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Sample records for cryogenic distillation column

  1. Efficiencies of trays in cryogenic distillation columns

    NASA Astrophysics Data System (ADS)

    Biddulph, M. W.

    1986-01-01

    This Paper considers the behaviour of the distillation trays in conventional use in cryogenic air separation plants. An earlier study showed that the trays should operate at higher efficiencies than plant experience would indicate. This conclusion was based on the assumption of uniform liquid flow across the trays. In practice, stagnant zones can occur which reduce the efficiency. A study of a small hole-size tray, rectangular in shape, providing uniform flow has confirmed the predictions of the theoretical model by producing high efficiencies. These results, together with those from the earlier study, provide an indication of the benefits of improving the flow behaviour of air separation distillation trays.

  2. Stabilization of the Circulation Flow of the Cryogenic Distillation Column

    NASA Astrophysics Data System (ADS)

    Juromskiy, V. M.

    Two-circuit system of automatic stabilization of the hydrodynamics of the cryogenic distillation column is considered. Control system eliminates flooding/depletion of column in long-term mode of operation when the accuracy of stabilization of the circulation flow is better than 1%.

  3. Design and Operation of Cryogenic Distillation Research Column for Ultra-Low Background Experiments

    NASA Astrophysics Data System (ADS)

    Chiller, Christopher; Alanson Chiller, Angela; Jasinski, Benjamin; Snyder, Nathan; Mei, Dongming

    2013-04-01

    Motivated by isotopically enriched germanium (76Ge and 73Ge) for monocrystalline crystal growth for neutrinoless double-beta decay and dark matter experiments, a cryogenic distillation research column was developed. Without market availability of distillation columns in the temperature range of interest with capabilities necessary for our purposes, we designed, fabricated, tested, refined and operated a two-meter research column for purifying and separating gases in the temperature range from 100-200K. Due to interest in defining stratification, purity and throughput optimization, capillary lines were integrated at four equidistant points along the length of the column such that real-time residual gas analysis could guide the investigation. Interior gas column temperatures were monitored and controlled within 0.1oK accuracy at the top and bottom. Pressures were monitored at the top of the column to four significant figures. Subsequent impurities were measured at partial pressures below 2E-8torr. We report the performance of the column in this paper.

  4. Experimental results of hydrogen distillation at the low power cryogenic column for the production of deuterium depleted hydrogen

    SciTech Connect

    Alekseev, I.; Fedorchenko, O.; Kravtsov, P.; Vasilyev, A.; Vznuzdaev, M.

    2008-07-15

    The Deuterium Removal Unit (DRU) has been designed and built at the Petersburg Nuclear Physics Inst. (PNPI) to produce isotopically pure hydrogen with deuterium content less than 1 ppm. The cryogenic distillation column of 2.2 cm inner diameter and 155 cm packing height is the main element of the DRU. Column performances at different hydrogen distillation operating modes have been measured. The height equivalent to theoretical plate (HETP) for the column is 2.2 cm and almost constant over a wide range of vapour flow rates. Deuterium depleted hydrogen with a deuterium content of less than 0.1 ppm was produced in required quantity. (authors)

  5. Distillation Column Modeling Tools

    SciTech Connect

    2001-09-01

    Advanced Computational and Experimental Techniques will Optimize Distillation Column Operation. Distillation is a low thermal efficiency unit operation that currently consumes 4.8 quadrillion BTUs of energy...

  6. Distillation Column Flooding Predictor

    SciTech Connect

    2002-02-01

    This factsheet describes a research project whose goal is to develop the flooding predictor, an advanced process control strategy, into a universally useable tool that will maximize the separation yield of a distillation column.

  7. Distillation Column Flooding Predictor

    SciTech Connect

    George E. Dzyacky

    2010-11-23

    The Flooding Predictor™ is a patented advanced control technology proven in research at the Separations Research Program, University of Texas at Austin, to increase distillation column throughput by over 6%, while also increasing energy efficiency by 10%. The research was conducted under a U. S. Department of Energy Cooperative Agreement awarded to George Dzyacky of 2ndpoint, LLC. The Flooding Predictor™ works by detecting the incipient flood point and controlling the column closer to its actual hydraulic limit than historical practices have allowed. Further, the technology uses existing column instrumentation, meaning no additional refining infrastructure is required. Refiners often push distillation columns to maximize throughput, improve separation, or simply to achieve day-to-day optimization. Attempting to achieve such operating objectives is a tricky undertaking that can result in flooding. Operators and advanced control strategies alike rely on the conventional use of delta-pressure instrumentation to approximate the column’s approach to flood. But column delta-pressure is more an inference of the column’s approach to flood than it is an actual measurement of it. As a consequence, delta pressure limits are established conservatively in order to operate in a regime where the column is never expected to flood. As a result, there is much “left on the table” when operating in such a regime, i.e. the capacity difference between controlling the column to an upper delta-pressure limit and controlling it to the actual hydraulic limit. The Flooding Predictor™, an innovative pattern recognition technology, controls columns at their actual hydraulic limit, which research shows leads to a throughput increase of over 6%. Controlling closer to the hydraulic limit also permits operation in a sweet spot of increased energy-efficiency. In this region of increased column loading, the Flooding Predictor is able to exploit the benefits of higher liquid

  8. Cryogenic distillation facility for isotopic purification of protium and deuterium

    NASA Astrophysics Data System (ADS)

    Alekseev, I.; Arkhipov, Ev.; Bondarenko, S.; Fedorchenko, O.; Ganzha, V.; Ivshin, K.; Kammel, P.; Kravtsov, P.; Petitjean, C.; Trofimov, V.; Vasilyev, A.; Vasyanina, T.; Vorobyov, A.; Vznuzdaev, M.

    2015-12-01

    Isotopic purification of the protium and deuterium is an important requirement of many physics experiments. A cryogenic facility for high-efficiency separation of hydrogen isotopes with a cryogenic distillation column as the main element is described. The instrument is portable, so that it can be used at the experimental site. It was designed and built at the Petersburg Nuclear Physics Institute, Gatchina, Russia. Fundamental operating parameters have been measured including a liquid holdup in the column packing, the pressure drops across the column and the purity of the product at different operating modes. A mathematical model describes expected profiles of hydrogen isotope concentration along the distillation column. An analysis of ortho-parahydrogen isomeric composition by gas chromatography was used for evaluation of the column performance during the tuning operations. The protium content during deuterium purification (≤100 ppb) was measured using gas chromatography with accumulation of the protium in the distillation column. A high precision isotopic measurement at the Institute of Particle Physics, ETH-Zurich, Switzerland, provided an upper bound of the deuterium content in protium (≤6 ppb), which exceeds all commercially available products.

  9. Cryogenic distillation facility for isotopic purification of protium and deuterium

    SciTech Connect

    Alekseev, I.; Arkhipov, Ev.; Bondarenko, S.; Fedorchenko, O.; Ganzha, V.; Ivshin, K.; Kravtsov, P. Trofimov, V.; Vasilyev, A.; Vasyanina, T.; Vorobyov, A.; Vznuzdaev, M.; Kammel, P.; Petitjean, C.

    2015-12-15

    Isotopic purification of the protium and deuterium is an important requirement of many physics experiments. A cryogenic facility for high-efficiency separation of hydrogen isotopes with a cryogenic distillation column as the main element is described. The instrument is portable, so that it can be used at the experimental site. It was designed and built at the Petersburg Nuclear Physics Institute, Gatchina, Russia. Fundamental operating parameters have been measured including a liquid holdup in the column packing, the pressure drops across the column and the purity of the product at different operating modes. A mathematical model describes expected profiles of hydrogen isotope concentration along the distillation column. An analysis of ortho-parahydrogen isomeric composition by gas chromatography was used for evaluation of the column performance during the tuning operations. The protium content during deuterium purification (≤100 ppb) was measured using gas chromatography with accumulation of the protium in the distillation column. A high precision isotopic measurement at the Institute of Particle Physics, ETH-Zurich, Switzerland, provided an upper bound of the deuterium content in protium (≤6 ppb), which exceeds all commercially available products.

  10. Neural network modeling of distillation columns

    SciTech Connect

    Baratti, R.; Vacca, G.; Servida, A.

    1995-06-01

    Neural network modeling (NNM) was implemented for monitoring and control applications on two actual distillation columns: the butane splitter tower and the gasoline stabilizer. The two distillation columns are in operation at the SARAS refinery. Results show that with proper implementation techniques NNM can significantly improve column operation. The common belief that neural networks can be used as black-box process models is not completely true. Effective implementation always requires a minimum degree of process knowledge to identify the relevant inputs to the net. After background and generalities on neural network modeling, the paper describes efforts on the development of neural networks for the two distillation units.

  11. Investigation related to hydrogen isotopes separation by cryogenic distillation

    SciTech Connect

    Bornea, A.; Zamfirache, M.; Stefanescu, I.; Preda, A.; Balteanu, O.; Stefan, I.

    2008-07-15

    Research conducted in the last fifty years has shown that one of the most efficient techniques of removing tritium from the heavy water used as moderator and coolant in CANDU reactors (as that operated at Cernavoda (Romania)) is hydrogen cryogenic distillation. Designing and implementing the concept of cryogenic distillation columns require experiments to be conducted as well as computer simulations. Particularly, computer simulations are of great importance when designing and evaluating the performances of a column or a series of columns. Experimental data collected from laboratory work will be used as input for computer simulations run at larger scale (for The Pilot Plant for Tritium and Deuterium Separation) in order to increase the confidence in the simulated results. Studies carried out were focused on the following: - Quantitative analyses of important parameters such as the number of theoretical plates, inlet area, reflux flow, flow-rates extraction, working pressure, etc. - Columns connected in series in such a way to fulfil the separation requirements. Experiments were carried out on a laboratory-scale installation to investigate the performance of contact elements with continuous packing. The packing was manufactured in our institute. (authors)

  12. Experimental investigation on hydrogen cryogenic distillation equipped with package made by ICIT

    SciTech Connect

    Bornea, A.; Zamfirache, M.; Stefan, L.; Stefanescu, I.; Preda, A.

    2015-03-15

    ICIT (Institute for Cryogenics and Isotopic Technologies) has used its experience in cryogenic water distillation process to propose a similar process for hydrogen distillation that can be used in detritiation technologies. This process relies on the same packages but a stainless filling is tested instead of the phosphorous bronze filling used for water distillation. This paper presents two types of packages developed for hydrogen distillation, both have a stainless filling but it differs in terms of density, exchange surface and specific volume. Performance data have been obtained on laboratory scale. In order to determine the characteristics of the package, the installation was operated in the total reflux mode, for different flow rate for the liquid. There were made several experiments considering different operating conditions. Samples extracted at the top and bottom of cryogenic distillation column allowed mathematical processing to determine the separation performance. The experiments show a better efficiency for the package whose exchange surface was higher and there were no relevant differences between both packages as the operating pressure of the cryogenic column was increasing. For a complete characterization of the packages, future experiments will be considered to determine performance at various velocities in the column and their correlation with the pressure in the column. We plan further experiments to separate tritium from the mixture of isotopes DT, having in view that our goal is to apply this results to a detritiation plant.

  13. Final Report, Distillation Column Flooding Predictor

    SciTech Connect

    George E. Dzyacky

    2003-05-31

    The Flooding Predictor is an advanced process control strategy comprising a patented pattern-recognition methodology that identifies pre-flood patterns discovered to precede flooding events in distillation columns. The grantee holds a U.S. patent on the modeling system. The technology was validated at the Separations Research Program, The University of Texas at Austin under a grant from the U. S. Department of Energy, Inventions & Innovation Program. Distillation tower flooding occurs at abnormally high vapor and/or liquid rates. The loss in tray efficiencies is attributed to unusual behavior of liquid inventories inside the column leading to conditions of flooding of the space in between trays with liquid. Depending on the severity of the flood condition, consequences range from off spec products to equipment damage and tower shutdown. This non-intrusive pattern recognition methodology, processes signal data obtained from existing column instrumentation. Once the pattern is identified empirically, it is modeled and coded into the plant's distributed control system. The control system is programmed to briefly "unload" the tower each time the pattern appears. The unloading takes the form of a momentary reduction in column severity, e.g., decrease bottom temperature, reflux or tower throughput. Unloading the tower briefly at the pre-flood state causes long-term column operation to become significantly more stable - allowing an increase in throughput and/or product purity. The technology provides a wide range of value between optimization and flooding. When a distillation column is not running at capacity, it should be run in such a way ("pushed") that optimal product purity is achieved. Additional benefits include low implementation and maintenance costs, and a high level of console operator acceptance. The previous commercial applications experienced 98% uptime over a four-year period. Further, the technology is unique in its ability to distinguish between different

  14. Distillation column for the XENON1T experiment

    NASA Astrophysics Data System (ADS)

    Fieguth, Alexander; XENON Collaboration

    2016-05-01

    The XENON1T experiment will probe a new parameter space in the direct dark matter search. Besides the enlargement of target mass to the ton scale, a further background reduction with respect to its predecessor XENON100 is necessary. A major contribution to the intrinsic contamination is the β-decaying isotope 85Kr, which leads to the requirement of a concentration less than 0.2 ppt of natural krypton in xenon. Its removal from the xenon gas is achieved by cryogenic distillation. For the new experiment a custom-build distillation column with a separation factor larger than 105 and a throughput of 3kg/h has been designed and built at the University of Muenster. Furthermore its performance has been characterized using different trace gas detection techniques, e.g. a novel 83mKr-tracer method, and its functionality has been tested successfully. The distillation column, which is installed and commissioned at the XENON1T experiment, is ready to process the 3.5 tons of xenon.

  15. Continuous and Batch Distillation in an Oldershaw Tray Column

    ERIC Educational Resources Information Center

    Silva, Carlos M.; Vaz, Raquel V.; Santiago, Ana S.; Lito, Patricia F.

    2011-01-01

    The importance of distillation in the separation field prompts the inclusion of distillation experiments in the chemical engineering curricula. This work describes the performance of an Oldershaw column in the rectification of a cyclohexane/n-heptane mixture. Total reflux distillation, continuous rectification under partial reflux, and batch…

  16. An Automated Distillation Column for the Unit Operations Laboratory

    ERIC Educational Resources Information Center

    Perkins, Douglas M.; Bruce, David A.; Gooding, Charles H.; Butler, Justin T.

    2005-01-01

    A batch distillation apparatus has been designed and built for use in the undergraduate unit operations laboratory course. The column is fully automated and is accompanied by data acquisition and control software. A mixture of 1­-propanol and 2-­propanol is separated in the column, using either a constant distillate rate or constant composition…

  17. Tritium Isotope Separation Using Adsorption-Distillation Column

    SciTech Connect

    Fukada, Satoshi

    2005-07-15

    In order to miniaturize the height of a distillation tower for the detritiation of waste water from fusion reactors, two experiments were conducted: (1) liquid frontal chromatography of tritium water eluting through an adsorption column and (2) water distillation using a column packed with adsorbent particles. The height of the distillation tower depends on the height equivalent to a theoretical plate, HETP, and the equilibrium isotope separation factor, {alpha}{sub H-T}{sup equi}. The adsorption action improved not only HETP but also {alpha}{sub H-T}{sup equi}. Since the adsorption-distillation method proposed here can shorten the tower height with keeping advantages of the distillation, it may bring an excellent way for miniaturizing the distillation tower to detritiate a large amount of waste water from fusion reactors.

  18. Design and minimum reflux calculations for multicomponent reactive distillation columns

    SciTech Connect

    Barbosa, D.; Doherty, M.F.

    1987-01-01

    A new set of transformed composition variables is introduced to simplify the design equations for single-feed, multicomponent reactive distillation columns. Based on these equations, a general method of calculating minimum reflux ratios for reactive distillation columns is presented. The new composition variables are also used to derive simple relationships between the dependent design variables, which are not evident when the design equations are written in terms of mole fractions.

  19. The setup of an extraction system coupled to a hydrogen isotopes distillation column

    SciTech Connect

    Zamfirache, M.; Bornea, A.; Stefanescu, I.; Bidica, N.; Balteanu, O.; Bucur, C.

    2008-07-15

    Among the most difficult problems of cryogenic distillation one stands apart: the extraction of the heavy fraction. By an optimal design of the cycle scheme, this problem could be avoided. A 'worst case scenario' is usually occurring when the extracted fraction consists of one prevalent isotope such as hydrogen and small amounts of the other two hydrogen isotopes (deuterium and/or tritium). This situation is further complicated by two parameters of the distillation column: the extraction flow rate and the hold-up. The present work proposes the conceptual design of an extraction system associated to the cryogenic distillation column used in hydrogen separation processes. During this process, the heavy fraction (DT, T{sub 2}) is separated, its concentration being the highest at the bottom of the distillation column. From this place the extraction of the gaseous phase can now begin. Being filled with adsorbent, the extraction system is used to temporarily store the heavy fraction. Also the extraction system provides samples for the gas Chromatograph. The research work is focused on the existent pilot plant for tritium and deuterium separation from our institute to validate the experiments carried out until now. (authors)

  20. Intermediate reboiler and condenser arrangement for binary distillation columns

    SciTech Connect

    Agrawal, R.; Herron, D.M.

    1998-06-01

    The most thermodynamically efficient configuration for adding or removing heat from an intermediate location of an ideal binary distillation column distilling pure products is derived. The optimal policy requires that preconditioning of the feed be part of the overall decision-making process. The optimal configuration can be determined through the use of two parameters, {alpha}{sub IR} and {alpha}{sub IC}, that are solely functions of feed composition. Simple and readily usable heuristics using these parameters are developed that help instantly identify the most efficient selection among (1) totally vaporizing and returning a side-draw liquid stream from an intermediate location of the distillation column, (2) partially or totally vaporizing a portion of the given saturated liquid feed, (3) partially or totally condensing a portion of the given saturated vapor feed, and (4) totally condensing and returning a side-draw vapor stream from an intermediate location of the distillation column.

  1. Temperature cascade control of distillation columns

    SciTech Connect

    Wolff, E.A.; Skogestad, S.

    1996-02-01

    This paper examines how difficult control tasks are enhanced by introducing secondary measurements, creating control cascades. Temperature is much used as secondary measurement because of cheap implementation and quick and accurate response. Distillation is often operated in this manner due to slow or lacking composition measurements, although the benefits have hardly been investigated closely, especially for multivariable control applications. The authors therefore use distillation as the example when quantifying improvements in interaction and disturbance rejection. They also give analytical expressions for the secondary controller gain. The improvements are reached through simple cascade operation of the control system and require no complicated estimator function.

  2. Miniature Distillation Column for Producing LOX From Air

    NASA Technical Reports Server (NTRS)

    Rozzi, Jay C.

    2006-01-01

    The figure shows components of a distillation column intended for use as part of a system that produces high-purity liquid oxygen (LOX) from air by distillation. (The column could be easily modified to produce high-purity liquid nitrogen.) Whereas typical industrial distillation columns for producing high-purity liquid oxygen and/or nitrogen are hundreds of feet tall, this distillation column is less than 3 ft (less than about 0.9 m) tall. This column was developed to trickle-charge a LOX-based emergency oxygen system (EOS) for a large commercial aircraft. A description of the industrial production of liquid oxygen and liquid nitrogen by distillation is prerequisite to a meaningful description of the present miniaturized distillation column. Typically, such industrial production takes place in a chemical processing plant in which large quantities of high-pressure air are expanded in a turboexpander to (1) recover a portion of the electrical power required to compress the air and (2) partially liquefy the air. The resulting two-phase flow of air is sent to the middle of a distillation column. The liquid phase is oxygen-rich, and its oxygen purity increases as it flows down the column. The vapor phase is nitrogen-rich and its nitrogen purity increases as it flows up the column. A heater or heat exchanger, commonly denoted a reboiler, is at the bottom of the column. The reboiler is so named because its role is to reboil some of the liquid oxygen collected at the bottom of the column to provide a flow of oxygen-rich vapor. As the oxygen-rich vapor flows up the column, it absorbs the nitrogen in the down-flowing liquid by mass transfer. Once the vapor leaves the lower portion of the column, it interacts with down-flowing nitrogen liquid that has been condensed in a heat exchanger, commonly denoted a condenser, at the top of the column. Liquid oxygen and liquid nitrogen products are obtained by draining some of the purified product at the bottom and top of the column

  3. Kinetic azeotropy and design of reactive distillation columns

    SciTech Connect

    Mahajani, S.M.

    1999-01-01

    The reactive fixed points in the distillation maps of a reactive distillation column (RDC) with kinetically controlled reactions are identified and their role in deciding the design feasibility has been elucidated. The fixed points at which both reaction and distillation vectors have zero magnitudes correspond to the equilibrium fixed point. It is known that the relative positions of these points for the rectifying and stripping sections determine the value of the minimum reflux ratio. However, apart from these fixed points, there are certain fixed points in the distillation map at which, though the reaction and distillation vectors have nonzero magnitudes, they nullify the effects of each other. These points correspond to the kinetic fixed points and have a special significance. Their positions have direct influence on the feasible product composition. A simple example of an ideal ternary system undergoing a reaction 2B {longleftrightarrow} A + c has been illustrated to show the importance of kinetic azeotropy in the design aspects of RDC.

  4. A geometric design method for side-stream distillation columns

    SciTech Connect

    Rooks, R.E.; Malone, M.F.; Doherty, M.F.

    1996-10-01

    A side-stream distillation column may replace two simple columns for some applications, sometimes at considerable savings in energy and investment. This paper describes a geometric method for the design of side-stream columns; the method provides rapid estimates of equipment size and utility requirements. Unlike previous approaches, the geometric method is applicable to nonideal and azeotropic mixtures. Several example problems for both ideal and nonideal mixtures, including azeotropic mixtures containing distillation boundaries, are given. The authors make use of the fact that azeotropes or pure components whose classification in the residue curve map is a saddle can be removed as side-stream products. Significant process simplifications are found among some alternatives in example problems, leading to flow sheets with fewer units and a substantial savings in vapor rate.

  5. Tritum recovery system from waste water of fusion reactor using CECE and cryogenic-wall thermal diffusion column

    SciTech Connect

    Arita, T.; Yamanishi, T.; Iwai, Y.; Okuno, K.; Kobayashi, N.; Yamamoto, I.

    1996-12-31

    A system for recovery of tritium in water has been proposed. The system is composed of CECE (Combined Electrolysis Chemical Exchange) and CTD (Cryogenic-wall Thermal Diffusion) columns. A design study was carried out for the two cases: the waste water processing in fusion facilities; and the tritium recovery from heavy water in a fission reactor in Japan. The size and power consumption of the system can greatly be reduced by using the CECE column than the system of WD (Water Distillation) columns. The operation and maintenance of the CTD column are quite easier than the CD (Cryogenic Distillation) column. The proposed system would be applicable for some cases such as the waste water processing in tritium facilities, where the processing flow rate is relatively small. 11 refs., 4 figs., 6 tabs.

  6. Experimental study of wave propagation dynamics of binary distillation columns

    SciTech Connect

    Hwang, Y.L.; Graham, G.K.; Keller, G.E. II; Ting, J.; Helfferich, F.G.

    1996-10-01

    High-purity distillation columns are typically difficult to control because of their severely nonlinear behavior reflected by their sharp composition and temperature profiles. The dynamic behavior of such a column, as characterized by the movement of its sharp profile, was elucidated by a nonlinear wave theory established previously. With binary alcohol mixtures, this study provides an experimental observation of such wave-propagation dynamics of a 40-tray stripping column and a 50-tray fractionation column in response to step disturbances of feed composition, feed flow rate, and reboiler heat supply. These experimental results have verified that the sharp profile in a high-purity column moves as a constant-pattern wave and that the nonlinear wave theory predicts its velocity satisfactorily with very simple mathematics. Results also demonstrate the asymmetric dynamics of the transitions between two steady states.

  7. Simple, analytical criteria for the sequencing of distillation columns

    SciTech Connect

    Malone, M.F.; Douglas, J.M.; Glinos, K.; Marquez, F.E.

    1985-04-01

    A quantitative criterion for the selection of simple distillation sequences is derived for ideal mixtures. A simple cost model, along with a short-cut solution of Underwood's equations, gives an analytical form for the total vapor rate, which is the key design variable. The results for column sequencing that are based on the analytical criterion agree well with more exact solutions, but they indicate that in numerous situations the commonly accepted heuristics are incorrect.

  8. Determination of the separation efficiencies of a single-stage cryogenic distillation setup to remove krypton out of xenon by using a (83m)Kr tracer method.

