaur egg-bearing deposits in the world and Korea are analyzed in geographic occurrences, geological ages, paleoenvironments, and lithology. Dinosaur eggs with spheroolithids, faveoloolithid, and elongatoolithid structural types occur in several stratigraphic formations of the Cretaceous Gyeongsang Basin in South Korea, and most of the egg-bearing formations are the Late Cretaceous. The dinosaur eggs usually occur as clutches in purple sandy mudstone of floodplain deposits preserved as calcic paleosol with association of vertic paleosol features in places. Most of the eggs are top-broken and filled with surrounding sediments. The general depositional environment of dinosaur egg deposits in the Gyeongsang Supergroup are interpreted as a dried floodplain where volcanic activity occurred intermittently in the vicinity of the nesting sites. Their depositional settings on which floodplains developed are diverse from fluvial plain with meandering rivers to alluvial plain with episodic sheet flooding. The nesting areas in the Gyeongsang Basin are deemed to have been under semi-arid climate, which resulted in formation of calcic soils facilitating preservation of the dinosaur eggs. The geochronologic occurrences of dinosaur egg-bearing deposits are mostly restricted to the Late Cretaceous in the world as well as in Korea. If it has not been resulted from biased discoveries and reports of dinosaur eggs, biological rather than physical and chemical conditions for preservation of dinosaur eggs might be related with the restricted occurrences in the Late Cretaceous. Two hypotheses are suggested for probable biological causes to the geochronologically restricted occurrences of dinosaur egg-bearing deposits. One is related with the appearance of angiosperms in the Late Jurassic and the spreading

Evidence of reworked Cretaceous fossils and their bearing on the existence of Tertiary dinosaurs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Eaton, J.G.; Kirkland, J.I.; Doi, K.

The Paleocene Shotgun fauna of Wyoming includes marine sharks as well as mammals. It has been suggested that the sharks were introduced from the Cannonball Sea. It is more likely that these sharks were reworked from a Cretaceous rock sequence that included both marine and terrestrial deposits as there is a mixture of marine and freshwater taxa. These taxa have not been recorded elsewhere after the Cretaceous and are not known from the Cannonball Formation. Early Eocene localities at Raven Ridge, Utah, similarly contain teeth of Cretaceous marine and freshwater fish, dinosaurs, and Eocene mammals. The Cretaceous teeth are wellmore » preserved, variably abraded, and serve to cast doubts on criteria recently used to claim that dinosaur teeth recovered from the Paleocene of Montana are not reworked. Another Eocene locality in the San Juan Basin has produced an Eocene mammalian fauna with diverse Cretaceous marine sharks. Neither the nature of preservation nor the degree of abrasion could be used to distinguish reworked from contemporaneous material. The mixed environments represented by the fish taxa and recognition of the extensive pre-Tertiary extinction of both marine and freshwater fish were employed to recognize reworked specimens.« less

Carbonate factories: A conundrum in sedimentary geology

NASA Astrophysics Data System (ADS)

Pomar, L.; Hallock, P.

2008-03-01

Describing, characterizing and interpreting the nearly infinite variety of carbonate rocks are conundrums - intricate and difficult problems having only conjectural answers - that have occupied geologists for more than two centuries. Depositional features including components, rock textures, lithofacies, platform types and architecture, all vary in space and time, as do the results of diagenetic processes on those primary features. Approaches to the study of carbonate rocks have become progressively more analytical. One focus has evolved from efforts to build reference models for specific Phanerozoic windows to scrutinize the effect of climate and long-term oscillations of the ocean-atmosphere system in influencing the mineralogy of carbonate components. This paper adds to the ongoing lively debates by attempting to understand changes in the predominant types of carbonate-producing organisms during the Mesozoic-Cenozoic, while striving to minimize the uniformitarian bias. Our approach integrates estimates of changes in Ca 2+ concentration in seawater and atmospheric CO 2, with biological evolution and ecological requirements of characteristic carbonate-producing marine communities. The underlying rationale for our approach is the fact that CO 2 is basic to both carbonates and organic matter, and that photosynthesis is a fundamental biological process responsible for both primary production of organic matter and providing chemical environments that promote calcification. Gross photosynthesis and hypercalcification are dependent largely upon sunlight, while net primary production and, e.g., subsequent burial of organic matter typically requires sources of new nutrients (N, P and trace elements). Our approach plausibly explains the changing character of carbonate production as an evolving response to changing environmental conditions driven by the geotectonic cycle, while identifying uncertainties that deserve further research. With metazoan consumer diversity reduced

Tectonosedimentary framework of Upper Cretaceous -Neogene series in the Gulf of Tunis inferred from subsurface data: implications for petroleum exploration

NASA Astrophysics Data System (ADS)

Dhraief, Wissem; Dhahri, Ferid; Chalwati, Imen; Boukadi, Noureddine

2017-04-01

The objective and the main contribution of this issue are dedicated to using subsurface data to delineate a basin beneath the Gulf of Tunis and its neighbouring areas, and to investigate the potential of this area in terms of hydrocarbon resources. Available well data provided information about the subsurface geology beneath the Gulf of Tunis. 2D seismic data allowed delineation of the basin shape, strata geometries, and some potential promising subsurface structures in terms of hydrocarbon accumulation. Together with lithostratigraphic data obtained from drilled wells, seismic data permitted the construction of isochron and isobath maps of Upper Cretaceous-Neogene strata. Structural and lithostratigraphic interpretations indicate that the area is tectonically complex, and they highlight the tectonic control of strata deposition during the Cretaceous and Neogene. Tectonic activity related to the geodynamic evolution of the northern African margin appears to have been responsible for several thickness and facies variations, and to have played a significant role in the establishment and evolution of petroleum systems in northeastern Tunisia. As for petroleum systems in the basin, the Cretaceous series of the Bahloul, Mouelha and Fahdene formations are acknowledged to be the main source rocks. In addition, potential reservoirs (Fractured Abiod and Bou Dabbous carbonated formations) sealed by shaly and marly formations (Haria and Souar formations respectively) show favourable geometries of trap structures (anticlines, tilted blocks, unconformities, etc.) which make this area adequate for hydrocarbon accumulations.

Geoligical outline of the Lower Cretaceous Bahia Supergroup, Brazil

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fonseca, J.I.

1966-01-01

The report area encompasses about 41,200 sq km covered by over 6,000 m of Lower Cretaceous sediments deposited in fresh to brackish water environment. These sediments, the Bahia Supergroup, represent most of the sedimentary section of the Almada, Reconcavo, Tucano and Jatoba basins. The Reconcavo basin is a half-graben filled with Lower Cretaceous rocks which tilt regionally to the SE. The sediments deposited in this basin were distorted by 2 major periods of deformation. As the result of the application of these systems of tensional forces, the sediments were broken into a complicated system of normal faults. Most of themore » oil production in Brazil, about 91,000 bpd, comes from the Reconcavo basin. During a great part of the Early Cretaceous the Reconcavo and Almada basins probably were connected with the Alagoas-Sergipe basin by the continental shelf. The continental drift theory may explain the presence of these fresh water sediments in the coast line and in the continental shelf of the Bahia and Alagoas-Sergipe states. This offshore area is very prospective and may contribute, in the future, with substantial quantities of hydrocarbons. (14 refs.)« less

Compaction history of Upper Cretaceous shale (Al-Khod Formation) and its relationship to plate margin tectonics, Arabian Plate, Sultanate of Oman

NASA Astrophysics Data System (ADS)

AL-Sarmi, Musaab; Mattern, Frank; Scharf, Andreas; Pracejus, Bernhard; Al-Mamari, Amira; Al-Hinaai, Al-Shima

2017-04-01

Conglomerates of the late Cretaceous Al-Khod Formation have been intruded by older shale of the same formation along faults, which were opened/widened by extension, thus, resulting in shale dike formation. Following intrusion the shale was behaving plastically as its fissility follows the contact contours of the conglomeratic host rock and as stoped sandstone blocks are floating within the shale. Vertical calcite veins were ptygmatically folded with subhorizontal fold axial planes. All these aspects show that the shale contained a high water content in the beginning. The ptygmatically folded calcite veins display vertical shortening amounts of 40 % corresponding to 35 % to 45 % of water loss during compaction. Incalculable numbers of calcite veins of different orientations and thicknesses within the conglomerate along the shale contact indicate that the fluid was expelled from the shale into the conglomerate host rock under high pressure (overpressure?). Shale dyke formation took place after the late Cretaceous obduction of the Semail Ophiolite, before the deposition of early Tertiary carbonate rocks, and during the latest Cretaceous doming of the Saih Hatat area which was caused by deformation and slab breakoff, likely associated with gravitational collapse and elastic rebound. Shale intrusion was followed by deposition of 100 to 200 m thick sediments of the upper part of Al-Khod Formation, leading to compaction and water loss. The shale retained much of its water during the uppermost Cretaceous-late Paleocene stratigraphic hiatus as this interval is marked by erosion and a reduction of overburden, which was probably due to the elastic rebound. Folding of calcite veins together with a high amount of water loss was a consequence of compaction caused by the overburden of 1000 m thick shallow marine limestones which were deposited from the Eocene to Oligocene.

Cretaceous paleoceanography of the western North Atlantic Ocean

USGS Publications Warehouse

Arthur, Michael A.; Dean, Walter E.

1986-01-01

In this paper we summarize available information on the Cretaceous lithostratigraphy and paleoceanography of the western North Atlantic. The data and some of our interpretations draw in large part on papers published in the Deep Sea Drilling Project (DSDP) volumes. We have attempted to cite relevant references when possible, but space limitations make it difficult to give proper credit to all sources; we apologize for any omissions.Organic carbon (Corg) and carbonate (CaCO3) analyses were tabulated for each site from papers in the DSDP Initial Report volumes and other published works (e.g., Summerhayes,1981). Corg, CaCO3, and non-CaCO3 mass accumulation rates (MARS) were calculated using core by core averages of component percentages for the more continuously cored sites; core averages for wet bulk density and porosity (from DSDP data files); biostratigraphies of de Graciansky and others (1982), Roth and Bowdler (1981), and Cool (1982); and the time scales of the Decade of North American Geology (Palmer, 1983; Kent and Gradstein, this volume) or Harland and others (1982; see Plate 1).Backtracked paleodepths for western North Atlantic DSDP Sites from Tucholke and Vogt (1979) with the revised stratigraphy of de Graciansky and others (1982) were used in plotting Corg and CaCO3 in Figures 2, 3, 4 and 5 (see also Thierstein, 1979).Backtracking curves of seafloor paleodepth versus age (Sclater and others, 1977; Tucholke and Vogt, 1979) for selected western North Atlantic DSDP sites. Average CaCO3 concentrations per core are shown by code number

Changes to Cretaceous surface fire behaviour influenced the spread of the early angiosperms.

PubMed

Belcher, Claire M; Hudspith, Victoria A

2017-02-01

Angiosperms evolved and diversified during the Cretaceous period. Early angiosperms were short-stature weedy plants thought to have increased fire frequency and mortality in gymnosperm forest, aiding their own expansion. However, no explorations have considered whether the range of novel fuel types that diversified throughout the Cretaceous also altered fire behaviour, which should link more strongly to mortality than fire frequency alone. We measured ignitability and heat of combustion in analogue Cretaceous understorey fuels (conifer litter, ferns, weedy and shrubby angiosperms) and used these data to model palaeofire behaviour. Variations in ignition, driven by weedy angiosperms alone, were found to have been a less important feedback to changes in Cretaceous fire activity than previously estimated. Our model estimates suggest that fires in shrub and fern understories had significantly greater fireline intensities than those fuelled by conifer litter or weedy angiosperms, and whilst fern understories supported the most rapid fire spread, angiosperm shrubs delivered the largest amount of heat per unit area. The higher fireline intensities predicted by the models led to estimates of enhanced scorch of the gymnosperm canopy and a greater chance of transitioning to crown fires. Therefore, changes in fire behaviour driven by the addition of new Cretaceous fuel groups may have assisted the angiosperm expansion. © 2016 The Authors. New Phytologist © 2016 New Phytologist Trust.

Distinguishing base-level change and climate signals in a Cretaceous alluvial sequence

USGS Publications Warehouse

White, T.; Witzke, B.; Ludvigson, G. A.; Brenner, R.

2005-01-01

We present the results of oxygen isotope and electron-microprobe analyses of sphaerosiderites obtained from Cretaceous paleosols in Iowa. The sphaerosiderite ??18O values record Cretaceous meteoric groundwater chemistry and an overall waning of brackish groundwater inundation during alluvial-plain aggradation and soil genesis. We focus on horizons that precipitated from freshwater, in which ??18O values ranging from -3.30??? to -6.8??? relative to the Peedee belemnite standard are interpreted to record variations in the Cretaceous atmospheric hydrologic cycle. During relative sea-level highstands, moisture was derived from the Cretaceous Western Interior Seaway, whereas during lowstands, when the seaway narrowed and occasionally withdrew from the Midcontinent, the dominance of hemispheric-scale atmospheric moisture transport initiated in the tropical Tethys Ocean led to decreased precipitation rates. These processes did not operate like a switch, but rather as a continuum of competing moisture sources and mechanisms of transport between the nearby epicontinental sea and the distant tropics. The sphaerosiderite data demonstrate (1) temporal variation in the intensity of hemispheric-scale atmospheric moisture transport and (2) long-term amplification of the global hydrologic cycle marked by extreme 18O depletion at the Albian-Cenomanian boundary. ?? 2005 Geological Society of America.

New Ophthalmosaurid Ichthyosaurs from the European Lower Cretaceous Demonstrate Extensive Ichthyosaur Survival across the Jurassic–Cretaceous Boundary

PubMed Central

Fischer, Valentin; Maisch, Michael W.; Naish, Darren; Kosma, Ralf; Liston, Jeff; Joger, Ulrich; Krüger, Fritz J.; Pérez, Judith Pardo; Tainsh, Jessica

2012-01-01

Background Ichthyosauria is a diverse clade of marine amniotes that spanned most of the Mesozoic. Until recently, most authors interpreted the fossil record as showing that three major extinction events affected this group during its history: one during the latest Triassic, one at the Jurassic–Cretaceous boundary (JCB), and one (resulting in total extinction) at the Cenomanian-Turonian boundary. The JCB was believed to eradicate most of the peculiar morphotypes found in the Late Jurassic, in favor of apparently less specialized forms in the Cretaceous. However, the record of ichthyosaurs from the Berriasian–Barremian interval is extremely limited, and the effects of the end-Jurassic extinction event on ichthyosaurs remains poorly understood. Methodology/Principal Findings Based on new material from the Hauterivian of England and Germany and on abundant material from the Cambridge Greensand Formation, we name a new ophthalmosaurid, Acamptonectes densus gen. et sp. nov. This taxon shares numerous features with Ophthalmosaurus, a genus now restricted to the Callovian–Berriasian interval. Our phylogenetic analysis indicates that Ophthalmosauridae diverged early in its history into two markedly distinct clades, Ophthalmosaurinae and Platypterygiinae, both of which cross the JCB and persist to the late Albian at least. To evaluate the effect of the JCB extinction event on ichthyosaurs, we calculated cladogenesis, extinction, and survival rates for each stage of the Oxfordian–Barremian interval, under different scenarios. The extinction rate during the JCB never surpasses the background extinction rate for the Oxfordian–Barremian interval and the JCB records one of the highest survival rates of the interval. Conclusions/Significance There is currently no evidence that ichthyosaurs were affected by the JCB extinction event, in contrast to many other marine groups. Ophthalmosaurid ichthyosaurs remained diverse from their rapid radiation in the Middle Jurassic to

Geology and physiography of the continental margin north of Alaska and implications for the origin of the Canada Basin

USGS Publications Warehouse

Grantz, Arthur; Eittreim, Stephen L.; Whitney, O.T.

