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Sample records for diffusive mass transfer

  1. Improved oxygen mass transfer modeling for diffused or subsurface aeration systems

    SciTech Connect

    McWhirter, J.R.; Hutter, J.C. . Dept. of Chemical Engineering)

    1988-01-01

    The mass transfer analysis of the oxygen transfer performance of diffused air or subsurface mechanical aeration systems has progressed very little over the past twenty years. The ASCE Standard Method for determination of the oxygen mass transfer performance as applied to a diffused or subsurface aeration systems is based on a greatly over-simplified mass transfer model. Although the ASCE Standard can be used to empirically evaluate point performance conditions, it is not suitable for prediction of the performance of diffused aeration systems under changing operating or environmental conditions. A new oxygen mass transfer model has been developed which is a fundamentally more rigorous description of the actual mass transfer process in diffused aeration systems. This model can be confidently used to predict aerator performance under changing operation and environmental conditions and is easily adapted to numerical solution on a computer for routing aeration system performance evaluation as well as process design. The model is presented in this book.

  2. Mass transfer in SCW extraction molecular diffusion and mass transfer coefficients of ketones and alkenes in sub- and supercritical water

    SciTech Connect

    Goemans, M.G.E.; Gloyna, E.F.

    1996-10-01

    The potential of sub- and supercritical water as extraction solvents has been demonstrated for the (reactive) extraction of coals, used car tires, organic species from residual aqueous solutions, and class selective extraction of organic pollutants with different polarities from solids. In addition, the potential of extraction of coal with supercritical aqueous solutions has been studied. However, physical transport in water at elevated temperature and pressures- and their impact on heterogenous reactions and (reactive) extraction -are not adequately understood. This situation is largely due to the limited data that is available for diffusion in high temperature, high pressure water mixture. Only the molecular diffusion of Iodine ions and hydroquinone in near-critical subcritical water and the self diffusion of coefficient of compressed supercritical water have been reported. In this paper, we present molecular diffusion coefficients of benzophenone, acetone, naphthalene, and anthracene in water at infinite dilution. Pressures ranged from 250 to 500 bar at temperatures ranging from 50{degrees}C to 500{degrees}C resulting in water densities ranging from 1000 to 150 kg/m{sup 3}. Diffusion coefficients were determined by the Taylor-Aris dispersion technique. The effects of increased diffusion on the mass transfer coefficients for emulsions and packed beds were quantified. Molecular division coefficients were 10 to 20 times faster in supercritical water than in water at ambient conditions. Experimental results were correlated with hydrodynamic and kinetic theory. This study and results to be published elsewhere show that diffusion-limited conditions are much more likely to be encountered in supercritical water than is commonly acknowledged.

  3. Diffusive transfer to membranes as an effective interface between gel electrophoresis and mass spectrometry

    NASA Astrophysics Data System (ADS)

    Ogorzalek Loo, Rachel R.; Mitchell, Charles; Stevenson, Tracy I.; Loo, Joseph A.; Andrews, Philip C.

    1997-12-01

    Diffusive transfer was examined as a blotting method to transfer proteins from polyacrylamide gels to membranes for ultraviolet matrix-assisted laser desorption ionization (MALDI) mass spectrometry. The method is well-suited for transfers from isoelectric focusing (IEF) gels. Spectra have been obtained for 11 pmol of 66 kDa albumin loaded onto an IEF gel and subsequently blotted to polyethylene. Similarly, masses of intact carbonic anhydrase and hemoglobin were obtained from 14 and 20 pmol loadings. This methodology is also compatible with blotting high molecular weight proteins, as seen for 6 pmol of the 150 kDa monoclonal antibody anti-[beta]-galactosidase transferred to Goretex. Polypropylene, Teflon, Nafion and polyvinylidene difluoride (PVDF) also produced good spectra following diffusive transfer. Only analysis from PVDF required that the membrane be kept wet prior to application of matrix. Considerations in mass accuracy for analysis from large-area membranes with continuous extraction and delayed extraction were explored, as were remedies for surface charging. Vapor phase CNBr cleavage was applied to membrane-bound samples for peptide mapping.

  4. Volatile organic compound emission rate from diffused aeration systems. 1: Mass transfer modeling

    SciTech Connect

    Chern, J.M.; Yu, C.F.

    1995-08-01

    The activated sludge process is one of the most commonly used biochemical oxidation process for the secondary treatment of municipal and industrial wastewaters. The release of volatile organic compounds (VOCs) from wastewater treatment plants has recently caused great concern. In wastewater treatment plants, many operation units such s equalization and aeration involve oxygen transfer between wastewater and air. While oxygen is transferred from air to wastewater, VOCs are stripped from wastewater to air. Due to increasingly stringent environmental regulations, wastewater treatment operators have to do VOC inventory of their facilities. A mass transfer model for VOCs is therefore called for to assess VOC emission rates from wastewater treatment processes. Almost all existing methods adopt an oxygen mass transfer model standardized by the American Society of Civil Engineers (ASCE) to evaluate VOC emission rates. A new and more fundamental oxygen mass transfer model for diffused aeration systems was developed to assess the VOC emission rates. The new model provides better insight of the VOC mass transfer process and requires only aeration performance data to predict the VOC emission rates. The results and implications of both models were discussed and compared.

  5. Diffusion mass transfer of KOH through Ni/Zn battery membrane separators

    SciTech Connect

    Poa, D.S.; Cook, G.M.; Yao, N.P.

    1983-01-01

    This report discusses three elements that influence KOH electrolyte diffusion fluxes through nickel/zinc battery separators: concentration gradient, temperature dependence, and ordering of multilayer membranes. The KOH diffusion fluxes through three different Ni/Zn battery separators (193 PUDO cellophane, Celgard 3401 and 3501, and Permion P-2291 40/30) are found to increase linearly with an increasing KOH concentration gradient from 10 to 40 wt% (the dilute side of the diffusion cell was filled with distilled water). Typically, the flux approaches a constant value as the concentration gradient is further increased from 45 to 60 wt%. This increase in diffusion mass transfer resistance, in the 45 to 60 wt% KOH concentration range, was analyzed by the method of modified Wilson plots and found to be related to an increase in the phase boundary resistance. It was also shown that the temperature dependences of the KOH diffusion fluxes through these three separators are not the same. Furthermore, they do not always explicitly follow liquid phase diffusion theory. In the case of two-layer composite membrance separators, in which one layer bears fixed negative charges and the other layer is an ideal Fickian membrane (simple porous structure), the KOH diffusion flux is higher when the charge-bearing layer faces the concentrated side of the diffusion cell.

  6. Diffusion mass transfer of KOH through Ni/Zn battery membrane separators

    NASA Astrophysics Data System (ADS)

    Poa, D. S.; Cook, G. M.; Yao, N. P.

    1983-01-01

    Three elements that influence KOH electrolyte diffusion fluxes through nickel/zinc battery separators are discussed: (1) concentration gradient; (2) temperature dependence; and (3) ordering of multilayer membranes. The KOH diffusion fluxes through three different Ni/Zn battery separators (193 PUDO cellophane, Celgard 3401 and 3501, and Permion P-2291 40/30) increase linearly with an increasing KOH concentration gradient from 10 to 40 wt%. The flux approaches a constant value as the concentration gradient is further increased from 45 to 60 wt%. This increase in diffusion mass transfer resistance, in the 45 to 60 wt% KOH concentration range, was analyzed by the modified Wilson plots and found to be related to an increase in the phase boundary resistance. It is shown that the temperature dependences of the KOH diffusion fluxes through these three separators are not the same and they do not always explicitly follow liquid phase diffusion theory. In the case of two layer composite membrane separators, in which one layer bears fixed negative charges and the other layer is an ideal Fickian membrane the KOH diffusion flux is higher when the charge bearing layer faces the concentrated side of the diffusion cell.

  7. Multicomponent mass transfer

    SciTech Connect

    Taylor, R.; Krishna, R.

    1993-01-01

    This is an important book on multicomponent mass transfer, meant for readers already acquainted with the theory of mass transfer and the fundamentals of transport phenomena. Part 1, entitled Molecular Diffusion, contains the following chapters: Preliminary Concepts; The Maxwell-Stefan Relations; Fick's Law; Estimation of Diffusion Coefficients; Solution of multicomponent Diffusion Problems: The Linearized Theory; and Solution of Multicomponent Diffusion Problems: Effective Diffusivity Methods. Part 2, entitled Interphase Transfer, contains the following chapters: Mass-Transfer Coefficients; Film Theory; Unsteady-State Mass-Transfer Models; Mass Transfer in Turbulent Flow; and Simultaneous Mass and Energy Transfer. Part 3, entitled Design, contains the following chapters: Multicomponent Distillation: Mass-Transfer Models; Multicomponent Distillation: Efficiency Models; Multicomponent Distillation: A Nonequilibrium Stage Model; and Condensation of Vapor Mixtures. Appendices are provided on matrix algebra, equation-solving and estimation of a thermodynamic derivative matrix. A computer diskette is provided with the book; the examples in Chapters 1--13 are solvable using this diskette and the commercial package Mathcad which the user must obtain. A separate software package, Chemsep, is needed for some of the exercises in Chapter 14.

  8. Single-drop reactive extraction/extractive reaction with forced convective diffusion and interphase mass transfer

    NASA Technical Reports Server (NTRS)

    Kleinman, Leonid S.; Reed, X. B., Jr.

    1995-01-01

    An algorithm has been developed for the forced convective diffusion-reaction problem for convection inside and outside a droplet by a recirculating flow field hydrodynamically coupled at the droplet interface with an external flow field that at infinity becomes a uniform streaming flow. The concentration field inside the droplet is likewise coupled with that outside by boundary conditions at the interface. A chemical reaction can take place either inside or outside the droplet or reactions can take place in both phases. The algorithm has been implemented and results are shown here for the case of no reaction and for the case of an external first order reaction, both for unsteady behavior. For pure interphase mass transfer, concentration isocontours, local and average Sherwood numbers, and average droplet concentrations have been obtained as a function of the physical properties and external flow field. For mass transfer enhanced by an external reaction, in addition to the above forms of results, we present the enhancement factor, with the results now also depending upon the (dimensionless) rate of reaction.

  9. Single-drop reactive extraction/extractive reaction with forced convective diffusion and interphase mass transfer

    NASA Technical Reports Server (NTRS)

    Kleinman, Leonid S.; Red, X. B., Jr.

    1995-01-01

    An algorithm has been developed for time-dependent forced convective diffusion-reaction having convection by a recirculating flow field within the drop that is hydrodynamically coupled at the interface with a convective external flow field that at infinity becomes a uniform free-streaming flow. The concentration field inside the droplet is likewise coupled with that outside by boundary conditions at the interface. A chemical reaction can take place either inside or outside the droplet, or reactions can take place in both phases. The algorithm has been implemented, and for comparison results are shown here for the case of no reaction in either phase and for the case of an external first order reaction, both for unsteady behavior. For pure interphase mass transfer, concentration isocontours, local and average Sherwood numbers, and average droplet concentrations have been obtained as a function of the physical properties and external flow field. For mass transfer enhanced by an external reaction, in addition to the above forms of results, we present the enhancement factor, with the results now also depending upon the (dimensionless) rate of reaction.

  10. A diffusion-kinetic model for pulverized-coal combustion and heat-and-mass transfer in a gas stream

    SciTech Connect

    E.A. Boiko; S.V. Pachkovskii

    2008-12-15

    A diffusion-kinetic model for pulverized-coal combustion and heat-and-mass transfer in a gas stream is proposed, and the results of numerical simulation of the burnout dynamics of Kansk-Achinsk coals in the pulverized state at different treatment conditions and different model parameters are presented. The mathematical model describes the dynamics of thermochemical conversion of solid organic fuels with allowance for complex physicochemical phenomena of heat-and-mass exchange between coal particles and the gaseous environment.

  11. Computational characterization of diffusive mass transfer in porous solid oxide fuel cell components

    NASA Astrophysics Data System (ADS)

    Nelson, George J.

    Diffusive mass transport within porous SOFC components is explored using two modeling approaches that can better inform the SOFC electrode design process. These approaches include performance metrics for electrode cross-sectional design and a fractal approach for modeling mass transport within the pore structure of the electrode reaction zone. The performance metrics presented are based on existing analytical models for transport within SOFC electrodes. These metrics include a correction factor for button-cell partial pressure predictions and two forms of dimensionless reactant depletion current density. The performance impacts of multi-dimensional transport phenomena are addressed through the development of design maps that capture the trade-offs inherent in the reduction of mass transport losses within SOFC electrode cross-sections. As a complement to these bulk electrode models, a fractal model is presented for modeling diffusion within the electrochemically active region of an SOFC electrode. The porous electrode is separated into bulk and reaction zone regions, with the bulk electrode modeled in one-dimension based on the dusty-gas formalism. The reaction zone is modeled in detail with a two-dimensional finite element model using a regular Koch pore cross-section as a fractal template for the pore structure. Drawing on concepts from the analysis of porous catalysts, this model leads to a straightforward means of assessing the performance impacts of reaction zone microstructure. Together, the modeling approaches presented provide key insights into the impacts of bulk and microstructural geometry on the performance of porous SOFC components.

  12. Mathematical Model of the Processes of Heat and Mass Transfer and Diffusion of the Magnetic Field in an Induction Furnace

    NASA Astrophysics Data System (ADS)

    Perminov, A. V.; Nikulin, I. L.

    2016-03-01

    We propose a mathematical model describing the motion of a metal melt in a variable inhomogeneous magnetic field of a short solenoid. In formulating the problem, we made estimates and showed the possibility of splitting the complete magnetohydrodynamical problem into two subproblems: a magnetic field diffusion problem where the distributions of the external and induced magnetic fields and currents are determined, and a heat and mass transfer problem with known distributions of volume sources of heat and forces. The dimensionless form of the heat and mass transfer equation was obtained with the use of averaging and multiscale methods, which permitted writing and solving separately the equations for averaged flows and temperature fields and their oscillations. For the heat and mass transfer problem, the boundary conditions for a real technological facility are discussed. The dimensionless form of the magnetic field diffusion equation is presented, and the experimental computational procedure and results of the numerical simulation of the magnetic field structure in the melt for various magnetic Reynolds numbers are described. The extreme dependence of heat release on the magnetic Reynolds number has been interpreted.

  13. Assessment of diffuse heavy metal pollution, mass transfer and flows at a gold mining site within the Lake Baikal Basin

    NASA Astrophysics Data System (ADS)

    Thorslund, Josefin; Jarsjö, Jerker; Chalov, Sergey; Belozerova, Ekaterina

    2013-04-01

    The flux, transfer and accumulation of heavy metals in aquatic systems pose a potential danger to the ecosystem at various scales, due to their toxicity and non-destroyable nature. Mining and ore excavation can cause heavy metal pollution of both local and downstream water systems, including groundwater sources. The Zaamar Goldfield, located in the upper Lake Baikal Basin (Mongolia), is an example of an extensive gold mining site, which significantly contributes to downstream increases in riverine concentrations of heavy metals, both in dissolved and suspended phases. However, the placer mining area is large and the pollution is diffuse by nature. Due to lack of detailed monitoring, it is unclear how the pollution is transported from the mine tailings to the river. There are several potentially important pathways, such as mobilization of bank sediments, in-stream dissolution from metal-rich suspended/bottom sediments, and through polluted groundwater. We here aim at estimating diffuse mass flows from the source zone to the river, in addition to riverine mass flows. Additionally, the behaviour of heavy metals under varying geochemical conditions (such as pH) is investigated, to be able to understand the solubility of various heavy metals and their partitioning between particulate and dissolved phase. We base our analysis on on-site hydrogeochemical field campaigns. These include concentration measurements in different media (groundwater, waste ponds, ditches, river water, suspended sediments, and bottom sediments). Runoff estimations from the site as well as solubility calculations are also main analytical methods. Results show a net increase in both dissolved and suspended riverine mass flows over the Zaamar site. Concentrations in the deep groundwater system are generally in the same order of magnitude as river concentrations, which suggest important inputs of dissolved heavy metals to the river through groundwater flows. The input of dissolved concentrations are

  14. Mass diffusion in liquids

    NASA Astrophysics Data System (ADS)

    Walter, H. U.

    Dimensionless number analysis indicates that diffusion-controlled conditions with liquid samples having characteristic dimensions larger than one millimetre can only be established under microgravity conditions.Consequently, heat and mass transport properties of fluids can only be quantitatively investigated in space.Results obtained from experiments on selfdiffusion, interdiffusion and thermodiffusion carried out during the SL-1 and D-1 Spacelab missions clearly demonstrate the potential of space platforms to determine such properties with a precision unattainable on earth. These results imply also that crystal growth from solutions, vapours and melts in the diffusive regime can be realised in space only.

  15. Modeling mass transfer in solid oxide fuel cell anode: II. H2/CO co-oxidation and surface diffusion in synthesis-gas operation

    NASA Astrophysics Data System (ADS)

    Bao, Cheng; Jiang, Zeyi; Zhang, Xinxin

    2016-08-01

    Following the previous work on comparing performance of Fickian, Stefan-Maxwell and dusty-gas model for mass transfer in single fuel system, this article is focused on the electrochemistry and transport in the anode of solid oxide fuel cell using H2sbnd H2Osbnd COsbnd CO2sbnd N2 hybrid fuel. Under the standard framework of the dusty-gas model combined with the Butler-Volmer equation, it carries out a macroscopic area-specific modeling work. More specifically, two variables of hydrogen current fraction and enhancement factor are well defined and solved for the electrochemical co-oxidation of H2 and CO, and the diffusion equivalent circuit model is introduced to describe more comprehensively the resistance of mass transfer including molecular/Knudsen diffusion and surface diffusion. The model has been validated well in full region of Vsbnd I performance of an experimental anode-supported button cell. An approximate analytical solution of the hydrogen current fraction is also presented for explicit computation. Comparison between the results by different approaches for the effective diffusivity shows the importance of right mass-transfer modeling.

  16. Heat transfer, diffusion, and evaporation

    NASA Technical Reports Server (NTRS)

    Nusselt, Wilhelm

    1954-01-01

    Although it has long been known that the differential equations of the heat-transfer and diffusion processes are identical, application to technical problems has only recently been made. In 1916 it was shown that the speed of oxidation of the carbon in iron ore depends upon the speed with which the oxygen of the combustion air diffuses through the core of gas surrounding the carbon surface. The identity previously referred to was then used to calculate the amount of oxygen diffusing to the carbon surface on the basis of the heat transfer between the gas stream and the carbon surface. Then in 1921, H. Thoma reversed that procedure; he used diffusion experiments to determine heat-transfer coefficients. Recently Lohrisch has extended this work by experiment. A technically very important application of the identity of heat transfer and diffusion is that of the cooling tower, since in this case both processes occur simultaneously.

  17. Effect of pectins on the mass transfer kinetics of monosaccharides, amino acids, and a corn oil-in-water emulsion in a Franz diffusion cell.

    PubMed

    Espinal-Ruiz, Mauricio; Restrepo-Sánchez, Luz-Patricia; Narváez-Cuenca, Carlos-Eduardo

    2016-10-15

    The effect of high (HMP) and low (LMP) methoxylated pectins (2%w/w) on the rate and extent of the mass transfer of monosaccharides, amino acids, and a corn oil-in-water emulsion across a cellulose membrane was evaluated. A sigmoidal response kinetic analysis was used to calculate both the diffusion coefficients (rate) and the amount of nutrients transferred through the membrane (extent). In all cases, except for lysine, HMP was more effective than LMP in inhibiting both the rate and extent of the mass transfer of nutrients through the membrane. LMP and HMP, e.g., reduced 1.3 and 3.0times, respectively, the mass transfer rate of glucose, as compared to control (containing no pectin), and 1.3 and 1.5times, respectively, the amount of glucose transferred through the membrane. Viscosity, molecular interactions, and flocculation were the most important parameters controlling the mass transfer of electrically neutral nutrients, electrically charged nutrients, and emulsified lipids, respectively. PMID:27173546

  18. Flow Structure and Mass Transfer Investigation of the Turbulized Boundary Layer with Ethanol Evaporation and Diffusion Combustion

    NASA Astrophysics Data System (ADS)

    Volchkov, E. P.; Boyarshinov, B. F.; Titkov, V. I.

    2002-07-01

    Uncertainty of evaluation of each factor (separation laminar-turbulent transition combustion and turbulization) hinders mathematical simulation of the joint effect on gas dynamic and thermal characteristics of the boundary layer. The characteristics may be most reliably determined experimentally. The work objective is the experimental study of the boundary layer structure comparison of the fields of temperature velocity and its pulsation with data on heat and mass transfer.

  19. Mass transport by diffusion

    NASA Technical Reports Server (NTRS)

    Baird, James K.

    1987-01-01

    For the purpose of determining diffusion coefficients as required for electrodeposition studies and other applications, a diaphragm cell and an isothermal water bath were constructed. the calibration of the system is discussed. On the basis of three calibration runs on the diaphram cell, researchers concluded that the cell constant beta equals 0.12 cm -2 . Other calibration runs in progress should permit the cell constant to be determined with an accuracy of one percent.

  20. Cation diffusion in the electrical double layer enhances the mass transfer rates for Sr2+, Co2+ and Zn2+ in compacted illite

    NASA Astrophysics Data System (ADS)

    Glaus, M. A.; Aertsens, M.; Appelo, C. A. J.; Kupcik, T.; Maes, N.; Van Laer, L.; Van Loon, L. R.

    2015-09-01

    Enhanced mass transfer rates have been frequently observed in diffusion studies with alkaline and earth alkaline elements in compacted clay minerals and clay rocks. Whether this phenomenon - often termed surface diffusion - is also relevant for more strongly sorbing species is an open question. We therefore investigated the diffusion of Sr2+, Co2+ and Zn2+ in compacted illite with respect to variations of the concentration of the background electrolyte, pH and carbonate. New experimental techniques were developed in order to avoid artefacts stemming from the confinement of the clay sample. A distinct dependence of the effective diffusion coefficients on the concentration of the background electrolyte was observed for all three elements. A similar correlation was found for the sorption distribution ratio (Rd) derived from tracer breakthrough in the case of Sr2+, while this dependence was much weaker for Co2+ and Zn2+. Model calculations using Phreeqc resulted in a good agreement with the experimental data when it was assumed that the cationic species, present in the electrical double layer (EDL) of the charged clay surface, are mobile. Species bound to the specific surface complexation sites at the clay edges were assumed to be immobile. An assessment of the mobility of the type of cationic elements studied here in argillaceous media thus requires an analysis of their distribution among specifically sorbed surface species and species in the EDL. The normal approach of deriving unknown effective diffusion coefficients from reference values of an uncharged water tracer may significantly underestimate the mobility of metal cations in argillaceous media.

  1. A mass transfer model for the fixed-bed adsorption of ferulic acid onto a polymeric resin: axial dispersion and intraparticle diffusion.

    PubMed

    Davila-Guzman, Nancy E; Cerino-Córdova, Felipe J; Soto-Regalado, Eduardo; Loredo-Cancino, Margarita; Loredo-Medrano, José A; García-Reyes, Refugio B

    2016-08-01

    In this study, amberlite XAD-16 (XAD-16) bed column system was used to remove ferulic acid (FA) from aqueous solutions. Laboratory-scale column experiments were conducted in downflow fixed bed at initial FA concentration of 1 g/L, initial pH 3, and 25°C. The performance of the adsorbent bed under different flow rates (1.3-7.7 mL/min) was studied. The bed utilization efficiency was in the range of 64.64-72.21% at the studied flow rates. A mass transfer model considering both axial dispersion and intraparticle diffusion was developed to predict the breakthrough curves of FA adsorption on XAD-16. This model predicted the experimental data better than Bohart-Adams model and Thomas model, based on the low deviation between predicted and experimental data. The axial dispersion coefficient value varied from 6.45 × 10(-6) to 1.10 × 10(-6) m(2)/s at flow rate from 1.3 to 7.7 mL/min, whereas the intraparticle diffusion coefficient was 1.04 × 10(-10) m(2)/s, being this last resistance the rate-limiting step. In conclusion, axial dispersion and intraparticle diffusion phenomena play the major role in predicting the adsorption of FA onto XAD-16 in fixed-bed columns. PMID:26789835

  2. Geochemical Speciation Mass Transfer

    SciTech Connect

    1985-12-01

    PHREEQC is designed to model geochemical reactions. Based on an ion association aqueous model, PHREEQC can calculate pH, redox potential, and mass transfer as a function of reaction progress. It can be used to describe geochemical processes for both far-field and near-field performance assessment and to evaluate data acquisition needs and test data. It can also calculate the composition of solutions in equilibrium with multiple phases. The data base, including elements, aqueous species, and mineral phases, is independent of the program and is completely user-definable. PHREEQC requires thermodynamic data for each solid, gaseous, or dissolved chemical species being modeled. The two data bases, PREPHR and DEQPAK7, supplied with PHREEQC are for testing purposes only and should not be applied to real problems without first being carefully examined. The conceptual model embodied in PHREEQC is the ion-association model of Pearson and Noronha. In this model a set of mass action equations are established for each ion pair (and controlling solid phases when making mass transfer calculations) along with a set of mass balance equations for each element considered. These sets of equations are coupled using activity coefficient values for each aqueous species and solved using a continued fraction approach for the mass balances combined with a modified Newton-Raphson technique for all other equations. The activity coefficient expressions in PHREEQC include the extended Debye-Huckel, WATEQ Debye-Huckel, and Davies equations from the original United States Geological Survey version of the program. The auxiliary preprocessor program PHTL, which is derived from EQTL, converts EQ3/6 thermodynamic data to PHREEQC format so that the two programs can be compared. PHREEQC can be used to determine solubility limits on the radionuclides present in the waste form. These solubility constraints may be input to the WAPPA leach model.

  3. Geochemical Speciation Mass Transfer

    Energy Science and Technology Software Center (ESTSC)

    1985-12-01

    PHREEQC is designed to model geochemical reactions. Based on an ion association aqueous model, PHREEQC can calculate pH, redox potential, and mass transfer as a function of reaction progress. It can be used to describe geochemical processes for both far-field and near-field performance assessment and to evaluate data acquisition needs and test data. It can also calculate the composition of solutions in equilibrium with multiple phases. The data base, including elements, aqueous species, and mineralmore » phases, is independent of the program and is completely user-definable. PHREEQC requires thermodynamic data for each solid, gaseous, or dissolved chemical species being modeled. The two data bases, PREPHR and DEQPAK7, supplied with PHREEQC are for testing purposes only and should not be applied to real problems without first being carefully examined. The conceptual model embodied in PHREEQC is the ion-association model of Pearson and Noronha. In this model a set of mass action equations are established for each ion pair (and controlling solid phases when making mass transfer calculations) along with a set of mass balance equations for each element considered. These sets of equations are coupled using activity coefficient values for each aqueous species and solved using a continued fraction approach for the mass balances combined with a modified Newton-Raphson technique for all other equations. The activity coefficient expressions in PHREEQC include the extended Debye-Huckel, WATEQ Debye-Huckel, and Davies equations from the original United States Geological Survey version of the program. The auxiliary preprocessor program PHTL, which is derived from EQTL, converts EQ3/6 thermodynamic data to PHREEQC format so that the two programs can be compared. PHREEQC can be used to determine solubility limits on the radionuclides present in the waste form. These solubility constraints may be input to the WAPPA leach model.« less

  4. Determination of convective diffusion heat/mass transfer rates to burner rig test targets comparable in size to cross-stream jet diameter

    NASA Technical Reports Server (NTRS)

    Gokoglu, S. A.; Santoro, G. J.

    1985-01-01

    Two sets of experiments have been performed to be able to predict the convective diffusion heat/mass transfer rates to a cylindrical target whose height and diameter are comparable to, but less than, the diameter of the circular cross-stream jet, thereby simulating the same geometric configuration as a typical burner rig test specimen located in the cross-stream of the combustor exit nozzle. The first set exploits the naphthalene sublimation technique to determine the heat/mass transfer coefficient under isothermal conditions for various flow rates (Reynolds numbers). The second set, conducted at various combustion temperatures and Reynolds numbers, utilized the temperature variation along the surface of the above-mentioned target under steady-state conditions to estimate the effect of cooling (dilution) due to the entrainment of stagnant room temperature air. The experimental information obtained is used to predict high temperature, high velocity corrosive salt vapor deposition rates in burner rigs on collectors that are geometrically the same. The agreement with preliminary data obtained from Na2SO4 vapor deposition experiments is found to be excellent.

  5. Mass Transfer with Chemical Reaction.

    ERIC Educational Resources Information Center

    DeCoursey, W. J.

    1987-01-01

    Describes the organization of a graduate course dealing with mass transfer, particularly as it relates to chemical reactions. Discusses the course outline, including mathematics models of mass transfer, enhancement of mass transfer rates by homogeneous chemical reaction, and gas-liquid systems with chemical reaction. (TW)

  6. Mass transfer in composite catalytic membranes

    SciTech Connect

    Langhendries, G.; Claessens, R.; Baron, G.V.

    1996-12-31

    The partial oxidation of cyclohexane was studied in a composite polymer-zeolite catalytic membrane reactor. In a first step the equilibrium and mass transfer properties (swelling, diffusion and sorption) of dense composite membranes were examined. The swelling behavior of the crosslinked poly(dimethylsiloxane) network was determined for several solvents and related to the differences between the Hildebrand solubility parameters of solvent and polymer. Time lag experiments, which enable us to measure simultaneously diffusion and partition coefficients, were carried out on a dense poly(dimethylsiloxane) membrane. A mathematical model describing the mass transfer behavior of these catalytic membranes was derived and validated with experimental data. Mass transfer through composite catalytic membranes can be predicted using the properties of pure catalyst and polymer material, and a single tortuosity factor. 9 refs., 5 figs., 4 tabs.

  7. Gas mass transfer for stratified flows

    SciTech Connect

    Duffey, R.B.; Hughes, E.D.

    1995-07-01

    We analyzed gas absorption and release in water bodies using existing surface renewal theory. We show a new relation between turbulent momentum and mass transfer from gas to water, including the effects of waves and wave roughness, by evaluating the equilibrum integral turbulent dissipation due to energy transfer to the water from the wind. Using Kolmogoroff turbulence arguments the gas transfer velocity, or mass transfer coefficient, is then naturally and straightforwardly obtained as a non-linear function of the wind speed drag coefficient and the square root of the molecular diffusion coefficient. In dimensionless form, the theory predicts the turbulent Sherwood number to be Sh{sub t} = (2/{radical}{pi}) Sc{sup 1/2}, where Sh{sub t} is based on an integral dissipation length scale in the air. The theory confirms the observed nonlinear variation of the mass transfer coefficient as a function of the wind speed; gives the correct transition with turbulence-centered models for smooth surfaces at low speeds; and predicts experimental data from both laboratory and environmental measurements within the data scatter. The differences between the available laboratory and field data measurements are due to the large differences in the drag coefficient between wind tunnels and oceans. The results also imply that the effect of direct aeration due to bubble entrainment at wave breaking is no more than a 20% increase in the mass transfer for the highest speeds. The theory has importance to mass transfer in both the geophysical and chemical engineering literature.

  8. Gas mass transfer for stratified flows

    SciTech Connect

    Duffey, R.B.; Hughes, E.D.

    1995-06-01

    We analyzed gas absorption and release in water bodies using existing surface renewal theory. We show a new relation between turbulent momentum and mass transfer from gas to water, including the effects of waves and wave roughness, by evaluating the equilibrium integral turbulent dissipation due to energy transfer to the water from the wind. Using Kolmogoroff turbulence arguments the gas transfer velocity, or mass transfer coefficient, is then naturally and straightforwardly obtained as a non-linear function of the wind speed drag coefficient and the square root of the molecular diffusion coefficient. In dimensionless form, the theory predicts the turbulent Sherwood number to be Sh{sub t} = (2/{radical}{pi})Sc{sup 1/2}, where Sh{sub t} is based on an integral dissipation length scale in the air. The theory confirms the observed nonlinear variation of the mass transfer coefficient as a function of the wind speed; gives the correct transition with turbulence-centered models for smooth surfaces at low speeds; and predicts experimental data from both laboratory and environmental measurements within the data scatter. The differences between the available laboratory and field data measurements are due to the large differences in the drag coefficient between wind tunnels and oceans. The results also imply that the effect of direct aeration due to bubble entrainment at wave breaking is no more than a 20% increase in the mass transfer for the highest speeds. The theory has importance to mass transfer in both the geo-physical and chemical engineering literature.

  9. Energy Transfer and Joint Diffusion

    NASA Astrophysics Data System (ADS)

    Pajor-Gyulai, Zs.; Szász, D.

    2012-03-01

    A paradigm model is suggested for describing the diffusive limit of trajectories of two Lorentz disks moving in a finite horizon periodic configuration of smooth, strictly convex scatterers and interacting with each other via elastic collisions. For this model the diffusive limit of the two trajectories is a mixture of joint Gaussian laws (analogous behavior is expected for the mechanical model of two Lorentz disks).

  10. Effect of internal pressure and gas/liquid interface area on the CO mass transfer coefficient using hollow fibre membranes as a high mass transfer gas diffusing system for microbial syngas fermentation.

    PubMed

    Yasin, Muhammad; Park, Shinyoung; Jeong, Yeseul; Lee, Eun Yeol; Lee, Jinwon; Chang, In Seop

    2014-10-01

    This study proposed a submerged hollow fibre membrane bioreactor (HFMBR) system capable of achieving high carbon monoxide (CO) mass transfer for applications in microbial synthesis gas conversion systems. Hydrophobic polyvinylidene fluoride (PVDF) membrane fibres were used to fabricate a membrane module, which was used for pressurising CO in water phase. Pressure through the hollow fibre lumen (P) and membrane surface area per unit working volume of the liquid (A(S)/V(L)) were used as controllable parameters to determine gas-liquid volumetric mass transfer coefficient (k(L)a) values. We found a k(L)a of 135.72 h(-1) when P was 93.76 kPa and AS/VL was fixed at 27.5m(-1). A higher k(L)a of 155.16 h(-1) was achieved by increasing AS/VL to 62.5m(-1) at a lower P of 37.23 kPa. Practicality of HFMBR to support microbial growth and organic product formation was assessed by CO/CO2 fermentation using Eubacterium limosum KIST612. PMID:25105269

  11. Enhancement of heat and mass transfer by cavitation

    NASA Astrophysics Data System (ADS)

    Zhang, Y. N.; Zhang, Y. N.; Du, X. Z.; Xian, H. Z.

    2015-01-01

    In this paper, a brief summary of effects of cavitation on the heat and mass transfer are given. The fundamental studies of cavitation bubbles, including its nonlinearity, rectified heat and mass diffusion, are initially introduced. Then selected topics of cavitation enhanced heat and mass transfer were discussed in details including whales stranding caused by active sonar activity, pool boiling heat transfer, oscillating heat pipe and high intensity focused ultrasound treatment.

  12. Fundamental mass transfer models for indoor air pollution sources

    SciTech Connect

    Tichenor, B.A.; Guo, Z.; Sparks, L.E.

    1993-01-01

    The paper discusses a simple, fundamental mass transfer model, based on Fick's Law of Diffusion, for indoor air pollution wet sorbent-based sources. (Note: Models are needed to predict emissions from indoor sources. While empirical approaches based on dynamic chamber data are useful, a more fundamental approach is needed to fully elucidate the relevant mass transfer processes). In the model, the mass transfer rate is assumed to be gas-phase limited and controlled by the boundary layer mass transfer coefficient, the saturation vapor pressure of the material being emitted, and the mass of volatile material remaining. Results of static and dynamic chamber tests, as well as test house studies, are presented.

  13. Mass partitioning effects in diffusion transport.

    PubMed

    Kojic, Milos; Milosevic, Miljan; Wu, Suhong; Blanco, Elvin; Ferrari, Mauro; Ziemys, Arturas

    2015-08-28

    Frequent mass exchange takes place in a heterogeneous environment among several phases, where mass partitioning may occur at the interface of phases. Analytical and computational methods for diffusion do not usually incorporate molecule partitioning masking the true picture of mass transport. Here we present a computational finite element methodology to calculate diffusion mass transport with a partitioning phenomenon included and the analysis of the effects of partitioning. Our numerical results showed that partitioning controls equilibrated mass distribution as expected from analytical solutions. The experimental validation of mass release from drug-loaded nanoparticles showed that partitioning might even dominate in some cases with respect to diffusion itself. The analysis of diffusion kinetics in the parameter space of partitioning and diffusivity showed that partitioning is an extremely important parameter in systems, where mass diffusivity is fast and that the concentration of nanoparticles can control payload retention inside nanoparticles. The computational and experimental results suggest that partitioning and physiochemical properties of phases play an important, if not crucial, role in diffusion transport and should be included in the studies of mass transport processes. PMID:26204522

  14. Diffusive and thermodiffusive transfer of magnetic nanoparticles in porous media.

    PubMed

    Sints, Viesturs; Blums, Elmars; Maiorov, Michail; Kronkalns, Gunars

    2015-05-01

    Experimental results on mass transfer within a thin porous layer saturated with ferrofluid are outlined in this paper. From the analysis of particle concentration distribution across the layer it is shown that both the mass diffusion and the Soret coefficients of nanoparticles are remarkably less than those measured in free fluid. The particle transport coefficient changes due to an external uniform magnetic field qualitatively well agree with the predictions of existing theoretical research. The magnetic field that is oriented transversely to the porous layer causes an increase in the diffusion coefficient and a decrease in the Soret coefficient whilst the longitudinal field causes a reduction of the mass diffusion and an intensification of the particle thermodiffusion. PMID:25957178

  15. Behavior of the mass transfer zone in a biosorption column.

    PubMed

    Naja, Ghinwa; Volesky, Bohumil

    2006-06-15

    Modeling of the mass transfer zone behavior under variable conditions in a flow-through fixed-bed sorption column enabled the prediction of breakthrough curves for Cu2+ and Ca-preloaded Sargassum fluitans biomass. The mass transfer resistance, particle diffusion, and the axial dispersion were incorporated in the model. The dynamics of the mass transfer zone was described under variable sorption column operating conditions including different column lengths and fluid flow rates. Accurate estimation of the behavior of the mass transfer zone as it progressed through the column, reflected eventually in the breakthrough curve, assisted in its relevant interpretations. Furthermore, the proposed mathematical model of the biosorption process was capable of demonstrating the expanding and broadening of the mass transfer zone linked to the equilibrium sorption isotherm. The fundamental understanding of the mass transfer zone dynamics is particularly important for process scale-up where maintaining the process efficiency is critical. PMID:16830573

  16. In situ study of mass transfer in aqueous solutions under high pressures via Raman spectroscopy: A new method for the determination of diffusion coefficients of methane in water near hydrate formation conditions

    USGS Publications Warehouse

    Lu, W.J.; Chou, I.-Ming; Burruss, R.C.; Yang, M.Z.

    2006-01-01

    A new method was developed for in situ study of the diffusive transfer of methane in aqueous solution under high pressures near hydrate formation conditions within an optical capillary cell. Time-dependent Raman spectra of the solution at several different spots along the one-dimensional diffusion path were collected and thus the varying composition profile of the solution was monitored. Diffusion coefficients were estimated by the least squares method based on the variations in methane concentration data in space and time in the cell. The measured diffusion coefficients of methane in water at the liquid (L)-vapor (V) stable region and L-V metastable region are close to previously reported values determined at lower pressure and similar temperature. This in situ monitoring method was demonstrated to be suitable for the study of mass transfer in aqueous solution under high pressure and at various temperature conditions and will be applied to the study of nucleation and dissolution kinetics of methane hydrate in a hydrate-water system where the interaction of methane and water would be more complicated than that presented here for the L-V metastable condition. ?? 2006 Society for Applied Spectroscopy.

  17. Nanoparticle volume fraction with heat and mass transfer on MHD mixed convection flow in a nanofluid in the presence of thermo-diffusion under convective boundary condition

    NASA Astrophysics Data System (ADS)

    Kandasamy, R.; Jeyabalan, C.; Sivagnana Prabhu, K. K.

    2016-02-01

    This article examines the influence of thermophoresis, Brownian motion of the nanoparticles with variable stream conditions in the presence of magnetic field on mixed convection heat and mass transfer in the boundary layer region of a semi-infinite porous vertical plate in a nanofluid under the convective boundary conditions. The transformed boundary layer ordinary differential equations are solved numerically using Maple 18 software with fourth-fifth order Runge-Kutta-Fehlberg method. Numerical results are presented both in tabular and graphical forms illustrating the effects of these parameters with magnetic field on momentum, thermal, nanoparticle volume fraction and solutal concentration boundary layers. The numerical results obtained for the velocity, temperature, volume fraction, and concentration profiles reveal interesting phenomenon, some of these qualitative results are presented through plots. It is interesting to note that the magnetic field plays a dominant role on nanofluid flow under the convective boundary conditions.

  18. Experiments for the determination of convective diffusion heat/mass transfer to burner rig test targets comparable in size to jet stream diameter

    NASA Technical Reports Server (NTRS)

    Santoro, G. J.; Gokoglu, S. A.

    1986-01-01

    The application of a recently formulated vapor transport theory to predict deposition rates of corrosive salts from alkali-seeded combustion gases of a small-capacity, high-velocity, atmospheric-pressure burner rig was hampered by the relatively large dimensions of the cylindrical deposit collector compared to the diameter of the combustion gas stream. The relative dimensions lead to a highly nonadiabatic combustion gas flow around the collector and necessitate two series of experiments. In the first series, mass transfer coefficients are determined by utilizing the naphthalene sublimation technique. The second series of experiments determines the dilution effect on the sodium species concentrations due to the entrainment of ambient air. This second series involves the measurement of the temperature variation along the surface of the collector under steady state conditions. Vapor deposition rates are determined exploiting this information and the results are found to compare favorably with experimentally obtained rates.

  19. PHREEQC. Geochemical Speciation Mass Transfer

    SciTech Connect

    Parkhurst, D.L.

    1995-01-01

    PHREEQC is designed to model geochemical reactions. Based on an ion association aqueous model, PHREEQC can calculate pH, redox potential, and mass transfer as a function of reaction progress. It can be used to describe geochemical processes for both far-field and near-field performance assessment and to evaluate data acquisition needs and test data. It can also calculate the composition of solutions in equilibrium with multiple phases. The data base, including elements, aqueous species, and mineral phases, is independent of the program and is completely user-definable. PHREEQC requires thermodynamic data for each solid, gaseous, or dissolved chemical species being modeled. The two data bases, PREPHR and DEQPAK7, supplied with PHREEQC are for testing purposes only and should not be applied to real problems without first being carefully examined. The conceptual model embodied in PHREEQC is the ion-association model of Pearson and Noronha. In this model a set of mass action equations are established for each ion pair (and controlling solid phases when making mass transfer calculations) along with a set of mass balance equations for each element considered. These sets of equations are coupled using activity coefficient values for each aqueous species and solved using a continued fraction approach for the mass balances combined with a modified Newton-Raphson technique for all other equations. The activity coefficient expressions in PHREEQC include the extended Debye-Huckel, WATEQ Debye-Huckel, and Davies equations from the original United States Geological Survey version of the program. The auxiliary preprocessor program PHTL, which is derived from EQTL, converts EQ3/6 thermodynamic data to PHREEQC format so that the two programs can be compared. PHREEQC can be used to determine solubility limits on the radionuclides present in the waste form. These solubility constraints may be input to the WAPPA leach model.

  20. Nonstationary Mass Transfer Near the Surface of a Cylindrical Body

    NASA Astrophysics Data System (ADS)

    Rudobashta, S. P.; Kosheleva, M. K.; Kartashov, É. M.

    2015-11-01

    The problem of nonstationary diffusion of the target component to a phase that is external relative to the surface of a cylindrical body has been formulated and solved analytically. From the found solution the dependences have been obtained for calculating the instantaneous mass transfer coefficient and the phase-contact-time mean mass transfer coefficient, on the basis of which the process of extraction of technological pollutants from fibrous materials has been analyzed.

  1. Mass transfer from bypassed zones during gas injection

    SciTech Connect

    Burger, J.E.; Mohanty, K.K.

    1995-12-31

    Gasflooding in oil reservoirs leads to bypassing of the oil due to gravitational, viscous and/or heterogeneity effects. The bypassed oil can be recovered by the flowing solvent by pressure-driven, gravity-driven, dispersion/diffusion-driven and capillarity-driven crossflow/mass transfer. It is difficult to represent all of these mechanisms explicitly in large-scale simulations. In this work, we have studied the effect of the orientation of the bypassed region and the enrichment of the solvent on the mass transfer. Laboratory-scale mass transfer and coreflood experiments were conducted. Numerical simulation was used to identify the role of the different mechanisms. Results indicate that the mass transfer is the least for the vertical orientation, intermediate for the inverted orientation and the highest for the horizontal orientation. The mass transfer increases with enrichment for all orientations. Liquid phase diffusion controls vertical orientation mass transfer for the fluids studied. Phase behavior determines the liquid phase saturation. Capillary pumping does not contribute to the mass transfer of oil because the interfacial tension decreases towards the flowing region. Gravity-driven flow contributes the most to the mass transfer in the horizontal and the inverted orientations. The gravity-driven flow, however, is impeded by the capillarity whose magnitude decreases with solvent enrichment. Oil recovery in the horizontal gasfloods is nonmonotonic with enrichment for this fluid system in an almost homogeneous Berea core. Multiphase flow in the near-miscible floods leads to less gravity override compared to the FCM floods. In the heterogeneous core studied, the heterogeneity is very strong and the capillary forces do not prevent bypassing. The capillary forces, in fact, reduce oil recovery by diminishing mass transfer from the bypassed regions.

  2. Heat and mass transfer in flames

    NASA Technical Reports Server (NTRS)

    Faeth, G. M.

    1986-01-01

    Heat- and mass-transfer processes in turbulent diffusion flames are discussed, considering turbulent mixing and the structure of single-phase flames, drop processes in spray flames, and nonluminous and luminous flame radiation. Interactions between turbulence and other phenomena are emphasized, concentrating on past work of the author and his associates. The conserved-scalar formalism, along with the laminar-flamelet approximation, is shown to provide reasonable estimates of the structure of gas flames, with modest levels of empiricism. Extending this approach to spray flames has highlighted the importance of drop/turbulence interactions; e.g., turbulent dispersion of drops, modification of turbulence by drops, etc. Stochastic methods being developed to treat these phenomena are yielding encouraging results.

  3. FUNDAMENTAL MASS TRANSFER MODELS FOR INDOOR AIR POLLUTION SOURCES

    EPA Science Inventory

    The paper discusses a simple, fundamental mass transfer model, based on Fick's Law of Diffusion, for indoor air pollution wet sorbent-based sources. (Note: Models are needed to predict emissions from indoor sources. hile empirical approaches based on dynamic chamber data are usef...

  4. Calculation of mass transfer in multiphase flow

    SciTech Connect

    Wang, L.; Gopal, M.

    1998-12-31

    This paper summarizes the results of mass transfer mechanisms under disturbed liquid-gas flow in 10 cm diameter pipe using electrochemical limiting current density and potentiostatic noise technique. The solution used is potassium ferro/ferricyanide dissolve in 1.3 N sodium hydroxide system. Mass transfer coefficients in full pipe flow and slug flow are obtained. The relationship between mass transfer coefficient with full pipe flow velocities and with slug flow Froude numbers are studied. The impact of bubbles in slugs on the mass transfer coefficient is revealed, The impact of flow disturbance, including weld beads and pits, are discussed for both full pipe flow and slug flow.

  5. Diffusion model for lightning radiative transfer

    NASA Technical Reports Server (NTRS)

    Koshak, William J.; Solakiewicz, Richard J.; Phanord, Dieudonne D.; Blakeslee, Richard J.

    1994-01-01

    A one-speed Boltzmann transport theory, with diffusion approximations, is applied to study the radiative transfer properties of lightning in optically thick thunderclouds. Near-infrared (lambda = 0.7774 micrometers) photons associated with a prominent oxygen emission triplet in the lightning spectrum are considered. Transient and spatially complex lightning radiation sources are placed inside a rectangular parallelepiped thundercloud geometry and the effects of multiple scattering are studied. The cloud is assumed to be composed of a homogeneous collection of identical spherical water droplets, each droplet a nearly conservative, anisotropic scatterer. Conceptually, we treat the thundercloud like a nuclear reactor, with photons replaced by neutrons, and utilize standard one-speed neutron diffusion techniques common in nuclear reactor analyses. Valid analytic results for the intensity distribution (expanded in spherical harmonics) are obtained for regions sufficiently far from sources. Model estimates of the arrival-time delay and pulse width broadening of lightning signals radiated from within the cloud are determined and the results are in good agreement with both experimental data and previous Monte Carlo estimates. Additional model studies of this kind will be used to study the general information content of cloud top lightning radiation signatures.

  6. Heat and mass transfer intensification in coaxial reactor

    NASA Astrophysics Data System (ADS)

    Ananyev, D. V.; Halitova, G. R.

    2014-04-01

    The work considers heat and mass transfer in the homophasic polymerization reactor. The reactor is a coaxial channel with internal tube in the form of a channel of confusor-diffuser type. The authors compared the degree of polymer transformation in the intensified coaxial reactor with internal tube of confusor-diffuser type and the reactor with constant rectilinear longitudinal section. It was found that in coaxial channels with internal tube of confusor-diffuser type, it is possible to reach high values of the transformation degree and to improve the quality of the obtained polymer.

  7. Diffusion Of Mass In Evaporating Multicomponent Drops

    NASA Technical Reports Server (NTRS)

    Bellan, Josette; Harstad, Kenneth G.

    1992-01-01

    Report summarizes study of diffusion of mass and related phenomena occurring in evaporation of dense and dilute clusters of drops of multicomponent liquids intended to represent fuels as oil, kerosene, and gasoline. Cluster represented by simplified mathematical model, including global conservation equations for entire cluster and conditions on boundary between cluster and ambient gas. Differential equations of model integrated numerically. One of series of reports by same authors discussing evaporation and combustion of sprayed liquid fuels.

  8. How We Make Mass Transfer Seem Difficult.

    ERIC Educational Resources Information Center

    Cussler, E. L.

    1984-01-01

    Indicates that teaching of mass transfer can be improved by: (1) using a single, simple definition of mass transfer coefficients; (2) altering use of analogies; and (3) repeatedly stressing differences between mathematical models used for chemical reactions and the actual chemistry of these reactions. Examples for undergraduate/graduate courses…

  9. Analysis of Heat and Mass Transfer in a Desiccant Rotor

    NASA Astrophysics Data System (ADS)

    Hamamoto, Yoshinori; Murase, Sousuke; Akisawa, Atsushi; Kashiwagi, Takao; Okajima, Jirou; Matsuoka, Fumio

    The study aims at clarifying the local heat and mass transfer in the desiccant rotor, and at obtaining the design aspects of high efficient desiccant rotor and operation method. In the paper, theoretical analysis is performed for rotary dehumidifier. Both surface diffusion and mass transfer coefficient are considered in the model. It is examined that the results of calculation agree well with the experimental data. The local temperature, humidity and the amount of adsorbed water vapor are calculated. It is clarified that temperature and humidity of air in the rotor change clockwise between each inlet air condition on the psychrometric chart. The outlet temperature and humidity distribution of the rotor is clarified in the system showing the optimum rotor speed. Furthermore, it is clarified that local desorption rate is higher than adsorption rate. It is attributed to the increase of mass transfer coefficient and surface diffusivity of the rotor during desorption process. And, it is clarified that the influence of surface diffusion on amount of adsorbed water vapor is much larger than that of mass transfer coefficient.

  10. Heat and mass transfer over slippery, superhydrophobic surfaces

    NASA Astrophysics Data System (ADS)

    Haase, A. Sander; Lammertink, Rob G. H.

    2016-04-01

    The classical Graetz-Nusselt problem is extended to describe heat and mass transfer over heterogeneously slippery, superhydrophobic surfaces. The cylindrical wall consists of segments with a constant temperature/concentration and areas that are insulating/impermeable. Only in the case of mass transport do the locations of hydrodynamic slip and mass exchange coincide. This makes advection near the mass exchanging wall segments larger than near the heat exchanging regions. Also the direction of radial fluid flow is reversed for heat and mass transport, which has an influence on the location where the concentration or temperature boundary layer is compressed or extended. As a result, mass transport is more efficient than heat transfer. Also the influence of axial diffusion on the Nusselt and Sherwood numbers is investigated for various Péclet numbers Pe. When Pe < 102, which is characteristic for heat transfer over superhydrophobic surfaces, axial conduction should be taken into account. For Pe ≥ 102, which are typical numbers for mass transport in microfluidic systems, axial diffusion can be neglected.

  11. Overall Heat and Mass Transfer Coefficient of Water Vapor Adsorption

    NASA Astrophysics Data System (ADS)

    Hamamoto, Yoshinori; Mori, Hideo; Godo, Masazumi; Miura, Kunio; Watanabe, Yutaka; Ishizawa, Toshihiko; Takatsuka, Takeshi

    A fundamental investigation was performed to develop a compact and simple desiccant ventilation unit which is one of the main components of a novel energy saving air-conditioning system. Water vapor in the air is adsorbed and/or desorbed to be controlled the humidity of supply air through a unit of an adsorbent packed bed. A numerical simulation helps to understand the phenomena of heat and mass transfer in the bed. Overall transfer coefficients of them as properties for the simulation were estimated by performing both experiment and calculation. It was clarified that the transient overall equivalent heat and mass transfer does not strongly depend on the air flow rate through the packed bed, the averaged equivalent mass transfer is governed by surface and pore diffusion in a particle of adsorbent at low flow rate. Moreover, the coefficient during the adsorption process is slightly larger than desorption. An equation of the overall mass transfer coefficient is derived. It shows five times as large as the value estimated by experiment. Therefore, the correlation and fitting parameters are presented for prediction of the overall heat and mass transfer coefficients. The estimation accuracy was improved.

  12. Mass and thermal diffusivity algorithms: reduced algorithms for mass and thermal diffusivity determinations.

    PubMed

    Banish, R Michael; Albert, Lyle B J; Pourpoint, Timothee L; Alexander, J Iwan D; Sekerka, Robert F

    2002-10-01

    Mass and thermal diffusivity measurements conducted on Earth are prone to contamination by uncontrollable convective contributions to the overall transport. Previous studies of mass and thermal diffusivities conducted on spacecraft have demonstration the gain in precision, and lower absolute values, resulting from the reduced convective transport possible in a low-gravity environment. We have developed and extensively tested real-time techniques for diffusivity measurements, where several measurements may be obtained on a single sample. This is particularly advantageous for low gravity research were there is limited experiment time. The mass diffusivity methodology uses a cylindrical sample geometry. A radiotracer, initially located at one end of the host is used as the diffusant. The sample is positioned in a concentric isothermal radiation shield with collimation bores located at defined positions along its axis. The intensity of the radiation emitted through the collimators is measured versus time with solid-state detectors and associated energy discrimination electronics. For the mathematical algorithm that we use, only a single pair of collimation bores and detectors are necessary for single temperature measurements. However, by employing a second, offset, pair of collimation holes and radiation detectors, diffusivities can be determined at several temperatures per sample. For thermal diffusivity measurements a disk geometry is used. A heat pulse is applied in the center of the sample and the temperature response of the sample is measured at several locations. Thus, several values of the diffusivity are measured versus time. The exact analytic solution to a heat pulse in the disk geometry leads to a unique heated area and measurement locations. Knowledge of the starting time and duration of he heating pulse is not used in the data evaluation. Thus, this methodology represents an experimentally simpler and more robust scheme. PMID:12446321

  13. Ozone mass transfer and kinetics experiments

    SciTech Connect

    Bollyky, L.J.; Beary, M.M.

    1981-12-01

    Experiments were conducted at the Hanford Site to determine the most efficient pH and temperature levels for the destruction of complexants in Hanford high-level defense waste. These complexants enhance migration of radionuclides in the soil and inhibit the growth of crystals in the evaporator-crystallizer. Ozone mass transfer and kinetics tests have been outlined for the determination of critical mass transfer and kinetics parameters of the ozone-complexant reaction.

  14. Mass transfer cycles in cataclysmic variables

    NASA Technical Reports Server (NTRS)

    King, A. R.; Frank, J.; Kolb, U.; Ritter, H.

    1995-01-01

    It is well known that in cataclysmic variables the mass transfer rate must fluctuate about the evolutionary mean on timescales too long to be directly observable. We show that limit-cycle behavior can occur if the radius change of the secondary star is sensitive to the instantaneous mass transfer rate. The only reasonable way in which such a dependence can arise is through irradiation of this star by the accreting component. The system oscillates between high states, in which irradiation causes slow expansion of the secondary and drives an elevated transfer rate, and low states, in which this star contracts.

  15. QUANTIFYING DIFFUSIVE MASS TRANSFER IN FRACTURED SHALEBEDROCK

    EPA Science Inventory

    A significant limitation in defining remediation needs at contaminated sites often results from aninsufficient understanding of the transport processes that control contaminant migration. Theobjectives of this research were to help resolve this dilemma by providing an improved...

  16. Mass transfer effects in a gasification riser

    SciTech Connect

    Breault, Ronald W; Li, Tingwen; Nicoletti, Phillip

    2013-01-01

    In the development of multiphase reacting computational fluid dynamics (CFD) codes, a number of simplifications were incorporated into the codes and models. One of these simplifications was the use of a simplistic mass transfer correlation for the faster reactions and omission of mass transfer effects completely on the moderate speed and slow speed reactions such as those in a fluidized bed gasifier. Another problem that has propagated is that the mass transfer correlation used in the codes is not universal and is being used far from its developed bubbling fluidized bed regime when applied to circulating fluidized bed (CFB) riser reactors. These problems are true for the major CFD codes. To alleviate this problem, a mechanistic based mass transfer coefficient algorithm has been developed based upon an earlier work by Breault et al. This fundamental approach uses the local hydrodynamics to predict a local, time varying mass transfer coefficient. The predicted mass transfer coefficients and the corresponding Sherwood numbers agree well with literature data and are typically about an order of magnitude lower than the correlation noted above. The incorporation of the new mass transfer model gives the expected behavior for all the gasification reactions evaluated in the paper. At the expected and typical design values for the solid flow rate in a CFB riser gasifier an ANOVA analysis has shown the predictions from the new code to be significantly different from the original code predictions. The new algorithm should be used such that the conversions are not over predicted. Additionally, its behaviors with changes in solid flow rate are consistent with the changes in the hydrodynamics.

  17. Role of diffusion in excitation energy transfer and migration

    NASA Astrophysics Data System (ADS)

    Misra, V.; Mishra, H.

    2007-09-01

    Effect of diffusion on excitation energy transfer and migration in a dye pair sodium fluorescein (donor) and Rhodamine-6G (acceptor) has been studied for different viscosities by both steady state and time domain fluorescence spectroscopic measurements. The donor-donor interaction appears to be weaker as compared to donor-acceptor interaction and thus favors direct Förster-type energy transfer. Interestingly, at low viscosity (water in this case) transfer appears to be controlled by material diffusion/energy migration. Further, acceptor dynamics reveals the fact that direct Förster transfer dominates in viscous media.

  18. Theory of exciton transfer and diffusion in conjugated polymers

    SciTech Connect

    Barford, William; Tozer, Oliver Robert

    2014-10-28

    We describe a theory of Förster-type exciton transfer between conjugated polymers. The theory is built on three assumptions. First, we assume that the low-lying excited states of conjugated polymers are Frenkel excitons coupled to local normal modes, and described by the Frenkel-Holstein model. Second, we assume that the relevant parameter regime is ℏω < J, i.e., the adiabatic regime, and thus the Born-Oppenheimer factorization of the electronic and nuclear degrees of freedom is generally applicable. Finally, we assume that the Condon approximation is valid, i.e., the exciton-polaron wavefunction is essentially independent of the normal modes. The resulting expression for the exciton transfer rate has a familiar form, being a function of the exciton transfer integral and the effective Franck-Condon factors. The effective Franck-Condon factors are functions of the effective Huang-Rhys parameters, which are inversely proportional to the chromophore size. The Born-Oppenheimer expressions were checked against DMRG calculations, and are found to be within 10% of the exact value for a tiny fraction of the computational cost. This theory of exciton transfer is then applied to model exciton migration in conformationally disordered poly(p-phenylene vinylene). Key to this modeling is the assumption that the donor and acceptor chromophores are defined by local exciton ground states (LEGSs). Since LEGSs are readily determined by the exciton center-of-mass wavefunction, this theory provides a quantitative link between polymer conformation and exciton migration. Our Monte Carlo simulations indicate that the exciton diffusion length depends weakly on the conformation of the polymer, with the diffusion length increasing slightly as the chromophores became straighter and longer. This is largely a geometrical effect: longer and straighter chromophores extend over larger distances. The calculated diffusion lengths of ∼10 nm are in good agreement with experiment. The spectral

  19. Discrete diffusion Monte Carlo for frequency-dependent radiative transfer

    SciTech Connect

    Densmore, Jeffrey D; Kelly, Thompson G; Urbatish, Todd J

    2010-11-17

    Discrete Diffusion Monte Carlo (DDMC) is a technique for increasing the efficiency of Implicit Monte Carlo radiative-transfer simulations. In this paper, we develop an extension of DDMC for frequency-dependent radiative transfer. We base our new DDMC method on a frequency-integrated diffusion equation for frequencies below a specified threshold. Above this threshold we employ standard Monte Carlo. With a frequency-dependent test problem, we confirm the increased efficiency of our new DDMC technique.

  20. Mass Transfer Enhancement in Moving Biofilm Structures

    PubMed Central

    Taherzadeh, Danial; Picioreanu, Cristian; Horn, Harald

    2012-01-01

    Biofilms are layers of microbial cells growing on an interface and they can form highly complex structures adapted to a wide variety of environmental conditions. Biofilm streamers have a small immobile base attached to the support and a flexible tail elongated in the flow direction, which can vibrate in fast flows. Herein we report numerical results for the role of the periodical movement of biofilm streamers on the nutrient uptake and in general on the solute mass transfer enhancement due to flow-induced oscillations. We developed what to our knowledge is a novel two-dimensional fluid-structure interaction model coupled to unsteady solute mass transport and solved the model using the finite element method with a moving mesh. Results demonstrate that the oscillatory movement of the biofilm tail significantly increases the substrate uptake. The mass transfer coefficient is the highest in regions close to the streamer tip. The reason for substrate transfer enhancement is the increase in speed of tip movement relative to the surrounding liquid, thereby reducing the thickness of the mass transfer boundary layer. In addition, we show that the relative mass transfer enhancement in unsteady conditions compared with the rigid static structure is larger at higher flow velocities, and this relative increase favors a more flexible structure. PMID:22500748

  1. Educational Policy Diffusion and Transfer: The Case of Armenia

    ERIC Educational Resources Information Center

    Karakhanyan, Susanna; van Veen, Klaas; Bergen, Theo

    2011-01-01

    This paper explores the quality of the implementation of the West European Bologna reforms in higher education in a post-soviet country. This process of policy diffusion is analysed using concepts of policy diffusion/transfer and innovation literature, attempting to combine both streams of literature. Despite strong motivation to improve the…

  2. Calculating Mass Diffusion in High-Pressure Binary Fluids

    NASA Technical Reports Server (NTRS)

    Bellan, Josette; Harstad, Kenneth

    2004-01-01

    A comprehensive mathematical model of mass diffusion has been developed for binary fluids at high pressures, including critical and supercritical pressures. Heretofore, diverse expressions, valid for limited parameter ranges, have been used to correlate high-pressure binary mass-diffusion-coefficient data. This model will likely be especially useful in the computational simulation and analysis of combustion phenomena in diesel engines, gas turbines, and liquid rocket engines, wherein mass diffusion at high pressure plays a major role.

  3. Effect of radiation heat transfer on thermal diffusivity measurements

    NASA Astrophysics Data System (ADS)

    Araki, N.

    1990-03-01

    Experimental data on thermal conductivity and thermal diffusivity of a semitransparent material generally include an error due to the radiation heat transfer. This error varies in accordance with the experimental conditions such as the temperature level of the sample and the measuring method. In this paper, research on the influence of radiation heat transfer on thermal diffusivity are reviewed, and as an example, the method to correct the radiation component in the apparent thermal diffusivity measured by the stepwise heating technique is presented. The transient heat transfer by simultaneous thermal conduction and radiation in a semitransparent material is analyzed when the front surface is subjected to stepwise heating. The apparent thermal diffusivity, which includes the radiation component, is calculated for various parameters.

  4. Thermodynamic evaluation of mass diffusion in ionic mixtures

    SciTech Connect

    Kagan, Grigory; Tang, Xian-Zhu

    2014-02-15

    The thermodynamic technique of Landau and Lifshitz originally developed for inter-species diffusion in a binary neutral gas mixture is extended to a quasi-neutral plasma with two ion species. It is shown that, while baro- and electro-diffusion coefficients depend on the choice of the thermodynamic system, prediction for the total diffusive mass flux is invariant.

  5. Overall Heat and Mass Transfer Coefficient of Water Vapor Adsorption

    NASA Astrophysics Data System (ADS)

    Hamamoto, Yoshinori; Mori, Hideo; Godo, Masazumi; Miura, Kunio; Watanabe, Yutaka; Ishizawa, Toshihiko; Takatsuka, Takeshi

    A fundamental investigation was performed to develop a compact and simple desiccant ventilation unit which is one of the main components of a novel energy saving air-conditioning system. Water vapor in the air is adsorbed and/or desorbed to be controlled the humidity of supply air through a unit of an adsorbent rotor. A numerical simulation helps to understand the phenomena of heat and mass transfer in the rotor block. Overall transfer coefficients were estimated by performing both experiment and calculation. It was examined that the transient overall equivalent heat and mass transfer coefficient was not constant. It seems that both film fluid and diffusion resistance govern the coefficients in the block, and the influence of air flow on the time averaged coefficients is estimated by a considering the laminar forced convection from a flat plate. There is little difference of the coefficient between adsorption and desorption process. The correlation and fitting parameters are presented for prediction of the overall heat and mass transfer coefficients. The estimation accuracy was improved.

  6. Non-conservative mass transfers in Algols

    NASA Astrophysics Data System (ADS)

    Erdem, A.; Öztürk, O.

    2014-06-01

    We applied a revised model for non-conservative mass transfer in semi-detached binaries to 18 Algol-type binaries showing orbital period increase or decrease in their parabolic O-C diagrams. The combined effect of mass transfer and magnetic braking due to stellar wind was considered when interpreting the orbital period changes of these 18 Algols. Mass transfer was found to be the dominant mechanism for the increase in orbital period of 10 Algols (AM Aur, RX Cas, DK Peg, RV Per, WX Sgr, RZ Sct, BS Sct, W Ser, BD Vir, XZ Vul) while magnetic braking appears to be the responsible mechanism for the decrease in that of 8 Algols (FK Aql, S Cnc, RU Cnc, TU Cnc, SX Cas, TW Cas, V548 Cyg, RY Gem). The peculiar behaviour of orbital period changes in three W Ser-type binary systems (W Ser, itself a prototype, RX Cas and SX Cas) is discussed. The empirical linear relation between orbital period (P) and its rate of change (dP/dt) was also revised.

  7. Proton Transfer Reaction Ion Trap Mass Spectrometer

    SciTech Connect

    Prazeller, Peter; Palmer, Peter T.; Boscaini, Elena; Jobson, B Tom T.; Alexander, M. Lizabeth

    2003-06-11

    Proton transfer reaction mass spectrometry is a relatively new field that has attracted a great deal of interest in the last few years. This technique uses H₃Oþ as a chemical ionization (CI) reagent to measure volatile organic compounds (VOCs) in the parts per billion by volume (ppbv) to parts per trillion by volume (pptv) range. Mass spectra acquired with a proton transfer reaction mass spectrometer (PTR-MS) are simple because proton transfer chemical ionization is ‘soft’ and results in little or no fragmentation. Unfortunately, peak identification can still be difficult due to isobaric interferences. A possible solution to this problem is to couple the PTR drift tube to an ion trap mass spectrometer (ITMS). The use of an ITMS is appealing because of its ability to perform MS/MS and possibly distinguish between isomers and other isobars. Additionally, the ITMS duty cycle is much higher than that of a linear quadrupole so faster data acquisition rates are possible that will allow for detection of multiple compounds. Here we present the first results from a proton transfer reaction ion trap mass spectrometer (PTR-ITMS). The aim of this study was to investigate ion injection and storage efficiency of a simple prototype instrument in order to estimate possible detection limits of a second-generation instrument. Using this prototype a detection limit of 100 ppbv was demonstrated. Modifications are suggested that will enable further reduction in detection limits to the low-ppbv to high-pptv range. Furthermore, the applicability of MS/MS in differentiating between isobaric species was determined. MS/MS spectra of the isobaric compounds methyl vinyl ketone (MVK) and methacrolein (MACR) are presented and show fragments of different mass making differentiation possible, even when a mixture of both species is present in the same sample. However, MS/MS spectra of acetone and propanal produce fragments with the same molecular masses but with different intensity ratios

  8. Heat and mass transfer in materials processing

    NASA Astrophysics Data System (ADS)

    Tanasawa, Ichiro; Lior, Noam

    Various papers on heat and mass transfer in materials processing are presented. The topics addressed include: heat transfer in plasma spraying, structure of ultrashort pulse plasma for CVD processing, heat flow and thermal contraction during plasma spray deposition, metal melting process by laser heating, improved electron beam weld design and control with beam current profile measurements, transport phenomena in laser materials processing, perspectives on integrated modeling of transport processes in semiconductor crystal growth, numerical simulation of natural convection in crystal growth in space and on the earth, conjugate heat transfer in crystal growth, effects of convection on the solidification of binary mixtures. Also discussed are: heat transfer in in-rotating-liquid-spinning process, thermal oscillations in materials processing, modeling and simulation of manufacturing processes of advanced composite materials, reaction engineering principles of combustion synthesis of advanced materials, numerical evaluation of the physical properties of magnetic fluids suitable for heat transfer control, and measurement techniques of thermophysical properties of high temperature melts. (For individual items see A93-10827 to A93-10843)

  9. Geoelectrical Measurement of Multi-Scale Mass Transfer Parameters

    SciTech Connect

    Day-Lewis, Frederick; Singha, Kamini; Haggerty, Roy; Johnson, Tim; Binley, Andrew; Lane, John

    2014-01-16

    measure mass transfer in-situ and estimate multi-scale and spatially variable mass-transfer parameters. The current lack of such techniques results in large parameter uncertainty, which in turn translates into enormous prediction uncertainty and cost to DOE. In this project, we considered three hydrogeophysical approaches for providing information about mass-transfer parameters: (1) the combination of electrical-resistivity tomography (ERT) and ionic tracer experiments to explore rates of exchange and relative mobile and immobile porosities; (2) complex resistivity (CR) measurements to infer the distribution of diffusive length scales active in a porous medium; and (3) nuclear magnetic resonance (NMR) to estimate mobile and immobile porosity.

  10. Proton Transfer Reaction Ion Trap Mass Spectrometer

    SciTech Connect

    Prazeller, Peter; Palmer, Peter T.; Boscaini, Elena; Jobson, B Tom; Alexander, M. Lizabeth

    2003-07-07

    Proton Transfer Reaction Mass Spectrometry (PTR-MS) is a relatively new field that has attracted a great deal of interest in the last several years. This technique uses H3O+ as a chemical ionization (CI) agent for measuring volatile organic compounds (VOCs) in the parts per billion by volume (ppbv) - parts per trillion by volume (pptv) range. PTR-MS mass spectra are simple because the ionization method of proton transfer is “soft”, resulting in little or no fragmentation. Unfortunately, the simplicity of the mass spectra can cause problems in peak identification due to isobaric interferences. A possible solution to this problem is to couple the PTR drift tube to an ion trap mass spectrometer (ITMS). ITMS is appealing because of the ability to perform MS/MS and possibly distinguish between isomers and other isobars. Additionally, the ITMS duty cycle is much higher than that of a linear quadrupole so faster data acquisition rates can be realized for detection of multiple compounds. We present here the first results from a Proton Transfer Reaction Ion Trap Mass Spectrometer (PTR-ITMS). The aim of this study was to investigate ion injection and storage efficiency of a simple prototype interface in order to estimate possible detection limits of a second generation instrument. Using this prototype a detection limit of 100 ppbv was demonstrated for the PTR-ITMS. Modifications are suggested that will enable further reduction in detection limits to the low ppbv to pptv range. Furthermore the applicability of MS/MS to differentiate between isobaric species was determined. MS/MS spectra of the isobaric compounds methyl vinyl ketone (MVK) and methacrolein (MACR) are presented and show fragments of different mass making a differentiation possible even when a mixture of both species is present in the same sample. MS/MS spectra of acetone and propanal produce fragments with the same molecular weight but different ratios, allowing quantitative distinction only if one species

  11. Orbital Transfer Vehicle Engine Technology High Velocity Ratio Diffusing Crossover

    NASA Technical Reports Server (NTRS)

    Lariviere, Brian W.

