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Sample records for erbium implanted lithium

  1. Erbium ion implantation into different crystallographic cuts of lithium niobate

    NASA Astrophysics Data System (ADS)

    Nekvindova, P.; Svecova, B.; Cajzl, J.; Mackova, A.; Malinsky, P.; Oswald, J.; Kolistsch, A.; Spirkova, J.

    2012-02-01

    Single crystals like lithium niobate are frequently doped with optically active rare-earth or transition-metal ions for a variety of applications in optical devices such as solid-state lasers, amplifiers or sensors. To exploit the potential of the Er:LiNbO 3, one must ensure high intensity of the 1.5 μm luminescence as an inevitable prerequisite. One of the important factors influencing the luminescence properties of a lasing ion is the crystal field of the surrounding, which is inevitably determined by the crystal structure of the pertinent material. From that point it is clear that it cannot be easy to affect the resulting luminescence properties - intensity or position of the luminescence band - without changing the structure of the substrate. However, there is a possibility to utilise a potential of the ion implantation of the lasing ions, optionally accompanied with a sensitising one, that can, besides the doping, also modify the structure of the treated area od the crystal. This effect can be eventually enhanced by a post-implantation annealing that may help to recover the damaged structure and hence to improve the desired luminescence. In this paper we are going to report on our experiments with ion-implantation technique followed with subsequent annealing could be a useful way to influence the crystal field of LN. Optically active Er:LiNbO 3 layers were fabricated by medium energy implantation under various experimental conditions. The Er + ions were implanted at energies of 330 and 500 keV with fluences ranging from 1.0 × 10 15 to 1.0 × 10 16 ion cm -2 into LiNbO 3 single-crystal cuts of both common and special orientations. The as-implanted samples were annealed in air and oxygen at two different temperatures (350 and 600 °C) for 5 h. The depth concentration profiles of the implanted erbium were measured by Rutherford Backscattering Spectroscopy (RBS) using 2 MeV He + ions. The photoluminescence spectra of the samples were measured to determine the

  2. Hybrid quantum circuit with implanted erbium ions

    SciTech Connect

    Probst, S.; Rotzinger, H.; Tkalčec, A.; Kukharchyk, N.; Wieck, A. D.; Wünsch, S.; Siegel, M.; Ustinov, A. V.; Bushev, P. A.

    2014-10-20

    We report on hybrid circuit quantum electrodynamics experiments with focused ion beam implanted Er{sup 3+} ions in Y{sub 2}SiO{sub 5} coupled to an array of superconducting lumped element microwave resonators. The Y{sub 2}SiO{sub 5} crystal is divided into several areas with distinct erbium doping concentrations, each coupled to a separate resonator. The coupling strength is varied from 5 MHz to 18.7 MHz, while the linewidth ranges between 50 MHz and 130 MHz. We confirm the paramagnetic properties of the implanted spin ensemble by evaluating the temperature dependence of the coupling. The efficiency of the implantation process is analyzed and the results are compared to a bulk doped Er:Y{sub 2}SiO{sub 5} sample. We demonstrate the integration of these engineered erbium spin ensembles with superconducting circuits.

  3. Er + medium energy ion implantation into lithium niobate

    NASA Astrophysics Data System (ADS)

    Svecova, B.; Nekvindova, P.; Mackova, A.; Oswald, J.; Vacik, J.; Grötzschel, R.; Spirkova, J.

    2009-05-01

    Erbium-doped lithium niobate (Er:LiNbO3) is a prospective photonics component, operating at 1.5 μm, which could find its use chiefly as an optical amplifier or waveguide laser. In this study, we have focused on the properties of the optically active Er:LiNbO3 layers, which are fabricated by medium energy ion implantation under various experimental conditions. Erbium ions were implanted at energies of 330 and 500 keV with fluences of 1.0 × 1015, 2.5 × 1015 and 1.0 × 1016 cm-2 into LiNbO3 single-crystalline cuts of various orientations. The as-implanted samples were annealed in air at 350 °C for 5 h. The depth distribution and diffusion profiles of the implanted Er were measured by Rutherford Backscattering Spectroscopy (RBS) using 2 MeV He+ ions. The projected range RP and projected range straggling ΔRP were calculated employing the SRIM code. The damage distribution and structural changes were described using the RBS/channelling method. Changes of the lithium concentration depth distribution were studied by Neutron Depth Profiling (NDP). The photoluminescence spectra of the samples were measured to determine whether the emission was in the desired region of 1.5 μm. The obtained data made it possible to reveal the relations between the structural changes of erbium-implanted lithium niobate and its luminescence properties important for photonics applications.

  4. Nanoscale nonlinear effects in Erbium-implanted Yttrium Orthosilicate

    NASA Astrophysics Data System (ADS)

    Kukharchyk, Nadezhda; Shvarkov, Stepan; Probst, Sebastian; Xia, Kangwei; Becker, Hans-Werner; Pal, Shovon; Markmann, Sergej; Kolesov, Roman; Siyushev, Petr; Wrachtrup, Jörg; Ludwig, Arne; Ustinov, Alexey V.; Wieck, Andreas D.; Bushev, Pavel

    2016-09-01

    Doping of substrates at desired locations is a key technology for spin-based quantum memory devices. Focused ion beam implantation is well-suited for this task due to its high spacial resolution. In this work, we investigate ion-beam implanted erbium ensembles in Yttrium Orthosilicate crystals by means of confocal photoluminescence spectroscopy. The sample temperature and the post-implantation annealing step strongly reverberate in the properties of the implanted ions. We find that hot implantation leads to a higher activation rate of the ions. At high enough fluences, the relation between the fluence and final concentration of ions becomes non-linear. Two models are developed explaining the observed behaviour.

  5. Erbium Implantation in Silica Studied by Molecular Dynamics Simulations

    SciTech Connect

    Du, Jincheng; Corrales, Louis R.

    2007-02-01

    Defect formation induced by erbium implantation in silica glass and cristobalite was studied using molecular dynamics simulations employing a partial charge model in combination with the ZBL potential. The results show that the number of displaced atoms generated at the same PKA energy is similar in silica and cristobalite but the number of coordination defects created is much lower in the cristobalite than in silica glass. In both cases, the erbium ion is able to create an optimal coordination environment at the end of the collision cascade. Subsequent thermal annealing causes the relaxation of the silicon oxygen network structure along with a reduction of silicon and oxygen defects. This research is supported by the Divisions of Materials Sciences and Engineering and Chemical Science, Office of Basic Energy Sciences, U.S. Department of Energy. The Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

  6. Erbium doping of lithium niobate by the ion exchange process for high-gain optical amplifiers

    NASA Astrophysics Data System (ADS)

    Caccavale, Frederico; Fedorov, Vyacheslav A.; Korkishko, Yuri N.; Morozova, Tamara V.; Sada, Cinzia; Segato, Francesco

    2000-04-01

    The erbium-lithium ion exchange is presented as a method for the erbium local doping of lithium niobate crystals. Ion exchange process is performed immersing the LiNbO3 substrates in a liquid melt, containing erbium ions; due to their high mobility, the lithium ions migrate from the crystal to the melt, and are replaced by erbium ions. A systematic analysis of the doping process is performed, and the influence of the process parameters is investigated: exchange time and temperature, crystal cut direction, composition and chemical reactivity of the Er ions liquid source. By structural (X-Ray Diffraction and Rutherford Backscattering Spectrometry), compositional (Secondary Ion Mass Spectrometry) and spectroscopic techniques (optical spectroscopy and micro-luminescence), the formation of lithium deficient phases and the incorporation of the Er ions into the LiNbO3 matrix is studied.

  7. Erbium localized doping into various cuts of lithium niobate and sapphire: a comparative study

    NASA Astrophysics Data System (ADS)

    Nekvindova, Pavla; Mackova, Anna; Perina, Vratislav; Cervena, Jarmila; Capek, Pavel; Schroefel, Josef; Spirkova, Jarmila; Oswald, Jiri

    2003-07-01

    Medium temperature (350 °C) localized doping of Er3+ was studied in lithium niobate (LN) and sapphire single crystal wafers that were cut in various crystallographic directions. It was found that the efficiency of the doping was connected with orientations of the substrate wafers of both LN and sapphire, and with the presence of mobile lithium ions in the structure of LN. The basic interstitial mechanism of erbium incorporation into the structure of sapphire and LN is in the latter accompanied with erbium for lithium ion exchange. While the rate of the interstitial diffusion was higher in the wafers oriented perpendicularly towards the cleavage planes of the crystals, ion exchange process was significant in the wafers cut in cleavage planes. Waveguiding properties in erbium doped lithium niobate originated rather from presence of erbium in the structure of the crystals than being a consequence of a weak proton exchange. Luminescence properties of the fabricated samples are also presented.

  8. Ion implantation of erbium into polycrystalline cadmium telluride

    SciTech Connect

    Ushakov, V. V. Klevkov, Yu. V.; Dravin, V. A.

    2015-05-15

    The specific features of the ion implantation of polycrystalline cadmium telluride with grains 20–1000 μm in dimensions are studied. The choice of erbium is motivated by the possibility of using rare-earth elements as luminescent “probes” in studies of the defect and impurity composition of materials and modification of the composition by various technological treatments. From the microphotoluminescence data, it is found that, with decreasing crystal-grain dimensions, the degree of radiation stability of the material is increased. Microphotoluminescence topography of the samples shows the efficiency of the rare-earth probe in detecting regions with higher impurity and defect concentrations, including regions of intergrain boundaries.

  9. Erbium-ion implantation into various crystallographic cuts of Al2O3

    NASA Astrophysics Data System (ADS)

    Nekvindova, P.; Mackova, A.; Malinsky, P.; Cajzl, J.; Svecova, B.; Oswald, J.; Wilhelm, R. A.

    2015-12-01

    This paper reports on the importance of crystallographic cuts with a different orientation on the luminescent properties and structural changes of Al2O3 implanted with Er+ ions at 190 keV and with a fluence of 1.0 × 1016 cm-2. Post-implantation annealing at 1000 °C in oxygen atmosphere was also done. The chemical compositions and erbium concentration-depth profiles of implanted layers were studied by Rutherford Backscattering Spectrometry (RBS) and compared to SRIM simulations. The same value of the maximum erbium concentration (up to 2 at.%) was observed at a depth of about 40 nm for all crystallographic cuts. The structural properties of the prepared layers were characterised by RBS/channelling. The relative amount of disordered atoms of 70-80% was observed in the prepared implanted layers and discussed for various cuts. It has been found that erbium is positioned randomly in the Al2O3 crystalline matrix, and no preferential positions appeared even after the annealing procedure. Erbium luminescence properties were measured in the wavelength range of 1440-1650 nm for all samples. As-implanted Al2O3 samples had a significant luminescence band at 1530 nm. The best luminescence was repeatedly observed in the <0 0 0 1> cut of Al2O3. The annealing procedure significantly improved the luminescent properties.

  10. Photoluminescence in silicon implanted with erbium ions at an elevated temperature

    SciTech Connect

    Sobolev, N. A. Kalyadin, A. E.; Shek, E. I.; Sakharov, V. I.; Serenkov, I. T.; Vdovin, V. I.; Parshin, E. O.; Makoviichuk, M. I.

    2011-08-15

    Photoluminescence spectra of n-type silicon upon implantation with erbium ions at 600 Degree-Sign C and oxygen ions at room temperature and subsequent annealings at 1100 Degree-Sign C in a chlorine-containing atmosphere have been studied. Depending on the annealing duration, photoluminescence spectra at 80 K are dominated by lines of the Er{sup 3+} ion or dislocation-related luminescence. The short-wavelength shift of the dislocation-related luminescence line observed at this temperature is due to implantation of erbium ions at an elevated temperature. At room temperature, lines of erbium and dislocation-related luminescence are observed in the spectra, but lines of near-band-edge luminescence predominate.

  11. Evaluation of the Removal Bacteria on Failed Titanium Implants After Irradiation With Erbium-Doped Yttrium Aluminium Garnet Laser.

    PubMed

    Scarano, Antonio; Nardi, Gianna; Murmura, Giovanna; Rapani, Manuela; Mortellaro, Carmen

    2016-07-01

    Peri-implantitis may occur because of biologic or mechanical factors. It can be treated by a variety of methods. The aim of the present study is to evaluate implant surface of failed oral titanium implants after being irradiated with erbium laser. PMID:27391491

  12. Silicon shallow doping by erbium and oxygen recoils implantation

    NASA Astrophysics Data System (ADS)

    Feklistov, K. V.; Cherkov, A. G.; Popov, V. P.

    2016-09-01

    In order to get shallow high doping of Si with optically active complexes ErOn, Er followed by O recoils implantation was realized by means of subsequent Ar+ 250-290 keV implantation with doses 2×1015-1×1016 cm-2 through 50-nm deposited films of Er and then SiO2, accordingly. High Er concentration up to 5×1020 cm-3 to the depth of 10 nm was obtained after implantation. However, about a half of the Er implanted atoms become part of surface SiO2 during post-implantation annealing at 950 °C for 1 h in the N2 ambient under a SiO2 cap. The mechanism of Er segregation into the cap oxide following the moving amorphous-crystalline interface during recrystallization was rejected by the transmission electron microscopy (TEM) analysis. Instead, the other mechanism of immobile Er atoms and redistribution of recoil-implanted O atoms toward cap oxide was proposed. It explains the observed formation of two Er containing phases: Er-Si-O phase with a high O content adjacent to the cap oxide and deeper O depleted Er-Si phase. The correction of heat treatments is proposed in order to avoid the above-mentioned problems.

  13. Temperature dependences of the photoluminescence intensities of centers in silicon implanted with erbium and oxygen ions

    SciTech Connect

    Sobolev, N. A. Shtel’makh, K. F.; Kalyadin, A. E.; Shek, E. I.

    2015-12-15

    Low-temperature photoluminescence in n-Cz-Si after the implantation of erbium ions at an elevated temperature and subsequent implantation of oxygen ions at room temperature is studied. So-called X and W centers formed from self-interstitial silicon atoms, H and P centers containing oxygen atoms, and Er centers containing Er{sup 3+} ions are observed in the photoluminescence spectra. The energies of enhancing and quenching of photoluminescence for these centers are determined. These energies are determined for the first time for X and H centers. In the case of P and Er centers, the values of the energies practically coincide with previously published data. For W centers, the energies of the enhancing and quenching of photoluminescence depend on the conditions of the formation of these centers.

  14. Surface microhardening in a lithium implanted aluminium alloy

    SciTech Connect

    Singh, A.; Fiset, M.; Knystautas, E.J.; Lapointe, R.

    1984-09-01

    This paper describes changes observed in microhardness after implanting energetic lithium ions into pure aluminum and its 2024-T351 alloy. The addition of lithium to aluminum lowers the density and increases both the modulus of elasticity and tensile strength. Thus, these properties make such alloys attractive in aerospace applications. The authors believe that this is the first report where lithium implantation has been used to evaluate near surface changes.

  15. Physical properties of erbium implanted tungsten oxide filmsdeposited by reactive dual magnetron sputtering

    SciTech Connect

    Mohamed, Sodky H.; Anders, Andre

    2006-11-08

    Amorphous and partially crystalline WO3 thin films wereprepared by reactive dual magnetron sputtering and successively implantedby erbium ions with a fluence in the range from 7.7 x 1014 to 5 x 1015ions/cm2. The electrical and optical properties were studied as afunction of the film deposition parameters and the ion fluence. Ionimplantation caused a strong decrease of the resistivity, a moderatedecrease of the index of refraction and a moderate increase of theextinction coefficient in the visible and near infrared, while theoptical band gap remained almost unchanged. These effects could belargely ascribed to ion-induced oxygen deficiency. When annealed in air,the already low resistivities of the implanted samples decreased furtherup to 70oC, whereas oxidation, and hence a strong increase of theresistivity, was observed at higher annealing temperatures.

  16. Optical switching and photoluminescence in erbium-implanted vanadium dioxide thin films

    SciTech Connect

    Lim, Herianto Stavrias, Nikolas; Johnson, Brett C.; McCallum, Jeffrey C.; Marvel, Robert E.; Haglund, Richard F.

    2014-03-07

    Vanadium dioxide (VO{sub 2}) is under intensive consideration for optical switching due to its reversible phase transition, which features a drastic and rapid shift in infrared reflectivity. Classified as an insulator–to–metal transition, the phase transition in VO{sub 2} can be induced thermally, electrically, and optically. When induced optically, the transition can occur on sub-picosecond time scales. It is interesting to dope VO{sub 2} with erbium ions (Er{sup 3+}) and observe their combined properties. The first excited-state luminescence of Er{sup 3+} lies within the wavelength window of minimal transmission-loss in silicon and has been widely utilized for signal amplification and generation in silicon photonics. The incorporation of Er{sup 3+} into VO{sub 2} could therefore result in a novel photonic material capable of simultaneous optical switching and amplification. In this work, we investigate the optical switching and photoluminescence in Er-implanted VO{sub 2} thin films. Thermally driven optical switching is demonstrated in the Er-implanted VO{sub 2} by infrared reflectometry. Photoluminescence is observed in the thin films annealed at ∼800 °C or above. In addition, Raman spectroscopy and a statistical analysis of switching hysteresis are carried out to assess the effects of the ion implantation on the VO{sub 2} thin films. We conclude that Er-implanted VO{sub 2} can function as an optical switch and amplifier, but with reduced switching quality compared to pure VO{sub 2}.

  17. Growth, characterization and upconversion properties of erbium-doped potassium lithium tantalate niobate single crystals under 975 nm laser excitation

    NASA Astrophysics Data System (ADS)

    Zhou, Zhongxiang; Li, Lei; Duan, Qianqian; Feng, Lei; Tian, Hao

    2012-04-01

    Potassium lithium tantalate niobate single crystals doped with erbium ions are grown by top-seeded solution growth method. The crystals are characterized by X-ray diffraction and differential thermal analysis. The refractive indices of the crystal are measured using ellipsometry method and fitted by Sellmeier equation. The as-grown crystals are tetragonal phase tungsten bronze-type structure with Curie temperature of 271.3 °C. Characteristic Er3 + absorption bands are observed from 350 to 1100 nm in ultraviolet-visible-near infrared absorption spectra. These crystals emit brightly green and red upconversion fluorescence under 975 nm LD laser excitation, and the steady state upconversion spectra are obtained at room temperature. The red emission intensity increases as the erbium ions concentration increases in crystals. Processes of excited state absorption and energy transfer are responsible for upconversion luminescence. The emission intensities are quadratic dependences on pump power from pump power dependence analyses and deduction of transition rate equation model.

  18. 1.54 micron Emission from Erbium implanted GaN for Photonic Applications

    NASA Technical Reports Server (NTRS)

    Thaik, Myo; Hommerich, U.; Schwartz, R. N.; Wilson, R. G.; Zavada, J. M.

    1998-01-01

    The development of efficient and compact light sources operating at 1.54 micron is of enormous importance for the advancement of new optical communication systems. Erbium (1%) doped fiber amplifiers (EDFA's) or semiconductor lasers are currently being employed as near infrared light sources. Both devices, however, have inherent limitations due to their mode of operation. EDFA's employ an elaborate optical pumping scheme, whereas diode lasers have a strongly temperature dependent lasing wavelength. Novel light emitters based on erbium doped III-V semiconductors could overcome these limitations. Er doped semiconductors combine the convenience of electrical excitation with the excellent luminescence properties of Er(3+) ions. Electrically pumped, compact, and temperature stable optoelectronic devices are envisioned from this new class of luminescent materials. In this paper we discuss the potential of Er doped GaN for optoelectronic applications based on temperature dependent photoluminescence excitation studies.

  19. Self-quenching of luminescence in concentrated lithium--erbium and lithium--holmium double fluoride crystals

    SciTech Connect

    Tkachuk, A.M.; Klokishner, S.I.; Petrov, M.V.

    1985-10-01

    For the radiative terms of holmium and erbium ions in concentrated LiErF/sub 4/ and LiHoF/sub 4/ crystals, numerical estimates were made of the microparameters and transfer rates on the basis of known experimental data on the structure of luminescence centers, probabilities of intracenter transitions, phonon spectrum of the crystals, and electron--phonon interaction. The schemes of the most important processes of cross-relaxation quenching and nonlinear (in excitation intensity) interaction have been determined. On the basis of an analysis of numerical values of the rates of intracenter relaxation and interionic transfer of energy, conclusions are reached concerning the processes which significantly affect the radiative characteristics of concentrated crystals. The role of the processes of cross-relaxation quenching and nonlinear interaction in the formation of an inverse population of excited multiplets and the influences of these processes on the characteristics of stimulated emission are discussed.

  20. Effect of erbium-doped: yttrium, aluminium and garnet laser irradiation on the surface microstructure and roughness of sand-blasted, large grit, acid-etched implants

    PubMed Central

    Lee, Ji-Hun; Kwon, Young-Hyuk; Herr, Yeek; Shin, Seung-Il

    2011-01-01

    Purpose The present study was performed to evaluate the effect of erbium-doped: yttrium, aluminium and garnet (Er:YAG) laser irradiation on sand-blasted, large grit, acid-etched (SLA) implant surface microstructure according to varying energy levels and application times of the laser. Methods The implant surface was irradiated by the Er:YAG laser under combined conditions of 100, 140, or 180 mJ/pulse and an application time of 1 minute, 1.5 minutes, or 2 minutes. Scanning electron microscopy (SEM) was used to examine the surface roughness of the specimens. Results All experimental conditions of Er:YAG laser irradiation, except the power setting of 100 mJ/pulse for 1 minute and 1.5 minutes, led to an alteration in the implant surface. SEM evaluation showed a decrease in the surface roughness of the implants. However, the difference was not statistically significant. Alterations of implant surfaces included meltdown and flattening. More extensive alterations were present with increasing laser energy and application time. Conclusions To ensure no damage to their surfaces, it is recommended that SLA implants be irradiated with an Er:YAG laser below 100 mJ/pulse and 1.5 minutes for detoxifying the implant surfaces. PMID:21811689

  1. Lithium Nitride Synthesized by in situ Lithium Deposition and Ion Implantation for Boron Neutron Capture Therapy

    NASA Astrophysics Data System (ADS)

    Ishitama, Shintaro; Baba, Yuji; Fujii, Ryo; Nakamura, Masaru; Imahori, Yoshio

    Li3N synthesis on Li deposition layer was conducted without H2O and O2 by in situ lithium deposition in high vacuum chamber of 10-6 Pa and ion implantation techniques and the thermo-chemical stability of the Li3N/Li/Cu tri-layered target for Boron Neutron Capture Therapy (BNCT) under laser heating and air exposure was characterized by X-ray photoelectron spectroscopy (XPS). Following conclusions were derived; (1) Li3N/Li/Cu tri-layered target with very low oxide and carbon contamination was synthesized by in situ lithium vacuum deposition and N2+ ion implantation without H2O and O2 additions, (2) The starting temperature of evaporation of Li3N/Li/Cu tri-layered target increased by 120K compared to that of the Li/Cu target and (3) Remarkable oxidation and carbon contamination were observed on the surface of Li3N/Li/Cu after air exposure and these contaminated compositions was not removed by Ar+ heavy sputtering.

  2. Synthesis of lithium nitride for neutron production target of BNCT by in situ lithium deposition and ion implantation

    NASA Astrophysics Data System (ADS)

    Ishiyama, S.; Baba, Y.; Fujii, R.; Nakamura, M.; Imahori, Y.

    2012-12-01

    To achieve high performance of BNCT (Boron Neutron Capture Therapy) device, Li3N/Li/Pd/Cu four layered Li target was designed and the structures of the synthesized four layered target were characterized by X-ray photoelectron spectroscopy. For the purpose of avoiding the radiation blistering and lithium evaporation, in situ vacuum deposition and nitridation techniques were established for in situ production and repairing maintenance of the lithium target. Following conclusions were derived: Uniform lithium layer of a few hundreds nanometer was formed on Pd/Cu multilayer surface by in situ vacuum deposition technique using metallic lithium as a source material. Lithium nitrides were formed by in situ nitridation reaction by the implantation of low-energy nitrogen ions on the deposited lithium layer surface. The chemical states of the nitridated zone were close to the stoichiometric lithium nitride, Li3N. This nitridated zone formed on surface of four layered lithium target is stable for a long time in air condition. The in situ nitridation is effective to protect lithium target from degradation by unfavorable reactions.

  3. Target dependent femtosecond laser plasma implantation dynamics in enabling silica for high density erbium doping.

    PubMed

    Chandrappan, Jayakrishnan; Murray, Matthew; Kakkar, Tarun; Petrik, Peter; Agocs, Emil; Zolnai, Zsolt; Steenson, D P; Jha, Animesh; Jose, Gin

    2015-01-01

    Chemical dissimilarity of tellurium oxide with silica glass increases phase separation and crystallization tendency when mixed and melted for making a glass. We report a novel technique for incorporating an Er(3+)-doped tellurite glass composition into silica substrates through a femtosecond (fs) laser generated plasma assisted process. The engineered material consequently exhibits the spectroscopic properties of Er(3+)-ions, which are unachievable in pure silica and implies this as an ideal material for integrated photonics platforms. Formation of a well-defined metastable and homogeneous glass structure with Er(3+)-ions in a silica network, modified with tellurite has been characterized using high-resolution cross-sectional transmission electron microscopy (HRTEM). The chemical and structural analyses using HRTEM, Rutherford backscattering spectrometry (RBS) and laser excitation techniques, confirm that such fs-laser plasma implanted glasses may be engineered for significantly higher concentration of Er(3+)-ions without clustering, validated by the record high lifetime-density product 0.96 × 10(19) s.cm(-3). Characterization of planar optical layers and photoluminescence emission spectra were undertaken to determine their thickness, refractive indices and photoluminescence properties, as a function of Er(3+) concentration via different target glasses. The increased Er(3+) content in the target glass enhance the refractive index and photoluminescence intensity of the modified silica layer whilst the lifetime and thickness decrease. PMID:26370060

  4. Target dependent femtosecond laser plasma implantation dynamics in enabling silica for high density erbium doping

    PubMed Central

    Chandrappan, Jayakrishnan; Murray, Matthew; Kakkar, Tarun; Petrik, Peter; Agocs, Emil; Zolnai, Zsolt; Steenson, D.P.; Jha, Animesh; Jose, Gin

    2015-01-01

    Chemical dissimilarity of tellurium oxide with silica glass increases phase separation and crystallization tendency when mixed and melted for making a glass. We report a novel technique for incorporating an Er3+-doped tellurite glass composition into silica substrates through a femtosecond (fs) laser generated plasma assisted process. The engineered material consequently exhibits the spectroscopic properties of Er3+-ions, which are unachievable in pure silica and implies this as an ideal material for integrated photonics platforms. Formation of a well-defined metastable and homogeneous glass structure with Er3+-ions in a silica network, modified with tellurite has been characterized using high-resolution cross-sectional transmission electron microscopy (HRTEM). The chemical and structural analyses using HRTEM, Rutherford backscattering spectrometry (RBS) and laser excitation techniques, confirm that such fs-laser plasma implanted glasses may be engineered for significantly higher concentration of Er3+-ions without clustering, validated by the record high lifetime-density product 0.96 × 1019 s.cm−3. Characterization of planar optical layers and photoluminescence emission spectra were undertaken to determine their thickness, refractive indices and photoluminescence properties, as a function of Er3+ concentration via different target glasses. The increased Er3+ content in the target glass enhance the refractive index and photoluminescence intensity of the modified silica layer whilst the lifetime and thickness decrease. PMID:26370060

  5. Target dependent femtosecond laser plasma implantation dynamics in enabling silica for high density erbium doping

    NASA Astrophysics Data System (ADS)

    Chandrappan, Jayakrishnan; Murray, Matthew; Kakkar, Tarun; Petrik, Peter; Agocs, Emil; Zolnai, Zsolt; Steenson, D. P.; Jha, Animesh; Jose, Gin

    2015-09-01

    Chemical dissimilarity of tellurium oxide with silica glass increases phase separation and crystallization tendency when mixed and melted for making a glass. We report a novel technique for incorporating an Er3+-doped tellurite glass composition into silica substrates through a femtosecond (fs) laser generated plasma assisted process. The engineered material consequently exhibits the spectroscopic properties of Er3+-ions, which are unachievable in pure silica and implies this as an ideal material for integrated photonics platforms. Formation of a well-defined metastable and homogeneous glass structure with Er3+-ions in a silica network, modified with tellurite has been characterized using high-resolution cross-sectional transmission electron microscopy (HRTEM). The chemical and structural analyses using HRTEM, Rutherford backscattering spectrometry (RBS) and laser excitation techniques, confirm that such fs-laser plasma implanted glasses may be engineered for significantly higher concentration of Er3+-ions without clustering, validated by the record high lifetime-density product 0.96 × 1019 s.cm-3. Characterization of planar optical layers and photoluminescence emission spectra were undertaken to determine their thickness, refractive indices and photoluminescence properties, as a function of Er3+ concentration via different target glasses. The increased Er3+ content in the target glass enhance the refractive index and photoluminescence intensity of the modified silica layer whilst the lifetime and thickness decrease.

  6. Depth profiles of MeV heavy ions implanted into Si and lithium triborate

    NASA Astrophysics Data System (ADS)

    Wang, Ke-Ming; Shi, Bo-Rong; Cue, Nelson; Shen, Ding-Yu; Chen, Feng; Wang, Xue-Lin; Lu, Fei

    2004-10-01

    MeV Cu + and Ni + ions were implanted into Si crystal and lithium triborate. The depth profiles of implanted Cu + and Ni + ions into Si and lithium triborate were measured by secondary ion mass spectrometry (SIMS). Mean projected range and range straggling extracted are compared with calculated values based on different versions of transport of ions in matter: TRIM'90, TRIM'98 and SRIM 2003. The results show that TRIM'90 has predicted well the experimental data of mean projected range and range straggling for MeV Cu + ions implanted into Si, the maximum differences between measured and calculated values are within 4%, but for the case of 2.0 MeV Ni + ions implanted into lithium triborate, the experimental value is significantly different from the calculated one based on TRIM'90.