1979-01-01

The continental margin north of Alaska is of Atlantic type. It began to form probably in Early Jurassic time but possibly in middle Early Cretaceous time, when the oceanic Canada Basin of the Arctic Ocean is thought to have opened by rifting about a pole of rotation near the Mackenzie Delta. Offsets of the rift along two fracture zones are thought to have divided the Alaskan margin into three sectors of contrasting structure and stratigraphy. In the Barter Island sector on the east and the Chukchi sector on the west the rift was closer to the present northern Alaska mainland than in the Barrow sector, which lies between them. In the Barter Island and Chukchi sectors the continental shelf is underlain by prisms of clastic sedimentary rocks that are inferred to include thick sections of Jurassic and Neocomian (lower Lower Cretaceous) strata of southern provenance. In the intervening Barrow sector the shelf is underlain by relatively thin sections of Jurassic and Neocomian strata derived from northern sources that now lie beneath the outer continental shelf. The rifted continental margin is overlain by a prograded prism of Albian (upper Lower Cretaceous) to Tertiary clastic sedimentary rocks that comprises the continental terrace of the western Beaufort and northern Chukchi Seas. On the south the prism is bounded by Barrow arch, which is a hingeline between the northward-tilted basement surface beneath the continental shelf of the western Beaufort Sea and the southward-tilted Arctic Platform of northern Alaska. The Arctic platform is overlain by shelf clastic and carbonate strata of Mississippian to Cretaceous age, and by Jurassic and Cretaceous clastic strata of the Colville foredeep. Both the Arctic platform and Colville foredeep sequences extend from northern Alaska beneath the northern Chukchi Sea. At Herald fault zone in the central Chukchi Sea they are overthrust by more strongly deformed Cretaceous to Paleozoic sedimentary rocks of Herald arch, which trends

Integrated geophysical and geological study and petroleum appraisal of Cretaceous plays in the Western Gulf of Gabes, Tunisia

NASA Astrophysics Data System (ADS)

Dkhaili, Noomen; Bey, Saloua; El Abed, Mahmoud; Gasmi, Mohamed; Inoubli, Mohamed Hedi

2015-09-01

An integrated study of available seismic and calibrated wells has been conducted in order to ascertain the structural development and petroleum potential of the Cretaceous Formations of the Western Gulf of Gabes. This study has resulted in an understanding of the controls of deep seated Tethyan tectonic lineaments by analysis of the Cretaceous deposits distribution. Three main unconformities have been identified in this area, unconformity U1 between the Jurassic and Cretaceous series, unconformity U2 separating Early from Late Cretaceous and known as the Austrian unconformity and the major unconformity U3 separating Cretaceous from Tertiary series. The seismic analysis and interpretation have confirmed the existence of several features dominated by an NE-SW extensive tectonic regime evidenced by deep listric faults, asymmetric horst and graben and tilted blocks structures. Indeed, the structural mapping of these unconformities, displays the presence of dominant NW-SE fault system (N140 to N160) bounding a large number of moderate sized basins. A strong inversion event related to the unconformity U3 can be demonstrated by the mapping of the unconformities consequence of the succession of several tectonic manifestations during the Cretaceous and post-Cretaceous periods. These tectonic events have resulted in the development of structural and stratigraphic traps further to the porosity and permeability enhancement of Cretaceous reservoirs.

Life Underneath the Deccan Trap: New Insights from Stable C, O and Clumped Isotopes from the Cretaceous Stromatolites Underneath the Amba Dongar Carbonatite Body, Gujarat, Western India

NASA Astrophysics Data System (ADS)

Banerjee, Y.; Ghosh, P.; Fosu, B. R.; Viladkar, S.

2016-12-01

Amba Dongar carbonatite-alkaline complex has been a longstanding subject of interest for the geoscientists as it is one of the best examples of a carbonatite ring dike complex emplaced in the western part of the Deccan Flood Basalts. The emplacement age at the K-T boundary (65 ma,) (1) makes it an exclusive body to understand the complexity of the Deccan eruption. Radiogenic Sr isotope study of carbonatites and alkaline silicate rocks of this complex indicate their cogenetic origin (1). The Amba Dongar complex intrudes cretaceous sedimentary layers known as the Bagh Formation of early to middle cretaceous based on biostratigraphic correlation (2). Although the carbonatite body has been investigated widely but only few attempts were made to investigate the sedimentary formations underneath. Here we report occurrence of cretaceous stromatolite deposit from the Amba Dongar complex. These stromatolites, previously interpreted as Travertine (3), occurs as thick sedimentary deposits in the valleys of Amba Dongar dome. Our preliminary stable C and O isotope results show a range of δ13CVPDB values from -2.24 to -3.90 ‰ while δ18OVPDB values ranges from -1.43 to -8.10‰ which is isotopically distinct from the Bagh Bed sediments investigated by others (4). In a δ13C vs δ18O crossplot, values are consistent with palustrine carbonates of Lameta Beds (4). The comparison between our results with the other cretaceous stromatolites deposits showed that the stromatolites from Amba Dongar were deposited in a coastal environment and that with the phanerozoic seawater δ13C , δ18O evolution curve given by (5) confirms its late cretaceous age. Based on the petrography studies, we speculate presence of organic debris in the layered structures and possible indication of thermal maturity (as the deposit is intruded by the Deccan basalt) suggesting reservoir characteristic of a hydrocarbon deposit. Further Clumped isotope investigation of the carbonate and organic matter extraction

High-resolution leaf-fossil record spanning the Cretaceous/Tertiary boundary

USGS Publications Warehouse

Johnson, K.R.; Nichols, D.J.; Attrep, M.; Orth, C.J.

1989-01-01

THEORIES that explain the extinctions characterizing the Cretaceous/Tertiary (K/T) boundary1-3 need to be tested by analyses of thoroughly sampled biotas. Palynological studies are the primary means for stratigraphic placement of the terrestrial boundary and for estimates of plant extinction4-12, but have not been combined with quantitative analyses of fossil leaves (megaflora). Megafloral studies complement palynology by representing local floras with assemblages capable of high taxonomic resolution13, but have previously lacked the sample size and stratigraphic spacing needed to resolve latest Cretaceous floral history5,14-18. We have now combined megafloral data from a 100-m-thick composite K/T boundary section in North Dakota with detailed palynological analysis. Here the boundary is marked by a 30% palynofloral extinction coincident with iridium and shocked-mineral anomalies and lies ???2 m above the highest dinosaur remains. The megaflora undergoes a 79% turnover across the boundary, and smaller changes 17- and 25-m below it. This pattern is consistent with latest Cretaceous climatic warming preceding a bolide impact. ?? 1989 Nature Publishing Group.

Toward a standardized soil carbon database platform in the US Critical Zone Observatory Network

NASA Astrophysics Data System (ADS)

Filley, T. R.; Marini, L.; Todd-Brown, K. E.; Malhotra, A.; Harden, J. W.; Kumar, P.

2017-12-01

Within the soil carbon community of the US Critical Zone Observatory (CZO) Network, efforts are underway to promote network-level data syntheses and modeling projects and to identify barriers to data intercomparability. This represents a challenging goal given the diversity of soil carbon sampling methodologies, spatial and vertical resolution, carbon pool isolation protocols, subsequent measurement techniques, and matrix terminology. During the last annual meeting of the CZO SOC Working Group, Dec 11, 2016, it was decided that integration with, and potentially adoption of, a widely used, active, and mature data aggregation, archival, and visualization platform was the easiest route to achieve this ultimate goal. Additionally, to assess the state of deep and shallow soil C data among the CZO sites it was recommended that a comprehensive survey must be undertaken to identify data gaps and catalog the various soil sampling and analysis methodologies. The International Soil Carbon Network (ISCN) has a long history of leadership in the development of soil C data aggregation, archiving, and visualization tools and currently houses data for over 70,000 soil cores contributed from international soil carbon community. Over the past year, members of the CZO network and the ISCN have met to discuss logistics of adopting the ISCN template within the CZO. Collaborative efforts among all of the CZO site data managers, led by the Intensively Managed Landscapes CZO, will evaluate feasibility of adoption of the ISCN template, or some modification thereof, and distribution to the appropriate soil scientists for data upload and aggregation. Partnering with ISCN also ensures that soil characteristics from the US CZO are placed in a developing global soil context and paves the way for future integration of data from other international CZO networks. This poster will provide an update of this overall effort along with a summary of data products, partnering networks, and recommendations

Anza palaeoichnological site. Late Cretaceous. Morocco. Part I. The first African pterosaur trackway (manus only)

NASA Astrophysics Data System (ADS)

Masrour, Moussa; Pascual-Arribas, Carlos; de Ducla, Marc; Hernández-Medrano, Nieves; Pérez-Lorente, Félix

2017-10-01

Cretaceous pterosaurs tracksites are very rare worldwide. Until now,only one African Cretaceous site withtracks of (Agadirichnus elegans and Pteraichnus) was known. This makes the discovery of a new outcrop in the Upper Cretaceous of Anza (Morocco) the third manifestation of this type of footprint in Africa, extending the existence of such traces from the Coniacian-Santonian to the Maastrichtian. The site contains only manus tracks, which can be explained as a result of erosion of pes prints. The lack of pes prints and the morphometric characteristics of the manus prints only allow us to relate these prints to Agadirichnus, Pteraichnus or maybe to a new ichnogenus. It is possible that the trackmakers are related to Ornithocheiroidea or Azhdarchoidea superfamilies whose fossil bones have been found from the Late Cretaceous in Morocco.

Magnetostratigraphy of the Lower Cretaceous Hekou and Liupanshan Group in NW China and its Implications for the Composite of the Cretaceous Normal Superchron (cns)

NASA Astrophysics Data System (ADS)

Dai, S.; Yan, N.; Luo, L.; Jenkyns, H. C.; Mac Niocaill, C.; Tang, Y.; Peng, D.; Wang, W.

2015-12-01

Are the short reversed-polarity subzones of the Cretaceous Normal Superchron (CNS) recorded in non-marine deposits? And, if so, how long did they last? These questions have been a matter of debate for some time. Lower Cretaceous terrestrial deposits in NW China, provide an opportunity to examine this problem. Here we present high-resolution magnetostratigraphic results for two Lower Cretaceous successions, the Liupanshan Group (Liupanshan Basin) and the Hekou Group (Longzhong Basin), NW China, and propose a minor revision for the CNS. The Liupanshan Group is a ~1300-m thick succession and comprises the alluvial-fluvial- lacustrine clastic sediments and carbonate rocks and gypsiferous mudstones. Samples from 457 levels were measured on the 2G cryogenic magnetometer after demagnetization. Six normal-polarity and five reversed-polarity magnetozones were obtained, which are correlated with the M3n to the M-'2r' of the GPTS of Gradstein (2012). The paleomagnetic data allow us to assign the Liupanshan Group to the interval from 131 Ma to 106 Ma (Barremian to Late Albian). The Hekou Group is 3700-m thick and consists of fluvial, lacustrine and deltaic sandstones, mudstones, conglomerates. 28 normal-polarity and 27 reversed-polarity magnetozones were observed from the thermal demagnetization for ~ 800 samples, and they can be reasonably correlated to the M15 thorough M-"2r" of GPTS of Gradstein (2012). This correlation yields an age control for the Hekou Group of 139-106 Ma (Valanginian- Albian). The different basal age of these two basins indicates that the Hekou Basin was initially developed prior to the Liupanshan Basin, but they stopped to develop almost at the same time. We found a short minus magnetozone in the upper part of the two groups, lying between M-'1r' and M-'2r' of the C34 of GPTS, equivalent to the reversed-polarity subzone (G2003) reported by Gilder et al. (2003) in a basalt from the Tuoyun Basin, NW China. Finally, we propose an alternative version for

Palynologically calibrated vertebrate record from North Dakota consistent with abrupt dinosaur extinction at the Cretaceous-Tertiary boundary

USGS Publications Warehouse

Pearson, D.A.; Schaefer, T.; Johnson, K.R.; Nichols, D.J.

2001-01-01

New data from 17 Cretaceous-Tertiary (K-T) boundary sections and 53 vertebrate sites in the Hell Creek and Fort Union Formations in southwestern North Dakota document a 1.76 m barren interval between the highest Cretaceous vertebrate fossils and the palynologically recognized K-T boundary. The boundary is above the formational contact at 15 localities and coincident with it at two, demonstrating that the formational contact is diachronous. Dinosaurs are common in the highest Cretaceous vertebrate samples and a partial dinosaur skeleton in the Fort Union Formation is the highest recorded Cretaceous vertebrate fossil in this area.

Petroleum geology and resources of northeastern Mexico

USGS Publications Warehouse

Peterson, James A.

1985-01-01

Petroleum deposits (primarily gas) in northeastern Mexico occur in two main basins, the Tertiary Burgos basin and the Mesozoic Sabinas basin. About 90 gas fields are present in the Burgos basin, which has undergone active exploration for the past 30-40 years. Production in this basin is from Oligocene and Eocene nearshore marine and deltaic sandstone reservoirs. Most of the fields are small to medium in size on faulted anticlinal or domal structures, some of which may be related to deep-seated salt intrusion. Cumulative production from these fields is about 4 trillion cubic feet gas and 100 million barrels condensate and oil. Since 1975, about 10 gas fields, some with large production rates, have been discovered in Cretaceous carbonate and Jurassic sandstone reservoirs in the Sabinas basin and adjacent Burro-Picachos platform areas. The Sabinas basin, which is in the early stages of exploration and development, may have potential for very large gas reserves. The Sabinas basin is oriented northwesterly with a large number of elongate northwest- or west-trending asymmetric and overturned Laramide anticlines, most of which-are faulted. Some of the structures may be related to movement of Jurassic salt or gypsum. Lower Cretaceous and in some cases Jurassic rocks are exposed in the centers of the larger anticlines, and Upper Cretaceous rocks are exposed in much of the remainder of the basin. A thick section of Upper Cretaceous clastic rocks is partly exposed in tightly folded and thrust-faulted structures of the west-east oriented, deeply subsided Parras basin, which lies south of the Sabinas basin and north of the Sierra Madre Oriental fold and thrust belt south and west of Monterrey. The sedimentary cover of Cretaceous and Jurassic rocks in the Sabinas and Parras basins ranges from about 1,550 m (5,000 ft) to 9,000 m (30,000 ft) in thickness. Upper Jurassic rocks are composed of carbonate and dark organic shaly or sandy beds underlain by an unknown thickness of Late

A Search for Soot from Global Wildfires in Central Pacific Cretaceous-Tertiary Boundary and Other Extinction and Impact Horizon Sediments

NASA Technical Reports Server (NTRS)

Wolbach, Wendy S.; Widicus, Susanna; Kyte, Frank T.

2003-01-01

Hypotheses of global wildfires following the Cretaceous-Tertiary (KT) boundary impact are supported by high concentrations of elemental carbon (3.6 mg cm-3) and soot (1.8 mg cm-2) in DSDP Site 465, which was located several thousand kilometers from potential continental sources at 65 Ma. Soot is not preserved at four other central Pacific KT localities, but this is attributed to loss during oxic diagenesis. We find no evidence for wildfires related to major impacts in the late Eocene or to Ir anomalies and extinctions in the late Cenomanian.

