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Sample records for field asymmetric ion

  1. Mass spectrometric characterization of a high-field asymmetric waveform ion mobility spectrometer

    NASA Astrophysics Data System (ADS)

    Purves, Randy W.; Guevremont, Roger; Day, Stephen; Pipich, Charles W.; Matyjaszczyk, Matthew S.

    1998-12-01

    Ion mobility spectrometry (IMS) has become an important method for the detection of many compounds because of its high sensitivity and amenability to miniaturization for field-portable monitoring; applications include detection of narcotics, explosives, and chemical warfare agents. High-field asymmetric waveform ion mobility spectrometry (FAIMS) differs from IMS in that the electric fields are applied using a high-frequency periodic asymmetric waveform, rather than a dc voltage. Furthermore, in FAIMS the compounds are separated by the difference in the mobility of ions at high electric field relative to low field, rather than by compound to compound differences in mobility at low electric field (IMS). We report here the first cylindrical-geometry-FAIMS interface with mass spectrometry (FAIMS-MS) and the MS identification of the peaks observed in a FAIMS compensation voltage (CV) spectrum. Using both an electrometer-based-FAIMS (FAIMS-E) and FAIMS-MS, several variables that affect the sensitivity of ion detection were examined for two (polarity reversed) asymmetric waveforms (modes 1 and 2) each of which yields a unique spectrum. An increase in the dispersion voltage (DV) was found to improve the sensitivity and separation observed in the FAIMS CV spectrum. This increase in sensitivity and the unexpected dissimilarity in modes 1 and 2 suggest that atmospheric pressure ion focusing is occurring in the FAIMS analyzer. The sensitivity and peak locations in the CV spectra were affected by temperature, gas flow rates, operating pressure, and analyte concentration.

  2. Control of Ion Distortion in Field Asymmetric Waveform Ion Mobility Spectrometry via Variation of Dispersion Field and Gas Temperature

    SciTech Connect

    Robinson, Errol W.; Shvartsburg, Alexandre A.; Tang, Keqi; Smith, Richard D.

    2008-10-01

    Field asymmetric waveform ion mobility spectrometry (FAIMS) has emerged as an analytical tool of broad utility, especially in conjunction with mass spectrometry. Of particular promise is the use of FAIMS and 2-D ion mobility methods that combine it with conventional IMS to resolve and characterize protein and other macromolecular conformers. However, FAIMS operation requires high electric fields and ions are inevitably heated by above-thermal collisions with buffer gas molecules. This may induce ion isomerization and dissociation that distort separation properties determined by FAIMS and subsequent stages and/or reduce instrumental sensitivity. As FAIMS employs a periodic waveform, the ion temperature can be characterized at the maximum or average field intensity (E). Which method is most applicable to temperature sensitive ions, such as protein ions, has been debated. Here we address this issue by measuring the unfolding of compact ubiquitin ion geometries as a function of waveform amplitude (dispersion field, ED) and gas temperature, T. The field heating is quantified by matching the dependences of structural transitions on ED and T. Increasing ED from 12 to 16 or from 16 to 20 kV/cm is equivalent to heating the (N2) gas by ~15 - 25 oC. The magnitude of field heating for any E can be calculated using the two-temperature theory, and raising ED by 4 kV/cm augments heating by ~15 - 30 oC for maximum and ~4 - 8 oC for average E in the FAIMS cycle. Hence, isomerization of ions in FAIMS appears to be governed by the maximum internal temperature at waveform peaks.

  3. Measurement of Asymmetric Optical Pumping of Ions Accelerating in a Magnetic-field Gradient

    SciTech Connect

    Xuan Sun; Earl Scime; Mahmood Miah; Samuel Cohen; Frederick Skiff

    2004-10-28

    We report observations of asymmetric optical pumping of argon ions accelerating in a magnetic field gradient. The signature is a difference in the laser-induced-fluorescence (LIF) emission amplitude from a pair of Zeeman-split states. A model that reproduces the dependence of the asymmetry on magnetic-field and ion-velocity gradients is described. With the model, the fluorescence intensity ratio provides a new method of measuring ion collisionality. This phenomenon has implications for interpreting stellar plasma spectroscopy data which often exhibit unequal Zeeman state intensities.

  4. Control of Ion Distortion in Field Asymmetric Waveform Ion Mobility Spectrometry via Variation of Dispersion Field and Gas Temperature

    PubMed Central

    Robinson, Errol W.; Shvartsburg, Alexandre A.; Tang, Keqi; Smith, Richard D.

    2009-01-01

    Field asymmetric waveform ion mobility spectrometry (FAIMS) has emerged as an analytical tool of broad utility, especially in conjunction with mass spectrometry. Of particular promise is the use of FAIMS and 2-D ion mobility methods that combine FAIMS with conventional IMS to resolve and characterize protein and other macromolecular conformers. However, FAIMS operation requires a strong electric field and ions are inevitably heated by energetic collisions with buffer gas molecules. This may induce ion isomerization or dissociation that distort the separation properties of FAIMS (and subsequent stages) and/or reduce instrumental sensitivity. As FAIMS employs a periodic waveform, whether those processes are controlled by ion temperature at maximum or average field intensity has been debated. Here we address this issue by measuring the unfolding of compact ubiquitin ion geometries as a function of waveform amplitude (dispersion field, ED) and gas temperature, T. The field heating is quantified by matching the dependences of structural transitions on ED and T: increasing ED from 12 to 16 or from 16 to 20 kV/cm is equivalent to heating the (N2) gas by ∼15 – 25 °C. The magnitude of field heating for any ED can be estimated using the two-temperature theory, and raising ED by 4 kV/cm augments heating by ∼15 – 30 °C for maximum and ∼4 – 8 °C for average field in the FAIMS cycle. Hence, isomerization of ions in FAIMS appears to be determined by the excitation at waveform peaks. PMID:18729473

  5. Asymmetric Ion-Pairing Catalysis

    PubMed Central

    Brak, Katrien

    2014-01-01

    Charged intermediates and reagents are ubiquitous in organic transformations. The interaction of these ionic species with chiral neutral, anionic, or cationic small molecules has emerged as a powerful strategy for catalytic, enantioselective synthesis. This review describes developments in the burgeoning field of asymmetric ion-pairing catalysis with an emphasis on the insights that have been gleaned into the structural and mechanistic features that contribute to high asymmetric induction. PMID:23192886

  6. Asymmetric ion trap

    DOEpatents

    Barlow, Stephan E.; Alexander, Michael L.; Follansbee, James C.

    1997-01-01

    An ion trap having two end cap electrodes disposed asymmetrically about a center of a ring electrode. The inner surface of the end cap electrodes are conformed to an asymmetric pair of equipotential lines of the harmonic formed by the application of voltages to the electrodes. The asymmetry of the end cap electrodes allows ejection of charged species through the closer of the two electrodes which in turn allows for simultaneously detecting anions and cations expelled from the ion trap through the use of two detectors charged with opposite polarity.

  7. Micro-machined planar field asymmetric ion mobility spectrometer as a gas chromatographic detector

    NASA Technical Reports Server (NTRS)

    Eiceman, G. A.; Nazarov, E. G.; Miller, R. A.; Krylov, E. V.; Zapata, A. M.

    2002-01-01

    A planar high field asymmetric waveform ion mobility spectrometer (PFAIMS) with a micro-machined drift tube was characterized as a detector for capillary gas chromatography. The performance of the PFAIMS was compared directly to that of a flame ionization detector (FID) for the separation of a ketone mixture from butanone to decanone. Effluent from the column was continuously sampled by the detector and mobility scans could be obtained throughout the chromatographic analysis providing chemical inforrmation in mobility scans orthogonal to retention time. Limits of detection were approximately I ng for measurement of positive ions and were comparable or slightly better than those for the FID. Direct comparison of calibration curves for the FAIMS and the FID was possible over four orders of magnitude with a semi-log plot. The concentration dependence of the PFAIMS mobility scans showed the dependence between ion intensity and ion clustering, evident in other mobility spectrometers and atmospheric pressure ionization technologies. Ions were identified using mass spectrometry as the protonated monomer and the proton bound dimer of the ketones. Residence time for column effluent in the PFAIMS was calculated as approximately 1 ms and a 36% increase in extra-column broadening versus the FID occurred with the PFAIMS.

  8. Peak deconvolution in high-field asymmetric waveform ion mobility spectrometry (FAIMS) to characterize macromolecular conformations

    NASA Astrophysics Data System (ADS)

    Robinson, Errol W.; Sellon, Rachel E.; Williams, Evan R.

    2007-01-01

    Protonated poly(ethylene glycol), produced by electrospray ionization (ESI), with molecular weights ranging from 0.3 to 5 kDa and charge states from 1+ to 7+ were characterized using high-field asymmetric waveform ion mobility spectrometry (FAIMS). Results for all but some of the 3+ and 4+ charge states are consistent with a single gas-phase conformer or family of unresolved conformers for each of these charge states. The FAIMS compensation voltage scans resulted in peaks that could be accurately fit with a single Gaussian for each peak. The peak widths increase linearly with compensation voltage for maximum ion transmission but do not depend on m/z or molecular weight. Fitting parameters obtained from the poly(ethylene glycol) data were used to analyze conformations of oxidized and reduced lysozyme formed from different solutions. For oxidized lysozyme formed from a buffered aqueous solution, a single conformer (or group of unresolved conformers) was observed for the 7+ and 8+ charge states. Two conformers were observed for the 9+ and 10+ charge states formed from more denaturing solutions. Data for the fully reduced form indicate the existence of up to three different conformers for each charge state produced directly by ESI and a general progression from a more extended to a more folded structure with decreasing charge state. These results are consistent with those obtained previously by proton-transfer reactivity and drift tube ion mobility experiments, although more conformers were identified for the fully reduced form of lysozyme using FAIMS.

  9. Enhancing Biological Analyses with Three Dimensional Field Asymmetric Ion Mobility, Low Field Drift Time Ion Mobility and Mass Spectrometry (µFAIMS/IMS-MS) Separations

    SciTech Connect

    Zhang, Xing; Ibrahim, Yehia M.; Chen, Tsung-Chi; Kyle, Jennifer E.; Norheim, Randolph V.; Monroe, Matthew E.; Smith, Richard D.; Baker, Erin Shammel

    2015-06-30

    We report the first evaluation of a platform coupling a high speed field asymmetric ion mobility spectrometry microchip (µFAIMS) with drift tube ion mobility and mass spectrometry (IMS-MS). The µFAIMS/IMS-MS platform was used to analyze biological samples and simultaneously acquire multidimensional information of detected features from the measured FAIMS compensation fields and IMS drift times, while also obtaining accurate ion masses. These separations thereby increase the overall separation power, resulting increased information content, and provide more complete characterization of more complex samples. The separation conditions were optimized for sensitivity and resolving power by the selection of gas compositions and pressures in the FAIMS and IMS separation stages. The resulting performance provided three dimensional separations, benefitting both broad complex mixture studies and targeted analyses by e.g. improving isomeric separations and allowing detection of species obscured by “chemical noise” and other interfering peaks.

  10. Developing Fieldable Systems for Chemical Sensing Using Field Asymmetric Ion Mobility Spectrometry and Mass Spectrometry

    SciTech Connect

    Kevin Kyle, Stephan Weeks, R. Trainham

    2008-03-01

    Currently, there is an urgent need for field-rugged and field-programmable sensor systems that provide highly selective, universal monitoring of vapors and aerosols at detectable levels from persons or areas involved with illicit chemical/biological/explosives (CBE) production. These devices must be portable, low cost, robust, and provide accurate measurements to avoid both false positive and negative results. Furthermore, the information provided by the devices must be received in a timely manner so that informed decisions can be immediately made and the appropriate actions taken. Two technologies that are unparalleled in their sensitivity, selectivity, and trace-level detection capabilities are field asymmetric ion mobility spectrometry (FAIMS) and mass spectrometry. Here, we will show progress that has been made toward developing fieldable FAIMS systems and mass spectrometers. Working in collaboration with Sionex Corporation, the microDMx detector was equipped with a continuous air sampling system to develop selective methods for the analysis of compounds of interest. A microdiaphragm pump (KNF Neuberger, Inc.) is used to pull in gas-phase analytes directly from the air for separation and detection with the FAIMS system. The FAIMS evaluation platform (SVAC) unit currently measures 9.8-inch x 4.6-inch x 3.2-inch, weighs 3.1 lb, and utilizes a {sup 63}Ni source to ionize incoming compounds. Analytes entering the unit are separated and identified by their characteristic response to the compensation voltage (V{sub c}) at a given rf field strength (V{sub rf}). This response has been observed to be unique for a wide range of substances studied. If additional verification were required or a targeted analyte present in a complex chemical matrix, a FAIMS unit equipped with a fast gas chromatography column has been evaluated. The unit combines the separation capabilities of gas chromatography with the selectivity of FAIMS. It measures 9.5-inch x 5.25-inch x 3.5-inch

  11. Asymmetrical field emitter

    DOEpatents

    Fleming, J.G.; Smith, B.K.

