Science.gov

Sample records for early-cluster chemical pollution

  1. Microorganisms and Chemical Pollution

    ERIC Educational Resources Information Center

    Alexander, M.

    1973-01-01

    Discusses the importance of microorganisms in chemical pollution and pollution abatement. Selected chemical pollutants are chosen to illustrate that microorganisms synthesize hazardous substances from reasonably innocuous precursors, while others act as excellent environmental decontaminating agents by removing undesirable natural and synthetic…

  2. Chemical pollution from transportation vehicles.

    PubMed

    Starkman, E S

    1969-04-01

    Recent publicity on electrically powered vehicles notwithstanding, the gasoline engine will probably be the principal power plant for passenger cars for at least the next decade. Chemical pollutants discharged by the gasoline engine are now under partial control. Motor cars of 1968 and 1969 model discharge only about 30 percent as much carbon monoxide and unburned hydrocarbons as do older models. In theory, carbon monoxide, unburned hydrocarbons and oxides of nitrogen ultimately can be completely removed from gasoline engine exhaust. In order to accomplish this it would be necessary to modify cars to operate satisfactorily on a lean mixture and perhaps to use a catalyst in the exhaust system. Present designs of gas turbines for aircraft and for future projected application to ground vehicles yield pollutants (except for smoke) at levels below those of gasoline engines for a decade to come. It has also been shown possible to eliminate smoke as well as odor from the gas turbine. Thus with proper effort it is feasible to reduce pollution of the atmosphere due to transportation to an acceptable level, even if electrically or alternatively powered vehicles cannot be developed for a decade. PMID:4183827

  3. Exploring the planetary boundary for chemical pollution.

    PubMed

    Diamond, Miriam L; de Wit, Cynthia A; Molander, Sverker; Scheringer, Martin; Backhaus, Thomas; Lohmann, Rainer; Arvidsson, Rickard; Bergman, Åke; Hauschild, Michael; Holoubek, Ivan; Persson, Linn; Suzuki, Noriyuki; Vighi, Marco; Zetzsch, Cornelius

    2015-05-01

    Rockström et al. (2009a, 2009b) have warned that humanity must reduce anthropogenic impacts defined by nine planetary boundaries if "unacceptable global change" is to be avoided. Chemical pollution was identified as one of those boundaries for which continued impacts could erode the resilience of ecosystems and humanity. The central concept of the planetary boundary (or boundaries) for chemical pollution (PBCP or PBCPs) is that the Earth has a finite assimilative capacity for chemical pollution, which includes persistent, as well as readily degradable chemicals released at local to regional scales, which in aggregate threaten ecosystem and human viability. The PBCP allows humanity to explicitly address the increasingly global aspects of chemical pollution throughout a chemical's life cycle and the need for a global response of internationally coordinated control measures. We submit that sufficient evidence shows stresses on ecosystem and human health at local to global scales, suggesting that conditions are transgressing the safe operating space delimited by a PBCP. As such, current local to global pollution control measures are insufficient. However, while the PBCP is an important conceptual step forward, at this point single or multiple PBCPs are challenging to operationalize due to the extremely large number of commercial chemicals or mixtures of chemicals that cause myriad adverse effects to innumerable species and ecosystems, and the complex linkages between emissions, environmental concentrations, exposures and adverse effects. As well, the normative nature of a PBCP presents challenges of negotiating pollution limits amongst societal groups with differing viewpoints. Thus, a combination of approaches is recommended as follows: develop indicators of chemical pollution, for both control and response variables, that will aid in quantifying a PBCP(s) and gauging progress towards reducing chemical pollution; develop new technologies and technical and social

  4. Chemical air pollutants and otorhinolaryngeal toxicity

    SciTech Connect

    Bisesi, M.S.; Rubin, A.M. . Occupational Health and Otolaryngology)

    1994-03-01

    Air pollution and the specific issue regarding the impact of airborne chemical agents to human health are familiar topics to most members of the environmental health science and environmental medicine communities. Some aspects, however, have received relatively less attention. Much has been published regarding the impact of air pollutants on the human upper and lower respiratory system, including interaction with the rhinologic (nasal) system. Relatively fewer data have been published, however, regarding the potential impact of air pollutants in reference specifically to the otologic (auditory and vestibular) and the laryngeal (larynx) system. Adverse impact to the ears, nose and throat, referred to as the otorhinolaryngeal system'', warrants attention as an important environmental health issue. Toxic interactions from exposure to many chemical air pollutants not only causes potential respiratory irritation and lung disease, but can also result in impaired hearing, balance, sense of smell, taste, and speech due to interaction with related target systems. This may be significant to environmental health risk assessment of chemical air pollutants if multi-target site models are considered.

  5. Chemical pollution from AGB Stars

    NASA Astrophysics Data System (ADS)

    Cristallo, S.; Straniero, O.; Gallino, R.; Piersanti, L.; Dominguez, I.

    Low mass AGB Stars are the main contributors to the Galactic s-process enrichment. We present new theoretical results obtained by adopting a full network from H to Bi coupled with the physical evolution of the stellar structure. We describe the formation of a 13C pocket as a consequence of H diffusion from the envelope into the He-rich intershell. Such 13C is burnt during the interpulse phase and provides the main neutron source in these stars. We computed two models with the same total mass (that is 2 M⊙) but two different initial chemical composition, namely (Y=0.269 - Z=0.015) and (Y=0.245 - Z=0.0001), representative of disk and halo stars respectively. We evaluate the differences in the final s-process surface composition and compare the results with the available observational data.

  6. [Chemical pollution and breast milk: Taking positions].

    PubMed

    Díaz-Gómez, N M; Ares, S; Hernández-Aguilar, M T; Ortega-García, J A; Paricio-Talayero, J M; Landa-Rivera, L

    2013-12-01

    Chemical pollution affects all ecosystems of our planet. Human milk has been used as a biomarker of environmental pollution as, due to bioaccumulation processes in fat tissue, many chemical compounds reach measurable concentrations that can be readily tested in breast milk. Quite frequently information about the presence of contaminants in breast milk appears in the media, leading to misunderstanding among parents and health professionals, and in some cases breastfeeding the child is stopped. In this article, the Breastfeeding Committee of the Spanish Association of Paediatrics stresses the importance of promoting breastfeeding as the healthiest option, because its benefits clearly outweigh any health risks associated with chemical contaminants in breast milk. Breast milk contains protective factors that counteract the potential effects related to prenatal exposure to environmental pollutants. This article summarises the key recommendations to reduce the level of chemical contaminants in breast milk. It also highlights the importance of government involvement in the development of programs to eliminate or reduce chemical contamination of food and the environment. In this way, the negative effects on child health resulting from exposure to these toxic compounds through the placenta and breast milk may be prevented. PMID:23791806

  7. A POLLUTION REDUCTION METHODOLOGY FOR CHEMICAL PROCESS SIMULATORS

    EPA Science Inventory

    A pollution minimization methodology was developed for chemical process design using computer simulation. It is based on a pollution balance that at steady state is used to define a pollution index with units of mass of pollution per mass of products. The pollution balance has be...

  8. Chemical Biomarkers of Human Breast Milk Pollution

    PubMed Central

    Massart, Francesco; Gherarducci, Giulia; Marchi, Benedetta; Saggese, Giuseppe

    2008-01-01

    Human milk is, without question, the best source of nutrition for infants containing the optimal balance of fats, carbohydrates and proteins for developing babies. Breastfeeding provides a range of benefits for growth, immunity and development building a powerful bond between mother and her child. Recognition of the manifold benefits of breast milk has led to the adoption of breast-feeding policies by numerous health and professional organizations such as the World Health Organization and American Academy of Pediatrics. In industrially developed as well as in developing nations, human milk contamination by toxic chemicals such as heavy metals, dioxins and organohalogen compounds, however, is widespread and is the consequence of decades of inadequately controlled pollution. Through breastfeeding, the mother may transfer to the suckling infant potentially toxic chemicals to which the mother has previously been exposed. In the present review, environmental exposure, acquisition and current levels of old and emerging classes of breast milk pollutants are systematically presented. Although scientific evidences indicated that the advantages of breast-feeding outweigh any risks from contaminants, it is important to identify contaminant trends, to locate disproportionately exposed populations, and to take public health measures to improve chemical BM pollution as possible. PMID:19578503

  9. Confronting unknown planetary boundary threats from chemical pollution.

    PubMed

    Persson, Linn M; Breitholtz, Magnus; Cousins, Ian T; de Wit, Cynthia A; MacLeod, Matthew; McLachlan, Michael S

    2013-11-19

    Rockström et al. proposed a set of planetary boundaries that delimitate a "safe operating space for humanity". One of the planetary boundaries is determined by "chemical pollution", however no clear definition was provided. Here, we propose that there is no single chemical pollution planetary boundary, but rather that many planetary boundary issues governed by chemical pollution exist. We identify three conditions that must be simultaneously met for chemical pollution to pose a planetary boundary threat. We then discuss approaches to identify chemicals that could fulfill those conditions, and outline a proactive hazard identification strategy that considers long-range transport and the reversibility of chemical pollution. PMID:23980998

  10. SYSTEMS CHEMICAL ANALYSIS OF PETROLEUM POLLUTANTS

    EPA Science Inventory

    The application of an established mathematical treatment useful for the characterization and identification of petroleum pollutants is described. Using discriminant analysis of relevant infrared spectrophotometric data, 99% of numerous known and unknown oil samples have been corr...

  11. Method for detecting pollutants. [through chemical reactions and heat treatment

    NASA Technical Reports Server (NTRS)

    Rogowski, R. S.; Richards, R. R.; Conway, E. J. (Inventor)

    1976-01-01

    A method is described for detecting and measuring trace amounts of pollutants of the group consisting of ozone, nitrogen dioxide, and carbon monoxide in a gaseous environment. A sample organic solid material that will undergo a chemical reaction with the test pollutant is exposed to the test environment and thereafter, when heated in the temperature range of 100-200 C., undergoes chemiluminescence that is measured and recorded as a function of concentration of the test pollutant. The chemiluminescence of the solid organic material is specific to the pollutant being tested.

  12. Aerosol chemical components in Alaska air masses: 1. Aged pollution

    NASA Astrophysics Data System (ADS)

    Shaw, Glenn E.

    1991-12-01

    A 4-year Alaska chemical data set of aerosols or "dust" in the air clearly reveals a mixture of distinct aerosol components with different and interesting chemical composition, one or two being ascribed to pollution imported to Alaska by winds all the way from other continents. Of particular note is a strong chemical contrast between what we imagine to be highly scavenged, orographically lifted, northern Pacific air (Pacific marine air mass) and stagnant Arctic air (polar air mass), the latter containing seasonal average concentrations of between 2-4 times the concentration of the former, at least for pollution markers noncrustal vanadium, noncrustal manganese, arsenic, selenium, bromine, and antimony. The findings concur our old discovery that Arctic air is persistently polluted (Arctic haze), but Pacific air is relatively clean, in spite of the fact that Alaska is downwind of major pollution sources in the Orient. This is remarkable. In this the first of a two-part paper, we concentrate on the pollution component found primarily during incursion of Arctic polar air. Two major occurrences of visual haze with optical depths of approximately 0.2 and elevated aerosol concentration lasting about a month (spring 1985 and 1986) were affiliated with strong incoming transport of polar air, temperatures ranging from 10° to 20°C below normal (polar air) and air trajectory hindcasts leading back to industrial pollution sources in Eurasia. These long-range transport pollution events brought metal-rich aerosol of removal-resistant submicron particles. The size, chemistry, and meteorology all strongly suggest the presence of a well-aged (10-100 day) polluted air mass. An important implication is that in spring a large fraction of the Arctic polar air mass becomes charged with by-products of industrial pollution. In this multiyear chemical data set one finds a notable summer-winter contrast, changing by factors of 2 to 4 for pollution markers As, Se, Sb, and noncrustal

  13. EFFECT OF WATER POLLUTANTS AND OTHER CHEMICALS UPON RIBONUCLEASE ACTIVITY IN VITRO

    EPA Science Inventory

    Ribonuclease was treated in vitro with 73 chemicals, many of which are environmental pollutants, including inorganic, organic, and metal-organic chemicals, pesticides, and other biocides, alkyl and aryl industrial pollutants, and certain additional chemicals, to determine their e...

  14. 40 CFR 1.43 - Office of Chemical Safety and Pollution Prevention.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 1 2014-07-01 2014-07-01 false Office of Chemical Safety and Pollution... ORGANIZATION AND GENERAL INFORMATION Headquarters § 1.43 Office of Chemical Safety and Pollution Prevention. The Assistant Administrator, Office of Chemical Safety and Pollution Prevention (OCSPP), serves as...

  15. Chemical climatology of air pollutants at Pico Mountain Observatory

    NASA Astrophysics Data System (ADS)

    Zhang, B.; Owen, R. C.; Perlinger, J. A.; Val Martin, M.; Fialho, P. J.; Mazzoleni, L. R.

    2013-12-01

    Pico Mountain Observatory (PMO) was established in 2001 on top of Pico Mountain (38.47°N, 28.40°W, 2,225 m a.s.l.) in the Azores Islands. PMO frequently samples free troposphere air over the Central North Atlantic. Long-range transport from neighboring continents impacts the concentration of air pollutants at PMO, but North American outflows have the most frequent influence due to predominantly westerly wind in mid-latitude regions of the Northern Hemisphere. This study summarizes observations of gases and aerosol since the station was established and combines transport patterns simulated by FLEXPART with observations to investigate chemical signatures of transport patterns. As the first step, FLEXPART backward retroplumes released from PMO will be created for the periods covered by our observation datasets. These results will be used to determine and classify sources of the transported air for long time periods. Seasonal variations in sources and transport pathways will be examined. This information is critical to understand variations in air pollutant observations at PMO, because sources and transport trajectories define age and composition of air plumes that arrive at PMO. In the second step, transport associated with certain chemical signatures, e.g., elevated ozone combined with depressed CO, will be extracted, and transport patterns will be identified for each classified chemical signature. The analysis will reveal correlations between transport patterns and elevation of air pollutants at PMO, which will help to understand measurement datasets of multiple air pollutants. Impacts of anthropogenic and biomass burning emissions on CO concentration at PMO will also be determined through multiplying retroplumes with emission inventories. Long-term trends in impacts from both sources will be examined to find potential correlations with recently implemented air quality regulations, occurrence of wildfires, and global climate change.

  16. Chemical pollution of the environment: past, present and future.

    PubMed

    Hoffmann, M R

    1993-01-01

    In an era of 'global environmental change' people are concerned about emissions of CO2, CH4, N2O and chlorofluorocarbons (CFCs) to the atmosphere because of their direct impact on global warming and their stratospheric ozone-depleting effects. Unprecedented efforts have been made to reduce the global emissions of CFCs. Major industries, which are competing within the modern global economy, have recognized the importance of maintaining a 'green' perspective. Future operations will be designed to reduce the direct emissions of chemical by-products to air, water and soil, and to recycle and to reuse critical solvents such as water. 'Star Wars' technologies for the rapid, economical and effective elimination of industrial and domestic wastes will be developed and employed on a large scale. Advanced technologies for the control and monitoring of chemical pollutants on regional and global scales will be developed and implemented. Satellite-based instruments will be able to detect, to quantify, and to monitor a wide range of chemical pollutants. Our understanding of the fate and consequences of chemicals in the environment will increase dramatically such that we shall be able to predict the environmental, ecological and biochemical consequences of novel synthetic molecules with much greater precision. PMID:8222994

  17. The Automobile and Air Pollution: A Chemical Review of the Problem

    ERIC Educational Resources Information Center

    Wildeman, Thomas R.

    1974-01-01

    Summarizes chemical principles underlying the operation of automobiles and the cause of air pollution, including concentrations of carbon monoxide, unburned hydrocarbons, and oxides of nitrogen. Comments and opinions are made concerning present and future pollution control devices. (CC)

  18. PROTOTYPE ADVANCED COMPUTATIONAL SYSTEM FOR CHEMICAL FATE PARAMETERS FOR POLLUTANT FATE MODELS. SPARC.

    EPA Science Inventory

    SPARC (SPARC Performs Automated Reasoning in Chemistry) is a computer modeling system that calculates a large number of physical and chemical properties for chemical pollutants from their molecular structure and from basic information about the environment such as media, temperat...

  19. Chemical footprint: a methodological framework for bridging life cycle assessment and planetary boundaries for chemical pollution.

    PubMed

    Sala, Serenella; Goralczyk, Malgorzata

    2013-10-01

    The development and use of footprint methodologies for environmental assessment are increasingly important for both the scientific and political communities. Starting from the ecological footprint, developed at the beginning of the 1990s, several other footprints were defined, e.g., carbon and water footprint. These footprints-even though based on a different meaning of "footprint"-integrate life cycle thinking, and focus on some challenging environmental impacts including resource consumption, CO2 emission leading to climate change, and water consumption. However, they usually neglect relevant sources of impacts, as those related to the production and use of chemicals. This article presents and discusses the need and relevance of developing a methodology for assessing the chemical footprint, coupling a life cycle-based approach with methodologies developed in other contexts, such as ERA and sustainability science. Furthermore, different concepts underpin existing footprint and this could be the case also of chemical footprint. At least 2 different approaches and steps to chemical footprint could be envisaged, applicable at the micro- as well as at the meso- and macroscale. The first step (step 1) is related to the account of chemicals use and emissions along the life cycle of a product, sector, or entire economy, to assess potential impacts on ecosystems and human health. The second step (step 2) aims at assessing to which extent actual emission of chemicals harm the ecosystems above their capability to recover (carrying capacity of the system). The latter step might contribute to the wide discussion on planetary boundaries for chemical pollution: the thresholds that should not be surpassed to guarantee a sustainable use of chemicals from an environmental safety perspective. The definition of what the planetary boundaries for chemical pollution are and how the boundaries should be identified is an on-going scientific challenge for ecotoxicology and ecology. In

  20. Great Lakes Environmentalists Push for Zero Chemical Pollution.

    ERIC Educational Resources Information Center

    Heylin, Michael

    1991-01-01

    Described are the efforts of a coalition of several environmental organizations to influence federal legislation regarding water pollution in the Great Lakes region. Statements from regional legislators are included. (CW)

  1. Marine biodegradation: Chemical pollutants. (Latest citations from Oceanic abstracts). Published Search

    SciTech Connect

    Not Available

    1993-03-01

    The bibliography contains citations concerning the biological degradation of marine pollutants. The citations explore the microbial breakdown of petroleum, herbicides, pesticides, polychlorinated biphenyls and other hazardous materials. The chemical details of biotransformation, and the development of microorganisms capable of degrading pollutants are presented. (Contains a minimum of 222 citations and includes a subject term index and title list.)

  2. Low levels of chemical anthropogenic pollution may threaten amphibians by impairing predator recognition.

    PubMed

    Polo-Cavia, Nuria; Burraco, Pablo; Gomez-Mestre, Ivan

    2016-03-01

    Recent studies suggest that direct mortality and physiological effects caused by pollutants are major contributing factors to global amphibian decline. However, even sublethal concentrations of pollutants could be harmful if they combined with other factors to cause high mortality in amphibians. Here we show that sublethal concentrations of pollutants can disrupt the ability of amphibian larvae to recognize predators, hence increasing their risk of predation. This effect is indeed much more important since very low amounts of pollutants are ubiquitous, and environmental efforts are mostly directed towards preventing lethal spills. We analyzed the effects of two common contaminants (humic acid and ammonium nitrate) on the ability of tadpoles of the western spadefoot toad (Pelobates cultripes) to recognize chemical cues from a common predator, nymphs of the dragonfly Anax imperator. We compared the swimming activity of tadpoles in the presence and absence of water-borne chemical cues from dragonflies at different concentrations of humic acid and ammonium nitrate. Tadpoles reduced swimming activity in response to predator cues in the absence of pollutants, whereas they remained unresponsive to these cues when either humic acid or ammonium nitrate was added to the water, even at low concentrations. Moreover, changes in tadpole activity associated with the pollutants themselves were non-significant, indicating no toxic effect. Alteration of the natural chemical environment of aquatic systems by pollutants may be an important contributing cause for declines in amphibian populations, even at sublethal concentrations. PMID:26765086

  3. Chemicals and excess materials disposition during facility deactivation as a means of pollution prevention

    SciTech Connect

    Godfrey, S.D.

    1998-05-28

    This paper presents several innovative and common sense approaches to pollution prevention that have been employed during facility deactivation at the Hanford Site in South Central Washington. It also presents several pollution prevention principles applicable to other projects. Innovative pollution prevention ideas employed at the Hanford site during facility deactivation included: (1) Recycling more than 185,000 gallons of radioactively contaminated nitric acid by sending it to an operating nuclear fuels reprocessing facility in England; (2) Recycling millions of pounds of chemicals and excess materials to other industries for reuse; (3) Evaporating flush water at a low rate and discharging it into the facility exhaust air stream to avoid discharging thousands of gallons of liquid to the soil column; and (4) Decontaminating and disposing of thousands of gallons of radioactively contaminated organic solvent waste to a RCRA licensed, power-producing, commercial incinerator. Common sense pollution prevention ideas that were employed include recycling office furniture, recycling paper from office files, and redeploying tools and miscellaneous process equipment. Additional pollution prevention occurred as the facility liquid and gaseous discharge streams were deactivated. From the facilities deactivation experiences at Hanford and the ensuing efforts to disposition excess chemicals and materials, several key pollution prevention principles should be considered at other projects and facilities, especially during the operational periods of the facility`s mission. These principles include: Institute pollution prevention as a fundamental requirement early in the planning stage of a project or during the operational phase of a facility`s mission; Promote recognition and implementation of pollution prevention initiatives; Instill pollution prevention as a value in all participants in the project or facility work scope; Minimize the amount of chemical products and materials

  4. Solar-Enhanced Advanced Oxidation Processes for Water Treatment: Simultaneous Removal of Pathogens and Chemical Pollutants

    PubMed Central

    Tsydenova, Oyuna; Batoev, Valeriy; Batoeva, Agniya

    2015-01-01

    The review explores the feasibility of simultaneous removal of pathogens and chemical pollutants by solar-enhanced advanced oxidation processes (AOPs). The AOPs are based on in-situ generation of reactive oxygen species (ROS), most notably hydroxyl radicals •OH, that are capable of destroying both pollutant molecules and pathogen cells. The review presents evidence of simultaneous removal of pathogens and chemical pollutants by photocatalytic processes, namely TiO2 photocatalysis and photo-Fenton. Complex water matrices with high loads of pathogens and chemical pollutants negatively affect the efficiency of disinfection and pollutant removal. This is due to competition between chemical substances and pathogens for generated ROS. Other possible negative effects include light screening, competitive photon absorption, adsorption on the catalyst surface (thereby inhibiting its photocatalytic activity), etc. Besides, some matrix components may serve as nutrients for pathogens, thus hindering the disinfection process. Each type of water/wastewater would require a tailor-made approach and the variables that were shown to influence the processes—catalyst/oxidant concentrations, incident radiation flux, and pH—need to be adjusted in order to achieve the required degree of pollutant and pathogen removal. Overall, the solar-enhanced AOPs hold promise as an environmentally-friendly way to substitute or supplement conventional water/wastewater treatment, particularly in areas without access to centralized drinking water or sewage/wastewater treatment facilities. PMID:26287222

  5. AN ADVANCED SYSTEM FOR POLLUTION PREVENTION IN CHEMICAL COMPLEXES

    EPA Science Inventory

    One important accomplishment is that the system will give process engineers interactively and simultaneously use of programs for total cost analysis, life cycle assessment and sustainability metrics to provide direction for the optimal chemical complex analysis pro...

  6. Chemical Pollution from Combustion of Modern Spacecraft Materials

    NASA Technical Reports Server (NTRS)

    Mudgett, Paul D.

    2013-01-01

    Fire is one of the most critical contingencies in spacecraft and any closed environment including submarines. Currently, NASA uses particle based technology to detect fires and hand-held combustion product monitors to track the clean-up and restoration of habitable cabin environment after the fire is extinguished. In the future, chemical detection could augment particle detection to eliminate frequent nuisance false alarms triggered by dust. In the interest of understanding combustion from both particulate and chemical generation, NASA Centers have been collaborating on combustion studies at White Sands Test Facility using modern spacecraft materials as fuels, and both old and new technology to measure the chemical and particulate products of combustion. The tests attempted to study smoldering pyrolysis at relatively low temperatures without ignition to flaming conditions. This paper will summarize the results of two 1-week long tests undertaken in 2012, focusing on the chemical products of combustion. The results confirm the key chemical products are carbon monoxide (CO), hydrogen cyanide (HCN), hydrogen fluoride (HF) and hydrogen chloride (HCl), whose concentrations depend on the particular material and test conditions. For example, modern aerospace wire insulation produces significant concentration of HF, which persists in the test chamber longer than anticipated. These compounds are the analytical targets identified for the development of new tunable diode laser based hand-held monitors, to replace the aging electrochemical sensor based devices currently in use on the International Space Station.

  7. [Research in Mexico on the health impact of environmental chemical pollutants].

    PubMed

    Ortega-Ceseña, J; Carreón-Valencia, T; López-Carrillo, L; Chávez-Ayala, R; Hernández-Avila, M

    1993-01-01

    This paper is intended to offer a qualitative and quantitative diagnosis on publications concerned with human health impact of exposure to environmental chemical pollutants in Mexico. The review of these subjects included scientific papers on studies carried out in Mexico, published both in Mexican and international journals. The articles were analyzed according to the following criteria: chemical pollutants, type of study and institution that conducted it, study population, design, and analysis of data. The article concludes that publications in this field are scarce. Moreover, this review showed that there is little diversity, limited methodology and an unequal distribution of the human and material resources for research. All this indicates a rudimentary level of scientific knowledge in Mexico regarding public health implications of chemical pollutants. PMID:8128296

  8. Large-Eddy Simulation of Chemically Reactive Pollutant Transport from a Point Source in Urban Area

    NASA Astrophysics Data System (ADS)

    Du, Tangzheng; Liu, Chun-Ho

    2013-04-01

    Most air pollutants are chemically reactive so using inert scalar as the tracer in pollutant dispersion modelling would often overlook their impact on urban inhabitants. In this study, large-eddy simulation (LES) is used to examine the plume dispersion of chemically reactive pollutants in a hypothetical atmospheric boundary layer (ABL) in neutral stratification. The irreversible chemistry mechanism of ozone (O3) titration is integrated into the LES model. Nitric oxide (NO) is emitted from an elevated point source in a rectangular spatial domain doped with O3. The LES results are compared well with the wind tunnel results available in literature. Afterwards, the LES model is applied to idealized two-dimensional (2D) street canyons of unity aspect ratio to study the behaviours of chemically reactive plume over idealized urban roughness. The relation among various time scales of reaction/turbulence and dimensionless number are analysed.

  9. Heavy metal pollution in soils from abandoned Taizhou Chemical Industry Zone in Zhejiang province.

    PubMed

    Yu, Binbin; Zhang, Huimin; Chen, Tao; Mou, Yijun; Wu, Zucheng

    2015-01-01

    Heavy metal (HM) pollution in soils from an abandoned Taizhou Chemical Industry Zone (TCIZ) was investigated. By analysing soils, including sediments, collected from the study zone, the main pollutants were quantitatively identified and their spatial distribution patterns were clearly displayed. Eleven types of HM pollutants were obtained and the results indicated a significant correlation in most of the elements of the soil and sediment. A pollution index Pi was employed to classify the degree of contamination and characterize the main pollutant, which was controlled with the evaluation standard value instead of background one. As was characterized to be one of the main pollutants with the mean concentrations at the pollution source, in the surrounding area, and in the sediment of 603, 20.4, and 22.5 mg/kg, respectively. Our study suggested that the contaminated area of TCIZ may necessitate remediation before it can be considered for reuse. Pollution index method could be a useful tool for assessing soils quality to provide comparable criteria. PMID:26510612

  10. Detection of chemical pollutants by passive LWIR hyperspectral imaging

    NASA Astrophysics Data System (ADS)

    Lavoie, Hugo; Thériault, Jean-Marc; Bouffard, François; Puckrin, Eldon; Dubé, Denis

    2012-09-01

    Toxic industrial chemicals (TICs) represent a major threat to public health and security. Their detection constitutes a real challenge to security and first responder's communities. One promising detection method is based on the passive standoff identification of chemical vapors emanating from the laboratory under surveillance. To investigate this method, the Department of National Defense and Public Safety Canada have mandated Defense Research and Development Canada (DRDC) - Valcartier to develop and test passive Long Wave Infrared (LWIR) hyperspectral imaging (HSI) sensors for standoff detection. The initial effort was focused to address the standoff detection and identification of toxic industrial chemicals (TICs) and precursors. Sensors such as the Multi-option Differential Detection and Imaging Fourier Spectrometer (MoDDIFS) and the Improved Compact ATmospheric Sounding Interferometer (iCATSI) were developed for this application. This paper describes the sensor developments and presents initial results of standoff detection and identification of TICs and precursors. The standoff sensors are based on the differential Fourier-transform infrared (FTIR) radiometric technology and are able to detect, spectrally resolve and identify small leak plumes at ranges in excess of 1 km. Results from a series of trials in asymmetric threat type scenarios will be presented. These results will serve to establish the potential of the method for standoff detection of TICs precursors and surrogates.

  11. Pollution

    ERIC Educational Resources Information Center

    Rowbotham, N.

    1973-01-01

    Presents the material given in one class period in a course on Environmental Studies at Chesterfield School, England. The topics covered include air pollution, water pollution, fertilizers, and insecticides. (JR)

  12. 40 CFR Table 1 to Subpart Vvvvvv... - Hazardous Air Pollutants Used To Determine Applicability of Chemical Manufacturing Operations

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 14 2010-07-01 2010-07-01 false Hazardous Air Pollutants Used To... EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Chemical Manufacturing Area Sources Pt. 63, Subpt. VVVVVV,...

  13. POLLUTION PREVENTION IN THE DESIGN OF CHEMICAL PROCESSES USING HIERARCHICAL DESIGN AND SIMULATION

    EPA Science Inventory

    The design of chemical processes is normally an interactive process of synthesis and analysis. When one also desires or needs to limit the amount of pollution generated by the process the difficulty of the task can increase substantially. In this work, we show how combining hier...

  14. EFFECT OF WATER POLLUTANTS AND OTHER CHEMICALS UPON THE ACTIVITY OF LIPASE 'IN VITRO'

    EPA Science Inventory

    Lipase preparations were treated in vitro with 100 chemicals of various classes, many of which are environmental pollutants, to determine their effect upon enzyme activity. The greatest inhibition was caused by mercuric ion and certain heavy metal cations; almost as inhibiting we...

  15. In situ combined chemical and biological assessment of estrogenic pollution in a water recycling system.

    PubMed

    Chi, Yulang; Huang, Qiansheng; Zhang, Huanteng; Chen, Yajie; Dong, Sijun

    2016-05-01

    Estrogenic pollution and its control in aquatic systems have drawn substantial attention around the world. The chemical and biological assessment approaches currently utilized in the laboratory or field cannot give an integrated assessment of the pollution when used separately. In this study, in situ chemical and biological methods were combined to detect pollution in a water recycling system. Data for the water quality index (WQI) demonstrated that the water treatment resulted in the decline of pollution from upstream to downstream. Wild male Nile tilapia, Oreochromis niloticus, was sampled in June and September. The concentrations of four common endocrine disrupting chemicals (EDCs) were determined in the tilapia liver by chromatographic analysis methods. The level of 17β-estradiol (E2) declined from upstream to downstream in both months. In contrast, the levels of bisphenol A (BPA), di-(2-ethylhcxyl) phthalate (DEHP), and perfluorooctane sulfonate (PFOS) did not display this declining tendency. The highest relative expression of vitellogenin 1 (VTG1) was observed in tilapia from upstream, then the level significantly decreased along the water system. The relative expression levels of CYP1A1 in the water system were also significantly higher than that of the control. However, no declining trend could be observed along the water system. The change of VTG1 expression corresponded well with that of E2 levels in the tilapia liver. Overall, our study assessed the pollution by endocrine disruptors using chemical and biological data with good correspondence. This study also demonstrated the effectiveness of the water recycling system in eliminating estrogen pollution in municipal sewage. PMID:27155427

  16. Toxicity testing of organic chemicals in groundwater polluted with landfill leachate

    SciTech Connect

    Baun, A.; Kloeft, L.; Bjerg, P.L.; Nyholm, N.

    1999-09-01

    A method for assessment of toxicity of nonvolatile organic chemicals contaminants in groundwater polluted with landfill leachate has been evaluated. The biotests utilized were composed of an algal growth inhibition test (Selenastrum capricornutum), a daphnia immobilization test (Daphnia magna), and a bacterial genotoxicity test (umuC, Salmonella typhimurium). The feasibility of the selected biotests was investigated for a series of groundwater samples collected along pollution gradients downstreams of two landfills in Jutland, Denmark. Two different approaches were used, direct toxicity testing of whole groundwater samples, and toxicity testing of concentrates obtained by solid-phase extraction. Direct testing of whole groundwater samples produced toxic responses, but the complex sample matrix masked the toxicity of the organic chemical contaminants of interest. Solid-phase extraction was used successfully as an on-site method that eliminated ion toxicity and produced biotest responses that reflected the toxicity of the nonvolatile organic chemical contaminants in the groundwater.

  17. Association of allergic asthma emergency room visits with the main biological and chemical air pollutants.

    PubMed

    Makra, László; Matyasovszky, István; Bálint, Beatrix

    2012-08-15

    Joint effect of biological (pollen) and chemical air pollutants on asthma emergency room (ER) visits was analyzed for Szeged region of Southern Hungary. Our database of a nine-year period (1999-2007) includes daily number of asthma emergency room (ER) visits, and daily mean concentrations of CO, PM(10), NO, NO(2), O(3) and SO(2), furthermore two pollen variables (Ambrosia and total pollen excluding Ambrosia), as well. The analysis was performed for ER visits of asthma bronchiale using two age groups (adults and the elderly) of males and females for three seasons. Factor analysis was performed in order to clarify the relative importance of the pollutant variables affecting asthma ER visits. Asthma ER visits denote notably stronger associations with the pollutants in adult male than in adult female patients both for the pollen season of Ambrosia and the pollen-free season. Furthermore, adults are substantially more sensitive to severe asthma attack than the elderly for the season of total pollen excluding Ambrosia pollen. The joint effect of the chemical and pollen variables is the highest for the asthma ER cases in the pollen season of Ambrosia, basically due to the extra impact of the total pollen excluding Ambrosia pollen and partly due to Ambrosia pollen. A nonparametric regression technique was applied to discriminate between events of ER visit-no ER visit using pollen and chemical pollutants as explaining variables. Based on multiple correlations, the strongest relationships between ER visits and pollutants are observed during the pollen-free season. The elderly group with asthma bronchiale is characterized by weaker relationships between ER visits and pollutants compared to adults. Ratio of the number of correct decisions on the events of ER visit-no ER visit is lowest for the season of total pollen excluding Ambrosia pollen. Otherwise, similar conclusions hold as those received by multiple correlations. PMID:22750174

  18. Bringing the Polluters Back In: Environmental Inequality and the Organization of Chemical Production

    PubMed Central

    Grant, Don; Trautner, Mary Nell; Downey, Liam; Thiebaud, Lisa

    2011-01-01

    Environmental justice scholars have suggested that because chemical plants and other hazardous facilities emit more pollutants where they face the least resistance, disadvantaged communities face a special health risk. In trying to determine whether race or income has the bigger impact on a neighborhood’s exposure to pollution, however, scholars tend to overlook the facilities themselves and the effect of their characteristics on emissions. In particular, how do the characteristics of facilities and their surrounding communities jointly shape pollution outcomes? We propose a new line of environmental justice research that focuses on facilities and how their features combine with communities’ features to create dangerous emissions. Using novel fuzzy-set analysis techniques and the EPA’s newly developed Risk-Screening Environmental Indicators, we test the influence of facility and community factors on chemical plants’ health-threatening emissions. Contrary to the idea that community characteristics have singular, linear effects, findings show that facility and community factors combine in a variety of ways to produce risky emissions. We speculate that as chemical firms experiment with different ways of producing goods and externalizing pollution costs, new “recipes of risk” are likely to emerge. The question, then, will no longer be whether race or income matters most, but in which of these recipes do they matter and how. PMID:21921966

  19. Comparing wastewater chemicals, indicator bacteria concentrations, and bacterial pathogen genes as fecal pollution indicators

    USGS Publications Warehouse

    Haack, S.K.; Duris, J.W.; Fogarty, L.R.; Kolpin, D.W.; Focazio, M.J.; Furlong, E.T.; Meyer, M.T.

    2009-01-01

    The objective of this study was to compare fecal indicator bacteria (FIB) (fecal coliforms, Escherichia coli [EC], and enterococci [ENT]) concentrations with a wide array of typical organic wastewater chemicals and selected bacterial genes as indicators of fecal pollution in water samples collected at or near 18 surface water drinking water intakes. Genes tested included esp (indicating human-pathogenic ENT) and nine genes associated with various animal sources of shiga-toxin-producing EC (STEC). Fecal pollution was indicated by genes and/or chemicals for 14 of the 18 tested samples, with little relation to FIB standards. Of 13 samples with <50 EC 100 mL-1, human pharmaceuticals or chemical indicators of wastewater treatment plant effluent occurred in six, veterinary antibiotics were detected in three, and stx1 or stx2 genes (indicating varying animal sources of STEC) were detected in eight. Only the EC eaeA gene was positively correlated with FIB concentrations. Human-source fecal pollution was indicated by the esp gene and the human pharmaceutical carbamazepine in one of the nine samples that met all FIB recreational water quality standards. Escherichia coli rfbO157 and stx2c genes, which are typically associated with cattle sources and are of potential human health significance, were detected in one sample in the absence of tested chemicals. Chemical and gene-based indicators of fecal contamination may be present even when FIB standards are met, and some may, unlike FIB, indicate potential sources. Application of multiple water quality indicators with variable environmental persistence and fate may yield greater confidence in fecal pollution assessment and may inform remediation decisions. Copyright ?? 2009 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

  20. Chemical Pollutants Sorbed to Ingested Microbeads from Personal Care Products Accumulate in Fish.

    PubMed

    Wardrop, Peter; Shimeta, Jeff; Nugegoda, Dayanthi; Morrison, Paul D; Miranda, Ana; Tang, Min; Clarke, Bradley O

    2016-04-01

    The prevalence of microplastics (<5 mm) in natural environments has become a widely recognized global problem. Microplastics have been shown to sorb chemical pollutants from their surrounding environment, thus raising concern as to their role in the movement of these pollutants through the food chain. This experiment investigated whether organic pollutants sorbed to microbeads (MBs) from personal care products were assimilated by fish following particle ingestion. Rainbow fish (Melanotaenia fluviatilis) were exposed to MBs with sorbed polybrominated diphenyl ethers (PBDEs; BDE-28, -47, -100, -99, -153, -154, -183, 200 ng g(-1); BDE-209, 2000 ng g(-1)) and sampled at 0, 21, 42, and 63 days along with two control treatments (food only and food + clean MBs). Exposed fish had significantly higher Σ8PBDE concentrations than both control treatments after just 21 days, and continued exposure resulted in increased accumulation of the pollutants over the experiment (ca. 115 pg g(-1) ww d(-1)). Lower brominated congeners showed the highest assimilation whereas higher brominated congeners did not appear to transfer, indicating they may be too strongly sorbed to the plastic or unable to be assimilated by the fish due to large molecular size or other factors. Seemingly against this trend, however, BDE-99 did not appear to bioaccumulate in the fish, which may be due to partitioning from the MBs or it being metabolized in vivo. This work provides evidence that MBs from personal care products are capable of transferring sorbed pollutants to fish that ingest them. PMID:26963589

  1. Biomarker response in the earthworm Lumbricus terrestris exposed to chemical pollutants.

    PubMed

    Calisi, A; Lionetto, M G; Schettino, T

    2011-09-15

    Earthworms are important organisms for the soil ecosystem. They are sensitive to toxic chemicals and represent useful bioindicator organisms for soil biomonitoring. Recently the use of biomarkers in earthworms has been increasingly investigated for soil monitoring and assessment purpose. The aim of the preset paper was to analyze the pollutant-induced response of a suite of cellular and biochemical biomarkers in the earthworm Lumbricus terrestris exposed to copper sulphate or methiocarb in OECD soil at the maximal concentrations recommended in agriculture. These responses were compared to lifecycle parameters such as survival, growth and reproduction. Granulocyte morphometric alteration, lysosomal membrane stability, metallothionein concentration, and acetylcholinesterase activity were considered. In either copper sulphate or methiocarb exposure conditions the mean percentage variation of the pollutant-induced molecular and cellular biomarkers was consistent with the whole organism end-point responses. In particular pollutant-induced granulocyte enlargement, detected in either copper sulphate or methiocarb exposed organisms, showed to be a potential general biomarker that may be directly linked to organism health. Compared to the other biological responses to pollutants, it showed high sensitivity to pollutant exposure suggesting its possible applications as a sensitive, simple, and quick general biomarker for monitoring and assessment applications. PMID:21783228

  2. [Characteristic of toxic risks of air pollution by chemical admixtures aboard the piloted orbital stations].

    PubMed

    Mukhamedieva, L N; Bogomolov, V V

    2009-01-01

    Trends in the chemical composition of air revealed by the sanitary-chemical and toxicological investigations in multifactorial ground-based tests and long-term space flights aboard the Salyut- 6, 7, Mir and the International space station have been used to deduce the chemical characteristic and to substantiate methods to and criteria for evaluation of toxic risks to space crews from air chemical pollution. Of particular concern were the toxic risks and crew protection during the first ingress to modules on the stage of station assembly in orbit, in the course of long-term missions, and in the event of acute exposure in off-nominal and emergency conditions. PMID:19711857

  3. Investigation of chemical properties and transport phenomena associated with pollutants in the atmospheric boundary layer

    NASA Astrophysics Data System (ADS)

    Holmes, Heather A.

    Under the Clean Air Act, the U.S. Environmental Protection Agency is required to determine which air pollutants are harmful to human health, then regulate, monitor and establish criteria levels for these pollutants. To accomplish this and for scientific advancement, integration of knowledge from several disciplines is required including: engineering, atmospheric science, chemistry and public health. Recently, a shift has been made to establish interdisciplinary research groups to better understand the atmospheric processes that govern the transport of pollutants and chemical reactions of species in the atmospheric boundary layer (ABL). The primary reason for interdisciplinary collaboration is the need for atmospheric processes to be treated as a coupled system, and to design experiments that measure meteorological, chemical and physical variables simultaneously so forecasting models can be improved (i.e., meteorological and chemical process models). This dissertation focuses on integrating research disciplines to provide a more complete framework to study pollutants in the ABL. For example, chemical characterization of particulate matter (PM) and the physical processes governing PM distribution and mixing are combined to provide more comprehensive data for source apportionment. Data from three field experiments were utilized to study turbulence, meteorological and chemical parameters in the ABL. Two air quality field studies were conducted on the U.S./Mexico border. The first was located in Yuma, AZ to investigate the spatial and temporal variability of PM in an urban environment and relate chemical properties of ambient aerosols to physical findings. The second border air quality study was conducted in Nogales, Sonora, Mexico to investigate the relationship between indoor and outdoor air quality in order to better correlate cooking fuel types and home activities to elevated indoor PM concentrations. The final study was executed in southern Idaho and focused on

  4. Chemical exposure-response relationship between air pollutants and reactive oxygen species in the human respiratory tract.

    PubMed

    Lakey, Pascale S J; Berkemeier, Thomas; Tong, Haijie; Arangio, Andrea M; Lucas, Kurt; Pöschl, Ulrich; Shiraiwa, Manabu

    2016-01-01

    Air pollution can cause oxidative stress and adverse health effects such as asthma and other respiratory diseases, but the underlying chemical processes are not well characterized. Here we present chemical exposure-response relations between ambient concentrations of air pollutants and the production rates and concentrations of reactive oxygen species (ROS) in the epithelial lining fluid (ELF) of the human respiratory tract. In highly polluted environments, fine particulate matter (PM2.5) containing redox-active transition metals, quinones, and secondary organic aerosols can increase ROS concentrations in the ELF to levels characteristic for respiratory diseases. Ambient ozone readily saturates the ELF and can enhance oxidative stress by depleting antioxidants and surfactants. Chemical exposure-response relations provide a quantitative basis for assessing the relative importance of specific air pollutants in different regions of the world, showing that aerosol-induced epithelial ROS levels in polluted megacity air can be several orders of magnitude higher than in pristine rainforest air. PMID:27605301

  5. Chemical exposure-response relationship between air pollutants and reactive oxygen species in the human respiratory tract

    PubMed Central

    Lakey, Pascale S. J.; Berkemeier, Thomas; Tong, Haijie; Arangio, Andrea M.; Lucas, Kurt; Pöschl, Ulrich; Shiraiwa, Manabu

    2016-01-01

    Air pollution can cause oxidative stress and adverse health effects such as asthma and other respiratory diseases, but the underlying chemical processes are not well characterized. Here we present chemical exposure-response relations between ambient concentrations of air pollutants and the production rates and concentrations of reactive oxygen species (ROS) in the epithelial lining fluid (ELF) of the human respiratory tract. In highly polluted environments, fine particulate matter (PM2.5) containing redox-active transition metals, quinones, and secondary organic aerosols can increase ROS concentrations in the ELF to levels characteristic for respiratory diseases. Ambient ozone readily saturates the ELF and can enhance oxidative stress by depleting antioxidants and surfactants. Chemical exposure-response relations provide a quantitative basis for assessing the relative importance of specific air pollutants in different regions of the world, showing that aerosol-induced epithelial ROS levels in polluted megacity air can be several orders of magnitude higher than in pristine rainforest air. PMID:27605301

  6. Chemical composition of lake sediments along a pollution gradient in a Subarctic watercourse.

    PubMed

    Dauvalter, Vladimir; Kashulin, Nikolay; Sandimirov, Sergey; Terentjev, Petr; Denisov, Dmitry; Amundsen, Per-Arne

    2011-01-01

    Sediment cores were collected from seven lakes in the Subarctic Pasvik watercourse, polluted by sewage waters and air emissions from the Pechenganickel Metallurgical Company, in order to study chemical composition and estimate the intensity of pollution by taking into account background concentration of elements and the vertical and spatial distribution of their contents in cores and surficial layers of sediments. Sediment samples were analysed by atomic-absorption spectrophotometry for 18 elements (Ni, Cu, Co, Zn, Cd, Pb, Hg, As, Cr, Sr, Mn, Fe, Ca, Mg, Na, K, Al, P). Maximum concentrations of all investigated heavy metals (Ni, Cu, Co, Zn, Cd, Pb, Hg, As) were found in the surficial sediment layers of Lake Kuetsjarvi situated directly below the metallurgic smelters. Decreased contents of heavy metals were observed in surficial sediment layers further downstream in the Pasvik watercourse, although pollution remained rather high. Considerable increase in the contents of the heavy metals emitted into the atmosphere in significant amounts by the Pechenganickel Company (Ni, Cu, Co, Zn), was not observed in surficial sediment layers of lakes upstream in the watercourse polluted only by air contamination and household sewage, but substantial increase of the concentrations of chalcophile elements (Pb, Cd, Hg, As) was revealed. The increase in P contents towards the sediment surface in some lakes may suggest a development of eutrophication processes. Our studies reveal that the metallurgic processing of the Pechenganickel Company has resulted in comprehensive heavy metal pollution and contaminations of lakes sediments in the Inari-Pasvik watercourse. The pollution impact on the sediments is most severe in Lake Kuetsjarvi in the vicinity of the smelters, intermediate in lake localities in the main watercourse downstream the metallurgic enterprises and least in lake localities in the upstream part of the watercourse. PMID:21847792

  7. A multivariate/chemical mass balance model for air pollution in China: A hybrid methodology

    SciTech Connect

    Zelenka, M.P.

    1992-01-01

    This research explores the possibility of using a two step method of identifying and quantifying air pollution emissions in an urban environment. The procedure uses a mathematical model called Target Transformation Factor Analysis (TTFA) to estimate source profiles using ambient trace element air concentration data. A source profile is analogous to a fingerprint since it is unique to each source of air pollution. It is important to use source profiles that are measured or estimated for the specific location under study. The profiles estimated by TTFA are then employed in a Chemical Mass Balance (CMB) source apportionment analysis for the airshed. Other known sources are estimated using source signatures from the literature. Applying the TTFA and CMB models in this fashion is called receptor modeling. Generically, a receptor model is the combination of measured air pollution concentration data with a numerical technique which apportions the measured air pollution among distinct source types. The results show that TTFA can be used to provide quantitative estimates of air pollution source profiles for an urban center in China. The number of profiles for unique source types was limited for this data set since emissions from certain types of sources co-varied during each sampling day. Consequently, the CMB analyses that applied the TTFA source profiles needed to be supplemented with standard US EPA source profiles. The application of TTFA for estimating source profiles from ambient data and the subsequent use of those profiles in CMB analyses with source profiles obtained from the EPA's source library can improve the statistical quality of the source apportionment analysis. TTFA can identify source categories of airborne pollution for specific cities, as well as give quantitative data on the composition of the emissions from those source types.

  8. Integrated assessment of oil pollution using biological monitoring and chemical fingerprinting.

    PubMed

    Lewis, Ceri; Guitart, Carlos; Pook, Chris; Scarlett, Alan; Readman, James W; Galloway, Tamara S

    2010-06-01

    A full assessment of the impact of oil and chemical spills at sea requires the identification of both the polluting chemicals and the biological effects they cause. Here, a combination of chemical fingerprinting of surface oils, tissue residue analysis, and biological effects measures was used to explore the relationship between spilled oil and biological impact following the grounding of the MSC Napoli container ship in Lyme Bay, England in January 2007. Initially, oil contamination remained restricted to a surface slick in the vicinity of the wreck, and there was no chemical evidence to link biological impairment of animals (the common limpet, Patella vulgata) on the shore adjacent to the oil spill. Secondary oil contamination associated with salvage activities in July 2007 was also assessed. Chemical analyses of aliphatic hydrocarbons and terpanes in shell swabs taken from limpet shells provided an unequivocal match with the fuel oil carried by the ship. Corresponding chemical analysis of limpet tissues revealed increased concentrations of polycyclic aromatic hydrocarbons (PAHs) dominated by phenanthrene and C1 to C3 phenanthrenes with smaller contributions from heavier molecular weight PAHs. Concurrent ecotoxicological tests indicated impairment of cellular viability (p < 0.001), reduced immune function (p < 0.001), and damage to DNA (Comet assay, p < 0.001) in these animals, whereas antioxidant defenses were elevated relative to un-oiled animals. These results illustrate the value of combining biological monitoring with chemical fingerprinting for the rapid identification of spilled oils and their sublethal impacts on biota in situ. PMID:20821580

  9. Evaluating the performance of low cost chemical sensors for air pollution research.

    PubMed

    Lewis, Alastair C; Lee, James D; Edwards, Peter M; Shaw, Marvin D; Evans, Mat J; Moller, Sarah J; Smith, Katie R; Buckley, Jack W; Ellis, Matthew; Gillot, Stefan R; White, Andrew

    2016-07-18

    Low cost pollution sensors have been widely publicized, in principle offering increased information on the distribution of air pollution and a democratization of air quality measurements to amateur users. We report a laboratory study of commonly-used electrochemical sensors and quantify a number of cross-interferences with other atmospheric chemicals, some of which become significant at typical suburban air pollution concentrations. We highlight that artefact signals from co-sampled pollutants such as CO2 can be greater than the electrochemical sensor signal generated by the measurand. We subsequently tested in ambient air, over a period of three weeks, twenty identical commercial sensor packages alongside standard measurements and report on the degree of agreement between references and sensors. We then explore potential experimental approaches to improve sensor performance, enhancing outputs from qualitative to quantitative, focusing on low cost VOC photoionization sensors. Careful signal handling, for example, was seen to improve limits of detection by one order of magnitude. The quantity, magnitude and complexity of analytical interferences that must be characterised to convert a signal into a quantitative observation, with known uncertainties, make standard individual parameter regression inappropriate. We show that one potential solution to this problem is the application of supervised machine learning approaches such as boosted regression trees and Gaussian processes emulation. PMID:27104223

  10. Chemical composition and sources of particle pollution in affluent and poor neighborhoods of Accra, Ghana

    NASA Astrophysics Data System (ADS)

    Zhou, Zheng; Dionisio, Kathie L.; Verissimo, Thiago G.; Kerr, Americo S.; Coull, Brent; Arku, Raphael E.; Koutrakis, Petros; Spengler, John D.; Hughes, Allison F.; Vallarino, Jose; Agyei-Mensah, Samuel; Ezzati, Majid

    2013-12-01

    The highest levels of air pollution in the world now occur in developing country cities, where air pollution sources differ from high-income countries. We analyzed particulate matter (PM) chemical composition and estimated the contributions of various sources to particle pollution in poor and affluent neighborhoods of Accra, Ghana. Elements from earth’s crust were most abundant during the seasonal Harmattan period between late December and late January when Saharan dust is carried to coastal West Africa. During Harmattan, crustal particles accounted for 55 μg m-3 (37%) of fine particle (PM2.5) mass and 128 μg m-3 (42%) of PM10 mass. Outside Harmattan, biomass combustion, which was associated with higher black carbon, potassium, and sulfur, accounted for between 10.6 and 21.3 μg m-3 of fine particle mass in different neighborhoods, with its contribution largest in the poorest neighborhood. Other sources were sea salt, vehicle emissions, tire and brake wear, road dust, and solid waste burning. Reducing air pollution in African cities requires policies related to energy, transportation and urban planning, and forestry and agriculture, with explicit attention to impacts of each strategy in poor communities. Such cross-sectoral integration requires emphasis on urban environment and urban poverty in the post-2015 Development Agenda.

  11. Prediction of Toxic Pollution Resulting From Warfare Chemical Munitions Dumped In The Sea

    NASA Astrophysics Data System (ADS)

    Korotenko, K. A.

    A 3-D high-resolution Hydrodynamic/Transport model was developed to predict chemical pollution in marine environment with a special reference to warfare chem- icals dumped in the Baltic Sea. The Flow module was developed on the basis of the Princeton Ocean Model (POM). The grid step is chosen at 1/15Deg and 1/30/Deg along x- and y-axes (that is, about 4.0 km and 3.7 km, respectively). The model grid covers the Baltic from 9.3 to 24.6E and from 53.0 to 60.2N. The Transport module of the model takes the predetermined velocity field and uses the random walk technique to predict the motion of individual particles, the sum of which constitutes a consid- ered chemical agent. Several different approaches for modeling are used for different kind of chemical agents. Basic processes affecting the chemicals to be modeled are hydrolysis, solubility, and microbiological destruction. All available toxicity data re- garding the chemical warfare agents of primary concern and the expected degradation products in the Baltic environment were gathered and summarized. This information was used to compare the toxicities of the different agents and their degradation prod- ucts and to decide which chemicals may represent a toxic threat to the environment. The model was adapted to be used for chemical agents with various characteristics and behavior (as Sarin, Lewsite, Musturd, etc.) in seawaters. Special algorithms are developed to describe nonlinear reactions producing toxic and nontoxic products in result of the warfare agent destruction. Sources of chemical pollution in the sea are considered as steady state (chronic) point and/or distributed releases because princi- pally different two methods were used in dumping CW: 1) concentrated dumping of containers, shells, and bombs together with ships; 2) dispersed dumping of individual containers, shells and aircraft bombs from moving vessels. The model was run with four most recurrent climatic wind fields for the Bornholm and Gotland

  12. TOXICITY AND METABOLISM STUDIES WITH EPA (ENVIRONMENTAL PROTECTION AGENCY) PRIORITY POLLUTANTS AND RELATED CHEMICALS IN FRESHWATER ORGANISMS

    EPA Science Inventory

    Twenty-two chemicals from the EPA priority pollutant list were studied for their acute and/or chronic toxicity to selected freshwater organisms. Freshwater species tested included the fathead minnow (Pimephales promelas), rainbow trout (Salmo gairdneri), bluegill sunfish (Lepomis...

  13. Emergency Response System for Pollution Accidents in Chemical Industrial Parks, China.

    PubMed

    Duan, Weili; He, Bin

    2015-07-01

    In addition to property damage and loss of lives, environment pollution, such as water pollution and air pollution caused by accidents in chemical industrial parks (CIPs) is a significant issue in China. An emergency response system (ERS) was therefore planned to properly and proactively cope with safety incidents including fire and explosions occurring in the CIPs in this study. Using a scenario analysis, the stages of emergency response were divided into three levels, after introducing the domino effect, and fundamental requirements of ERS design were confirmed. The framework of ERS was composed mainly of a monitoring system, an emergency command center, an action system, and a supporting system. On this basis, six main emergency rescue steps containing alarm receipt, emergency evaluation, launched corresponding emergency plans, emergency rescue actions, emergency recovery, and result evaluation and feedback were determined. Finally, an example from the XiaoHu Chemical Industrial Park (XHCIP) was presented to check on the integrality, reliability, and maneuverability of the ERS, and the result of the first emergency drill with this ERS indicated that the developed ERS can reduce delays, improve usage efficiency of resources, and raise emergency rescue efficiency. PMID:26184260

  14. Emergency Response System for Pollution Accidents in Chemical Industrial Parks, China

    PubMed Central

    Duan, Weili; He, Bin

    2015-01-01

    In addition to property damage and loss of lives, environment pollution, such as water pollution and air pollution caused by accidents in chemical industrial parks (CIPs) is a significant issue in China. An emergency response system (ERS) was therefore planned to properly and proactively cope with safety incidents including fire and explosions occurring in the CIPs in this study. Using a scenario analysis, the stages of emergency response were divided into three levels, after introducing the domino effect, and fundamental requirements of ERS design were confirmed. The framework of ERS was composed mainly of a monitoring system, an emergency command center, an action system, and a supporting system. On this basis, six main emergency rescue steps containing alarm receipt, emergency evaluation, launched corresponding emergency plans, emergency rescue actions, emergency recovery, and result evaluation and feedback were determined. Finally, an example from the XiaoHu Chemical Industrial Park (XHCIP) was presented to check on the integrality, reliability, and maneuverability of the ERS, and the result of the first emergency drill with this ERS indicated that the developed ERS can reduce delays, improve usage efficiency of resources, and raise emergency rescue efficiency. PMID:26184260

  15. Urban Pollution in the Nocturnal Boundary Layer: Chemical Processing and Vertical Transport

    NASA Astrophysics Data System (ADS)

    Stutz, J.; Flynn, C. J.; Rappenglück, B.; Lefer, B.; Brune, W. H.; Dibb, J. E.; Griffin, R. J.

    2007-12-01

    For many decades research on urban pollution and its chemistry has concentrated on processes occurring during the day. In recent years, however, it has become clear that transport and chemical processing at night can also play an important role for urban air quality. Various chemical pathways are known to remove gaseous pollutants, such as nitrogen oxides, ozone and hydrocarbons, as well as influence aerosol composition at night. The quantification of these processes is difficult due to the influence of vertical stability, which leads to a much slower vertical transport of trace gases emitted at the surface at night than during the day. As a consequence, chemistry at night is often very altitude dependent, making investigations in the NBL challenging. In recent years a number of field experiments have been performed where the nocturnal meteorology and the vertical distribution of the dominant trace gases at night have been observed. Here we will review the lessons learned in past studies and present results from a recent study in Houston, TX, which gives new insights into the meteorological and chemical processes at night. The TexAQS II Radical Measurement Project (TRAMP) was performed in August and September 2006, on the University of Houston campus. We will present data from a number of measurements, including a long-path Differential Optical Absorption Spectrometer, in situ instrumentation for gas phase compounds (O3, NO, NO2, CO, VOC), HOx radicals, aerosol size and composition, various meteorological and radiation parameters, and an aerosol LIDAR. The field observations will be compared to 1D model calculations which show the dominant chemical processes and allow the identification of gaps in our understanding of the polluted nocturnal urban boundary layer.

  16. An novel identification method of the environmental risk sources for surface water pollution accidents in chemical industrial parks.

    PubMed

    Peng, Jianfeng; Song, Yonghui; Yuan, Peng; Xiao, Shuhu; Han, Lu

    2013-07-01

    The chemical industry is a major source of various pollution accidents. Improving the management level of risk sources for pollution accidents has become an urgent demand for most industrialized countries. In pollution accidents, the released chemicals harm the receptors to some extent depending on their sensitivity or susceptibility. Therefore, identifying the potential risk sources from such a large number of chemical enterprises has become pressingly urgent. Based on the simulation of the whole accident process, a novel and expandable identification method for risk sources causing water pollution accidents is presented. The newly developed approach, by analyzing and stimulating the whole process of a pollution accident between sources and receptors, can be applied to identify risk sources, especially on the nationwide scale. Three major types of losses, such as social, economic and ecological losses, were normalized, analyzed and used for overall consequence modeling. A specific case study area, located in a chemical industry park (CIP) along the Yangtze River in Jiangsu Province, China, was selected to test the potential of the identification method. The results showed that there were four risk sources for pollution accidents in this CIP. Aniline leakage in the HS Chemical Plant would lead to the most serious impact on the surrounding water environment. This potential accident would severely damage the ecosystem up to 3.8 km downstream of Yangtze River, and lead to pollution over a distance stretching to 73.7 km downstream. The proposed method is easily extended to the nationwide identification of potential risk sources. PMID:24218858

  17. Air Pollution

    MedlinePlus

    Air pollution is a mixture of solid particles and gases in the air. Car emissions, chemicals from factories, dust, ... a gas, is a major part of air pollution in cities. When ozone forms air pollution, it's ...

  18. Air Pollution

    MedlinePlus

    Air pollution is a mixture of solid particles and gases in the air. Car emissions, chemicals from factories, ... Ozone, a gas, is a major part of air pollution in cities. When ozone forms air pollution, it's ...

