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Sample records for dated sediment core

  1. Dating sediment cores from Hudson River marshes

    SciTech Connect

    Robideau, R.; Bopp, R.F. . Dept. of Earth and Environmental Sciences)

    1993-03-01

    There are several methods for determining sediment accumulation rates in the Hudson River estuary. One involves the analysis of the concentration of certain radionuclides in sediment core sections. Radionuclides occur in the Hudson River as a result of: natural sources, fallout from nuclear weapons testing and low level aqueous releases from the Indian Point Nuclear Power Facility. The following radionuclides have been studied in the authors work: Cesium-137, which is derived from global fallout that started in the 1950's and has peaked in 1963. Beryllium-7, a natural radionuclide with a 53 day half-life and found associated with very recently deposited sediments. Another useful natural radionuclide is Lead-210 derived from the decay of Radon-222 in the atmosphere. Lead-210 has a half-life of 22 years and can be used to date sediments up to about 100 years old. In the Hudson River, Cobalt-60 is a marker for Indian Point Nuclear Reactor discharges. The author's research involved taking sediment core samples from four sites in the Hudson River Estuarine Research Reserve areas. These core samples were sectioned, dried, ground and analyzed for the presence of radionuclides by the method of gamma-ray spectroscopy. The strength of each current pulse is proportional to the energy level of the gamma ray absorbed. Since different radionuclides produce gamma rays of different energies, several radionuclides can be analyzed simultaneously in each of the samples. The data obtained from this research will be compared to earlier work to obtain a complete chronology of sediment deposition in these Reserve areas of the river. Core samples may then by analyzed for the presence of PCB's, heavy metals and other pollutants such as pesticides to construct a pollution history of the river.

  2. /sup 137/Cs radioactive dating of Lake Ontario sediment cores

    SciTech Connect

    Ward, T.E.; Breeden, J.; Komisarcik, K.; Porter, R.; Czuczwa, J.; Kaminski, R.; McVeety, B.D.

    1987-12-01

    The distribution of /sup 137/Cs in sediment cores from Lake Ontario provides estimates of the sediment accumulation rates. Geochronology with /sup 210/Pb dating and distribution of Ambrosia (ragweed) pollen compare well with /sup 137/Cs dating. These methods can determine with precision, changes in sedimentation occurring over the past 100 years or so. Typical sedimentation rates of 0.18-0.36 cm/yr were measured. 16 refs., 3 figs., 2 tabs.

  3. Estimation of a Historic Mercury Load Function for Lake Michigan using Dated Sediment Cores

    EPA Science Inventory

    Box cores collected between 1994 and 1996 were used to estimate historic mercury loads to Lake Michigan. Based on a kriging spatial interpolation of 54 Pb-210 dated cores, 228 metric tons of mercury are stored in the lake’s sediments (excluding Green Bay). To estimate the time ...

  4. A method for estimation of historic contaminant loads using dated sediment cores

    EPA Science Inventory

    Dated sediment cores were used to assess the history of contaminant loads. The contaminant selected must be one that is not significantly remobilized by post depositional processes such as diagenesis. In addition, the core must be from an area with a high deposition rate and litt...

  5. Anthropogenic Eutrophication of Narragansett Bay: Evidence from Dated Sediment Cores

    EPA Science Inventory

    The organic matter preserved in estuarine sediments provides a number of useful indicators, or "proxies" that can be used to infer paleoenvironmental changes One type of paleoenvironmental change is anthropogenic eutrophication. The human activity largely responsible for increasi...

  6. Beryllium Isotope Dating of Sediment Cores From the Alpha Ridge, Arctic Ocean

    NASA Astrophysics Data System (ADS)

    Sellen, E.; Jakobsson, M.; Kubik, P. W.; Frank, M.

    2007-12-01

    Poor preservation of biogenic calcium carbonate and biosilica in Arctic Ocean sediments has led to large problems regarding the establishment of a reliable chronostratigraphy. There are currently two differing sedimentation rate scenarios proposed for the Arctic Ocean. The first suggests sedimentation rates on the order of mm/ka and is based on cores from the Amerasian Basin, whereas the second suggests sedimentation rates on the order of cm/ka mainly derived from Eurasian Basin cores. Here we present dating results from cores HLY0503-09JPC and HLY0503-14JPC retrieved from the Alpha Ridge during the Healy-Oden Trans-Arctic Expedition 2005 (HOTRAX). These cores have been analyzed for seawater-derived beryllium (Be) isotopes in order to establish a chronostratigraphy. The isotopes 10Be and 9Be were extracted simultaneously from sample aliquots by using a leaching procedure. The decrease of 10Be concentration (half-life = 1.51 Million years) with depth in core provides first order sedimentation rates for the sampled cores. To eliminate the dilution effect of beryllium caused by short-term changes in sedimentation rate and grain size variability, the 10Be concentration was normalized to the stable isotope 9Be. The preliminary results show low downcore 10Be concentrations in both cores from the Alpha Ridge. Plotting 10Be against depth suggests an average sedimentation rate of ~2.9 mm/ka for core HLY0503-09JPC and ~2.3 mm/ka for HLY0503- 14JPC. The calculated 10Be/9Be ratios point to even lower average sedimentation rates of ~1.9 mm/ka for core HLY0503-09JPC and ~1.6 mm/ka for HLY0503-14JPC. However, core HLY0503-14JPC shows a pronounced variability of the 10Be concentration as well as for the 10Be/9Be ratio, which results in a large uncertainty of the calculated sedimentation rates. The 10Be concentrations for this core will be compared with the grain size record in order to reduce the scatter of the data. The preliminary beryllium isotope chronostratigraphy supports

  7. Depositional history of polychlorinated biphenyls in a dated sediment core from the northwestern Arabian Gulf.

    PubMed

    Gevao, Bondi; Aba, Abdul Aziz; Al-Ghadban, Abdul Nabi; Uddin, Saif

    2012-05-01

    The vertical distribution of polychlorinated biphenyls (PCBs) was measured in a dated sediment core from the northwestern Arabian Gulf to reconstruct their depositional history. The downcore profile showed an increase in concentrations from depth to a subsurface maximum of approximately 1,500 pg g(-1) in approximately 1991, followed by an exponential decrease to the sediment-water interface. Current concentrations of ΣPCBs are similar to levels predating the episodic input of PCBs in sediments dated coincident with the 1991 Arabian Gulf war. The spike in ΣPCB concentrations during the war may be related to the destruction of PCB-laden transformers during the conflict. The 15-fold decrease in ΣPCB concentrations from the period of maximum flux to prewar levels suggests that the factors delivering PCBs to sediments at present are similar to those that that existed before the war-related inputs. PMID:22218707

  8. Historical PCDD inputs and their source implications from dated sediment cores in Queensland (Australia).

    PubMed

    Gaus, C; Brunskill, G J; Weber, R; Papke, O; Muller, J F

    2001-12-01

    Recent investigations have demonstrated the presence of an unidentified source of polychlorinated dibenzo-p-dioxins (PCDDs) in the coastal zone of Queensland (Australia). The present study provides new information on the possible PCDD sources and their temporal input to this environment. Two estuarine sediment cores were collected in northern Queensland for which radiochemical chronologies were established. Core sections from different depositional ages, up to three centuries, have been analyzed for 2,3,7,8-substituted PCDDs and polychlorinated dibenzofurans (PCDFs). Variations of PCDD concentrations in the sediment cores over several centuries of depositional history were relatively small, and elevated PCDD levels were still present in sediment slices from the early 17th century. PCDD/F isomer patterns and congener profiles in sediments deposited during the last 350 years were almost identical and correlated well to the characteristic profiles observed in surface sediments and soils from the entire Queensland coastline. Profiles were dominated by higher chlorinated PCDDs, in particular octachlorodibenzodioxin (OCDD), whereas PCDF concentrations were below or near the limit of detection. These results indicate the presence of a PCDD source prior to industrialization and production of commercial organochlorine products. Further, the present study demonstrates that PCDD input patterns have been similar along an extensive but localized area over at least several centuries, contributing relatively high concentrations of PCDDs to the coastal system of Queensland. PMID:11770761

  9. Temporal trends of triclosan contamination in dated sediment cores from four urbanized estuaries: evidence of preservation and accumulation.

    PubMed

    Cantwell, Mark G; Wilson, Brittan A; Zhu, Jun; Wallace, Gordon T; King, John W; Olsen, Curtis R; Burgess, Robert M; Smith, Joseph P

    2010-01-01

    Triclosan is an antimicrobial agent added to a wide array of consumer goods and personal care products. Through its use, it is introduced into municipal sewer systems where it is only partially removed during wastewater treatment. In this study, triclosan was measured in dated sediment cores from four urbanized estuaries in order to reconstruct temporal and spatial trends of accumulation. Measurable concentrations of triclosan first appeared in each of the sediment cores near 1964, which corresponds with the US patent issuance date of triclosan. The presence of triclosan at each of the study sites at or near the patent date indicates that long-term preservation is occurring in estuarine sediments. Temporal trends of triclosan at each location are unique, reflecting between site variability. Concentrations at one site climbed to as high as 400ngg(-1), due in part, to local commercial production of triclosan. At two locations, levels of triclosan rise towards the surface of each core, suggesting increasing usage in recent years. One location adjacent to a major combined sewer overflow had high sediment concentrations of triclosan, confirming their potential as a source of triclosan to estuaries. PMID:20006371

  10. Historical profiles of PCB in dated sediment cores suggest recent lake contamination through the "halo effect".

    PubMed

    Naffrechoux, Emmanuel; Cottin, Nathalie; Pignol, Cécile; Arnaud, Fabien; Jenny, Jean-Philippe; Perga, Marie-Elodie

    2015-02-01

    We investigated the major sources of polychlorinated biphenyls (PCB) and interpreted the environmental fate processes of these persistent organic pollutants in the past and current PCB contamination of three large, urbanized, French peri-alpine lakes. Dated sediment cores were analyzed in order to reconstruct and compare the historical contamination in all three lakes. Stratigraphic changes of PCB contents and fluxes were considered as revealing the temporal dynamics of PCB deposition to the lakes and the distribution of the seven indicator congeners (further referred to as PCBi) as an indicator of the main contamination origin and pathway. Although located within a single PCB industrial production region, concentration profiles for the three lakes differed in timing, peak concentration magnitudes, and in the PCBi congeners compositions. PCBi fluxes to the sediment and the magnitude of the temporal changes were generally much lower in Lake Annecy (0.05-2 ng·cm(-2)·yr(-1)) as compared to Lakes Geneva (0.05-5 ng·cm(-2)·yr(-1)) and Bourget (5-290 ng·cm(-2)·yr(-1)). For all three lakes, the paramount contamination occurred in the early 1970s. In Lakes Annecy and Bourget, PCB fluxes have declined and plateaued at 0.5 and 8 ng·cm(-2)·yr(-1), respectively, since the early 1990s. In Lake Geneva, PCB fluxes have further decreased by the end of the XX(th) century and are now very low. For the most contaminated lake (Lake Bourget), the high PCBi flux (5-290 ng·cm(-2)·yr(-1)) and the predominance of heavy congeners for most of the time period are consistent with a huge local input to the lake. This still high rate of Lake Bourget is explained by transport of suspended solids from one of its affluents, polluted by an industrial point source. Intermediate historical levels and PCBi distribution over time for Lake Geneva suggest a mixed contamination (urban point sources and distant atmospheric transport), while atmospheric deposition to Lake Annecy explains its lowest

  11. Dating of pollen samples from the sediment core of Lake St Anne in the East Carpathian Mountains, Romania

    NASA Astrophysics Data System (ADS)

    Hubay, Katalin; Katalin Magyari, Enikö; Braun, Mihály; Schabitz, Frank; Molnár, Mihály

    2016-04-01

    Lake St Anne (950 m a.s.l.) is situated in the Ciomadul volcano crater, the youngest volcano in the Carpathians. Aims driving forward the studies there are twofold, one is dating the latest eruption of the Ciomadul volcano and the other is the multi-proxy palaeoenvironmental reconstruction of this region. The sediment of Lake St Anne was sampled several times already, but never reached the bottom of the lake before. During the winter of 2013 at a new core location drilling started at 600 cm water depth and finally reached the bottom of the lake sediment at approximately 2300 cm including water depth. As for all multi-proxy studies essential requirement was to build a reliable chronology. Sediments were dated by radiocarbon method. Previous radiocarbon dates were measured on plant macrofossils, charcoal, Cladocera eggs, chironomid head capsules and bulk lake sediments. Lake St Anne has volcanic origin and there is intensive upwelling of CO2it is important to study and take into consideration, whether there is any local reservoir effect at the case of samples where it could be problematic. Furthermore the late part of the sediment section (between 15,000 and 30,000 cal. yr BP) has low organic matter content (less than 2-4%) with scarcity of datable plant macrofossil material. In this review a different fraction of pollen samples with terrestrial origin was tested and studied as a novel sample type for the radiocarbon dating. Pollen samples were extracted from the lake sediment cores. This type of organic material could be an ideal candidate for radiocarbon based chronological studies as it has terrestrial source and is present in the whole core in contrast with the terrestrial macrofossils. Although the pollen remains were present in the whole core, in many cases their amount give a challenge even for the AMS technic. Samples were measured with EnvironMICADAS AMS and its gas ion source in the HEKAL laboratory (Debrecen, Hungary). We examine the reliability the

  12. CSciBox: An Intelligent Assistant for Dating Ice and Sediment Cores

    NASA Astrophysics Data System (ADS)

    Finlinson, K.; Bradley, E.; White, J. W. C.; Anderson, K. A.; Marchitto, T. M., Jr.; de Vesine, L. R.; Jones, T. R.; Lindsay, C. M.; Israelsen, B.

    2015-12-01

    CSciBox is an integrated software system for the construction and evaluation of age models of paleo-environmental archives. It incorporates a number of data-processing and visualization facilities, ranging from simple interpolation to reservoir-age correction and 14C calibration via the Calib algorithm, as well as a number of firn and ice-flow models. It employs modern database technology to store paleoclimate proxy data and analysis results in an easily accessible and searchable form, and offers the user access to those data and computational elements via a modern graphical user interface (GUI). In the case of truly large data or computations, CSciBox is parallelizable across modern multi-core processors, or clusters, or even the cloud. The code is open source and freely available on github, as are one-click installers for various versions of Windows and Mac OSX. The system's architecture allows users to incorporate their own software in the form of computational components that can be built smoothly into CSciBox workflows, taking advantage of CSciBox's GUI, data importing facilities, and plotting capabilities. To date, BACON and StratiCounter have been integrated into CSciBox as embedded components. The user can manipulate and compose all of these tools and facilities as she sees fit. Alternatively, she can employ CSciBox's automated reasoning engine, which uses artificial intelligence techniques to explore the gamut of age models and cross-dating scenarios automatically. The automated reasoning engine captures the knowledge of expert geoscientists, and can output a description of its reasoning.

  13. Abundances, depositional fluxes, and homologue patterns of polychlorinated biphenyls in dated sediment cores from the Pearl River Delta, China.

    PubMed

    Mai, Bixian; Zeng, Eddy Y; Luo, Xiaojun; Yang, Qingshu; Zhang, Gan; Li, Xiangdong; Sheng, Guoying; Fu, Jiamo

    2005-01-01

    Despite the recent efforts to investigate the distribution and fate of persistent organic pollutants in the tropical and subtropical regions of Asia, very little was known about the temporal change of polychlorinated biphenyls (PCBs) in the environmental ecosystem of China. In this study, three dated sediment cores collected from the Pearl River Delta of southern China were analyzed for a large suite of PCB congeners, from which the temporal profiles of PCB abundances, fluxes, and homologue patterns were constructed. The sedimentary inventories of total PCBs at the sampling sites ranged from 480 to 1310 ng/cm2, at the low end of the worldwide figures. Although production and use of PCBs have been banned or highly restricted in China since the early 1980s, the fluxes of total PCBs continued to increase in the Pearl River Delta sediments. There was a concurrent increase of PCB fluxes and gross domestic product per capita in the region from 1980 to 1997, and a decline of agricultural land use was evident at the same time. Apparently, large-scale land transform since the early 1980s as well as emissions from the PCB-containing electrical equipments were responsible for the sharp rise of PCB fluxes in the recent sediments. The difference in the PCB homologue patterns from 1940 to the mid-1970s was probably indicative of the different timelines of PCB usage in Macao/Hong Kong and mainland China and the differenttypes of technical PCBs commercially used. PCBs were detectable in sediments deposited well before the time frame when production of PCBs began (before 1930) and were relatively enriched in the less chlorinated homologue groups (3Cl and 4Cl PCBs), suggesting the downward mobility of lightly chlorinated PCB congeners in the sediment column. PMID:15667074

  14. Hexabromocyclododecanes, polybrominated diphenyl ethers, and polychlorinated biphenyls in radiometrically dated sediment cores from English lakes, ~1950-present.

    PubMed

    Yang, Congqiao; Rose, Neil L; Turner, Simon D; Yang, Handong; Goldsmith, Ben; Losada, Sara; Barber, Jonathan L; Harrad, Stuart

    2016-01-15

    This paper reports input fluxes between ~1950 and present, of polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs), and hexabromocyclododecanes (HBCDs) in radiometrically-dated sediment cores from 7 English lakes. Fluxes of PCBs at all but one location prone to significant sediment resuspension peaked in the late-1960s/early-1990s, before declining thereafter. Input fluxes of HBCDs at all sites increased from first emergence in the mid-1960s. Thereafter, fluxes peaked in the late-1980s/early-2000s, before declining through to the present, except at the most urban site where HBCD fluxes are still increasing. Trends of PBDEs predominant in the Penta-BDE and Octa-BDE formulations vary between sites. While at some locations, fluxes peaked in the late-1990s/early-2000s; at others, fluxes are still increasing. This suggests the full impact of EU restrictions on these formulations has yet to be felt. Fluxes of BDE-209 have yet to peak at all except one location, suggesting little discernible environmental response to recent EU restrictions on the Deca-BDE product. Strikingly, fluxes of BDE-209 in the most recent core slices either exceed or approach peak fluxes of ΣPCBs, implying substantial UK use of Deca-BDE. Excepting HBCDs, inventories of our target contaminants correlated significantly with local population density, implying substantial urban sources. PMID:26433331

  15. Historical records of mercury, lead, and polycyclic aromatic hydrocarbons depositions in a dated sediment core from the Eastern Mediterranean.

    PubMed

    Azoury, S; Tronczyński, J; Chiffoleau, J-F; Cossa, D; Nakhlé, K; Schmidt, S; Khalaf, G

    2013-07-01

    Depth profiles of mercury, lead and its stable isotopes, and polycyclic aromatic hydrocarbons were determined in a dated sediment core from the Levantine basin. Sedimentary records show that preindustrial fluxes and levels of Hg, Pb, and PAHs remained generally constant in the region before 1850. An almost concurrent uniform increase of both metals and PAHs deposition occurring at the beginning of the Industrial Revolution suggests coal combustion as a main source of these contaminants in the Levantine basin after the 1850s. However, none of the contaminant profiles indicates a decline after 1950-60, the characteristic period of coal use reduction. The modern fluxes of Hg and Pb reveal a 3- to 5-fold increase over preindustrial loads, while the contemporaneous flux of PAHs rises by 4-7 times. On the whole, records in the Eastern Mediterranean suggest atmospheric inputs from relatively distant sources, likely from Central and Eastern Europe. PMID:23725373

  16. Collection, analysis, and age-dating of sediment cores from 56 U.S. lakes and reservoirs sampled by the U.S. Geological Survey, 1992-2001

    USGS Publications Warehouse

    Van Metre, Peter; Wilson, Jennifer T.; Fuller, Christopher C.; Callender, Edward; Mahler, Barbara J.

    2004-01-01

    The U.S. Geological Survey Reconstructed Trends National Synthesis study collected sediment cores from 56 lakes and reservoirs between 1992 and 2001 across the United States. Most of the sampling was conducted as part of the National Water-Quality Assessment (NAWQA) Program. The primary objective of the study was to determine trends in particle-associated contaminants in response to urbanization; 47 of the 56 lakes are in or near one of 20 U.S. cities. Sampling was done with gravity, piston, and box corers from boats and push cores from boats or by wading, depending on the depth of water and thickness of sediment being sampled. Chemical analyses included major and trace elements, organochlorine pesticides, polychlorinated biphenyls, polycyclic aromatic hydrocarbons, cesium-137, and lead-210. Age-dating of the cores was done on the basis of radionuclide analyses and the position of the pre-reservoir land surface in the reservoir and, in a few cases, other chemical or lithologic depth-date markers. Dates were assigned in many cores on the basis of assumed constant mass accumulation between known depth-date markers. Dates assigned were supported using a variety of other date markers including first occurrence and peak concentrations of DDT and polychlorinated biphenyls and peak concentration of lead. A qualitative rating was assigned to each core on the basis of professional judgment to indicate the reliability of age assignments. A total of 122 cores were collected from the 56 lakes and age dates were assigned to 113 of them, representing 54 of the 56 lakes. Seventy-four of the 122 cores (61 percent) received a good rating for the assigned age dates, 28 cores (23 percent) a fair rating, and 11 cores (9 percent) a poor rating; nine cores (7 percent) had no dates assigned. An analysis of the influence of environmental factors on the apparent quality of age-dating of the cores concluded that the most important factor was the mass accumulation rate (MAR) of sediment: the

  17. High-resolution OSL chronology of a sediment core from Lake Nam Co on the southern Tibetan Plateau: Comparison with radiocarbon dating

    NASA Astrophysics Data System (ADS)

    Long, Hao; Shen, Ji; Haberzettl, Torsten; Fuchs, Markus; Frechen, Manfred; Wang, Junbo

    2013-04-01

    Numerous studies on lake sediment cores from the Tibetan Plateau aimed to reconstruct spatial and temporal changes of the late Glacial and Holocene monsoon variations, which are characterized by fluctuations in precipitation and expansion of monsoonal air masses across the Plateau. Accurate and reliable dating of lacustrine deposits is of crucial importance in both the reconstruction of palaeolake and palaeoclimate evolution and the understanding of the mechanisms for climate changes, especially abrupt changes of regional-hemispheric hydrological circulation. Radiocarbon dating is the most commonly used method for establishing chronologies of lake sediments. However, 14C dating of such sediments could be problematic due to the lack of organic matter or a reservoir effect, which appears common in radiocarbon dating of lacustrine sediments from the Tibetan Plateau. In this study, ca. 10.5 m long core (NC core) was retrieved from the water depth of 93 m at Nam Co Lake, which is the second largest saline lake in China, located on the southern Tibetan Plateau. For this core, high-resolution samples (23 samples) were obtained for optically stimulated luminescence (OSL) dating. Quartz of fine-grain (4-11 μm) fraction were extracted from this samples for OSL dating, which is compared with the 14C chronology of NC core based on accelerator mass spectrometry (AMS) dating of bulk organic matter of 22 samples. The sample from the top of NC core was dated to approximate zero age, indicating the sediments bleached well before deposition. Luminescence behaviors of the study samples further confirmed the robustness of OSL ages. Comparison between OSL and 14C ages suggested that: (1) two kinds of ages are in agreement within error from top to 1.8 m, (2) from 1.8 m to the base of NC core, the 14C ages show a general trend to ca. 4 ka higher ages than the OSL ages. Although 14C dating overestimate the ages from 1.8 m to base, they still show the general trend in sedimentation rate

  18. Hg Deposition to Lakes in Northern New England Inferred at Multiple Scales From 210Pb-Dated Sediment Cores

    NASA Astrophysics Data System (ADS)

    Kamman, N. C.; Engstrom, D.

    2004-05-01

    Mercury (Hg) contamination of aquatic systems is recognized to be a problem of global consequence, and Hg bioaccumulation poses significant risks to piscivorous animals and humans who consume gamefish. In order to quantify historical and current Hg deposition to the northern New England landscape, we dated and performed Hg analyses on sediments cores from various lakes at local and regional scales. In this presentation, we contrast results of three studies: a regional assessment of Hg deposition to the VT-NH landscape (10 lakes); a localized study of deposition to the Lye Brook Wilderness of southern VT (four lakes); and the first-ever dated assessment of sediment Hg deposition history for Lake Champlain (three sites + one adjacent inland lake). At the VT-NH scale, total Hg (HgT) fluxes to sediments ranged from 5 to 17 μ g.m-2.yr-1 during pre-industrial times, and from 21 to 83 μ g.m-2.yr-1 presently. Present-day HgT fluxes are between 2.1 to 6.9 times greater than pre-1850 fluxes, and atmospheric Hg deposition to the VT-NH region was estimated at 21 μ g.m-2.yr-1. This agrees well with measured HgT deposition, when re-evasion of Hg is accounted for. Hg fluxes to lake sediments have declined in recent decades, owing to reductions in atmospheric Hg deposition to the lake surfaces. In the high-elevation Lye Brook Wilderness landscape, baseline, peak, and present accumulations were higher than those estimated from the VT-NH dataset, a finding that highlights the roles of elevation, watershed size, and dissolved organic carbon export in mediating Hg transport. Available data from the Lake Champlain Basin show the influence of historical and current watershed sediment delivery due to land cultivation, and more recently to land-use conversion. These studies jointly indicate that watershed export of legacy Hg continues despite declines in present-day deposition rates, contributing to the impression that Hg retention by watershed soils has declined.

  19. Pleistocene meteoric pore water in dated marine sediment cores off Callao, Peru

    NASA Astrophysics Data System (ADS)

    Kriete, Cornelia; Suckow, Axel; Harazim, Bodo

    2004-03-01

    During cruise SO 147 of the German research vessel SONNE, a large decrease in salinity with depth was found in the pore water at a site about 10 sea miles off Callao, Lima, Peru. The origin of this freshening was investigated in a multidisciplinary approach using geochemical, geochronological and isotope hydrological methods. The methodology applied is a possible strategy to deal with anomalous pore water freshenings and if necessary to put them into the general framework of submarine groundwater discharge. Concentrations of the major and conservative elements (e.g., Na, K, Cl, B, Br) decrease at the same ratios. Deuterium ( δD) and oxygen-18 ( δ18O) data reveal the meteoric origin of the fresh water end member, indicating a mixture of 30% seawater and 70% fresh water at a depth in sediment of about 10 m. 210Pb and 137Cs sedimentation rates determined by gamma spectrometry range between 2 and 4.5 mm/y for the last century whereas values derived from AMS 14C for the last millennia give mean rates smaller than 1 mm/y. This indicates strongly varying sedimentation conditions. Nevertheless, from the geochronological data it can be concluded that the origin of the fresh water end member is situated in sediments of Pleistocene age. Literature data of the isotope signature of modern water in the nearby Lima aquifer are clearly different from the calculated values for the fresh water end member in the pore waters. On the basis of the isotopic altitude effect described in the literature, the isotopic signature of the fresh pore water end member can be explained as rain water directly infiltrated into the Lima aquifer. In contrast, this infiltration is negligible there under present-day arid climatic conditions. Theoretical considerations on pore water advective and diffusive transport give further indications that the fresh pore water end member is entrapped paleowater of Pleistocene origin. The observed pore water freshening and the geochemical and geochronological data

  20. Holocene environmental changes of the Godavari Delta, east coast of India, inferred from sediment core analyses and AMS 14C dating

    NASA Astrophysics Data System (ADS)

    Nageswara Rao, Kakani; Saito, Yoshiki; Nagakumar, K. Ch. V.; Demudu, G.; Basavaiah, N.; Rajawat, A. S.; Tokanai, Fuyuki; Kato, Kazuhiro; Nakashima, Rei

    2012-11-01

    The Godavari delta in India is a major wave dominated delta of a tropical monsoon-fed river with one of the largest sediment deliveries in the world. While several earlier studies revealed the nature of landforms and progradation style of the delta plain during the Holocene, the present study attempts to reconstruct the depositional environment of the Godavari delta through the analysis of core sediment and accelerator mass spectrometry (AMS) 14C dating from three locations. The sediment core obtained from a 27.06 m deep borehole at Vilasavilli (VV) supported by 13 14C dates revealed the complete succession of the Holocene deposits unconformably overlying Pleistocene sediments. Textural analysis indicates the lower upward-fining and upper upward-coarsening units in the Holocene succession. Total organic carbon (TOC)/total nitrogen (TN) ratios of > 20; high content of TOC around 1.5-2.5%; and black to very dark colored sediment throughout the muddy part of the Holocene succession indicated a predominance of terrigenous material. The VV core and two other cores (DRP and SDG) with 14 14C dates indicated the thickness of the Holocene sediments in the Godavari delta plain is in the order of ~ 20-50 m, unconformably resting on a seaward sloping Pleistocene basement. Sediment facies and sediment accumulation of the three cores show the evolution of the Godavari delta. A transgressive phase is recognized as an upward-fining succession in the VV core, 8.4-8.0 cal ky BP, followed by a low accumulation period, 8.0-6.3 cal ky BP including the Holocene maximum transgression in the Godavari delta. After 6.3 cal ky BP, areas of high accumulation rates have changed laterally between the central part (VV site) and southwestern part (DRP and SDG sites), may be controlled by the location of river-mouths. Further analysis coupled with 11 more 14C dates compiled from earlier works indicated that the strandplain of the Godavari delta prograded seaward in three stages, and that the rate

  1. Optical Dating of Marine Sediment From ODP Core 658B - An Intercomparison With an Independent AMS 14C Chronology

    NASA Astrophysics Data System (ADS)

    Armitage, S. J.; Stokes, S.; Henderson, G.

    2004-12-01

    We demonstrate the potential of optical dating of detrital quartz silt from marine sediments via a chronological intercomparison for samples from ODP Site 658, which range in age from 0 to 140ka. ODP Site 658 is located off Cap Blanc, Mauritania. It has a high sedimentation rate (18 cm/ka), due to high regional surface productivity and large inputs of windblown Africa dust. This windblown dust provides both the substrate for optical dating and a proxy for North African aridity. The AMS 14C chronology is based on monospecific foraminiferal (Globigerinoides bulloides) samples. This is the first large-scale, systematic application of optical dating to marine sediment, and demonstrates that the technique has considerable potential for the age estimation of otherwise undateable deep-sea material. Optical dating techniques measure the total ionising radiation dose that a mineral grain has received since its last exposure to sunlight (i.e. during burial). The resulting optical age is essentially calibrated via a knowledge of the environmental dose rate, yielding the burial period. The environmental dose rate is derived from the decay of radioisotopes in the sediment (K, U and Th). In terrestrial sediments, the uranium and thorium decay chains can be assumed to be in equilibrium. In the marine realm this assumption is not valid, and unsupported uranium decay series exist on deposition. Consequently, the environmental dose rate changes with sample age. This problem was circumvented by quantifying U and Th decay series disequilibrium, using an MC-ICP-MS. The evolution of the environmental dose rate during burial was modelled, and ages for each sample calculated. The 14C and optical ages are generally in good agreement, indicating that the latter technique can provide equally robust chronologies for marine sediments. Although the maximum age attainable using optical dating is sample specific, the dose rate and luminescence characteristics of the samples analysed in this study

  2. Contaminated Sediment Core Profiling

    EPA Science Inventory

    Evaluating the environmental risk of sites containing contaminated sediments often poses major challenges due in part to the absence of detailed information available for a given location. Sediment core profiling is often utilized during preliminary environmental investigations ...

  3. A carbon, nitrogen, and sulfur elemental and isotopic study in dated sediment cores from the Louisiana Shelf

    USGS Publications Warehouse

    Rosenbauer, R.J.; Swarzenski, P.W.; Kendall, C.; Orem, W.H.; Hostettler, F.D.; Rollog, M.E.

    2009-01-01

    Three sediment cores were collected off the Mississippi River delta on the Louisiana Shelf at sites that are variably influenced by recurring, summer-time water-column hypoxia and fluvial loadings. The cores, with established chronology, were analyzed for their respective carbon, nitrogen, and sulfur elemental and isotopic composition to examine variable organic matter inputs, and to assess the sediment record for possible evidence of hypoxic events. Sediment from site MRJ03-3, which is located close to the Mississippi Canyon and generally not influenced by summer-time hypoxia, is typical of marine sediment in that it contains mostly marine algae and fine-grained material from the erosion of terrestrial C4 plants. Sediment from site MRJ03-2, located closer to the mouth of the Mississippi River and at the periphery of the hypoxic zone (annual recurrence of summer-time hypoxia >50%), is similar in composition to core MRJ03-3, but exhibits more isotopic and elemental variability down-core, suggesting that this site is more directly influenced by river discharge. Site MRJ03-5 is located in an area of recurring hypoxia (annual recurrence >75%), and is isotopically and elementally distinct from the other two cores. The carbon and nitrogen isotopic composition of this core prior to 1960 is similar to average particulate organic matter from the lower Mississippi River, and approaches the composition of C3 plants. This site likely receives a greater input of local terrestrial organic matter to the sediment. After 1960 and to the present, a gradual shift to higher values of ??13C and ??15N and lower C:N ratios suggests that algal input to these shelf sediments increased as a result of increased productivity and hypoxia. The values of C:S and ??34S reflect site-specific processes that may be influenced by the higher likelihood of recurring seasonal hypoxia. In particular, the temporal variations in the C:S and ??34S down-core are likely caused by changes in the rate of

  4. RECONSTRUCTION OF CONTAMINANT TRENDS IN A SALT WEDGE ESTUARY WITH SEDIMENT CORES DATED USING A MULTIPLE PROXY APPROACH

    EPA Science Inventory

    The Taunton River is a partially mixed tidal estuary in southeastern Massachusetts (USA) which has received significant contaminant inputs, yet little information exists on the history of discharge and the subsequent fate of these contaminants. Three sediment cores taken along a...

  5. Dating sediments using luminescence signals

    SciTech Connect

    Wintle, A. )

    1993-05-01

    Before siting a nuclear power station or a nuclear waste repository, it is necessary to establish that the area has been free of earthquake activity for a sufficient period of time. Evidence of past earthquake activity is often provided by faults in surface sediments. Age limits for fault formation can be set by obtaining the depositional ages of the sediment unit in which the fault was formed and the overlying sediment. A useful technique would be one that dating could be applied to the mineral grains that make up the sediments and that would give the time that has passed since the grains were blown or washed into position. Luminescence dating techniques, of which the most well known is thermo-luminescence (TL), provide such information. This approach has been successful in dating movement on the Wasatch Fault in Utah. A combination of TL and radiocarbon dates indicated that three faulting events had occurred within the past 5000 years. 2 refs., 1 fig.

  6. Holocene paleoclimate history of Fallen Leaf Lake, CA., from geochemistry and sedimentology of well-dated sediment cores

    NASA Astrophysics Data System (ADS)

    Noble, Paula J.; Ball, G. Ian; Zimmerman, Susan H.; Maloney, Jillian; Smith, Shane B.; Kent, Graham; Adams, Kenneth D.; Karlin, Robert E.; Driscoll, Neal

    2016-01-01

    Millennial-scale shifts in aridity patterns have been documented during the Holocene in the western United States, yet the precise timing, severity, and regional extent of these shifts prompts further study. We present lake sediment core data from Fallen Leaf Lake, a subalpine system at the southern end of the Lake Tahoe basin for which 80% of the contemporary inflow is derived from snowpack delivered by Pacific frontal storm systems. A high quality age model has been constructed using 14C ages on plant macrofossils, 210Pb, and the Tsoyowata tephra datum (7.74-7.95 cal kyr BP). One core captures the transition from the Late Tioga-younger Dryas glaciolacustrine package to laminated opaline clay at 11.48 cal kyr BP. Early Holocene sedimentation rates are relatively high (∼1.9 mm/year) and cooler winter temperatures are inferred by the presence of pebbles interpreted to be transported out into the lake via shore ice. There is a geochemically distinct interval from ∼4.71 to 3.65 cal kyr BP that is interpreted as a late Holocene neopluvial, characterized by depleted δ13C and lower C:N that point to reduced runoff of terrigenous organic matter, increased winter precipitation, and increased algal productivity. The largest Holocene signal in the cores occurs at the end of the neopluvial, at 3.65 cal kyr BP, and marks a shift into a climate state with variable precipitation, yet is overall more arid than the neopluvial. This new climate state persists for ∼3 ka, until the Little Ice Age. Low sedimentation rates (0.5 mm/year), the homogeneous opaline sediment, and steadily increasing contributions of terrestrial vs. algal organic matter in these cores suggest that the lowstand state of Fallen Leaf Lake may have been the norm from 3.65 to 0.55 cal kyr BP, punctuated by short term high precipitation years or multi-year intervals capable of rapid short duration lake level rise. Fallen Leaf Lake is strongly influenced by changes in winter precipitation and temperature

  7. Historical records from dated sediment cores reveal the multidecadal dynamic of the toxic dinoflagellate Alexandrium minutum in the Bay of Brest (France).

    PubMed

    Klouch, Khadidja Z; Schmidt, Sabine; Andrieux-Loyer, Françoise; Le Gac, Mickaël; Hervio-Heath, Dominique; Qui-Minet, Zujaila N; Quéré, Julien; Bigeard, Estelle; Guillou, Laure; Siano, Raffaele

    2016-07-01

    The multiannual dynamic of the cyst-forming and toxic marine dinoflagellate Alexandrium minutum was studied over a time scale of about 150 years by a paleoecological approach based on ancient DNA (aDNA) quantification and cyst revivification data obtained from two dated sediment cores of the Bay of Brest (Brittany, France). The first genetic traces of the species presence in the study area dated back to 1873 ± 6. Specific aDNA could be quantified by a newly developed real-time PCR assay in the upper core layers, in which the germination of the species (in up to 17-19-year-old sediments) was also obtained. In both cores studied, our quantitative paleogenetic data showed a statistically significant increasing trend in the abundance of A. minutum ITS1 rDNA copies over time, corroborating three decades of local plankton data that have documented an increasing trend in the species cell abundance. By comparison, paleogenetic data of the dinoflagellate Scrippsiella donghaienis did not show a coherent trend between the cores studied, supporting the hypothesis of the existence of a species-specific dynamic of A. minutum in the study area. This work contributes to the development of paleoecological research, further showing its potential for biogeographical, ecological and evolutionary studies on marine microbes. PMID:27162179

  8. Riverine Export of Terrestrial Organic Carbon Investigated by Radiocarbon Dating of Lignin Phenols in River-influenced Marine Core-top Sediments

    NASA Astrophysics Data System (ADS)

    Mollenhauer, G.; Huang, Y.; Kreutz, R.; Kusch, S.; Rethemeyer, J.; Schefuss, E.

    2009-12-01

    Rivers are the principal pathways for the export of terrestrial organic carbon (OC) from the continent to the ocean in the form of particulate and dissolved OC, thereby directly linking the terrestrial and marine carbon cycles. Several recent studies using radiocarbon dates of terrigenous biomarkers in core-top marine sediments to investigate residence time of terrestrial plant biomass in terrestrial reservoirs have reported long-chain aliphatic compounds, i.e., n-alkanes and n-fatty acids as biomarkers for leaf waxes of higher plants, to be significantly pre-aged upon deposition in marine sediments. This could either be interpreted as resulting from admixture of fossil material (e.g., from fossil fuels) to compounds recently produced and rapidly transferred to the marine realm, or to reflect substantial residence time of terrigenous compounds in intermediate reservoirs like soils and fluvial sediments. However, plant leaf waxes are minor components of the terrestrial organic matter and quantitatively unimportant for understanding export rate of terrestrial organic carbon to the ocean. Moreover, long-chain aliphatic lipids are not exclusively derived from higher plants. In contrast, lignin comprises a quarter of the biomass of and is exclusively produced by terrestrial higher plants. Lignin is also considered to be resistant to microbial and enzymatic breakdown and has been used as tracer for terrestrial OC supply to marine sediments. Recently developed HPLC/MS methodology now allows isolation of lignin phenols from natural samples for radiocarbon dating. Here we present radiocarbon ages of lignin phenols isolated from core-top sediments recovered from three different river mouths: the Weser River draining NW and central Germany, the Danube originating in the Alps region and flowing through Southeastern Europe to the Black Sea, and the Congo River representing one of the major tropical river systems. These data are compared with radiocarbon ages of co

  9. Ice Core Dating Software for Interactive Dating of Ice Cores

    NASA Astrophysics Data System (ADS)

    Kurbatov, A. V.; Mayewski, P. A.; Abdul Jawad, B. S.

    2005-12-01

    Scientists involved in ice core dating are well familiar with the problem of identification and recording the depth of annual signals using stable isotopes, glaciochemistry, ECM (electrical conductivity), DEP (dielectric properties) and particle counter data. Traditionally all parameters used for ice core dating were plotted as a function of depth, printed and after years were marked on the paper, converted to depth vs. age time scale. To expedite this tedious and manual process we developed interactive computer software, Ice core Dating (ICD) program. ICD is written in Java programming language, and uses GPL and GPL site licensed graphic libraries. The same 3.5 Mb in size pre-compiled single jar file, that includes all libraries and application code, was successfully tested on WinOS, Mac OSX, Linux, and Solaris operating systems running Java VM version 1.4. We have followed the modular design philosophy in our source code so potential integration with other software modules, data bases and server side distributed computer environments can be easily implemented. We expect to continue development of new suites of tools for easy integration of ice core data with other available time proxies. ICD is thoroughly documented and comes with a technical reference and cookbook that explains the purpose of the software and its many features, and provides examples to help new users quickly become familiar with the operation and philosophy of the software. ICD is available as a free download from the Climate Change Institute web site ( under the terms of GNU GPL public license.

  10. Trace element fluxes and natural potential risks from 210Pb-dated sediment cores in lacustrine environments at the Central Mexican Plateau.

    PubMed

    Ontiveros-Cuadras, J F; Ruiz-Fernández, A C; Sanchez-Cabeza, J A; Pérez-Bernal, L H; Sericano, J L; Preda, M; Wee Kwong, L Liong; Páez-Osuna, F

    2014-01-15

    The accumulation, enrichment and provenance of selected trace metals (Ag, As, Cd, Cr, Cu, Hg, Ni, Pb, V and Zn) were studied in sediment cores collected from three lakes located in the Central Mexican Plateau, selected on the basis of their contrasting degree of urbanization: Santa Elena Lake, in a rural and remote area; El Tule Lake, in a rural and slightly urbanized area; and Chapala Lake, in a highly urbanized area. Grain size, magnetic susceptibility and sedimentary constituents such as organic carbon, calcium carbonate, as well as major (Al, Fe, Mn) and minor (Ca, Li, Rb, Sr, Th) elements were analyzed to explain the concentration trends of trace metals. Factor analysis (FA) was used to assess the provenance of the trace elements. The highest metal enrichment factor (EF) above natural concentration levels was found at Chapala Lake for Ag (EF = 3.9), although other trace element EF in all lakes was <2.0, indicating slight contamination. However, the concentration levels of Cr and Ni in all lakes, Hg and Zn in Chapala Lake, Cu in El Tule Lake and As in Santa Elena Lake were above international benchmarks for which adverse effects are expected to occur frequently, even for those metals only slightly enriched (e.g. As, Cr). Through FA, the terrigenous contribution was identified as the most important source of trace metals to the three lakes, most likely related to deforestation and erosion of the surrounding areas, followed by atmospheric transport of volcanic ashes, rather than to direct sources. PMID:24061059

  11. Temporal trends of persistent organic pollutants in dated sediment cores: Chemical fingerprinting of the anthropogenic impacts in the Seine River basin, Paris.

    PubMed

    Lorgeoux, C; Moilleron, R; Gasperi, J; Ayrault, S; Bonté, P; Lefèvre, I; Tassin, B

    2016-01-15

    Persistent organic pollutants (POPs) were extensively produced and used throughout the last century. In the early 1980s, a rising concern on the environmental impact of these chemicals has led to the establishment of regulations and changes of use including bans. Long term monitoring of the environmental impacts of these emissions and regulations is a challenge because regular monitoring was not mandatory at the beginning of the first emissions. Moreover, the analytical methods have been strongly improved over the decades. To overcome the lack of monitoring and accurate data, sediment cores are powerful tools to construct contamination records. In this study, a high resolution record was constructed for four POPs families (13 polycyclic aromatic hydrocarbons (PAHs), 15 polychlorinated biphenyls (PCBs), 3 alkylphenols (APs) and 8 polybromodiphenyl ethers (PBDEs)) to establish their historical trends in a long-term urbanized and industrialized environment: the Seine River basin, France. These specific families were selected because they had different sources, uses and histories. The results showed concentrations up to 90 mg/kg for ∑PAHs, 2.3mg/kg for ∑PCB, 1.2mg/kg for ∑APs and 0.06 mg/kg for ∑PBDE. The vertical distribution profiles were different from one family to another and presented a good correlation with uses (e.g. transition from coal to natural gas for PAHs), and regulation implementation (e.g., AP ban after "OSPAR Convention" in 1992). The study of compounds distribution provided original information on sources, e.g. temporal variations in PAH uses. This study demonstrates the usefulness and accuracy of sedimentary archives in floodplain to assess the fate of POPs through time in continental hydrosystems. These first results give a comprehensive overview of the contamination in the Seine River basin downstream of Paris Megacity. They were in good agreement with previous studies dedicated to European areas and highlighted specificities of this basin

  12. Accelerator-mass spectrometer (AMS) radiocarbon dating of Pleistocene lake sediments in the Great Basin

    USGS Publications Warehouse

    Thompson, R.S.; Toolin, L.J.; Forester, R.M.; Spencer, R.J.

    1990-01-01

    Pleistocene lake sediments in the Great Basin typically contain little organic carbon, and thus are difficult to date reliably by conventional radioccarbon methods. Paleoenvironmental data are abundant in these sediments, but are of limited value without adequate age controls. With the advent of accelerator-mass spectrometer (AMS) radiocarbon dating, it is now possible to date these paleolacustrine sediments. AMS dates were obtained on sediment cores from the Bonneville, Franklin, and Lahontan Basins. In the Bonneville Basin, the AMS-based chronology compares well with other chronologies constructed from dated shore-zone features. In the Bonneville and Franklin basins, AMS dates delimit unconformities not apparent by other means. We found that dispersed organic carbon from sediments deposited during relatively freshwater intervals provided apparently reliable AMS radiocarbon dates. Carbonate microfossils from the Lahontan Basin also produced results that appear reasonable, while bulk carbonate yielded erroneous results. ?? 1990.

  13. Historical records of organic pollutants in sediment cores.

    PubMed

    Bigus, Paulina; Tobiszewski, Marek; Namieśnik, Jacek

    2014-01-15

    Analyses of sediment core samples are primary sources of historical pollution trends in aquatic systems. Determining organic compounds, such as POPs, in the dated sediments enables the estimation of their temporal concentration changes and the identification of the contaminant origin in local regions. Wars, large-scale fires, economical transitions, and bans on certain chemicals are reflected in the sediment organic compound concentrations. The high POP concentrations in surficial sediments suggest that these chemicals, even after being banned, remain in the environment. Furthermore, vertical profiles can help in understanding the sedimentation process and in estimating effective countermeasures against pollution. Moreover, studies published during the period 1991-2013 on PAHs, PCBs, OCPs, dioxins and dioxin-like compound concentrations in sediment core samples are reviewed. PMID:24300286

  14. Response of magnetic susceptibility in Quaternary lacustrine sediments of the Qaidam Basin (NE Tibetan Plateau) to orbital forcing: applying time series analyses to improve magnetostratigraphic dating of drill core SG-1

    NASA Astrophysics Data System (ADS)

    Herb, C.; Appel, E.; Voigt, S.; Zhang, W.; Fang, X.; Koutsodendris, A.; Pross, J.

    2013-12-01

    The Cenozoic lacustrine sediments around the drilling site of the ~940-m-long core SG-1 from the western Qaidam Basin (NE Tibetan Plateau) in the Chahansilatu sub-depression, having a thickness of up to 6,000 m, offer a great archive for studying past climate change. Magnetostratigraphic dating of SG-1 reveals an average sediment accumulation rate of 35 cm/kyr and a time span ranging from ~2.8 to ~0.1 Ma. Beside several non-magnetic proxies, mass-specific magnetic susceptibility (χ) shows a response to past environmental change. The χ time series displays high-amplitude cyclicities (beside long-term trends), which can be attributed to orbital forcing. Major Milankovitch cycles can be detected as well as the occurrence of spectral power near periods corresponding to nonlinear responses to orbital forcing (near the typical periods of ~30, ~54, and ~70 ka). The Middle Pleistocene Transition (MPT; ~1.2-0.7 Ma) can also be observed in the χ record of SG-1, represented by a typical shift of main spectral power in the 41-kyr obliquity to an additional appearance of the 100-kyr eccentricity band. We attempt to use this climate forced signals of the χ record to establish a more detailed depth-to-time transformation for drill core SG-1 based on cyclostratigraphy and spectral analysis of χ in windows, with the magnetic polarity boundaries as tie points. Due to the changing spectral power of the Milankovitch cycles along the core, SG-1 has to be divided into different parts with different prominences of the 41- and 100-ka cycle, as well as cycles originating from nonlinear climate responses.

  15. Identifying sediment discontinuities and solving dating puzzles using monitoring and palaeolimnological records

    NASA Astrophysics Data System (ADS)

    Dong, Xuhui; Sayer, Carl D.; Bennion, Helen; Maberly, Stephen C.; Yang, Handong; Battarbee, Richard W.

    2016-05-01

    Palaeolimnological studies should ideally be based upon continuous, undisturbed sediment sequences with reliable chronologies. However for some lake cores, these conditions are not met and palaeolimnologists are often faced with dating puzzles caused by sediment disturbances in the past. This study chooses Esthwaite Water from England to illustrate how to identify sedimentation discontinuities in lake cores and how chronologies can be established for imperfect cores by correlation of key sediment signatures in parallel core records and with long-term monitoring data (1945-2003). Replicated short cores (ESTH1, ESTH7, and ESTH8) were collected and subjected to loss-on-ignition, radiometric dating (210Pb, 137Cs, and 14C), particle size, trace metal, and fossil diatom analysis. Both a slumping and a hiatus event were detected in ESTH7 based on comparisons made between the cores and the long-term diatom data. Ordination analysis suggested that the slumped material in ESTH7 originated from sediment deposited around 1805-1880 AD. Further, it was inferred that the hiatus resulted in a loss of sediment deposited from 1870 to 1970 AD. Given the existence of three superior 14C dates in ESTH7, ESTH1 and ESTH7 were temporally correlated by multiple palaeolimnological proxies for age-depth model development. High variability in sedimentation rates was evident, but good agreement across the various palaeolimnological proxies indicated coherence in sediment processes within the coring area. Differences in sedimentation rates most likely resulted from the natural morphology of the lake basin. Our study suggests that caution is required in selecting suitable coring sites for palaeolimnological studies of small, relatively deep lakes and that proximity to steep slopes should be avoided wherever possible. Nevertheless, in some cases, comparisons between a range of contemporary and palaeolimnological records can be employed to diagnose sediment disturbances and establish a chronology.

  16. Effects of sample mass and macrofossil type on radiocarbon dating of arctic and boreal lake sediments

    SciTech Connect

    Oswald, W W; Anderson, P M; Brown, T A; Brubaker, L B; Hu, F S; Lozhkin, A V; Tinner, W; Kaltenrieder, P

    2006-05-29

    Dating lake sediments by accelerator mass spectrometry (AMS) {sup 14}C analysis of plant macrofossils overcomes one of the main problems associated with dating bulk sediment samples, the presence of old organic matter. Even so, many AMS dates from arctic and boreal sites appear to misrepresent the age of the sediment. To understand the nature of these apparent dating anomalies better, we conducted a series of {sup 14}C dating experiments using samples from Alaskan and Siberian lake-sediment cores. First, to test whether our analytical procedures introduced a sample-mass bias, we obtained {sup 14}C dates for different-sized pieces of single woody macrofossils. In these sample-mass experiments, sized statistically equivalent ages were found for samples as small as 0.05 mg C. Second, to assess whether macrofossil type influenced dating results, we conducted sample-type experiments in which {sup 14}C dates were obtained for different macrofossil types sieved from the same depth in the sediment. We dated materials from multiple levels in sediment cores from Upper Capsule Lake (North Slope, northern Alaska) and Grizzly Lake (Copper River Basin, southern Alaska), and from single depths in other records from northern Alaska. In several of the experiments there were significant discrepancies between dates for different plant tissues, and in most cases wood and charcoal were older than other macrofossil types, usually by several hundred years. This pattern suggests that {sup 14}C dates for woody macrofossils may misrepresent the age of the sediment by centuries, perhaps due to their longer terrestrial residence time and the potential in-built age of long-lived plants. This study identifies why some {sup 14}C dates appear to be inconsistent with the overall age-depth trend of a lake-sediment record, and it may guide the selection of {sup 14}C samples in future studies.

  17. An inexpensive sampler for obtaining bulk sediment cores

    NASA Astrophysics Data System (ADS)

    Cooper, Charles M.; Schiebe, Frank R.; Ritchie, Jerry C.

    1991-09-01

    A large-volume core sampler for sediment—muck substrates is described. The sampler can acquire a discrete sediment core of 10 cm in diameter and up to 1.5 m long. Such samplers are needed to collect the volume necessary for analysis of sediments for contaminants, bulk density, or radioactive dating. The sampler consists of a 1- to 2-m length of PVC pipe mounted below a threaded metal pipe air exhaust—intake assembly. This assembly is quick-connected to standard threaded lengths (300 cm) of water pipe (2 cm diam) or electrical conduit so that bottom sediments in water depths of up to 10 m can be sampled. The core sampler is hand-operated and pushed into bottom sediments from a boat. It does not have to be triggered remotely because of the one-way modified check valve in the air exhaust—intake assembly. After the sampler is extracted from the sediment, the extension handle can be quickly removed for ease of sampler handling, and the core can be extruded from the PVC tube by air pressure.

  18. Evidence of fine-grained sediment transport and deposition in Sheboygan River, Wisconsin, based on sediment core chemical tracer profiles

    NASA Astrophysics Data System (ADS)

    Bzdusek, Philip A.; Lu, Jianhang; Christensen, Erik R.

    2005-04-01

    Fine-grained sediment transport and deposition is observed in nine dated sediment cores obtained from the Sheboygan River. The sediment cores were dated by 137Cs and 210Pb methods. Sediment dating was supported by a polychlorinated biphenyl (PCB) analysis and U.S. Army Corps of Engineers (USACE) hydrographic surveys from 1976 to 2002. Plots of 137Cs activity versus depth show distinct peaks related to peak Sheboygan River discharges in the years 1966, 1975, 1979, and 1989. These peaks result from the scouring of sediments during storm discharges and the increased deposition of the fine-grained fraction of particles, including colloidal clay particles (associated with 137Cs and, to some extent, PCBs), in place of the scoured sediments. Core SR1a, upstream of the Pennsylvania Avenue Bridge, and cores SR5-SR8, farther downstream, show continuous sedimentation (1.2-11.8 cm/yr) since the late 1950s, whereas net sediment accumulation virtually ceased after 1988 at the intermediate sites of cores SR1-SR4. The maximum PCB concentration (161 ppm) occurs in 1969 in core SR4.

  19. Application of compound-specific radiocarbon dating for Antarctic margin sediments

    NASA Astrophysics Data System (ADS)

    Ohkouchi, N.; Koizumi, M.; Anderson, J. B.; Eglinton, T. I.; Miura, H.; Yokoyama, Y.

    2008-12-01

    Radiocarbon dating has been extensively applied for the development of chronologies of Antarctic margin sediments deposited during the late Quaternary. However, the problems are 1) the DIC reservoir age in the surface mixed layer is much older than that of the other oceans, 2) Antarctic margin sediments generally lack calcareous foraminifera conventionally used for radiocarbon dating and as stratigraphic tool, and 3) the sediments are subjected to significant "contamination" of relict organic matter eroded from the Antarctic continent, leading to substantially older radiocarbon ages of bulk sedimentary organic matter. Ohkouchi et al. (2003) first applied compound-specific radiocarbon dating to the surface sediments collected from Ross Sea, Antarctica for resolving the problem. They reported that the radiocarbon ages of solvent-extractable, short-chain (C14, C16, and C18) fatty acids are consistent with the modern DIC reservoir age (Pre-bomb: 14C -150, Post-bomb: 14C -100). Furthermore, the radiocarbon ages of these fatty acids at five down-core intervals progressively increase with the core depth. These results clearly show a utility of the compound- specific radiocarbon dating for developing sediment chronologies in Antarctic margin sediments. We also determined radiocarbon ages of the fatty acids from a core recovered in the NW Ross Sea to reconstruct sediment chronologies. Furthermore, we determined hydrogen isotopic compositions of sedimentary biomarkers in the core. Around 6.8, 5.7, 4.1, 2.5, and 1.5 kyr ago, the reconstructed D values of paleo- seawater were -200 or lower, suggesting a large amount of meltwater influx to the Ross Sea. Currently, we are applying the method to more sediment samples collected from wider area of Ross Sea to investigate the timing and pattern of retreat of West Antarctic Ice Sheet in the Holocene. I will present the up-dated results in my talk.

  20. Geophysical Age Dating of Seamounts using Dense Core Flexure Model

    NASA Astrophysics Data System (ADS)

    Hwang, Gyuha; Kim, Seung-Sep

    2016-04-01

    Lithospheric flexure of oceanic plate is thermo-mechanical response of an elastic plate to the given volcanic construct (e.g., seamounts and ocean islands). If the shape and mass of such volcanic loads are known, the flexural response is governed by the thickness of elastic plate, Te. As the age of oceanic plate increases, the elastic thickness of oceanic lithosphere becomes thicker. Thus, we can relate Te with the age of plate at the time of loading. To estimate the amount of the driving force due to seamounts on elastic plate, one needs to approximate their density structure. The most common choice is uniform density model, which utilizes constant density value for a seamount. This approach simplifies computational processes for gravity prediction and error estimates. However, the uniform density model tends to overestimate the total mass of the seamount and hence produces more positive gravitational contributions from the load. Minimization of gravity misfits using uniform density, therefore, favors thinner Te in order to increase negative contributions from the lithospheric flexure, which can compensate for the excessive positives from the seamount. An alternative approach is dense core model, which approximate the heterogeneity nature of seamount density as three bodies of infill sediment, edifice, and dense core. In this study, we apply the dense core model to the Louisville Seamount Chain for constraining flexural deformation. We compare Te estimates with the loading time of the examined seamounts to redefine empirical geophysical age dating of seamounts.

  1. Historical trends in organochlorine compounds in river basins identified using sediment cores from reservoirs

    USGS Publications Warehouse

    Van Metre, P.C.; Callender, E.; Fuller, C.C.

    1997-01-01

    This study used chemical analyses of dated sediment cores from reservoirs to define historical trends in water quality in the influent river basins. This work applies techniques from paleolimnology to reservoirs, and in the process, highlights differences between sediment-core interpretations for reservoirs and natural lakes. Sediment cores were collected from six reservoirs in the central and southeastern United States, sectioned, and analyzed for 137Cs and organochlorine compounds. 137Cs analyses were used to demonstrate limited post-depositional mixing, to indicate sediment deposition dates, and to estimate sediment focusing factors. Relative lack of mixing, high sedimentation rates, and high focusing factors distinguish reservoir sediment cores from cores collected in natural lakes. Temporal trends in concentrations of PCBs, total DDT (DDT + DDD + DDE), and chlordane reflect historical use and regulation of these compounds and differences in land use between reservoir drainages. PCB and total DDT core burdens, normalized for sediment focusing, greatly exceed reported cumulative regional atmospheric fallout of PCBs and total DDT estimated using cores from peat hogs and natural lakes, indicating the dominance of fluvial inputs of both groups of compounds to the reservoirs.This study used chemical analyses of dated sediment cores from reservoirs to define historical trends in water quality in the influent river basins. This work applies techniques from paleolimnology to reservoirs, and in the process, highlights differences between sediment-core interpretations for reservoirs and natural lakes. Sediment cores were collected from six reservoirs in the central and southeastern United States, sectioned, and analyzed for 137Cs and organochlorine compounds. 137Cs analyses were used to demonstrate limited post-depositional mixing, to indicate sediment deposition dates, and to estimate sediment focusing factors. Relative lack of mixing, high sedimentation rates, and high

  2. The vertical variation of nutrients in a sediment core of Delong Lake reveals the anthropogenic effect.

    PubMed

    Guan, Ying; Zang, Shuying; Xiao, Haifeng

    2014-05-01

    Phosphorus content and its species were studied for the core sediments of Delong Lake, using the SMT sequential extraction method, and then were correlated to the contents of total nitrogen and organic matter. According to (210)Pb and (137)Cs dating, the historical profiles of 33 cm core sediments were generated. The objective of this study was to understand how nutrients of lake sediments evolved in order to get insights into the effect of human activities on their sedimentary history. The nutrients contents in the core sediments slowly increased after 1957, showing the human activity influence the natural deposition of the lake sediment. From 1978 to 1985, various nutrients in the lake sediment rapid increased, showing that the human activities strengthened. From 2003 to now, most of nutrients in the sediment rapidly increased and significantly modified the natural deposition of the lake sediment. PMID:24468926

  3. Age Dating Fluvial Sediment Storage Reservoirs to Construct Sediment Waiting Time Distributions

    NASA Astrophysics Data System (ADS)

    Skalak, K.; Pizzuto, J. E.; Benthem, A.; Karwan, D. L.; Mahan, S.

    2015-12-01

    Suspended sediment transport is an important geomorphic process that can often control the transport of nutrients and contaminants. The time a particle spends in storage remains a critical knowledge gap in understanding particle trajectories through landscapes. We dated floodplain deposits in South River, VA, using fallout radionuclides (Pb-210, Cs-137), optically stimulated luminescence (OSL), and radiocarbon dating to determine sediment ages and construct sediment waiting time distributions. We have a total of 14 age dates in two eroding banks. We combine these age dates with a well-constrained history of mercury concentrations on suspended sediment in the river from an industrial release. Ages from fallout radionuclides document sedimentation from the early 1900s to the present, and agree with the history of mercury contamination. OSL dates span approximately 200 to 17,000 years old. We performed a standard Weibull analysis of nonexceedance to construct a waiting time distribution of floodplain sediment for the South River. The mean waiting time for floodplain sediment is 2930 years, while the median is approximately 710 years. When the floodplain waiting time distribution is combined with the waiting time distribution for in-channel sediment storage (available from previous studies), the mean waiting time shifts to approximately 680 years, suggesting that quantifying sediment waiting times for both channel and floodplain storage is critical in advancing knowledge of particle trajectories through watersheds.

  4. Stepped-combustion 14C dating of bomb carbon in lake sediment

    USGS Publications Warehouse

    McGeehin, J.; Burr, G.S.; Hodgins, G.; Bennett, S.J.; Robbins, J.A.; Morehead, N.; Markewich, H.

    2004-01-01

    In this study, we applied a stepped-combustion approach to dating post-bomb lake sediment from north-central Mississippi. Samples were combusted at a low temperature (400 ??C) and then at 900 ??C. The CO2 was collected separately for both combustions and analyzed. The goal of this work was to develop a methodology to improve the accuracy of 14C dating of sediment by combusting at a lower temperature and reducing the amount of reworked carbon bound to clay minerals in the sample material. The 14C fraction modern results for the low and high temperature fractions of these sediments were compared with well-defined 137Cs determinations made on sediment taken from the same cores. Comparison of "bomb curves" for 14C and 137Cs indicate that low temperature combustion of sediment improved the accuracy of 14C dating of the sediment. However, fraction modern results for the low temperature fractions were depressed compared to atmospheric values for the same time frame, possibly the result of carbon mixing and the low sedimentation rate in the lake system.

  5. Radiocarbon dating of plant macrofossils from tidal-marsh sediment

    USGS Publications Warehouse

    Kemp, A.C.; Nelson, Alan R.; Horton, B.P.

    2013-01-01

    Tidal-marsh sediment is an archive of Holocene environmental changes, including movements of sea and land levels, and extreme events such as hurricanes, earthquakes, and tsunamis. Accurate and precise radiocarbon dating of environmental changes is necessary to estimate rates of change and the recurrence interval (frequency) of events. Plant macrofossils preserved in growth position (or deposited soon after death) in tidal-marsh sediment are ideal samples for dating such changes. In this chapter, we focus on the selection of plant macrofossils for radiocarbon dating and the application of ages from different types of macrofossils to varied research projects, and make recommendations for selection and preparation of tidal-marsh samples for dating.

  6. Sediment core and glacial environment reconstruction - a method review

    NASA Astrophysics Data System (ADS)

    Bakke, Jostein; Paasche, Øyvind

    2010-05-01

    Alpine glaciers are often located in remote and high-altitude regions of the world, areas that only rarely are covered by instrumental records. Reconstructions of glaciers has therefore proven useful for understanding past climate dynamics on both shorter and longer time-scales. One major drawback with glacier reconstructions based solely on moraine chronologies - by far the most common -, is that due to selective preservation of moraine ridges such records do not exclude the possibility of multiple Holocene glacier advances. This problem is true regardless whether cosmogenic isotopes or lichenometry have been used to date the moraines, or also radiocarbon dating of mega-fossils buried in till or underneath the moraines themselves. To overcome this problem Karlén (1976) initially suggested that glacial erosion and the associated production of rock-flour deposited in downstream lakes could provide a continuous record of glacial fluctuations, hence overcoming the problem of incomplete reconstructions. We want to discuss the methods used to reconstruct past glacier activity based on sediments deposited in distal glacier-fed lakes. By quantifying physical properties of glacial and extra-glacial sediments deposited in catchments, and in downstream lakes and fjords, it is possible to isolate and identify past glacier activity - size and production rate - that subsequently can be used to reconstruct changing environmental shifts and trends. Changes in average sediment evacuation from alpine glaciers are mainly governed by glacier size and the mass turnover gradient, determining the deformation rate at any given time. The amount of solid precipitation (mainly winter accumulation) versus loss due to melting during the ablation-season (mainly summer temperature) determines the mass turnover gradient in either positive or negative direction. A prevailing positive net balance will lead to higher sedimentation rates and vice versa, which in turn can be recorded in downstream

  7. Successful performance of luminescence dating on glacial sediments

    NASA Astrophysics Data System (ADS)

    Medialdea, Alicia; Bateman, Mark; Evans, David; Roberts, David; Chiverrell, Richard; Clark, Christopher

    2016-04-01

    The use of luminescence dating to establish accurate chronology of sedimentary environments has been exponentially increasing in the last decades. The age range covered and the versatility of the technique have made it become a key in studies of the Quaternary. Nevertheless luminescence dating of glacial sediments has shown to be challenging because of being affected by incomplete bleaching but also due to the complex luminescence behaviour of quartz grain within these sediments. This complexity often causes standard protocols in luminescence dating to be inadequate for this type of material. More than 150 samples from glacial environments are being dated using OSL (optically stimulated luminescence) to provide a base for the BRITICE-CHRONO project which aim is to establish the retreat patterns of the last British and Irish Ice Sheet. This work presents the successful performance of luminescence dating on a selection of these samples for which ages coherent with the LGM have been estimated when applying improved measuring and analysing methods. Comparison with the results obtained using standard protocols showed that implausible ages would have been derived otherwise. In addition, within the B-C project duplicate samples of some sedimentary units have been measured. The coherent results obtained show the reproducibility of these improved methods giving robustness to the age estimates and providing a solid base for the establishing of the ice retreat patterns.

  8. The Late Pliocene Eltanin Impact: Documentation From Sediment Core Analyses

    NASA Technical Reports Server (NTRS)

    Gersonde, R.; Kyte, F.; Flores, J. A.; Becquey, S.

    2002-01-01

    The expeditions ANT-XII/4 (1995) and ANT-XVIII/5a (2001) of the RV POLARSTERN collected extensive bathymetric and seismic data sets as well as sediment cores from an area in the Bellingshausen Sea (eastern Pacific Southern Ocean) that allow the first comprehensive geoscientific documentation of an asteroid impact into a deep ocean (approx. 5 km) basin, named the Eltanin impact. Impact deposits have now been recovered from a total of more than 20 sediment cores collected in an area covering about 80,000 km2. Combined biomagnetostratigraphic dating places the impact event into the earliest Matuyama Chron, a period of enhanced climate variability. Sediment texture analyses and studies of sediment composition including grain size and microfossil distribution reveal the pattern of impact- related sediment disturbance and the sedimentary processes immediately following the impact event. The pattern is complicated by the San Martin Seamounts (approx. 57.5 S, 91 W), a large topographic elevation that rises up to 3000 m above the surrounding abyssal plain in the area affected by the Eltanin impact. The impact ripped up sediments as old as Eocene and probably Paleocene that have been redeposited in a chaotic assemblage. This is followed by a sequence sedimented from a turbulent flow at the sea floor, overprinted by fall-out of airborne meteoritic ejecta that settled trough the water column. Grain size distribution reveals the timing and interaction of the different sedimentary processes. The gathered estimate of ejecta mass deposited over the studied area, composed of shock-melted asteroidal material and unmelted meteorites including fragments up to 2.5 cm in diameter, point to an Eltanin asteroid larger than the 1 km in diameter size originally suggested as a minimum based on the ANT-XII/4 results. This places the energy released by the impact at the threshold of those considered to cause environmental disturbance at a global scale and it makes the impact a likely transport

  9. The Late Pliocene Eltanin Impact - Documentation From Sediment Core Analyses

    NASA Astrophysics Data System (ADS)

    Gersonde, R.; Kuhn, G.; Kyte, F. T.; Flores, J.; Becquey, S.

    2002-12-01

    The expeditions ANT-XII/4 (1995) and ANT-XVIII/5a (2001) of the RV POLARSTERN collected extensive bathymetric and seismic data sets as well as sediment cores from an area in the Bellingshausen Sea (eastern Pacific Southern Ocean) that allow the first comprehensive geoscientific documentation of an asteroid impact into a deep ocean (~ 5 km) basin, named the Eltanin impact. Impact deposits have now been recovered from a total of more than 20 sediment cores collected in an area covering about 80,000 km2. Combined biomagnetostratigraphic dating places the impact event into the earliest Matuyama Chron, a period of enhanced climate variability. Sediment texture analyses and studies of sediment composition including grain size and microfossil distribution reveal the pattern of impact-related sediment disturbance and the sedimentary processes immediately following the impact event. The pattern is complicated by the San Martin Seamounts (~57.5 S, 91 W), a large topographic elevation that rises up to 3000 m above the surrounding abyssal plain in the area affected by the Eltanin impact. The impact ripped up sediments as old as Eocene and probably Paleocene that have been redeposited in a chaotic assemblage. This is followed by a sequence sedimented from a turbulent flow at the sea floor, overprinted by fall-out of airborne meteoritic ejecta that settled trough the water column. Grain size distribution reveals the timing and interaction of the different sedimentary processes. The gathered estimate of ejecta mass deposited over the studied area, composed of shock-melted asteroidal matrial and unmelted meteorites including fragments up to 2.5 cm in diameter, point to an Eltanin asteroid larger than the 1 km in diameter size originally suggested as a minimum based on the ANT-XII/4 results. This places the energy released by the impact at the threshold of those considered to cause environmental disturbance at a global scale and it makes the impact a likely transport mechanism

  10. Dating floodplain sediments using tree-ring response to burial

    USGS Publications Warehouse

    Friedman, J.M.; Vincent, K.R.; Shafroth, P.B.

    2005-01-01

    Floodplain sediments can be dated precisely based on the change in anatomy of tree rings upon burial. When a stem of tamarisk (Tamarix ramosissima) or sandbar willow (Salix exigua) is buried, subsequent annual rings in the buried section resemble the rings of roots: rings become narrower, vessels within the rings become larger, and transitions between rings become less distinct. We combined observations of these changes with tree-ring counts to determine the year of deposition of sedimentary beds exposed in a 150-m-long trench across the floodplain of the Rio Puerco, a rapidly filling arroyo in New Mexico. This method reliably dated most beds thicker than about 30 cm to within a year of deposition. Floodplain aggradation rates varied dramatically through time and space. Sediment deposition was mostly limited to brief overbank flows occurring every few years. The most rapid deposition occurred on channel-margin levees, which migrated laterally during channel narrowing. At the decadal timescale, the cross-section-average sediment deposition rate was steady, but there was a shift in the spatial pattern of deposition in the 1980s. From 1936 to 1986, sediment deposition occurred by channel narrowing, with little change in elevation of the thalweg. After 1986 sediment deposition occurred by vertical aggradation. From 1936 to 2000 about 27 per cent of the arroyo cross-section filled with sediment. The rate of filling from 1962 to 2000 was 0-8 vertical m/decade or 85 m2/decade. Published in 2005 by John Wiley & Sons, Ltd.

  11. ENANTIOMERIC RATIOS OF CHIRAL PCB ATROPISOMERS IN RADIODATED SEDIMENT CORES

    EPA Science Inventory

    Enantiomeric ratios (ERs)) of chiral polychlorinated biphenyl (PCB) atropisomers were quantified in radiodated sediment cores of Lake Hartwell SC, a reservoir heavily impacted by PCBS, to study spatial and temporal changes in chirality. A chiral analysis of cores showed accumulat...

  12. Infrared images of core sediments offshore southwestern Taiwan

    NASA Astrophysics Data System (ADS)

    Chiang, H. T.; Chuang, Y. H.

    2015-12-01

    The core sediments may retain the negative thermal anomaly caused by the gas hydrate dissociation on the way uploading from sea floor. To identify the signal of negative thermal anomaly, fifteen infrared images of core sediments with tens of meter in length have been analyzed the temperature distribution off southwestern Taiwan. This study results show that most of the core sediments were found lots of gaps with spiking pattern recognition of high temperature on the lower portions. The geochemistry study suggested that the gas in gaps and the sediments were mainly composed of methane which may be the indicators of gas hydrate dissociation in the higher temperature and lower pressure environment. The thermal gradients 0.044-0.114 ℃/m of core sediments are close to the observations in situ by the measurements of temperature probes that thermal gradient are 0.06-0.09 ℃/m. The temperature of all core sediments are greater than 20 ℃. It is obvious that the temperature of core sediments were increased tremendously by the heating of sea water. We found eight out of fifteen core sediments with significant negative thermal anomaly 0.4-1.0 ℃ in different depth between 2 and 10 meters below sea floor. Compare to the experiment in lab that the temperature could be decreased 1.1-1.5 ℃ due to the gas hydrate dissociation, the quantity of the negative thermal anomaly of the core sediments are possible related to the gas hydrate dissociation.

  13. Optical Dating of Martian Eolian Sediments by Robotic Spacecraft

    NASA Astrophysics Data System (ADS)

    Sears, Derek W. G.; Lepper, Kenneth; McKeever, W. S.

    2000-07-01

    The Martian polar ice caps record a wealth of information about the past history and climate of Mars, but as pointed out by Clifford et al. in the summary of the First International Conference on Mars Polar Science and Exploration, 'The single greatest obstacle to unlocking and interpreting the geologic and climatic record preserved at the [martian] poles is the need for absolute dating.' Stratification in the polar caps arises, at least in part, from the incorporation of eolian material into the ice, and dune fields near the poles indicate eolian transport is an important surfical process in this region of Mars. Eolian materials are ideally suited for sediment dating using luminescence methods. Luminescence dating techniques have been used successfully to make absolute age determinations for numerous terrestrial Quaternary eolian deposits. Clifford et al. also concluded that cost, simplicity, and potential for minaturization make luminescence dating more feasible than isotopic methods for in situ dating by robotic landers. In fact, the water detection equipment of the Deep Space 2 microprobes and the MECA on the Mars Polar Lander contain components similar to those required for luminescence dating.

  14. Radiocarbon Dating and age Inversions in Lake Chapala Late Holocene Sediments, Western Mexico.

    NASA Astrophysics Data System (ADS)

    Zarate-Del Valle, P.; Israde-Alcantara, I.; Ramírez-Sánchez, H.; Gómez-Salazar, S.; Ríos-Donato, N.

    2006-12-01

    Neotectonic Lake Chapala, the major Mexican freshwater reservoir lies at the north and northeast of the Citala Rift and is linked to history of the active Plio-Quaternary Transmexican Volcanic Belt geological province. Eight radiocarbon 14C dates were obtained on shallow sediment samples from a gravity corer (T46) of 5 cm in diameter and 1.7 m long. The core was collected from the western sector of Lake Chapala (103° 15.43' W, 20° 14.45' N) at water depth of 3.7 m (june 2000). In general, shallow sediments (<2m deep) in Lake Chapala are dark and silty with granulometric median ranging from 10 to 50 μm. Major oxides in sediments are: SiO2 (54.05%), Al2O3 (18.94%), Fe2O3 (6.75%) and CaO (2.57%). The major mineralogical composition of sediments is as follows: plagioclases (25.86%), quartz (20.92%), clays (38.5%), carbonates (2.99%) and TiO2 (1.05%). Radiocarbon ages were measured by accelerator mass spectrometry (AMS) and were obtained through the organic carbon fraction extracted from the bulk sediment samples sliced every 20 cm taken from the whole core. Stratigraphically ordered from highest to lowest, the eight ages reported are: 1) 2,000 ±40 yr on sediments at 30 cm deep; 2) 1,920 ±35 yr on sediments at 50 cm deep; 3) 1,900 ±35 yr on sediments at 70 cm deep; 4) 2,080 ±35 yr on sediments at 90 cm deep; 5) 2,090 ±50 yr on sediments at 110 cm deep; 6) 2,190 ±35 yr on sediments at 130 cm deep; 7) 2,050 ±35 yr on sediments at 150 cm deep and, 8) 1,500 ±35 yr on sediments at 170 cm deep. From the top until 70 cm and from 130 to bottom we observe two age inversions; the interval apparently with no age inversions is from 70cm to 130cm. As it is known the age inversions observed may be due to a) ancient carbon being incorporated into the sediment during deposition; b) unrecognized bioturbation, c) Postdepositional alteration and, d) variations in the apparent geological ages of the different chemical phases comprising the total sediment. Basically, the factors

  15. Geochemistry of sediments in cores and sediment traps from Bear Lake, Utah and Idaho

    USGS Publications Warehouse

    Bischoff, James L.; Cummins, Kathleen; Shamp, Donald D.

    2005-01-01

    The present study of Bear Lake began in 1998. Initially, the study utilized sediments from three long cores (up to 5 m) previously collected in 1996 and short cores (up to 40 cm) collected in 1998. The short cores were specifically acquired to preserve the uppermost layers of sediment that may have been lost in the long cores. In addition, three arrays of sediment traps were deployed during the summer of 1998, and sediment from these traps was collected during the summers of 1999 and 2000 (see Dean and others, 2005, for core and sediment trap locations). The cores and sediment traps were sampled, and splits were distributed to various investigators for analyses of a wide variety of sediment parameters. The chemical composition of the acid-soluble component of the sediments is presented in this report. HCl or HNO3 treatment of the sediment quantitatively dissolves the authigenic component of the sediment, a component that includes carbonates, sulfates, and iron-mono sulfides. In the case of Bear Lake, CaCO3 is the major component of the sediment today and for most of the Holocene (Dean and others 2005). The chemical composition of the acid-soluble fraction gives important information on this component and, therefore, insight into the chemical conditions of the lake at the time of carbonate deposition.

  16. Polychlorinated biphenyl congeners in sediment cores from the Upper Mississippi River.

    PubMed

    Martinez, Andres; Schnoebelen, Douglas J; Hornbuckle, Keri C

    2016-02-01

    We determined polychlorinated biphenyls (PCBs) and radionuclide (137)Cs in sediment cores from the Upper Mississippi River (UMR) and the Iowa River, Iowa, at their confluence. Vertical distribution of (137)Cs indicated negligible mixing in the UMR core, while the Iowa River core showed signs of mixing. A clear (137)Cs peak was found in the UMR core, which was correlated to 1963. The PCB vertical distribution in UMR core was similar to the historical trend in Aroclor production observed in Great Lakes cores, with a peak close to the (137)Cs peak, suggesting a date near 1960. In general, PCB congener profiles in both cores resembled the Iowa soil background signal. We concluded that despite evidence of mixing in the Iowa River core, both cores retain the PCB signature of historical and regional environmental exposure. Further, our results indicate that this iconic waterway has a long history of PCBs that reflects national production and use. PMID:26547030

  17. C-14 Dating and High-Resolution Physical Properties data from Holocene IMAGES core MD992286, Skagerrak

    NASA Astrophysics Data System (ADS)

    Gyllencreutz, R.

