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Sample records for evaporating fuel sprays

  1. Accurate analysis of multicomponent fuel spray evaporation in turbulent flow

    NASA Astrophysics Data System (ADS)

    Rauch, Bastian; Calabria, Raffaela; Chiariello, Fabio; Le Clercq, Patrick; Massoli, Patrizio; Rachner, Michael

    2012-04-01

    The aim of this paper is to perform an accurate analysis of the evaporation of single component and binary mixture fuels sprays in a hot weakly turbulent pipe flow by means of experimental measurement and numerical simulation. This gives a deeper insight into the relationship between fuel composition and spray evaporation. The turbulence intensity in the test section is equal to 10%, and the integral length scale is three orders of magnitude larger than the droplet size while the turbulence microscale (Kolmogorov scales) is of same order as the droplet diameter. The spray produced by means of a calibrated droplet generator was injected in a gas flow electrically preheated. N-nonane, isopropanol, and their mixtures were used in the tests. The generalized scattering imaging technique was applied to simultaneously determine size, velocity, and spatial location of the droplets carried by the turbulent flow in the quartz tube. The spray evaporation was computed using a Lagrangian particle solver coupled to a gas-phase solver. Computations of spray mean diameter and droplet size distributions at different locations along the pipe compare very favorably with the measurement results. This combined research tool enabled further investigation concerning the influencing parameters upon the evaporation process such as the turbulence, droplet internal mixing, and liquid-phase thermophysical properties.

  2. Convective Evaporation Of Sprayed Liquid

    NASA Technical Reports Server (NTRS)

    Bellan, Josette; Harstad, Kenneth G.

    1987-01-01

    Theoretical model developed to analyze behavior of both dense and dilute clusters of evaporating liquid drops in gas flows. Particularly useful in search for methods of controlling evaporation, ignition, and combustion of fuel sprays.

  3. Characterization of Liquid Fuel Evaporation of a Lifted Methanol Spray Flame in a Vitiated Coflow Burner

    NASA Technical Reports Server (NTRS)

    Cabra, Ricardo; Dibble, Robert W.; Chen, Jyh-Yuan

    2002-01-01

    An experimental investigation of lifted spray flames in a coflow of hot, vitiated gases is presented. The vitiated coflow burner is a spray flame that issues into a coaxial flow of hot combustion products from a lean, premixed H2/Air flame. The spray flame in a vitiated coflow emulates the combustion that occurs in many advanced combustors without the detailed fluid mechanics. Two commercially available laser diagnostic systems are used to characterize the spray flame and to demonstrate the vitiated coflow burner's amenability to optical investigation. The Ensemble Particle Concentration and Size (EPCS) system is used to measure the path-average droplet size distribution and liquid volume fraction at several axial locations while an extractive probe instrument named the Real-time Fuel-air Analyzer (RFA) is used to measure the air to fuel ratio downstream of the spray nozzle with high temporal and spatial resolution. The effect of coflow conditions (stoichiometry) and dilution of the fuel with water was studied with the EPCS optical system. As expected, results show that water retards the evaporation and combustion of fuels. Measurements obtained by the RFA extractive probe show that while the Delavan manufactured nozzle does distribute the fuel over the manufacturer specified spray angle, it unfortunately does not distribute the fuel uniformly, providing conditions that may result in the production of unwanted NOx. Despite some limitations due to the inherent nature of the experimental techniques, the two diagnostics can be readily applied to spray flames in the vitiated coflow environment.

  4. Quantitative fuel vapor/air mixing imaging in droplet/gas regions of an evaporating spray flow using filtered Rayleigh scattering.

    PubMed

    Allison, Patton M; McManus, Thomas A; Sutton, Jeffrey A

    2016-03-15

    This Letter demonstrates the application of filtered Rayleigh scattering (FRS) for quantitative two-dimensional fuel vapor/air mixing measurements in an evaporating hydrocarbon fuel spray flow. Using the FRS approach, gas-phase measurements are made in the presence of liquid-phase droplets without interference. Effective suppression of the liquid-phase droplet scattering using FRS is enabled by the high spectral purity of the current Nd:YAG laser system. Simultaneous Mie-scattering imaging is used to visualize the droplet field and illustrate the droplet loading under which the FRS imaging is applied in the current spray flows. The initial quantification of the FRS imaging is based on calibration measurements from a flow cell of known fuel vapor/air mixtures, while future work targets the utilization of a Rayleigh-Brillouin spectral model for quantification of the FRS signals. PMID:26977637

  5. Dense spray evaporation as a mixing process

    NASA Astrophysics Data System (ADS)

    de Rivas, A.; Villermaux, E.

    2016-05-01

    We explore the processes by which a dense set of small liquid droplets (a spray) evaporates in a dry, stirred gas phase. A dense spray of micron-sized liquid (water or ethanol) droplets is formed in air by a pneumatic atomizer in a closed chamber. The spray is conveyed in ambient air as a plume whose extension depends on the relative humidity of the diluting medium. Standard shear instabilities develop at the plume edge, forming the stretched lamellar structures familiar with passive scalars. Unlike passive scalars however, these lamellae vanish in a finite time, because individual droplets evaporate at their border in contact with the dry environment. Experiments demonstrate that the lifetime of an individual droplet embedded in a lamellae is much larger than expected from the usual d2 law describing the fate of a single drop evaporating in a quiescent environment. By analogy with the way mixing times are understood from the convection-diffusion equation for passive scalars, we show that the lifetime of a spray lamellae stretched at a constant rate γ is tv=1/γ ln(1/+ϕ ϕ ) , where ϕ is a parameter that incorporates the thermodynamic and diffusional properties of the vapor in the diluting phase. The case of time-dependent stretching rates is examined too. A dense spray behaves almost as a (nonconserved) passive scalar.

  6. On the role of physiochemical properties on evaporation behavior of DISI biofuel sprays

    NASA Astrophysics Data System (ADS)

    Knorsch, Tobias; Heldmann, Markus; Zigan, Lars; Wensing, Michael; Leipertz, Alfred

    2013-06-01

    Biofuels and alternative fuels are increasingly being blended to conventional gasoline fuel to reduce the overall CO2 emissions. The effect on NOx and soot formation is still unclear as the atomization and evaporation of gasoline with biocomponents differ depending on fuel specific physiochemical properties. This work focuses on describing the biofuel evaporation behavior of gasoline sprays at homogeneous charge (early injection timing) and stratified-charge conditions (late injection timing mode) used in modern direct injection spark ignition engines (DISI). A spray plume of a 6-hole solenoid injector is analyzed in terms of liquid spray propagation, and local droplet sizes studied in an injection chamber. Depending on the operating conditions, different physiochemical properties are found to dominate the atomization and evaporation processes: For low and moderate ambient temperature and pressure, high-boiling point components show a strong influence on the spray droplet size distribution. However, at elevated temperature and pressure, the evaporation behavior changes completely. Due to a high degree of evaporation, the evaporation cooling effect dominates the local droplet sizes. Fuel mixtures owing a larger heat of vaporization show larger droplet sizes—even if these fuels have a lower boiling point. Depending on the local evaporation behavior, the different remaining droplet momentum in the spray controls the air entrainment and the subsequent progress of evaporation and mixing. Overall, it can be stated that the heat of vaporization is a dominating physiochemical property for the droplet evaporation rate at high-level supercharged conditions.

  7. Measurements in liquid fuel sprays

    NASA Technical Reports Server (NTRS)

    Chigier, N.

    1984-01-01

    Techniques for studying the events directly preceding combustion in the liquid fuel sprays are being used to provide information as a function of space and time on droplet size, shape, number density, position, angle of flight and velocity. Spray chambers were designed and constructed for: (1) air-assist liquid fuel research sprays; (2) high pressure and temperature chamber for pulsed diesel fuel sprays; and (3) coal-water slurry sprays. Recent results utilizing photography, cinematography, and calibration of the Malvern particle sizer are reported. Systems for simultaneous measurement of velocity and particle size distributions using laser Doppler anemometry interferometry and the application of holography in liquid fuel sprays are being calibrated.

  8. The lifetime of evaporating dense sprays

    NASA Astrophysics Data System (ADS)

    de Rivas, Alois; Villermaux, Emmanuel

    2015-11-01

    We study the processes by which a set of nearby liquid droplets (a spray) evaporates in a gas phase whose relative humidity (vapor concentration) is controlled at will. A dense spray of micron-sized water droplets is formed in air by a pneumatic atomizer and conveyed through a nozzle in a closed chamber whose vapor concentration has been pre-set to a controlled value. The resulting plume extension depends on the relative humidity of the diluting medium. When the spray plume is straight and laminar, droplets evaporate at its edge where the vapor is saturated, and diffuses through a boundary layer developing around the plume. We quantify the shape and length of the plume as a function of the injecting, vapor diffusion, thermodynamic and environment parameters. For higher injection Reynolds numbers, standard shear instabilities distort the plume into stretched lamellae, thus enhancing the diffusion of vapor from their boundary towards the diluting medium. These lamellae vanish in a finite time depending on the intensity of the stretching, and relative humidity of the environment, with a lifetime diverging close to the equilibrium limit, when the plume develops in an medium saturated in vapor. The dependences are described quantitatively.

  9. Statistical Model of Evaporating Multicomponent Fuel Drops

    NASA Technical Reports Server (NTRS)

    Harstad, Kenneth; LeClercq, Patrick; Bellan, Josette

    2007-01-01

    An improved statistical model has been developed to describe the chemical composition of an evaporating multicomponent- liquid drop and of the mixture of gases surrounding the drop. The model is intended for use in computational simulations of the evaporation and combustion of sprayed liquid fuels, which are typically mixtures of as many as hundreds of different hydrocarbon compounds. The present statistical model is an approximation designed to afford results that are accurate enough to contribute to understanding of the simulated physical and chemical phenomena, without imposing an unduly large computational burden.

  10. Modeling of gas turbine fuel nozzle spray

    SciTech Connect

    Rizk, N.K.; Chin, J.S.; Razdan, M.K.

    1997-01-01

    Satisfactory performance of the gas turbine combustor relies on the careful design of various components, particularly the fuel injector. It is, therefore, essential to establish a fundamental basis for fuel injection modeling that involves various atomization processes. A two-dimensional fuel injection model has been formulated to simulate the airflow within and downstream of the atomizer and address the formation and breakup of the liquid sheet formed at the atomizer exit. The sheet breakup under the effects of airblast, fuel pressure, or the combined atomization mode of the air-assist type is considered in the calculation. The model accounts for secondary breakup of drops and the stochastic Lagrangian treatment of spray. The calculation of spray evaporation addresses both droplet heat-up and steady-state mechanisms, and fuel vapor concentration is based on the partial pressure concept. An enhanced evaporation model has been developed that accounts for multicomponent, finite mass diffusivity and conductivity effects, and addresses near-critical evaporation. The present investigation involved predictions of flow and spray characteristics of two distinctively different fuel atomizers under both nonreacting and reacting conditions. The predictions of the continuous phase velocity components and the spray mean drop sizes agree well with the detailed measurements obtained for the two atomizers, which indicates the model accounts for key aspects of atomization. The model also provides insight into ligament formation and breakup at the atomizer exit and the initial drop sizes formed in the atomizer near field region where measurements are difficult to obtain. The calculations of the reacting spray show the fuel-rich region occupied most of the spray volume with two-peak radial gas temperature profiles. The results also provided local concentrations of unburned hydrocarbon and CO in atomizer flowfield.

  11. Evaporating Spray in Supersonic Streams Including Turbulence Effects

    NASA Technical Reports Server (NTRS)

    Balasubramanyam, M. S.; Chen, C. P.

    2006-01-01

    Evaporating spray plays an important role in spray combustion processes. This paper describes the development of a new finite-conductivity evaporation model, based on the two-temperature film theory, for two-phase numerical simulation using Eulerian-Lagrangian method. The model is a natural extension of the T-blob/T-TAB atomization/spray model which supplies the turbulence characteristics for estimating effective thermal diffusivity within the droplet phase. Both one-way and two-way coupled calculations were performed to investigate the performance of this model. Validation results indicate the superiority of the finite-conductivity model in low speed parallel flow evaporating sprays. High speed cross flow spray results indicate the effectiveness of the T-blob/T-TAB model and point to the needed improvements in high speed evaporating spray modeling.

  12. Simulations of Evaporating Multicomponent Fuel Drops

    NASA Technical Reports Server (NTRS)

    Bellan, Josette; Le Clercq, Patrick

    2005-01-01

    A paper presents additional information on the subject matter of Model of Mixing Layer With Multicomponent Evaporating Drops (NPO-30505), NASA Tech Briefs, Vol. 28, No. 3 (March 2004), page 55. To recapitulate: A mathematical model of a three-dimensional mixing layer laden with evaporating fuel drops composed of many chemical species has been derived. The model is used to perform direct numerical simulations in continuing studies directed toward understanding the behaviors of sprays of liquid petroleum fuels in furnaces, industrial combustors, and engines. The model includes governing equations formulated in an Eulerian and a Lagrangian reference frame for the gas and drops, respectively, and incorporates a concept of continuous thermodynamics, according to which the chemical composition of a fuel is described by use of a distribution function. In this investigation, the distribution function depends solely on the species molar weight. The present paper reiterates the description of the model and discusses further in-depth analysis of the previous results as well as results of additional numerical simulations assessing the effect of the mass loading. The paper reiterates the conclusions reported in the cited previous article, and states some new conclusions. Some new conclusions are: 1. The slower evaporation and the evaporation/ condensation process for multicomponent-fuel drops resulted in a reduced drop-size polydispersity compared to their single-component counterpart. 2. The inhomogeneity in the spatial distribution of the species in the layer increases with the initial mass loading. 3. As evaporation becomes faster, the assumed invariant form of the molecular- weight distribution during evaporation becomes inaccurate.

  13. Fuel spray diagnostics

    NASA Technical Reports Server (NTRS)

    Bosque, M. A.

    1984-01-01

    Several laser measurement methods are being studied to provide the capability to make droplet size and velocity measurements under a variety of spray conditions. The droplet sizing interferometer (DSI) promises to be a successful technique because of its capability for rapid data acquisition, compilation and analysis. Its main advantage is the ability to obtain size and velocity measurements in air-fuel mixing studies and hot flows. The existing DSI at NASA Lewis is a two-color, two-component system. Two independent orthogonal measurements of size and velocity components can be made simultaneously. It also uses an off-axis large-angle light scatter detection. The fundamental features of the system are optics, signal processing and data management system. The major component includes a transmitter unit, two receiver units, two signal processors, two data management systems, two Bragg cell systems, two printer/plotters, a laser, power supply and color monitor.

  14. Photomicrographic Studies of Fuel Sprays

    NASA Technical Reports Server (NTRS)

    Lee, Dana W; Spencer, Robert C

    1934-01-01

    A large number of photomicrographs of fuel sprays were taken for the purpose of studying the spray structure and the process of spray formation. They were taken at magnifying powers of 2.5, 3.25, and 10, using a spark discharge of very short duration for illumination. Several types and sizes of nozzles were investigated, different liquids were used, and a wide range of injection pressures was employed. The sprays were photographed as they were injected into a glass-walled chamber in which the air density was varied from 14 atmospheres to 0.0013 atmosphere.

  15. Pollutant Formation in Monodisperse Fuel Spray Combustion

    NASA Technical Reports Server (NTRS)

    Cernansky, N. P.; Sarv, H.

    1983-01-01

    The combustion of liquid sprays represents an extremely important class of combustion processes. In the transition region, encompassing droplet sizes in the range of 25-80 micron diameter, the mixing and evaporation processes are both incomplete at the flame front and burning occurs in a combined diffusive and premixed fashion. Under these conditions, the relative importance of heterogeneous and homogeneous effects in dominating the combustion process is switched and gives rise to a number of interesting phenomena. NO (sub x) formation in monodisperse spray combustion was investigated with the following specific objectives: (1) to quantitatively determine the effect of droplet size, number density, etc. on NO sub x formation in monodisperse fuel spray combustion; and (2) to isolate the important physical and chemical phenomena in NO sub x formation in these combustion systems.

  16. Detailed fuel spray analysis techniques

    NASA Technical Reports Server (NTRS)

    Mularz, E. J.; Bosque, M. A.; Humenik, F. M.

    1983-01-01

    Detailed fuel spray analyses are a necessary input to the analytical modeling of the complex mixing and combustion processes which occur in advanced combustor systems. It is anticipated that by controlling fuel-air reaction conditions, combustor temperatures can be better controlled, leading to improved combustion system durability. Thus, a research program is underway to demonstrate the capability to measure liquid droplet size, velocity, and number density throughout a fuel spray and to utilize this measurement technique in laboratory benchmark experiments. The research activities from two contracts and one grant are described with results to data. The experiment to characterize fuel sprays is also described. These experiments and data should be useful for application to and validation of turbulent flow modeling to improve the design systems of future advanced technology engines.

  17. Evaluation of a locally homogeneous model of spray evaporation

    NASA Technical Reports Server (NTRS)

    Shearer, A. J.; Faeth, G. M.

    1979-01-01

    A model of spray evaporation which employs a second-order turbulence model in conjunction with the locally homogeneous flow approximation, which implies infinitely fast interphase transport rates is presented. Measurements to test the model were completed for single phase constant and variable density jets, as well as an evaporating spray in stagnant air. Profiles of mean velocity, composition, temperature and drop size distribution as well as velocity fluctuations and Reynolds stress, were measured within the spray. Predictions were in agreement with measurements in single phase flows and also with many characteristics of the spray, e.g. flow width, radial profiles of mean and turbulent quantities, and the axial rate of decay of mean velocity and mixture fraction.

  18. A study of diamond laminated surfaces in evaporative spray cooling

    NASA Astrophysics Data System (ADS)

    Sehmbey, M. S.; Pais, M. R.; Chow, L. C.

    This effort is directed towards studying the performance of diamond laminated surfaces under conditions of evaporative spray cooling of high-heat-flux electronic components. The experimental results presented illustrate the robustness of the surface, as well as its heat transfer characteristics, wettability and roughness. Exceptional heat flux rates of over 1100 W/sq cm were obtained within superheats of 40 C.

  19. Evaporative spray cooling of plain and microporous coated surfaces.

    SciTech Connect

    Kim, J. H.; You, S. M.; Choi, S. U.-S.; Energy Technology; Univ. of Texas at Arlington

    2004-07-01

    Experiments were performed on air and evaporative spray cooling of plain and microporous coated surfaces on flat and cylindrical heaters. Micron-size aluminum particles were used to build the microporous structures on the heated surfaces. To analyze the evaporative cooling, heat transfer curves were obtained in the form of the wall temperature difference versus heat flux. The heat transfer coefficients were also determined as a function of heat flux. Three water flow rates (1.25, 1.75 and 2.40 ml/min) were tested for the flat heater and one rate (3.0 ml/min) for the cylindrical heater, maintaining the air pressure of 7 psig (48 kPa) at the inlet of the nozzle. The effect of different particle sizes in the coating was also tested to optimize the microporous coating technique. Spraying water droplets on the microporous coating surface enhanced the heat removal due to the capillary pumping phenomenon through the microporous cavities connecting each other. The evaporative spray cooling increased the heat transfer coefficient by up to 400% relative to that of the uncoated surface cooled by dry air, and this enhancement was maintained at high heat fluxes by using microporous surfaces.

  20. Evaluation of a locally homogeneous model of spray evaporation

    NASA Technical Reports Server (NTRS)

    Shearer, A. J.; Faeth, G. M.; Tamura, H.

    1978-01-01

    Measurements were conducted on an evaporating spray in a stagnant environment. The spray was formed using an air-atomizing injector to yield a Sauter mean diameter of the order of 30 microns. The region where evaporation occurred extended approximately 1 m from the injector for the test conditions. Profiles of mean velocity, temperature, composition, and drop size distribution, as well as velocity fluctuations and Reynolds stress, were measured. The results are compared with a locally homogeneous two-phase flow model which implies no velocity difference and thermodynamic equilibrium between the phases. The flow was represented by a k-epsilon-g turbulence model employing a clipped Gaussian probability density function for mixture fraction fluctuations. The model provides a good representation of earlier single-phase jet measurements, but generally overestimates the rate of development of the spray. Using the model predictions to represent conditions along the centerline of the spray, drop life-history calculations were conducted which indicate that these discrepancies are due to slip and loss of thermodynamic equilibrium between the phases.

  1. Effects of sea spray evaporation and dissipative heating on intensity and structure of tropical cyclone

    NASA Astrophysics Data System (ADS)

    Cheng, Xiaoping; Fei, Jianfang; Huang, Xiaogang; Zheng, Jing

    2012-07-01

    To examine effects of sea spray evaporation and dissipative heating on structure and intensity of a real tropical cyclone, the sea spray flux parameterization scheme was incorporated into the fifth-generation Pennsylvania State University-National Center for Atmospheric Research Mesoscale Model (MM5). Sensitivity tests were performed with varying the spray source function intensities and with and without dissipation heating. The numerical results indicate that sea spray evaporation increases the interfacial sensible heat flux, which is increased by 16% for the moderate spray and 47% for the heavy spray, but has little effect on the interfacial latent heat flux. The net effect of sea spray evaporation is to decrease the total sensible heat flux and to increase the total latent heat flux. The total enthalpy flux is increased by 1% and 12% with moderate and strong spray amounts, respectively. Consistent with these results, the intensity of the tropical cyclone is increased by 5% and 16% in maximum 10-m wind speed, respectively, due to sea spray evaporation. Sea spray evaporation and dissipative heating modify the tropical cyclone structure in important but complex ways. The effect of sea spray on the near-surface temperature and moisture depends on the spray amounts and its location within the tropical cyclone. Within the high-wind region of a tropical cyclone, the lower atmosphere becomes cooler and moister due to the evaporation of sea spray. However, the dissipative heating offsets the cooling due to sea spray evaporation, which makes the lower atmosphere warmer.

  2. Modeling subgrid scale mixture fraction variance in LES of evaporating spray

    SciTech Connect

    Pera, Cecile; Reveillon, Julien; Vervisch, Luc; Domingo, Pascale

    2006-09-15

    Simulations of a dilute spray evaporating in spatially decaying homogeneous turbulence are performed. An Eulerian description of the flow is adopted, while the behavior of the discrete liquid phase is captured using Lagrangian modeling. Time and length scales of the continuous carrier phase are fully simulated; and by varying the properties of the modeled spray, a database of spray carrier phase direct numerical simulation (CP-DNS) is obtained. The CP-DNS is then filtered on a coarse grid to conduct a priori tests of subgrid scale (SGS) closures. The objective is to provide methods for approximating the level of SGS mixture fraction variance in large eddy simulation (LES) of fuel spray turbulent combustion. Direct estimation of the variance from the scales resolved in LES is first discussed. Then, the solving of a balance equation to get the variance is addressed, with closures for the scalar dissipation rate and the correlation between vapor source and mixture fraction. From the results, a procedure to couple spray evaporation with SGS turbulent combustion modeling emerges. (author)

  3. Experiments on the Distribution of Fuel in Fuel Sprays

    NASA Technical Reports Server (NTRS)

    Lee, Dana W

    1932-01-01

    The distribution of the fuel in sprays for compression-ignition engines was investigated by taking high-speed spark photographs of fuel sprays produced under a wide variety of conditions, and also by injecting them against pieces of Plasticine. A photographic study was made of sprays injected into evacuated chambers, into the atmosphere, into compressed air, and into transparent liquids. Pairs of identical sprays were injected counter to each other and their behavior analyzed. Small high-velocity air jets were directed normally to the axes of fuel sprays, with the result that the envelope of spray which usually obscures the core was blown aside, leaving the core exposed on one side.

  4. CFD Modeling of Superheated Fuel Sprays

    NASA Technical Reports Server (NTRS)

    Raju, M. S.

    2008-01-01

    An understanding of fuel atomization and vaporization behavior at superheat conditions is identified to be a topic of importance in the design of modern supersonic engines. As a part of the NASA aeronautics initiative, we have undertaken an assessment study to establish baseline accuracy of existing CFD models used in the evaluation of a ashing jet. In a first attempt towards attaining this goal, we have incorporated an existing superheat vaporization model into our spray solution procedure but made some improvements to combine the existing models valid at superheated conditions with the models valid at stable (non-superheat) evaporating conditions. Also, the paper reports some validation results based on the experimental data obtained from the literature for a superheated spray generated by the sudden release of pressurized R134A from a cylindrical nozzle. The predicted profiles for both gas and droplet velocities show a reasonable agreement with the measured data and exhibit a self-similar pattern similar to the correlation reported in the literature. Because of the uncertainty involved in the specification of the initial conditions, we have investigated the effect of initial droplet size distribution on the validation results. The predicted results were found to be sensitive to the initial conditions used for the droplet size specification. However, it was shown that decent droplet size comparisons could be achieved with properly selected initial conditions, For the case considered, it is reasonable to assume that the present vaporization models are capable of providing a reasonable qualitative description for the two-phase jet characteristics generated by a ashing jet. However, there remains some uncertainty with regard to the specification of certain initial spray conditions and there is a need for experimental data on separate gas and liquid temperatures in order to validate the vaporization models based on the Adachi correlation for a liquid involving R134A.

  5. Fuel thermal stability effects on spray characteristics

    NASA Technical Reports Server (NTRS)

    Lefebvre, A. H.; Nickolaus, D.

    1987-01-01

    The propensity of a heated hydrocarbon fuel toward solids deposition within a fuel injector is investigated experimentally. Fuel is arranged to flow through the injector at constant temperature, pressure, and flow rate and the pressure drop across the nozzle is monitored to provide an indication of the amount of deposition. After deposits have formed, the nozzle is removed from the test rig and its spray performance is compared with its performance before deposition. The spray characteristics measured include mean drop size, drop-size distribution, and radial and circumferential fuel distribution. It is found that small amounts of deposition can produce severe distortion of the fuel spray pattern. More extensive deposition restores spray uniformity, but the nozzle flow rate is seriously curtailed.

  6. Droplet-turbulence interactions in subcritical and supercritical evaporating sprays

    NASA Technical Reports Server (NTRS)

    Santavicca, Domenic A.; Coy, Edward; Greenfield, Stuart; Song, Young-Hoon

    1991-01-01

    The objective of this research is to obtain an improved understanding of droplet turbulence interactions in vaporizing liquid sprays under conditions typical of those encountered in liquid fueled rocket engines. The interaction between liquid droplets and the surrounding turbulent gas flow affects droplet dispersion, droplet collisions, droplet vaporization and gas-phase, fuel-oxidant mixing, and therefore has a significant effect on the engine's combustion characteristics. An example of this is the role which droplet-turbulence interactions are believed to play in combustion instabilities. Despite their importance, droplet-turbulence interactions and their effect on liquid fueled rocket engine performance are not well understood. This is particularly true under supercritical conditions, where many conventional concepts, such as surface tension, no longer apply. Our limited understanding of droplet-turbulence interactions, under both subcritical conditions, represents a major limitation in our ability to design improved liquid previously unavailable information and valuable new insights which will directly impact the design of future liquid fueled rocket engines, as well as, allow for the development of significantly improved spray combustion models, making such models useful design tools.

  7. The structure of evaporating and combusting sprays: Measurements and predictions

    NASA Astrophysics Data System (ADS)

    Shuen, J. S.; Solomon, A. S. P.; Faeth, G. M.

    1984-07-01

    An apparatus developed, to allow observations of monodisperse sprays, consists of a methane-fueled turbulent jet diffusion flame with monodisperse methanol drops injected at the burner exit. Mean and fluctuating-phase velocities, drop sizes, drop-mass fluxes and mean-gas temperatures were measured. Initial drop diameters of 100 and 180 microns are being considered in order to vary drop penetration in the flow and effects of turbulent dispersion. Baseline tests of the burner flame with no drops present were also conducted. Calibration tests, needed to establish methods for predicting drop transport, involve drops supported in the post-flame region of a flat-flame burner operated at various mixture ratios. Spray models which are being evaluated include: (1) locally homogeneous flow (LFH) analysis, (2) deterministic separated flow (DSF) analysis and (3) stochastic separated flow (SSF) analysis.

  8. The structure of evaporating and combusting sprays: Measurements and predictions

    NASA Technical Reports Server (NTRS)

    Shuen, J. S.; Solomon, A. S. P.; Faeth, G. M.

    1984-01-01

    An apparatus developed, to allow observations of monodisperse sprays, consists of a methane-fueled turbulent jet diffusion flame with monodisperse methanol drops injected at the burner exit. Mean and fluctuating-phase velocities, drop sizes, drop-mass fluxes and mean-gas temperatures were measured. Initial drop diameters of 100 and 180 microns are being considered in order to vary drop penetration in the flow and effects of turbulent dispersion. Baseline tests of the burner flame with no drops present were also conducted. Calibration tests, needed to establish methods for predicting drop transport, involve drops supported in the post-flame region of a flat-flame burner operated at various mixture ratios. Spray models which are being evaluated include: (1) locally homogeneous flow (LFH) analysis, (2) deterministic separated flow (DSF) analysis and (3) stochastic separated flow (SSF) analysis.

  9. A theoretical and experimental study of turbulent evaporating sprays

    NASA Technical Reports Server (NTRS)

    Solomon, A. S. P.; Shuen, J. S.; Zhang, Q. F.; Faeth, G. M.

    1984-01-01

    Measurements and analysis limited to the dilute portions of turbulent evaporating sprays, injected into a still air environment were completed. Mean and fluctuating velocities and Reynolds stress were measured in the continuous phase. Liquid phase measurements included liquid mass fluxes, drop sizes and drop size and velocity correlation. Initial conditions needed for model evaluation were measured at a location as close to the injector exit as possible. The test sprays showed significant effects of slip and turbulent dispersion of the discrete phase. The measurements were used to evaluate three typical models of these processes: (1) a locally homogeneous flow (LHF) model, where slip between the phases were neglected; (2) a deterministic separated flow (DSF) model, where slip was considered but effects of drop dispersion by turbulence were ignored; and (3) a stochastic separated flow (SSF) model, where effects of interphase slip and turbulent dispersion were considered using random-walk computations for drop motion. For all three models, a k-epsilon model as used to find the properties of the continuous phase. The LHF and DSF models did not provide very satisfactory predictions for the present measurements. In contrast, the SSF model performed reasonably well--with no modifications in the prescription of eddy properties from its original calibration.

  10. Preliminary Photomicrographic Studies of Fuel Sprays

    NASA Technical Reports Server (NTRS)

    Lee, Dana W; Spencer, Robert C

    1932-01-01

    Photomicrographs were taken of fuel sprays injected into air at various densities for the purpose of studying the spray structure and the stages in the atomization of the fuel. The photomicrographs were taken at magnifying powers of 2.5, 3.25, and 10, using a spark discharge of very short duration for illumination. The results indicate that the theory advanced by Dr. R. A. Castleman, Jr., on the atomization of fuel in carburetors may also be applied to the atomization of fuel sprays of the solid-injection type. The fuel leaves the nozzle as a solid column, is ruffled and then torn into small, irregular ligaments by the action of the air. These ligaments are then quickly broken up into drops by the surface tension of the fuel. The photomicrographs also show that the dispersion of a fuel spray at a given distance from the nozzle increases with an increase in the jet velocity or an increase in the air density. The first portions of fuel sprays injected from an automatic injection valve into air at atmospheric density have a much greater dispersion than the later portions, but this difference decreases rapidly as the air density is increased.

  11. Evaporation and Combustion Characteristics of Multicomponent Fuels

    NASA Astrophysics Data System (ADS)

    Govindaraju, Pavan; Stagni, Alessandro; Ihme, Matthias

    2015-11-01

    Current generation fuels are mixtures of hundreds of complicated organic compounds and accurate modeling of their combustion characteristics provides fundamental physical insights which also help in the design of efficient combustors. This however requires accurate simulation of both evaporation and combustion processes, which, in case of such fuels, demands an approach based on calculating properties using only the information of functional groups present in the mixture. The presentation will elaborate on the assumptions and the framework utilized for evaporation and chemical mechanisms. We also present a comparison between various fuels used in the aviation industry as test cases while highlighting on their pros and cons. The focus of the talk will however be on the physical aspects captured using 1D simulations, i.e., preferential evaporation of each species, ignition parameters and emissions while justifying the numerical calculations with experimental data at each stage. Further work involving the coupling of flow with evaporation and combustion can be performed and we briefly discuss why a DNS is necessary to characterize the various combustion regimes. Federal Aviation Administration.

  12. The evaporation of dense sprays as a mixing process

    NASA Astrophysics Data System (ADS)

    de Rivas, Alois; Villermaux, Emmanuel

    2014-11-01

    A dense spray of micron-sized droplets (water or ethanol) is formed in air by a pneumatic atomizer in a closed chamber, and is then conveyed through a nozzle in ambient air, forming a plume whose extension depends on the relative humidity of the diluting medium. We focus on the dry ambient medium, and large plume Reynolds number limit. Standard shear instabilities develop at the plume edge, forming the stretched lamellar structures familiar with passive scalars, except that these vanish in a finite time, because individual droplets evaporate at their border. Experiments also demonstrate that the lifetime of an individual droplet embedded in a lamellae is much larger than expected from the usual d-square law for an isolated droplet. By analogy with the way mixing times are understood from the convection-diffusion equation for passive scalars, we show that the lifetime of a lamellae stretched at a rate γ is tv =1/γ ln (1/+ ϕ ϕ ) where ϕ is a parameter which incorporates the thermodynamic and diffusional properties of the vapor in the diluting phase. The droplets field thus behaves as a -non conserved- passive scalar.

  13. Measurements in liquid fuel sprays

    NASA Technical Reports Server (NTRS)

    Chigier, N.; Mao, C. P.

    1985-01-01

    A ground test facility is being established at NASA Lewis Research Center to simulate the environmental and flight conditions needed to study adverse weather effects. One of the most important components is the water spray system which consists of many nozzles fitted on spray bars. Water is injected through air-assisted atomizers to generate uniform size drops to simulate icing in clouds. The primary objective is to provide experimental data on drop size distribution over a wide range of operating conditions. Correlation equations for mean drop size and initial injection parameters are being determined to assist in the design and modification of the Altitude Wind Tunnel. Special emphasis is being placed on the study of the aerodynamic structure of the air-assisted atomizer sprays. Detailed measurements of the variation of drop size distribution and velocity as a function of time and space are being made. Accurate initial and boundary conditions are being provided for computer model evaluation.

  14. Analysis of polydisperse fuel spray flame

    NASA Astrophysics Data System (ADS)

    Nave, Ophir; Lehavi, Yaron; Ajadi, Suraju; Gol'dshtein, Vladimir

    2016-06-01

    In this paper we analyzed the model of polydisperse fuel spray flame by using the sectional approach to describe the droplet-droplet interaction within the spray. The radii of the droplets are described by a probability density function. Our numerical simulations include a comparative analysis between three empirical droplet size distributions: the Rosin-Rammler distribution, the log-normal distribution and the Nakiyama-Tanasawa distribution. The log-normal distribution was found to produce a reasonable approximation to both the number and volume size distribution function. In addition our comparative analysis includes the application of the homotopy analysis method which yields convergent solutions for all values of the relevant parameters. We compared the above results to experimental fuel spray data such as {{Tetralin}} , n-{{Decane}} , and n-{{Heptane}} .

  15. Influence of Spray Formulation and Leaf Surface Structure on Droplet Evaporation and Wetted Area

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The fate of pesticide droplets on leaves is seriously influenced by spray formulations and fine structures on leaf surfaces. Evaporation times and wetted areas of droplets on hairy and waxy geranium leaf surfaces were determined under controlled conditions. Droplet evaporation processes were taken w...

  16. A tabulated chemistry approach for numerical modeling of diesel spray evaporation in a 'stabilized cool flame' environment

    SciTech Connect

    Kolaitis, D.I.; Founti, M.A.

    2006-04-15

    Droplet evaporation in a 'stabilized cool flame' environment leads to a homogeneous, heated air-fuel vapor mixture that can be subsequently either burnt or utilized in fuel-reforming applications for fuel cell systems. The paper investigates the locally occurring physico-chemical phenomena in an atmospheric pressure, diesel spray, stabilized cool flame reactor, utilizing a tabulated chemistry approach in conjunction with a two-phase, Eulerian-Lagrangian computational fluid dynamics code. Actual diesel oil physical properties are used to model spray evaporation in the two-phase simulations, whereas the corresponding chemistry is represented by n-heptane. A lookup table is constructed by performing a plethora of perfectly stirred reactor simulations, utilizing a semidetailed n-heptane oxidation chemical kinetics mechanism. The overall exothermicity of the preignition n-heptane oxidation chemistry and the fuel consumption rates are examined as a function of selected independent parameters, namely temperature, fuel concentration, and residence time; their influence on cool flame reactivity is thoroughly studied. It is shown that the tabulated chemistry approach allows accurate investigation of the chemical phenomena with low computational cost. The two-phase flow inside the stabilized cool flame reactor is simulated, utilizing the developed lookup table. Predictions are presented for a variety of test cases and are compared to available experimental data, with satisfactory agreement. Model validation tests indicate that prediction quality improves with increasing values of air temperature at the reactor's inlet. (author)

  17. Effect of Pre-evaporation on Flame Spread Limit of a Fuel Droplet Array

    NASA Astrophysics Data System (ADS)

    Yamamoto, Shin; Kikuchi, Masao; Suematsu, Takaaki; Yoda, Shinichi; Mikami, Masoto

    Spray combustion is utilized in various fields such as gas turbine and aero-engine. Combustion exhaust gas is one of the causes concerning global warming of the earth and the air pollution. In order to improve environmental problems, it is necessary to develop combustion technology which has high efficiency and low environmental loads. However, spray combustion is com-plex phenomena that grain refinement of fuel, the evaporation, diffusion, ignition and flame spread, etc. progress simultaneously. Therefore, it is important to clarify details of spray combustion mechanism. Objective of our research is clarification of flame spread mechanism between droplets for fundamental research of spray combustion by utilizing the microgravity experiments and numerical analysis. It is useful to employ a fuel droplet array as the simplified model in order to elucidate detail flame spread mechanism between fuel droplets. The micro-gravity environment enables to expand time and spatial scale without the disturbing effect of natural convection. This is useful for clarification of complex phenomena such as combustion. icrogravity experiments have been performed in a drop tower, parabolic flight, and sounding rocket. In our research, it was revealed and classified that there are three modes concerning the flame spread of a linear droplet array. Appearances of flame spread modes are depending on non-dimensional ambient temperature RT/L and droplet spacing S/d. Here, R represents the universal gas constant, T, is the gas temperature, L, is the latent heat, S, is the droplet spacing, and d, is the initial diameter of the droplet. However, flame spread mode is changed by the formation of fuel vapor around droplets. Formation of fuel vapor depends on pre-evaporation of fuel droplets. Moreover, flame structure is also changed by pre-evaporation. The flame spread limit between droplets is affected by pre-evaporation of fuel droplets. The flame spread limit (S/d) is an important factor to the

  18. Modeling of evaporation and oxidation phenomena in plasma spraying of metal powders

    NASA Astrophysics Data System (ADS)

    Zhang, Hanwei

    Plasma spraying of metals in air is usually accompanied by evaporation and oxidation of the sprayed material. Optimization of the spraying process must ensure that the particles are fully molten during their short residence time in the plasma jet and prior to hitting the substrate, but not overheated to minimize evaporation losses. In atmospheric plasma spraying (ASP), it is also clearly desirable to be able to control the extent of oxide formation. The objective of this work to develop an overall mathematical model of the oxidization and volatilization phenomena involved in the plasma-spraying of metallic particles in air atmosphere. Four models were developed to simulate the following aspects of the atmospheric plasma spraying (APS) process: (a) the particle trajectories and the velocity and temperature profiles in an Ar-H 2 plasma jet, (b) the heat and mass transfer between particles and plasma jet, (c) the interaction between the evaporation and oxidation phenomena, and (d) the oxidation of liquid metal droplets. The resulting overall model was generated by adapting the computational fluid dynamics code FIDAP and was validated by experimental measurements carried out at the collaborating plasma laboratory of the University of Limoges. The thesis also examined the environmental implications of the oxidization and volatilization phenomena in the plasma spraying of metals. The modeling results showed that the combination of the standard k-s model of turbulence and the Boussinesq eddy-viscosity model provided a more accurate prediction of plasma gas behavior. The estimated NOx generation levels from APS were lower than the U.S.E.P.A. emission standard. Either enhanced evaporation or oxidation can occur on the surface of the metal particles and the relative extent is determined by the process parameters. Comparatively, the particle size has the greatest impact on both evaporation and oxidation. The extent of particle oxidation depends principally on gas

  19. Development of a laboratory prototype spraying flash evaporator.

    NASA Technical Reports Server (NTRS)

    Gaddis, J. L.

    1972-01-01

    A functional description of the flash evaporator that is being developed as a candidate for the Space Shuttle Environmental Control System thermal control is presented. A single evaporator configuration uses water as an evaporant to accommodate on-orbit peak heat loads and Freon 22 for terrestrial flight phases below 120,000 ft altitude. Development history, test plans, and operational characteristics are described. Detailed information is included to show: design features, fabrication techniques used for a prototype unit, redundancy considerations, and the control arrangement.

  20. The structure of evaporating and combusting sprays: Measurements and predictions

    NASA Technical Reports Server (NTRS)

    Shuen, J. S.; Solomon, A. S. P.; Faeth, G. M.

    1982-01-01

    An apparatus was constructed to provide measurements in open sprays with no zones of recirculation, in order to provide well-defined conditions for use in evaluating spray models. Measurements were completed in a gas jet, in order to test experimental methods, and are currently in progress for nonevaporating sprays. A locally homogeneous flow (LHF) model where interphase transport rates are assumed to be infinitely fast; a separated flow (SF) model which allows for finite interphase transport rates but neglects effects of turbulent fluctuations on drop motion; and a stochastic SF model which considers effects of turbulent fluctuations on drop motion were evaluated using existing data on particle-laden jets. The LHF model generally overestimates rates of particle dispersion while the SF model underestimates dispersion rates. The stochastic SF flow yield satisfactory predictions except at high particle mass loadings where effects of turbulence modulation may have caused the model to overestimate turbulence levels.

  1. Effects of Feedstock Decomposition and Evaporation on the Composition of Suspension Plasma-Sprayed Coatings

    NASA Astrophysics Data System (ADS)

    Mauer, G.; Schlegel, N.; Guignard, A.; Vaßen, R.; Guillon, O.

    2015-10-01

    Emerging new applications and growing demands of plasma-sprayed coatings have initiated the development of new plasma spray processes. One of them is suspension plasma spraying (SPS). The use of liquid feedstock such as suspensions yields higher flexibility compared to the conventional atmospheric plasma spray processes as even submicron-to nano-sized particles can be processed. This allows achieving particular microstructural features, e.g., porous segmented or columnar-structured thermal barrier coatings. To exploit the potentials of such novel plasma spray processes, the plasma-feedstock interaction must be understood better. In this study, decomposition and evaporation of feedstock material during SPS were investigated, since particular difficulties can occur with respect to stoichiometry and phase composition of the deposits. Plasma conditions were analyzed by optical emission spectroscopy (OES). Experimental results are given, namely for gadolinium zirconate and for lanthanum strontium cobalt ferrite deposition. Moreover, the applied OES approach is validated by comparison with the simpler actinometry method.

  2. Direct numerical simulation of ignition in turbulent n-heptane liquid-fuel spray jets

    SciTech Connect

    Wang, Y.; Rutland, C.J.

    2007-06-15

    Direct numerical simulation was used for fundamental studies of the ignition of turbulent n-heptane liquid-fuel spray jets. A chemistry mechanism with 33 species and 64 reactions was adopted to describe the chemical reactions. The Eulerian method is employed to solve the carrier-gas flow field and the Lagrangian method is used to track the liquid-fuel droplets. Two-way coupling interaction is considered through the exchange of mass, momentum, and energy between the carrier-gas fluid and the liquid-fuel spray. The initial carrier-gas temperature was 1500 K. Six cases were simulated with different droplet radii (from 10 to 30 {mu}m) and two initial velocities (100 and 150 m/s). From the simulations, it was found that evaporative cooling and turbulence mixing play important roles in the ignition of liquid-fuel spray jets. Ignition first occurs at the edges of the jets where the fuel mixture is lean, and the scalar dissipation rate and the vorticity magnitude are very low. For smaller droplets, ignition occurs later than for larger droplets due to increased evaporative cooling. Higher initial droplet velocity enhances turbulence mixing and evaporative cooling. For smaller droplets, higher initial droplet velocity causes the ignition to occur earlier, whereas for larger droplets, higher initial droplet velocity delays the ignition time. (author)

  3. Numerical Modeling of Turbulence Effects within an Evaporating Droplet in Atomizing Sprays

    NASA Technical Reports Server (NTRS)

    Balasubramanyam, M. S.; Chen, C. P.; Trinh, H. P.

    2006-01-01

    A new approach to account for finite thermal conductivity and turbulence effects within atomizing liquid sprays is presented in this paper. The model is an extension of the T-blob and T-TAB atomization/spray model of Trinh and Chen (2005). This finite conductivity model is based on the two-temperature film theory, where the turbulence characteristics of the droplet are used to estimate the effective thermal diffhsivity within the droplet phase. Both one-way and two-way coupled calculations were performed to investigate the performance of this model. The current evaporation model is incorporated into the T-blob atomization model of Trinh and Chen (2005) and implemented in an existing CFD Eulerian-Lagrangian two-way coupling numerical scheme. Validation studies were carried out by comparing with available evaporating atomization spray experimental data in terms of jet penetration, temperature field, and droplet SMD distribution within the spray. Validation results indicate the superiority of the finite-conductivity model in low speed parallel flow evaporating spray.

  4. Eulerian CFD modeling and X-ray validation of non-evaporating diesel spray

    NASA Astrophysics Data System (ADS)

    Xue, Qingluan; Som, Sibendu; Quan, Shaoping; Pomraning, Eric; Senecal, P. K.

    2013-11-01

    This work implemented an Eulerian single-phase approach by Vallet et al. into CFD software (Convergent) for diesel spray simulations. This Eulerian approach considers liquid and gas phase as a complex mixture of a single flow with a highly variable density to describe the near nozzle dense sprays. The mean density is obtained form the Favre-averaged liquid mass fraction. Liquid mass fraction is transported with a model for the turbulent liquid diffusion flux into the gas. A mean gradient-based model is employed for the diffusion flux in this study. A non-evaporating diesel spray was measured using x-ray radiography at Argonne National Laboratory. The quantitative and time-resolved data of liquid penetration and mass distribution in the dense spray region are used to validate this approach. The different turbulence models are also used for the simulations. The comparison between the simulated results and experimental data and the turbulence model effect are discussed.

  5. Spark Ignition of Monodisperse Fuel Sprays. Ph.D. Thesis

    NASA Technical Reports Server (NTRS)

    Danis, Allen M.; Cernansky, Nicholas P.; Namer, Izak

    1987-01-01

    A study of spark ignition energy requirements was conducted with a monodisperse spray system allowing independent control of droplet size, equivalent ratio, and fuel type. Minimum ignition energies were measured for n-heptane and methanol sprays characterized at the spark gap in terms of droplet diameter, equivalence ratio (number density) and extent of prevaporization. In addition to sprays, minimum ignition energies were measured for completely prevaporized mixtures of the same fuels over a range of equivalence ratios to provide data at the lower limit of droplet size. Results showed that spray ignition was enhanced with decreasing droplet size and increasing equivalence ratio over the ranges of the parameters studied. By comparing spray and prevaporized ignition results, the existence of an optimum droplet size for ignition was indicated for both fuels. Fuel volatility was seen to be a critical factor in spray ignition. The spray ignition results were analyzed using two different empirical ignition models for quiescent mixtures. Both models accurately predicted the experimental ignition energies for the majority of the spray conditions. Spray ignition was observed to be probabilistic in nature, and ignition was quantified in terms of an ignition frequency for a given spark energy. A model was developed to predict ignition frequencies based on the variation in spark energy and equivalence ratio in the spark gap. The resulting ignition frequency simulations were nearly identical to the experimentally observed values.

  6. Preliminary Tests on the Vaporization of Fuel Sprays

    NASA Technical Reports Server (NTRS)

    Rothrock, A M

    1932-01-01

    High-speed motion pictures were taken of fuel sprays injected into the combustion chamber of the N.A.C.A. combustion apparatus. Three fuels, ethyl alcohol, gasoline, and fuel oil, which differed considerably in volatility were tested. By maintaining the engine temperature below that required for ignition the spray could be studied from soon after the start of injection until 130 crank degrees later. The results show that the sprays vaporize appreciably so that it is possible for the ignition in high speed compression-ignition engines to take place from the vapor phase.

  7. Spray Characterization of Gas-to-Liquid Synthetic Jet Fuels

    NASA Astrophysics Data System (ADS)

    Kannaiyan, Kumaran; Sadr, Reza

    2011-11-01

    In the recent years, development of alternative jet fuels is gaining importance owing to the demand for cleaner combustion. In addition to having energy density that matches those of conventional fuels, alternate jet fuels need to possess vital qualities such as rapid atomization and vaporization, quick re-ignition at high altitude, less emission, and poses ease of handling. The fuel preparatory steps (atomization and vaporization) and mixing in a combustion chamber play a crucial role on the subsequent combustion and emission characteristics. Gas-to-Liquid (GTL) synthetic jet fuel obtained from Fischer-Tropsch synthesis has grabbed the global attention due to its cleaner combustion characteristics as a result of the absence of aromatics and sulphur. As a part of an on-going joint effort between Texas A&M at Qatar (TAMUQ), Rolls-Royce (UK), and German Aerospace Laboratory (DLR), a spray characterization experimental facility is set up at TAMUQ to study the spray characteristics of GTL fuel and highlights the influence of change in fuel composition on the spray characteristics. In this work, spray characteristics such as droplet size, velocity, and distribution of different GTL fuel blends is investigated and compared with the spray characteristics of conventional JetA1 fuel. Supported by Qatar Science and Technology Park, QSTP.

  8. Evaporation and Deposition Coverage Area of Droplets Containing Insecticides and Spray Additives on Hydrophilic, Hydrophobic and Crabapple Leaf Surfaces

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The efficiency of foliar spray applications is influenced by the evaporation and residual pattern of pesticide droplets on targets. Evaporation time and maximal coverage area of a single droplet sizing from 246 to 886 µm at relative humidity (RH) ranging from 30 to 90% were measured with sequential ...

  9. Measuring the Nonuniform Evaporation Dynamics of Sprayed Sessile Microdroplets with Quantitative Phase Imaging.

    PubMed

    Edwards, Chris; Arbabi, Amir; Bhaduri, Basanta; Wang, Xiaozhen; Ganti, Raman; Yunker, Peter J; Yodh, Arjun G; Popescu, Gabriel; Goddard, Lynford L

    2015-10-13

    We demonstrate real-time quantitative phase imaging as a new optical approach for measuring the evaporation dynamics of sessile microdroplets. Quantitative phase images of various droplets were captured during evaporation. The images enabled us to generate time-resolved three-dimensional topographic profiles of droplet shape with nanometer accuracy and, without any assumptions about droplet geometry, to directly measure important physical parameters that characterize surface wetting processes. Specifically, the time-dependent variation of the droplet height, volume, contact radius, contact angle distribution along the droplet's perimeter, and mass flux density for two different surface preparations are reported. The studies clearly demonstrate three phases of evaporation reported previously: pinned, depinned, and drying modes; the studies also reveal instances of partial pinning. Finally, the apparatus is employed to investigate the cooperative evaporation of the sprayed droplets. We observe and explain the neighbor-induced reduction in evaporation rate, that is, as compared to predictions for isolated droplets. In the future, the new experimental methods should stimulate the exploration of colloidal particle dynamics on the gas-liquid-solid interface. PMID:26389788

  10. Some Characteristics of Fuel Sprays at Low-injection Pressures

    NASA Technical Reports Server (NTRS)

    Rothrock, A M; Waldron, C D

    1931-01-01

    This report presents the results of tests conducted at the Langley Memorial Aeronautical Laboratory, Langley Field, Va., to determine some of the characteristics of the fuel sprays obtained from an 0.008-inch and a 0.020-inch open nozzle when injection pressures from 100 to 500 pounds per square inch were used. Fuel oil and gasoline were injected into air at densities of atmospheric land 0.325 pound per cubic foot. It was found that the penetration rate at these low pressures was about the same as the rate obtained with higher pressures. Spray cone-angles were small and individual oil drops were visible in all the sprays. Gasoline and fuel oil sprays had similar characteristics.

  11. Numerical simulation of emulsified fuel spray combustion with puffing and micro-explosion

    SciTech Connect

    Watanabe, Hirotatsu; Matsushita, Yohsuke; Aoki, Hideyuki; Miura, Takatoshi

    2010-05-15

    The purpose of this study was to develop numerical simulation of spray combustion of emulsified fuel with considering puffing and micro-explosion. First, a mathematical model for puffing was proposed. In the proposed puffing model, the rate of mass change of a droplet during puffing was expressed by the evaporation rate of dispersed water and the mass change rate due to fine droplets spouted from the droplet surface. The mass change rate due to fine droplets was related to the evaporation rate of the dispersed water and each liquid content. This model had only one experimental parameter. The essential feature of this model was that it was simple to apply to numerical simulation of spray combustion. First, the validity of the proposed puffing model was investigated with the experimental results for a single droplet. The calculated results for a single droplet with the experimental parameter varying from 5.0 to 10 were in good agreement with the experimental results. Moreover, numerical simulation of spray combustion of emulsified fuel was carried out. The occurrence of puffing and micro-explosion was determined by the inner droplet temperature. When micro-explosion occurred, a droplet changed to vapor rapidly. When the proposed puffing model was used in numerical simulation of spray combustion, the experimental parameter in the puffing model was determined for each droplet by random numbers within the range 5.0-10. The calculated results of spray combustion of emulsified fuel without considering puffing or micro-explosions were different from the experimental results even where combustion reactions were almost terminated. Meanwhile, the calculated results when considering puffing and micro-explosions were in good agreement with experimental results at the same location. (author)

  12. Jet-A fuel evaporation analysis in conical tube injectors

    NASA Astrophysics Data System (ADS)

    Lai, M.-C.; Chue, T.-H.; Zhu, G.; Sun, H.; Tacina, R.; Chun, K.; Hicks, Y.

    1991-01-01

    A simple one-dimensional drop-life-history analysis and a multidimensional spray calculation using KIVA-II code are applied to the vaporization of Jet-A fuel in multiple tube injectors. Within the assumptions of the analysis, the one-dimensional results are useful for design purposes. The pressure-atomizer breakup models do not accurately predict the dropsize measured experimentally or deduced from the one-dimensional analysis. Cold flow visualization and dropsize measurements show that capillary wave breakup mechanism plays an important role in the spray angle and droplet impingement on the tube wall.

  13. A fundamental study of liquid spray evaporation at a heated surface

    NASA Technical Reports Server (NTRS)

    Wierum, F. A.

    1979-01-01

    The influence of feedwater temperature and the influence of pulsing nozzle flow on the heat transfer characteristics in the spray evaporative cooling process were investigated. A commercial water circulation heater was installed in the feedwater line between the supply reservoir and the nozzle. A pass through the heater provided water at temperatures up to 50 C at the nozzle; higher temperatures were obtained by multiple heater passes. A thermocouple installed in the water line just upstream of the nozzle provided a measure of the feedwater temperature. Initial tests were run with belljar exhaust orifice number two which provided a pressure in a range about 7mm Hg abs. The feedwater temperature was heated to a temperature of 45 C. Results indicate that for a given system operating pressure, there is an upper limit on the feedwater temperature above which the spray will flash to vapor before hitting the surface to be cooled.

  14. Spray evaporation and dispersion of n-heptane droplets within premixed flame

    NASA Astrophysics Data System (ADS)

    Chrigui, Mouldi; Zghal, Ali; Sadiki, Amsini; Janicka, Johannes

    2010-10-01

    A detailed numerical simulation of n-heptane droplets was carried out on a stationary three-dimensional configuration with complex geometry. The investigations focused on spray evaporation and dispersion within a carrier phase that featured operating conditions similar to those found in industrial applications, i.e. elevated pressure and temperature. The simulations were carried out using the Eulerian-Lagrangian approach with two-way coupling. There were two cases. The first dealt with spray characteristics within the preheated carrier phase without considering combustion. The second investigated the influence of combustion on droplet characteristics. Both cases had the same boundary conditions. The numerical simulations used two models to compute the progress variable mean reaction rate that governs the combustion process, which is captured by the Bray-Moss-Libby model.

  15. Characteristics of MCrAlY coatings sprayed by high velocity oxygen-fuel spraying system

    SciTech Connect

    Itoh, Y.; Saitoh, M.; Tamura, M.

    2000-01-01

    High velocity oxygen-fuel (HVOF) spraying system in open air has been established for producing the coatings that are extremely clean and dense. It is thought that the HVOF sprayed MCrAlY (M is Fe, Ni and/or Co) coatings can be applied to provide resistance against oxidation and corrosion to the hot parts of gas turbines. Also, it is well known that the thicker coating can be sprayed in comparison with any other thermal spraying systems due to improved residual stresses. However, thermal and mechanical properties of HVOF coatings have not been clarified. Especially, the characteristics of residual stress, that are the most important property from the view point of production technique, have not been made clear. In this paper, the mechanical properties of HVOF sprayed MCrAlY coatings were measured in both the case of as-sprayed and heat-treated coatings in comparison with a vacuum plasma sprayed MCrAlY coatings. It was confirmed that the mechanical properties of HVOF sprayed MCrAlY coatings could be improved by a diffusion heat treatment to equate the vacuum plasma sprayed MCrAlY coatings. Also, the residual stress characteristics were analyzed using a deflection measurement technique and a X-ray technique. The residual stress of HVOF coating was reduced by the shot-peening effect comparable to that of a plasma spray system in open air. This phenomena could be explained by the reason that the HVOF sprayed MCrAlY coating was built up by poorly melted particles.

  16. Dropwise ignition versus external ignition for multicomponent fuel sprays

    NASA Astrophysics Data System (ADS)

    Mawid, M.; Aggarwal, S. K.

    1988-07-01

    An attempt has been made to identify conditions for dropwise ignition and spray ignition. Both pure as well as multicomponent fuels are considered. For dropwise ignition, an existing ignition criterion has been modified to account for the nonlinear dependence of reaction rate on fuel and oxygen concentrations and to account for the multicomponent nature of the fuel. The external or spray ignition is considered through the zero heat flux condition at the ignition source. The effect of chemical kinetics is examined by employing reaction schemes with unity as well as non-unity exponents of fuel and oxygen concentrations. Results indicate that for most of the conditions considered, the individual droplet ignition is favored over the external ignition. Only when the drop diameter is smaller than 30 microns, the spray ignites earlier than droplets. The addition of a small amount of a volatile component significantly enhances the ignitability of both modes. However, the effect is stronger for the dropwise ignition mode.

  17. Some Characteristics of Fuel Sprays from Open Nozzles

    NASA Technical Reports Server (NTRS)

    Rothrock, A M; Lee, D W

    1930-01-01

    The penetration and cone-angle of fuel sprays from open nozzles were recorded with the NACA Spray Photography Equipment. The results show that for injection systems in which the rate of pressure rise at the discharge orifice is high, open nozzles give spray-tip velocities and penetrations which compare favorably with those of closed nozzles. The spray cone-angle was the same for all tests, although open nozzles having different orifice diameters were used, and one nozzle was used both as an open and as a closed nozzle. In designing a fuel system using open nozzles, particular care must be taken to avoid air pockets. The check valve should be placed close to the discharge orifice.