  7. SOLITONS: Dark photovoltaic spatial solitons in a planar waveguide obtained by proton implantation in lithium niobate

    NASA Astrophysics Data System (ADS)

    Kruglov, V. G.; Shandarov, V. M.; Tan, Ya; Chen, F.; Kip, D.

    2008-11-01

    A photovoltaic dark spatial soliton is generated in a planar waveguide produced by the implantation of protons into a copper-doped lithium niobate crystal. Stationary soliton regimes are achieved at powers 90 and 30 μW at wavelengths 633 and 532 nm, respectively.

  8. The structural changes and optical properties of LiNbO3 after Er implantation using high ion fluencies

    NASA Astrophysics Data System (ADS)

    Macková, A.; Malinský, P.; Pupíková, H.; Nekvindová, P.; Cajzl, J.; Sofer, Z.; Wilhelm, R. A.; Kolitsch, A.; Oswald, J.

    2014-08-01

    The structural and compositional changes of LiNbO3 implanted with 190 keV Er+ ions into various crystallographic cuts with fluencies of 1 × 1016 and 5 × 1016 cm-2 were studied. The effect of post-implantation annealing at 1000 °C in oxygen atmosphere was also examined. Concentration depth profiles of implanted erbium, determined by Rutherford Backscattering Spectrometry (RBS), are broader than those from the SRIM simulation. The maximum erbium concentration (of up to 8 at.%) is observed at the depth of about 50 nm, for all crystal cuts. The structure of the implanted layers were characterised by RBS-channelling method. The lower relative number of disordered atoms in the crystalline matrix was observed in the lithium niobate (LN) implanted at a fluence of 1 × 1016 cm-2, where also the preferential position of the erbium in substitutional sites was observed when compared to the randomly distributed erbium in interstitial positions at a fluence of 5 × 1016 cm-2 after the annealing. Surface-morphology changes at the highest implantation fluencies were studied using Atomic Force Microscopy (AFM). Since we were interested in the relation between the structural changes and optical properties, erbium luminescence properties were measured in the region of 1440-1650 nm. The positive effect of post-implantation annealing on the luminescence properties caused by structural recovery was proved.

  9. Utilizing dynamic annealing during ion implantation: synthesis of silver nanoparticles in crystalline lithium niobate.

    PubMed

    Wolf, Steffen; Rensberg, Jura; Stöcker, Hartmut; Abendroth, Barbara; Wesch, Werner; Ronning, Carsten

    2014-04-01

    Silver nanoparticles (NPs) embedded in lithium niobate were fabricated via ion beam synthesis and are suitable for various plasmonic applications, e.g. enhancement of optical nonlinear effects. After room temperature silver implantation, annealing in the temperature range of 400-600 °C was performed in order to recrystallize the damaged lithium niobate surface layer. The shape of the silver NPs, their optical properties as well as the structural properties of their surrounding matrix have been analyzed for various annealing steps. TEM investigations show that annealing at 400 °C does not lead to recrystallization of the damaged lithium niobate. A recrystallization occurs upon increasing the annealing temperature to 500 or 600 °C, but simultaneously a second phase consisting of lithium triniobate forms. This is additionally supported by XRD measurements. By utilizing dynamic annealing, i.e. implanting silver at elevated temperatures of 400 °C, it is shown that the LiNbO3 matrix stays single crystalline during ion implantation and no LiNb3O8 is formed. This is additionally verified by comparing the positions of the surface plasmon resonances with calculations based on Mie's scattering theory. PMID:24598310

  10. Adhesive bone bonding prospects for lithium disilicate ceramic implants

    NASA Astrophysics Data System (ADS)

    Vennila Thirugnanam, Sakthi Kumar

    Temporomandibular Joint (TMJ) implants articulating mandible with temporal bone in humans have a very high failure rate. Metallic TMJ implants available in the medical market are not osseointegrated, but bond only by mechanical interlocking using screws which may fail, mandating a second surgery for removal. Stress concentration around fixture screws leads to aseptic loosening or fracture of the bone. It has been proposed that this problem can be overcome by using an all-ceramic TMJ implant bonded to bone with dental adhesives. Structural ceramics are promising materials with an excellent track record in the field of dentis.

  11. Simulation of damage induced by ion implantation in Lithium Niobate

    NASA Astrophysics Data System (ADS)

    Bianconi, M.; Bentini, G. G.; Chiarini, M.; De Nicola, P.; Montanari, G. B.; Menin, A.; Nubile, A.; Sugliani, S.

    2010-11-01

    A simulation tool has been developed to engineer the damage formation in Lithium Niobate by ion irradiation with any atomic number and energy. Both nuclear and electronic processes were considered and, in particular, the dependence on the ion velocity of the electronic excitation damage efficiency has been taken into account. By using this tool it is possible both to draw damage nomograms, useful to qualitatively foresee the result of a given process, and to perform reliable simulations of the defect depth profiles, as demonstrated by the good agreement with the experimental data available in the literature.

  12. Thin-film rechargeable lithium batteries for implantable devices

    SciTech Connect

    Bates, J.b.; Dudney, N.J.

    1997-05-01

    Thin films of LiCoO{sub 2} have been synthesized in which the strongest x-ray reflection is either weak or missing, indicating a high degree of preferred orientation. Thin-film solid state batteries with these textured cathode films can deliver practical capacities at high current densities. For example, for one of the cells 70% of the maximum capacity between 4.2 V and 3 V ({approximately}0.2 mAh/cm{sup 2}) was delivered at a current of 2 mA/cm{sup 2}. When cycled at rates of 0.1 mA/cm{sup 2}, the capacity loss was 0.001 %/cycle or less. The reliability and performance of Li-LiCoO{sub 2} thin-film batteries make them attractive for application in implantable devices such as neural stimulators, pacemakers, and defibrillators.

  13. Thin-film Rechargeable Lithium Batteries for Implantable Devices

    DOE R&D Accomplishments Database

    Bates, J. B.; Dudney, N. J.

    1997-05-01

    Thin films of LiCoO{sub 2} have been synthesized in which the strongest x ray reflection is either weak or missing, indicating a high degree of preferred orientation. Thin film solid state batteries with these textured cathode films can deliver practical capacities at high current densities. For example, for one of the cells 70% of the maximum capacity between 4.2 V and 3 V ({approximately}0.2 mAh/cm{sup 2}) was delivered at a current of 2 mA/cm{sup 2}. When cycled at rates of 0.1 mA/cm{sup 2}, the capacity loss was 0.001%/cycle or less. The reliability and performance of Li LiCoO{sub 2} thin film batteries make them attractive for application in implantable devices such as neural stimulators, pacemakers, and defibrillators.

  14. Ion-implantation modification of lithium-phosphorus oxynitride thin-films

    NASA Astrophysics Data System (ADS)

    Kim, Byoungsoo; Cho, Yoon Sang; Lee, Joon-Gon; Joo, Kyong-Hee; Jung, Kwang-Ok; Oh, Jeongmin; Park, Byungwoo; Sohn, Hun-Joon; Kang, Tak; Cho, Jaephil; Park, Young-Shin; Oh, Joo Yeol

    Among various solid electrolytes, the lithium-phosphorus oxynitride (Lipon) electrolyte synthesized by sputtering of Li 3PO 4 in pure N 2 has a good ionic conductivity of 2(±1)×10 -6 S cm -1 at 25° C. As the nitrogen concentration increases in the Lipon electrolyte, the ionic conductivity is reported to increase as a result of a higher degree of cross-links. When Lipon films are deposited by sputtering, however, it is reported that the maximum nitrogen concentration saturates approximately at 6 at.%. By non-equilibrium processes, such as ion-implantation, nitrogen concentration can be controlled over 6 at.%. This study investigates the effect of nitrogen concentration on the ionic conductivity in Lipon films by using ion-implantation. Impedance measurements at 25° C show that the nitrogen-implanted Lipon films enhance or retard the ionic conductivity over a wide range after nitrogen-implantation, when compared with as-deposited thin-films.

  15. Lithium

    USGS Publications Warehouse

    Jaskula, B.W.

    2011-01-01

    In 2010, lithium consumption in the United States was estimated to have been about 1 kt (1,100 st) of contained lithium, a 23-percent decrease from 2009. The United States was estimated to be the fourth largest consumer of lithium. It remained the leading importer of lithium carbonate and the leading producer of value-added lithium materials. Only one company, Chemetall Foote Corp. (a subsidiary of Chemetall GmbH of Germany), produced lithium compounds from domestic resources. In 2010, world lithium consumption was estimated to have been about 21 kt (22,000 st) of lithium contained in minerals and compounds, a 12-percent increase from 2009.

  16. Lithium

    USGS Publications Warehouse

    Jaskula, B.W.

    2010-01-01

    In 2009, lithium consumption in the United States was estimated to have been about 1.2 kt (1,300 st) of contained lithium, a 40-percent decrease from 2008. The United States was estimated to be the fourth largest consumer of lithium, and remained the leading importer of lithium carbonate and the leading producer of value-added lithium materials. Only one company, Chemetall Foote Corp. (a subsidiary of Chemetall GmbH of Germany), produced lithium compounds from domestic resources. In 2009, world lithium consumption was estimated to have been about 18.7 kt (20,600 st) of lithium contained in minerals and compounds.

  17. Lithium

    USGS Publications Warehouse

    Jaskula, B.W.

    2012-01-01

    In 2011, world lithium consumption was estimated to have been about 25 kt (25,000 st) of lithium contained in minerals and compounds, a 10-percent increase from 2010. U.S. consumption was estimated to have been about 2 kt (2,200 st) of contained lithium, a 100-percent increase from 2010. The United States was estimated to be the fourth-ranked consumer of lithium and remained the leading importer of lithium carbonate and the leading producer of value-added lithium materials. One company, Chemetall Foote Corp. (a subsidiary of Chemetall GmbH of Germany), produced lithium compounds from domestic brine resources near Silver Peak, NV.

  18. Lithium

    USGS Publications Warehouse

    Ober, J.A.

    2006-01-01

    In 2005, lithium consumption in the United States was at 2.5 kt of contained lithium, nearly 32% more than the estimate for 2004. World consumption was 14.1 kt of lithium contained in minerals and compounds in 2003. Exports from the US increased slightly compared with 2004. Due to strong demand for lithium compounds in 2005, both lithium carbonate plants in Chile were operating at or near capacity.

  19. A paramagnetic implant containing lithium naphthalocyanine microcrystals for high-resolution biological oximetry

    NASA Astrophysics Data System (ADS)

    Meenakshisundaram, Guruguhan; Pandian, Ramasamy P.; Eteshola, Edward; Lee, Stephen C.; Kuppusamy, Periannan

    2010-03-01

    Lithium naphthalocyanine (LiNc) is a microcrystalline EPR oximetry probe with high sensitivity to oxygen [R.P. Pandian, M. Dolgos, C. Marginean, P.M. Woodward, P.C. Hammel, P.T. Manoharan, P. Kuppusamy, Molecular packing and magnetic properties of lithium naphthalocyanine crystal: hollow channels enabling permeability and paramagnetic sensitivity to molecular oxygen J. Mater. Chem. 19 (2009) 4138-4147]. However, direct implantation of the crystals in the tissue for in vivo oxygen measurements may be hindered by concerns associated with their direct contact with the tissue/cells and loss of EPR signal due to particle migration in the tissue. In order to address these concerns, we have developed encapsulations (chips) of LiNc microcrystals in polydimethyl siloxane (PDMS), an oxygen-permeable, bioinert polymer. Oximetry evaluation of the fabricated chips revealed that the oxygen sensitivity of the crystals was unaffected by encapsulation in PDMS. Chips were stable against sterilization procedures or treatment with common biological oxidoreductants. In vivo oxygen measurements established the ability of the chips to provide reliable and repeated measurements of tissue oxygenation. This study establishes PDMS-encapsulated LiNc as a potential probe for long-term and repeated measurements of tissue oxygenation.

  20. Lithium-manganese dioxide cells for implantable defibrillator devices-Discharge voltage models

    NASA Astrophysics Data System (ADS)

    Root, Michael J.

    The discharge potential behavior of lithium-manganese dioxide cells designed for implantable cardiac defibrillators was characterized as a function of extent of cell depletion for tests designed to discharge the cells for times between 1 and 7 years. The discharge potential curves may be separated into two segments from 0 ≤ x ≤ ∼0.51 and ∼0.51 ≤ x ≤ 1.00, where x is the dimensionless extent of discharge referenced to the rated cell capacity. The discharge potentials conform to Tafel kinetics in each segment. This behavior allows the discharge potential curves to be predicted for an arbitrary discharge load and long term discharge performance may be predicted from short term test results. The discharge potentials may subsequently be modeled by fitting the discharge curves to empirical functions like polynomials and Padé approximants. A function based on the Nernst equation that includes a term accounting for nonideal interactions between lithium ions and the cathode host material, such as the Redlich-Kister relationship, also may be used to predict discharge behavior.

  1. Lithium

    USGS Publications Warehouse

    Ober, J.

    1998-01-01

    The lithium industry can be divided into two sectors: ore concentrate producers and chemical producers. Ore concentrate producers mine lithium minerals. They beneficiate the ores to produce material for use in ceramics and glass manufacturing.

  2. Use of prefabricated titanium abutments and customized anatomic lithium disilicate structures for cement-retained implant restorations in the esthetic zone.

    PubMed

    Lin, Wei-Shao; Harris, Bryan T; Zandinejad, Amirali; Martin, William C; Morton, Dean

    2014-03-01

    This report describes the fabrication of customized abutments consisting of prefabricated 2-piece titanium abutments and customized anatomic lithium disilicate structures for cement-retained implant restorations in the esthetic zone. The heat-pressed lithium disilicate provides esthetic customized anatomic structures and crowns independently of the computer-aided design and computer-aided manufacturing process. PMID:24360007

  3. A novel approach to implant screw-retained restorations: adhesive combination between zirconia frameworks and monolithic lithium disilicate.

    PubMed

    Fabbri, Giacomo; Sorrentino, Roberto; Brennan, Myra; Cerutti, Antonio

    2014-01-01

    The use of zirconia is an esthetic alternative to metal for implant-supported frameworks, and it has increased primarily for its high biocompatibility, low bacterial surface adhesion, high flexural strength and high mechanical features. The zirconia frameworks in fixed prosthetic restorations that are supported by implants is commonly covered with hand-layered overlay porcelain. This technical procedure is highly esthetic but it can cause some complications, such as porcelain fractures. The purpose of this article is to introduce an innovative approach to create an esthetic fixed ceramic implant restoration to minimize and facilitate the repair of the mechanical complications, by combining the adhesive-cementation of lithium disilicate full coverage restorations on implant screw-retained zirconia frameworks. PMID:25289384

  4. Structural and optical properties of rare-earth doped lithium niobate waveguides formed by MeV helium ion implantation

    SciTech Connect

    Herreros, B.; Lifante, G.; Cusso, F.; Kling, A.; Soares, J.C.; Silva, M.F. da; Townsend, P.D.; Chandler, P.J.

    1996-12-31

    Results of investigations of optical waveguides formed by high energy helium implantation into lithium niobate codoped with 5 mol% MgO and 1 mol% Tm{sup 3+} or 1 mol% Er{sup 3+} are reported. A comparative study of structural and luminescence properties between implanted and untreated samples has been performed by means of Rutherford backscattering (RBS) combined with channeling and photoluminescence methods, respectively in order to investigate residual lattice damage and the incorporation of the optical active rare earths. For the case of Tm a full substitutional incorporation of the optical active rare earths. For the case of Tm a full substitutional incorporation on the lithium site and a high crystal quality in both bulk and implanted waveguide material has been found. For Er doped lithium niobate the channeling results show a fraction of Er randomly incorporated or forming precipitates and a deterioration of the waveguide`s lattice. The optical investigations show in both cases only a slight broadening of the emission lines of the rare earths in the waveguides compared to the bulk material.

  5. Lithium

    MedlinePlus

    ... bipolar disorder (manic-depressive disorder; a disease that causes episodes of depression, episodes of mania, and other abnormal moods). Lithium ... Lithium is also sometimes used to treat depression, schizophrenia (a mental ... emotions), disorders of impulse control (inability to resist the urge ...

  6. Construction of waveguiding structures in potassium lithium tantalate niobate crystals by combined laser ablation and ion implantation

    NASA Astrophysics Data System (ADS)

    Yashar, Ayelet Badichi; Ilan, Harel; Agranat, Aharon J.

    2015-02-01

    A generic methodology for constructing complex integrated electro-optic circuits in waveguided configurations is presented. The method is based on combining two techniques, "laser ablation" and "refractive index engineering by ion implantations." The constructed circuits are side-cladded by air trenches that were produced using laser ablation and bottom-cladded by a layer with a reduced refractive index which is generated through the implantation of He+ ions. This fabrication technique enables the construction of circular structures with complex geometry featuring small radii of curvature, and further can be employed to construct microfluidic channels on the same substrate. The research demonstrates waveguides in both linear and circular configurations that were constructed in a potassium lithium tantalate niobate (KLTN) substrate using the aforementioned method, proving that this substrate is a suitable candidate for use in creating laboratories-on-a-chip with multifunctional capabilities. The proposed techniques used in the research are generic and applicable to a wide range of substrates.

  7. Lithium

    MedlinePlus

    ... mania (frenzied, abnormally excited mood) in people with bipolar disorder (manic-depressive disorder; a disease that causes episodes of depression, episodes of mania, and other abnormal moods). Lithium is in a ... antimanic agents. It works by decreasing abnormal activity in the brain.

  8. Erbium laser in gynecology.

    PubMed

    Vizintin, Z; Lukac, M; Kazic, M; Tettamanti, M

    2015-10-01

    The aim of this paper is to present a novel laser technology utilizing the erbium YAG laser for various minimally invasive, non-surgical procedures in gynecology. Non-ablative, thermal-only SMOOTH-mode erbium pulses are used to produce vaginal collagen hyperthermia, followed by collagen remodeling and the synthesis of new collagen fibers, resulting in improved vaginal tissue tightness and elasticity. This erbium laser technology is used for treatments of vaginal laxity, stress urinary incontinence, pelvic organ prolapse and vaginal atrophy. In the period from 2010 to 2014, several clinical studies covering all four indications were conducted with the aim to prove the efficacy and safety of this novel technology. An overview is presented of the results of these studies where several objective as well as subjective assessment tools were used. The results have shown that SMOOTH-mode erbium laser seems to be an effective and safe method for treating vaginal laxity, stress urinary incontinence, pelvic organ prolapses and vaginal atrophy. PMID:26366793

  9. Erbium diffusion in silicon dioxide

    SciTech Connect

    Lu Yingwei; Julsgaard, B.; Petersen, M. Christian; Jensen, R. V. Skougaard; Pedersen, T. Garm; Pedersen, K.; Larsen, A. Nylandsted

    2010-10-04

    Erbium diffusion in silicon dioxide layers prepared by magnetron sputtering, chemical vapor deposition, and thermal growth has been investigated by secondary ion mass spectrometry, and diffusion coefficients have been extracted from simulations based on Fick's second law of diffusion. Erbium diffusion in magnetron sputtered silicon dioxide from buried erbium distributions has in particular been studied, and in this case a simple Arrhenius law can describe the diffusivity with an activation energy of 5.3{+-}0.1 eV. Within a factor of two, the erbium diffusion coefficients at a given temperature are identical for all investigated matrices.

  10. Erbium hydride decomposition kinetics.

    SciTech Connect

    Ferrizz, Robert Matthew

    2006-11-01

    Thermal desorption spectroscopy (TDS) is used to study the decomposition kinetics of erbium hydride thin films. The TDS results presented in this report are analyzed quantitatively using Redhead's method to yield kinetic parameters (E{sub A} {approx} 54.2 kcal/mol), which are then utilized to predict hydrogen outgassing in vacuum for a variety of thermal treatments. Interestingly, it was found that the activation energy for desorption can vary by more than 7 kcal/mol (0.30 eV) for seemingly similar samples. In addition, small amounts of less-stable hydrogen were observed for all erbium dihydride films. A detailed explanation of several approaches for analyzing thermal desorption spectra to obtain kinetic information is included as an appendix.

  11. Monolithic Lithium Disilicate Full-Contour Crowns Bonded on CAD/CAM Zirconia Complete-Arch Implant Bridges With 3 to 5 Years of Follow-Up.

    PubMed

    Pozzi, Alessandro; Tallarico, Marco; Barlattani, Alberto

    2015-08-01

    This study was carried on to assess the clinical performance of a novel restorative concept consisting in single monolithic lithium disilicate full-contour crowns bonded on computer-aided design/computer-aided manufacturing (CAD/CAM) zirconia complete-arch implant bridges, to overcome the drawbacks related to the chipping of porcelain fused to zirconia restorations. Sixteen patients received 18 implant-supported hybrid screw-cement-retained complete-arch restorations, consisting of single monolithic lithium disilicate full-contour crowns bonded on CAD/CAM zirconia frameworks. The restorations were supported by 4-8 implants. All patients were followed up for at least 3 years on function (range 36 to 60 months, mean 49.3 months). Clinical controls were scheduled every 4 months. The outcomes were implant and prosthetic survival and success rates, any complications, patient satisfaction, and soft tissue parameters. No dropouts occurred. The overall implant and prosthesis survival rates were 100%. One of 18 restorations (1 of 236 dental units) showed a chip-off fracture of the veneering ceramic that was polished intraorally without any additional treatment, scoring a cumulative prosthetic success rate of 100%, according to the California Dental Association index. All patients were functionally and esthetically highly satisfied with their restorations. Successful soft tissue parameters were found around all implants. Single monolithic lithium disilicate full-contour crowns, bonded on CAD/CAM screw-retained complete-arch zirconia frameworks, showed favorable preliminary outcomes with medium-term follow-up. However, randomized controlled studies of this technique are required for further conclusive recommendations. PMID:24188105

  12. Suppressed gross erosion of high-temperature lithium via rapid deuterium implantation

    DOE PAGESBeta

    Abrams, T.; Jaworski, M. A.; Chen, M.; Carter, E. A.; Kaita, R.; Stotler, D. P.; De Temmerman, G.; Morgan, T. W.; van den Berg, M. A.; van der Meiden, H. J.

    2015-12-17

    Lithium-coated high-Z substrates are planned for use in the NSTX-U divertor and are a candidate plasma facing component (PFC) for reactors, but it remains necessary to characterize the gross Li erosion rate under high plasma fluxes (>1023 m-2 s-1), typical for the divertor region. In this work, a realistic model for the compositional evolution of a Li/D layer is developed that incorporates first principles molecular dynamics (MD) simulations of D diffusion in liquid Li. Predictions of Li erosion from a mixed Li/D material are also developed that include formation of lithium deuteride (LiD). The erosion rate of Li from LiDmore » is predicted to be significantly lower than from pure Li. This prediction is tested in the Magnum-PSI linear plasma device at ion fluxes of 1023-1024 m-2 s-1 and Li surface temperatures. ≤800 °C. Li/LiD coatings ranging in thickness from 0.2 to 500 μm are studied. The dynamic D/Li concentrations are inferred via diffusion simulations. The pure Li erosion rate remains greater than Langmuir Law evaporation, as expected. For mixed-material Li/LiD surfaces, the erosion rates are reduced, in good agreement with modelling in almost all cases. Lastly, these results imply that the temperature limit for a Li-coated PFC may be significantly higher than previously imagined.« less

  13. Suppressed gross erosion of high-temperature lithium via rapid deuterium implantation

    NASA Astrophysics Data System (ADS)

    Abrams, T.; Jaworski, M. A.; Chen, M.; Carter, E. A.; Kaita, R.; Stotler, D. P.; De Temmerman, G.; Morgan, T. W.; van den Berg, M. A.; van der Meiden, H. J.

    2016-01-01

    Lithium-coated high-Z substrates are planned for use in the NSTX-U divertor and are a candidate plasma facing component (PFC) for reactors, but it remains necessary to characterize the gross Li erosion rate under high plasma fluxes (>1023 m-2 s-1), typical for the divertor region. In this work, a realistic model for the compositional evolution of a Li/D layer is developed that incorporates first principles molecular dynamics (MD) simulations of D diffusion in liquid Li. Predictions of Li erosion from a mixed Li/D material are also developed that include formation of lithium deuteride (LiD). The erosion rate of Li from LiD is predicted to be significantly lower than from pure Li. This prediction is tested in the Magnum-PSI linear plasma device at ion fluxes of 1023-1024 m-2 s-1 and Li surface temperatures  ⩽800 °C. Li/LiD coatings ranging in thickness from 0.2 to 500 μm are studied. The dynamic D/Li concentrations are inferred via diffusion simulations. The pure Li erosion rate remains greater than Langmuir Law evaporation, as expected. For mixed-material Li/LiD surfaces, the erosion rates are reduced, in good agreement with modelling in almost all cases. These results imply that the temperature limit for a Li-coated PFC may be significantly higher than previously imagined.

  14. Suppressed gross erosion of high-temperature lithium via rapid deuterium implantation

    SciTech Connect

    Abrams, T.; Jaworski, M. A.; Chen, M.; Carter, E. A.; Kaita, R.; Stotler, D. P.; De Temmerman, G.; Morgan, T. W.; van den Berg, M. A.; van der Meiden, H. J.

    2015-12-17

    Lithium-coated high-Z substrates are planned for use in the NSTX-U divertor and are a candidate plasma facing component (PFC) for reactors, but it remains necessary to characterize the gross Li erosion rate under high plasma fluxes (>10(23) m(-2) s(-1)), typical for the divertor region. In this work, a realistic model for the compositional evolution of a Li/D layer is developed that incorporates first principles molecular dynamics (MD) simulations of D diffusion in liquid Li. Predictions of Li erosion from a mixed Li/D material are also developed that include formation of lithium deuteride (LiD). The erosion rate of Li from LiD is predicted to be significantly lower than from pure Li. This prediction is tested in the Magnum-PSI linear plasma device at ion fluxes of 10(23)-10(24) m(-2) s(-1) and Li surface temperatures. 800 degrees C. Li/LiD coatings ranging in thickness from 0.2 to 500 mu m are studied. The dynamic D/Li concentrations are inferred via diffusion simulations. The pure Li erosion rate remains greater than Langmuir Law evaporation, as expected. For mixed-material Li/LiD surfaces, the erosion rates are reduced, in good agreement with modelling in almost all cases. These results imply that the temperature limit for a Li-coated PFC may be significantly higher than previously imagined.

  15. Evidence for lithium and boron from star-forming regions implanted in presolar SiC grains

    NASA Astrophysics Data System (ADS)

    Lyon, I. C.; Tizard, J. M.; Henkel, T.

    2007-03-01

    We report the first measurements of lithium and boron isotope ratios and abundances measured in "gently separated" presolar SiC grains. Almost all analyses of presolar SiC grains since their first isolation in 1987 have been obtained from grains that were separated from their host meteorite by harsh acid dissolution. We recently reported a new method of "gently" separating the grains from meteorites by using freeze-thaw disaggregation, size, and density separation to retain any nonrefractory coatings or alteration to the surfaces of the grains that have been acquired in interstellar space. Nonrefractory coats or amorphized surfaces will almost certainly be removed or altered by the traditional acid separation procedure. High Li/Si and B/Si ratios of up to ˜10-2 were found implanted in the outer 0.5 μm of the grains dropping to ˜10-5 in the core of the grains.7Li/6Li and 11B/10B ratios indistinguishable from solar system average values were found. Analyses obtained from SiC grains from the acid dissolution technique showed isotope ratios that were the same as those of gently separated grains, but depth profiles that were different. These results are interpreted as evidence of implantation of high velocity (1200-1800 km s-1) Li and B ions into the grains by shock waves as the grains traveled through star-forming regions some time after their condensation in the outflow of an AGB star that was their progenitor. The results are in line with spectroscopic measurements of Li and B isotope ratios in star-forming regions and may be used to infer abundances and isotopic sources in these regions.

  16. Suppressed gross erosion of high-temperature lithium via rapid deuterium implantation

    SciTech Connect

    Abrams, T.; Jaworski, M. A.; Chen, M.; Carter, E. A.; Kaita, R.; Stotler, D. P.; De Temmerman, G.; Morgan, T. W.; van den Berg, M. A.; van der Meiden, H. J.

    2015-12-17

    Lithium-coated high-Z substrates are planned for use in the NSTX-U divertor and are a candidate plasma facing component (PFC) for reactors, but it remains necessary to characterize the gross Li erosion rate under high plasma fluxes (>1023 m-2 s-1), typical for the divertor region. In this work, a realistic model for the compositional evolution of a Li/D layer is developed that incorporates first principles molecular dynamics (MD) simulations of D diffusion in liquid Li. Predictions of Li erosion from a mixed Li/D material are also developed that include formation of lithium deuteride (LiD). The erosion rate of Li from LiD is predicted to be significantly lower than from pure Li. This prediction is tested in the Magnum-PSI linear plasma device at ion fluxes of 1023-1024 m-2 s-1 and Li surface temperatures. ≤800 °C. Li/LiD coatings ranging in thickness from 0.2 to 500 μm are studied. The dynamic D/Li concentrations are inferred via diffusion simulations. The pure Li erosion rate remains greater than Langmuir Law evaporation, as expected. For mixed-material Li/LiD surfaces, the erosion rates are reduced, in good agreement with modelling in almost all cases. Lastly, these results imply that the temperature limit for a Li-coated PFC may be significantly higher than previously imagined.

  17. Optical emission from erbium-doped silica nanowires

    NASA Astrophysics Data System (ADS)

    Elliman, R. G.; Wilkinson, A. R.; Kim, T.-H.; Sekhar, P. K.; Bhansali, S.

    2008-05-01

    Infrared optical emission from erbium-doped silica nanowires is shown to have property characteristic of the material nanostructure and to provide the basis for the fabrication of integrated photonic devices and biosensors. Silica nanowires of approximately 150 nm diameter were grown on a silicon wafer by metal-induced growth using a thin (20 nm) sputter-deposited palladium layer as a catalyst. The resulting wires were then ion implanted with 110 keV ErO- ions and annealed at 900 °C to optically activate the erbium. These wires exhibited photoluminescence emission at 1.54 μm, characteristic of the I415/2-I413/2 transition in erbium; however, comparison to similarly implanted fused silica layers revealed stronger thermal quenching and longer luminescence lifetimes in the nanowire samples. The former is attributed to an increase in defect-induced quenching partly due to the large surface-volume ratio of the nanowires, while the latter is attributed to a reduction in the optical density of states associated with the nanostructure morphology. Details of this behavior are discussed together with the implications for potential device applications.