  19. Water Pollution

    ERIC Educational Resources Information Center

    Bowen, H. J. M.

    1975-01-01

    Deals with water pollution in the following categories: a global view, self purification, local pollution, difficulties in chemical analysis, and remedies for water pollution. Emphasizes the extent to which man's activities have modified the cycles of certain elements. (GS)

  20. Efficiency of stepwise magnetic-chemical site assessment for fly ash derived heavy metal pollution

    NASA Astrophysics Data System (ADS)

    Cao, Liwan; Appel, Erwin; Rösler, Wolfgang; Magiera, Tadeusz

    2015-11-01

    Previous works revealed a close relationship between magnetic susceptibility (MS) and heavy metal (HM) contents originating from industrial sources. However, despite general statements on the usefulness of magnetic mapping, the benefit of this procedure for geochemistry was not quantified yet. We present a study on fly ash pollution in soil around a coal-burning power plant complex and simulate a stepwise approach of magnetic pre-screening and subsequent targeted sampling for chemical analysis. The aim of this study is not to discuss correlations between MS and HM, but to show that a combined stepwise magnetic-chemical approach is the most efficient way for outlining HM contamination. In order to provide quantitative evidence, we explored map similarities of spatial HM distributions based on magnetochemical data and chemical data only. We determined 3-D triangular planes defined by categorized HM values at the sampling coordinates and calculated the average dihedral angle of the normal vectors as a similarity result. The study shows that the `Targeted' HM map (selection of 30 sites based magnetic pre-screening) has a higher similarity with the `True' Pollution HM map (85 sites) than HM maps resulting from site selections (30 sites) without using magnetic pre-screening information.

  1. Global styrene oligomers monitoring as new chemical contamination from polystyrene plastic marine pollution.

    PubMed

    Kwon, Bum Gun; Koizumi, Koshiro; Chung, Seon-Yong; Kodera, Yoichi; Kim, Jong-Oh; Saido, Katsuhiko

    2015-12-30

    Polystyrene (PS) plastic marine pollution is an environmental concern. However, a reliable and objective assessment of the scope of this problem, which can lead to persistent organic contaminants, has yet to be performed. Here, we show that anthropogenic styrene oligomers (SOs), a possible indicator of PS pollution in the ocean, are found globally at concentrations that are higher than those expected based on the stability of PS. SOs appear to persist to varying degrees in the seawater and sand samples collected from beaches around the world. The most persistent forms are styrene monomer, styrene dimer, and styrene trimer. Sand samples from beaches, which are commonly recreation sites, are particularly polluted with these high SOs concentrations. This finding is of interest from both scientific and public perspectives because SOs may pose potential long-term risks to the environment in combination with other endocrine disrupting chemicals. From SOs monitoring results, this study proposes a flow diagram for SOs leaching from PS cycle. Using this flow diagram, we conclude that SOs are global contaminants in sandy beaches around the world due to their broad spatial distribution. PMID:26218303

  2. Waste processing and pollution in the chemical and petrochemical industries. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect

    Not Available

    1994-01-01

    The bibliography contains citations concerning techniques and equipment used for pollution control in the chemical and petrochemical industries. Topics include emissions investigations, recycling and materials recovery studies, and standards for specific industries. Sources, site hazard evaluations, and the toxicity of specific chemicals are also discussed. (Contains 250 citations and includes a subject term index and title list.)

  3. Waste processing and pollution in the chemical and petrochemical industries. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect

    1995-02-01

    The bibliography contains citations concerning techniques and equipment used for pollution control in the chemical and petrochemical industries. Topics include emissions investigations, recycling and materials recovery studies, and standards for specific industries. Sources, site hazard evaluations, and the toxicity of specific chemicals are also discussed. (Contains 250 citations and includes a subject term index and title list.)

  4. Application of SOS umu-test for the detection of genotoxic volatile chemicals and air pollutants

    SciTech Connect

    Ong, T.M.; Stewart, J.; Wen, Y.F.; Whong, W.Z.

    1987-01-01

    The SOS umu-test has been used for the detection of DNA-damaging agents. In this system the plasmid pSK1002 carrying a fused gene umuC-lacZ was introduced into Salmonella typhimurium TA1535. The SOS function induced by genotoxic agents is detected by a colorimetric measurement of beta-galactosidase activity encoded by the lacZ gene, which is regulated by the Umu operon. This system was used with modifications to study the SOS function inducibility of volatile chemicals (propylene oxide, methyl bromide, and ethylene dibromide) and air pollutants (diesel emission, welding fumes, and cigarette smoke). Tester cells were exposed directly to the test material. The enzyme activity of the treated cells was measured according to the established procedure. Results of the study showed that all chemicals and pollutants tested induced SOS function in a dose-related manner. These results indicate that the SOS umu-test is potentially useful for the in situ detection of genotoxic agents in occupational settings.

  5. Chemical pollutants in field-collected canvasback tissues, eggs, and food materials

    USGS Publications Warehouse

    White, D.H.; Dieter, M.P.; Stendell, R.C.

    1976-01-01

    In 1972 studies began on the levels of environmental pollutants in canvasback tissues, eggs, and food items. The purpose of the studies were to determine if the levels of toxic chemicals found in canvasbacks were of the magnitude to cause problems affecting reproduction and survival. Overall, levels of organochlorine pesticides and PCB's were low in canvasbacks and their eggs. Some individual birds, however, laid eggs with elevated residues of DDE (12.1 ppm) or PCB's (28.6 ppm). There was no significant difference between eggshell thicknesses of 1972-73 and pre-1946 collections. About 12% of the canvasbacks analyzed had elevated levels of blood lead with reduced ALAD enzyme activity. Adult canvasbacks collected from the Chesapeake Bay in 1975 had moderate to high levels of cadmium in their kidneys. Cadmium, in excessive amounts is very toxic and can curtail spermatogenesis in male birds. Although no single toxic chemical found in wild canvasbacks appears to be a major factor in population declines, the cumulative effects of sublethal levels of all the pollutants may render birds susceptible to disease, hunting pressure or predation.

  6. Pollution-Induced Community Tolerance To Diagnose Hazardous Chemicals in Multiple Contaminated Aquatic Systems.

    PubMed

    Rotter, Stefanie; Gunold, Roman; Mothes, Sibylle; Paschke, Albrecht; Brack, Werner; Altenburger, Rolf; Schmitt-Jansen, Mechthild

    2015-08-18

    Aquatic ecosystems are often contaminated with large numbers of chemicals, which cannot be sufficiently addressed by chemical target analyses. Effect-directed analysis (EDA) enables the identification of toxicants in complex contaminated environmental samples. This study suggests pollution-induced community tolerance (PICT) as a confirmation tool for EDA to identify contaminants which actually impact on local communities. The effects of three phytotoxic compounds local periphyton communities, cultivated at a reference (R-site) and a polluted site (P-site), were assessed to confirm the findings of a former EDA study on sediments. The sensitivities of R- and P-communities to prometryn, tributyltin (TBT) and N-phenyl-2-naphthylamine (PNA) were quantified in short-term toxicity tests and exposure concentrations were determined. Prometryn and PNA concentrations were significantly higher at the P-site, whereas TBT concentrations were in the same range at both sites. Periphyton communities differed in biomass, but algal class composition and diatom diversity were similar. Community tolerance of P-communities was significantly enhanced for prometryn, but not for PNA and TBT, confirming site-specific effects on local periphyton for prometryn only. Thus, PICT enables in situ effect confirmation of phytotoxic compounds at the community level and seems to be suitable to support confirmation and enhance ecological realism of EDA. PMID:26196040

  7. Particle size and chemical constituents of ambient particulate pollution associated with cardiovascular mortality in Guangzhou, China.

    PubMed

    Lin, Hualiang; Tao, Jun; Du, Yaodong; Liu, Tao; Qian, Zhengmin; Tian, Linwei; Di, Qian; Rutherford, Shannon; Guo, Lingchuan; Zeng, Weilin; Xiao, Jianpeng; Li, Xing; He, Zhihui; Xu, Yanjun; Ma, Wenjun

    2016-01-01

    Though significant associations between particulate matter (PM) air pollution and cardiovascular diseases have been widely reported, it remains unclear what characteristics, such as particle size and chemical constituents, may be responsible for the effects. A time-series model was applied to examine the cardiovascular effects of particle size (for the period of 2009-2011) and chemical constituents (2007-2010) in Guangzhou, we controlled for potential confounders in the model, such as time trends, day of the week, public holidays, meteorological factors and influenza epidemic. We found significant associations of cardiovascular mortality with PM10, PM2.5 and PM1; the excess risk (ER) was 6.10% (95% CI: 1.76%, 10.64%), 6.11% (95% CI: 1.76%, 10.64%) and 6.48% (95% CI: 2.10%, 11.06%) for per IQR increase in PM10, PM2.5 and PM1 at moving averages for the current day and the previous 3 days (lag03), respectively. We did not find significant effects of PM2.5-10 and PM1-2.5. For PM2.5 constituents, we found that organic carbon, elemental carbon, sulfate, nitrate and ammonium were significantly associated with cardiovascular mortality, the corresponding ER for an IQR concentration increase at lag03 was 1.13% (95% CI: 0.10%, 2.17%), 2.77% (95% CI: 0.72%, 4.86%), 2.21% (95% CI: 1.05%, 3.38%), 1.98% (95% CI: 0.54%, 3.44%), and 3.38% (95% CI: 1.56%, 5.23%), respectively. These results were robust to adjustment of other air pollutants and they remained consistent in various sensitivity analyses by changing model parameters. Our study suggests that PM1 and constituents from combustion and secondary aerosols might be important characteristics of PM pollution associated with cardiovascular mortality in Guangzhou. PMID:26561449

  8. Joint actions of environmental nonionizing electromagnetic fields and chemical pollution in cancer promotion.

    PubMed Central

    Adey, W R

    1990-01-01

    Studies of environmental electromagnetic (EM) field interactions in tissues have contributed to a new understanding of both normal growth and the biology of cancer in cell growth. From cancer research comes a floodtide of new knowledge about the disruption of communication by cancer-promoting chemicals with an onset of unregulated growth. Bioelectromagnetic research reveals clear evidence of joint actions at cell membranes of chemical cancer promoters and environmental electromagnetic fields. The union of these two disciplines has resulted in the first major new approach to tumor formation in 75 years, directing attention to dysfunctions in inward and outward streams of signals at cell membranes, rather than to damage DNA in cell nuclei, and to synergic actions of chemical pollutants and environmental electromagnetic fields. We are witnesses and, in great measure, participants in one of the great revolutions in the history of biology. In little more than a century, we have moved from organs, to tissues, to cells, and finally to the molecules that are the elegant fabric of living tissues. Today, we stand at a new frontier. It may be more difficult to comprehend, but it is far more significant; for it is at the atomic level, rather than the molecular, that physical, rather than chemical, processes appear to shape the flow of signals that are at the essence of living matter. To pursue these problems in the environment and in the laboratory, our needs for further research with appropriate budgets are great.(ABSTRACT TRUNCATED AT 250 WORDS) PMID:2205491

  9. The Numerical Simulation of Coupling Behavior of Soil with Chemical Pollutant Effects

    NASA Astrophysics Data System (ADS)

    Liu, Z. J.; Li, X. K.; Tang, L. Q.

    2010-05-01

    The coupling behavior of clay plays a role in the integrity of clay barriers used in landfills. The clay barriers are subjected to mechanical and thermal effects coupled with hydraulic behavior, also, if the leachates become in contact with the clay liner, chemical effects may lead to some drastic changes in the properties of the clay. A numerical method to simulate the coupling behavior of soil with chemical pollutant effects is presented. Within the framework of Gens-Alonso model describing the constitutive behavior of unsaturated clay presented in reference[1], basing on the work of Wu[2] and Hueckel[3], a constitutive model describing the chemo-thermo-hydro-mechanical(CTHM) coupling behavior of clays in contact with a single organic contaminant is presented. The thermical softening and chemical softening is considered in the presented model. The strain arising in the material due to chemical and thermical effects can be decomposed into two parts: elastic expansion and plastic compaction. The chemical effects are described in terms of the mass concentration of the contaminant. The increases in temperature and contaminant concentration cause decreases of the pre-consolidation pressure and the cohesion. The mechanisms are called thermical softening and chemical softening. The presented coupled CTHM constitutive model has been integrated into the coupled thermo-hydro-mechanical mathematical model including contaminant transport in porous media. To solve the equilibrium equations, the grogram of finite element methods is developed with a stagger algorithm. The mechanisms taking place due to the coupling behaviour of the clay with a single contaminant solute are analysed with the presented numerical method.

  10. [AOX Pollution in Wastewater Treatment Process of Dyeing and Dyestuff Chemical Industries].

    PubMed

    Shen, Yang-yang; Liu, Rui; Xu, Can-can; Shu, Xiao-ming; Xu, Jiang-jun; Lan, Ya-qiong; Chen, Lü-jun

    2015-09-01

    Selecting six large-scale dyeing factories and four large-scale dyestuff chemical factories in the well-developed Yangtze River Delta region, this study aimed to investigate the AOX pollution status in the raw wastewater as well as in the activated sludge treatment system. The components of AOX were characterized by GC-MS. Results showed that AOX concentration was low in wastewater from the six dyeing enterprises, ranging 0. 15-1. 62 mg.L-1 in the raw wastewater and 0. 06-1. 30 mg.L-1 in the biologically treated effluent. All the biologically treated effluent met the emission limits of 8 mg.L-1 in the Discharge Standard of Water Pollutants for Dyeing and Finishing of Textile Industry. Sludge in five factories with AOX was below 621 mg.kg-1, only one factory was with high AOX concentration of 3 280 mg.kg-1. By comparison, AOX concentration greatly varied between the wastewater from dyestuff chemical factories, was 1. 70 mg.L-1 to 78. 72 mg.L-1 in the raw wastewater and was 1. 88 mg.L-1 to 33. 11 mg.L-1 in the biologically treated effluent. AOX concentration in the activated sludge was as high as 960-2,297 mg.kg-1. Chlorobenzenes, chloronitrobenzenes, chloroanilines, chlorine nitroanilines and halophenols were typical TOX components detectable in the dyestuff chemical wastewater. Halophenols and chlorine nitroanilines could be efficiently removed. Single chloroanilines and single chloronitrobenzenes seemed to be easier removable than polychlorinated anilines and polychlorinated nitrobenzenes. Polychlorinated benzenes were also easily removal but the products chlorobenzene was hard to remove. PMID:26717692

  11. Predicting physico-chemical properties of polychlorinated diphenyl ethers (PCDEs): potential persistent organic pollutants (POPs).

    PubMed

    Huang, Jun; Yu, Gang; Yang, Xi; Zhang, Zu-lin

    2004-01-01

    Polychlorinated diphenyl ethers (PCDEs) have received more and more concerns as a category of potential persistent organic pollutants (POPs). Modeling its environmental fate and exposure assessment require a number of fundamental physico-chemical properties. However, the experimental data are currently limited due to the difficulty in analysis caused by the complexity of PCDE congeners. As an alternative, the quantitative structure property relationship (QSPR) approach could be used. In this paper, twelve kinds of molecular connectivity indices (MCIs) of all 209 possible molecular structure patterns of PCDEs were calculated. Based on 106 PCDEs with three observed physico-chemical properties-vapour pressure (P0L), aqueous solubility (Sw) and n-octanol/water (Kow) and their MCIs data, a series of QSPR equations were established using multiple linear regression (MLR) method. As a result, three equations with best performance were selected mainly from the view of high regression coefficient (R) and low standard error(SE). All of them showed significant relationship and high accuracy. With these equations the properties of other 103 patterns of PCDEs without the reported observed values were predicted. Furthermore, three partition properties for PCDE congeners-Henry' s Law constants (H), partition coefficients between gas/water (Kgw) and gas/n-octanol (Kgo) were calculated according to the internal relationship among these six properties. These observed and predicted values, in contrast with the criteria listed in the Stockholm treaty about POPs which has been signed by more than ninety countries in May 2001, illustrated that most of PCDEs congeners are potential persistent organic pollutants. As all descriptors/predictors are derived just from the molecular structure itself and without the import of any empirical parameters, this method is impersonal and promising for the estimation of physico-chemical properties of PCDEs. PMID:15137639

  12. Characteristics of aerosol size distributions and chemical compositions during wintertime pollution episodes in Beijing

    NASA Astrophysics Data System (ADS)

    Liu, Zirui; Hu, Bo; Zhang, Junke; Yu, Yangchun; Wang, Yuesi

    2016-02-01

    To characterize the features of particle pollution, continuous measurements of particle number size distributions and chemical compositions were performed at an urban site in Beijing in January 2013. The particle number and volume concentration from 14 nm to 1000 nm were (37.4 ± 15.3) × 103 cm- 3 and (85.2 ± 65.6) μm3 cm- 3, respectively. N-Ait (Aitken mode) particles dominated the number concentration, whereas N-Acc (accumulation mode) particles dominated the volume concentration. Submicron particles were generally characterized by a high content of organics and SO42 -, and a low level of NO3- and Cl-. Two types of pollution episodes were observed, characterized by the "explosive growth" (EXP) and "sustained growth" (SUS) of PM2.5. Fine particles greater than 100 nm dominated the volume concentration during the ends of these pollution episodes, shifting the maximum of the number size distribution from 60 nm to greater than 100 nm in a few hours (EXP) or a few days (SUS). Secondary transformation is the main reason for the pollution episodes; SO42 -, NO3- and NH4+ (SNA) accounted for approximately 42% (EXP) and greater than 60% (SUS) of the N-Acc particle mass increase. The size distributions of particulate organics and SNA varied on timescales of hours to days, the characteristics of which changed from bimodal to unimodal during the evolution of haze episodes. The accumulation mode (peaking at approximately 500-700 nm) was dominated by organics that appeared to be internally mixed with nitrate or sulfate. The sulfate was most likely formed via heterogeneous reactions, because the SOR was constant under dry conditions (RH < 50%) and began to increase when RH > 50%, suggesting an important contribution from heterogeneous reactions with abundant aerosol water under wet conditions. Finally, the correlations between [NO3-]/[SO42 -] and [NH4+]/[SO42 -] suggest that the homogenous reaction between HNO3 and NH3 dominated the formation of nitrate under conditions of

  13. The impact of chemical pollution on the resilience of soils under multiple stresses: A conceptual framework for future research.

    PubMed

    Schaeffer, Andreas; Amelung, Wulf; Hollert, Henner; Kaestner, Matthias; Kandeler, Ellen; Kruse, Jens; Miltner, Anja; Ottermanns, Richard; Pagel, Holger; Peth, Stephan; Poll, Christian; Rambold, Gerhard; Schloter, Michael; Schulz, Stefanie; Streck, Thilo; Roß-Nickoll, Martina

    2016-10-15

    Soils are faced with man-made chemical stress factors, such as the input of organic or metal-containing pesticides, in combination with non-chemical stressors like soil compaction and natural disturbance like drought. Although multiple stress factors are typically co-occurring in soil ecosystems, research in soil sciences on this aspect is limited and focuses mostly on single structural or functional endpoints. A mechanistic understanding of the reaction of soils to multiple stressors is currently lacking. Based on a review of resilience theory, we introduce a new concept for research on the ability of polluted soil (xenobiotics or other chemical pollutants as one stressor) to resist further natural or anthropogenic stress and to retain its functions and structure. There is strong indication that pollution as a primary stressor will change the system reaction of soil, i.e., its resilience, stability and resistance. It can be expected that pollution affects the physiological adaption of organisms and the functional redundancy of the soil to further stress. We hypothesize that the recovery of organisms and chemical-physical properties after impact of a follow-up stressor is faster in polluted soil than in non-polluted soil, i.e., polluted soil has a higher dynamical stability (dynamical stability=1/recovery time), whereas resilience of the contaminated soil is lower compared to that of not or less contaminated soil. Thus, a polluted soil might be more prone to change into another system regime after occurrence of further stress. We highlight this issue by compiling the literature exemplarily for the effects of Cu contamination and compaction on soil functions and structure. We propose to intensify research on effects of combined stresses involving a multidisciplinary team of experts and provide suggestions for corresponding experiments. Our concept offers thus a framework for system level analysis of soils paving the way to enhance ecological theory. PMID:27372890

  14. Toxicity of organic chemical pollution in groundwater downgradient of a landfill (Grindsted, Denmark)

    SciTech Connect

    Baun, A.; Jensen, S.D.; Bjerg, P.L.; Christensen, T.H.; Nyholm, N.

    2000-05-01

    The aim of the present study was to describe the occurrence and distribution of toxicity related to organic chemical contaminants in the leachate plume downgradient of the Grindsted Landfill (Denmark). A total of 27 groundwater samples were preconcentrated by solid-phase extraction (SPE) using XAD-2 as the resin material. This treatment effectively eliminated sample matrix toxicity caused by inorganic salts and natural organic compounds and produced an aqueous concentrate of the nonvolatile chemical contaminants. The SPE extracts were tested in a battery of standardized short-term aquatic toxicity tests with luminescent bacteria (Vibrio fischeri), algae (Selenastrum capricornutum), and crustaceans (Daphnia magna). Additional genotoxicity tests were made using the umuC test (Salmonella typhimurium). Biotests with algae and luminescent bacteria were the most sensitive tests. On the basis of results with these two bioassays, it was concluded that SPE extracts of groundwater collected close to the landfill were toxic. The toxicity decreased with the distance from the landfill. At distances greater than 80 m from the border of the landfill, the groundwater toxicity was not significantly different from the background toxicity. SPE extracts were not toxic to Daphnia, and no genotoxicity was observed in the umuC test. The overall findings indicate that a battery of biotests applied on preconcentrated groundwater samples can be a useful tool for toxicity characterization and hazard ranking of groundwater polluted with complex chemical mixtures, such as landfill leachates.

  15. Aerosol physical, chemical and optical properties observed in the ambient atmosphere during haze pollution conditions

    NASA Astrophysics Data System (ADS)

    Li, Zhengqiang; Xie, Yisong; Li, Donghui; Li, Kaitao; Zhang, Ying; Li, Li; Lv, Yang; Qie, Lili; Xu, Hua

    Aerosol’s properties in the ambient atmosphere may differ significantly from sampling results due to containing of abundant water content. We performed sun-sky radiometer measurements in Beijing during 2011 and 2012 winter to obtain distribution of spectral and angular sky radiance. The measurements are then used to retrieve aerosol physical, chemical and optical properties, including single scattering albedo, size distribution, complex refractive indices and aerosol component fractions identified as black carbon, brown carbon, mineral dust, ammonium sulfate-like components and water content inside particle matters. We found that during winter haze condition aerosol is dominated by fine particles with center radius of about 0.2 micron. Fine particles contribute about 93% to total aerosol extinction of solar light, and result in serious decrease of atmospheric visibility during haze condition. The percentage of light absorption of haze aerosol can up to about 10% among its total extinction, much higher than that of unpolluted conditions, that causes significant radiative cooling effects suppressing atmospheric convection and dispersion of pollutants. Moreover, the average water content occupies about one third of the ambient aerosol in volume which suggests the important effect of ambient humidity in the formation of haze pollution.

  16. Origins of chemical pollution derived from Mid-Atlantic aircraft profiles using a clustering technique

    NASA Astrophysics Data System (ADS)

    Hains, Jennifer C.; Taubman, Brett F.; Thompson, Anne M.; Stehr, Jeffrey W.; Marufu, Lackson T.; Doddridge, Bruce G.; Dickerson, Russell R.

    Upwind sources of NO x and SO 2 play a crucial role in the amount of O 3 and aerosols in the lower troposphere in the Mid-Atlantic US. This paper describes a novel method of clustering trace gas and aerosol profiles allowing for the quantification of the relationship between point sources and pollution levels. This improves our understanding of pollution origins and has the potential for prediction of episodes of poor air quality. A hierarchical clustering method was used to classify distinct chemical and meteorological events from over 200 aircraft vertical profiles in the lower troposphere. Profile measurements included O 3, SO 2, CO and particle scattering from June to August 1997-2003, in the Mid-Atlantic US (mostly in Maryland, Pennsylvania and Virginia). The clustering technique could discriminate distinct profile shapes including measurements made during the 2002 Canadian forest fires. Forty-eight-hour back trajectories were run for each profile and the integrated NO x and SO 2 point source emissions encountered by each trajectory were calculated using data from the EPA Clean Air Market Division's emissions database. There was a strong correlation between integrated NO x emissions and O 3 profiles, indicating that O 3 profiles are strongly influenced by and can be predicted with point source emissions. There is a prevalent concentration of SO 2 over the eastern US with mixing ratios decreasing smoothly from about 3.5 ppb near the surface to 0.2 ppb at 2400 m.

  17. Chemical Diversity and Defence Metabolism: How Plants Cope with Pathogens and Ozone Pollution

    PubMed Central

    Iriti, Marcello; Faoro, Franco

    2009-01-01

    Chemical defences represent a main trait of the plant innate immune system. Besides regulating the relationship between plants and their ecosystems, phytochemicals are involved both in resistance against pathogens and in tolerance towards abiotic stresses, such as atmospheric pollution. Plant defence metabolites arise from the main secondary metabolic routes, the phenylpropanoid, the isoprenoid and the alkaloid pathways. In plants, antibiotic compounds can be both preformed (phytoanticipins) and inducible (phytoalexins), the former including saponins, cyanogenic glycosides and glucosinolates. Chronic exposure to tropospheric ozone (O3) stimulates the carbon fluxes from the primary to the secondary metabolic pathways to a great extent, inducing a shift of the available resources in favour of the synthesis of secondary products. In some cases, the plant defence responses against pathogens and environmental pollutants may overlap, leading to the unspecific synthesis of similar molecules, such as phenylpropanoids. Exposure to ozone can also modify the pattern of biogenic volatile organic compounds (BVOC), emitted from plant in response to herbivore feeding, thus altering the tritrophic interaction among plant, phytophagy and their natural enemies. Finally, the synthesis of ethylene and polyamines can be regulated by ozone at level of S-adenosylmethionine (SAM), the biosynthetic precursor of both classes of hormones, which can, therefore, mutually inhibit their own biosynthesis with consequence on plant phenotype. PMID:20111684

  18. Feasibility of Soil Aquifer Treatment for Removal Chemical Pollutants of Wastewater

    NASA Astrophysics Data System (ADS)

    El-Hattab, Ibrahim H.; Rashed, I. M.; Khalil, M. R.

    This study evaluated Soil Aquifer Treatment (SAT) as a method applied for removal of some chemical pollutants within wastewater. This study was made on two pilot areas in Egypt, in Abu Rawash district and El Mansouria district. The study concerned with evaluating the SAT system removal efficiency by different soil types, assessing optimum soil matrix for achieving adequate SAT, evaluating the renovated water quality conjugate to various water depths and assessing the change occur in some of the wastewater constituents (zinc, iron as heavy metals and magnesium, sodium as a basic cations). The results concluded that sandy loam soil was better than clayed soil for magnesium and sodium removal through SAT and sandy soil was not recommended for Magnesium and Sodium removal. Sandy soil was better than clayed soil for zinc and Iron removal through SAT system and sandy loam soil was not recommended for zinc and iron removal.

  19. Air pollutants effect on monoterpenes composition and foliar chemical parameters in Schinus areira L.

    PubMed

    Wannaz, E D; Zygadlo, J A; Pignata, M L

    2003-04-15

    Monoterpenes, pigments, lipid peroxidation products, sulfur and water content expressed as dry weight/fresh weight ratio were measured in leaves of Schinus areira L. collected in Mendoza, Argentina. The sampling sites showed different SO(2), NO(2) and PM(10) levels, which allowed setting out zones by mapping. Foliar chemical parameters in S. areira were analysed in relation to these zones. High hydroperoxy conjugated dienes (HPCD) and alpha-phellandrene content in foliar samples coming from areas with high SO(2) levels were measured. Principal component analysis (PCA) showed a positive association among SO(2), HPCD, malondialdehyde, sabinene and beta-pinene. In relation to NO(2) levels high values of chlorophyll (Chl)-b and Chl-b/Chl-a ratio were found. PCA showed for NO(2), an association with Chl-b/Chl-a, phaeophytin-a/Chl-a ratios and alpha-phellandrene. As regard PM(10), no significant differences were found in the chemical parameters indicating foliar damage, whereas the contents of tricyclene, alpha-pinene and beta-pinene showed low values in the area with high levels of this pollutant. From the results, it can be inferred that the more noticeable changes in the foliar chemistry of S. areira were detected in relation to the different SO(2) levels. This response was associated to an increase in the foliar oxidation processes accompanied by modifications in the levels of terpenes. This is important, as SO(2) was the only pollutant whose values in the annual arithmetic mean were over the standard value of 30 ppb. PMID:12670767

  20. Smog events over Athens during winter 2013-2014: Pollution measurements and chemical characterization

    NASA Astrophysics Data System (ADS)

    Gerasopoulos, Evangelos; Liakakou, Eleni; Psiloglou, Vassilis; Stavroulas, Jason; Fourtziou, Luciana; Roukounakis, Nikolaos; Lianou, Maria; Kappos, Nikolaos; Zarmpas, Pavlos; Kambezidis, Harry; Sciare, Jean; Mihalopoulos, Nikolaos

    2014-05-01

    Smog due to wood burning has evolved to a major pollution problem affecting the most populated Greek cities during winter time. The economic crisis and the subsequent increase in the price of heating oil, has led people to look for alternative ways for domestic heating. Wood burning appeared to be the most common option, resulting to a rapid increase of pollution levels during nighttime, with emphasis on particulate matter. Taking into account the fact that highly populated cities such as Athens are also overloaded with traffic pollution, the need for specialized air quality measurements for the evaluation of the newly emerged problem was an imperative. Measurements of smog related pollution components in Athens took place during winter 2013-2014, at the premises of the National Observatory of Athens in Thissio (city center). The site was selected as representative of the average situation in Athens, while most of wood burning activities take place in Athens' suburban areas. For the chemical characterization of the smog particles, on line chemistry monitoring was performed by an Aerosol Chemical Speciation Monitor (ACSM, with 30 minutes resolution for the determination of organics, ammonium, sulfate, nitrate and chloride) and a Particle Into Liquid Sampler coupled with an Ionic Chromatograph (PILS, with 15 minutes resolution for the determination of ammonium and potassium). Additionally, aerosol samples were collected on 12-hour basis using a sequential dichotomous sampler for the sampling of PM2.5, PM2.5-10and PM10 fractions of aerosols on quartz filters, for further analyses, while a beta attenuation PM monitor was also deployed. Gas analyzers were installed for continuous NOx (NO, NO2), SO2, CO and O3 monitoring on 1-minute resolution. Finally, black carbon (BC) measurements were conducted with: a Particle Soot Absorption Photometer, a portable Aethalometer and two Multi Angle Absorption Photometers. The meteorological conditions were recorded during the whole

  1. Determinants of exposure to chemical pollutants in wet X-ray film processing in Iran.

    PubMed

    Kakooei, Hossein; Ardakani, Mehdi B; Sadighi, Alireza

    2007-07-15

    The aim of the current study was to measure glutaraldehyde, acetic acid and sulfur dioxide and levels inside wet x-ray processing areas in a developing country and comparing data with those in developed countries. Forty-five radiographers from 10 educational hospitals affiliated to the Tehran University of Medical Sciences (TUMS) in Tehran, Iran participated in this descriptive-analytical study. Exposure to glutaraldehyde (a constituent of developer chemistry), acetic acid (a constituent of fixer chemistry) and sulfur dioxide (a byproduct of sulfites present in both developer and fixer solutions) was measured in all participants as well as area exposure. Average full-shift exposure to glutaraldehyde, acetic acid and sulfur dioxide were 0.0018, 2.65 and 1.64 mg m(-1), respectively. The results showed that the TUMS radiographers full-shift exposures are generally lower than the American Conference of Governmental Industrial Hygienists (ACGIH) recommended levels. The concentration of glutaraldehyde collected by area sampling (darkroom) was almost five times (0.0104 mg m(-3)) greater than taken by personal sampling. Exposure to the chemical pollutants in the currents study were generally higher than in developed countries. Identification of these key exposure determinants is useful in targeting exposure evaluation and controls to reduce developer and fixer chemicals exposures in the radiology departments. Employing of a digital imaging system that do not involve wet x-ray processing of photographic film would be a useful device for radiographers protection. PMID:19070154

  2. Cadmium chemical speciation and absorption in plant in a polluted soil

    NASA Astrophysics Data System (ADS)

    Gigliotti, Giovanni; Massaccesi, Luisa

    2013-04-01

    Cadmium is a very toxic heavy metal presents in nature in small amounts, with an average content of 0.2 mg kg-1 in the geosphere. Nonetheless, anthropogenic activities such as industrial processes, large use of phosphate fertilizers and sewage sludge disposals may determine a massive accumulation of Cd in soil. Cd is considered a particularly interesting heavy metal as it can be accumulated by plants to levels that can be toxic to humans and animals, when consumed even in minor amounts. The aim of the present work was to study in a soil polluted with Cd for a long time i) the distribution of Cd in different chemical fractions by means of a sequential extraction procedure; ii) the adsorption of Cd by plants grown in this polluted soil; iii) the change in the distribution of Cd in the soil fractions possibly due to root exudates after plant growing. The chemical fractionation procedure used involved the following forms: a) exchangeable, b) bound to carbonates, c) bound to Fe-Mn oxides and hydroxides, d) bound to organic matter, e) residual part. The following reagents and extraction times were applied: a) 1 M CH3COONa (1:10, w/v; pH 8.2) for 16 h at room temperature; b) 0,1 M CH3COOH for 16 h at room temperature; c) 0,1 M NH2OH•HCl (1:10, w/v; adjusted to pH 2.0 with HNO3) for 16 h at room temperature; d) 30% H2O2 (adjusted to pH 2.0 with HNO3) at 85 °C, followed by extraction with 1 M CH3COONH4 (1:10, w/v; adjusted to pH 2.0 with HNO3) for 16 h at room temperature; e) acid digestion with concentrated HNO3 and 30% H2O2 for residue fraction. Festuca seeds were germinated in the contaminated soil in plastic flats and non-contaminated soil. After two days the seedling were submitted to day/night conditions. The seedlings were collected 6 weeks after seeding and divided in roots and shoots and analysed for Cd concentration. The polluted soil has average Cd content of 200 mg kg-1, instead, the Cd content in the same unpolluted soil was about 0.44 mg kg-1. The

  3. Method for Fusing Observational Data and Chemical Transport Model Simulations To Estimate Spatiotemporally Resolved Ambient Air Pollution.

    PubMed

    Friberg, Mariel D; Zhai, Xinxin; Holmes, Heather A; Chang, Howard H; Strickland, Matthew J; Sarnat, Stefanie Ebelt; Tolbert, Paige E; Russell, Armistead G; Mulholland, James A

    2016-04-01

    Investigations of ambient air pollution health effects rely on complete and accurate spatiotemporal air pollutant estimates. Three methods are developed for fusing ambient monitor measurements and 12 km resolution chemical transport model (CMAQ) simulations to estimate daily air pollutant concentrations across Georgia. Temporal variance is determined by observations in one method, with the annual mean CMAQ field providing spatial structure. A second method involves scaling daily CMAQ simulated fields using mean observations to reduce bias. Finally, a weighted average of these results based on prediction of temporal variance provides optimized daily estimates for each 12 × 12 km grid. These methods were applied to daily metrics of 12 pollutants (CO, NO2, NOx, O3, SO2, PM10, PM2.5, and five PM2.5 components) over the state of Georgia for a seven-year period (2002-2008). Cross-validation demonstrates a wide range in optimized model performance across pollutants, with SO2 predicted most poorly due to limitations in coal combustion plume monitoring and modeling. For the other pollutants studied, 54-88% of the spatiotemporal variance (Pearson R(2) from cross-validation) was captured, with ozone and PM2.5 predicted best. The optimized fusion approach developed provides daily spatial field estimates of air pollutant concentrations and uncertainties that are consistent with observations, emissions, and meteorology. PMID:26923334

  4. Chemical pollution assessment and prioritisation model for the Upper and Middle Vaal water management areas of South Africa.

    PubMed

    Dzwairo, B; Otieno, F A O

    2014-12-01

    A chemical pollution assessment and prioritisation model was developed for the Upper and Middle Vaal water management areas of South Africa in order to provide a simple and practical Pollution Index to assist with mitigation and rehabilitation activities. Historical data for 2003 to 2008 from 21 river sites were cubic-interpolated to daily values. Nine parameters were considered for this purpose, that is, ammonium, chloride, electrical conductivity, dissolved oxygen, pH, fluoride, nitrate, phosphate and sulphate. Parameter selection was based on sub-catchment pollution characteristics and availability of a consistent data range, against a harmonised guideline which provided five classes. Classes 1, 2, 3 and 4 used ideal catchment background values for Vaal Dam, Vaal Barrage, Blesbokspruit/Suikerbosrant and Klip Rivers, respectively. Class 5 represented values which fell above those for Klip River. The Pollution Index, as provided by the model, identified pollution prioritisation monitoring points on Rietspruit-W:K2, Natalspruit:K12, Blesbokspruit:B1, Rietspruit-L:R1/R2, Taaibosspruit:T1 and Leeuspruit:L1. Pre-classification indicated that pollution sources were domestic, industrial and mine effluent. It was concluded that rehabilitation and mitigation measures should prioritise points with high classes. Ability of the model to perform simple scenario building and analysis was considered to be an effective tool for acid mine drainage pollution assessment. PMID:25473990

  5. Chemical constituents of fine particulate air pollution and pulmonary function in healthy adults: the Healthy Volunteer Natural Relocation study.

    PubMed

    Wu, Shaowei; Deng, Furong; Hao, Yu; Shima, Masayuki; Wang, Xin; Zheng, Chanjuan; Wei, Hongying; Lv, Haibo; Lu, Xiuling; Huang, Jing; Qin, Yu; Guo, Xinbiao

    2013-09-15

    The study examined the associations of 32 chemical constituents of particulate matter with an aerodynamic diameter ≤2.5 μm (PM₂.₅) with pulmonary function in a panel of 21 college students. Study subjects relocated from a suburban area to an urban area with changing ambient air pollution levels and contents in Beijing, China, and provided daily morning/evening peak expiratory flow (PEF) and forced expiratory volume in 1s (FEV₂₁) measurements over 6 months in three study periods. There were significant reductions in evening PEF and morning/evening FEV₂₁ associated with various air pollutants and PM₂.₅ constituents. Four PM₂.₅ constituents (copper, cadmium, arsenic and stannum) were found to be most consistently associated with the reductions in these pulmonary function measures. These findings provide clues for the respiratory effects of specific particulate chemical constituents in the context of urban air pollution. PMID:23747477

  6. 40 CFR Table 1 to Subpart Vvvvvv... - Hazardous Air Pollutants Used To Determine Applicability of Chemical Manufacturing Operations

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 14 2011-07-01 2011-07-01 false Hazardous Air Pollutants Used To Determine Applicability of Chemical Manufacturing Operations 1 Table 1 to Subpart VVVVVV of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED)...

  7. 40 CFR Table 1 to Subpart Vvvvvv... - Hazardous Air Pollutants Used To Determine Applicability of Chemical Manufacturing Operations

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 15 2012-07-01 2012-07-01 false Hazardous Air Pollutants Used To Determine Applicability of Chemical Manufacturing Operations 1 Table 1 to Subpart VVVVVV of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED)...

  8. Environmental Pollution

    ERIC Educational Resources Information Center

    Breitbeil, Fred W., III

    1973-01-01

    Presents a thorough overview of the many factors contributing to air and water pollution, outlines the chemical reactions involved in producing toxic end-products, and describes some of the consequences of pollutants on human health and ecosystems. (JR)

  9. Indoor Air Pollution (Environmental Health Student Portal)

    MedlinePlus

    ... Gases Impact on Weather Health Effects Take Action Water Pollution Water Pollution Home Chemicals and Pollutants Natural Disasters Drinking Water ... Gases Impact on Weather Health Effects Take Action Water Pollution Water Pollution Home Chemicals and Pollutants Natural Disasters ...

  10. Construction of a technique plan repository and evaluation system based on AHP group decision-making for emergency treatment and disposal in chemical pollution accidents.

    PubMed

    Shi, Shenggang; Cao, Jingcan; Feng, Li; Liang, Wenyan; Zhang, Liqiu

    2014-07-15

    The environmental pollution resulting from chemical accidents has caused increasingly serious concerns. Therefore, it is very important to be able to determine in advance the appropriate emergency treatment and disposal technology for different types of chemical accidents. However, the formulation of an emergency plan for chemical pollution accidents is considerably difficult due to the substantial uncertainty and complexity of such accidents. This paper explains how the event tree method was used to create 54 different scenarios for chemical pollution accidents, based on the polluted medium, dangerous characteristics and properties of chemicals involved. For each type of chemical accident, feasible emergency treatment and disposal technology schemes were established, considering the areas of pollution source control, pollutant non-proliferation, contaminant elimination and waste disposal. Meanwhile, in order to obtain the optimum emergency disposal technology schemes as soon as the chemical pollution accident occurs from the plan repository, the technique evaluation index system was developed based on group decision-improved analytical hierarchy process (AHP), and has been tested by using a sudden aniline pollution accident that occurred in a river in December 2012. PMID:24887122

  11. Association of allergic rhinitis or asthma with pollen and chemical pollutants in Szeged, Hungary, 1999-2007

    NASA Astrophysics Data System (ADS)

    Makra, László; Matyasovszky, István; Bálint, Beatrix; Csépe, Zoltán

    2014-07-01

    The effect of biological (pollen) and chemical air pollutants on respiratory hospital admissions for the Szeged region in Southern Hungary is analysed. A 9-year (1999-2007) database includes—besides daily number of respiratory hospital admissions—daily mean concentrations of CO, PM10, NO, NO2, O3 and SO2. Two pollen variables ( Ambrosia and total pollen excluding Ambrosia) are also included. The analysis was performed for patients with chronic respiratory complaints (allergic rhinitis or asthma bronchiale) for two age categories (adults and the elderly) of males and females. Factor analysis was performed to clarify the relative importance of the pollutant variables affecting respiratory complaints. Using selected low and high quantiles corresponding to probability distributions of respiratory hospital admissions, averages of two data sets of each air pollutant variable were evaluated. Elements of these data sets were chosen according to whether actual daily patient numbers were below or above their quantile value. A nonparametric regression technique was applied to discriminate between extreme and non-extreme numbers of respiratory admissions using pollen and chemical pollutants as explanatory variables. The strongest correlations between extreme patient numbers and pollutants can be observed during the pollen season of Ambrosia, while the pollen-free period exhibits the weakest relationships. The elderly group with asthma bronchiale is characterised by lower correlations between extreme patient numbers and pollutants compared to adults and allergic rhinitis, respectively. The ratio of the number of correct decisions on the exceedance of a quantile resulted in similar conclusions as those obtained by using multiple correlations.

  12. Chemical Properties of Air Pollutants and Cause-Specific Hospital Admissions among the Elderly in Atlanta, Georgia

    PubMed Central

    Zanobetti, Antonella; Schwartz, Joel; Coull, Brent A.

    2011-01-01

    Background: Health risks differ by fine particle (aerodynamic diameter ≤ 2.5 μm) component, although with substantial variability. Traditional methods to assess component-specific risks are limited, suggesting the need for alternative methods. Objectives: We examined whether the odds of daily hospital admissions differ by pollutant chemical properties. Methods: We categorized pollutants by chemical properties and examined their impacts on the odds of daily hospital admissions among Medicare recipients > 64 years of age in counties in Atlanta, Georgia, for 1998–2006. We analyzed data in two stages. In the first stage we applied a case-crossover analysis to simultaneously estimate effects of 65 pollutants measured in the Aerosol Research and Inhalation Epidemiology Study on cause-specific hospital admissions, controlling for temperature and ozone. In the second stage, we regressed pollutant-specific slopes from the first stage on pollutant properties. We calculated uncertainty estimates using a bootstrap procedure. We repeated the two-stage analyses using coefficients from first-stage models that included single pollutants plus ozone and meteorological variables only. We based our primary analyses on exposures on day of admission. Results: We found that 24-hr transition metals and alkanes were associated with increased odds [0.26%; 95% confidence interval (CI), 0.02–0.48; and 0.37%; 95% CI, 0.04–0.72, respectively] of hospital admissions for cardiovascular disease (CVD). Transition metals were significantly associated with increased hospital admissions for ischemic heart disease, congestive heart failure, and atrial fibrillation. Increased respiratory-related hospital admissions were significantly associated with alkanes. Aromatics and microcrystalline oxides were significantly associated with decreased CVD- and respiratory-related hospital admissions. Conclusions: The two-stage approach showed transition metals to be consistently associated with increased

  13. Association of allergic rhinitis or asthma with pollen and chemical pollutants in Szeged, Hungary, 1999-2007.

    PubMed

    Makra, László; Matyasovszky, István; Bálint, Beatrix; Csépe, Zoltán

    2014-07-01

    The effect of biological (pollen) and chemical air pollutants on respiratory hospital admissions for the Szeged region in Southern Hungary is analysed. A 9-year (1999-2007) database includes--besides daily number of respiratory hospital admissions--daily mean concentrations of CO, PM10, NO, NO2, O3 and SO2. Two pollen variables (Ambrosia and total pollen excluding Ambrosia) are also included. The analysis was performed for patients with chronic respiratory complaints (allergic rhinitis or asthma bronchiale) for two age categories (adults and the elderly) of males and females. Factor analysis was performed to clarify the relative importance of the pollutant variables affecting respiratory complaints. Using selected low and high quantiles corresponding to probability distributions of respiratory hospital admissions, averages of two data sets of each air pollutant variable were evaluated. Elements of these data sets were chosen according to whether actual daily patient numbers were below or above their quantile value. A nonparametric regression technique was applied to discriminate between extreme and non-extreme numbers of respiratory admissions using pollen and chemical pollutants as explanatory variables. The strongest correlations between extreme patient numbers and pollutants can be observed during the pollen season of Ambrosia, while the pollen-free period exhibits the weakest relationships. The elderly group with asthma bronchiale is characterised by lower correlations between extreme patient numbers and pollutants compared to adults and allergic rhinitis, respectively. The ratio of the number of correct decisions on the exceedance of a quantile resulted in similar conclusions as those obtained by using multiple correlations. PMID:23558448

  14. The pink shrimp Farfantepenaeus duorarum, its symbionts and helminths as bioindicators of chemical pollution in Campeche Sound, Mexico.

    PubMed

    Vidal-Martínez, V M; Aguirre-Macedo, M L; Del Rio-Rodríguez, R; Gold-Bouchot, G; Rendón-von Osten, J; Miranda-Rosas, G A

    2006-06-01

    The pink shrimp Farfantepenaeus duorarum may acquire pollutants, helminths and symbionts from their environment. Statistical associations were studied between the symbionts and helminths of F. duorarum and pollutants in sediments, water and shrimps in Campeche Sound, Mexico. The study area spatially overlapped between offshore oil platforms and natural shrimp mating grounds. Spatial autocorrelation of data was controlled with spatial analysis using distance indices (SADIE) which identifies parasite or pollutant patches (high levels) and gaps (low levels), expressing them as clustering indices compared at each point to produce a measure of spatial association. Symbionts included the peritrich ciliates Epistylis sp. and Zoothamnium penaei and all symbionts were pooled. Helminths included Hysterothylacium sp., Opecoeloides fimbriatus, Prochristianella penaei and an unidentified cestode. Thirty-five pollutants were identified, including polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), pesticides and heavy metals. The PAHs (2-3 ring) in water, unresolved complex mixture (UCM), Ni and V in sediments, and Zn, Cr and heptachlor in shrimps were significantly clustered. The remaining pollutants were randomly distributed in the study area. Juvenile shrimps acquired pesticides, PAHs (2-3 rings) and Zn, while adults acquired PAHs (4-5 rings), Cu and V. Results suggest natural PAH spillovers, and continental runoff of dichlorodiphenyltrichloroethane (DDT), PCBs and PAHs (2-3 ring). There were no significant associations between pollutants and helminths. However, there were significant negative associations of pesticides, UCM and PCBs with symbiont numbers after controlling shrimp size and spatial autocorrelation. Shrimps and their symbionts appear to be promising bioindicators of organic chemical pollution in Campeche Sound. PMID:16768859

  15. The Relationship between Odour Annoyance Scores and Modelled Ambient Air Pollution in Sarnia, “Chemical Valley”, Ontario

    PubMed Central

    Atari, Dominic Odwa; Luginaah, Isaac N.; Fung, Karen

    2009-01-01

    This study aimed at establishing the relationship between annoyance scores and modelled air pollution in “Chemical Valley”, Sarnia, Ontario (Canada). Annoyance scores were taken from a community health survey (N = 774); and respondents’ exposure to nitrogen dioxide (NO2) and sulphur dioxide (SO2) were estimated using land use regression (LUR) models. The associations were examined by univariate analysis while multivariate logistic regression was used to examine the determinants of odour annoyance. The results showed that odour annoyance was significantly correlated to modelled pollutants at the individual (NO2, r = 0.15; SO2, r = 0.13) and census tract (NO2, r = 0.56; SO2, r = 0.67) levels. The exposure-response relationships show that residents of Sarnia react to very low pollution concentrations levels even if they are within the Ontario ambient air quality criteria. The study found that exposure to high NO2 and SO2 concentrations, gender, and perception of health effects were significant determinants of individual odour annoyance reporting. The observed association between odour annoyance and modelled ambient pollution suggest that individual and census tract level annoyance scores may serve as proxies for air quality in exposed communities because they capture the within area spatial variability of pollution. However, questionnaire-based odour annoyance scores need to be validated longitudinally and across different scales if they are to be adopted for use at the national level. PMID:20054461

  16. Aquamicrobium terrae sp. nov., isolated from the polluted soil near a chemical factory.

    PubMed

    Wu, Zhi-Guo; Wang, Fang; Gu, Cheng-Gang; Zhang, Yin-Ping; Yang, Zong-Zheng; Wu, Xiao-Wei; Jiang, Xin

    2014-06-01

    A Gram-negative, aerobic, non-motile bacterial strain hun6(T) isolated from the polluted soil near a chemical factory in northern Nanjing, China was investigated to clarify its taxonomic position. Growth of strain hun6(T) occurred between 10 and 45 °C (optimum, 30 °C) and between pH 6.0 and 8.0 (optimum, pH 7.0). No growth occurred at NaCl concentrations greater than 5 % (w/v). The 16S rRNA gene sequence analysis indicated that strain hun6(T) belongs to the genus Aquamicrobium. The sequence similarities of strain hun6(T) to other type strains of Aquamicrobium genus were all below 98.5 %. The presence of ubiquinone-10, the predominant fatty acid summed feature 8 (C18:1 ω7c and/or C18:1 ω6c) and C19:0 cyclo ω8c, a polar lipid pattern with phosphatidylglycerol, phosphatidylcholine, diphosphatidylglycerol, phosphatidylethanolamine and phophatidylmonomethylethanoamine were in accord with the characteristics of the genus Aquamicrobium. The G+C content of the genomic DNA was determined to be 63.5 mol%. The results of DNA-DNA hybridization, physiological and biochemical tests and chemotaxonomic properties allowed genotypic and phenotypic differentiation of strain hun6(T) from all known Aquamicrobium species. Therefore, strain hun6(T) can be assigned to a new species of this genus for which the name Aquamicrobium terrae sp. nov. is proposed. The type strain is hun6(T) (= CICC 10733(T) = DSM 27865(T)). PMID:24788880

  17. Waste water treatment: Chemical industry. (Latest citations from Pollution Abstracts). Published Search

    SciTech Connect

    Not Available

    1992-05-01

    The bibliography contains citations concerning wastewater treatment of industrial pollutants. The use and effectiveness of biological treatments and carbon additives are examined. References also discuss problems and recommendations for the removal of mercury and its compounds, fertilizers, and pesticides from polluted waste water. (Contains 250 citations and includes a subject term index and title list.)

  18. A new technology for harnessing the dye polluted water and dye collection in a chemical factory.

    PubMed

    Pu, J P; Pu, P M; Hu, C H; Qian, J L; Pu, J X; Hua, J K

    2001-04-01

    A new technology for harnessing the dye polluted water and dye collection was developed. It is based on the enhanced evaporation by using solar, wind and air temperature energy and additional heat-electric energy. It consists of four parts: (1) evaporation carrier system (evaporation carrier and frame for evaporation carrier) for polluted water; (2) polluted water circulating system (pumping-spraying-collecting); (3) heating system; (4) workshop with polluted water reservoir-tanks and rainfall prevention roof. The polluted water was (heated in case necessary) sprayed to the evaporation carrier system and the water was evaporated when it moved in the space and downward along the carrier mainly by using natural (solar, wind and air temperature energy). In case, when there is no roof for the carrier system, the polluted water can be stored in the reservoirs (storage volume for about 20 days). The first 10-25 mm rainfall also need to be stored in the reservoirs to meet the state standard for discharging wastewater. The dye may be collected at the surface in the reservoir-tanks and the crystallized salt may be collected at the bottom plate. The black-color wastewater released by the factory is no more discharged to the surface water system of Taihu Lake Basin. About 2 kg dye and 200 kg industrial salt may be collected from each tone of the polluted water. The non-pollution production of dye may be realized by using this technology with environmental, economical and social benefits. PMID:11590742

  19. PROCESS MODIFICATIONS TOWARDS MINIMIZATION OF ENVIRONMENTAL POLLUTANTS IN THE CHEMICAL PROCESSING INDUSTRY

    EPA Science Inventory

    The report covers the development of a matrix of significant pollution problems and attendant process modifications which would have impact on the reduction or elimination of pollutants inherent in these processes. Industries covered are: (1) Refining of Nonferrous Metals; (2) Th...

  20. Non-Chemical Stressors and Cumulative Risk Assessment: An Overview of Current Initiatives and Potential Air Pollutant Interactions

    PubMed Central

    Lewis, Ari S.; Sax, Sonja N.; Wason, Susan C.; Campleman, Sharan L.

    2011-01-01

    Regulatory agencies are under increased pressure to consider broader public health concerns that extend to multiple pollutant exposures, multiple exposure pathways, and vulnerable populations. Specifically, cumulative risk assessment initiatives have stressed the importance of considering both chemical and non-chemical stressors, such as socioeconomic status (SES) and related psychosocial stress, in evaluating health risks. The integration of non-chemical stressors into a cumulative risk assessment framework has been largely driven by evidence of health disparities across different segments of society that may also bear a disproportionate risk from chemical exposures. This review will discuss current efforts to advance the field of cumulative risk assessment, highlighting some of the major challenges, discussed within the construct of the traditional risk assessment paradigm. Additionally, we present a summary of studies of potential interactions between social stressors and air pollutants on health as an example of current research that supports the incorporation of non-chemical stressors into risk assessment. The results from these studies, while suggestive of possible interactions, are mixed and hindered by inconsistent application of social stress indicators. Overall, while there have been significant advances, further developments across all of the risk assessment stages (i.e., hazard identification, exposure assessment, dose-response, and risk characterization) are necessary to provide a scientific basis for regulatory actions and effective community interventions, particularly when considering non-chemical stressors. A better understanding of the biological underpinnings of social stress on disease and implications for chemical-based dose-response relationships is needed. Furthermore, when considering non-chemical stressors, an appropriate metric, or series of metrics, for risk characterization is also needed. Cumulative risk assessment research will benefit

  1. Epiphytic lichenosynusia under conditions of chemical pollution: Dose-effect dependencies

    SciTech Connect

    Mikhailova, I.N.; Vorobeichik, E.L.

    1995-11-01

    The dose-effect dependencies, which characterize response of the epiphytic lichenosynusia of southern taiga in the Middle Urals to pollution by discharges of a copper-smelting plant, are substantially non-linear and, in most cases, have an S-shaped form. A transition from background to impact state is very sharp and begins when the background level of pollution is exceeded by 1.5 - 2.3 times.

  2. How chemical pollution becomes a social problem. Risk communication and assessment through regional newspapers during the management of PCB pollutions of the Rhône River (France).

    PubMed

    Comby, Emeline; Le Lay, Yves-François; Piégay, Hervé

    2014-06-01

    The case study of the polychlorinated biphenyl (PCB) pollutions of the Rhône River (France) offers the possibility of studying criteria for the construction of social problems that result from chemical pollution (2005-2010). We investigated the dynamics of competition that create and define pollution as a social problem and entail its decline. News outlets are crucial for determining how an environmental issue emerges locally or nationally; this study used newspapers to highlight the potential of new outlets as a data source to analyze discourse variability, science-policy-media connections and the hydrosphere. Media coverage was based on a content analysis and textual data analysis of 75 articles. Analytical frameworks such as the Downs Model and the Public Arena Model (Hilgartner and Bosk, 1988) that consider time and stakeholders were tested to determine how human alteration of the hydrosphere can become a social problem and to analyze different communication strategies held by stakeholders. In terms of management, we described the temporal dynamics of the social problem based on the case study and considered an explanation of the selections. We considered the organization of particular stakeholders who define the social problem from its beginning to end by focusing on their discourses, relationships, decision-making and political choices, and scientific studies. Despite some biases, newspapers are useful for retrospectively evaluating the emergence of a social problem in the public arena by describing it through discourse and then understanding the temporal patterns of information. Despite uncertainties and information flow, decisions are made and science is translated to the public. PMID:24646671

  3. Multi-step approach for comparing the local air pollution contributions of conventional and innovative MSW thermo-chemical treatments.

    PubMed

    Ragazzi, M; Rada, E C

    2012-10-01

    In the sector of municipal solid waste management the debate on the performances of conventional and novel thermo-chemical technologies is still relevant. When a plant must be constructed, decision makers often select a technology prior to analyzing the local environmental impact of the available options, as this type of study is generally developed when the design of the plant has been carried out. Additionally, in the literature there is a lack of comparative analyses of the contributions to local air pollution from different technologies. The present study offers a multi-step approach, based on pollutant emission factors and atmospheric dilution coefficients, for a local comparative analysis. With this approach it is possible to check if some assumptions related to the advantages of the novel thermochemical technologies, in terms of local direct impact on air quality, can be applied to municipal solid waste treatment. The selected processes concern combustion, gasification and pyrolysis, alone or in combination. The pollutants considered are both carcinogenic and non-carcinogenic. A case study is presented concerning the location of a plant in an alpine region and its contribution to the local air pollution. Results show that differences among technologies are less than expected. Performances of each technology are discussed in details. PMID:22795304

  4. Size-resolved aerosol chemical analysis of extreme haze pollution events during early 2013 in urban Beijing, China.

    PubMed

    Tian, Shili; Pan, Yuepeng; Liu, Zirui; Wen, Tianxue; Wang, Yuesi

    2014-08-30

    Using size-resolved filter sampling and chemical characterization, high concentrations of water-soluble ions, carbonaceous species and heavy metals were found in both fine (PM2.1) and coarse (PM2.1-9) particles in Beijing during haze events in early 2013. Even on clear days, average mass concentration of submicron particles (PM1.1) was several times higher than that previously measured in most of abroad urban areas. A high concentration of particulate matter on haze days weakens the incident solar radiation, which reduces the generation rate of secondary organic carbon in PM1.1. We show that the peak mass concentration of particles shifted from 0.43-0.65μm on clear days to 0.65-1.1μm on lightly polluted days and to 1.1-2.1μm on heavily polluted days. The peak shifts were also found for the following species: organic carbon, elemental carbon, NH4(+), SO4(2-), NO3(-), K, Cu, Zn, Cd and Pb. Our findings demonstrate that secondary inorganic aerosols (36%) and organic matter (26%) dominated the fine particle mass on heavily polluted days, while their contribution reduced to 29% and 18%, respectively, on clear days. Besides fine particles, anthropogenic chemical species also substantially accumulated in the coarse mode, which suggests that particles with aerodynamic diameter larger than 2.1μm cannot be neglected during severe haze events. PMID:25106045

  5. Ecotoxicological risk assessment of chemical pollution in four Iberian river basins and its relationship with the aquatic macroinvertebrate community status.

