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Sample records for diversification second-order properties

  1. Properties of second-order geometrical aberrations

    NASA Astrophysics Data System (ADS)

    Grammatin, A. P.

    1994-08-01

    This paper analyzes the properties of second-order aberrations that arise in centered optical systems that contain an aspherical surface whose sagittal equation contains a term proportional to the cube of the distance from a surface point to the optical axis. It is shown that the second-order spherical aberration decreases from the center of the field to its edge. No astigmatism appears in wide, oblique beams in the central part of the field. Coma increases linearly from zero at the center of the field to a value equal to the spherical aberration, and then remains constant over the field. A proof is given of the possibility of correcting the image curvature by using an aspherical surface of the type described above.

  2. Electron-transfer photochromism to switch bulk second-order nonlinear optical properties with high contrast.

    PubMed

    Li, Pei-Xin; Wang, Ming-Sheng; Zhang, Ming-Jian; Lin, Chen-Sheng; Cai, Li-Zhen; Guo, Sheng-Ping; Guo, Guo-Cong

    2014-10-20

    The first bulk electron-transfer photochromic compound with intrinsic second-order nonlinear optical (NLO) photoswitching properties has been synthesized. This system employs an electron-transfer photoactive asymmetric viologen ligand coordinated to a zinc(II) center. PMID:25195919

  3. Theoretical investigation on second-order nonlinear optical properties of (dicyanomethylene)-pyran derivatives

    NASA Astrophysics Data System (ADS)

    Liu, Yongjun; Liu, Ying; Zhang, Dongju; Hu, Haiquan; Liu, Chengbu

    2001-08-01

    On the basis of the ZINDO program, we have designed a program to calculate the second-order nonlinear polarizabilities βijk, β0 and βμ according to the sum-over-states (SOS) expression. A series of new 4-(dicyanomethylene)-2-methyl-6-( p-dithylamino-styryl)-4 H-pyran (DCM) derivatives were designed and their electron spectra and nonlinear optical properties were studied. It is proposed that these compounds possess two important excited states close to each other in energy, both contributing to hyperpolarizability in an additive fashion; 4-(dicyanomethylene)-2,6-bis-( p-donor-styryl)-4 H-pyran derivatives are more nonlinear than 4-(dicyanomethylene)-2,6-bis-( p-donor-phenyl)-azo-4 H-pyran derivatives. The high nonlinearities, good thermal stability and high transparency make them attractive candidates for second-order nonlinear applications such as electro-optic modulators and frequency doublers.

  4. Second order finite volume scheme for Maxwell's equations with discontinuous electromagnetic properties on unstructured meshes

    SciTech Connect

    Ismagilov, Timur Z.

    2015-02-01

    This paper presents a second order finite volume scheme for numerical solution of Maxwell's equations with discontinuous dielectric permittivity and magnetic permeability on unstructured meshes. The scheme is based on Godunov scheme and employs approaches of Van Leer and Lax–Wendroff to increase the order of approximation. To keep the second order of approximation near dielectric permittivity and magnetic permeability discontinuities a novel technique for gradient calculation and limitation is applied near discontinuities. Results of test computations for problems with linear and curvilinear discontinuities confirm second order of approximation. The scheme was applied to modelling propagation of electromagnetic waves inside photonic crystal waveguides with a bend.

  5. Analytic calculation of second-order electric response properties with the normalized elimination of the small component (NESC) method

    NASA Astrophysics Data System (ADS)

    Zou, Wenli; Filatov, Michael; Cremer, Dieter

    2012-08-01

    Analytic second derivatives of the relativistic energy for the calculation of electric response properties are derived utilizing the normalized elimination of the small component (NESC) method. Explicit formulas are given for electric static dipole polarizabilities and infrared intensities by starting at the NESC representation of electric dipole moments. The analytic derivatives are implemented in an existing NESC program and applied to calculate dipole moments, polarizabilities, and the infrared spectra of gold- and mercury-containing molecules as well as some actinide molecules. Comparison with experiment reveals the accuracy of NESC second order electric response properties.

  6. Polymer Physics and Structure/property Relationships of Thermally Stable Polyarylene Ethers for Second Order Nonlinear Optics.

    NASA Astrophysics Data System (ADS)

    Fu, Chu-Yun Stacey

    1995-01-01

    Over the past decade, researchers have been actively involved in developing nonlinear optical polymers for device applications. One major obstacle with the current polymers is that the chromophores doped or covalently bonded to the backbones disorient following electric field poling and thus the nonlinear optical signal decreases with time. The optical stability must thus be optimized before useful devices made from these materials will be feasible. Although several synthetic approaches have been employed to optimize polymer structures and glass transition temperatures in order to maximize stability, the studies of the polymer physics of these high temperature stable polymers are still limited. It is critical to understand the polymer physics governing the relaxation behavior of these nonlinear optical polymers so that one can better predict the long-term thermal and temporal stability and changes in properties throughout the anticipated service life when utilizing them for device applications. The goal of this research is to investigate the structure/property relationships that influence the relaxation behavior of a class of thermally stable polymers called polyarylene ethers (synthesized by Dr. Duane B. Priddy, Jr., Mr. Greg D. Lyle, and Dr. James E. McGrath at Virginia Polytechnic Institute and State University). Specific issues such as the effects of polymer backbone structures, dopant/polymer interactions, chromophore functionalization, and chromophore concentration on the dopant orientational dynamics and intermolecular cooperativity in these polymer systems were studied. Attempts to correlate the molecular level parameters including the molecular weight and polydispersities to the observed physical properties were made. The effect of physical aging during poling on the chromophore orientational dynamics was also examined. Second harmonic generation, a second order nonlinear optical effect, and dielectric relaxation are the two techniques employed for these

  7. Tuning the push-pull configuration for efficient second-order nonlinear optical properties in some chalcone derivatives.

    PubMed

    Muhammad, Shabbir; Al-Sehemi, Abdullah G; Irfan, Ahmad; Chaudhry, Aijaz R

    2016-07-01

    Using the density functional theory methods, we effectively tune the second-order nonlinear optical (NLO) properties in some chalcone derivatives. Various unique push-pull configurations are used to efficiently enhance the intramolecular charge transfer process over the designed derivatives, which result in significantly larger amplitudes of the first hyperpolarizability as compared to their parent molecule. The ground state molecular geometries have been optimized using B3LYP/6-311G** level of theory. A variety of methods including B3LYP, CAM-B3LYP, PBE0, M06, BHandHLYP and MP2 are tested with 6-311G** basis set to calculate the first hyperpolarizability of parent system 1. The results of M06 are found closer to highly correlated MP2 method, which has been selected to calculate static and frequency dependent first hyperpolarizability amplitudes of all selected systems. At M06/6-311G** level of theory, the permanent electronic dipole moment (μtot), polarizability (α0) and static first hyperpolarizability (βtot) amplitudes for parent system 1 are found to be 5.139 Debye, 274a. u. and 24.22×10(-30)esu, respectively. These amplitudes have been significantly enhanced in designed derivatives 2 and 3. More importantly, the (βtot) amplitudes of systems 2 and 3 mount to 75.78×10(-30) and 128.51×10(-30)esu, respectively, which are about 3 times and 5 times larger than that of their parent system 1. Additionally, we have extended the structure-NLO property relationship to several newly synthesized chalcone derivatives. Interestingly, the amplitudes of dynamic frequency dependent hyperpolarizability μβω (SHG) are also significantly larger having values of 366.72×10(-48), 856.32×10(-48) and 1913.46×10(-48)esu for systems 1-3, respectively, at 1400nm of incident laser wavelength. The dispersion behavior over a wide range of change in wavelength has also been studied adopting a range of wavelength from 1907 to 544nm. Thus, the present work realizes the potential of

  8. Second order Standard Model

    NASA Astrophysics Data System (ADS)

    Espin, Johnny; Krasnov, Kirill

    2015-06-01

    It is known, though not commonly, that one can describe fermions using a second order in derivatives Lagrangian instead of the first order Dirac one. In this description the propagator is scalar, and the complexity is shifted to the vertex, which contains a derivative operator. In this paper we rewrite the Lagrangian of the fermionic sector of the Standard Model in such second order form. The new Lagrangian is extremely compact, and is obtained from the usual first order Lagrangian by integrating out all primed (or dotted) 2-component spinors. It thus contains just half of the 2-component spinors that appear in the usual Lagrangian, which suggests a new perspective on unification. We sketch a natural in this framework SU (2) × SU (4) ⊂ SO (9) unified theory.

  9. Femtosecond single-beam direct laser poling of stable and efficient second-order nonlinear optical properties in glass

    NASA Astrophysics Data System (ADS)

    Papon, G.; Marquestaut, N.; Petit, Y.; Royon, A.; Dussauze, M.; Rodriguez, V.; Cardinal, T.; Canioni, L.

    2014-03-01

    We depict a new approach for the localized creation in three dimensions (3D) of a highly demanded nonlinear optical function for integrated optics, namely second harmonic generation. We report on the nonlinear optical characteristics induced by single-beam femtosecond direct laser writing in a tailored silver-containing phosphate glass. The original spatial distribution of the nonlinear pattern, composed of four lines after one single laser writing translation, is observed and modeled with success, demonstrating the electric field induced origin of the second harmonic generation. These efficient second-order nonlinear structures (with χeff(2) ˜ 0.6 pm V-1) with sub-micron scale are impressively stable under thermal constraint up to glass transition temperature, which makes them very promising for new photonic applications, especially when 3D nonlinear architectures are desired.

  10. Femtosecond single-beam direct laser poling of stable and efficient second-order nonlinear optical properties in glass

    SciTech Connect

    Papon, G.; Marquestaut, N.; Royon, A.; Canioni, L.; Petit, Y.; Dussauze, M.; Rodriguez, V.; Cardinal, T.

    2014-03-21

    We depict a new approach for the localized creation in three dimensions (3D) of a highly demanded nonlinear optical function for integrated optics, namely second harmonic generation. We report on the nonlinear optical characteristics induced by single-beam femtosecond direct laser writing in a tailored silver-containing phosphate glass. The original spatial distribution of the nonlinear pattern, composed of four lines after one single laser writing translation, is observed and modeled with success, demonstrating the electric field induced origin of the second harmonic generation. These efficient second-order nonlinear structures (with χ{sub eff}{sup (2)} ∼ 0.6 pm V{sup −1}) with sub-micron scale are impressively stable under thermal constraint up to glass transition temperature, which makes them very promising for new photonic applications, especially when 3D nonlinear architectures are desired.

  11. Fluorescence properties of flavonoid compounds. Quantification in paprika samples using spectrofluorimetry coupled to second order chemometric tools.

    PubMed

    Monago-Maraña, Olga; Durán-Merás, Isabel; Galeano-Díaz, Teresa; Muñoz de la Peña, Arsenio

    2016-04-01

    The influence of pH on the fluorescence of flavonoid compounds was investigated and the highest fluorescence emission was obtained in basic medium. Selected conditions to improve this signal were: pH 9.5, 0.14 M Britton Robinson buffer and methanol between 5% and 10%. The excitation-emission fluorescence matrices of a set of 36 samples of Spanish paprika were analyzed by means of parallel factor analysis (PARAFAC). Thus, the profiles of possible fluorescence components (PARAFAC loadings) were obtained. One of these profiles was identified by matching PARAFAC scores with LC analysis on the same samples. Two clusters of samples were obtained when score values were plotted against each other. Spectrofluorimetry coupled to second order multivariate calibration methods, as unfolded-partial least squares with residual bilinearization (U-PLS/RBL) and multidimensional-partial least-squares with residual bilinearization (N-PLS/RBL), was investigated to quantify quercetin and kaempferol in those samples. Good results were obtained for quercetin by this approach. PMID:26593589

  12. The electronic structure and second-order nonlinear optical properties of donor-acceptor acetylenes - A detailed investigation of structure-property relationships

    NASA Technical Reports Server (NTRS)

    Stiegman, A. E.; Graham, Eva; Khundkar, Lutfur R.; Perry, Joseph W.; Cheng, L.-T.; Perry, Kelly J.

    1991-01-01

    A series of donor-acceptor acetylene compounds was synthesized in which systematic changes in both the conjugation length and the donor-acceptor strength were made. The effect of these structural changes on the spectroscopic and electronic properties of the molecules and, ultimately, on the measured second-order molecular hyperpolarizabilities (beta) was investigated. It was found that increases in the donor-acceptor strength resulted in increases in the magnitude of beta. For this class of molecules, the increase is dominated by the energy of the intramolecular charge-transfer transition, while factors such as the ground to excited-state dipole moment change and the transition-moment integral are much less important. Increasing the conjugation length from one to two acetylene linkers did not result in an increase in the value of beta; however, beta increased sharply in going from two acetylenes to three. This increase is attributed to the superposition of several nearly isoenergetic excited states.

  13. Investigation of the second-order nonlinear optical properties of Cs{sub 2}TeMo{sub 3}O{sub 12} single crystal

    SciTech Connect

    Feng, Xiaoxiao; Zhang, Junjie; Gao, Zeliang; Zhang, Shaojun; Sun, Youxuan; Tao, Xutang

    2014-02-24

    The complete set of second-order nonlinear optical (NLO) coefficients of Cs{sub 2}TeMo{sub 3}O{sub 12} single crystals were obtained using the Maker Fringe techniques. The NLO coefficients d{sub 32} and d{sub 33} were measured to be on the order of 6.8 and 6.5 pm/V, respectively. Irradiated by 1064 nm laser, the crystal is phase-matchable, and its effective nonlinear coefficient is 4.6 pm/V for type I phase matching at θ = 42.7°. The relationship between the second-order nonlinear properties and the crystal structure is also discussed. Considering its wide transmission range, phase matching, and large effective NLO coefficient, Cs{sub 2}TeMo{sub 3}O{sub 12} is a good candidate for IR NLO application.

  14. Second-Order Nonlinear Optical Properties of a Dithienylethene-Indolinooxazolidine Hybrid: A Joint Experimental and Theoretical Investigation.

    PubMed

    Bondu, Flavie; Quertinmont, Jean; Rodriguez, Vincent; Pozzo, Jean-Luc; Plaquet, Aurélie; Champagne, Benoît; Castet, Frédéric

    2015-12-14

    The nonlinear optical (NLO) properties of a double photochrome molecular switch are reported for the first time by considering the four trans forms of a dithienylethene-indolinooxazolidine hybrid. The four forms are characterized by means of hyper-Rayleigh scattering (HRS) experiments and quantum chemical calculations. Experimental measurements provide evidence that the pH- and light-triggered transformations between the different forms of the hybrid are accompanied by large variations of the first hyperpolarizability, which makes this compound an effective multistate NLO switch. Quantum chemical calculations conducted at the time-dependent Hartree-Fock and time-dependent DFT levels agree with the experimental data and allow a complete rationalization of the NLO responses of the different forms. The HRS signal of the forms with an open indolinooxazolidine moiety are more than one order of magnitude larger than that measured for the other forms, whereas the open/closed status of the dithienylethene subunit barely influences the dynamic NLO properties. However, extrapolation of the NLO responses to the static limit leads to univocally distinguishable intrinsic responses for three of the various forms. This hybrid system thus acts as a highly efficient multistate NLO switch for eventual exploitation in optical memory systems with multiple storage and nondestructive readout capacity. PMID:26560091

  15. Magnetic, thermodynamic and transport properties at the first and second order magnetic phase transitions in Dy5Si3 compound

    NASA Astrophysics Data System (ADS)

    Falkowski, M.; Kowalczyk, A.; Toliński, T.

    2013-04-01

    We present extended studies including the dc and ac magnetic susceptibility, magnetization, specific heat, electrical resistivity and magnetoresistivity measurements for the Dy5Si3 compound with the hexagonal Mn5Si3-type structure. The results indicate that this compound orders antiferromagnetically below TN=137 K. The magnetic properties of Dy5Si3 are mainly governed by the presence of the magnetic moments of Dy3+ ions. In the paramagnetic range, the magnetic susceptibility follows the Curie-Weiss law with μeff=10.57 μB/Dy, which is very close to the theoretical value of 10.6 μB. From the magnetometric, specific heat and transport data it has been found that below 50 K this compound reveals a non-collinear magnetic order, associated with a phase transition, probably of the first order type. On the basis of the thermodynamic approach, we report the magnetocaloric properties in the whole temperature range but concentrate mainly on the region around 50 K. The magnetocaloric effect was calculated in terms of the isothermal magnetic entropy change ΔSM as well as the adiabatic temperature change ΔTad using the specific heat data. In spite of the only moderate ΔSM values a significant relative cooling power has been observed.

  16. Second-order nonlinear optical properties of dithienophenazine and TTF derivatives: A butterfly effect of dimalononitrile substitutions.

    PubMed

    Muhammad, Shabbir

    2015-06-01

    Using density functional theory (DFT) methods, the nonlinear optical (NLO) properties have been calculated with strong donor-π-conjugation-acceptor configurations. The static first hyperpolarizability (β0) and dynamic (frequency dependent) electric field induced second harmonic generation (EFISHG) first hyperpolarizability (μβ) are calculated for all designed systems. Our DFT calculations show dithienophenazine merged TTF (2) holds larger β0 amplitudes (β0=21.04×10(3)a.u.) as compared to its corresponding compounds of TTF merged-difurophenazine (1), dicyclopentaphenazine (3) and dipyrrolophenazine (4) derivatives having β0 amplitudes of 16.25×10(3), 12.69×10(3), and 18.38×10(3)a.u., respectively. Furthermore, substitution of dimalononitrile [C(CN)2]2 groups at acceptor end of these compounds results in new derivatives 1a-4a, respectively. Interestingly, a butterfly effect on first hyperpolarizability of all systems 1a-4a has been spotted, which not only results in their robustly larger β0 amplitudes but also changes the increasing order of β0 amplitudes from systems 3<1<4<2 to 1a<2a<3a<4a at both PBE0/6-31G* and CAM-B3LYP/6-31+G* levels of theory. For example, the increase in β0 amplitudes of systems 1a, 2a, 3a and 4a are 3, 3, 5, and 19 times as compared with their corresponding non dimalononitrile derivatives at PBE0/6-31G* level of theory, respectively. Remarkably, unlike the static first hyperpolarizability, the dynamic EFISHG hyperpolarizability (μβω) has the largest value for system 4a with its amplitudes of 1378.59×10(-46) and 1349.40×10(-46)esu, at PBE0/6-31G* and CAM-B3LYP/6-31+G* levels of theory, respectively. TD-DFT calculations have been performed to trace the origin of first hyperpolarizability. It has been found that the lower transition energy and higher oscillator strengths cause robustly large amplitudes especially in systems 3a and 4a, which consequently stems in strong donor-π-conjugation-acceptor configuration of these

  17. Synthesis, crystal structure and second-order nonlinear optical property of a novel pentanary selenide (K3I)[InB12(InSe4)3].

    PubMed

    Guo, Sheng-Ping; Chi, Yang; Liu, Bin-Wen; Guo, Guo-Cong

    2016-06-21

    A novel pentanary selenide (K3I)[InB12(InSe4)3] was obtained via a high-temperature solid-state method. It crystallizes in the hexagonal space group P6322 which features an InSe4 tetrahedron consolidated B12 icosahedron and 1-D chain constructed by InSe6 octahedron and B12Se12 cluster alternatively connected along the c-axis. Second-order nonlinear optical property measurement shows that it is second harmonic generation-active. Theory calculation indicates that it is an indirect semiconductor with the energy gap of 1.15 eV. PMID:27265446

  18. Ab initio molecular dynamics of liquid water using embedded-fragment second-order many-body perturbation theory towards its accurate property prediction.

    PubMed

    Willow, Soohaeng Yoo; Salim, Michael A; Kim, Kwang S; Hirata, So

    2015-01-01

    A direct, simultaneous calculation of properties of a liquid using an ab initio electron-correlated theory has long been unthinkable. Here we present structural, dynamical, and response properties of liquid water calculated by ab initio molecular dynamics using the embedded-fragment spin-component-scaled second-order many-body perturbation method with the aug-cc-pVDZ basis set. This level of theory is chosen as it accurately and inexpensively reproduces the water dimer potential energy surface from the coupled-cluster singles, doubles, and noniterative triples with the aug-cc-pVQZ basis set, which is nearly exact. The calculated radial distribution function, self-diffusion coefficient, coordinate number, and dipole moment, as well as the infrared and Raman spectra are in excellent agreement with experimental results. The shapes and widths of the OH stretching bands in the infrared and Raman spectra and their isotropic-anisotropic Raman noncoincidence, which reflect the diverse local hydrogen-bond environment, are also reproduced computationally. The simulation also reveals intriguing dynamic features of the environment, which are difficult to probe experimentally, such as a surprisingly large fluctuation in the coordination number and the detailed mechanism by which the hydrogen donating water molecules move across the first and second shells, thereby causing this fluctuation. PMID:26400690

  19. Ab initio molecular dynamics of liquid water using embedded-fragment second-order many-body perturbation theory towards its accurate property prediction

    PubMed Central

    Willow, Soohaeng Yoo; Salim, Michael A.; Kim, Kwang S.; Hirata, So

    2015-01-01

    A direct, simultaneous calculation of properties of a liquid using an ab initio electron-correlated theory has long been unthinkable. Here we present structural, dynamical, and response properties of liquid water calculated by ab initio molecular dynamics using the embedded-fragment spin-component-scaled second-order many-body perturbation method with the aug-cc-pVDZ basis set. This level of theory is chosen as it accurately and inexpensively reproduces the water dimer potential energy surface from the coupled-cluster singles, doubles, and noniterative triples with the aug-cc-pVQZ basis set, which is nearly exact. The calculated radial distribution function, self-diffusion coefficient, coordinate number, and dipole moment, as well as the infrared and Raman spectra are in excellent agreement with experimental results. The shapes and widths of the OH stretching bands in the infrared and Raman spectra and their isotropic-anisotropic Raman noncoincidence, which reflect the diverse local hydrogen-bond environment, are also reproduced computationally. The simulation also reveals intriguing dynamic features of the environment, which are difficult to probe experimentally, such as a surprisingly large fluctuation in the coordination number and the detailed mechanism by which the hydrogen donating water molecules move across the first and second shells, thereby causing this fluctuation. PMID:26400690

  20. Computational study of the vibrational spectroscopic studies, natural bond orbital, frontier molecular orbital and second-order non-linear optical properties of acetophenone thiosemicarbazone molecule

    NASA Astrophysics Data System (ADS)

    Li, Xiao-Hong; Mei, Zheng; Zhang, Xian-Zhou

    2014-01-01

    The vibrational frequencies of acetophenone thiosemicarbazone in the ground state have been calculated using density functional method (B3LYP) with 6-31G(d), 6-31G(d,p) and 6-311++G(d,p) basis sets. The analysis of natural bond orbital was also performed. The IR spectra were obtained and interpreted by means of potential energies distributions (PEDs) using MOLVIB program. In addition, the results show that there exist Nsbnd H…N and Nsbnd H…S hydrogen bonds in the title compound, which play a major role in stabilizing the molecule and are confirmed by the natural bond orbital analysis. The predicted NLO properties show that the title compound is a good candidate as second-order NLO material. In addition, the frontier molecular orbitals were analyzed and the crystal structure obtained by molecular mechanics belongs to the Pbca space group, with lattice parameters Z = 8, a = 16.0735 Å, b = 7.1719 Å, c = 7.8725 Å, ρ = 0.808 g/cm3.

  1. Computational study of the vibrational spectroscopic studies, natural bond orbital, frontier molecular orbital and second-order non-linear optical properties of acetophenone thiosemicarbazone molecule.

    PubMed

    Li, Xiao-Hong; Mei, Zheng; Zhang, Xian-Zhou

    2014-01-24

    The vibrational frequencies of acetophenone thiosemicarbazone in the ground state have been calculated using density functional method (B3LYP) with 6-31G(d), 6-31G(d,p) and 6-311++G(d,p) basis sets. The analysis of natural bond orbital was also performed. The IR spectra were obtained and interpreted by means of potential energies distributions (PEDs) using MOLVIB program. In addition, the results show that there exist N-H…N and N-H…S hydrogen bonds in the title compound, which play a major role in stabilizing the molecule and are confirmed by the natural bond orbital analysis. The predicted NLO properties show that the title compound is a good candidate as second-order NLO material. In addition, the frontier molecular orbitals were analyzed and the crystal structure obtained by molecular mechanics belongs to the Pbca space group, with lattice parameters Z=8, a=16.0735 Å, b=7.1719 Å, c=7.8725 Å, ρ=0.808 g/cm(3). PMID:24084483

  2. Second-Order Footsteps Illusions

    PubMed Central

    Anstis, Stuart

    2015-01-01

    In the “footsteps illusion”, light and dark squares travel at constant speed across black and white stripes. The squares appear to move faster and slower as their contrast against the stripes varies. We now demonstrate some second-order footsteps illusions, in which all edges are defined by colors or textures—even though luminance-based neural motion detectors are blind to such edges. PMID:27551366

  3. Second-Order Footsteps Illusions.

    PubMed

    Kitaoka, Akiyoshi; Anstis, Stuart

    2015-12-01

    In the "footsteps illusion", light and dark squares travel at constant speed across black and white stripes. The squares appear to move faster and slower as their contrast against the stripes varies. We now demonstrate some second-order footsteps illusions, in which all edges are defined by colors or textures-even though luminance-based neural motion detectors are blind to such edges. PMID:27551366

  4. Second-order coherence of supercontinuum light.

    PubMed

    Genty, Goëry; Surakka, Minna; Turunen, Jari; Friberg, Ari T

    2010-09-15

    We analyze the coherence properties of supercontinuum generated in photonic crystal fibers by applying the second-order coherence theory of nonstationary light. Using an ensemble of simulated realizations, we construct two-frequency cross-spectral density and two-time mutual coherence functions. This allows us to introduce measures of temporal and spectral coherence. We show that, in the long-pulse regime, supercontinuum light can be decomposed into a sum of coherent and quasi-stationary contributions. Our approach and findings are also applicable in the short-pulse regime. PMID:20847777

  5. Theoretical exploration to second-order nonlinear optical properties of new hybrid complexes via coordination interaction between (metallo)porphyrin and [MSiW11O39](3-) (M=Nb(V) or V(V)) polyoxometalates.

    PubMed

    Zhang, Ting; Ma, Nana; Yan, Likai; Wen, Shizheng; Ma, Tengying; Su, Zhongmin

    2013-11-01

    The second-order nonlinear optical (NLO) properties of hybrid complexes via coordination interaction between porphyrin and Keggin-type polyoxometalates (POMs) α-[MSiW11O39](3-) (M=Nb(V) or V(V)) are investigated by time-dependent density functional theory (TDDFT). The calculated results show that this kind of organic-inorganic hybrid complexes possesses remarkably large molecular second-order NLO polarizability, especially for the ZnP3P-C≡C-4-Py-[VSiW11O39](3-) (complex 4), which has a computed β0 value of 261,410 a.u. and might be an excellent second-order NLO material. The effects of substituted metal atom (M), metalloporphyrin, and π-conjugation on NLO response are analyzed, the substituted metal atom (M) with a large electronegativity, the metalloporphyrin, and the lengthening of π-conjugation are helpful in enhancing the optical nonlinearity of these systems, which reveal the general rules to design the complexes with large optical nonlinearities. Furthermore, the solvent effect largely affects the first-order hyperpolarizability of the complex, it implies that the second-order polarizabilities increased with the increase of the solvent in polarity. PMID:24149319

  6. Second order tensor finite element

    NASA Technical Reports Server (NTRS)

    Oden, J. Tinsley; Fly, J.; Berry, C.; Tworzydlo, W.; Vadaketh, S.; Bass, J.

    1990-01-01

    The results of a research and software development effort are presented for the finite element modeling of the static and dynamic behavior of anisotropic materials, with emphasis on single crystal alloys. Various versions of two dimensional and three dimensional hybrid finite elements were implemented and compared with displacement-based elements. Both static and dynamic cases are considered. The hybrid elements developed in the project were incorporated into the SPAR finite element code. In an extension of the first phase of the project, optimization of experimental tests for anisotropic materials was addressed. In particular, the problem of calculating material properties from tensile tests and of calculating stresses from strain measurements were considered. For both cases, numerical procedures and software for the optimization of strain gauge and material axes orientation were developed.

  7. Visualization of second order tensor fields and matrix data

    NASA Technical Reports Server (NTRS)

    Delmarcelle, Thierry; Hesselink, Lambertus

    1992-01-01

    We present a study of the visualization of 3-D second order tensor fields and matrix data. The general problem of visualizing unsymmetric real or complex Hermitian second order tensor fields can be reduced to the simultaneous visualization of a real and symmetric second order tensor field and a real vector field. As opposed to the discrete iconic techniques commonly used in multivariate data visualization, the emphasis is on exploiting the mathematical properties of tensor fields in order to facilitate their visualization and to produce a continuous representation of the data. We focus on interactively sensing and exploring real and symmetric second order tensor data by generalizing the vector notion of streamline to the tensor concept of hyperstreamline. We stress the importance of a structural analysis of the data field analogous to the techniques of vector field topology extraction in order to obtain a unique and objective representation of second order tensor fields.

  8. Source of second order chromaticity in RHIC

    SciTech Connect

    Luo, Y.; Gu, X.; Fischer, W.; Trbojevic, D.

    2011-01-01

    In this note we will answer the following questions: (1) what is the source of second order chromaticities in RHIC? (2) what is the dependence of second order chromaticity on the on-momentum {beta}-beat? (3) what is the dependence of second order chromaticity on {beta}* at IP6 and IP8? To answer these questions, we use the perturbation theory to numerically calculate the contributions of each quadrupole and sextupole to the first, second, and third order chromaticities.

  9. Binocular Combination of Second-Order Stimuli

    PubMed Central

    Zhou, Jiawei; Liu, Rong; Zhou, Yifeng; Hess, Robert F.

    2014-01-01

    Phase information is a fundamental aspect of visual stimuli. However, the nature of the binocular combination of stimuli defined by modulations in contrast, so-called second-order stimuli, is presently not clear. To address this issue, we measured binocular combination for first- (luminance modulated) and second-order (contrast modulated) stimuli using a binocular phase combination paradigm in seven normal adults. We found that the binocular perceived phase of second-order gratings depends on the interocular signal ratio as has been previously shown for their first order counterparts; the interocular signal ratios when the two eyes were balanced was close to 1 in both first- and second-order phase combinations. However, second-order combination is more linear than previously found for first-order combination. Furthermore, binocular combination of second-order stimuli was similar regardless of whether the carriers in the two eyes were correlated, anti-correlated, or uncorrelated. This suggests that, in normal adults, the binocular phase combination of second-order stimuli occurs after the monocular extracting of the second-order modulations. The sensory balance associated with this second-order combination can be obtained from binocular phase combination measurements. PMID:24404180

  10. Binocular combination of second-order stimuli.

    PubMed

    Zhou, Jiawei; Liu, Rong; Zhou, Yifeng; Hess, Robert F

    2014-01-01

    Phase information is a fundamental aspect of visual stimuli. However, the nature of the binocular combination of stimuli defined by modulations in contrast, so-called second-order stimuli, is presently not clear. To address this issue, we measured binocular combination for first- (luminance modulated) and second-order (contrast modulated) stimuli using a binocular phase combination paradigm in seven normal adults. We found that the binocular perceived phase of second-order gratings depends on the interocular signal ratio as has been previously shown for their first order counterparts; the interocular signal ratios when the two eyes were balanced was close to 1 in both first- and second-order phase combinations. However, second-order combination is more linear than previously found for first-order combination. Furthermore, binocular combination of second-order stimuli was similar regardless of whether the carriers in the two eyes were correlated, anti-correlated, or uncorrelated. This suggests that, in normal adults, the binocular phase combination of second-order stimuli occurs after the monocular extracting of the second-order modulations. The sensory balance associated with this second-order combination can be obtained from binocular phase combination measurements. PMID:24404180

  11. Assessment of long-range corrected and conventional DFT functional for the prediction of second - Order NLO properties and other molecular properties of N-(2-cyanoethyl)-N-butylaniline - A vibrational spectroscopy study

    NASA Astrophysics Data System (ADS)

    Anitha, K.; Balachandran, V.

    2015-07-01

    Vibrational spectral analysis and quantum chemical computations based on density functional theory have been performed on the N-(2-cyanoethyl)-N-butylaniline. The geometry, structural properties, intermolecular hydrogen bond, and harmonic vibrational frequencies of the title molecule have been investigated with the help of DFT (B3LYP) and LC-DFT (CAM-B3LYP) method. Molecular electrostatic potential (MEP) have been performed. The various intramolecular interactions have been exposed by natural bond orbital analysis. The distribution of atomic charges and bending of natural hybrid orbitals also reflect the presence of intramolecular hydrogen bonding. Global reactivity and local reactivity descriptors of the title molecule have been calculated. The analysis of the electron density of HOMO and LUMO gives an idea of the delocalization and low value of energy gap indicated the electron transport in the molecule and thereby NLO activity. The effect of solvent on second-order NLO properties has been studied using polarized continuum model (PCM) in the tetrahydrofuran (THF) solution. The solvent leads to a slight enhancement of the NLO responses for the studied complexes relevant to their NLO responses in gas phase. The electronic absorption spectra were investigated by the TDDFT methods. The frequency-dependent first hyperpolarizabilities of the N-(2-cyanoethyl)-N-butylaniline were also evaluated. The 1H and 13C NMR chemical shifts have been calculated by gauge-indepedent atomic orbital (GIAO) method with B3LYP/6-311++G(d, p) approach.

  12. The second-order gravitational red shift

    NASA Technical Reports Server (NTRS)

    Jaffe, J.

    1973-01-01

    The direct measurement of the nonlinear term of the gravitational field equations by using very stable clocks is discussed along with measuring the perhelion advance of a planet or satellite. These are considered measurements of the second-order gravitational red shift. The exact expression for the frequency shift of light in a gravitational field is derived. Other topics discussed include: The Doppler-cancelling technique; the second-order red shift in a spherically symmetric gravitational field; finite signal transit time; and the reality and interpretation of coordinates in the second-order red shift experiment.

  13. Nine Practices of Second Order Schools

    ERIC Educational Resources Information Center

    Brown, Bill; Tucker, Patrick; Williams, Thomas L.

    2012-01-01

    Many schools are in some stage of implementing differentiated instruction, with some already in what Carol Tomlinson describes in "The Differentiated School" as "second order change," where the entire school practices differentiation. In high-performing schools, differentiation has proved to be an effective instructional strategy; in classroom…

  14. Second-Order Conditioning in "Drosophila"

    ERIC Educational Resources Information Center

    Tabone, Christopher J.; de Belle, J. Steven

    2011-01-01

    Associative conditioning in "Drosophila melanogaster" has been well documented for several decades. However, most studies report only simple associations of conditioned stimuli (CS, e.g., odor) with unconditioned stimuli (US, e.g., electric shock) to measure learning or establish memory. Here we describe a straightforward second-order conditioning…

  15. Correction of second order chromaticity at Tevatron

    SciTech Connect

    Valishev, A.; Annala, G.; Lebedev, V.; Moore, R.S.; /Fermilab

    2007-06-01

    Correction of the second order betatron tune chromaticity is essential for operation at the working point near half integer resonance which is proposed as one of the ways to improve performance of the Tevatron. In this report the new chromaticity correction scheme with split sextupole families is described. Details of implementation and commissioning at the present working point are discussed.

  16. Solution of second order supersymmetrical intertwining relations in Minkowski plane

    NASA Astrophysics Data System (ADS)

    Ioffe, M. V.; Kolevatova, E. V.; Nishnianidze, D. N.

    2016-08-01

    Supersymmetrical (SUSY) intertwining relations are generalized to the case of quantum Hamiltonians in Minkowski space. For intertwining operators (supercharges) of second order in derivatives, the intertwined Hamiltonians correspond to completely integrable systems with the symmetry operators of fourth order in momenta. In terms of components, the intertwining relations correspond to the system of nonlinear differential equations which are solvable with the simplest—constant—ansatzes for the "metric" matrix in second order part of the supercharges. The corresponding potentials are built explicitly both for diagonalizable and nondiagonalizable form of "metric" matrices, and their properties are discussed.

  17. Textural segmentation, second-order statistics, and textural elements.

    PubMed

    Beck, J

    1983-01-01

    Beck (1972, 1973) hypothesized that textural segmentation occurs strongly on the basis of simple properties such as brightness, color, size, and the slopes of contours and lines of the elemental descriptors of a texture or textural elements. The experiment reported supports the hypothesis that specific stimulus features, rather than second-order statistics, account for textural segmentation. The results agree with Julesz (1981a,b) who has reported evidence disproving his original conjecture of the importance of second-order statistics. Julesz (1981a,b) now hypothesizes textural segmentation to be a function of local features which he called textons. Textons are features that give textural segmentation when textures have identical second-order statistics. The two hypotheses are to date in complete agreement on the stimulus features producing textural segmentation, and the experiment reported is consistent with both. PMID:6626590

  18. Second-Order Invariants and Holography

    NASA Astrophysics Data System (ADS)

    Luongo, Orlando; Bonanno, Luca; Iannone, Gerardo

    2012-12-01

    Motivated by recent works on the role of the holographic principle in cosmology, we relate a class of second-order Ricci invariants to the IR cutoff characterizing the holographic dark energy density. The choice of second-order invariants provides an invariant way to account the problem of causality for the correct cosmological cutoff, since the presence of event horizons is not an a priori assumption. We find that these models work fairly well, by fitting the observational data, through a combined cosmological test with the use of SNeIa, BAO and CMB. This class of models is also able to overcome the fine-tuning and coincidence problems. Finally, to make a comparison with other recent models, we adopt the statistical tests AIC and BIC.

  19. Calculating Second-Order Effects in MOSFET's

    NASA Technical Reports Server (NTRS)

    Benumof, Reuben; Zoutendyk, John A.; Coss, James R.

    1990-01-01

    Collection of mathematical models includes second-order effects in n-channel, enhancement-mode, metal-oxide-semiconductor field-effect transistors (MOSFET's). When dimensions of circuit elements relatively large, effects neglected safely. However, as very-large-scale integration of microelectronic circuits leads to MOSFET's shorter or narrower than 2 micrometer, effects become significant in design and operation. Such computer programs as widely-used "Simulation Program With Integrated Circuit Emphasis, Version 2" (SPICE 2) include many of these effects. In second-order models of n-channel, enhancement-mode MOSFET, first-order gate-depletion region diminished by triangular-cross-section deletions on end and augmented by circular-wedge-cross-section bulges on sides.

  20. Visualizing second order tensor fields with hyperstreamlines

    NASA Technical Reports Server (NTRS)

    Delmarcelle, Thierry; Hesselink, Lambertus

    1993-01-01

    Hyperstreamlines are a generalization to second order tensor fields of the conventional streamlines used in vector field visualization. As opposed to point icons commonly used in visualizing tensor fields, hyperstreamlines form a continuous representation of the complete tensor information along a three-dimensional path. This technique is useful in visulaizing both symmetric and unsymmetric three-dimensional tensor data. Several examples of tensor field visualization in solid materials and fluid flows are provided.

  1. Spacetime encodings. III. Second order Killing tensors

    SciTech Connect

    Brink, Jeandrew

    2010-01-15

    This paper explores the Petrov type D, stationary axisymmetric vacuum (SAV) spacetimes that were found by Carter to have separable Hamilton-Jacobi equations, and thus admit a second-order Killing tensor. The derivation of the spacetimes presented in this paper borrows from ideas about dynamical systems, and illustrates concepts that can be generalized to higher-order Killing tensors. The relationship between the components of the Killing equations and metric functions are given explicitly. The origin of the four separable coordinate systems found by Carter is explained and classified in terms of the analytic structure associated with the Killing equations. A geometric picture of what the orbital invariants may represent is built. Requiring that a SAV spacetime admits a second-order Killing tensor is very restrictive, selecting very few candidates from the group of all possible SAV spacetimes. This restriction arises due to the fact that the consistency conditions associated with the Killing equations require that the field variables obey a second-order differential equation, as opposed to a fourth-order differential equation that imposes the weaker condition that the spacetime be SAV. This paper introduces ideas that could lead to the explicit computation of more general orbital invariants in the form of higher-order Killing tensors.

  2. Second order Kerr-Newman time delay

    NASA Astrophysics Data System (ADS)

    He, G.; Lin, W.

    2016-01-01

    The explicit form for the post-Newtonian gravitational time delay of light signals propagating on the equatorial plane of a Kerr-Newman black hole is derived. Based on the null geodesic in Kerr-Newman spacetime, we adopt the iterative method to calculate the time delay. Our result reduces to the previous formulation for the Kerr black hole if we drop the contribution from the electrical charge. Our time-delay formula for the Reissner-Nordström geometry is different from the previous publication [Phys. Rev. D 69, 023002 (2004)], in which the largest second order contribution to the time delay is missing.

  3. Analysis of second-order gratings

    SciTech Connect

    Hardy, A.; Welch, D.F.; Streifer, W. )

    1989-10-01

    The authors report the results of a second-order grating analysis. The gratings are used as distributed Bragg reflectors in surface-emitting lasers, which are currently being fabricated in several laboratories. The gratings provide reflection, output coupling, and power transmission to other gain segments for purposes of injection locking. The analysis determines these quantities for arbitrary-shaped grating teeth and includes the presence of a substrate reflector to reduce the radiated power in that direction. The reflector is shown to be effective, but only if it can be precisely positioned. Examples illustrating variations in dimensions, tooth shapes and heights, waveguide loss, and detuning are included.

  4. Experimental Measurement of the Second-Order Coherence of Supercontinuum.

    PubMed

    Närhi, Mikko; Turunen, Jari; Friberg, Ari T; Genty, Goëry

    2016-06-17

    We measure experimentally the second-order coherence properties of supercontinuum generated in a photonic crystal fiber. Our approach is based on measuring separately the quasicoherent and quasistationary contributions to the cross-spectral density and mutual coherence functions using a combination of interferometric and nonlinear gating techniques. This allows us to introduce two-dimensional coherence spectrograms which provide a direct characterization and convenient visualization of the spectrotemporal coherence properties. The measured second-order coherence functions are in very good agreement with numerical simulations based on the generalized nonlinear Schrödinger equation. Our results pave the way towards the full experimental characterization of supercontinuum coherence properties. More generally, they provide a generic approach for the complete experimental measurement of the coherence of broadband sources. PMID:27367389

  5. Experimental Measurement of the Second-Order Coherence of Supercontinuum

    NASA Astrophysics Data System (ADS)

    Närhi, Mikko; Turunen, Jari; Friberg, Ari T.; Genty, Goëry

    2016-06-01

    We measure experimentally the second-order coherence properties of supercontinuum generated in a photonic crystal fiber. Our approach is based on measuring separately the quasicoherent and quasistationary contributions to the cross-spectral density and mutual coherence functions using a combination of interferometric and nonlinear gating techniques. This allows us to introduce two-dimensional coherence spectrograms which provide a direct characterization and convenient visualization of the spectrotemporal coherence properties. The measured second-order coherence functions are in very good agreement with numerical simulations based on the generalized nonlinear Schrödinger equation. Our results pave the way towards the full experimental characterization of supercontinuum coherence properties. More generally, they provide a generic approach for the complete experimental measurement of the coherence of broadband sources.

  6. Robust stability of second-order systems

    NASA Technical Reports Server (NTRS)

    Chuang, C.-H.

    1995-01-01

    It has been shown recently how virtual passive controllers can be designed for second-order dynamic systems to achieve robust stability. The virtual controllers were visualized as systems made up of spring, mass and damping elements. In this paper, a new approach emphasizing on the notion of positive realness to the same second-order dynamic systems is used. Necessary and sufficient conditions for positive realness are presented for scalar spring-mass-dashpot systems. For multi-input multi-output systems, we show how a mass-spring-dashpot system can be made positive real by properly choosing its output variables. In particular, sufficient conditions are shown for the system without output velocity. Furthermore, if velocity cannot be measured then the system parameters must be precise to keep the system positive real. In practice, system parameters are not always constant and cannot be measured precisely. Therefore, in order to be useful positive real systems must be robust to some degrees. This can be achieved with the design presented in this paper.

  7. First- and second-order Poisson spots

    NASA Astrophysics Data System (ADS)

    Kelly, William R.; Shirley, Eric L.; Migdall, Alan L.; Polyakov, Sergey V.; Hendrix, Kurt

    2009-08-01

    Although Thomas Young is generally given credit for being the first to provide evidence against Newton's corpuscular theory of light, it was Augustin Fresnel who first stated the modern theory of diffraction. We review the history surrounding Fresnel's 1818 paper and the role of the Poisson spot in the associated controversy. We next discuss the boundary-diffraction-wave approach to calculating diffraction effects and show how it can reduce the complexity of calculating diffraction patterns. We briefly discuss a generalization of this approach that reduces the dimensionality of integrals needed to calculate the complete diffraction pattern of any order diffraction effect. We repeat earlier demonstrations of the conventional Poisson spot and discuss an experimental setup for demonstrating an analogous phenomenon that we call a "second-order Poisson spot." Several features of the diffraction pattern can be explained simply by considering the path lengths of singly and doubly bent paths and distinguishing between first- and second-order diffraction effects related to such paths, respectively.

  8. Synchronization from Second Order Network Connectivity Statistics

    PubMed Central

    Zhao, Liqiong; Beverlin, Bryce; Netoff, Theoden; Nykamp, Duane Q.

    2011-01-01

    We investigate how network structure can influence the tendency for a neuronal network to synchronize, or its synchronizability, independent of the dynamical model for each neuron. The synchrony analysis takes advantage of the framework of second order networks, which defines four second order connectivity statistics based on the relative frequency of two-connection network motifs. The analysis identifies two of these statistics, convergent connections, and chain connections, as highly influencing the synchrony. Simulations verify that synchrony decreases with the frequency of convergent connections and increases with the frequency of chain connections. These trends persist with simulations of multiple models for the neuron dynamics and for different types of networks. Surprisingly, divergent connections, which determine the fraction of shared inputs, do not strongly influence the synchrony. The critical role of chains, rather than divergent connections, in influencing synchrony can be explained by their increasing the effective coupling strength. The decrease of synchrony with convergent connections is primarily due to the resulting heterogeneity in firing rates. PMID:21779239

  9. Second order optical nonlinearity in silicon by symmetry breaking

    NASA Astrophysics Data System (ADS)

    Cazzanelli, Massimo; Schilling, Joerg

    2016-03-01

    Although silicon does not possess a dipolar bulk second order nonlinear susceptibility due to its centro-symmetric crystal structure, in recent years several attempts were undertaken to create such a property in silicon. This review presents the different sources of a second order susceptibility (χ(2)) in silicon and the connected second order nonlinear effects which were investigated up to now. After an introduction, a theoretical overview discusses the second order nonlinearity in general and distinguishes between the dipolar contribution—which is usually dominating in non-centrosymmetric structures—and the quadrupolar contribution, which even exists in centro-symmetric materials. Afterwards, the classic work on second harmonic generation from silicon surfaces in reflection measurements is reviewed. Due to the abrupt symmetry breaking at surfaces and interfaces locally a dipolar second order susceptibility appears, resulting in, e.g., second harmonic generation. Since the bulk contribution is usually small, the study of this second harmonic signal allows a sensitive observation of the surface/interface conditions. The impact of covering films, strain, electric fields, and defect states at the interfaces was already investigated in this way. With the advent of silicon photonics and the search for ever faster electrooptic modulators, the interest turned to the creation of a dipolar bulk χ(2) in silicon. These efforts have been focussing on several experiments applying an inhomogeneous strain to the silicon lattice to break its centro-symmetry. Recent results suggesting the impact of electric fields which are exerted from fixed charges in adjacent covering layers are also included. After a subsequent summary on "competing" concepts using not Si but Si-related materials, the paper will end with some final conclusions, suggesting possible future research direction in this dynamically developing field.

  10. Role of the acceptor in tuning the properties of metal [M(II) = Ni, Pd, Pt] dithiolato/dithione (donor/acceptor) second-order nonlinear chromophores: combined experimental and theoretical studies.

    PubMed

    Espa, Davide; Pilia, Luca; Makedonas, Christodoulos; Marchiò, Luciano; Mercuri, M Laura; Serpe, Angela; Barsella, Alberto; Fort, Alain; Mitsopoulou, Christiana A; Deplano, Paola

    2014-01-21

    The mixed-ligand complexes [M(II)(Et2dazdt)(mnt)] (M = Ni, 1; Pd, 2; Pt, 3) [Et2dazdt = N,N'-diethyl-perhydrodiazepine-2,3-dithione; mnt = maleonitrile-2,3-dithiolate] have been prepared and fully characterized. X-ray diffractometric studies on 1-3 (the structure of 1 was already known) show that the crystals are isostructural (triclinic, P-1), and two independent molecular entities are present in the unit cell. These entities differ in the orientation of the ethyl substituents with respect to the epta-atomic ring. In the C2S2MS2C2 dithiolene core the four sulfur atoms define a square-planar coordination environment of the metal where the M-S bond distances involving the two ligands are similar, while the C-S bond distances in the C2S2 units exhibit a significant difference in Et2dazdt (dithione) and mnt (dithiolato) ligands. 1-3 show in the visible region one or two moderately strong absorption peaks, having ligand-to-ligand charge-transfer (CT) character with some contribution of the metal, and show negative solvatochromism and molecular quadratic optical nonlinearity, which was determined by the EFISH (electric-field-induced second-harmonic generation) technique. These complexes are redox active and show two reversible reduction waves and one irreversible oxidation wave. Theoretical calculations based on DFT and TD-DFT calculations on complexes 1-3 as well as on [Pt(Bz2pipdt)(mnt)] (4) and [Pt(Bz2pipdt)(dmit)] (5) highlight the factors which affect the optical properties of these second-order redox-active NLO chromophores. Actually, the torsion angle of the dithione system (δ2) inversely correlates either with the oscillator strengths of the main transition of the complexes or with their beta values. The high beta value of 5 can be attributed both to its lowest torsion angles and to the extent of the π system of its dithiolate ligand, dmit. PMID:24405208

  11. A second order parameter for 3SAT

    SciTech Connect

    Sandholm, T.W.

    1996-12-31

    The 3-satisfiability problem (3SAT) has had a central role in the study of complexity. It was recently found that 3SAT instances transition sharply from satisfiable to nonsatisfiable as the ratio of clauses to variables increases. Because this phase transition is so sharp, the ratio - an order parameter - can be used to predict satisfiability. This paper describes a second order parameter for 3SAT. Like the classical order parameter, it can be computed in linear time, but it analyzes the structure of the problem instance more deeply. We present an analytical method for using this new order parameter in conjunction with the classical one to enhance satisfiability prediction accuracy. The assumptions of the method are verified by rigorous statistical testing. The method significantly increases the satisfiability prediction accuracy over using the classical order parameter alone. Hardness - i.e. how long it takes to determine satisfiability - results for one complete and one incomplete algorithm from the literature are also presented as a function of the two order parameters. The importance of new order parameters lies in the fact that they refine the locating of satisfiable vs. nonsatisfiable and hard vs. easy formulas in the space of all problem instances by adding a new dimension in the analysis.

  12. Second-order parametrized-post-Newtonian Lagrangian

    SciTech Connect

    Benacquista, M.J. )

    1992-02-15

    A many-body Lagrangian to second post-Newtonian order using an extension of the parametrized-post-Newtonian (PPN) formalism is introduced and the properties of new parameters are explored. A parametrized gauge transformation is developed to permit comparison with theories of gravity in a variety of different coordinate systems. A procedure to impose Lorentz invariance on a general second-order post-Newtonian Lagrangian is developed. The Lagrangian is then constrained to possess Lorentz invariance and a Lorentz-invariant'' gauge is introduced. The constrained Lagrangian is found to be described by ten new second-order PPN parameters. When the Lagrangian is further constrained to describe theories of gravity for which test particles move along geodesics, one of the ten new parameters is given entirely in terms of first-order PPN parameters, leaving only nine PPN parameters to describe the second-order gravitational interaction. A metric'' gauge is introduced which allows the metric to be easily found from the Lagrangian and is shown to reduce to the gauge associated with the canonical formalism of Arnowitt, Deser, and Misner when the general-relativity values of the PPN parameters are used.

  13. Analysis of implicit second-order upwind-biased stencils

    NASA Technical Reports Server (NTRS)

    Roberts, Thomas W.; Warren, Gary P.

    1993-01-01

    Truncation error and stability properties of several implicit upwind schemes for the two-dimensional Euler equations are examined. The schemes use linear data reconstruction methods to achieve second-order flux integrations where the implicit Jacobian operators are first order. The stability properties of the schemes are examined by a Von Neumann analysis of the linearized, constant-coefficient Euler equations. The choice of the data reconstruction method used to evaluate the flux integral has a dramatic effect on the convergence properties of the implicit solution method. In particular, the typical one-dimensional data reconstruction methods used with structured grids exhibit poor convergence properties compared to the unstructured grid method considered. Of the schemes examined, the one with the superior convergence properties is well-suited for both unstructured and structured grids, which has important implications for the design of implicit methods.

  14. Entanglement in a second-order quantum phase transition

    SciTech Connect

    Vidal, Julien; Palacios, Guillaume; Mosseri, Remy

    2004-02-01

    We consider a system of mutually interacting spins 1/2 embedded in a transverse magnetic field which undergoes a second-order quantum phase transition. We analyze the entanglement properties and the spin squeezing of the ground state and show that, contrarily to the one-dimensional case, a cusplike singularity appears at the critical point {lambda}{sub c} in the thermodynamical limit. We also show that there exists a value {lambda}{sub 0}{>=}{lambda}{sub c} above which the ground state is not spin squeezed despite a nonvanishing concurrence.

  15. The Landscape of Evolution: Reconciling Structural and Dynamic Properties of Metabolic Networks in Adaptive Diversifications.

    PubMed

    Morrison, Erin S; Badyaev, Alexander V

    2016-08-01

    The network of the interactions among genes, proteins, and metabolites delineates a range of potential phenotypic diversifications in a lineage, and realized phenotypic changes are the result of differences in the dynamics of the expression of the elements and interactions in this deterministic network. Regulatory mechanisms, such as hormones, mediate the relationship between the structural and dynamic properties of networks by determining how and when the elements are expressed and form a functional unit or state. Changes in regulatory mechanisms lead to variable expression of functional states of a network within and among generations. Functional properties of network elements, and the magnitude and direction of evolutionary change they determine, depend on their location within a network. Here, we examine the relationship between network structure and the dynamic mechanisms that regulate flux through a metabolic network. We review the mechanisms that control metabolic flux in enzymatic reactions and examine structural properties of the network locations that are targets of flux control. We aim to establish a predictive framework to test the contributions of structural and dynamic properties of deterministic networks to evolutionary diversifications. PMID:27252203

  16. Design of optimal second-order state estimators

    NASA Technical Reports Server (NTRS)

    Joshi, Suresh M.

    1991-01-01

    The present consideration of the design of online computation-saving second-order state estimators for second-order vector-matrix differential systems proposes a class of such estimators which is proven to possess guaranteed convergence. A class of optimal second-order estimators is then obtained, and the conditions required for optimality are identified. The estimator proposed offers high performance in conjunction with online computation reductions sufficiently great to allow the estimation of the large number of state variables associated with control of large, flexible space structures represented by high-dimensional second-order systems.

  17. The Morse Oscillator and Second-Order Perturbation Theory

    NASA Astrophysics Data System (ADS)

    Pettitt, B. A.

    1998-09-01

    This article shows how the energies of the Morse oscillator are obtained exactly from a second-order perturbation expansion in a harmonic oscillator basis. This exercise is recommended for its instructional value in intermediate quantum chemistry, in that the second-order term is entirely tractable, it arises within an important context (anharmonicity of vibrations), and it gives the right answer.

  18. Effects of Second-Order Hydrodynamics on a Semisubmersible Floating Offshore Wind Turbine: Preprint

    SciTech Connect

    Bayati, I.; Jonkman, J.; Robertson, A.; Platt, A.

    2014-07-01

    The objective of this paper is to assess the second-order hydrodynamic effects on a semisubmersible floating offshore wind turbine. Second-order hydrodynamics induce loads and motions at the sum- and difference-frequencies of the incident waves. These effects have often been ignored in offshore wind analysis, under the assumption that they are significantly smaller than first-order effects. The sum- and difference-frequency loads can, however, excite eigenfrequencies of the system, leading to large oscillations that strain the mooring system or vibrations that cause fatigue damage to the structure. Observations of supposed second-order responses in wave-tank tests performed by the DeepCwind consortium at the MARIN offshore basin suggest that these effects might be more important than originally expected. These observations inspired interest in investigating how second-order excitation affects floating offshore wind turbines and whether second-order hydrodynamics should be included in offshore wind simulation tools like FAST in the future. In this work, the effects of second-order hydrodynamics on a floating semisubmersible offshore wind turbine are investigated. Because FAST is currently unable to account for second-order effects, a method to assess these effects was applied in which linearized properties of the floating wind system derived from FAST (including the 6x6 mass and stiffness matrices) are used by WAMIT to solve the first- and second-order hydrodynamics problems in the frequency domain. The method has been applied to the OC4-DeepCwind semisubmersible platform, supporting the NREL 5-MW baseline wind turbine. The loads and response of the system due to the second-order hydrodynamics are analysed and compared to first-order hydrodynamic loads and induced motions in the frequency domain. Further, the second-order loads and induced response data are compared to the loads and motions induced by aerodynamic loading as solved by FAST.