  18. Study of the negative magneto-resistance of single proton-implanted lithium-doped ZnO microwires.

    PubMed

    Lorite, I; Zandalazini, C; Esquinazi, P; Spemann, D; Friedländer, S; Pöppl, A; Michalsky, T; Grundmann, M; Vogt, J; Meijer, J; Heluani, S P; Ohldag, H; Adeagbo, W A; Nayak, S K; Hergert, W; Ernst, A; Hoffmann, M

    2015-07-01

    The magneto-transport properties of single proton-implanted ZnO and of Li(7%)-doped ZnO microwires have been studied. The as-grown microwires were highly insulating and not magnetic. After proton implantation the Li(7%) doped ZnO microwires showed a non-monotonous behavior of the negative magneto-resistance (MR) at temperature above 150 K. This is in contrast to the monotonous NMR observed below 50 K for proton-implanted ZnO. The observed difference in the transport properties of the wires is related to the amount of stable Zn vacancies created at the near surface region by the proton implantation and Li doping. The magnetic field dependence of the resistance might be explained by the formation of a magnetic/non-magnetic heterostructure in the wire after proton implantation. PMID:26043764

  19. Study of the negative magneto-resistance of single proton-implanted lithium-doped ZnO microwires

    NASA Astrophysics Data System (ADS)

    Lorite, I.; Zandalazini, C.; Esquinazi, P.; Spemann, D.; Friedländer, S.; Pöppl, A.; Michalsky, T.; Grundmann, M.; Vogt, J.; Meijer, J.; Heluani, S. P.; Ohldag, H.; Adeagbo, W. A.; Nayak, S. K.; Hergert, W.; Ernst, A.; Hoffmann, M.

    2015-06-01

    The magneto-transport properties of single proton-implanted ZnO and of Li(7%)-doped ZnO microwires have been studied. The as-grown microwires were highly insulating and not magnetic. After proton implantation the Li(7%) doped ZnO microwires showed a non-monotonous behavior of the negative magneto-resistance (MR) at temperature above 150 K. This is in contrast to the monotonous NMR observed below 50 K for proton-implanted ZnO. The observed difference in the transport properties of the wires is related to the amount of stable Zn vacancies created at the near surface region by the proton implantation and Li doping. The magnetic field dependence of the resistance might be explained by the formation of a magnetic/non-magnetic heterostructure in the wire after proton implantation.

  20. Growth studies of erbium-doped GaAs deposited by metalorganic vapor phase epitaxy using noval cyclopentadienyl-based erbium sources

    NASA Technical Reports Server (NTRS)

    Redwing, J. M.; Kuech, T. F.; Gordon, D. C.; Vaartstra, B. A.; Lau, S. S.

    1994-01-01

    Erbium-doped GaAS layers were grown by metalorganic vapor phase epitaxy using two new sources, bis(i-propylcyclopentadienyl)cyclopentadienyl erbium and tris(t-butylcyclopentadienyl) erbium. Controlled Er doping in the range of 10(exp 17) - 10(exp 18)/cu cm was achieved using a relatively low source temperature of 90 C. The doping exhibits a second-order dependence on inlet source partial pressure, similar to behavior obtained with cyclopentadienyl Mg dopant sources. Equivalent amounts of oxygen and Er are present in 'as-grown' films indicating that the majority of Er dopants probably exist as Er-O complexes in the material. Er(+3) luminescence at 1.54 micrometers was measured from the as-grown films, but ion implantation of additional oxygen decreases the emission intensity. Electrical compensation of n-type GaAs layers codoped with Er and Si is directly correlated to the Er concentration is proposed to arise from the deep centers associated with Er which are responsible for a broad emission band near 0.90 micrometers present in the photoluminescence spectra of GaAs:Si, Er films.

  1. Erbium-doped aluminophosphosilicate optical fibres

    SciTech Connect

    Likhachev, M E; Bubnov, M M; Zotov, K V; Medvedkov, O I; Lipatov, D S; Yashkov, M V; Gur'yanov, Aleksei N

    2010-09-10

    We have studied the active properties of erbium-doped aluminophosphosilicate (APS) core fibres in wide ranges of erbia, alumina and phosphorus pentoxide concentrations. The absorption and luminescence spectra of the P{sub 2}O{sub 5}- or Al{sub 2}O{sub 3}-enriched erbium-doped APS fibres are shown to be similar to those of the erbium-doped fibres singly doped with phosphorus pentoxide or alumina, respectively. The formation of AlPO{sub 4} in APS fibres leads not only to a reduction in the refractive index of the glass but also to a marked increase in Er{sub 2}O{sub 3} solubility in silica. (optical fibres)

  2. Effect of lithium-ion implantation of varying fluence on the optical properties of ZnMgO

    NASA Astrophysics Data System (ADS)

    Saha, S.; Nagar, S.; Gupta, S. K.; Chakrabarti, S.

    2014-03-01

    The large bandgap (3.37 eV) and exciton binding energy (60 meV) makes ZnO most promising material in the area of optoelectronic devices. The efficiency of these devices can be enhanced by increasing the bandgap of those materials which is possible by band-gap engineering. It has been found that incorporation of Mg can increase the bandgap of the alloy up to 4 eV and even more. We investigated the optical properties of Zn1-x MgxO film implanted by Li at low energy (40 KeV) with dosage of 5x1013 ions/cm2 and 1014 ions/cm2 respectively. Prior to implantation 150 nm Zn1-x MgxO (x=0.15) film was deposited on Si substrate followed by annealing at 650°C and 750°C. For dosage of 5x1013 ions/cm2 and 1014 ions/cm2 the low temperature (15K) and room temperature photoluminescence spectra is dominated by the emission of 3.66 eV which is the band gap energy of Zn1-xMgxO, shifts to 3.63 eV at higher dosage of ions. With increasing energy (50 KeV) this peak was revealed only at 5x1013 ions/cm2. At 1014 ions/cm2 no sign of this peak was visible. The splitting of conduction band and valence band into multiple sub-bands causes a transition between the subband of conduction band and sub-band of heavy-hole and an emission occurs at 3.58 eV referred as 11H. The existence of acceptor-bound exciton peak (A°X) around 3.33 eV and the presence of donor-to-acceptor-pair peak at 3.24 eV provide strong evidence of increased acceptor concentration.

  3. Complete atrioventricular block secondary to lithium therapy.

    PubMed

    Shiraki, Teruo; Kohno, Kunihisa; Saito, Daiji; Takayama, Hiroki; Fujimoto, Akira

    2008-05-01

    Sinus node dysfunction has been reported most frequently among the adverse cardiovascular effects of lithium. In the present case, complete atrioventricular (AV) block with syncopal attacks developed secondary to lithium therapy, necessitating permanent pacemaker implantation. Serum lithium levels remained under or within the therapeutic range during the syncopal attacks. Lithium should be used with extreme caution, especially in patients with mild disturbance of AV conduction. PMID:18441470

  4. Erbium hydride thermal desorption : controlling kinetics.

    SciTech Connect

    Ferrizz, Robert Matthew

    2007-08-01

    Thermal desorption spectroscopy (TDS) is used to study the decomposition kinetics of erbium hydride thin films. The TDS results presented in this report show that hydride film processing parameters directly impact thermal stability. Issues to be addressed include desorption kinetics for dihydrides and trihydrides, and the effect of film growth parameters, loading parameters, and substrate selection on desorption kinetics.

  5. Erbium:YAG laser for cataract extraction

    NASA Astrophysics Data System (ADS)

    Snyder, Robert W.; Jani, Mahendra G.; Yarborough, Mike; Marcellino, George R.; Noecker, Robert J.; Kramer, Theresa R.; Vidaurri, Jesus

    1998-06-01

    The Erbium:YAG laser may be an effective laser for use in cataract surgery. At 2.94 mm the energy is maximally absorbed by water thereby efficiently disrupting tissue with minimal surrounding thermal damage. The laser may be safer to use in the eye than conventional ultrasonic emulsifiers. Preliminary clinical studies of the safety and efficacy have begun.

  6. Anisotropic optical trapping of ultracold erbium atoms

    NASA Astrophysics Data System (ADS)

    Dulieu, Olivier; Lepers, Maxence; Wyart, Jean-Francois

    2014-05-01

    We calculate the complex dynamic dipole polarizability of ground-state erbium, a rare-earth atom that was recently Bose-condensed. This quantity determines the trapping conditions of cold atoms in an optical trap. The polarizability is calculated with the sum-over-state formula inherent to second-order perturbation theory. The summation is performed on transition energies and transition dipole moments from ground-state erbium, which are computed using the Racah-Slater least-square fitting procedure provided by the Cowan codes. This allows us to predict several yet unobserved energy levels in the range 25000-31000 cm-1 above the ground state. Regarding the trapping potential, we find that ground-state erbium essentially behaves like a spherically-symmetric atom, in spite of its large electronic angular momentum. We find a mostly isotropic van der Waals interaction between two ground-state erbium atoms, with a coefficient C6iso= 1760 a.u.. On the contrary, the photon-scattering rate is strongly anisotropic with respect to the polarization of the trapping light. also at LERMA, UMR8112, Observatoire de Paris-Meudon, Univ. Pierre et Marie Curie, Meudon, France.

  7. Anisotropic optical trapping of ultracold erbium atoms

    NASA Astrophysics Data System (ADS)

    Lepers, M.; Wyart, J.-F.; Dulieu, O.

    2014-02-01

    Ultracold atoms confined in a dipole trap are submitted to a potential whose depth is proportional to the real part of their dynamic dipole polarizability. The atoms also experience photon scattering whose rate is proportional to the imaginary part of their dynamic dipole polarizability. In this article we calculate the complex dynamic dipole polarizability of ground-state erbium, a rare-earth atom that was recently Bose condensed. The polarizability is calculated with the sum-over-state formula inherent to second-order perturbation theory. The summation is performed on transition energies and transition dipole moments from ground-state erbium, which are computed using the Racah-Slater least-squares fitting procedure provided by the cowan codes. This allows us to predict nine unobserved odd-parity energy levels of total angular momentum J =5, 6, and 7, in the range 25 000-31 000 cm-1 above the ground state. Regarding the trapping potential, we find that ground-state erbium essentially behaves like a spherically symmetric atom, in spite of its large electronic angular momentum. We also find a mostly isotropic van der Waals interaction between two ground-state erbium atoms, characterized by a coefficient C6iso=1760 a.u. To the contrary, the photon-scattering rate shows a pronounced anisotropy since it strongly depends on the polarization of the trapping light.

  8. Microstructural, electrical and magnetic properties of erbium doped zinc oxide single crystals

    NASA Astrophysics Data System (ADS)

    Murmu, P. P.; Kennedy, J.; Ruck, B. J.; Rubanov, S.

    2015-11-01

    We report the structural, electrical and magnetic properties of erbium (Er) implanted zinc oxide (ZnO) single crystals. Rutherford backscattering and channeling results showed that the majority of Er atoms resided in Zn substitutional lattice sites. Annealing led to a fraction of Er atoms moving into random interstitial sites. Transmission electron microscopy micrographs revealed that doped Er atoms were located in the near-surface region, consistent with the results obtained from DYNAMIC-TRIM calculations. A non-linear Hall-voltage was observed near 100 K, which is associated with inhomogeneous transport in the material. The Er implanted and annealed ZnO exhibited persistent magnetic ordering to room temperature. Ferromagnetism was likely from the presence of intrinsic defects in ZnO, which mediates the magnetic ordering in Er implanted and annealed ZnO. [Figure not available: see fulltext.

  9. Characterization of the surface changes during the activation of erbium/erbium oxide for hydrogen storage.

    SciTech Connect

    Zavadil, Kevin Robert; Snow, Clark Sheldon; Brumbach, Michael Todd

    2010-09-01

    Erbium is known to effectively load with hydrogen when held at high temperature in a hydrogen atmosphere. To make the storage of hydrogen kinetically feasible, a thermal activation step is required. Activation is a routine practice, but very little is known about the physical, chemical, and/or electronic processes that occur during Activation. This work presents in situ characterization of erbium Activation using variable energy photoelectron spectroscopy at various stages of the Activation process. Modification of the passive surface oxide plays a significant role in Activation. The chemical and electronic changes observed from core-level and valence band spectra will be discussed along with corroborating ion scattering spectroscopy measurements.

  10. The role of lithium batteries in modern health care

    NASA Astrophysics Data System (ADS)

    Holmes, Curtis F.

    Since the implantation of the first lithium-powered pacemaker in 1972, biomedical devices powered by lithium batteries have played a significant role in saving lives and providing health-improving therapy. Today a wide variety of devices performing functions from managing cardiac rhythm to relieving pain and administering drugs is available to clinicians. Newer devices such as ventricular assist devices and implantable hearing devices are powered by lithium ion secondary batteries.

  11. Gamma-ray-induced damage and recovery behavior in an erbium-doped fiber laser

    NASA Astrophysics Data System (ADS)

    Bussjager, Rebecca J.; Hayduk, Michael J.; Johns, Steven T.; Taylor, Linda R.; Taylor, Edward W.

    2002-01-01

    Erbium-doped fiber lasers (EDFLs) may soon find applications in space as high bit rate optical communication systems and photonic analog-to-digital converters (ADCs). The rapid advancement in digital signal processing systems has led to an increased interest in the direct digitization of high- frequency analog signals. The potential high bandwidth, reduced weight, and reduced power requirements makes photonics an attractive technology for wide-band signal conversion as well as for use in space-based platforms. It is anticipated that photonic ADCs will be able to operate at sampling rates and resolutions far greater than current electronic ADCs. The high repetition rates and narrow pulse widths produced by EDFLs allow for high-speed impulse sampling of analog signals thus making it a vital component of a photonic ADC. In this paper we report on the in situ gamma-ray irradiation of an actively mode-locked EDFL operating at 1530 nm. The onset, growth and extent of ionization induced damage under time-resolved operational conditions is presented. The laser consisted of approximately 3 meters of erbium-doped fiber pumped by a laser diode operating at 980 nm. The picosecond pulses produced by the laser were initiated and controlled by a Mach-Zehnder lithium niobate electro-optic modulator. The active mode-locking element allowed for the precise timing control of the laser repetition rate which is critical in high-speed optical networking systems as well as in photonic ADCs.

  12. Erbium laser resurfacing for actinic cheilitis.

    PubMed

    Cohen, Joel L

    2013-11-01

    Actinic cheilitis is a precancerous condition characterized by grayish-whitish area(s) of discoloration on the mucosal lip, often blunting the demarcation between mucosa and cutaneous lip. Actinic cheilitis is considered to be an early part of the spectrum of squamous cell carcinoma. Squamous cell carcinoma specifically of the lip has a high rate of recurrence and metastasis through the oral cavity leading to a poor overall survival. Risk factors for the development of actinic cheilitis include chronic solar irradiation, increasing age, male gender, light skin complexion, immunosuppression, and possibly tobacco and alcohol consumption. Treatment options include topical pharmacotherapy (eg, fluorouracil, imiquimod) or procedural interventions (eg, cryotherapy, electrosurgery, surgical vermillionectomy, laser resurfacing), each with their known advantages and disadvantages. There is little consensus as to which treatment options offer the most clinical utility given the paucity of comparative clinical data. In my practice, laser resurfacing has become an important tool for the treatment of actinic cheilitis owing to its ease of use and overall safety, tolerability, and cosmetic acceptability. Herein the use of erbium laser resurfacing is described for three actinic cheilitis presentations for which I find it particularly useful: clinically prominent actinic cheilitis, biopsy-proven actinic cheilitis, and treatment of the entire lip following complete tumor excision of squamous cell carcinoma. All patients were treated with a 2940-nm erbium laser (Sciton Profile Contour Tunable Resurfacing Laser [TRL], Sciton, Inc., Palo Alto, CA). PMID:24196339

  13. Microstructural Features in Aged Erbium Tritide Foils

    SciTech Connect

    Gelles, David S.; Brewer, L. N.; Kotula, Paul G.; Cowgill, Donald F.; Busick, C. C.; Snow, C. S.

    2008-01-01

    Aged erbium tritide foil specimens are found to contain five distinctly different microstructural features. The general structure was of large columnar grains of ErT2. But on a fine scale, precipitates believed to be erbium oxy-tritides and helium bubbles could be identified. The precipitate size was in the range of ~10 nm and the bubbles were of an unusual planar shape on {111} planes with an invariant thickness of ~1 nm and a diameter on the order of 10 nm. Also, an outer layer containing no fine precipitate structure and only a few helium bubbles was present on foils. This layer is best described as a denuded zone which probably grew during aging in air. Finally, large embedded Er2O3 particles were found at low density and non-uniformly distributed, but sometimes extending through the thickness of the foil. A failure mechanism allowing the helium to escape is suggested by observed cracking between bubbles closer to end of life.

  14. Optical Frequency Comb Generation based on Erbium Fiber Lasers

    NASA Astrophysics Data System (ADS)

    Droste, Stefan; Ycas, Gabriel; Washburn, Brian R.; Coddington, Ian; Newbury, Nathan R.

    2016-06-01

    Optical frequency combs have revolutionized optical frequency metrology and are being actively investigated in a number of applications outside of pure optical frequency metrology. For reasons of cost, robustness, performance, and flexibility, the erbium fiber laser frequency comb has emerged as the most commonly used frequency comb system and many different designs of erbium fiber frequency combs have been demonstrated. We review the different approaches taken in the design of erbium fiber frequency combs, including the major building blocks of the underlying mode-locked laser, amplifier, supercontinuum generation and actuators for stabilization of the frequency comb.

  15. Size control of erbium-doped silicon nanocrystals

    NASA Astrophysics Data System (ADS)

    John, John St.; Coffer, Jeffery L.; Chen, Yandong; Pinizzotto, Russell F.

    2000-09-01

    This work describes the effects of pyrolysis oven length and erbium precursor on the preparation of discrete erbium-doped silicon nanoparticles. These doped nanoparticles were prepared by the co-pyrolysis of disilane and the volatile complex Er(tmhd)3 (tmhd=2,2,6,6-tetramethyl-3,5-heptanedionato). The particle sizes and size distributions were determined using high resolution and conventional transmission electron microscopy. Erbium-doped silicon nanoparticles exhibit a selected area electron diffraction pattern consistent with the diamond cubic phase and a distinctive dark contrast in the transmission electron microscope. The presence of erbium is confirmed by x-ray energy dispersive spectroscopy. In general, the mean diameter of the individual nanoparticles increases as the length of the pyrolysis oven used during their preparation is increased.

  16. Luminescence of erbium ions in tellurite glasses

    SciTech Connect

    Savikin, Alexander P.; Grishin, Igor A.; Sharkov, Valery V.; Budruev, Andrei V.

    2013-11-15

    Optical characteristics of new generation of tellurite glasses having high stability against crystallization have been studied. As the initial reagents for the glasses synthesis on the base of tellurium oxide (TeO{sub 2}) there were used such oxides as WO{sub 3}, MoO{sub 3}, La{sub 2}O{sub 3}, Li{sub 2}CO{sub 3}, ZnO—Bi{sub 2}O{sub 2}CO{sub 3} and active components such as high purity Er{sub 2}O{sub 3}, Yb{sub 2}O{sub 3}, ErF{sub 3} and YbF{sub 3}. Intensities of luminescence at 1.53 µm of the erbium ions were determined after excitation at 975 nm. Experimental data obtained have shown the possibility to use the studied glasses doped by Er{sup 3+} and Yb{sup 3+} as active elements for fiber and integrated optics. - Graphical abstract: In contrast to the case of ZBLAN glass the TeO{sub 2}–WO{sub 3} (Er{sup 3+}) glass has bright intensity of luminescence at 1.53 µm for erbium ions that should be caused by excitation at 975 nm. Experimental data obtained have shown the possibility to use the studied glasses doped by Er{sup 3+} and Yb{sup 3+} as active elements for fiber and integrated optics. Display Omitted - Highlights: • We examined changes in growth of luminescence in doubly-doped tellurite glasses. • We found that luminescence grows in two orders by using Er{sup 3+} and Yb{sup 3+} at 1.53 μm. • We see possibility to use those glasses as active elements for integrated optics.

  17. Erbium Doped Fiber Sources and Amplifiers for Optical Fiber Sensors.

    NASA Astrophysics Data System (ADS)

    Wagener, Jefferson L.

    1996-08-01

    This thesis explores the use of erbium-doped fiber in lasers, amplified spontaneous emission sources, and amplifiers with particular attention to applications involving fiber sensor technology. Erbium-doped fiber laser output power is shown to be strongly dependent on the erbium dopant concentration in a fiber. Using multiple fibers with various erbium ion concentrations, laser output powers are found to decrease as erbium concentration is increased. Upconversion in paired ions is successfully used to model the lasers, resulting in a better understanding of the loss mechanism involved. Further investigation shows that co-doping an erbium-doped fiber with aluminum helps eliminate upconversion in paired ions, and an optimum ratio of 20 aluminum ions for every erbium ion is established. Upconversion due to paired ions is also used to predict the behavior of erbium-doped fiber amplifiers as a function of the erbium ion concentration. With this knowledge of concentration dependence, a low doped, high output power fiber is chosen for use as an amplified spontaneous emission source in a fiber optic gyroscope. Used as a single pass broadband source in one propagation direction and as a signal amplifier in the other direction, this source is tested experimentally in a high quality fiber gyroscope. Experimental results reveal an unexpected dependence on the polarization states of the optical pump and the gyroscope output signal. A theory of polarization anisotropy in the erbium ions is developed in full and accurately models the experimental observations. Using this model to optimize the source, a fiber gyroscope output stability of 4 parts per million is obtained experimentally, approaching the requirements of inertial navigation. This model is also used to explore novel single polarization amplified spontaneous emission sources. Large scale amplified sensor arrays are examined theoretically to determine component and amplification requirements. For balanced gain and loss

  18. Hydrogen, lithium, and lithium hydride production

    SciTech Connect

    Brown, Sam W; Spencer, Larry S; Phillips, Michael R; Powell, G. Louis; Campbell, Peggy J

    2014-03-25

    A method of producing high purity lithium metal is provided, where gaseous-phase lithium metal is extracted from lithium hydride and condensed to form solid high purity lithium metal. The high purity lithium metal may be hydrided to provide high purity lithium hydride.

  19. Batteries used to Power Implantable Biomedical Devices

    PubMed Central

    Bock, David C.; Marschilok, Amy C.; Takeuchi, Kenneth J.; Takeuchi, Esther S.

    2012-01-01

    Battery systems have been developed that provide years of service for implantable medical devices. The primary systems utilize lithium metal anodes with cathode systems including iodine, manganese oxide, carbon monofluoride, silver vanadium oxide and hybrid cathodes. Secondary lithium ion batteries have also been developed for medical applications where the batteries are charged while remaining implanted. While the specific performance requirements of the devices vary, some general requirements are common. These include high safety, reliability and volumetric energy density, long service life, and state of discharge indication. Successful development and implementation of these battery types has helped enable implanted biomedical devices and their treatment of human disease. PMID:24179249

  20. Activatino of Erbium Films for Hydrogen Storage

    SciTech Connect

    M Brumbach; j Ohlhausen; K Zavadil; C Snow; J Woicik

    2011-12-31

    Hydriding of metals can be routinely performed at high temperature in a rich hydrogen atmosphere. Prior to the hydrogen loading process, a thermal activation procedure is required to promote facile hydrogen sorption into the metal. Despite the wide spread utilization of this activation procedure, little is known about the chemical and electronic changes that occur during activation and how this thermal pretreatment leads to increased rates of hydrogen uptake. This study utilized variable kinetic energy X-ray photoelectron spectroscopy to interrogate the changes during in situ thermal annealing of erbium films, with results confirmed by time-of-flight secondary ion mass spectrometry and low energy ion scattering. Activation can be identified by a large increase in photoemission between the valence band edge and the Fermi level and appears to occur over a two stage process. The first stage involves desorption of contaminants and recrystallization of the oxide, initially impeding hydrogen loading. Further heating overcomes the first stage and leads to degradation of the passive surface oxide leading to a bulk film more accessible for hydrogen loading.

  1. Erbium concentration dependent absorbance in tellurite glass

    SciTech Connect

    Sazali, E. S. Rohani, M. S. Sahar, M. R. Arifin, R. Ghoshal, S. K. Hamzah, K.

    2014-09-25

    Enhancing the optical absorption cross-section in topically important rare earth doped tellurite glasses is challenging for photonic devices. Controlled synthesis and detailed characterizations of the optical properties of these glasses are important for the optimization. The influence of varying concentration of Er{sup 3+} ions on the absorbance characteristics of lead tellurite glasses synthesized via melt-quenching technique are investigated. The UV-Vis absorption spectra exhibits six prominent peaks centered at 490, 526, 652, 800, 982 and 1520 nm ascribed to the transitions in erbium ion from the ground state to the excited states {sup 4}F{sub 7/2}, {sup 2}H{sub 11/2}, {sup 4}F{sub 9/2}, {sup 4}I{sub 9/2}, {sup 2}H{sub 11/2} and {sup 4}I{sub 13/2}, respectively. The results are analyzed by means of optical band gap E{sub g} and Urbach energy E{sub u}. The values of the energy band gap are found decreased from 2.82 to 2.51 eV and the Urbach energy increased from 0.15 to 0.24 eV with the increase of the Er{sub 2}O{sub 3} concentration from 0 to 1.5 mol%. The excellent absorbance of the prepared tellurite glasses makes them suitable for fabricating solid state lasers.

  2. Activation of erbium films for hydrogen storage

    SciTech Connect

    Brumbach, Michael T.; Ohlhausen, James A.; Zavadil, Kevin R.; Snow, Clark S.; Woicik, Joseph C.

    2011-06-01

    Hydriding of metals can be routinely performed at high temperature in a rich hydrogen atmosphere. Prior to the hydrogen loading process, a thermal activation procedure is required to promote facile hydrogen sorption into the metal. Despite the wide spread utilization of this activation procedure, little is known about the chemical and electronic changes that occur during activation and how this thermal pretreatment leads to increased rates of hydrogen uptake. This study utilized variable kinetic energy X-ray photoelectron spectroscopy to interrogate the changes during in situ thermal annealing of erbium films, with results confirmed by time-of-flight secondary ion mass spectrometry and low energy ion scattering. Activation can be identified by a large increase in photoemission between the valence band edge and the Fermi level and appears to occur over a two stage process. The first stage involves desorption of contaminants and recrystallization of the oxide, initially impeding hydrogen loading. Further heating overcomes the first stage and leads to degradation of the passive surface oxide leading to a bulk film more accessible for hydrogen loading.

  3. Nanothermometry using optically trapped erbium oxide nanoparticle

    NASA Astrophysics Data System (ADS)

    Baral, Susil; Johnson, Samuel C.; Alaulamie, Arwa A.; Richardson, Hugh H.

    2016-04-01

    A new optical probe technique using a laser-trapped erbium oxide nanoparticle (size ~150 nm) is introduced that can measure absolute temperature with a spatial resolution on the size of the trapped nanoparticle. This technique (scanning optical probe thermometry) is used to collect a thermal image of a gold nanodot prepared with hole-mask colloidal lithography. A convolution analysis of the thermal profile shows that the point spread function of our measurement is a Gaussian with a FWHM of 165 nm. We attribute the width of this function to clustering of Er2O3 nanoparticles in solution. The scanning optical probe thermometer is used to measure the temperature where vapor nucleation occurs in degassed water (555 K), confirming that a nanoscale object heated in water will superheat the surrounding water to the spinodal decomposition temperature. Subsequently, the temperature inside the vapor bubble rises to the melting point of the gold nanostructure (~1300) where a temperature plateau is observed. The rise in temperature is attributed to inhibition of thermal transfer to the surrounding liquid by the thermal insulating vapor cocoon.

  4. Performance characteristics of a mode-locked erbium-doped fiber ring laser as a function of erbium ion concentration

    NASA Astrophysics Data System (ADS)

    Fanto, Michael L.; Gerhardstein, Cheryl M.; Vettese, E. K.; Winter, D. L.; Johns, Steven T.; Bussjager, Rebecca J.; Hayduk, Michael J.

    2003-07-01

    The generation of ultrastable picosecond pulses in the 1550 nm range is required for numerous applications including photonic analog-to-digital converter systems and high-bit rate optical communication systems. Mode-locked erbium-doped fiber ring lasers are typically used to generate pulses at this wavelength. In addition to stability and output power, the physical size of the laser cavity is of primary importance. The length of the erbium-doped fiber used as the gain medium may be on the order of meters or even tens of meters which makes packing of the laser rather difficult. However the length of the gain medium can often be reduced if the erbium ion concentration within the fiber is increased. This paper will investigate the performance of an erbium-doped fiber ring laser as a function of ion concentration within the gain medium. Results will be presented for mode-locked lasers consisting of Lucent HE980, HG980 and HC erbium-doped fibers. The parameters that will be compared between the lasers include the output power as a function of length and concentration, optical pulse width and spectral bandwidth. Phase noise measurements of the laser output will also be presented.

  5. Composition and structure of sputter deposited erbium hydride thin films

    SciTech Connect

    ADAMS,DAVID P.; ROMERO,JUAN A.; RODRIGUEZ,MARK A.; FLORO,JERROLD A.; BANKS,JAMES C.

    2000-05-10

    Erbium hydride thin films are grown onto polished, a-axis {alpha} Al{sub 2}O{sub 3} (sapphire) substrates by reactive ion beam sputtering and analyzed to determine composition, phase and microstructure. Erbium is sputtered while maintaining a H{sub 2} partial pressure of 1.4 x 10{sup {minus}4} Torr. Growth is conducted at several substrate temperatures between 30 and 500 C. Rutherford backscattering spectrometry (RBS) and elastic recoil detection analyses after deposition show that the H/Er areal density ratio is approximately 3:1 for growth temperatures of 30, 150 and 275 C, while for growth above {approximately}430 C, the ratio of hydrogen to metal is closer to 2:1. However, x-ray diffraction shows that all films have a cubic metal sublattice structure corresponding to that of ErH{sub 2}. RBS and Auger electron that sputtered erbium hydride thin films are relatively free of impurities.