  18. Novel method for the measurement of liquid film thickness during fuel spray impingement on surfaces.

    PubMed

    Henkel, S; Beyrau, F; Hardalupas, Y; Taylor, A M K P

    2016-02-01

    This paper describes the development and application of a novel optical technique for the measurement of liquid film thickness formed on surfaces during the impingement of automotive fuel sprays. The technique makes use of the change of the light scattering characteristics of a metal surface with known roughness, when liquid is deposited. Important advantages of the technique over previously established methods are the ability to measure the time-dependent spatial distribution of the liquid film without a need to add a fluorescent tracer to the liquid, while the measurement principle is not influenced by changes of the pressure and temperature of the liquid or the surrounding gas phase. Also, there is no need for non-fluorescing surrogate fuels. However, an in situ calibration of the dependence of signal intensity on liquid film thickness is required. The developed method can be applied to measure the time-dependent and two-dimensional distribution of the liquid fuel film thickness on the piston or the liner of gasoline direct injection (GDI) engines. The applicability of this technique was evaluated with impinging sprays of several linear alkanes and alcohols with different thermo-physical properties. The surface temperature of the impingement plate was controlled to simulate the range of piston surface temperatures inside a GDI engine. Two sets of liquid film thickness measurements were obtained. During the first set, the surface temperature of the plate was kept constant, while the spray of different fuels interacted with the surface. In the second set, the plate temperature was adjusted to match the boiling temperature of each fuel. In this way, the influence of the surface temperature on the liquid film created by the spray of different fuels and their evaporation characteristics could be demonstrated. PMID:26906828

  19. Evaporation of multi-component mixtures and shell formation in spray dried droplets

    NASA Astrophysics Data System (ADS)

    Valente, Pedro; Duarte, Íris; Porfirio, Tiago; Temtem, Márcio

    2015-11-01

    Drug particles where the active pharmaceutical ingredient (APIs) is dispersed in a polymer matrix forming an amorphous solid dispersion (ASD) is a commonly used strategy to increase the solubility and dissolution rate of poorly water soluble APIs. However, the formation and stability of an amorphous solid dispersion depends on the polymer/API combination and process conditions to generate it. The focus of the present work is to further develop a numerical tool to predict the formation of ASDs by spray drying solutions of different polymer/API combinations. Specifically, the evaporation of a multi-component droplet is coupled with a diffusion law within the droplet that minimizes the Gibbs free energy of the polymer/API/solvents system, following the Flory-Huggins model. Prior to the shell formation, the evaporation of the solvents is modelled following the simplified approach proposed by Abramzon & Sirignano (1989) which accounts for the varying relative velocity between the droplet and the drying gas. After shell formation, the diffusion of the solvents across the porous shell starkly modifies the evaporative dynamics.

  20. An Experimental Investigation and Numerical Analysis of Multi-Component Fuel Spray

    NASA Astrophysics Data System (ADS)

    Myong, Kwang-Jae; Arai, Motoyuki; Tanaka, Tomoyuki; Senda, Jiro; Fujimoto, Hajime

    In this study, droplet atomization and vaporization characteristics with multi-component fuel were investigated by experimental and numerical simulation methods. Spray characteristics of multi-component fuel including spray cone angle, spray angle and spray tip penetration were analyzed from shadowgraph imaging. Numerical simulation to investigate spatial distribution of fuel-vapor concentration of each component within multi-component fuel was implemented in KIVA code. Vaporization process was calculated by a simple two-phase region which was approximated by modified saturated liquid-vapor line. Experimental results show that spray cone angle and spray angle become larger increasing in mass fraction of low boiling point component. And spray tip penetration becomes shorter with increasing in mass fraction of low boiling point component in vaporizing spray during that is same on every mixed fuel in non-vaporizing spray. From numerical simulation results, temporal and spatial distribution of each fuel vapor concentration was found to be stratification.

  1. Certification of an agricultural spray aircraft on ethanol fuel

    SciTech Connect

    Shauck, M.E.; Zanin, M.G.

    1994-12-31

    A Piper Pawnee, one of the most common agricultural spray aircraft, is currently undergoing Federal Aviation Administration (FAA) certification to allow the use of denatured ethanol as its fuel. This certification is part of a broader effort to introduce ethanol as a replacement for aviation gasoline. Various reasons brought about the choice of an agricultural spray aircraft to be certified on ethanol. One is the minimization of initial fuel distribution problems. Agricultural aviation often requires only single fuel storage since most of the flying is local. Additionally, corn-produced ethanol is the natural fuel of choice for farming operations. The increased power developed on ethanol compared to aviation gasoline (avgas) is very important when operating heavily loaded spray aircraft at very low altitudes. The power-plant, a Lycoming IO-540, is already certified. The aircraft is currently flying on ethanol in order to satisfy the airframe requirements. The effort is being supported by a consortium of organizations of corn-producing states. Upon completion of certification, the aircraft will be demonstrated around the mid-western states. Certification will allow the use of the aircraft in the commercial arena. Many mid-western agricultural spray operations and ag-pilots have already expressed interest in converting their aircraft to ethanol fuel.

  2. Spray Penetration with a Simple Fuel Injection Nozzle

    NASA Technical Reports Server (NTRS)

    Miller, Harold E; Beardsley, Edward G

    1926-01-01

    The purpose of the tests covered by this report was to obtain specific information on the rate of penetration of the spray from a simple injection nozzle, having a single orifice with a diameter of 0.015 inch when injecting into compressed gases. The results have shown that the effects of both chamber and fuel pressures on penetration are so marked that the study of sprays by means of high-speed photography or its equivalent is necessary if the effects are to be appreciated sufficiently to enable rational analysis. It was found for these tests that the negative acceleration of the spray tip is approximately proportional to the 1.5 power of the instantaneous velocity of the spray tip.

  3. High-pressure combustion of binary fuel sprays

    NASA Technical Reports Server (NTRS)

    Mikami, Masato; Kono, Michikata; Sato, Jun'ichi; Dietrich, Daniel L.; Williams, Forman A.

    1995-01-01

    The ultimate objective of this study is to obtain fundamental information relevant to combustion processes that occur in fuel sprays of practical interest at high pressures in internal combustion engines. Since practical fuels are multicomponent and derived from petroleum, the present work involves the model alkane mixture of n-heptane and n-hexadecane. Since burning droplets in sprays can interact with each other, the present work involves investigation of the effects of this interaction on flame shapes and droplet burning times. The small droplets in practical combustion chambers are not significantly influenced by buoyancy. Since such small droplets are difficult to study experimentally, the present work takes advantage of microgravity to lessen buoyancy and enable information about droplet interactions to be obtained by studying larger droplets. The results are intended to provide fundamental understanding that can be used in improving descriptions of practical spray combustion.

  4. Diffusion properties of aqueous slurries in evaporative spray drying of copper (II) chloride dihydrate

    NASA Astrophysics Data System (ADS)

    Slowikowski, M.; Naterer, G. F.; Odukoya, A.

    2014-09-01

    This study examines the evaporative heat transfer and diffusive mass transfer of a droplet of CuCl2 solution. The validation of a new predictive model involves comparisons with experimental data from previous studies of different fluids based on non-dimensional analysis. The study provides new insight about the effects of different concentrations of water on the CuCl2 slurry drying at low to moderate air temperatures. Predictive correlations of heat and mass transfer are developed for the aqueous solution, subject to various drying conditions. The analysis is performed for moist air in contact with a sprayed aqueous solution of copper (II) chloride dihydrate [CuCl2·(2H2O)]. Results are presented and discussed for the drying processes.

  5. Influence of drop size distribution and fuel vapor fraction on premixed spray combustion

    NASA Astrophysics Data System (ADS)

    Machiroutu, Sridhar Venkatabojji

    Premixed spray combustion is affected by fuel and oxidizer properties, mixture equivalence ratio and spray quality. The spray quality is characterized by a mean droplet diameter (SMD) and a droplet size distribution (DSD). Prior experimental studies have considered only the influence of SMD, in part due to the difficulty in controlling the DSD independently. The present work provides experimental evidence demonstrating the effect of the fuel droplet size distribution and fuel vapor fraction on premixed spray combustion. Combustion experiments were performed in a pilot-ignited, continuous flow, tubular, vertical test rig wherein fuel sprays were injected into an air stream. A novel twin-atomizer technique that allowed control over overall equivalence ratio, SMD, DSD, and fuel vapor fraction of the premixed spray was used to generate test sprays. A line-of-sight, infrared (IR) extinction technique was developed to quantify the fuel vapor fraction in premixed sprays. Radial distributions of fuel vapor were evaluated using an 'onion peeling' deconvolution technique. Combustion of test sprays indicated flame propagation among regions of high fuel vapor fraction to generate a high rate of combustion. In lean premixed sprays, the presence of a low fuel vapor concentration does not impact the combustion process. Experimental evidence demonstrating the enhancement of flame propagation velocity for optimal SMDs of ethanol sprays has been found. It was observed that test sprays with narrower DSDs have faster burning rates and more complete combustion. The DSD of the sprays were characterized with a droplet surface-area-based standard deviation of the DSD.

  6. Ion/molecule reaction and ion evaporation in atmospheric pressure spray ionization

    NASA Astrophysics Data System (ADS)

    Hirabayashi, Atsumu; Takada, Yasuaki; Kambara, Hideki; Umemura, Yuta; Ohta, Hitoshi; Ito, Haruhiko; Kuchitsu, Kozo

    1992-12-01

    The positive ions produced in atmospheric pressure spray ionization of ammonia, alanine and sucrose in aqueous solution were detected with a double-focusing mass spectrometer. The relative intensities of the quasi-molecular ions of ammonia, NH+4 (H2O)n (n = 0-3), were found to be proportional to the concentration of the ammonia solution and to increase with increasing distance d between the nozzle tip and the sample aperture of the mass spectrometer; this observation shows that the ammonia molecule is produced by the spray and is protonated at atmospheric pressure by a proton transfer reaction with the hydronium ion and its hydrated clusters. The observed dependences of the relative intensities of the protonated alanine molecules from alanine solution and the cationized sucrose molecules from sucrose solution on d show that some part of these quasi-molecular ions are also produced by the ion/molecule reaction in the gas phase. However, their dependences on the concentration, which are steeper than that in the ammonia case, indicate that a significant proportion of these ions are produced by ion evaporation from a droplet or liquid.

  7. Numerical investigation of spray ignition of a multi-component fuel surrogate

    NASA Astrophysics Data System (ADS)

    Backer, Lara; Narayanaswamy, Krithika; Pepiot, Perrine

    2014-11-01

    Simulating turbulent spray ignition, an important process in engine combustion, is challenging, since it combines the complexity of multi-scale, multiphase turbulent flow modeling with the need for an accurate description of chemical kinetics. In this work, we use direct numerical simulation to investigate the role of the evaporation model on the ignition characteristics of a multi-component fuel surrogate, injected as droplets in a turbulent environment. The fuel is represented as a mixture of several components, each one being representative of a different chemical class. A reduced kinetic scheme for the mixture is extracted from a well-validated detailed chemical mechanism, and integrated into the multiphase turbulent reactive flow solver NGA. Comparisons are made between a single-component evaporation model, in which the evaporating gas has the same composition as the liquid droplet, and a multi-component model, where component segregation does occur. In particular, the corresponding production of radical species, which are characteristic of the ignition of individual fuel components, is thoroughly analyzed.

  8. Measurement of vapor/liquid distributions in a binary-component fuel spray using laser imaging of droplet scattering and vapor absorption

    NASA Astrophysics Data System (ADS)

    Li, Shiyan; Zhang, Yuyin; Wu, Shenqi; Xu, Bin

    2014-08-01

    Fuel volatility has a great effect on its evaporation processes and the mixture formation and thus combustion and emissions formation processes in internal combustion engines. To date, however, instead of the actual gasoline or diesel fuel, many researchers have been using single-component fuel in their studies, because the composition of the former is too complicated to understand the real physics behind the evaporation and combustion characteristics. Several research groups have reported their results on droplets evaporation in a spray of multi-component fuel, carried out both numerically and experimentally. However, there are plenty of difficulties in quantitative determination of vapor concentration and droplet distributions of each component in a multicomponent fuel spray. In this study, to determine the vapor phase concentration and droplet distributions in an evaporating binary component fuel spray, a laser diagnostics based on laser extinction by droplet scattering and vapor absorption was developed. In practice, measurements of the vapor concentration distributions of the lower (n-tridencane) and higher (n-octane) volatility components in the binary component fuel sprays have been carried out at ambient temperatures of 473K and 573K, by substituting p-xylene for noctane or α-methylnaphthalene for n-tridecane. p-Xylene and α-methylnaphthalene were selected as the substitutes is because they have strong absorption band near 266nm and transparent near 532nm and, their thermo-physical properties are similar to those of the original component. As a demonstration experiment, vapor/liquid distribution of the lower boiling point (LBP) and higher boiling point (HBP) components in the binary component fuel spray have been obtained.

  9. Effects of fuel evaporation on the octane number of methanol-gasoline blended fuels

    SciTech Connect

    Moran, D.P.

    1994-10-01

    A procedure is described to estimate the influence of end-gas temperature on Octane Number. Blending methanol with gasoline is known to cause a disproportionate increase in Research Octane Number, and this is found to correlate well with the evaporative cooling characteristics of these blends. The Motor Octane Number test eliminates evaporative effects, and the difference between the two test methods is evaluated in terms of evaporative cooling. It is concluded that the high heat of vaporization of methanol is largely responsible for the excellent RON performance of methanol-gasoline blended fuels. 17 refs., 11 refs., 2 tabs.

  10. A Comparison of Fuel Sprays from Several Types of Injection Nozzles

    NASA Technical Reports Server (NTRS)

    Lee, Dana W

    1936-01-01

    This report presents the tests results of a series of tests made of the sprays from 14 fuel injection nozzles of 9 different types, the sprays being injected into air at atmospheric density and at 6 and 14 times atmospheric density. High-speed spark photographs of the sprays from each nozzle at each air density were taken at the rate of 2,000 per second, and from them were obtained the dimensions of the sprays and the rates of spray-tip penetration. The sprays were also injected against plasticine targets placed at different distances from the nozzles, and the impressions made in the plasticine were used as an indication of the distribution of the fuel within the spray. Cross-sectional sketches of the different types of sprays are given showing the relative sizes of the spray cores and envelopes. The characteristics of the sprays are compared and discussed with respect to their application to various types of engines.

  11. Thermal Plasma Spraying Applied on Solid Oxide Fuel Cells

    NASA Astrophysics Data System (ADS)

    Soysal, D.; Arnold, J.; Szabo, P.; Henne, R.; Ansar, S. A.

    2013-06-01

    Solid oxide fuel cells (SOFCs), attractive for diverse applications in a broad range from small portable and auxiliary power units, up to central power systems, are conventionally produced by sintering methods. However, plasma spraying promises some advantages particularly for cells with metal support. In the present paper, research activities conducted in recent years at DLR as well as latest developments on plasma sprayed functional layers for SOFC as cathodes, electrolytes, and anodes are reported. Power densities of more than 800 mW/cm2 were achieved for plasma sprayed single cells of 12.56 cm2 size, and 300 mW/cm2, respectively, with a 250 W stack made of 10 cells. These values were attained at 0.7 V and 800 °C, with H2:N2 = 1:1 as fuel gas and air as oxidizing gas. Furthermore, continuous operation of more than 5000 h was attained with a plasma sprayed metal-supported SOFC stack which could also withstand more than 30 redox and thermal cycles.

  12. Vacuum plasma spray applications on liquid fuel rocket engines

    NASA Technical Reports Server (NTRS)

    Mckechnie, T. N.; Zimmerman, F. R.; Bryant, M. A.

    1992-01-01

    The vacuum plasma spray process (VPS) has been developed by NASA and Rocketdyne for a variety of applications on liquid fuel rocket engines, including the Space Shuttle Main Engine. These applications encompass thermal barrier coatings which are thermal shock resistant for turbopump blades and nozzles; bond coatings for cryogenic titanium components; wear resistant coatings and materials; high conductivity copper, NaRloy-Z, combustion chamber liners, and structural nickel base material, Inconel 718, for nozzle and combustion chamber support jackets.

  13. Vacuum plasma spray applications on liquid fuel rocket engines

    NASA Astrophysics Data System (ADS)

    McKechnie, T. N.; Zimmerman, F. R.; Bryant, M. A.

    1992-07-01

    The vacuum plasma spray process (VPS) has been developed by NASA and Rocketdyne for a variety of applications on liquid fuel rocket engines, including the Space Shuttle Main Engine. These applications encompass thermal barrier coatings which are thermal shock resistant for turbopump blades and nozzles; bond coatings for cryogenic titanium components; wear resistant coatings and materials; high conductivity copper, NaRloy-Z, combustion chamber liners, and structural nickel base material, Inconel 718, for nozzle and combustion chamber support jackets.

  14. Combustion characteristics in the transition region of liquid fuel sprays

    NASA Technical Reports Server (NTRS)

    Cernansky, N. P.; Namer, I.; Tidona, R. J.; Sarv, H.

    1984-01-01

    A monodisperse aerosol generator was modified to study ignition requirements, flammability limits, and flame speeds in the transition region. An ignition system was developed and tested. The fabrication of an optical drop sizing system is nearly complete. Preliminary measurements of droplet size effects on the minimum ignition energy for n-heptane sprays performed. Parameteric studies of droplet size effects on minimum ignition energies of various fuels including alcohols are in progress.

  15. Spray deposition of Nafion membranes: Electrode-supported fuel cells

    NASA Astrophysics Data System (ADS)

    Bayer, Thomas; Pham, Hung Cuong; Sasaki, Kazunari; Lyth, Stephen Matthew

    2016-09-01

    Fuel cells are a key technology for the successful transition towards a hydrogen society. In order to accelerate fuel cell commercialization, improvements in performance are required. Generally, polymer electrolyte membrane fuel cells (PEFCs) are membrane-supported; the electrocatalyst layer is sprayed onto both sides of the membrane, and sandwiched between carbon-based gas diffusion layers (GDLs). In this work we redesign the membrane electrode assembly (MEA) and fabricate an electrode-supported PEFC. First the electrocatalyst layer is sprayed onto the GDL, and then Nafion dispersion is sprayed over the top of this to form a thin membrane. This method has the advantage of simplifying the fabrication process, allowing the fabrication of extremely thin electrolyte layers (down to ∼10 μm in this case), and reducing the amount of ionomer required in the cell. Electrode-supported PEFCs operate at significantly increased power density compared to conventional membrane-supported PEFCs, with a maximum of 581 mW/cm2 at 80 °C (atmospheric pressure, air at the cathode). Impedance spectroscopy confirmed that the origin of the improved performance was an 80% reduction in the membrane resistance due the thinner Nafion layer. This novel fabrication method is a step towards cheaper, thinner, fully printable PEFCs with high power density and efficiency.

  16. Efficiency of using solid wood fuels in maple syrup evaporators. Forest service research paper (final)

    SciTech Connect

    Garrett, L.D.

    1981-01-01

    A study of commercial, wood-fired evaporators revealed that normal expected thermal efficiencies are between 35 to 50 percent. The moisture content and quality of wood fuels used and the design and method of firing the evaporator are critical in determining evaporator efficiency and the economic implications of using wood.

  17. Process gases for high velocity oxy-fuel thermal spraying

    SciTech Connect

    Creffield, G.K.; Chapman, I.F.; Cole, M.A.; Page, W.J.; McDonough, T.

    1994-12-31

    The importance of fuel and other process gases for high velocity oxy-fuel (HVOF) thermal spraying and especially the delivery of them to the point of use is well recognized. Problems associated with the supply of liquid fuel gases, at the high flow rates and pressures required by this process, have been addressed. Considerable development work has gone into designing an appropriate liquid withdrawal and vaporizer system for propylene, which overcomes these previous difficulties and enables users to maintain adequate fuel gas flow rates in order to ensure optimum operating conditions for the production of high quality coatings. A feature of the thermal spray process is that the temperature of the workpiece is kept low, typically below 150 C, in order to reduce residual stresses in the coating and to protect heat sensitive substrates. Traditionally this has been by compressed air, however, improved cooling has been achieved using carbon dioxide. Specially designed equipment is now available which provides and directs a cold mixture of carbon dioxide gas and solid particles (snow) via suitable nozzles, on the workpiece. The position of the cooling stream can be varied, depending on the application. These developments emphasize the importance now attached to providing dedicated gas installation packages for HVOF.

  18. Measurements of Fuel Distribution Within Sprays for Fuel-Injection Engines

    NASA Technical Reports Server (NTRS)

    Lee, Dana W

    1937-01-01

    Two methods were used to measure fuel distribution within sprays from several types of fuel-injection nozzles. A small tube inserted through the wall of an air tight chamber into which the sprays were injected could be moved about inside the chamber. When the pressure was raised to obtain air densities of 6 and 14 atmospheres, some air was forced through the tube and the fuel that was carried with it was separated by absorbent cotton and weighed. Cross sections of sprays from plain, pintle, multiple-orifice, impinging-jets, centrifugal, lip, slit, and annular-orifice nozzles were investigated, at distances of 1, 3, 5, and 7 inches from the nozzles.

  19. A Nonlinear Model for Fuel Atomization in Spray Combustion

    NASA Technical Reports Server (NTRS)

    Liu, Nan-Suey (Technical Monitor); Ibrahim, Essam A.; Sree, Dave

    2003-01-01

    Most gas turbine combustion codes rely on ad-hoc statistical assumptions regarding the outcome of fuel atomization processes. The modeling effort proposed in this project is aimed at developing a realistic model to produce accurate predictions of fuel atomization parameters. The model involves application of the nonlinear stability theory to analyze the instability and subsequent disintegration of the liquid fuel sheet that is produced by fuel injection nozzles in gas turbine combustors. The fuel sheet is atomized into a multiplicity of small drops of large surface area to volume ratio to enhance the evaporation rate and combustion performance. The proposed model will effect predictions of fuel sheet atomization parameters such as drop size, velocity, and orientation as well as sheet penetration depth, breakup time and thickness. These parameters are essential for combustion simulation codes to perform a controlled and optimized design of gas turbine fuel injectors. Optimizing fuel injection processes is crucial to improving combustion efficiency and hence reducing fuel consumption and pollutants emissions.

  20. The Effects of Fuel and Cylinder Gas Densities on the Characteristics of Fuel Sprays for Oil Engines

    NASA Technical Reports Server (NTRS)

    Joachim, W F; Beardsley, Edward G

    1928-01-01

    This investigation was conducted as a part of a general research on fuel-injection engines for aircraft. The purpose of the investigation was to determine the effects of fuel and cylinder gas densities with several characteristics of fuel sprays for oil engines. The start, growth, and cut-off of single fuel sprays produced by automatic injection valves were recorded on photographic film by means of special high-speed motion-picture apparatus. This equipment, which has been described in previous reports, is capable of taking twenty-five consecutive pictures of the moving spray at the rate of 4,000 per second. The penetrations of the fuel sprays increased and the cone angles and relative distributions decreased with increase in the specific gravity of the fuel. The density of the gas into which the fuel sprays were injected controlled their penetration. This was the only characteristic of the chamber gas that had a measurable effect upon the fuel sprays. Application of fuel-spray penetration data to the case of an engine, in which the pressure is rising during injection, indicated that fuel sprays may penetrate considerably farther than when injected into a gas at a density equal to that of the gas in an engine cylinder at top center.

  1. Carbon nanotube reinforced aluminum nanocomposite via plasma and high velocity oxy-fuel spray forming.

    PubMed

    Laha, T; Liu, Y; Agarwal, A

    2007-02-01

    Free standing structures of hypereutectic aluminum-23 wt% silicon nanocomposite with multiwalled carbon nanotubes (MWCNT) reinforcement have been successfully fabricated by two different thermal spraying technique viz Plasma Spray Forming (PSF) and High Velocity Oxy-Fuel (HVOF) Spray Forming. Comparative microstructural and mechanical property evaluation of the two thermally spray formed nanocomposites has been carried out. Presence of nanosized grains in the Al-Si alloy matrix and physically intact and undamaged carbon nanotubes were observed in both the nanocomposites. Excellent interfacial bonding between Al alloy matrix and MWCNT was observed. The elastic modulus and hardness of HVOF sprayed nanocomposite is found to be higher than PSF sprayed composites. PMID:17450788

  2. Evaporation Of Clustered Drops Of Binary-Liquid Fuels

    NASA Technical Reports Server (NTRS)

    Bellan, Josette; Harstad, Kenneth G.

    1993-01-01

    Report repeats and elaborates upon information presented in "Diffusion Of Mass In Evaporating Multicomponent Drops" (NPO-18206). Presents details of mathematical model of evaporation of binary liquid from both dense and dilute clusters of drops. Interactions among evaporation, diffusion in liquids, slip velocity, and other phenomena modeled.

  3. Evaporative cooling by a pulsed jet spray of binary ethanol-water mixture

    NASA Astrophysics Data System (ADS)

    Karpov, P. N.; Nazarov, A. D.; Serov, A. F.; Terekhov, V. I.

    2015-07-01

    We have experimentally studied the heat transfer under conditions of pulsed multinozzle jet spray impact onto a vertical surface. The working coolant fluid was aqueous ethanol solution in a range of concentrations K 1 = 0-96%. The duration of spray pulses was τ = 2, 4, and 10 ms at a repetition frequency of 10 Hz. The maximum heat transfer coefficient was achieved at an ethanol solution concentration within 50-60%. The thermal efficiency of pulsed spray cooling grows with increasing ethanol concentration and decreasing jet spray pulse duration.

  4. Solid oxide fuel cell electrolytes produced by a combination of suspension plasma spray and very low pressure plasma spray.

    SciTech Connect

    Slamovich, Elliot; Fleetwood, James; McCloskey, James F.; Hall, Aaron Christopher; Trice, Rodney Wayne

    2010-07-01

    Plasma spray coating techniques allow unique control of electrolyte microstructures and properties as well as facilitating deposition on complex surfaces. This can enable significantly improved solid oxide fuel cells (SOFCs), including non-planar designs. SOFCs are promising because they directly convert the oxidization of fuel into electrical energy. However, electrolytes deposited using conventional plasma spray are porous and often greater than 50 microns thick. One solution to form dense, thin electrolytes of ideal composition for SOFCs is to combine suspension plasma spray (SPS) with very low pressure plasma spray (VLPPS). Increased compositional control is achieved due to dissolved dopant compounds in the suspension that are incorporated into the coating during plasma spraying. Thus, it is possible to change the chemistry of the feed stock during deposition. In the work reported, suspensions of sub-micron diameter 8 mol.% Y2O3-ZrO2 (YSZ) powders were sprayed on NiO-YSZ anodes at Sandia National Laboratories (SNL) Thermal Spray Research Laboratory (TSRL). These coatings were compared to the same suspensions doped with scandium nitrate at 3 to 8 mol%. The pressure in the chamber was 2.4 torr and the plasma was formed from a combination of argon and hydrogen gases. The resultant electrolytes were well adhered to the anode substrates and were approximately 10 microns thick. The microstructure of the resultant electrolytes will be reported as well as the electrolyte performance as part of a SOFC system via potentiodynamic testing and impedance spectroscopy.

  5. Study of optical and structural properties of CZTS thin films grown by co-evaporation and spray pyrolysis

    NASA Astrophysics Data System (ADS)

    Moreno, R.; Ramirez, E. A.; Gordillo Guzmán, G.

    2016-02-01

    Results regarding optical and structural properties of Cu2ZnSnS4 (CZTS) thin films prepared by co-evaporation using a novel procedure are compared with those obtained with CZTS films grown using a solution based route. The lattice strain ε and crystallite size D of CZTS films prepared by co-evaporation and by spray pyrolysis were estimated through X-ray diffraction (XRD) measurements using Williamson-Hall-isotropic strain model. The results of estimated average crystallite size of CZTS films by Scherrer and Williamson-Hall plot methods were compared with AFM (atomic force microscopy) measurements. It was found that the average crystallite size measured by Williamson-Hall plot methods agree quite well with AFM results. Further, information regarding the influence of preparation method on both, crystalline phases and the formation of structural defects was achieved through Raman and Urbach energy measurements.

  6. One-dimensional and quasi-one-dimensional ZnO nanostructures prepared by spray-pyrolysis-assisted thermal evaporation

    NASA Astrophysics Data System (ADS)

    Liu, Wen-Cheng; Cai, Wei

    2008-03-01

    One-dimensional (1D) and quasi-1D ZnO nanostructures have been fabricated by a kind of new spray-pyrolysis-assisted thermal evaporation method. Pure ZnO powder serves as an evaporation source. Thus-obtained products have been characterized by X-ray diffraction (XRD) analysis, scanning electron microscope (SEM) equipped with energy dispersive X-ray spectroscopy (EDS), transmission electron microscope (TEM). The room temperature photoluminescence spectrum of these ZnO nanostructures is presented. The results show that as-grown ZnO nanomaterials have a hexagonal wurtzite crystalline structure. Besides nanosaws, nanobelts and nanowires, complex ZnO nanotrees have also been observed in synthesized products. The study provides a new simple route to construct 1D and quasi-1D ZnO nanomaterials, which can probably be extended to fabricate other oxide nanomaterials with high melting point and doped oxide nanomaterials.

  7. Some Effects of Air and Fuel Oil Temperatures on Spray Penetration and Dispersion

    NASA Technical Reports Server (NTRS)

    Gelalles, A G

    1930-01-01

    Presented here are experimental results obtained from a brief investigation of the appearance, penetration, and dispersion of oil sprays injected into a chamber of highly heated air at atmospheric pressure. The development of single sprays injected into a chamber containing air at room temperature and at high temperature was recorded by spray photography equipment. A comparison of spray records showed that with the air at the higher temperature, the spray assumed the appearance of thin, transparent cloud, the greatest part of which rapidly disappeared from view. With the chamber air at room temperature, a compact spray with an opaque core was obtained. Measurements of the records showed a decrease in penetration and an increase in the dispersion of the spray injected into the heated air. No ignition of the fuel injected was observed or recorded until the spray particles came in contact with the much hotter walls of the chamber about 0.3 second after the start of injection.

  8. Original use of a direct injection high efficiency nebulizer for the standardization of liquid fuels spray flames

    NASA Astrophysics Data System (ADS)

    Lemaire, R.; Maugendre, M.; Schuller, T.; Therssen, E.; Yon, J.

    2009-10-01

    It is of practical importance to lead laboratory-scale experiments allowing a better understanding of the impact of commercial fuels composition on the formation of combustion residues such as soot particles. To this end, a hybrid burner has been designed recently to burn high-speed sprays of small liquid fuel droplets. It consists of a Holthuis (previously McKenna) burner originally equipped with a direct injection high efficiency nebulizer for the atomization of liquid hydrocarbons. A detailed description of this original setup is given in this paper. A priori estimations of atomization and evaporation times and length scales are then proposed and compared with experimental data. Droplet-size distribution measurements obtained in nonreacting conditions using a Malvern Spraytec particle sizer are presented and compared with values estimated by calculation. Cold sprays contours and liquid jet lengths in flames determined by Mie scattering at 532 and 1064 nm, respectively, are also presented. The results discussed in this work indicate that the hydrodynamic characteristics of the sprays generated with our system are relatively independent of the physical properties of fuels leading to comparable flames with identical liquid jet lengths, dimensions, and global structure. This feature facilitates an accurate comparison of flames burning various liquid hydrocarbons, which is of interest to emphasize differences in pollutants emissions and to highlight chemical effects for soot formation analysis.

  9. Injector spray characterization of methanol in reciprocating engines

    SciTech Connect

    Dodge, L.; Naegeli, D.

    1994-06-01

    This report covers a study that addressed cold-starting problems in alcohol-fueled, spark-ignition engines by using fine-spray port-fuel injectors to inject fuel directly into the cylinder. This task included development and characterization of some very fine-spray, port-fuel injectors for a methanol-fueled spark-ignition engine. After determining the spray characteristics, a computational study was performed to estimate the evaporation rate of the methanol fuel spray under cold-starting and steady-state conditions.

  10. An evaporative and engine-cycle model for fuel octane sensitivity prediction

    SciTech Connect

    Moran, D.P.; Taylor, A.B.

    1995-12-31

    The Motor Octane Number (MON) ranks fuels by their chemical resistance to knock. Evaporative cooling coupled with fuel chemistry determine Research Octane Number (RON) antiknock ratings. It is shown in this study that fuel Octane sensitivity (numerically RON minus MON) is liked to an important difference between the two test methods; the RON test allows each fuel`s evaporative cooling characteristics to affect gas temperature, while the MON test generally eliminates this effect by pre-evaporation. In order to establish RON test charge temperatures, a computer model of fuel evaporation was adapted to Octane Engine conditions, and simulations were compared with real Octane Test Engine measurements including droplet and gas temperatures. A novel gas temperature probe yielded data that corresponded well with model predictions. Tests spanned single component fuels and blends of isomers, n-paraffins, aromatics and alcohols. Commercially available automotive and aviation gasolines were also tested. A good correlation was observed between the computer predictions and measured temperature data across the range of pure fuels and blends. A numerical method to estimate the effect of precombustion temperature differences on Octane sensitivity was developed and applied to analyze these data, and was found to predict the widely disparate sensitivities of the tested fuels with accuracy. Data are presented showing mixture temperature histories of various tested fuels, and consequent sensitivity predictions. It is concluded that a fuel`s thermal-evaporative behavior gives rise to fuel Octane sensitivity as measured by differences between the RON and MON tests. This is demonstrated by the success, over a wide range of fuels, of the sensitivity predictor method describes. Evaporative cooling, must therefore be regarded as an important parameter affecting the general road performance of automobiles.

  11. Group evaporation

    NASA Technical Reports Server (NTRS)

    Shen, Hayley H.

    1991-01-01

    Liquid fuel combustion process is greatly affected by the rate of droplet evaporation. The heat and mass exchanges between gas and liquid couple the dynamics of both phases in all aspects: mass, momentum, and energy. Correct prediction of the evaporation rate is therefore a key issue in engineering design of liquid combustion devices. Current analytical tools for characterizing the behavior of these devices are based on results from a single isolated droplet. Numerous experimental studies have challenged the applicability of these results in a dense spray. To account for the droplets' interaction in a dense spray, a number of theories have been developed in the past decade. Herein, two tasks are examined. One was to study how to implement the existing theoretical results, and the other was to explore the possibility of experimental verifications. The current theoretical results of group evaporation are given for a monodispersed cluster subject to adiabatic conditions. The time evolution of the fluid mechanic and thermodynamic behavior in this cluster is derived. The results given are not in the form of a subscale model for CFD codes.

  12. Microstructure and properties of tungsten carbide coatings sprayed with various high-velocity oxygen fuel spray systems

    NASA Astrophysics Data System (ADS)

    Schwetzke, R.; Kreye, H.

    1999-09-01

    This article reports on a series of experiments with various high-velocity oxygen fuel spray systems (Jet Kote, Top Gun, Diamond Jet (DJ) Standard, DJ 2600 and 2700, JP-5000, Top Gun-K) using different WC-Co and WC-Co-Cr powders. The microstructure and phase composition of powders and coatings were analyzed by optical and scanning electron microscopy and x-ray diffraction. Carbon and oxygen content of the coatings were determined to study the decarburization and oxidation of the material during the spray process. Coatings were also characterized by their hardness, bond strength, abrasive wear, and corrosion resistance. The results demonstrate that the powders exhibit various degrees of phase transformation during the spray process depending on type of powder, spray system, and spray parameters. Within a relatively wide range, the extent of phase transformation has only little effect on coating properties. Therefore, coatings of high hardness and wear resistance can be produced with all HVOF spray systems when the proper spray powder and process parameters are chosen.

  13. Gas density effect on dropsize of simulated fuel sprays

    NASA Technical Reports Server (NTRS)

    Ingebo, Robert D.

    1989-01-01

    Two-phase flow in pneumatic two-fluid fuel nozzles was investigated experimentally to determine the effect of atomizing-gas density and gas mass-flux on liquid-jet breakup in sonic-velocity gas-flow. Dropsize data were obtained for the following atomizing-gases: nitrogen; argon; carbon dioxide; and helium. They were selected to cover a gas molecular-weight range of 4 to 44. Atomizing-gas mass-flux ranged from 6 to 50 g/sq cm-sec and four differently sized two-fluid fuel nozzles were used having orifice diameters that varied from 0.32 to 0.56 cm. The ratio of liquid-jet diameter to SMD, D sub o/D sub 32, was correlated with aerodynamic and liquid-surface forces based on the product of the Weber and Reynolds number, and gas-to-liquid density ratio, rho sub g/rho sub 1. To correlate spray dropsize with breakup forces produced by using different atomizing-gases, a new molecular-scale dimensionless group was derived. The derived dimensionless group was used to obtain an expression for the ratio of liquid-jet diameter to SMD, D sub o/D sub 32. The mathematical expression of this phenomenon incorporates the product of the Weber and Reynolds number, liquid viscosity, surface tension, acoustic gas velocity, the RMS velocity of gas molecules, the acceleration of gas molecules due to gravity, and gas viscosity. The mathematical expression encompassing these parameters agrees well with the atomization theory for liquid-jet breakup in high velocity gas flow. Also, it was found that at the same gas mass-flux, helium was considerably more effective than nitrogen in producing small droplet sprays with SMD's in the order of 5 micrometers.

  14. Characterization of high velocity oxy-fuel combustion sprayed hydroxyapatite.

    PubMed

    Haman, J D; Lucas, L C; Crawmer, D

    1995-02-01

    Bioceramic coatings, created by the high velocity oxy-fuel combustion spraying of hydroxyapatite (HA) powders onto commercially pure titanium, were characterized in order to determine whether this relatively new coating process can be successfully applied to bioceramic coatings of orthopaedic and dental implants. Fourier transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy were used to characterize both the HA starting powders and coatings. A 12 wk immersion test was conducted and the resulting changes in the coatings were also characterized. Calcium ion release during dissolution was measured with flame atomic absorption during the first 6 weeks of the immersion study. A comparison of powder and coating X-ray diffraction patterns and lattice parameters revealed an HA-type coating with some loss in crystallinity. Fourier transform infrared results showed a partial loss of the OH- group during spraying, however the phosphate groups were still present. Scanning electron microscopy analysis showed a lamellar structure with very close coating-to-substrate apposition. The coatings experienced a loss of calcium during the immersion study, with the greatest release in calcium occurring during the first 6 days of the study. No significant structural or chemical changes were observed during the 12 wk immersion study. These results indicate that the high velocity oxy-fuel process can produce an HA-type coating; however, the process needs further optimization, specifically in the areas of coating-to-substrate bond strength and minimization of phases present other than HA, before it would be recommended for commercial use. PMID:7749000

  15. Gas density effect on dropsize of simulated fuel sprays

    NASA Technical Reports Server (NTRS)

    Ingebo, Robert D.

    1989-01-01

    Two-phase flow in pneumatic two-fluid fuel nozzles was investigated experimentally to determine the effect of atomizing-gas density and gas mass-flux on liquid-jet breakup in sonic-velocity gas-flow. Dropsize data were obtained for the following atomizing-gases: nitrogen; argon; carbon dioxide; and helium. They were selected to cover a gas molecular-weight range of 4 to 44. Atomizing-gas mass-flux ranged from 6 to 50 g/sq cm-sec and four differently sized two-fluid fuel nozzles were used having orifice diameters that varied from 0.32 to 0.56 cm. The ratio of liquid-jet diameter to SMD, D sub o/D sub 32, was correlated with aerodynamic and liquid-surface forces based on the product of the Weber and Reynolds number, We*Re, and gas-to-liquid density ratio, rho sub g/rho sub l. To correlate spray dropsize with breakup forces produced by using different atomizing-gases, a new molecular-scale dimensionless group was derived. The derived dimensionless group was used to obtain an expression for the ratio of liquid-jet diameter to SMD, D sub o/D sub 32. The mathematical expression of this phenomenon incorporates the product of the Weber and Reynolds number, liquid viscosity, surface tension, acoustic gas velocity, the RMS velocity of gas molecules, the acceleration of gas molecules due to gravity, and gas viscosity. The mathematical expression encompassing these parameters agrees well with the atomization theory for liquid-jet breakup in high velocity gas flow. Also, it was found that at the same gas mass-flux, helium was considerably more effective than nitrogen in producing small droplet sprays with SMD's in the order of 5 micrometers.

  16. A laser tomographic investigation of liquid fuel sprays

    NASA Technical Reports Server (NTRS)

    Yule, A. J.; Ahseng, C.; Felton, P.; Ungut, A.; Chigier, N. A.

    1980-01-01

    A light scattering technique is combined with a tomographic transformation to convert line of sight integrated data, measured in sprays, to measurements of droplet size and concentration in volume elements within the spray. The technique is developed and assessed by systematic experiments in axisymmetric sprays generated by twin-fluid atomisers. The good agreement found shows that, provided certain conditions are satisfied by the local spray structure, the technique provides information on spray structure, similar in detail and extent to that derived by photography, but with reduced experimental time. The technique is applied to an investigation of a kerosene spray vaporizing in a hot gas stream.

  17. Effect of Fuel Additives on Spray Performance of Alternative Jet Fuels

    NASA Astrophysics Data System (ADS)

    Kannaiyan, Kumaran; Sadr, Reza

    2015-11-01

    Role of alternative fuels on reducing the combustion pollutants is gaining momentum in both land and air transport. Recent studies have shown that addition of nanoscale metal particles as fuel additives to liquid fuels have a positive effect not only on their combustion performance but also in reducing the pollutant formation. However, most of those studies are still in the early stages of investigation with the addition of nanoparticles at low weight percentages. Such an addition can affect the hydrodynamic and thermo-physical properties of the fuel. In this study, the near nozzle spray performance of gas-to-liquid jet fuel with and without the addition of alumina nanoparticles are investigated at macro- and microscopic levels using optical diagnostic techniques. At macroscopic level, the addition of nanoparticles is seen to enhance the sheet breakup process when compared to that of the base fuel. Furthermore, the microscopic spray characteristics such as droplet size and velocity are also found to be affected. Although the addition of nanoscale metal particles at low weight percentages does not affect the bulk fluid properties, the atomization process is found to be affected in the near nozzle region. Funded by Qatar National Research Fund.

  18. Modeling evaporation from spent nuclear fuel storage pools: A diffusion approach

    NASA Astrophysics Data System (ADS)

    Hugo, Bruce Robert

    Accurate prediction of evaporative losses from light water reactor nuclear power plant (NPP) spent fuel storage pools (SFPs) is important for activities ranging from sizing of water makeup systems during NPP design to predicting the time available to supply emergency makeup water following severe accidents. Existing correlations for predicting evaporation from water surfaces are only optimized for conditions typical of swimming pools. This new approach modeling evaporation as a diffusion process has yielded an evaporation rate model that provided a better fit of published high temperature evaporation data and measurements from two SFPs than other published evaporation correlations. Insights from treating evaporation as a diffusion process include correcting for the effects of air flow and solutes on evaporation rate. An accurate modeling of the effects of air flow on evaporation rate is required to explain the observed temperature data from the Fukushima Daiichi Unit 4 SFP during the 2011 loss of cooling event; the diffusion model of evaporation provides a significantly better fit to this data than existing evaporation models.

  19. Characterization of coal-water slurry fuel sprays from diesel engine injectors

    SciTech Connect

    Caton, J.A.; Kihm, K.D.

    1993-06-01

    Experiments were conducted to characterize coal-water slurry fuel sprays from diesel engine injectors. Since the combustion event is a strong function of the fuel spray, full characterization of the spray is a necessity for successful engine design and for modeling of the combustion process. Two experimental facilities were used at TAMU to study the injection of coal slurry fuels. The first experimental facility incorporates General Electric locomotive engine components (injection pump, fuel line, and nozzle) and a specially designed diaphragm to separate the abrasive coal slurry fuel from the moving parts of the pump. The second experimental facility is based on an accumulator injector from General Electric. Instrumentation includes instantaneous needle lift and fuel line pressure. A pressurized visualization chamber was used to provide a spray environment which simulated the engine gas density and permitted the use of spray diagnostic techniques. The study was divided into two phases: (1) overall characterization of the spray, and (2) detailed droplet size and size distribution characterization. In addition to this overall characterization of the spray, the second phase of this study characterized the details of the atomization quality.

  20. Effect of Water Spray Evaporative Cooling at the Inlet of Regeneration Air Stream on the Performance of an Adsorption Desiccant Cooling Process

    NASA Astrophysics Data System (ADS)

    Ando, Kosuke; Kodama, Akio; Hirose, Tsutomu; Goto, Motonobu; Okano, Hiroshi

    This paper shows an influence of evaporative cooler at the inlet of regeneration air stream of an adsorptive desiccant cooling process on the cooling/dehumidifying performance. This evaporative cooling was expected to cause humidity increase in regeneration air reducing the dehumidifying performance of the honeycomb absorber, while the evaporative cooling plays an important role to produce a lower temperature in supply air. Two different airs to be used for the regeneration of the desiccant wheel were considered. One was fresh outside air (OA mode) and the other was air ventilated from the room (RA mode). Experimental results showed that the amount of dehumidified water obtained at the process without water spray evaporative cooler was actually larger than that of process with water spray evaporative cooler. This behavior was mainly due to increase of humidity or relative humidity in the regeneration air as expected. However, temperature of supply air produced by the process with the evaporator was rather lower than that of the other because of the cooled return air, resulting higher CE value. Regarding the operating mode, the evaporative cooler at the OA-mode was no longer useful at higher ambient humidity because of the difficulty of the evaporation of the water in such high humidity. It was also found that its dehumidifying performance was remarkably decreased at higher ambient humidity and lower regeneration temperature since the effective adsorption capacity at the resulting high relative humidity of the regeneration air decreased.

  1. Mixing of an Airblast-atomized Fuel Spray Injected into a Crossflow of Air

    NASA Technical Reports Server (NTRS)

    Leong, May Y.; McDonell, Vincent G.; Samuelsen, G. Scott

    2000-01-01

    The injection of a spray of fuel droplets into a crossflow of air provides a means of rapidly mixing liquid fuel and air for combustion applications. Injecting the liquid as a spray reduces the mixing length needed to accommodate liquid breakup, while the transverse injection of the spray into the air stream takes advantage of the dynamic mixing induced by the jet-crossflow interaction. The structure of the spray, formed from a model plain-jet airblast atomizer, is investigated in order to determine and understand the factors leading to its dispersion. To attain this goal, the problem is divided into the following tasks which involve: (1) developing planar imaging techniques that visualize fuel and air distributions in the spray, (2) characterizing the airblast spray without a crossflow, and (3) characterizing the airblast spray upon injection into a crossflow. Geometric and operating conditions are varied in order to affect the atomization, penetration, and dispersion of the spray into the crossflow. The airblast spray is first characterized, using imaging techniques, as it issues into a quiescent environment. The spray breakup modes are classified in a liquid Reynolds number versus airblast Weber number regime chart. This work focuses on sprays formed by the "prompt" atomization mode, which induces a well-atomized and well-dispersed spray, and which also produces a two-lobed liquid distribution corresponding to the atomizing air passageways in the injector. The characterization of the spray jet injected into the crossflow reveals the different processes that control its dispersion. Correlations that describe the inner and outer boundaries of the spray jet are developed, using the definition of a two-phase momentum-flux ratio. Cross-sections of the liquid spray depict elliptically-shaped distributions, with the exception of the finely-atomized sprays which show kidney-shaped distributions reminiscent of those obtained in gaseous jet in crossflow systems. A droplet

  2. Diffusion Of Mass In Evaporating Multicomponent Drops

    NASA Technical Reports Server (NTRS)

    Bellan, Josette; Harstad, Kenneth G.

    1992-01-01

    Report summarizes study of diffusion of mass and related phenomena occurring in evaporation of dense and dilute clusters of drops of multicomponent liquids intended to represent fuels as oil, kerosene, and gasoline. Cluster represented by simplified mathematical model, including global conservation equations for entire cluster and conditions on boundary between cluster and ambient gas. Differential equations of model integrated numerically. One of series of reports by same authors discussing evaporation and combustion of sprayed liquid fuels.

  3. Analytical and mechanical testing of high velocity oxy-fuel thermal sprayed and plasma sprayed calcium phosphate coatings.

    PubMed

    Haman, J D; Chittur, K K; Crawmer, D E; Lucas, L C

    1999-01-01

    Plasma spraying (PS) is the most frequently used coating technique for implants; however, in other industries a cheaper, more efficient process, high-velocity oxy-fuel thermal spraying (HVOF), is in use. This process provides higher purity, denser, more adherent coatings than plasma spraying. The primary objective of this work was to determine if the use of HVOF could improve the mechanical properties of calcium phosphate coatings. Previous studies have shown that HVOF calcium phosphate coatings are more crystalline than plasma sprayed coatings. In addition, because the coatings are exposed to more complex loading profiles in vivo than standard ASTM tensile tests provide, a secondary objective of this study was to determine the applicability of four-point bend testing for these coatings. Coatings produced by HVOF and PS were analyzed by profilometry, diffuse reflectance Fourier transform infrared spectroscopy, X-ray diffraction, four-point bend, and ASTM C633 tensile testing. HVOF coatings were found to have lower amorphous calcium phosphate content, higher roughness values, and lower ASTM C633 bond strengths than PS coatings; however, both coatings had similar crystal unit cell sizes, phases present (including hydroxyapatite, beta-tricalcium phosphate, and tetracalcium phosphate), and four-point bend bond strengths. Thus, the chemical, structural, and mechanical results of this study, in general, indicate that the use of HVOF to produce calcium phosphate coatings is equivalent to those produced by plasma spraying. PMID:10556851

  4. Modelling of automotive fuel droplet heating and evaporation: mathematical tools and approximations

    NASA Astrophysics Data System (ADS)

    Sazhin, Sergei S.; Qubeissi, Mansour Al

    2016-06-01

    New mathematical tools and approximations developed for the analysis of automotive fuel droplet heating and evaporation are summarised. The approach to modelling biodiesel fuel droplets is based on the application of the Discrete Component Model (DCM), while the approach to modelling Diesel fuel droplets is based on the application of the recently developed multi-dimensional quasi-discrete model. In both cases, the models are applied in combination with the Effective Thermal Conductivity/Effective Diffusivity model and the implementation in the numerical code of the analytical solutions to heat transfer and species diffusion equations inside droplets. It is shown that the approximation of biodiesel fuel by a single component leads to under-prediction of droplet evaporation time by up to 13% which can be acceptable as a crude approximation in some applications. The composition of Diesel fuel was simplified and reduced to only 98 components. The approximation of 98 components of Diesel fuel with 15 quasi-components/components leads to under-prediction of droplet evaporation time by about 3% which is acceptable in most engineering applications. At the same time, the approximation of Diesel fuel by a single component and 20 alkane components leads to a decrease in the evaporation time by about 19%, compared with the case of approximation of Diesel fuel with 98 components. The approximation of Diesel fuel with a single alkane quasi-component (C14.763H31.526) leads to under-prediction of the evaporation time by about 35% which is not acceptable even for qualitative analysis of the process. In the case when n-dodecane is chosen as the single alkane component, the above-mentioned under-prediction increases to about 44%.

  5. Exhaust and evaporative emissions from motorcycles fueled with ethanol gasoline blends.

    PubMed

    Li, Lan; Ge, Yunshan; Wang, Mingda; Peng, Zihang; Song, Yanan; Zhang, Liwei; Yuan, Wanli

    2015-01-01

    The emission characteristics of motorcycles using gasoline and E10 (90% gasoline and 10% ethanol by volume) were investigated in this article. Exhaust and evaporative emissions of three motorcycles were investigated on the chassis dynamometer over the Urban Driving Cycle (UDC) and in the Sealed Housing for Evaporative Determination (SHED) including regulated and unregulated emissions. The regulated emissions were detected by an exhaust gas analyzer directly. The unregulated emissions including carbonyls and volatile organic compounds (VOCs) were sampled through battery-operated air pumps using tubes coated with 2,4-dinitrophenylhydrazine (DNPH) and Tenax TA, respectively. The experimental results showed that the emission factors of total hydrocarbons (THC) and carbon monoxide (CO) from E10 fueling motorcycles decreased by 26%-45% and 63%-73%, while the emission factor of NOx increased by 36%-54% compared with those from gasoline fueling motorcycles. For unregulated emissions, the emission amount of VOCs from motorcycles fueled with E10 decreased by 18%-31% while total carbonyls were 2.6-4.5 times higher than those for gasoline. For evaporative emissions of THC and VOCs, for gasoline or E10, the diurnal breathing loss (DBL) was higher than hot soak loss (HSL). Using E10 as a fuel does not make much difference in the amount of evaporative THC, while resulted in a slightly growth of 14%-17% for evaporative BETX (benzene, toluene, ethylbenzene, xylene). PMID:25302450

  6. Experimental investigation of fuel evaporation in the vaporizing elements of combustion chambers

    NASA Technical Reports Server (NTRS)

    Vezhba, I.

    1979-01-01

    A description is given of the experimental apparatus and the methods used in the investigation of the degree of fuel (kerosene) evaporation in two types of vaporizing elements in combustion chambers. The results are presented as dependences of the degree of fuel evaporation on the factors which characterize the functioning of the vaporizing elements: the air surplus coefficient, the velocity of flow and temperature of the air at the entrance to the vaporizing element and the temperature of the wall of the vaporizing element.

  7. The Effect of Nozzle Design and Operating Conditions on the Atomization and Distribution of Fuel Sprays

    NASA Technical Reports Server (NTRS)

    Lee, Dana W

    1933-01-01

    The atomization and distribution characteristics of fuel sprays from automatic injection valves for compression-ignition engines were determined by catching the fuel drops on smoked-glass plates, and then measuring and counting the impressions made in the lampblack. The experiments were made in an air-tight chamber in which the air density was raised to values corresponding to engine conditions.

  8. Numerical study of solid fuel evaporation and auto-ignition in a dump combustor

    NASA Astrophysics Data System (ADS)

    Tahsini, A. M.; Farshchi, M.

    2010-10-01

    Evaporation of polymeric solid fuels in backward facing step geometry subject to an inlet oxidizer flow at elevated temperatures is considered and convective heating of the fuel surface by the hot oxidizing inlet flow and subsequent mixing of the evaporated fuel with the oxidizer flow and its combustion is numerically studied. The objective of this work is to gain insight into the auto-ignition of the fuel and its controlling parameters in this configuration. The system of governing equations is solved with a finite volume approach using a structured grid in which the AUSM + scheme is used to calculate the gas phase convective fluxes. The flowfield is turbulent and the Spalart-Allmaras turbulence model is used in these simulations. Special attention is paid to the coupling of gas and solid phase to study the ignition process. Distinct intervals in ignition delay time are studied and evaporation time, mixing time, and reaction time are individually estimated. We have demonstrated that for inlet oxidizer streams with high initial oxygen concentration levels and high enough inlet temperatures a diffusion-controlled ignition mechanism controls the ignition time delay independent of the inlet velocity. This ignition time delay is directly related to the solid fuel evaporation time delay.

  9. Experimental analysis and semicontinuous simulation of low-temperature droplet evaporation of multicomponent fuels

    NASA Astrophysics Data System (ADS)

    Lehmann, S.; Lorenz, S.; Rivard, E.; Brüggemann, D.

    2015-01-01

    Low-pollutant and efficient combustion not only in internal combustion engines requires a balanced gaseous mixture of fuel and oxidizer. As fuels may contain several hundred different chemical species with different physicochemical properties as well as defined amounts of biogenic additives, e.g., ethanol, a thorough understanding of liquid fuel droplet evaporation processes is necessary to allow further engine optimization. We have studied the evaporation of fuel droplets at low ambient temperature. A non-uniform temperature distribution inside the droplet was already considered by including a finite thermal conductivity in a one-dimensional radial evaporation model (Rivard and Brüggemann in Chem Eng Sci 65(18):5137-5145, 2010). For a detailed analysis of droplet evaporation, two non-laser-based experimental setups have been developed. They allow a fast and relatively simple but yet precise measurement of diameter decrease and composition change. The first method is based on collecting droplets in a diameter range from 70 to 150 µm by a high-precision scale. A simultaneous evaluation of mass increase is employed for an accurate average diameter value determination. Subsequently, a gas chromatographic analysis of the collected droplets was conducted. In the second experiment, evaporation of even smaller droplets was optically analyzed by a high-speed shadowgraphy/schlieren microscope setup. A detailed analysis of evaporating E85 (ethanol/gasoline in a mass ratio of 85 %/15 %) and surrogate fuel droplets over a wide range of initial droplet diameters and ambient temperatures was conducted. The comparison of experimental and numerical results shows the applicability of the developed model over a large range of diameters and temperatures.

  10. Coal-water slurry spray characteristics of an electronically-controlled accumulator fuel injection system

    SciTech Connect

    Caton, J.A.; Payne, S.E.; Terracina, D.P.; Kihm, K.D.

    1993-12-31

    Experiments have been complete to characterize coal-water slurry sprays from a electronically-controlled accumulator fuel injection system of diesel engine. The sprays were injected into a pressurized chamber equipped with windows. High speed movies, fuel pressures and needle lifts were obtained as a function of time, orifice diameter, coal loading, gas density in the chamber, and accumulator fuel pressure. For the base conditions 50% (by mass) coal loading, 0.4 mm diameter nozzle hole, coal-water slurry pressure of 82 MPa (12,000 psi), and a chamber density of 25 kg/m{sup 3}, the break-up time was 0. 30 ms. An empirical correlation for both spray tip penetration and initial jet velocity was developed. For the conditions of this study, the spray tip penetration and initial jet velocity were 15% greater for coal-water slurry than for diesel fuel or water. Cone angles of the sprays were dependent on the operating conditions and fluid, as well as the time and locations of the measurement. The time-averaged cone angle for the base case conditions was 13.6{degree}. Results of this study and the correlation are specific to the tested coal-water slurry and are not general for other coal-water slurry fuels.

  11. Penetration and Duration of Fuel Sprays from a Pump Injection System

    NASA Technical Reports Server (NTRS)

    Rothrock, A M; Marsh, E T

    1934-01-01

    High-speed motion pictures were taken of individual fuel sprays from a pump injection system. The changes in the spray-tip penetration with changes in the pump speed, injection-valve opening and closing pressures, discharge-orifice area, injection-tube length and diameter, and pump throttle setting were measured. The pump was used with and without a check valve. The results show that the penetration of the spray tip can be controlled by the dimensions of the injection tube, the area of the discharge orifice, and the injection-valve opening and closing pressures.

  12. Detailed investigation of a vaporising fuel spray. Part 1: Experimental investigation of time averaged spray

    NASA Technical Reports Server (NTRS)

    Yule, A. J.; Seng, C. A.; Boulderstone, R.; Ungut, A.; Felton, P. G.; Chigier, N. A.

    1980-01-01

    A laser tomographic light scattering technique provides rapid and accurate high resolution measurements of droplet sizes, concentrations, and vaporization. Measurements using a computer interfaced thermocouple are presented and it is found that the potential exists for separating gas and liquid temperature measurements and diagnosing local spray density by in situ analysis of the response characteristics of the thermocouple. The thermocouple technique provides a convenient means for measuring mean gas velocity in both hot and cold two phase flows. The experimental spray is axisymmetric and has carefully controlled initial and boundary conditions. The flow is designed to give relatively insignificant transfer of momentum and mass from spray to air flow. The effects of (1) size-dependent droplet dispersion by the turbulence, (2) the initial spatial segregation of droplet sizes during atomization, and (3) the interaction between droplets and coherent large eddies are diagnosed.

  13. Composition changes in liquid oxygen as a result of evaporation and relation to fuel cell operation

    NASA Technical Reports Server (NTRS)

    Easter, R. W.

    1973-01-01

    An expression is presented which may be used to estimate changes in composition as a consequence of evaporation during the storage of liquid oxygen. The sensitivity of fuel-cell systems to such changes is discussed, and sample calculations are presented.

  14. Experimental investigation of the liquid fuel evaporation in a premix duct for lean premixed and prevaporized combustion

    SciTech Connect

    Brandt, M.; Gugel, K.O.; Hassa, C.