    PubMed

    Kuzmanović, Maja; López-Doval, Julio C; De Castro-Català, Núria; Guasch, Helena; Petrović, Mira; Muñoz, Isabel; Ginebreda, Antoni; Barceló, Damià

    2016-01-01

    Ecotoxicological risk assessment of chemical pollution in four Iberian river basins (Llobregat, Ebro, Júcar and Guadalquivir) was performed. The data set included more than 200 emerging and priority compounds measured at 77 sampling sites along four river basins studied. The toxic units (TU) approach was used to assess the risk of individual compounds and the concentration addition model (CA) to assess the site specific risk. Link between chemical pollution and aquatic macroinvertebrate communities in situ was examined by using four biological indexes; SPEAR ("Species at Risk Index") as the indicator of decline of sensitive species in relation to general organic (SPEARorganic) and pesticides (SPEARpesticides) pollution; and Shannon and Margalef biodiversity indexes. The results of the study suggested that organic chemicals posed the risk of acute effects at 42% of the sampling sites and the risk of chronic effects at all the sites. Metals posed the acute risk at 44% of the sites. The main drivers of the risk were mainly pesticides and metals. However, several emerging contaminants (e.g. the antidepressant drug sertraline and the disinfectant triclosan) were contributing to the chronic effects risk. When risk associated with metals and organic chemicals was compared, the latter dominated in 2010, mainly due to the presence of highly toxic pesticides, while metals did in 2011. Compounds that are not regulated on the European level were posing the risk of chronic effects at 23% of the sites. The decline of sensitive macroinvertebrate taxa expressed in terms of SPEAR index was correlated with the increase of toxic stress related to organic compounds Biodiversity indexes were negatively correlated with the metals and the urban land use type in the catchment. PMID:26170110

  6. Blood Pressure Changes and Chemical Constituents of Particulate Air Pollution: Results from the Healthy Volunteer Natural Relocation (HVNR) Study

    PubMed Central

    Wu, Shaowei; Deng, Furong; Huang, Jing; Wang, Hongyi; Shima, Masayuki; Wang, Xin; Qin, Yu; Zheng, Chanjuan; Wei, Hongying; Hao, Yu; Lv, Haibo; Lu, Xiuling

    2012-01-01

    Background: Elevated blood pressure (BP) has been associated with particulate matter (PM) air pollution, but associations with PM chemical constituents are still uncertain. Objectives: We investigated associations of BP with various chemical constituents of fine PM (PM2.5) during 460 repeated visits among a panel of 39 university students. Methods: Resting BP was measured using standardized methods before and after the university students relocated from a suburban campus to an urban campus with different air pollution contents in Beijing, China. Air pollution data were obtained from central monitors close to student residences. We used mixed-effects models to estimate associations of various PM2.5 constituents with systolic BP (SBP), diastolic BP (DBP), and pulse pressure. Results: An interquartile range increase of 51.2 μg/m3 in PM2.5 was associated with a 1.08-mmHg (95% CI: 0.17, 1.99) increase in SBP and a 0.96-mmHg (95% CI: 0.31, 1.61) increase in DBP on the following day. A subset of PM2.5 constituents, including carbonaceous fractions (organic carbon and elemental carbon), ions (chloride and fluoride), and metals/metalloid elements (nickel, zinc, magnesium, lead, and arsenic), were found to have robust positive associations with different BP variables, though robust negative associations of manganese, chromium, and molybdenum with SBP or DBP also were observed. Conclusions: Our results support relationships between specific PM2.5 constituents and BP. These findings have potential implications for the development of pollution abatement strategies that maximize public health benefits. PMID:23086577

  7. Chemical characterization of particulate air pollutants Case studies on indoor air quality, cultural heritage and the marine environment

    NASA Astrophysics Data System (ADS)

    Horemans, Benjamin

    When attempting to discuss the effects of airborne particulate matter (PM), it is important to address both physical and chemical aspects of this pollutant. This work reports on the results of three separate case studies, each approaching a specific problem of air pollution by evaluating the chemical composition of PM. 1. In the US and Europe, office workers often complain about work-related health symptoms. These symptoms are collectively referred as the 'sick building syndrome'. This work could be considered as one of the largest data collections on particulate pollutants in Belgian offices. It helps to understand the sources as well as the behavior and fate of PM at our workplace environments. Especially the chemical information on PM makes the results unique, since it enables a better evaluation of the health risks connected to office dust. 2. The Alhambra and Generalife bring every year more than 3 million people to Granada in Southern Spain. Recently, the increasing urbanization of Granada and the immense pressure of mass tourism form a threat for this heritage. Despite the fact that atmospheric pollutants are known to he potentially aggressive for our cultural patrimony. this case study is the first to assess the effects of environmental aerosols on the Alhambra monument. The results of this study could help decision-makers at the Alhambra and the city of Granada with the formulation of preventive conservation measures. They show how local vehicular traffic is the main source for atmospheric pollution in and around the Alhambra monument. Targeted strategies are necessary in order to maximally preserve these monuments and their UNESCO world cultural heritage label. 3. Excessive input of nitrogen-containing atmospheric nutrients via dry and wet deposition can cause entrophication of marine regions, which is also a common, seasonal phenomenon along the coasts of the North Sea. This study is the first to give a complete quantitative description of the

  8. The physical and chemical characteristics of long-lasting trans-boundary mixed pollutants over East Asia

    NASA Astrophysics Data System (ADS)

    Hara, Y.; Uno, I.; Kobayashi, H.; Itahashi, S.; PAN, X.; Nishizawa, T.; Shimizu, A.; Matsui, I.; Sugimoto, N.

    2014-12-01

    Trans-boundary air pollution lasted about 1 week over East Asia from late May to early June 2014. Daily averaged PM2.5 and PM10 exceeded respectively 35μg/m3 and 100μg/m3 during this episode at Fukuoka, southeastern city of Japan. The continuous aerosol plumes were constructed by Asian dust and anthropogenic pollutants, and observed by many aerosol measurements, such as ground-based lidar, space-born lidar, Aerosol Chemical Speciation Analyzer (ACSA) and Polarization Optical Particle Counter (POPC). Regional chemical transport model was used to clarify the meteorological condition forming long-lasting aerosol plumes and the 3D structure. The continuous aerosol plume was made by 2 sequential low pressure systems passing over desert area, and subsequently generated blocking high pressure system over Japan. The averaged aerosol depolarization ratio derived by ground-based lidar and POPC at around 0.5μm during this episode were 0.11 and 0.146, these values were very low for dust case. ACSA data at Fukuoka also showed that coarse model nitrate and fine mode sulfate concentration was very high (3~6μg/m3 for coarse mode nitrate, 5-15 μg/m3 for fine mode sulfate) during this episode. These results suggested that transport of anthropogenic aerosols were occurred during this event together with dust plume. Coarse mode nitrate might be made by internal mixing between dust particles and nitrate. Numerical chemical transport model could not reproduced high concentration of coarse mode nitrate because model did not consider the process of internal mixing between dust particles and nitrate. Further vertical structure and mixing state during long-lasting trans-boundary pollution are clarified.

  9. Detection of human and animal sources of pollution by microbial and chemical methods

    Technology Transfer Automated Retrieval System (TEKTRAN)

    A multi-indicator approach comprising Enterococcus, bacterial source tracking (BST), and sterol analysis was tested for pollution source identification. Fecal contamination was detected in 100% of surface water sites tested. Enterococcus faecium was the dominant species in aged litter samples from p...

  10. CASE STUDY. MERCURY POLLUTION NEAR A CHEMICAL PLANT IN NORTHERN KAZAKHSTAN

    EPA Science Inventory

    In northern Kazakhstan, there is a serious case of mercury pollution near Pavlodar City from an old mercury cell chlor-alkali plant. The soil, sediment, and water are contaminated with more than a thousand tons of mercury and mercury compounds as a result of the operation of the ...

  11. CHANGES TO THE CHEMICAL MECHANISMS FOR HAZARDOUS AIR POLLUTANTS IN CMAQ VERSION 4.6

    EPA Science Inventory

    The extended abstract describes a presentation to the 2006 conference of the Community Modeling and Analysis System. The presentation introduces two new mechanisms for the atmospheric photochemistry of Hazardous Air Pollutants (HAPs) to be used in regional air quality models. It ...

  12. 40 CFR 1.43 - Office of Chemical Safety and Pollution Prevention.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Programs. The Office of Pesticide Programs (OPP), under the management of a Director and Deputy Director are responsible to the Assistant Administrator for leadership of the overall pesticide activities of.... The Office of Pollution Prevention and Toxics (OPPT), under the management of a Director and...

  13. Chemical pollution in inland shallow lakes in the Mediterranean region (NW Spain): PAHs, insecticides and herbicides in water and sediments.

    PubMed

    Hijosa-Valsero, María; Bécares, Eloy; Fernández-Aláez, Camino; Fernández-Aláez, Margarita; Mayo, Rebeca; Jiménez, Juan José

    2016-02-15

    The possible effect of land uses and human-related geographic patterns (presence of roads and urban settlements) on chemical pollution was evaluated in the waters and sediments of fifty-three Mediterranean shallow lakes. The presence of fifty-nine pollutants (belonging to PAHs, insecticides and herbicides groups) was analysed in these lakes by GC-MS. The studied lakes had similar pollutant concentrations to other lakes worldwide. The distribution of the compounds between water and sediment compartments was strongly influenced by log K(ow) values (an average of 3.61 for compounds found in water and of 4.69 for compounds found in sediments). A multivariate analysis suggested that the concentration of PAHs in water could be related to agricultural activities and not related to local road traffic. When assessing nutrient levels in the lakes, it was observed that eutrophicated lakes [>300 μg L(-1) total phosphorus (TP)] appeared in areas affected by urban or industrial use (at least 2% urban use in a 1-km radius around the lake), whilst lakes with lower TP concentrations were placed in forest areas (60% of forest use in a 1-km radius); in addition, the aqueous concentrations of Σ(PAH) were lower in lakes with higher TP concentrations (>150 μg L(-1) TP), which could be related to the adsorption capacity of PAHs onto suspended matter which is present in mesotrophic and eutrophic lakes, thus being removed from the aqueous phase. PMID:26688052

  14. Spatial distribution characteristics of polycyclic musks as a chemical marker in river water and sediment compared with other typical pollutants.

    PubMed

    Mu, Li; Wen, Jianping

    2013-01-01

    Polycyclic musks (PMs), widely used in the cosmetic and perfume industries, are gaining attention as a new type of persistent organic pollutant (POP). The related contamination in developing countries, such as China, where the use of these compounds is increasing, needs to be closely monitored. This work systematically studied the distribution profile (water-suspended particulate-sediment-porewater) of PMs in Haihe River, China. The average concentrations of PMs were comparable to those of the traditional POPs. The typical PMs (galaxolide and tonalide) exhibited different environmental behaviors in various media. Water played a more significant role than suspended particulates in the transport of pollutants. Importantly, this work explored the relationships among PMs, surfactant, phosphorus, carbon, salinity, heavy metals and pesticides. Unlike previous reports focusing on the relationships among PMs, wastewater discharge and population distribution, this work innovatively studied the distribution characteristics of pollutants by principal components analysis. The results suggest that PMs can be used as a chemical marker indicating domestic contamination. PMID:23508139

  15. MODELING OF CHEMICAL TRANSFORMATIONS OF SO(X) AND NO(X) IN THE POLLUTED ATMOSPHERE. AN OVERVIEW OF APPROACHES AND CURRENT STATUS

    EPA Science Inventory

    Two principal approaches are identified in the modeling of chemical transformations of SOx and NOx in the polluted atmosphere. The fundamental approach involves simulation of the detailed chemical kinetics of the SOx-NOx-HC system; in the empirical approach, relatively simple par...

  16. 77 FR 4522 - National Emission Standards for Hazardous Air Pollutants for Chemical Manufacturing Area Sources

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-01-30

    .... On October 29, 2009 (74 FR 56008), the EPA issued the NESHAP for the nine chemical manufacturing area... in 1999 in the Integrated Urban Air Toxics Strategy, (64 FR 38715, July 19, 1999) (Strategy... requirement in 2011 (76 FR 15308, March 21, 2011). The chemical manufacturing area source categories...

  17. Investigating long-range transport of pollution to the Arctic troposphere using aircraft observations and a global chemical transport model

    NASA Astrophysics Data System (ADS)

    Monks, S.; Arnold, S.; Chipperfield, M.; Turquety, S.; Ancellet, G.; Law, K.; Schlager, H.

    2009-04-01

    Surface temperatures in the Arctic have increased more than in any other region over the past few decades. A better understanding of the processes governing this warming, including the role of short-lived greenhouse gases, is therefore urgently required. During summer 2008, the POLARCAT campaign aimed to collect an extensive gas-phase and aerosol dataset within the Arctic troposphere, which will aid the evaluation of our understanding of oxidant photochemistry and aerosol processing in the region. Previous comparisons of global chemical transport models have shown that they exhibit large variability in their Arctic chemical budgets, indicating that the processes controlling Arctic tropospheric composition are not well understood or represented within models. Here, we will use new trace-gas observations from the French ATR and German DLR Falcon aircraft during the POLARCAT experiment to evaluate the ability of a global chemical transport model (TOMCAT) to simulate the summertime transport of pollutants to the Arctic, and their impact on oxidant budgets. In particular, we aim to quantify the impact of anthropogenic and biomass burning sources on the Arctic tropospheric ozone budget. Initial results show that the model underestimates observed concentrations of CO which has led to a re-evaluation of the different sources of CO to the region. Model performance in the Arctic is highly sensitive to the treatment of boreal biomass burning emissions. Boreal biomass burning plumes were sampled frequently over the course of the campaign therefore accurate representation of emission injection heights and fire locations is essential. Model CO is improved with real-time satellite derived daily biomass burning emissions, however large uncertainties in these emissions result in large variability in the Arctic CO budget. We will also present results on the ability of the model to capture pollution transport pathways to the Arctic and contributions to the oxidant and NOy budgets

  18. Exposure to Endocrine-Disrupting Chemicals during Pregnancy and Weight at 7 Years of Age: A Multi-pollutant Approach

    PubMed Central

    Agay-Shay, Keren; Martinez, David; Valvi, Damaskini; Garcia-Esteban, Raquel; Basagaña, Xavier; Robinson, Oliver; Casas, Maribel; Sunyer, Jordi

    2015-01-01

    Background Prenatal exposure to endocrine-disrupting chemicals (EDCs) may induce weight gain and obesity in children, but the obesogenic effects of mixtures have not been studied. Objective We evaluated the associations between pre- and perinatal biomarker concentrations of 27 EDCs and child weight status at 7 years of age. Methods In pregnant women enrolled in a Spanish birth cohort study between 2004 and 2006, we measured the concentrations of 10 phthalate metabolites, bisphenol A, cadmium, arsenic, and lead in two maternal pregnancy urine samples; 6 organochlorine compounds in maternal pregnancy serum; mercury in cord blood; and 6 polybrominated diphenyl ether congeners in colostrum. Among 470 children at 7 years, body mass index (BMI) z-scores were calculated, and overweight was defined as BMI > 85th percentile. We estimated associations with EDCs in single-pollutant models and applied principal-component analysis (PCA) on the 27 pollutant concentrations. Results In single-pollutant models, HCB (hexachlorobenzene), βHCH (β-hexachlorocyclohexane), and polychlorinated biphenyl (PCB) congeners 138 and 180 were associated with increased child BMI z-scores; and HCB, βHCH, PCB-138, and DDE (dichlorodiphenyldichloroethylene) with overweight risk. PCA generated four factors that accounted for 43.4% of the total variance. The organochlorine factor was positively associated with BMI z-scores and with overweight (adjusted RR, tertile 3 vs. 1: 2.59; 95% CI: 1.19, 5.63), and these associations were robust to adjustment for other EDCs. Exposure in the second tertile of the phthalate factor was inversely associated with overweight. Conclusions Prenatal exposure to organochlorines was positively associated with overweight at age 7 years in our study population. Other EDCs exposures did not confound this association. Citation Agay-Shay K, Martinez D, Valvi D, Garcia-Esteban R, Basagaña X, Robinson O, Casas M, Sunyer J, Vrijheid M. 2015. Exposure to endocrine

  19. Mussel watch - measurements of chemical pollutants in bivalves as one indicator of coastal environmental quality

    SciTech Connect

    Farrington, J.W.; Davis, A.C.; Tripp, B.W.; Phelps, D.K.; Galloway, W.B.

    1987-01-01

    The utility of the bivalve sentinel organism approach to monitoring for some chemicals of environmental concern in coastal and estuarine areas has been evaluated by regional and national programs and by smaller-scale research efforts during the past 15 years. The extent and severity of coastal contamination by chemicals such as polychlorinated biphenyls, chlorinated pesticides, trace metals, and plutonium was assessed in several bivalve sentinel organism programs. Advantages and limitations of this approach are presented and discussed briefly within the context of both national and international efforts.

  20. The chemical composition of red giants in 47 Tucanae. II. Magnesium isotopes and pollution scenarios

    NASA Astrophysics Data System (ADS)

    Thygesen, A. O.; Sbordone, L.; Ludwig, H.-G.; Ventura, P.; Yong, D.; Collet, R.; Christlieb, N.; Melendez, J.; Zaggia, S.

    2016-04-01

    Context. The phenomenon of multiple populations in globular clusters is still far from understood, with several proposed mechanisms to explain the observed behaviour. The study of elemental and isotopic abundance patterns are crucial for investigating the differences among candidate pollution mechanisms. Aims: We derive magnesium isotopic ratios for 13 stars in the globular cluster 47 Tucanae (NGC 104) to provide new, detailed information about the nucleosynthesis that has occurred within the cluster. For the first time, the impact of 3D model stellar atmospheres on the derived Mg isotopic ratios is investigated. Methods: Using both tailored 1D atmospheric models and 3D hydrodynamical models, we derive magnesium isotopic ratios from four features of MgH near 5135 Å in 13 giants near the tip of the red giant branch, using high signal-to-noise, high-resolution spectra. Results: We derive the magnesium isotopic ratios for all stars and find no significant offset of the isotopic distribution between the pristine and the polluted populations. Furthermore, we do not detect any statistically significant differences in the spread in the Mg isotopes in either population. No trends were found between the Mg isotopes and [Al/Fe]. The inclusion of 3D atmospheres has a significant impact on the derived 25Mg/24Mg ratio, increasing it by a factor of up to 2.5, compared to 1D. The 26Mg/24Mg ratio, on the other hand, essentially remains unchanged. Conclusions: We confirm the results seen from other globular clusters, where no strong variation in the isotopic ratios is observed between stellar populations, for observed ranges in [Al/Fe]. We see no evidence for any significant activation of the Mg-Al burning chain. The use of 3D atmospheres causes an increase of a factor of up to 2.5 in the fraction of 25Mg, resolving part of the discrepancy between the observed isotopic fraction and the predictions from pollution models. Based on observations made with the ESO Very Large Telescope

  1. Method for quantification of chemicals in a pollution plume using a moving membrane-based sensor exemplified by mass spectrometry.

    PubMed

    Janfelt, Christian; Lauritsen, Frants R; Toler, Strawn K; Bell, Ryan J; Short, R Timothy

    2007-07-15

    Quantification of a chemical concentration in a pollution plume using a moving membrane-based sensor can be problematic. In many cases, the sensor passes through the plume faster than the time necessary to reach a steady-state signal, which is often used for quantification. Since the exposure time is typically not known, quantification based upon the flow injection analysis principle is also impractical. In this paper, we present a two-dimensional calibration model, exemplified by membrane inlet mass spectrometry, in which the concentration of a chemical can be determined using a simple algorithm. The concentration is given by a calibration factor, which is multiplied by the peak height and divided by the value of a polynomial, calculated at a normalized peak width. The model is demonstrated to give good quantitative estimates of concentrations for exposure times down to approximately 1/10 of the time it takes to reach steady-state diffusion through the membrane. Although the model is demonstrated using membrane inlet mass spectrometry and detection of volatile organic chemicals, it should be generally applicable to many membrane-covered sensors. PMID:17563118

  2. Invertebrate diversity in relation to chemical pollution in an Umbrian stream system (Italy).

    PubMed

    Pallottini, Matteo; Goretti, Enzo; Gaino, Elda; Selvaggi, Roberta; Cappelletti, David; Céréghino, Régis

    2015-07-01

    We used self-organizing maps (SOM, neural network) to bring out patterns of benthic macroinvertebrate diversity in relation to river pollution. Fourteen stations were sampled over various seasons in the Nestore drainage basin (Central Italy) and characterized for macroinvertebrate communities, nutrient and heavy metal concentrations. Physicochemical variables were introduced into a SOM previously trained with macroinvertebrate data. Patterns of communities matched spatial and seasonal changes in environmental conditions, including water chemistry related to economic activities in the catchment. Although our analyses did not allow us to establish the specific effect of any given environmental parameter upon macroinvertebrate community composition based on the field study, they enabled us to map the ecological health of river ecosystems in a readily interpretable manner. PMID:26043800

  3. Pollution Comes Home and Gets Personal: Women's Experience of Household Chemical Exposure

    ERIC Educational Resources Information Center

    Altman, Rebecca Gasior; Morello-Frosch, Rachel; Brody, Julia Green; Rudel, Ruthann; Brown, Phil; Averick, Mara

    2008-01-01

    We report on interviews conducted with participants in a novel study about environmental chemicals in body fluids and household air and dust. Interviews reveal how personal and collective environmental history influence the interpretation of exposure data, and how participants fashion an emergent understanding of environmental health problems from…

  4. EFFECTS OF WATER POLLUTANTS AND OTHER CHEMICALS ON FISH ACETYLCHOLINESTERASE (IN VITRO)

    EPA Science Inventory

    Acetylcholinesterase (AChE) preparations from the muscle of the fathead minnow (Pimephales promelas Rafinesque) were treated (in vitro) with 74 chemicals of various classes, many of which are environmental contaminants, to determine their effect upon enzyme activity. A highly inh...

  5. MUSSEL WATCH--MEASUREMENTS OF CHEMICAL POLLUTANTS IN BIVALVES AS ONE INDICATOR OF COASTAL ENVIRONMENTAL QUALITY

    EPA Science Inventory

    The utility of the bivalve sentinel organism approach to monitoring for some chemicals of environmental concern in coastal and estuarine areas has been evaluated by regional and national programs and by smaller scale research efforts during the past 15 years. The extent and sever...

  6. CAN TISSUE ANOMALIES THAT OCCUR IN MARINE FISH IMPLICATE SPECIFIC POLLUTANT CHEMICALS

    EPA Science Inventory

    The advantage of using tissue abnormalities in wild fish as a measure of fish health is that the abnormality, unlike sensitive biochemical anomalies, cannot be said to have occurred during capture or transport. This paper is concerned with factors (chemical, physical, or biologic...

  7. Levels of chemical and microbiological pollutants in the vicinity of a waste incineration plant and human health risks: temporal trends.

    PubMed

    Vilavert, Lolita; Nadal, Martí; Figueras, María J; Kumar, Vikas; Domingo, José L

    2011-09-01

    In 2007, a program was initiated to monitor air levels of volatile organic compounds (VOCs) and bioaerosols in the vicinity of a municipal solid waste incinerator (MSWI) (Tarragona, Catalonia, Spain). To investigate the temporal trends of chemical and microbiological pollutants, four 6-monthly campaigns were performed. Air samples were collected at different distances and directions from the facility, as well as in reference sites. In general terms, the concentrations of microbiological agents were very similar to those found in urban zones worldwide. The seasonal evaluation of the results showed higher levels of gram-negative bacteria in winter, contrasting with the increase of the airborne amount of total bacteria in summer. On the other hand, the concentrations of VOCs (mean range: 7.6-18.2 μg m(-3)) were typical of suburban zones. The current exposure to those compounds should not mean additional health risks for the population living nearby. PMID:21550630

  8. Multivariate analysis of respiratory problems and their connection with meteorological parameters and the main biological and chemical air pollutants

    NASA Astrophysics Data System (ADS)

    Matyasovszky, István; Makra, László; Bálint, Beatrix; Guba, Zoltán; Sümeghy, Zoltán

    2011-08-01

    The aim of the study is to analyse the joint effect of biological (pollen) and chemical air pollutants, as well as meteorological variables, on the hospital admissions of respiratory problems for the Szeged region in Southern Hungary. The data set used covers a nine-year period (1999-2007) and is unique in the sense that it includes—besides the daily number of respiratory hospital admissions—not just the hourly mean concentrations of CO, PM 10, NO, NO 2, O 3 and SO 2 with meteorological variables (temperature, global solar flux, relative humidity, air pressure and wind speed), but two pollen variables ( Ambrosia and total pollen excluding Ambrosia) as well. The analysis was performed using three age categories for the pollen season of Ambrosia and the pollen-free season. Meteorological elements and air pollutants are clustered in order to define optimum environmental conditions of high patient numbers. ANOVA was then used to determine whether cluster-related mean patient numbers differ significantly. Furthermore, two novel procedures are applied here: factor analysis including a special transformation and a time-varying multivariate linear regression that makes it possible to determine the rank of importance of the influencing variables in respiratory hospital admissions, and also compute the relative importance of the parameters affecting respiratory disorders. Both techniques revealed that Ambrosia pollen is an important variable that influences hospital admissions (an increase of 10 pollen grains m -3 can imply an increase of around 24% in patient numbers). The role of chemical and meteorological parameters is also significant, but their weights vary according to the seasons and the methods. Clearer results are obtained for the pollination season of Ambrosia. Here, a 10 μg m -3 increase in O 3 implies a patient number response from -17% to +11%. Wind speed is a surprisingly important variable, where a 1 m s -1 rise may result in a hospital admission

  9. Chemical Pollution and Evolution of Massive Starbursts: Cleaning up the Environment in Star-Forming Galaxies

    NASA Astrophysics Data System (ADS)

    Kobulnicky, C.

    1996-12-01

    I present the results of a research program seeking to characterize the impact of massive star-clusters on the chemical and dynamical evolution of metal-poor, irregular and blue compact galaxies. The evolution of high mass stars is thought to contribute the bulk of heavy element enrichment in the interstellar medium, especially alpha -process elements like O, Si, etc. Yet, in actively star-forming galaxies, localized chemical inhomogeneities are seldom observed. Spatially-resolved optical and ultraviolet spectroscopy from the Hubble Space Telescope and ground-based observatories is used to search for chemical enrichment in the vicinity of young star clusters in nearby galaxies. VLA aperture synthesis maps are used to examine the neutral hydrogen content, dynamics, and local environment of the sample galaxies. Despite the spread in evolutionary state of the starbursts determined by the EW of Balmer emission lines and the radio continuum spectral index, few instances of localized enrichment are found. In light of these data, the ``instantaneous enrichment'' scenario for extragalactic HII regions appears less probable than one which operates on long timescales and global spatial scales. The results are consistent with the idea that starburst driven winds expel freshly synthesized metals in a hot 10(6) K phase into the halos of galaxies where they cool, condense into globules, and mix homogeneously with the rest of the galaxy on long (dynamical) timescales. The C/O and N/O ratios of the galaxies are used as new tools for measuring the recent star formation history. Implications for chemical evolution of galaxies both locally and cosmologically are developed.

  10. Scents and scents-ability: pollution disrupts chemical social recognition and shoaling in fish

    PubMed Central

    Ward, Ashley J.W; Duff, Alison J; Horsfall, Jennifer S; Currie, Suzanne

    2007-01-01

    Chemical cues are of enormous importance in mediating the behaviour of animals, enabling them to navigate throughout their habitats, to detect the presence of predators or prey and for social recognition—identifying and discriminating between conspecifics. In many species of freshwater fish, social recognition is known to be based primarily on chemical cues. Such recognition mechanisms are vulnerable to disruption by the presence of anthropogenic contaminants in the aquatic environment. Here we show that acute exposure to low, environmentally relevant dosages of the ubiquitous contaminant, 4-nonylphenol, can seriously affect social recognition and ultimately social organization in fishes. A 1 hour 0.5 μg l−1 dose was sufficient to alter the response of members of a shoaling fish species (juvenile banded killifish, Fundulus diaphanus) to conspecific chemical cues. Dosages of 1–2 μg l−1 caused killifish to orient away from dosed conspecifics, in both a flow channel and an arena. Given the overall importance of shoaling as an adaptive strategy against predators and for locating food, it is likely that its disruption by anthropogenic contaminants would have serious implications for fishes' fitness. PMID:17956844

  11. Simple, rapid zebrafish larva bioassay for assessing the potential of chemical pollutants and drugs to disrupt thyroid gland function.

    PubMed

    Raldúa, Demetrio; Babin, Patrick J

    2009-09-01

    Thyroid function may be altered by a very large number of chemicals routinely found in the environment Research evaluating potential thyroid disruption is ongoing, but there are thousands of synthetic and naturally occurring drugs and chemicals to be considered. European and United States policies call for the development of simple methodologies for screening endocrine-disrupting chemicals. Zebrafish are widely used as a model organism for assessing drug effects because of their small size, high fecundity, rapid organogenesis, morphological and physiological similarities to mammals, and easewithwhich large-scale phenotypic screening is performed. A zebrafish-based short-duration screening method was developed to detect the potential effect of chemicals and drugs on thyroid function. This method used a T4 immunofluorescence quantitative disruption test (TIQDT) to measure thyroid function. The 3 day exposure window protocol, from day 2 to day 5 postfertilization (dpf), avoided any potential side effects on thyroid gland morphogenesis. Methimazole, propylthiouracil, and potassium perchlorate, three well-known goitrogens, totally abolished T4 immunoreactivity in thyroid follicles in a dose-specific manner. Amiodarone, a human pharmaceutical with a reported cytotoxic effect on thyroid follicular cells, also decreased T4 levels. Moreover, exposure to 50 nM 3,3',5-triiodothyronine induced a significant decrease in T4 immunoreactivity as did DDT, 2,4-D, and 4-nonylphenol. In conclusion, these data indicated that TIQDT may be useful for obtaining initial information about the ability of environmental pollutants and drugs to impair thyroid gland function as well as assessing the combined effects of endocrine disruptors. PMID:19764258

  12. The sea urchin Paracentrotus lividus immunological response to chemical pollution exposure: The case of lindane.

    PubMed

    Stabili, Loredana; Pagliara, Patrizia

    2015-09-01

    In the marine environment organochlorine insecticides can be broadly detected in water, sediments, and biota. These pollutants may have major ecological consequences since they may affect marine organisms and endanger organismal growth, reproduction or survival. In this study we investigated the modification of some sea urchin immunological parameters in response to subchronic lindane (γ-HCH) exposure. Adult specimens of the sea urchin Paracentrotus lividus were exposed to two different concentrations (0.1 and 0.5 mg L(-1)) of lindane. After 24 and 48h of treatment, we examined the lindane influence on coelomocytes vitality and enumeration as well on some humoral parameters. Our results showed that the presence of the pesticide affected both cellular and humoral components of the immune system. In particular, P. lividus coelomocytes vitality did not change but a decrease of the total cell number and an increase of the red cells was recorded. Haemolytic and lysozyme-like activities as well as antibacterial activity on Vibrio alginolyticus of treated animals decreased. Sea urchin immunological competence modifications might represent a tool for monitoring disease susceptibility thus providing biological criteria for the implementation of water quality standards to protect marine organisms. PMID:25911048

  13. Potential Technology for Studying Dosimetry and Response to Airborne Chemical and Biological Pollutants

    SciTech Connect

    Timchalk, Chuck; Trease, Harold E.; Trease, Lynn L.; Minard, Kevin R.; Corley, Rick A.

    2001-06-01

    Advances in computational, and imaging techniques have enabled the rapid development of 3-dimensional (3-D) models of biological systems in unprecedented detail. Using these advances, 3-D models of the lungs and nasal passages of the rat and human are being developed to ultimately improve predictions of airborne pollutant dosimetry. Techniques for imaging the respiratory tract by magnetic resonance (MR) imaging were developed to improve the speed and accuracy of geometric data collection for mesh reconstruction. The MR imaging resolution is comparable to that obtained by manual measurements but at much greater speed and accuracy. Newly developed software (NWGrid) was utilized to translate imaging data from MR into 3-D mesh structures. Together, these approaches significantly reduced the time to develop a 3-D model. This more robust airway structure will ultimately facilitate modeling gas or vapor exchange between the respiratory tract and vasculature as well as enable linkages of dosimetry with cell response models. The 3-D, finite volume, visco-elastic mesh structures forms the geometric basis for computational fluid dynamics modeling of inhalation, exhalation and the delivery of individual particles (or concentrations of gas or vapors) to discrete regions of the respiratory tract. The ability of these 3-D models to resolve dosimetry at such a high level of detail will require new techniques to measure regional airflows and particulate deposition for model validation.

  14. Soil microcosm for testing the effects of chemical pollutants on soil fauna communities and trophic structure

    SciTech Connect

    Parmelee, R.W. . Dept. of Entomology); Wentsel, R.S.; Phillips, C.T.; Checkai, R.T. ); Simini, M. )

    1993-08-01

    A microcosm technique is presented that uses community and trophic-level analysis of soil nematodes and microarthropods to determine the effects of chemicals on soil systems. Forest soil was treated with either copper, p-nitrophenol, or trinitrotoluene. Nematodes were sorted into bacterivore, fungivore, herbivore, and omnivore-predator trophic groups, and a hatchling category. Microarthropods were sorted to the acarine suborders Prostigmata, Mesostigmata, and Oribatida; the insectan order Collembola; and a miscellaneous group. Omnivore-predator nematodes and meso-stigmatid and oribatid mites were the groups most sensitive to copper and were significantly reduced at levels as low as 100 [mu]g g[sup [minus]1] copper. Total nematode and microarthropod numbers declined above 200 [mu]g g[sup [minus]1] copper. Trophic structure analysis suggested that high sensitivity of nematode predators to intermediate levels of copper reduced predation on herbivore nematodes and resulted in greater numbers of nematodes compared to controls. p-Nitrophenol was very toxic to the nematode community, and all trophic groups were significantly reduced above 20 [mu]g g[sup [minus]1]. However, there was no effect of p-nitrophenol on microarthropods. Trinitrotoluene had no significant negative effect on total abundance of either groups of soil fauna, but oribatids were significantly reduced at 200 [mu]g g[sup [minus]1]. The results demonstrated that soil nematodes and microarthropods were sensitive indicators of environmental contaminants and that trophic-structure and community analysis has the potential to detect more subtle indirect effects of chemicals on soil food-web structure. The authors conclude that microcosms with field communities of soil microfauna offer high resolution of the ecotoxicological effects of chemicals in complex soil systems.

  15. Association of chemical constituents and pollution sources of ambient fine particulate air pollution and biomarkers of oxidative stress associated with atherosclerosis: A panel study among young adults in Beijing, China.

    PubMed

    Wu, Shaowei; Yang, Di; Wei, Hongying; Wang, Bin; Huang, Jing; Li, Hongyu; Shima, Masayuki; Deng, Furong; Guo, Xinbiao

    2015-09-01

    Ambient particulate air pollution has been associated with increased oxidative stress and atherosclerosis, but the chemical constituents and pollution sources behind the association are unclear. We investigated the associations of various chemical constituents and pollution sources of ambient fine particles (PM2.5) with biomarkers of oxidative stress in a panel of 40 healthy university students. Study participants underwent repeated blood collections for 12 times before and after relocating from a suburban campus to an urban campus with high air pollution levels in Beijing, China. Air pollution data were obtained from central air-monitoring stations, and plasma levels of oxidized low-density lipoprotein (Ox-LDL) and soluble CD36 (sCD36) were determined in the laboratory (n=464). Linear mixed-effects models were used to estimate the changes in biomarkers in association with exposure variables. PM2.5 iron and nickel were positively associated with Ox-LDL (p<0.05). For each interquartile range increase in iron (1-day, 0.51 μg/m(3)) and nickel (2-day, 2.5 ng/m(3)), there were a 1.9% [95% confidence interval (CI): 0.2%, 3.7%] increase and a 1.8% (95% CI: 0.2%, 3.4%) increase in Ox-LDL, respectively. We also found that each interquartile range increase in calcium (1-day, 0.7 μg/m(3)) was associated with a 4.8% (95% CI: 0.7%, 9.1%) increase in sCD36. Among the pollution sources, PM2.5 from traffic emissions and coal combustion were suggestively and positively associated with Ox-LDL. Our findings suggest that a subset of metals in airborne particles may be the major air pollution components that contribute to the increased oxidative stress associated with atherosclerosis. PMID:25981523

  16. Mixtures of Chemical Pollutants at European Legislation Safety Concentrations: How Safe Are They?

    PubMed Central

    Carvalho, Raquel N.; Arukwe, Augustine; Ait-Aissa, Selim; Bado-Nilles, Anne; Balzamo, Stefania; Baun, Anders; Belkin, Shimshon; Blaha, Ludek; Brion, François; Conti, Daniela; Creusot, Nicolas; Essig, Yona; Ferrero, Valentina E. V.; Flander-Putrle, Vesna; Fürhacker, Maria; Grillari-Voglauer, Regina; Hogstrand, Christer; Jonáš, Adam; Kharlyngdoh, Joubert B.; Loos, Robert; Lundebye, Anne-Katrine; Modig, Carina; Olsson, Per-Erik; Pillai, Smitha; Polak, Natasa; Potalivo, Monica; Sanchez, Wilfried; Schifferli, Andrea; Schirmer, Kristin; Sforzini, Susanna; Stürzenbaum, Stephen R.; Søfteland, Liv; Turk, Valentina; Viarengo, Aldo; Werner, Inge; Yagur-Kroll, Sharon; Zounková, Radka; Lettieri, Teresa

    2014-01-01

    The risk posed by complex chemical mixtures in the environment to wildlife and humans is increasingly debated, but has been rarely tested under environmentally relevant scenarios. To address this issue, two mixtures of 14 or 19 substances of concern (pesticides, pharmaceuticals, heavy metals, polyaromatic hydrocarbons, a surfactant, and a plasticizer), each present at its safety limit concentration imposed by the European legislation, were prepared and tested for their toxic effects. The effects of the mixtures were assessed in 35 bioassays, based on 11 organisms representing different trophic levels. A consortium of 16 laboratories was involved in performing the bioassays. The mixtures elicited quantifiable toxic effects on some of the test systems employed, including i) changes in marine microbial composition, ii) microalgae toxicity, iii) immobilization in the crustacean Daphnia magna, iv) fish embryo toxicity, v) impaired frog embryo development, and vi) increased expression on oxidative stress-linked reporter genes. Estrogenic activity close to regulatory safety limit concentrations was uncovered by receptor-binding assays. The results highlight the need of precautionary actions on the assessment of chemical mixtures even in cases where individual toxicants are present at seemingly harmless concentrations. PMID:24958932

  17. Mixtures of chemical pollutants at European legislation safety concentrations: how safe are they?

    PubMed

    Carvalho, Raquel N; Arukwe, Augustine; Ait-Aissa, Selim; Bado-Nilles, Anne; Balzamo, Stefania; Baun, Anders; Belkin, Shimshon; Blaha, Ludek; Brion, François; Conti, Daniela; Creusot, Nicolas; Essig, Yona; Ferrero, Valentina E V; Flander-Putrle, Vesna; Fürhacker, Maria; Grillari-Voglauer, Regina; Hogstrand, Christer; Jonáš, Adam; Kharlyngdoh, Joubert B; Loos, Robert; Lundebye, Anne-Katrine; Modig, Carina; Olsson, Per-Erik; Pillai, Smitha; Polak, Natasa; Potalivo, Monica; Sanchez, Wilfried; Schifferli, Andrea; Schirmer, Kristin; Sforzini, Susanna; Stürzenbaum, Stephen R; Søfteland, Liv; Turk, Valentina; Viarengo, Aldo; Werner, Inge; Yagur-Kroll, Sharon; Zounková, Radka; Lettieri, Teresa

    2014-09-01

    The risk posed by complex chemical mixtures in the environment to wildlife and humans is increasingly debated, but has been rarely tested under environmentally relevant scenarios. To address this issue, two mixtures of 14 or 19 substances of concern (pesticides, pharmaceuticals, heavy metals, polyaromatic hydrocarbons, a surfactant, and a plasticizer), each present at its safety limit concentration imposed by the European legislation, were prepared and tested for their toxic effects. The effects of the mixtures were assessed in 35 bioassays, based on 11 organisms representing different trophic levels. A consortium of 16 laboratories was involved in performing the bioassays. The mixtures elicited quantifiable toxic effects on some of the test systems employed, including i) changes in marine microbial composition, ii) microalgae toxicity, iii) immobilization in the crustacean Daphnia magna, iv) fish embryo toxicity, v) impaired frog embryo development, and vi) increased expression on oxidative stress-linked reporter genes. Estrogenic activity close to regulatory safety limit concentrations was uncovered by receptor-binding assays. The results highlight the need of precautionary actions on the assessment of chemical mixtures even in cases where individual toxicants are present at seemingly harmless concentrations. PMID:24958932

  18. Chemical characterization and sources apportionment of fine particulate pollution in a mining town of Vietnam

    NASA Astrophysics Data System (ADS)

    Hang, Nguyen Thanh; Kim Oanh, Nguyen Thi

    2014-08-01

    Monitoring for PM2.5 was conducted in a mining town in Northern Vietnam in both dry and wet seasons from 2009 to 2010. Levels and compositions of PM were characterized at two sites representing two separate air bubbles; an industrial site in Mong Duong (MD) and a reference rural site in Cam Hai (CH). Two MiniVol samplers were collocated to collect 24 h PM2.5 samples for about 30 days at each site in a season, simultaneously with meteorological data recording. All samples were analyzed for mass, black carbon (BC), water soluble ions and elements, while selected samples were also analyzed for OC (organic carbon) and EC (element carbon). Higher PM2.5 levels were observed in the dry season than the wet season at both sites in spite of abnormal rainfall occurrences observed on some days during the dry season. In both seasons, higher PM2.5 levels were observed in the industrial site than the reference rural site. The differences in PM, BC or EC and OC levels between two sites and between two seasons at one site, respectively, were all statistically significant except for that in OC between two sites, and BC between two seasons at MD. The reconstructed PM2.5 mass indicated major contributing groups being organic matter, secondary inorganic particles, crustal and soot in both seasons. Higher values of K-Smoke in the dry season suggested more contribution from biomass burning. The PMF results revealed the largest contribution to PM2.5 mass from secondary PM (35-40%); followed by biomass burning, ship and road traffic (diesel) each had a share of 15-22%; and a small contribution from miscellaneous sources such as industry and construction activities (3-8%). Analysis of HYSPLIT backward trajectory patterns showed a high potential contribution of the long range transport (LRT) pollution when air masses had long continental pathways before arriving at the study area.

  19. AMERICAN-SOVIET SYMPOSIUM ON CHEMICAL POLLUTION OF THE MARINE ENVIRONMENT (1ST) HELD AT ODESSA, USSR ON MAY 24-28, 1977

    EPA Science Inventory

    This symposium, organized under a U.S.-U.S.S.R. Environmental Agreement (Project 02.06-21), focuses on the impact of chemical pollution on the world's oceans. Soviet and American specialists discuss the fate of heavy metals in estuaries and the Gulf of Mexico; transport of natura...

  20. A HIGHWAY MODEL FOR THE ADVECTION, DIFFUSION AND CHEMICAL REACTION OF POLLUTANTS RELEASED BY AUTOMOBILES: PART I. ADVECTION AND DIFFUSION OF SF6 TRACER GAS

    EPA Science Inventory

    A two-dimensional, finite-difference model simulating a highway has been developed which is able to handle linear and nonlinear chemical reactions. Transport of the pollutants is accomplished by use of an upstream-flux-corrected algorithm developed at the Naval Research Laborator...

  1. Chemical forms and sources of extremely high nitrate and chloride in winter aerosol pollution in the Kanto Plain of Japan

    NASA Astrophysics Data System (ADS)

    Kaneyasu, Naoki; Yoshikado, Hiroshi; Mizuno, Tateki; Sakamoto, Kazuhiko; Soufuku, Masataka

    The spatial distributions, chemical forms, and potential sources have been investigated for extremely high concentrations of Cl - and NO -3 in aerosols collected during an extensive study for winter pollution episodes in the Kanto Plain of Japan. Air monitoring are conducted at 10 sites including the rooftops of skyscrapers during two measurement periods in November-December 1991. Similarity in the diurnal variation patterns of NO -3 among the sampling sites suggests that its precursor HNO 3 is formed by reactions in the atmosphere, while difference in the maximum concentration of Cl - between the sites indicates the presence of local sources. Measurements at ground level and on the rooftops of skyscrapers show that the pronounced diurnal variations of both components are phenomena occurring in the layer extending from the ground surface to at least 200 m height. Intensified measurements at two ground sites indicate that (1) NO -3 and non sea-salt Cl - are predominantly in the fine mode, (2) [NO -3] + [Cl -] and [NH +4] are in equivalence, (3) gaseous HCl, HNO 3, and NH 3 are in equilibrium with particulate NH 4Cl and NH 4NO 3. From these results, it is concluded that measured Cl - and NO -3 are predominantly in the form of NH 4Cl and NH 4NO 3, respectively. The behavior of peroxyacetyl nitrate (PAN) indicates that HNO 3, the precursor of NO -3, is produced in the photochemical reactions of the NO x-hydrocarbons system. The elevated concentration of NO 2 measured simultaneously in the pollution episodes is regarded as an alternative form of O 3 produced in photochemical reactions. As the precursor of Cl - in aerosols, sources of HCl are discussed, and the emission from incineration of domestic and industrial waste in the area is estimated.

  2. Airborne fine particulate pollution in Jinan, China: Concentrations, chemical compositions and influence on visibility impairment

    NASA Astrophysics Data System (ADS)

    Yang, Lingxiao; Zhou, Xuehua; Wang, Zhe; Zhou, Yang; Cheng, Shuhui; Xu, Pengju; Gao, Xiaomei; Nie, Wei; Wang, Xinfeng; Wang, Wenxing

    2012-08-01

    Daily PM2.5 samples were collected simultaneously at an urban site (SD) and a rural site (MP) in Jinan, China from March 2006 to February 2007. The samples were analyzed for major inorganic and organic water-soluble ions, 24 elements and carbonaceous species to determine the spatial and temporal variations of PM2.5 mass concentrations and chemical compositions and evaluate their contributions to visibility impairment. The annual average concentrations of PM2.5 were 148.71 μg m-3 and 97.59 μg m-3 at SD and MP, respectively. The predominant component of PM2.5 was (NH4)2SO4 at SD and organic mass at MP, which accounted for 28.71% and 37.25% of the total mass, respectively. The higher SOR (sulfur oxidation ratio) and ratios of OC/EC at SD indicated that the formation of secondary inorganic ions and secondary organic aerosols (SOA) could be accelerated in the urban area. Large size (NH4)2SO4 and large size organic mass were the most important contributors to visibility impairment at SD and MP, accounting for 43.80% and 41.02% of the light extinction coefficient, respectively.

  3. The Dart estuary, Devon, UK: a case study of chemical dynamics and pollutant mobility

    NASA Astrophysics Data System (ADS)

    Schuwerack, P.-M. M.; Neal, M.; Neal, C.

    2007-01-01

    Water, sediments and gill and digestive gland tissues of adult common shore crab (Carcinus maenas), collected at Noss Marina, Sandquay (Britannia Royal Naval College), the Dartmouth Pier, Warfleet Cove and Sugary Cove in the Dart estuary, Devon, UK, were analysed for major, minor and trace elements in spring 2004. Total acid-available measurements analysed included the truly dissolved component and acid-available sediments. Trace metal concentrations are associated largely with particulate and micro-particulate/colloidal phases, the latter being able to pass through standard filter papers. Wide ranges of chemical concentrations were found in the water, sediments and tissues at all the locations. In the water column, 48% of the variance is linked to the sea-salt component (Cl, Na, K, Ca, Mg, B, Li and Sr) and the sediment-associated acid-available fractions are linked to Fe-rich lithogenous materials (Ba, Co, Cu, Fe, Mn, V and Zn). In the sediments, trace elements of Cd, Co, Cr, Fe, Pb, Mn, Ni and V are correlated with the sea salts and associated with the fraction of fine sediments within the total sediment. In the gills and the digestive gland tissues of crabs, high concentrations of Al, Cu and Fe are found and there are correlations between acid-available trace metals of Cu, Cr, Fe, Mn, Ni, Sr and Zn. The relationships between trace metal contaminants, their site-specific concentrations, their temporal and spatial variability and the effects of human activities, such as moorland/agriculture with historic mining and recreational activities in the lower Dart estuary, are discussed.

  4. Toxicological investigation and evaluation of drinking-water pollution caused by chemical wastes

    SciTech Connect

    Desi, I.; Somosi, G.

    1984-08-01

    Acute, subacute, in vitro, and animal experiments were performed in the spring and fall of 1981. In the course of these investigations, samples from bank-filtered drinking-water wells of Vac, a town along the Danube; from three neighboring observation wells; from water transported from the opposite side of the Danube; from a drinking-water well of a town farther northward; and from Danube water were examined. The aim of the study was to detect whether any of the water samples became contaminated by toxic chemicals. The drinking-water samples of the wells in Vac (Nos. 1-5) proved to be contaminated, and toxic effects of different degrees were also induced by other wells of Vac. The Danube water caused changes in some tests only; the control drinking-water well, the samples of the K3 observation well, and of the well on the opposite side of the Danube examined in the fall only did not cause any alterations. The toxicity was confirmed by the elevated hemolysis by the genotoxic effects on human erythrocytes and leukocytes, by the functional changes observed in the nervous system of rats, by alterations detected in the electric activity of the rats brains, in the learning ability and the behavior of the rats, by the increase in the cytochrome P-450 enzyme level of the liver, and by the chromosome aberrations emerging in mice. The changes were caused by different compounds of low and high boiling points escaping with water vapor or with organic solvents. On the basis of the investigations, the water proved to be inappropriate for human consumption.

  5. Assessment of full-scale biological nutrient removal systems upgraded with physico-chemical processes for the removal of emerging pollutants present in wastewaters from Mexico.

    PubMed

    Estrada-Arriaga, Edson Baltazar; Cortés-Muñoz, Juana Enriqueta; González-Herrera, Arturo; Calderón-Mólgora, César Guillermo; de Lourdes Rivera-Huerta, Ma; Ramírez-Camperos, Esperanza; Montellano-Palacios, Leticia; Gelover-Santiago, Silvia Lucila; Pérez-Castrejón, Sara; Cardoso-Vigueros, Lina; Martín-Domínguez, Alejandra; García-Sánchez, Liliana

    2016-11-15

    Two full-scale biological nutrient removal systems upgraded with three physico-chemical processes (coagulation, chemical precipitation, and neutral Fenton) were evaluated in order to determine the removal of emerging pollutants (EPs) present in municipal wastewater from Mexico. Between 41 and 55 EPs were detected in the influents of two wastewater treatment plants (WWTPs), including personal care products (PPCPs), antibiotics, analgesics, antiepileptics, antilipidemics, antihypertensives, antiseptics, stimulants, and hormones. Emerging pollutants were detected at concentrations ranging from 0.69ng/L to 94,600ng/L. High concentrations of emerging pollutants were found during dry season. WWTP 1, integrated by oxidation ditches and UV light lamps, showed removal efficiencies of EPs between 20% and 22%. On the other hand, WWTP 2 consisted of anaerobic/anoxic/aerobic tanks coupled with two disinfection processes; chlorine dioxide and UV light lamps, for which the removal of EPs was significant (up to 80%). The concentrations of emerging pollutants in WWTP 1 effluent was found within a rangepollutants in the effluent were below 210ng/L. WWTP 2 showed high emerging pollutant removals, compared to those of WWTP 1, due to a greater activity of the simultaneous nitrification-denitrification processes, hydraulic retention time, and solids retention time. The compounds that were more persistent with removals below 50% in both effluents were: carbamazepine, dehydronifedipine, meprobamate, sertraline, propranolol, propoxyphene, norverapamil, diazepam, alprazolam, sulfamethoxazole, metoprolol, ofloxacin, norfloxacin, fluoxetine, erythromycin-H2O, diphenhydramine, dehydronifedipine, clarithromycin, hydrochlorothiazide, and albuterol. The application of neutral Fenton reaction as post-treatment for the two effluents from the WWTPs is promising for the removal of emerging pollutants (up to 100

  6. Design of Laser Based Monitoring Systems for Compliance Management of Odorous and Hazardous Air Pollutants in Selected Chemical Industrial Estates at Hyderabad, India

    NASA Astrophysics Data System (ADS)

    Sudhakar, P.; Kalavathi, P.; Ramakrishna Rao, D.; Satyanarayna, M.

    2014-12-01

    Industrialization can no longer sustain without internalization of the concerns of the receiving environment and land-use. Increased awareness and public pressure, coupled with regulatory instruments and bodies exert constant pressure on industries to control their emissions to a level acceptable to the receiving environment. However, when a group of industries come-up together as an industrial estate, the cumulative impacts of all the industries together often challenges the expected/desired quality of receiving environment, requiring stringent pollution control and monitoring measures. Laser remote sensing techniques provide powerful tools for environmental monitoring. These methods provide range resolved measurements of concentrations of various gaseous pollutants and suspended particulate matter (SPM) not only in the path of the beam but over the entire area. A three dimensional mapping of the pollutants and their dispersal can be estimated using the laser remote sensing methods on a continuous basis. Laser Radar (Lidar) systems are the measurements technology used in the laser remote sensing methods. Differential absorption lidar (DIAL) and Raman Lidar technologies have proved to be very useful for remote sensing of air pollutants. DIAL and Raman lidar systems can be applied for range resolved measurements of molecules like SO2, NO2, O3 Hg, CO, C2H4, H2O, CH4, hydrocarbons etc. in real time on a continuous basis. This paper describes the design details of the DAIL and Raman lidar techniques for measurement of various hazardous air pollutants which are being released into the atmosphere by the chemical industries operating in the Bachupally industrial Estate area at Hyderabad, India. The relative merits of the two techniques have been studied and the minimum concentration of pollutants that can be measured using these systems are presented. A dispersion model of the air pollutants in the selected chemical industrial estates at Hyderabad has been developed.

  7. The Effects of Chronic Lifelong Activation of the AHR Pathway by Industrial Chemical Pollutants on Female Human Reproduction

    PubMed Central

    Vacca, Margherita; Nardelli, Claudia; Castegna, Alessandra; Arnesano, Fabio; Carella, Nicola; Depalo, Raffaella

    2016-01-01

    Environmental chemicals, such as heavy metals, affect female reproductive function. A biological sensor of the signals of many toxic chemical compounds seems to be the aryl hydrocarbon receptor (AHR). Previous studies demonstrated the environmental of heavy metals in Taranto city (Italy), an area that has been influenced by anthropogenic factors such as industrial activities and waste treatments since 1986. However, the impact of these elements on female fertility in this geographic area has never been analyzed. Thus, in the present study, we evaluated the AHR pathway, sex steroid receptor pattern and apoptotic process in granulosa cells (GCs) retrieved from 30 women, born and living in Taranto, and 30 women who are living in non-contaminated areas (control group), who were undergoing in vitro fertilization (IVF) protocol. In follicular fluids (FFs) of both groups the toxic and essential heavy metals, such as chromiun (Cr), Manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), cadmium (Cd) and lead (Pb), were also analyzed. Higher levels of Cr, Fe, Zn and Pb were found in the FFs of the women from Taranto as compared to the control group, as were the levels of AHR and AHR-dependent cytochrome P450 1A1 and 1B1; while CYP19A1 expression was decreased. The anti-apoptotic process found in the GCs of women fromTaranto was associated with the highest levels of progesterone receptor membrane component 1 (PGRMC1), a novel progesterone receptor, the expression of which is subjected to AHR activated by its highest affinity ligands (e.g., dioxins) or indirectly by other environmental pollutants, such as heavy metals. In conclusion, decreased production of estradiol and decreased number of retrieved mature oocytes found in women from Taranto could be due to chronic exposure to heavy metals, in particular to Cr and Pb. PMID:27008165

  8. Influence of chemical and biological factors on trophic transfer of persistent organic pollutants in the northwater polynya marine food web.

    PubMed

    Fisk, A T; Hobson, K A; Norstrom, R J

    2001-02-15

    Persistent organic pollutants (POPs) and stable isotopes of nitrogen (delta 15N) were measured in zooplankton (6 species), a benthic invertebrate (Anonyx nugax), Arctic cod (Boreogadus saida), seabirds (6 species), and ringed seals (Phoca hispida) collected in 1998 in the Northwater Polynya to examine effects of biological and chemical factors on trophic transfer of POPs in an Arctic marine food web. Strong positive relationships were found between recalcitrant POP concentrations (lipid corrected) and trophic level based on stable isotopes of nitrogen, providing clear evidence of POP biomagnification in Arctic marine food webs. Food web magnification factors (FWMFs), derived from the slope of the POP--trophic level relationship, provided an overall magnification factor for the food web but over and underestimated biomagnification factors (BMFs) based on predator--prey concentrations in poikilotherms (fish) and homeotherms (seabirds and mammals), respectively. Greater biomagnification in homeotherms was attributed to their greater energy requirement and subsequent feeding rates. Within the homeotherms, seabirds had greater BMFs than ringed seals, consistent with greater energy demands in birds. Scavenging from marine mammal carcasses and accumulation in more contaminated winter habitats were considered important variables in seabird BMFs. Metabolic differences between species resulted in lower than expected BMFs, which would not be recognized in whole food web trophic level--POP relationships. The use of sigma POP groups, such as sigma PCB, is problematic because FWMFs and BMFs varied considerably between individual POPs. FWMFs of recalcitrant POPs had a strong positive relationship with log octanol--water partition coefficient (Kow). Results of this study show the utility of using delta 15N to characterize trophic level and trophic transfer of POPs but highlight the effects of species and chemical differences on trophic transfer of POPs that can be overlooked when

  9. [Pollution status of phenolic compounds in the soil and sediment from a chemical industrial park along the Yangtze River].

    PubMed

    Chen, Jiexia; Wei, Enze; Xian, Qiming

    2014-08-01

    A determination method of 12 phenolic compounds in soil and sediment samples by gas chromatography-mass spectrometry (GC-MS) analysis coupled with accelerated solvent extraction (ASE) and gel permeation chromatography (GPC) for clean-up was developed. The method detection limits (MDLs) varied from 0. 410 μg/kg to 13. 1 μg/kg (dry weight), and the average recoveries ranged from 70. 7% to 122% with the relative standard deviations (RSDs) of 1. 2% to 16%. Based on this method, the levels of 12 phenolic compounds were investigated in 17 soil surrounding a chemical industrial park along the Yangtze River and seven sediment samples collected in the river. It was found that 11 of the 12 phenolic compounds were detected in all of the 24 samples, and only hydroquinone was below the MDL. The contents of the total 12 phenolic compounds were 10. 16-30. 66 mg/kg in the soil and 18. 00-29. 83 mg/kg in the sediment, with the average contents of 18. 26 and 22. 51 mg/kg respectively. It showed that 4-nitro- phenol, 4-chloro-3-methylphenol, 2-chlorohydroquinone, 2-methyl-4,6-dinitrophenol and 2,4,6- trichlorophenol were five major phenolic contaminants in the soil and sediment in this study. The pollution levels of the 12 phenolic compounds were low in the soil of the chemical industrial park as well as in the sediment of the Yangtze River, which implied a comparatively low risk for the environment. PMID:25434120

  10. Development of microbial and chemical MST tools to identify the origin of the faecal pollution in bathing and shellfish harvesting waters in France.

    PubMed

    Gourmelon, M; Caprais, M P; Mieszkin, S; Marti, R; Wéry, N; Jardé, E; Derrien, M; Jadas-Hécart, A; Communal, P Y; Jaffrezic, A; Pourcher, A M

    2010-09-01

    The microbiological quality of coastal or river waters can be affected by faecal pollution from human or animal sources. An efficient MST (Microbial Source Tracking) toolbox consisting of several host-specific markers would therefore be valuable for identifying the origin of the faecal pollution in the environment and thus for effective resource management and remediation. In this multidisciplinary study, after having tested some MST markers on faecal samples, we compared a selection of 17 parameters corresponding to chemical (steroid ratios, caffeine, and synthetic compounds), bacterial (host-specific Bacteroidales, Lactobacillus amylovorus and Bifidobacterium adolescentis) and viral (genotypes I-IV of F-specific bacteriophages, FRNAPH) markers on environmental water samples (n = 33; wastewater, runoff and river waters) with variable Escherichia coli concentrations. Eleven microbial and chemical parameters were finally chosen for our MST toolbox, based on their specificity for particular pollution sources represented by our samples and their detection in river waters impacted by human or animal pollution; these were: the human-specific chemical compounds caffeine, TCEP (tri(2-chloroethyl)phosphate) and benzophenone; the ratios of sitostanol/coprostanol and coprostanol/(coprostanol+24-ethylcopstanol); real-time PCR (Polymerase Chain Reaction) human-specific (HF183 and B. adolescentis), pig-specific (Pig-2-Bac and L. amylovorus) and ruminant-specific (Rum-2-Bac) markers; and human FRNAPH genogroup II. PMID:20709349

  11. Simulating the transport and chemical evolution of biomass burning pollutants originating from Southeast Asia during 7-SEAS/2010 Dongsha experiment

    NASA Astrophysics Data System (ADS)

    Chuang, Ming-Tung; Fu, Joshua S.; Lin, Neng-Huei; Lee, Chung-Te; Gao, Yang; Wang, Sheng-Hsiang; Sheu, Guey-Rong; Hsiao, Ta-Chih; Wang, Jia-Lin; Yen, Ming-Cheng; Lin, Tang-Huang; Thongboonchoo, Narisara; Chen, Wei-Chen

    2015-07-01

    This study aimed to simulate the transport of biomass burning (BB) aerosol originating from Southeast Asia (SEA) during the Dongsha Experiment conducted from March 2010 to April 2010. Transport pathways were reanalyzed and steering flow in the mid-latitude areas and anticyclones in low-latitude areas were found to control the transport of BB plume after it was injected to a high atmosphere. For the 12 simulated and observed events at Mt. Lulin (2862 m MSL; 23°28‧07″ N, 120°52‧25″ E), the 72 h backward trajectories were all tracked back to southern China and northern Indochina, which were the locations of the largest BB fire activities in SEA. Chemical evolutions of BB pollutants along the moving trajectories showed that organic matter was always the dominant component in PM2.5, consistent with the observations at both near-source regions and Mt. Lulin. For nitrogen species, nearly all NOx molecules oxidized into HNO3, NO3-, PAN, and PANX in fires or near fires. The synchronic consumption of NOx, SO2, and NH3 explained the production of the major components of inorganic salts. In the moving BB plume, sulfate concentration increased with decreased nitrate concentration. Ratios of ammonium to PM2.5 and elemental carbon to PM2.5 remained nearly constant because additional sources were lacking.

  12. An ionic liquid tolerant cellulase derived from chemically polluted microhabitats and its application in in situ saccharification of rice straw.

    PubMed

    Xu, Jiaxing; He, Bingfang; Wu, Bin; Wang, Bin; Wang, Chenghua; Hu, Lei

    2014-04-01

    A cellulase-producing fungus was isolated from chemically polluted microhabitats by [Amim][Cl] enrichment and identified as Aspergillus fumigatus. The maximum activity of the cellulase in 30% (v/v) ionic liquids (ILs) was detected in [Emim][DMP], [Amim][Cl] and [Emim][MA] as 127%, 111% and 109%, respectively, of its activity in buffer, suggesting its superior performance in high concentration ILs. Strikingly, although its initial activity varied in each IL, its half-life was longer in most ILs than in buffer, evidence of a high conformational stability of the enzyme that is essential for maintaining the remaining activity in relevant media. It noteworthy that 1-3M NaCl can activate the cellulase somewhat. More gratifyingly, a compatible IL-cellulase system based on the cellulase was developed, and its use significantly improved the saccharification rate of rice straw from 53% to 88% versus the control, demonstrating its potential for efficient transformation of lignocellulose to glucose in a single-step process. PMID:24549238

  13. Large scale air pollution estimation method combining land use regression and chemical transport modeling in a geostatistical framework.