    2001-12-01

    A long piston core, MD992286, was retrieved from Skagerrak in 1999 during leg 3 of the IMAGES V cruise. The investigated area is characterised by high sedimentation rates and intense water mass mixing, as a branch of the North Atlantic Current turns anti-clockwise, slows down and blends with other waters to form the Norwegian Coastal Current. Present day SSTs in Skagerrak are strongly linked to the NAO-index. The sediments in the core consist of relatively homogenous silty clay with a slight coarsening upwards. A preliminary age model has been made from four AMS C-14 datings on shells, and the 32.4 m long core spans c. 11.800 cal years BP. This is nearly 50% older than expected from sediment thickness in Chirp-Sonar profiles and calculated sedimentation rates of about 4 mm/yr (Boe et al., 1996), and shows that MD992286 is the longest piston core covering the entire Holocene, ever retrieved. Further carbon dating of core MD992286 will be performed on foraminifera. The CALYPSO-corer is believed not to preserve the topmost sediments undisturbed. Therefore, a 1.5 m long Gravity core, Sk000209-2, was retrieved from the same location in order to get better recovery of the surface sediments. High-resolution susceptibility point-measurements at 1 cm resolution, of both core MD9922868 and Sk 000209-2, was used to correlate the two cores. The susceptibility correlation indicates that the sediment in the CALYPSO core is expanded 150% relative to the Gravity core. Susceptibility and L a b-colour data will be presented, along with water content and MST measured density log data displaying sub-centennial variability. Given the length of the core and the high sedimentation rate, a high resolution study of climate variability throughout the Holocene is possible in core MD992286. References: Boe, R., Rise L., Thorsnes, T. H., de Haas, H., Saether, O. M. and Kunzendorf, H.1996. Sea-bed sediments and sediment accumulation rates in the Norwegian part of Skagerrak. Nor. geol. unders

  18. Radiocarbon dating, chronologic framework, and changes in accumulation rates of holocene estuarine sediments from Chesapeake Bay

    USGS Publications Warehouse

    Colman, Steven M.; Baucom, P.C.; Bratton, J.F.; Cronin, T. M.; McGeehin, J.P.; Willard, D.; Zimmerman, A.R.; Vogt, P.R.

    2002-01-01

    Rapidly accumulating Holocene sediments in estuaries commonly are difficult to sample and date. In Chesapeake Bay, we obtained sediment cores as much as 20 m in length and used numerous radiocarbon ages measured by accelarator mass spectrometry methods to provide the first detailed chronologies of Holocene sediment accumulation in the bay. Carbon in these sediments is a complex mixture of materials from a variety of sources. Analyses of different components of the sediments show that total organic carbon ages are largely unreliable, because much of the carbon (including coal) has been transported to the bay from upstream sources and is older than sediments in which it was deposited. Mollusk shells (clams, oysters) and foraminifera appear to give reliable results, although reworking and burrowing are potential problems. Analyses of museum specimens collected alive before atmospheric nuclear testing suggest that the standard reservoir correction for marine samples is appropriate for middle to lower Chesapeake Bay. The biogenic carbonate radiocarbon ages are compatible with 210 Pb and 137 Cs data and pollen stratigraphy from the same sites. Post-settlement changes in sediment transport and accumulation is an important environmental issue in many estuaries, including the Chesapeake. Our data show that large variations in sediment mass accumulation rates occur among sites. At shallow water sites, local factors seem to control changes in accumulation rates with time. Our two relatively deep-water sites in the axial channel of the bay have different long-term average accumulation rates, but the history of sediment accumulation at these sites appears to reflect overall conditions in the bay. Mass accumulation rates at the two deep-water sites rapidly increased by about fourfold coincident with widespread land clearance for agriculture in the Chesapeake watershed.

  19. OSL dating of fine-grained quartz from Holocene Yangtze delta sediments

    NASA Astrophysics Data System (ADS)

    Sugisaki, S.; Buylaert, J. P.; Murray, A. S.; Tada, R.; Zheng, H.; Ke, W.; Saito, K.; Irino, T.; Chao, L.; Shiyi, L.; Uchida, M.

    2014-12-01

    Flood events in the Yangtze River are associated with variation in East Asian Summer Monsoon (EASM) precipitation. Understanding the frequency and scale of the EASM precipitation during the Holocene is a key to understanding the mechanism and cyclicity of floods and droughts. Because about 70% of the annual discharge occurs during the flood season, the Yangtze delta sediments provide a good archive of EASM precipitation. In this study, we investigate the possibility of applying OSL dating to establishing high-resolution chronologies for the Yangtze delta sediment cores YD13-1H and G3. The objectives of this study are: (1) test whether fine grained quartz in present day suspended particle matter (SPM) is fully bleached or reset before deposition, (2) where possible, test quartz fine- and coarse-grain OSL dating against radiocarbon shell ages, (3) interpret the sediment transport processes through the differential bleaching of quartz and feldspar OSL signals. We show that the SPM collected from the surface water column of the Yangtze River during the flood season is well-bleached (offset ~60 years). Fine-grained pro-delta sediments are thus potentially a good dosimeter for OSL dating. OSL ages sediment cores indicate a pronounced change in sedimentation rate at ~6 ka and ~2ka. These events are consistent with what is known of the evolution of the Yangtze catchment and delta. The delta began to build at ~6 ka (Zhao et al., 1979), and human activities increased significantly in the catchment at ~2ka (Chen et al., 1985). It is however surprising that the entire top 9 m of sediment only records these two events. The question of whether significant deposition was limited to 2 ka and 6 ka, or whether the record has been disturbed by erosion/reworking remains. These issues are discussed in terms of the reliability of the quartz OSL ages, the degree of bleaching by comparison with polymineral OSL signals, and the relationship of the OSL ages to the sedimentary record.

  20. Radiometric dating of sediments using fission tracks in conodonts

    USGS Publications Warehouse

    Sachs, H.M.; Denkinger, M.; Bennett, C.L.; Harris, A.G.

    1980-01-01

    Conodonts are microfossils which are commonly found in marine rocks of Cambrian to Triassic age. Although their biological affinities are difficult to assess, conodonts are valuable stratigraphical indices for much of their geological range1. Recent work has also established that conodont colour alteration indices (CAI) are useful guides to diagenetic temperatures and hence burial depth2. Fission tracks3 in conodonts allow measurement of uranium concentrations and estimates of 'age' to be made using isotopic methods4. We report here that fission tracks counted in irradiated, thermally unaltered (as indicated by CAI) middle Palaeozoic conodonts indicate typical uranium concentrations of ???1 part in 10 9, with some samples higher. A single specimen of Siphonodella from the Lower Mississippian yielded an age estimate of 380??140 Myr consistent with conventional interpolations. This method may also allow the unroofing of deeply buried sediments to be dated. ?? 1980 Nature Publishing Group.

  1. Source determination of benzotriazoles in sediment cores from two urban estuaries on the Atlantic Coast of the United States.

    PubMed

    Cantwell, Mark G; Sullivan, Julia C; Katz, David R; Burgess, Robert M; Bradford Hubeny, J; King, John

    2015-12-15

    Benzotriazoles (BZTs) are used in a broad range of commercial and industrial products, particularly as metal corrosion inhibitors and as ultraviolet (UV) light stabilizer additives in plastics and polymers. In this study, dated sediment cores from two east coast estuaries were analyzed for commonly used BZTs. In Narragansett Bay, UV stabilizing BZTs (UV-BZTs) were present at high levels from 1961 on, reflecting their patent date, local production and long-term preservation in sediment. In Salem Sound, UV-BZTs were present at concentrations consistent with other coastal marine locations not influenced by BZT production. Anticorrosive BZTs (AC-BZTs) were found in both cores, with the highest levels reported to date present in Narragansett Bay, indicating sorption to, and preservation in, sediments. This study revealed that both classes of BZTs have remained structurally intact over time in coastal sediment cores, demonstrating their resistance to degradation and persistence in environmental compartments. PMID:26561444

  2. Natural thorium isotopes in marine sediment core off Labuan port

    SciTech Connect

    Hafidz, B. Y.; Asnor, A. S.; Terence, R. C.; Mohamed, C. A. R.

    2014-02-12

    Sediment core was collected from Labuan port and analyzed to determine the radioactivity of thorium (Th) isotopes. The objectives of this study are to determine the possible sources of Th isotopes at Labuan port and estimates the sedimentation rate based on {sup 228}Th/{sup 232}Th model. The results suggest the {sup 230}Th and {sup 232}Th might be originated from terrestrial sedimentary rock while {sup 228}Th originated by authigenic origin. High ratio value of {sup 230}Th/{sup 232}Th detected at the top surface sediment indicates the increasing of {sup 230}Th at the recent years which might be contributed from the anthropogenic sources. The sedimentation rate of core sediment from Labuan Port was successfully estimated by using {sup 228}Th/{sup 232}Th model. The result show high sedimentation rate with 4.67 cm/year indicates rapid deposition occurred at this study area due to the high physical activity at the Labuan port. By assume the constant sedimentation rate at this area; we estimated the age of 142 cm core sediment obtained from Labuan port is 32 years started from 1981 to 2012. This chronology will be used in forthcoming research to investigate the historical profile of anthropogenic activities affecting the Labuan port.

  3. Dating Pliocene lacustrine sediments in the central Jordan Valley, Israel — Implications for cosmogenic burial dating

    NASA Astrophysics Data System (ADS)

    Davis, M.; Matmon, A.; Fink, D.; Ron, H.; Niedermann, S.

    2011-05-01

    Cosmogenic burial dating of sediments is usually used at sites with relatively simple or known exposure-burial histories, such as in caves. In an attempt to extend the applicability of the method to other common geological settings (i.e. the dating of late Neogene sedimentary formations), where much less is known about the exposure-burial history, we apply the cosmogenic burial method on Pliocene-early Pleistocene (1.5-4.5 Ma) lacustrine sediments in the central Jordan Valley, Israel. 26Al, 10Be, and 21Ne concentrations in quartz were obtained from a 170 m tectonically-tilted section. Assuming fast burial and no post-burial production we obtained burial ages which range between 3.5 and 5.3 Ma. Integrating simple geological reasoning and the cosmogenic nuclide data, post burial production is found to be insignificant. We also found that the samples contain two distinct populations of grains (chert and quartz) from two different sources which experienced different pre-burial exposure histories. The cosmogenic nuclide concentrations in the samples are in accordance with those expected for the mixing of two sources, and the burial ages computed for both end members agree. Theoretical calculations of two-source mixing show that initial 26Al/10Be ratios are depressed relative to the expected surface ratios and may result in burial ages overestimated by as much as 500 ka. Using ages derived from cosmogenic nuclides, independent age constraints, and magnetostratigraphy we correlate the bottom of the section to the Cochiti Normal magnetic subchron (4.19-4.30 Ma) within the Reverse Gilbert chron, and the top of the section to the Reverse subchron at the top of the Gilbert chron (3.60-4.19 Ma).

  4. Radiocarbon dating Arctic deep marine sediment to refine the usage of Mn pattern as a stratigraphic tool

    NASA Astrophysics Data System (ADS)

    Chiu, Pin-Yao Bernie; Löwemark, Ludvig

    2016-04-01

    The distinctive pattern of Mn content in Arctic deep marine sediment has been used as a proxy to indicate glacial-interglacial cyclicity (Löwemark et al., 2014). As has been observed in many sediment cores, Mn peaks correspond to warm interglacial periods. In order to improve the preciseness of Mn pattern as a proxy, we collected the foraminifera Neogloboquadrina pachyderma (sinistral) from brownish, Mn-rich layers, and performed radiocarbon dating on selected cores collected during the LOMROG07, LOMROG09 and LOMROG12 expeditions. Additional cores form the YMER and AO96 expeditions are also included. Based on our general understanding of the Mn system in the Arctic Ocean, we predicted a Mn pattern with a high peak in the uppermost core top, representing the Holocene. This Holocene peak in Mn is separated from the underlying warm period MIS 3 by a Mn-poor interval also characterized by a drop in Ca. This Mn and Ca poor interval reperesents MIS 2 and the LGM. Older warm periods, such as MIS 3, 5, 7 etc will display a similar pattern with distinct Mn peaks, separated by Mn minima representing cold iperiods For example, the MIS 5 sometimes shown a distinct pattern with three Mn peaks representing MIS 5a, 5c and 5e. However, there are still some limitations in the applicability of Mn stratigraphy, such as the remobilization of the Mn layer and the core-top loss during coring. We performed AMS carbon 14 dating on more than 10 cores, and the result revealed several cases of lost core tops, leading to depletion or complete loss of the Holocene interval. In several cores, our AMS dating revealed a hiatus in the MIS2 interval. The complete lack of MIS2 sediment likely is the result of extremely slow sedimentation rate due to severe sea ice conditions, while places with records of LGM may be the result of polynyas within the sea ice, or certain circulation pattern. Consequently, although Mn pattern can be used as a preliminary tool to identify glacial-interglacial cycles

  5. Diffusimetry (diffusion constant estimation) on sediment cores by resistivity probe

    USGS Publications Warehouse

    Manheim, Frank T.; Waterman, Lee S.

    1974-01-01

    Measurement of formation factor (ratio of rock resistivity to interstitial water resistivity) from sediment cores provides an indirect measurment of the tortuosity of the fluid channels in the sediments. From these measurements one can estimate the diffusion coefficient of the sediment with depth. The F (formation factor) values for Indian Ocean sediments varied from 1.6 for a clayey diatom ooze having 87% porosity (70% water content) to 13.6 for a cemented limestone having 25% porosity (11% water content). These formation factors would yield diffusion coefficients for chloride ions in the corresponding sediments of 6.4 x 10-6 to 1.5 x 10-6 cm2/sec. In general, surficial sediments showed diffusion coefficients about one-half to one-third of those for free solution, values decreasing with depth and porosity.

  6. Immunoassay screening of sediment cores for polychlorinated biphenyls, Devil's Swamp Lake near Baton Rouge, Louisiana, 2004

    USGS Publications Warehouse

    Van Metre, Peter C.; Wilson, Jennifer T.

    2004-01-01

    Devil?s Swamp Lake near Baton Rouge, Louisiana, constructed by dredging in 1973 in Devil?s Swamp along the Mississippi River, is contaminated with polychlorinated biphenyls (PCBs). This study investigated the possible historical contribution of PCBs from a hazardous-chemical disposal facility by way of a wastewater drainage ditch that operated from 1971 to 1993. Six sediment cores from the lake and three bottom-material samples from the drainage ditch were collected on October 5, 2004, and analyzed for PCBs using an immunoassay screening method. The results were used to evaluate qualitatively the historical input record of PCBs to the lake. Deposition dates in three of the cores were estimated by assuming that penetration of the push corer was stopped by firmer, pre-lake materials that mark the 1973 subsurface level of dredging. Sixty-one samples from five of the six cores and three bottom-material samples from the drainage ditch were analyzed. PCBs were at higher concentrations in ditch bottom material (about 1.1 to 2.2 milligrams per kilogram) than in cores from sites near where the ditch enters the lake (about 0.1 to 1.0 milligrams per kilogram). The highest concentrations of PCBs (maximum about 15 milligrams per kilogram) were detected in lake-bottom sediment about 350 meters west of where the drainage ditch enters the lake. Detection rates and median PCB concentrations were higher in all of the dated core sediments deposited before about 1990 than after 1990.

  7. Historical accumulation of organic contaminants in sediment cores from Massachusetts and Cape Cod Bays

    SciTech Connect

    Seavey, J.A.; Shea, D.; Weisbrod, A.V.; Hofelt, C.S.

    1995-12-31

    Trace level concentrations of over 50 polynuclear aromatic hydrocarbons (PAH) and linear alkyl benzenes (LAB), 16 chlorinated pesticides, and 20 polychlorinated biphenyls (PCB) were measured in sediment cores collected at ten sampling stations located in Massachusetts and Cape Cod Bays. The sediment cores were dated by using Pb-210. PAH and LAB values ranged from 36--30388 ng/g and < 1--181 ng/g (dry weight), respectively. Pesticide and PCB values ranged from 0.8--23 ng/g and 0.8--35 ng/g, respectively. As expected, the contaminant concentrations correlate with the amount of organic carbon in the sediment and generally decrease with increasing age of the sediment and increasing distance from Boston Harbor, the major historical source of many of these contaminants. Total inventories of contaminants in Massachusetts Bay were calculated and used to help construct a contaminant mass balance for the region. Down-core profiles were used to help reconstruct historical loading to the region. The relative distributions of contaminants in the sediment were used, along with source distributions (fingerprints), to calculate the contribution of each source to the measured sediment inventory. LABs were particularly useful in distinguishing the Boston Harbor sewage effluent from other sources. Implications to the long term fate and effects of contaminants in Massachusetts and Cape Cod Bays will be presented.

  8. A record of hydrocarbon input to San Francisco Bay as traced by biomarker profiles in surface sediment and sediment cores

    USGS Publications Warehouse

    Hostettler, F.D.; Pereira, W.E.; Kvenvolden, K.A.; VanGeen, A.; Luoma, S.N.; Fuller, C.C.; Anima, R.

    1999-01-01

    San Francisco Bay is one of the world's largest urbanized estuarine systems. Its water and sediment receive organic input from a wide variety of sources; much of this organic material is anthropogenically derived. To document the spatial and historical record of the organic contaminant input, surficial sediment from 17 sites throughout San Francisco Bay and sediment cores from two locations Richardson Bay and San Pablo Bay were analyzed for biomarker constituents. Biomarkers, that is, 'molecular fossils', primarily hopanes, steranes, and n-alkanes, provide information on anthropogenic contamination, especially that related to petrogenic sources, as well as on recent input of biogenic material. The biomarker parameters from the surficial sediment and the upper horizons of the cores show a dominance of anthropogenic input, whereas the biomarker profiles at the lower horizons of the cores indicate primarily biogenic input. In the Richardson Bay core the gradual upcore transition from lower maturity background organics to a dominance of anthropogenic contamination occurred about 70-100 years ago and corresponds to the industrial development of the San Francisco Bay area. In San Pablo Bay, the transition was very abrupt, reflecting the complex depositional history of the area. This sharp transition, perhaps indicating a depositional hiatus or erosional period, dated at pre-1952, is clearly visible. Below, the hiatus the biomarker parameters are immature; above, they are mature and show an anthropogenic overlay. Higher concentrations of terrigenous n-alkanes in the upper horizons in this core are indicative of an increase in terrigenous organic matter input in San Pablo Bay, possibly a result of water diversion projects and changes in the fresh water flow into the Bay from the Delta. Alternatively, it could reflect a dilution of organic material in the lower core sections with hydraulic mining debris.

  9. Dating Taal Lake sediment of Philippines by using the bomb radiocarbon curve

    NASA Astrophysics Data System (ADS)

    Li, H.; Xu, X.

    2008-12-01

    Taal Lake is located in Batangas Province of central Philippines (14° 00.1'N, 120° 59.1'E), with a surface area of 267 km2, a maximum depth of 176 m and an elevation of 3 m above sea level. The lake occupies the famous Taal Volcano system which consists of a 15 × 22 km prehistoric caldera. The 5 km wide Taal Volcano Island which has 47 craters and 4 maars, lies in the north central Taal Lake. With 34 recorded eruptions, Taal Volcano is considered one of the most active volcanic centers in the Philippines and is one of the 16 monitored volcanoes by the Global Volcanism Network. In order to investigate specifically geochemical and isotopic proxies which have paleo-eruption and paleoclimate significances in the sediment cores, we had retrieved two gravity cores from the lake in 2007: TLS1 with 90cm length from a water depth of 100m, and TLS2 with 120cm length from a water depth of 15m. Core TLS2 contains plant remains at 16 horizons which were selected for AMS 14C dating at UCI. Only one of the sixteen plant samples has a δ13C value of -16.4 per mil, whereas the rest samples have the δ13C values ranging from -24.2 to -30.1 per mil. The δ13C values indicate that the plant remains are mainly terrestrial C3 plants. The comparisons of Acid-Base-Acid (ABA) treated samples with non-ABA treated samples show the same results within uncertainty. Except for the sample at 16.7cm, the Δ14C of samples from 0 to 95cm are 51.9~401.9 per mil peaked at 79cm depth, matching very well with the bomb 14C curve determined in tree rings. The distribution of the bomb 14C profile allows us to establish the chronology of Core TLS2, which yields a constant sedimentation rate of 2.04cm/year. Based on this chronology, living plants around Taal Lake may have a lower initial Δ14C (-30 per mil) compared to the Modern Standard. Core TLS1 contains much less plant remains. Three samples from depths of 1.2, 38.5 and 72 cm have Δ14C values of -32.9, 9.9 and -141.8 per mil, respectively. This

  10. Using sediment cores to establish targets for the remediation of aquatic environments.

    PubMed

    Lintern, Anna; Anderson, Marion; Leahy, Paul; Deletic, Ana; McCarthy, David

    2016-01-01

    When assigning site-specific restoration targets for deteriorating aquatic systems, it is necessary to have an understanding of the undisturbed or background state of the system. However, the site-specific characteristics of aquatic systems prior to disturbance are mostly unknown, due to the lack of historical water and sediment quality data. This study aims to introduce a method for filling this gap in our understanding, using dated sediment cores from the beds of aquatic environments. We used Bolin Billabong, a floodplain lake of the Yarra River (South-East Australia), as a case study to demonstrate the application of this method. We identified the concentrations of aluminium, cadmium, chromium, copper, iron, lead, manganese, nickel, tin and zinc at 8 cm intervals through the sediment core. This showed that aluminium, chromium, copper, iron, lead, nickel, tin and zinc concentrations in Bolin Billabong sediments significantly increased after European settlement in the river catchment in the mid-19th century. The differences between current Australian sediment quality guidelines trigger values and the background metal concentrations in Bolin Billabong sediments underscore the value of using locally relevant background toxicant concentrations when setting water and sediment quality targets. PMID:26877046

  11. INNOVATIVE TECHNOLOGY EVALUATION REPORT, SEDIMENT SAMPLING TECHNOLOGY, ART'S MANUFACTURING, SPLIT CORE SAMPLER FOR SUBMERGED SEDIMENTS

    EPA Science Inventory


    The Split Core Sampler for Submerged Sediments (Split Core Sampler) designed and fabricated by Arts Manufacturing & Supply, Inc., was demonstrated under the U.S. Environmental Protection Agency (EPA) Superfund Innovative Technology Evaluation Program in April and May 1999 at ...

  12. Dating of Pliocene Colorado River sediments: implications for cosmogenic burial dating and the evolution of the lower Colorado River

    USGS Publications Warehouse

    Matmon, Ari; Stock, Greg M.; Granger, Darryl E.; Howard, Keith A.

    2011-01-01

    We applied cosmogenic 26Al/10Be burial dating to sedimentary deposits of the ancestral Colorado River. We compared cosmogenic burial ages of sediments to the age of an independently well-dated overlying basalt flow at one site, and also applied cosmogenic burial dating to sediments with less precise independent age constraints. All dated gravels yielded old ages that suggest several episodes of sediment burial over the past ∼5.3 m.y. Comparison of burial ages to the overlying 4.4 Ma basalt yielded good agreement and suggests that under the most favorable conditions, cosmogenic burial dating can extend back 4–5 m.y. In contrast, results from other sites with more broadly independent age constraints highlight the complexities inherent in burial dating; these complexities arise from unknown and complicated burial histories, insufficient shielding, postburial production of cosmogenic isotopes by muons, and unknown initial 26Al/10Be ratios. Nevertheless, and in spite of the large range of burial ages and large uncertainties, we identify samples that provide reasonable burial age constraints on the depositional history of sediment along the lower ancestral Colorado River. These samples suggest possible sediment deposition and burial at ca. 5.3, 4.7, and 3.6 Ma. Our calculated basinwide erosion rate for sediment transported by the modern Colorado River (∼187 mm k.y.−1) is higher than the modern erosion rates inferred from the historic sediment load (80–100 mm k.y.−1). In contrast, basinwide paleo-erosion rates calculated from Pliocene sediments are all under 40 mm k.y.−1 The comparatively lower denudation rates calculated for the Pliocene sediment samples are surprising given that the sampled time intervals include significant Pliocene aggradation and may include much incision of the Grand Canyon and its tributaries. This conflict may arise from extensive storage of sediment along the route of the Colorado River, slower paleobedrock erosion, or the inclusion

  13. Sediment Coring of the Proglacial Lake Donguz-Orun (northern Caucasus, Russia)

    NASA Astrophysics Data System (ADS)

    Alexandrin, Mikhail; Solomina, Olga; Kalugin, Ivan; Darin, Andrey; Nesje, Atle

    2014-05-01

    dendrochronology for dating its lateral and terminal moraines. The upper part of the core (0-170 mm) was scanned applying X-ray fluorescent microanalysis using synchrotron radiation and sampled for dating using 137Cs and 210Pb. The assumption that the sediment stratification represents annual layering (spring flood) is generally confirmed with correlation of the Rb/Sr-ratio (that supposedly marks grain-size variations in the sediments) curve and the image of the sediment core. Calculations of Rb/Sr peaks or visual layers yield an accumulation rate of around 2 mm/yr. Analogous results (1.73 mm/yr) are derived from 137Cs-dating. With this high accumulation rate, the sediment core of Lake Donguz-Orun represents an important source of information for high-resolution reconstructions of climatic parameters and glacier variations of the region. The research project of Mikhail Alexandrin is supported by grant# 227470/F11 issued by The Research Council of Norway.

  14. Bioavailability of sediment-associated PAHs by Lumbriculus variegatus in sediment cores

    SciTech Connect

    Harkey, G.A.; VanHoof, P.L.; Landrum, P.F.

    1994-12-31

    Lumbriculus variegatus were exposed four weeks to sediment core sections. Sediment was taken from Lake George in northern Michigan and known to be historically contaminated with PAHs. Bioaccumulation was maximal at the 12--16 cm depth where sediment PAH concentrations were greatest. Accumulation was minimal in surficial and 44--48 cm sections. Accumulation peaked at about 96 h, then declined over the remainder of the study for some of the lower molecular weight PAHs. For most higher molecular weight compounds, accumulation peaked at 2 weeks, then slightly declined at 4 weeks. Uptake rate coefficients stayed relatively constant for specific PAH congeners over the range of sediment depths, suggesting constant bioavailability with sediment aging. Accumulation factors (AFs) of selected congeners were also consistent among sediment depths and were comparable to those calculated for other species reported in previous studies.

  15. The Record of Geomagnetic Excursions from a ~150 m Sediment Core: Clear Lake, Northern California

    NASA Astrophysics Data System (ADS)

    Levin, E.; Byrne, R.; Looy, C. V.; Wahl, D.; Noren, A. J.; Verosub, K. L.

    2015-12-01

    We are studying the paleomagnetic properties of a new ~150 meter drill core from Clear Lake, CA. Step-wise demagnetization of the natural remanent magnetism (NRM) yields stable directions after 20 mT, implying that the sediments are reliable recorders of geomagnetic field behavior. Several intervals of low relative paleointensity (RPI) from the core appear to be correlated with known geomagnetic excursions. At about 46 m depth, and ~33 ka according to an age model based on radiocarbon dates obtained from pollen and the Olema ash bed, a low RPI zone seems to agree with the age and duration of the Mono Lake Excursion, previously identified between 32 and 35 ka. Slightly lower in the core, at about 50 m depth and ~40 ka, noticeably low RPI values seem to be coeval with the Laschamp excursion, which has been dated at ~41 ka. A volcanic ash near the bottom of the core (141 mblf) is near the same depth as an ash identified in 1988 by Andrei Sarna-Wojcicki and others as the Loleta ash bed in a previous Clear Lake core. If the basal ash in the new core is indeed the, Loleta ash bed, then the core may date back to about 270-300 ka. Depending on the age of the lowest ash, a sequence of low RPI intervals could correlate with the Blake (120 ka), Iceland Basin (188 ka), Jamaica/Pringle Falls (211 ka), and CR0 (260 ka) excursions. Correlation of the low RPI intervals to these geomagnetic excursions will help in the development of a higher resolution chronostratigraphy for the core, resolve a long-standing controversy about a possible hiatus in the Clear Lake record, and provide information about climatically-driven changes in sedimentation.

  16. Short Sediment Cores as Archives of Urban Pollution

    NASA Astrophysics Data System (ADS)

    Latimer, J. C.; McLennan, D. A.; Stone, J.; Memmer, E. D.; Foster, J. A.; Hardin, K. J.; Nickerson, Z.; Portwood, C. A.; Williams, T. M.

    2014-12-01

    Urban areas are host to numerous sources of environmental pollution, including industry, traffic, and past land uses. To document this pollution within Vigo County, Indiana, we collected several short cores from ponds and wetlands throughout the county, including cores from the old industrial park in Terre Haute, nature parks, a lake impacted by acid mine drainage, and a newly restored wetland to investigate heavy metal burial in these aquatic ecosystems. One core was collected from a holding pond that was constructed in the 1950's on the former International Paper (IP) site where corrugated packing products were produced for nearly a century. One of the nature parks (Dobbs Nature Park) was established in 1976, while the other sits on a former Brownfield site and was only recently opened to the public (Maple Avenue Nature Park). Scott Lake is adjacent to an abandoned coal mine, and continues to receive acidic drainage. Wabashiki Fish and Wildlife Area is flooded seasonally by the Wabash River. Prior land uses for the Wabashiki include agriculture and illegal dumping. All of these sites, except IP are designated fishing areas. Based on water chemistry and diatom assemblages, these ponds have acceptable water quality; however, some are becoming increasingly more eutrophic. Preliminary results from the IP and Maple Avenue Nature Park sediment cores indicate elevated heavy metal concentrations above background levels and at concentrations high enough to impact benthic organisms based on NOAA Sediment Quality Guidelines. Diatoms from the IP core suggest a transition from low productivity at the base to nutrient-rich conditions in more recent sediments, and several diatom specimens have observable deformities (typically an indicator of heavy metals). The base of the IP core also has metal concentrations that are 5 times greater than the top of the core. In many cases, sediments from the Maple Avenue Nature Park pond have metal concentrations higher than the surrounding

  17. Dating of sediments from four Swiss prealpine lakes with (210)Pb determined by gamma-spectrometry: progress and problems.

    PubMed

    Putyrskaya, V; Klemt, E; Röllin, S; Astner, M; Sahli, H

    2015-07-01

    In this paper the most important problems in dating lake sediments with unsupported (210)Pb are summarized and the progress in gamma-spectrometry of the unsupported (210)Pb is discussed. The main topics of these studies concern sediment samples preparation for gamma-spectrometry, measurement techniques and data analysis, as well as understanding of accumulation and sedimentation processes in lakes. The vertical distributions of artificial ((137)Cs, (241)Am, (239)Pu) and natural radionuclides ((40)K, (210,214)Pb, (214)Bi) as well as stable trace elements (Fe, Mn, Pb) in sediment cores from four Swiss lakes were used as examples for the interpretation, inter-comparison and validation of depth-age relations established by three (210)Pb-based models (CF-CSR, CRS and SIT). The identification of turbidite layers and the influence of the turbidity flows on the accuracy of sediment dating is demonstrated. Time-dependent mass sedimentation rates in lakes Brienz, Thun, Biel and Lucerne are discussed and compared with published data. PMID:25875007

  18. Technologies for retrieving sediment cores in Antarctic subglacial settings.

    PubMed

    Hodgson, Dominic A; Bentley, Michael J; Smith, James A; Klepacki, Julian; Makinson, Keith; Smith, Andrew M; Saw, Kevin; Scherer, Reed; Powell, Ross; Tulaczyk, Slawek; Rose, Mike; Pearce, David; Mowlem, Matt; Keen, Peter; Siegert, Martin J

    2016-01-28

    Accumulations of sediment beneath the Antarctic Ice Sheet contain a range of physical and chemical proxies with the potential to document changes in ice sheet history and to identify and characterize life in subglacial settings. Retrieving subglacial sediments and sediment cores presents several unique challenges to existing technologies. This paper briefly reviews the history of sediment sampling in subglacial environments. It then outlines some of the technological challenges and constraints in developing the corers being used in sub-ice shelf settings (e.g. George VI Ice Shelf and Larsen Ice Shelf), under ice streams (e.g. Rutford Ice Stream), at or close to the grounding line (e.g. Whillans Ice Stream) and in subglacial lakes deep under the ice sheet (e.g. Lake Ellsworth). The key features of the corers designed to operate in each of these subglacial settings are described and illustrated together with comments on their deployment procedures. PMID:26667918

  19. Multi-proxy dating of Holocene maar lakes and Pleistocene dry maar sediments in the Eifel, Germany

    NASA Astrophysics Data System (ADS)

    Sirocko, Frank; Dietrich, Stephan; Veres, Daniel; Grootes, Pieter M.; Schaber-Mohr, Katja; Seelos, Klemens; Nadeau, Marie-Josée; Kromer, Bernd; Rothacker, Leo; Röhner, Marieke; Krbetschek, Matthias; Appleby, Peter; Hambach, Ulrich; Rolf, Christian; Sudo, Masafumi; Grim, Stephanie

    2013-02-01

    During the last twelve years the ELSA Project (Eifel Laminated Sediment Archive) at Mainz University has drilled a total of about 52 cores from 27 maar lakes and filled-in maar basins in the Eifel/Germany. Dating has been completed for the Holocene cores using 6 different methods (210Pb and 137Cs activities, palynostratigraphy, event markers, varve counting, 14C). In general, the different methods consistently complement one another within error margins. Event correlation was used for relating typical lithological changes with historically known events such as the two major Holocene flood events at 1342 AD and ca 800 BC. Dating of MIS2-MIS3 core sections is based on greyscale tuning, radiocarbon and OSL dating, magnetostratigraphy and tephrochronology. The lithological changes in the sediment cores demonstrate a sequence of events similar to the North Atlantic rapid climate variability of the Last Glacial Cycle. The warmest of the MIS3 interstadials was GI14, when a forest with abundant spruce covered the Eifel area from 55 to 48 ka BP, i.e. during a time when also other climate archives in Europe suggested very warm conditions. The forest of this "Early Stage 3 warm phase" developed subsequently into a steppe with scattered birch and pine, and finally into a glacial desert at around 25 ka BP. Evidence for Mono Lake and Laschamp geomagnetic excursions is found in two long cores. Several large eruptions during Middle and Late Pleistocene (Ulmener Maar - 11,000 varve years BP, Laacher See - 12,900 varve years BP, Mosenberg volcanoes/Meerfelder Maar 41-45 cal ka BP, Dümpel Maar 116 ka BP, Glees Maar - 151 ka BP) produced distinct ash-layers crucial for inter-core and inter-site correlations. The oldest investigated maar of the Eifel is 40Ar/39Ar dated to the time older than 520 ka BP.

  20. Effects of Local Farming and Deforestation on Sediment Discharge Inferred From Sediment Accumulation Rates and Patterns in Lake Core Records From Coastal Lake Tanganyika, East Africa

    NASA Astrophysics Data System (ADS)

    Strickler, M. L.; Lezzar, K. E.; Soreghan, M.; Cohen, A. S.; Swarzenski, P. W.; Berke, M.; McHeni, M.; Gunderson, K.; Allen, K.; Palke, A.; Modesta, M.; Nkotagu, H.

    2006-12-01

    Lake Tanganyika is the oldest and largest of the East African rift lakes and vital to the economy of the surrounding villages and countries. Deforestation around the lake causes many negative effects from an increased sediment flux and has changed dramatically as a function of population. Increases in inorganic sediment flux from deforested watersheds and an associated decrease in organic sediment flux may negatively impact the viability of littoral habitats in the lake. This study examines the interrelationship between deforestation on streams that feed into Lake Tanganyika and sedimentation offshore. We mapped stream morphology of two distinct streams: Kalande (Gombe Stream National Park), and Ngelwa (deforested). An offshore core was collected from the lake bottom just offshore of the deforested Ngelwa stream at a water depth of 106m and dated using 14C and 210Pb geochronologic methods. In addition, multiple laboratory analyses were performed on the core and within the streams to help constrain sedimentation and deforestation effects. Three distinct units within the core correlate to reflect changes in sedimentation (higher rates as deforestation continues) in addition to a shift from dry, low lake level conditions to wet, high lake levels as evidenced by shifts in core lithologies, diatom taxonomy and content, magnetic susceptibility, and clastic particle size. Streambed and suspended sediment analyses reflect high levels of erosion in deforested watersheds coupled with changes in dissolved nutrients in the water (silica, orthophosphate), which may suggest an overall diminished level of ecosystem function in deforested and heavily farmed watersheds.

  1. Dating of mine waste in lacustrine sediments using cesium-137

    NASA Astrophysics Data System (ADS)

    Rember, W. C.; Erdman, T. W.; Hoffmann, M. L.; Chamberlain, V. E.; Sprenke, K. F.

    1993-11-01

    For over a century Medicine Lake in northern Idaho has received heavy-metal-laden tailings from the Coeur d'Alene mining district. Establishing the depositional chronology of the lake bottom sediments provides information on the source and rate of deposition of the tailings. Cesium-137, an isotope produced in the atmosphere by nuclear bomb tests, was virtually absent in the environment prior to 1951, but reached its apex in 1964. Our analysis of cesium-137 in the sediments of Medicine Lake revealed that 14 cm of fine-grained tailings were deposited in the lake from 1951 to 1964 and tailing deposition downstream was greatly reduced by the installation of tailings dams in the district in 1968. Cesium-137 analysis is accomplished by a fairly simple gamma-ray counting technique and should be a valuable tool for analyzing sedimentation in any lacustrine environment that was active during the 1950s and 1960s.

  2. Disequilibrium between [sup 226]Ra and supported [sup 210]Pb in a sediment core from a shallow Florida lake

    SciTech Connect

    Brenner, M.; Peplov, A.J.; Schelske, C.L. )

    1994-07-01

    [sup 210]Pb dating can be used to assign ages in lake sediment cores, calculate rates of sediment accumulation, and determine the timing of recent changes in lake-watershed ecosystems. We used low-background gamma counting to measure [sup 226]Ra and total [sup 210]Pb activity in a core from Lake Rowell, Florida. [sup 226]Ra activity was high and strongly variable throughout the core, even exceeding total [sup 210]Pb activity in recently deposited sediments. We traced one source of Ra-rich sediments to the only inflow, Alligator Creek, where stream-bottom deposits display disequilibrium between [sup 226]Ra and supported [sup 210]Pb. High and variable [sup 226]Ra activity in the Lake Rowell profile argues for direct estimates of in situ Ra in lake sediment cores from disturbed watersheds that have Ra-bearing bedrock. Isotopic disequilibrium between [sup 226]Ra and supported [sup 210]Pb makes it difficult to distinguish between supported and unsupported [sup 210]Pb activity throughout the Lake Rowell core and would require special assumptions and nonconventional dating models to establish age-depth relationships. 78 refs., 3 figs., 1 tab.

  3. Radioactive fallouts as temporal makers for glacier ice cores dating

    NASA Astrophysics Data System (ADS)

    Clemenza, M.; Cucciati, G.; Maggi, V.; Pattavina, L.; Previtali, E.

    2012-06-01

    In this paper, we intend to show how analytical methods used in nuclear physics, as gamma spectroscopy, are powerful tools for the dating of environmental archives. Specifically, we will show how events related to the release in the environment of great amount of radioactive isotopes ( e.g., atmospheric nuclear test explosions) can be used as temporal markers in alpine glaciers. The radio-isotope selected for the dating of ice carrots is 137Cs , because of its chemical and nuclear properties. The radioactive measurements have been conducted using a low-background high-purity germanium detector. The sensitivity for the prepared samples is 10mBq/kg. We will illustrate how dating curves (date versus depth of the sample) can be considered as an absolute calibrator for all the other chemical dating methods used on glacier samples analyses.

  4. A sampler for coring sediments in rivers and estuaries

    USGS Publications Warehouse

    Prych, Edmund A.; Hubbell, D.W.

    1966-01-01

    A portable sampler developed to core submerged unconsolidated sediments collects cores that are 180 cm long and 4.75cm in diameter. The sampler is used from a 12-m boat in water depths up to 20 m and in flow velocities up to 1.5m per second to sample river and estuarine deposits ranging from silty clay to medium sand. Even in sand that cannot be penetrated with conventional corers, the sampler achieves easy penetration through the combined application of vibration, suction, and axial force. A piston in the core barrel creates suction, and the suspension system is arranged so that tension on the support cable produces both a downward force on the core barrel and a lateral support against overturning. Samples are usually retained because of slight compaction in the driving head; as a precaution, however, the bottom of the core barrel is covered by a plate that closes after the barrel is withdrawn from the bed. Tests show that sample-retainers placed within the driving head restrict penetration and limit core lengths. Stratification within cores is disrupted little as a result of the sampling process.

  5. Diagenetic regimes in Arctic Ocean sediments: Implications for sediment geochemistry and core correlation

    NASA Astrophysics Data System (ADS)

    Meinhardt, A.-K.; März, C.; Schuth, S.; Lettmann, K. A.; Schnetger, B.; Wolff, J.-O.; Brumsack, H.-J.

    2016-09-01

    Dark brown sediment layers are a potential stratigraphic tool in Quaternary Arctic Ocean sediments. They are rich in Mn, Fe, and trace metals scavenged from the water column and were most likely deposited during interglacial intervals. In this study, we combine sediment and pore water data from sediment cores taken in different parts of the Arctic Ocean to investigate the influence of early diagenetic processes on sediment geochemistry. In most studied cores, Mn, Co, and Mo are released into the pore waters from Mn oxide dissolution in deeper (>1.5 m) sediment layers. The relationship between sedimentary Mn, Co, and Mo contents in excess of the lithogenic background (elementxs) shows that Coxs/Moxs values are a diagnostic tool to distinguish between layers with diagenetic metal addition from the pore waters (Coxs/Moxs < 1), layers affected by Mn oxide dissolution and metal release (Coxs/Moxs > 10), and unaffected layers (Coxs/Moxs from 1 to 10). Steady-state calculations based on current pore water profiles reveal that in the studied cores, the diagenetic addition of these metals from the pore water pool alone is not sufficient to produce the sedimentary metal enrichments. However, it seems evident that dissolution of Mn oxides in the Mn reduction zone can permanently alter the primary geochemical signature of the dark brown layers. Therefore, pore water data and Coxs/Moxs values should be considered before core correlation when this correlation is solely based on Mn contents and dark sediment color. In contrast to the mostly non-lithogenic origin of Mn in the dark brown layers, sedimentary Fe consists of a large lithogenic (80%) and a small non-lithogenic fraction (20%). Our pore water data show that diagenetic Fe remobilization is not currently occurring in the sediment. The dominant Fe sources are coastal erosion and river input. Budget calculations show that Fe seems to be trapped in the modern Arctic Ocean and accumulates in shelf and basin sediments. The Fe

  6. Dating of coastal marine sediments: 210Pb versus 137Cs signal on the Danube-influenced Black Sea shelf

    NASA Astrophysics Data System (ADS)

    Friedrich, Jana; Laptev, Gennady

    2010-05-01

    Coastal marine sediments represent a natural archive of pelagic processes, coastal erosion and river discharge of suspended matter. Correct dating of those sediments is a prerequisite for chronological reconstruction of the flux of pollutants and organic matter from the water column to the sediments and hence, the reconstruction of the pollution and eutrophication events. In the reconstruction of the sedimentation history during the pre-industrial and industrial periods, which usually spans the past 100 years, the natural occurring radionuclide 210Pb and the artificial radionuclides 137Cs and 241Am are widely applied tracers. 137Cs is used as an independent time marker for end the atmospheric bomb test fallout in 1963 and the Chernobyl accident in 1986. As the 137Cs signal is often weakened due to its mobility in sediments, 241Am, less mobile than 137Cs and derived from decay the bomb fallout of 241Pu, is used as a second time marker of the 1963 event. The northwestern shelf of the Black Sea has been seriously affected by eutrophication and pollution from the late 1960's to the mid-1990's, largely triggered by Danube River input of nutrients and pollutants. The aim of our study is ultimately to reconstruct the eutrophication history and recycling of nutrients following the deposition of organic matter. The ‘memory effect' of sediment recycling plays a critical role in maintaining eutrophic conditions in enclosed seas such as the Black Sea. Here we present results from sediment cores taken within the Danube River plume on the shallow northwestern shelf of the Black Sea. The cores have been dated in two laboratories to rule out artifacts. The sediment record is repeatedly interrupted by so-called turbidites that consist of stiff clay. The clay horizons display a drop in unsupported 210Pb and 137Cs and a higher signal of supported 210Pb than the non-clay horizons. Below the turbidite, the unsupported 210Pb and 137Cs increase again to values above the turbidite. This

  7. Reconstructed Sediment Mobilization Processes in a Large Reservoir Using Short Sediment Cores

    NASA Astrophysics Data System (ADS)

    Cockburn, J.; Feist, S.

    2014-12-01

    Williston Reservoir in northern British Columbia (56°10'31"N, 124°06'33") was formed when the W.A.C. Bennett Dam was created in the late 1960s, is the largest inland body of water in BC and facilitates hydroelectric power generation. Annually the reservoir level rises and lowers with the hydroelectric dam operation, and this combined with the inputs from several river systems (Upper Peace, Finlay, Parsnip, and several smaller creeks) renews suspended sediment sources. Several short-cores retrieved from shallow bays of the Finlay Basin reveal near-annual sedimentary units and distinct patterns related to both hydroclimate variability and the degree to which the reservoir lowered in a particular year. Thin section and sedimentology from short-cores collected in three bays are used to evaluate sediment mobilization processes. The primary sediment sources in each core location is linked to physical inputs from rivers draining into the bays, aeolian contributions, and reworked shoreline deposits as water levels fluctuate. Despite uniform water level lowering across the reservoir, sediment sequences differed at each site, reflecting the local stream inputs. However, distinct organic-rich units, facilitated correlation across the sites. Notable differences in particle size distributions from each core points to important aeolian derived sediment sources. Using these sedimentary records, we can evaluate the processes that contribute to sediment deposition in the basin. This work will contribute to decisions regarding reservoir water levels to reduce adverse impacts on health, economic activities and recreation in the communities along the shores of the reservoir.

  8. Chlorinated hydrocarbon pesticides and polychlorinated biphenyls in sediment cores from San Francisco Bay

    USGS Publications Warehouse

    Venkatesan, M.I.; De Leon, R. P.; VanGeen, A.; Luoma, S.N.

    1999-01-01

    Sediment cores of known chronology from Richardson and San Pablo Bays in San Francisco Bay, CA, were analyzed for a suite of chlorinated hydrocarbon pesticides and polychlorinated biphenyls to reconstruct a historic record of inputs. Total DDTs (DDT = 2,4'- and 4,4'-dichlorodiphenyltrichloroethane and the metabolites, 2,4'- and 4,4'-DDE, -DDD) range in concentration from 4-21 ng/g and constitute a major fraction (> 84%) of the total pesticides in the top 70 cm of Richardson Bay sediment. A subsurface maximum corresponds to a peak deposition date of 1969-1974. The first measurable DDT levels are found in sediment deposited in the late 1930's. The higher DDT inventory in the San Pablo relative to the Richardson Bay core probably reflects the greater proximity of San Pablo Bay to agricultural activities in the watershed of the Sacramento and San Joaquin rivers. Total polychlorinated biphenyls (PCBs) occur at comparable levels in the two Bays (< 1-34 ng/g). PCBs are first detected in sediment deposited during the 1930's in Richardson Bay, about a decade earlier than the onset of detectable levels of DDTs. PCB inventories in San Pablo Bay are about a factor of four higher in the last four decades than in Richardson Bay, suggesting a distribution of inputs not as strongly weighed towards the upper reaches of the estuary as DDTs. The shallower subsurface maximum in PCBs compared to DDT in the San Pablo Bay core is consistent with the imposition of drastic source control measures four these constituents in 1970 and 1977 respectively. The observed decline in DDT and PCB levels towards the surface of both cores is consistent with a dramatic drop in the input of these pollutants once the effect of sediment resuspension and mixing is taken into account.

  9. Absolute dating of Caribbean cores p6304-8 and p6304-9.

    PubMed

    Rona, E; Emiliani, C

    1969-01-01

    Two deep-sea cores from the central Caribbean have been dated by the thorium-230/ protactinium-231 method. The ages obtained are in agreement with the ages previously obtained from other deep-sea cores from the same area. Because of their greater precision, the new dates provide a more accurate time scale for the past 170,000 years. PMID:17780174

  10. Sediment core fossils in ancient Lake Ohrid: testing for faunal change since the Last Interglacial

    NASA Astrophysics Data System (ADS)

    Albrecht, C.; Vogel, H.; Hauffe, T.; Wilke, T.

    2010-11-01

    Ancient Lake Ohrid is probably of early Pleistocene or Pliocene origin and amongst the few lakes in the world harbouring an outstanding degree of endemic biodiversity. Although there is a long history of evolutionary research in Lake Ohrid, particularly on molluscs, a mollusc fossil record has been missing up to date. For the first time, gastropod and bivalve fossils are reported from the basal, calcareous part of a 2.6 m long sediment succession (core Co1200) from the north-eastern part of Lake Ohrid. Electron spin resonance (ESR) dating of mollusc shells from the same stratigraphic level yielded an age of 130 ± 28 ka. Lithofacies III sediments, i.e. a stratigraphic subdivision comprising the basal succession of core Co1200 between 181.5-263 cm, appeared solid, greyish-white, and consisted almost entirely of silt-sized endogenic calcite (CaCO3>70%) and intact and broken mollusc shells. Here we compare the faunal composition of the thanatocoenosis with recent mollusc associations in Lake Ohrid. A total of 13 mollusc species (9 gastropod and 4 bivalve species) could be identified within Lithofacies III sediments. The value of sediment core fossils for reconstructing palaeoenvironmental settings was evaluated and the agreement between sediment and palaeontological proxies was tested. The study also aims at investigating major faunal changes since the Last Interglacial and searching for signs of extinction events. The combined findings of the ecological study and the sediment characteristics suggest deposition in a shallow water environment during the Last Interglacial. The fossil fauna exclusively included species also found in the present fauna, i.e. no extinction events are evident for this site since the Last Interglacial. The thanatocoenosis showed the highest similarity with recent Intermediate Layer (5-25 m water depth) mollusc assemblages. The demonstrated existence of a mollusc fossil record in Lake Ohrid sediment cores also has great significance for future

  11. Exploring the use of paleomagnetic secular variations to date young sediments from the hardwater lake Tangra Yumco (Tibet)

    NASA Astrophysics Data System (ADS)

    Haberzettl, T.; Kasper, T.; Long, H.; Su, Y.; Ahlborn, M.; Appel, E.; Daut, G.; Henkel, K.; St-Onge, G.; Wang, J.; Zhu, L.; Maeusbacher, R.

    2013-12-01

    Magnetostratigraphy has been serving as a valuable tool for dating and confirming chronologies of lacustrine sediments. Although the coverage of suitable paleomagnetic records on the Tibetan Plateau (TP) and around has been extremely scarce, recently emerging records enable a validation of existing age-depth models using magnetostratigraphy. This is very important, since almost all radiocarbon ages obtained from lacustrine sediments on the TP are affected by a reservoir effect. For example at Nam Co (co = lake) on the eastern TP the chronology for the past 4 ka cal BP was supported by the comparison of paleomagnetic secular variation (PSV) and results from spherical harmonic geomagnetic field models. In addition, this approach was confirmed by comparison of the directional data of Nam Co to a varved record from the Makran accretionary wedge which is much further to the south-west but shows remarkable similarities. Here we present PSV data from multiple sediment cores from lake Tangra Yumco, located ~400 km west of Nam Co. Inclination and declination data from the different sediment cores are very similar, but only one core has been sufficiently dated yet. Unfortunately, validation of the reservoir corrected radiocarbon based age scale from this core is very poor although it contains one age from a part of wood (which because of its terrestrial nature was not reservoir corrected). On this chronology, the Tangra Yumco PSV data shows neither similarities with the Nam Co record, nor with geomagnetic field model outputs. Interestingly, if the chronology from Tangra Yumco is tuned to the chronology of the validated Nam Co record using inclination data, the minerogenic input proxies become almost identical. The minerogenic input is indicative of runoff and hence hydrological variations due to changes in the monsoon strength. Very similar hydrological variations can also be observed in the independently-dated Hongyuan peat bog (further to the north-east) which suggests

  12. Dating sediment in a fast sedimentation reservoir using 137Cs and 210Pb

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Over 10,000 reservoirs have been constructed in agricultural watersheds in the United States since the 1940s to control floods and sediments. Reservoir sedimentation records provide a unique opportunity to retrospectively study the effects of land use changes and climate variations on sediment produ...

  13. Anthropogenic stressors and changes in the Clear Lake ecosystem as recorded in sediment cores.

    PubMed

    Richerson, Peter J; Suchanek, Thomas H; Zierenberg, Robert A; Osleger, David A; Heyvaert, Alan C; Slotton, Darell G; Eagles-Smith, Collin A; Vaughn, Charles E

    2008-12-01

    Sediment cores were collected to investigate multiple stresses on Clear Lake, California, USA, through the period of European occupation to the present day. Earlier workers suggested the hypothesis that the use of mechanized earthmoving equipment, starting in the 1920s and 1930s, was responsible for erosion, mercury (Hg) contamination, and habitat loss stresses. Cores (approximately 2.5 m in depth) were collected in 1996 and 2000 from each of the three arms of the lake. Carbon-14 dating suggests that these cores represent as much as 3000 years of the lake's history, beginning long before European settlement. Total mercury (TotHg) and methylmercury (MeHg), dry matter, water, carbon, nitrogen, phosphorus, sulfur, and the stable isotopes 13C and 15N were measured at 5-cm intervals. Nearly all parameters show major changes at depths of 58-135 cm, beginning at ca. 1927 (dated with 210Pb). Accepting this date for concomitant major changes in seven cores yields an estimated 8.6 mm/yr average sedimentation rate after 1927. Pre-1927 sedimentation rates were approximately 1 mm/yr. Total mercury and MeHg, dry matter, phosphorus, and 15N increase significantly, whereas nitrogen, sulfur, carbon, and water content decrease significantly above the 1927 horizon. Both TotHg and MeHg show extremely large increases (roughly 10-fold) above the 1927 horizon. A peak in inorganic deposition rate and minimum values for percentage of water is present at depths corresponding to ca. 1970. Interestingly, the first 75 years of European settlement in the Clear Lake basin (including the most productive years of the Sulphur Bank Mercury Mine) appeared to have had undetectable effects on lake cores. Changes since 1927 were dramatic. The large increase in Hg beginning about 1927 corresponds to the use of heavy equipment to exploit the ore deposit at the mine using open-pit methods. Increases in sediment deposition from increased earthmoving in the basin and sulfate loading from the mine are the

  14. Climatic fluctuations during the Holocene based on eastern Mediterranean continental shelf sediment cores

    NASA Astrophysics Data System (ADS)

    Mor-Federman, Tsofit; Bookman, Revital; Almogi-Labin, Ahuva; Herut, Barak

    2013-04-01

    Sediments deposited on the south eastern Mediterranean continental shelf are sensitive recorders of climatic and oceanographic variability affected by the north Atlantic and indirectly by monsoonal systems. In order to reconstruct the influence of these climatic systems two cores were taken off shore the southern and central Israeli coast at water depths of ~35 m. The sediments were characterized by majors and traces elements, and the sediment provenance was determined using 87Sr/86Sr ratios. Detrital input from the Nile and local environment was studied using grain size distribution and sedimentation rates. Water column productivity was inferred by TOC and δ13Corg. The cores, dated to 7,630 and 8,440 14C years BP, show two distinct sedimentation regimes. The early Holocene is characterized by high sedimentation rates (190-140 cm/ka) that decrease in the last 5,500 years (50-60 cm/ka) in both north and central cores. Coarse grain size is dominant in the early Holocene, with a decreasing trend in the northern core. This distribution is probably connected to eustatic sea level rise and recycling of coarse sediments from the flooded shallow Nile cone. In the late Holocene, as sea level stabilized, grain size is finer in the south; while to the north, cycles of ~1,500 years in coarse grain size characterize the period. Carbonate and organic carbon further present the change along the period. Decrease in carbonate content and increase in δ13Corg during the late Holocene indicate decrease in water column productivity. In contradiction, organic carbon is relatively high in the late Holocene. This is explained by the coarse sediment texture in the early Holocene leading to better oxidation of buried organic matter. Strontium isotopes show changes in sediment provenance. In the early Holocene high 87Sr/86Sr values of ~0.71 reflect a dominant signature of the White Nile and the Yellow Nile and in part the local streams. During the last 5,500 years lower values of ~0

  15. Paleomagnetic chronology of Arctic Ocean sediment cores; reversals and excursions the conundrum

    NASA Astrophysics Data System (ADS)

    Løvlie, R.; Jakobsson, M.; Backman, J.

    2003-04-01

    Chronologies of Arctic Ocean sediment cores are mainly based on interpretation of paleomagnetic inclination records. The first paleomagnetic chronology assigned zones with negative inclinations to polarity reversals (Steuerwald et al, 1968) because geomagnetic excursions at that time were a novel observation and had only been reported from lavas. Arctic Ocean sedimentation rates were thus established to be in the mm/ka-range. A general recognition of excursions as real features of the geomagnetic field emerged more than three decades later, and presently there is still no consensus regarding the number (or name), duration and age of global synchronous excursions within the Brunhes Chron. Assigning inclination records to polarity reversals or excursions is an ambiguous exercise without independent age information. Based on independently derived time frames, 11 negative inclination intervals in core 96/12-1pc from the Lomonosov Ridge were assigned to reported excursions resulting in cm/ka deposition rates (Jakobsson et al, 2000). However, the detail of the "excursional stratigraphy" in this core is problematic. The absence of two (three?) excursions in the upper 2 m of core (base MIS5) was tentatively suggested to reflect pDRM-erasing in this sandy part of the core, while the short extent of the inferred pre-Brunhes Matyuama Chron remains unaccounted for. We have recently retrieved a relative paleointensity record from a parallel core (96/B6-1pc) for alternative dating control and assessment of stratigraphic completeness and uniformity of deposition. This study indicated the presence of a hiatus of the order of 200 ka (Løvlie et al 2002). We present a paleointensity record from core 96/12-1pc and will address identification of depositional hiatuses and their significance in understanding the paleomagnetic record in Arctic Ocean cores. Steuerwald B.A., Clark D.L. and Andrew J.A., 1968. Magnetic stratigraphy and faunal patterns in Arctic Ocean sediments. Earth and

  16. Hard-water dynamics and their reservoir effects on radiocarbon dating of Lake Heihai sediments (NE Tibetan Plateau, Qinghai, China)

    NASA Astrophysics Data System (ADS)

    Lockot, Gregori; Hartmann, Kai; Wünnemann, Bernd; Ramisch, Arne; Diekmann, Bernhard

    2014-05-01

    Age determination of lake sediments with radiocarbon dating can always entail a perturbation with hard water. Atmospheric carbon (expressing the "real" ages) can be mixed with older carbon from allochthonous input (e.g. marl or limestone), causing an overestimation of 14C ages. The usual approach to eliminate this effect is to date living plants or shells to determine the modern offset in age. Subsequently, this offset is subtracted from 14C ages of a sediment core to attain hard water corrected ages. However, this approach assumes a constant hard water effect over the entire period under consideration, which generally is unlikely. Here we present a highly variable hard water effect through time determined from a combined chronology of two long sediment cores from Lake Heihai (NE Tibetan Plateau). The chronology is based on 20 14C AMS dates of Potamogeton spec. Based on the relation between 14C ages and the input of allochthonous carbonates as well as calculated sedimentation rates, we developed an age-depth-model that estimates the actual ages of the sediments and allows the quantification of hard water effect through time. As a result this model suggests a fluctuating hard water effect varying between 102 to 103 ka. Ages in the lower 3 meter of the core, which corresponds to late glacial times, strongly correlate with the input of dolomite (CaMg(CO3)2). The correlation suggests a strong linkage between the allochthonous input of old carbon and the variations in dating results. In this section, the estimated hard water effect shows its highest values. Results of XRD, grain size and pollen data confirm a shallow lake with high rates of detrital input. The Late Glacial - Holocene transition to warmer and wetter conditions is marked by prominent changes in the mineralogy of lacustrine carbonates and the composition of pollen taxa. During this time the lake constantly rose and increasingly buffered the influence of allochthonous carbonates. The episode is

  17. [Character and sources identification of heavy metals contamination in sediment from the core sediment in Nanshan Lake, the Zhalong wetland].

    PubMed

    Su, Dan; Zang, Shu-Ying; Ye, Hua-Xiang; Sun, Li; Jia, Xiao-Dan; Li, Miao

    2012-06-01

    NSH2 sediment core from Nanshan Lake in the south of Zhalong wetland was studied, which was a typical lake for both empolder and aquaculture. The vertical distributions of heavy metals (Hg, Cd, Pb, Cr, As, Mn, Ag, Cu, Co, Fe and Zn) were investigated. The method of principal component analysis (PCA) was adopted to apportion the sources of heavy metals, and particle size, combined with 210Pb(ex) dating data were used to indicate characteristics, sources and polluted history of heavy metals in lake sediments since 1829. The results showed that: 1) the trend of changes in accumulation in the sedimentation was rather slow in the earlier stage, then was fast in the middle stage, and finally slowed down again in the later stage. The history of elements pollution is correspondent with the production of human activities and policies of soil and water conservation of Nanshan Lake; 2) the contents of all elements varied smoothly before 1957, and which fluctuated slightly from 1957 to 1985. The contents of Hg, Cd and Ag increased obviously since 1985. The sources of heavy metals determined were mainly from sewage, the loss of fertilizers, and combustion of fuel such as coal and gasoline; 3) natural sources of the degradation of organic matter, rock weathering and erosion, as well as the source of industrial emissions, with the contributions of 50.14%, 19.90% and 10.32%, respectively. High potential risk of heavy metals existed in NSH2 sediment core. Hence, enough attention must be paid to the pollution control of lakes. Therefore, this study can provide basic data for help wetland ecological environment improvement in Zhalong wetland. PMID:22946160

  18. Snežna jama (Slovenia): Interdisciplinary dating of cave sediments and implication for landscape evolution

    PubMed Central

    Häuselmann, Philipp; Mihevc, Andrej; Pruner, Petr; Horáček, Ivan; Čermák, Stanislav; Hercman, Helena; Sahy, Diana; Fiebig, Markus; Hajna, Nadja Zupan; Bosák, Pavel

    2015-01-01

    Caves are important markers of surface evolution, since they are, as a general rule, linked with ancient valley bottoms by their springs. However, caves can only be dated indirectly by means of the sediments they contain. If the sediment is older than common dating methods, one has to use multiple dating approaches in order to get meaningful results. U/Th dating, palaeomagnetic analysis of flowstone and sediment profiles, cosmogenic dating of quartz pebbles, and mammalian dating allowed a robust estimate of speleogenesis, sediment deposition, climatic change at the surface, and uplift history on the Periadriatic fault line during the Plio-Pleistocene. Our dates indicate that Snežna jama was formed in the (Upper) Miocene, received its sedimentary deposits during the Pliocene in a rather low-lying, hilly landscape, and became inactive due to uplift along the Periadriatic and Sava faults and climatic changes at the beginning of the Quaternary. Although it is only a single cave, the information contained within it makes it an important site of the Southern Alps. PMID:26516294

  19. Snežna jama (Slovenia): Interdisciplinary dating of cave sediments and implication for landscape evolution

    NASA Astrophysics Data System (ADS)

    Häuselmann, Philipp; Mihevc, Andrej; Pruner, Petr; Horáček, Ivan; Čermák, Stanislav; Hercman, Helena; Sahy, Diana; Fiebig, Markus; Hajna, Nadja Zupan; Bosák, Pavel

    2015-10-01

    Caves are important markers of surface evolution, since they are, as a general rule, linked with ancient valley bottoms by their springs. However, caves can only be dated indirectly by means of the sediments they contain. If the sediment is older than common dating methods, one has to use multiple dating approaches in order to get meaningful results. U/Th dating, palaeomagnetic analysis of flowstone and sediment profiles, cosmogenic dating of quartz pebbles, and mammalian dating allowed a robust estimate of speleogenesis, sediment deposition, climatic change at the surface, and uplift history on the Periadriatic fault line during the Plio-Pleistocene. Our dates indicate that Snežna jama was formed in the (Upper) Miocene, received its sedimentary deposits during the Pliocene in a rather low-lying, hilly landscape, and became inactive due to uplift along the Periadriatic and Sava faults and climatic changes at the beginning of the Quaternary. Although it is only a single cave, the information contained within it makes it an important site of the Southern Alps.

  20. Geochemical studies of backfill aggregates, lake sediment cores and the Hueco Bolson Aquifer

    NASA Astrophysics Data System (ADS)

    Thapalia, Anita

    This dissertation comprises of three different researches that focuses on the application of geochemistry from aggregates, lake sediment cores and Hueco Bolson Aquifer. Each study is independent and presented in the publication format. The first chapter is already published and the second chapter is in revision phase. Overall, three studies measure the large scale (field) as well as bench scale (lab) water-rock interactions influenced by the climatic and anthropogenic factors spans from the field of environmental geology to civil engineering. The first chapter of this dissertation addresses the chemical evaluation of coarse aggregates from six different quarries in Texas. The goal of this work is to find out the best geochemical methods for assessing the corrosion potential of coarse aggregates prior to their use in mechanically stabilized earth walls. Electrochemical parameters help to define the corrosion potential of aggregates following two different leaching protocols. Testing the coarse and fine aggregates demonstrate the chemical difference due to size-related kinetic leaching effects. Field fines also show different chemistry than the bulk rock indicating the weathering impact on carbonate rocks. The second chapter investigates zinc (Zn) isotopic signatures from eight lake sediment cores collected both from pristine lakes and those impacted by urban anthropogenic contamination. Zinc from the natural weathering of rocks and anthropogenic atmospheric pollutants are transported to these lakes and the signatures are recorded in the sediments. Isotopic analysis of core samples provides the signature of anthropogenic contamination sources. Dated sediment core and isotopic analysis can identify Zn inputs that are correlated to the landuse and population change of the watersheds. Comparison of isotopic data from both pristine and urban lake sediment core also serves as an analog in other lake sediment cores in the world. The third chapter studies on Hueco Bolson

  1. LacCore: Support for the terrestrial sediment core research community

    NASA Astrophysics Data System (ADS)

    Brady, K. L.; Noren, A. J.; Myrbo, A.; Ito, E.

    2009-12-01

    LacCore, the National Lacustrine Core Facility, has been funded by the US National Science Foundation and the University of Minnesota for the past decade as a public facility to support the terrestrial sediment core research community. LacCore provides free or low-cost access to an array of expensive equipment and instrumentation in the field and lab, training for a variety of procedures, and core and data curation. The user base has increased from perhaps 20 users and a handful of projects in the first year to 621 users and 250 projects in 2008. The community served is diverse, with topics including invasive species, eutrophication, salinization, tectonics, geomicrobiology, evolutionary biology, isostatic rebound, stream bank erosion, glaciology, hydrogeology, atmospheric chemistry, carbon cycling, and rock magnetics, as well as paleoenvironment and paleoclimate. The changing needs of projects drive innovation in procedures and equipment, all of which become available to subsequent researchers. Among the newest additions to the lab is a benchtop scanning electron microscope with electron-dispersive x-ray spectrometry (SEM-EDX or -EDS) capability for sediment characterization. This instrument allows rapid imaging of sedimentary components and determination of their elemental composition without substantial sample preparation, lead time, or user training. These images and data augment the initial core description process, filling a void between existing smear slide and scanning micro XRF capabilities.

  2. Sediment magnetic, paleomagnetic, and geochemical data from Quaternary lacustrine sediment in a core from Grass Lake, Siskiyou County, California

    USGS Publications Warehouse

    Best, Patti J.; Reynolds, Richard L.; Rosenbaum, Joseph G.; Drexler, John W.; Adam, David P.

    1996-01-01

    Sediment magnetic and geochemical results have been obtained from the top 60 meters of lacustrine sediments recovered in two cores from Tule Lake in northern California. The sediment magnetic and geochemical data, presented here in tabular form, complement studies of diatoms and pollen in the cores that are the bases for published paleoclimatic interpretations. This report also documents the methods used to obtain the magnetic properties and geochemical data.

  3. Sediment magnetic and geochemical data from Quaternary lacustine sediment in two cores from Tule Lake, Siskiyou County, California

    USGS Publications Warehouse

    Best, Patti J.; Reynolds, Richard L.; Rosenbaum, Joseph G.; Dean, Walter E.; Honey, Jeannine; Drexler, John W.; Adam, David P.

    1996-01-01

    Sediment magnetic and geochemical results have been obtained from the top 60 meters of lacustrine sediments recovered in two cores from Tule Lake in northern California. The sediment magnetic and geochemical data, presented here in tabular form, complement studies of diatoms and pollen in the cores that are the bases for published paleoclimatic interpretations. This report also documents the methods used to obtain the magnetic properties and geochemical data.

  4. Dating of the time of sedimentation using U-Pb ages for paleosol calcite

    SciTech Connect

    Rasbury, E.T.; Hanson, G.N.; Meyers, W.J.

    1997-04-01

    We have sampled paleosol horizons from a continuous core of a rapidly deposited Late Pennsylvanian-Early Permian marine shelf section in Texas. USA. The paleosols occur on the tops of shoaling upward cycles and, based on current time constraints, these cycles average 250 ka and cannot represent longer than 400 ka. As the unconformity which is represented by the paleosol can only be a fraction of the time allowed for deposition of the cycle, the age of minerals that form in the paleosol is effectively the time of sedimentation. The uncertainty on the {sup 238}U-{sup 206}Pb age of brown paleosol calcite from one exposure surface is only 1 Ma. Reported uncertainties on Paleozoic boundaries are greater than 10 Ma. Our early results suggest that the marine sedimentary record may be dated to a precision of 1 Ma with U-Pb analyses of carefully selected paleosol calcite. These results have implications for vastly improving time resolution of the rock record. 21 refs., 3 figs., 1 tab.

  5. Recent sediment remolding on a deep shelf, Ross Sea: implications for radiocarbon dating of Antarctic marine sediments

    NASA Astrophysics Data System (ADS)

    Domack, Eugene W.; Taviani, Marco; Rodriguez, Anthonio

    1999-11-01

    Coarse, bioclastic rich sands have been widely reported from the banks of the Antarctic continental shelf but their origin is still poorly known. We report on a suite of coarse sediments recovered from the top of the Mawson Bank in the northwestern Ross Sea. Radiocarbon ages of biogenic calcite, for modern and apparently late Pleistocene deposits, range from 1085±45 to 20,895±250 yr B.P.. Discovery of soft tissue (Ascidian) preserved as an incrustation on a pebble at 2 m depth indicates aggregation of the sediment within several months or a year of core recovery. Radiocarbon ages of acid insoluble organic matter (aiom) are less than those of the foraminifera calcite. The aiom ages are also reversed in sequence, indicating reworking of the sediment during deposition. These observations and a review of recently published literature suggest that much of the bank top sediment in Antarctica is presently undergoing remobilization, under the influence of strong currents and/or icebergs even under interglacical (high-stand) sea levels. These observations point out the need for careful, integrated studies on high latitude marine sediment cores before resultant "ages" alone are used as the foundation for paleoglacial reconstructions.

  6. OSL dating as a possible tool for provenance study of fine grained quartz/polymineral from Lake Suigetsu sediments

    NASA Astrophysics Data System (ADS)

    Sugisaki, S.; Murray, A. S.; Buylaert, J.; Tada, R.; Suzuki, Y.; Nagashima, K.; Schwenninger, J.; Haraguchi, T.; Gotanda, K.; Nakagawa, T.

    2013-12-01

    Lake Suigetsu in central Japan is known for its unusually well-developed sequence of varved sediments. These were first drilled in 1993 (SG93), and in the second attempt in 2006 the first complete sediment profile (SG06) was successfully recovered (Nakagawa et al. 2012). Several dating methods including varve counting, radiocarbon dating, tephrochronology have been applied to the sediments and a robust age model developed that covers the last ~70 kyr (Bronk Ramsey et al., 2012, Staff et al., 2013). OSL dating has the potential to extend this age range beyond 70ka, a period in which other dating methods have of limited applicability. Since reliable OSL dating requires the dosimeter to be reset by exposure to sunlight before deposition, we have tried to identify the lithology that is dominated by well-reset sediment such as aeolian dust; this is most likely to be the most suitable material for OSL dating. During 2012, Lake Suigetsu was re-drilled and cores from the fourth hole were extruded under orange light to avoid loss of OSL signal. We started our study by selecting sections 2 and 5, taken from intervals corresponding to the late Holocene (499 × 8-837 ×13 SG06 2012 yr BP and 2653 × 40-3173 ×29 SG06 2012 yr BP, respectively, based on the SG06 age model). The sediments of late Holocene Lake Suigetsu are classified into 3 lithological types: 1) faintly laminated (varves) olive gray to dark gray clay; 2) light gray homogeneous clay; and 3) olive gray-reddish brown graded silty clay to clay . Layer types 2) and 3) are generally thicker than varves. Unfortunately, sediments in sections 2 and 5 are weakly to moderately mixed and preservation of lamination is generally poor. As a result it is sometimes difficult to identify the three types of lithologies. 18 samples were taken from sediments representing an olive gray to dark gray layer (probably corresponding to type 1) and from types 2 and 3 (presumed event layers). Quartz and polymineral material in the 4-11

  7. Time trends of polybrominated diphenyl ethers in sediment cores from the Pearl River Estuary, South China.

    PubMed

    Chen, She-Jun; Luo, Xiao-Jun; Lin, Zhen; Luo, Yong; Li, Ke-Chang; Peng, Xian-Zhi; Mai, Bi-Xian; Ran, Yong; Zeng, Eddy Y

    2007-08-15

    The present study provides information on the time trend of PBDEs in three sediment cores from the Pearl River Estuary (PRE), South China, using 210Pb dating technique. The sigmaPBDEs (except for BDE 209) concentrations in all sediment cores increased gradually from the bottom (mid-1970s) to the middle layer (later 1980s and early 1990s) followed by different temporal trends in different locations to the surface sediments, reflecting the variations in the consumption of commercial penta-BDEs mixture in different regions of the Pearl River Delta. The BDE 209 concentrations remained constant until 1990 and thereafter increased exponentially to the present, with doubling times of 2.6 +/- 0.5-6.4 +/- 1.6 years, suggesting the increasing market demands for deca-BDE mixture after 1990 in China. The inventories of sigmaPBDEs and BDE 209 in sediments of the PRE were 56.0 and 368.2 ng cm(-2), respectively, and the total burden of PBDEs in the PRE were estimated at 8.6 metric tons. The current sigmaPBDEs and BDE 209 fluxes to the PRE were 2.1 and 29.7 ng cm(-2) yr(-1), respectively. The concurrent increase of BDE 209 fluxes and the annual gross industrial output values of electronics manufacturing revealed that the rapid growth of electronics manufacturing in this region since the early 1990s was responsible for the sharp rise of BDE 209 fluxes in the past decade. The PBDE congener compositions of the cores indicated the various input pathways for PBDEs transport to different locations of the estuary. PMID:17874760

  8. Thermoluminescence dating of sediments: a re-extension of age range for loess

    SciTech Connect

    Johnson, R.J.; Stipp, J.J.; Wintle, A.G.; Tamers, M.A.

    1985-01-01

    Thermoluminescence (TL) dating of wind blown minerals provides a technique whereby non-carbonaceous sediments could be dated to several hundred thousand years. Two recent reports, however, indicate age underestimates on feldspar in some European loesses older than 50 ka, the effect increasing in severity with age. Suggested causes include decay of luminescence centers, or does dependent sensitivity changes. Data presented in this paper do not support these limitations or explanations. TL provides 3 separate techniques of dating sediments, which, when used together, prove to be efficient internal cross checks for mineralogical anomalies or inconsistencies created by any of the individual methods. In the authors studies each sample was dated by all 3 methods whereas the Europeans analyses employed only the Regeneration technique. This work presents results from loess sections in Mississippi, Illinois and Alaska. These show excellent internal consistency, and consistency with both independent dating methods and stratigraphy, with 2 exceptions. Both exceptions were by the Regen technique giving age underestimates up to 30%. The underestimates were found to be caused by a change in mineral sensitivity resulting from the Regen requirements of strong laboratory light-bleaching followed by irradiations. A simple method to test and correct for this condition is presented. TL thus appears to remain a powerful and increasingly flexible method of sediment dating.

  9. Methodological issues and preliminary results from a combined sediment fingerprinting and radioisotope dating approach to explore changes in sediment sources with land-use change in the Brantian Catchment, Borneo.

    NASA Astrophysics Data System (ADS)

    Walsh, Rory; Higton, Sam; Marshall, Jake; Bidin, Kawi; Blake, William; Nainar, Anand

    2015-04-01

    This paper reports some methodological issues and early results of a project investigating the erosional impacts of land use changes (multiple selective logging and progressive, partial conversion to oil palm) over the last 25-40 years in the 600km2 Brantian river catchment in Sabah, Borneo. A combined sediment fingerprinting and radioisotope dating approach is being applied to sediment cores taken in stream hierarchical fashion across the intermediate catchment scale. Changes in sediment sources and sedimentation rates over time can be captured by changes in the relative importance of geochemical elements with depth in downstream sediment cores, which in turn can be linked to parallel changes in upstream cores by the application of unmixing models and statistical techniques. Radioisotope analysis of the sediment cores allows these changes to be dated and sedimentation rates to be estimated. Work in the neighbouring Segama catchment had successfully demonstrated the potential of such an approach in a rainforest environment (Walsh et al. 2011). The paper first describes steps taken to address methodological issues. The approach relies on taking continuous sediment cores which have aggraded progressively over time and remain relatively undisturbed and uncontaminated. This issue has been tackled (1) through careful core sampling site selection with a focus on lateral bench sites and (2) deployment of techniques such as repeat-measurement erosion bridge transects to assess the contemporary nature of sedimentation to validate (or reject) candidate sites. The issue of sediment storage and uncertainties over lag times has been minimised by focussing on sets of above- and below-confluence sites in the intermediate zone of the catchment, thus minimising sediment transit times between upstream contributing and downstream destination core sites. This focus on the intermediate zone was also driven by difficulties in finding suitable core sites in the mountainous headwaters

  10. Biogenic silica in Lake Baikal sediments: results from 1990-1992 American cores

    USGS Publications Warehouse

    Carter, Susan J.; Colman, Steven M.

    1994-01-01

    The Lake Baikal Paleoclimate Project is a joint Russian-American program established to study the paleoclimate of Central Asia. During three summer field seasons, duplicate Russian and American cores were taken at a number of sites in different sedimentary environments in the lake. Eight cores returned to the U.S. were quantitatively analyzed for biogenic silica using a single-step 5-hour alkaline leach, followed by dissolved silicon analysis by inductively-coupled-plasma atomic-emission spectroscopy. Sediments of Holocene age in these cores have biogenic silica maxima that range from about 15 to 80 percent. An underlying zone in each core with low biogenic-silica concentrations (0 to 5 percent) dates from the last glacial maximum. The transition from the last glaciation to the present interglaciation, recorded by biogenic silica, began about 13,000 years ago. Biogenic silica profiles from these cores appear to be a good measure of past diatom productivity and a useful basis for paleoclimatic interpretations.

  11. Chlorine-36 dating of saline sediments: Preliminary results from Searles Lake, California

    USGS Publications Warehouse

    Phillips, F.M.; Smith, G.I.; Bentley, H.W.; Elmore, D.; Gove, H.E.

    1983-01-01

    Measurements have been made of the ratios of chlorine-36 to chlorine in five halite samples from Searles Lake sediments, previously dated by carbon-14, thorium-230, and magnetostratigraphic techniques. The ages calculated from the chlorine ratios are generally concordant with those from the other methods, implying the constancy of the chlorine input ratio over the last million years.

  12. Concepts and approaches to in situ luminescence dating of Martian sediments.

    PubMed

    McKeever, S W S; Banerjee, D; Blair, M; Clifford, S M; Clowdsley, M S; Kim, S S; Lamothe, M; Lepper, K; Leuschen, M; McKeever, K J; Prather, M; Rowland, A; Reust, D; Sears, D W G; Wilson, J W

    2003-01-01

    In this paper we present the concept of a robotic instrument for in situ luminescence dating of near-surface sediments on Mars. The scientific objectives and advantages to be gained from the development of such an instrument are described, and the challenges presented by the Mars surface environment to the design and operation of the instrument are outlined. PMID:12856693

  13. Paleomagnetic Study of Marine Sediment Core OR715-21 from Eastern Offshore of Taiwan

    NASA Astrophysics Data System (ADS)

    Lee, T.; Wei, K.; Huh, C.