The Cretaceous - Paleogene paleogeography of Central Asia recorded in depositional environments of the Proto-Paratethys Sea in the Tarim Basin (Western China)

NASA Astrophysics Data System (ADS)

Yücel Kaya, Mustafa; Dupont-Nivet, Guillaume; Proust, Jean-Noel; Bougeois, Laurie; Meijer, Niels; Frieling, Joost; Fioroni, Chiara; Stoica, Marius; Roperch, Pierrick; Mamtimin, Mehmut; Aminov, Jovid

2017-04-01

The Proto-Paratethys, a shallow epicontinental sea, extended from Cretaceous to Paleogene times across Eurasia from the Mediterranean Tethys to the Tarim Basin in western China. Transgressive and regressive episodes of the Proto-Paratethys Sea have been previously recognized but their timing, extent and depositional environments remain poorly constrained especially for the Cretaceous and early Paleogene. This hampers understanding of their driving mechanisms (geodynamic and/or eustatic) and paleoclimatic consequences on regional aridification and monsoons. As part of the ERC "MAGIC" project, we report an integrated sedimentologic and stratigraphic analysis of the Proto-Paratethys from its initial Cretaceous onset to the final Paleogene retreat from multiple investigated sections in the western border of Tarim Basin. Facies associations include field observations and microfacies analyses from carbonate samples. New bio- and magneto-stratigraphic results from key intervals are also provided to testify the previously constructed regional stratigraphic framework. The previously controversial number of marine incursions in the Tarim Basin is resolved to 6 (3 Cretaceous and 3 Paleogene) also recognized in the neighboring Tajik and Turan Basins to the west and the present-day Alai Valley. The eastward extent of these marine incursions varied through time with a maximum extent during late Paleocene - early Eocene. The first marine incursion is a Cenomanian transgression recorded in the marls and calcareous mudstones of the Kukebai Formation. The next two are Coniacian and Campanian transgressions recognized in the carbonate units of the Yigeziya Formation. The first Paleogene incursion is characterized by thick evaporites of the Paleocene Aertashi Formation overlain by the marine shales of the Lower Qimugen Formation. The latter represents the maximum extent and the deepest environments of the Proto-Paratethys. The marine Kalatar limestones and silty shales of the Wulagen

Cretaceous anuran and dinosaur footprints from the Patuxent Formation of Virginia

USGS Publications Warehouse

Weems, R.E.; Bachman, J.M.

1997-01-01

Footprints of an anuran (gen. et sp. indet.), a theropod dinosaur (Megalosauropus sp.), and an ornithopod dinosaur (Amblydactylus sp.) have been recovered from the Lower Cretaceous Patuxent Formation in Stafford County, Virginia. These footprints are the first record of terrestrial vertebrates from Cretaceous strata in Virginia, and their discovery suggests that the scarcity of bones and teeth in the Patuxent probably is an artifact of preservation. The anuran trackway provides the oldest known direct evidence for hopping locomotion among these amphibians.

Integrated foraminiferal biostratigraphy and chemostratigraphy of the querecual formation (Cretaceous), Eastern Venezuela

USGS Publications Warehouse

Crespo De Cabrera, S.; Sliter, W.V.; Jarvis, I.

1999-01-01

An integrated foraminiferal biostratigraphy and chemostratigraphy is presented for the Lower to Upper Cretaceous Querecual Formation exposed on Chimana Grande Island, Eastern Venezuela. The formation consists of >450 m alternating foraminiferal and organic-rich carbonates and laminated mudrocks, and is considered the main hydrocarbon source rock for the eastern Venezuela Basin. Biostratigraphic resolution within the Querecual Formation is poor, due to a paucity of keeled planktonic foraminifera and impoverished benthic faunas. Deposition occurred in a bathyal environment, with dysaerobic or anoxic bottom waters resulting from high rates of surface productivity associated with an upwelling environment. Biostratigraphic evidence indicates that the Querecual Formation ranges from the upper Albian Rotalipora ticinensis Zone to the Santonian Dicarinella asymetrica Zone. Iron and Al contents fall through the Albian-Cenomanian indicating a progressive decrease in the detrital supply, driven by rising eustatic sea level. A Ca profile demonstrates variations in carbonate production and dissolution. High total organic carbon (TOC) intervals occur in the upper Albian to mid-Cenomanian and Turonian, and high Ba/Al and Si/Al ratios characterize mid-Cenomanian and younger sediments. Variations in these elements primarily reflect changes in marine productivity, but are also affected by diagenetic processes. A stable carbon isotope curve established from analysis of organic matter (??13Corg) correlates well with published ??13C curves for carbonates from England and Italy. The Cenomanian/Turonian boundary cannot be identified using planktonic foraminifera, because key taxa are absent, but the base of the Turonian is clearly indicated by a sharp fall in ??13C immediately above a major positive excursion. The bottom of the Coniacian is placed below a ??13C minimum, towards the base of the Dicarinella concavata Zone. Combined with the foraminiferal data, the isotopic data enable much

An enhanced sensing platform for ultrasensitive impedimetric detection of target genes based on ordered FePt nanoparticles decorated carbon nanotubes.

PubMed

Zhang, Wei; Zong, Peisong; Zheng, Xiuwen; Wang, Libin

2013-04-15

We demonstrate a novel high-performance DNA hybridization biosensor with a carbon nanotubes (CNTs)-based nanocomposite membrane as the enhanced sensing platform. The platform was constructed by homogenously distributing ordered FePt nanoparticles (NPs) onto the CNTs matrix. The surface structure and electrochemical performance of the FePt/CNTs nanocomposite membrane were systematically investigated. Such a nanostructured composite membrane platform could combine with the advantages of FePt NPs and CNTs, greatly facilitate the electron-transfer process and the sensing behavior for DNA detection, leading to excellent sensitivity and selectivity. The complementary target genes from acute promyelocytic leukemia could be quantified in a wide range of 1.0×10⁻¹² mol/L to 1.0×10⁻⁶ mol/L using electrochemical impedance spectroscopy, and the detection limit was 2.1×10⁻¹³ mol/L under the optimal conditions. In addition, the DNA electrochemical biosensor was highly selective to discriminate single-base or double-base mismatched sequences. Copyright © 2012 Elsevier B.V. All rights reserved.

Major wildfires at the Cretaceous-Tertiary boundary

NASA Technical Reports Server (NTRS)

Gilmour, Iain; Wolbach, Wendy S.; Anders, Edward

1989-01-01

K-T boundary (KTB) clays from five sites are enriched in soot and charcoal by factors of 100-1000 over Cretaceous levels, apparently due to a global fire. The soot profile nearly coincides with the Ir profile, implying that the fire was triggered by the impact. Much or all of the fuel was biomass, as indicated by the presence of retene and by the C isotopic composition. The amount of elemental C at the KTB (0.012 g/sq cm) is very large, and requires either that most of the Cretaceous biomass burned down or that the soot yield was higher than in small fires. At undisturbed sites, soot correlates tightly with Ir, As, Sb, and Zn. Apparently soot and Ir-bearing ejecta particles coagulated in the stratosphere and then scavenged additional chalcophiles from the hydrosphere. In view of this coagulation, the K-T fire would only slightly prolong the period of darkness and cold caused by impact ejecta.

A Ceratopsian Dinosaur from the Lower Cretaceous of Western North America, and the Biogeography of Neoceratopsia

PubMed Central

Farke, Andrew A.; Maxwell, W. Desmond; Cifelli, Richard L.; Wedel, Mathew J.

2014-01-01

The fossil record for neoceratopsian (horned) dinosaurs in the Lower Cretaceous of North America primarily comprises isolated teeth and postcrania of limited taxonomic resolution, hampering previous efforts to reconstruct the early evolution of this group in North America. An associated cranium and lower jaw from the Cloverly Formation (?middle–late Albian, between 104 and 109 million years old) of southern Montana is designated as the holotype for Aquilops americanus gen. et sp. nov. Aquilops americanus is distinguished by several autapomorphies, including a strongly hooked rostral bone with a midline boss and an elongate and sharply pointed antorbital fossa. The skull in the only known specimen is comparatively small, measuring 84 mm between the tips of the rostral and jugal. The taxon is interpreted as a basal neoceratopsian closely related to Early Cretaceous Asian taxa, such as Liaoceratops and Auroraceratops. Biogeographically, A. americanus probably originated via a dispersal from Asia into North America; the exact route of this dispersal is ambiguous, although a Beringian rather than European route seems more likely in light of the absence of ceratopsians in the Early Cretaceous of Europe. Other amniote clades show similar biogeographic patterns, supporting an intercontinental migratory event between Asia and North America during the late Early Cretaceous. The temporal and geographic distribution of Upper Cretaceous neoceratopsians (leptoceratopsids and ceratopsoids) suggests at least intermittent connections between North America and Asia through the early Late Cretaceous, likely followed by an interval of isolation and finally reconnection during the latest Cretaceous. PMID:25494182

Petroleum geology of Cretaceous-Tertiary rift basins in Niger, Chad, and Central African Republic

DOE Office of Scientific and Technical Information (OSTI.GOV)

Genik, G.J.

1993-08-01

This overview of the petroleum geology of rift basins in Niger, Chad, and Central African Republic (CAR) is based on exploration work by Exxon and partners in the years 1969-1991. The work included 50,000 km of modern reflection seismic, 53 exploration wells, 1,000,000 km[sup 2] of aeromagnetic coverage, and about 10,500 km of gravity profiles. The results outline ten Cretaceous and Tertiary rift basins, which constitute a major part of the West and Central African rift system (WCARS). The rift basins derive from a multiphased geologic history dating from the Pan-African (approximately 750-550 Ma) to the Holocene. WCARS in themore » study area is divided into the West African rift subsystem (WAS) and the Central African rift subsystem (WAS) and the Central African rift subsystem (CAS). WAS basins in Niger and Chad are chiefly extensional, and are filled by up to 13,000 m of Lower Cretaceous to Holocene continental and marine clastics. The basins contain five oil (19-43[degrees]API) and two oil and gas accumulations in Upper Cretaceous and Eocene sandstone reservoirs. The hydrocarbons are sourced and sealed by Upper Cretaceous and Eocene marine and lacustrine shales. The most common structural styles and hydrocarbon traps usually are associated with normal fault blocks. CAS rift basins in Chad and CAR are extensional and transtensional, and are filled by up to 7500 m of chiefly Lower Cretaceous continental clastics. The basins contain eight oil (15-39[degrees]API) and one oil and gas discovery in Lower and Upper Cretaceous sandstone reservoirs. The hydrocarbons are sourced by Lower Cretaceous shales and sealed by interbedded lacustrine and flood-plain shales. Structural styles range from simple fault blocks through complex flower structures. The main hydrocarbon traps are in contractional anticlines. Geological conditions favor the discovery of potentially commercial volumes of oil in WCARS basins, of Niger, Chad and CAR. 108 refs., 24 figs., 4 tabs.« less

Petrological, Magnetic and Geochemical Characterization of Cretaceous-Paleogene Boundary El Mimbral and La Lajilla Sections, Northeastern Mexico

NASA Astrophysics Data System (ADS)

Ortega Nieto, A.; Fucugauchi, J. U.; Perez-Cruz, L. L.

2009-12-01

We present initial results of a petrological, magnetic and geochemical study of El Mimbral and La Lajilla sections that span the Cretaceous-Paleogene (K-Pg) boundary. K-Pg sections in northeastern Mexico have been intensively studied in past years, mainly because of their relationship to the Chicxulub crater in the Yucatan platform and for investigating the nature, origin, stratigraphic relations and age of the impact ejecta deposits. The K-Pg boundary is preserved in between hemipelagic marls and limestones of the Mendez (Maastrichtian) and Velasco (Paleocene) formations. The two sections are situated about 1000 km away from Chicxulub and K-Pg deposits are part of the proximal ejecta and the complex channelized siliciclastic units. We had separated the siliciclastic units into two parts, with a basal coarse poorly graded spherulitic bed some 0.2 to 1 m thick and a second part with several sandstone siltstone beds that have been grouped in various ways in previous studies. In the field, samples were collected across stratigraphic profiles for rock magnetic, petrological and geochemical analyses. Using field observations and analytical data, detailed columns for the two localities are prepared. Rock magnetic measurements include susceptibility, remanent and isothermal magnetization and remanent coercivity. Magnetic hysteresis loops and IRM and back-field demagnetization were measured for samples of spherulitic bed. X-ray fluorescence analyses on whole rock were complemented with previous data obtained for the Mimbral section by atomic absorption spectrometry and inductively coupled plasma mass spectrometry (including platinum group elements). Further detailed analysis concentrated in the ejecta material. The spherulitic bed is characterized by Fe-Mg rich chlorite and Si-Al-K rich glass spherules and carbonate accretionary lapilli spherules. The silicic component spherules are altered to calcite or chlorite-smectite, with some retaining glass cores. Spherules have

Systems metabolic engineering of Corynebacterium glutamicum for the production of the carbon-5 platform chemicals 5-aminovalerate and glutarate.

PubMed

Rohles, Christina Maria; Gießelmann, Gideon; Kohlstedt, Michael; Wittmann, Christoph; Becker, Judith

2016-09-13

The steadily growing world population and our ever luxurious life style, along with the simultaneously decreasing fossil resources has confronted modern society with the issue and need of finding renewable routes to accommodate for our demands. Shifting the production pipeline from raw oil to biomass requires efficient processes for numerous platform chemicals being produced with high yield, high titer and high productivity. In the present work, we established a de novo bio-based production process for the two carbon-5 platform chemicals 5-aminovalerate and glutarate on basis of the lysine-hyperproducing strain Corynebacterium glutamicum LYS-12. Upon heterologous implementation of the Pseudomonas putida genes davA, encoding 5-aminovaleramidase and davB, encoding lysine monooxygenase, 5-aminovalerate production was established. Related to the presence of endogenous genes coding for 5-aminovalerate transaminase (gabT) and glutarate semialdehyde dehydrogenase, 5-aminovalerate was partially converted to glutarate. Moreover, residual L-lysine was secreted as by-product. The issue of by-product formation was then addressed by deletion of the lysE gene, encoding the L-lysine exporter. Additionally, a putative gabT gene was deleted to enhance 5-aminovalerate production. To fully exploit the performance of the optimized strain, fed-batch fermentation was carried out producing 28 g L(-1) 5-aminovalerate with a maximal space-time yield of 0.9 g L(-1) h(-1). The present study describes the construction of a recombinant microbial cell factory for the production of carbon-5 platform chemicals. Beyond a basic proof-of-concept, we were able to specifically increase the production flux of 5-aminovalerate thereby generating a strain with excellent production performance. Additional improvement can be expected by removal of remaining by-product formation and bottlenecks, associated to the terminal pathway, to generate a strain being applicable as centerpiece for a bio

Warm tropical ocean surface and global anoxia during the mid-Cretaceous period.

PubMed

Wilson, P A; Norris, R D

2001-07-26

The middle of the Cretaceous period (about 120 to 80 Myr ago) was a time of unusually warm polar temperatures, repeated reef-drowning in the tropics and a series of oceanic anoxic events (OAEs) that promoted both the widespread deposition of organic-carbon-rich marine sediments and high biological turnover. The cause of the warm temperatures is unproven but widely attributed to high levels of atmospheric greenhouse gases such as carbon dioxide. In contrast, there is no consensus on the climatic causes and effects of the OAEs, with both high biological productivity and ocean 'stagnation' being invoked as the cause of ocean anoxia. Here we show, using stable isotope records from multiple species of well-preserved foraminifera, that the thermal structure of surface waters in the western tropical Atlantic Ocean underwent pronounced variability about 100 Myr ago, with maximum sea surface temperatures 3-5 degrees C warmer than today. This variability culminated in a collapse of upper-ocean stratification during OAE-1d (the 'Breistroffer' event), a globally significant period of organic-carbon burial that we show to have fundamental, stratigraphically valuable, geochemical similarities to the main OAEs of the Mesozoic era. Our records are consistent with greenhouse forcing being responsible for the warm temperatures, but are inconsistent both with explanations for OAEs based on ocean stagnation, and with the traditional view (reviewed in ref. 12) that past warm periods were more stable than today's climate.

From D-sorbitol to five-membered bis(cyclo-carbonate) as a platform molecule for the synthesis of different original biobased chemicals and polymers.