  6. Dipolar Physics in an Erbium Quantum Gas Microscope

    NASA Astrophysics Data System (ADS)

    Hebert, Anne; Krahn, Aaron; Phelps, Gregory; Dickerson, Susannah; Greiner, Markus; Erbium Lab Team

    2016-05-01

    Erbium offers exciting possibilities for extending the single-site imaging work of current quantum gas microscopes. With a magnetic dipole moment of 7μB, the dipole-dipole interaction of erbium is 50 times that of alkali atoms. The long-range and anisotropic nature of the dipole interaction adds richness to the short-range interactions that dominate the physics of the ground-state alkali atoms commonly used in ultracold experiments today. Erbium has several abundant isotopes, giving the added flexibility of studying both bosonic and fermionic systems. We present proposed avenues of research for the dipolar microscope being developed, including studies of magnetism, the Einstein-de Haas effect, and quantum phase transitions with fractional filling factors.

  7. The influence of silver-ion doping using ion implantation on the luminescence properties of Er-Yb silicate glasses

    NASA Astrophysics Data System (ADS)

    Stanek, S.; Nekvindova, P.; Svecova, B.; Vytykacova, S.; Mika, M.; Oswald, J.; Mackova, A.; Malinsky, P.; Spirkova, J.

    2016-03-01

    A set of zinc-silicate glasses with different ratios of erbium and ytterbium was fabricated. To achieve Ag-rich thin films in a sub-surface layer, ion-implantation technique at an energy of 1.2 MeV and 1.7 MeV with a fluence of 1 × 1016 cm-2 was used. Post-implantation annealing was also applied. Changes in the spectroscopic and lasing properties of erbium ions as a function of implantation fluence of silver were studied with the aim to assess the positive effect of silver as a sensitiser of erbium luminescence. Therefore, absorption spectra in the visible range as well as luminescence spectra in the near-infrared range were measured and partially also the 4I11/2-4I15/2 transition of the erbium ion was studied. The results showed that silver positively influenced luminescence intensity at 1530 nm by increasing it almost three times. The biggest increase was achieved in glass with the highest concentration of erbium. Luminescence lifetime was not significantly influenced by the presence of silver and still remained around 10 ms.

  8. Lithium nephrotoxicity.

    PubMed

    Azab, Abed N; Shnaider, Alla; Osher, Yamima; Wang, Dana; Bersudsky, Yuly; Belmaker, R H

    2015-12-01

    Reports of toxic effects on the kidney of lithium treatment emerged very soon after lithium therapy was introduced. Lithium-induced nephrogenic diabetes insipidus is usually self-limiting or not clinically dangerous. Some reports of irreversible chronic kidney disease and renal failure were difficult to attribute to lithium treatment since chronic kidney disease and renal failure exist in the population at large. In recent years, large-scale epidemiological studies have convincingly shown that lithium treatment elevates the risk of chronic kidney disease and renal failure. Most patients do not experience renal side effects. The most common side effect of polyuria only weakly predicts increasing creatinine or reduced kidney function. Among those patients who do experience decrease in creatinine clearance, some may require continuation of lithium treatment even as their creatinine increases. Other patients may be able to switch to a different mood stabilizer medication, but kidney function may continue to deteriorate even after lithium cessation. Most, but not all, evidence today recommends using a lower lithium plasma level target for long-term maintenance and thereby reducing risks of severe nephrotoxicity. PMID:26043842

  9. Nonlinear optical responses of erbium-doped YAG ceramics

    NASA Astrophysics Data System (ADS)

    Sun, Wangliang; Yi, Jun; Miao, Lili; Li, Jiang; Xie, Tengfei; Zhao, Chujun; Pan, Yubai; Wen, Shuangchun

    2016-07-01

    By performing the Z-scan measurements with ultrafast femtosecond laser centered at 800 nm wavelength, we can unambiguously distinguish the real and imaginary part of the third-order optical nonlinearity of the erbium-doped YAG ceramics. The reverse saturable absorption of the erbium-doped YAG ceramics has been observed experimentally, and the nonlinear refractive index of the ceramics is estimated to be about 10-21 m2/W. The experimental results may provide design guidelines for the high power laser design and its applications.

  10. Radiation-resistant erbium-doped silica fibre

    SciTech Connect

    Zotov, K V; Likhachev, M E; Tomashuk, A L; Bubnov, M M; Yashkov, M V; Gur'yanov, A N

    2007-10-31

    It is shown that the service life of erbium-doped fibres can be increased many times under conditions of an elevated radiation level by loading the fibre glass network with molecular hydrogen. Backdiffusion of hydrogen from the fibre in the process of its operation is virtually excluded for the fibre covered with a hermetic carbon coating. It is shown that this technique of fibre preparation allows one to slow down significantly degradation of the lasing properties of erbium fibres under the conditions characteristic of space applications. (special issue devoted to the 25th anniversary of the a.m. prokhorov general physics institute)

  11. Air Force/Ion Physics hardened lithium doped solar cell development

    NASA Technical Reports Server (NTRS)

    Kirkpatrick, A.; Bartels, F.; Carnes, C.; Ho, J.; Smith, D.

    1971-01-01

    Introduction of lithium by ion implantation eliminates reproducibility and surface problem deficiencies of other introduction techniques. Implantation has been demonstrated to make possible a degree of control over the cell lithium content which has not previously been available. Front barrier development remains to be completed. Successful development of the barrier will make available the freedom to select optimum lithium concentration throughout the cell, including in the vicinity of the junction.

  12. Lithium iodide cardiac pacemakers: initial clinical experience.

    PubMed Central

    Burr, L. H.

    1976-01-01

    A new long-life cardiac pacemaker pulse generator powered by a lithium iodide fuel cell was introduced in Canada in 1973. The compact, hermetically sealed unit is easily implanted and reliable, has excellent patient acceptance and has an anticipated battery life of almost 14 years. Among 105 patients who received a lithium iodide pacemaker, complications occurred in 18. The lithium iodide pacemaker represents a significant advance in pacemaker generator technology and is recommended for long-term cardiac pacing; the manufacturer guarantees the pulse generator for 6 years. Images FIG. 1 PMID:974965

  13. Characterization of the surface changes during the activation process of erbium/erbium oxide for hydrogen storage.

    SciTech Connect

    Zavadil, Kevin Robert; Snow, Clark Sheldon; Ohlhausen, James Anthony; Brumbach, Michael Todd

    2010-10-01

    Erbium is known to effectively load with hydrogen when held at high temperature in a hydrogen atmosphere. To make the storage of hydrogen kinetically feasible, a thermal activation step is required. Activation is a routine practice, but very little is known about the physical, chemical, and/or electronic processes that occur during Activation. This work presents in situ characterization of erbium Activation using variable energy photoelectron spectroscopy at various stages of the Activation process. Modification of the passive surface oxide plays a significant role in Activation. The chemical and electronic changes observed from core-level and valence band spectra will be discussed along with corroborating ion scattering spectroscopy measurements.

  14. Cochlear Implants.

    ERIC Educational Resources Information Center

    Clark, Catherine; Scott, Larry

    This brochure explains what a cochlear implant is, lists the types of individuals with deafness who may be helped by a cochlear implant, describes the process of evaluating people for cochlear implants, discusses the surgical process for implanting the aid, traces the path of sound through the cochlear implant to the brain, notes the costs of…

  15. Influence of Bi on the Er luminescence in yttrium-erbium disilicate thin films

    SciTech Connect

    Scarangella, Adriana; Miritello, Maria; Priolo, Francesco

    2014-09-28

    The influence of bismuth on erbium optical properties at 1.54 μm has been investigated in yttrium-erbium disilicate thin films synthesized by magnetron co-sputtering and implanted with two Bi different doses. The Bi depth distribution and the evolution of its oxidation states after annealing treatments at 1000 °C in two atmospheres, O₂ and N₂, have been investigated. It was found that only in O₂ the Bi³⁺ valence state is prevalent, thanks to the enhanced Bi mobility in the oxidizing ambient, as demonstrated by Rutherford backscattering spectrometry. At lower Bi content, although the formation of Bi⁰ metallic nanoparticles that are deleterious non radiative channels for Er luminescence, efficient energy transfer from Bi to Er has been obtained only in O₂. It is due to the excitation of ultraviolet broad Bi₃⁺ absorption band and the energy transfer to Er ions. We have evaluated that in this case, Er effective excitation cross section increased by a factor of 5 in respect with the one for direct Er absorption at 488 nm. At higher Bi dose, this mechanism is absent, but an increased Er optical efficiency at 1.54 μm has been observed under resonant excitation. It is due to the contribution of a fraction of Er ions having an increased lifetime. This phenomenon is associated with the formation of Bi agglomerates, induced at higher Bi doses, which well isolate Er from non-radiative quenching centers. The increased decay time assures higher optical efficiency at 1.54 μm.

  16. Erbium-doped slot waveguides containing size-controlled silicon nanocrystals

    SciTech Connect

    Hoffmann, R.; Beyer, J. Heitmann, J.; Klemm, V.; Rafaja, D.; Johnson, B. C.; McCallum, J. C.

    2015-04-28

    Silicon based slot waveguides with a slot containing Si nanocrystals (Si-nc) and Erbium ions (Er{sup 3+}) inside a silica matrix were prepared using sputter deposition and low-energy ion implantation. This sequence enabled independent optimization of nanocrystal formation and Er{sup 3+} incorporation parameters. Using a superlattice approach, the size of the Si-nc inside the slot could be controlled and optimized for maximum Er{sup 3+} luminescence yield at 1.54 μm. Er{sup 3+} is found to be efficiently pumped by Si-nc of sizes around 3 to 4 nm. Increasing Er{sup 3+} photoluminescence at 1.54 μm with increasing post-implantation annealing temperatures up to 1000 °C is attributed to annealing of matrix or Si-nc interface defects mainly. Additionally, a dependence of the Er{sup 3+} luminescence intensity on both the excitation and emission linear polarization orientation is shown, which demonstrates efficient field enhancement in sputtered slot waveguide structures.

  17. Oxygen-impurity interactions in crystalline silicon: The cases of aluminum and erbium

    NASA Astrophysics Data System (ADS)

    Rimini, E.; La Ferla, A.; Galvagno, G.; Coffa, S.; Franzò, G.; Priolo, F.

    1997-01-01

    Impurities such as oxygen and carbon have a strong influence on the electrical and optical behaviour of other species introduced in Si. The influence can be either beneficial or detrimental according to the considered case. Two different examples are discussed in the present paper. The electrical activity of ion implanted Al, the fastest diffusing p-type dopant, amounts to a few percent of the fluence in Czochralski wafers while is practically unity in epitaxial or float-zone wafers, having a low content of dissolved oxygen. This behaviour is accounted for in terms of AlO inactive complexes whose formation is enhanced by defects. Good activation and deep junctions can be obtained by avoiding the simultaneous presence of O and defects. Erbium ions introduced by ion implantation in Si are optically active with an emission at 1.54 μm. The luminescence, however, strongly quenches with temperature and room temperature emission cannot be achieved. The co-introduction of Er and O, with the subsequent formation of ErO complexes in Si, strongly reduces this temperature quenching and room temperature light emission can be easily achieved. These two cases are presented and possible applications discussed.

  18. Discovery of dysprosium, holmium, erbium, thulium, and ytterbium isotopes

    SciTech Connect

    Fry, C.; Thoennessen, M.

    2013-09-15

    Currently, thirty-one dysprosium, thirty-two holmium, thirty-two erbium, thirty-three thulium, and thirty-one ytterbium isotopes have been observed and the discovery of these isotopes is described here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  19. Preparation, fluorescence spectroscopy, and AFM analysis of erbium oxide nanocolloid

    NASA Astrophysics Data System (ADS)

    Patel, Darayas; Vance, Calvin; King, Newton; Jessup, Malcolm; Sarkisov, Sergey

    2009-02-01

    Nanocolloids of compounds containing fluorescent rare earth ions have recently attracted significant attention as agents for biolabeling, bioimaging, bio- and chemical sensing, and other applications. Erbium oxide nanocolloids have been prepared for the first time in water and gammabutyrolactone. Optical dynamic scatterometry and atomic force microscopy determined an average size (average mean height) of erbium oxide nanoparticles to be 10-11 nm. Prominent optical absorption peaks of the nanocolloids at 442.5 nm, 450.0 nm, 487.2 nm (strong), 492.0 nm, 523.0 nm (strong), 541.6 nm, 548.6 nm, 652.6 nm, and 665.7 nm (strong) can be attributed to erbium ions hosted within nanoparticles. Laser fluorescence spectroscopy of the nanocolloids was conducted using excitations with the lines of argon-ion laser (514 nm, 488 nm, 476 nm, and 458 nm) and 980-nm semiconductor laser. Strong green emission at 571 nm is more likely from transition between 4S3/2 and 4I15/2 levels and relatively weak red emissions from transition between 4I9/2 and 4I15/2 level of erbium was observed at excitation with visible laser radiation 488 nm and 476 nm. The reported nanocolloids thus showed to be good candidates for fluorescent biosensing applications and also as a new lasing filling medium in fiber lasers.

  20. Specific features of erbium ion photoluminescence in structures with amorphous and crystalline silicon nanoclusters in silica matrix

    SciTech Connect

    Dyakov, S. A. Zhigunov, D. M.; Timoshenko, V. Yu.

    2010-04-15

    Photoluminescence properties of the structures of amorphous and crystalline silicon nanoclusters with average sizes no larger than 4 nm in an erbium-doped silicon dioxide matrix were studied. It was found that the photoluminescence lifetime of Er{sup 3+} ions at a wavelength of 1.5 {mu}m decreases from 5.7 to 2.0 ms and from 3.5 to 1.5 ms in samples with amorphous nanoclusters and with nanocrystals, respectively, as the Er{sup 3+} concentration increases from 10{sup 19} to 10{sup 21} cm{sup -3}. The decrease in the erbium photoluminescence lifetime with the ion concentration is attributed to the effects of concentration-related quenching and residual implantation-induced defects. The difference between lifetimes for samples with amorphous and crystalline nanoclusters is interpreted as the effect of different probabilities of energy back transfer from Er{sup 3+} ions to the solid-state matrix in the structures under consideration.

  1. Effect of temperature on the active properties of erbium-doped optical fibres

    NASA Astrophysics Data System (ADS)

    Kotov, L. V.; Ignat'ev, A. D.; Bubnov, M. M.; Likhachev, M. E.

    2016-03-01

    We have studied the effect of heating on the performance of erbium-doped fibre based devices and determined temperaturedependent absorption and emission cross sections of the erbium ion in silica glass. The results demonstrate that heating of fibres in claddingpumped high-power (~100 W) erbium-doped fibre lasers causes no significant decrease in their efficiency. In contrast, superluminescent sources operating in the long-wavelength region (1565 – 1610 nm) are extremely sensitive to temperature changes.

  2. Urbach absorption edge in epitaxial erbium-doped silicon

    SciTech Connect

    Shmagin, V. B. Kudryavtsev, K. E.; Shengurov, D. V.; Krasilnik, Z. F.

    2015-02-07

    We investigate the dependencies of the photocurrent in Si:Er p-n junctions on the energy of the incident photons. The exponential absorption edge (Urbach edge) just below fundamental edge of silicon was observed in the absorption spectra of epitaxial Si:Er layers grown at 400–600 C. It is shown that the introduction of erbium significantly enhances the structural disorder in the silicon crystal which was estimated from the slope of the Urbach edge. We discuss the possible nature of the structural disorder in Si:Er and a new mechanism of erbium excitation, which does not require the presence of deep levels in the band gap of silicon.

  3. Adaptive dynamic FBG interrogation utilising erbium-doped fibre

    NASA Astrophysics Data System (ADS)

    John, R. N.; Read, I.; MacPherson, W. N.

    2013-04-01

    A dynamic fibre Bragg grating interrogation scheme is investigated using two-wave mixing in erbium-doped fibre, capable of adapting to quasistatic strain and temperature drifts. An interference pattern set up in the erbium-doped fibre creates, due to the photorefractive effect, a dynamic grating capable of wavelength demodulating the FBG signal. The presence of a dynamic grating was verified and then dynamic strain signals from a fibre stretcher were measured. The adaptive nature of the technique was successfully demonstrated by heating the FBG while it underwent dynamic straining leading to detection unlike an alternative arrayed waveguide grating system which simultaneously failed detection. Two gratings were then wavelength division multiplexed with the signal grating receiving approximately 30dB greater signal showing that there was little cross talk in the system.

  4. Laser isotope separation of erbium and other isotopes

    DOEpatents

    Haynam, C.A.; Worden, E.F.

    1995-08-22

    Laser isotope separation is accomplished using at least two photoionization pathways of an isotope simultaneously, where each pathway comprises two or more transition steps. This separation method has been applied to the selective photoionization of erbium isotopes, particularly for the enrichment of {sup 167}Er. The hyperfine structure of {sup 167}Er was used to find two three-step photoionization pathways having a common upper energy level. 3 figs.

  5. Laser isotope separation of erbium and other isotopes

    DOEpatents

    Haynam, Christopher A.; Worden, Earl F.

    1995-01-01

    Laser isotope separation is accomplished using at least two photoionization pathways of an isotope simultaneously, where each pathway comprises two or more transition steps. This separation method has been applied to the selective photoionization of erbium isotopes, particularly for the enrichment of .sup.167 Er. The hyperfine structure of .sup.167 Er was used to find two three-step photoionization pathways having a common upper energy level.

  6. Transient photoacoustic effects induced in liquids by pulsed erbium lasers

    NASA Astrophysics Data System (ADS)

    Frenz, Martin; Pratisto, Hans; Ith, Michael; Asshauer, Thomas; Rink, Klaus; Delacretaz, Guy P.; Romano, Valerio; Salathe, Rene-Paul; Weber, Heinz P.

    1994-08-01

    The intense interest in the investigation of erbium laser radiation in medicine is due to the fact that radiation at 3 micrometers is very strongly absorbed by water, which is present in all biological tissue. As a consequence of this high absorption the interaction of pulsed radiation is characterized by an explosive process with a low ablation threshold and a thin coagulation zone along the laser incisions. Erbium lasers, therefore, have a wide field of potential medical applications which become even more attractive with the availability of reliable delivery systems. An interesting situation arises in orthopaedics and angioplasty, where a precise cutting instrument is needed in a liquid environment. For this reason, we experimentally investigated the interaction mechanism of fiber transmitted, pulsed, free-running and Q- switched Erbium:YSGG ((lambda) equals 2.79 micrometers ) and Erbium:YAG ((lambda) equals 2.94 micrometers ) laser radiation with liquid water. The dynamics of the bubble formation and the propagation of shockwaves in water was studied and visualized by flash photography. Acoustic transients of a few hundreds of bars accompanying the ablation process were measured with a needle hydrophone. A clear correlation between the spikes of the laser pulse and those of the pressure signal was observed. Additionally, strong pressure transients were measured after the end of the laser pulse, which could be associated with the collapse of the vapor bubble and further collapses after multiple rebounds. The influence of pulse energy, fiber size and pulse duration on the formation and the amplitude of the pressure waves is demonstrated.

  7. Erbium-doped fiber lasers as deep-sea hydrophones

    NASA Astrophysics Data System (ADS)

    Bagnoli, P. E.; Beverini, N.; Bouhadef, B.; Castorina, E.; Falchini, E.; Falciai, R.; Flaminio, V.; Maccioni, E.; Morganti, M.; Sorrentino, F.; Stefani, F.; Trono, C.

    2006-11-01

    The present work describes the development of a hydrophone prototype for deep-sea acoustic detection. The base-sensitive element is a single-mode erbium-doped fiber laser. The high sensitivity of these sensors makes them particularly suitable for a wide range of deep-sea acoustic applications, including geological and marine mammals surveys and above all as acoustic detectors in under-water telescopes for high-energy neutrinos.

  8. Simplified gain calculation in erbium-doped LiNbO 3 waveguides

    NASA Astrophysics Data System (ADS)

    Kapoor, Amita; Jain, Geetika; Sharma, Enakshi K.

    2007-02-01

    The combination of excellent electro-optical, acousto-optical and non-linear optical properties makes lithium niobate (LiNbO 3) an attractive host material for integrated optical components such as electro-optical modulators, acousto-optically tunable wavelength filters and Bragg gratings. In the last few years Erbium doped LiNbO 3 waveguide optical amplifiers (EDWA's) have attracted increasing interest. The combination of the amplifying properties of erbium with the excellent acousto-optical and electro-optical properties of the waveguide substrate LiNbO 3 allows the development of a whole class of new waveguide devices of higher functionality. The optical gain achievable in Ti:Er:LiNbO 3 waveguides by optical pumping could compensate or even over compensate these scattering, absorption and insertion losses leading to "zero loss" devices with net optical gain. The different types of lasers and amplifiers can be combined with other active and passive devices on the same substrate to form integrated optical circuits (IOC's) for a variety of applications in optical communications, sensing, signal processing and measurement techniques. The analysis of Er-doped diffused channel waveguides is, hence, required for design of amplifying integrated optical circuits in order to optimize the performance of these gain devices. The coupled differential equations, which govern the evolution of, pump power (1484nm), signal power (1485 to 1600nm) and amplified spontaneous emission, involve integrals which depend explicitly on the modal fields at the pump and signal wavelength in the diffused channel waveguide. In general, it is not possible to obtain analytical forms for the modal fields and propagation constant, hence, to obtain them various approximate or numerical methods (BPM, finite difference or finite element) are used. In this paper the modal field profiles obtained by the variational analysis are further approximated to an appropriately chosen Gaussian function, which

  9. The cardiac implantable electronic device power source: evolution and revolution.

    PubMed

    Mond, Harry G; Freitag, Gary

    2014-12-01

    Although the first power source for an implantable pacemaker was a rechargeable nickel-cadmium battery, it was rapidly replaced by an unreliable short-life zinc-mercury cell. This sustained the small pacemaker industry until the early 1970s, when the lithium-iodine cell became the dominant power source for low voltage, microampere current, single- and dual-chamber pacemakers. By the early 2000s, a number of significant advances were occurring with pacemaker technology which necessitated that the power source should now provide milliampere current for data logging, telemetric communication, and programming, as well as powering more complicated pacing devices such as biventricular pacemakers, treatment or prevention of atrial tachyarrhythmias, and the integration of innovative physiologic sensors. Because the current delivery of the lithium-iodine battery was inadequate for these functions, other lithium anode chemistries that can provide medium power were introduced. These include lithium-carbon monofluoride, lithium-manganese dioxide, and lithium-silver vanadium oxide/carbon mono-fluoride hybrids. In the early 1980s, the first implantable defibrillators for high voltage therapy used a lithium-vanadium pentoxide battery. With the introduction of the implantable cardioverter defibrillator, the reliable lithium-silver vanadium oxide became the power source. More recently, because of the demands of biventricular pacing, data logging, and telemetry, lithium-manganese dioxide and the hybrid lithium-silver vanadium oxide/carbon mono-fluoride laminate have also been used. Today all cardiac implantable electronic devices are powered by lithium anode batteries. PMID:25387600

  10. Pressure-dependent resistivity and magnetoresistivity of erbium

    NASA Astrophysics Data System (ADS)

    Ellerby, Mark; McEwen, Keith A.; Bauer, Ernst; Hauser, Robert; Jensen, Jens

    2000-03-01

    A comprehensive resistance study of erbium subjected to a hydrostatic pressure is presented. From the experimental results we derive a p-T phase diagram for the magnetic phases in erbium. In the zero-temperature limit, the conical structure is predicted to transform into the cycloidal one at a pressure of about 1.3 kbar. Experimentally, the transition is found to occur between 1 and 3 kbar at 4.5 K. The experimental results are analyzed in terms of a variational calculation of the resistivity using the model developed for erbium from previous experiments. The theory of Elliott and Wedgwood is utilized in the account of the superzone effects. The analysis indicates that the a-axis resistivity is slightly affected by the superzones. In the c-axis case the superzone effects do not simply scale with the magnetization, but also reflect the 20% change of the ordering wave vector. This occurs between TN and TC at ambient pressure, and at 4.5 K when the pressure is increased from 1 to 3 kbar. It is tentatively proposed that the tilted cycloidal structure exists in Er, just above TC at ambient pressure and in the interval between 1.3 and 9 kbar at zero temperature.

  11. High-performace cladding-pumped erbium-doped fibre laser and amplifier

    SciTech Connect

    Kotov, L V; Likhachev, M E; Bubnov, M M; Medvedkov, O I; Lipatov, D S; Vechkanov, N N; Guryanov, Aleksei N

    2012-05-31

    We report cladding-pumped erbium-doped fibre laser and amplifier configurations. Through fibre design optimisation, we have achieved a record-high laser slope efficiency, 40 % with respect to absorbed pump power ({lambda} = 976 nm), and an output power of 7.5 W. The erbium-doped fibre amplifier efficiency reaches 32 %.

  12. Cochlear Implants

    MedlinePlus

    ... electrodes are inserted. The electronic device at the base of the electrode array is then placed under ... FDA approval for implants The Food and Drug Administration (FDA) regulates cochlear implant devices for both adults ...

  13. Goserelin Implant

    MedlinePlus

    Goserelin implant is used in combination with radiation therapy and other medications to treat localized prostate cancer and is ... treatment of abnormal bleeding of the uterus. Goserelin implant is in a class of medications called gonadotropin- ...

  14. Cochlear Implants

    MedlinePlus

    A cochlear implant is a small, complex electronic device that can help to provide a sense of sound. People who are ... of-hearing can get help from them. The implant consists of two parts. One part sits on ...

  15. Carmustine Implant

    MedlinePlus

    Carmustine implant is used along with surgery and sometimes radiation therapy to treat malignant glioma (a certain type of ... Carmustine implant comes as a small wafer that is placed in the brain by a doctor during surgery to ...

  16. Breast Implants

    MedlinePlus

    ... Updated Safety Information (Consumer Article) FDA Provides Updated Safety Data on Silicone Gel-Filled Breast Implants (Press Announcement) [ARCHIVED] Breast Implant Guidance for Industry (2006) Post Approval Studies Webpage Freedom of Information ...

  17. Cochlear implant

    MedlinePlus

    ... antenna. This part of the implant receives the sound, converts the sound into an electrical signal, and sends it to ... implants allow deaf people to receive and process sounds and speech. However, these devices do not restore ...

  18. Performance analysis of a concatenated erbium-doped fiber amplifier supporting four mode groups

    NASA Astrophysics Data System (ADS)

    Qin, Zujun; Fan, Di; Zhang, Wentao; Xiong, Xianming

    2016-05-01

    An erbium-doped fiber amplifier (EDFA) supporting four mode groups has been theoretically designed by concatenating two sections of erbium-doped fibers (EDFs). Each EDF has a simple erbium doping profile for the purpose of reducing its fabrication complexity. We propose a modified genetic algorithm (GA) to provide detailed investigations on the concatenated amplifier. Both the optimal fiber length and erbium doping radius in each EDF have been found to minimize the gain difference between signal modes. Results show that the parameters of the central-doped EDF have a greater impact on the amplifier performance compared to those of the annular-doped one. We then investigate the influence of the small deviations of the erbium fiber length, doping radius and doping concentration of each EDF from their optimal values upon the amplifier performance, and discuss their design tolerances in obtaining a desirable amplification characteristics.

  19. Lithium in 2012

    USGS Publications Warehouse

    Jaskula, B.W.

    2013-01-01

    In 2012, estimated world lithium consumption was about 28 kt (31,000 st) of lithium contained in minerals and compounds, an 8 percent increase from that of 2011. Estimated U.S. consumption was about 2 kt (2,200 st) of contained lithium, the same as that of 2011. The United States was thought to rank fourth in consumption of lithium and remained the leading importer of lithium carbonate and the leading producer of value-added lithium materials. One company, Rockwood Lithium Inc., produced lithium compounds from domestic brine resources near Silver Peak, NV.

  20. Pyramidal structural defects in erbium silicide thin films

    NASA Astrophysics Data System (ADS)

    Tan, Eu Jin; Bouville, Mathieu; Chi, Dong Zhi; Pey, Kin Leong; Lee, Pooi See; Srolovitz, David J.; Tung, Chih Hang

    2006-01-01

    Pyramidal structural defects, 5-8μm wide, have been discovered in thin films of epitaxial ErSi2-x formed by annealing thin Er films on Si(001) substrates at temperatures of 500-800°C. The formation of these defects is not due to oxidation. We propose that they form as a result of the separation of the silicide film from the substrate and its buckling in order to relieve the compressive, biaxial epitaxial stresses. Silicon can then diffuse through the silicide or along the interface to fully or partially fill the void between the buckled erbium disilicide film and the substrate.

  1. Erbium Doped Fiber Sensor for Ammonia Detection into Water

    NASA Astrophysics Data System (ADS)

    Pérez-Sánchez, G. G.; Pinzón-Escobar, E. F.; Sandoval-Romero, G. E.; Álvarez Chávez, J. A.

    2015-01-01

    The water pollution is a health problem around the world. One of the most common pollutants in water is the Ammonia. Some sensors have been developed for Ammoniac detection even though most of them are not in real time and could be expensive. In this work an Erbium-doped fibre-sensor for Ammonia detection with a mechanical long period fibre grating and a taper in cascade for improving the sensitivity; the detection bandwidth is in the 1550 nm region from 1460 nm to 1640 nm. Output optical spectrum for Ammonia concentrations from 1ml to 5 ml is shown

  2. Erbium-doped fiber amplifier elements for structural analysis sensors

    NASA Technical Reports Server (NTRS)

    Hanna-Hawver, P.; Kamdar, K. D.; Mehta, S.; Nagarajan, S.; Nasta, M. H.; Claus, R. O.