    1995-10-10

    A method is disclosed for providing a field emitter with an asymmetrical emitter structure having a very sharp tip in close proximity to its gate. One preferred embodiment of the present invention includes an asymmetrical emitter and a gate. The emitter having a tip and a side is coupled to a substrate. The gate is connected to a step in the substrate. The step has a top surface and a side wall that is substantially parallel to the side of the emitter. The tip of the emitter is in close proximity to the gate. The emitter is at an emitter potential, and the gate is at a gate potential such that with the two potentials at appropriate values, electrons are emitted from the emitter. In one embodiment, the gate is separated from the emitter by an oxide layer, and the emitter is etched anisotropically to form its tip and its asymmetrical structure. 17 figs.

  12. Liquid extraction surface analysis field asymmetric waveform ion mobility spectrometry mass spectrometry for the analysis of dried blood spots.

    PubMed

    Griffiths, Rian L; Dexter, Alex; Creese, Andrew J; Cooper, Helen J

    2015-10-21

    Liquid extraction surface analysis (LESA) is a surface sampling technique that allows electrospray mass spectrometry analysis of a wide range of analytes directly from biological substrates. Here, we present LESA mass spectrometry coupled with high field asymmetric waveform ion mobility spectrometry (FAIMS) for the analysis of dried blood spots on filter paper. Incorporation of FAIMS in the workflow enables gas-phase separation of lipid and protein molecular classes, enabling analysis of both haemoglobin and a range of lipids (phosphatidylcholine or phosphatidylethanolamine, and sphingomyelin species) from a single extraction sample. The work has implications for multiplexed clinical assays of multiple analytes. PMID:26198596

  13. Separation of Opiate Isomers Using Electrospray Ionization and Paper Spray Coupled to High-Field Asymmetric Waveform Ion Mobility Spectrometry

    NASA Astrophysics Data System (ADS)

    Manicke, Nicholas E.; Belford, Michael

    2015-05-01

    One limitation in the growing field of ambient or direct analysis methods is reduced selectivity caused by the elimination of chromatographic separations prior to mass spectrometric analysis. We explored the use of high-field asymmetric waveform ion mobility spectrometry (FAIMS), an ambient pressure ion mobility technique, to separate the closely related opiate isomers of morphine, hydromorphone, and norcodeine. These isomers cannot be distinguished by tandem mass spectrometry. Separation prior to MS analysis is, therefore, required to distinguish these compounds, which are important in clinical chemistry and toxicology. FAIMS was coupled to a triple quadrupole mass spectrometer, and ionization was performed using either a pneumatically assisted heated electrospray ionization source (H-ESI) or paper spray, a direct analysis method that has been applied to the direct analysis of dried blood spots and other complex samples. We found that FAIMS was capable of separating the three opiate structural isomers using both H-ESI and paper spray as the ionization source.

  14. Decreased Gap Width in a Cylindrical High-Field Asymmetric Waveform Ion Mobility Spectrometry Device Improves Protein Discovery.

    PubMed

    Swearingen, Kristian E; Winget, Jason M; Hoopmann, Michael R; Kusebauch, Ulrike; Moritz, Robert L

    2015-12-15

    High-field asymmetric waveform ion mobility spectrometry (FAIMS) is an atmospheric pressure ion mobility technique that separates gas phase ions according to their characteristic dependence of ion mobility on electric field strength. FAIMS can be implemented as a means of automated gas-phase fractionation in liquid chromatography-tandem mass spectrometry (LC-MS/MS) experiments. We modified a commercially available cylindrical FAIMS device by enlarging the inner electrode, thereby narrowing the gap and increasing the effective field strength. This modification provided a nearly 4-fold increase in FAIMS peak capacity over the optimally configured unmodified device. We employed the modified FAIMS device for on-line fractionation in a proteomic analysis of a complex sample and observed major increases in protein discovery. NanoLC-FAIMS-MS/MS of an unfractionated yeast tryptic digest using the modified FAIMS device identified 53% more proteins than were identified using an unmodified FAIMS device and 98% more proteins than were identified with unaided nanoLC-MS/MS. We describe here the development of a nanoLC-FAIMS-MS/MS protocol that provides automated gas-phase fractionation for proteomic analysis of complex protein digests. We compare this protocol against prefractionation of peptides with isoelectric focusing and demonstrate that FAIMS fractionation yields comparable protein recovery while significantly reducing the amount of sample required and eliminating the need for additional sample handling. PMID:26560994

  15. Enhancement of mass spectrometry performance for proteomic analyses using high-field asymmetric waveform ion mobility spectrometry (FAIMS).

    PubMed

    Bonneil, Eric; Pfammatter, Sibylle; Thibault, Pierre

    2015-11-01

    Remarkable advances in mass spectrometry sensitivity and resolution have been accomplished over the past two decades to enhance the depth and coverage of proteome analyses. As these technological developments expanded the detection capability of mass spectrometers, they also revealed an increasing complexity of low abundance peptides, solvent clusters and sample contaminants that can confound protein identification. Separation techniques that are complementary and can be used in combination with liquid chromatography are often sought to improve mass spectrometry sensitivity for proteomics applications. In this context, high-field asymmetric waveform ion mobility spectrometry (FAIMS), a form of ion mobility that exploits ion separation at low and high electric fields, has shown significant advantages by focusing and separating multiply charged peptide ions from singly charged interferences. This paper examines the analytical benefits of FAIMS in proteomics to separate co-eluting peptide isomers and to enhance peptide detection and quantitative measurements of protein digests via native peptides (label-free) or isotopically labeled peptides from metabolic labeling or chemical tagging experiments. PMID:26505763

  16. High-Field Asymmetric-Waveform Ion Mobility Spectrometry and Electron Detachment Dissociation of Isobaric Mixtures of Glycosaminoglycans

    NASA Astrophysics Data System (ADS)

    Kailemia, Muchena J.; Park, Melvin; Kaplan, Desmond A.; Venot, Andre; Boons, Geert-Jan; Li, Lingyun; Linhardt, Robert J.; Amster, I. Jonathan

    2013-11-01

    High-field asymmetric waveform ion mobility spectrometry (FAIMS) is shown to be capable of resolving isomeric and isobaric glycosaminoglycan negative ions and to have great utility for the analysis of this class of molecules when combined with Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) and tandem mass spectrometry. Electron detachment dissociation (EDD) and other ion activation methods for tandem mass spectrometry can be used to determine the sites of labile sulfate modifications and for assigning the stereochemistry of hexuronic acid residues of glycosaminoglycans (GAGs). However, mixtures with overlapping mass-to-charge values present a challenge, as their precursor species cannot be resolved by a mass analyzer prior to ion activation. FAIMS is shown to resolve two types of mass-to-charge overlaps. A mixture of chondroitin sulfate A (CSA) oligomers with 4-10 saccharides units produces ions of a single mass-to-charge by electrospray ionization, as the charge state increases in direct proportion to the degree of polymerization for these sulfated carbohydrates. FAIMS is shown to resolve the overlapping charge. A more challenging type of mass-to-charge overlap occurs for mixtures of diastereomers. FAIMS is shown to separate two sets of epimeric GAG tetramers. For the epimer pairs, the complexity of the separation is reduced when the reducing end is alkylated, suggesting that anomers are also resolved by FAIMS. The resolved components were activated by EDD and the fragment ions were analyzed by FTICR-MS. The resulting tandem mass spectra were able to distinguish the two epimers from each other.

  17. Analysis of Supramolecular Complexes of 3-Methylxanthine with Field Asymmetric Waveform Ion Mobility Spectrometry Combined with Mass Spectrometry

    NASA Astrophysics Data System (ADS)

    Arthur, Kayleigh L.; Eiceman, Gary A.; Reynolds, James C.; Creaser, Colin S.

    2016-05-01

    Miniaturised field asymmetric waveform ion mobility spectrometry (FAIMS), combined with mass spectrometry (MS), has been applied to the study of self-assembling, noncovalent supramolecular complexes of 3-methylxanthine (3-MX) in the gas phase. 3-MX forms stable tetrameric complexes around an alkali metal (Na+, K+) or ammonium cation, to generate a diverse array of complexes with single and multiple charge states. Complexes of (3-MX)n observed include: singly charged complexes where n = 1-8 and 12 and doubly charged complexes where n = 12-24. The most intense ions are those associated with multiples of tetrameric units, where n = 4, 8, 12, 16, 20, 24. The effect of dispersion field on the ion intensities of the self-assembled complexes indicates some fragmentation of higher order complexes within the FAIMS electrodes (in-FAIMS dissociation), as well as in-source collision induced dissociation within the mass spectrometer. FAIMS-MS enables charge state separation of supramolecular complexes of 3-MX and is shown to be capable of separating species with overlapping mass-to-charge ratios. FAIMS selected transmission also results in an improvement in signal-to-noise ratio for low intensity complexes and enables the visualization of species undetectable without FAIMS.

  18. Analysis of Supramolecular Complexes of 3-Methylxanthine with Field Asymmetric Waveform Ion Mobility Spectrometry Combined with Mass Spectrometry

    NASA Astrophysics Data System (ADS)

    Arthur, Kayleigh L.; Eiceman, Gary A.; Reynolds, James C.; Creaser, Colin S.

    2016-02-01

    Miniaturised field asymmetric waveform ion mobility spectrometry (FAIMS), combined with mass spectrometry (MS), has been applied to the study of self-assembling, noncovalent supramolecular complexes of 3-methylxanthine (3-MX) in the gas phase. 3-MX forms stable tetrameric complexes around an alkali metal (Na+, K+) or ammonium cation, to generate a diverse array of complexes with single and multiple charge states. Complexes of (3-MX)n observed include: singly charged complexes where n = 1-8 and 12 and doubly charged complexes where n = 12-24. The most intense ions are those associated with multiples of tetrameric units, where n = 4, 8, 12, 16, 20, 24. The effect of dispersion field on the ion intensities of the self-assembled complexes indicates some fragmentation of higher order complexes within the FAIMS electrodes (in-FAIMS dissociation), as well as in-source collision induced dissociation within the mass spectrometer. FAIMS-MS enables charge state separation of supramolecular complexes of 3-MX and is shown to be capable of separating species with overlapping mass-to-charge ratios. FAIMS selected transmission also results in an improvement in signal-to-noise ratio for low intensity complexes and enables the visualization of species undetectable without FAIMS.

  19. Analysis of Supramolecular Complexes of 3-Methylxanthine with Field Asymmetric Waveform Ion Mobility Spectrometry Combined with Mass Spectrometry.

    PubMed

    Arthur, Kayleigh L; Eiceman, Gary A; Reynolds, James C; Creaser, Colin S

    2016-05-01

    Miniaturised field asymmetric waveform ion mobility spectrometry (FAIMS), combined with mass spectrometry (MS), has been applied to the study of self-assembling, noncovalent supramolecular complexes of 3-methylxanthine (3-MX) in the gas phase. 3-MX forms stable tetrameric complexes around an alkali metal (Na(+), K(+)) or ammonium cation, to generate a diverse array of complexes with single and multiple charge states. Complexes of (3-MX)n observed include: singly charged complexes where n = 1-8 and 12 and doubly charged complexes where n = 12-24. The most intense ions are those associated with multiples of tetrameric units, where n = 4, 8, 12, 16, 20, 24. The effect of dispersion field on the ion intensities of the self-assembled complexes indicates some fragmentation of higher order complexes within the FAIMS electrodes (in-FAIMS dissociation), as well as in-source collision induced dissociation within the mass spectrometer. FAIMS-MS enables charge state separation of supramolecular complexes of 3-MX and is shown to be capable of separating species with overlapping mass-to-charge ratios. FAIMS selected transmission also results in an improvement in signal-to-noise ratio for low intensity complexes and enables the visualization of species undetectable without FAIMS. Graphical Abstract ᅟ. PMID:26914231

  20. Nontarget analysis of urine by electrospray ionization-high field asymmetric waveform ion mobility-tandem mass spectrometry.

    PubMed

    Beach, Daniel G; Gabryelski, Wojciech

    2011-12-01

    Nearly a decade after first commercialization, high field asymmetric waveform ion mobility spectrometry (FAIMS) has yet to find its place in routine chemical analysis. Prototypes have been used to demonstrate the utility of this separation technique combined with mass spectrometry (MS). Unfortunately, first generation commercial FAIMS instruments have gone practically unused by early adopters. Here, we show this to be due to poor ion transmission in the FAIMS-MS source interface. We present simple instrumental modifications and optimization of experimental conditions to achieve good performance from the first generation commercial FAIMS device (the Ionalytics Selectra) coupled to a high resolution Q-TOF-MS. In combination with nanospray ionization, we demonstrate for the first time the nontarget analysis of urine by FAIMS with minimal sample preparation. We show the unique suitability of electrospray ionization (ESI)-FAIMS-MS for identification of low abundance species such as urinary biomarkers of damage of nucleic acids in a complex biological matrix. The elimination of electrospray noise and matrix components by FAIMS and the continuous flow of analytes through FAIMS for accurate and tandem mass analysis produce high quality spectral data suitable for structural identification of unknowns. These characteristics make ESI-FAIMS-MS ideal for nontarget identification, even when compared to high efficiency LC-ESI-MS. PMID:21978137

  1. Large-scale analysis of peptide sequence variants: the case for high-field asymmetric waveform ion mobility spectrometry.