    1992-01-01

    High speed, high efficiency head rise multistage pumps require continuous passage diffusing crossovers to effectively convey the pumped fluid from the exit of one impeller to the inlet of the next impeller. On Rocketdyne's Orbital Transfer Vehicle (OTV), the MK49-F, a three stage high pressure liquid hydrogen turbopump, utilizes a 6.23 velocity ratio diffusing crossover. This velocity ratio approaches the diffusion limits for stable and efficient flow over the operating conditions required by the OTV system. The design of the high velocity ratio diffusing crossover was based on advanced analytical techniques anchored by previous tests of stationary two-dimensional diffusers with steady flow. To secure the design and the analytical techniques, tests were required with the unsteady whirling characteristics produced by an impeller. A tester was designed and fabricated using a 2.85 times scale model of the MK49-F turbopumps first stage, including the inducer, impeller, and the diffusing crossover. Water and air tests were completed to evaluate the large scale turbulence, non-uniform velocity, and non-steady velocity on the pump and crossover head and efficiency. Suction performance tests from 80 percent to 124 percent of design flow were completed in water to assess these pump characteristics. Pump and diffuser performance from the water and air tests were compared with the actual MK49-F test data in liquid hydrogen.

  12. 43 CFR 3106.4-3 - Mass transfers.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 43 Public Lands: Interior 2 2011-10-01 2011-10-01 false Mass transfers. 3106.4-3 Section 3106.4-3... or Otherwise § 3106.4-3 Mass transfers. (a) A mass transfer may be utilized in lieu of the provisions... large number of Federal leases to the same transferee. (b) Three originally executed copies of the...

  13. 43 CFR 3106.4-3 - Mass transfers.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 43 Public Lands: Interior 2 2013-10-01 2013-10-01 false Mass transfers. 3106.4-3 Section 3106.4-3... or Otherwise § 3106.4-3 Mass transfers. (a) A mass transfer may be utilized in lieu of the provisions... large number of Federal leases to the same transferee. (b) Three originally executed copies of the...

  14. 43 CFR 3106.4-3 - Mass transfers.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 43 Public Lands: Interior 2 2012-10-01 2012-10-01 false Mass transfers. 3106.4-3 Section 3106.4-3... or Otherwise § 3106.4-3 Mass transfers. (a) A mass transfer may be utilized in lieu of the provisions... large number of Federal leases to the same transferee. (b) Three originally executed copies of the...

  15. 43 CFR 3106.4-3 - Mass transfers.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 43 Public Lands: Interior 2 2014-10-01 2014-10-01 false Mass transfers. 3106.4-3 Section 3106.4-3... or Otherwise § 3106.4-3 Mass transfers. (a) A mass transfer may be utilized in lieu of the provisions... large number of Federal leases to the same transferee. (b) Three originally executed copies of the...

  16. The diffusion approximation. An application to radiative transfer in clouds

    NASA Technical Reports Server (NTRS)

    Arduini, R. F.; Barkstrom, B. R.

    1976-01-01

    It is shown how the radiative transfer equation reduces to the diffusion equation. To keep the mathematics as simple as possible, the approximation is applied to a cylindrical cloud of radius R and height h. The diffusion equation separates in cylindrical coordinates and, in a sample calculation, the solution is evaluated for a range of cloud radii with cloud heights of 0.5 km and 1.0 km. The simplicity of the method and the speed with which solutions are obtained give it potential as a tool with which to study the effects of finite-sized clouds on the albedo of the earth-atmosphere system.

  17. Heat and mass transfer in multi-porous cavity

    SciTech Connect

    Saghir, M.Z.

    1998-10-01

    The study of heat and mass transfer in porous media has a large number of applications in the areas of environmental geothermal and petroleum engineering. Problems such as the disposal of waste material and groundwater contamination are only few applications of the present work. When heat and species transfer takes place within a fluid layer, the temperature and concentration gradients create a convection mode. This phenomenon is called double-diffusive convection. In this paper, two-dimensional non-linear double diffusive convection in a multiporous cavity is considered. The Darcy equation, including Brinkman term to account for the viscous effects, is used as the momentum equation. The model consists of two rectangular cavities filled with glass beads having a diameter d{sub 1} of either 5.25 mm (Case 1) or 3.25 mm (Case 2). The smaller cavity is located at the top left corner of the larger one. The larger cavity is filled initially with hot salty fluid while the smaller one contains initially cold fresh fluid. At the initial time, the obstacle between the two cavities was released and the double diffusive phenomena were studied in details. The momentum, solutal, energy and continuity equations are solved numerically using the finite element technique. This transient problem is solved for two different Darcy numbers. For each Darcy number, the influence of the solutal Rayleigh number on double diffusive convection was studied in details. The permeability in the horizontal and vertical direction was assumed identical. A comparison of the intruding force between this case and the open flow case studied by Saghir et al. showed that it is inversely proportional to the Darcy number. Finite element modeling results indicate that salinity induces stronger convection than the thermal ones.

  18. Interrupted Binary Mass Transfer in Star Clusters

    NASA Astrophysics Data System (ADS)

    Leigh, Nathan W. C.; Geller, Aaron M.; Toonen, Silvia

    2016-02-01

    Binary mass transfer (MT) is at the forefront of some of the most exciting puzzles of modern astrophysics, including SNe Ia, gamma-ray bursts, and the formation of most observed exotic stellar populations. Typically, the evolution is assumed to proceed in isolation, even in dense stellar environments such as star clusters. In this paper, we test the validity of this assumption via the analysis of a large grid of binary evolution models simulated with the SeBa code. For every binary, we calculate analytically the mean time until another single or binary star comes within the mean separation of the mass-transferring binary, and compare this timescale to the mean time for stable MT to occur. We then derive the probability for each respective binary to experience a direct dynamical interruption. The resulting probability distribution can be integrated to give an estimate for the fraction of binaries undergoing MT that are expected to be disrupted as a function of the host cluster properties. We find that for lower-mass clusters (≲ {10}4 {M}⊙ ), on the order of a few to a few tens of percent of binaries undergoing MT are expected to be interrupted by an interloping single, or more often binary, star, over the course of the cluster lifetime, whereas in more massive globular clusters we expect \\ll 1% to be interrupted. Furthermore, using numerical scattering experiments performed with the FEWBODY code, we show that the probability of interruption increases if perturbative fly-bys are considered as well, by a factor ˜2.

  19. A mass transfer model for VOC emission from silage

    NASA Astrophysics Data System (ADS)

    Hafner, Sasha D.; Montes, Felipe; Rotz, C. Alan

    2012-07-01

    Silage has been shown to be an important source of emissions of volatile organic compounds (VOCs), which contribute to the formation of ground-level ozone. Measurements have shown that environmental conditions and silage properties strongly influence emission rates, making it difficult to assess the contribution of silage in VOC emission inventories. In this work, we present an analytical convection-diffusion-dispersion model for predicting emission of VOCs from silage. It was necessary to incorporate empirical relationships from wind tunnel trials for the response of mass transfer parameters to surface air velocity and silage porosity. The resulting model was able to accurately predict the effect of temperature on ethanol emission in wind tunnel trials, but it over-predicted alcohol and aldehyde emission measured using a mass balance approach from corn silage samples outdoors and within barns. Mass balance results confirmed that emission is related to gas-phase porosity, but the response to air speed was not clear, which was contrary to wind tunnel results. Mass balance results indicate that alcohol emission from loose silage on farms may approach 50% of the initial mass over six hours, while relative losses of acetaldehyde will be greater.

  20. The electronic transfer of information and aerospace knowledge diffusion

    NASA Technical Reports Server (NTRS)

    Pinelli, Thomas E.; Bishop, Ann P.; Barclay, Rebecca O.; Kennedy, John M.

    1992-01-01

    Increasing reliance on and investment in information technology and electronic networking systems presupposes that computing and information technology will play a motor role in the diffusion of aerospace knowledge. Little is known, however, about actual information technology needs, uses, and problems within the aerospace knowledge diffusion process. The authors state that the potential contributions of information technology to increased productivity and competitiveness will be diminished unless empirically derived knowledge regarding the information-seeking behavior of the members of the social system - those who are producing, transferring, and using scientific and technical information - is incorporated into a new technology policy framework. Research into the use of information technology and electronic networks by U.S. aerospace engineers and scientists, collected as part of a research project designed to study aerospace knowledge diffusion, is presented in support of this assertion.

  1. A microscale turbine driven by diffusive mass flux.

    PubMed

    Yang, Mingcheng; Liu, Rui; Ripoll, Marisol; Chen, Ke

    2015-10-01

    An external diffusive mass flux is shown to be able to generate a mechanical torque on a microscale object based on anisotropic diffusiophoresis. In light of this finding, we propose a theoretical prototype micro-turbine driven purely by diffusive mass flux, which is in strong contrast to conventional turbines driven by convective mass flows. The rotational velocity of the proposed turbine is determined by the external concentration gradient, the geometry and the diffusiophoretic properties of the turbine. This scenario is validated by performing computer simulations. Our finding thus provides a new type of chemo-mechanical response which could be used to exploit existing chemical energies at small scales. PMID:26288078

  2. Mathematical modeling heat and mass transfer processes in porous media

    NASA Astrophysics Data System (ADS)

    Akhmed-Zaki, Darkhan

    2013-11-01

    On late development stages of oil-fields appears a complex problem of oil-recovery reduction. One of solution approaches is injecting of surfactant together with water in the form of active impurities into the productive layer - for decreasing oil viscosity and capillary forces between ``oil-water'' phases system. In fluids flow the surfactant can be in three states: dissolved in water, dissolved in oil and adsorbed on pore channels' walls. The surfactant's invasion into the reservoir is tracked by its diffusion with reservoir liquid and mass-exchange with two phase (liquid and solid) components of porous structure. Additionally, in this case heat exchange between fluids (injected, residual) and framework of porous medium has practical importance for evaluating of temperature influences on enhancing oil recovery. Now, the problem of designing an adequate mathematical model for describing a simultaneous flowing heat and mass transfer processes in anisotropic heterogeneous porous medium -surfactant injection during at various temperature regimes has not been fully researched. In this work is presents a 2D mathematical model of surfactant injections into the oil reservoir. Description of heat- and mass transfer processes in a porous media is done through differential and kinetic equations. For designing a computational algorithm is used modify version of IMPES method. The sequential and parallel computational algorithms are developed using an adaptive curvilinear meshes which into account heterogeneous porous structures. In this case we can evaluate the boundaries of our process flows - fronts (``invasion'', ``heat'' and ``mass'' transfers), according to the pressure, temperature, and concentration gradient changes.

  3. Simultaneous Heat and Mass Transfer Model for Convective Drying of Building Material

    NASA Astrophysics Data System (ADS)

    Upadhyay, Ashwani; Chandramohan, V. P.

    2016-06-01

    A mathematical model of simultaneous heat and moisture transfer is developed for convective drying of building material. A rectangular brick is considered for sample object. Finite-difference method with semi-implicit scheme is used for solving the transient governing heat and mass transfer equation. Convective boundary condition is used, as the product is exposed in hot air. The heat and mass transfer equations are coupled through diffusion coefficient which is assumed as the function of temperature of the product. Set of algebraic equations are generated through space and time discretization. The discretized algebraic equations are solved by Gauss-Siedel method via iteration. Grid and time independent studies are performed for finding the optimum number of nodal points and time steps respectively. A MATLAB computer code is developed to solve the heat and mass transfer equations simultaneously. Transient heat and mass transfer simulations are performed to find the temperature and moisture distribution inside the brick.

  4. Effects of Rate-Limited Mass Transfer on Modeling Vapor Intrusion with Aerobic Biodegradation.

    PubMed

    Chen, Yiming; Hou, Deyi; Lu, Chunhui; Spain, Jim C; Luo, Jian

    2016-09-01

    Most of the models for simulating vapor intrusion accept the local equilibrium assumption for multiphase concentration distributions, that is, concentrations in solid, liquid and vapor phases are in equilibrium. For simulating vapor transport with aerobic biodegradation controlled by counter-diffusion processes, the local equilibrium assumption combined with dual-Monod kinetics and biomass decay may yield near-instantaneous behavior at steady state. The present research investigates how predicted concentration profiles and fluxes change as interphase mass transfer resistances are increased for vapor intrusion with aerobic biodegradation. Our modeling results indicate that the attenuation coefficients for cases with and without mass transfer limitations can be significantly different by orders of magnitude. Rate-limited mass transfer may lead to larger overlaps of contaminant vapor and oxygen concentrations, which cannot be simulated by instantaneous reaction models with local equilibrium mass transfer. In addition, the contaminant flux with rate-limited mass transfer is much smaller than that with local equilibrium mass transfer, indicating that local equilibrium mass transfer assumption may significantly overestimate the biodegradation rate and capacity for mitigating vapor intrusion through the unsaturated zone. Our results indicate a strong research need for field tests to examine the validity of local equilibrium mass transfer, a widely accepted assumption in modeling vapor intrusion. PMID:27486832

  5. Mass transfer kinetics during osmotic dehydration of pomegranate arils.

    PubMed

    Mundada, Manoj; Hathan, Bahadur Singh; Maske, Swati

    2011-01-01

    The mass transfer kinetics during osmotic dehydration of pomegranate arils in osmotic solution of sucrose was studied to increase palatability and shelf life of arils. The freezing of the whole pomegranate at -18 °C was carried out prior to osmotic dehydration to increase the permeability of the outer cellular layer of the arils. The osmotic solution concentrations used were 40, 50, 60°Bx, osmotic solution temperatures were 35, 45, 55 °C. The fruit to solution ratio was kept 1:4 (w/w) during all the experiments and the process duration varied from 0 to 240 min. Azuara model and Peleg model were the best fitted as compared to other models for water loss and solute gain of pomegranate arils, respectively. Generalized Exponential Model had an excellent fit for water loss ratio and solute gain ratio of pomegranate arils. Effective moisture diffusivity of water as well as solute was estimated using the analytical solution of Fick's law of diffusion. For above conditions of osmotic dehydration, average effective diffusivity of water loss and solute gain varied from 2.718 × 10(-10) to 5.124 × 10(-10) m(2)/s and 1.471 × 10(-10) to 5.147 × 10(-10) m(2)/s, respectively. The final product was successfully utilized in some nutritional formulations such as ice cream and bakery products. PMID:21535673

  6. USINT. Heat and Mass Transfer In Concrete

    SciTech Connect

    Eyberger, L.R.

    1989-12-01

    USINT was developed to model the thermal response of concrete to very high heating rates such as might occur from sodium spills on concrete surfaces in a breeder reactor. The major phenomena treated are conductive energy transport; chemical decomposition of concrete; and two-phase, three-component heat and mass transfer of the decomposition products: steam, liquid water, and carbon dioxide. The USINT model provides for porosity to increase as water and carbon-dioxide are formed from the concrete. The concrete is treated generally as divided into two basic regions, wet and dry. In the wet region, steam, carbon-dioxide, and liquid water may co-exist, but in the dry region, there is no liquid water. There is also the possibility of a third region in which there is only liquid water and no gases.

  7. USINT. Heat and Mass Transfer in Concrete

    SciTech Connect

    Beck, J.V.; Knight, R.L.

    1989-12-01

    USINT was developed to model the thermal response of concrete to very high heating rates such as might occur from sodium spills on concrete surfaces in a breeder reactor. The major phenomena treated are conductive energy transport; chemical decomposition of concrete; and two-phase, three-component heat and mass transfer of the decomposition products: steam, liquid water, and carbon dioxide. The USINT model provides for porosity to increase as water and carbon-dioxide are formed from the concrete. The concrete is treated generally as divided into two basic regions, wet and dry. In the wet region, steam, carbon-dioxide, and liquid water may co-exist, but in the dry region, there is no liquid water. There is also the possibility of a third region in which there is only liquid water and no gases.

  8. Self-diffusion of vibrational states: Impact on the heat transfer in hypersonic flows

    NASA Astrophysics Data System (ADS)

    Josyula, E.; Kustova, E. V.; Vedula, P.

    2014-12-01

    In the present paper, the influence of self-diffusion of vibrationally excited states on the fluid dynamics and surface heat transfer in an axisymmetric Mach 7.2 air flow past a sphere-cone is discussed. Two models for state-to-state transport properties are considered: a simplified model using the Eucken's relation for thermal conductivity and Fick's law for diffusion velocities with the constant Lewis number, and a rigorous kinetic theory based model for the calculation of state-specific thermal conductivity, diffusion and thermal diffusion coefficients. The simplified model is applied for the flowfield simulation to avoid high computational costs. For the application of the accurate kinetic theory approach, a post-processing procedure is used. Inclusion of self-diffusion results in an increase in the surface heat flux of up to 6.5% upstream of a shoulder region. Thermal conductivity is found to be the primary contributor to surface heat flux; the influence of mass and thermal diffusion is found to be negligible. Self-diffusion has a considerably greater influence in decreasing heat flux in the downstream regions far from stagnation point.

  9. Mass transfer and interfacial properties in two-phase microchannel flows

    NASA Astrophysics Data System (ADS)

    Martin, Jeffrey D.; Hudson, Steven D.

    2009-11-01

    Drop-based microfluidic devices are becoming more common, and molecular mass transfer and drop circulation are issues that often affect the performance of such devices. Moreover, interfacial properties and surfactant mass transfer rates govern emulsion behavior. Since these phenomena depend strongly on drop size, measurement methods using small drops and flow typical of applications are desired. Using mineral oil as a continuous phase, water droplets and an alcohol surfactant, we demonstrate here a microfluidic approach to measure the interrelated phenomena of dynamic interfacial tension, surfactant mass transfer and interfacial retardation that employs droplet flows in a microchannel with constrictions/expansions. Interfacial flow is influenced markedly by adsorption of surfactant: severe interfacial retardation (by a factor of 30) is observed at low surfactant concentrations and interface remobilization is observed at higher surfactant concentrations. The interfacial tension is described by Langmuir kinetics and the parameters for interfaces with mineral oil (studied here) compare closely with those previously found at air interfaces. For the conditions explored, the surfactant mass transfer is described well by a mixed kinetic-diffusion limited model, and the desorption rate coefficients are measured to be both approximately 70 s-1. The transition from a diffusion-controlled to mixed diffusion-kinetic mass transfer mechanism predicted with reducing drop size is verified. This experimental approach (i.e. adjustable geometry and drop size and height) can therefore probe interfacial dynamics in simple and complex flow.

  10. Early solar mass loss, element diffusion, and solar oscillation frequencies

    SciTech Connect

    Guzik, J.A.; Cox, A.N.

    1994-07-01

    Swenson and Faulkner, and Boothroyd et al. investigated the possibility that early main-sequence mass loss via a stronger early solar wind could be responsible for the observed solar lithium and beryllium depiction. This depletion requires a total mass loss of {approximately}0.1 M{circle_dot}, nearly independent of the mass loss timescale. We have calculated the evolution and oscillation frequencies of solar models including helium and element diffusion, and such early solar mass loss. We show that extreme mass loss of 1 M{circle_dot} is easily ruled out by the low-degree p-modes that probe the solar center and sense the steeper molecular weight gradient produced by the early phase of more rapid hydrogen burning. The effects on central structure are much smaller for models with an initial mass of 1.1 M{circle_dot} and exponentially-decreasing mass loss irate with e-folding timescale 0.45 Gyr. While such mass loss slightly worsens the agreement between observed and calculated low-degree modes, the observational uncertainties of several tenths of a microhertz weaken this conclusion. Surprisingly, the intermediate-degree modes with much smaller observational uncertainties that probe the convection zone bottom prove to be the key to discriminating between models: The early mass loss phase decreases the total amount of helium and heavier elements diffused from the convection zone, and the extent of the diffusion produced composition gradient just below the convection zone, deteriorating the agreement with observed frequencies for these modes. Thus it appears that oscillations can also rule out this smaller amount of gradual early main-sequence mass loss in the young Sun. The mass loss phase must be confined to substantially under a billion years, probably 0.5 Gyr or less, to simultaneously solve the solar Li/Be problem and avoid discrepancies with solar oscillation frequencies.

  11. Topological spin-transfer drag driven by skyrmion diffusion

    NASA Astrophysics Data System (ADS)

    Ochoa, Héctor; Kim, Se Kwon; Tserkovnyak, Yaroslav

    2016-07-01

    We study the spin-transfer drag mediated by the Brownian motion of skyrmions. The essential idea is illustrated in a two-terminal geometry, in which a thin film of a magnetic insulator is placed in between two metallic reservoirs. An electric current in one of the terminals pumps topological charge into the magnet via a spin-transfer torque. The charge diffuses over the bulk of the system as stable skyrmion textures. By Onsager's reciprocity, the topological charge leaving the magnet produces an electromotive force in the second terminal. The voltage signal decays algebraically with the separation between contacts, in contrast to the exponential suppression of the spin drag driven by nonprotected excitations like magnons. We show how this topological effect can be used as a tool to characterize the phase diagram of chiral magnets and thin films with interfacial Dzyaloshinskii-Moriya interactions.

  12. Mass transfer and transport in a geologic environment

    SciTech Connect

    Chambre, P.L.; Pigford, T.H.; Lee, W.W.L.; Ahn, J.; Kajiwara, S.; Kim, C.L.; Kimura, H.; Lung, H.; Williams, W.J.; Zavoshy, S.J.

    1985-04-01

    This report is in a continuing series of reports that present analytic solutions for the dissolution and hydrogeologic transport of radionuclides from geologic repositories of nuclear waste. Previous reports have dealt mainly with radionuclide transport in the far-field, away from the effects of the repository. In the present report, the emphasis is on near-field processes, the transfer and transport of radionuclides in the vicinity of the waste packages. The primary tool used in these analyses is mass transfer theory from chemical engineering. The thrust of our work is to develop methods for predicting the performance of geologic repositories. The subjects treated in the present report are: radionuclide transport from a spherical-equivalent waste form through a backfill; analysis of radionuclide transport through a backfill using a non-linear sorption isotherm; radionuclide transport from a prolate spheroid-equivalent waste form with a backfill; radionuclide transport from a spherical-equivalent waste form through a backfill, where the solubility, diffusivity and retardation coefficients are temperature dependent; a coupled near-field, far-field analysis where dissolution and migration rates are temperature dependent; transport of radionuclides from a point source in a three-dimensional flow field; and a general solution for the transport of radioactive chains in geologic media. There are several important results from the numerical evaluations. First, radioactive decay, higher sorption in the rock and the backfill steepens the gradient for mass transfer, and lead to higher dissolution rates. This is contrary to what was expected by some other workers, but is shown clearly in the analytical solutions. Second, the backfill serves to provide sorption sites so that there is a delay in the arrival of radionuclides in the rock, although this effect is not so important for the steady-state transport of long-lived radionuclides.

  13. Analysis of turbulent heat transfer, mass transfer, and friction in smooth tubes at high Prandtl and Schmidt numbers

    NASA Technical Reports Server (NTRS)

    Deissler, Robert G

    1955-01-01

    The expression for eddy diffusivity from a previous analysis was modified in order to account for the effect of kinematic viscosity on the turbulence in the region close to a wall. By using the modified expression, good agreement was obtained between predicted and experimental results for heat and mass transfer at Prandtl and Schmidt numbers between 0.5 and 3000. The effects of length-to-diameter ratio and of variable viscosity were also investigated for a wide range of Prandtl numbers.

  14. A simple modelling of mass diffusion effects on condensation with noncondensable gases for the CATHARE Code

    SciTech Connect

    Coste, P.; Bestion, D.

    1995-09-01

    This paper presents a simple modelling of mass diffusion effects on condensation. In presence of noncondensable gases, the mass diffusion near the interface is modelled using the heat and mass transfer analogy and requires normally an iterative procedure to calculate the interface temperature. Simplifications of the model and of the solution procedure are used without important degradation of the predictions. The model is assessed on experimental data for both film condensation in vertical tubes and direct contact condensation in horizontal tubes, including air-steam, Nitrogen-steam and Helium-steam data. It is implemented in the Cathare code, a french system code for nuclear reactor thermal hydraulics developed by CEA, EDF, and FRAMATOME.

  15. Diffusion and phase change characterization by mass spectrometry

    NASA Technical Reports Server (NTRS)

    Koslin, M. E.; White, F. A.

    1979-01-01

    The high temperature diffusion of trace elements in metals and alloys was investigated. Measurements were made by high sensitivity mass spectrometry in which individual atoms were detected, and quantitative data was obtained for zircaloy-2, 304 stainless steel, and tantalum. Additionally, a mass spectrometer was also an analytical tool for determining an allotropic phase change for stainless steel at 955 C, and a phase transition region between 772 C and 1072 C existing for zircaloy-2. Diffusion rates were measured in thin (0.001" (0.0025 cm) and 0.0005" (0.0013 cm)) ribbons which were designed as high temperature thermal ion sources, with the alkali metals as naturally occurring impurities. In the temperature and pressure regime where diffusion measurements were made, the solute atoms evaporated from the ribbon filaments when the impurities diffused to the surface, with a fraction of these impurity atoms ionized according to the Langmuir-Saha relation. The techniques developed can be applied to many other alloys important to space vehicles and supersonic transports; and, with appropriate modifications, to the diffusion of impurities in composites.

  16. Calculation of the mass transfer coefficient for the combustion of a carbon particle

    SciTech Connect

    Scala, Fabrizio

    2010-01-15

    In this paper we address the calculation of the mass transfer coefficient around a burning carbon particle in an atmosphere of O{sub 2}, N{sub 2}, CO{sub 2}, CO, and H{sub 2}O. The complete set of Stefan-Maxwell equations is analytically solved under the assumption of no homogeneous reaction in the boundary layer. An expression linking the oxygen concentration and the oxygen flux at the particle surface (as a function of the bulk gas composition) is derived which can be used to calculate the mass transfer coefficient. A very simple approximate explicit expression is also given for the mass transfer coefficient, that is shown to be valid in the low oxygen flux limit or when the primary combustion product is CO{sub 2}. The results are given in terms of a correction factor to the equimolar counter-diffusion mass transfer coefficient, which is typically available in the literature for specific geometries and/or fluid-dynamic conditions. The significance of the correction factor and the accuracy of the different available expressions is illustrated for several cases of practical interest. Results show that under typical combustion conditions the use of the equimolar counter-diffusion mass transfer coefficient can lead to errors up to 10%. Larger errors are possible in oxygen-enriched conditions, while the error is generally low in oxy-combustion. (author)

  17. Mass transfer kinetics on heterogeneous binding sites of molecularly imprinted polymers

    SciTech Connect

    Kim, Hyunjung; Kaczmarski, Krzysztof; Guiochon, Georges A

    2005-07-01

    The mass transfer kinetics of the L- and D-Fmoc-Tryptophan (Fmoc-Trp) enantiomers on Fmoc-L-Trp imprinted polymer (MIP) and on its reference polymer (NIP), were measured using their elution peak profiles and the breakthrough curves recorded in frontal analysis for the determination of their equilibrium isotherms, at temperatures of 40, 50, 60, and 70 C. At all temperatures, the isotherm data of the Fmoc-Trp enantiomers on the MIP were best accounted for by the Tri-Langmuir isotherm model, while the isotherm data of Fmoc-Trp on the NIP were best accounted for by the Bi-Langmuir isotherm model. The profiles of the elution bands of various amounts of each enantiomer were acquired in the concentration range from 0.1 to 40 mM. These experimental profiles were compared with those calculated using the best values estimated for the isotherm parameters and the lumped pore diffusion model (POR), which made possible to calculate the intraparticle diffusion coefficients for each system. The results show that surface diffusion contributes predominantly to the overall mass transfer kinetics on both the MIP and the NIP, compared to external mass transfer and pore diffusion. The surface diffusion coefficients (D{sub s}) of Fmoc-L-Trp on the NIP does not depend on the amount bound (q) while the values of D{sub s} for the two Fmoc-Trp enantiomers on the MIP increase with increasing q at all temperatures. These positive dependencies of D{sub s} on q for Fmoc-Trp on the MIP were fairly well modeled by indirectly incorporating surface heterogeneity into the surface diffusion coefficient. The results obtained show that the mass transfer kinetics of the enantiomers on the imprinted polymers depend strongly on the surface heterogeneity.

  18. Hydrodynamically induced fluid transfer and non-convective double-diffusion in microgravity sliding solvent diffusion cells

    NASA Technical Reports Server (NTRS)

    Pollmann, Konrad W.; Stodieck, Louis S.; Luttges, Marvin W.

    1994-01-01

    Microgravity can provide a diffusion-dominated environment for double-diffusion and diffusion-reaction experiments otherwise disrupted by buoyant convection or sedimentation. In sliding solvent diffusion cells, a diffusion interface between two liquid columns is achieved by aligning two offset sliding wells. Fluid in contact with the sliding lid of the cavities is subjected to an applied shear stress. The momentum change by the start/stop action of the well creates an additional hydrodynamical force. In microgravity, these viscous and inertial forces are sufficiently large to deform the diffusion interface and induce hydrodynamic transfer between the wells. A series of KC-135 parabolic flight experiments were conducted to characterize these effects and establish baseline data for microgravity diffusion experiments. Flow visualizations show the diffusion interface to be deformed in a sinusoidal fashion following well alignment. After the wells were separated again in a second sliding movement, the total induced liquid transfer was determined and normalized by the well aspect ratio. The normalized transfer decreased linearly with Reynolds number from 3.3 to 4.0% (w/v) for Re = 0.4 (Stokes flow) to a minimum of 1.0% for Re = 23 to 30. Reynolds numbers that provide minimum induced transfers are characterized by an interface that is highly deformed and unsuitable for diffusion measurements. Flat diffusion interfaces acceptable for diffusion measurements are obtained with Reynolds numbers on the order of 7 to 10. Microgravity experiments aboard a sounding rocket flight verified counterdiffusion of different solutes to be diffusion dominated. Ground control experiments showed enhanced mixing by double-diffusive convection. Careful selection of experimental parameters improves initial conditions and minimizes induced transfer rates.

  19. Fundamental mass transfer model for indoor air emissions from surface coatings

    SciTech Connect

    Tichenor, B.A.; Guo, Z.; Sparks, L.E.

    1994-01-01

    The paper discusses the work of researchers at the U.S. EPA's Air and Energy Engineering Research Laboratory (Indoor Air Branch) who are evaluating mass transfer models based on fundamental principles to determine their effectiveness in predicting emissions from indoor architectural coatings. As a first step, a simple model based on Fick's Law of Diffusion has been developed. In the model, the mass transfer rate is assumed to be controlled by the boundary layer mass transfer coefficient, the saturation vapor pressure of the material being emitted, and the mass of volatile material remaining in the source at any point in time. Both static and dynamic chamber tests were conducted to obtain model validation data. Further validation experiments were conducted in a test house. Results of these tests are presented.

  20. Mass transfer across combustion gas thermal boundary layers - Power production and materials processing implications

    NASA Technical Reports Server (NTRS)

    Rosner, D. E.

    1985-01-01

    The effects of Soret diffusion (for vapors) and thermophoresis (for particles) are illustrated using recent optical experiments and boundary layer computations. Mass transfer rate augmentations of up to a factor of 1000 were observed and predicted for submicron-particle capture by cooled solid surfaces, while mass transfer suppressions of more than 10 to the -10th-fold were predicted for 'overheated' surfaces. It is noted that the results obtained are of interest in connection with such technological applications as fly-ash capture in power generation equipment and glass droplet deposition in optical-waveguide manufacture.

  1. Numerical study on heat and mass transfer in hygroscopic rotor during sorption process

    NASA Astrophysics Data System (ADS)

    Shin, Hyun-Geun; Park, Il Seouk

    2016-06-01

    Recently, interest in hygroscopic dehumidifiers has rapidly increased in the indoor environment industry because of their potential contribution to the development of hybrid (refrigerating + hygroscopic) dehumidifiers. Heat and mass transport phenomena such as adsorption and desorption, and their complex interactions occur in a desiccant rotor, which comprises many small hygroscopic channels. This study numerically investigated the conjugated heat and mass transfers in a channel modeled with the flow and porous desiccant regions, where only ordinary and surface diffusions (excluding Knudsen diffusion) during the sorption processes were considered. The change in the dehumidification performance depending on operating conditions such as the rotor's rotating speed, air flow rate, and adsorption-desorption ratio, was examined under various working environments. The temporal and spatial variations in the temperature, vapor mass fraction, and liquid water mass fraction in the channel were considered in detail. The closely linked heat and mass transports were clarified for a better understanding of the sorption processes in the desiccant rotor.

  2. Fluid flow and mass transfer over circular strands using the lattice Boltzmann method

    NASA Astrophysics Data System (ADS)

    Hossain, Md. Shakhawath; Chen, X. B.; Bergstrom, D. J.

    2015-10-01

    Knowledge of the fluid flow and mass transfer over circular strands is fundamental to the cell culture of tissue scaffolds in bio-reactors. This paper presents a study on the simulation of fluid flow and mass transfer over the circular strands of a tissue scaffold by using the multiple relaxation time lattice Boltzmann method for the low Reynolds number regime, with Re D = 0.01 and 0.1, respectively. The mass transfer problem approximates the transport of a scalar nutrient from the bulk fluid to the strand surface, such as is encountered in the flow through tissue scaffolds placed in bio-reactors. The circular geometry of the scaffold strand is treated and implemented by means of the interpolated bounce-back boundary condition formulation. Our simulation illustrates that the flow accelerates around the strand, resulting in the maximum shear stress at the shoulder of the strand and that diffusion mass transfer plays the dominant role in the scalar transport. The local Sherwood number varies significantly over the surface of the strand, with a peak value located on the upstream surface. Increasing the Schmidt number of the scalar and decreasing the blockage ratio results in higher mass transfer rates on the surface of the stand. Overall, the simulation results provide one with the insight into the fluid flow and mass transfer over the circular strands of a tissue scaffold in a bio-reactor, which would be impractical to obtain by experiments.

  3. Numerical simulation of mass transfer in the liquid phase of the bubble layer of a thermal deaerator

    NASA Astrophysics Data System (ADS)

    Laptev, A. G.; Misbakhov, R. Sh.; Lapteva, E. A.

    2015-12-01

    On the basis of one-dimensional diffusion model of the flow structure and boundary layer theory, a method for calculating the mass transfer of dissolved oxygen in the liquid phase of the bubble layer of a thermal deaerator is developed. Mass transfer with the bulk source of mass has been considered, wherein the basic parameter is mass-transfer coefficient. A model of pseudo laminar boundary layer on the bubble surface is proposed, and the possibility of calculating of mass-transfer coefficient from bubbles in the mass source of diffusion model is shown, taking into account the gas content and external turbulence. A comparison of the calculation results of mass-transfer coefficient is given from the bubbles with known experimental data. It is shown that taking into account gas content results in an increase of the mass-transfer coefficient by 2-4 times. Expressions for calculations of gas content, dynamic speed, and inverse stirring coefficient in the liquid phase of the bubble layer are presented. In the special case, transition from the diffusion model of the flow structure to cell model is made, and comparison of the calculation results on the concentration of oxygen in water at the output of DSA-300 bubbling thermal deaerator with experimental data is performed. The developed mathematical model and calculation algorithm can be used in the design, diagnosis, and modernization of thermal deaerators.

  4. Diffusion mass transport in liquid phase epitaxial growth of semiconductors

    SciTech Connect

    Dost, S.; Qin, Z.; Kimura, M.

    1996-12-01

    A numerical simulation model for the mass transport occurring during the liquid phase epitaxial growth of AlGaAs is presented. The mass transport equations in the liquid and solid phases, and the relationships between concentrations and temperature obtained from the phase diagram constitute the governing equations. These equations together with appropriate interface and boundary conditions were solved numerically by the Finite Element Method. Numerical results show the importance of diffusion into the solid phase, affecting the composition of grown layers. Simulation results agree with experiments.

  5. Rotational hydrodynamic diffusion system to study mass transport across boundaries.

    PubMed

    Mamidi, Sai Sree; Meas, Bo; Farhat, Tarek R

    2008-11-01

    The design and operation of a new mass transport technique is presented. Rotational hydrodynamic diffusion system (RHDS) is a method that can be adapted for analytical laboratory analysis as well as industrial-scale separation and purification. Although RHDS is not an electrochemical technique, its concept is derived from hydrodynamic rotating disk electrode voltammetry. A diffusion advantage gained using the RHDS is higher flux of probe molecules across the boundary (e.g., membrane or porous media) with increased rotation rate compared to the static two-half-cell (THC) method. The separation concept of RHDS differs from pressurized, agitated, electrodialysis, and reversed osmosis systems in design and theory. The detection mechanism of the RHDS opens the possibility to study mass transport properties of a large variety of molecules using different types of ultrathin membranes. Therefore, the RHDS is a potential alternative to classical mass transport detection methods such as THC, impedance spectroscopy, and cyclic and rotating disk electrode voltammetry. Theoretical analysis on the rotational hydrodynamic flux is derived and compared to experimental flux measured using HCl, KCl, KNO 3, Ni(NO 3) 2, LiCl, camphor sulfonic acid, and K 3Fe(CN) 6 ionic solutions. Values of effective diffusion coefficients of salts across Nucleopore membranes of thickness 6.0 and 10 mum with pore size 0.1 and 0.2 mum, respectively, are presented and discussed. PMID:18844370

  6. Electron Transfer Dissociation Mass Spectrometry of Hemoglobin on Clinical Samples

    NASA Astrophysics Data System (ADS)

    Coelho Graça, Didia; Lescuyer, Pierre; Clerici, Lorella; Tsybin, Yury O.; Hartmer, Ralf; Meyer, Markus; Samii, Kaveh; Hochstrasser, Denis F.; Scherl, Alexander

    2012-10-01

    A mass spectrometry-based assay combining the specificity of selected reaction monitoring and the protein ion activation capabilities of electron transfer dissociation was developed and employed for the rapid identification of hemoglobin variants from whole blood without previous proteolytic cleavage. The analysis was performed in a robust ion trap mass spectrometer operating at nominal mass accuracy and resolution. Subtle differences in globin sequences, resulting with mass shifts of about one Da, can be unambiguously identified. These results suggest that mass spectrometry analysis of entire proteins using electron transfer dissociation can be employed on clinical samples in a workflow compatible with diagnostic applications.

  7. Predicting diffusive alveolar oxygen transfer from carbon monoxide-diffusing capacity in exercising foxhounds.

    PubMed

    Hsia, Connie C W; Wagner, Peter D; Dane, D Merrill; Wagner, Harrieth E; Johnson, Robert L

    2008-11-01

    Although lung diffusing capacity for carbon monoxide (DL(CO)) is a widely used test of diffusive O2 transfer, few studies have directly related DL(CO) to O2-diffusing capacity (DL(O2)); none has used the components of Dl(CO), i.e., conductance of alveolar membrane and capillary blood, to predict DL(O2) from rest to exercise. To understand the relationship between DL(CO) and DL(O2) at matched levels of cardiac output, we analyzed cumulative data from rest to heavy exercise in 43 adult dogs, with normal lungs or reduced lung capacity following lung resection, that were studied by two techniques. 1) A rebreathing (RB) technique was used to measure Dl(CO) and pulmonary blood flow at two O2 tensions, independent of O2 exchange. DL(CO) was partitioned into CO-diffusing capacity of alveolar membrane and pulmonary capillary blood volume using the Roughton-Forster equation and converted into an equivalent DL(O2), [DL(O2)(RB)]. 2) A multiple inert-gas elimination technique (MIGET) was used to measure ventilation-perfusion distributions, O2 and CO2 exchange under hypoxia, to derive DL(O2) [DL(O2)(MIGET)] by the Lilienthal-Riley technique and Bohr integration. For direct comparisons, DL(O2)(RB) was interpolated to the cardiac output measured by the Fick principle corresponding to DL(O2)(MIGET). The DL(O2)-to-DL(CO) ratio averaged 1.61. Correlation between DL(O2)(RB) and DL(O2)(MIGET) was similar in normal and post-resection groups. Overall, DL(O2)(MIGET) = 0.975 DL(O2)(RB); mean difference between the two techniques was under 5% for both animal groups. We conclude that, despite various uncertainties inherent in these two disparate methods, the Roughton-Forster equation adequately predicts diffusive O2 transfer from rest to heavy exercise in canines with normal, as well as reduced, lung capacities. PMID:18719238

  8. Predicting diffusive alveolar oxygen transfer from carbon monoxide-diffusing capacity in exercising foxhounds

    PubMed Central

    Hsia, Connie C. W.; Wagner, Peter D.; Dane, D. Merrill; Wagner, Harrieth E.; Johnson, Robert L.

    2008-01-01

    Although lung diffusing capacity for carbon monoxide (DlCO) is a widely used test of diffusive O2 transfer, few studies have directly related DlCO to O2-diffusing capacity (DlO2); none has used the components of DlCO, i.e., conductance of alveolar membrane and capillary blood, to predict DlO2 from rest to exercise. To understand the relationship between DlCO and DlO2 at matched levels of cardiac output, we analyzed cumulative data from rest to heavy exercise in 43 adult dogs, with normal lungs or reduced lung capacity following lung resection, that were studied by two techniques. 1) A rebreathing (RB) technique was used to measure DlCO and pulmonary blood flow at two O2 tensions, independent of O2 exchange. DlCO was partitioned into CO-diffusing capacity of alveolar membrane and pulmonary capillary blood volume using the Roughton-Forster equation and converted into an equivalent DlO2, [DlO2(RB)]. 2) A multiple inert-gas elimination technique (MIGET) was used to measure ventilation-perfusion distributions, O2 and CO2 exchange under hypoxia, to derive DlO2 [DlO2(MIGET)] by the Lilienthal-Riley technique and Bohr integration. For direct comparisons, DlO2(RB) was interpolated to the cardiac output measured by the Fick principle corresponding to DlO2(MIGET). The DlO2-to-DlCO ratio averaged 1.61. Correlation between DlO2(RB) and DlO2(MIGET) was similar in normal and post-resection groups. Overall, DlO2(MIGET) = 0.975 DlO2(RB); mean difference between the two techniques was under 5% for both animal groups. We conclude that, despite various uncertainties inherent in these two disparate methods, the Roughton-Forster equation adequately predicts diffusive O2 transfer from rest to heavy exercise in canines with normal, as well as reduced, lung capacities. PMID:18719238

  9. Influence of drying air parameters on mass transfer characteristics of apple slices

    NASA Astrophysics Data System (ADS)

    Beigi, Mohsen

    2015-12-01

    To efficiently design both new drying process and equipment and/or to improve the existing systems, accurate values of mass transfer characteristics are necessary. The present study aimed to investigate the influence of drying air parameters (i.e. temperature, velocity and relative humidity) on effective diffusivity and convective mass transfer coefficient of apple slices. The Dincer and Dost model was used to determine the mass transfer characteristics. The obtained Biot number indicated that the moisture transfer in the apple slices was controlled by both internal and external resistance. The effective diffusivity and mass transfer coefficient values obtained to be in the ranges of 7.13 × 10-11-7.66 × 10-10 and 1.46 × 10-7-3.39 × 10-7 m s-1, respectively and the both of them increased with increasing drying air temperature and velocity, and decreasing relative humidity. The validation of the model showed that the model predicted the experimental drying curves of the samples with a good accuracy.

  10. Chemical mass transfer in magmatic processes

    NASA Astrophysics Data System (ADS)

    Ghiorso, Mark S.

    1987-07-01

    Lasaga's (1982) Master Equation for crystal growth is solved for multicomponent systems in situations which allow for coupled diffusion of melt species. The structure of the solution is explored in some detail for the case of a constant diffusion coefficient matrix. Incorporating these results, the growth of plagioclase is modeled in undercooled tholeiitic melts by approximating interface growth rates with (1) a reduced growth rate function and with (2) calculated solid-liquid solution properties obtained from the silicate liquid solution model of Ghiorso et al. (1983; appendix of Ghiorso 1985). For this purpose algorithms are provided for estimating the liquidus temperature or the chemical affinity of a multicomponent solid solution precipitating from a complex melt of specified bulk composition. Compositional trends in initial solids produced by successive degrees of undercooling are opposite to those predicted in the binary system NaAlSi3O8-CaAl2Si2O8. Calculations suggest that the solid phase and interface melt compositions rapidly approach a “steady state” for a given degree of undercooling. Consequently, the overall isothermal growth rate of plagioclase forming from tholeiitic melts appears to be entirely diffusion controlled. In magmatic systems the multicomponent growth equations allow for the formation of oscillatory zoned crystals as a consequence of the “couplingr” between interface reaction kinetics and melt diffusion. The magnitude of this effect is largely dependent upon the asymmetry of the diffusion coefficient matrix. Methods are described to facilitate the calibration of diffusion matrices from experimental data on multicomponent penetration curves. Experimental results (Lesher and Walker 1986) on steady state Soret concentration profiles resulting from thermal diffusion in MORB and andesitic liquids are analyzed using the theory of multicomponent linear irreversible thermodynamics. Under conditions where the entropy production is

  11. Application and limitations of a mass transfer VOC emission model for a dry building material

    NASA Astrophysics Data System (ADS)

    Crawford, S.; Lungu, C. T.

    2013-12-01

    Volatile organic compound (VOC) emission from building materials into air has been quantified, characterized and modeled. Internal diffusion of VOC through a material based on Fick's law of diffusion is the basis for mass transfer modeling of diffusive emission used to estimate VOC concentrations in air over time. Current mass transfer models have been shown to appropriately estimate air VOC concentrations at approximate room temperature, while other research has shown that temperature has a profound effect on the diffusion coefficient, D, of VOC in a material. Here, a mass transfer model is operated at 23 °C and 40 °C using input parameters applicable for each temperature. The model estimates are validated against environmental test chamber data for styrene emission from a vinyl ester resin thermoset composite material. The model correlates well with the 23 °C chamber data, but underestimates chamber data by as much as 10-4 at 264 h for the 40 °C modeling. This suggests that the model requires adjustment for predicting VOC air concentrations at temperatures other than 23 °C.

  12. Mass transfer characteristics of bisporus mushroom ( Agaricus bisporus) slices during convective hot air drying

    NASA Astrophysics Data System (ADS)

    Ghanbarian, Davoud; Baraani Dastjerdi, Mojtaba; Torki-Harchegani, Mehdi

    2016-05-01

    An accurate understanding of moisture transfer parameters, including moisture diffusivity and moisture transfer coefficient, is essential for efficient mass transfer analysis and to design new dryers or improve existing drying equipments. The main objective of the present study was to carry out an experimental and theoretical investigation of mushroom slices drying and determine the mass transfer characteristics of the samples dried under different conditions. The mushroom slices with two thicknesses of 3 and 5 mm were dried at air temperatures of 40, 50 and 60 °C and air flow rates of 1 and 1.5 m s-1. The Dincer and Dost model was used to determine the moisture transfer parameters and predict the drying curves. It was observed that the entire drying process took place in the falling drying rate period. The obtained lag factor and Biot number indicated that the moisture transfer in the samples was controlled by both internal and external resistance. The effective moisture diffusivity and the moisture transfer coefficient increased with increasing air temperature, air flow rate and samples thickness and varied in the ranges of 6.5175 × 10-10 to 1.6726 × 10-9 m2 s-1 and 2.7715 × 10-7 to 3.5512 × 10-7 m s-1, respectively. The validation of the Dincer and Dost model indicated a good capability of the model to describe the drying curves of the mushroom slices.

  13. Probing the Mass-Transfer Stability Limit in Close Binaries

    NASA Astrophysics Data System (ADS)

    D'Souza, M. C. R.; Motl, P. M.; Tohline, J. E.; Frank, J.

    2004-12-01

    We present results from numerical simulations that follow the nonlinear development of mass-transfer instabilities in close binary star systems. A self-consistent-field (SCF) technique is used to construct initial equilibrium models, which are synchronously rotating, semi-detached, polytropic stars on circular orbits. These models are evolved with an Eulerian, finite-difference hydrodynamics code in a fully self-consistent manner. Results are presented for binary systems having a wide range of initial conditions; emphasis is placed on systems in which the mass-transfer stream directly impacts the surface of the accreting star. Some systems are dynamically unstable and result in a merger; others approach a long-term, stable phase of mass transfer. The time-evolutionary behavior of the binary separation, mass transfer rate, spin angular momentum of the accretor, and gravitational wave strain are presented.

  14. Disentangling oil weathering using GC x GC. 2. Mass transfer calculations.

    PubMed

    Arey, J Samuel; Nelson, Robert K; Plata, Desiree L; Reddy, Christopher M

    2007-08-15

    Hydrocarbon mass transfers to the atmosphere and water column drive the early weathering of oil spills and also control the chemical exposures of many coastal wildlife species. However, in the field, mass transfer rates of individual hydrocarbons to air and water are often uncertain. In the Part 1 companion to this paper, we used comprehensive two-dimensional gas chromatography (GC x GC) to identify distinct signatures of evaporation and dissolution encoded in the compositional evolution of weathered oils. In Part 2, we further investigate patterns of mass removal in GC x GC chromatograms using a mass transfer model. The model was tailored to conditions at a contaminated beach on Buzzards Bay, MA, after the 2003 Bouchard 120 oil spill. The model was applied to all resolved hydrocarbon compounds in the C11-C24 boiling range, based on their GC x GC-estimated vapor pressures and aqueous solubilities. With no fitted parameters, the model successfully predicted GC x GC chromatogram patterns of mass removal associated with evaporation, water-washing, and diffusion-limited transport. This enabled a critical field evaluation of the mass transfer model and also allowed mass apportionment estimates of hundreds of individual hydrocarbon compounds to air and water. Ultimately, this method should improve assessments of wildlife exposures to oil spill hydrocarbons. PMID:17874782

  15. Heat and mass transfer in materials processing

    SciTech Connect

    Tanasawa, I. . Inst. of Industrial Science); Lior, N. . Dept. of Mechanical Engineering and Applied Mechanics)

    1992-01-01

    This book contains forty papers presented at the seminar. The papers are representative of the seminar's scope, and include plasma spraying, laser and electron beam processing, crystal growth, solidification, steel processing, casting and molding, and papermaking, as well as fundamental heat transfer issues and physical properties underlying all of the above. The seminar emphasized thorough discussion of the presentations and of the subfields. Brief summaries of the discussions are presented in the rapporteurs' reports.

  16. Local Mass and Heat Transfer on a Turbine Blade Tip

    DOE PAGESBeta

    Jin, P.; Goldstein, R. J.

    2003-01-01

    Locmore » al mass and heat transfer measurements on a simulated high-pressure turbine blade-tip surface are conducted in a linear cascade with a nonmoving tip endwall, using a naphthalene sublimation technique. The effects of tip clearance (0.86–6.90% of chord) are investigated at various exit Reynolds numbers (4–7 × 10 5 ) and turbulence intensities (0.2 and 12.0%). The mass transfer on the tip surface is significant along its pressure edge at the smallest tip clearance. At the two largest tip clearances, the separation bubble on the tip surface can cover the whole width of the tip on the second half of the tip surface. The average mass-transfer rate is highest at a tip clearance of 1.72% of chord. The average mass-transfer rate on the tip surface is four and six times as high as on the suction and the pressure surface, respectively. A high mainstream turbulence level of 12.0% reduces average mass-transfer rates on the tip surface, while the higher mainstream Reynolds number generates higher local and average mass-transfer rates on the tip surface.« less

  17. Oscillatory flow through submerged canopies: 2. Canopy mass transfer

    NASA Astrophysics Data System (ADS)

    Lowe, Ryan J.; Koseff, Jeffrey R.; Monismith, Stephen G.; Falter, James L.

    2005-10-01

    Mass transfer rates from submerged canopies constructed from arrays of vertical cylinders were investigated for a range of different cylinder spacings under both unidirectional and oscillatory flow. Individual canopy elements made from gypsum were dissolved in fresh water to simulate the mass transfer of dissolved metabolites to and from canopies of living benthic organisms. Mass transfer rates under oscillatory flow were up to three times higher than values measured for a comparable unidirectional current. This enhancement was shown to be a strong function of the canopy element spacing. A model was developed to predict canopy mass transfer rates on the basis of the in-canopy flow speed and was generalized to incorporate either unidirectional or oscillatory flow. Agreement between the modeled and experimentally measured mass transfer rates indicate that enhanced mass transfer to/from living benthic canopies under oscillatory flow is driven primarily by the higher in-canopy water motion generated by the oscillatory flow, as detailed in the companion paper (Lowe et al., 2005).

  18. New method to determine the mass transfer resistance of sterile closures for shaken bioreactors.

    PubMed

    Anderlei, Tibor; Mrotzek, Christian; Bartsch, Stefan; Amoabediny, Ghassem; Peter, Cyril P; Büchs, Jochen

    2007-12-01

    In this paper a novel and easily applied method to measure the mass transfer resistance of the sterile closures (e.g. cotton plug) of shaken bioreactors is introduced. This method requires no investment in special equipment (e.g. an oxygen sensor) and can be performed with the materials usually available in typical laboratories. The method is based on the model of Henzler et al. (1986), which mechanistically describes mass transfer through the sterile closure of a shaken bioreactor based on diffusion coupled with Stefan convection. The concentration dependency of the multi-component diffusion coefficients is taken into account. The water loss from two equivalent shaken bioreactors equipped with sterile closures during several days of shaking is measured. One flask contains distilled water, the other a saturated salt solution. From the water evaporation rate in each of the two flasks, the new model presented calculates the relative humidity in the environment, the average diffusion coefficient of oxygen in the sterile closure (D(O2)), and the diffusion coefficient of carbon dioxide (D(CO2)) . The diffusion coefficient of carbon dioxide (D(CO2)) only depends on the density and material properties of the sterile closure and not on the gas concentrations and is, therefore, an ideal parameter for the characterization of the mass transfer resistance. This new method is validated experimentally by comparing the diffusion coefficient of oxygen (D(O2)) to a measurement by the classic dynamic method; and by comparing the calculated relative humidity in the environment to a humidity sensor measurement. PMID:17497734

  19. Micro-scale mass-transfer variations during electrodeposition

    SciTech Connect

    Sutija, D.P.

    1991-08-01

    Results of two studies on micro-scale mass-transfer enhancement are reported: (1) Profiled cross-sections of striated zinc surfaces deposited in laminar channel flow were analyzed with fast-fourier transforms (FFT) to determine preferred striation wavelengths. Striation frequency increases with current density until a minimum separation between striae of 150 {mu}m is reached. Beyond this point, independent of substrate used, striae meld together and form a relatively smooth, nodular deposit. Substrates equipped with artificial micron-sized protrusions result in significantly different macro-morphology in zinc deposits. Micro-patterned electrodes (MPE) with hemispherical protrusions 5 {mu}m in diameter yield thin zinc striae at current densities that ordinarily produce random nodular deposits. MPEs with artificial hemi-cylinders, 2.5 {mu}m in height and spaced 250 {mu}m apart, form striae with a period which matches the spacing of micron-sized ridges. (2) A novel, corrosion-resistant micromosaic electrode was fabricated on a silicon wafer. Measurements of mass-transport enhancement to a vertical micromosaic electrode caused by parallel bubble streams rising inside of the diffusion boundary-layer demonstrated the presence of two co-temporal enhancement mechanisms: surface-renewal increases the limiting current within five bubble diameters of the rising column, while bubble-induced laminar flows cause weaker enhancement over a much broader swath. The enhancement caused by bubble curtains is predicted accurately by linear superposition of single-column enhancements. Two columns of smaller H{sub 2} bubbles generated at the same volumetric rate as a single column of larger bubbles cause higher peak and far-field enhancements. 168 refs., 96 figs., 6 tabs.

  20. Analysis of mass transfer in dissipative nonideal systems: Experiments on dusty plasmas

    SciTech Connect

    Vaulina, O. S.; Adamovich, K. G. Petrov, O. F.; Fortov, V. E.

    2008-08-15

    Results of an experimental study of mass transfer are presented for extended systems of dust particles observed in capacitively coupled RF discharge plasmas. The Green-Kubo relation and the Langevin equation are validated as applied to dust grain dynamics in laboratory plasmas. A procedure is proposed for evaluating the temperature, friction coefficient, and characteristic oscillation frequency for dust grains. Measured characteristics of the dust subsystem (diffusion coefficient, pair correlation function, and friction coefficient) are compared with available theoretical and numerical results.

  1. Intraparticle mass transfer kinetics on molecularly imprinted polymers of structural analogues of a template

    SciTech Connect

    Kim, Hyunjung; Kaczmarski, Krzysztof; Guiochon, Georges A

    2005-09-01

    The intraparticle mass transfer kinetics of the structural analogues of a template on a Fmoc-L-Tryptophan (Fmoc-L-Trp) imprinted polymer (MIP) and on the corresponding non-imprinted polymer (NIP) were quantitatively studied using the lumped pore diffusion model (POR) of chromatography. The best equilibrium isotherm models of these compounds were used to calculate the high-concentration band profiles of different substrates on the MIP and the NIP with the POR model. These profiles were compared to experimental band profiles. The numerical values of the intraparticle pore and surface diffusion coefficients were adjusted to determine those that minimized the differences between calculated and experimental profiles. The results of this exercise show that surface diffusion is the dominant intraparticle mass transfer process for the substrates on the polymers and that the energetic heterogeneity of the surface should be considered in accounting for the surface diffusion of the L-enantiomers on the MIP. The surface diffusion coefficient increases with decreasing overall affinity of each substrate for the polymers.

  2. Mass transfer of VOCs in laboratory-scale air sparging tank.

    PubMed

    Chao, Keh-Ping; Ong, Say Kee; Huang, Mei-Chuan

    2008-04-15

    Volatilization of VOCs was investigated using a 55-gal laboratory-scale model in which air sparging experiments were conducted with a vertical air injection well. In addition, X-ray imaging of an air sparging sand box showed air flows were in the form of air bubbles or channels depending on the size of the porous media. Air-water mass transfer was quantified using the air-water mass transfer coefficient which was determined by fitting the experimental data to a two-zone model. The two-zone model is a one-dimensional lumped model that accounts for the effects of air flow type and diffusion of VOCs in the aqueous phase. The experimental air-water mass transfer coefficients, KGa, obtained from this study ranged from 10(-2) to 10(-3)1/min. From a correlation analysis, the air-water mass transfer coefficient was found to be directly proportional to the air flow rate and the mean particle size of soil but inversely proportional to Henry's constant. The correlation results implied that the air-water mass transfer coefficient was strongly affected by the size of porous media and the air flow rates. PMID:17804158

  3. Geoelectrical Measurement of Multi-Scale Mass Transfer Parameters

    SciTech Connect

    Day-Lewis, Frederick David; Singha, Kamini; Johnson, Timothy C.; Haggerty, Roy; Binley, Andrew; Lane, John W.

    2014-11-25

    Mass transfer affects contaminant transport and is thought to control the efficiency of aquifer remediation at a number of sites within the Department of Energy (DOE) complex. An improved understanding of mass transfer is critical to meeting the enormous scientific and engineering challenges currently facing DOE. Informed design of site remedies and long-term stewardship of radionuclide-contaminated sites will require new cost-effective laboratory and field techniques to measure the parameters controlling mass transfer spatially and across a range of scales. In this project, we sought to capitalize on the geophysical signatures of mass transfer. Previous numerical modeling and pilot-scale field experiments suggested that mass transfer produces a geoelectrical signature—a hysteretic relation between sampled (mobile-domain) fluid conductivity and bulk (mobile + immobile) conductivity—over a range of scales relevant to aquifer remediation. In this work, we investigated the geoelectrical signature of mass transfer during tracer transport in a series of controlled experiments to determine the operation of controlling parameters, and also investigated the use of complex-resistivity (CR) as a means of quantifying mass transfer parameters in situ without tracer experiments. In an add-on component to our grant, we additionally considered nuclear magnetic resonance (NMR) to help parse mobile from immobile porosities. Including the NMR component, our revised study objectives were to: 1. Develop and demonstrate geophysical approaches to measure mass-transfer parameters spatially and over a range of scales, including the combination of electrical resistivity monitoring, tracer tests, complex resistivity, nuclear magnetic resonance, and materials characterization; and 2. Provide mass-transfer estimates for improved understanding of contaminant fate and transport at DOE sites, such as uranium transport at the Hanford 300 Area. To achieve our objectives, we implemented a 3

  4. Mass transfer between debris discs during close stellar encounters

    NASA Astrophysics Data System (ADS)

    Jílková, Lucie; Hamers, Adrian S.; Hammer, Michael; Portegies Zwart, Simon

    2016-04-01

    We study mass transfers between debris discs during stellar encounters. We carried out numerical simulations of close flybys of two stars, one of which has a disc of planetesimals represented by test particles. We explored the parameter space of the encounters, varying the mass ratio of the two stars, their pericentre and eccentricity of the encounter, and its geometry. We find that particles are transferred to the other star from a restricted radial range in the disc and the limiting radii of this transfer region depend on the parameters of the encounter. We derive an approximate analytic description of the inner radius of the region. The efficiency of the mass transfer generally decreases with increasing encounter pericentre and increasing mass of the star initially possessing the disc. Depending on the parameters of the encounter, the transfer particles have a specific distribution in the space of orbital elements (semimajor axis, eccentricity, inclination, and argument of pericentre) around their new host star. The population of the transferred particles can be used to constrain the encounter through which it was delivered. We expect that many stars experienced transfer among their debris discs and planetary systems in their birth environment. This mechanism presents a formation channel for objects on wide orbits of arbitrary inclinations, typically having high eccentricity but possibly also close to circular (eccentricities of about 0.1). Depending on the geometry, such orbital elements can be distinct from those of the objects formed around the star.

  5. Secular dynamics in hierarchical three-body systems with mass loss and mass transfer

    SciTech Connect

    Michaely, Erez; Perets, Hagai B.

    2014-10-20

    Recent studies have shown that secular evolution of triple systems can play a major role in the evolution and interaction of their inner binaries. Very few studies explored the stellar evolution of triple systems, and in particular the mass-loss phase of the evolving stellar components. Here we study the dynamical secular evolution of hierarchical triple systems undergoing mass loss. We use the secular evolution equations and include the effects of mass loss and mass transfer, as well as general relativistic effects. We present various evolutionary channels taking place in such evolving triples, and discuss both the effects of mass loss and mass transfer in the inner binary system, as well as the effects of mass loss/transfer from an outer third companion. We discuss several distinct types/regimes of triple secular evolution, where the specific behavior of a triple system can sensitively depend on its hierarchy and the relative importance of classical and general relativistic effects. We show that the orbital changes due to mass-loss and/or mass-transfer processes can effectively transfer a triple system from one dynamical regime to another. In particular, mass loss/transfer can both induce and quench high-amplitude (Lidov-Kozai) variations in the eccentricity and inclination of the inner binaries of evolving triples. They can also change the system dynamics from an orderly periodic behavior to a chaotic one, and vice versa.

  6. Monolithic supports with unique geometries and enhanced mass transfer.

    SciTech Connect

    Stuecker, John Nicholas; Ferrizz, Robert Matthew; Cesarano, Joseph, III; Miller, James Edward

    2004-01-01

    The catalytic combustion of natural gas has been the topic of much research over the past decade. Interest in this technology results from a desire to decrease or eliminate the emissions of harmful nitrogen oxides (NOX) from gas turbine power plants. A low-pressure drop catalyst support, such as a ceramic monolith, is ideal for this high-temperature, high-flow application. A drawback to the traditional honeycomb monoliths under these operating conditions is poor mass transfer to the catalyst surface in the straight-through channels. 'Robocasting' is a unique process developed at Sandia National Laboratories that can be used to manufacture ceramic monoliths with alternative 3-dimensional geometries, providing tortuous pathways to increase mass transfer while maintaining low pressure drops. This report details the mass transfer effects for novel 3-dimensional robocast monoliths, traditional honeycomb-type monoliths, and ceramic foams. The mass transfer limit is experimentally determined using the probe reaction of CO oxidation over a Pt / {gamma}-Al{sub 2}O{sub 3} catalyst, and the pressure drop is measured for each monolith sample. Conversion versus temperature data is analyzed quantitatively using well-known dimensionless mass transfer parameters. The results show that, relative to the honeycomb monolith support, considerable improvement in mass transfer efficiency is observed for robocast samples synthesized using an FCC-like geometry of alternating rods. Also, there is clearly a trade-off between enhanced mass transfer and increased pressure drop, which can be optimized depending on the particular demands of a given application.

  7. Reciprocal theorem for convective heat and mass transfer from a particle in Stokes and potential flows

    NASA Astrophysics Data System (ADS)

    Vandadi, Vahid; Jafari Kang, Saeed; Masoud, Hassan

    2016-06-01

    In the study of convective heat and mass transfer from a particle, key quantities of interest are usually the average rate of transfer and the mean distribution of the scalar (i.e., temperature or concentration) at the particle surface. Calculating these quantities using conventional equations requires detailed knowledge of the scalar field, which is available predominantly for problems involving uniform scalar and flux boundary conditions. Here we derive a reciprocal relation between two diffusing scalars that are advected by oppositely driven Stokes or potential flows whose streamline configurations are identical. This relation leads to alternative expressions for the aforementioned average quantities based on the solution of the scalar field for uniform surface conditions. We exemplify our results via two applications: (i) heat transfer from a sphere with nonuniform boundary conditions in Stokes flow at small Péclet numbers and (ii) extension of Brenner's theorem for the invariance of heat transfer rate to flow reversal.

  8. Controlling frontal photopolymerization with optical attenuation and mass diffusion.

    PubMed

    Hennessy, Matthew G; Vitale, Alessandra; Matar, Omar K; Cabral, João T

    2015-06-01

    Frontal photopolymerization (FPP) is a versatile directional solidification process that can be used to rapidly fabricate polymer network materials by selectively exposing a photosensitive monomer bath to light. A characteristic feature of FPP is that the monomer-to-polymer conversion profiles take on the form of traveling waves that propagate into the unpolymerized bulk from the illuminated surface. Practical implementations of FPP require detailed knowledge about the conversion profile and speed of these traveling waves. The purpose of this theoretical study is to (i) determine the conditions under which FPP occurs and (ii) explore how optical attenuation and mass transport can be used to finely tune the conversion profile and propagation kinetics. Our findings quantify the strong optical attenuation and slow mass transport relative to the rate of polymerization required for FPP. The shape of the traveling wave is primarily controlled by the magnitude of the optical attenuation coefficients of the neat and polymerized material. Unexpectedly, we find that mass diffusion can increase the net extent of polymerization and accelerate the growth of the solid network. The theoretical predictions are found to be in excellent agreement with experimental data acquired for representative systems. PMID:26172720

  9. Controlling frontal photopolymerization with optical attenuation and mass diffusion

    NASA Astrophysics Data System (ADS)

    Hennessy, Matthew G.; Vitale, Alessandra; Matar, Omar K.; Cabral, João T.

    2015-06-01

    Frontal photopolymerization (FPP) is a versatile directional solidification process that can be used to rapidly fabricate polymer network materials by selectively exposing a photosensitive monomer bath to light. A characteristic feature of FPP is that the monomer-to-polymer conversion profiles take on the form of traveling waves that propagate into the unpolymerized bulk from the illuminated surface. Practical implementations of FPP require detailed knowledge about the conversion profile and speed of these traveling waves. The purpose of this theoretical study is to (i) determine the conditions under which FPP occurs and (ii) explore how optical attenuation and mass transport can be used to finely tune the conversion profile and propagation kinetics. Our findings quantify the strong optical attenuation and slow mass transport relative to the rate of polymerization required for FPP. The shape of the traveling wave is primarily controlled by the magnitude of the optical attenuation coefficients of the neat and polymerized material. Unexpectedly, we find that mass diffusion can increase the net extent of polymerization and accelerate the growth of the solid network. The theoretical predictions are found to be in excellent agreement with experimental data acquired for representative systems.

  10. Agitating mass transfer with a warped disc's shadow

    NASA Astrophysics Data System (ADS)

    Cambier, H.

    2015-10-01

    For compact objects fed by Roche lobe overflow, accretion-generated X-rays irradiating the donor star can alter gas flow towards the Lagrange point thus varying mass transfer. The latest work specific to this topic consists of simple yet insightful two-dimensional hydrodynamics simulations stressing the role of global flow. To explore how a time-varying disc shadow affects mass transfer, I generalize the geometry, employ a robust hydrodynamics solver, and use phase space analysis near the nozzle to include coriolis lift there. Without even exposing the nozzle, a warped disc's shadow can drive mass transfer cycles by shifting the equatorial edges of the irradiation patches in turns: drawing in denser ambient gas before sweeping it into the nozzle. Other important effects remain missing in two-dimensional models, which I discuss along with prospects for more detailed yet efficient models.

  11. Augmentation of heat transfer by subsonic diffusion at a nearly separated state

    NASA Technical Reports Server (NTRS)

    Boldman, D. R.

    1972-01-01

    Measurements of mean velocity, turbulence intensity, and wall heat transfer were obtained in a 13 deg total angle of divergence conical diffuser coupled to a constant diameter recovery section. The results indicated that the boundary layer was in a nearly separated state. Turbulence intensity levels approaching 0.4 were observed in the latter stages of diffusion. The convective heat transfer was always equal to or higher than corresponding values for fully developed pipe flow at the same Reynolds number. The augmentation in heat transfer was greatest during the latter stages of diffusion where the Stanton number was nearly three times the pipe flow value.

  12. Calculation of Mass Transfer Coefficients in a Crystal Growth Chamber through Heat Transfer Measurements

    SciTech Connect

    Bell, J H; Hand, L A

    2005-04-21

    The growth rate of a crystal in a supersaturated solution is limited by both reaction kinetics and the local concentration of solute. If the local mass transfer coefficient is too low, concentration of solute at the crystal-solution interface will drop below saturation, leading to a defect in the growing crystal. Here, mass transfer coefficients are calculated for a rotating crystal growing in a supersaturated solution of potassium diphosphate (KDP) in water. Since mass transfer is difficult to measure directly, the heat transfer coefficient of a scale model crystal in water is measured using temperature-sensitive paint (TSP). To the authors' knowledge this is the first use of TSP to measure temperatures in water. The corresponding mass transfer coefficient is then calculated using the Chilton- Colburn analogy. Measurements were made for three crystal sizes at two running conditions each. Running conditions include periodic reversals of rotation direction. Heat transfer coefficients were found to vary significantly both across the crystal faces and over the course of a rotation cycle, but not from one face to another. Mean heat transfer coefficients increased with both crystal size and rotation rate. Computed mass transfer coefficients were broadly in line with expectations from the full-scale crystal growth experiments. Additional experiments show that continuous rotation of the crystal results in about a 30% lower heat transfer compared to rotation with periodic reversals. The continuous rotation case also shows a periodic variation in heat transfer coefficient of about 15%, with a period about 1/20th of the rotation rate.

  13. Measurements of airway dimensions and calculation of mass transfer characteristics of the human oral passage.

    PubMed

    Cheng, K H; Cheng, Y S; Yeh, H C; Swift, D L

    1997-11-01

    This paper presents measurements of the geometric shape, perimeter, and cross-sectional area of the human oral passage (from oral entrance to midtrachea) and relates them through dimensionless parameters to the depositional mass transfer of ultrafine particles. Studies were performed in two identical replicate oral passage models, one of which was cut orthogonal to the airflow direction into 3 mm elements for measurement, the other used intact for experimental measurements of ultrafine aerosol deposition. Dimensional data were combined with deposition measurements in two sections of the oral passage (the horizontal oral cavity and the vertical laryngeal-tracheal airway) to calculate the dimensionless mass transfer Sherwood number (Sh). Mass transfer theory suggests that Sh should be expressible as a function of the Reynolds number (Re) and the Schmidt number (Sc). For inhalation and exhalation through the oral cavity (O-C), an empirical relationship was obtained for flow rates from 7.5-30.0 1 min-1: Sh = 15.3 Re0.812 Sc-0.986 An empirical relationship was likewise obtained for the laryngeal-tracheal (L-T) region over the same range of flow rates: Sh = 25.9 Re0.861 Sc-1.37 These relationships were compared to heat transfer in the human upper airways through the well-known analogy between heat and mass transfer. The Reynolds number dependence for both the O-C and L-T relationships was in good agreement with that for heat transfer. The mass transfer coefficients were compared to extrathoracic uptake of gases and vapors and showed similar flow rate dependence. For gases and vapors that conform to the zero concentration boundary condition, the empirical relationships are applicable when diffusion coefficients are taken into consideration. PMID:9407288

  14. Subgrid models for mass and thermal diffusion in turbulent mixing

    NASA Astrophysics Data System (ADS)

    Lim, H.; Yu, Y.; Glimm, J.; Li, X.-L.; Sharp, D. H.