    1997-10-01

    Liquid fuel evaporation was investigated in a premix duct, operating at conditions expected for lean premixed and prevaporized combustion. Results from a flat prefilming airblast atomizer are presented. Kerosine Jet A was used in all experiments. Air pressure, air temperature, and liquid fuel flow rate were varied separately; their relative influences on atomization, evaporation, and fuel dispersion are discussed. The results show that at pressures up to 15 bars and temperatures up to 850 K, nearly complete evaporation of the fuel was achieved, without autoignition of the fuel. For the configuration tested, the fuel distributions of the liquid and evaporated fuel show very little difference in their dispersion characteristics and were not much affected by a variation of the operating conditions.

  15. Effect of aviation fuel type and fuel injection conditions on the spray characteristics of pressure swirl and hybrid air blast fuel injectors

    NASA Astrophysics Data System (ADS)

    Feddema, Rick

    Feddema, Rick T. M.S.M.E., Purdue University, December 2013. Effect of Aviation Fuel Type and Fuel Injection Conditions on the Spray Characteristics of Pressure Swirl and Hybrid Air Blast Fuel Injectors. Major Professor: Dr. Paul E. Sojka, School of Mechanical Engineering Spray performance of pressure swirl and hybrid air blast fuel injectors are central to combustion stability, combustor heat management, and pollutant formation in aviation gas turbine engines. Next generation aviation gas turbine engines will optimize spray atomization characteristics of the fuel injector in order to achieve engine efficiency and emissions requirements. Fuel injector spray atomization performance is affected by the type of fuel injector, fuel liquid properties, fuel injection pressure, fuel injection temperature, and ambient pressure. Performance of pressure swirl atomizer and hybrid air blast nozzle type fuel injectors are compared in this study. Aviation jet fuels, JP-8, Jet A, JP-5, and JP-10 and their effect on fuel injector performance is investigated. Fuel injector set conditions involving fuel injector pressure, fuel temperature and ambient pressure are varied in order to compare each fuel type. One objective of this thesis is to contribute spray patternation measurements to the body of existing drop size data in the literature. Fuel droplet size tends to increase with decreasing fuel injection pressure, decreasing fuel injection temperature and increasing ambient injection pressure. The differences between fuel types at particular set conditions occur due to differences in liquid properties between fuels. Liquid viscosity and surface tension are identified to be fuel-specific properties that affect the drop size of the fuel. An open aspect of current research that this paper addresses is how much the type of aviation jet fuel affects spray atomization characteristics. Conventional aviation fuel specifications are becoming more important with new interest in alternative

  16. Use of Oriented Spray Nozzles to Set the Vapor-Air Flow in Rotary Motion in the Superspray Space of the Evaporative Chimney-Type Tower

    NASA Astrophysics Data System (ADS)

    Dobrego, K. V.; Davydenko, V. F.; Koznacheev, I. A.

    2016-01-01

    The present paper considers the problem of upgrading the thermal efficiency of chimney-type evaporative cooling towers due to the rotary motion of the vapor-air flow in the superspray space. To set the vapor-air flow in rotary motion, we propose to use the momentum of the sprayed water. It has been shown that the existing parameters of spray nozzles permit setting up to 30% of the water flow momentum in translatory motion, which is enough for changing considerably the aerodynamics of the vapor-air flow in the superspray space and improving the operation of the cooling tower. The optimal angle of axial inclination of the spray cone has been estimated. Recommendations are given and problems have been posed for engineering realization of the proposed technologies in a chimney-type cooling tower.

  17. Numerical Investigation of the Flow Dynamics and Evaporative Cooling of Water Droplets Impinging onto Heated Surfaces: An Effective Approach To Identify Spray Cooling Mechanisms.

    PubMed

    Chen, Jian-Nan; Zhang, Zhen; Xu, Rui-Na; Ouyang, Xiao-Long; Jiang, Pei-Xue

    2016-09-13

    Numerical investigations of the dynamics and evaporative cooling of water droplets impinging onto heated surfaces can be used to identify spray cooling mechanisms. Droplet impingement dynamics and evaporation are simulated using the presented numerical model. Volume-of-fluid method is used in the model to track the free surface. The contact line dynamics was predicted from a dynamic contact angle model with the evaporation rate predicted by a kinetic theory model. A species transport equation was solved in the gas phase to describe the vapor convection and diffusion. The numerical model was validated by experimental data. The physical effects including the contact angle hysteresis and the thermocapillary effect are analyzed to offer guidance for future numerical models of droplet impingement cooling. The effects of various parameters including surface wettability, surface temperature, droplet velocity, droplet size, and droplet temperature were numerically studied from the standpoint of spray cooling. The numerical simulations offer profound analysis and deep insight into the spray cooling heat transfer mechanisms. PMID:27531256

  18. Formation of oxides of nitrogen in monodisperse spray combustion of hydrocarbon fuels

    NASA Technical Reports Server (NTRS)

    Nizami, A. A.; Singh, S.; Cernansky, N. P.

    1982-01-01

    Experimental results of exit plane NO/NO(x) emissions from atmospheric monodisperse fuel spray combustion are presented. Six different hydrocarbon fuels were studied: isopropanol, n-propanol, n-octane, iso-octane, n-heptane and methanol. The results indicate an optimum droplet size for minimizing NO/NO(x) production for all of the test fuels. At the optimum droplet diameter, reductions in NO/NO(x) relative to the NO(x) occurred at droplet diameters of 55 and 48 microns respectively, as compared to a 50-micron droplet size for isopropanol. The occurrence of the minimum NO(x) point at different droplet diameters for the different fuels appears to be governed by the extent of prevaporization of the fuel in the spray, and is consistent with theoretical calculations based on each fuel's physical properties. Estimates are also given for the behavior of heavy fuels and of polydisperse fuel sprays in shifting the minimum NO(x) point compared to a monodisperse situation.

  19. Diesel engine emissions and combustion predictions using advanced mixing models applicable to fuel sprays

    NASA Astrophysics Data System (ADS)

    Abani, Neerav; Reitz, Rolf D.

    2010-09-01

    An advanced mixing model was applied to study engine emissions and combustion with different injection strategies ranging from multiple injections, early injection and grouped-hole nozzle injection in light and heavy duty diesel engines. The model was implemented in the KIVA-CHEMKIN engine combustion code and simulations were conducted at different mesh resolutions. The model was compared with the standard KIVA spray model that uses the Lagrangian-Drop and Eulerian-Fluid (LDEF) approach, and a Gas Jet spray model that improves predictions of liquid sprays. A Vapor Particle Method (VPM) is introduced that accounts for sub-grid scale mixing of fuel vapor and more accurately and predicts the mixing of fuel-vapor over a range of mesh resolutions. The fuel vapor is transported as particles until a certain distance from nozzle is reached where the local jet half-width is adequately resolved by the local mesh scale. Within this distance the vapor particle is transported while releasing fuel vapor locally, as determined by a weighting factor. The VPM model more accurately predicts fuel-vapor penetrations for early cycle injections and flame lift-off lengths for late cycle injections. Engine combustion computations show that as compared to the standard KIVA and Gas Jet spray models, the VPM spray model improves predictions of in-cylinder pressure, heat released rate and engine emissions of NOx, CO and soot with coarse mesh resolutions. The VPM spray model is thus a good tool for efficiently investigating diesel engine combustion with practical mesh resolutions, thereby saving computer time.

  20. Fuel Spray and Flame Formation in a Compression-Ignition Engine Employing Air Flow

    NASA Technical Reports Server (NTRS)

    Rothrock, A M; Waldron, C D

    1937-01-01

    The effects of air flow on fuel spray and flame formation in a high-speed compression-ignition engine have been investigated by means of the NACA combustion apparatus. The process was studied by examining high-speed motion pictures taken at the rate of 2,200 frames a second. The combustion chamber was of the flat-disk type used in previous experiments with this apparatus. The air flow was produced by a rectangular displacer mounted on top of the engine piston. Three fuel-injection nozzles were tested: a 0.020-inch single-orifice nozzle, a 6-orifice nozzle, and a slit nozzle. The air velocity within the combustion chamber was estimated to reach a value of 425 feet a second. The results show that in no case was the form of the fuel spray completely destroyed by the air jet although in some cases the direction of the spray was changed and the spray envelope was carried away by the moving air. The distribution of the fuel in the combustion chamber of a compression-ignition engine can be regulated to some extent by the design of the combustion chamber, by the design of the fuel-injection nozzle, and by the use of air flow.

  1. Ceramic plasma-sprayed coating of melting crucibles for casting metal fuel slugs

    SciTech Connect

    K.H. Kim; C.T. Lee; C.B. Lee; R.S. Fielding; J.R. Kennedy

    2013-10-01

    Thermal cycling and melt reaction studies of ceramic coatings plasma-sprayed on Nb substrates were carried out to evaluate the performance of barrier coatings for metallic fuel casting applications. Thermal cycling tests of the ceramic plasma-sprayed coatings to 1450 degrees C showed that HfN, TiC, ZrC, and Y2O3 coating had good cycling characteristics with few interconnected cracks even after 20 cycles. Interaction studies by 1550 degrees C melt dipping tests of the plasma-sprayed coatings also indicated that HfN and Y2O3 do not form significant reaction layer between U–20 wt.% Zr melt and the coating layer. Plasma-sprayed Y2O3 coating exhibited the most promising characteristics among HfN, TiC, ZrC, and Y2O3 coating.

  2. The Gas Dynamics of High-Velocity Oxy-Fuel Thermal Sprays

    NASA Astrophysics Data System (ADS)

    Hackett, Charles Marcou

    An experimental study of the gas dynamics of the High-Velocity Oxy-Fuel (HVOF) thermal spray process has been performed. With this process, a hot, combustion-driven, supersonic jet is used to propel particles onto a surface, thus forming metal coatings that provide wear, temperature, and corrosion resistance. The fundamental physics of the spray process were studied and several key areas of interest were identified for in-depth study. Optical diagnostic techniques, including microsecond -exposure schlieren and shadowgraph imaging, were used to visualize the hot supersonic jet produced during the spray process. Energetic turbulent mixing of the jet with the surrounding atmosphere was observed. Measurements of oxide levels in aluminum and mild steel coatings sprayed for a range of conditions indicated that the turbulent mixing influences coating oxidation. However, experiments conducted with a low-speed coaxial shroud of inert gas demonstrated that coating oxide formation can be effectively controlled during the spray process. A simple numerical model was developed to predict the behavior of a spray particle in the HVOF jet. The results of computations indicated that independent control of spray particle velocity and temperature was possible through systematic variations in combustion chamber pressure and particle injection location within the nozzle. This hypothesis was confirmed through a series of experiments in which stainless steel particle velocity and temperature were measured using trace velocimetry and two-color radiative pyrometry, respectively. Combustion chamber pressure had a strong effect on particle velocity. Injection location was used to control the residence time of a particle within the flow, thus allowing manipulation of particle temperature without a measurable effect on velocity. Thus, the results of these experiments revealed that the gas dynamics--the behavior of the compressible gas flow--of the HVOF spray process strongly influenced spray

  3. Investigation of spray dispersion and particulate formation in diesel fuel flames

    NASA Technical Reports Server (NTRS)

    Back, L. H.; Bankston, C. P.; Kwack, E. Y.; Bellan, J.; Harstad, K.

    1988-01-01

    An experimental study of electrostatical atomized and dispersed diesel fuel jets was conducted at various back pressures to 40 atm. A new electrostatic injection technique was utilized to generate continuous, stable fuel sprays at charge densities of 1.5 to 2.0 C/m3 of fluid at one atm, and about 1.0 C/m3 at 40 atm. Flowrates were varied from 0.5 to 2.5 ml/s and electric potentials to -18 kV. Visual observations showed that significant enhanced dispersion of charged fuel jets occurred at high back pressures compared to aerodynamic breakup and dispersion. The average drop size was about the same as the spray triode orifice diameter, and was between the Kelly theory and the Rayleigh limit. The ignition tests, done only at one atm, indicated stable combustion of the electrostatically dispersed fuel jets.

  4. A model of the evaporation of binary-fuel clusters of drops

    NASA Technical Reports Server (NTRS)

    Harstad, K.; Bellan, J.

    1991-01-01

    A formulation has been developed to describe the evaporation of dense or dilute clusters of binary-fuel drops. The binary fuel is assumed to be made of a solute and a solvent whose volatility is much lower than that of the solute. Convective flow effects, inducing a circulatory motion inside the drops, are taken into account, as well as turbulence external to the cluster volume. Results obtained with this model show that, similar to the conclusions for single isolated drops, the evaporation of the volatile is controlled by liquid mass diffusion when the cluster is dilute. In contrast, when the cluster is dense, the evaporation of the volatile is controlled by surface layer stripping, that is, by the regression rate of the drop, which is in fact controlled by the evaporation rate of the solvent. These conclusions are in agreement with existing experimental observations. Parametric studies show that these conclusions remain valid with changes in ambient temperature, initial slip velocity between drops and gas, initial drop size, initial cluster size, initial liquid mass fraction of the solute, and various combinations of solvent and solute. The implications of these results for computationally intensive combustor calculations are discussed.

  5. Combustion characteristics in the transition region of liquid fuel sprays

    NASA Technical Reports Server (NTRS)

    Cernansky, N. P.; Namer, I.; Tidona, R. J.

    1984-01-01

    A number of important effects were observed in the droplet size transition region in spray combustion systems. In this region, where the mechanism of flame propagation is transformed from diffusive to premixed dominated combustion, the following effects have been observed: (1) maxima in burning velocity; (2) extension of flammability limits; (3) minima in ignition energy; and (4) minima in NO(x) formation. Unfortunately, because of differences in experimental facilities and limitations in the ranges of experimental data, a unified description of these transition region effects is not available at this time. Consequently, a fundamental experimental investigation was initiated to study the effect of droplet size, size distribution, and operating parameters on these transition region phenomena in a single well controlled spray combustion facility.

  6. Impact of alternative fuel rheology on spraying process of small pressure-swirl atomizer

    NASA Astrophysics Data System (ADS)

    Malý, Milan; Janáčková, Lada; Jedelský, Jan; Jícha, Miroslav

    2016-06-01

    A systematic investigation was made to analyse the atomizing performance of a small pressure-swirl atomizer with different crude-oil based fuels and water. The atomizer performance is characterized in terms of discharge coefficient, droplet Sauter mean diameter and nozzle efficiency. Phase-Doppler anemometry was used to measure droplets sizes and velocities and to determine the mean structure of the developed spray. A strong dependence of liquid viscosity on the mass flow rate through the atomizer as well as on the spray quality was found and discussed in comparison with relevant literature.

  7. Penetration and Duration of Fuel Sprays from a Pump Injection System

    NASA Technical Reports Server (NTRS)

    Rothrock, A M; Marsh, E T

    1931-01-01

    High-speed motion pictures were taken of individual fuel sprays from a pump injection system. The changes in the spray-tip penetration with changes in the pump speed, injection-valve opening and closing pressures, discharge-orifice area, injection-tube length and diameter, and pump throttle setting were measured. In addition, the effects of the variables on the time lag and duration of injection can be controlled by the dimensions of the injection tube, the area of the discharge orifice, and the injection-valve opening and closing pressures.

  8. A computational study of droplet evaporation with fuel vapor jet ejection induced by localized heat sources

    NASA Astrophysics Data System (ADS)

    Sim, Jaeheon; Im, Hong G.; Chung, Suk Ho

    2015-05-01

    Droplet evaporation by a localized heat source under microgravity conditions was numerically investigated in an attempt to understand the mechanism of the fuel vapor jet ejection, which was observed experimentally during the flame spread through a droplet array. An Eulerian-Lagrangian method was implemented with a temperature-dependent surface tension model and a local phase change model in order to effectively capture the interfacial dynamics between liquid droplet and surrounding air. It was found that the surface tension gradient caused by the temperature variation within the droplet creates a thermo-capillary effect, known as the Marangoni effect, creating an internal flow circulation and outer shear flow which drives the fuel vapor into a tail jet. A parametric study demonstrated that the Marangoni effect is indeed significant at realistic droplet combustion conditions, resulting in a higher evaporation constant. A modified Marangoni number was derived in order to represent the surface force characteristics. The results at different pressure conditions indicated that the nonmonotonic response of the evaporation rate to pressure may also be attributed to the Marangoni effect.

  9. Solid oxide fuel cell processing using plasma arc spray deposition techniques

    SciTech Connect

    Ray, E.R.; Spengler, C.J.; Herman, H.

    1991-07-01

    The Westinghouse Electric Corporation, in conjunction with the Thermal Spray Laboratory of the State University of New York, Stony Brook, investigated the fabrication of a gas-tight interconnect layer on a tubular solid oxide fuel cell with plasma arc spray deposition. The principal objective was to determine the process variables for the plasma spray deposition of an interconnect with adequate electrical conductivity and other desired properties. Plasma arc spray deposition is a process where the coating material in powder form is heated to or above its melting temperature, while being accelerated by a carrier gas stream through a high power electric arc. The molten powder particles are directed at the substrate, and on impact, form a coating consisting of many layers of overlapping, thin, lenticular particles or splats. The variables investigated were gun power, spray distance, powder feed rate, plasma gas flow rates, number of gun passes, powder size distribution, injection angle of powder into the plasma plume, vacuum or atmospheric plasma spraying, and substrate heating. Typically, coatings produced by both systems showed bands of lanthanum rich material and cracking with the coating. Preheating the substrate reduced but did not eliminate internal coating cracking. A uniformly thick, dense, adherent interconnect of the desired chemistry was finally achieved with sufficient gas- tightness to allow fabrication of cells and samples for measurement of physical and electrical properties. A cell was tested successfully at 1000{degree}C for over 1,000 hours demonstrating the mechanical, electrical, and chemical stability of a plasma-arc sprayed interconnect layer.

  10. Solid oxide fuel cell processing using plasma arc spray deposition techniques. Final report

    SciTech Connect

    Ray, E.R.; Spengler, C.J.; Herman, H.

    1991-07-01

    The Westinghouse Electric Corporation, in conjunction with the Thermal Spray Laboratory of the State University of New York, Stony Brook, investigated the fabrication of a gas-tight interconnect layer on a tubular solid oxide fuel cell with plasma arc spray deposition. The principal objective was to determine the process variables for the plasma spray deposition of an interconnect with adequate electrical conductivity and other desired properties. Plasma arc spray deposition is a process where the coating material in powder form is heated to or above its melting temperature, while being accelerated by a carrier gas stream through a high power electric arc. The molten powder particles are directed at the substrate, and on impact, form a coating consisting of many layers of overlapping, thin, lenticular particles or splats. The variables investigated were gun power, spray distance, powder feed rate, plasma gas flow rates, number of gun passes, powder size distribution, injection angle of powder into the plasma plume, vacuum or atmospheric plasma spraying, and substrate heating. Typically, coatings produced by both systems showed bands of lanthanum rich material and cracking with the coating. Preheating the substrate reduced but did not eliminate internal coating cracking. A uniformly thick, dense, adherent interconnect of the desired chemistry was finally achieved with sufficient gas- tightness to allow fabrication of cells and samples for measurement of physical and electrical properties. A cell was tested successfully at 1000{degree}C for over 1,000 hours demonstrating the mechanical, electrical, and chemical stability of a plasma-arc sprayed interconnect layer.

  11. Effect of Operating Parameters on a Dual-Stage High Velocity Oxygen Fuel Thermal Spray System

    NASA Astrophysics Data System (ADS)

    Khan, Mohammed N.; Shamim, Tariq

    2014-08-01

    High velocity oxygen fuel (HVOF) thermal spray systems are being used to apply coatings to prevent surface degradation. The coatings of temperature sensitive materials such as titanium and copper, which have very low melting points, cannot be applied using a single-stage HVOF system. Therefore, a dual-stage HVOF system has been introduced and modeled computationally. The dual-spray system provides an easy control of particle oxidation by introducing a mixing chamber. In addition to the materials being sprayed, the thermal spray coating quality depends to a large extent on flow behavior of reacting gases and the particle dynamics. The present study investigates the influence of various operating parameters on the performance of a dual-stage thermal spray gun. The objective is to develop a predictive understanding of various parameters. The gas flow field and the free jet are modeled by considering the conservation of mass, momentum, and energy with the turbulence and the equilibrium combustion sub models. The particle phase is decoupled from the gas phase due to very low particle volume fractions. The results demonstrate the advantage of a dual-stage system over a single-stage system especially for the deposition of temperature sensitive materials.

  12. Analysis of a High Velocity Oxygen-Fuel (HVOF) thermal spray torch. Part 2, Computational results

    SciTech Connect

    Oberkampf, W.L.; Talpallikar, M.

    1993-12-31

    The fluid dynamics inside and outside a High Velocity Oxygen-Fuel (HVOF) torch are analyzed using computational fluid dynamic (CFD) techniques. The thermal spray device analyzed is similar to a Metco Diamond Jet torch with powder injection. The spray nozzle is axisymmetric with powder injected on the centerline, premixed fuel and oxygen fed from an annulus, and air cooling injected along the interior surface of the aircap choked flow conditions occur at the exit of the aircap and a supersonic, under-expanded jet develops externally. The details of the CFD simulation are given in a companion paper. This paper describes the general gas dynamic features of HVOF spraying and then gives a detailed discussion of the computational predictions of the present analysis. The gas velocity, temperature, pressure and Mach number distributions are presented for various locations inside and outside the torch. Characteristics of the metal spray particle velocity, temperature, Mach number, trajectory, and phase state (solid or liquid) are also presented and discussed. Extensive numerical flow visualization is provided to show flow features such as mixing layers, shock waves, and expansion waves.

  13. Two-Phase PIV: Fuel-Spray Interaction with Surrounding Air

    NASA Astrophysics Data System (ADS)

    Dankers, Stefan; Gotthardt, Mark; Stengler, Thomas; Ohmstede, Gerhard; Hentschel, Werner

    The demand for improvement of combustion-engine processes leads to a great need for detailed experimental information about the complicated processes of injection, breakup and propagation of the fuel jet and the vaporization of the fuel. Thus, in the presented work it was the aim to visualize the air flow that is induced by the injected fuel jet and also to explore the air entrainment into the fuel spray. This was done using two-phase PIV (particle image velocimetry). The fuel jet was illuminated with a Nd:YAG PIV-laser and PIV analysis was done by simply measuring the elastically scattered light of the fuel droplets. For the investigation of the surrounding air propylene-carbonate doped with DCM-dye was dispersed and the droplets were added to the continuous gas flow upstream of the chamber. Scattered and fluorescence signals, respectively, were detected perpendicular to the laser sheet with a CCD camera. To detect the gas flow, the scattered light from the liquid fuel was suppressed by an OG 590 longpass filter glass that transmits the fluorescence signal of the DCM-dye. It was possible to measure both the fuel jet and the gas flow in the presence of the fuel spray and a clear separation of the two phases could be achieved. In both (fuel and air) vector pictures corresponding vortices could be identified near the air/fuel boundary layer. Maximum velocities in the jet are depending on the operation conditions up to 150ms-1 and the gas flow has typically a velocity of 1 to 10ms-1. In the region next to the injector the air was pressed away during the injection. After the end of the injection a strong fast air entrainment flow into this region can be observed that compensates the pressure difference.

  14. Heat Transfer to Fuel Sprays Injected into Heated Gases

    NASA Technical Reports Server (NTRS)

    Selden, Robert F; Spencer, Robert C

    1938-01-01

    This report presents the results of a study made of the influence of several variables on the pressure decrease accompanying injection of a relatively cool liquid into a heated compressed gas. Indirectly, this pressure decrease and the time rate of change of it are indicative of the total heat transferred as well as the rate of heat transfer between the gas and the injected liquid. Air, nitrogen, and carbon dioxide were used as ambient gases; diesel fuel and benzene were the injected liquids. The gas densities and gas-fuel ratios covered approximately the range used in compression-ignition engines. The gas temperatures ranged from 150 degrees c. to 350 degrees c.

  15. Effect of Moderate Air Flow on the Distribution of Fuel Sprays After Injection Cut-0ff

    NASA Technical Reports Server (NTRS)

    Rothrock, A M; Spencer, R C

    1935-01-01

    High-speed motion pictures were taken of fuel sprays with the NACA spray-photographic apparatus to study the distribution of the liquid fuel from the instant of injection cut-off until about 0.05 second later. The fuel was injected into a glass-walled chamber in which the air density was varied from 1 to 13 times atmospheric air density (0.0765 to 0.99 pound per cubic foot) and in which the air was at room temperature. The air in the chamber was set in motion by means of a fan, and was directed counter to the spray at velocities up to 27 feet per second. The injection pressure was varied from 2,000 to 6,000 pounds per square inch. A 0.20-inch single-orifice nozzle, an 0.008-inch single-orifice nozzle, a multiorifice nozzle, and an impinging-jets nozzle were used. The best distribution was obtained by the use of air and a high-dispersion nozzle.

  16. Analysis of a High Velocity Oxygen-Fuel (HVOF) thermal spray torch. Part 1, Numerical formulation

    SciTech Connect

    Oberkampf, W.L.; Talpallikar, M.

    1994-01-01

    The fluid and particle dynamics of a High Velocity Oxygen-Fuel (HVOF) torch are analyzed using computational fluid dynamic (CFD) techniques. The thermal spray device analyzed is similar to a Metco Diamond Jet torch with powder injection. The spray nozzle is axisymmetric with powder injection on the centerline, premixed fuel and oxygen fed from an annulus, and air cooling injected along the interior surface of the aircap. Choked flow conditions occur at the exit of the aircap and a supersonic, under-expanded jet develops externally. The CFD simulation assumes three injection streams (solid metal particles with argon as a carrier gas, premixed oxygen/fuel, and air) inside the aircap and solves the combusting two-phase flow until the external spray stream decays to sonic conditions. The numerical formulation solves the mass, momentum, and energy transfer for both the gas and particle phase and strongly couples each phase. The combustion process is modeled using approximate equilibrium chemistry with dissociation of the gas with a total of nine species. Melting and re-solidification of the metal panicles is modeled as a lumped-mass system. Turbulent flow is modeled by a two equation k-{epsilon} turbulence model, including compressibility effects on turbulent dissipation. A time iterative, implicit, finite volume numerical method is used to solve the partial differential equations. A companion paper [10] presents the results of the numerical simulation and gives a detailed discussion of the gas and panicle dynamics.

  17. Fuel retention in impurity seeded discharges in JET after Be evaporation

    NASA Astrophysics Data System (ADS)

    Brezinsek, S.; Loarer, T.; Krieger, K.; Jachmich, S.; Tsalas, M.; Coffey, I.; Esser, H. G.; Eich, T.; Fundamenski, W.; Giroud, C.; Grünhagen, S.; Huber, A.; Kruezi, U.; Knipe, S.; Maddison, G. P.; McCormick, K.; Meigs, A. G.; Morgan, Ph.; Philipps, V.; Sergienko, G.; Stagg, R.; Stamp, M. F.; Tabares, F. L.; EFDA Contributors, JET

    2011-07-01

    Preparatory experiments for the ITER-Like Wall in JET were carried out to simulate the massive Be first wall by a thin Be layer, induced by evaporation of about 2.0 g Be, and to study its impact on fuel retention and divertor radiation with reduced C content and N seeding. Residual gas analysis reveals a reduction of hydrocarbons by one order of magnitude and of O by a factor of 5 in the partial pressure owing to the evaporation. The evolution of wall conditions, impurity fluxes and divertor radiation have been studied in ELMy H-mode plasmas (Bt = 2.7 T, Ip = 2.5 MA, Paux = 16 MW) whereas a non-seeded reference discharge was executed prior to the evaporation. The in situ measured Be flux at the midplane increased by about a factor of 40 whereas the C flux decreased by ~50% in the limiter phase of the first discharge with respect to the reference, but erosion of the Be layer and partial coverage with C takes place quickly. To make best use of the protective Be layer, only the first four discharges were employed for a gas balance analysis providing a D retention rate of 1.94 × 1021 D s-1 which is comparable to rates with C walls. But the Be evaporation provides a non-saturated surface with respect to D and short term retention is not negligible in the balance; the measured retention is overestimated with respect to steady-state conditions like that of the ILW. Moreover, C was only moderately reduced and co-deposition of fuel with eroded Be and C occurs. The lower C content leads to a minor reduction in divertor radiation as the reference phase prior to seeding indicates. N adds to the radiation of D and the remaining C, and the N content rises due to the legacy effect which has been quantified by gas balance to be 30% of the injected N. C radiation increases with exposure time, and both contributors cause an increase in the radiated fraction in the divertor from 50% to 70%. The radiation pattern suggests that N dominates the increase in the first discharges though C

  18. Modeling the influence of precursor volatility and molecular structure on secondary organic aerosol formation using evaporated fuel experiments

    NASA Astrophysics Data System (ADS)

    Jathar, S. H.; Donahue, N. M.; Adams, P. J.; Robinson, A. L.

    2013-09-01

    We use SOA production data from an ensemble of evaporated fuels to test various SOA formation models. Except for gasoline, traditional SOA models focusing exclusively on volatile species in the fuels under-predict the observed SOA formation. These models can be improved dramatically by accounting for lower volatility species, but at the cost of a large set of free parameters. In contrast, a SOA model based only on the volatility of the precursor, starting with the volatility distribution of the evaporated fuels and optimized for the volatility reduction of first-generation products, reasonably reproduces the observed SOA formation with relatively few free parameters. The exceptions are exotic fuels such as Fischer-Tropsch fuels that expose the central assumption of the volatility based model that most emissions consist of complex mixtures displaying reasonably average behavior. However, for the vast majority of fuels, the volatility based model performs well.

  19. Ultrafast high-repetition imaging of fuel sprays using picosecond fiber laser.

    PubMed

    Purwar, Harsh; Wang, Hongjie; Tang, Mincheng; Idlahcen, Saïd; Rozé, Claude; Blaisot, Jean-Bernard; Godin, Thomas; Hideur, Ammar

    2015-12-28

    Modern diesel injectors operate at very high injection pressures of about 2000 bar resulting in injection velocities as high as 700 m/s near the nozzle outlet. In order to better predict the behavior of the atomization process at such high pressures, high-resolution spray images at high repetition rates must be recorded. However, due to extremely high velocity in the near-nozzle region, high-speed cameras fail to avoid blurring of the structures in the spray images due to their exposure time. Ultrafast imaging featuring ultra-short laser pulses to freeze the motion of the spray appears as an well suited solution to overcome this limitation. However, most commercial high-energy ultrafast sources are limited to a few kHz repetition rates. In the present work, we report the development of a custom-designed picosecond fiber laser generating ∼ 20 ps pulses with an average power of 2.5 W at a repetition rate of 8.2 MHz, suitable for high-speed imaging of high-pressure fuel jets. This fiber source has been proof tested by obtaining backlight images of diesel sprays issued from a single-orifice injector at an injection pressure of 300 bar. We observed a consequent improvement in terms of image resolution compared to standard white-light illumination. In addition, the compactness and stability against perturbations of our fiber laser system makes it particularly suitable for harsh experimental conditions. PMID:26832004

  20. Fuel spray simulation with two-fluid nozzles

    NASA Astrophysics Data System (ADS)

    Ingebo, Robert D.

    1989-01-01

    Two-phase interacting flow inside a two-fluid fuel atomizer was investigated and a correction of aerodynamic and liquid-surface forces with characteristic drop diameter was obtained for liquid-jet breakup in Mach 1 gas flow. Nitrogen gas mass-flux was varied from 6 to 50 g/sq cm sec by using four differently sized two-fluid atomizers with nozzle diameters varying from 0.32 to 0.56 cm. The correlation was derived by using the acoustic gas velocity, V sub c, as a basic parameter in defining and evaluating the dimensionless product of the Weber (We) and Reynolds (Re) numbers. By using the definition of WeRe, it was found that the ratio of orifice diameter to Sauter mean drop diameter could be correlated with the dimensionless ratio WeRe and the gas to liquid density ratio.

  1. Erosion Resistance of High Velocity Oxy-Fuel WC-Co-Cr Thermal Spray Coatings

    NASA Astrophysics Data System (ADS)

    Imeson, Chris

    Thermal spray coatings have been incorporated in oil and gas extraction efforts for many years. Recently, High Velocity Oxy-Fuel (HVOF) has become increasingly incorporated where erosive environments are present. This study investigates the microstructural and mechanical properties of HVOF WC-Co-Cr coatings deposited at SharkSkin Coatings ltd. The deposited coatings exhibited a low porosity with high adhesion strength, hardness, and superior erosion resistance. In this study, a recirculating solid particle erosion testing machine was designed and fabricated to simulate an erosive environment on a laboratory scale. This study was also aimed at improving microstructures and mechanical properties of the coatings by modifying the two coating deposition parameters e.g. standoff and pre-cycle heating. It was determined that pre-spray substrate heating negatively affected the coatings microstructures e.g. porosity, while reducing the stand-off distance positively influenced the coating microstructures and mechanical properties, e.g. erosion resistance.

  2. A Numerical Study on Gas Phase Dynamics of High-Velocity Oxygen Fuel Thermal Spray

    NASA Astrophysics Data System (ADS)

    Baik, Jae-Sang; Park, Sun-Kyu; Kim, Youn-Jea

    2008-08-01

    The high-velocity oxygen fuel (HVOF) thermal spray is used for a particulate deposition process in which micro-sized particles are propelled and heated in a supersonic combusting gas stream. It is characterized by high gas velocity and high density and is being used in an increasing variety of coating applications, such as ceramic and composite coatings, to improve wear and abrasion resistance. The particle temperature and velocity are two of the most important parameters in HVOF thermal spraying, which affect the quality of the coatings. To understand the particle dynamics, it is necessary to study, first, the thermal flow characteristics in the HVOF system. In this study, a numerical analysis is performed to predict the gas dynamic behaviors, and the effect of the geometrical parameter is studied to optimize the nozzle design.

  3. Numerical simulation of the flow field and fuel sprays in an IC engine

    NASA Technical Reports Server (NTRS)

    Nguyen, H. L.; Schock, H. J.; Ramos, J. I.; Carpenter, M. H.; Stegeman, J. D.

    1987-01-01

    A two-dimensional model for axisymmetric piston-cylinder configurations is developed to study the flow field in two-stroke direct-injection Diesel engines under motored conditions. The model accounts for turbulence by a two-equation model for the turbulence kinetic energy and its rate of dissipation. A discrete droplet model is used to simulate the fuel spray, and the effects of the gas phase turbulence on the droplets is considered. It is shown that a fluctuating velocity can be added to the mean droplet velocity every time step if the step is small enough. Good agreement with experimental data is found for a range of ambient pressures in Diesel engine-type microenvironments. The effects of the intake swirl angle in the spray penetration, vaporization, and mixing in a uniflow-scavenged two-stroke Diesel engine are analyzed. It is found that the swirl increases the gas phase turbulence levels and the rates of vaporization.

  4. Flame structure of wall-impinging diesel fuel sprays injected by group-hole nozzles

    SciTech Connect

    Gao, Jian; Moon, Seoksu; Nishida, Keiya; Matsumoto, Yuhei; Zhang, Yuyin

    2009-06-15

    This paper describes an investigation of the flame structure of wall-impinging diesel sprays injected by group-hole nozzles in a constant-volume combustion vessel at experimental conditions typical of a diesel engine. The particular emphasis was on the effect of the included angle between two orifices (0-15 deg. in current study) on the flame structure and combustion characteristics under various simulated engine load conditions. The laser absorption scattering (LAS) technique was applied to analyze the spray and mixture properties. Direct flame imaging and OH chemiluminescence imaging were utilized to quantify the ignition delay, flame geometrical parameters, and OH chemiluminescence intensity. The images show that the asymmetric flame structure emerges in wall-impinging group-hole nozzle sprays as larger included angle and higher engine load conditions are applied, which is consistent with the spray shape observed by LAS. Compared to the base nozzle, group-hole nozzles with large included angles yield higher overall OH chemiluminescence intensity, wider flame area, and greater proportion of high OH intensity, implying the better fuel/air mixing and improved combustion characteristics. The advantages of group-hole nozzle are more pronounced under high load conditions. Based on the results, the feasibility of group-hole nozzle for practical direct injection diesel engines is also discussed. It is concluded that the asymmetric flame structure of a group-hole nozzle spray is favorable to reduce soot formation over wide engine loads. However, the hole configuration of the group-hole nozzle should be carefully considered so as to achieve proper air utilization in the combustion chamber. Stoichiometric diesel combustion is another promising application of group-hole nozzle. (author)

  5. Development of methanol evaporation plate to reduce methanol crossover in a direct methanol fuel cell

    NASA Astrophysics Data System (ADS)

    Zhang, Ruiming

    This research focuses on methanol crossover reduction in direct methanol fuel cells (DMFC) through separating the methanol vapor from its liquid phase and feeding the vapor passively at low temperature range. Membrane electrode assemblies (MEAs) were fabricated by using commercial available membrane with different thickness at different anode catalyst loading levels, and tested under the operating conditions below 100°C in cell temperature and cathode exit open to ambient pressure. Liquid methanol transport from the anode through the membrane into cathode ("methanol crossover") is identified as one of the major efficiency losses in a DMFC. It is known that the methanol crossover rate in the vapor phase is much lower than in liquid phase. Vapor feed can be achieved by heating the liquid methanol to elevated temperatures (>100°C), but other issues limit the performance of the cell when operating above 100°C. High temperature membranes and much more active cathode catalyst structures are required, and a complex temperature control system must be employed. However, methanol vapor feed can also occur at a lower temperature range (<100°C) by separating its vapor from the liquid phase by evaporation through a porous body. The methanol crossover with this vapor feed mode is lower compared with the direct liquid methanol feed. A new method of using a methanol evaporation plate (MEP) to separate the vapor from its liquid phase to reduce the liquid methanol crossover at low temperature range is developed. A MEP plays the roles of liquid/vapor methanol phase separation and evaporation in a DMFC. The goal of this study is to develop a MEP with the proper properties to achieve high methanol phase separation efficiency and fast methanol evaporation rate over a wide range of temperature, i.e., from room temperature up to near boiling temperature (100°C). MEP materials were selected and characterized. MEPs made from three different types were tested extensively with different

  6. Monitoring of fuel consumption and aromatics formation in a kerosene spray flame as characterized by fluorescence spectroscopy.

    PubMed

    Allouis, C; Apicella, B; Barbella, R; Beretta, F; Ciajolo, A; Tregrossi, A

    2003-06-01

    The large presence of aromatic compounds in distillate fossil fuels should allow, in line of principle, to follow the fuel consumption and/or the presence of unburned fuel in a high temperature environment like a burner or the exhaust of combustion systems by exploiting the high fluorescence emission of aromatic fuel components. To this aim an UV-excited fluorescence source has to be used since the aromatic fuel components are strongly fluorescing in the UV region of the emission spectrum. In this work UV-excited laser induced fluorescence (LIF) diagnostics was applied to spray flames of kerosene in order to follow the fuel consumption and the formation of aromatic species. A strong UV signal was detected in the spray region of the flame that presented a shape similar to that found in the LIF spectra preliminary measured on the cold spray and in the room-temperature fluorescence of fuel solutions. The decrease of UV signal along the spray flame region was associated to the consumption of the fuel, but more difficult seems to be the attribution of a broad visible emission, that is present downstream of the flame. The visible emission feature could be assigned to flame-formed PAH species contained in the high molecular weight species, hypothesizing that their fluorescence spectra are shifted toward the visible for effect of the high temperature flame environment. PMID:12718975

  7. Investigation of spray characteristics for flashing injection of fuels containing dissolved air and superheated fuels

    NASA Technical Reports Server (NTRS)

    Solomon, A. S. P.; Chen, L. D.; Faeth, G. M.

    1982-01-01

    The flow, atomization and spreading of flashing injector flowing liquids containing dissolved gases (jet/air) as well as superheated liquids (Freon II) were considered. The use of a two stage expansion process separated by an expansion chamber, ws found to be beneficial for flashing injection particularly for dissolved gas systems. Both locally homogeneous and separated flow models provided good predictions of injector flow properties. Conventional correlations for drop sizes from pressure atomized and airblast injectors were successfully modified, using the separated flow model to prescribe injector exit conditions, to correlate drop size measurements. Additional experimental results are provided for spray angle and combustion properties of sprays from flashing injectors.

  8. Effects of Air-Fuel Spray and Flame Formation in a Compression-Ignition Engine

    NASA Technical Reports Server (NTRS)

    Rothrock, A M; Waldron, C D

    1937-01-01

    High-speed motion pictures were taken at the rate of 2,500 frames per second of the fuel spray and flame formation in the combustion chamber of the NACA combustion apparatus. The compression ratio was 13.2 and the speed 1,500 revolutions per minute. An optical indicator was used to record the time-pressure relationship in the combustion chamber. The air-fuel ratio was varied from 10.4 to 365. The results showed that as the air-fuel ratio was increased definite stratification of the charge occurred in the combustion chamber even though moderate air flow existed. The results also showed the rate of vapor diffusion to be relatively slow.

  9. Computational fluid dynamic analysis of a High-Velocity Oxygen-Fuel (HVOF) thermal spray torch

    SciTech Connect

    Hassan, B.; Oberkampf, W.L.; Neiser, R.A.; Roemer, T.J.

    1995-09-01

    The gas dynamics of a High-Velocity Oxygen-Fuel (HVOF) torch are analyzed using computational fluid dynamics (CFD) techniques. The thermal spray device analyzed is similar to a Metco Diamond Jet torch with powder feed. The injection nozzle is assumed to be axisymmetric with premixed fuel and oxygen fed from an annulus, and air cooling injected along the interior surface of the aircap. The aircap, a cronically converging nozzle, achieves choked flow conditions at the exit and a supersonic, under-expanded jet develops externally. Finite difference equations for mass, momentum, and energy conservation are solved for the gas dynamics. The combustion process is modeled using a single-step and a 12-step quasi-global finite-rate chemistry model with dissociation of the gas and a total of nine species. Turbulent flow inside the aircap and in the free-jet decay is modeled using a two-equation k-{epsilon} model. An iterative, implicit, finite volume numerical method is used to solve the gas dynamic equations inside and outside the torch . The CFD results are compared with recent experimental measurements of pressure inside the HVOF aircap. Comparisons are made for two flow rates of premixed fuel and oxygen and air cooling. This paper presents the first published comparisons of CFD predictions and experimental measurements for HVOF tbermal spraying.

  10. Influence of spray additives on droplet evaporation and residual patterns on wax and wax-free surfaces

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Evaporation time and wetted area of single droplets sizing from 246 to 886 µm at relative humidity (RH) ranging from 30 to 90% were measured with sequential images under controlled laboratory conditions. Droplets were placed inside an environmental-controlled chamber under a stereoscope and a high ...

  11. Some Factors Affecting the Reproducibility of Penetration and the Cut-Off of Oil Sprays for Fuel-injection Engines

    NASA Technical Reports Server (NTRS)

    Beardsley, E G

    1928-01-01

    This investigation was undertaken at the Langley Memorial Aeronautical Laboratory in connection with a general research on fuel-injection for aircraft. The purpose of the investigation was to determine the factors controlling the reproducibility of spray penetration and secondary discharges after cut-off. The development of single sprays from automatic injection valves was recorded by means of special high-speed photographic apparatus capable of taking 25 consecutive pictures of the moving spray at a rate of 4,000 per second. The effect of two types of injection valves, injection-valve tube length, initial pressure in the injection-valve tube, speed of the injection control mechanism, and time of spray cut-off, on the reproducibility of spray penetration, and on secondary discharges were investigated. It was found that neither type of injection valve materially affected spray reproducibility. The initial pressure in the injection-valve tube controlled the reproducibility of spray penetrations. An increase in the initial pressure or in the length of the injection-valve tube slightly increased the spray penetration within the limits of this investigation. The speed of the injection-control mechanism did not affect the penetration. Analysis of the results indicates that secondary discharges were caused in this apparatus by pressure waves initiated by the rapid opening of the cut-off valve. The secondary discharges were eliminated in this investigation by increasing the length of the injection-valve tube. (author)

  12. Synchronized droplet size measurements for coal-water-slurry (CWS) diesel sprays of an electronically-controlled fuel injection system

    SciTech Connect

    Kihm, K.D.; Terracina, D.P.; Payne, S.E.; Caton, J.A.

    1993-12-31

    Experiments were completed to study intermittent coal-water slurry (CWS) fuel sprays injected from an electronically-controlled accumulator injector system. A laser diffraction particle analyzing (LDPA) technique was used to measure the spray diameters (Sauter mean diameter, SMD) assuming the Rosin-Rammler two parameter model. In order to ensure an accurate synchronization of the measurement with the intermittent sprays, a new synchronization technique was developed using the light extinction signal as a triggering source for the data taking initiation. This technique allowed measurement of SMDs near the spray tip where the light extinction was low and the data were free from the multiscattering bias. Coal-water slurry fuel with 50% coal loading in mass containing 5 {mu}m mass median diameter coal particulates was considered. Injection pressures ranging from 28 to 110 MPa, two different nozzle orifice diameters, 0.2 ad 0.4 mm, and four axial measurement locations from 60 to 120 mm from the nozzle orifice were studied. Measurements were made for pressurized (2.0 MPa in gauge) and for ambient chamber conditions. The spray SMD showed an increase with the distance of the axial measurement location and with the ambient gas density, and showed a decrease with increasing injection pressure. A correlation of the Sauter mean diameter with the injection conditions was determined. The results were also compared with previous SMD correlations that were available only for diesel fuel sprays.

  13. Effect of orifice length-diameter ratio on fuel sprays for compression-ignition engines

    NASA Technical Reports Server (NTRS)

    Gelalles, A G

    1933-01-01

    Experimental results on the effect of the length-diameter ratio of the orifice on the spray characteristics, together with a brief analysis of the factors affecting these characteristics, are presented in this report. The length-diameter ratios tested ranged from 0.5 to 10; the orifice diameters from 0.008 to 0.040 inch; and the injection pressures from 2,000 to 8,000 pounds per square inch. The density of the air into which the fuel was discharged was varied from 0.38 to 1.35 pounds per cubic foot.

  14. In vitro performance of ceramic coatings obtained by high velocity oxy-fuel spray.

    PubMed

    Melero, H; Garcia-Giralt, N; Fernández, J; Díez-Pérez, A; Guilemany, J M

    2014-01-01

    Hydroxyapatite coatings obtained by plasma-spraying have been used for many years to improve biological performance of bone implants, but several studies have drawn attention to the problems arising from high temperatures and the lack of mechanical properties. In this study, plasma-spraying is substituted by high velocity oxy-fuel (HVOF) spray, with lower temperatures reached, and TiO2 is added in low amounts to hydroxyapatite in order to improve the mechanical properties. Four conditions have been tested to evaluate which are those with better biological properties. Viability and proliferation tests, as well as differentiation assays and morphology observation, are performed with human osteoblast cultures onto the studied coatings. The hydroxyapatite-TiO2 coatings maintain good cell viability and proliferation, especially the cases with higher amorphous phase amount and specific surface, and promote excellent differentiation, with a higher ALP amount for these cases than for polystyrene controls. Observation by SEM corroborates this excellent behaviour. In conclusion, these coatings are a good alternative to those used industrially, and an interesting issue would be improving biological behaviour of the worst cases, which in turn show the better mechanical properties. PMID:25201392

  15. Particle melting behavior during high-velocity oxygen fuel thermal spraying

    NASA Astrophysics Data System (ADS)

    He, J.; Ice, M.; Lavernia, E.

    2001-03-01

    Particle melting behavior during high-velocity oxygen fuel (HVOF) thermal spraying was investigated using Inconel 625 powders. The powder characteristics and coating properties were investigated using scanning electron microscopy (SEM), x-ray, and microhardness studies. Results indicated that the volume fraction of unmelted particles in the coatings was dependent on the proportion of powder within a specified size range, in these experiments, 30 to 50 µm. This particle size range was primarily determined by the particle temperature, which was measured during spraying. Particle temperature significantly decreased as particle size increased. The microhardness values for the coatings containing unmelted particles were predicted by a simple rule-of-mixtures equation for the case of a low volume fraction of unmelted particles. However, for the condition of high volume fraction of unmelted particles, the measured microhardness values did not compare favorably with the calculated values, probably due to the presence of porosity, which occurred in the form of voids found among unmelted particles. The microstructure and characteristics of the feedstock powder were retained in the corresponding coating under certain spray conditions.

  16. Prediction of the structure of fuel sprays in gas turbine combustors

    NASA Technical Reports Server (NTRS)

    Shuen, J. S.

    1985-01-01

    The structure of fuel sprays in a combustion chamber is theoretically investigated using computer models of current interest. Three representative spray models are considered: (1) a locally homogeneous flow (LHF) model, which assumes infinitely fast interphase transport rates; (2) a deterministic separated flow (DSF) model, which considers finite rates of interphase transport but ignores effects of droplet/turbulence interactions; and (3) a stochastic separated flow (SSF) model, which considers droplet/turbulence interactions using random sampling for turbulence properties in conjunction with random-walk computations for droplet motion and transport. Two flow conditions are studied to investigate the influence of swirl on droplet life histories and the effects of droplet/turbulence interactions on flow properties. Comparison of computed results with the experimental data show that general features of the flow structure can be predicted with reasonable accuracy using the two separated flow models. In contrast, the LHF model overpredicts the rate of development of the flow. While the SSF model provides better agreement with measurements than the DSF model, definitive evaluation of the significance of droplet/turbulence interaction is not achieved due to uncertainties in the spray initial conditions.

  17. Effects of fuel cetane number on the structure of diesel spray combustion: An accelerated Eulerian stochastic fields method

    NASA Astrophysics Data System (ADS)

    Jangi, Mehdi; Lucchini, Tommaso; Gong, Cheng; Bai, Xue-Song

    2015-09-01

    An Eulerian stochastic fields (ESF) method accelerated with the chemistry coordinate mapping (CCM) approach for modelling spray combustion is formulated, and applied to model diesel combustion in a constant volume vessel. In ESF-CCM, the thermodynamic states of the discretised stochastic fields are mapped into a low-dimensional phase space. Integration of the chemical stiff ODEs is performed in the phase space and the results are mapped back to the physical domain. After validating the ESF-CCM, the method is used to investigate the effects of fuel cetane number on the structure of diesel spray combustion. It is shown that, depending of the fuel cetane number, liftoff length is varied, which can lead to a change in combustion mode from classical diesel spray combustion to fuel-lean premixed burned combustion. Spray combustion with a shorter liftoff length exhibits the characteristics of the classical conceptual diesel combustion model proposed by Dec in 1997 (http://dx.doi.org/10.4271/970873), whereas in a case with a lower cetane number the liftoff length is much larger and the spray combustion probably occurs in a fuel-lean-premixed mode of combustion. Nevertheless, the transport budget at the liftoff location shows that stabilisation at all cetane numbers is governed primarily by the auto-ignition process.

  18. Oxides of Nitrogen Emissions from the Combustion of Monodisperse Liquid Fuel Sprays. Ph.D. Thesis

    NASA Technical Reports Server (NTRS)

    Sarv, H.

    1985-01-01

    A study of NO sub x formation in a one dimensional monodisperse spray combustion system, which allowed independent droplet size variation, was conducted. Temperature, NO and NO sub x concentrations were measured in the transition region, encompassing a 26 to 74 micron droplet size range. Emission measurements of hydrocarbons, carbon monoxide, carbon dioxide and oxygen were also made. The equivalence ratio was varied between 0.8 and 1.2 for the fuels used, including methanol, isopropanaol, n-heptane and n-octane. Pyridine and pyrrole were added to n-heptane as nitrogen-containing additives in order to simulate synthetic fuels. Results obtained from the postflame regions using the pure fuels indicate an optimum droplet size in the range of 43 to 58 microns for minimizing NO sub x production. For the fuels examined, the maximum NO sub x reductions relative to the small droplet size limit were about 10 to 20% for lean and 20 to 30% for stoichiometric and rich mixtures. This behavior is attributed to droplet interactions and the transition from diffusive to premixed type of burning. Preflame vaporization controls the gas phase stoichiometry which has a significant effect on the volume of the hot gases surrounding a fuel droplet, where NO sub x is formed.

  19. Cold spray deposition of Ti2AlC coatings for improved nuclear fuel cladding

    NASA Astrophysics Data System (ADS)

    Maier, Benjamin R.; Garcia-Diaz, Brenda L.; Hauch, Benjamin; Olson, Luke C.; Sindelar, Robert L.; Sridharan, Kumar

    2015-11-01

    Coatings of Ti2AlC MAX phase compound have been successfully deposited on Zircaloy-4 (Zry-4) test flats, with the goal of enhancing the accident tolerance of LWR fuel cladding. Low temperature powder spray process, also known as cold spray, has been used to deposit coatings ∼90 μm in thickness using powder particles of <20 μm. X-ray diffraction analysis showed the phase-content of the deposited coatings to be identical to the powders indicating that no phase transformation or oxidation had occurred during the coating deposition process. The coating exhibited a high hardness of about 800 HK and pin-on-disk wear tests using abrasive ruby ball counter-surface showed the wear resistance of the coating to be significantly superior to the Zry-4 substrate. Scratch tests revealed the coatings to be well-adhered to the Zry-4 substrate. Such mechanical integrity is required for claddings from the standpoint of fretting wear resistance and resisting wear handling and insertion. Air oxidation tests at 700 °C and simulated LOCA tests at 1005 °C in steam environment showed the coatings to be significantly more oxidation resistant compared to Zry-4 suggesting that such coatings can potentially provide accident tolerance to nuclear fuel cladding.

  20. Cold spray deposition of Ti2AlC coatings for improved nuclear fuel cladding

    NASA Astrophysics Data System (ADS)

    Maier, Benjamin R.; Garcia-Diaz, Brenda L.; Hauch, Benjamin; Olson, Luke C.; Sindelar, Robert L.; Sridharan, Kumar

    2015-11-01

    Coatings of Ti2AlC MAX phase compound have been successfully deposited on Zircaloy-4 (Zry-4) test flats, with the goal of enhancing the accident tolerance of LWR fuel cladding. Low temperature powder spray process, also known as cold spray, has been used to deposit coatings ˜90 μm in thickness using powder particles of <20 μm. X-ray diffraction analysis showed the phase-content of the deposited coatings to be identical to the powders indicating that no phase transformation or oxidation had occurred during the coating deposition process. The coating exhibited a high hardness of about 800 HK and pin-on-disk wear tests using abrasive ruby ball counter-surface showed the wear resistance of the coating to be significantly superior to the Zry-4 substrate. Scratch tests revealed the coatings to be well-adhered to the Zry-4 substrate. Such mechanical integrity is required for claddings from the standpoint of fretting wear resistance and resisting wear handling and insertion. Air oxidation tests at 700 °C and simulated LOCA tests at 1005 °C in steam environment showed the coatings to be significantly more oxidation resistant compared to Zry-4 suggesting that such coatings can potentially provide accident tolerance to nuclear fuel cladding.

  1. Interior flow and near-nozzle spray development in a marine-engine diesel fuel injector

    NASA Astrophysics Data System (ADS)

    Hult, J.; Simmank, P.; Matlok, S.; Mayer, S.; Falgout, Z.; Linne, M.

    2016-04-01

    A consolidated effort at optically characterising flow patterns, in-nozzle cavitation, and near-nozzle jet structure of a marine diesel fuel injector is presented. A combination of several optical techniques was employed to fully transparent injector models, compound metal-glass and full metal injectors. They were all based on a common real-scale dual nozzle hole geometry for a marine two-stroke diesel engine. In a stationary flow rig, flow velocities in the sac-volume and nozzle holes were measured using PIV, and in-nozzle cavitation visualized using high-resolution shadowgraphs. The effect of varying cavitation number was studied and results compared to CFD predictions. In-nozzle cavitation and near-nozzle jet structure during transient operation were visualized simultaneously, using high-speed imaging in an atmospheric pressure spray rig. Near-nozzle spray formation was investigated using ballistic imaging. Finally, the injector geometry was tested on a full-scale marine diesel engine, where the dynamics of near-nozzle jet development was visualized using high-speed shadowgraphy. The range of studies focused on a single common geometry allows a comprehensive survey of phenomena ranging from first inception of cavitation under well-controlled flow conditions to fuel jet structure at real engine conditions.

  2. Evaluation of Liquid Fuel Spray Models for Hybrid RANS/LES and DLES Prediction of Turbulent Reactive Flows

    NASA Astrophysics Data System (ADS)

    Afshar, Ali

    An evaluation of Lagrangian-based, discrete-phase models for multi-component liquid sprays encountered in the combustors of gas turbine engines is considered. In particular, the spray modeling capabilities of the commercial software, ANSYS Fluent, was evaluated. Spray modeling was performed for various cold flow validation cases. These validation cases include a liquid jet in a cross-flow, an airblast atomizer, and a high shear fuel nozzle. Droplet properties including velocity and diameter were investigated and compared with previous experimental and numerical results. Different primary and secondary breakup models were evaluated in this thesis. The secondary breakup models investigated include the Taylor analogy breakup (TAB) model, the wave model, the Kelvin-Helmholtz Rayleigh-Taylor model (KHRT), and the Stochastic secondary droplet (SSD) approach. The modeling of fuel sprays requires a proper treatment for the turbulence. Reynolds-averaged Navier-Stokes (RANS), large eddy simulation (LES), hybrid RANS/LES, and dynamic LES (DLES) were also considered for the turbulent flows involving sprays. The spray and turbulence models were evaluated using the available benchmark experimental data.

  3. Solid oxide fuel cell electrolytes produced via very low pressure suspension plasma spray and electrophoretic deposition

    NASA Astrophysics Data System (ADS)

    Fleetwood, James D.

    Solid oxide fuel cells (SOFCs) are a promising element of comprehensive energy policies due to their direct mechanism for converting the oxidization of fuel, such as hydrogen, into electrical energy. Both very low pressure plasma spray and electrophoretic deposition allow working with high melting temperature SOFC suspension based feedstock on complex surfaces, such as in non-planar SOFC designs. Dense, thin electrolytes of ideal composition for SOFCs can be fabricated with each of these processes, while compositional control is achieved with dissolved dopant compounds that are incorporated into the coating during deposition. In the work reported, sub-micron 8 mole % Y2O3-ZrO2 (YSZ) and gadolinia-doped ceria (GDC), powders, including those in suspension with scandium-nitrate dopants, were deposited on NiO-YSZ anodes, via very low pressure suspension plasma spray (VLPSPS) at Sandia National Laboratories' Thermal Spray Research Laboratory and electrophoretic deposition (EPD) at Purdue University. Plasma spray was carried out in a chamber held at 320 - 1300 Pa, with the plasma composed of argon, hydrogen, and helium. EPD was characterized utilizing constant current deposition at 10 mm electrode separation, with deposits sintered from 1300 -- 1500 °C for 2 hours. The role of suspension constituents in EPD was analyzed based on a parametric study of powder loading, powder specific surface area, polyvinyl butyral (PVB) content, polyethyleneimine (PEI) content, and acetic acid content. Increasing PVB content and reduction of particle specific surface area were found to eliminate the formation of cracks when drying. PEI and acetic acid content were used to control suspension stability and the adhesion of deposits. Additionally, EPD was used to fabricate YSZ/GDC bilayer electrolyte systems. The resultant YSZ electrolytes were 2-27 microns thick and up to 97% dense. Electrolyte performance as part of a SOFC system with screen printed LSCF cathodes was evaluated with peak

  4. Properly synchronized measurements of droplet sizes for high-pressure intermittent coal-water slurry fuel sprays

    SciTech Connect

    Kihm, K.D.; Terracina, D.P.; Payne, S.E.; Caton, J.A.

    1993-12-31

    Experiments were completed to study intermittent coal-water slurry (CWS) fuel sprays injected from an electronically-controlled accumulator injector system. A new synchronization technique was developed using the light extinction signal as a triggering source for the data taking initiation with a laser diffraction particle analyzing (LDPA) technique. This technique allowed measurement of SMDs near the spray tip where the light extinction was low and the data were free from the multiscattering bias. Coal-water slurry fuel with 50% coal loading in mass containing 5 {mu}m mass median diameter coal particulates was considered. A correlation of the SMD with the injection conditions was determined which should show a satisfactory agreement with the measured SMD data. The spray SMD showed an increase with the distance of the axial measurement location and with the ambient gas density, and showed a decrease with increasing injection pressure.