    1992-01-01

    The use of erbium-doped fiber amplifiers (EDFA's) in optical fiber sensor systems for structural analysis is described. EDFA's were developed for primary applications as periodic regenerator amplifiers in long-distance fiber-based communication systems. Their in-line amplification performance also makes them attractive for optical fiber sensor systems which require long effective lengths or the synthesis of special length-dependent signal processing functions. Sensor geometries incorporating EDFA's in recirculating and multiple loop sensors are discussed. Noise and polarization birefringence are also considered, and the experimental development of system components is discussed.

  3. Erbium-doped fiber amplifier elements for structural analysis sensors

    NASA Astrophysics Data System (ADS)

    Hanna-Hawver, P.; Kamdar, K. D.; Mehta, S.; Nagarajan, S.; Nasta, M. H.; Claus, R. O.

    1992-06-01

    The use of erbium-doped fiber amplifiers (EDFA's) in optical fiber sensor systems for structural analysis is described. EDFA's were developed for primary applications as periodic regenerator amplifiers in long-distance fiber-based communication systems. Their in-line amplification performance also makes them attractive for optical fiber sensor systems which require long effective lengths or the synthesis of special length-dependent signal processing functions. Sensor geometries incorporating EDFA's in recirculating and multiple loop sensors are discussed. Noise and polarization birefringence are also considered, and the experimental development of system components is discussed.

  4. Performance and properties of arsenic passivated lithium-titanium disulfide cells

    NASA Technical Reports Server (NTRS)

    Yen, S. P. S.; Shen, D.; Fitzgerald, D.; Vasquez, R. P.; Somoano, R. B.

    1986-01-01

    In order to inhibit chemical degradation associated with the lithium-electrolyte interaction in ambient temperature lithium cells, an attempt was made to synthetically passivate the anode via ion implantation of arsenic. Solvent reduction is reduced although salt reaction with lithium is still present. The performance of the Li-TiS2 cell differs from those with standard electrodes, but further work is necessary to clarify the efficacy of this mode of passivation.

  5. Lithium-associated hyperthyroidism.

    PubMed

    Siyam, Fadi F; Deshmukh, Sanaa; Garcia-Touza, Mariana

    2013-08-01

    Goiters and hypothyroidism are well-known patient complications of the use of lithium for treatment of bipolar disease. However, the occurrence of lithium-induced hyperthyroidism is a more rare event. Many times, the condition can be confused with a flare of mania. Monitoring through serial biochemical measurement of thyroid function is critical in patients taking lithium. Hyperthyroidism induced by lithium is a condition that generally can be controlled medically without the patient having to discontinue lithium therapy, although in some circumstances, discontinuation of lithium therapy may be indicated. We report on a patient case of lithium-associated hyperthyroidism that resolved after discontinuation of the medication. PMID:23948626

  6. Implantable Microimagers

    PubMed Central

    Ng, David C.; Tokuda, Takashi; Shiosaka, Sadao; Tano, Yasuo; Ohta, Jun

    2008-01-01

    Implantable devices such as cardiac pacemakers, drug-delivery systems, and defibrillators have had a tremendous impact on the quality of live for many disabled people. To date, many devices have been developed for implantation into various parts of the human body. In this paper, we focus on devices implanted in the head. In particular, we describe the technologies necessary to create implantable microimagers. Design, fabrication, and implementation issues are discussed vis-à-vis two examples of implantable microimagers; the retinal prosthesis and in vivo neuro-microimager. Testing of these devices in animals verify the use of the microimagers in the implanted state. We believe that further advancement of these devices will lead to the development of a new method for medical and scientific applications.

  7. Toxicity of materials used in the manufacture of lithium batteries

    SciTech Connect

    Archuleta, M.M.

    1994-05-01

    The growing interest in battery systems has led to major advances in high-energy and/or high-power-density lithium batteries. Potential applications for lithium batteries include radio transceivers, portable electronic instrumentation, emergency locator transmitters, night vision devices, human implantable devices, as well as uses in the aerospace and defense programs. With this new technology comes the use of new solvent and electrolyte systems in the research, development, and production of lithium batteries. The goal is to enhance lithium battery technology with the use of non-hazardous materials. Therefore, the toxicity and health hazards associated with exposure to the solvents and electrolytes used in current lithium battery research and development is evaluated and described.

  8. Toxicity of materials used in the manufacture of lithium batteries

    NASA Astrophysics Data System (ADS)

    Archuleta, Melecita M.

    The growing interest in battery systems has led to major advances in high-energy and/or high-power density lithium batteries. Potential applications for lithium batteries include radio transceivers, portable electronic instrumentation, emergency locator transmitters, night vision devices, human implantable devices, as well as uses in the aerospace and defense programs. With this new technology comes the use of new solvent and electrolyte systems in the research, development, and production of lithium batteries. The goal is to enhance lithium battery technology with the use of non-hazardous materials. Therefore, the toxicity and health hazards associated with exposure to the solvents and electrolytes used in current lithium battery research and development is evaluated and described.

  9. High Productivity Implantation ''PARTIAL IMPLANT''

    SciTech Connect

    Hino, Masayoshi; Miyamoto, Naoki; Sakai, Shigeki; Matsumoto, Takao

    2008-11-03

    The patterned ion implantation 'PARTIAL IMPLANT' has been developed as a productivity improvement tool. The Partial Implant can form several different ion dose areas on the wafer surface by controlling the speed of wafer moving and the stepwise rotation of twist axis. The Partial Implant system contains two implant methods. One method is 'DIVIDE PARTIAL IMPLANT', that is aimed at reducing the consumption of the wafer. The Divide Partial Implant evenly divides dose area on one wafer surface into two or three different dose part. Any dose can be selected in each area. So the consumption of the wafer for experimental implantation can be reduced. The second method is 'RING PARTIAL IMPLANT' that is aimed at improving yield by correcting electrical characteristic of devices. The Ring Partial Implant can form concentric ion dose areas. The dose of wafer external area can be selected to be within plus or minus 30% of dose of wafer central area. So the electrical characteristic of devices can be corrected by controlling dose at edge side on the wafer.

  10. Photoluminescence of Erbium-Doped Potassium Tantalate Niobate Polycrystalline

    NASA Astrophysics Data System (ADS)

    Wen, Cheng‑Hung; Chu, Sheng‑Yuan; Shin, Yan‑Yu; Wen, Cheng‑Kuo

    2006-07-01

    In this study, we investigated the luminescence properties of erbium-doped potassium tantalite niobate (KTaxNb1-xO3 or KTN) ceramics, which were prepared by the conventional solid-state reaction synthesis method. In this work, we studied the relationships of the crystal structure, and Raman and photoluminescence (PL) spectra with the tantalum concentration, respectively. The experiments showed that the tantalum dopants modified the intensity of the green, red and near-infrared emission bands. The experiments also showed a blue shift for the 2 mol % erbium doped KTN samples with different tantalum compositions. Doping Ta not only led to the change in PL intensity but also in spectral shapes. The PL spectra showed the splitting peaks for the samples with low Ta compositions. Then these peaks combined and broadened as Ta concentration increase. When Ta was substituted for Nb completely, the luminescence intensity of the green emission band had an increase of approximately about one order of magnitude, which was because of the absence of the first-order phonon relaxation in the high-Ta-concentration samples.

  11. Harmonically mode-locked erbium-doped waveguide laser

    NASA Astrophysics Data System (ADS)

    Fanto, Michael L.; Malowicki, John E.; Bussjager, Rebecca J.; Johns, Steven T.; Vettese, Elizabeth K.; Hayduk, Michael J.

    2004-08-01

    The generation of ultrastable picosecond pulses in the 1550 nm range is required for numerous applications that include photonic analog-to-digital converter systems and high-bit rate optical communication systems. Mode-locked erbium-doped fiber ring lasers (EDFLs) are typically used to generate pulses at this wavelength. In addition to timing stability and output power, the physical size of the laser cavity is of primary importance to the Air Force. The length of the erbium (Er)-doped fiber used as the gain medium may be on the order of meters or even tens of meters which adds complexity to packaging. However, with the recent advancements in the production of multi-component glasses, higher doping concentrations can be achieved as compared to silicate glasses. Even more recent is the introduction of Er-doped multi-component glass waveguides, thus allowing the overall footprint of the gain medium to be reduced. We have constructed a novel harmonically mode-locked fiber ring laser using the Er-doped multi-component glass waveguide as the gain medium. The performance characteristics of this Er-doped waveguide laser (EDWL) including pulse width, spectral width, harmonic suppression, optical output power, laser stability and single sideband residual phase noise will be discussed in this paper.

  12. Evidence of two erbium sites in standard aluminosilicate glass for EDFA.

    PubMed

    Peretti, R; Jurdyc, A M; Jacquier, B; Burov, E; Pastouret, A

    2010-09-27

    Site distributions of Er(3+)-doped aluminosilicate preforms of standard EDFA were studied by the low temperature Resonant Fluorescence Line Narrowing (RFLN) spectroscopy. Two erbium concentration samples with the same glass base were investigated. At very low erbium concentration, two classes of sites were identified, related to the number of AlO(6) octahedral linked by two oxygen edge-sharing to Er(3+) in the coordination sphere. As erbium concentration is increased, the high AlO(6) coordinated class of sites is smeared out by the optical response of the one AlO(6) coordinated class of sites. PMID:20940961

  13. Numerical simulation and optimization of passively q-switched erbium microchip lasers

    NASA Astrophysics Data System (ADS)

    Belghachem, Nabil; Mlynczak, Jarslow

    2015-08-01

    In this article we present a procedure of optimization of passively q-switched erbium microchip lasers. The procedure is based on the rate equation model, validated by comparing the numerical results to the experimental results of pulse generation in different types of erbium/ytterbium glass microchips q-switched by Co2+ : MgAl2O4 saturable absorber. Some Degnan’s optimization limitations in case of microchip lasers were also shown and the reabsorbtion cross section of erbium glass was also estimated.

  14. [Implant allergies].

    PubMed

    Thomas, P; Thomsen, M

    2010-03-01

    An increasing number of patients receive and benefit from osteosynthesis materials or artificial joint replacement. The most common complications are mechanical problems or infection. Metals like nickel, chromium and cobalt as well as bone cement components like acrylates and gentamicin are potential contact allergens which can cause intolerance reactions to implants. Eczema, delayed wound/bone healing, recurrent effusions, pain and implant loosening all have been described as manifestation of implant allergy. In contrast to the high incidence of cutaneous metal allergy, allergies associated with implants are rare. Diagnosis of metal implant allergy is still difficult. Thus differential diagnoses--in particular infection--have to be excluded and a combined approach of allergologic diagnostics by patch test and histopathology of peri-implant tissue is recommended. It is still unknown which conditions induce allergic sensitization to implants or trigger peri-implant allergic reactions in the case of preexisting cutaneous metal allergy. Despite the risk of developing complications being unclear, titanium based osteosynthesis materials are recommended for metal allergic patients and the use of metal-metal couplings in arthroplasty is not recommended for such patients. If the regular CoCr-polyethylene articulation is employed, the patient should give informed written consent. PMID:20204719

  15. Generalized rate-equation analysis of excitation exchange between silicon nanoclusters and erbium ions

    SciTech Connect

    Kenyon, A. J.; Wojdak, M.; Ahmad, I.; Loh, W. H.; Oton, C. J.

    2008-01-15

    We discuss the use of rate equations to analyze the sensitization of erbium luminescence by silicon nanoclusters. In applying the general form of second-order coupled rate-equations to the Si nanocluster-erbium system, we find that the photoluminescence dynamics cannot be described using a simple rate equation model. Both rise and fall times exhibit a stretched exponential behavior, which we propose arises from a combination of a strongly distance-dependent nanocluster-erbium interaction, along with the finite size distribution and indirect band gap of the silicon nanoclusters. Furthermore, the low fraction of erbium ions that can be excited nonresonantly is a result of the small number of ions coupled to nanoclusters.

  16. Radiation-resistant erbium-doped-nanoparticles optical fiber for space applications.

    PubMed

    Thomas, Jérémie; Myara, Mikhaël; Troussellier, Laurent; Burov, Ekaterina; Pastouret, Alain; Boivin, David; Mélin, Gilles; Gilard, Olivier; Sotom, Michel; Signoret, Philippe

    2012-01-30

    We demonstrate for the first time a radiation-resistant Erbium-Doped Fiber exhibiting performances that can fill the requirements of Erbium-Doped Fiber Amplifiers for space applications. This is based on an Aluminum co-doping atom reduction enabled by Nanoparticules Doping-Process. For this purpose, we developed several fibers containing very different erbium and aluminum concentrations, and tested them in the same optical amplifier configuration. This work allows to bring to the fore a highly radiation resistant Erbium-doped pure silica optical fiber exhibiting a low quenching level. This result is an important step as the EDFA is increasingly recognized as an enabling technology for the extensive use of photonic sub-systems in future satellites. PMID:22330481

  17. Long lifetime, high density single-crystal erbium compound nanowires as a high optical gain material

    NASA Astrophysics Data System (ADS)

    Yin, Leijun; Ning, Hao; Turkdogan, Sunay; Liu, Zhicheng; Nichols, Patricia L.; Ning, C. Z.

    2012-06-01

    Erbium-containing materials of long lifetime and high Er density are important for achieving strong luminescence and high optical gain in compact integrated photonics devices. We have systematically studied the lifetime and crystal quality as a function of growth conditions for an erbium compound that we recently reported, erbium chloride silicate (ECS). The lifetime for the best quality ECS nanowires can be as long as 540 μs, the longest for high-density Er-materials, representing a lifetime-density product as high as 8.7 × 1018 s cm-3. Such high density, long lifetime erbium materials can find many interesting applications such as compact lasers or amplifiers.

  18. Resonantly photo-pumped nickel-like erbium X-ray laser

    DOEpatents

    Nilsen, Joseph

    1990-01-01

    A resonantly photo-pumped X-ray laser (10) that enhances the gain of seve laser lines that also lase because of collisional excitations and recombination processes, is described. The laser comprises an aluminum (12) and erbium (14) foil combination (16) that is driven by two beams (18, 20) of intense line focused (22, 24) optical laser radiation. Ground state nickel-like erbium ions (34) are resonantly photo-pumped by line emission from hydrogen-like aluminum ions (32).

  19. Molten salt lithium cells

    DOEpatents

    Raistrick, Ian D.; Poris, Jaime; Huggins, Robert A.

    1983-01-01

    Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell (10) which may be operated at temperatures between about 100.degree.-170.degree. C. Cell (10) comprises an electrolyte (16), which preferably includes lithium nitrate, and a lithium or lithium alloy electrode (12).

  20. Molten salt lithium cells

    DOEpatents

    Raistrick, I.D.; Poris, J.; Huggins, R.A.

    1980-07-18

    Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400 to 500/sup 0/C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell which may be operated at temperatures between about 100 to 170/sup 0/C. The cell is comprised of an electrolyte, which preferably includes lithium nitrate, and a lithium or lithium alloy electrode.

  1. Molten salt lithium cells

    DOEpatents

    Raistrick, Ian D.; Poris, Jaime; Huggins, Robert A.

    1982-02-09

    Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell (10) which may be operated at temperatures between about 100.degree.-170.degree. C. Cell (10) comprises an electrolyte (16), which preferably includes lithium nitrate, and a lithium or lithium alloy electrode (12).

  2. An Erbium Quantum Gas Microscope with a Reflective Objective

    NASA Astrophysics Data System (ADS)

    Krahn, Aaron; Phelps, Gregory; Hebert, Anne; Dickerson, Susannah; Greiner, Markus; Erbium Lab Team

    2016-05-01

    Dipolar atoms present an exciting opportunity to extend previous quantum gas microscope (QGM) experiments to more complex systems influenced by long range, anisotropic interactions. We present on current progress toward the construction of a QGM for ultracold Erbium atoms in an optical lattice, including the development of a novel imaging system for single-site resolution. While most QGMs until now have typically utilized a high numerical aperture microscope objective, we discuss a reflective mirror alternative that offers an equally high NA (.9-.95), a comparable field of view (34 micrometers radial), and a larger working distance (25 millimeters) that keeps the atoms far from any surfaces. By operating in a Schmidt telescope configuration, this imaging system is well-suited both for collecting 401 nm imaging fluorescence and for the creation of an expandable lattice with a variety of associated lattice geometries.

  3. Analytical interactomic potential for a molybdenum–erbium system

    NASA Astrophysics Data System (ADS)

    Sun, Q. Q.; Yang, T. L.; Yang, L.; Peng, S. M.; Long, X. G.; Zhou, X. S.; Zu, X. T.; Gao, F.

    2016-05-01

    Analytical interatomic potentials of a molybdenum–erbium (Mo–Er) system are developed based on a Tersoff–Brenner-type form. The potentials well describes the bulk and defect properties of bcc Mo, including lattice parameter, cohesive energy, elastic constants, formation energies of point defects, surface energies and melting point. The adsorption behavior of Er on a Mo (1 1 0) surface is studied using ab initio calculations based on the density functional theory, which is used to fit the interatomic potential of a Mo–Er interaction. The growth mechanism of the Er film on a Mo substrate is investigated using the present potentials. The simulation results show that the microstructures and morphologies of Er films are sensitive to substrate temperatures. Columnar grains of hexagonal close-packed Er parallel to a Mo (1 1 0) surface are observed and the grain sizes increase with increasing substrate temperature.

  4. Dual-kind Q-switching of erbium fiber laser

    SciTech Connect

    Barmenkov, Yuri O. Kir'yanov, Alexander V.; Cruz, Jose L.; Andres, Miguel V.

    2014-03-03

    Two different regimes of Q-switching in the same implementation of an actively Q-switched erbium-doped fiber laser are demonstrated. Depending on the active fiber length and repetition rate of an intracavity Q-cell (acousto-optic modulator), the laser operates either in the regime of common, rather long and low-power, pulses composed of several sub-pulses or in the one of very short and powerful stimulated Brillouin scattering-induced pulses. The basic physical reason of the laser system to oscillate in one of these two regimes is the existence or absence of CW narrow-line “bad-cavity” lasing in the intervals when the Q-cell is blocked.

  5. Enhanced near-infrared-luminescence in an erbium tetrafluoroterephthalate framework.

    PubMed

    Chen, Banglin; Yang, Yu; Zapata, Fatima; Qian, Guodong; Luo, Yongshi; Zhang, Jiahua; Lobkovsky, Emil B

    2006-10-30

    Two erbium-organic frameworks Er2(BDC)3(DMF)2(H2O)2.H2O (1) and Er2(BDC-F4)3(DMF)(H2O).DMF (2) (BDC = 1,4-benzenedicarboxylate; BDC-F(4) = 2,3,5,6-tetrafluoro-1,4-benzenedicarboxylate or tetrafluoroterephthalate; DMF = dimethylformamide) have been synthesized and structurally characterized. Studies on thermal gravimetric analysis and the spectroscopic and luminescent properties of 1, 2, and their desolvated solid Er2(BDC)3 (1a) and partially desolvated solid Er2(BDC-F4)3(DMF).DMF (2a) indicate that fluorination can significantly improve the luminescence intensity of the Er ions by reducing the fluorescence quenching effect of the vibrational C-H bond; thus, the near-IR-luminescence intensity of 2a is 3 times higher than that of 1a. PMID:17054346

  6. Microwave multimode memory with an erbium spin ensemble

    NASA Astrophysics Data System (ADS)

    Probst, S.; Rotzinger, H.; Ustinov, A. V.; Bushev, P. A.

    2015-07-01

    Hybrid quantum systems combining circuit QED with spin-doped solids are an attractive platform for distributed quantum information processing. There, the magnetic ions serve as coherent memory elements and reversible conversion elements of microwave to optical qubits. Among many possible spin-doped solids, erbium ions offer the unique opportunity for a coherent conversion of microwave photons into the telecom C band at 1.54 μ m employed for long distance communication. In our work, we perform a time-resolved electron spin resonance study of an Er3 +:Y2SiO5 spin ensemble at millidegrees Kelvin temperatures and demonstrate multimode storage and retrieval of up to 16 coherent microwave pulses. The memory efficiency is measured to be 10-4 at a coherence time of T2=5.6 μ s . We observe a saturation of the spin coherence time below 50 mK due to full polarization of the surrounding electronic spin bath.

  7. Passive mode locking in erbium-ytterbium fiber lasers

    NASA Astrophysics Data System (ADS)

    Thai, Serey; Hayduk, Michael J.

    1999-11-01

    A novel mode-locked erbium-ytterbium fiber laser operating at 1550 nm using multiple quantum well (MQW) saturable absorbers was developed. The laser was constructed in a Fabry-Perot configuration using a fiber Bragg grating as a front reflector and a fiber Bragg grating output as a back reflector of the laser cavity. The passive mode-locking element placed inside the laser cavity is a 75 period InGaAs/InAlAs MQW saturable absorber grown lattice matched on an InP substrate. The output of the laser was taken through the other available port of a wavelength-division demultiplexer. The laser produced mode-locked output pulse trains at 16.67-MHz repetition rate and 10 mW of average output power.

  8. Stable dual-wavelength erbium fiber laser for temperature measurements

    NASA Astrophysics Data System (ADS)

    Diaz, S.; Lopez-Amo, M.

    2015-09-01

    In this work, a new stable dual-wavelength erbium fiber ring laser is proposed and experimentally demonstrated. This configuration is made by creating two symmetrical laser cavities with similar optical power. This topology allows the performance of two laser emission lines in single-longitudinal mode and with a power instability lower than 0.23 dB, and an optical signal-to-noise ratio higher than 40 dB for all the emitted wavelengths. The sensing capability of the FBGs enables this source to be also used as sensor-network multiplexing scheme. The system offers a better stability and higher optical signal to noise ratios than similar configurations.

  9. Combination of erbium and holmium laser radiation for tissue ablation

    NASA Astrophysics Data System (ADS)

    Pratisto, Hans S.; Frenz, Martin; Koenz, Flurin; Altermatt, Hans J.; Weber, Heinz P.

    1996-05-01

    Erbium lasers emitting at 2.94 micrometers and holmium lasers emitting at 2.1 micrometers are interesting tools for cutting, drilling, smoothing and welding of water containing tissues. The high absorption coefficient of water at these wavelengths leads to their good ablation efficiency with controlled thermally altered zones around the ablation sites. Combination of pulses with both wavelengths transmitted through one fiber were used to perform incisions in soft tissue and impacts in bone disks. Histological results and scanning electron microscope evaluations reveal the strong influence of the absorption coefficient on tissue effects, especially on the ablation efficiency and the zone of thermally damaged tissue. It is demonstrated that the combination of high ablation rates and deep coagulation zones can be achieved. The results indicate that this laser system can be considered as a first step towards a multi-functional medical instrument.

  10. Site-selective measurement of relaxation properties at 980 nm in Er^{3+}-doped congruent and stoichiometric lithium niobate crystals

    NASA Astrophysics Data System (ADS)

    Mandula, Gabor; Kis, Zsolt; Kovacs, Laszlo; Szaller, Zsuzsanna; Krampf, Andreas

    2016-04-01

    A pump-probe-type saturation spectroscopic experiment has been performed at 980 nm to measure the homogeneous linewidth of the ^4I_{11/2}-^4I_{15/2} transition and the lifetime of the ^4I_{11/2} state of erbium embedded into lithium niobate single crystals. There are several non-equivalent Er^{3+}_{Li^+}-V_{Li^+} sites with differently oriented defect structure for charge compensation. These non-equivalent centers differ in their transition energies. Hence, our measurements have been done at two nearby frequencies, addressing groups of erbium ions located at non-equivalent sites. The results are compared with lifetime calculations and measurements found in the literature and with the predictions of our simple model calculation.

  11. Site-selective spectroscopy of the solid-state defect chemistry in erbium-doped barium titanate.

    PubMed

    Bak, John D; Wright, John C

    2005-10-01

    Erbium-doped barium titanate crystals were studied by laser-induced fluorescence spectroscopy. Thirteen spectroscopically distinct erbium ion sites were found. The relative concentrations of the different sites changed as a function of the crystal and its preparation and treatment. One major site was present in all crystals. The site distribution was changed either by growing codoped crystals with donor (La3+) and acceptor (Sc3+) ions or by changing the temperature and partial pressure of the oxygen in the annealing atmosphere. Equilibrium calculations were done to simulate the defect distributions that result from the charge compensation of the erbium ions. Comparison with the observed dependence of the site spectral intensities indicated that the erbium enters the lattice on barium sites. We assigned the dominant site to an erbium ion on a barium site that is locally compensated by a barium vacancy, whereas the other lower-intensity sites corresponded to erbium ions that are locally compensated by an electron and a more complex center of an erbium, a barium vacancy, and a hole. The spectra of one sample showed that its defects were different and were characteristic of a sample that had not equilibrated. The new sites in this sample were assigned to erbium entering the lattice on a titanium site, which was then locally compensated by an oxygen vacancy or a hole. Heating equilibrated the sample and changed the erbium to a barium site. PMID:16853368

  12. Goserelin Implant

    MedlinePlus

    ... which the type of tissue that lines the uterus [womb] grows in other areas of the body ... with the treatment of abnormal bleeding of the uterus. Goserelin implant is in a class of medications ...

  13. Ion Implantation

    NASA Astrophysics Data System (ADS)

    Langouche, G.; Yoshida, Y.

    In this tutorial we describe the basic principles of the ion implantation technique and we demonstrate that emission Mössbauer spectroscopy is an extremely powerful technique to investigate the atomic and electronic configuration around implanted atoms. The physics of dilute atoms in materials, the final lattice sites and their chemical state as well as diffusion phenomena can be studied. We focus on the latest developments of implantation Mössbauer spectroscopy, where three accelerator facilities, i.e., Hahn-Meitner Institute Berlin, ISOLDE-CERN and RIKEN, have intensively been used for materials research in in-beam and on-line Mössbauer experiments immediately after implantation of the nuclear probes.

  14. Dental Implants

    MedlinePlus Videos and Cool Tools

    ... facts so you can make an informed decision as to whether dental implants are right for your ... the jaw bone. It’s obviously not the same as the original connection , but functions just the same. ...

  15. Cochlear Implants

    MedlinePlus

    ... additional visits are needed for activating, adjusting, and programming the various electrodes that have been implanted. Also, ... to the center for checkups once the final programming is made to the speech processor. Both children ...

  16. Histrelin Implant

    MedlinePlus

    ... bone growth and development of sexual characteristics) in girls usually between 2 and 8 years of age ... MRI scans (radiology techniques designed to show the images of body structures) to find the implant when ...

  17. Lasers in minimally invasive periodontal and peri-implant therapy.

    PubMed

    Mizutani, Koji; Aoki, Akira; Coluzzi, Donald; Yukna, Raymond; Wang, Chen-Ying; Pavlic, Verica; Izumi, Yuichi

    2016-06-01

    Laser therapy has the potential to be an effective, minimally invasive procedure in periodontal therapy. The aim of the present review was to survey the relevant literature on the clinical application of lasers as a minimally invasive treatment for periodontitis and peri-implant disease. Currently, there are a large number of published clinical studies and case reports that evaluate the adjunctive use of diode, carbon dioxide, neodymium-doped yttrium aluminium garnet (Nd:YAG), erbium-doped yttrium aluminium garnet (Er:YAG) and erbium, chromium-doped: yttrium, scandium, gallium, garnet (Er,Cr:YSGG) lasers or antimicrobial photodynamic therapy for nonsurgical and minimally invasive surgical treatment of periodontal pockets. These procedures are expected not only to control inflammation but also to provide biostimulation effects with photonic energy. Recent meta-analyses did not show statistically significant differences in pocket reduction and clinical attachment gain compared with mechanical debridement alone, although limited positive effects of adjunctive laser therapy were reported. At present, systematic literature approaches suggest that more evidence-based studies need to be performed to support the integration of various laser therapies into the treatment of periodontal and peri-implant diseases. The disparity between previous statistical analyses and individual successful clinical outcomes of laser applications might reveal the necessity of developing optimal laser-treatment modalities of different wavelengths and better-defined indications for each protocol. PMID:27045437

  18. Plasma source ion implantation to increase the adhesion of subsequently deposited coatings

    SciTech Connect

    Wood, B.P.; Walter, K.C.; Taylor, T.N.

    1997-10-01

    In Plasma Source Ion Implantation (PSII) an object is placed in a plasma and pulse biased to a high negative potential, so as to implant the plasma ions into the surface of the object. Although ion implantation, by itself, can yield desirable surface modification, it is even more useful as a method of creating a functionally graded interface between the substrate material and a subsequently deposited coating, which may be produced by altering operating conditions on the same plasma source. Although this interfacial region is very thin - as little as 20 nm - it can greatly increase the adhesion of the deposited coatings. We present here a description of this process, and compare a simulation of the graded interface with an XPS depth profile of the interfacial region for erbium metal implanted into steel.

  19. Thermal properties of holmium-implanted gold films for a neutrino mass experiment with cryogenic microcalorimeters.

    PubMed

    Prasai, K; Alves, E; Bagliani, D; Basak Yanardag, S; Biasotti, M; Galeazzi, M; Gatti, F; Ribeiro Gomes, M; Rocha, J; Uprety, Y

    2013-08-01

    In a microcalorimetric neutrino mass experiment using the radioactive decay of (163)Ho, the radioactive material must be fully embedded in the microcalorimeter absorber. One option that is being investigated is to implant the radioactive isotope into a gold absorber, as gold is successfully used in other applications. However, knowing the thermal properties at the working temperature of microcalorimeters is critical for choosing the absorber material and for optimizing the detector performance. In particular, it is paramount to understand if implanting the radioactive material in gold changes its heat capacity. We used a bolometric technique to measure the heat capacity of gold films, implanted with various concentrations of holmium and erbium (a byproduct of the (163)Ho fabrication), in the temperature range 70 mK-300 mK. Our results show that the specific heat capacity of the gold films is not affected by the implant, making this a viable option for a future microcalorimeter holmium experiment. PMID:24007077

  20. Thermal properties of holmium-implanted gold films for a neutrino mass experiment with cryogenic microcalorimeters

    SciTech Connect

    Prasai, K.; Yanardag, S. Basak; Galeazzi, M.; Uprety, Y.; Alves, E.; Rocha, J.; Bagliani, D.; Biasotti, M.; Gatti, F.; Gomes, M. Ribeiro

    2013-08-15

    In a microcalorimetric neutrino mass experiment using the radioactive decay of {sup 163}Ho, the radioactive material must be fully embedded in the microcalorimeter absorber. One option that is being investigated is to implant the radioactive isotope into a gold absorber, as gold is successfully used in other applications. However, knowing the thermal properties at the working temperature of microcalorimeters is critical for choosing the absorber material and for optimizing the detector performance. In particular, it is paramount to understand if implanting the radioactive material in gold changes its heat capacity. We used a bolometric technique to measure the heat capacity of gold films, implanted with various concentrations of holmium and erbium (a byproduct of the {sup 163}Ho fabrication), in the temperature range 70 mK–300 mK. Our results show that the specific heat capacity of the gold films is not affected by the implant, making this a viable option for a future microcalorimeter holmium experiment.