    2010-12-01

    We propose a new method for the large eddy simulation (LES) of turbulent mixing flows. The method yields convergent probability distribution functions (PDFs) for temperature and concentration and a chemical reaction rate when applied to reshocked Richtmyer-Meshkov (RM) unstable flows. Because such a mesh convergence is an unusual and perhaps original capability for LES of RM flows, we review previous validation studies of the principal components of the algorithm. The components are (i) a front tracking code, FronTier, to control numerical mass diffusion and (ii) dynamic subgrid scale (SGS) models to compensate for unresolved scales in the LES. We also review the relevant code comparison studies. We compare our results to a simple model based on 1D diffusion, taking place in the geometry defined statistically by the interface (the 50% isoconcentration surface between the two fluids). Several conclusions important to physics could be drawn from our study. We model chemical reactions with no closure approximations beyond those in the LES of the fluid variables itself, and as with dynamic SGS models, these closures contain no adjustable parameters. The chemical reaction rate is specified by the joint PDF for temperature and concentration. We observe a bimodal distribution for the PDF and we observe significant dependence on fluid transport parameters.

  15. Concentration Dependence of Solution Shear Viscosity and Solute Mass Diffusivity in Crystal Growth from Solutions

    NASA Technical Reports Server (NTRS)

    Izmailov, Alexander F.; Myerson, Allan S.

    1995-01-01

    The physical properties of a supersaturated binary solution such as its density rho, shear viscosity eta, and solute mass diffusivity D are dependent on the solute concentration c: rho = rho(c), eta = eta(c), and D = D(c). The diffusion boundary layer equations related to crystal growth from solution are derived for the case of natural convection with a solution density, a shear viscosity, and a solute diffusivity that are all depen- dent on solute concentration. The solution of these equations has demonstrated the following. (1) At the vicinity of the saturation concentration c(sub s) the solution shear viscosity eta depends on rho as eta(sub s) = eta(rho(sub s))varies as square root of rho(c(sub s)). This theoretically derived result has been verified in experiments with several aqueous solutions of inorganic and organic salts. (2) The maximum solute mass transfer towards the growing crystal surface can be achieved for values of c where the ratio of d ln(D(c)/dc) to d ln(eta(c)/dc) is a maximum.

  16. A protocol for the measurement of all the parameters of the mass transfer kinetics in columns used in liquid chromatography

    SciTech Connect

    Gritti, Fabrice; Guiochon, Georges A

    2010-01-01

    Band broadening in chromatography results from the combination of the dispersive effects that are associated with the different steps involved in the migration of compound bands along the column. These steps include longitudinal diffusion, trans-particle mass transfer, external film mass transfer, overall eddy diffusion, including trans-column, short-range inter-channel, trans-channel eddy diffusion, and the possible, additional mass transfer contributions arising from heat friction and the thermal heterogeneity of the column. We describe a series of experiments that provide the data needed to determine the coefficients of the contributions to band broadening of each one of these individual mass transfer steps. This specifically designed protocol can provide key information regarding the kinetic performance of columns used in liquid chromatography and explain why different columns behave so differently. The limitations, accuracy and precision of these methods are discussed. Further avenues of research that could improve the characterization of the mass transfer mechanisms in chromatographic columns, possibly contributing to the development of better columns, are suggested.

  17. Mass transfer apparatus and method for separation of gases

    DOEpatents

    Blount, Gerald C.

    2015-10-13

    A process and apparatus for separating components of a source gas is provided in which more soluble components of the source gas are dissolved in an aqueous solvent at high pressure. The system can utilize hydrostatic pressure to increase solubility of the components of the source gas. The apparatus includes gas recycle throughout multiple mass transfer stages to improve mass transfer of the targeted components from the liquid to gas phase. Separated components can be recovered for use in a value added application or can be processed for long-term storage, for instance in an underwater reservoir.

  18. Heat and mass transfer considerations in advanced heat pump systems

    SciTech Connect

    Panchal, C.B.; Bell, K.J.

    1992-01-01

    Advanced heat-pump cycles are being investigated for various applications. However, the working media and associated thermal design aspects require new concepts for maintaining high thermal effectiveness and phase equilibrium for achieving maximum possible thermodynamic advantages. In the present study, the heat- and mass-transfer processes in two heat-pump systems -- those based on absorption processes, and those using refrigerant mixtures -- are analyzed. The major technical barriers for achieving the ideal performance predicted by thermodynamic analysis are identified. The analysis provides general guidelines for the development of heat- and mass-transfer equipment for advanced heat-pump systems.

  19. Heat and mass transfer considerations in advanced heat pump systems

    SciTech Connect

    Panchal, C.B.; Bell, K.J.

    1992-08-01

    Advanced heat-pump cycles are being investigated for various applications. However, the working media and associated thermal design aspects require new concepts for maintaining high thermal effectiveness and phase equilibrium for achieving maximum possible thermodynamic advantages. In the present study, the heat- and mass-transfer processes in two heat-pump systems -- those based on absorption processes, and those using refrigerant mixtures -- are analyzed. The major technical barriers for achieving the ideal performance predicted by thermodynamic analysis are identified. The analysis provides general guidelines for the development of heat- and mass-transfer equipment for advanced heat-pump systems.

  20. Fuel cell collector plates with improved mass transfer channels

    SciTech Connect

    Gurau, Vladimir; Barbir, Frano; Neutzler, Jay K.

    2003-04-22

    A fuel cell collector plate can be provided with one or more various channel constructions for the transport of reactants to the gas diffusion layer and the removal of water therefrom. The outlet channel can be arranged to have a reduced volume compared to the inlet channel, in both interdigitated and discontinuous spiral applications. The land width between an inlet channel and outlet channel can be reduced to improved mass flow rate in regions of deleted reactant concentrations. Additionally or alternatively, the depth of the inlet channel can be reduced in the direction of flow to reduce the diffusion path as the concentration of reactant is reduced.

  1. Combined heat and mass transfer in absorption processes

    SciTech Connect

    Grossman, G.

    1982-01-01

    The approach to theoretical analysis of the combined heat and mass transfer process taking place in absorption systems is described. The two tranfer phenomena are strongly coupled here. The purpose of the analysis is to relate, quantitatively, the heat and mass transfer coefficients to the physical properties of the working fluids and to the geometry of the system. The preferred configuration is that of a falling film of liquid on a metallic surface which serves to transfer heat from the absorbent in contact with the vapor of the absorbate. The model developed may be solved for laminar, turbulent, or transition flow regimes. The results of the solution describe the development of the thermal and concentration boundary layers and the variation of the temperatures, concentrations, and heat and mass fluxes. These quantities in their normalized, dimensionless form depend on two characteristic parameters of the system: the Lewis number Le and the dimensionless heat of absorption lambda. The length in the direction of flow is normalized with respect to the Peclet number and the film thickness. Heat and mass transfer coefficients for the system were calculated. The Sherwood number for mass transfer from the vapor-liquid interface to the bulk of the film reaches a constant value of 3.63 with fully developed boundary layers for both the adiabatic and constant temperature wall. The Nusselt number for heat transfer from the interface to the bulk reaches under the same conditions values of 3.63 and 2.67 for the adiabatic and constant temperature wall, respectively. The Nusselt number for heat tranfer from the bulk to the wall reaches 1.60.

  2. Mass and charge transfer in the heavy ion reactions 208Ni and 208Ni

    NASA Astrophysics Data System (ADS)

    Sapotta, K.; Bass, R.; Hartmann, V.; Noll, H.; Renfordt, R. E.; Stelzer, K.

    1985-04-01

    Target-like reaction products corresponding to the transfer of one or several nucleons have been measured as a function of the total kinetic energy loss in the reactions 208Ni (1215 MeV) and 208Ni (1107 MeV) with a focusing time-of-flight spectrometer which provided a unique mass and charge separation and good energy resolution. The analysis of the experimental data covered the range from elastic scattering to deep-inelastic collisions. In the quasielastic region, neutron transfer dominates. The transfer probabilities as a function of the distance of closest approach can be described by a semiclassical theory of tunneling. Quasielastic transfer from the Ni targets to the 208Pb projectile is strongly inhibited by the reaction Q values. For the intermediate and deep-inelastic collisions, the mean values and variances of the mass and charge distributions as a function of the dissipated energy, as well as the correlations between neutron and proton transport, are discussed in a statistical diffusion theory. The important influence of the static potential energy surface on nucleon transport in the deep-inelastic region is demonstrated. Deviations from the simple diffusion model, observed at small to medium energy losses, are discussed.

  3. TWIN BINARIES: STUDIES OF STABILITY, MASS TRANSFER, AND COALESCENCE

    SciTech Connect

    Lombardi, J. C.; Holtzman, W.; Gearity, K.; Dooley, K. L.; Kalogera, V.; Rasio, F. A.

    2011-08-20

    Motivated by suggestions that binaries with almost equal-mass components ('twins') play an important role in the formation of double neutron stars and may be rather abundant among binaries, we study the stability of synchronized close and contact binaries with identical components in circular orbits. In particular, we investigate the dependency of the innermost stable circular orbit on the core mass, and we study the coalescence of the binary that occurs at smaller separations. For twin binaries composed of convective main-sequence stars, subgiants, or giants with low-mass cores (M{sub c} {approx}< 0.15M, where M is the mass of a component), a secular instability is reached during the contact phase, accompanied by a dynamical mass transfer instability at the same or at a slightly smaller orbital separation. Binaries that come inside this instability limit transfer mass gradually from one component to the other and then coalesce quickly as mass is lost through the outer Lagrangian points. For twin giant binaries with moderate to massive cores (M{sub c} {approx}> 0.15M), we find that stable contact configurations exist at all separations down to the Roche limit, when mass shedding through the outer Lagrangian points triggers a coalescence of the envelopes and leaves the cores orbiting in a central tight binary. In addition to the formation of binary neutron stars, we also discuss the implications of our results for the production of planetary nebulae with double degenerate central binaries.

  4. A METHOD FOR ESTIMATING DISTRIBUTIONS OF MASS TRANSFER RATE COEFFICIENTS WITH APPLICATION TO PURGING AND BATCH EXPERIMENTS. (R825825)

    EPA Science Inventory

    Mass transfer between aquifer material and groundwater is often modeled as first-order rate-limited sorption or diffusive exchange between mobile zones and immobile zones with idealized geometries. Recent improvements in experimental techniques and advances in our understanding o...

  5. Drop mass transfer in a microfluidic chip compared to a centrifugal contactor

    DOE PAGESBeta

    Nemer, Martin B.; Roberts, Christine C.; Hughes, Lindsey G.; Wyatt, Nicholas B.; Brooks, Carlton F.; Rao, Rekha

    2014-06-13

    A model system was developed for enabling a multiscale understanding of centrifugal-contactor liquid–liquid extraction.The system consisted of Nd(III) + xylenol orange in the aqueous phase buffered to pH =5.5 by KHP, and dodecane + thenoyltrifluroroacetone (HTTA) + tributyphosphate (TBP) in the organic phase. Diffusion constants were measured for neodymium in both the organic and aqueous phases, and the Nd(III) partition coefficients were measured at various HTTA and TBP concentrations. A microfluidic channel was used as a high-shear model environment to observe mass-transfer on a droplet scale with xylenol orange as the aqueous-phase metal indicator; mass-transfer rates were measured quantitatively inmore » both diffusion and reaction limited regimes on the droplet scale. Lastly, the microfluidic results were comparable to observations made for the same system in a laboratory scale liquid–liquid centrifugal contactor, indicating that single drop microfluidic experiments can provide information on mass transfer in complicated flows and geometries.« less

  6. Drop mass transfer in a microfluidic chip compared to a centrifugal contactor

    SciTech Connect

    Nemer, Martin B.; Roberts, Christine C.; Hughes, Lindsey G.; Wyatt, Nicholas B.; Brooks, Carlton F.; Rao, Rekha

    2014-06-13

    A model system was developed for enabling a multiscale understanding of centrifugal-contactor liquid–liquid extraction.The system consisted of Nd(III) + xylenol orange in the aqueous phase buffered to pH =5.5 by KHP, and dodecane + thenoyltrifluroroacetone (HTTA) + tributyphosphate (TBP) in the organic phase. Diffusion constants were measured for neodymium in both the organic and aqueous phases, and the Nd(III) partition coefficients were measured at various HTTA and TBP concentrations. A microfluidic channel was used as a high-shear model environment to observe mass-transfer on a droplet scale with xylenol orange as the aqueous-phase metal indicator; mass-transfer rates were measured quantitatively in both diffusion and reaction limited regimes on the droplet scale. Lastly, the microfluidic results were comparable to observations made for the same system in a laboratory scale liquid–liquid centrifugal contactor, indicating that single drop microfluidic experiments can provide information on mass transfer in complicated flows and geometries.

  7. Mixed convection heat and mass transfer in radially rotating rectangular ducts

    SciTech Connect

    Lee, K.T.; Yan, W.M.

    1998-11-27

    Heat transfer in rotating ducts is encountered in many engineering applications, such as cooling of turbomachinery, gas turbines, and other rotating systems. The present work investigates mixed convection heat and mass transfer in the entrance region of radially rotating rectangular ducts with water film evaporation along the porous duct walls. Mechanisms of secondary vortex development in the ducts under various conditions are examined by a vorticity-velocity numerical method. Emphasis is placed on the rotation effects, including both Coriolis and centrifugal buoyancy forces, and the mass diffusion effect on the flow structure and heat transfer characteristics. Results are presented in particular for an air-water vapor system under various conditions. Predicted results show that the effects of liquid film evaporation along the porous duct walls on the mixed convection heat transfer are rather substantial. The magnitude of the evaporative latent heat transfer may be 10 times greater than that of sensible heat transfer. The predictions also demonstrate that the distributions of Nu, Sh{sub z}, and fRe are closely related to the emergence, disappearance, growth, and decay of the rotating-induced secondary vortices. Additionally, a higher Nu{sub z} is found for a rectangular duct with a larger aspect ratio ({gamma} = 2) due to the relatively stronger secondary flows.

  8. Evaporation from flowing channels ( mass-transfer formulas).

    USGS Publications Warehouse

    Fulford, J.M.; Sturm, T.W.

    1984-01-01

    Stability-dependent and Dalton-type mass transfer formulas are determined from experimental evaporation data in ambient and heated channels and are shown to have similar performance in prediction of evaporation. The formulas developed are compared with those proposed by other investigators for lakes and flowing channels. -from ASCE Publications Information

  9. Dissociation and Mass Transfer Coefficients for Ammonia Volatilization Models

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Process-based models are being used to predict ammonia emissions from manure sources, but their accuracy has not been fully evaluated for cattle manure. Laboratory trials were conducted to measure the dissociation and mass transfer coefficients for ammonia volatilization from media of buffered ammon...

  10. LUT observations of the mass-transferring binary AI Dra

    NASA Astrophysics Data System (ADS)

    Liao, Wenping; Qian, Shengbang; Li, Linjia; Zhou, Xiao; Zhao, Ergang; Liu, Nianping

    2016-06-01

    Complete UV band light curve of the eclipsing binary AI Dra was observed with the Lunar-based Ultraviolet Telescope (LUT) in October 2014. It is very useful to adopt this continuous and uninterrupted light curve to determine physical and orbital parameters of the binary system. Photometric solutions of the spot model are obtained by using the W-D (Wilson and Devinney) method. It is confirmed that AI Dra is a semi-detached binary with secondary component filling its critical Roche lobe, which indicates that a mass transfer from the secondary component to the primary one should happen. Orbital period analysis based on all available eclipse times suggests a secular period increase and two cyclic variations. The secular period increase was interpreted by mass transfer from the secondary component to the primary one at a rate of 4.12 ×10^{-8}M_{⊙}/yr, which is in agreement with the photometric solutions. Two cyclic oscillations were due to light travel-time effect (LTTE) via the presence of two cool stellar companions in a near 2:1 mean-motion resonance. Both photometric solutions and orbital period analysis confirm that AI Dra is a mass-transferring binary, the massive primary is filling 69 % of its critical Roche lobe. After the primary evolves to fill the critical Roche lobe, the mass transfer will be reversed and the binary will evolve into a contact configuration.

  11. Interphase mass transfer between fluids in subsurface formations: A review

    NASA Astrophysics Data System (ADS)

    Agaoglu, Berken; Copty, Nadim K.; Scheytt, Traugott; Hinkelmann, Reinhard

    2015-05-01

    This paper presents a review of the state-of-the-art on interphase mass transfer between immiscible fluids in porous media with focus on the factors that have significant influence on this process. In total close to 300 papers were reviewed focusing to a large extent on the literature relating to NAPL contamination of the subsurface. The large body of work available on this topic was organized according to the length scale of the conducted studies, namely the pore, meso and field scales. The interrelation of interphase mass transfer at these different scales is highlighted. To gain further insight into interphase mass transfer, published studies were discussed and evaluated in terms of the governing flow configurations defined in terms of the wettability and mobility of the different phases. Such organization of the existing literature enables the identification of the interfacial domains that would have significant impact on interphase mass transfer. Available modeling approaches at the various length scales are discussed with regard to current knowledge on the physics of this process. Future research directions are also suggested.

  12. A Course in Advanced Topics in Heat and Mass Transfer.

    ERIC Educational Resources Information Center

    Shaeiwitz, Joseph A.

    1983-01-01

    A three or four semester-hour graduate course was designed to provide basic instruction in heat/mass transfer topics relevant to chemical engineering problems and to train students to develop mathematical descriptions for new situations encountered in problem-solving. Course outline and list of references used in the course are provided. (JM)

  13. Multidimensional mechanistic modeling of interfacial heat and mass transfer

    SciTech Connect

    Shaver, D. R.; Antal, S. P.; Podowski, M. Z.

    2012-07-01

    A combined theoretical and computational study in modeling multidimensional, diabatic vapor/liquid flows is presented. Models have been developed governing kinematic aspects of multiphase flow as well as interfacial mass and heat transfer for flows of condensable gas (vapor) and liquids. The modeling formulation is based on the Reynolds averaged Navier-Stokes (RANS) type multi-field approach which utilizes a complete set of conservation equations for each fluid component 1. The modeled interfacial interactions include energy, mass, and momentum transfer. Emphasis in the model development work has been placed on the mechanisms governing coupled interfacial heat and mass transfer between the liquid and vapor fields (condensation and/or boiling). A method for tracking changes in bubble size is presented and tested. Locally based models of multidimensional effects have been analyzed, including distributions of fluid temperatures and volume fractions. The overall model accounts for both kinematic and thermodynamic nonequilibrium between the component fluids including superheated vapor. The model has been implemented in the NPHASE-CMFD computer code. Results from the kinematic model are compared to experimental data and good agreement is demonstrated. The heat and mass transfer model is parametrically tested to show the multidimensional effects on the rate of heat and mass transfer. These effects are explained in terms of local characteristics of the two-phase flow. The model is applied to a scenario of saturated vapor injected into a subcooled flow through a heated, porous wall. This provides a reasonable approximation to subcooled boiling. The results are found to be dependent on the partitioning of the wall heat flux between direct liquid heating and vapor generation. However, the observed dependencies are explained and the modeling is considered consistent. (authors)

  14. Mass and heat transfer model of Tubular Solar Still

    SciTech Connect

    Ahsan, Amimul; Fukuhara, Teruyuki

    2010-07-15

    In this paper, a new mass and heat transfer model of a Tubular Solar Still (TSS) was proposed incorporating various mass and heat transfer coefficients taking account of the humid air properties inside the still. The heat balance of the humid air and the mass balance of the water vapor in the humid air were formulized for the first time. As a result, the proposed model enabled to calculate the diurnal variations of the temperature, water vapor density and relative humidity of the humid air, and to predict the hourly condensation flux besides the temperatures of the water, cover and trough, and the hourly evaporation flux. The validity of the proposed model was verified using the field experimental results carried out in Fukui, Japan and Muscat, Oman in 2008. The diurnal variations of the calculated temperatures and water vapor densities had a good agreement with the observed ones. Furthermore, the proposed model can predict the daily and hourly production flux precisely. (author)

  15. Mass transfer experiments on single irregular-shaped particles

    SciTech Connect

    Ramezan, M. ); Kale, S.R. ); Anderson, R.J. )

    1991-01-01

    Mass transfer from irregular-shaped naphthalene particles (100-200 {mu}m in size) was studied in an electrodynamic balance. Charged particles were suspended in an electrostatic field directly in line with a calibrated air jet. Mass and size change histories were obtained under ambient conditions, and under steady- and pulsed-flow conditions. For natural convection, the time-averaged Sherwood number was similar to that for spheres. Forced-convection Sherwood number under steady-flow conditions was strongly dependent on particle shape and particle Reynolds number, and was consistently higher than values predicted for spheres at comparable Reynolds numbers. This paper validates the technique and indicates the shape effect on mass transfer from single particles.

  16. Vadose Zone VOC Mass Transfer Testing At The SRS Miscellaneous Chemical Basin

    SciTech Connect

    Riha, B

    2005-10-30

    Active remedial activities have been ongoing since 1996 to address low levels of solvent contamination at the Miscellaneous Chemical Basin at SRS. Contaminant levels in the subsurface may be approaching levels where mass transfer limitations are impacting the efficiency of the remedial action. Rate limited mass transfer effects have been observed at other sites in the vadose zone at the SRS, however, detailed measurements and evaluation has not been undertaken. Anecdotal evidence suggests that the mass transfer rates are very slow from the fine grain sediments. This conclusion is based on the observation that measured soil gas concentrations tend to be low in permeable zones relative to the higher concentrations found in fine grain zones. Decreasing soil gas concentration with depth below the ''upland unit'' at several areas at SRS is also evidence of slow diffusion rates. In addition, due to the length of time since disposal ceased at the MCB, we hypothesize that mobile solvents have migrated downward, and the solvent remaining in the upper fine grain zone (''upland unit'') are trapped in fine grain material and are primarily released by gas diffusion (Riha and Rossabi 2004). Natural weathering and other chemical solutions disposed with the solvents can further enhance this effect by increasing the micro-porosity in the clays (kaolinite). This microporosity can result in increased entrapment of water and solvents by capillary forces (Powers, et. al., 2003). Also supporting this conclusion is the observation that active SVE has proven ineffective on VOC removal from the fine grain zones at the SRS. Adsorption and the very slow release phenomenon have been documented similarly in the literature especially for old solvent spills such as at the SRS (Pavlostathis and Mathavan 1992; Oostrom and Lenhard 2003). Mass transfer relationships need to be developed in order to optimize remediation activities and to determine actual loading rates to groundwater. These metrics

  17. Effect of protein molecular weight on the mass transfer in protein mixing

    NASA Astrophysics Data System (ADS)

    Asad, Ahmed; Chai, Chuan; Wu, JiangTao

    2012-03-01

    The mixing of protein solutions with that of precipitating agents is very important in protein crystallization experiments. In this work, the interferometry images were recorded during the mixing of two proteins with different molecular weights: lysozyme of ˜14.6 kDa, trypsin of ˜23.3 kDa and pepsin of ˜34.8 kDa were placed in a Mach-Zehnder interferometer. The protein molecular weight dependence on the competition of the transport process and kinetics at the interface was studied. The concentration profiles of protein solutions were calculated to analyze the mass transfer during the mixing process. It was observed that the mass transfer process is more efficient during the mixing of proteins with higher molecular weights. In addition, the more rapid concentration changes above the interface suggest that convection may dominate the diffusion. The phenomenon of convection is higher in the protein solutions with higher molecular weight.

  18. Heat and mass transfer at adiabatic evaporation of binary zeotropic solutions

    NASA Astrophysics Data System (ADS)

    Makarov, M. S.; Makarova, S. N.

    2016-01-01

    Results of numerical simulation of heat and mass transfer in a laminar flow of three-component gas at adiabatic evaporation of binary solutions from a flat plate are presented. The studies were carried out for the perfect solution of ethanol/methanol and zeotrope solutions of water/acetone, benzene/acetone, and ethanol/acetone. The liquid-vapor equilibrium is described by the Raoult law for the ideal solution and Carlson-Colburn model for real solutions. The effect of gas temperature and liquid composition on the heat and diffusion flows, and temperature of vapor-gas mixture at the interface is analyzed. The formula for calculating the temperature of the evaporation surface for the binary liquid mixtures using the similarity of heat and mass transfer was proposed. Data of numerical simulations are in a good agreement with the results of calculations based on the proposed dependence for all examined liquid mixtures in the considered range of temperatures and pressures.

  19. Estimation of whole lemon mass transfer parameters during hot air drying using different modelling methods

    NASA Astrophysics Data System (ADS)

    Torki-Harchegani, Mehdi; Ghanbarian, Davoud; Sadeghi, Morteza

    2015-08-01

    To design new dryers or improve existing drying equipments, accurate values of mass transfer parameters is of great importance. In this study, an experimental and theoretical investigation of drying whole lemons was carried out. The whole lemons were dried in a convective hot air dryer at different air temperatures (50, 60 and 75 °C) and a constant air velocity (1 m s-1). In theoretical consideration, three moisture transfer models including Dincer and Dost model, Bi- G correlation approach and conventional solution of Fick's second law of diffusion were used to determine moisture transfer parameters and predict dimensionless moisture content curves. The predicted results were then compared with the experimental data and the higher degree of prediction accuracy was achieved by the Dincer and Dost model.

  20. Energy (mass) transfer processes in low-temperature plasma as applied to forming ordered structures

    NASA Astrophysics Data System (ADS)

    Abramenko, T. N.; Laktyushina, T. V.; Laktyushin, A. N.

    2000-03-01

    The methods of irreversible thermodynamics are adopted to analyze the energy (mass) transfer in gases (their mixtures) over a wide temperature range up to 20000 K. An energy transfer process is considered as a path in the state space, and a concept of non-Euclidean state space is postulated. Experimental data on the gas thermal conductivity over a wide temperature range is generalized by the methods of thermodynamic similarity theory. Thermal conductivities of CH4-O2 and CH4-H2O mixtures are calculated for technological applications. The process of forming a space-time structure is analyzed by using the experimental data on the gas thermal conductivity over a wide temperature range. An attempt is made to interpret the mechanism of the thermal diffusion in gases due to the forming of ordered structures. A contribution of the diffusional thermoeffect to the energy transfer processes in a three-component nitrogen plasma is calculated.

  1. Modelling heat and mass transfer in a membrane-based air-to-air enthalpy exchanger

    NASA Astrophysics Data System (ADS)

    Dugaria, S.; Moro, L.; Del, D., Col

    2015-11-01

    The diffusion of total energy recovery systems could lead to a significant reduction in the energy demand for building air-conditioning. With these devices, sensible heat and humidity can be recovered in winter from the exhaust airstream, while, in summer, the incoming air stream can be cooled and dehumidified by transferring the excess heat and moisture to the exhaust air stream. Membrane based enthalpy exchangers are composed by different channels separated by semi-permeable membranes. The membrane allows moisture transfer under vapour pressure difference, or water concentration difference, between the two sides and, at the same time, it is ideally impermeable to air and other contaminants present in exhaust air. Heat transfer between the airstreams occurs through the membrane due to the temperature gradient. The aim of this work is to develop a detailed model of the coupled heat and mass transfer mechanisms through the membrane between the two airstreams. After a review of the most relevant models published in the scientific literature, the governing equations are presented and some simplifying assumptions are analysed and discussed. As a result, a steady-state, two-dimensional finite difference numerical model is setup. The developed model is able to predict temperature and humidity evolution inside the channels. Sensible and latent heat transfer rate, as well as moisture transfer rate, are determined. A sensitive analysis is conducted in order to determine the more influential parameters on the thermal and vapour transfer.

  2. Simplified Simulation of Mass Transfer in Double White Dwarf Systems

    NASA Astrophysics Data System (ADS)

    Vannah, Sara; Frank, Juhan

    2016-01-01

    The behavior both stable and unstable mass transfer in semi-detached double white dwarfs triggers a cornucopia of astrophysical phenomena including Type Ia supernovae and AM CVn stars. Current 3D hydrodynamic simulations of the evolution these systems following the mass transfer, binary orbital parameters, and the self-consistent gravitational field over several tens of orbital periods have produced a wealth of data. However, these simulations can take weeks to months in high-performance computing platforms to execute. To help with the interpretation of results of such large scale simulations, and to enable a quick exploration of binary parameter space, we have developed a Mathematica code that integrates forward in time a system of 5 ODEs describing the orbit-averaged evolution of the binary separation as well as the radius, mass, and spin angular momentum of both components of the binary. By adjusting a few parameters describing the mass transfer as a function of the Roche-lobe overflow and the strength of the tidal coupling between the orbit and component spins we are able to obtain approximate fits to previously run hydrodynamic simulations. This simplified simulation is able to run simulations similar to the hydrodynamic versions in a matter of seconds on a dual-core PC or Mac computer.

  3. Evaporative Mass Transfer Behavior of a Complex Immiscible Liquid

    PubMed Central

    McColl, Colleen M.; Johnson, Gwynn R.; Brusseau, Mark L.

    2010-01-01

    A series of laboratory experiments was conducted with a multiple-component immiscible liquid, collected from the Picillo Farm Superfund Site in Rhode Island, to examine liquid-vapor mass-transfer behavior. The immiscible liquid, which comprises solvents, oils, pesticides, PCBs, paint sludges, explosives, and other compounds, was characterized using gas chromatography and gas chromatography/mass spectrometry to determine mole fractions of selected constituents. Batch experiments were conducted to evaluate equilibrium phase-partitioning behavior. Two sets of air-stripping column studies were conducted to examine the mass-transfer dynamics of five selected target compounds present in the immiscible-liquid mixture. One set of column experiments was designed to represent a system with free-phase immiscible liquid present; the other was designed to represent a system with a residual phase of immiscible liquid. Initial elution behavior of all target components generally appeared to be ideal for both systems, as the initial vapor-phase concentrations were similar to vapor-phase concentrations measured for the batch experiment and those estimated using Raoult’s law (incorporating the immiscible-liquid composition data). Later-stage removal of 1,2-dichlorobenzene appeared to be rate limited for the columns containing free-phase immiscible liquid and no porous medium. Conversely, evaporative mass transfer appeared to be ideal throughout the experiment conducted with immiscible liquid distributed relatively uniformly as a residual phase within a sandy porous medium. PMID:18614196

  4. A hybrid transport-diffusion model for radiative transfer in absorbing and scattering media

    SciTech Connect

    Roger, M.; Caliot, C.; Crouseilles, N.; Coelho, P.J.

    2014-10-15

    A new multi-scale hybrid transport-diffusion model for radiative transfer is proposed in order to improve the efficiency of the calculations close to the diffusive regime, in absorbing and strongly scattering media. In this model, the radiative intensity is decomposed into a macroscopic component calculated by the diffusion equation, and a mesoscopic component. The transport equation for the mesoscopic component allows to correct the estimation of the diffusion equation, and then to obtain the solution of the linear radiative transfer equation. In this work, results are presented for stationary and transient radiative transfer cases, in examples which concern solar concentrated and optical tomography applications. The Monte Carlo and the discrete-ordinate methods are used to solve the mesoscopic equation. It is shown that the multi-scale model allows to improve the efficiency of the calculations when the medium is close to the diffusive regime. The proposed model is a good alternative for radiative transfer at the intermediate regime where the macroscopic diffusion equation is not accurate enough and the radiative transfer equation requires too much computational effort.

  5. A hybrid transport-diffusion model for radiative transfer in absorbing and scattering media

    NASA Astrophysics Data System (ADS)

    Roger, M.; Caliot, C.; Crouseilles, N.; Coelho, P. J.

    2014-10-01

    A new multi-scale hybrid transport-diffusion model for radiative transfer is proposed in order to improve the efficiency of the calculations close to the diffusive regime, in absorbing and strongly scattering media. In this model, the radiative intensity is decomposed into a macroscopic component calculated by the diffusion equation, and a mesoscopic component. The transport equation for the mesoscopic component allows to correct the estimation of the diffusion equation, and then to obtain the solution of the linear radiative transfer equation. In this work, results are presented for stationary and transient radiative transfer cases, in examples which concern solar concentrated and optical tomography applications. The Monte Carlo and the discrete-ordinate methods are used to solve the mesoscopic equation. It is shown that the multi-scale model allows to improve the efficiency of the calculations when the medium is close to the diffusive regime. The proposed model is a good alternative for radiative transfer at the intermediate regime where the macroscopic diffusion equation is not accurate enough and the radiative transfer equation requires too much computational effort.

  6. Mixing and mass transfer considerations in highly viscous fermentations

    SciTech Connect

    Applegate, M.A.; Flatt, J.H.

    1995-12-01

    Highly viscous microbial fermentations pose difficult scale-up challenges for the industrial biochemical engineer. Incomplete bulk mixing and poor oxygen mass transfer often limit fermentor titers and productivities. Lower heat transfer coefficients coupled with higher rates of heat generation through viscous dissipation further confound operational difficulties. Practical approaches to alleviating these factors will be discussed using examples from viscoelastic gellan, welan, and xanthan gum fermentations. In addition, a summary of the effects of power input, aeration, media manipulation, and genetic modifications will be discussed.

  7. Mass transfer at gas-evolving surfaces in electrolysis

    SciTech Connect

    Dees, D.W.; Tobias, C.W.

    1983-09-01

    A novel micro-mosaic electrode was developed to resolve time-dependent, mass-transfer distribution in the close vicinity of bubble phenomena. The electrode, prepared on a silicon wafer using integrated circuit manufacturing technology, consists of a 10 by 10 matrix of coplanar, electrically isolated, square platinum segments on 100 micron centers, surrounded by a relatively large buffer segment. A computer-actuated data acquisition and control system was assembled and the software developed to monitor the current to each of the segments and control the potential of selected segments. The utility of the electrode to examine interfacial mass transport phenomena which have characteristic lengths as small as 100 microns has been clearly demonstrated. The effect of a single hydrogen bubble disengagement and of the coalescence of two bubbles, on the limiting current of the reduction of ferric to ferrous ion was measured using the micro-mosaic electrode in a horizontal: facing-up orientation. In the absence of gas evolution, large regular fluctuations in the limiting current to the segments with a period of 29 sec were observed. This periodic behavior is attributed to free convection: a cellular fluid motion moving across the electrode with a velocity of 40 microns/second. It was found that the mass-transfer enhancement due to bubble disengagement is small when compared to that due to coalescence. Increases in the mass-transfer rate of more than an order of magnitude over the free convection limiting current were observed for the coalescence phenomena. Two theoretical models were developed to account for the observed effect of a bubble disengagement on the mass transfer-rate to the surface.

  8. Fundamental mass transfer modeling of emission of volatile organic compounds from building materials

    NASA Astrophysics Data System (ADS)

    Bodalal, Awad Saad

    In this study, a mass transfer theory based model is presented for characterizing the VOC emissions from building materials. A 3-D diffusion model is developed to describe the emissions of volatile organic compounds (VOCs) from individual sources. Then the formulation is extended to include the emissions from composite sources (system comprising an assemblage of individual sources). The key parameters for the model (The diffusion coefficient of the VOC in the source material D, and the equilibrium partition coefficient k e) were determined independently (model parameters are determined without the use of chamber emission data). This procedure eliminated to a large extent the need for emission testing using environmental chambers, which is costly, time consuming, and may be subject to confounding sink effects. An experimental method is developed and implemented to measure directly the internal diffusion (D) and partition coefficients ( ke). The use of the method is illustrated for three types of VOC's: (i) Aliphatic Hydrocarbons, (ii) Aromatic Hydrocarbons and ( iii) Aldehydes, through typical dry building materials (carpet, plywood, particleboard, vinyl floor tile, gypsum board, sub-floor tile and OSB). Then correlations for predicting D and ke based solely on commonly available properties such as molecular weight and vapour pressure were proposed for each product and type of VOC. These correlations can be used to estimate the D and ke when direct measurement data are not available, and thus facilitate the prediction of VOC emissions from the building materials using mass transfer theory. The VOC emissions from a sub-floor material (made of the recycled automobile tires), and a particleboard are measured and predicted. Finally, a mathematical model to predict the diffusion coefficient through complex sources (floor adhesive) as a function of time was developed. Then this model (for diffusion coefficient in complex sources) was used to predict the emission rate from

  9. Mass transfer of large molecules through collagen and collagen-silica hybrid membranes

    NASA Astrophysics Data System (ADS)

    Jofre-Lora, Pedro

    Diabetes is a growing concern in the United States and around the world that must be addressed through new treatment options. Current standard treatment options of diabetes are limiting and have tremendous impacts on patient's lives. Emerging therapies, such as the implantation of encapsulated islets, are promising treatment options, but have not yet materialized due to unsolved problems with material properties. Hybrid silica-collagen membranes address some of these unsolved problems and are a promising material for cell encapsulation. However, the mass transfer properties of large molecules, such as insulin, TNF-alpha, IL1beta, and other important proteins in the etiology of diabetes, through these hybrid membranes are poorly characterized. In order to begin characterizing these properties, a device was constructed to accurately and efficiently measure the mass transfer of other similar large molecules, fluorescein isothiocyanate dextrans (FITC-dextran), through collagen-silica hybrid membranes. The device was used to measure diffusion coefficients of 4, 20, 40, and 150 kDa FITC-dextrans through non-silicified and silicified samples of 200 and 1000 Pa porcine skin collagen. Diffusion coefficients were found to be in the 10-7-10-6 cm2s -1 range, which is in agreement with previously published data for similar molecules through similar hydrogels. The effects of collagen stiffness, FITC-dextran molecular weight, and silicification treatment on diffusion were investigated. It was found that collagen stiffness and FITC-dextran molecular weight had a negative correlation with diffusion, whereas silicification treatment had no global impact on diffusion. The device created, and the results of this preliminary investigation, can be used to develop collagen-silica hybrid membranes as an alternative material for cell encapsulation in a forward-design manner.

  10. Modeling PAH mass transfer in a slurry of contaminated soil or sediment amended with organic sorbents.

    PubMed

    Ahn, Sungwoo; Werner, David; Luthy, Richard G

    2008-06-01

    A three-compartment kinetic partitioning model was employed to assess contaminant mass transfer and intraparticle diffusion in systems comprising dense slurries of polluted soil or aquifer sediment with or without sorbent amendments to sequester polycyclic aromatic hydrocarbons (PAHs). The model was applied to simulate temporal changes in aqueous and particle-bound PAH concentrations comparing different pollution sources (heavy oil or tar sludge) and various sorbent amendments (polyoxymethylene (POM), coke breeze, and activated carbon). For the model evaluation, all the parameters needed were directly measured from a series of experiments, allowing full calibration and verification of model predictions without parameter fitting. The numerical model reproduced two separate laboratory-scale experiments reasonably: PAH uptake in POM beads and PAH uptake by semipermeable membrane devices. PAH mass transfer was then simulated for various scenarios, considering different sorbent doses and mass transfer rates as well as biodegradation. Such model predictions provide a quick assessment tool for identifying mass transfer limitations during washing, stabilization, or bioslurry treatments of polluted soil or sediment in mixed systems. It appears that PAHs would be readily released from materials contaminated by small oil droplets, but not tar decanter sludge. Released PAHs would be sequestered rapidly by activated carbon amendment but to a much lesser extent by coke breeze. If sorbing black carbon is present in the slurries, POM pellets would not be effective as a sequestration amendment. High first-order biodegradation rates in the free aqueous phase, e.g., in the order of 0.001 s(-1) for phenanthrene, would be required to compete effectively with adsorption and mass transfer for strong sorbents. PMID:18456306

  11. The calculational modeling of impurity mass transfer in NPP circuits with liquid metal coolant

    NASA Astrophysics Data System (ADS)

    Alexeev, V.; Kozlov, F.; Kumaev, V.; Orlova, E.; Klimanova, Yu; Torbenkova, I.

    2008-02-01

    The authors create three levels of models (one-dimensional, two-dimensional and three-dimensional) for estimation of impurity mass transfer in sodium circuits units as well as applicable computational programs. In the one-dimensional model the flow path elements are simulated by annular channels. The Lagrange coordinate system is used in the mathematical description of processes in channels. The two-dimensional model is based on the porous body approximation and enables one to simulate global spatial distributions of coolant flow velocity fields, coolant and fuel rods temperatures, and concentration distribution of transferred substances. The mathematical description of passive multicomponent impurity transfer is carried out using the system of the differential equations with sources and impurity diffusion, written for each component. The equations are solved by the finite-difference method. The developed version of the three-dimensional code is based on a general approach of the spatial three-dimensional description of thermal-hydraulic and mass-transfer processes in fuel rod bundles. The determining system of finite-difference equations of hydrodynamics and heat exchange is obtained using the control volume approach. As a result of the performed calculations, valuable data on corrosion products transfer in the primary circuit of the BN-600 reactor are obtained.

  12. Origin of Self-preservation Effect for Hydrate Decomposition: Coupling of Mass and Heat Transfer Resistances.

    PubMed

    Bai, Dongsheng; Zhang, Diwei; Zhang, Xianren; Chen, Guangjin

    2015-01-01

    Gas hydrates could show an unexpected high stability at conditions out of thermodynamic equilibrium, which is called the self-preservation effect. The mechanism of the effect for methane hydrates is here investigated via molecular dynamics simulations, in which an NVT/E method is introduced to represent different levels of heat transfer resistance. Our simulations suggest a coupling between the mass transfer resistance and heat transfer resistance as the driving mechanism for self-preservation effect. We found that the hydrate is initially melted from the interface, and then a solid-like water layer with temperature-dependent structures is formed next to the hydrate interface that exhibits fractal feature, followed by an increase of mass transfer resistance for the diffusion of methane from hydrate region. Furthermore, our results indicate that heat transfer resistance is a more fundamental factor, since it facilitates the formation of the solid-like layer and hence inhibits the further dissociation of the hydrates. The self-preservation effect is found to be enhanced with the increase of pressure and particularly the decrease of temperature. Kinetic equations based on heat balance calculations is also developed to describe the self-preservation effect, which reproduces our simulation results well and provides an association between microscopic and macroscopic properties. PMID:26423519

  13. Origin of Self-preservation Effect for Hydrate Decomposition: Coupling of Mass and Heat Transfer Resistances

    PubMed Central

    Bai, Dongsheng; Zhang, Diwei; Zhang, Xianren; Chen, Guangjin

    2015-01-01

    Gas hydrates could show an unexpected high stability at conditions out of thermodynamic equilibrium, which is called the self-preservation effect. The mechanism of the effect for methane hydrates is here investigated via molecular dynamics simulations, in which an NVT/E method is introduced to represent different levels of heat transfer resistance. Our simulations suggest a coupling between the mass transfer resistance and heat transfer resistance as the driving mechanism for self-preservation effect. We found that the hydrate is initially melted from the interface, and then a solid-like water layer with temperature-dependent structures is formed next to the hydrate interface that exhibits fractal feature, followed by an increase of mass transfer resistance for the diffusion of methane from hydrate region. Furthermore, our results indicate that heat transfer resistance is a more fundamental factor, since it facilitates the formation of the solid-like layer and hence inhibits the further dissociation of the hydrates. The self-preservation effect is found to be enhanced with the increase of pressure and particularly the decrease of temperature. Kinetic equations based on heat balance calculations is also developed to describe the self-preservation effect, which reproduces our simulation results well and provides an association between microscopic and macroscopic properties. PMID:26423519

  14. Mass transfer and magnetic braking in Sco X-1

    NASA Astrophysics Data System (ADS)

    Pavlovskii, K.; Ivanova, N.

    2016-02-01

    Sco X-1 is a low-mass X-ray binary (LMXB) that has one of the most precisely determined set of binary parameters such as the mass accretion rate, companions mass ratio and the orbital period. For this system, as well as for a large fraction of other well-studied LMXBs, the observationally-inferred mass accretion rate is known to strongly exceed the theoretically expected mass transfer (MT) rate. We suggest that this discrepancy can be solved by applying a modified magnetic braking prescription, which accounts for increased wind mass-loss in evolved stars compared to main sequence stars. Using our MT framework based on MESA, we explore a large range of binaries at the onset of the MT. We identify the subset of binaries for which the MT tracks cross the Sco X-1 values for the mass ratio and the orbital period. We confirm that no solution can be found for which the standard magnetic braking can provide the observed accretion rates, while wind-boosted magnetic braking can provide the observed accretion rates for many progenitor binaries that evolve to the observed orbital period and mass ratio.

  15. Modeling of solid-side mass transfer in desiccant particle beds

    SciTech Connect

    Pesaran, A.A.; Mills, A.F.

    1984-02-01

    A model is proposed for heat and mass transfer in a packed bed of desiccant particles and accounts for both Knudsen and surface diffusion within the particles. Using the model, predictions are made for the response of thin beds of silica gel particles to a step change in air inlet conditions compared to mental results. The predictions are found to be satisfactory and, in general, superior to those of pseudogas-side controlled models commonly used for the design of desiccant dehumidifiers for solar air conditioning application.

  16. MASS TRANSFER TO ROTATING DISKS AND ROTATING RINGS IN LAMINAR, TRANSITION, AND FULLY DEVELOPED TURBULENT FLOW

    SciTech Connect

    Law Jr., C.G.; Pierini, P.; Newman, J.

    1980-07-01

    Experimental data and theoretical calculations are presented for the mass-transfer rate to rotating disks and rotating rings when laminar, transition, and fully developed turbulent flow exist upon different portions of the surface. Good agreement of data and the model is obtained for rotating disks and relatively thick rotating rings. Results of the calculations for thin rings generally exceed the experimental data measured in transition and turbulent flow. A y{sup +{sup 3}} form for the eddy diffusivity is used to fit the data. No improvement is noticed with a form involving both y{sup +{sup 3}} and y{sup +{sup 3}}.

  17. Chemical separations by bubble-assisted interphase mass-transfer.

    PubMed

    Boyd, David A; Adleman, James R; Goodwin, David G; Psaltis, Demetri

    2008-04-01

    We show that when a small amount of heat is added close to a liquid-vapor interface of a captive gas bubble in a microchannel, interphase mass-transfer through the bubble can occur in a controlled manner with only a slight change in the temperature of the fluid. We demonstrate that this method, which we refer to as bubble-assisted interphase mass-transfer (BAIM), can be applied to interphase chemical separations, e.g., simple distillation, without the need for high temperatures, vacuum, or active cooling. Although any source of localized heating could be used, we illustrate BAIM with an all-optical technique that makes use of the plasmon resonance in an array of nanoscale metal structures that are incorporated into the channel to produce localized heating of the fluid when illuminated by a stationary low-power laser. PMID:18321130

  18. Mass-transfer in close binary and their companions

    NASA Astrophysics Data System (ADS)

    Liao, Wenping; Qian, Shengbang; Zhu, Liying; Li, Linjia

    2016-07-01

    Secular and/or cyclical orbital period variations of close binaries can be derived by analyzing the (O-C) diagram. The secular variations are usually explained as mass transfer between components, while the most plausible explanation of the cyclic period changes is the light-travel time effect (LTTE) through the presence of a third body. Mass transfer and additional companions in close binary systems are important for understanding the formation and evolution of the systems. Here, UV light curves of several close binaries based on the Lunar-based Ultraviolet Telescope (LUT) observations are presented and analyzed with the Wilson-Devinney (W-D) method. Then, based on those light-curve solutions and new analysis of the orbital period variations, the multiplicity, geometrical structure and evolution state of targets are discussed.

  19. Conjugate mixed convection heat and mass transfer in brick drying

    NASA Astrophysics Data System (ADS)

    Suresh, H. N.; Aswatha Narayana, P. A.; Seetharamu, K. N.

    In this study, a numerical methodology for the solution of conjugate heat and mass transfer problem is presented. Fluid flow, heat and mass transfer over a rectangular brick due to transient laminar mixed convection has been numerically simulated. The coupled non-linear partial differential equations, for both gas phase and solid are solved using finite element procedure. Flow is assumed to be incompressible, two-dimensional, laminar. Analysis has been carried out at a Reynolds number of 200 with Pr=0.71. The effect of buoyancy on the brick drying has been investigated. Velocity vectors, streamlines in the flow field and temperature and moisture contours and temperature distribution along the solid surface are presented. It is observed that there is considerable effect of buoyancy during drying. The results indicate a non-uniform drying of the brick with the leading edge drying faster than the rest of the brick.

  20. Heat and Mass Transfer in a Freezing Unsaturated Porous Medium

    NASA Astrophysics Data System (ADS)

    Jame, Yih-Wu; Norum, Donald I.

    1980-08-01

    A numerical simulation of a laboratory experiment involving coupled heat and mass transfer in a horizontal porous medium column with one end subjected to a temperature below 0°C has been carried out. The model is essentially that of Harlan (1973) and is solved numerically by the finite difference method using the Crank-Nicholson scheme. The solution yields temperature, liquid water content, and ice content profiles along the column as a function of time. Comparison of the experimental results and the simulation analysis results shows that Harlan's model, with some modification in the hydraulic conductivity of the frozen medium, can be used successfully to simulate numerically the coupled heat and mass transfer processes when ice lensing does not occur.

  1. Nonlinear analysis of capillary instability with heat and mass transfer

    NASA Astrophysics Data System (ADS)

    Awasthi, Mukesh Kumar; Agrawal, G. S.

    2012-06-01

    The nonlinear capillary instability of the cylindrical interface between the vapor and liquid phases of a fluid is studied when there is heat and mass transfer across the interface, using viscous potential flow theory. The fluids are considered to be viscous and incompressible with different kinematic viscosities. Both asymmetric and axisymmetric disturbances are considered. The analysis is based on the method of multiple scale perturbation and the nonlinear stability is governed by first-order nonlinear partial differential equation. The stability conditions are obtained and discussed theoretically as well as numerically. Regions of stability and instability have been shown graphically indicating the effect of various parameters. It has been observed that the heat and mass transfer has stabilizing effect on the stability of the system in the nonlinear analysis for both axisymmetric as well as asymmetric disturbances.

  2. Geoelectrical inference of mass transfer parameters using temporal moments

    USGS Publications Warehouse

    Day-Lewis, F. D.; Singha, K.

    2008-01-01

    We present an approach to infer mass transfer parameters based on (1) an analytical model that relates the temporal moments of mobile and bulk concentration and (2) a bicontinuum modification to Archie's law. Whereas conventional geochemical measurements preferentially sample from the mobile domain, electrical resistivity tomography (ERT) is sensitive to bulk electrical conductivity and, thus, electrolytic solute in both the mobile and immobile domains. We demonstrate the new approach, in which temporal moments of collocated mobile domain conductivity (i.e., conventional sampling) and ERT-estimated bulk conductivity are used to calculate heterogeneous mass transfer rate and immobile porosity fractions in a series of numerical column experiments. Copyright 2008 by the American Geophysical Union.

  3. Kinetic and mass transfer parameters of maltotriose hydrolysis catalyzed by glucoamylase immobilized on macroporous silica and wrapped in pectin gel.

    PubMed

    Gonçalves, L R; Suzuki, G S; Giordano, R C; Giordano, R L

    2001-01-01

    Kinetic and mass transport parameters were estimated for maltotriose hydrolysis using glucoamylase immobilized on macroporous silica and wrapped in pectin gel at 30 degrees C. Free enzyme assays were used to obtain the intrinsic kinetic parameters of a Michaelis-Menten equation, with product inhibition by glucose. The uptake method, based on transient experimental data, was employed in the estimation of mass transfer parameters. Effective diffusivities of maltotriose in pectin gel were estimated by fitting a classical diffusion model to experimental data of maltotriose diffusion into particles of pectin gel in the absence of silica. The effective diffusivities of maltotriose in silica were obtained after fitting a bidisperse model to experimental data of maltotriose hydrolysis using glucoamylase immobilized in silica and wrapped in pectin gel. PMID:11963897

  4. Mass transfer ways of ultraviolet printing ink ingredients into foodstuffs.

    PubMed

    Jung, T; Simat, T J; Altkofer, W

    2010-07-01

    The case of isopropylthioxanthone (ITX) showed conclusively that the ingredients of ultraviolet printing inks may migrate into packaged foodstuffs. For multilayered materials like beverage cartons, the only way that mass transfer can occur is by the so-called set-off effect. In contrast, in the case of rigid plastics like yoghurt cups, two other methods of mass transfer, permeation and gas phase, have to be considered. In cooperation with producers of ink, plastic cups and yoghurt, a project was conducted in order to elucidate the mass transfer of ink ingredients. In addition, the influence of storage time and the age of ultraviolet lamps on the migration level was examined. The suitability of 50% ethanol as a simulant for yoghurt was also tested. ITX was chosen as a model migrant, as it is easily detectable. Furthermore, the migration of two other substances, the photo-initiator 2-methyl-4'-(methylthio)-2-morpholinopropiophenone (MTMP) and the amine synergist ethyl-4-(dimethylamino)benzoate (EDAB), which may be used in combination with ITX, was studied. Before being filled with yoghurt or 50% ethanol, the printed cups were stored under different contact conditions, with and without contact between the inner layer and the printed surfaces, in order to distinguish between the possible mass transfer ways. All analyses were performed by means of high performance liquid chromatography with diode array and fluorescence detection (HPLC-DAD/FLD). It was shown that contamination with ITX and EDAB occurs via set-off and that the degree of migration increases with lamp age and storage time of the unfilled cups. Migration of MTMP was not detectable. The results show that besides the careful selection of the appropriate raw materials for printing ink, a close monitoring of the process also plays a major role in migration control. In addition, the results proved that 50% ethanol is a suitable simulant for yoghurt. PMID:20432097

  5. The impact of separated flow on heat and mass transfer

    SciTech Connect

    Goldstein, R.J.; Jabbari, M.Y.

    1990-01-01

    An investigation of the effect of flow separation on heat (or mass) transfer is underway. This research, sponsored by the Department of Energy (Contract No. FG02-87ER13800), is planned to enhance our understanding of the fundamental mechanisms governing the process. This report summarizes previous accomplishments and briefly describes works done during period May 1, 1989 through April 30, 1990. Future plans and studies under preparation are also mentioned. 8 refs., 7 figs.

  6. Combined heat and mass transfer device for improving separation process

    DOEpatents

    Tran, Thanh Nhon

    1999-01-01

    A two-phase small channel heat exchange matrix simultaneously provides for heat transfer and mass transfer between the liquid and vapor phases of a multi-component mixture at a single, predetermined location within a separation column, significantly improving the thermodynamic efficiency of the separation process. The small channel heat exchange matrix is composed of a series of channels having a hydraulic diameter no greater than 5.0 millimeters for conducting a two-phase coolant. In operation, the matrix provides the liquid-vapor contacting surfaces within the separation column, such that heat and mass are transferred simultaneously between the liquid and vapor phases. The two-phase coolant allows for a uniform heat transfer coefficient to be maintained along the length of the channels and across the surface of the matrix. Preferably, a perforated, concave sheet connects each channel to an adjacent channel to facilitate the flow of the liquid and vapor phases within the column and to increase the liquid-vapor contacting surface area.

  7. Combined heat and mass transfer device for improving separation process

    DOEpatents

    Tran, T.N.

    1999-08-24

    A two-phase small channel heat exchange matrix simultaneously provides for heat transfer and mass transfer between the liquid and vapor phases of a multi-component mixture at a single, predetermined location within a separation column, significantly improving the thermodynamic efficiency of the separation process. The small channel heat exchange matrix is composed of a series of channels having a hydraulic diameter no greater than 5.0 millimeters for conducting a two-phase coolant. In operation, the matrix provides the liquid-vapor contacting surfaces within the separation column, such that heat and mass are transferred simultaneously between the liquid and vapor phases. The two-phase coolant allows for a uniform heat transfer coefficient to be maintained along the length of the channels and across the surface of the matrix. Preferably, a perforated, concave sheet connects each channel to an adjacent channel to facilitate the flow of the liquid and vapor phases within the column and to increase the liquid-vapor contacting surface area. 12 figs.

  8. Secondary Ion Mass Spectrometry for Mg Tracer Diffusion: Issues and Solutions

    SciTech Connect

    Tuggle, Jay; Giordani, Andrew; Kulkarni, Nagraj S; Warmack, Robert J Bruce; Coffey, Kevin; Sohn, Yong Ho; HunterJr., Jerry

    2014-01-01

    A Secondary Ion Mass Spectrometry (SIMS) method has been developed to measure stable Mg isotope tracer diffusion. This SIMS method was then used to calculate Mg self- diffusivities and the data was verified against historical data measured using radio tracers. The SIMS method has been validated as a reliable alternative to the radio-tracer technique for the measurement of Mg self-diffusion coefficients and can be used as a routine method for determining diffusion coefficients.

  9. Modelling mass transfer and agitator performance in multiturbine fermentors.

    PubMed

    Bader, F G

    1987-07-01

    A methodology for mathematically analyzing agitator performance and mass transfer in large multiturbine production fermentors is presented. The application of this approach provides a method for determining axial dissolved oxygen profiles under conditions of known mass transfer rates as a function of agitation-aeration characteristics. A stagewise approach is used which divides the fermentor into a series of mixing cells. This allows for each turbine and mixing cell to be individually optimized. The model also permits the determination of the mass transfer coefficient for each turbine based upon limited dissolved oxygen data. The primary limitation of this approach rests in the limited data and correlations available for multiturbine systems. The structure of the modelling approach can serve as a basis for testing single turbine correlations and adapting them to multiturbine systems. The step-by-step details of the mathematical analysis are presented and interpreted. A series of computer simulations demonstrate the effect of typical fermentor operating variables on the axial dissolved oxygen profile. Further simulations demonstrate the effect of modifying agitator blade numbers on the dissolved oxygen profile and agitator power requirement. PMID:18576581

  10. Body mass scaling of passive oxygen diffusion in endotherms and ectotherms.

    PubMed

    Gillooly, James F; Gomez, Juan Pablo; Mavrodiev, Evgeny V; Rong, Yue; McLamore, Eric S

    2016-05-10

    The area and thickness of respiratory surfaces, and the constraints they impose on passive oxygen diffusion, have been linked to differences in oxygen consumption rates and/or aerobic activity levels in vertebrates. However, it remains unclear how respiratory surfaces and associated diffusion rates vary with body mass across vertebrates, particularly in relation to the body mass scaling of oxygen consumption rates. Here we address these issues by first quantifying the body mass dependence of respiratory surface area and respiratory barrier thickness for a diversity of endotherms (birds and mammals) and ectotherms (fishes, amphibians, and reptiles). Based on these findings, we then use Fick's law to predict the body mass scaling of oxygen diffusion for each group. Finally, we compare the predicted body mass dependence of oxygen diffusion to that of oxygen consumption in endotherms and ectotherms. We find that the slopes and intercepts of the relationships describing the body mass dependence of passive oxygen diffusion in these two groups are statistically indistinguishable from those describing the body mass dependence of oxygen consumption. Thus, the area and thickness of respiratory surfaces combine to match oxygen diffusion capacity to oxygen consumption rates in both air- and water-breathing vertebrates. In particular, the substantially lower oxygen consumption rates of ectotherms of a given body mass relative to those of endotherms correspond to differences in oxygen diffusion capacity. These results provide insights into the long-standing effort to understand the structural attributes of organisms that underlie the body mass scaling of oxygen consumption. PMID:27118837

  11. NASA/DoD Aerospace Knowledge Diffusion Research Project. Paper 30: The electronic transfer of information and aerospace knowledge diffusion

    NASA Technical Reports Server (NTRS)

    Pinelli, Thomas E.; Bishop, Ann P.; Barclay, Rebecca O.; Kennedy, John M.

    1992-01-01

    Increasing reliance on and investment in information technology and electronic networking systems presupposes that computing and information technology will play a major role in the diffusion of aerospace knowledge. Little is known, however, about actual information technology needs, uses, and problems within the aerospace knowledge diffusion process. The authors state that the potential contributions of information technology to increased productivity and competitiveness will be diminished unless empirically derived knowledge regarding the information-seeking behavior of the members of the social system - those who are producing, transferring, and using scientific and technical information - is incorporated into a new technology policy framework. Research into the use of information technology and electronic networks by U.S. aerospace engineers and scientists, collected as part of a research project designed to study aerospace knowledge diffusion, is presented in support of this assertion.

  12. Subgrid models for mass and thermal diffusion in turbulent mixing

    SciTech Connect

    Sharp, David H; Lim, Hyunkyung; Li, Xiao - Lin; Gilmm, James G

    2008-01-01

    We are concerned with the chaotic flow fields of turbulent mixing. Chaotic flow is found in an extreme form in multiply shocked Richtmyer-Meshkov unstable flows. The goal of a converged simulation for this problem is twofold: to obtain converged solutions for macro solution features, such as the trajectories of the principal shock waves, mixing zone edges, and mean densities and velocities within each phase, and also for such micro solution features as the joint probability distributions of the temperature and species concentration. We introduce parameterized subgrid models of mass and thermal diffusion, to define large eddy simulations (LES) that replicate the micro features observed in the direct numerical simulation (DNS). The Schmidt numbers and Prandtl numbers are chosen to represent typical liquid, gas and plasma parameter values. Our main result is to explore the variation of the Schmidt, Prandtl and Reynolds numbers by three orders of magnitude, and the mesh by a factor of 8 per linear dimension (up to 3200 cells per dimension), to allow exploration of both DNS and LES regimes and verification of the simulations for both macro and micro observables. We find mesh convergence for key properties describing the molecular level of mixing, including chemical reaction rates between the distinct fluid species. We find results nearly independent of Reynolds number for Re 300, 6000, 600K . Methodologically, the results are also new. In common with the shock capturing community, we allow and maintain sharp solution gradients, and we enhance these gradients through use of front tracking. In common with the turbulence modeling community, we include subgrid scale models with no adjustable parameters for LES. To the authors' knowledge, these two methodologies have not been previously combined. In contrast to both of these methodologies, our use of Front Tracking, with DNS or LES resolution of the momentum equation at or near the Kolmogorov scale, but without resolving the

  13. A Comparison of Stellar Mass-Transfer & Merger Simulations

    NASA Astrophysics Data System (ADS)

    Tohline, Joel E.; Motl, P.; Diehl, S.; Even, W.; Clayton, G.; Fryer, C.

    2011-01-01

    We present detailed comparisons of 3D stellar mass-transfer and merger simulations that have been carried out using two very different numerical hydrodynamic algorithms -- a finite-volume "grid" code (typically using 4M cylindrical grid cells) and a smoothed-particle hydrodynamics (SPH) code (typically using 1M particles). In all cases the initial binary models contain synchronously rotating, n = 3/2 polytropic stars of a specified mass ratio (q = Mdonor/Maccretor) that are in circular orbit with one star (the donor) marginally filling its Roche lobe. In our "base" set of 8 comparison simulations, we have followed the evolution of binaries having four different initial mass ratios (q0 = 1.3, 0.7, 0.5, 0.4) and each is evolved using two different equations of state: polytropic (P) and ideal-gas (I). In addition, some evolutions are repeated using a different numerical resolution and/or a different initial episode of "driving" to initiate mass-transfer. In the case of the binary systems with q0 = 1.3 and q0 = 0.7, the codes show a remarkable level of quantitative agreement; in the former case, the two stars merge and, in the latter case, the donor gets tidally disrupted. Binary systems with q0 = 0.5 or 0.4 enter a long phase (> 10-20 orbits) of stable mass-transfer during which the binary separation steadily increases; tidal disruption of the donor may ultimately occur if sufficiently deep contact is made between the Roche lobe and the donor during an initial episode of "driving." This work has been supported by grants AST-0708551 and DGE-0504507 from the U.S. National Science Foundation; by grants NNX07AG84G and NNX10AC72G from NASA's ATP program; and by grants of high-performance computing time on the TeraGrid, at LSU and across LONI (Louisiana Optical Network Initiative).

  14. 2D and 3D Mass Transfer Simulations in β Lyrae System

    NASA Astrophysics Data System (ADS)

    Nazarenko, V. V.; Glazunova, L. V.; Karetnikov, V. G.

    2001-12-01

    2D and 3D mass transfer simulations of the mass transfer in β Lyrae binary system. We have received that from a point L3 40 per cent of mass transfer from L1-point is lost.The structure of a gas envelope, around system is calculated.3-D mass transfer simulations has shown presence the spiral shock in the disk around primary star's and a jet-like structures (a mass flow in vertical direction) over a stream.

  15. Quantitative spatially resolved measurements of mass transfer through laryngeal cartilage.

    PubMed

    Macpherson, J V; O'Hare, D; Unwin, P R; Winlove, C P

    1997-11-01

    The scanning electrochemical microscope (SECM) is a scanned probe microscope that uses the response of a mobile ultramicroelectrode (UME) tip to determine the reactivity, topography, and mass transport characteristics of interfaces with high spatial resolution. SECM strategies for measuring the rates of solute diffusion and convection through samples of cartilage, using amperometric UMEs, are outlined. The methods are used to determine the diffusion coefficients of oxygen and ruthenium(III) hexamine [Ru(NH3)6(3+)] in laryngeal cartilage. The diffusion coefficient of oxygen in cartilage is found to be approximately 50% of that in aqueous electrolyte solution, assuming a partition coefficient of unity for oxygen between cartilage and aqueous solution. In contrast, diffusion of Ru(NH3)6(3+) within the cartilage sample cannot be detected on the SECM timescale, suggesting a diffusion coefficient at least two orders of magnitude lower than that in solution, given a measured partition coefficient for Ru(NH3)6(3+) between cartilage and aqueous solution, Kp = [Ru(NH3)6(3+)]cartilage/[RU(NH3)6(3+)]solution = 3.4 +/- 0.1. Rates of Ru(NH3)6(3+) osmotically driven convective transport across cartilage samples are imaged at high spatial resolution by monitoring the current response of a scanning UME, with an osmotic pressure of approximately 0.75 atm across the slice. A model is outlined that enables the current response to be related to the local flux. By determining the topography of the sample from the current response with no applied osmotic pressure, local transport rates can be correlated with topographical features of the sample surface, at much higher spatial resolution than has previously been achieved. PMID:9370471

  16. Quantitative spatially resolved measurements of mass transfer through laryngeal cartilage.

    PubMed Central

    Macpherson, J V; O'Hare, D; Unwin, P R; Winlove, C P

    1997-01-01

    The scanning electrochemical microscope (SECM) is a scanned probe microscope that uses the response of a mobile ultramicroelectrode (UME) tip to determine the reactivity, topography, and mass transport characteristics of interfaces with high spatial resolution. SECM strategies for measuring the rates of solute diffusion and convection through samples of cartilage, using amperometric UMEs, are outlined. The methods are used to determine the diffusion coefficients of oxygen and ruthenium(III) hexamine [Ru(NH3)6(3+)] in laryngeal cartilage. The diffusion coefficient of oxygen in cartilage is found to be approximately 50% of that in aqueous electrolyte solution, assuming a partition coefficient of unity for oxygen between cartilage and aqueous solution. In contrast, diffusion of Ru(NH3)6(3+) within the cartilage sample cannot be detected on the SECM timescale, suggesting a diffusion coefficient at least two orders of magnitude lower than that in solution, given a measured partition coefficient for Ru(NH3)6(3+) between cartilage and aqueous solution, Kp = [Ru(NH3)6(3+)]cartilage/[RU(NH3)6(3+)]solution = 3.4 +/- 0.1. Rates of Ru(NH3)6(3+) osmotically driven convective transport across cartilage samples are imaged at high spatial resolution by monitoring the current response of a scanning UME, with an osmotic pressure of approximately 0.75 atm across the slice. A model is outlined that enables the current response to be related to the local flux. By determining the topography of the sample from the current response with no applied osmotic pressure, local transport rates can be correlated with topographical features of the sample surface, at much higher spatial resolution than has previously been achieved. Images FIGURE 6 FIGURE 7 FIGURE 8 PMID:9370471

  17. The adsorption and mass-transfer process of cationic red X-GRL dye on natural zeolite.

    PubMed

    Tian, Jingjing; Guan, Junfang; Gao, Huimin; Wen, Yafei; Ren, Zijie

    2016-01-01

    The adsorption behavior of natural zeolite was studied in order to determine the adsorption capacity and mass-transfer process of cationic red X-GRL (C(18)H(21)BrN(6)) onto the adsorbent. The adsorption tests to determine both the uptake capacity and the mass-transfer process at equilibrium were performed under batch conditions, which showed rapid uptake in general for the initial 5 min, corresponding to 92% total removal. The equilibrium adsorption capacity value (q(e,cal)) in pseudo-second-order kinetics was 13.51 mg/g at 293 K and the whole adsorption process was governed by physical adsorption with an endothermic, endothermic spontaneous nature. Adsorption tests indicated that the zeolite has great potential as an alternative low-cost material in the treatment of X-GRL drainage. However, the mass-transfer process to determine the rate-controlling steps showed that both film diffusion and pore diffusion were important in controlling the adsorption rate. The adsorption process was governed by film diffusion while pore diffusion was poor because the X-GRL molecules could not penetrate into the zeolite easily. The X-GRL molecules were only adsorbed on the external surface of the zeolite. Hence, to improve the adsorption capacity of natural zeolite further, modification to expand its micropores is necessary. PMID:27148713

  18. Thermodynamic functions and intraparticle mass transfer kinetics of structural analogues of a template on molecularly imprinted polymers in liquid chromatography

    SciTech Connect

    Kim, Hyunjung; Guiochon, Georges A

    2005-08-01

    The parameters of the thermodynamics and mass transfer kinetics of the structural analogues (L-enantiomers) of the template were measured on an Fmoc-L-tryptophan (Fmoc-L-Trp) imprinted polymer, at different temperatures. The equilibrium isotherm data and the overloaded band profiles of these compounds were measured at temperatures of 298, 313, 323, and 333 K. The isotherm data were modeled. The thermodynamic functions of the different adsorption sites were derived from the isotherm parameters, using van't Hoff plots. The mass transfer parameters were derived by comparing the experimental peak profiles and profiles calculated using the lumped pore diffusion (POR) model for chromatography. These data show that (1) the strength between the substrate molecules and the MIP increases with increasing number of functional groups on the substrates; (2) enthalpy is the driving force for the affinity of the substrates for the MIP; (3) surface diffusion is the dominant mass transfer mechanism of the substrates through the porous MIP. For those substrate molecules that have the same stereochemistry as the template, the energetic surface heterogeneity needs to be incorporated into the surface diffusion coefficients. Heterogeneous surface diffusivities decrease with increasing affinity of the substrates for the MIP.

  19. A generalized mass transfer law unifying various particle transport mechanisms in dilute dispersions

    NASA Astrophysics Data System (ADS)

    Guha, Abhijit

    2008-09-01

    A generalized mass transfer law for dilute dispersion of particles (or droplets) of any sizes suspended in a fluid has been described, which can be applied to turbulent or laminar flow. The generalized law reduces to the Fick’s law of diffusion in the limit of very small particles. Thus the study shows how the well-known and much-used Fick’s law of diffusion fits into the broader context of particle transport. The general expression for particle flux comprises a diffusive flux due to Brownian motion and turbulent fluctuation, a diffusive flux due to temperature gradient (thermophoresis plus stressphoresis) and a convective flux that arises primarily due to the interaction of particle inertia and the inhomogeneity of the fluid turbulence field (turbophoresis). Shear-induced lift force, electrical force, gravity, etc. also contribute to the convective flux. The present study includes the effects of surface roughness, and the calculations show that the presence of small surface roughness even in the hydraulically smooth regime significantly enhances deposition especially of small particles. Thermophoresis can have equally strong effects, even with a modest temperature difference between the wall and the bulk fluid. For particles of the intermediate size range, turbophoresis, thermophoresis and roughness are all important contributors to the overall deposition rate. The paper includes a parametric study of the effects of electrostatic forces due to mirror charging. The present work provides a unified framework to determine the combined effect of various particle transport mechanisms on mass transfer rate and the inclusion of other mechanisms not considered in this paper is possible.

  20. Modelling mass and heat transfer in nano-based cancer hyperthermia

    PubMed Central

    Nabil, M.; Decuzzi, P.; Zunino, P.