    PubMed

    Creese, Andrew J; Smart, Jade; Cooper, Helen J

    2013-05-21

    Large scale analysis of proteins by mass spectrometry is becoming increasingly routine; however, the presence of peptide isomers remains a significant challenge for both identification and quantitation in proteomics. Classes of isomers include sequence inversions, structural isomers, and localization variants. In many cases, liquid chromatography is inadequate for separation of peptide isomers. The resulting tandem mass spectra are composite, containing fragments from multiple precursor ions. The benefits of high-field asymmetric waveform ion mobility spectrometry (FAIMS) for proteomics have been demonstrated by a number of groups, but previously work has focused on extending proteome coverage generally. Here, we present a systematic study of the benefits of FAIMS for a key challenge in proteomics, that of peptide isomers. We have applied FAIMS to the analysis of a phosphopeptide library comprising the sequences GPSGXVpSXAQLX(K/R) and SXPFKXpSPLXFG(K/R), where X = ADEFGLSTVY. The library has defined limits enabling us to make valid conclusions regarding FAIMS performance. The library contains numerous sequence inversions and structural isomers. In addition, there are large numbers of theoretical localization variants, allowing false localization rates to be determined. The FAIMS approach is compared with reversed-phase liquid chromatography and strong cation exchange chromatography. The FAIMS approach identified 35% of the peptide library, whereas LC-MS/MS alone identified 8% and LC-MS/MS with strong cation exchange chromatography prefractionation identified 17.3% of the library. PMID:23646896

  2. Analysis of paralytic shellfish toxins using high-field asymmetric waveform ion mobility spectrometry with liquid chromatography-mass spectrometry.

    PubMed

    Beach, Daniel G; Melanson, Jeremy E; Purves, Randy W

    2015-03-01

    The analysis of paralytic shellfish toxins (PSTs) by liquid chromatography-mass spectrometry remains a challenge because of their high polarity, large number of analogues and the complex matrix in which they occur. Here we investigate the potential utility of high-field asymmetric waveform ion mobility spectrometry (FAIMS) as a gas-phase ion separation tool for analysis of PSTs by mass spectrometry. We investigate the separation of PSTs using FAIMS with two divergent goals: using FAIMS as a primary separation tool for rapid screening by electrospray ionization (ESI)-FAIMS-MS or combined with LC in a multidimensional LC-ESI-FAIMS-MS separation. First, a survey of the parameters that affect the sensitivity and selectivity of PST analysis by FAIMS was carried out using ESI-FAIMS-MS. In particular, the use of acetonitrile as a gas additive in the carrier gas flow offered good separation of all PST epimeric pairs. A second set of FAIMS conditions was also identified, which focussed PSTs to a relatively narrow CV range allowing development of an LC-ESI-FAIMS-MS method for analysis of PST toxins in complex mussel tissue extracts. The quantitative capabilities of this method were evaluated by analysing a PST containing mussel tissue matrix material. Results compared favourably with analysis by an established LC-post-column oxidation-fluorescence method with recoveries ranging from 70 to 106%, although sensitivity was somewhat reduced. The current work represents the first successful separation of PST isomers using ion mobility and shows the promise of FAIMS as a tool for analysis of algal biotoxins in complex samples and outlines some critical requirements for its future improvement. PMID:25619987

  3. Detection of Potato Storage Disease via Gas Analysis: A Pilot Study Using Field Asymmetric Ion Mobility Spectrometry

    PubMed Central

    Rutolo, Massimo; Covington, James A.; Clarkson, John; Iliescu, Daciana

    2014-01-01

    Soft rot is a commonly occurring potato tuber disease that each year causes substantial losses to the food industry. Here, we explore the possibility of early detection of the disease via gas/vapor analysis, in a laboratory environment, using a recent technology known as FAIMS (Field Asymmetric Ion Mobility Spectrometry). In this work, tubers were inoculated with a bacterium causing the infection, Pectobacterium carotovorum, and stored within set environmental conditions in order to manage disease progression. They were compared with controls stored in the same conditions. Three different inoculation time courses were employed in order to obtain diseased potatoes showing clear signs of advanced infection (for standard detection) and diseased potatoes with no apparent evidence of infection (for early detection). A total of 156 samples were processed by PCA (Principal Component Analysis) and k-means clustering. Results show a clear discrimination between controls and diseased potatoes for all experiments with no difference among observations from standard and early detection. Further analysis was carried out by means of a statistical model based on LDA (Linear Discriminant Analysis) that showed a high classification accuracy of 92.1% on the test set, obtained via a LOOCV (leave-one out cross-validation). PMID:25171118

  4. Detection of potato storage disease via gas analysis: a pilot study using field asymmetric ion mobility spectrometry.

    PubMed

    Rutolo, Massimo; Covington, James A; Clarkson, John; Iliescu, Daciana

    2014-01-01

    Soft rot is a commonly occurring potato tuber disease that each year causes substantial losses to the food industry. Here, we explore the possibility of early detection of the disease via gas/vapor analysis, in a laboratory environment, using a recent technology known as FAIMS (Field Asymmetric Ion Mobility Spectrometry). In this work, tubers were inoculated with a bacterium causing the infection, Pectobacterium carotovorum, and stored within set environmental conditions in order to manage disease progression. They were compared with controls stored in the same conditions. Three different inoculation time courses were employed in order to obtain diseased potatoes showing clear signs of advanced infection (for standard detection) and diseased potatoes with no apparent evidence of infection (for early detection). A total of 156 samples were processed by PCA (Principal Component Analysis) and k-means clustering. Results show a clear discrimination between controls and diseased potatoes for all experiments with no difference among observations from standard and early detection. Further analysis was carried out by means of a statistical model based on LDA (Linear Discriminant Analysis) that showed a high classification accuracy of 92.1% on the test set, obtained via a LOOCV (leave-one out cross-validation). PMID:25171118

  5. Solitary waves in asymmetric electron-positron-ion plasmas

    NASA Astrophysics Data System (ADS)

    Lu, Ding; Li, Zi-Liang; Xie, Bai-Song

    2015-10-01

    > By solving the coupled equations of the electromagnetic field and electrostatic potential, we investigate solitary waves in an asymmetric electron-positron plasma and/or electron-positron-ion plasmas with delicate features. It is found that the solutions of the coupled equations can capture multipeak structures of solitary waves in the case of cold plasma, which are left out by using the long-wavelength approximation. By considering the effect of ion motion with respect to non-relativistic and ultra-relativistic temperature plasmas, we find that the ions' mobility can lead to larger-amplitude solitary waves; especially, this becomes more obvious for a high-temperature plasma. The effects of asymmetric temperature between electrons and positrons and the ion fraction on the solitary waves are also studied and presented. It is shown that the amplitudes of solitary waves decrease with positron temperature in asymmetric temperature electron-positron plasmas and decrease also with ion concentration.

  6. ASYMMETRIC SOLAR POLAR FIELD REVERSALS

    SciTech Connect

    Svalgaard, Leif; Kamide, Yohsuke

    2013-01-20

    The solar polar fields reverse because magnetic flux from decaying sunspots moves toward the poles, with a preponderance of flux from the trailing spots. If there is a strong asymmetry, in the sense that most activity is in the northern hemisphere, then that excess flux will move toward the north pole and reverse that pole first. If there is more activity in the south later on, then that flux will help to reverse the south pole. In this way, two humps in the solar activity and a corresponding difference in the time of reversals develop (in the ideal case). Such a difference was originally noted in the very first observation of polar field reversal just after the maximum of the strongly asymmetric solar cycle 19, when the southern hemisphere was most active before sunspot maximum and the south pole duly reversed first, followed by the northern hemisphere more than a year later, when that hemisphere became most active. Solar cycles since then have had the opposite asymmetry, with the northern hemisphere being most active before solar maximum. We show that polar field reversals for these cycles have all happened in the north first, as expected. This is especially noteworthy for the present solar cycle 24. We suggest that the association of two or more peaks of solar activity when separated by hemispheres with correspondingly different times of polar field reversals is a general feature of the cycle, and that asymmetric polar field reversals are simply a consequence of the asymmetry of solar activity.

  7. Field reversals in electrically asymmetric capacitively coupled radio-frequency discharges in hydrogen

    NASA Astrophysics Data System (ADS)

    Mohr, Sebastian; Schüngel, Edmund; Schulze, Julian; Czarnetzki, Uwe

    2013-10-01

    In this paper, we present a simulation study of electrically asymmetric capacitively coupled radio-frequency hydrogen discharges using the hybrid plasma equipment model operated at the combined frequencies of 10 and 20 MHz. We find that, in such discharges, field reversals cause ionization near the electrodes during the sheath collapse. In the case of the investigated asymmetric voltage waveforms, the field reversals are asymmetrically distributed over the sheaths, which causes asymmetric ionization and density profiles. The asymmetry of these profiles can be controlled by the phase angle between the two frequencies. As a result, the possibility to control the ion energy independently from the ion flux via the electrical asymmetry effect (EAE) is reduced in discharges displaying strong field reversals, as the asymmetric field reversals compensate the electrically induced asymmetry. The reason for this is understood by an analytical model. Furthermore, we demonstrate, that the EAE can be restored by the addition of specific gases to a pure hydrogen discharge.

  8. Polarization dependent switching of asymmetric nanorings with a circular field

    NASA Astrophysics Data System (ADS)

    Pradhan, Nihar R.; Tuominen, Mark T.; Aidala, Katherine E.

    2016-01-01

    We experimentally investigated the switching from onion to vortex states in asymmetric cobalt nanorings by an applied circular field. An in-plane field is applied along the symmetric or asymmetric axis of the ring to establish domain walls (DWs) with symmetric or asymmetric polarization. A circular field is then applied to switch from the onion state to the vortex state, moving the DWs in the process. The asymmetry of the ring leads to different switching fields depending on the location of the DWs and direction of applied field. For polarization along the asymmetric axis, the field required to move the DWs to the narrow side of the ring is smaller than the field required to move the DWs to the larger side of the ring. For polarization along the symmetric axis, establishing one DW in the narrow side and one on the wide side, the field required to switch to the vortex state is an intermediate value.

  9. Field reversed ion rings

    SciTech Connect

    Sudan, R.N.; Omelchenko, Y.A.

    1995-09-01

    In typical field-reversed ion ring experiments, an intense annular ion beam is injected across a plasma-filled magnetic cusp region into a neutral gas immersed in a ramped solenoidal magnetic field. Assuming the characteristic ionization time is much shorter than the long ({ital t}{approx_gt}2{pi}/{Omega}{sub {ital i}}) beam evolution time scale, we investigate the formation of an ion ring in the background plasma followed by field reversal, using a 21/2-D hybrid, PIC code FIRE, in which the beam and background ions are treated as particles and the electrons as a massless fluid. We show that beam bunching and trapping occurs downstream in a ramped magnetic field for an appropriate set of experimental parameters. We find that a compact ion ring is formed and a large field reversal {zeta}={delta}{ital B}/{ital B}{approx_gt}1 on axis develops. We also observe significant deceleration of the ring on reflection due to the transfer of its axial momentum to the background ions, which creates favorable trapping conditions. {copyright} {ital 1995 American Institute of Physics.}

  10. A mean-field theory on the differential capacitance of asymmetric ionic liquid electrolytes

    NASA Astrophysics Data System (ADS)

    Han, Yining; Huang, Shanghui; Yan, Tianying

    2014-07-01

    The size of ions significantly influences the electric double layer structure of room temperature ionic liquid (IL) electrolytes and their differential capacitance (Cd). In this study, we extended the mean-field theory (MFT) developed independently by Kornyshev (2007J. Phys. Chem. B 111 5545-57) and Kilic, Bazant, and Ajdari (2007 Phys. Rev. E 75 021502) (the KKBA MFT) to take into account the asymmetric 1:1 IL electrolytes by introducing an additional parameter ξ for the anion/cation volume ratio, besides the ionic compressibility γ in the KKBA MFT. The MFT of asymmetric ions becomes KKBA MFT upon ξ = 1, and further reduces to Gouy-Chapman theory in the γ → 0 limit. The result of the extended MFT demonstrates that the asymmetric ILs give rise to an asymmetric Cd, with the higher peak in Cd occurring at positive polarization for the smaller anionic size. At high potential, Cd decays asymptotically toward KKBA MFT characterized by γ for the negative polarization, and characterized by ξγ for the positive polarization, with inverse-square-root behavior. At low potential, around the potential of zero charge, the asymmetric ions cause a higher Cd, which exceeds that of Gouy-Chapman theory.