PubMed

Furtwengler, Pierre; Avérous, Luc

2018-06-14

Bis(cyclo-carbonate) was successfully synthesized from D-sorbitol (Sorb-BisCC) through an environmentally friendly process with dimethyl carbonate (DMC) as a reactant. In agreement with green chemistry principles, solvent free reactions were catalyzed and took place at low temperature. The reaction yield was increased until 50%, with the use of 1.3.5-triazabicyclo[4.4.0]dec-5-ene as catalyst and a continuous DMC feed to limit the side-reactions or the loss of reactant by azeotropic flux with a reactional subsidiary product. The obtained Sorb-BisCC is a remarkable platform molecule which could compete with others polycyclic platform molecules (isosorbide). Sorb-BisCC can be e.g., used to synthesize different chemicals such as short and long polyols, or novel biobased non-isocyanate polyurethanes (NIPU). Two Sorb-BisCC molecules have been coupled to obtain novel cyclic diols with pendant side chains. Polyether polyols were also obtained by anionic ring opening polymerization. According to the synthesis conditions, these synthetized polyether polyols range from partially to highly cross-linked materials. Finally, NIPU were synthesized with short and biobased fatty diamines. These different modifications and synthesis highlight the versatility of the Sorb-BisCC and demonstrated its high potential as building block. Sorb-BisCC can be considered as a platform molecule to open the way to different original and biobased chemical architectures.

A new Early Cretaceous eutherian mammal from the Sasayama Group, Hyogo, Japan

PubMed Central

Kusuhashi, Nao; Tsutsumi, Yukiyasu; Saegusa, Haruo; Horie, Kenji; Ikeda, Tadahiro; Yokoyama, Kazumi; Shiraishi, Kazuyuki

2013-01-01

We here describe a new Early Cretaceous (early Albian) eutherian mammal, Sasayamamylos kawaii gen. et sp. nov., from the ‘Lower Formation’ of the Sasayama Group, Hyogo Prefecture, Japan. Sasayamamylos kawaii is characterized by a robust dentary, a distinct angle on the ventral margin of the dentary at the posterior end of the mandibular symphysis, a lower dental formula of 3–4 : 1 : 4 : 3, a robust lower canine, a non-molariform lower ultimate premolar, and a secondarily reduced entoconid on the molars. To date, S. kawaii is the earliest known eutherian mammal possessing only four premolars, which demonstrates that the reduction in the premolar count in eutherians started in the late Early Cretaceous. The occurrence of S. kawaii implies that the relatively rapid diversification of eutherians in the mid-Cretaceous had already started by the early Albian. PMID:23536594

A new Early Cretaceous eutherian mammal from the Sasayama Group, Hyogo, Japan.

PubMed

Kusuhashi, Nao; Tsutsumi, Yukiyasu; Saegusa, Haruo; Horie, Kenji; Ikeda, Tadahiro; Yokoyama, Kazumi; Shiraishi, Kazuyuki

2013-05-22

We here describe a new Early Cretaceous (early Albian) eutherian mammal, Sasayamamylos kawaii gen. et sp. nov., from the 'Lower Formation' of the Sasayama Group, Hyogo Prefecture, Japan. Sasayamamylos kawaii is characterized by a robust dentary, a distinct angle on the ventral margin of the dentary at the posterior end of the mandibular symphysis, a lower dental formula of 3-4 : 1 : 4 : 3, a robust lower canine, a non-molariform lower ultimate premolar, and a secondarily reduced entoconid on the molars. To date, S. kawaii is the earliest known eutherian mammal possessing only four premolars, which demonstrates that the reduction in the premolar count in eutherians started in the late Early Cretaceous. The occurrence of S. kawaii implies that the relatively rapid diversification of eutherians in the mid-Cretaceous had already started by the early Albian.

Extreme adaptations for probable visual courtship behaviour in a Cretaceous dancing damselfly.

PubMed

Zheng, Daran; Nel, André; Jarzembowski, Edmund A; Chang, Su-Chin; Zhang, Haichun; Xia, Fangyuan; Liu, Haoying; Wang, Bo

2017-03-20

Courtship behaviours, frequent among modern insects, have left extremely rare fossil traces. None are known previously for fossil odonatans. Fossil traces of such behaviours are better known among the vertebrates, e.g. the hypertelic antlers of the Pleistocene giant deer Megaloceros giganteus. Here we describe spectacular extremely expanded, pod-like tibiae in males of a platycnemidid damselfly from mid-Cretaceous Burmese amber. Such structures in modern damselflies, help to fend off other suitors as well as attract mating females, increasing the chances of successful mating. Modern Platycnemidinae and Chlorocyphidae convergently acquired similar but less developed structures. The new findings provide suggestive evidence of damselfly courtship behaviour as far back as the mid-Cretaceous. These data show an unexpected morphological disparity in dancing damselfly leg structure, and shed new light on mechanisms of sexual selection involving intra- and intersex reproductive competition during the Cretaceous.

Middle Eocene seagrass facies from Apennine carbonate platforms (Italy)

NASA Astrophysics Data System (ADS)

Tomassetti, Laura; Benedetti, Andrea; Brandano, Marco

2016-04-01

Two stratigraphic sections located in the Latium-Abruzzi (Monte Porchio, Central Apennines, Central Italy) and in the Apulian carbonate platform (S. Cesarea-Torre Tiggiano, Salento, Southern Italy) were measured and sampled to document the sedimentological characteristic and the faunistic assemblages of Middle Eocene seagrass deposits. The faunistic assemblages are dominated by porcellaneous foraminifera Orbitolites, Alveolina, Idalina, Spiroloculina, Quinqueloculina, Triloculina and abundant hooked-shaped gypsinids, associated with hooked red algae and green algae Halimeda. Fabiania, rotaliids and textulariids as well as nummulitids are subordinated. The samples were assigned to Lutetian (SBZ13-16) according to the occurrence of Nummulites cf. lehneri, Alveolina ex. gr. elliptica, Idalina berthelini, Orbitolites complanatus, Slovenites decastroi and Medocia blayensis. At Santa Cesarea reticulate nummulites occur in association with Alveolina spp. and Halkyardia minima marking the lower Bartonian (SBZ17). Three main facies associations have been recognised: I) larger porcellaneous foraminiferal grainstones with orbitolitids and alveolinids deposited into high-energy shallow-water settings influenced by wave processes that reworked the sediments associated with a seagrass; II) grainstone to packstone with small porcellaneous foraminifera and abundant permanently-attached gypsinids deposited in a more protected (e.g., small embayment) in situ vegetated environment; III) bioclastic packstone with parautochthonous material reworked from the seagrass by rip currents and accumulated into rip channels in a slightly deeper environment. The biotic assemblages suggest that the depositional environment is consistent with tropical to subtropical vegetated environments within oligotrophic conditions.

Chapter 4: The Cretaceous-Lower Tertiary Composite Total Petroleum System, Wind River Basin, Wyoming

USGS Publications Warehouse

Johnson, R.C.; Finn, Thomas M.; Kirschbaum, Mark A.; Roberts, Stephen B.; Roberts, Laura N.R.; Cook, Troy; Taylor, David J.

2007-01-01

The Cretaceous-Lower Tertiary Composite Total Petroleum System (TPS) of the Wind River Basin Province includes all strata from the base of the Lower Cretaceous Cloverly Formation to the base of the Waltman Shale Member of the Paleocene age Fort Union Formation and, where the Waltman is absent, includes strata as young as the Eocene Wind River Formation. Locally, Cretaceous-sourced gas migrated into strata as old as the Mississippian Madison Limestone, and in these areas the TPS extends stratigraphically downward to include these reservoirs. The extensive vertical migration of gases in highly fractured areas of the Wind River Basin led to the commingling of gases from several Upper Cretaceous and lower Tertiary sources, thus only two petroleum systems are recognized in these rocks, the Cretaceous-Lower Tertiary Composite TPS, the subject of this report, and the Waltman Shale TPS described by Roberts and others (Chapter 5, this CD-ROM). The Cretaceous-lower Tertiary Composite TPS was subdivided into (1) seven continuous gas assessment units (AU): (a) Frontier-Muddy Continuous Gas AU, (b) Cody Sandstone Continuous Gas AU, (c) Mesaverde--Meeteetse Sandstone Gas AU, (d) Lance-Fort Union Sandstone Gas AU, (e) Mesaverde Coalbed Gas AU, (f) Meeteetse Coalbed Gas AU, and (g) Fort Union Coalbed Gas AU; (2) one continuous oil assessement unit--- Cody Fractured Shale Continuous Oil AU; and (3) one conventional assessment Unit--- Cretaceous-Tertiary Conventional Oil and Gas AU. Estimates of undiscovered resources having the potential for additions to reserves were made for all but the Cody Fractured Shale Continuous Oil AU, which is considered hypothetical and was not quantitively assessed. The mean estimate of the total oil is 41.99 million barrels, mean estimate of gas is 2.39 trillion cubic feet, and mean estimate of natural gas liquids is 20.55 million barrels. For gas, 480.66 billion cubic feet (BCFG) is estimated for the Frontier-Muddy Continuous Gas AU, 115.34 BCFG for

Morphologically Specialized Termite Castes and Advanced Sociality in the Early Cretaceous.

PubMed

Engel, Michael S; Barden, Phillip; Riccio, Mark L; Grimaldi, David A

2016-02-22

A hallmark of animals that are eusocial, or those with advanced sociality, is reproductive specialization into worker and queen castes. In the most derived societies, these divisions are essentially fixed and in some arthropods, include further specialization--a tripartite system with a soldier caste that defends the colony. Eusociality has originated numerous times among insects but is believed to have appeared first in the termites (Isoptera), in the Early Cretaceous. However, all termites known from the Cretaceous have, until now, only been winged reproductives (alates and dealates); the earliest soldiers and definitive workers were known from just the Miocene (ca. 17-20 million years ago [mya]). Here, we report six termite species preserved in Early Cretaceous (ca. 100 mya) amber from Myanmar, one described as Krishnatermes yoddha gen. et sp. nov., comprising the worker/pseudergate, winged reproductive, and soldier, and a second species, Gigantotermes rex gen. et sp. nov., based on one of the largest soldier termites yet known. Phylogenetic analysis indicates that Krishnatermes are in the basal "Meiatermes-grade" of Cretaceous termites. Workers/pseudergates of another four species are briefly described, but not named. One of these workers/pseudergates reveals that ants--the most serious enemies of modern termites--lived in close proximity to termites in the Burmese paleofauna. These discoveries demonstrate the Mesozoic antiquity of specialized termite caste systems and corroborate that among all social species, termites probably had the original societies. Copyright © 2016 Elsevier Ltd. All rights reserved.

A Feathered Dinosaur Tail with Primitive Plumage Trapped in Mid-Cretaceous Amber.

PubMed

Xing, Lida; McKellar, Ryan C; Xu, Xing; Li, Gang; Bai, Ming; Persons, W Scott; Miyashita, Tetsuto; Benton, Michael J; Zhang, Jianping; Wolfe, Alexander P; Yi, Qiru; Tseng, Kuowei; Ran, Hao; Currie, Philip J

2016-12-19

In the two decades since the discovery of feathered dinosaurs [1-3], the range of plumage known from non-avialan theropods has expanded significantly, confirming several features predicted by developmentally informed models of feather evolution [4-10]. However, three-dimensional feather morphology and evolutionary patterns remain difficult to interpret, due to compression in sedimentary rocks [9, 11]. Recent discoveries in Cretaceous amber from Canada, France, Japan, Lebanon, Myanmar, and the United States [12-18] reveal much finer levels of structural detail, but taxonomic placement is uncertain because plumage is rarely associated with identifiable skeletal material [14]. Here we describe the feathered tail of a non-avialan theropod preserved in mid-Cretaceous (∼99 Ma) amber from Kachin State, Myanmar [17], with plumage structure that directly informs the evolutionary developmental pathway of feathers. This specimen provides an opportunity to document pristine feathers in direct association with a putative juvenile coelurosaur, preserving fine morphological details, including the spatial arrangement of follicles and feathers on the body, and micrometer-scale features of the plumage. Many feathers exhibit a short, slender rachis with alternating barbs and a uniform series of contiguous barbules, supporting the developmental hypothesis that barbs already possessed barbules when they fused to form the rachis [19]. Beneath the feathers, carbonized soft tissues offer a glimpse of preservational potential and history for the inclusion; abundant Fe 2+ suggests that vestiges of primary hemoglobin and ferritin remain trapped within the tail. The new finding highlights the unique preservation potential of amber for understanding the morphology and evolution of coelurosaurian integumentary structures. Copyright © 2016 Elsevier Ltd. All rights reserved.

Integrating palaeoenvironmental and climate cyclicities - Optimizing the stratigraphic framework in the non-marine Lower Cretaceous

NASA Astrophysics Data System (ADS)

Sames, Benjamin

2015-04-01

Studies on changing paleoenvironments and climate cycles in non-marine archives of the Cretaceous greenhouse earth are hitherto rare, primarily a result of the lack of high-resolution stratigraphy and correlations to the marine record. On the other hand, recent refinements of the geological time scale have made major advances for the Cretaceous to yield a resolution comparable to that of younger Earth history. In the Cretaceous marine record is now possible to correlate and date short-term sea-level records and their possible relation to climate and/or tectonic events with appropriate resolution. Correlation in the non-marine realm ('continental' aquatic) has long been fraught with considerable problems and limitations, especially on supraregional (i.e., inter-basinal) to global scales, thus often hampering serious attempts at dating and chronological linking of events documented by the respective deposits - let alone appropriate correlation to marine successions. A new interdisciplinary project and multi-proxy study funded by the Austrian Science Fund (FWF) uses the Lower Cretaceous European record (English Wealden) as a test site for the integration of ostracod biostratigraphy and assemblage changes, and cyclostratigraphy (orbitally/climate driven cycles). Ostracods (microcrustaceans with a calcified shell) are the most useful biostratigraphical and palaeoenvironmental tool in Lower Cretaceous non-marine sequences. During the past two decades, research progress in late Mesozoic non-marine ostracods led to their extended applicability, whereas their wide dispersal ability has become a key conside-ration in their supraregional (inter-basinal to global) biostratigraphical utility. The integrative methodology applied in this project, targets the correlation of the ostracod faunal composition change with the variation of geochemical and sedimentological parameters through time and inferences on controlling (palaeoenvironmental) factors and their regulating mechanisms

Sediments of the Dry Tortugas, south Florida, USA: Facies distribution on a ramp-like isolated carbonate platform

NASA Astrophysics Data System (ADS)

Gischler, Eberhard; Isaack, Anja; Hudson, J. Harold

2017-04-01

Four sedimentary facies may be delineated based on quantitative analysis of texture and composition of modern surface sediments on the Dry Tortugas carbonate platform. These include (1) mollusk-Halimeda wackestone, (2) mollusk packstone-to-grainstone, (3) coralgal-Halimeda grainstone, and (4) coralgal grainstone. Even though the Tortugas platform is characterized by an open circulation due to deep, broad marginal channels and a lack of a continuous surface-breaking marginal reef, facies are not distributed at random and show bathymetrical zonation. Also, facies appear to cover wide belts rather than forming a mosaic. Mollusk-Halimeda wackestone occurs in protected platform interior areas ca. 10-18 m deep. Mollusk packstone-to-grainstone occurs in more open platform interior settings adjacent to channels and in deeper outer reef areas of 14-25 m water depth. Coralgal-Halimeda grainstone is found on shallow marginal shoals (1-11 m deep), and coralgal grainstone on the somewhat deeper (3-16 m), seaward edges of these shoals. However, there is bathymetrical overlap of facies in intermediate depths of ca. 5-17 m. This limitation has implications for the interpretation of the fossil record, because changes in water depth are commonly thought to be reflected in facies changes, e.g., in sequence stratigraphy. Comparison with previous sediment studies of the 1930s, 1960s, and 1970s in the area exhibit a decrease in coral fragments and increases in coralline algal and mollusk shell fragments. These observations might be a result of environmental changes such as coral decline and die-outs during temperature events, disease, and the increase in macroalgae (due to the ecological extinction of the echinoid Diadema). The results suggest that more long-term studies are needed that further explore the influence of environmental change on reef sediment composition. Dry Tortugas surface sediments consist of lower portions of Halimeda plates and mollusk shell fragments and higher

The Cretaceous glauconitic sandstones of Abu Tartur, Egypt

NASA Astrophysics Data System (ADS)

Pestitschek, Brigitte; Gier, Susanne; Essa, Mahmoud; Kurzweil, Johannes

2010-05-01

The Abu Tartur mine is located in the Western Desert of Egypt, 50 km west of El Kharga City. Geologically, the Abu Tartur plateau is built by a sequence of Upper Cretaceous (Campanian - Maastrichtian) phosphorites, black shales and glauconitic sandstones. The phosphate deposits are of great economic importance and have been mined since their discovery in 1967. Outcrop sections were measured, sampled, sedimentologically characterized and described. One specific glaucony layer was investigated mineralogically and chemically in detail and compared to a subsurface sample from the mine. Two depositional regimes can be interpreted based on sedimentary architecture and structures: 1) a deeper-water hemipelagic environment, where phosphorites and organic carbon-rich shales were deposited and 2) a shallower, prograding higher energy shelf environment with glauconies. From a sequence stratigraphic perspective 1) was deposited during the transgressive systems tract and the early highstand while 2) was deposited during the remaining highstand and a lowstand prograding wedge (Glenn & Arthur, 1990). Petrographic and SEM investigations show that the glaucony grains are of authochtonous origin. XRF, EMPA and thin-section analyses show that the glaucony grains from the outcrop differ significantly in their chemical composition, morphology and color from the grains of the mine sample. The fresh glauconies are enriched in Fe2O3 and K2O compared to the surface samples. XRD analyses of the clay fraction of the six outcrop samples and the mine sample show that the grains consist of illite(glauconite)/smectite mixed-layers, with more illite layers (80 %) in the mine sample. The charge distribution diagram muscovite-pyrophyllite-celadonite shows a clear trend from smectitic glaucony to illitic glaucony, the mine sample plots exactly in the field for glauconites. All these features indicate that the surface samples are strongly altered by weathering and that glauconite progressively

A mid-Cretaceous Eccrinales infesting a primitive wasp in Myanmar amber.