    2015-01-01

    We derive a sophisticated mathematical model for coupled heat and mass transport in the tumour microenvironment and we apply it to study nanoparticle delivery and hyperthermic treatment of cancer. The model has the unique ability of combining the following features: (i) realistic vasculature; (ii) coupled capillary and interstitial flow; (iii) coupled capillary and interstitial mass transfer applied to nanoparticles; and (iv) coupled capillary and interstitial heat transfer, which are the fundamental mechanisms governing nano-based hyperthermic treatment. This is an improvement with respect to previous modelling approaches, where the effect of blood perfusion on heat transfer is modelled in a spatially averaged form. We analyse the time evolution and the spatial distribution of particles and temperature in a tumour mass treated with superparamagnetic nanoparticles excited by an alternating magnetic field. By means of numerical experiments, we synthesize scaling laws that illustrate how nano-based hyperthermia depends on tumour size and vascularity. In particular, we identify two distinct mechanisms that regulate the distribution of particle and temperature, which are characterized by perfusion and diffusion, respectively. PMID:26587251

  1. Predictive mathematical modeling of trickling bed biofilters for elucidating mass transfer and kinetic effects

    SciTech Connect

    Barton, J.W.; Zhang, X.S.; Klasson, K.T.; Davison, B.H.

    1998-03-01

    Mathematical models of varying complexity have been proposed in the open literature for describing uptake of volatile organics in trickling bed biofilters. Many simpler descriptions yield relatively accurate solutions, but are limited as predictive tools by numerous assumptions which decrease the utility of the model. Trickle bed operation on the boundary between mass transfer and kinetic limitation regimes serves as one example in which these models may be insufficient. One-dimensional models may also fail to consider important effects/relationships in multiple directions, limiting their usefulness. This paper discusses the use of a predictive, two-dimensional mathematical model to describe microbial uptake, diffusion through a biofilm, and mass transfer of VOCs from gas to liquid. The model is validated by experimental data collected from operating trickle-bed bioreactors designed for removing sparingly soluble gaseous contaminants. Axial and radial (biofilm) concentration profiles are presented, along with validation results. Operation in regimes in which both mass transfer and kinetic factors play significant roles are discussed, along with predictive modeling implications.

  2. Mass transfer in a flow past a non-porous catalyst sphere

    NASA Astrophysics Data System (ADS)

    Sun, Bo; Tenneti, Sudheer; Subramaniam, Shankar

    2015-11-01

    Mass transfer in a flow past a particle with a surface chemical reaction occurs in applications involving catalytic reaction. This type of the mass transfer problem has been analyzed by solving the convection-diffusion equation for Stokes flow (Acrivos et al., 1962) or flow at low Reynolds number (Taylor 1963, Gupalo et al., 1972). The objective of this study is to extend our understanding of this mass transfer problem to higher Reynolds number (up to 100) and assemblies of several particles by using particle-resolved direct numerical simulation (PR-DNS) of gas-solid flow. A uniform flow past a non-porous spherical particle with a first-order surface reaction is simulated. The non-dimensional reaction rate constant is the important parameter in the single particle case. The PR-DNS results at low Reynolds number for a single particle are first compared with 2D analytical solutions for concentration fields and the Sherwood number. Finally, the dependence of the concentration field on the non-dimensional reaction rate constant, and comparison of PR-DNS results with other Sherwood number correlations that use the Reynolds analogy to adapt Nusselt number correlations (which do not explicitly account for surface reactions) are explored at high Reynolds number. CBET 1034307, CBET 1336941.

  3. Simultaneous heat and mass transfer in absorption of gases in laminar liquid films

    SciTech Connect

    Grossman, G

    1982-09-01

    A theoretical analysis of the combined heat and mass transfer process taking place in the absorption of a gas or vapor into a laminar liquid film is described. This type of process, which occurs in many gas-liquid systems, often releases only a small amount of heat, making the process almost isothermal. In some cases, however, the heat of absorption is significant and temperature variations cannot be ignored. One example, from which the present study originated, is in absorption heat pumps where mass transfer is produced specifically to generate a temperature change. The model analyzed describes a liquid film that flows over an inclined plane and has its free surface in contact with stagnant vapor. The absorption process at the surface creates nonuniform temperature and concentration profiles in the film, which develop until equilibrium between the liquid and vapor is achieved. The energy and diffusion equations are solved simultaneously to give the temperature and concentration variations at the interface and the wall. Two cases of interest are considered: constant-temperature and adiabatic walls. The Nusselt and Sherwood numbers are expressed in terms of the operating parameters, from which heat and mass transfer coefficients can be determined. The Nusselt and Sherwood numbers are found to depend on the Peclet and Lewis numbers as well as on the equilibrium characteristics of the working materials.

  4. Modelling mass and heat transfer in nano-based cancer hyperthermia.

    PubMed

    Nabil, M; Decuzzi, P; Zunino, P

    2015-10-01

    We derive a sophisticated mathematical model for coupled heat and mass transport in the tumour microenvironment and we apply it to study nanoparticle delivery and hyperthermic treatment of cancer. The model has the unique ability of combining the following features: (i) realistic vasculature; (ii) coupled capillary and interstitial flow; (iii) coupled capillary and interstitial mass transfer applied to nanoparticles; and (iv) coupled capillary and interstitial heat transfer, which are the fundamental mechanisms governing nano-based hyperthermic treatment. This is an improvement with respect to previous modelling approaches, where the effect of blood perfusion on heat transfer is modelled in a spatially averaged form. We analyse the time evolution and the spatial distribution of particles and temperature in a tumour mass treated with superparamagnetic nanoparticles excited by an alternating magnetic field. By means of numerical experiments, we synthesize scaling laws that illustrate how nano-based hyperthermia depends on tumour size and vascularity. In particular, we identify two distinct mechanisms that regulate the distribution of particle and temperature, which are characterized by perfusion and diffusion, respectively. PMID:26587251

  5. Modeling CO2 mass transfer in amine mixtures: PZ-AMP and PZ-MDEA.

    PubMed

    Puxty, Graeme; Rowland, Robert

    2011-03-15

    The most common method of carbon dioxide (CO(2)) capture is the absorption of CO(2) into a falling thin film of an aqueous amine solution. Modeling of mass transfer during CO(2) absorption is an important way to gain insight and understanding about the underlying processes that are occurring. In this work a new software tool has been used to model CO(2) absorption into aqueous piperazine (PZ) and binary mixtures of PZ with 2-amino-2-methyl-1-propanol (AMP) or methyldiethanolamine (MDEA). The tool solves partial differential and simultaneous equations describing diffusion and chemical reaction automatically derived from reactions written using chemical notation. It has been demonstrated that by using reactions that are chemically plausible the mass transfer in binary mixtures can be fully described by combining the chemical reactions and their associated parameters determined for single amines. The observed enhanced mass transfer in binary mixtures can be explained through chemical interactions occurring in the mixture without need to resort to using additional reactions or unusual transport phenomena such as the "shuttle mechanism". PMID:21329341

  6. A hybrid transport-diffusion Monte Carlo method for frequency-dependent radiative-transfer simulations

    SciTech Connect

    Densmore, Jeffery D.; Thompson, Kelly G.; Urbatsch, Todd J.

    2012-08-15

    Discrete Diffusion Monte Carlo (DDMC) is a technique for increasing the efficiency of Implicit Monte Carlo radiative-transfer simulations in optically thick media. In DDMC, particles take discrete steps between spatial cells according to a discretized diffusion equation. Each discrete step replaces many smaller Monte Carlo steps, thus improving the efficiency of the simulation. In this paper, we present an extension of DDMC for frequency-dependent radiative transfer. We base our new DDMC method on a frequency-integrated diffusion equation for frequencies below a specified threshold, as optical thickness is typically a decreasing function of frequency. Above this threshold we employ standard Monte Carlo, which results in a hybrid transport-diffusion scheme. With a set of frequency-dependent test problems, we confirm the accuracy and increased efficiency of our new DDMC method.

  7. Effect of diffusion on Förster resonance energy transfer in low-viscosity solution

    NASA Astrophysics Data System (ADS)

    Muratsugu, Atsushi; Watanabe, Junji; Kinoshita, Shuichi

    2014-06-01

    The effect of translational diffusion on Förster resonance energy transfer between rhodamine 6G (the donor) and malachite green (the acceptor) was investigated by examining the donor's fluorescence decay profile. Eight straight-chain alkyl alcohols were used, and the temperature of ethanol was changed to vary the viscosity; the decay profiles were analyzed using the theory developed by Gösele. The critical transfer distance obtained from the decay profile is in good agreement with that evaluated using the spectroscopic quantities, and the diffusion coefficients are consistent with the Stokes-Einstein relation. The fluorescence decay profile was described well by Gösele's theory and the effect of diffusion is clearly verified by the temperature/viscosity dependence of the diffusion constant.

  8. Effects of mass transfer between Martian satellites on surface geology

    NASA Astrophysics Data System (ADS)

    Nayak, Michael; Nimmo, Francis; Udrea, Bogdan

    2016-03-01

    Impacts on planetary bodies can lead to both prompt secondary craters and projectiles that reimpact the target body or nearby companions after an extended period, producing so-called "sesquinary" craters. Here we examine sesquinary cratering on the moons of Mars. We model the impact that formed Voltaire, the largest crater on the surface of Deimos, and explore the orbital evolution of resulting high-velocity ejecta across 500 years using four-body physics and particle tracking. The bulk of mass transfer to Phobos occurs in the first 102 years after impact, while reaccretion of ejecta to Deimos is predicted to continue out to a 104 year timescale (cf. Soter, S. [1971]. Studies of the Terrestrial Planets. Cornell University). Relative orbital geometry between Phobos and Deimos plays a significant role; depending on the relative true longitude, mass transfer between the moons can change by a factor of five. Of the ejecta with a velocity range capable of reaching Phobos, 25-42% by mass reaccretes to Deimos and 12-21% impacts Phobos. Ejecta mass transferred to Mars is <10%. We find that the characteristic impact velocity of sesquinaries on Deimos is an order of magnitude smaller than those of background (heliocentric) hypervelocity impactors and will likely result in different crater morphologies. The time-averaged flux of Deimos material to Phobos can be as high as 11% of the background (heliocentric) direct-to-Phobos impactor flux. This relatively minor contribution suggests that spectrally red terrain on Phobos (Murchie, S., Erard, S. [1996]. Icarus 123, 63-86) is not caused by Deimos material. However the high-velocity ejecta mass reaccreted to Deimos from a Voltaire-sized impact is comparable to the expected background mass accumulated on Deimos between Voltaire-size events. Considering that the high-velocity ejecta contains only 0.5% of the total mass sent into orbit, sesquinary ejecta from a Voltaire-sized impact could feasibly resurface large parts of the Moon

  9. Restrained Ion Population Transfer: A Novel Ion Transfer Method for Mass Spectrometry.

    SciTech Connect

    Kaiser, Nathan K.; Skulason, Gunnar; Weisbrod, Chad R.; Wu, Si; Zhang, Kai; Prior, David C.; Buschbach, Michael A.; Anderson, Gordon A.; Bruce, James E.

    2008-06-30

    With modern Fourier transform ion cyclotron resonance (ICR) mass spectrometers, ions are created and accumulated exterior to the mass analyzer. The ion accumulation event takes place in a region of higher pressure which allows ions to be thermally cooled before being given kinetic energy and accelerated toward the ICR cell where they are to be decelerated and re-trapped. When gated trapping is used to collect ions in the ICR cell for analysis, mass discrimination can occur due to time-of-flight effects. Also, trapping ions with large axial kinetic energy can decrease the performance of the ICR instrument when compared to the analysis of thermally-cooled ions located at the trap center. Therefore, it is desirable to limit the energy imparted in the ions within the ICR cell as well as minimize time-of-flight effects. The approach presented here for ion transfer called restrained ion population transfer or RIPT provides complete axial control of an ion population throughout the entire transfer sequence from the accumulation region to the ICR cell. This is accomplished by utilization of a number of quadrupole segments arranged in series with independent control of the dc bias voltage applied to each segment of the quadrupole ion guide. This approach circumvents problems associated with time-of-flight effects and minimizes the energy imparted to the ions allowing transfer of the cooled ion packet from the ion accumulation region to the ICR cell. Initial data are presented to illustrate feasibility of restrained ion population transfer. RIPT was also modeled with SIMION 7.0 and simulation results that support our feasibility studies of the ions transfer process are presented.

  10. Influence of mass transfer on bubble plume hydrodynamics.

    PubMed

    Lima Neto, Iran E; Parente, Priscila A B

    2016-03-01

    This paper presents an integral model to evaluate the impact of gas transfer on the hydrodynamics of bubble plumes. The model is based on the Gaussian type self-similarity and functional relationships for the entrainment coefficient and factor of momentum amplification due to turbulence. The impact of mass transfer on bubble plume hydrodynamics is investigated considering different bubble sizes, gas flow rates and water depths. The results revealed a relevant impact when fine bubbles are considered, even for moderate water depths. Additionally, model simulations indicate that for weak bubble plumes (i.e., with relatively low flow rates and large depths and slip velocities), both dissolution and turbulence can affect plume hydrodynamics, which demonstrates the importance of taking the momentum amplification factor relationship into account. For deeper water conditions, simulations of bubble dissolution/decompression using the present model and classical models available in the literature resulted in a very good agreement for both aeration and oxygenation processes. Sensitivity analysis showed that the water depth, followed by the bubble size and the flow rate are the most important parameters that affect plume hydrodynamics. Lastly, dimensionless correlations are proposed to assess the impact of mass transfer on plume hydrodynamics, including both the aeration and oxygenation modes. PMID:26840001

  11. Oxygen mass transfer and hydrodynamic behaviour in wastewater: determination of local impact of surfactants by visualization techniques.

    PubMed

    Jimenez, Mélanie; Dietrich, Nicolas; Grace, John R; Hébrard, Gilles

    2014-07-01

    Powerful techniques, based on the Planar Laser Induced Fluorescence (PLIF) technique, are deployed to locally visualize and quantify the impact of surfactants in wastewaters on hydrodynamics and oxygen mass transfer. Bubble diameter, aspect ratio, rise velocity, contamination angle, as well as flux, flux density, liquid side mass transfer and diffusion coefficients of transferred oxygen are determined based on these techniques applied in the wake of rising bubbles of diameter 1 mm and through planar gas/liquid interfaces. The initial experiments were performed in demineralized water containing small amounts of surfactant. Different concentrations of surfactant were added to finally reach the Critical Micelle Concentration (CMC). Bubbles have classically been found to be more spherical with a reduced rise velocity in the presence of surfactants up to the CMC. Above the CMC, these hydrodynamic characteristics were found to be almost constant, although the oxygen mass transfer decreased due to the presence of surfactants. Experimental results were markedly lower than predicted by the well-known Frössling equation with rigid surfaces. This is believed to be caused by a barrier of surfactants hindering the oxygen mass transfer at the interface. Similar hindrance of oxygen mass transfer applies to waters from sewage plants (filtered raw water and treated water), making accurate design of aeration tanks difficult. PMID:24747142

  12. Conjugate heat and mass transfer in the lattice Boltzmann equation method

    SciTech Connect

    Li, LK; Chen, C; Mei, RW; Klausner, JF

    2014-04-22

    An interface treatment for conjugate heat and mass transfer in the lattice Boltzmann equation method is proposed based on our previously proposed second-order accurate Dirichlet and Neumann boundary schemes. The continuity of temperature (concentration) and its flux at the interface for heat (mass) transfer is intrinsically satisfied without iterative computations, and the interfacial temperature (concentration) and their fluxes are conveniently obtained from the microscopic distribution functions without finite-difference calculations. The present treatment takes into account the local geometry of the interface so that it can be directly applied to curved interface problems such as conjugate heat and mass transfer in porous media. For straight interfaces or curved interfaces with no tangential gradient, the coupling between the interfacial fluxes along the discrete lattice velocity directions is eliminated and thus the proposed interface schemes can be greatly simplified. Several numerical tests are conducted to verify the applicability and accuracy of the proposed conjugate interface treatment, including (i) steady convection-diffusion in a channel containing two different fluids, (ii) unsteady convection-diffusion in the channel, (iii) steady heat conduction inside a circular domain with two different solid materials, and (iv) unsteady mass transfer from a spherical droplet in an extensional creeping flow. The accuracy and order of convergence of the simulated interior temperature (concentration) field, the interfacial temperature (concentration), and heat (mass) flux are examined in detail and compared with those obtained from the "half-lattice division" treatment in the literature. The present analysis and numerical results show that the half-lattice division scheme is second-order accurate only when the interface is fixed at the center of the lattice links, while the present treatment preserves second-order accuracy for arbitrary link fractions. For curved

  13. Coarsening of sand ripples in mass transfer models.

    PubMed

    Hellén, E K O; Krug, J

    2002-07-01

    Coarsening of sand ripples is studied in a one-dimensional stochastic model, where neighboring ripples exchange mass with algebraic rates, Gamma(m) approximately m(gamma), and ripples of zero mass are removed from the system. For gamma<0, ripples vanish through rare fluctuations and the average ripple mass grows as (t) approximately -gamma(-1)ln(t). Temporal correlations decay as t(-1/2) or t(-2/3) depending on the symmetry of the mass transfer, and asymptotically the system is characterized by a product measure. The stationary ripple mass distribution is obtained exactly. For gamma>0, ripple evolution is linearly unstable, and the noise in the dynamics is irrelevant. For gamma=1, the problem is solved on the mean-field level, but the mean-field theory does not adequately describe the full behavior of the coarsening. In particular, it fails to account for the numerically observed universality with respect to the initial ripple size distribution. The results are not restricted to sand ripple evolution since the model can be mapped to zero range processes, urn models, exclusion processes, and cluster-cluster aggregation. PMID:12241351

  14. Isotherm parameters and intraparticle mass transfer kinetics on molecularly imprinted polymers in acetonitrile/buffer mobile phases

    SciTech Connect

    Kim, Hyunjung; Kaczmarski, Krzysztof; Guiochon, Georges A

    2006-03-01

    The equilibrium isotherm and the intraparticle mass transfer kinetics of the enantiomers of the template were investigated on an Fmoc-L-tryptophan (Fmoc-L-Trp) imprinted polymer at different pHs and water concentrations in acetonitrile/aqueous buffer mobile phases. The equilibrium isotherm data were measured using frontal analysis at 25 {+-} 2 C. The adsorption energy distribution was found to be trimodal, with narrow modes. Consistent with this distribution, the adsorption data were modeled using a tri-Langmuir isotherm equation and the best estimates of the isotherm parameters were determined. The intraparticle mass transfer parameters were derived by comparing the profiles of experimental overloaded bands and the profiles calculated using the isotherm model and the lumped pore diffusion (POR) model of chromatography. These results showed that different adsorption and mass transfer mechanisms exist in mobile phases made of acetonitrile/aqueous buffer and of acetonitrile/acetic acid solutions.

  15. The balanced-force volume tracking algorithm and global embedded interface formulation for droplet dynamics with mass transfer

    SciTech Connect

    Francois, Marianne M; Carlson, Neil N

    2010-01-01

    Understanding the complex interaction of droplet dynamics with mass transfer and chemical reactions is of fundamental importance in liquid-liquid extraction. High-fidelity numerical simulation of droplet dynamics with interfacial mass transfer is particularly challenging because the position of the interface between the fluids and the interface physics need to be predicted as part of the solution of the flow equations. In addition, the discontinuity in fluid density, viscosity and species concentration at the interface present additional numerical challenges. In this work, we extend our balanced-force volume-tracking algorithm for modeling surface tension force (Francois et al., 2006) and we propose a global embedded interface formulation to model the interfacial conditions of an interface in thermodynamic equilibrium. To validate our formulation, we perform simulations of pure diffusion problems in one- and two-dimensions. Then we present two and three-dimensional simulations of a single droplet dynamics rising by buoyancy with mass transfer.

  16. Counter-extrapolation method for conjugate interfaces in computational heat and mass transfer.

    PubMed

    Le, Guigao; Oulaid, Othmane; Zhang, Junfeng

    2015-03-01

    In this paper a conjugate interface method is developed by performing extrapolations along the normal direction. Compared to other existing conjugate models, our method has several technical advantages, including the simple and straightforward algorithm, accurate representation of the interface geometry, applicability to any interface-lattice relative orientation, and availability of the normal gradient. The model is validated by simulating the steady and unsteady convection-diffusion system with a flat interface and the steady diffusion system with a circular interface, and good agreement is observed when comparing the lattice Boltzmann results with respective analytical solutions. A more general system with unsteady convection-diffusion process and a curved interface, i.e., the cooling process of a hot cylinder in a cold flow, is also simulated as an example to illustrate the practical usefulness of our model, and the effects of the cylinder heat capacity and thermal diffusivity on the cooling process are examined. Results show that the cylinder with a larger heat capacity can release more heat energy into the fluid and the cylinder temperature cools down slower, while the enhanced heat conduction inside the cylinder can facilitate the cooling process of the system. Although these findings appear obvious from physical principles, the confirming results demonstrates the application potential of our method in more complex systems. In addition, the basic idea and algorithm of the counter-extrapolation procedure presented here can be readily extended to other lattice Boltzmann models and even other computational technologies for heat and mass transfer systems. PMID:25871245

  17. Direct geoelectrical evidence of mass transfer at the laboratory scale

    NASA Astrophysics Data System (ADS)

    Swanson, Ryan D.; Singha, Kamini; Day-Lewis, Frederick D.; Binley, Andrew; Keating, Kristina; Haggerty, Roy

    2012-10-01

    Previous field-scale experimental data and numerical modeling suggest that the dual-domain mass transfer (DDMT) of electrolytic tracers has an observable geoelectrical signature. Here we present controlled laboratory experiments confirming the electrical signature of DDMT and demonstrate the use of time-lapse electrical measurements in conjunction with concentration measurements to estimate the parameters controlling DDMT, i.e., the mobile and immobile porosity and rate at which solute exchanges between mobile and immobile domains. We conducted column tracer tests on unconsolidated quartz sand and a material with a high secondary porosity: the zeolite clinoptilolite. During NaCl tracer tests we collected nearly colocated bulk direct-current electrical conductivity (σb) and fluid conductivity (σf) measurements. Our results for the zeolite show (1) extensive tailing and (2) a hysteretic relation between σf and σb, thus providing evidence of mass transfer not observed within the quartz sand. To identify best-fit parameters and evaluate parameter sensitivity, we performed over 2700 simulations of σf, varying the immobile and mobile domain and mass transfer rate. We emphasized the fit to late-time tailing by minimizing the Box-Cox power transformed root-mean square error between the observed and simulated σf. Low-field proton nuclear magnetic resonance (NMR) measurements provide an independent quantification of the volumes of the mobile and immobile domains. The best-fit parameters based on σf match the NMR measurements of the immobile and mobile domain porosities and provide the first direct electrical evidence for DDMT. Our results underscore the potential of using electrical measurements for DDMT parameter inference.

  18. Characterizing Mass Transfer at the Hanford 300 Area

    NASA Astrophysics Data System (ADS)

    Hall, L. H.

    2012-12-01

    Aquifer remediation efforts in the Hanford 300 Area in Washington have presented substantial challenges for the Department of Energy. Since the early 1940s, this site has been a receptacle for radiological and chemical wastes from nuclear weapons production, including high concentrations of uranium. Employing techniques to estimate and measure mass transfer in-situ will improve understanding of contaminant fate and transport at this site, and perhaps others. A field experiment was conducted with a combination of electrical resistivity tomography (ERT) and ionic tracer tests through a double-ring infiltrometer to quantify multirate mass-transfer and other transport parameters in the 300 Area. The tests included a series of injections into an infiltrating column of water. After saturating the column with fresh water at a constant head, bromide tracer solution with initial known concentration was injected for a specified amount of hours. This was followed by a continual fresh water injection during which time fluid samples were taken at varying depths along the probe to observe the tailing of the breakthrough curve during this purge. Throughout the experiment, ERT data collected along the column as well as along a transect perpendicular to the vertical sampling ports. These experiments will result in a model of the local vadose zone which will be calibrated using field data and modeled using HYDRUS 2D and its sequential inverse modeling feature. This program numerically solves the Richards equation for variably saturated water flow and advection-dispersion (AD) type equations for solute transport. It also considers dual-porosity type flow in the mobile and immobile domain. Additionally, mass transfer parameters will be modeled using a code which utilizes the AD equation and numerically solves for concentrations using Laplace Transforms. Analysis on governing processes and calibration of this code using field data will be used for additional verification on

  19. Direct geoelectrical evidence of mass transfer at the laboratory scale

    USGS Publications Warehouse

    Swanson, Ryan D.; Singha, Kamini; Day-Lewis, Frederick D.; Binley, Andrew; Keating, Kristina; Haggerty, Roy

    2012-01-01

    Previous field-scale experimental data and numerical modeling suggest that the dual-domain mass transfer (DDMT) of electrolytic tracers has an observable geoelectrical signature. Here we present controlled laboratory experiments confirming the electrical signature of DDMT and demonstrate the use of time-lapse electrical measurements in conjunction with concentration measurements to estimate the parameters controlling DDMT, i.e., the mobile and immobile porosity and rate at which solute exchanges between mobile and immobile domains. We conducted column tracer tests on unconsolidated quartz sand and a material with a high secondary porosity: the zeolite clinoptilolite. During NaCl tracer tests we collected nearly colocated bulk direct-current electrical conductivity (σb) and fluid conductivity (σf) measurements. Our results for the zeolite show (1) extensive tailing and (2) a hysteretic relation between σf and σb, thus providing evidence of mass transfer not observed within the quartz sand. To identify best-fit parameters and evaluate parameter sensitivity, we performed over 2700 simulations of σf, varying the immobile and mobile domain and mass transfer rate. We emphasized the fit to late-time tailing by minimizing the Box-Cox power transformed root-mean square error between the observed and simulated σf. Low-field proton nuclear magnetic resonance (NMR) measurements provide an independent quantification of the volumes of the mobile and immobile domains. The best-fit parameters based on σf match the NMR measurements of the immobile and mobile domain porosities and provide the first direct electrical evidence for DDMT. Our results underscore the potential of using electrical measurements for DDMT parameter inference.

  20. Increasing peritoneal contact area during dialysis improves mass transfer.

    PubMed

    Flessner, M F; Lofthouse, J; Williams, A

    2001-10-01

    Previous studies in mice demonstrated that relatively large volumes in the peritoneal cavity made contact with only 40% of the anatomic peritoneum and that this contact area (A(contact)) could be increased with use of a surfactant, dioctyl sodium sulfosuccinate (DSS). To investigate the hypothesis that mass transfer rates during peritoneal dialysis are dependent on the area of peritoneum in contact with the dialysis solution, rats were dialyzed for 2 h with a solution that contained (14)C-mannitol, with or without 0.02% DSS. The mass transfer-area coefficients (MTAC) were determined to be (mean +/- SEM, ml/min): no DSS, 0.163 +/- 0.008; with DSS, 0.247 +/- 0.006 (P < 0.002). DSS also caused an increase in total protein loss over 2 h (mean +/- SEM, mg): no DSS, 83.8 +/- 15.8; DSS, 159.5 +/- 6.3 (P < 0.001). In a separate set of animals, the ratio (R) of A(contact) to anatomic area in each plane was measured as in the previous study R(mean) (mean +/- SEM) and equaled 0.466 +/- 0.075, no DSS; 0.837 +/- 0.074, with DSS. The ratio of MTAC (1.52) and protein loss (1.90) approximate the ratio of R(mean(S)) (1.78). Because MTAC = mass transfer coefficient (MTC) x A(contact), small peritoneal transport chambers were used to determine MTC for (14)C-mannitol and fluorescein isothiocyanate-albumin. MTC(mannitol) did not change significantly with the addition of DSS. MTC(albumin) (cm/min x 10(4), mean +/- SEM) equaled 1.47 +/- 0.45 without DSS and 1.78 +/- 0.52 with DSS (P < 0.04). It was concluded that DSS increases the mass transfer rates of mannitol and protein by increasing A(contact), whereas protein transport is further augmented by an apparent increase in the barrier permeability to protein. PMID:11562413

  1. Modeling heat and mass transfer in catalytic wood gasification

    SciTech Connect

    Brown, M.D.; Robertus, R.J.; Baker, E.G.; Mudge, L.K.

    1986-03-01

    Current research in the gasification of biomass materials includes production of a methanol synthesis gas catalytically. Previous experiments have indicated early deactivation of catalysts due primarily to carbon deposition. This study presents the results of efforts to model the heat and mass transfer within a spherical catalyst pellet using orthogonal collocation. Solutions are presented which predict temperature and concentration distributions and pellet effectiveness factors. These solutions are compared to a thermodynamic equilibrium model to predict regimes of carbon deposition and subsequent deactivation. Experimental data are presented which support conclusions drawn above. 11 refs., 3 figs., 1 tab.

  2. Solid lubricant mass contact transfer technology usage for vacuum ball bearings longevity increasing

    NASA Astrophysics Data System (ADS)

    Arzymatov, B.; Deulin, E.

    2016-07-01

    A contact mass transfer technological method of solid lubricant deposition on components of vacuum ball bearings is presented. Physics-mathematical model of process contact mass transfer is being considered. The experimental results of ball bearings covered with solid lubricant longevity in vacuum are presented. It is shown that solid lubricant of contact mass transfer method deposition is prospective for ball bearing longevity increasing.

  3. Collisional processes and transfer of mass among the planetary satellites

    NASA Astrophysics Data System (ADS)

    Marchi, S.; Dell'Oro, A.; Paolicchi, P.; Barbieri, C.

    2001-08-01

    Several pairs of planetary satellites may have been involved, during the history of the Solar System, in mutual mass transfer processes. Such processes can be triggered by catastrophic collisions of a satellite (parent body) with a third object. As a consequence, the collision fragments are injected into independent orbits that can cross the trajectory of the another satellite (target). These swarms of secondary impacts may be of some importance influencing the properties of the target body. Even the formation of the atmosphere around some giant satellites may have been triggered by the gas released after the impacts of fragments onto the target's surface. Moreover, the different albedos and the different surface density of impact craters within the same satellite system may be connected to peculiar collisional phenomena, such as those we are dealing with. A quantitative modelling of the role of mass transfer processes obviously requires an estimate of how much material the parent bodies are able to supply, and under what circumstances the process may take place. A general analysis of the various pairs throughout the major satellite systems present in the Solar System has been performed in the present paper. Our analysis uses a statistical algorithm, computing, as a function of the initial properties of the fragments (masses and ejection velocities from their parent body), the mean intrinsic probability of impact, and then the mean lifetime of a fragment before impacting the target, as well as the distribution of the relative velocity. For an order-of-magnitude estimate of the available amount of mass, some simple analytical equations have been derived to evaluate the fraction of fragments from the parent body that can reach the target. These formulae allow a preliminary discrimination of the interesting cases. The pair Hyperion-Titan and the Uranus system have been analyzed in detail.

  4. Analysis and application of Luikov`s heat, mass, and pressure transfer model to a capillary porous media

    SciTech Connect

    Irudayaraj, J.; Wu, Y.

    1996-05-01

    Luikov`s system of partial differential equations for heat, mass and pressure transfer was applied to describe the drying process in a capillary porous body. A two dimensional finite element model were formulated to solve the system of equations. The simulated results agreed very well with the exact solutions. The finite element model was then used to study the sensitivity of the parameters in Luikov`s heat, mass and pressure transfer system, and to estimate the key parameters identified (the coefficient of moisture conductivity, k{sub m}, and the ratio of vapor diffusion to total diffusion, {epsilon}) for Norway spruce. The finite element model was further used for the prediction of temperature, moisture and pressure variation during drying of Norway spruce. Laboratory experiments were conducted to measure the temperature and moisture content of a Norway spruce sample during drying. The predicted results showed good agreement with the experimental results.

  5. Macro- to Nanoscale Heat and Mass Transfer: The Lagging Behavior

    NASA Astrophysics Data System (ADS)

    Ghazanfarian, Jafar; Shomali, Zahra; Abbassi, Abbas

    2015-07-01

    The classical model of the Fourier's law is known as the most common constitutive relation for thermal transport in various engineering materials. Although the Fourier's law has been widely used in a variety of engineering application areas, there are many exceptional applications in which the Fourier's law is questionable. This paper gathers together such applications. Accordingly, the paper is divided into two parts. The first part reviews the papers pertaining to the fundamental theory of the phase-lagging models and the analytical and numerical solution approaches. The second part wrap ups the various applications of the phase-lagging models including the biological materials, ultra-high-speed laser heating, the problems involving moving media, micro/nanoscale heat transfer, multi-layered materials, the theory of thermoelasticity, heat transfer in the material defects, the diffusion problems we call as the non-Fick models, and some other applications. It is predicted that the interest in the field of phase-lagging heat transport has grown incredibly in recent years because they show good agreement with the experiments across a wide range of length and time scales.

  6. Communication: Modeling of concentration dependent water diffusivity in ionic solutions: Role of intermolecular charge transfer

    SciTech Connect

    Yao, Yi; Berkowitz, Max L. E-mail: ykanai@unc.edu; Kanai, Yosuke E-mail: ykanai@unc.edu

    2015-12-28

    The translational diffusivity of water in solutions of alkali halide salts depends on the identity of ions, exhibiting dramatically different behavior even in solutions of similar salts of NaCl and KCl. The water diffusion coefficient decreases as the salt concentration increases in NaCl. Yet, in KCl solution, it slightly increases and remains above bulk value as salt concentration increases. Previous classical molecular dynamics simulations have failed to describe this important behavior even when polarizable models were used. Here, we show that inclusion of dynamical charge transfer among water molecules produces results in a quantitative agreement with experiments. Our results indicate that the concentration-dependent diffusivity reflects the importance of many-body effects among the water molecules in aqueous ionic solutions. Comparison with quantum mechanical calculations shows that a heterogeneous and extended distribution of charges on water molecules around the ions due to ion-water and also water-water charge transfer plays a very important role in controlling water diffusivity. Explicit inclusion of the charge transfer allows us to model accurately the difference in the concentration-dependent water diffusivity between Na{sup +} and K{sup +} ions in simulations, and it is likely to impact modeling of a wide range of systems for medical and technological applications.

  7. Communication: Modeling of concentration dependent water diffusivity in ionic solutions: Role of intermolecular charge transfer

    NASA Astrophysics Data System (ADS)

    Yao, Yi; Berkowitz, Max L.; Kanai, Yosuke

    2015-12-01

    The translational diffusivity of water in solutions of alkali halide salts depends on the identity of ions, exhibiting dramatically different behavior even in solutions of similar salts of NaCl and KCl. The water diffusion coefficient decreases as the salt concentration increases in NaCl. Yet, in KCl solution, it slightly increases and remains above bulk value as salt concentration increases. Previous classical molecular dynamics simulations have failed to describe this important behavior even when polarizable models were used. Here, we show that inclusion of dynamical charge transfer among water molecules produces results in a quantitative agreement with experiments. Our results indicate that the concentration-dependent diffusivity reflects the importance of many-body effects among the water molecules in aqueous ionic solutions. Comparison with quantum mechanical calculations shows that a heterogeneous and extended distribution of charges on water molecules around the ions due to ion-water and also water-water charge transfer plays a very important role in controlling water diffusivity. Explicit inclusion of the charge transfer allows us to model accurately the difference in the concentration-dependent water diffusivity between Na+ and K+ ions in simulations, and it is likely to impact modeling of a wide range of systems for medical and technological applications.

  8. Time-resolved diffuse spectroscopy measurements using a hybrid Green's function for the radiative transfer equation

    NASA Astrophysics Data System (ADS)

    Simon, Emanuel; Foschum, Florian; Kienle, Alwin

    2013-06-01

    Time-resolved diffuse optical spectroscopy measurements of phantoms at small source-detector separations yield good results for the retrieved coefficients of reduced scattering and absorption when a hybrid Green's function of the radiative transfer equation for semi-infinite media is used.

  9. Knowledge-for-Action Theories in Evaluation: Knowledge Utilization, Diffusion, Implementation, Transfer, and Translation

    ERIC Educational Resources Information Center

    Ottoson, Judith M.

    2009-01-01

    Five knowledge-for-action theories are summarized and compared in this chapter for their evaluation implications: knowledge utilization, diffusion, implementation, transfer, and translation. Usually dispersed across multiple fields and disciplines, these theories are gathered here for a common focus on knowledge and change. Knowledge in some form…

  10. Full scale evaluation of diffuser ageing with clean water oxygen transfer tests.

    PubMed

    Krampe, J

    2011-01-01

    Aeration is a crucial part of the biological wastewater treatment in activated sludge systems and the main energy user of WWTPs. Approximately 50 to 60% of the total energy consumption of a WWTP can be attributed to the aeration system. The performance of the aeration system, and in the case of fine bubble diffused aeration the diffuser performance, has a significant impact on the overall plant efficiency. This paper seeks to isolate the changes of the diffuser performance over time by eliminating all other influencing parameters like sludge retention time, surfactants and reactor layout. To achieve this, different diffusers have been installed and tested in parallel treatment trains in two WWTPs. The diffusers have been performance tested in clean water tests under new conditions and after one year of operation. A set of material property tests describing the diffuser membrane quality was also performed. The results showed a significant drop in the performance of the EPDM diffuser in the first year which resulted in similar oxygen transfer efficiency around 16 g/m3/m for all tested systems. Even though the tested silicone diffusers did not show a drop in performance they had a low efficiency in the initial tests. The material properties indicate that the EPDM performance loss is partly due to the washout of additives. PMID:22097050

  11. Hornblendite delineates zones of mass transfer through the lower crust

    PubMed Central

    Daczko, Nathan R.; Piazolo, Sandra; Meek, Uvana; Stuart, Catherine A.; Elliott, Victoria

    2016-01-01

    Geochemical signatures throughout the layered Earth require significant mass transfer through the lower crust, yet geological pathways are under-recognized. Elongate bodies of basic to ultrabasic rocks are ubiquitous in exposures of the lower crust. Ultrabasic hornblendite bodies hosted within granulite facies gabbroic gneiss of the Pembroke Valley, Fiordland, New Zealand, are typical occurrences usually reported as igneous cumulate hornblendite. Their igneous features contrast with the metamorphic character of their host gabbroic gneiss. Both rock types have a common parent; field relationships are consistent with modification of host gabbroic gneiss into hornblendite. This precludes any interpretation involving cumulate processes in forming the hornblendite; these bodies are imposter cumulates. Instead, replacement of the host gabbroic gneiss formed hornblendite as a result of channeled high melt flux through the lower crust. High melt/rock ratios and disequilibrium between the migrating magma (granodiorite) and its host gabbroic gneiss induced dissolution (grain-scale magmatic assimilation) of gneiss and crystallization of mainly hornblende from the migrating magma. The extent of this reaction-replacement mechanism indicates that such hornblendite bodies delineate significant melt conduits. Accordingly, many of the ubiquitous basic to ultrabasic elongate bodies of the lower crust likely map the ‘missing’ mass transfer zones. PMID:27546342

  12. Hornblendite delineates zones of mass transfer through the lower crust.

    PubMed

    Daczko, Nathan R; Piazolo, Sandra; Meek, Uvana; Stuart, Catherine A; Elliott, Victoria

    2016-01-01

    Geochemical signatures throughout the layered Earth require significant mass transfer through the lower crust, yet geological pathways are under-recognized. Elongate bodies of basic to ultrabasic rocks are ubiquitous in exposures of the lower crust. Ultrabasic hornblendite bodies hosted within granulite facies gabbroic gneiss of the Pembroke Valley, Fiordland, New Zealand, are typical occurrences usually reported as igneous cumulate hornblendite. Their igneous features contrast with the metamorphic character of their host gabbroic gneiss. Both rock types have a common parent; field relationships are consistent with modification of host gabbroic gneiss into hornblendite. This precludes any interpretation involving cumulate processes in forming the hornblendite; these bodies are imposter cumulates. Instead, replacement of the host gabbroic gneiss formed hornblendite as a result of channeled high melt flux through the lower crust. High melt/rock ratios and disequilibrium between the migrating magma (granodiorite) and its host gabbroic gneiss induced dissolution (grain-scale magmatic assimilation) of gneiss and crystallization of mainly hornblende from the migrating magma. The extent of this reaction-replacement mechanism indicates that such hornblendite bodies delineate significant melt conduits. Accordingly, many of the ubiquitous basic to ultrabasic elongate bodies of the lower crust likely map the 'missing' mass transfer zones. PMID:27546342

  13. Acoustic Streaming and Heat and Mass Transfer Enhancement

    NASA Technical Reports Server (NTRS)

    Trinh, E. H.; Gopinath, A.

    1996-01-01

    A second order effect associated with high intensity sound field, acoustic streaming has been historically investigated to gain a fundamental understanding of its controlling mechanisms and to apply it to practical aspects of heat and mass transfer enhancement. The objectives of this new research project are to utilize a unique experimental technique implementing ultrasonic standing waves in closed cavities to study the details of the generation of the steady-state convective streaming flows and of their interaction with the boundary of ultrasonically levitated near-spherical solid objects. The goals are to further extend the existing theoretical studies of streaming flows and sample interactions to higher streaming Reynolds number values, for larger sample size relative to the wavelength, and for a Prandtl and Nusselt numbers parameter range characteristic of both gaseous and liquid host media. Experimental studies will be conducted in support to the theoretical developments, and the crucial impact of microgravity will be to allow the neglect of natural thermal buoyancy. The direct application to heat and mass transfer in the absence of gravity will be emphasized in order to investigate a space-based experiment, but both existing and novel ground-based scientific and technological relevance will also be pursued.

  14. Pattern formation and mass transfer under stationary solutal Marangoni instability.

    PubMed

    Schwarzenberger, Karin; Köllner, Thomas; Linde, Hartmut; Boeck, Thomas; Odenbach, Stefan; Eckert, Kerstin

    2014-04-01

    According to the seminal theory by Sternling and Scriven, solutal Marangoni convection during mass transfer of surface-active solutes may occur as either oscillatory or stationary instability. With strong support of Manuel G. Velarde, a combined initiative of experimental works, in particular to mention those of Linde, Wierschem and coworkers, and theory has enabled a classification of dominant wave types of the oscillatory mode and their interactions. In this way a rather comprehensive understanding of the nonlinear evolution of the oscillatory instability could be achieved. A comparably advanced state-of-the-art with respect to the stationary counterpart seemed to be out of reach a short time ago. Recent developments on both the numerical and experimental side, in combination with assessing an extensive number of older experiments, now allow one to draw a more unified picture. By reviewing these works, we show that three main building blocks exist during the nonlinear evolution: roll cells, relaxation oscillations and relaxation oscillations waves. What is frequently called interfacial turbulence results from the interaction between these partly coexisting basic patterns which may additionally occur in different hierarchy levels. The second focus of this review lies on the practical importance of such convection patterns concerning their influence on mass transfer characteristics. Particular attention is paid here to the interaction between Marangoni and buoyancy effects which frequently complicates the pattern formation even more. To shed more light on these dependencies, new simulations regarding the limiting case of stabilizing density stratification and vanishing buoyancy are incorporated. PMID:24456800

  15. Gas Blowing: Mass Transfer in Gas and Melt

    NASA Astrophysics Data System (ADS)

    Sortland, Øyvind Sunde; Tangstad, Merete

    2014-09-01

    Metallurgical routes for solar grade silicon production are being developed as alternatives to chemical processes for their potential to achieve cost reductions, increased production volume, and reduced environmental and safety concerns. An important challenge in the development of metallurgical routes relates to the higher impurity concentrations in the silicon product, particularly for boron and other elements that are not efficiently segregated in solidification techniques. The reactive gas refining process is studied for its potential to remove boron below the solar grade silicon target concentration in a single step by blowing steam and hydrogen gas jets onto the melt surface. Boron in a silicon melt is extracted to HBO gas in parallel to active oxidation of silicon. The literature is not unified regarding the rate determining step in this process. Relevant theories and equations for gas blowing in induction furnaces are combined and used to explain mass transfer in experiments. Mass transfer in the melt and gas is investigated by comparing resistance and induction heating of the melt, and varying gas flow rate, crucible diameter, diameter of the gas lance, and the position of the gas lance above the melt surface. The rate of boron removal is found to increase with increasing gas flow rate and crucible diameter. A relatively high fraction of the reactive gas is utilized in the process, and supply of steam in the bulk gas is the only identified rate determining step.

  16. Improved Scheme for Modeling Mass Transfer between Fracture and Matrix Continua with Particle Tracking Method

    SciTech Connect

    L. Pan; Y. Seol; G. Bodvarsson

    2004-04-29

    The dual-continuum random-walk particle tracking approach is an attractive simulation method for simulating transport in a fractured porous medium. In order to be truly successful for such a model, however, the key issue is to properly simulate the mass transfer between the fracture and matrix continua. In a recent paper, Pan and Bodvarsson (2002) proposed an improved scheme for simulating fracture-matrix mass transfer, by introducing the concept of activity range into the calculation of fracture-matrix particle-transfer probability. By comparing with analytical solutions, they showed that their scheme successfully captured the transient diffusion depth into the matrix without any additional subgrid (matrix) cells. This technical note presents an expansion of their scheme to cases in which significant water flow through the fracture-matrix interface exists. The dual-continuum particle tracker with this new scheme was found to be as accurate as a numerical model using a more detailed grid. The improved scheme can be readily incorporated into the existing particle-tracking code, while still maintaining the advantage of needing no additional matrix cells to capture transient features of particle penetration into the matrix.

  17. On the behavior of Kazhikov-Smagulov mass diffusion model for vanishing diffusion and viscosity coefficients

    NASA Astrophysics Data System (ADS)

    Araruna, F. D.; Braz e Silva, P.; Carvalho, R. R.; Rojas-Medar, M. A.

    2015-06-01

    We consider the motion of a viscous incompressible fluid consisting of two components with a diffusion effect obeying Fick's law in ℝ3. We prove that there exists a small time interval where the fluid variables converge uniformly as the viscosity and the diffusion coefficient tend to zero. In the limit, we find a non-homogeneous, non-viscous, incompressible fluid governed by an Euler-like system.

  18. Stellar evolution including diffusion and matter flow induced by mass-loss

    NASA Astrophysics Data System (ADS)

    Richard, O.; Vick, M.

    2013-12-01

    It is clear that in order to explain many observed stellar phenomenae, atomic diffusion must be included in stellar models. Observed surface abundances allow us to constrain other transport pro- cesses which compete with atomic diffusion. We will focus on the effect of the flow of matter induced by mass-loss in stellar models.

  19. Evaluation of interfacial mass transfer coefficient as a function of temperature and pressure in carbon dioxide/normal alkane systems

    NASA Astrophysics Data System (ADS)

    Nikkhou, Fatemeh; Keshavarz, Peyman; Ayatollahi, Shahab; Jahromi, Iman Raoofi; Zolghadr, Ali

    2014-09-01

    CO2 gas injection is known as one of the most popular enhanced oil recovery techniques for light and medium oil reservoirs, therefore providing an acceptable mass transfer mechanism for CO2-oil systems seems necessary. In this study, interfacial mass transfer coefficient has been evaluated for CO2-normal heptane and CO2-normal hexadecane systems using equilibrium and dynamic interfacial tension data, which have been measured using the pendant drop method. Interface mass transfer coefficient has been calculated as a function of temperature and pressure in the range of 313-393 K and 1.7-8.6 MPa, respectively. The results showed that the interfacial resistance is a parameter that can control the mass transfer process for some CO2-normal alkane systems, and cannot be neglected. Additionally, it was found that interface mass transfer coefficient increased with pressure. However, the variation of this parameter with temperature did not show a clear trend and it was strongly dependent on the variation of diffusivity and solubility of CO2 in the liquid phase.

  20. Evaluation of interfacial mass transfer coefficient as a function of temperature and pressure in carbon dioxide/normal alkane systems

    NASA Astrophysics Data System (ADS)

    Nikkhou, Fatemeh; Keshavarz, Peyman; Ayatollahi, Shahab; Jahromi, Iman Raoofi; Zolghadr, Ali

    2015-04-01

    CO2 gas injection is known as one of the most popular enhanced oil recovery techniques for light and medium oil reservoirs, therefore providing an acceptable mass transfer mechanism for CO2-oil systems seems necessary. In this study, interfacial mass transfer coefficient has been evaluated for CO2-normal heptane and CO2-normal hexadecane systems using equilibrium and dynamic interfacial tension data, which have been measured using the pendant drop method. Interface mass transfer coefficient has been calculated as a function of temperature and pressure in the range of 313-393 K and 1.7-8.6 MPa, respectively. The results showed that the interfacial resistance is a parameter that can control the mass transfer process for some CO2-normal alkane systems, and cannot be neglected. Additionally, it was found that interface mass transfer coefficient increased with pressure. However, the variation of this parameter with temperature did not show a clear trend and it was strongly dependent on the variation of diffusivity and solubility of CO2 in the liquid phase.

  1. Optimal-mass-transfer-based estimation of glymphatic transport in living brain

    NASA Astrophysics Data System (ADS)

    Ratner, Vadim; Zhu, Liangjia; Kolesov, Ivan; Nedergaard, Maiken; Benveniste, Helene; Tannenbaum, Allen

    2015-03-01

    It was recently shown that the brain-wide cerebrospinal fluid (CSF) and interstitial fluid exchange system designated the `glymphatic pathway' plays a key role in removing waste products from the brain, similarly to the lymphatic system in other body organs . It is therefore important to study the flow patterns of glymphatic transport through the live brain in order to better understand its functionality in normal and pathological states. Unlike blood, the CSF does not flow rapidly through a network of dedicated vessels, but rather through para-vascular channels and brain parenchyma in a slower time-domain, and thus conventional fMRI or other blood-flow sensitive MRI sequences do not provide much useful information about the desired flow patterns. We have accordingly analyzed a series of MRI images, taken at different times, of the brain of a live rat, which was injected with a paramagnetic tracer into the CSF via the lumbar intrathecal space of the spine. Our goal is twofold: (a) find glymphatic (tracer) flow directions in the live rodent brain; and (b) provide a model of a (healthy) brain that will allow the prediction of tracer concentrations given initial conditions. We model the liquid flow through the brain by the diffusion equation. We then use the Optimal Mass Transfer (OMT) approach to derive the glymphatic flow vector field, and estimate the diffusion tensors by analyzing the (changes in the) flow. Simulations show that the resulting model successfully reproduces the dominant features of the experimental data. Keywords: inverse problem, optimal mass transport, diffusion equation, cerebrospinal fluid flow in brain, optical flow, liquid flow modeling, Monge Kantorovich problem, diffusion tensor estimation

  2. Monodisperse droplet generation for microscale mass transfer studies

    NASA Astrophysics Data System (ADS)

    Roberts, Christine; Rao, Rekha; Grillet, Anne; Jove-Colon, Carlos; Brooks, Carlton; Nemer, Martin

    2011-11-01

    Understanding interfacial mass transport on a droplet scale is essential for modeling liquid-liquid extraction processes. A thin flow-focusing microfluidic channel is evaluated for generating monodisperse liquid droplets for microscale mass transport studies. Surface treatment of the microfluidic device allows creation of both oil in water and water in oil emulsions, facilitating a large parameter study of viscosity and flow rate ratios. The unusually thin channel height promotes a flow regime where no droplets form. Through confocal microscopy, this regime is shown to be highly influenced by the contact angle of the liquids with the channel. Drop sizes are found to scale with a modified capillary number. Liquid streamlines within the droplets are inferred by high speed imagery of microparticles dispersed in the droplet phase. Finally, species mass transfer to the droplet fluid is quantitatively measured using high speed imaging. Sandia National Laboratories is a multi-program laboratory operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85.

  3. Evaluation of the Effect of Gravity Force on Transient Mass Diffusion Fields

    NASA Astrophysics Data System (ADS)

    Komiya, Atsuki; Maruyama, Shigenao

    In this study, the relationship between gravitational force and diffusion phenomena in aque-ous solutions is discussed. The microgravity environment gives a high quality crystal growth condition which produces high quality medicines or foods. In this condition, a natural con-vection can be neglected and diffusion phenomenon without convection is observed. The mass diffusion coefficient is one of the most important thermophysical properties to investigate that mass transport system. However, the available experimental data of mass diffusion coefficients in microgravity conditions is not enough. Because it is quite a few opportunity that exper-iments can be conducted using facilities which produce microgravity environment for a long time. Then we have developed an observation system of small transient diffusion fields within 20 seconds. The experimental apparatus is composed of phase shifting interferometer, special designed signal processing unit and recorder. The mechanism of test cell used in this study has a unique performance that the transient diffusion fields can be produced continuously with no change of solutions and cell. Therefore this system can be applied to short-time microgravity experiment which is generated by the parabolic flight of an airplane. By using this system, the transient diffusion field of Sodium Chloride (NaCl) solution in microgravity conditions could be clearly observed and the mass diffusion coefficient was estimated from the obtained data. In microgravity condition, the transient diffusion fields have different appearances from the normal gravity condition. A slight acceleration governs the transient diffusion fields because of no density difference, so vibrations applied the apparatus disturb the transient diffusion fields. The measured mass diffusion coefficient has been estimated as a smaller value compared with ones under normal gravity condition. Using the airplane as a facility, not only microgravity condition but also 0.8G, 1

  4. Transformed Fourier and Fick equations for the control of heat and mass diffusion

    NASA Astrophysics Data System (ADS)

    Guenneau, S.; Petiteau, D.; Zerrad, M.; Amra, C.; Puvirajesinghe, T.

    2015-05-01

    We review recent advances in the control of diffusion processes in thermodynamics and life sciences through geometric transforms in the Fourier and Fick equations, which govern heat and mass diffusion, respectively. We propose to further encompass transport properties in the transformed equations, whereby the temperature is governed by a three-dimensional, time-dependent, anisotropic heterogeneous convection-diffusion equation, which is a parabolic partial differential equation combining the diffusion equation and the advection equation. We perform two dimensional finite element computations for cloaks, concentrators and rotators of a complex shape in the transient regime. We precise that in contrast to invisibility cloaks for waves, the temperature (or mass concentration) inside a diffusion cloak crucially depends upon time, its distance from the source, and the diffusivity of the invisibility region. However, heat (or mass) diffusion outside cloaks, concentrators and rotators is unaffected by their presence, whatever their shape or position. Finally, we propose simplified designs of layered cylindrical and spherical diffusion cloaks that might foster experimental efforts in thermal and biochemical metamaterials.

  5. Transformed Fourier and Fick equations for the control of heat and mass diffusion

    SciTech Connect

    Guenneau, S.; Petiteau, D.; Zerrad, M.; Amra, C.; Puvirajesinghe, T.

    2015-05-15

    We review recent advances in the control of diffusion processes in thermodynamics and life sciences through geometric transforms in the Fourier and Fick equations, which govern heat and mass diffusion, respectively. We propose to further encompass transport properties in the transformed equations, whereby the temperature is governed by a three-dimensional, time-dependent, anisotropic heterogeneous convection-diffusion equation, which is a parabolic partial differential equation combining the diffusion equation and the advection equation. We perform two dimensional finite element computations for cloaks, concentrators and rotators of a complex shape in the transient regime. We precise that in contrast to invisibility cloaks for waves, the temperature (or mass concentration) inside a diffusion cloak crucially depends upon time, its distance from the source, and the diffusivity of the invisibility region. However, heat (or mass) diffusion outside cloaks, concentrators and rotators is unaffected by their presence, whatever their shape or position. Finally, we propose simplified designs of layered cylindrical and spherical diffusion cloaks that might foster experimental efforts in thermal and biochemical metamaterials.

  6. Syngas fermentation to biofuel: evaluation of carbon monoxide mass transfer coefficient (kLa) in different reactor configurations.

    PubMed

    Munasinghe, Pradeep Chaminda; Khanal, Samir Kumar

    2010-01-01

    Lignocellulosic biomass such as agri-residues, agri-processing by-products, and energy crops do not compete with food and feed, and is considered to be the ideal renewable feedstocks for biofuel production. Gasification of biomass produces synthesis gas (syngas), a mixture primarily consisting of CO and H(2). The produced syngas can be converted to ethanol by anaerobic microbial catalysts especially acetogenic bacteria such as various clostridia species.One of the major drawbacks associated with syngas fermentation is the mass transfer limitation of these sparingly soluble gases in the aqueous phase. One way of addressing this issue is the improvement in reactor design to achieve a higher volumetric mass transfer coefficient (k(L)a). In this study, different reactor configurations such as a column diffuser, a 20-μm bulb diffuser, gas sparger, gas sparger with mechanical mixing, air-lift reactor combined with a 20-μm bulb diffuser, air-lift reactor combined with a single gas entry point, and a submerged composite hollow fiber membrane (CHFM) module were employed to examine the k(L) a values. The k(L) a values reported in this study ranged from 0.4 to 91.08 h(-1). The highest k(L) a of 91.08 h(-1) was obtained in the air-lift reactor combined with a 20-μm bulb diffuser, whereas the reactor with the CHFM showed the lowest k(L) a of 0.4 h(-1). By considering both the k(L) a value and the statistical significance of each configuration, the air-lift reactor combined with a 20-μm bulb diffuser was found to be the ideal reactor configuration for carbon monoxide mass transfer in an aqueous phase. PMID:20677226

  7. Mass transfer during osmotic dehydration of celery stalks in a batch osmo-reactor

    NASA Astrophysics Data System (ADS)

    Sareban, M.; Abbasi Souraki, B.

    2016-07-01

    In this study, dehydration behavior of bulk of celery stalks, during osmotic drying in a limited volume of salt solution, was investigated. Experiments were carried out in the three initial solution concentrations of 10, 18 and 25 % (w/w) and at the three temperatures of 35, 45 and 55 °C. The volume ratio of the fruit to the solution was considered 1:3. A two-parameter model was used for prediction of kinetics of mass transfer and values of equilibrium moisture loss and solid gain. Moisture and salt effective diffusivities in celery stalks were estimated by fitting the experimental data of moisture loss and solute gain to the analytical solution of Fick's second law of diffusion. The analytical model was solved by defining a partition factor, K, assuming that the concentration of solute just within the surface of the material is K times that in the solution. Results showed that moisture and salt effective diffusivities and equilibrium values of moisture loss and solute gain increased with increasing the temperature and solution concentration. Results showed a good agreement between the two parameter model (with mean relative error of 4.016 % for moisture loss and 5.977 % for solid gain), analytical solution of Fick's second law (with mean relative error of 8.924 % for moisture loss and 9.164 % for solid gain) and experimental data.

  8. A new characterization of the turbulent diapycnal diffusivities of mass and momentum in the ocean

    NASA Astrophysics Data System (ADS)

    Salehipour, H.; Peltier, W. R.; Whalen, C. B.; MacKinnon, J. A.

    2016-04-01

    The diapycnal diffusivity of mass supported by turbulent events in the ocean interior plays a fundamental role in controlling the global overturning circulation. The conventional representation of this diffusivity, due to Osborn (1980), assumes a constant mixing efficiency. We replace this methodology by a generalized-Osborn formula which involves a mixing efficiency that varies nonmonotonically with at least two nondimensional variables. Using these two variables, we propose dynamic parameterizations for mixing efficiency and turbulent Prandtl number (the latter quantifies the ratio of momentum to mass diapycnal diffusivities) based on the first synthesis of an extensive direct numerical simulation of inhomogeneously stratified shear-induced turbulence. Data from Argo floats are employed to demonstrate the extent of the spatial and statistical variability to be expected in both the diapycnal diffusivities of mass and momentum. We therefore suggest that previous estimates of these important characteristics of the global ocean require reconsideration.

  9. Modeling of Heat and Mass Transfer in Fusion Welding

    SciTech Connect

    Zhang, Wei

    2011-01-01

    In fusion welding, parts are joined together by melting and subsequent solidification. Although this principle is simple, complex transport phenomena take place during fusion welding, and they determine the final weld quality and performance. The heat and mass transfer in the weld pool directly affect the size and shape of the pool, the solidification microstructure, the formation of weld defects such as porosity and humping, and the temperature distribution in the fusion zone and heat-affected zone (HAZ). Furthermore, the temperature evolution affects the kinetics and extent of various solid-state phase transformations, which in turn determine the final weld microstructure and mechanical properties. The formation of residual stresses and distortion originates from the thermal expansion and contraction during welding heating and cooling, respectively.

  10. Code System to Calculate Heat and Mass Transfer In Concrete

    Energy Science and Technology Software Center (ESTSC)

    1999-05-26

    Version 00 This version is designated USINTC and was developed to model the thermal response of concrete to very high heating rates such as might occur from sodium spills on concrete surfaces in a breeder reactor. The major phenomena treated are conductive energy transport; chemical decomposition of concrete; and two-phase, three-component heat and mass transfer of the decomposition products: steam, liquid water, and carbon dioxide. The USINT model provides for porosity to increase as watermore » and carbon-dioxide are formed from the concrete. The concrete is treated generally as divided into two basic regions, wet and dry. In the wet region, steam, carbon-dioxide, and liquid water may co-exist, but in the dry region, there is no liquid water. There is also the possibility of a third region in which there is only liquid water and no gases.« less

  11. Local translational diffusion rates of membranous Na+,K(+)-ATPase measured by saturation transfer ESR spectroscopy.

    PubMed Central

    Esmann, M; Marsh, D

    1992-01-01

    Diffusion-controlled Heisenberg spin exchange between spin-labeled Na+,K(+)-ATPase [ATP phosphohydrolase (Na+/K(+)-transporting), EC 3.6.1.37] proteins has been studied by saturation transfer ESR spectroscopy in reconstituted membranes. Na+,K(+)-ATPase from the salt gland of Squalus acanthias was solubilized in a polyoxyethylene ether detergent, octa(ethylene glycol) dodecyl monoether. Part of the solubilized enzyme was covalently spin-labeled with a nitroxide derivative of indanedione and recombined with various proportions of the unlabeled enzyme while the native lipid/protein ratio was maintained. Purified membranes were then reconstituted from the various samples by precipitation with divalent ions. The reciprocal integrated intensities of the saturation transfer ESR spectra were found to increase linearly with the fraction of protein that was spin-labeled, and the gradient of the concentration dependence increased with increasing temperature over the range 4 degrees-25 degrees C. Comparison with theoretical analyses of the effects of weak Heisenberg spin exchange [Marsh, D. & Horváth, L. I. (1992) J. Magn. Reson. 97, 13-26] suggests that the effects on the saturation transfer ESR intensity are attributable to short-range diffusional collisions between the spin-labeled protein molecules. The effective value of the local translational diffusion coefficient is 1.8-2.9 microns2.s-1 at 15 degrees C, depending on the diffusion model used, which is much larger than the values obtained for the long-range diffusion coefficient in cells by photobleaching techniques. The temperature dependence of the translational diffusion is larger than expected but correlates with the anomalous temperature dependence of the rotational diffusion observed in the same system. PMID:1323847

  12. Evaluation of a radiative transfer equation and diffusion approximation hybrid forward solver for fluorescence molecular imaging.

    PubMed

    Gorpas, Dimitris; Andersson-Engels, Stefan

    2012-12-01

    The solution of the forward problem in fluorescence molecular imaging strongly influences the successful convergence of the fluorophore reconstruction. The most common approach to meeting this problem has been to apply the diffusion approximation. However, this model is a first-order angular approximation of the radiative transfer equation, and thus is subject to some well-known limitations. This manuscript proposes a methodology that confronts these limitations by applying the radiative transfer equation in spatial regions in which the diffusion approximation gives decreased accuracy. The explicit integro differential equations that formulate this model were solved by applying the Galerkin finite element approximation. The required spatial discretization of the investigated domain was implemented through the Delaunay triangulation, while the azimuthal discretization scheme was used for the angular space. This model has been evaluated on two simulation geometries and the results were compared with results from an independent Monte Carlo method and the radiative transfer equation by calculating the absolute values of the relative errors between these models. The results show that the proposed forward solver can approximate the radiative transfer equation and the Monte Carlo method with better than 95% accuracy, while the accuracy of the diffusion approximation is approximately 10% lower. PMID:23208221

  13. Mass transfer of electron acceptor aross the capillary fringe

    NASA Astrophysics Data System (ADS)

    Liu, S.; Piepenbrink, M.; Grathwohl, P.

    2005-12-01

    Transverse dispersion has been identified as a potentially limiting parameter controlling the mixing of electron donors and electron acceptors for natural attenuation of plumes originating from continuously emitting sources, however determining reactive transverse dispersion coefficients is not a simple task. The objective of this work is to elaborate the mass transfer of electron acceptor across the capillary fringe. A two-dimensional numerical reactive transport model and a fully controlled tank experiment are set up to investigate the mass transfer across the capillary and reactive fringe, where the oxygen supply is the limiting factor. The tank (77.9 times 14 times 0.8 cm) is made from acrylic-glass and filled with glass beads (0.5-0.75mm). Sodium dithionite, an easily oxidizable compound, is used as a surrogate for contaminants and is continuously injected from the inlets of the tank and reaches a steady state flow. Air circulates on the top of the glass beads. The oxygen concentrations as well as the reactive products (sulfate) are measured at the outlets of the tank with an oxygen sensor and via IC. In addition to that, resazurine, a redox indicator, is added to visualize the redox zones. These two-dimensional experimental results show quantitatively and qualitatively how the oxygen concentrations decrease at the plume fringe. Two dimensional numerical simulations with Min3P predicted oxygen distributions are compared with the experimental results. Acknowledgements: This work was funded by Helmholtz Association and Helmholtz Research Center UFZ; Project: `Virtual Institute for isotope biogeochemistry-biologically mediated processes at geochemical gradients and interfaces in soil - aquifer systems', Contract VH-VI-155.

  14. Implicit Monte Carlo diffusion - an acceleration method for Monte Carlo time dependent radiative transfer simulations

    SciTech Connect

    Gentile, N A

    2000-10-01

    We present a method for accelerating time dependent Monte Carlo radiative transfer calculations by using a discretization of the diffusion equation to calculate probabilities that are used to advance particles in regions with small mean free path. The method is demonstrated on problems with on 1 and 2 dimensional orthogonal grids. It results in decreases in run time of more than an order of magnitude on these problems, while producing answers with accuracy comparable to pure IMC simulations. We call the method Implicit Monte Carlo Diffusion, which we abbreviate IMD.

  15. Devices with extended area structures for mass transfer processing of fluids

    DOEpatents

    TeGrotenhuis, Ward E.; Wegeng, Robert S.; Whyatt, Greg A.; King, David L.; Brooks, Kriston P.; Stenkamp, Victoria S.

    2009-04-21

    A microchannel device includes several mass transfer microchannels to receive a fluid media for processing at least one heat transfer microchannel in fluid communication with a heat transfer fluid defined by a thermally conductive wall, and at several thermally conductive fins each connected to the wall and extending therefrom to separate the mass transfer microchannels from one another. In one form, the device may optionally include another heat transfer microchannel and corresponding wall that is positioned opposite the first wall and has the fins and the mass transfer microchannels extending therebetween.

  16. Isotopic mass-dependence of noble gas diffusion coefficients inwater

    SciTech Connect

    Bourg, I.C.; Sposito, G.

    2007-06-25

    Noble gas isotopes are used extensively as tracers inhydrologic and paleoclimatic studies. These applications requireknowledge of the isotopic mass (m) dependence of noble gas diffusioncoefficients in water (D), which has not been measured but is estimatedusing experimental D-values for the major isotopes along with an untestedrelationship from kinetic theory, D prop m-0.5. We applied moleculardynamics methods to determine the mass dependence of D for four noblegases at 298 K, finding that D prop m-beta with beta<0.2, whichrefutes the kinetic theory model underlying all currentapplications.

  17. Diffusion-assisted photoexcitation transfer in coupled semiconducting carbon nanotube thin films.

    PubMed

    Grechko, Maksim; Ye, Yumin; Mehlenbacher, Randy D; McDonough, Thomas J; Wu, Meng-Yin; Jacobberger, Robert M; Arnold, Michael S; Zanni, Martin T

    2014-06-24

    We utilize femtosecond transient absorption spectroscopy to study dynamics of photoexcitation migration in films of semiconducting single-wall carbon nanotubes. Films of nanotubes in close contact enable energy migration such as needed in photovoltaic and electroluminescent devices. Two types of films composed of nanotube fibers are utilized in this study: densely packed and very porous. By comparing exciton kinetics in these films, we characterize excitation transfer between carbon nanotubes inside fibers versus between fibers. We find that intrafiber transfer takes place in both types of films, whereas interfiber transfer is greatly suppressed in the porous one. Using films with different nanotube composition, we are able to test several models of exciton transfer. The data are inconsistent with models that rely on through-space interfiber energy transfer. A model that fits the experimental results postulates that interfiber transfer occurs only at intersections between fibers, and the excitons reach the intersections by diffusing along the long-axis of the tubes. We find that time constants for the inter- and intrafiber transfers are 0.2-0.4 and 7 ps, respectively. In total, hopping between fibers accounts for about 60% of all exciton downhill transfer prior to 4 ps in the dense film. The results are discussed with regards to transmission electron micrographs of the films. This study provides a rigorous analysis of the photophysics in this new class of promising materials for photovoltaics and other technologies. PMID:24806792

  18. Mass balance model parameter transferability on a tropical glacier

    NASA Astrophysics Data System (ADS)

    Gurgiser, Wolfgang; Mölg, Thomas; Nicholson, Lindsey; Kaser, Georg

    2013-04-01

    The mass balance and melt water production of glaciers is of particular interest in the Peruvian Andes where glacier melt water has markedly increased water supply during the pronounced dry seasons in recent decades. However, the melt water contribution from glaciers is projected to decrease with appreciable negative impacts on the local society within the coming decades. Understanding mass balance processes on tropical glaciers is a prerequisite for modeling present and future glacier runoff. As a first step towards this aim we applied a process-based surface mass balance model in order to calculate observed ablation at two stakes in the ablation zone of Shallap Glacier (4800 m a.s.l., 9°S) in the Cordillera Blanca, Peru. Under the tropical climate, the snow line migrates very frequently across most of the ablation zone all year round causing large temporal and spatial variations of glacier surface conditions and related ablation. Consequently, pronounced differences between the two chosen stakes and the two years were observed. Hourly records of temperature, humidity, wind speed, short wave incoming radiation, and precipitation are available from an automatic weather station (AWS) on the moraine near the glacier for the hydrological years 2006/07 and 2007/08 while stake readings are available at intervals of between 14 to 64 days. To optimize model parameters, we used 1000 model simulations in which the most sensitive model parameters were varied randomly within their physically meaningful ranges. The modeled surface height change was evaluated against the two stake locations in the lower ablation zone (SH11, 4760m) and in the upper ablation zone (SH22, 4816m), respectively. The optimal parameter set for each point achieved good model skill but if we transfer the best parameter combination from one stake site to the other stake site model errors increases significantly. The same happens if we optimize the model parameters for each year individually and transfer

  19. Intracrystalline mass transfer in zeolites monitored by microscopic and macroscopic techniques

    SciTech Connect

    Foerste, C.; Kaerger, J.; Pfeifer, H. )

    1990-01-03

    Conventional {sup 1}H NMR signal intensity measurements have been used to monitor macroscopically the kinetics of molecular exchange of deuterium-labeled molecules between the intracrystalline space of zeolite crystallites and the surrounding atmosphere. After reaching equilibrium, a pulsed-field-gradient experiment was performed within the same sample tube so that it became possible for the first time to compare results for the intracrystalline migration of adsorbed molecules derived from macroscopic (intensity) and microscopic (pulsed-field-gradient) measurements on identical samples. For benzene adsorbed on zeolite Na-X the intracrystalline diffusivities resulting from these two measuring techniques are found to be in satisfactory agreement. This result proves that molecular exchange between benzene adsorbed in the intracrystalline space of Na-X and the surrounding atmosphere is essentially controlled by intracrystalline mass transfer.

  20. Limestone characterization to model damage from acidic precipitation: Effect of pore structure on mass transfer

    USGS Publications Warehouse

    Leith, S.D.; Reddy, M.M.; Irez, W.F.; Heymans, M.J.

    1996-01-01

    The pore structure of Salem limestone is investigated, and conclusions regarding the effect of the pore geometry on modeling moisture and contaminant transport are discussed based on thin section petrography, scanning electron microscopy, mercury intrusion porosimetry, and nitrogen adsorption analyses. These investigations are compared to and shown to compliment permeability and capillary pressure measurements for this common building stone. Salem limestone exhibits a bimodal pore size distribution in which the larger pores provide routes for convective mass transfer of contaminants into the material and the smaller pores lead to high surface area adsorption and reaction sites. Relative permeability and capillary pressure measurements of the air/water system indicate that Salem limestone exhibits high capillarity end low effective permeability to water. Based on stone characterization, aqueous diffusion and convection are believed to be the primary transport mechanisms for pollutants in this stone. The extent of contaminant accumulation in the stone depends on the mechanism of partitioning between the aqueous and solid phases. The described characterization techniques and modeling approach can be applied to many systems of interest such as acidic damage to limestone, mass transfer of contaminants in concrete and other porous building materials, and modeling pollutant transport in subsurface moisture zones.