    PubMed

    Akita, Yasuyuki; Baldasano, Jose M; Beelen, Rob; Cirach, Marta; de Hoogh, Kees; Hoek, Gerard; Nieuwenhuijsen, Mark; Serre, Marc L; de Nazelle, Audrey

    2014-04-15

    In recognition that intraurban exposure gradients may be as large as between-city variations, recent air pollution epidemiologic studies have become increasingly interested in capturing within-city exposure gradients. In addition, because of the rapidly accumulating health data, recent studies also need to handle large study populations distributed over large geographic domains. Even though several modeling approaches have been introduced, a consistent modeling framework capturing within-city exposure variability and applicable to large geographic domains is still missing. To address these needs, we proposed a modeling framework based on the Bayesian Maximum Entropy method that integrates monitoring data and outputs from existing air quality models based on Land Use Regression (LUR) and Chemical Transport Models (CTM). The framework was applied to estimate the yearly average NO2 concentrations over the region of Catalunya in Spain. By jointly accounting for the global scale variability in the concentration from the output of CTM and the intraurban scale variability through LUR model output, the proposed framework outperformed more conventional approaches. PMID:24621302

  14. Chemical dynamics of acidity and heavy metals in a mine water-polluted soil during decontamination using clean water.

    PubMed

    Chen, A; Lin, C; Lu, W; Ma, Y; Bai, Y; Chen, H; Li, J

    2010-03-15

    A column leaching experiment was conducted to investigate the chemical dynamics of the percolating water and washed soil during decontamination of an acidic mine water-polluted soil. The results show that leaching of the contaminated soil with clean water rapidly reduced soluble acidity and ion concentrations in the soils. However, only <20% of the total actual acidity in the soil column was eliminated after 30 leaching cycles. It is likely that the stored acidity continues to be released to the percolating water over a long period of time. During the column leaching, dissolved Cu and Pb were rapidly leached out, followed by mobilization of colloidal Cu and Pb from the exchangeable and the oxide-bound fractions as a result of reduced ionic strength in the soil solution. The soluble Fe contained in the soil was rare, probably because the soil pH was not sufficiently low; marked mobility of colloidal Fe took place after the ionic strength of the percolating water was weakened and the mobilized Fe was mainly derived from iron oxides. In contrast with Cu, Pb and Fe, the concentration of leachate Zn and Mn showed a continuously decreasing trend during the entire period of the experiment. PMID:19913356

  15. Organic and inorganic amendment application on mercury-polluted soils: effects on soil chemical and biochemical properties.

    PubMed

    García-Sánchez, Mercedes; Klouza, Martin; Holečková, Zlata; Tlustoš, Pavel; Száková, Jiřina

    2016-07-01

    On the basis of a previous study performed in our laboratory, the use of organic and inorganic amendments can significantly modify the Hg mobility in soil. We have compared the effectiveness of organic and inorganic amendments such as digestate and fly ash, respectively, reducing the Hg mobility in Chernozem and Luvisol soils differing in their physicochemical properties. Hence, the aim of this work was to compare the impact of digestate and fly ash application on the chemical and biochemical parameters in these two mercury-contaminated soils in a model batch experiment. Chernozem and Luvisol soils were artificially contaminated with Hg and then incubated under controlled conditions for 21 days. Digestate and fly ash were applied to both soils in a dose of 10 and 1.5 %, respectively, and soil samples were collected after 1, 7, 14, and 21 days of incubation. The presence of Hg in both soils negatively affected to processes such as nitrification, provoked a decline in the soil microbial biomass C (soil microbial biomass C (MBC)), and the microbial activities (arylsulfatase, and β-glucosaminidase) in both soils. Meanwhile, the digestate addition to Chernozem and Luvisol soils contaminated with Hg improved the soil chemical properties (pH, dissolved organic carbon (DOC), N (Ntot), inorganic-N forms (N-NH4 (+) and N-NO3 (-))), as consequence of high content in C and N contained in digestate. Likewise, the soil MBC and soil microbial activities (dehydrogenase, arylsulfatase, and β-glucosaminidase) were greatly enhanced by the digestate application in both soils. In contrast, fly ash application did not have a remarkable positive effect when compared to digestate in Chernozem and Luvisol soil contaminated with mercury. These results may indicate that the use of organic amendments such as digestate considerably improved the soil health in Chernozem and Luvisol compared with fly ash, alleviating the detrimental impact of Hg. Probably, the chemical properties present in

  16. Chemical constituents of ambient particulate air pollution and biomarkers of inflammation, coagulation and homocysteine in healthy adults: A prospective panel study

    PubMed Central

    2012-01-01

    Background Ambient air pollution has been associated with activation of systemic inflammation and hypercoagulability and increased plasma homocysteine, but the chemical constituents behind the association are not well understood. We examined the relations of various chemical constituents of fine particles (PM2.5) and biomarkers of inflammation, coagulation and homocysteine in the context of traffic-related air pollution. Methods A panel of 40 healthy college students underwent biweekly blood collection for 12 times before and after their relocation from a suburban campus to an urban campus with changing air pollution contents in Beijing. Blood samples were measured for circulatory biomarkers of high-sensitivity C reactive protein (hs-CRP), tumor necrosis factor alpha (TNF-α), fibrinogen, plasminogen activator inhibitor type 1 (PAI-1), tissue-type plasminogen activator (t-PA), von Willebrand factor (vWF), soluble platelet selectin (sP-selectin), and total homocysteine (tHcy). Various air pollutants were measured in a central air-monitoring station in each campus and 32 PM2.5 chemical constituents were determined in the laboratory. We used three different mixed-effects models (single-constituent model, constituent-PM2.5 joint model and constituent residual model) controlling for potential confounders to estimate the effects of PM2.5 chemical constituents on circulatory biomarkers. Results We found consistent positive associations between the following biomarkers and PM2.5 chemical constituents across different models: TNF-α with secondary organic carbon, chloride, zinc, molybdenum and stannum; fibrinogen with magnesium, iron, titanium, cobalt and cadmium; PAI-1 with titanium, cobalt and manganese; t-PA with cadmium and selenium; vWF with aluminum. We also found consistent inverse associations of vWF with nitrate, chloride and sodium, and sP-selectin with manganese. Two positive associations of zinc with TNF-α and of cobalt with fibrinogen, and two inverse

  17. Association between particulate matter and its chemical constituents of urban air pollution and daily mortality or morbidity in Beijing City.

    PubMed

    Li, Pei; Xin, Jinyuan; Wang, Yuesi; Li, Guoxing; Pan, Xiaochuan; Wang, Shigong; Cheng, Mengtian; Wen, Tianxue; Wang, Guangcheng; Liu, Zirui

    2015-01-01

    Recent time series studies have indicated that daily mortality and morbidity are associated with particulate matters. However, about the relative effects and its seasonal patterns of fine particulate matter constituents is particularly limited in developing Asian countries. In this study, we examined the role of particulate matters and its key chemical components of fine particles on both mortality and morbidity in Beijing. We applied several overdispersed Poisson generalized nonlinear models, adjusting for time, day of week, holiday, temperature, and relative humidity, to investigate the association between risk of mortality or morbidity and particulate matters and its constituents in Beijing, China, for January 2005 through December 2009. Particles and several constituents were associated with multiple mortality or morbidity categories, especially on respiratory health. For a 3-day lag, the nonaccident mortality increased by 1.52, 0.19, 1.03, 0.56, 0.42, and 0.32% for particulate matter (PM)2.5, PM10, K(+), SO4(2-), Ca(2+), and NO3(-) based on interquartile ranges of 36.00, 64.00, 0.41, 8.75, 1.43, and 2.24 μg/m(3), respectively. The estimates of short-term effects for PM2.5 and its components in the cold season were 1 ~ 6 times higher than that in the full year on these health outcomes. Most of components had stronger adverse effects on human health in the heavy PM2.5 mass concentrations, especially for K(+), NO3(-), and SO4(2-). This analysis added to the growing body of evidence linking PM2.5 with mortality or morbidity and indicated that excess risks may vary among specific PM2.5 components. Combustion-related products, traffic sources, vegetative burning, and crustal component and resuspended road dust may play a key role in the associations between air pollution and public health in Beijing. PMID:25074829

  18. The Influence of Intense Chemical Pollution on the Community Composition, Diversity and Abundance of Anammox Bacteria in the Jiaojiang Estuary (China)

    PubMed Central

    Hu, Baolan; Shen, Lidong; Du, Ping; Zheng, Ping; Xu, Xiangyang; Zeng, Jiangning

    2012-01-01

    Continuous chemical pollution is one of the most serious environmental problems in the Jiaojiang Estuary of the East Sea (China). This chemical pollution has significantly changed the estuarine environmental conditions and may have profoundly influenced the distribution of anammox bacterial communities in this estuary. Here, we investigated the influence of chemical pollution on the community composition, diversity and abundance of anammox bacteria in Jiaojiang estuarine sediments. Phylogenetic analysis of 16S rRNA genes showed that the majority of anammox bacterial sequences retrieved from the estuarine intertidal sediments were associated with Kuenenia. In contrast, different anammox communities composed of Brocadia, Kuenenia, Scalindua and Jettenia were found in the estuarine subtidal sediments. Redundancy analysis (RDA) indicated that the sediment nitrobenzene and organic content had significant impacts on the distribution of anammox communities in the intertidal sediments. Pearson correlation analysis showed that the diversity of anammox bacteria in the intertidal sediments was positively correlated with the organic content. In contrast, RDA results showed that the nitrobenzene content, NO3− concentration and salinity significantly influenced the distribution of anammox communities in the subtidal sediments. The diversity and relative abundance of anammox bacteria in the subtidal sediments were positively correlated with NO3− concentration. PMID:22470481

  19. The variation of chemical characteristics of PM2.5 and PM10 and formation causes during two haze pollution events in urban Beijing, China

    NASA Astrophysics Data System (ADS)

    Gao, Jiajia; Tian, Hezhong; Cheng, Ke; Lu, Long; Zheng, Mei; Wang, Shuxiao; Hao, Jiming; Wang, Kun; Hua, Shenbing; Zhu, Chuanyong; Wang, Yong

    2015-04-01

    Airborne particles in urban Beijing during haze days and normal days were collected and analyzed in the autumn and winter seasons to reveal the chemical characteristics variations of air pollution. The air quality in haze days was substantially worse than that in normal days. Both the relatively low wind speed and high relative humidity were in favor of the accumulation of pollution species and new formation of secondary PM2.5 in the atmosphere. Elevated concentrations of elements and water-soluble inorganic ions were found on haze days for both PM10 and PM2.5. Particularly, the crustal element, such as Fe, in both PM10 and PM2.5 were substantially higher in autumn normal days and winter haze days than those in autumn haze days and winter normal days, indicating that the abundance of Fe in autumn haze days mainly be originated from crustal dust while in winter haze days it might be primarily emitted from anthropogenic sources (iron and steel smelting) instead of road dust. Secondary ion species (SO42-, NO3-, NH4+) in particles were generated much more during haze episodes, and contributed a higher proportion in PM2.5 than in PM10 during the two sampling periods. Moreover, HYSPLIT model was used to explain the possible transport of airborne particles from distant sources. By comparing with south-type trajectory, west-type trajectory entrained larger amounts of primary crustal pollutants, while, south-type trajectory was comprised of a higher mass of anthropogenic pollution species. The results of back trajectory analysis indicated that the elevated concentration of aerosol and its chemical components during haze days might be caused by the integrated effects of accumulation under stagnant meteorological condition and the transport emissions of pollutants from anthropogenic sources surrounding Beijing city.

  20. Variation of particle number size distributions and chemical compositions at the urban and downwind regional sites in the Pearl River Delta during summertime pollution episodes

    NASA Astrophysics Data System (ADS)

    Yue, D. L.; Hu, M.; Wu, Z. J.; Guo, S.; Wen, M. T.; Nowak, A.; Wehner, B.; Wiedensohler, A.; Takegawa, N.; Kondo, Y.; Wang, X. S.; Li, Y. P.; Zeng, L. M.; Zhang, Y. H.

    2010-10-01

    In order to characterize the features of particulate pollution in the Pearl River Delta (PRD) in the summer, continuous measurements of particle number size distributions and chemical compositions were simultaneously performed at Guangzhou urban site (GZ) and Back-garden downwind regional site (BG) in July 2006. Particle number concentration from 20 nm to 10 μm at BG was (1.7±0.8)×104 cm-3, about 40% lower than that at GZ, (2.9±1.1)×104 cm-3. The total particle volume concentration at BG was 94±34 μm3 cm-3, similar to that at GZ, 96±43 μm3 cm-3. More 20-100 nm particles, significantly affected by the traffic emissions, were observed at GZ, while 100-660 nm particle number concentrations were similar at both sites as they are more regional. PM2.5 values were similar at GZ (69±43 μg m-3) and BG (69±58 μg m-3) with R2 of 0.71 for the daily average PM2.5 at these two sites, indicating the fine particulate pollution in the PRD region to be regional. Two kinds of pollution episodes, the accumulation pollution episode and the regional transport pollution episode, were observed. Fine particles over 100 nm dominated both number and volume concentrations of total particles during the late periods of these pollution episodes. Accumulation and secondary transformation are the main reasons for the nighttime accumulation pollution episode. SO42-, NO3- accounted for about 60% in 100-660 nm particle mass and PM2.5 increase. When south or southeast wind prevailed in the PRD region, regional transport of pollutants took place. Regional transport contributed about 30% to fine particulate pollution at BG during a regional transport case. Secondary transformation played an important role during regional transport, causing higher increase rates of secondary ions in PM1.0 than other species and shifting the peaks of sulfate and ammonium mass size distributions to larger sizes. SO42-, NO3-, and NH4+ accounted for about 70% and 40% of PM1.0 and PM2.5, respectively.

  1. Variation of particle number size distributions and chemical compositions at the urban and downwind regional sites in the Pearl River Delta during summertime pollution episodes

    NASA Astrophysics Data System (ADS)

    Yue, D. L.; Hu, M.; Wu, Z. J.; Guo, S.; Wen, M. T.; Nowak, A.; Wehner, B.; Wiedensohler, A.; Takegawa, N.; Kondo, Y.; Wang, X. S.; Li, Y. P.; Zeng, L. M.; Zhang, Y. H.

    2010-06-01

    In order to characterize the features of particulate pollution in the Pearl River Delta (PRD) in the summer, continuous measurements of particle number size distributions and chemical compositions were simultaneously performed at Guangzhou urban site (GZ) and Back-garden downwind regional site (BG) in July 2006. Particle number concentration from 20 nm to 10 μm at BG was (1.7±0.8)×104 cm-3, about 40% lower than that at GZ, (2.9±1.1)×104 cm-3 with intensive traffic emissions. The total particle volume concentration at BG was 94±34 μm3 cm-3, similar to that at GZ, 96±43 μm3 cm-3. More 20-100 nm particles, significantly affected by the traffic emissions, were observed at GZ, while 100-660 nm particle number concentrations were similar at both sites as they are more regional. PM2.5 values were also similar at GZ (69±43 μg m-3) and BG (69±58 μg m-3), indicating the fine particulate pollution in the PRD region to be regional. Two kinds of pollution episodes, the accumulation pollution episode and the regional transport pollution episode, were observed. Fine particles over 100 nm dominated both number and volume concentrations of total particles during the late periods of these pollution episodes. Accumulation and secondary transformations are two main reasons for the nighttime accumulation pollution episode. SO4-2, NO3-, and NH4+ accounted for about 60% in 100-660 nm particle mass and PM2.5. When south or south-southeast wind prevailed in the PRD region, regional transport of pollutants takes place. Regional transport contributed about 30% to fine particulate pollution at BG during a regional transport case. Secondary transformation played an important role during regional transport, causing higher increase rates of secondary ions in PM1.0 than other species and shifting the peaks of sulfate and ammonium mass size distributions to larger sizes. SO4-2, NO3-, and NH4+ accounted for about 70% and 40% of PM1.0 and PM2.5, respectively.

  2. [On the problem of the study of the chemical air pollution with chlororganic hydrocarbons at productions of polyvinyl chloride and epichlorohydrin].

    PubMed

    Taranenko, N A; Meshakova, N M; Zhurba, O M; Telezhkin, V V

    2014-01-01

    Hygienic assessment of working conditions at the chemical productions of polyvinyl chloride (PVC) and epichlorohydrin (EPCH) in East Siberia has shown that the employees are exposed to the chlororganic hydrocarbons of hazard category 1-2, out of them there were found to be more toxical pollutants such as vinyl chloride, 1.2-dicloroethane in the production of polyvinyl chloride; allyl chloride and epichlorohydrin in the production of epichlorohydrin. Multistageness of the technological processes, the absence of the isolation of main stages of the technological processes as well as the heating microclimate contribute to the chemical pollution of the air environment. In spite of the significant improvement of the hygienic situation at the productions mentioned in the recent 10 years according to the chemical factor due to the introduction of the complex of curative measures, the working conditions of the employees still belonged to the harmful category. According to the content of the harmful chemical substances in the air of the working zone and the parameters of microclimate, the working conditions of the employees working at the production of epichlorohydrin and in the shop of vinyl chloride production must be qualified as the harmful ones of the first category of the hazard and danger (Class 3.1), in the production shop for PVC- as the harmful ones which correspond to the second category of the hazard and danger (Class 3.2). PMID:25842495

  3. CHEMICALS IN PROGRESS BULLETIN

    EPA Science Inventory

    Chemicals in Progress Bulletin is a quarterly newsletter which highlights regulatory and program activities of the Office of Pollution Prevention and Toxics. Regular features and news items include the existing chemicals program, new chemicals program, pollution prevention activi...

  4. Atmospheric deposition of selected chemicals and their effect on nonpoint-source pollution in the Twin Cities Metropolitan Area, Minnesota

    USGS Publications Warehouse

    Brown, R.G.

    1984-01-01

    The atmospheric contribution to nonpoint-source-runoff pollution of nitrogen, in the form of nitrite-plus-nitrate, and lead was extremely high contributing as much as 84 percent of the runoff load. In contrast, phosphorus and chloride inputs were low averaging of 6 percent of the total runoff load. Future investigations of nonpoint-source pollution in runoff might include collection of data on atmospheric deposition of nitrite-plus-nitrate nitrogen and lead because of the importance of that source of these constituents in runoff.

  5. Coupling chemical oxidation and biostimulation: Effects on the natural attenuation capacity and resilience of the native microbial community in alkylbenzene-polluted soil.

    PubMed

    Martínez-Pascual, Eulàlia; Grotenhuis, Tim; Solanas, Anna M; Viñas, Marc

    2015-12-30

    Coupling chemical oxidation with bioremediation could be a cost-effective system to cope with soil and groundwater pollution. However, the effects of chemical oxidation on autochthonous microbial communities are scarcely known. A detailed analysis that considers both the efficiency of the two technologies and the response of the microbial communities was performed on a linear alkylbenzene-polluted soil and groundwater samples. The impacts of a modified Fenton's reaction (MFR) at various dosages and of permanganate on the microbiota over 4 weeks were assessed. The permanganate and MFR negatively affected microbial abundance and activity. However, the resilience of certain microbial populations was observed, with a final increase in potential hydrocarbon-degrading populations as determined by both the alkB gene abundance and the predominance of well-known hydrocarbon-degrading phylotypes such as Rhodococcus, Ochrobactrum, Acinetobacter and Cupriavidus genera as determined by 16S rRNA-based DGGE fingerprinting. The assessment of the chemical oxidant impact on autochthonous microbiota should be considered for the optimization of coupled field remediation technologies. PMID:26177489

  6. Emission inventory of primary pollutants and chemical speciation in 2010 for the Yangtze River Delta region, China

    NASA Astrophysics Data System (ADS)

    Fu, Xiao; Wang, Shuxiao; Zhao, Bin; Xing, Jia; Cheng, Zhen; Liu, Huan; Hao, Jiming

    2013-05-01

    We developed a high-resolution emission inventory of primary air pollutants for Yangtze River Delta (YRD) region, which included Shanghai plus 24 cities in the provinces of Jiangsu and Zhejiang. The emissions of SO2, NOX, PM10, PM2.5, NMVOCs and NH3 in the year of 2010 were estimated as 2147 kt, 2776 kt, 1006 kt, 643 kt, 3822 kt and 1439 kt, respectively. Power plants are the largest emission sources for SO2 and NOX, which contributes 44.1% and 37.3% of total SO2 and NOX emissions. Emissions from industrial process accounted for 26.9%, 28.9% and 33.7% of the total PM10, PM2.5 and NMVOCs respectively. Besides, 37.3% of NMVOCs emissions were contributed by solvent use. Livestock and fertilizer application contribute over 90% of NH3 emissions. High emission densities are visible in Shanghai and the area around Tai Lake. This emission inventory includes the speciation of PM2.5 for the YRD region for the first time, which is important to source apportionment and secondary-pollution analysis. In 2010, emissions of three major PM2.5 species, namely OC, EC and sulfate, are 136.9 kt, 75.0 kt and 76.2 kt, respectively. Aromatics and alkanes are the main NMVOC species, accounting for 30.4% and 20.3% of total VOCs. Non-road transportation and biomass burning were main uncertain sources because of a lack of proper activity and emission factor data. Compared with other pollutants, NMVOCs and NH3 have higher uncertainty. From 2000 to 2010, emissions of all pollutants have changed significantly, suggesting that the newly updated and high-resolution emission inventory will be useful for the identification of air pollution sources in YRD.

  7. Strategic of Applying Free Chemical Usage In Purified Water System For Pharmaceutical Industry Toward CPOB (Cara Pembuatan Obat yang Baik) Indonesia To Reducing Environmental Pollution

    NASA Astrophysics Data System (ADS)

    Kartono, R.; Basuki, Y. T.

    2014-03-01

    The purpose of this paper is to examine the sets of model and literature review to prove that strategy of applying free chemical usage in purified water system for pharmaceutical industry would be help the existing and new pharmaceutical companies to comply with part of Natioanal Agency of Drug and Food Control / Badan Pengawas Obat dan Makanan (NADFC/BPOM) regulation in order to achieve "Cara Pembuatan Obat yang Baik" (CPOB) of Indonesia pharmaceutical industry. One of the main reasons is when we figured out the number of Indonesian pharmaceutical industries in 2012 are kept reducing compare to the increasing numbers of Indonesian population growth. This strategy concept also might help the industries to reducing environmental pollution, and operational cost in pharmaceutical industries, by reducing of the chemical usage for water treatment process in floculation and cougulation and chlorination for sterillization. This new model is free usage of chemicals for purified water generation system process and sterilization. The concept offering of using membrane technology- Reverse Osmosis (RO) membrane base treatment to replace traditional chemical base treatment, following enhance Electrodeionization (EDI) as final polisher for controlling conductivity, and finally Ultra Violet (UV) disinfectant technology as final guard for bacteria controls instead of chemical base system in purified water generation system.

  8. Weather elements, chemical air pollutants and airborne pollen influencing asthma emergency room visits in Szeged, Hungary: performance of two objective weather classifications

    NASA Astrophysics Data System (ADS)

    Makra, László; Puskás, János; Matyasovszky, István; Csépe, Zoltán; Lelovics, Enikő; Bálint, Beatrix; Tusnády, Gábor

    2015-09-01

    Weather classification approaches may be useful tools in modelling the occurrence of respiratory diseases. The aim of the study is to compare the performance of an objectively defined weather classification and the Spatial Synoptic Classification (SSC) in classifying emergency department (ED) visits for acute asthma depending from weather, air pollutants, and airborne pollen variables for Szeged, Hungary, for the 9-year period 1999-2007. The research is performed for three different pollen-related periods of the year and the annual data set. According to age and gender, nine patient categories, eight meteorological variables, seven chemical air pollutants, and two pollen categories were used. In general, partly dry and cold air and partly warm and humid air aggravate substantially the symptoms of asthmatics. Our major findings are consistent with this establishment. Namely, for the objectively defined weather types favourable conditions for asthma ER visits occur when an anticyclonic ridge weather situation happens with near extreme temperature and humidity parameters. Accordingly, the SSC weather types facilitate aggravating asthmatic conditions if warm or cool weather occur with high humidity in both cases. Favourable conditions for asthma attacks are confirmed in the extreme seasons when atmospheric stability contributes to enrichment of air pollutants. The total efficiency of the two classification approaches is similar in spite of the fact that the methodology for derivation of the individual types within the two classification approaches is completely different.

  9. Weather elements, chemical air pollutants and airborne pollen influencing asthma emergency room visits in Szeged, Hungary: performance of two objective weather classifications.

    PubMed

    Makra, László; Puskás, János; Matyasovszky, István; Csépe, Zoltán; Lelovics, Enikő; Bálint, Beatrix; Tusnády, Gábor

    2015-09-01

    Weather classification approaches may be useful tools in modelling the occurrence of respiratory diseases. The aim of the study is to compare the performance of an objectively defined weather classification and the Spatial Synoptic Classification (SSC) in classifying emergency department (ED) visits for acute asthma depending from weather, air pollutants, and airborne pollen variables for Szeged, Hungary, for the 9-year period 1999-2007. The research is performed for three different pollen-related periods of the year and the annual data set. According to age and gender, nine patient categories, eight meteorological variables, seven chemical air pollutants, and two pollen categories were used. In general, partly dry and cold air and partly warm and humid air aggravate substantially the symptoms of asthmatics. Our major findings are consistent with this establishment. Namely, for the objectively defined weather types favourable conditions for asthma ER visits occur when an anticyclonic ridge weather situation happens with near extreme temperature and humidity parameters. Accordingly, the SSC weather types facilitate aggravating asthmatic conditions if warm or cool weather occur with high humidity in both cases. Favourable conditions for asthma attacks are confirmed in the extreme seasons when atmospheric stability contributes to enrichment of air pollutants. The total efficiency of the two classification approaches is similar in spite of the fact that the methodology for derivation of the individual types within the two classification approaches is completely different. PMID:25504051

  10. Exploitation of deep-sea resources: the urgent need to understand the role of high pressure in the toxicity of chemical pollutants to deep-sea organisms.

    PubMed

    Mestre, Nélia C; Calado, Ricardo; Soares, Amadeu M V M

    2014-02-01

    The advent of industrial activities in the deep sea will inevitably expose deep-sea organisms to potentially toxic compounds. Although international regulations require environmental risk assessment prior to exploitation activities, toxicity tests remain focused on shallow-water model species. Moreover, current tests overlook potential synergies that may arise from the interaction of chemicals with natural stressors, such as the high pressures prevailing in the deep sea. As pressure affects chemical reactions and the physiology of marine organisms, it will certainly affect the toxicity of pollutants arising from the exploitation of deep-sea resources. We emphasize the need for environmental risk assessments based on information generated from ecotoxicological trials that mimic, as close as possible, the deep-sea environment, with emphasis to a key environmental factor - high hydrostatic pressure. PMID:24230462

  11. Climatic, biological, and land cover controls on the exchange of gas-phase semivolatile chemical pollutants between forest canopies and the atmosphere.

    PubMed

    Nizzetto, Luca; Perlinger, Judith A

    2012-03-01

    An ecophysiological model of a structured broadleaved forest canopy was coupled to a chemical fate model of the air-canopy exchange of gaseous semivolatile chemicals to dynamically assess the short-term (hours) and medium term (days to season) air-canopy exchange and the influence of biological, climatic, and land cover drivers on the dynamics of the air-canopy exchange and on the canopy storage for airborne semivolatile pollutants. The chemical fate model accounts for effects of short-term variations in air temperature, wind speed, stomatal opening, and leaf energy balance, all as a function of layer in the canopy. Simulations showed the potential occurrence of intense short/medium term re-emission of pollutants having log K(OA) up to 10.7 from the canopy as a result of environmental forcing. In addition, relatively small interannual variations in seasonally averaged air temperature, canopy biomass, and precipitation can produce relevant changes in the canopy storage capacity for the chemicals. It was estimated that possible climate change related variability in environmental parameters (e.g., an increase of 2 °C in seasonally averaged air temperature in combination with a 10% reduction in canopy biomass due to, e.g., disturbance or acclimatization) may cause a reduction in canopy storage capacity of up to 15-25%, favoring re-emission and potential for long-range atmospheric transport. On the other hand, an increase of 300% in yearly precipitation can increase canopy sequestration by 2-7% for the less hydrophobic compounds. PMID:22304464

  12. Pollution evaluation in the Shahrood River: Do physico-chemical and macroinvertebrate-based indices indicate same responses to anthropogenic activities?

    PubMed

    Sharifinia, Moslem; Mahmoudifard, Abbas; Imanpour Namin, Javid; Ramezanpour, Zohreh; Yap, Chee Kong

    2016-09-01

    This study evaluates the impact of anthropogenic activities on the Shahrood River using water physico-chemical variables and macroinvertebrates data sets obtained over a period of 12 months between February 2012 and February 2013 at 8 sampling sites. Biotic indices i.e. FBI and BMWP based on macroinvertebrates and physico-chemical indices (MPI, HPI and NSF-WQI) were employed to evaluate the water quality status in connection with natural- and human-induced pressures. Based on physico-chemical indices, water quality was categorized as low polluted level and it is suitable for drinking purposes. The water quality based on biotic indices was related to the anthropic activities; a clear deterioration of the water quality was observed from upstream to downstream sites. The water quality along the river changed from very good (class I; reference sites) to good (class II; midstream sites) and turned into moderate (class III) and poor (class IV) quality (downstream sites). These findings indicate that biotic indices are more powerful indicators in assessing water quality than physico-chemical indices. Allocapnia, Glossosoma and Hesperoperla were exclusively related to least disturbed sites, and Naididae, Orthocladiinae and Ecdyonurus were found in sites showing notable degradation. Our results recommended that the use of macroinvertebrates could be employed as a cost-effective tool for biomonitoring and controlling of polluted riverine ecosystems in the Middle East. Finally, the results from this study may be useful not only for developing countries, but also for any organization struggling to use macroinvertebrate based indices with restricted financial resources and knowledge. PMID:27343865

  13. Temperature-dependent toxicities of four common chemical pollutants to the marine medaka fish, copepod and rotifer.

    PubMed

    Li, Adela J; Leung, Priscilla T Y; Bao, Vivien W W; Yi, Andy X L; Leung, Kenneth M Y

    2014-10-01

    We hypothesize that chemical toxicity to marine ectotherms is the lowest at an optimum temperature (OT) and it exacerbates with increasing or decreasing temperature from the OT. This study aimed to verify this hypothetical temperature-dependent chemical toxicity (TDCT) model through laboratory experiments. Acute toxicity over a range of temperatures was tested on four commonly used chemicals to three marine ectotherms. Our results confirmed that toxicities, in terms of 96-h LC50 (median lethal concentration; for the marine medaka fish Oryzias melastigma and the copepod Tigriopus japonicus) and 24-h LC50 (for the rotifer Brachionus koreanus), were highly temperature-dependent, and varied between test species and between study chemicals. The LC50 value of the fish peaked at 20 °C for copper (II) sulphate pentahydrate and triphenyltin chloride, and at 25 °C for dichlorophenyltrichloroethane and copper pyrithione, and decreased with temperature increase or decrease from the peak (i.e., OT). However, LC50 values of the copepod and the rotifer generally showed a negative relationship with temperature across all test chemicals. Both copepod and rotifer entered dormancy at the lowest temperature of 4 °C. Such metabolic depression responses in these zooplanktons could reduce their uptake of the chemical and hence minimize the chemical toxicity at low temperatures. Our TDCT model is supported by the fish data only, whereas a simple linear model fits better to the zooplankton data. Such species-specific TDCT patterns may be jointly ascribed to temperature-mediated changes in (1) the physiological response and susceptibility of the marine ectotherms to the chemical, (2) speciation and bioavailability of the chemical, and (3) toxicokinetics of the chemical in the organisms. PMID:25098775

  14. The pH-dependent long-term stability of an amorphous manganese oxide in smelter-polluted soils: implication for chemical stabilization of metals and metalloids.

    PubMed

    Ettler, Vojtěch; Tomášová, Zdeňka; Komárek, Michael; Mihaljevič, Martin; Šebek, Ondřej; Michálková, Zuzana

    2015-04-01

    An amorphous manganese oxide (AMO) and a Pb smelter-polluted agricultural soil amended with the AMO and incubated for 2 and 6 months were subjected to a pH-static leaching procedure (pH 3-8) to verify the chemical stabilization effect on metals and metalloids. The AMO stability in pure water was pH-dependent with the highest Mn release at pH 3 (47% dissolved) and the lowest at pH 8 (0.14% dissolved). Secondary rhodochrosite (MnCO3) was formed at the AMO surfaces at pH>5. The AMO dissolved significantly less after 6 months of incubation. Sequential extraction analysis indicated that "labile" fraction of As, Pb and Sb in soil significantly decreased after AMO amendment. The pH-static experiments indicated that no effect on leaching was observed for Cd and Zn after AMO treatments, whereas the leaching of As, Cu, Pb and Sb decreased down to 20%, 35%, 7% and 11% of the control, respectively. The remediation efficiency was more pronounced under acidic conditions and the time of incubation generally led to increased retention of the targeted contaminants. The AMO was found to be a promising agent for the chemical stabilization of polluted soils. PMID:25600581

  15. Evaluation of ELISA kits followed by liquid chromatography-atmospheric pressure chemical ionization-mass spectrometry for the determination of organic pollutants in industrial effluents

    SciTech Connect

    Castillo, M.; Oubina, A.; Barcelo, D.

    1998-07-15

    Contaminated industrial effluents often contain a variety of organic pollutants which are difficult to analyze by standard GC-MS methods since they often miss the more polar or nonvolatile of these organic compounds. The identification of highly polar analytes by chemical or rapid biological techniques is needed for characterization of the effluents. The present work evaluates the use of enzyme linked immunosorbent assays (ELISA) kits for determining pentachlorophenol, carcinogenic PAHs and BTEX (benzene, toluene, ethylbenzene, and o-, m-, and p-xylene) among the organic analytes present in various industrial effluents from Europe. The analytical protocol applied for the evaluation of the kits was based on the use of ELISA followed by solid-phase extraction (SPE) for the preconcentration of a variety of organic pollutants such as pentachlorophenol, phthalates, and nonylphenol and final determination with LC-MS characterization using an atmospheric pressure chemical ionization (APCI) interface in the positive and negative ionization modes. The developed protocol permitted the unequivocal identification of target analytes such as pentachlorophenol, nonylphenol, dibutylphthalate, dimethylphthalate, bis(2-ethylhexyl)phthalate 2-methylbenzenesulfonamide, and 2,2-dimethylbenzene-sulfonamide present in industrial effluents. The advantages and limitations of the three RaPID-magnetic particle-based ELISA kits applied to the characterization of industrial effluents are also reported.

  16. A synthetic method for atmospheric diffusion simulation and environmental impact assessment of accidental pollution in the chemical industry in a WEBGIS context.

    PubMed

    Ni, Haochen; Rui, Yikang; Wang, Jiechen; Cheng, Liang

    2014-09-01

    The chemical industry poses a potential security risk to factory personnel and neighboring residents. In order to mitigate prospective damage, a synthetic method must be developed for an emergency response. With the development of environmental numeric simulation models, model integration methods, and modern information technology, many Decision Support Systems (DSSs) have been established. However, existing systems still have limitations, in terms of synthetic simulation and network interoperation. In order to resolve these limitations, the matured simulation model for chemical accidents was integrated into the WEB Geographic Information System (WEBGIS) platform. The complete workflow of the emergency response, including raw data (meteorology information, and accident information) management, numeric simulation of different kinds of accidents, environmental impact assessments, and representation of the simulation results were achieved. This allowed comprehensive and real-time simulation of acute accidents in the chemical industry. The main contribution of this paper is that an organizational mechanism of the model set, based on the accident type and pollutant substance; a scheduling mechanism for the parallel processing of multi-accident-type, multi-accident-substance, and multi-simulation-model; and finally a presentation method for scalar and vector data on the web browser on the integration of a WEB Geographic Information System (WEBGIS) platform. The outcomes demonstrated that this method could provide effective support for deciding emergency responses of acute chemical accidents. PMID:25198686

  17. A Synthetic Method for Atmospheric Diffusion Simulation and Environmental Impact Assessment of Accidental Pollution in the Chemical Industry in a WEBGIS Context

    PubMed Central

    Ni, Haochen; Rui, Yikang; Wang, Jiechen; Cheng, Liang

    2014-01-01

    The chemical industry poses a potential security risk to factory personnel and neighboring residents. In order to mitigate prospective damage, a synthetic method must be developed for an emergency response. With the development of environmental numeric simulation models, model integration methods, and modern information technology, many Decision Support Systems (DSSs) have been established. However, existing systems still have limitations, in terms of synthetic simulation and network interoperation. In order to resolve these limitations, the matured simulation model for chemical accidents was integrated into the WEB Geographic Information System (WEBGIS) platform. The complete workflow of the emergency response, including raw data (meteorology information, and accident information) management, numeric simulation of different kinds of accidents, environmental impact assessments, and representation of the simulation results were achieved. This allowed comprehensive and real-time simulation of acute accidents in the chemical industry. The main contribution of this paper is that an organizational mechanism of the model set, based on the accident type and pollutant substance; a scheduling mechanism for the parallel processing of multi-accident-type, multi-accident-substance, and multi-simulation-model; and finally a presentation method for scalar and vector data on the web browser on the integration of a WEB Geographic Information System (WEBGIS) platform. The outcomes demonstrated that this method could provide effective support for deciding emergency responses of acute chemical accidents. PMID:25198686

  18. Decision-tree-model identification of nitrate pollution activities in groundwater: A combination of a dual isotope approach and chemical ions

    NASA Astrophysics Data System (ADS)

    Xue, Dongmei; Pang, Fengmei; Meng, Fanqiao; Wang, Zhongliang; Wu, Wenliang

    2015-09-01

    To develop management practices for agricultural crops to protect against NO3- contamination in groundwater, dominant pollution activities require reliable classification. In this study, we (1) classified potential NO3- pollution activities via an unsupervised learning algorithm based on δ15N- and δ18O-NO3- and physico-chemical properties of groundwater at 55 sampling locations; and (2) determined which water quality parameters could be used to identify the sources of NO3- contamination via a decision tree model. When a combination of δ15N-, δ18O-NO3- and physico-chemical properties of groundwater was used as an input for the k-means clustering algorithm, it allowed for a reliable clustering of the 55 sampling locations into 4 corresponding agricultural activities: well irrigated agriculture (28 sampling locations), sewage irrigated agriculture (16 sampling locations), a combination of sewage irrigated agriculture, farm and industry (5 sampling locations) and a combination of well irrigated agriculture and farm (6 sampling locations). A decision tree model with 97.5% classification success was developed based on SO42 - and Cl- variables. The NO3- and the δ15N- and δ18O-NO3- variables demonstrated limitation in developing a decision tree model as multiple N sources and fractionation processes both resulted in difficulties of discriminating NO3- concentrations and isotopic values. Although only the SO42 - and Cl- were selected as important discriminating variables, concentration data alone could not identify the specific NO3- sources responsible for groundwater contamination. This is a result of comprehensive analysis. To further reduce NO3- contamination, an integrated approach should be set-up by combining N and O isotopes of NO3- with land-uses and physico-chemical properties, especially in areas with complex agricultural activities.

  19. Decision-tree-model identification of nitrate pollution activities in groundwater: A combination of a dual isotope approach and chemical ions.

    PubMed

    Xue, Dongmei; Pang, Fengmei; Meng, Fanqiao; Wang, Zhongliang; Wu, Wenliang

    2015-09-01

    To develop management practices for agricultural crops to protect against NO3(-) contamination in groundwater, dominant pollution activities require reliable classification. In this study, we (1) classified potential NO3(-) pollution activities via an unsupervised learning algorithm based on δ(15)N- and δ(18)O-NO3(-) and physico-chemical properties of groundwater at 55 sampling locations; and (2) determined which water quality parameters could be used to identify the sources of NO3(-) contamination via a decision tree model. When a combination of δ(15)N-, δ(18)O-NO3(-) and physico-chemical properties of groundwater was used as an input for the k-means clustering algorithm, it allowed for a reliable clustering of the 55 sampling locations into 4 corresponding agricultural activities: well irrigated agriculture (28 sampling locations), sewage irrigated agriculture (16 sampling locations), a combination of sewage irrigated agriculture, farm and industry (5 sampling locations) and a combination of well irrigated agriculture and farm (6 sampling locations). A decision tree model with 97.5% classification success was developed based on SO4(2-) and Cl(-) variables. The NO3(-) and the δ(15)N- and δ(18)O-NO3(-) variables demonstrated limitation in developing a decision tree model as multiple N sources and fractionation processes both resulted in difficulties of discriminating NO3(-) concentrations and isotopic values. Although only the SO4(2-) and Cl(-) were selected as important discriminating variables, concentration data alone could not identify the specific NO3(-) sources responsible for groundwater contamination. This is a result of comprehensive analysis. To further reduce NO3(-) contamination, an integrated approach should be set-up by combining N and O isotopes of NO3(-) with land-uses and physico-chemical properties, especially in areas with complex agricultural activities. PMID:26231989

  20. Environmental parameters of the Tennessee River in Alabama. 2: Physical, chemical, and biological parameters. [biological and chemical effects of thermal pollution from nuclear power plants on water quality

    NASA Technical Reports Server (NTRS)

    Rosing, L. M.

    1976-01-01

    Physical, chemical and biological water quality data from five sites in the Tennessee River, two in Guntersville Reservoir and three in Wheeler Reservoir were correlated with climatological data for three annual cycles. Two of the annual cycles are for the years prior to the Browns Ferry Nuclear Power Plant operations and one is for the first 14 months of Plant operations. A comparison of the results of the annual cycles indicates that two distinct physical conditions in the reservoirs occur, one during the warm months when the reservoirs are at capacity and one during the colder winter months when the reservoirs have been drawn-down for water storage during the rainy months and for weed control. The wide variations of physical and chemical parameters to which the biological organisms are subjected on an annual basis control the biological organisms and their population levels. A comparison of the parameters of the site below the Power plant indicates that the heated effluent from the plant operating with two of the three reactors has not had any effect on the organisms at this site. Recommendations given include the development of prediction mathematical models (statistical analysis) for the physical and chemical parameters under specific climatological conditions which affect biological organisms. Tabulated data of chemical analysis of water and organism populations studied is given.

  1. Remote measurement of pollution

    NASA Technical Reports Server (NTRS)

    1971-01-01

    A summary of the major conclusions and recommendations developed by the panels on gaseous air pollution, water pollution, and particulate air pollution is presented. It becomes evident that many of the trace gases are amenable to remote sensing; that certain water pollutants can be measured by remote techniques, but their number is limited; and that a similar approach to the remote measurement of specific particulate pollutants will follow only after understanding of their physical, chemical, and radiative properties is improved. It is also clear that remote sensing can provide essential information in all three categories that can not be obtained by any other means.

  2. Bioaccumulation Potential Of Air Contaminants: Combining Biological Allometry, Chemical Equilibrium And Mass-Balances To Predict Accumulation Of Air Pollutants In Various Mammals

    SciTech Connect

    Veltman, Karin; McKone, Thomas E.; Huijbregts, Mark A.J.; Hendriks, A. Jan

    2009-03-01

    In the present study we develop and test a uniform model intended for single compartment analysis in the context of human and environmental risk assessment of airborne contaminants. The new aspects of the model are the integration of biological allometry with fugacity-based mass-balance theory to describe exchange of contaminants with air. The developed model is applicable to various mammalian species and a range of chemicals, while requiring few and typically well-known input parameters, such as the adult mass and composition of the species, and the octanol-water and air-water partition coefficient of the chemical. Accumulation of organic chemicals is typically considered to be a function of the chemical affinity forlipid components in tissues. Here, we use a generic description of chemical affinity for neutral and polar lipids and proteins to estimate blood-air partition coefficients (Kba) and tissue-air partition coefficients (Kta) for various mammals. This provides a more accurate prediction of blood-air partition coefficients, as proteins make up a large fraction of total blood components. The results show that 75percent of the modeled inhalation and exhalation rate constants are within a factor of 2 from independent empirical values for humans, rats and mice, and 87percent of the predicted blood-air partition coefficients are within a factor of 5 from empirical data. At steady-state, the bioaccumulation potential of air pollutants is shown to be mainly a function of the tissue-air partition coefficient and the biotransformation capacity of the species and depends weakly on the ventilation rate and the cardiac output of mammals.

  3. Chemical mechanisms of photocatalytic de-soiling and de-polluting processes in indoor environments and urban surfaces

    NASA Astrophysics Data System (ADS)

    Sleiman, M.; Rosseler, O.; Montesinos, N.; Litter, M.; Bikiel, D.; Kirchstetter, T.; Bluhm, H.; Ahmed, M.; Salmeron, M.; Destaillats, H.

    2013-12-01

    Photocatalysis has been postulated as a promising approach for the de-pollution of indoor air and urban atmospheres, and for self-cleaning surfaces. Building materials and coatings containing nano-sized TiO2 photocatalytic functionalities are gaining market share, including self-cleaning building envelope materials (coatings, mortar, plaster, architectural fabrics and tiles) and indoor air purifiers. While many studies have reported good performance of photocatalysis in the removal of organic pollutants from indoor air, more information is needed to understand secondary emissions of potentially harmful byproducts from photocatalytic air cleaners. This presentation will describe analytical methods and experimental results from room-sized chamber experiments using a realistic challenge VOC mixture at low ppb levels. We will also present results from separate studies that used synchrotron-based surface spectroscopic and mass spectrometric methods to better understand the photocatalytic mechanisms that regulate the de-soiling and de-polluting activity. Two photocatalytic processes were studied: de-noxification (NOx removal) and de-soiling (removal of deposited black carbon or soot). Ambient pressure XPS was used to study surface and gas-phase species formed during adsorption of NO2 on TiO2 and subsequent UV irradiation at λ = 365 nm. The results illustrate how NOx chemistry on TiO2 surfaces can be affected by the presence of water vapor, heteroatoms present as impurities, and carbonaceous soiling. The reactivity of NOx and NO3- on surfaces leads to reduced adsorbed and gas-phase nitrogenated species. These processes need to be considered in the engineering of depolluting materials and incorporated into atmospheric models. De-soiling properties were investigated by analyzing soot oxidation on TiO2 surfaces. Model soot samples were used as surrogates of urban grime. Using laser desorption coupled with time-of-flight (TOF) mass spectrometry synchrotron ionization, we

  4. Pollution biomonitoring in the Bizerte lagoon (Tunisia), using combined chemical and biomarker analyses in grass goby, Zosterisessor ophiocephalus (Teleostei, Gobiidae).

    PubMed

    Barhoumi, Badreddine; Clérandeau, Christelle; Gourves, Pierre-Yves; Le Menach, Karyn; El Megdiche, Yassine; Peluhet, Laurent; Budzinski, Hélène; Baudrimont, Magalie; Driss, Mohamed Ridha; Cachot, Jérôme

    2014-10-01

    In this study, biological responses and contaminant levels in biological tissues were investigated in grass goby fish specimens (Zosterisessor ophiocephalus) collected from five stations in a moderately polluted ecosystem, namely the Bizerte lagoon on the north coast of Tunisia. The following biomarkers were measured: muscular acetylcholinesterase (AChE), hepatic ethoxyresorufin-O-deethylase (EROD), glutathione-S-transferase (GST), catalase (CAT), lipoperoxidation (TBARS), condition factor (CF), and hepatosomatic index (HSI). These measurements were taken in parallel with the content of Organochlorine pesticides (OCPs), Polychlorinated biphenyls (PCBs), Polycyclic aromatic hydrocarbons (PAHs) and trace metals (As, Cr, Cu, Mn, Pb, V, Zn, Ag, Cd, Co and Ni) in muscle tissue. Total PAH concentrations ranged from 20.09 ± 0.68 to 105.77 ± 42.58 ng g(-1) dw, PCB from 33.19 ± 6.25 to 126.28 ± 7.37 ng g(-1) dw, OCP from 11.26 ± 1.62 to 19.17 ± 2.06 ng g(-1) dw, and metals from 107.83 ± 1.83 to 187.21 ± 2.00 mg/kg dw. The highest levels of pollutants and biomarkers were observed at station S1, located in the Bizerte channel. Elevated EROD, GST and CAT activities, as well as TBARS levels in liver were positively correlated with tissue contaminant levels at station S1. Significant negative correlations were also found between hexachlorobenzene (HCB) and dichlorodiphenyltrichloroethane (DDTs) body burden with AChE activity in muscle at station S2. The integration of biological responses and contaminant tissue content indicated that certain areas of the Bizerte lagoon, notably station S1, are significantly impacted by various human activities, which likely represent a threat for aquatic wildlife. On the basis of these results, and due to its ecological characteristics, the grass goby appears a suitable indicator species for pollution biomonitoring in coastal marine areas along the Mediterranean Sea. PMID:25106667

  5. Early warning signs of endocrine disruption in adult fish from the ingestion of polyethylene with and without sorbed chemical pollutants from the marine environment.

    PubMed

    Rochman, Chelsea M; Kurobe, Tomofumi; Flores, Ida; Teh, Swee J

    2014-09-15

    Plastic debris is associated with several chemical pollutants known to disrupt the functioning of the endocrine system. To determine if the exposure to plastic debris and associated chemicals promotes endocrine-disrupting effects in fish, we conducted a chronic two-month dietary exposure using Japanese medaka (Oryzias latipes) and environmentally relevant concentrations of microplastic (<1mm) and associated chemicals. We exposed fish to three treatments: a no-plastic (i.e. negative control), virgin-plastic (i.e. virgin polyethylene pre-production pellets) and marine-plastic treatment (i.e. polyethylene pellets deployed in San Diego Bay, CA for 3 months). Altered gene expression was observed in male fish exposed to the marine-plastic treatment, whereas altered gene expression was observed in female fish exposed to both the marine- and virgin-plastic treatment. Significant down-regulation of choriogenin (Chg H) gene expression was observed in males and significant down-regulation of vitellogenin (Vtg I), Chg H and the estrogen receptor (ERα) gene expression was observed in females. In addition, histological observation revealed abnormal proliferation of germ cells in one male fish from the marine-plastic treatment. Overall, our study suggests that the ingestion of plastic debris at environmentally relevant concentrations may alter endocrine system function in adult fish and warrants further research. PMID:24995635

  6. Large-eddy simulation of pollutant dispersion from a ground-level area source over urban street canyons with irreversible chemical reactions

    NASA Astrophysics Data System (ADS)

    Du, T. Z.; Liu, C.-H.; Zhao, Y. B.

    2014-10-01

    In this study, the dispersion of chemically reactive pollutants is calculated by large-eddy simulation (LES) in a neutrally stratified urban canopy layer (UCL) over urban areas. As a pilot attempt, idealized street canyons of unity building-height-to-street-width (aspect) ratio are used. Nitric oxide (NO) is emitted from the ground surface of the first street canyon into the domain doped with ozone (O3). In the absence of ultraviolet radiation, this irreversible chemistry produces nitrogen dioxide (NO2), developing a reactive plume over the rough urban surface. A range of timescales of turbulence and chemistry are utilized to examine the mechanism of turbulent mixing and chemical reactions in the UCL. The Damköhler number (Da) and the reaction rate (r) are analyzed along the vertical direction on the plane normal to the prevailing flow at 10 m after the source. The maximum reaction rate peaks at an elevation where Damköhler number Da is equal or close to unity. Hence, comparable timescales of turbulence and reaction could enhance the chemical reactions in the plume.

  7. Composition and effects of inhalable size fractions of atmospheric aerosols in the polluted atmosphere: part I. PAHs, PCBs and OCPs and the matrix chemical composition.

    PubMed

    Landlová, Linda; Cupr, Pavel; Franců, Juraj; Klánová, Jana; Lammel, Gerhard

    2014-05-01

    Atmospheric particulate matter (PM) abundance, mass size distribution (MSD) and chemical composition are parameters relevant for human health effects. The MSD and phase state of semivolatile organic pollutants were determined at various polluted sites in addition to the PM composition and MSD. The distribution pattern of pollutants varied from side to side in correspondence to main particle sources and PM composition. Levels of particle-associated polycyclic aromatic hydrocarbons (PAHs) were 1-30 ng m(-3) (corresponding to 15-35 % of the total, i.e., gas and particulate phase concentrations), of polychlorinated biphenyls (PCBs) were 2-11 pg m(-3) (4-26 % of the total) and of DDT compounds were 2-12 pg m(-3) (4-23 % of the total). The PM associated amounts of other organochlorine pesticides were too low for quantification. The organics were preferentially found associated with particles <0.45 μm of aerodynamic equivalent diameter. The mass fractions associated with sub-micrometer particles (PM0.95) were 73-90 %, 34-71 % and 36-81 % for PAHs, PCBs and DDT compounds, respectively. The finest particles fraction had the highest aerosol surface concentration (6.3-29.7)×10(-6) cm(-1) (44-70 % of the surface concentration of all size fractions). The data set was used to test gas-particle partitioning models for semivolatile organics for the first time in terms of the organics' MSD and size-dependent PM composition. The results of this study prove that at the various sites particles with diverse size, matrix composition, amount of contaminants and toxicological effects occur. Legislative regulation based on gravimetric determination of PM mass can clearly be insufficient for assessment. PMID:24488522

  8. COMPUTER AIDED CHEMICAL PROCESS DESIGN METHODOLOGIES FOR POLLUTION REDUCTION(SYSTEMS ANALYSIS BRANCH, SUSTAINABLE TECHNOLOGY DIVISION, NRMRL)

    EPA Science Inventory

    The objective of the project is to develop computer optimization and simulation methodologies for the design of economical chemical manufacturing processes with a minimum of impact on the environment. The computer simulation and optimization tools developed in this project can be...

  9. The role of acoustic screens in distribution of technogenic magnetic particles and chemical pollution in roadside soil

    NASA Astrophysics Data System (ADS)

    Wawer, Małgorzata; Magiera, Tadeusz; Szuszkiewicz, Marcin

    2015-04-01

    Roads constructed nowadays should by all means be functional for their motorized users but at the same time their effect on the environment ought to be limited to the minimum. Despite the existence of various methods for preventing from negative influence of roads on the environment, there is still lack of adequate techniques to monitor and reduce the spreading of roadside pollution in the air and soils. The aim of the study was to assess the influence of acoustic screens on spreading and deposition of solid pollutants deriving from car emissions, based on their quantitative and qualitative analysis. During this study, measurements of magnetic susceptibility and analyses of heavy metals as well as Pt and Rh contents in soil and plant samples (Taraxacum officinale, Plantago major, Parthenocissus quinquefolia) collected near different kinds of acoustic screens ("green walls", Plexiglass, sawdust concrete, steel panels and earth embankments) have been done. Previous investigations showed showed that most of traffic emission is deposited in the close vicinity of the roads (up to 10 m) and the level of contamination decreased with increasing distance from the road edge. However, the results of this project indicate that, in the area where the acoustic screens are located, this distribution is disturbed and the additional enrichment of heavy metals in soil about 10 - 15 m behind screens is observed. Spatial distribution of heavy metal contents in soil samples corresponds to its magnetic susceptibility values. High contents of Fe, Zn, Mn and Pb was observed next to acoustic screens made of sawdust concrete and steel panels. Additionally, concentration of Zn in soil samples collected close to these screens exceeded threshold value. Analyses of plants showed that the highest content of examined elements and highest values of magnetic susceptibility were recorded near road edge. What is more, samples of Parthenocissus quinquefolia collected at height 0.2 m were characterized

  10. Accuracy of different sensors for the estimation of pollutant concentrations (total suspended solids, total and dissolved chemical oxygen demand) in wastewater and stormwater.

    PubMed

    Lepot, Mathieu; Aubin, Jean-Baptiste; Bertrand-Krajewski, Jean-Luc

    2013-01-01

    Many field investigations have used continuous sensors (turbidimeters and/or ultraviolet (UV)-visible spectrophotometers) to estimate with a short time step pollutant concentrations in sewer systems. Few, if any, publications compare the performance of various sensors for the same set of samples. Different surrogate sensors (turbidity sensors, UV-visible spectrophotometer, pH meter, conductivity meter and microwave sensor) were tested to link concentrations of total suspended solids (TSS), total and dissolved chemical oxygen demand (COD), and sensors' outputs. In the combined sewer at the inlet of a wastewater treatment plant, 94 samples were collected during dry weather, 44 samples were collected during wet weather, and 165 samples were collected under both dry and wet weather conditions. From these samples, triplicate standard laboratory analyses were performed and corresponding sensors outputs were recorded. Two outlier detection methods were developed, based, respectively, on the Mahalanobis and Euclidean distances. Several hundred regression models were tested, and the best ones (according to the root mean square error criterion) are presented in order of decreasing performance. No sensor appears as the best one for all three investigated pollutants. PMID:23863442

  11. Surface runoff pollution by cattle slurry and inorganic fertilizer spreading: chemical oxygen demand, ortho-phosphates, and electrical conductivity levels for different buffer strip lengths.

    PubMed

    Núñez-Delgado, A; López-Periago, E; Quiroga-Lago, F; Díaz-Fierros Viqueira, F

    2001-01-01

    As a way of dealing with the removal of pollutants from farming practices generated wastewater in the EU, we investigate the effect of spreading cattle slurry and inorganic fertiliser on 8 x 5 m2 and 8 x 3 m2 areas, referred to surface runoff chemical oxygen demand (COD), ortho-phosphates (o-P) and electrical conductivity (EC) levels, and the efficiency of grass buffer strips of various lengths in removing pollutants from runoff. The experimental plot was a 15% sloped Lolium perenne pasture. Surface runoff was generated by means of a rainfall simulator working at 47 mm h-1 rainfall intensity. Runoff was sampled by using Gerlach-type troughs situated 2, 4, 6 and 8 m downslope from the amended areas. During the first rainfall simulation, COD, o-P and EC levels were consistently higher in the slurry zone, more evidently in the larger amended area. During the second and third rainfall simulations, concentration and mass levels show a downslope drift into the buffer zones, with no clear buffer strip length attenuation. Correlation between runoff and mass drift is clearly higher in the slurry zone. Percentage attenuation in COD and o-P levels, referred to initial slurry concentrations--including rainfall dilution--were higher than 98%, and higher than 90% for EC. PMID:11496670

  12. Gas exchange, growth, and chemical parameters in a native Atlantic forest tree species in polluted areas of Cubatão, Brazil.

    PubMed

    Moraes, R M; Delitti, W B C; Moraes, J A P V

    2003-03-01

    The Atlantic forest species near the industrial complex of Cubatão, Brazil have been subjected to heavy air pollution for decades. In this study, we used some physiological parameters (gas exchange, growth and chemical contents) to biomonitor the effects of air pollution on Tibouchina pulchra, one of the most common tree species in this forest. Under standardized conditions, saplings were exposed to the environment from April to July and from July to September of 1998, at three different sites in the vicinity of the industrial complex: the Valley of Pilões River (VP), the control area; the Valley of Mogi River (VM), near fertilizer, metallurgical, and cement industries sustaining high concentrations of fluorides, N and S oxides, and particulate materials; and Caminho do Mar (CM), near petrochemical industries under N and S oxides, photooxidants, and organic compounds. Plants exposed to CM and VM conditions presented visible injuries, reductions in net photosynthesis, growth parameters, and ascorbate concentrations, and increased F, N, and S foliar concentrations. These results indicate that the environmental conditions around these industries are still harmful to plants. PMID:12651190

  13. The Effect of Chemical Amendments Used for Phosphorus Abatement on Greenhouse Gas and Ammonia Emissions from Dairy Cattle Slurry: Synergies and Pollution Swapping.

    PubMed

    Brennan, Raymond B; Healy, Mark G; Fenton, Owen; Lanigan, Gary J

    2015-01-01

    Land application of cattle slurry can result in incidental and chronic phosphorus (P) loss to waterbodies, leading to eutrophication. Chemical amendment of slurry has been proposed as a management practice, allowing slurry nutrients to remain available to plants whilst mitigating P losses in runoff. The effectiveness of amendments is well understood but their impacts on other loss pathways (so-called 'pollution swapping' potential) and therefore the feasibility of using such amendments has not been examined to date. The aim of this laboratory scale study was to determine how the chemical amendment of slurry affects losses of NH3, CH4, N2O, and CO2. Alum, FeCl2, Polyaluminium chloride (PAC)- and biochar reduced NH3 emissions by 92, 54, 65 and 77% compared to the slurry control, while lime increased emissions by 114%. Cumulative N2O emissions of cattle slurry increased when amended with alum and FeCl2 by 202% and 154% compared to the slurry only treatment. Lime, PAC and biochar resulted in a reduction of 44, 29 and 63% in cumulative N2O loss compared to the slurry only treatment. Addition of amendments to slurry did not significantly affect soil CO2 release during the study while CH4 emissions followed a similar trend for all of the amended slurries applied, with an initial increase in losses followed by a rapid decrease for the duration of the study. All of the amendments examined reduced the initial peak in CH4 emissions compared to the slurry only treatment. There was no significant effect of slurry amendments on global warming potential (GWP) caused by slurry land application, with the exception of biochar. After considering pollution swapping in conjunction with amendment effectiveness, the amendments recommended for further field study are PAC, alum and lime. This study has also shown that biochar has potential to reduce GHG losses arising from slurry application. PMID:26053923

  14. The Effect of Chemical Amendments Used for Phosphorus Abatement on Greenhouse Gas and Ammonia Emissions from Dairy Cattle Slurry: Synergies and Pollution Swapping

    PubMed Central

    Brennan, Raymond B.; Healy, Mark G.; Fenton, Owen; Lanigan, Gary J.