  1. Combination of fiber-guided pulsed erbium and holmium laser radiation for tissue ablation under water

    NASA Astrophysics Data System (ADS)

    Pratisto, Hans; Frenz, Martin; Ith, Michael; Altermatt, Hans J.; Jansen, E. Duco; Weber, Heinz P.

    1996-07-01

    Because of the high absorption of near-infrared laser radiation in biological tissue, erbium lasers and holmium lasers emitting at 3 and 2 mu m, respectively, have been proven to have optimal qualities for cutting or welding and coagulating tissue. To combine the advantages of both wavelengths, we realized a multiwavelength laser system by simultaneously guiding erbium and holmium laser radiation by means of a single zirconium fluoride (ZrF4) fiber. Laser-induced channel formation in water and poly(acrylamide) gel was investigated by the use of a time-resolved flash-photography setup, while pressure transients were recorded simultaneously with a needle hydrophone. The shapes and depths of vapor channels produced in water and in a submerged gel after single erbium and after combination erbium-holmium radiation delivered by means of a 400- mu m ZrF4 fiber were measured. Transmission measurements were performed to determine the amount of pulse energy available for tissue ablation. The effects of laser wavelength and the delay time between pulses of different wavelengths on the photomechanical and photothermal responses of meniscal tissue were evaluated in vitro by the use of histology. It was observed that the use of a short (200- mu s, 100-mJ) holmium laser pulse as a prepulse to generate a vapor bubble through which the ablating erbium laser pulse can be transmitted (delay time, 100 mu s) increases the cutting depth in meniscus from 450 to 1120 mu m as compared with the depth following a single erbium pulse. The results indicate that a combination of erbium and holmium laser radiation precisely and efficiently cuts tissue under water with 20-50- mu m collateral tissue damage. wave, cavitation, channel formation, infrared-fiber-delivery system, tissue damage, cartilage.

  2. Lithium use in batteries

    USGS Publications Warehouse

    Goonan, Thomas G.

    2012-01-01

    Lithium has a number of uses but one of the most valuable is as a component of high energy-density rechargeable lithium-ion batteries. Because of concerns over carbon dioxide footprint and increasing hydrocarbon fuel cost (reduced supply), lithium may become even more important in large batteries for powering all-electric and hybrid vehicles. It would take 1.4 to 3.0 kilograms of lithium equivalent (7.5 to 16.0 kilograms of lithium carbonate) to support a 40-mile trip in an electric vehicle before requiring recharge. This could create a large demand for lithium. Estimates of future lithium demand vary, based on numerous variables. Some of those variables include the potential for recycling, widespread public acceptance of electric vehicles, or the possibility of incentives for converting to lithium-ion-powered engines. Increased electric usage could cause electricity prices to increase. Because of reduced demand, hydrocarbon fuel prices would likely decrease, making hydrocarbon fuel more desirable. In 2009, 13 percent of worldwide lithium reserves, expressed in terms of contained lithium, were reported to be within hard rock mineral deposits, and 87 percent, within brine deposits. Most of the lithium recovered from brine came from Chile, with smaller amounts from China, Argentina, and the United States. Chile also has lithium mineral reserves, as does Australia. Another source of lithium is from recycled batteries. When lithium-ion batteries begin to power vehicles, it is expected that battery recycling rates will increase because vehicle battery recycling systems can be used to produce new lithium-ion batteries.

  3. Raman and Fluorescence Study of Erbium-Doped Laser-Induced Crystals-in-Glass

    NASA Astrophysics Data System (ADS)

    Knorr, Brian; Veenhuizen, Keith; Stone, Adam; Jain, Himanshu; Dierolf, Volkmar

    Laser induced crystallization of glasses is a spatially selective process which has the potential to produce photonic integrated circuits in a glass matrix. Low temperature Combined Excitation Emission Spectroscopy in Er:LaBGeO5 show that erbium incorporates at predominantly one majority site in both glass-ceramics and laser-induced crystals-in-glass, but that other minority sites also exist. The energy levels of the majority site were quantified. The fluorescence characteristics of the erbium ions in any site in the laser-induced crystals were found to be only weakly influenced by the irradiation conditions during growth. On the other hand, a hidden parameter, potentially boron deficiency-related defects, resulted in a significant change in the incorporation behavior of the erbium ions. Simultaneous scanning confocal Raman and fluorescence spectroscopy showed that the energies of the Raman modes are shifted, and the erbium fluorescence intensity varies, in a non-uniform manner, despite the host glass being homogeneously doped, across the cross-sections of laser-induced crystals in glass. These fluctuations within the Raman and fluorescence are spatially correlated, implying that different erbium sites form preferentially at different locations in the crystal cross-section.

  4. Root Surface Bio-modification with Erbium Lasers- A Myth or a Reality??

    PubMed Central

    Lavu, Vamsi; Sundaram, Subramoniam; Sabarish, Ram; Rao, Suresh Ranga

    2015-01-01

    The objective of this literature review was to critically review the evidence available in the literature regarding the expediency of erbium family of lasers for root bio modification as a part of periodontal therapy. The literature search was performed on the Pubmed using MeSH words such as "lasers/therapeutic use, scaling, dental calculus, tooth root/anatomy and histology, ultrasonic therapy". The studies were screened and were grouped as follows: those evaluating a) efficacy for calculus removal with the Erbium family of laser b) root surface changes following Er YAG and Er Cr YSGG application c) comparative studies of the Er YAG, Er Cr YSGG lasers versus conventional methods of root surface modification d) Bio compatibility of root surface following Erbium laser treatment e) Studies on the combined efficacy of laser root modification with conventional methods towards root surface bio-modification f) Studies on effectiveness of root surface bio-modification prior to root coverage procedures. In conclusion, the erbium family has a proven anti-bacterial action, predictable calculus removal, minimal root substance removal, and appears to favor cell attachment. The Erbium family of lasers appears to be a useful adjunct for the management of periodontal disease. PMID:25713635

  5. The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth.

    PubMed

    Li, Weiyang; Yao, Hongbin; Yan, Kai; Zheng, Guangyuan; Liang, Zheng; Chiang, Yet-Ming; Cui, Yi

    2015-01-01

    Lithium metal has shown great promise as an anode material for high-energy storage systems, owing to its high theoretical specific capacity and low negative electrochemical potential. Unfortunately, uncontrolled dendritic and mossy lithium growth, as well as electrolyte decomposition inherent in lithium metal-based batteries, cause safety issues and low Coulombic efficiency. Here we demonstrate that the growth of lithium dendrites can be suppressed by exploiting the reaction between lithium and lithium polysulfide, which has long been considered as a critical flaw in lithium-sulfur batteries. We show that a stable and uniform solid electrolyte interphase layer is formed due to a synergetic effect of both lithium polysulfide and lithium nitrate as additives in ether-based electrolyte, preventing dendrite growth and minimizing electrolyte decomposition. Our findings allow for re-evaluation of the reactions regarding lithium polysulfide, lithium nitrate and lithium metal, and provide insights into solving the problems associated with lithium metal anodes. PMID:26081242

  6. The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth

    NASA Astrophysics Data System (ADS)

    Li, Weiyang; Yao, Hongbin; Yan, Kai; Zheng, Guangyuan; Liang, Zheng; Chiang, Yet-Ming; Cui, Yi

    2015-06-01

    Lithium metal has shown great promise as an anode material for high-energy storage systems, owing to its high theoretical specific capacity and low negative electrochemical potential. Unfortunately, uncontrolled dendritic and mossy lithium growth, as well as electrolyte decomposition inherent in lithium metal-based batteries, cause safety issues and low Coulombic efficiency. Here we demonstrate that the growth of lithium dendrites can be suppressed by exploiting the reaction between lithium and lithium polysulfide, which has long been considered as a critical flaw in lithium-sulfur batteries. We show that a stable and uniform solid electrolyte interphase layer is formed due to a synergetic effect of both lithium polysulfide and lithium nitrate as additives in ether-based electrolyte, preventing dendrite growth and minimizing electrolyte decomposition. Our findings allow for re-evaluation of the reactions regarding lithium polysulfide, lithium nitrate and lithium metal, and provide insights into solving the problems associated with lithium metal anodes.

  7. Laser treatment of peri-implantitis: a literature review.

    PubMed

    Ashnagar, Sajjad; Nowzari, Hessam; Nokhbatolfoghahaei, Hanieh; Yaghoub Zadeh, Behnoush; Chiniforush, Nasim; Choukhachi Zadeh, Nastaran

    2014-01-01

    Peri-implantitis is a state defined as an inflammatory reaction around osseointegrated implants, leading to progressive loss of supporting bone. Various treatment methods are suggested in the treatment of peri-implantitis and clinicians have to choose a method over a large number of treatment protocols. Lasers have shown promising therapeutic effect in treatment of peri-implantitis. However, some controversies have been found in clinical outcomes after using lasers. Therefore, we aimed to review the current literature over the past ten years for the use of lasers in treatment of peri-implantitis, via the Pubmed electronic database of the US National Library of Medicine. Fifteen human studies were reviewed. Er:YAG (Erbium-Doped Yttrium Aluminum Garnet), CO2(Carbon Dioxide Laser) and Diode lasers were used. Despite inconsistencies and disharmonies among studies in terms of study design, positive treatment outcomes were obvious among the majority of them. However, short period of follow-ups and poor control of plaque index, as a critical confounding factor, were the major problems which these studies suffered from. It seems that one session laser therapy is not adequate for achieving optimal clinical outcome. Further studies with longer periods of follow-ups, intense control of plaque index, and various sessions of laser treatments are needed to clearly illustrate the clinical privilege of laser therapy. PMID:25653815

  8. Method of recycling lithium borate to lithium borohydride through diborane

    DOEpatents

    Filby, Evan E.

    1976-01-01

    This invention provides a method for the recycling of lithium borate to lithium borohydride which can be reacted with water to generate hydrogen for utilization as a fuel. The lithium borate by-product of the hydrogen generation reaction is reacted with hydrogen chloride and water to produce boric acid and lithium chloride. The boric acid and lithium chloride are converted to lithium borohydride through a diborane intermediate to complete the recycle scheme.

  9. Electroluminescence efficiencies of erbium in silicon-based hosts

    SciTech Connect

    Cueff, Sébastien E-mail: christophe.labbe@ensicaen.fr; Manel Ramírez, Joan; Berencén, Yonder; Garrido, Blas; Kurvits, Jonathan A.; Zia, Rashid; Rizk, Richard; Labbé, Christophe E-mail: christophe.labbe@ensicaen.fr

    2013-11-04

    We report on room-temperature 1.5 μm electroluminescence from trivalent erbium (Er{sup 3+}) ions embedded in three different CMOS-compatible silicon-based hosts: SiO{sub 2}, Si{sub 3}N{sub 4}, and SiN{sub x}. We show that although the insertion of either nitrogen or excess silicon helps enhance electrical conduction and reduce the onset voltage for electroluminescence, it drastically decreases the external quantum efficiency of Er{sup 3+} ions from 2% in SiO{sub 2} to 0.001% and 0.0004% in SiN{sub x} and Si{sub 3}N{sub 4}, respectively. Furthermore, we present strong evidence that hot carrier injection is significantly more efficient than defect-assisted conduction for the electrical excitation of Er{sup 3+} ions. These results suggest strategies to optimize the engineering of on-chip electrically excited silicon-based nanophotonic light sources.

  10. Refractive index of erbium doped GaN thin films

    SciTech Connect

    Alajlouni, S.; Sun, Z. Y.; Li, J.; Lin, J. Y.; Jiang, H. X.; Zavada, J. M.

    2014-08-25

    GaN is an excellent host for erbium (Er) to provide optical emission in the technologically important as well as eye-safe 1540 nm wavelength window. Er doped GaN (GaN:Er) epilayers were synthesized on c-plane sapphire substrates using metal organic chemical vapor deposition. By employing a pulsed growth scheme, the crystalline quality of GaN:Er epilayers was significantly improved over those obtained by conventional growth method of continuous flow of reaction precursors. X-ray diffraction rocking curve linewidths of less than 300 arc sec were achieved for the GaN (0002) diffraction peak, which is comparable to the typical results of undoped high quality GaN epilayers and represents a major improvement over previously reported results for GaN:Er. Spectroscopic ellipsometry was used to determine the refractive index of the GaN:Er epilayers in the 1540 nm wavelength window and a linear dependence on Er concentration was found. The observed refractive index increase with Er incorporation and the improved crystalline quality of the GaN:Er epilayers indicate that low loss GaN:Er optical waveguiding structures are feasible.

  11. Assignments of the Raman modes of monoclinic erbium oxide

    SciTech Connect

    Yan, D.; Wu, P. Zhang, S. P.; Liang, L.; Yang, F.; Pei, Y. L.; Chen, S.

    2013-11-21

    As a heavy rare earth oxide, erbium oxide (Er{sub 2}O{sub 3}) has many attractive properties. Monoclinic Er{sub 2}O{sub 3} has useful properties not found in stable cubic Er{sub 2}O{sub 3}, such as unique optical properties and high radiation damage tolerance. In this study, cubic Er{sub 2}O{sub 3} coating and Er{sub 2}O{sub 3} coating with mixed phases were prepared. The Raman scattering spectra of these coatings were investigated by using a confocal micro-Raman spectrometer equipped with 325, 473, 514, 532, 633, and 784 nm lasers. A total of 17 first-order Raman modes of monoclinic Er{sub 2}O{sub 3} were identified and assigned. The modes at 83, 112, 152, 170, 278, 290, 409, 446, 478, 521, 603, and 622 cm{sup −1} are of A{sub g} symmetry, whereas modes at 71, 98, 333, 409, 446, and 468 cm{sup −1} are of B{sub g} symmetry. This research provides basic data necessary for the characterization of monoclinic Er{sub 2}O{sub 3} by Raman spectroscopy.

  12. Advanced experiments with an erbium-doped fiber laser

    NASA Astrophysics Data System (ADS)

    Marques, Paulo V. S.; Marques, Manuel B.; Rosa, Carla C.

    2014-07-01

    This communication describes an optical hands-on fiber laser experiment aimed at advanced college courses. Optical amplifiers and laser sources represent very important optical devices in numerous applications ranging from telecommunications to medicine. The study of advanced photonics experiments is particularly relevant at undergraduate and master level. This paper discusses the implementation of an optical fiber laser made with a cavity built with two tunable Bragg gratings. This scheme allows the students to understand the laser working principles as a function of the laser cavity set-up. One or both of the gratings can be finely tuned in wavelength through applied stress; therefore, the degree of spectral mismatch of the two gratings can be adjusted, effectively changing the cavity feedback. The impact of the cavity conditions on the laser threshold, spectrum and efficiency is analyzed. This experiment assumes that in a previous practice, the students should had already characterized the erbium doped fiber in terms of absorption and fluorescent spectra, and the spectral gain as a function of pump power.

  13. Surface behaviour in deuterium permeation through erbium oxide coatings

    NASA Astrophysics Data System (ADS)

    Chikada, T.; Suzuki, A.; Adelhelm, C.; Terai, T.; Muroga, T.

    2011-06-01

    Suppression of tritium permeation through structural materials is essential in order to mitigate fuel loss and radioactivity concerns. Ceramic coatings have been investigated for over three decades as tritium permeation barriers (TPBs); however, a very limited number of investigations on the mechanism of hydrogen-isotope permeation through the coatings have been reported. In this study, deuterium permeation behaviour of erbium oxide coatings fabricated by filtered arc deposition on reduced activation ferritic/martensitic steels has been investigated. The samples coated on both sides of the substrates showed remarkably lower permeability than those coated on one side, and the maximum reduction efficiency indicated a factor of 105 compared with the substrate. The different permeation behaviour between the coatings facing the high and low deuterium pressure sides has been found by the crystal structure analysis and the evaluation of the energy barriers. It is suggested that the permeation processes on the front and back surfaces are independent, and the TPB efficiency of the samples coated on both sides can be expressed by a multiplication of that of each side.

  14. Hydrogen diffusion along grain boundaries in erbium oxide coatings

    NASA Astrophysics Data System (ADS)

    Mao, Wei; Chikada, Takumi; Suzuki, Akihiro; Terai, Takayuki

    2014-12-01

    Diffusion of interstitial atomic hydrogen in erbium oxide (Er2O3) was investigated using density functional theory (DFT) and molecular dynamics (MD) methods. Hydrogen diffusivity in bulk, on (0 0 1) surface, and along Σ13 (4-3-1)/[1 1 1] symmetric tilt grain boundaries (GBs) were evaluated in a temperature range of 673-1073 K, as well as hydrogen diffusion barriers. It was found that H diffusion shows the faster on (0 0 1) surface than along GBs and in bulk. Also, energy barrier of H diffusion in bulk estimated by DFT and MD methods is somewhat higher than that along GBs evaluated in the experiments. This suggests that H diffusion in Er2O3 coatings depends on GBs rather than bulk. In addition, with a correction of GB density, the simulated diffusivity along GBs in MD simulations is in good agreement with the experimental data within one order of magnitude. The discrepancy of H diffusivity between the experiments and the simulations should be reduced by considering H concentration, H diffusion direction, deviations of the initial configuration, vacancy defects, etc.

  15. Cavitation bubbles induced by Erbium lasers: implications for dentistry

    NASA Astrophysics Data System (ADS)

    Verleng, Marja; Verdaasdonk, Rudolf; van der Veen, Albert; Lemberg, Vladimir; Boutoussov, Dmitri

    2014-02-01

    With new fiber systems available for 3 μm, Erbium lasers become more interesting for precise tissue ablation in a water environment enabling new application in e.g. dentistry. The dynamics of explosive bubble formation was investigated at 2.78 μm (Er,Cr;YSGG) and 2.94 μm (Er:YAG), in relation to energy (10-50 mJ), pulse length (20-150 μs) and fiber tip shape (flat or taper). The dynamics of exploding and imploding vapor bubbles were captured with high speed imaging (10 - 300 μs range). Increasing the pulse length and energy, the vapor bubble became more elongated with an opaque surface for flat tip fibers. Tapered fibers produced spherical vapor bubbles with an optically transparent surface expected to be more forceful for creating mechanical effects in both hard and soft tissues. There was no significant difference between bubbles formed at 2.78 μm (Er,Cr;YSGG) and 2.94 μm (Er:YAG).

  16. Ablation characteristics of quantum square pulse mode dental erbium laser

    NASA Astrophysics Data System (ADS)

    Lukač, Nejc; Suhovršnik, Tomaž; Lukač, Matjaž; Jezeršek, Matija

    2016-01-01

    Erbium lasers are by now an accepted tool for performing ablative medical procedures, especially when minimal invasiveness is desired. Ideally, a minimally invasive laser cutting procedure should be fast and precise, and with minimal pain and thermal side effects. All these characteristics are significantly influenced by laser pulse duration, albeit not in the same manner. For example, high cutting efficacy and low heat deposition are characteristics of short pulses, while vibrations and ejected debris screening are less pronounced at longer pulse durations. We report on a study of ablation characteristics on dental enamel and cementum, of a chopped-pulse Er:YAG [quantum square pulse (QSP)] mode, which was designed to reduce debris screening during an ablation process. It is shown that in comparison to other studied standard Er:YAG and Er,Cr:YSGG laser pulse duration modes, the QSP mode exhibits the highest ablation drilling efficacy with lowest heat deposition and reduced vibrations, demonstrating that debris screening has a considerable influence on the ablation process. By measuring single-pulse ablation depths, we also show that tissue desiccation during the consecutive delivery of laser pulses leads to a significant reduction of the intrinsic ablation efficacy that cannot be fully restored under clinical settings by rehydrating the tooth using an external water spray.

  17. The study on the effect of erbium on diamond-like carbon deposited by pulsed laser deposition technique

    NASA Astrophysics Data System (ADS)

    Foong, Y. M.; Hsieh, J.; Li, X.; Chua, D. H. C.

    2009-09-01

    Diamond-like carbon (DLC) films doped with a small fraction of erbium (0.5-2.0 at. %, at 0.5 at. % interval) were prepared by using a 248 nm KrF pulsed laser deposition technique. The effects of erbium on the surface morphology, microstructure, chemical binding states, tribological property, and the adhesion strength of DLC films were investigated. Atomic force microscopy showed that the surface roughness of the films increased with the increasing of erbium fraction, but generally the nanocomposite films were smooth with rms below 1 nm. Raman analysis showed broad peaks centered at 1550 cm-1 on all the samples. The deconvoluted Raman spectra on DLC doped with different fractions of erbium showed that the ID/IG ratio increased with increasing erbium content, and the comparative percent of sp3 is between 50% and 58% for erbium fraction between 0.5 and 2.0 at. %. High resolution x-ray photoelectron spectroscopy confirmed that the C 1s peaks had slightly shifted away from 285.2 (diamond) to 284.5 eV (graphite). The deconvolution of the spectra further confirmed the influence of erbium to the sp3 contents and revealed the presence of SiC with the increasing of Er fraction. Microscratch tester results showed that the adhesion strength (critical load) of the films improved with the presence of SiC bonding at the interface. This hinted that the presence of the heavier erbium may force the impinging carbon ions to react more with the interface to form silicon carbide bonds, thus enhancing the adhesion strength. Although the presence of erbium increased the surface roughness of the films, the coefficients of friction of the erbium doped DLC films were still closely resembled to pure DLC, i.e., 0.11-0.12 compared to 0.10 for pure DLC.

  18. Cochlear Implants

    MedlinePlus

    ... outside of the body, behind the ear. A second part is surgically placed under the skin. An implant does not restore normal hearing. It can help a person understand speech. Children and adults can benefit from them. National Institute on Deafness and Other Communication Disorders

  19. Cochlear implant

    MedlinePlus

    ... are sent along the auditory nerve to the brain. A deaf person does not have a functioning inner ear. A cochlear implant tries to replace the function of the inner ear by ... signals to the brain. Sound is picked up by a microphone worn ...

  20. Synthesis and characterization of discrete luminescent erbium-doped silicon nanocrystals

    SciTech Connect

    John, J.S.; Coffer, J.L.; Chen, Y.; Pinizzotto, R.F.

    1999-03-10

    The preparation of discrete erbium-doped silicon nanoparticles prepared by the co-pyrolysis of disilane and the volatile complex Er(tmhd){sub 3} (tmhd = 2,2,6,6-tetramethyl-3,5-heptanedionato) is described. The nanoparticles were characterized by transmission electron microscopy, selected area electron diffraction, X-ray dispersive spectroscopy, photoluminescence, and UV-visible absorption spectroscopies. Erbium-doped silicon nanoparticles possess a distinctive dark contrast in the transmission electron microscope, and the presence of erbium is confirmed by X-ray energy dispersive spectroscopy. The mean diameter of the nanoparticle aggregates can be shifted by altering the length of the pyrolysis oven employed. Characteristic Er{sup 3+} near-infrared photoluminescence at 1,540 nm is detected in these doped nanoparticles; preliminary excitation and power dependence measurements of this luminescence suggest a carrier-mediated emission mechanism.

  1. Low-temperature growth of silicon epitaxial layers codoped with erbium and oxygen atoms

    SciTech Connect

    Shengurov, D. V.; Chalkov, V. Yu.; Denisov, S. A.; Shengurov, V. G.; Stepikhova, M. V.; Drozdov, M. N.; Krasilnik, Z. F.

    2013-03-15

    The fabrication technology and properties of light-emitting Si structures codoped with erbium and oxygen are reported. The layers are deposited onto (100) Si by molecular beam epitaxy (MBE) using an Er-doped silicon sublimation source. The partial pressure of the oxygen-containing gases in the growth chamber of the MBE facility before layer growth is lower than 5 Multiplication-Sign 10{sup -10} Torr. The oxygen and erbium concentrations in the Si layers grown at 450 Degree-Sign C is {approx}1 Multiplication-Sign 10{sup 19} and 10{sup 18} cm{sup -3}, respectively. The silicon epitaxial layers codoped with erbium and oxygen have high crystal quality and yield effective photoluminescence and electroluminescence signals with the dominant optically active Er-1 center forming upon postgrowth annealing at a temperature of 800 Degree-Sign C.

  2. In vitro application of optical transmission systems in erbium:YAG laser temporomandibular joint surgery

    NASA Astrophysics Data System (ADS)

    Nuebler-Moritz, Michael; Hering, Peter; Niederdellmann, Herbert; Deuerling, Christian; Dammer, Ralf

    1995-05-01

    The experimental setup of this study is focused on the changes in temporomandibular joint tissue after irradiation with an Erbium:YAG laser. Initially, the free-running beam from the laser was focused onto freshly excised porcine tissue samples, indicating an optimum average energy density and pulse duration for the purpose of temporomandibular joint surgery of about 15 - 60 J/cm2 and 120 microsecond(s) - 240 microsecond(s) , respectively. Consecutively, an attempt was made to couple the Erbium:YAG laser beam on the one hand to optical fibers made of infrared-transmitting glasses (fluoride- and chalcogenide-based), on the other hand to a recently developed sapphire and liquid core fiber, respectively. From the preliminary observations of this investigation it appears that both the liquid core and the sapphire fiber are the most promising candidates for delivery of Erbium-YAG laser radiation in arthroscopic surgery of the craniomandibular articulation.

  3. Enhancement of photoluminescence intensity of erbium doped silica containing Ge nanocrystals: distance dependent interactions.

    PubMed

    Manna, S; Aluguri, R; Bar, R; Das, S; Prtljaga, N; Pavesi, L; Ray, S K

    2015-01-30

    Photo-physical processes in Er-doped silica glass matrix containing Ge nanocrystals prepared by the sol-gel method are presented in this article. Strong photoluminescence at 1.54 μm, important for fiber optics telecommunication systems, is observed from the different sol-gel derived glasses at room temperature. We demonstrate that Ge nanocrystals act as strong sensitizers for Er(3+) ions emission and the effective Er excitation cross section increases by almost four orders of magnitude with respect to the one without Ge nanocrystals. Rate equations are considered to demonstrate the sensitization of erbium luminescence by Ge nanocrystals. Analyzing the erbium effective excitation cross section, extracted from the flux dependent rise and decay times, a Dexter type of short range energy transfer from a Ge nanocrystal to erbium ion is established. PMID:25558802

  4. Optical characterization and crystal field calculations for some erbium based solid state materials for laser refrigeration

    NASA Astrophysics Data System (ADS)

    Hasan, Z.; Qiu, Z.; Johnson, Jackie; Homerick, Uwe

    2009-02-01

    The potential of three erbium based solids hosts has been investigated for laser cooling. Absorption and emission spectra have been studied for the low lying IR transitions of erbium that are relevant to recent reports of cooling using the 4I15/2-4I9/2 and4I15/2 -4I13/2 transitions. Experimental studies have been performed for erbium in three hosts; ZBLAN glass and KPb2Cl5 and Cs2NaYCl6 crystals. In order to estimate the efficiencies of cooling, theoretical calculations have been performed for the cubic Elpasolite (Cs2NaYCl6 ) crystal. These calculations also provide a first principle insight into the cooling efficiency for non-cubic and glassy hosts where such calculations are not possible.

  5. Photoluminescence in semiconductor structures based on butyl-substituted erbium phthalocyanine complexes

    SciTech Connect

    Belogorokhov, I. A. Ryabchikov, Yu. V.; Tikhonov, E. V.; Pushkarev, V. E.; Breusova, M. O.; Tomilova, L. G.; Khokhlov, D. R.

    2008-03-15

    The study is concerned with the luminescence properties of ensembles of semiconductor structures containing organic phthalocyanine molecules with erbium ions as complexing agents. The photoluminescence spectra of the structures of the type of erbium monophthalocyanine, bisphthalocyanine, and triphthalocyanine are recorded. The photoluminescence peaks are detected at the wavelengths 888, 760, and 708 nm (and photon energies 1.4, 1.6, and 1.75 eV) corresponding to electronic transitions within the organic complexes. It is found that, when a metal complexing agent is introduced into the molecular structure of the ligand, the 708 nm luminescence peak becomes unobservable. It is shown that, in the bisphthalocyanine samples, the photoluminescence signal corresponding to transitions from the 4F{sub 9/2} level of erbium ions is enhanced.

  6. Enhancement of photoluminescence intensity of erbium doped silica containing Ge nanocrystals: distance dependent interactions

    NASA Astrophysics Data System (ADS)

    Manna, S.; Aluguri, R.; Bar, R.; Das, S.; Prtljaga, N.; Pavesi, L.; Ray, S. K.

    2015-01-01

    Photo-physical processes in Er-doped silica glass matrix containing Ge nanocrystals prepared by the sol-gel method are presented in this article. Strong photoluminescence at 1.54 μm, important for fiber optics telecommunication systems, is observed from the different sol-gel derived glasses at room temperature. We demonstrate that Ge nanocrystals act as strong sensitizers for Er3+ ions emission and the effective Er excitation cross section increases by almost four orders of magnitude with respect to the one without Ge nanocrystals. Rate equations are considered to demonstrate the sensitization of erbium luminescence by Ge nanocrystals. Analyzing the erbium effective excitation cross section, extracted from the flux dependent rise and decay times, a Dexter type of short range energy transfer from a Ge nanocrystal to erbium ion is established.