  1. Numerical simulations of heat and mass transfer at ablating surface in hypersonic flow

    NASA Astrophysics Data System (ADS)

    Bocharov, A. N.; Golovin, N. N.; Petrovskiy, V. P.; Teplyakov, I. O.

    2015-11-01

    The numerical technique was developed to solve heat and mass transfer problem in 3D hypersonic flow taking into account destruction of thermal protection system. Described technique was applied for calculation of heat and mass transfer in sphere-cone shaped body. The data on temperature, heat flux and mass flux were obtained.

  2. Effect of molecular weight on ion diffusion and transference number in poly(ethylene oxide)

    NASA Astrophysics Data System (ADS)

    Timachova, Ksenia; Balsara, Nitash

    2015-03-01

    Solid polymer electrolytes are of great interest for their potential use in high specific energy, solid-state batteries, however, salt transport properties in polymer electrolytes have not been comprehensively addressed over a wide range of molecular weights. Poly(ethylene oxide) (PEO) has been the most widely studied polymer electrolyte due to its high solvation of lithium salts and low glass transition temperature. This study presents measurements of the transport properties of lithium bis(trifluoromethanesulfone)imide (LiTFSI) in PEO at both the high concentration present in functional electrolytes and in the dilute limit for a large range of PEO molecular weights. Individual diffusion coefficients of the Li + and TFSI- ions were measured using pulsed-field gradient nuclear magnetic resonance and the cation transference number was calculated. The diffusion coefficients, transference number, and conductivity as a function of molecular weight and salt concentration provide a complete set of transport properties for PEO.

  3. Diffusive transfer of polarized 3He gas through depolarizing magnetic gradients

    NASA Astrophysics Data System (ADS)

    Maxwell, J. D.; Epstein, C. S.; Milner, R. G.

    2015-03-01

    Transfer of polarized 3He gas across spatially varying magnetic fields will facilitate a new source of polarized 3He ions for particle accelerators. In this context, depolarization of atoms as they pass through regions of significant transverse field gradients is a major concern. To understand these depolarization effects, we have built a system consisting of a Helmholtz coil pair and a solenoid, both with central magnetic fields of order 30 gauss. The atoms are polarized via metastability exchange optical pumping in the Helmholtz coil and are in diffusive contact via a glass tube with a second test cell in the solenoid. We have carried out measurements of the spin relaxation during transfer of polarization in 3He at 1 torr by diffusion. We explore the use of measurements of the loss of polarization taken in one cell to infer the polarization in the other cell.

  4. Diffusion-enhanced lanthanide energy transfer studies of protein prosthetic groups

    SciTech Connect

    Meares, C.F.; Yeh, S.M.; Rice, L.S.

    1980-10-01

    A long-lived luminescent solute in aqueous solution (e.g., /sup 5/D/sub 4/ terbium, tau approx. =10/sup -3/s) can donate its excitation energy to a chromophore such as a protein prosthetic group by, e.g., the radiationless dipolar mechanism of Foerster. However, in contrast to the usual energy-transfer experiment, a donor with a 10/sup -3/s lifetime can diffuse extensively through the solution and, in a time scale short compared to its excited lifetime, sample all permitted locations with respect to chromophoric acceptors. As recently indicated by Thomas et al. energy transfer in this rapid-diffusion limit can permit direct measurement of the allowed distance of closest approach of small solute molecules to chromophores which may be buried within proteins or membranes.

  5. Image Reconstruction for Diffuse Optical Tomography Based on Radiative Transfer Equation

    PubMed Central

    Han, Bo; Tang, Jinping

    2015-01-01

    Diffuse optical tomography is a novel molecular imaging technology for small animal studies. Most known reconstruction methods use the diffusion equation (DA) as forward model, although the validation of DA breaks down in certain situations. In this work, we use the radiative transfer equation as forward model which provides an accurate description of the light propagation within biological media and investigate the potential of sparsity constraints in solving the diffuse optical tomography inverse problem. The feasibility of the sparsity reconstruction approach is evaluated by boundary angular-averaged measurement data and internal angular-averaged measurement data. Simulation results demonstrate that in most of the test cases the reconstructions with sparsity regularization are both qualitatively and quantitatively more reliable than those with standard L2 regularization. Results also show the competitive performance of the split Bregman algorithm for the DOT image reconstruction with sparsity regularization compared with other existing L1 algorithms. PMID:25648064

  6. The impact of separated flow on heat and mass transfer. Final report

    SciTech Connect

    Goldstein, R.J.

    1998-08-01

    An investigation of the effect of flow separation on heat and mass transfer has been completed. This research provided enhanced understanding of fundamental mechanisms governing important heat and mass transfer flow processes. This report summarizes the work conducted under the project. This research has provided considerable new knowledge on flow and heat transfer situations of great interest in a number of energy conversion devices, including heat exchangers, gas turbines, solar energy systems and general heat transfer systems.

  7. Multi-rate mass transfer modeling of two-phase flow in highly heterogeneous fractured and porous media

    NASA Astrophysics Data System (ADS)

    Tecklenburg, Jan; Neuweiler, Insa; Carrera, Jesus; Dentz, Marco

    2016-05-01

    We study modeling of two-phase flow in highly heterogeneous fractured and porous media. The flow behaviour is strongly influenced by mass transfer between a highly permeable (mobile) fracture domain and less permeable (immobile) matrix blocks. We quantify the effective two-phase flow behavior using a multirate rate mass transfer (MRMT) approach. We discuss the range of applicability of the MRMT approach in terms of the pertinent viscous and capillary diffusion time scales. We scrutinize the linearization of capillary diffusion in the immobile regions, which allows for the formulation of MRMT in the form of a non-local single equation model. The global memory function, which encodes mass transfer between the mobile and the immobile regions, is at the center of this method. We propose two methods to estimate the global memory function for a fracture network with given fracture and matrix geometry. Both employ a scaling approach based on the known local memory function for a given immobile region. With the first method, the local memory function is calculated numerically, while the second one employs a parametric memory function in form of truncated power-law. The developed concepts are applied and tested for fracture networks of different complexity. We find that both physically based parameter estimation methods for the global memory function provide predictive MRMT approaches for the description of multiphase flow in highly heterogeneous porous media.

  8. Numerical Simulations of the Onset and Stability of Dynamical Mass Transfer in Binaries

    NASA Astrophysics Data System (ADS)

    D'Souza, Mario C. R.; Motl, Patrick M.; Tohline, Joel E.; Frank, Juhan

    2006-05-01

    Hydrodynamical simulations of semidetached, polytropic binary stars are presented in an effort to study the onset and stability of dynamical mass transfer events. Initial, synchronously rotating equilibrium models are constructed using a self-consistent field technique and then evolved with an Eulerian hydrodynamics code in a fully self-consistent manner. We describe code improvements introduced over the past few years that permit us to follow dynamical mass transfer events through more than 30 orbits. Mass transfer evolutions are presented for two different initial configurations: a dynamically unstable binary with initial mass ratio (donor/accretor) q0=1.3 that leads to a complete merger in ~10 orbits, and a double-degenerate binary with initial mass ratio q0=0.5 that, after some initial unstable growth of mass transfer, tends to separate as the mass transfer rate levels off.

  9. Direct Geoelectrical Evidence of Mass Transfer at the Lab scale

    NASA Astrophysics Data System (ADS)

    Swanson, R. D.; Singha, K.; Day-Lewis, F. D.; Keating, K.; Binley, A.; Clifford, J.; Haggerty, R.

    2011-12-01

    At many field sites, anomalous tailing behavior-- a long, slow decrease of solute concentration in time-- is observed yet cannot be explained with the advection-dispersion model. One explanation for this commonly observed behavior is the exchange of solute between mobile and immobile domains; however, direct experimental observations of this controlling process remain elusive. Circumstantial evidence for a less-mobile phase is typically inferred from tailing behavior observed in fluid samples of the mobile phase. Electrical methods provide a measure of the total solutes in both the immobile and mobile domain and therefore have been hypothesized to provide, in combination with fluid sampling, direct experimental evidence for a less-mobile and mobile model, yet experimental evidence is needed to support this claim. Here, we conduct column solute tracer tests and measure both electrical resistivity and fluid conductivity on unconsolidated, well-sorted sand in addition to fine and coarse fractions of the porous zeolite clinoptilolite. We examine nearly co-located time-lapse standard fluid conductivity and bulk apparent resistivity measurements to identify solute exchange between multiple domains at the lab scale. Our results show extensive tailing behavior in both fluid and bulk electrical conductivity measurements in the zeolite but not in sand, providing evidence for a mobile-immobile framework. Transport parameters are estimated by minimizing the root-mean-square error between the observed and simulated fluid conductivity in COMSOL Multiphysics. These best-fit parameters support our claims of mass transfer occurring in the zeolite columns and provide the first direct electrical evidence of dual-domain mass transport at the lab scale.

  10. Sudden Morphometric Changes Induced by Diffuse Mass Wasting Processes

    NASA Astrophysics Data System (ADS)

    Moretti, S.; Casagli, N.; Catani, F.; Battistini, A.; Raspini, F.

    2010-12-01

    On October 1st, 2009, an exceptionally intense and prolonged rainfall event, preceded by two similar storms on 16 and 23-24 September, triggered a large number of shallow landslides in the province of Messina (Sicily), causing human losses and extensive damages. In a follow-up study a detailed geomorphological survey was carried out as well as a LIDAR digital elevation model. In this paper we present an attempt at using such data to model and understand the mass wasting processes and their consequences in terms of slope morphometry changes in one of the affected watersheds, the Briga creek. Here, the event was characterized by a sudden triggering of many similar shallow soil failures, generating in turn a sediment flow that moved along the main directions of drainage with high velocities and modalities ranging from debris flow to mud flow. The main damages were registered at the channel junctions and at the watershed outlet, where the major mass concentration was reached. Starting from the landslide inventory mapping carried out a few days after the event, we performed an analisys of mobilized volumes, using a method that numerically compares the pre-event and the post-event DEMs. Afterwards, we generated a very accurate, morphology-based reconstruction of flow directions for the entire watershed, in order to understand which were the main avenues of mass flow over the area and where most of the mobilized sediment was deposited. Finally, combining the extensive data connected with landslide scars with a statistical model for the prediction of regolith thickness, we propose a distributed model of colluvium depth for the Briga watershed. The use of this dataset together with present-day topography as derived from LIDAR data allows for the definition of topographic and bedrock gradient maps which, in turn, constitute an important step towards the definition of the actual boundary conditions for slope stability analysis. We believe that this will be a fundamental

  11. An experimental correction proposed for an accurate determination of mass diffusivity of wood in steady regime

    NASA Astrophysics Data System (ADS)

    Zohoun, Sylvain; Agoua, Eusèbe; Degan, Gérard; Perre, Patrick

    2002-08-01

    This paper presents an experimental study of the mass diffusion in the hygroscopic region of four temperate species and three tropical ones. In order to simplify the interpretation of the phenomena, a dimensionless parameter called reduced diffusivity is defined. This parameter varies from 0 to 1. The method used is firstly based on the determination of that parameter from results of the measurement of the mass flux which takes into account the conditions of operating standard device (tightness, dimensional variations and easy installation of samples of wood, good stability of temperature and humidity). Secondly the reasons why that parameter has to be corrected are presented. An abacus for this correction of mass diffusivity of wood in steady regime has been plotted. This work constitutes an advanced deal nowadays for characterising forest species.

  12. Intermolecular electron transfer rate in diffusion limited region: Picosecond fluorescence studies

    NASA Astrophysics Data System (ADS)

    Venkataraman, B.; Periasamy, N.; Modi, S.; Dutt, G. Bhaskar; Doraiswamy, S.

    1992-12-01

    The temporal profiles of the quenched fluorescence decay of the free base meso-tetraphenyl porphyrin (H 2TPP) and its Zn derivative (ZnTPP) with quenchers such as quinones and m-dinitrobenzene have been analysed by methods developed for short time regimes which are known to be diffusion influenced [N. Periasamy et al., J. Chem. Phys.88, 1638 (1988); 89, 4799 (1988); Chem. Phys. Lett.160, 457 (1989); N. Periasamy, Biophys. J.. 54, 961 (1988); R. Das and N. Periasamy, Chem. Phys. 136, 361 (1989); G.C. Joshi et al., J. Phys. Chem.94, 2908 (1990)]. These quenchers are known to participate in an electron transfer reaction leading to a charge separation. The intrinsic rate constant ( ka) derived from the analysis is examined as a function of the change in free energy in the electron transfer reaction. Such a comparison indicates that ka can be related to the electron transfer rate, ket. The electron transfer rates measured in acetonitrile (solvent reorganization energy, λ s = 1.35) and toluene (λ s = 0.1) do not indicate the existence of an inverted region as predicted by Marcus. The trend agrees with the findings of Rehm and Weller [ Isr. J. Chem.8, 259 (1970)], except that the rate constants are at least one order of magnitude larger than the diffusion limited values.

  13. Convective heat and mass transfer during the evaporation of a liquid into a gas flow

    NASA Astrophysics Data System (ADS)

    Boiarshinov, B. F.; Volchkov, E. P.; Terekhov, V. I.

    1985-10-01

    Heat and mass transfer processes associated with liquid evaporation are analyzed for adiabatic and nonadiabatic conditions. Experimental data are then presented on heat and mass transfer during the evaporation of water and ethyl alcohol from a porous surface. It is shown that heat and mass transfer under conditions of evaporation can be described by using expressions for flow past a 'dry' wall. A diagram is presented for determining the magnitudes of additional heat sources in the case of nonadiabatic evaporation. Finally, the effect of various factors, such as temperature, flow humidity, and liquid type, on heat and mass transfer during evaporation is analyzed for laminar and turbulent flows.

  14. Biological conversion of synthesis gas. Mass transfer/kinetic studies

    SciTech Connect

    Klasson, K.T.; Basu, R.; Johnson, E.R.; Clausen, E.C.; Gaddy, J.L.

    1992-03-01

    Mass transfer and kinetic studies were carried out for the Rhodospirillum rubrum and Chlorobium thiosulfatophilum bacterial systems. R. rubrum is a photosynthetic anaerobic bacterium which catalyzes the biological water gas shift reaction: CO + H{sub 2}0 {yields} CO{sub 2} + H{sub 2}. C. thiosulfatophilum is also a H{sub 2}S and COS to elemental sulfur. The growth of R. rubrum may be satisfactorily carried out at 25{degree} and 30{degree}C, while CO uptake and thus the conversion of CO best occurs at temperatures of either 30{degree}, 32{degree} or 34{degree}C. The rate of conversion of COs and H{sub 2}O to CO{sub 2} and H{sub 2}S may be modeled by a first order rate expression. The rate constant at 30{degree}C was found to be 0.243 h{sup {minus}1}. The growth of C. thiosulfatophilum may be modeled in terms of incoming light intensity using a Monod equation: {mu} = {sub 351} + I{sub o}/{sup 0.152}I{sub o}. Comparisons of the growth of R. rubrum and C. thiosulfatophilum shows that the specific growth rate of C. thiosulfatophilum is much higher at a given light intensity.

  15. Heat and mass transfer in unsaturated porous media. Final report

    SciTech Connect

    Childs, S.W.; Malstaff, G.

    1982-02-01

    A preliminary study of heat and water transport in unsaturated porous media is reported. The project provides background information regarding the feasibility of seasonal thermal energy storage in unconfined aquifers. A parametric analysis of the factors of importance, and an annotated bibliography of research findings pertinent to unconfined aquifer thermal energy storage (ATES) are presented. This analysis shows that heat and mass transfer of water vapor assume dominant importance in unsaturated porous media at elevated temperature. Although water vapor fluxes are seldom as large as saturated medium liquid water fluxes, they are important under unsaturated conditions. The major heat transport mechanism for unsaturated porous media at temperatures from 50 to 90/sup 0/C is latent heat flux. The mechanism is nonexistent under saturated conditions but may well control design of unconfined aquifer storage systems. The parametric analysis treats detailed physical phenomena which occur in the flow systems study and demonstrates the temperature and moisture dependence of the transport coefficients of importance. The question of design of an unconfined ATES site is also addressed by considering the effects of aquifer temperature, depth to water table, porous medium flow properties, and surface boundary conditions. Recommendations are made for continuation of this project in its second phase. Both scientific and engineering goals are considered and alternatives are presented.

  16. Sorption and modeling of mass transfer of toxic chemical vapors in activated-carbon fiber-cloth adsorbers

    USGS Publications Warehouse

    Lordgooei, M.; Sagen, J.; Rood, M.J.; Rostam-Abadi, M.

    1998-01-01

    A new activated-carbon fiber-cloth (ACFC) adsorber coupled with an electrothermal regenerator and a cryogenic condenser was designed and developed to efficiently capture and recover toxic chemical vapors (TCVs) from simulated industrial gas streams. The system was characterized for adsorption by ACFC, electrothermal desorption, and cryogenic condensation to separate acetone and methyl ethyl ketone from gas streams. Adsorption dynamics are numerically modeled to predict system characteristics during scale-up and optimization of the process in the future. The model requires diffusivities of TCVs into an activated-carbon fiber (ACF) as an input. Effective diffusivities of TCVs into ACFs were modeled as a function of temperature, concentration, and pore size distribution. Effective diffusivities for acetone at 65 ??C and 30-60 ppmv were measured using a chromatography method. The energy factor for surface diffusion was determined from comparison between the experimental and modeled effective diffusivities. The modeled effective diffusivities were used in a dispersive computational model to predict mass transfer zones of TCVs in fixed beds of ACFC under realistic conditions for industrial applications.

  17. A hybrid transport-diffusion method for Monte Carlo radiative-transfer simulations

    SciTech Connect

    Densmore, Jeffery D. . E-mail: jdd@lanl.gov; Urbatsch, Todd J. . E-mail: tmonster@lanl.gov; Evans, Thomas M. . E-mail: tme@lanl.gov; Buksas, Michael W. . E-mail: mwbuksas@lanl.gov

    2007-03-20

    Discrete Diffusion Monte Carlo (DDMC) is a technique for increasing the efficiency of Monte Carlo particle-transport simulations in diffusive media. If standard Monte Carlo is used in such media, particle histories will consist of many small steps, resulting in a computationally expensive calculation. In DDMC, particles take discrete steps between spatial cells according to a discretized diffusion equation. Each discrete step replaces many small Monte Carlo steps, thus increasing the efficiency of the simulation. In addition, given that DDMC is based on a diffusion equation, it should produce accurate solutions if used judiciously. In practice, DDMC is combined with standard Monte Carlo to form a hybrid transport-diffusion method that can accurately simulate problems with both diffusive and non-diffusive regions. In this paper, we extend previously developed DDMC techniques in several ways that improve the accuracy and utility of DDMC for nonlinear, time-dependent, radiative-transfer calculations. The use of DDMC in these types of problems is advantageous since, due to the underlying linearizations, optically thick regions appear to be diffusive. First, we employ a diffusion equation that is discretized in space but is continuous in time. Not only is this methodology theoretically more accurate than temporally discretized DDMC techniques, but it also has the benefit that a particle's time is always known. Thus, there is no ambiguity regarding what time to assign a particle that leaves an optically thick region (where DDMC is used) and begins transporting by standard Monte Carlo in an optically thin region. Also, we treat the interface between optically thick and optically thin regions with an improved method, based on the asymptotic diffusion-limit boundary condition, that can produce accurate results regardless of the angular distribution of the incident Monte Carlo particles. Finally, we develop a technique for estimating radiation momentum deposition during the

  18. Close binary systems before and after mass transfer. III - Spectroscopic binaries

    NASA Astrophysics Data System (ADS)

    Vansina, F.; De Greve, J. P.

    1982-10-01

    A method is presented, for the computation of absolute dimensions from spectroscopic data on binary systems, which has been adapted for use with the 7th Catalogue of Batten et al. (1978) and takes into account several results of close binary evolution, with emphasis on the phase of slow mass transfer during a case B mass transfer. Among the unevolved systems, the mass transfer case B is found to be the most abundant type of interaction. In the set of evolving systems, a subset of 18 interacting systems was found with mass ratio near unity, the first star being the mass loser as well as the brightest.

  19. Low energy emulsion-based fermentation enabling accelerated methane mass transfer and growth of poly(3-hydroxybutyrate)-accumulating methanotrophs.

    PubMed

    Myung, Jaewook; Kim, Minkyu; Pan, Ming; Criddle, Craig S; Tang, Sindy K Y

    2016-05-01

    Methane is a low-cost feedstock for the production of polyhydroxyalkanoate biopolymers, but methanotroph fermentations are limited by the low solubility of methane in water. To enhance mass transfer of methane to water, vigorous mixing or agitation is typically used, which inevitably increases power demand and operational costs. This work presents a method for accelerating methane mass transfer without agitation by growing methanotrophs in water-in-oil emulsions, where the oil has a higher solubility for methane than water does. In systems without agitation, the growth rate of methanotrophs in emulsions is five to six times that of methanotrophs in the medium-alone incubations. Within seven days, cells within the emulsions accumulate up to 67 times more P3HB than cells in the medium-alone incubations. This is achieved due to the increased interfacial area of the aqueous phase, and accelerated methane diffusion through the oil phase. PMID:26896714

  20. THE EFFECT OF MAGNETIC FIELDS AND AMBIPOLAR DIFFUSION ON CORE MASS FUNCTIONS

    SciTech Connect

    Bailey, Nicole D.; Basu, Shantanu E-mail: basu@uwo.ca

    2013-03-20

    Linear analysis of the formation of protostellar cores in planar magnetic interstellar clouds yields information about length scales involved in star formation. Combining these length scales with various distributions of other environmental variables (i.e., column density and mass-to-flux ratio) and applying Monte Carlo methods allow us to produce synthetic core mass functions (CMFs) for different environmental conditions. Our analysis shows that the shape of the CMF is directly dependent on the physical conditions of the cloud. Specifically, magnetic fields act to broaden the mass function and develop a high-mass tail while ambipolar diffusion will truncate this high-mass tail. In addition, we analyze the effect of small number statistics on the shape and high-mass slope of the synthetic CMFs. We find that observed CMFs are severely statistically limited, which has a profound effect on the derived slope for the high-mass tail.

  1. Imaging of mass transfer process using artificial fringe deflection

    NASA Astrophysics Data System (ADS)

    Chhaniwal, Vani K.; Narayanamurthy, Chittur S.; Anand, Arun

    2014-07-01

    A noninterferometric technique used to measure the diffusion coefficients of transparent liquid solutions is reported. This technique uses a white light source and a diffusion cell, with an artificially developed fringe pattern of dark and white stripes at its entrance. As the diffusion process takes place in the cell, the light passing through this nonuniform refractive index medium will bend toward the higher refractive index region, which results in a fringe shift. This shift in the fringe pattern at different times is recorded in a personal computer (PC) using a CCD camera for the calculation of diffusion coefficients. The fringe shift is calculated after skeletonization and linear fit of the captured fringe system. The diffusion coefficient of different concentrations of ammonium dihydrogen phosphate was determined using the proposed technique and the measured values lay within 1% of the reported values. Detailed theoretical and experimental analyses with a comparison of other existing results are discussed.

  2. Efficient Exciton Diffusion and Resonance-Energy Transfer in Multilayered Organic Epitaxial Nanofibers

    PubMed Central

    2015-01-01

    Multilayered epitaxial nanofibers are exemplary model systems for the study of exciton dynamics and lasing in organic materials because of their well-defined morphology, high luminescence efficiencies, and color tunability. We use temperature-dependent continuous wave and picosecond photoluminescence (PL) spectroscopy to quantify exciton diffusion and resonance-energy transfer (RET) processes in multilayered nanofibers consisting of alternating layers of para-hexaphenyl (p6P) and α-sexithiophene (6T) serving as exciton donor and acceptor material, respectively. The high probability for RET processes is confirmed by quantum chemical calculations. The activation energy for exciton diffusion in p6P is determined to be as low as 19 meV, proving p6P epitaxial layers also as a very suitable donor material system. The small activation energy for exciton diffusion of the p6P donor material, the inferred high p6P-to-6T resonance-energy-transfer efficiency, and the observed weak PL temperature dependence of the 6T acceptor material together result in an exceptionally high optical emission performance of this all-organic material system, thus making it well suited, for example, for organic light-emitting devices. PMID:26191119

  3. Aquatic vision and the modulation transfer properties of unlighted and diffusely lighted natural waters.

    PubMed

    Jagger, W S; Muntz, W R

    1993-09-01

    The modulation transfer function (MTF) of well-mixed unlighted and diffusely lighted samples of clear natural waters for path lengths up to 4 m was measured. The measuring conditions simulated the situation for horizontal aquatic vision. In unlighted water, the MTF decreased relatively slowly with increasing path length and spatial frequency up to 150 c/deg. We interpret this as the result of low-angle forward scattering of light from the target. For diffusely lighted water, the MTF fell much more rapidly with path length, but was nearly independent of spatial frequency. Here, scattering of ambient light into the light path contributes an additional veiling glare or path radiance, which is independent of spatial frequency but degrades the MTF strongly with increasing path length. These scattering processes are independent of wavelength in the visible spectrum. The modulation transfer properties of these waters do not preclude high aquatic visual acuity. However, the useful range of high acuity vision in diffusely lighted water is much less than for unlighted water. This places special requirements upon the design of high-acuity aquatic eyes. PMID:8266631

  4. Electrochemical characterization of binderless, recompressed exfoliated graphite electrodes: electron-transfer kinetics and diffusion characteristics.

    PubMed

    Ramesh, P; Sampath, S

    2003-12-15

    Exfoliated graphite (EG) is prepared by the thermal exfoliation of graphite intercalation compounds at different temperatures. Surface and bulk physicochemical properties of EG are followed by spectroscopic and analytical methods and are observed to be a function of exfoliation temperature. EG particles can be recompressed without any binder and used as surface-renewable electrodes. Surface preparation is accomplished by either polishing or roughening the electrode surface using emery sheets. Effects of exfoliation temperature and the surface preparation on the electron-transfer kinetics and on the diffusion characteristics have been followed by electrochemical methods using several benchmark redox systems. It is found that the electron-transfer kinetics and the diffusion of K(4)[Fe(CN)(6)] are affected by the nature of the EG surface while that of iron(II)(1,10-phenanthroline)(3) and cobalt(II)(1,10-phenanthroline)(3) are not affected by the surface preparation. The redox systems are classified into different groups according to their kinetic sensitivity. Diffusion of electroactive species toward the EG electrodes is found to nonlinear. Current-time plots suggest that the recompressed EG electrodes can be modeled as fractals. PMID:14670057

  5. Solutions for Reacting and Nonreacting Viscous Shock Layers with Multicomponent Diffusion and Mass Injection. Ph.D. Thesis - Virginia Polytechnic Inst. and State Univ.

    NASA Technical Reports Server (NTRS)

    Moss, J. N.

    1971-01-01

    Numerical solutions are presented for the viscous shocklayer equations where the chemistry is treated as being either frozen, equilibrium, or nonequilibrium. Also the effects of the diffusion model, surface catalyticity, and mass injection on surface transport and flow parameters are considered. The equilibrium calculations for air species using multicomponent: diffusion provide solutions previously unavailable. The viscous shock-layer equations are solved by using an implicit finite-difference scheme. The flow is treated as a mixture of inert and thermally perfect species. Also the flow is assumed to be in vibrational equilibrium. All calculations are for a 45 deg hyperboloid. The flight conditions are those for various altitudes and velocities in the earth's atmosphere. Data are presented showing the effects of the chemical models; diffusion models; surface catalyticity; and mass injection of air, water, and ablation products on heat transfer; skin friction; shock stand-off distance; wall pressure distribution; and tangential velocity, temperature, and species profiles.

  6. In situ studies with membrane diffusion chambers of antibiotic resistance transfer in Escherichia coli.

    PubMed Central

    Altherr, M R; Kasweck, K L

    1982-01-01

    Coliform bacteria were isolated from raw sewage and sewage effluent-receiving waters and tested for their antibiotic susceptibility patterns and their ability to transfer antibiotic resistance to Escherichia coli K-12 C600. An environmental isolate of E. coli (MA527) capable of transferring antibiotic resistance to C600 was mated, both in vitro and in situ, with an antibiotic-sensitive E. coli environmental isolate (MA728). In situ matings were conducted in modified membrane diffusion chambers, in the degritter tank at the Grant Street (Melbourne, Fla.) sewage treatment facility, and in the sewage effluent-receiving waters in Melbourne, Fla. The transfer frequencies in situ were 3.2 x 10(-5) to 1.0 x 10(-6), compared with 1.6 x 10(-4) to 4.4 x 10(-5) observed in vitro. Transfer was shown to occur in raw sewage but was not detected in the effluent-receiving waters. The presence of a 60-megadalton plasmid species in both donor and transconjugants, but not in the recipients, provided physical evidence for the transfer of antibiotic resistance in situ. Images PMID:6756306

  7. Diffusive transfer between two intensely interacting cells with limited surface kinetics

    PubMed Central

    Fahmy, T. M.

    2012-01-01

    The diffusive transfer, or paracrine delivery, of chemical factors during the interaction of an emitting cell and a receiving cell is a ubiquitous cellular process that facilitates information exchange between the cells an/or to bystander cells. In the cellular immune response this exchange governs the magnitude and breadth of killing of cellular targets, inflammation or tolerance. Paracrine delivery is examined here by solving the the steady-state diffusion equation for the concentration field surrounding two intensely interacting, equi-sized cells on which surface kinetics limits the rates of factor emission and absorption. These chemical factors may be cytokines, such as Interlukins and Interferons, but the results are presented in a generic form so as to be applicable to any chemical factor and/or cell-type interaction. In addition to providing overall transfer rates and transfer efficiencies, the results also indicate that when the receiving cell is naïve, with few factor receptors on its surface, there may be a significant accumulation of factor in the synaptic region between the cells with a consequent release of factor to the medium where it can signal bystander cells. This factor accumulation may play a critical role in activating a naïve receiving cell. As the receiving cell activates and becomes more absorbent, the factor accumulation diminishes, as does potential bystander signaling. PMID:22485051

  8. Reaction-diffusion systems in natural sciences and new technology transfer

    NASA Astrophysics Data System (ADS)

    Keller, André A.

    2012-12-01

    Diffusion mechanisms in natural sciences and innovation management involve partial differential equations (PDEs). This is due to their spatio-temporal dimensions. Functional semi-discretized PDEs (with lattice spatial structures or time delays) may be even more adapted to real world problems. In the modeling process, PDEs can also formalize behaviors, such as the logistic growth of populations with migration, and the adopters’ dynamics of new products in innovation models. In biology, these events are related to variations in the environment, population densities and overcrowding, migration and spreading of humans, animals, plants and other cells and organisms. In chemical reactions, molecules of different species interact locally and diffuse. In the management of new technologies, the diffusion processes of innovations in the marketplace (e.g., the mobile phone) are a major subject. These innovation diffusion models refer mainly to epidemic models. This contribution introduces that modeling process by using PDEs and reviews the essential features of the dynamics and control in biological, chemical and new technology transfer. This paper is essentially user-oriented with basic nonlinear evolution equations, delay PDEs, several analytical and numerical methods for solving, different solutions, and with the use of mathematical packages, notebooks and codes. The computations are carried out by using the software Wolfram Mathematica®7, and C++ codes.

  9. Simulation results for a multirate mass transfer modell for immiscible displacement of two fluids in highly heterogeneous porous media

    NASA Astrophysics Data System (ADS)

    Tecklenburg, Jan; Neuweiler, Insa; Dentz, Marco; Carrera, Jesus; Geiger, Sebastian

    2013-04-01

    Flow processes in geotechnical applications do often take place in highly heterogeneous porous media, such as fractured rock. Since, in this type of media, classical modelling approaches are problematic, flow and transport is often modelled using multi-continua approaches. From such approaches, multirate mass transfer models (mrmt) can be derived to describe the flow and transport in the "fast" or mobile zone of the medium. The porous media is then modeled with one mobile zone and multiple immobile zones, where the immobile zones are connected to the mobile zone by single rate mass transfer. We proceed from a mrmt model for immiscible displacement of two fluids, where the Buckley-Leverett equation is expanded by a sink-source-term which is nonlocal in time. This sink-source-term models exchange with an immobile zone with mass transfer driven by capillary diffusion. This nonlinear diffusive mass transfer can be approximated for particular imbibition or drainage cases by a linear process. We present a numerical scheme for this model together with simulation results for a single fracture test case. We solve the mrmt model with the finite volume method and explicit time integration. The sink-source-term is transformed to multiple single rate mass transfer processes, as shown by Carrera et. al. (1998), to make it local in time. With numerical simulations we studied immiscible displacement in a single fracture test case. To do this we calculated the flow parameters using information about the geometry and the integral solution for two phase flow by McWorther and Sunnada (1990). Comparision to the results of the full two dimensional two phase flow model by Flemisch et. al. (2011) show good similarities of the saturation breakthrough curves. Carrera, J., Sanchez-Vila, X., Benet, I., Medina, A., Galarza, G., and Guimera, J.: On matrix diffusion: formulations, solution methods and qualitative effects, Hydrogeology Journal, 6, 178-190, 1998. Flemisch, B., Darcis, M

  10. Bilayer mass transport model for determining swelling and diffusion in coated, ultrathin membranes.

    PubMed

    Nadermann, Nichole K; Chan, Edwin P; Stafford, Christopher M

    2015-02-18

    Water transport and swelling properties of an ultrathin, selective polyamide layer with a hydrophilic polymer coating, i.e., a polymer bilayer, are studied using quartz crystal microbalance with dissipation (QCM-D). Specifically, QCM-D is used to measure the dynamic and equilibrium change in mass in a series of differential sorption experiments to determine the dependence of the apparent diffusion coefficient and equilibrium swelling of the bilayer as a function of the water vapor activity. To determine transport properties specific to the polyamide layer, sorption kinetics of the bilayer was modeled with a bilayer mass transport model. The swelling and water diffusion coefficients are interpreted according to the Painter-Shenoy polymer network swelling model and the solution-diffusion model, respectively. PMID:25597964

  11. Nitrogen mass transfer models for plasma-based low-energy ion implantation

    SciTech Connect

    Zheng, Bocong; Wang, Kesheng; Zhang, Zhipeng; Che, Honglong; Lei, Mingkai

    2015-03-15

    The nitrogen mass transfer process in plasma-based low-energy ion implantation (PBLEII) is theoretically and experimentally studied in order to explore the process mechanism of PBLEII and therefore to optimize the apparatus design and the process conditions. An electron cyclotron resonance (ECR) microwave discharge generates the nitrogen plasma with a high density of 10{sup 11}–10{sup 12} ions/cm{sup 3}, which diffuses downstream to the process chamber along the divergent magnetic field. The nitrogen ions in the plasma implant into the surface and transport to the matrix of an austenitic stainless steel under the low negative pulsed bias of −2 kV at a process temperature of 400 °C. A global plasma model is used to simulate the ECR microwave plasma discharge for a range of working pressures and microwave powers. The fluid models are adopted to calculate the plasma downstream diffusion, the sheath expansion and the low-energy ion implantation on the surface. A nonlinear kinetic discrete model is established to describe the nitrogen transport in the austenitic stainless steel and the results are compared with the experimental measurements. Under an average implantation current density of 0.3–0.6 mA/cm{sup 2}, the surface nitrogen concentration in the range from 18.5 to 29 at. % is a critical factor for the nitrogen transport in the AISI 304 austenitic stainless steel by PBLEII, which accelerates the implanted nitrogen diffusion inward up to 6–12 μm during a nitriding time of 4 h.

  12. Impact of internal transport on the convective mass transfer from a droplet into a submerging falling film

    NASA Astrophysics Data System (ADS)

    Landel, Julien R.; Thomas, Amalia; McEvoy, Harry; Dalziel, Stuart B.

    2015-11-01

    We investigate the convective mass transfer of dilute passive tracers contained in small viscous drops into a submerging falling film. This problem has applications in industrial cleaning, domestic dishwashers, and decontamination of hazardous material. The film Peclet number is very high, whereas the drop Peclet number varies from 0.1 to 1. The characteristic transport time in the drop is much larger than in the film. We model the mass transfer using an analogy with Newton's law of cooling. This empirical model is supported by an analytical model solving the quasi-steady two-dimensional advection-diffusion equation in the film that is coupled with a time-dependent one-dimensional diffusion equation in the drop. We find excellent agreement between our experimental data and the two models, which predict an exponential decrease in time of the drop concentration. The transport characteristic time is related to the drop diffusion time scale, as diffusion within the drop is the limiting process. Our theoretical model not only predicts the well-known relationship between the Sherwood number and the external Reynolds number in the case of a well-mixed drop Sh ~ Re1/3, it also predicts a correction in the case of a non-uniform drop concentration. The correction depends on Re, the film Schmidt number, the drop aspect ratio and the diffusivity ratio between the two phases. This prediction is in good agreement with experimental data. This material is based upon work supported by the Defense Threat Reduction Agency under Contract No. HDTRA1-12-D-0003-0001.

  13. The influence of state-to-state kinetics on diffusion and heat transfer behind shock waves

    SciTech Connect

    Kunova, O.; Kustova, E.; Mekhonoshina, M.; Nagnibeda, E.

    2014-12-09

    In the paper, the influence of vibrational and chemical kinetics on heat transfer and diffusion in hypersonic flows of N{sub 2}/N mixture in the relaxation zone behind shock waves is studied on the basis of the state-to-state kinetic theory approach. The results of calculations of vibrational level populations ni, gas temperature T, total energy flux q, diffusion velocities of molecules at different vibrational states V{sub i} and atoms V{sub a} in the relaxation zone behind a shock front are presented for the free stream Mach number M = 10, 15. The contribution of different dissipative processes to the total energy flux is estimated for various flow conditions. The impact of non-equilibrium vibrational distributions in the free stream on molecular level populations and transport properties in the relaxation zone is shown.

  14. Fick's second law transformed: one path to cloaking in mass diffusion

    PubMed Central

    Guenneau, S.; Puvirajesinghe, T. M.

    2013-01-01

    Here, we adapt the concept of transformational thermodynamics, whereby the flux of temperature is controlled via anisotropic heterogeneous diffusivity, for the diffusion and transport of mass concentration. The n-dimensional, time-dependent, anisotropic heterogeneous Fick's equation is considered, which is a parabolic partial differential equation also applicable to heat diffusion, when convection occurs, for example, in fluids. This theory is illustrated with finite-element computations for a liposome particle surrounded by a cylindrical multi-layered cloak in a water-based environment, and for a spherical multi-layered cloak consisting of layers of fluid with an isotropic homogeneous diffusivity, deduced from an effective medium approach. Initial potential applications could be sought in bioengineering. PMID:23536540

  15. Charge transfer fluorescence and 34 nm exciton diffusion length in polymers with electron acceptor end traps

    DOE PAGESBeta

    Zaikowski, Lori; Mauro, Gina; Bird, Matthew; Karten, Brianne; Asaoka, Sadayuki; Wu, Qin; Cook, Andrew R.; Miller, John R.

    2014-12-22

    Photoexcitation of conjugated poly-2,7-(9,9-dihexylfluorene) polyfluorenes with naphthylimide (NI) and anthraquinone (AQ) electron-acceptor end traps produces excitons that form charge transfer states at the end traps. Intramolecular singlet exciton transport to end traps was examined by steady state fluorescence for polyfluorenes of 17 to 127 repeat units in chloroform, dimethylformamide (DMF), tetrahydrofuran (THF), and p-xylene. End traps capture excitons and form charge transfer (CT) states at all polymer lengths and in all solvents. The CT nature of the end-trapped states is confirmed by their fluorescence spectra, solvent and trap group dependence and DFT descriptions. Quantum yields of CT fluorescence are asmore » large as 46%. This strong CT emission is understood in terms of intensity borrowing. Energies of the CT states from onsets of the fluorescence spectra give the depths of the traps which vary with solvent polarity. For NI end traps the trap depths are 0.06 (p-xylene), 0.13 (THF) and 0.19 eV (CHCl3). For AQ, CT fluorescence could be observed only in p-xylene where the trap depth is 0.27 eV. Quantum yields, emission energies, charge transfer energies, solvent reorganization and vibrational energies were calculated. Fluorescence measurements on chains >100 repeat units indicate that end traps capture ~50% of the excitons, and that the exciton diffusion length LD =34 nm, which is much larger than diffusion lengths reported in polymer films or than previously known for diffusion along isolated chains. As a result, the efficiency of exciton capture depends on chain length, but not on trap depth, solvent polarity or which trap group is present.« less

  16. Charge transfer fluorescence and 34 nm exciton diffusion length in polymers with electron acceptor end traps

    SciTech Connect

    Zaikowski, Lori; Mauro, Gina; Bird, Matthew; Karten, Brianne; Asaoka, Sadayuki; Wu, Qin; Cook, Andrew R.; Miller, John R.

    2014-12-22

    Photoexcitation of conjugated poly-2,7-(9,9-dihexylfluorene) polyfluorenes with naphthylimide (NI) and anthraquinone (AQ) electron-acceptor end traps produces excitons that form charge transfer states at the end traps. Intramolecular singlet exciton transport to end traps was examined by steady state fluorescence for polyfluorenes of 17 to 127 repeat units in chloroform, dimethylformamide (DMF), tetrahydrofuran (THF), and p-xylene. End traps capture excitons and form charge transfer (CT) states at all polymer lengths and in all solvents. The CT nature of the end-trapped states is confirmed by their fluorescence spectra, solvent and trap group dependence and DFT descriptions. Quantum yields of CT fluorescence are as large as 46%. This strong CT emission is understood in terms of intensity borrowing. Energies of the CT states from onsets of the fluorescence spectra give the depths of the traps which vary with solvent polarity. For NI end traps the trap depths are 0.06 (p-xylene), 0.13 (THF) and 0.19 eV (CHCl3). For AQ, CT fluorescence could be observed only in p-xylene where the trap depth is 0.27 eV. Quantum yields, emission energies, charge transfer energies, solvent reorganization and vibrational energies were calculated. Fluorescence measurements on chains >100 repeat units indicate that end traps capture ~50% of the excitons, and that the exciton diffusion length LD =34 nm, which is much larger than diffusion lengths reported in polymer films or than previously known for diffusion along isolated chains. As a result, the efficiency of exciton capture depends on chain length, but not on trap depth, solvent polarity or which trap group is present.

  17. Charge, mass and heat transfer interactions in solid oxide fuel cells operated with different fuel gases-A sensitivity analysis

    NASA Astrophysics Data System (ADS)

    Nagel, Florian P.; Schildhauer, Tilman J.; Biollaz, Serge M. A.; Stucki, Samuel

    The interaction between charge, heat and mass transfer occurring in SOFCs is investigated applying a finite-volume-based SOFC model. The strong interactions are the consequence of the high degree of integration of different processes (chemical/electrochemical reactions, diffusion, heat and mass transfer) within SOFCs. The understanding of these interactions is a key for the future development and application of SOFCs. The investigation was conducted by means of a sensitivity analysis for two different fuel gases, where one gas features a considerable amount of methane inducing steam reforming reactions as additional disturbance factor in the energy and mass balance system of SOFCs. In order to isolate the impact of the varied model parameters and the according changes in the interactions of charge, mass and heat transfer from side effects, the sensitivity analysis was conducted at constant fuel utilization. It was found that the impact of different fuel gases on the operational conditions of SOFCs dominates geometrical and material-induced phenomena. The power output was most affected by the fuel, followed by the values for the activation polarization activation energy that reflects the employed electrode catalysts activity.

  18. Structural charge transfer in the aluminophosphate molecular sieves by diffuse reflectance spectroscopy

    NASA Astrophysics Data System (ADS)

    Zanjanchi, M. A.; Rashidi, M. K.

    1999-05-01

    Influence of water adsorption in AlPO-5, SAPO-5, AlPO-11 and SAPO-11 has been studied with UV diffuse reflectance spectroscopy. The observed UV absorption spectra in the as-synthesized, template free and hydrated materials are related to the charge transfer processes between aluminum and oxygen atoms of the aluminophosphate and water molecules. As-synthesised materials show two distinct and well-defined bands at about 220 and 260-280 nm correlated to framework aluminum and organic templates, respectively. Upon calcination, the band of occluded template disappears and the band assigned to the framework aluminum shifts at about 240 nm. When the calcined samples are completely hydrated, broadening of the aluminum charge transfer band is observed. This is due to coordination of water molecules to the part of the framework aluminum. Broadening occurs more in AlPO-5 possibly because of higher water capacity and homogenity with respect to SAPO-5.

  19. Investigation of Fundamental Physical Properties of a Polydimethylsiloxane (PDMS) Membrane using a Proton Transfer Reaction-Mass Spectrometry (PRTMS)

    SciTech Connect

    Boscaini, Elena; Alexander, M. Lizabeth; Prazeller, Peter; Mark, T. D.

    2004-12-15

    A membrane introduction proton transfer reaction mass spectrometry (MI-PTRMS) has been employed for the characterisation of a polydimethylsiloxane (PDMS) membrane. For this purpose the diffusion and partition coefficients (which serves as a measure for solubility) have been determined experimentally for different classes of chemical compounds both non-polar and polar species, i.e. aromatics, alcohols, ketones. It turned out that not only polar compounds exhibit strong interaction with a hydrophobic membrane such as the PDMS, but also non polar compounds as trimethylbenzene or propylbenzene which bear a relevant number of methyl groups or an alkyl chain show strong interaction with a PDMS membrane. Stronger interaction analyte-membrane leads to a slower diffusion coefficient and larger partition coefficient. The effect of the temperature on the diffusion coefficient and partition coefficient is also investigated. At higher temperature diffusion becomes faster and solubility lower. Permeability is calculated from diffusion and partition coefficients and activation energy are derived from corresponding Arrhenius plots. The MI-PTRMS system shows detection limits in the order of tens of pptv and it’s linear over five orders of magnitude.

  20. The effect of transpiration on coupled heat and mass transfer in mixed convection over a vertical plate embedded in a saturated porous medium

    SciTech Connect

    Yih, K.A.

    1997-03-01

    Effect of transpiration velocity on the heat and mass transfer characteristics of mixed convection about a permeable vertical plate embedded in a saturated porous medium under the coupled effects of thermal and mass diffusion is numerically analyzed. The plate is maintained at a uniform temperature and species concentration with constant transpiration velocity. The transformed governing equations are solved by Keller box method. Numerical results for the local Nusselt number and local Sherwood number are presented. In general, it has been found for thermally assisted flow that the local surface heat and mass transfer rates increase owing to suction of fluid. This trend reversed for blowing of fluid. It is apparent that the Lewis number has a pronounced effect on the local Sherwood number than it does on the local Nusselt number. Increasing the Lewis number decreases (increases) the local heat (mass) transfer rate.

  1. Impact of kinetic mass transfer on free convection in a porous medium

    NASA Astrophysics Data System (ADS)

    Lu, Chunhui; Shi, Liangsheng; Chen, Yiming; Xie, Yueqing; Simmons, Craig T.

    2016-05-01

    We investigate kinetic mass transfer effects on unstable density-driven flow and transport processes by numerical simulations of a modified Elder problem. The first-order dual-domain mass transfer model coupled with a variable-density-flow model is employed to describe transport behavior in porous media. Results show that in comparison to the no-mass-transfer case, a higher degree of instability and more unstable system is developed in the mass transfer case due to the reduced effective porosity and correspondingly a larger Rayleigh number (assuming permeability is independent on the mobile porosity). Given a constant total porosity, the magnitude of capacity ratio (i.e., immobile porosity/mobile porosity) controls the macroscopic plume profile in the mobile domain, while the magnitude of mass transfer timescale (i.e., the reciprocal of the mass transfer rate coefficient) dominates its evolution rate. The magnitude of capacity ratio plays an important role on the mechanism driving the mass flux into the aquifer system. Specifically, for a small capacity ratio, solute loading is dominated by the density-driven transport, while with increasing capacity ratio local mass transfer dominated solute loading may occur at later times. At significantly large times, however, both mechanisms contribute comparably to solute loading. Sherwood Number could be a nonmonotonic function of mass transfer timescale due to complicated interactions of solute between source zone, mobile zone and immobile zone in the top boundary layer, resulting in accordingly a similar behavior of the total mass. The initial assessment provides important insights into unstable density-driven flow and transport in the presence of kinetic mass transfer.

  2. Effect of NAPL Source Morphology on Mass Transfer in the Vadose Zone.

    PubMed

    Petri, Benjamin G; Fučík, Radek; Illangasekare, Tissa H; Smits, Kathleen M; Christ, John A; Sakaki, Toshihiro; Sauck, Carolyn C

    2015-01-01

    The generation of vapor-phase contaminant plumes within the vadose zone is of interest for contaminated site management. Therefore, it is important to understand vapor sources such as non-aqueous-phase liquids (NAPLs) and processes that govern their volatilization. The distribution of NAPL, gas, and water phases within a source zone is expected to influence the rate of volatilization. However, the effect of this distribution morphology on volatilization has not been thoroughly quantified. Because field quantification of NAPL volatilization is often infeasible, a controlled laboratory experiment was conducted in a two-dimensional tank (28 cm × 15.5 cm × 2.5 cm) with water-wet sandy media and an emplaced trichloroethylene (TCE) source. The source was emplaced in two configurations to represent morphologies encountered in field settings: (1) NAPL pools directly exposed to the air phase and (2) NAPLs trapped in water-saturated zones that were occluded from the air phase. Airflow was passed through the tank and effluent concentrations of TCE were quantified. Models were used to analyze results, which indicated that mass transfer from directly exposed NAPL was fast and controlled by advective-dispersive-diffusive transport in the gas phase. However, sources occluded by pore water showed strong rate limitations and slower effective mass transfer. This difference is explained by diffusional resistance within the aqueous phase. Results demonstrate that vapor generation rates from a NAPL source will be influenced by the soil water content distribution within the source. The implications of the NAPL morphology on volatilization in the context of a dynamic water table or climate are discussed. PMID:25535651

  3. Radiation Heat Transfer Between Diffuse-Gray Surfaces Using Higher Order Finite Elements

    NASA Technical Reports Server (NTRS)

    Gould, Dana C.

    2000-01-01

    This paper presents recent work on developing methods for analyzing radiation heat transfer between diffuse-gray surfaces using p-version finite elements. The work was motivated by a thermal analysis of a High Speed Civil Transport (HSCT) wing structure which showed the importance of radiation heat transfer throughout the structure. The analysis also showed that refining the finite element mesh to accurately capture the temperature distribution on the internal structure led to very large meshes with unacceptably long execution times. Traditional methods for calculating surface-to-surface radiation are based on assumptions that are not appropriate for p-version finite elements. Two methods for determining internal radiation heat transfer are developed for one and two-dimensional p-version finite elements. In the first method, higher-order elements are divided into a number of sub-elements. Traditional methods are used to determine radiation heat flux along each sub-element and then mapped back to the parent element. In the second method, the radiation heat transfer equations are numerically integrated over the higher-order element. Comparisons with analytical solutions show that the integration scheme is generally more accurate than the sub-element method. Comparison to results from traditional finite elements shows that significant reduction in the number of elements in the mesh is possible using higher-order (p-version) finite elements.

  4. Effects of reservoir heterogeneity on scaling of effective mass transfer coefficient for solute transport.

    PubMed

    Leung, Juliana Y; Srinivasan, Sanjay

    2016-09-01

    Modeling transport process at large scale requires proper scale-up of subsurface heterogeneity and an understanding of its interaction with the underlying transport mechanisms. A technique based on volume averaging is applied to quantitatively assess the scaling characteristics of effective mass transfer coefficient in heterogeneous reservoir models. The effective mass transfer coefficient represents the combined contribution from diffusion and dispersion to the transport of non-reactive solute particles within a fluid phase. Although treatment of transport problems with the volume averaging technique has been published in the past, application to geological systems exhibiting realistic spatial variability remains a challenge. Previously, the authors developed a new procedure where results from a fine-scale numerical flow simulation reflecting the full physics of the transport process albeit over a sub-volume of the reservoir are integrated with the volume averaging technique to provide effective description of transport properties. The procedure is extended such that spatial averaging is performed at the local-heterogeneity scale. In this paper, the transport of a passive (non-reactive) solute is simulated on multiple reservoir models exhibiting different patterns of heterogeneities, and the scaling behavior of effective mass transfer coefficient (Keff) is examined and compared. One such set of models exhibit power-law (fractal) characteristics, and the variability of dispersion and Keff with scale is in good agreement with analytical expressions described in the literature. This work offers an insight into the impacts of heterogeneity on the scaling of effective transport parameters. A key finding is that spatial heterogeneity models with similar univariate and bivariate statistics may exhibit different scaling characteristics because of the influence of higher order statistics. More mixing is observed in the channelized models with higher-order continuity. It

  5. Effects of reservoir heterogeneity on scaling of effective mass transfer coefficient for solute transport

    NASA Astrophysics Data System (ADS)

    Leung, Juliana Y.; Srinivasan, Sanjay

    2016-09-01

    Modeling transport process at large scale requires proper scale-up of subsurface heterogeneity and an understanding of its interaction with the underlying transport mechanisms. A technique based on volume averaging is applied to quantitatively assess the scaling characteristics of effective mass transfer coefficient in heterogeneous reservoir models. The effective mass transfer coefficient represents the combined contribution from diffusion and dispersion to the transport of non-reactive solute particles within a fluid phase. Although treatment of transport problems with the volume averaging technique has been published in the past, application to geological systems exhibiting realistic spatial variability remains a challenge. Previously, the authors developed a new procedure where results from a fine-scale numerical flow simulation reflecting the full physics of the transport process albeit over a sub-volume of the reservoir are integrated with the volume averaging technique to provide effective description of transport properties. The procedure is extended such that spatial averaging is performed at the local-heterogeneity scale. In this paper, the transport of a passive (non-reactive) solute is simulated on multiple reservoir models exhibiting different patterns of heterogeneities, and the scaling behavior of effective mass transfer coefficient (Keff) is examined and compared. One such set of models exhibit power-law (fractal) characteristics, and the variability of dispersion and Keff with scale is in good agreement with analytical expressions described in the literature. This work offers an insight into the impacts of heterogeneity on the scaling of effective transport parameters. A key finding is that spatial heterogeneity models with similar univariate and bivariate statistics may exhibit different scaling characteristics because of the influence of higher order statistics. More mixing is observed in the channelized models with higher-order continuity. It

  6. Effects of diffusion on energy transfer in solution using a microsecond decay time rhenium metal ligand complex as the donor

    NASA Astrophysics Data System (ADS)

    Kuśba, Józef; Piszczek, Grzegorz; Gryczynski, Ignacy; Johnson, Michael L.; Lakowicz, Joseph R.

    2000-03-01

    We used resonance energy transfer and frequency-domain fluorometry to measure slow donor to acceptor diffusion in viscous media. The frequency-domain RET data were analyzed using a new numerical algorithm for predicting the donor intensity decay in the presence of diffusion occurring within the donor decay time. By the use of a rhenium metal-ligand complex as a microsecond decay time donor we were able to measure mutual donor-to-acceptor diffusion coefficients as low as 2×10 -8 cm 2/s. The availability of microsecond decay time luminophores and appropriate theory suggests the use of diffusion-enhanced energy transfer for measurement of diffusive processes and structural dynamics in biological systems.

  7. Study of dynamic structure and heat and mass transfer of a vertical ceramic tiles dryer using CFD simulations

    NASA Astrophysics Data System (ADS)

    Kriaa, Wassim; Bejaoui, Salma; Mhiri, Hatem; Le Palec, Georges; Bournot, Philippe

    2014-02-01

    In this study, we developed a two-dimensional Computational Fluid Dynamics (CFD) model to simulate dynamic structure and heat and mass transfer of a vertical ceramic tiles dryer (EVA 702). The carrier's motion imposed the choice of a dynamic mesh based on two methods: "spring based smoothing" and "local remeshing". The dryer airflow is considered as turbulent ( Re = 1.09 × 105 at the dryer inlet), therefore the Re-Normalization Group model with Enhanced Wall Treatment was used as a turbulence model. The resolution of the governing equation was performed with Fluent 6.3 whose capacities do not allow the direct resolution of drying problems. Thus, a user defined scalar equation was inserted in the CFD code to model moisture content diffusion into tiles. User-defined functions were implemented to define carriers' motion, thermo-physical properties… etc. We adopted also a "two-step" simulation method: in the first step, we follow the heat transfer coefficient evolution (Hc). In the second step, we determine the mass transfer coefficient (Hm) and the features fields of drying air and ceramic tiles. The found results in mixed convection mode (Fr = 5.39 at the dryer inlet) were used to describe dynamic and thermal fields of airflow and heat and mass transfer close to the ceramic tiles. The response of ceramic tiles to heat and mass transfer was studied based on Biot numbers. The evolutions of averages temperature and moisture content of ceramic tiles were analyzed. Lastly, comparison between experimental and numerical results showed a good agreement.

  8. Ballistic vs. diffusive heat transfer across nanoscopic films of layered crystals

    SciTech Connect

    Shen, Meng; Keblinski, Pawel

    2014-04-14

    We use non-equilibrium molecular dynamics to study the heat transfer mechanism across sandwich interfacial structures of Si/n-atomic-layers/Si, with 1 ≤ n ≤ 20 and atomic layers composed of WSe{sub 2} and/or graphene. In the case of WSe{sub 2} sheets, we observe that the thermal resistance of the sandwich structure is increasing almost linearly with the number of WSe{sub 2} sheets, n, indicating a diffusive phonon transport mechanism. By contrast in the case of n graphene layers, the interfacial thermal resistance is more or less independent on the number of layers for 1 ≤ n ≤ 10, and is associated with ballistic phonon transport mechanism. We attribute the diffusive heat transfer mechanism across WSe{sub 2} sheets to abundant low frequency and low group velocity optical modes that carry most of the heat across the interface. By contrast, in graphene, acoustic modes dominate the thermal transport across the interface and render a ballistic heat flow mechanism.

  9. The Transfer and Diffusion of New Technologies: A Review of the Economics Literature

    SciTech Connect

    Curlee, T.R.

    1989-01-01

    This report presents a general overview of the economics literature on technological change and focuses particularly on the interface between the public and private sectors in promoting the transfer and diffusion of new technologies. Our ability to transfer and diffuse new technologies is generally recognized as a key to increased productivity in the United States and this country's ability to compete internationally. A great deal of research has been done on technology transfer and diffusion by various disciplines and from numerous perspectives. Unfortunately, the policy implications of those different works are not always consistent. Further, the different disciplines have difficulty in communicating even when addressing the same issues and drawing the same general conclusions. The primary objective of this report is to lessen the chasm among the disciplines with respect to technology transfer and diffusion by summarizing the perspectives presented in the economics literature. The document is intended primarily for an interdisciplinary audience. The discussion begins with an overview of the economics literature on technological change and focuses on what economists commonly refer to as the Schumpeter trilogy--i.e., invention, innovation, and diffusion. Economists typically view technological change to occur in these three distinct steps and have formulated conceptual frameworks that suggest how and why each step in the process of technological change takes place. After defining these three steps, the report presents brief overviews of the seminal conceptual and empirical works in the three areas. Of key concern is an overview of the types of questions historically posed by economists and the degree to which economists have reached a consensus on these questions. The report then abstracts from this larger picture of technological change and focuses specifically on the interface between the public and private sectors. Within this second thrust, the report poses and

  10. Solute mass transfer from near field to far field in a HLWR experiment at real scale.

    NASA Astrophysics Data System (ADS)

    Buil, B.; Peña, J.; Gómez, P.; Garralón, A.; Turrero, M. J.; Sánchez, L.; Durán, J. M.

    2009-04-01

    The FEBEX experiment located in Grimsel (Switzerland) is a 1:1 simulation of a high level waste disposal facility in crystalline rock according to the Spanish concept: two electrical heaters of dimension and weight equivalent to those of the real canisters were installed concentrically with the drift and simulated the thermal effect of the wastes and surrounded by a clay barrier constructed from highly-compacted bentonite blocks. This experiment started in 1996 and the external rim of bentonite is saturated with the granitic water. The difference between the chemical gradients generated by the bentonite porewater and the granitic water made possible the movement of solute into the geosphere. The experiment reproduces in the most realistic conditions, all the processes affecting the radionuclide migration in a HLWR. Two boreholes parallel to the axis of the FEBEX drift were drilled in granite relatively close to the bentonite surface (20 and 60cm) in order to highlight the solute migration mechanisms in crystalline host rock, influenced by the presence of the bentonite buffer and by the geochemical gradients generated at the bentonite/granite interface. After three years of periodic water sampling campaigns in those boreholes, the chemical composition of waters reveal that there is an appreciable increase of Na and Cl concentration in time in the waters sampled from the borehole located at 20cm from the bentonite surface. On the other hand, the Na/Cl ratio in waters is similar to the Na/Cl ratio in the bentonite porewater. For this reason Cl and Na are considered as the main natural tracers indicating the mass transfer process between the bentonite porewater and the granite. A diffusion transport modelling (PHREEQC) was used to describe the mass transfer process. The results show that the Cl and Na concentration in the granitic waters is the result of a diffusive transport from the bentonite to the granite, with a calculated De≈ 5,0E-11 m2/s. These results could

  11. Carbon monoxide mass transfer for syngas fermentation in a stirred tank reactor with dual impeller configurations.

    PubMed

    Ungerman, Andrew J; Heindel, Theodore J

    2007-01-01

    This study compares the power demand and gas-liquid volumetric mass transfer coefficient, kLa, in a stirred tank reactor (STR) (T = 0.211 m) using different impeller designs and schemes in a carbon monoxide-water system, which is applicable to synthesis gas (syngas) fermentation. Eleven different impeller schemes were tested over a range of operating conditions typically associated with the "after large cavity" region (ALC) of a Rushton-type turbine (D/T = 0.35). It is found that the dual Rushton-type impeller scheme exhibits the highest volumetric mass transfer rates for all operating conditions; however, it also displays the lowest mass transfer performance (defined as the volumetric mass transfer coefficient per unit power input) for all conditions due to its high power consumption. Dual impeller schemes with an axial flow impeller as the top impeller show improved mass transfer rates without dramatic increases in power draw. At high gas flow rates, dual impeller schemes with a lower concave impeller have kLa values similar to those of the Rushton-type dual impeller schemes but show improved mass transfer performance. It is believed that the mass transfer performance can be further enhanced for the bottom concave impeller schemes by operating at conditions beyond the ALC region defined for Rushton-type impellers because the concave impeller can handle higher gas flow rates prior to flooding. PMID:17326659

  12. A total internal reflection fluorescence microscopy study of mass diffusion enhancement in water-based alumina nanofluids

    NASA Astrophysics Data System (ADS)

    Veilleux, Jocelyn; Coulombe, Sylvain

    2010-11-01

    Mass diffusion of rhodamine 6G (R6G) in water-based alumina nanofluids is studied by means of total internal reflection fluorescence (TIRF) microscopy. We report a mass diffusivity enhancement that reaches an order of magnitude in a 2 vol % nanofluid when compared to the value in deionized water. Since experiments were performed with positively charged R6G, interfacial complexation between the dye and the nanoparticles was not observed. The effect of local density variations on mass diffusivity measurements is also addressed. An explanation for the enhancement of mass diffusion is presented using arguments based on dispersion, and it is shown that it correctly describes the order of magnitude differences between the thermal conductivity and mass diffusivity enhancements reported in the literature.

  13. Proton transfer reaction-mass spectrometry applications in medical research.

    PubMed

    Herbig, Jens; Amann, Anton

    2009-06-01

    Gathering information about a subject's physiological and pathophysiological condition from the `smell' of breath is an idea that dates back to antiquity. This intriguing concept of non-invasive diagnosis has been revitalized by `exhaled breath analysis' in recent decades. A main driving force was the development of sensitive and versatile gas-chromatographic and mass-spectrometric instruments for trace gas analysis. Ironically, only non-smelling constituents of breath, such as O(2), CO(2), H(2), and NO have so far been included in routine clinical breath analysis. The `smell' of human breath, on the other hand, arises through a combination of volatile organic compounds (VOCs) of which several hundred have been identified to date. Most of these volatiles are systemic and are released in the gas-exchange between blood and air in the alveoli. The concentration of these compounds in the alveolar breath is related to the respective concentrations in blood. Measuring VOCs in exhaled breath allows for screening of disease markers, studying the uptake and effect of medication (pharmacokinetics), or monitoring physiological processes. There is a range of requirements for instruments for the analysis of a complex matrix, such as human breath. Mass-spectrometric techniques are particularly well suited for this task since they offer the possibility of detecting a large variety of interesting compounds. A further requirement is the ability to measure accurately in the concentration range of breath VOCs, i.e. between parts-per-trillion (pptv) and parts-per-million (ppmv) range. In the mid 1990's proton transfer reaction-mass spectrometry (PTR-MS) was developed as a powerful and promising tool for the analysis of VOCs in gaseous media. Soon thereafter these instruments became commercially available to a still growing user community and have now become standard equipment in many fields including environmental research, food and flavour science, as well as life sciences. Their

  14. Physical modeling of liquid/liquid mass transfer in gas stirred ladles

    NASA Astrophysics Data System (ADS)

    Kim, Seon-Hyo; Fruehan, R. J.

    1987-06-01

    Several of the metallurgical reactions occurring in gas stirred steel ladles are controlled by liquid phase mass transfer between the metal and slag. In order to calculate the rate of these reactions, information about the two phase mass transfer parameter is necessary. The mass transfer between two immiscible liquids, oil and water simulating slag and steel, respectively, was measured in a scale model of a ladle. The mass transferred species was thymol which has an equilibrium partition ratio between oil and water similar to that for sulfur between slag and metal. The mass transfer rate was measured as a function of gas flow rate, tuyere position and size, method of injection, oil viscosity, and oil/water volume ratio. In addition, mixing times in the presence of the oil layer and mass transfer coefficient for the dissolution of solid benzoic acid rods were measured. The results show that there are three gas flow rate regimes in which the dependence of mass transfer on gas flow rate is different. At a critical gas flow rate, the oil layer breaks into droplets which are entrained into the water, resulting in an increase in the two phase interfacial area. This critical gas flow rate was found to be a function of tuyere position, oil volume, densities of two phases, and interfacial tension. Two phase mass transfer for a lance and a tuyere was found to be the same for the same stirring energy in low energy regions regardless of lance depth. Mass transfer is faster for a center tuyere as compared to an offcenter tuyere, but mixing times are smaller for the offcenter tuyere. From the results obtained, the optimum stirring conditions for metallurgical reactions are qualitatively discussed.

  15. Fluidic oscillator-mediated microbubble generation to provide cost effective mass transfer and mixing efficiency to the wastewater treatment plants.

    PubMed

    Rehman, Fahad; Medley, Gareth J D; Bandulasena, Hemaka; Zimmerman, William B J

    2015-02-01

    Aeration is one of the most energy intensive processes in the waste water treatment plants and any improvement in it is likely to enhance the overall efficiency of the overall process. In the current study, a fluidic oscillator has been used to produce microbubbles in the order of 100 μm in diameter by oscillating the inlet gas stream to a pair of membrane diffusers. Volumetric mass transfer coefficient was measured for steady state flow and oscillatory flow in the range of 40-100l/min. The highest improvement of 55% was observed at the flow rates of 60, 90 and 100l/min respectively. Standard oxygen transfer rate and efficiency were also calculated. Both standard oxygen transfer rate and efficiency were found to be considerably higher under oscillatory air flow conditions compared to steady state airflow. The bubble size distributions and bubble densities were measured using an acoustic bubble spectrometer and confirmed production of monodisperse bubbles with approximately 100 μm diameters with fluidic oscillation. The higher number density of microbubbles under oscillatory flow indicated the effect of the fluidic oscillation in microbubble production. Visual observations and dissolved oxygen measurements suggested that the bubble cloud generated by the fluidic oscillator was sufficient enough to provide good mixing and to maintain uniform aerobic conditions. Overall, improved mass transfer coefficients, mixing efficiency and energy efficiency of the novel microbubble generation method could offer significant savings to the water treatment plants as well as reduction in the carbon footprint. PMID:25483415

  16. Theory and applications of refractive index-based optical microscopy to measure protein mass transfer in spherical adsorbent particles.

    PubMed

    Bankston, Theresa E; Stone, Melani C; Carta, Giorgio

    2008-04-25

    This work provides the theoretical foundation and a range of practical application examples of a recently developed method to measure protein mass transfer in adsorbent particles using refractive index-based optical microscopy. A ray-theoretic approach is first used to predict the behavior of light traveling through a particle during transient protein adsorption. When the protein concentration gradient in the particle is sharp, resulting in a steep refractive index gradient, the rays bend and intersect, thereby concentrating light in a sharp ring that marks the position of the adsorption front. This behavior is observed when mass transfer is dominated by pore diffusion and the adsorption isotherm is highly favorable. Applications to protein cation-exchange, hydrophobic interaction, and affinity adsorption are then considered using, as examples, the three commercial, agarose-based stationary phases SP-Sepharose-FF, Butyl Sepharose 4FF, and MabSelect. In all three cases, the method provides results that are consistent with measurements based on batch adsorption and previously published data confirming its utility for the determination of protein mass transfer kinetics under a broad range of practically relevant conditions. PMID:18353343

  17. Mass-transfer limitations for immobilized enzyme-catalyzed kinetic resolution of racemate in a fixed-bed reactor.

    PubMed

    Xiu, G H; Jiang, L; Li, P

    2001-07-01

    A mathematical model has been developed for immobilized enzyme-catalyzed kinetic resolution of racemate in a fixed-bed reactor in which the enzyme-catalyzed reaction (the irreversible uni-uni competitive Michaelis-Menten kinetics is chosen as an example) was coupled with intraparticle diffusion, external mass transfer, and axial dispersion. The effects of mass-transfer limitations, competitive inhibition of substrates, deactivation on the enzyme effective enantioselectivity, and the optical purity and yield of the desired product are examined quantitatively over a wide range of parameters using the orthogonal collocation method. For a first-order reaction, an analytical solution is derived from the mathematical model for slab-, cylindrical-, and spherical-enzyme supports. Based on the analytical solution for the steady-state resolution process, a new concise formulation is presented to predict quantitatively the mass-transfer limitations on enzyme effective enantioselectivity and optical purity and yield of the desired product for a continuous steady-state kinetic resolution process in a fixed-bed reactor. PMID:11353408

  18. Assessing the influence of biofilm surface roughness on mass transfer by combining optical coherence tomography and two-dimensional modeling.

    PubMed

    Li, Chunyan; Wagner, Michael; Lackner, Susanne; Horn, Harald

    2016-05-01

    Imaging and modeling are two major approaches in biofilm research to understand the physical and biochemical processes involved in biofilm development. However, they are often used separately. In this study we combined these two approaches to investigate substrate mass transfer and mass flux. Cross-sectional biofilm images were acquired by means of optical coherence tomography (OCT) for biofilms grown on carriers. A 2D biofilm model was developed incorporating OCT images as well as a simplified biofilm geometry serving as structural templates. The model incorporated fluid flow, substrate transfer and biochemical conversion of substrates and simulated the hydrodynamics surrounding the biofilm structure as well as the substrate distribution. The method allowed detailed analysis of the hydrodynamics and mass transfer characteristics at the micro-scale. Biofilm activity with respect to substrate fluxes was compared among different combinations of flow, substrate availability and biomass density. The combined approach revealed that higher substrate fluxes at heterogeneous biofilm surface under two conditions: pure diffusion and when high flow velocity along the biofilms surface renders the whole liquid-biofilm interface to be highly active. In-between the two conditions the substrate fluxes across the surface of smooth biofilm geometry were higher than that of the heterogeneous biofilms. PMID:26498328

  19. Mass transfer within electrostatic precipitators: in-flight adsorption of mercury by charged suspended particulates

    SciTech Connect

    Herek L. Clack

    2006-06-01

    Electrostatic precipitation is the dominant method of particulate control used for coal combustion, and varying degrees of mercury capture and transformation have been reported across ESPs. Nevertheless, the fate of gas-phase mercury within an ESP remains poorly understood. The present analysis focuses on the gas-particle mass transfer that occurs within a charged aerosol in an ESP. As a necessary step in gas-phase mercury adsorption or transformation, gas-particle mass transfer - particularly in configurations other than fixed beds - has received far less attention than studies of adsorption kinetics. Our previous analysis showed that only a small fraction of gas-phase mercury entering an ESP is likely to be adsorbed by collected particulate matter on the plate electrodes. The present simplified analysis provides insight into gas-particle mass transfer within an ESP under two limiting conditions: laminar and turbulent fluid flows. The analysis reveals that during the process of particulate collection, gas-particle mass transfer can be quite high, easily exceeding the mass transfer to ESP plate electrodes in most cases. Decreasing particle size, increasing particle mass loading, and increasing temperature all result in increased gas-particle mass transfer. The analysis predicts significantly greater gas-particle mass transfer in the laminar limit than in the turbulent limit; however, the differences become negligible under conditions where other factors, such as total mass of suspended particulates, are the controlling mass transfer parameters. Results are compared to selected pilot- and full-scale sorbent injection data. 41 refs., 5 figs.