PubMed

Poinar, George

2016-12-01

A mid-Cretaceous Eccrinales in Myanmar amber is described as Paleocadus burmiticus gen. et sp. nov. in the family Eccrinaceae. The fossil is represented by two types of sporangiospores formed on different thalli protruding from the anus of a primitive wasp, with secondary infestation spores multinucleate and thin walled. Its presence establishes the Eccrinales in the mid-Cretaceous and shows that at that time, lineages of this group parasitized wasps, an association unknown with extant members of the Order. Copyright © 2016 British Mycological Society. Published by Elsevier Ltd. All rights reserved.

Dinosaur trackways from the early Late Cretaceous of western Cameroon

NASA Astrophysics Data System (ADS)

Martin, Jeremy E.; Menkem, Elie Fosso; Djomeni, Adrien; Fowe, Paul Gustave; Ntamak-Nida, Marie-Joseph

2017-10-01

Dinosaur trackways have rarely been reported in Cretaceous strata across the African continent. To the exception of ichnological occurrences in Morocco, Tunisia, Niger and Cameroon, our knowledge on the composition of Cretaceous dinosaur faunas mostly relies on skeletal evidence. For the first time, we document several dinosaur trackways from the Cretaceous of the Mamfe Basin in western Cameroon. Small and medium-size tridactyl footprints as well as numerous large circular footprints are present on a single horizon showing mudcracks and ripple marks. The age of the locality is considered Cenomanian-Turonian and if confirmed, this ichnological assemblage could be younger than the dinosaur footprints reported from northern Cameroon, and coeval with or younger than skeletal remains reported from the Saharan region. These trackways were left in an adjacent subsiding basin along the southern shore of the Benue Trough during a time of high-sea stand when the Trans-Saharan Seaway was already disconnecting West Africa from the rest of the continent. We predict that other similar track sites may be occurring along the margin of the Benue Trough and may eventually permit to test hypotheses related to provincialism among African dinosaur faunas.

Stratigraphic framework and evolution of the Cretaceous continental sequences of the Bauru, Sanfranciscana, and Parecis basins, Brazil

NASA Astrophysics Data System (ADS)

Batezelli, Alessandro; Ladeira, Francisco Sergio Bernardes

2016-01-01

With the breakup of the supercontinent Gondwana, the South American Plate has undergone an intense process of tectonic restructuring that led to the genesis of the interior basins that encompassed continental sedimentary sequences. The Brazilian Bauru, Sanfranciscana and Parecis basins during Late Cretaceous have had their evolution linked to this process of structuring and therefore have very similar sedimentary characteristics. The purpose of this study is to establish a detailed understanding of alluvial sedimentary processes and architecture within a stratigraphic sequence framework using the concept of the stratigraphic base level or the ratio between the accommodation space and sediment supply. The integration of the stratigraphic and facies data contributed to defining the stratigraphic architecture of the Bauru, Sanfranciscana and Parecis Basins, supporting a model for continental sequences that depicts qualitative changes in the sedimentation rate (S) and accommodation space (A) that occurred during the Cretaceous. This study discusses the origin of the unconformity surfaces (K-0, K-1 and K-1A) that separate Sequences 1, 2A and 2B and the sedimentary characteristics of the Bauru, Sanfranciscana and Parecis Basins from the Aptian to the Maastrichtian, comparing the results with other Cretaceous Brazilian basins. The lower Cretaceous Sequence 1 (Caiuá and Areado groups) is interpreted as a low-accommodation systems tract compound by fluvial and aeolian systems. The upper Cretaceous lacustrine, braided river-dominated alluvial fan and aeolian systems display characteristics of the evolution from high-to low-accommodation systems tracts (Sequences 2A and 2B). Unconformity K-0 is related to the origin of the Bauru Basin itself in the Early Cretaceous. In Sanfranciscana and Parecis basins, the unconformity K-0 marks the contact between aeolian deposits from Lower Cretaceous and Upper Cretaceous alluvial systems (Sequences 1 and 2). Unconformity K-1, which was

Paleaostress/strain study and its implications for the geodynamic history of the Jabal Akhdar Dome (Oman)

NASA Astrophysics Data System (ADS)

Scharf, Andreas; Amrouch, Khalid; Mattern, Frank

2016-04-01

Field observations, including oolite-, styolite, fracture analyses combined with laboratory measurements using calcite twin analysis show a ductile-to-brittle multiple-phase deformation history of the Arabian carbonate platform, ranging from Late Cretaceous to Neogene times. The Arabian carbonate platform, belonging to a passive continental margin since the Late Permian, was the site of the obduction of Tethyan oceanic lithosphere (Semail Ophiolite) during the Late Cretaceous, caused by the northward drift of Africa (Hanna, 1995). After or during the obduction, large parts of the entire nape pile composed of the Arabian platform and the Hawasina/Semail nappes, where folded and exhumed. This led to the exhumation of the Jabal Akhdar Dome. Our oolite samples from the Jabal Akhdar Dome and from below the ophiolite thrust reveal the strain ellipsoid related to the obduction. This strain ellipsoid shows components of pure and simple shear. In the latter case the longest axes of the strain ellipsoid are parallelly oriented to the direction of obduction (NE to SW), which is in good agreement with the direction of obduction as depicted by Hacker et al. (1996) for the study area. The pure-shear component (flattening) is interpreted to be a result of the overburden of the up to 7 km thick oceanic lithosphere. The oolites that are located approximately 200 m below the ophiolite thrust contact provide evidence for ductile deformation during the Late Cretaceous. These results are compared with strain and stress tensors obtained from styolites, calcite twins and fracture analyses, derived from the uppermost part of the Arabian platform of the Jabal Akhdar Dome. Our results show a complex and detailed structural deformation of the post-obduction history of the Jabal Akhdar Dome, including its folding and exhumation. Hanna, S. (1995) Field guide to the Geology of Oman. Ruwi (Historical Association of Oman. 178 pp. Hacker, B.R., Mosenfelder, J.L. & Gnos, E. (1996) Rapid emplacement

The Early Cretaceous Sulfur Isotope Record: New Data, Revised Ages, and Updated Modeling

NASA Astrophysics Data System (ADS)

Kristall, B.; Hurtgen, M.; Sageman, B. B.; Jacobson, A. D.

2015-12-01

The Early Cretaceous is a time of significant transformation with the continued break-up of Pangea, the emplacement of several LIPs, and a climatic shift from a cool greenhouse to a warm greenhouse. The timing of these major events and their relationship to seawater geochemistry (as recorded in isotope records) is critical for understanding changes in global biogeochemical cycles during this time. Within this context, recent revisions to the Cretaceous portion of the geologic timescale necessitate a reevaluation of the Cretaceous S isotope record as recorded in marine barite (Paytan et al., 2004). We present a revised Early Cretaceous S isotope record and present new δ34Sbarite data that extend the record further back in time and provide more detail during two major S isotope shifts of the Early Cretaceous. The new data maintain the major ~5‰ negative shift but raise questions on the timing and structure of this perturbation. Furthermore, recently updated estimates for global rates of marine microbial sulfate reduction (MSR) (Bowles et al., 2014) and sulfate burial during the Phanerozoic (Halevy et al., 2012) require notable revisions in the fluxes and isotopic values used to model the global S cycle. We present a revised global S cycle box model and reconstruct the evolution of the Early Cretaceous S isotope record primarily through perturbations in volcanic and hydrothermal fluxes (e.g., submarine LIPs). Changes to the weathering and pyrite burial fluxes and the global integrated fractionation factor for MSR are also used to modulate, balance, and smooth the LIP-driven perturbation. The massive evaporite burial during the Late Aptian post dates the major -5‰ shift and has little affect on the modeled S isotope composition of seawater sulfate, despite causing a major drop in sulfate concentration. The S cycle box model is coupled to a Sr cycle box model to provide additional constraints on the magnitude and timing of perturbations within the S isotope record.

Sequence stratigraphic control on prolific HC reservoir development, Southwest Iran

USGS Publications Warehouse

Lasemi, Y.; Kondroud, K.N.

2008-01-01

An important carbonate formation in the Persian Gulf and the onshore oil fields of Southwest Iran is the Lowermost Cretaceous Fahliyan formation. The formation in Darkhowain field consists of unconformity-bounded depositional sequences containing prolific hydrocarbon reservoirs of contrasting origin. Located in the high stand systems tract (HST) of the lower sequence encompassing over 200m of oil column are the most prolific reservoir. Another reservoir is over 80m thick consisting of shallowing-upward cycles that are best developed within the transgressive systems tract of the upper sequence. Vertical facies distribution and their paleobathymetry and geophysical log signatures of the Fahliyan formation in the Darkhowain platform reveal the presence of two unconformity-bounded depositional sequences in Vail et al., Van Wagoner et al., and Sarg. The Fahliyan formation mainly consists of platform carbonates composed of restricted bioclastic lime mudstone to packstone of the platform interior, Lithocodium boundstone or ooid-intraclast-bioclast grainstone of the high energy platform margin and the bioclast packstone to lime mudstone related to the off-platform setting.

Ascaulocardium armatum (Morton 1833), new genus (Late Cretaceous): the ultimate variation on the bivalve paradigm.

USGS Publications Warehouse

Pojeta, J.; Sohl, N.F.

1987-01-01

Cretaceous clavagellid pelecypods are a poorly known group, and have previously received little study. Ascaulocardium armatum is conchologically the most complex burrowing pelecypod known. From the study of living clavagellids, it is possible to interpret the various tubes extending outward from the adventitious crypt of A. armatum as devices for hydraulic burrowing and deposit feeding. The conchologically complex A. armatum occurs near the beginning of the history of the Clavagellidae, and does not seem to have given rise to any younger species. Ascaulocardium armatum is known only from the Upper Cretaceous rocks (Santonian-Maastrichtian) of the east Gulf and Atlantic Coastal Plains of the United States of America, as is probably the genus Ascaulocardium. All known Cretaceous clavagellids are burrowing species having a free right valve, and this is the ancestral mode of life of the Clavagellidae. Clavagellids that have a boring habit are a more recent evolutionary development, as are burrowing species having both juvenile valves cemented to the crypt. Clavagellids probably evolved from Jurassic-Early Cretaceous pholadomyids. Almost all Cretaceous clavagellids occur outside the Tethyan Zoogeographic Realm; this distribution is in marked contrast to the modern distribution of the family. Living species mostly inhabit clear, shallow seas in subtropical to tropical shelf areas. - Authors

Upper Cretaceous and lower Eocene conglomerates of Western Transverse Ranges: evidence for tectonic rotation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reed, W.E.; Krause, R.G.F.

1989-04-01

Stratigraphic and paleomagnetic studies have suggested that the western Transverse Ranges (WTR) microplate is allochthonous, and may have experienced translational and rotational motions. Present paleocurrent directions from the Upper Cretaceous Jalama Formation of the Santa Ynez Mountains are north-directed; these forearc sediments (Great Valley sequence) contain magmatic arc-derived conglomerate clasts from the Peninsular Ranges in southern California. Paleocurrents in the lower Eocene Juncal and Cozy Dell Formations are south-directed. This juxtaposition is best explained by 90/degrees/ or more of clockwise rotation of the WTR microplate, so that Upper Cretaceous forearc sediments sourced from the Peninsular Ranges magmatic arc were depositedmore » by west-directed currents. Eocene sediments were derived from an uplifted portion of the western basin margin and deposited by east-directed currents. Franciscan olistoliths in the Upper Cretaceous sediments indicate deposition adjacent to an accretionary wedge; conglomeratic clasts recycled from the Upper Cretaceous sequence, and radiolarian cherts and ophiolitic boulders in the Eocene strata indicate derivation from an outer accretionary ridge.« less

An Atmospheric CO2 Record Across the End-Cretaceous Extinction

NASA Astrophysics Data System (ADS)

Royer, D. L.; Milligan, J. N.; Kowalczyk, J.

2017-12-01

A bolide impact and flood-basalt emissions likely caused large changes to the end-Cretaceous carbon cycle. Presently, there is only one proxy record for atmospheric CO2 that captures these changes (Beerling et al., 2002, PNAS 99: 7836-7840). These authors estimated CO2 from the calibrated stomatal indices of Ginkgo dated to within 105 yrs before and after the extinction ( 300-500 ppm) in addition to that of Stenochlaena, a fern disaster taxa present in the Raton Basin, New Mexico, <104 yrs after the bolide impact (>2300 ppm). We revisited these fossil collections and applied a newer and more robust CO2 proxy that is based on leaf gas-exchange principles and does not require calibrations with present-day species (Franks et al., 2014, Geophys Res Lett 41: 4685-4694). We reconstruct pre- and post-extinction CO2 concentrations of 650 ppm from Ginkgo, compared to 850 ppm directly after the extinction from Stenochlaena. This change in CO2 of 200 ppm can be readily explained with carbon cycle models as a consequence of either the bolide impact or flood-basalt emissions. Placing these CO2 estimates into the broader context of other leaf gas-exchange CO2 estimates for the Cenozoic, the Earth system sensitivity was 3 K per CO2 doubling during the early Paleogene, before steepening to >6 K several million years before the Eocene-Oligocene boundary.

The last polar dinosaurs: high diversity of latest Cretaceous arctic dinosaurs in Russia

NASA Astrophysics Data System (ADS)

Godefroit, Pascal; Golovneva, Lina; Shchepetov, Sergei; Garcia, Géraldine; Alekseev, Pavel

2009-04-01

A latest Cretaceous (68 to 65 million years ago) vertebrate microfossil assemblage discovered at Kakanaut in northeastern Russia reveals that dinosaurs were still highly diversified in Arctic regions just before the Cretaceous-Tertiary mass extinction event. Dinosaur eggshell fragments, belonging to hadrosaurids and non-avian theropods, indicate that at least several latest Cretaceous dinosaur taxa could reproduce in polar region and were probably year-round residents of high latitudes. Palaeobotanical data suggest that these polar dinosaurs lived in a temperate climate (mean annual temperature about 10°C), but the climate was apparently too cold for amphibians and ectothermic reptiles. The high diversity of Late Maastrichtian dinosaurs in high latitudes, where ectotherms are absent, strongly questions hypotheses according to which dinosaur extinction was a result of temperature decline, caused or not by the Chicxulub impact.