  19. Study of second order upwind differencing in a recirculating flow

    NASA Technical Reports Server (NTRS)

    Vanka, S. P.

    1985-01-01

    The accuracy and stability of the second order upwind differencing scheme was investigated. The solution algorithm employed is based on a coupled solution of the nonlinear finite difference equations by the multigrid technique. Calculations have been made of the driven cavity flow for several Reynolds numbers and finite difference grids. In comparison with the hybrid differencing, the second order upwind differencing is somewhat more accurate but it is not monotonically accurate with mesh refinement. Also, the convergence of the solution algorithm deteriorates with the use of the second order upwind differencing.

  20. A study of second-order supersonic flow theory

    NASA Technical Reports Server (NTRS)

    Van Dyke, Milton D

    1952-01-01

    Second-order solutions of supersonic-flow problems are sought by iteration, using the linearized solution as the first step. For plane and axially symmetric flows, particular solutions of the iteration equation are discovered which reduce the second-order problem to an equivalent linearized problem. Comparison of second-order solutions with exact and numerical results shows great improvement over linearized theory. For full three-dimensional flow, only a partial particular solution is found. The inclined cone is solved, and the possibility of treating more general problems is considered.

  1. Method to render second order beam optics programs symplectic

    SciTech Connect

    Douglas, D.; Servranckx, R.V.

    1984-10-01

    We present evidence that second order matrix-based beam optics programs violate the symplectic condition. A simple method to avoid this difficulty, based on a generating function approach to evaluating transfer maps, is described. A simple example illustrating the non-symplectricity of second order matrix methods, and the effectiveness of our solution to the problem, is provided. We conclude that it is in fact possible to bring second order matrix optics methods to a canonical form. The procedure for doing so has been implemented in the program DIMAT, and could be implemented in programs such as TRANSPORT and TURTLE, making them useful in multiturn applications. 15 refs.

  2. Second-order state estimation experiments using acceleration measurements

    NASA Technical Reports Server (NTRS)

    Belvin, W. K.

    1992-01-01

    The estimation of dynamic states for feedback control of structural systems using second-order differential equations and acceleration measurements is described. The formulation of the observer model, and the design of the observer gains is discussed in detail. It is shown the second-order observer is highly stable because the stability constraints on the observer gains are model independent. The limitation of the proposed observer is the need for 'nearly' collocated actuators and accelerometers. Experimental results using a control-structure interaction testbed are presented that show the second-order observer provided more stability than a Kalman filter estimator without decreasing closed-loop performance.

  3. Orthogonal canonical forms for second-order systems

    NASA Technical Reports Server (NTRS)

    Williams, Trevor; Laub, Alan

    1989-01-01

    The authors prove that a linear second-order system with arbitrary damping cannot be reduced to Hessenberg-triangular form by means of orthogonal transformations, while this reduction is always possible for the modal damping commonly assumed for models of flexible structures. The type of canonical form obtainable by means of orthogonal transformations acting on a second-order system is heavily dependent on the type of damping considered. If the damping matrix is merely positive semi-definite symmetric, it is generally not possible to obtain a reduction to Hessenberg-triangular form, while this reduction is trivial for zero or Rayleigh damping. If damping is modal, however, as is commonly assumed in structural models, the reduction exists and is nontrivial. Furthermore, reduction to triangular second-order Schur form is always possible for such damping: this canonical form appears likely to have applications to second-order system theory.

  4. Oscillation theorems for second order nonlinear forced differential equations.

    PubMed

    Salhin, Ambarka A; Din, Ummul Khair Salma; Ahmad, Rokiah Rozita; Noorani, Mohd Salmi Md

    2014-01-01

    In this paper, a class of second order forced nonlinear differential equation is considered and several new oscillation theorems are obtained. Our results generalize and improve those known ones in the literature. PMID:25077054

  5. Fast second-order consensus via predictive mechanisms

    NASA Astrophysics Data System (ADS)

    Wu, Jie; Zhang, Li-Yi; Bai, Yu

    2015-01-01

    In this paper, we discuss second-order consensus problems for multi-agent systems with dynamic agents and fixed topologies. A new second-order consensus protocol incorporating the predictive mechanism is proposed and a convergence analysis related to the real and imaginary parts of the eigenvalues of the Laplacian matrix of the corresponding network is provided. We establish a direct connection between the eigenvalues of the Laplacian matrix and parameters of the proposed second-order consensus model, and we compute a lower bound for the sum of parameters. It is proved under general conditions related to the second-order consensus protocol and the network topology that the asymptotic consensus is achieved and the convergence speed is increased via designing a state predictor. Finally, simulation results are provided to verify the effectiveness of the proposed protocol and the analytical claims.

  6. Drift kinetic equation exact through second order in gyroradius expansion

    SciTech Connect

    Simakov, Andrei N.; Catto, Peter J.

    2005-01-01

    The drift kinetic equation of Hazeltine [R. D. Hazeltine, Plasma Phys. 15, 77 (1973)] for a magnetized plasma of arbitrary collisionality is widely believed to be exact through the second order in the gyroradius expansion. It is demonstrated that this equation is only exact through the first order. The reason is that when evaluating the second-order gyrophase dependent distribution function, Hazeltine neglected contributions from the first-order gyrophase dependent distribution function, and then used this incomplete expression to derive the equation for the gyrophase independent distribution function. Consequently, the second-order distribution function and the stress tensor derived by this approach are incomplete. By relaxing slightly Hazeltine's orderings one is able to obtain a drift kinetic equation accurate through the second order in the gyroradius expansion. In addition, the gyroviscous stress tensor for plasmas of arbitrary collisionality is obtained.

  7. Orthogonal canonical forms for second-order systems

    NASA Technical Reports Server (NTRS)

    Williams, Trevor; Laub, Alan J.

    1992-01-01

    It is shown that a linear second-order system with arbitrary damping cannot be reduced to Hessenberg-triangular form by means of orthogonal transformations. However, it is also shown that such an orthogonal reduction is always possible for the modal damping commonly assumed for models of flexible structures. It is shown that modally damped models can be orthogonally reduced to a new triangular second-order Schur form.

  8. A novel second-order flux splitting for ideal magnetohydrodynamics

    NASA Astrophysics Data System (ADS)

    Borah, Kalpajyoti; Natarajan, Ganesh; Dass, Anoop K.

    2016-05-01

    A new flux splitting scheme based on wave-particle behaviour is developed for one-dimensional ideal magnetohydrodynamics. We exploit the idea that while ideal magnetohydrodynamics equations are non-convex with non-homogeneous fluxes as opposed to their hydrodynamic counterparts, they exhibit an overall wave-like structure. The proposed approach splits the flux vector into three distinct parts: the particle-like transport part and the wave-like pressure and magnetic parts, with the latter vanishing for pure hydrodynamics. The pressure part of the fluxes satisfy homogeneity property and the split flux Jacobians are constructed with a provision to regulate the numerical dissipation. The magnetic part of the fluxes however is non-homogeneous and is treated using a central scheme with artificial viscosity. This disparate treatment of the individual components of the total flux vector results in a scheme with a central-upwind character that can be implemented with low computational effort. Referred to as Magneto-acoustic Wave Particle Splitting (MWPS) scheme, it is extended to second-order accuracy by using slope limiters incorporated through the solution-dependent weighted least squares approach for gradient calculations. Several one-dimensional MHD problems are numerically solved to highlight the accuracy, positivity preservation and robustness of the MWPS scheme and comparative studies show that MWPS performs at least as well as the Advection Upstream Splitting Method (AUSM) and even outperforms it for some test cases.

  9. Superconvergent discontinuous Galerkin methods for second-order elliptic problems

    NASA Astrophysics Data System (ADS)

    Cockburn, Bernardo; Guzman, Johnny; Wang, Haiying

    2009-03-01

    We identify discontinuous Galerkin methods for second-order elliptic problems in several space dimensions having superconvergence properties similar to those of the Raviart-Thomas and the Brezzi-Douglas-Marini mixed methods. These methods use polynomials of degree kge0 for both the potential as well as the flux. We show that the approximate flux converges in L^2 with the optimal order of k+1 , and that the approximate potential and its numerical trace superconverge, in L^2 -like norms, to suitably chosen projections of the potential, with order k+2 . We also apply element-by-element postprocessing of the approximate solution to obtain new approximations of the flux and the potential. The new approximate flux is proven to have normal components continuous across inter-element boundaries, to converge in L^2 with order k+1 , and to have a divergence converging in L^2 also with order k+1 . The new approximate potential is proven to converge with order k+2 in L^2 . Numerical experiments validating these theoretical results are presented.

  10. [Second-order retrospective revaluation in human contingency learning].

    PubMed

    Numata, Keitaro; Shimazaki, Tsuneo

    2009-04-01

    We demonstrated second-order retrospective revaluation with three cues (T1, T2, and C) and an outcome, in human contingency learning. Experimental task, PC-controlled video game in which participants were required to observe about the relations between firing missiles and the tank destruction, consisted of three training phases and two rating phases. Groups C+ and C- consisted of same first two training phases, CT+ (cues C and T with an outcome) and T1T2+ followed by C+, or C- training for Groups C+, C-, respectively. In rating phases, it is clearly demonstrated that the judgment of predictive value for the outcome of the T2 were higher by C+ training (second-order unovershadowing) and lowered by C- training (second-order backward blocking). The results for Groups RC+ and RC-, in which the orders of the first two training phase for Groups C+ and C- were interchanged, also showed second-order unovershadowing and second-order backward blocking. These results, the robustness of second-order retrospective revaluation against the order of the first training phases, can be explained by the extended comparator hypothesis and probabilistic contrast model. However, these results cannot be explained by traditional associative learning models. PMID:19489431

  11. Second-order quasinormal mode of the Schwarzschild black hole

    SciTech Connect

    Nakano, Hiroyuki; Ioka, Kunihito

    2007-10-15

    We formulate and calculate the second-order quasinormal modes (QNMs) of a Schwarzschild black hole (BH). Gravitational waves (GW) from a distorted BH, the so-called ringdowns, are well understood as QNMs in general relativity. Since QNMs from binary BH mergers will be detected with a high signal-to-noise ratio by GW detectors, it is also possible to detect the second perturbative order of QNMs, generated by nonlinear gravitational interaction near the BH. In the BH perturbation approach, we derive the master Zerilli equation for the metric perturbation to second order and explicitly regularize it at the horizon and spatial infinity. We numerically solve the second-order Zerilli equation by implementing the modified Leaver continued fraction method. The second-order QNM frequencies are found to be twice the first-order ones, and the GW amplitude is up to {approx}10% that of the first order for the binary BH mergers. Since the second-order QNMs always exist, we can use their detections (i) to test the nonlinearity of general relativity, in particular, the no-hair theorem, (ii) to remove fake events in the data analysis of QNM GWs, and (iii) to measure the distance to the BH.

  12. Second-Order Olfactory-Mediated Fear-Potentiated Startle

    PubMed Central

    Paschall, Gayla Y.; Davis, Michael

    2002-01-01

    Recently, we reported that discrete (4-sec) olfactory cues paired with footshock serve as effective conditioned stimuli (CSs) for potentiating the acoustic startle response in rats using the fear-potentiated startle paradigm. Because odors are such salient cues for the rat, and because of the robust olfactory conditioning observed previously, the current studies investigated second-order fear conditioning using olfactory and visual cues. In Experiments 1 and 2, we used a small number of first-order and second-order training trials on separate days to investigate second-order fear-potentiated startle. Significant potentiated startle was observed in animals receiving Paired/Paired training in both studies, but surprisingly, control animals in the Unpaired/Paired group (Exp. 1) also showed significant potentiated startle to a light S2 at testing. These findings are addressed in the Discussion. Overall, the results of both experiments suggest that olfactory cues serve as efficient S1 and S2 stimuli in second-order fear-potentiated startle paradigms when only a small number of first and second-order training trials are presented. PMID:12464699

  13. Weak value amplification via second-order correlated technique

    NASA Astrophysics Data System (ADS)

    Ting, Cui; Jing-Zheng, Huang; Xiang, Liu; Gui-Hua, Zeng

    2016-02-01

    We propose a new framework combining weak measurement and second-order correlated technique. The theoretical analysis shows that weak value amplification (WVA) experiment can also be implemented by a second-order correlated system. We then build two-dimensional second-order correlated function patterns for achieving higher amplification factor and discuss the signal-to-noise ratio influence. Several advantages can be obtained by our proposal. For instance, detectors with high resolution are not necessary. Moreover, detectors with low saturation intensity are available in WVA setup. Finally, type-one technical noise can be effectively suppressed. Project supported by the Union Research Centre of Advanced Spaceflight Technology (Grant No. USCAST2013-05), the National Natural Science Foundation of China (Grant Nos. 61170228, 61332019, and 61471239), and the High-Tech Research and Development Program of China (Grant No. 2013AA122901).

  14. Some restrictions on the existence of second order limit language

    NASA Astrophysics Data System (ADS)

    Ahmad, Muhammad Azrin; Sarmin, Nor Haniza; Yusof, Yuhani; Fong, Wan Heng

    2015-10-01

    The cut and paste phenomenon on DNA molecules with the presence of restriction enzyme and appropriate ligase has led to the formalism of mathematical modelling of splicing system. A type of splicing system named Yusof-Goode splicing system is used to present the transparent behaviour of the DNA splicing process. The limit language that is defined as the leftover molecules after the system reaches its equilibrium point has been extended to a second order limit language. The non-existence of the second order limit language biologically has lead to this study by using mathematical approach. In this paper, the factors that restrict the formation of the second order limit language are discussed and are presented as lemmas and theorem using Y-G approach. In addition, the discussion focuses on Yusof- Goode splicing system with at most two initial strings and two rules with one cutting site and palindromic crossing site and recognition sites.

  15. Second order perturbations during inflation beyond slow-roll

    SciTech Connect

    Huston, Ian; Malik, Karim A. E-mail: k.malik@qmul.ac.uk

    2011-10-01

    We numerically calculate the evolution of second order cosmological perturbations for an inflationary scalar field without resorting to the slow-roll approximation or assuming large scales. In contrast to previous approaches we therefore use the full non-slow-roll source term for the second order Klein-Gordon equation which is valid on all scales. The numerical results are consistent with the ones obtained previously where slow-roll is a good approximation. We investigate the effect of localised features in the scalar field potential which break slow-roll for some portion of the evolution. The numerical package solving the second order Klein-Gordon equation has been released under an open source license and is available for download.

  16. Deflection of light to second order in conformal Weyl gravity

    NASA Astrophysics Data System (ADS)

    Sultana, Joseph

    2013-04-01

    We reexamine the deflection of light in conformal Weyl gravity obtained in Sultana and Kazanas (2010), by extending the calculation based on the procedure by Rindler and Ishak, for the bending angle by a centrally concentrated spherically symmetric matter distribution, to second order in M/R, where M is the mass of the source and R is the impact parameter. It has recently been reported in Bhattacharya et al. (JCAP 09 (2010) 004; JCAP 02 (2011) 028), that when this calculation is done to second order, the term γr in the Mannheim-Kazanas metric, yields again the paradoxical contribution γR (where the bending angle is proportional to the impact parameter) obtained by standard formalisms appropriate to asymptotically flat spacetimes. We show that no such contribution is obtained for a second order calculation and the effects of the term γr in the metric are again insignificant as reported in our earlier work.

  17. Second-order wave effects on TLP tendon tension responses

    SciTech Connect

    Xue, H.; Mercier, R.S.

    1996-12-31

    This paper presents a general procedure for analyzing the second-order wave effects on the tendon tension responses of a TLP. The approach solves both first- and second-order equation of motions for a TLP system in frequency domain. Viscous effects are included in the form of statistically linearized damping coefficients. An efficient algorithm has been devised for reducing the burden of second-order wave diffraction analysis, which selects the interacting frequency pairs according to springing frequency of interest to minimize the cost of computing quadratic transfer functions (QTFs) and allow accurate interpolation of QTFs. Moment statistics of the tension process are computed through an eigenvalue analysis. The developed method is applied to analyze the tendon tension responses of a TLP design in water depth of 3,000 ft.

  18. Second-order subsonic airfoil theory including edge effects

    NASA Technical Reports Server (NTRS)

    Van Dyke, Milton D

    1956-01-01

    Several recent advances in plane subsonic flow theory are combined into a unified second-order theory for airfoil sections of arbitrary shape. The solution is reached in three steps: the incompressible result is found by integration, it is converted into the corresponding subsonic compressible result by means of the second-order compressibility rule, and it is rendered uniformly valid near stagnation points by further rules. Solutions for a number of airfoils are given and are compared with the results of other theories and of experiment. A straight-forward computing scheme is outlined for calculating the surface velocities and pressures on any airfoil at any angle of attack

  19. Static second-order polarizabilities of aminobenzophenones and nitrobenzophenones

    NASA Technical Reports Server (NTRS)

    Moore, Craig E.; Cardelino, Beatriz H.

    1991-01-01

    Static-field theoretical studies on molecular second-order polarizabilities (beta) of benzophenone derivatives were performed. Calculations were based on the use of shaped electric fields and semiempirical Hamiltonians. Either an electron-donating (amine) or an electron-withdrawing (nitro) substituent was incorporated into a phenyl ring of benzophenone; the phenyl rings of benzophenone were oriented either coplanar or perpendicular to the carbonyl. The change in charge transfer with respect to the electrophilic character of the carbonyl group was monitored to determine its effect on the molecular second-order polarizability. Calculations were performed for all constitutional isomers of the two benzophenone derivatives.

  20. Kubo Formulas for Second-Order Hydrodynamic Coefficients

    SciTech Connect

    Moore, Guy D.; Sohrabi, Kiyoumars A.

    2011-03-25

    At second order in gradients, conformal relativistic hydrodynamics depends on the viscosity {eta} and on five additional ''second-order'' hydrodynamical coefficients {tau}{sub {Pi}}, {kappa}, {lambda}{sub 1}, {lambda}{sub 2}, and {lambda}{sub 3}. We derive Kubo relations for these coefficients, relating them to equilibrium, fully retarded three-point correlation functions of the stress tensor. We show that the coefficient {lambda}{sub 3} can be evaluated directly by Euclidean means and does not in general vanish.

  1. Elasto-plastic model with second order defect density tensor

    NASA Astrophysics Data System (ADS)

    Cleja-Ţigoiu, Sanda

    2011-05-01

    The paper deals with a second order finite elasto-plastic model, which involves the defect density tensor, as a measure of the extra material defects existing in the damaged microstructure. The material behaviour is described with respect to an anholonomic configuration, which is introduced through the second order plastic deformation, consisting in plastic distortion and plastic connection. The defect density tensor enters the expression of the plastic connection through its gradient and represents a measure of non-metricity. The constitutive and evolution equations are derived to be compatible with the free energy imbalance. The evolution equation for the defect density tensor is non-local and coupled with the plastic distortion.

  2. Controlling flexible structures with second order actuator dynamics

    NASA Technical Reports Server (NTRS)

    Inman, Daniel J.; Umland, Jeffrey W.; Bellos, John

    1989-01-01

    The control of flexible structures for those systems with actuators that are modeled by second order dynamics is examined. Two modeling approaches are investigated. First a stability and performance analysis is performed using a low order finite dimensional model of the structure. Secondly, a continuum model of the flexible structure to be controlled, coupled with lumped parameter second order dynamic models of the actuators performing the control is used. This model is appropriate in the modeling of the control of a flexible panel by proof-mass actuators as well as other beam, plate and shell like structural numbers. The model is verified with experimental measurements.

  3. The Poisson equation at second order in relativistic cosmology

    SciTech Connect

    Hidalgo, J.C.; Christopherson, Adam J.; Malik, Karim A. E-mail: Adam.Christopherson@nottingham.ac.uk

    2013-08-01

    We calculate the relativistic constraint equation which relates the curvature perturbation to the matter density contrast at second order in cosmological perturbation theory. This relativistic ''second order Poisson equation'' is presented in a gauge where the hydrodynamical inhomogeneities coincide with their Newtonian counterparts exactly for a perfect fluid with constant equation of state. We use this constraint to introduce primordial non-Gaussianity in the density contrast in the framework of General Relativity. We then derive expressions that can be used as the initial conditions of N-body codes for structure formation which probe the observable signature of primordial non-Gaussianity in the statistics of the evolved matter density field.

  4. A novel second order fast decoupled load flow method in polar coordinates

    SciTech Connect

    Nanda, J.; Kothari, D.P.; Srivastava, S.C. )

    1988-01-01

    This paper presents a novel and effective second order fast decoupled load flow model in polar co-ordinates employing a totally different approach than used in existing second order methods in polar co-ordinates. This work eliminates the need for storing and computing repeatedly the second order terms by prudently injecting the elements of the Hessian matrix into the Jacobian. This results in a memory requirement at par with the usual fast decoupled load flow method. Investigations reveal that for well-behaved systems, the new method and the fast decoupled load flow method have practically the same convergence properties, whereas for certain ill-conditioned systems, the new method shows distinctly better convergence properties.

  5. Second-order accurate nonoscillatory schemes for scalar conservation laws

    NASA Technical Reports Server (NTRS)

    Huynh, Hung T.

    1989-01-01

    Explicit finite difference schemes for the computation of weak solutions of nonlinear scalar conservation laws is presented and analyzed. These schemes are uniformly second-order accurate and nonoscillatory in the sense that the number of extrema of the discrete solution is not increasing in time.

  6. Remarks on the second-order Seiberg-Witten maps

    SciTech Connect

    Trampetic, Josip; Wohlgenannt, Michael

    2007-12-15

    In this brief report, we discuss the Seiberg-Witten maps up to the second order in the noncommutative parameter {theta}. They add to the recently published solutions in [A. Alboteanu, T. Ohl, and R. Rueckl, Phys. Rev. D 76, 105018 (2007).]. Expressions for the vector, fermion, and Higgs fields are given explicitly.

  7. Second-order sliding mode control with experimental application.

    PubMed

    Eker, Ilyas

    2010-07-01

    In this article, a second-order sliding mode control (2-SMC) is proposed for second-order uncertain plants using equivalent control approach to improve the performance of control systems. A Proportional + Integral + Derivative (PID) sliding surface is used for the sliding mode. The sliding mode control law is derived using direct Lyapunov stability approach and asymptotic stability is proved theoretically. The performance of the closed-loop system is analysed through an experimental application to an electromechanical plant to show the feasibility and effectiveness of the proposed second-order sliding mode control and factors involved in the design. The second-order plant parameters are experimentally determined using input-output measured data. The results of the experimental application are presented to make a quantitative comparison with the traditional (first-order) sliding mode control (SMC) and PID control. It is demonstrated that the proposed 2-SMC system improves the performance of the closed-loop system with better tracking specifications in the case of external disturbances, better behavior of the output and faster convergence of the sliding surface while maintaining the stability. PMID:20413118

  8. Second-order nonlinear optical metamaterials: ABC-type nanolaminates

    SciTech Connect

    Alloatti, L. Kieninger, C.; Lauermann, M.; Köhnle, K.; Froelich, A.; Wegener, M.; Frenzel, T.; Freude, W.; Leuthold, J.; Koos, C.

    2015-09-21

    We demonstrate a concept for second-order nonlinear metamaterials that can be obtained from non-metallic centrosymmetric constituents with inherently low optical absorption. The concept is based on iterative atomic-layer deposition of three different materials, A = Al{sub 2}O{sub 3}, B = TiO{sub 2}, and C = HfO{sub 2}. The centrosymmetry of the resulting ABC stack is broken since the ABC and the inverted CBA sequences are not equivalent—a necessary condition for non-zero second-order nonlinearity. In our experiments, we find that the bulk second-order nonlinear susceptibility depends on the density of interfaces, leading to a nonlinear susceptibility of 0.26 pm/V at a wavelength of 800 nm. ABC-type nanolaminates can be deposited on virtually any substrate and offer a promising route towards engineering of second-order optical nonlinearities at both infrared and visible wavelengths.

  9. Children's Understanding of Second-Order Mental States

    ERIC Educational Resources Information Center

    Miller, Scott A.

    2009-01-01

    The most popular topic in theory-of-mind research has been first-order false belief: the realization that it is possible to hold false beliefs about events in the world. A more advanced development is second-order false belief: the realization that it is possible to hold a false belief about someone else's belief. This article reviews research…

  10. Second-order variational equations for N-body simulations

    NASA Astrophysics Data System (ADS)

    Rein, Hanno; Tamayo, Daniel

    2016-07-01

    First-order variational equations are widely used in N-body simulations to study how nearby trajectories diverge from one another. These allow for efficient and reliable determinations of chaos indicators such as the Maximal Lyapunov characteristic Exponent (MLE) and the Mean Exponential Growth factor of Nearby Orbits (MEGNO). In this paper we lay out the theoretical framework to extend the idea of variational equations to higher order. We explicitly derive the differential equations that govern the evolution of second-order variations in the N-body problem. Going to second order opens the door to new applications, including optimization algorithms that require the first and second derivatives of the solution, like the classical Newton's method. Typically, these methods have faster convergence rates than derivative-free methods. Derivatives are also required for Riemann manifold Langevin and Hamiltonian Monte Carlo methods which provide significantly shorter correlation times than standard methods. Such improved optimization methods can be applied to anything from radial-velocity/transit-timing-variation fitting to spacecraft trajectory optimization to asteroid deflection. We provide an implementation of first- and second-order variational equations for the publicly available REBOUND integrator package. Our implementation allows the simultaneous integration of any number of first- and second-order variational equations with the high-accuracy IAS15 integrator. We also provide routines to generate consistent and accurate initial conditions without the need for finite differencing.

  11. Second-Order Conditioning during a Compound Extinction Treatment

    ERIC Educational Resources Information Center

    Pineno, Oskar; Zilski, Jessica M.; Schachtman, Todd R.

    2007-01-01

    Two conditioned taste aversion experiments with rats were conducted to establish if a target taste that had received a prior pairing with illness could be subject to second-order conditioning during extinction treatment in compound with a flavor that also received prior conditioning. In these experiments, the occurrence of second-order…

  12. Green's function of the second order differential operator with involution

    NASA Astrophysics Data System (ADS)

    Ashyralyev, Allaberen; Sarsenbi, Abdisalam A.

    2016-08-01

    In the present paper, the Green's function of the second order differential operator L defined by formula L u =α u″ (x ) -u″ (-x ) =λ u (x ) ,-1

  13. PREDICTIONS OF HIGHWAY EMISSIONS BY A SECOND ORDER CLOSURE MODEL

    EPA Science Inventory

    The dispersion of sulfur hexafluoride tracer and sulfate from automobile emissions in the immediate vicinity of a highway were estimated for conditions similar to those existing during the General Motors sulfate dispersion experiment conducted at a GM test track. A second-order c...

  14. Second-Order Conditioning of Human Causal Learning

    ERIC Educational Resources Information Center

    Jara, Elvia; Vila, Javier; Maldonado, Antonio

    2006-01-01

    This article provides the first demonstration of a reliable second-order conditioning (SOC) effect in human causal learning tasks. It demonstrates the human ability to infer relationships between a cause and an effect that were never paired together during training. Experiments 1a and 1b showed a clear and reliable SOC effect, while Experiments 2a…

  15. Modeling Ability Differentiation in the Second-Order Factor Model

    ERIC Educational Resources Information Center

    Molenaar, Dylan; Dolan, Conor V.; van der Maas, Han L. J.

    2011-01-01

    In this article we present factor models to test for ability differentiation. Ability differentiation predicts that the size of IQ subtest correlations decreases as a function of the general intelligence factor. In the Schmid-Leiman decomposition of the second-order factor model, we model differentiation by introducing heteroscedastic residuals,…

  16. Pecuniary Effects, Second-Order Conditions, and the LRAC Curve.

    ERIC Educational Resources Information Center

    Comolli, Paul M.

    2000-01-01

    Explores the importance of second-order conditions in the cost-minimization problem confronting the monopsonistic employer of factor inputs. Describes an alternative approach to the presence of pecuniary effects that does not depend on the assumption that firms are monopsonistic in factor markets. (CMK)

  17. A New Factorisation of a General Second Order Differential Equation

    ERIC Educational Resources Information Center

    Clegg, Janet

    2006-01-01

    A factorisation of a general second order ordinary differential equation is introduced from which the full solution to the equation can be obtained by performing two integrations. The method is compared with traditional methods for solving these type of equations. It is shown how the Green's function can be derived directly from the factorisation…

  18. Forward and Backward Second-Order Pavlovian Conditioning in Honeybees

    ERIC Educational Resources Information Center

    Hussaini, Syed Abid; Komischke, Bernhard; Menzel, Randolf; Lachnit, Harald

    2007-01-01

    Second-order conditioning (SOC) is the association of a neutral stimulus with another stimulus that had previously been combined with an unconditioned stimulus (US). We used classical conditioning of the proboscis extension response (PER) in honeybees ("Apis mellifera") with odors (CS) and sugar (US). Previous SOC experiments in bees were…

  19. Generalized Second-Order Partial Derivatives of 1/r

    ERIC Educational Resources Information Center

    Hnizdo, V.

    2011-01-01

    The generalized second-order partial derivatives of 1/r, where r is the radial distance in three dimensions (3D), are obtained using a result of the potential theory of classical analysis. Some non-spherical-regularization alternatives to the standard spherical-regularization expression for the derivatives are derived. The utility of a…

  20. Solving Second-Order Differential Equations with Variable Coefficients

    ERIC Educational Resources Information Center

    Wilmer, A., III; Costa, G. B.

    2008-01-01

    A method is developed in which an analytical solution is obtained for certain classes of second-order differential equations with variable coefficients. By the use of transformations and by repeated iterated integration, a desired solution is obtained. This alternative method represents a different way to acquire a solution from classic power…

  1. On the second-order tangent bundle with horizontal lift connection

    NASA Astrophysics Data System (ADS)

    Gezer, Aydin; Magden, Abdullah; Karaca, Kubra

    2016-04-01

    Let M be an n-dimensional differentiable manifold equipped with a torsion-free linear connection ∇ and T2 M be its second-order tangent bundle. The present paper aims to study some curvature properties of T2 M with respect to the horizontal lift connection H∇.

  2. Theoretical study of second-order hyperpolarizability for nitrogen radical cation

    NASA Astrophysics Data System (ADS)

    Tarazkar, Maryam; Romanov, Dmitri A.; Levis, Robert J.

    2015-05-01

    We report calculations of the static and dynamic hyperpolarizabilities of the nitrogen radical cation in doublet state. The electronic contributions were computed analytically using density functional theory and multi-configurational self-consistent field method with extended basis sets for non-resonant excitation. The open-shell electronic system of nitrogen radical cation provides negative second-order optical nonlinearity, suggesting that the hyperpolarizability coefficient, {{γ }(2)}, in the non-resonant regime is mainly composed of combinations of virtual one-photon transitions rather than two-photon transitions. The second-order optical properties of nitrogen radical cation have been calculated as a function of bond length starting with the neutral molecular geometry (S0 minimum) and stretching the N-N triple bond, reaching the ionic D0 relaxed geometry all the way toward dissociation limit, to investigate the effect of internuclear bond distance on second-order hyperpolarizability.

  3. First- and second-order charged particle optics

    SciTech Connect

    Brown, K.L.; Servranckx, R.V.

    1984-07-01

    Since the invention of the alternating gradient principle there has been a rapid evolution of the mathematics and physics techniques applicable to charged particle optics. In this publication we derive a differential equation and a matrix algebra formalism valid to second-order to present the basic principles governing the design of charged particle beam transport systems. A notation first introduced by John Streib is used to convey the essential principles dictating the design of such beam transport systems. For example the momentum dispersion, the momentum resolution, and all second-order aberrations are expressed as simple integrals of the first-order trajectories (matrix elements) and of the magnetic field parameters (multipole components) characterizing the system. 16 references, 30 figures.

  4. An application of integral inequality to second order nonlinear oscillation

    NASA Astrophysics Data System (ADS)

    Kwong, Man Kam; Wong, James S. W.

    A simple result concerning integral inequalities enables us to give an alternative proof of Waltman's theorem: lim t → ∞ ∝ t0a( s) ds = ∞ implies oscillation of the second order nonlinear equation y″( t) + a( t) f( y( t)) = 0; to prove an analog of Wintner's theorem that relates the nonoscillation of the second order nonlinear equations to the existence of solutions of some integral equations, assuming that lim t → ∞ ∝ t0a( s) ds exists; and to give an alternative proof and to extend a result of Butler. An often used condition on the coefficient a( t) is given a more familiar equivalent form and an oscillation criterion involving this condition is established.

  5. Symmetries of second-order PDEs and conformal Killing vectors

    NASA Astrophysics Data System (ADS)

    Tsamparlis, Michael; Paliathanasis, Andronikos

    2015-06-01

    We study the Lie point symmetries of a general class of partial differential equations (PDE) of second order. An equation from this class naturally defines a second-order symmetric tensor (metric). In the case the PDE is linear on the first derivatives we show that the Lie point symmetries are given by the conformal algebra of the metric modulo a constraint involving the linear part of the PDE. Important elements in this class are the Klein-Gordon equation and the Laplace equation. We apply the general results and determine the Lie point symmetries of these equations in various general classes of Riemannian spaces. Finally we study the type II hidden symmetries of the wave equation in a Riemannian space with a Lorenzian metric.

  6. Robust eigensystem assignment for second-order estimators

    NASA Technical Reports Server (NTRS)

    Juang, Jer-Nan; Maghami, Peiman G.

    1990-01-01

    An approach for the robust eigensystem assignment of flexible structures using full state or output feedback is developed. Using the second-order dynamic equations, the approach can assign the eigenvalues of the system via velocity and displacement feedbacks, or acceleration and velocity feedbacks. The eigenvalues and eigenvectors of the system are assigned, via the second-order eigenvalue problem for the structural system, in two steps. First, an orthonormal basis spanning the attainable closed-loop eigenvector space corresponding to each desired closed-loop eigenvalue is generated using the Singular Value or QR decompositions. Second, a sequential procedure is used to choose a set of closed-loop eigenvectors that are as close as possible to the column space of a well-conditioned target matrix. Among the possible choices of the target matrix, the closest unitary matrix to the open-loop eigenvector matrix appears to be a suitable choice. A numerical example is given to illustrate the proposed algorithm.

  7. On the second order spatiochromatic structure of natural images.

    PubMed

    Provenzi, Edoardo; Delon, Julie; Gousseau, Yann; Mazin, Baptiste

    2016-03-01

    We provide a theoretical analysis of some empirical facts about the second order spatiochromatic structure of natural images in color. In particular, we show that two simple assumptions on the covariance matrices of color images yield eigenvectors made by the Kronecker product of Fourier features times the triad given by luminance plus color opponent channels. The first of these assumptions is second order stationarity while the second one is commutativity between color correlation matrices. The validity of these assumptions and the predicted shape of the PCA components of color images are experimentally observed on two large image databases. As a by-product of this experimental study, we also provide novel data to support an exponential decay law of the spatiochromatic covariance between pairs of pixels as a function of their spatial distance. PMID:26024561

  8. A Second-Order Achromat Design Based on FODO Cell

    SciTech Connect

    Sun, Yipeng; /SLAC

    2011-08-19

    Two dipole doglegs are widely used to translate the beam axis horizontally or vertically. Quadrupoles are placed between the two consecutive dipoles to match first order dispersion and provide betatron focusing. Similarly a four dipole chicane is usually employed to form a bypass region, where the beam axis is transversely shifted first, then translated back to the original axis. In order to generate an isochronous section, quadrupoles are again needed to tune the first order transfer matrix element R{sub 56} equaling zero. Usually sextupoles are needed to correct second order dispersion in the bending plane, for both the dogleg optics and the chicane (with quad) optics. In this paper, an alternative optics design is introduced, which is based on a simple FODO cell and does not need sextupoles assistance to form a second-order achromat. It may provide a similar function of either a dogleg or a bypass, by using 2 or 4 of such combined supercells.

  9. Second order upwind Lagrangian particle method for Euler equations

    DOE PAGESBeta

    Samulyak, Roman; Chen, Hsin -Chiang; Yu, Kwangmin

    2016-06-01

    A new second order upwind Lagrangian particle method for solving Euler equations for compressible inviscid fluid or gas flows is proposed. Similar to smoothed particle hydrodynamics (SPH), the method represents fluid cells with Lagrangian particles and is suitable for the simulation of complex free surface / multiphase flows. The main contributions of our method, which is different from SPH in all other aspects, are (a) significant improvement of approximation of differential operators based on a polynomial fit via weighted least squares approximation and the convergence of prescribed order, (b) an upwind second-order particle-based algorithm with limiter, providing accuracy and longmore » term stability, and (c) accurate resolution of states at free interfaces. In conclusion, numerical verification tests demonstrating the convergence order for fixed domain and free surface problems are presented.« less

  10. Second-order closure models for supersonic turbulent flows

    NASA Technical Reports Server (NTRS)

    Speziale, Charles G.; Sarkar, Sutanu

    1991-01-01

    Recent work on the development of a second-order closure model for high-speed compressible flows is reviewed. This turbulent closure is based on the solution of modeled transport equations for the Favre-averaged Reynolds stress tensor and the solenoidal part of the turbulent dissipation rate. A new model for the compressible dissipation is used along with traditional gradient transport models for the Reynolds heat flux and mass flux terms. Consistent with simple asymptotic analyses, the deviatoric part of the remaining higher-order correlations in the Reynolds stress transport equations are modeled by a variable density extension of the newest incompressible models. The resulting second-order closure model is tested in a variety of compressible turbulent flows which include the decay of isotropic turbulence, homogeneous shear flow, the supersonic mixing layer, and the supersonic flat-plate turbulent boundary layer. Comparisons between the model predictions and the results of physical and numerical experiments are quite encouraging.

  11. Analysis of the blazing effect in second-order gratings

    SciTech Connect

    Matsumoto, Masauki )

    1992-10-01

    The validity of the blazing effect for improving the output-coupling efficiency of second-order gratings for use in grating-coupled surface-emitting lasers is examined. The Floquet-Bloch expansion method is used for the analysis of finite-length gratings with asymmetric tooth shapes operated in resonance condition. It is shown that for saw-tooth gratings the blazing effect is almost lost around the second-order Bragg wavelength because the reflected guide mode generated in the distributed Bragg reflector radiates preferentially into the substrate. By using a parallelogram grating with equal tooth and groove lengths, however, a high efficiency of radiation into the air is attainable even at the Bragg wavelength while the reflectivity is reduced. 32 refs.

  12. Relativistic second-order dissipative hydrodynamics at finite chemical potential

    NASA Astrophysics Data System (ADS)

    Jaiswal, Amaresh; Friman, Bengt; Redlich, Krzysztof

    2015-12-01

    Starting from the Boltzmann equation in the relaxation time approximation and employing a Chapman-Enskog like expansion for the distribution function close to equilibrium, we derive second-order evolution equations for the shear stress tensor and the dissipative charge current for a system of massless quarks and gluons. The transport coefficients are obtained exactly using quantum statistics for the phase space distribution functions at non-zero chemical potential. We show that, within the relaxation time approximation, the second-order evolution equations for the shear stress tensor and the dissipative charge current can be decoupled. We find that, for large values of the ratio of chemical potential to temperature, the charge conductivity is small compared to the coefficient of shear viscosity. Moreover, we show that in the relaxation-time approximation, the limiting behaviour of the ratio of heat conductivity to shear viscosity is qualitatively similar to that obtained for a strongly coupled conformal plasma.

  13. Extensions and applications of a second-order landsurface parameterization

    NASA Technical Reports Server (NTRS)

    Andreou, S. A.; Eagleson, P. S.

    1983-01-01

    Extensions and applications of a second order land surface parameterization, proposed by Andreou and Eagleson are developed. Procedures for evaluating the near surface storage depth used in one cell land surface parameterizations are suggested and tested by using the model. Sensitivity analysis to the key soil parameters is performed. A case study involving comparison with an "exact" numerical model and another simplified parameterization, under very dry climatic conditions and for two different soil types, is also incorporated.

  14. Gravitational waves from global second order phase transitions

    SciTech Connect

    Jr, John T. Giblin; Price, Larry R.; Siemens, Xavier; Vlcek, Brian E-mail: larryp@caltech.edu E-mail: bvlcek@uwm.edu

    2012-11-01

    Global second-order phase transitions are expected to produce scale-invariant gravitational wave spectra. In this manuscript we explore the dynamics of a symmetry-breaking phase transition using lattice simulations. We explicitly calculate the stochastic gravitational wave background produced during the transition and subsequent self-ordering phase. We comment on this signal as it compares to the scale-invariant spectrum produced during inflation.

  15. Second order filter response with series coupled silica microresonators

    NASA Technical Reports Server (NTRS)

    Savchenkov, A.; Iitchenko, V. S.; Handley, T.; Maleki, L.

    2002-01-01

    We have demonstrated an approach for fabricating a photonic filter with second order response function. The filter consists of two germania-doped silica microtoroidal or microspherical resonators cascaded in series. We use UV irradiation to tune the mode of one microcavity to bring it close to the mode of the second microcavity. This approach produces a filter function with much sharper rolloff than can be obtained with the individual microresonators.

  16. athena: Tree code for second-order correlation functions

    NASA Astrophysics Data System (ADS)

    Kilbinger, Martin; Bonnett, Christopher; Coupon, Jean

    2014-02-01

    athena is a 2d-tree code that estimates second-order correlation functions from input galaxy catalogues. These include shear-shear correlations (cosmic shear), position-shear (galaxy-galaxy lensing) and position-position (spatial angular correlation). Written in C, it includes a power-spectrum estimator implemented in Python; this script also calculates the aperture-mass dispersion. A test data set is available.

  17. Second order parametric processes in nonlinear silica microspheres.

    PubMed

    Xu, Yong; Han, Ming; Wang, Anbo; Liu, Zhiwen; Heflin, James R

    2008-04-25

    We analyze second order parametric processes in a silica microsphere coated with radially aligned nonlinear optical molecules. In a high-Q nonlinear microsphere, we discover that it is possible to achieve ultralow threshold parametric oscillation that obeys the rule of angular momentum conservation. Based on symmetry considerations, one can also implement parametric processes that naturally generate quantum entangled photon pairs. Practical issues regarding implementation of the nonlinear microsphere are also discussed. PMID:18518201

  18. Second-order reconstruction of the inflationary potential

    NASA Technical Reports Server (NTRS)

    Liddle, Andrew R.; Turner, Michael S.

    1994-01-01

    To first order in the deviation from scale invariance the inflationary potential and its first two derivatives can be expressed in terms of the spectral indices of the scalar and tensor perturbations, n and n(sub T), and their contributions to the variance of the quadrupole CBR temperature anisotropy, S and T. In addition, there is a 'consistency relation' between these quantities: n(sub T) = (-1/ 7)(T/S). We derive the second-order expressions for the inflationary potential and its first two derivatives and the first-order expression for its third derivative, in terms, of n, n(sub T), S, T, and dn/d ln gamma. We also obtain the second-order consistency relation, n(sub T) = (-1/7)(T/S)(1 + 0.11(T/S) + 0.15(n-1)). As an example we consider the exponential potential, the only known case where exact analytic solutions for the perturbation spectra exist. We reconstruct the potential via Taylor expansion (with coefficients calculated at both first and second order), and introduce the Pade approximate as a greatly improved alternative.

  19. Free-Form Region Description with Second-Order Pooling.

    PubMed

    Carreira, João; Caseiro, Rui; Batista, Jorge; Sminchisescu, Cristian

    2015-06-01

    Semantic segmentation and object detection are nowadays dominated by methods operating on regions obtained as a result of a bottom-up grouping process (segmentation) but use feature extractors developed for recognition on fixed-form (e.g. rectangular) patches, with full images as a special case. This is most likely suboptimal. In this paper we focus on feature extraction and description over free-form regions and study the relationship with their fixed-form counterparts. Our main contributions are novel pooling techniques that capture the second-order statistics of local descriptors inside such free-form regions. We introduce second-order generalizations of average and max-pooling that together with appropriate non-linearities, derived from the mathematical structure of their embedding space, lead to state-of-the-art recognition performance in semantic segmentation experiments without any type of local feature coding. In contrast, we show that codebook-based local feature coding is more important when feature extraction is constrained to operate over regions that include both foreground and large portions of the background, as typical in image classification settings, whereas for high-accuracy localization setups, second-order pooling over free-form regions produces results superior to those of the winning systems in the contemporary semantic segmentation challenges, with models that are much faster in both training and testing. PMID:26357341

  20. Second-order (2 +1 ) -dimensional anisotropic hydrodynamics

    NASA Astrophysics Data System (ADS)

    Bazow, Dennis; Heinz, Ulrich; Strickland, Michael

    2014-11-01

    We present a complete formulation of second-order (2 +1 ) -dimensional anisotropic hydrodynamics. The resulting framework generalizes leading-order anisotropic hydrodynamics by allowing for deviations of the one-particle distribution function from the spheroidal form assumed at leading order. We derive complete second-order equations of motion for the additional terms in the macroscopic currents generated by these deviations from their kinetic definition using a Grad-Israel-Stewart 14-moment ansatz. The result is a set of coupled partial differential equations for the momentum-space anisotropy parameter, effective temperature, the transverse components of the fluid four-velocity, and the viscous tensor components generated by deviations of the distribution from spheroidal form. We then perform a quantitative test of our approach by applying it to the case of one-dimensional boost-invariant expansion in the relaxation time approximation (RTA) in which case it is possible to numerically solve the Boltzmann equation exactly. We demonstrate that the second-order anisotropic hydrodynamics approach provides an excellent approximation to the exact (0+1)-dimensional RTA solution for both small and large values of the shear viscosity.

  1. Non-Gaussianity from the second-order cosmological perturbation

    NASA Astrophysics Data System (ADS)

    Lyth, David H.; Rodríguez, Yeinzon

    2005-06-01

    Several conserved and/or gauge-invariant quantities described as the second-order curvature perturbation have been given in the literature. We revisit various scenarios for the generation of second-order non-Gaussianity in the primordial curvature perturbation ζ, employing for the first time a unified notation and focusing on the normalization fNL of the bispectrum. When ζ first appears a few Hubble times after horizon exit, |fNL| is much less than 1 and is, therefore, negligible. Thereafter ζ (and hence fNL) is conserved as long as the pressure is a unique function of energy density (adiabatic pressure). Nonadiabatic pressure comes presumably only from the effect of fields, other than the one pointing along the inflationary trajectory, which are light during inflation (“light noninflaton fields”). During single-component inflation fNL is constant, but multicomponent inflation might generate |fNL|˜1 or bigger. Preheating can affect fNL only in atypical scenarios where it involves light noninflaton fields. The simplest curvaton scenario typically gives fNL≪-1 or fNL=+5/4. The inhomogeneous reheating scenario can give a wide range of values for fNL. Unless there is a detection, observation can eventually provide a limit |fNL|≲1, at which level it will be crucial to calculate the precise observational limit using second-order theory.

  2. Dressed four-wave mixing second-order Talbot effect

    NASA Astrophysics Data System (ADS)

    Chen, Haixia; Zhang, Xun; Zhu, Dayu; Yang, Chang; Jiang, Tao; Zheng, Huaibin; Zhang, Yanpeng

    2014-10-01

    We theoretically demonstrate second-order Talbot effect (SOTE) based on entangled photon pairs. The photon pairs are generated from the spontaneous parametric four-wave mixing (SPFWM) process in a cold atomic medium and can be taken as the imaging light in order to realize coincidence recording. A strong standing wave is used to create the electromagnetically induced grating in the entangled photon pairs channels. By changing the frequency detuning of the standing wave or the other optical fields participating in the process, we can manipulate the contrast of the second-order Talbot image. We use the second-order correlation function and the dressed-state picture to explain the SOTE occurring in the SPFWM process. Moreover, we demonstrate the scheme for SOTE based on the spatially correlated twin beams generated from the SPFWM process with injection. This scheme provides a convenient detection proposal for the SOTE at the cost of the image contrast. Compared to the previous self-imaging schemes, the present schemes have the characteristic of controllable image contrast and of nonlocal imaging, and thus, they might broaden their applications in imaging techniques and find applications in quantum lithography.

  3. Carborane tuning on iridium complexes: redox-switchable second-order NLO responses.

    PubMed

    Wang, Jiao; Wang, Wen-Yong; Fang, Xin-Yan; Qiu, Yong-Qing

    2015-04-01

    Much effort has been devoted to investigating the molecular geometries, electronic structures, redox properties and nonlinear optical (NLO) properties of Ir complexes involving o-, m- or p-carborane groups by density functional theory (DFT) methods. Switchable second-order NLO properties were induced by redox processes involving these complexes, and it was found that mainly the coordination bonds of Ir complexes changed during the oxidation process. Our calculations revealed that oxidation reactions have a significant influence on the second-order NLO response owing to the change in charge transfer pattern. The β tot values of oxidized species are at least ∼9 times larger for set I and ∼5 times larger for set II than those of the corresponding parent complexes. Introduction of carborane groups into ppy (phenylpyridine) ligands can enhance the second-order NLO response by 1.2- 1.6 times by a metal-to-ligand charge transfer (MLCT) transition between the Ir atom and carborane. The β tot of complex 2 [(ppy)2Ir(phen)](+) (phen = phenanthroline) is 3.3 times larger than that of complex 1 (ppy)2Ir(acce) (acce = acetylacetonate), which is caused by ligand-to-ligand charge transfer (LLCT) between ppy ligands and the ancillary ligand. Therefore, it can be concluded that the second-order NLO response can be effectively enhanced by oxidation reactions. PMID:25791353

  4. Determination of robust stability margin for second-order systems

    NASA Technical Reports Server (NTRS)

    Chuang, C.-H.; Kau, C.-T.; Juang, Jer-Nan

    1992-01-01

    Robust stabilization of uncertain systems has been extensively investigated and the stability test for the whole set of uncertain parameters has been reduced to a finite number of test points, four points for the characteristic polynomial with independent coefficients. As a result the robust stability margin can be determined using a reasonable amount of computation. It is impossible to apply the results of the test to a practical system as the coefficients of the characteristic polynomial for a physical system are usually functions of uncertain parameters. However, many physical systems may be represented by a second-order mass-spring-damper system with a special multilinear form in its characteristic polynomial. This paper investigates second-order mass-spring-damper systems and the reduction of the number of test points. It is shown that such a system with arbritrary compensators always has a multilinear characteristic polynomial. It is also shown that a line in the two-dimensional parameter space forms the boundary after the mapping of a multilinear characteristic polynomial and this interior extreme line forms a conic curve in the complex plane. The boundary of uncertain domain for a multilinear polynomial with two uncertainty parameters can be determined analytically using this curve, and the four sides image of a square of the uncertain parameter. Therefore, the stability margin may be determined by checking the intersections of the boundary with the zero point. A similar procedure can be used for second-order systems with more than two uncertainty parameters when parameter optimization is used in determining the boundary.

  5. Superquadric glyphs for symmetric second-order tensors.

    PubMed

    Schultz, Thomas; Kindlmann, Gordon L

    2010-01-01

    Symmetric second-order tensor fields play a central role in scientific and biomedical studies as well as in image analysis and feature-extraction methods. The utility of displaying tensor field samples has driven the development of visualization techniques that encode the tensor shape and orientation into the geometry of a tensor glyph. With some exceptions, these methods work only for positive-definite tensors (i.e. having positive eigenvalues, such as diffusion tensors). We expand the scope of tensor glyphs to all symmetric second-order tensors in two and three dimensions, gracefully and unambiguously depicting any combination of positive and negative eigenvalues. We generalize a previous method of superquadric glyphs for positive-definite tensors by drawing upon a larger portion of the superquadric shape space, supplemented with a coloring that indicates the quadratic form (including eigenvalue sign). We show that encoding arbitrary eigenvalue magnitudes requires design choices that differ fundamentally from those in previous work on traceless tensors that arise in the study of liquid crystals. Our method starts with a design of 2-D tensor glyphs guided by principles of scale-preservation and symmetry, and creates 3-D glyphs that include the 2-D glyphs in their axis-aligned cross-sections. A key ingredient of our method is a novel way of mapping from the shape space of three-dimensional symmetric second-order tensors to the unit square. We apply our new glyphs to stress tensors from mechanics, geometry tensors and Hessians from image analysis, and rate-of-deformation tensors in computational fluid dynamics. PMID:20975202

  6. Detection of a diffusive cloak via second-order statistics

    NASA Astrophysics Data System (ADS)

    Koirala, Milan; Yamilov, Alexey

    2016-08-01

    We propose a scheme to detect the diffusive cloak proposed by Schittny et al [Science 345, 427 (2014)]. We exploit the fact that diffusion of light is an approximation that disregards wave interference. The long-range contribution to intensity correlation is sensitive to locations of paths crossings and the interference inside the medium, allowing one to detect the size and position, including the depth, of the diffusive cloak. Our results also suggest that it is possible to separately manipulate the first- and the second-order statistics of wave propagation in turbid media.

  7. Slowly rotating scalar field wormholes: The second order approximation

    SciTech Connect

    Kashargin, P. E.; Sushkov, S. V.

    2008-09-15

    We discuss rotating wormholes in general relativity with a scalar field with negative kinetic energy. To solve the problem, we use the assumption about slow rotation. The role of a small dimensionless parameter plays the ratio of the linear velocity of rotation of the wormhole's throat and the velocity of light. We construct the rotating wormhole solution in the second-order approximation with respect to the small parameter. The analysis shows that the asymptotical mass of the rotating wormhole is greater than that of the nonrotating one, and the null energy condition violation in the rotating wormhole spacetime is weaker than that in the nonrotating one.

  8. Detection of a diffusive cloak via second-order statistics.

    PubMed

    Koirala, Milan; Yamilov, Alexey

    2016-08-15

    We propose a scheme to detect the diffusive cloak proposed by Schittny et al. [Science345, 427 (2014).SCIEAS0036-807510.1126/science.1254524]. We exploit the fact that diffusion of light is an approximation that disregards wave interference. The long-range contribution to intensity correlation is sensitive to the locations of path crossings and the interference inside the medium, allowing one to detect the size and position, including the depth, of the diffusive cloak. Our results also suggest that it is possible to separately manipulate the first- and the second-order statistics of wave propagation in turbid media. PMID:27519108

  9. Stochastic systems with delay: Perturbation theory for second order statistics

    NASA Astrophysics Data System (ADS)

    Frank, T. D.

    2016-03-01

    Within the framework of delay Fokker-Planck equations, a perturbation theoretical method is developed to determine second-order statistical quantities such as autocorrelation functions for stochastic systems with delay. Two variants of the perturbation theoretical approach are presented. The first variant is based on a non-local Fokker-Planck operator. The second variant requires to solve a Fokker-Planck equation with source term. It is shown that the two variants yield consistent results. The perturbation theoretical approaches are applied to study negative autocorrelations that are induced by feedback delays and mediated by the strength of the fluctuating forces that act on the feedback systems.

  10. Supersonic second order analysis and optimization program user's manual

    NASA Technical Reports Server (NTRS)

    Clever, W. C.

    1984-01-01

    Approximate nonlinear inviscid theoretical techniques for predicting aerodynamic characteristics and surface pressures for relatively slender vehicles at supersonic and moderate hypersonic speeds were developed. Emphasis was placed on approaches that would be responsive to conceptual configuration design level of effort. Second order small disturbance theory was utilized to meet this objective. Numerical codes were developed for analysis and design of relatively general three dimensional geometries. Results from the computations indicate good agreement with experimental results for a variety of wing, body, and wing-body shapes. Case computational time of one minute on a CDC 176 are typical for practical aircraft arrangement.

  11. Second-order kinetic Kohn-Sham lattice model

    NASA Astrophysics Data System (ADS)

    Solórzano, S.; Mendoza, M.; Herrmann, H. J.

    2016-06-01

    In this work, we introduce a semi-implicit second-order correction scheme to the kinetic Kohn-Sham lattice model. This approach is validated by performing realistic exchange-correlation energy calculations of atoms and dimers of the first two rows of the Periodic Table, finding good agreement with the expected values. Additionally, we simulate the ethane molecule, where we recover the bond lengths and compare the results with standard methods. Finally, we discuss the current applicability of pseudopotentials within the lattice kinetic Kohn-Sham approach.

  12. P-stable boundary value methods for second order IVPs

    NASA Astrophysics Data System (ADS)

    Aceto, Lidia; Ghelardoni, Paolo; Magherini, Cecilia

    2012-09-01

    We introduce a family of Linear Multistep Methods used as Boundary Value Methods for the numerical solution of initial value problems for second order ordinary differential equations of special type. The aim is to obtain P-stable methods with arbitrary order of accuracy. This result allows to overcome the order barrier established by Lambert and Watson which limited to p = 2 the maximum order of a P-stable Linear Multistep Method. In addition, an extension of the methods in the Exponential Fitting framework is also considered.