    PubMed

    Rosendahl, S; Brown, E; Cristescu, I; Fieguth, A; Huhmann, C; Lebeda, O; Murra, M; Weinheimer, C

    2015-11-01

    The separation of krypton and xenon is of particular importance for the field of direct dark matter search with liquid xenon detectors. The intrinsic contamination of the xenon with radioactive (85)Kr makes a significant background for these kinds of low count-rate experiments and has to be removed beforehand. This can be achieved by cryogenic distillation, a technique widely used in industry, using the different vapor pressures of krypton and xenon. In this paper, we present an investigation on the separation performance of a single stage distillation system using a radioactive (83m)Kr-tracer method. The separation characteristics under different operation conditions are determined for very low concentrations of krypton in xenon at the level of (83m)Kr/Xe = 1.9 ⋅ 10(-15), demonstrating, that cryogenic distillation in this regime is working. The observed separation is in agreement with the expectation from the different volatilities of krypton and xenon. This cryogenic distillation station is the first step on the way to a multi-stage cryogenic distillation column for the next generation of direct dark matter experiment XENON1T. PMID:26628169

  9. Demonstration of ``regulatory`` process controls on the TSTA cryogenic distillation system

    SciTech Connect

    Willms, R.S.; Sherman, R.H.; Cole, S.P.; Riggs, J.B.; Okuno, K.

    1995-04-01

    Due to the nature of its fusion reaction, most of the DT used to fuel the International Thermonuclear Experimental Reactor (ITER) will exit unreacted. This effluent will be purified by the fuel cleanup system so that the isotope separation system (ISS) will be fed only hydrogen isotopes and possibly some helium. The ISS will separate this feed into streams nominally composed of He/H2/HD, D2, DT, and T2. These products will be recycled through appropriate fueling systems back to the fusion reactor or returned to storage. The ISS will have to respond properly to feed conditions which change rapidly. Feed changes will propagate quickly through the entire cascade. It is apparent that an automatic control system will be required to respond to these changes and maintain product quality. It is convenient to divide such a distillation control system into `regulatory` controls and composition controls. The `regulatory` controls include liquid levels, flowrates, reboiler heats, and pressure. A system of regulatory controls has been devised and installed on the four-column cascade of cryogenic columns at the Tritium Systems Test Assembly (TSTA) at Los Alamos National Laboratory. This tritium-compatible ISS is designed for approximately 1/10 the ITER flowrate and is dedicated to fusion fuel studies. Details of the TSTA ISS have been published previously.

  10. Floral aroma improvement of Muscat spirits by packed column distillation with variable internal reflux.

    PubMed

    Matias-Guiu, Pau; Rodríguez-Bencomo, Juan José; Orriols, Ignacio; Pérez-Correa, José Ricardo; López, Francisco

    2016-12-15

    The organoleptic quality of wine distillates depends on raw materials and the distillation process. Previous work has shown that rectification columns in batch distillation with fixed reflux rate are useful to obtain distillates or distillate fractions with enhanced organoleptic characteristics. This study explores variable reflux rate operating strategies to increase the levels of terpenic compounds in specific distillate fractions to emphasize its floral aroma. Based on chemical and sensory analyses, two distillate heart sub-fractions obtained with the best operating strategy found, were compared with a distillate obtained in a traditional alembic. Results have shown that a drastic reduction of the reflux rate at an early stage of the heart cut produced a distillate heart sub-fraction with a higher concentration of terpenic compounds and lower levels of negative aroma compounds. Therefore, this sub-fraction presented a much more noticeable floral aroma than the distillate obtained with a traditional alembic. PMID:27451153

  11. Cryogenic focussing, ohmically heated on-column trap

    NASA Technical Reports Server (NTRS)

    Springston, Stephen R.

    1991-01-01

    A procedure is described for depositing a conductive layer of gold on the exterior of a fused-silica capillary used in gas chromatography. By subjecting a section of the column near the inlet to a thermal cycle of cryogenic cooling and ohmic heating, volatile samples are concentrated and subsequently injected. The performance of this trap as a chromatographic injector is demonstrated. Several additional applications are suggested and the unique properties of this device are discussed.

  12. Cryogenic focussing, ohmically heated on-column trap

    SciTech Connect

    Springston, S.R.

    1991-12-01

    A procedure is described for depositing a conductive layer of gold on the exterior of a fused-silica capillary used in gas chromatography. By subjecting a section of the column near the inlet to a thermal cycle of cryogenic cooling and ohmic heating, volatile samples are concentrated and subsequently injected. The performance of this trap as a chromatographic injector is demonstrated. Several additional applications are suggested and the unique properties of this device are discussed. 11 refs., 5 figs., 1 tab.

  13. Startup of distillation columns using profile position control based on nonlinear wave model

    SciTech Connect

    Han, M.; Park, S. |

    1999-04-01

    Startup of distillation columns is a very challenging control problem because of its strong nonlinearity and a wide operating range during the transient period. A nonlinear wave model captures the essential dynamic behavior of the distillation process so that it is possible to deal with the difficulties encountered during startup operation. This paper is concerned with the startup of distillation systems using nonlinear wave model based control developed by Han and Park. This control scheme uses profile positions as controlled variables and is based on the nonlinear wave model by Hwang and generic model control scheme by Lee and Sullivan. It can be applied to a binary or a multicomponent distillation system that can be represented as a pseudobinary. The proposed control scheme is shown by simulation studies to provide a safe and economic startup operation not only for dual composition control of a simple distillation column but also for a complex distillation configuration.

  14. Assessing Safety in Distillation Column Using Dynamic Simulation and Failure Mode and Effect Analysis (FMEA)

    NASA Astrophysics Data System (ADS)

    Werner, Suhendra; Fred, Witt; Compart

    Safety assessment becomes an important activity in chemical industries since the need to comply with general legal requirements in addition to meet safer plant and profit. This paper reviews some most frequently causes of distillation column malfunction. First, analysis of case histories will be discussed for providing guidelines in identifying potential trouble spots in distillation column. A dynamic simulation for operational failure is simulated as the basis for assessing the consequences. A case study will be used from a side stream distillation column to show the implementation of the concept. A framework for assessing safety in the column is proposed using Fault Mode and Effect Analysis (FMEA). Further, trouble-free operation in order to reduce the risk associated with column malfunction is described.

  15. Heat Transfer Study of Heat-Integrated Distillation Column (HIDiC) Using Simulation Techniques

    NASA Astrophysics Data System (ADS)

    Pulido, Jeffrey León; Martínez, Edgar Leonardo; Wolf, Maria Regina; Filho, Rubens Maciel

    2011-08-01

    Separation processes is largely used in petroleum refining and alcohol industries. Distillation columns consume a huge amount of energy in industrial process. Therefore, the concept of Heat-Integrated Distillation Column (HIDiC) was studied using simulation techniques in order to overcome this drawback. In this configuration the column is composed for two concentric sections called rectifying and stripping. The heat transfer is conducted from the rectifying section (which works at higher pressure and temperature) to the stripping section (which works at lower pressure and temperature) using the heat present in the process and decreasing the energy charge required by the reboiler. The HIDiC column offers great potential to reduce energy consumption compared to conventional columns. However, the complexity of the internal configuration requires the development of rigorous works that enable a better understanding of the column operation. For this reason, techniques of simulation were used through of computational software. The current work presents a heat transfer study in a concentric stage of a HIDiC column. The results obtained by Aspen Plus and CFD simulation showed the internal heat transfer in a concentric tray as a promissory configuration in order to decrease energy consumption in distillation processes.

  16. Determination of the separation efficiencies of a single-stage cryogenic distillation setup to remove krypton out of xenon by using a {sup 83m}Kr tracer method

    SciTech Connect

    Rosendahl, S. Brown, E.; Fieguth, A.; Huhmann, C.; Murra, M.; Weinheimer, C.; Cristescu, I.; Lebeda, O.

    2015-11-15

    The separation of krypton and xenon is of particular importance for the field of direct dark matter search with liquid xenon detectors. The intrinsic contamination of the xenon with radioactive {sup 85}Kr makes a significant background for these kinds of low count-rate experiments and has to be removed beforehand. This can be achieved by cryogenic distillation, a technique widely used in industry, using the different vapor pressures of krypton and xenon. In this paper, we present an investigation on the separation performance of a single stage distillation system using a radioactive {sup 83m}Kr-tracer method. The separation characteristics under different operation conditions are determined for very low concentrations of krypton in xenon at the level of {sup 83m}Kr/Xe = 1.9 ⋅ 10{sup −15}, demonstrating, that cryogenic distillation in this regime is working. The observed separation is in agreement with the expectation from the different volatilities of krypton and xenon. This cryogenic distillation station is the first step on the way to a multi-stage cryogenic distillation column for the next generation of direct dark matter experiment XENON1T.

  17. Modified method to improve the design of Petlyuk distillation columns

    PubMed Central

    2014-01-01

    Background A response surface analysis was performed to study the effect of the composition and feeding thermal conditions of ternary mixtures on the number of theoretical stages and the energy consumption of Petlyuk columns. A modification of the pre-design algorithm was necessary for this purpose. Results The modified algorithm provided feasible results in 100% of the studied cases, compared with only 8.89% for the current algorithm. The proposed algorithm allowed us to attain the desired separations, despite the type of mixture and the operating conditions in the feed stream, something that was not possible with the traditional pre-design method. The results showed that the type of mixture had great influence on the number of stages and on energy consumption. A higher number of stages and a lower consumption of energy were attained with mixtures rich in the light component, while higher energy consumption occurred when the mixture was rich in the heavy component. Conclusions The proposed strategy expands the search of an optimal design of Petlyuk columns within a feasible region, which allow us to find a feasible design that meets output specifications and low thermal loads. PMID:25061476

  18. TRENTA Facility for Trade-Off Studies Between Combined Electrolysis Catalytic Exchange and Cryogenic Distillation Processes

    SciTech Connect

    Cristescu, I.; Cristescu, I.R.; Doerr, L.; Glugla, M.; Hellriegel, G.; Schaefer, P.; Welte, S.; Kveton, O.; Murdoch, D

    2005-07-15

    One of the most used methods for tritium recovery from different sources of tritiated water is based on the combination between Combined Electrolysis Catalytic Exchange (CECE) and Cryogenic Distillation (CD) processes. The development, i.e. configuration, design and performance testing of critical components, of a tritium recovery system based on the combination CECE-CD is essential for both JET and ITER. For JET, a Water Detritiation System (WDS) is not only needed to process tritiated water which has already been accumulated from operation, but also for the tritiated water which will be generated during decommissioning. For ITER, the WDS is one of the key systems to control the tritium content in the effluents streams, to recover as much tritium as possible and consequently to minimize the impact on the environment. A cryogenic distillation facility with the aim to investigate the trade-off between CECE-CD, to validate different components and mathematical modelling software is current under development at Tritium Laboratory Karlsruhe (TLK) as an extension of the existing CECE facility.

  19. GOBF-ARMA based model predictive control for an ideal reactive distillation column.

    PubMed

    Seban, Lalu; Kirubakaran, V; Roy, B K; Radhakrishnan, T K

    2015-11-01

    This paper discusses the control of an ideal reactive distillation column (RDC) using model predictive control (MPC) based on a combination of deterministic generalized orthonormal basis filter (GOBF) and stochastic autoregressive moving average (ARMA) models. Reactive distillation (RD) integrates reaction and distillation in a single process resulting in process and energy integration promoting green chemistry principles. Improved selectivity of products, increased conversion, better utilization and control of reaction heat, scope for difficult separations and the avoidance of azeotropes are some of the advantages that reactive distillation offers over conventional technique of distillation column after reactor. The introduction of an in situ separation in the reaction zone leads to complex interactions between vapor-liquid equilibrium, mass transfer rates, diffusion and chemical kinetics. RD with its high order and nonlinear dynamics, and multiple steady states is a good candidate for testing and verification of new control schemes. Here a combination of GOBF-ARMA models is used to catch and represent the dynamics of the RDC. This GOBF-ARMA model is then used to design an MPC scheme for the control of product purity of RDC under different operating constraints and conditions. The performance of proposed modeling and control using GOBF-ARMA based MPC is simulated and analyzed. The proposed controller is found to perform satisfactorily for reference tracking and disturbance rejection in RDC. PMID:25956185

  20. Cryogenic distillative removal of CO/sub 2/ from high CO/sub 2/ content hydrocarbon containing streams

    SciTech Connect

    Goddin, C.S. Jr.

    1984-07-10

    Carbon dioxide is removed from a carbon dioxide containing hydrocarbon stream having a varying composition of light lean oil components in the C/sub 3/ through C/sub 10/ range. A light lean oil recycle stream of predetermined carbon number range is produced and utilized in the cryogenic distillative process.

  1. Large scale xenon purification using cryogenic distillation for dark matter detectors

    NASA Astrophysics Data System (ADS)

    Wang, Z.; Bao, L.; Hao, X. H.; Ju, Y. L.; Pushkin, K.; He, M.

    2014-11-01

    A high efficiency cryogenic distillation system for removal of radioactive krypton-85 (85Kr) from commercially available xenon (Xe) has been designed, developed and assessed to meet the requirements of high sensitivity, low background dark matter detection experiments. The concentration of krypton (Kr) in a commercial xenon product can be decreased from 10-9 to 10-12 mol/mol based on the theoretical design and simulation. The experimental measurements showed that the concentration of krypton was decreased to 10-11 mol/mol with 99% xenon collection efficiency at maximum flow rate of 5 kg/h. Over 500 kg of xenon has been purified using this system, which has been used as the detection medium in project Panda X, the first dark matter detector developed in China.

  2. The effects of thermodynamic data on the design and operation of distillation columns

    SciTech Connect

    Zeck, S. )

    1993-04-01

    The relative importance of various physical properties for distillation-column design and operation is classified. Vapor-liquid equilibrium data have a dominant effect. It is possible to quantify the effect of errors of relative volatility on the uncertainty of the number of stages required for a given simple binary separation problem by using the simplest, so-termed short-cut methods of column design, because the results obtained are, practically, the same as those found by more sophisticated methods. The same error in the relative volatility [alpha] leads to a sharply increasing uncertainty in the number of stages required as the value of [alpha] approaches unity.

  3. Azeotropic distillation in a middle vessel batch column. 1: Model formulation and linear separation boundaries

    SciTech Connect

    Cheong, W.; Barton, P.I.

    1999-04-01

    A mathematical model for the middle vessel batch distillation column (MVC) is developed using the concept of warped time analysis and used to study the qualitative dynamics of the MVC when it is used to separate multicomponent azeotropic mixtures. A limiting analysis is then developed for a MVC with an infinite number of trays, operated under infinite reflux/reboil ratios, under the assumption of linear separation boundaries. It is determined that, under limiting conditions, the distillate product drawn from the MVC is given by the {alpha} limit set of the MVC still pot composition, while the bottoms product drawn from the MVC is given by the {omega} limit set of the MVC still pot composition. The net product composition is determined by taking a convex combination of the two products. The notions of steering the still pot composition, the vector cone of possible motion for the still pot composition, and the equivalency of the MVC to the combined operation of a batch rectifier and a stripper are also explored. The definition of batch distillation regions for the MVC operated at a given value of the middle vessel parameter {lambda}, and the bifurcation of these regions with the variation of {lambda}, are investigated. Lastly, a mathematical model incorporating the concept of warped time is developed for a multivessel column. The MVC can be viewed as a specific case of the multivessel column.

  4. Azeotropic distillation in a middle vessel batch column. 2: Nonlinear separation boundaries

    SciTech Connect

    Cheong, W.; Barton, P.I.

    1999-04-01

    On the basis of the analytical tools developed for the middle vessel column (MVC) operated under limiting conditions, analysis of the qualitative dynamics of the MVC in separating an azeotropic mixture is extended to the more realistic case in which the separation boundaries are nonlinear. The differences between batch stripper pot composition boundaries and batch rectifier pot composition being able to cross these pot composition boundaries. On the basis of these insights, operating procedures are developed in which ternary azeotropic mixtures of acetone, benzene, and chloroform can be separated into their constituent pure components, a separation not achievable with either the batch stripper or the batch rectifier. The operating procedures suggested for separating the ternary azeotropic mixture of acetone, benzene, and chloroform in the MVC are then shown to be the time analogues of sequences of continuous distillation columns that achieve the same separation. On the basis of this space-time analogy, further analogies are developed between the MVC and a continuous column, and it is postulated that many complex separations currently achieved with sequences of continuous columns can also be achieved with a single MVC. Thus, the MVC represents the ultimate multipurpose solvent recovery technology, as it can handle, in a batch multipurpose mode. separations that will otherwise require a dedicated continuous distillation sequence. Finally, the characteristics of perfect MVC batch entrainers, which allow the complete separation of any azeotrope into its constituent pure components in a single MVC, are discussed.

  5. A hybrid feedback linearizing-Kalman filtering control algorithm for a distillation column.

    PubMed

    Jana, Amiya Kumar; Samanta, Amar Nath

    2006-01-01

    This paper studies the design of a discrete-time multivariable feedback linearizing control (FLC) structure. The control scheme included (i) a transformer [also called the input/output (I/O) linearizing state feedback law] that transformed the nonlinear u-y to a linearized v-y system, (ii) a closed-loop observer [extended Kalman filter (EKF)], which estimated the unmeasured states, and (iii) a conventional proportional integral (PI) controller that was employed around the v-y system as an external controller. To avoid the estimator design complexity, the design of EKF for a binary distillation column has been performed based on a reduced-order compartmental distillation model. Consequently, there is a significant process/predictor mismatch, and despite this discrepancy, the EKF estimated the required states of the simulated distillation column precisely. The FLC in conjunction with EKF (FLC-EKF) and that coupled with a measured composition-based reduced-order open-loop observer (FLC-MCROOLO) have been synthesized. The FLC structures showed better performance than the traditional proportional integral derivative controller. In practice, the presence of uncertainties and unknown disturbances are common, and in such situations, the proposed FLC-EKF control scheme ensured the superiority over the FLC-MCROOLO law. PMID:16480113

  6. Fault detection in the distillation column process using Kullback Leibler divergence.

    PubMed

    Aggoune, Lakhdar; Chetouani, Yahya; Raïssi, Tarek

    2016-07-01

    Chemical plants are complex large-scale systems which need designing robust fault detection schemes to ensure high product quality, reliability and safety under different operating conditions. The present paper is concerned with a feasibility study of the application of the black-box modeling method and Kullback Leibler divergence (KLD) to the fault detection in a distillation column process. A Nonlinear Auto-Regressive Moving Average with eXogenous input (NARMAX) polynomial model is firstly developed to estimate the nonlinear behavior of the plant. Furthermore, the KLD is applied to detect abnormal modes. The proposed FD method is implemented and validated experimentally using realistic faults of a distillation plant of laboratory scale. The experimental results clearly demonstrate the fact that proposed method is effective and gives early alarm to operators. PMID:27020311

  7. Soft sensor based composition estimation and controller design for an ideal reactive distillation column.

    PubMed

    Vijaya Raghavan, S R; Radhakrishnan, T K; Srinivasan, K

    2011-01-01

    In this research work, the authors have presented the design and implementation of a recurrent neural network (RNN) based inferential state estimation scheme for an ideal reactive distillation column. Decentralized PI controllers are designed and implemented. The reactive distillation process is controlled by controlling the composition which has been estimated from the available temperature measurements using a type of RNN called Time Delayed Neural Network (TDNN). The performance of the RNN based state estimation scheme under both open loop and closed loop have been compared with a standard Extended Kalman filter (EKF) and a Feed forward Neural Network (FNN). The online training/correction has been done for both RNN and FNN schemes for every ten minutes whenever new un-trained measurements are available from a conventional composition analyzer. The performance of RNN shows better state estimation capability as compared to other state estimation schemes in terms of qualitative and quantitative performance indices. PMID:20887987

  8. On the use of intermediate reboilers in the rectifying section and condensers in the stripping section of a distillation column

    SciTech Connect

    Agrawal, R.; Fidkowski, Z.T.

    1996-08-01

    Advantages of an intermediate reboiler in the stripping section of a distillation column and an intermediate condenser in the rectifying section are well-known. For highly nonideal mixtures the distillation process can be improved by placing an intermediate reboiler in the rectifying section of the column or an intermediate condenser in the stripping section, which is counterintuitive. In consequence the more expensive heating utility used in the bottom reboiler can be partially replaced with a less expensive heating medium (at a lower temperature) used in the intermediate reboiler. Similarly, a portion of the condensing duty from the top condenser can be replaced with the less expensive condensing duty (at a higher temperature) in the intermediate condenser. This placement of reboilers (condensers) can be used to reduce the total number of stages in the distillation column with a lower (higher) level of utility. Operating and capital costs of the distillation process with an intermediate heat exchanger can be lower than those for a classic column. A simple method providing valuable insights on the possible placement of intermediate heat exchangers along the column is proposed. It is based on calculations of the vapor flow along the height of a reversible, binary distillation column performing the equivalent separation task.

  9. Penetration of different human pathogenic viruses into sand columns percolated with distilled water, groundwater, or wastewater.

    PubMed Central

    Dizer, H; Nasser, A; Lopez, J M

    1984-01-01

    The adsorption of several enteroviruses and rotavirus SA11 to sand from an aquifer in the Federal Republic of Germany was estimated in sand-filled columns loaded with ca. 10(7) PFU and run at a velocity of 2.5 m/day for 12 h. After either distilled water, groundwater, secondary effluent, or tertiary effluent was percolated, the sand core was slowly extruded out of the column and cut in 1-cm slices. The slices were eluted with nutrient broth, and the amount of viruses in the broth was estimated. The best adsorption was promoted by groundwater and tertiary effluent, followed by distilled water and secondary effluent. Similar experiments, carried out at different percolation rates, indicated that a 50-day underground stay of recharged water probably suffices to eliminate viruses in the groundwater-recharged tertiary effluent. However, when viruses and sand were incubated in the presence of the surfactants sodium dodecyl sulfate, nonyl phenol, dodigen 226, or alkylbenzylsulfonate, the adsorption of the viruses was substantially diminished. Experiments in the presence of nonyl phenol seem to indicate that hydrophobic interactions are involved in the adsorption of viruses to sand. PMID:6324676

  10. Azeotropic distillation in a middle vessel batch column. 3: Model validation

    SciTech Connect

    Cheong, W.; Barton, P.I.

    1999-04-01

    A dimensional time model of the middle vessel batch distillation column (MVC) is developed in the ABACUSS process modeling environment, and simulations are conducted to validate the theoretical insights developed for the operation of the MVC based on a warped time model of the MVC. The qualitative dynamics of the MVC operated in the presence of linear separation boundaries are validated via simulations conducted on the ternary azeotropic mixture of acetone, chloroform, and methanol. It is also shown via simulation that the separation results obtained from a column with significant but reasonable amounts of holdup on the trays are not significantly different from a column in which holdup in the trays is assumed to be negligible. Theoretical operating policies for separating the azeotrope of acetone and chloroform using benzene as a batch entrainer are also validated using the ABACUSS model. Finally, the authors explore the advantages and disadvantages of different feasible operating policies for separating a mixture of acetone, benzene, and chloroform completely into its constituent pure components.

  11. Design and construction of a cryogenic distillation device for removal of krypton for liquid xenon dark matter detectors.

    PubMed

    Wang, Zhou; Bao, Lei; Hao, Xihuan; Ju, Yonglin

    2014-01-01

    Liquid xenon (Xe) is one of the commendable detecting media for the dark matter detections. However, the small content of radioactive krypton-85 ((85)Kr) always exists in the commercial xenon products. An efficient cryogenic distillation system to remove this krypton (Kr) from commercial xenon products has been specifically designed, developed, and constructed in order to meet the requirements of the dark matter experiments with high- sensitivity and low-background. The content of krypton in regular commercial xenon products can be reduced from 10(-9) to 10(-12), with 99% xenon collection efficiency at maximum flow rate of 5 kg/h (15SLPM). The purified xenon gases produced by this distillation system can be used as the detecting media in the project of Panda X, which is the first dark matter detector developed in China. PMID:24517821

  12. Research on the separation properties of empty-column gas chromatography (EC-GC) and conditions for simulated distillation (SIMDIS).

    PubMed

    Boczkaj, Grzegorz; Kamiński, Marian

    2013-10-01

    Previous studies have revealed it is possible to separate a high-boiling mixture by gas chromatography in empty fused-silica capillary tubing rather than in columns coated with stationary phase. Chromatographic separation occurs solely on the basis of the different boiling points of the substances separated. The high similarity of such separations to those in classic distillation seems advantageous when gas chromatography is used for simulated distillation. This paper presents results from further research on the separation properties of empty fused silica tubing. The efficiency of this chromatographic system has been examined. The usefulness of such conditions has been studied for simulated distillation, i.e. to determine the boiling-point distribution of complex mixtures, mainly petroleum fractions and products, on the basis of their retention relative to reference substances. The results obtained by use of empty-column gas chromatography (EC-GC) and by use of classical simulated distillation columns have been compared for solutes of different polarity. Studies revealed boiling points determined by EC-GC were more accurate than those obtained by the standard method of simulated distillation. PMID:23925798

  13. Simulation calculations for a catalytic exchange/cryogenic distillation hydrogen isotope separation process

    SciTech Connect

    Rodman, M.; Howard, D.W.