  20. MASS TRANSFER VARIATIONS IN UX MONOCEROTIS: EIGHT YEARS OF AUTOMATED PHOTOMETRIC MONITORING

    SciTech Connect

    Olson, Edward C.; Henry, Gregory W.; ETZEL, PAUL B. E-mail: henry@schwab.tsuniv.edu

    2009-11-15

    We analyze eight years (1999-2007) of automated photometric observations of the active Algol binary UX Monocerotis to search for mass transfer bursts similar to those seen in U Cephei. The largest photometric anomaly is the mean gainer luminosity difference between the stream-impact hemisphere and the opposite hemisphere. We find an updated Wilson-Devinney solution for earlier six-color observations. The UX Mon donor star fills its Roche lobe and the gainer nearly fills its rotational lobe. Instead of isolated bursts of the U Cep type, we found nearly continuous brightness fluctuations likely produced by variable mass transfer. We discuss implications for mass transfer.

  1. Late Diagenesis and Mass Transfer in Sandstone Shale Sequences

    NASA Astrophysics Data System (ADS)

    Milliken, K. L.

    2003-12-01

    , involving only compaction and dewatering of sedimentary materials. Detrital phases that survived weathering were seen as essentially inert to subsequent reaction during burial and prior to the onset of metamorphism. Metamorphism itself was viewed as isochemical and accomplished principally through solid-state reactions (see a brief summary in Ague, 1991). Notable exceptions to these views constitute the foundations of existing theory regarding the nature of late diagenesis. "Intrastratal solution" of chemically unstable detrital minerals (e.g., Pettijohn, 1941), apparent potassium metasomatism of shales (e.g., Weaver and Beck, 1971), and massive mineralogical changes during progressive burial (e.g., Coombs et al., 1959) are observations that established the directions of modern research in late diagenesis. Advances in petrographic imaging techniques (e.g., backscattered electron- and cathodoluminescence-imaging) and integration of petrographic observations with both bulk and spatially resolved chemical analyses have greatly accelerated the evolution of concepts about late diagenesis and early metamorphism.Today, basin-scale mass transfer of some materials (e.g., helium, water, and petroleum) is unquestioned (e.g., Hunt, 1996). Other materials (e.g., titanium and the REEs) are sufficiently mobile to appear within authigenic precipitates, but are likely to be "immobile" on the scale of a hand specimen. Mobilities of the major elements that make up sandstones and shales (silicon, aluminum, calcium, sodium, potassium) remain controversial. Conflicting notions about processes in rock suites across the wide range of burial conditions and alteration show that fundamental questions remain unanswered about the nature of the volumetrically significant processes within a major segment of the rock cycle. It is very likely that something is wrong, or at least inadequate, with the present concepts and/or data pertaining to the evolution of permeability, transport mechanisms, and timing

  2. Noncontact diffuse optical assessment of blood flow changes in head and neck free tissue transfer flaps

    PubMed Central

    Huang, Chong; Radabaugh, Jeffrey P.; Aouad, Rony K.; Lin, Yu; Gal, Thomas J.; Patel, Amit B.; Valentino, Joseph; Shang, Yu; Yu, Guoqiang

    2015-01-01

    Abstract. Knowledge of tissue blood flow (BF) changes after free tissue transfer may enable surgeons to predict the failure of flap thrombosis at an early stage. This study used our recently developed noncontact diffuse correlation spectroscopy to monitor dynamic BF changes in free flaps without getting in contact with the targeted tissue. Eight free flaps were elevated in patients with head and neck cancer; one of the flaps failed. Multiple BF measurements probing the transferred tissue were performed during and post the surgical operation. Postoperative BF values were normalized to the intraoperative baselines (assigning “1”) for the calculation of relative BF change (rBF). The rBF changes over the seven successful flaps were 1.89±0.15, 2.26±0.13, and 2.43±0.13 (mean±standard error), respectively, on postoperative days 2, 4, and 7. These postoperative values were significantly higher than the intraoperative baseline values (p<0.001), indicating a gradual recovery of flap vascularity after the tissue transfer. By contrast, rBF changes observed from the unsuccessful flaps were 1.14 and 1.34, respectively, on postoperative days 2 and 4, indicating less flow recovery. Measurement of BF recovery after flap anastomosis holds the potential to act early to salvage ischemic flaps. PMID:26187444

  3. Distribution and Mass of Diffuse and Dense CO Gas in the Milky Way

    NASA Astrophysics Data System (ADS)

    Roman-Duval, Julia; Heyer, Mark; Brunt, Christopher M.; Clark, Paul; Klessen, Ralf; Shetty, Rahul

    2016-02-01

    Emission from carbon monoxide (CO) is ubiquitously used as a tracer of dense star-forming molecular clouds. There is, however, growing evidence that a significant fraction of CO emission originates from diffuse molecular gas. Quantifying the contribution of diffuse CO-emitting gas is vital for understanding the relation between molecular gas and star formation. We examine the Galactic distribution of two CO-emitting gas components, a high column density component detected in 13CO and 12CO, and a low column density component detected in 12CO, but not in 13CO. The “diffuse” and “dense” components are identified using a combination of smoothing, masking, and erosion/dilation procedures, making use of three large-scale 12CO and 13CO surveys of the inner and outer Milky Way. The diffuse component, which globally represents 25% (1.5 × 108M⊙) of the total molecular gas mass (6.5 × {10}8 M⊙), is more extended perpendicular to the Galactic plane. The fraction of diffuse gas increases from ˜10%-20% at a galactocentric radius of 3-4 kpc to 50% at 15 kpc, and increases with decreasing surface density. In the inner Galaxy, a yet denser component traced by CS emission represents 14% of the total molecular gas mass traced by 12CO emission. Only 14% of the molecular gas mass traced by 12CO emission is identified as part of molecular clouds in 13CO surveys by cloud identification algorithms. This study indicates that CO emission not only traces star-forming clouds, but also a significant diffuse molecular ISM component.

  4. Large-scale mass transfers related to pressure solution creep-faulting interactions in mudstones: Driving processes and impact of lithification degree

    NASA Astrophysics Data System (ADS)

    Richard, J.

    2014-02-01

    Where normal faulting is associated with PSC (Pressure Solution Creep), it generates evolutions in petrophysical properties of mudstones like chalk: decrease in reservoir qualities and transport properties in the deformed zones adjacent to the fault plane and increase (or no change) in reservoir qualities and transport properties in the outermost deformed zones. These modifications result from large-scale mass transfers linked to a transport of solutes through the pore space over distances of several grains within decimeter or larger zones (open systems at the grain scale). In the lithified mudstones, these large-scale mass transfers consist in a mass redistribution from the outermost deformed zones (mass and volume loss) to the deformed zones adjacent to the fault planes (mass gain). In the weakly lithified mudstones, the mass redistribution occurs in an opposite direction. A deeper understanding of these large-scale mass redistributions is essential because the PSC-faulting interactions and the associated petrophysical modifications can be a key topic in several geological applications (oil and gas migration and entrapment in mudstone reservoirs, anthropogenic waste storage, carbon dioxyde geosequestration). The results of two studies about mass transfers and volume changes induced by natural fault systems in “white chalk” allowed to point out that two driving processes control the large-scale mass transfers during PSC-faulting interactions: the advective mass transport related to pore fluid flows and the large-scale diffusive mass transport linked to chemical potential gradients. The present contribution also highlights that the lithification degree of the host material plays a key role in the large-scale mass transfers related to PSC-faulting interactions by controlling (1) the spatial distribution of voids induced by the deformation, (2) the particle displacement on the fault plane and in the adjacent zones and (3) the petrophysical properties of the host

  5. Effects of microscale inertia on heat or mass transfer from a drop

    NASA Astrophysics Data System (ADS)

    Krishnamurthy, Deepak; Subramanian, Ganesh

    2012-11-01

    Heat or mass transport from suspensions of solid particles or drops is ubiquitous in many industrial processes. In the zero inertia limit the transport is diffusion limited owing to the presence of closed streamlines around each particle. A small but finite amount of inertia though, results in a vastly different picture, greatly enhancing transport by destroying the closed streamline configuration. We develop a theoretical formulation to study the effects of weak inertia on transport from a density-matched drop in a 2D linear flow. It is shown that, unlike a solid particle, the near-surface streamlines are closed only when the viscosity ratio (λ) exceeds a critical value λc = 2 α / (1- α) , where α is the linear flow parameter measuring relative magnitudes of extension and vorticity. The velocity field on the drop surface can be characterized using a complex-valued analogue of the (C, τ) coordinate system used to describe Jeffrey orbits of an axisymmetric particle. In the open-streamline case (λ < λ c) , convective transport occurs even with zero inertia, and for large Peclet number (Pe) (the relative magnitude of convective to diffusive transport), the Nusselt number (dimensionless rate of heat transfer) is expected to scale as F(α, λ) Pe1/2 and is determined via a boundary layer analysis in the (C, τ) coordinate system. In the closed streamline case (λ > λ c) , similar to the solid particle, inertia plays a crucial role, and the Nusselt number must scale as G(α, λ)Re1/2Pe1/2. A methodology is developed to analyze the convection along spiraling streamlines using a physically motivated choice of coordinate system on the drop surface.

  6. Optimal-mass-transfer-based estimation of glymphatic transport in living brain

    PubMed Central

    Zhu, Liangjia; Kolesov, Ivan; Nedergaard, Maiken; Benveniste, Helene; Tannenbaum, Allen

    2016-01-01

    It was recently shown that the brain-wide cerebrospinal fluid (CSF) and interstitial fluid exchange system designated the ‘glymphatic pathway’ plays a key role in removing waste products from the brain, similarly to the lymphatic system in other body organs1,2. It is therefore important to study the flow patterns of glymphatic transport through the live brain in order to better understand its functionality in normal and pathological states. Unlike blood, the CSF does not flow rapidly through a network of dedicated vessels, but rather through para-vascular channels and brain parenchyma in a slower time-domain, and thus conventional fMRI or other blood-flow sensitive MRI sequences do not provide much useful information about the desired flow patterns. We have accordingly analyzed a series of MRI images, taken at different times, of the brain of a live rat, which was injected with a paramagnetic tracer into the CSF via the lumbar intrathecal space of the spine. Our goal is twofold: (a) find glymphatic (tracer) flow directions in the live rodent brain; and (b) provide a model of a (healthy) brain that will allow the prediction of tracer concentrations given initial conditions. We model the liquid flow through the brain by the diffusion equation. We then use the Optimal Mass Transfer (OMT) approach3 to derive the glymphatic flow vector field, and estimate the diffusion tensors by analyzing the (changes in the) flow. Simulations show that the resulting model successfully reproduces the dominant features of the experimental data. PMID:26877579

  7. Heat and mass transfer characteristics of absorption of R134a into DMAC in a horizontal tube absorber

    NASA Astrophysics Data System (ADS)

    Harikrishnan, L.; Maiya, M. P.; Tiwari, S.; Wohlfeil, A.; Ziegler, F.

    2009-10-01

    In this paper the heat and mass transfer characteristics of a horizontal tube absorber for the mixture R134a/DMAC in terms of experimentally gained heat and mass transfer coefficients are presented. The heat transfer coefficient is mainly dependent on the solution’s mass flow rate. The mass transfer coefficient is strongly related to the subcooling of the solution. The data are compared to experimental absorption characteristics of water into aqueous lithium bromide in an absorption chiller. The mass transfer coefficients are of similar size whereas the heat transfer coefficients are about one order of magnitude smaller for R134a-DMAC.

  8. The Sun is a plasma diffuser that sorts atoms by mass

    SciTech Connect

    Manuel, O. Kamat, S. A.; Mozina, M.

    2006-11-15

    The Sun is a plasma diffuser that selectively moves light elements like H and He and the lighter isotopes of each element to its surface. The Sun formed on the collapsed core of a supernova (SN) and is composed mostly of elements made near the SN core (Fe, O, Ni, Si, and S), like the rocky planets and ordinary meteorites. Neutron emission from the central neutron star triggers a series of reactions that generate solar luminosity, solar neutrinos, solar mass fractionation, and an outpouring of hydrogen in the solar wind. Mass fractionation seems to have operated in the parent star and likely occurs in other stars as well.

  9. Measurement of atmospheric sesquiterpenes by proton transfer reaction-mass spectrometry (PTR-MS)

    NASA Astrophysics Data System (ADS)

    Kim, S.; Karl, T.; Helmig, D.; Daly, R.; Rasmussen, R.; Guenther, A.

    2009-04-01

    The ability to measure sesquiterpenes (SQT; C15H24) by a Proton-Transfer-Reaction Mass Spectrometer (PTR-MS) was investigated. SQT calibration standards were prepared by a capillary diffusion method and the PTR-MS-estimated mixing ratios were derived from the counts of product ions and proton transfer reaction constants. These values were compared with mixing ratios determined by a calibrated Gas Chromatograph (GC) coupled to a Flame Ionization Detector (GC-FID). Product ion distributions from soft-ionization occurring in a selected ion drift tube via proton transfer were measured as a function of collision energies. Results after the consideration of the mass discrimination of the PTR-MS system suggest that quantitative SQT measurements within 20% accuracy can be achieved with PTR-MS if two major product ions (m/z 149+ and 205+), out of seven major product ions (m/z 81+, 95+, 109+, 123+, 135+, 149+ and 205+), are accounted for. Considerable fragmentation of bicyclic sesquiterpenes, i.e. β-caryophyllene and α-humulene, cause the accuracy to be reduced to 50% if only the parent ion (m/z 205+) is considered. These findings were applied to a field dataset collected above a deciduous forest at the PROPHET (Program for Research on Oxidants: Photochemistry, Emissions, and Transport) research station in 2005. Inferred average daytime ecosystem scale mixing ratios (fluxes) of isoprene, sum of monoterpenes (MT), and sum of SQT exhibited values of 15 μg m-3 (4.5 mg m-2 h-1), 1.2 μg m-3 (0.21 mg m-2 h-1), and 0.0016 μg m-3 (0.10 mg m-2 h-1), respectively. A range of MT and SQT reactivities with respect to the OH radical was calculated and compared to an earlier study inferring significantly underestimated OH reactivities due to unknown terpenes above this deciduous forest. The results indicate that incorporating these MT and SQT results can resolve ~30% of missing OH reactivity reported for this site.

  10. Measurement of atmospheric sesquiterpenes by proton transfer reaction-mass spectrometry (PTR-MS)

    NASA Astrophysics Data System (ADS)

    Kim, S.; Karl, T.; Helmig, D.; Daly, R.; Rasmussen, R.; Guenther, A.

    2008-12-01

    The ability to measure sesquiterpenes (SQT; C15H24) by a Proton-Transfer-Reaction Mass Spectrometer (PTR-MS) was investigated with SQT standards, prepared by a capillary diffusion method, and the estimated mixing ratios, derived from the counts of product ions and proton transfer reaction constants were intercompared with measured mixing ratios, measured by a complementary Gas Chromatograph (GC) coupled to a Flame Ionization Detector (GC-FID). Product ion distributions due to soft-ionization occurring in a selected ion drift tube via proton transfer were measured as a function of collision energies. Results after the consideration of the mass discrimination of the PTR-MS system suggest that quantitative SQT measurements within 20% accuracy can be achieved with PTR-MS if two major product ions (m/z 149+ and 205+) out of seven major product ions (m/z 81+, 95+, 109+, 123+, 135+, 149+ and 205+) are accounted for. Bicyclic sesquiterpenes, i.e. β-caryophyllene and α-humulene, showed considerable fragmentation causing the accuracy of their analysis to be reduced to 50% if only the parent ion (m/z 205) is considered. These findings were applied to a field dataset collected above a deciduous forest at the PROPHET (Program for Research on Oxidants: Photochemistry, Emissions, and Transport) research station in 2005. Inferred Average daytime ecosystem scale mixing ratios (fluxes) of isoprene, sum of monoterpenes (MT), and sum of SQT exhibited values of 15 μg m-3 (4.5 mg m-2 h-1), 1.2 μg m-3 (0.21 mg m-2 h-1) and 0.0016 μg m-3 (0.10 mgm-2 h-1) respectively. A range of MT and SQT reactivities with respect to the OH radical was calculated and compared to an earlier study inferring significantly underestimated OH reactivities due to unknown terpenes above this deciduous forest. The results indicate that MT and SQT can resolve ~30% of missing OH reactivity, reported from this site.

  11. Mass transfer in supercritical fluids instancing selected fluids in supercritical carbon dioxide

    NASA Astrophysics Data System (ADS)

    Hu, Miao; Benning, Rainer; Delgado, Antonio; Ertunc, Oezguer

    The research interests lie in a deeper understanding of the mechanisms of diffusion and nucle-ation of organic solutes in near-and supercritical state of a solvent, which count as important means of mass transfer in the process engineering industry. The use of supercritical fluids in industrial processes, such as extraction and particle handling, has become a more and more popular method. Take a closer look at the two processes one would find that there are obviously two sub-processes involved in each of the process, namely the diffusion/nucleation as well as a phase transition procedure. Because of the operational limitations in the practice, this phase transition can-not be neglected. So it is also included in the theoretical approach. Classically to deduce conclusions from experiment results, mathematical/physical models outlining property changes and summarizing characteristics of the two processes are expected. In order to become an insight of these phenomena from the origin, and also to serve as a fundamental attribute for the numerical simulation later, the theories of statistical thermodynamics are adopted here as a proper means to describe the behaviors of the two processes. As the diffusion coefficients of the samples in our case are only of an order of approx. 10-8m2s-1, it can be assumed that the processes are in equilibrium (local changes are neglectably small), a model can be built on a general macroscopic approach for equilibrium systems, namely the Boltzmann-Gibbs distri-bution. And some rather general methods e.g. linear response theory can be applied. But as the transfer phenomena are genuinely not equilibrium systems, from this aspect a model can also be built based on the microscopic description -the kinetic theory of the behaviors of the particles of this non-equilibrium system. The characteristics under compensated gravity are also to be considered in the models. The differences and constraints between the models are to be compared and

  12. Hydrodynamics and oxygen mass transfer in a packed bed split-cylinder airlift reactor containing dilute alcoholic solutions

    NASA Astrophysics Data System (ADS)

    Keshavarz Moraveji, Mostafa; Ebrahimi Fakhari, Mona; Mohsenzadeh, Elmira; Davarnejad, Reza

    2013-01-01

    In this article, the influences of alcohols on the hydrodynamics and oxygen mass transfer characteristics in an airlift reactor equipped with packing were investigated. The hydrodynamic parameters and mass transfer coefficient in 1 % (v/v) aqueous solutions of four aliphatic alcohols were tested. It was concluded that alcohols addition increased gas holdup and gas-liquid mass transfer coefficient. The packing installation increased mass transfer coefficient, gas holdup and liquid circulation velocity, as well.

  13. A mass transfer origin for blue stragglers in NGC 188 as revealed by half-solar-mass companions.

    PubMed

    Geller, Aaron M; Mathieu, Robert D

    2011-10-20

    In open star clusters, where all members formed at about the same time, blue straggler stars are typically observed to be brighter and bluer than hydrogen-burning main-sequence stars, and therefore should already have evolved into giant stars and stellar remnants. Correlations between blue straggler frequency and cluster binary star fraction, core mass and radial position suggest that mass transfer or mergers in binary stars dominates the production of blue stragglers in open clusters. Analytic models, detailed observations and sophisticated N-body simulations, however, argue in favour of stellar collisions. Here we report that the blue stragglers in long-period binaries in the old (7 × 10(9)-year) open cluster NGC 188 have companions with masses of about half a solar mass, with a surprisingly narrow mass distribution. This conclusively rules out a collisional origin, as the collision hypothesis predicts a companion mass distribution with significantly higher masses. Mergers in hierarchical triple stars are marginally permitted by the data, but the observations do not favour this hypothesis. The data are highly consistent with a mass transfer origin for the long-period blue straggler binaries in NGC 188, in which the companions would be white dwarfs of about half a solar mass. PMID:22012393

  14. A multiscale modeling study for the convective mass transfer in a subsurface aquifer

    NASA Astrophysics Data System (ADS)

    Alam, Jahrul M.

    2015-09-01

    Quantitative and realistic computer simulations of mass transfer associated with disposal in subsurface aquifers is a challenging endeavor. This article has proposed a novel and efficient multiscale modeling framework, and has examined its potential to study the penetrative mass transfer in a plume that migrates in an aquifer. Numerical simulations indicate that the migration of the injected enhances the vorticity generation, and the dissolution of has a strong effect on the natural convection mass transfer. The vorticity decays with the increase of the porosity. The time scale of the vertical migration of a plume is strongly dependent on the rate of dissolution. Comparisons confirm the near optimal performance of the proposed multiscale model. These primary results with an idealized computational model of the migration in an aquifer brings the potential of the proposed multiscale model to the field of heat and mass transfer in the geoscience.

  15. Mathematical model of quasistationary conditions of mass transfer in an electrodialysis cell

    NASA Astrophysics Data System (ADS)

    Khanmamedov, M. N.

    2000-07-01

    The author suggests a quasistationary mathematical model of the mass-transfer conditions in an electrodialysis cell in which the main operating parameters of the electrodialysis apparatus are expressed as a function of the dimensionless diluate concentration.

  16. Mass transfer in countercurrent packed columns: Application to supercritical CO[sub 2] extraction of terpenes

    SciTech Connect

    Simoes, P.C.; Matos, H.A.; Carmelo, P.J.; Gomes de Azevedo, E.; Nunes da Ponte, M. . Faculdade de Ciencias e Tecnologia)

    1995-02-01

    Supercritical fluid extraction (SFE) is an alternative separation method to more conventional processes such as liquid extraction and distillation. However, up to now, few works have been devoted to the investigation of the efficiency of countercurrent packed columns under supercritical conditions from a mass transfer point of view. Mass transfer in a countercurrent column, filled with structured gauze packing, was measured for the separation of a mixture of terpenes (d-limonene/1,8-cineole) by supercritical carbon dioxide, at 313 and 318 K and pressures up to 9 MPa. The extraction efficiency was determined in terms of the overall mass transfer coefficient. Operating lines for this process had an appreciable curvature due to a high miscibility of the two contacting phases. The real slope of these lines had to be estimated. Available mass transfer models for packed columns predicted efficiencies diverging to a great extent from the experimental results.

  17. Fluid-dynamic and mass-transfer behavior of static mixers and regular packings

    SciTech Connect

    Cavatorta, O.N.; Boehm, U.; Chiappori de del Giorgio, A.M.

    1999-05-01

    The fluid dynamics and liquid-to-wall mass transfer for spaced and stacked regular packings were studied for forced convection and fluidized beds. The behavior of these configurations in bubble columns and under natural convection conditions is also presented. Flow parameters characterizing structured packings, presented in the literature, were used in the evaluation of results. General equations to predict pressure drop and mass transfer are discussed, as well as the relationship between energy dissipation and mass transfer. In the presence of fluidized particles, single-phase flow or natural convection conditions, the mass-transfer behavior of a packing element stacked between other packs or separated from the neighboring elements by liquid layers is almost the same, but differs in bubble columns.

  18. Estimating Heat and Mass Transfer Processes in Green Roof Systems: Current Modeling Capabilities and Limitations (Presentation)

    SciTech Connect

    Tabares Velasco, P. C.

    2011-04-01

    This presentation discusses estimating heat and mass transfer processes in green roof systems: current modeling capabilities and limitations. Green roofs are 'specialized roofing systems that support vegetation growth on rooftops.'

  19. OVERALL MASS TRANSFER COEFFICIENT FOR POLLUTANT EMISSIONS FROM SMALL WATER POOLS UNDER SIMULATED INDOOR ENVIRONMENTAL CONDITIONS

    EPA Science Inventory

    Small chamber tests were conducted to experimentally determine the overall mass transfer coefficient for pollutant emissions from still water under simulated indoor-residential or occupational-environmental conditions. Fourteen tests were conducted in small environmental chambers...

  20. The mechanism of thermal-gradient mass transfer in the sodium hydroxide-nickel system

    NASA Technical Reports Server (NTRS)

    May, Charles E

    1958-01-01

    "Thermal-gradient mass transfer" was investigated in the molten sodium hydroxide-nickel system. Possible mechanisms (physical, electrochemical, and chemical) are discussed in terms of experimental and theoretical evidence. Experimental details are included in appendixes.

  1. Assessment of interfacial mass transfer in water-unsaturated soils during vapor extraction.

    PubMed

    Hoeg, S; Schöler, H F; Warnatz, J

    2004-10-01

    This paper presents results of a numerical investigation of soil vapor extraction (SVE) systems at the laboratory scale. The SVE technique is used to remove volatile chlorinated hydrocarbons (VCHC) from the water-unsaturated soil zone. The developed numerical model solves equations of flow, transport and interfacial mass transfer regarding an isothermal n-component and three-phase system. The mathematical model is based on a simple pore network and phase distribution model and designed to be scaled by a characteristic length. All mathematical expressions are structured into VCHC specific and VCHC non-specific parameters. Furthermore, indicators are introduced that help to separate thermodynamic equilibrium from thermodynamic non-equilibrium domains and to determine the controlling physical parameters. For numerical solution, the system of partial differential equations is discretized by a finite volume method and an implicit Euler time stepping scheme. Computational effort is reduced notably through techniques that enable spatial and temporal adaptivity, through a standard multigrid method as well as through a problem-oriented sparse-matrix storage concept. Computations are carried out in two dimensions regarding the laboratory experiment of Fischer et al. [Water Resour. Res. 32 (12) 1996 3413]. By varying the characteristic length scale of the pore network and phase distribution model, it is shown that the experimental gas phase concentrations cannot be explained only by the volatility and diffusivity of the VCHC. The computational results suggest a sorption process whose significance grows with the aqueous activity of the less or non-polar organic compounds. PMID:15358492

  2. Impact of plant shoot architecture on leaf cooling: a coupled heat and mass transfer model

    PubMed Central

    Bridge, L. J.; Franklin, K. A.; Homer, M. E.

    2013-01-01

    Plants display a range of striking architectural adaptations when grown at elevated temperatures. In the model plant Arabidopsis thaliana, these include elongation of petioles, and increased petiole and leaf angles from the soil surface. The potential physiological significance of these architectural changes remains speculative. We address this issue computationally by formulating a mathematical model and performing numerical simulations, testing the hypothesis that elongated and elevated plant configurations may reflect a leaf-cooling strategy. This sets in place a new basic model of plant water use and interaction with the surrounding air, which couples heat and mass transfer within a plant to water vapour diffusion in the air, using a transpiration term that depends on saturation, temperature and vapour concentration. A two-dimensional, multi-petiole shoot geometry is considered, with added leaf-blade shape detail. Our simulations show that increased petiole length and angle generally result in enhanced transpiration rates and reduced leaf temperatures in well-watered conditions. Furthermore, our computations also reveal plant configurations for which elongation may result in decreased transpiration rate owing to decreased leaf liquid saturation. We offer further qualitative and quantitative insights into the role of architectural parameters as key determinants of leaf-cooling capacity. PMID:23720538

  3. Heat and mass transfer in combustion - Fundamental concepts and analytical techniques

    NASA Technical Reports Server (NTRS)

    Law, C. K.

    1984-01-01

    Fundamental combustion phenomena and the associated flame structures in laminar gaseous flows are discussed on physical bases within the framework of the three nondimensional parameters of interest to heat and mass transfer in chemically-reacting flows, namely the Damkoehler number, the Lewis number, and the Arrhenius number which is the ratio of the reaction activation energy to the characteristic thermal energy. The model problems selected for illustration are droplet combustion, boundary layer combustion, and the propagation, flammability, and stability of premixed flames. Fundamental concepts discussed include the flame structures for large activation energy reactions, S-curve interpretation of the ignition and extinctin states, reaction-induced local-similarity and non-similarity in boundary layer flows, the origin and removal of the cold boundary difficulty in modeling flame propagation, and effects of flame stretch and preferential diffusion on flame extinction and stability. Analytical techniques introduced include the Shvab-Zeldovich formulation, the local Shvab-Zeldovich formulation, flame-sheet approximation and the associated jump formulation, and large activation energy matched asymptotic analysis. Potentially promising research areas are suggested.

  4. Comprehensive modeling of methanogenic biofilms in fluidized bed systems: Mass transfer limitations and multisubstrate aspects

    SciTech Connect

    Buffiere, P.; Steyer, J.P.; Moletta, R.; Fonade, C.

    1995-12-20

    Anaerobic digestion--a process where organic matter is degraded into a gas mixture of methane and carbon dioxide--is particularly adapted for food industry wastewater treatment because it reduces the chemical oxygen demand (COD) of the influent and produces valuable energy (methane). A cognitive model for anaerobic digestion in fluidized bed reactors is developed. The general pathway of the process is divided into five main reactions performed by different bacterial groups. Molecular diffusion of each substrate involved in the reaction scheme is described. Effectiveness factor calculations are performed in steady state for each bacterial group taken into account in the process. The case of a single substrate removal is discussed, and optimal biofilm sizes are found. Sequential substrate removal is investigated, and different kinetic regimes are characterized. The influence of biofilm size and primary substrate removal is discussed in the case of standard concentrations in the liquid phase. This study shows that, according to the theoretical model the limiting step of the process may be different and depends in a large way on mass transfer effects. Finally, importance of biofilm size is compared for acidogenic and methanogenic steps: each reaction is found to be optimized for different biofilm thicknesses. This result may be of interest for design purposes and further dynamic modeling. Concluding remarks concerning the validation of the model are made, and a comparison to experimental data from the literature is presented.

  5. Multi-layer onion drying: Study of mass and heat transfer mechanism and quality evaluation

    NASA Astrophysics Data System (ADS)

    Asiah, N.; Djaeni, M.

    2015-12-01

    Drying is one of methods to prolong storage life of onion. The outer layer of onion has kept dry around 12% of moisture content or below to retain the freshness of its inside part. The model of multi layers onion drying is very important to predict the water and temperature transport during dying process. In this case, one dimensional partial equation was used for predicting moisture distribution in the onion layer. To support the study, the onion drying was performed at various temperatures ranging of 40-50 °C. Then the attribute quality (quercetin content) of dried onion was analysed. The experimental data was to validate the value of water diffusivity and mass transfer coefficient used in the model. Results showed that the model can predict moisture distribution in each layer of onion. Moreover, based on the average moisture content during the drying, the model result closed to experiment data with accuracy of R2 0.970-0.999. The model was useful to estimate the drying time of outer layer to the desired level. Besides that, the quality evaluation showed that after 2 hours drying process, quercetin content can be retained.

  6. Investigation of coupled heat and mass transfer in heterogeneous porous media using numerical simulations

    NASA Astrophysics Data System (ADS)

    Illangasekare, T. H.; Frippiat, C. C.; Zyvoloski, G. A.

    2007-12-01

    A significant body of knowledge exists on separates processes of thermal and mass transport in granular and fractured subsurface formations. However, the need to simulate these processes in a fully coupled way has become necessary to deal with problems associated with long-term-storage of nuclear waste, and the development of new technologies for subsurface remediation. Another emerging area for research is associated with the development of technologies for in situ extraction of underground resources. Numerical models that couple thermal and mass transport processes will play a crucial role in understanding the fundamental processes associated with these new technologies, as well as in making predictions on how complex subsurface systems are expected to behave. It is our hypothesis that heat transport will have a significant impact on distributions of solute concentration, through temperature-dependent dissolution and precipitation, and temperature-dependent rate-limited diffusive transfer of solutes in fractured or highly heterogeneous media. A number of issues related to the validity of existing numerical tools that capture these processes, and their application to field systems through up-scaling need to be investigated. With this overall goal in mind, in this preliminary study, we explore the effect of the variability of subsurface properties on heat and mass transport using simulations conducted using an existing multiphase model. The finite-element code FEHM (Finite-Element Heat and Mass transport code) used in this study was developed at Los Alamos National Laboratory. This code allows for the coupled simulation of flow, heat and mass transport, accounting for density effects and dissolution and/or precipitation reactions. Our analysis is based on two- and three-dimensional simulations using synthetic data sets. Heterogeneous facies distributions are generated according to Markov Chain transition probability models. A distributed source of constant

  7. Bimolecular photoinduced electron transfer beyond the diffusion limit: the Rehm-Weller experiment revisited with femtosecond time resolution.

    PubMed

    Rosspeintner, Arnulf; Angulo, Gonzalo; Vauthey, Eric

    2014-02-01

    To access the intrinsic, diffusion free, rate constant of bimolecular photoinduced electron transfer reactions, fluorescence quenching experiments have been performed with 14 donor/acceptor pairs, covering a driving-force range going from 0.6 to 2.4 eV, using steady-state and femtosecond time-resolved emission, and applying a diffusion-reaction model that accounts for the static and transient stages of the quenching for the analysis. The intrinsic electron transfer rate constants are up to 2 orders of magnitude larger than the diffusion rate constant in acetonitrile. Above ∼1.5 eV, a slight decrease of the rate constant is observed, pointing to a much weaker Marcus inverted region than those reported for other types of electron transfer reactions, such as charge recombination. Despite this, the driving force dependence can be rationalized in terms of Marcus theory. PMID:24400958

  8. Exploring bubble oscillation and mass transfer enhancement in acoustic-assisted liquid-liquid extraction with a microfluidic device

    PubMed Central

    Xie, Yuliang; Chindam, Chandraprakash; Nama, Nitesh; Yang, Shikuan; Lu, Mengqian; Zhao, Yanhui; Mai, John D.; Costanzo, Francesco; Huang, Tony Jun

    2015-01-01

    We investigated bubble oscillation and its induced enhancement of mass transfer in a liquid-liquid extraction process with an acoustically-driven, bubble-based microfluidic device. The oscillation of individually trapped bubbles, of known sizes, in microchannels was studied at both a fixed frequency, and over a range of frequencies. Resonant frequencies were analytically identified and were found to be in agreement with the experimental observations. The acoustic streaming induced by the bubble oscillation was identified as the cause of this enhanced extraction. Experiments extracting Rhodanmine B from an aqueous phase (DI water) to an organic phase (1-octanol) were performed to determine the relationship between extraction efficiency and applied acoustic power. The enhanced efficiency in mass transport via these acoustic-energy-assisted processes was confirmed by comparisons against a pure diffusion-based process. PMID:26223474

  9. Calculation of Post-Closure Natural Convection Heat and Mass Transfer in Yucca Mountain Drifts

    SciTech Connect

    S. Webb; M. Itamura

    2004-03-16

    Natural convection heat and mass transfer under post-closure conditions has been calculated for Yucca Mountain drifts using the computational fluid dynamics (CFD) code FLUENT. Calculations have been performed for 300, 1000, 3000, and 10,000 years after repository closure. Effective dispersion coefficients that can be used to calculate mass transfer in the drift have been evaluated as a function of time and boundary temperature tilt.

  10. Evaluation of vapor mass transfer in various membrane distillation configurations: an experimental study

    NASA Astrophysics Data System (ADS)

    Mannella, G. A.; La Carrubba, V.; Brucato, V.

    2012-06-01

    Vapor mass transfer phenomena in four different membrane distillation (MD) configurations were examined through a self-built laboratory scale experimental apparatus: Air Gap MD, Sweeping Gas MD, Vacuum Sweeping Gas MD and Vacuum MD. Vapor fluxes were measured and compared with those predicted by various models, showing that MD performance under usual processing conditions is severely controlled by the permeate side resistance to mass transfer.

  11. Simultaneous heat and mass transfer from a two-dimensional, partially liquid-covered surface

    SciTech Connect

    Tao, Y.X.; Kaviany, M. )

    1991-11-01

    Simultaneous heat and mass transfer from partially liquid-covered surfaces is examined experimentally using a surface made of cylinders with the voids filled with liquid. The steady-state evaporation rate, surface temperature of the liquid and exposed solid, and location of meniscus are measured for various ambient air velocities and temperatures. Using these, the authors examine the effect of the extent to which the liquid covers the surface on the evaporation mass transfer rate resulting from the convective heat transfer from the ambient gas to this surface. The results show strong Bond and Reynolds number effects. For small Bond and Reynolds numbers, the presence of dry (exposed solid) surface does not influence the mass transfer rate. As the Bond or Reynolds number increases, a critical liquid coverage is found below which the mass transfer begins to decrease. Heat transfer from the exposed solid to the liquid is also examined using the measured surface temperature, a conduction model, and an estimate of the liquid and solid surface areas (using a static formation for the liquid meniscus). The results show that at the liquid surface an analogy between heat and mass transfer does not exist.

  12. Drop oscillation and mass transfer in alternating electric fields

    SciTech Connect

    Carleson, T.E.

    1992-06-24

    In certain cases droplet direct contact heat transfer rates can be significantly enhanced by the application of an alternating electric field. This field can produce shape oscillations in a droplet which will enhance mixing. The theoretical evaluation of the effect of the interaction of the field with drop charge on the hydrodynamics has been completed for small amplitude oscillations. Previous work with a zero order perturbation method was followed up with a first order perturbation method to evaluate the effect of drop distortion on drop charge and field distribution. The first order perturbation results show secondary drop oscillations of four modes and two frequencies in each mode. The most significant secondary oscillation has the same mode and frequency as the second mode oscillation predicted from the first order perturbation work. The resonant frequency of all oscillations decrease with increasing electric field strength and drop charge. Work is currently underway to evaluate the heat transfer enhancement from an applied alternating electric field.

  13. Influence of microwave irradiation on the mass-transfer kinetics of propylbenzene in reversed-phase liquid chromatography

    SciTech Connect

    Galinada, Wilmer; Kaczmarski, Krzysztof; Guiochon, Georges A

    2005-09-01

    The effect of microwave irradiation on the kinetics of mass transfer in reversed-phase liquid chromatography (RPLC) was studied by measuring its influence on the band profile of propylbenzene in a C{sub 18}-silica column eluted with an aqueous solution of methanol and placed inside a microwave oven. The elution peaks were measured by the pulse-response method, under linear conditions. The amount of microwave energy induced into the column was varied based on the microwave input power. The experimental data were analyzed using the conventional method of moment analysis and the lumped pore diffusion model. With input powers of 15 and 30 W, the effluent temperatures were 25 {+-} 1 and 30 {+-} 1 C, respectively. The effect of microwave irradiation on the mass transfer of the studied solute was determined by comparing the band profiles obtained under the same experimental conditions, at the same temperature, with and without irradiation. The values of the intraparticle diffusion coefficient, D{sub e}, measured with microwave irradiation were ca. 20% higher than those obtained without irradiation. Derived from the method of moments, the values of D{sub e} at 15 W (25 {+-} 1 C) and 0 W (25 {+-} 1 C) were 8.408 x 10{sup -6} cm{sup 2} s{sup -1} and 6.947 x 10{sup -6} cm{sup 2} s{sup -1}, respectively, while these values at 30 W (30 {+-} 1 C) and 0 W (30 {+-} 1 C) were 9.389 x 10{sup -6} cm{sup 2} s{sup -1} and 7.848 x 10{sup -6} cm{sup 2} s{sup -1}, respectively. The values of the surface diffusivity, D{sub S}, also increased with increasing power of the microwave irradiation. It is assumed that the increase in intraparticle diffusion for propylbenzene was caused by the molecular excitation of the organic modifier that has a higher dielectric loss than the solute. The values of D{sub e} were also analyzed and determined using the POR model. There was an excellent agreement between the results of the two independent methods. These preliminary results suggest that microwave

  14. Mass and Energy Transfer Between the Solar Photosphere and Corona

    NASA Astrophysics Data System (ADS)

    Peter, H.

    2015-12-01

    The problem of chromospheric and coronal heating is also a problem of mass supply to the corona. On average we see redshifts at transition region temperatures of the order of 10 km/s. If interpreted as downflows, this would quickly empty the corona, and fresh material has to be transported into the corona. Several models have been proposed to understand this mass cycle between the different atmospheric layers. However, as of yet all these proposals have serious shortcomings. On the observational side open questions remain, too. With the new IRIS mission we can observe the transition region at unprecedented spatial and spectral resolution, but the observational results are still puzzling. In particular the finding that the spatial distribution of line widths and Doppler shifts do not change with increasing resolution is against physical intuition. This shows that even with IRIS we still have significant velocity gradients along the line-of-sight, indicating that shocks might play a significant role. Likewise the temporal evolution might be a key for our understanding of the mass cycle. It might well be that the filling and draining of hot plasma occurs on significantly different time scales, which might be part of the difficulty to arrive at a conclusive observational picture. Considering the progress made for the quiet Sun, it seems clear that the processes responsible for the mass exchange are not resolved (yet). Therefore one might wonder to what extent one could use larger and resolved individual events in more active parts of the Sun to understand the details of the mass transport. In particular a common understanding of reconnection events such as Ellerman bombs in the photosphere, explosive events in the transition region and the recently discovered IRIS bombs in-between might provide the key to better understand the mass cycle throughout the atmospheric layers from the photosphere to the corona.

  15. Coupled effect of flow variability and mass transfer on contaminant transport and attenuation in groundwater

    NASA Astrophysics Data System (ADS)

    Cvetkovic, Vladimir; Fiori, Aldo; Dagan, Gedeon

    2016-04-01

    The driving mechanism of contaminant transport in aquifers is groundwater flow, which is controlled by boundary conditions and heterogeneity of hydraulic properties. In this work we show how hydrodynamics and mass transfer can be combined in a general analytical manner to derive a physically-based (or process-based) residence time distribution for a given integral scale of the hydraulic conductivity; the result can be applied for a broad class of linear mass transfer processes. The derived tracer residence time distribution is a transfer function with parameters to be inferred from combined field and laboratory measurements. It is scalable relative to the correlation length and applicable for an arbitrary statistical distribution of the hydraulic conductivity. Based on the derived residence time distribution, the coefficient of variation and skewness of contaminant residence time are illustrated assuming a log-normal hydraulic conductivity distribution and first-order mass transfer. We show that for a low Damkohler number the coefficient of variation is more strongly influenced by mass transfer than by heterogeneity, whereas skewness is more strongly influenced by heterogeneity. The derived physically-based residence time distribution for solute transport in heterogeneous aquifers is particularly useful for studying natural attenuation of contaminants. We illustrate the relative impacts of high heterogeneity and a generalised (non-Fickian) multi-rate mass transfer on natural attenuation defined as contaminant mass loss from injection to a downstream compliance boundary.

  16. Single-molecule-sensitive fluorescence resonance energy transfer in freely-diffusing attoliter droplets

    SciTech Connect

    Rahmanseresht, Sheema; Ramos, Kieran P.; Gamari, Ben D.; Goldner, Lori S.; Milas, Peker

    2015-05-11

    Fluorescence resonance energy transfer (FRET) from individual, dye-labeled RNA molecules confined in freely-diffusing attoliter-volume aqueous droplets is carefully compared to FRET from unconfined RNA in solution. The use of freely-diffusing droplets is a remarkably simple and high-throughput technique that facilitates a substantial increase in signal-to-noise for single-molecular-pair FRET measurements. We show that there can be dramatic differences between FRET in solution and in droplets, which we attribute primarily to an altered pH in the confining environment. We also demonstrate that a sufficient concentration of a non-ionic surfactant mitigates this effect and restores FRET to its neutral-pH solution value. At low surfactant levels, even accounting for pH, we observe differences between the distribution of FRET values in solution and in droplets which remain unexplained. Our results will facilitate the use of nanoemulsion droplets as attoliter volume reactors for use in biophysical and biochemical assays, and also in applications such as protein crystallization or nanoparticle synthesis, where careful attention to the pH of the confined phase is required.

  17. Single-molecule-sensitive fluorescence resonance energy transfer in freely-diffusing attoliter droplets

    NASA Astrophysics Data System (ADS)

    Rahmanseresht, Sheema; Milas, Peker; Ramos, Kieran P.; Gamari, Ben D.; Goldner, Lori S.

    2015-05-01

    Fluorescence resonance energy transfer (FRET) from individual, dye-labeled RNA molecules confined in freely-diffusing attoliter-volume aqueous droplets is carefully compared to FRET from unconfined RNA in solution. The use of freely-diffusing droplets is a remarkably simple and high-throughput technique that facilitates a substantial increase in signal-to-noise for single-molecular-pair FRET measurements. We show that there can be dramatic differences between FRET in solution and in droplets, which we attribute primarily to an altered pH in the confining environment. We also demonstrate that a sufficient concentration of a non-ionic surfactant mitigates this effect and restores FRET to its neutral-pH solution value. At low surfactant levels, even accounting for pH, we observe differences between the distribution of FRET values in solution and in droplets which remain unexplained. Our results will facilitate the use of nanoemulsion droplets as attoliter volume reactors for use in biophysical and biochemical assays, and also in applications such as protein crystallization or nanoparticle synthesis, where careful attention to the pH of the confined phase is required.

  18. Diffuse fluorescence tomography based on the radiative transfer equation for small animal imaging

    NASA Astrophysics Data System (ADS)

    Wang, Yihan; Zhang, Limin; Zhao, Huijuan; Gao, Feng; Li, Jiao

    2014-02-01

    Diffuse florescence tomography (DFT) as a high-sensitivity optical molecular imaging tool, can be applied to in vivo visualize interior cellular and molecular events for small-animal disease model through quantitatively recovering biodistributions of specific molecular probes. In DFT, the radiative transfer equation (RTE) and its approximation, such as the diffuse equation (DE), have been used as the forward models. The RTE-based DFT methodology is more suitable for biological tissue having void-like regions and the near-source area as in the situations of small animal imaging. We present a RTE-based scheme for the steady state DFT, which combines the discrete solid angle method and the finite difference method to obtain numerical solutions of the 2D steady RTE, with the natural boundary condition and collimating light source model. The approach is validated using the forward data from the Monte Carlo simulation for its better performances in the spatial resolution and reconstruction fidelity compared to the DE-based scheme.

  19. Design and characterisation of a novel in vitro skin diffusion cell system for assessing mass casualty decontamination systems.

    PubMed

    Matar, H; Larner, J; Kansagra, S; Atkinson, K L; Skamarauskas, J T; Amlot, R; Chilcott, R P

    2014-06-01

    The efficient removal of contaminants from the outer surfaces of the body can provide an effective means of reducing adverse health effects associated with incidents involving the accidental or deliberate release of hazardous materials. Showering with water is frequently used by first responders as a rapid method of mass casualty decontamination (MCD). However, there is a paucity of data on the generic effectiveness and safety of aqueous decontamination systems. To address these issues, we have developed a new in vitro skin diffusion cell system to model the conditions of a common MCD procedure ("ladder pipe system"). The new diffusion cell design incorporates a showering nozzle, an air sampling port for measurement of vapour loss and/aerosolisation, adjustable (horizontal to vertical) skin orientation and a circulating manifold system (to maintain a specified flow rate, temperature and pressure of shower water). The dermal absorption characteristics of several simulants (Invisible Red S, curcumin and methyl salicylate) measured with the new in vitro model were in good agreement with previous in vitro and in vivo studies. Moreover, these initial studies have indicated that whilst flow rate and water temperature are important factors for MCD, the presence of clothing during showering may (under certain circumstances) cause transfer and spreading of contaminants to the skin surface. PMID:24412538

  20. Orbital Evolution of Mass-transferring Eccentric Binary Systems. II. Secular Evolution

    NASA Astrophysics Data System (ADS)

    Dosopoulou, Fani; Kalogera, Vicky

    2016-07-01

    Finite eccentricities in mass-transferring eccentric binary systems can be explained by taking into account the mass loss and mass transfer processes that often occur in these systems. These processes can be treated as perturbations of the general two-body problem. The time-evolution equations for the semimajor axis and the eccentricity derived from perturbative methods are generally phase-dependent. The osculating semimajor axis and eccentricity change over the orbital timescale and are not easy to implement in binary evolution codes like MESA. However, the secular orbital element evolution equations can be simplified by averaging over the rapidly varying true anomalies. In this paper, we derive the secular time-evolution equations for the semimajor axis and the eccentricity for various mass loss/transfer processes using either the adiabatic approximation or the assumption of delta-function mass loss/transfer at periastron. We begin with the cases of isotropic and anisotropic wind mass loss. We continue with conservative and non-conservative non-isotropic mass ejection/accretion (including Roche-Lobe-Overflow) for both point-masses and extended bodies. We conclude with the case of phase-dependent mass accretion. Comparison of the derived equations with similar work in the literature is included and an explanation of the existing discrepancies is provided.

  1. Estimation of cauliflower mass transfer parameters during convective drying

    NASA Astrophysics Data System (ADS)

    Sahin, Medine; Doymaz, İbrahim

    2016-05-01

    The study was conducted to evaluate the effect of pre-treatments such as citric acid and hot water blanching and air temperature on drying and rehydration characteristics of cauliflower slices. Experiments were carried out at four different drying air temperatures of 50, 60, 70 and 80 °C with the air velocity of 2.0 m/s. It was observed that drying and rehydration characteristics of cauliflower slices were greatly influenced by air temperature and pre-treatment. Six commonly used mathematical models were evaluated to predict the drying kinetics of cauliflower slices. The Midilli et al. model described the drying behaviour of cauliflower slices at all temperatures better than other models. The values of effective moisture diffusivities (D eff ) were determined using Fick's law of diffusion and were between 4.09 × 10-9 and 1.88 × 10-8 m2/s. Activation energy was estimated by an Arrhenius type equation and was 23.40, 29.09 and 26.39 kJ/mol for citric acid, blanch and control samples, respectively.

  2. Effect of ohmic, mass-transfer, and kinetic resistances on linear-sweep voltammetry in a cylindrical-pore electrode

    NASA Technical Reports Server (NTRS)

    Weidner, John W.; Fedkiw, Peter S.

    1991-01-01

    A means is presented to account for the effect of ohmic, mass-transfer, and kinetic resistances on linear-sweep voltammograms by modeling a pore in a porous matrix as a cylindrical-pore electrode, and solving the mass and charge conservation equations in the context of this geometry for the simply redox reaction O + ne(-) yield R where both O and R are soluble species. Both analytical and numerical techniques are used to solve the governing equations. The calculated peak currents and potentials are correlated by empirical formulas to the measurable parameters: sweep rate, concentration of the redox species, diffusion coefficient, conductivity of the electrolyte, and pore dimensions. Using the correlations, a methodology is established for determining if the redox reaction kinetics are irreversible or reversible (Nernstian). If the reaction is irreversible, it is shown how the standard rate constant and the transfer coefficient may be extracted from linear-sweep voltammetry data, or, if the reaction is reversible, how the number of electrons transferred may be deduced.

  3. Experimental Investigations of Heat and Mass Transfer in Microchannel Heat-Transfer Elements

    NASA Astrophysics Data System (ADS)

    Konovalov, D. A.

    2016-06-01

    The present work seeks to develop and investigate experimentally microchannel heat-exchange apparatuses of two designs: with porous elements manufactured from titanium and copper, and also based on the matrix of filamentary silicon single crystals under operating conditions with high heat loads, unsteadiness, and nonlinear flow of the coolant. For experimental investigations, the authors have developed and manufactured a unique test bench allowing tests of the developed heat-transfer elements in unsteady operating regimes. The performed experimental investigations have made it possible to obtain criterial dependences of the heat-transfer coefficient on the Reynolds and Prandtl numbers and to refine the values of viscous and inertial coefficients. It has been established that microchannel heat-transfer elements based on silicon single crystals, which make it possible to remove a heat flux above 100 W/cm2, are the most efficient. For porous heat-transfer elements, the best result was attained for wedge-shaped copper samples. According to investigation results, the authors have considered the issues of optimization of thermal and hydraulic characteristics of the heat-transfer elements under study. In the work, the authors have given examples of practical use of the developed heat-transfer elements for cooling systems of radioelectronic equipment.

  4. Experimental Investigations of Heat and Mass Transfer in Microchannel Heat-Transfer Elements

    NASA Astrophysics Data System (ADS)

    Konovalov, D. A.

    2016-05-01

    The present work seeks to develop and investigate experimentally microchannel heat-exchange apparatuses of two designs: with porous elements manufactured from titanium and copper, and also based on the matrix of filamentary silicon single crystals under operating conditions with high heat loads, unsteadiness, and nonlinear flow of the coolant. For experimental investigations, the authors have developed and manufactured a unique test bench allowing tests of the developed heat-transfer elements in unsteady operating regimes. The performed experimental investigations have made it possible to obtain criterial dependences of the heat-transfer coefficient on the Reynolds and Prandtl numbers and to refine the values of viscous and inertial coefficients. It has been established that microchannel heat-transfer elements based on silicon single crystals, which make it possible to remove a heat flux above 100 W/cm2, are the most efficient. For porous heat-transfer elements, the best result was attained for wedge-shaped copper samples. According to investigation results, the authors have considered the issues of optimization of thermal and hydraulic characteristics of the heat-transfer elements under study. In the work, the authors have given examples of practical use of the developed heat-transfer elements for cooling systems of radioelectronic equipment.

  5. Monte-Carlo Radiative Transfer Model of the Diffuse Galactic Light

    NASA Astrophysics Data System (ADS)

    Seon, Kwang-Il

    2015-02-01

    Monte-Carlo radiative models of the diffuse Galactic light (DGL) in our Galaxy are calcu-lated using the dust radiative transfer code MoCafe, which is three-dimensional and takes full account of multiple scattering. The code is recently updated to use a fast voxel traversal algorithm, which has dramatically increased the computing speed. The radiative transfer models are calculated with the gen-erally accepted dust scale-height of 0.1 kpc. The stellar scale-heights are assumed to be 0.1 or 0.35 kpc, appropriate for far-ultraviolet (FUV) and optical wavelengths, respectively. The face-on optical depth, measured perpendicular to the Galactic plane, is also varied from 0.2 to 0.6, suitable to the optical to FUV wavelengths, respectively. We find that the DGL at high Galactic latitudes is mostly due to backward or large-angle scattering of starlight originating from the local stars within a radial distance of r < 0.5 kpc from the Earth. On the other hand, the DGL measured in the Galactic plane is mostly due to stars at a distance range that corresponds to an optical depth of -1 measured from the Earth. Therefore, the low-latitude DGL at the FUV wavelength band would be mostly caused by the stars located at a distance of r . 0.5 kpc and the optical DGL near the Galactic plane mainly originates from stars within a distance range of 1 . r . 2 kpc. We also calculate the radiative transfer models in a clumpy two-phase medium. The clumpy two-phase models provide lower intensities at high Galactic latitudes compared to the uniform density models, because of the lower effective optical depth in clumpy media. However, no significant difference in the intensity at the Galactic plane is found.

  6. Mathematical equivalence between time-dependent single-rate and multirate mass transfer models

    NASA Astrophysics Data System (ADS)

    Fernández-Garcia, D.; Sanchez-Vila, X.

    2015-05-01

    The often observed tailing of tracer breakthrough curves is caused by a multitude of mass transfer processes taking place over multiple scales. Yet, in some cases, it is convenient to fit a transport model with a single-rate mass transfer coefficient that lumps all the non-Fickian observed behavior. Since mass transfer processes take place at all characteristic times, the single-rate mass transfer coefficient derived from measurements in the laboratory or in the field vary with time ω>(t>). The literature review and tracer experiments compiled by Haggerty et al. (2004) from a number of sites worldwide suggest that the characteristic mass transfer time, which is proportional to ω>(t>)-1, scales as a power law of the advective and experiment duration. This paper studies the mathematical equivalence between the multirate mass transfer model (MRMT) and a time-dependent single-rate mass transfer model (t-SRMT). In doing this, we provide new insights into the previously observed scale-dependence of mass transfer coefficients. The memory function, g(t), which is the most salient feature of the MRMT model, determines the influence of the past values of concentrations on its present state. We found that the t-SRMT model can also be expressed by means of a memory function φ>(t,τ>). In this case, though the memory function is nonstationary, meaning that in general it cannot be written as φ>(t-τ>). Nevertheless, the full behavior of the concentrations using a single time-dependent rate ω>(t>) is approximately analogous to that of the MRMT model provided that the equality ω>(t>)=-dln⁡g>(t>)/dt holds and the field capacity is properly chosen. This relationship suggests that when the memory function is a power law, g>(t>)˜t1-k, the equivalent mass transfer coefficient scales as ω>(t>)˜t-1, nicely fitting without calibration the estimated mass transfer coefficients compiled by Haggerty et al. (2004).

  7. Final Report: Geoelectrical Measurement of Multi-Scale Mass Transfer Parameters

    SciTech Connect

    Haggerty, Roy; Day-Lewis, Fred; Singha, Kamini; Johnson, Timothy; Binley, Andrew; Lane, John

    2014-03-20

    Mass transfer affects contaminant transport and is thought to control the efficiency of aquifer remediation at a number of sites within the Department of Energy (DOE) complex. An improved understanding of mass transfer is critical to meeting the enormous scientific and engineering challenges currently facing DOE. Informed design of site remedies and long-term stewardship of radionuclide-contaminated sites will require new cost-effective laboratory and field techniques to measure the parameters controlling mass transfer spatially and across a range of scales. In this project, we sought to capitalize on the geophysical signatures of mass transfer. Previous numerical modeling and pilot-scale field experiments suggested that mass transfer produces a geoelectrical signature—a hysteretic relation between sampled (mobile-domain) fluid conductivity and bulk (mobile + immobile) conductivity—over a range of scales relevant to aquifer remediation. In this work, we investigated the geoelectrical signature of mass transfer during tracer transport in a series of controlled experiments to determine the operation of controlling parameters, and also investigated the use of complex-resistivity (CR) as a means of quantifying mass transfer parameters in situ without tracer experiments. In an add-on component to our grant, we additionally considered nuclear magnetic resonance (NMR) to help parse mobile from immobile porosities. Including the NMR component, our revised study objectives were to: 1. Develop and demonstrate geophysical approaches to measure mass-transfer parameters spatially and over a range of scales, including the combination of electrical resistivity monitoring, tracer tests, complex resistivity, nuclear magnetic resonance, and materials characterization; and 2. Provide mass-transfer estimates for improved understanding of contaminant fate and transport at DOE sites, such as uranium transport at the Hanford 300 Area. To achieve our objectives, we implemented a 3

  8. Mass Transfer Limited Enhanced Bioremediation at Dnapl Source Zones: a Numerical Study

    NASA Astrophysics Data System (ADS)

    Kokkinaki, A.; Sleep, B. E.

    2011-12-01

    The success of enhanced bioremediation of dense non-aqueous phase liquids (DNAPLs) relies on accelerating contaminant mass transfer from the organic to the aqueous phase, thus enhancing the depletion of DNAPL source zones compared to natural dissolution. This is achieved by promoting biological activity that reduces the contaminant's aqueous phase concentration. Although laboratory studies have demonstrated that high reaction rates are attainable by specialized microbial cultures in DNAPL source zones, field applications of the technology report lower reaction rates and prolonged remediation times. One possible explanation for this phenomenon is that the reaction rates are limited by the rate at which the contaminant partitions from the DNAPL to the aqueous phase. In such cases, slow mass transfer to the aqueous phase reduces the bioavailability of the contaminant and consequently decreases the potential source zone depletion enhancement. In this work, the effect of rate limited mass transfer on bio-enhanced dissolution of DNAPL chlorinated ethenes is investigated through a numerical study. A multi-phase, multi-component groundwater transport model is employed to simulate DNAPL mass depletion for a range of source zone scenarios. Rate limited mass transfer is modeled by a linear driving force model, employing a thermodynamic approach for the calculation of the DNAPL - water interfacial area. Metabolic reductive dechlorination is modeled by Monod kinetics, considering microbial growth and self-inhibition. The model was utilized to identify conditions in which mass transfer, rather than reaction, is the limiting process, as indicated by the bioavailability number. In such cases, reaction is slower than expected, and further increase in the reaction rate does not enhance mass depletion. Mass transfer rate limitations were shown to affect both dechlorination and microbial growth kinetics. The complex dynamics between mass transfer, DNAPL transport and distribution, and

  9. Numerical Simulation of Heat and Mass Transfer in an Ejection Apparatus

    NASA Astrophysics Data System (ADS)

    Kologrivov, M. M.; Buzovskii, V. P.

    2016-01-01

    The results of numerical simulation of heat and mass transfer in an ejection apparatus during condensation of vapor-gas mixture components on cold brine droplets are presented. The local parameters of working flows were determined by solving a system of differential heat transfer equations with account for the hydrodynamic pattern. Calculations were carried out on the assumption that the liquid spray is directed horizontally. The Stefan formula has been derived with reference to a spherical coordinate system. The results of calculation of heat and mass transfer rates with and without regard for steam condensation jointly with hydrocarbon vapors are compared and analyzed. Estimation of the effect exerted by the apparatus and drip pan walls on the general process of heat and mass transfer was carried out. The results of simulation made it possible to quantitatively estimate the influence of the adopted thickness of the diffusional boundary layer on the vapor-air mixture cooling effect.

  10. Gas-liquid mass transfer in filamentous slurries in airlift bioreactors

    SciTech Connect

    Chisti, M.Y.; Moo-Young, M. )

    1988-01-01

    Biotechnology production processes are often critically dependent on oxygen transfer in gas-liquid-solid multiphase systems. Some of these biofluid slurries are composed of fibrous or filamentous, mycelial, solids suspended in a water-like medium. Examples are the broths of Aspergilli, Penicillia, Neurospora and Streptomyces, all of which are of commercial importance. This paper reports of the gas-liquid mass transfer behaviour of aqueous slurries of cellulose fibre solids (1-3 wt./vol. % solids in 0.15 kmol m/sup -3/ NaCl) which simulate the filamentous fermentation broths of interest. Fundamental investigations into the relationship between the mass transfer coefficient (k/sub L/) and bubble diameter (d/sub B/) are undertaken. The observations can be usefully employed for scale-up of bioreactors for gas-liquid mass transfer as demonstrated in the paper.

  11. Stability of coaxial jets confined in a tube with heat and mass transfer

    NASA Astrophysics Data System (ADS)

    Mohanta, Lokanath; Cheung, Fan-Bill; Bajorek, Stephen M.

    2016-02-01

    A linear temporal stability of coaxial confined jets in a vertical tube involving heat and mass transfer at the interface is presented in this paper. A potential flow analysis that includes the effect of viscosity at the interface is performed in analyzing the stability of the system. Film boiling in a vertical tube gives rise to the flow configuration explored in this work. The effects of various non-dimensional parameters on the growth rate and the neutral curve are discussed. The heat transfer at the interface has been characterized by introducing a heat flux ratio between the conduction heat flux and the evaporation heat flux. Viscous forces and the heat and mass transfer at the interface are found to stabilize the flow both in the capillary instability region and Kelvin-Helmholtz instability region. Increasing heat and mass transfer at the interface stabilizes the flow to small as well as very large wave numbers.

  12. Rotating machinery heat and mass transfer research in the People's Republic of China

    NASA Astrophysics Data System (ADS)

    Wu, C.-H.; Ko, S.-Y.; Liu, D.; Shen, J.; Xu, J.-Z.

    A survey of research on rotating machinery heat and mass transfer in the People's Republic of China has been made. Since the later part of 1950's, considerable research and development work has been conducted in this field in China in order to improve the performance and prolong the life of rotating machinery. The emphasis of gas turbine heat transfer has been made in this survey. The water cooling of generator and the heat transfer of rotary piston engine are also included. Researches on the measuring technique of rotating machinery such as the temperature measurement, heat flux gauge, turbulence measurement, optical measurement and flow field visualization are discussed. The following topics of gas turbine heat and mass transfer are included: numerical analysis of air cooling of turbine blades, internal cooling passage heat transfer, impingment cooling, film cooling, transpiration cooling of turbine blades, cooling of blade root tenon, cooling of rotor disc, film cooling of flame tube and cooling of afterburner.

  13. Mass savings domain of plasma propulsion for LEO to GEO transfer

    SciTech Connect

    Choueiri, E.Y.; Kelly, A.J.; Jahn, R.G. )

    1993-01-20

    A parametric model is used to study the mass savings of plasma propulsion over advanced chemical propulsion for lower earth orbit (LEO) to geosynchronous orbit (GEO) transfer. Such savings are characterized by stringent requirements of massive payloads (O(10) metric tons) and high power levels (O(100) kW). Mass savings on the order of the payload mass are possible but at the expense of longer transfer times (8--20 months). Typical of the savings domain is the case of a self-field magnetoplasmadynamic (MPD) thruster running quasi-steadily, at an [ital I][sub [ital s

  14. Benign neck masses showing restricted diffusion: Is there a histological basis for discordant behavior?

    PubMed Central

    Das, Abanti; Bhalla, Ashu S; Sharma, Raju; Kumar, Atin; Sharma, Meher; Gamanagatti, Shivanand; Thakar, Alok; Sharma, Suresh

    2016-01-01

    Diffusion weighted imaging (DWI) evolved as a complementary tool to morphologic imaging by offering additional functional information about lesions. Although the technique utilizes movement of water molecules to characterize biological tissues in terms of their cellularity, there are other factors related to the histological constitution of lesions which can have a significant bearing on DWI. Benign lesions with atypical histology including presence of lymphoid stroma, inherently increased cellularity or abundant extracellular collagen can impede movement of water molecules similar to malignant tissues and thereby, show restricted diffusion. Knowledge of these atypical entities while interpreting DWI in clinical practice can avoid potential misdiagnosis. This review aims to present an imaging spectrum of such benign neck masses which, owing to their distinct histology, can show discordant behavior on DWI. PMID:26981226

  15. On the Effective Thermal Conductivity of Frost Considering Mass Diffusion and Eddy Convection

    NASA Technical Reports Server (NTRS)

    Kandula, Max

    2010-01-01

    A physical model for the effective thermal conductivity of water frost is proposed for application to the full range of frost density. The proposed model builds on the Zehner-Schlunder one-dimensional formulation for porous media appropriate for solid-to-fluid thermal conductivity ratios less than about 1000. By superposing the effects of mass diffusion and eddy convection on stagnant conduction in the fluid, the total effective thermal conductivity of frost is shown to be satisfactorily described. It is shown that the effects of vapor diffusion and eddy convection on the frost conductivity are of the same order. The results also point out that idealization of the frost structure by cylindrical inclusions offers a better representation of the effective conductivity of frost as compared to spherical inclusions. Satisfactory agreement between the theory and the measurements for the effective thermal conductivity of frost is demonstrated for a wide range of frost density and frost temperature.

  16. Facilitated Diffusion of Acetonitrile Revealed by Quantitative Breath Analysis Using Extractive Electrospray Ionization Mass Spectrometry

    PubMed Central

    Li, Ming; Ding, Jianhua; Gu, Haiwei; Zhang, Yan; Pan, Susu; Xu, Ning; Chen, Huanwen; Li, Hongmei

    2013-01-01

    By using silver cations (Ag+) as the ionic reagent in reactive extractive electrospray ionization mass spectrometry (EESI-MS), the concentrations of acetonitrile in exhaled breath samples from the volunteers including active smokers, passive smokers, and non-smokers were quantitatively measured in vivo, without any sample pretreatment. A limit of detection (LOD) and relative standard deviation (RSD) were 0.16 ng/L and 3.5% (n = 8), respectively, for the acetonitrile signals in MS/MS experiments. Interestingly, the concentrations of acetonitrile in human breath continuously increased for 1–4 hours after the smoker finished smoking and then slowly decreased to the background level in 7 days. The experimental data of a large number of (> 165) samples indicated that the inhaled acetonitrile is excreted most likely by facilitated diffusion, instead of simple diffusion reported previously for other volatile compounds. PMID:23386969

  17. A Convergence Study of Mass Transfer in a Simulated Double White Binary

    NASA Astrophysics Data System (ADS)

    Motl, Patrick M.; Tohline, J. E.; Frank, J.

    2011-01-01

    We present evolutions of a model double white dwarf binary with a low initial mass ratio (q = 0.4). We vary both the initial depth of contact (and hence the initial mass transfer rate) as well as the numerical resolution in our Eulerian hydrodynamics code. At the highest resolution of about 47 million grid cells we find that the binary has an initially growing mass transfer rate that then declines as the binary separates through the 50 orbital periods of the simulation. The lower resolution run (evolved with about 3 million cells) of the same binary also shows evidence for stable mass transfer though the mass transfer rate is significantly higher - emphasizing the importance of numerical resolution in these simulations. In this presentation we quantify the convergence of mass transfer between donor and accretor and measure the exchange of angular momentum through orbit-averaged equations. This work has been supported in part by NASA Astrophysics Theory Program grant number NNX10AC72G. The computations were performed on Teragrid and LONI facilities.

  18. Heat and mass transfer of submerged helium injection in liquid oxygen vessel

    NASA Astrophysics Data System (ADS)

    Jung, Youngsuk; Cho, Namkyung; Baek, Seungwhan; Jeong, Sangkwon

    2014-11-01

    The submerged helium injection process results in the heat and mass transfer between the helium bubble and the cryogenic liquid. The objective of this paper is to analyze the dynamics of the heat and mass transfer process. It is observed that during the helium injection process the dynamics of mass transfer is dominant and the transient heat transfer is negligible. The helium bubble shape and rising patterns are observed with a visualization device that helps to discern the dominant process between heat transfer and mass transfer. The clustering patterns such as coalescence of helium bubbles are observed with the visualization device. The visualization results indicate that, it is very difficult to determine the representative size of bubbles due to the irregular shape of the helium bubbles. The shape and size of the helium bubbles are important parameters for evaluating the overall mass transfer coefficient (kGA) which is the essential parameter for calculating the evaporation rate of the bulk liquid into the helium bubbles. In this paper, the simplified lumped model is considered to fairly approximate the evaporation rate of the cryogenic liquid into the bubbles and the cooling rate of helium injection. The empirical correlation for the average concentration (C‾A) of evaporated cryogenic liquid into the helium bubbles is presented and the overall mass transfer coefficients (kGA) are calculated as the result of the lumped model. The proposed model and empirical correlations are compared with the experimental results, and the comparison result shows good agreement with differences that are less than ±0.4 K.

  19. Heat and mass transfer in a steam-generating tube

    SciTech Connect

    Doroshchuk, V.Y.

    1990-01-01

    Reliable data on the distribution of phases of steam-water flow in a channel cross-section, on steam and water velocities, and on void fractions are almost non-existent. This paper reports that by assuming that u{sub 1}/u{sub 3} = square root {rho}{prime}/{rho}{prime}{prime} (where u{sub 1} and u{sub 3} are the velocities of steam in the flow core and of a liquid film near a wall, {rho}{prime}{prime} and {rho}{prime} are the densities of corresponding phases) and by using the limiting void fractions x{sup o}{sub lim}, the above-mentioned flow parameters can be determined analytically for the instant of onset of a heat transfer crisis of the second kind.