Terrestrial paleoclimatic changes in northeast Asia during OAE 3 in the Late Cretaceous: Organic geochemical evidences from the Songliao paleo-lake Basin, northeast China

NASA Astrophysics Data System (ADS)

Gao, Y.; Wang, C.; Huang, H.

2016-12-01

Oceanic anoxic events (OAEs) in the Cretaceous greenhouse world record significant paleoclimatic changes and represent major disturbances in the global carbon cycle. The Coniacian-Santonian oceanic anoxic event (OAE 3), the last of the Cretaceous OAEs, is characterized by restricted black shale deposits in equatorial to mid-latitude Atlantic and adjacent basins. Continental hydroclimate on tropical Africa and South America was proved have a strong effect on carbon burial in ocean basins during OAE 3, although terrestrial paleoclimatic changes on the other continents were not well understood. The Continental Scientific Drilling Project of the Songliao paleo-lake Basin (northeast China) recovered 500m thick, continuous, dark-colored, deep lacustrine mudstone of the Qingshankou Formation, with the age of 92.0-86.2Ma tightly constrained by radiometric dating on volcanic ashes, magnetostratigraphy and cyclostratigraphy. These sediments thus provide an opportunity to study terrestrial paleoclimate changes in northeast Asia during OAE 3. Our high-resolution ( 1m interval) TOC and δ13Corg data of the Qingshankou Formation in the Songliao Basin show several positive δ13Corg excursions over the OAE 3 time period. Spectrum analysis shows remarkable Milankovich cycles including eccentricity cycles ( 400kyr) and precession cycles ( 20 kyr). These data suggest that dark-colored mudstone deposition in the Songliao paleo-lake was probably controlled by regional hydroclimatic changes which were influenced by orbital forcing.

Geochemical characteristics of Cretaceous carbonatites from Angola

NASA Astrophysics Data System (ADS)

Alberti, A.; Castorina, F.; Censi, P.; Comin-Chiaramonti, P.; Gomes, C. B.

1999-12-01

The Early Cretaceous (138-130 Ma) carbonatites and associated alkaline rocks of Angola belong to the Paraná-Angola-Etendeka Province and occur as ring complexes and other central-type intrusions along northeast trending tectonic lineaments, parallel to the trend of coeval Namibian alkaline complexes. Most of the Angolan carbonatite-alkaline bodies are located along the apical part of the Moçamedes Arch, a structure representing the African counterpart of the Ponta Grossa Arch in southern Brazil, where several alkaline-carbonatite complexes were also emplaced in the Early Cretaceous. Geochemical and isotopic (C, 0, Sr and Nd) characteristics determined for five carbonatitic occurrences indicate that: (1) the overall geochemical composition, including the OC isotopes, is within the range of the Early and Late Cretaceous Brazilian occurrences from the Paraná Basin; (2) the La versus {La}/{Yb} relationships are consistent with the exsolution of CO i2-rich melts from trachyphonolitic magmas; and (3) the {143Nd}/{144Nd} and {87Sr}/{86Sr} initial ratios are similar to the initial isotopic ratios (129 Ma) of alkaline complexes in northwest Namibia. In contrast, the Lupongola carbonatites have a distinctly different {143Nd}/{144Nd} initial ratio, suggesting a different source. The Angolan carbonatites have SrNd isotopic compositions ranging from bulk earth to time-integrated depleted sources. Since those from eastern Paraguay (at the western fringe of the Paraná-Angola-Etendeka Province) and Brazil appear to be related to mantle-derived melts with time-integrated enriched or B.E. isotopic characteristics, it is concluded that the carbonatites of the Paraná-Angola-Etendeka Province have compositionally distinct mantle sources. Such mantle heterogeneity is attributed to 'metasomatic processes', which would have occurred at ca 0.6-0.7 Ga (Angola, northwest Namibia and Brazil) and ca 1.8 Ga (eastern Paraguay), as suggested by Nd-model ages.

Trace gas measurements from tethered balloon platforms

NASA Technical Reports Server (NTRS)

Bandy, Alan R.; Bandy, Terese L.; Youngbluth, Otto; Owens, Thomas L.

1987-01-01

Instrumentation and chemical sampling and analysis procedures are described for making measurements of atmospheric carbon disulfide in the concentration range 1-1000 pptv from tethered balloon platforms. Results of a study on the CS2 composition of air downward of a saltwater marsh are reported. A method for obtaining the necessary data for solving the budget equations for surface fluxes, chemical formation rates and chemical destruction rates using data acquired from tethered balloon platforms is presented.

Geologic Assessment of Undiscovered Oil and Gas Resources of the North Cuba Basin, Cuba

USGS Publications Warehouse

Schenk, Christopher J.

2010-01-01

Petroleum generation in the North Cuba Basin is primarily the result of thrust loading of Jurassic and Cretaceous source rocks during formation of the North Cuba fold and thrust belt in the Late Cretaceous to Paleogene. The fold and thrust belt formed as Cuban arc-forearc rocks along the leading edge of the Caribbean plate translated northward during the opening of the Yucatan Basin and collided with the passive margin of southern North America in the Paleogene. Petroleum fluids generated during thrust loading migrated vertically into complex structures in the fold and thrust belt, into structures in the foreland basin, and possibly into carbonate reservoirs along the margins of the Yucatan and Bahama carbonate platforms. The U.S. Geological Survey (USGS) defined a Jurassic-Cretaceous Composite Total Petroleum System (TPS) and three assessment units (AU)-North Cuba Fold and Thrust Belt AU, North Cuba Foreland Basin AU, and the North Cuba Platform Margin Carbonate AU-within this TPS based mainly on structure and reservoir type (fig. 1). There is considerable geologic uncertainty as to the extent of petroleum migration that might have occurred within this TPS to form potential petroleum accumulations. Taking this geologic uncertainty into account, especially in the offshore area, the mean volumes of undiscovered resources in the composite TPS of the North Cuba Basin are estimated at (1) 4.6 billion barrels of oil (BBO), with means ranging from an F95 probability of 1 BBO to an F5 probability of 9 BBO; and (2) 8.6 trillion cubic feet of of gas (TCFG), of which 8.6 TCFG is associated with oil fields, and about 1.2 TCFG is in nonassociated gas fields in the North Cuba Foreland Basin AU.

Portable life support for instrumentation of an offshore platform

NASA Technical Reports Server (NTRS)

Mull, M. M.; Coffin, C. L.

1972-01-01

A compressor was used to supply air through a nylon hose to the offshore platform field engineer working at the bottom of the piling. Air quality in the pile was sampled periodically for carbon dioxide, carbon monoxide, hydrogen sulfide, and combustible gases by an universal tester and an explosion meter.

Reconstructing a mid-Cretaceous landscape from paleosols in western Canada

USGS Publications Warehouse

Ufnar, David F.; Gonzalez, Luis A.; Ludvigson, Greg A.; Brenner, Richard L.; Witzke, B.J.; Leckie, D.

2005-01-01

The Albian Stage of the mid-Cretaceous was a time of equable climate conditions with high sea levels and broad shallow epeiric seas that may have had a moderating affect on continental climates. A Late Albian landscape surface that developed during a regression and subsequent sea-level rise in the Western Canada Foreland Basin is reconstructed on the basis of correlation of paleosols penetrated by cores through the Paddy Member of the Peace River Formation. Reconstruction of this landscape refines chronostratigraphic relationships and will benefit future paleoclimatological studies milizing continental sphaerosiderite proxy records. The paleosols developed in estuarine sandstones and mudstones, and they exhibit evidence of a polygenetic history. Upon initial exposure and pedogenesis, the Paddy Member developed deeply weathered, well-drained cumulative soil profiles. Later stages of pedogenesis were characterized by hydromorphic soil conditions. The stages of soil development interpreted for the Paddy Member correlate with inferred stages of pedogenic development in time-equivalent formations located both basinward and downslope (upper Viking Formation), and landward and upslope (Boulder Creek Formation). On the basis of the genetic similarity among paleosols in these three correlative formations, the paleosols are interpreted as having formed along a single, continuous landscape surface. Results of this study indicate that the catena concept of pedogenesis along sloping landscapes is applicable to ancient successions. Sphaerosiderites in the Paddy Mem ber paleosols are used to provide proxy values for meteoric ??18O values at 52?? N paleolatitude in the Cretaceous Western Interior Basin. The meteoric ??18O values are used to refine existing interpretations about the mid-Cretaceous paleolatitudinal gradient in meteoric ?? 18O values, and the mid-Cretaceous hydrologic cycle. Copyright ?? 2005, SEPM (Society for Sedimentary Geology).

Paleobotany of Livingston Island: The first report of a Cretaceous fossil flora from Hannah Point

USGS Publications Warehouse

Leppe, M.; Michea, W.; Muñoz, C.; Palma-Heldt, S.; Fernandoy, F.

2007-01-01

This is the first report of a fossil flora from Hannah Point, Livingston Island, South Shetland Islands, Antarctica. The fossiliferous content of an outcrop, located between two igneous rock units of Cretaceous age are mainly composed of leaf imprints and some fossil trunks. The leaf assemblage consists of 18 taxa of Pteridophyta, Pinophyta and one angiosperm. The plant assemblage can be compared to other Early Cretaceous floras from the South Shetland Islands, but several taxa have an evidently Late Cretaceous affinity. A Coniacian-Santonian age is the most probable age for the outcrops, supported by previous K/Ar isotopic studies of the basalts over and underlying the fossiliferous sequence

New Mid-Cretaceous (Latest Albian) Dinosaurs from Winton, Queensland, Australia

PubMed Central

Hocknull, Scott A.; White, Matt A.; Tischler, Travis R.; Cook, Alex G.; Calleja, Naomi D.; Sloan, Trish; Elliott, David A.

2009-01-01

Background Australia's dinosaurian fossil record is exceptionally poor compared to that of other similar-sized continents. Most taxa are known from fragmentary isolated remains with uncertain taxonomic and phylogenetic placement. A better understanding of the Australian dinosaurian record is crucial to understanding the global palaeobiogeography of dinosaurian groups, including groups previously considered to have had Gondwanan origins, such as the titanosaurs and carcharodontosaurids. Methodology/Principal Findings We describe three new dinosaurs from the late Early Cretaceous (latest Albian) Winton Formation of eastern Australia, including; Wintonotitan wattsi gen. et sp. nov., a basal titanosauriform; Diamantinasaurus matildae gen. et sp. nov., a derived lithostrotian titanosaur; and Australovenator wintonensis gen. et sp. nov., an allosauroid. We compare an isolated astragalus from the Early Cretaceous of southern Australia; formerly identified as Allosaurus sp., and conclude that it most-likely represents Australovenator sp. Conclusion/Significance The occurrence of Australovenator from the Aptian to latest Albian confirms the presence in Australia of allosauroids basal to the Carcharodontosauridae. These new taxa, along with the fragmentary remains of other taxa, indicate a diverse Early Cretaceous sauropod and theropod fauna in Australia, including plesiomorphic forms (e.g. Wintonotitan and Australovenator) and more derived forms (e.g. Diamantinasaurus). PMID:19584929

The Wandering Indian Plate and Its Changing Biogeography During the Late Cretaceous-Early Tertiary Period

NASA Astrophysics Data System (ADS)

Chatterjee, Sankar; Scotese, Christopher

Palaeobiogeographic analysis of Indian tetrapods during the Late Cretaceous-Early Tertiary time has recognized that both vicariance and geodispersal have played important roles in producing biogeographic congruence. The biogeographic patterns show oscillating cycles of geodispersal (Late Cretaceous), followed by congruent episodes of vicariance and geodispersal (Early Eocene), followed by another geodispersal event (Middle Eocene). New biogeographic synthesis suggests that the Late Cretaceous Indian tetrapod fauna is cosmopolitan with both Gondwanan and Laurasian elements. Throughout most of the Cretaceous, India was separated from the rest of Gondwana, but in the latest Cretaceous it reestablished contact with Africa through Kohistan-Dras (K-D) volcanic arc, and maintained biotic link with South America via Ninetyeast Ridge-Kerguelen-Antarctica corridor. These two geodispersal routes allowed exchanges of "pan-Gondwana" terrestrial tetrapods from Africa, South America, and Madagascar. During that time India also maintained biotic connections with Laurasia across the Neotethys via Kohistan-Dras Arc and Africa. During the Palaeocene, India, welded to the K-D Arc, rafted like a "Noah's Ark" as an island continent and underwent rapid cladogenesis because of allopatric speciation. Although the Palaeocene fossil record is blank, Early Eocene tetrapods contain both endemic and cosmopolitan elements, but Middle Eocene faunas have strong Asian character. India collided with Asia in Early and Middle Eocene time and established a new northeast corridor for faunal migration to facilitate the bidirectional "Great Asian Interchange" dispersals.

The paleohydrology of Lower Cretaceous seasonal wetlands, Isle of Wight, southern England

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wright, V.P.; Taylor, K.G.; Beck, V.H.

2000-05-01

The floodplain deposits of the Wealden Group (Lower Cretaceous) of the Isle of Wight, southern England, were formed in a seasonal wetland setting, a type of environment widespread today along higher-order tropical and subtropical river systems but rarely identified in the geological record. The unit consists of four main lithofacies: sheet sandstones with dinosaur footprint casts; green-gray mudstones with vertebrate remains, abundant lignite, pyrite, and siderite; spectacularly color-mottled mudstones with goethite and locally pseudo-anticlines; and red mudstones with pseudo-anticlines, hematite, and carbonate nodules. The sheet sandstones are interpreted as crevasse deposits; the green-gray mudstones were deposited in shallow ponds onmore » the floodplain, which acted as sinks for debris released by local floods following wildfires; the mottled mudstones represent surface-water gley soils formed in seasonally waterlogged areas; and the red mudstones resemble present-day Vertisols that formed on topographically elevated areas only intermittently flooded. These mudstones show vertical transitions from one to another, and although they could be interpreted as components of simple catenas, the absence of associated facies changes implies that topographic differences were not the only control. It is proposed that these three mudstone types formed as seasonal wetland catenas, in which differences in soil drainage conditions resulted from variations in the flooding hydroperiod affecting areas with minor relief differences, rather than drainage variability simply reflecting static topographic differences. Such seasonal wetland systems are rarely documented in the stratigraphic record despite being a widespread environment in present-day tropical regions, and the Wealden deposits are used to identify criteria for the recognition of this important environment in the rock record. These southern English wetlands are compared with other Lower Cretaceous wetlands from

Asteroid impact vs. Deccan eruptions: The origin of low magnetic susceptibility beds below the Cretaceous-Paleogene boundary revisited

NASA Astrophysics Data System (ADS)

Abrajevitch, Alexandra; Font, Eric; Florindo, Fabio; Roberts, Andrew P.