  11. A mean-field theory on the differential capacitance of asymmetric ionic liquid electrolytes.

    PubMed

    Han, Yining; Huang, Shanghui; Yan, Tianying

    2014-07-16

    The size of ions significantly influences the electric double layer structure of room temperature ionic liquid (IL) electrolytes and their differential capacitance (Cd). In this study, we extended the mean-field theory (MFT) developed independently by Kornyshev (2007J. Phys. Chem. B 111 5545-57) and Kilic, Bazant, and Ajdari (2007 Phys. Rev. E 75 021502) (the KKBA MFT) to take into account the asymmetric 1:1 IL electrolytes by introducing an additional parameter ξ for the anion/cation volume ratio, besides the ionic compressibility γ in the KKBA MFT. The MFT of asymmetric ions becomes KKBA MFT upon ξ = 1, and further reduces to Gouy-Chapman theory in the γ → 0 limit. The result of the extended MFT demonstrates that the asymmetric ILs give rise to an asymmetric Cd, with the higher peak in Cd occurring at positive polarization for the smaller anionic size. At high potential, Cd decays asymptotically toward KKBA MFT characterized by γ for the negative polarization, and characterized by ξγ for the positive polarization, with inverse-square-root behavior. At low potential, around the potential of zero charge, the asymmetric ions cause a higher Cd, which exceeds that of Gouy-Chapman theory. PMID:24920102

  12. Linac head scatter factor for asymmetric radiation field

    NASA Astrophysics Data System (ADS)

    Soubra, Mazen Ahmed

    1997-11-01

    the contributing to scatter. However this role was significantly reduced off- axis and other head components, such as the electron beam stopper and the primary collimator, became more important. The role of the mirror and ion chamber was relatively minor. Scatter from the secondary collimators was shown to be a function of the filed size and the position of the collimators in the treatment head. They were also found to play a dual role, both as a scatter source and as an attenuator for scatter produced upstream in the linac head. A closed form model, based on the work of Yu and Slobada, was developed to estimate head scatter factors for on- and off-axis asymmetric fields. The model requires three parameters to fit the measured data. The first, a constant c, has a physical significance and is independent of energy and off-axis distance. The second, g, shows a small variation with the energy and OAD while the third parameter, the primary-to-scatter ratio, is strongly dependent on energy and off-axis distance. Comparison of Sh, predicted by the model, to measurement for a large range of symmetric and asymmetric fields showed excellent agreement. A maximum of 0.7% discrepancy was observed at 12 cm OAD.

  13. Polarization Dependent Switching of Asymmetric Nanorings with a Circular field

    NASA Astrophysics Data System (ADS)

    Pradhan, Nihar; Tuominen, Mark; Aidala, Katherine

    2012-02-01

    We present experimental switching from the onion to vortex states in asymmetric cobalt nanorings in an applied circular field. We initialize the onion state in two polarizations, along the symmetric or asymmetric axes. We apply a circular field by passing current through a solid metal AFM tip positioned at the center of the ring [1]. The asymmetry of the ring leads to different switching fields depending on the location of the domain walls (DWs) and direction of applied field. For polarization along the asymmetric axis, the field required to move the DWs to the narrow side of the ring is smaller than moving the DWs to the larger side of the ring. The direction of the DW motion is controlled by the circular field. When polarizing the ring along the symmetric axis, establishing one DW in the narrow side and one on the wide side, the field required to switch to the vortex state is an intermediate value. We will be presenting detail of the switching field of cobalt nanoring by circular field with two different direction of polarization. (1) T. Yang, N. R. Pradhan, A. Goldman, A. Licht, Y. Li, M. T. Tuominen and K. E. Aidala, Applied Physics Letter, 98, 242505, (2011)

  14. Asymmetric ion transport through ion-channel-mimetic solid-state nanopores.

    PubMed

    Guo, Wei; Tian, Ye; Jiang, Lei

    2013-12-17

    Both scientists and engineers are interested in the design and fabrication of synthetic nanofluidic architectures that mimic the gating functions of biological ion channels. The effort to build such structures requires interdisciplinary efforts at the intersection of chemistry, materials science, and nanotechnology. Biological ion channels and synthetic nanofluidic devices have some structural and chemical similarities, and therefore, they share some common features in regulating the traverse ionic flow. In the past decade, researchers have identified two asymmetric ion transport phenomena in synthetic nanofluidic structures, the rectified ionic current and the net diffusion current. The rectified ionic current is a diode-like current-voltage response that occurs when switching the voltage bias. This phenomenon indicates a preferential direction of transport in the nanofluidic system. The net diffusion current occurs as a direct product of charge selectivity and is generated from the asymmetric diffusion through charged nanofluidic channels. These new ion transport phenomena and the elaborate structures that occur in biology have inspired us to build functional nanofluidic devices for both fundamental research and practical applications. In this Account, we review our recent progress in the design and fabrication of biomimetic solid-state nanofluidic devices with asymmetric ion transport behavior. We demonstrate the origin of the rectified ionic current and the net diffusion current. We also identify several influential factors and discuss how to build these asymmetric features into nanofluidic systems by controlling (1) nanopore geometry, (2) surface charge distribution, (3) chemical composition, (4) channel wall wettability, (5) environmental pH, (6) electrolyte concentration gradient, and (7) ion mobility. In the case of the first four features, we build these asymmetric features directly into the nanofluidic structures. With the final three, we construct

  15. Asymmetric explosion of clusters in intense laser fields

    SciTech Connect

    Kundu, M.

    2012-08-15

    We examine asymmetric expansion of argon clusters illuminated by 800 nm laser pulses of duration Almost-Equal-To 23fs, using three-dimensional particle-in-cell (PIC) simulation. For this short pulse duration, laser energy absorption by cluster electrons is dominated by the nonlinear resonance (NLR) absorption process [Phys. Rev. Lett. 96, 123401 (2006)]. In this work, we concentrate, particularly, on the ionic outcome in the NLR regime and show that higher charge states of argon ions are produced along the laser polarization than in the transverse directions leading to the anisotropy (asymmetry) in the ion energy distribution. This anisotropy already established during the short pulse duration (or in the early duration of a long pulse) may contribute to the anisotropic ion emission reported in cluster experiments with pulse duration longer than 100 fs. Our PIC results are compared with a charged-sphere model showing that cluster explosion is mainly due to Coulomb repulsion between the cluster ions.

  16. Dipolophoresis of dielectric spheroids under asymmetric fields

    NASA Astrophysics Data System (ADS)

    Frankel, Itzchak; Yossifon, Gilad; Miloh, Touvia

    2012-01-01

    Non-spherical particles are common in colloidal science. Spheroidal shapes are particularly convenient for the analysis of the pertinent electrostatic and hydrodynamic problems and are thus widely used to model the manipulation of biological cells as well as deformed drops and bubbles. We study the rotary motion of a dielectric spheroidal micro-particle which is freely suspended in an unbounded electrolyte solution in the presence of a uniform applied electric field, assuming a thin Debye layer. For the common case of a uniform distribution of the native surface-charge density, the rotary motion of the particle is generated by the contributions of the induced-charge electro-osmotic (ICEO) slip and the dielectrophoresis associated with the distribution of the Maxwell stress, respectively. Series solutions are obtained by using spheroidal (prolate or oblate) coordinates. Explicit results are presented for the angular velocity of particles spanning the entire spectrum from rod-like to disk-like shapes. These results demonstrate the non-monotonic variation of the angular speed with the eccentricity of particle shape and the singularity of the multiple limits corresponding to conducting (ideally polarizable) particles of extreme eccentricity (e ≈ 1). The non-monotonic variation of the angular speed with the particle dielectric permittivity is related to the induced-charge contribution. We apply these results to describe the motion of particles subject to a uniform field rotating in the plane. For a sufficiently slow rotation rate, prolate particles eventually become "locked" to the external field with their stationary relative orientation in the plane of rotation being determined by the particle eccentricity and dielectric constant. This effect may be of potential use in the manipulation of poly-disperse suspensions of dielectric non-spherical particles. Oblate spheroids invariably approach a uniform orientation with their symmetry axes directed normal to the external-field

  17. Feasibility of Higher-Order Differential Ion Mobility Separations Using New Asymmetric Waveforms

    PubMed Central

    Shvartsburg, Alexandre A.; Mashkevich, Stefan V.; Smith, Richard D.

    2011-01-01

    Technologies for separating and characterizing ions based on their transport properties in gases have been around for three decades. The early method of ion mobility spectrometry (IMS) distinguished ions by absolute mobility that depends on the collision cross section with buffer gas atoms. The more recent technique of field asymmetric waveform IMS (FAIMS) measures the difference between mobilities at high and low electric fields. Coupling IMS and FAIMS to soft ionization sources and mass spectrometry (MS) has greatly expanded their utility, enabling new applications in biomedical and nanomaterials research. Here, we show that time-dependent electric fields comprising more than two intensity levels could, in principle, effect an infinite number of distinct differential separations based on the higher-order terms of expression for ion mobility. These analyses could employ the hardware and operational procedures similar to those utilized in FAIMS. Methods up to the 4th or 5th order (where conventional IMS is 1st order and FAIMS is 2nd order) should be practical at field intensities accessible in ambient air, with still higher orders potentially achievable in insulating gases. Available experimental data suggest that higher-order separations should be largely orthogonal to each other and to FAIMS, IMS, and MS. PMID:16494377

  18. Digital field ion microscopy

    SciTech Connect

    Sijbrandij, S.J.; Russell, K.F.; Miller, M.K.; Thomson, R.C.

    1998-01-01

    Due to environmental concerns, there is a trend to avoid the use of chemicals needed to develop negatives and to process photographic paper, and to use digital technologies instead. Digital technology also offers the advantages that it is convenient, as it enables quick access to the end result, allows image storage and processing on computer, allows rapid hard copy output, and simplifies electronic publishing. Recently significant improvements have been made to the performance and cost of camera-sensors and printers. In this paper, field ion images recorded with two digital cameras of different resolution are compared to images recorded on standard 35 mm negative film. It should be noted that field ion images exhibit low light intensity and high contrast. Field ion images were recorded from a standard microchannel plate and a phosphor screen and had acceptance angles of {approximately} 60{degree}. Digital recordings were made with a Digital Vision Technologies (DVT) MICAM VHR1000 camera with a resolution of 752 x 582 pixels, and a Kodak DCS 460 digital camera with a resolution of 3,060 x 2,036 pixels. Film based recordings were made with Kodak T-MAX film rated at 400 ASA. The resolving power of T-MAX film, as specified by Kodak, is between 50 and 125 lines per mm, which corresponds to between 1,778 x 1,181 and 4,445 x 2,953 pixels, i.e. similar to that from the DCS 460 camera. The intensities of the images were sufficient to be recorded with standard fl:1.2 lenses with exposure times of less than 2 s. Many digital cameras were excluded from these experiments due to their lack of sensitivity or the inability to record a full frame image due to the fixed working distance defined by the vacuum system. The digital images were output on a Kodak Digital Science 8650 PS dye sublimation color printer (300 dpi). All field ion micrographs presented were obtained from a Ni-Al-Be specimen.

  19. Electro-responsive asymmetric nanopores in polyimide with stable ion-current signal

    NASA Astrophysics Data System (ADS)

    Siwy, Z.; Dobrev, D.; Neumann, R.; Trautmann, C.; Voss, K.

    For the preparation of a single asymmetrically shaped nanopore in a polyimide membrane, Kapton foils were irradiated with single heavy ions and subsequently etched from one side in sodium hypochlorite (NaOCl). The other side of the membrane was protected from etching by a stopping medium containing a reducing agent for hypochlorite ions (OCl-). The resulting conical nanopore rectified ion current and exhibited a stable ion-current flow.

  20. Asymmetric field-aligned currents in the conjugate hemispheres

    NASA Astrophysics Data System (ADS)

    Reistad, J. P.; Ostgaard, N.; Oksavik, K.; Laundal, K. M.

    2012-12-01

    Earlier studies using simultaneous imaging from space of the Aurora Borealis (Northern Hemisphere) and Aurora Australis (Southern Hemisphere) have revealed that the aurora can experience a high degree of asymmetry between the two hemispheres. Using 19 hours of simultaneous global imaging from both hemispheres (IMAGE satellite in north and Polar satellite in south) in conjunction with the entire IMAGE WIC database, we investigate the importance of various mechanisms thought to generate the asymmetries seen in global imaging. In terms of asymmetric or interhemispheric field-aligned currents, three candidate mechanisms have been suggested: 1) Hemispheric differences in solar wind dynamo efficiency mainly controlled by IMF Bx leading to asymmetric region 1 currents; 2) conductivity differences in conjugate areas; and 3) penetration of IMF By into the closed magnetosphere possibly generating a pair of oppositely directed interhemispheric currents. From the 19 hour conjugate dataset we find that the solar wind dynamo is likely to be the most important controlling mechanism for asymmetric bright aurora in the polar part of the nightside oval. Here we present statistical analyses of candidates 1) and 3). Using the entire IMAGE WIC database, a statistical analysis of the auroral brightness distribution along and across the Northern Hemisphere oval is carried out. For each candidate, two extreme cases (+/- IMF Bx for 1) and +/- IMF By for 3)) are compared during times non-favorable for the other two mechanisms. Our results indicate that solar wind dynamo induced currents play an important role for the nightside auroral brightness in an average sense. Also, signatures of interhemispheric currents due to IMF By penetration are seen in our statistics, although this effect is somehow weaker.

  1. Asymmetric line shapes for medium energy H and He ions undergoing a large-angle collision

    NASA Astrophysics Data System (ADS)

    Hazama, M.; Kitsudo, Y.; Nishimura, T.; Hoshino, Y.; Grande, P. L.; Schiwietz, G.; Kido, Y.