  20. Mitigating diffuse phosphorus transfer from agriculture according to cost and efficiency.

    PubMed

    Haygarth, P M; Apsimon, H; Betson, M; Harris, D; Hodgkinson, R; Withers, P J A

    2009-01-01

    Potential options for mitigating phosphorus (P) transfer from agriculture to water in England and Wales (E&W) were collated across a range of farm systems to assess their potential effectiveness in reducing mass of P transferred and potential cost (pounds sterling [ pound]) to the farming industry. A simple model framework (called PEASE) incorporating a number of assumptions was used to identify 15 methods for mitigating inputs of P to agricultural systems, 19 methods for preventing mobilization of P, and six methods for controlling the transport of P to streams. The scope for largest reductions in P inputs was to grassland and horticulture. Potential reductions in P mobilization were up to 1.2 kg P ha(-1). Reductions in P transfer associated with transport mitigation were larger than those associated with input and mobilization methods (up to 2.2 kg P ha(-1)). The largest estimated reductions were achieved by installing buffer zones and constructed wetlands, the former being very cost effective ( pound3-5 kg(-1) P saved). Plots of cost curves helped identify where the combined and cumulative P transfer reductions were attainable; these were approximately 0.2 kg ha(-1) for uplands, 0.6 kg ha(-1) for outdoor pigs, 0.9 kg ha(-1) for intensive dairy, and 2.2 kg ha(-1) for arable examples. We concluded that established catchment-scale evidence for mitigation is sparse, especially for specific farm systems in E&W. Sensitivities and uncertainties in the approach, especially associated with expert coefficients, are noted. This approach is nonetheless considered useful for prioritizing where and how best options might be most effectively targeted for least cost but greatest benefit. PMID:19704144

  1. Integral solutions to transient nonlinear heat (mass) diffusion with a power-law diffusivity: a semi-infinite medium with fixed boundary conditions

    NASA Astrophysics Data System (ADS)

    Hristov, Jordan

    2016-03-01

    Closed form approximate solutions to nonlinear heat (mass) diffusion equation with power-law nonlinearity of the thermal (mass) diffusivity have been developed by the integral-balance method avoiding the commonly used linearization by the Kirchhoff transformation. The main improvement of the solution is based on the double-integration technique and a new approach to the space derivative. Solutions to Dirichlet and Neumann boundary condition problems have been developed and benchmarked against exact numerical and approximate analytical solutions available in the literature.

  2. Orbital Evolution of Mass-transferring Eccentric Binary Systems. I. Phase-dependent Evolution

    NASA Astrophysics Data System (ADS)

    Dosopoulou, Fani; Kalogera, Vicky

    2016-07-01

    Observations reveal that mass-transferring binary systems may have non-zero orbital eccentricities. The time evolution of the orbital semimajor axis and eccentricity of mass-transferring eccentric binary systems is an important part of binary evolution theory and has been widely studied. However, various different approaches to and assumptions on the subject have made the literature difficult to comprehend and comparisons between different orbital element time evolution equations not easy to make. Consequently, no self-consistent treatment of this phase has ever been included in binary population synthesis codes. In this paper, we present a general formalism to derive the time evolution equations of the binary orbital elements, treating mass loss and mass transfer as perturbations of the general two-body problem. We present the self-consistent form of the perturbing acceleration and phase-dependent time evolution equations for the orbital elements under different mass loss/transfer processes. First, we study the cases of isotropic and anisotropic wind mass loss. Then, we proceed with non-isotropic ejection and accretion in a conservative as well as a non-conservative manner for both point masses and extended bodies. We compare the derived equations with similar work in the literature and explain the existing discrepancies.

  3. Thermal diffusivity of spinels at elevated temperature: implications for heat transfer in the transition zone

    NASA Astrophysics Data System (ADS)

    Hofmeister, A. M.

    2006-12-01

    The dependence of the vibrational component of thermal diffusivity (D) of spinel-family minerals on chemical composition, disorder, and temperature (T) is discerned using laser-flash measurements of single-crystals up to 1850 K, and used along with data on garnets and radiative transfer calculations to constrain heat transport in Earth's transition zone (TZ). Laser-flash analysis lacks the systematic errors associated with conventional methods, namely, corruption with radiative transfer, and thermal contact losses. Chemical compositions are synthetic disordered spinel, 4 natural samples near MgAl2O4; 4 natural hercynites (Mg,Fe,Al)3O4], nearly ZnAl2O4, and 2 magnetites [Fe3O4]. The magnetic transition is manifest as a lambda curve in 1/D, but otherwise, 1/D is described by low-order polynomial fits with temperature. Ordered, MgAl2O4 has D(298K) = 7.78 mm2/s, which should approximate that of γ-Mg2SiO4. At 298 K, D decreases strongly as cation substitution or Mg-Al disorder increases: D(298K) for ringwoodite is estimated as 5.8 mm2/s. However, above 1400 K, D becomes constant: this limit (Dsat=0.70-1.07 mm2/s) weakly depends on composition and disorder and is analogous to the Dulong-Petit limit in heat capacity (Cp). Mantle garnets have Dsat=0.65 mm2/s (Hofmeister 2006 Phys Chem Min.). To obtain TZ values, we use d(lnD)/dP= (4γth 2/3)KT, literature data on bulk modulus and thermal Gruneisen parameter, density from PREM, and Cp=1.3 J/g-K, which depends weakly on composition, T, and P. Average thermal conductivity (k)in the TZ is 5-6 W/m-K, depending on garnet proportion, and increase with P. Radiative transfer provides ca 1 W/m-K, depending on Fe content and grain-size (Hofmeister 2005 J. Geodyn.). Our estimate of large k = 6-7 W/m-K is twice recent estimates, and is a consequence of phonon saturation revealed by laser-flash measurements. Efficient vibrational transport of heat in the TZ and deeper stabilizes against convection, as does the positive temperature

  4. Modelling transport in media with heterogeneous advection properties and mass transfer with a Continuous Time Random Walk approach

    NASA Astrophysics Data System (ADS)

    Comolli, Alessandro; Moussey, Charlie; Dentz, Marco

    2016-04-01

    Transport processes in groundwater systems are strongly affected by the presence of heterogeneity. The heterogeneity leads to non-Fickian features, that manifest themselves in the heavy-tailed breakthrough curves, as well as in the non-linear growth of the mean squared displacement and in the non-Gaussian plumes of solute particles. The causes of non-Fickian transport can be the heterogeneity in the flow fields and the processes of mass exchange between mobile and immobile phases, such as sorption/desorption reactions and diffusive mass transfer. Here, we present a Continuous Time Random Walk (CTRW) model that describes the transport of solutes in d-dimensional systems by taking into account both heterogeneous advection and mobile-immobile mass transfer. In order to account for these processes in the CTRW, the heterogeneities are mapped onto a distribution of transition times, which can be decomposed into advective transition times and trapping times, the latter being treated as a compound Poisson process. While advective transition times are related to the Eulerian flow velocities and, thus, to the conductivity distribution, trapping times depend on the sorption/desorption time scale, in case of reactive problems, or on the distribution of diffusion times in the immobile zones. Since the trapping time scale is typically much larger than the advective time scale, we observe the existence of two temporal regimes. The pre-asymptotic regime is defined by a characteristic time scale at which the properties of transport are fully determined by the heterogeneity of the advective field. On the other hand, in the asymptotic regime both the heterogeneity and the mass exchange processes play a role in conditioning the behaviour of transport. We consider different scenarios to discuss the relative importance of the advective heterogeneity and the mass transfer for the occurrence of non-Fickian transport. For each case we calculate analytically the scalings of the breakthrough

  5. Mass Conservation in Modeling Moisture Diffusion in Multi-Layer Carbon Composite Structures

    NASA Technical Reports Server (NTRS)

    Nurge, Mark A.; Youngquist, Robert C.; Starr, Stanley O.

    2009-01-01

    Moisture diffusion in multi-layer carbon composite structures is difficult to model using finite difference methods due to the discontinuity in concentrations between adjacent layers of differing materials. Applying a mass conserving approach at these boundaries proved to be effective at accurately predicting moisture uptake for a sample exposed to a fixed temperature and relative humidity. Details of the model developed are presented and compared with actual moisture uptake data gathered over 130 days from a graphite epoxy composite sandwich coupon with a Rohacell foam core.

  6. Radiative transfer modeling of direct and diffuse sunlight in a Siberian pine forest

    NASA Astrophysics Data System (ADS)

    Alton, P. B.; North, P.; Kaduk, J.; Los, S.

    2005-12-01

    We have expanded the Monte Carlo, ray-tracing model FLIGHT in order to simulate photosynthesis within three-dimensional, heterogeneous tree canopies. In contrast to the simple radiative transfer schemes adopted in many land-surface models (e.g., the Big Leaf approximation), our simulation calculates explicitly the leaf irradiance at different heights within the canopy and thus produces an accurate scale-up in photosynthesis from leaf to canopy level. We also account for both diffuse and direct sunlight. For a Siberian stand of Scots pine Pinus sylvestris, FLIGHT predicts observed carbon assimilation, across the full range of sky radiance, with an r.m.s. error of 12%. Our main findings for this sparse canopy, using both measurements and model, are as follows: (1) Observationally, we detect a light-use efficiency (LUE) increase of only ≤10% for the canopy when the proportion of diffuse sky radiance is 75% rather than 25%. The corresponding enhancement predicted by our simulations is 10-20%. With such small increases in LUE, our site will not assimilate more carbon on overcast days compared to seasonally equivalent sunny days; (2) the scale-up in photosynthesis from top-leaf to canopy is less than unity. The Big Leaf approximation, based on Beer's law and light-acclimated leaf nitrogen, overpredicts this scale-up by ≥60% for low sky radiance (≤500 μmolPAR m-2 s-1); (3) when leaf nitrogen is distributed so as to maximize canopy photosynthesis, the increase in the canopy carbon assimilation, compared with a uniform nitrogen distribution, is small (≃4%). Maximum assimilation occurs when the vertical gradient of leaf nitrogen is slightly shallower than that of the light profile.

  7. Isotopic mass-dependence of metal cation diffusion coefficients in liquid water

    SciTech Connect

    Bourg, I.C.; Richter, F.M.; Christensen, J.N.; Sposito, G.

    2009-01-11

    Isotope distributions in natural systems can be highly sensitive to the mass (m) dependence of solute diffusion coefficients (D) in liquid water. Isotope geochemistry studies routinely have assumed that this mass dependence either is negligible (as predicted by hydrodynamic theories) or follows a kinetic-theory-like inverse square root relationship (D {proportional_to} m{sup -0.5}). However, our recent experimental results and molecular dynamics (MD) simulations showed that the mass dependence of D is intermediate between hydrodynamic and kinetic theory predictions (D {proportional_to} m{sup -{beta}} with 0 {<=} {beta} < 0.2 for Li{sup +}, Cl{sup -}, Mg{sup 2+}, and the noble gases). In this paper, we present new MD simulations and experimental results for Na{sup +}, K{sup +}, Cs{sup +}, and Ca{sup 2+} that confirm the generality of the inverse power-law relation D {proportional_to} m{sup -{beta}}. Our new findings allow us to develop a general description of the influence of solute valence and radius on the mass dependence of D for monatomic solutes in liquid water. This mass dependence decreases with solute radius and with the magnitude of solute valence. Molecular-scale analysis of our MD simulation results reveals that these trends derive from the exponent {beta} being smallest for those solutes whose motions are most strongly coupled to solvent hydrodynamic modes.

  8. On the upscaling of mass transfer rate expressions for interpretation of source zone partitioning tracer tests

    NASA Astrophysics Data System (ADS)

    Boroumand, Ali; Abriola, Linda M.

    2015-02-01

    Analysis of partitioning tracer tests conducted in dense nonaqueous phase liquid (DNAPL) source zones relies on conceptual models that describe mass exchange between the DNAPL and aqueous phases. Such analysis, however, is complicated by the complex distribution of entrapped DNAPL mass and formation heterogeneity. Due to parameter uncertainty in heterogeneous regions and the desire to reduce model complexity, the effect of mass transfer limitations is often neglected, and an equilibrium-based model is typically used to interpret test results. This work explores the consequences of that simplifying assumption on test data interpretation and develops an alternative upscaled modeling approach to quantify effective mass transfer rates. To this end, a series of partitioning tracer tests is numerically simulated in heterogeneous two-dimensional PCE-DNAPL source zones, representative of a range of hydraulic conductivity and DNAPL mass distribution characteristics. The effective mass transfer coefficient corresponding to each test is determined by fitting an upscaled model to the simulated data, and regression analysis is performed to explore the correlation between various source zone metrics and the effective mass transfer coefficient. Results suggest that vertical DNAPL spreading, Reynolds number, pool fraction, and the effective organic phase saturation are the most significant parameters controlling tracer partitioning rates. Finally, a correlation for prediction of the effective (upscaled) mass transfer coefficient is proposed and verified using existing experimental data. The developed upscaled model incorporates the influence of physical heterogeneity on the rate of tracer partitioning and, thus, can be used for the estimation of source zone mass distribution characteristics from tracer test results.

  9. Upscaling transport with mass transfer models: Mean behavior and propagation of uncertainty

    NASA Astrophysics Data System (ADS)

    Fernã Ndez-Garcia, D.; Llerar-Meza, G.; Gómez-HernáNdez, J. Jaime

    2009-10-01

    The choice of an adequate large-scale conceptual transport model constitutes a major challenge associated with the upscaling of solute transport. Among the different alternatives to the classical advection-dispersion model, the (multirate) mass transfer model has been proposed as a valuable and convenient alternative to model the large-scale behavior of solute transport. This paper evaluates the use of mass transfer models as a constitutive equation for upscaling solute transport. To achieve this, we compare Monte Carlo simulations of solute transport at two different support scales. Transport simulations performed at the smallest scale represent a set of reference transport solutions described at a high resolution, which are contrasted against transport simulations obtained using an upscaled model (low resolution). Several formulations of the multirate mass transfer model, which differ in the type of memory function (single rate, double rate, and truncated power law), are used as a constitutive transport equation. The large-scale scenario represents a simplified model obtained by partially homogenizing the reference solution. Results show that the double-rate and the truncated power law mass transfer models are capable of properly describing the ensemble average behavior of the main features associated with the integrated breakthrough curves. However, the uncertainty associated with the upscaled mass transfer models was substantially smaller than that attributed to the reference solution. Importantly, the cumulative distribution function of concentrations associated with the upscaled model follows a distribution similar to the reference solution but with smaller statistical dispersion. The reason is that while appropriate memory functions can be used to preserve the residence time distribution of mass particles during upscaling, the lack of memory in space prevents the model from reproducing mass fluxes in all directions. Specifically, the reproduction of mass

  10. Bridge Frost Prediction by Heat and Mass Transfer Methods

    NASA Astrophysics Data System (ADS)

    Greenfield, Tina M.; Takle, Eugene S.

    2006-03-01

    Frost on roadways and bridges can present hazardous conditions to motorists, particularly when it occurs in patches or on bridges when adjacent roadways are clear of frost. To minimize materials costs, vehicle corrosion, and negative environmental impacts, frost-suppression chemicals should be applied only when, where, and in the appropriate amounts needed to maintain roadways in a safe condition for motorists. Accurate forecasts of frost onset times, frost intensity, and frost disappearance (e.g., melting or sublimation) are needed to help roadway maintenance personnel decide when, where, and how much frost-suppression chemical to use. A finite-difference algorithm (BridgeT) has been developed that simulates vertical heat transfer in a bridge based on evolving meteorological conditions at its top and bottom as supplied by a weather forecast model. BridgeT simulates bridge temperatures at numerous points within the bridge (including its upper and lower surface) at each time step of the weather forecast model and calculates volume per unit area (i.e., depth) of deposited, melted, or sublimed frost. This model produces forecasts of bridge surface temperature, frost depth, and bridge condition (i.e., dry, wet, icy/snowy). Bridge frost predictions and bridge surface temperature are compared with observed and measured values to assess BridgeT's skill in forecasting bridge frost and associated conditions.

  11. Microfluidic bubbler facilitates near complete mass transfer for sustainable multiphase and microbial processing.

    PubMed

    Baker, Jordan J; Crivellari, Francesca; Gagnon, Zachary; Betenbaugh, Michael J

    2016-09-01

    A microfluidic device (channels <70 μm) was utilized to create micro-scale bubbles to significantly increase mass transfer efficiency at low flow rates. The convergence of one gas and two liquid channels at a Y-junction generates bubbles via cyclic changes in pressure. At low flow rates, the bubbles had an average diameter of 110 μm, corresponding to a volumetric mass transfer KL a of 1.43 h(-1) . Values of KL a normalized per flow rate showed that the microbubbler had a 100-fold increased transfer efficiency compared to four other commonly used bubblers. The calculated percentage of oxygen transferred was approximately 90%, which was consistent with a separate off-gas analysis. The improved mass transfer was also tested in an algae bioreactor in which the microbubbler absorbed approximately 90% of the CO2 feed compared to 2% in the culture with an alternative needle bubbling method. The microbubbler yielded a cell density 82% of the cell density for the alternative needle tip with an 800-fold lower flow rate (0.5 mL/min versus 400 mL/min) and a 700-fold higher ratio of biomass to fed carbon dioxide. The application of microfluidics may transform interfacial processing in order to increase mass transfer efficiencies, minimize gas feeding, and provide for more sustainable multiphase processes. Biotechnol. Bioeng. 2016;113: 1924-1933. © 2016 Wiley Periodicals, Inc. PMID:26928403

  12. Mathematical simulation of convective-radiative heat transfer in a ventilated rectangular cavity with consideration of internal mass transfer

    NASA Astrophysics Data System (ADS)

    Sheremet, M. A.; Shishkin, N. I.

    2012-07-01

    Mathematical simulation of the nonstationary regimes of heat-and-mass transfer in a ventilated rectangular cavity with heat-conducting walls of finite thickness in the presence of a heat-generating element of constant temperature has been carried out with account for the radiative heat transfer in the Rosseland approximation. As mechanisms of energy transfer in this cavity, the combined convection and the thermal radiation in the gas space of the cavity and the heat conduction in the elements of its fencing solid shell were considered. The mathematical model formulated in the dimensionless stream function-vorticity vector-temperature-concentration variables was realized numerically with the use of the finite-difference method. The streamline, temperature-field, and concentration distributions reflecting the influence of the Rayleigh number (Ra = 104, 105, 106), the nonstationarity (0 < τ ≤ 1000), and the optical thickness of the medium (τλ = 50, 100, 200) on the regimes of the gas flow and the heat-and-mass transfer in the cavity have been obtained.

  13. Heat/Mass Transfer Measurement on The Tip Surface Of Rotor Blade With Squlear Rim

    NASA Astrophysics Data System (ADS)

    Park, Jun Su; Lee, Dong Hyun; Lee, Woo Jin; Cho, Hyung Hee; Rhee, Dong-Ho; Kang, Shin-Hyung

    2010-06-01

    The present study investigates local heat/mass transfer characteristics on blade tip surface with squealer rim. A linear cascade experimental setup consists of three large scale airfoils was used. The axial chord length and turning angle of test blade are 237 mm and 126°, respectively. Heat/mass transfer coefficients were measured with three different rim heights (3%, 6% and 9% of axial chord length) and fixed tip clearance (2% of axial chord length). Main flow Reynolds number based on axial chord length is 1.5×105. Naphthalene sublimation method is used to measure the detailed mass transfer coefficient on the blade tip surface. The heat/mass transfer results show that as the rim height increases, the peak values on the upstream region of the tip surface decreases and moves to the suction side rim. At the downstream region of the tip surface, the pitch-wise averaged heat/mass transfer coefficients increases as the rim height increases.

  14. Effect of electric fields on mass transfer to droplets. Final report

    SciTech Connect

    Carleson, T.E.; Budwig, R.

    1994-02-01

    During the six year funding period, the effects of a direct and alternating field upon single drop hydrodynamics and mass transfer were evaluated both experimentally and theoretically. Direct current field effects upon drop size, velocity and mass transfer rates were also observed for multiple drops formed in a three stage sieve tray column. Drop size, velocity, and mass transfer rates were measured experimentally and compared to simple models for direct current electric fields. Agreement between theory and experiment was found for drop charge, size, and velocity. Drop mass transfer coefficients were substantially larger than theoretical predictions while extraction efficiencies were moderately higher. Drop distortion and oscillation were observed and are thought to result in the experimentally observed higher values. For alternating current fields, drop flow streamlines and oscillations were measured and found to compare well with predictions from a solved mathematical model. In addition, equipment was constructed to determine mass transfer rates to oscillating drops. Concentration profiles in still and oscillating drops were measured and qualitatively compared to theoretical predictions.

  15. Theoretical approach for enhanced mass transfer effects in-duct flue gas desulfurization processes

    SciTech Connect

    Not Available

    1990-08-22

    While developing dry sorbent duct injection flue gas desulfurization processes may offer significant improvement in capital cost and process simplicity compared to wet scrubbing systems, the economics of this technology can be improved significantly by an improvement in sorbent utilization. While a general understanding of the mechanism by which the sorbents operate is known, a much more detailed knowledge of reaction rate-controlling phenomena, the role of inherent reactivity, and mass transfer effects and their interaction in needed. Objectives of this project are threefold: 1. Mass transfer investigation--determine the controlling physical and chemical processes that limit sorbent utilization. In particular, determine whether mass transfer is a controlling factor in in-duct flue gas desulfurization and establish the relative contributions of gas- and liquid-phase mass transfer and inherent sorbent reactivity. 2. Field test support--evaluate various sorbents, operating conditions and process schemes to support large-scale field testings at Meredosia and Beverly. 3. Mass transfer enhancement--examine various techniques that will enable sorbent utilization rates of at least 75 percent to be achieved. Sorbents investigated were Ca(OH){sub 2}, Mississippi hydrate and Mississippi slaked lime. Epsom Salt was investigated as an additive. Agglomeration of Ca(OH){sub 2} solids was also investigated. 3 refs., 92 figs., 23 tabs.

  16. Understanding and controlling airborne organic compounds in the indoor environment: mass transfer analysis and applications.

    PubMed

    Zhang, Y; Xiong, J; Mo, J; Gong, M; Cao, J

    2016-02-01

    Mass transfer is key to understanding and controlling indoor airborne organic chemical contaminants (e.g., VVOCs, VOCs, and SVOCs). In this study, we first introduce the fundamentals of mass transfer and then present a series of representative works from the past two decades, focusing on the most recent years. These works cover: (i) predicting and controlling emissions from indoor sources, (ii) determining concentrations of indoor air pollutants, (iii) estimating dermal exposure for some indoor gas-phase SVOCs, and (iv) optimizing air-purifying approaches. The mass transfer analysis spans the micro-, meso-, and macroscales and includes normal mass transfer modeling, inverse problem solving, and dimensionless analysis. These representative works have reported some novel approaches to mass transfer. Additionally, new dimensionless parameters such as the Little number and the normalized volume of clean air being completely cleaned in a given time period were proposed to better describe the general process characteristics in emissions and control of airborne organic compounds in the indoor environment. Finally, important problems that need further study are presented, reflecting the authors' perspective on the research opportunities in this area. PMID:25740682

  17. Influence of mass diffusion on the stability of thermophoretic growth of a solid from the vapor phase

    NASA Technical Reports Server (NTRS)

    Castillo, J. L.; Garcia-Ybarra, P. L.; Rosner, D. E.

    1991-01-01

    The stability of solid planar growth from a binary vapor phase with a condensing species dilute in a carrier gas is examined when the ratio of depositing to carrier species molecular mass is large and the main diffusive transport mechanism is thermal diffusion. It is shown that a deformation of the solid-gas interface induces a deformation of the gas phase isotherms that increases the thermal gradients and thereby the local mass deposition rate at the crests and reduces them at the valleys. The initial surface deformation is enhanced by the modified deposition rates in the absence of appreciable Fick/Brownian diffusion and interfacial energy effects.

  18. A NUMERICAL METHOD FOR STUDYING SUPER-EDDINGTON MASS TRANSFER IN DOUBLE WHITE DWARF BINARIES

    SciTech Connect

    Marcello, Dominic C.; Tohline, Joel E. E-mail: tohline@phys.lsu.edu

    2012-04-01

    We present a numerical method for the study of double white dwarf (DWD) binary systems at the onset of super-Eddington mass transfer. We incorporate the physics of ideal inviscid hydrodynamical flow, Newtonian self-gravity, and radiation transport on a three-dimensional uniformly rotating cylindrical Eulerian grid. Care has been taken to conserve the key physical quantities such as angular momentum and energy. Our new method conserves total energy to a higher degree of accuracy than other codes that are presently being used to model mass transfer in DWD systems. We present the results of verification tests and simulate the first 20 + orbits of a binary system of mass ratio q 0.7 at the onset of dynamically unstable direct impact mass transfer. The mass transfer rate quickly exceeds the critical Eddington limit by many orders of magnitude, and thus we are unable to model a trans-Eddington phase. It appears that radiation pressure does not significantly affect the accretion flow in the highly super-Eddington regime. An optically thick common envelope forms around the binary within a few orbits. Although this envelope quickly exceeds the spatial domain of the computational grid, the fraction of the common envelope that exceeds zero gravitational binding energy is extremely small, suggesting that radiation-driven mass loss is insignificant in this regime. It remains to be seen whether simulations that capture the trans-Eddington phase of such flows will lead to the same conclusion or show that substantial material gets expelled.

  19. Analysis of the moisture diffusion transfer through fibrous porous membrane used for waterproof breathable fabrics

    NASA Astrophysics Data System (ADS)

    Zhu, Fanglong; Zhou, Yu; Liu, Suyan

    2013-10-01

    In this paper, we propose a new fractal model to determine the moisture effective diffusivity of porous membrane such as expanded polytetrafluorethylene membrane, by taking account of both parallel and perpendicular channels to diffusion flow direction. With the consideration of both the Knudsen and bulk diffusion effect, a relationship between micro-structural parameters and effective moisture diffusivity is deduced. The effective moisture diffusivities predicted by the present fractal model are compared with moisture diffusion experiment data and calculated values obtained from other theoretical models.

  20. A new, coupled transport-diffusion method for radiative transfer calculations

    SciTech Connect

    Wollaber, A. B.; Warsa, J. S.

    2013-07-01

    We derive and present a new frequency- and angle-integrated low-order system of equations designed to enhance the accuracy of a coupled, high-order (transport) solution of the thermal radiative transfer equations. In particular, our new low-order system is designed to use intensity-weighted opacities and anisotropic diffusion coefficients generated by a solution of the Implicit Monte Carlo (IMC) equations in order to predict the spatial dependence of the material temperature and radiation energies in the ensuing time cycle. The predicted temperature solution can then be exploited to generate appropriately time-centered opacities, specific heats, and Planck emission spectra for the upcoming IMC solution. Additionally, the relatively inexpensive solution of the low-order system can be iteratively solved to recommend an adaptive time step size before the IMC solution is computed. A test implementation has been implemented using existing software available from the Jayenne and Capsaicin projects at Los Alamos National Laboratory. We present initial results from a new driver code that has integrated these stochastic and deterministic software packages. (authors)

  1. A grey diffusion acceleration method for time-dependent radiative transfer calculations

    SciTech Connect

    Nowak, P.F.

    1991-07-01

    The equations of thermal radiative transfer describe the emission, absorption and transport of photons in a material. As photons travel through the material they are absorbed and re-emitted in a Planckian distribution characterized by the material temperature. As a result of these processes, the material can change resulting in a change in the Planckian emission spectrum. When the coupling between the material and radiation is strong, as occurs when the material opacity or the time step is large, standard iterative techniques converge very slowly. As a result, nested iterative algorithms have been applied to the problem. One algorithm, is to use multifrequency DSA to accelerate the convergence of the multifrequency transport iteration and a grey transport acceleration (GTA) followed by a single group DSA. Here we summarize a new method which uses a grey diffusion equation (GDA) to directly solve the multifrequency transport (S{sub N}) problem. Results of Fourier analysis for both the continuous and discretized equations are discussed and the computational efficiency of GDA is compared with the DSA and GTA nested algorithms. 5 refs., 1 fig., 1 tab.

  2. Seasonal changes of thermal diffusivity and their effect on heat transfer in soils

    NASA Astrophysics Data System (ADS)

    Dedecek, Petr; Correia, Antonio; Safanda, Jan; Cermak, Vladimir; Rajver, Dusan; Pechacova, Blanka

    2016-04-01

    The aim of the work is to describe the effects of seasonal changes of thermal diffusivity (TD) on the thermal regime in shallow subsurface soils. The long term temperature series from observatories at Prague (Czechia), Evora (Portugal) and Malence (Slovenia) were processed by newly improved code which enables a detailed calculation of time changes of TD of the soils. To determine the effect of climate warming of the recent years and to describe the possible effect of TD changes on the temperature-depth profiles, time dependent numerical models were computed. In the case of Evora, the effect of the TD changes on mean annual temperatures was confirmed. This observatory is located on bare sandy surface and TD in the upper soil layer significantly decreases (up to 50%) in summer months. It is due to local climate, which is typical by alternating winter/wet and summer/dry periods. The negative temperature gradient in the depth of 2-5 cm increases with TD decreasing, the coefficient of determination is 0.6 (2012). The TD decreasing during the summer months substitutes the effect of vegetation and controls the heat transfer to the subsurface. The climate in Prague and Malence is typical by rainy/snowy periods during the whole year and effect of TD changes in bare sandy soils is only short-term, or even insignificant under grassy surfaces.

  3. Radiative transfer equation modeling by streamline diffusion modified continuous Galerkin method

    NASA Astrophysics Data System (ADS)

    Long, Feixiao; Li, Fengyan; Intes, Xavier; Kotha, Shiva P.

    2016-03-01

    Optical tomography has a wide range of biomedical applications. Accurate prediction of photon transport in media is critical, as it directly affects the accuracy of the reconstructions. The radiative transfer equation (RTE) is the most accurate deterministic forward model, yet it has not been widely employed in practice due to the challenges in robust and efficient numerical implementations in high dimensions. Herein, we propose a method that combines the discrete ordinate method (DOM) with a streamline diffusion modified continuous Galerkin method to numerically solve RTE. Additionally, a phase function normalization technique was employed to dramatically reduce the instability of the DOM with fewer discrete angular points. To illustrate the accuracy and robustness of our method, the computed solutions to RTE were compared with Monte Carlo (MC) simulations when two types of sources (ideal pencil beam and Gaussian beam) and multiple optical properties were tested. Results show that with standard optical properties of human tissue, photon densities obtained using RTE are, on average, around 5% of those predicted by MC simulations in the entire/deeper region. These results suggest that this implementation of the finite element method-RTE is an accurate forward model for optical tomography in human tissues.

  4. Radiative transfer equation modeling by streamline diffusion modified continuous Galerkin method.

    PubMed

    Long, Feixiao; Li, Fengyan; Intes, Xavier; Kotha, Shiva P

    2016-03-01

    Optical tomography has a wide range of biomedical applications. Accurate prediction of photon transport in media is critical, as it directly affects the accuracy of the reconstructions. The radiative transfer equation (RTE) is the most accurate deterministic forward model, yet it has not been widely employed in practice due to the challenges in robust and efficient numerical implementations in high dimensions. Herein, we propose a method that combines the discrete ordinate method (DOM) with a streamline diffusion modified continuous Galerkin method to numerically solve RTE. Additionally, a phase function normalization technique was employed to dramatically reduce the instability of the DOM with fewer discrete angular points. To illustrate the accuracy and robustness of our method, the computed solutions to RTE were compared with Monte Carlo (MC) simulations when two types of sources (ideal pencil beam and Gaussian beam) and multiple optical properties were tested. Results show that with standard optical properties of human tissue, photon densities obtained using RTE are, on average, around 5% of those predicted by MC simulations in the entire/deeper region. These results suggest that this implementation of the finite element method-RTE is an accurate forward model for optical tomography in human tissues. PMID:26953662

  5. Effect of impeller geometry on gas-liquid mass transfer coefficients in filamentous suspensions.

    PubMed

    Dronawat, S N; Svihla, C K; Hanley, T R

    1997-01-01

    Volumetric gas-liquid mass transfer coefficients were measured in suspensions of cellulose fibers with concentrations ranging from 0 to 20 g/L. The mass transfer coefficients were measured using the dynamic method. Results are presented for three different combinations of impellers at a variety of gassing rates and agitation speeds. Rheological properties of the cellulose fibers were also measured using the impeller viscometer method. Tests were conducted in a 20 L stirred-tank fermentor and in 65 L tank with a height to diameter ratio of 3:1. Power consumption was measured in both vessels. At low agitation rates, two Rushton turbines gave 20% better performance than the Rushton and hydrofoil combination and 40% better performance than the Rushton and propeller combination for oxygen transfer. At higher agitation rates, the Rushton and hydrofoil combination gave 14 and 25% better performance for oxygen transfer than two Rushton turbines and the Rushton and hydrofoil combination, respectively. PMID:18576095

  6. Multi-Scale Modeling and the Eddy-Diffusivity/Mass-Flux (EDMF) Parameterization

    NASA Astrophysics Data System (ADS)

    Teixeira, J.

    2015-12-01

    Turbulence and convection play a fundamental role in many key weather and climate science topics. Unfortunately, current atmospheric models cannot explicitly resolve most turbulent and convective flow. Because of this fact, turbulence and convection in the atmosphere has to be parameterized - i.e. equations describing the dynamical evolution of the statistical properties of turbulence and convection motions have to be devised. Recently a variety of different models have been developed that attempt at simulating the atmosphere using variable resolution. A key problem however is that parameterizations are in general not explicitly aware of the resolution - the scale awareness problem. In this context, we will present and discuss a specific approach, the Eddy-Diffusivity/Mass-Flux (EDMF) parameterization, that not only is in itself a multi-scale parameterization but it is also particularly well suited to deal with the scale-awareness problems that plague current variable-resolution models. It does so by representing small-scale turbulence using a classic Eddy-Diffusivity (ED) method, and the larger-scale (boundary layer and tropospheric-scale) eddies as a variety of plumes using the Mass-Flux (MF) concept.

  7. Ambipolar diffusion in low-mass star formation. I. General comparison with the ideal magnetohydrodynamic case

    NASA Astrophysics Data System (ADS)

    Masson, J.; Chabrier, G.; Hennebelle, P.; Vaytet, N.; Commerçon, B.

    2016-03-01

    Angular momentum transport and the formation of rotationally supported structures are major issues in our understanding of protostellar core formation. Whereas purely hydrodynamical simulations lead to large Keplerian disks, ideal magnetohydrodynamics (MHD) models yield the opposite result, with essentially no disk formation. This stems from the flux-freezing condition in ideal MHD, which leads to strong magnetic braking. In this paper, we provide a more accurate description of the evolution of the magnetic flux redistribution by including resistive terms in the MHD equations. We focus more particularly on the effect of ambipolar diffusion on the properties of the first Larson core and its surrounding structure, exploring various initial magnetisations and magnetic field versus rotation axis orientations of a 1 M⊙ collapsing prestellar dense core. We used the non-ideal magnetohydrodynamics version of the adaptive mesh refinement code RAMSES to carry out these calculations. The resistivities required to calculate the ambipolar diffusion terms were computed using a reduced chemical network of charged, neutral, and grain species. Including ambipolar diffusion leads to the formation of a magnetic diffusion barrier (also known as the decoupling stage) in the vicinity of the core, which prevents accumulation of magnetic flux in and around the core and amplification of the field above 0.1 G. The mass and radius of the first Larson core, however, remain similar between ideal and non-ideal MHD models. This diffusion plateau, preventing further amplification of the field and reorganising the field topology, has crucial consequences for magnetic braking processes, allowing the formation of disk structures. Magnetically supported outflows launched in ideal MHD models are weakened or even disappear when using non-ideal MHD. In contrast to ideal MHD calculations, misalignment between the initial rotation axis and the magnetic field direction does not significantly affect the

  8. A holographic interferometric method to study combined heat and mass transfer in film sorption

    NASA Astrophysics Data System (ADS)

    Zheng, G.; Worek, W. M.

    1992-08-01

    Sorption by a liquid desiccant is a key process in open-cycle, liquid desiccant cooling systems. In order to study the absorption rates in a liquid desiccant, a fiber-optic, double-wavelength holographic interferometric method was developed and used to measure the combined heat and mass transfer processes that occurred during a regeneration process. In the experiment, the heat and mass transfer processes that occur at the interface between a dry air stream and either a liquid desiccant or a film of water are investigated. The temperature and concentration distribution were calculated and the results were used to determine the Lewis number Le and the local heat and mass transfer coefficients.

  9. Thermodynamics and mass transfer kinetics of phenol in reversed phase liquid chromatography

    SciTech Connect

    Kaczmarski, Krzysztof; Gritti, Fabrice; Guiochon, Georges A

    2006-05-01

    The thermodynamics and the mass transfer kinetics of the chromatographic system made of phenol, in a water-acetonitrile mobile phase, on a C18 RPLC column, were studied in the temperature range from 21 to 77 C and the interstitial velocity range of 0.021 to 1.27 cm/s. The equilibrium isotherm was accurately approximated by a multilayer model assuming lateral interactions between adsorbed molecules. The parameters of the kinetics of the phenol mass transfer in this column were measured by the method of moments. These data were analyzed using the available models and correlations. It was proven that the parameters of the mass transfer kinetics measured under linear conditions could be successfully used for the prediction of the concentration profiles obtained under overloaded conditions.

  10. Stagnation Point Flow and Mass Transfer with Chemical Reaction past a Stretching/Shrinking Cylinder

    PubMed Central

    Najib, Najwa; Bachok, Norfifah; Arifin, Norihan Md.; Ishak, Anuar

    2014-01-01

    This paper is about the stagnation point flow and mass transfer with chemical reaction past a stretching/shrinking cylinder. The governing partial differential equations in cylindrical form are transformed into ordinary differential equations by a similarity transformation. The transformed equations are solved numerically using a shooting method. Results for the skin friction coefficient, Schmidt number, velocity profiles as well as concentration profiles are presented for different values of the governing parameters. Effects of the curvature parameter, stretching/shrinking parameter and Schmidt number on the flow and mass transfer characteristics are examined. The study indicates that dual solutions exist for the shrinking cylinder but for the stretching cylinder, the solution is unique. It is observed that the surface shear stress and the mass transfer rate at the surface increase as the curvature parameter increases. PMID:24569547

  11. Influence of fluid dynamic conditions on enzymatic hydrolysis of lignocellulosic biomass: Effect of mass transfer rate.

    PubMed

    Wojtusik, Mateusz; Zurita, Mauricio; Villar, Juan C; Ladero, Miguel; Garcia-Ochoa, Felix

    2016-09-01

    The effect of fluid dynamic conditions on enzymatic hydrolysis of acid pretreated corn stover (PCS) has been assessed. Runs were performed in stirred tanks at several stirrer speed values, under typical conditions of temperature (50°C), pH (4.8) and solid charge (20% w/w). A complex mixture of cellulases, xylanases and mannanases was employed for PCS saccharification. At low stirring speeds (<150rpm), estimated mass transfer coefficients and rates, when compared to chemical hydrolysis rates, lead to results that clearly show low mass transfer rates, being this phenomenon the controlling step of the overall process rate. However, for stirrer speed from 300rpm upwards, the overall process rate is controlled by hydrolysis reactions. The ratio between mass transfer and overall chemical reaction rates changes with time depending on the conditions of each run. PMID:27233094

  12. A Novel Model for the Mass Transfer of Articular Cartilage: Rolling Depression Load Device

    NASA Astrophysics Data System (ADS)

    Fan, Zhenmin; Zhang, Chunqiu; Liu, Haiying; Xu, Baoshan; Li, Jiang; Gao, Lilan

    The mass transfer is one of important aspects to maintain the physiological activity proper of tissue, specially, cartilage cannot run without mechanical environment. The mechanical condition drives nutrition in and waste out in the cartilage tissue, the change of this process plays a key role for biological activity. Researchers used to adopt compression to study the mass transfer in cartilage, here we firstly establish a new rolling depression load (RDL) device, and also put this device into practice. The device divided into rolling control system and the compression adjusting mechanism. The rolling control system makes sure the pure rolling and uniform speed of roller applying towards cultured tissue. The compression adjusting mechanism can realize different compressive magnitudes and uniform compression. Preliminary test showed that rolling depression load indeed enhances the process of mass transfer articular cartilage.

  13. Permanently reconfigured metamaterials due to terahertz induced mass transfer of gold.

    PubMed

    Strikwerda, Andrew C; Zalkovskij, Maksim; Iwaszczuk, Krzysztof; Lorenzen, Dennis Lund; Jepsen, Peter Uhd

    2015-05-01

    We present a new technique for permanent metamaterial reconfiguration via optically induced mass transfer of gold. This mass transfer, which can be explained by field-emission induced electromigration, causes a geometric change in the metamaterial sample. Since a metamaterial's electromagnetic response is dictated by its geometry, this structural change massively alters the metamaterial's behavior. We show this by optically forming a conducting pathway between two closely spaced dipole antennas, thereby changing the resonance frequency by a factor of two. After discussing the physics of the process, we conclude by presenting an optical fuse that can be used as a sacrificial element to protect sensitive components, demonstrating the applicability of optically induced mass transfer for device design. PMID:25969252

  14. Plasma phospholipid mass transfer rate: relationship to plasma phospholipid and cholesteryl ester transfer activities and lipid parameters.

    PubMed

    Cheung, M C; Wolfbauer, G; Albers, J J

    1996-09-27

    Human plasma phospholipid transfer protein (PLTP) has been shown to facilitate the transfer of phospholipid from liposomes or isolated very low and low density lipoproteins to high density lipoproteins. Its activity in plasma and its physiological function are presently unknown. To elucidate the role of PLTP in lipoprotein metabolism and to delineate factors that may affect the rate of phospholipid transfer between lipoproteins, we determined the plasma phospholipid mass transfer rate (PLTR) in 16 healthy adult volunteers and assessed its relationship to plasma lipid levels, and to phospholipid transfer activity (PLTA) and cholesteryl ester transfer activity (CETA) measured by radioassays. The plasma PLTR in these subjects was 27.2 +/- 11.8 nmol/ml per h at 37 degrees C (mean +/- S.D.), and their PLTA and CETA were 13.0 +/- 1.7 mumol/ml per h and 72.8 +/- 15.7 nmol/ml per h, respectively. Plasma PLTR was correlated directly with total, non-HDL, and HDL triglyceride (rs = 0.76, P < 0.001), total and non-HDL phospholipid (rs > 0.53, P < 0.05), and inversely with HDL free cholesterol (rs = -0.54, P < 0.05), but not with plasma PLTA and CETA. When 85% to 96% of the PLTA in plasma was removed by polyclonal antibodies against recombinant human PLTP, phospholipid mass transfer from VLDL and LDL to HDL was reduced by 50% to 72%, but 80% to 100% of CETA could still be detected. These studies demonstrate that PLTP plays a major role in facilitating the transfer of phospholipid between lipoproteins, and suggest that triglyceride is a significant modulator of intravascular phospholipid transport. Furthermore, most of the PLTP and CETP in human plasma is associated with different particles. Plasma PLTA and CETA were also measured in mouse, rat, hamster, guinea pig, rabbit, dog, pig, and monkey. Compared to human, PLTA in rat and mouse was significantly higher and in rabbit and guinea pig was significantly lower while the remaining animal species had PLTA similar to humans. No

  15. A 17-billion-solar-mass black hole in a group galaxy with a diffuse core.

    PubMed

    Thomas, Jens; Ma, Chung-Pei; McConnell, Nicholas J; Greene, Jenny E; Blakeslee, John P; Janish, Ryan

    2016-04-21

    Quasars are associated with and powered by the accretion of material onto massive black holes; the detection of highly luminous quasars with redshifts greater than z = 6 suggests that black holes of up to ten billion solar masses already existed 13 billion years ago. Two possible present-day 'dormant' descendants of this population of 'active' black holes have been found in the galaxies NGC 3842 and NGC 4889 at the centres of the Leo and Coma galaxy clusters, which together form the central region of the Great Wall--the largest local structure of galaxies. The most luminous quasars, however, are not confined to such high-density regions of the early Universe; yet dormant black holes of this high mass have not yet been found outside of modern-day rich clusters. Here we report observations of the stellar velocity distribution in the galaxy NGC 1600--a relatively isolated elliptical galaxy near the centre of a galaxy group at a distance of 64 megaparsecs from Earth. We use orbit superposition models to determine that the black hole at the centre of NGC 1600 has a mass of 17 billion solar masses. The spatial distribution of stars near the centre of NGC 1600 is rather diffuse. We find that the region of depleted stellar density in the cores of massive elliptical galaxies extends over the same radius as the gravitational sphere of influence of the central black holes, and interpret this as the dynamical imprint of the black holes. PMID:27049949

  16. Determining Solubility and Diffusivity by Using a Flow Cell Coupled to a Mass Spectrometer.

    PubMed

    Khodayari, Mehdi; Reinsberg, Philip; Abd-El-Latif, Abd-El-Aziz A; Merdon, Christian; Fuhrmann, Juergen; Baltruschat, Helmut

    2016-06-01

    One of the main challenges in metal-air batteries is the selection of a suitable electrolyte that is characterized by high oxygen solubility, low viscosity, a liquid state and low vapor pressure across a wide temperature range, and stability across a wide potential window. Herein, a new method based on a thin layer flow through cell coupled to a mass spectrometer through a porous Teflon membrane is described that allows the determination of the solubility of volatile species and their diffusion coefficients in aqueous and nonaqueous solutions. The method makes use of the fact that at low flow rates the rate of species entering the vacuum system, and thus the ion current, is proportional to the concentration times the flow rate (c⋅u) and independent of the diffusion coefficient. The limit at high flow rates is proportional to D2/3·c·u1/3 . Oxygen concentrations and diffusion coefficients in aqueous electrolytes that contain Li(+) and K(+) and organic solvents that contain Li(+) , K(+) , and Mg(2+) , such as propylene carbonate, dimethyl sulfoxide tetraglyme, and N-methyl-2-pyrrolidone, have been determined by using different flow rates in the range of 0.1 to 80 μL s(-1) . This method appears to be quite reliable, as can be seen by a comparison of the results obtained herein with available literature data. The solubility and diffusion coefficient values of O2 decrease as the concentration of salt in the electrolyte was increased due to a "salting out" effect. PMID:27017297

  17. Numerical analysis of the diffusive mass transport in brain tissues with applications to optical sensors

    NASA Astrophysics Data System (ADS)

    Neculae, Adrian P.; Otte, Andreas; Curticapean, Dan

    2013-03-01

    In the brain-cell microenvironment, diffusion plays an important role: apart from delivering glucose and oxygen from the vascular system to brain cells, it also moves informational substances between cells. The brain is an extremely complex structure of interwoven, intercommunicating cells, but recent theoretical and experimental works showed that the classical laws of diffusion, cast in the framework of porous media theory, can deliver an accurate quantitative description of the way molecules are transported through this tissue. The mathematical modeling and the numerical simulations are successfully applied in the investigation of diffusion processes in tissues, replacing the costly laboratory investigations. Nevertheless, modeling must rely on highly accurate information regarding the main parameters (tortuosity, volume fraction) which characterize the tissue, obtained by structural and functional imaging. The usual techniques to measure the diffusion mechanism in brain tissue are the radiotracer method, the real time iontophoretic method and integrative optical imaging using fluorescence microscopy. A promising technique for obtaining the values for characteristic parameters of the transport equation is the direct optical investigation using optical fibers. The analysis of these parameters also reveals how the local geometry of the brain changes with time or under pathological conditions. This paper presents a set of computations concerning the mass transport inside the brain tissue, for different types of cells. By measuring the time evolution of the concentration profile of an injected substance and using suitable fitting procedures, the main parameters characterizing the tissue can be determined. This type of analysis could be an important tool in understanding the functional mechanisms of effective drug delivery in complex structures such as the brain tissue. It also offers possibilities to realize optical imaging methods for in vitro and in vivo

  18. Heat and mass transfer in magnetohydrodynamic flow of micropolar fluid on a circular cylinder with uniform heat and mass flux

    NASA Astrophysics Data System (ADS)

    Mansour, M. A.; El-Hakiem, M. A.; El Kabeir, S. M.

    2000-10-01

    Steady laminar boundary layer analysis of heat and mass transfer characteristics in magnetohydrodynamic (MHD) flow of a micropolar fluid on a circular cylinder maintained at uniform heat and mass flux has been conducted. The solution of the energy equation inside the boundary layer is obtained as a power series of the distance measured along the surface from the front stagnation point of the cylinder. The results of dimensionless temperature, Nusselt number, wall shear stress, wall couple stress and Sherwood number have been presented graphically for various values of the material parameters. The results indicate that the micropolar fluids display a reduction in drag as well as heat transfer rate when compared with Newtonian fluids.

  19. Monitoring the variations of the oxygen transfer rate in a full scale membrane bioreactor using daily mass balances.

    PubMed

    Racault, Y; Stricker, A-E; Husson, A; Gillot, S

    2011-01-01

    Oxygen transfer in biological wastewater treatment processes with high sludge concentration, such as membrane bioreactor (MBR), is an important issue. The variation of alpha-factor versus mixed liquor suspended solids (MLSS) concentration was investigated in a full scale MBR plant under process conditions, using mass balances. Exhaustive data from the Supervisory Control And Data Acquisition (SCADA) and from additional online sensors (COD, DO, MLSS) were used to calculate the daily oxygen consumption (OC) using a non-steady state mass balance for COD and total N on a 24-h basis. To close the oxygen balance, OC has to match the total oxygen transfer rate (OTRtot) of the system, which is provided by fine bubble (FB) diffusers in the aeration tank and coarse bubbles (CB) in separate membrane tanks. First assessing OTR(CB) then closing the balance OC = OTRtot allowed to calculate OTR(FB) and to fit an exponential relationship between OTR(FB) and MLSS. A comparison of the alpha-factor obtained by this balance method and by direct measurements with the off-gas method on the same plant is presented and discussed. PMID:22049761

  20. Numerical study of heat and mass transfer in an anisotropic porous enclosure due to constant heating and cooling

    SciTech Connect

    Bera, P.; Eswaran, V.; Singh, P.

    1998-12-01

    Combined heat and mass transfer in porous media occurs in many natural phenomena and engineering applications, such as the migration of moisture through air contained in insulation, the spreading of chemical pollutants in saturated soil, and the extraction of geothermal energy. Here, double-diffusive natural convective flow within a rectangular enclosure has been studied for an anisotropic porous medium using a non-Darcy extension. The principal direction of the permeability tensor has been taken oblique to the gravity vector. The spectral element method has been used to solve the problem numerically. The method has been validated using existing analytical and numerical results. Parametric studies are presented for isotropic and anisotropic cases for different fundamental parameters, e.g., buoyancy ratio, Lewis number, Rayleigh number, Darcy number. The results show that anisotropy causes significant changes in the Nusselt and Sherwood numbers. In particular, the present analysis shows that permeability orientation angle has a significant effect on the flow rate and, consequently, on the heat and mass transfer.

  1. Characterization of the intragranular water regime within subsurface sediments: Pore volume, surface area, and mass transfer limitations

    USGS Publications Warehouse

    Hay, M.B.; Stoliker, D.L.; Davis, J.A.; Zachara, J.M.

    2011-01-01

    Although "intragranular" pore space within grain aggregates, grain fractures, and mineral surface coatings may contain a relatively small fraction of the total porosity within a porous medium, it often contains a significant fraction of the reactive surface area, and can thus strongly affect the transport of sorbing solutes. In this work, we demonstrate a batch experiment procedure using tritiated water as a high-resolution diffusive tracer to characterize the intragranular pore space. The method was tested using uranium-contaminated sediments from the vadose and capillary fringe zones beneath the former 300A process ponds at the Hanford site (Washington). Sediments were contacted with tracers in artificial groundwater, followed by a replacement of bulk solution with tracer-free groundwater and the monitoring of tracer release. From these data, intragranular pore volumes were calculated and mass transfer rates were quantified using a multirate first-order mass transfer model. Tritium-hydrogen exchange on surface hydroxyls was accounted for by conducting additional tracer experiments on sediment that was vacuum dried after reaction. The complementary ("wet" and "dry") techniques allowed for the simultaneous determination of intragranular porosity and surface area using tritium. The Hanford 300A samples exhibited intragranular pore volumes of ???1% of the solid volume and intragranular surface areas of ???20%-35% of the total surface area. Analogous experiments using bromide ion as a tracer yielded very different results, suggesting very little penetration of bromide into the intragranular porosity. Copyright 2011 by the American Geophysical Union.

  2. Characterization of the intragranular water regime within subsurface sediments: pore volume, surface area, and mass transfer limitations

    USGS Publications Warehouse

    Hay, Michael B.; Stoliker, Deborah L.; Davis, James A.; Zachara, John M.

    2011-01-01

    Although "intragranular" pore space within grain aggregates, grain fractures, and mineral surface coatings may contain a relatively small fraction of the total porosity within a porous medium, it often contains a significant fraction of the reactive surface area, and can thus strongly affect the transport of sorbing solutes. In this work, we demonstrate a batch experiment procedure using tritiated water as a high-resolution diffusive tracer to characterize the intragranular pore space. The method was tested using uranium-contaminated sediments from the vadose and capillary fringe zones beneath the former 300A process ponds at the Hanford site (Washington). Sediments were contacted with tracers in artificial groundwater, followed by a replacement of bulk solution with tracer-free groundwater and the monitoring of tracer release. From these data, intragranular pore volumes were calculated and mass transfer rates were quantified using a multirate first-order mass transfer model. Tritium-hydrogen exchange on surface hydroxyls was accounted for by conducting additional tracer experiments on sediment that was vacuum dried after reaction. The complementary ("wet" and "dry") techniques allowed for the simultaneous determination of intragranular porosity and surface area using tritium. The Hanford 300A samples exhibited intragranular pore volumes of ~1% of the solid volume and intragranular surface areas of ~20%–35% of the total surface area. Analogous experiments using bromide ion as a tracer yielded very different results, suggesting very little penetration of bromide into the intragranular porosity.

  3. Tribological behavior of a friction couple functioning with selective mass transfer

    NASA Astrophysics Data System (ADS)

    Ilie, Filip

    2016-06-01

    Experimental researches on different lubricated friction couples, have confirmed that it is useful to investigate thermodynamic processes which are unstable in lubricant and on the friction couples surfaces in the first stage of the friction process. This presupposes that, in operating conditions, physical-chemical processes which are favourable to friction, such as: polymerization, formation of colloids, formation of other active substances at the contact surfaces and of other compounds with low resistance to shear take place. Friction in such conditions takes place with selective mass transfer, and it is used there where the friction of the mixed and adherence layers is not safe enough, or the durability of the friction couples is not assured. The selective mass transfer allows the transfer of some elements of the materials in contact from one surface to the other, covering them with a thin, superficial layer, with superior properties at minimal friction and wear. The aim of this paper is to analyse the physical-chemical factors and the proper processes for achieving the selective mass transfer for the couple steel/bronze, which in optimal conditions, forms a thin layer of copper on the contact surfaces areas. Also, it presents some studies and researches concerning the tribological behaviour of the surfaces of a friction couple with linear contact (roll/roll) which operates with selective mass transfer, tested on Amsler tribometer.

  4. Controlling the column spacing in isothermal magnetic advection to enable tunable heat and mass transfer

    NASA Astrophysics Data System (ADS)

    Solis, Kyle J.; Martin, James E.

    2012-11-01

    Isothermal magnetic advection (IMA) is a recently discovered method of inducing highly organized, non-contact flow lattices in suspensions of magnetic particles, using only uniform ac magnetic fields of modest strength. The initiation of these vigorous flows requires neither a thermal gradient nor a gravitational field, and so can be used to transfer heat and mass in circumstances where natural convection does not occur. These advection lattices are comprised of a square lattice of antiparallel flow columns. If the column spacing is sufficiently large compared to the column length and the flow rate within the columns is sufficiently large, then one would expect efficient transfer of both heat and mass. Otherwise, the flow lattice could act as a countercurrent heat exchanger and only mass will be efficiently transferred. Although this latter case might be useful for feeding a reaction front without extracting heat, it is likely that most interest will be focused on using IMA for heat transfer. In this paper, we explore the various experimental parameters of IMA to determine which of these can be used to control the column spacing. These parameters include the field frequency, strength, and phase relation between the two field components, the liquid viscosity, and particle volume fraction. We find that the column spacing can easily be tuned over a wide range to enable the careful control of heat and mass transfer.

  5. Mass transfer studies of Geobacter sulfurreducens biofilms on rotating disk electrodes.

    PubMed

    Babauta, Jerome T; Beyenal, Haluk

    2014-02-01

    Electrochemical impedance spectroscopy has received significant attention recently as a method to measure electrochemical parameters of Geobacter sulfurreducens biofilms. Here, we use electrochemical impedance spectroscopy to demonstrate the effect of mass transfer processes on electron transfer by G. sulfurreducens biofilms grown in situ on an electrode that was subsequently rotated. By rotating the biofilms up to 530 rpm, we could control the microscale gradients formed inside G. sulfurreducens biofilms. A 24% increase above a baseline of 82 µA could be achieved with a rotation rate of 530 rpm. By comparison, we observed a 340% increase using a soluble redox mediator (ferrocyanide) limited by mass transfer. Control of mass transfer processes was also used to quantify the change in biofilm impedance during the transition from turnover to non-turnover. We found that only one element of the biofilm impedance, the interfacial resistance, changed significantly from 900 to 4,200 Ω under turnover and non-turnover conditions, respectively. We ascribed this change to the electron transfer resistance overcome by the biofilm metabolism and estimate this value as 3,300 Ω. Additionally, under non-turnover, the biofilm impedance developed pseudocapacitive behavior indicative of bound redox mediators. Pseudocapacitance of the biofilm was estimated at 740 µF and was unresponsive to rotation of the electrode. The increase in electron transfer resistance and pseudocapacitive behavior under non-turnover could be used as indicators of acetate limitations inside G. sulfurreducens biofilms. PMID:23996084

  6. Mass Transfer Studies of Geobacter sulfurreducens Biofilms on Rotating Disk Electrodes

    PubMed Central

    Babuta, Jerome T.; Beyenal, Haluk

    2014-01-01

    Electrochemical impedance spectroscopy has received significant attention recently as a method to measure electrochemical parameters of Geobacter sulfurreducens bio-films. Here, we use electrochemical impedance spectroscopy to demonstrate the effect of mass transfer processes on electron transfer by G.sulfurreducens biofilms grown in situ on an electrode that was subsequently rotated. By rotating the biofilms up to 530 rpm, we could control the microscale gradients formed inside G.sulfurreducens biofilms. A 24% increase above a baseline of 82 μA could be achieved with a rotation rate of 530 rpm. By comparison, we observed a 340% increase using a soluble redox mediator (ferrocyanide) limited by mass transfer. Control of mass transfer processes was also used to quantify the change in biofilm impedance during the transition from turnover to non-turnover. We found that only one element of the biofilm impedance, the interfacial resistance, changed significantly from 900 to 4,200 Ω under turnover and non-turnover conditions, respectively. We ascribed this change to the electron transfer resistance overcome by the biofilm metabolism and estimate this value as 3,300 Ω. Additionally, under non-turnover, the biofilm impedance developed pseudocapacitive behavior indicative of bound redox mediators. Pseudocapacitance of the biofilm was estimated at 740 μF and was unresponsive to rotation of the electrode. The increase in electron transfer resistance and pseudocapacitive behavior under non-turnover could be used as indicators of acetate limitations inside G.sulfurreducens biofilms. PMID:23996084

  7. Volatile organic compound emission rates from mechanical surface aerators: Mass-transfer modeling

    SciTech Connect

    Chern, J.M.; Chou, S.R.

    1999-08-01

    In wastewater treatment plants, many operation units such as equalization and aeration involve oxygen transfer between wastewater and air. While oxygen is transferred from air to wastewater, volatile organic compounds (VOCs) are stripped from wastewater to air. Because of increasingly stringent environmental regulations, wastewater treatment operators have to do VOC inventory of their facilities. A new mass-transfer model has been developed to predict the VOC emission rates from batch and continuous aeration tanks with mechanical surface aerators. The model takes into consideration that the VOC mass transfer occurs in two separate mass-transfer zones instead of lumping the overall VOC transfer in the whole aeration tank as is done in the conventional ASCE-based model. The predictive capabilities of the two-zone and the ASCE-based models were examined by calculating the emission rates of 10 priority pollutants from aeration tanks. The effects of the hydraulic retention time, the Henry`s law constant, gas-phase resistance, and the water and air environmental conditions on the VOC emission rates were predicted by the two models.

  8. Intensification of heat and mass transfer by ultrasound: application to heat exchangers and membrane separation processes.

    PubMed

    Gondrexon, N; Cheze, L; Jin, Y; Legay, M; Tissot, Q; Hengl, N; Baup, S; Boldo, P; Pignon, F; Talansier, E

    2015-07-01

    This paper aims to illustrate the interest of ultrasound technology as an efficient technique for both heat and mass transfer intensification. It is demonstrated that the use of ultrasound results in an increase of heat exchanger performances and in a possible fouling monitoring in heat exchangers. Mass transfer intensification was observed in the case of cross-flow ultrafiltration. It is shown that the enhancement of the membrane separation process strongly depends on the physico-chemical properties of the filtered suspensions. PMID:25216897

  9. The model of heat and mass transfer in rough and irrigated ducts

    NASA Astrophysics Data System (ADS)

    Laptev, A. G.; Lapteva, E. A.

    2015-07-01

    To determine the coefficients of the heat and mass transfer in the ducts with rough and irrigated walls the development of the classical hydrodynamic analogy of the momentum, mass, and energy transfer has been continued. The conservation properties of the skin-friction laws with respect to various disturbances are used for this purpose, and the "effective velocity" is found the value of which enables us to correct the hydrodynamic analogy. The examples of computations of the Nusselt, Sherwood, and Stanton numbers are shown for rough ducts, cooler, and film flow in the counter-flow. A comparison with the results of other researchers is given.

  10. Influence of Mass Transfer on Bioavailability and Kinetic Rate of Uranium(VI) Biotransformation

    SciTech Connect

    Chongxuan Liu; Zheming Wang; John M. Zachara; James K. Fredrickson

    2006-06-01

    This research is investigating the influence of mass transfer process on the rate and extent of microbial reduction of U(VI) associated with intragrain domains in the Hanford subsurface sediments. The project will develop instrumental techniques to characterize microscopic mass transfer process at the sediment grain scale and to develop kinetic data and process models that describe microbial reduction of intragrain U(VI). Scientific knowledge and process models developed from this research will enhance our understanding on the future behavior of in-ground U(VI) at Hanford and other DOE sites where sediments contain U(VI) in intragrain domains or fracture-matrix systems.

  11. Mathematical Modeling of Mass Transfer in Laminar Motion of a Droplet in a Liquid Medium

    NASA Astrophysics Data System (ADS)

    Elizarov, D. V.; Elizarov, V. V.; Kamaliev, T. S.; D‧yakonov, S. G.

    2016-03-01

    Consideration is given to mathematical modeling of the process of nonstationary liquid-liquid extraction in apparatuses with free motion of a dispersed phase. Solutions of nonstationary equations of transfer of momentum and mass in the boundary layer on the droplet and inside the droplet near the phase boundary are given. Equations for calculation of the coefficients of mass transfer and concentration of the extracted component are obtained. A comparison is made of the calculated data and experimental results in extracting various liquid mixtures.

  12. Mass transfer effects in solvent-free fat interesterification reactions: influences on catalyst design.

    PubMed

    Ison, A P; Macrae, A R; Smith, C G; Bosley, J

    1994-01-20

    The use of solvent-free systems in the oil and fats industry is commonplace. Initial studies on interesterification were carried out in solvent systems because the lipase was immobilized solely by adsorption onto particles of diatomaceous earth. In this study, the mass transfer characteristics associated with the continuous interesterification of olive oil in a solvent-free system have been examined, for lipase immobilized on the three ion-exchange materials: Duolite ES562, Duolite ES568, and Spheroil DEA. The process of immobilization is influenced by the internal structure of the material and this in turn influences the interesterification activity of the catalyst. Individually prepared catalysts for the three support materials have shown that external mass transfer limitations are unlikely even at low flowrates.In the case of Spherosil DEA, with a mean pore diameter of 1480 A, the wide pores would be expected to reduce internal mass transfer limitations; however, it is more likely that the reduction in activity with increased catalyst loading is due to the lipase molecules being immobilized in a tightly packed monolayer. In such a situation, some active sites of the lipase molecules would become inaccessible to substrate molecules leading to an observed reduction in activity. For Duolite ES568, the observed results are very similar to those seen for Spherosil DEA, however, the pore structure of this support material indicate that some internal mass transfer limitations may also be occurring. Yet the contribution of the individual effects cannot be determined. The results observed for the support Duolite ES562 are different than those observed for the other materials and reflect the heterogeneity of Duolite ES562. The large proportion of narrow pores in the support mean that, for the catalysts examined, immobilization is most likely to have occurred in the external pores of the particles, and as such no internal mass transfer limitation is observed.It is clear

  13. Solution Phase Exciton Diffusion Dynamics of a Charge-Transfer Copolymer PTB7 and a Homopolymer P3HT.

    PubMed

    Cho, Sung; Rolczynski, Brian S; Xu, Tao; Yu, Luping; Chen, Lin X

    2015-06-18

    Using ultrafast polarization-controlled transient absorption (TA) measurements, dynamics of the initial exciton states were investigated on the time scale of tens of femtoseconds to about 80 ps in two different types of conjugated polymers extensively used in active layers of organic photovoltaic devices. These polymers are poly(3-fluorothienothiophenebenzodithiophene) (PTB7) and poly-3-hexylthiophene (P3HT), which are charge-transfer polymers and homopolymers, respectively. In PTB7, the initial excitons with excess vibrational energy display two observable ultrafast time constants, corresponding to coherent exciton diffusion before the vibrational relaxation, and followed by incoherent exciton diffusion processes to a neighboring local state after the vibrational relaxation. In contrast, P3HT shows only one exciton diffusion or conformational motion time constant of 34 ps, even though its exciton decay kinetics are multiexponential. Based on the experimental results, an exciton dynamics mechanism is conceived taking into account the excitation energy and structural dependence in coherent and incoherent exciton diffusion processes, as well as other possible deactivation processes including the formation of the pseudo-charge-transfer and charge separate states, as well as interchain exciton hopping or coherent diffusion. PMID:25620363

  14. A random walk solution for modeling solute transport with network reactions and multi-rate mass transfer in heterogeneous systems: Impact of biofilms

    NASA Astrophysics Data System (ADS)

    Henri, Christopher V.; Fernàndez-Garcia, Daniel

    2015-12-01

    The interplay between the spatial variability of the aquifer hydraulic properties, mass transfer due to sub-grid heterogeneity and chemical reactions often complicates reactive transport simulations. It is well documented that hydro-biochemical properties are ubiquitously heterogeneous and that diffusion and slow advection at the sub-grid scale typically leads to the conceptualization of an aquifer as a multi-porosity system. Within this context, chemical reactions taking place in mobile/immobile water regions can be substantially different between each other. This paper presents a particle-based method that can efficiently simulate heterogeneity, network reactions and multi-rate mass transfer. The approach is based on the development of transition probabilities that describe the likelihood that particles belonging to a given species and mobile/immobile domain at a given time will be transformed into another species and mobile/immobile domain afterwards. The joint effect of mass transfer and sequential degradation is shown to be non-trivial. A characteristic rebound of degradation products can be observed. This late rebound of concentrations is not driven by any change in the flow regime (e.g., pumping ceases in the pump-and-treat remediation strategy) but due to the natural interplay between mass transfer and chemical reactions. To illustrate that the method can simultaneously represent mass transfer, spatially varying properties and network reactions without numerical problems, we have simulated the degradation of tetrachloroethylene (PCE) in a three-dimensional fully heterogeneous aquifer subjected to rate-limited mass transfer. Two types of degradation modes were considered to compare the effect of an active biofilm with that of clay pods present in the aquifer. Results of the two scenarios display significantly differences. Biofilms that promote the degradation of compounds in an immobile region are shown to significantly enhance degradation, rapidly producing

  15. Dual coupled radiative transfer equation and diffusion approximation for the solution of the forward problem in fluorescence molecular imaging

    NASA Astrophysics Data System (ADS)

    Gorpas, Dimitris; Andersson-Engels, Stefan

    2012-03-01

    The solution of the forward problem in fluorescence molecular imaging is among the most important premises for the successful confrontation of the inverse reconstruction problem. To date, the most typical approach has been the application of the diffusion approximation as the forward model. This model is basically a first order angular approximation for the radiative transfer equation, and thus it presents certain limitations. The scope of this manuscript is to present the dual coupled radiative transfer equation and diffusion approximation model for the solution of the forward problem in fluorescence molecular imaging. The integro-differential equations of its weak formalism were solved via the finite elements method. Algorithmic blocks with cubature rules and analytical solutions of the multiple integrals have been constructed for the solution. Furthermore, specialized mapping matrices have been developed to assembly the finite elements matrix. As a radiative transfer equation based model, the integration over the angular discretization was implemented analytically, while quadrature rules were applied whenever required. Finally, this model was evaluated on numerous virtual phantoms and its relative accuracy, with respect to the radiative transfer equation, was over 95%, when the widely applied diffusion approximation presented almost 85% corresponding relative accuracy for the fluorescence emission.

  16. LUT Reveals a New Mass-transferring Semi-detached Binary

    NASA Astrophysics Data System (ADS)

    Qian, S.-B.; Zhou, X.; Zhu, L.-Y.; Zejda, M.; Soonthornthum, B.; Zhao, E.-G.; Zhang, J.; Zhang, B.; Liao, W.-P.

    2015-12-01

    GQ Dra is a short-period eclipsing binary in a double stellar system that was discovered by Hipparcos. Complete light curves in the UV band were obtained with the Lunar-based Ultraviolet Telescope in 2014 November and December. Photometric solutions are determined using the W-D (Wilson and Devinney) method. It is discovered that GQ Dra is a classical Algol-type semi-detached binary where the secondary component is filling the critical Roche lobe. An analysis of all available times of minimum light suggests that the orbital period is increasing continuously at a rate of \\dot{P}=+3.48(+/- 0.23)× {10}-7 days yr-1. This could be explained by mass transfer from the secondary to the primary, which is in agreement with the semi-detached configuration with a lobe-filling secondary. By assuming a conservation of mass and angular momentum, the mass transfer rate is estimated as \\dot{m}=9.57(+/- 0.63)× {10}-8 {M}⊙ {{yr}}-1. All of these results reveal that GQ Dra is a mass-transferring semi-detached binary in a double system that was formed from an initially detached binary star. After the massive primary evolves to fill the critical Roche lobe, the mass transfer will be reversed and the binary will evolve into a contact configuration with two sub-giant or giant component stars.

  17. Heat/mass transfer and flow characteristics of pin fin cooling channels in turbine blades

    NASA Astrophysics Data System (ADS)

    Lau, S. C.; Saxena, A.

    Experiments studied the local heat/mass transfer distributions and pressure drops in pin fin channels that modeled internal cooling passages in gas turbine blades. Heat/mass transfer distributions were determined for a straight flow through a pin fin channel (H/D = 1.0, X/D = S/D = 2.5) and a flow through the pin fin channel with trailing edge flow ejection. The overall friction factor and local pressure drop results were obtained for various configurations and lengths of the trailing edge ejection holes. The results show that, when there is trailing edge flow ejection, the main flow stream turns toward the trailing edge ejection holes. The wake regions downstream of the pins and the regions affected by secondary flow shift toward the ejection holes. The local channel wall heat/mass transfer is generally high immediately upstream of a pin, in the wake region downstream of a pin, and in the regions affected by secondary flow. In the case with trailing edge flow ejection, the heat/mass transfer generally decreases in the radial direction as a result of the reducing radial mass flow rate. The overall friction is higher when the trailing edge ejection holes are longer and when they are configured such that more flow is forced further downstream in the pin fin channel before exiting through the ejection holes.

  18. In-situ determination of field-scale NAPL mass transfer coefficients: Performance, simulation and analysis

    NASA Astrophysics Data System (ADS)

    Mobile, Michael; Widdowson, Mark; Stewart, Lloyd; Nyman, Jennifer; Deeb, Rula; Kavanaugh, Michael; Mercer, James; Gallagher, Daniel

    2016-04-01

    Better estimates of non-aqueous phase liquid (NAPL) mass, its persistence into the future, and the potential impact of source reduction are critical needs for determining the optimal path to clean up sites impacted by NAPLs. One impediment to constraining time estimates of source depletion is the uncertainty in the rate of mass transfer between NAPLs and groundwater. In this study, an innovative field test is demonstrated for the purpose of quantifying field-scale NAPL mass transfer coefficients (klN) within a source zone of a fuel-contaminated site. Initial evaluation of the test concept using a numerical model revealed that the aqueous phase concentration response to the injection of clean groundwater within a source zone was a function of NAPL mass transfer. Under rate limited conditions, NAPL dissolution together with the injection flow rate and the radial distance to monitoring points directly controlled time of travel. Concentration responses observed in the field test were consistent with the hypothetical model results allowing field-scale NAPL mass transfer coefficients to be quantified. Site models for groundwater flow and solute transport were systematically calibrated and utilized for data analysis. Results show klN for benzene varied from 0.022 to 0.60 d- 1. Variability in results was attributed to a highly heterogeneous horizon consisting of layered media of varying physical properties.