  5. Semi-automated structural characterisation of high velocity oxy fuel thermally sprayed WC-Co based coatings

    NASA Astrophysics Data System (ADS)

    Fay, M. W.; Han, Y.; McCartney, G.; Korpiola, K.; Brown, P. D.

    2008-08-01

    The application of an automated procedure for the rapid assessment of selected area electron diffraction patterns is described. Comparison with complementary EDX spectra has enabled the thermal decomposition reactions within high velocity oxy-fuel thermally sprayed WC-Co coatings to be investigated.

  6. Aerodynamic study on supersonic flows in high-velocity oxy-fuel thermal spray process

    NASA Astrophysics Data System (ADS)

    Katanoda, Hiroshi; Matsuoka, Takeshi; Kuroda, Seiji; Kawakita, Jin; Fukanuma, Hirotaka; Matsuo, Kazuyasu

    2005-06-01

    To clarify the characteristics of gas flow in high velocity oxy-fuel (HVOF) thermal spray gun, aerodynamic research is performed using a special gun. The gun has rectangular cross-sectional area and sidewalls of optical glass to visualize the internal flow. The gun consists of a supersonic nozzle with the design Mach number of 2.0 followed by a straight passage called barrel. Compressed dry air up to 0.78 MPa is used as a process gas instead of combustion gas which is used in a commercial HVOF gun. The high-speed gas flows with shock waves in the gun and jets are visualized by schlieren technique. Complicated internal and external flow-fields containing various types of shock wave as well as expansion wave are visualized.

  7. Gas-phase saturation and evaporative cooling effects during wet compression of a fuel aerosol under RCM conditions

    SciTech Connect

    Goldsborough, S.S.; Johnson, M.V.; Zhu, G.S.; Aggarwal, S.K.

    2011-01-15

    Wet compression of a fuel aerosol has been proposed as a means of creating gas-phase mixtures of involatile diesel-representative fuels and oxidizer + diluent gases for rapid compression machine (RCM) experiments. The use of high concentration aerosols (e.g., {proportional_to}0.1 mL{sub fuel}/L{sub gas}, {proportional_to}1 x 10{sup 9} droplets/L{sub gas} for stoichiometric fuel loading at ambient conditions) can result in droplet-droplet interactions which lead to significant gas-phase fuel saturation and evaporative cooling during the volumetric compression process. In addition, localized stratification (i.e., on the droplet scale) of the fuel vapor and of temperature can lead to non-homogeneous reaction and heat release processes - features which could prevent adequate segregation of the underlying chemical kinetic rates from rates of physical transport. These characteristics are dependent on many factors including physical parameters such as overall fuel loading and initial droplet size relative to the compression rate, as well as fuel and diluent properties such as the boiling curve, vaporization enthalpy, heat capacity, and mass and thermal diffusivities. This study investigates the physical issues, especially fuel saturation and evaporative cooling effects, using a spherically-symmetric, single-droplet wet compression model. n-Dodecane is used as the fuel with the gas containing 21% O{sub 2} and 79% N{sub 2}. An overall compression time and compression ratio of 15.3 ms and 13.4 are used, respectively. It is found that smaller droplets (d{sub 0}{proportional_to} 2-3 {mu}m) are more affected by 'far-field' saturation and cooling effects, while larger droplets (d{sub 0}{proportional_to} 14 {mu}m) result in greater localized stratification of the gas-phase due to the larger diffusion distances for heat and mass transport. Vaporization of larger droplets is more affected by the volumetric compression process since evaporation requires more time to be completed

  8. The N.A.C.A. Apparatus for Studying the Formation and Combustion of Fuel Sprays and the Results from Preliminary Tests

    NASA Technical Reports Server (NTRS)

    Rothrock, A M

    1931-01-01

    Described here is an apparatus for studying the formation and combustion of fuel sprays under conditions closely simulating those in a high speed compression-ignition engine. The apparatus consists of a single-cylinder modified test engine, a fuel injection system so designed that a single charge of fuel can be injected into the combustion chamber, an electric driving motor, and a high-speed photographic apparatus. The cylinder head of the engine has a vertical disk form of combustion chamber whose sides are glass windows. When the fuel is injected into the combustion chamber, motion pictures at the rate of 2000 per second are taken of the spray formation by means of spark discharges. When combustion takes place, the light of combustion is recorded on the same photographic film as the spray photographs. Included here are the results of some tests to determine the effect of air temperature, air flow, and nozzle design on the spray formation. The results show that the compression temperature has little effect on the penetration of the fuel spray, but does not affect the dispersion, that air velocities of about 300 feet per second are necessary to destroy the core of the spray, and that the effect of air flow on the spray is controlled to a certain extent by the design of the injection nozzle. The results on the combustion of the spray show that when ignition does not take place until after spray cut-off, the ignition may start almost simultaneously throughout the combustion chamber or at different points throughout the chamber. When ignition takes place before spray cut-off, the combustion starts around the edge of the spray and then spreads throughout the chamber.

  9. NOx formation from the combustion of monodisperse n-heptane sprays doped with fuel-nitrogen additives

    NASA Technical Reports Server (NTRS)

    Sarv, Hamid; Cernansky, Nicholas P.

    1989-01-01

    A series of experiments with simulated synthetic fuels were conducted in order to investigate the effect of droplet size on the conversion of fuel-nitrogen to NOx. Pyridine and pyrrole were added to n-heptane as nitrogen-containing additives and burned as monodisperse fuel droplets under various operating conditions in a spray combustion facility. The experimental results indicate that under stoichiometric and fuel-rich conditions, reducing the droplet size increases the efficiency of fuel-N conversion to NOx. This observation is associated with improved oxidation of the pyrolysis fragments of the additive by better oxygen penetration through the droplet flame zone. The dominant reactions by which fuel-N is transformed to NOx were also considered analytically by a premixed laminar flame code. The calculations are compared to the small droplet size results.

  10. Liquid spray cooling of a heated surface

    NASA Technical Reports Server (NTRS)

    Grissom, W. M.; Wierum, F. A.

    1981-01-01

    The lowest surface temperature possible for the existance of spray evaporative cooling is determined experimentally to be a linear function of the impinging spray mass flux. A conduction-controlled analytical model of droplet evaporation gives fairly good agreement with experimental measurements at atmospheric pressure. At reduced pressures droplet evaporation rates are decreased significantly such that an optimum operating pressure exists for each desired surface heat flux. The initiation of the 'Leidenfrost state' provides the upper surface temperature bound for spray evaporative cooling.

  11. Effect of pervaporation plate thickness on the rate of methanol evaporation in a passive vapor-feed direct methanol fuel cell

    NASA Astrophysics Data System (ADS)

    Fauzi, N. F. I.; Hasran, U. A.; Kamarudin, S. K.

    2015-09-01

    In a passive vapor-feed direct methanol fuel cell (DMFC), methanol vapor is typically obtained using a pervaporation plate in a process by which liquid methanol contained in the fuel reservoir undergoes a phase change to vapor in the anodic vapor chamber. This work investigates the effect of pervaporation plate thickness on the rate of methanol evaporation using a three-dimensional simulation model developed by varying the plate thickness. A. The rate of methanol evaporation was measured using Darcy's law. The rate of methanol evaporation was found to be inversely proportional to the plate thickness, where the decrease in thickness inevitably lowers the resistance along the plate and consequently increases the methanol transport through the plate. This shows that the plate thickness has a significant influence on the rate of methanol evaporation and thereby plays an important role in improving the performance of the passive vapor-feed direct methanol fuel cell.

  12. Effect of Nozzle Design on Fuel Spray and Flame Formation in a High-Speed Compression-Ignition Engine

    NASA Technical Reports Server (NTRS)

    Rothrock, A M; Waldron, C D

    1937-01-01

    Fuel was injected from different type of injection nozzles into the combustion chamber of the NACA combustion apparatus, operated as a compression-ignition engine. High speed motion pictures were taken of the fuel sprays and combustion. Single-orifice nozzles of 0.008, 0.020, and 0.040 inch diameter, and multiorifice nozzles having 2, 6, and 16 orifices were tested. Nozzles having impinging jets and slit orifices were also included. The photographs indicate that the rate of vapor diffusion from the spray is comparatively slow and that this slow rate of diffusion for combustion chambers with little or no air flow prevents the compression-ignition engine from giving the high performance inherent in the high compression ratios. The sprays from the multiorifice nozzles destroyed the air movement to a greater extent than did those from single orifice nozzles. It is concluded that high performance cannot be realized until the methods of distributing the fuel are improved by means of the injection-nozzle design, air flow, or both.

  13. Numerical Investigation of Combustion and Flow Dynamics in a High Velocity Oxygen-Fuel Thermal Spray Gun

    NASA Astrophysics Data System (ADS)

    Wang, Xiaoguang; Song, Qiuzhi; Yu, Zhiyi

    2016-02-01

    The combustion and flow behavior within a high velocity oxygen-fuel (HVOF) thermal spray gun is very complex and involves multiphase flow, heat transfer, chemical reactions, and supersonic/subsonic transitions. Additionally, this behavior has a significant effect on the formation of a coating. Non-premixed combustion models have been developed and are able to provide insight into the underlying physics of the process. Therefore, this investigation employs a non-premixed combustion model and the SST k - ω turbulence model to simulate the flow field of the JP5000 (Praxair-TAFA, US) HVOF thermal spray gun. The predicted temperature and velocity have a high level of agreement with experimental data when using the non-premixed combustion model. The results are focused on the fuel combustion, the subsequent gas dynamics within the HVOF gun, and the development of a supersonic free jet outside the gun. Furthermore, the oxygen/fuel inlet turbulence intensity, the fuel droplet size, and the oxygen/fuel ratio are investigated to determine their effect on the supersonic flow characteristics of the combustion gas.

  14. Characterization of sprays

    NASA Astrophysics Data System (ADS)

    Chigier, N.; Mao, C.-P.

    It is pointed out that most practical power generation and propulsion systems involve the burning of different types of fuel sprays, taking into account aircraft propulsion, industrial furnaces, boilers, gas turbines, and diesel engines. There has been a lack of data which can serve as a basis for spray model development and validation. A major aim of the present investigation is to fill this gap. Experimental apparatus and techniques for studying the characteristics of fuel sprays are discussed, taking into account two-dimensional still photography, cinematography, holography, a laser diffraction particle sizer, and a laser anemometer. The considered instruments were used in a number of experiments, taking into account three different types of fuel spray. Attention is given to liquid fuel sprays, high pressure pulsed diesel sprays, and coal-water slurry sprays.

  15. Characterization of sprays

    NASA Technical Reports Server (NTRS)

    Chigier, N.; Mao, C.-P.

    1984-01-01

    It is pointed out that most practical power generation and propulsion systems involve the burning of different types of fuel sprays, taking into account aircraft propulsion, industrial furnaces, boilers, gas turbines, and diesel engines. There has been a lack of data which can serve as a basis for spray model development and validation. A major aim of the present investigation is to fill this gap. Experimental apparatus and techniques for studying the characteristics of fuel sprays are discussed, taking into account two-dimensional still photography, cinematography, holography, a laser diffraction particle sizer, and a laser anemometer. The considered instruments were used in a number of experiments, taking into account three different types of fuel spray. Attention is given to liquid fuel sprays, high pressure pulsed diesel sprays, and coal-water slurry sprays.

  16. Titanium dioxide reinforced hydroxyapatite coatings deposited by high velocity oxy-fuel (HVOF) spray.

    PubMed

    Li, H; Khor, K A; Cheang, P

    2002-01-01

    Hydroxyapatite (HA) coatings with titania addition were produced by the high velocity oxy-fuel (HVOF) spray process. Mechanical properties of the as-sprayed coatings in terms of adhesive strength, shear strength and fracture toughness were investigated to reveal the effect of the titania reinforcement on HA. Qualitative phase analysis with X-ray diffraction (XRD) showed that mutual chemical reaction between TiO2 and HA, that formed CaTiO3 occurred during coating formation. Differential scanning calorimetry (DSC) analysis of the starting powders showed that the mutual chemical reaction temperature was approximately 1410 degrees C and the existence of TiO2 can effectively inhibit the decomposition of HA at elevated temperatures. The positive influence of TiO2 addition on the shear strength was revealed. The incorporation of 10 vol% TiO2 significantly improved the Young's modulus of HA coatings from 24.82 (+/- 2.44) GPa to 43.23 (+/- 3.20) GPa. It decreased to 38.51 (+/- 3.65) GPa as the amount of TiO2 increased to 20 vol%. However, the addition of TiO2 has a negative bias on the adhesive strength of HA coatings especially when the content of TiO2 reached 20 vol%. This is attributed to the weak chemical bonding and brittle phases existing at the splats' interface that resulted from mutual chemical reactions. The fracture toughness exhibited values of 0.48 (+/- 0.08) MPa m0.5, 0.60 (+/- 0.07) MPa m0.5 and 0.67 (+/- 0.06) MPa m0.5 for the HA coating, 10 vol% TiO2 blended HA coating and 20 vol% TiO2 blended HA coating respectively. The addition of TiO2 in HA coating with the amount of less than 20 vol% is suggested for satisfactory toughening effect in HVOF HA coating. PMID:11762858

  17. Deposition of solid oxide fuel cell electrodes by solution precursor plasma spray

    NASA Astrophysics Data System (ADS)

    Wang, Youliang

    Porous La1-xSrxMnO3 (LSM) perovskite cathodes and Yttria Stabilized Zirconia (YSZ)-Nickel (Ni) anodes were successfully deposited by direct current arc solution precursor plasma spray (DC-SPPS), in which a solution precursor of the product material was injected into DC plasma jet. The deposition mechanisms, such as the changes in the solution precursor with the increase of temperature and the evolution of the droplet as it moved along the plasma jet, as well as the impact of the synthesized particles onto the substrate, were investigated. The effects of processing parameters on the microstructure and phase composition of the fabricated LSM cathode and Ni-YSZ anode were examined systematically using TGA/TDA, XRD and SEM. Coating deposition efficiencies and porosities as a function of processing parameters were analyzed by statistical experimental design techniques, based on which the deposition processes were optimized. In addition, the hardness and electrical resistance of the fabricated coatings were measured. From the theoretical and experimental analyses conducted, a comprehensive description of the DC-SPPS process was developed. The precursor solution droplets undergo breakup; solvent evaporation and precursor salt precipitation and crystallization; precursor salt melting and decomposition; nucleation and growth of particles of the product phase; agglomeration, sintering, and perhaps melting of these particles; and impact onto the substrate. The breakup of droplets can only occur in the short period of time after the droplets are injected into the plasma jet. Agglomeration of droplets or particles may occur at any point along the plasma plume. This work has clearly established: (a) the critical importance of droplet breakup and the agglomeration of precursors or synthesized particles in-flight in the plasma jet in determining the structure of the deposited coating, and (b) the basis of the low deposition efficiencies obtained in DC-SPPS. The microstructure and

  18. Furnace endoscope—measuring fuel spray properties in hot and corrosive environments

    NASA Astrophysics Data System (ADS)

    Miikkulainen, P.; Kankkunen, A.; Järvinen, M. P.

    2004-12-01

    A furnace endoscope was developed to carry out in-furnace measurements of black liquor sprays in order to discover the initial velocity, opening angle and trajectory of the spray, and compare spray disintegration mechanisms and spray appearance with the ones measured in a spray chamber. An error analysis of the velocity measurement method was carried out, and the meaning of the optimum measurement distance from the optics to the observed object is discussed. Some details of the development process of the probe are also presented, especially the definition of the scale of the image and the cooling system of the protection tubes. The furnace endoscope can be used in difficult conditions, such as those found inside a chemical recovery boiler (~1,200°C and corrosive chemicals) with promising and accurate measurement results. The equipment has been tested in several furnaces.

  19. Hot air drum evaporator

    DOEpatents

    Black, Roger L.

    1981-01-01

    An evaporation system for aqueous radioactive waste uses standard 30 and 55 gallon drums. Waste solutions form cascading water sprays as they pass over a number of trays arranged in a vertical stack within a drum. Hot dry air is circulated radially of the drum through the water sprays thereby removing water vapor. The system is encased in concrete to prevent exposure to radioactivity. The use of standard 30 and 55 gallon drums permits an inexpensive compact modular design that is readily disposable, thus eliminating maintenance and radiation build-up problems encountered with conventional evaporation systems.

  20. Modeling of Two-Phase Flow and Heat Transfer in Low-Temperature Oxygen-Fuel Spray Process

    NASA Astrophysics Data System (ADS)

    Shan, Y. G.; Shen, C. H.; Jia, L. B.; Mostaghimi, J.

    2014-01-01

    The low-temperature oxygen-fuel (LTOF) spray is a modification of high velocity oxygen fuel spray. In this process, the high-temperature gas is accelerated to supersonic speed through a Laval nozzle followed by a straight barrel. By injecting room temperature gas into the mixing chamber, the temperature of the gas can be controlled in a range of about 1000-2500 K, so that some oxygen and temperature-sensitive materials, such as titanium and copper, can avoid oxidation or decomposition during the spraying process. The purpose of this paper is to establish a 2-D mathematical model to simulate the supersonic gas dynamics and particles behavior in LTOF process. The temperature and velocity of the flow fields, and the trajectory and heating of in-flight particles are predicted for different operating parameters. The model is validated by experimental data in the literature. Effects of the mixing gas flow rates, particle sizes, and injection conditions on this process were investigated as well.

  1. Controllable p- and n-type doping of poly[2-methoxy-5-(2‧-methyl-hexyloxy)-p-phenylenevinylene] films prepared by evaporative spray deposition using ultradilute solution

    NASA Astrophysics Data System (ADS)

    Sakiyama, Shin; Mizutani, Naoki; Fujita, Katsuhiko

    2016-04-01

    Evaporative spray deposition using an ultradilute solution (ESDUS) enables polymer film preparation using diluted solution at ppm levels. We used this method for p- and n-type doping of poly[2-methoxy-5-(2‧-methyl-hexyloxy)-p-phenylenevinylene] (MEH-PPV), which is a bipolar-transport polymer semiconductor. The device characteristics indicated a drastic improvement of conductivity with carrier mobility. Moreover, the doping efficiency was higher than 15% in both p- and n-type doping owing to the wide dopant dispersion realized by the ESDUS technique.

  2. Modeling the effects of drop drag and breakup on fuel sprays

    NASA Astrophysics Data System (ADS)

    Liu, Alex B.; Mather, Daniel; Reitz, Rolf D.

    1993-03-01

    Spray models were evaluated using experimentally measured trajectories and drop sizes of single drops injected into a high relative velocity gas flow. The computations were made using a modified version of the KIVA-2 code. It was found that the drop drag coefficient and the drop breakup time model constant had to be adjusted in order to match the measurements. Based on these findings, a new drop drag submodel is proposed in which the drop drag coefficient changes dynamically with the flow conditions. The model accounts for the effects of drop distortion and oscillation due to the relative motion between the drop and the gas. The value of the drag coefficient varies between the two limits of that of a rigid sphere (no distortion) and that of a disk (maximum distortion). The modified model was also applied to diesel sprays. The results show that the spray tip penetration is relatively insensitive to the value used for the drop drag coefficient. However, the distribution of drop sizes within sprays is influenced by drop drag. This is due to the fact that changes in drop drag produce changes in the drop-gas relative velocity. This, in turn, causes changes in the spray drop size through the drop breakup and coalescence processes. The changes occur in such a way that the net effect on the spray penetration is small over the tested ranges of conditions. These results emphasize that measurements of spray penetration are not sufficient to test and produce improved spray models. Instead, local measurements of drop size and velocity are needed to develop accurate spray models.

  3. Effect of High-Velocity Oxy-Fuel (HVOF) Thermal Spraying on Physical and Mechanical Properties of Type 316 Stainless Steel

    SciTech Connect

    Terry C. Totemeier

    2005-09-01

    Data on the microstructural, physical, and mechanical characteristics of high-velocity oxygen-fuel (HVOF)-sprayed type 316 stainless steel coatings are presented and compared with properties of wrought 316 stainless steel. Coatings were prepared at three different spray particle velocities; coating characteristics are presented as a function of velocity. The coatings had relatively low porosity and oxide contents and were significantly harder than annealed, wrought 316 stainless steel. The hardness difference is primarily attributed to high dislocation densities resulting from peening imparted by high-velocity spray particles. The coating hardness increased with increasing spray particle velocity, reflecting increased peening effects. The elastic modulus of the coatings was essentially identical to wrought material. The mean coefficient of thermal expansion of as-sprayed coatings was lower than wrought material, but the expansion of annealed coatings matched the wrought behavior.

  4. Experimental and numerical evaluation of the performance of supersonic two-stage high-velocity oxy-fuel thermal spray (Warm Spray) gun

    NASA Astrophysics Data System (ADS)

    Katanoda, H.; Morita, H.; Komatsu, M.; Kuroda, S.

    2011-03-01

    The water-cooled supersonic two-stage high-velocity oxy-fuel (HVOF) thermal spray gun was developed to make a coating of temperature-sensitive material, such as titanium, on a substrate. The gun has a combustion chamber (CC) followed by a mixing chamber (MC), in which the combustion gas is mixed with the nitrogen gas at room temperature. The mixed gas is accelerated to supersonic speed through a converging-diverging (C-D) nozzle followed by a straight passage called the barrel. This paper proposes an experimental procedure to estimate the cooling rate of CC, MC and barrel separately. Then, the mathematical model is presented to predict the pressure and temperature in the MC for the specific mass flow rates of fuel, oxygen and nitrogen by assuming chemical equilibrium with water-cooling in the CC and MC, and frozen flow with constant specific heat from stagnant condition to the throat in the CC and MC. Finally, the present mathematical model was validated by comparing the calculated and measured stagnant pressures of the CC of the two-stage HVOF gun.

  5. Effect of plastic viscosity and yield value on spray characteristics of magnesium-slurry fuel

    NASA Technical Reports Server (NTRS)

    Prok, George M

    1957-01-01

    Magnesium slurries were sprayed onto a sheet of paper from an air-atomizing injector. Drop sizes and distributions were then determined from photomicrographs. Four different surface-active additives were used in preparing the slurries to give plastic viscosities between 0.22 and 0.51 poise and yield values between 150 and 810 dynes-cm(exp 2). It was found that there was no significant variation in the spray characteristics of these slurries when tested under the same conditions.

  6. The development and application of an automatic boundary segmentation methodology to evaluate the vaporizing characteristics of diesel spray under engine-like conditions

    NASA Astrophysics Data System (ADS)

    Ma, Y. J.; Huang, R. H.; Deng, P.; Huang, S.

    2015-04-01

    Studying the vaporizing characteristics of diesel spray could greatly help to reduce engine emission and improve performance. The high-speed schlieren imaging method is an important optical technique for investigating the macroscopic vaporizing morphological evolution of liquid fuel, and pre-combustion constant volume combustion bombs are often used to simulate the high pressure and high temperature conditions occurring in diesel engines. Complicated background schlieren noises make it difficult to segment the spray region in schlieren spray images. To tackle this problem, this paper develops a vaporizing spray boundary segmentation methodology based on an automatic threshold determination algorithm. The methodology was also used to quantify the macroscopic characteristics of vaporizing sprays including tip penetration, near-field and far-field angles, and projected spray area and spray volume. The spray boundary segmentation methodology was realized in a MATLAB-based program. Comparisons were made between the spray characteristics obtained using the program method and those acquired using a manual method and the Hiroyasu prediction model. It is demonstrated that the methodology can segment and measure vaporizing sprays precisely and efficiently. Furthermore, the experimental results show that the spray angles were slightly affected by the injection pressure at high temperature and high pressure and under inert conditions. A higher injection pressure leads to longer spray tip penetration and a larger projected area and volume, while elevating the temperature of the environment can significantly promote the evaporation of cold fuel.

  7. Mechanistic modeling of evaporating thin liquid film instability on a BWR fuel rod with parallel and cross vapor flow

    NASA Astrophysics Data System (ADS)

    Hu, Chih-Chieh

    This work has been aimed at developing a mechanistic, transient, 3-D numerical model to predict the behavior of an evaporating thin liquid film on a non-uniformly heated cylindrical rod with simultaneous parallel and cross flow of vapor. Interest in this problem has been motivated by the fact that the liquid film on a full-length boiling water reactor fuel rod may experience significant axial and azimuthal heat flux gradients and cross flow due to variations in the thermal-hydraulic conditions in surrounding subchannels caused by proximity to inserted control blade tip and/or the top of part-length fuel rods. Such heat flux gradients coupled with localized cross flow may cause the liquid film on the fuel rod surface to rupture, thereby forming a dry hot spot. These localized dryout phenomena can not be accurately predicted by traditional subchannel analysis methods in conjunction with empirical dryout correlations. To this end, a numerical model based on the Level Contour Reconstruction Method was developed. The Standard k-ε turbulence model is included. A cylindrical coordinate system has been used to enhance the resolution of the Level Contour Reconstruction Model. Satisfactory agreement has been achieved between the model predictions and experimental data. A model of this type is necessary to supplement current state-of-the-art BWR core thermal-hydraulic design methods based on subchannel analysis techniques coupled with empirical dry out correlations. In essence, such a model would provide the core designer with a "magnifying glass" by which the behavior of the liquid film at specific locations within the core (specific axial node on specific location within a specific bundle in the subchannel analysis model) can be closely examined. A tool of this type would allow the designer to examine the effectiveness of possible design changes and/or modified control strategies to prevent conditions leading to localized film instability and possible fuel failure.

  8. Improved Orifice Plate for Spray Gun

    NASA Technical Reports Server (NTRS)

    Cunningham, W.

    1986-01-01

    Erratic spray pattern of commercial spray gun changed to repeatable one by simple redesign of two parts. In modified spray gun orifice plate and polytetrafluoroethylene bushing redesigned to assure centering and alignment with nozzle. Such improvement useful in many industrial applications requiring repeatable spray patterns. Might include spraying of foam insulation, paint, other protective coatings, detergents, abrasives, adhesives, process chemicals, or fuels. Unmodified spray gun produces erratic spray because lateral misalignment between orifice plate and nozzle.

  9. Evaporative precooling unit

    SciTech Connect

    Rogers, A.R.

    1988-03-15

    In combination with a refrigeration unit, an evaporative heat exchange unit for precooling an air stream traveling toward and over the condensing coil of the refrigeration unit is described. The heat exchange unit includes: (a) a frame, (b) a porous heat transfer pad mounted in the frame; (c) nozzle means carried on the frame for directing a spray mist forwardly of the heat transfer pad, the spray mist emitted from the nozzle means initially traveling in a direction of travel such that the mist will not contact the porous heat transfer pad; (d) means mounted on the frame for causing the turbulent intermixing of the air stream with the spray mist prior to the air stream passing through the porous heat transfer pad; and (e) means for controlling the quantity of water emitted by the nozzle means such that substantially all of the spray mist is intermixed with the air stream prior to the air stream passing through the heat transfer pad.

  10. The N.A.C.A. Photographic Apparatus for Studying Fuel Sprays from Oil Engine Injection Valves and Test Results from Several Researches

    NASA Technical Reports Server (NTRS)

    Beardsley, Edward G

    1928-01-01

    Apparatus for recording photographically the start, growth, and cut-off of oil sprays from injection valves has been developed at the Langley Memorial Aeronautical Laboratory. The apparatus consists of a high-tension transformer by means of which a bank of condensers is charged to a high voltage. The controlled discharge of these condensers in sequence, at a rate of several thousand per second, produces electric sparks of sufficient intensity to illuminate the moving spray for photographing. The sprays are injected from various types of valves into a chamber containing gases at pressures up to 600 pounds per square inch. Several series of pictures are shown. The results give the effects of injection pressure, chamber pressure, specific gravity of the fuel oil used, and injection-valve design, upon spray characteristics.

  11. On the gas dynamics of HVOF thermal sprays. [HVOF (High-Velocity Oxy-Fuel)

    SciTech Connect

    Hackett, C.M.; Settles, G.S.; Miller, J.D.

    1993-01-01

    An experimental study has been performed on the gas dynamic aspects of the HVOF thermal spray process. A commercially-available HVOF gun (Hobart Tafa JP-5000) is used in this study. Optical diagnostic techniques including microsecond-exposure schlieren and shadowgraph imaging are applied to visualize the hot supersonic jet produced by this equipment without any particle injection. Rapid turbulent mixing of the jet with the surrounding atmosphere is observed, which is an issue of concern in coating quality because of the possibility of oxidation of the sprayed particles. This mixing appears principally to be a function of the density ratio between the hot jet and the cold atmosphere, rather than depending upon the combustion-chamber pressure or barrel length. The supersonic core of the HVOF jet dissipates rapidly due to the, mixing, so that the jet is no longer supersonic when it impinges upon the target surface being sprayed. Secondary issues also observed in this study include strong jet-noise radiation from the HVOF plume and the entrainment and induced bulk motion of the surrounding air. All these issues have a background in the field of gas dynamics which has not been previously applied to thermal spray technology.

  12. Continuous synthesis of graphene sheets by spray pyrolysis and their use as catalysts for fuel cells.

    PubMed

    Zou, Biao; Wang, Xiao Xia; Huang, Xin Xin; Wang, Jian Nong

    2015-01-14

    Graphene sheets (GNS) were synthesized continuously by spray pyrolysis of iron carbonyl and pyridine. The Pt catalyst supported on GNS exhibited excellent durability for oxygen reduction reaction (ORR). The GNS, when used as a metal-free catalyst for ORR, showed performance even better than the commercial Pt/C catalyst. PMID:25421428

  13. Vacuum Plasma Spray of Cu-8Cr-4Nb for Advanced Liquid-Fuel Combustion Chambers

    NASA Technical Reports Server (NTRS)

    Zimmerman, F.; Elam, S.; Ellis, D.; Miller, H.; McKechnie, T.; Hickman, R.

    2001-01-01

    Vacuum plasma spray (VPS) formed Cu-8Cr-4Nb alloy, with low oxygen, exhibits higher strength at room and elevated temperature than material formed by extrusion. The VPS formed material exhibits slightly lower ductility than the extruded material. VPS forming of Cu-8Cr-4Nb can be used to produce near net structures with mechanical properties comparable to current extruded material.

  14. On the combustion of a laminar spray

    NASA Technical Reports Server (NTRS)

    Levy, Yeshayahou; Bulzan, Daniel L.

    1993-01-01

    A spray combustor, with flow velocities in the laminar range, exhibits a unique operating mode where large amplitude, self-induced oscillations of the flame shape occur. The phenomenon, not previously encountered, only occurs when fuel is supplied in the form of fine liquid droplets and does not occur when fuel is supplied in gaseous form. Several flow mechanisms are coupled in such a fashion as to trigger and maintain the oscillatory motion of the flame. These mechanisms include heat transfer and evaporation processes, dynamics of two-phase flows, and effects of gravity (buoyancy forces). An interface volume, lying above the fuel nozzle and below the flame was found to be the most susceptible to gravity effects and postulated to be responsible for inducing the oscillatory motion. Heptane fuel was used in the majority of the tests. Tests performed with iso-octane also showed similar results.

  15. Laser-induced plasma generation and evolution in a transient spray.

    PubMed

    Kawahara, Nobuyuki; Tsuboi, Kazuya; Tomita, Eiji

    2014-01-13

    The behaviors of laser-induced plasma and fuel spray were investigated by visualizing images with an ultra-high-speed camera. Time-series images of laser-induced plasma in a transient spray were visualized using a high-speed color camera. The effects of a shockwave generated from the laser-induced plasma on the evaporated spray behavior were investigated. The interaction between a single droplet and the laser-induced plasma was investigated using a single droplet levitated by an ultrasonic levitator. Two main conclusions were drawn from these experiments: (1) the fuel droplets in the spray were dispersed by the shockwave generated from the laser-induced plasma; and (2) the plasma position may have shifted due to breakdown of the droplet surface and the lens effect of droplets. PMID:24921999

  16. The effects of fuel additives on alcohol exhaust and evaporative emissions

    SciTech Connect

    Espinola, S.A.; Nebolon, J.F.; Pepley, R.K.; Tamura, A.T.

    1982-06-01

    As a result of the past decade of evaluation, the technical feasibility of alcohols as extenders and substitutes for gasoline in spark ignited engines has been generally established both with regards to performance and emissions. One of the problem areas is cold starting and warm-up driveability. High heats of vaporation and low vapor pressures at low temperatures of the alcohols are the cause of these problems. Current solutions include electric heating, separate fuel supply, and the addition of volatile components to the alcohol such as gasoline, isopentane and dimethyl ether. The alcohols typically are as clean burning or cleaner burning than gasoline. The effect on regulated emissions from using additives needs to be included in the evaluation of cold starting additives. This assessment should include consideration of total hydrocarbons as well as detailed hydrocarbons for photochemical impact and flame ionization detector responsivity. This paper presents an examination of the emissions evidence from two three-way catalysts equipped vehicles: A 1980 Ford Pinto and a 1981 Volkswagon Rabbit. The test fuels were neat methanol and a 5.5% (by mass) isopentane/methanol blend.

  17. Tribological Properties of Hard Metal Coatings Sprayed by High-Velocity Air Fuel Process

    NASA Astrophysics Data System (ADS)

    Lyphout, C.; Sato, K.; Houdkova, S.; Smazalova, E.; Lusvarghi, L.; Bolelli, G.; Sassatelli, P.

    2016-01-01

    Lowering the thermal energy and increasing the kinetic energy of hard metal particles sprayed by the newly developed HVAF systems can significantly reduce their decarburization, and increases the sliding wear and corrosion resistance of the resulting coatings, making the HVAF technique attractive, both economically and environmentally, over its HVOF predecessors. Two agglomerated and sintered feedstock powder chemistries, WC-Co (88/12) and WC-CoCr (86/10/4), respectively, with increasing primary carbides grain size from 0.2 to 4.0 microns, have been deposited by the latest HVAF-M3 process onto carbon steel substrates. Their dry sliding wear behaviors and friction coefficients were evaluated at room temperature via Ball-on-disk (ASTM G99-90) wear tests against Al2O3 counterparts, and via Pin-on-disk (ASTM G77-05) wear tests against modified martensitic steel counterparts in both dry and lubricated conditions. Sliding wear mechanisms, with the formation of wavy surface morphology and brittle cracking, are discussed regarding the distribution and size of primary carbides. Corrosion behaviors were evaluated via standard Neutral Salt Spray, Acetic Acid Salt Spray, accelerated corrosion test, and electrochemical polarization test at room temperature. The optimization of the tribological properties of the coatings is discussed, focusing on the suitable selection of primary carbide size for different working load applications.

  18. Characterization of the bone-like apatite precipitated on high velocity oxy-fuel (HVOF) sprayed calcium phosphate deposits.

    PubMed

    Khor, K A; Li, H; Cheang, P

    2003-02-01

    Bone-like apatite was precipitated on the surface of thermal sprayed calcium phosphate coatings following in vitro incubation in a simulated body fluid. The coatings were initially deposited on titanium alloy substrates by the high velocity oxy-fuel (HVOF) spray technique. Structural characterization and mechanical evaluation of the precipitated apatite layer were conducted. Results showed that the precipitation rate was directly influenced by the local Ca(2+) concentration in the vicinity of the coating's surface and that preferential dissolution of certain phases was found to accelerate the precipitation of the bone-like apatite. The dense precipitates exhibited a competitive Young's modulus value of approximately 120GPa, which was obtained through nanoindentation. This compared favorably to the calcium phosphate matrix. Differences in microstructure at various locations within the layer resulted in altered Young's modulus and microhardness values. Precipitation mechanism investigation was carried out through a comparative experiment. Chemical analysis showed that the precipitation of bone-like apatite on the calcium phosphate coating was quite conceivably a partial diffusion-controlled process. PMID:12485795

  19. Properties of heat-treated calcium phosphate coatings deposited by high-velocity oxy-fuel (HVOF) spray.

    PubMed

    Li, H; Khor, K A; Cheang, P

    2002-05-01

    The influence of crystallization, upon heat treatment, on the properties of high-velocity oxy-fuel (HVOF) sprayed hydroxyapatite (HA) coatings was investigated. The characterization of the HA coating was performed by X-ray diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FTIR). Differential Scanning Calorimeter (DSC) was employed to determine the crystallization temperature of the amorphous phase in an as-sprayed HA coating. The study demonstrated the effect of crystallization on the coating properties by considering the changes in materials chemistry, crystallinity level, and mechanical performance. Results showed that complete crystallization of the amorphous phase occurred at approximately 700 degrees C and the crystallization temperature was dependent on sample heating rate in the DSC test. The changes of ion groups were detected by FTIR, before and after the phase transformation. The crystallization of the coating after annealing at 750 degrees C resulted in a significant increase of the coatings' adhesive strength and shear strength, which attained maximum values 34 +/- 3 and 14.1 -/+ 0.8 MPa, respectively. Young's modulus increased from 21 +/- 1 to 25 +/- 2 GPa. Microhardness measurements confirmed the changes in coating properties. It is also found that the transformation from the amorphous phase has crystalline HA as the only resultant phase detected by XRD. PMID:11962650

  20. Computational analysis of a three-dimensional High-Velocity Oxygen-Fuel (HVOF) Thermal Spray torch

    SciTech Connect

    Hassan, B.; Lopez, A.R.; Oberkampf, W.L.

    1995-07-01

    An analysis of a High-Velocity Oxygen-Fuel Thermal Spray torch is presented using computational fluid dynamics (CFD). Three-dimensional CFD results are presented for a curved aircap used for coating interior surfaces such as engine cylinder bores. The device analyzed is similar to the Metco Diamond Jet Rotating Wire torch, but wire feed is not simulated. To the authors` knowledge, these are the first published 3-D results of a thermal spray device. The feed gases are injected through an axisymmetric nozzle into the curved aircap. Argon is injected through the center of the nozzle. Pre-mixed propylene and oxygen are introduced from an annulus in the nozzle, while cooling air is injected between the nozzle and the interior wall of the aircap. The combustion process is modeled assuming instantaneous chemistry. A standard, two-equation, K-{var_epsilon} turbulence model is employed for the turbulent flow field. An implicit, iterative, finite volume numerical technique is used to solve the coupled conservation of mass, momentum, and energy equations for the gas in a sequential manner. Flow fields inside and outside the aircap are presented and discussed.

  1. High-Velocity Oxygen Fuel Thermal Spray of Fe-Based Amorphous Alloy: a Numerical and Experimental Study

    NASA Astrophysics Data System (ADS)

    Ajdelsztajn, L.; Dannenberg, J.; Lopez, J.; Yang, N.; Farmer, J.; Lavernia, E. J.

    2009-09-01

    The fabrication of dense coatings with appropriate properties using a high velocity oxygen fuel (HVOF) spray process requires an in-depth understanding of the complete gas flow field and particle behavior during the process. A computational fluid dynamics (CFD) model is implemented to investigate the gas flow behavior that occurs during the HVOF process and a simplified one-dimensional decoupled model of the in-flight thermal behavior of the amorphous Fe-based powder particles was developed and applied for three different spray conditions. The numerical results were used to rationalize the different coating microstructures described in the experimental results. Low porosity and amorphous coatings were produced using two different particle size distributions (16 to 25 μm and 25 to 53 μm). The amorphous characteristics of the powder were retained in the coating due to melting and rapid solidification in the case of very fine powder or ligaments (<16 μm) and to the fact that the crystallization temperature was not reached in the case of the large particles (16 to 53 μm).

  2. Transient heat transfer behavior of water spray evaporative cooling on a stainless steel cylinder with structured surface for safety design application in high temperature scenario

    NASA Astrophysics Data System (ADS)

    Aamir, Muhammad; Liao, Qiang; Hong, Wang; Xun, Zhu; Song, Sihong; Sajid, Muhammad

    2016-05-01

    High heat transfer performance of spray cooling on structured surface might be an additional measure to increase the safety of an installation against any threat caused by rapid increase in the temperature. The purpose of present experimental study is to explore heat transfer performance of structured surface under different spray conditions and surface temperatures. Two cylindrical stainless steel samples were used, one with pyramid pins structured surface and other with smooth surface. Surface heat flux of 3.60, 3.46, 3.93 and 4.91 MW/m2 are estimated for sample initial average temperature of 600, 700, 800 and 900 °C, respectively for an inlet pressure of 1.0 MPa. A maximum cooling rate of 507 °C/s was estimated for an inlet pressure of 0.7 MPa at 900 °C for structured surface while for smooth surface maximum cooling rate of 356 °C/s was attained at 1.0 MPa for 700 °C. Structured surface performed better to exchange heat during spray cooling at initial sample temperature of 900 °C with a relative increase in surface heat flux by factor of 1.9, 1.56, 1.66 and 1.74 relative to smooth surface, for inlet pressure of 0.4, 0.7, 1.0 and 1.3 MPa, respectively. For smooth surface, a decreasing trend in estimated heat flux is observed, when initial sample temperature was increased from 600 to 900 °C. Temperature-based function specification method was utilized to estimate surface heat flux and surface temperature. Limited published work is available about the application of structured surface spray cooling techniques for safety of stainless steel structures at very high temperature scenario such as nuclear safety vessel and liquid natural gas storage tanks.

  3. Modeling of the Evaporative Cooling of Running-Down Liquid Films in the Slit Channel of the Spraying Device of a Cooling Tower

    NASA Astrophysics Data System (ADS)

    Dashkov, G. V.; Malenko, G. L.; Solodukhin, A. D.; Tyutyuma, V. D.

    2014-11-01

    This paper presents the results of computational modeling of the nonstationary evaporative cooling of a liquid film running down a vertical surface cooled by a turbulent vapor-air counterflow. The heat and mass transfer problem has been formulated in conjugate form. The calculation data on the total heat flow density at the interface for various instants of time are given.

  4. Comparison of the Mechanical and Electrochemical Properties of WC-25Co Coatings Obtained by High Velocity Oxy-Fuel and Cold Gas Spraying

    NASA Astrophysics Data System (ADS)

    Couto, M.; Dosta, S.; Fernández, J.; Guilemany, J. M.

    2014-12-01

    Cold gas spray (CGS) coatings were previously produced by spraying WC-25Co cermet powders onto Al7075-T6 and low-carbon steel substrates. Unlike conventional flame spray techniques (e.g., high-velocity oxy-fuel; HVOF), no melting of the powder occurs; the particles are deformed and bond together after being sprayed by a supersonic jet of compressed gas, thereby building up several layers and forming a coating. WC-Co cermets are used in wear-resistant parts, because of their combination of mechanical, physical, and chemical properties. XRD tests were previously run on the initial powder and the coatings to determine possible phase changes during spraying. The bonding strength of the coatings was measured by adhesion tests. Here, WC-25Co coatings were also deposited on the same substrates by HVOF spraying. The wear resistance and fracture toughness of the coatings obtained previously by CGS and the HVOF coatings obtained here were studied. Their corrosion resistance was determined by electrochemical measurements. It was possible to achieve thick, dense, and hard CGS coatings on Al7075-T6 and low-carbon steel substrates, with better or the same mechanical and electrochemical properties as those of the HVOF coatings; making the former a highly competitive method for producing WC-25Co coatings.

  5. Prediction of soot and thermal radiation in a model gas turbine combustor burning kerosene fuel spray at different swirl levels

    NASA Astrophysics Data System (ADS)

    Ghose, Prakash; Patra, Jitendra; Datta, Amitava; Mukhopadhyay, Achintya

    2016-05-01

    Combustion of kerosene fuel spray has been numerically simulated in a laboratory scale combustor geometry to predict soot and the effects of thermal radiation at different swirl levels of primary air flow. The two-phase motion in the combustor is simulated using an Eulerian-Lagragian formulation considering the stochastic separated flow model. The Favre-averaged governing equations are solved for the gas phase with the turbulent quantities simulated by realisable k-ɛ model. The injection of the fuel is considered through a pressure swirl atomiser and the combustion is simulated by a laminar flamelet model with detailed kinetics of kerosene combustion. Soot formation in the flame is predicted using an empirical model with the model parameters adjusted for kerosene fuel. Contributions of gas phase and soot towards thermal radiation have been considered to predict the incident heat flux on the combustor wall and fuel injector. Swirl in the primary flow significantly influences the flow and flame structures in the combustor. The stronger recirculation at high swirl draws more air into the flame region, reduces the flame length and peak flame temperature and also brings the soot laden zone closer to the inlet plane. As a result, the radiative heat flux on the peripheral wall decreases at high swirl and also shifts closer to the inlet plane. However, increased swirl increases the combustor wall temperature due to radial spreading of the flame. The high incident radiative heat flux and the high surface temperature make the fuel injector a critical item in the combustor. The injector peak temperature increases with the increase in swirl flow mainly because the flame is located closer to the inlet plane. On the other hand, a more uniform temperature distribution in the exhaust gas can be attained at the combustor exit at high swirl condition.

  6. Soil Evaporation

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Soil evaporation can significantly influence energy flux partitioning of partially vegetated surfaces, ultimately affecting plant transpiration. While important, quantification of soil evaporation, separately from canopy transpiration, is challenging. Techniques for measuring soil evaporation exis...

  7. Simultaneous imaging of fuel vapor mass fraction and gas-phase temperature inside gasoline sprays using two-line excitation tracer planar laser-induced fluorescence.

    PubMed

    Zigan, Lars; Trost, Johannes; Leipertz, Alfred

    2016-02-20

    This paper reports for the first time, to the best of our knowledge, on the simultaneous imaging of the gas-phase temperature and fuel vapor mass fraction distribution in a direct-injection spark-ignition (DISI) spray under engine-relevant conditions using tracer planar laser-induced fluorescence (TPLIF). For measurements in the spray, the fluorescence tracer 3-pentanone is added to the nonfluorescent surrogate fuel iso-octane, which is excited quasi-simultaneously by two different excimer lasers for two-line excitation LIF. The gas-phase temperature of the mixture of fuel vapor and surrounding gas and the fuel vapor mass fraction can be calculated from the two LIF signals. The measurements are conducted in a high-temperature, high-pressure injection chamber. The fluorescence calibration of the tracer was executed in a flow cell and extended significantly compared to the existing database. A detailed error analysis for both calibration and measurement is provided. Simultaneous single-shot gas-phase temperature and fuel vapor mass fraction fields are processed for the assessment of cyclic spray fluctuations. PMID:26906600

  8. Application of high velocity oxygen fuel flame (HVOF) spraying to fabrication of La0.8Sr0.2Ga0.8Mg0.2O3 electrolyte for solid oxide fuel cells

    NASA Astrophysics Data System (ADS)

    Zhang, Shan-Lin; Li, Cheng-Xin; Li, Chang-Jiu; Yang, Guan-Jun; Liu, Meilin

    2016-01-01

    La0.8Sr0.2Ga0.8Mg0.2O3 (LSGM) is considered a promising electrolyte for intermediate-temperature solid oxide fuel cells (IT-SOFCs) due to its high ionic conductivity and stability under fuel cell operating conditions. Here we report our findings in investigating the feasibility of using a high velocity oxygen fuel flame (HVOF) spraying process for cost-effective fabrication of dense LSGM electrolyte membranes. The flame and in-flight particle behavior were simulated numerically to optimize the microstructure and phase compositions of the LSGM deposits. The measured gas leakage rate of an LSGM deposit is ∼7 × 10-7 cm4gf-1 s-1. The single cell assembled with 50-55 μm HVOF-sprayed LSGM electrolyte shows open circuit voltage (OCV) of 1.08 V at 800 °C, suggesting that the as-sprayed LSGM deposit is dense enough for direct application as SOFC electrolyte. At 800 °C, the ionic conductivity of the sprayed LSGM deposit is ∼0.04 S cm-1, indicating that the HVOF spraying is a promising process for low-temperature fabrication of dense LSGM electrolyte membranes for IT-SOFCs.

  9. Spray momentum measuring system

    NASA Technical Reports Server (NTRS)

    Sheffield, E. W.

    1971-01-01

    Technique enables accurate prediction of erosion and cavitation produced by fluid spray. Method measures high velocity sprays produced by small orifices. Originally designed to determine oxidizer-injection patterns of liquid fueled rocket engines, technique is used with other liquids, or, with appropriate modification, with gases.

  10. Computational fluid dynamic modeling of gas flow characteristics in a high-velocity oxy-fuel thermal spray system

    NASA Astrophysics Data System (ADS)

    Gu, S.; Eastwick, C. N.; Simmons, K. A.; McCartney, D. G.

    2001-09-01

    A computational fluid dynamics (CFD) model is developed to predict gas dynamic behavior in a high-velocity oxy-fuel (HVOF) thermal spray gun in which premixed oxygen and propylene are burnt in a 12 mm combustion chamber linked to a parallel-sided nozzle. The CFD analysis is applied to investigate axisymmetric, steady-state, turbulent, compressible, and chemically combusting flow both within the gun and in a free jet region between the gun and the substrate to be coated. The combustion of oxygen and propylene is modeled using a single-step, finite-rate chemistry model that also allows for dissociation of the reaction products. Results are presented to show the effect of (1) fuel-to-oxygen gas ratio and (2) total gas flow rate on the gas dynamic behavior. Along the centerline, the maximum temperature reached is insensitive to the gas ratio but depends on the total flow. However, the value attained (˜2500 K) is significantly lower than the maximum temperature (˜3200 K) of the annular flame in the combustion chamber. By contrast, the centerline gas velocity depends on both total flow and gas ratio, the highest axial gas velocity being attained with the higher flow and most fuel-rich mixture. The gas Mach number increases through the gun and reaches a maximum value of approximately 1.6 around 5 mm downstream from the nozzle exit. The numerical calculations also show that the residual oxygen level is principally dependent on the fuel-to-oxygen ratio and decreases by approximately fivefold as the ratio is varied from 90 to 69% of the stoichiometric requirement. The CFD model is also used to investigate the effect of changes in combustion chamber size and geometry on gas dynamics, and the results are compared with the nominal 12 mm chamber baseline calculations.

  11. A Novel Hybrid Axial-Radial Atmospheric Plasma Spraying Technique for the Fabrication of Solid Oxide Fuel Cell Anodes Containing Cu, Co, Ni, and Samaria-Doped Ceria

    NASA Astrophysics Data System (ADS)

    Cuglietta, Mark; Kuhn, Joel; Kesler, Olivera

    2013-06-01

    Composite coatings containing Cu, Co, Ni, and samaria-doped ceria (SDC) have been fabricated using a novel hybrid atmospheric plasma spraying technique, in which a multi-component aqueous suspension of CuO, Co3O4, and NiO was injected axially simultaneously with SDC injected radially in a dry powder form. Coatings were characterized for their microstructure, permeability, porosity, and composition over a range of plasma spray conditions. Deposition efficiency of the metal oxides and SDC was also estimated. Depending on the conditions, coatings displayed either layering or high levels of mixing between the SDC and metal phases. The deposition efficiencies of both feedstock types were strongly dependent on the nozzle diameter. Plasma-sprayed metal-supported solid oxide fuel cells utilizing anodes fabricated with this technique demonstrated power densities at 0.7 V as high as 366 and 113 mW/cm2 in humidified hydrogen and methane, respectively, at 800 °C.

  12. Low platinum loading for high temperature proton exchange membrane fuel cell developed by ultrasonic spray coating technique

    NASA Astrophysics Data System (ADS)

    Su, Huaneng; Jao, Ting-Chu; Barron, Olivia; Pollet, Bruno G.; Pasupathi, Sivakumar

    2014-12-01

    This paper reports use of an ultrasonic-spray for producing low Pt loadings membrane electrode assemblies (MEAs) with the catalyst coated substrate (CCS) fabrication technique. The main MEA sub-components (catalyst, membrane and gas diffusion layer (GDL)) are supplied from commercial manufacturers. In this study, high temperature (HT) MEAs with phosphoric acid (PA)-doped poly(2,5-benzimidazole) (AB-PBI) membrane are fabricated and tested under 160 °C, hydrogen and air feed 100 and 250 cc min-1 and ambient pressure conditions. Four different Pt loadings (from 0.138 to 1.208 mg cm-2) are investigated in this study. The experiment data are determined by in-situ electrochemical methods such as polarization curve, electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV). The high Pt loading MEA exhibits higher performance at high voltage operating conditions but lower performances at peak power due to the poor mass transfer. The Pt loading 0.350 mg cm-2 GDE performs the peak power density and peak cathode mass power to 0.339 W cm-2 and 0.967 W mgPt-1, respectively. This work presents impressive cathode mass power and high fuel cell performance for high temperature proton exchange membrane fuel cells (HT-PEMFCs) with low Pt loadings.

  13. Numerical modeling of in-flight characteristics of inconel 625 particles during high-velocity oxy-fuel thermal spraying

    NASA Astrophysics Data System (ADS)

    Gu, S.; McCartney, D. G.; Eastwick, C. N.; Simmons, K.

    2004-06-01

    A computational fluid dynamics (CFD) model is developed to predict particle dynamic behavior in a high-velocity oxyfuel (HVOF) thermal spray gun in which premixed oxygen and propylene are burnt in a combustion chamber linked to a long, parallel-sided nozzle. The particle transport equations are solved in a Lagrangian manner and coupled with the two-dimensional, axisymmetric, steady state, chemically reacting, turbulent gas flow. Within the particle transport model, the total flow of the particle phase is modeled by tracking a small number of particles through the continuum gas flow, and each of these individual particles is tracked independently through the continuous phase. Three different combustion chamber designs were modeled, and the in-flight particle characteristics of Inconel were 625 studied. Results are presented to show the effect of process parameters, such as particle injection speed and location, total gas flow rate, fuel-to-oxygen gas ratio, and particle size on the particle dynamic behavior for a parallel-sided, 12 mm long combustion chamber. The results indicate that the momentum and heat transfer to particles are primarily influenced by total gas flow. The 12 mm long chamber can achieve an optimum performance for Inconel 625 powder particles ranging in diameter from 20 to 40 µm. At a particular spraying distance, an optimal size of particles is observed with respect to particle temperature. The effect of different combustion chamber dimensions on particle dynamics was also investigated. The results obtained for both a 22 mm long chamber and also one with a conical, converging design are compared with the baseline data for the 12 mm chamber.

  14. Microstructural Characterization and Wear Behavior of Nano-Boride Dispersed Coating on AISI 304 Stainless Steel by Hybrid High Velocity Oxy-Fuel Spraying Laser Surface Melting

    NASA Astrophysics Data System (ADS)

    Sharma, Prashant; Majumdar, Jyotsna Dutta

    2015-07-01

    The current study concerns the detailed microstructural characterization and investigation of wear behavior of nano-boride dispersed coating developed on AISI 304 stainless steel by high velocity oxy-fuel spray deposition of nickel-based alloy and subsequent laser melting. There is a significant refinement and homogenization of microstructure with improvement in microhardness due to laser surface melting (1200 VHN as compared to 945 VHN of as-sprayed and 250 VHN of as-received substrate). The high temperature phase stability of the as-coated and laser melted surface has been studied by differential scanning calorimeter followed by detailed phase analysis at room and elevated temperature. There is a significant improvement in wear resistance of laser melted surface as compared to as-sprayed and the as-received one due to increased hardness and reduced coefficient of friction. The mechanism of wear has been investigated in details. Corrosion resistance of the coating in a 3.56 wt pct NaCl solution is significantly improved (4.43 E-2 mm/year as compared to 5 E-1 mm/year of as-sprayed and 1.66 mm/year of as-received substrate) due to laser surface melting as compared to as-sprayed surface.

  15. Spray combustion at normal and reduced gravity in counterflow and co-flow configurations

    NASA Technical Reports Server (NTRS)

    Gomez, Alessandro; Chen, Gung

    1995-01-01

    Liquid fuel dispersion in practical systems is typically achieved by spraying the fuel into a polydisperse distribution of droplets evaporating and burning in a turbulent gaseous environment In view of the nearly insurmountable difficulties of this two-phase flow, a systematic study of spray evaporation and burning in configurations of gradually increasing levels of complexity, starting from laminar sprays to fully turbulent ones, would be useful. A few years ago we proposed to use an electrostatic spray of charged droplets for this type of combustion experiments under well-defined conditions. In the simplest configuration, a liquid is fed into a small metal tube maintained at several kilovolts relative to a ground electrode few centimeters away. Under the action of the electric field, the liquid meniscus at the outlet of the capillary takes a conical shape, with a thin jet emerging from the cone tip (cone-jet mode). This jet breaks up farther downstream into a spray of charged droplets - the so-called ElectroSpray (ES). Several advantages distinguish the electrospray from alternative atomization techniques: (1) it can produce quasi-monodisperse droplets over a phenomenal size range; (2) the atomization, that is strictly electrostatic, is decoupled from gas flow processes, which provides some flexibility in the selection and control of the experimental conditions; (3) the Coulombic repulsion of homopolarly charged droplets induces spray self-dispersion and prevents droplet coalescence; (4) the ES provides the opportunity of studying regimes of slip between droplets and host gas without compromising the control of the spray properties; and (5) the compactness and potential controllability of this spray generation system makes it appealing for studies in reduced-gravity environments aimed at isolating the spray behavior from natural convection complications. With these premises, in March 1991 we initiated a series of experiments under NASA sponsorship (NAG3-1259 and

  16. Probing the Evaporation Dynamics of Ethanol/Gasoline Biofuel Blends Using Single Droplet Manipulation Techniques.

    PubMed

    Corsetti, Stella; Miles, Rachael E H; McDonald, Craig; Belotti, Yuri; Reid, Jonathan P; Kiefer, Johannes; McGloin, David

    2015-12-24

    Using blends of bioethanol and gasoline as automotive fuel leads to a net decrease in the production of harmful emission compared to the use of pure fossil fuel. However, fuel droplet evaporation dynamics change depending on the mixing ratio. Here we use single particle manipulation techniques to study the evaporation dynamics of ethanol/gasoline blend microdroplets. The use of an electrodynamic balance enables measurements of the evaporation of individual droplets in a controlled environment, while optical tweezers facilitate studies of the behavior of droplets inside a spray. Hence, the combination of both methods is perfectly suited to obtain a complete picture of the evaporation process. The influence of adding varied amounts of ethanol to gasoline is investigated, and we observe that droplets with a greater fraction of ethanol take longer to evaporate. Furthermore, we find that our methods are sensitive enough to observe the presence of trace amounts of water in the droplets. A theoretical model, predicting the evaporation of ethanol and gasoline droplets in dry nitrogen gas, is used to explain the experimental results. Also a theoretical estimation of the saturation of the environment, with other aerosols, in the tweezers is carried out. PMID:26633739

  17. High-pressure flame visualization of autoignition and flashback phenomena with liquid-fuel spray

    NASA Technical Reports Server (NTRS)

    Marek, C. J.; Baker, C. E.

    1983-01-01

    A study was undertaken to determine the effect of boundary layers on autoignition and flashback for premixed Jet-A fuel in a unique high-pressure windowed test facility. A plate was placed in the center of the fuel-air stream to establish a boundary layer. Four experimental configurations were tested: a 24.5-cm-long plate with either a pointed leading edge, a rounded edge or an edge with a 0.317-cm step, or the duct without the plate. Experiments at an equivalence ratio ranging from 0.4 to 0.9 were performed at pressures to 2500 kPa (25 atm.) at temperatures of 600, 645, and 700 K and velocities to 115 meters per second. Flame shapes were observed during flashback and autoignition using high speed cinematography. Flashback and autoignition limits were determined.

  18. Synthesis of nanostructured WC-12 pct Co coating using mechanical milling and high velocity oxygen fuel thermal spraying

    SciTech Connect

    He, J. Ice, M.; Dallek, S.; Lavernia, E.J.