    1984-01-01

    Some of the aspects of the optimization and simulation calculations for the Moderator Detritiation Plant thay may be applicable to other processes are described. The FORTRAN optimization program and the CPES and PROCESS distillation calculation are covered.

  14. Effects of reflux ratio and feed conditions for the purification of bioethanol in a continuous distillation column

    NASA Astrophysics Data System (ADS)

    Dasan, Y. K.; Abdullah, M. A.; Bhat, A. H.

    2014-10-01

    Continuous distillation column was used for the purification of bioethanol from fermentation of molasses using Saccharomyces cerevisia. Bioethanol produced was at 8.32% (v/v) level. The efficiency of continuous distillation process was evaluated based on reflux ratio, and feed condition. The lab results were validated using COFE simulation Software. The analyses showed that both reflux ratio and feed condition had significant effects on the distillation process. Stages increased from 1.79 to 2.26 as the reflux ratio was decreased from 90% to 45% and the saturated feed produced lower mole fraction of desired product. We concluded that the lower reflux ratio with cold feed condition was suitable for higher mole fraction of top product.

  15. Design/retrofit targets of pump-around refluxes for better energy integration of a crude distillation column

    SciTech Connect

    Sharma, R.; Jindal, A.; Mandawala, D.; Jana, S.K.

    1999-06-01

    Crude oil distillation is a highly energy-intensive process and represents one of the most important areas for energy integration in a refinery. Current practice recovers useful energy by pump-around refluxes in type A columns for the preheating of crude oil in heat exchanger trains; however, energy-recovery targets are not well-defined or known a priori. This work presents a simple methodology for developing invariant column grand composite curves (CGCCs) for type U and type A columns using the well-established principles of pinch analysis and the refining-industry accepted Packie`s method for designing/rating crude columns. The CGCCs for type U and type A columns set the thermodynamic and practical heat-recovery targets, respectively. Since the CGCCs developed in this work are invariant with respect to pump-around reflux and depend only on the feed and product rates and specifications at given conditions of temperature and pressure, they set reflux-energy-recovery targets for either designing a new crude column or retrofitting an existing column. The application of this methodology is illustrated by means of a case study.

  16. COED Transactions, Vol. X, No. 5, May 1978. STAGEF, A Program to Compute the Internal Variables of an Operating Distillation Column.

    ERIC Educational Resources Information Center

    Marcovitz, Alan B., Ed.

    A digital computer program, STAGEF, designed for use with the distillation experiments in a typical undergraduate Chemical Engineering laboratory in Unit Operations is explained. The program enables the student to determine the rate of liquid overflow and vapor boil-up which leaves each tray within the distillation column. The student may also…

  17. Validating the Equilibrium Stage Model for an Azeotropic System in a Laboratorial Distillation Column

    ERIC Educational Resources Information Center

    Duarte, B. P. M.; Coelho Pinheiro, M. N.; Silva, D. C. M.; Moura, M. J.

    2006-01-01

    The experiment described is an excellent opportunity to apply theoretical concepts of distillation, thermodynamics of mixtures and process simulation at laboratory scale, and simultaneously enhance the ability of students to operate, control and monitor complex units.

  18. A novel 83mKr tracer method for characterizing xenon gas and cryogenic distillation systems

    NASA Astrophysics Data System (ADS)

    Rosendahl, S.; Bokeloh, K.; Brown, E.; Cristescu, I.; Fieguth, A.; Huhmann, C.; Lebeda, O.; Levy, C.; Murra, M.; Schneider, S.; V'enos, D.; Weinheimer, C.

    2014-10-01

    The radioactive isomer 83mKr, has many properties that make it very useful for various applications. Its low energy decay products, like conversion, shake-off and Auger electrons as well as X- and γ-rays are used for calibration purposes in neutrino mass experiments and direct dark matter detection experiments. Thanks to the short half-life of 1.83 h and the decay to the ground state 83Kr, one does not risk contamination of any low-background experiment with long-lived radionuclides. In this paper, we present a new approach, using 83mKr as a radioactive tracer in noble gases. A method of doping 83mKr, into xenon gas and its detection, using special custom-made detectors, based on a photomultiplier tube, is described. Two applications of this method are presented: firstly, it can be used to characterize the particle flow inside of gas routing systems and determine the circulation speed of gas particles inside of a gas purification system for xenon. Secondly, it is used for rapid estimating of the separation performance of a distillation system.

  19. Experiments on water detritiation and cryogenic distillation at TLK; Impact on ITER fuel cycle subsystems interfaces

    SciTech Connect

    Cristescu, I.; Cristescu, I. R.; Doerr, L.; Hellriegel, G.; Michling, R.; Murdoch, D.; Schaefer, P.; Welte, S.; Wurster, W.

    2008-07-15

    The ITER Isotope Separation System (ISS) and Water Detritiation System (WDS) should be integrated in order to reduce potential chronic tritium emissions from the ISS. This is achieved by routing the top (protium) product from the ISS to a feed point near the bottom end of the WDS Liquid Phase Catalytic Exchange (LPCE) column. This provides an additional barrier against ISS emissions and should mitigate the memory effects due to process parameter fluctuations in the ISS. To support the research activities needed to characterize the performances of various components for WDS and ISS processes under various working conditions and configurations as needed for ITER design, an experimental facility called TRENTA representative of the ITER WDS and ISS protium separation column, has been commissioned and is in operation at TLK The experimental program on TRENTA facility is conducted to provide the necessary design data related to the relevant ITER operating modes. The operation availability and performances of ISS-WDS have impact on ITER fuel cycle subsystems with consequences on the design integration. The preliminary experimental data on TRENTA facility are presented. (authors)

  20. Final Report - Advanced Hydraulic and Mass Transfer Models for Distillation Column Optimization and Design

    SciTech Connect

    Eldridge, Robert, B.

    2005-10-13

    The project successfully developed a computational fluid dynamics (CFD) based simulation of the hydrodynamics of flow in a commercial structured packing element. This result fulfilled the prime objective of the research program. The simulation utilized commercial CFD code marketed by Fluent Inc. in combination with a novel graphical interface developed by Oak Ridge National Lab. The end product will allow the design of next generation column internals without the need for extensive experimental validation and will expand the fundamental understanding of the vapor-liquid contacting process.

  1. Catalytic distillation structure

    DOEpatents

    Smith, Jr., Lawrence A.

    1984-01-01

    Catalytic distillation structure for use in reaction distillation columns, a providing reaction sites and distillation structure and consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and being present with the catalyst component in an amount such that the catalytic distillation structure consist of at least 10 volume % open space.

  2. Extractive distillation method

    SciTech Connect

    Ogura, Sh.; Miyamoto, M.

    1984-05-08

    A method is disclosed for separating a hydrocarbon mixture into relatively difficulty soluble hydrocarbons and relatively easily soluble hydrocarbons by extractive distillation using a polar solvent. The method comprises feeding the starting hydrocarbon mixture to at least two evaporators, an extractive distillation column, a stripping column and a rectifying column; the improvement wherein (1) the polar solvent discharged at a high temperature from the bottom of the stripping column is recycled to the extractive distillation column after it has been cooled to a suitable temperature by giving up heat to a reboiler of the extractive distillation column, a reboiler of the rectifying column and successively to the two or more evaporators, and (2) the starting hydrocarbon mixture is divided into two or more streams and heated in two or more evaporators, one stream being evaporated in a first evaporator to a pressure necessary for introduction into the extractive distillation column and then fed to the extractive distillation column, and the other stream, after evaporation in a second and subsequent evaporators, being pressurized to a pressure required for introduction into the extractive distillation column by means of a compressor and then fed into the extractive distillation column.

  3. Comparison of simulated distillation to true boiling point distillation of H-Coal distillates

    SciTech Connect

    Kiser, M.D.; Malone, D.P.

    1982-01-01

    A comparison of simulated distillation to true boiling point (TBP) from both actual TBP distillation and single theoretical plate distillations converted to TBP for various H-Coal distillates is presented. The TBP distillation data was obtained using a Todd distillation column having 15 theoretical plates and a 5:1 reflux ratio. The simulated data presented were obtained using a Hewlitt Packard 5731 gas chromatograph equipped with dual flame ionization detectors. Graphical comparisons of distillation curves obtained by direct weight % TBP distillation and simulated distillation for a full range H-Coal syncrude, of boiling point curves for H-Coal naphtha, H-Coal middle distillate, and H-Coal heavy distillate are included. From an examination of the distillation data, it was apparent that simulated distillation data compared favorable with weight % distillation data, whether derived from direct TBP distillation or single theoretical plate distillation data and converted to TBP data. (BLM)

  4. Simulation of a Novel Single-column Cryogenic Air Separation Process Using LNG Cold Energy

    NASA Astrophysics Data System (ADS)

    Jieyu, Zheng; Yanzhong, Li; Guangpeng, Li; Biao, Si

    In this paper, a novel single-column air separation process is proposed with the implementation of heat pump technique and introduction of LNG coldenergy. The proposed process is verifiedand optimized through simulation on the Aspen Hysys® platform. Simulation results reveal that thepower consumption per unit mass of liquid productis around 0.218 kWh/kg, and the total exergy efficiency of the systemis 0.575. According to the latest literatures, an energy saving of 39.1% is achieved compared with those using conventional double-column air separation units.The introduction of LNG cold energy is an effective way to increase the system efficiency.

  5. Catalytic distillation structure

    DOEpatents

    Smith, L.A. Jr.

    1984-04-17

    Catalytic distillation structure is described for use in reaction distillation columns, and provides reaction sites and distillation structure consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and is present with the catalyst component in an amount such that the catalytic distillation structure consists of at least 10 volume % open space. 10 figs.

  6. Computer simulation of the water and hydrogen distillation and CECE process and its experimental verification

    SciTech Connect

    Fedorchenko, O.A.; Alekseev, I.A.; Trenin, V.D.; Uborski, V.V.

    1995-10-01

    Mathematical simulation procedures have been developed for three processes of hydrogen isotopes separation: (1) a non steady-state water distillation; (2) a cryogenic distillation; and (3) a combined electrolysis and multistage water/hydrogen catalytic exchange (CECE) process. The simulation procedures possess some special features. Thus, the comparatively large step of integration and as a result of this high fast-acting is the peculiarity of the model for the dynamic behaviour of water distillation column operating at total reflux. The simulation procedure for CECE process considers six components and three phases (liquid water, water vapour, and hydrogen gas) and allows one to carry out computations for any mole fraction stock. This procedure, as the one for cryogenic distillation process, is not based on the Newton-Raphson method, and, in spite of this, convergence is reached by a small number of iterations (4 - 11). 8 refs., 4 figs., 6 tabs.

  7. Catalytic distillation process

    DOEpatents

    Smith, Jr., Lawrence A.

    1982-01-01

    A method for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C.sub.4 feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  8. Catalytic distillation process

    DOEpatents

    Smith, L.A. Jr.

    1982-06-22

    A method is described for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C[sub 4] feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  9. A Comprehensive Real-World Distillation Experiment

    ERIC Educational Resources Information Center

    Kazameas, Christos G.; Keller, Kaitlin N.; Luyben, William L.

    2015-01-01

    Most undergraduate mass transfer and separation courses cover the design of distillation columns, and many undergraduate laboratories have distillation experiments. In many cases, the treatment is restricted to simple column configurations and simplifying assumptions are made so as to convey only the basic concepts. In industry, the analysis of a…

  10. Design of processes with reactive distillation line diagrams

    SciTech Connect

    Bessling, B.; Schembecker, G.; Simmrock, K.H.

    1997-08-01

    On the basis of the transformation of concentration coordinates, the concept of reactive distillation lines is developed. It is applied to study the feasibility of a reactive distillation with an equilibrium reaction on all trays of a distillation column. The singular points in the distillation line diagrams are characterized in terms of nodes and saddles. Depending on the characterization of the reactive distillation line diagrams, it can be decided whether a column with two feed stages is required. On the basis of the reaction space concept, a procedure for identification of reactive distillation processes is developed, in which the reactive distillation column has to be divided into reactive and nonreactive sections. This can be necessary to overcome the limitations in separation which result from the chemical equilibrium. The concentration profile of this combined reactive/nonreactive distillation column is estimated using combined reactive/nonreactive distillation lines.

  11. Distributive Distillation Enabled by Microchannel Process Technology

    SciTech Connect

    Arora, Ravi

    2013-01-22

    The application of microchannel technology for distributive distillation was studied to achieve the Grand Challenge goals of 25% energy savings and 10% return on investment. In Task 1, a detailed study was conducted and two distillation systems were identified that would meet the Grand Challenge goals if the microchannel distillation technology was used. Material and heat balance calculations were performed to develop process flow sheet designs for the two distillation systems in Task 2. The process designs were focused on two methods of integrating the microchannel technology 1) Integrating microchannel distillation to an existing conventional column, 2) Microchannel distillation for new plants. A design concept for a modular microchannel distillation unit was developed in Task 3. In Task 4, Ultrasonic Additive Machining (UAM) was evaluated as a manufacturing method for microchannel distillation units. However, it was found that a significant development work would be required to develop process parameters to use UAM for commercial distillation manufacturing. Two alternate manufacturing methods were explored. Both manufacturing approaches were experimentally tested to confirm their validity. The conceptual design of the microchannel distillation unit (Task 3) was combined with the manufacturing methods developed in Task 4 and flowsheet designs in Task 2 to estimate the cost of the microchannel distillation unit and this was compared to a conventional distillation column. The best results were for a methanol-water separation unit for the use in a biodiesel facility. For this application microchannel distillation was found to be more cost effective than conventional system and capable of meeting the DOE Grand Challenge performance requirements.

  12. Simple rules help select best hydrocarbon distillation scheme

    SciTech Connect

    Sanchezllanes, M.T.; Perez, A.L.; Martinez, M.P.; Aguilar-Rodriguez, E.; Rosal, R. del )

    1993-12-06

    Separation economics depend mainly on investment for major equipment and energy consumption. This relationship, together with the fact that, in most cases, many alternative schemes will be proposed, make it essential to find an optimum scheme that minimizes overall costs. Practical solutions are found by applying heuristics -- exploratory problem-solving techniques that eliminate alternatives without applying rigorous mathematical procedures. These techniques have been applied to a case study. In the case study, a hydrocarbon mixture will be transported through a pipeline to a fractionation plant, where it will be separated into commercial products for distribution. The fractionation will consist of a simple train of distillation columns, the sequence of which will be defined by applying heuristic rules and determining the required thermal duties for each column. The facility must separate ethane, propane and mixed butanes, natural gasoline (light straight-run, or LSR, gasoline), and condensate (heavy naphtha). The ethane will be delivered to an ethylene plant as a gaseous stream, the propane and butanes will be stored in cryogenic tanks, and the gasoline and heavy naphtha also will be stored.

  13. Distillation tray structural parameter study: Phase 1

    NASA Technical Reports Server (NTRS)

    Winter, J. Ronald

    1991-01-01

    The purpose here is to identify the structural parameters (plate thickness, liquid level, beam size, number of beams, tray diameter, etc.) that affect the structural integrity of distillation trays in distillation columns. Once the sensitivity of the trays' dynamic response to these parameters has been established, the designer will be able to use this information to prepare more accurate specifications for the construction of new trays. Information is given on both static and dynamic analysis, modal response, and tray failure details.

  14. Cryogenic exciter

    SciTech Connect

    Bray, James William; Garces, Luis Jose

    2012-03-13

    The disclosed technology is a cryogenic static exciter. The cryogenic static exciter is connected to a synchronous electric machine that has a field winding. The synchronous electric machine is cooled via a refrigerator or cryogen like liquid nitrogen. The static exciter is in communication with the field winding and is operating at ambient temperature. The static exciter receives cooling from a refrigerator or cryogen source, which may also service the synchronous machine, to selected areas of the static exciter and the cooling selectively reduces the operating temperature of the selected areas of the static exciter.

  15. Collocation methods for distillation design. 2: Applications for distillation

    SciTech Connect

    Huss, R.S.; Westerberg, A.W.

    1996-05-01

    The authors present applications for a collocation method for modeling distillation columns that they developed in a companion paper. They discuss implementation of the model, including discussion of the ASCEND (Advanced System for Computations in ENgineering Design) system, which enables one to create complex models with simple building blocks and interactively learn to solve them. They first investigate applying the model to compute minimum reflux for a given separation task, exactly solving nonsharp and approximately solving sharp split minimum reflux problems. They next illustrate the use of the collocation model to optimize the design a single column capable of carrying out a prescribed set of separation tasks. The optimization picks the best column diameter and total number of trays. It also picks the feed tray for each of the prescribed separations.

  16. Integrated process of distillation with side reactors for synthesis of organic acid esters

    SciTech Connect

    Panchal, Chandrakant B; Prindle, John C; Kolah, Aspri; Miller, Dennis J; Lira, Carl T

    2015-11-04

    An integrated process and system for synthesis of organic-acid esters is provided. The method of synthesizing combines reaction and distillation where an organic acid and alcohol composition are passed through a distillation chamber having a plurality of zones. Side reactors are used for drawing off portions of the composition and then recycling them to the distillation column for further purification. Water is removed from a pre-reactor prior to insertion into the distillation column. An integrated heat integration system is contained within the distillation column for further purification and optimizing efficiency in the obtaining of the final product.

  17. Distillation sequence for the purification and recovery of hydrocarbons

    DOEpatents

    Reyneke, Rian; Foral, Michael; Papadopoulos, Christos G.; Logsdon, Jeffrey S.; Eng, Wayne W. Y.; Lee, Guang-Chung; Sinclair, Ian

    2007-12-25

    This invention is an improved distillation sequence for the separation and purification of ethylene from a cracked gas. A hydrocarbon feed enters a C2 distributor column. The top of the C2 distributor column is thermally coupled to an ethylene distributor column, and the bottoms liquid of a C2 distributor column feeds a deethanizer column. The C2 distributor column utilizes a conventional reboiler. The top of the ethylene distributor is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor feeds a C2 splitter column. The ethylene distributor column utilizes a conventional reboiler. The deethanizer and C2 splitter columns are also thermally coupled and operated at a substantially lower pressure than the C2 distributor column, the ethylene distributor column, and the demethanizer column. Alternatively, a hydrocarbon feed enters a deethanizer column. The top of the deethanizer is thermally coupled to an ethylene distributor column, and the ethylene distributor column utilizes a conventional reboiler. The top of the ethylene distributor column is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor column feeds a C2 splitter column. The C2 splitter column operates at a pressure substantially lower than the ethylene distributor column, the demethanizer column, and the deethanizer column.

  18. Hybrid nonlocality distillation

    NASA Astrophysics Data System (ADS)

    Wu, Keng-Shuo; Hsu, Li-Yi

    2013-08-01

    In this Letter, we introduce the notion of hybrid nonlocality distillation, in which different nonlocal boxes are exploited for nonlocality distillation. Here, we quantify the nonlocality using the violation degree of either the Clauser-Horne-Shimony-Holt inequality or the I3322 inequality. Our study shows that hybrid nonlocality distillation can outperform nonlocality distillation using copies of single nonlocal boxes. In particular, more nonlocality of undistillable boxes can be activated with the assistance of distillable boxes. Equivalently, distillable boxes can achieve more nonlocality with the assistance of undistillable boxes.

  19. Setting the Pressure at Which to Conduct a Distillation.

    ERIC Educational Resources Information Center

    Barduhn, Allen J.

    1984-01-01

    Discusses how pressure setting is determined for distillation columns, examining factors which must be considered when optimizing design for economical balance. Also discusses the basics of heat exchangers and cites a common problem with pressure differences. (JM)

  20. Distillation with Vapour Compression. An Undergraduate Experimental Facility.

    ERIC Educational Resources Information Center

    Pritchard, Colin

    1986-01-01

    Discusses the need to design distillation columns that are more energy efficient. Describes a "design and build" project completed by two college students aimed at demonstrating the principles of vapour compression distillation in a more energy efficient way. General design specifications are given, along with suggestions for teaching and…

  1. Cryogenic Systems

    NASA Astrophysics Data System (ADS)

    Hosoyama, Kenji

    2002-02-01

    In this lecture we discuss the principle of method of cooling to a very low temperature, i.e. cryogenic. The "gas molecular model" will be introduced to explain the mechanism cooling by the expansion engine and the Joule-Thomson expansion valve. These two expansion processes are normally used in helium refrigeration systems to cool the process gas to cryogenic temperature. The reverse Carnot cycle will be discussed in detail as an ideal refrigeration cycle. First the fundamental process of liquefaction and refrigeration cycles will be discussed, and then the practical helium refrigeration system. The process flow of the system and the key components; -compressor, expander, and heat exchanger- will be discussed. As an example of an actual refrigeration system, we will use the cryogenic system for the KEKB superconducting RF cavity. We will also discuss the liquid helium distribution system, which is very important, especially for the cryogenic systems used in accelerator applications. 1 Principles of Cooling and Fundamental Cooling Cycle 2 Expansion engine, Joule-Thomson expansion, kinetic molecular theory, and enthalpy 3 Liquefaction Systems 4 Refrigeration Systems 5 Practical helium liquefier/refrigeration system 6 Cryogenic System for TRISTAN Superconducting RF Cavity

  2. RHIC cryogenics

    NASA Astrophysics Data System (ADS)

    Iarocci, M. A.; Brown, D.; Sondericker, J.; Wu, K. C.; Benson, J.; Farah, Y.; Lac, C.; Morgillo, A.; Nicoletti, A.; Quimby, E.; Rank, J.; Rehak, M.; Werner, A.

    2003-03-01

    An integrated helium cryogenic system was designed with the specific performance goal of cooling and refrigerating the cryogenic magnets to below their nominal operating temperature. These magnets make up the steering and focusing elements for the Relativistic Heavy Ion Collider (RHIC). In addition to meeting the accelerator demands, reliability, flexibility, safety, and ease of operation were key considerations during the design phase of the project. The refrigerator, with a capacity of 25 kW at about 4 K, was originally designed to match the load for the Colliding Beam Accelerator Project. The existing refrigerator, along with its complimentary warm compressor system was reconfigured slightly to meet the cooling process cycle design for RHIC. The original VAX based process control system was also adapted for RHIC, and later expanded upon to integrate a new programmable logic controller based ring resident control system, hence forming a common system to monitor and control all cryogenic components.

  3. Kinetic Method for Hydrogen-Deuterium-Tritium Mixture Distillation Simulation

    SciTech Connect

    Sazonov, A.B.; Kagramanov, Z.G.; Magomedbekov, E.P.

    2005-07-15

    Simulation of hydrogen distillation plants requires mathematical procedures suitable for multicomponent systems. In most of the present-day simulation methods a distillation column is assumed to be composed of theoretical stages, or plates. However, in the case of a multicomponent mixture theoretical plate does not exist.An alternative kinetic method of simulation is depicted in the work. According to this method a system of mass-transfer differential equations is solved numerically. Mass-transfer coefficients are estimated with using experimental results and empirical equations.Developed method allows calculating the steady state of a distillation column as well as its any non-steady state when initial conditions are given. The results for steady states are compared with ones obtained via Thiele-Geddes theoretical stage technique and the necessity of using kinetic method is demonstrated. Examples of a column startup period and periodic distillation simulations are shown as well.

  4. Cryogenic shutter

    NASA Astrophysics Data System (ADS)

    Barney, Richard D.; Magner, Thomas J.

    1992-07-01

    A magnetically operated shutter mechanism is provided that will function in cryogenic or cryogenic zero gravity environments to selectively block radiation such as light from passing through a window to a target object such as a mirror or detector located inside a cryogenic container such as a dewar. The mechanism includes a shutter paddle blade that is moved by an electromagnetically actuated torquing device between an open position where the target object is exposed to ambient radiation or light and a closed position where the shutter paddle blade shields the ambient radiation or light from the target object. The purpose of the shuttering device is to prevent the mirror or other target object from being directly exposed to radiation passing through the window located on the side wall of the dewar, thereby decreasing or eliminating any temperature gradient that would occur within the target object due to exposure to the radiation. A special nylon bearing system is utilized to prevent the device from binding during operation and the paddle blade is also thermally connected to a reservoir containing cryogen to further reduce the internal temperature.