    2015-01-01

    Land application of cattle slurry can result in incidental and chronic phosphorus (P) loss to waterbodies, leading to eutrophication. Chemical amendment of slurry has been proposed as a management practice, allowing slurry nutrients to remain available to plants whilst mitigating P losses in runoff. The effectiveness of amendments is well understood but their impacts on other loss pathways (so-called ‘pollution swapping’ potential) and therefore the feasibility of using such amendments has not been examined to date. The aim of this laboratory scale study was to determine how the chemical amendment of slurry affects losses of NH3, CH4, N2O, and CO2. Alum, FeCl2, Polyaluminium chloride (PAC)- and biochar reduced NH3 emissions by 92, 54, 65 and 77% compared to the slurry control, while lime increased emissions by 114%. Cumulative N2O emissions of cattle slurry increased when amended with alum and FeCl2 by 202% and 154% compared to the slurry only treatment. Lime, PAC and biochar resulted in a reduction of 44, 29 and 63% in cumulative N2O loss compared to the slurry only treatment. Addition of amendments to slurry did not significantly affect soil CO2 release during the study while CH4 emissions followed a similar trend for all of the amended slurries applied, with an initial increase in losses followed by a rapid decrease for the duration of the study. All of the amendments examined reduced the initial peak in CH4 emissions compared to the slurry only treatment. There was no significant effect of slurry amendments on global warming potential (GWP) caused by slurry land application, with the exception of biochar. After considering pollution swapping in conjunction with amendment effectiveness, the amendments recommended for further field study are PAC, alum and lime. This study has also shown that biochar has potential to reduce GHG losses arising from slurry application. PMID:26053923

  15. Industrial waste pollution

    NASA Technical Reports Server (NTRS)

    Jensen, L. D.

    1972-01-01

    The characteristics and effects of industrial waste pollution in the Chesapeake Bay are discussed. The sources of inorganic and organic pollution entering the bay are described. The four types of pollutants are defined as: (1) inorganic chemical wastes, (2) naturally occurring organic wastes, (3) synthetic organic wastes (exotics) and (4) thermal effluents. The ecological behavior of industrial wastes in the surface waters is analyzed with respect to surface film phenomena, interfacial phenomena, and benthis phenomena

  16. BIOINDICATORS IN AIR POLLUTION RESEARCH: APPLICATIONS AND CONSTRAINTS

    EPA Science Inventory

    Physical and chemical measurements of air pollutants provide a precise measure of pollutant exposure which is frequently used to estimate probable biological impacts. Bioindicators may be classified as either accumulators of the pollutant or reactors to the pollutant. The ultimat...

  17. Day and night variation in chemical composition and toxicological responses of size segregated urban air PM samples in a high air pollution situation

    NASA Astrophysics Data System (ADS)

    Jalava, P. I.; Wang, Q.; Kuuspalo, K.; Ruusunen, J.; Hao, L.; Fang, D.; Väisänen, O.; Ruuskanen, A.; Sippula, O.; Happo, M. S.; Uski, O.; Kasurinen, S.; Torvela, T.; Koponen, H.; Lehtinen, K. E. J.; Komppula, M.; Gu, C.; Jokiniemi, J.; Hirvonen, M.-R.

    2015-11-01

    Urban air particulate pollution is a known cause for adverse human health effects worldwide. China has encountered air quality problems in recent years due to rapid industrialization. Toxicological effects induced by particulate air pollution vary with particle sizes and season. However, it is not known how distinctively different photochemical activity and different emission sources during the day and the night affect the chemical composition of the PM size ranges and subsequently how it is reflected to the toxicological properties of the PM exposures. The particulate matter (PM) samples were collected in four different size ranges (PM10-2.5; PM2.5-1; PM1-0.2 and PM0.2) with a high volume cascade impactor. The PM samples were extracted with methanol, dried and thereafter used in the chemical and toxicological analyses. RAW264.7 macrophages were exposed to the particulate samples in four different doses for 24 h. Cytotoxicity, inflammatory parameters, cell cycle and genotoxicity were measured after exposure of the cells to particulate samples. Particles were characterized for their chemical composition, including ions, element and PAH compounds, and transmission electron microscopy (TEM) was used to take images of the PM samples. Chemical composition and the induced toxicological responses of the size segregated PM samples showed considerable size dependent differences as well as day to night variation. The PM10-2.5 and the PM0.2 samples had the highest inflammatory potency among the size ranges. Instead, almost all the PM samples were equally cytotoxic and only minor differences were seen in genotoxicity and cell cycle effects. Overall, the PM0.2 samples had the highest toxic potential among the different size ranges in many parameters. PAH compounds in the samples and were generally more abundant during the night than the day, indicating possible photo-oxidation of the PAH compounds due to solar radiation. This was reflected to different toxicity in the PM

  18. Chemical Speciation and Quantitative Evaluation of Heavy Metal Pollution Hazards in Two Army Shooting Range Backstop Soils.

    PubMed

    Islam, Mohammad Nazrul; Nguyen, Xuan Phuc; Jung, Ho-Young; Park, Jeong-Hun

    2016-02-01

    The chemical speciation and ecological risk assessment of heavy metals in two shooting range backstop soils in Korea were studied. Both soils were highly contaminated with Cd, Cu, Pb, and Sb. The chemical speciation of heavy metals reflected the present status of contamination, which could help in promoting management practices. We-rye soil had a higher proportion of exchangeable and carbonate bound metals and water-extractable Cd and Sb than the Cho-do soil. Bioavailable Pb represented 42 % of the total Pb content in both soils. A significant amount of Sb was found in the two most bioavailable fractions, amounting to ~32 % in the soil samples, in good agreement with the batch leaching test using water. Based on the values of ecological risk indices, both soils showed extremely high potential risk and may represent serious environmental problems. PMID:26546228

  19. Effects of Pollution on Freshwater Fish.

    ERIC Educational Resources Information Center

    Brungs, W. A.; And Others

    1978-01-01

    Presents a literature review of the effects of pollution on freshwater fish, covering publications of 1976-77. This review includes: (1) water quality; (2) pesticide pollutants; (3) chemical pollutants; (4) miscellaneous pollutants; and (5) physical factors of pollution on freshwater fish. A list of 338 references is also presented. (HM)

  20. Eutrophication. [Water pollution

    SciTech Connect

    Medine, A.J.; Porcella, D.B.

    1982-06-01

    A literature review dealing with the process of eutrophication with respect to the sources and transport of pollutants is presented. Topics include the mathematical modeling of nutrient loading, eutrophication, and aquatic ecosystems. Biological and environmental indicators of eutrophication are reviewed, and the interactions between various chemical and biological pollutants are considered. Several lake management projects are discussed. (KRM)

  1. Air Pollution Surveillance Systems

    ERIC Educational Resources Information Center

    Morgan, George B.; And Others

    1970-01-01

    Describes atmospheric data monitoring as part of total airpollution control effort. Summarizes types of gaseous, liquid and solid pollutants and their sources; contrast between urban and rural environmental air quality; instrumentation to identify pollutants; and anticipated new non-wet chemical physical and physiochemical techniques tor cetection…

  2. Air Pollution and Industry.

    ERIC Educational Resources Information Center

    Ross, R. D., Ed.

    This book is an authoritative reference and practical guide designed to help the plant engineer identify and solve industrial air pollution problems in order to be able to meet current air pollution regulations. Prepared under the editorial supervision of an experienced chemical engineer, with each chapter contributed by an expert in his field,…

  3. DEVELOPMENT OF ANALYTICAL METHODS FOR THE QUANTIFICATION OF THE CHEMICAL FORMS OF MERCURY AND OTHER TARGET POLLUTANTS IN COAL-FIRED BOILER FLUE GAS

    SciTech Connect

    Terence J. McManus, Ph.D.

    1999-06-30

    Since approximately 55% of the electrical power produced in the U. S. is generated by coal-based power utility plants, there is serious concern about the massive amounts of coal combustion products emitted into the atmosphere annually. Furthermore, Title III of the 1990 Clean Air Act Amendments (CAAA) requires the measurement and inventory of a possible 189 hazardous air pollutants (HAPs) from any stationary source producing more than 10 tons per year of any one pollutant or more than 25 tons per year of total pollutants. Although power utilities are not presently included on the list of source categories, the CAAA requires the U. S. Environmental Protection Agency to carry out a study of emissions from electricity generation using fossil fuels. Since many of these HAPs are known to be present in coal derived flue gas, coal-fired electric power utilities may be subject to regulation following these studies if Congress considers it necessary. In a cooperative effort with the U. S. Environmental Protection Agency (EPA), the U. S. Department of Energy (DOE) through its Federal Energy Technology Center (FETC) initiated such a study in 1991. DOE-FETC commissioned five primary contractors to conduct emission studies at eight different coal-fired electric utilities. The eight sites represented a cross section of feed coal type, boiler designs, and particulate and gaseous pollutant control technologies. The major goal of these studies was to determine the sampling and analytical methodologies that could be used efficiently to perform these emission tests while producing representative and reliable emission data. The successful methodology could then be recommended to the EPA for use in compliance testing in the event the regulation of air toxic emissions from coal-fired power plants is implemented. A secondary purpose of the testing was to determine the effectiveness of the control technologies in reducing target hazardous air pollutants. Advanced Technology Systems, Inc

  4. Levels, sources and chemical fate of persistent organic pollutants in the atmosphere and snow along the western Antarctic Peninsula.

    PubMed

    Khairy, Mohammed A; Luek, Jenna L; Dickhut, Rebecca; Lohmann, Rainer

    2016-09-01

    The Antarctic continent is among the most pristine regions; yet various organic contaminants have been measured there routinely. Air and snow samples were collected during the austral spring (October-November, 2010) along the western Antarctic Peninsula and analyzed for organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs) to assess the relative importance of long-range transport versus local primary or secondary emissions. Highest concentrations of PCBs, PBDEs and DDTs were observed in the glacier's snow sample, highlighting the importance of melting glaciers as a possible secondary source of legacy pollutants to the Antarctic. In the atmosphere, contaminants were mainly found in the vapor phase (>65%). Hexachlorobenzene (33.6 pg/m(3)), PCBs (11.6 pg/m(3)), heptachlor (5.64 pg/m(3)), PBDEs (4.22 pg/m(3)) and cis-chlordane (2.43 pg/m(3)) were the most abundant contaminants. In contrast to other compounds, PBDEs seem to have originated from local sources, possibly the research station itself. Gas-particle partitioning for analytes were better predicted using the adsorption partitioning model than an octanol-based absorption approach. Diffusive flux calculations indicated that net deposition is the dominant pathway for PBDEs and chlordanes, whereas re-volatilization from snow (during melting or metamorphosis) was observed for PCBs and some OCPs. PMID:27288629

  5. CHEMICAL ABUNDANCES IN THE EXTERNALLY POLLUTED WHITE DWARF GD 40: EVIDENCE OF A ROCKY EXTRASOLAR MINOR PLANET

    SciTech Connect

    Klein, B.; Jura, M.; Zuckerman, B.; Melis, C.; Koester, D. E-mail: jura@astro.ucla.ed E-mail: cmelis@ucsd.ed

    2010-02-01

    We present Keck/High Resolution Echelle Spectrometer data with model atmosphere analysis of the helium-dominated polluted white dwarf GD 40, in which we measure atmospheric abundances relative to helium of nine elements: H, O, Mg, Si, Ca, Ti, Cr, Mn, and Fe. Apart from hydrogen, whose association with the other contaminants is uncertain, this material most likely accreted from GD 40's circumstellar dust disk whose existence is demonstrated by excess infrared emission. The data are best explained by accretion of rocky planetary material, in which heavy elements are largely contained within oxides, derived from a tidally disrupted minor planet at least the mass of Juno, and probably as massive as Vesta. The relatively low hydrogen abundance sets an upper limit of 10% water by mass in the inferred parent body, and the relatively high abundances of refractory elements, Ca and Ti, may indicate high-temperature processing. While the overall constitution of the parent body is similar to the bulk Earth being over 85% by mass composed of oxygen, magnesium, silicon, and iron, we find n(Si)/n(Mg) = 0.30 +- 0.11, significantly smaller than the ratio near unity for the bulk Earth, chondrites, the Sun, and nearby stars. This result suggests that differentiation occurred within the parent body.

  6. Controlling Indoor Air Pollution.

    ERIC Educational Resources Information Center

    Nero, Anthony V, Jr.

    1988-01-01

    Discusses the health risks posed by indoor air pollutants, such as airborne combustion products, toxic chemicals, and radioactivity. Questions as to how indoor air might be regulated. Calls for new approaches to environmental protection. (TW)

  7. A high-pressure premixed flat-flame burner for chemical process studies. [of pollutant formation in hydrocarbon flames

    NASA Technical Reports Server (NTRS)

    Miller, I. M.

    1978-01-01

    A premixed flat-flame burner was designed and tested with methane-air mixtures at pressures from 1.1 to 20 atm and equivalence ratios from 0.7 to 1.1. Reactant velocity in the burner mixing chamber was used to characterize the range of stable flames at each pressure-equivalence-ratio condition. Color photographs of the flames were used to determine flame zone thickness and flame height. The results show that this burner can be used for chemical process studies in premixed high pressure methane-air flames up to 20 atm.

  8. A NEW NON-DESTRUCTIVE METHOD FOR CHEMICAL ANALYSIS OF PARTICULATE MATTER FILTERS: THE CASE OF MANGANESE AIR POLLUTION IN VALLECAMONICA (ITALY)

    PubMed Central

    Borgese, Laura; Zacco, Annalisa; Pal, Sudipto; Bontempi, Elza; Lucchini, Roberto; Zimmerman, Neil; Depero, Laura E.

    2011-01-01

    Total Reflection X-ray Fluorescence (TXRF) is a well-established technique for chemical analysis, but it is mainly employed for quality control in the electronics semiconductor industry. The capability to analyze liquid and uniformly thin solid samples makes this technique suitable for other applications, and especially in the very critical field of environmental analysis. Comparison with standard methods like Inductively Coupled Plasma (ICP) and Atomic Absorption Spectroscopy (AAS) show that TXRF is a practical, accurate, and reliable technique in occupational settings. Due to the greater sensitivity necessary in trace heavy metal detection, TXRF is also suitable for environmental chemical analysis. In this paper we show that based on appropriate standards, TXRF can be considered for non-destructive routine quantitative analysis of environmental matrices such as air filters. This work has been developed in the frame of the EU-FP6 PHIME (Public Health Impact of long-term, low-level Mixed element Exposure in susceptible population strata) Integrated Project (www.phime.org). The aim of this work was to investigate Mn air pollution in the area of Vallecamonica (Italy). PMID:21315919

  9. [Effect of physico-chemical characteristics of activated carbon on the adsorption of organic pollutants in natural water].

    PubMed

    Zhang, Jing-Yi; Shi, Bao-You; Xie, Jian-Kun; Yuan, Hong-Lin; Wang, Dong-Sheng

    2011-02-01

    In this paper, the adsorption characteristics of two synthetic organic compounds (SOCs), i. e., methyl parathion(MP) and trichloroethylene (TCE), and natural organic matter (NOM) on powdered activated carbons (PAC) in natural water were studied. On the basis of fully characterizing the physical and chemical characteristics of PAC, the effect of physical and chemical properties of PAC on the adsorption of low molecular weight SOCs in natural water was studied by correlation analysis. The effect of molecular weight fractionation on the adsorption of NOM on PAC was investigated using high performance size exclusion chromatography (HPSEC). It was found that, compared to the surface chemistry, the physical property (pore properties) of PAC was the critical factor to determine its adsorption capacity of MP and TCE in natural water. The adsorption of the low molecular weight SOC and NOM with apparent molecular weight (AMW) < 500 on PAC was primarily impacted by the micropore surface area, and that of NOM with 500 < AMW < 3 000 was affected by the mesopore surface area combined with the mesopore size distribution. PMID:21528573

  10. Chemical speciation, human health risk assessment and pollution level of selected heavy metals in urban street dust of Shiraz, Iran

    NASA Astrophysics Data System (ADS)

    Keshavarzi, Behnam; Tazarvi, Zahra; Rajabzadeh, Mohammad Ali; Najmeddin, Ali

    2015-10-01

    The distribution, pollution level, sources and health risk of Hg, As, Cd, Cu, Cr, Ni, Mn, Fe, Pb, Sb and Zn in urban street dust were investigated. X-ray diffraction analysis of dust samples shows that the mineralogy of airborne dusts is dominated by calcite, dolomite and quartz. The total concentration of trace elements across the sampling sites ranged from 36.8 to 234.3 mg kg-1 for Pb, 0.004-4.504 mg kg-1 for Hg, 160.9-778.3 mg kg-1 for Zn, 245-652 mg kg-1 for Mn, 39.4-117.9 mg kg-1 for Ni, 31.6-105.9 mg kg-1 for Cr, 49.8-232.5 mg kg-1 for Cu, 5.3-8.6 mg kg-1 for As, 0.31-0.85 mg kg-1 for Cd, 0.76-9.45 mg kg-1 for Sb, and 16,300-24,900 mg kg-1 for Fe. The enrichment factor results reveal the following order: Cu > Hg > Sb > Zn > Pb > Ni > Cr > As > Mn > Cd > Fe. Among the measured elements, the highest mobility factor belongs to Pb (79.2%), Hg (74.6%), Zn (64.1%) and Mn (56.4%). According to the calculated Hazard Quotient (HQ) and Hazard Index (HI), special attention should be paid to Hg, Pb, Zn, and Mn in the street dusts of Shiraz. Multivariate statistics indicate that traffic, natural soil particles and industrial activities are likely to be the main sources of heavy metals in Shiraz street dusts.

  11. Characterizing ozone pollution in a petrochemical industrial area in Beijing, China: a case study using a chemical reaction model.

    PubMed

    Wei, Wei; Lv, Zhaofeng; Cheng, Shuiyuan; Wang, Lili; Ji, Dongsheng; Zhou, Ying; Han, Lihui; Wang, Litao

    2015-06-01

    This study selected a petrochemical industrial complex in Beijing, China, to understand the characteristics of surface ozone (O3) in this industrial area through the on-site measurement campaign during the July-August of 2010 and 2011, and to reveal the response of local O3 to its precursors' emissions through the NCAR-Master Mechanism model (NCAR-MM) simulation. Measurement results showed that the O3 concentration in this industrial area was significantly higher, with the mean daily average of 124.6 μg/m(3) and mean daily maximum of 236.8 μg/m(3), which are, respectively, 90.9 and 50.6 % higher than those in Beijing urban area. Moreover, the diurnal O3 peak generally started up early in 11:00-12:00 and usually remained for 5-6 h, greatly different with the normal diurnal pattern of urban O3. Then, we used NCAR-MM to simulate the average diurnal variation of photochemical O3 in sunny days of August 2010 in both industrial and urban areas. A good agreement in O3 diurnal variation pattern and in O3 relative level was obtained for both areas. For example of O3 daily maximum, the calculated value in the industrial area was about 51 % higher than in the urban area, while measured value in the industrial area was approximately 60 % higher than in the urban area. Finally, the sensitivity analysis of photochemical O3 to its precursors was conducted based on a set of VOCs/NOx emissions cases. Simulation results implied that in the industrial area, the response of O3 to VOCs was negative and to NOx was positive under the current conditions, with the sensitivity coefficients of -0.16~-0.43 and +0.04~+0.06, respectively. By contrast, the urban area was within the VOCs-limitation regime, where ozone enhancement in response to increasing VOCs emissions and to decreasing NOx emission. So, we think that the VOCs emissions control for this petrochemical industrial complex will increase the potential risk of local ozone pollution aggravation, but will be helpful to inhibit the

  12. Dissolved Organic In Natural and Polluted Waters: Methodology and Results of Running Control of Chemical Oxygen Demand (cod) For The Inland and Marine Aquatic System

    NASA Astrophysics Data System (ADS)

    Melentyev, K. V.; Worontsov, A. M.

    Current control of dissolved organic matter in natural and waste waters is the definition traditionally of chemical oxygen demand (COD) -- one of the basic parameters of quality of water. According to the International Standard (ISO 6060), it requires not less than one hour, while in many cases the operative information about amount of dissolved organic matter in aquatic environments have importance for prevention of an emergency. The standard method is applicable to waters with meaning of COD above 30 mg O2/l and, as the chloride ion prevents, it could be difficult for assessment of organic matter in sea water. Besides it is based on dichromate oxidation of the sum of organic substances in strong acid conditions at the presence of silver and mercury, that resulted in formation toxic pollutants. Till now attempts of automation of the COD definition in aquatic system were limited, basically, to duplication of the technology submitted the above standard (automatic COD analyzers "SERES Co."-- France, or "Tsvet Co." - Russia). The system of ozone-chemiluminescence automatic control of organic matter in water (CS COD) is offered and designed. Its based on the ozone oxidation of these substances in flowing water system and measurement arising from luminescent effects. CS COD works in real time. An instrument uses for reaction the atmospheric air, doesn't require fill of reagents and doesn't make new toxic pollutants. The system was tested in laboratory, and biochemical control of organic matter in water samples gathered from the river Neva and other polluted inland water areas and basins in St. Petersburg region was fulfilled (distilled water was used as "zero" media). The results of systematization of these measurements are presented. The new special ozone generator and flowing reactor for real-time running control of different waters in natural conditions were developed, and several series of large - scale field experiments onboard research ship were provided

  13. Fine particles (PM2.5) at a CAWNET background site in Central China: Chemical compositions, seasonal variations and regional pollution events

    NASA Astrophysics Data System (ADS)

    Zhang, Fan; Cheng, Hai-rong; Wang, Zu-wu; Lv, Xiao-pu; Zhu, Zhong-min; Zhang, Gan; Wang, Xin-ming

    2014-04-01

    Fine particle (PM2.5) samples were collected at Jinsha (JSH), a regional background China Atmosphere Watch Network (CAWNET) site in Central China from March 2012 to March 2013. The mass concentrations of water-soluble inorganic ions (WSIIs), organic carbon (OC) and elemental carbon (EC) in PM2.5 were measured. The average PM2.5 mass concentration was 48.7 ± 26.9 μg m-3, exceeding the Chinese National Ambient Air Quality Standards (NAAQS) (35 μg m-3), implying that PM2.5 is a pollutant of regional concern in Central China. The average concentrations of total WSIIs, OC and EC were 26.1 ± 18.8, 7.5 ± 3.5 and 0.7 ± 0.5 μg m-3, accounting for 53.5%, 15.1% and 1.5% of the PM2.5 concentrations at JSH, respectively. Clear seasonal variations in PM2.5 and the levels of its main chemical species were observed in the following order: winter > autumn > spring > summer. Backward air trajectory analysis and potential source contribution function (PSCF) analysis implied that the areas north and northeast of JSH contributed significantly to the levels of SO42-, NO3-, NH4+ and OC, while sandstorms originating from Mongolia and traveling across Northwest China may have contributed significantly to the levels of Na+, Ca2+, and Mg2+ in PM2.5 at JSH. Two pollution events, related to regional biomass burning and haze, respectively, were recorded at JSH during the sampling campaign.

  14. Assessment of multi-chemical pollution in aquatic ecosystems using toxic units: compound prioritization, mixture characterization and relationships with biological descriptors.

    PubMed

    Ginebreda, Antoni; Kuzmanovic, Maja; Guasch, Helena; de Alda, Miren López; López-Doval, Julio C; Muñoz, Isabel; Ricart, Marta; Romaní, Anna M; Sabater, Sergi; Barceló, Damià

    2014-01-15

    Chemical pollution is typically characterized by exposure to multiple rather than to single or a limited number of compounds. Parent compounds, transformation products and other non-targeted compounds yield mixtures whose composition can only be partially identified by monitoring, while a substantial proportion remains unknown. In this context, risk assessment based on the application of additive ecotoxicity models, such as concentration addition (CA), is rendered somewhat misleading. Here, we show that ecotoxicity risk information can be better understood upon consideration of the probabilistic distribution of risk among the different compounds. Toxic units of the compounds identified in a sample fit a lognormal probability distribution. The parameters characterizing this distribution (mean and standard deviation) provide information which can be tentatively interpreted as a measure of the toxic load and its apportionment among the constituents in the mixture (here interpreted as mixture complexity). Furthermore, they provide information for compound prioritization tailored to each site and enable prediction of some of the functional and structural biological variables associated with the receiving ecosystem. The proposed approach was tested in the Llobregat River basin (NE Spain) using exposure and toxicity data (algae and Daphnia) corresponding to 29 pharmaceuticals and 22 pesticides, and 5 structural and functional biological descriptors related to benthic macroinvertebrates (diversity, biomass) and biofilm metrics (diatom quality, chlorophyll-a content and photosynthetic capacity). Aggregated toxic units based on Daphnia and algae bioassays provided a good indication of the pollution pattern of the Llobregat River basin. Relative contribution of pesticides and pharmaceuticals to total toxic load was variable and highly site dependent, the latter group tending to increase its contribution in urban areas. Contaminated sites' toxic load was typically dominated by

  15. In Search of Air Pollution

    ERIC Educational Resources Information Center

    Beckendorf, Kirk

    2006-01-01

    Air pollution is no longer just a local issue; it is a global problem. The atmosphere is a very dynamic system. Pollution not only changes in chemical composition after it is emitted, but also is transported on local and global air systems hundreds and even thousands of miles away. Some of the pollutants that are major health concerns are not even…

  16. [Feasibility of washing as a remediation technology for the heavy metals-polluted soils left by chemical plant].

    PubMed

    Liu, Lei; Hu, Shao-Ping; Chen, Ying-Xu; Li, Hang

    2010-06-01

    Laboratory simulation tests were conducted to examine the effects of different washing reagents (distilled water, HCl, H3PO4, oxalic acid, and CaCl2) in extracting the heavy metals from contaminated soils left by a chemical plant. The effects of reagent concentration, reaction time, and washing time on the washing efficiency were investigated, and the form variation of test heavy metals was determined before and after HCl washing. Distilled water, H3PO4, and CaCl2 could remove less than 1% of most heavy metals, and the highest removal rate was only 3.58%; while 2 mol HCl x L(-1) could obtain the highest washing efficiency under the optimal conditions, i. e., soil:liquid ratio was 1:3, reaction time was 1 hour, and the soils were washed twice by HCl solution. The removal rates of Cr, Pb, Zn, Cu, and Cd from test soils were 80.75%, 88.69%, 98.00%, 79.33%, and 95.52%, respectively. Among the washing reagents, HCl could effectively remove all forms of heavy metals. PMID:20873632

  17. Marine pollution

    SciTech Connect

    Albaiges, J. )

    1989-01-01

    This book covers the following topics: Transport of marine pollutants; Transformation of pollutants in the marine environment; Biological effects of marine pollutants; Sources and transport of oil pollutants in the Persian Gulf; Trace metals and hydrocarbons in Syrian coastal waters; and Techniques for analysis of trace pollutants.

  18. Pollution of the marine environment

    SciTech Connect

    Malins, D.C.

    1980-01-01

    An interdisciplinary approach to identifying chemical pollution in the marine environment and assessing the effects of such pollution on living marine resources is described. Such a study requires knowing: what pollutants organisms are exposed to, which pollutants are accumulated; the fate of pollutants taken up by organisms, and biological changes caused by the pollutants. Analytical limitations of such studies are noted. Examples of specific interdisciplinary laboratory and field investigations are presented, for instance, the finding of liver tumors in flatfish that accumulated sediment-bound naphthalene.

  19. Extreme haze pollution in Beijing during January 2013: chemical characteristics, formation mechanism and role of fog processing

    NASA Astrophysics Data System (ADS)

    Huang, K.; Zhuang, G.; Wang, Q.; Fu, J. S.; Lin, Y.; Liu, T.; Han, L.; Deng, C.

    2014-03-01

    Severe haze hovered over large areas of China in January 2013 right after the public release of PM2.5 data of major cities in China at the very first time. This historical severe haze emerged over the northern China with monthly average concentrations of PM2.5, SO2, and NO2 exceeding 225, 200, and 80 μg m-3, respectively. Surface aerosol mean concentration of Beijing in January 2013 reached record high (only slightly lower than 2006) compared to historical data from 2003-2012, but with the largest daily fluctuation. Anomalous meteorological conditions in 2013 compared to the mean climatology from 2007-2012 were especially favorable for the formation of haze, such as higher humidity, lower temperature, lower PBL height, lower wind speed, and the high frequency of fog occurrences. The field campaign in Beijing showed an extremely high PM2.5 average concentration of 299.2 ± 79.1μg m-3 with extremely low visibility of 0.92 ± 0.82 km during an episode of high relative humidity with fog events. High AOD (Aerosol Optical Depth) was observed during fog days but with relatively low Angstrom exponent (< 1.0), suggesting the modification of fog processing on the particle size. Major aerosol chemical species, such as SO42-, NO3-, NH4+, Cl-, K+, and C2O42- presented an explicit exponential growth relationship with relative humidity, suggesting the significant impact of aerosol hygroscopicity on the visibility impairment. SO42- increased ∼5 folds while NO3-, NH4+, and C2O42- increased ∼3 folds in the fog days compared to the non-fog days. Aerosol in fog days was much more acidic than that in non-fog days. The in situ aerosol pH ranged from -0.78 to 0.14 in fog days based on the E-AIM model simulation. Bisulfate (HSO42-) accounted for 52% of the total sulfate and free hydrogen ion (H+Aq) accounted for 27% of the total acids in average. Enhanced coal combustion during the winter heating season along with traffic and industrial emissions were recognized to be the major

  20. Noise Pollution

    MedlinePlus

    ... here: EPA Home Air and Radiation Noise Pollution Noise Pollution This page has moved. You should be ... epa.gov/clean-air-act-overview/title-iv-noise-pollution Local Navigation Air & Radiation Home Basic Information ...

  1. An integrated chemical-biological study using caged mussels (Mytilus trossulus) along a pollution gradient in the Archipelago Sea (SW Finland, Baltic Sea).

    PubMed

    Lehtonen, Kari K; Turja, Raisa; Budzinski, Hélène; Devier, Marie-Hélène

    2016-08-01

    Mussels (Mytilus trossulus) were caged along a known pollution gradient in the inner Archipelago Sea (northern Baltic Sea) and retrieved after 71 and 121 d for the measurement of selected chemical contaminants in tissues and biological endpoints including biochemical biomarkers and growth. Additional samples were collected during the growth season from a native mussel population at an alleged reference site. Elevated concentrations of numerous contaminants (e.g., PAH) were observed in spring, apparently due to the loss of tissue mass during the winter, while also the levels of many biomarkers (e.g., glutathione S-transferase activity) were elevated. Spatial and temporal changes in the accumulation of contaminants and biological parameters were observed with some of them (e.g., growth) linked to seasonal changes in environmental factors. The results underline the importance of understanding the effects of seasonal natural factors on the growth dynamics and general condition of mussels when assessing tissue concentrations of contaminants and biological effects. PMID:27337550

  2. Canadian National Air Pollution Surveillance (NAPS) PM 2.5 speciation program: Methodology and PM 2.5 chemical composition for the years 2003-2008

    NASA Astrophysics Data System (ADS)

    Dabek-Zlotorzynska, Ewa; Dann, Tom F.; Kalyani Martinelango, P.; Celo, Valbona; Brook, Jeffrey R.; Mathieu, David; Ding, Luyi; Austin, Claire C.

    2011-01-01

    The Canadian National Air Pollution Surveillance (NAPS) network, monitoring criteria gases (CO, O 3, NO x, and SO 2), PM 2.5, PM 10, volatile organic compounds (VOCs), semi-volatile organic compounds (SVOCs) and particle chemical mass and composition, has been in operation for over 40 years. Since 1984 both fine (<2.5 μm - PM 2.5) and coarse (2.5-10 μm - PM 10-2.5) particle mass measurements have been made at NAPS network sites using dichotomous samplers. In January 2003, the NAPS PM 2.5 speciation program was initiated with the purpose of measuring all major components of PM 2.5, including ammonium nitrate, ammonium sulphate, metals, and organic and elemental carbon. The present paper describes the improved sampling (e.g. Teflon/Nylon filter packs for nitrate loss, and an active blank for each and every sample in the determination of positive organic carbon artifacts), and analytical methods used in the Canadian NAPS PM 2.5 speciation program. A detailed dataset was then analyzed for seasonal and geographical variations in the major components of 24-h time integrated PM 2.5 samples collected at eight urban and three rural measurement sites across Canada (2003-2008). Chemical mass reconstruction was used for assessment of the adequacy of selected sampling and chemical parameters as well as for the determination of the relative contributions of different compound classes to PM 2.5 mass. The highest frequency of PM 2.5 episodes exceeding 30 μg m -3 were observed in Ontario and southern Quebec. In general, the most important contributions to PM 2.5 mass were secondary aerosol sulphate and nitrate (38-63% for western sites and 3-44% for eastern sites), depending on the season. Organic matter (OM) was found to be the second most important component (21-45%), while particle-bound water (PBW) accounted for 6-12% of the PM 2.5 mass. Golden B.C. was an exception, exhibiting high levels of OM (60-70%) and low levels of PBW (˜3%).

  3. Use of criteria pollutants, active and passive mercury sampling, and receptor modeling to understand the chemical forms of gaseous oxidized mercury in Florida

    NASA Astrophysics Data System (ADS)

    Huang, J.; Miller, M. B.; Edgerton, E.; Gustin, M. S.

    2015-04-01

    The highest mercury (Hg) wet deposition in the United States (US) occurs along the Gulf of Mexico, and in the southern and central Mississippi River Valley. Gaseous oxidized Hg (GOM) is thought to be a major contributor due to its high water solubility and reactivity. Therefore, it is critical to understand the concentrations, potential for wet and dry deposition, and GOM compounds present in the air. Concentrations and dry deposition fluxes of GOM were measured at Outlying Landing Field (OLF), Florida, using a Tekran® 2537/1130/1135, and active and passive samplers using cation-exchange and nylon membranes. Relationships with Tekran® derived data must be interpreted with caution, since GOM concentrations can be biased low depending on the chemical compounds in air, and interferences with water vapor and ozone. Only gaseous elemental Hg and GOM are discussed here since the PBM measurement uncertainties are higher. Criteria air pollutants were concurrently measured and Tekran® data were assessed along with these using Principal Component Analysis to identify associations among air pollutants. Based on the diel pattern, high GOM concentrations at this site were associated with fossil fuel combustion and gas phase oxidation during the day, and gas phase oxidation and transport in the free troposphere. The ratio of GEM/CO at OLF (0.008 ng m-3 ppbv-1) was much higher than the numbers reported for the Western United States and central New York for domestic emissions or biomass burning (0.001 ng m-3 ppbv-1), which we suggest is indicative of a marine boundary layer source. Results from nylon membranes with thermal desorption analyses suggest five potential GOM compounds exist in this area, including HgBr2, HgO, Hg(NO3)2, HgSO4, and an unknown compound. This indicates that the site is influenced by different gaseous phase reactions and sources. A~high GOM event related to high CO but average SO2 suggests the air parcels moved from the free troposphere and

  4. Pollution Probe.

    ERIC Educational Resources Information Center

    Chant, Donald A.

    This book is written as a statement of concern about pollution by members of Pollution Probe, a citizens' anti-pollution group in Canada. Its purpose is to create public awareness and pressure for the eventual solution to pollution problems. The need for effective government policies to control the population explosion, conserve natural resources,…

  5. Chemical and isotopical characterisation of atmospheric pollution from urban and rural environments of the Rhine Valley (PCBs, trace elements and Sr-, Nd- and Pb- isotope determinations)

    NASA Astrophysics Data System (ADS)

    Guéguen, F.; Stille, P.; Millet, M.; Dietze, V.; Gieré, R.

    2010-05-01

    Atmosheric samples (gas and particulate matter (PM)) have been collected in the urban environment of the cities of Strasbourg and Kehl and in the rural environment of the Vosges mountains. For sampling of gas phase pollutants and particles two different passive sampler devices have been applied (PAS and Sigma-2, respectively). The PAS has been used for gas phase Polychlorinated Biphenyls (PCBs) sampling and is based on the passive adsorption of gas phase pollutants onto XAD-2 resin. The Sigma-2 sampler is based on the sedimentation principle (Stoke's law), collects particles in the size range 2.5-100 μm and allows the calculation of ambient air concentration. The sampler is mainly used for routine air quality measurements in German health and recreation resorts and in this field study the first time for collection of samples for subsequent trace element and isotope analysis. The collection time for the Sigma-2 and PAS are four and two weeks, respectively. Major and trace elements have been analyzed by ICP-MS and the Sr, Nd and Pb isotope ratios by a sector field MC-ICP-MS (Neptune) while PCBs were ASE extracted and analysed by GC-ECD. The aerosol data are compared with those from tree barks which have previously been used successfully as biomonitors of atmospheric pollution (Lahd Geagea et al. 2008)1. The outer 1 mm thick part of the bark has been analyzed corresponding to about 2 to 8 years of accumulation. Some of the trace elements (Cr, Ni and Mo) of the aerosol samples are strongly (up to 1000 times) enriched compared to average 'upper continental crust (UCC)'. Normalization to a « natural » sample with an atmospheric baseline composition allows to identify industrial contributions: transition metals (Cr, Mn, Fe, Co, Ni, Zn, Mo, Cd), Ba and Pb appear to be important elements in steel plant and incinerator (chemical waste) emissions. Similarly enrichment in light rare earth elements (La, Pr, Nd) is observable. The enrichments increase with decreasing distance

  6. Dissolved Organic In Natural and Polluted Waters: Methodology and Results of Running Control of Chemical Oxygen Demand (cod) For The Inland and Marine Aquatic System

    NASA Astrophysics Data System (ADS)

    Melentyev, K. V.; Worontsov, A. M.

    Current control of dissolved organic matter in natural and waste waters is the definition traditionally of chemical oxygen demand (COD) -- one of the basic parameters of quality of water. According to the International Standard (ISO 6060), it requires not less than one hour, while in many cases the operative information about amount of dissolved organic matter in aquatic environments have importance for prevention of an emergency. The standard method is applicable to waters with meaning of COD above 30 mg O2/l and, as the chloride ion prevents, it could be difficult for assessment of organic matter in sea water. Besides it is based on dichromate oxidation of the sum of organic substances in strong acid conditions at the presence of silver and mercury, that resulted in formation toxic pollutants. Till now attempts of automation of the COD definition in aquatic system were limited, basically, to duplication of the technology submitted the above standard (automatic COD analyzers "SERES Co."-- France, or "Tsvet Co." - Russia). The system of ozone-chemiluminescence automatic control of organic matter in water (CS COD) is offered and designed. Its based on the ozone oxidation of these substances in flowing water system and measurement arising from luminescent effects. CS COD works in real time. An instrument uses for reaction the atmospheric air, doesn't require fill of reagents and doesn't make new toxic pollutants. The system was tested in laboratory, and biochemical control of organic matter in water samples gathered from the river Neva and other polluted inland water areas and basins in St. Petersburg region was fulfilled (distilled water was used as "zero" media). The results of systematization of these measurements are presented. The new special ozone generator and flowing reactor for real-time running control of different waters in natural conditions were developed, and several series of large - scale field experiments onboard research ship were provided

  7. Nurses join pollution fight.

    PubMed

    Sadler, Catharine

    2016-08-10

    Most of us are aware of outdoor air pollution: spend time in any traffic-clogged street, and you can taste the chemicals. Even spring days in the countryside can be spoiled by ozone haze. But a report published earlier this year by the Royal College of Physicians (RCP) and the Royal College of Paediatrics and Child Health (RCPCH) revealed that air pollution is much more than an inconvenience - it is a major health risk. PMID:27507373

  8. Vitellogenin gene expression in the intertidal blenny Lipophrys pholis: a new sentinel species for estrogenic chemical pollution monitoring in the European Atlantic coast?

    PubMed

    Ferreira, F; Santos, M M; Castro, L Filipe C; Reis-Henriques, M A; Lima, D; Vieira, M N; Monteiro, N M

    2009-01-01

    The presence of estrogenic chemicals (ECs) in the aquatic environment is a growing problem. While most attention was initially given to fresh water and estuarine ecosystems, it is now evident that coastal marine areas are also vulnerable to these pollutants. The use of vitellogenin induction in male fish, a specific biomarker of EC exposure, has been the most widely applied methodology. However, in some occasions, the high mobility and migratory behaviour of common sentinel fish species makes data interpretation difficult. Hence, there is the need to validate new sentinel marine fish species which should display, among other features, a strong homing behaviour. The shanny, Lipophrys pholis, is an intertidal fish that combines many of the required characteristics for a sentinel species: abundance and easy of catch, wide geographical distribution and restricted home range. Thus, in order to evaluate, in the field, the species sensitivity to ECs, L. pholis males were collected at two sites reflecting different degrees of anthropogenic contamination. The vitellogenin II gene (VTGII) was isolated and its liver expression evaluated by RT-PCR in the field samples. A significant induction of gene expression was observed in the specimens collected in the urban area, if compared to the reference site, which suggests exposure to ECs. Moreover, a 21-days laboratory exposure to environmental relevant concentrations of ethinylestradiol (EE2) was also performed. A significant induction of L. pholis VTGII gene in EE2 exposed males was observed suggesting similar sensitivity to that of other marine/estuarine fishes. Even though further validation is currently in progress, the available data indicates that L. pholis is responsive to ECs, thus favouring its future integration in monitoring programmes designed to evaluate the presence of ECs in European marine ecosystems. PMID:18672093

  9. Chemical compositions responsible for inflammation and tissue damage in the mouse lung by coarse and fine particulate samples from contrasting air pollution in Europe.

    PubMed

    Happo, Mikko S; Hirvonen, Maija-Riitta; Halinen, Arja I; Jalava, Pasi I; Pennanen, Arto S; Sillanpaa, Markus; Hillamo, Risto; Salonen, Raimo O

    2008-11-01

    Inflammation is regarded as an important mechanism in mortality and morbidity associated with exposures of cardiorespiratory patients to urban air particulate matter. We investigated the association of the chemical composition and sources of urban air fine (PM(2.5-0.2)) and coarse (PM(10-2.5)) particulate samples with the inflammatory activity in the mouse lung. The particulate samples were collected during selected seasons in six European cities using a high-volume cascade impactor. Healthy C57BL/6J mice were intratracheally instilled with a single dose (10 mg/kg) of the particulate samples. At 4, 12, and 24 h after the exposure, the lungs were lavaged and the bronchoalveolar lavage fluid (BALF) was assayed for indicators of inflammation and tissue damage: cell number, total protein, and cytokines (tumor necrosis factor [TNF]-alpha, interleukin [IL]-6, and KC). Dicarboxylic acids and transition metals, especially Ni and V, in PM(2.5-0.2) correlated positively and some secondary inorganic ions (NO3(-), NH4(+)) negatively with the inflammatory activity. Total organic matter and SO4(2-) had no consistent correlations. In addition, the soil-derived constituents (Ca2+, Al, Fe, Si) showed positive correlations with the PM(2.5-0.2)-induced inflammatory activity, but their role in PM(10-2.5) remained obscure, possibly due to largely undefined biogenic material. Markers of poor biomass and coal combustion, i.e., monosaccharide anhydrides and As, were associated with elevated PAH contents in PM(2.5-0.2) and a consistent immunosuppressive effect. Overall, our results support epidemiological findings that the local sources of incomplete combustion and resuspended road dust are important in urban air particulate pollution-related health effects. PMID:18855153

  10. Temporal trends of persistent organic pollutants in dated sediment cores: Chemical fingerprinting of the anthropogenic impacts in the Seine River basin, Paris.

    PubMed

    Lorgeoux, C; Moilleron, R; Gasperi, J; Ayrault, S; Bonté, P; Lefèvre, I; Tassin, B

    2016-01-15

    Persistent organic pollutants (POPs) were extensively produced and used throughout the last century. In the early 1980s, a rising concern on the environmental impact of these chemicals has led to the establishment of regulations and changes of use including bans. Long term monitoring of the environmental impacts of these emissions and regulations is a challenge because regular monitoring was not mandatory at the beginning of the first emissions. Moreover, the analytical methods have been strongly improved over the decades. To overcome the lack of monitoring and accurate data, sediment cores are powerful tools to construct contamination records. In this study, a high resolution record was constructed for four POPs families (13 polycyclic aromatic hydrocarbons (PAHs), 15 polychlorinated biphenyls (PCBs), 3 alkylphenols (APs) and 8 polybromodiphenyl ethers (PBDEs)) to establish their historical trends in a long-term urbanized and industrialized environment: the Seine River basin, France. These specific families were selected because they had different sources, uses and histories. The results showed concentrations up to 90 mg/kg for ∑PAHs, 2.3mg/kg for ∑PCB, 1.2mg/kg for ∑APs and 0.06 mg/kg for ∑PBDE. The vertical distribution profiles were different from one family to another and presented a good correlation with uses (e.g. transition from coal to natural gas for PAHs), and regulation implementation (e.g., AP ban after "OSPAR Convention" in 1992). The study of compounds distribution provided original information on sources, e.g. temporal variations in PAH uses. This study demonstrates the usefulness and accuracy of sedimentary archives in floodplain to assess the fate of POPs through time in continental hydrosystems. These first results give a comprehensive overview of the contamination in the Seine River basin downstream of Paris Megacity. They were in good agreement with previous studies dedicated to European areas and highlighted specificities of this basin

  11. Ecological restoration of a copper polluted vineyard: Long-term impact of farmland abandonment on soil bio-chemical properties and microbial communities.

    PubMed

    Cavani, Luciano; Manici, Luisa M; Caputo, Francesco; Peruzzi, Elisabetta; Ciavatta, Claudio

    2016-11-01

    This study aimed at investigating the degree of interference of high soil copper (Cu) contamination when an old vineyard is converted into a protected area. This study was performed within an intensive agricultural system; it was organized into a two-factorial nested design to analyze the impact of management (conventional vs re-naturalized orchard) and position within each orchard (tree-rows and strips). Chemical and biochemical properties along with bacterial and fungal communities, evaluated with PCR-DGGE starting from total soil DNA, were analyzed. Total Cu was localized in tree rows in the old vineyard at 1000 mg kg(-1) of soil, whereas it did not exceed 80 mg kg(-1) soil in the other treatments. Total organic carbon and all biochemical properties significantly improved in re-naturalized compared to conventionally cultivated site, while no significant differences were observed between tree row and strip. Moreover, a higher extractable carbon-extractable nitrogen (Cext-to-Next) ratio in the re-naturalized (19.3) site than in the conventionally managed site (10.2) indicated a shift of soil system from C-limited to N-limited, confirming a successful ecological restoration. Deep improvement of soil biochemical properties exceeded the negative impact of Cu contamination. A shift of bacterial community composition as well as increased bacterial diversity in Cu contaminated treatment indicated a bacterial response to Cu stress; to the contrary, soil fungi were less susceptible than bacteria, though an overall reduction of fungal DNA was detected. Findings suggest that ecological restoration of highly polluted agricultural soils leads to overcoming the reduction of soil functionalities linked to Cu contamination and opens interesting perspectives for mitigating Cu stress in agricultural soils with strategies based on conservative agriculture. PMID:27454095

  12. Chemical compositions responsible for inflammation and tissue damage in the mouse lung by coarse and fine particulate samples from contrasting air pollution in Europe

    SciTech Connect

    Happo, M.S.; Hirvonen, M.R.; Halinen, A.I.; Jalava, P.I.; Pennanen, A.S.; Sillanpaa, M.; Hillamo, R.; Salonen, R.O.

    2008-07-01

    Inflammation is regarded as an important mechanism in mortality and morbidity associated with exposures of cardiorespiratory patients to urban air particulate matter. We investigated the association of the chemical composition and sources of urban air fine (PM2.5-0.2) and coarse (PM10-2.5) particulate samples with the inflammatory activity in the mouse lung. The particulate samples were collected during selected seasons in six European cities using a high-volume cascade impactor. Healthy C57BL/6J mice were intratracheally instilled with a single dose (10 mg/kg) of the particulate samples. At 4, 12, and 24 h after the exposure, the lungs were lavaged and the bronchoalveolar lavage fluid (BALF) was assayed for indicators of inflammation and tissue damage: cell number, total protein, and cytokines (tumor necrosis factor (TNF)-alpha, interleukin (IL)-6, and KC). Dicarboxylic acids and transition metals, especially Ni and V, in PM2.5-0.2 correlated positively and some secondary inorganic ions (NO{sub 3}{sup -}, NH{sub 4}{sup +}) negatively with the inflammatory activity. Total organic matter and SO{sub 4}{sup 2-} had no consistent correlations. In addition, the soil-derived constituents (Ca{sup 2+}, Al, Fe, Si) showed positive correlations with the PM2.5-0.2-induced inflammatory activity, but their role in PM10 (2.5) remained obscure, possibly due to largely undefined biogenic material. Markers of poor biomass and coal combustion, i.e., monosaccharide anhydrides and As, were associated with elevated PAH contents in PM2.5 (0.2) and a consistent immunosuppressive effect. Overall, our results support epidemiological findings that the local sources of incomplete combustion and resuspended road dust are important in urban air particulate pollution-related health effects.

  13. Examining the temperature dependence of ethanol (E85) versus gasoline emissions on air pollution with a largely-explicit chemical mechanism

    NASA Astrophysics Data System (ADS)

    Ginnebaugh, Diana L.; Liang, Jinyou; Jacobson, Mark Z.

    2010-03-01

    The increased use of ethanol in transportation fuels warrants an investigation of its consequences. An important component of such an investigation is the temperature dependence of ethanol and gasoline exhaust chemistry. We use the Master Chemical Mechanism (MCM, version 3.1, LEEDS University) with the SMVGEAR II chemical ordinary differential solver to provide the speed necessary to simulate complex chemistry to examine such effects. The MCM has over 13,500 organic reactions and 4600 species. SMVGEAR II is a sparse-matrix Gear solver that reduces the computation time significantly while maintaining any specified accuracy. Although we use a box model for this study, we determine and demonstrate in a separate study that the speed of the MCM with SMVGEAR II allows the MCM to be modeled in 3-dimensions. We also verified the accuracy of the model in comparison with smog chamber data. We then use the model with species-resolved tailpipe emissions data for E85 (15% gasoline, 85% ethanol fuel blend) and gasoline vehicles to compare the impact of each on nitrogen oxides, organic gases, and ozone as a function of ambient temperature and background concentrations, using Los Angeles in 2020 as a base case. We use two different emissions sets - one is a compilation of exhaust and evaporative data taken near 24 °C and the other from exhaust data taken at -7 °C - to determine how atmospheric chemistry and emissions are affected by temperature. We include diurnal effects by examining two day scenarios. We find that, accounting for chemistry and dilution alone, the average ozone concentrations through the range of temperatures tested are higher with E85 than with gasoline by ˜7 part per billion volume (ppbv) at higher temperatures (summer conditions) to ˜39 ppbv at low temperatures and low sunlight (winter conditions) for an area with a high nitrogen oxide (NOx) to non-methane organic gas (NMOG) ratio. The results suggest that E85's effect on health through ozone formation

  14. EFFECTS OF POLLUTION ON FRESHWATER FISH

    EPA Science Inventory

    An extensive literature review is presented which is concerned with the effects of pollutants (metals, pesticides, detergents, industrial wastes) on freshwater fish; chemical and biological methods for identifying and determining the effects of such pollutants; and the effects of...

  15. Vertical profiles of pollutant gases measured with passive DOAS in the Po Valley devoted to satellite and chemical model data comparison

    NASA Astrophysics Data System (ADS)

    Masieri, S.; Petritoli, A.; Kostadinov, I.; Bortoli, D.; Premuda, M.; Ravegnani, F.; Giovanelli, G.

    2009-04-01

    In the frame of QUITSAT Italian pilot project (Air QUality with InTegration of ground-based and SAtellite measurement and chemical Transport model), two field campaigns were made in S.Pietro Capofiume (44.65˚ N; 11.37˚ E) and Bologna (44.52˚ N; 11.34˚ E) to provide concentration of ground particular matter and gaseous pollutants, namely nitrogen dioxide (NO2), formaldehyde (HCHO), sulphur dioxide (SO2) and ozone (O3). The aim of the campaigns was to provide experimental data need for tests and improvement of algorithms developed for integration of satellite and ground-based data together with chemical transport model data in order to retrieve air quality in the QUITSAT domain. Ground based measurements were carried out within a network of in-situ analyser in the Po Valley and with a scanning multi-axis DOAS (Differential Optical Absorption Spectroscopy) spectrometer system developed at ISAC-CNR institute [1], in collaboration with Geophysics Center of Evora [2]. TropoGAS (TROPOspheric Gas Analyser Spectrometer) spectrometer permits active and passive DOAS measurements at the chosen angles: α =1,2,3,6,10,15,20,90 and another measurement was taken along the sun direction. A Xenon lamp installed at 1km of distance from spectrometer was used as a reference concentration measured in the same place, and these values shows good agreement with in-situ analyser concentration. Gas spectral absorption was evaluated with DOAS [3] algorithms from 430 to 500 nm in two different windows: first from 436 to 460 nm for NO2 retrieval; second from 460 to 500 nm for O4 (best line at 477 nm) and NO2. Air Mass Factor (AMF) was calculated using PROMSAR (PROcessing of Multi-Scattered Atmospheric Radiation) model [4], that is a backward Montecarlo Radiative Transfer Model (RTM). An apposite inversion method [5][6], was applied to retrieve profiles of the target gases from their Slant Column Densities (SCD), using advanced approaches involving measurement of the atmospheric O4

  16. Social Pollution

    ERIC Educational Resources Information Center

    Esser, Aristide Henri

    1971-01-01

    Social pollution provides the matrix for the pollution of the physical environment. This stems from man's present inability to function synergistically. To find new freedoms in purposeful evolution, we will have to start cleansing our Mind. (Author/SD)

  17. Oxygen levels versus chemical pollutants: do they have similar influence on macrofaunal assemblages? A case study in a harbour with two opposing entrances.

    PubMed

    Guerra-García, J M; García-Gómez, J C

    2005-05-01

    Generally, harbours are polluted zones characterised by low values of hydrodynamism and oxygen in the water column and high concentrations of pollutants in sediments. The harbour of Ceuta, North Africa, has an unusual structure; it is located between two bays connected by a channel, which increases the water movement and exchange in the harbour, maintaining moderate oxygen levels in the water-sediment interface. Nevertheless, high concentration of organic matter, nutrients and heavy metals were measured in sediments from this harbour. Under these unusual conditions (high levels of pollution but total saturation of oxygen in the water column) we studied the responses of soft-bottom macrobenthic communities using uni and multivariate analyses. The number of species was similar inside and outside the harbour but the species composition differed between internal and external stations; oxygen levels seem to control the "quantity" of species whereas pollutants control the "quality" of them. PMID:15734588

  18. Air Pollution.

    ERIC Educational Resources Information Center

    Fox, Donald L.

    1989-01-01

    Materials related to air pollution are reviewed for the period January 1987, to October 1988. The topics are pollution monitoring, air pollution, and environmental chemistry. The organization consists of two major analytical divisions: (1) gaseous methods; and (2) aerosol and particulate methods. (MVL)

  19. Air Pollution.

    ERIC Educational Resources Information Center

    Barker, K.; And Others

    Pollution of the general environment, which exposes an entire population group for an indeterminate period of time, certainly constitutes a problem in public health. Serious aid pollution episodes have resulted in increased mortality and a possible relationship between chronic exposure to a polluted atmosphere and certain diseases has been…

  20. Air Pollution.

    ERIC Educational Resources Information Center

    Gilpin, Alan

    A summary of one of our most pressing environmental problems, air pollution, is offered in this book by the Director of Air Pollution Control for the Queensland (Australia) State Government. Discussion of the subject is not restricted to Queensland or Australian problems and policies, however, but includes analysis of air pollution the world over.…

  1. Silica- and sulfate-bearing rock coatings in smelter areas: Products of chemical weathering and atmospheric pollution I. Formation and mineralogical composition

    NASA Astrophysics Data System (ADS)

    Mantha, Nathalie M.; Schindler, Michael; Murayama, Mitsuhiro; Hochella, Michael F.

    2012-05-01

    Black rock-coatings occur in proximity to smelters and roast yards of the Greater Sudbury area, Ontario, Canada and contain information about the past interactions between surface minerals, and gaseous and particulate atmospheric components, many of which were pollutants. Rock-coatings were collected from various locations within the Sudbury area and are characterized with scanning electron microscopy, transmission electron microscopy, X-ray diffraction, electron microprobe analysis, infrared spectroscopy and X-ray photoelectron spectroscopy. Acidic fumigations and rain, the result of vast quantities of SO2 released from smelting, increased the chemical weathering rate of exposed rocks in the Sudbury area. Non-stoichiometric dissolution of the silicate minerals under acidic conditions resulted in the accumulation of silicic acid and the subsequent formation of a silica-gel type coating. The silica gel transformed overtime into amorphous silica, opal (opal C and opal-CT) and cristobalite. Dissolution of the underlying rock and also of metal-bearing particles by sulfuric acid resulted in the in situ formation of metal-sulfate-rich layers on the interfaces between the atmosphere and the silica-rich coating (atmosphere-coating interface, ACI) and between the silica-rich coating and the underlying rock (rock-coating interface, RCI). These metal-sulfate-rich layers contain nanometer aggregates of Fe-Cu-sulfate-hydroxide, goldichite, mereiterite, guildite, butlerite and antlerite. The silica-rich matrix also contains a mix of detrital grains from adjacent rocks and soils (feldspar, quartz, hematite, chlorite, montmorillonite) and non-dissolved smelter-derived nano- to micro-size particulates (metal-silicates, metal-oxides, C-spheres). The apparent disequilibrium between the embedded particles and the Fe-Cu-sulfates suggests that trapped nanoparticles were encapsulated into pores which prevented their equilibration with acidic metal-sulfate-bearing fluids. An XPS depth

  2. Estimation of the influence that natural fires have on air pollution in the region of Moscow megalopolis based on the combined use of chemical transport model and measurement data

    NASA Astrophysics Data System (ADS)

    Konovalov, I. B.; Beekmann, M.; Kuznetsova, I. N.; Glazkova, A. A.; Vasil'Eva, A. V.; Zaripov, R. B.

    2011-08-01

    Satellite measurements of the fire radiation power, measurements of atmospheric pollution in the network of GPU Mosekomonitoring stations, and the modern CHIMERE chemical transport model (CHIMERE CTM) are used for estimating the influence that forest fires have on the air pollution level in the Moscow megalopolis region during the summer of 2007. The method by which the radiation power caused by natural fires determined from satellite measurements is converted into emissions of individual model species is described. General problems related to the optimization of estimates of fire emission and the effects caused by them based on the combined use of measurement data on the composition of the atmosphere and the CTM are considered using a concrete example. It is shown, in particular, that the use of the standard least squares method for the optimization of fire emissions from leads in the general case to obtaining biased (underestimated) estimates. The results of calculations consistent with measurements show that forest fires near Moscow can occasionally be responsible for a considerable part of the air pollution observed in Moscow and its vicinities, and they can be the main reason for the high level of atmospheric pollution in some neighboring regions.

  3. Chemistry for Pollution Control.

    ERIC Educational Resources Information Center

    Everson, Larry

    This booklet presents some methods of quantitative chemical analysis currently used in the field of fresh water pollution control. Only those tests that may be performed with little or no special reagents or pieces of equipment are listed. The booklet addresses the following determinations: (1) acidity; (2) alkalinity; (3) chloride; (4) hardness;…

  4. Water Pollution: Monitoring the Source.

    ERIC Educational Resources Information Center

    Wilkes, James W.

    1980-01-01

    Described is an advanced biology class project involving study of the effects of organic pollution on an aquatic ecosystem from an sewage treatment plant overflow to evaluate the chemical quality and biological activity of the river water. (DS)

  5. Aircraft borne combined measurements of the Fukushima radionuclide Xe-133 and fossil fuel combustion generated pollutants in the TIL - Implications for Cyclone induced lift and TIL physical-chemical processes

    NASA Astrophysics Data System (ADS)

    Arnold, Frank; Schlager, Hans; Simgen, Hardy; Aufmhoff, Heinfried; Baumann, Robert; Lindemann, Sigfried; Rauch, Ludwig; Kaether, Frank; Pirjolla, Liisa; Schumann, Ulrich

    2013-04-01

    The radionuclide Xe-133, released by the March 2011 nuclear disaster at Fukushima/Daiichi (hereafter FD), represents an ideal tracer for atmospheric transport. We report the, to our best knowledge, only aircraft borne measurements of FD Xe-133 in the Tropopause Inversion Layer (TIL), indicating rapid lift of Xe-133 rich planetary boundary layer air to the TIL. On the same research aircraft (FALCON), we have also conducted on-line measurements of fossil fuel combustion generated pollutant gases (SO2, NOx, HNO3,NOy), which were found to have increased concentrations in the TIL. In addition, we have conducted supporting model simulations of transport, chemical processes, and aerosol processes. Our investigations reveal a potentially important influence of East-Asian cyclone induced pollutants transport to the TIL, particularly influencing aerosol formation in the TIL.

  6. Source apportionment of fine particles and its chemical components over the Yangtze River Delta, China during a heavy haze pollution episode

    NASA Astrophysics Data System (ADS)

    Li, L.; An, J. Y.; Zhou, M.; Yan, R. S.; Huang, C.; Lu, Q.; Lin, L.; Wang, Y. J.; Tao, S. K.; Qiao, L. P.; Zhu, S. H.; Chen, C. H.