    2009-12-01

    This study presents paleomagnetic secular variation results of a marine sediment core, named as OR715-21, taken from eastern offshore of Taiwan (121.5°E, 22.7°N, water depth 760 m). The total recovered length is 1.87 meters. Sediments in the core mainly consist of gray clay and silt. Planktonic foraminiferal shells (>250 μm, >6 mg, Globigerinoides spp. and Orbulina universa) were picked from six levels of the core and subjected to AMS 14C dating for constructing the age model. The results indicated that this core could support the information for the last 7000 years. The averaged sedimentation rate is estimated to be of about 26.5 cm/kyr. Psuedo-single domain (PSD) magnetite is identified as the most important magnetic carrier. Alternating field (AF) demagnetization was applied to treat the u-channel samples of the core. The median destructive field of the samples distributed between 15~25 mT. The characteristic remanent magnetization could be resolved after 20 mT cleaning. The paleo-declinations of the samples varied about ±200 around their mean and their paleo-inclinations varied between 300 and 500 . The variation pattern of the paleo-declination is somehow similar to the pattern compiled by Hyoto et al. (1993) based on the lake and marine sediment records from Japan except the varied amplitude is less between 4000 and 5000 yrB.P. Using NRM/ARM after 20 mT cleaning to simulate the paleo-intensity secular variation, our record shows that an increased trend began from 6500 yrB.P. to 3000 yrB.P., but decreased after. Magnetic proxies of this core indicate that 4 stages of environmental changes has happened in the area studied: (1) high magnetite abundance with relative low oxidized magnetic mineral contents occurred during ~6900 to 6200 yrB.P.; (2) a relative low abundance of magnetite with relative high oxidized magnetic minerals during ~6200 to ~5400 yrB.P.; (3) an abnormal low HIRM with relative higher ARM/SIRM could be found during the time period of ~5400

  14. Molecular Radiocarbon Dating of Tropical Lake Sediments: Insights into the Chronology of Leaf Wax Stable Isotope Records

    NASA Astrophysics Data System (ADS)

    Douglas, P. M.; Pagani, M.; Eglinton, T. I.; Brenner, M.; Curtis, J. H.; Hodell, D. A.

    2010-12-01

    Leaf wax δD and δ13C measurements in marine and lacustrine sediment cores are promising proxies for past climatic and environmental change. However, a number of studies of marine sediments indicate centennial to millennial scale offsets between the radiocarbon ages of leaf waxes and the age of surrounding sediments due to long-term storage of these lipids in soils. These offsets present a complication for the interpretation of leaf wax stable isotope records that has not been thoroughly addressed. We present leaf wax δD, δ13C and Δ14C values for a sediment core from Lake Chichancanab in southeastern Mexico. This lake was previously studied using mineralogical (gypsum) and carbonate isotopic (δ18O) climate proxies, which indicated a sequence of severe droughts from 750 to 1000 AD, coincident with the collapse of the Classic Maya civilization. A suite of leaf wax δD values was plotted against the original sediment core chronology, which was developed using radiocarbon dates on terrestrial macrofossils. The leaf wax results also indicated major hydrological variability over the past 3000 years, but were not temporally coherent with the other climate proxy records. Leaf wax radiocarbon ages are 400 to 1200 years older than terrestrial macrofossil radiocarbon ages from the same depths, suggesting that leaf waxes are retained in the watershed for extended periods prior to deposition in the lake. We fit a 2nd-order polynomial equation to the depth profile of leaf wax radiocarbon ages (r2 =0.99) and refit the leaf wax δD profile to this “leaf wax age model”. This approach yielded much greater coherence with mineralogical and carbonate isotopic proxy records, including evidence for a period of severe drought (35‰ D-enrichment) from 750 to 1000 A.D. Our results indicate that long-term storage of leaf waxes in drainage basin soils can lead to temporal inaccuracies in leaf wax stable isotope records. These inaccuracies, however, can be corrected using a

  15. Dating the upper Cenozoic sediments in Fisher Valley, southeastern Utah ( USA).

    USGS Publications Warehouse

    Colman, Steven M.; Choquette, Anne F.; Rosholt, J.M.; Miller, G.H.; Huntley, D.J.

    1986-01-01

    More than 140 m of upper Cenozoic basin-fill sediments were deposited and then deformed in Fisher Valley between about 2.5 and 0.25 m.y. ago, in response to uplift of the adjacent Onion Creek salt diapir. In addition to these basin-fill sediments, minor amounts of eolian and fluvial sand were depositd in Holocene time. The sediments, whose relative ages are known from the stratigraphy, are predominantly sandy, second-cycle red beds derived from nearby Mesozoic rocks; most were deposited in a vertical sequence, filling a sedimentary basin now exposed by fluvial dissection. We have applied a variety of established and experimental dating methods to the sediments in Fisher Valley to establish their age and to provide time control for the recent history of the Onion Creek salt diapir.-from Authors

  16. Geochemical assessment of metal pollution and ecotoxicology in sediment cores along Karachi Coast, Pakistan.

    PubMed

    Mashiatullah, Azhar; Chaudhary, Muhammad Zaman; Ahmad, Nasir; Ahmad, Nisar; Javed, Tariq; Ghaffar, Abdul

    2015-05-01

    This paper is an attempt to compare the pollution status in two sediment cores, one from a polluted site (Ghizri Creek) and another from a relatively unpolluted site (Sandspit). Sediment cores (45 cm in length) from coastal locations were characterized in terms of grain size, sediment composition, pH, organic matter, calcium carbonate, and metal element contents. Metal elements, including Al, Ca, Cr, Co Cu, Fe, K, Mg, Mn, Ni, Pb, V, Ti, and Zn, were determined using PIXE. Grain size analysis and sediment composition demonstrated a sandy nature of both cores. Acidic trend in sediment core I was predominant from bottom to top, whereas neutral pH was observed throughout core II. TOC values varied in the range of 1.23-2.68 and 1.14-2.60% in core I and core II, respectively; however, there was an increasing trend in TOC level from bottom to top. The values of enrichment factor for Zn, Cu, Co, Ni, Pb, and Cr were slightly higher in core I than core II. The average geo-accumulation index values for core I and core II showed that sediments were moderately Co- and Pb-polluted but not polluted with Mg, Al, Ca, K, Cr, Cu, Fe, Mn, Ni, Ti, V, and Zn. The degree of contamination was however considerably higher in core I relative to core II. The pollution load index values, although showing an increasing trend from bottom to top in both cores, overall rendered the marine sediment pollution free. The metal toxicology results demonstrated that heavy metal pollution, except Cr, may pose low to moderate risk to marine biota. The sum of toxic unit values however indicated that sediment core I was relatively more polluted than that of core II. PMID:25869090

  17. Mono Lake Excursion in Cored Sediment from the Eastern Tyrrhenian Sea

    NASA Astrophysics Data System (ADS)

    Liddicoat, Joseph; Iorio, Marina; Sagnotti, Leonardo; Incoronato, Alberto

    2013-04-01

    A search for the Laschamp and Mono Lake excursions in cored marine and lacustrine sediment younger than 50,000 years resulted in the discovery of both excursions in the Greenland Sea (73.3˚ N, 351.0˚ E, Nowaczyk and Antanow, 1997), in the North Atlantic Ocean (62.7˚ N, 222.5˚ E, Channell, 2006), in Pyramid Lake in the Lahontan Basin, NV, USA (40.1˚ N, 240.2˚ E, Benson et al., 2008), and in the Black Sea (43.2˚ N, 36.5˚ E, Nowaczyk et al., 2012). The inclination, declination, and relative field intensity during the Mono Lake Excursion (MLE) in the Black Sea sediment matches well the behaviour of the excursion in the Mono Basin, CA, in that a reduction in inclination during westerly declination is soon followed by steep positive inclination when declination is easterly, and relative field intensity increases after a low at the commencement of the excursion (Liddicoat and Coe, 1979). A large clockwise loop of Virtual Geomagnetic Poles (VGPs) at the Black Sea when followed from old to young patterns very well the VGP loop formed by the older portion of the MLE in the Mono Basin (Liddicoat and Coe, 1979). We also searched for the MLE in cored sediment from the eastern Tyrrhenian Sea (40.1˚ N, 14.7˚ E) where the age of the sediment is believed to be about 32,000 years when comparing the susceptibility in the core with the susceptibility in a nearby one that is dated by palaeomagnetic secular variation records, Carbon-14, and numerous tephra layers in the Tyrrhenian Sea sediment (Iorio et al., 2011). In the Tyrrhenian Sea core, called C1067, closely spaced samples demagnetized in an alternating field to100 mT record a shallowing of positive inclination to 48˚ that is followed by steep positive inclination of 82˚ when declination moves rapidly to the southeast. The old to young path of the VGPs in C1067 forms a narrow counter-clockwise loop that reaches 30.3˚ N, 30.8˚ E and that is centered at about 55˚ N, 15˚ E. Although descending to a latitude that is

  18. Distribution and partitioning of heavy metals in estuarine sediment cores and implications for the use of sediment quality standards

    NASA Astrophysics Data System (ADS)

    Spencer, K. L.; MacLeod, C. L.

    Total metal concentrations in surface sediments and historically contaminated sediments were determined in sediment cores collected from three estuaries (Thames, Medway and Blackwater) in south-east England. The partitioning behaviour of metals in these sediments was also determined using a sequential extraction scheme. These data were then compared with sediment quality values (SQVs) to determine the potential ecotoxicological risk to sediment dwelling organisms. When total metal concentrations in surface sediments are examined, no risk to biota in any of the estuaries is indicated. However, when historically contaminated sediments at depth are also considered, risks to biota are apparent and are greatest for the Thames, followed by the Medway and then the Blackwater. This suggests that regulatory authorities should examine vertical metal profiles, particularly in estuaries that are experiencing low sediment accumulation rates where historically contaminated sediments are in the shallow sub-surface zone and where erosion or dredging activities may take place. When metal partitioning characteristics are also considered, the risk to biota is comparable for the Medway and the Blackwater with the potentially bioavailable fraction presenting no ecotoxicological risk. Conversely, over 70% of metals are labile in the Thames Estuary sediments and toxic effects are probable. This suggests that the application of SQVs using total sediment metal concentrations may over- or under-estimate the risk to biota in geochemically dissimilar estuarine sediments.

  19. Dating of the oldest continental sediments from the Himalayan foreland basin.

    PubMed

    Najman, Y; Pringle, M; Godin, L; Oliver, G

    2001-03-01

    A detailed knowledge of Himalayan development is important for our wider understanding of several global processes, ranging from models of plateau uplift to changes in oceanic chemistry and climate. Continental sediments 55 Myr old found in a foreland basin in Pakistan are, by more than 20 Myr, the oldest deposits thought to have been eroded from the Himalayan metamorphic mountain belt. This constraint on when erosion began has influenced models of the timing and diachrony of the India-Eurasia collision, timing and mechanisms of exhumation and uplift, as well as our general understanding of foreland basin dynamics. But the depositional age of these basin sediments was based on biostratigraphy from four intercalated marl units. Here we present dates of 257 detrital grains of white mica from this succession, using the 40Ar-39Ar method, and find that the largest concentration of ages are at 36-40 Myr. These dates are incompatible with the biostratigraphy unless the mineral ages have been reset, a possibility that we reject on the basis of a number of lines of evidence. A more detailed mapping of this formation suggests that the marl units are structurally intercalated with the continental sediments and accordingly that biostratigraphy cannot be used to date the clastic succession. The oldest continental foreland basin sediments containing metamorphic detritus eroded from the Himalaya orogeny therefore seem to be at least 15-20 Myr younger than previously believed, and models based on the older age must be re-evaluated. PMID:11242076

  20. Submerged terrestrial landscapes in the Baltic Sea: Evidence from multiproxy analyses of sediment cores from Fehmarnbelt

    NASA Astrophysics Data System (ADS)

    Enters, Dirk; Wolters, Steffen; Blume, Katharina; Segschneider, Martin; Lücke, Andreas; Theuerkauf, Martin; Hübener, Thomas

    2016-04-01

    Five sediment cores were taken from the southern part of the Fehmarn Belt (Baltic Sea) in the context of an environmental impact study for the intended fixed traverse between Germany and Denmark. The lithologies of the 8m long cores reveal dramatic changes in sedimentary environments which reflect the early Holocene history of the southern Baltic Sea. A succession of terrestrial, semiterrestrial and limnic facies from glacial sediments to peat, lacustrine/estuarine deposits and finally marine sediments document the interplay of eustatic sea level rise and isostatic rebound, which finally lead to the establishment of marine conditions during the Littorina transgression. An age control of the observed changes was established by dating over 50 C-14 samples of different fractions. During the Lateglacial minerogenic varves with thicknesses of several centimeters verify the existence of a proglacial lake in the Fehmarnbelt. Peat development started around 11.250 cal. BP and terminated ca. 10.600 cal. BP which is roughly contemporaneous with the end of the Yoldia Phase in the central Baltic Sea. The oldest peat layers consist of undecomposed sedges and reed. Woody remains of willows appear not before 10.700 cal BP and indicate a stagnant or slowly decreasing water table. This semi-terrestrial phase is followed by a shallow inland lake which existed until the Littorina transgression around 8.300 cal. BP. Initially the lacustrine sediments exhibit high C/N ratios, low low δ13Corg values and contain numerous wood fragments as well as other botanical macro remains. This indicates shallow conditions close to the lake shore. Later, the occurrence of planktonic diatom species such as Aulacoseira ambigua suggest greater water depths. We did not find any indications of the often postulated catastrophic outburst of the Ancylus Lake via Fehmarnbelt and the Great Belt into the North Sea. Likewise, XRF scanning does not show conspicuous peaks in Ti or K which would have been

  1. Radioactive dating: Studies on ground water and sediments. (Latest citations from the Selected Water Resources Abstracts database). Published Search

    SciTech Connect

    Not Available

    1994-10-01

    The bibliography contains citations concerning radioactive dating of ground water and sediments. Articles discuss ground water movement and recharge; and lake, marine, and glacial sediments. Citations address dating techniques using isotopes of carbon, lead, uranium, radium, and tritium. Studies on sedimentation rate, water quality, aquifer characteristics, geological survey, and glacial history are presented. (Contains a minimum of 103 citations and includes a subject term index and title list.)

  2. Vertical distribution and indications of lipids biomarkers in the sediment core from East China Sea

    NASA Astrophysics Data System (ADS)

    Wang, Rui; Wang, Jiangtao; Li, Feng; Yang, Shu; Tan, Liju

    2016-07-01

    To study the distribution and indications of lipids biomarkers in the mud areas of the East China Sea shelf, a sediment core was collected. Lipids were determined to find the origination of different organic matter (fatty acids and sterols) inputs. The results demonstrated that the distribution of fatty acids and sterols indicated the organic matter derived from the mixed allochthonous and autochthonous sources, but mainly autochthonous. The total fatty acids concentrations ranged from 29.08 μg g-1 to 303.92 μg g-1 and exhibited unimodal distribution with the predominance of C16-fatty acid. Neutral lipid concentrations ranged from 1.77 μg g-1 to 4.65 μg g-1. Furthermore, the distribution patterns of sterols varied with depth, and were dominated by C27-sterol and C29-sterol in the top and bottom sediments respectively. Although bacterial lipids were recruited during diagenesis, the refractory terrestrial lipids were usually preferentially preserved. This records dated from the 1980s suggested that the phytoplankton community was mainly influenced by eutrophication in the East China Sea and this variation may be recorded by lipid biomarkers deposited in the sediment.

  3. Tracing metal sources in core sediments of the artificial lake An-Dong, Korea: Concentration and metal association.

    PubMed

    Choi, Mansik; Park, Jongkyu; Cho, Dongjin; Jang, Dongjun; Kim, Miseon; Choi, Jongwoo

    2015-09-15

    The concentration and source of trace metals in the artificial lake An-Dong, which has widespread abandoned mines and a Zn smelter upstream of the drainage basin, were investigated. Soils (18ea), stream waters (15ea) and sediments (15ea) in the main channel and five tributaries downstream of the Zn smelter towards the lake (~ 50 km downstream) were collected. And two core sediments were also taken from the middle of the lake. All samples were analyzed for trace metals in bulk and in a 1N HCl-leached fraction. Although the soil and stream sediments consisted mostly of sand-sized grains, concentrations of metals (Cu, Zn, Cd and Pb) were very high in all samples, including soils, stream waters and sediments at sites near the Zn smelter. However the metal concentrations decreased rapidly downstream, suggesting that the area of impact of the smelter lies within 5 km. Highly enriched metal concentrations were also found in dated core sediments from the lake; while the highest concentrations of Co, Ni, As, Cu, Zn, Cd and Pb were detected in the bottom of the sediment core (dated 1980) they decreased towards 2000, and only Cu, Zn and Cd concentrations increased again in present-day samples. Since the temporal variation in metal concentrations appeared consistent with historical variation in ore mining and Zn smelter production rates, a model combining the production rates of each was developed, which estimated 3%, 12% and 7% contributions from Zn smelter compared to ore mining production rate to levels of Cu, Cd and Zn, respectively, suggesting the different pathways by different sources. In addition, analysis of Cd/Zn and Cu/Zn ratios showed that contamination from ore mining decreased from 1980 to 2000, and smelting processes were most likely responsible for metal enrichment (Cu, Cd and Zn) from 2000 to the present. PMID:25981937

  4. Preliminary Results of a Multi-Proxy Lake Sediment Core Study in East-Central France

    NASA Astrophysics Data System (ADS)

    Misner, T.; Meyers, S.; Rosenmeier, M.; Strano, S.; Straffin, E.

    2008-12-01

    This paper presents the preliminary results of a multi-proxy study of natural and human-induced changes in the Burgundian environment, as recorded in the sediment geochemistry of three small freshwater basins within the Arroux River Valley, east-central France. Accelerator mass spectrometry radiocarbon dates constrain the age of core material collected from the basins, and indicate that these mill and farm ponds were constructed by at least 1200 A.D. The pond sediments are predominantly massive, organic-rich muds that contain discrete sand and gravel lenses likely related to episodic flooding and/or basin drainage. In this study, continuous X-ray fluorescence (XRF) scanning is used to quantify bulk geochemical variability throughout the lake sediment cores, and to investigate specific elemental proxies for paleoenvironmental change (detrital flux, biogenic flux, and redox state). The high-resolution XRF data are supplemented by sediment magnetic susceptibility measurements, and organic matter concentration as determined by loss on ignition. These records demonstrate a general increase in detrital sediment input from 1200 to 1300 A.D., during a period of known regional agricultural expansion. We infer these changes to be the consequence of increased catchment soil erosion and material flux to the water bodies. The data also suggest changes in mill and farm pond primary productivity, also related to soil erosion and changing transport of soil nutrients to the basins. Near the onset of the Little Ice Age (ca. 1500 A.D.) pond productivity reductions are apparent, likely indicating colder climates. These mill and farm pond sedimentary archives, in conjunction with historic records, can be used to better understand past land management strategies. Furthermore, historically documented landscape changes can be examined within the context of prevailing climatic conditions over the last ~800 years in an effort to establish future best management practices and the most

  5. Sediment cores from kettle holes in NE Germany reveal recent impacts of agriculture.

    PubMed

    Kleeberg, Andreas; Neyen, Marielle; Schkade, Uwe-Karsten; Kalettka, Thomas; Lischeid, Gunnar

    2016-04-01

    Glacial kettle holes in young moraine regions receive abundant terrigenous material from their closed catchments. Core chronology and sediment accumulation were determined for two semi-permanent kettle holes, designated RG and KR, on arable land close to the villages of Rittgarten and Kraatz, respectively, in Uckermark, NE Germany. Core dating ((210)Pb, (137)Cs) revealed variable sediment accretion rates through time (RG 0.4-23.1 mm a(-1); KR 0.2-35.5 mm a(-1)), with periods of high accumulation corresponding to periods of intensive agricultural activity and consequent erosional inputs from catchments. Sediment composition (C, N, P, S, K, Ca, Fe, Mn, Zn, Cu, Mo, Pb, Cd, Zr) was used to determine sediment source and input processes. At RG, annual P input increased from 0.65 kg ha(-1) in the early nineteenth century to 1.67 kg ha(-1) by 2013. At KR, P input increased from 0.6 to 4.1 kg ha(-1) over the last century. There was a concurrent increase in Fe input in both water bodies. Thus, Fe/P ratios showed no temporal trend and did not differ between RG (18.5) and KR (18.4), indicating similar P mobility. At RG, the S/Fe ratio increased from 0.4 to 2.3, indicating more iron sulphides and thus higher P availability, coinciding with high coverage of duckweed (Spirodela polyrhiza (L.)) and soft hornwort (Ceratophyllum submersum L.). At KR, however, this ratio remained low and relatively unchanged (0.3 ± 0.4), indicating more efficient Fe-P binding and lower hydrophyte productivity. Trends in sediment composition indicate a shift towards eutrophication in both kettle holes, but with differences in timing and magnitude. Other morphologically similar kettle holes in NE Germany that are prone to erosion could have been similarly impacted but may differ in the extent of sediment infilling and degradation of their ecological functions. PMID:26695416

  6. Dating cave speleothems using diamond core bits in Tennessee and Virginia

    NASA Astrophysics Data System (ADS)

    Burnham, T. G.; Gao, Y.; Cheng, H.; Edwards, R.

    2011-12-01

    Removing speleothems for paleoclimate study was a destructive practice in cave and karst communities. It was considered illegal and even resulted in lawsuits in some cases. We used small diamond core bits to investigate age distributions of speleothems in several caves in Virginia and Tennessee without removing them from caves. Core bits of 8 mm diameter and one inch depth of cut were used to drill nearly 100 cores from three caves: Morril's Cave (aka Worley's Cave) and Blue Springs Cave in Tennessee and Grand Caverns in Virginia. Samples drilled in Morrill's Cave were processed for U/Th chemistry directly. Cores drilled in Blue Springs Cave and Grand Caverns were carefully selected and cleaned using ultrasonic cleaner before the U/Th chemistry procedure. Age dating results showed significant differences for these two sets of samples. For Morril's Cave samples, most of the age errors (2 sigma) were greater than 1%. For the pre-cleaned samples, more than 90% of the age errors (2 sigma) were less than 1%. This method is non-destructive and easy to use with minimum equipment needed in the field. Age dating results are fairly precise if samples are pre-cleaned for U/Th chemistry. Major limitations of this methods are 1) Pre-cleaning is necessary to ensure precise dating results; 2) Hiatus could be missed if cores are only drilled at the top and bottom portions of the speleothems; 3) Exact location of ages are hard to interpret especially for relatively longer cores.

  7. Determination of PAH sources in dated sediments from Green Bay, Wisconsin, by a chemical mass balance model.

    PubMed

    Su, M C; Christensen, E R; Karls, J F

    1998-01-01

    Six sediment cores were collected from Green Bay, Wisconsin, in order to identify possible sources of polycyclic aromatic hydrocarbons (PAHs) by a chemical mass balance (CMB) model. The cores which were obtained in 1995 had total PAH concentrations between 8.04 and 0.460 ppm. 210Pb and 137Cs dating was used to determine historical trends of PAH inputs, and elemental carbon particle analysis was done to characterize particles from combustion of coal, wood and petroleum. The results show that coke burning, highway dust, and wood burning are likely sources of PAHs to Green Bay. The contribution of coke oven emissions (CB) for the Green Bay cores is in the range of 5 to 90%. The overall highway dust (HWY) contribution is between 5 and 70%. There is a maximum (approximately 67%) contribution of HWY around 1988 which is in agreement with the historical US petroleum consumption. The wood burning (WB) contribution is between 1 to 30%, except in core GB-A where a maximum (approximately 50%) is found around 1994. The average relative errors of measurement for x2 equal to the number of degrees of freedom, are 52.5, 56.2, 36.2, 52.3, and 42.8 (df = 3) for the Green Bay cores A, B, C, E, and F, respectively. The sums of the contribution factors are less than one, indicating gain of inert biological or other bulk material between source and receptor. The results of carbon particles for Green Bay core D show that coal, oil, and wood burning are consistent with the CMB modeling results. PMID:15093306

  8. Characterization of organic matter in a sediment Core near the Mataripe refinery, Bahia-Brazil.

    PubMed

    Costa, Alexandre Barreto; de Souza, José Roberto Bispo; Zucchi, Maria do Rosário; de Azevedo, Antonio Expedito Gomes; de Argollo, Roberto Max

    2016-04-15

    A sediment core was taken from the Todos os Santos Bay, near the Mataripe Bahia-Brazil refinery. The results of dating, (210)Pb and (137)Cs methods, combined with organic indicators, Polycyclic aromatic hydrocarbons (PAHs), n-alkanes and total organic carbon (TOC), showed significant change with the start of production of the oil fields of Aratu, Itaparica and Dom João (1939-1947) and the construction of the Mataripe refinery (1949-1950). This event was marked by a series of significant changes, including an abrupt increase in TOC and the growth of PAH concentrations and the presence Unresolved/Resolved ratio (UR/R)>4 in n-alkanes fraction, which indicated that the contamination was of petrogenic origin. The δ(13)C of specific n-alkanes compounds showed gradual deplete with the depth. PMID:26920428

  9. On high-resolution sampling of short ice cores: Dating and temperature information recovery from Antarctic Peninsula virtual cores

    NASA Astrophysics Data System (ADS)

    Sime, Louise C.; Lang, Nicola; Thomas, Elizabeth R.; Benton, Ailsa K.; Mulvaney, Robert

    2011-10-01

    Recent developments in ice melter systems and continuous flow analysis (CFA) techniques now allow higher-resolution ice core analysis. Here, we present a new method to aid interpretation of high-resolution ice core stable water isotope records. Using a set of simple isotopic recording and postdepositional assumptions, the European Centre for Medium-Range Weather Forecasts' 40 year reanalysis time series of temperature and precipitation are converted to "virtual core" depth series across the Antarctic Peninsula, helping us to understand what information can be gleaned from the CFA high-resolution observations. Virtual core temperatures are transferred onto time using three different depth-age transfer assumptions: (1) a perfect depth-age model, (2) a depth-age model constructed from single or dual annual photochemical tie points, and (3) a cross-dated depth-age model. Comparing the sampled temperatures on the various depth-age models with the original time series allows quantification of the effect of ice core sample resolution and dating. We show that accurate annual layer count depth-age models should allow some subseasonal temperature anomalies to be recovered using a sample resolution of around 40 mm, or 10-20 samples per year. Seasonal temperature anomalies may be recovered using sample lengths closer to 60 mm, or about 7-14 samples per year. These results tend to confirm the value of current CFA ice core sampling strategies and indicate that it should be possible to recover about a third of subannual (but not synoptic) temperature anomaly information from annually "layer-counted" peninsula ice cores.

  10. Partitioning of Heavy Metals In Estuarine Sediments Cores and Implications For The Use of Sediment Quality Standards

    NASA Astrophysics Data System (ADS)

    Spencer, K.; MacLeod, C.

    Total metal concentrations and partitioning behaviour of metal contaminants in sedi- ment cores collected from three estuaries (Thames, Medway and Blackwater) in south east England were examined with respect to sediment quality guidelines (SQGs). Metal data from surface sediments were compared with historically contaminated sed- iments at depth to determine whether vertical contaminant profiles should be consid- ered when applying sediment quality guidelines. Initial investigations, based on total metal concentrations in surface sediments indicate that there is no risk to biota in any of the estuaries studied. However, in the Medway and Thames estuaries, which have received past industrial inputs, consideration of sediments at depth is also im- portant. Comparison of sediments at depth with SQGs suggests that local authorities should examine vertical metal profiles, particularly in estuaries that are experiencing low sediment accumulation rates, erosion or dredging activities. Total metal data indi- cate that the risk to biota is greatest in the Thames followed by the Medway and then the Blackwater. However, metal partitioning data indicate that the risk to biota is com- parable for the Medway and the Blackwater with the potentially bioavailable fraction presenting no risk to biota. Conversely, over 70% of metals are labile in the Thames Estuary sediments and toxic effects are probable. This suggests that the application of sediment quality guidelines using total sediment metal concentrations may over or under estimate the risk to biota in geochemically dissimilar estuarine sediments.

  11. AMS radiocarbon analyses from Lake Baikal, Siberia: Challenges of dating sediments from a large, oligotrophic lake

    USGS Publications Warehouse

    Colman, Steven M.; Jones, Glenn A.; Rubin, M.; King, J.W.; Peck, J.A.; Orem, W.H.

    1996-01-01

    A suite of 146 new accelerator-mass spectrometer (AMS) radiocarbon ages provides the first reliable chronology for late Quaternary sediments in Lake Baikal. In this large, highly oligotrophic lake, biogenic and authigenic carbonate are absent, and plant macrofossils are extremely rare. Total organic carbon is therefore the primary material available for dating. Several problems are associated with the TOC ages. One is the mixture of carbon sources in TOC, not all of which are syndepositional in age. This problem manifests itself in apparent ages for the sediment surface that are greater than zero. However, because most of the organic carbon in Lake Baikal sediments is algal (autochthonous) in origin, this effect is limited to about 1000+500 years, which can be corrected, at least for young deposits. The other major problem with dating Lake Baikal sediments is the very low carbon contents of glacial-age deposits, which makes them extremely susceptible to contamination with modern carbon. This problem can be minimized by careful sampling and handling procedures. The ages show almost an order of magnitude difference in sediment-accumulation rates among different sedimentary environments in Lake Baikal, from about 0.04 mm/year on isolated banks such as Academician Ridge, to nearly 0.3 mm/year in the turbidite depositional areas beneath the deep basin floors, such as the Central Basin. The new AMS ages clearly indicate that the dramatic increase in diatom productivity in the lake, as evidenced by increases in biogenic silica and organic carbon, began about 13 ka, in contrast to previous estimates of 7 ka for the age of this transition. Holocene net sedimentation rates may be less than, equal to, or greater than those in the late Pleistocene, depending on the site. This variability reflects the balance between variable terrigenous sedimentation and increased biogenic sedimentation during interglaciations. The ages reported here, and the temporal and spatial variation in

  12. Analysis of particulate matter collected by sediment traps and from sediment Cores

    NASA Astrophysics Data System (ADS)

    Collier, Bob; Dymond, Jack; Conard, Roberta; Robbins, Jim

    These contributions are primarily directed at elemental analyses for major and trace cations and silicon on particles collected by sediment traps and sediment cores; samples typically having at least several hundred milligrams available. The techniques outlined below and other wet chemical methods are reviewed in more detail in an OSU technical report by Robbins et al. [1984]. Typically, our group filters water samples for trace metal analyses immediately upon their arrival at the surface. The primary emphasis of these techniques focuses on the dissolved material. Since we have not had a full clean-lab available, we subsample the Niskins immediately using a semi-closed connection to large mouth bottles (LPE) which minimizes atmospheric exposure to contamination. The samples are then vacuum filtered within a portable laminar-flow hood (HEPA filtered) using plastic filtration "chimneys" (Millipore or Nuclepore) placed over a plastic vacuum chamber which contains the filtrate sample bottle. Filtration is carried out with 1 N HCl acid-leached Nuclepore or Poretics filters (0.4 μm) and the filtrate is collected directly into the final sample bottle. Both filtered and unfiltered subsamples are acidified to a pH<2 with 2 mL 6 N HCl L-1 sample using subboiling-distilled HCl, and the difference in concentration between the filtered and unfiltered sample is taken to represent an acid-labile particulate fraction.

  13. RECENT DECLINES IN PAH, PCB, AND TOXAPHENE LEVELS IN THE NORTHERN GREAT LAKES AS DETERMINED FROM HIGH RESOLUTION SEDIMENT CORES. (R825151)

    EPA Science Inventory

    Sediment cores were collected from two sites in Grand Traverse Bay, Lake
    Michigan in May 1998, dated using 210Pb geochronology, and analyzed
    for polychlorinated biphenyl (PCB) congeners, polycyclic aromatic hydrocarbons
    (PAHs), and toxaphene. The extraor...

  14. Perfluoroalkyl substances and extractable organic fluorine in surface sediments and cores from Lake Ontario.

    PubMed

    Yeung, Leo W Y; De Silva, Amila O; Loi, Eva I H; Marvin, Chris H; Taniyasu, Sachi; Yamashita, Nobuyoshi; Mabury, Scott A; Muir, Derek C G; Lam, Paul K S

    2013-09-01

    Fourteen perfluoroalkyl substances (PFASs) including short-chain perfluorocarboxylates (PFCAs, C4-C6) and perfluoroalkane sulfonates (PFSAs, C4 and C6) were measured in surface sediment samples from 26 stations collected in 2008 and sediment core samples from three stations (Niagara, Mississauga, and Rochester basins) collected in 2006 in Lake Ontario. Perfluorooctanesulfonate (PFOS), perfluorooctanoate (PFOA), perfluorononanoate (PFNA), perfluorodecanoate (PFDA), and perfluoroundecanoate (PFUnDA) were detected in all 26 surface sediment samples, whereas perfluorohexane sulfonate (PFHxS), perfluorooctane sulfonamide (FOSA), perfluorododecanoate (PFDoDA) and perfluorobutanoate (PFBA) were detected in over 70% of the surface sediment samples. PFOS was detected in all of the sediment core samples (range: 0.492-30.1ngg(-1) d.w.) over the period 1952-2005. The C8 to C11 PFCAs, FOSA, and PFBA increased in early 1970s. An overall increasing trend in sediment PFAS concentrations/fluxes from older to more recently deposited sediments was evident in the three sediment cores. The known PFCAs and PFSAs accounted for 2-44% of the anionic fraction of the extractable organic fluorine in surface sediment, suggesting that a large proportion of fluorine in this fraction remained unknown. Sediment core samples collected from Niagara basin showed an increase in unidentified organic fluorine in recent years (1995-2006). These results suggest that the use and manufacture of fluorinated organic compounds other than known PFCAs and PFSAs has diversified and increased. PMID:23911339

  15. Sediment Dating With Short-Lived Radioisotopes In Monterey Canyon, California Imply Episodes Of Rapid Deposition And Erosion

    NASA Astrophysics Data System (ADS)

    Lorenson, T. D.; Swarzenski, P. W.; Maier, K. L.; Gwiazda, R.; Paull, C. K.; Sumner, E.; Symons, W. O.

    2015-12-01

    Submarine canyons are a major conduit for terrestrial material to the deep sea. To better constrain the timing and rates in which sediment is transported down-canyon, we collected a series of sediment cores along the axis of Monterey Canyon, and quantified mass accumulation rates using short-lived radio-isotopes. A suite of sediment cores were carefully collected perpendicular to the canyon thalweg in water depths of approximately 300m, 500m, 800m, and 1500m using a remotely operated vehicle (ROV). We choose cores that were between 60m and 75m above the canyon thalweg on canyon side bench features for correlation with moored instrument deployments. The sediment cores reveal a complex stratigraphy that includes copious bioturbation features, sand lenses, subtle erosional surfaces, subtle graded bedding, and abrupt changes sediment texture and color. Downcore excess 210Pb and 137Cs profiles imply episodic deposition and remobilization cycles on the canyon benches. Excess 210Pb activities in cores reach depths of up to 1m, implying very rapid sedimentation. Sedimentation rates vary with water depth, generally with the highest sedimentation rate in closest to land, but vary substantially on adjacent canyon benches. Preliminary results demonstrate that sediment movement within Monterey Canyon is both dynamic and episodic on human time-scales and can be reconstructed used short-lived radio-isotopes.

  16. Possible recording of the Mono Lake Excursion in cored sediment from Clear Lake, California

    NASA Astrophysics Data System (ADS)

    Liddicoat, Joseph; Verosub, Kenneth

    2010-05-01

    We report the possible recording of the Mono Lake Excursion (MLE) in cored sediment from Clear Lake, CA. The locality (39.0˚N, 237.3˚E) is about 120 km north of San Francisco, CA, and 320 km northwest of the Mono Basin, CA, where the MLE first was discovered in North America (Denham and Cox, 1971). The field behaviour at Clear Lake that might be the MLE is recorded in clay and peaty clay about 50 cm below the top of the lowermost 80-cm core slug of a 21.6-m core. The coring was done by the wire-line method (Sims and Rymer, 1975) and the samples (rectangular solids 21 mm on a side and 15 mm high) were measured in a cryogenic magnetometer after demagnetization in an alternating field to 35 milliTesla (Verosub, 1977). The continuously-spaced samples record negative inclination of nearly 20˚ and northerly declination when unnormalized relative field intensity was reduced by an order of magnitude from the mean value. Those palaeomagnetic directions are followed immediately by positive inclination to about 50˚ and easterly declination of about 60˚ when the field intensity is at a relative high. That pattern of behaviour is recorded at three localities (Wilson Creek, Mill Creek, and Warm Springs) in the Mono Basin at the MLE (Liddicoat and Coe, 1979; Liddicoat, 1992). A path of the Virtual Geomagnetic Poles (VGPs) at Clear Lake form a clockwise-trending loop that is centered at 65˚N, 20˚E in the hemisphere away from the locality. The VGP that is farthest from the North Geographic Pole is at 29.3˚N, 337.1˚E, which is close to the path formed by the VGPs in the older portion of the MLE (Liddicoat and Coe, 1979; Liddicoat, 1992). The age of the sediment recording the anomalous palaeomagnetic directions in Clear Lake is about 30,000 years B.P. (Verosub, 1977). That age was determined from six (uncalibrated) radiocarbon dates, three of which are from near the base of the core (Sims and Rymer, 1975) where there are the anomalous palaeomagnetic directions, and linear

  17. Compositional classification and sedimentological interpretation of the laminated lacustrine sediments at Baumkrichen (Western Austria) using XRF core scanning data

    NASA Astrophysics Data System (ADS)

    Barrett, Samuel; Tjallingii, Rik; Bloemsma, Menno; Brauer, Achim; Starnberger, Reinhard; Spötl, Christoph; Dulski, Peter

    2015-04-01

    The outcrop at Baumkirchen (Austria) encloses part of a unique sequence of laminated lacustrine sediments deposited during the last glacial cycle. A ~250m long composite sediment record recovered at this location now continuously covers the periods ~33 to ~45 ka BP (MIS 3) and ~59 to ~73 ka BP (MIS 4), which are separated by a hiatus. The well-laminated (mm-cm scale) and almost entirely clastic sediments reveal alternations of clayey silt and medium silt to very-fine sand layers. Although radiocarbon and optically stimulated luminescence (OSL) dating provide a robust chronology, accurate dating of the sediment laminations appears to be problematic due to very high sedimentation rates (3-8 cm/yr). X-ray fluorescence (XRF) core scanning provided a detailed ~150m long record of compositional changes of the sediments at Baumkirchen. Changes in the sediments are subtle and classification into different facies based on individual elements is therefore subjective. We applied a statistically robust clustering analysis to provide an objective compositional classification without prior knowledge, based on XRF measurements for 15 analysed elements (all those with an acceptable signal-noise ratio: Zr, Sr, Ca, Mn, Cu, Zn, Rb, Ni, Fe, K, Cr, V, Si, Ba, T). The clustering analysis indicates a distinct compositional change between sediments deposited below and above the stratigraphic hiatus, but also differentiates between individual different laminae. Preliminary results suggest variations in the sequence are largely controlled by the relative occurrence of different kinds of sediment represented by different clusters. Three clusters identify well-laminated sediments, visually similar in appearance, each dominated by an anti-correlation between Ca and one or more of the detrital elements K, Zr, Ti, Si and Fe. Two of these clusters occur throughout the entire sequence, one frequently and the other restricted to short sections, while the third occurs almost exclusively below the

  18. Dating a tropical ice core by time-frequency analysis of ion concentration depth profiles

    NASA Astrophysics Data System (ADS)

    Gay, M.; De Angelis, M.; Lacoume, J.-L.

    2014-09-01

    Ice core dating is a key parameter for the interpretation of the ice archives. However, the relationship between ice depth and ice age generally cannot be easily established and requires the combination of numerous investigations and/or modelling efforts. This paper presents a new approach to ice core dating based on time-frequency analysis of chemical profiles at a site where seasonal patterns may be significantly distorted by sporadic events of regional importance, specifically at the summit area of Nevado Illimani (6350 m a.s.l.), located in the eastern Bolivian Andes (16°37' S, 67°46' W). We used ion concentration depth profiles collected along a 100 m deep ice core. The results of Fourier time-frequency and wavelet transforms were first compared. Both methods were applied to a nitrate concentration depth profile. The resulting chronologies were checked by comparison with the multi-proxy year-by-year dating published by de Angelis et al. (2003) and with volcanic tie points. With this first experiment, we demonstrated the efficiency of Fourier time-frequency analysis when tracking the nitrate natural variability. In addition, we were able to show spectrum aliasing due to under-sampling below 70 m. In this article, we propose a method of de-aliasing which significantly improves the core dating in comparison with annual layer manual counting. Fourier time-frequency analysis was applied to concentration depth profiles of seven other ions, providing information on the suitability of each of them for the dating of tropical Andean ice cores.

  19. User Friendly Processing of Sediment CT Data: Software and Application in High Resolution Non-Destructive Sediment Core Data Sets

    NASA Astrophysics Data System (ADS)

    Reilly, B. T.; Stoner, J. S.; Wiest, J.; Abbott, M. B.; Francus, P.; Lapointe, F.

    2015-12-01

    Computed Tomography (CT) of sediment cores allow for high resolution images, three dimensional volumes, and down core profiles, generated through the attenuation of X-rays as a function of density and atomic number. When using a medical CT-Scanner, these quantitative data are stored in pixels using the Hounsfield scale, which are relative to the attenuation of X-rays in water and air at standard temperature and pressure. Here we present MATLAB based software specifically designed for sedimentary applications with a user friendly graphical interface to process DICOM files and stitch overlapping CT scans. For visualization, the software allows easy generation of core slice images with grayscale and false color relative to a user defined Hounsfield number range. For comparison to other high resolution non-destructive methods, down core Hounsfield number profiles are extracted using a method robust to coring imperfections, like deformation, bowing, gaps, and gas expansion. We demonstrate the usefulness of this technique with lacustrine sediment cores from the Western United States and Canadian High Arctic, including Fish Lake, Oregon, and Sawtooth Lake, Ellesmere Island. These sites represent two different depositional environments and provide examples for a variety of common coring defects and lithologies. The Hounsfield profiles and images can be used in combination with other high resolution data sets, including sediment magnetic parameters, XRF core scans and many other types of data, to provide unique insights into how lithology influences paleoenvironmental and paleomagnetic records and their interpretations.

  20. Luminescence Dating of Marine Terrace Sediments Between Trabzon and Rize, Eastern Black Sea Basin: Preliminary Results

    NASA Astrophysics Data System (ADS)

    Softa, Mustafa; Spencer, Joel Q. G.; Emre, Tahir; Sözbilir, Hasan; Turan, Mehmet

    2016-04-01

    Quaternary marine terraces in the coastal region of Pontides in Northeastern Turkey are valuable archives of past sea level change. Until recently, dates of raised marine terraces undeciphered in the coastal region between Trabzon and Rize because of chronologic limitations. In this paper was to determine ages of the terrace deposits by applying optically stimulated luminescence (OSL) dating methods using single aliquot regenerative dose (SAR) techniques on quartz minerals from extracted marine terraces. Several samples were collected from three orders of Quaternary marine terraces which are reproducible at all sampling location in between cities of Trabzon and Rize, Turkey, coastal of Eastern Pontides, at the front of the thrust system. The terrace deposits mainly consist of clays, silts, sands and gravels. The sediments in these deposits are mainly derived from basaltic, andesitic, and limestone geology, and have elipsoid, square and flat shapes. The terrace deposits have heights ranging from 1 to 17 meters and increases in height and thickness from west to east. Initial OSL results from 1 mm and 3 mm quartz aliquots demonstrate good luminescence characteristics. Preliminary equivalent dose analysis results ranging from 17.6 Gy to 79.6 Gy have been calculated using the Central Age Model (CAM) and Minimum Age Model (MAM). According to ages obtained from three separate terrace is ~8 ka, ~42 ka and ~78 ka, respectively. Results of marine terrace sediments indicate this region has three sedimentation periods and coastal region of Pontides has been remarkably tectonically active since latest Pleistocene to earlier Holocene. This study will present preliminary OSL dating results obtained from samples of Quaternary marine terrace formation. Keywords: optically stimulated luminescence (OSL) dating, single grain, marine terraces, Eastern Pontides.

  1. Possible Recording of the Hilina Pali Excursion in Cored Tyrrhenian Sea Sediment

    NASA Astrophysics Data System (ADS)

    Iorio, Marina; Liddicoat, Joseph; Sagnotti, Leonardo; Incoronato, Alberto; de Anteriis, Giovanni; Insinga, Donatella; Angelino, Antimo

    2013-04-01

    First encountered in marine sediment cored from the Gulf of Mexico (19.5˚ N, 267.0˚ E)(Clark and Kennett, 1973), the Hilina Pali Excursion (HPE) is named for a locality in Hawaii (19.5˚ N, 205.0˚ E) where inclination of about negative 40˚ is documented in cored basalt (Teanby et al., 2002). Prior to naming the excursion, Coe et al. (1978) also found shallow inclination in basalt from Kilauea Volcano (19.2˚ N, 204.7˚ E) that is dated at about 18,000 yrs B.P. (uncorrected Carbon-14, Rubin and Berthold, 1961) - the age now assigned to the HPE - and was erupted when the field intensity was reduced to nearly half the present intensity. More recently, the HPE was located at Changbaishan Volcano in northeastern China (40.2˚ N, 128.0˚ E) where the age is established by Ar40/Ar39 dates (Singer et al., 2011). In exposed lake sediments in the Mono Basin, CA (38.0˚ N, 240.8˚ E), shallow positive inclination at about 18,000 yrs B.P. might also be the HPE. In the Mono Basin, normalized (NRM/ARM) intensity is reduced at that time (Zimmerman et al., 2006), and the Virtual Geomagnetic Poles (VGPs) during the reduced intensity form a clockwise trending loop when followed from old to young that descends to 53.8˚ N, 22.7˚ E (n = 6, Alpha-95 = 2.3˚) and is centered at about 50˚ N, 30˚ E (Coe and Liddicoat, 2012). There is a possible excursion of the palaeomagnetic field recorded in marine sediment at a locality in the Tyrrhenian Sea about 25 km south of Ischia (40.5˚ N, 13.7˚ E). The excursion is in sediment from two core segments that span about 22,000-18,000 yrs B.P. (de Alteriis et al., 2010) and occurs as reduced positive inclination (about 50˚) at about 20,000 yrs B.P. that increases to about 80˚ at about 18,000 yrs B.P. when declination changes from west to east. This pattern of field behaviour is similar to the behaviour of the possible HPE in the Mono Basin (Coe and Liddicoat, 2012) and in sediment cored from Lac du Bouchet, FR (44.9˚ N, 3.8˚ E) that is

  2. Chronologies of marine sediment cores during the Last Interglacial: strengths and limitations of commonly used climato-stratigraphic alignments

    NASA Astrophysics Data System (ADS)

    Govin, Aline; Capron, Emilie

    2015-04-01

    The Last Interglacial (LIG, ~129-116 thousand of years, ka) is relatively well documented in marine sediment cores retrieved across the globe. However, these records exhibit very few absolute age markers such as magnetic events and dated tephra layers, which limits the definition of independent and precise LIG age models. As a result, age models of marine sediments are defined using various methods based on the (i) synchronisation or (ii) climato-stratigraphic alignment of marine records to dated "reference" records, assuming simultaneous regional changes for a given climate variable (e.g. foraminiferal δ18O, temperature). The use of different "reference" chronologies (e.g. LR04, speleothem or ice core chronologies) also limits a precise investigation of climatic sequences across the LIG. Here, we evaluate the underlying hypotheses, strengths and limitations, and age uncertainties of methods commonly used in marine sediments during the LIG: i.e. benthic δ18O alignment to the LR04 benthic δ18O stack, temperature alignment to ice core or to speleothem records. We compare the resulting age models using examples from the North Atlantic core MD95-2042 and the Southern Ocean core MD02-2488. We show a lack of remarkable tie-points within the LIG, which limits the study of the sub-millennial-scale climate variability. We also report age offsets up to 4 ka when different reference chronologies (e.g. ice cores vs. speleothems) or different types of aligned records (e.g. SST vs. planktonic δ18O) are used. These results highlight the need for careful estimates of age uncertainties when defining age models in marine sediments. They also emphasize the fact that LIG chronologies should be considered with care. A clear statement on the reference chronology, the method of alignment and the type of tracers that are used should be given when investigating the LIG sequence of climatic events from various sediment cores or when comparing LIG marine records and climate model

  3. Uranium-series dating of sediments from Searles Lake: Differences between continental and marine climate records

    USGS Publications Warehouse

    Bischoff, J.L.; Rosenbauer, R.J.; Smith, G.I.

    1985-01-01

    One of the major unresolved questions in Pleistocene paleoclimatology has been whether continental climatic transitions are consistent with the glacial ??18O marine record. Searles Lake in California, now a dry salt pan, is underlain by sediment layers deposited in a succession of lakes whose levels and salinities have fluctuated in response to changes in climate over the last 3 ?? 106 years. Uranium-series dates on the salt beds range from 35 ?? 103 to 231 ?? 103 years. This range of dates allows identification of lake-sediment horizons that are time correlatives of the boundaries of marine isotope stages from the recent 3/4 boundary back to the 8/9 boundary. The 5/6 boundary coincided with a deepening of the lake, but the analogous 1/2 boundary coincided with desiccation. The 3/4, 4/5, 6/7, 7/8, and 8/9 boundaries correspond in age to horizons that record little or no change in sedimentation or climate. These hydrologic results demonstrate that the continental paleoclimate record at this mid-latitude site does not mimic the marine record.

  4. Uranium-series dating of sediments from searles lake: differences between continental and marine climate records.

    PubMed

    Bischoff, J L; Rosenbauer, R J; Smith, G I

    1985-03-01

    One of the major unresolved questions in Pleistocene paleoclimatology has been whether continental climatic transitions are consistent with the glacial delta(18)O marine record. Searles Lake in California, now a dry salt pan, is underlain by sediment layers deposited in a succession of lakes whose levels and salinities have fluctuated in response to changes in climate over the last 3 x 10(6) years. Uraniumseries dates on the salt beds range from 35 x 10(3) to 231x 10(3) years. This range of dates allows identification of lake-sediment horizons that are time correlatives of the boundaries of marine isotope stages from the recent 3/4 boundary back to the 8/9 boundary. The 5/6 boundary coincided with a deepening of the lake, but the analogous 1/2 boundary coincided with desiccation. The 3/4, 4/5, 6/7, 7/8, and 8/9 boundaries correspond in age to horizons that record little or no change in sedimentation or climate. These hydrologic results demonstrate that the continental paleoclimate record at this mid-latitude site does not mimic the marine record. PMID:17757864

  5. Isochron dating of sediments using luminescence of K-feldspar grains

    NASA Astrophysics Data System (ADS)

    Li, Bo; Li, Sheng-Hua; Wintle, Ann G.; Zhao, Hui

    2008-06-01

    A new method for dating well-bleached sediments is presented, with results for thirteen samples from China. The method uses an isochron constructed from the measurement of natural radiation doses received by potassium-feldspar grains in a range of grain sizes using the infrared stimulated luminescence (IRSL) signal. The age of deposition of the sediment is calculated from this isochron and from the internal dose rate to the grains from 40K and 87Rb in the crystal lattice. This procedure appears to overcome age underestimation due to anomalous fading, a phenomenon that has precluded conventional luminescence dating of K-feldspars and would be applicable to K-feldspars for which the natural dose is beyond the linear dose response region. Also, since the isochron IRSL method is reliant on only the internal dose rate, it overcomes problems related to (1) changes in past dose rate due to postdepositional migration of radionuclides, (2) changes in water content as water-lain sediments dry out, (3) spatial heterogeneity in the gamma dose rate, and (4) uncertainties in the cosmic ray dose rate during the period of sample burial.

  6. Chronological constraints on Cordilleran Ice Sheet glaciomarine sedimentation from core MD02-2496 off Vancouver Island (western Canada)

    NASA Astrophysics Data System (ADS)

    Cosma, T. N.; Hendy, I. L.; Chang, A. S.

    2008-05-01

    Chronology based on 46 radiocarbon dates has been generated for MD02-2496, western Vancouver Island, Canada. Subsequent correlation between glaciomarine sedimentary sequences within the core and the terrestrial stratigraphy of the Cordilleran Ice Sheet for the last 50 ka provide new insight into Cordilleran Ice Sheet processes. Glaciomarine sedimentation associated with the most recent advance (Fraser Glaciation) of the Cordilleran Ice Sheet began at 30.5 cal kyr BP (˜25 14C kyr BP). Extremely high sedimentation rates indicate the ice sheet became proximal to the site at ˜19.5 cal kyr BP (16 14C kyr BP). Deposition of ice rafted detritus (IRD) began at ˜17 cal kyr BP (14 14C kyr BP), and abruptly terminated at ˜16.2 cal kyr BP (13.5 14C kyr BP) indicating rapid regional ice sheet retreat. A minor IRD event followed at ˜14.7 cal kyr BP (12.5 14C kyr BP). Glaciomarine sediment deposition abruptly ended at 10.2 cal kyr BP (˜8.8 14C kyr BP) with the resumption of biogenic sedimentation. The Olympia Interstade is represented by an interval of hemipelagic sedimentation between ˜43 and 31.5 ka. Prior to ˜45 ka sediment deposition is controlled by glaciomarine processes with evidence for a significant IRD event at ˜47 cal kyr BP (>41±1.06 14C kyr BP).

  7. Sediment core fossils in ancient Lake Ohrid: testing for faunal change in molluscs since the Last Interglacial period

    NASA Astrophysics Data System (ADS)

    Albrecht, C.; Vogel, H.; Hauffe, T.; Wilke, T.

    2010-05-01

    Ancient Lake Ohrid is probably of early Pleistocene or Pliocene origin and amongst the few lakes in the world harboring an outstanding degree of endemic biodiversity. Although there is a long history of evolutionary research in Lake Ohrid, particularly on molluscs, a mollusc fossil record has been missing up to date. For the first time, gastropod and bivalve fossils are reported from the basal, calcareous part of a 2.6 m long sediment succession (core Co1200) from the north-eastern part of Lake Ohrid. Electron spin resonance (ESR) dating of mollusc shells from the same stratigraphic level yielded an age of 130±28 ka. Lithofacies III sediments, i.e. a subdivision of the stratigraphic unit comprising the basal succession of core Co1200 between 181.5-263 cm appeared solid, grayish-white, and consisted almost entirely of silt-sized endogenic calcite (CaCO3>70%) and intact and broken mollusc shells. Here we compare the faunal composition of the thanatocoenosis with recent mollusc associations in Lake Ohrid. A total of 13 mollusc species (9 gastropod and 4 bivalve species) could be identified within Lithofacies III sediments. The value of sediment core fossils for reconstructing palaeoenvironmental settings was evaluated. The agreement between sediment and palaeontological proxies was tested. The combined findings of the ecological study and the sediment characteristics suggest deposition in a shallow water environment during the Last Interglacial period. We tested for major faunal changes since the Last Interglacial period and searched for signs of extinction events. The fossil fauna exclusively included species also found in the present fauna, i.e. no extinction events are evident for this site since the Last Interglacial. The thanatocoenosis showed the highest similarity with recent Intermediate Layer (5-25 m) mollusc assemblages. The demonstrated existence of a mollusc fossil record in Lake Ohrid sediment cores also has great significance for future deep drilling

  8. Doppler Scanning of Sediment Cores: A Useful Method for Studying Sedimentary Structures and Defining the Cutting Angle for Half Cores

    NASA Astrophysics Data System (ADS)

    Acar, Dursun; Cagatay, Namik; Biltekin, Demet; Eris, Kadir; Albut, Gulum; Ogretmen, Nazik; Arslan, Tugce; Sari, Erol

    2014-05-01

    We tested the doppler ultrasound scanning of sediment cores in PVC liners using 8 megahertz ultrasonic waves for detection of angular laminations. The method was tested with artificially prepared cores as well as marine and lake sediment cores, and proven to be a useful and fast technique for imaging and determining the vertical angularity of sedimentary structures, such as laminations and beddings. Random cutting axes provide two angularities on X and Y dimensions. In this study, the main scientific problem is 'sequential angular disconformity'. Importance of detection of these anomalies on whole cores before dividing into half cores based on determining the right cutting axes. Successful imaging was obtained from top three centimeter depth of the sediments below the PVC liner, using a linear Doppler probe. Other Doppler probes (e.g., convex probe) did not work for core scanning because of their wave-form and reflection characteristics. Longitudinal and rotational scanning with gap filler and ultrasonic wave conductive gel material for keeping energy range of wave is necessary for detecting the variation in the dip of the bedding and laminae in the cores before separation. Another angular reasoned problem is about horizontal surface and can be easily solved with adjustable position of sensor or ray source placement. Border of sampling points between two different lithology must be stay with regard to neighbour sediment angles. Vertical angularity correction is not easy and its effect on signal propagation, detection biases and effectible to mixed samples contamination during physical sampling (particle size analyzing). Determining the attitude of angled bedding before core splitting is important for further core analyses such as elemental analysis and digital X-ray radiography. After Doppler scanning, the splitting direction (i.e., vertical to bedding and lamination) can be determined. The method is cheap, quick and non- hazardous to health, unlike the x

  9. Chemical analysis of sediment cores from the East Waterway (Everett, Washington). Final report

    SciTech Connect

    Crecelius, E.A.; Bloom, N.S.; Gurtisen, J.M.

    1984-06-01

    Chemical data for two sediment cores from the East Waterway of Everett, Washington, indicate that 20 to 30 cm of contaminated sediments are accumulating per year. The concentrations of several heavy metals (Pb, Hg and Cu), polychlorinated biphenyls (PCBs) and petroleum hydrocarbons increase with depth in the sediments suggesting contamination of this waterway has varied by as much as a factor of 10 during the last 5 years. 7 references, 9 figures, 12 tables.

  10. TL, OSL and C-14 dating results of the sediments and bricks from mummified nuns' grave.

    PubMed

    Tudela, Diego R G; Tatumi, Sonia H; Yee, Márcio; Brito, Silvio L M; Morais, José L; Morais, Daisy de; Piedade, Silvia C; Munita, Casimiro S P; Hazenfratz, Roberto

    2012-06-01

    This paper presents the results of TL and OSL dating of soil and fragments of bricks from a grave, which was occupied by two mummified nuns, found at "Luz" Monastery, located in the state of São Paulo, Brazil. The TL and OSL ages were compared to C-14 dating ones obtained from bone collagens of the mummies. The majority of the ages is related to the eighteenth century. The gamma-ray spectroscopy was used to evaluate natural radioisotope concentrations in the samples, and by using these concentrations the annual dose rates, from 3.0 to 5.3 Gy/kyr, were obtained. Neutron activation analysis was performed and the radioisotope contents results are in agreement with those obtained by gamma-ray spectroscopy. The contents of U, Th and Ce elements were higher than those found in usual sediments. PMID:22569952

  11. Using an independent geochronology based on palaeomagnetic secular variation (PSV) and atmospheric Pb deposition to date Baltic Sea sediments and infer 14C reservoir age

    NASA Astrophysics Data System (ADS)

    Lougheed, Bryan C.; Snowball, Ian; Moros, Matthias; Kabel, Karoline; Muscheler, Raimund; Virtasalo, Joonas J.; Wacker, Lukas

    2012-05-01

    Dating of sediment cores from the Baltic Sea has proven to be difficult due to uncertainties surrounding the 14C reservoir age and a scarcity of macrofossils suitable for dating. Here we present the results of multiple dating methods carried out on cores in the Gotland Deep area of the Baltic Sea. Particular emphasis is placed on the Littorina stage (8 ka ago to the present) of the Baltic Sea and possible changes in the 14C reservoir age of our dated samples. Three geochronological methods are used. Firstly, palaeomagnetic secular variations (PSV) are reconstructed, whereby ages are transferred to PSV features through comparison with varved lake sediment based PSV records. Secondly, lead (Pb) content and stable isotope analysis are used to identify past peaks in anthropogenic atmospheric Pb pollution. Lastly, 14C determinations were carried out on benthic foraminifera (Elphidium spec.) samples from the brackish Littorina stage of the Baltic Sea. Determinations carried out on smaller samples (as low as 4 μg C) employed an experimental, state-of-the-art method involving the direct measurement of CO2 from samples by a gas ion source without the need for a graphitisation step - the first time this method has been performed on foraminifera in an applied study. The PSV chronology, based on the uppermost Littorina stage sediments, produced ten age constraints between 6.29 and 1.29 cal ka BP, and the Pb depositional analysis produced two age constraints associated with the Medieval pollution peak. Analysis of PSV data shows that adequate directional data can be derived from both the present Littorina saline phase muds and Baltic Ice Lake stage varved glacial sediments. Ferrimagnetic iron sulphides, most likely authigenic greigite (Fe3S4), present in the intermediate Ancylus Lake freshwater stage sediments acquire a gyroremanent magnetisation during static alternating field (AF) demagnetisation, preventing the identification of a primary natural remanent magnetisation for

  12. Contaminant trends in reservoir sediment cores as records of influent stream quality

    USGS Publications Warehouse

    Van Metre, P.C.; Mahler, B.J.

    2004-01-01

    When reconstructing water-quality histories from lake and reservoir cores, it is sometimes assumed that the chemical signatures in the cores reflect historical water quality in the influent streams. To investigate this assumption, concentrations of metals, PAHs, and organochlorine compounds in sediment cores were compared to those associated with an influent-stream suspended sediment for three reservoirs in Fort Worth, TX, and two reservoirs in Boston, MA, U.S.A., and interpreted in light of land-use and regulation histories. In evaluating relations between suspended sediments and cores, three levels of preservation were indicated: (1) influent concentrations and historical trends are preserved in cores (metals at all sites; some organic contaminants at some sites); (2) some loss occurs during transport and initial deposition but relative historical trends are preserved in cores (some organic contaminants at some sites); and (3) neither stream concentrations nor relative historical trends are preserved (dieldrin and p,p???-DDT). The degree of preservation of influent concentration histories varied between lakes, particularly for PAHs. The results support the use of sediment cores to infer streamwater-quality histories for many contaminants but indicate that reservoir-bottom sediment samples might underestimate concentrations of organic contaminants in some streams.

  13. Magnetic and Sedimentological Analyses of Sediment Cores from Otsego Lake Reveal Climate and Possible Delta Dynamics Throughout the Holocene

    NASA Astrophysics Data System (ADS)

    Geiss, C. E.; Hasbargen, L. E.

    2015-12-01

    Otsego Lake (42°43'N, -74°54'W) is a large oligotrophic, monomictic lake in upstate New York that occupies a narrow, N-S trending basin (approx. 13 km length, 2 km width) and has a maximum water depth of approx. 50 m. We collected two sediment cores from a shallow (4 m water depth) bench near the SW shore of the lake. The cores were collected approximately 200 m off-shore from a small stream delta. Age control was established through five 14C AMS-dates obtained from terrestrial plant macrofossils. We analyzed sediments for their magnetic properties (magnetic susceptibility, anhysteretic- and isothermal remanent magnetization, hysteresis properties and coercivity distributions) and performed loss-on-ignition and X-ray analyses to determine the relative abundance of organic matter, quartz and calcite. The watershed of Otsego Lake rests in glacial debris and Devonian shale and limestone. The base of the core (> 9 ka) consists mostly of silt-sized, massive to weakly laminated siliceous and strongly magnetic sediments. Between 8-9 ka the climate warmed sufficiently to allow for the formation of calcareous sediments. Between 8 - 6 ka magnetic minerals are characterized by low abundance and small grainsize, while organic and inorganic carbon increase. Sedimentation rates decrease significantly between 6-2 ka (from ~100 cm/ka to 12-15 cm/ka). During this time interval the relative abundance of quartz increases, sediment becomes slightly more magnetic, and the magnetic grain-size increases as well. We interpret this time period as a low-stand, when lower lake levels allow for the redeposition and possible loss of sediment into the deeper part of the lake, as well as increased terrigenous input from the nearby lakeshore. This lowstand is clearly identified as a strong, continuous reflector in GPR profiles. Sediments younger than 2 ka are characterized by variable abundances of magnetic minerals, with magnetic remanence peaks appearing semi-periodically approximately every

  14. Vertical and lateral flux on the continental slope off Pakistan: correlation of sediment core and trap results

    NASA Astrophysics Data System (ADS)

    Schulz, H.; von Rad, U.

    2014-06-01

    Due to the lack of bioturbation, the varve-laminated muds from the oxygen minimum zone (OMZ) off Pakistan provide a unique opportunity to precisely determine the vertical and lateral sediment fluxes in the nearshore part of the northeastern Arabian Sea. West of Karachi (Hab area), the results of two sediment trap stations (EPT and WPT) were correlated with 16 short sediment cores on a depth transect crossing the OMZ. The top of a distinct, either reddish- or light-gray silt layer, 210Pb-dated as AD 1905 ± 10, was used as an isochronous stratigraphic marker bed to calculate sediment accumulation rates. In one core, the red and gray layer were separated by a few (5-10) thin laminae. According to our varve model, this contributes < 10 years to the dating uncertainty, assuming that the different layers are almost synchronous. We directly compared the accumulation rates with the flux rates from the sediment traps that collected the settling material within the water column above. All traps on the steep Makran continental slope show exceptionally high, pulsed winter fluxes of up to 5000 mg m-2 d-1. Based on core results, the flux at the seafloor amounts to 4000 mg m-2 d-1 and agrees remarkably well with the bulk winter flux of material, as well as with the flux of the individual bulk components of organic carbon, calcium carbonate and opal. However, due to the extreme mass of remobilized matter, the high winter flux events exceeded the capacity of the shallow traps. Based on our comparisons, we argue that high-flux events must occur regularly during winter within the upper OMZ off Pakistan to explain the high accumulations rates. These show distribution patterns that are a negative function of water depth and distance from the shelf. Some of the sediment fractions show marked shifts in accumulation rates near the lower boundary of the OMZ. For instance, the flux of benthic foraminifera is lowered but stable below ~1200-1300 m. However, flux and sedimentation in the

  15. Exploration Of Activity Measurements And Equilibrium Checks For Sediment Dating Using Thick-Window Germanium Detectors

    SciTech Connect

    Warner, Jacob A.; Gladkis, Laura G.; Timmers, Heiko; Fitzsimmons, Kathryn E.; Reynolds, Eva M.

    2011-06-01

    Activity measurements on sediment samples for trapped-charge geological dating using gamma-ray spectroscopy are an important verification of the field-site dose rate determination. Furthermore gamma-ray spectroscopy can check if the natural decay series are in secular equilibrium which is a crucial assumption in such dating. Typically the activities of leading members of the Thorium and Uranium decay series are measured, which requires Germanium detectors with thin windows and good energy resolution in order to effectively detect the associated low energy gamma-rays. Such equipment is not always readily available. The potential of conventional Germanium detectors with thick entrance window has been explored towards routine gamma-ray spectroscopy of sediment samples using higher energy gamma-rays. Alternative isotopes, such as Ac-228 and Pb-212 for the Thorium series, and Pa-234m, Ra-226 and Bi-214 for the Uranium series, have been measured in order to determine the mass-specific activity for the respective series and possibly provide a check of secular equilibrium. In addition to measurements of the K-40 activity, with the alternative approach, the activities of both decay series can be accurately determined. The secular equilibrium condition may be tested for the Thorium series. Measurement accuracy for Pa-234m is, however, not sufficient to permit also a reliable check of equilibrium for the Uranium series.

  16. Uranium-series Comminution Ages for Dating Detrital Sediments: Investigating the Methodological Underpinnings

    NASA Astrophysics Data System (ADS)

    Lee, V. E.; DePaolo, D. J.; Christensen, J. N.; Huber, C.; Henderson, G. M.

    2011-12-01

    The uranium-series comminution age method can be utilized to directly date fine-grained detrital clasts, which are nearly ubiquitous throughout the sediments and soils blanketing the Earth's surface environment. In addition to yielding the comminution age (which is the elapsed time since the detrital particle was reduced below a critical threshold grain size (~50 microns)), sediment transport timescales can also be obtained in settings where the depositional age can be determined using independent dating methods. Therefore, the comminution age method is a powerful approach for investigating the timescales and associated Earth surface processes of a broad range of terrestrial deposits. The basic model for how the comminution age method works is that for grains that have been reduced below the critical threshold size, there is a measurable decrease in the (234U/238U) activity ratio due to time-dependent alpha recoil loss of the 234U daughter following decay of the 238U parent isotope. The magnitude of this decrease yields the comminution age, when information is also taken into account regarding the initial (234U/238U) ratio, as well as the grain surface area over which recoiled 234U daughters are lost (described by a constant termed the recoil loss parameter fα). Although the fundamental concepts underlying the use of the comminution age method as a chronometer are simple and well-established, the complexity of natural samples requires that careful attention be paid to methodological details that can affect the accuracy of the comminution ages obtained from U isotope measurements. Of particular interest for terrestrial samples are potential impacts of both physical and chemical weathering on the U isotope composition of bulk sediments. Weathering processes can potentially obscure and/or alter the U isotopic composition of the detrital fraction by mechanisms such as the production of secondary phases with different U isotope compositions, dissolution-induced removal

  17. Identification of Water-Quality Trends Using Sediment Cores from Dillon Reservoir, Summit County, Colorado

    USGS Publications Warehouse

    Greve, Adrienne I.; Spahr, Norman E.; Van Metre, Peter C.; Wilson, Jennifer T.

    2001-01-01

    Since the construction of Dillon Reservoir, in Summit County, Colorado, in 1963, its drainage area has been the site of rapid urban development and the continued influence of historical mining. In an effort to assess changes in water quality within the drainage area, sediment cores were collected from Dillon Reservoir in 1997. The sediment cores were analyzed for pesticides, polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), and trace elements. Pesticides, PCBs, and PAHs were used to determine the effects of urban development, and trace elements were used to identify mining contributions. Water-quality and streambed-sediment samples, collected at the mouth of three streams that drain into Dillon Reservoir, were analyzed for trace elements. Of the 14 pesticides and 3 PCBs for which the sediment samples were analyzed, only 2 pesticides were detected. Low amounts of dichloro-diphenyldichloroethylene (DDE) and dichloro-diphenyldichloroethane (DDD), metabolites of dichlorodiphenyltrichloroethane (DDT), were found at core depths of 5 centimeters and below 15 centimeters in a core collected near the dam. The longest core, which was collected near the dam, spanned the entire sedimentation history of the reservoir. Concentrations of total combustion PAH and the ratio of fluoranthene to pyrene in the core sample decreased with core depth and increased over time. This relation is likely due to growth in residential and tourist populations in the region. Comparisons between core samples gathered in each arm of the reservoir showed the highest PAH concentrations were found in the Tenmile Creek arm, the only arm that has an urban area on its shores, the town of Frisco. All PAH concentrations, except the pyrene concentration in one segment in the core near the dam and acenaphthylene concentrations in the tops of three cores taken in the reservoir arms, were below Canadian interim freshwater sediment-quality guidelines. Concentrations of arsenic, cadmium

  18. 10Be depth-profile dating of glaciofluvial sediments in the northern Alpine Foreland

    NASA Astrophysics Data System (ADS)

    Claude, Anne; Akçar, Naki; Ivy-Ochs, Susan; Schlunegger, Fritz; Kubik, Peter; Christl, Marcus; Vockenhuber, Christof; Dehnert, Andreas; Rahn, Meinert; Schlüchter, Christian

    2016-04-01

    10Be depth-profile dating is based on the fact that nuclide production is decreasing as an exponential function of depth. This method requires collecting at least four sediment samples in a vertical profile. The obtained nuclide concentrations are plotted against depth and fitted depth-profiles to the measured dataset. The age is then calculated based on the best-fit. The requirements for this method are the following: sampling geological units in artificial outcrops with minimum thickness of soil (less than around 80 cm), preferably with a flat-topped landform in order to guarantee that the uppermost surface of the deposit remains as unmodified as possible and is related to a defined geomorphologic process. Additionally at least one sample, preferably three, from the uppermost one meter of the profile as the exponential decrease mainly occurs around this depth. No sample is collected from the overlying soil. In this study, we aim to establish the chronology of the oldest Quaternary sediments in the northern Alpine Foreland using depth-profile dating with 10Be. These ages contribute to the understanding of the Quaternary landscape evolution of the Alpine Foreland. Here, we unravel the chronology of five sites at different morphostratigraphic positions: Mandach and Ängi (canton Aargau), Stadlerberg and Irchel (canton Zurich) and Rechberg (Germany, 4 km from the border to Switzerland). All sites are abandoned gravel pits and at each site we collected between four and seven sediment samples. First results yielded chronologies between 0.8 and 2 Ma for these glaciofluvial deposits. Our study shows that this relatively new method is successful when the geological setting matches the methodological requirements.

  19. Detecting environmental change in estuaries: Nutrient and heavy metal distributions in sediment cores in estuaries from the Gulf of Finland, Baltic Sea

    NASA Astrophysics Data System (ADS)

    Vaalgamaa, S.; Conley, D. J.

    2008-01-01

    Historical sediment nutrient concentrations and heavy metal distributions were studied in four estuaries in the Gulf of Finland, Baltic Sea to examine the response of these estuaries to temporal changes in human activities. Cores were collected using a 1-m Mackereth corer and dated using 210Pb and 137Cs. The cores were analyzed for total carbon (TC), total nitrogen (TN), total phosphorus (TP), organic phosphorus (OP), inorganic phosphorus (IP), biogenic silica (BSi), loss-on-ignition (LOI), Cu, Zn, Al, Fe, Mn, K, Ca, Mg and Na. Principal component analysis (PCA) was used to summarize the trends in the chemical variables and to compare the trends at the different sites. Applying the 1986 137Cs date as a reference point, 210Pb chronologies were constructed for the sites using either the CRS model or a composite model (using both CIC and CRS). Significant increases were observed in sedimentation rates, TP and TN concentrations in all of the cores. Copper showed clear increases from 1850 towards present at all sites. Furthermore, redundancy analysis (RDA) was used to correlate environmental variables (catchment land use, catchment size, estuary surface area, depth and lake percentage) to sediment geochemistry. Based on redundancy analysis (RDA), the percentage of agriculture in the catchment was the most important factor affecting the sediment accumulation rate. Urban land-use types and industry correlate well with sediment Cu and Ca concentrations. Forest areas were related to high sediment BSi concentrations. Catchment land use was the most significant factor affecting sediment geochemical composition and sediment accumulation rates in these coastal embayments. Our results demonstrate that the coastal estuaries of the Gulf of Finland respond to the increased nutrient loading with the increased sedimentation and nutrient accumulation rates.

  20. Dating Plio-Pleistocene glacial sediments using the cosmic-ray-produced radionuclides 10Be and 26Al

    USGS Publications Warehouse

    Balco, G.; Stone, J.O.H.; Jennings, C.

    2005-01-01

    We use the cosmic-ray-produced radionuclides 26Al and 10Be to date Plio-Pleistocene glacial sediment sequences. These two nuclides are produced in quartz at a fixed ratio, but have different decay constants. If a sample is exposed at the surface for a time and then buried by overburden and thus removed from the cosmic-ray flux, the 26Al/10Be ratio is related to the duration of burial. We first attempted to date pre-Wisconsinan tills by measuring 26Al and 10Be in fluvial sediments beneath them and applying the method of "burial dating," which previous authors have used to date river sediment carried into caves. This method, however, requires simplifying assumptions about the 26Al and 10Be concentrations in the sediment at the time of burial. We show that these assumptions are not valid for river sediment in glaciated regions. 26Al and 10Be analyses of such sediment do not provide accurate ages for these tills, although they do yield limiting ages in some cases. We overcome this difficulty by instead measuring 26Al and 10Be in quartz from paleosols that are buried by tills. We use a more general mathematical approach to determine the initial nuclide concentrations in the paleosol at the time it was buried, as well as the duration of burial. This technique provides a widely applicable improvement on other means of dating Plio-Pleistocene terrestrial glacial sediments, as well as a framework for applying cosmogenic-nuclide dating techniques in complicated stratigraphic settings. We apply it to pre-Wisconsinan glacial sediment sequences in southwest Minnesota and eastern South Dakota. Pre-Wisconsinan tills underlying the Minnesota River Valley were deposited 0.5 to 1.5 Ma, and tills beneath the Prairie Coteau in eastern South Dakota and adjacent Minnesota were deposited 1 to 2 Ma.

  1. Butyltin compounds in a sediment core from the old Tilbury basin, London, UK.

    PubMed

    Scrimshaw, M D; Wahlen, R; Catterick, T; Lester, J N

    2005-12-01

    Sections from a sediment core taken from the River Thames were analysed for butyltin species using gas chromatography with species-specific isotope dilution mass spectrometry. Results demonstrated that in most samples tributyltin concentrations of 20-60 ng/g accounted for <10% of the total butyltin species present, which is in agreement with data from other sediment samples which were historically contaminated with tributyltin. Vertical distribution of the organotin residues with depth throughout the core, with data on organochlorine compounds and heavy metals allowed for the construction of a consistent hypothesis on historical deposition of contaminated sediments. From this it was possible to infer that the concentrations of tributyltin in sediments deposited during the early 1960s were in the order of 400-600 microg/g by using degradation rate constants derived by other workers. Such values fall well within the range quoted for harbour sediments in the literature. PMID:16040058

  2. Seasonal variation of methylmercury in sediment cores from the Tagus Estuary (Portugal).

    PubMed

    Monteiro, Carlos Eduardo; Cesário, Rute; O'Driscoll, Nelson J; Nogueira, Marta; Válega, Mónica; Caetano, Miguel; Canário, João

    2016-03-15

    Seasonal and spatial variations of dissolved and particulate methylmercury were evaluated for the first time in sediment cores from the Tagus Estuary. Results showed the highest MeHg concentrations in summer months indicating that the "seasonally" methylation process occurs not only at the topmost layers of the sediments but also in the deeper layers of the sediment column. The proportion of MeHg (up to 92%) in some of our pore water samples was higher than values reported in the literature for other estuaries suggesting that the sedimentary environment in the Tagus tends to favour Hg methylation. This work points to the importance of seasonal variation of the MeHg production in sediment cores. In physically dominated estuaries this enhances seasonal MeHg production in deeper sediments that can have serious ecological impacts due to resuspension or advection processes under extreme events by the increase of MeHg transported to the water column. PMID:26851871

  3. Influence of sampling on magnetic susceptibility anisotropy of soft sediments: comparison between gravity and piston cores

    NASA Astrophysics Data System (ADS)

    Shimono, Takaya; Yamazaki, Toshitsugu; Inoue, Seiko

    2014-12-01

    Anisotropy of magnetic susceptibility (AMS) has been used extensively for determining mineral orientatrections. In terms of the sample coordinate, K max declinations in the three gravity cores are oriented along the core-splitting surface, whereas K max declinations in the three piston cores are perpendicular to the splitting surface. We attribute the artificial AMS to the stress created by the deformation of core liners when being split. When interpreting AMS data from sediment cores, it is necessary to investigate the influence of sampling using the sample coordinates. In this paper, we also report over-sampling and under-sampling of piston cores from a comparison of down-core magnetic susceptibility variations between piston and gravity cores. It is noteworthy that under-sampling as well as over-sampling can occur in the uppermost few meters of piston cores.

  4. An assessment of the utility of optically-stimulated luminescence to date sediments from Lakes Malawi, Bosumtwi, and Tanganyika, Africa

    NASA Astrophysics Data System (ADS)

    Gomez, J.; Forman, S. L.; Pierson, J.; Scholz, C.; Peck, J.; Heil, C.; King, J.; Shanahan, T.; Overpeck, J.; Koeberl, C.; Milkereit, B.