  5. Multipartite nonlocality distillation

    SciTech Connect

    Hsu, Li-Yi; Wu, Keng-Shuo

    2010-11-15

    The stronger nonlocality than that allowed in quantum theory can provide an advantage in information processing and computation. Since quantum entanglement is distillable, can nonlocality be distilled in the nonsignalling condition? The answer is positive in the bipartite case. In this article the distillability of the multipartite nonlocality is investigated. We propose a distillation protocol solely exploiting xor operations on output bits. The probability-distribution vectors and matrix are introduced to tackle the correlators. It is shown that only the correlators with extreme values can survive the distillation process. As the main result, the amplified nonlocality cannot maximally violate any Bell-type inequality. Accordingly, a distillability criterion in the postquantum region is proposed.

  6. CRYOGENIC MAGNETS

    DOEpatents

    Post, R.F.; Taylor, C.E.

    1963-05-21

    A cryogenic magnet coil is described for generating magnetic fields of the order of 100,000 gauss with a minimum expenditure of energy lost in resistive heating of the coil inductors and energy lost irreversibly in running the coil refrigeration plant. The cryogenic coil comprises a coil conductor for generating a magnetic field upon energization with electrical current, and refrigeration means disposed in heat conductive relation to the coil conductor for cooling to a low temperature. A substantial reduction in the power requirements for generating these magnetic fields is attained by scaling the field generating coil to large size and particular dimensions for a particular conductor, and operating the coil at a particular optimum temperature commensurate with minimum overall power requirements. (AEC)

  7. Contact structure for use in catalytic distillation

    DOEpatents

    Jones, E.M. Jr.

    1984-03-27

    A method is described for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor, contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

  8. Contact structure for use in catalytic distillation

    DOEpatents

    Jones, Jr., Edward M.

    1984-01-01

    A method for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catatlyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

  9. Contact structure for use in catalytic distillation

    DOEpatents

    Jones, E.M. Jr.

    1985-08-20

    A method and apparatus are disclosed for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

  10. Contact structure for use in catalytic distillation

    DOEpatents

    Jones, Jr., Edward M.

    1985-01-01

    A method and apparatus for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

  11. Parametric study of complex distillation flowsheets for the separations of five-component mixtures

    SciTech Connect

    Rong, B.G.; Zheng, S.Q.; Zhou, C.G.

    1996-12-31

    Twenty two distillation flowsheets are studied for the separations of five-component mixtures based on the energy consumption and the annual costs. Fourteen flowsheets with simple columns and eight flowsheets with complex columns of side strippers and/or side rectifiers are included. Several five-component mixtures are selected, for various cases of feed composition distribution, the costs of the flowsheets are calculated and compared. Several heuristics are produced for the synthesis of distillation flowsheets with complex columns.

  12. Advanced Distillation Final Report

    SciTech Connect

    Maddalena Fanelli; Ravi Arora; Annalee Tonkovich; Jennifer Marco; Ed Rode

    2010-03-24

    The Advanced Distillation project was concluded on December 31, 2009. This U.S. Department of Energy (DOE) funded project was completed successfully and within budget during a timeline approved by DOE project managers, which included a one year extension to the initial ending date. The subject technology, Microchannel Process Technology (MPT) distillation, was expected to provide both capital and operating cost savings compared to conventional distillation technology. With efforts from Velocys and its project partners, MPT distillation was successfully demonstrated at a laboratory scale and its energy savings potential was calculated. While many objectives established at the beginning of the project were met, the project was only partially successful. At the conclusion, it appears that MPT distillation is not a good fit for the targeted separation of ethane and ethylene in large-scale ethylene production facilities, as greater advantages were seen for smaller scale distillations. Early in the project, work involved flowsheet analyses to discern the economic viability of ethane-ethylene MPT distillation and develop strategies for maximizing its impact on the economics of the process. This study confirmed that through modification to standard operating processes, MPT can enable net energy savings in excess of 20%. This advantage was used by ABB Lumus to determine the potential impact of MPT distillation on the ethane-ethylene market. The study indicated that a substantial market exists if the energy saving could be realized and if installed capital cost of MPT distillation was on par or less than conventional technology. Unfortunately, it was determined that the large number of MPT distillation units needed to perform ethane-ethylene separation for world-scale ethylene facilities, makes the targeted separation a poor fit for the technology in this application at the current state of manufacturing costs. Over the course of the project, distillation experiments were

  13. Aspects regarding at 13C isotope separation column control using Petri nets system

    NASA Astrophysics Data System (ADS)

    Boca, M. L.; Ciortea, M. E.

    2015-11-01

    This paper is intended to show that Petri nets can be also applicable in the chemical industry. It used linear programming, modeling underlying Petri nets, especially discrete event systems for isotopic separation, the purpose of considering and control events in real-time through graphical representations. In this paper it is simulate the control of 13C Isotope Separation column using Petri nets. The major problem with 13C comes from the difficulty of obtaining it and raising its natural fraction. Carbon isotopes can be obtained using many methods, one of them being the cryogenic distillation of carbon monoxide. Some few aspects regarding operating conditions and the construction of such cryogenic plants are known today, and even less information are available as far as the separation process modeling and control are concerned. In fact, the efficient control of the carbon monoxide distillation process represents a necessity for large-scale 13C production. Referring to a classic distillation process, some models for carbon isotope separation have been proposed, some based on mass, component and energy balance equations, some on the nonlinear wave theory or the Cohen equations. For modeling the system it was used Petri nets because in this case it is deal with discrete event systems. In use of the non-timed and with auxiliary times Petri model, the transport stream was divided into sections and these sections will be analyzed successively. Because of the complexity of the system and the large amount of calculations required it was not possible to analyze the system as a unitary whole. A first attempt to model the system as a unitary whole led to the blocking of the model during simulation, because of the large processing times.

  14. Datalogging the Distillation Process.

    ERIC Educational Resources Information Center

    Soares, Allan; Creevy, Steven

    1995-01-01

    Presents a distillation experiment that uses temperature sensors connected to a computer in place of thermometers, and enables the whole class to view the data on a monitor and interpret and discuss the data in real time. (JRH)

  15. CRYOGENIC DEWAR

    DOEpatents

    Chamberlain, W.H.; Maseck, H.E.

    1964-01-28

    This patent relates to a dewar for storing cryogenic gase and is of the type having aii inner flask surrounded by a vacuum jacket and having a vent spout through which evaporating gas escapes. Heretofore substantial gas loss has resulted from the radiation of heat towards the flask from the warmer outer elements of the dewar. In this invention, the mask is surrounded by a thermally conducting shield which is disposed in the vacuum space between the flask and the outer elements of the dewar. The shield contacts only the vent spout, which is cooled by the evaporating gas, and thus is maintained at a temperature very close to that of the flask itself. Accordingly, heat radiated toward the flask is intercepted and conducted to the evaporating gas rather than being re-radiated towards the hask. In a liquid helium dewar of typical configniration the mention reduces the boil-off rate by approximately one-half.(AEC)

  16. DISTILLATION OF CALCIUM

    DOEpatents

    Barton, J.

    1954-07-27

    This invention relates to an improvement in the process for the purification of caicium or magnesium containing an alkali metal as impurity, which comprises distiiling a batch of the mixture in two stages, the first stage distillation being carried out in the presence of an inert gas at an absolute pressure substantially greater than the vapor pressure of calcium or maguesium at the temperature of distillation, but less than the vaper pressure at that temperature of the alkali metal impurity so that only the alkali metal is vaporized and condensed on a condensing surface. A second stage distilso that substantially only the calcium or magnesium distills under its own vapor pressure only and condenses in solid form on a lower condensing surface.

  17. Feasibility of separations for distillation of nonideal ternary mixtures

    SciTech Connect

    Fidkowski, Z.T.; Doherty, M.F.; Malone, M.F. . Dept. of Chemical Engineering)

    1993-08-01

    The product compositions in single-feed distillation columns can be specified only in certain regions of the composition space, which depend only on the pressure, feed, and vapor-liquid equilibrium for the mixture. In nonideal mixtures, even without azeotropes, the regions may allow unusual product distributions. For example, the distillate in a direct split is composed primarily of the lightest component. Intuition and experience with relatively ideal mixtures suggest that the next most plentiful component is the intermediate boiler. In nonideal mixtures, however, with or without azeotropes, the next most plentiful component may be the highest-boiling species with only trace amounts of the intermediate boiler. For azeotropic mixtures, distillation boundaries may give rise to additional restrictions on the product compositions. The authors describe how simple distillation boundaries deform into continuous distillation boundaries and, in a limited number of cases, how the simple distillation boundaries can be crossed in continuous columns for certain ranges of the design variables. Unfortunately, such designs may be quite sensitive to model uncertainties or to disturbances in the parameters.

  18. Dehydrate ethanol without distillation

    SciTech Connect

    Not Available

    1993-10-01

    Usina da Pedra (Serrana, state of Sao Paulo, Brazil) produces 60 million gal/yr of ethanol in 180 operating days. Until this year, the plant made 96 vol.% ethanol that is used as automotive fuel, and absolute ethanol (99.5 vol. %), which is blended with gasoline. Water is the remainder in both products. The ethanol is produced from the fermentation of sugar cane, and distilled with benzene. Benzene lowers the boiling point of the ethanol-water mixture and ties up the water. In May, Usina da Pedra installed a process that dehydrates ethanol by adsorption, not distillation. A vapor-phase process containing molecular sieves, handles throughputs as high as 160,000 acfh and has a maximum capacity of 70 million gal/yr. In addition to generating safer products, the energy savings gained by switching from distillation to adsorption are significant. The adsorptive system requires input of only 2,900 Btu per gallon of ethanol; one-third the energy consumed by distillation systems that employ benzene or cyclohexane.

  19. Tritium Attenuation by Distillation

    SciTech Connect

    Wittman, N.E.

    2001-07-31

    The objective of this study was to determine how a 100 Area distillation system could be used to reduce to a satisfactory low value the tritium content of the dilute moderator produced in the 100 Area stills, and whether such a tritium attenuator would have sufficient capacity to process all this material before it is sent to the 400 Area for reprocessing.

  20. Distillation under electric fields

    SciTech Connect

    Shah, V.M.; Blankenship, K.D.; Tsouris, C.

    1997-11-01

    Distillation Is the most common separation process used in the chemical and petroleum industry. Major limitations in the applicability and efficiency of distillation come from thermodynamic equilibria, that is, vapor-liquid equilibria (VLE), and heat and mass transfer rates. In this work, electric fields are used to manipulate the VLE of mixtures. VLE experiments are performed for various binary mixtures in the presence of electric fields on the order of a few kilovolts per centimeter. The results show that the VLE is changed by electric fields, with changes in the separation factor as high as 10% being observed. Batch distillation experiments are also carried out for binary mixtures of 2-propanol and water with and without an applied electric field. Results show enhanced distillation rates and separation efficiency in the presence of an electric field but decreased separation enhancement when the electric current is increased. The latter phenomenon is caused by the formation at the surface of the liquid mixture of microdroplets that are entrained by the vapor. These observations suggest that there should be an electric field strength for each system for which the separation enhancement is maximum.

  1. Reactive Distillation and Air Stripping Processes for Water Recycling and Trace Contaminant Control

    NASA Technical Reports Server (NTRS)

    Boul, Peter J.; Lange, Kevin E.; Conger, Bruce; Anderson, Molly

    2009-01-01

    Reactive distillation designs are considered to reduce the presence of volatile organic compounds in the purified water. Reactive distillation integrates a reactor with a distillation column. A review of the literature in this field has revealed a variety of functional reactive columns in industry. Wastewater may be purified by a combination of a reactor and a distiller (e.g., the EWRS or VPCAR concepts) or, in principle, through a design which integrates the reactor with the distiller. A review of the literature in reactive distillation has identified some different designs in such combinations of reactor and distiller. An evaluation of reactive distillation and reactive air stripping is presented with regards to the reduction of volatile organic compounds in the contaminated water and air. Among the methods presented, an architecture is presented for the evaluation of the simultaneous oxidation of organics in air and water. These and other designs are presented in light of potential improvements in power consumptions and air and water purities for architectures which include catalytic activity integrated into the water processor. In particular, catalytic oxidation of organics may be useful as a tool to remove contaminants that more traditional distillation and/or air stripping columns may not remove. A review of the current leading edge at the commercial level and at the research frontier in catalytically active materials is presented. Themes and directions from the engineering developments in catalyst design are presented conceptually in light of developments in the nanoscale chemistry of a variety of catalyst materials.

  2. Energy Efficient Cryogenics

    NASA Technical Reports Server (NTRS)

    Meneghelli, Barry J.; Notardonato, William; Fesmire, James E.

    2016-01-01

    The Cryogenics Test Laboratory, NASA Kennedy Space Center, works to provide practical solutions to low-temperature problems while focusing on long-term technology targets for the energy-efficient use of cryogenics on Earth and in space.

  3. Refrigeration for Cryogenic Sensors

    NASA Technical Reports Server (NTRS)

    Gasser, M. G. (Editor)

    1983-01-01

    Research in cryogenically cooled refrigerators is discussed. Low-power Stirling cryocoolers; spacecraft-borne long-life units; heat exchangers; performance tests; split-stirling, linear-resonant, cryogenic refrigerators; and computer models are among the topics discussed.

  4. Cryogenic immersion microscope

    DOEpatents

    Le Gros, Mark; Larabell, Carolyn A.

    2010-12-14

    A cryogenic immersion microscope whose objective lens is at least partially in contact with a liquid reservoir of a cryogenic liquid, in which reservoir a sample of interest is immersed is disclosed. When the cryogenic liquid has an index of refraction that reduces refraction at interfaces between the lens and the sample, overall resolution and image quality are improved. A combination of an immersion microscope and x-ray microscope, suitable for imaging at cryogenic temperatures is also disclosed.

  5. Gas chromatographic characterization of vegetable oil deodorization distillate.

    PubMed

    Verleyen, T; Verhe, R; Garcia, L; Dewettinck, K; Huyghebaert, A; De Greyt, W

    2001-07-01

    Because of its complex nature, the analysis of deodorizer distillate is a challenging problem. Deodorizer distillate obtained from the deodorization process of vegetable oils consists of many components including free fatty acids, tocopherols, sterols, squalene and neutral oil. A gas chromatographic method for the analysis of deodorizer distillate without saponification of the sample is described. After a concise sample preparation including derivatization and silylation, distillate samples were injected on column at 60 degrees C followed by a gradual increase of the oven temperature towards 340 degrees C. The temperature profile of the oven was optimized in order to obtain a baseline separation of the different distillate components including free fatty acids, tocopherols, sterols, squalene and neutral oil. Good recoveries for delta-tocopherol, alpha-tocopherol, stigmasterol and cholesteryl palmitate of 97, 94.4, 95.6 and 92%, respectively were obtained. Repeatability of the described gas chromatographic method was evaluated by analyzing five replicates of a soybean distillate. Tocopherols and sterols had low relative standard deviations ranging between 1.67 and 2.25%. Squalene, mono- and diacylglycerides had higher relative standard deviations ranging between 3.33 and 4.12%. Several industrial deodorizer distillates obtained from chemical and physical refining of corn, canola, sunflower and soybean have been analyzed for their composition. PMID:11471811

  6. 27 CFR 24.216 - Distilling material.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... fermentation or distillation. No sugar may be added in the production of distilling material. Distillates containing aldehydes may be used in the fermentation of wine to be used as distilling material. Lees,...

  7. 27 CFR 27.40 - Distilled spirits.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... OF THE TREASURY LIQUORS IMPORTATION OF DISTILLED SPIRITS, WINES, AND BEER Tax On Imported Distilled Spirits, Wines, and Beer Distilled Spirits § 27.40 Distilled spirits. (a) A tax is imposed on...

  8. 27 CFR 27.40 - Distilled spirits.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... OF THE TREASURY ALCOHOL IMPORTATION OF DISTILLED SPIRITS, WINES, AND BEER Tax On Imported Distilled Spirits, Wines, and Beer Distilled Spirits § 27.40 Distilled spirits. (a) A tax is imposed on...

  9. 27 CFR 27.40 - Distilled spirits.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... OF THE TREASURY ALCOHOL IMPORTATION OF DISTILLED SPIRITS, WINES, AND BEER Tax On Imported Distilled Spirits, Wines, and Beer Distilled Spirits § 27.40 Distilled spirits. (a) A tax is imposed on...

  10. 27 CFR 27.40 - Distilled spirits.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... OF THE TREASURY LIQUORS IMPORTATION OF DISTILLED SPIRITS, WINES, AND BEER Tax On Imported Distilled Spirits, Wines, and Beer Distilled Spirits § 27.40 Distilled spirits. (a) A tax is imposed on...

  11. 27 CFR 27.40 - Distilled spirits.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... OF THE TREASURY LIQUORS IMPORTATION OF DISTILLED SPIRITS, WINES, AND BEER Tax On Imported Distilled Spirits, Wines, and Beer Distilled Spirits § 27.40 Distilled spirits. (a) A tax is imposed on...

  12. Cascade Distillation System Development

    NASA Technical Reports Server (NTRS)

    Callahan, Michael R.; Sargushingh, Miriam; Shull, Sarah

    2014-01-01

    NASA's Advanced Exploration Systems (AES) Life Support System (LSS) Project is chartered with de-veloping advanced life support systems that will ena-ble NASA human exploration beyond low Earth orbit (LEO). The goal of AES is to increase the affordabil-ity of long-duration life support missions, and to re-duce the risk associated with integrating and infusing new enabling technologies required to ensure mission success. Because of the robust nature of distillation systems, the AES LSS Project is pursuing develop-ment of the Cascade Distillation Subsystem (CDS) as part of its technology portfolio. Currently, the system is being developed into a flight forward Generation 2.0 design.

  13. Renormalizing Entanglement Distillation

    NASA Astrophysics Data System (ADS)

    Waeldchen, Stephan; Gertis, Janina; Campbell, Earl T.; Eisert, Jens

    2016-01-01

    Entanglement distillation refers to the task of transforming a collection of weakly entangled pairs into fewer highly entangled ones. It is a core ingredient in quantum repeater protocols, which are needed to transmit entanglement over arbitrary distances in order to realize quantum key distribution schemes. Usually, it is assumed that the initial entangled pairs are identically and independently distributed and are uncorrelated with each other, an assumption that might not be reasonable at all in any entanglement generation process involving memory channels. Here, we introduce a framework that captures entanglement distillation in the presence of natural correlations arising from memory channels. Conceptually, we bring together ideas from condensed-matter physics—ideas from renormalization and matrix-product states and operators—with those of local entanglement manipulation, Markov chain mixing, and quantum error correction. We identify meaningful parameter regions for which we prove convergence to maximally entangled states, arising as the fixed points of a matrix-product operator renormalization flow.

  14. Cryogenic wind tunnels. III

    NASA Technical Reports Server (NTRS)

    Kilgore, Robert A.

    1987-01-01

    Specific problems pertaining to cryogenic wind tunnels, including LN(2) injection, GN(2) exhaust, thermal insulation, and automatic control are discussed. Thermal and other physical properties of materials employed in these tunnels, properties of cryogenic fluids, storage and transfer of liquid nitrogen, strength and toughness of metals and nonmetals at low temperatures, and material procurement and qualify control are considered. Safety concerns with cryogenic tunnels are covered, and models for cryogenic wind tunnels are presented, along with descriptions of major cryogenic wind-tunnel facilities the United States, Europe, and Japan. Problems common to wind tunnels, such as low Reynolds number, wall and support interference, and flow unsteadiness are outlined.

  15. Telescoping columns

    NASA Astrophysics Data System (ADS)

    Mazur, J. T.

    1980-12-01

    An extendable column is described which consists of several axially elongated rigid structural sections nested within one another. Each section includes a number of rotatably attached screws running along its length. The next inner section includes threaded lugs oriented to threadingly engage the screws. The column is extended or retracted upon rotation of the screws. The screws of each section are selectively rotated by a motor and an engagement mechanism.

  16. An artificial intelligence method for the synthesis of heat-integrated distillation flowsheets

    SciTech Connect

    Fang-Yu Han; Ben-Guang Rong

    1996-12-31

    In this paper, a concept of Heat-Integrated Distillation Flowsheet (HIDF) is proposed. It refers to the multicomponent separation flowsheet which is composed of simple and complex columns and in which heat integration is considered so as to achieve minimum energy consumption. The HIDF is very different from the Heat-Integrated Distillation Sequences (HIDS) in the literature which only consists of simple columns. In this paper, an artificial intelligence method is proposed for the synthesis of HIDF. It is based on the Database, Simulator, Heat Exchanger Network, and four Knowledge Bases which are all developed by the authors and their coworkers. A strategy of eight steps which combines the knowledge-based and rigorous algorithms is adopted for the synthesis of HIDF. The illustrated examples for the conventional distillation and extractive distillation show that the practical minimum energy consumption distillation flowsheets; can be generated with this method.

  17. Simulation, design, and analysis of azeotropic distillation operations

    SciTech Connect

    Bossen, B.S.; Joergensen, S.B.; Gani, R. )

    1993-04-01

    The computational tools needed for simulation, design, and analysis of azeotropic distillation operations are described. These tools include simple methods to identify the existence of binary and ternary azeotropes and to classify ternary mixtures as homogeneous or heterogeneous. The tools also include more complex methods to compute the phase diagram (or a heterogeneous liquid boiling surface), predict liquid-vapor phase equilibrium, and/or predict liquid-liquid-vapor phase equilibrium for simulations of batch and continuous distillation column operations. Important new features of these tools are the incorporation of a fast and efficient method for test of phase stability in simulation of distillation operations, the ability to handle a large range of mixtures (including mixtures with supercritical compounds), and the ability for computations covering wide ranges of temperature and pressure. On the basis of these tools, simple and consistent design algorithms are developed. The applicability of the design algorithms is verified through process simulation and analysis of the predicted behavior and data from the open literature. Conditions are given for examples illustrating (when and how possible distillation boundaries can be crossed) how multiple steady states can be obtained. Finally, the effect of changes in operating on the dynamic behavior of the azeotropic distillation columns and the sensitivity of design to the prediction of phase equilibria are presented.

  18. A heat & mass integration approach to reduce capital and operating costs of a distillation configuration

    SciTech Connect

    Madenoor Ramapriya, Gautham; Jiang, Zheyu; Tawarmalani, Mohit; Agrawal, Rakesh

    2015-11-11

    We propose a general method to consolidate distillation columns of a distillation configuration using heat and mass integration. The proposed method encompasses all heat and mass integrations known till date, and includes many more. Each heat and mass integration eliminates a distillation column, a condenser, a reboiler and the heat duty associated with a reboiler. Thus, heat and mass integration can potentially offer significant capital and operating cost benefits. In this talk, we will study the various possible heat and mass integrations in detail, and demonstrate their benefits using case studies. This work will lay out a framework to synthesize an entire new class of useful configurations based on heat and mass integration of distillation columns.

  19. Thermomechanically integrated distillation of ethylene from ethane

    SciTech Connect

    Greene, D.G.; Haddad, H.; Manley, D.B.

    1994-12-31

    The separation of ethylene from ethane by distillation is normally the final step in the production of ethylene. The critical temperature of ethylene is about 50 F, therefore moderately low temperatures and moderately high pressures are typically used to provide optimum economic conditions. The optimum design can require thick walled and heavy pressure vessels which may be constructed of expensive alloy steels depending on the specific operating conditions. The required purity of ethylene usually exceeds 99.9%, and the economic level of recovery is approximately 99%. In addition, the relative volatility of ethylene to ethane is moderately small ranging from about 1.13 for high pressure mixtures rich in ethylene to 2.34 for low pressure mixtures rich in ethane. The relatively high purity and recovery and relatively low relative volatility dictate a large distillation column with more than 100 trays and a large diameter for world scale production levels of over a billion pounds per year of ethylene. The installed capital cost for a unit of this type and size can exceed twenty million dollars, and utility costs can exceed one million dollars per year. Consequently, there is a strong economic incentive to reduce costs through improved process designs for the distillation of ethylene from ethane, and the process is well studied in the literature. Thermomechanically integrated distillation provides an improved design which can reduce both capital and operating costs as compared to the best conventional designs. In this paper, the conventional designs for both vapor and liquid feeds are reviewed, the underlying thermodynamics characterizing the process is discussed, alternative thermomechanically integrated designs are presented, and utility and purchased equipment costs are compared.

  20. Synthesis of crystallization-distillation hybrid separation processes

    SciTech Connect

    Berry, D.A.; Ng, K.M.