    2015-12-01

    An extremely high PM2.5 pollution episode occurred over the eastern China in January 2013. In this paper, the particulate matter source apportionment technology (PSAT) method coupled within the Comprehensive air quality model with extensions (CAMx) is applied to study the source contributions to PM2.5 and its major components at six receptors (Urban Shanghai, Chongming, Dianshan Lake, Urban Suzhou, Hangzhou and Zhoushan) in the Yangtze River Delta (YRD) region. Contributions from 4 source areas (including Shanghai, South Jiangsu, North Zhejiang and Super-region) and 9 emission sectors (including power plants, industrial boilers and kilns, industrial processing, mobile source, residential, volatile emissions, dust, agriculture and biogenic emissions) to PM2.5 and its major components (sulfate, nitrate, ammonia, organic carbon and elemental carbon) at the six receptors in the YRD region are quantified. Results show that accumulation of local pollution was the largest contributor during this air pollution episode in urban Shanghai (55%) and Suzhou (46%), followed by long-range transport (37% contribution to Shanghai and 44% to Suzhou). Super-regional emissions play an important role in PM2.5 formation at Hangzhou (48%) and Zhoushan site (68%). Among the emission sectors contributing to the high pollution episode, the major source categories include industrial processing (with contributions ranging between 12.7 and 38.7% at different receptors), combustion source (21.7-37.3%), mobile source (7.5-17.7%) and fugitive dust (8.4-27.3%). Agricultural contribution is also very significant at Zhoushan site (24.5%). In terms of the PM2.5 major components, it is found that industrial boilers and kilns are the major source contributor to sulfate and nitrate. Volatile emission source and agriculture are the major contributors to ammonia; transport is the largest contributor to elemental carbon. Industrial processing, volatile emissions and mobile source are the most significant

  7. [Air pollution].

    PubMed

    Bauters, Christophe; Bauters, Gautier

    2016-01-01

    Short-term exposure to particulate matter (PM) air pollution is associated with an increased cardiovascular mortality. Chronic exposure to PM is also associated with cardiovascular risk. Myocardial infarction and heart failure are the most common cardiovascular events associated with PM pollution. The pathophysiological mechanisms related to PM pollution are inflammation, thrombosis, vasomotion abnormalities, progression of atherosclerosis, increased blood pressure, and cardiac remodeling. A decrease in PM exposure may be particularly beneficial in subjects with a high cardiovascular risk. PMID:26547674

  8. Screening of pollution control and clean-up materials for river chemical spills using the multiple case-based reasoning method with a difference-driven revision strategy.

    PubMed

    Liu, Rentao; Jiang, Jiping; Guo, Liang; Shi, Bin; Liu, Jie; Du, Zhaolin; Wang, Peng

    2016-06-01

    In-depth filtering of emergency disposal technology (EDT) and materials has been required in the process of environmental pollution emergency disposal. However, an urgent problem that must be solved is how to quickly and accurately select the most appropriate materials for treating a pollution event from the existing spill control and clean-up materials (SCCM). To meet this need, the following objectives were addressed in this study. First, the material base and a case base for environment pollution emergency disposal were established to build a foundation and provide material for SCCM screening. Second, the multiple case-based reasoning model method with a difference-driven revision strategy (DDRS-MCBR) was applied to improve the original dual case-based reasoning model method system, and screening and decision-making was performed for SCCM using this model. Third, an actual environmental pollution accident from 2012 was used as a case study to verify the material base, case base, and screening model. The results demonstrated that the DDRS-MCBR method was fast, efficient, and practical. The DDRS-MCBR method changes the passive situation in which the choice of SCCM screening depends only on the subjective experience of the decision maker and offers a new approach to screening SCCM. PMID:26922461

  9. SOURCE APPORTIONMENT OF AIR POLLUTION IN CHINA: EXTENDING THE USEFULNESS OF RECEPTOR MODELING BY COMBINING MULTIVARIATE AND CHEMICAL MASS BALANCE MODELS

    EPA Science Inventory

    This research explores the possibility of using a two step method of identify and quantify air pollution emissions in an urban environment. he procedure was a mathematical model called Target Transformation Factor Analysis (TTFA) to estimate source profiles using ambient trace el...

  10. Pollution of the marine environment

    SciTech Connect

    Malins, D.C.

    1980-01-01

    With 63,000 chemicals in common use, the task of identifying specific pollutants and their effects in relation to marine life is immense. The interdisciplinary approach to this complex issue includes studies in analytical chemistry, biochemistry, vertebrate and invertebrate pathology, electron microscopy, immunology, and behavioral biology. Primary concerns are whether pollutants are available to organisms and whether they are transferred through marine food webs. Studies on marine and estuarine pollution in the New York Bight and Puget Sound, Washington, are summarized. Among other results it is interactive effects between two pollutants in marine organism that account for substantial alterations in certain biochemical systems and in cellular morphology. (JGB)

  11. Air Pollution.

    ERIC Educational Resources Information Center

    Scorer, Richard S.

    The purpose of this book is to describe the basic mechanisms whereby pollution is transported and diffused in the atmosphere. It is designed to give practitioners an understanding of basic mechanics and physics so they may have a correct basis on which to formulate their decisions related to practical air pollution control problems. Since many…

  12. Particle Pollution

    MedlinePlus

    ... EPA Air Quality Index (AQI) tells you when air pollution is likely to reach levels that could be ... high, take steps to limit the amount of air you breathe in while you're outside. ... pollution levels are usually lower. Choose easier outdoor activities ( ...

  13. Air Pollution.

    EPA Science Inventory

    Air quality is affected by many types of pollutants that are emitted from various sources, including stationary and mobile. These sources release both criteria and hazardous air pollutants, which cause health effects, ecological harm, and material damage. They are generally categ...

  14. Chemical signatures of the Anthropocene in the Clyde estuary, UK: sediment-hosted Pb, (207/206)Pb, total petroleum hydrocarbon, polyaromatic hydrocarbon and polychlorinated biphenyl pollution records.

    PubMed

    Vane, C H; Chenery, S R; Harrison, I; Kim, A W; Moss-Hayes, V; Jones, D G

    2011-03-13

    The sediment concentrations of total petroleum hydrocarbons (TPHs), polyaromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), Pb and (207/206)Pb isotope ratios were measured in seven cores from the middle Clyde estuary (Scotland, UK) with an aim of tracking the late Anthropocene. Concentrations of TPHs ranged from 34 to 4386 mg kg(-1), total PAHs from 19 to 16,163 μg kg(-1) and total PCBs between less than 4.3 to 1217 μg kg(-1). Inventories, distributions and isomeric ratios of the organic pollutants were used to reconstruct pollutant histories. Pre-Industrial Revolution and modern non-polluted sediments were characterized by low TPH and PAH values as well as high relative abundance of biogenic-sourced phenanthrene and naphthalene. The increasing industrialization of the Clyde gave rise to elevated PAH concentrations and PAH isomeric ratios characteristic of both grass/wood/coal and petroleum and combustion (specifically petroleum combustion). Overall, PAHs had the longest history of any of the organic contaminants. Increasing TPH concentrations and a concomitant decline in PAHs mirrored the lessening of coal use and increasing reliance on petroleum fuels from about the 1950s. Thereafter, declining hydrocarbon pollution was followed by the onset (1950s), peak (1965-1977) and decline (post-1980s) in total PCB concentrations. Lead concentrations ranged from 6 to 631 mg kg(-1), while (207/206)Pb isotope ratios spanned 0.838-0.876, indicative of various proportions of 'background', British ore/coal and Broken Hill type petrol/industrial lead. A chronology was established using published Pb isotope data for aerosol-derived Pb and applied to the cores. PMID:21282161

  15. Bioremediation of environmental pollutants

    SciTech Connect

    Madsen, E.L. . Div. of Biological Sciences)

    1992-01-01

    This paper reports on disremediation of environmental pollutants. When a tree falls in the forest, when crop residues are left in the fields, and even when spilled gasoline soaks into the ground, microorganisms go to work. Just as humans eat food to sustain life, microorganisms digest nonliving organic materials, using an astounding diversity of enzymes. In the process of deriving carbon and energy for their own use, microorganisms recycle essential nutrients such as nitrogen and phosphorus to the other species with which they share the biosphere. This has thrown many ecosystems into a unsteady state and has threatened human health. Increasing expertise in analytical chemistry and toxicology has contributed to an understanding of the problems of environmental pollution, and remedies are now being sought. Both physical and chemical processes may be essential to pollution-control technologies, but controlled biodegradation also offers significant promise.

  16. Light Pollution

    ERIC Educational Resources Information Center

    Riegel, Kurt W.

    1973-01-01

    Outdoor lighting is light pollution which handicaps certain astronomical programs. Protective measures must be adopted by the government to aid observational astronomy without sacrificing legitimate outdoor lighting needs. (PS)

  17. Air Pollution

    MedlinePlus

    ... tobacco smoke. How is air pollution linked to climate change? While climate change is a global process, it ... ozone levels are also a concern. Impacts of Climate Change on Human Health in the United States: A ...

  18. Water Pollution

    MedlinePlus

    ... to survive. Many different pollutants can harm our rivers, streams, lakes, and oceans. The three most common ... and bacteria. Rain washes soil into streams and rivers. The soil can kill tiny animals and fish ...

  19. Atmospheric pollution

    SciTech Connect

    Pickett, E.E.

    1987-01-01

    Atmospheric pollution (AP), its causes, and measures to prevent or reduce it are examined in reviews and reports presented at a workshop held in Damascus, Syria in August 1985. Topics discussed include AP and planning studies, emission sources, pollutant formation and transformation, AP effects on man and vegetation, AP control, atmospheric dispersion mechanisms and modeling, sampling and analysis techniques, air-quality monitoring, and applications. Diagrams, graphs, and tables of numerical data are provided.

  20. Influence of regional pollution and sandstorms on the chemical composition of cloud/fog at the summit of Mt. Taishan in northern China

    NASA Astrophysics Data System (ADS)

    Wang, Yan; Guo, Jia; Wang, Tao; Ding, Aijun; Gao, Jian; Zhou, Yang; Collett, Jeffrey L., Jr.; Wang, Wenxing

    2011-03-01

    Cloud/fog samples were collected during spring of 2007 in the highly polluted North China Plain in order to examine the impact of pollution and dust particles on cloud water chemistry. The volume weighted mean pH of cloud water was 3.68. The cloud acidity was shown to be associated with air mass origins. Cloud water with its air mass trajectories originating from the southern part of China was more acidic than those from northern China. Anthropogenic source and dust had obvious impact on cloud water composition as indicated by the very high mean concentrations of SO42- (1331.65 μeq L- 1), NO3- (772.44 μeq L- 1), NH4+ (1375.92 μeq L- 1) and Ca2+ (625.81 μeq L- 1) in the observation periods. During sandstorm days, cloud pH values were relatively high, and the concentrations of all the ions in cloud water reached unusual high levels. Significant decreases in the mass concentrations of PM2.5 and PM10 were observed during cloud events. The average scavenging ratio for PM2.5 and PM10 was 52.0% and 55.7%, respectively. Among the soluble ions in fine particles, NO3-, K+ and NH4+ tend to be more easily scavenged than Ca2+ and Na+.

  1. Emerging Pollutants - Part II: Treatment.

    PubMed

    Bo, Liu; Shengen, Zhang; Chang, Chein-Chi; Zhanfeng, Dong; Hongxiang, Li

    2015-10-01

    Emerging contaminants are considered as some substances of actual or potential threat to human health or environment, which include endocrine disruptors, pharmaceutical, personal care products, nanoparticles, antibiotic resistance genes and chemicals used in packaging products, etc. The disposal and treatment of emerging contaminants has become a key problem in the field of water pollution control. The purpose of this review is to summarize published researches on emerging pollutants treatment in 2014. PMID:26420107

  2. Emerging Pollutants - Part II: Treatment.

    PubMed

    Bo, Liu; Shengen, Zhang; Chang, Chein-Chi

    2016-10-01

    Emerging contaminants are considered as some substances of actual or potential threat to human health or environment, which include endocrine disruptors, pharmaceutical, personal care products, nanoparticles, antibiotic resistance genes and chemicals used in packaging products, etc. The disposal and treatment of emerging contaminants has become a key problem in the field of water pollution control. The purpose of this review is to summarize published researches on emerging pollutants treatment in 2015. PMID:27620112

  3. Significant concentration changes of chemical components of PM1 in the Yangtze River Delta area of China and the implications for the formation mechanism of heavy haze-fog pollution.

    PubMed

    Zhang, Y W; Zhang, X Y; Zhang, Y M; Shen, X J; Sun, J Y; Ma, Q L; Yu, X M; Zhu, J L; Zhang, L; Che, H C

    2015-12-15

    Since the winter season of 2013, a number of persistent haze-fog events have occurred in central-eastern China. Continuous measurements of the chemical and physical properties of PM1 at a regional background station in the Yangtze River Delta area of China from 16 Nov. to 18 Dec., 2013 revealed several haze-fog events, among which a heavy haze-fog event occurred between 6 Dec. and 8 Dec. The mean concentration of PM1 was 212μgm(-3) in the heavy haze-fog period, which was about 10 times higher than on clean days and featured a peak mass concentration that reached 298μgm(-3). Organics were the largest contributor to the dramatic rise of PM1 on heavy haze-fog days (average mass concentration of 86μgm(-3)), followed by nitrate (58μgm(-3)), sulfate (35μgm(-3)), ammonium (29μgm(-3)), and chloride (4.0μgm(-3)). Nitrate exhibited the largest increase (~20 factors), associated with a significant increase in NOx. This was mainly attributable to increased coal combustion emissions, relative to motor vehicle emissions, and was caused by short-distance pollutant transport within surrounding areas. Low-volatility oxidized organic aerosols (OA) (LV-OOA) and biomass-burning OA (BBOA) also increased sharply on heavy haze-fog days, exhibiting an enhanced oxidation capacity of the atmosphere and increased emissions from biomass burning. The strengthening of the oxidation capacity during the heavy pollution episode, along with lower solar radiation, was probably due to increased biomass burning, which were important precursors of O3. The prevailing meteorological conditions, including low wind and high relative humidity, and short distance transported gaseous and particulate matter surrounding of the sampling site, coincided with the increased pollutant concentrations mainly from biomass-burning mentioned above to cause the persistent haze-fog event in the YRD area. PMID:26298245

  4. Mixture effects at very low doses with combinations of anti-androgenic pesticides, antioxidants, industrial pollutant and chemicals used in personal care products.

    PubMed

    Orton, Frances; Ermler, Sibylle; Kugathas, Subramaniam; Rosivatz, Erika; Scholze, Martin; Kortenkamp, Andreas

    2014-08-01

    Many xenobiotics have been identified as in vitro androgen receptor (AR) antagonists, but information about their ability to produce combined effects at low concentrations is missing. Such data can reveal whether joint effects at the receptor are induced at low levels and may support the prioritisation of in vivo evaluations and provide orientations for the grouping of anti-androgens in cumulative risk assessment. Combinations of 30 AR antagonists from a wide range of sources and exposure routes (pesticides, antioxidants, parabens, UV-filters, synthetic musks, bisphenol-A, benzo(a)pyrene, perfluorooctane sulfonate and pentabromodiphenyl ether) were tested using a reporter gene assay (MDA-kb2). Chemicals were combined at three mixture ratios, equivalent to single components' effect concentrations that inhibit the action of dihydrotesterone by 1%, 10% or 20%. Concentration addition (CA) and independent action were used to calculate additivity expectations. We observed complete suppression of dihydrotestosterone effects when chemicals were combined at individual concentrations eliciting 1%, 10% or 20% AR antagonistic effect. Due to the large number of mixture components, the combined AR antagonistic effects occurred at very low concentrations of individual mixture components. CA slightly underestimated the combined effects at all mixture ratios. In conclusion, large numbers of AR antagonists from a wide variety of sources and exposure routes have the ability of acting together at the receptor to produce joint effects at very low concentrations. Significant mixture effects are observed when chemicals are combined at concentrations that individually do not induce observable AR antagonistic effects. Cumulative risk assessment for AR antagonists should apply grouping criteria based on effects where data are available, rather than on criteria of chemical similarity. PMID:24055644

  5. Mixture effects at very low doses with combinations of anti-androgenic pesticides, antioxidants, industrial pollutant and chemicals used in personal care products

    SciTech Connect

    Orton, Frances; Ermler, Sibylle; Kugathas, Subramaniam; Rosivatz, Erika; Scholze, Martin; Kortenkamp, Andreas

    2014-08-01

    Many xenobiotics have been identified as in vitro androgen receptor (AR) antagonists, but information about their ability to produce combined effects at low concentrations is missing. Such data can reveal whether joint effects at the receptor are induced at low levels and may support the prioritisation of in vivo evaluations and provide orientations for the grouping of anti-androgens in cumulative risk assessment. Combinations of 30 AR antagonists from a wide range of sources and exposure routes (pesticides, antioxidants, parabens, UV-filters, synthetic musks, bisphenol-A, benzo(a)pyrene, perfluorooctane sulfonate and pentabromodiphenyl ether) were tested using a reporter gene assay (MDA-kb2). Chemicals were combined at three mixture ratios, equivalent to single components' effect concentrations that inhibit the action of dihydrotesterone by 1%, 10% or 20%. Concentration addition (CA) and independent action were used to calculate additivity expectations. We observed complete suppression of dihydrotestosterone effects when chemicals were combined at individual concentrations eliciting 1%, 10% or 20% AR antagonistic effect. Due to the large number of mixture components, the combined AR antagonistic effects occurred at very low concentrations of individual mixture components. CA slightly underestimated the combined effects at all mixture ratios. In conclusion, large numbers of AR antagonists from a wide variety of sources and exposure routes have the ability of acting together at the receptor to produce joint effects at very low concentrations. Significant mixture effects are observed when chemicals are combined at concentrations that individually do not induce observable AR antagonistic effects. Cumulative risk assessment for AR antagonists should apply grouping criteria based on effects where data are available, rather than on criteria of chemical similarity. - Highlights: • Mixtures of AR antagonists at low individual concentrations cause complete inhibition.

  6. BIOASSAY OF COMPLEX MIXTURES OF INDOOR AIR POLLUTANTS

    EPA Science Inventory

    Indoor air pollution is a complex mixture of chemicals originating from outdoor air and indoor sources. oxicology studies of these mixtures are limited by difficulties in obtaining indoor air samples or appropriately simulated exposures. he concentration of pollutants from indoor...

  7. Water Pollution

    MedlinePlus

    We all need clean water. People need it to grow crops and to operate factories, and for drinking and recreation. Fish and wildlife depend on ... and phosphorus make algae grow and can turn water green. Bacteria, often from sewage spills, can pollute ...

  8. MOLD POLLUTION

    EPA Science Inventory

    Mold pollution is the growth of molds in a building resulting in a negative impact on the use of that structure. The negative impacts generally fall into two categories: destruction of the structure itself and adverse health impacts on the building's occupants. It is estimated...

  9. Pollution Solution

    ERIC Educational Resources Information Center

    Vannan, Donald A.

    1972-01-01

    Stresses briefly the need for individuals' actions for controlling the environmental pollution. A number of projects are suggested for teachers to involve children in this area. Simulated discussion groups of sellers'' and consumers, use of pictures, onion juice, and a water filtration contest are a few of the sources used. (PS)

  10. High-resolution mass spectrometry associated with data mining tools for the detection of pollutants and chemical characterization of honey samples.

    PubMed

    Cotton, Jérôme; Leroux, Fanny; Broudin, Simon; Marie, Mylène; Corman, Bruno; Tabet, Jean-Claude; Ducruix, Céline; Junot, Christophe

    2014-11-19

    Analytical methods for food control are mainly focused on restricted lists of well-known contaminants. This paper shows that liquid chromatography-high-resolution mass spectrometry (LC/ESI-HRMS) associated with the data mining tools developed for metabolomics can address this issue by enabling (i) targeted analyses of pollutants, (ii) detection of untargeted and unknown xenobiotics, and (iii) detection of metabolites useful for the characterization of food matrices. A proof-of-concept study was performed on 76 honey samples. Targeted analysis indicated that 35 of 83 targeted molecules were detected in the 76 honey samples at concentrations below regulatory limits. Furthermore, untargeted metabolomic-like analyses highlighted 12 chlorinated xenobiotics, 1 of which was detected in lavender honey samples and identified as 2,6-dichlorobenzamide, a metabolite of dichlobenil, a pesticide banned in France since 2010. Lastly, multivariate statistical analyses discriminated honey samples according to their floral origin, and six discriminating metabolites were characterized thanks to the MS/MS experiments. PMID:25358104

  11. Chemical fertilizers as a source of (238)U, (40)K, (226)Ra, (222)Rn, and trace metal pollutant of the environment in Saudi Arabia.

    PubMed

    Alshahri, Fatimh; Alqahtani, Muna

    2015-06-01

    The specific activities of (238)U, (226)Ra, (40)K, and (222)Rn in chemical fertilizers were measured using gamma ray spectrometer and Cr-39 detector. In this study, 21 chemical fertilizers were collected from Eastern Saudi Arabian markets. The specific activities of (238)U ranged from 23 ± 0.5 to 3900 ± 195 Bq kg(-1); (226)Ra ranged from 5.60 ± 2.80 to 392 ± 18 Bq kg(-1); and (40)K ranged from 18.4 ± 3 to 16,476 ± 820 Bq kg(-1). The radon concentrations and the radon exhalation rates were found to vary from 3.20 ± 1.20 to 1532 ± 160 Bq m(-3) and from 1.60 to 774 mBq m(-2) h(-1), respectively. Radium equivalent activities (Raeq) were calculated for the analyzed samples to assess the radiation hazards arising due to the use of these chemical fertilizers in the agriculture soil. The Raeq for six local samples (nitrogen, phosphorous, and potassium (NPK) and single superphosphate (SSP)) and one imported sample (Sulfate of Potash (SOP)) were greater than the acceptable value 370 Bq kg(-1). The total air absorbed doses rates in air 1 m above the ground (D) were calculated for all samples. All samples, except one imported granule sample diammonium phosphate (DAP), were higher than the estimated average global terrestrial radiation of 55 nGy h(-1). The highest annual effective dose was in triple super phosphate (TSP) fertilizers (2.1 mSv y(-1)). The results show that the local TSP, imported SOP, and local NPK (sample 13) fertilizers were unacceptable for use as fertilizers in agricultural soil. Furthermore, the toxic elements and trace metals (Pb, Cd, Cr, Co, Ni, Hg, and As) were determined using atomic absorption spectrometer. The concentrations of chromium in chemical fertilizers were higher than the global values. PMID:25532871

  12. Aerosol chemical properties and related pollutants measured in Dongsha Island in the northern South China Sea during 7-SEAS/Dongsha Experiment

    NASA Astrophysics Data System (ADS)

    Chuang, Ming-Tung; Chang, Shuenn-Chin; Lin, Neng-Huei; Wang, Jia-Lin; Sheu, Guey-Rong; Chang, You-Jia; Lee, Chung-Te

    2013-10-01

    Aerosol observations were conducted at Dongsha Island in two batches from 19 to 23 March and 10 to 19 April 2010. Dongsha Island is located in a remote area over the northern South China Sea (SCS), distantly surrounded by southern China, Taiwan, the Philippines, and the Indochinese Peninsula. During the study period, the average PM10 and PM2.5 mass concentrations were 26.5 ± 19.4 and 12.6 ± 6.0 μg m-3, respectively. In particular, a daily PM10 concentration of 94.1 μg m-3 caused by a yellow-dust event originating from the Asian Continent was recorded on 21 March. Other than this event, the PM2.5 and PM10-2.5 daily levels were 7.1 ± 1.2 and 12.6 ± 5.0 μg m-3, respectively, on days without pollution from anthropogenic sources in the surrounding areas. Water-soluble ions (WSIs) were the predominant components that accounted for 58.7% ± 10.5% and 51.1% ± 7.2% of the PM10 and PM2.5 mass. The second most abundant component was carbonaceous content, which accounted for 9.5% ± 4.7% and 17.5% ± 5.3% of PM10 and PM2.5, respectively. SO42- was the most abundant PM2.5 WSI, whereas the Na+ and Cl- pair was the most abundant PM10-2.5 WSI. Based on the U.S. IMPROVE protocol, the resolved carbonaceous fractions were mainly distributed in PM2.5 and influenced by coal combustion, mobile vehicles, and biomass burning. Most of the resolved WSIs in particles were in the liquid phase due to the humid environment around the northern SCS.

  13. Study on ambient concentrations of PM 10, PM 10-2.5, PM 2.5 and gaseous pollutants. Trace elements and chemical speciation of atmospheric particulates

    NASA Astrophysics Data System (ADS)

    Dongarrà, G.; Manno, E.; Varrica, D.; Lombardo, M.; Vultaggio, M.

    2010-12-01

    This study provides the first comprehensive report on mass concentrations of particulate matter of various sizes, inorganic and organic gas concentrations monitored at three sampling sites in the city of Palermo (Sicily, Italy). It also provides information on the water-soluble species and trace elements. A total of 2054 PM 10 (1333) and PM 2.5 (721) daily measurements were collected from November 2006 to February 2008. The highest mass concentrations were observed at the urban stations, average values being about two times higher than those at the suburban (control) site. Time variations in PM 10 and also PM 10-2.5 were observed at the urban stations, the highest concentrations being measured in autumn and winter. CO, NOx, NO 2, benzene, toluene and o-xylene concentrations peaked in autumn and winter, a pattern similar to those recorded for PM 10 and PM 10-2.5 mass levels, indicating the importance of traffic emissions in urban air pollution. 91% and 51% of the benzene measurements exceeded the limit of 5 μg m -3 at the two urban monitoring sites. Trace elements (As, Ba, Cr, Cu, Mo, Pb, Sb) suspected of being introduced into the atmosphere mainly by anthropogenic activities, were highly enriched with respect to local soil. Results indicate that a large fraction of PM 10 (31-47% in weight) and PM 2.5 (29% in weight) is made up of water-soluble ions. Ammonium sulphate and nitrate particles accounted for 14-29 wt% of particulate matter mass concentrations. Crustal and marine components, combined, account for 41% and 49% in PM 2.5 and PM 10, respectively. The calculated deficits in Cl - and NH 4+ ions suggest that a proportion of these ions are lost, via the formation of gaseous NH 4Cl or HCl and NH 3.

  14. Influence of meteorology and anthropogenic pollution on chemical flux divergence of the NO-NO2-O3 triad above and within a natural grassland canopy

    NASA Astrophysics Data System (ADS)

    Plake, D.; Sörgel, M.; Stella, P.; Held, A.; Trebs, I.

    2015-02-01

    The detailed understanding of surface-atmosphere exchange fluxes of reactive trace gases is a crucial precondition for reliable modelling of processes in atmospheric chemistry. Plant canopies significantly impact the atmospheric budget of trace gases. In the past, many studies focused on taller forest canopies or crops, where the bulk plant material is concentrated in the uppermost canopy layer. However, within grasslands, a land-cover class that globally covers vast terrestrial areas, the canopy structure is fundamentally different, as the main biomass is concentrated in the lowest part of the canopy. This has obvious implications for aerodynamic in-canopy transport, and consequently also impacts on global budgets of key species in atmospheric chemistry such as nitric oxide (NO), nitrogen dioxide (NO2) and ozone (O3). This study presents for the first time a comprehensive data set of directly measured in-canopy transport times and aerodynamic resistances, chemical timescales, Damköhler numbers, trace gas and micrometeorological measurements for a natural grassland canopy (canopy height = 0.6 m). Special attention is paid to the impact of contrasting meteorological and air chemical conditions on in-canopy transport and chemical flux divergence. Our results show that the grassland canopy is decoupled throughout the day. In the lowermost canopy layer, the measured transport times are fastest during nighttime, which is due to convection during nighttime and a stable stratification during daytime in this layer. The inverse was found in the layers above. During periods of low wind speed and high NOx (NO+NO2) levels, the effect of canopy decoupling on trace gas transport was found to be especially distinct. The aerodynamic resistance in the lowermost canopy layer (0.04-0.2 m) was around 1000 s m-1, which is as high as values determined previously for the lowest metre of an Amazonian rain forest canopy. The aerodynamic resistance representing the bulk canopy was found to

  15. Influence of meteorology and anthropogenic pollution on chemical flux divergence of the NO-NO2-O3 triad above and within a natural grassland canopy

    NASA Astrophysics Data System (ADS)

    Plake, D.; Sörgel, M.; Stella, P.; Held, A.; Trebs, I.

    2014-07-01

    The detailed understanding of surface-atmosphere exchange of reactive trace gas species is a crucial precondition for reliable modeling of processes in atmospheric chemistry. Plant canopies significantly impact the atmospheric budget of trace gases. In the past, many studies focused on taller forest canopies or crops, where the bulk plant material is concentrated in the uppermost canopy layer. However, within grasslands, a land-cover class that globally covers vast terrestrial areas, the canopy structure is fundamentally different, as the main biomass is concentrated in the lowest canopy part. This has obvious implications for aerodynamic in-canopy transport, and consequently also impacts on global budgets of key species in atmospheric chemistry such as nitric oxide (NO), nitrogen dioxide (NO2) and ozone (O3). This study presents for the first time a~comprehensive data set of directly measured in-canopy transport times and aerodynamic resistances, chemical timescales, Damköhler numbers, trace gas and micrometeorological measurements for a natural grassland canopy (canopy height = 0.6 m). Special attention is paid to the impact of contrasting meteorological and air chemical conditions on in-canopy transport and chemical flux divergence. Our results show that the grassland canopy is decoupled throughout the day. In the lower canopy, the measured transport times are fastest during nighttime, which is due to convection during nighttime and stable stratification during daytime in this layer. The inverse was found in the layers above. During periods of low wind speed and high NOx (NO+NO2) levels, the effect of canopy decoupling on trace gas transport was found especially distinct. The aerodynamic resistance in the lower canopy (0.04-0.2 m) was around 1000 s m-1, thus as high as values from literature representing the lowest meter of an Amazonian rain forest canopy. The aerodynamic resistance representing the bulk canopy was found to be more than 3-4 times higher as in

  16. Transformation of the chemical composition of the waters of small lakes on Kola Peninsula owing to a decrease in technogenic air pollution and to climate warming

    NASA Astrophysics Data System (ADS)

    Moiseenko, T. I.; Bazova, M. M.; Efimova, L. E.

    2014-05-01

    The emission of sulfur dioxide and metals from copper-nickel melting plants on Kola Peninsula (Russia) decreased pronouncedly over the last two decades. The decrease in the sulfate content and increase in the acid-neutralizing capability of waters were proven on the basis of the data of surveys on 75 small lakes repeated once every five years from 1990 to 2010. The variations of other parameters of the chemical composition of the waters of small lakes depend on the geological and landscape conditions of the formation of waters. The alkalinity and pH values increased in 46% of the lakes; 24% of them showed a further decrease of these parameters; and no reliable changes were traced in 31% of the lakes. The concentrations of Cu and Ni in the lacustrine water decreased 5-to 10-fold over the last two decades.

  17. Air Pollution

    PubMed Central

    Clifton, Marjorie

    1964-01-01

    Dr Marjorie Clifton describes the classification of gaseous and nongaseous constituents of air pollution and then outlines the methods of measuring these. The National Survey embraced 150 towns of all sizes throughout England and Wales and provided data on smoke and sulphur dioxide in relation to climate, topography, industrialization, population density, fuel utilization and urban development. Dr W C Turner discusses the relationship between air pollution and mortality from respiratory conditions, and particularly the incidence of chronic bronchitis. He postulates a theory that such respiratory conditions arise as an allergy to the spores of certain moulds, spore formation being encouraged by the air humidity in Greatv Britain and overcrowded and damp living conditions. He describes the results of a twenty-week study undertaken in 1962-3, showing associations between respiratory disease and levels of air pollution. Dr Stuart Carne undertook a survey in general practice to plot the patterns of respiratory illness in London during the winter of 1962-3. There were two peaks of respiratory illnesses coinciding with the fog at the beginning of December and the freeze-up from the end of December until the beginning of March. PMID:14178955

  18. Water Pollution. Project COMPSEP.

    ERIC Educational Resources Information Center

    Lantz, H. B., Jr.

    This is an introductory program on water pollution. Examined are the cause and effect relationships of water pollution, sources of water pollution, and possible alternatives to effect solutions from our water pollution problems. Included is background information on water pollution, a glossary of pollution terminology, a script for a slide script…

  19. Charting environmental pollution. [by noise measurements

    NASA Technical Reports Server (NTRS)

    Halpert, E.; Bizo, F.; Karacsonyi, Z.

    1974-01-01

    It is found that areas affected by different noxious agents are within the limits traced for high noise level areas; consequently, it is suggested that high noise pressure levels should be used as the primary indication of environmental pollution. A complex methodology is reported for charting environmental pollution due to physical, chemical and biological noxious agents on the scale of an industrial district.

  20. Historical reconstruction of major pollutant levels in the Hudson-Raritan Basin: 1880-1980. Volume 3. Chemicals and other wastes. Technical report

    SciTech Connect

    Ayers, R.U.; Ayers, L.W.

    1988-10-01

    Chapters 2-5 of Volume 3 deal with chlorinated aromatic hydrocarbon-based biocides (insecticides, acaricides, fungicides, herbicides and germicides) that have been introduced since World War II. Chapter 6 is concerned with PCB's, another class of chlorinated aromatic hydrocarbons, manufactured since 1930, that were utilized not for their biocidal properties but because of their physical properties and extraordinary chemical stability. Chapter 7 is concerned with a class of non-chlorinated polynuclear aromatic hydrocarbons (PAH's) that occurs naturally in crude oil, coal tar, pitch and asphalt and is created artificially by most combustion processes. Chapters 10 and 11 deal with other essential components of organic material (called nutrients for this reason) namely, nitrogen (N) and phosphorus (P). Again N and P are not toxic as such, but their presence may encourage the growth of algae and plankton in profusion. Finally, chapter 12 deals with water withdrawals per se. It has become clear in recent decades that the turbulence and de-oxygenation associated with most large-scale uses of water for cooling, waste dilution or other purposes, is physically harmful to spawning fish and some other ecologically important biota.

  1. [Chemical characteristics in airborne particulate matter (PM10) during a high pollution spring dust storm episode in Beijing, Tianjin and Zhangjiakou, China].

    PubMed

    Liu, Qing-Yang; Liu, Yan-Ju; Zhao, Qiang; Zhang, Ting-Ting; Zhang, Mei-Gen; Wang, Cun-Mei

    2014-08-01

    Atmospheric particulate matter (PM10) was collected at sampling locations of Beijing, Tianjin and Zhangjiakou from April 1st to May 24th, 2012. The mass concentration of PM10 and concentrations of ions, elemental carbon (EC) and organic carbon (OC) in PM10 were determined. The results showed that average mass concentration of PM10 were 233.82 microg x m(-3) for Beijing, 279.64 microg x (-3) for Tianjin and 238.13 microg x m(-3) for Zhangjiakou, respectively. Backward trajectories results confirmed dust storm events occurred from 27th to 29th April. The maximum daily mass concentrations of PM10 were 755.54 microg x m(-3) for Beijing, 831.32 microg x m(-3) for Tianjin and 582.82 microg x m(-3) for Zhangjiakou during the dust storm episodes, respectively. Water-soluble ions (Na+, NH4+, Ca2+, K+, F-, Cl-, NO3-, SO4(2-)), organic carbon (OC) and elemental carbon (EC) were major aerosol components during the dust storm episodes, and their concentrations were higher than non-dust storm days. In addition, dust storm caused increases in NO3-, SO4(2-) and enrichment of secondary organic carbon (SOC) concentration relative to OC, suggesting that chemical reaction processes involving gas-particle conversion occurred during the long-distance transport of aerosol particles. PMID:25338350

  2. Health Effects of Air Pollution.

    ERIC Educational Resources Information Center

    Environmental Education Report and Newsletter, 1985

    1985-01-01

    Summarizes health hazards associated with air pollution, highlighting the difficulty in establishing acceptable thresholds of exposure. Respiratory disease, asthma, cancer, cardiovascular disease, and other problems are addressed. Indicates that a wide range of effects from any one chemical exists and that there are differences in sensitivity to…

  3. AIR POLLUTION, OXIDATIVE STRESS AND NEUROTOXICITY.

    EPA Science Inventory

    Increased incidents of classic and variant forms of neurodegenerative diseases suggest that environmental chemicals and susceptibility factors (e.g., genetics, diseased states, obesity, etc.) may be contributory. Particulate matter (PM) is a type of air pollution that is associat...

  4. Water Pollution: Appearances Can Be Deceiving

    ERIC Educational Resources Information Center

    Raloff, Janet

    1977-01-01

    Expresses concern over the amounts of toxic chemical pollutants being discharged into fresh water supplies. Analyzes the role of the Environmental Protection Agency (EPA) in establishing and enforcing water quality standards. (CP)

  5. Method oil shale pollutant sorption/NO.sub.x reburning multi-pollutant control

    DOEpatents

    Boardman, Richard D.; Carrington, Robert A.

    2008-06-10

    A method of decreasing pollutants produced in a combustion process. The method comprises combusting coal in a combustion chamber to produce at least one pollutant selected from the group consisting of a nitrogen-containing pollutant, sulfuric acid, sulfur trioxide, carbonyl sulfide, carbon disulfide, chlorine, hydroiodic acid, iodine, hydrofluoric acid, fluorine, hydrobromic acid, bromine, phosphoric acid, phosphorous pentaoxide, elemental mercury, and mercuric chloride. Oil shale particles are introduced into the combustion chamber and are combusted to produce sorbent particulates and a reductant. The at least one pollutant is contacted with at least one of the sorbent particulates and the reductant to decrease an amount of the at least one pollutant in the combustion chamber. The reductant may chemically reduce the at least one pollutant to a benign species. The sorbent particulates may adsorb or absorb the at least one pollutant. A combustion chamber that produces decreased pollutants in a combustion process is also disclosed.

  6. Noise Pollution

    MedlinePlus

    ... menu Learn the Issues Air Chemicals and Toxics Climate Change Emergencies Greener Living Health and Safety Land and Cleanup Pesticides Waste Water Science & Technology Air Climate Change Ecosystems Health Land, Waste and Cleanup Pesticides Substances ...

  7. Coupling passive air sampling with emission estimates and chemical fate modeling for persistent organic pollutants (POPs): a feasibility study for Northern Europe.

    PubMed

    Gioia, Rosalinda; Sweetman, Andy J; Jones, Kevin C

    2007-04-01

    Passive air samplers (polyurethane foam disks) were deployed at 23 background locations along a broadly west-east transect in 8 northern European countries and analyzed for PCBs, PBDEs, PAHs, and a range of organochlorine pesticides (HCB, DDTs, and DDEs). PCBs and PAHs were highest at the center of the transect (Denmark) and lowest in northern Norway. HCB was relatively uniformly distributed, reflecting its persistence and high degree of mixing in air. Higher DDE and DDT levels occurred in Eastern Europe and at several sites in Central Europe. PBDE levels were generally similar at all sites, but lower for some locations in Eastern Europe and Ireland. Emissions information for PCBs, HCB, and PBDEs was used as input for a multi-media chemical fate model, to generate predicted air concentrations and compare with these measured values. Different scenarios were highlighted by this exercise: (i) country and compound combinations where the national inventory gave predicted air concentrations in close agreement with those measured (e.g., PCBs in the UK); (ii) country and compound combinations where predicted concentrations were well below those measured, but where advection of emissions from elsewhere is likely to be important (e.g., PCBs in Norway); (iii) consistent underestimation of compound concentrations by the emissions modeling (i.e., HCB); and (iv) general overestimation of ambient concentrations (i.e., PBDEs). Air mass trajectory analysis showed the likely role of long-range atmospheric transport (LRAT) on national levels. In general, advection from the south and west of Europe appeared to contribute to ambient POPs levels for countries in the center and northeast of the transect. Guidelines are presented as to how countries that want to assess their POPs source inventories can do so with this relatively cheap initial screening approach. PMID:17438758

  8. Sorbents for Trapping Organic Pollutants From Air.

    PubMed

    Ligor; Gorecka; Buszewski

    1998-01-01

    A series of siliceous adsorbents with chemically bonded phases (CBPs) of different polarity were tested as sorbents for trapping air pollutants (petroleum ether) using controlled setup. Moreover, special attention was paid to the potential role of metal impurities as strong adsorption sites. Sorbents were characterized by various physico-chemical methods, such as porosimetry, inductively coupled plasma (ICP) analysis, elemental analysis, derivatography, and gas chromatography. Trapping tubes were utilized for sorption of toxic pollutants from indoor air. PMID:10602615

  9. USER'S GUIDE FOR PEM-2: POLLUTION EPISODIC MODEL (VERSION 2)

    EPA Science Inventory

    The Pollution Episodic Model Version 2 (PEM-2) is an urban-scale model designed to predict short term average ground-level concentrations and deposition fluxes of one or two gaseous or particulate pollutants at multiple receptors. The two pollutants may be non-reactive, or chemic...

  10. Teaching Applied Chemistry in a Pollution Control Context.

    ERIC Educational Resources Information Center

    Sell, Nancy J.

    1982-01-01

    Discusses rationale behind and content of a course (Industrial Pollution Control Techniques) combining knowledge from fields of industrial chemistry and chemical engineering and utilizing this knowledge in the context of understanding pollution problems and potential methods of pollution control. (Author/SK)

  11. A Course on the Physics and Chemistry of Pollution

    ERIC Educational Resources Information Center

    Hodges, Laurent

    1971-01-01

    Describes a course on environmental pollution which stresses physical and chemical principles. Course presents a unified discussion of air and water pollution and solid waste with special treatment of pesticides, thermal pollution, radioactivity, and electric power generation. Uses historical and current statistics extensively to set pollution…

  12. Contemporary threats and air pollution

    NASA Astrophysics Data System (ADS)

    Hopke, Philip K.

    It is now well understood that air pollution produces significant adverse health effects in the general public and over the past 60 years, there have been on-going efforts to reduce the emitted pollutants and their resulting health effects. There are now shifting patterns of industrialization with many heavily polluting industries moving from developed countries with increasingly stringent air quality standards to the developing world. However, even in decreasing concentrations of pollutants, health effects remain important possibly as a result of changes in the nature of the pollutants as new chemicals are produced and as other causes of mortality and morbidity are reduced. In addition, there is now the potential for deliberate introduction of toxic air pollutants by local armed conflicts and terrorists. Thus, there are new challenges to understand the role of the atmospheric environment on public health in this time of changing economic and demographic conditions overlaid with the willingness to indirectly attack governments and other established entities through direct attacks on the general public.

  13. PHARMACEUTICALS & PERSONAL CARE PRODUCTS AS ENVIRONMENTAL POLLUTANTS FROM EVERYDAY ACTIVITIES

    EPA Science Inventory

    Those chemical pollutants that are regulated under various international, federal, and state programs represent but a small fraction of the universe of chemicals that occur in the environment as a result of both natural processes and human influence.

  14. MODULATING STORM DRAIN FLOWS TO REDUCE STREAM POLLUTANT CONCENTRATIONS

    EPA Science Inventory

    Pathogen and toxic chemical concentrations above the chemical and toxicity water quality standards in creeks and rivers pose risks to human health and aquatic ecosystems. Storm drains discharging into these watercourses often contribute significantly to elevating pollutant concen...

  15. SAMPLING FOR ORGANIC CHEMICALS IN AIR

    EPA Science Inventory

    Organic chemicals by far account for the majority of pollutants found in air. ore than 90% of the 75,000 chemicals listed in EPA's Toxic Substances Control Act Chemical Substance Inventory and 88% of the 189 Hazardous Air Pollutants (HAPS) named in the Clean Air Act Amendments of...

  16. Indoor Air Pollution

    MedlinePlus

    We usually think of air pollution as being outdoors, but the air in your house or office could also be polluted. Sources of indoor pollution include Mold and pollen Tobacco smoke Household products ...

  17. PHARMACEUTICALS AND PERSONAL CARE PRODUCTS (PPCPS) AS ENVIRONMENTAL POLLUTANTS: POLLUTION FROM PERSONAL ACTIONS

    EPA Science Inventory

    The occurrence of pharmaceuticals and personal care products (PPCPs) as trace environmental pollutants is a multifaceted issue whose scope of concerns continues to expand. PPCPs comprise thousands of distinct chemicals from numerous therapeutic and consumer classes. They typicall...

  18. PHARMACEUTICALS AND PERSONAL CARE PRODUCTS (PPCP'S) AS ENVIRONMENTAL POLLUTANTS: POLLUTION FROM PERSONAL ACTIONS

    EPA Science Inventory

    The occurrence of pharmaceuticals and personal care products (PPCPs) as trace environmental pollutants is a multifaceted issue whose scope of concerns continues to expand. PPCPs comprise thousands of distinct chemicals from numerous therapeutic and consumer classes. They typical...

  19. Understanding Environmental Pollution

    NASA Astrophysics Data System (ADS)

    Hill, Marquita K.

    2004-09-01

    Introducing pollution issues to students and others with little scientific background, this new edition of a well-received textbook has been completely revised and updated. Starting with the definition of pollution and how pollutants behave, it progresses to covering air and water pollution basics, pollution and global change, solid waste, and pollution in the home. First Edition Hb (1997): 0-521-56210-4 First Edition Pb (1997): 0-521-56680-0

  20. PHARMACEUTICALS AS UBIQUITOUS POLLUTANTS: SIGNIFICANCE, CONCERNS, SOLUTIONS

    EPA Science Inventory

    Those chemical pollutants that are regulated under various international, federal, and state programs represent but a small fraction of the universe of chemicals that occur in the environment as a result of both natural processes and human influence. Although this galaxy of targe...

  1. Air quality simulation over South Asia using Hemispheric Transport of Air Pollution version-2 (HTAP-v2) emission inventory and Model for Ozone and Related chemical Tracers (MOZART-4)

    NASA Astrophysics Data System (ADS)

    Surendran, Divya E.; Ghude, Sachin D.; Beig, G.; Emmons, L. K.; Jena, Chinmay; Kumar, Rajesh; Pfister, G. G.; Chate, D. M.

    2015-12-01

    This study presents the distribution of tropospheric ozone and related species for South Asia using the Model for Ozone and Related chemical Tracers (MOZART-4) and Hemispheric Transport of Air Pollution version-2 (HTAP-v2) emission inventory. The model present-day simulated ozone (O3), carbon monoxide (CO) and nitrogen dioxide (NO2) are evaluated against surface-based, balloon-borne and satellite-based (MOPITT and OMI) observations. The model systematically overestimates surface O3 mixing ratios (range of mean bias about: 1-30 ppbv) at different ground-based measurement sites in India. Comparison between simulated and observed vertical profiles of ozone shows a positive bias from the surface up to 600 hPa and a negative bias above 600 hPa. The simulated seasonal variation in surface CO mixing ratio is consistent with the surface observations, but has a negative bias of about 50-200 ppb which can be attributed to a large part to the coarse model resolution. In contrast to the surface evaluation, the model shows a positive bias of about 15-20 × 1017 molecules/cm2 over South Asia when compared to satellite derived CO columns from the MOPITT instrument. The model also overestimates OMI retrieved tropospheric column NO2 abundance by about 100-250 × 1013 molecules/cm2. A response to 20% reduction in all anthropogenic emissions over South Asia shows a decrease in the anuual mean O3 mixing ratios by about 3-12 ppb, CO by about 10-80 ppb and NOX by about 3-6 ppb at the surface level. During summer monsoon, O3 mixing ratios at 200 hPa show a decrease of about 6-12 ppb over South Asia and about 1-4 ppb over the remote northern hemispheric western Pacific region.

  2. CHEMICALS IN THE ENVIRONMENT: OPPT CHEMICAL FACT SHEETS

    EPA Science Inventory

    The OPPT Chemical Fact Sheets are produced by the Office of Pollution, Prevention and Toxics to provide a brief summary of information on selected chemicals. The Fact Sheets cover each chemicals identity, production and use, environmental fate, and health and environmental effect...

  3. Criteria air pollutants and toxic air pollutants.

    PubMed Central

    Suh, H H; Bahadori, T; Vallarino, J; Spengler, J D

    2000-01-01

    This review presents a brief overview of the health effects and exposures of two criteria pollutants--ozone and particulate matter--and two toxic air pollutants--benzene and formaldehyde. These pollutants were selected from the six criteria pollutants and from the 189 toxic air pollutants on the basis of their prevalence in the United States, their physicochemical behavior, and the magnitude of their potential health threat. The health effects data included in this review primarily include results from epidemiologic studies; however, some findings from animal studies are also discussed when no other information is available. Health effects findings for each pollutant are related in this review to corresponding information about outdoor, indoor, and personal exposures and pollutant sources. Images Figure 3 Figure 8 Figure 9 PMID:10940240

  4. Aerosols and environmental pollution

    NASA Astrophysics Data System (ADS)

    Colbeck, Ian; Lazaridis, Mihalis

    2010-02-01

    The number of publications on atmospheric aerosols has dramatically increased in recent years. This review, predominantly from a European perspective, summarizes the current state of knowledge of the role played by aerosols in environmental pollution and, in addition, highlights gaps in our current knowledge. Aerosol particles are ubiquitous in the Earth’s atmosphere and are central to many environmental issues; ranging from the Earth’s radiative budget to human health. Aerosol size distribution and chemical composition are crucial parameters that determine their dynamics in the atmosphere. Sources of aerosols are both anthropogenic and natural ranging from vehicular emissions to dust resuspension. Ambient concentrations of aerosols are elevated in urban areas with lower values at rural sites. A comprehensive understanding of aerosol ambient characteristics requires a combination of measurements and modeling tools. Legislation for ambient aerosols has been introduced at national and international levels aiming to protect human health and the environment.

  5. 40 CFR Appendix: Table 1 to... - List of Hazardous Air Pollutants (HAP) for Subpart HHH

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 11 2010-07-01 2010-07-01 true List of Hazardous Air Pollutants (HAP... AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants From... HHH of Part 63—List of Hazardous Air Pollutants (HAP) for Subpart HHH CAS Number a Chemical name...

  6. The impact of pollution on the voice

    SciTech Connect

    Sataloff, R.T. )

    1992-06-01

    Pollution is responsible for the presence of toxic substances and conditions throughout our environment. Inhalation of toxic pollutants may affect the voice adversely by direct laryngeal injury, by causing pulmonary dysfunction that results in voice maladies, or through impairments elsewhere in the vocal tract. Ingested substances--especially those that have neurolaryngologic effects--may also adversely affect the voice. Non-chemical environmental pollutants such as noise may also be responsible for voice abnormalities. Most of the information about the effects of pollution on the voice is anecdotal. Equipment and techniques that permit valid, reliable voice research have recently become available; and studies on the impact of pollution on communication, and specifically on voice, should be encouraged.33 references.

  7. Chemical Engineering in the Spectrum of Knowledge.

    ERIC Educational Resources Information Center

    Sutija, Davor P.; Prausnitz, John M.

    1990-01-01

    Provides three classroom examples showing students how chemical engineering techniques can supply partial answers to social questions, such as environmental issues. Examples are depletion of the ozone layer, nuclear winter, and air pollution by chemical solvents. (YP)

  8. PREDICTING CHEMICAL REACTIVITY BY COMPUTER

    EPA Science Inventory

    Mathematical models for predicting the fate of pollutants in the environment require reactivity parameter values--that it, the physical and chemical constants that govern reactivity. lthough empirical structure-activity relationships have been developed that allow estimation of s...

  9. [Current data on atmospheric pollutions].

    PubMed

    Festy, B; Petit-Coviaux, F; Le Moullec, Y

    1991-01-01

    Atmospheric pollutions (AP) are very important for human health and ecological equilibrium. They may be natural or anthropogenic and in this later case they can appear outdoor or indoor. Urban air pollution is the most known form of AP. Its main sources are industries, individual and collective heating and now mainly automobile traffic in most cities. Classical AP indicators are SO2, particles, NOx, CO and Pb measured in networks. Important factors of AP are amounts of pollutants emitted and local climatic and meteorological characteristics. Health effects of AP peaks and of AP background levels are not well known. But generally, mean AP levels of SO2 and particles decreased in the last years in most towns as the consequence of collective actions on the three main sources of AP and on fuels, emission and immission levels; but more is wanted about motor-cars. Progress are necessary for limitation of three major ecological risks: "acid-rain" (SO2 and NOx derivatives, ozone,...) which participates in lake and forest attacks; "green house" effects whose air CO2 concentration increase is the main responsible, and stratospheric ozone depletion mainly due to freons (CFC); the consequences of these two last phenomena are not well known but ecological and health risk exist. Besides, indoor air pollution (IAP) is very important because we live more than 20 h a day indoor. IAP may be occupational (a lot of chemical or biological agents) or not. In the later case air pollutants are very various: CO, NOx and particles from heating or cooking, formaldehyde from wood glue, plywood or urea-formol foams, radon and derivatives in some granitic countries, odd jobs products, cosmetics, aero-allergens of chemical or biological origins, microbes,... Environmental tobacco smoke (ETS) is also an important pollutant complex. Risks of IAP are real or potential: acute risk is obvious for CO, aero-allergens, formaldehyde, NOx,...); irritations are produced by ETS, formaldehyde, solvants

  10. Optimal pollution trading without pollution reductions

    EPA Science Inventory

    Many kinds of water pollution occur in pulses, e.g., agricultural and urban runoff. Ecosystems, such as wetlands, can serve to regulate these pulses and smooth pollution distributions over time. This smoothing reduces total environmental damages when “instantaneous” damages are m...

  11. Air pollution and cardiovascular disease.

    PubMed

    Franklin, Barry A; Brook, Robert; Arden Pope, C

    2015-05-01

    An escalating body of epidemiologic and clinical research provides compelling evidence that exposure to fine particulate matter air pollution contributes to the development of cardiovascular disease and the triggering of acute cardiac events. There are 3 potential mediating pathways that have been implicated, including "systemic spillover," autonomic imbalance, and circulating particulate matter constituents. Further support that the increased morbidity and mortality attributed to air pollution comes from studies demonstrating the adverse cardiovascular effects of even brief periods of exposure to secondhand smoke. Accordingly, persons with known or suspected cardiovascular disease, the elderly, diabetic patients, pregnant women, and those with pulmonary disease should be counseled to limit leisure-time outdoor activities when air pollution is high. Recognizing the insidious and pervasive nature of air pollution, and the associated odds ratios and population attributable fractions for this widely underappreciated chemical trigger of acute cardiovascular events, may serve to maximize the potential for cardiovascular risk reduction by addressing at least a portion of the 10%-25% incidence of coronary disease that is unexplained by traditional risk factors. PMID:25882781

  12. Tracking toxic chemicals

    NASA Astrophysics Data System (ADS)

    Showstack, Randy

    A new report tracking industrial pollution in North America indicates some good news, in terms of downward trends in the release and transfer of these substances.The July report, which tracks 165 chemicals released in the United States and Canada, shows that the total amount of 3.2 million tonnes of chemical releases and transfers from industrial facilities tracked by the North American Commission for Environmental Cooperation (CEC) decreased by 2% overall from 1995 to 1998.

  13. Regional air pollution over Malaysia

    NASA Astrophysics Data System (ADS)

    Krysztofiak, G.; Catoire, V.; Dorf, M.; Grossmann, K.; Hamer, P. D.; Marécal, V.; Reiter, A.; Schlager, H.; Eckhardt, S.; Jurkat, T.; Oram, D.; Quack, B.; Atlas, E.; Pfeilsticker, K.

    2012-12-01

    During the SHIVA (Stratospheric Ozone: Halogen Impacts in a Varying Atmosphere) campaign in Nov. and Dec. 2011 a number of polluted air masses were observed in the marine and terrestrial boundary layer (0 - 2 km) and in the free troposphere (2 - 12 km) over Borneo/Malaysia. The measurements include isoprene, CO, CO2, CH4, N2O, NO2, SO2 as primary pollutants, O3 and HCHO as secondary pollutants, and meteorological parameters. This set of trace gases can be used to fingerprint different sources of local and regional air pollution (e.g., biomass burning and fossil fuel burning, gas flaring on oil rigs, emission of ships and from urban areas, volcanic emissions, and biogenic emissions). Individual sources and location can be identified when the measurements are combined with a nested-grid regional scale chemical and meteorological model and lagrangian particle dispersion model (e.g., CCATT-BRAMS and FLEXPART). In the case of the former, emission inventories of the primary pollutants provide the basis for the trace gas simulations. In this region, the anthropogenic influence on air pollution seems to dominate over natural causes. For example, CO2 and CH4 often show strong correlations with CO, suggesting biomass burning or urban fossil fuel combustion dominates the combustion sources. The study of the CO/CO2 and CH4/CO ratios can help separate anthropogenic combustion from biomass burning pollution sources. In addition, these ratios can be used as a measure of combustion efficiency to help place the type of biomass burning particular to this region within the wider context of fire types found globally. On several occasions, CH4 enhancements are observed near the ocean surface, which are not directly correlated with CO enhancements thus indicating a non-combustion-related CH4 source. Positive correlations between SO2 and CO show the anthropogenic influence of oil rigs located in the South China Sea. Furthermore, SO2 enhancements are observed without any increase in CO

  14. [Literature review of pollutants

    SciTech Connect

    1999-08-01

    This review focuses on the following: the measurement and monitoring of pollutants; treatment systems, including physicochemical processes, as well as biological processes; industrial wastes (management); hazardous wastes (waste management as well as remediation); and the fate and effects of pollutants.

  15. Exploring Oil Pollution

    ERIC Educational Resources Information Center

    Rillo, Thomas J.

    1974-01-01

    Discusses damages of oil tanker spillage to the marine organisms and scientists' research in oil pollution removal techniques. Included is a list of learning activities concerning the causes and effects of oil pollution and methods of solving the problem. (CC)

  16. The Pollution Solution.

    ERIC Educational Resources Information Center

    Stephens, Lillian

    1981-01-01

    Presented are methods to help teachers continue the environmental awareness programs they have already started by providing up-to-date information and activities dealing with air pollution, water pollution, and solid waste disposal. (Author/KC)

  17. Kookaburras and Polluted Streams.

    ERIC Educational Resources Information Center

    Clark, Julie; Harrison, Terry

    2000-01-01

    Discusses the role of teachers in environmental education. Presents two simulations on water pollution in order to explore pollution of the environment and investigate the life and ecology of a native bird or investigate predator/prey relationships. (ASK)

  18. Indoor Air Pollution

    MedlinePlus

    We usually think of air pollution as being outdoors, but the air in your house or office could also be polluted. Sources of indoor pollution ... is known as sick building syndrome. Usually indoor air quality problems only cause discomfort. Most people feel ...

  19. FACILITY POLLUTION PREVENTION GUIDE

    EPA Science Inventory

    The U.S. Environmental Protection Agency (U.S. EPA) has developed the Facility Pollution Prevention Guide for those who are interested in and responsible for pollution prevention in industrial or service facilities. t summarizes the benefits of a company-wide pollution prevention...

  20. Discriminatory Air Pollution

    ERIC Educational Resources Information Center

    McCaull, Julian

    1976-01-01

    Described are the patterns of air pollution in certain large urban areas. Persons in poverty, in occupations below the management or professional level, in low-rent districts, and in black population are most heavily exposed to air pollution. Pollution paradoxically is largely produced by high energy consuming middle-and upper-class households.…

  1. Air Pollution, Teachers' Edition.

    ERIC Educational Resources Information Center

    Lavaroni, Charles W.; O'Donnell, Patrick A.

    One of three in a series about pollution, this teacher's guide for a unit on air pollution is designed for use in junior high school grades. It offers suggestions for extending the information and activities contained in the textual material for students. Chapter 1 discusses the problem of air pollution and involves students in processes of…

  2. Air Pollution Training Programs.

    ERIC Educational Resources Information Center

    Public Health Service (DHEW), Rockville, MD.

    This catalog lists the universities, both supported and not supported by the Division of Air Pollution, which offer graduate programs in the field of air pollution. The catalog briefly describes the programs and their entrance requirements, the requirements, qualifications and terms of special fellowships offered by the Division of Air Pollution.…

  3. Noise Pollution, Teachers' Edition.

    ERIC Educational Resources Information Center

    O'Donnell, Patrick A.; Lavaroni, Charles W.

    One of three in a series about pollution, this teacher's guide for a unit on noise pollution is designed for use in junior high school grades. It offers suggestions for extending the information and activities contained in the textual material for students. Chapter 1 discusses the problem of noise pollution and involves students in processes of…

  4. Air pollution and society

    NASA Astrophysics Data System (ADS)

    Brimblecombe, P.

    2010-12-01

    Air pollution is as much a product of our society as it is one of chemistry and meteorology. Social variables such as gender, age, health status and poverty are often linked with our exposure to air pollutants. Pollution can also affect our behaviour, while regulations to improve the environment can often challenge of freedom.

  5. The Other Water Pollution

    ERIC Educational Resources Information Center

    Barton, Kathy

    1978-01-01

    Nonpoint source pollution, water pollution not released at one specific identifiable point, now accounts for 50 percent of the nation's water pollution problem. Runoff is the primary culprit and includes the following sources: agriculture, mining, hydrologic modifications, and urban runoff. Economics, legislation, practices, and management of this…

  6. Water Pollution, Teachers' Edition.

    ERIC Educational Resources Information Center

    Lavaroni, Charles W.; And Others

    One of three in a series about pollution, this teacher's guide for a unit on water pollution is designed for use in junior high school grades. It offers suggestions for extending the information and activities contained in the textual material for students. Chapter 1 discusses the problem of water pollution and involves students in processes of…

  7. 48 CFR 52.223-5 - Pollution Prevention and Right-to-Know Information.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ...) Definitions. As used in this clause— Toxic chemical means a chemical or chemical category listed in 40 CFR 372... 48 Federal Acquisition Regulations System 2 2013-10-01 2013-10-01 false Pollution Prevention and... Provisions and Clauses 52.223-5 Pollution Prevention and Right-to-Know Information. As prescribed in...

  8. 48 CFR 52.223-5 - Pollution Prevention and Right-to-Know Information.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ...) Definitions. As used in this clause— Toxic chemical means a chemical or chemical category listed in 40 CFR 372... 48 Federal Acquisition Regulations System 2 2012-10-01 2012-10-01 false Pollution Prevention and... Provisions and Clauses 52.223-5 Pollution Prevention and Right-to-Know Information. As prescribed in...