  13. A second-order impact model for forest fire regimes.

    PubMed

    Maggi, Stefano; Rinaldi, Sergio

    2006-09-01

    We present a very simple "impact" model for the description of forest fires and show that it can mimic the known characteristics of wild fire regimes in savannas, boreal forests, and Mediterranean forests. Moreover, the distribution of burned biomasses in model generated fires resemble those of burned areas in numerous large forests around the world. The model has also the merits of being the first second-order model for forest fires and the first example of the use of impact models in the study of ecosystems. PMID:16723147

  14. A-posteriori error estimation for second order mechanical systems

    NASA Astrophysics Data System (ADS)

    Ruiner, Thomas; Fehr, Jörg; Haasdonk, Bernard; Eberhard, Peter

    2012-06-01

    One important issue for the simulation of flexible multibody systems is the reduction of the flexible bodies degrees of freedom. As far as safety questions are concerned knowledge about the error introduced by the reduction of the flexible degrees of freedom is helpful and very important. In this work, an a-posteriori error estimator for linear first order systems is extended for error estimation of mechanical second order systems. Due to the special second order structure of mechanical systems, an improvement of the a-posteriori error estimator is achieved. A major advantage of the a-posteriori error estimator is that the estimator is independent of the used reduction technique. Therefore, it can be used for moment-matching based, Gramian matrices based or modal based model reduction techniques. The capability of the proposed technique is demonstrated by the a-posteriori error estimation of a mechanical system, and a sensitivity analysis of the parameters involved in the error estimation process is conducted.

  15. Second-order modeling of arsenite transport in soils

    NASA Astrophysics Data System (ADS)

    Zhang, Hua; Magdi Selim, H.

    2011-11-01

    Rate limited processes including kinetic adsorption-desorption can greatly impact the fate and behavior of toxic arsenic compounds in heterogeneous soils. In this study, miscible displacement column experiments were carried out to investigate the extent of reactivity during transport of arsenite in soils. Arsenite breakthrough curves (BTCs) of Olivier and Windsor soils exhibited strong retardation with diffusive effluent fronts followed by slow release or tailing during leaching. Such behavior is indicative of the dominance of kinetic retention reactions for arsenite transport in the soil columns. Sharp decrease or increase in arsenite concentration in response to flow interruptions (stop-flow) further verified that non-equilibrium conditions are dominant. After some 40-60 pore volumes of continued leaching, 30-70% of the applied arsenite was retained by the soil in the columns. Furthermore, continued arsenite slow release for months was evident by the high levels of residual arsenite concentrations observed during leaching. In contrast, arsenite transport in a reference sand material exhibited no retention where complete mass recovery in the effluent solution was attained. A second-order model (SOM) which accounts for equilibrium, reversible, and irreversible retention mechanisms was utilized to describe arsenite transport results from the soil columns. Based on inverse and predictive modeling results, the SOM model successfully depicted arsenite BTCs from several soil columns. Based on inverse and predictive modeling results, a second-order model which accounts for kinetic reversible and irreversible reactions is recommended for describing arsenite transport in soils.

  16. Natural Constraints to Species Diversification

    PubMed Central

    Lewitus, Eric; Morlon, Hélène

    2016-01-01

    Identifying modes of species diversification is fundamental to our understanding of how biodiversity changes over evolutionary time. Diversification modes are captured in species phylogenies, but characterizing the landscape of diversification has been limited by the analytical tools available for directly comparing phylogenetic trees of groups of organisms. Here, we use a novel, non-parametric approach and 214 family-level phylogenies of vertebrates representing over 500 million years of evolution to identify major diversification modes, to characterize phylogenetic space, and to evaluate the bounds and central tendencies of species diversification. We identify five principal patterns of diversification to which all vertebrate families hold. These patterns, mapped onto multidimensional space, constitute a phylogenetic space with distinct properties. Firstly, phylogenetic space occupies only a portion of all possible tree space, showing family-level phylogenies to be constrained to a limited range of diversification patterns. Secondly, the geometry of phylogenetic space is delimited by quantifiable trade-offs in tree size and the heterogeneity and stem-to-tip distribution of branching events. These trade-offs are indicative of the instability of certain diversification patterns and effectively bound speciation rates (for successful clades) within upper and lower limits. Finally, both the constrained range and geometry of phylogenetic space are established by the differential effects of macroevolutionary processes on patterns of diversification. Given these properties, we show that the average path through phylogenetic space over evolutionary time traverses several diversification stages, each of which is defined by a different principal pattern of diversification and directed by a different macroevolutionary process. The identification of universal patterns and natural constraints to diversification provides a foundation for understanding the deep-time evolution of

  17. Natural Constraints to Species Diversification.

    PubMed

    Lewitus, Eric; Morlon, Hélène

    2016-08-01

    Identifying modes of species diversification is fundamental to our understanding of how biodiversity changes over evolutionary time. Diversification modes are captured in species phylogenies, but characterizing the landscape of diversification has been limited by the analytical tools available for directly comparing phylogenetic trees of groups of organisms. Here, we use a novel, non-parametric approach and 214 family-level phylogenies of vertebrates representing over 500 million years of evolution to identify major diversification modes, to characterize phylogenetic space, and to evaluate the bounds and central tendencies of species diversification. We identify five principal patterns of diversification to which all vertebrate families hold. These patterns, mapped onto multidimensional space, constitute a phylogenetic space with distinct properties. Firstly, phylogenetic space occupies only a portion of all possible tree space, showing family-level phylogenies to be constrained to a limited range of diversification patterns. Secondly, the geometry of phylogenetic space is delimited by quantifiable trade-offs in tree size and the heterogeneity and stem-to-tip distribution of branching events. These trade-offs are indicative of the instability of certain diversification patterns and effectively bound speciation rates (for successful clades) within upper and lower limits. Finally, both the constrained range and geometry of phylogenetic space are established by the differential effects of macroevolutionary processes on patterns of diversification. Given these properties, we show that the average path through phylogenetic space over evolutionary time traverses several diversification stages, each of which is defined by a different principal pattern of diversification and directed by a different macroevolutionary process. The identification of universal patterns and natural constraints to diversification provides a foundation for understanding the deep-time evolution of

  18. Second-Order Systematicity of Associative Learning: A Paradox for Classical Compositionality and a Coalgebraic Resolution

    PubMed Central

    Phillips, Steven; Wilson, William H.

    2016-01-01

    Systematicity is a property of cognitive architecture whereby having certain cognitive capacities implies having certain other “structurally related” cognitive capacities. The predominant classical explanation for systematicity appeals to a notion of common syntactic/symbolic structure among the systematically related capacities. Although learning is a (second-order) cognitive capacity of central interest to cognitive science, a systematic ability to learn certain cognitive capacities, i.e., second-order systematicity, has been given almost no attention in the literature. In this paper, we introduce learned associations as an instance of second-order systematicity that poses a paradox for classical theory, because this form of systematicity involves the kinds of associative constructions that were explicitly rejected by the classical explanation. Our category theoretic explanation of systematicity resolves this problem, because both first and second-order forms of systematicity are derived from the same categorical construction: universal morphisms, which generalize the notion of compositionality of constituent representations to (categorical) compositionality of constituent processes. We derive a model of systematic associative learning based on (co)recursion, which is an instance of a universal construction. These results provide further support for a category theory foundation for cognitive architecture. PMID:27505411

  19. Second-Order Systematicity of Associative Learning: A Paradox for Classical Compositionality and a Coalgebraic Resolution.

    PubMed

    Phillips, Steven; Wilson, William H

    2016-01-01

    Systematicity is a property of cognitive architecture whereby having certain cognitive capacities implies having certain other "structurally related" cognitive capacities. The predominant classical explanation for systematicity appeals to a notion of common syntactic/symbolic structure among the systematically related capacities. Although learning is a (second-order) cognitive capacity of central interest to cognitive science, a systematic ability to learn certain cognitive capacities, i.e., second-order systematicity, has been given almost no attention in the literature. In this paper, we introduce learned associations as an instance of second-order systematicity that poses a paradox for classical theory, because this form of systematicity involves the kinds of associative constructions that were explicitly rejected by the classical explanation. Our category theoretic explanation of systematicity resolves this problem, because both first and second-order forms of systematicity are derived from the same categorical construction: universal morphisms, which generalize the notion of compositionality of constituent representations to (categorical) compositionality of constituent processes. We derive a model of systematic associative learning based on (co)recursion, which is an instance of a universal construction. These results provide further support for a category theory foundation for cognitive architecture. PMID:27505411

  20. Magnetic Compensation for Second-Order Doppler Shift in LITS

    NASA Technical Reports Server (NTRS)

    Burt, Eric; Tjoelker, Robert

    2008-01-01

    The uncertainty in the frequency of a linear-ion-trap frequency standard (LITS) can be reduced substantially by use of a very small magnetic inhomogeneity tailored to compensate for the residual second-order Doppler shift. An effect associated with the relativistic time dilatation, one cause of the second-order Doppler shift, is ion motion that is attributable to the trapping radio-frequency (RF)electromagnetic field used to trap ions. The second-order Doppler shift is reduced by using a multi-pole trap; however it is still the largest source of systematic frequency shift in the latest generation of LITSs, which are among the most stable clocks in the world. The present compensation scheme reduces the frequency instability of the affected LITS to about a tenth of its previous value. The basic principles of prior generation LITSs were discussed in several prior NASA Tech Briefs articles. Below are recapitulated only those items of basic information necessary to place the present development in context. A LITS includes a microwave local oscillator, the frequency of which is stabilized by comparison with the frequency of the ground state hyperfine transition of 199Hg+ ions. The comparison involves a combination of optical and microwave excitation and interrogation of the ions in a linear ion trap in the presence of a nominally uniform magnetic field. In the current version of the LITS, there are two connected traps (see figure): (1) a quadrupole trap wherein the optical excitation and measurement take place and (2) a 12-pole trap (denoted the resonance trap), wherein the microwave interrogation takes place. The ions are initially loaded into the quadrupole trap and are thereafter shuttled between the two traps. Shuttling ions into the resonance trap allows sensitive microwave interrogation to take place well away from loading interference. The axial magnetic field for the resonance trap is generated by an electric current in a finely wound wire coil surrounded by

  1. A new approach for second-order perturbation theory.

    PubMed

    Tomlinson, David G; Asadchev, Andrey; Gordon, Mark S

    2016-05-30

    A new second-order perturbation theory (MP2) approach is presented for closed shell energy evaluations. The new algorithm has a significantly lower memory footprint, a lower FLOP (floating point operations) count, and a lower time to solution compared to previously implemented parallel MP2 methods in the GAMESS software package. Additionally, this algorithm features an adaptive approach for the disk/distributed memory storage of the MP2 amplitudes. The algorithm works well on a single workstation, small cluster, and large Cray cluster, and it allows one to perform large calculations with thousands of basis functions in a matter of hours on a single workstation. The same algorithm has been adapted for graphical processing unit (GPU) architecture. The performance of the new GPU algorithm is also discussed. © 2016 Wiley Periodicals, Inc. PMID:26940648

  2. Absorbing boundary conditions for second-order hyperbolic equations

    NASA Technical Reports Server (NTRS)

    Jiang, Hong; Wong, Yau Shu

    1989-01-01

    A uniform approach to construct absorbing artificial boundary conditions for second-order linear hyperbolic equations is proposed. The nonlocal boundary condition is given by a pseudodifferential operator that annihilates travelling waves. It is obtained through the dispersion relation of the differential equation by requiring that the initial-boundary value problem admits the wave solutions travelling in one direction only. Local approximation of this global boundary condition yields an nth-order differential operator. It is shown that the best approximations must be in the canonical forms which can be factorized into first-order operators. These boundary conditions are perfectly absorbing for wave packets propagating at certain group velocities. A hierarchy of absorbing boundary conditions is derived for transonic small perturbation equations of unsteady flows. These examples illustrate that the absorbing boundary conditions are easy to derive, and the effectiveness is demonstrated by the numerical experiments.

  3. Compact Two-State-Variable Second-Order Memristor Model.

    PubMed

    Kim, Sungho; Kim, Hee-Dong; Choi, Sung-Jin

    2016-06-01

    A key requirement for using memristors in functional circuits is a predictive physical model to capture the resistive switching behavior, which shall be compact enough to be implemented using a circuit simulator. Although a number of memristor models have been developed, most of these models (i.e., first-order memristor models) have utilized only a one-state-variable. However, such simplification is not adequate for accurate modeling because multiple mechanisms are involved in resistive switching. Here, a two-state-variable based second-order memristor model is presented, which considers the axial drift of the charged vacancies in an applied electric field and the radial vacancy motion caused by the thermophoresis and diffusion. In particular, this model emulates the details of the intrinsic short-term dynamics, such as decay and temporal heat summation, and therefore, it accurately predicts the resistive switching characteristics for both DC and AC input signals. PMID:27152649

  4. K-inflationary power spectra at second order

    SciTech Connect

    Martin, Jérôme; Vennin, Vincent; Ringeval, Christophe E-mail: christophe.ringeval@uclouvain.be

    2013-06-01

    Within the class of inflationary models, k-inflation represents the most general single field framework that can be associated with an effective quadratic action for the curvature perturbations and a varying speed of sound. The incoming flow of high-precision cosmological data, such as those from the Planck satellite and small scale Cosmic Microwave Background (CMB) experiments, calls for greater accuracy in the inflationary predictions. In this work, we calculate for the first time the next-to-next-to-leading order scalar and tensor primordial power spectra in k-inflation needed in order to obtain robust constraints on the inflationary theory. The method used is the uniform approximation together with a second order expansion in the Hubble and sound flow functions. Our result is checked in various limits in which it reduces to already known situations.

  5. Second-Order Nonlinear Optical Imaging of Chiral Crystals

    PubMed Central

    Kissick, David J.; Wanapun, Debbie; Simpson, Garth J.

    2012-01-01

    Second-order nonlinear optical imaging of chiral crystals (SONICC) is an emerging technique for crystal imaging and characterization. We provide a brief overview of the origin of second harmonic generation signals in SONICC and discuss recent studies using SONICC for biological applications. Given that they provide near-complete suppression of any background, SONICC images can be used to determine the presence or absence of protein crystals through both manual inspection and automated analysis. Because SONICC creates high-resolution images, nucleation and growth kinetics can also be observed. SONICC can detect metastable, homochiral crystalline forms of amino acids crystallizing from racemic solutions, which confirms Ostwald’s rule of stages for crystal growth. SONICC’s selectivity, based on order, and sensitivity, based on background suppression, make it a promising technique for numerous fields concerned with chiral crystal formation. PMID:21469954

  6. Absorbing boundary conditions for second-order hyperbolic equations

    NASA Technical Reports Server (NTRS)

    Jiang, Hong; Wong, Yau Shu

    1990-01-01

    A uniform approach to construct absorbing artificial boundary conditions for second-order linear hyperbolic equations is proposed. The nonlocal boundary condition is given by a pseudodifferential operator that annihilates travelling waves. It is obtained through the dispersion relation of the differential equation by requiring that the initial-boundary value problem admits the wave solutions travelling in one direction only. Local approximation of this global boundary condition yields an nth-order differential operator. It is shown that the best approximations must be in the canonical forms which can be factorized into first-order operators. These boundary conditions are perfectly absorbing for wave packets propagating at certain group velocities. A hierarchy of absorbing boundary conditions is derived for transonic small perturbation equations of unsteady flows. These examples illustrate that the absorbing boundary conditions are easy to derive, and the effectiveness is demonstrated by the numerical experiments.

  7. Second-Order Fermi Acceleration and Emission in Blazar Jets

    NASA Astrophysics Data System (ADS)

    Asano, Katsuaki; Takahara, Fumio; Toma, Kenji; Kusunose, Masaaki; Kakuwa, Jun

    The second-order Fermi acceleration (Fermi-II) driven by turbulence may be responsible for the electron acceleration in blazar jets. We test this model with time-dependent simulations, adopt it for 1ES 1101-232, and Mrk 421. The Fermi-II model with radial evolution of the electron injection rate and/or diffusion coefficient can reproduce the spectra from the radio to the gamma-ray regime. For Mrk 421, an external radio photon field with a luminosity of 4.9 begin{math} {times} 10 (38) erg s (-1) is required to agree with the observed GeV flux. The temporal variability of the diffusion coefficient or injection rate causes flare emission. The observed synchronicity of X-ray and TeV flares implies a decrease of the magnetic field in the flaring source region.

  8. New implicitly solvable potential produced by second order shape invariance

    SciTech Connect

    Cannata, F.; Ioffe, M.V.; Kolevatova, E.V.; Nishnianidze, D.N.

    2015-05-15

    The procedure proposed recently by Bougie et al. (2010) to study the general form of shape invariant potentials in one-dimensional Supersymmetric Quantum Mechanics (SUSY QM) is generalized to the case of Higher Order SUSY QM with supercharges of second order in momentum. A new shape invariant potential is constructed by this method. It is singular at the origin, it grows at infinity, and its spectrum depends on the choice of connection conditions in the singular point. The corresponding Schrödinger equation is solved explicitly: the wave functions are constructed analytically, and the energy spectrum is defined implicitly via the transcendental equation which involves Confluent Hypergeometric functions. - Highlights: • New potential with 2nd order irreducible shape invariance was constructed. • The connection conditions at the singularity of potential were obtained. • The explicit expressions for all wave functions were derived. • The implicit equation for the energy spectrum was obtained.

  9. Pump power dependence of second order correlation in nondegenerate SPDC

    NASA Astrophysics Data System (ADS)

    Kim, Charles; Kanner, Gary

    2009-08-01

    We observed the second order correlation peak for nondegenerate spontaneous parametric down conversion (SPDC) of a pulsed pump at 532 nm into 810 nm and 1550 nm entangled beams. We used a Si avalanche photodiode (APD) to detect the 810 nm photons, and an InGaAs APD to detect those at 1550 nm. We defined both a visibility and signal-to-noise ratio (SNR) based on the data, which were obtained at various pump powers. In contrast to classical imaging systems, for which SNR increases monotonically with transmitted power, the SNR for the correlation peak in our setup exhibited a gradual decay as the pump power increased. We derived an empirical relation for the SNR, which was inversely proportional to the square root of pump power.

  10. Second-order UV contamination in astronomical spectra

    NASA Astrophysics Data System (ADS)

    Gutierrez-Moreno, A.; Heathcote, S.; Moreno, H.; Hamuy, M.

    1994-11-01

    Observations of the planetary nebula Me 2-1 are used to discuss some effects of contamination produced by the second-order ultraviolet spectrum in the first-order red, longer than approximately 6200 A. It is found that this contamination is present with some instrumental setups, and that the contaminating lines are displaced in wavelength with respect to the predictions from diffraction theory by an amount which varies slightly for different setups. From the theoretical and empirical analysis of these displacements, it is concluded that the shift in wavelength is due to the presence of chromatic difference in magnification in spectrograph cameras including any transmission element, as in the case in the semi-solid Schmidt-Cassegrain cameras used in our observations.

  11. Relativistic quantum transport coefficients for second-order viscous hydrodynamics

    NASA Astrophysics Data System (ADS)

    Florkowski, Wojciech; Jaiswal, Amaresh; Maksymiuk, Ewa; Ryblewski, Radoslaw; Strickland, Michael

    2015-05-01

    We express the transport coefficients appearing in the second-order evolution equations for bulk viscous pressure and shear stress tensor using Bose-Einstein, Boltzmann, and Fermi-Dirac statistics for the equilibrium distribution function and Grad's 14-moment approximation as well as the method of Chapman-Enskog expansion for the nonequilibrium part. Focusing on the case of transversally homogeneous and boost-invariant longitudinal expansion of the viscous medium, we compare the results obtained using the above methods with those obtained from the exact solution of the massive 0+1 d relativistic Boltzmann equation in the relaxation-time approximation. We show that compared to the 14-moment approximation, the hydrodynamic transport coefficients obtained by employing the Chapman-Enskog method lead to better agreement with the exact solution of the relativistic Boltzmann equation.

  12. Gravitational Microlensing by Ellis Wormhole: Second Order Effects

    NASA Astrophysics Data System (ADS)

    Lukmanova, Regina; Kulbakova, Aliya; Izmailov, Ramil; Potapov, Alexander A.

    2016-07-01

    Gravitational lensing is the effect of light bending in a gravitational field. It can be used as a possible observational method to detect or exclude the existence of wormholes. In this work, we extend the work by Abe on gravitational microlensing by Ellis wormhole by including the second order deflection term. Using the lens equation and definition of Einstein radius, we find the angular locations of the physical image inside and outside Einstein ring. The work contains a comparative analysis of light curves between the Schwarzschild black hole and the Ellis wormhole that can be used to distinguish such objects though such distinctions are too minute to be observable even in the near future. We also tabulate the optical depth and event rate for lensing by bulge and Large Magellanic Cloud (LMC) stars.

  13. Invariant classification of second-order conformally flat superintegrable systems

    NASA Astrophysics Data System (ADS)

    Capel, J. J.; Kress, J. M.

    2014-12-01

    In this paper we continue the work of Kalnins et al in classifying all second-order conformally-superintegrable (Laplace-type) systems over conformally flat spaces, using tools from algebraic geometry and classical invariant theory. The results obtained show, through Stäckel equivalence, that the list of known nondegenerate superintegrable systems over three-dimensional conformally flat spaces is complete. In particular, a seven-dimensional manifold is determined such that each point corresponds to a conformal class of superintegrable systems. This manifold is foliated by the nonlinear action of the conformal group in three dimensions. Two systems lie in the same conformal class if and only if they lie in the same leaf of the foliation. This foliation is explicitly described using algebraic varieties formed from representations of the conformal group. The proof of these results rely heavily on Gröbner basis calculations using the computer algebra software packages Maple and Singular.

  14. WEAK GALERKIN METHODS FOR SECOND ORDER ELLIPTIC INTERFACE PROBLEMS.

    PubMed

    Mu, Lin; Wang, Junping; Wei, Guowei; Ye, Xiu; Zhao, Shan

    2013-10-01

    Weak Galerkin methods refer to general finite element methods for partial differential equations (PDEs) in which differential operators are approximated by their weak forms as distributions. Such weak forms give rise to desirable flexibilities in enforcing boundary and interface conditions. A weak Galerkin finite element method (WG-FEM) is developed in this paper for solving elliptic PDEs with discontinuous coefficients and interfaces. Theoretically, it is proved that high order numerical schemes can be designed by using the WG-FEM with polynomials of high order on each element. Extensive numerical experiments have been carried to validate the WG-FEM for solving second order elliptic interface problems. High order of convergence is numerically confirmed in both L 2 and L ∞ norms for the piecewise linear WG-FEM. Special attention is paid to solve many interface problems, in which the solution possesses a certain singularity due to the nonsmoothness of the interface. A challenge in research is to design nearly second order numerical methods that work well for problems with low regularity in the solution. The best known numerical scheme in the literature is of order [Formula: see text] to [Formula: see text] for the solution itself in L ∞ norm. It is demonstrated that the WG-FEM of the lowest order, i.e., the piecewise constant WG-FEM, is capable of delivering numerical approximations that are of order [Formula: see text] to [Formula: see text] in the L ∞ norm for C (1) or Lipschitz continuous interfaces associated with a C (1) or H (2) continuous solution. PMID:24072935

  15. Second order closure modeling of turbulent buoyant wall plumes

    NASA Technical Reports Server (NTRS)

    Zhu, Gang; Lai, Ming-Chia; Shih, Tsan-Hsing

    1992-01-01

    Non-intrusive measurements of scalar and momentum transport in turbulent wall plumes, using a combined technique of laser Doppler anemometry and laser-induced fluorescence, has shown some interesting features not present in the free jet or plumes. First, buoyancy-generation of turbulence is shown to be important throughout the flow field. Combined with low-Reynolds-number turbulence and near-wall effect, this may raise the anisotropic turbulence structure beyond the prediction of eddy-viscosity models. Second, the transverse scalar fluxes do not correspond only to the mean scalar gradients, as would be expected from gradient-diffusion modeling. Third, higher-order velocity-scalar correlations which describe turbulent transport phenomena could not be predicted using simple turbulence models. A second-order closure simulation of turbulent adiabatic wall plumes, taking into account the recent progress in scalar transport, near-wall effect and buoyancy, is reported in the current study to compare with the non-intrusive measurements. In spite of the small velocity scale of the wall plumes, the results showed that low-Reynolds-number correction is not critically important to predict the adiabatic cases tested and cannot be applied beyond the maximum velocity location. The mean and turbulent velocity profiles are very closely predicted by the second-order closure models. but the scalar field is less satisfactory, with the scalar fluctuation level underpredicted. Strong intermittency of the low-Reynolds-number flow field is suspected of these discrepancies. The trends in second- and third-order velocity-scalar correlations, which describe turbulent transport phenomena, are also predicted in general, with the cross-streamwise correlations better than the streamwise one. Buoyancy terms modeling the pressure-correlation are shown to improve the prediction slightly. The effects of equilibrium time-scale ratio and boundary condition are also discussed.

  16. Disformal invariance of second order scalar-tensor theories: Framing the Horndeski action

    NASA Astrophysics Data System (ADS)

    Bettoni, Dario; Liberati, Stefano

    2013-10-01

    The Horndeski action is the most general one involving a metric and a scalar field that leads to second-order field equations in four dimensions. Being the natural extension of the well-known scalar-tensor theories, its structure and properties are worth analyzing along the experience accumulated in the latter context. Here, we argue that disformal transformations play, for the Horndeski theory, a similar role to that of conformal transformations for scalar-tensor theories a là Brans-Dicke. We identify the most general transformation preserving second-order field equations and discuss the issue of viable frames for this kind of theory, in particular, the possibility to cast the action in the so-called Einstein frame. Interestingly, we find that only for a subset of the Horndeski Lagrangian such a frame exists. Finally, we investigate the transformation properties of such frames under field redefinitions and frame transformations and their reciprocal relationship.

  17. Ninth order block hybrid collocation method for second order ordinary differential equations

    NASA Astrophysics Data System (ADS)

    Yap, Lee Ken; Ismail, Fudziah

    2016-02-01

    A ninth order block hybrid collocation method is proposed for solving general second order ordinary differential equations directly. The derivation involves interpolation and collocation of basic polynomial that generates the main and additional methods. These methods are applied simultaneously to provide approximate solutions at five main points and three off-step points. The stability properties of the block method are discussed. Some illustrative examples are given to demonstrate the efficiency of the method.

  18. Interval oscillation criteria for second-order forced impulsive delay differential equations with damping term.

    PubMed

    Thandapani, Ethiraju; Kannan, Manju; Pinelas, Sandra

    2016-01-01

    In this paper, we present some sufficient conditions for the oscillation of all solutions of a second order forced impulsive delay differential equation with damping term. Three factors-impulse, delay and damping that affect the interval qualitative properties of solutions of equations are taken into account together. The results obtained in this paper extend and generalize some of the the known results for forced impulsive differential equations. An example is provided to illustrate the main result. PMID:27218008

  19. Cavity-Enhanced Second-Order Nonlinear Photonic Logic Circuits

    NASA Astrophysics Data System (ADS)

    Trivedi, Rahul; Khankhoje, Uday K.; Majumdar, Arka

    2016-05-01

    A large obstacle for realizing photonic logic is the weak optical nonlinearity of available materials, which results in large power consumption. In this paper, we present the theoretical design of all-optical logic with second-order (χ(2 )) nonlinear bimodal cavities and their networks. Using semiclassical models derived from the Wigner quasiprobability distribution function, we analyze the power consumption and signal-to-noise ratio (SNR) of networks implementing an optical and gate and an optical latch. A comparison between the second- and third-order (χ(3 )) optical logic reveals that, while the χ(3 ) design outperforms the χ(2 ) design in terms of the SNR for the same input power, employing the χ(3 ) nonlinearity necessitates the use of cavities with ultrahigh-quality factors (Q ˜106) to achieve a gate power consumption comparable to that of the χ(2 ) design at significantly smaller quality factors (Q ˜104). Using realistic estimates of the χ(2 ) and χ(3 ) nonlinear susceptibilities of available materials, we show that, at achievable quality factors (Q ˜104), the χ(2 ) design is an order of magnitude more energy efficient than the corresponding χ(3 ) design.

  20. Second order sliding mode control for a quadrotor UAV.

    PubMed

    Zheng, En-Hui; Xiong, Jing-Jing; Luo, Ji-Liang

    2014-07-01

    A method based on second order sliding mode control (2-SMC) is proposed to design controllers for a small quadrotor UAV. For the switching sliding manifold design, the selection of the coefficients of the switching sliding manifold is in general a sophisticated issue because the coefficients are nonlinear. In this work, in order to perform the position and attitude tracking control of the quadrotor perfectly, the dynamical model of the quadrotor is divided into two subsystems, i.e., a fully actuated subsystem and an underactuated subsystem. For the former, a sliding manifold is defined by combining the position and velocity tracking errors of one state variable, i.e., the sliding manifold has two coefficients. For the latter, a sliding manifold is constructed via a linear combination of position and velocity tracking errors of two state variables, i.e., the sliding manifold has four coefficients. In order to further obtain the nonlinear coefficients of the sliding manifold, Hurwitz stability analysis is used to the solving process. In addition, the flight controllers are derived by using Lyapunov theory, which guarantees that all system state trajectories reach and stay on the sliding surfaces. Extensive simulation results are given to illustrate the effectiveness of the proposed control method. PMID:24751475

  1. The motion of ellipsoids in a second order fluid

    NASA Astrophysics Data System (ADS)

    Kim, S.

    1985-09-01

    The rigid body motion of an ellipsoid in a second order fluid (SOF) under the action of specified (time independent) external forces and torques have been obtained to first order in the Weissenberg number by inverting the resistance relations for the force an torque under specified rigid body motions. The reciprocal theorem of Lorentz was used to bypass the calculation of the O(W) velocity field. The results agree with known analytic solutions for SOF with the secondary to primary normal stress ratio of -1/2. The solution procedure was also tested by computing the torque on a translating prolate spheroid with aspect ratios ranging from slender bodies to near-spheres. One result is that for a SOF with zero secondary normal stress (Weissenberg fluid), previous asymptotic results for near-spheres were found to be accurate even at fairly large aspect ratios. New results of nondegenerate ellipsoids suggest that the orientation (as monitored by Euler angles) and trajectory of sedimenting, nonaxisymmetric particles such as ellipsoids provide useful information on the rheology of the suspending fluid.

  2. Modal cost analysis for linear matrix-second-order systems

    NASA Technical Reports Server (NTRS)

    Skelton, R. E.; Hughes, P. C.

    1980-01-01

    Reduced models and reduced controllers for systems governed by matrix-second-order differential equations are obtained by retaining those modes which make the largest contributions to quadratic control objectives. Such contributions, expressed in terms of modal data, used as mode truncation criteria, allow the statement of the specific control objectives to influence the early model reduction from very high order models which are available, for example, from finite element methods. The relative importance of damping, frequency, and eigenvector in the mode truncation decisions are made explicit for each of these control objectives: attitude control, vibration suppression and figure control. The paper also shows that using modal cost analysis (MCA) on the closed loop modes of the optimally controlled system allows the construction of reduced control policies which feedback only those closed loop modal coordinates which are most critical to the quadratic control performance criterion. In this way, the modes which should be controlled (and hence the modes which must be observable by choice of measurements), are deduced from truncations of the optimal controller.

  3. Second order anisotropy contribution in perpendicular magnetic tunnel junctions

    PubMed Central

    Timopheev, A. A.; Sousa, R.; Chshiev, M.; Nguyen, H. T.; Dieny, B.

    2016-01-01

    Hard-axis magnetoresistance loops were measured on perpendicular magnetic tunnel junction pillars of diameter ranging from 50 to 150 nm. By fitting these loops to an analytical model, the effective anisotropy fields in both free and reference layers were derived and their variations in temperature range between 340 K and 5 K were determined. It is found that a second-order anisotropy term of the form −K2cos4θ must be added to the conventional uniaxial –K1cos2θ term to explain the experimental data. This higher order contribution exists both in the free and reference layers. At T = 300 K, the estimated −K2/K1 ratios are 0.1 and 0.24 for the free and reference layers, respectively. The ratio is more than doubled at low temperatures changing the ground state of the reference layer from “easy-axis” to “easy-cone” regime. The easy-cone regime has clear signatures in the shape of the hard-axis magnetoresistance loops. The existence of this higher order anisotropy was also confirmed by ferromagnetic resonance experiments on FeCoB/MgO sheet films. It is of interfacial nature and is believed to be due to spatial fluctuations at the nanoscale of the first order anisotropy parameter at the FeCoB/MgO interface. PMID:27246631

  4. Modeling Second-Order Chemical Reactions using Cellular Automata

    NASA Astrophysics Data System (ADS)

    Hunter, N. E.; Barton, C. C.; Seybold, P. G.; Rizki, M. M.

    2012-12-01

    Cellular automata (CA) are discrete, agent-based, dynamic, iterated, mathematical computational models used to describe complex physical, biological, and chemical systems. Unlike the more computationally demanding molecular dynamics and Monte Carlo approaches, which use "force fields" to model molecular interactions, CA models employ a set of local rules. The traditional approach for modeling chemical reactions is to solve a set of simultaneous differential rate equations to give deterministic outcomes. CA models yield statistical outcomes for a finite number of ingredients. The deterministic solutions appear as limiting cases for conditions such as a large number of ingredients or a finite number of ingredients and many trials. Here we present a 2-dimensional, probabilistic CA model of a second-order gas phase reaction A + B → C, using a MATLAB basis. Beginning with a random distribution of ingredients A and B, formation of C emerges as the system evolves. The reaction rate can be varied based on the probability of favorable collisions of the reagents A and B. The model permits visualization of the conversion of reagents to products, and allows one to plot concentration vs. time for A, B and C. We test hypothetical reaction conditions such as: limiting reagents, the effects of reaction probabilities, and reagent concentrations on the reaction kinetics. The deterministic solutions of the reactions emerge as statistical averages in the limit of the large number of cells in the array. Modeling results for dynamic processes in the atmosphere will be presented.

  5. Second order anisotropy contribution in perpendicular magnetic tunnel junctions.

    PubMed

    Timopheev, A A; Sousa, R; Chshiev, M; Nguyen, H T; Dieny, B

    2016-01-01

    Hard-axis magnetoresistance loops were measured on perpendicular magnetic tunnel junction pillars of diameter ranging from 50 to 150 nm. By fitting these loops to an analytical model, the effective anisotropy fields in both free and reference layers were derived and their variations in temperature range between 340 K and 5 K were determined. It is found that a second-order anisotropy term of the form -K2cos(4)θ must be added to the conventional uniaxial -K1cos(2)θ term to explain the experimental data. This higher order contribution exists both in the free and reference layers. At T = 300 K, the estimated -K2/K1 ratios are 0.1 and 0.24 for the free and reference layers, respectively. The ratio is more than doubled at low temperatures changing the ground state of the reference layer from "easy-axis" to "easy-cone" regime. The easy-cone regime has clear signatures in the shape of the hard-axis magnetoresistance loops. The existence of this higher order anisotropy was also confirmed by ferromagnetic resonance experiments on FeCoB/MgO sheet films. It is of interfacial nature and is believed to be due to spatial fluctuations at the nanoscale of the first order anisotropy parameter at the FeCoB/MgO interface. PMID:27246631

  6. Correction of the Chromaticity up to Second Order for MEIC

    SciTech Connect

    H. K. Sayed, S.A. Bogacz, P. Chevtsov

    2010-03-01

    The proposed electron collider lattice exhibits low β- functions at the Interaction Point (IP) (βx*100mm - βy* 20 mm) and rather large equilibrium momentum spread of the collider ring (δp/p = 0.00158). Both features make the chromatic corrections of paramount importance. Here the chromatic effects of the final focus quadruples are cor- rected both locally and globally. Local correction features symmetric sextupole families around the IP, the betatron phase advances from the IP to the sextupoles are chosen to eliminate the second order chromatic aberration. Global interleaved families of sextupoles are placed in the figure-8 arc sections, and non-interleaved families at straight sec- tion making use of the freely propagated dispersion wave from the arcs. This strategy minimizes the required sex- tupole strength and eventually leads to larger dynamic aper- ture of the collider. The resulting spherical aberrations induced by the sextupoles are mitigated by design; the straight and arc sections optics features an inverse identity transformation between sextupoles in each pair.

  7. Photonic second-order duty-cycle modulator

    NASA Astrophysics Data System (ADS)

    Costanzo-Caso, Pablo A.; Reeves, Erin; Jin, Yiye; Granieri, Sergio; Siahmakoun, Azad

    2011-09-01

    The delta sigma modulator (DSM) is a device which transforms the amplitude information of an analog input signal to the duty cycle and frequency of a binary output. This device, typically employed in oversampled analog-to-digital converters, is based on a feedback loop which includes at least one integrator and one quantizer in the forward path. In this paper, a novel photonic second-order DSM is proposed and experimentally demonstrated. The system is composed of two inverted leaky integrator and one electro-optic quantizer. The maximum input frequency is around 2 MHz, limited by the fiber length of the accumulator and feedback loops, and the quantizer rise/fall times. The system is characterized at different input frequencies and waveforms (sinusoidal and saw tooth) to analyze the modulator performance and linearity. The binary output is acquired, processed and demodulated using a personal computer, in order to reconstruct the input analog signal. The reported fiber-optic DSM is very promising for future integration increasing the operation frequency up to GHz range.

  8. A planar second-order DC SQUID gradiometer.

    PubMed

    Carelli, P; Chiaventi, L; Leoni, R; Pullano, M; Schirripa Spagnolo, G

    1991-01-01

    In this work we describe a DC SQUID gradiometer, sensitive to the second spatial derivative of the magnetic field. The sensitive area of the gradiometer is the inductive body of the DC SQUID itself. The isoflux line distribution generated by a dipolar source, obtained by performing magnetic measurements with an array of such detectors, is relatively complicated, but its localisation capability is similar to that one usually achieves with axial detector arrays. Planar gradiometers also show a better resolution for near sources and a stronger rejection of far disturbances. The final device is expected to have an inductance of a few hundreds of pH in order to obtain performances typical of a low noise DC SQUID. The pick-up coils will be the combination of four square holes of 500 microns side with a 1.05 cm baseline. Due to the magnetic field concentration (in the final device it can be a factor 10) the gradiometer will have a sensitivity of 10(-11) T m-2 Hz-1/2 and a field sensitivity of about 2 fT Hz-1/2. Some preliminary results, obtained on detectors with an intermediate area between the prototype and final device, are reported here. The process used to fabricate this second-order gradiometer is based on Nb-NbO chi-PbAuIn Josephson tunnel junctions. Some possible improvements will also be described. PMID:1807874

  9. Second-order perturbation theory: Problems on large scales

    NASA Astrophysics Data System (ADS)

    Pound, Adam

    2015-11-01

    In general-relativistic perturbation theory, a point mass accelerates away from geodesic motion due to its gravitational self-force. Because the self-force is small, one can often approximate the motion as geodesic. However, it is well known that self-force effects accumulate over time, making the geodesic approximation fail on long time scales. It is less well known that this failure at large times translates to a failure at large distances as well. At second perturbative order, two large-distance pathologies arise: spurious secular growth and infrared-divergent retarded integrals. Both stand in the way of practical computations of second-order self-force effects. Utilizing a simple flat-space scalar toy model, I develop methods to overcome these obstacles. The secular growth is tamed with a multiscale expansion that captures the system's slow evolution. The divergent integrals are eliminated by matching to the correct retarded solution at large distances. I also show how to extract conservative self-force effects by taking local-in-time "snapshots" of the global solution. These methods are readily adaptable to the physically relevant case of a point mass orbiting a black hole.

  10. Second order gyrokinetic theory for particle-in-cell codes

    NASA Astrophysics Data System (ADS)

    Tronko, Natalia; Bottino, Alberto; Sonnendrücker, Eric

    2016-08-01

    The main idea of the gyrokinetic dynamical reduction consists in a systematical removal of the fast scale motion (the gyromotion) from the dynamics of the plasma, resulting in a considerable simplification and a significant gain of computational time. The gyrokinetic Maxwell-Vlasov equations are nowadays implemented in for modeling (both laboratory and astrophysical) strongly magnetized plasmas. Different versions of the reduced set of equations exist, depending on the construction of the gyrokinetic reduction procedure and the approximations performed in the derivation. The purpose of this article is to explicitly show the connection between the general second order gyrokinetic Maxwell-Vlasov system issued from the modern gyrokinetic theory and the model currently implemented in the global electromagnetic Particle-in-Cell code ORB5. Necessary information about the modern gyrokinetic formalism is given together with the consistent derivation of the gyrokinetic Maxwell-Vlasov equations from first principles. The variational formulation of the dynamics is used to obtain the corresponding energy conservation law, which in turn is used for the verification of energy conservation diagnostics currently implemented in ORB5. This work fits within the context of the code verification project VeriGyro currently run at IPP Max-Planck Institut in collaboration with others European institutions.

  11. Second order anisotropy contribution in perpendicular magnetic tunnel junctions

    NASA Astrophysics Data System (ADS)

    Timopheev, A. A.; Sousa, R.; Chshiev, M.; Nguyen, H. T.; Dieny, B.

    2016-06-01

    Hard-axis magnetoresistance loops were measured on perpendicular magnetic tunnel junction pillars of diameter ranging from 50 to 150 nm. By fitting these loops to an analytical model, the effective anisotropy fields in both free and reference layers were derived and their variations in temperature range between 340 K and 5 K were determined. It is found that a second-order anisotropy term of the form ‑K2cos4θ must be added to the conventional uniaxial –K1cos2θ term to explain the experimental data. This higher order contribution exists both in the free and reference layers. At T = 300 K, the estimated ‑K2/K1 ratios are 0.1 and 0.24 for the free and reference layers, respectively. The ratio is more than doubled at low temperatures changing the ground state of the reference layer from “easy-axis” to “easy-cone” regime. The easy-cone regime has clear signatures in the shape of the hard-axis magnetoresistance loops. The existence of this higher order anisotropy was also confirmed by ferromagnetic resonance experiments on FeCoB/MgO sheet films. It is of interfacial nature and is believed to be due to spatial fluctuations at the nanoscale of the first order anisotropy parameter at the FeCoB/MgO interface.

  12. Scaled Opposite Spin Second Order Moller-Plesset Correlation Energy: An Economical Electronic Structure Method

    SciTech Connect

    Jung, Yousung; Lochan, Rohini C.; Dutoi, Anthony D.; Head-Gordon, Martin

    2004-08-02

    A simplified approach to treating the electron correlation energy is suggested in which only the alpha-beta component of the second order Moller-Plesset energy is evaluated, and then scaled by an empirical factor which is suggested to be 1.3. This scaled opposite spin second order energy (SOS-MP2) yields results for relative energies and derivative properties that are statistically improved over the conventional MP2 method. Furthermore, the SOS-MP2 energy can be evaluated without the 5th order computational steps associated with MP2 theory, even without exploiting any spatial locality. A 4th order algorithm is given for evaluating the opposite spin MP2 energy using auxiliary basis expansions, and a Laplace approach, and timing comparisons are given.

  13. Serpentine: Finite Difference Methods for Wave Propagation in Second Order Formulation

    SciTech Connect

    Petersson, N A; Sjogreen, B

    2012-03-26

    second order system is significantly smaller. Another issue with re-writing a second order system into first order form is that compatibility conditions often must be imposed on the first order form. These (Saint-Venant) conditions ensure that the solution of the first order system also satisfies the original second order system. However, such conditions can be difficult to enforce on the discretized equations, without introducing additional modeling errors. This project has previously developed robust and memory efficient algorithms for wave propagation including effects of curved boundaries, heterogeneous isotropic, and viscoelastic materials. Partially supported by internal funding from Lawrence Livermore National Laboratory, many of these methods have been implemented in the open source software WPP, which is geared towards 3-D seismic wave propagation applications. This code has shown excellent scaling on up to 32,768 processors and has enabled seismic wave calculations with up to 26 Billion grid points. TheWPP calculations have resulted in several publications in the field of computational seismology, e.g.. All of our current methods are second order accurate in both space and time. The benefits of higher order accurate schemes for wave propagation have been known for a long time, but have mostly been developed for first order hyperbolic systems. For second order hyperbolic systems, it has not been known how to make finite difference schemes stable with free surface boundary conditions, heterogeneous material properties, and curvilinear coordinates. The importance of higher order accurate methods is not necessarily to make the numerical solution more accurate, but to reduce the computational cost for obtaining a solution within an acceptable error tolerance. This is because the accuracy in the solution can always be improved by reducing the grid size h. However, in practice, the available computational resources might not be large enough to solve the problem with a

  14. Second order multidimensional sign-preserving remapping for ALE methods

    SciTech Connect

    Hill, Ryan N; Szmelter, J.

    2010-12-15

    A second-order conservative sign-preserving remapping scheme for Arbitrary Lagrangian-Eulerian (ALE) methods is developed utilising concepts of the Multidimensional Positive Definite Advection Transport Algorithm (MPDATA). The algorithm is inherently multidimensional, and so does not introduce splitting errors. The remapping is implemented in a two-dimensional, finite element ALE solver employing staggered quadrilateral meshes. The MPDATA remapping uses a finite volume discretization developed for volume coordinates. It is applied for the remapping of density and internal energy arranged as cell centered, and velocity as nodal, dependent variables. In the paper, the advection of scalar fields is examined first for test cases with prescribed mesh movement. A direct comparison of MPDATA with the performance of the van Leer MUSCL scheme indicates advantages of a multidimensional approach. Furthermore, distinctly different performance between basic MPDATA and the infinite gauge option is illustrated using benchmarks involving transport of a sign changing velocity field. Further development extends the application of MPDATA remapping to the full ALE solver with a staggered mesh arrangement for density, internal energy and momentum using volume coordinates. At present, two options of the algorithm - basic and infinite gauge - are implemented. To ensure a meaningful assessment, an identical Lagrangian solver and computational mesh update routines are used with either MPDATA or van Leer MUSCL remapping. The evaluation places particular focus on the abilities of both schemes to accurately model multidimensional problems. Theoretical considerations are supported with numerical examples. In addition to the prescribed mesh movement cases for advection of scalars, the demonstrations include two-dimensional Eulerian and ALE flow simulations on quadrilateral meshes with both fixed and variable timestep control. The key comparisons include the standard test cases of Sod and Noh

  15. Dynamic origin of first and second order phase transitions in magnetization reversal of elliptical nanodots.

    SciTech Connect

    Montoncello, F.; Giovannini, L.; Nizzoli, F.; Vavassori, P.; Grimsditch, M.; Materials Science Division; Univ. di Ferrara; CNISM; CNR-INFM; CIC nanoGUNE Res. Ctr.

    2008-06-01

    We study the magnetization reversal in elliptical nanodots with the external field applied exactly along the minor (hard) axis. By varying the magnitude of the applied field, several first and second order transitions take place and the system proceeds through magnetic configurations characterized by different symmetry properties. The dynamical matrix method is used to calculate the spin excitations as function of the applied field. This model system allows us to investigate the relationship between the singularities of the magnetization, the presence of soft spin excitations, and the symmetry properties of the static and dynamic magnetization fields. Rules that govern the transitions are formulated.

  16. Second-order dispersion interactions in π-conjugated polymers

    NASA Astrophysics Data System (ADS)

    Barford, William; Paiboonvorachat, Nattapong; Yaron, David

    2011-06-01

    We calculate the ground state and excited state second-order dispersion interactions between parallel π-conjugated polymers. The unperturbed eigenstates and energies are calculated from the Pariser-Parr-Pople model using CI-singles theory. Based on large-scale calculations using the molecular structure of trans-polyacetylene as a model system and by exploiting dimensional analysis, we find that: (1) For inter-chain separations, R, greater than a few lattice spacings, the ground-state dispersion interaction, Δ E_{GS}, satisfies, Δ E_{GS} ˜ L^2/R^6 for L ≪ R and Δ E_{GS} ˜ L/R^5 for R ≪ L, where L is the chain length. The former is the London fluctuating dipole-dipole interaction while the latter is a fluctuating line dipole-line dipole interaction. (2) The excited state screening interaction exhibits a crossover from fluctuating monopole-line dipole interactions to either fluctuating dipole-dipole or fluctuating line dipole-line dipole interactions when R exceeds a threshold Rc, where Rc is related to the root-mean-square separation of the electron-hole excitation. Specifically, the excited state screening interaction, ΔEn, satisfies, ΔEn ˜ L/R6 for Rc < L ≪ R and ΔEn ˜ L0/R5 for Rc < R ≪ L. For R < Rc < L, ΔEn ˜ R-ν, where ν ≃ 3. We also investigate the relative screening of the primary excited states in conjugated polymers, namely the n = 1, 2, and 3 excitons. We find that a larger value of n corresponds to a larger value of ΔEn. For example, for poly(para-phenylene), ΔEn = 1 ≃ 0.1 eV, ΔEn = 2 ≃ 0.6 eV, and ΔEn = 3 ≃ 1.2 eV (where n = 1 is the 11B1 state, n = 2 is the m1A state, and n = 3 is the n1B1 state). Finally, we find that the strong dependence of ΔEn on inter-chain separation implies a strong dependency of ΔEn on density fluctuations. In particular, a 10% density fluctuation implies a fluctuation of 13 meV, 66 meV, and 120 meV for the 11B1, m1A state, and n1B1 states of poly(para-phenylene), respectively. Our results

  17. Second-order bosonic Kadanoff-Baym equations for plasmon-accompanied optical absorption

    NASA Astrophysics Data System (ADS)

    Schüler, Michael; Pavlyukh, Yaroslav

    2016-03-01

    The availability of ultra-short and strong light sources opens the door for a variety of new experiments such as transient absorption, where optical properties of systems can be studied in extreme nonequilibrium situations. The nonequilibrium Green's function formalism is an efficient approach to investigate these processes theoretically. Here we apply the method to the light-matter interaction of the magnesium 2p core level accompanied by electron-plasmon interaction due to collective excitations in the conduction band. The plasmons are described as massive bosonic quasi-particle excitations, leading to a second-order equations of motion, requiring a new approach for their propagation.

  18. Hanbury Brown-Twiss interferometry and second-order correlations of inflaton quanta

    SciTech Connect

    Giovannini, Massimo

    2011-01-15

    The quantum theory of optical coherence is applied to the scrutiny of the statistical properties of the relic inflaton quanta. After adapting the description of the quantized scalar and tensor modes of the geometry to the analysis of intensity correlations, the normalized degrees of first-order and second-order coherence are computed in the concordance paradigm and are shown to encode faithfully the statistical properties of the initial quantum state. The strongly bunched curvature phonons are not only super-Poissonian but also superchaotic. Testable inequalities are derived in the limit of large-angular scales and can be physically interpreted in the light of the tenets of Hanbury Brown-Twiss interferometry. The quantum mechanical results are compared and contrasted with different situations including the one where intensity correlations are the result of a classical stochastic process. The survival of second-order correlations (not necessarily related to the purity of the initial quantum state) is addressed by defining a generalized ensemble where super-Poissonian statistics is an intrinsic property of the density matrix and turns out to be associated with finite volume effects which are expected to vanish in the thermodynamic limit.

  19. Spacecraft Attitude Estimation Using the Second-Order Extended H Infinity Filter

    NASA Astrophysics Data System (ADS)

    Reis Silva, William; Koiti Kuga, Helio; Zanardi, Maria Cecilia

    In this work, will be described the attitude determination and the gyros drift estimation using the Second-Order Extended H Infinity Filter for nonlinear systems. Such filter uses the Taylor series to approximate the non-linearity of the known dynamics and assumes that the noise sources have approximately known statistical properties. The application uses simulated measurement data for orbit and attitude through the propagator PROPAT. The attitude dynamical model is described by nonlinear equations involving the Euler angles. The attitude sensors available are two DSS (Digital Sun Sensors), two IRES (Infra-Red Earth Sensor), and one triad of mechanical gyros. These sensors configurations are similar to those found in real satellite CBERS-2 (China Brazil Earth Resources Satellite). According to the theory, in comparison with the Kalman filtering, the H Infinity filtering has some advantages in state estimation. In the H Infinity filter, the nature is assumed to be perverse and actively seeks to degrade our state estimate as much as possible, whereas the Kalman filtering, the nature is assumed to be indifferent. Thus, Extended H Infinity Filter is simply a robust version of the extended Kalman filter because to add tolerance to unmodeled noise and dynamics. Using the Second-Order Extend H Infinity Filter, the aim is to highlight and magnify the properties of the H Infinity Filter in terms of its favourable characteristics, since this is a refinement of the Extended H∞ Filter and certainly the Second-Order Extend H Infinity Filter provides better results. The results in this work show that one can reach accuracies in attitude determination within the prescribed requirements, besides providing estimates of the gyro drifts which can be further used to enhance the gyro error model. It is known that gyros present several sources of error of which the drift is the most troublesome,because over time the accumulation of errorshinder the accuracy in the estimation process

  20. New - and Photoswitchable Chromophores for Second-Order Nonlinear Optics

    NASA Astrophysics Data System (ADS)

    Sanguinet, L.; Ahmed, S.; Pozzo, J. L.; Rodriguez, V.; Adamietz, F.

    New acidochromic and photochromic compounds with nonlinear optical properties have been designed and synthesized. The hyperpolarizabilities of the zwitterionic colored forms have been quantified with polarized hyper-Rayleigh scattering experiments. The static value of oxazolidino-indoline 2 is found to be as high as Disperse Red One. This opens the way to novel multi-addressable NLO-systems.

  1. A second order radiative transfer equation and its solution by meshless method with application to strongly inhomogeneous media

    SciTech Connect

    Zhao, J.M.; Tan, J.Y.; Liu, L.H.

    2013-01-01

    A new second order form of radiative transfer equation (named MSORTE) is proposed, which overcomes the singularity problem of a previously proposed second order radiative transfer equation [J.E. Morel, B.T. Adams, T. Noh, J.M. McGhee, T.M. Evans, T.J. Urbatsch, Spatial discretizations for self-adjoint forms of the radiative transfer equations, J. Comput. Phys. 214 (1) (2006) 12-40 (where it was termed SAAI), J.M. Zhao, L.H. Liu, Second order radiative transfer equation and its properties of numerical solution using finite element method, Numer. Heat Transfer B 51 (2007) 391-409] in dealing with inhomogeneous media where some locations have very small/zero extinction coefficient. The MSORTE contains a naturally introduced diffusion (or second order) term which provides better numerical property than the classic first order radiative transfer equation (RTE). The stability and convergence characteristics of the MSORTE discretized by central difference scheme is analyzed theoretically, and the better numerical stability of the second order form radiative transfer equations than the RTE when discretized by the central difference type method is proved. A collocation meshless method is developed based on the MSORTE to solve radiative transfer in inhomogeneous media. Several critical test cases are taken to verify the performance of the presented method. The collocation meshless method based on the MSORTE is demonstrated to be capable of stably and accurately solve radiative transfer in strongly inhomogeneous media, media with void region and even with discontinuous extinction coefficient.

  2. A second order residual based predictor-corrector approach for time dependent pollutant transport

    NASA Astrophysics Data System (ADS)

    Pavan, S.; Hervouet, J.-M.; Ricchiuto, M.; Ata, R.

    2016-08-01

    We present a second order residual distribution scheme for scalar transport problems in shallow water flows. The scheme, suitable for the unsteady cases, is obtained adapting to the shallow water context the explicit Runge-Kutta schemes for scalar equations [1]. The resulting scheme is decoupled from the hydrodynamics yet the continuity equation has to be considered in order to respect some important numerical properties at discrete level. Beyond the classical characteristics of the residual formulation presented in [1,2], we introduce the possibility to iterate the corrector step in order to improve the accuracy of the scheme. Another novelty is that the scheme is based on a precise monotonicity condition which guarantees the respect of the maximum principle. We thus end up with a scheme which is mass conservative, second order accurate and monotone. These properties are checked in the numerical tests, where the proposed approach is also compared to some finite volume schemes on unstructured grids. The results obtained show the interest in adopting the predictor-corrector scheme for pollutant transport applications, where conservation of the mass, monotonicity and accuracy are the most relevant concerns.

  3. Effects of Deception on Children's Understanding of Second-Order False Belief

    ERIC Educational Resources Information Center

    Miller, Scott A.

    2013-01-01

    This research examined two questions: effects of deception on children's understanding of second-order false belief, and possible effects of number of siblings on second-order performance. Kindergarten children responded to 3 second-order problems that varied in the presence and the nature of deception. Performance was better on the problems…

  4. Adolescent, but not adult, rats exhibit ethanol-mediated appetitive second-order conditioning

    PubMed Central

    Pautassi, Ricardo Marcos; Myers, Mallory; Spear, Linda Patia; Molina, Juan Carlos; Spear, Norman E.