    2008-11-01

    Asymmetric line shapes for medium energy H and He ions backscattered from topmost adatoms such as Si(111)-3×3-Sb and Ni(111)-2×2-O are measured by a toroidal electrostatic analyzer with an excellent energy resolution. The spectra exhibit a pronounced asymmetric nature and are well fitted by an exponentially modified Gaussian profile. It is found that the nonperturbative coupled-channel calculations reproduce well the observed asymmetric line shapes for He+ impact on different materials, although slightly overestimate the asymmetry for H+ impact on Au. On the other hand, the CASP 3.2 program (involving additional approximations) gives large underestimates for He ions and overestimates for H ions. This problem has been partially solved by modifying the order of the implementation of the shell corrections and higher-order effects in the CASP model.

  2. Asymmetric Reconnection With a Guide Field: the Saga Continues

    NASA Astrophysics Data System (ADS)

    Hesse, M.; Aunai, N.; Liu, Y. H.; Kuznetsova, M. M.; Birn, J.

    2014-12-01

    Magnetic reconnection at the Earth's magnetopause facilitates the transfer of mass, energy, and momentum from the solar wind into the Earth's magnetosphere. Owing to the variability of the solar wind plasma and magnetic field, the reconnection process typically involves different conditions on both inflow sides, but occasionally more symmetric conditions are encountered as well. Based on prior research we now know that the structure of the reconnection diffusion region depends substantially on the symmetry (or lack thereof) of the inflowing plasmas and magnetic fields. It is therefore of considerable interest to investigate the transition of one scenario to the other - in particular for the purpose of understanding the role of plasma mixing, heating, and of features such as pressure nongyrotropies. This presentation will involve recent theory and modeling results pertaining to these topics, and it will illuminate the means by which these kinetic processes play a role in determining the reconnection rate. Specific emphasis will be on the structure of the reconnection region, when both inflow regions are asymmetric and reconnection occurs at shear angles other than 180 degrees.

  3. Concentrating membrane proteins using asymmetric traps and AC electric fields.

    PubMed

    Cheetham, Matthew R; Bramble, Jonathan P; McMillan, Duncan G G; Krzeminski, Lukasz; Han, Xiaojun; Johnson, Benjamin R G; Bushby, Richard J; Olmsted, Peter D; Jeuken, Lars J C; Marritt, Sophie J; Butt, Julea N; Evans, Stephen D

    2011-05-01

    Membrane proteins are key components of the plasma membrane and are responsible for control of chemical ionic gradients, metabolite and nutrient transfer, and signal transduction between the interior of cells and the external environment. Of the genes in the human genome, 30% code for membrane proteins (Krogh et al. J. Mol. Biol.2001, 305, 567). Furthermore, many FDA-approved drugs target such proteins (Overington et al. Nat. Rev. Drug Discovery 2006, 5, 993). However, the structure-function relationships of these are notably sparse because of difficulties in their purification and handling outside of their membranous environment. Methods that permit the manipulation of membrane components while they are still in the membrane would find widespread application in separation, purification, and eventual structure-function determination of these species (Poo et al. Nature 1977, 265, 602). Here we show that asymmetrically patterned supported lipid bilayers in combination with AC electric fields can lead to efficient manipulation of charged components. We demonstrate the concentration and trapping of such components through the use of a "nested trap" and show that this method is capable of yielding an approximately 30-fold increase in the average protein concentration. Upon removal of the field, the material remains trapped for several hours as a result of topographically restricted diffusion. Our results indicate that this method can be used for concentrating and trapping charged membrane components while they are still within their membranous environment. We anticipate that our approach could find widespread application in the manipulation and study of membrane proteins. PMID:21476549

  4. Ion track symmetric and asymmetric nanopores in polyethylene terephthalate foils for versatile applications

    NASA Astrophysics Data System (ADS)

    Apel, P. Yu.; Blonskaya, I. V.; Dmitriev, S. N.; Orelovich, O. L.; Sartowska, B. A.

    2015-12-01

    In this report we present several fabrication methods which allow production of ion track nanopore membranes with different pore configurations. Polymer foils, typically polyethylene terephthalate with a thickness of 5-23 μm, are irradiated with accelerated heavy ions (energy of 1-10 MeV/u) and then subjected to different physico-chemical treatments. Depending on the procedure, symmetric or asymmetric pores with nanoscale-sized narrowing are obtained. The asymmetric configurations include conical, funnel-like and bullet-like shapes. In electrolyte solutions the asymmetric nanopores exhibit diode-like properties which strongly depend on the pore shape. The peculiar features of such pores provide a basis for various applications.

  5. Counter-Ions Between or at Asymmetrically Charged Walls: 2D Free-Fermion Point

    NASA Astrophysics Data System (ADS)

    Šamaj, Ladislav; Trizac, Emmanuel

    2014-09-01

    This work contributes to the problem of determining effective interaction between asymmetrically (likely or oppositely) charged objects whose total charge is neutralized by mobile pointlike counter-ions of the same charge, the whole system being in thermal equilibrium. The problem is formulated in two spatial dimensions with logarithmic Coulomb interactions. The charged objects correspond to two parallel lines at distance , with fixed line charge densities. Two versions of the model are considered: the standard "unconstrained" one with particles moving freely between the lines and the "constrained" one with particles confined to the lines. We solve exactly both systems at the free-fermion coupling and compare the results for the pressure (i.e. the force between the lines per unit length of one of the lines) with the mean-field Poisson-Boltzmann solution. For the unconstrained model, the large- asymptotic behaviour of the free-fermion pressure differs from that predicted by the mean-field theory. For the constrained model, the asymptotic pressure coincides with the attractive van der Waals-Casimir fluctuational force. For both models, there are fundamental differences between the cases of likely-charged and oppositely-charged lines, the latter case corresponding at large distances to a capacitor.

  6. An analytical method to calculate equivalent fields to irregular symmetric and asymmetric photon fields

    SciTech Connect

    Tahmasebi Birgani, Mohamad J.; Chegeni, Nahid; Zabihzadeh, Mansoor; Hamzian, Nima

    2014-04-01

    Equivalent field is frequently used for central axis depth-dose calculations of rectangular- and irregular-shaped photon beams. As most of the proposed models to calculate the equivalent square field are dosimetry based, a simple physical-based method to calculate the equivalent square field size was used as the basis of this study. The table of the sides of the equivalent square or rectangular fields was constructed and then compared with the well-known tables by BJR and Venselaar, et al. with the average relative error percentage of 2.5 ± 2.5% and 1.5 ± 1.5%, respectively. To evaluate the accuracy of this method, the percentage depth doses (PDDs) were measured for some special irregular symmetric and asymmetric treatment fields and their equivalent squares for Siemens Primus Plus linear accelerator for both energies, 6 and 18 MV. The mean relative differences of PDDs measurement for these fields and their equivalent square was approximately 1% or less. As a result, this method can be employed to calculate equivalent field not only for rectangular fields but also for any irregular symmetric or asymmetric field.

  7. Asymmetric dynamics of ion channel forming proteins - Hepatitis C virus (HCV) p7 bundles.

    PubMed

    Kalita, Monoj Mon; Fischer, Wolfgang B

    2016-07-01

    Protein p7 of hepatitis C virus (HCV) is a short 63 amino acid membrane protein which homo-oligomerises in the lipid membrane to form ion and proton conducting bundles. Two different genotypes (GTs) of p7, 1a and 5a, are used to simulate hexameric bundles of the protein embedded in a fully hydrated lipid bilayer during 400ns molecular dynamics (MD) simulations. Whilst the bundle of GT 1a is based on a fully computational derived structure, the bundle of GT 5a is based on NMR spectroscopic data. Results of a full correlation analysis (FCA) reveal that albeit structural differences both bundles screen local minima during the simulation. The collective motion of the protein domains is asymmetric. No 'breathing-mode'-like dynamics is observed. The presence of divalent ions, such as Ca-ions affects the dynamics of especially solvent exposed parts of the protein, but leaves the asymmetric domain motion unaffected. PMID:27079148

  8. New method of asymmetric flow field measurement in hypersonic shock tunnel.

    PubMed

    Yan, D P; He, A Z; Ni, X W

    1991-03-01

    In this paper a method of large aperture (?500 mm) high sensitivity moire deflectometry is used to obtain multidirectional deflectograms of the asymmetric flow field in hypersonic (M = 10.29) shock tunnel. At the same time, a 3-D reconstructive method of the asymmetric flow field is presented which is based on the integration of the moire deflective angle and the double-cubic many-knot interpolating splines; it is used to calculate the 3-D density distribution of the asymmetric flow field. PMID:20582058

  9. Asymmetric Functional Conversion of Eubacterial Light-driven Ion Pumps.

    PubMed

    Inoue, Keiichi; Nomura, Yurika; Kandori, Hideki

    2016-05-01

    In addition to the well-known light-driven outward proton pumps, novel ion-pumping rhodopsins functioning as outward Na(+) and inward Cl(-) pumps have been recently found in eubacteria. They convert light energy into transmembrane electrochemical potential difference, similar to the prototypical archaeal H(+) pump bacteriorhodopsin (BR) and Cl(-) pump halorhodopsin (HR). The H(+), Na(+), and Cl(-) pumps possess the conserved respective DTE, NDQ, and NTQ motifs in the helix C, which likely serve as their functional determinants. To verify this hypothesis, we attempted functional interconversion between selected pumps from each category by mutagenesis. Introduction of the proton-pumping motif resulted in successful Na(+) → H(+) functional conversion. Introduction of the respective characteristic motifs with several additional mutations leads to successful Na(+) → Cl(-) and Cl(-) → H(+) functional conversions, whereas remaining conversions (H(+) → Na(+), H(+) → Cl(-), Cl(-) → Na(+)) were unsuccessful when mutagenesis of 4-6 residues was used. Phylogenetic analysis suggests that a H(+) pump is the common ancestor of all of these rhodopsins, from which Cl(-) pumps emerged followed by Na(+) pumps. We propose that successful functional conversions of these ion pumps are achieved exclusively when mutagenesis reverses the evolutionary amino acid sequence changes. Dependence of the observed functional conversions on the direction of evolution strongly suggests that the essential structural mechanism of an ancestral function is retained even after the gain of a new function during natural evolution, which can be evoked by a few mutations. By contrast, the gain of a new function needs accumulation of multiple mutations, which may not be easily reproduced by limited mutagenesis in vitro. PMID:26929409

  10. Ion size effects on the osmotic pressure and electrocapillarity in a nanoslit: Symmetric and asymmetric ion sizes

    NASA Astrophysics Data System (ADS)

    Rajni; Oh, J. M.; Kang, I. S.

    2016-06-01

    We analyze the effect of asymmetric finite ion size in nanoconfinement in the view of osmotic pressure and electrocapillarity. When the confinement width becomes comparable with the Debye length, the overlapped electric double layer is significantly deformed by the steric effects. We derive the osmotic pressure from the modified Poisson-Boltzmann equation in a nanoslit to examine the deviation from the ideal osmotic pressure and the repulsive force on the wall considering the asymmetry of ion sizes. Then the electrocapillarity due to the steric effect is investigated under constant potential condition with the flat interface assumption. Later, the deformation by the electrocapillarity is also considered in the first order approximation.

  11. Ion size effects on the osmotic pressure and electrocapillarity in a nanoslit: Symmetric and asymmetric ion sizes.

    PubMed

    Rajni; Oh, J M; Kang, I S

    2016-06-01

    We analyze the effect of asymmetric finite ion size in nanoconfinement in the view of osmotic pressure and electrocapillarity. When the confinement width becomes comparable with the Debye length, the overlapped electric double layer is significantly deformed by the steric effects. We derive the osmotic pressure from the modified Poisson-Boltzmann equation in a nanoslit to examine the deviation from the ideal osmotic pressure and the repulsive force on the wall considering the asymmetry of ion sizes. Then the electrocapillarity due to the steric effect is investigated under constant potential condition with the flat interface assumption. Later, the deformation by the electrocapillarity is also considered in the first order approximation. PMID:27415363

  12. Generation of circularly polarized attosecond pulses by intense ultrashort laser pulses from extended asymmetric molecular ions

    NASA Astrophysics Data System (ADS)

    Yuan, Kai-Jun; Bandrauk, André D.

    2011-08-01

    We present a method for generation of single circularly polarized attosecond pulses in extended asymmetric HHe2+ molecular ions. By employing an intense ultrashort circularly polarized laser pulse with intensity 4.0×1014 W/cm2, wavelength 400 nm, and duration 10 optical cycles, molecular high-order-harmonic generation (MHOHG) spectra with multiple plateaus exhibit characters of circular polarization. Using a classical laser-induced collision model, double collisions of continuum electrons first with neighboring ions and then second with parent ions are presented at a particular internuclear distance and confirmed from numerical solutions of a time-dependent Schrödinger equation. We analyze the MHOHG spectra with a Gabor time window and find that, due to the asymmetry of HHe2+, a single collision trajectory of continuum electrons with ions can produce circularly polarized harmonics, leading to single circularly polarized attosecond pulses for specific internuclear distances.