  9. 48 CFR 52.223-5 - Pollution Prevention and Right-to-Know Information.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ...) Definitions. As used in this clause— Toxic chemical means a chemical or chemical category listed in 40 CFR 372... 48 Federal Acquisition Regulations System 2 2011-10-01 2011-10-01 false Pollution Prevention and... Provisions and Clauses 52.223-5 Pollution Prevention and Right-to-Know Information. As prescribed in...

  10. Evaluating Exposures to Chemical and Non-Chemical Stressors in a Cumulative Risk Assessment

    EPA Science Inventory

    Characteristically toxicological and epidemiological studies involving chemical mixtures (e.g., multi-pollutant exposures) have been increasing. Human health assessment of chemical and nonchemical mixture risk remains rare. Recently, there has been an increased emphasis on integr...

  11. Anthropogenic pollutants: a threat to ecosystem sustainability?

    PubMed Central

    Rhind, S. M.

    2009-01-01

    Pollutants, including synthetic organic materials and heavy metals, are known to adversely affect physiological systems in all animal species studied to date. While many individual chemicals can perturb normal functions, the combined actions of multiple pollutants are of particular concern because they can exert effects even when each individual chemical is present at concentrations too low to be individually effective. The biological effects of pollutants differ greatly between species reflecting differences in the pattern of exposure, routes of uptake, metabolism following uptake, rates of accumulation and sensitivity of the target organs. Thus, understanding of the effects of pollutants on wildlife and ecosystems will require detailed study of many different species, representing a wide range of taxa. However, such studies can be informed by knowledge obtained in more controlled conditions which may indicate likely mechanisms of action and suitable endpoint measurements. Responses may be exacerbated by interactions between the effects of pollutants and environmental stressors, such as under-nutrition or osmotic stresses and so changes in such variables associated with climatic changes may exacerbate physiological responses to pollutant burdens. PMID:19833650

  12. Environmental costs of mercury pollution.

    PubMed

    Hylander, Lars D; Goodsite, Michael E

    2006-09-01

    Mercury (Hg) has been used for millennia in many applications, primarily in artisanal mining and as an electrode in the chlor-alkali industry. It is anthropogenically emitted as a pollutant from coal fired power plants and naturally emitted, primarily from volcanoes. Its unique chemical characteristics enable global atmospheric transport and it is deposited after various processes, ultimately ending up in one of its final sinks, such as incorporated into deep sediment or bioaccumulated, primarily in the marine environment. All forms of Hg have been established as toxic, and there have been no noted biological benefits from the metal. Throughout time, there have been notable incidents of Hg intoxication documented, and the negative health effects have been documented to those chronically or acutely exposed. Today, exposure to Hg is largely diet or occupationally dependent, however, many are exposed to Hg from their amalgam fillings. This paper puts a tentative monetary value on Hg polluted food sources in the Arctic, where local, significant pollution sources are limited, and relates this to costs for strategies avoiding Hg pollution and to remediation costs of contaminated sites in Sweden and Japan. The case studies are compiled to help policy makers and the public to evaluate whether the benefits to the global environment from banning Hg and limiting its initial emission outweigh the benefits from its continued use or lack of control of Hg emissions. The cases we studied are relevant for point pollution sources globally and their remediation costs ranged between 2,500 and 1.1 million US dollars kg(-1) Hg isolated from the biosphere. Therefore, regulations discontinuing mercury uses combined with extensive flue gas cleaning for all power plants and waste incinerators is cost effective. PMID:16442592

  13. Sensing land pollution.

    NASA Technical Reports Server (NTRS)

    Bowden, L. W.

    1971-01-01

    Land pollution is described in numerous ways by various societies. Pollutants of land are material by-products of human activity and range from environmentally ineffective to positively toxic. The pollution of land by man is centuries old and correlates directly with economy, technology and population. In order to remotely sense land pollution, standards or thresholds must be established. Examples of the potential for sensing land pollution and quality are presented. The technological capabilities for remotely sensed land quality is far advanced over the judgment on how to use the sensed data. Until authoritative and directive decisions on land pollution policy are made, sensing of pollutants will be a random, local and academic affair.

  14. Water Pollution, Causes and Cures.

    ERIC Educational Resources Information Center

    Manufacturing Chemists Association, Washington, DC.

    This commentary on sources of water pollution and water pollution treatment systems is accompanied by graphic illustrations. Sources of pollution such as lake bottom vegetation, synthetic organic pollutants, heat pollution, radioactive substance pollution, and human and industrial waste products are discussed. Several types of water purification…

  15. Linking Urban Air Pollution to Global Tropospheric Chemistry and Climate

    NASA Technical Reports Server (NTRS)

    Wang, Chien

    2005-01-01

    The two major tasks of this project are to study: (a) the impact of urban nonlinear chemistry on chemical budgets of key pollutants in non-urban areas; and (b) the influence of air pollution control strategies in selected metropolitan areas, particularly of emerging economies in East and South Asia, on tropospheric chemistry and hence on regional and global climate.

  16. Monitoring of air pollution by plants methods and problems

    SciTech Connect

    Steubing, L.; Jager, H.J.

    1985-01-01

    Ecosystem pollution is often discovered too late for preventive measure to be implemented. Papers include the topics of methods and problems of bioindication of air pollution. The participants discussed passive and active biological monitoring, including mapping of natural vegetation (lichens and mosses, for example) and plant exposure. Morphological and microscopical studies, chemical, physiological and biochemical investigations are presented.

  17. Chemistry and Pollution of the Stratosphere.

    ERIC Educational Resources Information Center

    Donovan, R. J.

    1978-01-01

    Presents an outline of the chemistry involved and the steps which are being taken to gain a better understanding of the stratosphere. Chemical composition of natural stratosphere and depletion of ozone in the stratosphere by man-made pollutants are covered. (HM)

  18. Water Conservation and Nonpoint Source Pollution.

    ERIC Educational Resources Information Center

    Farrell-Poe, Kitt

    This book contains science activities that are designed to make learning and demonstrating nonpoint source pollution concepts exciting and fun. These activities can either be used alone or with an existing water resources education curricula. Activities include: Water Tasting, Acting Out the Hydrologic Cycle, Concentration of Chemical Pollutants…

  19. Immune Response in Mussels To Environmental Pollution.

    ERIC Educational Resources Information Center

    Pryor, Stephen C.; Facher, Evan

    1997-01-01

    Describes the use of mussels in measuring the extent of chemical contamination and its variation in different coastal regions. Presents an experiment to introduce students to immune response and the effects of environmental pollution on marine organisms. Contains 14 references. (JRH)

  20. Article "403. Toxicology of Persistent Organic Pollutants (POPs)"

    EPA Science Inventory

    Persistent Organic Pollutants (POPs) are all synthetic chemicals, either intentionally or unintentionally produced/released. Some POPs are pesticides. Others are industrial products or unintended by-products resulting from industrial processes or combustions (see figure 1). POPs ...

  1. Air Pollution Instrumentation: A Trend toward Physical Methods

    ERIC Educational Resources Information Center

    Maugh, Thomas H., II

    1972-01-01

    Reviews reasons for the trend from wet chemical'' analytic techniques for measuring air pollutants toward physical methods based upon chemiluminescence, electrochemical transduction, flame ionization coupled with gas chromotography, and spectroscopy. (AL)

  2. NOXIOUS TRACE GASES IN THE AIR. PART II. HALOGENATED POLLUTANTS

    EPA Science Inventory

    The chemistry of chlorofluorocarbons and other halogenated air pollutants is discussed. A summary is presented of the present levels of concentration of such compounds, along with comments on anticipated increases. Chemical reactions that transform and remove halogenated pollutan...

  3. PHARMACEUTICALS AND PERSONAL CARE PRODUCTS (PPCPS) AS ENVIRONMENTAL POLLUTANTS

    EPA Science Inventory

    The occurrence of pharmaceuticals and personal care products (PPCPs) as trace environmental pollutants is a multifaceted issue whose scope of concerns continues to expand. PPCPs comprise thousands of distinct chemicals from numerous therapeutic and consumer classes. They typical...

  4. PHARMACEUTICALS AND PERSONAL CARE PRODUCTS: DIVERSE GALAXY OF ENVIRONMENTAL POLLUTANTS

    EPA Science Inventory

    The occurrence of pharmaceuticals and personal care products (PPCPs) as trace environmental pollutants is a multifaceted issue whose scope of concerns continues to expand. PPCPs comprise thousands of distinct chemicals from numerous therapeutic and consumer classes. They typical...

  5. STREAM MODELS FOR CALCULATING POLLUTIONAL EFFECTS OF STORMWATER RUNOFF

    EPA Science Inventory

    Three related studies are described which provide the means to quantify the pollutional and hydraulic effects on flowing streams caused by stormwater runoff. Mathematical stream models were developed to simulate the biological, physical, chemical, and hydraulic reactions which oc...

  6. Recent trends of persistent organic pollutants in air in central Europe - Air monitoring in combination with air mass trajectory statistics as a tool to study the effectivity of regional chemical policy

    NASA Astrophysics Data System (ADS)

    Dvorská, A.; Lammel, G.; Holoubek, I.

    We use air mass back trajectory analysis of persistent organic pollutant (POP) levels monitored at a regional background site, Košetice, Czech Republic, as a tool to study the effectiveness of emission reduction measures taken in the last decade in the region. The representativity of the chosen trajectory starting height for air sampling near ground was ensured by excluding trajectories starting at time of inversions lower than their starting height. As the relevant pollutant sources are exclusively located in the atmospheric boundary layer, trajectory segments above this layer were also excluded from the analysis. We used a linear time weight to account for the influence of dispersion and deposition on trace components abundances and to quantify the ground source loading, a continuous measure for the influence of surface emissions. Hexachlorocyclohexanes (HCHs), hexachlorobenzene (HCB), polychlorinated biphenyls (PCBs), DDT, and two time periods, the years 1997-1999 and 2004-2006, were studied. The pollutant levels transported to Košetice decreased for all substances except HCB. Except for lindane seasonal emissions were insignificant. Increasing emissions of HCB were at least partly linked to the 2002 floods in the Danube basin. Major emissions of 1997-1999 which decreased significantly were in France (lindane), western Poland, Hungary and northern ex-Yugoslavia (technical HCH), and the Czech Republic (DDT). Emissions remaining in 2004-2006 include HCB and DDT in the northern Czech Republic, HCB and PCBs in Germany. Besides changes in emission strength meteorological factors influence the level of transported pollutant concentrations. The prevailing air flow pattern limits the geographic coverage of this analysis to central Europe and parts of western Europe. However, no POP monitoring stations exist in areas suitable for a possible extension of the study area.

  7. Detection of Pollution Caused by Solid Wastes

    NASA Technical Reports Server (NTRS)

    Golueke, Clarence G.

    1971-01-01

    To develop a means of detecting pollution, it s necessary to know something about the source and nature of the pollution. The type of pollution rising from solid wastes differs considerably from hat from liquid wastes or that from gaseous wastes ni its effect on the immediate environment. It may be "defined" by a series of negatives. When solid wastes are discarded on land, the resulting pollution is not land pollution in the sense of air and water pollution. For one thing, the solid wastes do not become a "part" of the land in that the wastes are neither intimately mixed nor homogenized into the land as are liquid and gaseous wastes into their respective media. The waste particles retain not only their chemical identity but also their visible (i.e., physical) characteristics. When buried, for example, the soil is under, above, and around the solids, because the wastes are there as discrete units. Secondly, solid wastes neither diffuse nor are they carried from the place at which they were deposited. In other words they remain stationary, providing of course the disposal site is land and not moving water. In a given area, solid wastes be not distributed uniformly over that area. Even the solid wastes falling into the specification of letter meets these specifications. In contrast liquid and gaseous wastes become intimately mixed, homogenized, and even dissolved in their media. Because solid wastes remain stationary, pollution constituted by their presence is highly localized and heavily concentrated, even to the extent that the pollution could be termed "micro" when compared to the macro-pollution arising from liquid and gasequs wastes.

  8. Cultural Dimensions of Water Pollution

    NASA Astrophysics Data System (ADS)

    Polaki, L.; Bekkam, V. R.

    2014-12-01

    Water (along with leaf, flower and fruit) is an important ingredient of Hindu worship. Abhishekam is the ritual pouring of water over idols. Some Shaivite temples perform Sahasra Ghatabhishekam (pouring of thousand pots of water, about 15000 L). However, the pollution caused by Abhishekam is minimal. Hindus cremate their dead and immerse the ashes in the waters of perennial rivers, the most preferred being the sacred waters of the Ganga. It has been estimated that 15,000 tonnes/year of cremation ash is immersed in the Ganga. Apart from these 140 to 250 tonnes of half burned corpses are dumped in the Ganges per year. There are 500 million people living in the catchment area of the Ganga, and that number is increasing. While there may be no objection from the public in regard to the cleansing of about 5.8 ×105 million liters of chemical wastes per year, the control of cremation ashes in the Ganga is for more difficult to achieve because of the sentiment. It is urgently necessary that pollution including cultural pollution of Ganges, is drastically reduced. The new Indian government has ambitious plans to do this, with allocation of about US$ 700 million in the current year's budget.

  9. Pollution control system

    SciTech Connect

    Voliva, B.H.; Bernstein, I.B.

    1984-09-25

    A pollution control system is disclosed wherein condensable pollutants are removed from a high-temperature gas stream by counterflow contact in a vertical tower with downwardly flowing, relatively cool absorbent oil. The absorbent is at a sufficiently low temperature so as to rapidly condense a portion of the pollutants in order to form a fog of fine droplets of pollutant entrained by the gas stream, which fog is incapable of being absorbed by the absorbent. The remainder of the condensable pollutants is removed by downwardly flowing absorbent oil, and the gas and entrained fog are directed from the tower to gas/droplet separation means, such as an electrostatic precipitator. The fog is thereby separated from the gas and substantially pollutant-free gas is discharged to the atmosphere.

  10. Joint Conference on Sensing of Environmental Pollutants, 2nd, Washington, D.C., December 10-12, 1973, Proceedings

    NASA Technical Reports Server (NTRS)

    1973-01-01

    Subjects considered are related to the remote passive sensing of atmosphere pollutants, the extension of laboratory measurement techniques for field use, instrument quality and measurement standardization, the remote active sensing of atmospheric pollutants, stationary source sensing, and air quality standards and measurement accuracy. Aspects of radiological, electromagnetic, and acoustic pollution monitoring are discussed together with new methods in particulate analysis, the measurement of meteorological variables that impact on atmospheric pollutants, and the impact of meteorological parameters on pollution analysis. The in-situ sensing of acoustic chemical and biological pollutants is reported along with global scale pollution monitoring and the remote sensing of water pollutants. Individual items are announced in this issue.

  11. Air pollution in China: Scientific and Public Policy Challenges

    NASA Astrophysics Data System (ADS)

    Zhu, T.

    2014-12-01

    Sever air pollution in China has in recent years caused intensive public, media and governmental attention. Many questions need to be answered about the air pollution in China, such as how harmful is the air pollution, especially PM2.5? Why suddenly so many reports about sever air pollution, is the air in China getting more polluted? How to design a policy that can control the air pollution most efficiently? After updated the national Ambient Air Quality Standards in 2012 and included PM2.5 as one of the critical air pollutants, in 2013, Chinese central government released for the first time the "Air Pollution Prevention and Control Action Plan". The plan has set goals to reduce annual mean concentration of PM2.5 up to 25% in 2017 in different regions in China. If the ambitious goals were achieved, this could be the most significant air pollution reduction in such a short time that affects so many people in human history. To achieve these goals, however, there are enormous scientific and public policy challenges to deal with. For example: Identify the key components, size fraction of PM that have the largest health effects; and identify the sources of PM that has the most harmful effects on human health and ecosystem. Reduce the uncertainty in health risk assessment. Understand complicate chemical transformation processes in air pollution formation with intensive emissions from industry, power plant, vehicles, agriculture. Interactions between air pollution, PBL, and atmospheric circulation at different scales. The accountability, feasibility, effectiveness, and efficiency of air pollution control policies. Integrate multi-pollutant control and achieve co-benefit with climate and energy policy. Regional coordinated air pollution control. The largest challenge in China for air pollution control remains how to strength the link between science and policy.

  12. NON-REGULATED CONTAMINANTS EMERGING RESEARCH, EXISTING AND FUTURE POLLUTANTS IN WATER SUPPLIES: OLD POLLUTANTS, NEW CONCERNS - NEW POLLUTANTS, UNKNOWN ISSUES

    EPA Science Inventory

    Those chemical pollutants that are regulated under various international, federal, and state programs represent but a small fraction of the universe of chemicals that occur in the environment as a result of both natural processes and human influence. Although this galaxy of targe...

  13. Endocrine disrupting chemicals

    PubMed Central

    Yeung, Bonnie HY; Wan, Hin T; Law, Alice YS

    2011-01-01

    In the past 200 years, an enormous number of synthetic chemicals with diverse structural features have been produced for industrial, medical and domestic purposes. These chemicals, originally thought to have little or no biological toxicity, are widely used in our daily lives as well as are commonly present in foods. It was not until the first World Wildlife Federation Wingspread Conference held in 1994 were concerns about the endocrine disrupting (ED) effects of these chemicals articulated. The potential hazardous effects of endocrine disrupting chemicals (EDCs) on human health and ecological well-being are one of the global concerns that affect the health and propagation of human beings. Considerable numbers of studies indicated that endocrine disruption is linked to “the developmental basis of adult disease,” highlighting the significant effects of EDC exposure on a developing organism, leading to the propensity of an individual to develop a disease or dysfunction in later life. In this review, we intend to provide environmental, epidemiological and experimental data to associate pollutant exposure with reproductive disorders, in particular on the development and function of the male reproductive system. Possible effects of pollutant exposure on the processes of embryonic development, like sex determination and masculinization are described. In addition, the effects of pollutant exposure on hypothalamus-pituitary-gonadal axis, testicular signaling, steroidogenesis and spermatogenesis are also discussed. PMID:22319671

  14. 40 CFR 63.2495 - How do I comply with the pollution prevention standard?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 13 2014-07-01 2014-07-01 false How do I comply with the pollution... Chemical Manufacturing Alternative Means of Compliance § 63.2495 How do I comply with the pollution prevention standard? (a) You may elect to comply with the pollution prevention alternative...

  15. 40 CFR 63.2495 - How do I comply with the pollution prevention standard?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 13 2013-07-01 2012-07-01 true How do I comply with the pollution... Chemical Manufacturing Alternative Means of Compliance § 63.2495 How do I comply with the pollution prevention standard? (a) You may elect to comply with the pollution prevention alternative...

  16. 40 CFR 63.2495 - How do I comply with the pollution prevention standard?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 13 2012-07-01 2012-07-01 false How do I comply with the pollution... Chemical Manufacturing Alternative Means of Compliance § 63.2495 How do I comply with the pollution prevention standard? (a) You may elect to comply with the pollution prevention alternative...

  17. Tinkering with the tinkerer: pollution versus evolution.

    PubMed Central

    Fox, G A

    1995-01-01

    Pollutants can act as powerful selective forces by altering genetic variability, its intergenerational transfer, and the size, functional viability, adaptability, and survival of future generations. It is at the level of the cell and the individual that meiosis occurs, that genetic diversity is maintained, and behavior, reproduction, growth, and survival occur and are regulated. It is at this level that evolutionary processes occur and most pollutants exert their toxic effects. Chronic exposure to chemicals contributes to the cumulative stress on individuals and disrupts physiological processes and chemically mediated communication thereby threatening the diversity and long-term survival of sexually reproducing biota. Regional or global effects of pollution on the atmosphere, hydrosphere, and lithosphere have indirectly altered Earth's life-support systems, thereby modifying trace metal balance, reproduction, and incidence of UV-B-induced DNA damage in biota. By altering the competitive ability and survival of species, chemical pollutants potentially threaten evolutionary processes and the biodiversity and function of intercepting ecosystems. PMID:7556031

  18. The status of indoor air pollution.

    PubMed Central

    Esmen, N A

    1985-01-01

    Indoor air pollution, specifically restricted in its meaning to chemicals in home indoor air environment, presents a new and probably an important challenge to the researchers of the air pollution field. The general overview of this topic suggests that the voluminous data generated in the past ten or so years have only defined the rudiments of the problem, and significant areas of research still exist. Among the important areas where information is lacking, the exposures to contaminants generated by the use of consumer products and through hobbies and crafts represent perhaps the most urgent need for substantial research. PMID:4085429

  19. River and Stream Pollution

    MedlinePlus

    ... Pollution Dirt Dirt is a big cause of pollution in our rivers and streams. Rain washes dirt into streams and rivers. Dirt can smother fish and other animals that live in the water. If plants can't get enough sunlight because ...

  20. Automotive Pollution Control.

    ERIC Educational Resources Information Center

    Raudenbush, David B.

    Intended for a 1- or 2-month curriculum in auto mechanics, this student manual on automotive pollution control was developed by a subject matter specialist at an area vocational school and tested in a vocational auto shop. Intended either for use in an integrated curriculum or for use in teaching pollution control as a separate course, these 12…

  1. MEASURING POLLUTION PREVENTION PROGRESS

    EPA Science Inventory

    The workshop, "Measuring Pollution Prevention Progress," was held in Salem, MA, March 31 - April 2, 1993. he purpose of this workshop was to present the latest significant research and practical findings related to pollution prevention measurement from ongoing and recently comple...

  2. River Pollution: Part I.

    ERIC Educational Resources Information Center

    Openshaw, Peter

    1983-01-01

    Describes a unit on river pollution and analytical methods to use in assessing temperature, pH, flow, calcium, chloride, dissolved oxygen, biochemical oxygen demand, dissolved nitrogen, detergents, heavy metals, sewage pollution, conductivity, and sediment cores. Suggests tests to be carried out and discusses significance of results. (JM)

  3. Pollution, An Environmental Crisis.

    ERIC Educational Resources Information Center

    Fischer, Richard B.

    This document, written for teachers, outlines the causes and extent of environmental problems relating to air pollution, water pollution, the use of fertilizers and pesticides, land use, and population density. A short bibliography includes references to periodicals and books dealing with teaching methods as well as references for background…

  4. Quebec's Toxic Pollution Concern.

    ERIC Educational Resources Information Center

    Mingie, Walter

    The best solution to the problems of increased pollution of Quebec lakes and rivers with toxic wastes and increased incidence of pollution related diseases is to educate children, to make them aware of the environment and man's interrelationship with it. Attitudes of concern, based on knowledge, must be developed so that as adults, they will take…

  5. IMMUNOTOXICITY OF AIR POLLUTANTS

    EPA Science Inventory

    The most common ubiquitous air pollutants, as well as some point source (e.g. metals) air pollutants, decrease the function of pulmonary host defense mechanisms against infection. Most of this knowledge is based on animal studies and involves cellular antibacterial defenses such ...

  6. Nonpoint Source Pollution.

    PubMed

    Ahmad, Zaki Uddin; Sakib, Salman; Gang, Daniel Dianchen

    2016-10-01

    Research advances on non-point source pollution in the year 2015 have been depicted in this review paper. Nonpoint source pollution is mainly caused by agricultural runoff, urban stormwater, and atmospheric deposition. Modeling techniques of NPS with different tools are reviewed in this article. PMID:27620104

  7. Bioindicators in air-pollution research: applications and constraints

    SciTech Connect

    Tingey, D.T.

    1988-05-01

    Physical and chemical measurements of air pollutants provide a precise measure of pollutant exposure frequently used to estimate probable biological impacts. Bioindicators may be classified as either accumulators of the pollutant or reactors to the pollutant. The ultimate selection of a bioindicator depends on the pollutant and the ultimate use of the data. A bioindicator should: (1) provide a readily detectable response to the pollutant; (2) be easy and efficient to use; (3) be readily related to the response of interest; and (4) have a distinctive syndrome not readily confused with other causes. Bioindicators clearly have value in assessing environmental problems, but, at most, they are only indicators of a problem. Corrective or mitigative actions require additional data.

  8. Aircraft engine pollution reduction.

    NASA Technical Reports Server (NTRS)

    Rudey, R. A.

    1972-01-01

    The effect of engine operation on the types and levels of the major aircraft engine pollutants is described and the major factors governing the formation of these pollutants during the burning of hydrocarbon fuel are discussed. Methods which are being explored to reduce these pollutants are discussed and their application to several experimental research programs are pointed out. Results showing significant reductions in the levels of carbon monoxide, unburned hydrocarbons, and oxides of nitrogen obtained from experimental combustion research programs are presented and discussed to point out potential application to aircraft engines. An experimental program designed to develop and demonstrate these and other advanced, low pollution combustor design methods is described. Results that have been obtained to date indicate considerable promise for reducing advanced engine exhaust pollutants to levels significantly below current engines.

  9. [Indoor pollution and health].

    PubMed

    Kummer, J

    1998-09-01

    The indoor pollution, where the patients pass in general close to 90% of their time, is an important factor to take in consideration if one wants to evaluate suitably the effects of the air pollution on the health. Causes of this kind of pollution are partially linked to the external pollution and the outdoor environment and also are function of human activities and introduced products in the habitat (heating, tabagisme, handywork, products of maintenance, coatings, materials of construction, etc.). The effects on health are as various as the pollutants, going from sharp intoxication to irritations or simply desagreements. In this problem of public health we may not underestimated sensitive persons and risky group as well as long terme effects, and chronic exposition effects. The search of solutions needs multiple competences from the physician, who has to play an essential role. PMID:9805975

  10. Ecological crisis in eastern Europe. (Latest citations from Pollution Abstracts database). Published Search

    SciTech Connect

    Not Available

    1993-09-01

    The bibliography contains citations concerning the severe problem of chemical pollution in Eastern Europe. The citations examine the contamination of air, soil, and water by pollutants from agriculture, energy production, chemical plants, and oil refineries, including adverse health effects of chemical pollution. Topics also include international cooperation between Eastern Europe and western nations to exchange information, standardize pollution monitoring techniques, and establish environmental legislation compatible with western standards. The development of remediation technologies, and economic incentives which would promote environmental protection while fostering future economic developments are also discussed. (Contains 250 citations and includes a subject term index and title list.)

  11. Health Effects of Air Pollution

    MedlinePlus

    ... Health effects of air pollution Health effects of air pollution Breathing air that is not clean can hurt ... important to know about the health effects that air pollution can have on you and others. Once you ...

  12. Oil pollution detection and sensing. (Latest citations from the NTIS bibliographic database). NewSearch

    SciTech Connect

    Not Available

    1994-10-01

    The bibliography contains citations concerning techniques used to detect and sense oil spills and slicks. Citations discuss remote sensing, chemical and biological monitoring, satellite imagery, surveilllance, and models. Topics include pollution information systems, environmental monitoring, coastal ecology, and paths of pollutants. Pollution effects on fisheries, leak detectors, artificial oil pollution, remedial actions, and international cooperation are covered. (Contains a minimum of 236 citations and includes a subject term index and title list.)

  13. Pollution prevention for the kraft pulp and paper industry

    SciTech Connect

    Not Available

    1992-09-01

    The document is an annotated bibliography of publications related to pollution prevention in the Kraft segment of the pulp and paper industry. It is organized by process area as follows: chip preparation, chemical pulping, pulp washing, bleaching, chemical recovery, recausticizing, power generation, wastewater treatment, papermaking, and general plant. The document contains 269 citations.

  14. The regeneration of polluted activated carbon by radiation techniques

    NASA Astrophysics Data System (ADS)

    Minghong, Wu; Borong, Bao; Ruimin, Zhou; Jinliang, Zhu; Longxin, Hu

    1998-10-01

    In this paper, the regeneration of used activated carbon from monosodium glutamate factory was experimented using radiation and acid-alkali chemical cleaning method. Results showed that the activated carbon saturated with pollutants can be wash away easily by flushing with chemical solution prior irradiation. DSC was used to monitor the change of carbon adsorption

  15. Correlation of Quantitative PCR for a Poultry-Specific Brevibacterium Marker Gene with Bacterial and Chemical Indicators of Water Pollution in a Watershed Impacted by Land Application of Poultry Litter▿

    PubMed Central

    Weidhaas, Jennifer L.; Macbeth, Tamzen W.; Olsen, Roger L.; Harwood, Valerie J.

    2011-01-01

    The impact of fecal contamination from human and agricultural animal waste on water quality is a major public health concern. Identification of the dominant source(s) of fecal pollution in a watershed is necessary for assessing the safety of recreational water and protecting water resources. A field study was conducted using quantitative PCR (qPCR) for the 16S rRNA gene of Brevibacterium sp. LA35 to track feces-contaminated poultry litter in environmental samples. Based on sensitivity and specificity characteristics of the qPCR method, the Bayesian conditional probability that detection of the LA35 marker gene in a water sample represented a true-positive result was 93%. The marker's covariance with fecal indicator bacteria (FIB) and metals associated with poultry litter was also assessed in litter, runoff, surface water, and groundwater samples. LA35 was detected in water and soil samples collected throughout the watershed, and its concentration covaried with concentrations of Escherichia coli, enterococci, As, Cu, P, and Zn. Significantly greater concentrations of FIB, As, Cu, P, and Zn were observed in edge-of-field runoff samples in which LA35 was detected, compared to samples in which it was not detected. Furthermore, As, Cu, P, and Zn concentrations covaried in environmental samples in which LA35 was detected and typically did not in samples in which the marker gene was not detected. The covariance of the poultry-specific LA35 marker gene with these known contaminants from poultry feces provides further evidence that it is a useful tool for assessing the impact of poultry-derived fecal pollution in environmental waters. PMID:21278274

  16. Correlation of quantitative PCR for a poultry-specific brevibacterium marker gene with bacterial and chemical indicators of water pollution in a watershed impacted by land application of poultry litter.

    PubMed

    Weidhaas, Jennifer L; Macbeth, Tamzen W; Olsen, Roger L; Harwood, Valerie J

    2011-03-01

    The impact of fecal contamination from human and agricultural animal waste on water quality is a major public health concern. Identification of the dominant source(s) of fecal pollution in a watershed is necessary for assessing the safety of recreational water and protecting water resources. A field study was conducted using quantitative PCR (qPCR) for the 16S rRNA gene of Brevibacterium sp. LA35 to track feces-contaminated poultry litter in environmental samples. Based on sensitivity and specificity characteristics of the qPCR method, the Bayesian conditional probability that detection of the LA35 marker gene in a water sample represented a true-positive result was 93%. The marker's covariance with fecal indicator bacteria (FIB) and metals associated with poultry litter was also assessed in litter, runoff, surface water, and groundwater samples. LA35 was detected in water and soil samples collected throughout the watershed, and its concentration covaried with concentrations of Escherichia coli, enterococci, As, Cu, P, and Zn. Significantly greater concentrations of FIB, As, Cu, P, and Zn were observed in edge-of-field runoff samples in which LA35 was detected, compared to samples in which it was not detected. Furthermore, As, Cu, P, and Zn concentrations covaried in environmental samples in which LA35 was detected and typically did not in samples in which the marker gene was not detected. The covariance of the poultry-specific LA35 marker gene with these known contaminants from poultry feces provides further evidence that it is a useful tool for assessing the impact of poultry-derived fecal pollution in environmental waters. PMID:21278274

  17. Pollution and Infant Health

    PubMed Central

    Currie, Janet

    2016-01-01

    In this article, I review recent research showing that even relatively low levels of pollution can affect infants' health. This research attempts to go beyond documenting correlations by using sharp changes in pollution levels, carefully selecting control groups (including unexposed siblings as controls for exposed children), and considering behavioral responses to pollution such as maternal mobility. Poor and minority children are more likely to be affected and differential exposure could be responsible for some of the observed group-level differences in health at birth. Policymakers concerned about the roots of inequality should consider the role played by environmental exposures of pregnant mothers. PMID:27134646

  18. Earthworms and Soil Pollutants

    PubMed Central

    Hirano, Takeshi; Tamae, Kazuyoshi

    2011-01-01

    Although the toxicity of metal contaminated soils has been assessed with various bioassays, more information is needed about the biochemical responses, which may help to elucidate the mechanisms involved in metal toxicity. We previously reported that the earthworm, Eisenia fetida, accumulates cadmium in its seminal vesicles. The bio-accumulative ability of earthworms is well known, and thus the earthworm could be a useful living organism for the bio-monitoring of soil pollution. In this short review, we describe recent studies concerning the relationship between earthworms and soil pollutants, and discuss the possibility of using the earthworm as a bio-monitoring organism for soil pollution. PMID:22247659

  19. Air Pollution Exposure

    PubMed Central

    Balmes, John R.; Collard, Harold R.

    2015-01-01

    Air pollution exposure is a well-established risk factor for several adverse respiratory outcomes, including airways diseases and lung cancer. Few studies have investigated the relationship between air pollution and interstitial lung disease (ILD) despite many forms of ILD arising from environmental exposures. There are potential mechanisms by which air pollution could cause, exacerbate, or accelerate the progression of certain forms of ILD via pulmonary and systemic inflammation as well as oxidative stress. This article will review the current epidemiologic and translational data supporting the plausibility of this relationship and propose a new conceptual framework for characterizing novel environmental risk factors for these forms of lung disease. PMID:25846532

  20. Quantifying light pollution

    NASA Astrophysics Data System (ADS)

    Cinzano, P.; Falchi, F.

    2014-05-01

    In this paper we review new available indicators useful to quantify and monitor light pollution, defined as the alteration of the natural quantity of light in the night environment due to introduction of manmade light. With the introduction of recent radiative transfer methods for the computation of light pollution propagation, several new indicators become available. These indicators represent a primary step in light pollution quantification, beyond the bare evaluation of the night sky brightness, which is an observational effect integrated along the line of sight and thus lacking the three-dimensional information.

  1. Aircraft engine pollution reduction

    NASA Technical Reports Server (NTRS)

    Rudey, R. A.

    1972-01-01

    The effect of engine operation on the types and levels of the major aircraft engine pollutants is described and the major factors governing the formation of these pollutants during the burning of hydrocarbon fuel are discussed. Methods which are being explored to reduce these pollutants are discussed and their application to several experimental research programs are pointed out. Results showing significant reductions in the levels of carbon monoxide, unburned hydrocarbons, and oxides of nitrogen obtained from experimental combustion research programs are presented and discussed to point out potential application to aircraft engines.

  2. CHEMICALS IN THE ENVIRONMENT (PUBLIC ACCESS BULLETIN)

    EPA Science Inventory

    Chemicals in the Environment (Public Access Bulletin) is an information product developed to provide the general public, environmental groups, educational organizations, state and local organizations, and other interested parties with access to many of the Office of Pollution Pre...

  3. Chemical Emergencies

    MedlinePlus

    When a hazardous chemical has been released, it may harm people's health. Chemical releases can be unintentional, as in the case of an ... the case of a terrorist attack with a chemical weapon. Some hazardous chemicals have been developed by ...

  4. Effect of environmental pollutants on human semen

    SciTech Connect

    Kaur, S.

    1988-01-01

    With the increased release of numerous chemical substances into the biosphere, careful assessment of health effects of polluted environment must be made for maintaining and enhancing the quality of human life on this earth. Significant number of malformed children are born each year. Sixty-five to 70% of all birth defects have an unknown etiology. More than one-third of early human conception and up to 15% of recognized pregnancies are terminated by spontaneous abortion. The extent of the effect of environmental pollution on human reproductive performance is for the most part unknown. Of the approximately five million chemicals in existence, humans could be expose to a sufficient quantity of an estimated 53,000 for toxicity to be of potential problem. Methods that do not require autopsy or surgery such as semen analysis would be attractive for assessing the effect of environmental toxicology on quality of human life. Therefore, the present study was conducted to observe the effects of heavily polluted environment of industrial area of Ludhiana and relatively clean, pollution free environment of Chandigarh on the human semen quality. It was believed that the function of the male reproductive system may often be the most sensitive to toxic effects.

  5. Air pollution and circulating biomarkers of oxidative stress

    PubMed Central

    Staimer, Norbert; Vaziri, Nosratola D.

    2013-01-01

    Chemical components of air pollutant exposures that induce oxidative stress and subsequent inflammation may be partly responsible for associations of cardiovascular morbidity and mortality with airborne particulate matter and combustion-related pollutant gasses. However, epidemiologic evidence regarding this is limited. An exposure-assessment approach is to measure the oxidative potential of particle mixtures because it is likely that hundreds of correlated chemicals are involved in overall effects of air pollution on health. Oxidative potential likely depends on particle composition and size distribution, especially ultrafine particle concentration, and on transition metals and certain semivolatile and volatile organic chemicals. For health effects, measuring systemic oxidative stress in the blood is one feasible approach, but there is no universal biomarker of oxidative stress and there are many potential target molecules (lipids, proteins, DNA, nitric oxide, etc.), which may be more or less suitable for specific study goals. Concurrent with the measurement of oxidative stress, it is important to measure gene and/or protein expression of endogenous antioxidant enzymes because they can modify relations between oxidative stress biomarkers and air pollutants. Conversely, the expression and activities of these enzymes are modified by oxidative stress. This interplay will likely determine the observed effects of air pollutants on systemic inflammatory and thrombotic mediators and related clinical outcomes. Studies are needed to assess the reliability and validity of oxidative stress biomarkers, evaluate differences in associations between oxidative stress biomarkers and various pollutant measurements (mass, chemical components, and oxidative potential), and evaluate impacts of antioxidant responses on these relations. PMID:23626660

  6. URBAN RUNOFF POLLUTION CONTROL

    EPA Science Inventory

    Combined sewer overflows are major sources of water pollution problems, but even discharges of stormwater alone can seriously affect water quality. urrent approaches involve control of over flows, treatment, and combinations of the two. ontrol may involve maximizing treatment wit...

  7. Profiting from pollution prevention

    SciTech Connect

    LoPilato, A.J.; Eng, D.B.

    1994-12-31

    In the case of pollution prevention, national environmental goals coincide with industry`s economic interests. Most, if not all businesses have strong incentives to reduce the toxicity and quantities of wastes generated. These incentives include not only the ever increasing cost of compliance within a growing framework of regulations, but may include a firms desire to reduce the risk of criminal and civil liability, reduce overall operating costs, improve employee morale and participation, enhance corporate image in the community and insure protection of both public health and the environment. Although some businesses may invest in a pollution prevention program because it is the green thin to do, most businesses will weight their initial and long-term pollution prevention program investments on sound economic analyses. An effective pollution prevention program can provide cost savings that will more than offset the initial development and implementation costs.

  8. Students 'Weigh' Atmospheric Pollution.

    ERIC Educational Resources Information Center

    Caporaloni, Marina

    1998-01-01

    Describes a procedure developed by students that measures the mass concentration of particles in a polluted urban atmosphere. Uses a portable fan and filters of various materials. Compares students' data with official data. (DDR)

  9. The Polluter Pays

    ERIC Educational Resources Information Center

    Jamieson, Martyn

    1975-01-01

    Presents part of the winning entry in the competition organized by Stirling University (England). The extract presented forms the conclusion to a wide ranging essay which covered the various forms of pollution. (EB)

  10. Investigating Air Pollution

    ERIC Educational Resources Information Center

    Carter, Edward J.

    1977-01-01

    Describes an experiment using live plants and cigarette smoke to demonstrate the effects of air pollution on a living organism. Procedures include growth of the test plants in glass bottles, and construction and operation of smoking machine. (CS)

  11. Indoor air pollution

    SciTech Connect

    Not Available

    1985-05-01

    This factsheet reviews what is currently known about pollutant sources, abatement and control equipment and techniques for poorly ventilated houses. Radon, formaldehyde, tobacco smokes, carbon dioxide, carbon monoxide, particulates, bacteria, fungi and viruses are addressed. (PSB)

  12. AIR POLLUTION CONTROL TECHNOLOGIES

    EPA Science Inventory

    This is a chapter for John Wiley & Son's Mechanical Engineers' Handbook, and covers issues involving air pollution control. Various technologies for controlling sulfur oxides is considered including fuel desulfurization. It also considers control of nitrogen oxides including post...

  13. Landsat and water pollution

    NASA Technical Reports Server (NTRS)

    Castruccio, P.; Fowler, T.; Loats, H., Jr.

    1979-01-01

    Report presents data derived from satellite images predicting pollution loads after rainfall. It explains method for converting Landsat images of Eastern United States into cover maps for Baltimore/five county region.

  14. Pollution in the upland environment.

    PubMed

    Crossley, A; Wilson, D B; Milne, R

    1992-01-01

    As part of a study on the effects of pollutants on forests, a long-term monitoring programme has been operating at two sites (602 and 275 m above sea level (a.s.l.)) in Glentress Forest, south-east Scotland, since June 1987. At these sites, equipment has been recording 20-min data for weather parameters, and cloud and rain event frequency, duration and intensity. The chemical composition of bulk cloud and rainwater has been measured. Cloudwater detection and collection has been made using passive 'Harp wire' gauges (with a cross-sectional area of 0.047 m2) strung with polypropylene filament and having a typical collection efficiency of 29% when compared with independent measurements of windspeed and liquid water content. During 1988, the annual rainfall at the upper site was 1213 mm, occurring over 1776 h. The equivalent cloudwater deposition to a forest with a drag coefficient of 0.06 was estimated to be 375 mm over 1936 h. A 'typical cloud event' lasted 4.5 h and would deposit to forests at a rate of 0.2 mm h(-1). There were significantly higher loadings of suspended particulate material (> 0.2 microm) in cloudwater (mean 18.42, max. 94.5 mg litre(-1)) compared with rainwater (mean 2.6, max. 25.6 mg litre(-1)). There were similar differences in ion concentrations, e.g. for H+ in cloudwater (mean 163, max. 1259 microm) and in rainwater (mean 33, max. 262 microM). It is concluded that cloudwater deposition represents a major pathway for pollutant transfer to the upland environment, especially where the surface vegetation is efficient at capturing cloudwater, i.e. forests. The consequences of this increased pollutant loading to forests and water catchments are yet to be assessed. PMID:15092053

  15. Compliance through pollution prevention

    SciTech Connect

    McCarty, B.D.; Coyle, S.; Kachel, W.M.

    1999-07-01

    Decreased budgetary resources have caused the Air Force Materiel Command to look for a better way to target pollution prevention investments. The new paradigm, Compliance through Pollution Prevention (CTP2), is based upon the Code of Environmental Management Principles (CEMP) for federal facilities. It provides a procedure to assure that all future AFMC P2 investments result in the greatest reduction in environmental compliance burden possible. This paper describes the evolution of this new environmental management system, both past and future.

  16. Air pollution from aircraft

    NASA Technical Reports Server (NTRS)

    Heywood, J. B.; Fay, J. A.; Chigier, N. A.

    1979-01-01

    A series of fundamental problems related to jet engine air pollution and combustion were examined. These include soot formation and oxidation, nitric oxide and carbon monoxide emissions mechanisms, pollutant dispension, flow and combustion characteristics of the NASA swirl can combustor, fuel atomization and fuel-air mixing processes, fuel spray drop velocity and size measurement, ignition and blowout. A summary of this work, and a bibliography of 41 theses and publications which describe this work, with abstracts, is included.

  17. Pollution control apparatus

    SciTech Connect

    McVorvey, A.F.

    1992-06-16

    This patent describes a pollution control apparatus for a motor vehicle having an engine discharging exhaust gases into a muffler and out through a tail pipe. It comprises: means to spray water into the exhaust gases into produce a mist of water droplets containing dissolved and entrained pollutants in the exhaust gases and connected to the muffler, means to separate the water droplets from the exhaust gas mist and pass cleaned exhaust gases from the muffler and out through the tail pipe.

  18. Indoor Pollutants Emitted by Electronic Office Equipment

    SciTech Connect

    Maddalena, Randy L.; Destaillats, Hugo; Russell, Marion L.; Hodgson, Alfred T.; McKone, Thomas E.

    2008-07-01

    The last few decades have seen major changes in how people collect and process information at work and in their homes. More people are spending significant amounts of time in close proximity to computers, video display units, printers, fax machines and photocopiers. At the same time, efforts to improve energy efficiency in buildings by reducing leaks in building envelopes are resulting in tighter (i.e., less ventilated) indoor environments. Therefore, it is critical to understand pollutant emission rates for office equipment because even low emissions in areas that are under-ventilated or where individuals are in close proximity to the pollutant source can result in important indoor exposures. We reviewed existing literature reports on pollutant emission by office equipment, and measured emission factors of equipment with significant market share in California. We determined emission factors for a range of chemical classes including volatile and semivolatile organic compounds (VOCs and SVOCs), ozone and particulates. The measured SVOCs include phthalate esters, brominated and organophosphate flame retardants and polycyclic aromatic hydrocarbons. Measurements were carried out in large and small exposure chambers for several different categories of office equipment. Screening experiments using specific duty cycles in a large test chamber ({approx}20 m{sup 3}) allowed for the assessment of emissions for a range of pollutants. Results from the screening experiments identified pollutants and conditions that were relevant for each category of office equipment. In the second phase of the study, we used a smaller test chamber ({approx}1 m{sup 3}) to measure pollutant specific emission factors for individual devices and explored the influence of a range of environmental and operational factors on emission rates. The measured emission factors provide a data set for estimating indoor pollutant concentrations and for exploring the importance of user proximity when estimating

  19. Voluntary pollution reduction programs

    SciTech Connect

    Sears, E.B.

    1997-08-01

    Despite claims that the government is reducing the amount of environmental regulation, the sheer amount of regulatory language has actually increased yearly. Yet based on media reports and citizen claims, pollution appears to go unchecked. Citizens condemn a perceived lack of government regulation of industrial pollution, while industries find themselves mired in increasingly complex regulatory programs that are sometimes far removed from real world situations. US Environmental Protection Agency (EPA) decision-makers have responded to these concerns by designing regulatory programs that abandon traditional command-and-control regulatory schemes as ill-suited to today`s pollution problems and the interests of these stakeholders. This paper analyzes the use of voluntary pollution control programs in place of command-and-control regulation. It is proposed that voluntary programs may serve as carrots to entice regulated entities to reduce pollution, but that there are a number of hurdles to their effective implementation that preclude them from being embraced as effective environmental regulatory tools. This paper reviews why agencies have moved from command-and-control regulation and examines current voluntary pollution control programs. This paper also contemplates the future of such programs.

  20. Opportunities for innovation: Pollution prevention

    SciTech Connect

    Edgerly, D.E.

    1994-08-01

    The objective was to identify technological opportunities within a number of selected industries and/or manufacturing/finishing processes, to reduce pollution. These industries/processes were selected as representative of and applicable to the broad range of U.S. manufacturing businesses. These include: metals coating (i.e., painting) which is widely done in a number of major industries, including the automotive industry; metals degreasing; recyclability of office equipment; chemical manufacturing; printing; textiles dye and dyeing; and the pulp and paper industry. Additionally, the promulgation of new regulations, requiring companies to change their historical manufacturing and waste generating/disposal practices, will continue to create technological needs and opportunities for savvy businesses to develop solutions.

  1. Environmental pollutants and breast cancer.

    PubMed Central

    Brody, Julia Green; Rudel, Ruthann A

    2003-01-01

    Breast cancer is the most common cancer in women and the leading cause of cancer death among women 35-54 years of age. Rising incidence, increased risk among migrants to higher risk regions, and poor prediction of individual risk have prompted a search for additional modifiable factors. Risk factors for breast cancer include reproductive characteristics associated with estrogen and other hormones, pharmaceutical hormones, and activities such as alcohol use and lack of exercise that affect hormone levels. As a result, investigation of hormonally active compounds in commercial products and pollution is a priority. Compounds that cause mammary tumors in animals are additional priorities. Animal models provide insight into possible mechanisms for effects of environmental pollutants on breast cancer and identify chemical exposures to target in epidemiologic studies. Although few epidemiologic studies have been conducted for chemical exposures, occupational studies show associations between breast cancer and exposure to certain organic solvents and polycyclic aromatic hydrocarbons (PAHs). Population-based studies have been limited to a few organochlorine compounds and PAHs and have been mostly negative. A variety of challenges in studies of breast cancer and the environment may have contributed to negative findings. Lack of exposure assessment tools and few hypothesis-generating toxicologic studies limit the scope of epidemiologic studies. Issues of timing with respect to latency and periods of breast vulnerability, and individual differences in susceptibility pose other challenges. Substantial work is needed in exposure assessment, toxicology, and susceptibility before we can expect a pay-off from large epidemiologic studies of breast cancer and environment. PMID:12826474

  2. Pollution Microbiology, A Laboratory Manual.

    ERIC Educational Resources Information Center

    Finstein, Melvin S.

    This manual is designed for use in the laboratory phase of courses dealing with microbial aspects of pollution. It attempts to cover the subject area broadly in four major categories: (1) microorganisms in clean and polluted waters, (2) carbonaceous pollutants, (3) nitrogen, phosphorus, iron, and sulfur as pollutants, and (4) sanitary…

  3. Pupils' Understanding of Air Pollution

    ERIC Educational Resources Information Center

    Dimitriou, Anastasia; Christidou, Vasilia

    2007-01-01

    This paper reports on a study of pupils' knowledge and understanding of atmospheric pollution. Specifically, the study is aimed at identifying: 1) the extent to which pupils conceptualise the term "air pollution" in a scientifically appropriate way; 2) pupils' knowledge of air pollution sources and air pollutants; and 3) pupils' knowledge of air…

  4. Environmental benefits of chemical propulsion

    NASA Technical Reports Server (NTRS)

    Hayes, Joyce A.; Goldberg, Benjamin E.; Anderson, David M.

    1995-01-01

    This paper identifies the necessity of chemical propulsion to satellite usage and some of the benefits accrued through monitoring global resources and patterns, including the Global Climate Change Model (GCM). The paper also summarized how the satellite observations are used to affect national and international policies. Chemical propulsion, like all environmentally conscious industries, does provide limited, controlled pollutant sources through its manufacture and usage. However, chemical propulsion is the sole source which enables mankind to launch spacecraft and monitor the Earth. The information provided by remote sensing directly affects national and international policies designed to protect the environment and enhance the overall quality of life on Earth. The resultant of chemical propulsion is the capability to reduce overall pollutant emissions to the benefit of mankind.

  5. Workshop on Spanning Regional-to-Global Pollution

    NASA Technical Reports Server (NTRS)

    Thompson, Anne M.; Newman, Paul A.; Gleason, James F.; Brune, William H.; Dickerson, Russell R.

    2002-01-01

    Pollution is often considered a localized phenomenon, but it is now clear that it travels from region-to-region, country to country, and even continent to continent. In addition to urban pollution in developed countries, large emissions from developing nations and large-scale biomass fires add to the global pollution burden. Ozone and aerosols are two components of pollution that contribute to radiative forcing of the earth s climate. In turn, as climate changes, rates of chemical and microphysical reactions may be perturbed. Considering the earth as a coupled chemical-microphysical-climate system poses challenges for models and observations alike. These issues were the topic of a Workshop held in May 2002 at NASA GSFC s Laboratory for Atmospheres. Highlights of the Workshop are summarized in this article.

  6. A review of ion and metal pollutants in urban green water infrastructures.

    PubMed

    Kabir, Md Imran; Daly, Edoardo; Maggi, Federico

    2014-02-01

    In urban environments, the breakdown of chemicals and pollutants, especially ions and metal compounds, can be favoured by green water infrastructures (GWIs). The overall aim of this review is to set the basis to model GWIs using deterministic approaches in contrast to empirical ones. If a better picture of chemicals and pollutant input and an improved understanding of hydrological and biogeochemical processes affecting these pollutants were known, GWIs could be designed to efficiently retain these pollutants for site-specific meteorological patterns and pollutant load. To this end, we surveyed the existing literature to retrieve a comprehensive dataset of anions and cations, and alkaline and transition metal pollutants incoming to urban environments. Based on this survey, we assessed the pollution load and ecological risk indexes for metals. The existing literature was then surveyed to review the metal retention efficiency of GWIs, and possible biogeochemical processes related to inorganic metal compounds were proposed that could be integrated in biogeochemical models of GWIs. PMID:24184546

  7. Method for measuring pollutant formation

    NASA Technical Reports Server (NTRS)

    Annen, Kurt (Inventor); Stickler, David B. (Inventor)

    2001-01-01

    Diagnostic methods for determining an instantaneous rate of pollutant formation in a combustion system are based on measurement of chemiluminescence intensity generated simultaneously with the formation of the pollutant. The chemiluminescent signal is generated by an analog reaction which occurs in parallel with a key step in the formation of a specific pollutant of interest. The connection between the analog reaction and the pollution reaction is such that the chemiluminescent signal indicates the local, instantaneous formation rate of the pollutant of interest.

  8. Use of electron ionization and atmospheric pressure chemical ionization in gas chromatography coupled to time-of-flight mass spectrometry for screening and identification of organic pollutants in waters.

    PubMed

    Portolés, Tania; Mol, Johannes G J; Sancho, Juan V; Hernández, Félix

    2014-04-25

    A new approach has been developed for multiclass screening of organic contaminants in water based on the use of gas chromatography coupled to hybrid quadrupole high-resolution time-of-flight mass spectrometry with atmospheric pressure chemical ionization (GC-(APCI)QTOF MS). The soft ionization promoted by the APCI source allows effective and wide-scope screening based on the investigation of the molecular ion and/or protonated molecule. This is in contrast to electron ionization (EI) where ionization typically results in extensive fragmentation, and diagnostic ions and/or spectra need to be known a priori to facilitate detection of the analytes in the raw data. Around 170 organic contaminants from different chemical families were initially investigated by both approaches, i.e. GC-(EI)TOF and GC-(APCI)QTOF, including polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs) and a notable number of pesticides and relevant metabolites. The new GC-(APCI)QTOF MS approach easily allowed widening the number of compounds investigated (85 additional compounds), with more pesticides, personal care products (UV filters, musks), polychloronaphthalenes (PCNs), antimicrobials, insect repellents, etc., most of them considered as emerging contaminants. Both GC-(EI)TOF and GC-(APCI)QTOF methodologies have been applied, evaluating their potential for a wide-scope screening in the environmental field. PMID:24674644

  9. Micronucleus test of erythrocytes and lymphocytes in the blood of the people living in the radiation pollution zone as a result of the accident at the Siberian Chemical plant on April 6, 1993

    SciTech Connect

    Ilyinskikh, N.N.; Ivanchuk, I.I.; Ilyinskikh, E.N.

    1997-10-01

    We have carried out analysis of the number of blood erythrocytes and lymphocytes with micronuclei in the inhabitants of four settlements located near the place of the accident which happened at the atomic power station of the Siberian Chemical plant (Tomsk-7) on April 6, 1993. In all cases, the people examined showed a considerable increase in the number of cells with micronuclei as compared with the control. We observed the same people for two years and found a gradual decrease in the number of cells with micronuclei. It has been shown in this work that people born in 1963-1970 have a much higher level of cells with micronuclei which we tend to regard as a result of the radiation accident at the Siberian chemical plant in 1963. The data we have obtained allow us to conclude that penetration of radionuclides into the human organism in the prenatal and early postnatal periods can lead to the formation of stable clones of erythroid cells with micronuclei and a higher level of erythrocytes with micronuclei which can remain in the blood for a long time.

  10. LINEAR MODELS FOR MANAGING SOURCES OF GROUNDWATER POLLUTION.

    USGS Publications Warehouse

    Gorelick, Steven M.; Gustafson, Sven-Ake

    1984-01-01

    Mathematical models for the problem of maintaining a specified groundwater quality while permitting solute waste disposal at various facilities distributed over space are discussed. The pollutants are assumed to be chemically inert and their concentrations in the groundwater are governed by linear equations for advection and diffusion. The aim is to determine a disposal policy which maximises the total amount of pollutants released during a fixed time T while meeting the condition that the concentration everywhere is below prescribed levels.

  11. Prosperity without pollution: The prevention strategy for industry and consumers

    SciTech Connect

    Hirschhorn, J.S.; Oldenburg, K.U.

    1991-12-31

    ;Contents: Pollution prevention pays for everyone; What pollution prevention is-What waste recycling and other strategies are not; Achieving succcess by overcoming obstacles; Data tells the story-too much waste; The ozone groan-do we still have time; Harm to the farm and home from chemical pesticides; Changing consumption-reducing garbage; Household toxic products-thinking more and buying less; and No time to waste.

  12. CHEMICAL ASPECTS OF AFTERBURNER SYSTEMS

    EPA Science Inventory

    The report reviews the chemistry and reaction kinetics of oxidation and pyrolysis reaction that occur in afterburners (or fume incinerators) that are used to destroy organic pollutants in air or gas streams. Chemical kinetic rate data are compiled for both complex and global reac...

  13. [Chemical food contaminants].

    PubMed

    Schrenk, D

    2004-09-01

    Chemical food contaminants are substances which are neither present naturally in the usual raw material used for food production nor are added during the regular production process. Examples are environmental pollutants or contaminants derived from agricultural production of crops or livestock or from inadequate manufacturing of the food product itself. More difficult is the classification of those compounds formed during regular manufacturing such as products of thermal processes including flavoring substances. In these cases, it is common practice to call those compounds contaminants which are known for their adverse effects such as acrylamide, whereas constituents which add to the food-specific flavor such as Maillard products formed during roasting, baking etc. are not termed contaminants. From a toxicological viewpoint this distinction is not always clear-cut. Important groups of chemical contaminants are metals such as mercury or lead, persistent organic pollutants such as polychlorinated biphenyls and related pollutants, which are regularly found in certain types of food originating from background levels of these compounds in our environment. Furthermore, natural toxins form microorganisms or plants, and compounds formed during thermal treatment of food are of major interest. In general, a scientific risk assessment has to be carried out for any known contaminant. This comprises an exposure analysis and a toxicological and epidemiological assessment. On these grounds, regulatory and/or technological measures can often improve the situation. Major conditions for a scientific risk assessment and a successful implementation of regulations are highly developed food quality control, food toxicology and nutritional epidemiology. PMID:15378171

  14. Air pollution modifies floral scent trails

    NASA Astrophysics Data System (ADS)

    McFrederick, Quinn S.; Kathilankal, James C.; Fuentes, Jose D.

    Floral hydrocarbons provide essential signals to attract pollinators. As soon as they are emitted to the atmosphere, however, hydrocarbons are destroyed by chemical reactions involving pollutants such as ozone. It is therefore likely that increased air pollution interferes with pollinator attracting hydrocarbon signals. To test this hypothesis, a Lagrangian diffusion model was used to determine the position of air parcels away from hydrocarbon sources and to estimate the rate of chemical destruction of hydrocarbons as air parcels moved across the landscape. The hydrocarbon compounds linalool, β-myrcene, and β-ocimene were chosen because they are known to be common scents released from flowers. The suppressed ambient abundances of volatile organic compounds were determined in response to increased regional levels of ozone, hydroxyl, and nitrate radicals. The results indicate that the documented increases in air pollution concentrations, from pre-industrial to present times, can lead to reductions in volatile compound concentrations insects detect as they pollinate flowers. For highly reactive volatiles the maximum downwind distance from the source at which pollinators can detect the scents may have changed from kilometers during pre-industrial times to <200 m during the more polluted conditions of present times. The increased destruction of floral signals in polluted air masses may have important implications for both pollinators and signaling plants. When patches of flowers are further apart than the visual range of pollinators, such as in fragmented landscapes, the loss of scent signals may mean that pollinators spend more time searching for patches and less time foraging. This decrease in pollinator foraging efficiency will simultaneously decrease the pollinator's reproductive output and the amount of pollen flow in flowering plants.

  15. Mercury pollution issues in mining districts (Armenia)

    NASA Astrophysics Data System (ADS)

    Saghatelyan, Armen; Sahakyan, Lilit; Belyaeva, Olga; Torosyan, Nver

    2015-04-01

    The issue of mercury (Hg) due to its chemical and geochemical peculiarities and a negative impact it produces on human health has a long history. Existence of international projects devoted to Hg research (AMAP Technical Background Report, 2013) and elaboration on a new convention to combat Hg pollution (http://www.mercuryconvention.org/Home/tabid/3360/Default.aspx) prove that Hg has already become a global concern. Presently, data on Armenia's area pollution with Hg available in international literature sources and reports are scarce and cover pollution sources only. According to published data (AMAP Technical Background Report, 2013), in 2009 summary emission of Hg on the entire territory of the Republic of Armenia made 222,723 kg, considerable shares of which fell on primary copper production (88,057 kg), cement production (57,094 kg), production of gold from large mines (46,728 kg), waste and other losses due to breakage and disposal in landfill (29,995 kg); besides, some quantities originated from amalgams, combustion of different-type fuel and garbage, and so on. One should mind, that these are calculated statistical data, which reflect neither a complete list of Hg pollution sources nor a realistic picture of levels of Hg pollution of different environmental compartments and risks. Local monitoring data on Hg pollution are not sufficient either. This abstract is aimed at revealing of Hg pollution problems in some of Armenia's mining regions through generalization of data on complex investigations implemented at the Center for Ecological-Noosphere Studies NAS RA between 2005 and 2011, and is focused on Hg pollution of different environmental compartments: water - atmosphere - soil - farm produce - atmospheric precipitation - human bio-substrates. The obtained data indicate that as a result of ore mining and processing Hg enters onto the surface, travels through air and water migration streams and finally brings to pollution of all environmental compartments

  16. Automated Pollution Control

    NASA Technical Reports Server (NTRS)

    1997-01-01

    Patterned after the Cassini Resource Exchange (CRE), Sholtz and Associates established the Automated Credit Exchange (ACE), an Internet-based concept that automates the auctioning of "pollution credits" in Southern California. An early challenge of the Jet Propulsion Laboratory's Cassini mission was allocating the spacecraft's resources. To support the decision-making process, the CRE was developed. The system removes the need for the science instrument manager to know the individual instruments' requirements for the spacecraft resources. Instead, by utilizing principles of exchange, the CRE induces the instrument teams to reveal their requirements. In doing so, they arrive at an efficient allocation of spacecraft resources by trading among themselves. A Southern California RECLAIM air pollution credit trading market has been set up using same bartering methods utilized in the Cassini mission in order to help companies keep pollution and costs down.