    2000-02-01

    A nanostructured WC-12 pct Co coating was synthesized using mechanical milling and high velocity oxygen fuel (HVOF) thermal spraying. The variation of powder characteristics with milling time and the performance of the coatings were investigated using scanning electron microscope (SEM), X-ray, transmission electron microscope (TEM), thermogravimetric analyzer (TGA), and microhardness measurements. There is no evidence that indicates the presence of an amorphous phase in the sintered WC-12 pct Co powder, and the binder phase in this powder is still crystalline Co. Mechanical milling of up to 20 hours did not lead to the formation of an amorphous phase in the sintered WC-12 pct Co powder. During the initial stages of the milling, the brittle carbide particles were first fractured into fragments and then embedded into the binder phase. This process gradually formed polycrystal nanocomposite powders of the Co binder phase and W carbide particles. The conventional cold welding and fracturing processes primarily occurred among the Co binder powders and polycrystal composite powders. The nanostructured WC-12 pct Co coatings, synthesized in the present study, consist of an amorphous matrix and carbides with an average particle diameter of 35 nm. The coating possesses an average microhardness of 1135 HV and higher resistance to indentation fracture than that of its conventional counterpart.

  19. Computational fluid dynamics analysis of a wire-feed, high-velocity oxygen-fuel (HVOF) thermal spray torch

    SciTech Connect

    Lopez, A.R.; Hassan, B.; Oberkampf, W.L.; Neiser, R.A.; Roemer, T.J.

    1996-09-01

    The fluid and particle dynamics of a High-Velocity Oxygen-Fuel Thermal Spray torch are analyzed using computational and experimental techniques. Three-dimensional Computational Fluid Dynamics (CFD) results are presented for a curved aircap used for coating interior surfaces such as engine cylinder bores. The device analyzed is similar to the Metco Diamond Jet Rotating Wire (DJRW) torch. The feed gases are injected through an axisymmetric nozzle into the curved aircap. Premixed propylene and oxygen are introduced from an annulus in the nozzle, while cooling air is injected between the nozzle and the interior wall of the aircap. The combustion process is modeled using a single-step finite-rate chemistry model with a total of 9 gas species which includes dissociation of combustion products. A continually-fed steel wire passes through the center of the nozzle and melting occurs at a conical tip near the exit of the aircap. Wire melting is simulated computationally by injecting liquid steel particles into the flow field near the tip of the wire. Experimental particle velocity measurements during wire feed were also taken using a Laser Two-Focus (L2F) velocimeter system. Flow fields inside and outside the aircap are presented and particle velocity predictions are compared with experimental measurements outside of the aircap.

  20. Vacuum Plasma Spray of CuCrNb Alloy for Advanced Liquid - Fuel Combustion Chambers

    NASA Technical Reports Server (NTRS)

    Zimmerman, Frank

    2000-01-01

    The copper-8 atomic percent chromium-4 atomic percent niobium (CuCrNb) alloy was developed by Glenn Research Center (formally Lewis Research Center) as an improved alloy for combustion chamber liners. In comparison to NARloy-Z, the baseline (as in Space Shuttle Main Engine) alloy for such liners, CuCrNb demonstrates mechanical and thermophysical properties equivalent to NARloy-Z, but at temperatures 100 C to 150 C (180 F to 270 F) higher. Anticipated materials related benefits include decreasing the thrust cell liner weight 5% to 20%, increasing the service life at least two fold over current combustion chamber design, and increasing the safety margins available to designers. By adding an oxidation and thermal barrier coating to the liner, the combustion chamber can operate at even higher temperatures. For all these benefits, however, this alloy cannot be formed using conventional casting and forging methods because of the levels of chromium and niobium, which exceed their solubility limit in copper. Until recently, the only forming process that maintains the required microstructure of CrNb intermetallics is powder metallurgy formation of a billet from powder stock, followed by extrusion. This severely limits its usefulness in structural applications, particularly the complex shapes required for combustion chamber liners. Vacuum plasma spray (VPS) has been demonstrated as a method to form structural articles including small combustion chambers from the CuCrNb alloy. In addition, an oxidation and thermal barrier layer can be formed integrally on the hot wall of the liner that improve performance and extend service life. This paper discusses the metallurgy and thermomechanical properties of VPS formed CuCrNb versus the baseline powder metallurgy process, and the manufacturing of small combustion chamber liners at Marshall Space Flight Center using the VPS process. The benefits to advanced propulsion initiatives of using VPS to fabricate combustion chamber liners

  1. Effect of elevated temperature and pressure on sprays from simplex swirl atomizers

    NASA Technical Reports Server (NTRS)

    Dodge, L. G.; Biaglow, J. A.

    1986-01-01

    An examination is made of the effects of air temperature and pressure on the spray quality of a moderately high capacity pressure swirl atomizer spraying jet-A and No. 2 diesel fuel. Drop size distributions, in terms of both Sauter mean diameter (SMD) and the width of the distribution given by the Rosin-Rammler N parameter, are determined over a variety of air conditions. Close to the nozzle, limited data suggest that the SMDs were a strong function of air density, but independent of air temperature. Trends of SMD and N are shown as a function of distance from the nozzle at all conditions, indicating some of the evaporation characteristics of fuel sprays.

  2. Effect of nano-crystallization of high velocity oxy-fuel-sprayed amorphous NiCrBSi alloy on properties of the coatings

    NASA Astrophysics Data System (ADS)

    Li, Chang-Jiu; Wang, Yu-Yue; Li, Hua

    2004-09-01

    NiCrBSi self-fluxing alloy coatings were deposited by high velocity oxy-fuel (HVOF) spraying. Annealing treatment was applied to the as-sprayed coatings to develop the microstructure of the Ni-based coating. The microstructure of the coating was characterized using optical microscopy, x-ray diffraction and transmission electron microscopy. The crystallization behavior of the amorphous coating was also characterized by differential scanning calorimetry. The properties of the coating were characterized by microhardness and abrasive wear tests. The results showed that the as-sprayed HVOF coating deposited by well melted spray particles exhibited a dense microstructure of amorphous phase. It was revealed that the crystallization of the amorphous phase in HVOF NiCrBSi coating occurs at a temperature of about 502°C. Annealing at temperature a little higher than recrystallization temperature leads to the formation of the nano-crystalline microstructure. The subsequent nanostructured Ni-based coating presents higher microhardness and excellent wear performance. With the further increase in annealing temperature, the growth of the nano-crystalline grains occurs and, accordingly, the microhardness of the coating and the wear performance decrease. Thereafter, the microstructure and properties of the Ni-based self-fluxing alloy coating can be controlled through postannealing treatment.

  3. Experimental Investigation of Droplet Evaporation of Water with Ground Admixtures while Motion in a Flame of Liquid Fuel

    NASA Astrophysics Data System (ADS)

    Dmitriyenko, Margarita A.; Nyashina, Galina S.; Zhdanova, Alena O.; Vysokomornaya, Olga V.

    2016-02-01

    The evaporation features for the atomized flow of suspension on the base of water with ground admixtures in an area of high-temperature combustion products of liquid flammable substance (acetone) were investigated experimentally by the optical methods of gas flow diagnostic and the high-speed video recording. The scales of influence of clay and silt concentration in droplets of atomized flow on the intensity of its evaporation were determined. The approximation dependences describing a decrease in typical size of suspension droplets at various values of ground admixtures were obtained.

  4. A single step solution combustion approach for preparing gadolinia doped ceria solid oxide fuel cell electrolyte material suitable for wet powder and plasma spraying processes

    NASA Astrophysics Data System (ADS)

    Shri Prakash, B.; William Grips, V. K.; Aruna, S. T.

    2012-09-01

    The present study explores the versatility of solution combustion method for preparing powders of varying characteristics suitable for intermediate temperature solid oxide fuel cell (IT-SOFC) fabrication. The promising electrolyte material for IT-SOFC, Gd0.2Ce0.8O2-δ (GDC), is considered for the present investigation. GDC powders consisting of sub-micron sized particles (<250 nm) and micron sized (>20 μm) particles are produced by varying the fuel used in the combustion reaction. Highly sinteractive nano-GDC powders prepared using oxalyl dihydrazide as a fuel results in dense pellets with high conductivity (3 × 10-4 Scm-1 at 400 °C). This powder also results in a stable suspension suitable for wet powder spraying and electrophoretic deposition. Powders with larger particle size (>20 μm) prepared by solution combustion method using mixture of fuels, exhibits necessary flowability for atmospheric plasma spraying (APS). GDC coatings fabricated by APS using flowable powders are dense with superior adhesion between the splats. Good adhesion between the splats in the APS coatings is attributed to the higher level of melting of the combustion synthesized particles in the plasma flame owing to their low specific mass.

  5. On the Oscillation of Combustion of a Laminar Spray

    NASA Technical Reports Server (NTRS)

    Levy, Yeshayahou; Bulzan, Daniel L.

    1995-01-01

    A spray combustor, with flow velocities in the laminar range, exhibits a unique operating mode where large amplitude, self-induced oscillations of the flame shape occur. The phenomenon, not previously encountered, only occurs when fuel is supplied in the form of fine liquid droplets and does not occur when fuel is supplied in gaseous form. Several flow mechanisms are coupled in such a fashion as to trigger and maintain the oscillatory motion of the flame. These mechanisms include heat transfer and evaporation processes, dynamics of two-phase flows, and effects of gravity (buoyancy forces). An interface volume, lying between the fuel nozzle and the flame was found to be the most susceptible to gravity effects, and postulated to be responsible for inducing the oscillatory motion. Heptane fuel was used in the majority of the tests.

  6. Friction and wear properties of high-velocity oxygen fuel sprayed WC-17Co coating under rotational fretting conditions

    NASA Astrophysics Data System (ADS)

    Luo, Jun; Cai, Zhenbing; Mo, Jiliang; Peng, Jinfang; Zhu, Minhao

    2016-05-01

    Rotational fretting which exist in many engineering applications has incurred enormous economic loss. Thus, accessible methods are urgently needed to alleviate or eliminate damage by rotational fretting. Surface engineering is an effective approach that is successfully adopted to enhance the ability of components to resist the fretting damage. In this paper, using a high-velocity oxygen fuel sprayed (HVOF) technique WC-17Co coating is deposited on an LZ50 steel surface to study its properties through Vickers hardness testing, scanning electric microscope (SEM), energy dispersive X-ray spectroscopy (EDX), and X-ray diffractrometry (XRD). Rotational fretting wear tests are conducted under normal load varied from 10 N to 50 N, and angular displacement amplitudes vary from 0.125° to 1°. Wear scars are examined using SEM, EDX, optical microscopy (OM), and surface topography. The experimental results reveal that the WC-17Co coating adjusted the boundary between the partial slip regime (PSR) and the slip regime (SR) to the direction of smaller amplitude displacement. As a result, the coefficients of friction are consistently lower than the substrate's coefficients of friction both in the PSR and SR. The damage to the coating in the PSR is very slight. In the SR, the coating exhibits higher debris removal efficiency and load-carrying capacity. The bulge is not found for the coating due to the coating's higher hardness to restrain plastic flow. This research could provide experimental bases for promoting industrial application of WC-17Co coating in prevention of rotational fretting wear.

  7. Friction and wear properties of high-velocity oxygen fuel sprayed WC-17Co coating under rotational fretting conditions

    NASA Astrophysics Data System (ADS)

    Luo, Jun; Cai, Zhenbing; Mo, Jiliang; Peng, Jinfang; Zhu, Minhao

    2016-04-01

    Rotational fretting which exist in many engineering applications has incurred enormous economic loss. Thus, accessible methods are urgently needed to alleviate or eliminate damage by rotational fretting. Surface engineering is an effective approach that is successfully adopted to enhance the ability of components to resist the fretting damage. In this paper, using a high-velocity oxygen fuel sprayed (HVOF) technique WC-17Co coating is deposited on an LZ50 steel surface to study its properties through Vickers hardness testing, scanning electric microscope (SEM), energy dispersive X-ray spectroscopy (EDX), and X-ray diffractrometry (XRD). Rotational fretting wear tests are conducted under normal load varied from 10 N to 50 N, and angular displacement amplitudes vary from 0.125° to 1°. Wear scars are examined using SEM, EDX, optical microscopy (OM), and surface topography. The experimental results reveal that the WC-17Co coating adjusted the boundary between the partial slip regime (PSR) and the slip regime (SR) to the direction of smaller amplitude displacement. As a result, the coefficients of friction are consistently lower than the substrate's coefficients of friction both in the PSR and SR. The damage to the coating in the PSR is very slight. In the SR, the coating exhibits higher debris removal efficiency and load-carrying capacity. The bulge is not found for the coating due to the coating's higher hardness to restrain plastic flow. This research could provide experimental bases for promoting industrial application of WC-17Co coating in prevention of rotational fretting wear.

  8. Spray Diagnostics in Rocket Engines Using Phase Doppler Analyzer

    NASA Technical Reports Server (NTRS)

    Isaac, Kakkattukuzhy M.

    1996-01-01

    Characteristics such as drop velocity, drop size, number density, volume flow rate, volume flux, and evaporation rate of the fuel spray in a rocket engine are directly related to engine performance. Several studies of shear coaxial atomization have been done in the past. However, additional work related to sprays at supercritical and transcritical conditions would be useful. The author undertook a study of the feasibility of using a phase Doppler particle analyzer (PDPA) for spray measurements in rocket engines as a part of the Summer Faculty Fellowship Program at the NASA Marshall Space Flight Center. The PDPA is a single particle counter (SPC) system based on light scattering from spherical particles. The PDPA instrument is based on refractive and reflective scattering as opposed to other instruments based on diffractive scattering. The main advantage of the PDPA instrument is its ability to provide point-wise information. The following sections describe the principle of operation of the PDPA system and the data obtained using a PDPA instrument in a spray formed by a commercially available fuel injection nozzle.

  9. Portable Spray Booth

    NASA Technical Reports Server (NTRS)

    Hansen, Timothy D.; Bardwell, Micheal J.

    1996-01-01

    Portable spray booth provides for controlled application of coating materials with high solvent contents. Includes contoured shroud and carbon filter bed limiting concentration of fumes in vicinity. Designed to substitute spraying for brush application of solvent-based adhesive prior to installing rubber waterproof seals over joints between segments of solid-fuel rocket motor. With minor adjustments and modifications, used to apply other solvent-based adhesives, paints, and like.

  10. Sprayed coatings

    NASA Astrophysics Data System (ADS)

    Steffens, H. D.

    1980-03-01

    Thermal spraying is shown to be an efficient means for the protection of surface areas against elevated temperature, wear, corrosion, hot gas corrosion, and erosion in structural aircraft components. Particularly in jet engines, numerous parts are coated by flame, detonation, or plasma spraying techniques. The applied methods of flame, detonation, and plasma spraying are explained, as well as electric arc spraying. Possibilities for spray coatings which meet aircraft service requirements are discussed, as well as methods for quality control, especially nondestructive test methods. In particular, coating characteristics and properties obtained by different spray methods are described, and special attention is paid to low pressure plasma spraying.

  11. Model of Mixing Layer With Multicomponent Evaporating Drops

    NASA Technical Reports Server (NTRS)

    Bellan, Josette; Le Clercq, Patrick

    2004-01-01

    A mathematical model of a three-dimensional mixing layer laden with evaporating fuel drops composed of many chemical species has been derived. The study is motivated by the fact that typical real petroleum fuels contain hundreds of chemical species. Previously, for the sake of computational efficiency, spray studies were performed using either models based on a single representative species or models based on surrogate fuels of at most 15 species. The present multicomponent model makes it possible to perform more realistic simulations by accounting for hundreds of chemical species in a computationally efficient manner. The model is used to perform Direct Numerical Simulations in continuing studies directed toward understanding the behavior of liquid petroleum fuel sprays. The model includes governing equations formulated in an Eulerian and a Lagrangian reference frame for the gas and the drops, respectively. This representation is consistent with the expected volumetrically small loading of the drops in gas (of the order of 10 3), although the mass loading can be substantial because of the high ratio (of the order of 103) between the densities of liquid and gas. The drops are treated as point sources of mass, momentum, and energy; this representation is consistent with the drop size being smaller than the Kolmogorov scale. Unsteady drag, added-mass effects, Basset history forces, and collisions between the drops are neglected, and the gas is assumed calorically perfect. The model incorporates the concept of continuous thermodynamics, according to which the chemical composition of a fuel is described probabilistically, by use of a distribution function. Distribution functions generally depend on many parameters. However, for mixtures of homologous species, the distribution can be approximated with acceptable accuracy as a sole function of the molecular weight. The mixing layer is initially laden with drops in its lower stream, and the drops are colder than the gas

  12. Fundamental studies of spray combustion

    SciTech Connect

    Li, S.C.; Libby, P.A.; Williams, F.A.

    1997-12-31

    Our research on spray combustion involves both experiment and theory and addresses the characteristics of individual droplets and of sprays in a variety of flows: laminar and turbulent, opposed and impinging. Currently our focus concerns water and fuel sprays in two stage laminar flames, i.e., flames arising, for example from a stream of fuel and oxidizer flowing opposite to an air stream carrying a water spray. Our interest in these flames is motivated by the goals of reducing pollutant emissions and extending the range of stable spray combustion. There remains considerable research to be carried out in order to achieve these goals. Thus far our research on the characteristics of sprays in turbulent flows has been limited to nonreacting jets impinging on a plate but this work will be extended to opposed flows with and without a flame. In the following we discuss details of these studies and our plans for future work.

  13. Acoustic effects of sprays

    NASA Technical Reports Server (NTRS)

    Pindera, Maciej Z.; Przekwas, Andrzej J.

    1994-01-01

    Since the early 1960's, it has been known that realistic combustion models for liquid fuel rocket engines should contain at least a rudimentary treatment of atomization and spray physics. This is of particular importance in transient operations. It has long been recognized that spray characteristics and droplet vaporization physics play a fundamental role in determining the stability behavior of liquid fuel rocket motors. This paper gives an overview of work in progress on design of a numerical algorithm for practical studies of combustion instabilities in liquid rocket motors. For flexibility, the algorithm is composed of semi-independent solution modules, accounting for different physical processes. Current findings are report and future work is indicated. The main emphasis of this research is the development of an efficient treatment to interactions between acoustic fields and liquid fuel/oxidizer sprays.

  14. 40 CFR 1045.25 - How do the requirements related to evaporative emissions apply to engines and their fuel systems?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... of conformity issued under 40 CFR part 1060. (c) Fuel lines intended to be used with new engines and new portable marine fuel tanks must be certified to the applicable requirements of 40 CFR part 1060... of 40 CFR part 1060. (d) All persons installing engines certified under this part 1045 must...

  15. 40 CFR 1045.25 - How do the requirements related to evaporative emissions apply to engines and their fuel systems?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... of conformity issued under 40 CFR part 1060. (c) Fuel lines intended to be used with new engines and new portable marine fuel tanks must be certified to the applicable requirements of 40 CFR part 1060... of 40 CFR part 1060. (d) All persons installing engines certified under this part 1045 must...

  16. 40 CFR 1045.25 - How do the requirements related to evaporative emissions apply to engines and their fuel systems?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... of conformity issued under 40 CFR part 1060. (c) Fuel lines intended to be used with new engines and new portable marine fuel tanks must be certified to the applicable requirements of 40 CFR part 1060... of 40 CFR part 1060. (d) All persons installing engines certified under this part 1045 must...

  17. Electrostatic Dispersion and Evaporation of Dense and Dilute Clusters of Drops of High-Energy Fuel For Soot Control

    NASA Technical Reports Server (NTRS)

    Bellan, J.; Harstad, K.

    1997-01-01

    The high-energy-density (HED) fuels developed under U.S. Navy sponsorship as a replacement for conventional liquid fuels, in its missile propulsion systems have the drawback of high soot propensity: this makes misiles visible and thus strategically unacceptabel.

  18. 40 CFR 1045.25 - How do the requirements related to evaporative emissions apply to engines and their fuel systems?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... of conformity issued under 40 CFR part 1060. (c) Fuel lines intended to be used with new engines and new portable marine fuel tanks must be certified to the applicable requirements of 40 CFR part 1060... of 40 CFR part 1060. (d) All persons installing engines certified under this part 1045 must...

  19. 40 CFR 1045.25 - How do the requirements related to evaporative emissions apply to engines and their fuel systems?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... of conformity issued under 40 CFR part 1060. (c) Fuel lines intended to be used with new engines and new portable marine fuel tanks must be certified to the applicable requirements of 40 CFR part 1060... of 40 CFR part 1060. (d) All persons installing engines certified under this part 1045 must...

  20. Spray-on polyvinyl alcohol separators and impact on power production in air-cathode microbial fuel cells with different solution conductivities.

    PubMed

    Hoskins, Daniel L; Zhang, Xiaoyuan; Hickner, Michael A; Logan, Bruce E

    2014-11-01

    Separators are used to protect cathodes from biofouling and to avoid electrode short-circuiting, but they can adversely affect microbial fuel cell (MFC) performance. A spray method was used to apply a polyvinyl alcohol (PVA) separator to the cathode. Power densities were unaffected by the PVA separator (339±29mW/m(2)), compared to a control lacking a separator in a low conductivity solution (1mS/cm) similar to wastewater. Power was reduced with separators in solutions typical of laboratory tests (7-13mS/cm), compared to separatorless controls. The PVA separator produced more power in a separator assembly (SEA) configuration (444±8mW/m(2)) in the 1mS/cm solution, but power was reduced if a PVA or wipe separator was used in higher conductivity solutions with either Pt or activated carbon catalysts. Spray and cast PVA separators performed similarly, but the spray method is preferred as it was easier to apply and use. PMID:25260178

  1. Plasma sprayed ceria-containing interlayer

    DOEpatents

    Schmidt, Douglas S.; Folser, George R.

    2006-01-10

    A plasma sprayed ceria-containing interlayer is provided. The interlayer has particular application in connection with a solid oxide fuel cell used within a power generation system. The fuel cell advantageously comprises an air electrode, a plasma sprayed interlayer disposed on at least a portion of the air electrode, a plasma sprayed electrolyte disposed on at least a portion of the interlayer, and a fuel electrode applied on at least a portion of the electrolyte.

  2. Spray combustion model improvement study, 1

    NASA Technical Reports Server (NTRS)

    Chen, C. P.; Kim, Y. M.; Shang, H. M.

    1993-01-01

    This study involves the development of numerical and physical modeling in spray combustion. These modeling efforts are mainly motivated to improve the physical submodels of turbulence, combustion, atomization, dense spray effects, and group vaporization. The present mathematical formulation can be easily implemented in any time-marching multiple pressure correction methodologies such as MAST code. A sequence of validation cases includes the nonevaporating, evaporating and_burnin dense_sprays.

  3. Effects of turbulence mixing, variable properties, and vaporization on spray droplet combustion

    NASA Technical Reports Server (NTRS)

    Kim, Y. M.; Chung, T. J.

    1990-01-01

    Combustion of liquid fuels in the form of spray droplets is simulated numerically. Various vaporization models are examined as to their performance in finite element calculations involving a turbulent flow field. The Eulerian coordinate for the gas and Lagrangian coordinate for the liquid spray droplets are coupled through source terms being updated in the equations of continuity, momentum, and energy. The k-epsilon and modified eddy breakup models are used for simulating turbulent spray combustion flow field. Numerical results for the droplet trajectories, droplet heating, recirculation characteristics, and effects of evaporation models are evaluated. It is also shown that the finite element method is advantageous in dealing with complex geometries, complex boundary conditions, adaptive unstructured grids.

  4. Fe-Al Weld Overlay and High Velocity Oxy-Fuel Thermal Spray Coatings for Corrosion Protection of Waterwalls in Fossil Fired Plants with Low NOx Burners

    SciTech Connect

    Regina, J.R.

    2002-02-08

    Iron-aluminum-chromium coatings were investigated to determine the best candidates for coatings of boiler tubes in Low NOx fossil fueled power plants. Ten iron-aluminum-chromium weld claddings with aluminum concentrations up to 10wt% were tested in a variety of environments to evaluate their high temperature corrosion resistance. The weld overlay claddings also contained titanium additions to investigate any beneficial effects from these ternary and quaternary alloying additions. Several High-Velocity Oxy-Fuel (HVOF) thermal spray coatings with higher aluminum concentrations were investigated as well. Gaseous corrosion testing revealed that at least 10wt%Al is required for protection in the range of environments examined. Chromium additions were beneficial in all of the environments, but additions of titanium were beneficial only in sulfur rich atmospheres. Similar results were observed when weld claddings were in contact with corrosive slag while simultaneously, exposed to the corrosive environments. An aluminum concentration of 10wt% was required to prevent large amounts of corrosion to take place. Again chromium additions were beneficial with the greatest corrosion protection occurring for welds containing both 10wt%Al and 5wt%Cr. The exposed thermal spray coatings showed either significant cracking within the coating, considerable thickness loss, or corrosion products at the coating substrate interface. Therefore, the thermal spray coatings provided the substrate very little protection. Overall, it was concluded that of the coatings studied weld overlay coatings provide superior protection in these Low NOx environments; specifically, the ternary weld composition of 10wt%Al and 5wt%Cr provided the best corrosion protection in all of the environments tested.

  5. Experimental evaluation of a breadboard heat and product-water removal system for a space-power fuel cell designed with static water removal and evaporative cooling

    NASA Technical Reports Server (NTRS)

    Hagedorn, N. H.; Prokipius, P. R.

    1977-01-01

    A test program was conducted to evaluate the design of a heat and product-water removal system to be used with fuel cell having static water removal and evaporative cooling. The program, which was conducted on a breadboard version of the system, provided a general assessment of the design in terms of operational integrity and transient stability. This assessment showed that, on the whole, the concept appears to be inherently sound but that in refining this design, several facets will require additional study. These involve interactions between pressure regulators in the pumping loop that occur when they are not correctly matched and the question of whether an ejector is necessary in the system.

  6. Effect of fuel rate and annealing process of LiFePO{sub 4} cathode material for Li-ion batteries synthesized by flame spray pyrolysis method

    SciTech Connect

    Halim, Abdul; Setyawan, Heru; Machmudah, Siti; Nurtono, Tantular; Winardi, Sugeng

    2014-02-24

    In this study the effect of fuel rate and annealing on particle formation of LiFePO{sub 4} as battery cathode using flame spray pyrolysis method was investigated numerically and experimentally. Numerical study was done using ANSYS FLUENT program. In experimentally, LiFePO{sub 4} was synthesized from inorganic aqueous solution followed by annealing. LPG was used as fuel and air was used as oxidizer and carrier gas. Annealing process attempted in inert atmosphere at 700°C for 240 min. Numerical result showed that the increase of fuel rate caused the increase of flame temperature. Microscopic observation using Scanning Electron Microscopy (SEM) revealed that all particles have sphere and polydisperse. Increasing fuel rate caused decreasing particle size and increasing particles crystallinity. This phenomenon attributed to the flame temperature. However, all produced particles still have more amorphous phase. Therefore, annealing needed to increase particles crystallinity. Fourier Transform Infrared (FTIR) analysis showed that all particles have PO4 function group. Increasing fuel rate led to the increase of infrared spectrum absorption corresponding to the increase of particles crystallinity. This result indicated that phosphate group vibrated easily in crystalline phase. From Electrochemical Impedance Spectroscopy (EIS) analysis, annealing can cause the increase of Li{sup +} diffusivity. The diffusivity coefficient of without and with annealing particles were 6.84399×10{sup −10} and 8.59888×10{sup −10} cm{sup 2} s{sup −1}, respectively.

  7. Antistatic sprays

    NASA Technical Reports Server (NTRS)

    Ming, James E.

    1989-01-01

    Antistatic sprays from several different manufacturers are examined. The sprays are examined for contamination potential (i.e., outgassing and nonvolatile residue), corrosiveness on an aluminum mirror surface, and electrostatic effectiveness. In addition, the chemical composition of the antistatic sprays is determined by infrared spectrophotometry, mass spectrometry, and ultraviolet spectrophotometry. The results show that 12 of the 17 antistatic sprays examined have a low contamination potential. Of these sprays, 7 are also noncorrosive to an aluminum surface. And of these, only 2 demonstrate good electrostatic properties with respect to reducing voltage accumulation; these sprays did not show a fast voltage dissipation rate however. The results indicate that antistatic sprays can be used on a limited basis where contamination potential, corrosiveness, and electrostatic effectiveness is not critical. Each application is different and proper evaluation of the situation is necessary. Information on some of the properties of some antistatic sprays is presented in this document to aid in the evaluation process.

  8. Hot air drum evaporator. [Patent application

    DOEpatents

    Black, R.L.

    1980-11-12

    An evaporation system for aqueous radioactive waste uses standard 30 and 55 gallon drums. Waste solutions form cascading water sprays as they pass over a number of trays arranged in a vertical stack within a drum. Hot dry air is circulated radially of the drum through the water sprays thereby removing water vapor. The system is encased in concrete to prevent exposure to radioactivity. The use of standard 30 and 55 gallon drums permits an inexpensive compact modular design that is readily disposable, thus eliminating maintenance and radiation build-up problems encountered with conventional evaporation systems.

  9. High Power Diode Laser-Treated HP-HVOF and Twin Wire Arc-Sprayed Coatings for Fossil Fuel Power Plants

    NASA Astrophysics Data System (ADS)

    Mann, B. S.

    2013-08-01

    This article deals with high power diode laser (HPDL) surface modification of twin wire arc-sprayed (TWAS) and high pressure high velocity oxy-fuel (HP-HVOF) coatings to combat solid particle erosion occurring in fossil fuel power plants. To overcome solid particle impact wear above 673 K, Cr3C2-NiCr-, Cr3C2-CoNiCrAlY-, and WC-CrC-Ni-based HVOF coatings are used. WC-CoCr-based HVOF coatings are generally used below 673 K. Twin wire arc (TWA) spraying of Tafa 140 MXC and SHS 7170 cored wires is used for a wide range of applications for a temperature up to 1073 K. Laser surface modification of high chromium stainless steels for steam valve components and LPST blades is carried out regularly. TWA spraying using SHS 7170 cored wire, HP-HVOF coating using WC-CoCr powder, Ti6Al4V alloy, and high chromium stainless steels (X20Cr13, AISI 410, X10CrNiMoV1222, 13Cr4Ni, 17Cr4Ni) were selected in the present study. Using robotically controlled parameters, HPDL surface treatments of TWAS-coated high strength X10CrNiMoV1222 stainless steel and HP-HVOF-coated AISI 410 stainless steel samples were carried out and these were compared with HPDL-treated high chromium stainless steels and titanium alloy for high energy particle impact wear (HEPIW) resistance. The HPDL surface treatment of the coatings has improved the HEPIW resistance manifold. The improvement in HPDL-treated stainless steels and titanium alloys is marginal and it is not comparable with that of HPDL-treated coatings. These coatings were also compared with "as-sprayed" coatings for fracture toughness, microhardness, microstructure, and phase analyses. The HEPIW resistance has a strong relationship with the product of fracture toughness and microhardness of the HPDL-treated HP-HVOF and TWAS SHS 7170 coatings. This development opens up a possibility of using HPDL surface treatments in specialized areas where the problem of HEPIW is very severe. The HEPIW resistance of HPDL-treated high chromium stainless steels and

  10. Water spray ejector system for steam injected engine

    SciTech Connect

    Hines, W.R.

    1991-10-08

    This paper describes a method of increasing the power output of a steam injected gas turbine engine. It comprises: a compressor, a combustor having a dome which receives fuel and steam from a dual flow nozzle, and a turbine in series combination with a gas flow path passing therethrough, and a system for injection of superheated steam into the gas flow path, the method comprising spraying water into the steam injection system where the water is evaporated by the superheated steam, mixing the evaporated water with the existing steam in the steam injection system so that the resultant steam is at a temperature of at least 28 degrees celsius (50 degrees fahrenheit) superheat and additional steam is added to the dome from the fuel nozzle to obtain a resultant increased mass flow of superheated steam mixture for injection into the gas flow path, and controlling the amount of water sprayed into the steam injection system to maximize the mass flow of superheated steam without quenching the flame.

  11. Mechanisms of spray formation and combustion from a multi-hole injector with E85 and gasoline

    SciTech Connect

    Aleiferis, P.G.; Serras-Pereira, J.; van Romunde, Z.; Caine, J.; Wirth, M.

    2010-04-15

    The spray formation and combustion characteristics of gasoline and E85 (85% ethanol, 15% gasoline) have been investigated using a multi-hole injector with asymmetric nozzle-hole arrangement. Experiments were carried out in a quiescent optical chamber using high-speed shadowgraphy (9 kHz) to characterise the spray sensitivity to both injector temperature and ambient pressure in the range of 20-120 C and 0.5, 1.0 bar. Spray-tip penetrations and 'umbrella' spray cone angles were calculated for all conditions. Phase Doppler Anemometry was also used to measure droplet sizes in the core of one of the spray plumes, 25 mm below the injector tip. To study the effect of fuel properties on vaporisation and mixture preparation under realistic operating conditions, a separate set of experiments was carried out in a direct-injection spark-ignition optical engine. The engine was run at 1500 RPM under cold and fully warmed-up conditions (20 C and 90 C) at part load and full load (0.5 and 1.0 bar intake pressure). Floodlit laser Mie-scattering images of the sprays on two orthogonal planes corresponding to the swirl and tumble planes of in-cylinder flow motion were acquired to study the full injection event and post-injection mixing stage. These were used to make comparisons with the static chamber sprays and to quantify the liquid-to-vapour phase evaporation process for both fuels by calculating the projected 'footprint' of the sprays at different conditions. Analysis of the macroscopic structure and turbulent primary break-up properties of the sprays was undertaken in light of jet exit conditions described in terms of non-dimensional numbers. The effects on stoichiometric combustion were investigated by imaging the natural flame chemiluminescence through the engine's piston crown (swirl plane) and by post-processing to derive flame growth rates and trajectories of flame motion. (author)

  12. Investigation of particulate formation during diesel spray combustion

    SciTech Connect

    Not Available

    1989-01-01

    The objective of the contract is to conduct an experimental and analytical research program to investigate strategies for using coherent anti-Stokes Raman scattering (CARS) laser diagnostic techniques for detecting the degree of fuel pyrolysis and determining fuel-air ratio. Smoke and NO{sub x} production rates depend in a complex way on the local temperature, the evaporation of the diesel spray, the local fuel-air ratio, and the pyrolysis history of fuels. Furthering the ability of CARS to provide more of this information may give engine designers more insight into the combustion process and allow them to create engines which produce fewer particulates or lower amounts of NO{sub x}. Controlling the production rates is preferable to processing emissions. If they cannot be suppressed simultaneously, adjusting the tradeoff between producing particulates or NO{sub x} may be helpful if an exhaust processing method is available for one of them. During the present quarter CARS results have been obtained in the reference/calibration cell with toluene vapor. These CARS results appear very favorable for use of toluene in 1 atm spray chamber studies as a room temperature saturated vapor mixture with CO{sub x} and N{sub 2}. The results indicate that toluene is likely a better candidate than hexane for droplet effects studies. Strong toluene CH stretch resonant CARS peaks have been found and three useful resonant CARS spectral features have been found near CO{sub 2} CARS.

  13. Influence of Heat Treatment on Corrosion Resistance of High-Velocity Oxygen-Fuel Sprayed WC-17Co Coatings on 42CrMo Steel

    NASA Astrophysics Data System (ADS)

    Sun, Wan-chang; Zhang, Pei; Zhang, Feng; Dong, Chu-xu; Zhang, Ju-mei; Cai, Hui

    2015-09-01

    The influence of heat treatment from 500 to 1100 °C on the 5 wt.% H2SO4 solution-induced corrosion resistance of high-velocity oxygen-fuel sprayed WC-17Co coatings on 42CrMo steel was investigated, by using x-ray diffractometer (XRD), scanning electron microscopy (SEM)-energy-dispersive spectrometer (EDS), and polarization curve methods. XRD analysis showed decrease in W2C phase intensity with recrystallization of amorphous Co and generation of new Co3W3C and Co6W6C phases with heat treatment. Porosity distribution did not follow a particular pattern; it initially increased and then decreased with increasing temperature. Corrosion resistance sequence of the as-sprayed and heat-treated coatings in 5 wt.% H2SO4 solution was C-5 > C-9 > C-A > C-7 > C-11. Furthermore, microstructure and phase structure of heat-treated coatings revealed the formation of different discontinuous plate-like oxide films on the surface of the heat-treated coatings which indicated the vital effect of binder structure on the corrosion resistance.

  14. Effect of Particle and Injection Parameters on the Performance of a Dual-Stage High-Velocity Oxygen Fuel Thermal Spray System

    NASA Astrophysics Data System (ADS)

    Khan, Mohammed N.; Shamim, Tariq

    2015-06-01

    For temperature-sensitive material (such as titanium) coatings, recently developed high-velocity oxygen fuel dual-stage thermal spray systems offer better control of particle oxidation and production of various coating structures. These advantages of the dual-stage thermal system are significantly influenced by the state of the coating particles being injected. Hence, the objective of the present study is to investigate the effects of particle size, shape, injection velocity, and injection angle on a dual-stage thermal spray system by employing a comprehensive mathematical model. The results demonstrate that the particle size, shape, injection velocity, and injection angle affect the particle velocity and temperature, which in turn may affect the coating quality. The results show that smaller particles have higher temperatures and velocities owing to decrease in particle thermal and mass inertia. Spherical particles have higher temperature and lower velocity than the non-spherical particles because of lower drag. The particle velocity and temperature also increase with the increase of the injection velocity. Similarly, the particles injection angle also plays an important role. Higher particle temperatures and velocities outside of the barrel are obtained if the particles are injected at oblique angles to the main gaseous flow.

  15. Chemical compatibility and properties of suspension plasma-sprayed SrTiO3-based anodes for intermediate-temperature solid oxide fuel cells

    NASA Astrophysics Data System (ADS)

    Zhang, Shan-Lin; Li, Cheng-Xin; Li, Chang-Jiu

    2014-10-01

    La-doped strontium titanate (LST) is a promising, redox-stable perovskite material for direct hydrocarbon oxidation anodes in intermediate-temperature solid oxide fuel cells (IT-SOFCs). In this study, nano-sized LST and Sm-doped ceria (SDC) powders are produced by the sol-gel and glycine-nitrate processes, respectively. The chemical compatibility between LST and electrolyte materials is studied. A LST-SDC composite anode is prepared by suspension plasma spraying (SPS). The effects of annealing conditions on the phase structure, microstructure, and chemical stability of the LST-SDC composite anode are investigated. The results indicate that the suspension plasma-sprayed LST-SDC anode has the same phase structure as the original powders. LST exhibits a good chemical compatibility with SDC and Mg/Sr-doped lanthanum gallate (LSGM). The anode has a porosity of ∼40% with a finely porous structure that provides high gas permeability and a long three-phase boundary for the anode reaction. Single cells assembled with the LST-SDC anode, La0.8Sr0.2Ga0.8Mg0.2O3 electrolyte, and La0.8Sr0.2CoO3-SDC cathode show a good performance at 650-800 °C. The annealing reduces the impedances due to the enhancement in the bonding between the particles in the anode and interface of anode and LSGM electrolyte, thus improving the output performance of the cell.

  16. Investigation into the diffusion and oxidation behavior of the interface between a plasma-sprayed anode and a porous steel support for solid oxide fuel cells

    NASA Astrophysics Data System (ADS)

    Zhang, Shan-Lin; Li, Cheng-Xin; Li, Chang-Jiu; Liu, Meilin; Yang, Guan-Jun

    2016-08-01

    Porous metal-supported solid oxide fuel cells (SOFCs) have attracted much attention because their potential to dramatically reduce the cost while enhancing the robustness and manufacturability. In particular, 430 ferritic steel (430L) is one of the popular choice for SOFC support because of its superior performance and low cost. In this study, we investigate the oxidation and diffusion behavior of the interface between a Ni-based anode and porous 430L support exposed to a humidified (3% H2O) hydrogen atmosphere at 700 °C. The Ni-GDC (Ce0.8Gd0.2O2-δ) cermet anodes are deposited on the porous 430L support by atmospheric plasma spraying (APS). The effect of exposure time on the microstructure and phase structure of the anode and the supports is studied and the element diffusion across the support/anode interface is characterized. Results indicate that the main oxidation product of the 430L support is Cr2O3, and that Cr and Fe will diffuse to the anode and the diffusion thickness increases with the exposure time. The diffusion thickness of Cr and Fe reach about 5 and 2 μm, respectively, after 1000 h exposure. However, the element diffusion and oxidation has little influence on the area-specific resistance, indicating that the porous 430L steel and plasma sprayed Ni-GDC anode are promising for durable SOFCs.

  17. Improvement in wear and corrosion resistance of AISI 1020 steel by high velocity oxy-fuel spray coating containing Ni-Cr-B-Si-Fe-C

    NASA Astrophysics Data System (ADS)

    Prince, M.; Thanu, A. Justin; Gopalakrishnan, P.

    2012-04-01

    In this investigation, AISI 1020 low carbon steel has been selected as the base material. The Ni based super alloy powder NiCrBSiFeC was sprayed on the base material using high velocity oxy-fuel spraying (HVOF) technique. The thickness of the coating was approximately 0.5 mm (500 μm). The coating was characterized using optical microscopy, Vickers microhardness testing, X-ray diffraction technique and scanning electron microscopy. Dry sliding wear tests were carried out at 3 m/s sliding speed under the load of 10 N for 1000 m sliding distance at various temperatures i.e., 35° C, 250° C and 350° C. The corrosion test was carried out in 1 M copper chloride in acetic acid solution. The polarization studies were also conducted for both base material and coating. The improvement in microhardness from 1.72 GPa (175 HV0.05) to 10.54 GPa (1075 HV0.05) was observed. The coatings exhibited 3-6 times improved wear resistance as compared with base material. Also, the corrosion rate was reduced by 3.5 times due to the presence of coatings.

  18. Surface characteristic of chemically converted graphene coated low carbon steel by electro spray coating method for polymer electrolyte membrane fuel cell bipolar plate.

    PubMed

    Kim, Jungsoo; Kim, Yang Do; Nam, Dae Geun

    2013-05-01

    Graphene was coated on low carbon steel (SS400) by electro spray coating method to improve its properties of corrosion resistance and contact resistance. Exfoliated graphite was made of the graphite by chemical treatment (Chemically Converted Graphene, CCG). CCG is distributed using dispersing agent, and low carbon steel was coated with diffuse graphene solution by electro spray coating method. The structure of the CCG was analyzed using XRD and the coating layer of surface was analyzed using SEM. Analysis showed that multi-layered graphite structure was destroyed and it was transformed in to fine layers graphene structure. And the result of SEM analysis on the surface and the cross section, graphene layer was uniformly formed with 3-5 microm thickness on the surface of substrate. Corrosion resistance test was applied in the corrosive solution which is similar to the polymer electrolyte membrane fuel cell (PEMFC) stack inside. And interfacial contact resistance (ICR) test was measured to simulate the internal operating conditions of PEMFC stack. As a result of measuring corrosion resistance and contact resistance, it could be confirmed that low carbon steel coated with CCG was revealed to be more effective in terms of its applicability as PEMFC bipolar plate. PMID:23858864

  19. Evaporating firewalls

    NASA Astrophysics Data System (ADS)

    Van Raamsdonk, Mark

    2014-11-01

    In this note, we begin by presenting an argument suggesting that large AdS black holes dual to typical high-energy pure states of a single holographic CFT must have some structure at the horizon, i.e. a fuzzball/firewall, unless the procedure to probe physics behind the horizon is state-dependent. By weakly coupling the CFT to an auxiliary system, such a black hole can be made to evaporate. In a case where the auxiliary system is a second identical CFT, it is possible (for specific initial states) that the system evolves to precisely the thermofield double state as the original black hole evaporates. In this case, the dual geometry should include the "late-time" part of the eternal AdS black hole spacetime which includes smooth spacetime behind the horizon of the original black hole. Thus, if a firewall is present initially, it evaporates. This provides a specific realization of the recent ideas of Maldacena and Susskind that the existence of smooth spacetime behind the horizon of an evaporating black hole can be enabled by maximal entanglement with a Hawking radiation system (in our case the second CFT) rather than prevented by it. For initial states which are not finely-tuned to produce the thermofield double state, the question of whether a late-time infalling observer experiences a firewall translates to a question about the gravity dual of a typical high-energy state of a two-CFT system.

  20. Dispersion and evaporation of droplets amended with adjuvants on soybeans

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Increased use of adjuvants to improve pesticide spray application efficiency is hindered by a lack of knowledge to enhance droplet adhesion. Dispersion and evaporation of single 300 µm droplets amended with four different spray adjuvants deposited at four different soybean plant locations were inves...

  1. Spray combustion stability

    NASA Technical Reports Server (NTRS)

    Liang, Pak-Yan; Jeng, San-Mou; Litchford, Ronald

    1989-01-01

    The central purpose of this project is the improvement of liquid-fueled rocket motor design technology in order to assist the establishment of economical commercial access to space through the development of engines with enhanced performance and reliability. Specific research effort is focused on spray physics and associated combustion instability phenomena. Results concerning high pressure droplet gasification model, droplet turbulent dispersion model, and spray atomization model will contribute to the development of new computational tools for design of stable liquid propellant rocket engines.

  2. Performance of high-velocity oxy-fuel-sprayed chromium carbide-nickel chromium coating in an actual boiler environment of a thermal power plant

    SciTech Connect

    Sidhu, T.S.; Prakash, S.; Agrawal, R.D.

    2007-09-15

    The present study aims to evaluate the performance of a high-velocity oxy-fuel (HVOF)-sprayed Cr{sub 3}C{sub 2}-NiCr (chromium carbide-nickel chromium) coating on a nickel-based super-alloy in an actual industrial environment of a coal-fired boiler, with the objective to protect the boiler super-heater and reheater tubes from hot corrosion. The tests were performed in the platen super heater zone of a coal-fired boiler for 1,000 h at 900 degrees C under cyclic conditions. The Cr{sub 3}C{sub 2}-NiCr coating imparted the necessary protection to the nickel-based super alloy in the given environment. The dense and flat splat structure of the coating, and the formation of oxides of chromium and nickel and their spinels, might have protected the substrate super alloy from the inward permeation of corrosive species.

  3. Effect of ultrasonic cavitation erosion on corrosion behavior of high-velocity oxygen-fuel (HVOF) sprayed near-nanostructured WC-10Co-4Cr coating.

    PubMed

    Hong, Sheng; Wu, Yuping; Zhang, Jianfeng; Zheng, Yugui; Qin, Yujiao; Lin, Jinran

    2015-11-01

    The effect of ultrasonic cavitation erosion on electrochemical corrosion behavior of high-velocity oxygen-fuel (HVOF) sprayed near-nanostructured WC-10Co-4Cr coating in 3.5 wt.% NaCl solution, was investigated using free corrosion potential, potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS) in comparison with stainless steel 1Cr18Ni9Ti. The results showed that cavitation erosion strongly enhanced the cathodic current density, shifted the free corrosion potential in the anodic direction, and reduced the magnitude of impedance of the coating. The impedance of the coating decreased more slowly under cavitation conditions than that of the stainless steel 1Cr18Ni9Ti, suggesting that corrosion behavior of the coating was less affected by cavitation erosion than that of the stainless steel. PMID:26186856

  4. Numerical Modeling of Suspension HVOF Spray

    NASA Astrophysics Data System (ADS)

    Jadidi, M.; Moghtadernejad, S.; Dolatabadi, A.

    2016-02-01

    A three-dimensional two-way coupled Eulerian-Lagrangian scheme is used to simulate suspension high-velocity oxy-fuel spraying process. The mass, momentum, energy, and species equations are solved together with the realizable k-ɛ turbulence model to simulate the gas phase. Suspension is assumed to be a mixture of solid particles [mullite powder (3Al2O3·2SiO2)], ethanol, and ethylene glycol. The process involves premixed combustion of oxygen-propylene, and non-premixed combustion of oxygen-ethanol and oxygen-ethylene glycol. One-step global reaction is used for each mentioned reaction together with eddy dissipation model to compute the reaction rate. To simulate the droplet breakup, Taylor Analogy Breakup model is applied. After the completion of droplet breakup, and solvent evaporation/combustion, the solid suspended particles are tracked through the domain to determine the characteristics of the coating particles. Numerical simulations are validated against the experimental results in the literature for the same operating conditions. Seven or possibly eight shock diamonds are captured outside the nozzle. In addition, a good agreement between the predicted particle temperature, velocity, and diameter, and the experiment is obtained. It is shown that as the standoff distance increases, the particle temperature and velocity reduce. Furthermore, a correlation is proposed to determine the spray cross-sectional diameter and estimate the particle trajectories as a function of standoff distance.

  5. LSPRAY: Lagrangian Spray Solver for Applications With Parallel Computing and Unstructured Gas-Phase Flow Solvers

    NASA Technical Reports Server (NTRS)

    Raju, Manthena S.

    1998-01-01

    Sprays occur in a wide variety of industrial and power applications and in the processing of materials. A liquid spray is a phase flow with a gas as the continuous phase and a liquid as the dispersed phase (in the form of droplets or ligaments). Interactions between the two phases, which are coupled through exchanges of mass, momentum, and energy, can occur in different ways at different times and locations involving various thermal, mass, and fluid dynamic factors. An understanding of the flow, combustion, and thermal properties of a rapidly vaporizing spray requires careful modeling of the rate-controlling processes associated with the spray's turbulent transport, mixing, chemical kinetics, evaporation, and spreading rates, as well as other phenomena. In an attempt to advance the state-of-the-art in multidimensional numerical methods, we at the NASA Lewis Research Center extended our previous work on sprays to unstructured grids and parallel computing. LSPRAY, which was developed by M.S. Raju of Nyma, Inc., is designed to be massively parallel and could easily be coupled with any existing gas-phase flow and/or Monte Carlo probability density function (PDF) solver. The LSPRAY solver accommodates the use of an unstructured mesh with mixed triangular, quadrilateral, and/or tetrahedral elements in the gas-phase solvers. It is used specifically for fuel sprays within gas turbine combustors, but it has many other uses. The spray model used in LSPRAY provided favorable results when applied to stratified-charge rotary combustion (Wankel) engines and several other confined and unconfined spray flames. The source code will be available with the National Combustion Code (NCC) as a complete package.

  6. Oxymetazoline Nasal Spray

    MedlinePlus

    Afrin® Nasal Spray ... Anefrin® Nasal Spray ... Dristan® Nasal Spray ... Mucinex® Nasal Spray ... Nostrilla® Nasal Spray ... Vicks Sinex® Nasal Spray ... Zicam® Nasal Spray ... Oxymetazoline nasal spray is used to relieve nasal discomfort caused by colds, allergies, and hay fever. It is also used to ...

  7. Streamer Evaporation

    NASA Technical Reports Server (NTRS)

    Suess, S. T.; Wang, A.-H.; Wu, S. T.; Nerney, S. F.

    1998-01-01

    Evaporation is the consequence of heating near the top of streamers in ideal Magnetohydrodynamics (MHD) models, where the plasma is weakly contained by the magnetic field. Heating causes slow opening of field lines and release of new solar wind. It was discovered in simulations and, due to the absence of loss mechanisms, the ultimate end point is the complete evaporation of the streamer. Of course streamers do not behave in this way because there are losses by thermal conduction and radiation. Physically, heating is also expected to depend on ambient conditions. We use our global MHD model with thermal conduction to examine the effect of changing the heating scale height. We also apply and extend an analytic model of streamers developed by Pneuman (1968) to show that steady streamers are unable to contain plasma for temperatures near the cusp greater than approximately 2 x 10(exp 6) K.

  8. The properties of Co- and Fe-doped GDC for low-temperature processing of solid oxide fuel cell by electron-beam evaporation.

    PubMed

    Yang, Seon-Ho; Kim, Kyung-Hwan; Choi, Hyung-Wook

    2013-08-01

    This study is transition metal oxides (FeO and CoO) were added to Gd-doped ceria (Gd0.1Ce0.9O1.95, GDC) powder for preparing the thin-film electrolyte used in the Ni-GDC anode-supported intermediate temperature solid oxide fuel cell (SOFC). Recently much attention was aimed at successful powder preparation with high sinter activity and conductivity. However, one of the challenges in preparing the GDC electrolytes is the densification issue. It is difficult to achieve the densification of GDC below 1600 degrees C. To overcome this drawback, attentions of the research on the densification of the GDC electrolyte is paid more on changing of the fabrication technology, the powder properties, and the sintering mechanism. Among them, Fe3+ and Co2+ showed the significant beneficial effect on the grain boundary conductivity. So, electrolyte powder made of Co- and Fe-doped GDC by solid-state reaction method. And thin-film electrolyte was fabricated on the presintered Ni-GDC cermet anode substrate by E-beam evaporating method and then co-sintered to form the electrolyte/anode bilayer. We realized crystal structure of Co and Fe doped Gd0.1Ce0.9O1.95 (GDC) electrolyte by X-ray diffraction (XRD). The morphology was measured by scanning electron microscopy (SEM) for the sintered samples were performed. The performance of the cells was evaluated over 500-800 degrees C using humidified hydrogen as fuel and air as oxidant. PMID:23882837

  9. Fabrication of an anode-supported yttria-stabilized zirconia thin film for solid-oxide fuel cells via wet powder spraying

    NASA Astrophysics Data System (ADS)

    Zhou, Wei; Shi, Huangang; Ran, Ran; Cai, Rui; Shao, Zongping; Jin, Wanqin

    The wet powder spraying (WPS) technique was used for the deposition of dense and thin (Y 2O 3) 0.08(ZrO 2) 0.92 (YSZ-8) films on an anode substrate being used for fuel cell applications. Both agglomeration of the powder and the presence of organics in the substrate have a significant effect on the quality and densification of the thin electrolyte layer. High-energy ball milling effectively broke up the agglomerates and enhanced the packing density of the green layer. Pre-calcination of the substrate at ∼1000 °C enhanced the match of sintering shrinkage between the electrolyte layer and the substrate and improved the quality of the YSZ-8 thin film significantly. Crack-free dual-layer assembly with a highly densified YSZ-8 film as thin as 10 μm was successfully fabricated by optimizing the fabrication parameters. The cells with a La 0.8Sr 0.2MnO 3 cathode showed a high open circuit voltage of 1.071 V and a peak power density of 894 mW cm -2 at 850 °C operated with hydrogen fuel.

  10. Effects of intensive evaporative cooling on performance characteristics of land-based gas turbine

    SciTech Connect

    Utamura, Motoaki; Kuwahara, Takaaki; Murata, Hidetaro; Horii, Nobuyuki

    1999-07-01

    Injection of finely-atomized water droplets at inlet to compressor is demonstrated to increase the power and augment the efficiency of gas turbine using a 115MW simple cycle commercial power plant. Power-up mechanism of the present system is identified to be a composite of three existing methods. Design requirement on droplet diameter is discussed in view of blade erosion as well as evaporation efficiency within the compressor. Special spray nozzle to generate water droplets with sauter mean diameter of 10 {micro} m is developed and applied to demonstration test. Experiments show that injection of spray water of 1% to air mass ratio would increase power output by about 10% and thermal efficiency by 3% (relative) respectively. A newly introduced incremental efficiency defined as the ratio of incremental power to additional fuel energy is found to be in excess of 10% (absolute) over thermal efficiency in case without water injection and to be independent of spray amount. It is also revealed that the operation of water spraying suppresses dust deposition on compressor blades under proper control of water quality, which mitigates the deterioration of compressor adiabatic efficiency.

  11. Droplet Cluster Behavior in Dense and Dilute Regions of a Spray

    NASA Technical Reports Server (NTRS)

    Bellan, J.

    1995-01-01

    Concern regarding the efficiency, stability and safety margins of bi-propellant combustion in rocket engines has prompted the investigation of many specific aspects of spray evaporation, ignition and combustion previously not studied. The phenomenology of bi- propellant spray evaporation, ignition and combustion in a highly turbulent environment at elevated pressure is discussed.

  12. Nitroglycerin Spray

    MedlinePlus

    ... attacks. Your doctor will probably tell you to sit down and use one dose of nitroglycerin when ... dose.To use the spray, follow these steps: Sit down if possible, and hold the container without ...

  13. Streamer Evaporation

    NASA Technical Reports Server (NTRS)

    Suess, Steven T.; Wang, A. H.; Wu, Shi T.; Nerney, S.

    1998-01-01

    Evaporation is the consequence of slow plasma heating near the tops of streamers where the plasma is only weakly contained by the magnetic field. The form it takes is the slow opening of field lines at the top of the streamer and transient formation of new solar wind. It was discovered in polytropic model calculations, where due to the absence of other energy loss mechanisms in magnetostatic streamers, its ultimate endpoint is the complete evaporation of the streamer. This takes, for plausible heating rates, weeks to months in these models. Of course streamers do not behave this way, for more than one reason. One is that there are losses due to thermal conduction to the base of the streamer and radiation from the transition region. Another is that streamer heating must have a characteristic time constant and depend on the ambient physical conditions. We use our global Magnetohydrodynamics (MHD) model with thermal conduction to examine a few examples of the effect of changing the heating scale height and of making ad hoc choices for how the heating depends on ambient conditions. At the same time, we apply and extend the analytic model of streamers, which showed that streamers will be unable to contain plasma for temperatures near the cusp greater than about 2xl0(exp 6) K. Slow solar wind is observed to come from streamers through transient releases. A scenario for this that is consistent with the above physical process is that heating increases the near-cusp temperature until field lines there are forced open. The subsequent evacuation of the flux tubes by the newly forming slow wind decreases the temperature and heating until the flux tubes are able to reclose. Then, over a longer time scale, heating begins to again refill the flux tubes with plasma and increase the temperature until the cycle repeats itself. The calculations we report here are first steps towards quantitative evaluation of this scenario.

  14. Visual characterization of heated water spray jet breakup induced by full cone spray nozzles

    NASA Astrophysics Data System (ADS)

    Naz, M. Y.; Sulaiman, S. A.; Ariwahjoedi, B.; Zilati, K.

    2015-03-01

    The present work with specific objectives places a greater emphasis on measurements of the breakup lengths and phenomenological analysis of a hot water jet under reduced pumping pressures in still environment. Therefore, visual and comparative studies are conducted on full cone jet disintegration of heated water for low pumping pressures. A further analysis of the grabbed images confirms the strong influence of the input processing parameters on full cone spray patternation. It is also predicted that the heated liquids generate a dispersed spray pattern by utilizing partial evaporation of the spraying medium. The radial spray cone width and angle do not vary significantly with increasing Reynolds and Weber numbers at early injection phases, leading to enhanced macroscopic spray propagation. The discharge coefficient, mean flow rate, and mean flow velocity are significantly influenced by the load pressure, but less affected by the temperature. The fine scale image analysis also predicts toroidal-shaped vortex formation in the spray structure near the water boiling point.

  15. Digital Image Processing application to spray and flammability studies

    NASA Technical Reports Server (NTRS)

    Hernan, M. A.; Parikh, P.; Sarohia, V.

    1985-01-01

    Digital Image Processing has been integrated into a new technique for measurements of fuel spray characteristics. The advantages of this technique are: a wide dynamic range of droplet sizes, accounting for nonspherical droplet shapes not possible with other spray assessment techniques. Finally, the technique has been applied to the study of turbojet engine fuel nozzle atomization performance with Jet A and antimisting fuel.

  16. Spray combustion modeling

    NASA Technical Reports Server (NTRS)

    Bellan, J.

    1997-01-01

    Concern over the future availability of high quality liquid fuels or use in furnaces and boilers prompted the U. S. Department of Energy (DOE) to consider alternate fuels as replacements for the high grade liquid fuels used in the 1970's and 1980's. Alternate fuels were defined to be combinations of a large percentage of viscous, low volatility fuels resulting from the low end of distillation mixed with a small percentage of relatively low viscosity, high volatility fuels yielded by the high end of distillation. The addition of high volatility fuels was meant to promote desirable characteristics to a fuel that would otherwise be difficult to atomize and burn and whose combustion would yield a high amount of pollutants. Several questions thus needed to be answered before alternate fuels became commercially viable. These questions were related to fuel atomization, evaporation, ignition, combustion and pollutant formation. This final report describes the results of the most significant studies on ignition and combustion of alternative fuels.