  13. Generation of circularly polarized attosecond pulses by intense ultrashort laser pulses from extended asymmetric molecular ions

    SciTech Connect

    Yuan, Kai-Jun; Bandrauk, Andre D.

    2011-08-15

    We present a method for generation of single circularly polarized attosecond pulses in extended asymmetric HHe{sup 2+} molecular ions. By employing an intense ultrashort circularly polarized laser pulse with intensity 4.0x10{sup 14} W/cm{sup 2}, wavelength 400 nm, and duration 10 optical cycles, molecular high-order-harmonic generation (MHOHG) spectra with multiple plateaus exhibit characters of circular polarization. Using a classical laser-induced collision model, double collisions of continuum electrons first with neighboring ions and then second with parent ions are presented at a particular internuclear distance and confirmed from numerical solutions of a time-dependent Schroedinger equation. We analyze the MHOHG spectra with a Gabor time window and find that, due to the asymmetry of HHe{sup 2+}, a single collision trajectory of continuum electrons with ions can produce circularly polarized harmonics, leading to single circularly polarized attosecond pulses for specific internuclear distances.

  14. Detection, identification, and occurrence of thiotetronic acids in drinking water from underground sources by electrospray ionization-high field asymmetric waveform ion mobility spectrometry-quadrupole time-of-flight-mass spectrometry.

    PubMed

    Lyczko, Jadwiga; Beach, Daniel; Gabryelski, Wojciech

    2015-10-01

    This paper demonstrates that electrospray ionization (ESI) with differential ion mobility spectroscopy (FAIMS) and "soft" mass spectrometry (MS) provide unique analytical capabilities that led to the discovery of sulfur-containing polar congeners of thiotetronic acid (TA) in drinking water from underground sources in Canada and the United States. Polar TAs accumulate in underground aquifers and appear to be the most abundant class of organic compounds in bottled water but cannot be detected by conventional mass spectrometry methods. We show that normally stable TAs are converted into very reactive ions in ESI which have to be analyzed using special conditions in ESI-FAIMS-MS to avoid extensive dissociation and ion/molecule reactions. De novo identification of 10 TAs was accomplished by the comparative tandem mass spectrometry analysis of authentic TA derivatives from groundwater samples and synthetic TA analogues prepared for this study. We present highlights of gas phase ion chemistry of polar TAs to explain their unique properties and reactivity. TA derivatives were originally isolated from soil bacteria and are of interest in the pharmaceutical industry due to their potent activity against a broad spectrum of pathogenic bacteria and negligible toxicity to mammals. We suspect that TAs are natural disinfection agents protecting groundwater from bacterial contamination, but these compound undergo modifications or decompose during an ozonation water treatment. PMID:26340067

  15. Improving the field-effect performance of Bi2S3 single nanowires by an asymmetric device fabrication.

    PubMed

    Lu, Fangyuan; Li, Renxiong; Li, Yan; Huo, Nengjie; Yang, Juehan; Li, Yongtao; Li, Bo; Yang, Shengxue; Wei, Zhongming; Li, Jingbo

    2015-01-12

    High-quality Bi2 S3 nanowires are synthesized by chemical vapor deposition and their intrinsic photoresponsive and field-effect characteristics are explored in detail. Among the studied Au-Au, Ag-Ag, and Au-Ag electrode pairs, the device with stepwise band alignment of asymmetric Au-Ag electrodes has the highest mobility. Furthermore, it is shown that light can cause a sevenfold decrease of the on/off ratio. This can be explained by the photoexcited charge carriers that are more beneficial to the increase of Ioff than Ion . The photoresponsive properties of the asymmetric Au-Ag electrode devices were also explored, and the results show a photoconductive gain of seven with a rise time of 2.9 s and a decay time of 1.6 s. PMID:25294685

  16. Implosion and explosion of electrostatic cylindrical and spherical shocks in asymmetric pair-ion plasmas

    SciTech Connect

    Masood, W.; Rizvi, H.

    2011-04-15

    Nonlinear electrostatic shock waves are studied in unmagnetized, dissipative pair-ion plasmas. The dissipation in the system is taken into account by considering the effect of kinematic viscosity of both positive and negative ions in plasmas. The system of fluid equations for asymmetric pair-ion plasma is reduced to Korteweg-deVries-Burgers equation in the limit of small amplitude perturbation. It is observed that the system under consideration admits rarefactive shocks. Keeping in view the practical applications, the nonlinear propagation of both the exploding and imploding shocks is investigated and the differences are expounded in detail. The present study may have relevance in the study of the formation of electrostatic shocks in laser-induced implosion devices, star formation, supernovae explosion, etc.

  17. Constraints on the asymmetric equation of state from heavy-ion collisions

    NASA Astrophysics Data System (ADS)

    Yennello, Sherry; McIntosh, Alan; Heilborn, Lauren

    2016-05-01

    Nuclear matter is one of the most fascinating materials that exists.Therefore elucidating the equation-of-state of nuclear matter is a fundamentally interesting question. Additionally, the nuclear equationof-state has impacts on astrophysical observables. One important means of constraining the nuclear equation-of-state is through studying heavy-ion collisions. Nuclear material has two components - neutrons and protons - the ratio of which impacts the equation-of-state. Measurements of fragments emitted from reactions of nuclei with different ratios of neutrons and protons - and comparison to simulations based on various underlying interactions - have placed constraints on both the symmetric and asymmetric parts of the equation of state.

  18. Using heavy-ion collisions to elucidate the asymmetric equation-of-state

    NASA Astrophysics Data System (ADS)

    Yennello, Sherry; McIntosh, Alan

    2016-06-01

    The nuclear equation-of-state impacts a number of nuclear properties as well as astrophysical processes. The asymmetric term of the equation-of-state, which describes the behavior away from N=Z, has significant uncertainty. Giant resonances and nuclear masses can elucidate the asymmetry energy for cold normal-density nuclei. Heavy-ion collisions can be used to probe nuclear matter at higher temperatures and densities away from saturation density. The temperatures that are attained in these nuclear collisions are predicted to depend on the isospin asymmetry. In this work we present evidence of the asymmetry dependence of the nuclear caloric curve.

  19. Three-Dimensional Quantitative Optical Measurement of Asymmetrically Focused Ultrasound Pressure Field

    NASA Astrophysics Data System (ADS)

    Shimazaki, Yuta; Harigane, Soichiro; Yoshizawa, Shin; Umemura, Shin-ichiro

    2012-07-01

    High-intensity focused ultrasound (HIFU) is used for the treatment of tumors such as prostate cancer. In the development of this technique, an accurate and fast measurement of the HIFU pressure field is important. A hydrophone is generally used for the measurement, but it might disturb the pressure field and scanning it in the field takes a long time. On the other hand, optical ultrasonic field mapping has the advantages of speed and its nature of not by interfering with the acoustic field. In this study, we reconstructed an asymmetric ultrasound field by optical measurement using a computed tomography (CT) algorithm. The asymmetric field was generated by a focused transducer with four elements. Also, the absolute measurement of ultrasonic pressure was checked by measuring the center of the field of the charge-coupled device (CCD) camera. The results showed overall agreement with those of hydrophone measurement.

  20. Asymmetric error field interaction with rotating conducting walls

    SciTech Connect

    Paz-Soldan, C.; Brookhart, M. I.; Hegna, C. C.; Forest, C. B.

    2012-07-15

    The interaction of error fields with a system of differentially rotating conducting walls is studied analytically and compared to experimental data. Wall rotation causes eddy currents to persist indefinitely, attenuating and rotating the original error field. Superposition of error fields from external coils and plasma currents are found to break the symmetry in wall rotation direction. The vacuum and plasma eigenmodes are modified by wall rotation, with the error field penetration time decreased and the kink instability stabilized, respectively. Wall rotation is also predicted to reduce error field amplification by the marginally stable plasma.

  1. The Asymmetric Polar Field Reversal - Long Term Observations from WSO

    NASA Astrophysics Data System (ADS)

    Hoeksema, J. T.

    2012-12-01

    The Sun's polar field above 55 degrees in the northern hemisphere is reversing and the southern field may be beginning to weaken. This asymmetry is not unusual and is related to the poleward transport of flux that emerged in the active region bands earlier in the cycle. In the declining phase of Cycle 23 the poles were fairly equal, but the northern field began to decay in early 2009. Prior cycles have behaved differently, as observed by the Wilcox Solar Observatory and elsewhere.

  2. Interaction of toluene with two-color asymmetric laser fields: Controlling the directional emission of molecular hydrogen fragments

    NASA Astrophysics Data System (ADS)

    Kaziannis, S.; Kotsina, N.; Kosmidis, C.

    2014-09-01

    The interaction of toluene with strong asymmetric two-color laser irradiation of 40 fs duration is studied by means of Time of flight mass spectrometry. Highly energetic H2+ and H3+ fragment ions are produced through an isomerization process taking place within transient multiply charged parent ions. Comparative study of deuterium labeled toluene isotopes enables the discrimination between molecular hydrogen fragments formed exclusively within the CH3- part from those that require hydrogen atom exchange between the former and the phenyl moiety. It is demonstrated that by manipulating the relative phase of the ω/2ω field components the selective ionization of oriented toluene molecules can be used as a tool to control the directional emission of the H2+, H3+ species.

  3. Interaction of toluene with two-color asymmetric laser fields: controlling the directional emission of molecular hydrogen fragments.

    PubMed

    Kaziannis, S; Kotsina, N; Kosmidis, C

    2014-09-14

    The interaction of toluene with strong asymmetric two-color laser irradiation of 40 fs duration is studied by means of Time of flight mass spectrometry. Highly energetic H2(+) and H3(+) fragment ions are produced through an isomerization process taking place within transient multiply charged parent ions. Comparative study of deuterium labeled toluene isotopes enables the discrimination between molecular hydrogen fragments formed exclusively within the CH3- part from those that require hydrogen atom exchange between the former and the phenyl moiety. It is demonstrated that by manipulating the relative phase of the ω/2ω field components the selective ionization of oriented toluene molecules can be used as a tool to control the directional emission of the H2(+), H3(+) species. PMID:25217928

  4. Interaction of toluene with two-color asymmetric laser fields: Controlling the directional emission of molecular hydrogen fragments

    SciTech Connect

    Kaziannis, S.; Kotsina, N.; Kosmidis, C.

    2014-09-14

    The interaction of toluene with strong asymmetric two-color laser irradiation of 40 fs duration is studied by means of Time of flight mass spectrometry. Highly energetic H{sub 2}{sup +} and H{sub 3}{sup +} fragment ions are produced through an isomerization process taking place within transient multiply charged parent ions. Comparative study of deuterium labeled toluene isotopes enables the discrimination between molecular hydrogen fragments formed exclusively within the CH{sub 3}- part from those that require hydrogen atom exchange between the former and the phenyl moiety. It is demonstrated that by manipulating the relative phase of the ω/2ω field components the selective ionization of oriented toluene molecules can be used as a tool to control the directional emission of the H{sub 2}{sup +}, H{sub 3}{sup +} species.

  5. Digital Holographic setup for Measurement of Asymmetric Temperature Field and Tomographic Reconstruction

    NASA Astrophysics Data System (ADS)

    Doleček, R.; Kopecký, V.; Psota, P.; Lédl, V.

    2013-04-01

    This paper presents a digital holographic multidirectional interferometric method for measurement of periodic asymmetric temperature fields. This method uses a modified Twymann-Green setup having double sensitivity. The setup employs one precisely synchronized and triggered CCD camera with a measured coherent phenomenon. That allows a large number of the phenomenon's different projections capturing which are used for 3D tomographic reconstruction..

  6. Ion flux's pressure dependence in an asymmetric capacitively coupled rf discharge in NF3

    NASA Astrophysics Data System (ADS)

    Mateev, Emil; Zhelyazkov, Ivan

    2004-03-01

    Starting from an analytical macroscopic/phenomenological model yielding the self-bias voltage as a function of the absorbed radio-frequency (rf) power of an asymmetric capacitively coupled discharge in NF3 this paper studies the dependence of the ion flux onto the powered electrode on the gas pressure. An essential feature of the model is the assumption that the ions' drift velocity in the sheath near the powered electrode is proportional to E α, where E=-ΔU (U being the self-bias potential), and α is a coefficient depending on the gas pressure and cross section of elastic ion-neutral collisions. The model also considers the role of γ-electrons, stochastic heating as well as the contribution of the active electron current to the global discharge power balance. Numerically solving the model's basic equations one can extract the magnitude of the ion flux (at three different gas pressures) in a technological etching device (Alcatel GIR 220) by using easily measurable quantities, notably the self-bias voltage and absorbed rf power.

  7. Design of vortex fluid amplifiers with asymmetrical flow fields.

    NASA Technical Reports Server (NTRS)

    Lawley, T. J.; Price, D. C.

    1972-01-01

    Variation of geometric parameters, including supply area, control area, chamber length, and outlet diameter, of a large scale, modular design vortex fluid amplifier with single supply and control jets, has confirmed and extended a previously published design method, developed for vortex amplifiers with symmetric flow fields. This allows application of the method to devices which are more representative of practical, production type components.