    2005-12-01

    An exciting recent development in geochronology is the advent of optically-stimulated luminescence (OSL) for dating late Quaternary sediments. OSL signal of mineral grains is reset by exposure to sunlight prior to deposition and a time-sensitive charge is acquired from exposure to ionizing radiation post burial. The OSL signal is highly sensitive to solar resetting, with background counts rendered after few minutes of sunlight exposure. OSL geochronology can yield decadal resolution in the past 1000 years, a period of limited precision for radiocarbon dating and potentially date sediment spanning the past 200 to 400 ka. Nearly continuous sedimentary records from African lakes provide unparalleled opportunities to develop new OSL dating approaches to constrain hydro-climatic events in the tropics. A variety of OSL geochronologic approaches are attempted for sediments from Lakes Malawi, Bosumtwi and Tanganyika providing an internal test of reproducibility. Accuracy is assessed by OSL dating levels with radiocarbon ages and with correlated chronologic control e.g. from the sediment magnetic signature or sediment carbon to atmosphere methane relations. The fine-grained (3-11 micron) polymineral and quartz fractions and for coarser levels the quartz fine sand is extracted for dating. Additive and regenerative dose procedures using multiple and single aliquots under blue, green and infrared light exposure are used to estimate the post-burial paleodose. A regenerative procedure with dose normalization and stepped preheating (140-180° C) provides a particularly robust approach for dating sediments greater than 75 ka. OSL emissions for sediment from Lake Malawi for the past ca. 100 ka are not at saturated dose and are amenable for dating by a variety of methods. In contrast sediments from Lake Bosumtwi, with a probable Sahel dust source, exhibit saturation in OSL signal for sediments ca. 100 ka old, necessitating the using of regenerative approaches. The concordance

  5. Historical trends in Chesapeake Bay dissolved oxygen based on benthic foraminifera from sediment cores

    USGS Publications Warehouse

    Karlsen, A.W.; Cronin, T. M.; Ishmans, S.E.; Willard, D.A.; Kerhin, R.; Holmes, C.W.; Marot, M.

    2000-01-01

    Environmentally sensitive benthic foraminifera (protists) from Chesapeake Bay were used as bioindicators to estimate the timing and degree of changes in dissolved oxygen (DO) over the past five centuries. Living foraminifers from 19 surface samples and fossil assemblages from 11 sediment cores dated by 210Pb, 137Cs, 14C, and pollen stratigraphy were analyzed from the tidal portions of the Patuxent, Potomac, and Choptank Rivers and the main channel of the Chesapeake Bay. Ammonia parkinsoniana, a facultative anaerobe tolerant of periodic anoxic conditions, comprises an average of 74% of modern Chesapeake foraminiferal assemblages (DO = 0.47 and 1.72 ml l-1) compared to 0% to 15% of assemblages collected in the 1960s. Paleoecological analyses show that A. parkinsoniana was absent prior to the late 17th century, increased to 10-25% relative frequency between approximately 1670-1720 and 1810-1900, and became the dominant (60-90%) benthic foraminiferal species in channel environments beginning in the early 1970s. Since the 1970s, deformed tests of A. parkinsoniana occur in all cores (10-20% of Ammonia), suggesting unprecedented stressful benthic conditions. These cores indicate that prior to the late 17th century, there was limited oxygen depletion. During the past 200 years, decadal scale variability in oxygen depletion has occurred, as dysoxic (DO = 0.1-1.0 ml l-1), perhaps short-term anoxic (DO < 0.1 ml l-1) conditions developed. The most extensive (spatially and temporally) anoxlc conditions were reached during the 1970s. Over decadal timescales, DO variability seems to be linked closely to climatological factors influencing river discharge; the unprecedented anoxia since the early 1970s is attributed mainly to high freshwater flow and to an increase in nutrient concentrations from the watershed.

  6. Chemical composition of short sediment cores from Thermaikos Gulf (Eastern Mediterranean): Sediment accumulation rates, trawling and winnowing effects

    NASA Astrophysics Data System (ADS)

    Karageorgis, A. P.; Kaberi, H.; Price, N. B.; Muir, G. K. P.; Pates, J. M.; Lykousis, V.

    2005-12-01

    Four cores recovered within the framework of the INTERPOL Project have been analysed for their grain size and geochemistry; sediment accumulation rates (SARs) were also determined from 210Pb and 137Cs profiles. Two cores are representative of the Axios and Aliakmon Rivers depositional environment, whilst the third core represents the Pinios River province; the fourth core represents an environment of outer shelf relict sands. Apparent SARs ranged between 0.667 g cm -2 yr -1 (Axios and Aliakmon Rivers) and 0.414 g cm -2 yr -1 (Pinios River). Trawling activities and biomixing are critical processes that may be responsible for the mixing of the surface sediments, as observed from the excess 210Pb profiles. The thickness of the surface mixed layer was 4.5 cm in the vicinity of Axios and Aliakmon Rivers and in the area of Pinios River, 3.75 cm on the outer shelf and 1 cm in the area where no trawling was observed. Sediment accumulation appeared to be regulated by variations in the riverine discharge, shelf transport pathways and winnowing processes. Major element variations, such as Si, Al, Ti, V and Ni, were dominated by terrigenous supply as aluminosilicate minerals and quartz, whereas most Ca and Sr were biogenic. Si/Al and Ca/Al ratios have been used to express changes in sediment accumulation and winnowing. Redox processes were depicted by Mn, which showed an increase in the depth of its redoxcline, from ˜1 cm in inshore stations to ˜2 cm on the outer shelf. Si/Al ratios follow the Ca/Al ratios and can be used to assess percentage winnowing in the sediment. Increases in these ratios indicate a decrease in sediment input rates and are seen in the upper parts of most of the cores. Anthropogenic or 'excess' metal contents have been calculated from Zn/V and Pb/V ratios. Their distributions in the cores showed that by far the highest contamination is associated with the Axios River output, whilst sediments influenced by the Pinios River were relatively uncontaminated.

  7. Sediment Core Extrusion Method at Millimeter Resolution Using a Calibrated, Threaded-rod.

    PubMed

    Schwing, Patrick T; Romero, Isabel C; Larson, Rebekka A; O'Malley, Bryan J; Fridrik, Erika E; Goddard, Ethan A; Brooks, Gregg R; Hastings, David W; Rosenheim, Brad E; Hollander, David J; Grant, Guy; Mulhollan, Jim

    2016-01-01

    Aquatic sediment core subsampling is commonly performed at cm or half-cm resolution. Depending on the sedimentation rate and depositional environment, this resolution provides records at the annual to decadal scale, at best. An extrusion method, using a calibrated, threaded-rod is presented here, which allows for millimeter-scale subsampling of aquatic sediment cores of varying diameters. Millimeter scale subsampling allows for sub-annual to monthly analysis of the sedimentary record, an order of magnitude higher than typical sampling schemes. The extruder consists of a 2 m aluminum frame and base, two core tube clamps, a threaded-rod, and a 1 m piston. The sediment core is placed above the piston and clamped to the frame. An acrylic sampling collar is affixed to the upper 5 cm of the core tube and provides a platform from which to extract sub-samples. The piston is rotated around the threaded-rod at calibrated intervals and gently pushes the sediment out the top of the core tube. The sediment is then isolated into the sampling collar and placed into an appropriate sampling vessel (e.g., jar or bag). This method also preserves the unconsolidated samples (i.e., high pore water content) at the surface, providing a consistent sampling volume. This mm scale extrusion method was applied to cores collected in the northern Gulf of Mexico following the Deepwater Horizon submarine oil release. Evidence suggests that it is necessary to sample at the mm scale to fully characterize events that occur on the monthly time-scale for continental slope sediments. PMID:27585268

  8. Polarization study on solid core photonic crystal fibers partially sedimented with polyethylene micro-spheres and carbon nanotubes

    NASA Astrophysics Data System (ADS)

    Pérez-Chimal, R. Janette; Mata-Chávez, Ruth I.; Estudillo-Ayala, J. M.; Vargas-Rodríguez, E.; Alvarado-Méndez, E.; Rojas-Laguna, R.

    2010-10-01

    We present an experimental study of light polarization on solid core microstructured optical fibers type (Large Mode Area) LMA-16, LMA-20 and LMA-25. These fibers were partially filled with one micron diameter polyethylene spheres or carbon nanotubes diluted in distilled H2O by capillarity. Polarization characterization was realized on these Photonic Crystal fibers with air filled holes and partially particle filled holes using a He-Ne 633nm central wavelength laser at 10mW. The achieved results were compared using graphical data of every test collected at different exposition dates where the fiber was exposed to particle sedimentation. Results depicted that short time sedimentation of these particles does not change the light polarization leaving from the fiber except for the phase of the beam. On the other hand, longer time particle exposition visibly changes the light phase measured at the end of the photonic crystal fiber with repeatable results.

  9. The preglacial sediment record of Lake Ladoga, Russia - first results from a seismic survey and sediment coring in 2013

    NASA Astrophysics Data System (ADS)

    Melles, Martin; Krastel, Sebastian; Fedorov, Grigory; Subetto, Dmitry A.; Savelieva, Larisa A.; Andreev, Andrej; Wagner, Bernd

    2014-05-01

    The new German-Russian project PLOT (Paleolimnological Transect) aims at investigating the Late Quaternary climatic and environmental history along a more than 6000 km long longitudinal transect crossing northern Eurasia. Special emphasis is put on the preglacial history. For this purpose shallow and deep seismic surveys shall be carried out on five lakes, which potentially host preglacial sediment records, followed by sediment coring based on the results of the seismic campaigns. The well-studied Lake El'gygytgyn represents the eastern-most location of the transect and acts as reference site. Within the scope of a pilot phase for the PLOT project, funded by the German Federal Ministry of Education and Research, we were able to investigate Lake Ladoga, which is located close to St. Petersburg at the western end of the transect. Lake Ladoga is the largest lake in Europe, covering an area of almost 18.000 km2. The modern sedimentation as well as the late glacial and Holocene history of the lake were already studied in detail over the past decades. The older, preglacial lake history, however, is only rudimentary known from a core transect drilled in the southern lake in the 1930th. The cores of up to about 60 m length were only briefly described and are not existing any more. The results from these cores, known from unpublished reports only, suggest the existence of marine sediments of presumably Eemian age, representing a time when Lake Lagoga was part of a precursor of the Baltic Sea, which had a connection via Ladoga and Onega Lakes to the White Sea and further to the Arctic Ocean. In late August/early September 2013 we carried out a seismic survey on Lake Ladoga using a Mini-GI-Gun and a 32-channel seismic streamer. In total, 1500 km of seismic profiles were measured, covering most parts of the lake. The seismic lines typically show acoustically well stratified Holocene muds overlaying rather transparent postglacial varves. These sediment successions can reach

  10. Tephrostratigraphic studies on a sediment core from Lake Prespa in the Balkans

    NASA Astrophysics Data System (ADS)

    Damaschke, M.; Sulpizio, R.; Zanchetta, G.; Wagner, B.; Böhm, A.; Nowaczyk, N.; Rethemeyer, J.; Hilgers, A.

    2013-01-01

    A detailed tephrostratigraphic record, which dates back to Marine Isotope Stage (MIS) 5b (ca. 91 kyr), has been established from a 17.76 m long core (Co1215) from Lake Prespa (Macedonia, Albania and Greece). A total of eleven tephra and cryptotephra layers (PT0915-1 to PT0915-11) were identified, using XRF scanning, magnetic susceptibility measurements, and macro- and microscopic inspection of the sediments. The major element composition of glass shards and/or micro-pumice fragments indicates that the tephras and cryptotephras originate from the explosive volcanism of Italy. Eight tephra and cryptotephra layers were correlated with specific volcanic eruptions: the AD 512 eruption of Somma-Vesuvius (1438 cal yr BP), the Mercato eruption of Somma-Vesuvius (8890 ± 90 cal yr BP), the Tufi Biancastri/LN1-LN2 eruption of the Campi Flegrei (14 749 ± 523 cal yr BP and 15 551 ± 621 cal yr BP), the SMP1-e/Y-3 eruption of the Campi Flegrei (30 000-31 000 cal yr BP), the Campanian Ignimbrite/Y-5 eruption of the Campi Flegrei (39 280 ± 110 cal yr BP), the SMP1-a event of Ischia Island (around 44 000 cal yr BP) and the Green Tuff/Y-6 eruption of Pantelleria Island (around 45 000 cal yr BP). One tephra could be attributed to the volcanic activity of Mount Etna, but probably represents an unknown eruption at ca. 60 000 cal yr BP. Cryptotephras PT0915-6 and PT0915-10 remain unclassified so far, but according to the presented age-depth model these would have been deposited around 35 000 and 48 500 cal yr BP, respectively. Some of the tephras and cryptotephras are recognised for the first time in the Balkan region. The tephrostratigraphic work provides important information about ash dispersal and explosion patterns of source volcanoes and can be used to correlate and date geographically distant paleoenvironmental and archaeological archives in the central Mediterranean region. Moreover, the tephrostratigraphic work in combination with radiocarbon and electron spin resonance (ESR

  11. Temporal trends of nonylphenol and bisphenol A contamination in the Pearl River Estuary and the adjacent South China Sea recorded by dated sedimentary cores.

    PubMed

    Peng, Xianzhi; Wang, Zhendi; Mai, Bixian; Chen, Fanrong; Chen, Shejun; Tan, Jianhua; Yu, Yiyi; Tang, Caiming; Li, Kechang; Zhang, Gan; Yang, Chun

    2007-10-01

    Three dated sedimentary cores were collected for the investigation of temporal trends and the environmental loadings of nonylphenol (NP) and bisphenol A (BPA) in recent decades in the Pearl River Estuary (PRE), South China and the adjacent South China Sea (SCS). The peak fluxes of NP and BPA occurred in the mid-1980s in the PRE, coincident with the rapid economic growth in China. The decline of NP and BPA fluxes is attributable to the implementation of sewage treatment in the late 1980s in the Pearl River Delta (PRD). Multi-model distributions were observed for the fluxes of NP and BPA in the SCS with the peak fluxes occurring in the late 1950s and the mid-1970s respectively. The fluxes of NP and BPA have increased since the 1990s due to the lack of adequate wastewater treatment facilities and the constant economic growth. Nonylphenol was quantifiably detected in sediments predating its widespread application (1940s), suggesting the downward penetration of NP in the sediment columns. The characterization results revealed that NP and BPA were preserved well and the isomer-selective degradation of NP did not occur significantly in the sediment cores. The environmental loadings of NP and BPA in the PRE sediments were roughly estimated to be 124 t and 1.7 t respectively over the past 30 years. PMID:17618676

  12. Geochemical assessment of metal concentrations in sediment core of Korangi Creek along Karachi Coast, Pakistan.

    PubMed

    Chaudhary, M Z; Ahmad, N; Mashiatullah, A; Ahmad, N; Ghaffar, A

    2013-08-01

    Sediment core from Korangi Creek, one of the polluted coastal locations along the Karachi Coast Pakistan, was collected to trace the history of marine pollution and to determine the impact of industrial activity in the area. Down core variation of metals such as Ca, K, Mg, Al, S, Ti, V, Cr, Mn, Fe, Ni, Cu and Zn was studied in the 72.0 cm core. Nuclear analytical techniques, proton induced X-rays emission (PIXE), was employed to ascertain the chemical composition in sediment core. Grain size analysis and sediment composition of cored samples indicated that Korangi creek sediments are clayey in nature. Correlation matrix revealed a strong association of Ni, Cu, Cr and Zn with Fe and Mn. To infer anthropogenic input, enrichment factor (EF), degree of contamination and pollution load index were calculated. EF showed severe enrichment in surface sediment for Ni, Cu, Cr and Zn, indicating increased industrial effluents discharge in recent years. The study suggests that heavy metal discharge in the area should be regulated. If the present trend of enrichment is allowed to continue unabated, it is most likely that the local food web complexes in the creek might be at highest risk. PMID:23279880

  13. The multiproxy analysis of a lacustrine-palustrine sediment core from Lebanon reveals four climate cycles

    NASA Astrophysics Data System (ADS)

    Gasse, F. A.; van Campo, E.; Demory, F.; Develle, A.; Tachikawa, K.; Buchet, N.; Sonzogni, C.; Thouveny, N.; Bard, E. G.; Vidal, L.

    2013-12-01

    The study of a sediment core retrieved from the small Yammouneh basin (34.06°N-34.09°N, 36.0°E-36.03°E, 1360 m a.s.l.), Lebanon, provides for the first time a nearly continuous record spanning approximately 360 ka in northern Levant. The basin, located on the eastern flank of Mount Lebanon, is mainly supplied by karstic springs which discharge snowmelt water infiltrated through the western highlands. Part of its water inputs is lost by seepage through its faulted bottom. The core, 73 m long, consists of four whitish carbonated intervals rich in lacustrine organism remains, interrupting a thick accumulation of colored silty clays almost devoid of shells but for ostracods. We analyzed sediment features (mineralogical and elemental composition, light microscopy and SEM observations, grain size), magnetic properties, pollen and calcite oxygen isotopes (δc) derived from ostracod shell composition. The chronological framework is based on 14C ages of wood fragments, U/Th dating, and a high resolution reconstruction of relative paleointensity variations correlated with regional (Portuguese margin) and global (Sint-800) master curves down to about 360 ka. Although the chronology still needs improvement, the 3 upper carbonated intervals undoubtedly fit Interglacials MIS 1, MIS 5.5 and MIS 7, respectively. The deepest one (49-60 m) is assigned to MIS 9 by its proxy analogies with dated Interglacials. The sequence covers a large part of MIS 10. Relationships between individual indicators are explored, in addition to visual comparisons of individual records, from the multiproxy matrix after resampling at a common depth scale of 25 cm. We compute simple linear coefficients between 20 variables, perform Principal Component Analyses based on all variables, on terrestrial pollen biomes, on all sedimentological proxies, and cross-correlations between them and δc. During Interglacial maxima, high local and regional efficient moisture is evidenced by dense arboreal vegetation of

  14. Tephra in marine sediment cores offshore southern Iceland: A 68,000 year record of explosive volcanism

    NASA Astrophysics Data System (ADS)

    Bonanati, Christina; Wehrmann, Heidi; Portnyagin, Maxim; Hoernle, Kaj; Mirzaloo, Maryam; Nürnberg, Dirk

    2016-04-01

    Explosive volcanic eruptions on Iceland, even of intermediate magnitude have far-reaching impacts. Their far-distal deposits have been found up to Northern Continental Europe and Greenland. On Iceland, the harsh environment and strongly erosive conditions limit the preservation of volcanic deposits and their accessibility on land. The area offshore southern Iceland preserves information about the depositional fans at medial distance from the volcanic source. Here we use this sedimentary archive to reconstruct the Icelandic eruption record in greater detail. This high resolution geological record allows us to infer eruption frequencies and explosiveness in great detail and contributes to the assessment of Icelandic volcanic hazards, volcano-climate interaction, stratigraphy and palaeoceanographic reconstructions. Eight gravity cores were obtained during RV Poseidon Cruise 457, at 260 to 1,600 m water depths and distances of 130 to 400 km west to southeast of Iceland. The ˜4 to 10 m long sediment cores reach back to the Late Pleistocene (˜68 ka BP; dated by 14C and sedimentation rates), mostly excluding the Holocene. Potential tephra layers were identified by visual inspection and color scans. Volcanic glass shards were analyzed for their major element composition by electron microprobe and assigned to their eruptive source by geochemical fingerprinting. More than 50 primary tephra layers and nearly as many reworked layers were identified, several of which were correlated across the cores. The mostly basaltic tephra shards are derived from the Katla, Grímsvötn-Lakagígar, Bárðarbunga-Veiðivötn, and Hekla volcanic systems. Primary and mixed layers with particles of unique bimodal composition identical to the ˜12 ka BP Vedde-Tephra from the Katla Volcanic System, including rhyolitic particles, were identified in nearly all cores and used as time marker and for inter-core correlation. Tephra layers of unique unknown composition were also identified and

  15. Historical trends of organochlorine pesticides in a sediment core from the Gulf of Batabanó, Cuba.

    PubMed

    Alonso-Hernández, C M; Tolosa, I; Mesa-Albernas, M; Díaz-Asencio, M; Corcho-Alvarado, J A; Sánchez-Cabeza, J A

    2015-10-01

    Sediments can be natural archives to reconstruct the history of pollutant inputs into coastal areas. This is important to improve management strategies and evaluate the success of pollution control measurements. In this work, the vertical distribution of organochlorine pesticides (DDTs, Lindane, HCB, Heptachlor, Aldrin and Mirex) was determined in a sediment core collected from the Gulf of Batabanó, Cuba, which was dated by using the (210)Pb dating method and validated with the (239,240)Pu fallout peak. Results showed significant changes in sediment accumulation during the last 40 years: recent mass accumulation rates (0.321 g cm(-2) yr(-1)) double those estimated before 1970 (0.15 g cm(-2) yr(-1)). This change matches closely land use change in the region (intense deforestation and regulation of the Colon River in the late 1970s). Among pesticides, only DDTs isomers, Lindane and HCB were detected, and ranged from 0.029 to 0.374 ng g(-1) dw for DDTs, from<0.006 to 0.05 ng g(-1) dw for Lindane and from<0.04 to 0.134 ng g(-1) dw for HCB. Heptachlor, Aldrin and Mirex were below the detection limits (∼0.003 ng g(-1)), indicating that these compounds had a limited application in the Coloma watershed. Pesticide contamination was evident since the 1970s. DDTs and HCB records showed that management strategies, namely the banning the use of organochlorine contaminants, led to a concentration decline. However, Lindane, which was restricted in 1990, can still be found in the watershed. According to NOAA guidelines, pesticides concentrations encountered in these sediments are low and probably not having an adverse effect on sediment dwelling organisms. PMID:26051863

  16. Amino acid racemization analysis (AAR) as a successful tool for dating Holocene coastal sediments: Stratigraphy of a barrier island spit (Southern Sylt/North Sea)

    NASA Astrophysics Data System (ADS)

    Tillmann, Tanja; Ziehe, Daniel

    2014-05-01

    Dating of Holocene sediments in shallow coastal areas of the German North Sea by conventional techniques is commonly problematic. In particular the marine reservoir effect of radiocarbon means that radiocarbon dating cannot be applied to sediments younger than about 400 years. Amino acid racemization dating (AAR) is a viable alternative for dating young sediments. The method is based on the determination of ratios of D and L amino acid enantiomers in organic matrices of biogenic carbonates. In this study we use AAR as a tool for dating Holocene barrier islands sediments. Based on an AAR derived chronological framework we develop a model of barrier spit accretion which describes the interaction between extreme events, fair weather coastal processes and sedimentary development that constrains the major episodes of barrier island evolution. The stratigraphy was defined using ground-penetrating radar (GPR) surveys complemented by sedimentological coring data. The stratigraphy is then conceptualised in a AAR chronostratigraphic framework to define a chronological order and allow the development of a stratigraphic model of the evolution of Southern Sylt. The AAR data provide high temporal resolution and have been used for dating stages of barrier spit accretion. The time lines are marked as storm surge generated erosion unconformities in the stratigraphic profile. Individual shells and shell fragments of Cerastoderma edule, Mya arenaria, Mytilus edulis and Scrobicularia plana have been accumulated by short-term storm events as shell layers associated with the erosion unconformities and have been dated by AAR. Time lines reveal that the barrier spit accretion occurred episodically, and is dependant on the provided rate of sand delivery. The general trend is that sequences young to the. South. The AAR derived time lines have been verified and correlated by historic maps and sea charts. It is apparent that spit enlargement at this site increased significantly during the

  17. Visual-Stratigraphic Dating of the GISP2 Ice Core: Basis, Reproducibility, and Application

    NASA Technical Reports Server (NTRS)

    Alley, R. B.; Shuman, C. A.; Meese, D. A.; Gow, A. J.; Taylor, K. C.; Cuffey, K. M.; Fitzpatrick, J. J.; Grootes, P. M.; Zielinski, G. A.; Ram, M.; Spinelli, G.; Elder, B.

    1997-01-01

    Annual layers are visible in the Greenland Ice Sheet Project 2 ice core from central Greenland, allowing rapid dating of the core. Changes in bubble and grain structure caused by near-surface, primarily summertime formation of hoar complexes provide the main visible annual marker in the Holocene, and changes in "cloudiness" of the ice correlated with dustiness mark Wisconsinan annual cycles; both markers are evident and have been intercalibrated in early Holocene ice. Layer counts are reproducible between different workers and for one worker at different times, with 1% error over century-length times in the Holocene. Reproducibility is typically 5% in Wisconsinan ice-age ice and decreases with increasing age and depth. Cumulative ages from visible stratigraphy are not significantly different from independent ages of prominent events for ice older than the historical record and younger than approximately 50,000 years. Visible observations are not greatly degraded by "brittle ice" or many other core-quality problems, allowing construction of long, consistently sampled time series. High accuracy requires careful study of the core by dedicated observers.

  18. Provenance of Apollo 15 deep drill core sediments

    NASA Technical Reports Server (NTRS)

    Basu, A.; Bower, J. F.

    1977-01-01

    Modal analysis and electron probe microanalysis were performed on polished thin sections prepared from Apollo 15 deep drill core soils in an effort to characterize their provenance. The particles were in the 0.25-1.00 mm size range. The particles were classified into mineral fragments, agglutinates, glasses, rock fragments, and breccias. The results show that highland and mare material occur in the core in an approximately 60:40 ratio, with mare component generally increasing from bottom to top in the core. Quartz-normative basalts are nearly twice as abundant as olivine basalts. Nonmare sources include KREEP basalt flow units from some depth in the crust, excavated by cratering events and supplied to the site as 'rays'.

  19. A new dating method for Dome Fuji ice core using data assimilation

    NASA Astrophysics Data System (ADS)

    Suzuki, Kazue; Kawamura, Kenji; Nakano, Shin'ya; Nagao, Hiromichi; Abe-Ouchi, Ayako; Saito, Fuyuki; Higuchi, Tomoyuki; Parrenin, Frédéric

    2013-04-01

    Understanding of past climate changes is regarded as a key for predicting the future climate. In particular, ice cores have been providing excellent records of the past climatic and environmental changes. The second Dome Fuji deep ice core (DF2 core) was drilled to 3,035 m below surface, and the comparison of its isotopic record with that of EDC core suggests that the DF2 core reaches ~700 kyr ago. In order to accurately date the core, one needs good estimation of accumulation rate and thinning function especially in the deep part (within ~500 m from the bed corresponding to ~340-700 kyr ago). The thinning function, which results from the horizontal stretching and vertical compression of an ice layer, is a function of several factors such as depth, temperature, basal sliding and geothermal heat flux. Using Data Assimilation, we try to make a new dating method but based on the glaciological dynamics of Parrenin et al. (2004, 2007). Trough Kalman filter and smoothing method, we could gain a new tracking method for the age of ice. In this time, we treat the age of ice as an object for the data assimilation and we don't assimilate both of accumulation rates and thinning function individually. It is still in the experimental stage but we will introduce the method and indicate the results. The new method has an advantage in the speed for calculation of parameterizations over the other models. We will indicate the results of calculation times and the optimized parameters in comparison with the other models. From reductions of calculation times, we would be able to calculate sampling of larger members for parameterization using another data assimilation method like a particle filter which needs a huge cost of calculations. In the use of Kalman Filter, it is difficult to treat both of the accumulation rate and the thinning function as variable in the state space model because there is the exponential equation for the accumulation rate. We will design a new state space model

  20. Multivariate analysis of heavy metal contamination using river sediment cores of Nankan River, northern Taiwan

    NASA Astrophysics Data System (ADS)

    Lee, An-Sheng; Lu, Wei-Li; Huang, Jyh-Jaan; Chang, Queenie; Wei, Kuo-Yen; Lin, Chin-Jung; Liou, Sofia Ya Hsuan

    2016-04-01

    Through the geology and climate characteristic in Taiwan, generally rivers carry a lot of suspended particles. After these particles settled, they become sediments which are good sorbent for heavy metals in river system. Consequently, sediments can be found recording contamination footprint at low flow energy region, such as estuary. Seven sediment cores were collected along Nankan River, northern Taiwan, which is seriously contaminated by factory, household and agriculture input. Physico-chemical properties of these cores were derived from Itrax-XRF Core Scanner and grain size analysis. In order to interpret these complex data matrices, the multivariate statistical techniques (cluster analysis, factor analysis and discriminant analysis) were introduced to this study. Through the statistical determination, the result indicates four types of sediment. One of them represents contamination event which shows high concentration of Cu, Zn, Pb, Ni and Fe, and low concentration of Si and Zr. Furthermore, three possible contamination sources of this type of sediment were revealed by Factor Analysis. The combination of sediment analysis and multivariate statistical techniques used provides new insights into the contamination depositional history of Nankan River and could be similarly applied to other river systems to determine the scale of anthropogenic contamination.

  1. (129)I record of nuclear activities in marine sediment core from Jiaozhou Bay in China.

    PubMed

    Fan, Yukun; Hou, Xiaolin; Zhou, Weijian; Liu, Guangshan

    2016-04-01

    Iodine-129 has been used as a powerful tool for environmental tracing of human nuclear activities. In this work, a sediment core collected from Jiaozhou Bay, the east coast of China, in 2002 was analyzed for (129)I to investigate the influence of human nuclear activities in this region. Significantly enhanced (129)I level was observed in upper 70 cm of the sediment core, with peak values in the layer corresponding to 1957, 1964, 1974, 1986, and after 1990. The sources of (129)I and corresponding transport processes in this region are discussed, including nuclear weapons testing at the Pacific Proving Grounds, global fallout from a large numbers of nuclear weapon tests in 1963, the climax of Chinese nuclear weapons testing in the early 1970s, the Chernobyl accident in 1986, and long-distance dispersion of European reprocessing derived (129)I. The very well (129)I records of different human nuclear activities in the sediment core illustrate the potential application of (129)I in constraining ages and sedimentation rates of the recent sediment. The releases of (129)I from the European nuclear fuel reprocessing plants at La Hague (France) and Sellafield (UK) were found to dominate the inventory of (129)I in the Chinese sediments after 1990, not only the directly atmospheric releases of these reprocessing plants, but also re-emission of marine discharged (129)I of these reprocessing plants in the highly contaminated European seas. PMID:26821329

  2. Isochron-burial dating of glacially-driven sediments: first results from the Alps

    NASA Astrophysics Data System (ADS)

    Akçar, Naki; Ivy-Ochs, Susan; Alfimov, Vasily; Claude, Anne; Reber, Regina; Christl, Marcus; Vockenhuber, Christof; Schlunegger, Fritz; Dehnert, Andreas; Rahn, Meinert; Schlüchter, Christian

    2016-04-01

    The recently introduced method of isochron-burial dating, employs the fact that the samples from a well-defined single bed in a deposit would have the same post-burial but different pre-burial histories. The analysis of cosmogenic 10Be and 26Al in such samples enables the modeling of the post-burial component and the determination of the 26Al/10Be at the time of burial. The isochron-burial age can then be calculated from the initial and the measured ratios. In this study, we focus on the isochron-burial dating of the oldest Quaternary deposits of the Alpine Foreland. These are called Swiss Deckenschotter (cover gravels) as they build mesa-type hill tops on the Mesozoic or Cenozoic bedrock of the Swiss Alpine forelands. Deckenschotter consists of glaciofluvial gravel layers intercalated with glacial and/or overbank deposits. Although previously morphostratigraphically correlated with Günz and Mindel glaciations of Penck and Brückner, the Swiss Deckenschotter is likely much older, and their chronostratigraphy is not well constrained. In order to reconstruct the chronology of these deposits, we collected more than 30 clasts of different lithology, shape and size from a single stratigraphic horizon in an abandoned gravel pit in Siglistorf (canton Zurich). We processed 19 clasts for cosmogenic 10Be and 26Al. Four samples did not yield successful 26Al measurements and two were unsuccessful for 10Be. Most of the samples have low nuclide concentrations, i.e. <20000 10Be at/g and <150000 26Al at/g. Finally, using the 26Al/10Be ratio of the samples we calculated an isochron-burial age of around 1.5 Ma. Our results from this study indicate that glaciofluvial sediments can well be time-calibrated with isochron-burial dating despite the low cosmogenic nuclide concentrations.

  3. Initial Results on the Meteoritic Component of new Sediment Cores Containing Deposits of the Eltanin Impact Event

    NASA Technical Reports Server (NTRS)

    Kyte, Frank T.; Gersonde, Rainer; Kuhn, Gerhard

    2002-01-01

    The late Pliocene impact of the Eltanin asteroid is the only known asteroid impact in a deep- ocean (-5 km) basin . This was first discovered in 1981 as an Ir anomaly in sediment cores collected by the USNS Eltanin in 1965. In 1995, Polarstern expedition ANT XII/4 made the first geological survey of the suspected impact region. Three sediment cores sampled around the San Martin seamounts (approx. 57.5 S, 91 W) contained well-preserved impact deposits that include disturbed ocean sediments and meteoritic impact ejecta. The latter is composed of shock-melted asteroidal materials and unmelted meteorites. In 2001, the FS Polarstern returned to the impact area during expedition ANT XVIIU5a. At least 16 cores were recovered that contain ejecta deposits. These cores and geophysical data from the expedition can be used to map the effects of the impact over a region of about 80,000 square km. To date we have measured Ir concentrations in sediments from seven of the new cores and preliminary data should be available for a few more by the time of the meeting. Our initial interpretation of these data is that there is a region in the vicinity of the San Martin Seamounts comprising at least 20,000 square km in which the average amount of meteoritic material deposited was more than 1 g per square cm. This alone is enough material to support a 500 m asteroid. Beyond this is a region of about 60,000 square km, mostly to the north and west, where the amount of ejecta probably averages about 0.2 g per square cm. Another 400 km to the east, USNS Eltanin core E10-2 has about 0.05 g per square cm, so we know that ejecta probably occurs across more than a million square km of ocean floor. A key to future exploration of this impact is to find evidence of the ejecta at more sites distant from the seamounts. We currently have almost no data from regions to the west or south of the San Martin seamounts.

  4. Selected data for sediment cores collected in Chesapeake Bay in 1996 and 1998

    USGS Publications Warehouse

    Baucom, P.C.; Bratton, J.F.; Colman, Steven M.; Moore, Johnnie N.; King, John W.; Seal, Chip; Seal, R.R., II

    2001-01-01

    As part of a study of recent history of the Chesapeake Bay ecosystem, one- to eight- meter long sediment cores were obtained from the mesohaline section of the Chesapeake Bay between the mouths of the Potomac and Rhode Rivers. The sediments consist of three lithofacies: coarse-grained channel deposits, restricted-estuary sands and muds, and open-estuary muds. Water content, biogenic silica, magnetic susceptibility, trace metals, and nutrients (carbon, nitrogen, and their isotopes) were measured in the cores. Biogenic silica, trace-metal, and nutrient data provide a strong basis for discussing past primary productivity and water-column anoxia in the bay.

  5. Non-destructive X-ray Computed Tomography (XCT) Analysis of Sediment Variance in Marine Cores

    NASA Astrophysics Data System (ADS)

    Oti, E.; Polyak, L. V.; Dipre, G.; Sawyer, D.; Cook, A.

    2015-12-01

    Benthic activity within marine sediments can alter the physical properties of the sediment as well as indicate nutrient flux and ocean temperatures. We examine burrowing features in sediment cores from the western Arctic Ocean collected during the 2005 Healy-Oden TransArctic Expedition (HOTRAX) and from the Gulf of Mexico Integrated Ocean Drilling Program (IODP) Expedition 308. While traditional methods for studying bioturbation require physical dissection of the cores, we assess burrowing using an X-ray computed tomography (XCT) scanner. XCT noninvasively images the sediment cores in three dimensions and produces density sensitive images suitable for quantitative analysis. XCT units are recorded as Hounsfield Units (HU), where -999 is air, 0 is water, and 4000-5000 would be a higher density mineral, such as pyrite. We rely on the fundamental assumption that sediments are deposited horizontally, and we analyze the variance over each flat-lying slice. The variance describes the spread of pixel values over a slice. When sediments are reworked, drawing higher and lower density matrix into a layer, the variance increases. Examples of this can be seen in two slices in core 19H-3A from Site U1324 of IODP Expedition 308. The first slice, located 165.6 meters below sea floor consists of relatively undisturbed sediment. Because of this, the majority of the sediment values fall between 1406 and 1497 HU, thus giving the slice a comparatively small variance of 819.7. The second slice, located 166.1 meters below sea floor, features a lower density sediment matrix disturbed by burrow tubes and the inclusion of a high density mineral. As a result, the Hounsfield Units have a larger variance of 1,197.5, which is a result of sediment matrix values that range from 1220 to 1260 HU, the high-density mineral value of 1920 HU and the burrow tubes that range from 1300 to 1410 HU. Analyzing this variance allows us to observe changes in the sediment matrix and more specifically capture

  6. Permeability of sediment cores from methane hydrate deposit in the Eastern Nankai Trough, Japan

    NASA Astrophysics Data System (ADS)

    Konno, Y.; Yoneda, J.; Egawa, K.; Ito, T.; Jin, Y.; Kida, M.; Suzuki, K.; Nakatsuka, Y.; Nagao, J.

    2013-12-01

    Effective and absolute permeability are key parameters for gas production from methane-hydrate-bearing sandy sediments. Effective and/or absolute permeability have been measured using methane-hydrate-bearing sandy cores and clayey and silty cores recovered from Daini Atsumi Knoll in the Eastern Nankai Trough during the 2012 JOGMEC/JAPEX Pressure coring operation. Liquid-nitrogen-immersed cores were prepared by rapid depressurization of pressure cores recovered by a pressure coring system referred to as the Hybrid PCS. Cores were shaped cylindrically on a lathe with spraying of liquid nitrogen to prevent hydrate dissociation. Permeability was measured by a flooding test or a pressure relaxation method under near in-situ pressure and temperature conditions. Measured effective permeability of hydrate-bearing sediments is less than tens of md, which are order of magnitude less than absolute permeability. Absolute permeability of clayey cores is approximately tens of μd, which would perform a sealing function as cap rocks. Permeability reduction due to a swelling effect was observed for a silty core during flooding test of pure water mimicking hydrate-dissociation-water. Swelling effect may cause production formation damage especially at a later stage of gas production from methane hydrate deposits. This study was financially supported by the Research Consortium for Methane Hydrate Resources in Japan (MH21 Research Consortium) that carries out Japan's Methane Hydrate R&D Program conducted by the Ministry of Economy, Trade and Industry (METI).

  7. Characterization of sediment cores containing methane hydrate recovered from the Eastern Nankai Trough

    NASA Astrophysics Data System (ADS)

    Nagao, J.; Jin, Y.; Konno, Y.; Yoneda, J.; Egawa, K.; Ito, T.; Kida, M.; Nakatsuka, Y.; Suzuki, K.; Fujii, T.; Yamamoto, K.

    2013-12-01

    On the March 2013, Japan Oil, Gas and Metals National Corporation (JOGMEC) has conducted the first gas production test from methane hydrate deposits in the Nankai Trough offshore Japan. In the Eastern Nankai Trough area off the Pacific coast of Japan, highly concentrated methane hydrate deposits were discovered in Pleistocene turbidite sediments.. Along with geological information, structure and physical properties of the sediments are essential information to understand the nature and origin of the deposits, and preserving those in-situ values in core samples for laboratory testing on surface is a quite important scientific challenge. To solve the problem, JOGMEC and JAMSTEC have developed a pressure coring device and utilized it on D/V Chikyu for our coring operation before the production test. In this operation, we obtained two types of cores; one is the dissociation preserved core by rapidly cooled by emerging into liquid nitrogen (LN2 core), the other is stored in special pressure vessels without depressurizing and kept under original pressure and temperature (pressure core). Here the summary of LN2 core sample analyses, such as X-ray CT, p-wave velocity, particle analysis, permeability, mechanical properties, and gas composition, is presented. Also future analysis plan for pressure core is explained. This work was supported by funding from the Research Consortium for Methane Hydrate Resources in Japan (MH21 Research Consortium) planned by METI.

  8. Dating the Vostok ice core record by importing the Devils Hole chronology

    USGS Publications Warehouse

    Landwehr, J.M.; Winograd, I.J.

    2001-01-01

    The development of an accurate chronology for the Vostok record continues to be an open research question because these invaluable ice cores cannot be dated directly. Depth-to-age relationships have been developed using many different approaches, but published age estimates are inconsistent, even for major paleoclimatic events. We have developed a chronology for the Vostok deuterium paleotemperature record using a simple and objective algorithm to transfer ages of major paleoclimatic events from the radiometrically dated 500,000-year ??18O-paleotemperature record from Devils Hole, Nevada. The method is based only on a strong inference that major shifts in paleotemperature recorded at both locations occurred synchronously, consistent with an atmospheric teleconnection. The derived depth-to-age relationship conforms with the physics of ice compaction, and internally produces ages for climatic events 5.4 and 11.24 which are consistent with the externally assigned ages that the Vostok team needed to assume in order to derive their most recent chronology, GT4. Indeed, the resulting V-DH chronology is highly correlated with GT4 because of the unexpected correspondence even in the timing of second-order climatic events that were not constrained by the algorithm. Furthermore, the algorithm developed herein is not specific to this problem; rather, the procedure can be used whenever two paleoclimate records are proxies for the same physical phenomenon, and paleoclimatic conditions forcing the two records can be considered to have occurred contemporaneously. The ability of the algorithm to date the East Antarctic Dome Fuji core is also demonstrated.

  9. Paleomagnetism and environmental magnetism of GLAD800 sediment cores from Bear Lake, Utah and Idaho

    USGS Publications Warehouse

    Heil, C.W., Jr.; King, J.W.; Rosenbaum, J.G.; Reynolds, R.L.; Colman, Steven M.

    2009-01-01

    A ???220,000-year record recovered in a 120-m-long sediment core from Bear Lake, Utah and Idaho, provides an opportunity to reconstruct climate change in the Great Basin and compare it with global climate records. Paleomagnetic data exhibit a geomagnetic feature that possibly occurred during the Laschamp excursion (ca. 40 ka). Although the feature does not exhibit excursional behavior (???40?? departure from the expected value), it might provide an additional age constraint for the sequence. Temporal changes in salinity, which are likely related to changes in freshwater input (mainly through the Bear River) or evaporation, are indicated by variations in mineral magnetic properties. These changes are represented by intervals with preserved detrital Fe-oxide minerals and with varying degrees of diagenetic alteration, including sulfidization. On the basis of these changes, the Bear Lake sequence is divided into seven mineral magnetic zones. The differing magnetic mineralogies among these zones reflect changes in deposition, preservation, and formation of magnetic phases related to factors such as lake level, river input, and water chemistry. The occurrence of greigite and pyrite in the lake sediments corresponds to periods of higher salinity. Pyrite is most abundant in intervals of highest salinity, suggesting that the extent of sulfidization is limited by the availability of SO42-. During MIS 2 (zone II), Bear Lake transgressed to capture the Bear River, resulting in deposition of glacially derived hematite-rich detritus from the Uinta Mountains. Millennial-scale variations in the hematite content of Bear Lake sediments during the last glacial maximum (zone II) resemble Dansgaard-Oeschger (D-O) oscillations and Heinrich events (within dating uncertainties), suggesting that the influence of millennial-scale climate oscillations can extend beyond the North Atlantic and influence climate of the Great Basin. The magnetic mineralogy of zones IV-VII (MIS 5, 6, and 7

  10. Using Cyclic Variations Of Early Pliocene Diatom Assemblages To Determine Sediment Accumulation Rates In The ANDRILL AND-1B Core

    NASA Astrophysics Data System (ADS)

    Konfirst, M. A.; Scherer, R. P.; Monien, D.; Kuhn, G.; Winter, D.; Sjunneskog, C. M.

    2009-12-01

    In the 2006-2007 Antarctic field season, the ANDRILL MIS project recovered a 1,285m record of Miocene through Plio-Pleistocene sediments near Ross Island in the Ross Sea region of Antarctica. Diatom biostratigraphy, radiometric dating and magnetostratigraphy were used in conjunction with the evaluation of glacial surfaces of erosion (GSEs) to produce a well-constrained age model for the core. However, within the Plio-Pleistocene interval (the upper ~620m), the ANDRILL record also included 13 discrete intervals composed of nearly pure diatomite, the longest of which is over 80m thick. The lack of GSEs during periods of high diatom accumulation has created limitations in assigning ages to specific core depths within the diatomite intervals. In this study, data were collected on abundance of key diatom species present within 290 samples from the long Early Pliocene diatomite unit (DU XI- 363.37-459.24 mbsf) as well as ~15m of diatom-rich mudstone immediately overlying it. We analyzed diatom records at high resolution (as high as ca. 600 year sample interval, according to the chronostratigraphic correlations established by this study). This approximately 100m section was then subdivided into five units based on major diatom assemblage shifts and changes in both geochemical properties and clast abundance counts (Pompilio et al., 2007). Cyclic changes in relative diatom abundance were identified within each unit using characteristic species and matched to variations in the oxygen isotope record (Lisiecki & Raymo, 2005) using the chronostratigraphic framework established by Naish et al. (2007), which included the assignment of an oxygen isotope age to specific core depths. Additionally, the core ages provided by the correlation of diatom abundance with the isotope record allowed the calculation of sediment accumulation rates through the interval. The results presented here provide a further refinement to the ANDRILL age model and allow interpretation of the interaction

  11. Hexabromocyclododecanes in surface sediments and a sediment core from Rivers and Harbor in the northern Chinese city of Tianjin.

    PubMed

    Zhang, Yanwei; Ruan, Yuefei; Sun, Hongwen; Zhao, Lijie; Gan, Zhiwei

    2013-02-01

    In the present study, hexabromocyclododecanes (HBCDs) were investigated in the sediment from Haihe River (HR), Dagu Dainage Canal (DDC) and Tianjin Harbor (TH) at Bohai Bay using a total of 51 samples of surface sediments and a sediment core collected from May to September in 2010, and its diastereomer- and enantiomer-specific profiles were analyzed. The concentration of total HBCDs were generally high, with mean value and ranges of 31.0 and 1.35-634 ng g(-1)dw, respectively. The contamination followed the order of TH>DDC>HR. Higher levels (up to 634 ng g(-1)dw) occurred in the lower reach of HR and DDC located in an industrial area of Tianjin. This is the first time to report so high concentration of HBCDs in sediment in Southeast Asia. The γ-diastereomer dominated in most samples (44 out of 51), and this is in agreement with the diastereomer distribution pattern in industrial products, while α-HBCD was the dominant diastereomer in the other seven samples. However, only few samples exhibited γ-diastereomer ratio similar to that (75-89%) in technical products, indicating the inter-transformation and variable degradation of the different isomers. The high ratio of γ-diastereomer could be used as an indicator for fresh contamination input. Enantiomeric factors (EFs) of HBCD isomers in most of the samples were statistically different from technical products (p<0.05), showing a trend of more easily enrichment of the (-)-HBCD-enantiomer compared to the (+)-HBCD-enantiomer. The δ- and ε-diastereomers were frequently detected but at low level. The HBCDs in the sediment core showed several peaks, and the greatest value occurred in 2005, when a plastic manufacture plant using HBCD was set up nearby. PMID:23062943

  12. Chromium geochemistry of serpentinous sediment in the Willow core, Santa Clara County, California

    USGS Publications Warehouse

    Oze, Christopher J.; LaForce, Matthew J.; Wentworth, Carl M.; Hanson, Randall T.; Bird, Dennis K.; Coleman, Robert G.

    2003-01-01

    A preliminary investigation of Cr geochemistry in serpentinous sediment completed for a multiple-aquifer ground-water monitoring well (Willow core of Santa Clara County, CA) determined sediment at depths >225 meters contains Cr concentrations ranging from 195 to 1155 mg/kg. Serpentinous sediment from this site is a potential source of non-anthropogenic Cr contamination. Chromium-bearing minerals such as Cr-spinel appear to be the main source of Cr in the sediment; however, Cr-bearing silicates and clay minerals are additional Cr sources. Aqueous Cr concentrations in the sediment are <4.6 mg/L; however, the valence of Cr was not identified in the solutions or in the sediment. Although there is no indication of Cr(VI) contamination derived from the serpentinous sediment, elevated Cr concentrations in the sediment, the observed ‘dissolution’ textures of the Cr-bearing minerals, the estimated redox environment, and water chemistry indicate the formation of Cr(VI) is potentially favorable.

  13. DDTs and HCHs in sediment cores from the coastal East China Sea.

    PubMed

    Lin, Tian; Nizzetto, Luca; Guo, Zhigang; Li, Yuanyuan; Li, Jun; Zhang, Gan

    2016-01-01

    Four sediment cores were collected along the Yangtze-derived sediment transport pathway in the inner shelf of the East China Sea (ECS) for OCP analysis. The sediment records of HCHs and DDTs in estuarine environment reflected remobilization of chemicals from enhanced soil erosion associated to extreme flood events or large scale land use transformation. The sediment records in the open sea, instead, reflected long-term historical trends of OCP application in the source region. Unlike the so-called mud wedge distribution of sediment, inventories of HCHs and DDTs slightly increased from the mouth of Yangtze River alongshore toward south, suggesting the sediment deposition rate was one of factors on the exposure of chemicals within the inner shelf of the ECS. Re-suspension and transport of the Yangtze-derived sediment and consequent fractionation in grain size and TOC were also responsible for the spatial variation of inventories of catchment derived OCPs in a major repository area of the Yangtze suspended sediment. The total burdens of HCHs and DDTs in the inner shelf of the ECS were 35tons and 110tons, respectively. After 1983 (year of the official ban in China), those values were 13tons and 50tons, respectively. It appears that the Yangtze still delivers relatively high inputs of DDTs more than 30years after the official ban. High proportions of DDD+DDE and β-HCH suggested those OCPs mainly originated from historical usage in the catchment recent years. PMID:26372941

  14. Toxicity of sediment cores from Yangtze River estuary to zebrafish (Danio rerio) embryos.

    PubMed

    Wang, Peipei; Zhang, Lili; Liu, Li; Chen, Ling; Gao, Hongwen; Wu, Lingling

    2015-11-01

    Toxicity evaluation is an important segment in sediment quality monitoring in order to protect aquatic organisms and human health. The purpose of this study is to assess the toxicity of sediments from three sediment cores in Yangtze River Estuary, China, using the zebrafish (Danio rerio) embryo tests. Fertilized zebrafish eggs were exposed to both whole sediments and sediment organic extracts prepared from collected sediments, in order to provide a comprehensive and realistic insight into the bioavailable toxicity potential of the sediments. As end points, development parameters (mortality, hatching rate, and abnormality) in the developing embryos were recorded during the 96-h exposure. The results showed that some samples increased mortality, inhibited the hatching of embryos, and induced morphological abnormalities. The embryonic toxicities presented serrated changes and irregular distribution with depth, which may be related to hydrodynamic effect and unstable environmental input. However, lethal and sub-lethal effects were more significant at the sub-surface sediments (10∼40 cm), which indicated that the pollution is more serious in recent decades. PMID:25163567

  15. Structural identification of long-chain polyamines associated with diatom biosilica in a Southern Ocean sediment core

    NASA Astrophysics Data System (ADS)

    Bridoux, Maxime C.; Ingalls, Anitra E.

    2010-07-01

    Long-chain polyamines (LCPAs) constitute a new family of natural organic compounds that have recently been isolated and characterized from the biosilicified cell walls of diatom cultures. To date, diatom-specific polyamines have not been investigated from the marine environment and their fate in the environment is entirely unknown. Here, we report a series of LCPAs in a diatom frustule-rich sediment core (TNO57-13 PC4), originating from the Atlantic sector of the Southern Ocean and spanning from the Holocene to the Last Glacial Maximum (LGM). Liquid chromatography with electrospray ionization mass spectrometry (LC-ESI-MS) revealed a complex mixture of linear polyamines with at least 28 individual molecular species. Ion trap mass fragmentation studies, combined with high resolution Time of Flight (TOF) mass spectrometry showed that the polyamine pool consisted of a series of N-methylated propylamine compounds attached to a putrescine moiety, with individual LCPAs varying in chain length and degree of methylation. The structural similarity between LCPAs extracted from the diatom-rich sediment core and those extracted from the frustules of cultured diatoms suggests that sedimentary LCPAs are derived from diatom frustules. We hypothesize that these intrinsically labile organic molecular fossils are protected from diagenesis by encapsulation within the frustule. These compounds constitute a new class of biomarkers that could potentially be indicators of diatom species distribution. Isotopic analysis of LCPAs could be used to improve age models for sediment cores that lack calcium carbonate and to improve current interpretations of diatom-based paleoproxies, including diatom-bound nitrogen isotopes.

  16. Bioavailability of polycyclic aromatic hydrocarbons from a historically contaminated sediment core

    SciTech Connect

    Harkey, G.A.; Van Hoof, P.L.; Landrum, P.F.

    1995-09-01

    To determine changes in bioavailability of selected polycyclic aromatic hydrocarbons (PAHs) with sediment aging, Lumbriculus variegatus were exposed for 4 weeks to sediment core sections taken from a contaminated lake. Core depths included surficial (0 to 4 cm), 4- to 8-, 12- to 16-, 28- to 32-, and 44- to 48-cm sections deposited for approximately 1899 to 1993, and were known to be historically contaminated with PAHs. Bioaccumulation was maximal at the 12- to 16-cm depth (circa 1967) where sediment PAH concentrations were greatest. Accumulation was generally below detection limits in the 0- to 4-cm depths, even though sediment concentrations of some compounds were comparable to those at the 12- to 16-cm depth where accumulation was great enough to generate accurate kinetics curves. Accumulation peaked at about 96 h, then declined over the remainder of the study for the lower-molecular-weight PAHs. For most higher-molecular-weight PAHs, accumulation peaked at about 2 weeks, then declined only slightly after 4 weeks. The differential bioavailability observed between surficial and at-depth core sections raises questions concerning the adequacy of results generated from toxicity and bioaccumulation tests routinely conducted surficial sediments.

  17. Geochemical characteristics of organic compounds in a permafrost sediment core sample from northeast Siberia, Russia

    NASA Technical Reports Server (NTRS)

    Matsumoto, G. I.; Friedmann, E. I.; Gilichinsky, D. A.

    1995-01-01

    We studied total organic carbon (TOC), hydrocarbons and fatty acids in a permafrost sediment core sample (well 6-90, length 32.0 m, 1.5-2.5 Ma BP) from northeast Siberia (approximately 70 degrees N, 158 degrees E), Russia, to elucidate their geochemical features in relation to source organisms and paleoenvironmental conditions. Long-chain n-alkanes and n-alkanoic acids (>C19) were most predominant hydrocarbons and fatty acids, respectively, so organic matter in the sediment core was derived mainly from vascular plants and, to a much smaller extent, from bacteria. Low concentrations of unsaturated fatty acids revealed that organic matter in the sediment core was considerably degraded during and/or after sedimentation. The predominance of vascular plant components, the major ionic components of nonmarine sources, and geological data strongly implied that the sediment layers were formed in shallow lacustrine environments, such as swamp with large influences of tundra or forest-tundra vegetation. Also, no drastic changes in paleoenvironmental conditions for biological activity or geological events, such as sea transgressions or ice-sheet influences, occurred at the sampling site approximately 100 km from the coast of the East Siberian Sea during the late Pliocene an early Pleistocene periods.

  18. Thermal Properties of Bazhen fm. Sediments from Thermal Core Logging

    NASA Astrophysics Data System (ADS)

    Spasennykh, Mikhail; Popov, Evgeny; Popov, Yury; Chekhonin, Evgeny; Romushkevich, Raisa; Zagranovskaya, Dzhuliya; Belenkaya, Irina; Zhukov, Vladislav; Karpov, Igor; Saveliev, Egor; Gabova, Anastasia

    2016-04-01

    The Bazhen formation (B. fm.) is the hugest self-contained source-and-reservoir continuous petroleum system covering by more than 1 mln. km2 (West Siberia, Russia). High lithological differentiation in Bazhen deposits dominated by silicic shales and carbonates accompanied by extremely high total organic carbon values (of up to 35%), pyrite content and brittle mineralogical composition deteriorate standard thermal properties assessment for low permeable rocks. Reliable information of unconventional system thermal characteristics is the necessary part of works such as modelling of different processes in reservoir under thermal EOR for accessing their efficiency, developing and optimizing design of the oil recovery methods, interpretation of the well temperature logging data and for the basin petroleum modelling. A unique set of data including thermal conductivity, thermal diffusivity, volumetric heat capacity, thermal anisotropy for the B.fm. rocks was obtained from thermal core logging (high resolution continuous thermal profiling) on more than 4680 core samples (2000 of B.fm. samples are among) along seven wells for four oil fields. Some systematic peculiarities of the relation between thermal properties of the B.fm. rocks and their mineralogical composition, structural and texture properties were obtained. The high-resolution data are processed jointly with the standard petrophysical logging that allowed us to provide better separation of the formation. The research work was done with financial support of the Russian Ministry of Education and Science (unique identification number RFMEFI58114X0008).

  19. Correlations Between Physical and Hydraulic Properties and Uranium Desorption in Contaminated, Intact Sediment Cores

    NASA Astrophysics Data System (ADS)

    Rockhold, M. L.; Oostrom, M.; Wietsma, T. W.; Zachara, J. M.

    2010-12-01

    An unlined disposal pond in the 300 Area of the Hanford Site received uranium-bearing liquid effluents associated with nuclear reactor fuel rod processing from 1943 to 1975. Contaminated sediments from the base and sides of the former pond were excavated and removed from the site in the early 1990s, but a uranium plume has persisted in the groundwater at concentrations exceeding the drinking water standard. The former process pond is located adjacent to the Columbia River and seasonal fluctuations in the river stage and water table provide a mechanism for resupplying residual uranium from the vadose zone to the groundwater when the lower vadose zone is periodically rewetted. Intact cores were collected from the site for measurements of physical, hydraulic, and geochemical properties. Multistep outflow experiments were also performed on the intact cores to determine permeability-saturation-capillary pressure relations. Pore water displaced during these experiments for two of the vadose zone cores was also analyzed for uranium. For a core containing finer-textured sediment classified as muddy sandy gravel, and a core containing coarser-textured sediment classified as gravel, the relative aqueous uranium concentrations increased by factors of 8.3 and 1.5, respectively, as the cores were desaturated and progressively smaller pore-size classes were drained. Aqueous concentrations of uranium in the extracted pore waters were up to 115 times higher than the current drinking water standard of 30 ppb. These results confirm that there is a continuing source of uranium in the vadose zone at the site, and are consistent with a hypothesis that the persistence of the groundwater uranium plume is also associated, in part, with rate-limited mass transfer from finer-textured sediments. The data from these and several other intact cores from the site are evaluated to explore relationships between physical and hydraulic properties and uranium desorption characteristics.

  20. Shallow stratigraphy of the Skagit River Delta, Washington, derived from sediment cores

    USGS Publications Warehouse

    Grossman, Eric E.; George, Douglas A.; Lam, Angela

    2011-01-01

    Sedimentologic analyses of 21 sediment cores, ranging from 0.4 to 9.6 m in length, reveal that the shallow geologic framework of the Skagit River Delta, western Washington, United States, has changed significantly since 1850. The cores collected from elevations of 3.94 to -2.41 m (relative to mean lower low water) along four cross-shore transects between the emergent marsh and delta front show relatively similar environmental changes across an area spanning ~75 km2. Offshore of the present North Fork Skagit River and South Fork Skagit River mouths where river discharge is focused by diked channels through the delta, the entire 5–7-km-wide tidal flats are covered with 1–2 m of cross-bedded medium-to-coarse sands. The bottoms of cores, collected in these areas are composed of mud. A sharp transition from mud to a cross-bedded sand unit indicates that the tidal flats changed abruptly from a calm environment to an energetic one. This is in stark contrast to the Martha's Bay tidal flats north of the Skagit Bay jetty that was completed in the 1940s to protect the newly constructed Swinomish Channel from flooding and sedimentation. North of the jetty, mud ranging from 1 to 2 m thick drapes a previously silt- and sand-rich tidal flat. The silty sand is a sediment facies that would be expected there where North Fork Skagit River sedimentation occurred prior to jetty emplacement. This report describes the compositional and textural properties of the sediment cores by using geophysical, photographic, x-radiography, and standard sediment grain-size and carbon-analytical methods. The findings help to characterize benthic habitat structure and sediment transport processes and the environmental changes that have occurred across the nearshore of the Skagit River Delta. The findings will be useful for quantifying changes to nearshore marine resources, including impacts resulting from diking, river-delta channelization, shoreline development, and natural variations in fluvial-sediment

  1. Time-series analysis of chemical trends in a dated ice core from Antarctica

    SciTech Connect

    Keskin, S.S.; Olmez, I.; Langway, C.C. Jr.

    1994-12-31

    Polar ice sheets contain valuable information about past atmospheric conditions. Atmospherically produced or transported substances from natural and anthropogenic sources are preserved stratigraphically within the ice layers as a result of both wet and dry deposition mechanisms. Substances deposited include aerosols and gaseous compounds. The analysis of trace elements contained in dated annual snow layers provides a measure of the elemental chemistry content of the atmosphere during the same time interval. The aerosol content of the atmosphere and ice sheets is one of the most important parameters for cloud/radiation interaction processes. Ice cores were obtained from the Byrd Station, West Antarctica, in November, 1989. This study presents results obtained from instrumental neutron activation analysis and ion chromatography on 30 samples over a 20 year period.

  2. Mercury accumulation in sediment cores from three Washington state lakes: evidence for local deposition from a coal-fired power plant.

    PubMed

    Furl, Chad V; Meredith, Callie A

    2011-01-01

    Mercury accumulation rates measured in age-dated sediment cores were compared at three Washington state lakes. Offutt Lake and Lake St. Clair are located immediately downwind (18 and 28 km, respectively) of a coal-fired power plant and Lake Sammamish is located outside of the immediate area of the plant (110 km). The sites immediately downwind of the power plant were expected to receive increased mercury deposition from particulate and reactive mercury not deposited at Lake Sammamish. Mercury accumulation in cores was corrected for variable sedimentation, background, and sediment focusing to estimate the anthropogenic contribution (Hg(A,F)). Results indicated lakes immediately downwind of the power plant contained elevated Hg(A,F) levels with respect to the reference lake. Estimated fluxes to Lake Sammamish were compared to measured values from a nearby mercury wet deposition collector to gauge the efficacy of the core deconstruction techniques. Total deposition calculated through the sediment core (20.7 μg/m²/year) fell just outside of the upper estimate (18.9 μg/m²/year) of total deposition approximated from the wet deposition collector. PMID:20437040

  3. Inorganic nitrogen transformations in the bed of the Shingobee River, Minnesota: Integrating hydrologic and biological processes using sediment perfusion cores

    USGS Publications Warehouse

    Sheibley, R.W.; Duff, J.H.; Jackman, A.P.; Triska, F.J.

    2003-01-01

    Inorganic N transformations were examined in streambed sediments from the Shingobee River using sediment perfusion cores. The experimental design simulated groundwater-stream water mixing within sediment cores, which provided a well-defined one-dimensional representation of in situ hydrologic conditions. Two distinct hydrologic and chemical settings were preserved in the sediment cores: the lowermost sediments, perfused with groundwater, remained anaerobic during the incubations, whereas the uppermost sediments, perfused with oxic water pumped from the overlying water column, simulated stream water penetration into the bed. The maintenance of oxic and anoxic zones formed a biologically active aerobic-anaerobic interface. Ammonium (NH4+) dissolved in groundwater was transported conservatively through the lower core zone but was removed as it mixed with aerated recycle water. Concurrently, a small quantity of nitrate (NO3-) equaling ???25% of the NH4+ loss was produced in the upper sediments. The NH4+ and NO3- profiles in the uppermost sediments resulted from coupled nitrification-denitrification, because assimilation and sorption were negligible. We hypothesize that anaerobic microsites within the aerated upper sediments supported denitrification. Rates of nitrification and denitrification in the perfusion cores ranged 42-209 and 53-160 mg N m-2 day-1, respectively. The use of modified perfusion cores permitted the identification and quantification of N transformations and verified process control by surface water exchange into the shallow hyporheic zone of the Shingobee River.

  4. Spatial and temporal variation of the last ice age mega-floods in the Pacific Northwest: Sediment provenance using single-aliquot K/Ar dating

    NASA Astrophysics Data System (ADS)

    Gombiner, J.; Hendy, I. L.; Hemming, S. R.; Fleisher, M. Q.; Pierce, E.; Mesko, G.; Dale, C. L.; Ages-Argon GeochronologyThe Earth Sciences

    2010-12-01

    Glacial outburst floods (jokulhaups) are important, but poorly understood, drivers of climate change during large-scale deglaciations. Meltwater fluxes are one of the climate forcings with the most uncertain histories included in climate modeling of the last 21 kyr. Outburst flood events are not included in modeled meltwater fluxes due to their small volume, though they are one of the fastest delivery mechanisms for freshwater to the ocean. The most significant outburst floods known to have occurred during the last deglaciation came from glacial Lake Missoula between 18 and 15 kyr BP. Although the volume of meltwater delivered to the North Pacific Ocean was small, the speed of delivery and sediment content of these floods was large. Here we present data that constrain the location and timing of outburst flooding to the N Pacific. Single aliquot bulk K/Ar dates of fine silts and clays from a deep sea core collected off Vancouver Island, British Columbia [MD-02-2496 (48°58’47”N: 127°02’14”W; 2043m water depth)] provide a geochemical fingerprint of the provenance of glacial marine sediments. K/Ar ages, combined with mapped continental geology, allow for the identification of potential source regions for individual flood layers in the core. K/Ar ages in this study represent an integrated age of the entire sediment package delivered to the core site. This includes the Proterozoic Belt-Purcell metasediments (which glacial Lake Missoula covered), the Miocene/Pliocene Columbia Plateau Basalts (which were heavily eroded by the Missoula Floods), and the largely Cenozoic rocks of the coastal and Cascade mountain ranges. Initial results indicate a significant variation in K/Ar ages between background sedimentation and flood deposition events. Missoula Flood outburst sediments appear to have K/Ar ages of around 300 million years while background sediments appear to have K/Ar ages of less than 100 million years. Timing of outburst flood deposits has been determined by

  5. A Direct-Push Sample-Freezing Drive Shoe for Collecting Sediment Cores with Intact Pore Fluid, Microbial, and Sediment Distributions

    NASA Astrophysics Data System (ADS)

    Bekins, B. A.; Trost, J.; Christy, T. M.; Mason, B.

    2015-12-01

    Abiotic and biological reactions in shallow groundwater and bottom sediments are central to understanding groundwater contaminant attenuation and biogeochemical cycles. The laminar flow regime in unconsolidated surficial aquifers creates narrow reaction zones. Studying these reaction zones requires fine-scale sampling of water together with adjacent sediment in a manner that preserves in situ redox conditions. Collecting representative samples of these narrow zones with traditional subsurface sampling equipment is challenging. For example, use of a basket type core catcher for saturated, non-cohesive sediments results in loss of fluid and sediments during retrieval. A sample-freezing drive shoe designed for a wire line piston core sampler allowed collection of cores with intact sediment, microbial, and pore fluid distributions and has been the basis for studies documenting centimeter-scale variations in aquifer microbial populations (Murphy and Herkelrath, 1996). However, this freezing drive shoe design is not compatible with modern-day direct push sampling rigs. A re-designed sample-freezing drive shoe compatible with a direct-push dual-tube coring system was developed and field-tested. The freezing drive shoe retained sediment and fluid distributions in saturated sediment core samples by freezing a 10 centimeter plug below the core sample with liquid CO­2. Core samples collected across the smear zone at a crude oil spill site near Bemidji, Minnesota, were successfully extracted without loss of fluid or sediment. Multiple core sections from different depths in the aquifer were retrieved from a single hole. This new design makes a highly effective sampling technology available on modern-day direct push sampling equipment to inform myriad questions about subsurface biogeochemistry processes. The re-design of the freezing drive shoe was supported by the USGS Innovation Center for Earth Sciences. References: Murphy, Fred, and W. N. Herkelrath. "A sample

  6. Analysis of the microbial community and geochemistry of a sediment core from Great Slave Lake, Canada.

    PubMed

    Lim, Jesmine; Woodward, John; Tulaczyk, Slawek; Christoffersen, Poul; Cummings, Stephen P

    2011-02-01

    Sediment cores taken from Great Slave Lake, Canada, were analysed to investigate their metabolically active microbial populations and geochemistry. The amplification of cDNA detected metabolically active bacterial (50 separate bands) and archaeal (49 separate band) communities. The bacterial communities were further resolved indicating active actinobacterial and γ-proteobacterial communities (36 and 43 individual bands respectively). Redundancy discriminate analysis and Monte Carlo permutation testing demonstrated the significant impact of geochemical parameters on microbial community structures. Geochemical analyses suggest that the upper 0.4 m represents soil weathering and erosion in the lake catchment. An increase in organic carbon in the lower core suggests either more primary productivity, indicating warmer climate conditions, associated with Holocene Climatic Optimum conditions pre 5,000 years BP or change from a reducing environment in the lower core to an oxidizing environment during more recent deposition. Drivers for bacterial, archaeal and actinobacterial community structures were sediment particle size, and its mineral composition. Depth also significantly affected γ- proteobacterial community structure. In contrast the organic carbon content did not significantly shape the microbial community structures within the sediment. This study indicates that geochemical parameters significantly contribute to microbial community structure in these sediments. PMID:20803250

  7. Analytical approaches for determination of bromine in sediment core samples by X-ray fluorescence spectrometry.

    PubMed

    Pashkova, Galina V; Aisueva, Tatyana S; Finkelshtein, Alexander L; Ivanov, Egor V; Shchetnikov, Alexander A

    2016-11-01

    Bromine has been recognized as a valuable indicator for paleoclimatic studies. Wavelength dispersive X-ray fluorescence (WDXRF) and total reflection X-ray fluorescence (TXRF) methods were applied to study the bromine distributions in lake sediment cores. Conventional WDXRF technique usually requires relatively large mass of a sediment sample and a set of calibration samples. Some analytical approaches were developed to apply WDXRF to small sediment core samples in the absence of adequate calibration samples with a known Br content. The mass of a sample to be analyzed was reduced up to 200-300mg and the internal standard method with correction using fundamental parameters was developed for Br quantification. TXRF technique based on the direct analysis of a solid suspension using 20mg of sediment sample by internal standard method was additionally tested. The accuracy of the WDXRF and TXRF techniques was assessed by the comparative analysis of reference materials of sediments, soil and biological samples. In general, good agreement was achieved between the reference values and the measured values. The detection limits of Br were 1mg/kg and 0.4mg/kg for WDXRF and TXRF respectively. The results of the Br determination obtained with different XRF techniques were comparable to each other and used for paleoclimatic reconstructions. PMID:27591627

  8. Profile of trace metals accumulation in core sediment from Seine river estuary (docks basin).

    PubMed

    Hamzeh, Mariam; Ouddane, Baghdad; El-Daye, Mirna; Halwani, Jalal

    2013-01-01

    The Seine is one of the most polluted rivers in Europe with respect to potentially harmful elements. It receives effluents from the upstream Paris urban and industrial area, and also local inputs from the heavily industrialized Rouen and Le Havre regions. The present study deals with this environmental topic and the concentrations of Cd, Ni, Pb, Hg, Zn and Cu were determined in sediment cores collected in the docks basin of Rouen harbour in 2008. The intensity of metal pollution during recent decades was evaluated using an enrichment factor (EF) and a geoaccumulation index (Igeo). The results of vertical distribution showed that the metal pollution in the past is much higher than in the surface sediment. Mercury was found to be the heaviest pollutant (with Igeo and EF exceeding 4 and 20, respectively), and Cd and Pb were the second most important pollutants. A slight contamination in Ni was observed with very low Igeo values. To estimate the sediment toxicity, simultaneously extracted metals/acid volatile sulfides ratio (SEM/AVS) was calculated. Low values of the toxicity index SEM/AVS were observed in the core sediments indicating the inexistence of metal potential toxicity. Also the concentrations of these trace metals were lower than the probable effect concentration values reported as consensus-based sediment quality guidelines for fresh water ecosystems. PMID:24191442

  9. [Study on trace elements of lake sediments by ICP-AES and XRF core scanning].

    PubMed

    Cheng, Ai-Ying; Yu, Jun-Qing; Gao, Chun-Liang; Zhang, Li-Sha; He, Xian-Hu

    2013-07-01

    It is the first time to study sediment of Toson lake in Qaidam Basin. Trace elements including Cd, Cr, Cu, Zn and Pb in lake sediment were measured by ICP-AES method, studied and optimized from different resolution methods respectively, and finally determined a optimum pretreatment system for sediment of Toson lake, namely, HCl-HNO3-HF-HClO4-H2O2 system in the proportions of 5 : 5 : 5 : 1 : 1 was determined. At the same time, the data measured by XRF core scanning were compared, the use of moisture content correction method was analyzed, and the influence of the moisture content on the scanning method was discussed. The results showed that, compared to the background value, the contents of Cd and Zn were a little higher, the content of Cr, Cu and Pb was within the background value limits. XRF core scanning was controlled by sediment elements as well as water content in sediment to some extent. The results by the two methods showed a significant positive correlation, with the correlation coefficient up to 0.673-0.925, and they have a great comparability. PMID:24059207

  10. Temporal trends of hydrocarbons in sediment cores from the Pearl River Estuary and the northern South China Sea.

    PubMed

    Peng, Xianzhi; Wang, Zhendi; Yu, Yiyi; Tang, Caiming; Lu, Hong; Xu, Shiping; Chen, Fanrong; Mai, Bixian; Chen, Shejun; Li, Kechang; Yang, Chun

    2008-11-01

    Concentrations and fluxes of unresolved complex mixture of hydrocarbons (UCM) and polycyclic aromatic hydrocarbons (PAHs) were analyzed for two (210)Pb dated sediment cores from the Pearl River Estuary (PRE) and the adjacent northern South China Sea (NSCS). Compound-specific stable carbon isotopic compositions of individual n-alkanes were also measured for identification of the hydrocarbon sources. The historical records of PAHs in the NSCS reflected the economic development in the Pearl River Delta during the 20th century. PAHs in the NSCS predominantly derive from combustion of coal and biomass, whereas PAHs in the PRE are a mixture of petrogenic and pyrogenic in origins. The isotopic profiles reveal that the petrogenic hydrocarbons in the PRE originate predominantly from local spillage/leakage of lube oil and crude oils. The accumulation rates of pyrogenic PAHs have significantly increased, whereas UCM accumulation has slightly declined in the NSCS in the recent three decades. PMID:18339464

  11. Dispersion of the Geomagnetic Field Caused by Secular Variation: Constraints From Sediment Cores From Around Antarctica

    NASA Astrophysics Data System (ADS)

    Acton, G.; Jovane, L.; Verosub, K. L.; Sagnotti, L.; Ohneiser, C.; Strada, E.; Florindo, F.; Wilson, G. S.

    2010-12-01

    The angular dispersion of the virtual geomagnetic pole (VGP) measured over time and at many sites around the globe provides a measure of spatial variability in geodynamo processes. For example, longitudinal and latitudinal variations in dispersion may imply lateral differences in the boundary conditions at the core-mantle interface. Latitudinal variations in dispersion may also provide constraints on the size of dipole wobble and zonal non-dipole components. Furthermore, changes in dispersion across high latitudes may be indicative of changes in outer core flow regimes across the tangent cylinder. The spatial variation of dispersion, particularly the latitudinal variation, thus has the potential to be a powerful constraint on geodynamo models. Currently, estimates of the latitudinal variation in dispersion are based on volcanic data sets that give ambiguous results, with some studies finding an increase in dispersion with latitude and others finding virtually no change with latitude. The ambiguity arises mainly from the sparseness of data from high latitudes and from the difficulty in dealing with excursional VGPs in volcanic data sets. To improve the dispersion estimates at high latitudes, we use paleomagnetic data obtained from sedimentary ocean drill cores from several sites from around Antarctica, including ODP Leg 178 Sites 1095, 1096, and 1098 cored off the Antarctic Peninsula, and ANDRILL Site AND-2A and Eltanin Core 27-21 from the Ross Sea. Unlike volcanic units, sedimentary sections can provide continuous paleomagnetic records that capture both short and long term geomagnetic field variability. This allows us to examine not only the size of dispersion but changes in dispersion that occur over time. Such records also make it possible to investigate the amount of time it takes to average paleosecular variation and to use that information to estimate the duration of sedimentation at other sites. As with volcanics, a variety of issues, including sedimentation

  12. Amino acid epimerization implies rapid sedimentation rates in Arctic Ocean cores

    USGS Publications Warehouse

    Sejrup, H.P.; Miller, G.H.; Brigham-Grette, J.; Lovlie, R.; Hopkins, D.

    1984-01-01

    The palaeooceanography of the Arctic Ocean is less well known than any other ocean basin, due to difficulties in obtaining cores and in providing a secure chronological framework for those cores that have been raised. Most recent investigators have suggested that low sedimentation rates (0.05-0.1 cm kyr-1) have characterized the deep basins over the past 5 Myr (refs 1,2) despite the glacial-marine character of the sediment and proximity to major centres of shelf glaciation. These calculations have been primarily based on the down-core pattern in the inclination of magnetic minerals, supported by uranium-series, 14C and micropalaeontological evidence. Here we analyse amino acid diagnesis in foraminifera from two gravity cores raised from the floor of the Arctic Ocean, our results suggest that these cores span <200 kyr., conflicting with the earlier estimate of 3 Myr based on palaeomagnetic data. The chronology of other Arctic Ocean cores and previous palaeoenvironmental interpretations need re-evaluation. ?? 1984 Nature Publishing Group.

  13. Historical trends of PBDEs and HBCDs in sediment cores from Sydney estuary, Australia.

    PubMed

    Drage, D; Mueller, J F; Birch, G; Eaglesham, G; Hearn, L K; Harrad, S

    2015-04-15

    This paper presents the first historical data on the occurrence of polybrominated diphenyl ethers (PBDEs) and hexabromocyclododecane (HBCDs) in estuarine sediment from Australia. Sediment cores and surficial sediment samples were collected from four locations within Sydney estuary, Australia. Large increases in concentrations were observed for all compounds between 1980 and 2014, especially for BDE-209 (representative usage of Deca-BDE commercial mixture), which was found in surficial sediment at an average concentration of 42 ng/g dry wt (21-65 ng/g dry wt). PBDE congeners representative of both the Penta- and Octa-BDE commercial mixtures (∑6PBDEs) were also found in their highest concentrations in surficial sediments (average: 1.3 ng/g dry wt; range: 0.65-2.5 ng/g dry wt). PBDE concentrations in surficial sediments were relatively high when compared with those presented in the available literature. This suggests that their input into the Sydney estuary has not decreased since their bans almost a decade earlier. After a sharp increase in the 1990s, HBCD concentrations peaked at an average of 3.5 ng/g dry wt (1.8-5.3 ng/g dry wt) in surficial samples. With global legislation on HBCDs allowing its usage for the next 10 years, it is expected that its input into the estuary is likely to continue. PMID:25617997

  14. Rare earth element compositions of core sediments from the shelf of the South Sea, Korea: Their controls and origins

    NASA Astrophysics Data System (ADS)

    Jung, Hoi-Soo; Lim, Dhongil; Choi, Jin-Yong; Yoo, Hae-Soo; Rho, Kyung-Chan; Lee, Hyun-Bok

    2012-10-01

    Rare earth elements (REEs) of bulk sediments and heavy mineral samples of core sediments from the South Sea shelf, Korea, were analyzed to determine the constraints on REE concentrations and distribution patterns as well as to investigate their potential applicability for discriminating sediment provenance. Bulk sediment REEs showed large variation in concentrations and distribution patterns primarily due to grain size and carbonate dilution effects, as well as due to an abundance of heavy minerals. In the fine sandy sediments (cores EZ02-15 and 19), in particular, heavy minerals (primarily monazite and titanite/sphene) largely influenced REE compositions. Upper continental crust-normalized REE patterns of these sand-dominated sediments are characterized by enriched light REEs (LREEs), because of inclusion of heavy minerals with very high concentrations in LREEs. Notably, such a strong LREE enrichment is also observed in Korean river sediments. So, a great care must be taken when using the REE concentrations and distribution patterns of sandy and coarse silty shelf sediments as a proxy for discriminating sediment provenance. In the fine-grained muddy sediments with low heavy mineral abundance, in contrast, REE fractionation ratios and their UCC-normalized patterns seem to be reliable proxies for assessing sediment provenance. The resultant sediment origin suggested a long lateral transportation of some fine-grained Chinese river sediments (probably the Changjiang River) to the South Sea of Korea across the shelf of the northern East China Sea.

  15. Relationship between microbial diversity and chemical contamination along a 50-year-old sediment core

    NASA Astrophysics Data System (ADS)

    Berthe, T.; Petit, F.; Boust, D.; Lesueur, P.; Roose-Amsaleg, C.; Cécillon, S.; Kaci-Benaicha, A.