  17. The characteristics of alumina scales formed on HVOF-sprayed MCrAlY coatings[High Velocity Oxygen Fuel

    SciTech Connect

    Toma, D.; Brandl, W.; Koester, U.

    2000-02-01

    HVOF MCrAlY (M = Ni, Co) coatings were isothermally oxidized in synthetic air between 850 and 1050 C for times up to 167 hr. During thermal spraying, aluminum and yttrium oxidized to form a fine oxide dispersion. The HVOF MCrAlY coatings exhibited a microstructure similar to ODS alloys. The fine dispersion consisted of Al{sub 2}O{sub 3} and aluminum-yttrium oxides. The oxidation experiments showed that the oxidation rate of HVOF coatings was two times slower than the oxidation rate of VPS MCrAlY coatings. The oxidation mechanism changed mainly in the transient-stage (no metastable modification of Al{sub 2}O{sub 3} formed) and it was assumed that the oxide dispersion hindered diffusion of various elements from the bulk material during oxidation. The formation of the fine oxide dispersion also influenced the adherence of the oxide scale. The microstructures of the transient oxide scales were examined by X-ray diffraction (XRD) scanning electron microscopy (SEM), and transmission electron microscopy (TEM).

  18. Simulation of spray-turbulence-flame interactions in a lean direct injection combustor

    SciTech Connect

    Patel, Nayan; Menon, Suresh

    2008-04-15

    Large-eddy simulation (LES) of a liquid-fueled lean-direct injection (LDI) combustor is carried out by resolving the entire inlet flow path through the swirl vanes and the combustor. A localized dynamic subgrid closure is combined with a subgrid mixing and combustion model so that no adjustable parameters are required. The inflow spray is specified by a Kelvin-Helmholtz (or aerodynamic) breakup model and compared with LES without breakup, where the incoming spray is approximated using measured data just downstream of the injector. Overall, both time-averaged gas and droplet velocity predictions compare well with the measured data. The major impact of breakup is on fuel evaporation in the vicinity of the injector. Further downstream, a broad spectrum of drop sizes are recovered by the breakup simulation and produces spray quality, as in the no-breakup case. It is shown that the vortex breakdown bubble (VBB) is smaller with more intense reverse flow when there is heat release. The swirling shear layer plays a major role in spray dispersion and the VBB provides an efficient flame-holding mechanism to stabilize the flame. Unsteady features such as the efficient dispersion of the spray by the precessing vortex core (PVC) are well captured. Flame structure analysis using the Takeno flame index shows the presence of a diffusion flame in the central portion, whereas premixed burning mode is observed farther away. Instantaneous thermochemical states of fuel-air mixing and oxidation indicate significant departure from the gaseous diffusion limits, consistent with earlier observations. Additionally, particle-particle and particle-gas correlations are analyzed and discussed. (author)

  19. Nb-doped TiO2/carbon composite supports synthesized by ultrasonic spray pyrolysis for proton exchange membrane (PEM) fuel cell catalysts

    NASA Astrophysics Data System (ADS)

    Senevirathne, Keerthi; Neburchilov, Vladimir; Alzate, Vanesa; Baker, Ryan; Neagu, Roberto; Zhang, Jiujun; Campbell, Stephen; Ye, Siyu

    2012-12-01

    In this paper we report the use of both ultrasonic spray pyrolysis and microwave-assisted polyol reduction methods to synthesize Nb-doped TiO2/carbon (25 wt% Nb0.07Ti0.93O2/75 wt% carbon) composite supports and Pt0.62Pd0.38 alloy catalysts, respectively. The physicochemical properties of the synthesized supports and their Pt0.62Pd0.38 supported catalysts are evaluated using several methods including XRD, TEM, BET surface area analysis, TGA, as well as ICP-MS elemental analysis. The electronic conductivities and thermal/chemical stabilities of the supports are also evaluated with respect to their possible use as catalyst supports. Electrochemical measurements for oxygen reduction activity of the Pt0.62Pd0.38 alloy catalysts supported on oxide/carbon composites are also carried out in order to check their suitability for possible PEM fuel cell applications. The results show that 20wt%Pt0.62Pd0.38/25 wt%(Nb0.07Ti0.93O2)-75 wt%C catalysts exhibit enhanced mass activities compared to those of commercially available 48wt% Pt/C and home-made 20wt% Pt62Pd38/C catalysts.

  20. Characterization of Ceramic Plasma-Sprayed Coatings, and Interaction Studies Between U-Zr Fuel and Ceramic Coated Interface at an Elevated Temperature

    SciTech Connect

    Ki Hwan Kim; Chong Tak Lee; R. S. Fielding; J. R. Kennedy

    2011-08-01

    Candidate coating materials for re-usable metallic nuclear fuel crucibles, HfN, TiC, ZrC, and Y2O3, were plasma-sprayed onto niobium substrates. The coating microstructure and the thermal cycling behavior were characterized, and U-Zr melt interaction studies carried out. The Y2O3 coating layer had a uniform thickness and was well consolidated with a few small pores scattered throughout. While the HfN coating was not well consolidated with a considerable amount of porosity, but showed somewhat uniform thickness. Thermal cycling tests on the HfN, TiC, ZrC, and Y2O3 coatings showed good cycling characteristics with no interconnected cracks forming even after 20 cycles. Interaction studies done on the coated samples by dipping into a U-20wt.%Zr melt indicated that HfN and Y2O3 did not form significant reaction layers between the melt and the coating while the TiC and the ZrC coatings were significantly degraded. Y2O3 exhibited the most promising performance among HfN, TiC, ZrC, and Y2O3 coatings.

  1. An easy and innovative method based on spray-pyrolysis deposition to obtain high efficiency cathodes for Solid Oxide Fuel Cells

    NASA Astrophysics Data System (ADS)

    dos Santos-Gómez, L.; Porras-Vázquez, J. M.; Martín, F.; Ramos-Barrado, J. R.; Losilla, E. R.; Marrero-López, D.

    2016-07-01

    A novel electrode preparation method based on the spray-pyrolysis deposition of metal nitrate solutions onto a porous electrolyte scaffold is proposed. This method has been proved with different cathode materials, usually used in Solid Oxide Fuel Cells, such as La0.8Sr0.2MnO3-δ and La0.6Sr0.4Co1-xFexO3-δ (x = 0, 0.2, 0.8 and 1). The electrode microstructure is composed by two layers; the inner layer is a porous electrolyte scaffold homogeneously coated by cathode nanoparticles, providing an increased number of triple phase boundary sites for oxygen reduction, whereas, the top layer is formed by only cathode nanoparticles and acts mainly as a current collector. Polarization resistance values as low as 0.07 and 1.0 Ω cm2 at 600 and 450 °C, respectively, are obtained at open circuit voltage. This alternative approach has several advantages with respect to the traditional wet infiltration method for large area electrode fabrication, such as higher reproducibility, shorter preparation time in a single thermal deposition step, and easy implementation at industrial scale as a continuous process.

  2. Ultrasonic cavitation erosion of high-velocity oxygen-fuel (HVOF) sprayed near-nanostructured WC-10Co-4Cr coating in NaCl solution.

    PubMed

    Hong, Sheng; Wu, Yuping; Zhang, Jianfeng; Zheng, Yugui; Qin, Yujiao; Lin, Jinran

    2015-09-01

    The high-velocity oxygen-fuel (HVOF) spraying process was used to prepare near-nanostructured WC-10Co-4Cr coating. The cavitation erosion behavior and mechanism of the coating in 3.5 wt.% NaCl solution were analyzed in detail. The results showed that the amorphous phase and WC grain were present in the coating. The cavitation erosion resistance of the coating was about 1.27 times that of the stainless steel 1Cr18Ni9Ti under the same testing conditions. The effects of erosion time on the microstructural evolution were discussed. It was revealed that cracks initiated at the edge of pre-existing pores and propagated along the carbide-binder interface, leading to the pull-out of carbide particle and the formation of pits and craters on the surface. The main failure mechanism of the coating was erosion of the binder phases, brittle detachment of hard phases and formation of pitting corrosion products. PMID:25617967

  3. Some Effects of Air Flow on the Penetration and Distribution of Oil Sprays

    NASA Technical Reports Server (NTRS)

    Rothrock, A M; Beardsley, E G

    1929-01-01

    Tests were made to determine the effects of air flow on the characteristics of fuel sprays from fuel injection valves. Curves and photographs are presented showing the airflow throughout the chamber and the effects of the air flow on the fuel spray characteristics. It was found that the moving air had little effect on the spray penetration except with the 0.006 inch orifice. The moving air did, however, affect the oil particles on the outside of the spray cone. After spray cut-off, the air flow rapidly distributed the atomized fuel throughout the spray chamber.

  4. Hair spray poisoning

    MedlinePlus

    Hair spray poisoning occurs when someone breathes in (inhales) hair spray or sprays it down their throat or ... The harmful ingredients in hair spray are: Carboxymethylcellulose ... Polyvinyl alcohol Propylene glycol Polyvinylpyrrolidone

  5. Comparison of cooling criteria with a cryogen spray and water/air spray

    NASA Astrophysics Data System (ADS)

    Exley, Jonathan; Dickinson, Mark R.; King, Terence A.; Charlton, Andrew; Falder, Sian; Kenealy, John

    1999-06-01

    Skin cooling using a cryogen spray (tetrafluoroethane) has been shown to dramatically reduce the skin surface temperature whilst predictions show that the underlying dermal tissue is unaffected. This technique is repeated with a chilled water spray, along with a continuous airflow to enhance evaporation. Radiometric skin surface temperature measurements are recorded during trials utilizing this technique and the results are compared with theoretical predictions in order to determine the mechanism by which the heat is removed from the skin. The optimum spray conditions are achieved when the water is chilled to around 2 degrees Celsius with a continuous airflow of 50 liters/minute. Under these conditions skin surface temperature reduction is about 8 degrees Celsius - 10 degrees Celsius. The measured radiometric skin surface temperature change indicates that the mechanism by which this process removes heat from the skin is predominantly evaporation. Predictions of skin temperature change with varying skin depth indicate that the optimum spray time is around 100 ms.

  6. Aerothermal modeling program, phase 2. Element C: Fuel injector-air swirl characterization

    NASA Technical Reports Server (NTRS)

    Mostafa, A. A.; Mongia, H. C.; Mcdonnell, V. G.; Samuelsen, G. S.

    1986-01-01

    The main objectives of the NASA-sponsored Aerothermal Modeling Program, Phase 2--Element C, are experimental evaluation of the air swirler interaction with a fuel injector in a simulated combustor chamber, assessment of the current two-phase models, and verification of the improved spray evaporation/dispersion models. This experimental and numerical program consists of five major tasks. Brief descriptions of the five tasks are given.

  7. Noncircular Cross Sections Could Enhance Mixing in Sprays

    NASA Technical Reports Server (NTRS)

    Bellan, Josette; Abdel-Hameed, Hesham

    2003-01-01

    A computational study has shown that by injecting drops in jets of gas having square, elliptical, triangular, or other noncircular injection cross sections, it should be possible to increase (relative to comparable situations having circular cross section) the entrainment and dispersion of liquid drops. This finding has practical significance for a variety of applications in which it is desirable to increase dispersion of drops. For example, in chemical-process sprays, increased dispersion leads to increases in chemical- reaction rates; in diesel engines, increasing the dispersion of drops of sprayed fuel reduces the production of soot; and in household and paint sprays, increasing the dispersion of drops makes it possible to cover larger surfaces. It has been known for some years that single-phase fluid jets that enter flow fields through noncircular inlets entrain more fluid than do comparable jets entering through circular inlets. The computational study reported here was directed in part toward determining whether and how this superior mixing characteristic of noncircular single phase jets translates to a similar benefit in cases of two-phase jets (that is, sprays). The study involved direct numerical simulations of single- and two-phase free jets with circular, elliptical, rectangular, square, and triangular inlet cross sections. The two-phase jets consisted of gas laden with liquid drops randomly injected at the inlets. To address the more interesting case of evaporating drops, the carrier gas in the jets was specified to be initially unvitiated by the vapor of the liquid chemical species and the initial temperature of the drops was chosen to be smaller than that of the gas. The mathematical model used in the study was constructed from the conservation equations for the two-phase flow and included complete couplings of mass, momentum, and energy based on thermodynamically self-consistent specification of the enthalpy, internal energy, and latent heat of

  8. Numerical Investigation of High Velocity Suspension Flame Spraying

    NASA Astrophysics Data System (ADS)

    Taleby, M.; Hossainpour, S.

    2012-12-01

    High-velocity suspension flame spraying (HVSFS) has recently developed as a possible alternative to conventional HVOF-spraying employing liquid suspensions instead of dry powder feedstock enables the use of nanoparticles. From the fluid dynamics point of view, the HVSFS system is complex and involves three-phase (gas, liquid and solid particles) turbulent flow, heat transfer, evaporation of the suspension solvent, chemical reactions of main fuel (propane) and suspension solvent (ethanol) and supersonic/subsonic flow transitions. Computational fluid dynamic techniques were carried out to solve the mass, momentum, and energy conservation equations. The realizable k-ɛ turbulence model was used to account for the effect of turbulence. The HVSFS process involves two combustion reactions. A primary combustion process is the premixed oxygen-propane reaction and secondary process is the non-premixed oxygen-gaseous ethanol reaction. For each reaction, one step global reaction, which takes dissociations and intermediate reactions into account, was derived from the equilibrium chemistry code developed by Gordon and McBride and eddy dissipation model was used to calculate the rate of reactions based on the transport equations for all species (10 species) mass fractions. Droplets were tracked in the continuum in a Lagrangian approach. In this paper, flow field inside and outside the gun simulated to provide clear and complete insight about the HVSFS processes. Moreover, the effect of some operative parameters (oxy-fuel flow rate, ethanol flow rate, droplets injection velocity and droplets size) on the gas flow field along the centerline and droplets evaporation behavior was discussed.

  9. Nitroglycerin Spray

    MedlinePlus

    ... of the hole, the container will no longer dispense full doses of medication. Do not try to open the container of nitroglycerin spray. This product may catch fire, so do not use near an open flame, and do not allow the container to be burned after use.

  10. Numerical modeling for dilute and dense sprays

    NASA Technical Reports Server (NTRS)

    Chen, C. P.; Kim, Y. M.; Shang, H. M.; Ziebarth, J. P.; Wang, T. S.

    1992-01-01

    We have successfully implemented a numerical model for spray-combustion calculations. In this model, the governing gas-phase equations in Eulerian coordinate are solved by a time-marching multiple pressure correction procedure based on the operator-splitting technique. The droplet-phase equations in Lagrangian coordinate are solved by a stochastic discrete particle technique. In order to simplify the calculation procedure for the circulating droplets, the effective conductivity model is utilized. The k-epsilon models are utilized to characterize the time and length scales of the gas phase in conjunction with turbulent modulation by droplets and droplet dispersion by turbulence. This method entails random sampling of instantaneous gas flow properties and the stochastic process requires a large number of computational parcels to produce the satisfactory dispersion distributions even for rather dilute sprays. Two major improvements in spray combustion modelings were made. Firstly, we have developed a probability density function approach in multidimensional space to represent a specific computational particle. Secondly, we incorporate the Taylor Analogy Breakup (TAB) model for handling the dense spray effects. This breakup model is based on the reasonable assumption that atomization and drop breakup are indistinguishable processes within a dense spray near the nozzle exit. Accordingly, atomization is prescribed by injecting drops which have a characteristic size equal to the nozzle exit diameter. Example problems include the nearly homogeneous and inhomogeneous turbulent particle dispersion, and the non-evaporating, evaporating, and burning dense sprays. Comparison with experimental data will be discussed in detail.

  11. Measurement of biodiesel blend and conventional diesel spray structure using x-ray radiography.

    SciTech Connect

    Kastengren, A. L.; Powell, C. F.; Wang, Y. J.; IM, K. S.; Wang, J.

    2009-11-01

    The near-nozzle structure of several nonevaporating biodiesel-blend sprays has been studied using X-ray radiography. Radiography allows quantitative measurements of the fuel distribution in sprays to be made with high temporal and spatial resolution. Measurements have been made at different values of injection pressure, ambient density, and with two different nozzle geometries to understand the influences of these parameters on the spray structure of the biodiesel blend. These measurements have been compared with corresponding measurements of Viscor, a diesel calibration fluid, to demonstrate the fuel effects on the spray structure. Generally, the biodiesel-blend spray has a similar structure to the spray of Viscor. For the nonhydroground nozzle used in this study, the biodiesel-blend spray has a slightly slower penetration into the ambient gas than the Viscor spray. The cone angle of the biodiesel-blend spray is generally smaller than that of the Viscor spray, indicating that the biodiesel-blend spray is denser than the Viscor spray. For the hydroground nozzle, both fuels produce sprays with initially wide cone angles that transition to narrow sprays during the steady-state portion of the injection event. These variations in cone angle with time occur later for the biodiesel-blend spray than for the Viscor spray, indicating that the dynamics of the injector needle as it opens are somewhat different for the two fuels.

  12. Characterization of thermal spray coatings

    SciTech Connect

    Schorr, B.S.; Stein, K.J.; Marder, A.R.

    1999-02-01

    The ability to characterize fully the microstructure of a coating is paramount for understanding the in-service properties and eventual optimization of the coating. This article discusses sample preparation and subsequent analytical techniques (LOM, SEM, XRD, WDS, and QIA) for several cermet thermal spray coatings and provides a detailed analysis of as-sprayed microstructures in addition to processing trends for several FeCrAIY-carbide coatings. It was found that the splats produced in these high velocity oxy-fuel (HVOF) coatings tended to exhibit a predominantly dendritic structure most likely retained from the gas atomization process that produced the original powder. Chemical analysis showed that the carbides tend to break down during spraying producing a complex mixture of oxides and various carbides. Finally, image analysis revealed that as the carbides in the pre-sprayed powder were increased, more carbides and oxides with less FeCrAIY and thinner coatings were found. These techniques allow the thorough characterization of thermal spray cermet coatings, which in turn should further the understanding of the thermal spray processes and help provide superior coatings in the future.

  13. Tailoring the Spray Conditions for Suspension Plasma Spraying

    NASA Astrophysics Data System (ADS)

    Joulia, A.; Duarte, W.; Goutier, S.; Vardelle, M.; Vardelle, A.; Rossignol, S.

    2015-01-01

    The plasma spray process using suspensions as liquid feedstock allows the deposition of finely structured coatings with improved properties compared to that of coatings deposited by the conventional plasma spray techniques. The evaporation of the solvent, acceleration, heating, and melting of the fine solid particles within the plasma jet take place in a shorter time, as the substrate is located closer to the plasma torch when a mono-cathode mono-anode plasma torch is used, while the liquid material processing globally consumes more energy than a powder material. Therefore, achieving a coating with the expected properties requires a broad understanding of the process. In this study, a large range of plasma spray conditions have been used to achieve yttria-stabilized zirconia coatings by suspension plasma spraying. The properties of the plasma jet (velocity, enthalpy, and stability) as well as those of droplets (trajectories, number, and size) and particles (velocity) were measured and correlated to the coating microstructure. The operating conditions necessary for obtaining disk-shape splats and achieving homogeneous coatings are described including the plasma jet properties and substrate parameters.

  14. Spray combustion stability

    NASA Technical Reports Server (NTRS)

    Liang, Pak-Yan; Jeng, S. M.; Litchford, Ronald

    1995-01-01

    The central purpose of this project is the improvement of liquid-fueled rocket motor design technology in order to assist the establishment of economical commercial access to space through the development of engines with enhanced performance and reliability. Specific research effort in the project is focused on spray physics and associated combustion instability phenomena. Results garnered from this work will contribute to the development of new computational tools for design of stable liquid propellant rocket engines. The specific objectives of the research effort include identifying and evaluating physical submodels which pertain to spray combustion stability with the idea of enhancing or refining existing submodels with a more comprehensive approach. In particular, any refinements to the spray combustion physical submodels which are achieved during the project will be channeled back to Rocketdyne for incorporation in their ARICC liquid rocket combustor code as second generation improvements. Also, as the ARICC code forms the basis or future CFD development, some effort is devoted to an evaluation of the code's capability for modeling oscillating pressure waves within the combustor.

  15. Vacuum plasma spray coating

    NASA Technical Reports Server (NTRS)

    Holmes, Richard R.; Mckechnie, Timothy N.

    1989-01-01

    Currently, protective plasma spray coatings are applied to space shuttle main engine turbine blades of high-performance nickel alloys by an air plasma spray process. Originally, a ceramic coating of yttria-stabilized zirconia (ZrO2.12Y2O3) was applied for thermal protection, but was removed because of severe spalling. In vacuum plasma spray coating, plasma coatings of nickel-chromium-aluminum-yttrium (NiCrAlY) are applied in a reduced atmosphere of argon/helium. These enhanced coatings showed no spalling after 40 MSFC burner rig thermal shock cycles between 927 C (1700 F) and -253 C (-423 F), while current coatings spalled during 5 to 25 test cycles. Subsequently, a process was developed for applying a durable thermal barrier coating of ZrO2.8Y2O3 to the turbine blades of first-stage high-pressure fuel turbopumps utilizing the enhanced NiCrAlY bond-coating process. NiCrAlY bond coating is applied first, with ZrO2.8Y2O3 added sequentially in increasing amounts until a thermal barrier coating is obtained. The enchanced thermal barrier coating has successfully passed 40 burner rig thermal shock cycles.

  16. On the lifetimes of evaporating droplets

    NASA Astrophysics Data System (ADS)

    Wilson, Stephen; Stauber, Jutta; Duffy, Brian; Sefiane, Khellil

    2013-11-01

    The evaporation of a fluid droplet on a solid substrate is a practically important problem which has been the subject of considerable research in recent years, much of it motivated by a range of technological applications, such as the application of pesticides to plants, DNA microarray analysis, inkjet printing, micro-fabrication, and spray cooling. In particular, the lifetime of a fluid droplet is not only of fundamental scientific interest, but is also important in a number of technological applications, such as inkjet printing and spray cooling applications (in which shorter droplet lifetimes are often needed) and the application of pesticides to plants (in which longer droplet lifetimes are often needed). In this talk we will analyse the lifetimes of fluid droplets evaporating in a variety of modes and, in particular, show that the widely believed folklore that the lifetime of a droplet is always longer than that of an identical droplet evaporating in the constant radius (i.e. pinned contact line) mode and shorter than that of an identical droplet evaporating in the constant angle mode is not, in general, true.

  17. Agricultural Spraying

    NASA Technical Reports Server (NTRS)

    1986-01-01

    AGDISP, a computer code written for Langley by Continuum Dynamics, Inc., aids crop dusting airplanes in targeting pesticides. The code is commercially available and can be run on a personal computer by an inexperienced operator. Called SWA+H, it is used by the Forest Service, FAA, DuPont, etc. DuPont uses the code to "test" equipment on the computer using a laser system to measure particle characteristics of various spray compounds.

  18. Flame propagation in heterogeneous mixtures of fuel drops and air

    NASA Technical Reports Server (NTRS)

    Myers, G. D.; Lefebvre, A. H.

    1984-01-01

    Photographic methods are used to measure flame speeds in flowing mixtures of fuel props and air at atmospheric pressure. The fuels employed include a conventional fuel oil plus various blends JP 7 with stocks containing single-ring and mullti-ring aromatics. The results for stoichiometric mixtures show that flame propagation cannot occur in mixtures containing mean drop sizes larger than 300 to 400 microns, depending on the fuel type. For smaller drop sizes, down to around 60 microns, flame speed is inversely proportional to drop size, indicating that evaporation rates are limiting to flame speed. Below around 60 microns, the curves of flame speed versus mean drop size flatten out, thereby demonstrating that for finely atomized sprays flame speeds are much less dependent on evaporation rates, and are governed primarily by mixing and/or chemical reaction rates. The fuels exhibiting the highest flame speeds are those containing multi-ring aromatics. This is attributed to the higher radiative heat flux emanating from their soot-bearing flames which enhances the rate of evaporation of the fuel drops approaching the flame front.

  19. High power density spray cooling

    NASA Astrophysics Data System (ADS)

    Tilton, Donald E.; Pais, Martin R.; Chow, Louis C.

    1989-07-01

    The research reported describes experimental and theoretical investigations of high power density evaporative spray cooling. Preliminary experiments demonstrating heat fluxes greater than 1,000 W/sq cm were conducted. Extensive laser phase Doppler measurements of spray characteristics were also taken. These measurements provided valuable insight into the heat transfer process. An in-depth analysis was conducted to determine the mechanisms responsible for critical heat flux. Theoretical modeling was also conducted to determine the most desirable heat transfer conditions. After analysis of these results, an improved experimental apparatus was designed and fabricated. The new apparatus provided greater experimental control and improve accuracy. New tests were conducted in which the critical heat flux was increased, and the heat transfer efficiency was greatly improved. These results are compared to those of previous researchers, and indicated substantial improvement.

  20. Colloidal spray method for low cost thin coating deposition

    DOEpatents

    Pham, Ai-Quoc; Glass, Robert S.; Lee, Tae H.

    2005-01-25

    A dense or porous coating of material is deposited onto a substrate by forcing a colloidal suspension through an ultrasonic nebulizer and spraying a fine mist of particles in a carrier medium onto a sufficiently heated substrate. The spraying rate is essentially matched to the evaporation rate of the carrier liquid from the substrate to produce a coating that is uniformly distributed over the surface of the substrate. Following deposition to a sufficient coating thickness, a single sintering step may be used to produce a dense ceramic coating. Using this method, coatings ranging in thickness from about one to several hundred microns can be obtained. By using a plurality of compounds in the colloidal suspension, coatings of mixed composition can be obtained. By using a plurality of solutions and separate pumps and a single or multiple ultrasonic nebulizer(s), and varying the individual pumping rates and/or the concentrations of the solutions, a coating of mixed and discontinuously graded (e.g., stepped) or continuously graded layers may be obtained. This method is particularly useful for depositing ceramic coatings. Dense ceramic coating materials on porous substrates are useful in providing improved electrode performance in devices such as high power density solid oxide fuel cells. Dense ceramic coatings obtained by the invention are also useful for gas turbine blade coatings, sensors, steam electrolyzers, etc. The invention has general use in preparation of systems requiring durable and chemically resistant coatings, or coatings having other specific chemical or physical properties.

  1. Colloidal spray method for low cost thin coating deposition

    DOEpatents

    Pham, Ai-Quoc; Glass, Robert S.; Lee, Tae H.

    2002-01-01

    A dense or porous coating of material is deposited onto a substrate by forcing a colloidal suspension through an ultrasonic nebulizer and spraying a fine mist of particles in a carrier medium onto a sufficiently heated substrate. The spraying rate is essentially matched to the evaporation rate of the carrier liquid from the substrate to produce a coating that is uniformly distributed over the surface of the substrate. Following deposition to a sufficient coating thickness, a single sintering step may be used to produce a dense ceramic coating. Using this method, coatings ranging in thickness from about one to several hundred microns can be obtained. By using a plurality of compounds in the colloidal suspension, coatings of mixed composition can be obtained. By using a plurality of solutions and separate pumps and a single or multiple ultrasonic nebulizer(s), and varying the individual pumping rates and/or the concentrations of the solutions, a coating of mixed and discontinuously graded (e.g., stepped) or continuously graded layers may be obtained. This method is particularly useful for depositing ceramic coatings. Dense ceramic coating materials on porous substrates are useful in providing improved electrode performance in devices such as high power density solid oxide fuel cells. Dense ceramic coatings obtained by the invention are also useful for gas turbine blade coatings, sensors, steam electrolyzers, etc. The invention has general use in preparation of systems requiring durable and chemically resistant coatings, or coatings having other specific chemical or physical properties.

  2. Agrochemical spray drift; assessment and mitigation--a review.

    PubMed

    Felsot, Allan S; Unsworth, John B; Linders, Jan B H J; Roberts, Graham; Rautman, Dirk; Harris, Caroline; Carazo, Elizabeth

    2011-01-01

    During application of agrochemicals spray droplets can drift beyond the intended target to non-target receptors, including water, plants and animals. Factors affecting this spray drift include mode of application, droplet size, which can be modified by the nozzle types, formulation adjuvants, wind direction, wind speed, air stability, relative humidity, temperature and height of released spray relative to the crop canopy. The rate of fall of spray droplets depends upon the size of the droplets but is modified by entrainment in a mobile air mass and is also influenced by the rate of evaporation of the liquid constituting the aerosol. The longer the aerosol remains in the air before falling to the ground (or alternatively striking an object above ground) the greater the opportunity for it to be carried away from its intended target. In general, all size classes of droplets are capable of movement off target, but the smallest are likely to move the farthest before depositing on the ground or a non-target receptor. It is not possible to avoid spray drift completely but it can be minimized by using best-management practices. These include using appropriate nozzle types, shields, spray pressure, volumes per area sprayed, tractor speed and only spraying when climatic conditions are suitable. Field layout can also influence spray drift, whilst crop-free and spray-free buffer zones and windbreak crops can also have a mitigating effect. Various models are available to estimate the environmental exposure from spray drift at the time of application. PMID:20981606

  3. Olopatadine Nasal Spray

    MedlinePlus

    ... relieve sneezing and a stuffy, runny or itchy nose caused by allergic rhinitis (hay fever). Olopatadine is ... comes as a liquid to spray in the nose. Olopatadine nasal spray is usually sprayed in each ...

  4. Modeling Evaporation of Drops of Different Kerosenes

    NASA Technical Reports Server (NTRS)

    Bellan, Josette; Harstad, Kenneth

    2007-01-01

    A mathematical model describes the evaporation of drops of a hydrocarbon liquid composed of as many as hundreds of chemical species. The model is intended especially for application to any of several types of kerosenes commonly used as fuels. The concept of continuous thermodynamics, according to which the chemical composition of the evaporating multicomponent liquid is described by use of a probability distribution function (PDF). However, the present model is more generally applicable than is its immediate predecessor.

  5. Surface and gas-phase resistances to the evaporation of droplets.

    PubMed

    Zung, J T

    1975-01-01

    Attempt has been made to asses quantitatively the magnitudes of both the gas-phase resistance and the surface resistance to the evaporation of droplets and to determine the transition point at which the evaporation changes from a diffusion-controlled to a surface-controlled process. This transition point is strongly dependent upon the ambient pressure and the droplet size. It is found that at atmospheric pressure the particle radius at which the transition takes place is in the range of 1 - 10mu for water, 0.1mu for n-dibutylphthalate, 0.1 - 1.0mu for mercury, and 0.001mu for liquid helium. Furthermore, we have found that the surface resistance and the gas-phase resistance vary with the size of the droplet in opposite direction, leading to the existence of a maximum rate of evaporation at a certain value of the droplet radius, this radius being dependent upon the characteristics of the liquid concerned. This conclusion may be useful in the search for an optimum and most efficient method of combustion of fuel sprays in automotive engines, gas turbines, and oil-burning power plants. PMID:1149699

  6. Evaporator Development for an Evaporative Heat Pipe System

    NASA Technical Reports Server (NTRS)

    Peters, Leigh C.

    2004-01-01

    As fossil fuel resources continue to deplete, research for alternate power sources continues to develop. One of these alternate technologies is fuel cells. They are a practical fuel source able to provide significant amounts of power for applications from laptops to automobiles and their only byproduct is water. However, although this technology is over a century old and NASA has been working with it since the early 1960 s there is still room for improvement. The research I am involved in at NASA's Glenn Research Center is focusing on what is called a regenerative fuel cell system. The unique characteristic of this type of system is that it used an outside power source to create electrolysis of the water it produces and it then reuses the hydrogen and oxygen to continue producing power. The advantage of this type of system is that, for example, on space missions it can use solar power to recharge its gas supplies between periods when the object being orbited blocks out the sun. This particular system however is far from completion. This is because of the many components that are required to make up a fuel cell that need to be tested individually. The specific part of the system that is being worked on this summer of 2004 is the cooling system. The fuel cell stack, that is the part that actually creates the power, also produces a lot of heat. When not properly cooled, it has been known to cause fires which, needless to say are not conducive to the type of power that is trying to be created. In order to cool the fuel cell stack in this system we are developing a heat pipe cooling system. One of the main components of a heat pipe cooling system is what is known as the evaporator, and that is what happens to be the part of the system we are developing this summer. In most heat pipe systems the evaporator is a tube in which the working fluid is cooled and then re-circulated through the system to absorb more heat energy from the fuel cell stack. For this system, instead

  7. Combustion of liquid sprays at high pressures

    NASA Technical Reports Server (NTRS)

    Shearer, A. J.; Faeth, G. M.

    1977-01-01

    The combustion of pressure atomized fuel sprays in high pressure stagnant air was studied. Measurements were made of flame and spray boundaries at pressures in the range 0.1-9 MPa for methanol and n-pentane. At the higher test pressure levels, critical phenomena are important. The experiments are compared with theoretical predictions based on a locally homogeneous two-phase flow model. The theory correctly predicted the trends of the data, but underestimates flame and spray boundaries by 30-50 percent, indicating that slip is still important for the present experiments (Sauter mean diameters of 30 microns at atmospheric pressure under cold flow conditions). Since the sprays are shorter at high pressures, slip effects are still important even though the density ratio of the phases approach one another as the droplets heat up. The model indicates the presence of a region where condensed water is present within the spray and provides a convenient means of treating supercritical phenomena.

  8. Evaporator Cleaning Studies

    SciTech Connect

    Wilmarth, W.R.

    1999-04-15

    Operation of the 242-16H High Level Waste Evaporator proves crucial to liquid waste management in the H-Area Tank Farm. Recent operational history of the Evaporator showed significant solid formation in secondary lines and in the evaporator pot. Additional samples remain necessary to ensure material identity in the evaporator pot. Analysis of these future samples will provide actinide partitioning information and dissolution characteristics of the solid material from the pot to ensure safe chemical cleaning.

  9. Heat transfer evaluation of HFC-236ea and CFC-114 in condensation and evaporation. Final report, October 1992-March 1995

    SciTech Connect

    Huebsch, W.W.; Pate, M.B.

    1996-06-01

    The report gives results of a heat transfer evaluation of the refrigerants hexafluoropropane (HFC-236ea) and 1,1,2,2-dichloro-tetrafluoroethane (CFC-114). This research focuses on comparing the refrigerants not only in condesation and pool boiling, but also with various tube surfaces. The test facility used in this study was initially used for spray evaporation testing; however, it was redesigned and modified for use with condensation, pool boiling, or spray evaporation testing. During condensation, the rig was capable of producing saturated or superheated vapor. During pool boiling or spray evaporation, the test facility was capable of testing pure refrigerants or refrigerant/lubricant mixtures.

  10. Evaporation Of Clusters Of Drops In A Jet

    NASA Technical Reports Server (NTRS)

    Bellan, Josette; Harstad, Kenneth G.

    1993-01-01

    Report presents theoretical study of evaporation of clusters of liquid drops injected with gas jet flowing into hot ambient gas. One in series of studies of various aspects of behavior of sprays. Simplified mathematical models used to extract qualitative information on trends in interactions.

  11. Adjuvant Effects on Evaporation Time and Wetted Area of Droplets

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Appropriate adjuvant selection for pesticide applications is central to improve spray performances on waxy leaves and to reduce off-target losses. Evaporation and deposition patterns of 500 µm sessile droplets with five classes of adjuvants on five different waxy plants were investigated. Droplets g...

  12. Plasma-Sprayed Coatings on Porous Surfaces

    NASA Technical Reports Server (NTRS)

    Leibert, C. H.

    1986-01-01

    Need for combining benefits of duplex thermal-barrier coatings with film cooling on gas-turbine vanes and blades stimulated development of improved method for plasma spraying these coatings. Method reduces blocking of holes by plasma-sprayed material and at same time reduces base-metal oxidation during coating operation. Features provide potential for increased engine efficiency and power, reduced fuel consumption, use of less costly materials or construction procedures, and extended life and durability.

  13. Evaporation in space manufacturing

    NASA Technical Reports Server (NTRS)

    Li, C. H.

    1974-01-01

    'Normal evaporation' equations for predicting the compositional changes with time and temperature have been developed and correlated with actual experimental data. An evaporative congruent temperature is defined and used to explain, predict, or plan space experiments on anomalous constitutional melting (on cooling) or solidification (on heating). Uneven evaporation causes reactive jetting forces capable of initiating new convection currents, nongravitational accelerations, surface vibrations, or other disturbances. Applications of evaporation to space manufacturing are described concerning evaporative purification, surface cooling, specimen selection, particles splitting, freezing data interpretation, material loss and dimensional control, and surface contamination or compositional changes.

  14. JET BREAKUP AND SPRAY FORMATION IN A DIESEL ENGINE.

    SciTech Connect

    GLIMM,J.; LI,X.; KIM,M.N.; OH,W.; MARCHESE,A.; SAMULYAK,R.; TZANOS,C.

    2003-06-17

    The breakup of injected fuel into spray is of key interest to the design of a fuel efficient, nonpolluting diesel engine. We report preliminary progress on the numerical simulation of diesel fuel injection spray with the front tracking code FronTier. Our simulation design is set to match experiments at ANL, and our present agreement is semi-quantitative. Future efforts will include mesh refinement studies, which will better model the turbulent flow.

  15. Field Performance of a Slimline Turbomist Evaporator under Southeastern U. S. Climate Conditions

    SciTech Connect

    Sappington, F.C.

    2003-12-15

    A recent study of evaporation technologies for treating F- and H-area groundwater contaminated with radionuclides and metals (Flach 2002) suggested that spray evaporation might be a viable alternative or supplemental technique for managing tritiated groundwater at the Mixed Waste Management Facility. The particular technology of interest in this study is the Slimline Manufacturing Ltd. Turbo-Mist Evaporator, which uses a powerful blower and high-pressure spray nozzles to propel a fine mist into the air at high air and water flowrates.

  16. Effect of Spray Parameters on the Corrosion Behavior of HVOF Sprayed WC-Co-Cr Coatings

    NASA Astrophysics Data System (ADS)

    Hong, Sheng; Wu, Yuping; Zheng, Yugui; Wang, Bo; Gao, Wenwen; Li, Gaiye; Ying, Guobing; Lin, Jinran

    2014-04-01

    WC-10Co-4Cr cermet coatings were deposited on the substrate of AISI 1045 steel by using high-velocity oxygen-fuel (HVOF) thermal spraying process. The Taguchi method including the signal-to-noise (S/N) ratio and the analysis of variance (ANOVA) was employed to optimize the porosity and, in turn, the corrosion resistance of the coatings. The spray parameters evaluated in this study were spray distance, oxygen flow, and kerosene flow. The results indicated that the important sequence of spray parameters on the porosity of the coatings was spray distance > oxygen flow > kerosene flow, and the spray distance was the only significant factor. The optimum spraying condition was 300 mm for the spray distance, 1900 scfh for the oxygen flow, and 6.0 gph for the kerosene flow. The results showed the significant influence of the microstructure on the corrosion resistance of the coatings. Potentiodynamic polarization and electrochemical impendence spectroscopy (EIS) results showed that the WC-10Co-4Cr cermet coating obtained by the optimum spraying condition with the lowest porosity exhibits the best corrosion resistance and seems to be an alternative to hard chromium coating.

  17. Investigation of particulate formation during diesel spray combustion. Technical progress quarterly report, June 1, 1989--August 31, 1989

    SciTech Connect

    Not Available

    1989-12-31

    The objective of the contract is to conduct an experimental and analytical research program to investigate strategies for using coherent anti-Stokes Raman scattering (CARS) laser diagnostic techniques for detecting the degree of fuel pyrolysis and determining fuel-air ratio. Smoke and NO{sub x} production rates depend in a complex way on the local temperature, the evaporation of the diesel spray, the local fuel-air ratio, and the pyrolysis history of fuels. Furthering the ability of CARS to provide more of this information may give engine designers more insight into the combustion process and allow them to create engines which produce fewer particulates or lower amounts of NO{sub x}. Controlling the production rates is preferable to processing emissions. If they cannot be suppressed simultaneously, adjusting the tradeoff between producing particulates or NO{sub x} may be helpful if an exhaust processing method is available for one of them. During the present quarter CARS results have been obtained in the reference/calibration cell with toluene vapor. These CARS results appear very favorable for use of toluene in 1 atm spray chamber studies as a room temperature saturated vapor mixture with CO{sub x} and N{sub 2}. The results indicate that toluene is likely a better candidate than hexane for droplet effects studies. Strong toluene CH stretch resonant CARS peaks have been found and three useful resonant CARS spectral features have been found near CO{sub 2} CARS.

  18. Evaporation of petroleum products from contaminated soils

    SciTech Connect

    Kang, S.H.; Oulman, C.S.

    1996-05-01

    Bioremediation can remove petroleum products from soil that has been contaminated by leaking underground storage tanks, but abiotic processes such as evaporation can contribute significantly to the overall removal process. The mathematical model described in this paper was developed to predict the evaporation rate of volatile liquids from petroleum-contaminated sand. The model is based on simple concepts relating to molecular diffusion embodied in the theory underlying the estimation of binary diffusivities using measurements made with an Arnold diffusion cell. The model in its simplified form indicates that the rate of evaporation for a particular volatile liquid is proportional to the square root of the product of diffusivity and partial pressure divided by the molecular weight of the liquid. This in part explains why evaporative losses from sand are so much higher for gasoline than for diesel fuel. The model also shows that the time for evaporation is directly proportional to the square of the depth dried out and inversely proportional to the vapor pressure of the volatile liquid. The model was tested using gravimetric measurements of the evaporation of n-heptane, unleaded gasoline, and diesel fuel from sand under laboratory conditions.

  19. Paint spray tests for respirators: aerosol characteristics.

    PubMed

    Ackley, M W

    1980-05-01

    Liquid paint is sprayed from an atomizing nozzle to form an aerosol for testing paint spray respirators. The generated aerosol conditions are dependent upon liguid properties, spray-nozzle flow conditions and droplet evaporation. A technique was developed for controlling the aerosol concentrations reliably. Particle-size distributions of lacquer and enamel have been measured. The lacquer distribution was found to be multi-modal. Aerosol concentration dradients arise when the nozzle is not properly positioned. Filter loading resistance is significantly affected by these concentration variations. With regard to selection of standard aerosol test be improved by modifying the current NIOSH criteria to include a description of the particle-size distribution, a more precise definition of the paint and paint thinner chemical compositions, and a narrower concentration range. PMID:6932174

  20. Understanding the sprayed boric acid method for bulk doping of silicon ribbons

    NASA Astrophysics Data System (ADS)

    Silva, J. A.; Pêra, David; Brito, Miguel C.; Alves, Jorge Maia; Serra, João; Vallêra, A. M.

    2011-07-01

    The sprayed boric acid (SBA) method for bulk doping of silicon ribbons is investigated. Experimental procedures and main results are reviewed. Computational fluid dynamics and experimental tests using partial spraying suggest the role of gas transported evaporated boron oxide to explain the boron incorporation profiles along the sample. The industrial applicability of the SBA method is discussed.

  1. Plasma Spraying of Ceramics with Particular Difficulties in Processing

    NASA Astrophysics Data System (ADS)

    Mauer, G.; Schlegel, N.; Guignard, A.; Jarligo, M. O.; Rezanka, S.; Hospach, A.; Vaßen, R.

    2015-01-01

    Emerging new applications and growing demands of plasma-sprayed coatings initiate the development of new materials. Regarding ceramics, often complex compositions are employed to achieve advanced material properties, e.g., high thermal stability, low thermal conductivity, high electronic and ionic conductivity as well as specific thermo-mechanical properties and microstructures. Such materials however, often involve particular difficulties in processing by plasma spraying. The inhomogeneous dissociation and evaporation behavior of individual constituents can lead to changes of the chemical composition and the formation of secondary phases in the deposited coatings. Hence, undesired effects on the coating characteristics are encountered. In this work, examples of such challenging materials are investigated, namely pyrochlores applied for thermal barrier coatings as well as perovskites for gas separation membranes. In particular, new plasma spray processes like suspension plasma spraying and plasma spray-physical vapor deposition are considered. In some cases, plasma diagnostics are applied to analyze the processing conditions.

  2. Plasma Spraying of Ceramics with Particular Difficulties in Processing

    NASA Astrophysics Data System (ADS)

    Mauer, G.; Schlegel, N.; Guignard, A.; Jarligo, M. O.; Rezanka, S.; Hospach, A.; Vaßen, R.

    2014-09-01

    Emerging new applications and growing demands of plasma-sprayed coatings initiate the development of new materials. Regarding ceramics, often complex compositions are employed to achieve advanced material properties, e.g., high thermal stability, low thermal conductivity, high electronic and ionic conductivity as well as specific thermo-mechanical properties and microstructures. Such materials however, often involve particular difficulties in processing by plasma spraying. The inhomogeneous dissociation and evaporation behavior of individual constituents can lead to changes of the chemical composition and the formation of secondary phases in the deposited coatings. Hence, undesired effects on the coating characteristics are encountered. In this work, examples of such challenging materials are investigated, namely pyrochlores applied for thermal barrier coatings as well as perovskites for gas separation membranes. In particular, new plasma spray processes like suspension plasma spraying and plasma spray-physical vapor deposition are considered. In some cases, plasma diagnostics are applied to analyze the processing conditions.

  3. Optimal feature extraction for segmentation of Diesel spray images.

    PubMed

    Payri, Francisco; Pastor, José V; Palomares, Alberto; Juliá, J Enrique

    2004-04-01

    A one-dimensional simplification, based on optimal feature extraction, of the algorithm based on the likelihood-ratio test method (LRT) for segmentation in colored Diesel spray images is presented. If the pixel values of the Diesel spray and the combustion images are represented in RGB space, in most cases they are distributed in an area with a given so-called privileged direction. It is demonstrated that this direction permits optimal feature extraction for one-dimensional segmentation in the Diesel spray images, and some of its advantages compared with more-conventional one-dimensional simplification methods, including considerably reduced computational cost while accuracy is maintained within more than reasonable limits, are presented. The method has been successfully applied to images of Diesel sprays injected at room temperature as well as to images of sprays with evaporation and combustion. It has proved to be valid for several cameras and experimental arrangements. PMID:15074419

  4. Laboratory prototype flash evaporator

    NASA Technical Reports Server (NTRS)

    Gaddis, J. L.

    1972-01-01

    A laboratory prototype flash evaporator that is being developed as a candidate for the space shuttle environmental control system expendable heat sink is described. The single evaporator configuration uses water as an evaporant to accommodate reentry and on-orbit peak heat loads, and Freon 22 for terrestrial flight phases below 120,000 feet altitude. The design features, fabrication techniques used for the prototype unit, redundancy considerations, and the fluid temperature control arrangement are reported in detail. The results of an extensive test program to determine the evaporator operational characteristics under a wide variety of conditions are presented.

  5. 40 CFR 1060.605 - Exemptions from evaporative emission standards.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... exemption in 40 CFR 1068.240 must use fuel-system components that meet the evaporative emission standards.... See 40 CFR 1068.225. (3) Economic hardship. See 40 CFR 1068.245 and 1068.250. (f) Evaporative emission... using an engine that is exempt from exhaust emission standards under the provisions in 40 CFR part...

  6. 40 CFR 1060.605 - Exemptions from evaporative emission standards.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... exemption in 40 CFR 1068.240 must use fuel-system components that meet the evaporative emission standards.... See 40 CFR 1068.225. (3) Economic hardship. See 40 CFR 1068.245 and 1068.250. (f) Evaporative emission... using an engine that is exempt from exhaust emission standards under the provisions in 40 CFR part...

  7. 40 CFR 1060.605 - Exemptions from evaporative emission standards.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... exemption in 40 CFR 1068.240 must use fuel-system components that meet the evaporative emission standards.... See 40 CFR 1068.225. (3) Economic hardship. See 40 CFR 1068.245 and 1068.250. (f) Evaporative emission... using an engine that is exempt from exhaust emission standards under the provisions in 40 CFR part...

  8. 40 CFR 1060.605 - Exemptions from evaporative emission standards.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... exemption in 40 CFR 1068.240 must use fuel-system components that meet the evaporative emission standards.... See 40 CFR 1068.225. (3) Economic hardship. See 40 CFR 1068.245 and 1068.250. (f) Evaporative emission... using an engine that is exempt from exhaust emission standards under the provisions in 40 CFR part...

  9. Measure Guideline: Evaporative Condensers

    SciTech Connect

    German, A; Dakin, B.; Hoeschele, M.

    2012-03-01

    This measure guideline on evaporative condensers provides information on properly designing, installing, and maintaining evaporative condenser systems as well as understanding the benefits, costs, and tradeoffs. This is a prescriptive approach that outlines selection criteria, design and installation procedures, and operation and maintenance best practices.

  10. Evaporation, Boiling and Bubbles

    ERIC Educational Resources Information Center

    Goodwin, Alan

    2012-01-01

    Evaporation and boiling are both terms applied to the change of a liquid to the vapour/gaseous state. This article argues that it is the formation of bubbles of vapour within the liquid that most clearly differentiates boiling from evaporation although only a minority of chemistry textbooks seems to mention bubble formation in this context. The…

  11. Computer modelling of the meteorological and spraying parameters that influence the aerial dispersion of agrochemical sprays

    NASA Astrophysics Data System (ADS)

    Mokeba, M. L.; Salt, D. W.; Lee, B. E.; Ford, M. G.

    random-walk process predominates. The computed effects of the release height of spray droplets, atmospheric turbulence intensity, evaporation, drop size spectrum, wind velocity and wind direction on the transport process have been studied and an analysis of spray drift is provided.

  12. Evaporative Cooling Membrane Device

    NASA Technical Reports Server (NTRS)

    Lomax, Curtis (Inventor); Moskito, John (Inventor)

    1999-01-01

    An evaporative cooling membrane device is disclosed having a flat or pleated plate housing with an enclosed bottom and an exposed top that is covered with at least one sheet of hydrophobic porous material having a thin thickness so as to serve as a membrane. The hydrophobic porous material has pores with predetermined dimensions so as to resist any fluid in its liquid state from passing therethrough but to allow passage of the fluid in its vapor state, thereby, causing the evaporation of the fluid and the cooling of the remaining fluid. The fluid has a predetermined flow rate. The evaporative cooling membrane device has a channel which is sized in cooperation with the predetermined flow rate of the fluid so as to produce laminar flow therein. The evaporative cooling membrane device provides for the convenient control of the evaporation rates of the circulating fluid by adjusting the flow rates of the laminar flowing fluid.

  13. Investigation of critical burning of fuel droplets

    NASA Technical Reports Server (NTRS)

    Faeth, G. M.

    1979-01-01

    The general problem of spray combustion was investigated. The combustion of bipropellent droplets; combustion of hydrozine fuels; and combustion of sprays were studied. A model was developed to predict mean velocities and temperatures in a combusting gas jet.

  14. External characteristics of unsteady spray atomization from a nasal spray device.

    PubMed

    Fung, Man Chiu; Inthavong, Kiao; Yang, William; Lappas, Petros; Tu, Jiyuan

    2013-03-01

    The nasal route presents an enormous opportunity to exploit the highly vascularized respiratory airway for systemic drug delivery to provide more rapid onset of therapy and reduced drug degradation compared with conventional oral routes. The dynamics of atomization at low injection pressure is less known as typical spray atomization studies have focused on industrial applications such as fuel injection that are performed at much higher pressure. An experimental test station was designed in house and an alternative method to characterize the external spray is presented. This involved the use of high-speed camera to capture the temporal development of the spray as it is atomized through actuation of the spray device. An image-processing technique based on edge detection was developed to automate processing through the large number of images captured. The results showed that there are three main phases of spray development (prestable, stable, and poststable) that can be correlated by examining the spray width. A comparison with a human nasal cavity is made to put into perspective the dimensions and geometry that the spray atomization produces. This study aimed to extend the current existing set of data to contribute toward a better understanding in nasal spray drug delivery. PMID:23303644

  15. Thermodynamic performance testing of the orbiter flash evaporator system

    NASA Technical Reports Server (NTRS)

    Jaax, J. R.; Melgares, M. A.; Frahm, J. P.

    1980-01-01

    System level testing of the space shuttle orbiter's development flash evaporator system (FES) was performed in a thermal vacuum chamber capable of simulating ambient ascent, orbital, and entry temperature and pressure profiles. The test article included the evaporator assembly, high load and topping exhaust duct and nozzle assemblies, and feedwater supply assembly. Steady state and transient heat load, water pressure/temperature and ambient pressure/temperature profiles were imposed by especially designed supporting test hardware. Testing in 1978 verified evaporator and duct heater thermal design, determined FES performance boundaries, and assessed topping evaporator plume characteristics. Testing in 1979 combined the FES with the other systems in the orbiter active thermal control subsystem (ATCS). The FES met or exceeded all nominal and contingency performance requirements during operation with the integrated ATCS. During both tests stability problems were encountered during steady state operations which resulted in subsequent design changes to the water spray nozzle and valve plate assemblies.

  16. Numerical Modeling of Spray Combustion with an Unstructured-Grid Method

    NASA Technical Reports Server (NTRS)

    Shang, H. M.; Chen, Y. S.; Liaw, P.; Shih, M. H.; Wang, T. S.

    1996-01-01

    The present unstructured-grid method follows strictly the basic finite volume forms of the conservation laws of the governing equations for the entire flow domain. High-order spatially accurate formulation has been employed for the numerical solutions of the Navier-Stokes equations. A two-equation k-epsilon turbulence model is also incorporated in the unstructured-grid solver. The convergence of the resulted linear algebraic equation is accelerated with preconditioned Conjugate Gradient method. A statistical spray combustion model has been incorporated into the present unstructured-grid solver. In this model, spray is represented by discrete particles, rather than by continuous distributions. A finite number of computational particles are used to predict a sample of total population of particles. Particle trajectories are integrated using their momentum and motion equations and particles exchange mass, momentum and energy with the gas within the computational cell in which they are located. The interaction calculations are performed simultaneously and eliminate global iteration for the two-phase momentum exchange. A transient spray flame in a high pressure combustion chamber is predicted and then the solution of liquid-fuel combusting flow with a rotating cup atomizer is presented and compared with the experimental data. The major conclusion of this investigation is that the unstructured-grid method can be employed to study very complicated flow fields of turbulent spray combustion. Grid adaptation can be easily achieved in any flow domain such as droplet evaporation and combustion zone. Future applications of the present model can be found in the full three-dimensional study of flow fields of gas turbine and liquid propulsion engine combustion chambers with multi-injectors.

  17. Ciclesonide Nasal Spray

    MedlinePlus

    Ciclesonide nasal spray is used to treat the symptoms of seasonal (occurs only at certain times of the year), and perennial ( ... Ciclesonide comes as a solution (liquid) to spray in the nose. It is usually sprayed in each nostril once daily. Use ciclesonide at around the same time every day. Follow the ...

  18. Remotely controlled spray gun

    NASA Technical Reports Server (NTRS)

    Cunningham, William C. (Inventor)

    1987-01-01

    A remotely controlled spray gun is described in which a nozzle and orifice plate are held in precise axial alignment by an alignment member, which in turn is held in alignment with the general outlet of the spray gun by insert. By this arrangement, the precise repeatability of spray patterns is insured.

  19. Application of global rainbow technique in sprays with a dependence of the refractive index on droplet size

    NASA Astrophysics Data System (ADS)

    Saengkaew, S.; Bodoc, V.; Lavergne, G.; Grehan, G.

    2013-01-01

    In liquid combustion, the evaporation process is one of the key parameters which controls combustion efficiency. To understand the combustion process, and to be able to develop an efficient combustor which produces less pollutant, it is necessary to be able to measure evaporation properties. Several techniques exist to measure the physical properties of fuel droplets, but very few exist to measure the thermo-chemical properties. The global rainbow technique (GRT) has been proposed and successfully used to measure the average temperature and the size distribution of sprays under the assumption that all the droplets are at the same temperature. This paper explores the applicability of GRT to sprays where the refractive index is a function of the particle size. A first result proves that the refractive index measured by GRT is weighted by the droplet diameter to the power of 7/3. This result permits accurate and fast comparisons between the numerical simulations and the experiments. A second result is the measurement of the refractive index by the size class by coupling GRT and Phase Doppler Anemometry (PDA) measurements (or another measurement technique with a low sensitivity to the refractive index such as holography, diffractometry, etc).

  20. An Interactive Microsoft(registered tm) Excel Program for Tracking a Single Evaporating Droplet in Crossflow

    NASA Technical Reports Server (NTRS)

    Liew, K. H.; Urip, E.; Yang, S. L.; Marek, C. J.

    2004-01-01

    Droplet interaction with a high temperature gaseous crossflow is important because of its wide application in systems involving two phase mixing such as in combustion requiring quick mixing of fuel and air with the reduction of pollutants and for jet mixing in the dilution zone of combustors. Therefore, the focus of this work is to investigate dispersion of a two-dimensional atomized and evaporating spray jet into a two-dimensional crossflow. An interactive Microsoft Excel program for tracking a single droplet in crossflow that has previously been developed will be modified to include droplet evaporation computation. In addition to the high velocity airflow, the injected droplets are also subjected to combustor temperature and pressure that affect their motion in the flow field. Six ordinary differential equations are then solved by 4th-order Runge-Kutta method using Microsoft Excel software. Microsoft Visual Basic programming and Microsoft Excel macrocode are used to produce the data and plot graphs describing the droplet's motion in the flow field. This program computes and plots the data sequentially without forcing the user to open other types of plotting programs. A user's manual on how to use the program is included.

  1. Flash evaporator systems test

    NASA Technical Reports Server (NTRS)

    Dietz, J. B.

    1976-01-01

    A flash evaporator heat rejection system representative of that proposed for the space shuttle orbiter underwent extensive system testing at the NASA Johnson Space Center (JSC) to determine its operational suitability and to establish system performance/operational characteristics for use in the shuttle system. During the tests the evaporator system demonstrated its suitability to meet the shuttle requirements by: (1) efficient operation with 90 to 95% water evaporation efficiency, (2) control of outlet temperature to 40 + or - 2 F for partial heat load operation, (3) stability of control system for rapid changes in Freon inlet temperature, and (4) repeated dormant-to-active device operation without any startup procedures.

  2. A novel metered dose transdermal spray formulation for oxybutynin.

    PubMed

    Bakshi, A; Bajaj, A; Malhotra, G; Madan, M; Amrutiya, N

    2008-11-01

    The objective of the present work was to develop a metered dose spray formulation for transdermal delivery of oxybutynin and to carry out the in vitro characterization of the optimized formulation. Oxybutynin release from a series of ethanol/acetone/methylal based formulations was assessed in vitro and the developed formulation was used for delivery from a metered dose spray. Various qualitative and quantitative parameters like spray pattern, particle size distribution, pH, evaporation time, pump seal efficiency test, average weight per metered dose, content per spray and content uniformity were evaluated. The different film forming agents were assessed and carbopol (0.5%) and lutrol (0.1%) were found to give good clarity of solution, evaporation rate, spray pattern and tackiness of the film. Diffusion studies of the optimized formulations through the semipermeable membrane showed the release of drug to the extent of almost 50% over a period of 24 h. Stability studies were conducted as per ICH guidelines and indicated that formulations were stable. Skin irritation studies were performed using rabbit as an animal model. The results obtained show that the metered dose transdermal spray formulation can be a promising and innovative therapeutic system for the transdermal administration of oxybutynin. PMID:21369433

  3. A Novel Metered Dose Transdermal Spray Formulation for Oxybutynin

    PubMed Central

    Bakshi, A.; Bajaj, A.; Malhotra, G.; Madan, M.; Amrutiya, N.