  8. Adapting military field water supplies to the asymmetric battlefield.

    PubMed

    Lundquist, Arthur H; White, George H; Bonilla, Alejandro; Richards, Todd E; Richards, Stephen C

    2011-01-01

    Army transformation to a brigade-centric force has created a distributed battlefield, challenging the surveillance and logistical supply of field water. The daily requirement of up to 15 gal of potable water per person per day from bulk water supplies has been achievable for many years using currently fielded ROWPUs. However, the need to reduce the transport of water and move towards a sustainable force has created a gap in materiel capable of producing safe water at the individual and unit level. While materiel development is slow, the PM community, tasked with doctrine development and battlefield oversight of field water, is beginning to address the requirements of field water on the changed battlefield. In addition to materiel gaps, the transformed battlefield has created a lack of trained personnel for water production and oversight. Without trained operators and PM oversight, to what level of health risk are consumers of this water exposing themselves? Currently PM is unable to answer this question but is working diligently with the RDT&E community to develop materiel solutions, and with the medical community to provide interim guidance to reduce the potential health risks to using such equipment. PMID:21805456

  9. Laser ion source with solenoid field

    NASA Astrophysics Data System (ADS)

    Kanesue, Takeshi; Fuwa, Yasuhiro; Kondo, Kotaro; Okamura, Masahiro

    2014-11-01

    Pulse length extension of highly charged ion beam generated from a laser ion source is experimentally demonstrated. The laser ion source (LIS) has been recognized as one of the most powerful heavy ion source. However, it was difficult to provide long pulse beams. By applying a solenoid field (90 mT, 1 m) at plasma drifting section, a pulse length of carbon ion beam reached 3.2 μs which was 4.4 times longer than the width from a conventional LIS. The particle number of carbon ions accelerated by a radio frequency quadrupole linear accelerator was 1.2 × 1011, which was provided by a single 1 J Nd-YAG laser shot. A laser ion source with solenoid field could be used in a next generation heavy ion accelerator.

  10. Laser ion source with solenoid field

    SciTech Connect

    Kanesue, Takeshi Okamura, Masahiro; Fuwa, Yasuhiro; Kondo, Kotaro

    2014-11-10

    Pulse length extension of highly charged ion beam generated from a laser ion source is experimentally demonstrated. The laser ion source (LIS) has been recognized as one of the most powerful heavy ion source. However, it was difficult to provide long pulse beams. By applying a solenoid field (90 mT, 1 m) at plasma drifting section, a pulse length of carbon ion beam reached 3.2 μs which was 4.4 times longer than the width from a conventional LIS. The particle number of carbon ions accelerated by a radio frequency quadrupole linear accelerator was 1.2 × 10{sup 11}, which was provided by a single 1 J Nd-YAG laser shot. A laser ion source with solenoid field could be used in a next generation heavy ion accelerator.

  11. Laser ion source with solenoid field

    SciTech Connect

    Kanesue, Takeshi; Fuwa, Yasuhiro; Kondo, Kotaro; Okamura, Masahiro

    2014-11-12

    Pulse length extension of highly charged ion beam generated from a laser ion source is experimentally demonstrated. In this study, the laser ion source (LIS) has been recognized as one of the most powerful heavy ion source. However, it was difficult to provide long pulse beams. By applying a solenoid field (90 mT, 1 m) at plasma drifting section, a pulse length of carbon ion beam reached 3.2 μs which was 4.4 times longer than the width from a conventional LIS. The particle number of carbon ions accelerated by a radio frequency quadrupole linear accelerator was 1.2 × 1011, which was provided by a single 1 J Nd-YAG laser shot. A laser ion source with solenoid field could be used in a next generation heavy ion accelerator.

  12. Laser ion source with solenoid field

    DOE PAGESBeta

    Kanesue, Takeshi; Fuwa, Yasuhiro; Kondo, Kotaro; Okamura, Masahiro

    2014-11-12

    Pulse length extension of highly charged ion beam generated from a laser ion source is experimentally demonstrated. In this study, the laser ion source (LIS) has been recognized as one of the most powerful heavy ion source. However, it was difficult to provide long pulse beams. By applying a solenoid field (90 mT, 1 m) at plasma drifting section, a pulse length of carbon ion beam reached 3.2 μs which was 4.4 times longer than the width from a conventional LIS. The particle number of carbon ions accelerated by a radio frequency quadrupole linear accelerator was 1.2 × 1011, whichmore » was provided by a single 1 J Nd-YAG laser shot. A laser ion source with solenoid field could be used in a next generation heavy ion accelerator.« less

  13. Self-assembled asymmetric membrane containing micron-size germanium for high capacity lithium ion batteries

    DOE PAGESBeta

    Byrd, Ian; Chen, Hao; Webber, Theron; Li, Jianlin; Wu, Ji

    2015-10-23

    We report the formation of novel asymmetric membrane electrode containing micron-size (~5 μm) germanium powders through a self-assembly phase inversion method for high capacity lithium ion battery anode. 850 mA h g-1 capacity (70%) can be retained at a current density of 600 mA g-1 after 100 cycles with excellent rate performance. Such a high retention rate has rarely been seen for pristine micron-size germanium anodes. Moreover, scanning electron microscope studies reveal that germanium powders are uniformly embedded in a networking porous structure consisting of both nanopores and macropores. It is believed that such a unique porous structure can efficientlymore » accommodate the ~260% volume change during germanium alloying and de-alloying process, resulting in an enhanced cycling performance. Finally, these porous membrane electrodes can be manufactured in large scale using a roll-to-roll processing method.« less

  14. Self-assembled asymmetric membrane containing micron-size germanium for high capacity lithium ion batteries

    SciTech Connect

    Byrd, Ian; Chen, Hao; Webber, Theron; Li, Jianlin; Wu, Ji

    2015-10-23

    We report the formation of novel asymmetric membrane electrode containing micron-size (~5 μm) germanium powders through a self-assembly phase inversion method for high capacity lithium ion battery anode. 850 mA h g-1 capacity (70%) can be retained at a current density of 600 mA g-1 after 100 cycles with excellent rate performance. Such a high retention rate has rarely been seen for pristine micron-size germanium anodes. Moreover, scanning electron microscope studies reveal that germanium powders are uniformly embedded in a networking porous structure consisting of both nanopores and macropores. It is believed that such a unique porous structure can efficiently accommodate the ~260% volume change during germanium alloying and de-alloying process, resulting in an enhanced cycling performance. Finally, these porous membrane electrodes can be manufactured in large scale using a roll-to-roll processing method.

  15. Dynamics of a reconnection-driven runaway ion tail in a reversed field pinch plasma

    NASA Astrophysics Data System (ADS)

    Anderson, J. K.; Kim, J.; Bonofiglo, P. J.; Capecchi, W.; Eilerman, S.; Nornberg, M. D.; Sarff, J. S.; Sears, S. H.

    2016-05-01

    While reconnection-driven ion heating is common in laboratory and astrophysical plasmas, the underlying mechanisms for converting magnetic to kinetic energy remain not fully understood. Reversed field pinch discharges are often characterized by rapid ion heating during impulsive reconnection, generating an ion distribution with an enhanced bulk temperature, mainly perpendicular to magnetic field. In the Madison Symmetric Torus, a subset of discharges with the strongest reconnection events develop a very anisotropic, high energy tail parallel to magnetic field in addition to bulk perpendicular heating, which produces a fusion neutron flux orders of magnitude higher than that expected from a Maxwellian distribution. Here, we demonstrate that two factors in addition to a perpendicular bulk heating mechanism must be considered to explain this distribution. First, ion runaway can occur in the strong parallel-to-B electric field induced by a rapid equilibrium change triggered by reconnection-based relaxation; this effect is particularly strong on perpendicularly heated ions which experience a reduced frictional drag relative to bulk ions. Second, the confinement of ions varies dramatically as a function of velocity. Whereas thermal ions are governed by stochastic diffusion along tearing-altered field lines (and radial diffusion increases with parallel speed), sufficiently energetic ions are well confined, only weakly affected by a stochastic magnetic field. High energy ions traveling mainly in the direction of toroidal plasma current are nearly classically confined, while counter-propagating ions experience an intermediate confinement, greater than that of thermal ions but significantly less than classical expectations. The details of ion confinement tend to reinforce the asymmetric drive of the parallel electric field, resulting in a very asymmetric, anisotropic distribution.

  16. Improvement of infrared near-field spectrum by asymmetric interferometer configuration

    NASA Astrophysics Data System (ADS)

    Ikemoto, Yuka; Okamura, Hidekazu; Moriwaki, Taro; Suto, Hitoshi; Kinoshita, Toyohiko

    2015-08-01

    Infrared synchrotron radiation (IR-SR) is a highly brilliant white light source. We are developing an infrared near-field spectroscopy system with an IR-SR light source. The near-field spectroscopy system previously reported comprised an atomic force microscope (AFM) and a commercial Fourier transform infrared (FTIR) spectrometer. In the present study, the configuration of the FTIR interferometer has been modified to an asymmetric one. In the asymmetric interferometer, one beam split by a beamsplitter is focused onto the tip of an AFM probe, and the other beam goes to a movable mirror. The scattered light from the probe and the light reflected by the movable mirror interfere with each other. The near-field signal is extracted by a modulation method with an AFM oscillation frequency. The signal-to-noise ratio has been improved 6-fold and the signal-to-background ratio is improved 8-fold compared with those observed in the previous system.

  17. Numerical simulation of mass injection for the formation of prominence magnetic field configurations. I - Asymmetric injection

    NASA Technical Reports Server (NTRS)

    An, Chang-Hyuk; Bao, J. J.; Wu, S. T.

    1988-01-01

    A two-dimensional ideal MHD numerical model is used to investigate chromospheric mass injection into an overlying coronal dipole magnetic field. Such injection is shown to produce magnetic field deformations conducive to the formation of active region prominences. The results support a model in which an absorptive strand is formed by chromospheric asymmetric mass injection into the overlying coronal magnetic field. A necessary condition for the accumulation of the strands is that the mass injection forms a Kippenhahn-Schluter-type (1957) field configuration.

  18. Assessing Adaptation with Asymmetric Climate Information: evidence from water bargaining field experiments in Northeast Brazil

    NASA Astrophysics Data System (ADS)

    Pfaff, A.; Velez, M.; Taddei, R.; Broad, K.

    2011-12-01

    We assess how asymmetric climate information affects bargaining -- an adaptation institution. As often observed in the field, some actors lack information. This yields vulnerability, despite participation. We examine the loss for a participant from being uncertain about water quantity when bargaining with a fully informed participant in an ultimatum game in Northeast Brazil. When all are fully informed, our field populations in the capital city and an agricultural valley produce a typical 60-40 split between those initiating and responding in one-shot bargaining. With asymmetric information, when initiators know the water quantity is low they get 80%. Thus even within bargaining, i.e. given strong participation, better integrating climate science into water management via greater effort to communicate relevant information to all involved can help to avoid inequities that could arise despite all of the stakeholders being 'at the table', as may well occur within future water allocation along a large new canal in the case we study.

  19. Asymmetric catalytic formation of quaternary carbons by iminium ion trapping of radicals.

    PubMed

    Murphy, John J; Bastida, David; Paria, Suva; Fagnoni, Maurizio; Melchiorre, Paolo

    2016-04-14

    An important goal of modern organic chemistry is to develop new catalytic strategies for enantioselective carbon-carbon bond formation that can be used to generate quaternary stereogenic centres. Whereas considerable advances have been achieved by exploiting polar reactivity, radical transformations have been far less successful. This is despite the fact that open-shell intermediates are intrinsically primed for connecting structurally congested carbons, as their reactivity is only marginally affected by steric factors. Here we show how the combination of photoredox and asymmetric organic catalysis enables enantioselective radical conjugate additions to β,β-disubstituted cyclic enones to obtain quaternary carbon stereocentres with high fidelity. Critical to our success was the design of a chiral organic catalyst, containing a redox-active carbazole moiety, that drives the formation of iminium ions and the stereoselective trapping of photochemically generated carbon-centred radicals by means of an electron-relay mechanism. We demonstrate the generality of this organocatalytic radical-trapping strategy with two sets of open-shell intermediates, formed through unrelated light-triggered pathways from readily available substrates and photoredox catalysts--this method represents the application of iminium ion activation (a successful catalytic strategy for enantioselective polar chemistry) within the realm of radical reactivity. PMID:27075098

  20. Asymmetric catalytic formation of quaternary carbons by iminium ion trapping of radicals

    NASA Astrophysics Data System (ADS)

    Murphy, John J.; Bastida, David; Paria, Suva; Fagnoni, Maurizio; Melchiorre, Paolo

    2016-04-01

    An important goal of modern organic chemistry is to develop new catalytic strategies for enantioselective carbon–carbon bond formation that can be used to generate quaternary stereogenic centres. Whereas considerable advances have been achieved by exploiting polar reactivity, radical transformations have been far less successful. This is despite the fact that open-shell intermediates are intrinsically primed for connecting structurally congested carbons, as their reactivity is only marginally affected by steric factors. Here we show how the combination of photoredox and asymmetric organic catalysis enables enantioselective radical conjugate additions to β,β-disubstituted cyclic enones to obtain quaternary carbon stereocentres with high fidelity. Critical to our success was the design of a chiral organic catalyst, containing a redox-active carbazole moiety, that drives the formation of iminium ions and the stereoselective trapping of photochemically generated carbon-centred radicals by means of an electron-relay mechanism. We demonstrate the generality of this organocatalytic radical-trapping strategy with two sets of open-shell intermediates, formed through unrelated light-triggered pathways from readily available substrates and photoredox catalysts—this method represents the application of iminium ion activation (a successful catalytic strategy for enantioselective polar chemistry) within the realm of radical reactivity.