    2008-01-01

    Background Adolescent rats are less sensitive to the sedative effects of ethanol than older animals. They also seem to perceive the reinforcing properties of ethanol. However, unlike neonates or infants, ethanol-mediated appetitive behavior has yet to be clearly shown in adolescents. Appetitive ethanol reinforcement was assessed in adolescent (postnatal day 33, P33) and adult rats (P71) through second-order conditioning (SOC). Methods On P32 or P70 animals were intragastrically administered ethanol (0.5 or 2.0 g/kg) paired with intraoral pulses of sucrose (CS1, first-order conditioning phase). CS1 delivery took place either 5-20 (Early pairing) or 30-45 (Late pairing) min following ethanol. CS1 exposure and ethanol administration were separated by 240 min in unpaired controls. On P33 or P71, animals were presented the CS1 (second-order conditioning phase) while in a distinctive chamber (CS2). Then, they were tested for CS2 preference. Results Early and late paired adolescents, but not adults, had greater preference for the CS2 than controls, a result indicative of ontogenetic variation in ethanol-mediated reinforcement. During the CS1 - CS2 associative phase, paired adolescents given 2.0 g/kg ethanol wall-climbed more than controls. Blood and brain ethanol levels associated with the 0.5 and 2.0 g/kg doses at the onset of each conditioning phase did not differ substantially across age, with mean BECs of 38 and 112 mg %. Conclusions These data indicate age-related differences between adolescent and adult rats in terms of sensitivity to ethanol’s motivational effects. Adolescents exhibit high sensitivity for ethanol’s appetitive effects. These animals also showed EtOH-mediated behavioral activation during the second-order conditioning phase. The SOC preparation provides a valuable conditioning model for assessing ethanol’s motivational effects across ontogeny. PMID:18782343

  5. Second-order nonlinear optical Langmuir-Blodgett films based on a series of azo rare-earth coordination compounds

    SciTech Connect

    Gao, L.H.; Wang, K.Z.; Huang, C.H.

    1995-06-01

    A series of novel azo dyes composed of a lanthanide complex anion and an azo cation, in which strongly electron-donating (dihexadecylamino)phenyl and electron-accepting pyridinium groups are separated by an azo group, was designed as second-order nonlinear optical Langmuir-Blodgett (LB) film materials. The compounds are of good film-forming properties. The values of second-order molecular hyperpolarizability {beta} were determined to be (1.20-3.03) x 10{sup {minus}27} esu, comparable to the largest value known for azo LB materials. The compounds studied may be attactive in the application in future optical devices. 13 refs., 5 figs., 1 tab.

  6. A Critical Evaluation of Gestural Stiffness Estimations in Speech Production Based on a Linear Second-Order Model

    ERIC Educational Resources Information Center

    Fuchs, Susanne; Perrier, Pascal; Hartinger, Mariam

    2011-01-01

    Purpose: Linear second-order models have often been used to investigate properties of speech production. However, these models are inaccurate approximations of the speech apparatus. This study aims at assessing how reliably stiffness can be estimated from kinematics with these models. Method: Articulatory movements were collected for 9 speakers of…

  7. Optimization of microscopic and macroscopic second order optical nonlinearities

    NASA Technical Reports Server (NTRS)

    Marder, Seth R.; Perry, Joseph W.

    1993-01-01

    Nonlinear optical materials (NLO) can be used to extend the useful frequency range of lasers. Frequency generation is important for laser-based remote sensing and optical data storage. Another NLO effect, the electro-optic effect, can be used to modulate the amplitude, phase, or polarization state of an optical beam. Applications of this effect in telecommunications and in integrated optics include the impression of information on an optical carrier signal or routing of optical signals between fiber optic channels. In order to utilize these effects most effectively, it is necessary to synthesize materials which respond to applied fields very efficiently. In this talk, it will be shown how the development of a fundamental understanding of the science of nonlinear optics can lead to a rational approach to organic molecules and materials with optimized properties. In some cases, figures of merit for newly developed materials are more than an order of magnitude higher than those of currently employed materials. Some of these materials are being examined for phased-array radar and other electro-optic switching applications.

  8. Second order blended multidimensional upwind residual distribution scheme for steady and unsteady computations

    NASA Astrophysics Data System (ADS)

    Dobes, Jiri; Deconinck, Herman

    2008-06-01

    matrix [M. Mezine, M. Ricchiuto, R. Abgrall, H. Deconinck, Monotone and stable residual distribution schemes on prismatic space-time elements for unsteady conservation laws, 33rd Computational Fluid Dynamics Course, Von Karman Institute for Fluid Dynamics, 2003; R. Abgrall, M. Mezine, Construction of second order accurate monotone and stable residual distribution schemes for unsteady flow problems, J. Comput. Phys. 188 (2003) 16-55]. For the time integration, a three point backward scheme is selected for its accuracy and robustness and the shock capturing operator is modified appropriately, to handle moving shocks. We present a numerical solution of several challenging test cases involving the solution of the Euler equations from the subsonic to the hypersonic regime. All the tests shows very good accuracy, robustness and convergence properties.

  9. The Face Inversion Effect: Roles of First- and Second-Order Configural Information.

    PubMed

    Civile, Ciro; McLaren, Rossy; McLaren, Ian P L

    2016-01-01

    The face inversion effect (FIE) is a reduction in recognition performance for inverted faces compared with upright faces. Several studies have proposed that a type of configural information, called second-order relational information, becomes more important with increasing expertise and gives rise to the FIE. However, recently it has been demonstrated that it is possible to obtain an FIE with facial features presented in isolation, showing that configural information is not necessary for this effect to occur. In this article we test whether there is a role for configural information in producing the FIE and whether second- or first-order relational information is particularly important. In Experiment 1, we investigated the role of configural information and local feature orientation by using a new type of "Thatcherizing" transformation on our set of faces, aiming to disrupt second-order and local feature orientation information but keeping all first-order properties unaltered. The results showed a significant reduction in the FIE for these "new" Thatcherized faces, but it did not entirely disappear. Experiment 2 confirmed the FIE for new Thatcherized faces, and Experiment 3 establishes that both local feature orientation and first-order relational information have a role in determining the FIE. PMID:27029104

  10. Beyond the GW approximation: a second-order screened exchange correction

    NASA Astrophysics Data System (ADS)

    Rinke, Patrick; Caruso, Fabio; Ren, Xinguo; Scheffler, Matthias; Marom, Noa

    2013-03-01

    Despite the success of the GW method in describing the photoemission spectra of solids, molecules and clusters, challenges remain. For aromatic molecules for example absolute as well as relative positions of ionisation energies and affinities are not well reproduced in perturbative G0W0 schemes with different starting points as well as in self-consistent GW, sometimes even giving the wrong orbital order. Motivated by renormalized second-order perturbation theory for the ground-state energy, we propose a second-order screened exchange correction (SOSEX) to the GW self-energy. This correction follows the spirit of the SOSEX correction to the random-phase approximation for the electron correlation energy and reduces the self-correlation error. The performance of the GW +SOSEX scheme has been benchmarked for a set of molecular systems, including the G2 set, commonly used acceptor molecules, benzene and the azabenzene molecules. We find that the SOSEX correction improves the description of the spectral properties including the orbital order with respect to the different GW schemes, highlighting the importance of reducing the self-correlation error.

  11. A parallel second-order adaptive mesh algorithm for incompressible flow in porous media.

    PubMed

    Pau, George S H; Almgren, Ann S; Bell, John B; Lijewski, Michael J

    2009-11-28

    In this paper, we present a second-order accurate adaptive algorithm for solving multi-phase, incompressible flow in porous media. We assume a multi-phase form of Darcy's law with relative permeabilities given as a function of the phase saturation. The remaining equations express conservation of mass for the fluid constituents. In this setting, the total velocity, defined to be the sum of the phase velocities, is divergence free. The basic integration method is based on a total-velocity splitting approach in which we solve a second-order elliptic pressure equation to obtain a total velocity. This total velocity is then used to recast component conservation equations as nonlinear hyperbolic equations. Our approach to adaptive refinement uses a nested hierarchy of logically rectangular grids with simultaneous refinement of the grids in both space and time. The integration algorithm on the grid hierarchy is a recursive procedure in which coarse grids are advanced in time, fine grids are advanced multiple steps to reach the same time as the coarse grids and the data at different levels are then synchronized. The single-grid algorithm is described briefly, but the emphasis here is on the time-stepping procedure for the adaptive hierarchy. Numerical examples are presented to demonstrate the algorithm's accuracy and convergence properties and to illustrate the behaviour of the method. PMID:19840985

  12. A Parallel Second-Order Adaptive Mesh Algorithm for Incompressible Flow in Porous Media

    SciTech Connect

    Pau, George Shu Heng; Almgren, Ann S.; Bell, John B.; Lijewski, Michael J.

    2008-04-01

    In this paper we present a second-order accurate adaptive algorithm for solving multiphase, incompressible flows in porous media. We assume a multiphase form of Darcy's law with relative permeabilities given as a function of the phase saturation. The remaining equations express conservation of mass for the fluid constituents. In this setting the total velocity, defined to be the sum of the phase velocities, is divergence-free. The basic integration method is based on a total-velocity splitting approach in which we solve a second-order elliptic pressure equation to obtain a total velocity. This total velocity is then used to recast component conservation equations as nonlinear hyperbolic equations. Our approach to adaptive refinement uses a nested hierarchy of logically rectangular grids with simultaneous refinement of the grids in both space and time. The integration algorithm on the grid hierarchy is a recursive procedure in which coarse grids are advanced in time, fine grids areadvanced multiple steps to reach the same time as the coarse grids and the data atdifferent levels are then synchronized. The single grid algorithm is described briefly,but the emphasis here is on the time-stepping procedure for the adaptive hierarchy. Numerical examples are presented to demonstrate the algorithm's accuracy and convergence properties and to illustrate the behavior of the method.

  13. Second order formalism for spin (1/2) fermions and Compton scattering

    SciTech Connect

    Delgado-Acosta, E. G.; Napsuciale, Mauro; Rodriguez, Simon

    2011-04-01

    We develop a second order formalism for massive spin 1/2 fermions based on the projection over Poincare invariant subspaces in the ((1/2),0)+(0,(1/2)) representation of the homogeneous Lorentz group. Using the U(1){sub em} gauge principle we obtain a second order description for the electromagnetic interactions of a spin 1/2 fermion with two free parameters, the gyromagnetic factor g and a parameter {xi} related to odd-parity Lorentz structures. We calculate Compton scattering in this formalism. In the particular case g=2, {xi}=0, and for states with well-defined parity, we recover Dirac results. In general, we find the correct classical limit and a finite value r{sub c}{sup 2} for the forward differential cross section, independent of the photon energy and of the value of the parameters g and {xi}. The differential cross section vanishes at high energies for all g, {xi} except in the forward direction. The total cross section at high energies vanishes only for g=2, {xi}=0. We argue that this formalism is more convenient than Dirac theory in the description of low energy electromagnetic properties of baryons and illustrate the point with the proton case.

  14. A generalized LSTM-like training algorithm for second-order recurrent neural networks

    PubMed Central

    Monner, Derek; Reggia, James A.

    2011-01-01

    The Long Short Term Memory (LSTM) is a second-order recurrent neural network architecture that excels at storing sequential short-term memories and retrieving them many time-steps later. LSTM’s original training algorithm provides the important properties of spatial and temporal locality, which are missing from other training approaches, at the cost of limiting it’s applicability to a small set of network architectures. Here we introduce the Generalized Long Short-Term Memory (LSTM-g) training algorithm, which provides LSTM-like locality while being applicable without modification to a much wider range of second-order network architectures. With LSTM-g, all units have an identical set of operating instructions for both activation and learning, subject only to the configuration of their local environment in the network; this is in contrast to the original LSTM training algorithm, where each type of unit has its own activation and training instructions. When applied to LSTM architectures with peephole connections, LSTM-g takes advantage of an additional source of back-propagated error which can enable better performance than the original algorithm. Enabled by the broad architectural applicability of LSTM-g, we demonstrate that training recurrent networks engineered for specific tasks can produce better results than single-layer networks. We conclude that LSTM-g has the potential to both improve the performance and broaden the applicability of spatially and temporally local gradient-based training algorithms for recurrent neural networks. PMID:21803542

  15. The maintenance of the second-order advantage: second-order calibration of excitation-emission matrix fluorescence for quantitative analysis of herbicide napropamide in various environmental samples.

    PubMed

    Li, Yuan-Na; Wu, Hai-Long; Qing, Xiang-Dong; Nie, Chong-Chong; Li, Shu-Fang; Yu, Yong-Jie; Zhang, Shu-Rong; Yu, Ru-Qin

    2011-07-15

    A rapid non-separative spectrofluorometric method based on the second-order calibration of excitation-emission matrix (EEM) fluorescence was proposed for the determination of napropamide (NAP) in soil, river sediment, and wastewater as well as river water samples. With 0.10 mol L(-1) sodium citrate-hydrochloric acid (HCl) buffer solution of pH 2.2, the system of NAP has a large increase in fluorescence intensity. To handle the intrinsic fluorescence interferences of environmental samples, the alternating penalty trilinear decomposition (APTLD) algorithm as an efficient second-order calibration method was employed. Satisfactory results have been achieved for NAP in complex environmental samples. The limit of detection obtained for NAP in soil, river sediment, wastewater and river water samples were 0.80, 0.24, 0.12, 0.071 ng mL(-1), respectively. Furthermore, in order to fully investigate the performance of second-order calibration method, we test the second-order calibration method using different calibration approaches including the single matrix model, the intra-day various matrices model and the global model based on the APTLD algorithm with nature environmental datasets. The results showed the second-order calibration methods also enable one or more analyte(s) of interest to be determined simultaneously in the samples with various types of matrices. The maintenance of second-order advantage has been demonstrated in simultaneous determinations of the analyte of interests in the environmental samples of various matrices. PMID:21645706

  16. A superconvergent LDG-hybridizable Galerkin method for second-order elliptic problems

    NASA Astrophysics Data System (ADS)

    Cockburn, Bernardo; Dong, Bo; Guzman, Johnny

    2008-12-01

    We identify and study an LDG-hybridizable Galerkin method, which is not an LDG method, for second-order elliptic problems in several space dimensions with remarkable convergence properties. Unlike all other known discontinuous Galerkin methods using polynomials of degree kge0 for both the potential as well as the flux, the order of convergence in L^2 of both unknowns is k+1 . Moreover, both the approximate potential as well as its numerical trace superconverge in L^2 -like norms, to suitably chosen projections of the potential, with order k+2 . This allows the application of element-by-element postprocessing of the approximate solution which provides an approximation of the potential converging with order k+2 in L^2 . The method can be thought to be in between the hybridized version of the Raviart-Thomas and that of the Brezzi-Douglas-Marini mixed methods.

  17. Second-order optical effects in several pyrazolo-quinoline derivatives

    NASA Astrophysics Data System (ADS)

    Makowska-Janusik, M.; Gondek, E.; Kityk, I. V.; Wisła, J.; Sanetra, J.; Danel, A.

    2004-11-01

    Using optical poling of several pyazolo-quinoline (PAQ) derivatives we have found an existence of sufficiently high second order optical susceptibility at wavelength 1.76 μm varying in the range 0.9-2.8 pm/V. The performed quantum chemical simulations of the UV-absorption for isolated, solvated and incorporated into the polymethacrylate (PMMA) polymer films have shown that the PM3 method is the best among the semi-empirical ones to simulate the optical properties. The calculations of the hyperpolarizabilites have shown a good correlation with experimentally measured susceptibilities obtained from the optical poling. We have found that experimental susceptibility depends on linear molecular polarizability and photoinducing changes of the molecular dipole moment. It is clearly seen for the PAQ4-PAQ6 molecules possessing halogen atoms with relatively large polarizabilities.

  18. Relative form boundedness and compactness for a second-order differential operator

    NASA Astrophysics Data System (ADS)

    Brown, Richard C.; Hinton, D. B. Don B.

    2004-10-01

    If A and L are self-adjoint operators on a Hilbert space such that A is nonnegative and L≥[var epsilon]I for some [var epsilon]>0 we study conditions under which A is form bounded or form compact with respect to L and contrast these concepts with the stronger properties that A be relatively operator bounded or compact with respect to L. In particular several definitions of form compactness are shown to be equivalent. The principal application of the theory is to self-adjoint second order operators. In this case conditions that A be form bounded or form compact with respect to L are shown in some cases to be necessary and sufficient. Examples include the energy operator of the hydrogen atom.

  19. Fisher information of special functions and second-order differential equations

    NASA Astrophysics Data System (ADS)

    Yáñez, R. J.; Sánchez-Moreno, P.; Zarzo, A.; Dehesa, J. S.

    2008-08-01

    We investigate a basic question of analytic information theory, namely, the evaluation of the Fisher information and the relative Fisher information with respect to a non-negative function, for the probability distributions obtained by squaring the special functions of mathematical physics which are solutions of second-order differential equations. We obtain explicit expressions for these information-theoretic properties via the expectation values of the coefficients of the differential equation. We illustrate our approach for various nonrelativistic D-dimensional wavefunctions and some special functions of physicomathematical interest. Emphasis is made in the Nikiforov-Uvarov hypergeometric-type functions, which include and generalize the Hermite functions and the Gauss and Kummer hypergeometric functions, among others.

  20. Unbalanced and Minimal Point Equivalent Estimation Second-Order Split-Plot Designs

    NASA Technical Reports Server (NTRS)

    Parker, Peter A.; Kowalski, Scott M.; Vining, G. Geoffrey

    2007-01-01

    Restricting the randomization of hard-to-change factors in industrial experiments is often performed by employing a split-plot design structure. From an economic perspective, these designs minimize the experimental cost by reducing the number of resets of the hard-to- change factors. In this paper, unbalanced designs are considered for cases where the subplots are relatively expensive and the experimental apparatus accommodates an unequal number of runs per whole-plot. We provide construction methods for unbalanced second-order split- plot designs that possess the equivalence estimation optimality property, providing best linear unbiased estimates of the parameters; independent of the variance components. Unbalanced versions of the central composite and Box-Behnken designs are developed. For cases where the subplot cost approaches the whole-plot cost, minimal point designs are proposed and illustrated with a split-plot Notz design.

  1. Asynchronous consensus of multiple second-order agents with partial state information

    NASA Astrophysics Data System (ADS)

    Gao, Yanping; Zuo, Min; Jiang, Tongqiang; Du, Junping; Ma, Jingwei

    2013-05-01

    This article studies the asynchronous consensus problem of multiple second-order agents in a sampled-data setting, where asynchrony means that the sampling period of each agent is independent of the others. It is assumed that each agent can only obtain the information of its positions relative to its neighbours at sampling instants. First, a discrete-time protocol is provided based on velocity estimation, and a sufficient and necessary condition for consensus under this protocol is established in virtue of properties of periodic systems. Second, a continuous-time protocol is presented by the theory of dynamic output feedback control, and a sufficient condition for consensus under this protocol is obtained by applying an input delay approach. Simulations are performed to illustrate the effectiveness of the theoretical results.

  2. A second-order learning algorithm for multilayer networks based on block Hessian matrix.

    PubMed

    Wang, Yi Jen; Lin, Chin Teng

    1998-12-01

    This article proposes a new second-order learning algorithm for training the multilayer perceptron (MLP) networks. The proposed algorithm is a revised Newton's method. A forward-backward propagation scheme is first proposed for network computation of the Hessian matrix, H, of the output error function of the MLP. A block Hessian matrix, H(b), is then defined to approximate and simplify H. Several lemmas and theorems are proved to uncover the important properties of H and H(b), and verify the good approximation of H(b) to H; H(b) preserves the major properties of H. The theoretic analysis leads to the development of an efficient way for computing the inverse of H(b) recursively. In the proposed second-order learning algorithm, the least squares estimation technique is adopted to further lessen the local minimum problems. The proposed algorithm overcomes not only the drawbacks of the standard backpropagation algorithm (i.e. slow asymptotic convergence rate, bad controllability of convergence accuracy, local minimum problems, and high sensitivity to learning constant), but also the shortcomings of normal Newton's method used on the MLP, such as the lack of network implementation of H, ill representability of the diagonal terms of H, the heavy computation load of the inverse of H, and the requirement of a good initial estimate of the solution (weights). Several example problems are used to demonstrate the efficiency of the proposed learning algorithm. Extensive performance (convergence rate and accuracy) comparisons of the proposed algorithm with other learning schemes (including the standard backpropagation algorithm) are also made. PMID:12662732

  3. Differential effects of exogenous and endogenous attention on second-order texture contrast sensitivity

    PubMed Central

    Barbot, Antoine; Landy, Michael S.; Carrasco, Marisa

    2012-01-01

    The visual system can use a rich variety of contours to segment visual scenes into distinct perceptually coherent regions. However, successfully segmenting an image is a computationally expensive process. Previously we have shown that exogenous attention—the more automatic, stimulus-driven component of spatial attention—helps extract contours by enhancing contrast sensitivity for second-order, texture-defined patterns at the attended location, while reducing sensitivity at unattended locations, relative to a neutral condition. Interestingly, the effects of exogenous attention depended on the second-order spatial frequency of the stimulus. At parafoveal locations, attention enhanced second-order contrast sensitivity to relatively high, but not to low second-order spatial frequencies. In the present study we investigated whether endogenous attention—the more voluntary, conceptually-driven component of spatial attention—affects second-order contrast sensitivity, and if so, whether its effects are similar to those of exogenous attention. To that end, we compared the effects of exogenous and endogenous attention on the sensitivity to second-order, orientation-defined, texture patterns of either high or low second-order spatial frequencies. The results show that, like exogenous attention, endogenous attention enhances second-order contrast sensitivity at the attended location and reduces it at unattended locations. However, whereas the effects of exogenous attention are a function of the second-order spatial frequency content, endogenous attention affected second-order contrast sensitivity independent of the second-order spatial frequency content. This finding supports the notion that both exogenous and endogenous attention can affect second-order contrast sensitivity, but that endogenous attention is more flexible, benefitting performance under different conditions. PMID:22895879

  4. Linear matrix inequalities for analysis and control of linear vector second-order systems

    SciTech Connect

    Adegas, Fabiano D.; Stoustrup, Jakob

    2014-10-06

    Many dynamical systems are modeled as vector second-order differential equations. This paper presents analysis and synthesis conditions in terms of LMI with explicit dependence in the coefficient matrices of vector second-order systems. These conditions benefit from the separation between the Lyapunov matrix and the system matrices by introducing matrix multipliers, which potentially reduce conservativeness in hard control problems. Multipliers facilitate the usage of parameter-dependent Lyapunov functions as certificates of stability of uncertain and time-varying vector second-order systems. The conditions introduced in this work have the potential to increase the practice of analyzing and controlling systems directly in vector second-order form.

  5. Simulation of hydrodynamics using large eddy simulation-second-order moment model in circulating fluidized beds

    NASA Astrophysics Data System (ADS)

    Juhui, Chen; Yanjia, Tang; Dan, Li; Pengfei, Xu; Huilin, Lu

    2013-07-01

    Flow behavior of gas and particles is predicted by the large eddy simulation of gas-second order moment of solid model (LES-SOM model) in the simulation of flow behavior in CFB. This study shows that the simulated solid volume fractions along height using a two-dimensional model are in agreement with experiments. The velocity, volume fraction and second-order moments of particles are computed. The second-order moments of clusters are calculated. The solid volume fraction, velocity and second order moments are compared at the three different model constants.

  6. Second-order accurate interface- and discontinuity-aware diffusion solvers in two and three dimensions

    SciTech Connect

    Dai, William W. Scannapieco, Anthony J.

    2015-01-15

    A numerical scheme is developed for two- and three-dimensional time-dependent diffusion equations in numerical simulations involving mixed cells. The focus of the development is on the formulations for both transient and steady states, the property for large time steps, second-order accuracy in both space and time, the correct treatment of the discontinuity in material properties, and the handling of mixed cells. For a mixed cell, interfaces between materials are reconstructed within the cell so that each of resulting sub-cells contains only one material and the material properties of each sub-cell are known. Diffusion equations are solved on the resulting polyhedral mesh even if the original mesh is structured. The discontinuity of material properties between different materials is correctly treated based on governing physics principles. The treatment is exact for arbitrarily strong discontinuity. The formulae for effective diffusion coefficients across interfaces between materials are derived for general polyhedral meshes. The scheme is general in two and three dimensions. Since the scheme to be developed in this paper is intended for multi-physics code with adaptive mesh refinement (AMR), we present the scheme on mesh generated from AMR. The correctness and features of the scheme are demonstrated for transient problems and steady states in one-, two-, and three-dimensional simulations for heat conduction and radiation heat transfer. The test problems involve dramatically different materials.

  7. Second order effects of structural and material damage on ultrasonic waves

    NASA Astrophysics Data System (ADS)

    O'Neill, Brian E.

    Damage mechanics is a relatively new and powerful approach to the analysis of material degradation and failure. The idea is to build a continuum model of a solid containing a distribution of microcracks. Such a model, relying on the thermodynamics and statistical mechanics of microcracks, very naturally ties into other continuum models of solids, including acoustic and elastic models. In this dissertation, the impact of material and structural damage is investigated, with an emphasis on the relation between this effect and specific second order ultrasonic effects. The investigation has two main streams. The first, more experimental stream involves damage in the bulk. In this case, we chose to look at fatigue damage in the Ni-based alloy, waspaloy, which is used particularly for high strength, high temperature applications in the aerospace industry, as well as exhibiting very intriguing physical and thermodynamic properties. The approach was to monitor the changes in two second order parameters, the so-called nonlinearity, or beta parameter, and the acousto-elastic parameter. Results of these experiments seem to indicate that the latter is a better indicator of fatigue and damage, at least in this material. The second, more theoretical stream concerns damage along an individual weak interface. In this case, a nonlinear "thin layer" model was developed for propagation of ultrasonic waves through a weak bonded interface, as well as a time-domain approach to a general solution to this problem for a multiply layered system. This was combined with a simple damage model, and used to demonstrate how poorly bonded interfaces may be interpreted as locally damaged materials. It was also demonstrated how the nonlinearity of intensive ultrasound passing through or reflecting off an interface bond may be used, along with an appropriate damage model, to estimate the ultimate strength of this bond.

  8. Operator Factorization and the Solution of Second-Order Linear Ordinary Differential Equations

    ERIC Educational Resources Information Center

    Robin, W.

    2007-01-01

    The theory and application of second-order linear ordinary differential equations is reviewed from the standpoint of the operator factorization approach to the solution of ordinary differential equations (ODE). Using the operator factorization approach, the general second-order linear ODE is solved, exactly, in quadratures and the resulting…

  9. Explanation of Second-Order Asymptotic Theory Via Information Spectrum Method

    NASA Astrophysics Data System (ADS)

    Hayashi, Masahito

    We explain second-order asymptotic theory via the information spectrum method. From a unified viewpoint based on the generality of the information spectrum method, we consider second-order asymptotic theory for use in fixed-length data compression, uniform random number generation, and channel coding. Additionally, we discuss its application to quantum cryptography, folklore in source coding, and security analysis.

  10. Second-order theory of the rotation of an artificial satellite

    NASA Astrophysics Data System (ADS)

    Bois, Eric

    The attitude evolution of the motion of a satellite subjected to specified torques is investigated analytically, extending the theory of Bois (1986) to second order. The formulation and reduction of the second-order differential equations are outlined, and the derivation of the solutions is given in detail. Numerical results for the ESA Hipparcos astrometric satellite are presented in graphs and briefly characterized.

  11. The Second Order Approximation to Sample Influence Curve in Canonical Correlation Analysis.

    ERIC Educational Resources Information Center

    Fung, Wing K.; Gu, Hong

    1998-01-01

    A second order approximation to the sample influence curve (SIC) has been derived in the literature. This paper presents a more accurate second order approximation, which is exact for the SIC of the squared multiple correction coefficient. An example is presented. (SLD)

  12. Simplifying Second-Order Belief Attribution: What Facilitates Children's Performance on Measures of Conceptual Understanding?

    ERIC Educational Resources Information Center

    Coull, Greig J.; Leekam, Susan R.; Bennett, Mark

    2006-01-01

    This study investigated how 4- to 7-year-old children's second-order belief attribution might be facilitated by either reducing information processing or varying the sequence of task questions. In Experiment 1, compared with Perner and Wimmer's (1985) original second-order false-belief task, a new task with reduced information-processing demands…

  13. The similarity rules for second-order subsonic and supersonic flow

    NASA Technical Reports Server (NTRS)

    Van Dyke, Milton D

    1958-01-01

    The similarity rules for linearized compressible flow theory (Gothert's rule and its supersonic counterpart) are extended to second order. It is shown that any second-order subsonic flow can be related to "nearly incompressible" flow past the same body, which can be calculated by the Janzen-Rayleigh method.

  14. On group classification of normal systems of linear second-order ordinary differential equations

    NASA Astrophysics Data System (ADS)

    Meleshko, S. V.; Moyo, S.

    2015-05-01

    In this paper we study the general group classification of systems of linear second-order ordinary differential equations inspired from earlier works and recent results on the group classification of such systems. Some interesting results and subsequent theorem arising from this particular study are discussed here. This paper considers the study of irreducible systems of second-order ordinary differential equations.

  15. Post processing with first- and second-order hidden Markov models

    NASA Astrophysics Data System (ADS)

    Taghva, Kazem; Poudel, Srijana; Malreddy, Spandana

    2013-01-01

    In this paper, we present the implementation and evaluation of first order and second order Hidden Markov Models to identify and correct OCR errors in the post processing of books. Our experiments show that the first order model approximately corrects 10% of the errors with 100% precision, while the second order model corrects a higher percentage of errors with much lower precision.

  16. Teacher's Corner: Testing Measurement Invariance of Second-Order Factor Models

    ERIC Educational Resources Information Center

    Chen, Fang Fang; Sousa, Karen H.; West, Stephen G.

    2005-01-01

    We illustrate testing measurement invariance in a second-order factor model using a quality of life dataset (n = 924). Measurement invariance was tested across 2 groups at a set of hierarchically structured levels: (a) configural invariance, (b) first-order factor loadings, (c) second-order factor loadings, (d) intercepts of measured variables,…

  17. Second order gravitational effects on CMB temperature anisotropy in {lambda} dominated flat universes

    SciTech Connect

    Tomita, Kenji; Inoue, Kaiki Taro

    2008-05-15

    We study second order gravitational effects of local inhomogeneities on the cosmic microwave background radiation in flat universes with matter and a cosmological constant {lambda}. We find that the general relativistic correction to the Newtonian approximation is negligible at second order provided that the size of the inhomogeneous region is sufficiently smaller than the horizon scale. For a spherically symmetric top-hat type quasilinear perturbation, the first order temperature fluctuation corresponding to the linear integrated Sachs-Wolfe effect is enhanced (suppressed) by the second order one for a compensated void (lump). As a function of redshift of the local inhomogeneity, the second order temperature fluctuations due to evolution of the gravitational potential have a peak before the matter-{lambda} equality epoch for a fixed comoving size and a density contrast. The second order gravitational effects from local quasilinear inhomogeneities at a redshift z{approx}1 may significantly affect the cosmic microwave background.

  18. Second-order optical non-linearity of proton exchanged lithium tantalate waveguides

    NASA Astrophysics Data System (ADS)

    Korkishko, Y. N.; Fedorov, V. A.; Alkaev, A. N.; Laurell, F.

    2001-10-01

    A detailed correlation between the fabrication conditions, crystallographic phase state of HxLi1-xTaO3 waveguides and second-order optical non-linearity has been investigated by using reflected SHG measurements from the polished waveguide end face. The non-linearity, strongly reduced after the initial proton exchange, is found to be restored and even increased after annealing. However, this apparent increase in the non-linearity is accompanied by a strong degradation of the quality of the SHG reflected beam in the region of the initial as-exchanged waveguide due to beam scattering. The high temperature proton exchange technique has been shown to produce high-quality α-phase waveguides with essentially undegraded non-linear optical properties. There is no phase transition when the α-phase waveguides are fabricated by direct exchange. This phase presents the same crystalline structure as that of LiTaO3 and maintains the excellent non-linear properties of the bulk material. The results obtained are important for the design, fabrication and optimization of guided-wave non-linear optical devices in LiTaO3.

  19. In unison: First- and second-order information combine for integration of shape information.

    PubMed

    Tan, Ken W S; Dickinson, J Edwin; Badcock, David R

    2016-09-01

    The modulation of orientation around radial frequency (RF) patterns and RF textures is globally processed in both cases. This psychophysical study investigates whether the combination-a textured RF path obtained by applying an RF texture to an RF contour-is processed like a texture or a contour when making judgements about shape. Unlike RF textures, the impression of a closed flow was not required for global integration of textured RF paths, suggesting that these paths were processed as second-order, or contrast-defined contours. Luminance-defined (LD) RF paths were shown to globally integrate but with thresholds approximately half of those for the proposed second-order textured paths. The next experiment investigated whether this benefit was due to LD stimuli possessing double the amount of information (first- and second-order information). A mixed three-part contour composed of two different second-order texture components and an LD component was then employed to determine how the different cues combined. The mixed path thresholds matched predictions derived from a linear combination of first- and second-order cues. The conclusion is that the shape of isolated contours is processed using both first- and second-order information equally and that the contribution of texture is to carry additional second-order signal. PMID:27618513

  20. Linear-noise approximation and the chemical master equation agree up to second-order moments for a class of chemical systems

    NASA Astrophysics Data System (ADS)

    Grima, Ramon

    2015-10-01

    It is well known that the linear-noise approximation (LNA) agrees with the chemical master equation, up to second-order moments, for chemical systems composed of zero and first-order reactions. Here we show that this is also a property of the LNA for a subset of chemical systems with second-order reactions. This agreement is independent of the number of interacting molecules.

  1. First and second order approximations to stage numbers in multicomponent enrichment cascades

    SciTech Connect

    Scopatz, A.

    2013-07-01

    This paper describes closed form, Taylor series approximations to the number product stages in a multicomponent enrichment cascade. Such closed form approximations are required when a symbolic, rather than a numeric, algorithm is used to compute the optimal cascade state. Both first and second order approximations were implemented. The first order solution was found to be grossly incorrect, having the wrong functional form over the entire domain. On the other hand, the second order solution shows excellent agreement with the 'true' solution over the domain of interest. An implementation of the symbolic, second order solver is available in the free and open source PyNE library. (authors)

  2. First and Second Order Necessary Conditions for Stochastic Optimal Control Problems

    SciTech Connect

    Bonnans, J. Frederic; Silva, Francisco J.

    2012-06-15

    In this work we consider a stochastic optimal control problem with either convex control constraints or finitely many equality and inequality constraints over the final state. Using the variational approach, we are able to obtain first and second order expansions for the state and cost function, around a local minimum. This fact allows us to prove general first order necessary condition and, under a geometrical assumption over the constraint set, second order necessary conditions are also established. We end by giving second order optimality conditions for problems with constraints on expectations of the final state.

  3. Bose-Einstein or HBT Correlation Signals of a Second Order QCD Phase Transition

    SciTech Connect

    Csoergo, T.; Hegyi, S.; Novak, T.; Zajc, W. A.

    2006-04-11

    For particles emerging from a second order QCD phase transition, we show that a recently introduced shape parameter of the Bose-Einstein correlation function, the Levy index of stability equals to the correlation exponent -- one of the critical exponents that characterize the behaviour of the matter in the vicinity of the second order phase transition point. Hence the shape of the Bose-Einstein / HBT correlation functions, when measured as a function of bombarding energy and centrality in various heavy ion reactions, can be utilized to locate experimentally the second order phase transition and the critical end point of the first order phase transition line in QCD.

  4. Orientation-selective adaptation to first- and second-order patterns in human visual cortex

    PubMed Central

    Larsson, Jonas; Landy, Michael S.; Heeger, David J.

    2006-01-01

    Second-order textures – patterns that cannot be detected by mechanisms sensitive only to luminance changes – are ubiquitous in visual scenes, but the neuronal mechanisms mediating perception of such stimuli are not well understood. We used an adaptation protocol to measure neural activity in the human brain selective for the orientation of second-order textures. FMRI responses were measured in three subjects to presentations of first- and second-order probe gratings after adapting to a high-contrast first- or second-order grating that was either parallel or orthogonal to the probe gratings. First-order (LM) stimuli were generated by modulating the stimulus luminance. Second-order stimuli were generated by modulating the contrast (CM) or orientation (OM) of a first-order carrier. We used four combinations of adapter and probe stimuli: LM:LM, CM:CM, OM:OM, and LM:OM. The fourth condition tested for cross-modal adaptation with first-order adapter and second-order probe stimuli. Attention was diverted from the stimulus by a demanding task at fixation. Both first- and second-order stimuli elicited orientation-selective adaptation in multiple cortical visual areas, including V1, V2, V3, V3A/B, a newly identified visual area anterior to dorsal V3 which we have termed LO1, hV4, and VO1. For first-order stimuli (condition LM:LM), the adaptation was no larger in extrastriate areas than in V1, implying that the orientation-selective first-order (luminance) adaptation originated in V1. For second-order stimuli (conditions CM:CM and OM:OM), the magnitude of adaptation, relative to the absolute response magnitude, was significantly larger in VO1 (and for condition CM:CM, also in V3A/B and LO1) than in V1, suggesting that second-order stimulus orientation was extracted by additional processing after V1. There was little difference in the amplitude of adaptation between the second-order conditions. No consistent effect of adaptation was found in the cross-modal condition LM

  5. Propagation based on second-order moments for partially coherent Laguerre–Gaussian beams through atmospheric turbulence

    NASA Astrophysics Data System (ADS)

    Xu, Yonggen; Li, Yude; Dan, Youquan; Du, Quan; Wang, Shijian

    2016-07-01

    The Wigner distribution function (WDF) has been used to study the propagation properties of partially coherent Laguerre Gaussian (PCLG) beams through atmospheric turbulence. Based on the extended Huygens-Fresnel principle, an analytical formula of the propagation matrixes in terms of the second-order moments of the WDF for PCLG Beams in the receiving plane is derived. And then the analytical formulae for the curvature radii of PCLG Beams propagating in turbulence are given by the second-order moments of the WDF. The numerical results indicate that the curvature radius of PCLG Beams changes more rapidly in turbulence than that in the free space. The influence of the transverse coherence width and the beam waist width on the curvature radius of PCLG Beams is obvious, while the laser wavelength and the inner scale of turbulence have a slight effect. The study results may be useful for remote sensing and free space optical communications.

  6. Trigonometrically fitted two step hybrid method for the numerical integration of second order IVPs

    NASA Astrophysics Data System (ADS)

    Monovasilis, Th.; Kalogiratou, Z.; Simos, T. E.

    2016-06-01

    In this work we consider the numerical integration of second order ODEs where the first derivative is missing. We construct trigonometrically fitted two step hybrid methods. We apply the new methods on the numerical integration of several test problems.

  7. A second order accurate embedded boundary method for the wave equation with Dirichlet data

    SciTech Connect

    Kreiss, H O; Petersson, N A

    2004-03-02

    The accuracy of Cartesian embedded boundary methods for the second order wave equation in general two-dimensional domains subject to Dirichlet boundary conditions is analyzed. Based on the analysis, we develop a numerical method where both the solution and its gradient are second order accurate. We avoid the small-cell stiffness problem without sacrificing the second order accuracy by adding a small artificial term to the Dirichlet boundary condition. Long-time stability of the method is obtained by adding a small fourth order dissipative term. Several numerical examples are provided to demonstrate the accuracy and stability of the method. The method is also used to solve the two-dimensional TM{sub z} problem for Maxwell's equations posed as a second order wave equation for the electric field coupled to ordinary differential equations for the magnetic field.

  8. Evaluation of decay curves of a chemical species undergoing simultaneous first- and second-order decay

    NASA Technical Reports Server (NTRS)

    Schmidt, K. H.

    1970-01-01

    IBM 1620 computer prepares tables to enable fast calculation of the first- and second-order rate constants from two half-lives and the corresponding initial concentrations, obtained from either one or two decay curves.

  9. Second-order curved boundary treatments of the lattice Boltzmann method for convection-diffusion equations

    NASA Astrophysics Data System (ADS)

    Huang, Juntao; Hu, Zexi; Yong, Wen-An

    2016-04-01

    In this paper, we present a kind of second-order curved boundary treatments for the lattice Boltzmann method solving two-dimensional convection-diffusion equations with general nonlinear Robin boundary conditions. The key idea is to derive approximate boundary values or normal derivatives on computational boundaries, with second-order accuracy, by using the prescribed boundary condition. Once the approximate information is known, the second-order bounce-back schemes can be perfectly adopted. Our boundary treatments are validated with a number of numerical examples. The results show the utility of our boundary treatments and very well support our theoretical predications on the second-order accuracy thereof. The idea is quite universal. It can be directly generalized to 3-dimensional problems, multiple-relaxation-time models, and the Navier-Stokes equations.

  10. Completeness of first and second order ODE flows and of Euler-Lagrange equations

    NASA Astrophysics Data System (ADS)

    Minguzzi, Ettore

    2015-11-01

    Two results on the completeness of maximal solutions to first and second order ordinary differential equations (or inclusions) over complete Riemannian manifolds, with possibly time-dependent metrics, are obtained. Applications to Lagrangian mechanics and gravitational waves are given.

  11. Comparison of Second-Order Loads on a Tension-Leg Platform for Wind Turbines: Preprint

    SciTech Connect

    Gueydon, S.; Wuillaume, P.; Jonkman, J.; Robertson, A.; Platt, A.

    2015-03-01

    The first objective of this work is to compare the two floating offshore wind turbine simulation packages {DIFFRAC+aNySIM} and {WAMIT+FAST}. The focus is on second-order wave loads, and so first- and second-order wave loads are applied to a structure sequentially for a detailed comparison and a more precise analysis of the effects of the second-order loads. aNySIM does not have the capability to model flexible bodies, and so the simulations performed in this tool are done assuming a rigid body. FAST also assumes that the platform is rigid, but can account for the flexibility of the tower. The second objective is to study the effects of the second-order loads on the response of a TLP floating wind turbine. The flexibility of the tower must be considered for this investigation, and therefore only FAST is used.

  12. Multiple Positive Solutions in the Second Order Autonomous Nonlinear Boundary Value Problems

    NASA Astrophysics Data System (ADS)

    Atslega, Svetlana; Sadyrbaev, Felix

    2009-09-01

    We construct the second order autonomous equations with arbitrarily large number of positive solutions satisfying homogeneous Dirichlet boundary conditions. Phase plane approach and bifurcation of solutions are the main tools.

  13. An Example of Following Second-Order Kinetics by Simple Laboratory Means

    ERIC Educational Resources Information Center

    Schreiber, Gisela

    1976-01-01

    Describes a procedure for studying the kinetics of the second-order hydrolysis of ethylene bromohydrine in alkaline medium by incorporating a substance that changes color as one of the reacting components is depleted. (MLH)

  14. Second Order Duality in Multiobjective Fractional Programming with Square Root Term under Generalized Univex Function

    PubMed Central

    Tripathy, Arun Kumar

    2014-01-01

    Three approaches of second order mixed type duality are introduced for a nondifferentiable multiobjective fractional programming problem in which the numerator and denominator of objective function contain square root of positive semidefinite quadratic form. Also, the necessary and sufficient conditions of efficient solution for fractional programming are established and a parameterization technique is used to establish duality results under generalized second order ρ-univexity assumption. PMID:27379308

  15. Comments on the present state of second-order closure models for incompressible flows

    NASA Technical Reports Server (NTRS)

    Speziale, Charles G.

    1992-01-01

    Second-order closure models account for history and nonlocal effects of the mean velocity gradients on the Reynolds stress tensor. Turbulent flows involving body forces or curvature, Reynolds stress relaxational effects, and counter-gradient transport are usually better described. The topics are presented in viewgraph form and include: (1) the Reynolds stress transport equation; (2) issues in second-order closure modeling; and (3) near wall models.

  16. Parallel coding of first- and second-order stimulus attributes by midbrain electrosensory neurons.

    PubMed

    McGillivray, Patrick; Vonderschen, Katrin; Fortune, Eric S; Chacron, Maurice J

    2012-04-18

    Natural stimuli often have time-varying first-order (i.e., mean) and second-order (i.e., variance) attributes that each carry critical information for perception and can vary independently over orders of magnitude. Experiments have shown that sensory systems continuously adapt their responses based on changes in each of these attributes. This adaptation creates ambiguity in the neural code as multiple stimuli may elicit the same neural response. While parallel processing of first- and second-order attributes by separate neural pathways is sufficient to remove this ambiguity, the existence of such pathways and the neural circuits that mediate their emergence have not been uncovered to date. We recorded the responses of midbrain electrosensory neurons in the weakly electric fish Apteronotus leptorhynchus to stimuli with first- and second-order attributes that varied independently in time. We found three distinct groups of midbrain neurons: the first group responded to both first- and second-order attributes, the second group responded selectively to first-order attributes, and the last group responded selectively to second-order attributes. In contrast, all afferent hindbrain neurons responded to both first- and second-order attributes. Using computational analyses, we show how inputs from a heterogeneous population of ON- and OFF-type afferent neurons are combined to give rise to response selectivity to either first- or second-order stimulus attributes in midbrain neurons. Our study thus uncovers, for the first time, generic and widely applicable mechanisms by which parallel processing of first- and second-order stimulus attributes emerges in the brain. PMID:22514313

  17. Second-order contributions to relativistic time delay in the parametrized post-Newtonian formalism

    SciTech Connect

    Richter, G.W.; Matzner, R.A.

    1983-12-15

    Using a parametrized expansion of the solar metric to second order in the Newtonian potential, we calculate the relativistic delay in the round-trip travel time of a radar signal reflected from a nearby planet. We find that one second-order contribution to the delay is on the order of ten nanoseconds, which is comparable to the uncertainties in present-day experiments involving the Viking spacecraft.

  18. Numerical minimization of a second-order functional for image segmentation

    NASA Astrophysics Data System (ADS)

    Zanetti, Massimo; Ruggiero, Valeria; Miranda, Michele, Jr.

    2016-07-01

    In this paper we address the numerical minimization of a variational approximation of the Blake-Zisserman functional given by Ambrosio, Faina and March. Our approach exploits a compact matricial formulation of the objective functional and its decomposition into quadratic sparse convex sub-problems. This structure is well suited for using a block-coordinate descent method that cyclically determines a descent direction with respect to a block of variables by few iterations of a preconditioned conjugate gradient algorithm. We prove that the computed search directions are gradient related and, with convenient step-sizes, we obtain that any limit point of the generated sequence is a stationary point of the objective functional. An extensive experimentation on different datasets including real and synthetic images and digital surface models, enables us to conclude that: (1) the numerical method has satisfying performance in terms of accuracy and computational time; (2) a minimizer of the proposed discrete functional preserves the expected good geometrical properties of the Blake-Zisserman functional, i.e., it is able to detect first and second order edge-boundaries in images and (3) the method allows the segmentation of large images.

  19. ACKS2: Atom-condensed Kohn-Sham DFT approximated to second order

    NASA Astrophysics Data System (ADS)

    Verstraelen, T.; Ayers, P. W.; Van Speybroeck, V.; Waroquier, M.

    2013-02-01

    A new polarizable force field (PFF), namely atom-condensed Kohn-Sham density functional theory approximated to second order (ACKS2), is proposed for the efficient computation of atomic charges and linear response properties of extended molecular systems. It is derived from Kohn-Sham density functional theory (KS-DFT), making use of two novel ingredients in the context of PFFs: (i) constrained atomic populations and (ii) the Legendre transform of the Kohn-Sham kinetic energy. ACKS2 is essentially an extension of the Electronegativity Equalization Method (EEM) [W. J. Mortier, S. K. Ghosh, and S. Shankar, J. Am. Chem. Soc. 108, 4315 (1986)], 10.1021/ja00275a013 in which two major EEM shortcomings are fixed: ACKS2 predicts a linear size-dependence of the dipole polarizability in the macroscopic limit and correctly describes the charge distribution when a molecule dissociates. All ACKS2 parameters are defined as atoms-in-molecules expectation values. The implementation of ACKS2 is very similar to that of EEM, with only a small increase in computational cost.

  20. Second-order many-body perturbation study of ice Ih.

    PubMed

    He, Xiao; Sode, Olaseni; Xantheas, Sotiris S; Hirata, So

    2012-11-28

    Ice Ih is arguably the most important molecular crystal in nature, yet our understanding of its structural and dynamical properties is still far from complete. We present embedded-fragment calculations of the structures and vibrational spectra of the three-dimensional, proton-disordered phase of ice Ih performed at the level of second-order many-body perturbation theory with a basis-set superposition error correction. Our calculations address previous controversies such as the one related to the O-H bond length as well as the existence of two types of hydrogen bonds with strengths differing by a factor of two. For the latter, our calculations suggest that the observed spectral features arise from the directionality or the anisotropy of collective hydrogen-bond stretching vibrations rather than the previously suggested vastly different force constants. We also report a capability to efficiently compute infrared and Raman intensities of a periodic solid. Our approach reproduces the infrared and Raman spectra, the variation of inelastic neutron scattering spectra with deuterium concentration, and the anomaly of heat capacities at low temperatures for ice Ih. PMID:23206017

  1. A Geometric Interpretation of the Second-Order Structure Function Arising in Turbulence

    NASA Astrophysics Data System (ADS)

    Grebenev, Vladimir N.; Oberlack, Martin

    2009-02-01

    We primarily deal with homogeneous isotropic turbulence and use a closure model for the von Kármán-Howarth equation to study several geometric properties of turbulent fluid dynamics. We focus our attention on the application of Riemannian geometry methods in turbulence. Some advantage of this approach consists in exploring the specific form of a closure model for the von Kármán-Howarth equation that enables to equip a model manifold (a cylindrical domain in the correlation space) by a family of inner metrics (length scales of turbulent motion) which depends on time. We show that for large Reynolds numbers (in the limit of large Reynolds numbers) the radius of this manifold can be evaluated in terms of the second-order structure function and the correlation distance. This model manifold presents a shrinking cylindrical domain as time evolves. This result is derived by using a selfsimilar solution of the closure model for the von Kármán-Howarth equation under consideration. We demonstrate that in the new variables the selfsimilar solution obtained coincides with the element of Beltrami surface (or pseudo-sphere): a canonical surface of the constant sectional curvature equals - 1.

  2. Distributed RSS-Based Localization in Wireless Sensor Networks Based on Second-Order Cone Programming

    PubMed Central

    Tomic, Slavisa; Beko, Marko; Dinis, Rui

    2014-01-01

    In this paper, we propose a new approach based on convex optimization to address the received signal strength (RSS)-based cooperative localization problem in wireless sensor networks (WSNs). By using iterative procedures and measurements between two adjacent nodes in the network exclusively, each target node determines its own position locally. The localization problem is formulated using the maximum likelihood (ML) criterion, since ML-based solutions have the property of being asymptotically efficient. To overcome the non-convexity of the ML optimization problem, we employ the appropriate convex relaxation technique leading to second-order cone programming (SOCP). Additionally, a simple heuristic approach for improving the convergence of the proposed scheme for the case when the transmit power is known is introduced. Furthermore, we provide details about the computational complexity and energy consumption of the considered approaches. Our simulation results show that the proposed approach outperforms the existing ones in terms of the estimation accuracy for more than 1.5 m. Moreover, the new approach requires a lower number of iterations to converge, and consequently, it is likely to preserve energy in all presented scenarios, in comparison to the state-of-the-art approaches. PMID:25275350

  3. Beyond Wenzel and Cassie-Baxter: second-order effects on the wetting of rough surfaces.

    PubMed

    Hejazi, Vahid; Moghadam, Afsaneh Dorri; Rohatgi, Pradeep; Nosonovsky, Michael

    2014-08-12

    The Wenzel and Cassie-Baxter models are almost exclusively used to explain the contact angle dependence of the structure of rough and patterned solid surfaces. However, these two classical models do not always accurately predict the wetting properties of surfaces since they fail to capture the effect of many interactions occurring during wetting, including, for example, the effect of the disjoining pressure and of crystal microstructure, grains, and defects. We call such effects the second-order effects and present here a model showing how the disjoining pressure isotherm can affect wettability due to the formation of thin liquid films. We measure water contact angles on pairs of metallic surfaces with nominally the same Wenzel roughness obtained by abrasion and by chemical etching. These two methods of surface roughening result in different rough surface structure, thus leading to different values of the contact angle, which cannot be captured by the Wenzel- and Cassie-type models. The chemical and physical changes that occur on the stainless steel and aluminum alloy surfaces as a result of intergranular corrosion, along with selective intermetallic dissolution, lead to a surface roughness generated on the nano- and microscales. PMID:25051526

  4. Analyzing a stochastic time series obeying a second-order differential equation

    NASA Astrophysics Data System (ADS)

    Lehle, B.; Peinke, J.

    2015-06-01

    The stochastic properties of a Langevin-type Markov process can be extracted from a given time series by a Markov analysis. Also processes that obey a stochastically forced second-order differential equation can be analyzed this way by employing a particular embedding approach: To obtain a Markovian process in 2 N dimensions from a non-Markovian signal in N dimensions, the system is described in a phase space that is extended by the temporal derivative of the signal. For a discrete time series, however, this derivative can only be calculated by a differencing scheme, which introduces an error. If the effects of this error are not accounted for, this leads to systematic errors in the estimation of the drift and diffusion functions of the process. In this paper we will analyze these errors and we will propose an approach that correctly accounts for them. This approach allows an accurate parameter estimation and, additionally, is able to cope with weak measurement noise, which may be superimposed to a given time series.

  5. Analyzing a stochastic time series obeying a second-order differential equation.

    PubMed

    Lehle, B; Peinke, J

    2015-06-01

    The stochastic properties of a Langevin-type Markov process can be extracted from a given time series by a Markov analysis. Also processes that obey a stochastically forced second-order differential equation can be analyzed this way by employing a particular embedding approach: To obtain a Markovian process in 2N dimensions from a non-Markovian signal in N dimensions, the system is described in a phase space that is extended by the temporal derivative of the signal. For a discrete time series, however, this derivative can only be calculated by a differencing scheme, which introduces an error. If the effects of this error are not accounted for, this leads to systematic errors in the estimation of the drift and diffusion functions of the process. In this paper we will analyze these errors and we will propose an approach that correctly accounts for them. This approach allows an accurate parameter estimation and, additionally, is able to cope with weak measurement noise, which may be superimposed to a given time series. PMID:26172667

  6. Second-order nonlinear optical characteristics of nanoscale self-assembled multilayer organic films

    NASA Astrophysics Data System (ADS)

    Neyman, Patrick J.

    (30 pm/V). Thermal and temporal stability are important properties of electro-optic device implementation, and are demonstrated for CHISAM films. CHISAM films have remained stable at room temperature for more than 420 days, and suffered no loss of chi(2) when held at 80°C for 36 hours, followed by 150°C for 24 hours. Studies are also presented that demonstrate the ability to produce ISAM chi (2) films that are nearly one micron thick, and exhibit no evidence of a thickness limitation to the polar order. Analytical considerations for second-order NLO characterization of thick films are addressed in detail. The effect of absorption of the second harmonic wavelength and resonant enhancement of chi(2) are investigated, and it is demonstrated that accurate determination of chi(2) may be made for thick films and for films that absorb the second harmonic. The temporal and thermal stability of a variety of ISAM and CHISAM NLO films are examined in detail. In some cases, a decrease in the NLO response is observed at elevated temperature that is completely restored upon cooling. Studies are presented that suggest this effect is a result of thermally induced trans-to- cis isomerization of azo linkages in the NLO chromophores.

  7. Polarimetric signatures of a canopy of dielectric cylinders based on first and second order vector radiative transfer theory

    NASA Technical Reports Server (NTRS)

    Tsang, Leung; Chan, Chi Hou; Kong, Jin AU; Joseph, James

    1992-01-01

    Complete polarimetric signatures of a canopy of dielectric cylinders overlying a homogeneous half space are studied with the first and second order solutions of the vector radiative transfer theory. The vector radiative transfer equations contain a general nondiagonal extinction matrix and a phase matrix. The energy conservation issue is addressed by calculating the elements of the extinction matrix and the elements of the phase matrix in a manner that is consistent with energy conservation. Two methods are used. In the first method, the surface fields and the internal fields of the dielectric cylinder are calculated by using the fields of an infinite cylinder. The phase matrix is calculated and the extinction matrix is calculated by summing the absorption and scattering to ensure energy conservation. In the second method, the method of moments is used to calculate the elements of the extinction and phase matrices. The Mueller matrix based on the first order and second order multiple scattering solutions of the vector radiative transfer equation are calculated. Results from the two methods are compared. The vector radiative transfer equations, combined with the solution based on method of moments, obey both energy conservation and reciprocity. The polarimetric signatures, copolarized and depolarized return, degree of polarization, and phase differences are studied as a function of the orientation, sizes, and dielectric properties of the cylinders. It is shown that second order scattering is generally important for vegetation canopy at C band and can be important at L band for some cases.

  8. Space and time behaviour of the temperature second-order structure function in Rayleigh-Bénard convection

    NASA Astrophysics Data System (ADS)

    Togni, Riccardo; Cimarelli, Andrea; Lozano-Durán, Adrián; De Angelis, Elisabetta

    2016-04-01

    One of the most peculiar aspects of turbulence in wall bounded-flows is the ability of the turbulent fluctuations to regenerate themselves through self-sustained processes. The dynamics of these self-sustaining mechanisms has been extensively investigated in the past via two complementary approaches. From one side, the possibility to identify very robust kinematic features within the flow feeds the hope of the scientific community to obtain a complete and consistent dynamical description of the physics of the turbulent regeneration cycles in terms of the so-called coherent structures. From the other side, the multi-scale and inhomogeneous features of the self-sustaining mechanisms of turbulence have been addressed by means of global statistical quantities based on two-point averages such as second-order structure functions. The present work attempts to link these two approaches, by identifying how turbulent cycle mechanisms and turbulent structures reflect on the global statistical properties of second-order structure function. To this aim we use Direct Numerical Simulation data of thermally driven turbulence in the Rayleigh-Bénard convection and we analyse for the first time the behaviour of the second-order structure function of temperature in the complete four-dimensional space of spatio-temporal scales and wall-distances. The observed behaviour is then interpreted in terms of the dynamics of coherent thermal structures and of their commonly accepted model of life-cycle.