  7. Lithium Redistribution in Lithium-Metal Batteries

    SciTech Connect

    Ferrese, A; Albertus, P; Christensen, J; Newman, J

    2012-01-01

    A model of a lithium-metal battery with a CoO2 positive electrode has been modeled in order to predict the movement of lithium in the negative electrode along the negative electrode/separator interface during cell cycling. A finite-element approach was used to incorporate an intercalation positive electrode using superposition, electrode tabbing, transport using concentrated solution theory, as well as the net movement of the lithium electrode during cycling. From this model, it has been found that movement of lithium along the negative electrode/separator interface does occur during cycling and is affected by three factors: the cell geometry, the slope of the open-circuit-potential function of the positive electrode, and concentration gradients in both the solid and liquid phases in the cell. (C) 2012 The Electrochemical Society. [DOI: 10.1149/2.027210jes] All rights reserved.

  8. Nanostructuring an erbium local environment inside sol-gel silica glasses: toward efficient erbium optical fiber lasers

    NASA Astrophysics Data System (ADS)

    Savelii, Inna; El Hamzaoui, Hicham; Bigot, Laurent; Bouwmans, Géraud; Fsaifes, Ihsan; Capoen, Bruno; Bouazaoui, Mohamed

    2016-02-01

    To extend the use of erbium- (Er-)/aluminum- (Al-) codoped optical fibers in hostile environments, the reduction of the Al amount has been identified as a serious way to harden them against harsh radiation. In this work, sol-gel monolithic Er3+-doped and Er3+/Al3+-codoped silica glasses were prepared from nanoporous silica xerogels soaked in a solution containing an Er salt together or not with an Al salt. After sintering, these glasses were used as the core material of microstructured optical fibers made by the stack-and-draw method. The influence of Al incorporation on the optical properties of Er3+-doped silica glasses and fibers is investigated. This approach enabled the preparation of silica glasses containing dispersed Er3+ ions with low Al content. The obtained fibers have been tested in an all-fibered cavity laser architecture. The Er3+/Al3+-codoped fiber laser presents a maximum efficiency of 27% at 1530 nm. We show that without Al doping, the laser exhibits lower performances that depend on Er content inside the doped fiber core. The effect of Er pair-induced quenching also has been investigated through nonsaturable absorption experiments, which clearly indicate that the fraction of Er ion pairs is significantly reduced in the Al-codoped fiber.

  9. Manufacture and properties of erythromycin beads containing neutron-activated erbium-171

    SciTech Connect

    Parr, A.F.; Digenis, G.A.; Sandefer, E.P.; Ghebre-Sellassie, I.; Iyer, U.; Nesbitt, R.U.; Scheinthal, B.M. )

    1990-03-01

    To evaluate the effects of a neutron activation radiolabeling technique on an enteric-coated multiparticulate formulation of erythromycin, test quantities were produced under industrial pilot scale conditions. The pellets contained the stable isotope erbium oxide (Er-170), which was later converted by neutron activation into the short-lived gamma ray-emitting radionuclide, erbium-171. In vitro studies indicated that the dissolution profile, acid resistance, and enteric-coated surface of the pellets were minimally affected by the irradiation procedure. Antimicrobial potency was also unaffected, as determined by microbiological assay. Neutron activation thus appears to simplify the radiolabeling of complex pharmaceutical dosage forms for in vivo study by external gamma scintigraphy.

  10. Optical bistability in erbium-doped yttrium aluminum garnet crystal combined with a laser diode.

    PubMed

    Maeda, Y

    1994-01-10

    Optical bistability was observed in a simple structure of an injection laser diode combined with an erbium-doped yttrium aluminum garnet crystal. Since a hysteresis characteristic exists in the relationship between the wavelength and the injection current of a laser diode, an optical memory function capable of holding the output status is confirmed. In addition, an optical signal inversion was caused by the decrease of transmission of the erbium-doped yttrium aluminum garnet crystal against the red shift (principally mode hopping) of the laser diode. It is suggested that the switching time of this phenomenon is the time necessary for a mode hopping by current injection. PMID:20862016

  11. Lithium and symptomatic hyperparathyroidism.

    PubMed Central

    Ananth, J; Dubin, S E

    1983-01-01

    Hyperparathyroidism with or without adenoma has occasionally been reported in association with lithium treatment, and in symptomatic patients depression, psychosis and an exacerbation of existing psychopathology may occur. Three lithium-treated patients with hyperparathyroidism are reported, in whom discontinuation of lithium in one and removal of parathyroid adenomata in two led to both a reduction in plasma calcium levels and an improvement in their psychopathology. PMID:6423822

  12. Lithium purification technique

    DOEpatents

    Keough, R.F.; Meadows, G.E.

    1984-01-10

    A method for purifying liquid lithium to remove unwanted quantities of nitrogen or aluminum. The method involves precipitation of aluminum nitride by adding a reagent to the liquid lithium. The reagent will be either nitrogen or aluminum in a quantity adequate to react with the unwanted quantity of the impurity to form insoluble aluminum nitride. The aluminum nitride can be mechanically separated from the molten liquid lithium.

  13. Lithium purification technique

    DOEpatents

    Keough, Robert F.; Meadows, George E.

    1985-01-01

    A method for purifying liquid lithium to remove unwanted quantities of nitrogen or aluminum. The method involves precipitation of aluminum nitride by adding a reagent to the liquid lithium. The reagent will be either nitrogen or aluminum in a quantity adequate to react with the unwanted quantity of the impurity to form insoluble aluminum nitride. The aluminum nitride can be mechanically separated from the molten liquid lithium.

  14. Reliability systems for implantable cardiac defibrillator batteries

    NASA Astrophysics Data System (ADS)

    Takeuchi, Esther S.

    The reliability of the power sources used in implantable cardiac defibrillators is critical due to the life-saving nature of the device. Achieving a high reliability power source depends on several systems functioning together. Appropriate cell design is the first step in assuring a reliable product. Qualification of critical components and of the cells using those components is done prior to their designation as implantable grade. Product consistency is assured by control of manufacturing practices and verified by sampling plans using both accelerated and real-time testing. Results to date show that lithium/silver vanadium oxide cells used for implantable cardiac defibrillators have a calculated maximum random failure rate of 0.005% per test month.

  15. Optical addressing of an individual erbium ion in silicon.

    PubMed

    Yin, Chunming; Rancic, Milos; de Boo, Gabriele G; Stavrias, Nikolas; McCallum, Jeffrey C; Sellars, Matthew J; Rogge, Sven

    2013-05-01

    The detection of electron spins associated with single defects in solids is a critical operation for a range of quantum information and measurement applications under development. So far, it has been accomplished for only two defect centres in crystalline solids: phosphorus dopants in silicon, for which electrical read-out based on a single-electron transistor is used, and nitrogen-vacancy centres in diamond, for which optical read-out is used. A spin read-out fidelity of about 90 per cent has been demonstrated with both electrical read-out and optical read-out; however, the thermal limitations of the former and the poor photon collection efficiency of the latter make it difficult to achieve the higher fidelities required for quantum information applications. Here we demonstrate a hybrid approach in which optical excitation is used to change the charge state (conditional on its spin state) of an erbium defect centre in a silicon-based single-electron transistor, and this change is then detected electrically. The high spectral resolution of the optical frequency-addressing step overcomes the thermal broadening limitation of the previous electrical read-out scheme, and the charge-sensing step avoids the difficulties of efficient photon collection. This approach could lead to new architectures for quantum information processing devices and could drastically increase the range of defect centres that can be exploited. Furthermore, the efficient electrical detection of the optical excitation of single sites in silicon represents a significant step towards developing interconnects between optical-based quantum computing and silicon technologies. PMID:23636400

  16. Erbium-doped sol-gel materials for optical applications

    NASA Astrophysics Data System (ADS)

    Berni, Anette; Mennig, Martin; Schmidt, Helmut K.

    2003-04-01

    A new chemical nanotechnological route for the preparation of fully densified doped SiO2 coatings with thicknesses in the low ´m-range on Si- and SiO2-wafers has been developed. Beside pure SiO2 coatings, that might be useful as a buffer layer on silicon, silicate layers with increased refractive index are needed for planar waveguide application. Therefore, a synthesis for the preparation of nano particulate sols was developed, thus allowing the incorporation of dopands like Al2O3, PbO and Er2O3 for passive and active layers. Alumina was incorporated for the improvement of the Erbium solubility in active components. The coating sols consist of an organic binder, dissolved in a suspension of nanoscaled silica particles (10 nm in diameter) and dopands and were applied on Si- and SiO2-wafers by spin coating. After removal of the binder at 500 °C, investigated by IR-spectroscopy, highly porous (nD = 1.23) but transparent doped silica layers were obtained. The densification of the layers was examined by measuring the refractive index by ellipsometry as a function of the densification temperature. Completely densified layers with thicknesses between 1.7 ´m (doped SiO2) and 6.5 ´m (doped SiO2) were obtained at temperatures between 1000 °C (doped SiO2) and 1100 °C) (pure SiO2). The layer thickness and unevenness was determined by interferometric measurements. The optical loss of Al2O3 and PbO doped layers was measured by prism coupling, the Er2O3 doped layers with Er3+ concentrations of up to 2.5 mole % show fluorescence around 1500 nm with a fluorescence lifetime of about 3.6 ms.

  17. Laminar Multicell Lithium Batteries

    SciTech Connect

    Bruder, A. H.

    1984-01-31

    Laminar batteries of series connected cells comprising lithium anodes and an electrolyte containing a passivating solvent reactive with lithium in which the cells are electrically connected in series by intercell barriers comprising outer layers of electrochemically inert electronically conducting material in contact with the electrochemically active anode and cathode of adjacent cells and a layer of metal foil between the electrochemically inert layers.

  18. Microwave photonic filter using multiwavelength Brillouin-erbium fiber laser with double-Brillouin-frequency shift

    SciTech Connect

    Loh, K. K.; Yeo, K. S.; Shee, Y. G.

    2015-04-24

    A microwave photonic filter based on double-Brillouin-frequency spaced multiwavelength Brillouin-erbium fiber laser (BEFL) is experimentally demonstrated. The filter selectivity can be easily adjusted by tuning and apodizing the optical taps generated from the multiwavelength BEFL. Reconfiguration of different frequency responses are demonstrated.

  19. Performance of a High-Concentration Erbium-Doped Fiber Amplifier with 100 nm Amplification Bandwidth

    SciTech Connect

    Hajireza, P.; Shahabuddin, N. S.; Abbasi-Zargaleh, S.; Emami, S. D.; Abdul-Rashid, H. A.; Yusoff, Z.

    2010-07-07

    Increasing demand for higher bandwidth has driven the need for higher Wavelength Division Multiplexing (WDM) channels. One of the requirements to achieve this is a broadband amplifier. This paper reports the performance of a broadband, compact, high-concentration and silica-based erbium-doped fiber amplifier. The amplifier optimized to a 2.15 m long erbium-doped fiber with erbium ion concentration of 2000 ppm. The gain spectrum of the amplifier has a measured amplification bandwidth of 100 nm using a 980 nm laser diode with power of 150 mW. This silica-based EDFA shows lower noise figure, higher gain and wider bandwidth in shorter wavelengths compared to Bismuth-based EDFA with higher erbium ion concentration of 3250 ppm at equivalent EDF length. The silica-based EDF shows peak gain at 22 dB and amplification bandwidth between 1520 nm and 1620 nm. The lowest noise figure is 5 dB. The gain is further improved with the implementation of enhanced EDFA configurations.

  20. Effects of simultaneously fiber transmitted erbium and holmium radiation on the interaction with highly absorbing media

    NASA Astrophysics Data System (ADS)

    Frenz, Martin; Pratisto, Hans S.; Ith, Michael; Koenz, Flurin; Weber, Heinz P.

    1995-05-01

    Erbium and Holmium lasers have both been shown to be suitable for orthopedic surgery performed under water. Erbium lasers emitting in the 3 micrometers wavelength region corresponding to the maximum water absorption peak effectively ablated biological tissues with high precision and minimal thermal damage. Holmium laser radiation at 2 micrometers , due to a lower absorption coefficient, is characterized by a greater extent of thermal damage leading to hemostasis. To combine the special advantages of each system we simultaneously coupled their radiation into a zirconium fluoride fiber (ZrF4) which was protected with a quartz fiber tip. Pressure measurements performed in the liquid using a piezo electrical transducer, transmission measurements and video flash lamp schlieren imaging of the laser induced vapor bubble were used in order to determine optimum laser parameters. The cutting efficiency of the Erbium laser is drastically improved when a low energy Holmium laser pulse is additionally used which is just able to open a vapor channel through which the Erbium laser pulse can be transmitted. The dynamics of the channel formation, geometry and life time are measured as a function of the delay time between the two different laser pulses and the pulse energy applied. The combination of 2 micrometers and 3 micrometers radiation seems to be an ideal instrument for tissue treatment.

  1. Microwave photonic filter using multiwavelength Brillouin-erbium fiber laser with double-Brillouin-frequency shift

    NASA Astrophysics Data System (ADS)

    Loh, K. K.; Yeo, K. S.; Shee, Y. G.

    2015-04-01

    A microwave photonic filter based on double-Brillouin-frequency spaced multiwavelength Brillouin-erbium fiber laser (BEFL) is experimentally demonstrated. The filter selectivity can be easily adjusted by tuning and apodizing the optical taps generated from the multiwavelength BEFL. Reconfiguration of different frequency responses are demonstrated.

  2. REVIEW ARTICLE: Slow and fast light based on coherent population oscillations in erbium-doped fibres

    NASA Astrophysics Data System (ADS)

    Arrieta-Yáñez, Francisco; Calderón, Oscar G.; Melle, Sonia

    2010-10-01

    In this paper we review the main results on slow and fast light induced by coherent population oscillations in optical fibres doped with erbium ions. We explain the physics behind this technique and we describe the experimental realization. Finally, we summarize some recent advances in this field and future goals.

  3. Flat-Gain Wide-Band Erbium Doped Fiber Amplifier by Combining Two Difference Doped Fibers

    NASA Astrophysics Data System (ADS)

    Hamida, B. A.; Azooz, S. M.; Jasim, A. A.; Eltaif, T.; Ahmad, H.; Khan, S.; Harun, S. W.

    2015-03-01

    A new erbium-doped fibre amplifier (EDFA) is demonstrated using a combination of newly developed Erbium Zirconia co-doped fiber (Zr-EDF) and the commercial silica-based Erbium-doped fiber (Si-EDF) as the gain medium. Both fibers have a very high concentration of erbium ion. A compact amplifier operating in C-band region is firstly reported using a double-pass configuration. It is shown that average gains of the proposed Zr-EDF amplifier are obtained at approximately 18 dB with a gain variation of ±2 dB within C-band region. A flat-gain and wide band operation is achieved by configuring the amplifier in two stages comprising a 2 m long Zr-EDF and 9 m long Si-EDF optimised for C- and L-band operations, respectively, in a double-pass parallel configuration. A chirp fibre Bragg grating (CFBG) is used in both stages to ensure double propagation of the signal and thus to increase the attainable gain in both C- and L-band regions. At an input signal power of 0 dBm, a flat gain of 15 dB is achieved with a gain variation of less than 0.5 dB within a wide wavelength range from 1530 to 1605 nm. The corresponding noise figure varies from 6.2 to 10.8 dB within this wavelength region.

  4. Ultrasonic approach for formation of erbium oxide nanoparticles with variable geometries.

    PubMed

    Radziuk, Darya; Skirtach, André; Gessner, Andre; Kumke, Michael U; Zhang, Wei; Möhwald, Helmuth; Shchukin, Dmitry

    2011-12-01

    Ultrasound (20 kHz, 29 W·cm(-2)) is employed to form three types of erbium oxide nanoparticles in the presence of multiwalled carbon nanotubes as a template material in water. The nanoparticles are (i) erbium carboxioxide nanoparticles deposited on the external walls of multiwalled carbon nanotubes and Er(2)O(3) in the bulk with (ii) hexagonal and (iii) spherical geometries. Each type of ultrasonically formed nanoparticle reveals Er(3+) photoluminescence from crystal lattice. The main advantage of the erbium carboxioxide nanoparticles on the carbon nanotubes is the electromagnetic emission in the visible region, which is new and not examined up to the present date. On the other hand, the photoluminescence of hexagonal erbium oxide nanoparticles is long-lived (μs) and enables the higher energy transition ((4)S(3/2)-(4)I(15/2)), which is not observed for spherical nanoparticles. Our work is unique because it combines for the first time spectroscopy of Er(3+) electronic transitions in the host crystal lattices of nanoparticles with the geometry established by ultrasound in aqueous solution of carbon nanotubes employed as a template material. The work can be of great interest for "green" chemistry synthesis of photoluminescent nanoparticles in water. PMID:22022886

  5. Erbium:YAG laser contouring of the nasal dorsum: a preliminary investigation

    NASA Astrophysics Data System (ADS)

    Truong, Mai T.; Majaron, Boris; Pandoh, Nidhi S.; Wong, Brian J.

    2001-05-01

    In conventional aesthetic rhinoplasty operations, manual or powered rasps are used to reduce the osseo-cartilagenous nasal dorsum. This tactile method requires palpation of the instrument and the dorsum during surgery to estimate the degree of volume reduction, and often requires forceful manipulation of the dorsum which may illicit pain during surgery and contribute to post-operative edema and echymosis. In this preliminary study, we investigated the use of the Erbium:YAG laser ((lambda) equals294 micrometers ) to reduce bone and cartilage using ex-vivo porcine nasal dorsum and human cadaveric tissues. The short pulsed length and high absorption of this laser in biologic tissues results in minimization of thermal injury which are ideal for non- contact optical contouring of osseous and cartilagenous tissues in the face. Two Erbium:YAG lasers were used to ablate fresh porcine nasal bone and compared for their use. One Erbium:YAG laser, the Fidelis Laser, Fontana Medical Lasers, Ljubljana, Slovenija with variable pulse repetition rates (2 to 50 Hz), pulse energy (80 to 1000 mJ), and pulse duration (100, 300, 750 and 1000 microsecond(s) ) was used and compared to the Ultrafine Erbium:YAG laser, Coherent Inc., Santa Clara California, with variable pulse repetition rate (2 to 10 Hz), pulse energy (2-16 J/cm2), and spot diameter (2-6 mm). Only laser parameters approximating the conditions for thermal confinement were evaluated.

  6. Thermal Properties of Holmium-Implanted Gold Films

    NASA Astrophysics Data System (ADS)

    Prasai, K.; Alves, E.; Bagliani, D.; Yanardag, S. Basak; Biasotti, M.; Galeazzi, M.; Gatti, F.; Gomes, M. Ribeiro; Rocha, J.; Uprety, Y.

    2014-09-01

    The effective mass of the electron neutrino can be probed by studying the Ho electron capture decay with cryogenic microcalorimeters. The goal is to perform a calorimetric experiment, where all the energy released in the decay is measured except for the kinetic energy of the neutrino. To achieve such a goal, multiple approaches are being investigated to enclose the radioactive source in a microcalorimeter absorber without affecting the thermal properties of the absorber material. One such approach is to implant the radioactive isotope into a gold absorber, as gold is successfully used in similar applications. We measured the heat capacity of gold films, implanted with various concentrations of holmium and erbium (a byproduct of the Ho fabrication), in the temperature range 70-300 mK. Our results show that the specific heat capacity of the films is not affected by the implant, making this a viable option for a future experiment. We also verified that the implant does not affect the crystal structure of the gold film.

  7. Cathode material for lithium batteries

    DOEpatents

    Park, Sang-Ho; Amine, Khalil

    2015-01-13

    A method of manufacture an article of a cathode (positive electrode) material for lithium batteries. The cathode material is a lithium molybdenum composite transition metal oxide material and is prepared by mixing in a solid state an intermediate molybdenum composite transition metal oxide and a lithium source. The mixture is thermally treated to obtain the lithium molybdenum composite transition metal oxide cathode material.

  8. Cathode material for lithium batteries

    DOEpatents

    Park, Sang-Ho; Amine, Khalil

    2013-07-23

    A method of manufacture an article of a cathode (positive electrode) material for lithium batteries. The cathode material is a lithium molybdenum composite transition metal oxide material and is prepared by mixing in a solid state an intermediate molybdenum composite transition metal oxide and a lithium source. The mixture is thermally treated to obtain the lithium molybdenum composite transition metal oxide cathode material.

  9. Lithium and autophagy.

    PubMed

    Motoi, Yumiko; Shimada, Kohei; Ishiguro, Koichi; Hattori, Nobutaka

    2014-06-18

    Lithium, a drug used to treat bipolar disorders, has a variety of neuroprotective mechanisms, including autophagy regulation, in various neuropsychiatric conditions. In neurodegenerative diseases, lithium enhances degradation of aggregate-prone proteins, including mutated huntingtin, phosphorylated tau, and α-synuclein, and causes damaged mitochondria to degrade, while in a mouse model of cerebral ischemia and Alzheimer's disease autophagy downregulation by lithium is observed. The signaling pathway of lithium as an autophagy enhancer might be associated with the mammalian target of rapamycin (mTOR)-independent pathway, which is involved in myo-inositol-1,4,5-trisphosphate (IP3) in Huntington's disease and Parkinson's disease. However, the mTOR-dependent pathway might be involved in inhibiting glycogen synthase kinase-3β (GSK3β) in other diseases. Lithium's autophagy-enhancing property may contribute to the therapeutic benefit of patients with neuropsychiatric disorders. PMID:24738557

  10. Lithium metal oxide electrodes for lithium batteries

    DOEpatents

    Thackeray, Michael M.; Kim, Jeom-Soo; Johnson, Christopher S.

    2008-01-01

    An uncycled electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula Li.sub.(2+2x)/(2+x)M'.sub.2x/(2+x)M.sub.(2-2x)/(2+x)O.sub.2-.delta., in which 0.ltoreq.x<1 and .delta. is less than 0.2, and in which M is a non-lithium metal ion with an average trivalent oxidation state selected from two or more of the first row transition metals or lighter metal elements in the periodic table, and M' is one or more ions with an average tetravalent oxidation state selected from the first and second row transition metal elements and Sn. Methods of preconditioning the electrodes are disclosed as are electrochemical cells and batteries containing the electrodes.

  11. Erbium:YAG-laser induced vapor bubbles as a function of the quartz fiber tip geometry

    NASA Astrophysics Data System (ADS)

    Mrochen, Michael; Riedel, Peter; Donitzky, Christof; Seiler, Theo

    2001-07-01

    Background. The use of modern erbium: yttrium-aluminum- garnet (YAG) laser systems in ophthalmic microsurgery requires a precise knowledge of the size and dynamics of the laser induced vapor bubbles. The aim of this work was to clarify the possibilities of controlling the vapor bubble shape and size by using an optimized fiber tip geometry for various ophthalmic applications with the erbium:YAG laser. Methods. The mid-infrared radiation of free-running erbium:YAG laser was coupled optically into means of different low OH- quartz fiber tips to investigate the vapor bubble formation in water by high-speed photography. The core diameter of four fiber tips ranged from 200 up to 940 micrometers . Fourteen fiber tips were polished at an angle graduated from 10 degree(s) to 70 degree(s) over the full core diameter (seven fiber tips) and over the half core diameter (seven fiber tips). Three fiber tips were produced to have a curvature at the distal end with curvature radii of 160, 230, and 420 micrometers . Results. The shape as well as the size of erbium:YAG laser induced vapor bubbles can be controlled systematically by using adequate fiber tip geometries. In detail, the used different angles and curvatures demonstrate that the propagation direction of the vapor bubbles can be estimated by optical modeling considering Snell's law and the Fresnel laws at a quartz-air boundary. Beside this, the size of a vapor bubble can be predetermined by choosing ideal fiber tip geometries to reduce or increase the radiant exposure at the distal end of the quartz fiber tip. Conclusions. The good possibility of controlling the shape and size of vapor bubbles offers a wider range of new applications, especially in ophthalmic microsurgery such as erbium YAG laser vitrectomy.

  12. Comparison of the erbium-yttrium aluminum garnet and carbon dioxide lasers for in vitro bone and cartilage ablation

    SciTech Connect

    Gonzalez, C.; van de Merwe, W.P.; Smith, M.; Reinisch, L. )

    1990-01-01

    The in vitro bone- and cartilage-ablation characteristics of the solid-state erbium:yttrium aluminum garnet laser were compared to those of the carbon dioxide laser. Ablations of fresh, frozen cadaver septal cartilage and maxillary sinus bone were performed using total energies between 1 and 6 J. Specimens were studied using hematoxylin and eosin stain and digitized, computer-assisted measurements of 35-mm photographs. Erbium-yttrium aluminum garnet-ablated bone averaged 5 microns of adjacent tissue thermal injury, compared with 67 microns with carbon dioxide-ablated bone. Erbium-yttrium aluminum garnet-ablated cartilage averaged 2 microns of adjacent tissue thermal injury, compared with 21 microns with the carbon dioxide-ablated cartilage. The tissue-ablation characteristics of the erbium-yttrium aluminum garnet laser are promising for future otolaryngologic applications.

  13. Coupling of erbium dopants to yttrium orthosilicate photonic crystal cavities for on-chip optical quantum memories

    NASA Astrophysics Data System (ADS)

    Miyazono, Evan; Zhong, Tian; Craiciu, Ioana; Kindem, Jonathan M.; Faraon, Andrei

    2016-01-01

    Erbium dopants in crystals exhibit highly coherent optical transitions well suited for solid-state optical quantum memories operating in the telecom band. Here, we demonstrate coupling of erbium dopant ions in yttrium orthosilicate to a photonic crystal cavity fabricated directly in the host crystal using focused ion beam milling. The coupling leads to reduction of the photoluminescence lifetime and enhancement of the optical depth in microns-long devices, which will enable on-chip quantum memories.

  14. Lithium cell test results

    NASA Technical Reports Server (NTRS)

    Bragg, B. J.

    1977-01-01

    Three lithium SO2 cells, two lithium CF cells, and a vinyl chloride cell, all with crimped seals, and all strictly experimental, were independently discharged on resistors. Three temperatures were used and several different storage temperatures. Discharge rate generally on the nominal discharges were 0.1 amp, 0.5 amp, and 1 amp. Tests results show that the crimp seals are inadequate, especially for the SO2 cells. Normal discharges present no hazards. All cells discharge to zero. The problem of lithium cell explosions, such as occurred during off-limits testing, is discussed.

  15. Lithium Dendrite Formation

    SciTech Connect

    2015-03-06

    Scientists at the Department of Energy’s Oak Ridge National Laboratory have captured the first real-time nanoscale images of lithium dendrite structures known to degrade lithium-ion batteries. The ORNL team’s electron microscopy could help researchers address long-standing issues related to battery performance and safety. Video shows annular dark-field scanning transmission electron microscopy imaging (ADF STEM) of lithium dendrite nucleation and growth from a glassy carbon working electrode and within a 1.2M LiPF6 EC:DM battery electrolyte.

  16. Lithium metal oxide electrodes for lithium batteries

    DOEpatents

    Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil; Kang, Sun-Ho

    2010-06-08

    An uncycled preconditioned electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula xLi.sub.2-yH.sub.yO.xM'O.sub.2.(1-x)Li.sub.1-zH.sub.zMO.sub.2 in which 0lithium metal ion with an average trivalent oxidation state selected from two or more of the first row transition metals or lighter metal elements in the periodic table, and M' is one or more ions with an average tetravalent oxidation state selected from the first and second row transition metal elements and Sn. The xLi.sub.2-yH.sub.y.xM'O.sub.2.(1-x)Li.sub.1-zH.sub.zMO.sub.2 material is prepared by preconditioning a precursor lithium metal oxide (i.e., xLi.sub.2M'O.sub.3.(1-x)LiMO.sub.2) with a proton-containing medium with a pH<7.0 containing an inorganic acid. Methods of preparing the electrodes are disclosed, as are electrochemical cells and batteries containing the electrodes.

  17. Development of erbium phosphate doped poly(glycidyl methacrylate/ethylene dimethacrylate) spin columns for selective enrichment of phosphopeptides.

    PubMed

    Güzel, Yüksel; Rainer, Matthias; Messner, Christoph B; Hussain, Shah; Meischl, Florian; Sasse, Michael; Tessadri, Richard; Bonn, Günther K

    2015-05-01

    In this study, a novel method for the highly selective enrichment of phosphopeptides using erbium phosphate doped poly(glycidyl methacrylate/ethylene dimethacrylate) spin columns is presented. Erbium phosphate was synthesized by precipitation from boiling phosphoric acid and incubated overnight in erbium chloride solutions. The resulting powder was embedded in a monolithic poly(glycidyl methacrylate/ethylene dimethacrylate) polymer. The monolith was synthesized in a spin column by radical polymerization. Erbium phosphate demonstrated a high affinity and selectivity for phosphopeptides due to the strong interaction of trivalent erbium ions with the phosphate groups of phosphopeptides. The high selectivity and performance of the designed spin columns were demonstrated by successfully enriching phosphopeptides from tryptically digested protein mixtures containing the model phosphoproteins α- and β-casein, bovine milk, and human saliva. By the implementation of several washing steps, unspecific components were removed and the enriched phosphopeptides were effectively eluted from the spin columns under alkaline conditions. The selective performance of the presented method was further demonstrated by the enrichment of two synthetic phosphopeptides, which were spiked in tryptically digested and dephosphorylated HeLa cell lysates at low ratios. Finally, the presented approach was compared to conventional phosphopeptide enrichment by titanium oxide and revealed higher recoveries for the erbium phosphate doped monoliths. PMID:25645427

  18. Periodontal and peri-implant wound healing following laser therapy.

    PubMed

    Aoki, Akira; Mizutani, Koji; Schwarz, Frank; Sculean, Anton; Yukna, Raymond A; Takasaki, Aristeo A; Romanos, Georgios E; Taniguchi, Yoichi; Sasaki, Katia M; Zeredo, Jorge L; Koshy, Geena; Coluzzi, Donald J; White, Joel M; Abiko, Yoshimitsu; Ishikawa, Isao; Izumi, Yuichi

    2015-06-01

    Laser irradiation has numerous favorable characteristics, such as ablation or vaporization, hemostasis, biostimulation (photobiomodulation) and microbial inhibition and destruction, which induce various beneficial therapeutic effects and biological responses. Therefore, the use of lasers is considered effective and suitable for treating a variety of inflammatory and infectious oral conditions. The CO2 , neodymium-doped yttrium-aluminium-garnet (Nd:YAG) and diode lasers have mainly been used for periodontal soft-tissue management. With development of the erbium-doped yttrium-aluminium-garnet (Er:YAG) and erbium, chromium-doped yttrium-scandium-gallium-garnet (Er,Cr:YSGG) lasers, which can be applied not only on soft tissues but also on dental hard tissues, the application of lasers dramatically expanded from periodontal soft-tissue management to hard-tissue treatment. Currently, various periodontal tissues (such as gingiva, tooth roots and bone tissue), as well as titanium implant surfaces, can be treated with lasers, and a variety of dental laser systems are being employed for the management of periodontal and peri-implant diseases. In periodontics, mechanical therapy has conventionally been the mainstream of treatment; however, complete bacterial eradication and/or optimal wound healing may not be necessarily achieved with conventional mechanical therapy alone. Consequently, in addition to chemotherapy consisting of antibiotics and anti-inflammatory agents, phototherapy using lasers and light-emitting diodes has been gradually integrated with mechanical therapy to enhance subsequent wound healing by achieving thorough debridement, decontamination and tissue stimulation. With increasing evidence of benefits, therapies with low- and high-level lasers play an important role in wound healing/tissue regeneration in the treatment of periodontal and peri-implant diseases. This article discusses the outcomes of laser therapy in soft-tissue management, periodontal

  19. Lithium drifted germanium system

    NASA Technical Reports Server (NTRS)

    Fjarlie, E. J.