  19. In-situ determination of field-scale NAPL mass transfer coefficients: Performance, simulation and analysis.

    PubMed

    Mobile, Michael; Widdowson, Mark; Stewart, Lloyd; Nyman, Jennifer; Deeb, Rula; Kavanaugh, Michael; Mercer, James; Gallagher, Daniel

    2016-04-01

    Better estimates of non-aqueous phase liquid (NAPL) mass, its persistence into the future, and the potential impact of source reduction are critical needs for determining the optimal path to clean up sites impacted by NAPLs. One impediment to constraining time estimates of source depletion is the uncertainty in the rate of mass transfer between NAPLs and groundwater. In this study, an innovative field test is demonstrated for the purpose of quantifying field-scale NAPL mass transfer coefficients (kl(N)) within a source zone of a fuel-contaminated site. Initial evaluation of the test concept using a numerical model revealed that the aqueous phase concentration response to the injection of clean groundwater within a source zone was a function of NAPL mass transfer. Under rate limited conditions, NAPL dissolution together with the injection flow rate and the radial distance to monitoring points directly controlled time of travel. Concentration responses observed in the field test were consistent with the hypothetical model results allowing field-scale NAPL mass transfer coefficients to be quantified. Site models for groundwater flow and solute transport were systematically calibrated and utilized for data analysis. Results show kl(N) for benzene varied from 0.022 to 0.60d(-1). Variability in results was attributed to a highly heterogeneous horizon consisting of layered media of varying physical properties. PMID:26855386

  20. Influence of end-to-end diffusion on intramolecular energy transfer as observed by frequency-domain fluorometry

    NASA Astrophysics Data System (ADS)

    Lakowicz, Joseph R.; Wiczk, Wieslaw M.; Gryczynski, Ignacy; Szmacinski, Henryk; Johnson, Michael L.

    1990-05-01

    We investigated the influence of end-to-end diffusion on intramolecular energy transfer between a naphthalene donor and dansyl acceptor linked by polymethylene chain. A range of viscosities of 0.6 - 200cP were obtained using propylene glycol at different temperatures (0-80°C) and methanol at 20°C. The intensity decays of naphthalene were measured in frequency-domain. Several theoretical models, including distance distributions were used to fit the data. The results indicate that end-to-end diffusion of flexible donor - acceptor pairs can be readily detected and quantified using frequency-domain fluorometry.

  1. Transient, compressible heat and mass transfer in porous media using the strongly implicit iteration procedure.

    NASA Technical Reports Server (NTRS)

    Curry, D. M.; Cox, J. E.

    1972-01-01

    Coupled nonlinear partial differential equations describing heat and mass transfer in a porous matrix are solved in finite difference form with the aid of a new iterative technique (the strongly implicit procedure). Example numerical results demonstrate the characteristics of heat and mass transport in a porous matrix such as a charring ablator. It is emphasized that multidimensional flow must be considered when predicting the thermal response of a porous material subjected to nonuniform boundary conditions.

  2. On the stream-accretion disk interaction - Response to increased mass transfer rate

    NASA Technical Reports Server (NTRS)

    Dgani, Ruth; Livio, Mario; Soker, Noam

    1989-01-01

    The time-dependent interaction between the stream of mass from the inner Lagrangian point and the accretion disk, resulting from an increasing mass transfer rate is calculated. The calculation is fully three-dimensional, using a pseudoparticle description of the hydrodynamics. It is demonstrated that the results of such calculations, when combined with specific observations, have the potential of both determining essential parameters, such as the viscosity parameter alpha, and can distinguish between different models of dwarf nova eruptions.

  3. Simultaneous heat and mass transfer in polymer solutions exposed to intermittent infrared radiation heating

    SciTech Connect

    Chen, J.J.; Lin, J.D.

    1998-06-01

    Drying is one of the essential steps in a number of industrial applications, such as the preserving of food and the drying of paint, pulp, and paper. The quality of paper tubes is significantly affected by the heat and mass transfer process. The drying of polymer solution plays a crucial role in the manufacturer of photographic film, synthetic fibers, adhesives, and a variety of other polymeric products. During drying of wet materials, simultaneous heat and mass transfer occurs both inside the medium and in the boundary layer of the drying agent. Drying is one of the most energy-consuming processes in the industrial sector and can also be very time consuming as, for example, in conventional convective drying by hot air, while minimum cost and energy consumption and maximum product quality are among the main concerns in industry today. Here, a theoretical study is performed that describes heat transfer and moisture variation while a polymer solution is exposed to high-intensity infrared radiation flux and/or an airflow. While the intermittent heating is considered, the authors investigate the influences of various radiation and convection parameters on the transfer of heat and moisture variation of coated layers on an optically thick substrate. During the tempering stage in the intermittent heating process, the convective mass transfer is included to simulate the ambient air in reality. The effects of radiation and convection parameters on the transfer processes are presented in terms of the rate of water content removal, heat transfer, and moisture distributions. Numerical results show that the rate of water removal from the polymer solution is dominated by both the adsorbed radiative heat energy and the distributions of water mass fraction in the polymer solution.

  4. Effect of acoustic streaming on the mass transfer from a sublimating sphere

    NASA Astrophysics Data System (ADS)

    Kawahara, N.; Yarin, A. L.; Brenn, G.; Kastner, O.; Durst, F.

    2000-04-01

    The effect of the acoustic streaming on the mass transfer from the surface of a sphere positioned in an ultrasonic acoustic levitator is studied both experimentally and theoretically. Acoustic levitation using standing ultrasonic waves is an experimental tool for studying the heat and mass transfer from small solid or liquid samples, because it allows an almost steady positioning of a sample at a fixed location in space. However, the levitator introduces some difficulties. One of the main problems with acoustic levitation is that an acoustic streaming is induced near the sample surface, which affects the heat and mass transfer rates, as characterized by increased Nusselt and Sherwood numbers. The transfer rates are not uniform along the sample surface, and the aim of the present study is to quantify the spatial Sherwood number distribution over the surface of a sphere. The experiments are based on the measurement of the surface shape of a sphere layered with a solid substance as a function of time using a charge-coupled device (CCD) camera with backlighting. The sphere used in this research is a glass sphere layered with a volatile solid substance (naphthalene or camphor). The local mass transfer from the surface both with and without an ultrasonic acoustic field is investigated in order to evaluate the effect of the acoustic streaming. The experimental results are compared with predictions following from the theory outlined [A. L. Yarin, M. Pfaffenlehner, and C. Tropea, J. Fluid Mech. 356, 65 (1998); A. L. Yarin, G. Brenn, O. Kastner, D. Rensink, and C. Tropea, ibid. 399, 151 (1999)] which describes the acoustic field and the resulting acoustic streaming, and the mass transfer at the surface of particles and droplets located in an acoustic levitator. The results are also compared with the experimental data and with the theoretical predictions of Burdukov and Nakoryakov [J. Appl. Mech. Tech. Phys. 6, 51 (1965)], which are valid only in the case of spherical

  5. Effect of laminar and turbulent fluid flow on mass transfer in some electrochemical systems

    NASA Astrophysics Data System (ADS)

    Chen, Qian

    2000-10-01

    The influence of fluid flow on electrode-shape change that results from electrodeposition in the presence of a model leveling agent is simulated and discussed. The treatment is more rigorous than past studies in that flow and concentration fields are recalculated as the electrode shape changes. It is shown that uncertainties due to approximate treatments of fluid flow may be as significant as existing discrepancies between experiment and theory. The mass transfer characteristics of a turbulent slot jet impinging normally on a target wall are examined using numerical simulations. Fluid flow is modeled using the k-turbulence model of Wilcox [1]. The computations are validated against existing experimental fluid flow, heat transfer and mass transfer data. The range of Reynolds numbers examined is from 450 to 20,000 with Prandtl or Schmidt numbers from 1 to 2,400. The distance of the target plate from the slot jet varies between 2 to 8 times the slot jet width. The study reveals computational aspects that are unique to the solution of flow and mass transfer problems with the combination of high Schmidt numbers and turbulent flows. A low order "coherent structure" near-wall flow model first proposed by Chapman and Kuhn [2] is used to obtain the near-wall fluid flow field. This flow field is then used to compute high Schmidt number mass transfer for a turbulent boundary layer flow. It is shown that useful insight can be obtained into high Schmidt number mass transfer for a turbulent fluid flow using this model. The boundary conditions for this near-wall field for more complicated flow or geometries may be obtained either from experimental turbulent velocity and frequency data or from a k-o type of turbulence model.

  6. Heat And Mass Transfer Analysis of a Film Evaporative MEMS Tunable Array

    NASA Astrophysics Data System (ADS)

    O'Neill, William J.

    This thesis details the heat and mass transfer analysis of a MEMs microthruster designed to provide propulsive, attitude control and thermal control capabilities to a cubesat. This thruster is designed to function by retaining water as a propellant and applying resistive heating in order to increase the temperature of the liquid-vapor interface to either increase evaporation or induce boiling to regulate mass flow. The resulting vapor is then expanded out of a diverging nozzle to produce thrust. Because of the low operating pressure and small length scale of this thruster, unique forms of mass transfer analysis such as non-continuum gas flow were modeled using the Direct Simulation Monte Carlo method. Continuum fluid/thermal simulations using COMSOL Multiphysics have been applied to model heat and mass transfer in the solid and liquid portions of the thruster. The two methods were coupled through variables at the liquid-vapor interface and solved iteratively by the bisection method. The simulations presented in this thesis confirm the thermal valving concept. It is shown that when power is applied to the thruster there is a nearly linear increase in mass flow and thrust. Thus, mass flow can be regulated by regulating the applied power. This concept can also be used as a thermal control device for spacecraft.

  7. Light-Time Effect and Mass Transfer in the Triple Star SW Lyncis

    NASA Astrophysics Data System (ADS)

    Kim, Chun-Hwey

    1999-06-01

    In this paper all the photoelectric times of minimum for the triple star SW Lyn have been analyzed in terms of light-time e ect due to the third-body and secular period decreases induced by mass transfer process. The light-time orbit determined recently by Ogloza et al.(1998) were modi ed and improved. And it is found that the orbital period of SW Lyn have been decreasing secularly. The third-body revolves around the mass center of triple stars every 5y.77 in a highly eccentric elliptical orbit(e=0.61). The third-body with a minimum mass of 1.13M may be a binary or a white dwarf. The rate of secular period-decrease were obtained as ¡âP/P = -12.45 x 10-11, implying the mass-transfer from the massive primary star to the secondary. The mass losing rate from the primary were calculated as about 1.24 x 10-8M /y. It is noticed that the mass-transfer in SW Lyn system is opposite in direction to that deduced from it's Roche geometry by previous investigators.

  8. Heat and mass transfer models to understand the drying mechanisms of a porous substrate.

    PubMed

    Songok, Joel; Bousfield, Douglas W; Gane, Patrick A C; Toivakka, Martti

    2016-02-01

    While drying of paper and paper coatings is expensive, with significant energy requirements, the rate controlling mechanisms are not currently fully understood. Two two-dimensional models are used as a first approximation to predict the heat transfer during hot air drying and to evaluate the role of various parameters on the drying rates of porous coatings. The models help determine the structural limiting factors during the drying process, while applying for the first time the recently known values of coating thermal diffusivity. The results indicate that the thermal conductivity of the coating structure is not the controlling factor, but the drying rate is rather determined by the thermal transfer process at the structure surface. This underlines the need for ensuring an efficient thermal transfer from hot air to coating surface during drying, before considering further measures to increase the thermal conductivity of porous coatings. PMID:26920528

  9. Mass transfer based on chemical potential theory: ZnSO{sub 4}/H{sub 2}SO{sub 4}/D2EHPA

    SciTech Connect

    Klocker, H.; Bart, H.J.; Marr, R.; Mueller, H.

    1997-10-01

    The zinc sulfate/D2EHPA system is used commercially for the recovery of zinc from waste streams and secondary materials. A fundamental model based on chemical reaction kinetics and diffusional mass transfer for the extraction of zinc sulfate with di(2-ethylhexyl) phosphoric acid (D2EHPA) in n-heptane at 25 C was developed. Gradients of the chemical potential were used as the driving force for diffusion. Activity coefficients and their derivatives were calculated from the Pitzer equation in the aqueous phase, while the organic non-ideality was considered by the Hildebrand-Scott treatment. The Nerst-Planck equation was chosen for describing the diffusion of aqueous ions, paying special care to the formation of hydrogen sulfate. It was assumed that this fast ionic reaction can be described in terms of the mass action law in the bulk and film. For the multicomponent mass transfer of the organic species, the Maxwell-Stefan theory was adopted. A kinetic equation for the extraction of zinc with D2EHPA, which considers the adsorption of the D2EHPA molecules at the interface based on the Langmuir law, was suitable for the experimental data. Organic zinc concentration vs. time was obtained in a type of Lewis cell with vibrational mixing. Molar fluxes were calculated by fitting it with rational functions, which were analytically differentiated. Initial conditions of the experiments cover a wide range of the zinc (0.1 mM to 0.05 M), D2EHPA, and sulfuric acid concentration. Experimental fluxes could be well described by this model when chemical kinetics and mass transfer were considered. In particular, the resistance to mass transfer in the organic film is important.

  10. Determination of characteristic constants for some basic processes in plasma—diffusion, Penning ionization, asymmetric charge transfer

    NASA Astrophysics Data System (ADS)

    Temelkov, K. A.; Vuchkov, N. K.; Ekov, R. P.; Sabotinov, N. V.

    2008-05-01

    The diffusion coefficients of ten chemical element atoms in the binary system with helium and neon are calculated on the basis of 12-6 Lennard-Jones and rigid sphere inter-atomic interaction approximations. Cross-sections and rate constants for thermal energy charge transfer and Penning collisions are calculated for all Tl+ and I+ excited states possibly populated via these reactions. For the case of the charge transfer process the theoretical results are compared with the experimentally obtained ones. Since the characteristic constants considered depend on the gas temperature, the gas temperature distribution is also calculated by solving the heat conduction equation for the gas discharges studied.

  11. Development of Turbulent Diffusion Transfer Model to Estimate Hydrologic Budget of Upper Klamath Lake Oregon, USA

    NASA Astrophysics Data System (ADS)

    Sahoo, G. B.; Schladow, G.

    2013-12-01

    Detailed and accurate hydrologic budgets of lake or reservoirs are essential for sustainable water supply and ecosystem managements due to increasing water demand and uncertainties related to climate change. Ensuring sustainable water allocation to stakeholders requires accurate heat and hydrologic budgets. A number of micrometeorological methods have been developed to approximate heat budget components, such as evaporative and sensible heat loss, that are not directly measurable. Although micrometeorological methods estimate the sensible and evaporative loss well for stationary (i.e. ideal) condition, these methods can rarely be approximated for non-idealized condition. We developed a turbulent diffusion transfer model and coupled to the dynamic lake model (DLM-WQ), developed at UC Davis, with the goal of correctly estimating the hydrologic budget of Upper Klamath Lake Oregon, USA. The measured and DLM-WQ estimated lake water temperatures and water elevation are in excellent agreement with correlation coefficient equals 0.95 and 0.99, respectively. Consistent with previous studies, the sensible and latent heat exchange coefficients were found to be site specific. Estimated lake mixing shows that the lake became strongly stratified during summer (between late April and the end of August). For the hypereutrophic shallow Upper Klamath Lake, longer stratification results in low dissolved oxygen (DO) concentration at the sediment surface causing DO sensitive habitat destruction and ecological problems. The updated DLM-WQ can provide quantitative estimates of hydrologic components and predict the effects of natural- or human-induced changes in one component of the hydrologic cycle on the lake supplies and associated consequences.

  12. Supercritical CO2 Dissolution and Mass Transfer in a Heterogeneous Pore Network under Drainage and Imbibition Conditions

    NASA Astrophysics Data System (ADS)

    Kneafsey, T. J.; Chang, C.; Zhou, Q.; Oostrom, M.; Wietsma, T. W.; Yu, Q.

    2015-12-01

    Dissolution trapping of supercritical CO2 (scCO2) is usually modeled by assuming instantaneous scCO2 dissolution and equilibrium phase partitioning. Our recent core-scale imbibition experiments show a prolonged depletion of residual scCO2 by dissolution, implying a non-equilibrium mechanism. In our 2D sandstone-analogue micromodel experimental study, pore-scale scCO2 dissolution was inferred from imaging (1) drainage using a pH-sensitive water dye and (2) imbibition using a scCO2 dye. The drainage experiment was conducted by injecting scCO2 into the dissolved-CO2 (dsCO2)-free water-filled pore network. The time-lapse images of non-uniform dye intensities indicating varying pH show that dsCO2 concentration varies from zero to solubility in individual pores and pore clusters and the average concentration gradually increases with time. The different rates of dissolution in different pores/clusters can be attributed to (1) fast scCO2 dissolution at scCO2-water interfaces, (2) rate-limited mass transfer due to limited interface areas, and (3) a transition from rate-limited to diffusion-limited mass transfer, revealed by detailed analysis on selected pores and pore clusters. The imbibition experiments conducted by injecting deionized water at different rates show (1) water flow in channels bypassing scCO2 at high residual saturations, (2) subsequent, slow scCO2 depletion by dissolution and mass transfer as effluent dsCO2 concentration varies from 0.06% to 4.44% of solubility, and (3) creation of new water flow paths by dissolution, enhancing scCO2 depletion by coupled displacement and dissolution. Both the drainage and imbibitions experiments indicate non-equilibrium scCO2 dissolution in the centimeter-scale pore network over 4.5 hours and up to 14 hours, respectively. The pore-scale imaging can help better understand the effects of pore-throat characteristics on scCO2 dissolution and mass transfer during drainage and imbibition and the interplay between displacement and

  13. Analysis of coupled mass transfer and sol-gel reaction in a two-phase system

    NASA Astrophysics Data System (ADS)

    Castelijns, H. J.; Huinink, H. P.; Pel, L.; Zitha, P. L. J.

    2006-07-01

    The coupled mass transfer and chemical reactions of a gel-forming compound in a two-phase system were studied in detail. Tetra-methyl-ortho-silicate (TMOS) is often used as a precursor in sol-gel chemistry to produce silica gels in aqueous systems. TMOS can also be mixed with many hydrocarbons without chemical reaction, which allows for various applications in multiphase systems. In this study, TMOS was mixed with n-hexadecane and placed together with water in small cylinders. Upon contact of the mixture with the water, TMOS transfers completely to the aqueous phase where it forms a gel through a heterogeneous reaction. Nuclear magnetic resonance imaging and relaxation time measurements were employed to monitor the mass transfer of TMOS from the oleic to the aqueous phase. The longitudinal relaxation time (T1) was calibrated and used to determine the concentration of TMOS in n-hexadecane during the transfer. The mass transfer rate was obtained at various temperatures (25-45°C) and for several initial concentrations of TMOS. In the aqueous phase a sharp decrease in the transversal relaxation time (T2) is observed which is attributed to the gel reaction, in particular the formation of methanol in the initial stage. The minimum in T2 indicates the gelation point, and was found to be strongly dependent on temperature and concentration.

  14. Mass Transfer Study of Chlorine Dioxide Gas Through Polymeric Packaging Materials

    Technology Transfer Automated Retrieval System (TEKTRAN)

    A continuous system for measuring the mass transfer of gaseous chlorine dioxide (ClO2), a strong oxidizing agent and used in food and pharmaceutical packaging, through 10 different types of polymeric packaging material was developed utilizing electrochemical sensor as a detector. Permeability, diff...

  15. A mass transfer model of ethanol emission from thin layers of corn silage

    Technology Transfer Automated Retrieval System (TEKTRAN)

    A mass transfer model of ethanol emission from thin layers of corn silage was developed and validated. The model was developed based on data from wind tunnel experiments conducted at different temperatures and air velocities. Multiple regression analysis was used to derive an equation that related t...

  16. Effect of mass transfer on the oxygen reduction reaction catalyzed by platinum dendrimer encapsulated nanoparticles

    PubMed Central

    Dumitrescu, Ioana; Crooks, Richard M.

    2012-01-01

    Here we report on the effect of the mass transfer rate (kt) on the oxygen reduction reaction (ORR) catalyzed by Pt dendrimer-encapsulated nanoparticles (DENs) comprised of 147 and 55 atoms (Pt147 and Pt55). The experiments were carried out using a dual-electrode microelectrochemical device, which enables the study of the ORR under high kt conditions with simultaneous detection of H2O2. At low kt (0.02 to 0.12 cm s-1) the effective number of electrons involved in ORR, neff, is 3.7 for Pt147 and 3.4 for Pt55. As kt is increased, the mass-transfer-limited current for the ORR becomes significantly lower than the value predicted by the Levich equation for a 4-electron process regardless of catalyst size. However, the percentage of H2O2 detected remains constant, such that neff barely changes over the entire kt range explored (0.02 cm s-1). This suggests that mass transfer does not affect neff, which has implications for the mechanism of the ORR on Pt nanoparticles. Interestingly, there is a significant difference in neff for the two sizes of Pt DENs (neff = 3.7 and 3.5 for Pt147 and Pt55, respectively) that cannot be assigned to mass transfer effects and that we therefore attribute to a particle size effect. PMID:22665772

  17. Demonstrating the Effect of Interphase Mass Transfer in a Transparent Fluidized Bed Reactor

    ERIC Educational Resources Information Center

    Saayman, Jean; Nicol, Willie

    2011-01-01

    A demonstration experiment is described that employs the ozone decomposition reaction at ambient conditions on Fe2O3 impregnated Fluidized Catalytic Cracking (FCC) catalyst. Using a two-dimensional see-through column the importance of interphase mass transfer is clearly illustrated by the significant difference in ozone conversion between the…

  18. A Laboratory Experiment for Measuring Solid-Liquid Mass Transfer Parameters

    ERIC Educational Resources Information Center

    Dapia, Sonia; Vila, Carlos; Dominguez, Herminia; Parajo, Juan Carlos

    2004-01-01

    The lab experiment described starts from the principles developed by Sensel and Myers, but the experimental procedure are modified to provide a more reliable experiment assessment. The mass transfer equation is solved and all the involved parameters are calculated by a simple, numerical method.

  19. FUNDAMENTAL MASS TRANSFER MODEL FOR INDOOR AIR EMISSION FROM SURFACE COATINGS

    EPA Science Inventory

    The paper, discusses the work of researchers at the U.S. EPA's Air and Energy Engineering Research Laboratory (Indoor Air Branch) who are evaluating mass transfer models based on fundamental principles to determine their effectiveness in predicting emissions from indoor architect...

  20. Dissociation and ammonia mass transfer from ammonium solution and dairy cattle manure

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Process-based models are being used to predict ammonia (NH**3) emissions from manure sources, but their accuracy has not been fully evaluated for cattle manure. Laboratory trials were conducted to measure the dissociation and mass transfer coefficient for NH**3 volatilization from media of buffered ...

  1. Determination of Heat and Mass Transfer Efficiency on a Bubbling Plate with Account for Scale Transition

    NASA Astrophysics Data System (ADS)

    Laptev, A. G.; Lapteva, E. A.

    2015-07-01

    The efficiency of heat and mass transfer in the bubbling bed on the plate has been investigated with the use of the method of combined physical and mathematical modeling based on the representation of the physical process in the form of a combination of elementary phenomena having a hierarchy of scales that permits realizing a scale transition in designing a contact device. The mathematical modeling of the heat and mass transfer in the above bed is based on the idea that the structure of this bed is invariant with its size and the interaction of the phases in it. A parametric investigation of the interaction of various effects in the process of heat and mass transfer in the bubbling bed on the plate and their conjugation has been carried out on the basis of the variational formulation of the conservation laws. Examples of calculating the efficiencies of the heat and mass transfer processes on bubbling plates are given. The results of calculations were compared with the corresponding experimental data.

  2. Mass transfer coefficient in ginger oil extraction by microwave hydrotropic solution

    NASA Astrophysics Data System (ADS)

    Handayani, Dwi; Ikhsan, Diyono; Yulianto, Mohamad Endy; Dwisukma, Mandy Ayulia

    2015-12-01

    This research aims to obtain mass transfer coefficient data on the extraction of ginger oil using microwave hydrotropic solvent as an alternative to increase zingiberene. The innovation of this study is extraction with microwave heater and hydrotropic solvent,which able to shift the phase equilibrium, and the increasing rate of the extraction process and to improve the content of ginger oil zingiberene. The experiment was conducted at the Laboratory of Separation Techniques at Chemical Engineering Department of Diponegoro University. The research activities carried out in two stages, namely experimental and modeling work. Preparation of the model postulated, then lowered to obtain equations that were tested and validated using data obtained from experimental. Measurement of experimental data was performed using microwave power (300 W), extraction temperature of 90 ° C and the independent variable, i.e.: type of hydrotropic, the volume of solvent and concentration in order, to obtain zingiberen levels as a function of time. Measured data was used as a tool to validate the postulation, in order to obtain validation of models and empirical equations. The results showed that the mass transfer coefficient (Kla) on zingiberene mass transfer models ginger oil extraction at various hydrotropic solution attained more 14 ± 2 Kla value than its reported on the extraction with electric heating. The larger value of Kla, the faster rate of mass transfer on the extraction process. To obtain the same yields, the microwave-assisted extraction required one twelfth time shorter.

  3. Mass transfer coefficients developed from the air gasification of wood pellets

    SciTech Connect

    Botts, J.W.

    1998-07-01

    A convertible updraft/downdraft, fixed-bed gasifier was used in the gasification of 3/8-inch diameter wood pellets. The test data was used to develop mass transfer coefficients and describe the gasification process for each gasifier configuration. The results show that the production of the principal combustion gases, i.e., hydrogen (H{sub c}), carbon monozide (CO), and methane (CH{sub 4}), varies directly as to their mass transfer coefficient: H{sub 2}, CO, and CH{sub 4} = k h{sub DA}. Factoring the Reynolds (Re{sub d}) and Schmidt (Sc) numbers with the influence of the noncombustible gases, i.e., nitrogen (N{sub 2}), oxygen (O{sub 2}), and carbon dioxide (CO{sub 2}), is used to define the mass transfer coefficients. The general form describing this joint variation is: H{sub 2}, CO, and CH{sub 4} = kx (the effect of the noncombustible gases) x Re x Sc where Re = Reynolds number and Sc = Schmidt number. The developments of these mass transfer coefficients are shown for updraft and downdraft gasification.

  4. Mass Transfer Testing of a 12.5-cm Rotor Centrifugal Contactor

    SciTech Connect

    D. H. Meikrantz; T. G. Garn; J. D. Law; N. R. Mann; T. A. Todd

    2008-09-01

    TRUEX mass transfer tests were performed using a single stage commercially available 12.5 cm centrifugal contactor and stable cerium (Ce) and europium (Eu). Test conditions included throughputs ranging from 2.5 to 15 Lpm and rotor speeds of 1750 and 2250 rpm. Ce and Eu extraction forward distribution coefficients ranged from 13 to 19. The first and second stage strip back distributions were 0.5 to 1.4 and .002 to .004, respectively, throughout the dynamic test conditions studied. Visual carryover of aqueous entrainment in all organic phase samples was estimated at < 0.1 % and organic carryover into all aqueous phase samples was about ten times less. Mass transfer efficiencies of = 98 % for both Ce and Eu in the extraction section were obtained over the entire range of test conditions. The first strip stage mass transfer efficiencies ranged from 75 to 93% trending higher with increasing throughput. Second stage mass transfer was greater than 99% in all cases. Increasing the rotor speed from 1750 to 2250 rpm had no significant effect on efficiency for all throughputs tested.

  5. The ultrasonic-enhanced factor of mass-transfer coefficient in the supercritical carbon dioxide extraction

    NASA Astrophysics Data System (ADS)

    Luo, Benyi; Lu, Yigang

    2008-10-01

    Based on several hypotheses about the process of supercritical carbon dioxide extraction, the onflow around the solute granule is figured out by the Navier-Stocks equation. In combination with the Higbie’s solute infiltration model, the link between the mass-transfer coefficient and the velocity of flow is found. The mass-transfer coefficient with the ultrasonical effect is compared with that without the ultrasonical effect, and then a new parameter named the ultrasonic-enhanced factor of mass-transfer coefficient is brought forward, which describes the mathematical model of the supercritical carbon dioxide extraction process enhanced by ultrasonic. The model gives out the relationships among the ultrasonical power, the ultrasonical frequency, the radius of solute granule and the ultrasonic-enhanced factor of mass-transfer coefficient. The results calculated by this model fit well with the experimental data, including the extraction of Coix Lacryma-jobi Seed Oil (CLSO) and Coix Lacryma-jobi Seed Ester (CLSE) from coix seeds and the extraction of Eicosapentaenoic Acid (EPA) and Docosahexaenoic Acid (DHA) from the alga by means of the ultrasonic-enhanced supercritical carbon dioxide extraction (USFE) and the supercritical carbon dioxide extraction (SFE) respectively. This proves the rationality of the ultrasonic-enhanced factor model. The model provides a theoretical basis for the application of ultrasonic-enhanced supercritical fluid extraction technique.

  6. Numerical Problems and Agent-Based Models for a Mass Transfer Course

    ERIC Educational Resources Information Center

    Murthi, Manohar; Shea, Lonnie D.; Snurr, Randall Q.

    2009-01-01

    Problems requiring numerical solutions of differential equations or the use of agent-based modeling are presented for use in a course on mass transfer. These problems were solved using the popular technical computing language MATLABTM. Students were introduced to MATLAB via a problem with an analytical solution. A more complex problem to which no…

  7. Empirical correlation of volumetric mass transfer coefficient for a rectangular internal-loop airlift bioreactor

    Technology Transfer Automated Retrieval System (TEKTRAN)

    An empirical correlation of volumetric mass transfer coefficient was developed for a pilot scale internal-loop rectangular airlift bioreactor that was designed for biotechnology. The empirical correlation combines classic turbulence theory, Kolmogorov’s isotropic turbulence theory with Higbie’s pen...

  8. Measurement of mass-transfer rates for surfactant-enhanced solubilization of nonaqueous phase liquids

    SciTech Connect

    Mayer, A.S.; Zhong, L.; Pope, G.A.

    1999-09-01

    Surfactant-enhanced solubilization of residual, non-aqueous-phase liquid (NAPL) contaminants is an emerging, subsurface remediation technology. The potential for nonequilibrium conditions is investigated for surfactant-enhanced solubilization of a NAPL, trichlorethylene (TCE), in a model porous medium. The surfactant formulation consists of an anionic surfactant, sodium dihexyl sulfosuccinate, an alcohol, and an electrolyte in aqueous solution. Batch solubilization experiments are conducted to assess the significant of chemical rate limitations. Surfactant flood experiments are conducted in packed columns with residual TCE. Mass-transfer rate coefficients are determined as a function of aqueous-phase pore velocity, NAPL volumetric fraction, and surfactant concentration. A correlation for predicting mass-transfer rate coefficients as a function of system properties is developed. The mass-transfer rate coefficients and correlation are obtained by fitting a transport simulator to the column effluent concentration results. Significant differences are found between the correlation developed here and correlations developed for other NAPL--surfactant systems. The correlation predicts near-linear dependences of mass-transfer rates on the NAPL volumetric fraction and pore velocity. Using the Damkohler number, the degree of nonequilibrium behavior in surfactant-enhanced NAPL solubilization is analyzed for a range of conditions. Nonequilibrium conditions are found to be significant at relatively low NAPL volumetric fractions.

  9. Hydrodynamic characteristics and gas-liquid mass transfer in a biofilm airlift suspension reactor.

    PubMed

    Nicolella, C; van Loosdrecht, M C; van der Lans, R G; Heijnen, J J

    1998-12-01

    The hydrodynamics and mass transfer, specifically the effects of gas velocity and the presence and type of solids on the gas hold-up and volumetric mass transfer coefficient, were studied on a lab-scale airlift reactor with internal draft tube. Basalt particles and biofilm-coated particles were used as solid phase. Three distinct flow regimes were observed with increasing gas flow rate. The influence of the solid phase on the hydrodynamics was a peculiar characteristic of the regimes. The volumetric mass transfer coefficient was found to decrease with increasing solid loading and particle size. This could be predominantly related to the influence that the solid has on gas hold-up. The ratio between gas hold-up and volumetric mass transfer coefficient was found to be independent of solid loading, size, or density, and it was proven that the presence of solids in airlift reactors lowers the number of gas bubbles without changing their size. To evaluate scale effects, experimental results were compared with theoretical and empirical models proposed for similar systems. PMID:10099471

  10. MASS TRANSFER IN BINARY STARS USING SMOOTHED PARTICLE HYDRODYNAMICS. II. ECCENTRIC BINARIES

    SciTech Connect

    Lajoie, Charles-Philippe; Sills, Alison E-mail: asills@mcmaster.ca

    2011-01-10

    Despite numerous efforts to better understand binary star evolution, some aspects of it remain poorly constrained. In particular, the evolution of eccentric binaries has remained elusive mainly because the Roche lobe formalism derived for circular binaries does not apply. Here we report the results of our smoothed particle hydrodynamic simulations of mass transfer in eccentric binaries using an alternate method in which we model only the outermost layers of the stars with appropriate boundary conditions. Using this technique, along with properly relaxed model stars, we characterize the mass transfer episodes of binaries with various orbital parameters. In particular, we show that these episodes can be described by Gaussians with an FWHM of {approx}0.12P{sub orb} and that the peak rates occur after periastron, at an orbital phase of {approx}0.58, independently of the eccentricity and mass of the stars. The accreted material is observed to form a rather sparse envelope around either or both stars. Although the fate of this envelope is not modeled in our simulations, we show that a constant fraction ({approx}5%) of the material transferred is ejected from the systems. We discuss this result in terms of the non-conservative mass transfer scenario. We suggest that our results could be incorporated in analytical and binary population synthesis studies to help better understand the evolution of eccentric binaries and the formation of exotic stellar populations.

  11. The effects of recirculation flows on mass transfer from the arterial wall to flowing blood.

    PubMed

    Zhang, Zhiguo; Deng, Xiaoyan; Fan, Yubo; Guidoin, Robert

    2008-01-01

    Using a sudden tubular expansion as a model of an arterial stenosis, the effect of disturbed flow on mass transfer from the arterial wall to flowing blood was studied theoretically and tested experimentally by measuring the dissolution rate of benzoic acid disks forming the outer tube of a sudden tubular expansion. The study revealed that mass transfer from vessel wall to flowing fluid in regions of disturbed flow is independent of wall shear rates. The rate of mass transfer is significantly higher in regions of disturbed flow with a local maximum around the reattachment point where the wall shear rate is zero. The experimental study also revealed that the rate of mass transfer from the vessel wall to a flowing fluid is much higher in the presence of microspheres (as models of blood cells) in the flowing fluid and under the condition of pulsatile flow than in steady flow. These results imply that flow disturbance may enhance the transport of biochemicals and macromolecules, such as plasma proteins and lipoproteins synthesized within the blood vessel wall, from the blood vessel wall to flowing blood. PMID:18204314

  12. Diffuse boundary extraction of breast masses on ultrasound by leak plugging

    SciTech Connect

    Cary, T.W.; Conant, E.F.; Arger, P.H.; Sehgal, C.M.

    2005-11-15

    We propose a semiautomated seeded boundary extraction algorithm that delineates diffuse region boundaries by finding and plugging their leaks. The algorithm not only extracts boundaries that are partially diffuse, but in the process finds and quantifies those parts of the boundary that are diffuse, computing local sharpness measurements for possible use in computer-aided diagnosis. The method treats a manually drawn seed region as a wellspring of pixel 'fluid' that flows from the seed out towards the boundary. At indistinct or porous sections of the boundary, the growing region will leak into surrounding tissue. By changing the size of structuring elements used for growing, the algorithm changes leak properties. Since larger elements cannot leak as far from the seed, they produce compact, less detailed boundary approximations; conversely, growing from smaller elements results in less constrained boundaries with more local detail. This implementation of the leak plugging algorithm decrements the radius of structuring disks and then compares the regions grown from them as they increase in both area and boundary detail. Leaks are identified if the outflows between grown regions are large compared to the areas of the disks. The boundary is plugged by masking out leaked pixels, and the process continues until one-pixel-radius resolution. When tested against manual delineation on scans of 40 benign masses and 40 malignant tumors, the plugged boundaries overlapped and correlated well in area with manual tracings, with mean overlap of 0.69 and area correlation R{sup 2} of 0.86, but the algorithm's results were more reproducible.

  13. Natural convection mass transfer at a vertical array of closely-spaced horizontal cylinders with special reference to electrochemical reactor design

    SciTech Connect

    Sedahmed, G.H.; Nirdosh, I.

    1995-06-01

    Many industrial electrochemical processes such as electrowinning of metals, electrochemical pollution control, and electroorganic and electroinorganic syntheses are diffusion-controlled processes whose rates depend on the geometry of the working electrode as well as the prevailing hydrodynamic conditions. Recently much work has been done to develop new electrochemical reactors which are more efficient than the traditional parallel plate electrochemical reactor used in conducting such processes. In line with this, the object of the present work was to study the natural convection mass transfer behavior of a new electrode geometry, namely an array of closely-spaced horizontal tubes. Natural convection mass transfer at a vertical array of closely-spaced horizontal cylinders was studied by an electrochemical technique involving the measurement of the limiting current of the cathodic deposition of copper from acidified copper sulfate solution. Various combinations of solution concentration, cylinder diameter, and number of cylinders per array were used including experiments on single cylinders. The mass transfer coefficient at the array was found to decrease with increasing number of cylinders, pass through a minimum, and then increase with further increase in the number of cylinders per array; the mass transfer coefficient increased with increasing cylinder diameter in the array. Mass transfer data for different arrays were correlated for the range 6.3 {times} 10{sup 9} < ScGr < 3.63 {times} 10{sup 10} by the equation Sh = 0.455(ScGr){sup 0.25} and for the range 6.3 {times} 10{sup 10} < ScGr < 3.63 {times} 10{sup 12} by the equation Sh = 0.0064(ScGr){sup 0.42}. The characteristic length used in the above correlations was obtained by dividing the array area by the perimeter projected onto a horizontal plane. Practical implications of the present results in designing electrochemical reactors with heat transfer facilities are highlighted.

  14. Local endwall heat/mass-transfer distributions in pin fin channels

    NASA Astrophysics Data System (ADS)

    Lau, S. C.; Kim, Y. S.; Han, J. C.

    1987-10-01

    Naphthalene sublimination experiments were conducted to study the effects of the pin configuration, the pin length-to-diameter ratio, and the entrance length on local endwall heat/mass transfer in a channel with short pin fins (pin length-to-diameter ratios of 0.5 and 1.0). The detailed distributions of the local endwall heat/mass-transfer coefficient were obtained for staggered and aligned arrays of pin fins, for the spanwise pin spacing-to-diameter ratio of 2.5, and for streamwise pin spacing-to-diameter ratios of 1.25 and 2.5. The Reynolds numbers were kept at about 33,000. Overall- and row-averaged Nusselt numbers compared very well with those from previous heat-transfer studies.

  15. Numerical Analysis of Simultaneous Heat and Mass Transfer in Cork Lightweight Concretes Used in Building Envelopes

    NASA Astrophysics Data System (ADS)

    Sotehi, Nassima; Chaker, Abla

    A numerical study was carried out in order to investigate the behaviour of building envelopes made of lightweight concretes. In this work, we are particularly interested to the building envelopes which are consist of cement paste with incorporation of cork aggregates in order to obtain small thermal conductivity and low-density materials. The mathematical formulation of coupled heat and mass transfer in wet porous materials has been made using Luikov's model, the system describing temperature and moisture transfer processes within building walls is solved numerically with the finite elements method. The obtained results illustrate the temporal evolutions of the temperature and the moisture content, and the distributions of the temperature and moisture content inside the wall for several periods of time. They allow us to specify the effect of the nature and dosage of fibre on the heat and mass transfer.

  16. Freeze-drying in novel container system: Characterization of heat and mass transfer in glass syringes.

    PubMed

    Patel, Sajal M; Pikal, Michael J

    2010-07-01

    This study is aimed at characterizing and understanding different modes of heat and mass transfer in glass syringes to develop a robust freeze-drying process. Two different holder systems were used to freeze-dry in syringes: an aluminum (Al) block and a plexiglass holder. The syringe heat transfer coefficient was characterized by a sublimation test using pure water. Mannitol and sucrose (5% w/v) were also freeze-dried, as model systems, in both the assemblies. Dry layer resistance was determined from manometric temperature measurement (MTM) and product temperature was measured using thermocouples, and was also determined from MTM. Further, freeze-drying process was also designed using Smart freeze-dryer to assess its application for freeze-drying in novel container systems. Heat and mass transfer in syringes were compared against the traditional container system (i.e., glass tubing vial). In the Al block, the heat transfer was via three modes: contact conduction, gas conduction, and radiation with gas conduction being the dominant mode of heat transfer. In the plexiglass holder, the heat transfer was mostly via radiation; convection was not involved. Also, MTM/Smart freeze-drying did work reasonably well for freeze-drying in syringes. When compared to tubing vials, product temperature decreases and hence drying time increases in syringes. PMID:20166199

  17. Heat and mass transfer performances on plate fin and tube heat exchangers with dehumidification

    SciTech Connect

    Seshimo, Y.; Ogawa, K.; Marumoto, K.; Fujii, M. )

    1990-09-01

    The authors discuss how they conducted an experimental study on the air side performance of a single-row plate fin and tube heat exchanger in moist air where mass transfer exist under a relatively low driving potential. The results are as follows: The heat transfer with dehumidification is about 20% greater than that with only sensible heat transfer. Also the air side pressure drop is about 30-40% greater. The reason, as clarified by visual observations, comes from the condensate effect. To study how the condensate film affects performance, the presence of the stagnant condensate in the heat exchanger was modeled as an apparent change of the heat exchanger geometry, and the equivalent thickness of the condensate film was calculated from the increase in the air side pressure drop. As a result, if the presence of condensate in the heat exchanger is considered, then the heat transfer with dehumidification can be treated in the same way as with only sensible heat transfer. The analogy between heat and mass transfer does not strictly hold, the experimental results being closed to the Lewis Law.

  18. On the role of mass diffusion and fluid dynamics in the dissipation of chunk mix

    SciTech Connect

    Cloutman, L D

    1999-03-01

    When numerically simulating multicomponent turbulent flows, subgrid-scale diffusion of chemical species requires closure. This mixing of chemical species at the molecular level dissipates concentration uctuations, which limits possible demixing and affects other pro- cesses such as energy transport and reaction rates at the subgrid level. We discuss some of the physical processes that reduce small chunks of a heavy material in a light gas or plasma to a mixture at the atomic level. Preliminary direct numerical simulations of these processes are presented using the dissipation of small spheres of heavy gas in a light gas as an archetypal process in turbulent micromixing in multicomponent ows, including classical uid instabilities and shock ejecta. We use a detailed approach for the diffusion process, directly solving the Stefan-Maxwell equations for the mass fluxes. We discuss the dissipa- tion of a 24µm sphere of xenon in helium in three different flow regimes, and we present suggestions for future work intended as input to improved subgrid-scale turbulence models.

  19. Pore Network Simulation to Develop Electrical Petrophysical Relations in the Presence of Mass Transfer

    NASA Astrophysics Data System (ADS)

    Day-Lewis, F. D.; Haggerty, R.; Singha, K.; Binley, A.; Swanson, R. D.; Clifford, J.; Lane, J. W.; Ward, A. L.; Johnson, T. J.

    2011-12-01

    In both field and laboratory settings, time-lapse electrical measurements have indicated rate-limited mass transfer of ionic tracer between mobile and immobile (or less mobile) domains in porous media over a range of flow rates and time scales. In previous work, a simple bicontinuum extension of Archie's Law was used to relate direct-current bulk conductivity and fluid conductivity assuming that the mobile and immobile domains contribute as conductors in parallel with weights given by porosity fraction; however, other petrophysical models may account for the effect of internal connectivity of each domain on its relative contribution to bulk conductivity. Additional work is required to (1) evaluate the bicontinuum Archie formulation relative to these other models for bulk conductivity of multiphase (i.e., multidomain) media with application to mass-transfer problems, and (2) characterize the geoelectrical signature of mass transfer for porous media with different pore geometries and electrical properties. To address this long standing problem, we developed a coupled fluid flow, electrical conduction, and solute transport simulator for two-dimensional pore networks. The pore space is modeled as a pipe lattice where pipes are square in cross section with widths drawn from random distributions. Pipe conductances for the fluid flow problem are assigned according to Hagen-Pouseuille flow, and the conservation problem is solved. Alternative to computationally intensive simulation of transient advective-dispersive transport, we adopt a more efficient but approximate two-step approach. First, we find the zeroth and first temporal moments throughout the network by solving sequentially two steady-state transport problems; from these results we calculate mean arrival time for each node in the network. Second, we convert the calculated mean arrival times to mass-transfer rates for input to a semi-analytical multi-rate mass transfer model to simulate gross transport through a

  20. About Mass Transfer in Capillaries of Biological Systems under Influence of Vibrations

    NASA Astrophysics Data System (ADS)

    Prisniakov, K.

    Vibrations accompany the flight of the manned spacecraft both at a stage of a orbital injection to an orbit, and during long flights (as noise), rendering undesirable physiological influence on crew, reducing serviceability and creating constant discomfort. The report represents attempt to predict a state of the cosmonaut in conditions of influence of vibrations for the period of start and stay in Space, being based on researches of mass transfer processes in capillary systems. For this purpose the original researches on heat and mass transfer processes with evaporation of liquids in capillary - porous structures in conditions of vibration actions and changes of a direction of action of gravitation are generalized. Report demonstrates the existence of modes at which increased or lowered mass transfer is achieved on border of separation "liquid - gas". The possible mechanism of influence of vibrations on evaporation of a liquid in capillaries is examined. The magnitudes of frequencies and amplitudes are submitted at which minimax characteristics are observed. The opportunity of application of the developed mathematical model of heat and mass transfer in capillary - porous structures to forecasting influence of vibrations for biological processes in capillaries of alive essences is analyzed. Such approach is justified on the mechanical nature of harmful influence of vibrations on an organism of the person. In addition the range of vibration frequencies which arise during space flights, corresponds to own resonant frequencies of a human body and his separate organs. Comparison of these resonant frequencies of a body of the person (5-80 Hertz) with vibration frequencies of optimum modes of heat and mass transfer in capillary - porous structures (20-40 Hertz) is shown their ranges of coverage. It gives the basis to assume existence of similar effects in capillaries of human body. It is supposed, that the difficulty of breath, change of a rhythm of breath, the subsequent

  1. Effect of laminar unsteady fluid flows on mass transfer in electrochemical systems

    NASA Astrophysics Data System (ADS)

    Shehata, Ahmed Kamal

    1999-11-01

    A numerical study of mass transfer in steady as well as unsteady two-dimensional laminar channel flows is investigated. When a circular cylinder is suspended in a steady flow stream, the flow becomes unsteady and oscillates periodically for Reynolds numbers, Re, between 200 and 800 (where Re is based on the channel height) due to the formation of the Karman vortex street. This well- characterized unsteady periodic flow is utilized to study mass transfer rates at different positions downstream of the blocking cylinder. The study consisted of mass transfer to a channel wall and mass transfer to the bottom surface of rectangular cavities, of different depth/width ratios. All investigated positions, including cavity position, are located downstream of the blocking cylinder. The study also included the mass transfer to a channel wall in a steady fully-developed flow when a hemi-cylindrical bump is located at the lower wall. The results of the numerical simulations are then compared to the experimental data. The numerical and experimental results are found to be generally in good agreement. Structured multi-block grids are utilized for the fluid flow simulations. It is shown that grids can be created differently with different block topologies. Solution accuracy is shown to be strongly affected by the shape as well as the densities of the resulting grids. The finite element method is used to simulate the fluid flow while for the concentration field a procedure based on the finite volume method is used. The strength of the flow at the cavity mouth was found to scale linearly with wall shear in the absence of the cavity for steady channel flow. The flow at the cavity mouth was also found to be independent of the cavity depth for both steady and unsteady flows. Based on these observations it is possible to predict cavity flows and cavity mass transfer without computing the flow in the entire channel plus cavity domain when studying different cavity aspect ratios. A

  2. Differentiation of the functional in an optimization problem for diffusion and convective transfer coefficients of elliptic imperfect contact interface problems

    NASA Astrophysics Data System (ADS)

    Manapova, Aigul

    2016-08-01

    We consider optimal control problems for second order elliptic equations with non-self-adjoint operators-convection-diffusion problems. Control processes are described by semi-linear convection-diffusion equation with discontinuous data and solutions (states) subject to the boundary interface conditions of imperfect type (i.e., problems with a jump of the coefficients and the solution on the interface; the jump of the solution is proportional to the normal component of the flux). Controls are involved in the coefficients of diffusion and convective transfer. We prove differentiability and Lipshitz continuity of the cost functional, depending on a state of the system and a control. The calculation of the gradients uses the numerical solutions of direct problems for the state and adjoint problems.

  3. Hybrid model of light propagation in random media based on the time-dependent radiative transfer and diffusion equations

    NASA Astrophysics Data System (ADS)

    Fujii, Hiroyuki; Okawa, Shinpei; Yamada, Yukio; Hoshi, Yoko

    2014-11-01

    Numerical modeling of light propagation in random media has been an important issue for biomedical imaging, including diffuse optical tomography (DOT). For high resolution DOT, accurate and fast computation of light propagation in biological tissue is desirable. This paper proposes a space-time hybrid model for numerical modeling based on the radiative transfer and diffusion equations (RTE and DE, respectively) in random media under refractive-index mismatching. In the proposed model, the RTE and DE regions are separated into space and time by using a crossover length and the time from the ballistic regime to the diffusive regime, ρDA~10/μt‧ and tDA~20/vμt‧ where μt‧ and v represent a reduced transport coefficient and light velocity, respectively. The present model succeeds in describing light propagation accurately and reduces computational load by a quarter compared with full computation of the RTE.

  4. Elastic stress transfer as a diffusive process due to aseismic fault slip in response to fluid injection

    NASA Astrophysics Data System (ADS)

    Viesca, R. C.

    2015-12-01

    Subsurface fluid injection is often followed by observations of an enlarging cloud of microseismicity. The cloud's diffusive growth is thought to be a direct response to the diffusion of elevated pore fluid pressure reaching pre-stressed faults, triggering small instabilities; the observed high rates of this growth are interpreted to reflect a relatively high permeability of a fractured subsurface [e.g., Shapiro, GJI 1997]. We investigate an alternative mechanism for growing a microseismic cloud: the elastic transfer of stress due to slow, aseismic slip on a subset of the pre-existing faults in this damaged subsurface. We show that the growth of the slipping region of the fault may be self-similar in a diffusive manner. While this slip is driven by fluid injection, we show that, for critically stressed faults, the apparent diffusion of this slow slip may quickly exceed the poroelastically driven diffusion of the elevated pore fluid pressure. Under these conditions, microseismicity can be first triggered by the off-fault stress perturbation due to the expanding region of slip on principal faults. This provides an alternative interpretation of diffusive growth rates in terms of the subsurface stress state rather than an enhanced hydraulic diffusivity. That such aseismic slip may occur, outpace fluid diffusion, and in turn trigger microseismic events, is also suggested by on- and near-fault observations in past and recently reported fluid injection experiments [e.g., Cornet et al., PAGEOPH 1997; Guglielmi et al., Science 2015]. The model of injection-induced slip assumes elastic off-fault behavior and a fault strength determined by the product of a constant friction coefficient and the local effective normal stress. The sliding region is enlarged by the pore pressure increase resolved on the fault plane. Remarkably, the rate of self-similar expansion may be determined by a single parameter reflecting both the initial stress state and the magnitude of the pore pressure

  5. GRAVITATIONAL INSTABILITY OF SOLIDS ASSISTED BY GAS DRAG: SLOWING BY TURBULENT MASS DIFFUSIVITY

    SciTech Connect

    Shariff, Karim; Cuzzi, Jeffrey N.

    2011-09-01

    The Goldreich and Ward (axisymmetric) gravitational instability of a razor thin particle layer occurs when the Toomre parameter Q{sub T} {identical_to} c{sub p}{Omega}{sub 0}/{pi}G{Sigma}{sub p} < 1 (c{sub p} being the particle dispersion velocity). Ward extended this analysis by adding the effect of gas drag upon particles and found that even when Q{sub T} > 1, sufficiently long waves were always unstable. Youdin carried out a detailed analysis and showed that the instability allows chondrule-sized ({approx}1 mm) particles to undergo radial clumping with reasonable growth times even in the presence of a moderate amount of turbulent stirring. The analysis of Youdin includes the role of turbulence in setting the thickness of the dust layer and in creating a turbulent particle pressure in the momentum equation. However, he ignores the effect of turbulent mass diffusivity on the disturbance wave. Here, we show that including this effect reduces the growth rate significantly, by an amount that depends on the level of turbulence, and reduces the maximum intensity of turbulence the instability can withstand by 1-3 orders of magnitude. The instability is viable only when turbulence is extremely weak and the solid to gas surface density of the particle layer is considerably enhanced over minimum-mass-nebula values. A simple mechanistic explanation of the instability shows how the azimuthal component of drag promotes instability while the radial component hinders it. A gravito-diffusive overstability is also possible but never realized in the nebula models.

  6. An Eddy-Diffusivity/Mass-Flux Turbulence Parameterization: Application to Dust Convection on Mars

    NASA Astrophysics Data System (ADS)

    Witek, M. L.; Teixeira, J.; Richardson, M. I.; Mischna, M. A.

    2014-12-01

    The Eddy-diffusivity/Mass-flux (EDMF) parameterization has been extremely successful in simulating the evolution of terrestrial atmospheric boundary layers. It is particularly suited for representing strong and moderate convection, where turbulence organizes in coherent structures and transports heat, humidity and pollution throughout the extent of the boundary layer. The EDMF's ability to explicitly represent turbulent updrafts and associated fluxes is key to a proper depiction of the thermodynamic structure of the atmosphere. It is the most appropriate tool currently available to address the outstanding issues in the Mars atmosphere and dust modeling on a global and regional scale. Dust is one of the most important moderators of the Martian climate. Basic theoretical arguments and observations such as high-altitude dust maxima, dust layering, and transport in plumes during dust storm onset—none of which are currently captured in general circulation models (GCMs)—all demonstrate the vital importance of representing dust vertical mixing by plumes. Most GCMs, however, only consider local, Mellor-Yamada-type diffusion, which is insufficient to capture the evolving dust distribution and hence the Martian climate system correctly. Here, we developed an EDMF parameterization for the Martian convective boundary layer. We report on details of the parameterization and its performance as compared against large-eddy simulations. We investigate a downdraft contribution to turbulent fluxes and the importance of mass-flux transport of TKE. Furthermore, we investigate the role of plume heating—through absorption of solar radiation by uplifted dust particles—on the plume evolution (a mechanisms that could act as a surrogate of the latent heat release in terrestrial clouds). Our results shed light on the reasons behind the presence of elevated dust layers in the Martian atmosphere.

  7. THE HALO MASS FUNCTION FROM EXCURSION SET THEORY. II. THE DIFFUSING BARRIER

    SciTech Connect

    Maggiore, Michele; Riotto, Antonio

    2010-07-01

    In excursion set theory, the computation of the halo mass function is mapped into a first-passage time process in the presence of a barrier, which in the spherical collapse model is a constant and in the ellipsoidal collapse model is a fixed function of the variance of the smoothed density field. However, N-body simulations show that dark matter halos grow through a mixture of smooth accretion, violent encounters, and fragmentations, and modeling halo collapse as spherical, or even as ellipsoidal, is a significant oversimplification. In addition, the very definition of what is a dark matter halo, both in N-body simulations and observationally, is a difficult problem. We propose that some of the physical complications inherent to a realistic description of halo formation can be included in the excursion set theory framework, at least at an effective level, by taking into account that the critical value for collapse is not a fixed constant {delta}{sub c}, as in the spherical collapse model, nor a fixed function of the variance {sigma} of the smoothed density field, as in the ellipsoidal collapse model, but rather is itself a stochastic variable, whose scatter reflects a number of complicated aspects of the underlying dynamics. Solving the first-passage time problem in the presence of a diffusing barrier we find that the exponential factor in the Press-Schechter mass function changes from exp{l_brace}-{delta}{sup 2}{sub c}/2{sigma}{sup 2{r_brace}} to exp{l_brace}-a{delta}{sup 2}{sub c}/2{sigma}{sup 2{r_brace}}, where a = 1/(1 + D{sub B}) and D{sub B} is the diffusion coefficient of the barrier. The numerical value of D{sub B} , and therefore the corresponding value of a, depends among other things on the algorithm used for identifying halos. We discuss the physical origin of the stochasticity of the barrier and, from recent N-body simulations that studied the properties of the collapse barrier, we deduce a value D{sub B} {approx_equal} 0.25. Our model then predicts a

  8. A 17-billion-solar-mass black hole in a group galaxy with a diffuse core

    NASA Astrophysics Data System (ADS)

    Thomas, Jens; Ma, Chung-Pei; McConnell, Nicholas J.; Greene, Jenny E.; Blakeslee, John P.; Janish, Ryan

    2016-04-01

    Quasars are associated with and powered by the accretion of material onto massive black holes; the detection of highly luminous quasars with redshifts greater than z = 6 suggests that black holes of up to ten billion solar masses already existed 13 billion years ago. Two possible present-day ‘dormant’ descendants of this population of ‘active’ black holes have been found in the galaxies NGC 3842 and NGC 4889 at the centres of the Leo and Coma galaxy clusters, which together form the central region of the Great Wall—the largest local structure of galaxies. The most luminous quasars, however, are not confined to such high-density regions of the early Universe; yet dormant black holes of this high mass have not yet been found outside of modern-day rich clusters. Here we report observations of the stellar velocity distribution in the galaxy NGC 1600—a relatively isolated elliptical galaxy near the centre of a galaxy group at a distance of 64 megaparsecs from Earth. We use orbit superposition models to determine that the black hole at the centre of NGC 1600 has a mass of 17 billion solar masses. The spatial distribution of stars near the centre of NGC 1600 is rather diffuse. We find that the region of depleted stellar density in the cores of massive elliptical galaxies extends over the same radius as the gravitational sphere of influence of the central black holes, and interpret this as the dynamical imprint of the black holes.

  9. Analysis of Effect of Gas-Liquid Interfacial Disturbance on Mass Transfer Performance

    NASA Astrophysics Data System (ADS)

    Wu, Honda; Chung, Tsair-Wang

    In order to study the mass transfer phenomena for water vapor absorbed by triethylene glycol (TEG) solution and to elucidate effect of interfacial disturbance on absorption performance, the interfacial phenomena for water drop instilling on the surface of TEG solution and mass transfer process were observed and operated in this study. Besides liquid and gas flow rates, the interfacial disturbance can also affect the mass transfer performance in the absorption system with continuous liquid phase, and the advanced mass transfer phenomena must be discussed from the interface of matter. Therefore, the surface tensions of desiccant solutions were measured to analyze the disturbed phenomena of water drop instilling on the surface of TEG solution. Since the Marangoni-Index (MI) means the maximum surface tension difference on the surface of liquid layer, the values of MI were calculated and compared with the mass transfer performance of packed-bed absorber. Generally speaking, the interfacial disturbance, resulted from the surface tension difference, would promote the contacting area of gas and liquid phases. The observation of water drop instilling on surface of TEG solution found that the interfacial disturbance existed between water drop and TEG solution, and the interfacial instability was found in the peripheral region of the water drop. On the other hand, the values of MI were increased by the increased TEG concentrations, and it can be deduced that the surface tension effect should be significant in the higher concentration of TEG solution and the interfacial disturbance would be heavier above 95 wt.% TEG solutions. Finally, the absorption performance for 95 and 96 wt.% TEG solutions were much larger than that of 90 and 88.6 wt.% TEG solutions in the operation of packed-bed absorber.

  10. 3D modelling of coupled mass and heat transfer of a convection-oven roasting process.

    PubMed

    Feyissa, Aberham Hailu; Gernaey, Krist V; Adler-Nissen, Jens

    2013-04-01

    A 3D mathematical model of coupled heat and mass transfer describing oven roasting of meat has been developed from first principles. The proposed mechanism for the mass transfer of water is modified and based on a critical literature review of the effect of heat on meat. The model equations are based on a conservation of mass and energy, coupled through Darcy's equations of porous media - the water flow is mainly pressure-driven. The developed model together with theoretical and experimental assessments were used to explain the heat and water transport and the effect of the change in microstructure (permeability, water binding capacity and elastic modulus) that occur during the meat roasting process. The developed coupled partial differential equations were solved by using COMSOL Multiphysics®3.5 and state variables are predicted as functions of both position and time. The proposed mechanism was partially validated by experiments in a convection oven where temperatures were measured online. PMID:23305831

  11. Bibliography on augmentation of convective heat and mass transfer-II

    SciTech Connect

    Bergles, A.E.; Nirmalan, V.; Junkhan, G.H.; Webb, R.L.

    1983-12-01

    Heat transfer augmentation has developed into a major specialty area in heat transfer research and development. This report presents and updated bibliography of world literature on augmentation. The literature is classified into passive augmentation techniques, which require no external power, and active techniques, which do require external power. The fifteen techniques are grouped in terms of their applications to the various modes of heat transfer. Mass transfer is included for completeness. Key words are included with each citation for technique/mode identification. The total number of publications cited is 3045, including 135 surveys of various techniques and 86 papers on performance evaluation of passive techniques. Patents are not included, as they are the subject of a separate bibliographic report.

  12. THE PROCESS OF MASS TRANSFER ON THE SOLID-LIQUID BOUNDARY LAYER DURING THE RELEASE OF DICLOFENAC SODIUM AND PAPAVERINE HYDROCHLORIDE FROM TABLETS IN A PADDLE APPARATUS.

    PubMed

    Kasperek, Regina; Zimmer, Lukasz; Poleszak, Ewa

    2016-01-01

    The release study of diclofenac sodium (DIC) and papaverine hydrochloride (PAP) from two formulations of the tablets in the paddle apparatus using different rotation speeds to characterize the process of mass transfer on the solid-liquid boundary layer was carried out. The dissolution process of active substances was described by values of mass transfer coefficients, the diffusion boundary layer thickness and dimensionless numbers (Sh and Re). The values of calculated parameters showed that the release of DIC and PAP from tablets comprising potato starch proceeded faster than from tablets containing HPMC and microcrystalline cellulose. They were obtained by direct dependencies between Sh and Re in the range from 75 rpm to 125 rpm for both substances from all tablets. The description of the dissolution process with the dimensionless numbers make it possible to plan the drug with the required release profile under given in vitro conditions. PMID:27008811

  13. A risk-based probabilistic framework to estimate the endpoint of remediation: Concentration rebound by rate-limited mass transfer

    NASA Astrophysics Data System (ADS)

    Barros, F. P. J.; Fernã Ndez-Garcia, D.; Bolster, D.; Sanchez-Vila, X.

    2013-04-01

    Aquifer remediation is a challenging problem with environmental, social, and economic implications. As a general rule, pumping proceeds until the concentration of the target substance within the pumped water lies below a prespecified value. In this paper we estimate the a priori potential failure of the endpoint of remediation due to a rebound of concentrations driven by back diffusion. In many cases, it has been observed that once pumping ceases, a rebound in the concentration at the well takes place. For this reason, administrative approaches are rather conservative, and pumping is forced to last much longer than initially expected. While a number of physical and chemical processes might account for the presence of rebounding, we focus here on diffusion from low water mobility into high mobility zones. In this work we look specifically at the concentration rebound when pumping is discontinued while accounting for multiple mass transfer processes occurring at different time scales and parametric uncertainty. We aim to develop a risk-based optimal operation methodology that is capable of estimating the endpoint of remediation based on aquifer parameters characterizing the heterogeneous medium as well as pumping rate and initial size of the polluted area.

  14. Wind mass transfer in S-type symbiotic binaries. II. Indication of wind focusing

    NASA Astrophysics Data System (ADS)

    Shagatova, N.; Skopal, A.; Cariková, Z.

    2016-04-01

    Context. The wind mass transfer from a giant to its white dwarf companion in symbiotic binaries is not well understood. For example, the efficiency of wind mass transfer of the canonical Bondi-Hoyle accretion mechanism is too low to power the typical luminosities of the accretors. However, recent observations and modelling indicate a considerably more efficient mass transfer in symbiotic binaries. Aims: We determine the velocity profile of the wind from the giant at the near-orbital-plane region of eclipsing S-type symbiotic binaries EG And and SY Mus, and derive the corresponding spherical equivalent of the mass-loss rate. With this approach, we indicate the high mass transfer ratio. Methods: We achieved this aim by modelling the observed column densities taking into account ionization of the wind of the giant, whose velocity profile is derived using the inversion of Abel's integral operator for the hydrogen column density function. Results: Our analysis revealed the spherical equivalent of the mass-loss rate from the giant to be a few times 10-6 M⊙ yr-1, which is a factor of ≳10 higher than rates determined by methods that do not depend on the line of sight. This discrepancy rules out the usual assumption that the wind is spherically symmetric. As our values were derived from near-orbital-plane column densities, these values can be a result of focusing the wind from the giant towards the orbital plane. Conclusions: Our findings suggests that the wind from giants in S-type symbiotic stars is not spherically symmetric, since it is enhanced at the orbital plane and, thus, is accreted more effectively onto the hot component.

  15. Structures of Fluoranthene Reagent Anions Used in Electron Transfer Dissociation and Proton Transfer Reaction Tandem Mass Spectrometry.

    PubMed

    Martens, Jonathan; Berden, Giel; Oomens, Jos

    2016-06-21

    Ion/ion reactions have in recent years seen widespread use in ion activation methods such as electron transfer dissociation (ETD) tandem mass spectrometry (MS/MS) as well as in charge manipulation of highly charged peptides/proteins and their fragments by proton transfer reaction (PTR). These techniques have, in combination, enabled top-down proteomics on limited-resolution benchtop mass spectrometry platforms such as quadrupole ion traps. Anions generated by chemical ionization of fluoranthene are often used for both ETD and PTR reactions; the radical anion of fluoranthene (m/z 202) for ETD and the closed-shell anion resulting from H atom attachment to the radical anion (m/z 203) for PTR. Here we use infrared ion spectroscopy in combination with density functional theory calculations to identify the structures of these reagent anions. We establish that the m/z 203 PTR reagent anion possesses a structure that deviates from what has been suggested previously and provides some insight into the reaction mechanism involved in PTR. PMID:27228406

  16. Characterization of gas-liquid mass transfer phenomena in microtiter plates.

    PubMed

    Hermann, Robert; Lehmann, Mathias; Büchs, Jochen

    2003-01-20

    Gas-liquid mass transfer properties of shaken 96-well microtiter plates were characterized using a recently described method. The maximum oxygen transfer capacity (OTR(max)), the specific mass transfer area (a), and the mass transfer coefficient (k(L)) in a single well were determined at different shaking intensities (different shaking frequencies and shaking diameters at constant filling volume) and different filling volumes by means of sulfite oxidation as a chemical model system. The shape (round and square cross-sections) and the size (up to 2 mL maximum filling volume) of a microtiter plate well were also considered as influencing parameters. To get an indication of the hydrodynamic behavior of the liquid phase in a well, images were taken during shaking and the liquid height derived as a characteristic parameter. The investigations revealed that the OTR(max) is predominantly dependent on the specific mass transfer area (a) for the considered conditions in round-shaped wells. The mass transfer coefficient (k(L)) in round-shaped wells remains at a nearly constant value of about 0.2 m/h for all shaking intensities, thus within the range reported in the literature for surface-aerated bioreactors. The OTR(max) in round-shaped wells is strongly influenced by the interfacial tension, determined by the surface tension of the medium used and the surface properties of the well material. Up to a specific shaking intensity the liquid surface in the wells remains horizontal and no liquid movement can be observed. This critical shaking intensity must be exceeded to overcome the surface tension and, thus, to increase the liquid height and enlarge the specific mass transfer area. This behavior is solely specific to microtiter plates and has not yet been observed for larger shaking bioreactors such as shaking flasks. In square-shaped microtiter plate wells the corners act as baffles and cause a significant increase of OTR(max), a, and k(L). An OTR(max) of up to 0.15 mol

  17. Combustion of a Methane-Air Mixture in a Slot Burner with an Inert Insert in Mass Transfer to the Environment

    NASA Astrophysics Data System (ADS)

    Krainov, A. Yu.; Moiseeva, K. M.

    2016-03-01

    A problem on combustion of a methane-air mixture in a slot burner with an internal insert in mass transfer from the burner's exterior wall to the environment has been solved. A mathematical formulation of the problem takes account of the dependence of the diffusion, thermal-conductivity, and heat-transfer coefficients on temperature, and also of the heat removal from the gas to the environment by convective and radiant heat transfer. A numerical investigation has been carried out in a one-dimensional mathematical formulation of the problem in dimensional variables. The boundary of existence of a stable high-temperature regime of combustion of the methane-air mixture has been determined as a function of the rate of feed of the gas, the environmental temperature, and the width of the flow area of the burner.

  18. Diffuse supernova neutrinos: oscillation effects, stellar cooling and progenitor mass dependence

    SciTech Connect

    Lunardini, Cecilia; Tamborra, Irene E-mail: tamborra@mpp.mpg.de

    2012-07-01

    We estimate the diffuse supernova neutrino background (DSNB) using the recent progenitor-dependent, long-term supernova simulations from the Basel group and including neutrino oscillations at several post-bounce times. Assuming multi-angle matter suppression of collective effects during the accretion phase, we find that oscillation effects are dominated by the matter-driven MSW resonances, while neutrino-neutrino collective effects contribute at the 5–10% level. The impact of the neutrino mass hierarchy, of the time-dependent neutrino spectra and of the diverse progenitor star population is 10% or less, small compared to the uncertainty of at least 25% of the normalization of the supernova rate. Therefore, assuming that the sign of the neutrino mass hierarchy will be determined within the next decade, the future detection of the DSNB will deliver approximate information on the MSW-oscillated neutrino spectra. With a reliable model for neutrino emission, its detection will be a powerful instrument to provide complementary information on the star formation rate and for learning about stellar physics.

  19. Mass fractionation of noble gases in diffusion-limited hydrodynamic hydrogen escape.

    PubMed

    Zahnle, K; Kasting, J F; Pollack, J B

    1990-01-01

    Mass fractionation by hydrodynamic hydrogen escape is a promising mechanism for explaining the observed elemental and isotopic abundance patterns in terrestrial planet atmospheres. Previous work has considered only pure hydrogen winds. Here, the theory of mass fractionation by hydrogen escape is extended to atmospheres in which hydrogen is not the only major constituent. Analytical solutions are derived for cases in which all relevant atmospheric constituents escape; both analytical and numerical solutions are obtained for cases in which important heavy constituents are retained. In either case the fractionation patterns that result can differ significantly from those produced by pure hydrogen winds. Three applications of the theory are discussed: (1) The observed fractionation of terrestrial atmospheric neon with respect to mantle neon can be explained as a by-product of diffusion-limited hydrogen escape from a steam atmosphere toward the end of accretion. (2) The anomalously high Martian (SNC) 38Ar/36Ar ratio is attributed to hydrodynamic fractionation by a vigorously escaping, nearly pure hydrogen wind. (3) It is possible that the present high Martian D/H ratio was established during the same hydrodynamic escape phase that fractionated argon, but the predicted degree of D/H enrichment is sensitive to other, less well constrained parameters. PMID:11538474

  20. Ultra-diffuse Galaxies in Clusters and the Field: Masses and Stellar Populations

    NASA Astrophysics Data System (ADS)

    Romanowsky, Aaron; Laine, Seppo; Krick, Jessica; van Dokkum, Pieter; Villaume, Alexa; Brodie, Jean

    2016-08-01

    Ultra-diffuse galaxies (UDGs) were recognized only last year as a novel class of galaxies, with luminosities like dwarfs but sizes like giants. Although some UDGs appear to be just unusually extended dwarfs, others show evidence of being very different and unexpected: their dark matter halos are overmassive by factors of ~10, with one UDG even being arguably a 'failed Milky Way.' These exotic galaxies might be a byproduct of environmental processes within galaxy clusters, but UDGs have also now been found in the field. It is crucial for understanding their origins to test if UDGs have the same properties in cluster and field environments. Here we propose studying the stellar populations (ages and metallicities) of seven UDGs using Spitzer/IRAC 3.6- and 4.5-micron imaging combined with optical photometry, along with mass estimation of three of the UDGs using HST/ACS imaging to provide globular cluster number counts and colors (proxies for halo mass). This ultra low surface brightness photometry in the near infrared, on an important new class of galaxies, could become a legacy result from the Spitzer mission.