  9. First- and Second-Order Stimuli Reaction Time Measures Are Highly Sensitive to Mild Traumatic Brain Injuries.

    PubMed

    Piponnier, Jean-Claude; Forget, Robert; Gagnon, Isabelle; McKerral, Michelle; Giguère, Jean-François; Faubert, Jocelyn

    2016-01-15

    Mild traumatic brain injury (mTBI) has subtle effects on several brain functions that can be difficult to assess and follow up. We investigated the impact of mTBI on the perception of sine-wave gratings defined by first- and second-order characteristics. Fifteen adults diagnosed with mTBI were assessed at 15 days, 3 months, and 12 months postinjury. Fifteen matched controls followed the same testing schedule. Reaction times (RTs) for flicker detection and motion direction discrimination were measured. Stimulus contrast of first- and second-order patterns was equated to control for visibility, and correct-response RT means, standard deviations (SDs), medians, and interquartile ranges (IQRs) were calculated. The level of symptoms was also evaluated to compare it to RT data. In general in mTBI, RTs were longer, and SDs as well as IQRs larger, than those of controls. In addition, mTBI participants' RTs to first-order stimuli were shorter than those to second-order stimuli, and SDs as well as IQRs larger for first- than for second-order stimuli in the motion condition. All these observations were made over the three sessions. The level of symptoms observed in mTBI was higher than that of control participants, and this difference did also persist up to 1 year after the brain injury, despite an improvement. The combination of RT measures with particular stimulus properties is a highly sensitive method for measuring mTBI-induced visuomotor anomalies and provides a fine probe of the underlying mechanisms when the brain is exposed to mild trauma. PMID:25950948

  10. Oxazines: A New Class of Second-Order Nonlinear Optical Switches.

    PubMed

    Beaujean, Pierre; Bondu, Flavie; Plaquet, Aurélie; Garcia-Amorós, Jaume; Cusido, Janet; Raymo, Françisco M; Castet, Frédéric; Rodriguez, Vincent; Champagne, Benoît

    2016-04-20

    A combined experimental-theoretical investigation has revealed that oxazine-based compounds are multiaddressable, multistate, and multifunctional molecular switches exhibiting contrasts of both linear and second-order nonlinear optical properties. The switching properties are particularly large when the substituent is a donor group. In this study, the cleavage of the C-O bond at the junction of the indole and oxazine cycles (of the closed a forms) is acido-triggered, leading to an open form (b(+)) characterized by larger first hyperpolarizabilities (βHRS) and smaller excitation energies than in the closed form. These results are confirmed and interpreted utilizing ab initio calculations that have been carried out on a broad set of compounds to unravel the role of the substituent. With respect to acceptor groups, oxazines bearing donor groups are characterized not only by larger βHRS and βHRS contrast ratios but also by smaller excitation energies, larger opening-induced charge transfer, and reduction of the bond length alternation, as well as smaller Gibbs energies of the opening reaction. Compared to protonated open forms (b(+)), calculations on the zwitterionic open forms (b) have pointed out similarities in the long-wavelength UV/vis absorption spectra, whereas their βHRS values might differ strongly as a function of the substituent. Indeed, the open forms present two NLOphores, the indoleninium-substituent entity and the nitrophenol (present in the protonated open form, b(+)) or nitrophenolate (present in the zwitterionic open form, b) moiety. Then, nitrophenolate displays a larger first hyperpolarizability than nitrophenol and the β tensor of the two entities might reinforce or cancel each other. PMID:26996994

  11. Second-Order Inference for the Mean of a Variable Missing at Random.

    PubMed

    Díaz, Iván; Carone, Marco; van der Laan, Mark J

    2016-05-01

    We present a second-order estimator of the mean of a variable subject to missingness, under the missing at random assumption. The estimator improves upon existing methods by using an approximate second-order expansion of the parameter functional, in addition to the first-order expansion employed by standard doubly robust methods. This results in weaker assumptions about the convergence rates necessary to establish consistency, local efficiency, and asymptotic linearity. The general estimation strategy is developed under the targeted minimum loss-based estimation (TMLE) framework. We present a simulation comparing the sensitivity of the first and second-order estimators to the convergence rate of the initial estimators of the outcome regression and missingness score. In our simulation, the second-order TMLE always had a coverage probability equal or closer to the nominal value 0.95, compared to its first-order counterpart. In the best-case scenario, the proposed second-order TMLE had a coverage probability of 0.86 when the first-order TMLE had a coverage probability of zero. We also present a novel first-order estimator inspired by a second-order expansion of the parameter functional. This estimator only requires one-dimensional smoothing, whereas implementation of the second-order TMLE generally requires kernel smoothing on the covariate space. The first-order estimator proposed is expected to have improved finite sample performance compared to existing first-order estimators. In the best-case scenario of our simulation study, the novel first-order TMLE improved the coverage probability from 0 to 0.90. We provide an illustration of our methods using a publicly available dataset to determine the effect of an anticoagulant on health outcomes of patients undergoing percutaneous coronary intervention. We provide R code implementing the proposed estimator. PMID:27227727

  12. Co-Ordinate Transformations for Second Order Systems. Part II: Elementary Structure-Preserving Transformations

    NASA Astrophysics Data System (ADS)

    Garvey, S. D.; Friswell, M. I.; Prells, U.

    2002-12-01

    It has been shown in a previous paper that there is a real-valued transformation from the general N -degree-of-freedom second order system to a second order system characterized by diagonal matrices. An immediate extension of this fact is that for any second order system, there is a set of real-valued transformations (the structure-preserving transformations) which transform this system to a different second order system having identical characteristic behaviour. There are several possible reasons why it may be very useful to achieve a particular structure in the transformed system. It is obvious that a diagonal structure is extremely useful and a method has been devised for determining the diagonalizing transformation from the solution of the usual (complex) eigenvalue-eigenvector problem. This paper begins by outlining the usefulness of some other structures. Then it defines a class of elementary structure-preserving co-ordinate transformations that transform from one N -degree-of-freedom second order system to another. The term elementary is applied because any one of these transformations is the minimum-rank modification of the identity transformation. The changes occurring in the system matrices as a result of the application of one such elementary transformation transpire to be very simple in form, they are low rank, and they can be computed very efficiently. This paper provides the fundamental tools to enable the design of structure-preserving co-ordinate transformations which transform a second order system originally characterized by three general matrices in stages into a mathematically similar second order system characterized by three diagonal matrices. The procedure by which the individual elementary transformations are obtained is still under development and it is not discussed in this paper. However, an illustration is given of a five-degree-of-freedom self-adjoint system being transformed into tridiagonal form.

  13. A second order operator splitting method for Allen-Cahn type equations with nonlinear source terms

    NASA Astrophysics Data System (ADS)

    Lee, Hyun Geun; Lee, June-Yub

    2015-08-01

    Allen-Cahn (AC) type equations with nonlinear source terms have been applied to a wide range of problems, for example, the vector-valued AC equation for phase separation and the phase-field equation for dendritic crystal growth. In contrast to the well developed first and second order methods for the AC equation, not many second order methods are suggested for the AC type equations with nonlinear source terms due to the difficulties in dealing with the nonlinear source term numerically. In this paper, we propose a simple and stable second order operator splitting method. A core idea of the method is to decompose the original equation into three subequations with the free-energy evolution term, the heat evolution term, and a nonlinear source term, respectively. It is important to combine these three subequations in proper order to achieve the second order accuracy and stability. We propose a method with a half-time free-energy evolution solver, a half-time heat evolution solver, a full-time midpoint solver for the nonlinear source term, and a half-time heat evolution solver followed by a final half-time free-energy evolution solver. We numerically demonstrate the second order accuracy of the new numerical method through the simulations of the phase separation and the dendritic crystal growth.

  14. Assessing Stability and Change in a Second-Order Confirmatory Factor Model of Meaning in Life

    PubMed Central

    Hayward, R. David

    2013-01-01

    Research indicates that meaning in life is an important correlate of health and well-being. However, relatively little is known about the way a sense of meaning may change over time. The purpose of this study is to explore two ways of assessing change in meaning within a second-order confirmatory factor analysis framework. First, tests are conducted to see if the first and second-order factor loadings and measurement error terms are invariant over time. Second, a largely overlooked technique is used to assess change and stability in meaning at the second-order level. Findings from a nationwide survey reveal that the first and second-order factor loadings are invariant of time. Moreover, the second-order measurement error terms, but not the first-order measurement error terms, are invariant, as well. The results further reveal that standard ways of assessing stability mask significant change in meaning that is due largely to regression to the mean. PMID:24778574

  15. A critical perspective on second-order empathy in understanding psychopathology: phenomenology and ethics.

    PubMed

    Rashed, Mohammed Abouelleil

    2015-04-01

    The centenary of Karl Jaspers' General Psychopathology was recognised in 2013 with the publication of a volume of essays dedicated to his work (edited by Stanghellini and Fuchs). Leading phenomenological-psychopathologists and philosophers of psychiatry examined Jaspers notion of empathic understanding and his declaration that certain schizophrenic phenomena are 'un-understandable'. The consensus reached by the authors was that Jaspers operated with a narrow conception of phenomenology and empathy and that schizophrenic phenomena can be understood through what they variously called second-order and radical empathy. This article offers a critical examination of the second-order empathic stance along phenomenological and ethical lines. It asks: (1) Is second-order empathy (phenomenologically) possible? (2) Is the second-order empathic stance an ethically acceptable attitude towards persons diagnosed with schizophrenia? I argue that second-order empathy is an incoherent method that cannot be realised. Further, the attitude promoted by this method is ethically problematic insofar as the emphasis placed on radical otherness disinvests persons diagnosed with schizophrenia from a fair chance to participate in the public construction of their identity and, hence, to redress traditional symbolic injustices. PMID:25820144

  16. Spatial Variances of Wind Fields and Their Relation to Second-Order Structure Functions and Spectra

    NASA Astrophysics Data System (ADS)

    King, G. P.; Vogelzang, J.; Stoffelen, A.; Portabella, M.

    2014-12-01

    Kinetic energy variance as a function of spatial scale for wind fields is commonly estimated either using second-order structure functions (in the spatial domain) or by spectral analysis (in the frequency domain). It will be demonstrated that neither spectra nor second-order structure functions offer a good representation of the variance as a function of scale. These difficulties can be circumvented by using a statistical quantity called spatial variance. It combines the advantages of spectral analysis and spatial statistics. In particular, when applied to observations, spatial variances have a clear interpretation and are tolerant for missing data. They can be related to second-order structure functions, both for discrete and continuous data. For data sets without missing points the relation is statistically exact. Spatial variances can also be Fourier transformed to yield a relation with spectra. The flexibility of spatial variances is used to study various sampling strategies, and to compare them with second-order structure functions and spectral variances. It is shown that the spectral sampling strategy is not seriously biased to calm conditions for scatterometer ocean surface vector winds, and that one-fifth of the second-order structure function value is a good proxy for the cumulative variance.

  17. First estimates of the second-order ionospheric effect on radio occultation observations

    NASA Astrophysics Data System (ADS)

    Vergados, Panagiotis; Pagiatakis, Spiros D.

    2010-07-01

    This study examines the impact of the second-order ionospheric effect on radio occultation (RO) data products. We propose a new linear combination between dual frequency GPS observables, which retrieves slant total electron content free from the second-order ionospheric effect. Our STEC values differ from those obtained by independent techniques by a maximum of 3 total electron content units (TECU), depending on the geographic location and geomagnetic activity. Additionally, we suggest an alternative method of computing the second-order ionospheric delay in RO experiments, which does not require the use of geomagnetic and ionospheric models. First estimates show that the second-order ionospheric delay for the RO experiments falls within the range [-10, -8] mm, which is of the same order of magnitude with second-order ionospheric delay estimates from ground-based experiments. Finally, as a by-product of our model, we retrieve weighted mean geomagnetic field values, which we compare with theoretical estimates computed by the International Geomagnetic Reference Field-10 (IGRF-10) model. Our estimations agree with the IGRF-10 model between 0.23% and 7.0%.

  18. Revisiting Hartle's model using perturbed matching theory to second order: amending the change in mass

    NASA Astrophysics Data System (ADS)

    Reina, Borja; Vera, Raül

    2015-08-01

    Hartle's model describes the equilibrium configuration of a rotating isolated compact body in perturbation theory up to second order in general relativity. The interior of the body is a perfect fluid with a barotropic equation of state, no convective motions and rigid rotation. That interior is matched across its surface to an asymptotically flat vacuum exterior. Perturbations are taken to second order around a static and spherically symmetric background configuration. Apart from the explicit assumptions, the perturbed configuration is constructed upon some implicit premises, in particular the continuity of the functions describing the perturbation in terms of some background radial coordinate. In this work we revisit the model within a modern general and consistent theory of perturbative matchings to second order, which is independent of the coordinates and gauges used to describe the two regions to be joined. We explore the matching conditions up to second order in full. The main particular result we present is that the radial function m0 (in the setting of the original work) of the second order perturbation tensor, contrary to the original assumption, presents a jump at the surface of the star, which is proportional to the value of the energy density of the background configuration there. As a consequence, the change in mass δ M needed by the perturbed configuration to keep the value of the central energy density unchanged must be amended. We also discuss some subtleties that arise when studying the deformation of the star.

  19. Democratic decisions establish stable authorities that overcome the paradox of second-order punishment

    PubMed Central

    Hilbe, Christian; Traulsen, Arne; Röhl, Torsten; Milinski, Manfred

    2014-01-01

    Individuals usually punish free riders but refuse to sanction those who cooperate but do not punish. This missing second-order peer punishment is a fundamental problem for the stabilization of cooperation. To solve this problem, most societies today have implemented central authorities that punish free riders and tax evaders alike, such that second-order punishment is fully established. The emergence of such stable authorities from individual decisions, however, creates a new paradox: it seems absurd to expect individuals who do not engage in second-order punishment to strive for an authority that does. Herein, we provide a mathematical model and experimental results from a public goods game where subjects can choose between a community with and without second-order punishment in two different ways. When subjects can migrate continuously to either community, we identify a bias toward institutions that do not punish tax evaders. When subjects have to vote once for all rounds of the game and have to accept the decision of the majority, they prefer a society with second-order punishment. These findings uncover the existence of a democracy premium. The majority-voting rule allows subjects to commit themselves and to implement institutions that eventually lead to a higher welfare for all. PMID:24367116

  20. Encoding and estimation of first- and second-order binocular disparity in natural images

    PubMed Central

    Hibbard, Paul B.; Goutcher, Ross; Hunter, David W.

    2016-01-01

    The first stage of processing of binocular information in the visual cortex is performed by mechanisms that are bandpass-tuned for spatial frequency and orientation. Psychophysical and physiological evidence have also demonstrated the existence of second-order mechanisms in binocular processing, which can encode disparities that are not directly accessible to first-order mechanisms. We compared the responses of first- and second-order binocular filters to natural images. We found that the responses of the second-order mechanisms are to some extent correlated with the responses of the first-order mechanisms, and that they can contribute to increasing both the accuracy, and depth range, of binocular stereopsis. PMID:26731646

  1. Use of the particle swarm optimization algorithm for second order design of levelling networks

    NASA Astrophysics Data System (ADS)

    Yetkin, Mevlut; Inal, Cevat; Yigit, Cemal Ozer

    2009-08-01

    The weight problem in geodetic networks can be dealt with as an optimization procedure. This classic problem of geodetic network optimization is also known as second-order design. The basic principles of geodetic network optimization are reviewed. Then the particle swarm optimization (PSO) algorithm is applied to a geodetic levelling network in order to solve the second-order design problem. PSO, which is an iterative-stochastic search algorithm in swarm intelligence, emulates the collective behaviour of bird flocking, fish schooling or bee swarming, to converge probabilistically to the global optimum. Furthermore, it is a powerful method because it is easy to implement and computationally efficient. Second-order design of a geodetic levelling network using PSO yields a practically realizable solution. It is also suitable for non-linear matrix functions that are very often encountered in geodetic network optimization. The fundamentals of the method and a numeric example are given.

  2. New second order Mumford-Shah model based on Γ-convergence approximation for image processing

    NASA Astrophysics Data System (ADS)

    Duan, Jinming; Lu, Wenqi; Pan, Zhenkuan; Bai, Li

    2016-05-01

    In this paper, a second order variational model named the Mumford-Shah total generalized variation (MSTGV) is proposed for simultaneously image denoising and segmentation, which combines the original Γ-convergence approximated Mumford-Shah model with the second order total generalized variation (TGV). For image denoising, the proposed MSTGV can eliminate both the staircase artefact associated with the first order total variation and the edge blurring effect associated with the quadratic H1 regularization or the second order bounded Hessian regularization. For image segmentation, the MSTGV can obtain clear and continuous boundaries of objects in the image. To improve computational efficiency, the implementation of the MSTGV does not directly solve its high order nonlinear partial differential equations and instead exploits the efficient split Bregman algorithm. The algorithm benefits from the fast Fourier transform, analytical generalized soft thresholding equation, and Gauss-Seidel iteration. Extensive experiments are conducted to demonstrate the effectiveness and efficiency of the proposed model.

  3. An efficient second-order projection method for viscous incompressible flow

    NASA Astrophysics Data System (ADS)

    Bell, J. B.; Howell, L. H.; Colella, P.

    1991-04-01

    In this paper we describe a second-order projection method for the time-dependent, incompressible Navier-Stokes equations. The method is a second-order fractional step scheme in which one first solves diffusion-convection equations to determine intermediate velocities which are then projected onto the space of divergence-free vector fields. The diffusion-convection step uses a specialized second-order Godunov method for differencing the nonlinear convective terms that is conservative and free-stream preserving and provides a robust treatment of the nonlinearities at high Reynolds number. The projection is based on cell-centered centered difference approximations to divergence and gradient operators with the resulting linear system solved using a multigrid relaxation scheme. We apply the method to vortex spindown in a box to validate the numerical convergence of the method and to measure its overall performance.

  4. Encoding and estimation of first- and second-order binocular disparity in natural images.

    PubMed

    Hibbard, Paul B; Goutcher, Ross; Hunter, David W

    2016-03-01

    The first stage of processing of binocular information in the visual cortex is performed by mechanisms that are bandpass-tuned for spatial frequency and orientation. Psychophysical and physiological evidence have also demonstrated the existence of second-order mechanisms in binocular processing, which can encode disparities that are not directly accessible to first-order mechanisms. We compared the responses of first- and second-order binocular filters to natural images. We found that the responses of the second-order mechanisms are to some extent correlated with the responses of the first-order mechanisms, and that they can contribute to increasing both the accuracy, and depth range, of binocular stereopsis. PMID:26731646

  5. Consistency of Equations in the Second-Order Gauge-Invariant Cosmological Perturbation Theory

    NASA Astrophysics Data System (ADS)

    Nakamura, K.

    2009-06-01

    Along the general framework of the gauge-invariant perturbation theory developed in the papers [K.~Nakamura, Prog.~Theor.~Phys. 110 (2003), 723; Prog.~Theor.~Phys. 113 (2005), 481], we rederive the second-order Einstein equation on four-dimensional homogeneous isotropic background universe in a gauge-invariant manner without ignoring any mode of perturbations. We consider the perturbations both in the universe dominated by the single perfect fluid and in that dominated by the single scalar field. We also confirmed the consistency of all the equations of the second-order Einstein equation and the equations of motion for matter fields, which are derived in the paper [K.~Nakamura, arXiv:0804.3840]. This confirmation implies that all the derived equations of the second order are self-consistent and these equations are correct in this sense.

  6. Finite element method combined with second-order time discrete scheme for nonlinear fractional Cable equation

    NASA Astrophysics Data System (ADS)

    Wang, Yajun; Liu, Yang; Li, Hong; Wang, Jinfeng

    2016-03-01

    In this article, a Galerkin finite element method combined with second-order time discrete scheme for finding the numerical solution of nonlinear time fractional Cable equation is studied and discussed. At time t_{k-α/2} , a second-order two step scheme with α -parameter is proposed to approximate the first-order derivative, and a weighted discrete scheme covering second-order approximation is used to approximate the Riemann-Liouville fractional derivative, where the approximate order is higher than the obtained results by the L1-approximation with order (2-α in the existing references. For the spatial direction, Galerkin finite element approximation is presented. The stability of scheme and the rate of convergence in L^2 -norm with O(Δ t^2+(1+Δ t^{-α})h^{m+1}) are derived in detail. Moreover, some numerical tests are shown to support our theoretical results.

  7. Second-order fluid dynamics for the unitary Fermi gas from kinetic theory

    NASA Astrophysics Data System (ADS)

    Schäfer, Thomas

    2014-10-01

    We compute second-order transport coefficients of the dilute Fermi gas at unitarity. The calculation is based on kinetic theory and the Boltzmann equation at second order in the Knudsen expansion. The second-order transport coefficients describe the shear stress relaxation time, nonlinear terms in the strain-stress relation, and nonlinear couplings between vorticity and strain. An exact calculation in the dilute limit gives τR=η /P , where τR is the shear stress relaxation time, η is the shear viscosity, and P is pressure. This relation is identical to the result obtained using the Bhatnagar-Gross-Krook approximation to the collision term, but other transport coefficients are sensitive to the exact collision integral.

  8. Time-dependent Second Order Scattering Theory for Weather Radar with a Finite Beam Width

    NASA Technical Reports Server (NTRS)

    Kobayashi, Satoru; Tanelli, Simone; Im, Eastwood; Ito, Shigeo; Oguchi, Tomohiro

    2006-01-01

    Multiple scattering effects from spherical water particles of uniform diameter are studied for a W-band pulsed radar. The Gaussian transverse beam-profile and the rectangular pulse-duration are used for calculation. An second-order analytical solution is derived for a single layer structure, based on a time-dependent radiative transfer theory as described in the authors' companion paper. When the range resolution is fixed, increase in footprint radius leads to increase in the second order reflectivity that is defined as the ratio of the second order return to the first order one. This feature becomes more serious as the range increases. Since the spaceborne millimeter-wavelength radar has a large footprint radius that is competitive to the mean free path, the multiple scattering effect must be taken into account for analysis.

  9. A Quasi-Lie Schemes Approach to Second-Order Gambier Equations

    NASA Astrophysics Data System (ADS)

    Cariñena, José F.; Guha, Partha; de Lucas, Javier

    2013-03-01

    A quasi-Lie scheme is a geometric structure that provides t-dependent changes of variables transforming members of an associated family of systems of first-order differential equations into members of the same family. In this note we introduce two quasi-Lie schemes for studying second-order Gambier equations in a geometric way. This allows us to study the transformation of these equations into simpler canonical forms, which solves a gap in the previous literature, and other relevant differential equations, which leads to derive new constants of motion for families of second-order Gambier equations. Additionally, we describe general solutions of certain second-order Gambier equations in terms of particular solutions of Riccati equations, linear systems, and t-dependent frequency harmonic oscillators.

  10. Second-order systematic errors in Mueller matrix dual rotating compensator ellipsometry.

    PubMed

    Broch, Laurent; En Naciri, Aotmane; Johann, Luc

    2010-06-10

    We investigate the systematic errors at the second order for a Mueller matrix ellipsometer in the dual rotating compensator configuration. Starting from a general formalism, we derive explicit second-order errors in the Mueller matrix coefficients of a given sample. We present the errors caused by the azimuthal inaccuracy of the optical components and their influences on the measurements. We demonstrate that the methods based on four-zone or two-zone averaging measurement are effective to vanish the errors due to the compensators. For the other elements, it is shown that the systematic errors at the second order can be canceled only for some coefficients of the Mueller matrix. The calibration step for the analyzer and the polarizer is developed. This important step is necessary to avoid the azimuthal inaccuracy in such elements. Numerical simulations and experimental measurements are presented and discussed. PMID:20539341

  11. BOTDA sensors enhanced using high-efficiency second-order distributed Brillouin amplification.

    PubMed

    Jia, Xin-Hong; Chang, Han-Qing; Ao, Lei; Ji, Xiao-Ling; Xu, Cong; Zhang, Wei-Li

    2016-06-27

    A novel approach for long-distance sensing through Brillouin optical time-domain analysis (BOTDA) assisted by second-order distributed Brillouin amplification (DBA) was proposed and experimentally demonstrated. To the best of our knowledge, this is the first BOTDA study that used second-order DBA. Compared with BOTDA assisted by first-order DBA, the proposed approach enhanced the signal-to-noise ratio of the Brillouin trace by ~3 dB for a range featuring minimum sensing intensity. Long-distance sensing with ~5 m spatial resolution and ± 1.6°C measurement uncertainty over ~99 km fiber was successfully realized by employing high-efficiency pumping using ~6 dBm second-order and ~1.5 dBm first-order pumps. PMID:27410568

  12. Shot-Noise Seeded Microbunching Instability: Second-Order Correction to the Gain Function

    SciTech Connect

    Venturini, Marco

    2008-06-30

    We determine the second-order correction to the gain function of the microbunching instability in single-pass systems of interest for the next generation of light sources. The calculation applies to the case where the instability is seeded by shot noise. We examine an analytically treatable model of beam dynamics where collective forces are active only in non-dispersive sections of the linac. We find that the second order term can augment the linear gain significantly while affecting the spectrum of the overall gain only marginally. The weight of the second-order correction relative to the linear gain is found to scale quadratically with respect to R56. The qualitative behavior predicted by the model is consistent with exact numerical solutions of the Vlasov equations for realistic lattices.

  13. Feasibility of a second-order gravitational red-shift experiment

    NASA Technical Reports Server (NTRS)

    Jaffe, J.; Vessot, R. F. C.

    1976-01-01

    The number of gravitation experiments undertaken since the advent of Einstein's theory of gravitation is quite small, with, so far, only the famous perihelion-advance experiment and a recent lunar-laser-ranging experiment being capable of measuring a nonlinear, second-order effect. It now appears that another distinct test of the second-order term may be feasible through the use of very stable atomic clocks. This experiment, which would measure the second-order gravitational red-shift, is a bona fide test of the field equations of gravity, not just a test of the underlying principle of equivalence. The nature of such an experiment, the basic equations, model-orbit calculations, and some tracking-accuracy requirements are presented. It is concluded that current space-probe tracking capabilities cannot determine all the necessary orbital parameters with sufficient accuracy for this experiment at the present time.

  14. The stability of numerical methods for second order ordinary differential equations

    NASA Technical Reports Server (NTRS)

    Gear, C. W.

    1978-01-01

    An important characterization of a numerical method for first order ODE's is the region of absolute stability. If all eigenvalues of the linear problem dy/dt = Ay are inside this region, the numerical method is stable. If the second order system d/dt(dy/dt) = 2Ady/dt - By is solved as a first order system, the same result applies to the eigenvalues of the generalized eigenvalue problem (lambda-squared)I 2(lambda)A + B. No such region exists for general methods for second order equations, but in some cases a region of absolute stability can be defined for methods for the single second order equation d/dt(dy/dt) = 2ady/dt - by. The absence of a region of absolute stability can occur when different members of a system of first order equations are solved by different methods.

  15. First- and Second-Order Full-Differential in Edge Analysis of Images

    PubMed Central

    Pu, Dong-Mei; Yuan, Yu-Bo

    2014-01-01

    Two concepts of first- and second-order differential of images are presented to deal with the changes of pixels. These are the basic ideas in mathematics. We propose and reformulate them with a uniform definition framework. Based on our observation and analysis with the difference, we propose an algorithm to detect the edge from image. Experiments on Corel5K and PASCAL VOC 2007 are done to show the difference between the first order and the second order. After comparison with Canny operator and the proposed first-order differential, the main result is that the second-order differential has the better performance in analysis of changes of the context of images with good selection of control parameter. PMID:25054162

  16. Boltzmann hierarchy for the cosmic microwave background at second order including photon polarization

    SciTech Connect

    Beneke, M.; Fidler, C.

    2010-09-15

    Non-Gaussianity and B-mode polarization are particularly interesting features of the cosmic microwave background, as--at least in the standard model of cosmology--their only sources to first order in cosmological perturbation theory are primordial, possibly generated during inflation. If the primordial sources are small, the question arises how large is the non-Gaussianity and B-mode background induced in second order from the initially Gaussian and scalar perturbations. In this paper we derive the Boltzmann hierarchy for the microwave background photon phase-space distributions at second order in cosmological perturbation theory including the complete polarization information, providing the basis for further numerical studies. As an aside we note that the second-order collision term contains new sources of B-mode polarization and that no polarization persists in the tight-coupling limit.

  17. Observation of second order ion acoustic Peregrine breather in multicomponent plasma with negative ions

    NASA Astrophysics Data System (ADS)

    Pathak, Pallabi; Sharma, S. K.; Nakamura, Y.; Bailung, H.

    2016-02-01

    The experimental observation of second order ion acoustic Peregrine breathers in multicomponent plasma with negative ions is reported. A long wavelength initial perturbation on a continuous carrier frequency ˜0.5 ωpi (where ωpi is the ion plasma frequency) of finite amplitude is found to undergo self-modulation due to the interplay between nonlinear dispersive effect and group velocity dispersion because of modulational instability. Wave energy focusses to a smaller localized and isolated group of waves within the packet with amplitude amplification up to 5 times of the background carrier wave. The experimental results are compared with second order breather solution of nonlinear Schrodinger equation. The wavelet analysis and fast Fourier transform analysis of the experimental time series data indicate strong nonlinear evolution (wave energy focusing and spectral broadening) conforming to the formation of second order Peregrine solitons.

  18. First- or second-order transition in the melting of repeat sequence DNA.

    PubMed Central

    Chen, Y Z; Prohofsky, E W

    1994-01-01

    Both theoretical analysis and observation of the continuity of the melted fraction of base pairs indicate that the melting transition in DNA is second order. Analysis of the salt dependence of the transition by polyelectrolyte limiting laws, however, has first-order dynamics imbedded in the analysis. This paper proposes that the observation taken to be a latent heat of melting in the limiting law analysis could instead be a specific heat anomaly associated with a second-order transition. The limiting laws can be reconstructed based on a second-order transition with a specific heat anomaly. The T2M dependence of this excess heat is also consistent with its being a specific heat anomaly of a system displaying classical critical behavior. Classical critical behavior indicates that theoretical mean field approaches such as MSPA should be particularly appropriate to helix melting studies. PMID:8130338

  19. Second-order radio frequency kinetic theory revisited: Resolving inconsistency with conventional fluid theory

    SciTech Connect

    Chen, Jiale; Gao, Zhe

    2013-08-15

    The second-order velocity distribution function was calculated from the second-order rf kinetic theory [Jaeger et al., Phys. Plasmas 7, 641 (2000)]. However, the nonresonant ponderomotive force in the radial direction derived from the theory is inconsistent with that from the fluid theory. The inconsistency arises from that the multiple-timescale-separation assumption fails when the second-order Vlasov equation is directly integrated along unperturbed particle orbits. A slowly ramped wave field including an adiabatic turn-on process is applied in the modified kinetic theory in this paper. Since this modification leads only to additional reactive/nonresonant response relevant with the secular resonant response from the previous kinetic theory, the correct nonresonant ponderomotive force can be obtained while all the resonant moments remain unchanged.

  20. Second order incommensurate phase transition in 25L-Ta{sub 2}O{sub 5}

    SciTech Connect

    Audier, M.; Chenevier, B.; Roussel, H.; Lintanf Salauen, A.

    2010-09-15

    A new structural state 25L-Ta{sub 2}O{sub 5}, obtained from sintering and annealing treatments of a Ta{sub 2}O{sub 5} powder, is identified both by electron diffraction and high resolution imaging on a transmission electron microscope (TEM). According to general rules for the different L-Ta{sub 2}O{sub 5} structures proposed by Grey et al. (J. Solid State Chem. 178 (2005) 3308), a structural model is derived from their crystallographic data on 19L-Ta{sub 2}O{sub 5}. This model yields simulated images in agreement with high resolution TEM observations of the structure oriented along its [001] zone axis, but only for a very thin crystal thickness of less than 1.2 nm. Such a limitation is shown to be due to a modulation of the structure along its [001] axis. Actually, from an analysis of a diffuse scattering and of its evolution into satellites reflections as a function of the cooling rate, a second order incommensurate phase transition can be assumed to occur in this compound. The property of single phase samples observed by TEM is also verified by X-ray powder diffraction. In a discussion about studies performed by different authors on incommensurate structures in the system Ta{sub 2}O{sub 5}-WO{sub 3}, it is noticed that TEM results, similar to ours, indicate that phase transitions could be expected in these structures. - Graphical Abstract: Electron diffraction patterns of [100] zone axis, showing a structural change of the 25L-Ta{sub 2}O{sub 5} phase through a variation of the cooling rate from 1000 {sup o}C.

  1. Enhancement and investigation of second-order nonlinearity through rational design and organic synthesis

    NASA Astrophysics Data System (ADS)

    Davies, Joshua A.

    2009-12-01

    Since the turn of the century, continued research in the field of organic electrooptics (EO) has led to an enormous amount of progress in terms of bulk second-order nonlinear optical response. However, as of late, fundamental research in chromophore structure-property relationships and optimization of molecular hyperpolarizability through new approaches certainly does not get the consideration it is warranted despite having a significant contribution to the present success in the realm of EO. Guided through the use of sophisticated quantum mechanical modeling and classic design paradigms, materials were engineered in an attempt to further increase first-order hyperpolarizability (beta) above and beyond state-of-the-art materials through the use of novel heteroaryl-based electron donors and acceptors. The unprecedented degree of polarization in these neutral ground state chromophores, which resulted from lower ionization potentials and aromaticities, was extensively explored, both analytically and theoretically. In one new class of chromophores, an increase in electron-donor strength was off-set by the resistivity towards polarization caused by the divinylthienyl bridge. This led to an excellent balance in asymmetry and polarizability, and thus large beta. However, when these heteroaryl donors were incorporated into ring-locked tetraene bridges, the strong electron-donors were believed to have polarized the highly efficient bridges beyond optimal beta. Finally, ground work has been laid out for the application of all-optical, and optically assisted poling of a class of second generation, high beta, azo-based chromophores as an alternate means of improving poling induced order.

  2. Ethanol induces second-order aversive conditioning in adolescent and adult rats

    PubMed Central

    Pautassi, Ricardo Marcos; Myers, Mallory; Spear, Linda Patia; Molina, Juan Carlos; Spear, Norman E.

    2011-01-01

    Alcohol abuse and dependence is considered a developmental disorder with etiological onset during late childhood and adolescence, and understanding age-related differences in ethanol sensitivity is important. Low to moderate ethanol doses (0.5 and 2.0 g/kg, i.g.) induce single-trial, appetitive second-order place conditioning (SOC) in adolescent, but not adult, rats. Recent studies have demonstrated that adolescents may be less sensitive than adults to the aversive properties of ethanol, reflected by conditioned taste aversion. The present study assessed the aversive motivational effects of high-dose ethanol (3.0 and 3.25 g/kg, i.g., for adolescent and adults, respectively) using SOC. These doses were derived from Experiment 1, which found similar blood and brain ethanol levels in adolescent and adult rats given 3.0 and 3.25 g/kg ethanol, respectively. In Experiment 2, animals received ethanol or vehicle paired with intraoral pulses of sucrose (conditioned stimulus 1 [CS1]). After one, two, or three conditioning trials, rats were presented with the CS1 while in a distinctive chamber (CS2). When tested for CS2 preference, ethanol-treated animals exhibited reduced preference for the CS2 compared with controls. This result, indicative of ethanol-mediated aversive place conditioning, was similar for adolescents and adults, for females and males, and after one, two, or three training trials. One finding, however, suggested that adolescents were less sensitive than adults to ethanol’s aversive effects at the intermediate level of training. In conjunction with previous results, the present study showed that in adolescent rats subjected to SOC, ethanol’s hedonic effects vary from appetitive to aversive as the ethanol dose increases. Adolescent and adult animals appear to perceive the post-ingestive effects of high-dose ethanol as similarly aversive when assessed by SOC. PMID:21187242

  3. Stability and accuracy analysis of some fully-discrete algorithms for the one-dimensional second-order wave equation

    NASA Technical Reports Server (NTRS)

    Hughes, T. J. R.; Tezduyar, T. E.

    1984-01-01

    The present investigation is concerned with some basic results for a predictor-multicorrector algorithm applied to the one-dimensional wave equation, giving particular attention to so-called 2-pass explicit schemes in which both lumped and coupled mass matrices are employed. In an assessment of the accuracy and stability properties of the algorithms, use is made of the one-dimensional, second-order wave equation. The maximum stable time step of the lumped right-hand-side mass, 2-pass explicit algorithm is twice that of the 1-pass explicit algorithm. Improved accuracy is obtained by employing higher-order, or consistent, right-hand-side, mass.

  4. Observed galaxy number counts on the lightcone up to second order: I. Main result

    SciTech Connect

    Bertacca, Daniele; Maartens, Roy; Clarkson, Chris E-mail: roy.maartens@gmail.com

    2014-09-01

    We present the galaxy number overdensity up to second order in redshift space on cosmological scales for a concordance model. The result contains all general relativistic effects up to second order that arise from observing on the past light cone, including all redshift effects, lensing distortions from convergence and shear, and contributions from velocities, Sachs-Wolfe, integrated SW and time-delay terms. This result will be important for accurate calculation of the bias on estimates of non-Gaussianity and on precision parameter estimates, introduced by nonlinear projection effects.

  5. Ambient temperature normalization for infrared face recognition based on the second-order polynomial model

    NASA Astrophysics Data System (ADS)

    Wang, Zhengzi

    2015-08-01

    The influence of ambient temperature is a big challenge to robust infrared face recognition. This paper proposes a new ambient temperature normalization algorithm to improve the performance of infrared face recognition under variable ambient temperatures. Based on statistical regression theory, a second order polynomial model is learned to describe the ambient temperature's impact on infrared face image. Then, infrared image was normalized to reference ambient temperature by the second order polynomial model. Finally, this normalization method is applied to infrared face recognition to verify its efficiency. The experiments demonstrate that the proposed temperature normalization method is feasible and can significantly improve the robustness of infrared face recognition.

  6. Second-order infinitesimal bendings of surfaces of revolution with flattening at the poles

    NASA Astrophysics Data System (ADS)

    Sabitov, I. Kh

    2014-12-01

    We study infinitesimal bendings of surfaces of revolution with flattening at the poles. We begin by considering the minimal possible smoothness class C^1 both for surfaces and for deformation fields. Conditions are formulated for a given harmonic of a first-order infinitesimal bending to be extendable into a second order infinitesimal bending. We finish by stating a criterion for nonrigidity of second order for closed surfaces of revolution in the analytic class. We also give the first concrete example of such a nonrigid surface. Bibliography: 15 entries.

  7. Second-order explicit finite-difference methods for transient-flow analysis

    NASA Technical Reports Server (NTRS)

    Chaudhry, M. H.; Hussaini, M. Y.

    1983-01-01

    Three second-order accurate numerical methods - MacCormack's method, Lambda scheme and Gabutti scheme - are introduced to solve the quasi-linear, hyperbolic partial differential equations describing transient flows in closed conduits. The details of these methods and the treatment of boundary conditions are presented and the results computed by using these methods for a typical piping system are compared. It is shown that for the same accuracy, second-order methods require considerably lesser number of computational nodes and computer time as compared to those required by the first-order methods.

  8. Second-order discrete Kalman filtering equations for control-structure interaction simulations

    NASA Technical Reports Server (NTRS)

    Park, K. C.; Belvin, W. Keith; Alvin, Kenneth F.

    1991-01-01

    A general form for the first-order representation of the continuous, second-order linear structural dynamics equations is introduced in order to derive a corresponding form of first-order Kalman filtering equations (KFE). Time integration of the resulting first-order KFE is carried out via a set of linear multistep integration formulas. It is shown that a judicious combined selection of computational paths and the undetermined matrices introduced in the general form of the first-order linear structural systems leads to a class of second-order discrete KFE involving only symmetric, N x N solution matrix.

  9. Discrete integration of continuous Kalman filtering equations for time invariant second-order structural systems

    NASA Technical Reports Server (NTRS)

    Park, K. C.; Belvin, W. Keith

    1990-01-01

    A general form for the first-order representation of the continuous second-order linear structural-dynamics equations is introduced to derive a corresponding form of first-order continuous Kalman filtering equations. Time integration of the resulting equations is carried out via a set of linear multistep integration formulas. It is shown that a judicious combined selection of computational paths and the undetermined matrices introduced in the general form of the first-order linear structural systems leads to a class of second-order discrete Kalman filtering equations involving only symmetric sparse N x N solution matrices.

  10. Second-order infinitesimal bendings of surfaces of revolution with flattening at the poles

    SciTech Connect

    Sabitov, I Kh

    2014-12-31

    We study infinitesimal bendings of surfaces of revolution with flattening at the poles. We begin by considering the minimal possible smoothness class C{sup 1} both for surfaces and for deformation fields. Conditions are formulated for a given harmonic of a first-order infinitesimal bending to be extendable into a second order infinitesimal bending. We finish by stating a criterion for nonrigidity of second order for closed surfaces of revolution in the analytic class. We also give the first concrete example of such a nonrigid surface. Bibliography: 15 entries.

  11. A solvatochromic method for determining second-order polarizabilities of organic molecules

    SciTech Connect

    Paley, M.S.; Harris, J.M. ); Looser, H.; Baumert, J.C.; Bjorklund, G.C.; Jundt, D.; Twieg, R.J. )

    1989-08-04

    A simple experimental method for determining optical second-order polarizabilities of organic molecules for second harmonic generation (SHG) is developed by using a two-level quantum mechanical model. Required values of excited-state dipole moments are obtained from a solvatochromic method based on the theoretical treatment of McRae. Second-order polarizabilities obtained by this method for a series of compounds compare well with those obtained by the conventional EFISH technique. The solvatochromic method has the important advantage that measurements can be made rapidly with simple equipment available in most chemistry laboratories.

  12. Effective second-order susceptibility in photonic crystals mode of centrosymmetric materials

    NASA Astrophysics Data System (ADS)

    Feigel, A.; Kotler, Z.; Sfez, B.

    2002-02-01

    A technique for obtaining efficient bulk second-order susceptibility in noncentrosymmetric photonic crystals (PC) made of centrosymmetric materials is discussed. The effect is based on the electric quadrupole effect, strong electromagnetic mode deformation, and nonhomogeneous contribution to volume polarization from different parts of the PC. The required symmetry breaking is introduced on the macroscale of the PC unit cell. The obtained structural χ(2)str is comparable with the second-order susceptibility of ordinary nonlinear materials. Phase matching can be achieved by introducing symmetry modulation (quasi-phase-matching) during fabrication of the PC.

  13. Imaging of biological tissues with pixel-level analysis of second-order susceptibility

    NASA Astrophysics Data System (ADS)

    Hu, Po-Sheng; Ghazaryan, Ara; Hovhannisyan, Vladimir; Chen, Shean-Jen; Chen, Yang-Fang; Kim, Chang-Seok; Tsai, Tsung-Hua; Dong, Chen-Yuan

    2013-03-01

    We discuss the recent advances in the development and applications of second-order susceptibility as a contrast mechanism in optical microscopy for biological tissues. We review nonlinear optical methods and approaches for differentiation of tissue structures and discrimination of normal and pathological skin tissues, which have been demonstrated for the potential use in clinical diagnosis. In addition, the potential of second-order susceptibility imaging, encompassing applications in differentiating various types of collagen molecules for clinical diagnosis, is demonstrated. Finally, we discuss future development and application of this technique.

  14. Using unknown input observers for robust adaptive fault detection in vector second-order systems

    NASA Astrophysics Data System (ADS)

    Demetriou, Michael A.

    2005-03-01

    The purpose of this manuscript is to construct natural observers for vector second-order systems by utilising unknown input observer (UIO) methods. This observer is subsequently used for a robust fault detection scheme and also as an adaptive detection scheme for a certain class of actuator faults wherein the time instance and characteristics of an incipient actuator fault are detected. Stability of the adaptive scheme is provided by a parameter-dependent Lyapunov function for second-order systems. Numerical example on a mechanical system describing an automobile suspension system is used to illustrate the theoretical results.

  15. Robust controller designs for second-order dynamic systems - A virtual passive approach

    NASA Technical Reports Server (NTRS)

    Juang, Jer-Nan; Phan, Minh

    1991-01-01

    A robust controller design is presented for second-order dynamic systems. The controller is model-independent and itself is a virtual second-order dynamic system. Conditions on actuator and sensor placements are identified for controller designs that guarantee overall closed-loop stability. The dynamic controller can be viewed as a virtual passive damping system that serves to stabilize the actual dynamic system. The control gians are interpreted as virtual mass, spring, and dashpot elements that play the same roles as actual physical elements in stability analysis. Position, velocity, and acceleration feedback are considered. Simple examples are provided to illustrate the physical meaning of this controller design.

  16. Robust controller designs for second-order dynamic system: A virtual passive approach

    NASA Technical Reports Server (NTRS)

    Juang, Jer-Nan; Phan, Minh

    1990-01-01

    A robust controller design is presented for second-order dynamic systems. The controller is model-independent and itself is a virtual second-order dynamic system. Conditions on actuator and sensor placements are identified for controller designs that guarantee overall closed-loop stability. The dynamic controller can be viewed as a virtual passive damping system that serves to stabilize the actual dynamic system. The control gains are interpreted as virtual mass, spring, and dashpot elements that play the same roles as actual physical elements in stability analysis. Position, velocity, and acceleration feedback are considered. Simple examples are provided to illustrate the physical meaning of this controller design.

  17. A general model of resonance capture in planetary systems: first- and second-order resonances

    NASA Astrophysics Data System (ADS)

    Mustill, Alexander J.; Wyatt, Mark C.

    2011-05-01

    Mean motion resonances are a common feature of both our own Solar system and of extrasolar planetary systems. Bodies can be trapped in resonance when their orbital semimajor axes change, for instance when they migrate through a protoplanetary disc. We use a Hamiltonian model to thoroughly investigate the capture behaviour for first- and second-order resonances. Using this method, all resonances of the same order can be described by one equation, with applications to specific resonances by appropriate scaling. We focus on the limit where one body is a massless test particle and the other a massive planet. We quantify how the probability of capture into a resonance depends on the relative migration rate of the planet and particle, and the particle's eccentricity. Resonant capture fails for high migration rates, and has decreasing probability for higher eccentricities, although for certain migration rates, capture probability peaks at a finite eccentricity. More massive planets can capture particles at higher eccentricities and migration rates. We also calculate libration amplitudes and the offset of the libration centres for captured particles, and the change in eccentricity if capture does not occur. Libration amplitudes are higher for larger initial eccentricity. The model allows for a complete description of a particle's behaviour as it successively encounters several resonances. Data files containing the integration grid output will be available online. We discuss implications for several scenarios: (i) Planet migration through gas discs trapping other planets or planetesimals in resonances: we find that, with classical prescriptions for Type I migration, capture into second-order resonances is not possible, and lower mass planets or those further from the star should trap objects in first-order resonances closer to the planet than higher mass planets or those closer to the star. For fast enough migration, a planet can trap no objects into its resonances. We

  18. Second-order theories for extensional vibrations of piezoelectric crystal plates and strips.

    PubMed

    Lee, Peter C Y; Edwards, Nicholas P; Lin, Wen-Sen; Syngellakis, Stavros

    2002-11-01

    An infinite system of two-dimensional (2-D) equations for piezoelectric plates with general symmetry and faces in contact with vacuum is derived from the 3-D equations of linear piezoelectricity in a manner similar to that of previous work, in which an infinite system of 2-D equations for plates with electroded faces was derived. By using a new truncation procedure, second-order equations for piezoelectric plates with faces in contact with either vacuums or electrodes are extracted from the aforementioned infinite systems of equations, respectively. The second-order equations for plates with or without electrodes are shown to predict accurate dispersion curves by comparing to the corresponding curves from the 3-D equations in a range up to the cut-off frequencies of the first symmetric thickness-stretch and the second symmetric thickness-shear modes without introducing any correction factors. Furthermore, a system of 1-D second-order equations for strips with rectangular cross section is deduced from the 2-D second-order equations by averaging variables across the narrow width of the plate. The present 1-D equations are used to study the extensional vibrations of barium titanate strips of finite length and narrow rectangular cross section. Predicted frequency spectra are compared with previously calculated results and experimental data. PMID:12484472

  19. Evidence of Second-Order Factor Structure in a Diagnostic Problem Space: Implications for Medical Education.

    ERIC Educational Resources Information Center

    Papa, Frank J.; And Others

    1997-01-01

    Chest pain was identified as a specific medical problem space, and disease classes were modeled to define it. Results from a test taken by 628 medical residents indicate a second-order factor structure that suggests that chest pain is a multidimensional problem space. Implications for medical education are discussed. (SLD)

  20. Solving Second-Order Ordinary Differential Equations without Using Complex Numbers

    ERIC Educational Resources Information Center

    Kougias, Ioannis E.

    2009-01-01

    Ordinary differential equations (ODEs) is a subject with a wide range of applications and the need of introducing it to students often arises in the last year of high school, as well as in the early stages of tertiary education. The usual methods of solving second-order ODEs with constant coefficients, among others, rely upon the use of complex…

  1. ALTERNATIVE NONLINEAR MODEL FOR ESTIMATING SECOND-ORDER RATE COEFFICIENTS FOR BIODEGRADATION

    EPA Science Inventory

    A modification of the second-order model for biodegradation was derived, applied to an example data set and shown to be superior for describing the anaerobic biodegradation of p-cresol by an enriched bacterial consortium. The modified model circumvents the no-growth assumption im...

  2. Multidimensional first and second order symmetric strang splitting for hyperbolic systems

    SciTech Connect

    Kucharik, Milan; Wendroff, Burton

    2008-01-01

    We propose an algebraic basis for symmetric Strang splitting for first and second order accurate schemes for hyperbolic systems in N dimensions. Examples are given for two and three dimensions. Optimal stability is shown for symmetric systems. Lack of strong stability is shown for a non-symmetric example. Some numerical examples are presented for some Euler-like constant coefficient problems.

  3. Second-order magnetic critical points at finite magnetic fields: Revisiting Arrott plots

    NASA Astrophysics Data System (ADS)

    Bustingorry, S.; Pomiro, F.; Aurelio, G.; Curiale, J.

    2016-06-01

    The so-called Arrott plot, which consists in plotting H /M against M2, with H the applied magnetic field and M the magnetization, is used to extract valuable information in second-order magnetic phase transitions. Besides, it is widely accepted that a negative slope in the Arrott plot is indicative of a first-order magnetic transition. This is known as the Banerjee criterion. In consequence, the zero-field transition temperature T* is reported as the characteristic first-order transition temperature. By carefully analyzing the mean-field Landau model used for studying first-order magnetic transitions, we show in this work that T* corresponds in fact to a triple point where three first-order lines meet. More importantly, this analysis reveals the existence of two symmetrical second-order critical points at finite magnetic field (Tc,±Hc) . We then show that a modified Arrott plot can be used to obtain information about these second-order critical points. To support this idea we analyze experimental data on La2 /3Ca1 /3MnO3 and discuss an estimate for the location of the triple point and the second-order critical points.

  4. Second-order cascading in third-order nonlinear optical processes

    NASA Astrophysics Data System (ADS)

    Meredith, Gerald R.

    1982-12-01

    Because cascaded second-order processes make substantial qualitative and quanitative differences to the results of third-order nonlinear optical experiments, a formalism for their treatment is presented. The symmetry dictates concerning the occurrence and relationships of magnitudes of cascading are tabulated for the higher symmetry crystal classes. Angular momentum considerations are applied to the situations allowing circularly polarized light waves.

  5. Second-order effects of parasitic resistances on the efficiency of solar cells

    NASA Astrophysics Data System (ADS)

    Easwarakhantan, T.; Nguyen, P. H.; Es-Slassi, A.; Ravelet, S.

    1984-11-01

    A simplified expression is developed for analyzing the performance of solar cells. An iterative solution is obtained for the cell efficiency and carried out to second-order to account for the resistance and shunt conductance of cells connected in series. A third-order truncation error is derived and found to be negligible. The model is amenable to BASIC programming on a microcomputer.

  6. Computer Simulation for Calculating the Second-Order Correlation Function of Classical and Quantum Light

    ERIC Educational Resources Information Center

    Facao, M.; Lopes, A.; Silva, A. L.; Silva, P.

    2011-01-01

    We propose an undergraduate numerical project for simulating the results of the second-order correlation function as obtained by an intensity interference experiment for two kinds of light, namely bunched light with Gaussian or Lorentzian power density spectrum and antibunched light obtained from single-photon sources. While the algorithm for…

  7. DECAY OF DISSOLVED SUBSTANCES BY SECOND-ORDER REACTION: PROBLEM DESCRIPTION AND BATCH-REACTOR SOLUTIONS

    EPA Science Inventory

    The mass transport (advection-dispersion) equations allowing coupled second-order reaction (i.e. Omega sub 1, C sub 1) + (omega sub 2, C sub 2) (R sub 12) -> Re) between two constituents are derived and result in a set of coupled nonlinear partial differential equations. Neglecti...

  8. Lie symmetries of systems of second-order linear ordinary differential equations with constant coefficients.

    PubMed

    Boyko, Vyacheslav M; Popovych, Roman O; Shapoval, Nataliya M

    2013-01-01

    Lie symmetries of systems of second-order linear ordinary differential equations with constant coefficients are exhaustively described over both the complex and real fields. The exact lower and upper bounds for the dimensions of the maximal Lie invariance algebras possessed by such systems are obtained using an effective algebraic approach. PMID:23564972

  9. A novel unsplit perfectly matched layer for the second-order acoustic wave equation.

    PubMed

    Ma, Youneng; Yu, Jinhua; Wang, Yuanyuan

    2014-08-01

    When solving acoustic field equations by using numerical approximation technique, absorbing boundary conditions (ABCs) are widely used to truncate the simulation to a finite space. The perfectly matched layer (PML) technique has exhibited excellent absorbing efficiency as an ABC for the acoustic wave equation formulated as a first-order system. However, as the PML was originally designed for the first-order equation system, it cannot be applied to the second-order equation system directly. In this article, we aim to extend the unsplit PML to the second-order equation system. We developed an efficient unsplit implementation of PML for the second-order acoustic wave equation based on an auxiliary-differential-equation (ADE) scheme. The proposed method can benefit to the use of PML in simulations based on second-order equations. Compared with the existing PMLs, it has simpler implementation and requires less extra storage. Numerical results from finite-difference time-domain models are provided to illustrate the validity of the approach. PMID:24794509

  10. First-Order or Second-Order Kinetics? A Monte Carlo Answer

    ERIC Educational Resources Information Center

    Tellinghuisen, Joel

    2005-01-01

    Monte Carlo computational experiments reveal that the ability to discriminate between first- and second-order kinetics from least-squares analysis of time-dependent concentration data is better than implied in earlier discussions of the problem. The problem is rendered as simple as possible by assuming that the order must be either 1 or 2 and that…

  11. Independence of First- and Second-Order Memories in Newborn Rabbits

    ERIC Educational Resources Information Center

    Coureaud, Gerard; Languille, Solene; Joly, Virginie; Schaal, Benoist; Hars, Bernard

    2011-01-01

    The mammary pheromone promotes the acquisition of novel odorants (CS1) in newborn rabbits. Here, experiments pinpoint that CS1 becomes able to support neonatal learning of other odorants (CS2). We therefore evaluated whether these first- and second-order memories remained dependent after reactivation. Amnesia induced after CS2 recall selectively…

  12. Second-order optical filter based on a mirrored gradient index lens.

    PubMed

    Liang, W; Savchenkov, A A; Matsko, A B; Ilchenko, V S; Seidel, D; Maleki, L

    2010-07-15

    We demonstrate a second-order bandpass filter using a single gradient index lens (GRIN) coated with mirrors. The filter becomes possible because of the residual and externally introduced small birefringence of the GRIN lens material. We show that the filter function can be trimmed by mechanical strain of the lens. Applications of the filter in microwave photonics are discussed. PMID:20634829

  13. Navier-Stokes computation of compressible turbulent flows with a second order closure, part 1

    NASA Technical Reports Server (NTRS)

    Haminh, Hieu; Kollmann, Wolfgang; Vandromme, Dany

    1990-01-01

    A second order closure turbulence model for compressible flows is developed and implemented in a 2D Reynolds-averaged Navier-Stokes solver. From the beginning where a kappa-epsilon turbulence model was implemented in the bidiagonal implicit method of MACCORMACK (referred to as the MAC3 code) to the final stage of implementing a full second order closure in the efficient line Gauss-Seidel algorithm, numerous work was done, individually and collectively. Besides the collaboration itself, the final product of this work is a second order closure derived from the Launder, Reece, and Rodi model to account for near wall effects, which has been called FRAME model, which stands for FRench-AMerican-Effort. During the reporting period, two different problems were worked out. The first was to provide Ames researchers with a reliable compressible boundary layer code including a wide collection of turbulence models for quick testing of new terms, both in two equations and in second order closure (LRR and FRAME). The second topic was to complete the implementation of the FRAME model in the MAC5 code. The work related to these two different contributions is reported. dilatation in presence of stron shocks. This work, which has been conducted during a work at the Center for Turbulence Research with Zeman aimed also to cros-check earlier assumptions by Rubesin and Vandromme.