    1969-01-01

    General characteristics of the lithium-drifted germanium photodiode-Dewar-preamplifier system and particular operating instructions for the device are given. Information is included on solving operational problems.

  20. APPARATUS FOR THE PRODUCTION OF LITHIUM METAL

    DOEpatents

    Baker, P.S.; Duncan, F.R.; Greene, H.B.

    1961-08-22

    Methods and apparatus for the production of high-purity lithium from lithium halides are described. The apparatus is provided for continuously contacting a molten lithium halide with molten barium, thereby forming lithium metal and a barium halide, establishing separate layers of these reaction products and unreacted barium and lithium halide, and continuously withdrawing lithium and barium halide from the reaction zone. (AEC)

  1. Scoping studies: behavior and control of lithium and lithium aerosols

    SciTech Connect

    Jeppson, D W

    1982-01-01

    The HEDL scoping studies examining the behavior of lithium and lithium aerosols have been conducted to determine and examine potential safety and environmental issues for postulated accident conditions associated with the use of lithium as a fusion reactor blanket and/or coolant. Liquid lithium reactions with air, nitrogen, carbon dioxide and concretes have been characterized. The effectiveness of various powder extinguishing agents and methods of application were determined for lithium-air reactions. The effectiveness of various lithium aerosol collection methods were determined and the volatilization and transport of radioactive metals potentially associated with lithium-air reactions were evaluated. Liquid lithium atmosphere reactions can be safely controlled under postulated accident conditions, but special handling practices must be provided. Lithium-concrete reactions should be avoided because of the potential production of high temperatures, corrosive environment and hydrogen. Carbon microspheres are effective in extinguishing well established lithium-air reactions for the lithium quantities tested (up to 10 kg). Large mass loading of lithium aerosols can be efficiently collected with conventional air cleaning systems. Potentially radioactive species (cobalt, iron and manganese) will be volatilized in a lithium-air reaction in contact with neutron activated stainless steel.

  2. Lithium battery management system

    DOEpatents

    Dougherty, Thomas J.

    2012-05-08

    Provided is a system for managing a lithium battery system having a plurality of cells. The battery system comprises a variable-resistance element electrically connected to a cell and located proximate a portion of the cell; and a device for determining, utilizing the variable-resistance element, whether the temperature of the cell has exceeded a predetermined threshold. A method of managing the temperature of a lithium battery system is also included.

  3. Lithium to the Rescue.

    PubMed

    Jope, Richard S; Nemeroff, Charles B

    2016-01-01

    Lithium, an element that Mother Nature has put in some drinking water sources, has been used for its curative powers for centuries. Today, it's given in capsule form as a mood stabilizer for bipolar disorder and depression. New research, however, reveals its role as a neuroprotector, and suggests that a better understanding of the role enzymes modulated by lithium play could lead to new treatments for Alzheimer's disease, Parkinson's disease, multiple sclerosis, and other neurodegenerative disorders. PMID:27408673

  4. Solid-state lithium battery

    SciTech Connect

    Ihlefeld, Jon; Clem, Paul G; Edney, Cynthia; Ingersoll, David; Nagasubramanian, Ganesan; Fenton, Kyle Ross

    2014-11-04

    The present invention is directed to a higher power, thin film lithium-ion electrolyte on a metallic substrate, enabling mass-produced solid-state lithium batteries. High-temperature thermodynamic equilibrium processing enables co-firing of oxides and base metals, providing a means to integrate the crystalline, lithium-stable, fast lithium-ion conductor lanthanum lithium tantalate (La.sub.1/3-xLi.sub.3xTaO.sub.3) directly with a thin metal foil current collector appropriate for a lithium-free solid-state battery.

  5. Real-time synchrotoron radiation X-ray diffraction and abnormal temperature dependence of photoluminescence from erbium silicates on SiO{sub 2}/Si substrates

    SciTech Connect

    Omi, H.; Tawara, T.; Tateishi, M.

    2012-03-15

    The erbium silicate formation processes during annealing in Ar gas were monitored by synchrotron radiation grazing incidence X-ray diffraction (GIXD) in real time and the optical properties of the silicates were investigated by photoluminescence measurements in spectral and time-resolved domains. The GIXD measurements show that erbium silicates and erbium oxide are formed by interface reactions between silicon oxide and erbium oxides deposited on silicon oxide by reactive sputtering in Ar gas and O{sub 2}/Ar mixture gas ambiences. The erbium silicates are formed above 1060 degree sign C in Ar gas ambience and above 1010 degree sign C in O{sub 2}/Ar gas ambience, and erbium silicides are dominantly formed above 1250 degree sign C. The I{sub 15/2}-I{sub 13/2} Er{sup 3+} photoluminescence from the erbium oxide and erbium silicate exhibits abnormal temperature dependence, which can be explained by the phonon-assisted resonant absorption of the 532-nm excitation photons into the {sup 2}H{sub 11/2} levels of Er{sup 3+} ions of the erbium compounds.

  6. Retrograde peri-implantitis.

    PubMed

    Mohamed, Jumshad B; Shivakumar, B; Sudarsan, Sabitha; Arun, K V; Kumar, T S S

    2010-01-01

    Retrograde peri-implantitis constitutes an important cause for implant failure. Retrograde peri-implantitis may sometimes prove difficult to identify and hence institution of early treatment may not be possible. This paper presents a report of four cases of (the implant placed developing to) retrograde peri-implantitis. Three of these implants were successfully restored to their fully functional state while one was lost due to extensive damage. The paper highlights the importance of recognizing the etiopathogenic mechanisms, preoperative assessment, and a strong postoperative maintenance protocol to avoid retrograde peri-implant inflammation. PMID:20922082

  7. Hydrogen Outgassing from Lithium Hydride

    SciTech Connect

    Dinh, L N; Schildbach, M A; Smith, R A; Balazs1, B; McLean II, W

    2006-04-20

    Lithium hydride is a nuclear material with a great affinity for moisture. As a result of exposure to water vapor during machining, transportation, storage and assembly, a corrosion layer (oxide and/or hydroxide) always forms on the surface of lithium hydride resulting in the release of hydrogen gas. Thermodynamically, lithium hydride, lithium oxide and lithium hydroxide are all stable. However, lithium hydroxides formed near the lithium hydride substrate (interface hydroxide) and near the sample/vacuum interface (surface hydroxide) are much less thermally stable than their bulk counterpart. In a dry environment, the interface/surface hydroxides slowly degenerate over many years/decades at room temperature into lithium oxide, releasing water vapor and ultimately hydrogen gas through reaction of the water vapor with the lithium hydride substrate. This outgassing can potentially cause metal hydriding and/or compatibility issues elsewhere in the device. In this chapter, the morphology and the chemistry of the corrosion layer grown on lithium hydride (and in some cases, its isotopic cousin, lithium deuteride) as a result of exposure to moisture are investigated. The hydrogen outgassing processes associated with the formation and subsequent degeneration of this corrosion layer are described. Experimental techniques to measure the hydrogen outgassing kinetics from lithium hydride and methods employing the measured kinetics to predict hydrogen outgassing as a function of time and temperature are presented. Finally, practical procedures to mitigate the problem of hydrogen outgassing from lithium hydride are discussed.

  8. Modelling of micromachining of human tooth enamel by erbium laser radiation

    NASA Astrophysics Data System (ADS)

    Belikov, A. V.; Skrypnik, A. V.; Shatilova, K. V.

    2014-08-01

    We consider a 3D cellular model of human tooth enamel and a photomechanical cellular model of enamel ablation by erbium laser radiation, taking into account the structural peculiarities of enamel, energy distribution in the laser beam cross section and attenuation of laser energy in biological tissue. The surface area of the texture in enamel is calculated after its micromachining by erbium laser radiation. The influence of the surface area on the bond strength of enamel with dental filling materials is discussed. A good correlation between the computer simulation of the total work of adhesion and experimentally measured bond strength between the dental filling material and the tooth enamel after its micromachining by means of YAG : Er laser radiation is attained.

  9. Few-mode erbium-doped fiber amplifier with photonic lantern for pump spatial mode control.

    PubMed

    Lopez-Galmiche, G; Sanjabi Eznaveh, Z; Antonio-Lopez, J E; Velazquez Benitez, A M; Rodriguez Asomoza, J; Sanchez Mondragon, J J; Gonnet, C; Sillard, P; Li, G; Schülzgen, A; Okonkwo, C M; Amezcua Correa, R

    2016-06-01

    We demonstrate a few-mode erbium-doped fiber amplifier employing a mode-selective photonic lantern for controlling the modal content of the pump light. Amplification of six spatial modes in a 5 m long erbium-doped fiber to ∼6.2  dBm average power is obtained while maintaining high modal fidelity. Through mode-selective forward pumping of the two degenerate LP21 modes operating at 976 nm, differential modal gains of <1  dB between all modes and signal gains of ∼16  dB at 1550 nm are achieved. In addition, low differential modal gain for near-full C-band operation is demonstrated. PMID:27244421

  10. Invariant bandwidth of erbium in ZnO-PbO-tellurite glasses: Local probe/model

    SciTech Connect

    Ramamoorthy, Raj Kumar; Bhatnagar, Anil K.

    2014-04-24

    A series of [(70TeO{sub 2}−(30−x)ZnO−xPbO){sub 0.99}−(Er{sub 2}O{sub 3}){sub 0.01}; where x = 5, 10, 15 and 20] tellurite glasses, were prepared using the melt quenching technique. Crucial emission bandwidth of erbium at 1.5 μm has been derived and found to be the same for all the glasses, irrespective of PbO content. This identical bandwidth in all tellurite glasses is attributed to the presence of erbium in tellurium rich disordered environments. This result has been complemented through XANES spectra and the obtained invariant first shell of 6.5 oxygen atoms, confirm the unchanged environment in these glasses for all PbO content.

  11. Opportunities for Low Cost Processing of Erbium 8-Quinolinolates for Active Integrated Photonic Applications.

    PubMed

    Penna, Stefano; Mattiello, Leonardo; Di Bartolo, Silvia; Pizzoleo, Angelo; Attanasio, Vincenzo; Beleffi, Giorgio Maria Tosi; Otomo, Akira

    2016-04-01

    Erbium-doped organic emitters are promising active materials for Photonic Integrated Circuits (PICs) due to their emission shown at 1550 nm combined to the potential low cost processing. In particular, Erbium Quinoline (ErQ) gained a strong interest in the last decade for the good emission efficiency. This contribution reports the results derived from the application of ErQ as active core material within a buried optical waveguide, following the development of a purposed optical process to control the refractive index of ErQ and then to define a patterned structure from a single thin film deposition step. The reported results show the potential of Er-doped organic materials for low cost processing and application to planar PICs. PMID:27451632

  12. Modelling of micromachining of human tooth enamel by erbium laser radiation

    SciTech Connect

    Belikov, A V; Skrypnik, A V; Shatilova, K V

    2014-08-31

    We consider a 3D cellular model of human tooth enamel and a photomechanical cellular model of enamel ablation by erbium laser radiation, taking into account the structural peculiarities of enamel, energy distribution in the laser beam cross section and attenuation of laser energy in biological tissue. The surface area of the texture in enamel is calculated after its micromachining by erbium laser radiation. The influence of the surface area on the bond strength of enamel with dental filling materials is discussed. A good correlation between the computer simulation of the total work of adhesion and experimentally measured bond strength between the dental filling material and the tooth enamel after its micromachining by means of YAG : Er laser radiation is attained. (laser biophotonics)

  13. Effect of holmium and erbium laser action on the human lens: an in-vitro study

    NASA Astrophysics Data System (ADS)

    Kasprzak, Jan; Kecik, Dariusz

    1997-10-01

    We investigated the holmium and erbium lasers operating at the medium IR range, used for cataract surgery. The main advantage of these lasers action on biological structures is total absorption of radiation by superficial layers. During the study of the lens emulsification process we found that the mechanical properties of the lens nucleus were of crucial importance for the rate of emulsification. The soft lenses were fragmented and emulsified after 200-700 pulses, while the hard lens required 5000 or more pulses while complete emulsification was not achieved. The results are promising and show that the holmium and erbium lasers can be used for human lens emulsification during ECCE. For clinical purposes, however, it is necessary to construct a suitable fiberoptic tip to be used in cataract removal. It seems that lasers whose beam is in the medium IR range could be used in many ophthalmic operations.

  14. Simulation of an erbium-doped chalcogenide micro-disk mid-infrared laser source.

    PubMed

    Al Tal, Faleh; Dimas, Clara; Hu, Juejun; Agarwal, Anu; Kimerling, Lionel C

    2011-06-20

    The feasibility of mid-infrared (MIR) lasing in erbium-doped gallium lanthanum sulfide (GLS) micro-disks was examined. Lasing condition at 4.5 µm signal using 800 nm pump source was simulated using rate equations, mode propagation and transfer matrix formulation. Cavity quality (Q) factors of 1.48 × 10(4) and 1.53 × 10(6) were assumed at the pump and signal wavelengths, respectively, based on state-of-the-art chalcogenide micro-disk resonator parameters. With an 80 µm disk diameter and an active erbium concentration of 2.8 × 10(20) cm(-3), lasing was shown to be possible with a maximum slope efficiency of 1.26 × 10(-4) and associated pump threshold of 0.5 mW. PMID:21716429

  15. High-performance air-stable n-type carbon nanotube transistors with erbium contacts.

    PubMed

    Shahrjerdi, Davood; Franklin, Aaron D; Oida, Satoshi; Ott, John A; Tulevski, George S; Haensch, Wilfried

    2013-09-24

    So far, realization of reproducible n-type carbon nanotube (CNT) transistors suitable for integrated digital applications has been a difficult task. In this work, hundreds of n-type CNT transistors from three different low work function metals-erbium, lanthanum, and yttrium-are studied and benchmarked against p-type devices with palladium contacts. The crucial role of metal type and deposition conditions is elucidated with respect to overall yield and performance of the n-type devices. It is found that high oxidation rates and sensitivity to deposition conditions are the major causes for the lower yield and large variation in performance of n-type CNT devices with low work function metal contacts. Considerable improvement in device yield is attained using erbium contacts evaporated at high deposition rates. Furthermore, the air-stability of our n-type transistors is studied in light of the extreme sensitivity of these metals to oxidation. PMID:24006886

  16. Reflection L-band erbium-doped fiber-amplifier-based fiber loop mirror

    NASA Astrophysics Data System (ADS)

    Meng, Hongyun; Liu, Songhao; Dong, Xiaoyi

    2005-01-01

    We constructed a reflection L-band erbium-doped fiber amplifier based on fiber loop mirror, which reflects the backward ASE to the EDF as a secondary pumping source. A gain of 30 dB increased 6 dB compared to the forward end-pumped EDFA has been achieved in the wavelength region from 1570 to 1603 nm. In order to improve the gain and NF further, we constructed a novel configuration for reflection L-band erbium-doped fiber amplifier via inserting a 980 nm LD in the input part. Adjusting the ratio of power of the two LDs, the gain and NF are greatly improved in different degree in the region from 1565 to 1615 nm. Compared to the configuration pumped by only 1480 nm LD with given power, the gain enhanced 1.5-9.9 dB and the NF decreases 1.3-9.4 dB.

  17. Erbium:YAG laser incision of urethral strictures: early clinical results

    NASA Astrophysics Data System (ADS)

    Munoz, John A.; Riemer, Jennifer D.; Hayes, Gary B.; Negus, Dan; Fried, Nathaniel M.

    2007-02-01

    Two cases involving Erbium:YAG laser incision of proximal bulbar urethral strictures are described. Erbium:YAG laser radiation with a wavelength of 2.94 μm, pulse energy of 10 mJ, and a pulse repetition rate of 15 Hz, was delivered through a 2-m-long, 250-μm-core sapphire optical fiber in contact with tissue. Total laser irradiation time was 5 min. The first patient suffering from a virgin urethral stricture was treated and is stricture-free. The second patient suffering from a recurrent urethral stricture required further treatment. This case report describes the first clinical application of the Er:YAG laser in urology.

  18. A Room-Temperature Multiwavelength Erbium-Doped Fibre Laser by Exploiting Polarization Hole Burning

    NASA Astrophysics Data System (ADS)

    Zhang, Hao; Xiong, Ling-Yun; Dou, Qing-Ying; Li, Yao; Yu, Ling; Liu, Yan-Ge; Liu, Li-Hui; Yuan, Shu-Zhong; Kai, Gui-Yun; Dong, Xiao-Yi

    2005-01-01

    Multiwavelength operation of a linear cavity erbium-doped fibre laser (EDFL) is proposed and demonstrated. A 3-dB fibre loop mirror and a high birefringence (HiBi) fibre loop mirror are utilized as the cavity reflectors. By utilizing the wavelength-dependent polarization rotation induced by the HiBi fibre loop mirror and by using a fibre polarizer to control the intracavity polarization state, the polarization states of different wavelengths are diversified. Therefore, the polarization hole burning (PHB) effect has been greatly enhanced and the homogeneous broadening of erbium-doped fibre is suppressed to a large extent. By simply tuning a polarization controller, we experimentally obtained simultaneous lasing of four and five wavelengths with wavelength spacing of ~1.8 nm and less than 2 nm at room temperature, respectively. The repeated scans show that all of these lasers have good stability.

  19. Fibre-end micro-lens system for endoscopic erbium-laser surgery applications

    NASA Astrophysics Data System (ADS)

    Heifer, D.; Frenz, M.; Romano, V.; Weber, H. P.

    1994-04-01

    A sapphire micro-lens system in combination with a zirconium-fluoride (ZrF4) fibre has been designed and constructed as a surgical tool for focusing Er:YAG-laser radiation. It both refocuses the laser radiation transmitted through a 350 µm core fibre to a spot diameter of 570 µm at a working distance of 7.6 mm, and protects the distal fibre end from damage. An accurate and uncomplicated visualization of the focus position of the erbium-laser beam is realized by coupling a HeNe aiming laser into the cladding of the fibre. In vitro cutting experiments reveal the high cutting precision with minimal thermal damage of the surrounding tissue and the high damage resistance of the system. It may render the use of the erbium laser possible in a wide range of endoscopic applications.

  20. Double Brillouin frequency spaced multiwavelength Brillouin-erbium fiber laser with 50 nm tuning range

    NASA Astrophysics Data System (ADS)

    Zhao, J. F.; Liao, T. Q.; Zhang, C.; Zhang, R. X.; Miao, C. Y.; Tong, Z. R.

    2012-09-01

    A 50 nm tuning range multiwavelength Brillouin-erbium fiber laser (MWBEFL) with double Brillouin frequency spacing is presented. Two separated gain blocks with symmetrical architecture, consisted by erbium-doped fiber amplifiers (EDFAs) and Brillouin gain media, are used to generate double Brillouin frequency spacing. The wider tuning range is realized by eliminating the self-lasing cavity modes existing in conventional MWBEFLs because of the absence of the physical mirrors at the ends of the linear cavity. The Brillouin pump (BP) is preamplified by the EDFA before entering the single-mode fiber (SMF), which leads to the reduction of threshold power and the generation enhancement of Brillouin Stokes (BS) signals. Four channels with 0.176 nm spacing are achieved at 2 mW BP power and 280 mW 980 nm pump power which can be tuned from 1525 to 1575 nm.

  1. Healing of bone in the rat following surgery with the erbium-YAG laser

    NASA Astrophysics Data System (ADS)

    Dickinson, Mark R.; Devlin, Hugh; El Montaser, Monsour A.; Sloan, Philip

    1996-12-01

    Background and objectives: the aim of this study was to examine the pattern of healing in rat calvarial defects prepared with the erbium-YAG laser, using the 'guided tissue regeneration' technique. Materials and method: PTFE membranes were placed over lased skull defects, and the skin wounds sutured. Rats were killed humanely at intervals after surgery, and the skulls processed for paraffin wax histology. A further group of mature rats were also killed humanely and the calvariae removed. Slots were prepared using the erbium-YAG laser and immediately examined under the environmental scanning electron microscope (ESEM) in hydrated conditions, which avoided drying artifacts. Results: An amorphous, mineral-rich carbon layer surrounds the lased bone defect, which in the in vivo experiments was seen as a basophilic zone which was resistant to resorption.

  2. Biomimetic synthesis of chiral erbium-doped silver/peptide/silica core-shell nanoparticles (ESPN).

    PubMed

    Mantion, Alexandre; Graf, Philipp; Florea, Ileana; Haase, Andrea; Thünemann, Andreas F; Mašić, Admir; Ersen, Ovidiu; Rabu, Pierre; Meier, Wolfgang; Luch, Andreas; Taubert, Andreas

    2011-12-01

    Peptide-modified silver nanoparticles have been coated with an erbium-doped silica layer using a method inspired by silica biomineralization. Electron microscopy and small-angle X-ray scattering confirm the presence of an Ag/peptide core and silica shell. The erbium is present as small Er(2)O(3) particles in and on the silica shell. Raman, IR, UV-Vis, and circular dichroism spectroscopies show that the peptide is still present after shell formation and the nanoparticles conserve a chiral plasmon resonance. Magnetic measurements find a paramagnetic behavior. In vitro tests using a macrophage cell line model show that the resulting multicomponent nanoparticles have a low toxicity for macrophages, even on partial dissolution of the silica shell. PMID:22031101

  3. Coupling erbium spins to a three-dimensional superconducting cavity at zero magnetic field

    NASA Astrophysics Data System (ADS)

    Chen, Yu-Hui; Fernandez-Gonzalvo, Xavier; Longdell, Jevon J.

    2016-08-01

    We experimentally demonstrate the coupling at zero magnetic field of an isotopically pure erbium-doped yttrium orthosilicate crystal (167Er:YSO ) to a three-dimensional superconducting cavity with a Q factor of 105. A tunable loop-gap resonator is used and its resonance frequency is tuned to observe the hyperfine transitions of the erbium sample. The observed spectrum differs from what is predicted by the published spin Hamiltonian parameters. The narrow cavity linewidth also enables the observation of asymmetric line shapes for these hyperfine transitions. Such a broadly tunable superconducting cavity (from 1.6 to 4.0 GHz in the current design) is a promising device for building hybrid quantum systems.

  4. Space radiation effects on erbium-doped fiber devices: Sources, amplifiers and passive measurements

    SciTech Connect

    Williams, G.M. |; Friebele, E.J.

    1998-06-01

    Measurements have been made of the effect of {gamma}-irradiation on the performance of active erbium-doped fiber devices. These include the decrease in optical power of an erbium-doped fiber amplifier (EDFA) and a superluminescent source (SLS), and the shift in centroid wavelength of the SLS with exposure. Calculations have been performed to correlate these effects with the radiation-induced absorption measured passively. Excellent agreement was obtained for the radiation-induced power loss in the EDFA, and a good agreement was obtained for the SLS. However, the calculation underestimated the centroid wavelength shift in the SLS by a factor of {approximately}3. A model has been developed to extrapolate the results of passive loss measurements to the low dose rates typical of the natural space environment.

  5. Multiwavelength Brillouin-erbium fiber laser with double-Brillouin-frequency spacing.

    PubMed

    Shee, Y G; Al-Mansoori, M H; Ismail, A; Hitam, S; Mahdi, M A

    2011-01-31

    We demonstrate a multiwavelength Brillouin-erbium fiber laser with double-Brillouin-frequency spacing. The wider channel spacing is realized by circulating the odd-order Stokes signals in the Brillouin gain medium through a four-port circulator. The circulated odd-order Stokes signals are amplified by the Brillouin gain and thus produce even-order Stokes signals at the output. These signals are then amplified by erbium gain block to form a ring-cavity laser. Ten channels with 0.174 nm spacing that are generated at 0.5 mW Brillouin pump power and 150 mW pump power at 1480 nm can be tuned from 1556 nm to 1564 nm. The minimum optical signal-to-noise ratio of the generated output channels is 30 dB with maximum power fluctuations of ±0.5 dB. PMID:21368983

  6. Generation of efficient 20 GHz optical combs in a Brillouin-erbium fiber laser

    NASA Astrophysics Data System (ADS)

    Parvizi, R.; Shahabuddin, N. S.; Ali, N. M.; Harun, S. W.; Emami, S. D.; Vaseghi, B.; Ahmad, H.

    2013-01-01

    A tunable multiwavelength Brillouin-erbium fiber laser is experimentally demonstrated with a double-Brillouin-frequency spacing. This double-frequency shifter is constructed by incorporating a four-port circulator to isolate and circulate the odd-Stokes signals through the 10 km long non-zero dispersion shifted fiber, which acts as a Brillouin gain medium. The output even-order Stokes signals are amplified in the erbium gain block formed in a ring cavity. Up to 15 lasing lines with a wavelength spacing of 0.173 nm have been achieved at a 980 nm pump power of 50 mW and a Brillouin pump of 3 dB m. The multiwavelength laser source exhibits a 10 nm tuning range from 1552 to 1562 nm with the optical signal-to-noise ratio of the desired output channels at around 34.5 dB.

  7. Erbium-doped spiral amplifiers with 20 dB of net gain on silicon.

    PubMed

    Vázquez-Córdova, Sergio A; Dijkstra, Meindert; Bernhardi, Edward H; Ay, Feridun; Wörhoff, Kerstin; Herek, Jennifer L; García-Blanco, Sonia M; Pollnau, Markus

    2014-10-20

    Spiral-waveguide amplifiers in erbium-doped aluminum oxide on a silicon wafer are fabricated and characterized. Spirals of several lengths and four different erbium concentrations are studied experimentally and theoretically. A maximum internal net gain of 20 dB in the small-signal-gain regime is measured at the peak emission wavelength of 1532 nm for two sample configurations with waveguide lengths of 12.9 cm and 24.4 cm and concentrations of 1.92 × 10(20) cm(-3) and 0.95 × 10(20) cm(-3), respectively. The noise figures of these samples are reported. Gain saturation as a result of increasing signal power and the temperature dependence of gain are studied. PMID:25401633

  8. Dynamic Fano-like resonances in erbium-doped whispering-gallery-mode microresonators

    SciTech Connect

    Lei, Fuchuan; Peng, Bo; Özdemir, Şahin Kaya Yang, Lan; Long, Gui Lu

    2014-09-08

    We report Fano-like asymmetric resonances modulated by optical gain in a whispering-gallery-mode resonator fabricated from erbium-doped silica. A time-dependent gain profile leads to dynamically varying sharp asymmetric resonances with features similar to Fano resonances. Depending on the scan speed of the frequency of the probe laser and the pump-probe power ratio, transmission spectra of the active microcavity exhibit a resonance dip, a resonance peak, or a Fano-like resonance.

  9. Synthesis and characterization of erbium-doped YAlO3 phosphor.

    PubMed

    Baig, Huma Nazli; Saluja, Jagjeet Kaur; Dhoble, S J

    2016-03-01

    In the yttrium aluminium system, the YAlO3 phosphor is a prominent host because of the yttrium aluminium ratio (1:1). Phosphor was synthesized by the solid-state reaction method at variable concentrations of erbium (0.1-2.5 mol%). This method is suitable for large-scale production and is a less time-consuming method when compared with the soft synthesis method. The prepared sample was characterized by X-ray diffraction technique and the crystallite size was calculated by Scherer's formula. Vibrational and bending analysis of prepared phosphor for optimized concentration of erbium ion is described based on the Fourier transform infrared spectroscopic technique. The photoluminescence (PL) emission spectra of prepared phosphor for variable concentrations of erbium ion were recorded and the excitation spectrum was found to be at 291 nm with three shoulder peaks at 305, 270 and 242 nm. For 291 nm excitation, the emission spectrum was found at 546 nm and 552 nm. PL intensity increased with increasing concentrations of erbium and after 2 mol% emission intensity decreased due to concentration quenching. Spectrophotometric determination of YAlO3:Er(3+) is described by CIE co-ordinates and shows an intense emission in the green region such that the prepared phosphor can act as a single host for green light emission. Thermoluminescence glow curve analysis of the YAlO3:Er(3+) phosphor was recorded for different ultraviolet (UV) light exposures and gamma exposure. Different gamma doses 0.5-2 kGy show a linear response. Kinetic parameters were calculated by the peak shape method. PMID:26455914

  10. Theoretical explanation of enhanced low dose rate sensitivity in erbium-doped optical fibers.

    PubMed

    Gilard, Olivier; Thomas, Jérémie; Troussellier, Laurent; Myara, Mikhael; Signoret, Philippe; Burov, Ekaterina; Sotom, Michel

    2012-05-01

    A new theoretical framework is proposed to explain the dose and dose-rate dependence of radiation-induced absorption in optical fibers. A first-order dispersive kinetics model is used to simulate the growth of the density of color centers during an irradiation. This model succeeds in explaining the enhanced low dose rate sensitivity observed in certain kinds of erbium-doped optical fiber and provides some insight into the physical reasons behind this sensitivity. PMID:22614396