  17. Deposition of Atmospheric Pollutants

    NASA Astrophysics Data System (ADS)

    Malet, L. M.

    Deposition of Atmospheric Pollutants, containing the proceedings of a colloquium held at Oberursel/Taunus, FRG, November 9-11, 1981, is divided into three main parts: dry deposition; wet deposition; and deposition on plants and vegetation.The 20 articles in the volume permit a fair survey of present-day knowledge and will be a useful tool to all working on the topic. Pollution by deposition of either the dry or wet sort is very insidious; its importance only appears in the long range, when its effects are or are almost irreversible. That is why concern was so long in emerging from decision makers.

  18. Rapid guide to hazardous air pollutants

    SciTech Connect

    Beim, H.J.; Spero, J.; Theodore, L.

    1998-12-31

    Concise and easy to use, this book brings together a wealth of hard-to-gather information in one compact pocket guide. It offers--in alphabetical order--detailed profiles of the 189 elements and compounds determined to be hazardous air pollutants by the 1990 Amendments of the Clean Air Act. The profile for each pollutant includes: fundamental identification data (CAS number, molecular formula, formula weight, synonyms); uses (primarily in the manufacture of chemicals and as a component in the manufacturing process); physical properties (such as boiling point, density, vapor pressures, color); chemical properties (such as air/water reactivity, reactivity with skin or metal, flash point, heat of combustion); health risks, including toxic exposure guidelines, toxicity data, and acute and chronic risks; hazard risks (the substance`s potential for accidents, fires, explosions, corrosion, and chemical incompatibility); exposure routes tracking the activities, environment, sources, and occupations that tend to lead to exposure; regulatory status, listing the primary laws and citations of regulated chemicals; and important additional information on symptoms, first aid, firefighting methods, protective equipment, and safe storage.

  19. Atlantic and indian oceans pollution in africa

    NASA Astrophysics Data System (ADS)

    Abubakar, Babagana

    Africa is the second largest and most populated continent after Asia. Geographically it is located between the Atlantic and Indian Oceans. Most of the Africa's most populated and industrialized cities are located along the coast of the continent facing the Atlantic and Indian Oceans, example of such cities include Casablanca, Dakar, Accra, Lagos, Luanda and Cape town all facing the Atlantic Ocean and cities like East London, Durban, Maputo, Dar-es-salaam and Mogadishu are all facing the Indian Ocean. As a result of the geographical locations of African Coastal Cities plus increase in their population, industries, sea port operations, petroleum exploration activities, trafficking of toxic wastes and improper waste management culture lead to the incessant increase in the pollution of the two oceans. NATURE OF POLLUTION OF THE ATLANTIC OCEAN i. The petroleum exploration activities going on along the coast of "Gulf of Guinea" region and Angola continuously causes oil spillages in the process of drilling, bunkering and discharging of petroleum products in the Atlantic Ocean. ii. The incessant degreasing of the Sea Ports "Quay Aprons" along the Coastal cities of Lagos, Luanda, Cape Town etc are continuously polluting the Atlantic Ocean with chemicals. iii. Local wastes generated from the houses located in the coastal cities are always finding their ways into the Atlantic Ocean. NATURE OF POLLUTION OF THE INDIAN OCEAN i. Unlike the Atlantic ocean where petroleum is the major pollutant, the Indian Ocean is polluted by Toxic / Radioactive waste suspected to have been coming from the developed nations as reported by the United Nations Environmental Programme after the Tsunami disaster in December 2004 especially along the coast of Somalia. ii. The degreasing of the Quay Aprons at Port Elizabeth, Maputo, Dar-es-Salaam and Mongolism Sea Ports are also another major source polluting the Indian Ocean. PROBLEMS GENERATED AS A RESULT OF THE OCEANS POLLUTION i. Recent report

  20. China's international trade and air pollution: 2000 - 2009

    NASA Astrophysics Data System (ADS)

    Yan, Y.; Ni, R.; Lin, J.; Pan, D.; Wang, J.; Zhang, Q.

    2015-12-01

    As the world's top trading country, China is now one of the most polluted regions worldwide. Much attention has been paid to the global impacts of Chinese pollution via atmospheric transport processes. However, a large portion of pollution produced in China is associated with its production of goods for foreign consumption via international trade. International trade allows for separation of regions producing and consuming the products, altering the spatial distribution of associated emissions and leading to substantial changes in regional air pollution and global transport. Along with China's rapid economic growth in recent years, its economic-trade structure and volume has been changing all the time, resulting in large changes in total emissions and the shares of trade-related emissions. Our previous work has shown considerable variability in the contributions of export-related emissions to Chinese total emissions from 2000 to 2009. Here, we attempt to assess the influence of China's changing total and export-related emissions between 2000 and 2009 on its atmospheric pollution loadings and global impacts, by exploiting simulations of a global chemical transport model. Given the distinctive contributions of different economic sectors to pollutant emissions, we also attempt to investigate the sectoral contributions to pollution loadings and transport. Our study will help understand the role of international trade in the trends and variability of Chinese pollution.

  1. Australians are not equally protected from industrial air pollution

    NASA Astrophysics Data System (ADS)

    Dobbie, B.; Green, D.

    2015-05-01

    Australian air pollution standards are set at national and state levels for a number of chemicals harmful to human health. However, these standards do not need to be met when ad hoc pollution licences are issued by state environment agencies. This situation results in a highly unequal distribution of air pollution between towns and cities, and across the country. This paper examines these pollution regulations through two case studies, specifically considering the ability of the regulatory regime to protect human health from lead and sulphur dioxide pollution in the communities located around smelters. It also considers how the proposed National Clean Air Agreement, once enacted, might serve to reduce this pollution equity problem. Through the case studies we show that there are at least three discrete concerns relating to the current licencing system. They are: non-onerous emission thresholds for polluting industry; temporal averaging thresholds masking emission spikes; and ineffective penalties for breaching licence agreements. In conclusion, we propose a set of new, legally-binding national minimum standards for industrial air pollutants must be developed and enforced, which can only be modified by more (not less) stringent state licence arrangements.

  2. Pollution from pipelines

    SciTech Connect

    Not Available

    1991-01-01

    During the 1980s, over 3,900 spills from land-based pipelines released nearly 20 million gallons of oil into U.S. waters-almost twice as much as was released by the March 1989 Exxon Valdez oil spill. Although the Department of Transportation is responsible for preventing water pollution from petroleum pipelines, GAO found that it has not established a program to prevent such pollution. DOT has instead delegated this responsibility to the Coast Guard, which has a program to stop water pollution from ships, but not from pipelines. This paper reports that, in the absence of any federal program to prevent water pollution from pipelines, both the Coast Guard and the Environmental Protection Agency have taken steps to plan for and respond to oil spills, including those from pipelines, as required by the Clean Water Act. The Coast Guard cannot, however, adequately plan for or ensure a timely response to pipeline spills because it generally is unaware of specific locations and operators of pipelines.

  3. Measuring River Pollution

    ERIC Educational Resources Information Center

    Ayyavoo, Gabriel

    2004-01-01

    The Don River watershed is located within Canada's most highly urbanized area--metropolitan Toronto. Many residential and commercial uses, including alterations to the river's course with bridges, have had a significant impact on the Don's fauna and flora. Pollutants have degraded the river's water quality, a situation exacerbated by the…

  4. Pollution Prevention Progress

    EPA Science Inventory

    P2P no longer supported by EPA it has been replaced by TRACI http://cfpub.epa.gov/crem/knowledge_base/crem_report.cfm?deid=74923

    P2P is a pollutant cl...

  5. Exploring Detergent Pollution

    ERIC Educational Resources Information Center

    Rillo, Thomas J.

    1975-01-01

    Reviews the ecological dangers of certain types of detergents, and the action taken by government agencies and detergent manufacturers to alleviate the problem. Describes classroom activities and instructional procedures designed to illustrate detergent characteristics and the effects of detergent pollution. (MLH)

  6. Marine and Estuarine Pollution.

    ERIC Educational Resources Information Center

    Reish, Donald J.

    1978-01-01

    Presents a literature review of the effects of various pollutants on marine and estuarine organisms, covering publications of 1976-77. This review includes: (1) effects of pesticides, dredging, dumping, sludge, and petroleum hydrocarbons; and (2) diseases and tissue abnormalities. A list of 441 references is also presented. (HM)

  7. Pollution--Who Pays?

    ERIC Educational Resources Information Center

    Ball, D. F.

    1979-01-01

    The cost of dealing with pollution and ensuring an acceptable environment must be regarded as part of the price to be paid for providing ourselves with the products of industrial activity. However, since environmental problems are relative rather than absolute, any judgment of risk needs to be balanced against the assessment of the benefit.…

  8. Shanghai alleviates noise pollution

    SciTech Connect

    Ding Runling

    1983-07-14

    ''Environmental noise is now under control in Shanghai, the level of environmental noise is basically holding steady, and in some areas industrial and traffic noise has decreased.'' These were the conclusions of research by Hong Zonghui (3163 1350 6540) and Wang Shixian (3769 6164 6343) of Tongji University's Acoustics Laboratory, as put forward at a recent public academic lecture at Tongji University. In order to eliminate noise from the environment, Tongji University in the early 1970's began conducting investigations and research on noise pollution and its control together with concerned units in this city. After tests in a network of 2,117 points throughout the city, they determined that the most common form of noise pollution is traffic, which accounts for 50 percent of all noise. Since 1979, this city has adopted successive measures in the area of traffic control in order to eliminate the source of noise. Traffic noise has now dropped about 3 decibels in the city. This research report also pointed out that according to the results of regional environmental noise tests, this city does not meet the noise pollution standards set by the state. Tugboats on the Suzhou He blow their whistles late at night, and the noise at riverside homes can reach 82 decibels; the Fangua Lane residential district is close to a railroad where engine noise can reach 89 decibels and affect the residents' health. In addition, rather serious noise pollution is produced by more than 300 handicraft, light industry, textile, and electrical machinery plants.

  9. Controlling Population with Pollution

    ERIC Educational Resources Information Center

    Browne, Joseph

    2010-01-01

    Population models are often discussed in algebra, calculus, and differential equations courses. In this article we will use the human population of the world as our application. After quick looks at two common models we'll investigate more deeply a model which incorporates the negative effect that accumulated pollution may have on population.

  10. Air Pollution Primer.

    ERIC Educational Resources Information Center

    National Tuberculosis and Respiratory Disease Association, New York, NY.

    As the dangers of polluted air to the health and welfare of all individuals became increasingly evident and as the complexity of the causes made responsibility for solutions even more difficult to fix, the National Tuberculosis and Respiratory Disease Association felt obligated to give greater emphasis to its clean air program. To this end they…

  11. Laser Detection of Pollution.

    ERIC Educational Resources Information Center

    Patel, C. K. N.

    1978-01-01

    Discusses the use of laser spectroscopy in determining the presence of specific gaseous constituents. Three of currently used modes for laser detection of pollution are reviewed; (1) long-path measurements; (2) laser raman (differential absorption) measurements; and (3) optoacoustic detection. (HM)

  12. Pollution Measuring System

    NASA Technical Reports Server (NTRS)

    1980-01-01

    Research Ventures, Inc.'s visiplume is a portable, microprocessor-controlled air pollution monitor for measuring sulfur dioxide emissions from fossil fuel-fired power plants, and facilities that manufacture sulfuric acid. It observes smokestack plumes at a distance from the stack obviating the expense and difficulty of installing sample collectors in each stack and later analyzing the samples.

  13. Fecal Pollution of Water.

    EPA Science Inventory

    Fecal pollution of water from a health point of view is the contamination of water with disease-causing organisms (pathogens) that may inhabit the gastrointestinal tract of mammals, but with particular attention to human fecal sources as the most relevant source of human illnesse...

  14. Noise pollution resources compendium

    NASA Technical Reports Server (NTRS)

    1973-01-01

    Abstracts of reports concerning noise pollution are presented. The abstracts are grouped in the following areas of activity: (1) sources of noise, (2) noise detection and measurement, (3) noise abatement and control, (4) physical effects of noise and (5) social effects of noise.

  15. Testing for Air Pollution.

    ERIC Educational Resources Information Center

    Dunbar, Artice

    Three experiments are presented in this Science Study Aid to provide the teacher with some fundamental air pollution activities. The first experiment involved particulates, the second deals with microorganisms, and the third looks at gases in the atmosphere. Each activity outlines introductory information, objectives, materials required, procedure…

  16. Fine particle pollution

    Atmospheric Science Data Center

    2013-01-10

    ... decade ago, a pioneering study by Harvard's School of Public Health showed that one of the most dangerous forms of air pollution is ... 2.5 are acceptable, based on studies of its effect on human health. For the scientists studying these health effects and for regulators ...

  17. Fecal Pollution of Water

    EPA Science Inventory

    Fecal pollution of water from a health point of view is the contamination of water with disease-causing organisms (pathogens) that may inhabit the gastrointestinal tract of mammals, but with particular attention to human fecal sources as the most relevant source of human illnesse...

  18. The Pollution Detectives.

    ERIC Educational Resources Information Center

    Sanderson, P. L.; Newton, G.

    1986-01-01

    Describes the field work component of a half-term course in environmental chemistry. Discusses the teaching methods used with the students in detecting water pollution. Outlines the activities and experiments in one field trip and presents the results and deductions made by the students. (TW)

  19. POLLUTION PREVENTION RESEARCH STRATEGY

    EPA Science Inventory

    One of the strategic goals of the U.S. Environmental Protection Agency (EPA) is to prevent pollution and reduce risk in communities, homes, workplaces, and ecosystems. This goal must be based in large part on the application of the best available science and technology associat...

  20. Sulfur Dioxide Pollution Monitor.

    ERIC Educational Resources Information Center

    National Bureau of Standards (DOC), Washington, DC.

    The sulfur dioxide pollution monitor described in this document is a government-owed invention that is available for licensing. The background of the invention is outlined, and drawings of the monitor together with a detailed description of its function are provided. A sample stream of air, smokestack gas or the like is flowed through a…

  1. DOAS URBAN POLLUTION MEASUREMENTS

    EPA Science Inventory

    During July and August of 1990, a differential optical absorption spectrometer (DOAS) made by OPSIS Inc. was used to measure gaseous air pollutants over three separate open paths in Atlanta, GA. ver path 1 (1099 m) and path 2 (1824 m), ozone (O3), sulfur dioxide (SO2), nitrogen d...

  2. Exploring Noise: Sound Pollution.

    ERIC Educational Resources Information Center

    Rillo, Thomas J.

    1979-01-01

    Part one of a three-part series about noise pollution and its effects on humans. This section presents the background information for teachers who are preparing a unit on sound. The next issues will offer learning activities for measuring the effects of sound and some references. (SA)

  3. Exploring Noise: Sound Pollution.

    ERIC Educational Resources Information Center

    Rillo, Thomas J.

    1980-01-01

    This article is the last of a three-part series dealing with sound measurement, effects, pollution, and indoor/door learning activities. This section focuses on outdoor activities and equipment that students can make to assist them in data collection. (Author/SA)

  4. AIR POLLUTION AND HUMMINGBIRDS

    EPA Science Inventory

    A multidisciplinary team of EPA-RTP ORD pulmonary toxicologists, engineers, ecologists, and statisticians have designed a study of how ground-level ozone and other air pollutants may influence feeding activity of the ruby-throated hummingbird (Archilochus colubris). Be...

  5. Investigating Ocean Pollution.

    ERIC Educational Resources Information Center

    LeBeau, Sue

    1998-01-01

    Describes a fifth-grade class project to investigate two major forms of ocean pollution: plastics and oil. Students work in groups and read, discuss, speculate, offer opinions, and participate in activities such as keeping a plastics journal, testing the biodegradability of plastics, and simulating oil spills. Activities culminate in…

  6. Water Pollution Control Industry

    ERIC Educational Resources Information Center

    Environmental Science and Technology, 1974

    1974-01-01

    A special report on the state of the water pollution control industry reveals that due to forthcoming federal requirements, sales and the backlogs should increase; problems may ensue because of shortages of materials and inflation. Included are reports from various individual companies. (MLB)

  7. Recent Progress in Optical Chemical Sensors

    PubMed Central

    Qazi, Hummad Habib; Mohammad, Abu Bakar bin; Akram, Muhammad

    2012-01-01

    Optical chemical sensors have promoted escalating interest in the determination of various pollutants in the environment, which are creating toxicity and may cause serious health problems. This review paper focuses particularly on the recent progress and developments in this field; the working principles and basic classes of optical chemical sensors have been briefly described. PMID:23443392

  8. Impact of estuarine pollution on birds

    USGS Publications Warehouse

    Blus, L.J.; Wiemeyer, Stanley N.; Kerwin, J.A.; Stendell, R.C.; Ohlendorf, H.M.; Stickel, L.F.

    1977-01-01

    Pollution of estuaries affects bird populations indirectly through changes in habitat and food supply. The multi-factor pollution of Chesapeake Bay has resulted in diminution of submerged aquatic plants and consequent change in food habits of the canvasback duck. Although dredge-spoil operations can improve wildlife habitat, they often result in its demise. Pollution of estuaries also affects birds directly, through chemical toxication, which may result in outright mortality or in reproductive impairment. Lead from industrial sources and roadways enters the estuaries and is accumulated in tissues of birds. Lead pellets deposited in estuaries as a result of hunting are consumed by ducks with sufficient frequency .to result m large annual die-offs from lead poisoning. Fish in certain areas, usually near industrial sources, may contain levels of mercury high enough to be hazardous to birds that consume them. Other heavy metals are present in estuarine birds, but their significance is poorly known. Oil exerts lethal or sublethal effects on birds by oiling their feathers, oiling eggs and young by contaminated parents, and by ingestion of oil-contaminated food. Organochlorine chemicals, of both agricultural and industrial origin, travel through the food chains and reach harmful levels in susceptible species of birds in certain estuarine ecosystems. Both outright mortality and reproductive impairment have occurred.

  9. Multidimensional evaluation of soil pollution from railway tracks.

    PubMed

    Wierzbicka, Małgorzata; Bemowska-Kałabun, Olga; Gworek, Barbara

    2015-05-01

    Railway transport is a source of pollution to soils and living organisms by e.g. PAHs, PCBs, oil-derived products, pesticides and heavy metals. Soil toxicity evaluation requires chemical analyses, indicating the type and content of particular pollutants, as well as biological analyses, which allow assessing the reaction of organisms to these pollutants. This paper is focused on a multi-aspect evaluation of the degree of toxicity and pollution of soil in selected railway areas from north-eastern Poland by application of numerous biotests and chemical analyses. The soils were sampled on railway tracks from the following railway stations: Białystok Fabryczny, Siemianówka, Hajnówka, Iława Główna and Waliły. The most toxic soils occur on the railway tracks at Białystok Fabryczny and Siemianówka. They had a significant toxic effect on test organisms from various trophic levels. The contents of PAHs, PCBs, heavy metals, oil-derived hydrocarbons and pesticide residues were determined in the examined soils. In all cases the detected pollutants did not exceed the admissible levels. The highest content of oil-derived substances was noted in soils from Białystok Fabryczny and concentrations were moderate in soils from Siemianówka. Although the pollutants determined in soils from railway tracks did not exceed the admissible values, they had a toxic effect on numerous test organisms from different trophic levels. This suggests a synergistic effect of low concentrations (within the admissible levels) of several pollutants together, which resulted in a toxic effect on the organisms. Thus, there is a strong need of not only chemical, but also ecotoxicological analyses during the evaluation of environmental conditions. Based on data obtained from biological and chemical analyses, we concluded that railway transport may pose a hazard to the natural environment to a larger extent that hitherto expected. PMID:25762102

  10. Monitoring air pollution in the Bialowieza Forest

    NASA Astrophysics Data System (ADS)

    Malzahn, Elżbieta; Sondej, Izabela; Paluch, Rafał

    2016-04-01

    Air pollution, as sulfur dioxide(SO2) and nitrous oxides (NOx), affects forest health negatively and can initiate forest dieback. Long-term monitoring (since 1986) and analyses are conducted in the Bialowieza Forest due to the threat by abiotic, biotic and anthropogenic factors. This forest has a special and unique natural value, as confirmed by the various forms of protection of national and international rank. The main aim of monitoring is to determine the level and trends of deposition of air pollutants and their effects on selected forest stands and forest communities in the Bialowieza Forest. Concentration measurements of gaseous pollutants and the chemical composition of the precipitation are performed at seven points within the forest area (62 219 ha). Measurement gauges are measuring gaseous pollutants (SO2 and NOx) by the passive method and collecting precipitation at each point at a height of three meters. The period of measuring by the instruments is 30 days. All analyses are conducted according to the methodology of the European forest monitoring program in the certified Laboratory of Natural Environment Chemistry of the Polish Forest Research Institute (IBL). The concentration of pollutant gases (dry deposition) in the years 2002-2015 accounted for only 6-13% of the limit in Poland, as defined by the Polish Ministry of Environment, and are of no threat to the forest environment. Wet deposition of pollutants, which dependents directly from the amount of precipitation and its concentration of pollutants, varied strongly between different months and years. Total deposition (dry and wet) of sulfur (S) and nitrogen (N) was calculated for seasonal and annual periods. On an annual basis, wet deposition represented approximately 80% of the total deposition of S and N. Total deposition of S did not exceed the average deposition values for forests in north-eastern Europe (5-10 kg ha‑1 year‑1) at any of the seven measuring points. Total deposition of N did

  11. INTEGRATION OF POLLUTION PREVENTION TOOLS

    EPA Science Inventory

    A prototype computer-based decision support system was designed to provide small businesses with an integrated pollution prevention methodology. Preliminary research involved compilation of an inventory of existing pollution prevention tools (i.e., methodologies, software, etc.),...

  12. Particulate Air Pollution: The Particulars

    ERIC Educational Resources Information Center

    Murphy, James E.

    1973-01-01

    Describes some of the causes and consequences of particulate air pollution. Outlines the experimental procedures for measuring the amount of particulate materials that settles from the air and for observing the nature of particulate air pollution. (JR)

  13. Amphetamines Polluting Some Urban Streams

    MedlinePlus

    ... or federal policy. More Health News on: Medicines Water Pollution Recent Health News Related MedlinePlus Health Topics Medicines Methamphetamine Water Pollution About MedlinePlus Site Map FAQs Contact Us Get ...

  14. AGRICULTURAL NONPOINT SOURCE POLLUTION (AGNPS)

    EPA Science Inventory

    Developed by the USDA Agricultural Research Service, Agricultural Nonpoint Source Pollution (AGNPS) model addresses concerns related to the potential impacts of point and nonpoint source pollution on surface and groundwater quality (Young et al., 1989). It was designed to quantit...

  15. Reduction potential, shadow prices, and pollution costs of agricultural pollutants in China.

    PubMed

    Tang, Kai; Gong, Chengzhu; Wang, Dong

    2016-01-15

    This paper analyses the reduction potential, shadow prices, and pollution costs of agricultural pollutants in China based on provincial panel data for 2001-2010. Using a parameterized quadratic form for the directional output distance function, we find that if agricultural sectors in all provinces were to produce on the production frontier, China could potentially reduce agricultural emissions of chemical oxygen demand (COD), total nitrogen (TN), and total phosphorus (TP) by 16.0%, 16.2%, and 20.4%, respectively. Additionally, our results show that the shadow price of TN increased rapidly and continuously, while that of COD and TP fluctuated for the whole period. For the whole country, the average shadow price of COD, TN, and TP are 8266 Yuan/tonne, 25,560 Yuan/tonne, and 10,160 Yuan/tonne, respectively. The regional shadow prices of agricultural pollutants are unbalanced. Furthermore, we show that the pollution costs from emissions of COD, TN, and TP are 6.09% of the annual gross output value of the agricultural sector and are highest in the Western and lowest in the Eastern provinces. Our estimates suggest that there is scope for further pollution abatement and simultaneous output expansion for China's agriculture if farmers promote greater efficiency in their production process. Policymakers are required to dynamically adjust the pollution tax rates and ascertain the initial permit price in an emission trading system. Policymakers should also consider the different pollution costs for each province when making the reduction allocations within the agricultural sector. PMID:26398449

  16. E-Alerts: Environmental pollution and control (solid waste pollution and control). E-mail newsletter

    SciTech Connect

    1999-04-01

    The paper discusses pollution by solid wastes including garbage, scrap, junked automobiles, spoil, sludge, containers; Disposal methods such as composts or land application, injection wells, incineration, sanitary landfills; Mining wastes; Processing for separation and materials recovery; Solid waste utilization; Recycling; Biological and ecological effects; Superfund (Records of Decision, etc.); SITE technology; Laws, legislation, and regulations; Public administration; Economics; Land use. The discussion includes disposal of concentrated or pure liquids such as brines, oils, chemicals, and hazardous materials.

  17. Atlantic and Indian Oceans Pollution in Africa

    NASA Astrophysics Data System (ADS)

    Abubakar, B.

    2007-05-01

    Africa is the second largest and most populated continent after Asia. Geographically it is located between the Atlantic and Indian Oceans. Most of the Africa's most populated and industrialized cities are located along the coast of the continent facing the Atlantic and Indian Oceans, example of such cities include Casablanca, Dakar, Accra, Lagos, Luanda and Cape town all facing the Atlantic Ocean and cities like East London, Durban, Maputo, Dar-es-salaam and Mogadishu are all facing the Indian Ocean. As a result of the geographical locations of African Coastal Cities plus increase in their population, industries, sea port operations, petroleum exploration activities, trafficking of toxic wastes and improper waste management culture lead to the incessant increase in the pollution of the two oceans. NATURE OF POLLUTION OF THE ATLANTIC OCEAN i. The petroleum exploration activities going on along the coast of "Gulf of Guinea" region and Angola continuously causes oil spillages in the process of drilling, bunkering and discharging of petroleum products in the Atlantic Ocean. ii. The incessant degreasing of the Sea Ports "Quay Aprons" along the Coastal cities of Lagos, Luanda, Cape Town etc are continuously polluting the Atlantic Ocean with chemicals. iii. Local wastes generated from the houses located in the coastal cities are always finding their ways into the Atlantic Ocean. NATURE OF POLLUTION OF THE INDIAN OCEAN i. Unlike the Atlantic ocean where petroleum is the major pollutant, the Indian Ocean is polluted by Toxic / Radioactive waste suspected to have been coming from the developed nations as reported by the United Nations Environmental Programme after the Tsunami disaster in December 2004 especially along the coast of Somalia. ii. The degreasing of the Quay Aprons at Port Elizabeth, Maputo, Dar-es-Salaam and Mongolism Sea Ports are also another major source polluting the Indian Ocean. PROBLEMS GENERATED AS A RESULT OF THE OCEANS POLLUTION i. Recent report

  18. Chemical munitions dumped at sea

    NASA Astrophysics Data System (ADS)

    Edwards, Margo; Bełdowski, Jacek

    2016-06-01

    Modern chemical warfare is a byproduct of the industrial revolution, which created factories capable of rapidly producing artillery shells that could be filled with toxic chemicals such as chlorine, phosgene and mustard agent. The trench warfare of World War I inaugurated extensive deployments of modern chemical weapons in 1915. Concomitantly, the need arose to dispose of damaged, captured or excess chemical munitions and their constituents. Whereas today chemical warfare agents (CWA) are destroyed via chemical neutralization processes or high-temperature incineration in tandem with environmental monitoring, in the early to middle 20th century the options for CWA disposal were limited to open-air burning, burial and disposal at sea. The latter option was identified as the least likely of the three to impact mankind, and sea dumping of chemical munitions commenced. Eventually, the potential impacts of sea dumping human waste were recognized, and in 1972 an international treaty, the Convention on the Prevention of Marine Pollution by Dumping of Wastes and Other Matter, was developed to protect the marine environment from pollution caused by the dumping of wastes and other matter into the ocean. By the time this treaty, referred to as the London Convention, was signed by a majority of nations, millions of tons of munitions were known to have been disposed throughout the world's oceans.

  19. Air Pollution Control, Part I.

    ERIC Educational Resources Information Center

    Strauss, Werner, Ed.

    Authoritative reviews in seven areas of current importance in air pollution control are supplied in this volume, the first of a two-part set. Titles contained in this book are: "Dispersion of Pollutants Emitted into the Atmosphere,""The Formation and Control of Oxides of Nitrogen in Air Pollution,""The Control of Sulfur Emissions from Combustion…

  20. The Federal Air Pollution Program.

    ERIC Educational Resources Information Center

    National Air Pollution Control Administration (DHEW), Washington, DC.

    Described is the Federal air pollution program as it was in 1967. The booklet is divided into these major topics: History of the Federal Program; Research; Assistance to State and Local Governments; Abatement and Prevention of Air Pollution; Control of Motor Vehicle Pollution; Information and Education; and Conclusion. Federal legislation has…

  1. Remote Sensing of Water Pollution

    NASA Technical Reports Server (NTRS)

    White, P. G.

    1971-01-01

    Remote sensing, as a tool to aid in the control of water pollution, offers a means of making rapid, economical surveys of areas that are relatively inaccessible on the ground. At the same time, it offers the only practical means of mapping pollution patterns that cover large areas. Detection of oil slicks, thermal pollution, sewage, and algae are discussed.

  2. Phytoremediation of ionic and methylmercury pollution

    SciTech Connect

    Meagher, Richard B

    2010-04-28

    Our long-term goal is to enable highly productive plant species to extract, resist, detoxify, and sequester the toxic elemental pollutants, like the heavy metal mercury. Our current working hypothesis is that transgenic plants controlling the transport, chemical speciation, electrochemical state. volatilization, and aboveground binding of mercury will: a) tolerate mercury and grow rapidly in mercury contaminated environments; b) prevent methylmercury from entering the food chain; c) remove mercury from polluted soil and . water; and d) hyperaccumulate mercury in aboveground tissues for later harvest. Progress toward these specific aims is reported: to increase the transport of mercury into roots and to aboveground vegetative organs; to increase biochemical sinks and storage for mercury in leaves; to increase leaf cell vacuolar storage of mercury; and to demonstrate that several stacked transgenes, when functioning in concert, enhance mercury resistance and hyperaccumulation to high levels.

  3. Ovarian cancer mortality and industrial pollution.

    PubMed

    García-Pérez, Javier; Lope, Virginia; López-Abente, Gonzalo; González-Sánchez, Mario; Fernández-Navarro, Pablo

    2015-10-01

    We investigated whether there might be excess ovarian cancer mortality among women residing near Spanish industries, according to different categories of industrial groups and toxic substances. An ecologic study was designed to examine ovarian cancer mortality at a municipal level (period 1997-2006). Population exposure to pollution was estimated by means of distance from town to facility. Using Poisson regression models, we assessed the relative risk of dying from ovarian cancer in zones around installations, and analyzed the effect of industrial groups and pollutant substances. Excess ovarian cancer mortality was detected in the vicinity of all sectors combined, and, principally, near refineries, fertilizers plants, glass production, paper production, food/beverage sector, waste treatment plants, pharmaceutical industry and ceramic. Insofar as substances were concerned, statistically significant associations were observed for installations releasing metals and polycyclic aromatic chemicals. These results support that residing near industries could be a risk factor for ovarian cancer mortality. PMID:26046426

  4. China's water pollution by persistent organic pollutants.

    PubMed

    Bao, Lian-Jun; Maruya, Keith A; Snyder, Shane A; Zeng, Eddy Y

    2012-04-01

    Available data were reviewed to assess the status of contamination by persistent organic pollutants (POPs), including organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs), polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs), perfluorooctane sulfonate (PFOS) and perfluorooctanoate (PFOA), in drinking water sources and coastal waters of China. The levels of POPs in China's waters were generally at the high end of the global range. A comparison of China's regulatory limits indicated that PCBs in rivers and coastal water may pose potential human health risk. Occurrence of DDTs in some rivers of China may also pose health risk to humans using the regulatory limits of DDTs recommended by the European Union. Future monitoring of POPs in China's waters should be directed towards analytes of concern (e.g. PCBs and PCDD/Fs) and to fill data gaps for analytes (e.g. PBDEs, PCDD/Fs, and chlordane) and in watersheds/regions (e.g. West China) where data are scarce. PMID:22325437

  5. The Effects of Organic Pollutants in Soil on Human Health

    NASA Astrophysics Data System (ADS)

    Burgess, Lynn

    2013-04-01

    The soil has always been depository of the organic chemicals produced naturally or anthropogenically. Soil contamination is a serious human and environmental problem. A large body of evidence has shown the risks of adverse health effects with the exposure to contaminated soil due to the large quantities of organic chemicals used in agriculture and urban areas that have a legacy of environmental pollution linked to industrial activities, coal burning, motor vehicle emissions, waste incineration and waste dumping. In agricultural areas, because of the effort to provide adequate quantities of agricultural products, farmers have been using an increasing amount of organic chemicals, but the resulting pollution has enormous potential for environmental damage. The types of organic pollutants commonly found in soils are polychlorinated biphenyls, polybrominated biphenyls, polychlorinated dibenzofurans, polycyclic aromatic hydrocarbons, organophosphorus and carbamate insecticides, herbicides and organic fuels, especially gasoline and diesel. Another source of soil pollution is the complex mixture of organic chemicals, metals and microorganisms in the effluent from septic systems, animal wastes and other sources of biowaste. The soils of the world are a vast mixture of chemicals and although conditions are such that an individual is rarely exposed to a single compound, the great majority of people are exposed to a vast chemical mixture of organics, their metabolites, and other compounds at low concentrations Human exposure to organic pollutants in the soil is an area of toxicology that is very difficult to study due to the low concentration of the pollutants. The toxicological studies of single organic pollutants found in soils are limited and research on the metabolites and of chemical mixtures is very limited. The majority of toxicological studies are conducted at relatively high doses and for short periods of exposure. This makes the application of this data to exposure

  6. Lead polluters get punished

    SciTech Connect

    Not Available

    1991-08-09

    The Environmental Protection Agency (EPA) and the Department of Justice last week cracked down on 36 US companies for polluting the environment with lead. EPA slapped fines totaling more than $10 million on 12 of the offending companies, and Justice filed 24 civil complaints. Hank Habicht, deputy administrator of the EPA, said that his agency's initiative comes after 8 months of intense - and presumably successful - efforts at locating and documenting lead pollution in the soil, air, and water supply. Most feared has been lead's ability to damage the intellectual development of children. This caused the agency, Habicht said, to look beyond the usual suspect - lead in the water supply - to lead-laced dirt in residential areas. Meanwhile, the Department of Justice is using the EPA contamination data as well. Twenty US attorneys have been assigned to pore over the federal environmental statutes, including the Clean Water Act and the Superfund Law, in order to file civil complaints.

  7. Air pollution source identification

    NASA Technical Reports Server (NTRS)

    Fordyce, J. S.

    1975-01-01

    Techniques for air pollution source identification are reviewed, and some results obtained with them are evaluated. Described techniques include remote sensing from satellites and aircraft, on-site monitoring, and the use of injected tracers and pollutants themselves as tracers. The use of a large number of trace elements in ambient airborne particulate matter as a practical means of identifying sources is discussed in detail. Sampling and analysis techniques are described, and it is shown that elemental constituents can be related to specific source types such as those found in the earth's crust and those associated with specific industries. Source identification sytems are noted which utilize charged particle X-ray fluorescence analysis of original field data.

  8. Air pollution source identification

    NASA Technical Reports Server (NTRS)

    Fordyce, J. S.

    1975-01-01

    The techniques available for source identification are reviewed: remote sensing, injected tracers, and pollutants themselves as tracers. The use of the large number of trace elements in the ambient airborne particulate matter as a practical means of identifying sources is discussed. Trace constituents are determined by sensitive, inexpensive, nondestructive, multielement analytical methods such as instrumental neutron activation and charged particle X-ray fluorescence. The application to a large data set of pairwise correlation, the more advanced pattern recognition-cluster analysis approach with and without training sets, enrichment factors, and pollutant concentration rose displays for each element is described. It is shown that elemental constituents are related to specific source types: earth crustal, automotive, metallurgical, and more specific industries. A field-ready source identification system based on time and wind direction resolved sampling is described.

  9. Use of Chemical Analysis and Assays of Semipermeable Membrane Devices Extracts to Assess the Response of Bioavailable Organic Pollutants in Streams to Urbanization in Six Metropolitan Areas of the United States

    USGS Publications Warehouse

    Bryant, Wade L.; Goodbred, Steve L.; Leiker, Thomas L.; Inouye, Laura; Johnson, B. Thomas

    2007-01-01

    Studies to assess the effects of urbanization on stream ecosystems are being conducted as part of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program. The overall objectives of these studies are to (1) determine how hydrologic, geomorphic, water quality, habitat, and biological characteristics respond to land-use changes associated with urbanization in specific environmental settings, and (2) compare these responses across environmental settings. As part of an integrated assessment, semipermeable membrane devices (SPMDs) were deployed in streams along a gradient of urban land-use intensity in and around Atlanta, Georgia; Raleigh-Durham, North Carolina; and Denver-Fort Collins, Colorado, in 2003; and Dallas-Fort Worth, Texas; Milwaukee-Green Bay, Wisconsin; and Portland, Oregon, in 2004. Sites were selected to avoid point-source discharge and to minimize natural variability within each of the six metropolitan areas. In addition to standard chemical analysis for hydrophobic organic contaminants, three assays were used to address mixtures and potential toxicity: (1) Fluoroscan provides an estimate of the total concentration of polycyclic aromatic hydrocarbons (PAHs); (2) the P450RGS assay indicates the presence and levels of aryl hydrocarbon receptor agonists; and (3) Microtox? measures toxicological effects on photo-luminescent bacteria. Of the 140 compounds targeted or identified by gas chromatography/mass spectrometry analysis in this study, 67 were not detected. In terms of numbers and types of compounds, the following were detected: 2 wood preservatives, 6 insecticides (parent compounds), 5 herbicides, 22 polycyclic aromatic hydrocarbons, 2 dibenzofurans, 4 polychlorinated biphenyls, 7 compounds associated with fragrances or personal care products, 4 steroids associated with wastewater, 5 polydibromated diphenyl ethers (flame retardants), 3 plasticizers, 3 antimicrobials/disinfectants, and 3 detergent metabolites. Of the 73 compounds

  10. OIL POLLUTION ABSTRACTS. VOLUME 6, NUMBER 1

    EPA Science Inventory

    Oil Pollution Abstracts (formerly entitled Oil Pollution Reports) is a quarterly compilation of abstracts of current oil pollution related literature and research projects. Comprehensive coverage of oil pollution and its prevention and control is provided, with emphasis on the aq...

  11. OIL POLLUTION REPORTS. VOLUME 5, NUMBER 4

    EPA Science Inventory

    OIL POLLUTION REPORTS (formerly OIL SPILL AND OIL POLLUTION REPORTS) is a quarterly compilation of abstracts of current oil pollution related literature, research projects, and conferences. Comprehensive coverage of terrestrial and aquatic oil pollution and its prevention and con...

  12. Innovation for Pollution Control

    NASA Technical Reports Server (NTRS)

    1986-01-01

    Kinetic Controls Inc.'s refuse-fired steam generating facility led to the development of an air pollution equipment control device. The device is currently marketed by two NASA/Langley Research Center employees. It automatically senses and compensates for the changes in smoke composition when refuse is used as a fuel by adjusting the precipitator's voltage and current to permit maximum collection of electrically charged dust particles. The control adapts to any electrostatic precipitator and should have extensive commercial applications.

  13. China's international trade and air pollution in the United States.

    PubMed

    Lin, Jintai; Pan, Da; Davis, Steven J; Zhang, Qiang; He, Kebin; Wang, Can; Streets, David G; Wuebbles, Donald J; Guan, Dabo

    2014-02-01

    China is the world's largest emitter of anthropogenic air pollutants, and measurable amounts of Chinese pollution are transported via the atmosphere to other countries, including the United States. However, a large fraction of Chinese emissions is due to manufacture of goods for foreign consumption. Here, we analyze the impacts of trade-related Chinese air pollutant emissions on the global atmospheric environment, linking an economic-emission analysis and atmospheric chemical transport modeling. We find that in 2006, 36% of anthropogenic sulfur dioxide, 27% of nitrogen oxides, 22% of carbon monoxide, and 17% of black carbon emitted in China were associated with production of goods for export. For each of these pollutants, about 21% of export-related Chinese emissions were attributed to China-to-US export. Atmospheric modeling shows that transport of the export-related Chinese pollution contributed 3-10% of annual mean surface sulfate concentrations and 0.5-1.5% of ozone over the western United States in 2006. This Chinese pollution also resulted in one extra day or more of noncompliance with the US ozone standard in 2006 over the Los Angeles area and many regions in the eastern United States. On a daily basis, the export-related Chinese pollution contributed, at a maximum, 12-24% of sulfate concentrations over the western United States. As the United States outsourced manufacturing to China, sulfate pollution in 2006 increased in the western United States but decreased in the eastern United States, reflecting the competing effect between enhanced transport of Chinese pollution and reduced US emissions. Our findings are relevant to international efforts to reduce transboundary air pollution. PMID:24449863

  14. Intercontinental Transport of Air Pollution

    NASA Technical Reports Server (NTRS)

    Rogers, David; Whung, Pai-Yei; Einaudi, Franco (Technical Monitor)

    2001-01-01

    The development of the global economy goes beyond raising our standards of living. We are in an ear of increasing environmental as well as economic interdependence. Long-range transport of anthropogenic atmospheric pollutants such as ozone, ozone precursors, airborne particles, heavy metals (such as mercury) and persistent organic pollutants are the four major types of pollution that are transported over intercontinental distances and have global environmental effects. The talk includes: 1) an overview of the international agreements related to intercontinental transport of air pollutants, 2) information needed for decision making, 3) overview of the past research on intercontinental transport of air pollutants - a North American's perspective, and 4) future research needs.

  15. Atlantic and indian oceans pollution in africa

    NASA Astrophysics Data System (ADS)

    Abubakar, Babagana

    Africa is the second largest and most populated continent after Asia. Geographically it is located between the Atlantic and Indian Oceans. Most of the Africa's most populated and industrialized cities are located along the coast of the continent facing the Atlantic and Indian Oceans, example of such cities include Casablanca, Dakar, Accra, Lagos, Luanda and Cape town all facing the Atlantic Ocean and cities like East London, Durban, Maputo, Dar-es-salaam and Mogadishu are all facing the Indian Ocean. As a result of the geographical locations of African Coastal Cities plus increase in their population, industries, sea port operations, petroleum exploration activities, trafficking of toxic wastes and improper waste management culture lead to the incessant increase in the pollution of the two oceans. NATURE OF POLLUTION OF THE ATLANTIC OCEAN i. The petroleum exploration activities going on along the coast of "Gulf of Guinea" region and Angola continuously causes oil spillages in the process of drilling, bunkering and discharging of petroleum products in the Atlantic Ocean. ii. The incessant degreasing of the Sea Ports "Quay Aprons" along the Coastal cities of Lagos, Luanda, Cape Town etc are continuously polluting the Atlantic Ocean with chemicals. iii. Local wastes generated from the houses located in the coastal cities are always finding their ways into the Atlantic Ocean. NATURE OF POLLUTION OF THE INDIAN OCEAN i. Unlike the Atlantic ocean where petroleum is the major pollutant, the Indian Ocean is polluted by Toxic / Radioactive waste suspected to have been coming from the developed nations as reported by the United Nations Environmental Programme after the Tsunami disaster in December 2004 especially along the coast of Somalia. ii. The degreasing of the Quay Aprons at Port Elizabeth, Maputo, Dar-es-Salaam and Mongolism Sea Ports are also another major source polluting the Indian Ocean. PROBLEMS GENERATED AS A RESULT OF THE OCEANS POLLUTION i. Recent report

  16. The Economics of Pollution; Part Three: Can Pollution Be Controlled? Teaching About: Can Pollution Be Controlled?

    ERIC Educational Resources Information Center

    Wolozin, Harold; Reilly, Patricia R.

    In this third of three articles on the economics of pollution control general statements from several sources present a background which questions our ability to devise the necessary tools to fight pollution, even if adequate expenditures of money are provided. In the struggle to control pollution, the economist, it is believed, can provide…

  17. Issues of Rural Light Pollution

    NASA Astrophysics Data System (ADS)

    Osborn, W. H.; Hammer, R. L.; Hammer, A.

    2001-12-01

    Light pollution is generally considered mostly an urban problem. Common sources of light pollution are poorly designed lighting of streets, parking lots, businesses and advertizing signs and for security. These sources, and the amount of light pollution generated, increase with population density. Nevertheless, light pollution can also be significant in rural areas. Rural light pollution differs from that in urban settings, both in the types of pollution and in the means that must be employed to control it. In the country the offending sources are often isolated lights such as from farm barns, vacation cottages, radio and cell phone towers, and road intersections. A culture of strong property rights and privacy rights affects attempts to control rural light pollution. We describe how some of these issues may be addressed based on the results from an Eagle Scout project carried out in central Michigan.

  18. Storm water pollution prevention plans

    SciTech Connect

    Rossmiller, R.L. )

    1993-03-01

    National Pollutant Discharge Elimination System (NPDES) general permit applications for industrial storm water discharge were to have been filed by October 1992. The Environmental Protection Agency (EPA) and state agencies are now issuing permits based on these applications. One compliance aspect of the permits is the Storm Water Pollution Prevention Plan (SWP3). The plan must identify the facility's potential sources of storm water pollution and develop and implement best management practices (BMPs) to reduce pollutants in storm water runoff. The objectives of the NPDES storm water program are to eliminate illegal dumping and illicit connections, and to reduce pollutants in industrial storm water discharge. These regulations require industry to develop detailed facility site maps, and describe the types, amounts and locations of potential pollutants. Based on this information, industry can develop and implement best management practices to reduce pollutants in storm water runoff.

  19. Outdoor air pollution and asthma

    PubMed Central

    Guarnieri, Michael; Balmes, John R.

    2015-01-01

    Traffic and power generation are the main sources of urban air pollution. The idea that outdoor air pollution can cause exacerbations of pre-existing asthma is supported by an evidence base that has been accumulating for several decades, with several studies suggesting a contribution to new-onset asthma as well. In this Series paper, we discuss the effects of particulate matter (PM), gaseous pollutants (ozone, nitrogen dioxide, and sulphur dioxide), and mixed traffic-related air pollution. We focus on clinical studies, both epidemiological and experimental, published in the previous 5 years. From a mechanistic perspective, air pollutants probably cause oxidative injury to the airways, leading to inflammation, remodelling, and increased risk of sensitisation. Although several pollutants have been linked to new-onset asthma, the strength of the evidence is variable. We also discuss clinical implications, policy issues, and research gaps relevant to air pollution and asthma. PMID:24792855

  20. Isotope Effects as New Proxies for Organic Pollutant Transformation.

    PubMed

    Hofstetter, Thomas B; Bolotin, Jakov; Pati, Sarah G; Skarpeli-Liati, Marita; Spahr, Stephanie; Wijker, Reto S

    2014-11-01

    Assessing the pathways and rates of organic pollutant transformation in the environment is a major challenge due to co-occurring transport and degradation processes. Measuring changes of stable isotope ratios (e.g. (13)C/(12)C, (2)H/(1)H, (15)N/(14)N) in individual organic compounds by compound-specific isotope analysis (CSIA) makes it possible to identify degradation pathways without the explicit need to quantify pollutant concentration dynamics. The so-called isotope fractionation observed in an organic pollutant is related to isotope effects of (bio)chemical reactions and enables one to characterize pollutant degradation even if multiple processes take place simultaneously. Here, we illustrate some principles of CSIA using benzotriazole, a frequently observed aquatic micropollutant, as example. We show subsequently how the combined C and N isotope fractionation analysis of nitroaromatic compounds reveals kinetics and mechanisms of reductive and oxidative reactions as well as their (bio)degradation pathways in the environment. PMID:26508486

  1. Integrated pollution evaluation of the Tagus River in Central Spain.

    PubMed

    Berzas Nevado, J J; Rodríguez Martín-Doimeadios, R C; Guzmán Bernardo, F J; Jiménez Moreno, M; Ortega Tardío, S; Sánchez-Herrera Fornieles, M M; Martín-Nieto Ríos, S; Doncel Pérez, A

    2009-09-01

    The aim of this study was to integrate hydrochemical and sediment data in order to obtain a picture of the pollution state of the Tagus River along central Spain. This area is of special interest because tributaries from the Madrid region are discharged and no previous data were available. Waters and sediments were sampled between 2002 and 2004 from selected sites before and after Jarama River confluence (Madrid city input). The samples were analysed for more than 50 parameters, including those of physico-chemical nature and those reporting the pollution caused by both metals and organic compounds. The quality of waters for different uses has been tested and statistical quality indexes of both global and partial type has also been established. Sediments pollution state was evaluated by comparison with general quality standards. A high degree of pollution and general degradation was observed in the Tagus River downstream the Jarama River input. The pollution of waters is mainly related to parameters indicators of organic pollution from urban sewage. In sediments, a dramatic increase in the concentration of trace metals was found in different points, exceeding toxicological threshold. Further studies would be necessary for organic pollutants and also to evaluate the remobilization potential. PMID:18758980

  2. Ambient and household air pollution: complex triggers of disease

    PubMed Central

    Farmer, Stephen A.; Nelin, Timothy D.; Falvo, Michael J.

    2014-01-01

    Concentrations of outdoor air pollution are on the rise, particularly due to rapid urbanization worldwide. Alternatively, poor ventilation, cigarette smoke, and other toxic chemicals contribute to rising concentrations of indoor air pollution. The World Health Organization recently reported that deaths attributable to indoor and outdoor air pollutant exposure are more than double what was originally documented. Epidemiological, clinical, and animal data have demonstrated a clear connection between rising concentrations of air pollution (both indoor and outdoor) and a host of adverse health effects. During the past five years, animal, clinical, and epidemiological studies have explored the adverse health effects associated with exposure to both indoor and outdoor air pollutants throughout the various stages of life. This review provides a summary of the detrimental effects of air pollution through examination of current animal, clinical, and epidemiological studies and exposure during three different periods: maternal (in utero), early life, and adulthood. Additionally, we recommend future lines of research while suggesting conceivable strategies to curb exposure to indoor and outdoor air pollutants. PMID:24929855

  3. Buddha's birthplace (Lumbini, Nepal) is polluted

    NASA Astrophysics Data System (ADS)

    Rupakheti, Dipesh; Adhikary, Bhupesh; Praveen Puppala, Siva; Kang, Shichang; Naja, Manish; Panday, Arnico; Zhang, Qianggong; Rupakheti, Maheswar; Mahata, Khadak; Lawrence, Mark

    2016-04-01

    Lumbini, in southern Nepal, is a UNESCO world heritage site of universal value as the birthplace of the Buddha. Poor air quality in Lumbini and surrounding regions is a great concern for public health as well as for preservation, protection and promotion of Buddhist heritage and culture. Measurements of the ambient concentrations of key air pollutants (BC, PM, CO, O3) were conducted in Lumbini, first of its kind in Lumbini, during an intensive measurement period of three months (April-June 2013) in the pre-monsoon season. The measurements were carried out as a part of the international air pollution measurement campaign; SusKat-ABC (Sustainable Atmosphere for the Kathmandu Valley - Atmospheric Brown Clouds). Hourly average concentrations were: BC: 4.9±3.8 (0.3-29.9) μg/m3; CO: 344.1±160.3 (124.9-1429.7) ppbv; O3: 46.6±20.3 (0.85-118.1) ppbv; PM10: 128.8±91.9 (10.5-603.9) μg/m3; and PM2.5: 53.1±35.1 (6.1-272.2) μg/m3. These levels are comparable to heavily polluted sites in the region. The 24-h average PM2.5 and PM10 concentrations frequently (94% and 85%, respectively, of the sampled period) exceeded the WHO guideline, which implies significant health risks for the residents and visitors in the region. Clear diurnal cycles were observed for the pollutants. Occurrences of peak concentrations during the study period were due to regional forest fires and meteorological conditions conducive of transport to Lumbini. The WRF-STEM model was used to simulate the meteorology and the pollution concentration, and showed the model concentration to be lower by a factor of ~1.4-5, even though the model was able to capture the observed variability. Regionally tagged CO tracers and the chemical composition of fine mode PM2.5 was obtained from the model. The aerosol spectral light absorption coefficients obtained from Lumbini indicated presence of BC from both biomass burning and fossil fuel combustion, with more than half of the ambient BC attributable to fossil fuel

  4. Dispersion modeling of air pollutants in the atmosphere: a review

    NASA Astrophysics Data System (ADS)

    Leelőssy, Ádám; Molnár, Ferenc; Izsák, Ferenc; Havasi, Ágnes; Lagzi, István; Mészáros, Róbert

    2014-09-01

    Modeling of dispersion of air pollutants in the atmosphere is one of the most important and challenging scientific problems. There are several natural and anthropogenic events where passive or chemically active compounds are emitted into the atmosphere. The effect of these chemical species can have serious impacts on our environment and human health. Modeling the dispersion of air pollutants can predict this effect. Therefore, development of various model strategies is a key element for the governmental and scientific communities. We provide here a brief review on the mathematical modeling of the dispersion of air pollutants in the atmosphere. We discuss the advantages and drawbacks of several model tools and strategies, namely Gaussian, Lagrangian, Eulerian and CFD models. We especially focus on several recent advances in this multidisciplinary research field, like parallel computing using graphical processing units, or adaptive mesh refinement.

  5. Interior Landscape Plants for Indoor Air Pollution Abatement

    NASA Technical Reports Server (NTRS)

    Wolverton, B. C.; Johnson, Anne; Bounds, Keith

    1989-01-01

    In this study, the leaves, roots, soil, and associated microorganisms of plants have been evaluated as a possible means of reducing indoor air pollutants. Additionally, a novel approach of using plant systems for removing high concentrations of indoor air pollutants such as cigarette smoke, organic solvents, and possibly radon has been designed from this work. This air filter design combines plants with an activated carbon filter. The rationale for this design, which evolved from wastewater treatment studies, is based on moving large volumes of contaminated air through an activated carbon bed where smoke, organic chemicals, pathogenic microorganisms (if present), and possibly radon are absorbed by the carbon filter. Plant roots and their associated microorganisms then destroy the pathogenic viruses, bacteria, and the organic chemicals, eventually converting all of these air pollutants into new plant tissue. It is believed that the decayed radon products would be taken up the plant roots and retained in the plant tissue.

  6. Impact of Environmental Pollution on the Preservation of Archives and Records: A RAMP Study.

    ERIC Educational Resources Information Center

    Pascoe, M. W.

    Following a description of the essential chemical and physical structures of most archive documents, this paper examines the various pollutants that can damage these documents and gives their characteristics. The pollutants are categorized as environmental (e.g., smokes, mineral dusts); exterior gas and vapor (e.g., oxygen, water, sulphur…

  7. DEVELOPMENT OF THE U.S. EPA'S METAL FINISHING FACILITY POLLUTION PREVENTION TOOL

    EPA Science Inventory

    Metal finishing processes are a type of chemical processes and can be modeled using Computer Aided Process Engineering (CAPE). Currently, the U.S. EPA is developing the Metal Finishing Facility Pollution Prevention Tool (MFFP2T), a pollution prevention software tool for the meta...

  8. 40 CFR Table 8 to Part 455 - List of Pollution Prevention Alternative Practices

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 30 2014-07-01 2014-07-01 false List of Pollution Prevention Alternative Practices 8 Table 8 to Part 455 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS (CONTINUED) PESTICIDE CHEMICALS Pt. 455, Table 8 Table 8 to Part 455—List of Pollution Prevention...

  9. 40 CFR Table 8 to Part 455 - List of Pollution Prevention Alternative Practices

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 30 2011-07-01 2011-07-01 false List of Pollution Prevention Alternative Practices 8 Table 8 to Part 455 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS PESTICIDE CHEMICALS Pt. 455, Table 8 Table 8 to Part 455—List of Pollution Prevention Alternative Practices...

  10. Biomass - chemicals

    SciTech Connect

    Kovaly, K.A.

    1982-08-01

    A host of industrial chemicals, specialty items, solvents, plastics, elastomers, fibers and films can be produced from agricultural crops, wood, paper mill wastes, food processing wastes, municipal waste and sewage. Existing chemical processes based on readily renewable plant materials are reviewed. These include ethanol and acetone-butanol fermentations, oilseed chemicals, furfural and cellulosics. (Refs. 16).

  11. Chemical sensor

    NASA Technical Reports Server (NTRS)

    Rauh, R. David (Inventor)

    1990-01-01

    A sensor for detecting a chemical substance includes an insertion element having a structure which enables insertion of the chemical substance with a resulting change in the bulk electrical characteristics of the insertion element under conditions sufficient to permit effective insertion; the change in the bulk electrical characteristics of the insertion element is detected as an indication of the presence of the chemical substance.

  12. Pollutant swapping: greenhouse gas emissions from wetland systems constructed to mitigate agricultural pollution

    NASA Astrophysics Data System (ADS)

    Freer, Adam; Quinton, John; Surridge, Ben; McNamara, Niall

    2014-05-01

    Diffuse (non-point) water pollution from agricultural land continues to challenge water quality management, requiring the adoption of new land management practices. The use of constructed agricultural wetlands is one such practice, designed to trap multiple pollutants mobilised by rainfall prior to them reaching receiving water. Through capturing and storing pollutants in bottom sediments, it could be hypothesised that the abundance of nutrients stored in the anoxic conditions commonly found in these zones may lead to pollutant swapping. Under these circumstances, trapped material may undergo biogeochemical cycling to change chemical or physical form and thereby become more problematic or mobile within the environment. Thus, constructed agricultural wetlands designed to mitigate against one form of pollution may in fact offset the created benefits by 'swapping' this pollution into other forms and pathways, such as through release to the atmosphere. Pollutant swapping to the atmosphere has been noted in analogous wetland systems designed to treat municipal and industrial wastewaters, with significant fluxes of CO2, CH4 and N2O being recorded in some cases. However the small size, low level of engineering and variable nutrient/sediment inputs which are features of constructed agricultural wetlands, means that this knowledge is not directly transferable. Therefore, more information is required when assessing whether a wetland's potential to act as hotspot for pollution swapping outweighs its potential to act as a mitigation tool for surface water pollution. Here we present results from an on-going monitoring study at a trial agricultural wetland located in small a mixed-use catchment in Cumbria, UK. Estimates were made of CH4, CO2 and N2O flux from the wetland surface using adapted floating static chambers, which were then directly compared with fluxes from an undisturbed riparian zone. Results indicate that while greenhouse gas flux from the wetland may be

  13. RISK ASSESSMENT FOR TOXIC AIR POLLUTANTS: A CITIZEN'S GUIDE

    EPA Science Inventory

    Toxic air pollutants are poisonous substances in the air that come from natural sources (for example, radon gas coming up from the ground) or from manmade sources (for example, chemical compounds given off by factory smokestacks) and can harm the environment or your health. Inhal...

  14. LAKE ONTARIO BASIN POLLUTANT REDUCTION PROJECT - AIR DEPOSITION MONITORING

    EPA Science Inventory

    The Lake Ontario LaMP identified six critical pollutants for the lake: PCBs, DDT, mirex, dieldrin, mercury and dioxins. In order to gain a better understanding of the movement of toxic chemicals through the Lake Ontario ecosystem, EPA Region 2, in coordination with the other LaMP...

  15. Models of Fate and Transport of Pollutants in Surface Waters

    ERIC Educational Resources Information Center

    Okome, Gloria Eloho

    2013-01-01

    There is the need to answer very crucial questions of "what happens to pollutants in surface waters?" This question must be answered to determine the factors controlling fate and transport of chemicals and their evolutionary state in surface waters. Monitoring and experimental methods are used in establishing the environmental states.…

  16. METHODOLOGY FOR COLLECTING AND ANALYZING ORGANIC AIR POLLUTANTS

    EPA Science Inventory

    A number of support-bonded liquid phase sorption media were developed and evaluated in model systems for collecting and analyzing organic air pollutants. Polymers with various functional groups were synthesized and chemically bonded onto inert supports in thick layers. A media co...

  17. The Engineered Phytoremediation of Ionic and Methylmercury Pollution

    SciTech Connect

    Richard Meagher; Sarah Marshburn; Andrew Heaton; Anne Marie Zimer; Raoufa Rahman

    2003-06-24

    Our current specific objectives are to use transgenic plants to control the chemical species, electrochemical state, and above ground binding of mercury to (a) prevent methylmercury from entering the food-chain, (b) remove mercury from polluted sites, and (c) hyperaccumulate mercury in above ground tissues for later harvest.

  18. Historic and newer persistent organic pollutants in food

    Technology Transfer Automated Retrieval System (TEKTRAN)

    This book chapter reviews the literature published over the past five years with regard to the concentrations of historic and newly-listed persistent organic pollutants (POPs) in foods. The chemical classes selected for this review include historic POPs (dioxins, polychlorinated biphenyls, and DDT) ...

  19. Retrofit conserves energy at a water pollution control facility

    SciTech Connect

    Haimes, A.S.; Dedyo, J.

    1980-01-01

    A major retrofit of process structures and incorporation of additional mechanical equipment was undertaken to replace the existing chemical phosphorus removal process with a biological phosphorus removal process. The new process will reduce energy use up to 81% and lime use up to 86% at the Amherst, New York water pollution control facility.

  20. CAPILLARY ELECTROPHORESIS FOR ENANTIOMER SEPARATION AND MEASUREMENT OF ENANTIOSELECTIVITY OF CHIRAL POLLUTANTS IN THE ENVIRONMENT

    EPA Science Inventory

    Chiral pollutants exist as 2 species, -- enantiomers - that have identical physical and chemical properties except when they interact with enzymes or other chiral molecules; then they usually react selectively. This enantioselectivity results in different rates of microbial trans...