  14. Can Reflection Be Confined into Roles? First and Second Order Research in Action Research.

    ERIC Educational Resources Information Center

    Losito, Bruno; Pozzo, Graziella; Somekh, Bridget

    The distinction between first-order and second-order research in action research is explored in the context of work on the Management for Organizational and Human Development (MOHD) project in Italy. Researchers worked with two groups of heads of primary schools in Italy to develop a path of reflection and research on their roles and functions and…

  15. Concurrent Second-Order Schedules: Some Effects of Variations in Response Number and Duration

    ERIC Educational Resources Information Center

    Sealey, Diane M.; Sumpter, Catherine E.; Temple, W.; Foster, T. Mary

    2005-01-01

    To examine the effects on concurrent performance of independent manipulations of response-unit duration and number, 6 hens were exposed to concurrent second- order schedules of reinforcement. Each first-order operant unit required completion of a fixed-ratio schedule within the time specified by a fixed- interval schedule, with one further…

  16. Validity of a Measure of Children's Health Locus of Control: A Second-Order Factor Analysis.

    ERIC Educational Resources Information Center

    Thompson, Bruce; And Others

    The study reported in this paper investigated the structure of the health locus of control beliefs of elementary school children using second-order factor analysis and the measurement characteristics of the Multidimensional Health Locus of Control (MHLC) Scales. Changes of wording were made in 10 of the MHLC Scales items in order to improve the…

  17. Time domain reflectometry waveform analysis with second order bounded mean oscillation

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Tangent-line methods and adaptive waveform interpretation with Gaussian filtering (AWIGF) have been proposed for determining reflection positions of time domain reflectometry (TDR) waveforms. However, the accuracy of those methods is limited for short probe TDR sensors. Second order bounded mean osc...

  18. Temporal Frequency Modulates Reaction Time Responses to First-Order and Second-Order Motion

    ERIC Educational Resources Information Center

    Hutchinson, Claire V.; Ledgeway, Tim

    2010-01-01

    This study investigated the effect of temporal frequency and modulation depth on reaction times for discriminating the direction of first-order (luminance-defined) and second-order (contrast-defined) motion, equated for visibility using equal multiples of direction-discrimination threshold. Results showed that reaction times were heavily…

  19. Direct measurement of second-order coupling in a waveguide lattice

    NASA Astrophysics Data System (ADS)

    Keil, Robert; Pressl, Benedikt; Heilmann, René; Gräfe, Markus; Weihs, Gregor; Szameit, Alexander

    2015-12-01

    We measure the next-nearest-neighbour coupling in an array of coupled optical waveguides directly via an integrated eigenmode interferometer. In contrast to light propagation experiments, the technique is insensitive to nearest-neighbour dynamics. Our results show that second-order coupling in a linear configuration can be suppressed well below the level expected from the exponential decay of the guided modes.

  20. The Green's function of the second order differential operator with an involution and its application

    NASA Astrophysics Data System (ADS)

    Sarsenbi, Abdizhahan

    2015-09-01

    In this paper, the Green's function of a boundary boundary value problem with an involution is constructed. Applying the Green's function, a formula for expansion in the eigenfunctions of the spectral problem for a second order differential equation with an involution involving boundary conditions of Dirichlet type is presented.

  1. Sample Sizes for Two-Group Second-Order Latent Growth Curve Models

    ERIC Educational Resources Information Center

    Wanstrom, Linda

    2009-01-01

    Second-order latent growth curve models (S. C. Duncan & Duncan, 1996; McArdle, 1988) can be used to study group differences in change in latent constructs. We give exact formulas for the covariance matrix of the parameter estimates and an algebraic expression for the estimation of slope differences. Formulas for calculations of the required sample…

  2. Calculation of laminar flows with second-order schemes and collocated variable arrangement

    NASA Astrophysics Data System (ADS)

    Biagioli, Fernando

    1998-04-01

    A numerical study of laminar flows is carried out to examine the performance of two second-order discretization schemes: a total variation diminishing scheme and a second-order upwind scheme. The former has the same form as the standard first-order hybrid central upwind scheme, but with a numerical diffusion reduced by the Van Leer limiter; the latter is based on the linear extrapolation of cell face values using the two upwind neighbors. A collocated grid arrangement is used; oscillations which could be generated by pressure-velocity decoupling are avoided via the Rhie-Chow interpolation. Two iterative solution methods are used: (i) the deferred correction procedure proposed by Khosla and Rubin and (ii) implicit treatment of the second-order upwind contribution. Three two-dimensional laminar test cases are considered for assessment: the plane lid-driven cavity, the plane backward facing step and the axisymmetric pipe with sudden contraction. Experimental data are available for the two last cases. Both the total variation diminishing and the second-order upwind schemes give wiggle-free results and can predict the flowfields more accurately than the standard first-order hybrid central upwind scheme.

  3. Control by Contextual Stimuli in Novel Second-Order Conditional Discriminations

    ERIC Educational Resources Information Center

    Perez-Gonzalez, Luis Antonio; Martinez, Hector

    2007-01-01

    Eighteen undergraduates participated in studies designed to examine the factors that produce transfer of contextual functions to novel stimuli in second-order conditional discriminations. In Study 1, participants selected comparison B1 given sample A1 and comparison B2 given sample A2 in a matching-to-sample procedure. Contextual stimuli X1 or X2…

  4. Positronium formation as a three-body reaction. II. The second-order nuclear amplitudes

    SciTech Connect

    Shojaei, F.; Bolorizadeh, M. A.; Ghanbari-Adivi, E.; Brunger, M. J.

    2009-01-15

    We derive an exact analytic form for the second-order nuclear amplitudes, under the Faddeev three-body approach, which is applicable to the nonrelativistic high energy impact interaction where positronium is formed in the collision of a positron with an atom.

  5. Employment of Second Order Ruled Surfaces in Design of Sheet Beam Guns

    SciTech Connect

    Krasnykh, Anatoly; /SLAC

    2007-03-05

    A novel 3D method of sheet beam gun design has recently been developed. Second order ruled surfaces (SORS) can be used to define the geometry of the gun electrodes. The gun design process is made simpler if SORS are derived from analytical formulas. A proposed method is discussed and illustrated.

  6. On types of the resolvent of a complete second order differential operator

    SciTech Connect

    Ospanov, Kordan Nauryzkhanovich

    2015-09-18

    In this work we consider the complete second order differential operator, the intermediate coefficient of which is growing rapidly. We find the conditions when its resolvent is compact or belongs to Schatten class, in particular, it is a nuclear operator. The most accurate results are obtained when the coefficient oscillates weakly. In this case we shown that the operator is separable.

  7. Oscillation criteria for second order forced ordinary differential equations with mixed nonlinearities

    NASA Astrophysics Data System (ADS)

    Sun, Yuan Gong; Wong, James S. W.

    2007-10-01

    We present new oscillation criteria for the second order forced ordinary differential equation with mixed nonlinearities: where , p(t) is positive and differentiable, [alpha]1>...>[alpha]m>1>[alpha]m+1>...>[alpha]n. No restriction is imposed on the forcing term e(t) to be the second derivative of an oscillatory function. When n=1, our results reduce to those of El-Sayed [M.A. El-Sayed, An oscillation criterion for a forced second order linear differential equation, Proc. Amer. Math. Soc. 118 (1993) 813-817], Wong [J.S.W. Wong, Oscillation criteria for a forced second linear differential equations, J. Math. Anal. Appl. 231 (1999) 235-240], Sun, Ou and Wong [Y.G. Sun, C.H. Ou, J.S.W. Wong, Interval oscillation theorems for a linear second order differential equation, Comput. Math. Appl. 48 (2004) 1693-1699] for the linear equation, Nazr [A.H. Nazr, Sufficient conditions for the oscillation of forced super-linear second order differential equations with oscillatory potential, Proc. Amer. Math. Soc. 126 (1998) 123-125] for the superlinear equation, and Sun and Wong [Y.G. Sun, J.S.W. Wong, Note on forced oscillation of nth-order sublinear differential equations, JE Math. Anal. Appl. 298 (2004) 114-119] for the sublinear equation.

  8. The Development of Perceptual Sensitivity to Second-Order Facial Relations in Children

    ERIC Educational Resources Information Center

    Baudouin, Jean-Yves; Gallay, Mathieu; Durand, Karine; Robichon, Fabrice

    2010-01-01

    This study investigated children's perceptual ability to process second-order facial relations. In total, 78 children in three age groups (7, 9, and 11 years) and 28 adults were asked to say whether the eyes were the same distance apart in two side-by-side faces. The two faces were similar on all points except the space between the eyes, which was…

  9. Analytical and numerical Gubser solutions of the second-order hydrodynamics

    NASA Astrophysics Data System (ADS)

    Pang, Long-Gang; Hatta, Yoshitaka; Wang, Xin-Nian; Xiao, Bo-Wen

    2015-04-01

    Evolution of quark-gluon plasma near equilibrium can be described by the second-order relativistic viscous hydrodynamic equations. Consistent and analytically verifiable numerical solutions are critical for phenomenological studies of the collective behavior of quark-gluon plasma in high-energy heavy-ion collisions. A novel analytical solution based on the conformal Gubser flow that is a boost-invariant solution with transverse fluid velocity is presented. Because of the nonlinear nature of the equation, the analytical solution is nonperturbative and exhibits features that are rather distinct from solutions to usual linear hydrodynamic equations. It is used to verify with high precision the numerical solution with a newly developed state-of-the-art (3 +1 ) -dimensional second-order viscous hydro code (CLVisc). The perfect agreement between the analytical and numerical solutions demonstrates the reliability of the numerical simulations with the second-order viscous corrections. This lays the foundation for future phenomenological studies that allow one to gain access to the second-order transport coefficients.

  10. Second-Order Schedules of Token Reinforcement with Pigeons: Implications for Unit Price

    ERIC Educational Resources Information Center

    Bullock, Christopher E.; Hackenberg, Timothy D.

    2006-01-01

    Four pigeons were exposed to second-order schedules of token reinforcement, with stimulus lights serving as token reinforcers. Tokens were earned according to a fixed-ratio (token-production) schedule, with the opportunity to exchange tokens for food (exchange period) occurring after a fixed number had been produced (exchange-production ratio).…

  11. Maximally confined high-speed second-order silicon microdisk switches.

    SciTech Connect

    Young, Ralph Watson; Trotter, Douglas Chandler; Watts, Michael R.

    2008-03-01

    We demonstrate the first high-speed second-order silicon microdisk bandpass switch. The switch, constructed of a pair of 3 {micro}m radii active microdisks possesses {approx}40GHz flat-top passbands, a 4.2THz free-spectral-range, and a 2.4ns switching time.

  12. On Second-Order Fault Analysis Resistance for CRT-RSA Implementations

    NASA Astrophysics Data System (ADS)

    Dottax, Emmanuelle; Giraud, Christophe; Rivain, Matthieu; Sierra, Yannick

    Since their publication in 1996, Fault Attacks have been widely studied from both theoretical and practical points of view and most of cryptographic systems have been shown vulnerable to this kind of attacks. Until recently, most of the theoretical fault attacks and countermeasures used a fault model which assumes that the attacker is able to disturb the execution of a cryptographic algorithm only once. However, this approach seems too restrictive since the publication in 2007 of the successful experiment of an attack based on the injection of two faults, namely a second-order fault attack. Amongst the few papers dealing with second-order fault analysis, three countermeasures were published at WISTP’07 and FDTC’07 to protect the RSA cryptosystem using the CRT mode. In this paper, we analyse the security of these countermeasures with respect to the second-order fault model considered by their authors. We show that these countermeasures are not intrinsically resistant and we propose a new method allowing us to implement a CRT-RSA that resists to this kind of second-order fault attack.

  13. A Multilevel Algorithm for the Solution of Second Order Elliptic Differential Equations on Sparse Grids

    NASA Technical Reports Server (NTRS)

    Pflaum, Christoph

    1996-01-01

    A multilevel algorithm is presented that solves general second order elliptic partial differential equations on adaptive sparse grids. The multilevel algorithm consists of several V-cycles. Suitable discretizations provide that the discrete equation system can be solved in an efficient way. Numerical experiments show a convergence rate of order Omicron(1) for the multilevel algorithm.

  14. Keep Your Distance! Using Second-Order Ordinary Differential Equations to Model Traffic Flow

    ERIC Educational Resources Information Center

    McCartney, Mark

    2004-01-01

    A simple mathematical model for how vehicles follow each other along a stretch of road is presented. The resulting linear second-order differential equation with constant coefficients is solved and interpreted. The model can be used as an application of solution techniques taught at first-year undergraduate level and as a motivator to encourage…

  15. Design and development of second order MEMS sound pressure gradient sensor

    NASA Astrophysics Data System (ADS)

    Albahri, Shehab

    The design and development of a second order MEMS sound pressure gradient sensor is presented in this dissertation. Inspired by the directional hearing ability of the parasitoid fly, Ormia ochracea, a novel first order directional microphone that mimics the mechanical structure of the fly's ears and detects the sound pressure gradient has been developed. While the first order directional microphones can be very beneficial in a large number of applications, there is great potential for remarkable improvements in performance through the use of second order systems. The second order directional microphone is able to provide a theoretical improvement in Sound to Noise ratio (SNR) of 9.5dB, compared to the first-order system that has its maximum SNR of 6dB. Although second order microphone is more sensitive to sound angle of incidence, the nature of the design and fabrication process imposes different factors that could lead to deterioration in its performance. The first Ormia ochracea second order directional microphone was designed in 2004 and fabricated in 2006 at Binghamton University. The results of the tested parts indicate that the Ormia ochracea second order directional microphone performs mostly as an Omni directional microphone. In this work, the previous design is reexamined and analyzed to explain the unexpected results. A more sophisticated tool implementing a finite element package ANSYS is used to examine the previous design response. This new tool is used to study different factors that used to be ignored in the previous design, mainly; response mismatch and fabrication uncertainty. A continuous model using Hamilton's principle is introduced to verify the results using the new method. Both models agree well, and propose a new way for optimizing the second order directional microphone using geometrical manipulation. In this work we also introduce a new fabrication process flow to increase the fabrication yield. The newly suggested method uses the shell

  16. First and second order semi-Markov chains for wind speed modeling

    NASA Astrophysics Data System (ADS)

    Prattico, F.; Petroni, F.; D'Amico, G.

    2012-04-01

    -order Markov chain with different number of states, and Weibull distribution. All this model use Markov chains to generate synthetic wind speed time series but the search for a better model is still open. Approaching this issue, we applied new models which are generalization of Markov models. More precisely we applied semi-Markov models to generate synthetic wind speed time series. Semi-Markov processes (SMP) are a wide class of stochastic processes which generalize at the same time both Markov chains and renewal processes. Their main advantage is that of using whatever type of waiting time distribution for modeling the time to have a transition from one state to another one. This major flexibility has a price to pay: availability of data to estimate the parameters of the model which are more numerous. Data availability is not an issue in wind speed studies, therefore, semi-Markov models can be used in a statistical efficient way. In this work we present three different semi-Markov chain models: the first one is a first-order SMP where the transition probabilities from two speed states (at time Tn and Tn-1) depend on the initial state (the state at Tn-1), final state (the state at Tn) and on the waiting time (given by t=Tn-Tn-1), the second model is a second order SMP where we consider the transition probabilities as depending also on the state the wind speed was before the initial state (which is the state at Tn-2) and the last one is still a second order SMP where the transition probabilities depends on the three states at Tn-2,Tn-1 and Tn and on the waiting times t_1=Tn-1-Tn-2 and t_2=Tn-Tn-1. The three models are used to generate synthetic time series for wind speed by means of Monte Carlo simulations and the time lagged autocorrelation is used to compare statistical properties of the proposed models with those of real data and also with a time series generated though a simple Markov chain. [1] F. Youcef Ettoumi, H. Sauvageot, A.-E.-H. Adane, Statistical bivariate modeling

  17. Second order distorted born approximation for backscattering from a layer of discrete random medium

    NASA Technical Reports Server (NTRS)

    Lang, Roger H.; Saatchi, Sasan S.

    1993-01-01

    In recent years there has been increasing interest in scattering and depolarization characteristics of the vegetation canopies. Scattering models applied to the microwave remote sensing of vegetation canopies showed that multiple scattering effects can be important in simulating the backscattering coefficients correctly. In particular, in most applications, the cross-polarized backscattering coefficients are often underestimated by single scattering models. Recently, there have been concerted efforts to include the second order terms in the radiative transfer models of vegetation canopies in order to account for multiple scattering within the canopy. The coherent wave theory approach is extended to include multiple scattering effects to predict the coherent and incoherent backscattering contributions from a layer of vegetation canopy. The problem is initially formulated in terms of the exact equation for the correlation function of the field, i.e., the Bethe-Salpeter equation. Using fractional volume as a small parameter, a Foldy type approximation is made to obtain a more manageable correlation equation. This equation is iterated to obtain first and second order solutions. The iteration procedure assumes the variance of the field fluctuations are small compared to the coherent intensity. This assumption proved to be particularly successful in computing backscattering coefficients. First and second order backscattering coefficients are calculated from the iterants of the correlation equation. It is shown that the first order coefficients are the same as the distorted Born results used previously by the authors. These results contained enhancement terms in the direct-reflected contributions. The important contributions to second order backscattering are examined and interpreted in terms of scattering diagrams. Examples of situations in which second order backscattering coefficients are important are given.

  18. Pseudo almost periodic solutions to some systems of nonlinear hyperbolic second-order partial differential equations

    NASA Astrophysics Data System (ADS)

    Al-Islam, Najja Shakir

    In this Dissertation, the existence of pseudo almost periodic solutions to some systems of nonlinear hyperbolic second-order partial differential equations is established. For that, (Al-Islam [4]) is first studied and then obtained under some suitable assumptions. That is, the existence of pseudo almost periodic solutions to a hyperbolic second-order partial differential equation with delay. The second-order partial differential equation (1) represents a mathematical model for the dynamics of gas absorption, given by uxt+a x,tux=Cx,t,u x,t , u0,t=4 t, 1 where a : [0, L] x RR , C : [0, L] x R x RR , and ϕ : RR are (jointly) continuous functions ( t being the greatest integer function) and L > 0. The results in this Dissertation generalize those of Poorkarimi and Wiener [22]. Secondly, a generalization of the above-mentioned system consisting of the non-linear hyperbolic second-order partial differential equation uxt+a x,tux+bx,t ut+cx,tu=f x,t,u, x∈ 0,L,t∈ R, 2 equipped with the boundary conditions ux,0 =40x, u0,t=u 0t, uxx,0=y 0x, x∈0,L, t∈R, 3 where a, b, c : [0, L ] x RR and f : [0, L] x R x RR are (jointly) continuous functions is studied. Under some suitable assumptions, the existence and uniqueness of pseudo almost periodic solutions to particular cases, as well as the general case of the second-order hyperbolic partial differential equation (2) are studied. The results of all studies contained within this text extend those obtained by Aziz and Meyers [6] in the periodic setting.

  19. Second order symmetry-preserving conservative Lagrangian scheme for compressible Euler equations in two-dimensional cylindrical coordinates

    SciTech Connect

    Cheng, Juan; Shu, Chi-Wang

    2014-09-01

    In applications such as astrophysics and inertial confinement fusion, there are many three-dimensional cylindrical-symmetric multi-material problems which are usually simulated by Lagrangian schemes in the two-dimensional cylindrical coordinates. For this type of simulation, a critical issue for the schemes is to keep spherical symmetry in the cylindrical coordinate system if the original physical problem has this symmetry. In the past decades, several Lagrangian schemes with such symmetry property have been developed, but all of them are only first order accurate. In this paper, we develop a second order cell-centered Lagrangian scheme for solving compressible Euler equations in cylindrical coordinates, based on the control volume discretizations, which is designed to have uniformly second order accuracy and capability to preserve one-dimensional spherical symmetry in a two-dimensional cylindrical geometry when computed on an equal-angle-zoned initial grid. The scheme maintains several good properties such as conservation for mass, momentum and total energy, and the geometric conservation law. Several two-dimensional numerical examples in cylindrical coordinates are presented to demonstrate the good performance of the scheme in terms of accuracy, symmetry, non-oscillation and robustness. The advantage of higher order accuracy is demonstrated in these examples.

  20. Generalized Galileons: All scalar models whose curved background extensions maintain second-order field equations and stress tensors

    SciTech Connect

    Deffayet, C.; Deser, S.; Esposito-Farese, G.

    2009-09-15

    We extend to curved backgrounds all flat-space scalar field models that obey purely second-order equations, while maintaining their second-order dependence on both field and metric. This extension simultaneously restores to second order the, originally higher derivative, stress tensors as well. The process is transparent and uniform for all dimensions.

  1. Second-Order Factor Analysis as a Validity Assessment Tool: A Case Study Example Involving Perceptions of Stereotypic Love.

    ERIC Educational Resources Information Center

    Borrello, Gloria M.; Thompson, Bruce

    The calculation of second-order results in the validity assessment of measures and some useful interpretation aids are presented. First-order and second-order results give different and informative pictures of data dynamics. Several aspects of good practice in interpretation of second-order results are presented using data from 487 subjects…

  2. Second-order two-scale finite element algorithm for dynamic thermo-mechanical coupling problem in symmetric structure

    NASA Astrophysics Data System (ADS)

    Li, Zhi-Hui; Ma, Qiang; Cui, Junzhi

    2016-06-01

    The new second-order two-scale (SOTS) finite element algorithm is developed for the dynamic thermo-mechanical coupling problems in axisymmetric and spherical symmetric structures made of composite materials. The axisymmetric structure considered is periodic in both radial and axial directions and homogeneous in circumferential direction. The spherical symmetric structure is only periodic in radial direction. The dynamic thermo-mechanical coupling model is presented and the equivalent compact form is derived. Then, the cell problems, effective material coefficients and the homogenized thermo-mechanical coupling problem are obtained successively by the second-order asymptotic expansion of the temperature increment and displacement. The homogenized material obtained is manifested with the anisotropic property in the circumferential direction. The explicit expressions of the homogenized coefficients in the plane axisymmetric and spherical symmetric cases are given and both the derivation of the analytical solutions of the cell functions and the quasi-static thermoelasticity problems are discussed. Based on the SOTS method, the corresponding finite-element procedure is presented and the unconditionally stable implicit algorithm is established. Some numerical examples are solved and the mutual interaction between the temperature and displacement field is studied under the condition of structural vibration. The computational results demonstrate that the second-order asymptotic analysis finite-element algorithm is feasible and effective in simulating and predicting the dynamic thermo-mechanical behaviors of the composite materials with small periodic configurations in axisymmetric and spherical symmetric structures. This may provide a vital computational tool for analyzing composite material internal temperature distribution and structural deformation induced by the dynamic thermo-mechanical coupling response under strong aerothermodynamic environment.

  3. Some properties of solutions of a functional-differential equation of second order with delay.

    PubMed

    Ilea, Veronica Ana; Otrocol, Diana

    2014-01-01

    Existence, uniqueness, data dependence (monotony, continuity, and differentiability with respect to parameter), and Ulam-Hyers stability results for the solutions of a system of functional-differential equations with delays are proved. The techniques used are Perov's fixed point theorem and weakly Picard operator theory. PMID:24683363

  4. The Relationship Between Second-Order Nonlinear Optical Properties and Ground-State Polarization

    NASA Technical Reports Server (NTRS)

    Bourhil, G.; Cheng, L-T.; Lee, G.; Marder, S. R.; Perry, J. W.; Perry, M. J.; Tienmann, B. G.

    1993-01-01

    A review is presented describing our recent work to correlate the first hyperpolarizability, of organic materials with the molecular parameter bond length alternation (BLA). Donor-acceptor polyenes displaying a wide BLA range were synthesized.

  5. Long-wavelength properties of phase-field-crystal models with second-order dynamics

    NASA Astrophysics Data System (ADS)

    Heinonen, V.; Achim, C. V.; Ala-Nissila, T.

    2016-05-01

    The phase-field-crystal (PFC) approach extends the notion of phase-field models by describing the topology of the microscopic structure of a crystalline material. One of the consequences is that local variation of the interatomic distance creates an elastic excitation. The dynamics of these excitations poses a challenge: pure diffusive dynamics cannot describe relaxation of elastic stresses that happen through phonon emission. To this end, several different models with fast dynamics have been proposed. In this article we use the amplitude expansion of the PFC model to compare the recently proposed hydrodynamic PFC amplitude model with two simpler models with fast dynamics. We compare these different models analytically and numerically. The results suggest that in order to have proper relaxation of elastic excitations, the full hydrodynamical description of the PFC amplitudes is required.

  6. Second-order nonlinear optical property and crystal growth of chalcone derivatives

    NASA Astrophysics Data System (ADS)

    Goto, Yoshitaka; Hayashi, Akio; Zhang, G. J.; Nakayama, M.; Kitaoka, Yasuo; Sasaki, Takatomo; Watanabe, Toshiyuki; Miyata, Seizo; Honda, K.; Goto, Midori

    1990-12-01

    300 types of "chalcone" derivatives excellent in blue light region transparency were synthesized to investigate on second harmonic generation(SHG). The results of investigation suggested that an alkoxy group, an alkylthio group and halogen were effective as a substituent. Besides, a single crystal with respect to 4-ethoxy-4 ' -methoxychalcone(C-607) and 1- (2-thienyl ) -3- (4- fflethylphenyl)propene-l-one(TC-28) were grown. The obtained crystals were high quality and large size over 5 cm. We also had the first success in continuous SHG on a intracavity of the microchip laser using this single crystal "chalcone".

  7. Organic self-assembled layer-by-layer thin films for second-order nonlinear optics

    NASA Astrophysics Data System (ADS)

    Guzy, Matthew T.

    Layer-by-layer deposition techniques were used to fabricate films with second order nonlinear optical (NLO) properties. These materials are key to the development of electro-optic modulators used in fiber optic communication systems. Performance benefits and lower manufacturing costs are driving the development of organic NLO materials as replacements for inorganic crystalline materials such as lithium niobate. The layer-by-layer deposition technique in which polyelectrolytes are deposited on a surface by electrostatic effects is called the Ionically Self-Assembled Monolayer or ISAM method. The role of the optically inactive polycation's structure on deposition and chromophore orientation was studied by fabricating films with several different polycations. While the specific interactions responsible for chromophore orientation in ISAM films remains unclear, hydrogen bonding and electrostatic effects are ruled out as the sole sources of orientation. The highest values of chi(2) were observed under pH conditions that resulted in flat and thin layers. The relationship between pH and the optical homogeneity of the film was also explored. Deposition of polymers under pH conditions in which the polymer chains were aggregated in solution results in films that are not suitable for use in devices. In this work, a new layer-by-layer deposition technique was developed. Coined hybrid deposition, it relies on covalent bonds and electrostatic interactions for film fabrication. Optically inactive polyamines were used as sources of positive charges and as binding sites with optically active low molecular weight chromophores functionalized with a reactive triazine ring and negative charged sulfonate groups. Polar ordering of the chromophores was obtained when the deposition was done under conditions in which covalent bonding was the preferred attachment mechanism for the chromophore molecules. pH conditions in which electrostatic attachment dominated resulted in poorer orientation

  8. Second-order cone programming formulation for consolidation analysis of saturated porous media

    NASA Astrophysics Data System (ADS)

    Zhang, Xue; Sheng, Daichao; Sloan, Scott W.; Krabbenhoft, Kristian

    2016-07-01

    In this paper, the incremental problem for consolidation analysis of elastoplastic saturated porous media is formulated and solved using second-order cone programming. This is achieved by the application of the Hellinger-Reissner variational theorem, which casts the governing equations of Biot's consolidation theory as a min-max optimisation problem. The min-max problem is then discretised using the finite element method and converted into a standard second-order cone programming problem that can be solved efficiently using modern optimisation algorithms (such as the primal-dual interior-point method). The proposed computational formulation is verified against a number of benchmark examples and also applied to simulate the construction of a road embankment on soft clay.

  9. Second-order theory for nonlinear dielectric composites incorporating field fluctuations

    NASA Astrophysics Data System (ADS)

    Ponte Castañeda, P.

    2001-12-01

    This paper deals with the development of an improved second-order theory for estimating the effective behavior of nonlinear composite dielectrics. The theory makes use of the field fluctuations in the phases of the relevant ``linear comparison composite'' to generate improved Maxwell-Garnett (MGA) and effective-medium (EMA) types of approximations for nonlinear media. Similar to the earlier version of the theory, the resulting MGA and EMA predictions are exact to second-order in the contrast, but-unlike the earlier version-the estimates satisfy all known bounds. In particular, the EMA estimates exhibit a nonlinearity-independent percolation threshold, and critical exponents that are consistent with recently developed bounds on these exponents. In addition, the MGA and EMA estimates are shown to yield reasonable predictions for strongly nonlinear composites with ``threshold-type'' nonlinearities, which are extreme cases where earlier methods have been known to sometimes fail.

  10. Second-order interference of two independent and tunable single-mode continuous-wave lasers

    NASA Astrophysics Data System (ADS)

    Jianbin, Liu; Dong, Wei; Hui, Chen; Yu, Zhou; Huaibin, Zheng; Hong, Gao; Fu-Li, Li; Zhuo, Xu

    2016-03-01

    The second-order temporal interference of two independent single-mode continuous-wave lasers is discussed by employing two-photon interference in Feynman’s path integral theory. It is concluded that whether the second-order temporal interference pattern can or cannot be retrieved via two-photon coincidence counting rate is dependent on the resolution time of the detection system and the frequency difference between these two lasers. Two identical and tunable single-mode continuous-wave diode lasers are employed to verify the predictions. These studies are helpful to understand the physics of two-photon interference with photons of different spectra. Project supported by the National Natural Science Foundation of China (Grant No. 11404255) and the Doctor Foundation of Education Ministry of China (Grant No. 20130201120013).

  11. {open_quotes}Quadrupoled{close_quotes} materials for second-order nonlinear optics

    SciTech Connect

    Hubbard, S.F.; Petschek, R.G.; Singer, K.D.

    1997-10-01

    We describe a new approach to second-order nonlinear optical materials, namely quadrupoling. This approach is valid in the regime of Kleinman (full permutation) symmetry breaking, and thus requires a two- or three dimensional microscopic nonlinearity at wavelengths away from material resonances. This {open_quotes}quadrupolar{close_quotes} nonlinearity arises from the second rank pseudotensor of the rotationally invariant representation of the second-order nonlinear optical tensor. We have experimentally investigated candidate molecules comprised of chiral camphorquinone derivatives by measuring the scalar invariant associated with the rank two pseudotensor using hyper-Rayleigh scattering. We have found sizable scalar figures of merit for several compounds using light for which the second harmonic wavelengths are greater than 100 nm longer than the absorption peak location. At these wavelengths, the quadrupolar scalar is as large as the polar (EFISH) scalar of p-nitroaniline. Prospects for applications are discussed.

  12. Linear ion trap for second-order Doppler shift reduction in frequency standard applications

    NASA Technical Reports Server (NTRS)

    Prestage, John D.; Janik, Gary R.; Dick, G. John; Maleki, Lute

    1990-01-01

    The authors have designed and are presently testing a novel linear ion trap that permits storage of a large number of ions with reduced susceptibility to the second-order Doppler effect caused by the RF confining fields. This new trap should store about 20 times the number of ions as a conventional RF trap with no corresponding increase in second-order Doppler shift from the confining field. In addition, the sensitivity of this shift to trapping parameters, i.e., RF voltage, RF frequency, and trap size, is greatly reduced. The authors have succeeded in trapping mercury ions and xenon ions in the presence of helium buffer gas. Trap times as long as 2000 s have been measured.

  13. Second-order accurate finite volume method for well-driven flows

    NASA Astrophysics Data System (ADS)

    Dotlić, M.; Vidović, D.; Pokorni, B.; Pušić, M.; Dimkić, M.

    2016-02-01

    We consider a finite volume method for a well-driven fluid flow in a porous medium. Due to the singularity of the well, modeling in the near-well region with standard numerical schemes results in a completely wrong total well flux and an inaccurate hydraulic head. Local grid refinement can help, but it comes at computational cost. In this article we propose two methods to address the well singularity. In the first method the flux through well faces is corrected using a logarithmic function, in a way related to the Peaceman model. Coupling this correction with a non-linear second-order accurate two-point scheme gives a greatly improved total well flux, but the resulting scheme is still inconsistent. In the second method fluxes in the near-well region are corrected by representing the hydraulic head as a sum of a logarithmic and a linear function. This scheme is second-order accurate.

  14. Second-order two-scale method for bending behaviors of composite plate with periodic configuration

    NASA Astrophysics Data System (ADS)

    Zhu, Guoqing; Cui, Junzhi

    2010-06-01

    In this paper, the second-order two-scale analysis method for bending behaviors of the plate made from composites with 3-D periodic configuration is presented by means of construction way. It can capture the microscopic 3-D mechanics behaviors caused from 3-D micro-structures. First, directly starting from the 3-D elastic plate model of composite materials with 3-D periodic configuration, three cell models are defined, and correspondingly the three classes of cell functions only defined on 3 normalized cells are constructed. And then, the effective homogenization parameters of composites are calculated from those local functions, it leads to a 2-D homogenized laminar plate problem. Next, to solve it the homogenization solution is obtained. Finally, the second-order two-scale solution is constructed from the micro-cell functions and the homogenization solution.

  15. Second-Order Two-Scale Method for Bending Behaviors of Composite Plate with Periodic Configuration

    NASA Astrophysics Data System (ADS)

    Zhu, Guoqing; Cui, Junzhi

    2010-05-01

    In this paper, the second-order two-scale analysis method for bending behaviors of the plate made from composites with 3-D periodic configuration is presented by means of construction way. It can capture the microscopic 3-D mechanics behaviors caused from 3-D micro-structures. First, directly starting from the 3-D elastic plate model of composite materials with 3-D periodic configuration, three cell models are defined, and correspondingly the three classes of cell functions only defined on 3 normalized cells are constructed. And then, the effective homogenization parameters of composites are calculated from those local functions, it leads to a 2-D homogenized laminar plate problem. Next, to solve it the homogenization solution is obtained. Finally, the second-order two-scale solution is constructed from the micro-cell functions and the homogenization solution.

  16. Direct method for second-order sensitivity analysis of modal assurance criterion

    NASA Astrophysics Data System (ADS)

    Lei, Sheng; Mao, Kuanmin; Li, Li; Xiao, Weiwei; Li, Bin

    2016-08-01

    A Lagrange direct method is proposed to calculate the second-order sensitivity of modal assurance criterion (MAC) values of undamped systems. The eigenvalue problem and normalizations of eigenvectors, which augmented by using some Lagrange multipliers, are used as the constraints of the Lagrange functional. Once the Lagrange multipliers are determined, the sensitivities of MAC values can be evaluated directly. The Lagrange direct method is accurate, efficient and easy to implement. A simply supported beam is utilized to check the accuracy of the proposed method. A frame is adopted to validate the predicting capacity of the first- and second-order sensitivities of MAC values. It is shown that the computational costs of the proposed method can be remarkably reduced in comparison with those of the indirect method without loss of accuracy.

  17. Nonequilibrium Second-Order Phase Transition in a Cooper-Pair Insulator.

    PubMed

    Doron, A; Tamir, I; Mitra, S; Zeltzer, G; Ovadia, M; Shahar, D

    2016-02-01

    In certain disordered superconductors, upon increasing the magnetic field, superconductivity terminates with a direct transition into an insulating phase. This phase is comprised of localized Cooper pairs and is termed a Cooper-pair insulator. The current-voltage characteristics measured in this insulating phase are highly nonlinear and, at low temperatures, exhibit abrupt current jumps. Increasing the temperature diminishes the jumps until the current-voltage characteristics become continuous. We show that a direct correspondence exists between our system and systems that undergo an equilibrium, second-order, phase transition. We illustrate this correspondence by comparing our results to the van der Waals equation of state for the liquid-gas mixture. We use the similarities to identify a critical point where an out of equilibrium second-order-like phase transition occurs in our system. Approaching the critical point, we find a power-law behavior with critical exponents that characterizes the transition. PMID:26894728

  18. Second order classical perturbation theory for the sticking probability of heavy atoms scattered on surfaces

    SciTech Connect

    Sahoo, Tapas; Pollak, Eli

    2015-08-14

    A second order classical perturbation theory is developed to calculate the sticking probability of a particle scattered from an uncorrugated thermal surface. An analytic expression for the temperature dependent energy loss of the particle to the surface is derived by employing a one-dimensional generalized Langevin equation. The surface temperature reduces the energy loss, since the thermal surface transfers energy to the particle. Using a Gaussian energy loss kernel and the multiple collision theory of Fan and Manson [J. Chem. Phys. 130, 064703 (2009)], enables the determination of the fraction of particles trapped on the surface after subsequent momentum reversals of the colliding particle. This then leads to an estimate of the trapping probability. The theory is tested for the model scattering of Ar on a LiF(100) surface. Comparison with numerical simulations shows excellent agreement of the analytical theory with simulations, provided that the energy loss is determined by the second order perturbation theory.

  19. Relativistic second-order dissipative fluid dynamics at finite chemical potential

    NASA Astrophysics Data System (ADS)

    Jaiswal, Amaresh; Friman, Bengt; Redlich, Krzysztof

    2016-07-01

    We employ a Chapman-Enskog like expansion for the distribution function close to equilibrium to solve the Boltzmann equation in the relaxation time approximation and subsequently derive second-order evolution equations for dissipative charge currentand shear stress tensor for a system of massless quarks and gluons. We use quantum statistics for the phase space distribution functions to calculate the transport coefficients. We show that, the second-order evolution equations for the dissipative charge current and the shear stress tensor can be decoupled. We find that, for large chemical potential, the charge conductivity is small compared to the shear viscosity. Moreover, we demonstrate that the limiting behaviour of the ratio of heat conductivity to shear viscosity is identicalto that obtained for a strongly coupled conformal plasma.

  20. Sustainable institutionalized punishment requires elimination of second-order free-riders

    NASA Astrophysics Data System (ADS)

    Perc, Matjaž

    2012-03-01

    Although empirical and theoretical studies affirm that punishment can elevate collaborative efforts, its emergence and stability remain elusive. By peer-punishment the sanctioning is something an individual elects to do depending on the strategies in its neighborhood. The consequences of unsustainable efforts are therefore local. By pool-punishment, on the other hand, where resources for sanctioning are committed in advance and at large, the notion of sustainability has greater significance. In a population with free-riders, punishers must be strong in numbers to keep the ``punishment pool'' from emptying. Failure to do so renders the concept of institutionalized sanctioning futile. We show that pool-punishment in structured populations is sustainable, but only if second-order free-riders are sanctioned as well, and to a such degree that they cannot prevail. A discontinuous phase transition leads to an outbreak of sustainability when punishers subvert second-order free-riders in the competition against defectors.

  1. Second-Order Gauge Invariant Cosmological Perturbation Theory --- Einstein Equations in Terms of Gauge Invariant Variables ---

    NASA Astrophysics Data System (ADS)

    Nakamura, K.

    2007-01-01

    Following the general framework of the gauge invariant perturbation theory developed in the papers [K. Nakamura, Prog. Theor. Phys. 110 (2003), 723; ibid. 113 (2005), 481], we formulate second-order gauge invariant cosmological perturbation theory in a four-dimensional homogeneous isotropic universe. We consider perturbations both in the universe dominated by a single perfect fluid and in that dominated by a single scalar field. We derive all the components of the Einstein equations in the case that the first-order vector and tensor modes are negligible. All equations are derived in terms of gauge invariant variables without any gauge fixing. These equations imply that second-order vector and tensor modes may be generated due to the mode-mode coupling of the linear-order scalar perturbations. We also briefly discuss the main progress of this work through comparison with previous works.

  2. Nonequilibrium Second-Order Phase Transition in a Cooper-Pair Insulator

    NASA Astrophysics Data System (ADS)

    Doron, A.; Tamir, I.; Mitra, S.; Zeltzer, G.; Ovadia, M.; Shahar, D.

    2016-02-01

    In certain disordered superconductors, upon increasing the magnetic field, superconductivity terminates with a direct transition into an insulating phase. This phase is comprised of localized Cooper pairs and is termed a Cooper-pair insulator. The current-voltage characteristics measured in this insulating phase are highly nonlinear and, at low temperatures, exhibit abrupt current jumps. Increasing the temperature diminishes the jumps until the current-voltage characteristics become continuous. We show that a direct correspondence exists between our system and systems that undergo an equilibrium, second-order, phase transition. We illustrate this correspondence by comparing our results to the van der Waals equation of state for the liquid-gas mixture. We use the similarities to identify a critical point where an out of equilibrium second-order-like phase transition occurs in our system. Approaching the critical point, we find a power-law behavior with critical exponents that characterizes the transition.

  3. Beyond the G W approximation: A second-order screened exchange correction

    NASA Astrophysics Data System (ADS)

    Ren, Xinguo; Marom, Noa; Caruso, Fabio; Scheffler, Matthias; Rinke, Patrick

    2015-08-01

    Motivated by the recently developed renormalized second-order perturbation theory for ground-state energy calculations, we propose a second-order screened exchange correction (SOSEX) to the G W self-energy. This correction follows the spirit of the SOSEX correction to the random-phase approximation for the electron correlation energy and can be clearly represented in terms of Feynman diagrams. We benchmark the performance of the perturbative G0W0 +SOSEX scheme for a set of molecular systems, including the G2 test set from quantum chemistry as well as benzene and tetracyanoethylene. We find that G0W0 +SOSEX improves over G0W0 for the energy levels of the highest occupied and lowest unoccupied molecular orbitals. In addition, it can resolve some of the difficulties encountered by the G W method for relative energy positions as exemplified by benzene where the energy spacing between certain valence orbitals is severely underestimated.

  4. Second-order cone programming formulation for consolidation analysis of saturated porous media

    NASA Astrophysics Data System (ADS)

    Zhang, Xue; Sheng, Daichao; Sloan, Scott W.; Krabbenhoft, Kristian

    2016-03-01

    In this paper, the incremental problem for consolidation analysis of elastoplastic saturated porous media is formulated and solved using second-order cone programming. This is achieved by the application of the Hellinger-Reissner variational theorem, which casts the governing equations of Biot's consolidation theory as a min-max optimisation problem. The min-max problem is then discretised using the finite element method and converted into a standard second-order cone programming problem that can be solved efficiently using modern optimisation algorithms (such as the primal-dual interior-point method). The proposed computational formulation is verified against a number of benchmark examples and also applied to simulate the construction of a road embankment on soft clay.

  5. Second-Order Perturbation Theory for Generalized Active Space Self-Consistent-Field Wave Functions.

    PubMed

    Ma, Dongxia; Li Manni, Giovanni; Olsen, Jeppe; Gagliardi, Laura

    2016-07-12

    A multireference second-order perturbation theory approach based on the generalized active space self-consistent-field (GASSCF) wave function is presented. Compared with the complete active space (CAS) and restricted active space (RAS) wave functions, GAS wave functions are more flexible and can employ larger active spaces and/or different truncations of the configuration interaction expansion. With GASSCF, one can explore chemical systems that are not affordable with either CASSCF or RASSCF. Perturbation theory to second order on top of GAS wave functions (GASPT2) has been implemented to recover the remaining electron correlation. The method has been benchmarked by computing the chromium dimer ground-state potential energy curve. These calculations show that GASPT2 gives results similar to CASPT2 even with a configuration interaction expansion much smaller than the corresponding CAS expansion. PMID:27276688

  6. Atmospheric Effects of Second Order on Cosmic Rays Intensity Measured at the South Hemisphere

    NASA Astrophysics Data System (ADS)

    Alvarez-Castillo, Jesús; Francisco Valdes-Galicia, Jose

    In this work, we show atmospheric effects of second order on the cosmic rays intensity observed in the South Hemisphere; analysis is using meteorologic data of the TRMM satelite and others of the NOAA, and free data of the surface detectors from Pierre Auger Observatory with a resolution of 15 minutes. The time period analized was from 2006-2011. The methodology consisted in analize the anomalies in atmospheric pressure and in the corrected cosmic rays data for barometric effects considering a sigma level >|2|, the results reflecting a second order variation in the atmospheric pressure, applying digital filters and the spectrum of the data showed a trend that correspond to periodicities of the rain and electric field.

  7. Error analysis of exponential integrators for oscillatory second-order differential equations

    NASA Astrophysics Data System (ADS)

    Grimm, Volker; Hochbruck, Marlis

    2006-05-01

    In this paper, we analyse a family of exponential integrators for second-order differential equations in which high-frequency oscillations in the solution are generated by a linear part. Conditions are given which guarantee that the integrators allow second-order error bounds independent of the product of the step size with the frequencies. Our convergence analysis generalizes known results on the mollified impulse method by García-Archilla, Sanz-Serna and Skeel (1998, SIAM J. Sci. Comput. 30 930-63) and on Gautschi-type exponential integrators (Hairer E, Lubich Ch and Wanner G 2002 Geometric Numerical Integration (Berlin: Springer), Hochbruck M and Lubich Ch 1999 Numer. Math. 83 403-26).

  8. Temporal second-order coherence function for displaced-squeezed thermal states

    NASA Astrophysics Data System (ADS)

    Alexanian, Moorad

    2016-05-01

    We calculate the quantum mechanical, temporal second-order coherence function for a single-mode, degenerate parametric amplifier for a system in the Gaussian state, viz. a displaced-squeezed thermal state. The calculation involves first dynamical generation at time t of the Gaussian state from an initial thermal state and subsequent measurements of two photons a time ? apart. The generation of the Gaussian state by the parametric amplifier insures that the temporal second-order coherence function depends only on ?, via ?, for the given Gaussian state parameters, Gaussian state preparation time t, and average number ? of thermal photons. It is interesting that the time evolution for displaced thermal states shows a power decay in ? rather than an exponential one as is the case for general, displaced-squeezed thermal states.

  9. Quasidegenerate second-order perturbation corrections to single excitation configuration interaction

    NASA Astrophysics Data System (ADS)

    Head-Gordon, Martin

    1999-02-01

    A family of quasidegenerate second-order perturbation theories that correct excitation energies from single-excitation configuration interaction (CIS) are introduced which generalize the earlier non-degenerate second-order method, CIS(D). The new methods are termed CIS(D), where n ranges from 0 to x, according to the number of terms retained in a doubles denominator expansion. Truncation at either n = 0 or n = 1 yields methods which involve the diagonalization of a dressed singles-only response matrix, where the dressing is state-independent. Hence CIS(D0) and CIS(D1) can be implemented efficiently using semidirect methods, which are discussed. Test calculations on formaldehyde, ethylene, chlorine nitrate, styrene, benzaldehyde, and chalcone are presented to assess the performance of these methods. CIS(D0) and CIS(D1) both show significant improvements relative to CIS(D) in cases of near-degeneracy.

  10. Second-order discretization in space and time for radiation hydrodynamics

    SciTech Connect

    Edwards, J. D.; Morel, J. E.; Lowrie, R. B.

    2013-07-01

    We present a method for solving the equations of radiation hydrodynamics that is second-order accurate in space and time. This method combines the MUSCL-Hancock method for solving the Euler equations with the TR/BDF2 scheme in time for solving the equations of radiative transfer. We use an LDFEM to discretize the radiative transfer equations in space, which, though uncommon for radiation diffusion calculations, is a standard for radiation transport applications. We address the challenges inherent to using different spatial discretizations for the hydrodynamics and radiation and demonstrate how these may be overcome. We define our method for a 1-D model of compressible fluid dynamics coupled with grey radiation diffusion. Using the method of manufactured solutions, we show that the method is second-order accurate in space and time for both the equilibrium diffusion and streaming limit. (authors)

  11. Second-order consensus for multiagent systems with directed topologies and nonlinear dynamics.

    PubMed

    Yu, Wenwu; Chen, Guanrong; Cao, Ming; Kurths, Jürgen

    2010-06-01

    This paper considers a second-order consensus problem for multiagent systems with nonlinear dynamics and directed topologies where each agent is governed by both position and velocity consensus terms with a time-varying asymptotic velocity. To describe the system's ability for reaching consensus, a new concept about the generalized algebraic connectivity is defined for strongly connected networks and then extended to the strongly connected components of the directed network containing a spanning tree. Some sufficient conditions are derived for reaching second-order consensus in multiagent systems with nonlinear dynamics based on algebraic graph theory, matrix theory, and Lyapunov control approach. Finally, simulation examples are given to verify the theoretical analysis. PMID:19900852

  12. Improved Global Soft Decision Incorporating Second-Order Conditional MAP in Speech Enhancement

    NASA Astrophysics Data System (ADS)

    Kum, Jong-Mo; Chang, Joon-Hyuk

    In this paper, we propose a novel method based on the second-order conditional maximum a posteriori (CMAP) to improve the performance of the global soft decision in speech enhancement. The conventional global soft decision scheme is found through investigation to have a disadvantage in that the global speech absence probability (GSAP) in that scheme is adjusted by a fixed parameter, which could be a restrictive assumption in the consecutive occurrences of speech frames. To address this problem, we devise a method to incorporate the second-order CMAP in determining the GSAP, which is clearly different from the previous approach in that not only current observation but also the speech activity decisions of the previous two frames are exploited. Performances of the proposed method are evaluated by a number of tests in various environments and show better results than previous work.

  13. A second-order closure analysis of turbulent diffusion flames. [combustion physics

    NASA Technical Reports Server (NTRS)

    Varma, A. K.; Fishburne, E. S.; Beddini, R. A.

    1977-01-01

    A complete second-order closure computer program for the investigation of compressible, turbulent, reacting shear layers was developed. The equations for the means and the second order correlations were derived from the time-averaged Navier-Stokes equations and contain third order and higher order correlations, which have to be modeled in terms of the lower-order correlations to close the system of equations. In addition to fluid mechanical turbulence models and parameters used in previous studies of a variety of incompressible and compressible shear flows, a number of additional scalar correlations were modeled for chemically reacting flows, and a typical eddy model developed for the joint probability density function for all the scalars. The program which is capable of handling multi-species, multistep chemical reactions, was used to calculate nonreacting and reacting flows in a hydrogen-air diffusion flame.

  14. Low threshold blue conjugated polymer lasers with first- and second-order distributed feedback

    NASA Astrophysics Data System (ADS)

    Karnutsch, C.; Gýrtner, C.; Haug, V.; Lemmer, U.; Farrell, T.; Nehls, B. S.; Scherf, U.; Wang, J.; Weimann, T.; Heliotis, G.; Pflumm, C.; deMello, J. C.; Bradley, D. D. C.

    2006-11-01

    We report on the fabrication of low threshold distributed feedback (DFB) polymer lasers based on a polyfluorene derivative containing statistical binaphthyl units (BN-PFO). First- and second-order feedback lasers have been realized. The emission was tuned in the wavelength range from 438to459nm by varying the grating period and the film thickness. A threshold energy of 280pJ/pulse was observed in second-order DFB structures, which could be further reduced to 160pJ/pulse by employing first-order feedback in electron beam lithographically patterned structures with a period of 140nm. In these first-order structures, laser oscillation at both edges of the photonic stop band was observed. These very low threshold values render BN-PFO a very promising material for future electrically pumped organic semiconductor laser diodes.

  15. Crossed-second-order specific-mass isotope shift in the Nickel atom

    NASA Astrophysics Data System (ADS)

    Fonseca, A. L. A.; Bauche, J.

    1983-10-01

    The crossed-second-order corrections to the specific mass shifts of the lowest terms of the two lowest configurations of the Nickel atom are evaluated ab initio in the Multiconfigurational Hartree-Fock scheme. The excitations towards the nf( l=3) empty subshells play the major role. If the contributions obtained are added to the Hartree-Fock values, the discrepancy between experiment and theory for the 3 d 8 4 s 2-3 d 9 4 s (virtual) transition is only reduced by one third. As concerns the differences between the specific shifts of the five Russell-Saunders terms of 3 d 8 4 s 2, the crossed-second-order contributions are predicted to be practically as large as the Hartree-Fock values, which makes the total definitely measurable.

  16. Helquat Dyes: Helicene-like Push-Pull Systems with Large Second-Order Nonlinear Optical Responses.

    PubMed

    Coe, Benjamin J; Rusanova, Daniela; Joshi, Vishwas D; Sánchez, Sergio; Vávra, Jan; Khobragade, Dushant; Severa, Lukáš; Císařová, Ivana; Šaman, David; Pohl, Radek; Clays, Koen; Depotter, Griet; Brunschwig, Bruce S; Teplý, Filip

    2016-03-01

    Helquat dyes combine a cationic hemicyanine with a helicene-like motif to form a new blueprint for chiral systems with large and tunable nonlinear optical (NLO) properties. We report a series of such species with characterization, including determination of static first hyperpolarizabilities β0 via hyper-Rayleigh scattering and Stark spectroscopy. The measured β0 values are similar to or substantially larger than that of the commercial chromophore E-4'-(dimethylamino)-N-methyl-4-stilbazolium. Density functional theory (DFT) and time-dependent DFT calculations on two of the new cations are used to probe their molecular electronic structures and optical properties. Related molecules are expected to show bulk second-order NLO effects in even nonpolar media, overcoming a key challenge in developing useful materials. PMID:26844587

  17. Generalized second-order Thomas-Fermi method for superfluid Fermi systems

    NASA Astrophysics Data System (ADS)

    Pei, J. C.; Fei, Na; Zhang, Y. N.; Schuck, P.

    2015-12-01

    Using the ℏ expansion of the Green's function of the Hartree-Fock-Bogoliubov equation, we extend the second-order Thomas-Fermi approximation to generalized superfluid Fermi systems by including the density-dependent effective mass and the spin-orbit potential. We first implement and examine the full correction terms over different energy intervals of the quasiparticle spectra in calculations of finite nuclei. Final applications of this generalized Thomas-Fermi method are intended for various inhomogeneous superfluid Fermi systems.

  18. Finite amplitude instability of second-order fluids in plane Poiseuille flow.

    NASA Technical Reports Server (NTRS)

    Mcintire, L. V.; Lin, C. H.

    1972-01-01

    The hydrodynamic stability of plane Poiseuille flow of second-order fluids to finite amplitude disturbances is examined using the method of Stuart and Watson as extended by Reynolds and Potter. For slightly non-Newtonian fluids subcritical instabilities are predicted. No supercritical equilibrium states are expected if the entire spectrum of disturbance wavelengths is present. Possible implications with respect to the Toms phenomenon are discussed.

  19. A preliminary compressible second-order closure model for high speed flows

    NASA Technical Reports Server (NTRS)

    Speziale, Charles G.; Sarkar, Sutanu

    1989-01-01

    A preliminary version of a compressible second-order closure model that was developed in connection with the National Aero-Space Plane Project is presented. The model requires the solution of transport equations for the Favre-averaged Reynolds stress tensor and dissipation rate. Gradient transport hypotheses are used for the Reynolds heat flux, mass flux, and turbulent diffusion terms. Some brief remarks are made about the direction of future research to generalize the model.

  20. A second-order method for interface reconstruction in orthogonal coordinate systems

    SciTech Connect

    Colella, P.; Graves, D.T.; Greenough, J.A.

    2002-01-02

    The authors present a second-order algorithm for reconstructing an interface from a distribution of volume fractions in a general orthogonal coordinate system with derivatives approximated using finite differences. The method approximates the interface curve by a piecewise-linear profile. An integral formulation is used that accounts for the orthogonal coordinate system in a natural way. The authors present results obtained using this method for tracking a material interface between two compressible media in spherical coordinates.

  1. First- and second-order aerodynamic sensitivity derivatives via automatic differentiation with incremental iterative methods

    SciTech Connect

    Sherman, L.L.; Taylor, A.C. III; Hou, G.W.; Korivi, V.M.

    1996-12-01

    The straightforward automatic-differentiation and the hand-differentiated incremental iterative methods are interwoven to produce a hybrid scheme that captures some of the strengths of each strategy. With this compromise, discrete aerodynamic sensitivity derivatives are calculated with the efficient incremental iterative solution algorithm of the original flow code. Moreover, the principal advantage of automatic differentiation is retained. The basic equations for second-order sensitivity derivatives are presented, which results in a comparison of four different methods. Each of these four schemes for second-order derivatives requires that large systems are solved first for the first-order adjoint variables. Of these latter three schemes, two require no solutions of large systems thereafter. For the other two for which additional systems are solved, the equations and solution procedures are analogous to those for the first-order derivatives. From a practical viewpoint, implementation of the second-order methods is feasible only with software tools such as automatic differentiation, because of the extreme complexity and large number of terms. First- and second-order sensitivities are calculated accurately for two airfoil problems, including a turbulent-flow example. In each of these two sample problems, three dependent variables (coefficients of lift, drag, and pitching-moment) and six independent variables (three geometric-shape and three flow-condition design variables) are considered. Several different procedures are tested, and results are compared on the basis of accuracy, computational time, and computer memory. For first-order derivatives, the hybrid incremental iterative scheme obtained with automatic differentiation is competitive with the best hand-differentiated method. Furthermore, it is at least two to four times faster than central finite differences, without an overwhelming penalty in computer memory. 23 refs., 14 tabs.