    2013-12-01

    The purpose of this study was to evaluate the potential use of sediment microbial diversity (community structure) as an indicator of the impact of anthropogenic activities within an estuarine ecosystem. The diversity of microbial communities was investigated along a 5-m-long sediment core collected in an anthropized European estuary (Seine, France), giving an evolution of trace metal, polycyclic aromatic hydrocarbons (PAHs), and polychlorinated biphenyls (PCBs) concentrations over the last 50 years. An increase of trace metal and PCB concentrations are observed with depth, with an enrichment of these contaminants in the 1970s. The concentration profiles of light, intermediate and heavy PAHs showed distinct peaks, but the highest total PAH concentration was also detected in the sediment from the 1970s. We first investigated the bacterial community resistant to cobalt, zinc and cadmium by analyzing the diversity of the czcA gene encoding an RND efflux pump (Heavy Metal Efflux-RND) in 5-year and 33-year-old sediment samples displaying contrasted concentrations in these trace metals. The diversity of the czcA gene was reduced in the 33-year-old and more contaminated sediments suggesting a selection of resistant bacterial species. A molecular fingerprinting method (DGGE) was used to study the evolution of total microbial (Bacteria and Archaea) community structures for samples selected along the sediment core. A correlation is observed between the bacterial community structures, the sediment age, the trace metal and PAH concentrations. The metabolically active and total microbial communities were further characterized by a microarray approach (Phylochips) in sediment samples selected according to the DGGE results. Bacterial diversity was found dominated by Proteobacteria, Actinobacteria, and Firmicutes in all analyzed samples. Diversity of phylotypes corresponds to changes in PAH and trace metal concentrations in sediment, suggesting that chemical contaminants have

  16. Exploitation of chemical profiles by conjugate variable analysis: application to the dating of a tropical ice core (Nevado Illimani, Bolivia)

    NASA Astrophysics Data System (ADS)

    Gay, M.; De Angelis, M.; Lacoume, J.-L.

    2013-06-01

    Ice core dating is a key parameter for the interpretation of the ice archives. However, the relationship between ice depth and age can generally not be easily established and requires to combine a large number of investigations and/or modeling effort. This paper presents a new approach of ice core dating based on conjugate variable (depth and spatial frequency) analysis of chemical profiles. The relationship between the depth of a given ice layer and the date it was deposited is determined using ion concentration depth profiles obtained along a one hundred-meters deep ice core recovered in the summit area of the Nevado Illimani (6350 m a.s.l.), located in the Eastern Bolivian Andes (16°37' S, 67°46' W). The results of Fourier conjugate analysis and wavelet tranforms are first compared. Both methods are applied to nitrate concentration depth profile. The resulting chronologies are checked by comparison with the multi-proxy year-by-year dating published by de Angelis et al. (2003) and with volcanic tie points, demonstrating the efficiency of Fourier conjugate analysis when tracking the natural variability of chemical proxies. The Fourier conjugate analysis is then applied to concentration depth profiles of seven other ions thus providing information on the suitability of each of them for dating studies of tropical Andean ice cores.

  17. Uranium-series dating of fossil corals from marine sediments of southeastern United States Atlantic Coastal Plain.

    USGS Publications Warehouse

    Szabo, B. J.

    1985-01-01

    The average 230Th ages of samples from the Norfolk Formation, and from later- and earlier-deposited sediments of the Wando Formation are 71 000, 87 000, and 129 000 yr, and they appear to correlate with oxygen isotope substages 5a, 5c and 5e, respectively. The average 230 Th age of samples from beds of the Rappahannock Rver, Ponzer, and Ten Mile Hill localities is 212 000 yr, and they correlate with oxygen isotope stage 7. The sediment of the Canepatch Formation is 460 000 yr old, and it is tentatively correlated with oxygen isotope stage 11. There is general agreement between uranium-series and uranium-trend dates and between the quantitative trends of the amino acid data and uranium-series dates. The amino acid values, however, are unacceptably high in at least two groups of samples, those from localities near Charleston, South Carolina, and from central Virginia. -from Author

  18. Historical lead isotope record of a sediment core from the Derwent River (Tasmania, Australia): a multiple source environment.

    PubMed

    Townsend, Ashley T; Seen, Andrew J

    2012-05-01

    A 105 cm sediment core from the Derwent River (Tasmania, Australia) was collected in 2004 and was characterised considering both physical (loss on ignition at 550 °C and grain size) and chemical (Fe, Cu, Zn, Cd and Pb concentrations, Pb isotope ratios and (210)Pb dating) properties. The core was analysed to (i) investigate the historical profiles of some important elements associated with the Risdon zinc refinery adjacent to the Derwent River, (ii) determine Pb isotopic signatures of sediment samples, and (iii) assess the veracity of Pb isotope ratios as indicators of contaminant Pb input. Extractable metal concentrations were (all values as mgkg(-1), non-normalised for grain size) Fe: 20,000-35,000, Zn: 42-4500, Pb: 5-1090, Cu: 13-141, and Cd: 1-31; with a close correlation between Cu, Zn, Cd and Pb. Metal enrichment factors (normalised to Al) were Pb: 0.9-144, Zn: 0.8-93, Cd: 0.8-30, Cu: 0.8-8.9 and Fe: 0.9-1.3, confirming anthropogenic contributions of Cu, Zn, Pb and Cd to the sediments. The onset of metal contamination above background levels occurred at a depth between 43 and 49 cm, with maximum concentrations noted near 20 cm for Cu, Zn, Cd and Pb. Lead isotope ratios were determined in sediments using sector field ICP-MS, and were found to be 36.5-38.8, 16.5-18.7 and 1.07-1.20 for (208)Pb/(204)Pb, (206)Pb/(204)Pb and (206)Pb/(207)Pb ratios, respectively. Major Australian ores processed at the refinery over the previous ~90 years include those from Broken Hill, Rosebery, Mt Isa, Elura, Hellyer and Century deposits. Anthropogenic impact by Pb with Broken Hill type isotopic ratio was initially evident in the core at 43-49 cm. The introduction of Rosebery and Elura ores to the refinery was also clearly noted. Pb isotope ratios further highlight that the Derwent River has been exposed to a greater impact by anthropogenic Pb in comparison to other major Tasmanian rivers, namely the Huon and Tamar. PMID:22444061

  19. Water-quality trends in White Rock Creek Basin from 1912-1994 identified using sediment cores from White Rock Lake Reservoir, Dallas, Texas

    USGS Publications Warehouse

    Van Metre, P.C.; Callender, E.

    1997-01-01

    Historical trends in selected water-quality variables from 1912 to 1994 in White Rock Creek Basin were identified by dated sediment cores from White Rock Lake. White Rock Lake is a 4.4-km2 reservoir filled in 1912 and located on the north side of Dallas, Texas, with a drainage area of 259 km2. Agriculture dominated land use in White Rock Creek Basin before about 1950. By 1990, 72% of the basin was urban. Sediment cores were dated using cesium-137 and core lithology. Major element concentrations changed, and sedimentation rates and percentage of clay-sized particles in sediments decreased beginning in about 1952 in response to the change in land use. Lead concentrations, normalized with respect to aluminum, were six times larger in sediment deposited in about 1978 than in pre-1952 sediment. Following the introduction of unleaded gasoline in the 1970s, normalized lead concentrations in sediment declined and stabilized at about two and one-half times the pre-1952 level. Normalized zinc and arsenic concentrations increased 66 and 76%, respectively, from before 1952 to 1994. No organochlorine compounds were detected in sediments deposited prior to about 1940. Concentrations of polychlorinated biphenyls (PCB) and DDE (a metabolite of DDT) increased rapidly beginning in the 1940s and peaked in the 1960s at 21 and 20 ??g kg-1, respectively, which is coincident with their peak use in the United States. Concentrations of both declined about an order of magnitude from the 1960s to the 1990s to 3.0 and 2.0 ??g kg-1, respectively. Chlordane and dieldrin concentrations increased during the 1970s and 1980s. The largest chlordane concentration was 8.0 ??g kg-1 and occurred in a sediment sample deposited in about 1990. The largest dieldrin concentration was 0.7 ??g kg-1 and occurred in the most recent sample deposited in the early 1990s. Agricultural use of chlordane and dieldrin was restricted in the 1970s; however, both were used as termiticides, and urban use of chlordane

  20. Antarctic Sediment and Rock Cores: Decoding the Geologic History of Antarctica

    NASA Astrophysics Data System (ADS)

    Huffman, L.; Rack, F. R.

    2007-12-01

    Sediment and rock cores are like a history book waiting to be read, and ANDRILL (ANtarctic geologic DRILLing) scientists have developed techniques for decoding the messages locked in the stratigraphic record. Educators accompany the multinational, interdisciplinary science team to Antarctica through their participation in a program known as ARISE (ANDRILL Research Immersion for Science Educators). Capitalizing on the excitement and interest surrounding polar research during the IPY (International Polar Year), the ARISE team collaborates with scientists to develop activities and lessons to transfer the technology of sediment and rock core drilling, and the science involved in decoding the information about past climates stored within them, to non-technical audiences. This talk will present information about a successful model of education and outreach that includes examples of geoscience activities developed for grades 5-12, and discuss methods of teacher training through immersion in scientific research.

  1. Nondestructive X-Ray Computed Tomography Analysis of Sediment Cores: A Case Study from the Arctic Ocean

    NASA Astrophysics Data System (ADS)

    Oti, E.; Polyak, L. V.; Cook, A.; Dipre, G.

    2014-12-01

    Investigation of marine sediment records can help elucidate recent changes in the Arctic Ocean circulation and sea ice conditions. We examine sediment cores from the western Arctic Ocean, representing Late to Early Quaternary age (potentially up to 1 Ma). Previous studies of Arctic sediment cores indicate that interglacial/interstadial periods with relatively high sea levels and reduced ice cover are characterized by vigorous bioturbation, while glacial intervals have little to no bioturbation. Traditional methods for studying bioturbation require physical dissection of the cores, effectively destroying them. To treat this limitation, we evaluate archival sections of the cores using an X-ray Computed Tomography (XCT) scanner, which noninvasively images the sediment cores in three dimensions. The scanner produces density sensitive images suitable for quantitative analysis and for identification of bioturbation based on size, shape, and orientation. We use image processing software to isolate burrows from surrounding sediment, reconstruct them three-dimensionally, and then calculate their surface areas, volumes, and densities. Preliminary analysis of a core extending to the early Quaternary shows that bioturbation ranges from 0 to approximately 20% of the core's volume. In future research, we will quantitatively define the relationship between bioturbation activity and glacial regimes. XCT examination of bioturbation and other sedimentary features has the potential to shed light on paleoceanographic conditions such as sedimentation patterns and food flux. XCT is an alternative, underexplored investigation method that bears implications not only for illustrating paleoclimate variations but also for preserving cores for future, more advanced technologies.

  2. Microscale Deformation of (Post) Perovskite-Dominated Sediment in the Uppermost Outer Core

    NASA Astrophysics Data System (ADS)

    Petford, N.; Yuen, D.; Rushmer, T.

    2005-05-01

    Seismic and nutational data hint strongly at a layer comprised of silicate sediments several km thick confined to the top of the liquid outer core, directly beneath the core-mantle boundary and equating with observed ultra low velocity zones (ULVZs)1. Its origin is thought to be due to high pressure chemical reactions that take place between Fe-rich silicate in the lower mantle and liquid iron in the underlying outer core. We speculate that the Fe silicate is dominated by the newly discovered post-perovskite phase (ppv). Initial numerical investigations show that viscous compaction in the sediment layer will act to expel interstitial core metal liquid and reduce an initial 50% porosity to a residual value of < 0.1 on timescales of the order 80-100 Ma1. Using a modified form of Biot's equations2, we show that deformation of a poro-viscoelastic sediment pile will respond by drawing up Fe liquid metal into the layer from below at a rate proportional to the shear stress rate. Instead of a static, isolated residual porosity distribution in the most compacted upper regions of sediment, we envisage a more dynamic environment where fresh core liquid is emplaced periodically into the slowly accumulating pile. Estimates of the potential magnitude of the instability, including pressure changes, local fluid flow rates and timescales compare favourably with fluid motions in the convecting outer core. A key difference between both models, which are in fact complementary, relates to the rheology and microscale deformation behaviour of the assumed ppv-dominated sediment. The small grain size of the suspension is close to the limit of dilatant behaviour (c. 10-6 m) in granular materials. More information is required on the chemical and physical behaviour of the post-perovskite phase at lengthscales characteristic of geophysically interesting colloidal suspensions under high P-T conditions. 1.Buffet, BA., Garnero, EJ & Jeanloz, R. 2000. Science, 290, 1338-1342. 2.Koenders, MA

  3. Magnetostratigraphy of a long Quaternary sediment core in the South Yellow Sea

    NASA Astrophysics Data System (ADS)

    Liu, Jianxing; Liu, Qingsong; Zhang, Xunhua; Liu, Jian; Wu, Zhiqiang; Mei, Xi; Shi, Xuefa; Zhao, Quanhong

    2016-07-01

    Continental shelves serve as a bridge between the continent and ocean and sediments in this region are sensitive to land-sea interaction, sea-level variation and local subsidence. In this study, we present a comprehensive magnetic study of the longest sediment core (CSDP-1, 300.1 m) recovered from the South Yellow Sea. The major magnetic minerals in the studied sediments are magnetite, hematite and greigite. Greigite records a chemical remanent magnetization, which can be removed effectively by thermal demagnetization. The magnetostratigraphy defined in this study contains the Matuyama-Brunhes boundary (M/B, 781 ka) at ∼73.68 m, which is consistent with results from adjacent cores. The base of the Quaternary (∼2.6 Ma) in the Yellow Sea is recovered for the first time at a depth of 227.16 m. The basal age of the core is estimated to be ∼3.50 Ma. It indicates that the first transgression of the Yellow Sea occurred no later than ∼1.7 Ma. Succeeding large amplitude regressions occurred in some cold periods such as during MIS 20, MIS 18, and MIS 10. Our results provide the first chronology that brackets the entire Quaternary and we reconstruct the sedimentary evolution of the Yellow Sea with robust age constraints, which provides an important framework for further paleoenvironmental and tectonic studies.

  4. Sediment Core Sectioning and Extraction of Pore Waters under Anoxic Conditions.

    PubMed

    Keimowitz, Alison R; Zheng, Yan; Lee, Ming-Kuo; Natter, Michael; Keevan, Jeffrey

    2016-01-01

    We demonstrate a method for sectioning sediment cores and extracting pore waters while maintaining oxygen-free conditions. A simple, inexpensive system is built and can be transported to a temporary work space close to field sampling site(s) to facilitate rapid analysis. Cores are extruded into a portable glove bag, where they are sectioned and each 1-3 cm thick section (depending on core diameter) is sealed into 50 ml centrifuge tubes. Pore waters are separated with centrifugation outside of the glove bag and then returned to the glove bag for separation from the sediment. These extracted pore water samples can be analyzed immediately. Immediate analyses of redox sensitive species, such as sulfide, iron speciation, and arsenic speciation indicate that oxidation of pore waters is minimal; some samples show approximately 100% of the reduced species, e.g. 100% Fe(II) with no detectable Fe(III). Both sediment and pore water samples can be preserved to maintain chemical species for further analysis upon return to the laboratory. PMID:27023267

  5. Relationship between catchment events (earthquake and heavy rain) and sediment core analysis result in Taiwan.

    NASA Astrophysics Data System (ADS)

    Chen, Hsin-Ying; Lin, Jiun-Chuan

    2015-04-01

    Lake sediments contains material from the catchment. In those sediments, there are some features which can indicate characteristic or status of the catchment. These features were formed by different mechanisms, including some events like earthquakes or heavy rain, which are very common in Taiwan. By analyzing and discussing features of sediments there is a chance to identify historical events and rebuild catchment history. In this study, we compare features of sediment core ( including density, mineral grain size, whole grain size, and biogenic silica content) and earthquake, precipitation records. Sediment cores are collected from Emerald peak lake (24.514980, 121.605844; 77.5, 77.2, 64cm depth), Liyutan lake (23.959878, 120.996585; 43.2, 78.1 cm depth), Sun Moon Lake (23.847043, 120.909869; 181 cm depth), and Dongyuan lake (22.205742, 120.854984; 45.1, 44.2cm depth) in 2014. We assume that there are regular material and organic output in catchments. And rain will provide impetus to move material into lakes. The greater the rain is the larger the material can move. So, if there is a heavy rainfall event, grain size of lake sediment may increase. However, when earthquakes happen, it will produce more material which have lower organic composition than ordinary. So we suggest that after earthquakes there will be more material stored in catchment than often. And rainfall event provides power to move material into lakes, cause more sediment and mineral content higher than usual. Comparing with earthquake record(from 1949, by USGS) and precipitation record(from1940, by Central Weather Bureau,Taiwan), there were few earthquakes which happened near lakes and scale were more than 7 ML. There were 28 rainfall events near Emerald peak lake; 32 near Liyutan lake and Sun Moon Lake; 58 near Dongyuan lake ( rainfall event: >250 mm/day ). In sediment analytical results, ratio of whole and mineral grain size indeed have similar trends with earthquake record. However, rainfall

  6. Is it possible to use "twin cores" as a unique sedimentary record? An experimental design based on sediment color

    NASA Astrophysics Data System (ADS)

    Veiga-Pires, C.; Mestre, N. C.

    2009-01-01

    Sedimentary cores are widely used for studying Quaternary records. However, the amount of sediment that is available is proportional to the diameter of the core, which is rarely bigger than 15 cm. One way to obtain more sediment is to use two cores retrieved from almost the same location and use them as if they represent a unique sedimentary record. In the present work, an experimental design has been applied to verify if "twin cores" from an estuary can be considered as representing the same sedimentary record with twice the amount of sediment to study. Because sediment can be characterized based on its color, the variables used as replicates in the experimental design are the three Lab CIE colors acquired with a X-Rite Colortron spectrophotometer. Sediment cores were retrieved from the upper saltmarsh of Gilão River's estuary, southern Portugal. Twin cores, with in between distances of 50 cm, 100 cm and 200 cm, from two different sites were analysed. Results from a nested ANOVA show that even for the closest twin cores (50 cm apart) there is at least one color variable that shows significant variations between the profiles of both cores. These results clearly show that "twin cores" cannot be used as a unique sedimentary record without any previous testing, at least in such transitional regions.

  7. Sources and evolution of anthropogenic lead in dated sediments from Lake Clair, Québec, Canada.

    PubMed

    Ndzangou, Sabary Omer; Richer-Laflèche, Marc; Houle, Daniel

    2005-01-01

    Two sediments cores were collected from the deepest part of Lake Clair (Québec, Canada) to assess the historical sources of Pb additions to the lake. The cores were collected by divers by carefully inserting a Plexiglas tube into the sediments. To determine the stratigraphic ages of the sediments, (210)Pb and (137)Cs activities were counted by gamma-ray spectroscopy. Lead concentrations and isotopic ratios were performed by inductively coupled plasma-mass spectrometry (ICP-MS), following digestion of the samples with a mixture of HF, HNO(3), and HClO(4) acids and Pb separation by anion-exchange chromatography. Starting at the middle of the 19th century, Pb content of the sediments increased until 1975. The maximum Pb enrichment factor of 35 times (relative to the natural background) was found in sediments deposited in 1975. At this time, excess Pb flux was estimated to be about 0.03 g m(-2) yr(-1). Before 1872, the Pb isotopic ratios were relatively stable (mean (206)Pb/(207)Pb = 1.20 +/- 0.01), reflecting the natural Pb background. Between 1872 and 1894, the source of anthropogenic Pb was highly radiogenic as shown by the Pb isotopic signatures of the sediments (mean (206)Pb/(207)Pb = 1.22 +/- 0.01), possibly reflecting deforestation and agricultural developments in the St.-Lawrence Valley. Between 1894 and 1937, widespread use of industrial and domestic charcoals may explain the isotopic composition of Pb accumulated in the sediments (mean (206)Pb/(207)Pb = 1.19 +/- 0.01). From 1937 to 1975, Pb isotopic compositions became less radiogenic ((206)Pb/(207)Pb from 1.18 to 1.17) even though elemental Pb abundance reached extremely high values (623 mg kg(-1)). This isotopic shift reflects increased use of alkyl-lead in gasoline. For sediments accumulated between 1967 and 1996, the U.S. contribution to anthropogenic Pb accumulated in Lake Clair sediments amounted to between 30 and 63%. PMID:15888887

  8. Sediment cores as archives of historical changes in floodplain lake hydrology.

    PubMed

    Lintern, Anna; Leahy, Paul J; Zawadzki, Atun; Gadd, Patricia; Heijnis, Henk; Jacobsen, Geraldine; Connor, Simon; Deletic, Ana; McCarthy, David T

    2016-02-15

    Anthropogenic activities are contributing to the changing hydrology of rivers, often resulting in their degradation. Understanding the drivers and nature of these changes is critical for the design and implementation of effective mitigation strategies for these systems. However, this can be hindered by gaps in historical measured flow data. This study therefore aims to use sediment cores to identify historical hydrological changes within a river catchment. Sediment cores from two floodplain lakes (billabongs) in the urbanised Yarra River catchment (Melbourne, South-East Australia) were collected and high resolution images, trends in magnetic susceptibility and trends in elemental composition through the sedimentary records were obtained. These were used to infer historical changes in river hydrology to determine both average trends in hydrology (i.e., coarse temporal resolution) as well as discrete flood layers in the sediment cores (i.e., fine temporal resolution). Through the 20th century, both billabongs became increasingly disconnected from the river, as demonstrated by the decreasing trends in magnetic susceptibility, particle size and inorganic matter in the cores. Additionally the number of discrete flood layers decreased up the cores. These reconstructed trends correlate with measured flow records of the river through the 20th century, which validates the methodology that has been used in this study. Not only does this study provide evidence on how natural catchments can be affected by land-use intensification and urbanisation, but it also introduces a general analytical framework that could be applied to other river systems to assist in the design of hydrological management strategies. PMID:26779954

  9. Anthropogenic impact on the Swartvlei lake system in the Wilderness area (South Africa) as reflected in a sediment core

    NASA Astrophysics Data System (ADS)

    Haberzettl, Torsten; Kirsten, Kelly; Franz, Sarah; Reinwarth, Bastian; Baade, Jussi; Daut, Gerhard; Kasper, Thomas; Meadows, Michael; Su, Youliang; Mäusbacher, Roland

    2016-04-01

    Swartvlei is one of the most thoroughly investigated lacustrine coastal systems in South Africa. However, studies focussing on anthropogenic impacts on sediment deposition in the most recent past (i.e., the last 30-40 years) are rare. A 96 cm long sediment core, covering the past two centuries, provides evidence for intense changes over the last few decades probably related to anthropogenic activities, such as farming, water abstraction etc. A decrease in marine influence is observed starting somewhat earlier but was potentially supported by human management activities. The development of the age-depth model turned out to be a serious issue, as old marine carbon affected samples impacted the robustness of the chronology, hence further investigations are required in most coastal geoarchives from South Africa. A multi-dating approach using several methods is suggested as errors in the chronology distinctly impact paleoenvironmental reconstructions (timing, flux rates etc.). In this context initial paleomagnetic secular variation data are presented, which needs further exploration and inclusion in the future.

  10. Colloid mobilization in an undisturbed sediment core under semiarid recharge rates

    NASA Astrophysics Data System (ADS)

    Liu, Ziru; Flury, Markus; Harsh, James B.; Mathison, Jon B.; Vogs, Carolina

    2013-08-01

    The semiarid US Department of Energy Hanford site has a deep vadose zone with low recharge rates. Contaminants originating from nuclear waste processing are expected to move slowly through the vadose zone. The movement of certain contaminants can be facilitated by colloids. We hypothesized that the low recharge rates and low water contents in semiarid regions, however, tend to inhibit movement of colloidal particles, thereby reducing the risk for colloid-facilitated contaminant transport. The goal of this study was to investigate whether in situ natural colloids can be mobilized and transported in undisturbed, deep vadose zone sediments at the Hanford site under typical, semiarid recharge rates. We sampled an undisturbed sediment core (i.d. 50 cm, 59.5 cm height) from a depth of 17 m below ground at the Hanford 200 Area. The core was set up as a laboratory lysimeter and exposed to an infiltration rate of 18 mm/yr by applying simulated pore water onto the surface. Particle concentrations were quantified in the column outflow, and selected samples were examined microscopically and for elemental composition (transmission electron microscopy and energy dispersive X-ray). Measured water contents and potentials were used to calibrate a numerical model (HYDRUS-1D), which was then applied to simulate colloid mobilization from the sediment core. During 5.3 years of monitoring, natural colloids like silicates, aluminosilicates, and Fe-oxides were observed in the core outflow, indicating the continuous mobilization of in situ colloids. The total amount of particles mobilized during 5.3 years corresponded to 1.1% of the total dispersible colloids inside the core. Comparison of the amounts of colloids released with weathering rates suggests that mineral weathering can be a major source of the mobilized colloids. The fitted colloid release rate coefficient was 6 to 7 orders of magnitude smaller than coefficients reported from previous studies, where disturbed Hanford sediments

  11. Fine-tuning of age integrating magnetostratigraphy, radiocarbon dating, and carbonate cyclicity: Example of lacustrine sediments from Heqing basin (Yunnan, China) covering the past 1 Myr

    NASA Astrophysics Data System (ADS)

    Hu, Shouyun; Goddu, Srinivasa Rao; Appel, Erwin; Verosub, Ken

    2007-05-01

    High-resolution magnetostratigraphy, wavelength spectra of carbonate cyclicities, and AMS radiocarbon dating are integrated to establish an optimum age model for a 168 m long drill core of lacustrine sediments from Heqing basin, Yunnan Province, southwestern China. A 14C age of 51.62 +2.42/-1.85 kyr BP is obtained at a depth of 7.3 m. Remanent magnetization is carried by maghemite and partly in addition by magnetite, both showing the same direction. The polarity sequence clearly reveals the Brunhes/Matuyama (B/M) boundary at 141.5 m. Blake Event is found between 16.3 and 17.5 m, and the upper boundary of Jaramillo is indicated at 167.0 m. Carbonate content and magnetic susceptibility were used for spectral analysis. Fourier analysis was done on the depth section for sliding windows with different window lengths. The spectra within the range of window centers (30-140 m) show a dominant long wavelength, which changes from about 18.5 m in the lower part (>65 m depth) to about 14.5 m in the upper part (<65 m depth) of the core. It is assumed that the long wavelength peak represents the 95-kyr Milankovitch eccentricity cycle. The B/M boundary and Blake Event match very well with this model, but the age of Jaramillo is strongly underestimated. Fourier spectra of sliding windows slightly indicate a drop of the sedimentation rate at the lowermost part of the core. An optimum age model is calculated by cubic spline interpolation using tie points from 14C dating, magnetostratigraphy ('true' ages of Blake Event, B/M boundary, and Jaramillo), and wavelengths of carbonate (change in sedimentation rate at 65 m). Alternative depth-to-age transfer functions were tested, i.e. a wavelength age model (using sedimentation rates with 14C as a tie point), a cyclostratigraphic model (using bandpass-filtered carbonate data corresponding to 95 kyr eccentricity cycles) and correlation of carbonate variations to the marine oxygen isotope curve. However, none of the approaches lead to a

  12. Detection of Tephra Layers in Antarctic Sediment Cores with Hyperspectral Imaging.

    PubMed

    Aymerich, Ismael F; Oliva, Marc; Giralt, Santiago; Martín-Herrero, Julio

    2016-01-01

    Tephrochronology uses recognizable volcanic ash layers (from airborne pyroclastic deposits, or tephras) in geological strata to set unique time references for paleoenvironmental events across wide geographic areas. This involves the detection of tephra layers which sometimes are not evident to the naked eye, including the so-called cryptotephras. Tests that are expensive, time-consuming, and/or destructive are often required. Destructive testing for tephra layers of cores from difficult regions, such as Antarctica, which are useful sources of other kinds of information beyond tephras, is always undesirable. Here we propose hyperspectral imaging of cores, Self-Organizing Map (SOM) clustering of the preprocessed spectral signatures, and spatial analysis of the classified images as a convenient, fast, non-destructive method for tephra detection. We test the method in five sediment cores from three Antarctic lakes, and show its potential for detection of tephras and cryptotephras. PMID:26815202

  13. Detection of Tephra Layers in Antarctic Sediment Cores with Hyperspectral Imaging

    PubMed Central

    Aymerich, Ismael F.; Oliva, Marc; Giralt, Santiago; Martín-Herrero, Julio

    2016-01-01

    Tephrochronology uses recognizable volcanic ash layers (from airborne pyroclastic deposits, or tephras) in geological strata to set unique time references for paleoenvironmental events across wide geographic areas. This involves the detection of tephra layers which sometimes are not evident to the naked eye, including the so-called cryptotephras. Tests that are expensive, time-consuming, and/or destructive are often required. Destructive testing for tephra layers of cores from difficult regions, such as Antarctica, which are useful sources of other kinds of information beyond tephras, is always undesirable. Here we propose hyperspectral imaging of cores, Self-Organizing Map (SOM) clustering of the preprocessed spectral signatures, and spatial analysis of the classified images as a convenient, fast, non-destructive method for tephra detection. We test the method in five sediment cores from three Antarctic lakes, and show its potential for detection of tephras and cryptotephras. PMID:26815202

  14. Results of submerged sediment core sampling and analysis on Par Pond, Pond C, and L Lake: July 1995

    SciTech Connect

    Koch, J.W. II; Martin, F.D.; Friday, G.P.

    1996-06-01

    Sediment cores from shallow and deep water locations in Par Pond, Pond C, and L Lake were collected and analyzed in 1995 for radioactive and nonradioactive constituents. This core analysis was conducted to develop a defensible characterization of contaminants found in the sediments of Par Pond, Pond C, and L Lake. Mercury was the only nonradiological constituent with a nonestimated quantity that was detected above the U.S Environmental Protection Agency Region IV potential contaminants of concern screening criteria. It was detected at a depth of 0.3--0.6 meters (1.0--2.0 feet) at one location in L Lake. Cesium-137, promethium-146, plutonium-238, and zirconium-95 had significantly higher concentrations in Par Pond sediments than in sediments from the reference sites. Cobalt-60, cesium-137, plutonium-238, plutonium-239/240, and strontium-90 had significantly higher concentrations in L-Lake sediments than sediments from the reference sites.

  15. Meiofauna Analyses of Sediment Cores to Investigate the Influence of Sea Level Rise on Saltmarsh Development

    NASA Astrophysics Data System (ADS)

    Radl, Michaela; Hughes, Rob G.; Horne, David J.

    2013-04-01

    The text-book explanation for the development of coastal saltmarshes is through increase in sediment elevation (with respect to sea level), mainly facilitated by plants leading to seaward progradation and succession from the lowest plant species to higher ones. An alternative hypothesis is that saltmarshes develop mainly by sea level rise leading to landward migration, where succession will be from the higher to lower species. These competing hypotheses are tested by comparing the assemblages of foraminifera in sediment cores with surface samples, in saltmarshes on isostatically rising (NW Scotland) and sinking coasts (SE England and Wales). The surface meiofauna assemblages differ with saltmarsh vertical zones and between saltmarshes. Ostracod abundance decreased with elevation at both sites and none were found in the high marsh (among sea couch grass Elytrigia atherica), limiting their use in some succession studies. The ratio of agglutinated foraminifera (e.g. Jadammina macrescens) to calcified species (e.g. Quinqueloculina spp.) increases with elevation. Geographical differences also occur which may be related to different sediment characteristics, particularly grain size, water content and plant species or grazing effects. For example, the domination of the mid-low saltmarsh by Cornuspira involuens on the sandier west coast in Wales and Quinqueloculina spp. in a muddier saltmarsh in SE England. Foraminifera assemblages throughout a 2.5 meter core in Tollesbury (SE England) were dominated by agglutinated species, indicating high marsh. The absence of lower marsh assemblages supports the hypothesis for the importance of sea level rise in saltmarsh development. In Loch Riddon (W Scotland) too there is no evidence of low marsh assemblages in the sediment strata (1 meter core). While there is no evidence of facilitation succession in this saltmarsh, sea level rise is unlikely to be responsible for its formation and development as it is on a rising coast.

  16. Identifying water-quality trends in the Trinity River, Texas, USA, 1969-1992, using sediment cores from Lake Livingston

    USGS Publications Warehouse

    Van Metre, P.C.; Callender, E.

    1996-01-01

    Chemical analyses were done on cores of bottom sediment from three locations in Lake Livingston, a reservoir on the Trinity River in east Texas to identify trends in water quality in the Trinity River using the chemical record preserved in bottom sediments trapped by the reservoir. Sediment cores spanned the period from 1969, when the reservoir was impounded, to 1992, when the cores were collected. Chemical concentrations in reservoir sediment samples were compared to concentrations for 14 streambed sediment samples from the Trinity River Basin and to reported concentrations for soils in the eastern United States and shale. These comparisons indicate that sediments deposited in Lake Livingston are representative of the environmental setting of Lake Livingston within the Trinity River Basin. Vertical changes in concentrations within sediment cores indicate temporal trends of decreasing concentrations of lead, sodium, barium, and total DDT (DDT plus its metabolites DDD and DDE) in the Trinity River. Possible increasing temporal trends are indicated for chlordane and dieldrin. Each sediment-derived trend is related to trends in water quality in the Trinity River or known changes in environmental factors in its drainage basin or both.

  17. Geochemical proxies for weathering and provenance of Late Quaternary alluvial core-sediments from NW India

    NASA Astrophysics Data System (ADS)

    Singh, Ajit; Amir, Mohd; Paul, Debajyoti; Sinha, Rajiv

    2014-05-01

    The Indo-Gangetic alluvial plains are formed by sediment deposition in the foreland basin as a result of upliftment and subsequent erosion of the Himalaya. Earlier study (Sinha et al., 2013) has shown the subsurface existence of buried channel bodies beneath the Ghaggar plains in NW Indo-Gangetic plains. The mapped sand bodies follow trace of a paleochannel that begins at the mountain front near the exit of river Sutlej and extends to the northern margin of the Thar desert, suggesting existence of a large Himalayan-sourced river (Singh et al., 2011) in the past. The buried sand bodies hold potential records of erosion history over the Himalaya that could be used to assess climate-controlled erosion over the Himalaya. Geochemical variations in the sediments from two (~45m long) cores drilled below the trace of the paleochannel (upstream) near Sirhind, Punjab and two cores (GS-10 & 11) from downstream near Kalibangan, Rajasthan, are used in this study to understand the erosional pattern over the Himalaya during Late Quaternary. Down-core variations in chemical index of alteration (CIA=51-79) along with K2O/Na2O and Al2O3/(CaO+Na2O) ratios are consistent with the trends of SW summer monsoonal fluctuations during the Glacial-Interglacial periods indicating climate controlled weathering at the source; higher values during Interglacial and lower during Glacial periods with maximum value during the Holocene. Sr-Nd isotopic compositions of drill-cores sediments, 87Sr/86Sr (0.7314-0.7946), ɛNd (-23.2 to -14) are within the range of silicate rocks from the Higher and Lesser Himalaya. Significant down-core variations in 87Sr/86Sr and ɛNd are observed that reflect the mixing of varying proportions of the Higher and Lesser Himalayan sediments, the two dominant sources to the core sites. Sediments deposited during MIS-2 and MIS-4, cold and dry Glacial periods, show high 87Sr/86Sr and low ɛNd suggesting an enhanced contribution from the Lesser Himalayan rocks that are

  18. Rare earth elements in core marine sediments of coastal East Malaysia by instrumental neutron activation analysis.

    PubMed

    Ashraf, Ahmadreza; Saion, Elias; Gharibshahi, Elham; Kamari, Halimah Mohamed; Kong, Yap Chee; Hamzah, Mohd Suhaimi; Elias, Md Suhaimi

    2016-01-01

    A study was carried out on the concentration of REEs (Dy, Sm, Eu,Yb, Lu, La and Ce) that are present in the core marine sediments of East Malaysia from three locations at South China Sea and one location each at Sulu Sea and Sulawesi Sea. The sediment samples were collected at a depth of between 49 and 109 m, dried, and crushed to powdery form. The entire core sediments prepared for Instrumental Neutron Activation Analysis (INAA) were weighted approximately 0.0500 g to 0.1000 g for short irradiation and 0.1500 g to 0.2000 g for long irradiation. The samples were irradiated with a thermal neutron flux of 4.0×10(12) cm(-2) s(-1) in a TRIGA Mark II research reactor operated at 750 kW. Blank samples and standard reference materials SL-1 were also irradiated for calibration and quality control purposes. It was found that the concentration of REEs varies in the range from 0.11 to 36.84 mg/kg. The chondrite-normalized REEs for different stations suggest that all the REEs are from similar origins. There was no significant REEs contamination as the enrichment factors normalized for Fe fall in the range of 0.42-2.82. PMID:26405840

  19. U-series disequilibria in early diagenetic minerals from Lake Magadi sediments, Kenya: Dating potential

    NASA Astrophysics Data System (ADS)

    Goetz, Christian; Hillaire-Marcel, Claude

    1992-03-01

    At the southern end of the Gregory Rift Valley, Lake Magadi occupies the bottom of a relatively large drainage basin. It is presently covered by a thick trona crust, which overlies two silty-clay units deposited during Late Pleistocene high lake stands. These units consist of a mixture of detrital grains (anorthoclase, amphiboles, quartz), clays (illite, authigenic zeolites), phosphates, and sedimentary sodium silicates and cherts. A late diagenetic calcite is occasionally observed. The authigenic and/or diagenetic mineralogical phases were extracted and analyzed for their uranium and thorium isotope contents. All yielded highly correlated ( 234U /232Th vs. 238U /232Th ) and ( 230Th /232Th vs. 234U /232Th ) isochrons defining two-component mixing systems (detrital and authigenic phases). The detrital component is characterized by large excesses of 230Th (over 234U) and by 230Th /232Th ratios carrying an imprint of the source rocks (e.g., Precambrian basement vs. volcanics) and indicating efficient uranium-leaching processes during the previous pedologic cycle. The slope of the isochrons defines the 234U /238U and 230Th /234U ratios of the authigenic component, i.e., the age of the uranium-uptake episode. Zeolites yield an age of 10.4 ± 0.6 ka. This age is in agreement with the 14C chronology already established for the most recent high lake level episode in the basin (10,000-12,000 yr Bp). Sodium-silicates and cherts yield distinct ages of 98.5 ± 20 and 6 ± 3 ka, respectively, for the lower and upper lacustrine units. These ages allow the conclusion that (1) sedimentary silicates are of late diagenetic origin, and (2) that the lower lacustrine unit was deposited during a former high Lake Magadi level, possibly during the lacustrine episode dated at 135 ± 10 ka from uranium-series measurements on littoral stromatolites. Finally, the late diagenetic calcite, which yields an age of about 5 ka, indicates a significant change in the sediment interstitial water

  20. {sup 210}Pb dating of sediments from the central and northern Adriatic Sea: deposition and preservation of sedimentary organic carbon

    SciTech Connect

    Hamilton, T. F., LLNL

    1998-04-01

    Lead-210 ({sup 21O}Pb) and organic C depth distribution profiles in sediments from the northern and central Adriatic Sea were measured as part of the EEC funded project on Eutrophic Limits of the Northern Adriatic (ELNA). {sup 210}Pb derived mass-accumulation rates decrease southward from between 0.15 and 0.2 g cm{sup -2}y{sup -1} close to the Po River outflow (> 24 m, water depth) to less than 0.04 g cm{sup -2}y{sup -1} in the Jabuka Pit (246 m, water depth) in the central Adriatic Sea. The mass- accumulation rates obtained in the Jabuka Pit correspond to mean sedimentation rates of about 0.03 cm y{sup -1} (ref. porosity = 0.5) and fall between 5 to 20 times lower than rates found for north Adriatic shelf cores. Estimated sedimentation rates are considered as upper limits because of the possible effects of bioturbation and physical disturbance on the {sup 21O}Pb sedimentary record but are consistent with data from previous work. Rates of sediment accumulation and carbon burial appear to be strongly influenced by the transport of fluvial materials from land and transport of fine-grained particles. First-order estimates of organic C burial rates into surface sediment ranged from 1 to 0.028 mMol cm{sup -2}y{sup -1} between the Po delta and the Jabuka Pit regions, respectively. We estimate that a maximum of 50% of organic C preserved in surface sediment may be derived from biological production in the overlying water column.

  1. Atmospheric Mercury Depositional Chronology Reconstructed from Lake Sediments and Ice Core in the Himalayas and Tibetan Plateau.

    PubMed

    Kang, Shichang; Huang, Jie; Wang, Feiyue; Zhang, Qianggong; Zhang, Yulan; Li, Chaoliu; Wang, Long; Chen, Pengfei; Sharma, Chhatra Mani; Li, Qing; Sillanpää, Mika; Hou, Juzhi; Xu, Baiqing; Guo, Junming

    2016-03-15

    Alpine lake sediments and glacier ice cores retrieved from high mountain regions can provide long-term records of atmospheric deposition of anthropogenic contaminants such as mercury (Hg). In this study, eight lake sediment cores and one glacier ice core were collected from high elevations across the Himalaya-Tibet region to investigate the chronology of atmospheric Hg deposition. Consistent with modeling results, the sediment core records showed higher Hg accumulation rates in the southern slopes of the Himalayas than those in the northern slopes in the recent decades (post-World War II). Despite much lower Hg accumulation rates obtained from the glacier ice core, the temporal trend in the Hg accumulation rates matched very well with that observed from the sediment cores. The combination of the lake sediments and glacier ice core allowed us to reconstruct the longest, high-resolution atmospheric Hg deposition chronology in High Asia. The chronology showed that the Hg deposition rate was low between the 1500s and early 1800, rising at the onset of the Industrial Revolution, followed by a dramatic increase after World War II. The increasing trend continues to the present-day in most of the records, reflecting the continuous increase in anthropogenic Hg emissions from South Asia. PMID:26878654

  2. Geochemical data for core and bottom-sediment samples collected in 2007 from Grand Lake O' the Cherokees, northeast Oklahoma

    USGS Publications Warehouse

    Fey, David L.; Becker, Mark F.; and Smith, Kathleen S.

    2010-01-01

    Grand Lake O' the Cherokees is a large reservoir in northeast Oklahoma, below the confluence of the Neosho and Spring Rivers, both of which drain the Tri-State Mining District to the north. The Tri-State district covers an area of 1,200 mi2 (3,100 km2) and comprises Mississippi Valley-type lead-zinc deposits. A result of 120 years of mining activity is an estimated 75 million tons of processed mine tailings (chat) remaining in the district. Concerns of sediment quality and the possibility of human exposure to cadmium and lead through eating fish have led to several studies of the sediments in the Tri-State district. In order to record the transport and deposition of metals from the Tri-State district by the Spring and Neosho Rivers into Grand Lake O' the Cherokees, the U.S. Geological Survey collected 11 sediment cores and 15 bottom-sediment samples in September 2007. Subsamples from five selected cores and the bottom-sediment samples were analyzed for major and trace elements and forms of carbon. The sediment samples collected from the sediment-water interface had larger average concentrations of zinc, cadmium, and lead than local background. The core collected from the Spring River had the largest concentrations of mining-related elements. A core collected just south of Twin Bridges State Park, at the confluence of the Spring and Neosho Rivers, showed a mixing zone with more mining-related elements coming from the Spring River side. The element zinc showed the most definitive patterns in graphs depicting concentration-versus-depth profiles. A core collected from the main body of the reservoir showed affected sediment down to a depth of 85 cm (33 in). This core and two others appear to have penetrated to below mining-affected sediment.

  3. Distribution, provenance and early diagenesis of major and trace metals in sediment cores from the Mandovi estuary, western India

    NASA Astrophysics Data System (ADS)

    Prajith, A.; Rao, V. Purnachandra; Chakraborty, P.

    2016-03-01

    Major elements and trace metals were analyzed in four sediment cores recovered along a transect in the Mandovi estuary for their distribution, provenance and early diagenesis. The sediments were clayey silts in cores from the upper/lower estuary and sand-dominated in cores from the middle estuary/bay. Organic carbon (OC) content varied from 0.5 to 4%, with higher values in fine-grained sediments. The mean Fe and Mn contents of sediments from the upper/middle estuary were 3-5 times and 8-13 times, respectively higher than the reference sediment (RS) from the same estuary. The mean Fe and Mn contents of sediments from the lower estuary/bay were close to the RS. Strong inter-metal correlation among Ti, V, Cr and Zr in all the cores indicated their contribution from a common source, probably the laterites from hinterland. Trace metals were more enriched in fine-grained sediments than in sand-dominated sediments. Early diagenetic control on the redistribution of metal is evident in core sediments from the middle estuary to Bay. The distribution of Mo, U and Pb followed that of Fe and Mn in the upper estuary and OC in the lower estuary/bay. Our results indicated strong anthropogenic contribution of metals from ore deposits in the upper/middle estuary. The Mn and Cr contents of sediment in the upper/middle estuary and Fe in the middle estuary were highly enriched suggestive of 'significant pollution signal'. More trace metals from the middle estuary were moderately enriched. Speciation studies showed Mn and Pb occurred abundantly in non-residual phases. High Mn content and its high percentage in exchangeable and reductive phases indicate that it was susceptible to be mobilized. However, Fe, Cu and Ni occurred abundantly in residual phases and less percentage of them were expected to be bio-available.

  4. Physical processes in Subglacial Lake Whillans, West Antarctica: Inferences from sediment cores

    NASA Astrophysics Data System (ADS)

    Hodson, T. O.; Powell, R. D.; Brachfeld, S. A.; Tulaczyk, S.; Scherer, R. P.

    2016-06-01

    The hydrologic system beneath the Antarctic Ice Sheet is thought to influence both the dynamics and distribution of fast flowing ice streams, which discharge most of the ice lost by the ice sheet. Despite considerable interest in understanding this subglacial network and its affect on ice flow, in situ observations from the ice sheet bed are exceedingly rare. Here we describe the first sediment cores recovered from an active subglacial lake. The lake, known as Subglacial Lake Whillans, is part of a broader, dynamic hydrologic network beneath the Whillans Ice Stream in West Antarctica. Even though "floods" pass through the lake, the lake floor shows no evidence of erosion or deposition by flowing water. By inference, these floods must have insufficient energy to erode or transport significant volumes of sediment coarser than silt. Consequently, water flow beneath the region is probably incapable of incising continuous channels into the bed and instead follows preexisting subglacial topography and surface slope. Sediment on the lake floor consists of till deposited during intermittent grounding of the ice stream following flood events. The fabrics within the till are weaker than those thought to develop in thick deforming beds suggesting subglacial sediment fluxes across the ice plain are currently low and unlikely to have a large stabilizing effect on the ice stream's grounding zone.

  5. Sediment cores and chemistry for the Kootenai River White Sturgeon Habitat Restoration Project, Boundary County, Idaho

    USGS Publications Warehouse

    Barton, Gary J.; Weakland, Rhonda J.; Fosness, Ryan L.; Cox, Stephen E.; Williams, Marshall L.

    2012-01-01

    The Kootenai Tribe of Idaho, in cooperation with local, State, Federal, and Canadian agency co-managers and scientists, is assessing the feasibility of a Kootenai River habitat restoration project in Boundary County, Idaho. This project is oriented toward recovery of the endangered Kootenai River white sturgeon (Acipenser transmontanus) population, and simultaneously targets habitat-based recovery of other native river biota. Projects currently (2010) under consideration include modifying the channel and flood plain, installing in-stream structures, and creating wetlands to improve the physical and biological functions of the ecosystem. River restoration is a complex undertaking that requires a thorough understanding of the river. To assist in evaluating the feasibility of this endeavor, the U.S. Geological Survey collected and analyzed the physical and chemical nature of sediment cores collected at 24 locations in the river. Core depths ranged from 4.6 to 15.2 meters; 21 cores reached a depth of 15.2 meters. The sediment was screened for the presence of chemical constituents that could have harmful effects if released during restoration activities. The analysis shows that concentrations of harmful chemical constituents do not exceed guideline limits that were published by the U.S. Army Corps of Engineers in 2006.

  6. Lake Chad sedimentation and environments during the late Miocene and Pliocene: New evidence from mineralogy and chemistry of the Bol core sediments

    NASA Astrophysics Data System (ADS)

    Moussa, Abderamane; Novello, Alice; Lebatard, Anne-Elisabeth; Decarreau, Alain; Fontaine, Claude; Barboni, Doris; Sylvestre, Florence; Bourlès, Didier L.; Paillès, Christine; Buchet, Guillaume; Duringer, Philippe; Ghienne, Jean-François; Maley, Jean; Mazur, Jean-Charles; Roquin, Claude; Schuster, Mathieu; Vignaud, Patrick; Brunet, Michel

    2016-06-01

    This study presents mineralogical and geochemical data from a borehole drilled near the locality of Bol (13°27‧N, 14°44‧E), in the eastern archipelago of the modern Lake Chad (Chad). Samples were taken from a ∼200 m long core section forming a unique sub-continuous record for Central Africa. Among these samples, 25 are dated between 6.4 and 2.4 Ma. Dominant minerals are clays (66% average) mixed with varying amounts of silt and diatomite. The clay fraction consists of Fe-beidellite (87% average), kaolinite, and traces of illite. Clay minerals originate from the erosion of the vertisols that surrounded the paleolake Chad. Sedimentological data indicate that a permanent lake (or recurrent lakes) existed from 6.7 until 2.4 Ma in the vicinity of Bol. By comparison with modern latitudinal distribution of vertisols in Africa the climate was Sudanian-like. Changes in the sedimentation rate suggest a succession of wetter and dryer periods during at least six million years in the region during the critical time period covering the Miocene-Pliocene transition.

  7. Radiological and multi-element analysis of sediments from the Proserpina reservoir (Spain) dating from Roman times.

    PubMed

    Baeza, A; Guillén, J; Ontalba Salamanca, M A; Rodríguez, A; Ager, F J

    2009-10-01

    The Proserpina dam was built in Roman times to provide drinking water to Emerita Augusta (today's Mérida in SW Spain). During maintenance work, a sediment core was extracted, offering an excellent opportunity to analyze the historical environmental impacts of the dam and its reservoir over the 2000 years since Roman times. In order to establish an accurate chronology, (14)C ages were determined by accelerator mass spectrometry (AMS). Core samples were assayed for their content in uranium and thorium series isotopes, (40)K, and the anthropogenic radionuclides (137)Cs, (90)Sr, and (239+240)Pu. Potassium-40 presented the highest activity level and was not constant with depth. The uranium and thorium series were generally in equilibrium, suggesting there had been no additional input of natural radionuclides. The presence of (137)Cs was only found in relation with the global fallout in the early 1960s. Multi-element assays were performed using the PIXE and PIGE techniques. Some variations in the multi-element concentrations were observed with depth, but the sediment core could be considered as clean, and no presumptive anthropogenic pollutants were found. Nevertheless, an unusually high Zn content was detected at depths corresponding to pre-Roman times, due to geological anomalies in the area. PMID:19631426

  8. Surface (sea floor) and near-surface (box cores) sediment mineralogy in Baffin Bay as a key to sediment provenance and ice sheet variations

    USGS Publications Warehouse

    Andrews, John T.; Eberl, D.D.

    2011-01-01

    To better understand the glacial history of the ice sheets surrounding Baffin Bay and to provide information on sediment pathways, samples from 82 seafloor grabs and core tops, and from seven box cores were subjected to quantitative X-ray diffraction weight percent (wt.%) analysis of the 2000 m) all show an abrupt drop in calcite wt.% (post-5 cal ka BP?) following a major peak in detrital carbonate (mainly dolomite). This dolomite-rich detrital carbonate (DC) event in JR175BC06 is possibly coeval with the Younger Dryas cold event. Four possible glacial-sourced end members were employed in a compositional unmixing algorithm to gain insight into down core changes in sediment provenance at the deep central basin. Estimates of the rates of sediment accumulation in the central basin are only in the range of 2 to 4 cm/cal ka, surprisingly low given the glaciated nature of the surrounding land.

  9. Why would we use the Sediment Isotope Tomography (SIT) model to establish a 210Pb-based chronology in recent-sediment cores?

    PubMed

    Abril Hernández, José-María

    2015-05-01

    After half a century, the use of unsupported (210)Pb ((210)Pbexc) is still far off from being a well established dating tool for recent sediments with widespread applicability. Recent results from the statistical analysis of time series of fluxes, mass sediment accumulation rates (SAR), and initial activities, derived from varved sediments, place serious constraints to the assumption of constant fluxes, which is widely used in dating models. The Sediment Isotope Tomography (SIT) model, under the assumption of non post-depositional redistribution, is used for dating recent sediments in scenarios in that fluxes and SAR are uncorrelated and both vary with time. By using a simple graphical analysis, this paper shows that under the above assumptions, any given (210)Pbexc profile, even with the restriction of a discrete set of reference points, is compatible with an infinite number of chronological lines, and thus generating an infinite number of mathematically exact solutions for histories of initial activity concentrations, SAR and fluxes onto the SWI, with these two last ranging from zero up to infinity. Particularly, SIT results, without additional assumptions, cannot contain any statistically significant difference with respect to the exact solutions consisting in intervals of constant SAR or constant fluxes (both being consistent with the reference points). Therefore, there is not any benefit in its use as a dating tool without the explicit introduction of additional restrictive assumptions about fluxes, SAR and/or their interrelationship. PMID:25725452

  10. Dissolved methane profiles in marine sediments observed in situ differ greatly from analyses of recovered cores

    NASA Astrophysics Data System (ADS)

    Zhang, X.; Brewer, P. G.; Hester, K.; Ussler, W.; Walz, P. M.; Peltzer, E. T.; Ripmeester, J.

    2009-12-01

    The flux of dissolved methane through continental margin sediments is of importance in marine geochemistry due to its role in massive hydrate formation with enigmatic climate consequences, and for the huge and complex microbial assemblage it supports. Yet the actual dissolved methane concentration driving this flux is poorly known since strong degassing during sample recovery from depth is commonplace. Thus, pore water analyses from high CH4 environments typically show values clustered around the one-atmosphere equilibrium value of 1-2 mM, erasing the original pore water profile and frustrating model calculations. We show that accurate measurement of pore water profiles of dissolved CH4, SO4, and H2S can be made rapidly in situ using a Raman-based probe. While Raman spectra were formerly believed to yield only qualitative data we show that by using a peak area ratio technique to known H2O bands and a form of Beer’s Law quantitative data may be readily obtained. Results from Hydrate Ridge, Oregon clearly show coherent profiles of all three species in this high flux environment, and while in situ Raman and conventional analyses of SO4 in recovered cores agree well, very large differences in CH4 are found. The in situ CH4 results show up to 35 mM in the upper 30cm of seafloor sediments and are inversely correlated with SO4. This is below the methane hydrate saturation value, yet disturbing the sediments clearly released hydrate fragments suggesting that true saturation values may exist only in the hydrate molecular boundary layer, and that lower values may typically characterize the bulk pore fluid of hydrate-hosting sediments. The in situ Raman measurement protocols developed take only a few minutes. Profiles obtained in situ showed minimal fluorescence while pore water samples from recovered cores quickly developed strong fluorescence making laboratory analyses using Raman spectroscopy challenging and raising questions over the reaction sequence responsible for

  11. Paleomagnetism of a 150 m Sediment Core from the Co-Seismic Subsidence Depocenter of the 2009 Mw=6.1 L'Aquila Earthquake (Italy)

    NASA Astrophysics Data System (ADS)

    Macri', P.; Porreca, M.; Sagnotti, L.; Smedile, A.; Speranza, F.

    2014-12-01

    The 150 m deep borehole LAQUI-CORE was drilled in the co-seismic subsidence depocenter, shown by INSAR images in the middle Aterno continental basin, after the 2009 Mw=6.1 earthquake that struck the historical city of L'Aquila (Italy). The drill site was located where geological, seismological and geophysical surveys indicated a continuous record with a maximum thickness of fine-grained sediments. The aim was to investigate stratigraphic and geometrical architecture of the middle Aterno basin, in order to define its relationship with the local active fault system. The core consists of continental Holocene and Pleistocene sediments subdivided into two main sequences separated by an erosional discontinuity. The upper sequence consists of 41 m thick fluvial-alluvial deposits of silt and sand interbedded with metric intervals of rounded gravel. The lower sequence consists of palustrine sediments of clays and sands interrupted in the middle by a 30 m thick coarse gravel deposit. Biostratigraphic and radiometric measurements on the core are still in progress, while high-resolution paleomagnetic and rock magnetic measurements were performed on u-channel samples. Natural remanent magnetization (NRM), anhysteretic remanent magnetization (ARM), magnetic susceptibility (k) were measured at 1-cm spacing using a 2G Cryogenic magnetometer. The sediments carry a well-defined characteristic remanent magnetization (ChRM), isolated between 15 and 40 mT AF steps. The ChRM is of normal polarity down to ca. 83 m depth, with paleomagnetic inclination values oscillating around 57°. The main magnetic carrier in this interval is magnetite, below ca. 115 m depth the data show frequent apparent polarity changes due to the additional widespread occurrence of greigite. This interval has to be anyway older than the Brunhes-Matuyama transition. Relative paleointensity (RPI) curves were obtained by normalising the NRM20mT with k and ARM20mT and may be useful to improve the dating of the core.

  12. Latitudinal trends in fluxes and congener patterns of PCBs inferred from lake sediment cores from mid-latitude and Arctic Lakes

    SciTech Connect

    Muir, D.; Omelchenko, A.; Grift, N.; Lockhart, L.; Wilkinson, P.; Brunskill, G.; Robbins, J.A.

    1995-12-31

    Sediment cores collected from 9 remote lakes in central and Arctic Canada (49{degree}N to 82{degree}N and from 71{degree} to 136{degree}W) were analyzed for PCBs with the objective of examining latitudinal and temporal trends in deposition. Core slices (1--1.3 cm) were dated with {sup 210}Pb and {sup 137}Cs using the Robbins rapid steady-state mixing model and sediment focusing factors were determined with the aid of soil cores or predictions of historical radionuclide deposition. Slices were freeze-dried, Soxhlet extracted with DCM and chromatographed on Florisil, then analyzed by high resolution GC-ECD with confirmation by GC-HRMS. {Sigma}PCB concentrations in surface sediments were low ranging from 8 to 40 ng{center_dot}g{sup {minus}1} (dry wt) in southern mid-continental sites (49--63{degree}N) to 2 ng{center_dot}g{sup {minus}1} in Lake Hazen, the most northerly location (82{degree}N). Highest concentrations were found in the most recent slices (1980s) of cores from high Arctic lakes (at 75 and 82{degree}N) whereas peak concentrations were reached earlier (in the 1970s) at more southerly locations. Principal components analysis revealed that sediments from high Arctic lakes could be distinguished by greater proportions of lower chlorinated PCBs in comparison with published results for Lakes Ontario and Superior. Focus corrected {Sigma}PCBs fluxes ranged from 305 to 920 ng{center_dot}m{sup 2}{center_dot}yr{sup {minus}1} in the 9 lakes and were negatively correlated with latitude (r{sup 2} = 0.53). Fluxes of Cl{sup 8} CBs had a strong negative correlation with latitude (r2 = 0.88) while Cl{sup 3} CBs showed no latitudinal trend. The results generally support several of the predictions of the cold condensation hypothesis.

  13. Tracking the Transformation and Preservation of Organic Biomarkers in a Varved Sediment-Core Series

    NASA Astrophysics Data System (ADS)

    Tolu, J.; Bigler, C.; Bindler, R.

    2014-12-01

    An important premise for reconstructing environmental changes using sediment records is to understand which environmental information reaches the lake bottom and how diagenetic processes may affect the proxies, such as terrestrial and aquatic organic biomarkers. We can tackle this question using a unique series of varved sediment cores collected from the lake Nylandssjön (northern Sweden). In addition to limnological and sediment trap sampling since 2001, we have a collection of freeze cores taken in late winter and stored since 1979, which allows us to track individual varve years (e.g., 1978) over time (~30 years). A previous study using this collection showed that 23 % of C and 35 % of N were lost during the first 25 years with a C:N ratio increase of ≈21, suggesting important implications for diagenetic effects on organic biomarkers. To assess the preservation/transformation of organic biomarkers, we developed a new Pyrolysis-Gas Chromatography/Mass Spectrometry method that allows the rapid determination of biomarkers from the common OM classes (e.g., plant waxes, microbial lipids, lignins) using sub-mg sample sizes and thus applicable to high-resolution sampling of the varved sediment (Tolu et al., under review). Our results show that the different biomarkers exhibit a broad spectrum of reactivities over ~30 years -% change determined by ([Peak area at t] - [Peak area at t=0])/ [peak area at t=0] x 100-. For example: 67-80 % of the algal chlorophyll-derived product 'phytene' is lost depending which single varve year is followed over time (e.g., 1979). Only 12-32 % of "pristene", the degraded form of algal chlorophyll, is lost. The guaiacyl and syringyl lignin units are affected by a smaller loss, i.e. 5-15 %, and the S/G ratio, indicative of angiosperm/gymnosperm plant input remains stable, which is contrary to previous work on non-varved lake sediments. Considering all biomarkers, the degradation/production plateaued after ~15 years, which indicates that

  14. Post-depositional remanent magnetization lock-in depth in precisely dated varved sediments assessed by archaeomagnetic field models

    NASA Astrophysics Data System (ADS)

    Mellström, Anette; Nilsson, Andreas; Stanton, Tania; Muscheler, Raimund; Snowball, Ian; Suttie, Neil

    2015-01-01

    Accurate and precise chronologies are needed to evaluate the existence and effect of a post-depositional remanent magnetization lock-in process on sedimentary palaeomagnetic records. Here we present lock-in modelling results of two palaeomagnetic records from varved lake sediments (lakes Kälksjön and Gyltigesjön) in Sweden by using model predictions based on archaeomagnetic data. We used the 14C wiggle-match dating technique to improve the precision of the Kälksjön varve chronology in the period between 3000 and 2000 cal BP, which is characterized by pronounced palaeomagnetic secular variation. This method allowed us to infer an age model with uncertainties of ±20 years (95.4% probability range). Furthermore, we compared the palaeomagnetic record of Kälksjön to Gyltigesjön, which has a corresponding 14C wiggle-matched chronology. The ages of palaeomagnetic features derived from the wiggle-matched varve chronologies are older than those predicted by the archaeomagnetic models. Lock-in modelling was performed with different filter functions to explain the temporal offset and the amplitude of the lake sediment palaeomagnetic data. The analyses suggest that a linear lock-in function with lock-in depths (the depth below which no more natural magnetic remanence is acquired) that range between 30 and 80 cm in Kälksjön and 50 and 160 cm in Gyltigesjön are most appropriate to explain the data. These relatively deep lock-in depths in sediments without a bioturbated 'mixed-zone' can be attributed to the relatively high organic contents and low density of the lake sediments, which contribute to a thick unconsolidated upper zone of the sediment sequence in which re-alignment of magnetic particles can take place.

  15. Causal links between Nile floods and eastern Mediterranean sapropel formation during the past 125 kyr confirmed by OSL and radiocarbon dating of Blue and White Nile sediments

    NASA Astrophysics Data System (ADS)

    Williams, M. A. J.; Duller, G. A. T.; Williams, F. M.; Woodward, J. C.; Macklin, M. G.; El Tom, O. A. M.; Munro, R. N.; El Hajaz, Y.; Barrows, T. T.

    2015-12-01

    It has long been hypothesised that beds of highly organic mud or sapropels seen in marine sediment cores retrieved from the floor of the eastern Mediterranean accumulated during times of high Nile fluvial discharge. Our recent fieldwork in the valleys of the Blue Nile, the White Nile and the main Nile has for the first time revealed a sequence of extreme flood episodes synchronous with sapropel units S5 (124 kyr), S4 (102 kyr), S3 (81 kyr), S2 (55 kyr) and S1 (13.5-6.5 kyr). There are more weakly defined links with Nile floods and sapropel units S9 (240 kyr), S8 (217 kyr), S7 (195 kyr), S6 (172 kyr), but the dating error terms are too large to allow us to be too definite. During times of extreme floods over the past 125 kyr, wide distributary channels of the Blue Nile flowed across the Gezira alluvial fan in central Sudan and transported a bed load of sand and gravel into the lower White Nile valley. The sands were reworked by wind to form source-bordering dunes, all of which contain heavy minerals of Ethiopian provenance. These source-bordering dunes were active at 115-105 kyr, 60 kyr and 12-7 kyr, all times of extreme Blue Nile floods. The flood and dune sediments were dated using a combination of optically stimulated luminescence (OSL) and radiocarbon analyses. The Quaternary record of Nile floods discussed here shows a precessional signal and reflects episodes of stronger summer monsoon and more northerly seasonal movement of the ITCZ, linked to times of higher insolation in northern tropical latitudes. Progressive aggradation of Holocene Nile channels in northern Sudan has had a profound influence upon human settlement in the last 8 kyr.

  16. Using lead isotopes and trace element records from two contrasting Lake Tanganyika sediment cores to assess watershed – Lake exchange

    USGS Publications Warehouse

    Odigie, Kingsley; Cohen, A.D.; Swarzenski, Peter W.; Flegal, R

    2014-01-01

    Lead isotopic and trace element records of two contrasting sediment cores were examined to reconstruct historic, industrial contaminant inputs to Lake Tanganyika, Africa. Observed fluxes of Co, Cu, Mn, Ni, Pb, and Zn in age-dated sediments collected from the lake varied both spatially and temporally over the past two to four centuries. The fluxes of trace elements were lower (up to 10-fold) at a mid-lake site (MC1) than at a nearshore site (LT-98-58), which is directly downstream from the Kahama and Nyasanga River watersheds and adjacent to the relatively pristine Gombe Stream National Park. Trace element fluxes at that nearshore site did not measurably change over the last two centuries (1815–1998), while the distal, mid-lake site exhibited substantial changes in the fluxes of trace elements – likely caused by changes in land use – over that period. For example, the flux of Pb increased by ∼300% from 1871 to 1991. That apparent accelerated weathering and detrital mobilization of lithogenic trace elements was further evidenced by (i) positive correlations (r = 0.77–0.99, p < 0.05) between the fluxes of Co, Cu, Mn, Ni, Pb, and Zn and those of iron (Fe) at both sites, (ii) positive correlations (r = 0.82–0.98, p < 0.01, n = 9) between the fluxes of elements (Al, Co, Cu, Fe, Mn, Ni, Pb, and Zn) and the mass accumulation rates at the offshore site, (iii) the low enrichment factors (EF < 5) of those trace elements, and (iv) the temporal consistencies of the isotopic composition of Pb in the sediment. These measurements indicate that accelerated weathering, rather than industrialization, accounts for most of the increases in trace element fluxes to Lake Tanganyika in spite of the development of mining and smelting operations within the lake’s watershed over the past century. The data also indicate that the mid-lake site is a much more sensitive and useful recorder of environmental changes than the nearshore site. Furthermore, the lead isotopic compositions

  17. An Ocean Sediment Core-Top Calibration of Foraminiferal (Cibicides) Stable Carbon Isotope Ratios

    NASA Astrophysics Data System (ADS)

    Schmittner, A.; Mix, A. C.; Lisiecki, L. E.; Peterson, C.; Mackensen, A.; Cartapanis, O. A.

    2015-12-01

    Stable carbon isotope ratios (δ13C) measured on calcium carbonate shells of benthic foraminifera (cibicides) from late Holocene sediments (δ13CCib) are compiled and compared with newly updated datasets of contemporary water-column δ13C observations of dissolved inorganic carbon (δ13CDIC) as the initial core-top calibration of the international Ocean Circulation and CarbonCycling (OC3) project. Using selection criteria based on the spatial distance between samples we find high correlation between δ13CCib and natural (pre-industrial) δ13CDIC, confirming earlier work. However, our analysis reveals systematic differences such as higher (lower) δ13CCib values in the Atlantic (Indian and Pacific) oceans. Regression analyses are impacted by anthropogenic carbon and suggest significant carbonate ion, temperature, and pressure effects, consistent with lab experiments with planktonic foraminifera and theory. The estimated standard error of core-top sediment data is generally σ ~= 0.25 ‰, whereas modern foram data from the South Atlantic indicate larger errors (σ ~= 0.4 ‰).

  18. Holocene environment changes around the Sara Us River, northern China, revealed by optical dating of lacustrine-aeolian sediments

    NASA Astrophysics Data System (ADS)

    Zhao, Hui; Sheng, Yongwei; Li, Bo; Fan, Yuxin

    2016-04-01

    The Sara Us River is located along the boundary of the Mu Us Desert and the Chinese Loess Plateau in northern China. The river has cut down through Quaternary sediments creating 70-80 m deep valleys with thick lacustrine/aeolian sequences exposed. We applied optical stimulated luminescence on sediments from a Holocene section of aeolian sand/lacustrine deposits in the top of the river valley. The dating results show that a humid period existed from 7.1 to 2.0 ka ago as evidenced by two layers of peat and lacustrine sediments. However, compared to other published Holocene sections in the Sara Us River valleys close to the section under studying, the local environment experienced very complicated changes during the Holocene. All of the sections recorded a period with drought and/or cold before the Holocene at around 13 ka, and an episode of aridity after about 2 ka ago as evidenced by the layers of aeolian sand. However, the ages of the lacustrine and peat layers in these sections are substantially different. Geomorphological analysis by digital elevation models does not support the existence of a mega lake covering the study area at 2 ka. The intricate environmental changes may have been caused by the meandering of the Sara Us River. Environmental changes also strongly affected human migration in this area, which is documented by Chinese historical records.

  19. Phosphorus in foraminiferal sediments from North Atlantic Ridge cores and in pure limestones

    NASA Technical Reports Server (NTRS)

    Sherwood, B. A.; Sager, S. L.; Holland, H. D.

    1987-01-01

    Samples of foraminiferal ooze from two North Atlantic cores were cleaned and progressively dissolved. Most of the P, Fe, and Mn was released during the first of two reductive cleaning steps. Most of the remainder of these elements and most of the Ca were released during the final acid dissolution step. The P in these samples is present largely in Fe- and Mn-rich coatings, not as a constituent of the foraminiferal shells themselves. Our results are consistent with those of earlier studies. The concentration of P in carbonate oozes in which it is clearly associated with coatings is similar to that of modern calcareous sediments in general, and with that of reasonably pure limestones of all ages. Phosphorus is apparently associated with (Fe, Mn)-oxide coatings in many carbonate sediments. The rate of removal of P from the oceans as a constituent of such sediments depends on the rate of formation of (Fe, Mn) coatings, not on the rate of incorporation of P into calcium carbonate.

  20. Promise and Pitfalls of Using Grain Size Analysis to Identify Glacial Sediments in Alpine Lake Cores.

    NASA Astrophysics Data System (ADS)

    Clark, D. H.

    2011-12-01

    Lakes fed by glacier outwash should have a clastic particle-size record distinct from non-glacial lakes in the same area, but do they? The unique turquoise color of alpine glacial lakes reflects the flux of suspended clastic glacial rock flour to those lakes; conversely, lakes not fed by outwash are generally clear with sediments dominated by organics or slope-wash from nearby hillslopes. This contrast in sediment types and sources should produce a distinct and measureable different in grain sizes between the two settings. Results from a variety of lakes suggest the actual situation is often more subtle and complex. I compare grain size results to other proxies to assess the value of grain size analysis for paleoglacier studies. Over the past 10 years, my colleagues and I have collected and analyzed sediment cores from a wide variety of lakes below small alpine glaciers in an attempt to constrain the timing and magnitude of alpine glaciation in those basins. The basic concept is that these lakes act as continuous catchments for any rock flour produced upstream by glacier abrasion; as a glacier grows, the flux of rock flour to the lake will also increase. If the glacier disappears entirely, rock flour deposition will also cease in short order. We have focused our research in basins with simple sedimentologic settings: mostly small, high-altitude, stripped granitic or metamorphic cirques in which the cirque glaciers are the primary source of clastic sediments. In most cases, the lakes are fed by meltwater from a modern glacier, but were ice free during the earlier Holocene. In such cases, the lake cores should record formation of and changes in activity of the glacier upstream. We used a Malvern Mastersizer 2000 laser particle size analyzer for our grain size analyses, as well as recording magnetic susceptibility, color, and organics for the same cores. The results indicate that although lakes often experience increases in silt and clay-size (<0.63 mm) clastic

  1. A Bayesian Approach to the Evaluation of Equivalent Doses in Sediment Mixtures for Luminescence Dating

    NASA Astrophysics Data System (ADS)

    Sivia, D. S.; Burbidge, C.; Roberts, R. G.; Bailey, R. M.

    2004-11-01

    The optically stimulated luminescence from minerals is proving to be a very useful dating technique in archaeology and physical geography. In this work we study the analysis of the relevant data from a Bayesian viewpoint, comparing some simple age and noise models.

  2. Extensive lake sediment coring survey on Sub-Antarctic Indian Ocean Kerguelen Archipelago (French Austral and Antarctic Lands)

    NASA Astrophysics Data System (ADS)

    Arnaud, Fabien; Fanget, Bernard; Malet, Emmanuel; Poulenard, Jérôme; Støren, Eivind; Leloup, Anouk; Bakke, Jostein; Sabatier, Pierre

    2016-04-01

    sequence from the newly-named Lake Tiercelin (2m-long) was recovered using UWITEC gravity coring equipment operated from a portable rubber boat by 54m water-depth. Those three sequences cover the whole Holocene periods. The 3m-long sequence taken in Lake Guynemer, Loranchet peninsula, was taken using a homemade small platform and a Nesje piston corer by 50m water-depth and covers the last 5 ka cal. BP. Two additional lakes were cored in the vicinity of Lake Armor: Fougères and Poule from which short sequences were taken in order to study environmental changes since the arrival of humans in the 18th century and the subsequent introduction of exogenous plant and animal species. We present here preliminary results including the dating of all sediment sequences as well as their chemical logging and sedimentological description. This already revealed the recurrence of Holocene volcanic eruptions as well as erosion patterns that are comparable among different records. The recognition of tephra layers will further allow the synchronization of terrestrial records together and with marine records around Kerguelen Archipelago. Paleoclimate interpretations of acquired data as well as further measurements are still ongoing processes. However, one may already argue that we collected rare geological sequences of prime importance in the quest of understanding climate patterns affecting the southern high latitudes all along the Holocene. 1. Lamy. et al. 2015. in Integr. Anal. of Intergl. Clim. Dyn. Schulz & Paul eds., 75-81 (Springer) 2. Rebolledo et al. 2015. Quat. Res. 84, 21-36 3. Agosta et al. 2015. Clim. Res. 62, 219-240 4. Van der Putten et al 2015. Quat. Sci. Rev. 122, 142-157

  3. C:N:P Molar Ratios, Sources and 14C Dating of Surficial Sediments from the NW Slope of Cuba

    PubMed Central

    de la Lanza Espino, Guadalupe; Soto, Luis A.

    2015-01-01

    The surficial sediments recovered from 12 sites located near the channel axis of the Florida Straits and the lower slope off NW Cuba were analyzed for total organic carbon (TOC), nitrogen (TN), phosphorus (TP), elemental C:N:P ratios, C and N isotopic values, and 14C dating. The depth profiles of TOC, TN, and TP (0-18 cm) displayed a downcore trend and a significant variation. The TOC values were low (0.15 to 0.62%; 66 to 516 µmol g-1). Sites near the island’s lower slope had lower TOC average concentrations (158-333 µmol g-1) than those closer to the channel axis (averaging 341-516 µmol g-1; p <0.05). The TN concentrations near the lower slope attained 0.11% (80 µmol g-1), whereas, towards the channel axis, they decreased to 0.07% (55 µmol g-1; p<0.05). The C:N ratios ranged from 1.9 to 10.2. The mean molar C:N ratio (5.4) indicated a marine hemipelagic deposition. The TP was lower at sites near the lower slope (38.4 to 50.0 µmol g-1; 0.12% to 0.16%) than those near the channel axis (50.0 to 66 µmol g-1; 0.15 to 0.21%). C:P fluctuated from 7.7 to 14.1 in the surficial sediment layer. The bulk organic δ13Corg and δ15N values confirmed pelagic organic sources, and the 14C dating revealed that the sediments were deposited during the Holocene (1000-5000 yr BP). We suggest that the hydrodynamic conditions in the Straits influence vertical and advective fluxes of particulate organic material trapped in the mixed-layer, which reduces the particulate matter flux to the seabed. PMID:26110791

  4. Studying and Dating Indian Ocean Tsunamis by Using Benthic Foraminifera in the Sediment Stratigraphy of South Andaman Islands, India

    NASA Astrophysics Data System (ADS)

    Johnson, F. C.

    2015-12-01

    We analyzed the foraminifera and dated them to identify the sea level fluctuations in the coastal sediment stratigraphy of Andaman Islands. Our recent paleotsunami investigations are specially focused on unusual large magnitude earthquake and tsunamis in the south coast of Andaman. Our detailed study on the foraminifers preserved in the near sub surface stratigraphy and AMS ages show a strong signature of the tsunami event very much similar to the modern tsunami of December 2004. We found that foraminifer is an ideal geological key to bracket paleotsunami events. The AMS ages of these foraminifers supports the ages given by corals of Sumatra with a small error bar. The recent research approach to identify the ruptures and tsunami based on the corals of south Sumatra suggests a large time span of 1000 years for such mega events. Our foraminiferal archives obtained from 10g soil samples from the 2.5m deep Holocene stratigraphy suggests four seismic predecessors similar to the 2004 event with ~Mw9 with huge rupture. Huge foraminiferal population in the sedimentary stratigraphy is an indicative of sea level changes and the signatures of abrasion in the foraminifer's test (180µm) indicate strong wave surges and bead load transport during tsunami events. Spontaneous death of organisms due to tsunami waves gives an exact time frame with a narrow age limit than the charcoal. Sediment stratigraphy of south Andaman had such changes in each millennium. Sediment stratigraphy sections shows the huge population and assemblages and the AMS dates of this foraminifera in south Andaman shows four mega events. This kind of fossil assemblages are commonly associated with the sea regression and transgressions in the geological time scale. Tamil 'Sangam literatures' one of the oldest literature available in Indian main land and the corals ages from Sumatra are also emphasizes the predecessors of such unusual large magnitude earthquakes and tsunamis in the Indian Ocean. All these

  5. Using the U-Pb system of calcretes to date the time of sedimentation of clastic sedimentary rocks

    NASA Astrophysics Data System (ADS)

    Wang, Z. S.; Rasbury, E. T.; Hanson, G. N.; Meyers, W. J.

    1998-08-01

    The time of sedimentation of rapidly deposited clastic sedimentary rocks in fluvial environments may be directly dated with an uncertainty of less than three million years using U-Pb dating of pure micritic calcite from calcretes developed in overbank deposits. This conclusion is based on results obtained for calcretes (soil calcite, caliche) formed in the late Triassic New Haven Arkose, Hartford Basin, Connecticut, USA. The paragenesis of calcrete samples from the New Haven Arkose was determined using plane-polarized light and cathodoluminesence petrography, uranium fission track analysis, as well as trace element and stable isotope geochemistry. These calcretes contain an abundance of paleosol microfabrics and diagenetic calcite. The first-generation micritic calcite and second-generation blocky calcite have characteristics consistent with soil calcite. The third generation blocky calcite is a later diagenetic calcite (post-soil calcite). The U-Pb data for pure micritic calcite (first generation) in a horizontal sheet calcrete in sedimentary rocks of Norian age gives a 238U/ 207Pb- 206Pb/ 207Pb isochron age of 211.9 ± 2.1 Ma (2-sigma, and used hereafter for all ages). This age and the stratigraphic position for this sample are in excellent agreement with the ages proposed by Gradstein et al. (1994) for the Norian/Rhaetian boundary of 209.6 ± 4.1 Ma and the Carnian/Norian boundary of 220.7 ± 4.4 Ma. The U-Pb data for two samples of first generation micrite in rhizoliths with about 15% insoluble residues give "ages" of 7 ± 66 Ma and 20 ± 36 Ma. These results suggest that relatively recent events disturbed the U-Pb system of these detrital rich samples, perhaps due to redistribution of U during weathering or during chemical dissolution for analysis. The U-Pb data for a sample of pure third generation blocky calcite cement in a rhizolith yields a 206Pb/ 238U- 207Pb/ 235U isochron age of 81 ± 11 Ma. This age suggests that this sample of third generation blocky

  6. Response of Benthic Foraminiferal Size to Oxygen Concentration in Antarctic Sediment Cores

    NASA Astrophysics Data System (ADS)

    Guo, D.; Keating-Bitonti, C.; Payne, J.