    2008-01-01

    The objective of the present work was to develop a metered dose spray formulation for transdermal delivery of oxybutynin and to carry out the in vitro characterization of the optimized formulation. Oxybutynin release from a series of ethanol/acetone/methylal based formulations was assessed in vitro and the developed formulation was used for delivery from a metered dose spray. Various qualitative and quantitative parameters like spray pattern, particle size distribution, pH, evaporation time, pump seal efficiency test, average weight per metered dose, content per spray and content uniformity were evaluated. The different film forming agents were assessed and carbopol (0.5%) and lutrol (0.1%) were found to give good clarity of solution, evaporation rate, spray pattern and tackiness of the film. Diffusion studies of the optimized formulations through the semipermeable membrane showed the release of drug to the extent of almost 50% over a period of 24 h. Stability studies were conducted as per ICH guidelines and indicated that formulations were stable. Skin irritation studies were performed using rabbit as an animal model. The results obtained show that the metered dose transdermal spray formulation can be a promising and innovative therapeutic system for the transdermal administration of oxybutynin. PMID:21369433

  4. CAPSULE REPORT: EVAPORATION PROCESS

    EPA Science Inventory

    Evaporation has been an established technology in the metal finishing industry for many years. In this process, wastewaters containing reusable materials, such as copper, nickel, or chromium compounds are heated, producing a water vapor that is continuously removed and condensed....

  5. Ultimate Heat Sink Cooling Pond and Spray Pond Analysis Models.

    Energy Science and Technology Software Center (ESTSC)

    1999-05-02

    Version 00 Three programs model performance of an ultimate heat sink cooling pond. National Weather Service data is read and analyzed to predict periods of lowest cooling performance and highest evaporative loss. The data is compared to local site data for significant differences. Then the maximum pond temperature is predicted. Five programs model performance of an ultimate heat sink spray pond. The cooling performance, evaporative water loss, and drift water loss as a function ofmore » windspeed are estimated for a spray field. These estimates are used in conjunction with National Weather Service data to predict periods of lowest cooling performance and highest evaporative loss. This data is compared to local site data for significant differences. Then the maximum pond temperature is predicted.« less

  6. Measure Guideline: Evaporative Condensers

    SciTech Connect

    German, A.; Dakin, B.; Hoeschele, M.

    2012-03-01

    The purpose of this measure guideline on evaporative condensers is to provide information on a cost-effective solution for energy and demand savings in homes with cooling loads. This is a prescriptive approach that outlines selection criteria, design and installation procedures, and operation and maintenance best practices. This document has been prepared to provide a process for properly designing, installing, and maintaining evaporative condenser systems as well as understanding the benefits, costs, and tradeoffs.

  7. Mixed feed evaporator

    DOEpatents

    Vakil, Himanshu B.; Kosky, Philip G.

    1982-01-01

    In the preparation of the gaseous reactant feed to undergo a chemical reaction requiring the presence of steam, the efficiency of overall power utilization is improved by premixing the gaseous reactant feed with water and then heating to evaporate the water in the presence of the gaseous reactant feed, the heating fluid utilized being at a temperature below the boiling point of water at the pressure in the volume where the evaporation occurs.

  8. Microwave and Millimeter Wave Imaging of the Space Shuttle External Fuel Tank Spray on Foam Insulation (SOFI) using Synthetic Aperture Focusing Techniques (SAFT}

    NASA Technical Reports Server (NTRS)

    Case, J. T.; Robbins, J.; Kharkivskiy, S.; Hepburn, F.; Zoughi, R.

    2005-01-01

    The Space Shuttle Columbia s catastrophic failure is thought to have been caused by a dislodged piece of external tank spray on foam insulation (SOFI) striking the left wing of the orbiter causing significant damage to some of the reinforced carbodcarbon leading edge wing panels. Microwave and millimeter wave nondestructive evaluation methods have shown great potential for inspecting SOFI for the purpose of detecting anomalies such as small air voids that may cause separation of the SOFI from the external tank during a launch. These methods are capable of producing relatively high-resolution images of the interior of SOFI particularly when advanced imaging algorithms are incorporated into the overall system. To this end, synthetic aperture focusing techniques (SAFT) are being developed. This paper presents some of the preliminary results of this investigation using SAFT-based methods and microwave holography at relatively low frequencies illustrating their potential capabilities for operation at millimeter wave frequencies.

  9. 40 CFR 59.611 - What evaporative emission requirements apply under this subpart?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 6 2012-07-01 2012-07-01 false What evaporative emission requirements... CONSUMER AND COMMERCIAL PRODUCTS Control of Evaporative Emissions From New and In-Use Portable Fuel Containers Emission Standards and Related Requirements § 59.611 What evaporative emission requirements...

  10. 40 CFR 59.611 - What evaporative emission requirements apply under this subpart?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 5 2011-07-01 2011-07-01 false What evaporative emission requirements... CONSUMER AND COMMERCIAL PRODUCTS Control of Evaporative Emissions From New and In-Use Portable Fuel Containers Emission Standards and Related Requirements § 59.611 What evaporative emission requirements...

  11. 40 CFR 59.611 - What evaporative emission requirements apply under this subpart?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 6 2013-07-01 2013-07-01 false What evaporative emission requirements... CONSUMER AND COMMERCIAL PRODUCTS Control of Evaporative Emissions From New and In-Use Portable Fuel Containers Emission Standards and Related Requirements § 59.611 What evaporative emission requirements...

  12. 40 CFR 59.611 - What evaporative emission requirements apply under this subpart?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 6 2014-07-01 2014-07-01 false What evaporative emission requirements... CONSUMER AND COMMERCIAL PRODUCTS Control of Evaporative Emissions From New and In-Use Portable Fuel Containers Emission Standards and Related Requirements § 59.611 What evaporative emission requirements...

  13. Evaporative Emission Model (EVAP 3. 0) (for microcomputers). Software

    SciTech Connect

    Not Available

    1993-02-01

    The potential role of automotive evaporative emissions in the formation of photochemical smog has underscored the need for an accurate evaluation of real-world motor vehicle evaporative emission rates. Two general categories of information are needed to predict evaporative emissions for vehicles in actual use. The first category defines the environment that a vehicle experiences in the real world. This includes conditions such as driving pattern, ambient temperature, refueling behavior, and gasoline Reid vapor pressure (RVP). The second category describes how the vehicle responds to these conditions. This includes weathering of the fuel in the fuel tank and how evaporative emissions vary as a function of RVP, ambient temperature, and fuel tank level.

  14. Evaporative cooling on a grooved surface. M.S. Thesis

    NASA Technical Reports Server (NTRS)

    Yoder, D.

    1979-01-01

    The transition point where water begins to accumulate on the surface during spray evaporative cooling was investigated experimentally to determine the temperatures and corresponding heat flux at which this transition occurs. Several pressure ranges were considered including one below the triple point of water. Additionally, the results using a grooved surface were compared to those using a smooth surface. It was determined that a grooved surface has no effect on the heat transfer.

  15. Direct numerical simulations of temporally developing turbulent reacting liquid-fueled jets

    NASA Astrophysics Data System (ADS)

    Shashank, Shashank; Pitsch, Heinz

    2012-11-01

    Liquid fueled engines are ubiquitous in the transportation industry because liquid fuel minimizes the weight and volume of propulsion systems. The combustion that occurs in these engines is an inherently multi-physics process, involving fuel evaporation, reaction kinetics, and high levels of turbulence. A desire for high fidelity data that explains complex interaction between different physical mechanisms motivates the consideration of direct numerical simulation (DNS) as an investigation tool. In this study three-dimensional DNS of a reacting n-heptane liquid fueled temporal jet have been performed to study auto-ignition and subsequent burning in conditions that are representative of a diesel engine environment. In these simulations the continuous phase is described using an Eulerian representation whereas Lagrangian particle tracking is used to model the dispersed phase. The results of this study will demonstrate the importance of unsteady effects, and of accounting for the interaction between different modes of combustion, when simulating spray combustion.

  16. An evaporation model of colloidal suspension droplets

    NASA Astrophysics Data System (ADS)

    Sartori, Silvana; Li\\ Nán, Amable; Lasheras, Juan C.

    2009-11-01

    Colloidal suspensions of polymers in water or other solvents are widely used in the pharmaceutical industry to coat tablets with different agents. These allow controlling the rate at which the drug is delivered, taste or physical appearance. The coating is performed by simultaneously spraying and drying the tablets with the colloidal suspension at moderately high temperatures. The spreading of the coating on the pills surface depends on the droplet Webber and Reynolds numbers, angle of impact, but more importantly on the rheological properties of the drop. We present a model for the evaporation of a colloidal suspension droplet in a hot air environment with temperatures substantially lower than the boiling temperature of the carrier fluid. As the liquid vaporizes from the surface, a compacting front advances into the droplet faster than the liquid surface regresses, forming a shell of a porous medium where the particles reach their maximum packing density. While the surface regresses, the evaporation rate is determined by both the rate at which heat is transported to the droplet surface and the rate at which liquid vapor is diffused away from it. This regime continues until the compacting front reaches the center of the droplet, at which point the evaporation rate is drastically reduced.

  17. An evaporation model of multicomponent solution drops

    NASA Astrophysics Data System (ADS)

    Sartori, Silvana; Liñán, Amable; Lasheras, Juan C.

    2010-11-01

    Solutions of polymers are widely used in the pharmaceutical industry as tablets coatings. These allow controlling the rate at which the drug is delivered, taste or appearance. The coating is performed by spraying and drying the tablets at moderate temperatures. The wetting of the coating solution on the pill's surface depends on the droplet Webber and Re numbers, angle of impact and on the rheological properties of the droplet. We present a model for the evaporation of multicomponent solutions droplets in a hot air environment with temperatures substantially lower than the boiling temperature of the solvent. As the liquid vaporizes from the surface the fluid in the drop increases in concentration, until reaching its saturation point. After saturation, precipitation occurs uniformly within the drop. As the surface regresses, a compacting front formed by the precipitate at its maximum packing density advances into the drop, while the solute continues precipitating uniformly. This porous shell grows fast due to the double effect of surface regression and precipitation. The evaporation rate is determined by the rates at which heat is transported to the droplet surface and at which liquid vapor diffuses away from it. When the drop is fully compacted, the evaporation is drastically reduced.

  18. Effect of atomization air on droplet dynamics of spray flames

    SciTech Connect

    Presser, C.; Semerjian, H.G. . Center for Chemical Technology); Gupta, A.K. . Dept. of Mechanical Engineering)

    1988-01-01

    Fuel spray combustions is an important part of a wide variety of propulsion and power systems such as furnaces and gas turbine combustors, afterburners, fuel-injection internal combustion engines, liquid rocket engines, etc. Recent studies using air-assist nozzles have shown that the design and fabrication of these nozzles can directly influence spray circumferential uniformity, i.e., the presence of asymmetrical fuel flux profiles in combustors. The practical implications of these fuel flux nonuniformities are that they seriously alter the spray structure, which subsequently affects droplet/air interactions, local fuel/air mixing, overall flame characteristics and combustor performance, and pollutant emission levels. In addition, the effect of aerodynamic factors on spray characteristics has been investigated. This paper discusses the effect of atomization air on the droplet dynamics of spray flames formed by an air-assist nozzle. Presented are spatial distributions of mean droplet velocity and their probability distributions, which provide quantitative information for examination of the observed spray flame features.

  19. Spray combustion experiments and numerical predictions

    NASA Technical Reports Server (NTRS)

    Mularz, Edward J.; Bulzan, Daniel L.; Chen, Kuo-Huey

    1993-01-01

    The next generation of commercial aircraft will include turbofan engines with performance significantly better than those in the current fleet. Control of particulate and gaseous emissions will also be an integral part of the engine design criteria. These performance and emission requirements present a technical challenge for the combustor: control of the fuel and air mixing and control of the local stoichiometry will have to be maintained much more rigorously than with combustors in current production. A better understanding of the flow physics of liquid fuel spray combustion is necessary. This paper describes recent experiments on spray combustion where detailed measurements of the spray characteristics were made, including local drop-size distributions and velocities. Also, an advanced combustor CFD code has been under development and predictions from this code are compared with experimental results. Studies such as these will provide information to the advanced combustor designer on fuel spray quality and mixing effectiveness. Validation of new fast, robust, and efficient CFD codes will also enable the combustor designer to use them as additional design tools for optimization of combustor concepts for the next generation of aircraft engines.

  20. Bear Spray Safety Program

    USGS Publications Warehouse

    Blome, C.D.; Kuzniar, R.L.

    2009-01-01

    A bear spray safety program for the U.S. Geological Survey (USGS) was officially initiated by the Firearms Safety Committee to address accident prevention and to promote personnel training in bear spray and its transportation, storage, and use for defense against wild animals. Used as part of a system including firearms, or used alone for those who choose not to carry a firearm, bear spray is recognized as an effective tool that can prevent injury in a wild animal attack.

  1. 40 CFR 1042.107 - Evaporative emission standards.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... fuels (for example, natural gas). (b) If an engine uses a volatile liquid fuel, such as methanol, the... requirements of 40 CFR part 1045 that apply with respect to spark-ignition engines. Manufacturers subject to evaporative emission standards must meet the requirements of 40 CFR 1045.112 as described in 40 CFR part...

  2. 40 CFR 1042.107 - Evaporative emission standards.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... fuels (for example, natural gas). (b) If an engine uses a volatile liquid fuel, such as methanol, the... requirements of 40 CFR part 1045 that apply with respect to spark-ignition engines. Manufacturers subject to evaporative emission standards must meet the requirements of 40 CFR 1045.112 as described in 40 CFR part...

  3. 40 CFR 86.1243-96 - Calculations; evaporative emissions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 19 2010-07-01 2010-07-01 false Calculations; evaporative emissions. 86.1243-96 Section 86.1243-96 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... Petroleum Gas-Fueled and Methanol-Fueled Heavy-Duty Vehicles § 86.1243-96 Calculations;...

  4. A MICRO-VARIABLE CIRCULAR ORIFICE (MVCO) FUEL INJECTOR WITH VARIABLE SPRAY ANGLES AND PATTERNS FOR REDUCING NOX EMISSIONS FROM DIESEL ENGINES - PHASE I

    EPA Science Inventory

    Diesel engines are widely used due to their high fuel efficiency. However, conventional diesel engines have high NOx and soot emissions. Selective catalytic reduction (SCR) for NOx reduction is less accepted by the construction industry due to complexity ...

  5. Simulation of a turbulent spray flame using coupled PDF gas phase and spray flamelet modeling

    SciTech Connect

    Ge, Hai-Wen; Gutheil, Eva

    2008-04-15

    A joint mixture fraction-enthalpy probability density function (PDF) is proposed for the simulation of turbulent spray flames. The PDF transport equation is deduced and modeled. The interaction-by-exchange-with-the-mean (IEM) model that has been developed for gas-phase flows is extended to describe molecular mixing in nonreactive and reactive spray flows. The joint PDF transport equation is solved by a hybrid finite-volume and Lagrangian Monte Carlo method. Standard spray and turbulence models are used to describe the gas phase and the liquid phase. A turbulent methanol/air spray flame is simulated using the present method. Detailed chemistry is implemented through the spray flamelet model. The precalculated spray flamelet library for methanol/air combustion comprises 23 species and 168 elementary reactions. Thus, the model is capable of predicting the formation of radicals and of pollutants. Different values for the model constant C{sub {phi}} in the IEM model are tested. The numerical results for the gas velocity, the gas temperature, and the mass fraction of methanol vapor are compared with experimental data in the literature. Good agreement with experiment is obtained when C{sub {phi}}=2.0. Marginal PDFs of mixture fraction, enthalpy, and gas temperature are presented. The computed PDFs of mixture fraction are compared with the presumed standard {beta} function and modified {beta} function. The results show that the standard {beta} function fails to reproduce bimodal shapes observed in transported PDF computation, while the modified {beta} function, fits the computed PDFs very well. Moreover, joint PDFs of mixture fraction and enthalpy are presented and analyzed. The enthalpy and mixture fraction are strongly correlated. The samples that deviate from the linear correlation are due to the energy consumption of local spray evaporation. (author)

  6. Plasma sprayed manganese-cobalt spinel coatings: Process sensitivity on phase, electrical and protective performance

    NASA Astrophysics Data System (ADS)

    Han, Su Jung; Pala, Zdenek; Sampath, Sanjay

    2016-02-01

    Manganese cobalt spinel (Mn1.5Co1.5O4, MCO) coatings are prepared by the air plasma spray (APS) process to examine their efficacy in serving as protective coatings from Cr-poisoning of the cathode side in intermediate temperature-solid oxide fuel cells (IT-SOFCs). These complex oxides are susceptible to process induced stoichiometric and phase changes which affect their functional performance. To critically examine these effects, MCO coatings are produced with deliberate modifications to the spray process parameters to explore relationship among process conditions, microstructure and functional properties. The resultant interplay among particle thermal and kinetic energies are captured through process maps, which serve to characterize the parametric effects on properties. The results show significant changes to the chemistry and phase composition of the deposited material resulting from preferential evaporation of oxygen. Post deposition annealing recovers oxygen in the coatings and allows partial recovery of the spinel phase, which is confirmed through thermo-gravimetric analysis (TGA)/differential scanning calorimetry (DSC), X-ray Diffraction (XRD), and magnetic hysteresis measurements. In addition, coatings with high density after sintering show excellent electrical conductivity of 40 S cm-1 at 800 °C while simultaneously providing requisite protection characteristics against Cr-poisoning. This study provides a framework for optimal evaluation of MCO coatings in intermediate temperature SOFCs.

  7. Post-heat treatment pressure effect on performances of metal-supported solid oxide fuel cells fabricated by atmospheric plasma spraying

    NASA Astrophysics Data System (ADS)

    Tsai, Chun-Huang; Hwang, Chang-sing; Chang, Chun-Liang; Yu, Jen-Feng; Nien, Sheng-Hui

    2012-01-01

    The nickel metal-supported cells fabricated by atmospheric plasma spraying are post-heat treated in air at 960 °C for 2 h with different pressures. The current-voltage-power and AC impedance measurements show the prepared cell with an applied pressure of 450 g cm-2 in the post-heat treatment has a better electrochemical performance at test temperatures ≥ 650 °C. For test temperatures < 650 °C, the maximum power densities at 450 g cm-2 pressure are about the same as the maximum power densities at 1250 g cm-2 pressure. The SEM micrograph indicates that the cathode including the cathode interlayer and the cathode collector is the most porous region in the cell. AC impedance results show this cathode is the most sensitive part to the applied pressure in the post-heat treatment and the cell with 450 g cm-2 pressure has the smallest low frequency intercept R2 and the polarization resistance Rp at temperatures from 600 to 800 °C. The performance durability test of the cell post-heat treated at 450 g cm-2 pressure shows a degradation rate of 0.0087 mV h-1 or 0.0026 mW h-1 at 300 mA cm-2 constant current density and 750 °C test temperature.

  8. Microwave and Millimeter Wave Imaging of the Space Shuttle External Fuel Tank Spray on Foam Insulation (SOFI) Using Synthetic Aperture Focusing Techniques (SAFT)

    NASA Technical Reports Server (NTRS)

    Case, J. T.; Robbins, J.; Kharkovshy, S.; Hepburn, F. L.; Zoughi, R.

    2005-01-01

    The Space Shuttle Columbia's catastrophic failure is thought to have been caused by a dislodged piece of external tank SOFI (Spray On Foam Insulation) striking the left wing of the orbiter causing significant damage to some of the reinforced carbodcarbon leading edge wing panels. Microwave and millimeter wave nondestructive evaluation methods, have shown great potential for inspecting the SOFI for the purpose of detecting anomalies such as small voids that may cause separation of the foam from the external tank during the launch. These methods are capable of producing relatively high-resolution images of the interior of SOH particularly when advanced imaging algorithms are incorporated into the overall system. To this end, synthetic aperture focusing techniques are being deveioped for this purpose. These iechniqiies pradiice high-resolution images that are independent of the distance of the imaging probe to the SOFI with spatial resolution in the order of the half size of imaging probe aperture. At microwave and millimeter wave frequencies these apertures are inherently small resulting in high-resolution images. This paper provides the results of this investigation using 2D and 3D SAF based methods and holography. The attributes of these methods and a full discussion of the results will also be provided.

  9. 40 CFR 1051.110 - What evaporative emission standards must my vehicles meet?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... the hose. (c) You may certify your fuel tanks and fuel lines under the provisions of 40 CFR part 1060... 40 Protection of Environment 34 2012-07-01 2012-07-01 false What evaporative emission standards... Emission Standards and Related Requirements § 1051.110 What evaporative emission standards must my...

  10. 40 CFR 1051.110 - What evaporative emission standards must my vehicles meet?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... the hose. (c) You may certify your fuel tanks and fuel lines under the provisions of 40 CFR part 1060... 40 Protection of Environment 34 2013-07-01 2013-07-01 false What evaporative emission standards... Emission Standards and Related Requirements § 1051.110 What evaporative emission standards must my...

  11. 40 CFR 1051.110 - What evaporative emission standards must my vehicles meet?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... the hose. (c) You may certify your fuel tanks and fuel lines under the provisions of 40 CFR part 1060... 40 Protection of Environment 33 2014-07-01 2014-07-01 false What evaporative emission standards... Emission Standards and Related Requirements § 1051.110 What evaporative emission standards must my...

  12. 40 CFR 1051.110 - What evaporative emission standards must my vehicles meet?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... the hose. (c) You may certify your fuel tanks and fuel lines under the provisions of 40 CFR part 1060... 40 Protection of Environment 32 2010-07-01 2010-07-01 false What evaporative emission standards... Emission Standards and Related Requirements § 1051.110 What evaporative emission standards must my...

  13. Chromium coatings by HVOF thermal spraying: Simulation and practical results

    SciTech Connect

    Knotek, O.; Lugscheider, E.; Jokiel, P.; Schnaut, U.; Wiemers, A.

    1994-12-31

    Within recent years High Velocity Oxygen-Fuel (HVOF) thermal spraying has been considered an asset to the family of thermal spraying processes. Especially for spray materials with melting points below 3,000 K it has proven successful, since it shows advantages when compared to coating processes that produce similar qualities. In order to enlarge the fields of thermal spraying applications into regions with rather low thickness, e.g. about 50--100 {micro}m, especially HVOF thermally sprayed coatings seem to be advantageous. The usual evaluation of optimized spraying parameters, including spray distance, traverse speed, gas flow rates etc. is, however, based on numerous and extensive experiments laid out by trial-and-error or statistical experimental design and thus being expensive: man-power and material is required, spray systems are occupied for experimental works and the optimal solution is questioned, for instance, when a new powder fraction or nozzle is used. In this paper the possibility of reducing such experimental efforts by using modeling and simulation is exemplified for producing thin chromium coatings with a CDS{trademark}-HVOF system. The aim is the production of thermally sprayed chromium coatings competing with galvanic hard chromium platings, which are applied to reduce friction and corrosion but are environmentally disadvantageous during their production.

  14. Warm Spray Forming of Ti-6Al-4V

    NASA Astrophysics Data System (ADS)

    Molak, R. M.; Araki, H.; Watanabe, M.; Katanoda, H.; Ohno, N.; Kuroda, S.

    2014-01-01

    Warm spray (WS) is a modification of high-velocity oxy-fuel spraying, in which the temperature of the supersonic gas flow generated by the combustion of kerosene and oxygen is controlled by diluting the combustion flame with an inert gas such as nitrogen. The inert gas is injected into the mixing chamber placed between the combustion chamber and the powder feed ports, thus the temperature of the propellant gas can be controlled from ~700 to 2,000 K. Since WS allows for higher particle temperatures in comparison to cold spray, warm sprayed particles are more softened upon impact, thus resulting in greater deformation facilitating the formation of shear instability for bonding. Recently, the combustion pressure of WS has been increased from 1 (low-pressure warm spray) to 4 MPa (high-pressure warm spray) in order to increase the velocity of sprayed particles. Effects of spray parameters on microstructure, mechanical properties, and splats formation of Ti-6Al-4V were systematically studied. Obtained coatings were examined by analyzing the coating cross-section images, microhardness as well as oxygen content. In addition, flattening ratio of splats was calculated as a function of nitrogen flow rate. It was found that the increased particle velocity caused by the increased combustion pressure had significant beneficial effects in terms of improving density and controlling the oxygen level in the sprayed Ti-6Al-4V coatings.

  15. Optimization of evaporative cooling

    NASA Astrophysics Data System (ADS)

    Sackett, C. A.; Bradley, C. C.; Hulet, R. G.

    1997-05-01

    Recent experiments have used forced evaporative cooling to produce Bose-Einstein condensation in dilute gases. The evaporative cooling process can be optimized to provide the maximum phase-space density with a specified number of atoms remaining. We show that this global optimization is approximately achieved by locally optimizing the cooling efficiency at each instant. We discuss how this method can be implemented, and present the results for our 7Li trap. The predicted behavior of the gas is found to agree well with experiment.

  16. Investigation on the suitability of plasma sprayed Fe Cr Al coatings as tritium permeation barrier

    NASA Astrophysics Data System (ADS)

    Fazio, C.; Stein-Fechner, K.; Serra, E.; Glasbrenner, H.; Benamati, G.

    1999-08-01

    Results on the fabrication of a tritium permeation barrier by spraying Fe-Cr-Al powders are described. The sprayed coatings were deposited at temperatures below the Ac1 temperature of the ferritic-martensitic steel substrate and no post-deposition heat treatment was applied. The aim of the investigation was the determination of the efficiency of the coatings to act as tritium permeation barrier. Metallurgical investigations as well as hydrogen isotope permeation measurements were carried out onto the produced coatings. The depositions were performed on ferritic-martensitic steels by means of three types of spray techniques: high velocity oxy fuel, air plasma spray and vacuum plasma spray.

  17. Cold spray nozzle design

    DOEpatents

    Haynes, Jeffrey D.; Sanders, Stuart A.

    2009-06-09

    A nozzle for use in a cold spray technique is described. The nozzle has a passageway for spraying a powder material, the passageway having a converging section and a diverging section, and at least the diverging section being formed from polybenzimidazole. In one embodiment of the nozzle, the converging section is also formed from polybenzimidazole.

  18. SPRAY ATOMIZATION MODELS

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Crop protection product labels are now being written with spray droplet spectra classification terms that have specific definitions. Some of these terms are the same as previously used for generic descriptions such as fine or coarse sprays, but these terms used on new product labels have very speci...

  19. Environmentally compatible spray cement

    SciTech Connect

    Loeschnig, P.

    1995-12-31

    Within the framework of a European research project, Heidelberger Zement developed a quickly setting and hardening binder for shotcrete, called Chronolith S, which avoids the application of setting accelerators. Density and strength of the shotcrete produced with this spray cement correspond to those of an unaccelerated shotcrete. An increased hazard for the heading team and for the environment, which may occur when applying setting accelerators, can be excluded here. Owing to the special setting properties of a spray cement, the process engineering for its manufacturing is of great importance. The treatment of a spray cement as a dry concrete with kiln-dried aggregates is possible without any problems. The use of a naturally damp pre-batched mixture is possible with Chronolith S but requires special process engineering; spray cement and damp aggregate are mixed with one another immediately before entering the spraying machinery.

  20. Spray Rolling Aluminum Strip

    SciTech Connect

    Lavernia, E.J.; Delplanque, J-P; McHugh, K.M.

    2006-05-10

    Spray forming is a competitive low-cost alternative to ingot metallurgy for manufacturing ferrous and non-ferrous alloy shapes. It produces materials with a reduced number of processing steps, while maintaining materials properties, with the possibility of near-net-shape manufacturing. However, there are several hurdles to large-scale commercial adoption of spray forming: 1) ensuring strip is consistently flat, 2) eliminating porosity, particularly at the deposit/substrate interface, and 3) improving material yield. Through this program, a new strip/sheet casting process, termed spray rolling, has been developed, which is an innovative manufacturing technique to produce aluminum net-shape products. Spray rolling combines the benefits of twin-roll casting and conventional spray forming, showing a promising potential to overcome the above hurdles associated with spray forming. Spray rolling requires less energy and generates less scrap than conventional processes and, consequently, enables the development of materials with lower environmental impacts in both processing and final products. Spray Rolling was developed as a collaborative project between the University of California-Davis, the Colorado School of Mines, the Idaho National Engineering and Environmental Laboratory, and an industry team. The following objectives of this project were achieved: (1) Demonstration of the feasibility of the spray rolling process at the bench-scale level and evaluation of the materials properties of spray rolled aluminum strip alloys; and (2) Demonstration of 2X scalability of the process and documentation of technical hurdles to further scale up and initiate technology transfer to industry for eventual commercialization of the process.

  1. Current Status and Future Prospects of Warm Spray Technology

    NASA Astrophysics Data System (ADS)

    Kuroda, Seiji; Watanabe, Makoto; Kim, Keehyun; Katanoda, Hiroshi

    2011-06-01

    A modification of high-velocity oxy-fuel (HVOF) thermal spray process named as warm spray (WS) has been developed. By injecting room temperature inert gas into the combustion gas jet of HVOF, the temperature of the propellant gas can be controlled in a range approximately from 2300 to 1000 K so that many powder materials can be deposited in thermally softened state at high impact velocity. In this review, the characteristics of WS process were analyzed by using gas dynamic simulation of the flow field and heating/acceleration of powder particles in comparison with HVOF, cold spray (CS), and high-velocity air-fuel (HVAF) spray. Transmission electron microscopy of WS and CS titanium splats revealed marked differences in the microstructures stemming from the different impact temperatures. Mechanical properties of several metallic coatings formed under different WS and CS conditions were compared. Characteristics of WC-Co coatings made by WS were demonstrated for wear resistant applications.

  2. Parametric study on a compound-drop spray flame

    NASA Astrophysics Data System (ADS)

    Hsuan, Chung-Yao; Lin, Ta-Hui

    2012-06-01

    The introduction of compound-drop spray in a combustion system is a new concept. These droplets bear two gasification stages to cause an integral positive or negative effect on a premixed flame to raise or lower the local temperature of the gasification region. In this paper, we adopt a compound drop which contains a water core encased by a layer of shell fuel. A one-dimensional homogeneous lean or rich premixed flame with the dilute compound-drop spray was investigated by using large activation energy asymptotic analysis. The compound-drop spray burning mode was defined and divided into completely pre-vaporised burning (CPB), shell pre-vaporised burning (SPB) and shell partially pre-vaporised (SPP) burning modes by way of the gasification zones of the shell fuel and the core water relative to the flame position. The influences of the initial droplet radius, the shell-fuel mass fraction and the liquid loading of the compound-drop spray on the lean and rich flames were analysed. By means of the normalisation parameter of flame propagation mass flux (?), enhancement, suppression or extinction of the compound-drop spray flame can be represented clearly. Furthermore, from the observation of extinction, the necessary conditions of extinction of a lean spray flame by the internal heat transfer are that the spray is a negative effect and causes a sufficient heat loss rate at flame sheet downstream side. For a rich spray flame, three extinction patterns were observed; they occur in SPP, SPB or at the critical SPB mode, but do not in CPB. The extinction maps of the compound-drop spray demarcate the patterns and also indicate the limitations and corresponding conditions of the flame extinction.

  3. An overview of spray drift reduction testing of spray nozzles

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The importance of the development and testing of drift reduction technologies (DRTs) is increasing. Common spray drift reduction technologies include spray nozzles and spray adjuvants. Following draft procedures developed for a DRT program, three spray nozzles were tested under high air speed cond...

  4. Polydisperse spray diffusion flames in oscillating flow

    NASA Astrophysics Data System (ADS)

    Greenberg, Jerrold Barry; Katoshevski, David

    2016-03-01

    The phenomenon of droplet clustering or grouping found when a spray of droplets is moving in an oscillating host flow field is investigated for the case of a polydisperse spray that fuels a laminar co-flow diffusion flame. A mathematical solution is developed for the liquid phase based on use of small Stokes numbers for size sections into which the polydisperse spray size distribution is divided. Droplet clustering in the oscillatory flow field is accounted for by constructing a special model for the sectional vaporization Damkohler numbers in accordance with droplet size. Combining this with a formal solution for a gas phase Schvab-Zel'dovich variable yields the means whereby flame dynamics can be described. Results calculated from this solution demonstrate that preferential droplet size behaviour (with smaller droplets tending to cluster to a greater extent and reduce the vaporization Damkohler number more than larger ones) can have a major impact on the flame dynamics through local droplet enrichment with attendant consequences on the production of fuel vapour. The dynamics of the sort of flame (over- or under-ventilated) and the occurrence of flame pinching leading to multiple flame sheets are altered under these circumstances. However, potential control of the actual initial spray polydispersity may reduce the intensity of such effects.

  5. Mesoporous-silica films, fibers, and powders by evaporation

    DOEpatents

    Bruinsma, Paul J.; Baskaran, Suresh; Bontha, Jagannadha R.; Liu, Jun

    2008-05-06

    This invention pertains to surfactant-templated nanometer-scale porosity of a silica precursor solution and forming a mesoporous material by first forming the silica precursor solution into a preform having a high surface area to volume ratio, then rapid drying or evaporating a solvent from the silica precursor solution. The mesoporous material may be in any geometric form, but is preferably in the form of a film, fiber, powder or combinations thereof. The rapid drying or evaporation of solvent from the solution is accomplished by layer thinning, for example spin casting, liquid drawing, and liquid spraying respectively. Production of a film is by layer thinning, wherein a layer of the silica precursor solution is formed on a surface followed by removal of an amount of the silica precursor solution and leaving a geometrically thinner layer of the silica precursor solution from which the solvent quickly escapes via evaporation. Layer thinning may be by any method including but not limited to squeegeeing and/or spin casting. In powder formation by spray drying, the same conditions of fast drying exists as in spin-casting (as well as in fiber spinning) because of the high surface-area to volume ratio of the product. When a powder is produced by liquid spraying, the particles or micro-bubbles within the powder are hollow spheres with walls composed of mesoporous silica. Mesoporous fiber formation starts with a similar silica precursor solution but with an added pre-polymer making a pituitous mixture that is drawn into a thin strand from which solvent is evaporated leaving the mesoporous fiber(s).

  6. Mesoporous-silica films, fibers, and powders by evaporation

    DOEpatents

    Bruinsma, Paul J.; Baskaran, Suresh; Bontha, Jagannadha R.; Liu, Jun

    1999-01-01

    This invention pertains to surfactant-templated nanometer-scale porosity of a silica precursor solution and forming a mesoporous material by first forming the silica precursor solution into a preform having a high surface area to volume ratio, then rapid drying or evaporating a solvent from the silica precursor solution. The mesoporous material may be in any geometric form, but is preferably in the form of a film, fiber, powder or combinations thereof. The rapid drying or evaporation of solvent from the solution is accomplished by layer thinning, for example spin casting, liquid drawing, and liquid spraying respectively. Production of a film is by layer thinning, wherein a layer of the silica precursor solution is formed on a surface followed by removal of an amount of the silica precursor solution and leaving a geometrically thinner layer of the silica precursor solution from which the solvent quickly escapes via evaporation. Layer thinning may be by any method including but not limited to squeegeeing and/or spin casting. In powder formation by spray drying, the same conditions of fast drying exists as in spin-casting (as well as in fiber spinning) because of the high surface-area to volume ratio of the product. When a powder is produced by liquid spraying, the particles or micro-bubbles within the powder are hollow spheres with walls composed of mesoporous silica. Mesoporous fiber formation starts with a similar silica precursor solution but with an added pre-polymer making a pituitous mixture that is drawn into a thin strand from which solvent is evaporated leaving the mesoporous fiber(s).

  7. Mesoporous-silica films, fibers, and powders by evaporation

    DOEpatents

    Bruinsma, P.J.; Baskaran, S.; Bontha, J.R.; Liu, J.

    1999-07-13

    This invention pertains to surfactant-templated nanometer-scale porosity of a silica precursor solution and forming a mesoporous material by first forming the silica precursor solution into a preform having a high surface area to volume ratio, then rapid drying or evaporating a solvent from the silica precursor solution. The mesoporous material may be in any geometric form, but is preferably in the form of a film, fiber, powder or combinations thereof. The rapid drying or evaporation of solvent from the solution is accomplished by layer thinning, for example spin casting, liquid drawing, and liquid spraying respectively. Production of a film is by layer thinning, wherein a layer of the silica precursor solution is formed on a surface followed by removal of an amount of the silica precursor solution and leaving a geometrically thinner layer of the silica precursor solution from which the solvent quickly escapes via evaporation. Layer thinning may be by any method including but not limited to squeegeeing and/or spin casting. In powder formation by spray drying, the same conditions of fast drying exists as in spin-casting (as well as in fiber spinning) because of the high surface-area to volume ratio of the product. When a powder is produced by liquid spraying, the particles or micro-bubbles within the powder are hollow spheres with walls composed of mesoporous silica. Mesoporous fiber formation starts with a similar silica precursor solution but with an added pre-polymer making a pituitous mixture that is drawn into a thin strand from which solvent is evaporated leaving the mesoporous fiber(s). 24 figs.

  8. MOVES2014: Evaporative Emissions Report

    EPA Science Inventory

    Vehicle evaporative emissions are now modeled in EPA’s MOVES according to physical processes, permeation, tank vapor venting, liquid leaks, and refueling emissions. With this update, the following improvements are being incorporated into MOVES evaporative emissions methodology, a...

  9. Evaporation of pure liquid sessile and spherical suspended drops: a review.

    PubMed

    Erbil, H Yildirim

    2012-01-15

    A sessile drop is an isolated drop which has been deposited on a solid substrate where the wetted area is limited by a contact line and characterized by contact angle, contact radius and drop height. Diffusion-controlled evaporation of a sessile drop in an ambient gas is an important topic of interest because it plays a crucial role in many scientific applications such as controlling the deposition of particles on solid surfaces, in ink-jet printing, spraying of pesticides, micro/nano material fabrication, thin film coatings, biochemical assays, drop wise cooling, deposition of DNA/RNA micro-arrays, and manufacture of novel optical and electronic materials in the last decades. This paper presents a review of the published articles for a period of approximately 120 years related to the evaporation of both sessile drops and nearly spherical droplets suspended from thin fibers. After presenting a brief history of the subject, we discuss the basic theory comprising evaporation of micrometer and millimeter sized spherical drops, self cooling on the drop surface and evaporation rate of sessile drops on solids. The effects of drop cooling, resultant lateral evaporative flux and Marangoni flows on evaporation rate are also discussed. This review also has some special topics such as drop evaporation on superhydrophobic surfaces, determination of the receding contact angle from drop evaporation, substrate thermal conductivity effect on drop evaporation and the rate evaporation of water in liquid marbles. PMID:22277832

  10. Program Models A Laser Beam Focused In An Aerosol Spray

    NASA Technical Reports Server (NTRS)

    Barton, J. P.

    1996-01-01

    Monte Carlo analysis performed on packets of light. Program for Analysis of Laser Beam Focused Within Aerosol Spray (FLSPRY) developed for theoretical analysis of propagation of laser pulse optically focused within aerosol spray. Applied for example, to analyze laser ignition arrangement in which focused laser pulse used to ignite liquid aerosol fuel spray. Scattering and absorption of laser light by individual aerosol droplets evaluated by use of electromagnetic Lorenz-Mie theory. Written in FORTRAN 77 for both UNIX-based computers and DEC VAX-series computers. VAX version of program (LEW-16051). UNIX version (LEW-16065).

  11. Modeling of Plasma Spray Processes

    NASA Astrophysics Data System (ADS)

    Chang, Chong H.

    1996-10-01

    A comprehensive computational model for thermal plasma processes is being developed with sufficient generality and flexibility to apply to a wide variety of present and proposed plasma processing concepts and devices. In our model for gas-particle flows, the gas is represented as a continuous multicomponent chemically reacting gas with temperature-dependent thermodynamic and transport properties. Ions and electrons are considered as separate components or species of the mixture, while ionization and dissociation reactions are treated as chemical reactions. Entrained particles interacting with the plasma are represented by a stochastic particle model in which the velocities, temperatures, sizes, and other characteristics of typical particles are computed simultaneously with the plasma flow. The model in its present form can simulate particle injection, heating, and melting, but not evaporation and condensation. This model is embodied in the LAVA computer code, which has previously been applied to simulate plasma spraying, mixing and demixing of plasma gases, and departures from chemical (ionization/dissociation), thermal, and excitation equilibrium in plasmas. A transient simulation has been performed of stainless steel particles injected into a swirling high-velocity nitrogen-hydrogen plasma jet in air under typical operating conditions for a newly developed high-velocity high-power (HVHP) torch, which produces plasma jets with peak velocities in excess of 3000 m/s. The calculational results show that strong departures from ionization and dissociation equilibrium develop in the downstream region as the chemical reactions freeze out at lower temperatures. The calculational results also show good agreement with experimental data on particle temperature, velocity, and spray pattern, together with important statistical effects associated with distributions in particle properties and injection conditions. This work was performed under the auspices of the U. S

  12. Spray drift mitigation with spray mix adjuvants

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Numerous drift reduction adjuvants and spray deposition aids are available to applicators of crop production and protection chemicals. Performance of many of the newly introduced drift control adjuvants has not been well documented for aerial application. Four new drift control adjuvants were sele...

  13. Evaporation and deposition coverage of single droplets on various waxy surfaces

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The droplet evaporation and residual coverage area on surfaces with various waxy conditions was investigated to improve the foliar spray application efficiency. The investigation was conducted with an environmental-controlled chamber under controlled laboratory conditions. A stereoscope and a high...

  14. Thermal Arc Spray Overview

    NASA Astrophysics Data System (ADS)

    Hafiz Abd Malek, Muhamad; Hayati Saad, Nor; Kiyai Abas, Sunhaji; Mohd Shah, Noriyati

    2013-06-01

    Usage of protective coating for corrosion protection was on highly demand during the past decade; and thermal spray coating played a major part during that time. In recent years, the thermal arc spray coating becomes a popular coating. Many big players in oil and gas such as PETRONAS, EXXON MOBIL and SHELL in Malaysia tend to use the coating on steel structure as a corrosion protection. Further developments in coating processes, the devices, and raw materials have led to expansion of functional coatings and applications scope from conventional coating to specialized industries. It is widely used because of its ability to withstand high process temperature, offer advantages in efficiency, lower cost and acts as a corrosion protection. Previous research also indicated that the thermal arc spray offers better coating properties compared to other methods of spray. This paper reviews some critical area of thermal spray coating by discussing the process/parameter of thermal arc spray technology and quality control of coating. Coating performance against corrosion, wear and special characteristic of coating are also described. The field application of arc spray technology are demonstrated and reviewed.

  15. Method of producing thermally sprayed metallic coating

    DOEpatents

    Byrnes, Larry Edward; Kramer, Martin Stephen; Neiser, Richard A.

    2003-08-26

    The cylinder walls of light metal engine blocks are thermally spray coated with a ferrous-based coating using an HVOF device. A ferrous-based wire is fed to the HVOF device to locate a tip end of the wire in a high temperature zone of the device. Jet flows of oxygen and gaseous fuel are fed to the high temperature zone and are combusted to generate heat to melt the tip end. The oxygen is oversupplied in relation to the gaseous fuel. The excess oxygen reacts with and burns a fraction of the ferrous-based feed wire in an exothermic reaction to generate substantial supplemental heat to the HVOF device. The molten/combusted metal is sprayed by the device onto the walls of the cylinder by the jet flow of gases.

  16. Evaporated VOx Thin Films

    NASA Astrophysics Data System (ADS)

    Stapinski, Tomasz; Leja, E.

    1989-03-01

    VOx thin films on glass were obtained by thermal evaporation of V205, powder. The structural investigations were carried out with the use of X-ray diffractometer. The electrical properties of the film were examined by means of temperature measurements of resistivity for the samples heat-treated in various conditions. Optical transmission and reflection spectra of VOX films of various composition showed the influence of the heat treatment.

  17. Falling film evaporator

    DOEpatents

    Bruns, Lester E.

    1976-01-01

    A falling film evaporator including a vertically oriented pipe heated exteriorly by a steam jacket and interiorly by a finned steam tube, all heating surfaces of the pipe and steam tube being formed of a material wet by water such as stainless steel, and packing within the pipe consisting of Raschig rings formed of a material that is not wet by water such as polyvinylidene fluoride.

  18. Vertical counterflow evaporative cooler

    DOEpatents

    Bourne, Richard C.; Lee, Brian Eric; Callaway, Duncan

    2005-01-25

    An evaporative heat exchanger having parallel plates that define alternating dry and wet passages. A water reservoir is located below the plates and is connected to a water distribution system. Water from the water distribution system flows through the wet passages and wets the surfaces of the plates that form the wet passages. Air flows through the dry passages, mixes with air below the plates, and flows into the wet passages before exiting through the top of the wet passages.

  19. Measuring forest floor evaporation from interception in prescribed burned forests in Southern Italy.

    NASA Astrophysics Data System (ADS)

    Giuditta, Elisabetta; Coenders-Gerrits, Miriam; Bogaard, Thom; Wenninger, Jochen; Greco, Roberto; Ialongo, Gianluca; Esposito, Assunta; Rutigliano, Flora Angela

    2016-04-01

    Wildfires are one of the major environmental issue in the Mediterranean area. Prescribed burning (PB) is increasingly used in Europe as a practice to reduce fire risk, through dead fine fuel reduction. Several studies have focused on fire effects on vegetation and soil microbial community, but very few on ecosystem processes involved in water cycle. This study aims to estimate interception by the litter and fermentation layer and the successive evaporation flux in laboratory conditions, using a water balance and 2H and 18O isotopes mass balance calculation, in order to assess PB effects on the hydrology and ecosystem in pine plantations. PB was carried out in spring 2014 in three pine plantations of Southern Italy, dominated by Pinus halepensis (Cilento, Vallo di Diano e Alburni National Park, CVDANP), P. pinaster (Vesuvio National Park, VNP) and P. pinea (Castel Volturno Nature Reserve, CVNR). A dataset concerning the effects of PB on vegetation structure, floristic composition, microbial biomass and activity in the fermentation layer and 5-cm of soil beneath is available for the same stands. In each plantation, two cores of litter and fermentation layer were sampled in a burned area and in a near unburned area (control), respectively, with a collector to extract an "undisturbed" core. Then, each core was transferred in a lysimeter installed in the Water Lab of Delft University of Technology. In total, three lysimeters were set up and each experiment was carried out in duplicate. The laboratory had constant temperature, and both temperature and relative humidity were recorded every 15 minutes. To simulate rainfall, ~1 litre of tap water was sprinkled uniformly on the lysimeter with a plant spray (equivalent to 32 mm of rain). The precipitation was sprinkled every 3 days for a period of two months. Soil moisture and temperature were measured during the experiment every 15 minutes in the top and bottom of the litter and fermentation layer. Interception water was

  20. Water Membrane Evaporator

    NASA Technical Reports Server (NTRS)

    Ungar, Eugene K.; Almlie, Jay C.

    2010-01-01

    A water membrane evaporator (WME) has been conceived and tested as an alternative to the contamination-sensitive and corrosion-prone evaporators currently used for dissipating heat from space vehicles. The WME consists mainly of the following components: An outer stainless-steel screen that provides structural support for the components mentioned next; Inside and in contact with the stainless-steel screen, a hydrophobic membrane that is permeable to water vapor; Inside and in contact with the hydrophobic membrane, a hydrophilic membrane that transports the liquid feedwater to the inner surface of the hydrophobic membrane; Inside and in contact with the hydrophilic membrane, an annular array of tubes through which flows the spacecraft coolant carrying the heat to be dissipated; and An inner exclusion tube that limits the volume of feedwater in the WME. In operation, a pressurized feedwater reservoir is connected to the volume between the exclusion tube and the coolant tubes. Feedwater fills the volume, saturates the hydrophilic membrane, and is retained by the hydrophobic membrane. The outside of the WME is exposed to space vacuum. Heat from the spacecraft coolant is conducted through the tube walls and the water-saturated hydrophilic membrane to the liquid/vapor interface at the hydrophobic membrane, causing water to evaporate to space. Makeup water flows into the hydrophilic membrane through gaps between the coolant tubes.

  1. A spray-suppression model for turbulent combustion

    SciTech Connect

    DESJARDIN,PAUL E.; TIESZEN,SHELDON R.; GRITZO,LOUIS A.

    2000-02-14

    A spray-suppression model that captures the effects of liquid suppressant on a turbulent combusting flow is developed and applied to a turbulent diffusion flame with water spray suppression. The spray submodel is based on a stochastic separated flow approach that accounts for the transport and evaporation of liquid droplets. Flame extinguishment is accounted for by using a perfectly stirred reactor (PSR) submodel of turbulent combustion. PSR pre-calculations of flame extinction times are determined using CHEMKIN and are compared to local turbulent time scales of the flow to determine if local flame extinguishment has occurred. The PSR flame extinguishment and spray submodels are incorporated into Sandia's flow fire simulation code, VULCAN, and cases are run for the water spray suppression studies of McCaffrey for turbulent hydrogen-air jet diffusion flames. Predictions of flame temperature decrease and suppression efficiency are compared to experimental data as a function of water mass loading using three assumed values of drop sizes. The results show that the suppression efficiency is highly dependent on the initial droplet size for a given mass loading. A predicted optimal suppression efficiency was observed for the smallest class of droplets while the larger drops show increasing suppression efficiency with increasing mass loading for the range of mass loadings considered. Qualitative agreement to the experiment of suppression efficiency is encouraging, however quantitative agreement is limited due to the uncertainties in the boundary conditions of the experimental data for the water spray.

  2. Plasma Spray System

    NASA Technical Reports Server (NTRS)

    1980-01-01

    Computer aided, fully-automatic TRW system sprays very hot plasma onto a turbine blade. Composed of gas into which metallic and ceramic powders have been injected, the plasma forms a two-layer coating which insulates the blade. Critical part of operation is controlling the thickness of the deposit which is measured in thousandths of an inch. This is accomplished by an optical detector which illuminates spots at various locations on the blade and determines thickness by measuring the light reflections. Optical sensor monitors spraying process until precise thickness is attained, then computer halts the spraying.

  3. Measurement of spray combustion processes

    NASA Technical Reports Server (NTRS)

    Peters, C. E.; Arman, E. F.; Hornkohl, J. O.; Farmer, W. M.

    1984-01-01

    A free jet configuration was chosen for measuring noncombusting spray fields and hydrocarbon-air spray flames in an effort to develop computational models of the dynamic interaction between droplets and the gas phase and to verify and refine numerical models of the entire spray combustion process. The development of a spray combustion facility is described including techniques for laser measurements in spray combustion environments and methods for data acquisition, processing, displaying, and interpretation.

  4. Exploration of Impinging Water Spray Heat Transfer at System Pressures Near the Triple Point

    NASA Technical Reports Server (NTRS)

    Golliher, Eric L.; Yao, Shi-Chune

    2013-01-01

    The heat transfer of a water spray impinging upon a surface in a very low pressure environment is of interest to cooling of space vehicles during launch and re-entry, and to industrial processes where flash evaporation occurs. At very low pressure, the process occurs near the triple point of water, and there exists a transient multiphase transport problem of ice, water and water vapor. At the impingement location, there are three heat transfer mechanisms: evaporation, freezing and sublimation. A preliminary heat transfer model was developed to explore the interaction of these mechanisms at the surface and within the spray.

  5. Dropwise Evaporative Cooling of Heated Surfaces with Various Wettability Characteristics Obtained by Nanostructure Modifications

    NASA Astrophysics Data System (ADS)

    Chen, Jian-nan; Zhang, Zhen; Ouyang, Xiao-long; Jiang, Pei-xue

    2016-03-01

    A numerical and experimental investigation was conducted to analyze dropwise evaporative cooling of heated surfaces with various wettability characteristics. The surface wettability was tuned by nanostructure modifications. Spray-cooling experiments on these surfaces show that surfaces with better wettability have better heat transfer rate and higher critical heat flux (CHF). Single droplet impingement evaporative cooling of a heated surface was then investigated numerically with various wettability conditions to characterize the effect of contact angle on spray-cooling heat transfer. The volume of fluid (VOF) model with variable-time stepping was used to capture the time-dependent liquid-gas interface motion throughout the computational domain with the kinetic theory model used to predict the evaporation rate at the liquid-gas interface. The numerical results agree with the spray-cooling experiments that dropwise evaporative cooling is much better on surfaces with better wettability because of the better liquid spreading and convection, better liquid-solid contact, and stronger liquid evaporation.

  6. Dropwise Evaporative Cooling of Heated Surfaces with Various Wettability Characteristics Obtained by Nanostructure Modifications.

    PubMed

    Chen, Jian-Nan; Zhang, Zhen; Ouyang, Xiao-Long; Jiang, Pei-Xue

    2016-12-01

    A numerical and experimental investigation was conducted to analyze dropwise evaporative cooling of heated surfaces with various wettability characteristics. The surface wettability was tuned by nanostructure modifications. Spray-cooling experiments on these surfaces show that surfaces with better wettability have better heat transfer rate and higher critical heat flux (CHF). Single droplet impingement evaporative cooling of a heated surface was then investigated numerically with various wettability conditions to characterize the effect of contact angle on spray-cooling heat transfer. The volume of fluid (VOF) model with variable-time stepping was used to capture the time-dependent liquid-gas interface motion throughout the computational domain with the kinetic theory model used to predict the evaporation rate at the liquid-gas interface. The numerical results agree with the spray-cooling experiments that dropwise evaporative cooling is much better on surfaces with better wettability because of the better liquid spreading and convection, better liquid-solid contact, and stronger liquid evaporation. PMID:27003427

  7. Experimental investigation of synfuel spray characteristics and combustion dynamics. Quarterly technical progress report, January 1-March 31, 1981

    SciTech Connect

    1981-04-01

    Objective is to study both petroleum-based oils and synthetic fuels in spray combustion, by using advanced optical diagnostic techniques to study the processes of fuel injection and atomization, droplet ignition, and spray flame combustion. During this period, efforts were focused on the completion of the cold spray test facility, the design of the monodisperse droplet combustor, and the construction of an oil burner with the gathering of preliminary holography data. (DLC)

  8. A numerical simulation of the dispersal of aerial sprays

    NASA Technical Reports Server (NTRS)

    Bragg, M. B.

    1981-01-01

    A computer program was developed to predict the trajectory, ground deposition, and drift of liquid sprays injected into the wake of an agricultural aircraft in ground effect. The program uses a horseshoe vortex wake model and includes the effects of liquid droplet evaporation, crosswind, the propeller slipstream, ground effect, and tunnel walls on small scale models. This user's guide includes several case examples demonstrating user options. A complete listing of the FORTRAN program is provided.

  9. Normal evaporation of binary alloys

    NASA Technical Reports Server (NTRS)

    Li, C. H.

    1972-01-01

    In the study of normal evaporation, it is assumed that the evaporating alloy is homogeneous, that the vapor is instantly removed, and that the alloy follows Raoult's law. The differential equation of normal evaporation relating the evaporating time to the final solute concentration is given and solved for several important special cases. Uses of the derived equations are exemplified with a Ni-Al alloy and some binary iron alloys. The accuracy of the predicted results are checked by analyses of actual experimental data on Fe-Ni and Ni-Cr alloys evaporated at 1600 C, and also on the vacuum purification of beryllium. These analyses suggest that the normal evaporation equations presented here give satisfactory results that are accurate to within an order of magnitude of the correct values, even for some highly concentrated solutions. Limited diffusion and the resultant surface solute depletion or enrichment appear important in the extension of this normal evaporation approach.

  10. Supersonic-Spray Cleaner

    NASA Technical Reports Server (NTRS)

    Caimi, Raoul E. B.; Lin, Feng-Nan; Thaxton, Eric A.

    1995-01-01

    Spraying system for cleaning mechanical components uses less liquid and operates at pressures significantly lower. Liquid currently used is water. Designed to replace chlorofluorocarbon (CFC) solvent-based cleaning and cleanliness verification methods. Consists of spray head containing supersonic converging/diverging nozzles, source of gas at regulated pressure, pressurized liquid tank, and various hoses, fittings, valves, and gauges. Parameters of nozzles set so any of large variety of liquids and gases combined in desired ratio and rate of flow. Size and number of nozzles varied so system built in configurations ranging from small hand-held spray heads to large multinozzle cleaners. Also used to verify part adequately cleaned. Runoff liquid from spray directed at part collected. Liquid analyzed for presence of contaminants, and part recleaned if necessary.

  11. Bug spray poisoning

    MedlinePlus

    ... effective bug sprays contain pyrethrins. Pyrethrins are a pesticide made from the chrysanthemum flower. It is generally ... death. References Borron SW. Pyrethrins, repellants, and other pesticides. In: Shannon MW, Borron SW, Burns MJ, eds. ...

  12. Mometasone Nasal Spray

    MedlinePlus

    ... sneezing, stuffy, runny, itchy nose) caused by the common cold. Mometasone nasal spray is in a class of ... taking, as well as any products such as vitamins, minerals, or other dietary supplements. You should bring ...

  13. Beclomethasone Nasal Spray

    MedlinePlus

    ... relieve symptoms of sneezing, runny, stuffy, or itchy nose (rhinitis) caused by hay fever, other allergies, or ... nasal polyps (swelling of the lining of the nose) after nasal polyp removal surgery. Beclomethasone nasal spray ...

  14. Budesonide Nasal Spray

    MedlinePlus

    ... used to relieve sneezing, runny, stuffy, or itchy nose caused by hay fever or other allergies (caused ... treat symptoms (e.g., sneezing, stuffy, runny, itchy nose) caused by the common cold. Budesonide nasal spray ...

  15. Mometasone Nasal Spray

    MedlinePlus

    ... relieve symptoms of sneezing, runny, stuffy, or itchy nose caused by hay fever or other allergies. It ... nasal polyps (swelling of the lining of the nose). Mometasone nasal spray should not be used to ...

  16. Bug spray poisoning

    MedlinePlus

    ... effective bug sprays contain pyrethrins. Pyrethrins are a pesticide made from the chrysanthemum flower. It is generally ... Borron SW. Pyrethrins, repellants, and other pesticides. In: Shannon ... of Poisoning and Drug Overdose . 4th ed. Philadelphia, PA: ...

  17. Olopatadine Nasal Spray

    MedlinePlus

    ... a stuffy, runny or itchy nose caused by allergic rhinitis (hay fever). Olopatadine is in a class of ... Olopatadine nasal spray controls the symptoms of seasonal allergic rhinitis, but does not cure these condition. Continue to ...

  18. Nasal corticosteroid sprays

    MedlinePlus

    ... Allergic rhinitis symptoms , such as congestion, runny nose, sneezing, itching, or swelling of the nasal passageway Nasal ... Repeat these steps for the other nostril. Avoid sneezing or blowing your nose right after spraying.

  19. Nicotine Nasal Spray

    MedlinePlus

    ... the bottle in front of a tissue or paper towel. Pump the spray bottle six to eight times ... up the spill immediately with a cloth or paper towel. Avoid touching the liquid. Throw away the used ...

  20. Beclomethasone Nasal Spray

    MedlinePlus

    ... the lining of the nose) after nasal polyp removal surgery. Beclomethasone nasal spray should not be used ... as well as any products such as vitamins, minerals, or other dietary supplements. You should bring this ...

  1. Ciclesonide Nasal Spray

    MedlinePlus

    ... used to treat the symptoms of seasonal (occurs only at certain times of the year), and perennial ( ... prescribed by your doctor.Ciclesonide nasal spray is only for use in the nose. Do not swallow ...

  2. Fentanyl Sublingual Spray

    MedlinePlus

    Fentanyl sublingual spray is used to treat breakthrough pain (sudden episodes of pain that occur despite round ... effects of the medication) to narcotic pain medications. Fentanyl is in a class of medications called narcotic ( ...

  3. Fentanyl Nasal Spray

    MedlinePlus

    Fentanyl nasal spray is used to treat breakthrough pain (sudden episodes of pain that occur despite round ... effects of the medication) to narcotic pain medications. Fentanyl is in a class of medications called narcotic ( ...