    1997-07-01

    A systematic method to synthesize crystallization-distillation hybrid separation processes is presented. Two classes of hybrids are identified for binary mixtures. The first bypasses azeotropes and tangent pinches, while the second bypasses eutectics. Guidelines for flow-sheet selection are proposed based on an analysis of simple eutectic, constant relative volatility systems. In addition, the hybrids are compared to both extractive and adductive crystallization in order to determine the conditions under which solvent-based crystallization techniques outperform the proposed hybrid configurations. The method is extended to ternary mixture. The use of stream combination and complex distillation columns is also considered.

  1. Interlinked Test Results for Fusion Fuel Processing and Blanket Tritium Recovery Systems Using Cryogenic Molecular Sieve Bed

    SciTech Connect

    Yamanishi, Toshihiko; Hayashi, Takumi; Kawamura, Yoshinori; Iwai, Yasunori; Isobe, Kanetsugu; Uzawa, Masayuki; Nishi, Masataka

    2005-07-15

    A simulated fuel processing (cryogenic distillation columns and a palladium diffuser) and CMSB (cryogenic molecular sieve bed) systems were linked together, and were operated. The validity of the CMSB was discussed through this experiment as an integrated system for the recovery of blanket tritium. A gas stream of hydrogen isotopes and He was supplied to the CMSB as the He sweep gas in blanket of a fusion reactor. After the breakthrough of tritium was observed, regeneration of the CMSB was carried out by evacuating and heating. The hydrogen isotopes were finally recovered by the diffuser. At first, only He gas was sent by the evacuating. The hydrogen isotopes gas was then rapidly released by the heating. The system worked well against the above drastic change of conditions. The amount of hydrogen isotopes gas finally recovered by the diffuser was in good agreement with that adsorbed by the CMSB. The dynamic behaviors (breakthrough and regeneration) of the system were explained well by a set of basic codes.

  2. A cryogenic test facility

    NASA Astrophysics Data System (ADS)

    Veenendaal, Ian

    The next generation, space-borne instruments for far infrared spectroscopy will utilize large diameter, cryogenically cooled telescopes in order to achieve unprecedented sensitivities. Low background, ground-based cryogenic facilities are required for the cryogenic testing of materials, components and subsystems. The Test Facility Cryostat (TFC) at the University of Lethbridge is a large volume, closed cycle, 4K cryogenic facility, developed for this purpose. This thesis discusses the design and performance of the facility and associated external instrumentation. An apparatus for measuring the thermal properties of materials is presented, and measurements of the thermal expansion and conductivity of carbon fibre reinforced polymers (CFRPs) at cryogenic temperatures are reported. Finally, I discuss the progress towards the design and fabrication of a demonstrator cryogenic, far infrared Fourier transform spectrometer.

  3. Renormalizing Entanglement Distillation.

    PubMed

    Waeldchen, Stephan; Gertis, Janina; Campbell, Earl T; Eisert, Jens

    2016-01-15

    Entanglement distillation refers to the task of transforming a collection of weakly entangled pairs into fewer highly entangled ones. It is a core ingredient in quantum repeater protocols, which are needed to transmit entanglement over arbitrary distances in order to realize quantum key distribution schemes. Usually, it is assumed that the initial entangled pairs are identically and independently distributed and are uncorrelated with each other, an assumption that might not be reasonable at all in any entanglement generation process involving memory channels. Here, we introduce a framework that captures entanglement distillation in the presence of natural correlations arising from memory channels. Conceptually, we bring together ideas from condensed-matter physics-ideas from renormalization and matrix-product states and operators-with those of local entanglement manipulation, Markov chain mixing, and quantum error correction. We identify meaningful parameter regions for which we prove convergence to maximally entangled states, arising as the fixed points of a matrix-product operator renormalization flow. PMID:26824532

  4. PULSE COLUMN

    DOEpatents

    Grimmett, E.S.

    1964-01-01

    This patent covers a continuous countercurrent liquidsolids contactor column having a number of contactor states each comprising a perforated plate, a layer of balls, and a downcomer tube; a liquid-pulsing piston; and a solids discharger formed of a conical section at the bottom of the column, and a tubular extension on the lowest downcomer terminating in the conical section. Between the conical section and the downcomer extension is formed a small annular opening, through which solids fall coming through the perforated plate of the lowest contactor stage. This annular opening is small enough that the pressure drop thereacross is greater than the pressure drop upward through the lowest contactor stage. (AEC)

  5. Systems and methods for reactive distillation with recirculation of light components

    DOEpatents

    Stickney, Michael J.; Jones, Jr., Edward M.

    2011-07-26

    Systems and methods for producing gas-to-liquids products using reactive distillation are provided. The method for producing gas-to-liquids products can include reacting a feedstock in a column having a distillation zone and a reaction zone to provide a bottoms stream and an overhead stream. A first portion of the overhead stream can be recycled to the column at the top of the reaction zone and second portion of the overhead stream can be recycled to the column at the bottom of the reaction zone.

  6. Fundamentals of Cryogenics

    NASA Technical Reports Server (NTRS)

    Johnson, Wesley; Tomsik, Thomas; Moder, Jeff

    2014-01-01

    Analysis of the extreme conditions that are encountered in cryogenic systems requires the most effort out of analysts and engineers. Due to the costs and complexity associated with the extremely cold temperatures involved, testing is sometimes minimized and extra analysis is often relied upon. This short course is designed as an introduction to cryogenic engineering and analysis, and it is intended to introduce the basic concepts related to cryogenic analysis and testing as well as help the analyst understand the impacts of various requests on a test facility. Discussion will revolve around operational functions often found in cryogenic systems, hardware for both tests and facilities, and what design or modelling tools are available for performing the analysis. Emphasis will be placed on what scenarios to use what hardware or the analysis tools to get the desired results. The class will provide a review of first principles, engineering practices, and those relations directly applicable to this subject including such topics as cryogenic fluids, thermodynamics and heat transfer, material properties at low temperature, insulation, cryogenic equipment, instrumentation, refrigeration, testing of cryogenic systems, cryogenics safety and typical thermal and fluid analysis used by the engineer. The class will provide references for further learning on various topics in cryogenics for those who want to dive deeper into the subject or have encountered specific problems.

  7. Vapor compression distillation module

    NASA Technical Reports Server (NTRS)

    Nuccio, P. P.

    1975-01-01

    A Vapor Compression Distillation (VCD) module was developed and evaluated as part of a Space Station Prototype (SSP) environmental control and life support system. The VCD module includes the waste tankage, pumps, post-treatment cells, automatic controls and fault detection instrumentation. Development problems were encountered with two components: the liquid pumps, and the waste tank and quantity gauge. Peristaltic pumps were selected instead of gear pumps, and a sub-program of materials and design optimization was undertaken leading to a projected life greater than 10,000 hours of continuous operation. A bladder tank was designed and built to contain the waste liquids and deliver it to the processor. A detrimental pressure pattern imposed upon the bladder by a force-operated quantity gauge was corrected by rearranging the force application, and design goals were achieved. System testing has demonstrated that all performance goals have been fulfilled.

  8. Sealing Mechanical Cryogenic Coolers

    NASA Technical Reports Server (NTRS)

    Richter, R.

    1985-01-01

    Metal bellows used to seal Vuilleumier and Stirling-cycle cryogenic coolers, replacing sliding seals that failed after only 3,000 hours of service. Metal bellows, incorporated in displacer design provide nonrubbing dynamic seal. Lifetime of cryogenic cooler no longer limited by loss of sealing material and by deterioration of regenerators due to clogging by seal debris.

  9. Cryogenic storage devices

    SciTech Connect

    Pelloux-gervais, P.

    1982-02-09

    The present invention relates to a device for the cryogenic storing of products. In a tank, canisters are suspended via rods, and these rods rest on the rim of the tank via retaining heads. The invention is applicable to the cryogenic storage of seeds, semen, vegetable substances, etc.

  10. Cryogenic Information Center

    NASA Technical Reports Server (NTRS)

    Mohling, Robert A.; Marquardt, Eric D.; Fusilier, Fred C.; Fesmire, James E.

    2003-01-01

    The Cryogenic Information Center (CIC) is a not-for-profit corporation dedicated to preserving and distributing cryogenic information to government, industry, and academia. The heart of the CIC is a uniform source of cryogenic data including analyses, design, materials and processes, and test information traceable back to the Cryogenic Data Center of the former National Bureau of Standards. The electronic database is a national treasure containing over 146,000 specific bibliographic citations of cryogenic literature and thermophysical property data dating back to 1829. A new technical/bibliographic inquiry service can perform searches and technical analyses. The Cryogenic Material Properties (CMP) Program consists of computer codes using empirical equations to determine thermophysical material properties with emphasis on the 4-300K range. CMP's objective is to develop a user-friendly standard material property database using the best available data so government and industry can conduct more accurate analyses. The CIC serves to benefit researchers, engineers, and technologists in cryogenics and cryogenic engineering, whether they are new or experienced in the field.

  11. MOSFET's for Cryogenic Amplifiers

    NASA Technical Reports Server (NTRS)

    Dehaye, R.; Ventrice, C. A.

    1987-01-01

    Study seeks ways to build transistors that function effectively at liquid-helium temperatures. Report discusses physics of metaloxide/semiconductor field-effect transistors (MOSFET's) and performances of these devices at cryogenic temperatures. MOSFET's useful in highly sensitive cryogenic preamplifiers for infrared astronomy.

  12. Cryogenic Capillary Screen Heat Entrapment

    NASA Technical Reports Server (NTRS)

    Bolshinskiy, L.G.; Hastings, L.J.; Stathman, G.

    2007-01-01

    Cryogenic liquid acquisition devices (LADs) for space-based propulsion interface directly with the feed system, which can be a significant heat leak source. Further, the accumulation of thermal energy within LAD channels can lead to the loss of sub-cooled propellant conditions and result in feed system cavitation during propellant outflow. Therefore, the fundamental question addressed by this program was: "To what degree is natural convection in a cryogenic liquid constrained by the capillary screen meshes envisioned for LADs.?"Testing was first conducted with water as the test fluid, followed by LN2 tests. In either case, the basic experimental approach was to heat the bottom of a cylindrical column of test fluid to establish stratification patterns measured by temperature sensors located above and below a horizontal screen barrier position. Experimentation was performed without barriers, with screens, and with a solid barrier. The two screen meshes tested were those typically used by LAD designers, "200x1400" and "325x2300", both with Twill Dutch Weave. Upon consideration of both the water and LN2 data it was concluded that heat transfer across the screen meshes was dependent upon barrier thermal conductivity and that the capillary screen meshes were impervious to natural convection currents.

  13. The cryogenic wind tunnel

    NASA Technical Reports Server (NTRS)

    Kilgore, R. A.

    1976-01-01

    Based on theoretical studies and experience with a low speed cryogenic tunnel and with a 1/3-meter transonic cryogenic tunnel, the cryogenic wind tunnel concept was shown to offer many advantages with respect to the attainment of full scale Reynolds number at reasonable levels of dynamic pressure in a ground based facility. The unique modes of operation available in a pressurized cryogenic tunnel make possible for the first time the separation of Mach number, Reynolds number, and aeroelastic effects. By reducing the drive-power requirements to a level where a conventional fan drive system may be used, the cryogenic concept makes possible a tunnel with high productivity and run times sufficiently long to allow for all types of tests at reduced capital costs and, for equal amounts of testing, reduced total energy consumption in comparison with other tunnel concepts.

  14. Experimental study of multiple steady states in homogeneous azeotropic distillation

    SciTech Connect

    Guettinger, T.E.; Dorn, C.; Morari, M.

    1997-03-01

    Bekiaris et al. (1993) explained the existence of multiple steady states in homogeneous ternary azeotropic distillation, on the basis of the analysis of the case of infinite reflux and infinite column length (infinite number of trays). They showed that the predictions of multiple steady states for such infinite columns have relevant implications for columns of finite length operated at finite reflux. In this article, experiments are described for the ternary homogeneous system methanol-methyl butyrate-toluene which demonstrate the existence of multiple steady states (output multiplicities) caused by the vapor-liquid-equilibrium. The experiments on an industrial pilot column show two stable steady states for the same feed flow rate and composition and the same set of operating parameters. The measurements are in excellent agreement with the predictions obtained for infinite columns using the {infinity}/{infinity} analysis tool as well as with stage-by-stage simulation results. These experiments represent the first published study reporting evidence for the predictions and simulations by various researchers showing that type of output multiplicities in distillation.

  15. Steam distillation of crude oils

    SciTech Connect

    Duerksen, J.H.; Hsueh, L.

    1983-04-01

    The objectives of this investigation were to generate crude oil steam distillation data for the prediction of phase behavior in steamflood simulation and to correlate the steam distillation yields for a variety of crude oils. Thirteen steam distillation tests were run on 10 crude oils ranging in gravity from 9.4 to 37/sup 0/API (1.004 to 0.840 g/cm/sup 3/). In each test the crude was steam distilled sequentially at about 220, 300, 400, and 500/sup 0/F (104, 149, 204, and 260/sup 0/C). The cumulative steam distillation yields at 400/sup 0/F (204/sup 0/C) ranged from about 20 to 55 vol%. Experimental results showed that crude oil steam distillation yields at steamflood conditions are significant, even for heavy oils. The effects of differences in steam volume throughput and steam temperature were taken into account when comparing yields for different crudes or repeat runs on the same crude. Steam distillation yields show a high correlation with crude oil API gravity and wax content.

  16. Cryogenic Pound Circuits for Cryogenic Sapphire Oscillators

    NASA Technical Reports Server (NTRS)

    Dick, G. John; Wang, Rabi

    2006-01-01

    Two modern cryogenic variants of the Pound circuit have been devised to increase the frequency stability of microwave oscillators that include cryogenic sapphire-filled cavity resonators. The original Pound circuit is a microwave frequency discriminator that provides feedback to stabilize a voltage-controlled microwave oscillator with respect to an associated cavity resonator. In the present cryogenic Pound circuits, the active microwave devices are implemented by use of state-of-the-art commercially available tunnel diodes that exhibit low flicker noise (required for high frequency stability) and function well at low temperatures and at frequencies up to several tens of gigahertz. While tunnel diodes are inherently operable as amplitude detectors and amplitude modulators, they cannot, by themselves, induce significant phase modulation. Therefore, each of the present cryogenic Pound circuits includes passive circuitry that transforms the AM into the required PM. Each circuit also contains an AM detector that is used to sample the microwave signal at the input terminal of the high-Q resonator for the purpose of verifying the desired AM null at this point. Finally, each circuit contains a Pound signal detector that puts out a signal, at the modulation frequency, having an amplitude proportional to the frequency error in the input signal. High frequency stability is obtained by processing this output signal into feedback to a voltage-controlled oscillator to continuously correct the frequency error in the input signal.

  17. Quantum distillation of bosons

    NASA Astrophysics Data System (ADS)

    Weiss, David

    2015-05-01

    The non-equilibrium dynamics of many-body quantum systems present a series of challenges for theory and opportunities for cold atom experiments. I will describe an experiment in which a bundle of initially trapped superfluid 1D Bose lattice gases is quenched to an untrapped, flat lattice potential. This simple experimental situation in the intermediate coupling regime (U/J between 4 and 9.6) leads to interesting dynamics. These include the progressive dissolution of a fraction of the doublons, as well as the quantum distillation and long term confinement of singlons out of and within the central, doublon-dominated region. We measure these processes by combining absorption imaging, photoassociation and 3-body loss to separately reconstruct the spatial distributions of the expectation values of singlons, doublons and triplons. The qualitative dynamics is reproduced by a Gutzwiller mean field model and the essence of the experiment can be understood by considering simple spatial pictures of site occupancies. This work was supported by the NSF and the ARO.

  18. Cryogenic activities at ESTEC

    NASA Astrophysics Data System (ADS)

    Jewell, C. I.

    1989-05-01

    Although the main present cryogenic activity in ESTEC revolves around the preparation of ISO for launch in 1993, many other activities such as Meteosat second generation, FIRST, GRASP, QUASAT, and X-ray detection using bolometers all require some form of cooling to 80 K or less. ESTEC, in an effort to overcome the major constraint of lifetime when using the solution of cryogens is currently involved in the study and development of two mechanical coolers for work in the temperature ranges of 80 and 4 K are based on a Stirling cycle. This paper gives an overview of ESTEC cryogenic interests with an emphasis on the above mechanical coolers.

  19. FRIB Cryogenic Plant Status

    SciTech Connect

    Dixon, Kelly D.; Ganni, Venkatarao; Knudsen, Peter N.; Casagranda, Fabio

    2015-12-01

    After practical changes were approved to the initial conceptual design of the cryogenic system for MSU FRIB and an agreement was made with JLab in 2012 to lead the design effort of the cryogenic plant, many activities are in place leading toward a cool-down of the linacs prior to 2018. This is mostly due to using similar equipment used at CHLII for the 12 GeV upgrade at JLab and an aggressive schedule maintained by the MSU Conventional Facilities department. Reported here is an updated status of the cryogenic plant, including the equipment procurement status, plant layout, facility equipment and project schedule.

  20. Revamp for more middle distillate

    SciTech Connect

    Weeks, D.J.; Pierce, V.E.

    1985-03-01

    In view of the continued decline in demand for residual fuel oil, the much publicised tightness of refining margins and hence funds for new investment, it is appropriate at this time to review some relatively inexpensive, but well-proven, revamp options that are available to the refiner for increasing yields of mid-distillate products at the expense of fuel oil components. With the partial or complete closure of so much refining capacity, much surplus equipment is available for implementing revamp projects. There is also scope for revamping hitherto moth-balled units and operating them in a manner different from that envisaged during their original design. Some long established conversion processes such as visbreaking and thermal cracking can enjoy a renaissance if demand for distillates remains strong. Mild hydrocracking and distillate dewaxing which are more recent developments in refinery processing can also figure prominently in plans for incremental production of middle distillates.

  1. Zirconium and hafnium tetrachloride separation by extractive distillation with molten zinc chloride lead chloride solvent

    SciTech Connect

    McLaughlin, D.F.; Stoltz, R.A.

    1988-04-12

    In an extractive distillation method for separating hafniuim tetrachloride from zirconium tetrachloride of the type wherein a mixture of zirconium and hafnium tetrachlorides is introduced into an extractive distillation column, which extractive distillation column has a reboiler connected at the bottom and a reflux condenser connected at the top and wherein a molten salt solvent is circulated into the reflux condenser and through the column to provide a liquid phase, and wherein molten salt solvent containing zirconium tetrachloride is taken from the reboiler and run through a stripper to remove zirconium tetrachloride product from the molten salt solvent and the stripped molten salt solvent is returned to the reflux condenser and hafnium tetrachloride enriched vapor is taken as product from the reflux condenser, the improvement is described comprising: the molten salt having a composition of at least 30 mole percent zinc chloride and at least 10 mole percent of lead chloride.

  2. Distillation process using microchannel technology

    DOEpatents

    Tonkovich, Anna Lee; Simmons, Wayne W.; Silva, Laura J.; Qiu, Dongming; Perry, Steven T.; Yuschak, Thomas; Hickey, Thomas P.; Arora, Ravi; Smith, Amanda; Litt, Robert Dwayne; Neagle, Paul

    2009-11-03

    The disclosed invention relates to a distillation process for separating two or more components having different volatilities from a liquid mixture containing the components. The process employs microchannel technology for effecting the distillation and is particularly suitable for conducting difficult separations, such as the separation of ethane from ethylene, wherein the individual components are characterized by having volatilities that are very close to one another.

  3. Liquid cryogenic lubricant

    NASA Technical Reports Server (NTRS)

    Dietrich, M. W.; Townsend, D. P.; Zaretsky, E. V.

    1970-01-01

    Fluorinated polyethers are suitable lubricants for rolling-element bearings in cryogenic systems. Lubrication effectiveness is comparable to that of super-refined mineral oil lubricants operating at room temperature.

  4. CRYOGENICS IN BEPCII UPGRADE.

    SciTech Connect

    JIA,L.; WANG,L.; LI,S.

    2002-07-22

    THIS PAPER PRESENTS A CRYOGENIC DESIGN FOR UPGRADING THE BEIJING ELECTRON POSITRON COLLIDER AT THE INSTITUTE OF HIGH ENERGY PHYSICS IN BEIJING. THE UPGRADE INVOLVES 3 NEW SUPERCONDUCTING FACILITIES, THE INTERACTION REGION QUADRUPOLE MAGNETS, THE DETECTOR SOLENOID MAGNETS AND THE SRF CAVITIES. FOR COOLING OF THESE DEVICES, A NEW CRYPLANT WITH A TOTAL CAPACITY OF 1.0KW AT 4.5K IS TO BE BUILT AT IHEP. AN INTEGRATED CRYOGENIC DESIGN TO FIT THE BEPCII CRYOGENIC LOADS WITH HIGH EFFICIENCY IS CARRIEDOUT USING COMPUTATIONAL PROCESS ANALYSIS SOFTWARE WITH THE EMPHASES ON ECONOMICS AND SAFETY IN BOTH CONSTRUCTION AND OPERATION OF THE PLANT. THIS PAPER DESCRIBES THE CRYOGENIC CHARACTERISTICS OF EACH SUPERCONDUCTING DEVICE, THEIR COOLING SCHEMES AND THE OVERALL CRYOPLANT.

  5. Cryogenic Insulation Systems

    NASA Technical Reports Server (NTRS)

    Augustynowicz, S. D.; Fesmire, J. E.; Wikstrom, J. P.

    1999-01-01

    The results of a comparative study of cryogenic insulation systems performed are presented. The key aspects of thermal insulation relative to cryogenic system design, testing, manufacturing, and maintenance are discussed. An overview of insulation development from an energy conservation perspective is given. Conventional insulation materials for cryogenic applications provide three levels of thermal conductivity. Actual thermal performance of standard multilayer insulation (MLI) is several times less than laboratory performance and often 10 times worse than ideal performance. The cost-effectiveness of the insulation system depends on thermal performance; flexibility and durability; ease of use in handling, installation, and maintenance; and overall cost including operations, maintenance, and life cycle. Results of comprehensive testing of both conventional and novel materials such as aerogel composites using cryostat boil-off methods are given. The development of efficient, robust cryogenic insulation systems that operate at a soft vacuum level is the primary focus of this paper.

  6. Cryogenic Feedthrough Test Rig

    NASA Technical Reports Server (NTRS)

    Skaff, Antony

    2009-01-01

    The cryogenic feedthrough test rig (CFTR) allows testing of instrumentation feedthroughs at liquid oxygen and liquid hydrogen temperature and pressure extremes (dangerous process fluid) without actually exposing the feedthrough to a combustible or explosive process fluid. In addition, the helium used (inert gas), with cryogenic heat exchangers, exposes the feedthrough to that environment that allows definitive leak rates of feedthrough by typical industry-standard helium mass spectrometers.

  7. Distillation and Air Stripping Designs for the Lunar Surface

    NASA Technical Reports Server (NTRS)

    Boul, Peter J.; Lange, Kevin E.; Conger, Bruce; Anderson, Molly

    2009-01-01

    Air stripping and distillation are two different gravity-based methods, which may be applied to the purification of wastewater on the lunar base. These gravity-based solutions to water processing are robust physical separation techniques, which may be advantageous to many other techniques for their simplicity in design and operation. The two techniques can be used in conjunction with each other to obtain high purity water. The components and feed compositions for modeling waste water streams are presented in conjunction with the Aspen property system for traditional stage distillation models and air stripping models. While the individual components for each of the waste streams will vary naturally within certain bounds, an analog model for waste water processing is suggested based on typical concentration ranges for these components. Target purity levels for the for recycled water are determined for each individual component based on NASA s required maximum contaminant levels for potable water Distillation processes are modeled separately and in tandem with air stripping to demonstrate the potential effectiveness and utility of these methods in recycling wastewater on the Moon. Optimum parameters such as reflux ratio, feed stage location, and processing rates are determined with respect to the power consumption of the process. Multistage distillation is evaluated for components in wastewater to determine the minimum number of stages necessary for each of 65 components in humidity condensate and urine wastewater mixed streams. Components of the wastewater streams are ranked by Henry s Law Constant and the suitability of air stripping in the purification of wastewater in terms of component removal is evaluated. Scaling factors for distillation and air stripping columns are presented to account for the difference in the lunar gravitation environment. Commercially available distillation and air stripping units which are considered suitable for Exploration Life Support

  8. Spacecraft cryogenic gas storage systems

    NASA Technical Reports Server (NTRS)

    Rysavy, G.