    2014-12-01

    Oxygen availability is important for biological reactions and the demand of oxygen is determined by the size of the organism. Few marine organisms can tolerate low oxygen conditions, but benthic foraminifera, a group of amoeboid protists that are highly sensitive to environmental factors, are known to live in these conditions. Benthic foraminifera may be able to live in oxygen stressed environments by changing the size and shape of their test. Low oxygen concentrations should favor smaller, thinner-shelled, flattened test morphologies. We hypothesize that the volume-to-surface area ratio of benthic foraminifera will decrease with decreasing dissolved oxygen concentrations. To test this hypothesis, we picked two calcareous species (Epistominella exigua and Cassulinoides porrectus) and one agglutinated species (Portatrochammina antarctica) from three sediment cores collected from Explorer's Cove, Antarctica. Starting at the sediment-water interface, each core spans approximately 5-8 cm of depth. Profiles of dissolved oxygen concentrations were measured at the time of collection. At specific depths within the cores, we measured the three dimensions of picked foraminiferal tests using NIS-Elements. We calculated the volume and surface area of the tests assuming the shape of the foraminifers was an ellipsoid. The size trends of E. exigua confirm our hypothesis that the test volume-to-surface area ratios correlate positively with dissolved oxygen concentrations (p-value < 0.001). However, the size trends of the other species refute our hypothesis: P. antarctica shows no correlation and C. porrectus shows a negative correlation (p-value < 0.001) to dissolved oxygen concentrations. Thus, our results show that the change in size in response to variations in dissolved oxygen concentrations is species dependent. Moreover, we find that calcareous species are more sensitive to oxygen fluctuations than agglutinated species.

  7. Aligning MIS5 proxy records from Lake Ohrid (FYROM) with independently dated Mediterranean archives: implications for core chronology

    NASA Astrophysics Data System (ADS)

    Zanchetta, G.; Regattieri, E.; Giaccio, B.; Wagner, B.; Sulpizio, R.; Francke, A.; Vogel, L. H.; Sadori, L.; Masi, A.; Sinopoli, G.; Lacey, J. H.; Leng, M. L.; Leicher, N.

    2015-10-01

    The DEEP site sediment sequence obtained during the ICDP SCOPSCO project at Lake Ohrid was dated using tephrostratigraphic information, cyclostratigraphy, and orbital tuning through marine isotope record. Although this approach is suitable for the generation of a general chronological framework of the long succession, it is insufficient to resolve more detailed paleoclimatological questions, such as leads and lags of climate events between marine and terrestrial records or between different regions. In this paper, we demonstrate how the use of different tie points can affect cyclostratigraphy and orbital tuning for the period between ca. 140 and 70 ka and how the results can be correlated with directly/indirectly radiometrically-dated Mediterranean marine and continental proxy records. The alternative age model obtained shows consistent differences with that proposed by Francke et al. (2015) for the same interval, in particular at the level of the MIS6-5e transition. According to this age model, different proxies from the DEEP site sediment record support an increase of temperatures between glacial to interglacial conditions, which is almost synchronous with a rapid increase in sea surface temperature observed in the western Mediterranean. The results show how important a detailed study of independent chronological tie points is for synchronizing different records and to highlight asynchronisms of climate events.

  8. Possibility of radiologic dating based on the glauconite from the paleogene sediments in the eastern mediterranean

    SciTech Connect

    Nikolaeva, I.V.; Golovii, D.I.; Ivanovskaya, T.A.; Krasheninnikov, V.A.

    1986-05-01

    Mineralogic studies and K-Ar age determinations of 11 glauconite specimens from the Paleogene of Syria suggest the need for a comprehensive approach to analyzing the stratigraphy, lithology, mineralogy, and isotope geochemistry, and the use of physical methods of investigation for interpreting the age values obtained by K-Ar methods. The authors conclude that, at the current stage of development K-Ar dating cannot be regarded as a reliable correlation method in stratigraphy.

  9. Extensive MIS 3 glaciation in southernmost Patagonia revealed by cosmogenic nuclide dating of outwash sediments

    NASA Astrophysics Data System (ADS)

    Darvill, Christopher M.; Bentley, Michael J.; Stokes, Chris R.; Hein, Andrew S.; Rodés, Ángel

    2015-11-01

    The timing and extent of former glacial advances can demonstrate leads and lags during periods of climatic change and their forcing, but this requires robust glacial chronologies. In parts of southernmost Patagonia, dating pre-global Last Glacial Maximum (gLGM) ice limits has proven difficult due to post-deposition processes affecting the build-up of cosmogenic nuclides in moraine boulders. Here we provide ages for the Río Cullen and San Sebastián glacial limits of the former Bahía Inútil-San Sebastián (BI-SSb) ice lobe on Tierra del Fuego (53-54°S), previously hypothesised to represent advances during Marine Isotope Stages (MIS) 12 and 10, respectively. Our approach uses cosmogenic 10Be and 26Al exposure dating, but targets glacial outwash associated with these limits and uses depth-profiles and surface cobble samples, thereby accounting for surface deflation and inheritance. The data reveal that the limits formed more recently than previously thought, giving ages of 45.6 ka (+139.9/-14.3) for the Río Cullen, and 30.1 ka (+45.6/-23.1) for the San Sebastián limits. These dates indicate extensive glaciation in southern Patagonia during MIS 3, prior to the well-constrained, but much less extensive MIS 2 (gLGM) limit. This suggests the pattern of ice advances in the region was different to northern Patagonia, with the terrestrial limits relating to the last glacial cycle, rather than progressively less extensive glaciations over hundreds of thousands of years. However, the dates are consistent with MIS 3 glaciation elsewhere in the southern mid-latitudes, and the combination of cooler summers and warmer winters with increased precipitation, may have caused extensive glaciation prior to the gLGM.

  10. Iron Fertilization in the Southern Ocean Deduced From Environmental Magnetism of Sediment Cores

    NASA Astrophysics Data System (ADS)

    Yamazaki, T.; Ikehara, M.

    2012-12-01

    With rock-magnetic technique, biogenic magnetites in sediments can be detected utilizing the characteristics of almost no magnetostatic interactions and narrow coercivity distribution, reflecting occurrence of single-domain magnetites in a chain (e.g., Egli et al., 2010; Roberts et al., 2011). Magnetic mineral assemblages in pelagic sediments of Pacific and Indian Oceans often have two distinctive constituents; the first is characterized by non-interacting on first-order reversal curve (FORC) diagrams and low-coercivity (~40 mT) with small dispersion on isothermal remanent magnetization (IRM) component analyses, and the second is characterized by interacting and middle-coercivity (~100 mT). The former is interpreted as biogenic magnetites and the latter is terrigenous maghemites (Yamazaki, 2009; 2012). The ratio of anhysteretic remanent magnetization susceptibility to saturation IRM reflects relative abundance of the biogenic and terrigenous components. In the Southern Ocean, magnetic mineral concentration increases in glacial periods. The variation pattern closely resembles eolian dust flux records from Antarctic ice cores, but the cause of the linkage was unclear, as the dust flux is too small for the source of terrigenous materials in the Southern Ocean. Our environmental magnetic study of late Pleistocene sediments from the south Indian Ocean revealed that biogenic magnetites are a dominant constituent of the magnetic minerals. In glacials, the abundance of both biogenic and terrigenous components increased with increased proportions of the latter. Increased ocean productivity in glacials is suggested from increased proportions of biogenic magnetites with elongated morphologies, indicative of less-oxic conditions, and increased sedimentation rates. These observations suggest that the increased magnetic concentration in glacials in the Southern Ocean may be explained by iron fertilization; the production of biogenic magnetites was enhanced associated with

  11. Incision rates of headwater streams: Determination by paleomagnetic dating of clastic cave sediments in valley walls

    SciTech Connect

    Sasowsky, I.D.; White, W.B. . Dept. of Geosciences); Schmidt, V.A. . Dept. of Geology and Planetary Science)

    1992-01-01

    Incision rates of headwater streams which downcut through carbonate rocks can be inferred by correlating surface channels to associated subsurface drainage and the conduit fragments that remain as the channel deepens. Stream-deposited sediments from caves in the valley walls can be sampled for paleomagnetic polarity. Using these data, a local paleomagnetic column is constructed and matched with the global paleomagnetic record which then provides time markers for the sediments. The morphological characteristics of the caves are used to relate paleo-drainage in the karst to previous elevations of the surface channel. A test case was made in a headwater basin in the Western Cumberland Plateau Escarpment, the East Fork of the Obey River in northcentral Tennessee. The basin has a relief of 300m and an area of 523 km[sup 2]. Four extensive caves in the valley walls provided 118 paleomagnetic samples. Samples were step-demagnetized in an alternating field from 10 to 100 mT, and gave well-clustered normal and reversed field directions. NRM intensities were between 8 [times] 10[sup [minus]8] and 1 [times] 10[sup [minus]5] kA/m. Construction of a local paleomagnetic polarity column revealed that two normal and one reversed sedimentary sequences were present in the caves. The age of the uppermost (oldest) cave level was placed at 0.91 Ma, yielding an incision rate for the basin of 0.06 m/ka. This rate is consistent with rates of incision determined for other basins in the eastern US using different methods.

  12. Microbial population, activity, and phylogenetic diversity in the subseafloor core sediment from the Sea of Okhotsk

    NASA Astrophysics Data System (ADS)

    Inagaki, F.; Suzuki, M.; Takai, K.; Nealson, K. H.; Horikoshi, K.

    2002-12-01

    Subseafloor environments has already been recognized as the largest biosphere on the planet Earth, however, the microbial diversity and activity has been still poorly understood, even in their impacts on biogeochemical processes, tectonic settings, and paleoenvironmental events. We demonstrate here the evaluation of microbial community structure and active habitats in deeply buried cold marine sediments collected from the Sea of Okhotsk by a combined use of molecular ecological surveys and culturing assays. The piston core sediment (MD01-2412) was collected by IMAGES (International Marine Global Change Study) Project from the southeastern Okhotsk Sea, June 2001. The total recovered length was about 58m. The lithology of the core sediment was mainly constructed from pelagic clay (PC) and volcanic ash layers (Ash). We collected aseptically the most inside core parts from 16 sections at different depths for microbiological study. The direct count of DAPI-stained cells revealed that the cells in Ash samples were present 1.2 to 2.2 times higher than in PC samples. The quantitative-PCR of 16S rDNA between bacterial and archaeal rDNA suggested that the increased population density in Ash layers was caused by the bacterial components. We studied approximately 650 and 550 sequences from bacterial and archaeal rDNA clone libraries, respectively. The similarity and phylogenetic analyses revealed that the microbial community structures were apparently different between in Ash layers and PC samples. From bacterial rDNA clone libraries, the members within gamma-Proteobacteria such as genera Halomonas, Shewanella, Psychromonas and Methylosinus were predominantly detected in Ash layers whereas the Dehalococcoides group and delta-Proteobacteria were major bacterial components in PC samples. From archaeal libraries, the sequences from Ash and PC samples were affiliated into the clusters represented by the environmental sequences obtained from terrestrial and deep-sea environments

  13. Detrital zircon and apatite (U-Th)/He thermochronology of intercalated baked sediments: a new approach to dating young basalts

    NASA Astrophysics Data System (ADS)

    Cooper, F. J.; van Soest, M. C.; Hodges, K.

    2009-12-01

    Placing accurate age constraints on young volcanic eruptions, particularly in populated areas such as New Mexico, is important for not only tectonic and climate studies, but also for geohazard analysis. A primary lack of zircon and apatite crystals in basaltic rocks leaves K/Ar and 40Ar/39Ar dating as the most favored methods, though extraneous Ar and low K contents can often reduce precision. Alternative techniques suggested in recent years include (U-Th)/He dating of U and Th rich inclusions in olivine phenocrysts and other phenocrysts (Min et al., 2006; Aciego et al., 2007), (U-Th)/He dating of zircon xenocrysts (Blondes et al., 2007), and (U-Th)/He dating of magnetite phenocrysts (Blackburn et al., 2007). Unfortunately, zircon xenocrysts are not very abundant in basalts, and not all basalts contain suitably sized olivine, magnetite, or other phenocrysts. Here, we present a new application of the (U-Th)/He method to dating young volcanic eruptions in an area where the emplacement of basalt flows has reset the (U-Th)/He systematics of zircons and apatites in intercalated baked sediments. The Taos Plateau volcanic field (TPVF) in New Mexico formed in Middle to Late Miocene time in association with extensional processes in the Rio Grande Rift. The voluminous (>200 km3) basalt flows of the TPVF have been carefully dated with 40Ar/39Ar (Appelt, 1998) and therefore provide a sound basis for comparison with the (U-Th)/He results. Two fluvial sand and gravel samples were collected from directly beneath the Upper member of the Servilleta Basalt (40Ar/39Ar age: 3.57 ± 0.19 Ma [2 S.E., n = 3]; Appelt, 1998) in the Rio Grande River Gorge just west of Taos. These two samples yielded a distinct population of single-crystal (U-Th)/He zircon and apatite ages of 3.54 ± 0.11 Ma [2 S.E., n = 4] and 3.44 ± 0.25 Ma [2 S.E., n = 2] respectively. Sixteen additional grains (6 zircons and 10 apatites) gave significantly older dates (~ 9 to 27 Ma). We interpret the older dates as

  14. Diagenetic effects on magnetic minerals in a Holocene lacustrine sediment core from Huguangyan maar lake, southeast China

    NASA Astrophysics Data System (ADS)

    Wu, Xudong; Wang, Yong; Bian, Liu; Shen, Ji

    2016-06-01

    Post-depositional reductive diagenesis usually results in partial or entire cleansing of the pristine palaeomagnetic signal, therefore, its intensity is important to be assessed for sediments that are in the purpose of retrieving palaeomagnetic information. Grain size, rock magnetic and geochemical studies on the entire core, along with scanning electron microscope (SEM) observations and X-ray diffraction (XRD) analyses for representative samples were carried out on a Holocene sediment core retrieved from the deep water part of Huguangyan maar lake (HGY), southeast China. The pristine magnetic mineral assemblage of the studied core is domianted by superparamagnetic (SP) and stable single domain (SSD) titanomagnetite, and high coercivity minerals are not detectable. Based on down-core variations of the average grain size (MZ), total organic carbon (TOC), detrital elements (Al, Ti, Fe and Mn), and the concentration and mineralogy of magnetic minerals, the studied core could be divided into three subsections. The uppermost subsection is the least affected by diagenesis, with detrital titanomagnetite as the dominant magnetic mineral. This is owing to low TOC contents, but high detrital input generated by weak Asian summer monsoon intensity during the late Holocene. The intermediate subsection shows down-core progressively enhanced dissolution of detrital titanomagnetite, and concomitant formation of authigenic pyrite and siderite, which indicates down-core progressively enhanced diagenesis generated by down-core progressive increasing TOC content, but decreasing detrital input as the result of down-core progressively strengthened Asian summer monsoon intensity. The pristine magnetic mineral assemblage has been profoundly modified in the lowermost subsection. At certain positions of the lowermost subsection, detrital titanomagnetite has been even completely dissolved via diagenesis, giving place to authigenic pyrite and siderite. High TOC content, but low detrital input

  15. Paleoclimatic record of the late Quaternary from a gravity core sediment of Lake Hovsgol in northern Mongolia

    NASA Astrophysics Data System (ADS)

    Cheong, D.; Kim, B.

    2007-12-01

    Gravity core sediment (HS 7) from Lake Hovsgol(Mongolia) is divided into three sedimentary units on the basis of sediments texture, water contents, occurrence of fossils and sediment color. Unit 1(27¢¦128§¯) is generally massive and is crudely stratified. Ostracods are well preserved over the all interval of Unit1, but diatoms are not well preserved. At Unit2(9¢¦27§¯), mud content is slightly low and lamination is well developed. It is dark greenish gray in the upper part, and dark greenish gray is alternating with light brownish gray in the lower part. Diatom contents increase towards the top and ostracods fragments disappear at the top of Unit 2. Unit3(0¢¦9§¯) is laminated mud in olive gray color. Diatom contents are high but ostracods are not observed in this unit. According to 14C age dating results, we assumed that Unit1 is Pleistocene sediment, Unit2 is sediment of a transitional stage and Unit 3 is Holocene sediment. Chemical composition of trace elements from ostracods show variations through Unit1, especially showing a distinct change at 95¢¦100§¯ interval. It matches to the distribution of ostracod at this interval. Contents of ostracod decrease at the interval and contents of Cytherissa lacustris decrease, but Limnocythere inopinata increase. It was interpreted that warm air was supplied to Lake Hovsgol after LGM(Last Glacial Maximum), causing ice melting. Consequently the bottom environment of Lake Hovsgol experienced some changes as the lake level increased little bit. At the top of Unit 1 appear a lots of pyrite which are arranged in line, and diatoms occure but ostracods are not observed toward the top of Unit 2, and lamination is developed in Unit 2. It means the bottom environment of Lake Hovsgol changed to anoxic condition. At that time, plenty of water was supplied into the lake, resulting in water stratification and cutting off oxygen supply to the bottom of Lake Hovsgol. It made the lake level rise higher, so that the bottom

  16. Estimation of sources and inflow of dioxins and polycyclic aromatic hydrocarbons from the sediment core of Lake Suwa, Japan.

    PubMed

    Ikenaka, Yoshinori; Eun, Heesoo; Watanabe, Eiki; Kumon, Fujio; Miyabara, Yuichi

    2005-12-01

    To elucidate the historical changes in polychlorinated dibenzo-p-dioxin (PCDD), polychlorinated dibenzofuran (PCDF), coplanar polychlorinated biphenyl (co-PCB), and polycyclic aromatic hydrocarbon (PAH) inflows in Lake Suwa, their concentrations in the sediment core were analyzed in 5 cm interval. The maximum concentrations (depth cm) of PCDDs/DFs, co-PCBs, and PAHs were 25.2 ng/g dry (30-35 cm), 19.0 ng/g dry (30-35 cm), and 738, 795 ng/g dry (50-55 cm, 30-35 cm), respectively. Age and sedimentation rate of the sediment were estimated from the vertical changes in apparent density. Deposition rate of dioxins and PAHs were calculated from the concentration and sedimentation rate of the sediment. The results indicate that large amounts of dioxins and PAHs flowed into the lake in flood stage compared to normal stage. PMID:15964115

  17. Concentration of Antifouling Biocides and Metals in Sediment Core Samples in the Northern Part of Hiroshima Bay

    PubMed Central

    Tsunemasa, Noritaka; Yamazaki, Hideo

    2014-01-01

    Accumulation of Ot alternative antifoulants in sediment is the focus of this research. Much research had been done on surface sediment, but in this report, the accumulation in the sediment core was studied. The Ot alternative antifoulants, Diuron, Sea-Nine211, and Irgarol 1051, and the latter’s degradation product, M1, were investigated in five samples from the northern part of Hiroshima Bay. Ot compounds (tributyltin (TBT) and triphenyltin (TPT)) were also investigated for comparison. In addition, metal (Pb, Cu, Zn, Fe and Mn) levels and chronology were measured to better understand what happens after accumulation on the sea floor. It was discovered that Ot alternative antifoulant accumulation characteristics in sediment were like Ot compounds, with the concentration in the sediment core being much higher than surface sediment. The concentration in sediment seems to have been affected by the regulation of Ot compounds in 1990, due to the concentration of Ot alternative antifoulants and Ot compounds at the survey point in front of the dock, showing an increase from almost the same layer after the regulation. PMID:24901529

  18. Paleomagnetic inclination errors in sediments cored from a Gulf of Mexico salt dome - An indicator of ancient sea level

    SciTech Connect

    Sager, W.W.; Singleton, S.W. )

    1989-08-01

    A paleomagnetic study of piston-cored sediments was done in conjunction with a high-resolution seismic reflection study of a salt dome on the upper continental slope in the northern Gulf of Mexico. Seismic data showed that late Pleistocene sediment layers are exposed around the bank and tilted up to 8{degree} by the diapiric uplift. Cores were taken on the flanks of the bank to test the use of paleomagnetism in measuring the tectonic tilt of the sediments. After structural corrections, results from six cores agreed with the geocentric axial dipole inclination for the site, but four other cores displayed significantly shallowed inclinations. Moreover, several cores showed linear trends of inclination shallowing, increasing downcore. The anomalous results are from the summit of the bank and suggest a relation to subaerial exposure during a sea-level lowstand. The authors think that the shallow inclinations were caused by compaction, but that the linear trends resulted from rehydration of the sediments after exposure by erosion.

  19. Historical tide gauge data and sediment cores put Hurricane Sandy in context

    NASA Astrophysics Data System (ADS)

    Balcerak, Ernie

    2012-11-01

    Historical tide gauge data and sediment cores put Hurricane Sandy in context Several studies that put the recent devastating Hurricane Sandy in context were reported on 5 November at the annual meeting of the Geological Society of America in Charlotte, N. C. Stefan Talke of Portland State University explained that old tide gauge data that he and colleagues have been digitizing show that Sandy was the largest hurricane to hit New York in more than 100 years. Compared to the 1893 storm that was the largest in their records, "Hurricane Sandy was much larger, probably about twice as large, in terms of storm surge," he said. Their study is part of an effort to determine whether sea level rise is accelerating.

  20. Hg Isotope Ratios of a Sediment Core from Plastic Lake, Ontario: Implications for Hg Cycle in Aquatic Environment

    NASA Astrophysics Data System (ADS)

    Xie, Q.; Dillon, P.; Evans, D.; Lu, S.

    2004-12-01

    Hg isotope ratios in a sediment core obtained in Plastic Lake, Ontario, Canada, have been measured by coupling a gold trap with an MC-ICP-MS. The core is about 30 cm in depth and corresponds to a time period of about 250 years, based on 210Pb dating. The samples were combusted at high temperature and the Hg collected onto a gold trap. The gold trap was subsequently heated to release Hg directly into the MC-ICP-MS. An in-house sample introduction system was employed to extend Hg signal duration in order to obtain high precision in isotope ratio measurement. The instrumental mass bias was corrected using Tl introduced simultaneously via an Aridus membrane desolvation nebulizer. Based on long term measurement of a NIST-2225 elemental Hg standard (over 120 measurements since Oct. 2002), the external reproducibility ranges from 45 ppm for 201Hg/202Hg to 100 ppm for 199Hg/202Hg (2 sigma relative standard error). Hg in the sediments shows an increase in light isotope enrichment at about 10 cm depth. The total Hg also displays an increase at the same depth. The depth corresponds to approximately the 1920s, a time period when there was a major increase in coal-burning power generation. Limited Hg isotope data for other terrestrial samples appears to indicate that Hg bound to organic carbon is enriched in light isotopes relative to elemental Hg. For example, the DOLT-3, a dogfish liver standard reference material with half of its Hg as MeHg, has the lightest Hg isotope composition among measured terrestrial samples. It is not clear at this stage whether the increase in total Hg and light Hg isotope enrichment in recent years represent a change in methylation rate of the lake, or an increase in atmospheric deposition of Hg combined with a change in source. Discussions based on available Hg isotope data of terrestrial samples together with other chemical data for the lake will be presented.

  1. A revised burial dose estimation procedure for optical dating of youngand modern-age sediments

    USGS Publications Warehouse

    Arnold, L.J.; Roberts, R.G.; Galbraith, R.F.; DeLong, S.B.

    2009-01-01

    The presence of genuinely zero-age or near-zero-age grains in modern-age and very young samples poses a problem for many existing burial dose estimation procedures used in optical (optically stimulated luminescence, OSL) dating. This difficulty currently necessitates consideration of relatively simplistic and statistically inferior age models. In this study, we investigate the potential for using modified versions of the statistical age models of Galbraith et??al. [Galbraith, R.F., Roberts, R.G., Laslett, G.M., Yoshida, H., Olley, J.M., 1999. Optical dating of single and multiple grains of quartz from Jinmium rock shelter, northern Australia: Part I, experimental design and statistical models. Archaeometry 41, 339-364.] to provide reliable equivalent dose (De) estimates for young and modern-age samples that display negative, zero or near-zero De estimates. For this purpose, we have revised the original versions of the central and minimum age models, which are based on log-transformed De values, so that they can be applied to un-logged De estimates and their associated absolute standard errors. The suitability of these 'un-logged' age models is tested using a series of known-age fluvial samples deposited within two arroyo systems from the American Southwest. The un-logged age models provide accurate burial doses and final OSL ages for roughly three-quarters of the total number of samples considered in this study. Sensitivity tests reveal that the un-logged versions of the central and minimum age models are capable of producing accurate burial dose estimates for modern-age and very young (<350??yr) fluvial samples that contain (i) more than 20% of well-bleached grains in their De distributions, or (ii) smaller sub-populations of well-bleached grains for which the De values are known with high precision. Our results indicate that the original (log-transformed) versions of the central and minimum age models are still preferable for most routine dating applications

  2. On the principles of the U-trend method for dating quaternary sediments, I: Model, experimental procedures and data

    NASA Astrophysics Data System (ADS)

    Latham, A. G.

    The U-trend method for dating a wide range of Quaternary sediments was first presented by John Rosholt in a series of U.S. Geological Survey Open File Reports. The thinking was that upon fluviation uranium, filtering down through the unit, left behind a trail of daughter products in a systematic fashion — a trend. The exponential decrease of this U flux was defined by a flux factor the significance of which was not known exactly. Equivalently, the flux of U could be characterized by a 'half-period', which appeared to act analogously to a radioactive decay half-life. By using leaching techniques, the loosely bound isotopes would define a trend when plotted on a 'U-trend isochron' diagram. This trend was characterized in the plot by a gradient and intercept which could be referred to calibration diagrams in order to recover the half-period and the age of the unit. Such age estimates have now appeared in the more fully-refereed literature, though without the fuller descriptions found in the USGS publications. The assumptions of the method are examined here, together with the details of the method from the earlier publications. Various problems with the method stand out, among which are: (i) it is not clear how α-recoil effects are included in the empirical equations; (ii) the use of independently-dated sediments as calibration units has not been fully justified; (iii) the leaching techniques appear to be too strong to select only the loosely bound isotopes and no others; and (iv) several of the key data-sets do not show a sufficiently strong variation of isotope ratios with depth to warrant being described as a trend. Despite these and other difficulties and because of its potential importance to Quaternary chronology, it is felt that the continuing study of U-trend type methods is worth the effort.

  3. Natural uranium and thorium isotopes in sediment cores off Malaysian ports

    NASA Astrophysics Data System (ADS)

    Yusoff, Abdul Hafidz; Sabuti, Asnor Azrin; Mohamed, Che Abd Rahim

    2015-06-01

    Sediment cores collected from three Malaysian marine ports, namely, Kota Kinabalu, Labuan and Klang were analyzed to determine the radioactivities of 234U, 238U, 230Th, 232Th and total organic carbon (TOC) content. The objectives of this study were to determine the factors that control the activity of uranium isotopes and identify the possible origin of uranium and thorium in these areas. The activities of 234U and 238U show high positive correlation with TOC at the middle of sediment core from Kota Kinabalu port. This result suggests that activity of uranium at Kota Kinabalu port was influenced by organic carbon. The 234U/238U value at the upper layer of Kota Kinabalu port was ≥1.14 while the ratio value at Labuan and Klang port was ≤ 1.14. These results suggest a reduction process occurred at Kota Kinabalu port where mobile U(VI) was converted to immobile U(IV) by organic carbon. Therefore, it can be concluded that the major input of uranium at Kota Kinabalu port is by sorptive uptake of authigenic uranium from the water column whereas the major inputs of uranium to Labuan and Klang port are of detrital origin. The ratio of 230Th/232Th was used to estimate the origin of thorium. Low ratio value (lt; 1.5) at Labuan and Klang ports support the suggestion that thorium from both areas were come from detrital input while the high ratio (> 1.5) of 230Th/232Th at Kota Kinabalu port suggest the anthropogenic input of 230Th to this area. The source of 230Th is probably from phosphate fertilizers used in the oil-palm cultivation in Kota Kinabalu that is adjacent to the Kota Kinabalu port.

  4. Dating sediment deposits on Montalvanian carvings using EPR and TL methods

    NASA Astrophysics Data System (ADS)

    Sastry, M. D.; Sullasi, Henry S. L.; Camargo, Fabiola; Watanabe, Shigueo; Prous, André P. P.; Silva, Martha M. C.

    2004-01-01

    About 30 years ago a rock shelter with engravings by early settlers was found at Montalvânia, northern end of state of Minas Gerais, Brazil. Lower part of engravings was covered with thin deposit of calcite mixed with quartz grains, due to occasional flood. This mixture of two minerals was dated by thermoluminescence and electron paramagnetic resonance using in both cases, additive method. The accumulated dose DAC, that is, natural radioactivity and cosmic rays radiation dose that induces TL and EPR signal intensity has been found to be around 50 Gy both by TL and EPR methods. The annual radiation dose rate was estimated to be about 1.027 mGy/a from knowledge of uranium, thorium and potassium content determined by inductively coupled plasma-mass spectrometer system. The age of this calcite plus quartz deposits was estimated to be about 50 ka.

  5. Physical and chemical characteristics of the Subglacial Lake Whillans sediment cores, Whillans Ice Stream, West Antarctica

    NASA Astrophysics Data System (ADS)

    Hodson, T. O.; Powell, R. D.

    2013-12-01

    Sediment recovered from Subglacial Lake Whillans (SLW) is well-homogenized, structureless diamict; typical subglacial till. Based on theoretical estimates, the basal ice above SLW should be below the pressure melting point preventing melt-out of debris from basal ice. Therefore, the lake floor diamict likely formed through deformation while the ice stream was grounded at the drill site. Using satellite altimetry, Fricker, et al. (2007) inferred that SLW experiences short (~7 month) discharge events, lowering the ice surface and lake water level by between 1 and 4 m. The lake 'lowstands' are separated by longer periods of gradual recharge, but over the period of a lowstand the ice stream is suspected to touch down and couple with the lake floor, potentially shearing new till into the lake. The lack of sorted sediment or erosional lags indicates water flow during discharge/recharge events has had a low current velocity with quiescent conditions in the lake. The most notable variability in the cores is a uniformly weak, critical porosity horizon extending to ~50 cm depth above more consolidated till. We interpret the weak upper horizon as the product of shear deformation and decreasing effective pressure experienced during the final stages of grounding prior to a lake recharge event (see generally, the undrained plastic bed model of Tulaczyk et al. (2000)). The presence of this weak layer illustrates the importance of hydrology in modulating till rheology and is an example of how subglacial sediments can preserve archives of hydrologic conditions at the glacial bed. Fricker, H.A., T. Scambos, R. Bindschadler and L. Padman. 2007. An active subglacial water system in West Antarctica mapped from space. Science, 315(5818), 1544-1548. Tulaczyk S, Kamb WB, Engelhardt HF. 2000. Basal mechanics of Ice Stream B, West Antarctica. 2. Undrained plastic bed model. J. Geophys. Res. 105:483-94.

  6. Reverse palaeomagnetic polarity recorded in exposed lacustrine sediments dated 34,000-46,000 years B.P. at Searles Valley, California

    NASA Astrophysics Data System (ADS)

    Liddicoat, Joseph; Coe, Robert; Knott, Jeffrey

    2010-05-01

    The history of pluvial Searles Lake in the Great Basin of the United States is well known from extensive field work and numerous cores recovered as part of industrial exploration of Searles Valley, in which the lake formed during the Quaternary (Smith et al., 1979; Liddicoat et al., 1980; Smith, 2009). Sediments deposited in Searles Lake (now dry) are exposed throughout Searles Valley, and siltstone and mudstone bracket about 14,000 to 46,000 calendar years B.P (23 AMS 14-Carbon dates on gastropods and mollusks from fine- to medium-grain sand units that are interbedded with the siltstone and mudstone). The siltstone and mudstone of that age record reverse palaeomagnetic polarity following thermal demagnetization to 600 C at two localities three km apart. For three horizons of paired samples at each locality, the combined mean palaeomagnetic directions are I = -37.5, D = 180.2, alpha-95 = 19.5, n =12, and the mean Virtual Geomagnetic Pole (VGP) is 73.6 S, 231.8 E, Alpha-95 = 20.6, n = 12. The reverse polarity is not attributed to the Mono Lake Excursion (Denham and Cox, 1971) that never has a southerly declination or VGP in the Southern Hemisphere (Liddicoat and Coe, 1979; Liddicoat, 1992). Other samples from the two Searles Valley localities do not reach a definite reverse direction but contain a component of magnetization that approaches reverse polarity above 400 C, and higher in the sections full normal polarity is recorded. The remanence in the Searles Lake sediment that records the reverse palaeomagnetic directions is very low, and when examined in polished thin section, the siltstone contains detrital opaque grains that have a diameter of about 0.2 microns.

  7. Incision of the Danube River (Hungary), inferred by cosmogenic in situ 10Be and luminescence dating of terrace sediments

    NASA Astrophysics Data System (ADS)

    Ruszkiczay-Rüdiger, Zsófia; Novothny, Ágnes; Braucher, Régis; Csillag, Gábor; Fodor, László; Molnár, Gábor; Thamó-Bozsó, Edit

    2014-05-01

    Major part of the former chronological studies showed that Danube terraces, and connected uplift of the surrounding hills are significantly younger than it was suggested before. On the other hand, some studies provided older than expected ages. Accordingly, a novel terrace chronology is necessary, which we try to approach by using two different dating methods on the alluvial terraces: luminescence dating, which provides the burial ages and cosmogenic in situ 10Be dating, which yields the exposure ages of the sediments. Cosmogenic 10Be and luminescence samples were collected from several terrace horizons. Cosmogenic in situ 10Be sampling occurred along depth profiles, because this method allows determining both the exposure time and the denudation rate at each locality by using all particles involved in the cosmogenic nuclide production. Post-Infrared Infrared Stimulated Luminescence (post-IR IRSL) measurements were carried out on K-feldspar samples, comparing the post-IR IRSL 290 and post-IR IRSL 225 signals. Besides, quartz from younger samples was also measured using Optically Stimulated Luminescence (OSL). The lower horizons (tIIa,b) were datable by both luminescence and cosmogenic exposure age dating methods. However, the upper horizons (tIV, tV) were frequently above the datable time range for one or both methods. In these cases, instead of the 'exact' ages with errors, only minimum ages could be assessed. Most of the luminescence data show older ages than 10Be exposure ages for the terrace surfaces. This may be due to the fact that the dated processes are different. Luminescence ages reveal the time of deposition of the sediment, while 10Be ages show the time since the actual terrace surface has been exposed to cosmic irradiation. The effect of considerable surface erosion also has to be taken into account, as well as the possibility of incomplete bleaching of the luminescence signal. The possible effect of post-depositional sediment mixing could be excluded

  8. Major and trace elements in 35 lake and reservoir sediment cores from across the United States, 1994-2001

    USGS Publications Warehouse

    Van Metre, Peter C.; Mahler, Barbara J.; Wilson, Jennifer T.; Callender, Edward

    2006-01-01

    This report presents data on major and trace element concentrations in sediment cores collected from 35 lakes and reservoirs during 1994-2001. The lakes and reservoirs are located in or near 18 major urban areas across the United States and provide a geographically diverse coverage of urban land use for the country as well as some reference settings. Vertical intervals of the cores were analyzed for eight major elements and eight trace elements.

  9. Grain Size Analyses of Neogene-Quaternary Sediments from the Arctic Coring Expedition

    NASA Astrophysics Data System (ADS)

    Moran, K.; Lado-Insua, T.; O'Regan, M.

    2013-12-01

    The Arctic Coring Expedition (ACEX) recovered the first Cenozoic sediment sequence from the central Arctic Ocean. Results from this expedition indicate that perennial sea ice may have formed in the Arctic at or before the early mid-Miocene. Sea ice formation is an important process in the global climate system, affecting directly the Earth's albedo and indirectly the Meridional Overturning Circulation. The deep Arctic Ocean receives sediment primarily from ice-rafted debris and turbidity currents. Suspension freezing on the shallow continental shelves of the Arctic has generally been considered the major process trapping sediment within sea ice. Sea ice motion is largely driven by wind. The anticyclonic Beaufort Gyre transports sea ice over the Amerasia Basin, while the Transpolar Drift transports it across the Eurasian Basin. The Transpolar Drift is divided into a Siberian and Polar branch, both branches cross the position of the ACEX drilling sites on the Lomonosov Ridge. Grain size analyses of ACEX sediments were obtained with a Malvern Mastersizer 2000 laser diffraction particle sizing system. Preliminary analyses indicate pulses with a higher percentage of sand between 3.64 Ma ago until the end of the Gelasian (1.8 Ma). The percent sand remained relatively low during the Cenozoic with the exception of two major increases of sand occurring ~6.2 and 9.2 Ma ago and a smaller peak ~8.2 Ma ago. These intervals also show less sorting and lower values for skewness and kurtosis. Increases in the percentage of sand and less sorting at this latitude relate to ice rafted debris, indicating an increase in sea-ice melting during these periods. A Principal Components Analysis and a Maximum Correlation Factor Analysis agree on a correlation between different grain sizes that would divide the grain size in two major distributions (<19 μm and 19 μm to 2 mm) based on the sedimentation and transport mechanism. These two classes do not agree with the major divisions of sand (63

  10. Sediment provenance, reworking and transport processes in the Indus River by U-Pb dating of detrital zircon grains

    NASA Astrophysics Data System (ADS)

    Alizai, Anwar; Carter, Andrew; Clift, Peter D.; VanLaningham, Sam; Williams, Jeremy C.; Kumar, Ravindra

    2011-03-01

    We present new major and trace element data, together with U-Pb ages for zircon sand grains from the major tributaries of the Indus River, as well as the adjacent Ghaggar and Yamuna Rivers and from bedrocks within the Sutlej Valley, in order to constrain the origin of the sediment reaching the Arabian Sea. Zircon grains from the upper Indus are generally younger than 200 Ma and contrast with those from the eastern tributaries eroded from Himalayan sources. Grains younger than 15 Ma, which typify the Nanga Parbat Massif, comprise no more than 1-2% of the total, even in the upper Indus, showing that this terrain is not a major sediment producer, in contrast with the Namche Barwe Massif in the eastern Himalayan syntaxis. The Sutlej and Yamuna Rivers in particular are very rich in Lesser Himalayan-derived 1500-2300 Ma zircons, while the Chenab is dominated by 750-1250 Ma zircons, mostly eroded from the Greater Himalaya. The upper Indus, Chenab and Ravi yield zircon populations broadly consistent with the outcrop areas, but the Jhelum and the Sutlej contain many more 1500-2300 Ma zircons than would be predicted from the area of Lesser Himalayan rock within their drainages. A significant population of grains younger than 200 Ma in the sands of the Thar Desert indicates preferential eolian, monsoon-related transport from the Indus lower reaches, rather than reworking from the local rivers. Modelling of observed zircon ages close to the delta contrasts with modern water discharge. The delta is rich in zircons dating 1500-2300 Ma, while discharge from modern rivers carrying such grains is low. The modest size of the Sutlej, the richest source of these materials in the modern system, raises the possibility that the compositionally similar Yamuna used to flow westwards in the recent past. Our data indicate a non-steady state river with zircon transport times of 5-10 k.y. inferred from earlier zircon dating of delta sands. The modern delta zircons image an earlier, likely

  11. The Effectiveness of L*a*b* Color Analysis in Determining the Elemental and Mineralogical Composition of Lake Sediment Cores

    NASA Astrophysics Data System (ADS)

    Dawson, S.; Lascu, I.; Myrbo, A.; Wittkop, C.

    2006-12-01

    High-resolution L*a*b color and x-ray fluorescence (XRF) elemental profiles were compared for a set of Midwestern U.S. lake sediment cores held in the National Lacustrine Core Repository. The cores all display centi- to decimeter scale light-dark banding (nicknamed "raccoon-tail banding"), determined by variations in carbonate versus organic matter content. Carbonate minerals are evidently depleted in the organic-rich strata due to carbonate dissolution in the hypolimnion and sediment column, which is the result of both external (i.e., climatic) and internal factors. XRF was performed at a resolution comparable to the L*a*b* image analysis of the core sections, which allowed the investigation of the relationship between sediment color and composition within a core. The "a" component in this image analysis is correlated with elemental iron abundance, and the "b" and "L" components are related to calcium (calcite) and organic carbon content. Overall, this study has determined that L*a*b* color analysis of high-resolution digital images is an easy and fast way to obtain preliminary information about the composition of core material. When used in conjunction with scanning XRF data, color analysis can replace lower-resolution geochemical analyses to produce sub-annual scale records of lake dynamics and responses to climate change.

  12. Recent history of sediment dynamics in Lake Toro and applicability of 210Pb dating in a highly disturbed catchment in northern Japan

    NASA Astrophysics Data System (ADS)

    Ahn, Young Sang; Nakamura, Futoshi; Chun, Kun Woo

    2010-01-01

    Sediment dynamics for the last 300 years in Lake Toro and the applicability of 210Pb dating (CIC and CRS models) are evaluated. The lake sedimentation and sediment yield were determined by 137Cs (in 1963) and two tephra layers (Ko-c2 in 1694 and Ta-a in 1739). The average sediment yields for initial development periods of catchments were 13.0-14.1 t km - 2 yr - 1 until 1963 and increased to 30.5 t km - 2 yr - 1 after 1963 because of the conversion of floodplain and upland forests to cultivated lands. In particular, the western zone of the lake near the conjunction with the Kushiro River had a high sedimentation rate, which is attributable to sediment inflow back from the Kushiro River during floods. The CIC model was not applicable because of fluctuations in the 210Pb profiles since 1963. The CRS model agrees with the 137Cs dating in all sites except for one site close to the Kushiro River inflow. 210Pb dating may contain considerable errors where the 210Pb concentration profile and flux are perturbed by floodwater from the Kushiro River, which contains low levels of 210Pb.

  13. 3D Porosity Estimation of the Nankai Trough Sediments from Core-log-seismic Integration

    NASA Astrophysics Data System (ADS)

    Park, J. O.

    2015-12-01

    The Nankai Trough off southwest Japan is one of the best subduction-zone to study megathrust earthquake fault. Historic, great megathrust earthquakes with a recurrence interval of 100-200 yr have generated strong motion and large tsunamis along the Nankai Trough subduction zone. At the Nankai Trough margin, the Philippine Sea Plate (PSP) is being subducted beneath the Eurasian Plate to the northwest at a convergence rate ~4 cm/yr. The Shikoku Basin, the northern part of the PSP, is estimated to have opened between 25 and 15 Ma by backarc spreading of the Izu-Bonin arc. The >100-km-wide Nankai accretionary wedge, which has developed landward of the trench since the Miocene, mainly consists of offscraped and underplated materials from the trough-fill turbidites and the Shikoku Basin hemipelagic sediments. Particularly, physical properties of the incoming hemipelagic sediments may be critical for seismogenic behavior of the megathrust fault. We have carried out core-log-seismic integration (CLSI) to estimate 3D acoustic impedance and porosity for the incoming sediments in the Nankai Trough. For the CLSI, we used 3D seismic reflection data, P-wave velocity and density data obtained during IODP (Integrated Ocean Drilling Program) Expeditions 322 and 333. We computed acoustic impedance depth profiles for the IODP drilling sites from P-wave velocity and density data. We constructed seismic convolution models with the acoustic impedance profiles and a source wavelet which is extracted from the seismic data, adjusting the seismic models to observed seismic traces with inversion method. As a result, we obtained 3D acoustic impedance volume and then converted it to 3D porosity volume. In general, the 3D porosities show decrease with depth. We found a porosity anomaly zone with alteration of high and low porosities seaward of the trough axis. In this talk, we will show detailed 3D porosity of the incoming sediments, and present implications of the porosity anomaly zone for the

  14. Assessment of PCDD/F source contributions in Baltic Sea sediment core records.

    PubMed

    Assefa, Anteneh T; Tysklind, Mats; Sobek, Anna; Sundqvist, Kristina L; Geladi, Paul; Wiberg, Karin

    2014-08-19

    Spatial and temporal trends of sources of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in the Baltic Sea were evaluated by positive matrix factorization (PMF) and principal component analysis (PCA). Sediment cores were sampled at eight coastal, one coastal reference, and six offshore sites covering the northern to the southern Baltic Sea. The cores, which covered the period 1919-2010, were sliced into 2-3 cm disks among which 8-11 disks per core (in total 141 disks) were analyzed for all tetra- through octa-CDD/Fs. Identification and apportionment of PCDD/F sources was carried out using PMF. Five stable model PCDD/F congener patterns were identified, which could be associated with six historically important source types: (i) atmospheric background deposition (ABD), (ii) use and production of penta-chlorophenol (PCP), (iii) use and production of tetra-chlorophenol (TeCP), (iv) high temperature processes (Thermal), (v) hexa-CDD-related sources (HxCDD), and (vi) chlorine-related sources (Chl), all of which were still represented in the surface layers. Overall, the last four decades of the period 1920-2010 have had a substantial influence on the Baltic Sea PCDD/F pollution, with 88 ± 7% of the total amount accumulated during this time. The 1990s was the peak decade for all source types except TeCP, which peaked in the 1980s in the northern Baltic Sea and has still not peaked in the southern part. The combined impact of atmospheric-related emissions (ABD and Thermal) was dominant in the open sea system throughout the study period (1919-2010) and showed a decreasing south to north trend (always >80% in the south and >50% in the north). Accordingly, to further reduce levels of PCDD/Fs in the open Baltic Sea ecosystem, future actions should focus on reducing atmospheric emissions. PMID:25103626

  15. Magnetostratigraphic Dating of Paleogene Sediments in the Seymour Island (Antarctic Peninsula): A Preliminary Chronostratigraphy

    NASA Astrophysics Data System (ADS)

    Beamud, E.; Montes, M. J.; Santillana, S.; Nozal, F.; Marenssi, S.

    2015-12-01

    Seymour Island is located at 64 º S, close to the northeastern tip of the Antarctic Peninsula. This glacier-free island contains the southernmost exposures of the K/Pg boundary and it has the most complete record of the Paleogene in Antarctica. The base of the Paleogene is represented by the Early Paleocene shallow marine shelf deposits of the Marambio Group; which are unconformably overlain by the Late Paleocene to Late Eocene Seymour Island Group. The Marambio Group is divided into the quartz-rich silty sandstones and mudstones of the López de Bertodano Fm and the mudstones to quartz-rich sandstones of the Sobral Fm. The overlaying Seymour Island Group records the erosion and filling of incised valleys. This group is made up by the Cross Valley-Wiman, La Meseta and the uppermost new Submeseta Formations. Main regressive periods are evidenced by the erosional unconformities and their related time gaps at the base of these three Formations. The La Meseta and Submeseta Formations are composed by poorly consolidated marine sandstones and siltstones deposited in a shallow coastal (possibly estuarine) environment. Several biostratigraphic and isotopic studies have been conducted in the Seymour Island due to its extremely rich fossil record, and the age of the López de Bertodano Fm has been recently refined by magnetostratigraphy. However, the overlying Paleogene formations lack a reliable absolute continuous dating. To solve this problem, a composite magnetostratigraphic section spanning more than 1300 m from the K/Pg boundary up to the top of the Submeseta Fm was conducted, with an average sampling resolution of 3 m per site. Although many samples yielded weak results, a local magnetostratigraphy was obtained which has been correlated to the GPTS. The new derived ages range from Danian (~ 66 Ma) up to Priabonian (~ 34 Ma). These results have been integrated with previous litho-, bio- and isotopic data to build a new Paleogene chronostratigraphy for the Seymour

  16. 210Pb-derived chronology in sediment cores evidencing the anthropogenic occupation history at Corumbataí River basin, Brazil

    NASA Astrophysics Data System (ADS)

    Bonotto, D. M.; de Lima, J. L. N.

    2006-07-01

    Activity profiles of excess 210Pb combined with chemical data determined in two sediment cores from Corumbataí River basin, São Paulo State, Brazil, provided new insights into the reconstruction of historical inputs of anthropogenic constituents, contributing to improving management strategies of the hydrological resources in the basin since most of the municipalities extensively utilize the waters of Corumbataí River and tributaries for drinking purposes, among other uses. Excellent significant relationships between loss on ignition (LOI) and organic matter were found for sediments of both analyzed profiles. Silica was found to be inversely related to organic matter at both analyzed profiles: its decrease accompanied an increase in the specific surface of the sediments. This relationship was confirmed by a great number of inverse significant correlations among silica and oxides Na2O, K2O, CaO, MgO, Al2O3, P2O5, Fe2O3, MnO, and TiO2. It was possible to identify the role of organic matter on adsorption of several oxides/elements in the core sediments profiles. Apparent sediment mass accumulation rates corresponding to 224 and 802 mg cm-2 year-1 were obtained, and are compatible with field evidence, indicating a higher value associated with sand mining activities interfering with the natural/normal sedimentation process, due to modifications of the channel drainage.

  17. Late Pleistocene and Holocene paleoclimate and alpine glacier fluctuations recorded by high-resolution grain-size data from an alpine lake sediment core, Wind River Range, Wyoming, USA

    NASA Astrophysics Data System (ADS)

    Thompson Davis, P.; Machalett, Björn; Gosse, John

    2013-04-01

    Varved lake sediments, which provide ideal high-resolution climate proxies, are not commonly available in many geographic areas over long time scales. This paper utilizes high-resolution grain-size analyses (n = 1040) from a 520-cm long sediment core from Lower Titcomb Lake (LTL), which lies just outside the type Titcomb Basin (TTB) moraines in the Wind River Range, Wyoming. The TTB moraines lie between Lower Titcomb Lake and Upper Titcomb Lake (UTL), about 3 km beyond, and 200 m lower than the modern glacier margin and Gannett Peak (Little Ice Age) moraines in the basin. Based on cosmogenic exposure dating, the TTB moraines are believed to be Younger Dryas (YD) age (Gosse et al., 1995) and lie in a geomorphic position similar to several other outer cirque moraines throughout the western American Cordillera. Until recently, many of these outer cirque moraines were believed to be Neoglacial age. The sediment core discussed here is one of five obtained from the two Titcomb Lakes, but is by the far the longest with the oldest sediment depositional record. Two AMS radiocarbon ages from the 445- and 455-cm core depths (about 2% loss on ignition, LOI) suggest that the lake basin may have been ice-free as early as 16.1 or even 16.8 cal 14C kyr, consistent with 10Be and 26Al exposure ages from boulders and bedrock surfaces outside the TTB moraines. The 257-cm depth in the core marks an abrupt transition from inorganic, sticky gray silt below (<1% LOI) to more organic, less sticky, light brown silt above (4-10% LOI). Eight AMS radiocarbon ages on bulk sediment and macrofossils date the transition to about 11.6 cal 14C kyr. Thus, sampling resolution above the transition is about 22.57 yr and below the transition is about 12.56 yr, consistent with a decreased sediment accumulation rate in LTL when Younger Dryas ice pulled back from the TTB moraines opening up UTL as a sediment depositional basin. The presented high-resolution grain size record reveals amplitudes and other

  18. Modern and historical fluxes of halogenated organic contaminants to a lake in the Canadian arctic, as determined from annually laminated sediment cores.

    PubMed

    Stern, G A; Braekevelt, E; Helm, P A; Bidleman, T F; Outridge, P M; Lockhart, W L; McNeeley, R; Rosenberg, B; Ikonomou, M G; Hamilton, P; Tomy, G T; Wilkinson, P

    2005-04-15

    Two annually laminated cores collected from Lake DV09 on Devon Island in May 1999 were dated using 210Pb and 137Cs, and analyzed for a variety of halogenated organic contaminants (HOCs), including polychlorinated biphenyls (PCBs), organochlorine pesticides, short-chain polychlorinated n-alkanes (sPCAs), polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), and polybrominated diphenyl ethers (PBDEs). Dry weight HOC concentrations in Lake DV09 sediments were generally similar to other remote Arctic lakes. Maximum HOC fluxes often agreed well with production maxima, although many compound groups exhibited maxima at or near the sediment surface, much later than peak production. The lower than expected HOC concentrations in older sediment slices may be due to anaerobic degradation and possibly to dilution resulting from a temporary increase in sedimentation rate observed between the mid-1960s and 1970s. Indeed, temporal trends were more readily apparent for those compound classes when anaerobic metabolites were also analyzed, such as for DDT and toxaphene. However, it is postulated here for the first time that the maximum or increasing HOC surface fluxes observed for many of the major compound classes in DV09 sediments may be influenced by climate variation and the resulting increase in algal primary productivity which could drive an increasing rate of HOC scavenging from the water column. Both the fraction (F(TC)) and enantiomer fraction (EF) of trans-chlordane (TC) decreased significantly between 1957 and 1997, suggesting that recent inputs to the lake are from weathered chlordane sources. PCDD/Fs showed a change in sources from pentachlorophenol (PeCP) in the 1950s and 1960s to combustion sources into the 1990s. Improvements in combustion technology may be responsible for the reducing the proportion of TCDF relative to OCDD in the most recent slice. PMID:15866277

  19. Correction of interstitial water changes in calibration methods applied to XRF core-scanning major elements in long sediment cores: Case study from the South China Sea

    NASA Astrophysics Data System (ADS)

    Chen, Quan; Kissel, Catherine; Govin, Aline; Liu, Zhifei; Xie, Xin

    2016-05-01

    Fast and nondestructive X-ray fluorescence (XRF) core scanning provides high-resolution element data that are widely used in paleoclimate studies. However, various matrix and specimen effects prevent the use of semiquantitative raw XRF core-scanning intensities for robust paleoenvironmental interpretations. We present here a case study of a 50.8 m-long piston Core MD12-3432 retrieved from the northern South China Sea. The absorption effect of interstitial water is identified as the major source of deviations between XRF core-scanning intensities and measured element concentrations. The existing two calibration methods, i.e., normalized median-scaled calibration (NMS) and multivariate log-ratio calibration (MLC), are tested with this sequence after the application of water absorption correction. The results indicate that an improvement is still required to appropriately correct the influence of downcore changes in interstitial water content in the long sediment core. Consequently, we implement a new polynomial water content correction in NMS and MLC methods, referred as NPS and P_MLC calibrations. Results calibrated by these two improved methods indicate that the influence of downcore water content changes is now appropriately corrected. We therefore recommend either of the two methods to be applied for robust paleoenvironmental interpretations of major elements measured by XRF-scanning in long sediment sequences with significant downcore interstitial water content changes.

  20. Benchscale Assessment of the Efficacy of a Reactive Core Mat to Isolate PAH-spiked Aquatic Sediments

    PubMed Central

    Meric, Dogus; Barbuto, Sara; Sheahan, Thomas C.; Shine, James P.; Alshawabkeh, Akram N.

    2013-01-01

    This paper describes the results of a benchscale testing program to assess the efficacy of a reactive core mat (RCM) for short term isolation and partial remediation of contaminated, subaqueous sediments. The 1.25 cm thick RCM (with a core reactive material such as organoclay with filtering layers on top and bottom) is placed on the sediment, and approximately 7.5 – 10 cm of overlying soil is placed on the RCM for stability and protection. A set of experiments were conducted to measure the sorption characteristics of the mat core (organoclay) and sediment used in the experiments, and to determine the fate of semi-volatile organic contaminants and non-reactive tracers through the sediment and reactive mat. The experimental study was conducted on naphthalene-spiked Neponset River (Milton, MA) sediment. The results show nonlinear sorption behavior for organoclay, with sorption capacity increasing with increasing naphthalene concentration. Neponset River sediment showed a notably high sorption capacity, likely due to the relatively high organic carbon fraction (14%). The fate and transport experiments demonstrated the short term efficiency of the reactive mat to capture the contamination that is associated with the post-capping period during which the highest consolidation-induced advective flux occurs, driving solid particles, pore fluid and soluble contaminants toward the reactive mat. The goal of the mat placement is to provide a physical filtering and chemically reactive layer to isolate contamination from the overlying water column. An important finding is that because of the high sorption capacity of the Neponset River sediment, the physical filtering capability of the mat is as critical as its chemical reactive capacity. PMID:24367237

  1. Initial Results on the Extraterrestrial Component of New Sediment Cores Containing Deposits of the Eltanin Impact Event

    NASA Technical Reports Server (NTRS)

    Kyte, Frank T.; Gersonde, Rainer

    2003-01-01

    Background The impact of the Eltanin asteroid into the Bellingshausen Sea (2.15 Ma) is the only known impact in a deep-ocean (approx. 5 km) basin. In 1995, Polarstern expedition ANT XII/4 made the first geological survey of the suspected impact region. Three sediment cores sampled around the San Martin seamounts (approx. 57.5 S, 91 W) contained well-preserved impact deposits. Sediments of Eocene age and younger were ripped up and redeposited by the impact. The depositional sequence produced by the impact has three units: a chaotic assemblage of sediment fragments up to 50 cm, followed by laminated sands deposited as a turbulent flow, and finally silts and clays that accumulated from dispersed sediments in the water column. The meteoritic impact ejecta, which is composed of shock-melted asteroidal materials and unmelted meteorites, settled through the water column and concentrated near the top of the laminated sands.

  2. Winter sea surface temperature reflected by the TEX86 proxy in core sediments from the coastal northern South China Sea

    NASA Astrophysics Data System (ADS)

    Wei, Y.; Wang, P.; Zhao, M.; Zhang, C.

    2013-12-01

    Although TEX86 is widely used as a sea surface temperature proxy for the open ocean, the validity of TEX86 in the coastal seas has yet to be tested. In this study, three sediment cores from the coastal northwestern South China Sea (SCS) (water depth 33 m for core A9, 73 m for core, and 102 m for core A9, respectively) were analyzed using lipid biomarker approaches. The distribution of archaeal core lipids varied in core A9 and A7 but remained constant in A5. TEX86-based temperature according to Kim et al. (2010) averaged 17.2 × 0.4 οC (n=30), 20.9 × 0.3 οC (n=19) and 23.0 × 0.3 οC(n=16) in core A9, A7 and A5, respectively. These results show that temperature changed little with sediment depth at each location and increased by about 3 οC between the two adjacent locations. These are lower than the annual SST (24.5-25.7 οC) and much lower than the summer SST (>28 οC), indicating that organisms producing the TEX86-related compounds mostly lived in the winter season.

  3. Distribution and sources of lipid compound series in sediment cores of the southern South China Sea.

    PubMed

    Tahir, N Mohd; Pang, S Y; Simoneit, B R T

    2015-05-01

    Three short sediment cores from inner continental shelf of the southern South China Sea (5-50 km) off Terengganu were analyzed for lipid contents (i.e., homologous aliphatic compounds and sterols) using gas chromatography-mass spectrometry. The concentrations of the total aliphatic hydrocarbons (TAHs) ranged from 0.152 to 6.91 μg/g dry weight. The n-alkane distribution was from nC₁₃ to nC₃₆, with a carbon preference index (CPI₁₃₋₃₅) from 1.08 to 4.28 and a carbon number maximum (Cmax), depending on a sample, at 31 or 18. In addition, a strong odd-to-even carbon number predominance was observed in nC₂₅-nC₃₅ range. The distribution of the n-alkanoic acids and n-alkanols in all samples exhibited an even-to-odd carbon number predominance and ranged from C₁₀ to C₂₆ and from C₁₂ to C₃₄, respectively. The n-alkanols were dominated by the long-chain homologs with Cmax at 22; on the other hand, the n-alkanoic acid distributions showed a predominance of short-chain homologs with a Cmax at 16. The total sterol concentrations ranged from 0.41 to 3.57 μg/g dry weight. Cholesterol was most abundant at the offshore stations, whereas sitosterol was dominant at near-shore station. Pentacyclic triterpenoids such as friedelin and taraxerol α- and β-amyrins, which are known biomarkers for higher plants, were detected at all stations with a dilution trend offshore. In conclusion, the marine sediments off southern Terengganu can still be considered uncontaminated, where the compound sources are biogenic from terrestrial plants superimposed with a marine productivity input. PMID:25752627

  4. Climate-induced changes in sediment supply revealed by surface exposure dating of Sijiquan River terraces, northeastern Tibet

    NASA Astrophysics Data System (ADS)

    Shirahama, Yoshiki; Miyairi, Yosuke; He, Honglin; Fu, Bihong; Echigo, Tomoo; Kano, Ken'ichi; Yokoyama, Yusuke; Ikeda, Yasutaka

    2015-04-01

    response to glacial-interglacial cycles; clastic sediments are transported from mountain slopes much more directly in glacial periods than in interglacial periods. This violates the common assumption for surface exposure dating that the inherited cosmogenic isotope concentration is constant through time.

  5. Palaeoclimatic implications of aeolian sediments on the Miaodao Islands, Bohai Sea, East China, based on OSL dating and proxies

    NASA Astrophysics Data System (ADS)

    Xu, Shujian; Ding, Xinchao; Yu, Lupeng; Ni, Zhichao

    2015-12-01

    The loess-paleosol sequences in Shandong Province, East China, is an important aeolian archive, which can provide information for aeolian activity, palaeoclimatic change and sea level change in eastern coast of China since the last interglacial period. However, for so long, most of the studies about loess have been focused on the Chinese Loess Plateau, remaining many questions and disputes about the loess in East China. The Xianjingyuan (XJY) section on the TIA, Bohai Sea, is a representative aeolian section for islands off the eastern coast of China. In this study, optically stimulated luminescence (OSL) dating, particle size and magnetic susceptibility were applied to date and analysis the loess-paleosol sequences in this section. The results show that: (1) The OSL ages at the depths of 0.8 m, 2.5 m, and 3.9 m are 12.6 ± 1.0 ka, 19.2 ± 1.1 ka and 56.9 ± 2.6 ka, respectively, and the loess started to accumulate at ca. 86.5 ka according to the depositional rates (2) The loess accumulated mainly during the Marine Isotope Stage (MIS) 2, i.e., Last glacial maximum and deglaciation, MIS4 and MIS3b with higher depositional rate, coarser grain size, and higher magnetic susceptibility; while paleosol mainly developed during MIS3a, MIS3c and MIS5 with lower depositional rate, finer grain size and lower magnetic susceptibility. (3) The palaeoclimatic changes and aeolian sediments evolution were mainly controlled by the changes of East Asian summer monsoon and sea levels.

  6. Using the U-Pb system of calcretes to date the time of sedimentation of clastic sedimentary rocks

    SciTech Connect

    Wang, Z.S.; Rasbury, E.T.; Hanson, G.N.; Meyers, W.J.

    1998-08-01

    The time of sedimentation of rapidly deposited clastic sedimentary rocks in fluvial environments may be directly dated with an uncertainty of less than three million years using U-Pb dating of pure micritic calcite from calcretes developed in overbank deposits. This conclusion is based on results obtained for calcretes (soil calcite, caliche) formed in the late Triassic New Haven Arkose, Hartford Basin, Connecticut, USA. The paragenesis of calcrete samples from the New Haven Arkose was determined using plane-polarized light and cathodoluminescence petrography, uranium fission track analysis, as well as trace element and stable isotope geochemistry. These calcretes contain an abundance of paleosol microfabrics and diagenetic calcite. The first-generation micritic calcite and second-generation blocky calcite have characteristics consistent with soil calcite. The third generation blocky calcite is a later diagenetic calcite (post-soil calcite). The U-Pb data for pure micritic calcite (first generation) in a horizontal sheet calcrete in sedimentary rocks of Norian age gives a {sup 238}U/{sup 207}Pb-{sup 206}Pb/{sub 207}Pb isochron age of 211.9 {+-} 2.1 Ma (2-sigma, and used hereafter for all ages). The U-Pb data for two samples of first generation micrite in rhizoliths with about 15% insoluble residues give ages of 7 {+-} 66 Ma and 20 {+-} 36 Ma. These results suggest that relatively recent events disturbed the U-Pb system of these detrital rich samples, perhaps due to redistribution of U during weathering or during chemical dissolution for analysis. The U-Pb data for a sample of pure third generation blocky calcite cement in a rhizolith yields a {sup 206}Pb/{sup 238}U-{sup 207}Pb/{sup 235}U isochron age of 81 {+-} 11 Ma. This age suggests that this sample of third generation blocky calcite precipitated during the late Cretaceous perhaps over an extended period.

  7. Depth Depending Pattern Recognition (DDPR) - a tool for visualization of spatial and temporal similarities of properties in sediment cores

    NASA Astrophysics Data System (ADS)

    Büttner, Olaf; Baborowski, Martina

    2013-04-01

    Depth Depending Pattern Recognition (DDPR) is a new simple tool for the visualization of spatial and temporal similarities of measured parameters in a set of sediment cores. It was developed to support the multivariate analysis of data of sediment cores taken in a still water area of the River Elbe [1]. The idea behind is the assumption that correlations in spatial or temporal distributions of environmental parameters can be visualized by different ways and that a distance between two patterns can be defined with mathematical methods. So the similarity of two patterns can be quantified and assessed by a catalog of subjective rules. Generally, defining one reference pattern, the computation of a distance matrix for different parameter distributions is easily possible. Consequently, the three main steps of the algorithm are a) the creation of the pattern from the measurements, b) the definition of the distance calculation and c) the interpretation and assessment of the distance matrix. The method can be used in addition to classical uni- or multivariate statistical methods like regression analysis, principal component analysis, correlation analysis etc. DDPR supports hypothesis testing and explanation of relationships. In the poster DDPR is explained and the method is presented for two examples, an artificial one and one with data from sediment cores. Reference [1] Baborowski M., Büttner O., Morgenstern P., Jancke T., Westrich B. (2012) Spatial variability of metal pollution in groyne fields of the Middle Elbe - Implications for sediment monitoring, Environmental Pollution, 167,115-123

  8. Iridium Concentrations and Abundances of Meteoritic Ejecta from the Eltanin Impact in Sediment Cores from Polarstern Expedition ANT XII/4

    NASA Technical Reports Server (NTRS)

    Kyte, Frank T.

    2002-01-01

    The abundances of meteoritic ejecta from the Eltanin asteroid impact have been examined in several sediment cores recovered by the FS Polarstern during expedition ANT XII/4 using elemental concentrations of iridium and weights of coarse ejecta debris. Three cores with well-preserved impact deposits, PS204-1, PS2708-1, and PS2709-1, each contain Ir and ejecta fluences similar to those found in USNS Eltanin core E13-4. Small Ir anomalies and traces of ejecta were found in cores PS2706-1 and PS2710-1, but since these cores lack well-defined deposits, these are considered to be reworked and not representative of the fallout. No evidence of ejecta was found in cores PS2802-1 and PS2705-1. These results confirm earlier speculation that the Eltanin impact resulted in deposits of ejecta with up to 1 gram/sq centimeter of depris over a wide area of the ocean floor. However, there are sill large uncertainties over the actual regional or global extent of this unique sediment deposit.

  9. Quantitative mineralogy of surface sediments of the Iceland shelf, and application to down-core studies of holocene ice-rafted sediments

    USGS Publications Warehouse

    Andrews, John T.; Eberl, D.D.

    2007-01-01

    Quantitative X-ray diffraction analyses on the < 2 mm sediment fraction from the Iceland shelves are reported for subglacial diamictons, seafloor surface sediments, and the last 2000 cal yr BP from two cores. The overall goal of the paper is to characterize the spatial variability of the mineralogy of the present-day surface sediments (18 non-clay minerals and 7 clay minerals), compare that with largely in situ erosional products typified by the composition of subglacial diamictons, and finally examine the late Holocene temporal variability in mineral composition using multi-mineral compositions. The subglacial diamictons are dominated in the non-clay-mineral fraction by the plagioclase feldspars and pyroxene with 36.7 ?? 6.1 and 17.9 ?? 3.5 wt % respectively, with smectites being the dominant clay minerals. The surface seafloor sediments have similar compositions although there are substantial amounts of calcite, plus there is a distinct band of sites from NW to N-central Iceland that contain 1-6 wt% of quartz. This latter distribution mimics the modern and historic pattern of drift ice in Iceland waters. Principal component analysis of the transformed wt% (log-ratio) non-clay minerals is used to compare the subglacial, surface, and down-core mineral compositions. Fifty-eight percent of the variance is explained by the first two axes, with dolomite, microcline, and quartz being important "foreign" species. These analyses indicate that today the NW-N-central Iceland shelf is affected by the import of exotic minerals, which are transported and released from drift ice. The down-core mineralogy indicates that this is a process that has varied over the last 2000 cal yr BP. Copyright ?? 2007, SEPM (Society for Sedimentary Geology).

  10. A luminescence dating study of the sediment stratigraphy of the Lajia Ruins in the upper Yellow River valley, China

    NASA Astrophysics Data System (ADS)

    Zhang, Yuzhu; Huang, Chun Chang; Pang, Jiangli; Zhou, Yali; Zha, Xiaochun; Wang, Longsheng; Zhou, Liang; Guo, Yongqiang; Wang, Leibin

    2014-06-01

    Pedo-sedimentological fieldwork were carried out in the Lajia Ruins within the Guanting Basin along the upper Yellow River valley. In the eolian loess-soil sections on the second river terrace in the Lajia Ruins, we find that the land of the Qijia Culture (4.20-3.95 ka BP) are fractured by several sets of earthquake fissures. A conglomerated red clay covers the ground of the Qijia Culture and also fills in the earthquake fissures. The clay was deposited by enormous mudflows in association with catastrophic earthquakes and rainstorms. The aim of this study is to provide a luminescence chronology of the sediment stratigraphy of the Lajia Ruins. Eight samples were taken from an eolian loess-soil section (Xialajia section) in the ruins for optically stimulated luminescence (OSL) dating. The OSL ages are in stratigraphic order and range from (31.94 ± 1.99) ka to (0.76 ± 0.02) ka. Combined OSL and 14C ages with additional stratigraphic correlations, a chronological framework is established. We conclude that: (1) the second terrace of the upper part of Yellow River formed 35.00 ka ago, which was followed by the accumulation of the eolian loess-soil section; and (2) the eolian loess-soil section is composed of the Malan Loess of the late last glacial (MIS-2) and Holocene loess-soil sequences.

  11. History and geochemistry of a metalliferous sediment core from the Mid-Atlantic Ridge at 26 degree N

    SciTech Connect

    Metz, S.; Trefry, J.H. ); Nelsen, T.A. )

    1988-10-01

    Fourteen thousand years of hydrothermal deposition are recorded in a metalliferous sediment core recovered from the Trans-Atlantic Geotraverse (TAG) Hydrothermal Field on the Mid-Atlantic Ridge at 26{degree}N. An estimated 26 to > 96% of the sediment at this core site is hydrothermally derived as determined from the CaCO{sub 3}, Al and Fe data. Layers of essentially pure vent precipitates contain < 3% CaCO{sub 3} and < 0.5% Al, with high concentrations of Fe (43%), Cu (4.1%), Zn (1.2%), Mn (1.1%), V (480 ppm), Pb (175 ppm), Cd (32 ppm) and Hg (3.8 ppm). Sediment accumulation rates vary from {approximately}1 to > 30 g/cm{sup 2}/1,000 y throughout the core, a function of the intensity of hydrothermal inputs. Distinct hydrothermal events are recorded at 6,000 and 8,500 y B.P. in layers containing > 90% vent-derived material. Vertical metal profiles and interelement relationships in the core result from variable deposition of oxides and sulfides, oxidation and dissolution of sulfide phases and scavenging of metals from seawater.

  12. Are Your Paleoecological Indicators Telling the Truth? Diatoms in Great Lakes Sediment Cores As an Example

    NASA Astrophysics Data System (ADS)

    Reavie, E. D.; Heathcote, A.

    2014-12-01

    Many existing models to infer paleoecological conditions from species assemblages are based on weak species-environmental relationships that are confounded by secondary variables, resulting in poor predictive power. We evaluated diatoms from Laurentian Great Lakes phytoplankton samples in the development of a total phosphorus (TP) transfer function based on weighted-average species abundance. Several tests were applied to validate our new indicator. Of the 118 common diatom taxa 76% had non-monotonous responses along the Great Lakes TP gradient. However, there was substantial autocorrelation among samples, justifying the need for further validation. A randomization procedure indicated that the actual transfer function consistently performed better than simulated functions. Further, TP was minimally confounded by other environmental variables. We then hindcasted TP using fossil diatom assemblages in a Lake Superior sediment core. Passive, multivariate analysis of the fossil samples against the training set data indicated that TP was a major determinant of historical diatoms, verifying that the function was well suited to reconstruct past TP. Collectively, these results show that diatom coefficients for water quality are robust indicators of Great Lakes condition. We recommend use in management when retrospective data are needed for tracking long-term degradation, remediation and trajectories.

  13. USE OF SEDIMENT CORE PROFILING IN ASSESSING EFFECTIVENESS OF MONITORED NATURAL RECOVERY

    EPA Science Inventory

    The Sediment Issue summarizes two studies conducted by the National Risk Management Research Laboratory of U.S. EPA to evaluate the natural recovery of surface sediments contaminated with polycyclic aromatic hydrocarbons (PAHs) an polychlorinated biphenyls (PCBs). Natural recove...

  14. Radiocarbon dating of silica sinter deposits in shallow drill cores from the Upper Geyser Basin, Yellowstone National Park

    USGS Publications Warehouse

    Lowenstern, Jacob B.; Hurwitz, Shaul; McGeehin, John

    2016-01-01

    To explore the timing of hydrothermal activity at the Upper Geyser Basin (UGB) in Yellowstone National Park, we obtained seven new accelerator mass spectrometry (AMS) radiocarbon 14C ages of carbonaceous material trapped within siliceous sinter. Five samples came from depths of 15–152 cm within the Y-1 well, and two samples were from well Y-7 (depths of 24 cm and 122 cm). These two wells, at Black Sand and Biscuit Basins, respectively, were drilled in 1967 as part of a scientific drilling program by the U.S. Geological Survey (White et al., 1975). Even with samples as small as 15 g, we obtained sufficient carbonaceous material (a mixture of thermophilic mats, pollen, and charcoal) for the 14C analyses. Apparent time of deposition ranged from 3775 ± 25 and 2910 ± 30 14C years BP at the top of the cores to about 8000 years BP at the bottom. The dates are consistent with variable rates of sinter formation at individual sites within the UGB over the Holocene. On a basin-wide scale, though, these and other existing 14C dates hint that hydrothermal activity at the UGB may have been continuous throughout the Holocene.

  15. Radiocarbon dating of silica sinter deposits in shallow drill cores from the Upper Geyser Basin, Yellowstone National Park

    NASA Astrophysics Data System (ADS)

    Lowenstern, Jacob B.; Hurwitz, Shaul; McGeehin, John P.

    2016-01-01

    To explore the timing of hydrothermal activity at the Upper Geyser Basin (UGB) in Yellowstone National Park, we obtained seven new accelerator mass spectrometry (AMS) radiocarbon 14C ages of carbonaceous material trapped within siliceous sinter. Five samples came from depths of 15-152 cm within the Y-1 well, and two samples were from well Y-7 (depths of 24 cm and 122 cm). These two wells, at Black Sand and Biscuit Basins, respectively, were drilled in 1967 as part of a scientific drilling program by the U.S. Geological Survey (White et al., 1975). Even with samples as small as 15 g, we obtained sufficient carbonaceous material (a mixture of thermophilic mats, pollen, and charcoal) for the 14C analyses. Apparent time of deposition ranged from 3775 ± 25 and 2910 ± 30 14C years BP at the top of the cores to about 8000 years BP at the bottom. The dates are consistent with variable rates of sinter formation at individual sites within the UGB over the Holocene. On a basin-wide scale, though, these and other existing 14C dates hint that hydrothermal activity at the UGB may have been continuous throughout the Holocene.

  16. Spatial and Temporal Patterns in Black Carbon Deposition to Dated Fennoscandian Arctic Lake Sediments from 1830 to 2010.

    PubMed

    Ruppel, Meri M; Gustafsson, Örjan; Rose, Neil L; Pesonen, Antto; Yang, Handong; Weckström, Jan; Palonen, Vesa; Oinonen, Markku J; Korhola, Atte

    2015-12-15

    Black carbon (BC) is fine particulate matter produced by the incomplete combustion of biomass and fossil fuels. It has a strong climate warming effect that is amplified in the Arctic. Long-term trends of BC play an important role in assessing the climatic effects of BC and in model validation. However, few historical BC records exist from high latitudes. We present five lake-sediment soot-BC (SBC) records from the Fennoscandian Arctic and compare them with records of spheroidal carbonaceous fly-ash particles (SCPs), another BC component, for ca. the last 120 years. The records show spatial and temporal variation in SBC fluxes. Two northernmost lakes indicate declining values from 1960 to the present, which is consistent with modeled BC deposition and atmospheric measurements in the area. However, two lakes located closer to the Kola Peninsula (Russia) have recorded increasing SBC fluxes from 1970 to the present, which is likely caused by regional industrial emissions. The increasing trend is in agreement with a Svalbard ice-core-BC record. The results suggest that BC deposition in parts of the European Arctic may have increased over the last few decades, and further studies are needed to clarify the spatial extent of the increasing BC values and to ascertain the climatic implications. PMID:26575216

  17. He Pb double dating of detrital zircons from the Ganges and Indus Rivers: Implication for quantifying sediment recycling and provenance studies

    NASA Astrophysics Data System (ADS)

    Campbell, Ian H.; Reiners, Peter W.; Allen, Charlotte M.; Nicolescu, Stefan; Upadhyay, Rajeev

    2005-09-01

    He-Pb double dating of detrital zircons is more reliable than conventional U-Pb dating for tracing the source of detritus in sediments and can be used to constrain the percentage of recycled material in sediments. Conventional U-Pb dating can be used to constrain the provenance of sediments if the U-Pb zircon age pattern for potential source regions is known but can only be used to trace the source of individual zircons if they are first-cycle grains. The advantages of He-Pb double dating are demonstrated using examples from the Indus and Ganges rivers, and previously published data from the Navajo sandstone. Conventional U-Pb dating can unambiguously identify only 2.5% of the Ganges zircons, and 18% of the Indus zircons as coming from the Himalayan Mountains or Tibet Plateau and only 23% of the Navajo zircons as coming from the Appalachian Mountains. The correct figure, as determined from double dating, is over 95% from the Himalayan Mountains or Tibet Plateau in the case of the Indus and Ganges rivers and at least 70% from the Appalachian Mountains in the case of the Navajo Sandstone. This result casts doubt on the reliability of the U-Pb method when used in the absence of other techniques, such as He dating, to identify the true provenance of sediments, as opposed to the ultimate source of the zircons. Double dating also shows that at least 60% of the Indus and 70% of the Ganges and Navajo sandstone zircons have been recycled from earlier sediments. Exhumation rates, estimated from the He dates, reveal that ˜ 75% of the Indus and Ganges zircons were derived from areas where the exhumation rate exceeds 1.5 km/Myr. These rates are higher and more varied than those calculated from detrital muscovites. These results imply that ˜ 75% of the eroded material in the Himalayan Mountains is derived from areas of anomalously high erosion where the short-term exhumation rate exceeds the long-term average.

  18. {sup 210}Pb dating of sediments from the central and the northern Adriatic Sea: The deposition and preservation of sedimentary organic carbon

    SciTech Connect

    Hamilton, T.; Fowler, S.; Miquel, J.C.; La Rosa, J.

    1996-04-01

    A central goal of the ELNA project is to assess the carbon assimilation capacity of the Northern Adriatic Sea. This requires fundamental quantitative information on budgets and sinks of organic carbon. Any change in carbon production in the water column should be reflected in the underlying sediments. Moreover, the fraction of particulate organic carbon reaching the sea floor which is subsequently preserved in the sediment will be strongly coupled to sediment accumulation and mixing. In this study a series of box cores were collected in order to characterize a hypothetical eutrophication gradient extending from the Po River outflow region in the north down to the shallow meso-Adriatic depression (Jabuka Pit). The main tasks assigned to IAEA-MEL were to provide {sup 210}Pb derived sedimentation and dry-mass accumulation rates and to examine the possible correlations between sedimentary processes, the deposition and preservation of sedimentary organic carbon and pelagic primary productivity.