2015-11-01

The respective roles of an asteroid impact and Deccan Traps eruptions in biotic changes at the Cretaceous-Paleogene (K-Pg) boundary are still debated. In many shallow marine sediments from around the world, the K-Pg boundary is marked by a distinct clay layer that is often underlain by a several decimeter-thick low susceptibility zone. A previous study of the Gubbio section, Italy (Lowrie et al., 1990), attributed low magnetization intensity in this interval to post-depositional dissolution of ferrimagnetic minerals. Dissolution was thought to be a consequence of downward infiltration of reducing waters that resulted from rapid accumulation of organic matter produced by mass extinctions after the K-Pg event. We compare the magnetic properties of sediments from the Gubbio section with those of the Bidart section in southern France. The two sections are similar in their carbonate lithology and the presence of a boundary clay and low susceptibility zone. When compared to background Cretaceous sediments, the low susceptibility zone in both sections is marked by an absence of biogenic magnetite, a decrease in total ferrimagnetic mineral content, and a preferential loss of magnetite with respect to hematite - features that are consistent with reductive dissolution. However, unlike the Gubbio section, where the low susceptibility zone starts immediately below the boundary clay, the low susceptibility zone and the clay layer at Bidart are separated by a ∼4-cm carbonate interval that contains abundant biogenic magnetite. Such separation casts doubt on a causal link between the impact and sediment bleaching. More likely, the low susceptibility layer marks a different environmental event that preceded the impact. An episode of increased atmospheric and oceanic acidity associated with Deccan Traps volcanism that occurred well before the K-Pg impact is argued here to account for the distinct magnetic properties of the low susceptibility intervals.

The Ree and ɛNd of 40-70 Ma old fish debris from the west-African platform

NASA Astrophysics Data System (ADS)

Grandjean, Patricia; Cappetta, Henri; Albarède, Francis

1988-04-01

REE concentrations and Nd isotopic compositions have been determined in Late Cretaceous-Early Cenozoic fish debris from West African and Israeli platform sediments and show a strong regional control independent of time, except for those from the Northern Morocco. It is suggested that, although diagenetic fluids do not contribute REE's directly to the phosphatic debris, they may significantly change the Ce anomaly and the ɛNd(T) value of the epicontinental seas, which, in turn, control the REE in marine phosphates. It is shown that, over the investigated period, the North Moroccan shelf seawater was progressively flushed by deep North-Atlantic water.

Cosmic Genes in the Cretaceous-Tertiary transition

NASA Astrophysics Data System (ADS)

Wallis, M. K.

2003-07-01

It is proposed that genes coding for Aib-polypeptides arose early on in the K/T transition, presumed from the Earth's accretion of interplanetary (comet) dust. Aib-fungi flourished because of the evolutionary advantage of novel antibiotics. The stress on Cretaceous biology led directly and indirectly to mass species extinctions, including many dinosaur species, in the epoch preceding the Chicxulub impact.

Honeggeriella complexa gen. et sp. nov., a heteromerous lichen from the Lower Cretaceous of Vancouver Island (British Columbia, Canada).

PubMed

Matsunaga, Kelly K S; Stockey, Ruth A; Tomescu, Alexandru M F

2013-02-01

Colonists of even the most inhospitable environments, lichens are present in all terrestrial ecosystems. Because of their ecological versatility and ubiquity, they have been considered excellent candidates for early colonizers of terrestrial environments. Despite such predictions, good preservation potential, and the extant diversity of lichenized fungi, the fossil record of lichen associations is sparse. Unequivocal lichen fossils are rare due, in part, to difficulties in ascertaining the presence of both symbionts and in characterizing their interactions. This study describes an exceptionally well-preserved heteromerous lichen from the Lower Cretaceous of Vancouver Island. The fossil occurs in a marine carbonate concretion collected from the Apple Bay locality on Vancouver Island, British Columbia, and was prepared for light microscopy and SEM using the cellulose acetate peel technique. The lichen, Honeggeriella complexa gen. et sp. nov., is formed by an ascomycete mycobiont and a chlorophyte photobiont, and exhibits heteromerous thallus organization. This is paired with a mycobiont-photobiont interface characterized by intracellular haustoria, previously not documented in the fossil record. Honeggeriella adds a lichen component to one of the richest and best characterized Early Cretaceous floras and provides a significant addition to the sparse fossil record of lichens. As a heteromerous chlorolichen, it bridges the >350 million-year gap between previously documented Early Devonian and Eocene occurrences.

Macrofossil evidence for a rapid and severe Cretaceous-Paleogene mass extinction in Antarctica.

PubMed

Witts, James D; Whittle, Rowan J; Wignall, Paul B; Crame, J Alistair; Francis, Jane E; Newton, Robert J; Bowman, Vanessa C

2016-05-26

Debate continues about the nature of the Cretaceous-Paleogene (K-Pg) mass extinction event. An abrupt crisis triggered by a bolide impact contrasts with ideas of a more gradual extinction involving flood volcanism or climatic changes. Evidence from high latitudes has also been used to suggest that the severity of the extinction decreased from low latitudes towards the poles. Here we present a record of the K-Pg extinction based on extensive assemblages of marine macrofossils (primarily new data from benthic molluscs) from a highly expanded Cretaceous-Paleogene succession: the López de Bertodano Formation of Seymour Island, Antarctica. We show that the extinction was rapid and severe in Antarctica, with no significant biotic decline during the latest Cretaceous, contrary to previous studies. These data are consistent with a catastrophic driver for the extinction, such as bolide impact, rather than a significant contribution from Deccan Traps volcanism during the late Maastrichtian.

Macrofossil evidence for a rapid and severe Cretaceous-Paleogene mass extinction in Antarctica

NASA Astrophysics Data System (ADS)

Witts, James D.; Whittle, Rowan J.; Wignall, Paul B.; Crame, J. Alistair; Francis, Jane E.; Newton, Robert J.; Bowman, Vanessa C.

2016-05-01

Debate continues about the nature of the Cretaceous-Paleogene (K-Pg) mass extinction event. An abrupt crisis triggered by a bolide impact contrasts with ideas of a more gradual extinction involving flood volcanism or climatic changes. Evidence from high latitudes has also been used to suggest that the severity of the extinction decreased from low latitudes towards the poles. Here we present a record of the K-Pg extinction based on extensive assemblages of marine macrofossils (primarily new data from benthic molluscs) from a highly expanded Cretaceous-Paleogene succession: the López de Bertodano Formation of Seymour Island, Antarctica. We show that the extinction was rapid and severe in Antarctica, with no significant biotic decline during the latest Cretaceous, contrary to previous studies. These data are consistent with a catastrophic driver for the extinction, such as bolide impact, rather than a significant contribution from Deccan Traps volcanism during the late Maastrichtian.

The role of evaporites in the formation of gems during metamorphism of carbonate platforms: a review

NASA Astrophysics Data System (ADS)

Giuliani, Gaston; Dubessy, Jean; Ohnenstetter, Daniel; Banks, David; Branquet, Yannick; Feneyrol, Julien; Fallick, Anthony E.; Martelat, Jean-Emmanuel

2018-01-01

The mineral and fluid inclusions trapped by gemstones during the metamorphism of carbonate platform successions are precious markers for the understanding of gem genesis. The nature and chemical composition of inclusions highlight the major contribution of evaporites through dissolution or fusion, depending on the temperature of formation from greenschist to granulite facies. The fluids are highly saline NaCl-brines circulating either in an open system in the greenschist facies (Colombian and Afghan emeralds) and with huge fluid-rock metasomatic interactions, or sulphurous fluids (ruby, garnet tsavorite, zoisite tanzanite and lapis-lazuli) or molten salts formed in a closed system with a low fluid mobility (ruby in marble) in the conditions of the amphibolite to granulite facies. These chloride-fluoride-sulphate ± carbonate-rich fluids scavenged the metals essential for gem formation. At high temperature, the anions SO4 2-, NO3 -, BO3 - and F- are powerful fluxes which lower the temperature of chloride- and fluoride-rich ionic liquids. They provided transport over a very short distance of aluminium and/or silica and transition metals which are necessary for gem growth. In summary, the genetic models proposed for these high-value and ornamental gems underline the importance of the metamorphism of evaporites formed on continental carbonate shelves and emphasise the chemical power accompanying metamorphism at moderate to high temperatures of evaporite-rich and organic matter-rich protoliths to form gem minerals.

A Diplodocid Sauropod Survivor from the Early Cretaceous of South America

PubMed Central

Gallina, Pablo A.; Apesteguía, Sebastián; Haluza, Alejandro; Canale, Juan I.

2014-01-01

Diplodocids are by far the most emblematic sauropod dinosaurs. They are part of Diplodocoidea, a vast clade whose other members are well-known from Jurassic and Cretaceous strata in Africa, Europe, North and South America. However, Diplodocids were never certainly recognized from the Cretaceous or in any other southern land mass besides Africa. Here we report a new sauropod, Leikupal laticauda gen. et sp. nov., from the early Lower Cretaceous (Bajada Colorada Formation) of Neuquén Province, Patagonia, Argentina. This taxon differs from any other sauropod by the presence of anterior caudal transverse process extremely developed with lateroventral expansions reinforced by robust dorsal and ventral bars, very robust centroprezygapophyseal lamina in anterior caudal vertebra and paired pneumatic fossae on the postzygapophyses in anterior-most caudal vertebra. The phylogenetic analyses support its position not only within Diplodocidae but also as a member of Diplodocinae, clustering together with the African form Tornieria, pushing the origin of Diplodocoidea to the Middle Jurassic or even earlier. The new discovery represents the first record of a diplodocid for South America and the stratigraphically youngest record of this clade anywhere. PMID:24828328

A diplodocid sauropod survivor from the early cretaceous of South America.

PubMed

Gallina, Pablo A; Apesteguía, Sebastián; Haluza, Alejandro; Canale, Juan I

2014-01-01

Diplodocids are by far the most emblematic sauropod dinosaurs. They are part of Diplodocoidea, a vast clade whose other members are well-known from Jurassic and Cretaceous strata in Africa, Europe, North and South America. However, Diplodocids were never certainly recognized from the Cretaceous or in any other southern land mass besides Africa. Here we report a new sauropod, Leikupal laticauda gen. et sp. nov., from the early Lower Cretaceous (Bajada Colorada Formation) of Neuquén Province, Patagonia, Argentina. This taxon differs from any other sauropod by the presence of anterior caudal transverse process extremely developed with lateroventral expansions reinforced by robust dorsal and ventral bars, very robust centroprezygapophyseal lamina in anterior caudal vertebra and paired pneumatic fossae on the postzygapophyses in anterior-most caudal vertebra. The phylogenetic analyses support its position not only within Diplodocidae but also as a member of Diplodocinae, clustering together with the African form Tornieria, pushing the origin of Diplodocoidea to the Middle Jurassic or even earlier. The new discovery represents the first record of a diplodocid for South America and the stratigraphically youngest record of this clade anywhere.

A new dinosaur ichnotaxon from the Lower Cretaceous Patuxent Formation of Maryland and Virginia

USGS Publications Warehouse

Stanford, Ray; Weems, Robert E.; Lockley, Martin G.

2004-01-01

In recent years, numerous dinosaur footprints have been discovered on bedding surfaces within the Lower Cretaceous Patuxent Formation of Maryland and Virginia. Among these, distinctive small tracks that display a combination of small manus with five digit impressions and a relatively much larger pes with four toe impressions evidently were made by animals belonging to the ornithischian family Hypsilophodontidae. These tracks differ from any ornithischian ichnotaxon previously described. We here name them Hypsiloichnus marylandicus and provide a description of their diagnostic characteristics. Although hypsilophodontid skeletal remains have not been found in the Patuxent, their skeletal remains are known from Lower Cretaceous strata of similar age in both western North America and Europe. Therefore, it is not surprising to find that an Early Cretaceous representative of this family also existed in eastern North America.

Paleomagnetic tests for tectonic reconstructions of the Late Jurassic-Early Cretaceous Woyla Group, Sumatra

NASA Astrophysics Data System (ADS)

Advokaat, Eldert; Bongers, Mayke; van Hinsbergen, Douwe; Rudyawan, Alfend; Marshal, Edo

2017-04-01

SE Asia consists of multiple continental blocks, volcanic arcs and suture zones representing remnants of closing ocean basins. The core of this mainland is called Sundaland, and was formed by accretion of continental and arc fragments during the Paleozoic and Mesozoic. The former positions of these blocks are still uncertain but reconstructions based on tectonostratigraphic, palaeobiogeographic, geological and palaeomagnetic studies indicate the continental terranes separated from the eastern margin of Gondwana. During the mid-Cretaceous, more continental and arc fragments accreted to Sundaland, including the intra-oceanic Woyla Arc now exposed on Sumatra. These continental fragments were derived from Australia, but the former position of the Woyla Arc is unconstrained. Interpretations on the former position of the Woyla Arc fall in two end-member groups. The first group interprets the Woyla Arc to be separated from West Sumatra by a small back-arc basin. This back arc basin opened in the Late Jurassic, and closed mid-Cretaceous, when the Woyla Arc collided with West Sumatra. The other group interprets the Woyla Arc to be derived from Gondwana, at a position close to the northern margin of Greater India in the Late Jurassic. Subsequently the Woyla Arc moved northwards and collided with West Sumatra in the mid-Cretaceous. Since these scenarios predict very different plate kinematic evolutions for the Neotethyan realm, we here aim to place paleomagnetic constraints on paleolatitudinal evolution of the Woyla Arc. The Woyla Arc consists mainly of basaltic to andesitic volcanics and dykes, and volcaniclastic shales and sandstones. Associated limestones with volcanic debris are interpreted as fringing reefs. This assemblage is interpreted as remnants of an Early Cretaceous intra-oceanic arc. West Sumatra exposes granites, surrounded by quartz sandstones, shales and volcanic tuffs. These sediments are in part metamorphosed. This assemblage is interpreted as a Jurassic

The development of the continental margin of eastern North America-conjugate continental margin to West Africa

USGS Publications Warehouse

Dillon, William P.; Schlee, J.S.; Klitgord, Kim D.

1988-01-01

The continental margin of eastern North America was initiated when West Africa and North America were rifted apart in Triassic-Early Jurassic time. Cooling of the crust and its thinning by rifting and extension caused subsidence. Variation in amounts of subsidence led to formation of five basins. These are listed from south to north. (1) The Blake Plateau Basin, the southernmost, is the widest basin and the one in which the rift-stage basement took longest to form. Carbonate platform deposition was active and persisted until the end of Early Cretaceous. In Late Cretaceous, deposition slowed while subsidence persisted, so a deep water platform was formed. Since the Paleocene the region has undergone erosion. (2) The Carolina Trough is narrow and has relatively thin basement, on the basis of gravity modeling. The two basins with thin basement, the Carolina Trough and Scotian Basin, also show many salt diapirs indicating considerable deposition of salt during their early evolution. In the Carolina Trough, subsidence of a large block of strata above the flowing salt has resulted in a major, active normal fault on the landward side of the basin. (3) The Baltimore Canyon Trough has an extremely thick sedimentary section; synrift and postrift sediments exceed 18 km in thickness. A Jurassic reef is well developed on the basin's seaward side, but post-Jurassic deposition was mainly non-carbonate. In general the conversion from carbonate to terrigenous deposition, characteristics of North American Basins, occurred progressively earlier toward the north. (4) The Georges Bank Basin has a complicated deep structure of sub-basins filled with thick synrift deposits. This may have resulted from some shearing that occurred at this offset of the continental margin. Postrift sediments apparently are thin compared to other basins-only about 8 km. (5) The Scotian Basin, off Canada, contains Jurassic carbonate rocks, sandstone, shale and coal covered by deltaic deposits and Upper

Chitinase genes (CHIAs) provide genomic footprints of a post-Cretaceous dietary radiation in placental mammals

PubMed Central

Emerling, Christopher A.