    1971-01-01

    Cryogenic gas storage systems were developed for the liquid storage of oxygen, hydrogen, nitrogen, and helium. Cryogenic storage is attractive because of the high liquid density and low storage pressure of cryogens. This situation results in smaller container sizes, reduced container-strength levels, and lower tankage weights. The Gemini and Apollo spacecraft used cryogenic gas storage systems as standard spacecraft equipment. In addition to the Gemini and Apollo cryogenic gas storage systems, other systems were developed and tested in the course of advancing the state of the art. All of the cryogenic storage systems used, developed, and tested to date for manned-spacecraft applications are described.

  9. Comparison of advanced distillation control methods. Third annual report

    SciTech Connect

    Riggs, J.B.

    1997-07-01

    Detailed dynamic simulations of three industrial distillation columns (a propylene/propane splitter, a xylene/toluene column, and a depropanizer) have been used to study the issue of configuration selection for diagonal PI dual composition controls, feedforward from a feed composition analyzer, and decouplers. Auto Tune Variation (ATV) identification with on-line detuning for setpoint changes was used for tuning the diagonal proportional integral (PI) composition controls. In addition, robustness tests were conducted by inducting reboiler duty upsets. For single composition control, the (L, V) configuration was found to be best. For dual composition control, the optimum configuration changes from one column to another. Moreover, the use of analysis tools, such as RGA, appears to be of little value in identifying the optimum configuration for dual composition control. Using feedforward from a feed composition analyzer and using decouplers are shown to offer significant advantages for certain specific cases.

  10. Sample distillation/graphitization system for carbon pool analysis by accelerator mass spectrometry (AMS)

    NASA Astrophysics Data System (ADS)

    Pohlman, J. W.; Knies, D. L.; Grabowski, K. S.; DeTurck, T. M.; Treacy, D. J.; Coffin, R. B.

    2000-10-01

    A facility at the Naval Research Laboratory (NRL), Washington, DC, has been developed to extract, trap, cryogenically distill and graphitize carbon from a suite of organic and inorganic carbon pools for analysis by accelerator mass spectrometry (AMS). The system was developed to investigate carbon pools associated with the formation and stability of methane hydrates. However, since the carbon compounds found in hydrate fields are ubiquitous in aquatic ecosystems, this apparatus is applicable to a number of oceanographic and environmental sample types. Targeted pools are dissolved methane, dissolved organic carbon (DOC), dissolved inorganic carbon (DIC), solid organic matrices (e.g., seston, tissue and sediments), biomarkers and short chained (C 1-C 5) hydrocarbons from methane hydrates. In most instances, the extraction, distillation and graphitization events are continuous within the system, thus, minimizing the possibility of fractionation or contamination during sample processing. A variety of methods are employed to extract carbon compounds and convert them to CO 2 for graphitization. Dissolved methane and DIC from the same sample are sparged and cryogenically separated before the methane is oxidized in a high temperature oxygen stream. DOC is oxidized to CO 2 by 1200 W ultraviolet photo-oxidation lamp, and solids oxidized in sealed, evacuated tubes. Hydrocarbons liberated from the disassociation of gas hydrates are cryogenically separated with a cryogenic temperature control unit, and biomarkers separated and concentrated by preparative capillary gas chromatography (PCGC). With this system, up to 20 samples, standards or blanks can be processed per day.

  11. TPC magnet cryogenic system

    SciTech Connect

    Green, M.A.; Burns, W.A.; Taylor, J.D.; Van Slyke, H.W.

    1980-03-01

    The Time Projection Chamber (TPC) magnet at LBL and its compensation solenoids are adiabatically stable superconducting solenoid magnets. The cryogenic system developed for the TPC magnet is discussed. This system uses forced two-phase tubular cooling with the two cryogens in the system. The liquid helium and liquid nitrogen are delivered through the cooled load by forced tubular flow. The only reservoirs of liquid cryogen exist in the control dewar (for liquid helium) and the conditioner dewar (for liquid nitrogen). The operation o these systems during virtually all phases of system operation are described. Photographs and diagrams of various system components are shown, and cryogenic system data are presented in the following sections: (1) heat leaks into the TPC coil package and the compensation solenoids; (2) heat leaks to various components of the TPC magnet cryogenics system besides the magnets and control dewar; (3) the control dewar and its relationship to the rest of the system; (4) the conditioner system and its role in cooling down the TPC magnet; (5) gas-cooled electrical leads and charging losses; and (6) a summation of the liquid helium and liquid nitrogen requirements for the TPC superconducting magnet system.

  12. Optimal protocols for nonlocality distillation

    SciTech Connect

    Hoeyer, Peter; Rashid, Jibran

    2010-10-15

    Forster et al. recently showed that weak nonlocality can be amplified by giving the first protocol that distills a class of nonlocal boxes (NLBs) [Phys. Rev. Lett. 102, 120401 (2009)] We first show that their protocol is optimal among all nonadaptive protocols. We next consider adaptive protocols. We show that the depth-2 protocol of Allcock et al. [Phys. Rev. A 80, 062107 (2009)] performs better than previously known adaptive depth-2 protocols for all symmetric NLBs. We present a depth-3 protocol that extends the known region of distillable NLBs. We give examples of NLBs for which each of the Forster et al., the Allcock et al., and our protocols perform best. The understanding we develop is that there is no single optimal protocol for NLB distillation. The choice of which protocol to use depends on the noise parameters for the NLB.

  13. Distillation Apparatuses Using Household Items

    NASA Astrophysics Data System (ADS)

    Campanizzi, Danielle R. D.; Mason, Brenda; Hermann, Christine K. F.

    1999-08-01

    A simple apparatus to demonstrate distillation principles can be very difficult to build without the specialty glassware found in chemistry laboratories. We have built inexpensive but effective distillation apparatuses from equipment that can be easily purchased at local department, grocery, or hardware stores. In one apparatus, colored water is heated to boiling and the condensed vapors drip into another container. In another apparatus, acetone is heated to boiling with hot water and the acetone vapors condense onto a Styrofoam cup. The Styrofoam cup is softened by the acetone and collapses. Rubbing alcohol can be used instead of acetone, but the cup is not softened and the boiling point is much higher. Both apparatuses can be used in a classroom. Both are simple, cost-effective ways of demonstrating distillation, evaporation, and condensation. They would be ideal to use in elementary and middle school classrooms when explaining these concepts.

  14. Solar power water distillation unit

    NASA Astrophysics Data System (ADS)

    Hameed, Kamran; Muzammil Khan, Muhammad; Shahrukh Ateeq, Ijlal; Omair, Syed Muhammad; Ahmer, Muhammad; Wajid, Abdul

    2013-06-01

    Clean drinking water is the basic necessity for every human being, but about 1.1 billion people in the world lacked proper drinking water. There are many different types of water purification processes such as filtration, reverse osmosis, ultraviolet radiation, carbon absorption, but the most reliable processes are distillation and boiling. Water purification, such as distillation, is especially important in regions where water resources or tap water is not suitable for ingesting without boiling or chemical treatment. In design project It treats the water by combining different methods such as Filtration, Distillation and a technique called concentrated solar power (CSP). Distillation is literally the method seen in nature, whereby: the sun heats the water on the earth's surface, the water is turned into a vapor (evaporation) and rises, leaving contaminants behind, to form clouds. As the upper atmosphere drops in temperature the vapors cool and convert back to water to form water. In this project distillation is achieved by using a parabolic mirror which boils water at high temperature. Filtration is done by sand filter and carbon filter. First sand filter catches the sand particles and the carbon filter which has granules of active carbon is used to remove odor dissolved gases from water. This is the Pre-treatment of water. The filtered water is then collected in a water container at a focus of parabolic mirror where distillation process is done. Another important feature of designed project is the solar tracking of a parabolic mirror which increases the efficiency of a parabolic mirror [1],[2].

  15. Solar distillation of sea water

    SciTech Connect

    Subramanyam, S. )

    1989-01-01

    Indian coastal and fishing villages suffer from scarcity of potable water. Solar distillation could provide a solution to this problem by adopting the following criteria: (1) Integration of distillation and storage systems with the house design. (2) Public supply of sea water and a public drain pipe system to periodically drain away the concentrated brine. (3) Harvest and store rain water to tide over cloudy rainy periods. In India there has been a thrust towards centralized non-conventional energy systems. Decentralized non-conventional energy devices and centralized service support units may offer a better solution. 1 fig.

  16. Bounds for nonlocality distillation protocols

    SciTech Connect

    Forster, Manuel

    2011-06-15

    Nonlocality can be quantified by the violation of a Bell inequality. Since this violation may be amplified by local operations, an alternative measure has been proposed--distillable nonlocality. The alternative measure is difficult to calculate exactly due to the double exponential growth of the parameter space. In this paper, we give a way to bound the distillable nonlocality of a resource by the solutions to a related optimization problem. Our upper bounds are exponentially easier to compute than the exact value and are shown to be meaningful in general and tight in some cases.

  17. Extended testing of compression distillation.

    NASA Technical Reports Server (NTRS)

    Bambenek, R. A.; Nuccio, P. P.

    1972-01-01

    During the past eight years, the NASA Manned Spacecraft Center has supported the development of an integrated water and waste management system which includes the compression distillation process for recovering useable water from urine, urinal flush water, humidity condensate, commode flush water, and concentrated wash water. This paper describes the design of the compression distillation unit, developed for this system, and the testing performed to demonstrate its reliability and performance. In addition, this paper summarizes the work performed on pretreatment and post-treatment processes, to assure the recovery of sterile potable water from urine and treated urinal flush water.

  18. Bakery product from distiller's grain

    SciTech Connect

    Reddy, J.A.; Stoker, R.

    1993-07-06

    A method is described for preparing a bran from a solid fermentation wet distiller's grain (WDG) or distiller's dried grain with solubles (DDGS), which consisting essentially of: adding sodium bicarbonate at about 0.05-5 weight percent, amino acid at about 0.05-5 weight percent and potato starch at about 10-50 weight percent in the form of additives to WDG or DDGS; blending the WDG/DDGS-additive mix; and drying the blended mix to form a bran suitable for use in products for human consumption.

  19. Cryogenic process simulation

    SciTech Connect

    Panek, J.; Johnson, S.

    1994-01-01

    Combining accurate fluid property databases with a commercial equation-solving software package running on a desktop computer allows simulation of cryogenic processes without extensive computer programming. Computer simulation can be a powerful tool for process development or optimization. Most engineering simulations to date have required extensive programming skills in languages such as Fortran, Pascal, etc. Authors of simulation code have also usually been responsible for choosing and writing the particular solution algorithm. This paper describes a method of simulating cryogenic processes with a commercial software package on a desktop personal computer that does not require these traditional programming tasks. Applications include modeling of cryogenic refrigerators, heat exchangers, vapor-cooled power leads, vapor pressure thermometers, and various other engineering problems.

  20. Cryogenic wind tunnels. II

    NASA Technical Reports Server (NTRS)

    Kilgore, Robert A.

    1987-01-01

    The application of the cryogenic concept to various types of tunnels including Ludwieg tube tunnel, Evans clean tunnel, blowdown, induced-flow, and continuous-flow fan-driven tunnels is discussed. Benefits related to construction and operating costs are covered, along with benefits related to new testing capabilities. It is noted that cooling the test gas to very low temperatures increases Reynolds number by more than a factor of seven. From the energy standpoint, ambient-temperature fan-driven closed-return tunnels are considered to be the most efficient type of tunnel, while a large reduction in the required tunnel stagnation pressure can be achieved through cryogenic operation. Operating envelopes for three modes of operation for a cryogenic transonic pressure tunnel with a 2.5 by 2.5 test section are outlined. A computer program for calculating flow parameters and power requirements for wind tunnels with operating temperatures from saturation to above ambient is highlighted.

  1. Ball Aerospace Actuator Cryogenic Testing

    NASA Technical Reports Server (NTRS)

    Kingsbury, Lana; Lightsey, Paul; Quigley, Phil; Rutkowski, Joel; Russell, J. Kevin (Technical Monitor)

    2002-01-01

    The ambient testing characterizing step size and repeatability for the Ball Aerospace Cryogenic Nano-Positioner actuators for the AMSD (Advanced Mirror System Demonstrator) program has been completed and are presented. Current cryogenic testing is underway. Earlier cryogenic test results for a pre-cursor engineering model are presented.

  2. Cryogenic Hybrid Magnetic Bearing

    NASA Technical Reports Server (NTRS)

    Meeks, Crawford R.; Dirusso, Eliseo; Brown, Gerald V.

    1994-01-01

    Cryogenic hybrid magnetic bearing is example of class of magnetic bearings in which permanent magnets and electromagnets used to suspend shafts. Electromagnets provide active control of position of shaft. Bearing operates at temperatures from -320 degrees F (-196 degrees C) to 650 degrees F (343 degrees C); designed for possible use in rocket-engine turbopumps, where effects of cryogenic environment and fluid severely limit lubrication of conventional ball bearings. This and similar bearings also suitable for terrestrial rotating machinery; for example, gas-turbine engines, high-vacuum pumps, canned pumps, precise gimbals that suspend sensors, and pumps that handle corrosive or gritty fluids.

  3. Cryogenic Model Materials

    NASA Technical Reports Server (NTRS)

    Kimmel, W. M.; Kuhn, N. S.; Berry, R. F.; Newman, J. A.

    2001-01-01

    An overview and status of current activities seeking alternatives to 200 grade 18Ni Steel CVM alloy for cryogenic wind tunnel models is presented. Specific improvements in material selection have been researched including availability, strength, fracture toughness and potential for use in transonic wind tunnel testing. Potential benefits from utilizing damage tolerant life-prediction methods, recently developed fatigue crack growth codes and upgraded NDE methods are also investigated. Two candidate alloys are identified and accepted for cryogenic/transonic wind tunnel models and hardware.

  4. Unique Cryogenic Welded Structures

    NASA Astrophysics Data System (ADS)

    Yushchenko, K. A.; Monko, G. G.

    2004-06-01

    For the last few decades, the E. O. Paton Electric Welding Institute has been active in the field of cryogenic materials science. Integrated research on development of new grades of steels and alloys for cryogenic engineering was carried out in collaboration with the leading institutions of Russia, Ukraine, and Georgia. Commercially applied welding technologies and consumables were developed. They include large, spherical tanks for storage of liquefied gases (from oxygen to helium) under high pressures; space simulators with a capacity of 10 000 m3 and more; and load-carrying elements of superconducting fusion magnetic systems for the TOKAMAK, MGD, and ITER series.

  5. Unique Cryogenic Welded Structures

    SciTech Connect

    Yushchenko, K.A.; Monko, G.G.

    2004-06-28

    For the last few decades, the E. O. Paton Electric Welding Institute has been active in the field of cryogenic materials science. Integrated research on development of new grades of steels and alloys for cryogenic engineering was carried out in collaboration with the leading institutions of Russia, Ukraine, and Georgia. Commercially applied welding technologies and consumables were developed. They include large, spherical tanks for storage of liquefied gases (from oxygen to helium) under high pressures; space simulators with a capacity of 10 000 m3 and more; and load-carrying elements of superconducting fusion magnetic systems for the TOKAMAK, MGD, and ITER series.

  6. Cryogenic Propellant Densification Study

    NASA Technical Reports Server (NTRS)

    Ewart, R. O.; Dergance, R. H.

    1978-01-01

    Ground and vehicle system requirements are evaluated for the use of densified cryogenic propellants in advanced space transportation systems. Propellants studied were slush and triple point liquid hydrogen, triple point liquid oxygen, and slush and triple point liquid methane. Areas of study included propellant production, storage, transfer, vehicle loading and system requirements definition. A savings of approximately 8.2 x 100,000 Kg can be achieved in single stage to orbit gross liftoff weight for a payload of 29,484 Kg by utilizing densified cryogens in place of normal boiling point propellants.

  7. Entanglement preservation by continuous distillation

    SciTech Connect

    Mundarain, D.; Orszag, M.

    2009-05-15

    We study the two-qubit entanglement preservation for a system in the presence of independent thermal baths. We use a combination of filtering operations and distillation protocols as a series of frequent measurements on the system. It is shown that a small fraction of the total amount of available copies of the system preserves or even improves its initial entanglement during the evolution.

  8. Purifying Aluminum by Vacuum Distillation

    NASA Technical Reports Server (NTRS)

    Du Fresne, E. R.

    1985-01-01

    Proposed method for purifying aluminum employs one-step vacuum distillation. Raw material for process impure aluminum produced in electrolysis of aluminum ore. Impure metal melted in vacuum. Since aluminum has much higher vapor pressure than other constituents, boils off and condenses on nearby cold surfaces in proportions much greater than those of other constituents.

  9. Corrosion inhibition for distillation apparatus

    DOEpatents

    Baumert, Kenneth L.; Sagues, Alberto A.; Davis, Burtron H.; Schweighardt, Frank K.

    1985-01-01

    Tower material corrosion in an atmospheric or sub-atmospheric distillation tower in a coal liquefaction process is reduced or eliminated by subjecting chloride-containing tray contents to an appropriate ion-exchange resin to remove chloride from such tray contents materials.

  10. Plant transpiration distillation of water

    SciTech Connect

    Virostko, M.K.; Spielberg, J.I.

    1986-01-01

    A project using solar energy and the transpiration of plants for the distillation of water is described. Along with determining which of three plants thrived best growing in a still, the experiment also revealed that the still functioned nearly as well in inclement weather as in fair weather.

  11. Corrosion inhibition for distillation apparatus

    SciTech Connect

    Baumert, K.L.; Davis, B.H.; Sagues, A.A.; Schweighardt, F.K.

    1985-04-30

    Tower material corrosion in an atmospheric or subatmospheric distillation tower in a coal liquefaction process is reduced or eliminated by subjecting chloride-containing tray contents to an appropriate ion-exchange resin to remove chloride from such tray contents materials.

  12. 21 CFR 184.1848 - Starter distillate.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... distillate) is a steam distillate of the culture of any or all of the following species of bacteria grown on a medium consisting of skim milk usually fortified with about 0.1 percent citric acid:...

  13. Cryogenics Research and Engineering Experience

    NASA Technical Reports Server (NTRS)

    Toro Medina, Jaime A.

    2013-01-01

    Energy efficient storage, transfer and use of cryogens and cryogenic propellants on Earth and in space have a direct impact on NASA, government and commercial programs. Research and development on thermal insulation, propellant servicing, cryogenic components, material properties and sensing technologies provides industry, government and research institutions with the cross-cutting technologies to manage low-temperature applications. Under the direction of the Cryogenic Testing Lab at Kennedy Space Center, the work experience acquired allowed me to perform research, testing, design and analysis of current and future cryogenic technologies to be applied in several projects.

  14. Valve for cryogenic service

    DOEpatents

    Worwetz, H.A.

    1975-09-02

    This patent relates to a valve for use with a liquefied gas at cryogenic temperatures in which a pair of joined knife edges are bellows controlled to contact an indium alloy seat in an annular slot when flow is to be stopped. The sealing alloy may be renewed by heating in situ. (auth)

  15. Compact cryogenic inductors

    SciTech Connect

    Singh, S.K.; Carr, W.J. Jr.; Fagan, T.J. Jr.; Hordubay, T.D.; Chuboy, H.L. . Science and Technology Center)

    1994-07-01

    Power systems requiring power levels as high as a few megawatts to a few gigawatts for periods of several microseconds to several milliseconds with repetitive frequencies of a few hertz to a few kilohertz are being considered for potential space applications. The impulsive nature of the power presents the opportunity to use inductive energy storage techniques for pulse duty to enhance economic and practical considerations. An inductors must be efficient, lightweight, and reliable, and it must have high energy density if it is to be used in space based power systems. Cryogenic inductors are best studied for such an application. Parametric analyses of the two potential types of cryogenic inductors (superconducting and hyperconducting reveal that the hyperconducting (high purity aluminum)) inductor would be significantly lighter and achieve higher energy densities without the added penalty of a helium refrigeration system, thus resulting in improved overall system reliability. The lightweight hyperconducting cryogenic inductor technology is, however, in its infancy. This paper describes the required technology base which would allow the eventual application of the lightweight cryogenic inductor in space power systems, and also conclusively demonstrates the underlying principles.

  16. High Power Cryogenic Targets

    SciTech Connect

    Gregory Smith

    2011-08-01

    The development of high power cryogenic targets for use in parity violating electron scattering has been a crucial ingredient in the success of those experiments. As we chase the precision frontier, the demands and requirements for these targets have grown accordingly. We discuss the state of the art, and describe recent developments and strategies in the design of the next generation of these targets.

  17. Real-time monitoring of distillations by near-infrared spectroscopy.

    PubMed

    Pasquini, Celio; Scafi, Sérgio H F

    2003-05-15

    A simple device is described to couple a fast-scanning acoustooptic tunable filter-based NIR spectrophotometer to a distillation apparatus for monitoring the condensed vapor in real time. The device consists of a small funnel whose glass neck (2-mm diameter) is bent into an "U" format to produce a flow cell of approximately 150-microL inner volume. A pair of optical fibers is used to deliver the monochromatic light and to collect the fraction passing through the glass tube. The end of the condenser of the distillation head touches the wall of the small funnel. The condensed liquid flows uncoupled from pressure changes in the interior of the distillation head. Absorbance spectra were obtained, during the distillation, as averages of 50 scans (4 s) every 5 s in the spectral range 950-1800 nm with nominal resolution of 2.0 nm. In the first experiments, the distillations were performed at constant power supplied to the sample (25 mL) in a microdistillation apparatus working without any type of reflux column. The usefulness of the real-time monitoring of distillation is demonstrated using some prepared binary mixtures and by comparing the distillation behavior of adulterated and regular gasoline samples. Data analysis and interpretation are facilitated by employing principal component analysis. The system accesses the composition of the condensate, which can separate and concentrate one or more compounds present in the original sample. PMID:12918966

  18. 27 CFR 24.216 - Distilling material.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2014-04-01 2014-04-01 false Distilling material. 24..., DEPARTMENT OF THE TREASURY ALCOHOL WINE Production of Other Than Standard Wine § 24.216 Distilling material... fruit residues, for use as distilling material, using any quantity of water desired to...

  19. 27 CFR 19.301 - Distillation.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2013-04-01 2013-04-01 false Distillation. 19.301 Section 19.301 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT... of Spirits § 19.301 Distillation. The distillation of spirits must be done in a continuous...

  20. 27 CFR 19.316 - Distillation.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Distillation. 19.316 Section 19.316 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Production § 19.316 Distillation. The...

  1. 27 CFR 19.301 - Distillation.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2011-04-01 2011-04-01 false Distillation. 19.301 Section 19.301 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT... of Spirits § 19.301 Distillation. The distillation of spirits must be done in a continuous...

  2. 27 CFR 19.301 - Distillation.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2012-04-01 2012-04-01 false Distillation. 19.301 Section 19.301 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT... of Spirits § 19.301 Distillation. The distillation of spirits must be done in a continuous...

  3. 27 CFR 19.301 - Distillation.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2014-04-01 2014-04-01 false Distillation. 19.301 Section 19.301 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT... of Spirits § 19.301 Distillation. The distillation of spirits must be done in a continuous...

  4. 27 CFR 24.216 - Distilling material.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2011-04-01 2011-04-01 false Distilling material. 24..., DEPARTMENT OF THE TREASURY LIQUORS WINE Production of Other Than Standard Wine § 24.216 Distilling material... fruit residues, for use as distilling material, using any quantity of water desired to...

  5. Cascade Distillation Subsystem Development: Progress Toward a Distillation Comparison Test

    NASA Technical Reports Server (NTRS)

    Callahan, M. R.; Lubman, A.; Pickering, Karen D.

    2009-01-01

    Recovery of potable water from wastewater is essential for the success of long-duration manned missions to the Moon and Mars. Honeywell International and a team from NASA Johnson Space Center (JSC) are developing a wastewater processing subsystem that is based on centrifugal vacuum distillation. The wastewater processor, referred to as the Cascade Distillation Subsystem (CDS), utilizes an innovative and efficient multistage thermodynamic process to produce purified water. The rotary centrifugal design of the system also provides gas/liquid phase separation and liquid transport under microgravity conditions. A five-stage subsystem unit has been designed, built, delivered and integrated into the NASA JSC Advanced Water Recovery Systems Development Facility for performance testing. A major test objective of the project is to demonstrate the advancement of the CDS technology from the breadboard level to a subsystem level unit. An initial round of CDS performance testing was completed in fiscal year (FY) 2008. Based on FY08 testing, the system is now in development to support an Exploration Life Support (ELS) Project distillation comparison test expected to begin in early 2009. As part of the project objectives planned for FY09, the system will be reconfigured to support the ELS comparison test. The CDS will then be challenged with a series of human-gene-rated waste streams representative of those anticipated for a lunar outpost. This paper provides a description of the CDS technology, a status of the current project activities, and data on the system s performance to date.