  2. Numerical solution of second order ODE directly by two point block backward differentiation formula

    NASA Astrophysics Data System (ADS)

    Zainuddin, Nooraini; Ibrahim, Zarina Bibi; Othman, Khairil Iskandar; Suleiman, Mohamed; Jamaludin, Noraini

    2015-12-01

    Direct Two Point Block Backward Differentiation Formula, (BBDF2) for solving second order ordinary differential equations (ODEs) will be presented throughout this paper. The method is derived by differentiating the interpolating polynomial using three back values. In BBDF2, two approximate solutions are produced simultaneously at each step of integration. The method derived is implemented by using fixed step size and the numerical results that follow demonstrate the advantage of the direct method as compared to the reduction method.

  3. Dynamic gain aperture modelocking in picosecond regime based on cascaded second-order nonlinearity.

    PubMed

    Mondal, Shyamal; Mukherjee, Shouvik; Singh, Satya Pratap; Rand, Stephen C; Bhattacharya, Sayantan; Das, Amit C; Datta, Prasanta Kumar

    2016-07-11

    The operation of a cascaded second-order mode-locked Nd:YVO4 laser has been investigated considering it as a soft-aperture Kerr lens type and using complex beam parameters. A self consistent complex beam propagation method is used to incorporate the effect of cascaded Kerr nonlinearity on radially varying gain aperturing. The analysis deduces a stable pulsewidth of ~9.5 ps which agrees well with the experimental value of 10.3 ps. PMID:27410804

  4. Reanalyzing the 16PF-5 Second Order Structure: Exploratory versus Confirmatory Factorial Analysis

    ERIC Educational Resources Information Center

    Aluja, Anton; Blanch, Angel; Garcia, Luis F.

    2005-01-01

    In the present study, the second order structures of the 16PF-5 for 3, 4, 5 and 6 factors are analysed in a sample of 636 undergraduate students and their friends and relatives, with a mean age of 25.09 years (sd: 9.20). A two-stage analysis with Exploratory and Confirmatory Factor Analysis (EFA and CFA) was performed assigning subjects either to…

  5. On the basic equations for the second-order modeling of compressible turbulence

    NASA Technical Reports Server (NTRS)

    Liou, W. W.; Shih, T.-H.

    1991-01-01

    Equations for the mean and turbulent quantities for compressible turbulent flows are derived. Both the conventional Reynolds average and the mass-weighted, Favre average were employed to decompose the flow variable into a mean and a turbulent quality. These equations are to be used later in developing second order Reynolds stress models for high speed compressible flows. A few recent advances in modeling some of the terms in the equations due to compressibility effects are also summarized.

  6. Double ionization of single oriented water molecules by electron impact: Second-order Born description

    SciTech Connect

    Dal Cappello, C.; Champion, C.; Kada, I.; Mansouri, A.

    2011-06-15

    The double ionization of isolated water molecules fixed in space is investigated within a theoretical approach based on the second-order Born approximation. Electron angular distributions have been studied for specific kinematical conditions. The three usual mechanisms, the shake-off and the two two-step mechanisms, have been identified. A significant contribution of the two-step mechanism is clearly visible for some particular kinematics.

  7. Static multipole polarisabilities and second-order Stark shift in francium.

    PubMed

    Khan, F; Khandelwal, G S; Wilson, J W

    1988-01-01

    The multipole polarisability of the ground state of francium is calculated by utilising both the variational technique of Davison and the quantum defect theory underlying the Bates-Damgaard method. This approach is also shown to yield reasonable results for other alkali atoms. Second-order Stark shift for the ground state of francium is presented as a function of field strength for possible future experimental comparison. PMID:11539071

  8. Static multipole polarisabilities and second-order Stark shift in francium

    NASA Technical Reports Server (NTRS)

    Khan, F.; Khandelwal, G. S.; Wilson, J. W.

    1988-01-01

    The multipole polarizability of the ground state of francium is calculated by utilizing both the variational technique of Davison and the quantum defect theory underlying the Bates-Damgaard method. This approach is also shown to yield reasonable results for other alkali atoms. Second-order Stark shift for the ground state of francium is presented as a function of field strength for possible future experimental comparison.

  9. Screening of Protein Crystallization Trials by Second Order Nonlinear Optical Imaging of Chiral Crystals (SONICC)

    PubMed Central

    Haupert, Levi; Simpson, Garth

    2011-01-01

    Second order nonlinear optical imaging of chiral crystals (SONICC) is a promising new method for the sensitive and selective detection of protein crystals. Relevant general principles of second harmonic generation, which underpins SONICC, are reviewed. Instrumentation and methods for SONICC measurements are described and critically assessed in terms of performance trade-offs. Potential origins of false-positives and false-negatives are also discussed. PMID:22101350

  10. Mitigation of Second-Order Ionospheric Error for Real-Time PPP Users in Europe

    NASA Astrophysics Data System (ADS)

    Abdelazeem, Mohamed

    2016-07-01

    Currently, the international global navigation satellite system (GNSS) real-time service (IGS-RTS) products are used extensively for real-time precise point positioning and ionosphere modeling applications. The major challenge of the dual frequency real-time precise point positioning (RT-PPP) is that the solution requires relatively long time to converge to the centimeter-level accuracy. This relatively long convergence time results essentially from the un-modeled high-order ionospheric errors. To overcome this challenge, a method for the second-order ionospheric delay mitigation, which represents the bulk of the high-order ionospheric errors, is proposed for RT-PPP users in Europe. A real-time regional ionospheric model (RT-RIM) over Europe is developed using the IGS-RTS precise satellite orbit and clock products. GPS observations from a regional network consisting of 60 IGS and EUREF reference stations are processed using the Bernese 5.2 software package in order to extract the real-time vertical total electron content (RT-VTEC). The proposed RT-RIM has spatial and temporal resolution of 1º×1º and 15 minutes, respectively. In order to investigate the effect of the second-order ionospheric delay on the RT-PPP solution, new GPS data sets from another reference stations are used. The examined stations are selected to represent different latitudes. The GPS observations are corrected from the second-order ionospheric errors using the extracted RT-VTEC values. In addition, the IGS-RTS precise orbit and clock products are used to account for the satellite orbit and clock errors, respectively. It is shown that the RT-PPP convergence time and positioning accuracy are improved when the second-order ionospheric delay is accounted for.

  11. Second-order Born approximation for the ionization of molecules by electron and positron impact

    SciTech Connect

    Dal Cappello, C.; Rezkallah, Z.; Houamer, S.; Charpentier, I.; Hervieux, P. A.; Ruiz-Lopez, M. F.; Dey, R.; Roy, A. C.

    2011-09-15

    Second-order Born approximation is applied to study the ionization of molecules. The initial and final states are described by single-center wave functions. For the initial state a Gaussian wave function is used while for the ejected electron it is a distorted wave. Results of the present model are compared with recent (e,2e) experiments on the water molecule. Preliminary results are also presented for the ionization of the thymine molecule by electrons and positrons.

  12. Computationally efficient multidimensional analysis of complex flow cytometry data using second order polynomial histograms.

    PubMed

    Zaunders, John; Jing, Junmei; Leipold, Michael; Maecker, Holden; Kelleher, Anthony D; Koch, Inge

    2016-01-01

    Many methods have been described for automated clustering analysis of complex flow cytometry data, but so far the goal to efficiently estimate multivariate densities and their modes for a moderate number of dimensions and potentially millions of data points has not been attained. We have devised a novel approach to describing modes using second order polynomial histogram estimators (SOPHE). The method divides the data into multivariate bins and determines the shape of the data in each bin based on second order polynomials, which is an efficient computation. These calculations yield local maxima and allow joining of adjacent bins to identify clusters. The use of second order polynomials also optimally uses wide bins, such that in most cases each parameter (dimension) need only be divided into 4-8 bins, again reducing computational load. We have validated this method using defined mixtures of up to 17 fluorescent beads in 16 dimensions, correctly identifying all populations in data files of 100,000 beads in <10 s, on a standard laptop. The method also correctly clustered granulocytes, lymphocytes, including standard T, B, and NK cell subsets, and monocytes in 9-color stained peripheral blood, within seconds. SOPHE successfully clustered up to 36 subsets of memory CD4 T cells using differentiation and trafficking markers, in 14-color flow analysis, and up to 65 subpopulations of PBMC in 33-dimensional CyTOF data, showing its usefulness in discovery research. SOPHE has the potential to greatly increase efficiency of analysing complex mixtures of cells in higher dimensions. PMID:26097104

  13. A novel nonlinear adaptive filter using a pipelined second-order Volterra recurrent neural network.

    PubMed

    Zhao, Haiquan; Zhang, Jiashu

    2009-12-01

    To enhance the performance and overcome the heavy computational complexity of recurrent neural networks (RNN), a novel nonlinear adaptive filter based on a pipelined second-order Volterra recurrent neural network (PSOVRNN) is proposed in this paper. A modified real-time recurrent learning (RTRL) algorithm of the proposed filter is derived in much more detail. The PSOVRNN comprises of a number of simple small-scale second-order Volterra recurrent neural network (SOVRNN) modules. In contrast to the standard RNN, these modules of a PSOVRNN can be performed simultaneously in a pipelined parallelism fashion, which can lead to a significant improvement in its total computational efficiency. Moreover, since each module of the PSOVRNN is a SOVRNN in which nonlinearity is introduced by the recursive second-order Volterra (RSOV) expansion, its performance can be further improved. Computer simulations have demonstrated that the PSOVRNN performs better than the pipelined recurrent neural network (PRNN) and RNN for nonlinear colored signals prediction and nonlinear channel equalization. However, the superiority of the PSOVRNN over the PRNN is at the cost of increasing computational complexity due to the introduced nonlinear expansion of each module. PMID:19523787

  14. Treatment of Second Order Structures of Protein on Medical Equipments Using Oxygen Plasma

    NASA Astrophysics Data System (ADS)

    Hayashi, Nobuya; Kitazaki, Satoshi; Goto, Masaaki; Yagyu, Yoshihito; Yonesu, Akira

    2009-10-01

    Removal of proteins from the surface of medical equipments are attempted using an RF plasma. Oxygen gas is introduced into a vacuum chamber with dimensions of 450 mm in length, 200 mm in diameter and 20L of capacity. When an RF power (13.56 MHz, 60W) is applied to an ICP type antenna, oxygen radicals (atomic oxygen and excited oxygen molecule) are produced below the antenna. The characteristics of removing protein from the medical equipments was investigated using casein and heat-resistive keratin proteins. Initial concentration of the proteins on a CaF2 substrate is several mg/cm2. The treatment effect of proteins is determined by the peak height of chemical bonds in amide and second order structures appeared on FTIR spectra. The second order structure of a protein such as alpha-helix and beta-sheet are decomposed with the treatment period. Complete treatment of proteins including the second order structure requires several hours avoiding the damage to medical equipments.

  15. A second order self-consistent IMEX method for radiation hydrodynamics

    SciTech Connect

    Kadioglu, Samet Y.; Knoll, Dana A.; Lowrie, Robert B.; Rauenzahn, Rick M.

    2010-11-01

    We present a second order self-consistent implicit/explicit (methods that use the combination of implicit and explicit discretizations are often referred to as IMEX (implicit/explicit) methods ) time integration technique for solving radiation hydrodynamics problems. The operators of the radiation hydrodynamics are splitted as such that the hydrodynamics equations are solved explicitly making use of the capability of well-understood explicit schemes. On the other hand, the radiation diffusion part is solved implicitly. The idea of the self-consistent IMEX method is to hybridize the implicit and explicit time discretizations in a nonlinearly consistent way to achieve second order time convergent calculations. In our self-consistent IMEX method, we solve the hydrodynamics equations inside the implicit block as part of the nonlinear function evaluation making use of the Jacobian-free Newton Krylov (JFNK) method . This is done to avoid order reductions in time convergence due to the operator splitting. We present results from several test calculations in order to validate the numerical order of our scheme. For each test, we have established second order time convergence.

  16. The second-order post-newtonian orbit equation of light

    NASA Astrophysics Data System (ADS)

    Xiao, Y.; Fei, B. J.; Sun, W. J.; Ji, C. X.

    2008-04-01

    The photon's orbital equation is often used to discuss the movement of man-made satellite, small planet and photon in the solar system. It is also applied to the studies of astronomical measure such as VLBI, GPS and XNAV etc. In this paper, based on the second-order post-Newtonian approximation under the DSX scheme of GTR, it is educed that the second-order post-Newtonian orbit equation of light in axis-symmetrical stationary space-time using Lagrange equation. From here, the orbit equation and deflection angle of light propagating in equatorial plane are got. The conclusions are consistent with that of Schwarzchild and Kerr metric in the precision of measure. Because the oblateness of star is considered, it is more accurate than that of Kerr metric. The great advantage of the second-order post-Newtonian approximation under the DSX scheme of GTR is satisfy linear superposition. So, the conclusions in the paper can be applied to deal with the motion of light in multiple systems, but in this situation Kerr metric is of no effect.

  17. Effect of Second-Order Hydrodynamics on Floating Offshore Wind Turbines: Preprint

    SciTech Connect

    Roald, L.; Jonkman, J.; Robertson, A,; Chokani, N.

    2013-07-01

    Offshore winds are generally stronger and more consistent than winds on land, making the offshore environment attractive for wind energy development. A large part of the offshore wind resource is however located in deep water, where floating turbines are the only economical way of harvesting the energy. The design of offshore floating wind turbines relies on the use of modeling tools that can simulate the entire coupled system behavior. At present, most of these tools include only first-order hydrodynamic theory. However, observations of supposed second-order hydrodynamic responses in wave-tank tests performed by the DeepCwind consortium suggest that second-order effects might be critical. In this paper, the methodology used by the oil and gas industry has been modified to apply to the analysis of floating wind turbines, and is used to assess the effect of second-order hydrodynamics on floating offshore wind turbines. The method relies on combined use of the frequency-domain tool WAMIT and the time-domain tool FAST. The proposed assessment method has been applied to two different floating wind concepts, a spar and a tension-leg-platform (TLP), both supporting the NREL 5-MW baseline wind turbine. Results showing the hydrodynamic forces and motion response for these systems are presented and analysed, and compared to aerodynamic effects.

  18. Effects of Second-Order Hydrodynamic Forces on Floating Offshore Wind Turbines

    SciTech Connect

    Duarte, T.; Sarmento, A. J. N. A.; Jonkman, J.

    2014-04-01

    Relative to first-order, second-order wave-excitation loads are known to cause significant motions and additional loads in offshore oil and gas platforms. The design of floating offshore wind turbines was partially inherited from the offshore oil and gas industry. Floating offshore wind concepts have been studied with powerful aero-hydro-servo-elastic tools; however, most of the existing work on floating offshore wind turbines has neglected the contribution of second-order wave-excitation loads. As a result, this paper presents a computationally efficient methodology to consider these loads within FAST, a wind turbine computer-aided engineering tool developed by the National Renewable Energy Laboratory. The method implemented was verified against the commercial OrcaFlex tool, with good agreement, and low computational time. A reference floating offshore wind turbine was studied under several wind and wave load conditions, including the effects of second-order slow-drift and sum-frequency loads. Preliminary results revealed that these loads excite the turbine's natural frequencies, namely the surge and pitch natural frequencies.

  19. High-speed first- and second-order frequency modulated halftoning

    NASA Astrophysics Data System (ADS)

    Gooran, Sasan; Kruse, Björn

    2015-03-01

    Halftoning is a crucial part of image reproduction in print. First-order frequency modulated (FM) halftones, in which the single dots are stochastically distributed, are widely used in printing technologies, such as inkjet, that are able to stably print isolated dispersed dots. Printers, such as laser printers, that utilize electrophotographic technology are not able to stably print the isolated dots and, therefore, use clustered-dot halftones. Periodic clustered-dot, i.e., amplitude modulated halftones are commonly used in this type of printer, but they suffer from an undesired periodic interference pattern called moiré. An alternative solution is to use second-order FM halftones in which the clustered dots are stochastically distributed. The iterative halftoning techniques that usually result in well-formed halftones operate on the whole input image and require extensive computations and thus, are very slow when the input image is large. We introduce a method to generate image-independent threshold matrices for first- and second-order FM halftoning. The first-order threshold matrix generates well-formed halftone patterns and the second-order FM threshold matrix can be adjusted to produce clustered dots of different sizes, shapes, and alignment. Using predetermined and image-independent threshold matrices makes the proposed halftoning method a point-by-point process and thereby very fast.

  20. Second-order coding rates for pure-loss bosonic channels

    NASA Astrophysics Data System (ADS)

    Wilde, Mark M.; Renes, Joseph M.; Guha, Saikat

    2016-03-01

    A pure-loss bosonic channel is a simple model for communication over free-space or fiber-optic links. More generally, phase-insensitive bosonic channels model other kinds of noise, such as thermalizing or amplifying processes. Recent work has established the classical capacity of all of these channels, and furthermore, it is now known that a strong converse theorem holds for the classical capacity of these channels under a particular photon-number constraint. The goal of the present paper is to initiate the study of second-order coding rates for these channels, by beginning with the simplest one, the pure-loss bosonic channel. In a second-order analysis of communication, one fixes the tolerable error probability and seeks to understand the back-off from capacity for a sufficiently large yet finite number of channel uses. We find a lower bound on the maximum achievable code size for the pure-loss bosonic channel, in terms of the known expression for its capacity and a quantity called channel dispersion. We accomplish this by proving a general "one-shot" coding theorem for channels with classical inputs and pure-state quantum outputs which reside in a separable Hilbert space. The theorem leads to an optimal second-order characterization when the channel output is finite-dimensional, and it remains an open question to determine whether the characterization is optimal for the pure-loss bosonic channel.

  1. Mapping of the second-order nonlinear susceptibility of inhomogeneous absorbing media by Maker fringes analysis of optical difference mixing

    NASA Astrophysics Data System (ADS)

    Golubkov, Andrey A.; Makarov, Vladimir A.

    2012-04-01

    This paper proves the possibility of and offers a technique for a unique reconstitution of the spatial profiles of various components of the complex second-order susceptibility tensor χ(z,ω-ω;ω,-ω) responsible for difference frequency generation in one-dimensionally inhomogeneous plates. To be able to achieve such reconstitution it is necessary to measure the complex amplitude of the reflected difference frequency wave in a certain range of incidence angles of the plane biharmonic wave with frequencies ω1 and ω2 in its spectrum. By altering the incidence plane of the initial biharmonic wave and/or the polarization of its monochromatic components it is possible to uniquely determine the coordinate dependences of more than a half of all second-order susceptibility tensor components. Such reconstitution is successful when the symmetric nature of the medium ensures the diagonal character of the linear dielectric permittivity tensor of the plate. Besides, the dielectric properties of the plate can change arbitrarily along the z axis. The suggested approach includes measuring the intensity of difference frequency waves generated under specific conditions with the use of an auxiliary reference plate to be able to avoid complex phase measurements.

  2. Jacobi stability for dynamical systems of two-dimensional second-order differential equations and application to overhead crane system

    NASA Astrophysics Data System (ADS)

    Yajima, Takahiro; Yamasaki, Kazuhito

    2016-03-01

    Geometric structures of dynamical systems are investigated based on a differential geometric method (Jacobi stability of KCC-theory). This study focuses on differences of Jacobi stability of two-dimensional second-order differential equation from that of one-dimensional second-order differential equation. One of different properties from a one-dimensional case is the Jacobi unstable condition given by eigenvalues of deviation curvature with different signs. Then, this geometric theory is applied to an overhead crane system as a two-dimensional dynamical system. It is shown a relationship between the Hopf bifurcation of linearized overhead crane and the Jacobi stability. Especially, the Jacobi stable trajectory is found for stable and unstable spirals of the two-dimensional linearized system. In case of the linearized overhead crane system, the Jacobi stable spiral approaches to the equilibrium point faster than the Jacobi unstable spiral. This means that the Jacobi stability is related to the resilience of deviated trajectory in the transient state. Moreover, for the nonlinear overhead crane system, the Jacobi stability for limit cycle changes stable and unstable over time.

  3. Second-order statistics of a radially polarized cosine-Gaussian correlated Schell-model beam in anisotropic turbulence.

    PubMed

    Wang, Jing; Zhu, Shijun; Wang, Haiyan; Cai, Yangjian; Li, Zhenhua

    2016-05-30

    Recently, we introduced a new class of radially polarized cosine-Gaussian correlated Schell-model (CGCSM) beams of rectangular symmetry based on the partially coherent electromagnetic theory [Opt. Express23, 33099 (2015)]. In this paper, we extend the work to study the second-order statistics such as the average intensity, the spectral degree of coherence, the spectral degree of polarization and the state of polarization in anisotropic turbulence based on an extended von Karman power spectrum with a non-Kolmogorov power law α and an effective anisotropic parameter. Analytical formulas for the cross-spectral density matrix elements of a radially polarized CGCSM beam in anisotropic turbulence are derived. It is found that the second-order statistics are greatly affected by the source correlation function, and the change in the turbulent statistics induces relatively small effect. The significant effect of anisotropic turbulence on the beam parameters mainly appears nearα=3.1, and decreases with the increase of the anisotropic parameter. Furthermore, the polarization state exhibits self-splitting property and each beamlet evolves into a radially polarized structure in the far field. Our work enriches the classical coherence theory and may be important for free-space optical communications. PMID:27410089

  4. Cogeneration and utility diversification

    SciTech Connect

    Duggan, M.M.

    1985-08-01

    Niagara Mohawk saw cogeneration and utility diversification as an opportunity to break away from the traditional model of a public utility and avoid the fate of the railroads. The author reviews how HYDRA-CO Enterprises evaluated the risks and opportunities of diversification and the steps it took to diversify, which included a joint venture cogeneration project. The company sees a future with ever expanding opportunities for utility subsidiaries for those with courage and imagination.

  5. Hospital diversification strategy.

    PubMed

    Eastaugh, Steven R

    2014-01-01

    To determine the impact of health system restructuring on the levels of hospital diversification and operating ratio this article analyzed 94 teaching hospitals and 94 community hospitals during the period 2008-2013. The 47 teaching hospitals are matched with 47 other teaching hospitals experiencing the same financial market position in 2008, but with different levels of preference for risk and diversification in their strategic plan. Covariates in the analysis included levels of hospital competition and the degree of local government planning (for example, highly regulated in New York, in contrast to Texas). Moreover, 47 nonteaching community hospitals are matched with 47 other community hospitals in 2008, having varying manager preferences for service-line diversification and risk. Diversification and operating ratio are modeled in a two-stage least squares (TSLS) framework as jointly dependent. Institutional diversification is found to yield better financial position, and the better operating profits provide the firm the wherewithal to diversify. Some services are in a growth phase, like bariatric weight-loss surgery and sleep disorder clinics. Hospital managers' preferences for risk/return potential were considered. An institution life cycle hypothesis is advanced to explain hospital behavior: boom and bust, diversification, and divestiture, occasionally leading to closure or merger. PMID:25223156

  6. Quantum mechanical/molecular mechanical/continuum style solvation model: Second order Møller-Plesset perturbation theory

    SciTech Connect

    Thellamurege, Nandun M.; Si, Dejun; Cui, Fengchao; Li, Hui

    2014-05-07

    A combined quantum mechanical/molecular mechanical/continuum (QM/MM/C) style second order Møller-Plesset perturbation theory (MP2) method that incorporates induced dipole polarizable force field and induced surface charge continuum solvation model is established. The Z-vector method is modified to include induced dipoles and induced surface charges to determine the MP2 response density matrix, which can be used to evaluate MP2 properties. In particular, analytic nuclear gradient is derived and implemented for this method. Using the Assisted Model Building with Energy Refinement induced dipole polarizable protein force field, the QM/MM/C style MP2 method is used to study the hydrogen bonding distances and strengths of the photoactive yellow protein chromopore in the wild type and the Glu46Gln mutant.

  7. Second-order Poisson-Nernst-Planck solver for ion transport

    NASA Astrophysics Data System (ADS)

    Zheng, Qiong; Chen, Duan; Wei, Guo-Wei

    2011-06-01

    The Poisson-Nernst-Planck (PNP) theory is a simplified continuum model for a wide variety of chemical, physical and biological applications. Its ability of providing quantitative explanation and increasingly qualitative predictions of experimental measurements has earned itself much recognition in the research community. Numerous computational algorithms have been constructed for the solution of the PNP equations. However, in the realistic ion-channel context, no second-order convergent PNP algorithm has ever been reported in the literature, due to many numerical obstacles, including discontinuous coefficients, singular charges, geometric singularities, and nonlinear couplings. The present work introduces a number of numerical algorithms to overcome the abovementioned numerical challenges and constructs the first second-order convergent PNP solver in the ion-channel context. First, a Dirichlet to Neumann mapping (DNM) algorithm is designed to alleviate the charge singularity due to the protein structure. Additionally, the matched interface and boundary (MIB) method is reformulated for solving the PNP equations. The MIB method systematically enforces the interface jump conditions and achieves the second order accuracy in the presence of complex geometry and geometric singularities of molecular surfaces. Moreover, two iterative schemes are utilized to deal with the coupled nonlinear equations. Furthermore, extensive and rigorous numerical validations are carried out over a number of geometries, including a sphere, two proteins and an ion channel, to examine the numerical accuracy and convergence order of the present numerical algorithms. Finally, application is considered to a real transmembrane protein, the Gramicidin A channel protein. The performance of the proposed numerical techniques is tested against a number of factors, including mesh sizes, diffusion coefficient profiles, iterative schemes, ion concentrations, and applied voltages. Numerical predictions are

  8. Second-order Poisson Nernst-Planck solver for ion channel transport.

    PubMed

    Zheng, Qiong; Chen, Duan; Wei, Guo-Wei

    2011-06-01

    The Poisson Nernst-Planck (PNP) theory is a simplified continuum model for a wide variety of chemical, physical and biological applications. Its ability of providing quantitative explanation and increasingly qualitative predictions of experimental measurements has earned itself much recognition in the research community. Numerous computational algorithms have been constructed for the solution of the PNP equations. However, in the realistic ion-channel context, no second order convergent PNP algorithm has ever been reported in the literature, due to many numerical obstacles, including discontinuous coefficients, singular charges, geometric singularities, and nonlinear couplings. The present work introduces a number of numerical algorithms to overcome the abovementioned numerical challenges and constructs the first second-order convergent PNP solver in the ion-channel context. First, a Dirichlet to Neumann mapping (DNM) algorithm is designed to alleviate the charge singularity due to the protein structure. Additionally, the matched interface and boundary (MIB) method is reformulated for solving the PNP equations. The MIB method systematically enforces the interface jump conditions and achieves the second order accuracy in the presence of complex geometry and geometric singularities of molecular surfaces. Moreover, two iterative schemes are utilized to deal with the coupled nonlinear equations. Furthermore, extensive and rigorous numerical validations are carried out over a number of geometries, including a sphere, two proteins and an ion channel, to examine the numerical accuracy and convergence order of the present numerical algorithms. Finally, application is considered to a real transmembrane protein, the Gramicidin A channel protein. The performance of the proposed numerical techniques is tested against a number of factors, including mesh sizes, diffusion coefficient profiles, iterative schemes, ion concentrations, and applied voltages. Numerical predictions are

  9. Renormalized second-order perturbation theory for the electron correlation energy: Concept, implementation, and benchmarks

    NASA Astrophysics Data System (ADS)

    Ren, Xinguo; Rinke, Patrick; Scuseria, Gustavo E.; Scheffler, Matthias

    2013-07-01

    We present a renormalized second-order perturbation theory (rPT2), based on a Kohn-Sham (KS) reference state, for the electron correlation energy that includes the random-phase approximation (RPA), second-order screened exchange (SOSEX), and renormalized single excitations (rSE). These three terms all involve a summation of certain types of diagrams to infinite order, and can be viewed as ``renormalization'' of the second-order direct, exchange, and single-excitation (SE) terms of Rayleigh-Schrödinger perturbation theory based on a KS reference. In this work, we establish the concept of rPT2 and present the numerical details of our SOSEX and rSE implementations. A preliminary version of rPT2, in which the renormalized SE (rSE) contribution was treated approximately, has already been benchmarked for molecular atomization energies and chemical reaction barrier heights and shows a well-balanced performance [J. Paier , New J. Phys.1367-263010.1088/1367-2630/14/4/043002 14, 043002 (2012)]. In this work, we present a refined version of rPT2, in which we evaluate the rSE series of diagrams rigorously. We then extend the benchmark studies to noncovalent interactions, including the rare-gas dimers, and the S22 and S66 test sets, as well as the cohesive energy of small copper clusters, and the equilibrium geometry of 10 diatomic molecules. Despite some remaining shortcomings, we conclude that rPT2 gives an overall satisfactory performance across different electronic situations, and is a promising step towards a generally applicable electronic-structure approach.

  10. Second-order coherence of microwave photons emitted by a quantum point contact

    NASA Astrophysics Data System (ADS)

    Hassler, Fabian; Otten, Daniel

    2015-11-01

    Shot noise of electrons that are transmitted with probability T through a quantum point contact (biased at a voltage V0) leads to a fluctuating current that in turn emits radiation in the microwave regime. By calculating the Fano factor F for the case where only a single channel contributes to the transport, it has been shown that the radiation produced at finite frequency ω0 close to e V0/ℏ and at low temperatures is nonclassical with sub-Poissonian statistics (F <1 ). The origin of this effect is the fermionic nature of the electrons producing the radiation, which reduces the probability of simultaneous emission of two or more photons. However, the Fano factor, being a time-averaged quantity, offers only limited information about the system. Here, we calculate the second-order coherence g(2 )(τ ) for this source of radiation. We show that due to the interference of two contributions, two photon processes (leading to bunching) are completely absent at zero temperature for T =50 % . At low temperatures, we find a competition of the contribution due to Gaussian current-current fluctuations (leading to bunching) with the one due to non-Gaussian fluctuations (leading to antibunching). At slightly elevated temperatures, the non-Gaussian contribution becomes suppressed, whereas the Gaussian contributions remain largely independent of temperature. We show that the competition of the two contributions leads to a nonmonotonic behavior of the second-order coherence as a function of time. As a result, g(2 )(τ ) obtains a minimal value for times τ*≃ω0-1 . Close to this time, the second-order coherence remains below 1 at temperatures where the Fano factor is already above 1. We identify realistic experimental parameters that can be used to test the sub-Poissonian nature of the radiation.

  11. Ethanol Self-Administration in Mice under a Second-Order Schedule

    PubMed Central

    Lamb, Richard J.; Pinkston, Jonathan W.; Ginsburg, Brett C.

    2015-01-01

    Long Fixed-Interval (FI) schedules, particularly second-order schedules, can engender substantial responding before drug or ethanol delivery that is uninfluenced by the direct effects of the drug or ethanol. Thus, these schedules can be used to study the effects of medications upon drug- or ethanol-seeking, uninfluenced by the direct effects of the self-administered drug or ethanol. Long FI second-order schedules are frequently used in primates and occasionally in rats. Under second-order schedules, completion of one response requirement, e.g., a Fixed Ratio 10 (FR10:S), produces a brief stimulus presentation, e.g., a 1-sec 80-dB 4-kHZ tone, and this FR10:S serves as the response unit under another schedule, e.g., a FI 1800-sec. Thus, the first FR10 completed after 1800 sec would result in delivery both of the tone and of reinforcement, e.g., 10 × 0.01 mL 16% (w/v) ethanol. To examine if such schedules could be effectively used in mice, which have advantages in neurobiological and genetic studies, we trained eight C57BL/6J mice to respond under the schedule just described. This schedule maintained substantial responding. The temporal pattern of behavior was typical of an FI schedule with responding accelerating across the interval. We also examined the effects of acute and chronic administration of fluvoxamine on this responding, and these were modest. Finally, we examined responding when alcohol and/or tone deliveries were withheld, and found that extinction occurred most rapidly when both were withheld. This work demonstrates that long FI schedules of ethanol delivery may be useful in studying ethanol seeking in mice. PMID:26254963

  12. Comparison of Second-Order Loads on a Semisubmersible Floating Wind Turbine: Preprint

    SciTech Connect

    Gueydon, S.; Duarte, T.; Jonkman, J.; Bayati, I.; Sarmento, A.

    2014-03-01

    As offshore wind projects move to deeper waters, floating platforms become the most feasible solution for supporting the turbines. The oil and gas industry has gained experience with floating platforms that can be applied to offshore wind projects. This paper focuses on the analysis of second-order wave loading on semisubmersible platforms. Semisubmersibles, which are being chosen for different floating offshore wind concepts, are particularly prone to slow-drift motions. The slack catenary moorings usually result in large natural periods for surge and sway motions (more than 100 s), which are in the range of the second-order difference-frequency excitation force. Modeling these complex structures requires coupled design codes. Codes have been developed that include turbine aerodynamics, hydrodynamic forces on the platform, restoring forces from the mooring lines, flexibility of the turbine, and the influence of the turbine control system. In this paper two different codes are employed: FAST, which was developed by the National Renewable Energy Laboratory, and aNySIM, which was developed by the Maritime Research Institute Netherlands. The hydrodynamic loads are based on potential-flow theory, up to the second order. Hydrodynamic coefficients for wave excitation, radiation, and hydrostatic forces are obtained with two different panel codes, WAMIT (developed by the Massachusetts Institute of Technology) and DIFFRAC (developed by MARIN). The semisubmersible platform, developed for the International Energy Agency Wind Task 30 Offshore Code Comparison Collaboration Continuation project is used as a reference platform. Irregular waves are used to compare the behavior of this platform under slow-drift excitation loads. The results from this paper highlight the effects of these loads on semisubmersible-type platforms, which represent a promising solution for the commercial development of the offshore deepwater wind resource.

  13. Second-order accurate kinetic schemes for the ultra-relativistic Euler equations

    NASA Astrophysics Data System (ADS)

    Kunik, Matthias; Qamar, Shamsul; Warnecke, Gerald

    2003-12-01

    A second-order accurate kinetic scheme for the numerical solution of the relativistic Euler equations is presented. These equations describe the flow of a perfect fluid in terms of the particle density n, the spatial part of the four-velocity u and the pressure p. The kinetic scheme, is based on the well-known fact that the relativistic Euler equations are the moments of the relativistic Boltzmann equation of the kinetic theory of gases when the distribution function is a relativistic Maxwellian. The kinetic scheme consists of two phases, the convection phase (free-flight) and collision phase. The velocity distribution function at the end of the free-flight is the solution of the collisionless transport equation. The collision phase instantaneously relaxes the distribution to the local Maxwellian distribution. The fluid dynamic variables of density, velocity, and internal energy are obtained as moments of the velocity distribution function at the end of the free-flight phase. The scheme presented here is an explicit method and unconditionally stable. The conservation laws of mass, momentum and energy as well as the entropy inequality are everywhere exactly satisfied by the solution of the kinetic scheme. The scheme also satisfies positivity and L1-stability. The scheme can be easily made into a total variation diminishing method for the distribution function through a suitable choice of the interpolation strategy. In the numerical case studies the results obtained from the first- and second-order kinetic schemes are compared with the first- and second-order upwind and central schemes. We also calculate the experimental order of convergence and numerical L1-stability of the scheme for smooth initial data.

  14. Ethanol self-administration in mice under a second-order schedule.

    PubMed

    Lamb, Richard J; Pinkston, Jonathan W; Ginsburg, Brett C

    2015-09-01

    Long Fixed-Interval (FI) schedules, particularly second-order schedules, can engender substantial responding before drug or ethanol delivery that is uninfluenced by the direct effects of the drug or ethanol. Thus, these schedules can be used to study the effects of medications upon drug- or ethanol-seeking, uninfluenced by the direct effects of the self-administered drug or ethanol. Long FI second-order schedules are frequently used in primates and occasionally in rats. Under second-order schedules, completion of one response requirement, e.g., a Fixed Ratio 10 (FR10:S), produces a brief stimulus presentation, e.g., a 1-s 80-dB 4-kHZ tone, and this FR10:S serves as the response unit under another schedule, e.g., an FI 1800-s. Thus, the first FR10 completed after 1800 s would result in delivery both of the tone and of reinforcement, e.g., 10 × 0.01 mL 16% (w/v) ethanol. To examine if such schedules could be effectively used in mice, which have advantages in neurobiological and genetic studies, we trained eight C57BL/6J mice to respond under the schedule just described. This schedule maintained substantial responding. The temporal pattern of behavior was typical of an FI schedule with responding accelerating across the interval. We also examined the effects of acute and chronic administration of fluvoxamine on this responding, and these were modest. Finally, we examined responding when alcohol and/or tone deliveries were withheld, and found that extinction occurred most rapidly when both were withheld. This work demonstrates that long FI schedules of ethanol delivery may be useful in studying ethanol seeking in mice. PMID:26254963

  15. Second-order Poisson Nernst-Planck solver for ion channel transport

    PubMed Central

    Zheng, Qiong; Chen, Duan; Wei, Guo-Wei

    2010-01-01

    The Poisson Nernst-Planck (PNP) theory is a simplified continuum model for a wide variety of chemical, physical and biological applications. Its ability of providing quantitative explanation and increasingly qualitative predictions of experimental measurements has earned itself much recognition in the research community. Numerous computational algorithms have been constructed for the solution of the PNP equations. However, in the realistic ion-channel context, no second order convergent PNP algorithm has ever been reported in the literature, due to many numerical obstacles, including discontinuous coefficients, singular charges, geometric singularities, and nonlinear couplings. The present work introduces a number of numerical algorithms to overcome the abovementioned numerical challenges and constructs the first second-order convergent PNP solver in the ion-channel context. First, a Dirichlet to Neumann mapping (DNM) algorithm is designed to alleviate the charge singularity due to the protein structure. Additionally, the matched interface and boundary (MIB) method is reformulated for solving the PNP equations. The MIB method systematically enforces the interface jump conditions and achieves the second order accuracy in the presence of complex geometry and geometric singularities of molecular surfaces. Moreover, two iterative schemes are utilized to deal with the coupled nonlinear equations. Furthermore, extensive and rigorous numerical validations are carried out over a number of geometries, including a sphere, two proteins and an ion channel, to examine the numerical accuracy and convergence order of the present numerical algorithms. Finally, application is considered to a real transmembrane protein, the Gramicidin A channel protein. The performance of the proposed numerical techniques is tested against a number of factors, including mesh sizes, diffusion coefficient profiles, iterative schemes, ion concentrations, and applied voltages. Numerical predictions are

  16. An invariant asymptotic formula for solutions of second-order linear ODE's

    NASA Technical Reports Server (NTRS)

    Gingold, H.

    1988-01-01

    An invariant-matrix technique for the approximate solution of second-order ordinary differential equations (ODEs) of form y-double-prime = phi(x)y is developed analytically and demonstrated. A set of linear transformations for the companion matrix differential system is proposed; the diagonalization procedure employed in the final stage of the asymptotic decomposition is explained; and a scalar formulation of solutions for the ODEs is obtained. Several typical ODEs are analyzed, and it is shown that the Liouville-Green or WKB approximation is a special case of the present formula, which provides an approximation which is valid for the entire interval (0, infinity).

  17. The second-order theory of electromagnetic hot ion beam instabilities. [in interplanetary magnetic field

    NASA Technical Reports Server (NTRS)

    Gary, S. P.; Tokar, R. L.

    1985-01-01

    The present investigation is concerned with the application of a second-order theory for electromagnetic instabilities in a collisionless plasma to two modes which resonate with hot ion beams. The application of the theory is strictly limited to the linear growth phase. However, the application of the theory may be extended to obtain a description of the beam at postsaturation if the wave-beam resonance is sufficiently broad in velocity space. Under the considered limitations, it is shown that, as in the cold beam case, the fluctuating fields do not gain appreciable momentum and that the primary exchange of momentum is between the beam and main component.

  18. Second order effect of twist deformations in the D1D5 CFT

    NASA Astrophysics Data System (ADS)

    Carson, Zaq; Hampton, Shaun; Mathur, Samir D.

    2016-04-01

    Thermalization in the D1D5 CFT should occur via interactions caused by the twist operator, which deforms the theory off its free orbifold point. Earlier studies investigating this deformation at first order did not show any definite evidence of thermalization. In this paper we study the deformation to second order, where we do expect to see the effects that should give thermalization. We compute the effect of two twist operators on an initial vacuum state, which generates a squeezed state analogous to the case for a single twist. We obtain expressions for the Bogoliubov coefficients in this 2-twist case.

  19. Treatment Characteristics of Second Order Structure of Proteins Using Low-Pressure Oxygen RF Plasma

    NASA Astrophysics Data System (ADS)

    Hayashi, Nobuya; Nakahigashi, Akari; Kawaguchi, Ryutaro; Goto, Masaaki

    2010-10-01

    Removal of proteins from the surface of medical equipments is attempted using oxygen plasma produced by RF discharge. FTIR spectra indicate that the bonding of C-H and N-H in the casein protein is reduced after irradiation of oxygen plasma. Also, the second order structure of a protein such as α-helix and β-sheet are modified by the oxygen plasma. Complete removal of casein protein with the concentration of 0.016 mg/cm2 that is equivalent to remnants on the medical equipment requires two hours avoiding the damage to medical equipments.

  20. Treatment Characteristics of Second Order Structure of Proteins Using Low-Pressure Oxygen RF Plasma

    SciTech Connect

    Hayashi, Nobuya; Nakahigashi, Akari; Kawaguchi, Ryutaro; Goto, Masaaki

    2010-10-13

    Removal of proteins from the surface of medical equipments is attempted using oxygen plasma produced by RF discharge. FTIR spectra indicate that the bonding of C-H and N-H in the casein protein is reduced after irradiation of oxygen plasma. Also, the second order structure of a protein such as {alpha}-helix and {beta}-sheet are modified by the oxygen plasma. Complete removal of casein protein with the concentration of 0.016 mg/cm{sup 2} that is equivalent to remnants on the medical equipment requires two hours avoiding the damage to medical equipments.

  1. Practical Calculation of Second-order Supersonic Flow past Nonlifting Bodies of Revolution

    NASA Technical Reports Server (NTRS)

    Van Dyke, Milton D

    1952-01-01

    Calculation of second-order supersonic flow past bodies of revolution at zero angle of attack is described in detail, and reduced to routine computation. Use of an approximate tangency condition is shown to increase the accuracy for bodies with corners. Tables of basic functions and standard computing forms are presented. The procedure is summarized so that one can apply it without necessarily understanding the details of the theory. A sample calculation is given, and several examples are compared with solutions calculated by the method of characteristics.

  2. Second-order stochastic leapfrog algorithm for multiplicative noise brownian motion

    PubMed

    Qiang; Habib

    2000-11-01

    A stochastic leapfrog algorithm for the numerical integration of Brownian motion stochastic differential equations with multiplicative noise is proposed and tested. The algorithm has a second-order convergence of moments in a finite time interval and requires the sampling of only one uniformly distributed random variable per time step. The noise may be white or colored. We apply the algorithm to a study of the approach towards equilibrium of an oscillator coupled nonlinearly to a heat bath and investigate the effect of the multiplicative noise (arising from the nonlinear coupling) on the relaxation time. This allows us to test the regime of validity of the energy-envelope approximation method. PMID:11102105

  3. Second-order stochastic leapfrog algorithm for multiplicative noise Brownian motion

    NASA Astrophysics Data System (ADS)

    Qiang, Ji; Habib, Salman

    2000-11-01

    A stochastic leapfrog algorithm for the numerical integration of Brownian motion stochastic differential equations with multiplicative noise is proposed and tested. The algorithm has a second-order convergence of moments in a finite time interval and requires the sampling of only one uniformly distributed random variable per time step. The noise may be white or colored. We apply the algorithm to a study of the approach towards equilibrium of an oscillator coupled nonlinearly to a heat bath and investigate the effect of the multiplicative noise (arising from the nonlinear coupling) on the relaxation time. This allows us to test the regime of validity of the energy-envelope approximation method.

  4. A Stable Clock Error Model Using Coupled First and Second Order Gauss-Markov Processes

    NASA Technical Reports Server (NTRS)

    Carpenter, Russell; Lee, Taesul

    2008-01-01

    Long data outages may occur in applications of global navigation satellite system technology to orbit determination for missions that spend significant fractions of their orbits above the navigation satellite constellation(s). Current clock error models based on the random walk idealization may not be suitable in these circumstances, since the covariance of the clock errors may become large enough to overflow flight computer arithmetic. A model that is stable, but which approximates the existing models over short time horizons is desirable. A coupled first- and second-order Gauss-Markov process is such a model.

  5. Second-order Bragg gratings in single-mode chalcogenide fibres

    SciTech Connect

    Bernier, M; Asatryan, K E; Vallee, R; Galstian, T M; Vasil'ev, Sergei A; Medvedkov, O I; Plotnichenko, V G; Gnusin, P I; Dianov, Evgenii M

    2011-05-31

    Bragg gratings with a second-order resonance wavelength in the near-IR spectral region have been inscribed into single-mode chalcogenide (As{sub 2}S{sub 3}) glass fibre by a He - Ne laser beam using a configuration typical of Bragg grating fabrication in germanosilicate fibre, with the use of a phase mask that ensures effective diffraction of the writing light into the +1 and -1 orders. The spectra of the inscribed gratings show no resonances due to cladding mode excitation because the cladding material is photosensitive. (fibre optics)

  6. Second-order shaped pulsed for solid-state quantum computation

    SciTech Connect

    Sengupta, Pinaki

    2008-01-01

    We present the construction and detailed analysis of highly optimized self-refocusing pulse shapes for several rotation angles. We characterize the constructed pulses by the coefficients appearing in the Magnus expansion up to second order. This allows a semianalytical analysis of the performance of the constructed shapes in sequences and composite pulses by computing the corresponding leading-order error operators. Higher orders can be analyzed with the numerical technique suggested by us previously. We illustrate the technique by analyzing several composite pulses designed to protect against pulse amplitude errors, and on decoupling sequences for potentially long chains of qubits with on-site and nearest-neighbor couplings.

  7. Ultrasound waveform tomography with the second-order total-generalized-variation regularization

    NASA Astrophysics Data System (ADS)

    Lin, Youzuo; Huang, Lianjie

    2016-03-01

    Ultrasound waveform tomography with the total-variation regularization could improve reconstructions of tumor margins, but the reconstructions usually contain unwanted blocky artifacts. We develop a new ultrasound waveform tomography method with a second-order total-generalized-variation regularization scheme to improve tomographic reconstructions of breast tumors and remove blocky artifacts in reconstruction results. We validate our new method using numerical phantom data and real phantom data acquired using our synthetic-aperture breast ultrasound tomography system with two parallel transducer arrays. Compared to reconstructions of ultrasound waveform tomography with modified total-variation regularization, our new ultrasound waveform tomography yields accurate sound-speed reconstruction results with significantly reduced artifacts.

  8. Synthesis of several novel multifunctionalized chromophores for second-order NLO

    NASA Astrophysics Data System (ADS)

    Luo, Jingdong; Zhan, Caimao; Qin, Jingui

    1998-08-01

    4-[4-disubstituted-amino-phenylazo]-(alpha) - cyanocinnamates with two or more functional groups (such as hydroxyl, allyl) at both ends of the molecule to be used as novel chromophores for second-order NLO polymeric materials are synthesized by diazonium coupling and Knoevenagel condensation. In this two-step method, the tediousness of functionalization at the electron-acceptor end is avoided by selecting (alpha) -cyanoacrylate as electron-acceptor. The products are easy to purify, and the whole procedure is simple and time-saving, which facilitates the choice of polymer system for effective hardened NLO lattice in a broader range.

  9. Ultra-fast digital holography of the femto-second order

    NASA Astrophysics Data System (ADS)

    Zhai, Hongchen; Wang, Xiaolei; Mu, Guoguang

    2007-01-01

    We report on pulsed digital micro holographic systems recording ultra-fast process of the femto-second order, by spatially angular division multiplexing (SADM) and wavelength division multiplexing (WDM), respectively. Both intensity and phase images of the digitally reconstructed images are obtained through Fourier transformation and digital filtering, which show clearly the plasma forming and propagating dynamic process of laser induced ionization of ambient air at the wavelength of 800 nm, with a time resolution of 50 fs and frame intervals of 300 to 550 fs.

  10. Effect of Second-Order Hydrodynamics on a Floating Offshore Wind Turbine

    SciTech Connect

    Roald, L.; Jonkman, J.; Robertson, A.

    2014-05-01

    The design of offshore floating wind turbines uses design codes that can simulate the entire coupled system behavior. At the present, most codes include only first-order hydrodynamics, which induce forces and motions varying with the same frequency as the incident waves. Effects due to second- and higher-order hydrodynamics are often ignored in the offshore industry, because the forces induced typically are smaller than the first-order forces. In this report, first- and second-order hydrodynamic analysis used in the offshore oil and gas industry is applied to two different wind turbine concepts--a spar and a tension leg platform.

  11. Efficient configuration selection scheme for vibrational second-order perturbation theory

    NASA Astrophysics Data System (ADS)

    Yagi, Kiyoshi; Hirata, So; Hirao, Kimihiko

    2007-07-01

    A fast algorithm of vibrational second-order Møller-Plesset perturbation theory is proposed, enabling a substantial reduction in the number of vibrational self-consistent-field (VSCF) configurations that need to be summed in the calculations. Important configurations are identified a priori by assuming that a reference VSCF wave function is approximated well by harmonic oscillator wave functions and that fifth- and higher-order anharmonicities are negligible. The proposed scheme has reduced the number of VSCF configurations by more than 100 times for formaldehyde, ethylene, and furazan with an error in computed frequencies being not more than a few cm-1.

  12. Efficient configuration selection scheme for vibrational second-order perturbation theory.

    PubMed

    Yagi, Kiyoshi; Hirata, So; Hirao, Kimihiko

    2007-07-21

    A fast algorithm of vibrational second-order Moller-Plesset perturbation theory is proposed, enabling a substantial reduction in the number of vibrational self-consistent-field (VSCF) configurations that need to be summed in the calculations. Important configurations are identified a priori by assuming that a reference VSCF wave function is approximated well by harmonic oscillator wave functions and that fifth- and higher-order anharmonicities are negligible. The proposed scheme has reduced the number of VSCF configurations by more than 100 times for formaldehyde, ethylene, and furazan with an error in computed frequencies being not more than a few cm(-1). PMID:17655435

  13. Kohn–Sham exchange-correlation potentials from second-order reduced density matrices

    SciTech Connect

    Cuevas-Saavedra, Rogelio; Staroverov, Viktor N.; Ayers, Paul W.

    2015-12-28

    We describe a practical algorithm for constructing the Kohn–Sham exchange-correlation potential corresponding to a given second-order reduced density matrix. Unlike conventional Kohn–Sham inversion methods in which such potentials are extracted from ground-state electron densities, the proposed technique delivers unambiguous results in finite basis sets. The approach can also be used to separate approximately the exchange and correlation potentials for a many-electron system for which the reduced density matrix is known. The algorithm is implemented for configuration-interaction wave functions and its performance is illustrated with numerical examples.

  14. Solution of second order quasi-linear boundary value problems by a wavelet method

    SciTech Connect

    Zhang, Lei; Zhou, Youhe; Wang, Jizeng

    2015-03-10

    A wavelet Galerkin method based on expansions of Coiflet-like scaling function bases is applied to solve second order quasi-linear boundary value problems which represent a class of typical nonlinear differential equations. Two types of typical engineering problems are selected as test examples: one is about nonlinear heat conduction and the other is on bending of elastic beams. Numerical results are obtained by the proposed wavelet method. Through comparing to relevant analytical solutions as well as solutions obtained by other methods, we find that the method shows better efficiency and accuracy than several others, and the rate of convergence can even reach orders of 5.8.

  15. Analytical solution to a non-autonomous second order differential equation with modified hyperbolic tangent function

    NASA Astrophysics Data System (ADS)

    Fernández-Guasti, M.

    2015-03-01

    The solution to a non-autonomous second order ordinary differential equation is presented. The real function, dependent on the differentiation variable, is a squared hyperbolic tangent function plus a term that involves the quotient of hyperbolic functions. This function varies from one limiting value to another without having any singularities. The solution is remarkably simple and involves only trigonometric and hyperbolic trigonometric functions. The solution is analyzed in the context of wave propagation in an inhomogeneous one-dimensional medium. The profile is shown to act as a perfect anti-reflection interface, providing a possible alternative route to the fabrication of reflectionless surfaces.

  16. A procedure on the first integrals of second-order nonlinear ordinary differential equations

    NASA Astrophysics Data System (ADS)

    Yasar, Emrullah; Yıldırım, Yakup

    2015-12-01

    In this article, we demonstrate the applicability of the integrating factor method to path equation describing minimum drag work, and a special Hamiltonian equation corresponding Riemann zeros for obtaining the first integrals. The effectiveness and powerfullness of this method is verified by applying it for two selected second-order nonlinear ordinary differential equations (NLODEs). As a result integrating factors and first integrals for them are succesfully established. The obtained results show that the integrating factor approach can also be applied to other NLODEs.

  17. Experimental demonstration of a second-order memristor and its ability to biorealistically implement synaptic plasticity.

    PubMed

    Kim, Sungho; Du, Chao; Sheridan, Patrick; Ma, Wen; Choi, ShinHyun; Lu, Wei D

    2015-03-11

    Memristors have been extensively studied for data storage and low-power computation applications. In this study, we show that memristors offer more than simple resistance change. Specifically, the dynamic evolutions of internal state variables allow an oxide-based memristor to exhibit Ca(2+)-like dynamics that natively encode timing information and regulate synaptic weights. Such a device can be modeled as a second-order memristor and allow the implementation of critical synaptic functions realistically using simple spike forms based solely on spike activity. PMID:25710872

  18. Cluster consensus of second-order multi-agent systems via pinning control

    NASA Astrophysics Data System (ADS)

    Lu, Xiao-Qing; Francis, Austin; Chen, Shi-Hua

    2010-12-01

    This paper investigates the cluster consensus problem for second-order multi-agent systems by applying the pinning control method to a small collection of the agents. Consensus is attained independently for different agent clusters according to the community structure generated by the group partition of the underlying graph and sufficient conditions for both cluster and general consensus are obtained by using results from algebraic graph theory and the LaSalle Invariance Principle. Finally, some simple simulations are presented to illustrate the technique.

  19. Analysis and design of a second-order digital phase-locked loop

    NASA Technical Reports Server (NTRS)

    Blasche, P. R.

    1979-01-01

    A specific second-order digital phase-locked loop (DPLL) was modeled as a first-order Markov chain with alternatives. From the matrix of transition probabilities of the Markov chain, the steady-state phase error of the DPLL was determined. In a similar manner the loop's response was calculated for a fading input. Additionally, a hardware DPLL was constructed and tested to provide a comparison to the results obtained from the Markov chain model. In all cases tested, good agreement was found between the theoretical predictions and the experimental data.

  20. Action approach to cosmological perturbations: the second-order metric in matter dominance

    SciTech Connect

    Boubekeur, Lotfi; Creminelli, Paolo; Vernizzi, Filippo; Norena, Jorge

    2008-08-15

    We study nonlinear cosmological perturbations during post-inflationary evolution, using the equivalence between a perfect barotropic fluid and a derivatively coupled scalar field with Lagrangian [-({partial_derivative}{phi}){sup 2}]{sup (1+w)/2w}. Since this Lagrangian is just a special case of k-inflation, this approach is analogous to the one employed in the study of non-Gaussianities from inflation. We use this method to derive the second-order metric during matter dominance in the comoving gauge directly as a function of the primordial inflationary perturbation {zeta}. Going to Poisson gauge, we recover the metric previously derived in the literature.

  1. Second order non-linear equations of motion for spinning highly flexible line elements

    NASA Technical Reports Server (NTRS)

    Salama, M.; Trubert, M.; Essawi, M.; Utku, S.

    1982-01-01

    The second order nonlinear equations of motion are formulated for spinning line elements having little or no intrinsic structural stiffness. The derivation is based on the extended Hamilton's principle and includes the effect of initial geometric imperfections (axial, curvature, and twist) on the line element dynamics. For comparison with previous work, the nonlinear equations are reduced to a linearized form frequently found in the literature. The comparison revealed several new spin-stiffening terms that have not been previously identified and/or retained. They combine geometric imperfections, rotary inertia, Coriolis, and gyroscopic terms.

  2. Gmr Second Order Electronic Gradiometer as Eddy Current Probe in Nde Applications

    NASA Astrophysics Data System (ADS)

    Valentino, M.; Bonavolontà, C.; Marrocco, N.; Peluso, G.; Pepe, G. P.

    2009-03-01

    This paper reports on Giant-Magneto Resistance (GMR) electronic second order gradiometer used as an EC probe to detect defects in Al-Ti riveted multi-layers non-magnetic metallic samples used in aircraft structures. An electronic characterization of the GMR gradiometer set-up for investigating the probe performance and its magnetic field sensitivity is presented. The comparison between magnetic images obtained by GMR probes and conventional excitation coils demonstrates the possibility to use successfully GMR technology as sensors for NDT applications.