2018-01-01

The end-Cretaceous extinction led to a massive faunal turnover, with placental mammals radiating in the wake of nonavian dinosaurs. Fossils indicate that Cretaceous stem placentals were generally insectivorous, whereas their earliest Cenozoic descendants occupied a variety of dietary niches. It is hypothesized that this dietary radiation resulted from the opening of niche space, following the extinction of dinosaurian carnivores and herbivores. We provide the first genomic evidence for the occurrence and timing of this dietary radiation in placental mammals. By comparing the genomes of 107 placental mammals, we robustly infer that chitinase genes (CHIAs), encoding enzymes capable of digesting insect exoskeletal chitin, were present as five functional copies in the ancestor of all placental mammals, and the number of functional CHIAs in the genomes of extant species positively correlates with the percentage of invertebrates in their diets. The diverse repertoire of CHIAs in early placental mammals corroborates fossil evidence of insectivory in Cretaceous eutherians, with descendant lineages repeatedly losing CHIAs beginning at the Cretaceous/Paleogene (K/Pg) boundary as they radiated into noninsectivorous niches. Furthermore, the timing of gene loss suggests that interordinal diversification of placental mammals in the Cretaceous predates the dietary radiation in the early Cenozoic, helping to reconcile a long-standing debate between molecular timetrees and the fossil record. Our results demonstrate that placental mammal genomes, including humans, retain a molecular record of the post-K/Pg placental adaptive radiation in the form of numerous chitinase pseudogenes. PMID:29774238

Use of Multibeam-Bathymetry and Seismic-Reflection Data to Investigate the Origin of Seafloor Depressions Along the Southeastern Carbonate Florida Platform

NASA Astrophysics Data System (ADS)

Cunningham, K. J.; Kluesner, J.; Westcott, R. L.; Ebuna, D. R.; Walker, C.

2016-12-01

Numerous large, semicircular, deep submarine depressions on the seafloor of the Miami Terrace (a bathymetric bench that interrupts the Atlantic continental slope on the southeastern carbonate Florida Platform) have been described as submarine sinkholes resulting from freshwater discharge at the seafloor and dissolution of carbonate rock. Multibeam-bathymetry and marine, high-resolution, multichannel 2D and 3D seismic-reflection data acquired over two of these depressions at water depths of about 250 m ("Miami sinkhole") and 336 m ("Key Biscayne sinkhole") indicate the depressions are pockmarks. Seafloor pockmarks are concave, crater-like depressions that form through the outburst or venting of fluid (gas, liquid) at the sea floor and are important seabed features that provide information about fluid flow on continental margins. Both the "Miami sinkhole" and "Key Biscayne sinkhole" (about 25 and 48m deep, respectively) have a seismic-chimney structure beneath them that indicates an origin related to seafloor fluid expulsion, as supported by multi-attribute analysis of the "Key Biscayne sinkhole". Further, there is no widening of the depressions with depth, as in the Fort Worth Basin, where downward widening of seismic, sub-circular, karst-collapse structures is common. However, hypogenic karst dissolution is not ruled out as part of the evolution of the two depressions. Indeed, a hypogenic karst pipe plausibly extends downward from the bottom of "Key Biscayne sinkhole", providing a passageway for focused upward flow of fluids to the seafloor. In "Key Biscayne sinkhole", the proposed karst pipe occurs above the underlying seismic chimney that contains flat bright spots (a hydrocarbon indicator) in the seismic data plausibly showing fluids are currently trapped beneath the pockmark within a tightly folded popup structure. The Miami Terrace depressions have seismic-reflection features similar to modern pockmarks imaged on the Maldives carbonate platform. The seismic

Influence of pre-tectonic carbonate facies architecture on deformation patterns of syntectonic turbidites, an example from the central Mexican fold-thrust belt

NASA Astrophysics Data System (ADS)

Vásquez Serrano, Alberto; Tolson, Gustavo; Fitz Diaz, Elisa; Chávez Cabello, Gabriel

2018-04-01

The Mexican fold-thrust belt in central México excellently exposes relatively well preserved syntectonic deposits that overlay rocks with lateral lithostratigraphic changes across the belt. We consider the deformational effects of these changes by investigating the geometry, kinematics and strain distribution within syntectonic turbidites, which are deposited on top of Albian-Cenomanian shallow and deep water carbonate layers. Field observations and detailed structural analysis at different stratigraphic and structural levels of the Late Cretaceous syntectonic formation are compared with the deformation as a function of lithological and structural variations in the underlying carbonate units, to better understand the effect of these lithostratigraphic variations on deformation, kinematics, strain distribution and propagation of deformation. From our kinematic analyses, we conclude that the syntectonic strata are pervasively affected by folding in all areas and that deformation partitioning localized shear zones at the boundaries of this unit, particularly along the contact with massive carbonates. At the boundaries with massive platformal carbonates, the turbidites are strongly deformed by isoclinal folding with a pervasive sub-horizontal axial plane cleavage and 70-60% shortening. In contrast, contacts with thinly-bedded carbonate layers (basinal facies), do not show strain localization, and have horizontal shortening of 50-40% that is accommodated by buckle folds with a less pervasive, steeply dipping cleavage. The mechanical properties variations in the underlying pre-tectonic units as a function of changes in lithostratigraphy fundamentally control the deformation in the overlying syntectonic strata, which is an effect that could be expected to occur in any deformed sedimentary sequence with such variations.

Comparative burial and thermal history of lower Upper Cretaceous strata, Powder River basin, Wyoming

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nuccio, V.F.

1989-03-01

Burial histories were reconstructed for three localities in the Powder River basin (PRB), Wyoming. Thermal maturity of lower Upper Cretaceous source rocks was determined by vitrinite reflectance (R/sub m/) and time-temperature index (TTI) modeling, producing independent estimates for timing of the oil window (0.55-1.35% R/sub m/). In the northwestern PRB, lower Upper Cretaceous rocks were buried to about 12,500 ft and achieved a thermal maturity of 0.50% to 0.56% at maximum burial, 10 Ma, based on measured R/sub m/. TTI modeling suggests a slightly higher thermal maturity, with an R/sub m/ equivalent of approximately 0.75%, placing the source rocks atmore » the beginning of the oil window 30 Ma. In the southwestern PRB, lower Upper Cretaceous rocks have been buried to about 15,000 ft and achieved thermal maturities between 0.66% and 0.75% about 10 Ma based on measured R/sub m/; therefore, petroleum generation may have begun slightly earlier. TTI modeling estimates an R/sub m/ equivalent of 1.10%, placing the beginning of the oil window at 45 Ma. In the northeastern PRB, lower Upper Cretaceous rocks have been buried only to approximately 5500 ft. Measured R/sub m/ and TTI modeling indicate a thermal maturity for lower Upper Cretaceous rocks between 0.45% and 0.50% R/sub m/, too low for petroleum generation. The higher R/sub m/ values determined by the TTI models may be due to overestimation of maximum burial depth and/or paleogeothermal gradients. The two independent maturity indicators do, however, constrain fairly narrowly the onset of petroleum generation.« less

Palaeomagnetism of lower cretaceous tuffs from Yukon-Kuskokwim delta region, western Alaska

USGS Publications Warehouse

Globerman, B.R.; Coe, R.S.; Hoare, J.M.; Decker, J.

1983-01-01

During the past decade, the prescient arguments1-3 for the allochthoneity of large portions of southern Alaska have been corroborated by detailed geological and palaeomagnetic studies in south-central Alaska 4-9 the Alaska Peninsula10, Kodiak Island11,12 and the Prince William Sound area13 (Fig. 1). These investigations have demonstrated sizeable northward displacements for rocks of late Palaeozoic, Mesozoic, and early Tertiary age in those regions, with northward motion at times culminating in collision of the allochthonous terranes against the backstop of 'nuclear' Alaska14,15. A fundamental question is which parts of Alaska underwent significantly less latitudinal translation relative to the 'stable' North American continent, thereby serving as the 'accretionary nucleus' into which the displaced 'microplates'16 were eventually incorporated17,18? Here we present new palaeomagnetic results from tuffs and associated volcaniclastic rocks of early Cretaceous age from the Yukon-Kuskokwin delta region in western Alaska. These rocks were probably overprinted during the Cretaceous long normal polarity interval, although a remagnetization event as recent as Palaeocene cannot be ruled out. This overprint direction is not appreciably discordant from the expected late Cretaceous direction for cratonal North America. The implied absence of appreciable northward displacement for this region is consistent with the general late Mesozoic-early Tertiary tectonic pattern for Alaska, based on more definitive studies: little to no poleward displacement for central Alaska, though substantially more northward drift for the 'southern Alaska terranes' (comprising Alaska Peninsula, Kodiak Island, Prince William Sound area, and Matunuska Valley) since late Cretaceous to Palaeocene time. ?? 1983 Nature Publishing Group.

Explosive radiation of Malpighiales supports a mid-cretaceous origin of modern tropical rain forests.

PubMed

Davis, Charles C; Webb, Campbell O; Wurdack, Kenneth J; Jaramillo, Carlos A; Donoghue, Michael J

2005-03-01

Fossil data have been interpreted as indicating that Late Cretaceous tropical forests were open and dry adapted and that modern closed-canopy rain forest did not originate until after the Cretaceous-Tertiary (K/T) boundary. However, some mid-Cretaceous leaf floras have been interpreted as rain forest. Molecular divergence-time estimates within the clade Malpighiales, which constitute a large percentage of species in the shaded, shrub, and small tree layer in tropical rain forests worldwide, provide new tests of these hypotheses. We estimate that all 28 major lineages (i.e., traditionally recognized families) within this clade originated in tropical rain forest well before the Tertiary, mostly during the Albian and Cenomanian (112-94 Ma). Their rapid rise in the mid-Cretaceous may have resulted from the origin of adaptations to survive and reproduce under a closed forest canopy. This pattern may also be paralleled by other similarly diverse lineages and supports fossil indications that closed-canopy tropical rain forests existed well before the K/T boundary. This case illustrates that dated phylogenies can provide an important new source of evidence bearing on the timing of major environmental changes, which may be especially useful when fossil evidence is limited or controversial.

Soot and palynologic analysis of Manson impact-related strata (Upper Cretaceous) of Iowa and South Dakota, USA

USGS Publications Warehouse

Varricchio, D.J.; Raven, R.F.; Wolbach, W.S.; Elsik, W.C.; Witzke, B.J.

2009-01-01

The Campanian Manson impact structure of Iowa represents the best-preserved, large-diameter complex crater within the continental U.S. To assess the timing and potential mode of crater infilling and the possible presence of an impact event horizon, we analyzed samples from both within and distal to the impact structure for their elemental carbon, soot and palynomorphs. Within the impact structure, identifiable soot occurred in fragmented impact breccia and suevite but not in lower impact-melt breccia. Although most of this soot likely represents reworking of material from older Cretaceous marine shales, one high soot concentration occurs with melt material in a Keweenawan Shale-Phanerozoic clast breccia mix. This represents the first association of soot and impact-generated materials within an impact structure and the best sample candidate for Manson impact-generated soot. No palynomorphs occurred in the impact melt breccia. Overlying suevite (Keweenawan Shale clast breccia) of the central peak yielded sparse and thermally altered palynomorphs, indicating deposition prior to full cooling of the crater debris. Presence of easily degraded soot also argues for rapid backfilling of the crater. Distal samples from South Dakota represent the Sharon Springs and Crow Creek members of the Pierre Shale 230 km northwest of the Manson impact structure. Although containing shocked grains, the Crow Creek preserves no soot. In contrast, the Sharon Springs, generally considered as predating the Manson impact, has significant soot quantities. Palynomorphs differ markedly across the unconformity separating the two members with the Crow Creek containing more terrestrial forms, normapolles, and older reworked palynomorphs, consistent with a terrestrial impact to the east. Origin of the Sharon Springs soot remains unclear. Given soot occurrence within four of the five Cretaceous marine units sampled, the relatively shallow, anoxic bottom conditions of the Western Interior Cretaceous

Volcanostratigraphy, petrography and petrochemistry of Late Cretaceous volcanic rocks from the Görele area (Giresun, NE Turkey)

NASA Astrophysics Data System (ADS)

Oguz, Simge; Aydin, Faruk; Baser, Rasim

2015-04-01

In this study, we have reported for lithological, petrographical and geochemical features of late Cretaceous volcanic rocks from the Çanakçı and the Karabörk areas in the south-eastern part of Görele (Giresun, NE Turkey) in order to investigate their origin and magmatic evolution. Based on the previous ages and recent volcano-stratigraphic studies, the late Cretaceous time in the study area is characterized by an intensive volcanic activity that occurred in two different periods. The first period of the late Cretaceous volcanism (Cenomanian-Santonian; 100-85 My), conformably overlain by Upper Jurassic-Lower Cretaceous massive carbonates (Berdiga Formation), is represented by bimodal units consisting of mainly mafic rock series (basaltic-andesitic lavas and hyaloclastites, dikes and sills) in the lower part (Çatak Formation), and felsic rock series (dacitic lavas and hyaloclastites, crystal- and pyrite-bearing tuffs) in the upper part (Kızılkaya Formation). The second period of the late Cretaceous volcanism (Santonian-Late Campanian; 85-75 Ma) is also represented by bimodal character and again begins with mafic rock suites (basaltic-basaltic andesitic lavas and hyaloclastites) in the lower part (Çağlayan Formation), and grades upward into felsic rock suites (biotite-bearing rhyolitic lavas, ignimbrites and hyaloclastites) through the upper part (Tirebolu Formation). These bimodal units are intercalated with volcanic conglomerates-sandstones, claystones, marl and red pelagic limestones throughout the volcanic sequence, and the felsic rock series have a special important due to hosting of volcanogenic massive sulfide deposits in the region. All volcano-sedimentary units are covered by Tonya Formation (Late Campanian-Paleocene) containing calciturbidites, biomicrites and clayey limestones. The mafic rocks in the two volcanic periods generally include basalt, basaltic andesite and minor andesite, whereas felsic volcanics of the first period mainly consists of

Mummified precocial bird wings in mid-Cretaceous Burmese amber

PubMed Central

Xing, Lida; McKellar, Ryan C.; Wang, Min; Bai, Ming; O'Connor, Jingmai K.; Benton, Michael J.; Zhang, Jianping; Wang, Yan; Tseng, Kuowei; Lockley, Martin G.; Li, Gang; Zhang, Weiwei; Xu, Xing

2016-01-01

Our knowledge of Cretaceous plumage is limited by the fossil record itself: compression fossils surrounding skeletons lack the finest morphological details and seldom preserve visible traces of colour, while discoveries in amber have been disassociated from their source animals. Here we report the osteology, plumage and pterylosis of two exceptionally preserved theropod wings from Burmese amber, with vestiges of soft tissues. The extremely small size and osteological development of the wings, combined with their digit proportions, strongly suggests that the remains represent precocial hatchlings of enantiornithine birds. These specimens demonstrate that the plumage types associated with modern birds were present within single individuals of Enantiornithes by the Cenomanian (99 million years ago), providing insights into plumage arrangement and microstructure alongside immature skeletal remains. This finding brings new detail to our understanding of infrequently preserved juveniles, including the first concrete examples of follicles, feather tracts and apteria in Cretaceous avialans. PMID:27352215

Mummified precocial bird wings in mid-Cretaceous Burmese amber.

PubMed

Xing, Lida; McKellar, Ryan C; Wang, Min; Bai, Ming; O'Connor, Jingmai K; Benton, Michael J; Zhang, Jianping; Wang, Yan; Tseng, Kuowei; Lockley, Martin G; Li, Gang; Zhang, Weiwei; Xu, Xing

2016-06-28

Our knowledge of Cretaceous plumage is limited by the fossil record itself: compression fossils surrounding skeletons lack the finest morphological details and seldom preserve visible traces of colour, while discoveries in amber have been disassociated from their source animals. Here we report the osteology, plumage and pterylosis of two exceptionally preserved theropod wings from Burmese amber, with vestiges of soft tissues. The extremely small size and osteological development of the wings, combined with their digit proportions, strongly suggests that the remains represent precocial hatchlings of enantiornithine birds. These specimens demonstrate that the plumage types associated with modern birds were present within single individuals of Enantiornithes by the Cenomanian (99 million years ago), providing insights into plumage arrangement and microstructure alongside immature skeletal remains. This finding brings new detail to our understanding of infrequently preserved juveniles, including the first concrete examples of follicles, feather tracts and apteria in Cretaceous avialans.

Carbon isotopic compositions of organic matter across continental Cretaceous-Tertiary (K-T) boundary sections: Implications for paleoenvironment after the K-T impact event