  6. Assisted Distillation of Quantum Coherence.

    PubMed

    Chitambar, E; Streltsov, A; Rana, S; Bera, M N; Adesso, G; Lewenstein, M

    2016-02-19

    We introduce and study the task of assisted coherence distillation. This task arises naturally in bipartite systems where both parties work together to generate the maximal possible coherence on one of the subsystems. Only incoherent operations are allowed on the target system, while general local quantum operations are permitted on the other; this is an operational paradigm that we call local quantum-incoherent operations and classical communication. We show that the asymptotic rate of assisted coherence distillation for pure states is equal to the coherence of assistance, an analog of the entanglement of assistance, whose properties we characterize. Our findings imply a novel interpretation of the von Neumann entropy: it quantifies the maximum amount of extra quantum coherence a system can gain when receiving assistance from a collaborative party. Our results are generalized to coherence localization in a multipartite setting and possible applications are discussed. PMID:26943512

  7. Assisted Distillation of Quantum Coherence

    NASA Astrophysics Data System (ADS)

    Chitambar, E.; Streltsov, A.; Rana, S.; Bera, M. N.; Adesso, G.; Lewenstein, M.

    2016-02-01

    We introduce and study the task of assisted coherence distillation. This task arises naturally in bipartite systems where both parties work together to generate the maximal possible coherence on one of the subsystems. Only incoherent operations are allowed on the target system, while general local quantum operations are permitted on the other; this is an operational paradigm that we call local quantum-incoherent operations and classical communication. We show that the asymptotic rate of assisted coherence distillation for pure states is equal to the coherence of assistance, an analog of the entanglement of assistance, whose properties we characterize. Our findings imply a novel interpretation of the von Neumann entropy: it quantifies the maximum amount of extra quantum coherence a system can gain when receiving assistance from a collaborative party. Our results are generalized to coherence localization in a multipartite setting and possible applications are discussed.

  8. Cryogenic thermal diodes

    NASA Astrophysics Data System (ADS)

    Paulsen, Brandon R.; Batty, J. C.; Agren, John

    2000-01-01

    Space based cryogenic thermal management systems for advanced infrared sensor platforms are a critical failure mode to the spacecraft missions they are supporting. Recent advances in cryocooler technologies have increased the achievable cooling capacities and decreased the operating temperatures of these systems, but there is still a fundamental need for redundancy in these systems. Cryogenic thermal diodes act as thermal switches, allowing heat to flow through them when in a conduction mode and restricting the flow of heat when in an isolation mode. These diodes will allow multiple cryocoolers to cool a single infrared focal plane array. The Space Dynamics Laboratory has undertaken an internal research and development effort to develop this innovative technology. This paper briefly describes the design parameters of several prototype thermal diodes that were developed and tested. .

  9. Cryogenic mirror analysis

    NASA Technical Reports Server (NTRS)

    Nagy, S.

    1988-01-01

    Due to extraordinary distances scanned by modern telescopes, optical surfaces in such telescopes must be manufactured to unimaginable standards of perfection of a few thousandths of a centimeter. The detection of imperfections of less than 1/20 of a wavelength of light, for application in the building of the mirror for the Space Infrared Telescope Facility, was undertaken. Because the mirror must be kept very cold while in space, another factor comes into effect: cryogenics. The process to test a specific morror under cryogenic conditions is described; including the follow-up analysis accomplished through computer work. To better illustrate the process and analysis, a Pyrex Hex-Core mirror is followed through the process from the laser interferometry in the lab, to computer analysis via a computer program called FRINGE. This analysis via FRINGE is detailed.

  10. Oxygen chemisorption cryogenic refrigerator

    NASA Technical Reports Server (NTRS)

    Jones, Jack A. (Inventor)

    1987-01-01

    The present invention relates to a chemisorption compressor cryogenic refrigerator which employs oxygen to provide cooling at 60 to 100 K. The invention includes dual vessels containing an oxygen absorbent material, alternately heated and cooled to provide a continuous flow of high pressure oxygen, multiple heat exchangers for precooling the oxygen, a Joule-Thomson expansion valve system for expanding the oxygen to partially liquefy it and a liquid oxygen pressure vessel. The primary novelty is that, while it was believed that once oxygen combined with an element or compound the reaction could not reverse to release gaseous oxygen, in this case oxygen will indeed react in a reversible fashion with certain materials and will do so at temperatures and pressures which make it practical for incorporation into a cryogenic refrigeration system.

  11. Flexible cryogenic conduit

    DOEpatents

    Brindza, Paul Daniel; Wines, Robin Renee; Takacs, James Joseph

    1999-01-01

    A flexible and relatively low cost cryogenic conduit is described. The flexible cryogenic conduit of the present invention comprises a first inner corrugated tube with single braided serving, a second outer corrugated tube with single braided serving concentric with the inner corrugated tube, and arranged outwardly about the periphery of the inner corrugated tube and between the inner and outer corrugated tubes: a superinsulation layer; a one half lap layer of polyester ribbon; a one half lap layer of copper ribbon; a spirally wound refrigeration tube; a second one half lap layer of copper ribbon; a second one half lap layer of polyester ribbon; a second superinsulation layer; a third one half lap layer of polyester ribbon; and a spirally wound stretchable and compressible filament.

  12. Cryogenic support system

    DOEpatents

    Nicol, T.H.; Niemann, R.C.; Gonczy, J.D.

    1988-11-01

    A support system is disclosed for restraining large masses at very low or cryogenic temperatures. The support system employs a tie bar that is pivotally connected at opposite ends to an anchoring support member and a sliding support member. The tie bar extends substantially parallel to the longitudinal axis of the cold mass assembly, and comprises a rod that lengthens when cooled and a pair of end attachments that contract when cooled. The rod and end attachments are sized so that when the tie bar is cooled to cryogenic temperature, the net change in tie bar length is approximately zero. Longitudinal force directed against the cold mass assembly is distributed by the tie bar between the anchoring support member and the sliding support member. 7 figs.

  13. Cryogenic support system

    DOEpatents

    Nicol, Thomas H.; Niemann, Ralph C.; Gonczy, John D.

    1988-01-01

    A support system is disclosed for restraining large masses at very low or cryogenic temperatures. The support system employs a tie bar that is pivotally connected at opposite ends to an anchoring support member and a sliding support member. The tie bar extends substantially parallel to the longitudinal axis of the cold mass assembly, and comprises a rod that lengthens when cooled and a pair of end attachments that contract when cooled. The rod and end attachments are sized so that when the tie bar is cooled to cryogenic temperature, the net change in tie bar length is approximately zero. Longitudinal force directed against the cold mass assembly is distributed by the tie bar between the anchoring support member and the sliding support member.

  14. Stirling cycle cryogenic cooler

    NASA Astrophysics Data System (ADS)

    Gasser, M. G.; Sherman, A.; Studer, P. A.; Daniels, A.; Goldowsky, M. P.

    1983-06-01

    A long lifetime Stirling cycle cryogenic cooler particularly adapted for space applications is described. It consists of a compressor section centrally aligned end to end with an expansion section, and respectively includes a reciprocating compressor piston and displacer radially suspended in interconnecting cylindrical housings by active magnetic bearings and has adjacent reduced clearance regions so as to be in noncontacting relationship therewith and wherein one or more of these regions operate as clearance seals. The piston and displacer are reciprocated in their housings by linear drive motors to vary the volume of respectively adjacent compression and expansion spaces which contain a gaseous working fluid and a thermal regenerator to effect Stirling cycle cryogenic cooling.

  15. Stirling cycle cryogenic cooler

    NASA Technical Reports Server (NTRS)

    Gasser, M. G.; Sherman, A.; Studer, P. A.; Daniels, A.; Goldowsky, M. P. (Inventor)

    1983-01-01

    A long lifetime Stirling cycle cryogenic cooler particularly adapted for space applications is described. It consists of a compressor section centrally aligned end to end with an expansion section, and respectively includes a reciprocating compressor piston and displacer radially suspended in interconnecting cylindrical housings by active magnetic bearings and has adjacent reduced clearance regions so as to be in noncontacting relationship therewith and wherein one or more of these regions operate as clearance seals. The piston and displacer are reciprocated in their housings by linear drive motors to vary the volume of respectively adjacent compression and expansion spaces which contain a gaseous working fluid and a thermal regenerator to effect Stirling cycle cryogenic cooling.

  16. Cryogenic treatment of gas

    DOEpatents

    Bravo, Jose Luis; Harvey, III, Albert Destrehan; Vinegar, Harold J.

    2012-04-03

    Systems and methods of treating a gas stream are described. A method of treating a gas stream includes cryogenically separating a first gas stream to form a second gas stream and a third stream. The third stream is cryogenically contacted with a carbon dioxide stream to form a fourth and fifth stream. A majority of the second gas stream includes methane and/or molecular hydrogen. A majority of the third stream includes one or more carbon oxides, hydrocarbons having a carbon number of at least 2, one or more sulfur compounds, or mixtures thereof. A majority of the fourth stream includes one or more of the carbon oxides and hydrocarbons having a carbon number of at least 2. A majority of the fifth stream includes hydrocarbons having a carbon number of at least 3 and one or more of the sulfur compounds.

  17. Flexible cryogenic conduit

    SciTech Connect

    Brindza, P.D.; Wines, R.R.; Takacs, J.J.

    1999-12-21

    A flexible and relatively low cost cryogenic conduit is described. The flexible cryogenic conduit of the present invention comprises a first inner corrugated tube with single braided serving, a second outer corrugated tube with single braided serving concentric with the inner corrugated tube, and arranged outwardly about the periphery of the inner corrugated tube and between the inner and outer corrugated tubes: a superinsulation layer; a one half lap layer of polyester ribbon; a one half lap layer of copper ribbon; a spirally wound refrigeration tube; a second one half lap layer of copper ribbon; a second one half lap layer of polyester ribbon; a second superinsulation layer; a third one half lap layer of polyester ribbon; and a spirally wound stretchable and compressible filament.

  18. The Cryogenic Grating Spectrometer

    NASA Technical Reports Server (NTRS)

    Erickson, Edwin F.; Haas, Michael R.; Colgan, Sean W. J.; Simpson, Janet P.; Rubin, Robert H.

    1995-01-01

    The Cryogenic Grating Spectrometer (CGS) first flew on the KAO in 1982 December and has been open to guest investigators since 1984 October. In the past 12 years it has completed over 100 research flights supporting 13 different principal investigators studying a variety of objects. We briefly describe the instrument, its capabilities and accomplishments, and acknowledge the people who have contributed to its development and operation.

  19. Cryogenic Selective Surfaces

    NASA Technical Reports Server (NTRS)

    Youngquist, Robert; Nurge, Mark

    2015-01-01

    Under our NASA Innovative Advanced Concepts (NIAC) project we have theoretically demonstrated a novel selective surface that reflects roughly 100 times more solar radiation than any other known coating. If this prediction holds up under experimental tests it will allow cryogenic temperatures to be reached in deep space even in the presence of the sun. It may allow LOX to be carried to the Moon and Mars. It may allow superconductors to be used in deep space without a refrigeration system.

  20. Cryogenic turbopump bearing materials

    NASA Technical Reports Server (NTRS)

    Bhat, Biliyar N.

    1989-01-01

    Materials used for modern cryogenic turbopump bearings must withstand extreme conditions of loads and speeds under marginal lubrication. Naturally, these extreme conditions tend to limit the bearing life. It is possible to significantly improve the life of these bearings, however, by improving the fatigue and wear resistance of bearing alloys, and improving the strength, liquid oxygen compatibility and lubricating ability of the bearing cage materials. Improved cooling will also help to keep the bearing temperatures low and hence prolong the bearing life.

  1. A compact cryogenic pump

    NASA Astrophysics Data System (ADS)

    Li, Gang; Caldwell, Shane; Clark, Jason A.; Gulick, Sidney; Hecht, Adam; Lascar, Daniel D.; Levand, Tony; Morgan, Graeme; Orford, Rodney; Savard, Guy; Sharma, Kumar S.; Van Schelt, Jonathon

    2016-04-01

    A centrifugal cryogenic pump has been designed at Argonne National Laboratory to circulate liquid nitrogen (LN2) in a closed circuit allowing the recovery of excess fluid. The pump can circulate LN2 at rates of 2-10 L/min, into a head of 0.5-3 m. Over four years of laboratory use the pump has proven capable of operating continuously for 50-100 days without maintenance.

  2. Experiments on Cryogenic Complex Plasma

    SciTech Connect

    Ishihara, O.; Sekine, W.; Kubota, J.; Uotani, N.; Chikasue, M.; Shindo, M.

    2009-11-10

    Experiments on a cryogenic complex plasma have been performed. Preliminary experiments include production of a plasma in a liquid helium or in a cryogenic helium gas by a pulsed discharge. The extended production of a plasma has been realized in a vapor of liquid helium or in a cryogenic helium gas by rf discharge. The charge of dust particles injected in such a plasma has been studied in detail.

  3. Surface Tension Confines Cryogenic Liquid

    NASA Technical Reports Server (NTRS)

    Castles, Stephen H.; Schein, Michael E.

    1989-01-01

    New type of Dewar provides passive, constant-temperature cryogenic cooling for scientific instruments under normal-to low-gravity conditions. Known as Surface-Tension-Contained Liquid Cryogen Cooler (STCLCC), keeps liquid cryogen in known location inside the Dewar by trapping liquid inside spongelike material. Unique sponge material fills most of volume of inner tank. Sponge is all-silica, open-cell material similar to that used for Space Shuttle thermal-protection tiles.

  4. Cryogenic gas processing

    SciTech Connect

    Perez, E.P.

    1984-04-24

    Higher boiling constituents are separated from a normally gaseous feed mixture, predominating in lower boiling constituents and containing significant amounts of such higher boiling constituents, such as natural gas by fractionally distilling a feed mixture having a temperature substantially below atmospheric temperature at a pressure substantially above atmospheric pressure at which temperature and pressure the feed mixture comprises both vapor and liquid phases to produce a first vapor phase substantially enriched in lower boiling constituents and a first liquid phase substantially enriched in higher boiling constituents, expanding at least a part of the first vapor phase to reduce the pressure and temperature and produce an expanded fluid stream comprising a second vapor phase and a second liquid phase, separating the second vapor phase from the second liquid phase, recycling the second liquid phase to the fractional distillation step as a reflux, recovering the second vapor phase as a product and recovering the first liquid phase as a product. In another embodiment, at least a part of the feed mixture is expanded prior to fractional distillation. In other embodiments, the feed mixture is separated into a vapor phase and a liquid phase and at least a part of the vapor phase is expanded and/or the feed mixture is first cooled by indirect heat exchange with the second vapor phase prior to recovery of the latter as a product.

  5. Precision Cryogenic Dilatometer

    NASA Technical Reports Server (NTRS)

    Dudik, Matthew; Halverson, Peter; Levine-West, Marie; Marcin, Martin; Peters, Robert D.; Shaklan, Stuart

    2005-01-01

    A dilatometer based on a laser interferometer is being developed to measure mechanical creep and coefficients of thermal expansion (CTEs) of materials at temperatures ranging from ambient down to 15 K. This cryogenic dilatometer has been designed to minimize systematic errors that limit the best previously available dilatometers. At its prototype stage of development, this cryogenic dilatometer yields a strain measurement error of 35 ppb or 1.7 ppb/K CTE measurement error for a 20-K thermal load, for low-expansion materials in the temperature range from 310 down to 30 K. Planned further design refinements that include a provision for stabilization of the laser and addition of a high-precision sample-holding jig are expected to reduce the measurement error to 5-ppb strain error or 0.3-ppb/K CTE error for a 20-K thermal load. The dilatometer (see figure) includes a common-path, differential, heterodyne interferometer; a dual-frequency, stabilized source bench that serves as the light source for the interferometer; a cryogenic chamber in which one places the material sample to be studied; a cryogenic system for cooling the interior of the chamber to the measurement temperature; an ultra-stable alignment stage for positioning the chamber so that the sample is properly positioned with respect to the interferometer; and a data-acquisition and control system. The cryogenic chamber and the interferometer portion of the dilatometer are housed in a vacuum chamber on top of a vibration isolating optical table in a cleanroom. The sample consists of two pieces a pillar on a base both made of the same material. Using reflections of the interferometer beams from the base and the top of the pillar, what is measured is the change in length of the pillar as the temperature in the chamber is changed. In their fundamental optical and electronic principles of operation, the laser light source and the interferometer are similar to those described in Common-Path Heterodyne

  6. Dynamic simulation and nonlinear control of a rigorous batch reactive distillation.

    PubMed

    Kathel, Prateek; Jana, Amiya K

    2010-01-01

    This work deals with the dynamics and control of a high-purity batch distillation column with chemical reaction. A heterogeneous esterification reaction between the acetic acid and butanol takes place to produce butyl acetate. The process model is formulated considering variable liquid holdup, UNIQUAC model for thermodynamic property predictions, nonlinear Francis weir formula for tray hydraulics, pseudohomogeneous model to represent the reaction kinetics and rigorous energy balance. A structured and simple iterative approach is devised to compute the vapor flows with the fast convergence, under the rigorous energy balance. The representative column is treated with a distillate policy based on which, the lightest product, water is removed as distillate at the starting of production phase. As a consequence, the column gets progressively richer with the main product, butyl acetate. In addition, almost complete conversion of the limiting reactant is achieved. In order to maintain the product purity at the top, a nonlinear generic model controller (GMC) in two different forms has been proposed. Finally, a comparative closed-loop performance is addressed. It is shown that the control scheme, along with the effective distillate strategy, leads to almost complete conversion of ingredients and high-purity products. PMID:19815199

  7. Irresolvable complex mixture of hydrocarbons in soybean oil deodorizer distillate.

    PubMed

    Ju, Yi-Hsu; Huynh, Lien-Huong; Gunawan, Setiyo; Chern, Yaw-Terng; Kasim, Novy S

    2012-01-01

    Aliphatic hydrocarbons (HCs) can be used as a fingerprint of a given seed oil. Only by characterization of aliphatic HCs could contamination by mineral oil in that seed oil be confirmed. During the isolation of squalene from soybean oil deodorizer distillate, a significant amount of unknown HCs, ca. 44 wt%, was obtained. These seemingly-easy-to-identify HCs turned out to be much more difficult to elucidate due to the presence of an irresolvable complex mixture (ICM). The objective of this study was to purify and identify the unknown ICM of aliphatic HCs from soybean oil deodorizer distillate. Purification of the ICM was successfully achieved by using modified Soxhlet extraction, followed by modified preparative column chromatography, and finally by classical preparative column chromatography. FT-IR, TLC, elemental analysis, GC/FID, NMR and GC-MS analyses were then performed on the purified HCs. The GC chromatogram detected the presence of ICM peaks comprising two major peaks and a number of minor peaks. Validation methods such as IR and NMR justified that the unknowns are saturated HCs. This work succeeded in tentatively identifying the two major peaks in the ICM as cycloalkane derivatives. PMID:22162261

  8. Design guidelines for solid-catalyzed reactive distillation systems

    SciTech Connect

    Subawalla, H.; Fair, J.R.

    1999-10-01

    In this paper the authors discuss design guidelines for solid-catalyzed reactive distillation systems. The guidelines are used to generate initial estimates for column pressure, reactive zone location, catalyst mass, reactant feed location, reactant ratio, reflux ratio, column diameter, number of equilibrium stages, and packed height. They form a part of a methodical design procedure that makes extensive use of both nonequilibrium (rate-based) and equilibrium-stage simulation models. Important choices prior to design include selection of reliable thermodynamic and reaction kinetic models. The authors tested the guidelines for two etherification systems and validated them experimentally for a hydration reaction. The results from a case study, the manufacture of tert-amyl methyl ether, are shown here. Superimposing reaction on separation leads to unique design trade-offs. Thus, column diameter depends both on maximum vapor velocity and on packing catalyst density, reactant ratios are a function of conversion and azeotrope formation, the operating pressure affects the relative volatility, chemical equilibrium, and reaction rate (reactive zone temperature), and the reflux ratio impacts both separation and conversion. The guidelines and procedures presented here simplify the detailed reactive column design considerably.

  9. Vapor Compression Distillation Flight Experiment

    NASA Technical Reports Server (NTRS)

    Hutchens, Cindy F.

    2002-01-01

    One of the major requirements associated with operating the International Space Station is the transportation -- space shuttle and Russian Progress spacecraft launches - necessary to re-supply station crews with food and water. The Vapor Compression Distillation (VCD) Flight Experiment, managed by NASA's Marshall Space Flight Center in Huntsville, Ala., is a full-scale demonstration of technology being developed to recycle crewmember urine and wastewater aboard the International Space Station and thereby reduce the amount of water that must be re-supplied. Based on results of the VCD Flight Experiment, an operational urine processor will be installed in Node 3 of the space station in 2005.

  10. Small codes for magic state distillation

    NASA Astrophysics Data System (ADS)

    Howard, Mark; Dawkins, Hillary

    2016-03-01

    Magic state distillation is a critical component in leading proposals for fault-tolerant quantum computation. Relatively little is known, however, about how to construct a magic state distillation routine or, more specifically, which stabilizer codes are suitable for the task. While transversality of a non-Clifford gate within a code often leads to efficient distillation routines, it appears to not be a necessary condition. Here we have examined a number of small stabilizer codes and highlight a handful of which displaying interesting, albeit inefficient, distillation behaviour. Many of these distill noisy states right up to the boundary of the known undististillable region, while some distill toward non-stabilizer states that have not previously been considered.

  11. A new procedure for the determination of distillation temperature distribution of high-boiling petroleum products and fractions.

    PubMed

    Boczkaj, Grzegorz; Przyjazny, Andrzej; Kamiński, Marian

    2011-03-01

    The distribution of distillation temperatures of liquid and semi-fluid products, including petroleum fractions and products, is an important process and practical parameter. It provides information on properties of crude oil and content of particular fractions, classified on the basis of their boiling points, as well as the optimum conditions of atmospheric or vacuum distillation. At present, the distribution of distillation temperatures is often investigated by simulated distillation (SIMDIS) using capillary gas chromatography (CGC) with a short capillary column with polydimethylsiloxane as the stationary phase. This paper presents the results of investigations on the possibility of replacing currently used CGC columns for SIMDIS with a deactivated fused silica capillary tube without any stationary phase. The SIMDIS technique making use of such an empty fused silica column allows a considerable lowering of elution temperature of the analytes, which results in a decrease of the final oven temperature while ensuring a complete separation of the mixture. This eliminates the possibility of decomposition of less thermally stable mixture components and bleeding of the stationary phase which would result in an increase of the detector signal. It also improves the stability of the baseline, which is especially important in the determination of the end point of elution, which is the basis for finding the final temperature of distillation. This is the key parameter for the safety process of hydrocracking, where an excessively high final temperature of distillation of a batch can result in serious damage to an expensive catalyst bed. This paper compares the distribution of distillation temperatures of the fraction from vacuum distillation of petroleum obtained using SIMDIS with that obtained by the proposed procedure. A good agreement between the two procedures was observed. In addition, typical values of elution temperatures of n-paraffin standards obtained by the two

  12. Cryogenic Flow Sensor

    NASA Technical Reports Server (NTRS)

    Justak, John

    2010-01-01

    An acousto-optic cryogenic flow sensor (CFS) determines mass flow of cryogens for spacecraft propellant management. The CFS operates unobtrusively in a high-pressure, high-flowrate cryogenic environment to provide measurements for fluid quality as well as mass flow rate. Experimental hardware uses an optical plane-of-light (POL) to detect the onset of two-phase flow, and the presence of particles in the flow of water. Acousto-optic devices are used in laser equipment for electronic control of the intensity and position of the laser beam. Acousto-optic interaction occurs in all optical media when an acoustic wave and a laser beam are present. When an acoustic wave is launched into the optical medium, it generates a refractive index wave that behaves like a sinusoidal grating. An incident laser beam passing through this grating will diffract the laser beam into several orders. Its angular position is linearly proportional to the acoustic frequency, so that the higher the frequency, the larger the diffracted angle. If the acoustic wave is traveling in a moving fluid, the fluid velocity will affect the frequency of the traveling wave, relative to a stationary sensor. This frequency shift changes the angle of diffraction, hence, fluid velocity can be determined from the diffraction angle. The CFS acoustic Bragg grating data test indicates that it is capable of accurately determining flow from 0 to 10 meters per second. The same sensor can be used in flow velocities exceeding 100 m/s. The POL module has successfully determined the onset of two-phase flow, and can distinguish vapor bubbles from debris.

  13. Distillation of liquid fuels by thermogravimetry

    SciTech Connect

    Huang, He; Wang, Keyu; Wang, Shaojie; Klein, M.T.; Calkins, W.H.