  3. Communication: Explicitly correlated four-component relativistic second-order Møller-Plesset perturbation theory.

    PubMed

    Ten-no, Seiichiro; Yamaki, Daisuke

    2012-10-01

    We propose explicitly correlated Ansatz for four-component relativistic methods within the framework of the no-pair approximation. Kinetically balanced geminal basis is derived to satisfy the cusp conditions in the non-relativistic limit based on the Lévy-Leblend-like equation. Relativistic variants of strong-orthogonality projection operator (Ansätze 2α and 2β) suitable for practical calculations are introduced by exploiting the orthogonal complement of the large-component basis. A pilot implementation is performed for the second order Møller-Plesset perturbation theory. PMID:23039576

  4. Using second-order generalized estimating equations to model heterogeneous intraclass correlation in cluster randomized trials

    PubMed Central

    Crespi, Catherine M.; Wong, Weng Kee; Mishra, Shiraz I.

    2009-01-01

    SUMMARY In cluster randomized trials, it is commonly assumed that the magnitude of the correlation among subjects within a cluster is constant across clusters. However, the correlation may in fact be heterogeneous and depend on cluster characteristics. Accurate modeling of the correlation has the potential to improve inference. We use second-order generalized estimating equations to model heterogeneous correlation in cluster randomized trials. Using simulation studies we show that accurate modeling of heterogeneous correlation can improve inference when the correlation is high or varies by cluster size. We apply the methods to a cluster randomized trial of an intervention to promote breast cancer screening. PMID:19109804

  5. Block correlated second order perturbation theory with a generalized valence bond reference function

    SciTech Connect

    Xu, Enhua; Li, Shuhua

    2013-11-07

    The block correlated second-order perturbation theory with a generalized valence bond (GVB) reference (GVB-BCPT2) is proposed. In this approach, each geminal in the GVB reference is considered as a “multi-orbital” block (a subset of spin orbitals), and each occupied or virtual spin orbital is also taken as a single block. The zeroth-order Hamiltonian is set to be the summation of the individual Hamiltonians of all blocks (with explicit two-electron operators within each geminal) so that the GVB reference function and all excited configuration functions are its eigenfunctions. The GVB-BCPT2 energy can be directly obtained without iteration, just like the second order Møller–Plesset perturbation method (MP2), both of which are size consistent. We have applied this GVB-BCPT2 method to investigate the equilibrium distances and spectroscopic constants of 7 diatomic molecules, conformational energy differences of 8 small molecules, and bond-breaking potential energy profiles in 3 systems. GVB-BCPT2 is demonstrated to have noticeably better performance than MP2 for systems with significant multi-reference character, and provide reasonably accurate results for some systems with large active spaces, which are beyond the capability of all CASSCF-based methods.

  6. Indirect reciprocity can stabilize cooperation without the second-order free rider problem.

    PubMed

    Panchanathan, Karthik; Boyd, Robert

    2004-11-25

    Models of large-scale human cooperation take two forms. 'Indirect reciprocity' occurs when individuals help others in order to uphold a reputation and so be included in future cooperation. In 'collective action', individuals engage in costly behaviour that benefits the group as a whole. Although the evolution of indirect reciprocity is theoretically plausible, there is no consensus about how collective action evolves. Evidence suggests that punishing free riders can maintain cooperation, but why individuals should engage in costly punishment is unclear. Solutions to this 'second-order free rider problem' include meta-punishment, mutation, conformism, signalling and group-selection. The threat of exclusion from indirect reciprocity can sustain collective action in the laboratory. Here, we show that such exclusion is evolutionarily stable, providing an incentive to engage in costly cooperation, while avoiding the second-order free rider problem because punishers can withhold help from free riders without damaging their reputations. However, we also show that such a strategy cannot invade a population in which indirect reciprocity is not linked to collective action, thus leaving unexplained how collective action arises. PMID:15565153

  7. Perturbations of matter fields in the second-order gauge-invariant cosmological perturbation theory

    NASA Astrophysics Data System (ADS)

    Nakamura, Kouji

    2009-12-01

    To show that the general framework of the second-order gauge-invariant perturbation theory developed by K. Nakamura [Prog. Theor. Phys. 110, 723 (2003)PTPKAV0033-068X10.1143/PTP.110.723; Prog. Theor. Phys. 113, 481 (2005)PTPKAV0033-068X10.1143/PTP.113.481] is applicable to a wide class of cosmological situations, some formulas for the perturbations of the matter fields are summarized within the framework of the second-order gauge-invariant cosmological perturbation theory in a four-dimensional homogeneous isotropic universe, which is developed in Prog. Theor. Phys. 117, 17 (2007)PTPKAV0033-068X10.1143/PTP.117.17. We derive the formulas for the perturbations of the energy-momentum tensors and equations of motion for a perfect fluid, an imperfect fluid, and a single scalar field, and show that all equations are derived in terms of gauge-invariant variables without any gauge fixing. Through these formulas, we may say that the decomposition formulas for the perturbations of any tensor field into gauge-invariant and gauge-variant parts, which are proposed in the above papers, are universal.

  8. First and second order derivatives for optimizing parallel RF excitation waveforms

    NASA Astrophysics Data System (ADS)

    Majewski, Kurt; Ritter, Dieter

    2015-09-01

    For piecewise constant magnetic fields, the Bloch equations (without relaxation terms) can be solved explicitly. This way the magnetization created by an excitation pulse can be written as a concatenation of rotations applied to the initial magnetization. For fixed gradient trajectories, the problem of finding parallel RF waveforms, which minimize the difference between achieved and desired magnetization on a number of voxels, can thus be represented as a finite-dimensional minimization problem. We use quaternion calculus to formulate this optimization problem in the magnitude least squares variant and specify first and second order derivatives of the objective function. We obtain a small tip angle approximation as first order Taylor development from the first order derivatives and also develop algorithms for first and second order derivatives for this small tip angle approximation. All algorithms are accompanied by precise floating point operation counts to assess and compare the computational efforts. We have implemented these algorithms as callback functions of an interior-point solver. We have applied this numerical optimization method to example problems from the literature and report key observations.

  9. First and second order derivatives for optimizing parallel RF excitation waveforms.

    PubMed

    Majewski, Kurt; Ritter, Dieter

    2015-09-01

    For piecewise constant magnetic fields, the Bloch equations (without relaxation terms) can be solved explicitly. This way the magnetization created by an excitation pulse can be written as a concatenation of rotations applied to the initial magnetization. For fixed gradient trajectories, the problem of finding parallel RF waveforms, which minimize the difference between achieved and desired magnetization on a number of voxels, can thus be represented as a finite-dimensional minimization problem. We use quaternion calculus to formulate this optimization problem in the magnitude least squares variant and specify first and second order derivatives of the objective function. We obtain a small tip angle approximation as first order Taylor development from the first order derivatives and also develop algorithms for first and second order derivatives for this small tip angle approximation. All algorithms are accompanied by precise floating point operation counts to assess and compare the computational efforts. We have implemented these algorithms as callback functions of an interior-point solver. We have applied this numerical optimization method to example problems from the literature and report key observations. PMID:26232364

  10. Transport coefficients in second-order non-conformal viscous hydrodynamics

    NASA Astrophysics Data System (ADS)

    Ryblewski, Radoslaw

    2015-05-01

    Based on the exact solution of Boltzmann kinetic equation in the relaxation-time approximation, the precision of the two most recent formulations of relativistic second-order non-conformal viscous hydrodynamics (14-moment approximation and causal Chapman-Enskog method), standard Israel-Stewart theory, and anisotropic hydrodynamics framework, in the simple case of one-dimensional Bjorken expansion, is tested. It is demonstrated that the failure of Israel-Stewart theory in reproducing exact solutions of the Boltzmann kinetic equation occurs due to neglecting and/or choosing wrong forms of some of the second-order transport coefficients. In particular, the importance of shear-bulk couplings in the evolution equations for dissipative quantities is shown. One finds that, in the case of the bulk viscous pressure correction, such coupling terms are as important as the corresponding first-order Navier-Stokes term and must be included in order to obtain, at least qualitative, overall agreement with the kinetic theory.

  11. A new second-order integration algorithm for simulating mechanical dynamic systems

    NASA Technical Reports Server (NTRS)

    Howe, R. M.

    1989-01-01

    A new integration algorithm which has the simplicity of Euler integration but exhibits second-order accuracy is described. In fixed-step numerical integration of differential equations for mechanical dynamic systems the method represents displacement and acceleration variables at integer step times and velocity variables at half-integer step times. Asymptotic accuracy of the algorithm is twice that of trapezoidal integration and ten times that of second-order Adams-Bashforth integration. The algorithm is also compatible with real-time inputs when used for a real-time simulation. It can be used to produce simulation outputs at double the integration frame rate, i.e., at both half-integer and integer frame times, even though it requires only one evaluation of state-variable derivatives per integration step. The new algorithm is shown to be especially effective in the simulation of lightly-damped structural modes. Both time-domain and frequency-domain accuracy comparisons with traditional integration methods are presented. Stability of the new algorithm is also examined.

  12. Second order effects in RCI calculations of La^-, Ce^- and Lu^- electron affinities

    NASA Astrophysics Data System (ADS)

    O'Malley, Steven M.; Beck, Donald R.

    2000-06-01

    Recent improvements in the relativistic configuration interaction method have relied upon identifying problem configurations that exhibit losses of energy contribution between consecutive stages of the calculations. These losses occur due to the differential pulling away of the manifold of interest as it is more fully correlated. To recoup some of these losses we add second order effects by including excitations from the problem configurations which are also important first order contributors to the energies of the levels of interest. Three recent studies of the rare earths La^- (S. M. O'Malley and D. R. Beck, Phys. Rev. A 60), 2558 (1999), Ce^- (S. M. O'Malley and D. R. Beck, Phys. Rev. A, in press) and Lu^- (S. M. O'Malley and D. R. Beck, submitted to Phys. Rev. A) have indicated increases in electron affinities over previous estimates by Vosko et al. (S. H. Vosko, J. B. Lagowski, I. L. Mayer and J. A. Chevary, Phys. Rev. A 43), 6389 (1991) and S. H. Vosko and J. A. Chevary, J. Phys. B 26, 873 (1993) and our own group (K. Dinov, D. R. Beck, and D. Datta, Phys. Rev. A 50), 1144 (1994) on the order of 100 meV, primarily due to inclusion of this second order correlation.

  13. Effects of polarons on static polarizabilities and second order hyperpolarizabilities of conjugated polymers

    NASA Astrophysics Data System (ADS)

    Wang, Ya-Dong; Meng, Yan; Di, Bing; Wang, Shu-Ling; An, Zhong

    2010-12-01

    According to the one-dimensional tight-binding Su—Schrieffer—Heeger model, we have investigated the effects of charged polarons on the static polarizability, αxx, and the second order hyperpolarizabilities, γxxxx, of conjugated polymers. Our results are consistent qualitatively with previous ab initio and semi-empirical calculations. The origin of the universal growth is discussed using a local-view formalism that is based on the local atomic charge derivatives. Furthermore, combining the Su-Schrieffer-Heeger model and the extended Hubbard model, we have investigated systematically the effects of electron-electron interactions on αxx and γxxxx of charged polymer chains. For a fixed value of the nearest-neighbour interaction V, the values of αxx and γxxxx increase as the on-site Coulomb interaction U increases for U < Uc and decrease with U for U > Uc, where Uc is a critical value of U at which the static polarizability or the second order hyperpolarizability reaches a maximal value of αmax or γmax. It is found that the effect of the e-e interaction on the value of αxx is dependent on the ratio between U and V for either a short or a long charged polymer. Whereas, that effect on the value of γxxxx is sensitive both to the ratio of U to V and to the size of the molecule.

  14. ℓ-oscillators from second-order invariant PDEs of the centrally extended conformal Galilei algebras

    NASA Astrophysics Data System (ADS)

    Aizawa, N.; Kuznetsova, Z.; Toppan, F.

    2015-03-01

    We construct, for any given ℓ = /1 2 + N 0 , the second-order, linear partial differential equations (PDEs) which are invariant under the centrally extended conformal Galilei algebra. At the given ℓ, two invariant equations in one time and ℓ + /1 2 space coordinates are obtained. The first equation possesses a continuum spectrum and generalizes the free Schrödinger equation (recovered for ℓ = /1 2 ) in 1 + 1 dimension. The second equation (the "ℓ-oscillator") possesses a discrete, positive spectrum. It generalizes the 1 + 1-dimensional harmonic oscillator (recovered for ℓ = /1 2 ). The spectrum of the ℓ-oscillator, derived from a specific osp(1|2ℓ + 1) h.w.r., is explicitly presented. The two sets of invariant PDEs are determined by imposing (representation-dependent) on-shell invariant conditions both for degree 1 operators (those with continuum spectrum) and for degree 0 operators (those with discrete spectrum). The on-shell condition is better understood by enlarging the conformal Galilei algebras with the addition of certain second-order differential operators. Two compatible structures (the algebra/superalgebra duality) are defined for the enlarged set of operators.

  15. Increasing returns to scale: The solution to the second-order social dilemma.

    PubMed

    Ye, Hang; Chen, Shu; Luo, Jun; Tan, Fei; Jia, Yongmin; Chen, Yefeng

    2016-01-01

    Humans benefit from extensive cooperation; however, the existence of free-riders may cause cooperation to collapse. This is called the social dilemma. It has been shown that punishing free-riders is an effective way of resolving this problem. Because punishment is costly, this gives rise to the second-order social dilemma. Without exception, existing solutions rely on some stringent assumptions. This paper proposes, under very mild conditions, a simple model of a public goods game featuring increasing returns to scale. We find that punishers stand out and even dominate the population provided that the degree of increasing returns to scale is large enough; consequently, the second-order social dilemma dissipates. Historical evidence shows that people are more willing to cooperate with others and punish defectors when they suffer from either internal or external menaces. During the prehistoric age, the abundance of contributors was decisive in joint endeavours such as fighting floods, defending territory, and hunting. These situations serve as favourable examples of public goods games in which the degrees of increasing returns to scale are undoubtedly very large. Our findings show that natural selection has endowed human kind with a tendency to pursue justice and punish defection that deviates from social norms. PMID:27535087

  16. Increasing returns to scale: The solution to the second-order social dilemma

    PubMed Central

    Ye, Hang; Chen, Shu; Luo, Jun; Tan, Fei; Jia, Yongmin; Chen, Yefeng

    2016-01-01

    Humans benefit from extensive cooperation; however, the existence of free-riders may cause cooperation to collapse. This is called the social dilemma. It has been shown that punishing free-riders is an effective way of resolving this problem. Because punishment is costly, this gives rise to the second-order social dilemma. Without exception, existing solutions rely on some stringent assumptions. This paper proposes, under very mild conditions, a simple model of a public goods game featuring increasing returns to scale. We find that punishers stand out and even dominate the population provided that the degree of increasing returns to scale is large enough; consequently, the second-order social dilemma dissipates. Historical evidence shows that people are more willing to cooperate with others and punish defectors when they suffer from either internal or external menaces. During the prehistoric age, the abundance of contributors was decisive in joint endeavours such as fighting floods, defending territory, and hunting. These situations serve as favourable examples of public goods games in which the degrees of increasing returns to scale are undoubtedly very large. Our findings show that natural selection has endowed human kind with a tendency to pursue justice and punish defection that deviates from social norms. PMID:27535087

  17. Analysis of heart rate variability signal in meditation using second-order difference plot

    NASA Astrophysics Data System (ADS)

    Goswami, Damodar Prasad; Tibarewala, Dewaki Nandan; Bhattacharya, Dilip Kumar

    2011-06-01

    In this article, the heart rate variability signal taken from subjects practising different types of meditations have been investigated to find the underlying similarity among them and how they differ from the non-meditative condition. Four different groups of subjects having different meditation techniques are involved. The data have been obtained from the Physionet and also collected with our own ECG machine. For data analysis, the second order difference plot is applied. Each of the plots obtained from the second order differences form a single cluster which is nearly elliptical in shape except for some outliers. In meditation, the axis of the elliptical cluster rotates anticlockwise from the cluster formed from the premeditation data, although the amount of rotation is not of the same extent in every case. This form study reveals definite and specific changes in the heart rate variability of the subjects during meditation. All the four groups of subjects followed different procedures but surprisingly the resulting physiological effect is the same to some extent. It indicates that there is some commonness among all the meditative techniques in spite of their apparent dissimilarity and it may be hoped that each of them leads to the same result as preached by the masters of meditation. The study shows that meditative state has a completely different physiology and that it can be achieved by any meditation technique we have observed. Possible use of this tool in clinical setting such as in stress management and in the treatment of hypertension is also mentioned.

  18. First- and second-order elliptic conditional moment closure calculations of piloted methane diffusion flames

    SciTech Connect

    Fairweather, M.; Woolley, R.M.

    2007-07-15

    Presented are results obtained from the application of a first- and higher-order conditional moment closure (CMC) approach to the modeling of three methane diffusion flames at differing levels of local extinction. In addition to the analysis of higher-order chemistry applications, the results obtained from an elliptic formulation of the CMC equation are considered next to parabolic results presented in previous work. All predictions are based upon second-moment turbulence and scalar-flux closures, and the chemistry applied to represent mean production rates of species is a 16-step reduced mechanism. A second-order chemistry is implemented on the basis of a two-step kinetic representation of methane combustion, used to correct first-order rates. In general, predictions obtained using the second-order model improve significantly upon first-order results for both major and minor species under fuel-rich conditions. The simplified chemistry employed does not however fully capture the effects of local extinction, and suggestions are made regarding the further developments required to permit the accurate prediction of highly strained flames using CMC methods. (author)

  19. Sachs-Wolfe at second order: the CMB bispectrum on large angular scales

    SciTech Connect

    Boubekeur, Lotfi; Creminelli, Paolo; D'Amico, Guido; Noreña, Jorge; Vernizzi, Filippo E-mail: creminel@ictp.it E-mail: norena@sissa.it

    2009-08-01

    We calculate the Cosmic Microwave Background anisotropy bispectrum on large angular scales in the absence of primordial non-Gaussianities, assuming exact matter dominance and extending at second order the classic Sachs-Wolfe result δT/T = Φ/3. The calculation is done in Poisson gauge. Besides intrinsic contributions calculated at last scattering, one must consider integrated effects. These are associated to lensing, and to the time dependence of the potentials (Rees-Sciama) and of the vector and tensor components of the metric generated at second order. The bispectrum is explicitly computed in the flat-sky approximation. It scales as l{sup −4} in the scale invariant limit and the shape dependence of its various contributions is represented in 3d plots. Although all the contributions to the bispectrum are parametrically of the same order, the full bispectrum is dominated by lensing. In the squeezed limit it corresponds to f{sub NL}{sup local} = −1/6−cos(2θ), where θ is the angle between the short and the long modes; the angle dependent contribution comes from lensing. In the equilateral limit it corresponds to f{sub NL}{sup equil} ≅ 3.13.

  20. Signal representation on the angular Poincaré sphere, based on second-order moments.

    PubMed

    Bastiaans, Martin J; Alieva, Tatiana

    2010-04-01

    Based on the analysis of second-order moments, a generalized canonical representation of a two-dimensional optical signal is proposed, which is associated with the angular Poincaré sphere. Vortex-free (or zero-twist) optical beams arise on the equator of this sphere, while beams with a maximum vorticity (or maximum twist) are located at the poles. An easy way is shown how the latitude on the sphere, which is a measure for the degree of vorticity, can be derived from the second-order moments. The latitude is invariant when the beam propagates through a first-order optical system between conjugate planes. To change the vorticity of a beam, a system that does not operate between conjugate planes is needed, with the gyrator as the prime representative of such a system. A direct way is derived to find an optical system (consisting of a lens, a magnifier, a rotator, and a gyrator) that transforms a beam with an arbitrary moment matrix into its canonical form. PMID:20360834

  1. Cosmology in generalized Horndeski theories with second-order equations of motion

    NASA Astrophysics Data System (ADS)

    Kase, Ryotaro; Tsujikawa, Shinji

    2014-08-01

    We study the cosmology of an extended version of Horndeski theories with second-order equations of motion on the flat Friedmann-Lemaître-Robertson-Walker background. In addition to a dark energy field χ associated with the gravitational sector, we take into account multiple scalar fields ϕI (I =1,2,…,N-1) characterized by the Lagrangians P(I)(XI) with XI=∂μϕI∂μϕI. These additional scalar fields can model the perfect fluids of radiation and nonrelativistic matter. We derive propagation speeds of scalar and tensor perturbations as well as conditions for the absence of ghosts. The theories beyond Horndeski induce nontrivial modifications to all the propagation speeds of N scalar fields, but the modifications to those for the matter fields ϕI are generally suppressed relative to that for the dark energy field χ. We apply our results to the covariantized Galileon with an Einstein-Hilbert term in which partial derivatives of the Minkowski Galileon are replaced by covariant derivatives. Unlike the covariant Galileon with second-order equations of motion in general space-time, the scalar propagation speed square cs12 associated with the field χ becomes negative during the matter era for late-time tracking solutions, so the two Galileon theories can be clearly distinguished at the level of linear cosmological perturbations.

  2. Seeing the unseen: Second-order correlation learning in 7- to 11-month-olds.

    PubMed

    Yermolayeva, Yevdokiya; Rakison, David H

    2016-07-01

    We present four experiments with the object-examining procedure that investigated 7-, 9-, and 11-month-olds' ability to associate two object features that were never presented simultaneously. In each experiment, infants were familiarized with a number of 3D objects that incorporated different correlations among the features of those objects and the body of the objects (e.g., Part A and Body 1, and Part B and Body 1). Infants were then tested with objects with a novel body that either possessed both of the parts that were independently correlated with one body during familiarization (e.g., Part A and B on Body 3) or that were attached to two different bodies during familiarization. The experiments demonstrate that infants as young as 7months of age are capable of this kind of second-order correlation learning. Furthermore, by at least 11months of age infants develop a representation for the object that incorporates both of the features they experienced during training. We suggest that the ability to learn second-order correlations represents a powerful but as yet largely unexplored process for generalization in the first years of life. PMID:27038738

  3. Enhanced modified Smith predictor for second-order non-minimum phase unstable processes

    NASA Astrophysics Data System (ADS)

    Uma, S.; Seshagiri Rao, A.

    2016-03-01

    In this paper, a modified Smith predictor design is proposed for enhanced control of non-minimum phase unstable second-order time-delay processes with/without zero. The proposed method involves the design of two controllers, i.e. set-point tracking controller and disturbance rejection controller. Set-point tracking controller is designed as a proportional-integral-derivative (PID) in series with a lag filter using direct synthesis method. The disturbance rejection controller is designed as a PID in series with a lead/lag filter based on direct synthesis method. Set-point weighting is considered for minimising the overshoots. The proposed method is applied by simulation on several second-order unstable processes. Robustness studies have been carried out using the small-gain theorem. The method gives good nominal and robust control performances. Significant improvement in the disturbance rejection is obtained with the proposed method when compared to the recently reported methods in the literature.

  4. Second-Order Controllability of Multi-Agent Systems with Multiple Leaders

    NASA Astrophysics Data System (ADS)

    Liu, Bo; Shi, Yun-Tao; Su, Hou-Sheng; Han, Xiao

    2016-05-01

    This paper proposes a new second-order continuous-time multi-agent model and analyzes the controllability of second-order multi-agent system with multiple leaders based on the asymmetric topology. This paper considers the more general case: velocity coupling topology is different from location coupling topology. Some sufficient and necessary conditions are presented for the controllability of the system with multiple leaders. In addition, the paper studies the controllability of the system with velocity damping gain. Simulation results are given to illustrate the correctness of theoretical results. Supported by the National Natural Science Foundation of China under Grant Nos. 61473129, 61304049, 61104140, 61473002, the Beijing Natural Science Foundation Program under Grant No. 4132021, the Program for New Century Excellent Talents in University from Chinese Ministry of Education under Grant NCET-12-0215, “The-Great-Wall-Scholar” Candidate Training-Plan of North China University of Technology (NX130), and the Plan Training Project of Excellent Young Teacher of North China University of Technology (NX132), the Fundamental Research Funds for the Central Universities, (HUST: Grant No. 2015TS025), the Fundamental Research Funds for the Central Universities (WUT: Grant No. 2015VI015)

  5. Modeling of finite-amplitude sound beams: second order fields generated by a parametric loudspeaker.

    PubMed

    Yang, Jun; Sha, Kan; Gan, Woon-Seng; Tian, Jing

    2005-04-01

    The nonlinear interaction of sound waves in air has been applied to sound reproduction for audio applications. A directional audible sound can be generated by amplitude-modulating the ultrasound carrier with an audio signal, then transmitting it from a parametric loudspeaker. This brings the need of a computationally efficient model to describe the propagation of finite-amplitude sound beams for the system design and optimization. A quasilinear analytical solution capable of fast numerical evaluation is presented for the second-order fields of the sum-, difference-frequency and second harmonic components. It is based on a virtual-complex-source approach, wherein the source field is treated as an aggregation of a set of complex virtual sources located in complex distance, then the corresponding fundamental sound field is reduced to the computation of sums of simple functions by exploiting the integrability of Gaussian functions. By this result, the five-dimensional integral expressions for the second-order sound fields are simplified to one-dimensional integrals. Furthermore, a substantial analytical reduction to sums of single integrals also is derived for an arbitrary source distribution when the basis functions are expressible as a sum of products of trigonometric functions. The validity of the proposed method is confirmed by a comparison of numerical results with experimental data previously published for the rectangular ultrasonic transducer. PMID:16060510

  6. Assessment of Patellar Tendon Reflex Responses Using Second-Order System Characteristics

    PubMed Central

    Steineman, Brett D.; Karra, Pavan; Park, Kiwon

    2016-01-01

    Deep tendon reflex tests, such as the patellar tendon reflex (PTR), are widely accepted as simple examinations for detecting neurological disorders. Despite common acceptance, the grading scales remain subjective, creating an opportunity for quantitative measures to improve the reliability and efficacy of these tests. Previous studies have demonstrated the usefulness of quantified measurement variables; however, little work has been done to correlate experimental data with theoretical models using entire PTR responses. In the present study, it is hypothesized that PTR responses may be described by the exponential decay rate and damped natural frequency of a theoretical second-order system. Kinematic data was recorded from both knees of 45 subjects using a motion capture system and correlation analysis found that the mean R2 value was 0.99. Exponential decay rate and damped natural frequency ranges determined from the sample population were −5.61 to −1.42 and 11.73 rad/s to 14.96 rad/s, respectively. This study confirmed that PTR responses strongly correlate to a second-order system and that exponential decay rate and undamped natural frequency are novel measurement variables to accurately measure PTR responses. Therefore, further investigation of these measurement variables and their usefulness in grading PTR responses is warranted. PMID:27041981

  7. Structural diversification and photocatalytic properties of three Cd(II) coordination polymers decorated with different auxiliary ligands

    NASA Astrophysics Data System (ADS)

    Yin, Wen-Yu; Zhuang, Guo-Yong; Huang, Zuo-Long; Cheng, Hong-Jian; Zhou, Li; Ma, Man-Hong; Wang, Hao; Tang, Xiao-Yan; Ma, Yun-Sheng; Yuan, Rong-Xin

    2016-03-01

    Three cadmium coordination polymers, [Cd(bismip)]n (1), {[Cd(bismip)(phen)]·H2O}n (2) and {[Cd2(bismip)2(4,4‧-bipy)]·2H2O}n (3) (H2bismip=5-(1H-benzoimidazol-2-ylsulfanylmethyl)-isophthalic acid, phen=1,10-phenanthroline, 4,4‧-bipy=4,4‧-bipyridine) have been prepared under solvothermal conditions. In 1, the [Cd4(bismip)3] units are jointed by bismip ligands to afford a three-dimensional (3D) architecture. Complex 2 exhibits a 3D supramolecular framework based on the interconnection of 1D chains through hydrogen bonding interactions and π-π packing interactions. 3 is a two-fold interpenetrating 3D architecture with a (4·82)(42·84) Schläfli symbol in which 2D layers are interlinked by 4,4‧-bipy ligands. The diverse structures of compounds 1-3 indicate that the auxiliary ligands have significant effects on the final structures. The photoluminescent properties and photocatalytic properties of these coordination polymers in the solid state were also investigated. Remarkably, 3 shows the wide gap semiconductor nature and exhibit excellent photocatalytic performance.

  8. An adaptive, formally second order accurate version of the immersed boundary method

    NASA Astrophysics Data System (ADS)

    Griffith, Boyce E.; Hornung, Richard D.; McQueen, David M.; Peskin, Charles S.

    2007-04-01

    Like many problems in biofluid mechanics, cardiac mechanics can be modeled as the dynamic interaction of a viscous incompressible fluid (the blood) and a (visco-)elastic structure (the muscular walls and the valves of the heart). The immersed boundary method is a mathematical formulation and numerical approach to such problems that was originally introduced to study blood flow through heart valves, and extensions of this work have yielded a three-dimensional model of the heart and great vessels. In the present work, we introduce a new adaptive version of the immersed boundary method. This adaptive scheme employs the same hierarchical structured grid approach (but a different numerical scheme) as the two-dimensional adaptive immersed boundary method of Roma et al. [A multilevel self adaptive version of the immersed boundary method, Ph.D. Thesis, Courant Institute of Mathematical Sciences, New York University, 1996; An adaptive version of the immersed boundary method, J. Comput. Phys. 153 (2) (1999) 509-534] and is based on a formally second order accurate (i.e., second order accurate for problems with sufficiently smooth solutions) version of the immersed boundary method that we have recently described [B.E. Griffith, C.S. Peskin, On the order of accuracy of the immersed boundary method: higher order convergence rates for sufficiently smooth problems, J. Comput. Phys. 208 (1) (2005) 75-105]. Actual second order convergence rates are obtained for both the uniform and adaptive methods by considering the interaction of a viscous incompressible flow and an anisotropic incompressible viscoelastic shell. We also present initial results from the application of this methodology to the three-dimensional simulation of blood flow in the heart and great vessels. The results obtained by the adaptive method show good qualitative agreement with simulation results obtained by earlier non-adaptive versions of the method, but the flow in the vicinity of the model heart valves

  9. Implementing the Second-Order Fermi Process in a Kinetic Monte-Carlo Simulation

    NASA Astrophysics Data System (ADS)

    Summerlin, E. J.

    2010-12-01

    Kinetic Monte-Carlo test-particle simulations require a way to simulate the effects of turbulence on particles. One way to do this is to prescribe a phenomenological scattering mechanism based on an empirical and/or qualitative description of turbulent scattering. Previous incarnations of the simulation presented here parameterize a scattering mean free path proportional to some power of the particle’s momentum in agreement with observational evidence from many sources. The scattering itself was done by scattering of the particle’s local fluid frame velocity onto a sphere of radius |v| via either large of small angle scattering. However, in real plasmas the scattering centers (turbulent plasma waves) are not stationary in the local fluid frame and particle velocities should, instead, be randomized in the frame of the moving scattering centers (which presumably move with the Alfvén speed) to more accurately represent the effects of turbulence on particles. Allowing scattering centers to move introduces heating as particles now diffuse in momentum as well as space (receiving a random kick of order the Alfvén speed at each scattering event). In 1965, Eugene Parker considered this effect (then called fermi acceleration) for cosmic ray particles and (correctly) concluded that it was negligible for those highly energetic particles because the particle speed was so much larger than the Alfvén speed kick which it received. However, doing the same calculation for thermal particles embedded in the solar wind (for whom a single kick of an Alfvén speed is significant) yields a very different result and it becomes clear that this process, now called second-order Fermi acceleration, must be included to get an accurate picture of particle acceleration in the heliosphere. This presentation will highlight the theoretical argument for the importance of second-order fermi acceleration in both the solar wind and shock environs as well as problems in heliophysics to which it

  10. FAST TRACK COMMUNICATION: On the Liouvillian solution of second-order linear differential equations and algebraic invariant curves

    NASA Astrophysics Data System (ADS)

    Man, Yiu-Kwong

    2010-10-01

    In this communication, we present a method for computing the Liouvillian solution of second-order linear differential equations via algebraic invariant curves. The main idea is to integrate Kovacic's results on second-order linear differential equations with the Prelle-Singer method for computing first integrals of differential equations. Some examples on using this approach are provided.

  11. The Development of Expert Face Processing: Are Infants Sensitive to Normal Differences in Second-Order Relational Information?

    ERIC Educational Resources Information Center

    Hayden, Angela; Bhatt, Ramesh S.; Reed, Andrea; Corbly, Christine R.; Joseph, Jane E.

    2007-01-01

    Sensitivity to second-order relational information (i.e., spatial relations among features such as the distance between eyes) is a vital part of achieving expertise with face processing. Prior research is unclear on whether infants are sensitive to second-order differences seen in typical human populations. In the current experiments, we examined…

  12. Second-order power spectra of CMB anisotropies due to primordial random perturbations in flat cosmological models

    SciTech Connect

    Tomita, Kenji

    2008-05-15

    Second-order power spectra of cosmic microwave background (CMB) anisotropies due to random primordial perturbations at the matter-dominant stage are studied, based on the relativistic second-order theory of perturbations in flat cosmological models and on the second-order formula of CMB anisotropies derived by Mollerach and Matarrese. So far the second-order integrated Sachs-Wolfe effect has been analyzed using the three-point correlation or bispectrum. In this paper we derive the second-order term of power spectra given using the two-point correlation of temperature fluctuations. The second-order density perturbations are small, compared with the first-order ones. The second-order power spectra of CMB anisotropies, however, are not small at all, compared with the first-order power spectra, because at the early stage the first-order integrated Sachs-Wolfe effect is very small and the second-order integrated Sachs-Wolfe effect may be dominant over the first-order ones. So their characteristic behaviors may be measured through future precise observation and bring useful information on the structure and evolution of our universe in the future.

  13. Influence of the mixing parameter on the second order moments of velocity and concentration in Rayleigh-Taylor turbulence

    NASA Astrophysics Data System (ADS)

    Soulard, Olivier; Griffond, Jérôme; Gréa, Benoît-Joseph

    2016-06-01

    The purpose of this paper is to highlight the existence of simple algebraic expressions linking the second order moments of velocity and concentration in Rayleigh-Taylor turbulence, in the Boussinesq limit. Focusing on the concentration variance, these relations allow to underline the influence of mixing on the remaining second order correlations, as well as on the growth rate of the mixing zone.

  14. Approach Detect Sensor System by Second Order Derivative of Laser Irradiation Area

    NASA Astrophysics Data System (ADS)

    Hayashi, Tomohide; Yano, Yoshikazu; Tsuda, Norio; Yamada, Jun

    In recent years, as a result of a large amount of greenhouse gas emission, atmosphere temperature at ground level gradually rises. Therefore the Kyoto Protocol was adopted to solve the matter in 1997. By the energy-saving law amended in 1999, it is advisable that an escalator is controlled to pause during no user. Now a photo-electric sensor is used to control escalator, but a pole to install the sensor is needed. Then, a new type of approach detection sensor using laser diode, CCD camera and CPLD, which can be built-in escalator, has been studied. This sensor can derive the irradiated area of laser beam by simple processing in which the laser beam is irradiated in only the odd field of the interlace video signal. By second order derivative of laser irradiated area, this sensor can detect only the approaching target but can not detect the target which crosses and stands in the sensing area.

  15. Generalized second-order slip boundary condition for nonequilibrium gas flows.

    PubMed

    Guo, Zhaoli; Qin, Jishun; Zheng, Chuguang

    2014-01-01

    It is a challenging task to model nonequilibrium gas flows within a continuum-fluid framework. Recently some extended hydrodynamic models in the Navier-Stokes formulation have been developed for such flows. A key problem in the application of such models is that suitable boundary conditions must be specified. In the present work, a generalized second-order slip boundary condition is developed in which an effective mean-free path considering the wall effect is used. By combining this slip scheme with certain extended Navier-Stokes constitutive relation models, we obtained a method for nonequilibrium gas flows with solid boundaries. The method is applied to several rarefied gas flows involving planar or curved walls, including the Kramers' problem, the planar Poiseuille flow, the cylindrical Couette flow, and the low speed flow over a sphere. The results show that the proposed method is able to give satisfied predictions, indicating the good potential of the method for nonequilibrium flows. PMID:24580334

  16. FASTSIM2: a second-order accurate frictional rolling contact algorithm

    NASA Astrophysics Data System (ADS)

    Vollebregt, E. A. H.; Wilders, P.

    2011-01-01

    In this paper we consider the frictional (tangential) steady rolling contact problem. We confine ourselves to the simplified theory, instead of using full elastostatic theory, in order to be able to compute results fast, as needed for on-line application in vehicle system dynamics simulation packages. The FASTSIM algorithm is the leading technology in this field and is employed in all dominant railway vehicle system dynamics packages (VSD) in the world. The main contribution of this paper is a new version "FASTSIM2" of the FASTSIM algorithm, which is second-order accurate. This is relevant for VSD, because with the new algorithm 16 times less grid points are required for sufficiently accurate computations of the contact forces. The approach is based on new insights in the characteristics of the rolling contact problem when using the simplified theory, and on taking precise care of the contact conditions in the numerical integration scheme employed.

  17. A second-order closure prediction of premixed turbulent combustion in jets

    NASA Astrophysics Data System (ADS)

    Davé, N.; Kollmann, W.

    1987-02-01

    In this paper, a numerical prediction is reported involving second-order closure of a turbulent flow of a vertically burning, lean mixture of premixed combustible gases discharging from a pipe and developing into a turbulent combusting roundjet. Classical closures are used where available. Expressions for the chemical reaction rate term and other unclosed terms related to variable density flow in the Favre-averaged turbulent transport equations are based on the Bray-Moss-Libby aerothermochemistry for premixed turbulent combustion, extended to variable enthalpy systems. Mixing of hot burned and cool ambient gases and the attendant buoyancy effects are found to be significant physical phenomena in the behavior of such lean premixed combusting jets. Results of the simulation are compared with experimental data of Yoshida [Proceedings of the Eighteenth International Symposium on Combustion (The Combustion Institute, Pittsburgh, 1981), p. 931] with which reasonable numerical agreement is obtained. Reasons for discrepancies and possible lines for future research are discussed.

  18. Observed galaxy number counts on the lightcone up to second order: II. Derivation

    SciTech Connect

    Bertacca, Daniele; Maartens, Roy; Clarkson, Chris E-mail: roy.maartens@gmail.com

    2014-11-01

    We present a detailed derivation of the observed galaxy number over-density on cosmological scales up to second order in perturbation theory. We include all relativistic effects that arise from observing on the past lightcone. The derivation is in a general gauge, and applies to all dark energy models (including interacting dark energy) and to metric theories of modified gravity. The result will be important for accurate cosmological parameter estimation, including non-Gaussianity, since all projection effects need to be taken into account. It also offers the potential for new probes of General Relativity, dark energy and modified gravity. This paper accompanies Paper I which presents the key results for the concordance model in Poisson gauge.

  19. Further development and testing of a second-order bulk boundary layer model. Master's thesis

    SciTech Connect

    Krasner, R.D.

    1993-05-03

    A one-layer bulk boundary layer model is developed. The model predicts the mixed layer values of the potential temperature, mixing ratio, and u- and v-momentum. The model also predicts the depth of the boundary layer and the vertically integrated turbulence kinetic energy (TKE). The TKE is determined using a second-order closure that relates the rate of dissipation to the TKE. The fractional area covered by rising motion sigma and the entrainment rate (E) are diagnostically determined. The model is used to study the clear convective boundary layer (CBL) using data from the Wangara, Australia boundary layer experiment. The Wangara data is also used as an observation base to validate model results. A further study is accomplished by simulating the planetary boundary layer (PBL) over an ocean surface. This study is designed to find the steady-state solutions of the prognostic variable.

  20. Treatment of Second-Order Structures of Proteins Using Oxygen Radio Frequency Plasma

    NASA Astrophysics Data System (ADS)

    Hayashi, Nobuya; Nakahigashi, Akari; Liu, Hao; Goto, Masaaki

    2010-08-01

    Decomposition characteristics of second-order structures of proteins are determined using an oxygen radio frequency (RF) plasma sterilizer in order to prevent infectious proteins from contaminating medical equipment in hospitals. The removal of casein protein as a test protein with a concentration of 50 mg/cm2 on the plane substrate requires approximately 8 h when singlet atomic oxygen is irradiated. The peak intensity of Fourier transform infrared spectroscopy (FTIR) spectra of the β-sheet structures decreases at approximately the same rate as those of the α-helix and first-order structures of proteins. Active oxygen has a sufficient oxidation energy to dissociate hydrogen bonds within the β-sheet structure.

  1. First and second order operator splitting methods for the phase field crystal equation

    SciTech Connect

    Lee, Hyun Geun; Shin, Jaemin; Lee, June-Yub

    2015-10-15

    In this paper, we present operator splitting methods for solving the phase field crystal equation which is a model for the microstructural evolution of two-phase systems on atomic length and diffusive time scales. A core idea of the methods is to decompose the original equation into linear and nonlinear subequations, in which the linear subequation has a closed-form solution in the Fourier space. We apply a nonlinear Newton-type iterative method to solve the nonlinear subequation at the implicit time level and thus a considerably large time step can be used. By combining these subequations, we achieve the first- and second-order accuracy in time. We present numerical experiments to show the accuracy and efficiency of the proposed methods.

  2. First-Order System Least-Squares for Second-Order Elliptic Problems with Discontinuous Coefficients

    NASA Technical Reports Server (NTRS)

    Manteuffel, Thomas A.; McCormick, Stephen F.; Starke, Gerhard

    1996-01-01

    The first-order system least-squares methodology represents an alternative to standard mixed finite element methods. Among its advantages is the fact that the finite element spaces approximating the pressure and flux variables are not restricted by the inf-sup condition and that the least-squares functional itself serves as an appropriate error measure. This paper studies the first-order system least-squares approach for scalar second-order elliptic boundary value problems with discontinuous coefficients. Ellipticity of an appropriately scaled least-squares bilinear form of the size of the jumps in the coefficients leading to adequate finite element approximation results. The occurrence of singularities at interface corners and cross-points is discussed. and a weighted least-squares functional is introduced to handle such cases. Numerical experiments are presented for two test problems to illustrate the performance of this approach.

  3. Second Order Catalytic Quasispecies Yields Discontinuous Mean Fitness at Error Threshold

    NASA Astrophysics Data System (ADS)

    Wagner, Nathaniel; Tannenbaum, Emmanuel; Ashkenasy, Gonen

    2010-05-01

    The quasispecies model describes processes related to the origin of life and viral evolutionary dynamics. We discuss how the error catastrophe that reflects the transition from localized to delocalized quasispecies population is affected by catalytic replication of different reaction orders. Specifically, we find that second order mechanisms lead to a discontinuity in the mean fitness of the population at the error threshold. This is in contrast to the behavior of the first order, autocatalytic replication mechanism considered in the standard quasispecies model. This suggests that quasispecies models with higher order replication mechanisms produce discontinuities in the mean fitness, and hence the viable population fraction as well, at the error threshold, while lower order replication mechanisms yield a continuous mean fitness function. We discuss potential implications for understanding replication in the RNA world and in virology.

  4. A second-order focusing electrostatic toroidal electron spectrometer with 2pi radian collection.

    PubMed

    Khursheed, Anjam; Hoang, Hung Quang

    2008-12-01

    This paper presents a toroidal electron energy spectrometer designed to capture electrons in the full 2pi azimuthal angular direction while at the same time having second-order focusing optics. Simulation results based upon direct ray tracing predict that the relative energy resolution of the spectrometer will be 0.146% and 0.0188% at input angular spreads of +/- 6 degrees and +/- 3 degrees, respectively, comparable to the theoretically best resolution of the cylindrical mirror analyzer (CMA), and an order of magnitude better than existing toroidal spectrometers. Also predicted for the spectrometer is a parallel energy acquisition mode of operation, where the energy bandwidth is expected to be > +/- 10% (20% total) of the pass energy. The spectrometer is designed to allow for retardation of the pass energy without the need to incorporate auxiliary lenses. PMID:18952374

  5. Determination of Second-Order Nonlinear Optical Susceptibility of GaN Films on Sapphire

    NASA Astrophysics Data System (ADS)

    Fujita, Takashi; Hasegawa, Tatsuo; Haraguchi, Masanobu; Okamoto, Toshihiro; Fukui, Masuo; Nakamura, Syuji

    2000-05-01

    The second-order nonlinear susceptibilities of GaN films on sapphire were determined by the Maker fringe technique. In deriving the second-harmonic intensity, the bound wave propagating from the GaN-air interface to the GaN-sapphire interface and that propagating in the opposite direction were taken into account. We obtained |χ(2)zxx|=14.7±0.2 pm/V, |χ(2)xzx|=14.4±0.2 pm/V and |χ(2)zzz|=29.7±0.7 pm/V for the GaN film with a thickness of 2.55 μm using fundamental light with a wavelength of 1.064 μm.

  6. Mass Polarization Effect in He-like Ions: First and Second Order

    NASA Technical Reports Server (NTRS)

    Bhatia, A. K.; Drachman, Richard J.

    2003-01-01

    In a paper with a similar title Yamanaka has calculated the mass polarization effect (to first order in mu/M for several low-lying states of the two-electron atoms and ions with atomic number Z from 2 to 10. Here we improve the previous results by using Hylleraas variational wave functions with up to 560 terms and extend the calculation to include some additional states and the Z=1ground state. In addition, we compute the second-order effect using the method of pseudostate summation. In one appendix another method of computation is discussed and used as a check, while the energies of the Z=1 ions are presented and discussed in a second appendix.

  7. Second order particle motion equations and linear chromaticity calculation in accelerator rings

    SciTech Connect

    Liu, R.Z.

    1984-01-01

    The first part of this note presents a thorough study on the second order particle motion equations, both in continuous field and in hard edges, with emphasis put on the latter. Having quite general conditions and strict mathematical treatments, it provides a sound ground from which many problems can be solved without fear of being misled. Then the linear CHR calculation is inspected, the first step being a general analytical expression of the transverse oscillation phase increment due to a small disturbance. The expression for the CHR is then readily obtained since tune is the transverse oscillation number per turn and the CHR is the linear dependence of the tune on particle energy/momentum deviation. The last part gives the formulae for practical CHR calculation, which are general enough to include almost all the magnet types commonly used in various accelerator rings and are simpler than can be found elsewhere.

  8. Photoassociation of a cold-atom-molecule pair. II. Second-order perturbation approach

    SciTech Connect

    Lepers, M.; Vexiau, R.; Bouloufa, N.; Dulieu, O.; Kokoouline, V.

    2011-04-15

    The electrostatic interaction between an excited atom and a diatomic ground-state molecule in an arbitrary rovibrational level at large mutual separations is investigated with a general second-order perturbation theory, in the perspective of modeling the photoassociation between cold atoms and molecules. We find that the combination of quadrupole-quadrupole and van der Waals interactions competes with the rotational energy of the dimer, limiting the range of validity of the perturbative approach to distances larger than 100 Bohr radii. Numerical results are given for the long-range interaction between Cs and Cs{sub 2}, showing that the photoassociation is probably efficient for any Cs{sub 2} rotational energy.

  9. DPDC (double-pass donor cell): A second-order monotone scheme for advection

    SciTech Connect

    Beason, C W; Margolin, L G

    1988-09-26

    We are developing a new, second-order, monotone scheme for advection. DPDC (i.e., double-pass donor cell) is based on Smolarkiewicz' simple, positive definite method. Both schemes are multipass methods in which upstream approximations to the truncation error are subtracted from the equations. We describe two significant improvements to Smolarkiewicz' method. First, we use a local gauge transformation to convert the method from being positive definite to the stronger condition of being monotone. Second, we analytically approximate the sum of the corrections of all the passes to use in a single corrective pass. This increases the accuracy of the method, but does not increase the order of accuracy. We compare DPDC with van Leer's method for advection of several different pulses in a constant velocity field. 5 refs., 4 figs.

  10. Measurement of two-dimensional optical system MTF by computation of second order speckle statistics

    NASA Astrophysics Data System (ADS)

    Lund, G.; Azouit, M.

    1980-04-01

    An interferometric approach to the calculation of the two-dimensional MTF of an optical system is proposed. The technique, in some ways analogous to that of speckle interferometry used in astronomical situations, is based on the computation of the second-order spatio-temporal statistics of a fluctuating speckle pattern. The theorum of Van Cittert-Zernike is invoked to relate the speckle, due to the illumination of a perfect diffuser by the point spread function of an optical system, to the two-dimensional MTF of the system. The computed MTF is displayed in the form of a contour map and can also be represented in the conventional form of a one-dimensional vertical cut. Preliminary measurements have yielded qualitatively useful results and clearly illustrate the suitability of two-dimensional maps for the detection of transfer function anisotropies.

  11. COMPARISON OF NUMERICAL METHODS FOR SOLVING THE SECOND-ORDER DIFFERENTIAL EQUATIONS OF MOLECULAR SCATTERING THEORY

    SciTech Connect

    Thomas, L.D.; Alexander, M.H.; Johnson, B.R.; Lester Jr., W. A.; Light, J.C.; McLenithan, K.D.; Parker, G.A.; Redmon, M.J.; Schmalz, T.G.; Secrest, D.; Walker, R.B.

    1980-07-01

    The numerical solution of coupled, second-order differential equations is a fundamental problem in theoretical physics and chemistry. There are presently over 20 commonly used methods. Unbiased comparisons of the methods are difficult to make and few have been attempted. Here we report a comparison of 11 different methods applied to 3 different test problems. The test problems have been constructed to approximate chemical systems of current research interest and to be representative of the state of the art in inelastic molecular collisions. All calculations were done on the same computer and the attempt was made to do all calculations to the same level of accuracy. The results of the initial tests indicated that an improved method might be obtained by using different methods in different integration regions. Such a hybrid program was developed and found to be at least 1.5 to 2.0 times faster than any individual method.

  12. A Second-Order Iterative Implicit Explicit Hybrid Scheme for Hyperbolic Systems of Conservation Laws

    NASA Astrophysics Data System (ADS)

    Dai, Wenlong; Woodward, Paul R.

    1996-10-01

    An iterative implicit-explicit hybrid scheme is proposed for hyperbolic systems of conservation laws. Each wave in a system may be implicitly, or explicitly, or partially implicitly and partially explicitly treated depending on its associated Courant number in each numerical cell, and the scheme is able to smoothly switch between implicit and explicit calculations. The scheme is of Godunov-type in both explicit and implicit regimes, is in a strict conservation form, and is accurate to second-order in both space and time for all Courant numbers. The computer code for the scheme is easy to vectorize. Multicolors proposed in this paper may reduce the number of iterations required to reach a converged solution by several orders for a large time step. The feature of the scheme is shown through numerical examples.

  13. Discrete Kalman filtering equations of second-order form for control-structure interaction simulations

    NASA Technical Reports Server (NTRS)

    Park, K. C.; Alvin, K. F.; Belvin, W. Keith

    1991-01-01

    A second-order form of discrete Kalman filtering equations is proposed as a candidate state estimator for efficient simulations of control-structure interactions in coupled physical coordinate configurations as opposed to decoupled modal coordinates. The resulting matrix equation of the present state estimator consists of the same symmetric, sparse N x N coupled matrices of the governing structural dynamics equations as opposed to unsymmetric 2N x 2N state space-based estimators. Thus, in addition to substantial computational efficiency improvement, the present estimator can be applied to control-structure design optimization for which the physical coordinates associated with the mass, damping and stiffness matrices of the structure are needed instead of modal coordinates.

  14. Second-order nonlinear optical susceptibilities in nonelectrically poled guest-host polymers with tricyanofuran chromophores

    NASA Astrophysics Data System (ADS)

    Ito, Kazuma; Sato, Yasuaki; Takasu, Ryosuke; Mase, Nobuyuki; Kawata, Yoshimasa; Tasaka, Shigeru; Sugita, Atsushi

    2014-01-01

    In this manuscript, we describe the current manuscript describes the second-order nonlinear optical susceptibility of guest-host polymers possessing chromophores with strongly electron-accepting tricyanofuran (TCF). Chromophores substituted with different numbers of hydroxyl groups were prepared. Our experimental results demonstrated that the guest-host polymers exhibited nonlinear optical susceptibilities simply upon annealing at temperatures higher than the glass transition point of the host polymers even in the absence of applied external DC electric fields. Nonelectrical poling behaviors were only available for the materials possessing hydroxyl-group-functionalized chromophores. The results indicate that chemisorption of the hydroxyl groups on the substrate led to the orientation order of the guest chromophores. The orientation order of the chromophores was reproduced well by the model of poled polymers in previous studies.

  15. Relaxation approximations to second-order traffic flow models by high-resolution schemes

    SciTech Connect

    Nikolos, I.K.; Delis, A.I.; Papageorgiou, M.

    2015-03-10

    A relaxation-type approximation of second-order non-equilibrium traffic models, written in conservation or balance law form, is considered. Using the relaxation approximation, the nonlinear equations are transformed to a semi-linear diagonilizable problem with linear characteristic variables and stiff source terms with the attractive feature that neither Riemann solvers nor characteristic decompositions are in need. In particular, it is only necessary to provide the flux and source term functions and an estimate of the characteristic speeds. To discretize the resulting relaxation system, high-resolution reconstructions in space are considered. Emphasis is given on a fifth-order WENO scheme and its performance. The computations reported demonstrate the simplicity and versatility of relaxation schemes as numerical solvers.

  16. Second-order robust regularization cost function for detecting and reconstructing phase discontinuities

    SciTech Connect

    Galvan, Carlos; Rivera, Mariano

    2006-01-10

    We propose a robust method for computing discontinuous phase maps from a fringe pattern with carrier frequency. Our algorithm is based on the minimization of an edge-preserving regularized cost function, specifically, on a robust regularized potential that uses a paradigm called the plate with adaptive rest condition, i.e., a second-order edge-preserving potential. Given that the proposed cost function is not convex, our method uses as its initial point an overly smoothed phase computed with a standard fringe analysis method and then reconstructs the phase discontinuities. Although the method is general purpose, it is introduced in the context of interferometric gauge-block calibration. The performance of the algorithm is demonstrated by numerical experiments with both synthetic and real data.

  17. Transmission performance improvement using random DFB laser based Raman amplification and bidirectional second-order pumping.

    PubMed

    Tan, M; Rosa, P; Le, S T; Iqbal, Md A; Phillips, I D; Harper, P

    2016-02-01

    We demonstrate that a distributed Raman amplification scheme based on random distributed feedback (DFB) fiber laser enables bidirectional second-order Raman pumping without increasing relative intensity noise (RIN) of the signal. This extends the reach of 10 × 116 Gb/s DP-QPSK WDM transmission up to 7915 km, compared with conventional Raman amplification schemes. Moreover, this scheme gives the longest maximum transmission distance among all the Raman amplification schemes presented in this paper, whilst maintaining relatively uniform and symmetric signal power distribution, and is also adjustable in order to be highly compatible with different nonlinearity compensation techniques, including mid-link optical phase conjugation (OPC) and nonlinear Fourier transform (NFT). PMID:26906797

  18. A First and Second Order Moment Approach to Probabilistic Control Synthesis

    NASA Technical Reports Server (NTRS)

    Crespo, Luis G.; Kenny, Sean P.

    2005-01-01

    This paper presents a robust control design methodology based on the estimation of the first two order moments of the random variables and processes that describe the controlled response. Synthesis is performed by solving an multi-objective optimization problem where stability and performance requirements in time- and frequency domains are integrated. The use of the first two order moments allows for the efficient estimation of the cost function thus for a faster synthesis algorithm. While reliability requirements are taken into account by using bounds to failure probabilities, requirements related to undesirable variability are implemented by quantifying the concentration of the random outcome about a deterministic target. The Hammersley Sequence Sampling and the First- and Second-Moment- Second-Order approximations are used to estimate the moments, whose accuracy and associated computational complexity are compared numerically. Examples using output-feedback and full-state feedback with state estimation are used to demonstrate the ideas proposed.

  19. Bioethics as a second-order discipline: who is not a bioethicist?

    PubMed

    Kopelman, Loretta M

    2006-12-01

    A dispute exists about whether bioethics should become a new discipline with its own methods, competency standards, duties, honored texts, and core curriculum. Unique expertise is a necessary condition for disciplines. Using the current literature, different views about the sort of expertise that might be unique to bioethicists are critically examined to determine if there is an expertise that might meet this requirement. Candidates include analyses of expertise based in "philosophical ethics," "casuistry," "atheoretical or situation ethics," "conventionalist relativism," "institutional guidance," "regulatory guidance and compliance," "political advocacy," "functionalism," and "principlism." None succeed in identifying a unique area of expertise for successful bioethicists that could serve as a basis for making it a new discipline. Rather expertise in bioethics is rooted in many professions, disciplines and fields and best understood as a second-order discipline. PMID:17162730

  20. Enhancing image watermarking methods with/without reference images by optimization on second-order statistics.

    PubMed

    Tzeng, Jengnan; Hwang, Wen-Liang; Chern, I-Liang

    2002-01-01

    The watermarking method has emerged as an important tool for content tracing, authentication, and data hiding in multimedia applications. We propose a watermarking strategy in which the watermark of a host is selected from the robust features of the estimated forged images of the host. The forged images are obtained from Monte Carlo simulations of potential pirate attacks on the host image. The solution of applying an optimization technique to the second-order statistics of the features of the forged images gives two orthogonal spaces. One of them characterizes most of the variations in the modifications of the host. Our watermark is embedded in the other space that most potential pirate attacks do not touch. Thus, the embedded watermark is robust. Our watermarking method uses the same framework for watermark detection with a reference and blind detection. We demonstrate the performance of our method under various levels of attacks. PMID:18244673