  4. Spray applicator for spraying coatings and other fluids in space

    NASA Technical Reports Server (NTRS)

    Kuminecz, J. F.; Lausten, M. F. (Inventor)

    1985-01-01

    A self contained spray application is developed for one handed operation in a zero gravity vacuum environment by a free flying astronaut not attached to any spacecraft. This spray applicator eliminates contamination of the operator by back spray. This applicator includes a rigid accumulator containment of a fluid within a flexible bladder the fluid being urged out of the accumulator under pressure through a spray gun. The spray gun includes a spring loaded lockable trigger which controls a valve. When in an open position, the fluid passes through the valve into the ambient environment in the form of a spray. A spray shield is provided which directs the flow of the spray from the applicator by trapping errant particles of spray yet allowing the passage of escaping gases through its material.

  5. Metal atomization spray nozzle

    DOEpatents

    Huxford, Theodore J.

    1993-01-01

    A spray nozzle for a magnetohydrodynamic atomization apparatus has a feed passage for molten metal and a pair of spray electrodes mounted in the feed passage. The electrodes, diverging surfaces which define a nozzle throat and diverge at an acute angle from the throat. Current passes through molten metal when fed through the throat which creates the Lorentz force necessary to provide atomization of the molten metal.

  6. Metal atomization spray nozzle

    DOEpatents

    Huxford, T.J.

    1993-11-16

    A spray nozzle for a magnetohydrodynamic atomization apparatus has a feed passage for molten metal and a pair of spray electrodes mounted in the feed passage. The electrodes, diverging surfaces which define a nozzle throat and diverge at an acute angle from the throat. Current passes through molten metal when fed through the throat which creates the Lorentz force necessary to provide atomization of the molten metal. 6 figures.

  7. Directed spray mast

    DOEpatents

    Nance, Thomas A.; Siddall, Alvin A.; Cheng, William Y.; Counts, Kevin T.

    2005-05-10

    Disclosed is an elongated, tubular, compact high pressure sprayer apparatus for insertion into an access port of vessels having contaminated interior areas that require cleaning by high pressure water spray. The invention includes a spray nozzle and a camera adjacent thereto with means for rotating and raising and lowering the nozzle so that areas identified through the camera may be cleaned with a minimum production of waste water to be removed.

  8. Thermally sprayed coatings

    SciTech Connect

    Diaz, D.J.; Blann, G.A. )

    1991-05-01

    Standardization of specimen preparation for microstructural evaluation of thermally sprayed coatings is considered. Metallographic specimen preparation procedures including sectioning, encapsulation, planar grinding, and power lapping of thermally sprayed coatings are described. A Co-Ni-Cr-W coating on an AISI 410 stainless steel substrate is used as a control sample. Specimen-preparation techniques have been evaluated through scanning electron microscopy for determining the percentage of apparent porosity and energy dispersive spectroscopy for determining elemental composition.

  9. Fabrication of copper-based anodes via atmosphoric plasma spraying techniques

    DOEpatents

    Lu, Chun

    2012-04-24

    A fuel electrode anode (18) for a solid oxide fuel cell is made by presenting a solid oxide fuel cell having an electrolyte surface (15), mixing copper powder with solid oxide electrolyte in a mixing step (24, 44) to provide a spray feedstock (30,50) which is fed into a plasma jet (32, 52) of a plasma torch to melt the spray feed stock and propel it onto an electrolyte surface (34, 54) where the spray feed stock flattens into lamellae layer upon solidification, where the layer (38, 59) is an anode coating with greater than 35 vol. % based on solids volume.

  10. Method of evaporation

    NASA Technical Reports Server (NTRS)

    Dufresne, Eugene R.

    1987-01-01

    Liquids, such as juices, milk, molten metal and the like are concentrated by forming uniformly-sized, small droplets in a precision droplet forming assembly and deploying the droplets in free fall downwardly as a central column within an evacuated column with cool walls. A portion of the solvent evaporates. The vapor flows to the wall, condenses, and usually flows down the wall as a film to condensate collector and drain. The vertical column of freely falling droplets enters the splash guard. The condensate can be collected, sent to other towers or recycled.

  11. SPRAY CALCINATION REACTOR

    DOEpatents

    Johnson, B.M.

    1963-08-20

    A spray calcination reactor for calcining reprocessin- g waste solutions is described. Coaxial within the outer shell of the reactor is a shorter inner shell having heated walls and with open regions above and below. When the solution is sprayed into the irner shell droplets are entrained by a current of gas that moves downwardly within the inner shell and upwardly between it and the outer shell, and while thus being circulated the droplets are calcined to solids, whlch drop to the bottom without being deposited on the walls. (AEC) H03 H0233412 The average molecular weights of four diallyl phthalate polymer samples extruded from the experimental rheometer were redetermined using the vapor phase osmometer. An amine curing agent is required for obtaining suitable silver- filled epoxy-bonded conductive adhesives. When the curing agent was modified with a 47% polyurethane resin, its effectiveness was hampered. Neither silver nor nickel filler impart a high electrical conductivity to Adiprenebased adhesives. Silver filler was found to perform well in Dow-Corning A-4000 adhesive. Two cascaded hot-wire columns are being used to remove heavy gaseous impurities from methane. This purified gas is being enriched in the concentric tube unit to approximately 20% carbon-13. Studies to count low-level krypton-85 in xenon are continuing. The parameters of the counting technique are being determined. The bismuth isotopes produced in bismuth irradiated for polonium production are being determined. Preliminary data indicate the presence of bismuth207 and bismuth-210m. The light bismuth isotopes are probably produced by (n,xn) reactions bismuth-209. The separation of uranium-234 from plutonium-238 solutions was demonstrated. The bulk of the plutonium is removed by anion exchange, and the remainder is extracted from the uranium by solvent extraction techniques. About 99% of the plutonium can be removed in each thenoyltrifluoroacetone extraction. The viscosity, liquid density, and

  12. Lanthanide-based laser-induced phosphorescence for spray diagnostics

    NASA Astrophysics Data System (ADS)

    van der Voort, D. D.; Maes, N. C. J.; Lamberts, T.; Sweep, A. M.; van de Water, W.; Kunnen, R. P. J.; Clercx, H. J. H.; van Heijst, G. J. F.; Dam, N. J.

    2016-03-01

    Laser-induced phosphorescence (LIP) is a relatively recent and versatile development for studying flow dynamics. This work investigates certain lanthanide-based molecular complexes for their use in LIP for high-speed sprays. Lanthanide complexes in solutions have been shown to possess long phosphorescence lifetimes (˜1-2 ms) and to emit light in the visible wavelength range. In particular, europium and terbium complexes are investigated using fluorescence/phosphorescence spectrometry, showing that europium-thenoyltrifluoracetone-trioctylphosphineoxide (Eu-TTA-TOPO) can be easily and efficiently excited using a standard frequency-tripled Nd:YAG laser. The emitted spectrum, with maximum intensity at a wavelength of 614 nm, is shown not to vary strongly with temperature (293-383 K). The decay constant of the phosphorescence, while independent of ambient pressure, decreases by approximately 12 μs/K between 323 and 373 K, with the base level of the decay constant dependent on the used solvent. The complex does not luminesce in the gas or solid state, meaning only the liquid phase is visualized, even in an evaporating spray. By using an internally excited spray containing the phosphorescent complex, the effect of vaporization is shown through the decrease in measured intensity over the length of the spray, together with droplet size measurements using interferometric particle imaging. This study shows that LIP, using the Eu-TTA-TOPO complex, can be used with different solvents, including diesel surrogates. Furthermore, it can be easily handled and used in sprays to investigate spray breakup and evaporation.

  13. Lanthanide-based laser-induced phosphorescence for spray diagnostics.

    PubMed

    van der Voort, D D; Maes, N C J; Lamberts, T; Sweep, A M; van de Water, W; Kunnen, R P J; Clercx, H J H; van Heijst, G J F; Dam, N J

    2016-03-01

    Laser-induced phosphorescence (LIP) is a relatively recent and versatile development for studying flow dynamics. This work investigates certain lanthanide-based molecular complexes for their use in LIP for high-speed sprays. Lanthanide complexes in solutions have been shown to possess long phosphorescence lifetimes (∼1-2 ms) and to emit light in the visible wavelength range. In particular, europium and terbium complexes are investigated using fluorescence/phosphorescence spectrometry, showing that europium-thenoyltrifluoracetone-trioctylphosphineoxide (Eu-TTA-TOPO) can be easily and efficiently excited using a standard frequency-tripled Nd:YAG laser. The emitted spectrum, with maximum intensity at a wavelength of 614 nm, is shown not to vary strongly with temperature (293-383 K). The decay constant of the phosphorescence, while independent of ambient pressure, decreases by approximately 12 μs/K between 323 and 373 K, with the base level of the decay constant dependent on the used solvent. The complex does not luminesce in the gas or solid state, meaning only the liquid phase is visualized, even in an evaporating spray. By using an internally excited spray containing the phosphorescent complex, the effect of vaporization is shown through the decrease in measured intensity over the length of the spray, together with droplet size measurements using interferometric particle imaging. This study shows that LIP, using the Eu-TTA-TOPO complex, can be used with different solvents, including diesel surrogates. Furthermore, it can be easily handled and used in sprays to investigate spray breakup and evaporation. PMID:27036779

  14. Development and Application of HVOF Sprayed Spinel Protective Coating for SOFC Interconnects

    NASA Astrophysics Data System (ADS)

    Thomann, O.; Pihlatie, M.; Rautanen, M.; Himanen, O.; Lagerbom, J.; Mäkinen, M.; Varis, T.; Suhonen, T.; Kiviaho, J.

    2013-06-01

    Protective coatings are needed for metallic interconnects used in solid oxide fuel cell (SOFC) stacks to prevent excessive high-temperature oxidation and evaporation of chromium species. These phenomena affect the lifetime of the stacks by increasing the area-specific resistance (ASR) and poisoning of the cathode. Protective MnCo2O4 and MnCo1.8Fe0.2O4 coatings were applied on ferritic steel interconnect material (Crofer 22 APU) by high velocity oxy fuel spraying. The substrate-coating systems were tested in long-term exposure tests to investigate their high-temperature oxidation behavior. Additionally, the ASRs were measured at 700 °C for 1000 h. Finally, a real coated interconnect was used in a SOFC single-cell stack for 6000 h. Post-mortem analysis was carried out with scanning electron microscopy. The deposited coatings reduced significantly the oxidation of the metal, exhibited low and stable ASR and reduced effectively the migration of chromium.

  15. Spray and High-Pressure Flow Computations in the National Combustion Code (NCC) Improved

    NASA Technical Reports Server (NTRS)

    Raju, Manthena S.

    2002-01-01

    Sprays occur in a wide variety of industrial and power applications and in materials processing. A liquid spray is a two-phase flow with a gas as the continuous phase and a liquid as the dispersed phase in the form of droplets or ligaments. The interactions between the two phases--which are coupled through exchanges of mass, momentum, and energy--can occur in different ways at disparate time and length scales involving various thermal, mass, and fluid dynamic factors. An understanding of the flow, combustion, and thermal properties of a rapidly vaporizing spray requires careful modeling of the ratecontrolling processes associated with turbulent transport, mixing, chemical kinetics, evaporation, and spreading rates of the spray, among many other factors. With the aim of developing an efficient solution procedure for use in multidimensional combustor modeling, researchers at the NASA Glenn Research Center have advanced the state-of-the-art in spray computations in several important ways.

  16. Some Characteristics of Sprays Obtained from Pintle-type Injection Nozzles

    NASA Technical Reports Server (NTRS)

    Marsh, E. T.; Waldron, C. D.

    1933-01-01

    This report presents the results of tests made with the pintle-type injection nozzles, one having a pintle angle of 8 degrees, the other a pintle angle of 30 degrees. The fuel was injected into a glass-windowed pressure chamber and the spray photographed by means of the N.A.C.A. spray photography apparatus. Curves are presented that give the penetration of the spray tips when fuel oil is injected by pressures of 1,500 to 4,000 pounds per square inch into air at room temperature and densities of 11 to 18 atmospheres. High-speed spark photographs show the appearance of the sprays in air at a density of 18 atmospheres. The results indicate that the pintle angles have little effect on the size of the spray cone angle, which is about the same as that of sprays from plain round hole orifices. The penetration of the spray from the nozzle with an 8 degree pintle is slightly higher than that of the spray from the nozzle with a 30 degree pintle. The penetration of the sprays from the pintle nozzles, for comparable conditions of injection pressure and air density, is about the same as that of sprays from round-hole orifices. Increase in air density decreases the penetration in about the same ratio with all the injection pressures.

  17. Plasma sprayed and electrospark deposited zirconium metal diffusion barrier coatings

    SciTech Connect

    Hollis, Kendall J; Pena, Maria I

    2010-01-01

    Zirconium metal coatings applied by plasma spraying and electrospark deposition (ESD) have been investigated for use as diffusion barrier coatings on low enrichment uranium fuel for research nuclear reactors. The coatings have been applied to both stainless steel as a surrogate and to simulated nuclear fuel uranium-molybdenum alloy substrates. Deposition parameter development accompanied by coating characterization has been performed. The structure of the plasma sprayed coating was shown to vary with transferred arc current during deposition. The structure of ESD coatings was shown to vary with the capacitance of the deposition equipment.

  18. Reservoir evaporation in Texas, USA

    NASA Astrophysics Data System (ADS)

    Wurbs, Ralph A.; Ayala, Rolando A.

    2014-03-01

    The role of reservoir surface evaporation in river/reservoir water budgets and water management is explored using a modeling system that combines historical natural hydrology with current conditions of water resources development and management. The long-term mean evaporation from the 3415 reservoirs in the Texas water rights permit system is estimated to be 7.53 billion m3/year, which is equivalent to 61% of total agricultural or 126% of total municipal water use in the state during the year 2010. Evaporation varies with the hydrologic conditions governing reservoir surface areas and evaporation rates. Annual statewide total evaporation volumes associated with exceedance probabilities of 75%, 50%, and 25% are 7.07, 7.47, and 7.95 billion m3/year, respectively. Impacts of evaporation are greatest during extended severe droughts that govern water supply capabilities.

  19. Representative shuttle evaporative heat sink

    NASA Technical Reports Server (NTRS)

    Hixon, C. W.

    1978-01-01

    The design, fabrication, and testing of a representative shuttle evaporative heat sink (RSEHS) system which vaporizes an expendable fluid to provide cooling for the shuttle heat transport fluid loop is reported. The optimized RSEHS minimum weight design meets or exceeds the shuttle flash evaporator system requirements. A cold trap which cryo-pumps flash evaporator exhaust water from the CSD vacuum chamber test facility to prevent water contamination of the chamber pumping equipment is also described.

  20. Evaporation control research, 1959-60

    USGS Publications Warehouse

    U.S. Geological Survey

    1963-01-01

    Two hundred and forty-five dispersions of long-chain alkanols were formulated by using various emulsifiers and alkanols. The dispensing and spreading ability of each of these formulations was tested. The most promising emulsifier that could be used with any of the alkanols was glyceryl monostearate (self-emulsifying). However, the concentration of the alkanol in the dispersion form varied somewhat: with the length of the carbon chain. A maximum concentration of 16 percent was obtained using the longer chain alkanols in the dispersion form without losing any of the properties of a fluid. Nine field tests were undertaken on small stock tanks. The retardant materials used in these tests were dodecanol, hexadecanol, and octadecanol. These materials were applied in either liquid or dispersion form. Four types of dispensing equipment were tested. The first type used a pressure system which sprayed a liquid onto the surface of the water. An anemometer and wind-controlled vane, operated by an electrical system, determined the length End frequency of application. The second type was similar to the first except that gravity was utilized to force the liquid onto the surface. The third type. used a drip system with rates of about 10 drops per minute. The fourth type used a gravity feed and a wind-controlled valve which allowed the dispersion material to flow onto the surface of the water when the wind was in the proper direction. In the field tests, the best reduction in evaporation was obtained using octadecanol in dispersion form and dispensed with the wind-controlled valve and gravity feed system. The maximum reduction in evaporation for a 2-week period was 27 percent. However, the economics of suppressing evaporation from stock tanks is questionable because of the short travel time across the tank by the film. There are still many problems unsolved. Some of these can be resolved in the laboratory whereas others can be resolved only in the field. Some of the more serious

  1. Thermal spray processing

    SciTech Connect

    Herman, H.; Berndt, C.C.

    1995-03-01

    Thermal spray processing has been used for a number of years to cost-effecticely apply TBC`s for a wide range of heat engine applications. In particular, bond coats are applied by plasma spray and HVOF techniques and partially-stabilized zirconia top coats are applied by plasma spray methods. Thermal spray involves melting and rapid transport of the molten particles to the substrate, where high-rate solidification and coating build-up occur. It is the very nature of this melt processing that leads to the unique layered microstructure, as well as the apparent imperfections, so readily identified with thermal spray. Modeling the process, process-induced residual stresses, and thermal conductivity will be discussed in light of a new understanding of porosity and its anisotropy. Microcracking can be understood using new approaches, allowing a fuller view of the processing-performance connection. Detailed electron microscopic, novel neutron diffraction and fracture analysis of the deposits can lead to a better understanding of how overall microstructure can be controlled to influence critical properties of the deposited TBC system.

  2. Thermal spray processing

    NASA Technical Reports Server (NTRS)

    Herman, H.; Berndt, C. C.

    1995-01-01

    Thermal spray processing has been used for a number of years to cost-effecticely apply TBC's for a wide range of heat engine applications. In particular, bond coats are applied by plasma spray and HVOF techniques and partially-stabilized zirconia top coats are applied by plasma spray methods. Thermal spray involves melting and rapid transport of the molten particles to the substrate, where high-rate solidification and coating build-up occur. It is the very nature of this melt processing that leads to the unique layered microstructure, as well as the apparent imperfections, so readily identified with thermal spray. Modeling the process, process-induced residual stresses, and thermal conductivity will be discussed in light of a new understanding of porosity and its anisotropy. Microcracking can be understood using new approaches, allowing a fuller view of the processing-performance connection. Detailed electron microscopic, novel neutron diffraction and fracture analysis of the deposits can lead to a better understanding of how overall microstructure can be controlled to influence critical properties of the deposited TBC system.

  3. HVOF and plasma sprayed molybdenum coatings -- microstructure and properties

    SciTech Connect

    Zimmermann, S.; Kreye, H.

    1995-12-31

    High velocity oxy-fuel (HVOF) and plasma spray experiments were carried out to investigate the oxidation mechanism of molybdenum in the spray process and to determine how the various process parameters affect the microstructure and properties of the coatings. HVOF coatings exhibit their highest hardness and wear resistance at an oxygen content of 6 to 8% by weight. Such an oxygen level can be achieved with Mo and Mo-MoO{sub 2} composite powders as well. In the plasma spray process oxidation of molybdenum is less pronounced and Mo-MoO{sub 2} composite powders containing 6 to 8% oxygen have to be used to obtain similar properties as compared to HVOF-coatings. When Mo-Mo{sub 2}C composite powders are used oxidation of molybdenum becomes greatly reduced and highly wear resistant coatings are obtained at a low hardness level in both spray processes.

  4. Supercritical fuel injection system

    NASA Technical Reports Server (NTRS)

    Marek, C. J.; Cooper, L. P. (Inventor)

    1980-01-01

    a fuel injection system for gas turbines is described including a pair of high pressure pumps. The pumps provide fuel and a carrier fluid such as air at pressures above the critical pressure of the fuel. A supercritical mixing chamber mixes the fuel and carrier fluid and the mixture is sprayed into a combustion chamber. The use of fuel and a carrier fluid at supercritical pressures promotes rapid mixing of the fuel in the combustion chamber so as to reduce the formation of pollutants and promote cleaner burning.

  5. Structure of confined laminar spray diffusion flames: Numerical investigation

    NASA Technical Reports Server (NTRS)

    Mawid, M. A.; Bulzan, D. L.; Aggarwal, S. K.

    1993-01-01

    The structure of confined laminar spray diffusion flames is investigated numerically by solving the gas-phase conservation equations for mass species, continuity, momentum, and energy and the liquid-phase equations for droplet position, velocity, size, and temperature. A one-step global reaction scheme along with six equilibrium reactions are employed to model the flame chemistry. Monodisperse as well as polydisperse sprays are considered. The numerical results demonstrate that liquid spray flames substantially differ from gaseous flames in their structure, i.e., temperature, concentration, and velocity fields, shape, and dimensions under the same conditions. Spray flames are predicted to be taller and narrower than their counterpart gaseous ones and their shapes are almost cylindrical. This is in agreement with experimental observations. The numerical computations also show that the use of the equilibrium reactions with the one-step reaction scheme decreases the flame temperature compared to the one-step reaction scheme without the equilibrium reactions and more importantly increases the surface area of the flame zone due to a phenomenon termed 'equilibrium broadening.' The spray flames also possess a finite thickness with minimal overlap of the fuel and oxygen species. A case for which a fuel-mixture consisting of 20 to 80 percent gas-liquid by mass is introduced into the combustor is also investigated and compared with predictions using only gaseous or liquid fuel.

  6. Turkish Undergraduates' Misconceptions of Evaporation, Evaporation Rate, and Vapour Pressure

    ERIC Educational Resources Information Center

    Canpolat, Nurtac

    2006-01-01

    This study focused on students' misconceptions related to evaporation, evaporation rate, and vapour pressure. Open-ended diagnostic questions were used with 107 undergraduates in the Primary Science Teacher Training Department in a state university in Turkey. In addition, 14 students from that sample were interviewed to clarify their written…

  7. Miniature spray-painting booth

    NASA Technical Reports Server (NTRS)

    Fee, K. W.

    1970-01-01

    Transparent spray booth provides method for quality painting and repair of surfaces in clean room or other specialized environments. Overspray and virtually all contaminating vapor and odor can be eliminated. Touch-up painting is achieved with spray gun.

  8. Numerical Investigation of Evaporating Droplets with Direct Quadrature-Based Moments of Closure Method

    NASA Astrophysics Data System (ADS)

    Jamaly, Seyed Mohammad; Hasan Saidi, Mohammad; Ghafourian, Akbar

    2007-11-01

    In this study, due to the weaknesses of the models with Lagrangian approaches, an attempt has been made to model the spray flow with Eulerian approach. In this regard, the quadrature-based moment closure model for the spray equation, the so-called DQMOM, is applied. This method overcomes the shortcoming of other Eulerian methods while it is in good agreement with the Lagrangian methods. After that, the model has been developed to be able to deal with the evaporating droplets. Moreover, the feasibility of applying non-linear external forces, such as drag forces, and evaporation laws for the droplets are considered and implemented. The required order for the equations in this method has been studied thoroughly as well. Finally, the solution procedure for accurate computations of multi dimension problems is presented. In general, the proposed modified DQMOM method can consider and solve all kinds of spray flows with any desirable dimension for the problem. Here, assuming one-way coupling situation with the gas-phase in an axial engine, the spray phase equations are solved by the proposed method to account for evaporating droplets. Results are compared with the methods with Lagrangian approach and the computational costs and accuracies of the methods are compared as well.

  9. 40 CFR 1045.112 - What are the standards for evaporative emissions?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ...? Fuel systems must meet the evaporative emission requirements of 40 CFR part 1060 as specified in this... lines must meet the permeation requirements specified in 40 CFR 1060.102 for EPA NRFL fuel lines as... specified in 40 CFR 1060.103. Portable marine fuel tanks must meet permeation standards starting January...

  10. 40 CFR 1045.112 - What are the standards for evaporative emissions?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...? Fuel systems must meet the evaporative emission requirements of 40 CFR part 1060 as specified in this... lines must meet the permeation requirements specified in 40 CFR 1060.102 for EPA NRFL fuel lines as... specified in 40 CFR 1060.103. Portable marine fuel tanks must meet permeation standards starting January...

  11. 40 CFR 1045.112 - What are the standards for evaporative emissions?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ...? Fuel systems must meet the evaporative emission requirements of 40 CFR part 1060 as specified in this... lines must meet the permeation requirements specified in 40 CFR 1060.102 for EPA NRFL fuel lines as... specified in 40 CFR 1060.103. Portable marine fuel tanks must meet permeation standards starting January...

  12. 40 CFR 1045.112 - What are the standards for evaporative emissions?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ...? Fuel systems must meet the evaporative emission requirements of 40 CFR part 1060 as specified in this... lines must meet the permeation requirements specified in 40 CFR 1060.102 for EPA NRFL fuel lines as... specified in 40 CFR 1060.103. Portable marine fuel tanks must meet permeation standards starting January...

  13. 40 CFR 1045.112 - What are the standards for evaporative emissions?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...? Fuel systems must meet the evaporative emission requirements of 40 CFR part 1060 as specified in this... lines must meet the permeation requirements specified in 40 CFR 1060.102 for EPA NRFL fuel lines as... specified in 40 CFR 1060.103. Portable marine fuel tanks must meet permeation standards starting January...

  14. Impact of Sea Spray on Air-Sea Fluxes

    NASA Astrophysics Data System (ADS)

    Veron, Fabrice; Mueller, James

    2013-11-01

    The contributions of sea spray drops to the total air-sea exchanges of momentum, heat, and mass remain an open question. A number of factors obscure any simple quantification of their contribution: the number of drops formed at the ocean surface and the per-drop contribution to the fluxes. To estimate these per-droplet fluxes, we present results from a large number of drop trajectories, which are simulated with a recently developed Lagrangian Stochastic model adapted for the heavy drop transport and evaporation within the marine boundary layer. Then, using commonly accepted spray generation functions we present estimates of spray fluxes which account for the mediating feedback effects from the droplets on the atmosphere. The results suggest that common simplifications in previous sea spray models, such as the residence time in the marine boundary layer, may not be appropriate. We further show that the spray fluxes may be especially sensitive to the size distribution of the drops. The total effective air-sea fluxes lead to drag and enthalpy coefficients that increase modestly with wind speed. The rate of increase for the drag coefficient is greatest at moderate wind speeds, while the rate of increase for the enthalpy coefficient is greatest at higher wind speeds. Funded by grants OCE-0850663 and OCE-0748767 from the National Science Foundation.

  15. Modeling of Bulk Evaporation and Condensation

    NASA Technical Reports Server (NTRS)

    Anghaie, S.; Ding, Z.

    1996-01-01

    This report describes the modeling and mathematical formulation of the bulk evaporation and condensation involved in liquid-vapor phase change processes. An internal energy formulation, for these phase change processes that occur under the constraint of constant volume, was studied. Compared to the enthalpy formulation, the internal energy formulation has a more concise and compact form. The velocity and time scales of the interface movement were obtained through scaling analysis and verified by performing detailed numerical experiments. The convection effect induced by the density change was analyzed and found to be negligible compared to the conduction effect. Two iterative methods for updating the value of the vapor phase fraction, the energy based (E-based) and temperature based (T-based) methods, were investigated. Numerical experiments revealed that for the evaporation and condensation problems the E-based method is superior to the T-based method in terms of computational efficiency. The internal energy formulation and the E-based method were used to compute the bulk evaporation and condensation processes under different conditions. The evolution of the phase change processes was investigated. This work provided a basis for the modeling of thermal performance of multi-phase nuclear fuel elements under variable gravity conditions, in which the buoyancy convection due to gravity effects and internal heating are involved.

  16. 40 CFR 1048.105 - What evaporative emission standards and requirements apply?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... requirements of 40 CFR part 1045. The vessels are not required to comply with the evaporative emission... 40 CFR part 86. They are not required to comply with the evaporative emission standards and related... manufacturers may alternatively use other fuel-system components that have been certified under 40 CFR part...

  17. Analysis of Evaporative On-Board Diagnostic (OBD) Readiness and DTCs Using I/M Data

    EPA Science Inventory

    Gasoline vehicles are equipped with evaporative emissions control systems that control vapor from the fuel storage system while a vehicle is sitting or driving. When these systems or the vehicle’s gasoline delivery system malfunction, excessive evaporative emissions can be emitte...

  18. Controlled overspray spray nozzle

    NASA Technical Reports Server (NTRS)

    Prasthofer, W. P. (Inventor)

    1981-01-01

    A spray system for a multi-ingredient ablative material wherein a nozzle A is utilized for suppressing overspray is described. The nozzle includes a cyclindrical inlet which converges to a restricted throat. A curved juncture between the cylindrical inlet and the convergent portion affords unrestricted and uninterrupted flow of the ablative material. A divergent bell-shaped chamber and adjustable nozzle exit B is utilized which provides a highly effective spray pattern in suppressing overspray to an acceptable level and producing a homogeneous jet of material that adheres well to the substrate.

  19. New techniques for spraying dust

    SciTech Connect

    Mukherjee, S.K.

    1984-06-01

    Two recent developments for reducing airborne dust on longwall faces are described. One flushes foam through the drums of a shearer and also sprays foam onto the cutting drum. The other modifies the spray-head to produce different water spray patterns on continuous miners.

  20. Programable Plasma-Spray System

    NASA Technical Reports Server (NTRS)

    Fetheroff, C. W.; Derkacs, T.; Matay, I. M.; Toth, I.

    1982-01-01

    NASA-funded research led to development of automated plasma-spray system programable and reproducible. System utilizes standard plasma-spray equipment with noncoherent light-measuring system and microprocessor. System monitors and controls surface contours and coating thickness. Other advantages of system are consistant coating reproducibility, exact blending and feathering operations, ability to handle complex shapes and ease of changing spray parameters.

  1. Sprayed Coating Renews Butyl Rubber

    NASA Technical Reports Server (NTRS)

    Martin, R. B.

    1982-01-01

    Damaged butyl rubber products are renewed by spray technique originally developed for protective suits worn by NASA workers. A commercial two-part adhesive is mixed with Freon-113 (or equivalent) trichlorotrifluoroethane to obtain optimum viscosity for spraying. Mix is applied with an external-air-mix spray gun.

  2. Gas detonation gun for thermal spraying

    SciTech Connect

    Kadyrov, E.; Kadyrov, V.

    1995-08-01

    High-velocity oxy-fuel and gas detonation are competing spray coating processes well known for providing premium quality coatings with low porosity and high adhesion. They are favored for applications in environments of extreme wear, heat, and aggressive corrosion. Nevertheless, they both have limitations. For the HVOF process, these include excessive gas consumption, high rate of heat transfer to the sprayed substrate, and the short life of the (supersonic) Laval nozzle. On the other hand, the traditional gas detonation gun also has drawbacks, and the purpose of this article is to outline some factors that led to the design of an improved gas detonation coating process called Demeton, produced by Demeton USA Inc., Garden City Park, N.Y.

  3. MODELING OF SO2 REMOVAL IN SPRAY-DRYER FLUE-GAS DESULFURIZATION SYSTEM

    EPA Science Inventory

    The report presents a comprehensive mathematical model of the SO2 removal process in a spray-dryer flue-gas desulfurization system. Simultaneous evaporation of a sorbent droplet and absorption/reaction of SO2 in the droplet are described by the corresponding heat- and mass-transf...

  4. An analysis on the blast initiation of spray detonations

    NASA Astrophysics Data System (ADS)

    Ohyagi, S.

    1982-02-01

    An analytic model for the transition from a blast to a spray detonation is presented, taking into account the droplet reaction zone. A continuum mixture is assumed, along with zero interaction between droplets, no thermal motions of the droplets, monodispersal, a perfect gas, no dissipation, disregard of the volume fraction of the droplets, no ignition delay, and a defined gasification rate. Introduction of an energy source into a uniformly dispersed spray of fuel and gaseous oxidizer is considered to produce a strong blast wave, for which governing equations are defined, as well as equations of state, boundary conditions, and necessary transformations. The blast wave moving through fuel sprays is solved with two-phase flow equations, by restricting the problem to when the chemical heat release is small. More realistic results are indicated to be available with inclusion of laws of drag and gasification in the model, along with a quasi-similar technique.

  5. Vacuum flash evaporated polymer composites

    DOEpatents

    Affinito, John D.; Gross, Mark E.

    1997-01-01

    A method for fabrication of polymer composite layers in a vacuum is disclosed. More specifically, the method of dissolving salts in a monomer solution, vacuum flash evaporating the solution, condensing the flash evaporated solution as a liquid film, and forming the condensed liquid film into a polymer composite layer on a substrate is disclosed.

  6. Vacuum flash evaporated polymer composites

    DOEpatents

    Affinito, J.D.; Gross, M.E.

    1997-10-28

    A method for fabrication of polymer composite layers in a vacuum is disclosed. More specifically, the method of dissolving salts in a monomer solution, vacuum flash evaporating the solution, condensing the flash evaporated solution as a liquid film, and forming the condensed liquid film into a polymer composite layer on a substrate is disclosed.

  7. Effects of chilling rate and spray-chilling on weight loss and tenderness in beef strip loin steaks.

    PubMed

    Prado, C S; de Felício, P E

    2010-10-01

    We evaluated the effects of chilling rate and the use of a spray-chilling system on the weight loss by evaporation on carcasses. We also evaluated the effects on meat purge in vacuum package, cooking losses, and on parameters related to the tenderness of strip loin steaks (M. longissimus lumborum). Forty non-castrated males of approximately 12 months old, finished in feed-lot were harvested in 16 Montana cattle (a composite breed), and 24 SimmentalxNellore crossbred cattle. After bleeding, the bodies were electrically stimulated and assigned to one of the four treatments: conventional air-chilling (CAC), conventional spray-chilling (CSC), slow air-chilling (SAC), and slow spray-chilling (SSC). Strip loin steaks (M. longissimus lumborum) of approximately 2.5 cm thick were removed, vacuum packed and aged for 7, 14, 30 or 60 days. Samples were analyzed for sarcomere length, myofibrillar fragmentation index, Warner-Bratzler shear force, and weight losses by purge and cooking. Spraying was efficient in reducing weight loss by evaporation (P<0.05). Effects of treatments and aging period on purge losses were observed, where samples from sprayed carcasses or aged cuts showed higher losses. Cooking losses were not affected either by spraying or aging. The slow chilling, with or without spraying, was more efficient in producing strip loin steaks with lower average shear force and longer sarcomere. The myofibrillar fragmentation index increased with aging time, but was not affected by carcasses spraying. PMID:20647150

  8. Photographic characterization of spark-ignition engine fuel injectors

    NASA Technical Reports Server (NTRS)

    Evanich, P. L.

    1978-01-01

    Manifold port fuel injectors suitable for use in general aviation spark-ignition engines were evaluated qualitatively on the basis of fuel spray characteristics. Photographs were taken at various fuel flow rates or pressure levels. Mechanically and electronically operated pintle injectors generally produced the most atomization. The plain-orifice injectors used on most fuel-injected general aviation engines did not atomize the fuel when sprayed into quiescent air.

  9. Experimental Investigation of Microstructured Evaporators

    NASA Astrophysics Data System (ADS)

    Wibel, W.; Westermann, S.; Maikowske, S.; Brandner, J. J.

    2012-11-01

    Microfluidic devices have become more and more popular over the last decades [1]. Cooling is a topic where microstructures offer significant advantages compared to conventional techniques due the much higher possible surface to volume ratios and short heat transfer lengths. By evaporating of a fluid in microchannels, compact, fast and powerful cooling devices become possible [2]. Experimental results for different designs of microstructured evaporators are presented here. They have been obtained either using water as evaporating coolant or the refrigerant R134a (Tetrafluoroethane). A new microstructured evaporator design consisting of bended microchannels instead of straight channels for a better performance is shown and compared to previous results [2] for the evaporation of R134a in straight microchannels.

  10. Molecular Mechanism of Water Evaporation

    NASA Astrophysics Data System (ADS)

    Nagata, Yuki; Usui, Kota; Bonn, Mischa

    2015-12-01

    Evaporation is the process by which water changes from a liquid to a gas or vapor, and is a key step in Earth's water cycle. At the molecular level, evaporation requires breaking at least one very strong intermolecular bond between two water molecules at the interface. Despite the importance of this process the molecular mechanism by which an evaporating water molecule gains sufficient energy to escape from the surface has remained elusive. Here, we show, using molecular dynamics simulations at the water-air interface with polarizable classical force field models, that the high kinetic energy of the evaporated water molecule is enabled by a well-timed making and breaking of hydrogen bonds involving at least three water molecules at the interface, the recoil of which allows one of the molecules to escape. The evaporation of water is thus enabled by concerted, ultrafast hydrogen-bond dynamics of interfacial water, and follows one specific molecular pathway.

  11. Simultaneous Analysis of the Dispersed Liquid and the Bulk Gas Phase of Water Sprays Using Raman Spectroscopy.

    PubMed

    Schuster, Julian Jonathan; Siegler, Philipp; Guenther, Astrid; Wirth, Karl-Ernst; Braeuer, Andreas Siegfried

    2016-06-01

    Currently, a comprehensive physical description of sprays is not possible, as the involved heat- and mass-transport mechanisms have not yet been understood completely. Therefore, we here show and apply a straightforward Raman evaluation technique which simultaneously probes spatially resolved (i) droplet temperature, (ii) evaporation progress and (iii) entrainment of air into the spray. First, the working principle of the Raman technique and the calibration of the sensor are described. Then, the applicability of the Raman technique is demonstrated showing example measurement results obtained from a superheated water spray. The plausibility of the obtained measurement results is demonstrated comparing them with computations for thermodynamic equilibrium conditions. Information about the droplet temperature, the evaporation progress and the entrainment of air might complement the insights into heat- and mass-transport mechanisms which can already be provided applying other existing optical spray diagnostic techniques. PMID:27091902

  12. A New Finite-Conductivity Droplet Evaporation Model Including Liquid Turbulence Effect

    NASA Technical Reports Server (NTRS)

    Balasubramanyam, M. S.; Chen, C. P.; Trinh, H. P.

    2006-01-01

    A new approach to account for finite thermal conductivity and turbulence effects within atomizing droplets of an evaporating spray is presented in this paper. The model is an extension of the T-blob and T-TAB atomization/spray model of Trinh and Chen [9]. This finite conductivity model is based on the two-temperature film theory in which the turbulence characteristics of the droplet are used to estimate the effective thermal diffusivity for the liquid-side film thickness. Both one-way and two-way coupled calculations were performed to investigate the performance cf this model against the published experimental data.

  13. Spray combustion stability project

    NASA Technical Reports Server (NTRS)

    Jeng, San-Mou; Litchford, Ron J.

    1992-01-01

    This report summarizes research activity on the Spray Combustion Stability Project, characterizes accomplishments and current status, and discusses projected future work. The purpose is to provide a concise conceptual overview of the research effort to date so the reader can quickly assimilate the gist of the research results and place them within the context of their potential impact on liquid rocket engine design technology.

  14. Ocean Spray Lubricates Winds

    ERIC Educational Resources Information Center

    Journal of College Science Teaching, 2005

    2005-01-01

    According to a new study by two University of California, Berkeley, mathematicians and their Russian colleague, the water droplets kicked up by rough seas serve to lubricate the swirling winds of hurricanes and cyclones, letting them build to speeds approaching 200 miles per hour. Without the lubricating effect of the spray, the mathematicians…

  15. Oxymetazoline Nasal Spray

    MedlinePlus

    ... is recommended by a doctor. Children 6 to 12 years of age should use oxymetazoline nasal spray carefully and under adult supervision. Oxymetazoline is in a class of medications called nasal decongestants. It works by narrowing the blood vessels in the nasal passages.

  16. Fluticasone Nasal Spray

    MedlinePlus

    ... improve. Follow the directions on your prescription or product label carefully, and ask your doctor or pharmacist to ... ingredients in fluticasone nasal spray. Check the package label for a list of the ... and herbal products you are taking, or have recently taken, or ...

  17. Titanium Cold Spray Coatings

    NASA Astrophysics Data System (ADS)

    Ajaja, Jihane; Goldbaum, Dina; Chromik, Richard; Yue, Stephen; Rezaeian, Ahmad; Wong, Wilson; Irissou, Eric; Legoux, Jean-Gabriel

    Titanium Cold Spray Coatings Cold Spray is an emerging technology used for the deposition of coatings for many industries including aerospace. This technique allows the deposition of metallic materials at low temper-atures below their melting point. The aim of this research was to develop a test technique that can measure the degree to which a cold spray coating achieves mechanical properties similar to a traditional bulk material. Vickers hardness testing and nanoindentation were used as micro-and nano-scale measurement techniques to characterize the mechanical properties of titanium coatings, deposited at different deposition conditions, and bulk Ti. The mechanical properties of bulk titanium and titanium coatings were measured over a range of length scales, with the indentation size effect examined with Meyer's law. Hardness measurements are shown to be affected by material porosity, microstructure and coating particle bonding mechanism. Hard-ness measurements showed that Ti coatings deposited at higher gas pressures and temperatures demonstrate an indentation load response similar to bulk Ti. Key words: titanium, cold spray, Vickers hardness, nanoindentation, indentation size effect, microstructure, mechanical properties

  18. Picosecond imaging of sprays

    NASA Technical Reports Server (NTRS)

    Breisacher, Kevin; Liou, Larry; Wang, L.; Liang, X.; Galland, P.; Ho, P. P.; Alfano, R. R.

    1994-01-01

    Preliminary results from applying a Kerr-Fourier imaging system to a water/air spray produced by a shear coaxial element are presented. The physics behind ultrafast time-gated optical techniques is discussed briefly. A typical setup of a Kerr-Fourier time gating system is presented.

  19. Zolmitriptan Nasal Spray

    MedlinePlus

    ... diarrhea and stomach pain caused by decreased blood flow to the intestines). Your doctor may tell you not to use zolmitriptan nasal spray.tell your doctor if you smoke or are overweight; if you have or have ever had high blood pressure, high cholesterol, diabetes, or liver or ...

  20. Naloxone Nasal Spray

    MedlinePlus

    ... symptoms, he or she should give you your first naloxone dose and then call 911 immediately. After receiving the naloxone nasal spray, ... the person on their side (recovery position) and call for emergency medical ... after giving the first naloxone dose. If the person does not respond ...

  1. Liquid sprays and flow studies in the direct-injection diesel engine under motored conditions

    NASA Technical Reports Server (NTRS)

    Nguyen, Hung Lee; Carpenter, Mark H.; Ramos, Juan I.; Schock, Harold J.; Stegeman, James D.

    1988-01-01

    A two dimensional, implicit finite difference method of the control volume variety, a two equation model of turbulence, and a discrete droplet model were used to study the flow field, turbulence levels, fuel penetration, vaporization, and mixing in diesel engine environments. The model was also used to study the effects of engine speed, injection angle, spray cone angle, droplet distribution, and intake swirl angle on the flow field, spray penetration and vaporization, and turbulence in motored two-stroke diesel engines. It is shown that there are optimum conditions for injection, which depend on droplet distribution, swirl, spray cone angle, and injection angle. The optimum conditions result in good spray penetration and vaporization and in good fuel mixing. The calculation presented clearly indicates that internal combustion engine models can be used to assess, at least qualitatively, the effects of injection characteristics and engine operating conditions on the flow field and on the spray penetration and vaporization in diesel engines.

  2. High Fidelity Simulation of Primary Atomization in Diesel Engine Sprays

    NASA Astrophysics Data System (ADS)

    Ivey, Christopher; Bravo, Luis; Kim, Dokyun

    2014-11-01

    A high-fidelity numerical simulation of jet breakup and spray formation from a complex diesel fuel injector at ambient conditions has been performed. A full understanding of the primary atomization process in fuel injection of diesel has not been achieved for several reasons including the difficulties accessing the optically dense region. Due to the recent advances in numerical methods and computing resources, high fidelity simulations of atomizing flows are becoming available to provide new insights of the process. In the present study, an unstructured un-split Volume-of-Fluid (VoF) method coupled to a stochastic Lagrangian spray model is employed to simulate the atomization process. A common rail fuel injector is simulated by using a nozzle geometry available through the Engine Combustion Network. The working conditions correspond to a single orifice (90 μm) JP-8 fueled injector operating at an injection pressure of 90 bar, ambient condition at 29 bar, 300 K filled with 100% nitrogen with Rel = 16,071, Wel = 75,334 setting the spray in the full atomization mode. The experimental dataset from Army Research Lab is used for validation in terms of spray global parameters and local droplet distributions. The quantitative comparison will be presented and discussed. Supported by Oak Ridge Associated Universities and the Army Research Laboratory.

  3. Rapid Evaporation of microbubbles

    NASA Astrophysics Data System (ADS)

    Gautam, Jitendra; Esmaeeli, Asghar

    2008-11-01

    When a liquid is heated to a temperature far above its boiling point, it evaporates abruptly. Boiling of liquid at high temperatures can be explosive and destructive, and poses a potential hazard for a host of industrial processes. Explosive boiling may occur if a cold and volatile liquid is brought into contact with a hot and non-volatile liquid, or if a liquid is superheated or depressurized rapidly. Such possibilities are realized, for example, in the depressurization of low boiling point liquefied natural gas (LNG) in the pipelines or storage tanks as a result of a leak. While boiling of highly heated liquids can be destructive at macroscale, the (nearly) instantaneous pace of the process and the release of large amount of kinetic energy make the phenomena extremely attractive at microscale where it is possible to utilize the released energy to derive micromechanical systems. For instance, there is currently a growing interest in micro-explosion of liquid for generation of micro bubbles for actuation purposes. The aim of the current study is to gain a fundamental understanding of the subject using direct numerical simulations. In particular, we seek to investigate the boundary between stable and unstable nucleus growth in terms of the degree of liquid superheat and to compare the dynamics of unstable and stable growth.

  4. Optimisation of a vertical spray boom for greenhouse spraying applications.

    PubMed

    Nuyttens, D; Windey, S; Braekman, P; De Moor, A; Sonck, B

    2003-01-01

    The European Crop Protection Association (ECPA) and CLO-DVL joined forces in a project to stimulate a safe use of pesticides in Southern European countries. CLO-DVL optimised a method with mineral chelates to evaluate deposition tests. This quantitative method to evaluate spray deposits and to check spray distributions is used to assess two novel spraying techniques. Deposition tests with water-sensitive paper and mainly with the manganese and molybdenum chelates as tracer elements were performed with a manually pulled trolley and a motorised vehicle both equipped with vertical spray booms. Filter papers were attached to the tomato and pepper plants at several heights to obtain an indication of the spray distribution in the crop. Particular attention was paid to the effect on the spray distribution of the vertical nozzle distance (35 cm vs. 50 cm) and the spray distance to the crop. The tests proved that a nozzle spacing of 35 cm delivers a much better spray distribution than one of 50 cm. The optimal spray distance for flat fan nozzles with a spray angle of 80 degrees and a nozzle spacing of 35 cm is about 30 cm. PMID:15151329

  5. Radiation-Spray Coupling for Realistic Flow Configurations

    NASA Technical Reports Server (NTRS)

    El-Asrag, Hossam; Iannetti, Anthony C.

    2011-01-01

    Three Large Eddy Simulations (LES) for a lean-direct injection (LDI) combustor are performed and compared. In addition to the cold flow simulation, the effect of radiation coupling with the multi-physics reactive flow is analyzed. The flame let progress variable approach is used as a subgrid combustion model combined with a stochastic subgrid model for spray atomization and an optically thin radiation model. For accurate chemistry modeling, a detailed Jet-A surrogate mechanism is utilized. To achieve realistic inflow, a simple recycling technique is performed at the inflow section upstream of the swirler. Good comparison is shown with the experimental data mean and root mean square profiles. The effect of combustion is found to change the shape and size of the central recirculation zone. Radiation is found to change the spray dynamics and atomization by changing the heat release distribution and the local temperature values impacting the evaporation process. The simulation with radiation modeling shows wider range of droplet size distribution by altering the evaporation rate. The current study proves the importance of radiation modeling for accurate prediction in realistic spray combustion configurations, even for low pressure systems.

  6. Evaporative cooling of flare plasma

    NASA Technical Reports Server (NTRS)

    Antiochos, S. K.; Sturrock, P. A.

    1976-01-01

    A one-dimensional loop model for the evaporative cooling of the coronal flare plasma was investigated. Conductive losses dominated radiative cooling, and the evaporative velocities were small compared to the sound speed. The profile and evolution of the temperature were calculated. The model was in agreement with soft X-ray observations on the evolution of flare temperatures and emission measures. The effect of evaporation was to greatly reduce the conductive heat flux into the chromosphere and to enhance the EUV emission from the coronal flare plasma.

  7. Evaporative cooling of flare plasma

    NASA Technical Reports Server (NTRS)

    Antiochos, S. K.; Sturrock, P. A.

    1978-01-01

    We investigate a one-dimensional loop model for the evaporative cooling of the coronal flare plasma. The important assumptions are that conductive losses dominate radiative cooling and that the evaporative velocities are small compared with the sound speed. We calculate the profile and evolution of the temperature and verify the accuracy of our assumptions for plasma parameters typical of flare regions. The model is in agreement with soft X-ray observations on the evolution of flare temperatures and emission measures. The effect of evaporation is to greatly reduce the conductive heat flux into the chromosphere and to enhance the EUV emission from the coronal flare plasma.

  8. Volatilization of metal powders in plasma sprays

    NASA Astrophysics Data System (ADS)

    Vardelle, A.; Vardelle, M.; Zhang, H.; Themelis, N. J.; Gross, K.

    2002-06-01

    Ideally, plasma spraying of metal powders must take place within a narrow processing “window” where the particles become fully molten before they hit the substrate, but are not overheated to the point that substantial volatilization occurs. Metal evaporation in flight results in a decrease in the deposition efficiency. In addiiton, the emission of vapors leads to the formation of metal and oxide fumes that are undesirable from the viewpoints of both resource conservation and environmental control. This study examines the vaporization and fume formation in the plasma spraying of iron powders of different size ranges. The experimental part involves the determination of the population (number density) of metal atoms at different cross sections along the trajectory of the plasma jet, and the collection of the submicronic particles resulting from vapor condensation. The experimental results are compared with the projections of a mathematical model that computes the gas/particle velocity and temperature fields within the jet envelope, projects the rate of heat/mass transfer at the surface of individual particles, and determines the rate of volatilization that results in the formation of metal and metal oxide fumes.

  9. Probing a Spray Using Frequency-Analyzed Light Scattering

    NASA Technical Reports Server (NTRS)

    Eskridge, Richard; Lee, Michael H.; Rhys, Noah O.

    2008-01-01

    Frequency-analyzed laser-light scattering (FALLS) is a relatively simple technique that can be used to measure principal characteristics of a sheet of sprayed liquid as it breaks up into ligaments and then the ligaments break up into droplets. In particular, through frequency analysis of laser light scattered from a spray, it is possible to determine whether the laser-illuminated portion of the spray is in the intact-sheet region, the ligament region, or the droplet region. By logical extension, it is possible to determine the intact length from the location of the laser beam at the transition between the intact-sheet and ligament regions and to determine a breakup frequency from the results of the frequency analysis. Hence, FALLS could likely be useful both as a means of performing research on sprays in general and as a means of diagnostic sensing in diverse applications in which liquid fuels are sprayed. Sprays are also used for drying and to deposit paints and other coating materials.

  10. Numerical Simulation of Spray Atomization in Supersonic Flows

    NASA Astrophysics Data System (ADS)

    Wang, Jiangfeng; Liu, Chen; Wu, Yizhao

    With the rapid development of the air-breathing hypersonic vehicle design, an accurate description of the combustion properties becomes more and more important, where one of the key techniques is the procedure of the liquid fuel mixing, atomizing and burning coupled with the supersonic crossflow in the combustion chamber. The movement and distribution of the liquid fuel droplets in the combustion chamber will influence greatly the combustion properties, as well as the propulsion performance of the ramjet/scramjet engine. In this paper, numerical simulation methods on unstructured hybrid meshes were carried out for liquid spray atomization in supersonic crossflows. The Kelvin-Helmholtz/Rayleigh-Taylor hybrid model was used to simulate the breakup process of the liquid spray in a supersonic crossflow with Mach number 1.94. Various spray properties, including spray penetration height, droplet size distribution, were quantitatively compared with experimental results. In addition, numerical results of the complex shock wave structure induced by the presence of liquid spray were illustrated and discussed.

  11. Development and parametric evaluation of the prototype 2 and 3 flash evaporators

    NASA Technical Reports Server (NTRS)

    Hixon, C. W.; Dietz, J. B.

    1975-01-01

    Development of the Prototype 2 and 3 flash evaporator heat sinks which vaporize an expendable fluid to cool a heat transport fluid loop is reported. The units utilize Freon 21 as the heat transport fluid and water as the expendable fluid to meet the projected performance requirements of the space shuttle for both on-orbit and ascent/reentry operations. The evaporant is pulse-sprayed by on-off control onto heat transfer surfaces containing the transport fluid and exhausted to the vacuum environment through fixed area exhaust ducts.

  12. Development of plasma spray coated cylinder liners

    SciTech Connect

    Tricard, M.; Hagan, J.; Redington, P.; Subramanian, K.; Haselkorn, M.

    1996-09-01

    Improved fuel economy and reduction of emissions can be achieved by insulation of the combustion chamber components to reduce heat rejection. However, such insulation will also increase the operating temperature of the piston ring/cylinder liner interface from approximately 150 C to over 300 C. Since existing ring/liner materials cannot withstand these higher operating temperatures alternatives are needed for this critical tribological interface. This paper describes the development of a cost effective ID grinding technique for machining the bores of plasma sprayed diesel engine cylinder liners.

  13. Numerical simulation of internal and near-nozzle flow of a gasoline direct injection fuel injector

    NASA Astrophysics Data System (ADS)

    Saha, Kaushik; Som, Sibendu; Battistoni, Michele; Li, Yanheng; Quan, Shaoping; Senecal, Peter Kelly

    2015-12-01

    A numerical study of two-phase flow inside the nozzle holes and the issuing spray jets for a multi-hole direct injection gasoline injector has been presented in this work. The injector geometry is representative of the Spray G nozzle, an eight-hole counterbore injector, from, the Engine Combustion Network (ECN). Simulations have been carried out for the fixed needle lift. Effects of turbulence, compressibility and, non-condensable gases have been considered in this work. Standard k—ɛ turbulence model has been used to model the turbulence. Homogeneous Relaxation Model (HRM) coupled with Volume of Fluid (VOF) approach has been utilized to capture the phase change phenomena inside and outside the injector nozzle. Three different boundary conditions for the outlet domain have been imposed to examine non-flashing and evaporative, non-flashing and non-evaporative, and flashing conditions. Inside the nozzle holes mild cavitation-like and in the near-nozzle region flash boiling phenomena have been predicted in this study when liquid fuel is subjected to superheated ambiance. Noticeable hole to hole variation has been also observed in terms of mass flow rates for all the holes under both flashing and non-flashing conditions.

  14. Evaporative cooling: effective latent heat of evaporation in relation to evaporation distance from the skin.

    PubMed

    Havenith, George; Bröde, Peter; den Hartog, Emiel; Kuklane, Kalev; Holmer, Ingvar; Rossi, Rene M; Richards, Mark; Farnworth, Brian; Wang, Xiaoxin

    2013-03-15

    Calculation of evaporative heat loss is essential to heat balance calculations. Despite recognition that the value for latent heat of evaporation, used in these calculations, may not always reflect the real cooling benefit to the body, only limited quantitative data on this is available, which has found little use in recent literature. In this experiment a thermal manikin, (MTNW, Seattle, WA) was used to determine the effective cooling power of moisture evaporation. The manikin measures both heat loss and mass loss independently, allowing a direct calculation of an effective latent heat of evaporation (λeff). The location of the evaporation was varied: from the skin or from the underwear or from the outerwear. Outerwear of different permeabilities was used, and different numbers of layers were used. Tests took place in 20°C, 0.5 m/s at different humidities and were performed both dry and with a wet layer, allowing the breakdown of heat loss in dry and evaporative components. For evaporation from the skin, λeff is close to the theoretical value (2,430 J/g) but starts to drop when more clothing is worn, e.g., by 11% for underwear and permeable coverall. When evaporation is from the underwear, λeff reduction is 28% wearing a permeable outer. When evaporation is from the outermost layer only, the reduction exceeds 62% (no base layer), increasing toward 80% with more layers between skin and wet outerwear. In semi- and impermeable outerwear, the added effect of condensation in the clothing opposes this effect. A general formula for the calculation of λeff was developed. PMID:23329814

  15. Evaporation effects in elastocapillary aggregation

    NASA Astrophysics Data System (ADS)

    Vella, Dominic; Hadjittofis, Andreas; Singh, Kiran; Lister, John

    2015-11-01

    We consider the effect of evaporation on the aggregation of a number of elastic objects due to a liquid's surface tension. In particular, we consider an array of spring-block elements in which the gaps between blocks are filled by thin liquid films that evaporate during the course of an experiment. Using lubrication theory to account for the fluid flow within the gaps, we study the dynamics of aggregation. We find that a non-zero evaporation rate causes the elements to aggregate more quickly and, indeed, to contact within finite time. However, we also show that the number of elements within each cluster decreases as the evaporation rate increases. We explain these results quantitatively by comparison with the corresponding two-body problem and discuss their relevance for controlling pattern formation in carbon nanotube forests.

  16. Explosive evaporation in solar flares

    NASA Technical Reports Server (NTRS)

    Fisher, George H.

    1987-01-01

    This paper develops a simple analytical model for the phenomenon of 'explosive evaporation' driven by nonthermal electron heating in solar flares. The model relates the electron energy flux and spectrum, plus details of the preflare atmosphere, to the time scale for explosive evaporation to occur, the maximum pressure and temperature to be reached, rough estimates for the UV pulse emission flux and duration, and the evolution of the blueshifted component of the soft X-ray lines. An expression is given for the time scale for buildup to maximum pressures and the onset of rapid motion of the explosively evaporating plasma. This evaporation can excite a rapid response of UV line and continuum emission. The emission lines formed in the plasma approach a given emissivity-weighted blueshift speed.

  17. Dual manifold heat pipe evaporator

    DOEpatents

    Adkins, Douglas R.; Rawlinson, K. Scott

    1994-01-01

    An improved evaporator section for a dual manifold heat pipe. Both the upper and lower manifolds can have surfaces exposed to the heat source which evaporate the working fluid. The tubes in the tube bank between the manifolds have openings in their lower extensions into the lower manifold to provide for the transport of evaporated working fluid from the lower manifold into the tubes and from there on into the upper manifold and on to the condenser portion of the heat pipe. A wick structure lining the inner walls of the evaporator tubes extends into both the upper and lower manifolds. At least some of the tubes also have overflow tubes contained within them to carry condensed working fluid from the upper manifold to pass to the lower without spilling down the inside walls of the tubes.

  18. Dual manifold heat pipe evaporator

    DOEpatents

    Adkins, D.R.; Rawlinson, K.S.

    1994-01-04

    An improved evaporator section is described for a dual manifold heat pipe. Both the upper and lower manifolds can have surfaces exposed to the heat source which evaporate the working fluid. The tubes in the tube bank between the manifolds have openings in their lower extensions into the lower manifold to provide for the transport of evaporated working fluid from the lower manifold into the tubes and from there on into the upper manifold and on to the condenser portion of the heat pipe. A wick structure lining the inner walls of the evaporator tubes extends into both the upper and lower manifolds. At least some of the tubes also have overflow tubes contained within them to carry condensed working fluid from the upper manifold to pass to the lower without spilling down the inside walls of the tubes. 1 figure.

  19. Horst Meyer and Quantum Evaporation

    NASA Astrophysics Data System (ADS)

    Balibar, S.

    2016-06-01

    With their 1963 article in Cryogenics Horst Meyer and his collaborators triggered intense research activity on the evaporation of superfluid helium. Discussing this subject with him in 1975 was enlightening. Fifty years later, the analogy between the photoelectric effect and the evaporation of superfluid helium in the low temperature limit is not yet clear, although remarkable progress has been made in its observation and its understanding. This special issue of the Journal of Low Temperature Physics is an opportunity to recall the history of quantum evaporation, and to express my gratitude to Horst Meyer. It describes quickly most of the experimental and theoretical works which have been published on quantum evaporation during the last 50 years, but it is not a comprehensive review of this fascinating subject.

  20. Evaporation Tower With Prill Nozzles

    NASA Technical Reports Server (NTRS)

    Du Fresne, E. R.

    1984-01-01

    Tower more efficient than conventional evaporation equipment. Liquids such as milk and fruit juice concentrated by passing them through tiny nozzle to form droplets, then allowing droplets to fall through evacuated tower with cooled walls.