    1996-12-31

    In this paper, design and operation of a custom-built thermogravimetric apparatus for the distillation of liquid fuels are reported. Using a sensitive balance with scale of 0.001 g and ASTM distillation glassware, several petroleum and petroleum-derived samples have been analyzed by the thermogravimetric distillation method. When the ASTM distillation glassware is replaced by a micro-scale unit, sample size could be reduced from 100 g to 5-10 g. A computer program has been developed to transfer the data into a distillation plot, e.g. Weight Percent Distilled vs. Boiling Point. It also generates a report on the characteristic distillation parameters, such as, IBP (Initial Boiling Point), FBP (Final Boiling Point), and boiling point at 50 wt% distilled. Comparison of the boiling point distributions determined by TG (thermogravimetry) with those by SimDis GC (Simulated-Distillation Gas Chromatography) on two liquid fuel samples (i.e. a decanted oil and a filtered crude oil) are also discussed in this paper.

  14. Nuclear Cryogenic Propulsion Stage

    NASA Technical Reports Server (NTRS)

    Houts, Michael G.; Borowski, S. K.; George, J. A.; Kim, T.; Emrich, W. J.; Hickman, R. R.; Broadway, J. W.; Gerrish, H. P.; Adams, R. B.

    2012-01-01

    The fundamental capability of Nuclear Thermal Propulsion (NTP) is game changing for space exploration. A first generation Nuclear Cryogenic Propulsion Stage (NCPS) based on NTP could provide high thrust at a specific impulse above 900 s, roughly double that of state of the art chemical engines. Characteristics of fission and NTP indicate that useful first generation systems will provide a foundation for future systems with extremely high performance. The role of the NCPS in the development of advanced nuclear propulsion systems could be analogous to the role of the DC-3 in the development of advanced aviation. Progress made under the NCPS project could help enable both advanced NTP and advanced NEP.

  15. Cryogenic insulation development

    NASA Technical Reports Server (NTRS)

    Leonhard, K. E.

    1972-01-01

    Multilayer insulations for long term cryogenic storage are described. The development effort resulted in an insulation concept using lightweight radiation shields, separated by low conductive Dacron fiber tufts. The insulation is usually referred to as Superfloc. The fiber tufts are arranged in a triangular pattern and stand about .040 in. above the radiation shield base. Thermal and structural evaluation of Superfloc indicated that this material is a strong candidate for the development of high performance thermal protection systems because of its high strength, purge gas evacuation capability during boost, its density control and easy application to a tank.

  16. Cryogenic support member

    DOEpatents

    Niemann, Ralph C.; Gonczy, John D.; Nicol, Thomas H.

    1987-01-01

    A cryogenic support member is comprised of a non-metallic rod having a depression in at least one end and a metallic end connection assembled to the rod. The metallic end connection comprises a metallic plug which conforms to the shape and is disposed in the depression and a metallic sleeve is disposed over the rod and plug. The plug and the sleeve are shrink-fitted to the depression in the rod to form a connection good in compression, tension and bending.

  17. Refrigerated cryogenic envelope

    DOEpatents

    Loudon, John D.

    1976-11-16

    An elongated cryogenic envelope including an outer tube and an inner tube coaxially spaced within said inner tube so that the space therebetween forms a vacuum chamber for holding a vacuum. The inner and outer tubes are provided with means for expanding or contracting during thermal changes. A shield is located in the vacuum chamber intermediate the inner and outer tubes; and, a refrigeration tube for directing refrigeration to the shield is coiled about at least a portion of the inner tube within the vacuum chamber to permit the refrigeration tube to expand or contract along its length during thermal changes within said vacuum chamber.

  18. Cryogenic Propellant Scavenging

    NASA Technical Reports Server (NTRS)

    Louie, B.; Kemp, N. J.; Daney, D. E.

    1985-01-01

    A detailed description of a computer model that has been developed for assessing the feasibility of low g cryogen propellant scavenging from the space shuttle External Tank (ET) is given. Either pump-assisted or pressure-induced propellant transfer may be selected. The program will accept a wide range of input variables, including the fuel to be transferred (LOX or LH2), heat leaks, tank temperatures, and piping and equipment specifications. The model has been parametrically analyzed to determine initial design specification for the system.

  19. FRIB cryogenic distribution system

    NASA Astrophysics Data System (ADS)

    Ganni, V.; Dixon, K.; Laverdure, N.; Knudsen, P.; Arenius, D.; Barrios, M.; Jones, S.; Johnson, M.; Casagrande, F.

    2014-01-01

    The Michigan State University Facility for Rare Isotope Beams (MSU-FRIB) helium distribution system has been revised to include bayonet/warm valve type disconnects between each cryomodule and the transfer line distribution system, similar to the Thomas Jefferson National Accelerator Facility (JLab) and the Spallation Neutron Source (SNS) cryogenic distribution systems. The heat loads at various temperature levels and some of the features in the design of the distribution system are outlined. The present status, the plans for fabrication, and the procurement approach for the helium distribution system are also included.

  20. Optical Detection Of Cryogenic Leaks

    NASA Technical Reports Server (NTRS)

    Wyett, Lynn M.

    1988-01-01

    Conceptual system identifies leakage without requiring shutdown for testing. Proposed device detects and indicates leaks of cryogenic liquids automatically. Detector makes it unnecessary to shut equipment down so it can be checked for leakage by soap-bubble or helium-detection methods. Not necessary to mix special gases or other materials with cryogenic liquid flowing through equipment.

  1. Kodak AMSD Cryogenic Test Plans

    NASA Technical Reports Server (NTRS)

    Matthews, Gary; Hammon, John; Barrett, David; Russell, Kevin (Technical Monitor)

    2002-01-01

    NGST will be an IR based optical system that will operate at cryogenic temperatures. As part of the AMSD program, Kodak must demonstrate the ability of our system to perform at these very cold temperatures. Kodak will discuss the test approach that will be used for cryogenic testing at MSFC's XRCF.

  2. Column Liquid Chromatography.

    ERIC Educational Resources Information Center

    Majors, Ronald E.; And Others

    1984-01-01

    Reviews literature covering developments of column liquid chromatography during 1982-83. Areas considered include: books and reviews; general theory; columns; instrumentation; detectors; automation and data handling; multidimensional chromatographic and column switching techniques; liquid-solid chromatography; normal bonded-phase, reversed-phase,…

  3. Cryogenic Piezoelectric Actuator

    NASA Technical Reports Server (NTRS)

    Jiang, Xiaoning; Cook, William B.; Hackenberger, Wesley S.

    2009-01-01

    In this paper, PMN-PT single crystal piezoelectric stack actuators and flextensional actuators were designed, prototyped and characterized for space optics applications. Single crystal stack actuators with footprint of 10 mm x10 mm and the height of 50 mm were assembled using 10 mm x10mm x0.15mm PMN-PT plates. These actuators showed stroke > 65 - 85 microns at 150 V at room temperature, and > 30 microns stroke at 77 K. Flextensional actuators with dimension of 10mm x 5 mm x 7.6 mm showed stroke of >50 microns at room temperature at driving voltage of 150 V. A flextensional stack actuator with dimension of 10 mm x 5 mm x 47 mm showed stroke of approx. 285 microns at 150 V at room temperature and > 100 microns at 77K under driving of 150 V should be expected. The large cryogenic stroke and high precision of these actuators are promising for cryogenic optics applications.

  4. Cryogenics maintenance strategy

    NASA Astrophysics Data System (ADS)

    Cruzat, Fabiola

    2012-09-01

    ALMA is an interferometer composed of 66 independent systems, with specific maintenance requirements for each subsystem. To optimize the observation time and reduce downtime maintenance, requirements are very demanding. One subsystem with high maintenance efforts is cryogenics and vacuum. To organize the maintenance, the Cryogenic and Vacuum department is using and implementing different tools. These are monitoring and problem reporting systems and CMMS. This leads to different maintenance approaches: Preventive Maintenance, Corrective Maintenance and Condition Based Maintenance. In order to coordinate activities with other departments the preventive maintenance schedule is kept as flexible as systems allow. To cope with unavoidable failures, the team has to be prepared to work under any condition with the spares on time. Computerized maintenance management system (CMMS) will help to manage inventory control for reliable spare part handling, the correct record of work orders and traceability of maintenance activities. For an optimized approach the department is currently evaluating where preventive or condition based maintenance applies to comply with the individual system demand. Considering the change from maintenance contracts to in-house maintenance will help to minimize costs and increase availability of parts. Due to increased number of system and tasks the cryo team needs to grow. Training of all staff members is mandatory, in depth knowledge must be built up by doing complex maintenance activities in the Cryo group, use of advanced computerized metrology systems.

  5. Cryogenic fluid management experiment

    NASA Technical Reports Server (NTRS)

    Eberhardt, R. N.; Bailey, W. J.; Fester, D. A.

    1981-01-01

    The cryogenic fluid management experiment (CFME), designed to characterize subcritical liquid hydrogen storage and expulsion in the low-q space environment, is discussed. The experiment utilizes a fine mesh screen fluid management device to accomplish gas-free liquid expulsion and a thermodynamic vent system to intercept heat leak and control tank pressure. The experiment design evolved from a single flight prototype to provision for a multimission (up to 7) capability. A detailed design of the CFME, a dynamic test article, and dedicated ground support equipment were generated. All materials and parts were identified, and components were selected and specifications prepared. Long lead titanium pressurant spheres and the flight tape recorder and ground reproduce unit were procured. Experiment integration with the shuttle orbiter, Spacelab, and KSC ground operations was coordinated with the appropriate NASA centers, and experiment interfaces were defined. Phase 1 ground and flight safety reviews were conducted. Costs were estimated for fabrication and assembly of the CFME, which will become the storage and supply tank for a cryogenic fluid management facility to investigate fluid management in space.

  6. Cryogenic skirt support post

    NASA Astrophysics Data System (ADS)

    Niemann, R. C.; Buckles, W. E.

    The cold masses of cryostats having vertical axes, like vertical pressure vessels, can be effectively supported by means of a cylindrical skirt that wraps concentrically around the cold mass. The skirt is a cryogenic support post connected at its upper end to the cold mass and at its lower end to the cryostat vacuum vessel. A heat intercept connection to an intermediate temperature refrigeration source can be employed to control heat leak. The support post consists of a composite; e.g. epoxy fibreglass, or cylinder with bolted or thermal interference fit end connections. The support post, being a single element support, simplifies cryostat assembly and alignment. The composite cylinder, with a relatively large diameter, lends itself to structural soundness and stability under both static and dynamic loading conditions. Its relatively long length and intermediate temperature heat intercept allows low heat leak to the cold mass. The details of the design of a cryogenic skirt support post as applied to a superconducting magnetic energy storage cryostat are presented. Included are support post fabrication, cryostat assembly, and predicted structural and thermal performance. Fabrication of and operational experiences with a prototype support post assembly are discussed.

  7. 27 CFR 1.90 - Distilled spirits in bulk.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Distilled spirits in bulk..., NONINDUSTRIAL USE OF DISTILLED SPIRITS AND WINE, BULK SALES AND BOTTLING OF DISTILLED SPIRITS Bulk Sales and Bottling of Distilled Spirits Warehouse Receipts § 1.90 Distilled spirits in bulk. By the terms of the...

  8. 27 CFR 1.91 - Bottled distilled spirits.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Bottled distilled spirits..., NONINDUSTRIAL USE OF DISTILLED SPIRITS AND WINE, BULK SALES AND BOTTLING OF DISTILLED SPIRITS Bulk Sales and Bottling of Distilled Spirits Warehouse Receipts § 1.91 Bottled distilled spirits. The provisions of...

  9. Quality evaluation of agricultural distillates using different types of electronic noses

    NASA Astrophysics Data System (ADS)

    Dymerski, Tomasz; Gebicki, Jacek; Namieśnik, Jacek

    2014-08-01

    The paper presents the results of investigation on quality evaluation of agricultural distillates using a prototype of electronic nose instrument and a commercial electronic nose of Fast/Flash GC type- HERACLES II. The prototype was equipped with TGS type semiconductor sensors. HERACLES II included two chromatographic columns with different polarity of stationary phase and two FID detectors. In case of the prototype volatile fraction of the agricultural distillate was prepared via barbotage process, whereas HERACLES II analysed the headspace fraction. Classification of the samples into three quality classes was performed using: quadratic discriminant function (QDA), supported with cross-validation method. Over 95% correct classification of the agricultural distillates into particular quality classes was observed for the analyses with HERACLES II. The prototype of electronic nose provided correct classification at the level of 70%.

  10. Neuro-estimator based GMC control of a batch reactive distillation.

    PubMed

    Prakash, K J Jithin; Patle, Dipesh S; Jana, Amiya K

    2011-07-01

    In this paper, an artificial neural network (ANN)-based nonlinear control algorithm is proposed for a simulated batch reactive distillation (RD) column. In the homogeneously catalyzed reactive process, an esterification reaction takes place for the production of ethyl acetate. The fundamental model has been derived incorporating the reaction term in the model structure of the nonreactive distillation process. The process operation is simulated at the startup phase under total reflux conditions. The open-loop process dynamics is also addressed running the batch process at the production phase under partial reflux conditions. In this study, a neuro-estimator based generic model controller (GMC), which consists of an ANN-based state predictor and the GMC law, has been synthesized. Finally, this proposed control law has been tested on the representative batch reactive distillation comparing with a gain-scheduled proportional integral (GSPI) controller and with its ideal performance (ideal GMC). PMID:21334616

  11. Distillation of Bell states in open systems

    SciTech Connect

    Isasi, E.; Mundarain, D.

    2010-04-15

    In this work we show that the distillation protocol proposed by P. Chen et al. [Phys. Rev. A 54, 3824 (1996)] allows one to distill Bell states at any time for a system evolving in vacuum and prepared in an initial singlet. It is also shown that the same protocol, applied in nonzero temperature thermal baths, yields a considerable recovering of entanglement.

  12. Potential bleaching techniques for corn distillers grains

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The ethanol industry is booming, and extensive research is now being pursued to develop alternative uses for distillers dried grains (DDG) and distillers dried grains with solubles (DDGS), coproducts of the ethanol production process. Currently, DDG and DDGS are used exclusively as livestock feed. P...

  13. 27 CFR 24.216 - Distilling material.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2012-04-01 2012-04-01 false Distilling material. 24.216 Section 24.216 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS WINE Production of Other Than Standard Wine § 24.216 Distilling material. Wine may be produced on bonded...

  14. 27 CFR 24.216 - Distilling material.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Distilling material. 24.216 Section 24.216 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS WINE Production of Other Than Standard Wine § 24.216 Distilling material. Wine may be produced on bonded...

  15. Recycling of Waste Acetone by Fractional Distillation

    ERIC Educational Resources Information Center

    Weires, Nicholas A.; Johnston, Aubrey; Warner, Don L.; McCormick, Michael M.; Hammond, Karen; McDougal, Owen M.

    2011-01-01

    Distillation is a ubiquitous technique in the undergraduate organic chemistry curriculum; the technique dates back to ca. 3500 B.C.E. With the emergence of green chemistry in the 1990s, the importance of emphasizing responsible waste management practices for future scientists is paramount. Combining the practice of distillation with the message…

  16. Locally accessible information and distillation of entanglement

    SciTech Connect

    Ghosh, Sibasish; Joag, Pramod; Kar, Guruprasad; Kunkri, Samir; Roy, Anirban

    2005-01-01

    A different type of complementarity relation is found between locally accessible information and final average entanglement for a given ensemble. It is also shown that in some well-known distillation protocols, this complementary relation is optimally satisfied. We discuss the interesting trade-off between locally accessible information and distillable entanglement for some states.

  17. Ultrastable Cryogenic Microwave Oscillators

    NASA Astrophysics Data System (ADS)

    Mann, Anthony G.

    Ultrastable cryogenic microwave oscillators are secondary frequency standards in the microwave domain. The best of these oscillators have demonstrated a short term frequency stability in the range 10-14 to a few times 10-16. The main application for these oscillators is as flywheel oscillators for the next generation of passive atomic frequency standards, and as local oscillators in space telemetry ground stations to clean up the transmitter close in phase noise. Fractional frequency stabilities of passive atomic frequency standards are now approaching 3 x10^-14 /τ where τ is the measurement time, limited only by the number of atoms that are being interrogated. This requires an interrogation oscillator whose short-term stability is of the order of 10-14 or better, which cannot be provided by present-day quartz technology. Ultrastable cryogenic microwave oscillators are based on resonators which have very high electrical Q-factors. The resolution of the resonator's linewidth is typically limited by electronics noise to about 1ppm and hence Q-factors in excess of 108 are required. As these are only attained in superconducting cavities or sapphire resonators at low temperatures, use of liquid helium cooling is mandatory, which has so far restricted these oscillators to the research or metrology laboratory. Recently, there has been an effort to dispense with the need for liquid helium and make compact flywheel oscillators for the new generation of primary frequency standards. Work is under way to achieve this goal in space-borne and mobile liquid-nitrogen-cooled systems. The best cryogenic oscillators developed to date are the ``whispering gallery'' (WG) mode sapphire resonator-oscillators of NASA's Jet Propulsion Laboratory (JPL) and the University of Western Australia (UWA), as well as Stanford University's superconducting cavity stabilized oscillator (SCSO). All of these oscillators have demonstrated frequency

  18. Cryogenic Fluid Transfer for Exploration

    NASA Technical Reports Server (NTRS)

    Chato, David J.

    2008-01-01

    This paper discusses current plans and issues for exploration that involve the use of cryogenic transfer. The benefits of cryogenic transfer to exploration missions are examined. The current state of the art of transfer technology is reviewed. Mission concepts of operation for exploration are presented, and used to qualitatively discuss the performance benefits of transfer. The paper looks at the challenges faced to implement a cryogenic transfer system and suggest approaches to address them with advanced development research. Transfer rates required for exploration are shown to have already been achieved in ground test. Cost-effective approaches to the required on-orbit demonstration are suggested.

  19. Cryogenic Fluid Transfer for Exploration

    NASA Technical Reports Server (NTRS)

    Chato, David J.

    2007-01-01

    This paper discusses current plans and issues for exploration that involve the use of cryogenic transfer. The benefits of cryogenic transfer to exploration missions are examined. The current state of the art of transfer technology is reviewed. Mission concepts of operation for exploration are presented, and used to qualitatively discuss the performance benefits of transfer. The paper looks at the challenges faced to implement a cryogenic transfer system and suggest approaches to address them with advanced development research. Transfer rates required for exploration are shown to have already been achieved in ground test. Cost effective approaches to the required on-orbit demonstration are suggested.

  20. 27 CFR 24.183 - Use of distillates containing aldehydes.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... the fermentation of wine and then returned to the distilled spirits plant from which distillates were... fermentation of wine made from a different kind of fruit. Distillates containing aldehydes which are...

  1. 27 CFR 24.183 - Use of distillates containing aldehydes.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... the fermentation of wine and then returned to the distilled spirits plant from which distillates were... fermentation of wine made from a different kind of fruit. Distillates containing aldehydes which are...

  2. 27 CFR 24.183 - Use of distillates containing aldehydes.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... the fermentation of wine and then returned to the distilled spirits plant from which distillates were... fermentation of wine made from a different kind of fruit. Distillates containing aldehydes which are...

  3. 27 CFR 24.183 - Use of distillates containing aldehydes.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... the fermentation of wine and then returned to the distilled spirits plant from which distillates were... fermentation of wine made from a different kind of fruit. Distillates containing aldehydes which are...

  4. 27 CFR 24.183 - Use of distillates containing aldehydes.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... the fermentation of wine and then returned to the distilled spirits plant from which distillates were... fermentation of wine made from a different kind of fruit. Distillates containing aldehydes which are...

  5. Comparison of advanced distillation control methods. Second annual report

    SciTech Connect

    Riggs, J.B.

    1996-11-01

    Detailed dynamic simulations of two industrial distillation columns (a propylene/propane splitter and a xylene/toluene column) have been used to study the issue of configuration selection for diagonal PI dual composition controls. Auto Tune Variation (ATV) identification with on-line detuning was used for tuning the diagonal proportional integral (PI) composition controls. Each configuration was evaluated with respect to steady-state relative gain array (RGA) values, sensitivity to feed composition changes, and open loop dynamic performance. Each configuration was tuned using setpoint changes over a wider range of operation for robustness and tested for feed composition upsets. Overall, configuration selection was shown to have a dominant effect upon control performance. Configuration analysis tools (e.g., RGA, condition number, disturbance sensitivity) were found to reject configuration choices that are obviously poor choices, but were unable to critically differentiate between the remaining viable choices. Configuration selection guidelines are given although it is demonstrated that the most reliable configuration selection approach is based upon testing the viable configurations using dynamic column simulators.

  6. Cryogenic expansion machine

    DOEpatents

    Pallaver, Carl B.; Morgan, Michael W.

    1978-01-01

    A cryogenic expansion engine includes intake and exhaust poppet valves each controlled by a cam having adjustable dwell, the valve seats for the valves being threaded inserts in the valve block. Each cam includes a cam base and a ring-shaped cam insert disposed at an exterior corner of the cam base, the cam base and cam insert being generally circular but including an enlarged cam dwell, the circumferential configuration of the cam base and cam dwell being identical, the cam insert being rotatable with respect to the cam base. GI CONTRACTUAL ORIGIN OF THE INVENTION The invention described herein was made in the course of, or under, a contract with the UNITED STATES ENERGY RESEARCH AND DEVELOPMENT ADMINISTRATION.

  7. Basic cryogenics and materials

    NASA Technical Reports Server (NTRS)

    Wigley, D. A.

    1985-01-01

    The effects of cryogenic temperatures on the mechanical and physical properties of materials are summarized. Heat capacity and thermal conductivity are considered in the context of conservation of liquid nitrogen, thermal stability of the gas stream, and the response time for changes in operating temperature. Particular attention is given to the effects of differential expansion and failure due to thermal fatigue. Factors affecting safety are discussed, including hazards created due to the inadvertent production of liquid oxygen and the physiological effects of exposure to liquid and gaseous nitrogen, such as cold burns and asphyxiation. The preference for using f.c.c. metals at low temperatures is explained in terms of their superior toughness. The limitations on the use of ferritic steels is also considered. Nonmetallic materials are discussed, mainly in the context of their LOX compatibility and their use in the form of foams and fibers as insulatants, seals, and fiber reinforced composites.

  8. LUX Cryogenics and Circulation

    NASA Astrophysics Data System (ADS)

    Bradley, Adam

    2012-10-01

    LUX is a new dark matter direct detection experiment being carried out at the Sanford Underground Research Facility, at the renewed Homestake mine in Lead, SD. The detector's large size supports effective internal shielding from natural radioactivity of the surrounding materials and environment. The LUX detector consists of a cylindrical vessel containing 350 kg of liquid xenon (LXe) cooled down and maintained at 175-K operating temperature using a novel cryogenic system. We report the efficiency of our thermosyphon-based cooling system, as well as the efficiency of a unique internal heat exchanger with standard gas phase purification using a heated getter, which allows for very high flow purification without requiring large cooling power. Such systems are required for multi-ton scale up.

  9. Cryogenic cooler apparatus

    DOEpatents

    Wheatley, John C.; Paulson, Douglas N.; Allen, Paul C.

    1983-01-01

    A Malone-type final stage for utilization in a Stirling cycle cryogenic cooler apparatus includes a displacer slidable within a vessel. .sup.4 He, .sup.3 He, or a mixture thereof is made to flow in a pulsating unidirectional manner through a regenerator in the displacer by utilization of check valves in separate fluid channels. Stacked copper screen members extend through the channels and through a second static thermodynamic medium within the displacer to provide efficient lateral heat exchange and enable cooling to temperatures in the range of 3-4 K. Another embodiment utilizes sintered copper particles in the regenerator. Also described is a final stage that has a non-thermally conducting displacer having passages with check valves for directing fluid past a regenerator formed in the surrounding vessel.

  10. Cryogenic Propulsion Stage

    NASA Technical Reports Server (NTRS)

    Jones, David

    2011-01-01

    The CPS is an in-space cryogenic propulsive stage based largely on state of the practice design for launch vehicle upper stages. However, unlike conventional propulsive stages, it also contains power generation and thermal control systems to limit the loss of liquid hydrogen and oxygen due to boil-off during extended in-space storage. The CPS provides the necessary (Delta)V for rapid transfer of in-space elements to their destinations or staging points (i.e., E-M L1). The CPS is designed around a block upgrade strategy to provide maximum mission/architecture flexibility. Block 1 CPS: Short duration flight times (hours), passive cryo fluid management. Block 2 CPS: Long duration flight times (days/weeks/months), active and passive cryo fluid management.