  19. Biomarker signatures in sediment cores of Lake Urmia (NW Iran): Potential implications for paleo-climate and paleo-environment reconstruction

    NASA Astrophysics Data System (ADS)

    Haghipour, Negar; Eglinton, Timothy Ian; McIntyre, Cameron; Darvishi Khatooni, Javad; Hunziker, Daniela; Mohammadi, Ali

    2015-04-01

    Lake Urmia, in northwest Iran, is the largest saline lake in the Middle East with a surface area of ~ 5000km2. Historical documents indicate its existence since at least 2000 years BC, and palynological investigation of a 100 m-long core suggest it contains a sedimentary record spanning the last 200 ka. Despite this potential as an archive of paleo-climate and paleo-environmental information, to date there has been no molecular organic geochemical investigation or precise dating of these sediments. As part of an exploratory study, we have analyzed material from 3 recently collected 8 m-long cores from the eastern, western and middle part of the lake, with the aim of gaining insight in to past depositional and environmental conditions from biomarker signatures preserved in Lake Urmia sediments. The main objectives are to 1) constrain major source(s) of organic matter and gain insights into carbon cycle and depositional processes from bulk isotopic (δ13Corg, 14Corg) and molecular information, 2) determine the applicability of molecular proxies (TEX86 index derived from glyceroldialkylglycerol tetraethers, GDGTs, and unsaturation index UK37 based on long chain alkenones) for paleo-temperature reconstruction and 3) reconstruct the paleo- vegetation and hydrology from compound-specific stable isotopes (δ13C and δD of n-alkanes). In select samples examined from the three cores, we find the hydrocarbon fractions are dominated by long-chain n-alkanes, with n-C29 and C31 as the dominant homologues in most of the samples. Based on the n-alkane distribution, we distinguish two main types; Type 1 mainly includes the samples deeper than ca 4 m (CPI= 10.2, ACL= 30), characteristic of a terrestrial higher plant source; Type 2 comprises mainly shallower samples (CPI =1.5, ACL = 27.3) which may suggest an increased contribution of aquatic plants. Preliminary GDGT analyses indicate low BIT values for most samples, which suggest little input of soil-derived branched-GDGTs. The

  20. Holocene environmental changes in the south-western Baltic Sea reflected by the geochemical data and diatoms of the sediment cores

    NASA Astrophysics Data System (ADS)

    Kostecki, Robert; Janczak-Kostecka, Beata

    2012-12-01

    Marine sediment cores from the Pomeranian Bay and Arkona Basin were analysed in terms of geochemical composition, diatom assemblages and radiocarbon dating, in order to evaluate the characteristics of the Littorina transgression, on the environment of the south Baltic basin. The data show that this transgression had a strong influence on the evolution of the hydrographic system, which has changed substantially from the Ancylus Lake to the Littorina Sea. The beginning of the period of the Littorina Sea was estimated at 7400-8000 cal BP, but culmination of the marine ingression appeared a few hundred years afterwards in the western cores from the Arkona Basin, and almost 2000 years later in the eastern cores from the Pomeranian Bay. In this study we present a new look at the evolution of the Baltic Sea during the Holocene, based on the statistical analysis of relations between geochemical composition and diatom occurrence. Canonical correlation analysis clearly describes Ancylus and Littorina environments. The Ancylus Lake was characterised as a cold lacustrine environment with poor nutrient availability and high mineral matter inflow, probably from adjacent rivers, while the Littorina Sea environment was much warmer, with a high inflow of nutrients that favoured biogenic production.

  1. Post-Wisconsinan Chemical Weathering Rates and Trajectories From a 13,400-Year Sediment Core Record of Lead Isotopic Ratios in Maine

    NASA Astrophysics Data System (ADS)

    Perry, R. H.; Norton, S. A.; Koons, P. O.; Handley, M.

    2008-12-01

    Lead isotopic ratios recorded in a 5.3-m 13.4-ka 14C-dated lake sediment core from Sargent Mountain Pond, Maine (USA) are interpreted as an archive of post-glacial chemical weathering. Early weathering yielded highly radiogenic sediment from the preferential release of U and Th decay products (206Pb, 207Pb, and 208Pb) from accessory mineral phases in the catchment's predominantly-granitic till and bedrock relative to non-radiogenic 204Pb from the more abundant primary minerals. Values for 207Pb/206Pb in the sediment increased rapidly from 0.799 to 0.814 in the catchment's first 4,000 years of post-Wisconsinan weathering, and thereafter increased only slightly to just prior to the 19th century. Values for 208Pb/204Pb, 207Pb/204Pb, and 206Pb/204Pb decline over the same time-scale, as a result of decreasing radiogenic Pb being released from catchment weathering. Our results are consistent with: (1) the published interpretation of Pb isotopic variation in ferromanganese ocean crusts as a reflection of continental-scale glacial-interglacial chemical weathering cycles, (2) bench-scale whole-rock weathering experiments, and (3) soil chronosequence Pb isotope dissolution experiments and bridge the gap between short-term, mineral-scale experiments and long-term, ocean sediment records. We establish a time-scale for depletion of accessory minerals, and loss of their Pb isotopic signature at one catchment, and document the concurrent shift to slower primary mineral-controlled chemical weathering after deglaciation.

  2. Geochemistry of Miocene glass in sediments from the AND-2A Core, McMurdo Sound, Antarctica: magma petrogenesis and response to glacial unloading

    NASA Astrophysics Data System (ADS)

    Nyland, R.; Rocchi, S.; Di Vincenzo, G.; Del Carlo, P.; Tiepolo, M.; Field, B.

    2011-12-01

    Volcanic glass recovered from the AND-2A core between ~354 and 765 mbsf (~15.9-18.4 Ma) occurs as accumulations (2-50 vol.%) within sediments. Glass-rich sediments consist of muddy to fine sandstone and stratified diamictite. Glass varies in color, size, vesicularity, crystal content, angularity, and from fresh to moderately altered. The common occurrence of delicate cuspate forms and fresh glass suggest that they were introduced directly into the water as ashfall with minimal reworking. Therefore, key samples currently being dated using the 40Ar/39Ar method will likely provide important time horizons for the core. Pristine basaltic glass (MgO 3-8 wt.%) is ne-normative (5-30 wt.%) and has a restricted average SiO2 content (ca. 45.2 ± 0.8 wt.%). Variations in CaO and TiO2, positively correlated with MgO content, indicate differentiation controlled by fractionation of plagioclase, olivine, clinopyroxene and magnetite. Trace element concentrations, determined on glasses by LA-ICP-MS, are typical for alkaline volcanism of the Erebus Volcanic Province (EVP). Specifically, our data extends the known compositional range of Mt. Morning, the only known Early-Middle Miocene source in the EVP, to more mafic compositions, revealing the roots of both high alkaline (basanite to phonolite) and lower alkaline (alkali basalt to trachyte) differentiation series. Glass-rich sediments in glacimarine sequences from the AND-2A core record numerous cycles of glacial advance and retreat [1, 2]. Increases in rate, explosivity and volume of volcanism have been related to crustal loading and unloading by ice-sheets in Iceland and elsewhere. AND-2A sediments with high glass contents correspond with ice minimums and, geochemically, Ba/La and Ba/Hf ratios are correlated to intervals of ice expansion (decreasing values) and contraction (increasing values) at multiple depths. Within a single cycle, glass angularity, vesicularity, and composition also vary systematically. Results provide new

  3. Numerical modeling of coupled nitrification-denitrification in sediment perfusion cores from the hyporheic zone of the Shingobee River, MN

    USGS Publications Warehouse

    Sheibley, R.W.; Jackman, A.P.; Duff, J.H.; Triska, F.J.

    2003-01-01

    Nitrification and denitrification kinetics in sediment perfusion cores were numerically modeled and compared to experiments on cores from the Shingobee River MN, USA. The experimental design incorporated mixing groundwater discharge with stream water penetration into the cores, which provided a well-defined, one-dimensional simulation of in situ hydrologic conditions. Ammonium (NH+4) and nitrate (NO-3) concentration gradients suggested the upper region of the cores supported coupled nitrification-denitrification, where groundwater-derived NH+4 was first oxidized to NO-3 then subsequently reduced via denitrification to N2. Nitrification and denitrification were modeled using a Crank-Nicolson finite difference approximation to a one-dimensional advection-dispersion equation. Both processes were modeled using first-order reaction kinetics because substrate concentrations (NH+4 and NO-3) were much smaller than published Michaelis constants. Rate coefficients for nitrification and denitrification ranged from 0.2 to 15.8 h-1 and 0.02 to 8.0 h-1, respectively. The rate constants followed an Arrhenius relationship between 7.5 and 22 ??C. Activation energies for nitrification and denitrification were 162 and 97.3 kJ/mol, respectively. Seasonal NH+4 concentration patterns in the Shingobee River were accurately simulated from the relationship between perfusion core temperature and NH+4 flux to the overlying water. The simulations suggest that NH+4 in groundwater discharge is controlled by sediment nitrification that, consistent with its activation energy, is strongly temperature dependent. ?? 2003 Elsevier Ltd. All rights reserved.

  4. U-Th and ESR dating of drilled cores from a giant hydrothermal mounds in South Mariana

    NASA Astrophysics Data System (ADS)

    Takamasa, A.; Nakai, S.; Sato, F.; Toyoda, S.; Ishibashi, J.

    2012-12-01

    The time scale for hydrothermal activity is an important factor controlling the size of hydrothermal ore deposits and the evolution of chemosynthesis-based communities in a submarine hydrothermal system. We determined the age of hydrothermal deposits samples, both collected samples by submersible and drilled core samples from South Mariana Trough. Samples were collected from four hydrothermal sites, Snail (near the spreading axis), Archean ( 1.5km from the axis), Pika ( 4.9km from the axis) and Urashima ( 4.9km from the axis). 230Th-234U radioactive disequilibrium dating was applied to hydrothermal sufide minerals consisting of pyrite and sphalerite while electron spin resonance (ESR) dating was applied to barite. For 230Th-234U radioactive disequilibrium dating, we carried out magnetic separation for bulk samples, then we digested samples with nitric acid. U and Th were purified by two-step column separations, and isotopic compositions of spiked and unspiked U and Th were measured by a MC-ICP-MS. Analytical methods for ESR age determination were described in a companion abstract by Toyoda et al. We found that the magnetic fractions had significantly higher U/Th ratios, which enabled 230Th-234U age determinations as precise as ±2% (2σ). This probably reflects that pyrite enriched in magnetic fractions has high U/Th ration. In a sulfide crust sample collected from Archean site, the 230Th-234U ages of the sulfide minerals (0.3-2.2 ka) were compared with ESR ages of barites separated from 12 subsamples of the same sulfide crust. ESR ages (0.27 - 1.7 ka) show a spatial pattern broadly resembling that observed in 230Th-234U dating method. While there are some significant offsets, these results illustrate the potential of the two methods for use in provide information on evolution history of a hydrothermal system. Samples from Pika, Archean and Snail sites yield from 0.5 to ~9 ka, from 0.1 to 3 ka and < ~90 a, respectively. The oldest ages from each site are correlated

  5. The extent and historical trend of metal pollution recorded in core sediments from the artificial Lake Shihwa, Korea.

    PubMed

    Ra, Kongtae; Bang, Jae-Hyun; Lee, Jung-Moo; Kim, Kyung-Tae; Kim, Eun-Soo

    2011-08-01

    The vertical distribution of trace metals in sediment cores was investigated to evaluate the extent and the historical record of metal pollution over 30 years in the artificial Lake Shihwa in Korea. A marked increase of trace metals after 1980 was observed due to the operation of two large industrial complexes and dike construction for a reclamation project. There was a decreasing trend of metal concentrations with the distance from the pollution source. The enrichment factor and pollution load index of the metals indicated that the metal pollution was mainly derived from Cu, Zn and Cd loads due to anthropogenic activities. The concentrations of Cr, Ni, Cu, Zn, As and Pb in the upper part of all core sediments exceeded the ERL criteria of NOAA. Our results indicate that inadequate planning and management of industrialization and a large reclamation project accomplished by dike construction have continued to strongly accelerate metal pollution in Lake Shihwa. PMID:21658731

  6. Relationship of polycyclic aromatic hydrocarbons with algae-derived organic matter in sediment cores from a subtropical region

    NASA Astrophysics Data System (ADS)

    Duan, Dandan; Huang, Youda; Cheng, Hefa; Ran, Yong

    2015-11-01

    The influence of algae-derived organic matter (AOM) and climate warming on the historical record of polycyclic aromatic hydrocarbons (PAHs) in the subtropical reservoir sediments was investigated. The profiles of PAH concentrations and AOM contents at the eutrophic and meso-eutrophic reservoirs are significantly elevated and show good correlations with increasing mean air temperature during the past 60 years, suggesting that increasing temperature plays a significant role in increase of algal productivity and PAH deposition. Temperature-mediated AOM is suggested to enhance the deposition and accumulation of pyrogenic PAHs in the sediment cores, also implying an inaccurate estimation on the historical record for atmospheric deposition of PAHs in eutrophic and meso-eutrophic reservoirs. For an oligotrophic reservoir, PAHs decrease as the sediment depth decreases and are less significantly related to AOM. As the oligotrophic reservoir is phosphorus limited and its AOM is significantly oxidized, the effect of increasing temperature on AOM and PAHs is insignificant.

  7. Lead isotope ratios in six lake sediment cores from Japan Archipelago: Historical record of trans-boundary pollution sources.

    PubMed

    Hosono, Takahiro; Alvarez, Kelly; Kuwae, Michinobu

    2016-07-15

    Sediment cores from six lakes situated from north to south on the Japanese Archipelago were collected during 2009-2010 to investigate the hypothesis that deposition of lead (Pb) was coming from East Asia (including China, South Korea and eastern part of Russia). Accumulation rates and ages of the lake sediment were estimated by the (210)Pb constant rate of supply model and (137)Cs inputs to reconstruct the historical trends of Pb accumulation. Cores from four lakes located in the north and central Japan, showed clear evidence of Pb pollution with a change in the (206)Pb/(207)Pb and (208)Pb/(207)Pb ratios in the recent sediment as compared to the deeper sediment. Among the six studied lakes, significant inputs of anthropogenic lead emissions were observed at Lake Mikazuki (north Hokkaido in north Japan), Lake Chokai (north of Honshu), and Lake Mikuriga (central part of Honshu). Pb isotopic comparison of collected core sediment and previously reported data for wet precipitation and aerosols from different Asian regions indicate that, before 1900, Pb accumulated in these three lakes was not affected by trans-boundary sources. Lake Mikazuki started to receive Pb emissions from Russia in early 1900s, and during the last two decades, this lake has been affected by trans-boundary Pb pollution from northern China. Lake Chokai has received Pb pollutant from northern China since early 1900s until 2009, whereas for the Lake Mikuriga the major Pb contaminant was transported from southern China during the past 100years. The results of our study demonstrate that Japan Archipelago has received trans-boundary Pb emissions from different parts of East Asian region depending on location, and the major source region has changed historically. PMID:27058126

  8. Linking Late Pleistocene alpine glacial erosion and continental margin sedimentation: Insights from 40Ar/39Ar dating of silt-sized sediment, Canterbury Basin, New Zealand

    NASA Astrophysics Data System (ADS)

    Villaseñor, Tania; Jaeger, John M.; Foster, David A.

    2016-01-01

    Quaternary climatic and eustatic cycles in mid-latitude regions have led to more extensive alpine glaciations and continental shelf progradation, respectively. However, the glacial influence on sediment fluxes to the ocean creating continental margin strata is poorly documented. This contribution analyzes the provenance of fine sediment accumulating on the continental shelf during the Late Pleistocene to evaluate the influence of glacial cycles on sediment erosion and routing to the continental shelf. Taking advantage of the contrasting bedrock ages exposed across the Southern Alps, New Zealand, we perform 40Ar/39Ar incremental heating on the bulk silt-size sediment from three drill sites of IODP Expedition 317, Canterbury Basin, New Zealand. The results suggest that a large proportion of sediment accumulating on the continental shelf results from erosion within the Main Divide fault zone of the Southern Alps. Sediment 40Ar/39Ar age fluctuations over this time period suggest that bedrock with various 40Ar/39Ar cooling ages has been differentially eroded in the upper Waitaki River catchment and mixed in the Waitaki-Canterbury sediment-routing system. Across-shelf variations in sediment 40Ar/39Ar age reflect changing modes of sediment dispersal on the continental shelf. Fluvial material, likely derived from the main drainage divide zone, preferentially accumulates in the middle continental shelf, whereas material representing erosion of older bedrock (Torlesse Terrane), located lower in the drainage basin, is dispersed uniformly across the shelf. The age signature of the muddy sediment accumulating on the continental shelf reflects Late Pleistocene landscape evolution of the Southern Alps and its influence on sediment dispersal to the continental shelf.

  9. [Concentrations and Distribution of Metals in the Core Sediments from Estuary and City Section of Liaohe River].

    PubMed

    Wang, Wei-jie; Zhou, Jun-li; Pei, Shu-wei; Liu, Zheng-tao

    2016-01-15

    The particle size, total organic carbon (TOC), total nitrogen (TN), C/N ratio and metal concentrations as well as activities of 210Pb were determined in Liaohe River estuary area (LN-2) and Shenyang area (LN-5), and the organic matter resources were discussed in two core sediments. Also the index of geoaccumulation (Igeo) and enrichment factors (EFs) methods were applied to evaluate the state of heavy metal contamination in the studied sties. The study showed that both sediment cores LN-2 and LN-5 were dominated by silts, and the vertical variations of grain-size composition and organic matter were well distributed in LN- 2 while fluctuated in LN-5. According to the organic matter source analysis through C/N ratio, C/N ratio varied in the scale of 5. 24-7.93 in LN-2 which was dominated by river source, and 9.94-14.21 in LN-5 which was dominated by terrestrial input. Al, Ca, Fe, Mn, Ni, Cu, Zn, Cd, Pb and Cr in two sediment cores had different vertical changing rules, Ni and Zn in LN-2 as well as Pb and Zn in LN-5 were affected by both natural and human factors, other elements had similar distributions to those of organic matters, which showed that these elements were mainly affected by the natural activities. Based on Igeo and EFs, both sediment cores were more severely polluted with Ni, Zn and Pb than other metals. The effects of human activities on the environment were also discussed in this study, combined with the economical development of Liaoning Province and the studied sites in the past 20 years. PMID:27078953

  10. Historical contamination of PAHs, PCBs, DDTs, and heavy metals in Mississippi River Delta, Galveston Bay and Tampa Bay sediment cores.

    PubMed

    Santschi, P H; Presley, B J; Wade, T L; Garcia-Romero, B; Baskaran, M

    2001-07-01

    Profiles of trace contaminant concentrations in sediment columns can be a natural archive from which pollutant inputs into coastal areas can be reconstructed. Reconstruction of historical inputs of anthropogenic chemicals is important for improving management strategies and evaluating the success of recent pollution controls measures. Here we report a reconstruction of historical contamination into three coastal sites along the US Gulf Coast: Mississippi River Delta, Galveston Bay and Tampa Bay. Within the watersheds of these areas are extensive agricultural lands as well as more than 50% of the chemical and refinery capacity of the USA. Despite this pollution potential, relatively low concentrations of trace metals and trace organic contaminants were found in one core from each of the three sites. Concentrations and fluxes of most trace metals found in surface sediments at these three sites, when normalized to Al, are typical for uncontaminated Gulf Coast sediments. Hydrophobic trace organic contaminants that are anthropogenic (polycyclic aromatic hydrocarbons, DDTs, and polychlorinated biphenyls) are found in sediments from all locations. The presence in surface sediments from the Mississippi River Delta of low level trace contaminants such as DDTs, which were banned in the early 1970's, indicate that they are still washed out from cultivated soils. It appears that the DDTs profile in that sediment core was produced by a combination of erosion processes of riverine and other sedimentary deposits during floods. Most of the pollutant profiles indicate that present-day conditions have improved from the more contaminated conditions in the 1950-1970's, before the advent of the Clean Water Act. PMID:11488356

  11. Final report on the sampling and analysis of sediment cores from the L-Area oil and chemical basin

    SciTech Connect

    Not Available

    1985-08-01

    Nine vibracores were collected in the L-Area oil and chemical basin (904-83G) during late March and early April 1985. These cores were collected for analysis of the sludge on the basin floor and the underlying sediment. Several different field and laboratory analyses were performed on each three inch segment of all the cores. These included: (1) Sediment characterization; (2) Percent moisture; (3) Dry weight; (4) Spectral gamma analysis; (5) Gross alpha and beta analysis. Detailed chemical analysis were measured on selected intervals of 2 cores (LBC-5 and 6) for complete chemical characterization of the sediments. This sampling program was conducted to provide information so that a closure plan for the basin could be developed. This report describes the methods employed during the project and provide a hard copy of the analytical results from the sample analyses. Included in the appendices are copies of all field and laboratory notes taken during the project and copies of the gas chromatograms for the petroleum hydrocarbon analysis. All chemical results were also submitted on a 5-inch floppy disk.

  12. The stabilisation of wet sediment cores by means of a polyethylene glycol/freeze-drying treatment for display and permanent storage

    NASA Astrophysics Data System (ADS)

    Hoffmann, Per; Pätzold, Jürgen

    2001-12-01

    A reversible method is presented to transform waterlogged sediment cores into dry and stable specimens which can go on exhibition or into permanent storage, needing no special precautions. Wet sediment core segments are bath-impregnated with polyethylene glycol of molecular weight 3,350 (PEG 3,350) dissolved in water. The samples are then subjected to a freeze-drying process, during which the PEG forms a stabilising and bonding porous network structure in the capillary system of the sediment. Standard sediment cores at least 1 m long become strong enough to stand upright. Sediment types ranging from muddy deep-sea sediments to very coarse littoral Halimeda sand were successfully stabilised. For standard cores of 10-cm diameters split length-wise, impregnation times vary from 2 weeks for coarse sand to 6-10 weeks for more compacted sediments. With regard to the stability of the samples and the visual clarity of detail, best results were obtained by impregnation with 25 to 60% solutions of PEG 3,350, coarse sediments needing more PEG than finer ones. Colour changes are systematic - the processed samples are lighter in appearance and the contrasts are enhanced, but there is no serious shift in colour tones. The PEG can easily be re-dissolved and washed out of the sediments. Display specimens can thus be made available for research again.

  13. 3.5-D model of sediment age and grain size for the Northern Gulf of Aqaba-Elat (Red Sea) using submarine cores

    NASA Astrophysics Data System (ADS)

    Kanari, Mor; Ben-Avraham, Zvi; Tibor, Gideon; Goodman Tchernov, Beverly N.; Bookman, Revital; Taha, Nimer; Marco, Shmuel

    2016-04-01

    The Northern Gulf of Aqaba-Elat (NGAE) is the northeast extension of the Red Sea, located at the southernmost part of the Dead Sea Fault, at the transition zone between the deep en-echelon submarine basins of the Red Sea and the shallow continental basins of the Arava Valley (Israel and Jordan). We aim to characterize the top sedimentary cover across the NGAE in order to check the effect of tectonics on the sedimentary column, using high resolution grain size data and radiocarbon dating of core sediments. We analyzed 11 piston cores and 9 short cores: high resolution grain-size and radiocarbon age determinations were used to compile a 3.5-D (3.5 dimensional) model of age-depth-grain size for the top 3-5 meters of the NGAE. Two general trends of the grain size spatial distribution are observed: grains are coarsest at the NE corner of the NGAE (Aqaba coastline) and grow finer with the distance to the west on the shelf and with the distance from shore to the south. Long- and short-term accumulation rates were compiled for the entire NGAE, demonstrating a distinct E-W trend on the shelf and a NNE-SSW trend in the deep basin. The 3.5-D age-depth-grain size model conforms to- and validates the tectonic structure of the shelf detailed by previous authors. We suggest that the impact of tectonic structure of the shelf is highly significant in terms of spatial variations across the shelf, both in age of the sediment and its grain size characteristics. The temporal-spatial distribution of the grain size in the deep basin of the NGAE reveals a correlation between sediment age, dominant grain size and active tectonics: fine-grain, old sediment in the margins (Late Pleistocene, as old as >40 ka on the west margin; Early Holocene, as old as 7.5 ka, on the east margin), and Late Pleistocene sediment farther south from the dominant active diagonal fault which underlies the Elat Canyon. Young coarse sediment is present in the middle of the basin, where most of the active sediment

  14. Detrital zircon and apatite (U-Th)/He geochronology of intercalated baked sediments: A new approach to dating young basalt flows

    NASA Astrophysics Data System (ADS)

    Cooper, Frances J.; van Soest, Matthijs C.; Hodges, Kip V.

    2011-07-01

    Simple numerical models suggest that many basaltic lava flows should sufficiently heat the sediments beneath them to reset (U-Th)/He systematics in detrital zircon and apatite. This result suggests a useful way to date such flows when more conventional geochronological approaches are either impractical or yield specious results. We present here a test of this method on sediments interstratified with basalt flows of the Taos Plateau Volcanic Field of New Mexico. Nineteen zircons and apatites from two samples of baked sand collected from the uppermost 2 cm of a fluvial channel beneath a flow of the Upper Member of the Servilleta Basalt yielded an apparent age of 3.487 ± 0.047 Ma (2 SE confidence level), within the range of all published 40Ar/39Ar dates for other flows in the Upper Member (2.81-3.72 Ma) and statistically indistinguishable from the 40Ar/39Ar dates for basal flows of the Upper Member with which the studied flow is broadly correlative (3.61 ± 0.13 Ma). Given the high yield of 4He from U and Th decay, this technique may be especially useful for dating Pleistocene basalt flows. Detailed studies of the variation of (U-Th)/He detrital mineral dates in sedimentary substrates, combined with thermal modeling, may be a valuable tool for physical volcanologists who wish to explore the temporal and spatial evolution of individual flows and lava fields.

  15. Seismically induced soft-sediment deformation structures revealed by X-ray computed tomography of boring cores

    NASA Astrophysics Data System (ADS)

    Nakashima, Yoshito; Komatsubara, Junko

    2016-06-01

    X-ray computed tomography (CT) allows us to visualize three-dimensional structures hidden in boring cores nondestructively. We applied medical X-ray CT to cores containing seismically induced soft-sediment deformation structures (SSDSs) obtained from the Kanto region of Japan, where the 2011 off the Pacific coast of Tohoku Earthquake occurred. The CT images obtained clearly revealed various types of the seismically induced SSDSs embedded in the cores: a propagating sand dyke bent complexly by the preexisting geological structure, deformed laminations of fluidized sandy layers, and two types of downward mass movement (ductile downward folding and brittle normal faulting) as compensation for upward sand transport through sand dykes. Two advanced image analysis techniques were applied to the sand dyke CT images for the first time. The GrowCut algorithm, a specific digital image segmentation technique that uses cellular automata, was used successfully to extract the three-dimensional complex sand dyke structures embedded in the sandy sediments, which would have been difficult to achieve using a conventional image processing technique. Local autocorrelation image analysis was performed to detect the flow pattern aligned along the sand dykes objectively. The results demonstrate that X-ray CT coupled with advanced digital image analysis techniques is a promising approach to studying the seismically induced SSDSs in boring cores.

  16. A pervasive link between Antarctic ice core and subarctic Pacific sediment records over the past 800 kyrs

    NASA Astrophysics Data System (ADS)

    Jaccard, S. L.; Galbraith, E. D.; Sigman, D. M.; Haug, G. H.

    2010-01-01

    Recently developed XRF core-scanning methods permit paleoceanographic reconstructions on timescales similar to those of ice-core records. We have investigated the distribution of biogenic barium (Ba/Al), opal and carbonate (Ca/Al) in a sediment core retrieved from the abyssal subarctic Pacific (ODP 882, 50°N, 167°E, 3244 m) over an interval that spans the full length of the EPICA Dome C (EDC) ice-core record. Ba/Al and biogenic opal show a strong resemblance to the EDC δD and CO 2, with generally high concentrations during interglacials and lower values during ice ages of the past 800 kyrs. The sedimentary Ba/Al and biogenic opal are most easily interpreted as indicating a reduced sinking flux of organic matter from the surface ocean during cold periods. The Ba/Al maxima during peak interglacials are accompanied by transient Ca/Al peaks in these otherwise carbonate-devoid sediments, which are best explained by a deepening of the calcite lysocline, presumably due to reduced storage of respired CO 2 in the deep North Pacific. For most of the "luke-warm" interglacials noted between 420 and 750 ka in EDC, the Ba/Al peaks in ODP 882 are also lower, further strengthening the evidence for a simple physical link between global climate and the biogeochemistry of the subarctic Pacific.

  17. Provenance and flux of detrital materials in Lake Suigetsu sediment (SG12 core) and their temporal changes during the last 20 kyrs based on color and XRF data

    NASA Astrophysics Data System (ADS)

    Suzuki, Y.; Tada, R.; Nakagawa, T.; Gotanda, K.; Haraguchi, T.; Nagashima, K.; Irino, T.; Sugisaki, S.; Kojima, H.; Horiuchi, D.

    2013-12-01

    Lake Suigetsu in Central Japan is known for its annual lamination (varve) starting from 70kys ago. Extremely precise Age-depth model is established for SG06 core based on over 800 14C dates obtained on terrestrial leaf fossils and wiggle-matched to stalagmite 14C records constrained by varve counts (Staff et al., 2013). By projecting this age model to newly drilled core from the same site, we can obtain precisely age-controlled high resolution paleoenvironmental record around the Lake Suigetsu drainage. It is likely that detrital materials in Lake Suigetsu sediments have several different sources such as soil on the slopes around the lake itself, aeolian dust from inland Asia, and suspended particles supplied from Hasu river through lake Mikata, which is located immediately upstream of Lake Suigetsu and trapping most of coarse detrital grains. However, the relative contribution from each detrital source and its temporal changes are poorly known. The lack of knowledge on relative contribution of different detrital sources limits utility of detrital materials as proxies of paleo-environments. In this study, we are aiming to reconstruct the history of precipitation changes in the drainage area of Lake Suigetsu during the Holocene to explore the relationship between precipitation in the Japan Sea side of SW Japan, behavior of Asian monsoon system as an important component of the global climate system. It is well known that flux of suspended particles in rivers increases with precipitation. In order for us to be able to use the Hasu river's flux of suspended particles as the precipitation proxy, however, we first need to establish a simple and swift way to estimate the contribution of detrital materials from Hasu River flowing through Lake Mikata into Lake Suigetsu. We carried out color measurement with 5mm resolution on split half core surface of the sediment drilled in the summer of 2012(SG12), and compared these values to chemical composition data by XRF microscanner

  18. Sediment core record of global fallout and Bikini close-in fallout Pu in Sagami Bay, Western Northwest Pacific margin.

    PubMed

    Zheng, Jian; Yamada, Masatoshi

    2004-07-01

    The total 239-240Pu activity and 240Pu/239Pu atom ratio in the sediments in Sagami Bay of the western Northwest Pacific margin were investigated using ICP-MS with a shield torch system. 239+240Pu inventories in the examined sediment cores were found to be much higher than those predicted from atmospheric global fallout (42 MBq/km2) at the same latitude. In addition, elevated 240Pu/239Pu atom ratios ranging from 0.22 to 0.28 were observed in the sediment samples. On the basis of the vertical profiles of 239+240Pu and characterized 240Pu/239Pu atom ratios in a sediment core collected in the center of Sagami Bay, we identified two distinct sources of fallout Pu in the bay: the global stratospheric fallout with characteristic 240Pu/239Pu ratio of 0.18 and the transported close-in fallout derived from Bikini and Enewetak surface nuclear weapon test series in the 1950s. We propose that the Pu transportation was mainly due to oceanic processes (for example, through the North Equatorial Current and the Kuroshio Current). Using a two fallout end-member model, we find that the contribution of Bikini close-in fallout Pu ranged from 44 to 59% in Sagami Bay sediments. To the best of our knowledge, this is the first report that Pu contamination, which originated from Bikini and Enewetak nuclear weapon test series in the 1950s, has extended westwards as far as the Japanese coast. PMID:15296298

  19. Climatic Impact on Major and Trace Elements in Deltaic Core Sediments: Evidence from Muthupet Lagoon, South East Coast of India

    NASA Astrophysics Data System (ADS)

    Jayaprakash, M.; Velmurugan, P. M.; Giridharan, L.; Urban, B.

    2013-05-01

    Geochemistry of lagoon deposits provides a continuous record of climatic changes, and such core sediments at successive deeper and older layers have long been utilized for sedimentologic, and organic geochemical studies. These ecosystems provide a mechanism for trapping sediment and can act as a recorder of climatic changes via geochemical imprints. The aim of the present study is to evaluate the climatic and depositional controls in the Muthupet lagoon, Southeast coast of India, situated at the southern most end of the Cauvery delta. The down core variations of geochemical parameters and their ratios were employed to reveal the characteristics of Holocene climate and associated paleoenvironmental implications of the study area. Moderate values of the Chemical Index of Alteration (CIA) suggest intensive chemical weathering of the source rock under tropical to subtropical climatic conditions. Index of Composition Variability (ICV) values indicate low proportion of nonclay silicate minerals in these sediments. V/Cr ratio has been used as a paleo-oxygenation indicator and in the present study, the ratio V/Cr was found to be < 2 indicating oxic-depositional conditions prevailing in this lagoon. Ni/Co, Ni/V and (Cu+Mg)/Zn ratios of the sediments are evaluated and the variations are interpreted to reflect the changes in the input from the marine environment. Fe/Ti and Fe/Al ratios yields valuable information on the impact of climate changes on the sedimentation of the study areas. Na and S, indicators of paleosalinity and marine flooding have been evaluated. The increase in the concentration of Na at various depths was identified and the marine incursions were characterized.

  20. Aliphatic hydrocarbons in sediment cores from the southern basin of Lake Michigan

    SciTech Connect

    Doskey, P.V.; Andren, A.W.

    1991-10-01

    Aliphatic hydrocarbons in sediments of the southern basin of Lake Michigan have planktonic, terrigenous, and petroleum residue origins. Surficial sediments collected near the eastern shore in 60-80 m of water contained more petroleum residue and planktonic hydrocarbons and exhibited less terrigenous character than sediments collected from the deepest location in the basin. Petroleum residue inputs have increased since 1900 as evidenced by a change in the flux of an unresolved complex mixture (UCM) of hydrocarbons from 6 ng/cm{sup 2}{center_dot}yr to a flux of approximately 100 ng/cm{sup 2}{center_dot}yr in 1980. Sediment profiles of the UCM exhibited subsurface concentration maxima that may be due to reduced inputs of combustion products or feeding by oligochaetes. Profiles of n-C{sub l7} and pristane indicated that planktonic n-alkanes undergo degradation in the aerobic, mixed zone of the sediments.

  1. Core and Intact Polar Glycerol Dibiphytanyl Glycerol Tetraether Lipids of Ammonia-Oxidizing Archaea Enriched from Marine and Estuarine Sediments ▿ ¶

    PubMed Central

    Pitcher, Angela; Hopmans, Ellen C.; Mosier, Annika C.; Park, Soo-Je; Rhee, Sung-Keun; Francis, Christopher A.; Schouten, Stefan; Sinninghe Damsté, Jaap S.

    2011-01-01

    Glycerol dibiphytanyl glycerol tetraether (GDGT)-based intact membrane lipids are increasingly being used as complements to conventional molecular methods in ecological studies of ammonia-oxidizing archaea (AOA) in the marine environment. However, the few studies that have been done on the detailed lipid structures synthesized by AOA in (enrichment) culture are based on species enriched from nonmarine environments, i.e., a hot spring, an aquarium filter, and a sponge. Here we have analyzed core and intact polar lipid (IPL)-GDGTs synthesized by three newly available AOA enriched directly from marine sediments taken from the San Francisco Bay estuary (“Candidatus Nitrosoarchaeum limnia”), and coastal marine sediments from Svalbard, Norway, and South Korea. Like previously screened AOA, the sedimentary AOA all synthesize crenarchaeol (a GDGT containing a cyclohexane moiety and four cyclopentane moieties) as a major core GDGT, thereby supporting the hypothesis that crenarchaeol is a biomarker lipid for AOA. The IPL headgroups synthesized by sedimentary AOA comprised mainly monohexose, dihexose, phosphohexose, and hexose-phosphohexose moieties. The hexose-phosphohexose headgroup bound to crenarchaeol was common to all enrichments and, in fact, the only IPL common to every AOA enrichment analyzed to date. This apparent specificity, in combination with its inferred lability, suggests that it may be the most suitable biomarker lipid to trace living AOA. GDGTs bound to headgroups with a mass of 180 Da of unknown structure appear to be specific to the marine group I.1a AOA: they were synthesized by all three sedimentary AOA and “Candidatus Nitrosopumilus maritimus”; however, they were absent in the group I.1b AOA “Candidatus Nitrososphaera gargensis.” PMID:21441324

  2. Watershed erosion estimated from a high-resolution sediment core reveals a non-stationary frequency-magnitude relationship and importance of seasonal climate drivers

    NASA Astrophysics Data System (ADS)

    Gavin, D. G.; Colombaroli, D.; Morey, A. E.

    2015-12-01

    The inclusion of paleo-flood events greatly affects estimates of peak magnitudes (e.g., Q100) in flood-frequency analysis. Likewise, peak events also are associated with certain synoptic climatic patterns that vary on all time scales. Geologic records preserved in lake sediments have the potential to capture the non-stationarity in frequency-magnitude relationships, but few such records preserve a continuous history of event magnitudes. We present a 10-meter 2000-yr record from Upper Squaw Lake, Oregon, that contains finely laminated silt layers that reflect landscape erosion events from the 40 km2 watershed. CT-scans of the core (<1 mm resolution) and a 14C-dated chronology yielded a pseudo-annual time series of erosion magnitudes. The most recent 80 years of the record correlates strongly with annual peak stream discharge and road construction. We examined the frequency-magnitude relationship for the entire pre-road period and show that the seven largest events fall above a strongly linear relationship, suggesting a distinct process (e.g., severe fires or earthquakes) operating at low-frequency to generate large-magnitude events. Expressing the record as cumulative sediment accumulation anomalies showed the importance of the large events in "returning the system" to the long-term mean rate. Applying frequency-magnitude analysis in a moving window showed that the Q100 and Q10 of watershed erosion varied by 1.7 and 1.0 orders of magnitude, respectively. The variations in watershed erosion are weakly correlated with temperature and precipitation reconstructions at the decadal to centennial scale. This suggests that dynamics both internal (i.e., sediment production) and external (i.e., earthquakes) to the system, as well as more stochastic events (i.e., single severe wildfires) can at least partially over-ride external climate forcing of watershed erosion at decadal to centennial time scales.

  3. OSL dating of sediments from a mountainous river in southeastern Brazil: Late Cenozoic tectonic and climatic implications

    NASA Astrophysics Data System (ADS)

    Junior, Antônio Pereira Magalhães; Cherem, Luis Felipe Soares; Barros, Luiz Fernando de Paula; Santos, Gisele Barbosa dos

    2011-09-01

    The upper Das Velhas River basin is located in the central portion of the Quadrilátero Ferrífero in southeastern edge of São Francisco Craton, southeastern Brazil. Its drainage network has a strong lithostructural influence and mountainous river segments crossing different tectonic blocks. The neotectonic activity in this cratonic edge is associated with epirogenetic Brazilian Shield uplift and with local and regional differential movements of crustal blocks due to WNW migration of South-American plate. This process cause an intraplate transfer of tectonic efforts, forcing the reactivation of old faults (NW-SE and NE-SW) and the generation of recent ones (E-W). Using optically stimulated luminescence (OSL) dating and fluvial deposit data, this paper focuses on the late Cenozoic evolution of this mountainous river basin, relating it to tectonic and climatic forcing. Even with few records of ancient alluvial deposits as a result of intense dissection, three levels of river terraces were identified in some sites along the valley: a higher terrace level (T3), a cut-in-bedrock terrace of ~ 48 ka; an intermediate terrace level (T2) of ~ 7.5 ka; and a lower terrace level (T1), of ~ 1 ka. The T2 is found along the valley as a cut-in-bedrock terrace or as a fill terrace, and is found T1 as a cut-in-bedrock terrace or as a nested fill terrace or even overlapping T2 sediments. The diverse relation between these terraces may be related to unequal fluvial downcutting. We identified three main downcutting periods: (i) before T3; (ii) from T3 to T2, related to Late Pleistocene regional tectonics; and (iii) from T2 to T1, which was a response to tectonics and climate change in the early Holocene. These stages of more intense downcutting should be a response to uplift pulses. In the most active blocks, cut-in-bedrock terraces show a greater unevenness in relation to lower levels, while in the most stable blocks, T1 is found as a nested fill terrace or overlapping T2.

  4. Discriminating Sediment Supply versus Accommodation Controls on Foreland Basin Stratigraphic Architecture in the Book Cliffs, central Utah using Detrital Double Dating

    NASA Astrophysics Data System (ADS)

    Bartschi, N.; Saylor, J. E.; Blum, M. D.

    2014-12-01

    Middle-late Campanian strata of the Book Cliffs record the deposition of three clastic wedges in the foreland basin east of the Sevier fold-thrust belt. Variations in wedge geometries provide an opportunity to evaluate the effects of sediment supply versus accommodation on foreland basin architecture. There is an increase in eastward progradation rate between the L. and M. Castlegate Sandstone, followed by a return to slower progradation rates in the overlying Bluecastle Tongue, and Price River Formation, as well as their lateral equivalents. Rapid progradation may be caused by increased sediment supply, due either to rapid exhumation in the Sevier fold-thrust belt, or changes in the sediment source. Alternatively, reduced accommodation within the foreland basin due to uplift during initial Laramide deformation could produce the same rapid progradation. In this scenario, decreased progradation would be coincident with enhanced foreland basin subsidence and rapid sediment accumulation in the proximal foredeep. We test these hypotheses using thermo- and geochronology to double date individual detrital grains, enabling identification of changes in lag time and sediment provenance. Upsection decreases or increases in lag time correspond to increased or decreased exhumation rates, respectively, or introduction of a new upper crustal sedimentary source. We focus on 21 samples from 7 measured sections along depositional strike and dip. Samples were collected from the upper Blackhawk Formation, L. and M. Castlegate Sandstone, Bluecastle Tongue, Price River Formation, and their lateral equivalents. Initial results indicate major sediment provenance changes associated with the transition between slow and rapid wedge progradation, as well as minor provenance changes within individual wedges. There is also a significantly greater proportion of Cordilleran magmatic arc grains in distal locations than in proximal locations, interpreted as sediment mixing during transport.

  5. Sulfate reduction controlled by organic matter availability in deep sediment cores from the saline, alkaline Lake Van (Eastern Anatolia, Turkey)

    PubMed Central

    Glombitza, Clemens; Stockhecke, Mona; Schubert, Carsten J.; Vetter, Alexandra; Kallmeyer, Jens

    2013-01-01

    As part of the International Continental Drilling Program deep lake drilling project PaleoVan, we investigated sulfate reduction (SR) in deep sediment cores of the saline, alkaline (salinity 21.4‰, alkalinity 155 m mEq-1, pH 9.81) Lake Van, Turkey. The cores were retrieved in the Northern Basin (NB) and at Ahlat Ridge (AR) and reached a maximum depth of 220 m. Additionally, 65–75 cm long gravity cores were taken at both sites. SR rates (SRR) were low (≤22 nmol cm-3 day-1) compared to lakes with higher salinity and alkalinity, indicating that salinity and alkalinity are not limiting SR in Lake Van. Both sites differ significantly in rates and depth distribution of SR. In NB, SRR are up to 10 times higher than at AR. SR could be detected down to 19 mblf (meters below lake floor) at NB and down to 13 mblf at AR. Although SRR were lower at AR than at NB, organic matter (OM) concentrations were higher. In contrast, dissolved OM in the pore water at AR contained more macromolecular OM and less low molecular weight OM. We thus suggest, that OM content alone cannot be used to infer microbial activity at Lake Van but that quality of OM has an important impact as well. These differences suggest that biogeochemical processes in lacustrine sediments are reacting very sensitively to small variations in geological, physical, or chemical parameters over relatively short distances. PMID:23908647

  6. Sulfate reduction controlled by organic matter availability in deep sediment cores from the saline, alkaline Lake Van (Eastern Anatolia, Turkey).

    PubMed

    Glombitza, Clemens; Stockhecke, Mona; Schubert, Carsten J; Vetter, Alexandra; Kallmeyer, Jens

    2013-01-01

    As part of the International Continental Drilling Program deep lake drilling project PaleoVan, we investigated sulfate reduction (SR) in deep sediment cores of the saline, alkaline (salinity 21.4‰, alkalinity 155 m mEq(-1), pH 9.81) Lake Van, Turkey. The cores were retrieved in the Northern Basin (NB) and at Ahlat Ridge (AR) and reached a maximum depth of 220 m. Additionally, 65-75 cm long gravity cores were taken at both sites. SR rates (SRR) were low (≤22 nmol cm(-3) day(-1)) compared to lakes with higher salinity and alkalinity, indicating that salinity and alkalinity are not limiting SR in Lake Van. Both sites differ significantly in rates and depth distribution of SR. In NB, SRR are up to 10 times higher than at AR. SR could be detected down to 19 mblf (meters below lake floor) at NB and down to 13 mblf at AR. Although SRR were lower at AR than at NB, organic matter (OM) concentrations were higher. In contrast, dissolved OM in the pore water at AR contained more macromolecular OM and less low molecular weight OM. We thus suggest, that OM content alone cannot be used to infer microbial activity at Lake Van but that quality of OM has an important impact as well. These differences suggest that biogeochemical processes in lacustrine sediments are reacting very sensitively to small variations in geological, physical, or chemical parameters over relatively short distances. PMID:23908647

  7. Determination of Sediment Oxygen Demand in the Ziya River Watershed, China: Based on Laboratory Core Incubation and Microelectrode Measurements

    PubMed Central

    Rong, Nan; Shan, Baoqing; Wang, Chao

    2016-01-01

    A study coupling sedimentcore incubation and microelectrode measurementwas performed to explore the sediment oxygen demand (SOD) at 16 stations in the Ziya River Watershed, a severely polluted and anoxic river system in the north of China. Total oxygen flux values in the range 0.19–1.41 g/(m2·d) with an average of 0.62 g/(m2·d) were obtained by core incubations, and diffusive oxygen flux values in the range 0.15–1.38 g/(m2·d) with an average of 0.51 g/(m2·d) were determined by microelectrodes. Total oxygen flux obviously correlated with diffusive oxygen flux (R2 = 0.842). The microelectrode method produced smaller results than the incubation method in 15 of 16 sites, and the diffusive oxygen flux was smaller than the total oxygen flux. Although the two sets of SOD values had significant difference accepted by the two methods via the Wilcoxon signed-rank test (p < 0.05), the microelectrode method was shown to produce results that were similar to those from the core incubation method. The microelectrode method, therefore, could be used as an alternative method for traditional core incubation method, or as a method to verify SOD rates measured by other methods. We consider that high potential sediment oxygen demand would occur in the Ziya River Watershed when the dissolved oxygen (DO) recovered in the overlying water. PMID:26907307

  8. Determination of Sediment Oxygen Demand in the Ziya River Watershed, China: Based on Laboratory Core Incubation and Microelectrode Measurements.

    PubMed

    Rong, Nan; Shan, Baoqing; Wang, Chao

    2016-02-01

    A study coupling sedimentcore incubation and microelectrode measurement was performed to explore the sediment oxygen demand (SOD) at 16 stations in the Ziya River Watershed, a severely polluted and anoxic river system in the north of China. Total oxygen flux values in the range 0.19-1.41 g/(m²·d) with an average of 0.62 g/(m²·d) were obtained by core incubations, and diffusive oxygen flux values in the range 0.15-1.38 g/(m²·d) with an average of 0.51 g/(m²·d) were determined by microelectrodes. Total oxygen flux obviously correlated with diffusive oxygen flux (R² = 0.842). The microelectrode method produced smaller results than the incubation method in 15 of 16 sites, and the diffusive oxygen flux was smaller than the total oxygen flux. Although the two sets of SOD values had significant difference accepted by the two methods via the Wilcoxon signed-rank test (p < 0.05), the microelectrode method was shown to produce results that were similar to those from the core incubation method. The microelectrode method, therefore, could be used as an alternative method for traditional core incubation method, or as a method to verify SOD rates measured by other methods. We consider that high potential sediment oxygen demand would occur in the Ziya River Watershed when the dissolved oxygen (DO) recovered in the overlying water. PMID:26907307

  9. The Inter-Tropical Convergence Zone: A causal mechanism for Pb isotope cyclicity in Tropical Atlantic sediment cores

    NASA Astrophysics Data System (ADS)

    Abouchami, W.; Zabel, M.

    2003-04-01

    Lead isotopic compositions of bulk sediment cores from the Tropical Atlantic can be used to infer variations in the provenance of terrigenous input to the Tropical Atlantic during Pleistocene climate cycles. Pb isotope data were obtained using the triple spike method (Galer, 1999) on bulk sediments cores and cover the last six Marine Isotope Stages. The 200-ka high precision (2σ ˜100 ppm) Pb isotope records of the Ceará Rise (Western Atlantic, core GeoB1523-1, 3^o49'N, 41^o37'W, 3292 m) and Sierra Leone Rise (Eastern Atlantic, core GeoB2910-1, 4^o50'N, 21^o03'W, 2703 m) cores show a clear glacial-interglacial cyclicity, reflected by alternating unradiogenic Pb and radiogenic Pb. Changes in the relative proportions of the glacial (unradiogenic) and interglacial (radiogenic) Pb source(s) can be explained by changes in the erosional regime (chemical vs. physical) as a function of prevailing climate, combined with different mechanisms of Pb transport to the oceans (predominantly eolian in the Eastern Atlantic vs. riverine in the Western Atlantic). We interpret these regional changes as reflecting shifts in the mean latitude of the Inter-Tropical Convergence Zone that affects the hydrological cycle over South America and the wind systems over Africa. Our results strongly favor an increase in winter wind transport (rather than glacial hyper aridity) as the cause of enhanced glacial terrigenous fluxes observed in the Tropical Atlantic (Ruddiman, 1997). The two Atlantic Pb isotopic records exhibit strong correlations with Pleistocene sea level fluctuations, providing evidence for global teleconnection between tropical records and high latitude climate. Galer, S.J.G. (1999). Optimal double and triple spiking for high precision lead isotopic measurements. Chem. Geol. 154, 255-274. Ruddiman, W. F. (1997). Tropical Atlantic terrigenous fluxes since 25,000 yrs B.P., Mar. Geol., 136, 189-207.

  10. Chemical quality of sediment cores from the Laguna Madre, Laguna Atascosa and Arroyo Colorado, Texas

    USGS Publications Warehouse

    Van Metre, Peter C.

    1999-01-01

    Many contaminants introduced into the environment by human activities are hydrophobic, meaning they are relatively insoluble in water and, thus, are associated primarily with sediments. These contaminants include the organochlorine pesticides DOT and chlordane, polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) from industrial facilities and urban areas, and heavy metals such as arsenic, lead, mercury, and zinc. Understanding the occurrence of these contaminants in the environment requires sampling the sediments where the contaminants might be detected.

  11. Magnetic fingerprint in marine sediments: clues from cultivated Magnetovibrio blakemorei and recent cores from Brazilian Coast

    NASA Astrophysics Data System (ADS)

    Jovane, L.; Florindo, F.; Bazylinski, D. A.; Pellizari, V. H.; Brandini, F. P.; de Almeida, L. A.; Carneiro, F. R.; Braga, E. D.; Lins, U.

    2013-12-01

    The magnetic properties (first order reversal curves, ferromagnetic resonance and decomposition of saturation remanent magnetization acquisition) of Magnetovibrio blakemorei strain MV-1, a marine magnetotactic bacterium, differ from those of other magnetotactic species from sediments deposited in lakes and marine habitats previously studied. This finding suggests that magnetite produced by some magnetotactic bacteria retains magnetic properties in relation to the crystallographic structure of the magnetic phase produced and thus might represent a 'magnetic fingerprint' for a specific magnetotactic bacterium. The technique used to determine this fingerprint is a non-destructive, new technology that might allow for the identification and presence of specific species or types of magnetotactic bacteria in certain environments such as sediment. We also show some preliminary results on the biogeochemical factors that control magnetotactic bacterial populations, documenting the environment and the preservation of bacterial magnetite, which dominates the palaeomagnetic signal throughout recent sediments from Brazilian Coast. We searched for magnetotactic bacteria in order to understand the ecosystems and environmental change related to their presence in sediments. We focused on studying the environmental conditions that allow for the presence of magnetotactic bacteria and magnetosomes in sediments including determining magnetotactic bacterial populations in marine settings, measuring crucial nutrient availability in the water column and in sediments, and examining particulate delivery to the seafloor.

  12. Characterization of Fundamental Luminescence Properties of the Mars Soil Simulant JSC Mars-1 and Their Relevance to Absolute Dating of Martian Eolian Sediments

    NASA Astrophysics Data System (ADS)

    Lepper, Kenneth; McKeever, Stephen W. S.

    2000-04-01

    This report explores the potential for luminescence dating techniques to provide absolute age determinations of eolian sediments on the surface of Mars, including those incorporated in the martian polar ice caps. Fundamental thermally and optically stimulated luminescence properties of bulk samples of JSC Mars-1 soil simulant are reported and their relevance to the development of dating procedures is discussed. The radiation-induced luminescence signals (both thermoluminescence, TL, and optically stimulated luminescence, OSL) from JSC Mars-1 are found to have a wide dynamic dose-response range, with the luminescence increasing linearly to the highest doses used (936 Gy), following irradiation with 90Sr/ 90Y beta particles. The signals are also susceptible to solar resetting, with the OSL signals decreasing to <10% of their original levels within the first 20 min of exposure to sunlight. The TL signal also decays rapidly, being reduced to ˜15% within the first 20 min, but reaches a stable, nonzero level at long bleaching times. Neither the TL nor the OSL signals exhibit fading (i.e., loss of signal after irradiation before TL or OSL readout), nor do they exhibit significant sensitivity changes upon repeated irradiation and readout. These three properties (wide dynamic range, solar bleaching, and signal stability) form a stable base for future investigation of the material for luminescence dating and form a preliminary step toward development of dating protocols for terrestrial analogs of Mars surface materials. We conclude that luminescence dating, properly developed, holds the potential to be a valuable tool for absolute dating of martian eolian sediments

  13. Use of radiometric (Cs-137, Pb-210), geomorphic, and stratigraphic techniques to date recent oxbow sediments in the Rio Puerco drainage Grants uranium region, New Mexico

    SciTech Connect

    Popp, C.J.; Dehn, M. ); Hawley, J.W.; Love, D.W. )

    1988-06-01

    In the absence of historic geochemical baseline data for the Grants uranium region, environmental changes resulting from uranium mine-mill activities can be determined only by indirect methods. A methodology for determining the age of recent sediments in streams draining the region has been established based on combined geomorphic, stratigraphic, and radiometric dating techniques. Because clay-rich sediments retain possible radionuclides and heavy metals derived from mineralization and mined sources, sample sites which contain fine-grained deposits that both predate and postdate mine-mill activity were located in abandoned-channel segments (oxbows) of major streams draining the eastern Grants uranium region. Aerial photographs (and derivative maps) taken between 1935 and 1971 provided the historical and geomorphic documentation of approximate dates of oxbow formation and ages of alluvial fills in the abandoned-channel segments. Pits were dug at these oxbow sites to determine stratigraphy and composition of the deposits. Samples collected from pit walls and auger holes below the pits were subjected to radiometric analysis by gamma ray spectrometry for the artificial radionuclide Cs-137 and the natural radionuclide Pb-210 as well as other U-238 and Th-232 daughters. Because of the dynamic nature of the system, absolute dating with Cs-137 was not possible but samples could be dated as either pre- or post-1950. The 1950 date is important because it marked the beginning of the uranium exploitation in the region. The Pb-210 dating was not possible because background Pb-210 was very high relative to fallout Pb-210.

  14. Magnetotactic bacteria in marine sediments: clues from recent cores from Brazilian Coast

    NASA Astrophysics Data System (ADS)

    Jovane, L.; Pellizari, V. H.; Brandini, F. P.; Braga, E. D. S.; Freitas, G. R.; Benites, M.; Rodelli, D.; Giorgioni, M.; Iacoviello, F.; Ruffato, D. G.; Lins, U.

    2014-12-01

    The magnetic properties (first order reversal curves, ferromagnetic resonance and decomposition of saturation remanent magnetization acquisition) of marine magnetotactic bacteria, in conjunction with geophysical, geochemical and oceanographic data from the Brazilian Coast, provide interesting insights regarding the primary productivity distribution in oceans. This finding suggests that magnetite produced by some magnetotactic bacteria retains magnetic properties in relation to the crystallographic structure of the magnetic phase produced and thus might represent a "magnetic fingerprint" for the presence of magnetotactic bacteria. The use of those magnetic properties is a non-destructive, new technology that might allow for the identification and presence of specific species or types of magnetotactic bacteria in certain environments such as sediment. We will also show some preliminary results on the biogeochemical factors that control magnetotactic bacterial populations, documenting the environment and the preservation of bacterial magnetite, which dominates the palaeomagnetic signal throughout recent sediments from Brazilian Coast. We searched for magnetotactic bacteria in order to understand the ecosystems and environmental change related to their presence in sediments. We studied magnetotactic bacterial concentration and geophysical, geochemical and oceanographic results in marine settings measuring crucially nutrients availability in the water column and in sediments, on particulate delivery to the seafloor, to understand the environmental condition that allow the presence of magnetotactic bacteria and magnetosomes in sediments.

  15. The Comparative Study of Paleoenvironmental Proxies from 3 Sediment Cores Sampled from Lake Erie at 1988, 1991 and 2003

    NASA Astrophysics Data System (ADS)

    Lu, Y.; Meyers, P. A.; Brian, E. J.; Robbins, J. A.

    2006-05-01

    The oxygen isotopic composition of calcium carbonate in hardwater lakes reflect the impacts from meteorological factors whereas the carbon and nitrogen isotopes indicate the changes of biological productivity in the lake. However, the fidelity of these proxies in recording paleoenvironment information can be biased by the post-deposition diagenesis. We have compared the isotopic contents and the mass accumulation rates of organic carbon and calcium carbonate in sediment cores collected in 1988, 1991, and 2003 from the same location in Lake Erie to each other and to meteorological records beginning in 1895. Eutrophication accelerated calcite dissolution, but isotopic proxies are preserved. The comparison of paleoenvironmental histories concurrently interpreted from the there cores has provided interesting insights into early diagenesis, carbon dynamics and past depositional environments in Lake Erie. The geochemical proxies also reflect significant impacts from twentieth century urbanization.

  16. Holocene climate change in Newfoundland reconstructed using oxygen isotope analysis of lake sediment cores

    NASA Astrophysics Data System (ADS)

    Finkenbinder, Matthew S.; Abbott, Mark B.; Steinman, Byron A.

    2016-08-01

    Carbonate minerals that precipitate from open-basin lakes can provide archives of past variations in the oxygen isotopic composition of precipitation (δ18Oppt). Holocene δ18Oppt records from the circum- North Atlantic region exhibit large fluctuations during times of rapid ice sheet deglaciation, followed by more stable conditions when interglacial boundary conditions were achieved. However, the timing, magnitude, and climatic controls on century to millennial-scale variations in δ18Oppt in northeastern North America are unclear principally because of a dearth of paleo-proxy data. Here we present a lacustrine sediment oxygen isotope (δ18O) record spanning 10,200 to 1200 calendar years before present (cal yr BP) from Cheeseman Lake, a small, alkaline, hydrologically open lake basin located in west-central Newfoundland, Canada. Stable isotope data from regional lakes, rivers, and precipitation indicate that Cheeseman Lake water δ18O values are consistent with the isotopic composition of inflowing meteoric water. In light of the open-basin hydrology and relatively short water residence time of the lake, we interpret down-core variations in calcite oxygen isotope (δ18Ocal) values to primarily reflect changes in δ18Oppt and atmospheric temperature, although other factors such as changes in the seasonality of precipitation may be a minor influence. We conducted a series of climate sensitivity simulations with a lake hydrologic and isotope mass balance model to investigate theoretical lake water δ18O responses to climate change. Results from these experiments suggest that Cheeseman Lake δ18O values are primarily controlled by temperature and to a much lesser extent, the seasonality of precipitation. Increasing and more positive δ18Ocal values between 10,200 and 8000 cal yr BP are interpreted to reflect the waning influence of the Laurentide Ice Sheet on atmospheric circulation, warming temperatures, and rapidly changing surface ocean δ18O from the input of

  17. Sediment input pathways from North American highlands to the Gulf of Mexico based on detrital zircon U-Pb and U-Th/He dating

    NASA Astrophysics Data System (ADS)

    Xu, J.; Snedden, J.; Stockli, D. F.; Fulthorpe, C.

    2014-12-01

    The lower Miocene is a period of significant sediment input to the Gulf of Mexico (GOM) Basin that accompanied tectonic and climatic changes in North America. However, the resulting sediment pathways from continental upland sources to basinal sink remain poorly constrained. We employ detrital zircon (DZ) U-Pb and (U-Th)/He double dating to define both basement provenance and the exhumation histories of detrital source regions. We have collected samples from outcrops across the northern Gulf, from Texas to Florida, in order to discriminate sediment pathways. Most of our data show a mixture of source terranes, including Oligocene volcanic centers, Cordilleran Arc, Laramide uplifts, Grenville, Mid-Continent, Yavapai-Mazatzal, and Appalachian-Ouachita as major provinces and Wyoming and Superior regions as minor provinces. However, major DZ age peaks vary greatly between different samples, providing a means to differentia drainage systems. Five major sediment input pathways are defined: the Paleo-Rio Grande, Paleo-Red, Paleo-Mississippi and Paleo-Tennessee rivers and a local river system in Florida draining from Appalachians. The Paleo-Rio Grande and Paleo-Red rivers show a significant sediment input from Oligocene volcanic centers, Laramide uplift regions and the Cordilleran Arc, whereas the Paleo-Tennessee River received most of its sediments from Appalachian-Ouachita and Grenville basement. The Paleo-Mississippi River lies within a transitional zone between western and eastern North American drainage systems. By integrating (U-Th)/He ages we can further distinguish first order volcanic zircons from recycled zircons. This can increase the ability to discriminate different drainage systems because the recycled zircons come from source terranes that are different from the original basement in which they formed. For example, two different Grenville-age zircon sources are differentiated by our U-Pb and (U-Th)/He ages. Sediments in Texas show a mixed zircon source from

  18. Spatial Variations in Archaeal Lipids of Surface Water and Core-Top Sediments in the South China Sea and Their Implications for Paleoclimate Studies▿†

    PubMed Central

    Wei, Yuli; Wang, Jinxiang; Liu, Jie; Dong, Liang; Li, Li; Wang, Hui; Wang, Peng; Zhao, Meixun; Zhang, Chuanlun L.

    2011-01-01

    The South China Sea (SCS) is the largest marginal sea of the western Pacific Ocean, yet little is known about archaeal distributions and TEX86-based temperatures in this unique oceanic setting. Here we report findings of abundances in both core lipids (CL) and intact polar lipids (IPL) of Archaea from surface water (CL only) and core-top sediments from different regions of the SCS. TEX86-derived temperatures were also calculated for these samples. The surface water had extremely low abundances of CL (average of 0.05 ± 0.13 ng/liter; n = 75), with higher values present in regions where upwelling is known to occur. The core-top sediments had CL values of 0.1 to 0.9 μg/g, which are on the low end of CL concentrations reported for other marine sediments and may reflect the oligotrophic nature of the open SCS. The IPL of Archaea accounted for 6 to 36.4% of total lipids (CL plus IPL), indicating that the majority of archaeal lipids in core-top sediments were derived from nonliving cells. The TEX86-based temperatures of surface water were overall lower than satellite-based sea surface temperatures or CTD-measured in situ temperatures. The core-top sediment samples, however, had TEX86 temperatures very close to the mean annual sea surface temperatures, except for samples with water depths of less than 100 m. Our results demonstrated low and heterogeneous distributions of archaeal lipids in surface water and core-top sediments of the SCS, which may reflect local or regional differences in productivity of Archaea. While TEX86-based temperatures for core-top marine sediments at deep water depths (>100 m) generally reflected mean annual sea surface temperatures, TEX86 temperatures in surface water varied basin wide and underestimated sea surface temperatures in most locations for the season when surface water samples were collected. PMID:21890672

  19. Spatial Variations in Archaeal Lipids of Surface Water and Core-Top Sediments in the South China Sea: Implications for Paleoclimate Studies

    NASA Astrophysics Data System (ADS)

    Wei, Y.; Wang, J.; Liu, J.; Dong, L.; Li, L.; Wang, H.; Wang, P.; Zhao, M.; Zhang, C.

    2011-12-01

    The South China Sea (SCS) is the largest marginal sea of the western Pacific Ocean; yet, little is known about archaeal distributions and TEX86-based temperatures in this unique oceanic setting. Here we report findings of abundances in both core lipids (CL) and intact polar lipids (IPL) of Archaea from surface water (CL only) and core-top sediments from different regions of the SCS. TEX86-derived temperatures were also calculated for these samples. The surface water had extremely low abundances of CL (average 0.05±0.13 ng/L; n = 75) with higher values present in regions where upwelling is known to occur. The core-top sediments had CL values of 0.1 to 0.9 g/g, which are in the low end of CL concentrations reported for other marine sediments and may reflect the oligotrophic nature of the open SCS. The IPL of Archaea accounted for 6-36.4% of total lipids (CL+IPL), indicating that the majority of archaeal lipids in core-top sediments were derived from nonliving cells. The TEX86-based temperatures of surface water were overall lower than satellite-based sea surface temperatures or CTD-measured in situ temperatures. The core-top sediment samples, however, had TEX86 temperatures very close to the mean annual sea surface temperatures except for samples with water depth shallower than 100 m. Our results demonstrated low and heterogeneous distributions of archaeal lipids in surface water and core-top sediments of the SCS, which may reflect the local or regional differences in productivity of Archaea. While TEX86-based temperatures for core-top marine sediments at deep water depths (>100 m) generally reflected mean annual sea surface temperatures, TEX86 temperatures in surface water varied basin wide and underestimated sea surface temperatures in most locations for the season when surface water samples were collected.

  20. Holocene lake level changes at a lowland lake in northeastern Germany inferred from acoustic sub-bottom profiling and a transect of sediment cores

    NASA Astrophysics Data System (ADS)

    Dietze, Elisabeth; Zawiska, Izabela; Słowiński, Michał; Brauer, Achim

    2015-04-01

    Holocene lake level changes were studied at Lake Fürstenseer See, a typical lake with complex basin morphology in northeastern German sandur area. An acoustic sub-bottom profile and a transect of four long sediment cores in the deepest lake sub-basin were analyzed. The cores were dated with AMS-14C and correlated with multiple proxies (sediment facies, μ-XRF, macrofossils, subfossil Cladocera, carbonate isotopes). At sites in 10 and 15 m water depth, shifts in the sand-mud boundary, i.e. sediment limit sensu Digerfeldt (1986), allowed quantitative estimates of the absolute amplitude of lake level changes. At sites in 20 and 23 m water depth, the negative correlation of Ca and Ti reflect lake level changes qualitatively. During high lake stands massive organic muds were deposited. Lower lake levels isolated the lake sub-basins which reduced the overall water circulation and lead to the deposition of Ti-poor carbonate muds. Furthermore, macrofossil and subfossil Cladocera analyses were used as proxies for the intense reworking at the slope and for the trophic state of the lake, respectively. Lake levels were up to 4 m higher, e.g. around 5000 cal. yrs BP and during the Medieval time period (see also Kaiser et al., 2014). During the early to mid-Holocene (between 9400 and 6400 cal. yrs BP), Lake Fürstenseer See fluctuated at an at least 3-m lower level. Further water level changes can be related to known climatic events and regional human impact. Digerfeldt, G., 1986. Studies on past lake-level fluctuations. In Berglund, B. (ed.), Handbook of Holocene Palaeoecology and Palaeohydrology: 127-144. John Wiley & Sons, New York. Kaiser, K., Küster, M., Fülling, A., Theuerkauf, M., Dietze, E., Graventein, H., Koch, P.J., Bens, O., Brauer, A., 2014. Littoral landforms and pedosedimentary sequences indicating late Holocene lake-level changes in northern central Europe ' A case study from northeastern Germany. Geomorphology 216, 58-78.

  1. Approximation methods for the solution of inverse problems in lake and sea sediment core analysis

    NASA Technical Reports Server (NTRS)

    Banks, H. T.; Rosen, I. G.

    1985-01-01

    A theoretical model employing one-dimensional (depth) transport equations to describe vertical redistribution of ocean-floor and lake-floor sediment (particulates, volcanic ash, microtektites, or radioactive tracers) by episodic and nonepisodic events including bioturbation is developed analytically and demonstrated. The principles underlying the model are explained; the model equations are derived; the inverse problem of identifying the depth-dependent bioturbation coefficient is addressed; two approximation theorems are presented; and numerical results for two sample problems are presented graphically. It is suggested that compatification, porosity effects, and depth-dependent sedimentation be taken into account when formulating future models.

  2. Improved stratigraphic dating at a low accumulation Alpine ice core through laser ablation trace element profiling at sub-mm depth resolution

    NASA Astrophysics Data System (ADS)

    Bohleber, Pascal; Spaulding, Nicole; Mayewski, Paul; Sneed, Sharon; Handley, Mike; Erhardt, Tobias; Wagenbach, Dietmar

    2015-04-01

    The small scale Colle Gnifetti glacier saddle (4450 m asl, Monte Rosa region) is the only ice core drilling site in the European Alps with a net accumulation low enough to offer multi-millennia climate records. However, a robust interpretation of such long term records (i.e. mineral dust, stable water isotopes) at the Colle Gnifetti (CG) multi core array is strongly challenged by depositional noise associated with a highly irregular annual layer stratigraphy. In combination with a relatively large vertical strain rate and rapid layer thinning, annual layer counting gets increasingly ambiguous as of approximately 100 years. In addition, this prevents clear attribution of likely volcanic horizons to historical eruption dates. To improve stratigraphic dating under such intricate conditions, we deployed laser ablation (LA) ICP-MS at sub-mm sample resolution. We present here the first LA impurity profiles from a new Colle Gnifetti ice core drilled 73 m to bedrock in 2013 at a site where the net snow accumulation is around 20 cm w.e. per year. We contrast the LA signal variability (including Ca, Fe, Na) to continuous flow analyses (CFA) records at cm-resolution (Ca, Na, melt water conductivity, micro- particle) recorded over the whole core length. Of special concern are the lower 28 m to bedrock, which have been continuously profiled in LA Ca, thus offering the direct comparison of Ca-signals between CFA and LA. By this means, we first validate at upper depths LA based annual layer identification through agreement with CFA based counting efforts before demonstrating the LA based counting still works at depths where CFA derived annual layers become spurious since embedded in strong, multi-year cycles. Finally, LA ice core profiling of our CG core has potential for not only dating improvement but also reveals benefits in resolving highly thinned basal ice sections including accounting for micro-structural features such as grain boundaries.

  3. Paleomagnetic record of a marine sediment core from eastern offshore of Taiwan over the past 7,500 years

    NASA Astrophysics Data System (ADS)

    Huang, Y.; Lee, T.

    2013-12-01

    To study the Holocene geomagnetic field behavior, we performed a series of paleomagnetic experiments, including measurements of magnetic susceptibility (χ), natural remanent magnetization (NRM), anhysteretic remanent magnetization (ARM), and isothermal remanent magnetization (IRM), to a marine sediment core OR1-715-21 obtained from eastern offshore of Taiwan during the OR1-715 cruise. The analyzed magnetic properties show that the remanent magnetization (RM) carriers of the core are uniformly dominated by single-domain (SD) and pseudo-single-domain (PSD) magnetite, suggesting a suitable material for relative paleointensity (RPI) determination. Also the stable and well defined characteristic remanent magnetization (ChRM) indicates the reliable determination of the paleomagnetic direction (inclination and declination). Virtual dipole moment (VDM) is further calculated based on these reliable RPI and paleo direction data. The VDM variability of the study compares well to the CALS10K model (a continuous model of archaeomagnetic and lake sediment data for the past 10,000 years). Outcomes of the study imply the domination of the magnetic dipole field in Taiwan area over the past 7,500 years.

  4. Accumulation and partitioning of seven trace metals in mangroves and sediment cores from three estuarine wetlands of Hainan Island, China.

    PubMed

    Qiu, Yao-Wen; Yu, Ke-Fu; Zhang, Gan; Wang, Wen-Xiong

    2011-06-15

    Trace metals in mangrove tissues (leaf, branch, root and fruit) of nine species and sediments of ten cores collected in 2008 from Dongzhai Harbor, Sanya Bay and Yalong Bay, Hainan Island, were analyzed. The average concentrations of Cu, Pb, Zn, Cd, Cr, Hg and As in surface sediments were 14.8, 24.1, 57.9, 0.17, 29.6, 0.08 and 9.7 μg g(-1), whereas those in mangrove tissues were 2.8, 1.4, 8.7, 0.03, 1.1, 0.03, and 0.2 μg g(-1), respectively. Compared to those from other typical mangrove wetlands of the world, the metal levels in Hainan were at low- to median-levels, which is consistent with the fact that Hainan Island is still in low exploitation and its mangroves suffer little impact from human activities. Metal concentrations among different tissues of mangroves were different. In general, Zn and Cu were enriched in fruit, Hg was enriched in leaf, Pb, Cd and Cr were enriched in branch, and As was enriched in root. The cycle of trace metals in mangrove species were estimated. The biota-sediment accumulation factors (BSAFs) followed the sequence of Hg (0.43)>Cu (0.27)>Cd (0.22)>Zn (0.17)>Pb (0.07)>Cr (0.06)>As (0.02). PMID:21501926

  5. Origin and vertical variation of the bound fatty acids in core sediments of Lake Dianchi in Southwest China.

    PubMed

    Wang, Lifang; Wu, Fengchang; Xiong, Yongqiang; Fang, Jidun

    2013-04-01

    Based on the molecular distribution of bound fatty acid (BFA) compound classes in core sediments of Lake Dianchi combined with the compound-specific δ(13)C values of the straight-chain BFAs, origin and vertical changes of organic matters in the sediments were investigated. The results indicated a significant change of BFA sources over the past 700 years. Contrast to the low concentrations of the terrestrial BFAs, the abundance of BFAs derived from the plankton/bacteria in the top sections (1944-recent) was more than 80%. The increasing proportions of the branched and unsaturated BFAs in total fatty acids were closely correlated with the heavy eutrophication and the frequent algal blooms in the decades. Furthermore, the positive shift of δ (13)C of C16 and C18 (~2‰) in the upper section might be an indicator of the excess phytoplankton productivity. However, it was found that the plankton/bacteria-derived BFAs were more easily degraded during the early diagenetic process. The special compound carbon isotopic compositions of the long straight-chain BFAs (C24 and C26) in the sediments showed a depletion of heavier δ (13)C values (ca. -30‰) in the midsections (1559-1787), reflecting a relatively growing contribution of C3 plants to C4 plants or that C4 plant growth was inhibited in cold and arid climates during the period. PMID:22903813

  6. Paleoenvironmental records from newly recovered sediment cores at the southeast margin of the Salar de Atacama, Chile

    NASA Astrophysics Data System (ADS)

    Boutt, D. F.; Munk, L. A.; Hynek, S. A.; Corenthal, L.; Huff, H. A.

    2014-12-01

    A suite of new cores recovered from recent boreholes in the southeastern margin of the Salar de Atacama, Chile span a modern environmental gradient from distal alluvial fans, groundwater discharge marshes, sulfate-rich playas, saline lagoons, and the halite nucleus of the salar. These same environments are preserved as stratigraphic records of environmental change in the cores. Cores from the salar nucleus are dominated by halite, and similarly alluvial cores provide a poor paleoenvironmental record. However, the cores from the transition zone between the salar margin and the halite nucleus document alluvial, lagoonal, and evaporite environments. Cores near the halite nucleus record inter-bedded carbonate, gypsum, and halite. Finely laminated carbonates inter-bedded with cm-thick halite beds are a target for U-series geochronology. Cores near modern lagoons contain 2-6 m thick diatomites in addition to microbially-mediated carbonate, organic-rich mud, and minor alluvium. The uppermost 20 cm of diatomite deposits are commonly rooted with vascular plant material which is being processed for 14C geochronology. Ignimbrite and tephra deposits are also encountered and will provide important chronological control. The presence and absence of the 3.5-4.0 Ma Tucucaro ignimbrite in various cores documents a complex pattern of subsidence near the salar margin, some areas have accumulated little sediment since its deposition while in other areas the cores likely record only late Pleistocene deposition. Preliminary interpretations of the stratigraphic records within a paleohydrologic context are tenable. The specific control on this paleohydrologic record is likely to be a combination of increased inflow due to wetter climates and migration of the freshwater/brine interface which underlies the margins of the Salar de Atacama. Stratigraphic variations in the lithium content of evaporite minerals is being explored as a potential indicator of water balance. Lithium concentrations

  7. Distribution and possible source of trace elements in the sediment cores of a tropical macrotidal estuary and their ecotoxicological significance.

    PubMed

    Chatterjee, M; Silva Filho, E V; Sarkar, S K; Sella, S M; Bhattacharya, A; Satpathy, K K; Prasad, M V R; Chakraborty, S; Bhattacharya, B D

    2007-04-01

    The paper presents the first document regarding concentration, distribution and possible sources of selected trace elements (Cu, Fe, Mn, Zn, Cr, Co, Ni, Pb, Al, B and Ba) in core sediments (<63 micro particle size) from the lower stretch of Hugli (Ganges) estuary, northeast coast of Bay of Bengal by ICP-AES and EDXRF to evaluate geochemical processes influencing their distribution and possible environmental consequences. The levels of elements showed a wide range of variations in different core depths, in upper and lower intertidal zones as well as among three sampling stations. The most interesting feature of the study is the downward increase of concentrations of majority of the elements reaching overall maximum values at a depth of 20-28 cm in upper littoral zone of the site located in the extreme downstream stretch of the estuary. Values of organic carbon showed very strong positive correlations with most of the elements as revealed by correlation matrix (r) values. The interelemental relationship revealed the identical behavior of element during its transport in the estuarine environment. The overall variation in concentration can be attributed to differential discharge of untreated effluents originating from industrial, agricultural, and aquacultural sources as well as from domestic sewage along with the fishing and boating activities. The resulting compositional dataset was tested by principal component analyses and cluster analyses. Pollution load index (PLI) and index of Geoaccumulation (Igeo) revealed overall low values but the enrichment factors (EFs) for Pb were typically high for all the stations. The mean concentrations of Zn and to some extent Cu exceeded the Effects Range-Low (ER-L) values in the majority of the cases indicating that there may be some ecotoxicological risk to organisms living in sediments. The concentration of the trace elements reported in this work is useful as baselines for comparison in future sediment quality studies. PMID

  8. Climatic Impact on Major and Trace Elements in Deltaic Core Sediments: Evidence from Muthupet Lagoon, se Coast of India

    NASA Astrophysics Data System (ADS)

    Jayaprakash, M.; Urban, B.; Murugan, P. M. V.; Dharan, L.; Seshachalam, S.; Jonathan, M.

    2013-12-01

    Geochemistry of lagoon deposits provides a continuous record of climatic changes, and such core sediments at successive deeper and older layers have long been utilized for sedimentologic and organic geochemical studies. These ecosystems present a mechanism for trapping sediment and therefore record climatic changes in the form of geochemical imprints. The aim of the present study is to evaluate the climatic and depositional controls in the Muthupet lagoon, situated at the southern most end of the Cauvery delta, south east India. The variations of geochemical parameters with depth and their ratios were employed to reveal the characteristics of Holocene climate and associated paleoenvironmental implications of this region. Moderate values of the Chemical Index of Alteration (CIA) suggest intermediate chemical weathering of the source rock under tropical to subtropical climatic conditions. Index of Composition Variability (ICV) values indicate low proportion of non clay silicate minerals in these sediments. V/Cr ratio has been used as a paleo-oxygenation indicator and in the present study, the ratio V/Cr was found to be < 2 indicating oxic-depositional conditions prevailing in this lagoon. Fe/Ti and Fe/Al ratios reveal valuable information on the impact of climate changes on the sedimentation in the study area. Na and S, indicators of paleosalinity and marine flooding were evaluated. The increase in concentration of Na at various depths was identified and marine incursions characterized. Abrupt changes in the values at certain depths were directly related to major climatic events using the available rainfall and 210Pb data. Key words: Climate change, Weathering Pattern, Muthupet Mangroves, SE coast of India. Location map of the study area

  9. Magnetostratigraphy of a greigite-bearing core from the South Yellow Sea: Implications for remagnetization and sedimentation

    NASA Astrophysics Data System (ADS)

    Liu, Jianxing; Shi, Xuefa; Liu, Qingsong; Ge, Shulan; Liu, Yanguang; Yao, Zhengquan; Zhao, Quanhong; Jin, Chunsheng; Jiang, Zhaoxia; Liu, Shengfa; Qiao, Shuqing; Li, Xiaoyan; Li, Chuanshun; Wang, Chunjuan

    2014-10-01

    Sediments from the continental shelf are sensitive to sea level, climatic changes, and local tectonic history. In this study, we carried out a high-resolution magnetostratigraphic investigation on the longest core (NHH01, 125.64 m) recovered from the South Yellow Sea (SYS). An abnormal interval dominated by negative inclinations was discovered by applying alternating field demagnetization (AFD) on samples from a greigite-bearing layer (44.90-51.80 m). In contrast, the inclinations of most greigite-bearing samples changed from negative to positive when heated to ~360°C. This strongly indicates that this inclination anomaly revealed by the AFD alone is not a true negative subchron. After neglecting the effects of greigite-bearing layers, the straightforward correlation of the interpreted magnetostratigraphy defines the Matuyama-Brunhes boundary (781 ka) and the Jaramillo top (990 ka) at 68.64 m and 101.54 m, respectively. The linearly extrapolated basal age of the core is ~1.10 Ma. In addition, several short-lived inclination anomalies can be tentatively assigned to magnetic excursions, which indicates that the sedimentation could be continuous even at the millennial time scale at depth intervals bracketing these fast geomagnetic events. Moreover, the excellent correspondence between clay content variations of the core and the marine oxygen isotope record indicates the potential of clay content as a paleoclimatic proxy in the studied region in the past ~1 Ma. In brief, our study provides not only a robust age model in the SYS but also a methodological guide for paleomagnetic studies in continental shelf region.

  10. Vertical profile, source apportionment, and toxicity of PAHs in sediment cores of a wharf near the coal-based steel refining industrial zone in Kaohsiung, Taiwan.

    PubMed

    Chen, Chih-Feng; Chen, Chiu-Wen; Ju, Yun-Ru; Dong, Cheng-Di

    2016-03-01

    Three sediment cores were collected from a wharf near a coal-based steel refining industrial zone in Kaohsiung, Taiwan. Analyses for 16 polycyclic aromatic hydrocarbons (PAHs) of the US Environmental Protection Agency priority list in the core sediment samples were conducted using gas chromatography-mass spectrometry. The vertical profiles of PAHs in the core sediments were assessed, possible sources and apportionment were identified, and the toxicity risk of the core sediments was determined. The results from the sediment analyses showed that total concentrations of the 16 PAHs varied from 11774 ± 4244 to 16755 ± 4593 ng/g dry weight (dw). Generally, the vertical profiles of the PAHs in the sediment cores exhibited a decreasing trend from the top to the lower levels of the S1 core and an increasing trend of PAHs from the top to the lower levels of the S2 and S3 cores. Among the core sediment samples, the five- and six-ring PAHs were predominantly in the S1 core, ranging from 42 to 54 %, whereas the composition of the PAHs in the S2 and S3 cores were distributed equally across three groups: two- and three-ring, four-ring, and five- and six-ring PAHs. The results indicated that PAH contamination at the site of the S1 core had a different source. The molecular indices and principal component analyses with multivariate linear regression were used to determine the source contributions, with the results showing that the contributions of coal, oil-related, and vehicle sources were 38.6, 35.9, and 25.5 %, respectively. A PAH toxicity assessment using the mean effect range-median quotient (m-ERM-q, 0.59-0.79), benzo[a]pyrene toxicity equivalent (TEQ(carc), 1466-1954 ng TEQ/g dw), and dioxin toxicity equivalent (TEQ(fish), 3036-4174 pg TEQ/g dw) identified the wharf as the most affected area. The results can be used for regular monitoring, and future pollution prevention and management should target the coal-based industries in this region for pollution reduction

  11. Determining the controls on δ13C of sedimentary organic matter in Lake Tiefer See (NE Germany) - an integration of sediment cores and monitoring data

    NASA Astrophysics Data System (ADS)

    Dräger, Nadine; Kienel, Ulrike; Groß-Schmölders, Miriam; Plessen, Birgit; Brauer, Achim

    2016-04-01

    The carbon isotopic composition of sedimentary organic matter (δ13Corg) is widely used in paleoenvironmental studies and commonly considered as proxy for lake productivity. In order to better understand the δ13Corg record of the partly annually laminated (varved) sediment profile of Lake Tiefer See, we complemented measurements from a long sediment core with analyses of short cores from different water depths and sediment trap data. The δ13Corg signature was determined (i) at 2 cm resolution from a 7.7 m-long continuous sediment record covering the last ˜6100 years retrieved from the deepest part of the lake (62 m), (ii) at 1 cm resolution from four short cores (0.5 to 0.9 m long) located at different water depths (20 -- 62 m) and covering at least the last 200 years and (iii) at bi-weekly to monthly resolution from sediment trap material collected at three water depths (5, 12 and 45 m) since march 2012. We observed that δ13Corg fluctuations are paralleled by changes in varve preservation, as well-varved sections show more negative δ13Corg values compared to non-varved intervals (1 -- 4‰ difference; analytical precision ±0.2‰). In short cores the negative shift of δ13Corg always appears at the most recent transition from non-varved to well-varved sediments. Depending on the water depth the onset of varve preservation occurred at different times (e.g. AD 1924 in 62 m water depth; AD 1981 in 20 m water depth). Since sediment trap data exhibit similar δ13Corg values of -30‰ to -31‰ in the entire water column and in the uppermost varved parts of the sediment cores, it is unlikely that the shift in δ13Corg was caused by processes in the water column because this should be seen in all cores at the same time. Therefore, we suggest that the δ13Corg record of the long sediment core of Lake Tiefer See does not reflect processes in the water column (i.e. productivity), but different early diagenetic processes in varved and non-varved sediment. In this study

  12. Temporal Trends of Triclosan Contamination in Dated Sediment Cores from Four Urbanized Estuaries: Evidence of Preservation and Accumulation

    EPA Science Inventory

    Triclosan is an antimicrobial agent added to a wide array of consumer goods and personal care products. Through its use, it is introduced into municipal sewer systems where it is only partially removed during wastewater treatment with the balance entering receiving waters via ef...

  13. Temporal Rends of Triclorosan in Dated Sediment Cores from Four Urbanized Estuaries: Evidence of Preservation and Accumulation

    EPA Science Inventory

    Triclosan is an antimicrobial agent present in a wide array of consumer based goods such as soaps, skin creams and dental care products. It has also been incorporated into textiles and plastics due to its effectiveness as a biocide in solid material. It is introduced into munic...

  14. Dating Modern Deltas: Progress, Problems, and Prognostics

    NASA Astrophysics Data System (ADS)

    Stanley, Jean-Daniel

    Radiocarbon dating is the method most frequently used to date Holocene deltaic sequences, but less than one quarter of 14C dates are within +/-500 years of predicted age. Such dates tend to be unreliable, in other words, often too old and commonly inverted upsection, and core sample dates obtained near deltaic plain surfaces may be as old as mid- to late Holocene. Stratigraphic irregularities result primarily from downslope reworking of upland alluvial sediment, with displacement of "old carbon" in the sediment that accumulates in lower valleys and deltaic plains. Use of dates that are too old results in inaccurately calculated rates (most often too low) of relative sea-level rise and/or land subsidence. More reliable timing of deltaic sediment requires a multiple-method dating approach, including, where possible, identification of associated archaeological material. Developing an accurate dating strategy is a critical step for implementing reliable coastal protection measures needed for the rapidly increasing human populations in these low-lying, vulnerable nearshore settings.

  15. Zn and Cu isotopes as tracers of anthropogenic contamination in a sediment core from an Urban Lake

    USGS Publications Warehouse

    Thapalia, A.; Borrok, D.M.; Van Metre, P.C.; Musgrove, M.; Landa, E.R.

    2010-01-01

    In this work, we use stable Zn and Cu isotopes to identify the sources and timing of the deposition of these metals in a sediment core from Lake Ballinger near Seattle, Washington, USA. The base of the Lake Ballinger core predates settlement in the region, while the upper sections record the effects of atmospheric emissions from a nearby smelter and rapid urbanization of the watershed. ??66Zn and ??65Cu varied by 0.50% and 0.29%, respectively, over the 500 year core record. Isotopic changes were correlated with the presmelter period (~1450 to 1900 with ??66Zn = +0.39% ?? 0.09% and ??65Cu = +0.77% ?? 0.06%), period of smelter operation (1900 to 1985 with ??66Zn = +0.14 ?? 0.06% and ??65Cu = +0.94 ?? 0.10%), and postsmelting/stable urban land use period (post 1985 with ??66Zn = 0.00 ?? 0.10% and ??65Cu = +0.82% ?? 0.12%). Rapid early urbanization during the post World War II era increased metal loading to the lake but did not significantly alter the ??66Zn and ??65Cu, suggesting that increased metal loads during this time were derived mainly from mobilization of historically contaminated soils. Urban sources of Cu and Zn were dominant since the smelter closed in the 1980s, and the (??66Zn measured in tire samples suggests tire wear is a likely source of Zn. ?? 2010 American Chemical Society.

  16. Two likely stratospheric volcanic eruptions in the 1450s C.E. found in a bipolar, subannually dated 800 year ice core record

    NASA Astrophysics Data System (ADS)

    Cole-Dai, Jihong; Ferris, David G.; Lanciki, Alyson L.; Savarino, Joël.; Thiemens, Mark H.; McConnell, Joseph R.

    2013-07-01

    An 800 year volcanic record is constructed from high-resolution chemical analysis of recently obtained West Antarctica and central Greenland ice cores. The high accuracy and precision of the ice core chronologies are a result of dating by annual ice layer counting. Nineteen bipolar volcanic signals in this record represent large, explosive eruptions in the tropics with probable climatic impact. One of the two bipolar volcanic signals dated at 1453 and 1459 is probably left by the eruption of the submarine volcano Kuwae in the tropical Pacific, one of the largest volcanic eruptions in the last millennium. The discovery of the two signals in the 1450s casts doubt on the eruption year of 1452 or 1453 for Kuwae based on previous ice core records. The volcanic sulfate deposition patterns in this bipolar record suggest that the later signal is likely from the Kuwae eruption in 1458, although a firm attribution is not possible. Sulfur isotope composition in the volcanic sulfate in the central Greenland cores indicates that both eruptions in the 1450s injected sulfur gases into the stratosphere with probable impact on the global climate. These results are in agreement with tree ring records showing two short cold episodes during that decade. The bipolar volcanic record supports the hypothesis that unusually active volcanism in the thirteenth century contributed to the onset of the Little Ice Age and another active period in the mid fifteenth century may have helped to sustain the Little Ice Age.

  17. Noble Gas and Mineralogical Tracers of Interplanetary Dust Particles and Impact Debris in a Central Pacific Sediment Core

    NASA Astrophysics Data System (ADS)

    Darrah, T. H.; Poreda, R. J.

    2005-12-01

    Thirty-five deep ocean sediment samples from the Central Pacific sediment core LL-44 GPC-3 were examined for their noble gas composition and mineralogy. The samples spanned from 30 to 71 Ma in age, including the Cretaceous/Tertiary (K/T), Paleocene/Eocene (P/E), and Eocene/Oligocene (E/O) boundaries. From each bulk sediment sample, magnetic grains (5-200 μg/g; 1-20 μm diameter) were isolated and analyzed. Noble gas measurements determined the helium and neon isotopic compositions and the abundance of extra-terrestrial (ET) noble gases for the bulk and magnetic fractions. 3He/4He ratios of 3.1x10-4 and 20Ne/22Ne ratios of 9.96-12.62 are consistent with the SEP (solar energetic particle) signature seen in both zero-age magnetic grains (Z-MAG) from the central Pacific sediments and stratospheric interplanetary dust particles (IDPs). The isolated magnetic fraction typically consisted of less than 1% of the bulk sample while accounting for 3 to 10% of the bulk sediment 3He with a maximum of 40% at K/T boundary. The magnetic isolates revealed no significant differences of 3He/4He, 20Ne/22Ne, or (3He/20Ne)solar from the bulk GPC-3 sediments or Z-MAG grains. No temporal variation in He or Ne or anomalous gas signatures associated with the boundaries present within this time interval was observed. Scanning electron microscope analysis was utilized to determine the mineralogy of the magnetic isolates in an effort to distinguish between the continuous flux of interplanetary dust particles and the flux associated with major impact events. This information may also assist in determining the carrier phase of ET noble gases. Anomalously high Ni, Mg, Al, and Cr compositions combined with low or nonexistent abundances of titanium can distinguish extraterrestrial spinel grains from terrestrial spinel. The SEM analysis revealed stark contrasts in composition and morphology in the samples associated with the boundaries included in this study. A survey of ``background'' samples

  18. The use of downstream sediment mini-cores to indicate changes through time in the spatial pattern and process contribution of erosion within a small, selectively logged rainforest catchment in Sabah, Malaysian Borneo

    NASA Astrophysics Data System (ADS)

    Williams, R. E.; Walsh, R. P. D.; Coombs, T. J.; Bidin, K.; Blake, W. H.

    2012-04-01

    Multi-proxy sediment fingerprinting (using changes in geochemical variables within downstream floodplain or lateral bench cores and relating them to differences in geochemical character of upstream tributary sediment inputs and/or down soil profiles, preferably in combination with dating using Pb-210 and Cs-137) provides the potential for assessing changes in sediment sources through time. This has rarely been done in tropical rainforest catchments, but needs to be tested at a variety of spatial scales. This poster paper presents the results of an attempt to use mini-cores of bankside sediment to explore changes through post-logging time in the relative contributions made by different sub-catchments to the sediment budget of a small (0.44 sq.km.) Baru catchment (selectively logged in the first half of 1989) in the Danum Valley area of Sabah, Malaysian Borneo. The catchment provides a good testing ground for the technique, as it has been monitored for slope erosion and stream suspended sediment transport continuously from before logging to the present day. The research design comprised (1) sampling (at 2 cm vertical intervals) fluvially deposited sediment down replicated pit profiles at three bankside locations at the downstream end of the catchment between the long-term gauging station and the confluence with a higher-order stream: (2) sampling of the finer bed-sediment the three principal tributaries (2West, 2Middle and 2East) and of surface, sub-surface and deep surface soil material from soil pits and road-cuttings across the catchment; (3) geochemical analysis of the <63μ, 63-125μ and 125μ-2mm fractions of all samples (following drying and sieving), using a portable Niton elemental analyser; (4) graphical and statistical analysis of the data. Pit 1 (34 cm deep) was considered to provide the longest and most dependable sediment record and marked changes in the levels of some elements were detected, with Mn, Fe, Ti and Zr proving to be the most useful. Local

  19. Results of a detailed infill lake-sediment survey in the Snow Lake area: Evaluation and comparison of grab sample and short core data

    USGS Publications Warehouse

    Friske, P.W.B.

    1996-01-01

    As part of the Exploration Science and Technology Initiative (EXTECH) program a detailed infill lake-sediment and water survey was undertaken in the Snow Lake area during the fall of 1991. This involved the collection of 346 lake sediment grab samples and concomitant waters. In 1993, additional work was undertaken involving the collection of 23 short cores from selected grab sample sites. The primary objectives of the infill survey and short core work were to: 1) evaluate the effectiveness of lake sediment geochemistry in detecting known mineralization in the Snow Lake area; 2) evaluate and develop new approaches in the use of lake sediment geochemistry; and, 3) define, if possible, new exploration targets. At most sites, data from the cores verify the original grab sample results. However, at a few sites the original anomalous grab sample results are interpreted as being related to contamination as opposed to naturally elevated levels. An unusually thick sequence of contaminated surface sediments with extremely high concentrations of trace metals is a likely contributing factor, a condition which is restricted to lakes in the immediate vicinity of local anthropogenic activity. Collection of lake cores provides a useful new approach to the follow-up of grab sample data and to the application of lake sediment geochemistry, particularly in areas with significant local contamination. Much of the known mineralization in the area is clearly reflected by the lake sediment data. Character of the anomalies mirror the composition of the nearby mineralization. The lake sediment data also identify a number of areas that warrant further investigation, several of which are discussed.

  20. Development of a precise and accurate age-depth model based on 40Ar/39Ar dating of volcanic material in the ANDRILL (1B) drill core, Southern McMurdo Sound, Antarctica

    NASA Astrophysics Data System (ADS)

    Ross, J. I.; McIntosh, W. C.; Dunbar, N. W.

    2012-10-01

    High precision 40Ar/39Ar dates on a variety of volcanic materials from the AND-1B drill core provide pinning points for defining the chronostratigraphy for the core. The volcanic materials dated include 1) felsic and basaltic tephra, 2) interior of a ~ 3 m thick intermediate submarine lava flow, and 3) felsic and basaltic volcanic clasts. In the upper 600 m of the core, two felsic tephra, two basaltic tephra and the intermediate laval flow yield precise and depositional ages, with further maximum age constraints from volcanic clasts. Below 600 m in the core, tephric intervals are significantly altered and maximum age constraints only are available from volcanic clasts. The ages for eight stratigraphic intervals are 1) 17.17-17.18 mbsf, basaltic clast (maximum depositional age 0.310 ± 0.039 Ma, all errors quoted at 2σ), 2) 52.80-52.82 mbsf, three basaltic clasts (maximum depositional age 0.726 ± 0.052 Ma), 3) 85.27-85.87 mbsf felsic tephra (1.014 ± 0.008 Ma), 4) ~ 112-145 mbsf sequence of basaltic tephra (1.633 ± 0.057 to 1.683 ± 0.055 Ma), 5) 480.97-481.96 mbsf pumice-rich mudstone (4.800 ± 0.076 Ma), 6) 646.30-649.34 mbsf intermediate lava flow (6.48 ± 0.13 Ma), 7) 822.78 mbsf kaersutite phenocrysts from volcanic clasts (maximum depositional age 8.53 ± 0.53 Ma) and 8) ~ 1280 mbsf, three volcanic clasts (maximum depositional age 13.57 ± 0.13 Ma). Minimum average sediment accumulation rates or 102 and 87 m/Ma for the upper and lower 650 m of core, respectively were calculated using the 40Ar/39Ar analyses. The volcanic material recovered from AND-1B also reveals a general northward progression of volcanism in Southern McMurdo Sound.

  1. Erosion of soil organic carbon at high latitudes and its delivery to Arctic Ocean sediments: New source to sink insight from radiocarbon dating

    NASA Astrophysics Data System (ADS)

    Hilton, Robert; Galy, Valier; Gaillardet, Jerome; Dellinger, Mathieu; Bryant, Charlotte; O'Regan, Matt; Grocke, Darren; Coxall, Helen

    2016-04-01

    Soils of the northern high latitudes store carbon over thousands of years and contain almost double the carbon stock of the atmosphere. Erosion processes can mobilise this pre-aged soil organic carbon from the landscape and supply it to rivers. If it escapes degradation during river transport and is delivered to the coastal ocean, this carbon may be sequestered for much longer periods of time (>104 yr) as a geological CO2 sink. Despite this recognition, the erosional flux and fate of particulate organic carbon (POC) in large rivers draining the high latitudes remains poorly constrained. Using radiocarbon activity, we quantify POC source, flux and fate in the Mackenzie River, the main sediment supplier to the Arctic Ocean. When combined with stable carbon isotopes and element ratios, the radiocarbon activity of POC allows us to distinguish inputs of POC from sedimentary rocks and quantify the average age of biospheric POC (from vegetation and soil) transported through the river system. We find that the eroded biospheric POC has resided in the basin for millennia, with a mean radiocarbon age of 5800±800 years. This is much older than large tropical rivers where we have equivalent data (Amazon River, Ganges River), and likely reflects the longer residence time of organic matter in cold, wet, high latitude soils. Based on the measured biospheric POC content and annual sediment flux, we calculate a biospheric POC flux of 2.2 (+1.3/-0.9) TgC yr‑1 from the Mackenzie River. This is the largest input of aged organic carbon to the Arctic Ocean, more than the combined POC flux from the Eurasian Rivers. Offshore, we use a marine core to investigate organic carbon burial over the Holocene period. Radiocarbon measurements of bulk organic carbon reveal a significant offset from benthic foraminifera radiocarbon ages throughout the core, which is dependent upon the grain size of the sediments. Organic matter in sediments >63μm are offset from foraminifera by ˜ 6,000 14C years

  2. The use of vintage surficial sediment data and sedimentary cores to determine past and future trends in estuarine metal contamination (Sydney estuary, Australia).

    PubMed

    Birch, G F; Chang, C-H; Lee, J-H; Churchill, L J

    2013-06-01

    The objectives of the present investigation were to determine past trends in sediment contamination and possibly predict future trends. Multiple vintages of surficial sediment metal data, from a quasi-decadal 'Status and Trends' programme, were used to provide large-scale spatial information on current status and temporal change. This information was augmented by sediment cores, specifically located to verify surface sediment data and to determine trends at major points of stormwater discharge. The data obtained indicate that surficial sediment metal concentrations have declined, since about the early 1990s, in extensive parts of the upper and central estuaries and have increased slightly in the lower estuary, due mainly to a down-estuary shift in industry and urbanisation. Declining surficial sediment metal concentrations is due to a movement of industry out of the catchment, especially from foreshore areas and the introduction of regulation, which prevent pollutants being discharged directly to the estuary. The major present-day source of metals is stormwater, with minor inputs from the main estuary channel into embayments and runoff from previously contaminated mainland sites. Modelled relaxation rates are optimistic as high metal concentrations in stormwater will slow predicted rates. Stormwater remediation should be the main managerial focus for this estuary. Multiple vintages of surficial sediment metal data covering the past 30 years, supplemented by sedimentary core data, have allowed past and future contamination trends to be determined. This type of science-based information provides an important tool for strategic management of this iconic waterway. PMID:23570910

  3. Integrated sequence stratigraphy of the postimpact sediments from the Eyreville core holes, Chesapeake Bay impact structure inner basin

    USGS Publications Warehouse

    Browning, J.V.; Miller, K.G.; McLaughlin, P.P., Jr.; Edwards, L.E.; Kulpecz, A.A.; Powars, D.S.; Wade, B.S.; Feigenson, M.D.; Wright, J.D.

    2009-01-01

    The Eyreville core holes provide the first continuously cored record of postimpact sequences from within the deepest part of the central Chesapeake Bay impact crater. We analyzed the upper Eocene to Pliocene postimpact sediments from the Eyreville A and C core holes for lithology (semiquantitative measurements of grain size and composition), sequence stratigraphy, and chronostratigraphy. Age is based primarily on Sr isotope stratigraphy supplemented by biostratigraphy (dinocysts, nannofossils, and planktonic foraminifers); age resolution is approximately ??0.5 Ma for early Miocene sequences and approximately ??1.0 Ma for younger and older sequences. Eocene-lower Miocene sequences are subtle, upper middle to lower upper Miocene sequences are more clearly distinguished, and upper Miocene- Pliocene sequences display a distinct facies pattern within sequences. We recognize two upper Eocene, two Oligocene, nine Miocene, three Pliocene, and one Pleistocene sequence and correlate them with those in New Jersey and Delaware. The upper Eocene through Pleistocene strata at Eyreville record changes from: (1) rapidly deposited, extremely fi ne-grained Eocene strata that probably represent two sequences deposited in a deep (>200 m) basin; to (2) highly dissected Oligocene (two very thin sequences) to lower Miocene (three thin sequences) with a long hiatus; to (3) a thick, rapidly deposited (43-73 m/Ma), very fi ne-grained, biosiliceous middle Miocene (16.5-14 Ma) section divided into three sequences (V5-V3) deposited in middle neritic paleoenvironments; to (4) a 4.5-Ma-long hiatus (12.8-8.3 Ma); to (5) sandy, shelly upper Miocene to Pliocene strata (8.3-2.0 Ma) divided into six sequences deposited in shelf and shoreface environments; and, last, to (6) a sandy middle Pleistocene paralic sequence (~400 ka). The Eyreville cores thus record the fi lling of a deep impact-generated basin where the timing of sequence boundaries is heavily infl uenced by eustasy. ?? 2009 The Geological

  4. Mass accumulation rate changes in Chinese loess during MIS 2, and asynchrony with records from Greenland ice cores and North Pacific Ocean sediments during the Last Glacial Maximum

    NASA Astrophysics Data System (ADS)

    Kang, Shugang; Roberts, Helen M.; Wang, Xulong; An, Zhisheng; Wang, Min

    2015-12-01

    Sensitivity-corrected quartz optically stimulated luminescence (OSL) dating methods have been widely accepted as a promising tool for the construction of late Pleistocene chronology and mass or dust accumulation rates (MARs or DARs) on the Chinese Loess Plateau (CLP). Many quartz OSL ages covering marine isotope stage (MIS) 2 (equal to L1-1 in Chinese loess) have been determined for individual sites within the CLP in the past decade. However, there is still a lack of detailed MAR or DAR reconstruction during MIS 2 across the whole of the CLP. Here, we present detailed MARs determined for eight sites with closely-spaced quartz OSL ages covering ∼MIS 2, and relative MARs suggested by a probability density analysis of 159 quartz OSL ages ranging from ∼30 to 10 ka ago, from 15 sites on the CLP. The results show enhanced dust accumulation during the Last Glacial Maximum (LGM), with particularly rapid dust accumulation from ∼23 to 19 ka ago (the late LGM). In contrast, MARs determined for the last deglaciation (from ∼19 to 12 ka ago) are low. The MAR changes during MIS 2 in Chinese loess are mainly controlled by the East Asian winter monsoon (EAWM) intensity, which is forced by Northern Hemisphere ice volume. The MAR changes also indicate that dust accumulation during MIS 2 is generally continuous at millennial time scales on the CLP. Comparison of Asian-sourced aeolian dust MARs in Chinese loess with those preserved in Greenland ice cores and North Pacific Ocean sediments indicates that rapid dust accumulation occurred from ∼26 to 23 ka ago (the early LGM) in Greenland ice cores and North Pacific Ocean sediments, suggesting a several kilo-year difference in timing when compared with the rapid dust accumulation during the late LGM in Chinese loess. This asynchronous timing in enhanced dust accumulation is probably related to both changes in the EAWM intensity and changes in the mean position of zone axis of the Westerly jet, both of which are greatly influenced

  5. Response To The Paleocene-Eocene Thermal Maximum Of Calcareous Nannofossils: Observations On Composition, Preservation And Calcification In Sediments From ODP Reference Cores

    NASA Astrophysics Data System (ADS)

    Raffi, I.; de Bernardi, B.

    2007-12-01

    Studies on a climate extreme as the Paleocene-Eocene Thermal Maximum (PETM, ~ 55 myrs ago) have shown the effects of these critical conditions on global biogeochemical cycles and ecosystem, including the marine and terrestrial biota. A prominent negative shift (~ 3 ‰) in marine δ13C, the Carbon Isotope Excursion (CIE) reflects the input of a large amount of isotopically depleted carbon in the ocean- atmosphere system. Studies of the few complete deep-sea sections recovered to date have shown how global climate, atmospheric CO2 levels, marine carbonate chemistry and continental weathering were dynamically related during the PETM. Together, these changes should have strongly influenced the calcifying organisms living in the surface (photic zone) of the oceans. For this reason, recent investigations have focus on the planktonic community response to the shifts in oceanic environments during the PETM, specifically the response of calcifying microplankton to higher CO2 and lower pH, as well as the possible role of plankton in drawing down CO2. Calcareous nannofossils seem to play an important role in these interrelated mechanisms. For this reason we have performed detailed micropaleontologic analysis (using a SEM) of calcareous nannofossil assemblages in selected samples from selected Paleocene/Eocene deep-sea sediment cores with the purpose of documenting possible influence on assemblage composition and preservation. The sediments studied in detail are from ODP Site 1263 (from Southern East Atlantic, Walvis Ridge) that has been chosen as representative of one of the few complete PETM deep-sea cores. Comparative analyses were performed in few selected samples from sections located at different latitudes in the Atlantic and Pacific oceans (ODP Site 929, paleo-equatorial Atlantic, Ceara Rise; ODP Site 689, high-latitude Southern Atlantic, Maud Rise; ODP Sites 1215 and 1221, Eastern equatorial Pacific; ODP Site 1209, central Pacific, Shatsky Rise). This study documents

  6. Further Paleogene and Cretaceous sediment cores from the Kilwa area of coastal Tanzania: Tanzania Drilling Project Sites 6 10

    NASA Astrophysics Data System (ADS)

    Pearson, Paul N.; Nicholas, Christopher J.; Singano, Joyce M.; Bown, Paul R.; Coxall, Helen K.; van Dongen, Bart E.; Huber, Brian T.; Karega, Amina; Lees, Jackie A.; MacLeod, Kenneth; McMillan, Ian K.; Pancost, Richard D.; Pearson, Marion; Msaky, Emma

    2006-07-01

    Initial results from scientific drilling in southern coastal Tanzania are described. In a field season in 2003, a total of five sites was drilled (mostly using continuous coring) by the Tanzania Drilling Project for paleoclimate studies. The sediments are predominantly marine clays and claystones deposited in an outer shelf or slope environment and often contain excellently preserved microfossils suitable for geochemical analysis. The studies reported here include summaries of the lithostratigraphy, biostratigraphy (planktonic foraminifers, calcareous nannofossils, benthic foraminifers, and palynology) and organic geochemistry. TDP Site 6 was drilled near Kilwa Masoko (UTM 37L 555752, 9014922), 350 m to the south-east of a previous site, TDP Site 1. The top 59.58 m, which was mostly drilled without coring, consists of an Oligocene clay formation belonging to nannofossil Zone NP23. The rest of the hole, to a total depth of 61.25 m, consists of a fault zone in which the Oligocene sediments are intermixed with middle Eocene clays of planktonic foraminifer Zone E9 and nannofossil Subzone NP15b. TDP Site 7 consists of two holes (Hole TDP7A: UTM 37L 547126, 9030142; Hole TDP7B: UTM 37L 0547130, 9030140) drilled just 5 m apart at Kwamatola, a creek to the south of Kilwa Kivinje. Underneath approximately 20 m of unconsolidated sands and gravels, claystones and siltstones were recovered to a total depth of 128.00 m. The site spans lower Eocene planktonic foraminifer Zones E1, E2 and E3 and nannofossil Subzones NP 9b and NP10. The bottom of Hole TDP7B approaches the Paleocene-Eocene boundary but no unambiguously Paleocene sediments were recovered. TDP Site 8 was drilled to the south-east of Singino Hill (UTM 37L 548033, 9025811). Below a covering of surface gravels, it yielded predominantly dark greenish-grey claystones to a total depth of 22.95 m. The sediments are from the lower Eocene and span the boundary between planktonic foraminifer Zones E3 and E4 and fall within

  7. Characterization of Vadose Zone Sediment: Uncontaminated RCRA Borehole Core Samples and Composite Samples

    SciTech Connect

    Serne, R. Jeffrey; Bjornstad, Bruce N.; Schaef, Herbert T.; Williams, Bruce A.; Lanigan, David C.; Horton, Duane G.; Clayton, Ray E.; Mitroshkov, Alexandre V.; Legore, Virginia L.; O'Hara, Matthew J.; Brown, Christopher F.; Parker, Kent E.; Kutnyakov, Igor V.; Serne, Jennifer N.; Last, George V.; Smith, Steven C.; Lindenmeier, Clark W.; Zachara, John M.; Burke, Deborah S.

    2008-09-11

    This report was revised in September 2008 to remove acid-extractable sodium data from Tables 4.14, 4.16, 5.20, 5.22, 5.43, and 5.45. The sodium data was removed due to potential contamination introduced during the acid extraction process. The rest of the text remains unchanged from the original report issued in February 2002. The overall goal of the of the Tank Farm Vadose Zone Project, led by CH2M HILL Hanford Group, Inc., is to define risks from past and future single-shell tank farm activities. To meet this goal, CH2M HILL Hanford Group, Inc. asked scientists from Pacific Northwest National Laboratory to perform detailed analyses on vadose zone sediment from within the S-SX Waste Management Area. This report is one in a series of four reports to present the results of these analyses. Specifically, this report contains all the geologic, geochemical, and selected physical characterization data collected on vadose zone sediment recovered from Resource Conservation and Recovery Act (RCRA) borehole bore samples and composite samples.

  8. Developments in optically stimulated luminescence and photo-transferred thermoluminescence dating of young sediments: Application to a 2000-year sequence of flood deposits

    NASA Astrophysics Data System (ADS)

    Murray, A. S.

    1996-02-01

    This paper demonstrates how optically stimulated luminescence (OSL) and photo-transferred thermoluminescence (PTTL) can be used to date young (0-2000 year-old) flood deposits on the bank of a major river in the Southern Tablelands of southeastern Australia. Quartz grains extracted from these deposits do not show a detectable dose-dependent sensitivity change following optical stimulation. This allows a recently proposed regeneration-based protocol (SARA) to be used to estimate the equivalent dose ( De) acquired since burial. For the oldest sample, a dependence of De on pre-heat temperature is removed by heating to at least 180 °C for 10 s before stimulation. Values of De are reported for six samples using both OSL and PTTL. Values ranged between 0.4 and 6.5 Gy, with overall uncertainties usually <7%; the values of De obtained using OSL and PTTL are in agreement. Dose rates are calculated from detailed analyses of environmental radionuclide concentrations, and the resulting luminescence dates range from 100 ± 13 to 1920 ± 130 years before present; the uncertainties include systematic effects. For two layers where there is age control by 14C dates, the luminescence dates are in good agreement. Unfortunately, the limitations of the 14C data preclude firm conclusions about the size of any effective age-residual at deposition for the luminescence samples, although this is likely to be <50-100 years. It is concluded that luminescence dating offers a considerable improvement over other techniques, including 14C, for recently transported fluvial sediments.

  9. Metal binding in soil cores and sediments in the vicinity of a dammed agricultural and industrial watershed.

    PubMed

    Kanbar, Hussein Jaafar; Hanna, Nour; El Samrani, Antoine G; Kazpard, Véronique; Kobaissi, Ahmad; Harb, Nafez; Amacha, Nabil

    2014-12-01

    The environment is witnessing a downgrade caused by the amelioration of the industrial and agricultural sectors, namely, soil and sediment compartments. For those reasons, a comparative study was done between soil cores and sediments taken from two locations in the Qaraaoun reservoir, Lebanon. The soil cores were partitioned into several layers. Each layer was analyzed for several physicochemical parameters, such as functional groups, particle size distribution, ζ-potential, texture, pH, electric conductivity, total dissolved solids, organic matter, cation exchange capacity, active and total calcareous, available sodium and potassium, and metal content (cadmium, copper, and lead). The metal content of each site was linked to soil composition and characteristics. The two sites showed distinguishable characteristics for features such as organic matter, pH, mineral fraction, calcareous, and metal content. The samples taken toward the south site (Q1), though contain lower organic matter than the other but are more calcareous, showed higher metal content in comparison to the other site (Q2) (average metal content of Q1 > Q2; for Cd 3.8 > 1.8 mg/kg, Cu 28.6 > 21.9 mg/kg, Pb 26.7 > 19 mg/kg). However, the metal content in this study did not correlate as much to the organic matter; rather, it was influenced by the location of the samples with respect to the dam, the reservoir's hydrodynamics, the calcareous nature of the soil, and the variation of the industrial and agricultural influence on each site. PMID:25228528

  10. Historical Associations of Molecular Measurements of Escherichia coli and Enterococci to Anthropogenic Activities and Climate Variables in Freshwater Sediment Cores.

    PubMed

    Brooks, Yolanda M; Baustian, Melissa M; Baskaran, Mark; Ostrom, Nathaniel E; Rose, Joan B

    2016-07-01

    This study investigated the long-term associations of anthropogenic (sedimentary P, C, and N concentrations, and human population in the watershed), and climatic variables (air temperature, and river discharge) with Escherichia coli uidA and enterococci 23S rRNA concentrations in sediment cores from Anchor Bay (AB) in Lake St. Clair, and near the mouth of the Clinton River (CR), Michigan. Calendar year was estimated from vertical abundances of (137)Cs. The AB and CR cores spanned c.1760-2012 and c.1895-2012, respectively. There were steady state concentrations of enterococci in AB during c.1760-c.1860 and c.1910-c.2003 at ∼0.1 × 10(5) and ∼2.0 × 10(5) cell equivalents (CE) per g-dry wt, respectively. Enterococci concentrations in CR increased toward present day, and ranged from ∼0.03 × 10(5) to 9.9 × 10(5) CE/g-dry wt. The E. coli concentrations in CR and AB increased toward present day, and ranged from 0.14 × 10(7) to 1.7 × 10(7) CE/g-dry wt, and 1.8 × 10(6) to 8.5 × 10(6) CE/g-dry wt, respectively. Enterococci was associated with population and river discharge, while E. coli was associated with population, air temperature, and N and C concentrations (p < 0.05). Sediments retain records of the abundance of fecal indicator bacteria, and offer a way to evaluate responses to increased population, nutrient loading, and environmental policies. PMID:27322138

  11. Shallow-marine sediment cores record climate variability and earthquake activity off Lisbon (Portugal) for the last 2000 years

    NASA Astrophysics Data System (ADS)

    Abrantes, F.; Lebreiro, S.; Rodrigues, T.; Gil, I.; Bartels-Jónsdóttir, H.; Oliveira, P.; Kissel, C.; Grimalt, J. O.

    2005-12-01

    Sea Surface Temperature (SST), river discharge and biological productivity have been reconstructed from a multi-proxy study of a high-temporal-resolution sedimentary sequence recovered from the Tagus deposition center off Lisbon (Portugal) for the last 2000 years. SST shows 2 °C variability on a century scale that allows the identification of the Medieval Warm Period (MWP) and the Little Ice Age (LIA). High Iron (Fe) and fine-sediment deposition accompanied by high n-alkane concentrations and presence of freshwater diatoms during the LIA (1300-1900 AD) (Science 292 (2001) 662) suggest augmented river discharge, whereas higher total-alkenone concentrations point to increased river-induced productivity. During the MWP (550-1300 AD) (Science 292 (2001) 662) larger mean-grain size and low values of magnetic susceptibility, and concentrations of Fe, n-alkanes, and n-alcohols are interpreted to reflect decreased runoff. At the same time, increased benthic and planktonic foraminifera abundances and presence of upwelling related diatoms point to increased oceanic productivity. On the basis of the excellent match found between the negative phases of the North Atlantic Oscillation (NAO) index and the intensified Tagus River discharge observed for the last century, it is hypothesized that the increased influx of terrigenous material during the LIA reflects a negative NAO-like state or the occurrence of frequent extreme NAO minima. During the milder few centuries of the MWP, stronger coastal upwelling conditions are attributed to a persistent, positive NAO-like state or the frequent occurrence of extreme NAO maxima. The peak in magnetic susceptibility, centered at 90 cm composite core depth (ccd), is interpreted as the result of the well-known 1755 AD Lisbon earthquake. The Lisbon earthquake and accompanying tsunami are estimated to have caused the loss of 39 cm of sediment (355 years of record—most of the LIA) and the instantaneous deposition of a 19-cm sediment bed.

  12. Examination of Potential Management Decisions Based upon a Core Collection Derived from Last Circulation Date Data. Research Report No. 1.

    ERIC Educational Resources Information Center

    Schwarz, Philip; Olson, Linda

    This study was conducted to fulfill two objectives: to gather the data necessary to define the core collection, i.e., a subset of the holdings that can be identified with reasonable assurance as being able to fulfill a certain predetermined percentage of the future demand on the present collection, and to examine the value of these data as a…

  13. Holocene sea-level determination relative to the Australian continent: U/Th (TIMS) and 14C (AMS) dating of coral cores from the Abrolhos Islands

    NASA Astrophysics Data System (ADS)

    Eisenhauer, A.; Wasserburg, G. J.; Chen, J. H.; Bonani, G.; Collins, L. B.; Zhu, Z. R.; Wyrwoll, K. H.

    1993-02-01

    U/Th (TIMS) and 14C (AMS) measurements are presented from two coral cores from the Easter group of the Houtman Abrolhos Islands between 28°S and 29°S on the western continental margin of Australia. The U/Th measurements on the Morley core from Morley Island cover a depth interval from 0.2 m above present sea level to 24.4 m below present sea level and comprise eleven samples. The ages vary between 6320 ± 50 a, at 0.2 m above sea level, and 9809 ± 95 a, at 24.4 m below sea level (all errors are 2σ). The mean growth rate is 7.1 ± 0.9 m/ka. The 14C dates of selected Morley core corals show that the 14C ages are ˜ 1000 a younger than their corresponding U/Th ages, which agrees with previous results. The main purpose of our 14C measurements is to be able to compare them precisely with other coral cores where no U/Th measurements are available. The U/Th measurements of the Suomi core from Suomi Island cover a depth interval from 0.05 m to 14.2 m below present sea level and consist of four samples. The ages vary between 4671 ± 40 a, at 0.05 m below sea level, and 7102 ± 82 a, at 14.2 m below sea level, with a mean growth rate of 5.8 ± 0.2 m/ka. The growth history of both cores is explained by a simple model in which the growth rates of the Morley core can be interpreted as reflecting local rates of sea level rise, whereas the Suomi core is interpreted as reflecting lateral growth during the past ˜ 6000 a. Our results indicate that sea level relative to the western margins of the Australian continent was about 24 m lower than present at about 9800 a B.P. ( 14C gives a date of 8500 a B.P.). Sea level then rose and reached a highstand, slightly higher than the present position at about 6300 a B.P ( 14C date: 5500 a). This highstand declined but was still higher than present at 4600 a B.P. This is in agreement with previous observations along the Australian coastal margins and with observations from the Huon peninsula (Papua New Guinea). Our results are very

  14. Use of plutonium isotope activity ratios in dating recent sediments. [/sup 238/Pu//sup 239/Pu + /sup 240/Pu

    SciTech Connect

    Beasley, T. M.

    1982-01-01

    The majority of plutonium presently in the biosphere has come from the testing of nuclear devices. In the early 1950s, the Pu-238/239+240 activity ratio of fallout debris was > 0.04; in the more extensive test series of 1961 to 1962, the Pu-238/239+240 activity ratios were quite consistent at 0.02 to 0.03 and maximum fallout delivery occurred in mid-1963. A significant perturbation in Pu isotope activity ratios occurred in mid-1966 with the deposition of Pu-238 from the SNAP-9A reentry and burn-up. Recently deposited sediments have recorded these events and where accumulation rates are rapid (> 1 cm/y), changes in Pu isotope activity ratios can be used as a geochronological tool.

  15. Controls on the distribution and fractionation of yttrium and rare earth elements in core sediments from the Mandovi estuary, western India

    NASA Astrophysics Data System (ADS)

    Prajith, A.; Rao, V. Purnachandra; Kessarkar, Pratima M.

    2015-01-01

    Mineralogy, major elements (Fe, Mn and Al), rare earths and yttrium (REY) of bulk sediments were analyzed in four gravity cores recovered along the main channel of the Mandovi estuary, western India, to determine the sources and controls on REY distribution. The accelerator mass spectrometer (AMS) ages of total organic carbon indicated modern age for the sediments of the upper estuary and, maximum mean ages of 1588 years AD and 539 years AD for the bottom sediments of the cores in the lower estuary and bay, respectively. The sediments of the upper/middle estuary showed abundant hematite, magnetite and goethite and high Fe, Mn, total-REE (ΣREE) and Y, while those in the lower estuary/bay showed abundant silicate minerals and relatively low Fe, Mn, ΣREE and Y. ΣREE showed significant correlation with clay and silt fractions and Y, Al and organic carbon (OC) content of the sediments. The light to heavy REE ratios (LREE/HREE) of sediments were lower than in Post-Archean Australian Shale (PAAS). The PAAS-normalized rare earths and yttrium (REY; Y inserted between Dy and Ho) patterns of sediments showed middle REE (MREE)- and HREE-enrichment with positive Eu anomaly (Eu/Eu*) and variable Ce anomaly (Ce/Ce*). The REY of sediments is primarily controlled by its texture and REE of source sediment, which is ore material-dominated in the upper/middle estuary and silicate material-dominated in the lower estuary/bay. Low LREE/HREE ratios suggest that very fine-grained sediments were carried away from the estuary because of high-energy conditions. Fractionations of REY (Y/Ho, Sm/Nd, Ce/Ce* and Eu/Eu*) are controlled by different mechanisms. High Y/Ho ratios in clayey silts are due to redistribution of Y and Ho by adsorption onto organic-rich, clays. Variations in Sm/Nd ratios are similar to that of Eu/Eu* in cores from the lower estuary/bay and are controlled by mineral constituents of the sediments. Positive Ce and Eu anomalies are inherited from ore material, and ore

  16. Spatial and Temporal Variations in the Geomagnetic Field Determined From the Paleomagnetism of Sediment Cores From Scientific Ocean Drilling

    NASA Astrophysics Data System (ADS)

    Acton, G.

    2014-12-01

    Quantifying the spatial and temporal variations of the main geomagnetic field at Earth's surface is important for understanding underlying geodynamo processes and conditions near the core-mantle boundary. Much of the geomagnetic variability, known as secular variation, occurs on timescales of tens of years to many thousands of years, requiring the use of paleomagnetic observations to derive continuous records of the ancient field, referred to as paleosecular variation (PSV) records. Marine depositional systems where thick sedimentary sections accumulate at high sedimentation rates provide some of the best locations for obtaining long continuous PSV records that can reveal both the short- and long-term changes in the field. Scientific ocean drilling has been successful at recovering many such sections and the paleomagnetic records from these reveal how the amplitude of PSV differs between sites and through time. In this study, several such records cored during Ocean Drilling Program (ODP), Integrated Ocean Drilling Program (IODP), and other cruises from high, mid, and low latitudes will be used to quantify time intervals of low and high PSV, to examine time-average properties of the field, to map spatial variations in the angular dispersion of the virtual geomagnetic pole (VGP), and to assess whether the spatial variation in angular dispersion changes with time.

  17. Apollo 11 drive-tube core samples: an initial physical analysis of lunar surface sediment.

    PubMed

    Fryxell, R; Anderson, D; Carrier, D; Greenwood, W; Heiken, G

    1970-01-30

    Two drive-tube core samples were obtained at Tranquillity Base. Fines include much glass, are unweathered, medium gray, loose, nonstructured, very weakly coherent, and demonstrate both accumulation and mixing in a waterless vacuum environment. In contrast to chemical weathering characteristic on the earth, lunar alteration processes are primarily mechanical. We infer that environmental processes of the lunar surface may be expressed as follows: R (regolith) = f(cl, p, r, t, b, a, . . .), in which climate (cl) is constant and the time (t)-de-pendent processes of bombardment (b) and accumulation (a) assume significance unparalleled on the earth because of their effects on parent material (p) and relief (r). PMID:17781569

  18. Zn and Cu Isotopes as Tracers of Anthropogenic Contamination in a Sediment Core from an Urban Lake

    USGS Publications Warehouse

    Thapalia, Anita; Borrok, David M.; Van Metre, Peter C.; Musgrove, MaryLynn; Landa, Edward R.

    2010-01-01

    In this work, we use stable Zn and Cu isotopes to identify the sources and timing of the deposition of these metals in a sediment core from Lake Ballinger near Seattle, Washington, USA. The base of the Lake Ballinger core predates settlement in the region, while the upper sections record the effects of atmospheric emissions from a nearby smelter and rapid urbanization of the watershed. δ66Zn and δ65Cu varied by 0.50%o and 0.29%o, respectively, over the 500 year core record. Isotopic changes were correlated with the presmelter period (~1450 to 1900 with δ66Zn = +0.39%o ± 0.09%o and δ65Cu = +0.77%o ± 0.06%o), period of smelter operation (1900 to 1985 with δ66Zn = +0.14 ± 0.06%o and δ65Cu = +0.94 ± 0.10%o), and postsmelting/stable urban land use period (post 1985 with δ66Zn = 0.00 ± 0.10%o and δ65Cu = +0.82%o ± 0.12%o). Rapid early urbanization during the post World War II era increased metal loading to the lake but did not significantly alter the δ66Zn and δ65Cu, suggesting that increased metal loads during this time were derived mainly from mobilization of historically contaminated soils. Urban sources of Cu and Zn were dominant since the smelter closed in the 1980s, and the δ66Zn measured in tire samples suggests tire wear is a likely source of Zn.

  19. Relationship of uranium to petrography of caliche paleosols with application to precisely dating the time of sedimentation

    SciTech Connect

    Rasbury, E.T.; Meyers, W.J.; Hanson, G.N.; Goldstein, R.H.; Saller, A.H.

    2000-05-01

    The authors use petrography combined with fission-track mapping to evaluate qualitatively the phases that concentrate uranium in caliche paleosols from late Paleozoic cyclothems of Texas and New Mexico. They also discuss geochemical analyses of U and Pb concentrations and Pb isotopic compositions. Uranium concentrations in brown caliche calcite range from 1 to 9 ppm. Lead concentrations in the same calcites range from 0.5 to 1 ppm. Lead-isotope compositions range from common (no apparent radiogenic component) to lead with a substantial radiogenic component. Cliches with brown calcite most likely developed near the vadose-phreatic interface--often a redox boundary where organic material (and uranium) is expected to be concentrated. In contrast, uranium concentrations in light-colored caliche nodules from the vadose zone have uranium concentrations that are 1 ppm or less. Fifteen of forty-five samples from this study have a range in U/Pb that would permit precise dating of the rocks, but only the data from three give precise ages. Some of the samples have hematite, which has high concentrations of U and Pb. For one of the precisely dated samples, the two-sigma uncertainty was improved from 10 to 2.6 Ma by avoiding hematite when sampling.

  20. Consistently dated records from three Greenland ice cores reveal regional millennial-scale isotope gradients with possible Heinrich Event imprint

    NASA Astrophysics Data System (ADS)

    Seierstad, Inger K.; Rasmussen, Sune O.

    2014-05-01

    We here present records from the NGRIP, GRIP and GISP2 ice cores tied to the same chronology for the past 104 ka at an unprecedented time resolution. The three ice cores have been linked by matching distinct peaks in volcanic proxy records and other impurity records from the three ice cores, assuming that these layers of elevated impurity content represent the same, instantaneous event in the past at all three sites. In total there are more than 900 identified marker horizons between the three cores including previously published match points, of which we introduce a minor revision. Our matching is independently confirmed by new and existing volcanic ash layers (tephra). The depth-depth relationship from the detailed matching is used to transfer the most recent and widely used Greenland ice core chronology, the GICC05modelext timescale, to the two Summit cores, GRIP and GISP2. Furthermore, we provide gas chronologies for the Summit cores that are consistent with the GICC05modelext timescale by utilizing both existing and new unpublished gas data. A comparison of the GICC05modelext and the former GISP2 timescale reveals major discrepancies in short time intervals during the glacial section. We detect a pronounced change in the relative annual layer thickness between the two Summit sites and NGRIP across the Last Glacial termination and early-to-mid Holocene, which can be explained by a relative accumulation increase at NGRIP compared to the Summit region as response to the onset of the Holocene and the climatic optimum. Between stadials and interstadials we infer that the accumulation contrast typically was nearly 10% greater at Summit compared to at NGRIP. The δ18O temperature-proxy records from NGRIP, GRIP and GISP2 are generally very similar and display a synchronous behavior at climate transitions, but the δ18O differences between Summit and NGRIP is slowly changing over the last glacial-interglacial cycle superimposed by abrupt millennial-to centennial scale

  1. Simultaneous determination of mercury and organic carbon using a direct mercury analyzer: Mercury profiles in sediment cores from oxbow lakes in the Mississippi Delta

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Sediment cores from seasonal wetland and open water areas from six oxbow lakes in the Mississippi River alluvial flood plain were analyzed for total-mercury (Hg) using a direct mercury analyzer (DMA). In the process we evaluated the feasibility of simultaneously determining organic matter content by...

  2. Onset of a small but significant regional climate change documented in high-resolution late Holocene sediment cores from the maritime western Antarctic Peninsula

    NASA Astrophysics Data System (ADS)

    Barnard, A.; Wellner, J. S.; Anderson, J. B.

    2010-12-01

    The glacimarine environment of the Antarctic Peninsula region is one of the fastest warming places on earth; however, late Holocene paleoclimate reconstructions in this region are separated by large distances and details of past changes remain uncertain. This study focuses on a marine sediment core collected in 2007 from the deep Central Bransfield Basin in 1980 m of water and provides a central tie for other published studies in this region. The core lithology is dominantly diatomaceous mud with some turbidites. Radiocarbon and cesium dates have been used to create a age model that spans the interval 3600 cal yr BP to present. This chronostratigraphic framework was used to establish five units, which are grouped into two super-units, based upon: detailed facies descriptions, laser particle size analysis, x-ray radiograph analysis, multi-sensor core logger data, elemental and isotopic data. The two super-units that have been recognized are a lower super-unit (3559-1600 cal yr BP) and an upper super-unit (1600 cal yr BP - present). The upper super-unit signature is described by elevated δ13C coupled with decreasing δ15N values, lower magnetic susceptibility values and less frequent facies changes. This signature is interpreted as an increase in primary productivity and a potential mechanism for this small but significant change may be an increase in surface water temperature and/or shortening of the sea-ice season. The five units that are recognized are comparable with known climatic transitions across the western Antarctic Peninsula: the Mid-Holocene Climatic Optimum, the Neoglacial, the Medieval Warm Period, the Little Ice Age, and rapid recent warming. The super-unit boundary coincides with an early onset of the Medieval Warm Period (1600 cal yr BP) which is typically at 1200 cal yr BP. These changes in the Bransfield Basin have been compared to other published records from the Bransfield Basin, Firth of Tay, Maxwell Bay, and Palmer Deep. These comparisons

  3. Distribution of REEs in box-core sediments offshore an industrial area in SE Sicily, Ionian Sea: evidence of anomalous sedimentary inputs.

    PubMed

    Di Leonardo, Rossella; Bellanca, Adriana; Neri, Rodolfo; Tranchida, Giorgio; Mazzola, Salvo

    2009-10-01

    The distribution of rare earth elements and yttrium (REEs+Y) has been investigated in box-core sediments recovered from four stations in the Sicilian coastal zone seawards of Augusta, one of the most industrialized and contaminated areas in the Mediterranean region. Shale-like REE patterns and low Y/Ho ratios (close to the chondritic ratio) suggest a dominant terrigenous (geogenic) source for REE. Slight enrichment of LREE over the HREE is interpreted as due to preferential adsorptive transfer of LREE from seawater to sediment particles. Samples from offshore cores exhibit slightly positive Gd and negative Ce anomalies. It is here hypothesized that main drivers of anthropogenic Gd flux towards the offshore are dredged contaminated materials that, recovered from the Augusta Bay, have been repeatedly discharged offshore. Consistent with the redox-chemistry of Ce, these anomalous sedimentary inputs induce a decrease of O(2) concentration in the sediment, which in turn triggers Ce regeneration. PMID:19735932

  4. The rare earth element geochemistry on surface sediments, shallow cores and lithological units of Lake Acıgöl basin, Denizli, Turkey

    NASA Astrophysics Data System (ADS)

    Budakoglu, Murat; Abdelnasser, Amr; Karaman, Muhittin; Kumral, Mustafa

    2015-11-01

    The sediments in Lake Acıgöl, located in SW Anatolia, Turkey, were formed under tectono-sedimentary events. REE geochemical investigations of the Lake Acıgöl sediments, from surface and shallow core sediments at different depths (0-10 cm, 10-20 cm and 20-30 cm) are presented to clarify the characteristics of REE and the nature of source rocks in the lake sediments' and to deduce their paleoenvironmental proxies. The chondrite-normalized REE patterns of these sediments are shown as light enrichment in LREE and flat HREE with a negative Eu anomaly that is close to the continental collision basin (CCB) in its profile; this is not comparable with PAAS and UCC. Inorganic detrital materials control the REE characteristics of the Lake Acıgöl sediments and these sediments were accumulated in oxic and dysoxic depositional conditions and/or at passive margins derived from oceanic island arc rocks. They were affected by low chemical weathering, either at the original source or during transport, before deposition under arid or subtropical humid climatic conditions. In addition, we used GIS techniques (such as Inverse Distance Weighted (IDW) and Geographically Weighted Regression (GWR)) to investigate the spatial interpolation and spatial correlation of the REEs from the lake surface sediments in Lake Acıgöl and its surrounding lithological units. GIS techniques showed that the lithological units (e.g., Hayrettin Formation) north of Lake Acıgöl have high REE contents; however, Eu/Eu∗ values were higher in some lake surface sediments than in lithological units, and that refers to a negative Eu-anomaly. Therefore, Lake Acıgöl sediments are derived from the weathered products, mainly from local, highly basic bedrock around the lake from the Archean crust. The chronology of Lake Acıgöl sediment was conducted using the Constant Rate of Supply (CRS) model. Using the CRS methods for the calculation of sedimentation rate, we obtained a 0.012 g/cm2/year value which is an

  5. Hydrothermal energy transfer and contribution to autotrophic CO2 fixation down sediment core in Central Indian Basin

    NASA Astrophysics Data System (ADS)

    Das, Anindita; LokaBharathi P., A.

    2014-05-01

    Hydrothermal Energy Transfer is not only restricted to active vents sites but also to the passive ones. These passive sources could include the sub-seafloor hydrothermal fluid flux derived from distant sources like erupting vents or from deep-mantle. The contribution from such fluxes in stimulating autotrophic carbon fixation could be measurable. In this paper an attempt is made to measure the autotrophic CO2 fixation down a siliceous sediment core (Core 20, 75?30'E, 12?S) adjoining Trace of Rodrigues Triple Junction in the Central Indian Basin (CIB) with a fluid flux influence at 15-20 cms bsf (below sea-floor) which is quite distinct from the pelagic influence on the overlying 0-15 cms bsf. This work assumes that NH4+and S2- are major e-donors/reductants to fuel C-Fixation. The down-core carbon fixation varied from 0.032-0.122μmol C g-1day-1 with the larger peak at 15-20 cms bsf. This coincides with the dips in pore-water concentrations of NH4+ and S2-. Therefore the corresponding standard free energy change (ΔG?') down-core varied from -97 at 4-6 cms bsf to -375 J μmol-1 C fixed m-3 day-1 at 12-14 cms bsf in case of NH4+. In case of S2- the values varied from -42 at 4-6 cms bsf to -162 J μmol-1 m-3 day-1at 12-14 cms bsf. Integrated down-core estimate of ΔG?' is calculated to be -26.97 J μmol-1 C fixation m-2 day-1 during CO2 fixation using NH4+ and -11.7 J μmol-1 C fixation m-2 day-1 using S2-. This fluid-flow influenced layer appears physically as a brown-green transition zone in the core at a depth of 15-20 cm bsf. Interestingly similar observations have been made in >15 such cores around the present test core. These observations suggest that this spreading bed at this depth could be due to the upward fluid flow that then spreads laterally. This spread could perhaps be more than the area that the current observations permit. So the Hydrothermal Energy Transfer is equivalent to -11.70 to -26.97 J μmol-1 C fixation m-2 day-1and corresponds to 88 μmol of

  6. Refined depositional history and dating of the Tongaporutuan reference section, north Taranaki, New Zealand: new volcanic ash U-Pb zircon ages, biostratigraphy and sedimentation rates

    USGS Publications Warehouse

    Maier, K.L.; Crundwell, Martin P.; Coble, Matthew A.; Kingsley-Smith, Peter R.; Graham, Stephan A.

    2016-01-01

    This study presents new radiometric ages from volcanic ash beds within a c. 1900 m thick, progradational, deep-water clastic slope succession of late Miocene age exposed along the north Taranaki coast of the North Island, New Zealand. The ash beds yield U–Pb zircon ages ranging from 10.63 ± 0.65 Ma to 8.97 ± 0.22 Ma. The new ages are compatible with and provide corroboration of New Zealand Tongaporutuan Stage planktic foraminiferal and bolboformid biostratigraphic events identified in the same section. The close accord between these two age datasets provides a stratigraphically consistent and coherent basis for examining margin evolution. The arrival of a prograding clastic wedge and ensuing upward shoaling is recorded by sedimentation rates c. 2000 m/Ma–1 that are an order of magnitude higher than sedimentation rates on the precursor deep basin floor. This outcrop study provides new constraints for interpreting analogous subsurface deposits in Taranaki Basin and complements the regional late Miocene biostratigraphic dating framework.

  7. Late Quaternary sediment deposition of core MA01 in the Mendeleev Ridge, the western Arctic Ocean: Preliminary results

    NASA Astrophysics Data System (ADS)

    Park, Kwang-Kyu; Kim, Sunghan; Khim, Boo-Keun; Xiao, Wenshen; Wang, Rujian

    2014-05-01

    Late Quaternary deep marine sediments in the Arctic Ocean are characterized by brown layers intercalated with yellowish to olive gray layers (Poore et al., 1999; Polyak et al., 2004). Previous studies reported that the brown and gray layers were deposited during interglacial (or interstadial) and glacial (or stadial) periods, respectively. A 5.5-m long gravity core MA01 was obtained from the Mendeleev Ridge in the western Arctic Ocean by R/V Xue Long during scientific cruise CHINARE-V. Age (~450 ka) of core MA01 was tentatively estimated by correlation of brown layers with an adjacent core HLY0503-8JPC (Adler et al., 2009). A total of 22 brown layers characterized by low L* and b*, high Mn concentration, and abundant foraminifera were identified. Corresponding gray layers are characterized by high L* and b*, low Mn concentration, and few foraminiferal tests. Foraminifera abundance peaks are not well correlated to CaCO3 peaks which occurred with the coarse-grained (>0.063 mm) fractions (i.e., IRD) both in brown and gray layers. IRDs are transported presumably by sea ice for the deposition of brown layers and by iceberg for the deposition of gray layers (Polyak et al., 2004). A strong correlation coefficient (r2=0.89) between TOC content and C/N ratio indicates that the major source of organic matter is terrestrial. The good correlations of CaCO3 content to TOC (r2=0.56) and C/N ratio (r2=0.69) imply that IRDs contain detrital CaCO3 which mainly originated from the Canadian Arctic Archipelago. In addition, high kaolinite/chlorite (K/C) ratios mostly correspond to CaCO3 peaks, which suggests that the fine-grained particles in the Mendeleev Ridge are transported from the north coast Alaska and Canada where Mesozoic and Cenozoic strata are widely distributed. Thus, the Beaufort Gyre, the predominant surface current in the western Arctic Ocean, played an important role in the sediment delivery to the Mendeleev Ridge. It is worthy of note that the TOC and CaCO3 peaks are

  8. Dynamics of metallic contaminants at a basin scale--Spatial and temporal reconstruction from four sediment cores (Loire fluvial system, France).

    PubMed

    Dhivert, E; Grosbois, C; Courtin-Nomade, A; Bourrain, X; Desmet, M

    2016-01-15

    From the 19th century, the Loire basin (France) presents potentially pollutant activities such as mining and heavy industries. This paper shows spatio-temporal distribution of trace elements in sediments at a basin-scale, based on a comparison of archived temporal signals recorded in four sedimentary cores. Anthropogenic sources contributing to sediment contamination are also characterized, using geochemical signatures recorded in river bank sediments of the most industrialized tributaries. This study highlights upstream-downstream differences concerning recorded contamination phases in terms of spatial influence and temporality of archiving processes. Such differences were related to (i) various spatial influences of contamination sources and (ii) polluted sediments dispersion controlled by transport capacity of metal-carrier phases and hydrosedimentary dynamics. PMID:26490530

  9. Lead in Lake Michigan and Green Bay Surficial Sediments

    EPA Science Inventory

    Sediment cores were collected in 1987-1989 in Green Bay using a box corer and in 1994-1996 in Lake Michigan using a box corer and a PONAR. Core samples were segmented and dated. Historic background lead concentrations were determined for Green Bay (range=1.8-39.3 mg/kg, mean=14...

  10. Temporal trends of contaminants recorded in sediments of Puget Sound

    SciTech Connect

    Crecelius, E.A.; Curl, H.C. Jr.

    1988-03-01

    This paper discusses the temporal trends of contamination that can be inferred from the chemical composition of age-dated sediment cores from central Puget Sound. The fine-grain sediment (less than 10% sand) of the deep region (>150m) of central Puget Sound, which accumulates relatively undisturbed sediment at a rate of approximately 1 cm per year, provides a useful record of the history of contamination. 21 refs., 4 figs.

  11. Independently dated paleomagnetic secular variation records from the Tibetan Plateau

    NASA Astrophysics Data System (ADS)

    Haberzettl, T.; Henkel, K.; Kasper, T.; Ahlborn, M.; Su, Y.; Appel, E.; St-Onge, G.; Stoner, J. S.; Daut, G.; Wang, J.; Zhu, L.; Maeusbacher, R.

    2014-12-01

    Magnetostratigraphy has been serving as a valuable tool for dating and confirming chronologies of lacustrine sediments in many parts of the world. However, suitable paleomagnetic records on the Tibetan Plateau (TP) and adjacent areas are extremely scarce. Here, independently radiocarbon dated sediments of two lakes on the southern central TP, Tangra Yumco and Taro Co some 250 km further west, were investigated for their potential to record paleomagnetic secular variations. Multiple sediment cores resemble a very similar inclination pattern for the past 4000 years. This demonstrates the high potential of inclination to compare records over the Tibetan Plateau and eventually date other Tibetan records stratigraphically. Comparisons to an existing record from Nam Co, a lake 350 km west of Tangra Yumco, a varve dated record from the Makran Accretionary Wedge, and a stack record from East Asia reveal many similarities. However, model output data of geomagnetic field models for the coordinates of Tangra Yumco do not agree with our findings.

  12. Analysis of the La:P ratio in lake sediments - Vertical and spatial distribution assessed by a multiple-core survey.

    PubMed

    Yasseri, Said; Epe, Tim S

    2016-06-15

    In recent years, lanthanum modified bentonite has been increasingly applied to eutrophic lakes with the aim of converting potentially bio-available forms of phosphorus in sediments into biologically unavailable forms. In many of these applications, however, no attempts have been made to assess the efficiency and efficacy of the measure in terms of its effect on the sediment. In this study, we collected sediment cores from a heavily eutrophied lake that has previously been treated with lanthanum modified clay. This restoration method is based on the strong ionic bond formed between lanthanum and phosphate which results in the formation of LaPO4 (Rhabdophane) in the sediment. In order to determine the changes that had occurred in the sediments as a result of the addition of the clay, we measured the vertical distribution of lanthanum in the collected cores, calculated La:P ratios of the different sediment layers and used the ratios to determine whether or not the applied dosage was sufficient. By means of the geostatistical method of kriging these values were transferred into maps of different depth intervals to visualize the results. The results indicate that the La:P ratio may be a useful tool which allows lake managers to measure the vertical distribution of lanthanum in sediments following treatments and determine whether or not dosages are sufficient to permanently render sediment phosphorus biologically unavailable. The method may also provide a basis on which to decide whether or not smaller reapplications are needed and can be used to control the dispersion of the material. PMID:26250755

  13. Hominin Sites and Paleolakes Drilling Project. Chew Bahir, southern Ethiopia: How to get from three tonnes of sediment core to > 500 ka of continuous climate history?

    NASA Astrophysics Data System (ADS)

    Foerster, Verena; Asrat, Asfawossen; Cohen, Andrew S.; Gromig, Raphael; Günter, Christina; Junginger, Annett; Lamb, Henry F.; Schaebitz, Frank; Trauth, Martin H.

    2016-04-01

    In search of the environmental context of the evolution and dispersal of Homo sapiens and our close relatives within and beyond the African continent, the ICDP-funded Hominin Sites and Paleolakes Drilling Project (HSPDP) has recently cored five fluvio-lacustrine archives of climate change in East Africa. The sediment cores collected in Ethiopia and Kenya are expected to provide valuable insights into East African environmental variability during the last ~3.5 Ma. The tectonically-bound Chew Bahir basin in the southern Ethiopian rift is one of the five sites within HSPDP, located in close proximity to the Lower Omo River valley, the site of the oldest known fossils of anatomically modern humans. In late 2014, the two cores (279 and 266 m long respectively, HSPDP-CHB14-2A and 2B) were recovered, summing up to nearly three tonnes of mostly calcareous clays and silts. Deciphering an environmental record from multiple records, from the source region of modern humans could eventually allow us to reconstruct the pronounced variations of moisture availability during the transition into Middle Stone Age, and its implications for the origin and dispersal of Homo sapiens. Here we present the first results of our analysis of the Chew Bahir cores. Following the HSPDP protocols, the two parallel Chew Bahir sediment cores have been merged into one single, 280 m long and nearly continuous (>90%) composite core on the basis of a high resolution MSCL data set (e.g., magnetic susceptibility, gamma ray density, color intensity transects, core photographs). Based on the obvious cyclicities in the MSCL, correlated with orbital cycles, the time interval covered by our sediment archive of climate change is inferred to span the last 500-600 kyrs. Combining our first results from the long cores with the results from the accomplished pre-study of short cores taken in 2009/10 along a NW-SE transect across the basin (Foerster et al., 2012, Trauth et al., 2015), we have developed a hypothesis

  14. Ultra-high-resolution paleoenvironmental records via direct laser-based analysis of lipid biomarkers in sediment core samples

    PubMed Central

    Wörmer, Lars; Elvert, Marcus; Fuchser, Jens; Lipp, Julius Sebastian; Buttigieg, Pier Luigi; Zabel, Matthias; Hinrichs, Kai-Uwe

    2014-01-01

    Marine microorganisms adapt to their habitat by structural modification of their membrane lipids. This concept is the basis of numerous molecular proxies used for paleoenvironmental reconstruction. Archaeal tetraether lipids from ubiquitous marine planktonic archaea are particularly abundant, well preserved in the sedimentary record and used in several molecular proxies. We here introduce the direct, extraction-free analysis of these compounds in intact sediment core sections using laser desorption ionization (LDI) coupled to Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS). LDI FTICR-MS can detect the target lipids in single submillimeter-sized spots on sediment sections, equivalent to a sample mass in the nanogram range, and could thus pave the way for biomarker-based reconstruction of past environments and ecosystems at subannual to decadal resolution. We demonstrate that ratios of selected archaeal tetraethers acquired by LDI FTICR-MS are highly correlated with values obtained by conventional liquid chromatography/MS protocols. The ratio of the major archaeal lipids, caldarchaeol and crenarchaeol, analyzed in a 6.2-cm intact section of Mediterranean sapropel S1 at 250-µm resolution (∼4-y temporal resolution), provides an unprecedented view of the fine-scale patchiness of sedimentary biomarker distributions and the processes involved in proxy signal formation. Temporal variations of this lipid ratio indicate a strong influence of the ∼200-y de Vries solar cycle on reconstructed sea surface temperatures with possible amplitudes of several degrees, and suggest signal amplification by a complex interplay of ecological and environmental factors. Laser-based biomarker analysis of geological samples has the potential to revolutionize molecular stratigraphic studies of paleoenvironments. PMID:25331871

  15. 40Ar-39Ar dating of volcanogenic products from the AND-2A core (ANDRILL Southern McMurdo Sound Project, Antarctica): correlations with the Erebus Volcanic Province and implications for the age model of the core

    NASA Astrophysics Data System (ADS)

    di Vincenzo, Gianfranco; Bracciali, Laura; Del Carlo, Paola; Panter, Kurt; Rocchi, Sergio

    2010-05-01

    The AND-2A drillcore (Antarctic Drilling Program—ANDRILL) was successfully completed in late 2007 on the Antarctic continental margin (Southern McMurdo Sound, Ross Sea) with the aim of tracking ice proximal to shallow marine environmental fluctuations and to document the 20-Ma evolution of the Erebus Volcanic Province. Lava clasts and tephra layers from the AND-2A drillcore were investigated from a petrographic and stratigraphic point of view and analyzed by the 40Ar-39Ar laser technique in order to constrain the age model of the core and to gain information on the style and nature of sediment deposition in the Victoria Land Basin since Early Miocene. Ten out of 17 samples yielded statistically robust 40Ar-39Ar ages, indicating that the AND-2A drillcore recovered ≤230 m of Middle Miocene (˜128-358 m below sea floor, ˜11.5-16.0 Ma) and >780 m of Early Miocene (˜358-1093 m below sea floor, ˜16.0-20.1 Ma). Results also highlight a nearly continuous stratigraphic record from at least 358 m below sea floor down hole, characterized by a mean sedimentation rate of ˜19 cm/ka, possible oscillations of no more than a few hundreds of ka and a break within ˜17.5-18.1 Ma. Comparison with available data from volcanic deposits on land, suggests that volcanic rocks within the AND-2A core were supplied from the south, possibly with source areas closer to the drill site for the upper core levels, and from 358 m below sea floor down hole, with the “proto-Mount Morning” as the main source.

  16. Isothermal thermoluminescence dating of K-feldspar from sediments to determine fault slip rates: development and assessment

    NASA Astrophysics Data System (ADS)

    Rhodes, E. J.; Roder, B. J.; Lawson, M. J.; Dolan, J. F.; McGill, S. F.; McAuliffe, L.

    2012-04-01

    Faults in California accommodate most of the relative motion between the Pacific and North American tectonic plates, along either one main strike-slip fault, - the San Andreas fault - or a network of sub-parallel faults (e.g., the San Jacinto, Elsinore and San Andreas faults). Slip is also accommodated along many other associated faults and folds, and the region suffers frequent damaging earthquakes. Contemporary movements of different fault-bounded blocks are relatively well established on decadal timescales using remote sensing and GPS, and on timescales of 106 to 107 years, by dating offset geologic features with radiometric methods. However, on timescales of decades to several hundred thousand years, determining total fault offset and mean slip rate is harder. Critical questions for understanding fault dynamics and improving earthquake risk assessment include the degree to which slip is clustered into episodes of more rapid movement, and how slip is accommodated by different sub-parallel faults. In many cases, streams with offset courses can be recognised, and in some cases offset terrace surfaces can be located, especially when using LiDAR data to complement field mapping. Radiocarbon and terrestrial cosmogenic nuclides have been used to date these features, but both have limitations of age range, sample suitability and availability. OSL (optically stimulated luminescence) and IRSL (infra-red stimulated luminescence) have great potential to complement these techniques, though the characteristics of quartz in some parts of southern California are suboptimal, displaying low sensitivity and other limitations. In order to overcome these limitations encountered using quartz OSL, we are developing a new geochronometer based on the isothermal thermoluminescence (ITL) signal of K feldspar measured at 250°C. Preliminary ITL age estimates from the paleoseismic site of El Paso Peaks on the Central Garlock fault in the Mojave Desert, California, agree well with a well

  17. Thin Film XRF measurements (Wet and dry) of Black Sea Sediment Samples And Their Elemental Comparisons With Same Core U Channel Sample.

    NASA Astrophysics Data System (ADS)

    Acar, Dursun; Eris, Kadir; Sarı, Erol; Genc, S. Can

    2015-04-01

    This paper presents the XRF data from about 0.3mm thin film sediment core. We prepared 3 different model from same sediment core. The main aim is the finding for elemental changing of spectra variety and their comparison with physical changes of samples about mass and water content. Our XRF measurements were carried out by ITRAX (Cox System), and we have documented the some useful and more precision tricks; a) the first point is that the wet or dry nature of the core, b) the second is the use of U channel sample or thin film sample. For base referencing for the selected elements, we prepared normal wet U channel sample with the thickness of 1.5 cm. We used thin material (film) for keeping the humidty of every core sample's surface. Because humidity loss very high on thin film core sample and very effective to get bad results related to changing of topography and beam emission related to loss of pore water. Our XRF measurements have revealed that the Zn, Ti, Si, V,S, Cr, Mn, Ba, K and Ca elements were measured more precisely and accurate using by the dry thin film sample than those of wet U channel and wet thin sediment sample experiments. Beside this, Y, Zr, Nb, Rb, Sr, Ir, Fe,Co, Ni and Al elements were measured from the wet U channeled core more reliable with respect to the former. Lead (Pb) and Cd elements have behaved constantly during the three types of measurements. Keywords: Thin film XRF, U channel, Elements, Sediment, Measurement

  18. Clay Mineralogy of Shallow Core Sediments of Lake Acigöl, Denizli, Turkey

    NASA Astrophysics Data System (ADS)

    Budakoglu, Murat; Karaman, Muhittin; Geredeli, Serpil; Unal, Hatice; Abdelnasser, Amr; Kiran Yildirim, Demet

    2014-05-01

    Lake Acıgöl is a hypersaline and active industrial salt production lake located in Denizli, Turkey. Lake Acıgöl has been investigated to elucidate the distribution clay minerals under the saline conditions of the lake and carbonate and ophiolitic rocks controlled lake basin. The lake is very shallow and generally characterized by an un-stratified and whole oxygenated water table. Determination clay minerals in the bulk samples via XRD method was not possible due to the their small amount. Therefore, the sequential clay enrichment procedure applied to the bulk samples such as sample dispersion, removal of soluble salts and ions, and particle-size fractionation. The XRD analyses of normal, glycolated and heat-treated shallow core samples show that the dominant clay minerals in the samples to be illite, including the swelling montmorillonite and kaolinite minerals are encountered less frequently. Glauberite, Blodite, Dansite and Nickelblodite have been also identified as soda minerals by XRD studies.

  19. Aligning and synchronization of MIS5 proxy records from Lake Ohrid (FYROM) with independently dated Mediterranean archives: implications for DEEP core chronology

    NASA Astrophysics Data System (ADS)

    Zanchetta, Giovanni; Regattieri, Eleonora; Giaccio, Biagio; Wagner, Bernd; Sulpizio, Roberto; Francke, Alex; Vogel, Hendrik; Sadori, Laura; Masi, Alessia; Sinopoli, Gaia; Lacey, Jack H.; Leng, Melanie J.; Leicher, Niklas

    2016-05-01

    The DEEP site sediment sequence obtained during the ICDP SCOPSCO project at Lake Ohrid was dated using tephrostratigraphic information, cyclostratigraphy, and orbital tuning through the marine isotope stages (MIS) 15-1. Although this approach is suitable for the generation of a general chronological framework of the long succession, it is insufficient to resolve more detailed palaeoclimatological questions, such as leads and lags of climate events between marine and terrestrial records or between different regions. Here, we demonstrate how the use of different tie points can affect cyclostratigraphy and orbital tuning for the period between ca. 140 and 70 ka and how the results can be correlated with directly/indirectly radiometrically dated Mediterranean marine and continental proxy records. The alternative age model presented here shows consistent differences with that initially proposed by Francke et al. (2015) for the same interval, in particular at the level of the MIS6-5e transition. According to this new age model, different proxies from the DEEP site sediment record support an increase of temperatures between glacial to interglacial conditions, which is almost synchronous with a rapid increase in sea surface temperature observed in the western Mediterranean. The results show how a detailed study of independent chronological tie points is important to align different records and to highlight asynchronisms of climate events. Moreover, Francke et al. (2016) have incorporated the new chronology proposed for tephra OH-DP-0499 in the final DEEP age model. This has reduced substantially the chronological discrepancies between the DEEP site age model and the model proposed here for the last glacial-interglacial transition.

  20. Offshore Extent of the Iceland Ice Cap During the Last Glacial Maximum Inferred from Multibeam Bathymetric Data and Sediment Cores.

    NASA Astrophysics Data System (ADS)

    Helgadottir, G.; Brandsdottir, B.; Geirsdottir, A.; Björnsson, H.

    2005-12-01

    The insular margin of Iceland is incised by several major troughs, which mark the pathways of outlet glaciers during the last glaciations. Multibeam bathymetric data have revealed features of glacial erosion and sedimentation pertinent to the extent of the Iceland ice cap during the Last Glacial Maximum. Marginal moraines have been identified at the southern, western and northwestern edge of the insular margin. Furthermore, glacial erosion and sedimentation along the Kolbeinsey Ridge, North Iceland, indicates that the Iceland ice cap extended beyond 67°30'N. The ridge axis is made up of various types of seamounts, crater rows and hummocky ridges whereas older seamounts have been sculptured into roche moutonnées by glacial erosion. The far extent of the ice cap to the north is also supported by sediment studies on cores that have been retrieved from the troughs on the northern and northwestern part of the insular margin. Numerous smaller moraines exist closer to land marking stepwise retreat of the ice cap during deglacial times. Such moraines have been identified at 400-500 m depth within a 3-6 km wide, U-shaped valley along the western margin of the Kolbeinsey ridge (at 66°55'N) and within many of the costal fjords. Many of the offshore features resemble those known from land, such as streamlined bedrock features elongated in the regional direction of ice flow, eskers and subglacial meltwater channels together with erosional channels possibly formed by jökulhlaups. Extensive number of ice plough marks are revealed on bank areas and landslides on the marginal slope. Fluted surfaces and subglacially formed meltwater channels suggest formation underneath fast flowing, warm-based ice streams. These newly identified glacial features reveal new information on the spatial extent, dynamics and retreat of the Iceland ice cap during the last glaciation and deglaciation. Eustatic and isostatic contributions can be predicted from models of ice sheets and mantle rheology