  1. Asymmetric kinetic equilibria: Generalization of the BAS model for rotating magnetic profile and non-zero electric field

    SciTech Connect

    Dorville, Nicolas Belmont, Gérard; Aunai, Nicolas; Dargent, Jérémy; Rezeau, Laurence

    2015-09-15

    Finding kinetic equilibria for non-collisional/collisionless tangential current layers is a key issue as well for their theoretical modeling as for our understanding of the processes that disturb them, such as tearing or Kelvin Helmholtz instabilities. The famous Harris equilibrium [E. Harris, Il Nuovo Cimento Ser. 10 23, 115–121 (1962)] assumes drifting Maxwellian distributions for ions and electrons, with constant temperatures and flow velocities; these assumptions lead to symmetric layers surrounded by vacuum. This strongly particular kind of layer is not suited for the general case: asymmetric boundaries between two media with different plasmas and different magnetic fields. The standard method for constructing more general kinetic equilibria consists in using Jeans theorem, which says that any function depending only on the Hamiltonian constants of motion is a solution to the steady Vlasov equation [P. J. Channell, Phys. Fluids (1958–1988) 19, 1541 (1976); M. Roth et al., Space Sci. Rev. 76, 251–317 (1996); and F. Mottez, Phys. Plasmas 10, 1541–1545 (2003)]. The inverse implication is however not true: when using the motion invariants as variables instead of the velocity components, the general stationary particle distributions keep on depending explicitly of the position, in addition to the implicit dependence introduced by these invariants. The standard approach therefore strongly restricts the class of solutions to the problem and probably does not select the most physically reasonable. The BAS (Belmont-Aunai-Smets) model [G. Belmont et al., Phys. Plasmas 19, 022108 (2012)] used for the first time the concept of particle accessibility to find new solutions: considering the case of a coplanar-antiparallel magnetic field configuration without electric field, asymmetric solutions could be found while the standard method can only lead to symmetric ones. These solutions were validated in a hybrid simulation [N. Aunai et al., Phys. Plasmas (1994-present

  2. Asymmetric kinetic equilibria: Generalization of the BAS model for rotating magnetic profile and non-zero electric field

    NASA Astrophysics Data System (ADS)

    Dorville, Nicolas; Belmont, Gérard; Aunai, Nicolas; Dargent, Jérémy; Rezeau, Laurence

    2015-09-01

    Finding kinetic equilibria for non-collisional/collisionless tangential current layers is a key issue as well for their theoretical modeling as for our understanding of the processes that disturb them, such as tearing or Kelvin Helmholtz instabilities. The famous Harris equilibrium [E. Harris, Il Nuovo Cimento Ser. 10 23, 115-121 (1962)] assumes drifting Maxwellian distributions for ions and electrons, with constant temperatures and flow velocities; these assumptions lead to symmetric layers surrounded by vacuum. This strongly particular kind of layer is not suited for the general case: asymmetric boundaries between two media with different plasmas and different magnetic fields. The standard method for constructing more general kinetic equilibria consists in using Jeans theorem, which says that any function depending only on the Hamiltonian constants of motion is a solution to the steady Vlasov equation [P. J. Channell, Phys. Fluids (1958-1988) 19, 1541 (1976); M. Roth et al., Space Sci. Rev. 76, 251-317 (1996); and F. Mottez, Phys. Plasmas 10, 1541-1545 (2003)]. The inverse implication is however not true: when using the motion invariants as variables instead of the velocity components, the general stationary particle distributions keep on depending explicitly of the position, in addition to the implicit dependence introduced by these invariants. The standard approach therefore strongly restricts the class of solutions to the problem and probably does not select the most physically reasonable. The BAS (Belmont-Aunai-Smets) model [G. Belmont et al., Phys. Plasmas 19, 022108 (2012)] used for the first time the concept of particle accessibility to find new solutions: considering the case of a coplanar-antiparallel magnetic field configuration without electric field, asymmetric solutions could be found while the standard method can only lead to symmetric ones. These solutions were validated in a hybrid simulation [N. Aunai et al., Phys. Plasmas (1994-present) 20

  3. Field-free molecular alignment of asymmetric top molecules using elliptically polarized laser pulses

    NASA Astrophysics Data System (ADS)

    Rouzée, A.; Guérin, S.; Faucher, O.; Lavorel, B.

    2008-04-01

    We show theoretically that a short specific elliptically polarized laser pulse driving an asymmetric top molecule can induce postpulse revivals of three-dimensional (3D) alignment. By choosing the field ellipticity resulting in the best compromise between the alignment of two molecular axes, we demonstrate that efficient 3D alignment can be achieved at low temperature. In the experiment, the field-free alignment of moderately cool ethylene molecules is probed by using a technique based on the optical Kerr effect. Control of 3D field-free alignment opens the door to a large range of applications in chemistry as well as in molecular optics.

  4. Determination of the functioning parameters in asymmetrical flow field-flow fractionation with an exponential channel.

    PubMed

    Déjardin, P

    2013-08-30

    The flow conditions in normal mode asymmetric flow field-flow fractionation are determined to approach the high retention limit with the requirement d≪l≪w, where d is the particle diameter, l the characteristic length of the sample exponential distribution and w the channel height. The optimal entrance velocity is determined from the solute characteristics, the channel geometry (exponential to rectangular) and the membrane properties, according to a model providing the velocity fields all over the cell length. In addition, a method is proposed for in situ determination of the channel height. PMID:23885667

  5. Meeting in Florida: Using Asymmetric Flow Field-Flow Fractionation (AF4) to Determine C60 Colloidal Size Distributions

    EPA Science Inventory

    The study of nanomaterials in environmental systems requires robust and specific analytical methods. Analytical methods which discriminate based on particle size and molecular composition are not widely available. Asymmetric Flow Field-Flow Fractionation (AF4) is a separation...

  6. Asymmetric inhibition of spicule formation in sea urchin embryos with low concentrations of gadolinium ion.

    PubMed

    Saitoh, Motoshi; Kuroda, Ritsu; Muranaka, Yoshinori; Uto, Norihiko; Murai, Junko; Kuroda, Hideyo

    2010-12-01

    As gastrulation proceeds during sea urchin embryogenesis, primary mesenchyme cells (PMCs) fuse to form syncytial cables, within which calcium is deposited as CaCO₃, and a pair of spicules is formed. Earlier studies suggested that calcium, previously sequestered by primary mesenchyme cells, is secreted and incorporated into growing spicules. We examined the effects of gadolinium ion (Gd(3+)), a Ca(2+) channel blocker, on spicule formation. Gd(3+) did not lead to a retardation of embryogenesis prior to the initiation of gastrulation and did not inhibit the ingression of PMCs from the blastula wall or their migration along the inner blastocoel surface. However, when embryos were raised in seawater containing submicromolar to a few micromolar Gd(3+), of which levels are considered to be insufficient to block Ca(2+) channels, a pair of triradiate spicules was formed asymmetrically. At 1-3 μmol/L Gd(3+), many embryos formed only one spicule on either the left or right side, or embryos formed a very small second spicule. Induction of the spicule abnormality required the presence of Gd(3+) specifically during late blastula stage prior to spicule formation. An accumulation or adsorption of Gd(3+) was not detected anywhere in the embryos by X-ray microanalysis, which suggests that Ca(2+) channels were not inhibited. These results suggest that Gd(3+) exerts an inhibitory effect on spicule formation through a mechanism that does not involve inhibition of Ca(2+) channels. PMID:21158753

  7. Experimental implementation of a strong two-color asymmetric laser field in the mid-infrared

    NASA Astrophysics Data System (ADS)

    Kaziannis, S.; Danakas, S.; Kotsina, N.; Kosmidis, C.

    2016-05-01

    We report the experimental implementation of a strong two-color (ω/2ω) asymmetric laser field in the mid-infrared regime (MIR) consisting of a fs pulse centered at 1400 nm and its second harmonic (700 nm). Control of the temporal delay between the two pulses with sub-cycle accuracy and, therefore, the two-color field phase is based on the use of a birefringent calcite plate. The experimental methodology is described in detail for the 1400/700 nm case, while its applicability is discussed for a broader wavelength range, nowadays accessible by optical parametric amplifiers. The validity of the proposed methodology is further supported by the application of the asymmetric 1400/700 nm field on the dissociative ionization of carbon monoxide, which is considered to be a benchmark target in the field of coherent control of strong laser‑matter interaction. It is demonstrated that efficient control on the directional emission of the CO ionic fragments is achieved by varying the relative phase of the 1400 and 700 nm field components.

  8. Temporally asymmetric laser pulse for magnetic-field generation in plasmas

    NASA Astrophysics Data System (ADS)

    Singh, Mamta; Gopal, Krishna; Gupta, Devki Nandan

    2016-04-01

    Of particular interest in this article, the case study of an asymmetric laser pulse interaction with a plasma for magnetic field enhancement has been investigated. The strong ponderomotive force due to the short leading edge of the propagating laser pulse drives a large nonlinear current, producing a stronger quasistatic magnetic field. An analytical expression for the magnetic field is derived and the strength of the magnetic field is estimated for the current laser-plasma parameters. The theoretical results are validated through the particle-in-cell (PIC) simulations and are in very close agreement with the simulation based estimations. This kind of magnetic field can be useful in the plasma based accelerators as well as in the laser-fusion based experiments.

  9. On the Electron Diffusion Region in Asymmetric Reconnection with a Guide Magnetic Field

    NASA Technical Reports Server (NTRS)

    Hesse, Michael; Liu, Yi-Hsin; Chen, Li-Jen; Bessho, Naoki; Kuznetsova, Masha; Birn, Joachim; Burch, James L.

    2016-01-01

    Particle-in-cell simulations in a 2.5-D geometry and analytical theory are employed to study the electron diffusion region in asymmetric reconnection with a guide magnetic field. The analysis presented here demonstrates that similar to the case without guide field, in-plane flow stagnation and null of the in-plane magnetic field are well separated. In addition, it is shown that the electric field at the local magnetic X point is again dominated by inertial effects, whereas it remains dominated by nongyrotropic pressure effects at the in-plane flow stagnation point. A comparison between local electron Larmor radii and the magnetic gradient scale lengths predicts that distribution should become nongyrotropic in a region enveloping both field reversal and flow stagnation points. This prediction is verified by an analysis of modeled electron distributions, which show clear evidence of mixing in the critical region.

  10. Dosimetric considerations of symmetric and asymmetric 60Co teletherapy split fields.

    PubMed

    Wrede, D E; Givens, S B

    1977-01-01

    Split fields are commonly used for a variety of treatments for which local shielding is desired; a single field is split into two fields by means of lead blocks placed in the beam. The condition for assuming independence of the two fields is investigated by using the area over perimeter calculational method and comparing this to experimental depth-dose data measured in a water phantom using a Shonka ionization chamber. Two principal variations affecting dose distributions are examined: block width and position of the block expressed as the fractional perpendicular distance between the central ray of the overall field and the center of the block. An intercomparison between calculation and experimental data shows that the right and left sides of the split field behave as independent fields giving TAR values in agreement with experimental data to within +/-1%. If the fields are asymmetric and if the larger field is less than 70% of the total area including the blocked part, then the dosimetry should be based on average TARs, off-center ratios, and backscatter factors for the two fields. If the larger area is greater than 70% of the total area, then the treatment time can be calculated from the larger field only. PMID:904593

  11. Adiabatic Field-Free Alignment of Asymmetric Top Molecules with an Optical Centrifuge

    NASA Astrophysics Data System (ADS)

    Korobenko, A.; Milner, V.

    2016-05-01

    We use an optical centrifuge to align asymmetric top SO2 molecules by adiabatically spinning their most polarizable O-O axis. The effective centrifugal potential in the rotating frame confines the sulfur atoms to the plane of the laser-induced rotation, leading to the planar molecular alignment that persists after the molecules are released from the centrifuge. The periodic appearance of the full three-dimensional alignment, typically observed only with linear and symmetric top molecules, is also detected. Together with strong in-plane centrifugal forces, which bend the molecules by up to 10 deg, permanent field-free alignment offers new ways of controlling molecules with laser light.

  12. Selective charge asymmetric distribution in heteronuclear diatomic molecules in strong laser fields

    NASA Astrophysics Data System (ADS)

    Lai, Wei; Guo, Chunlei

    2015-07-01

    In this paper we study double-ionization-induced charge asymmetric dissociation (CAD) in heteronuclear diatomic molecules. In CO we find a selective charge distribution in two CAD channels, i.e., C2 ++O is abundantly produced but C +O2 + is nearly nonexistent. This cannot be explained by the ionization energy difference between the two channels alone. Our study shows that the C2 ++O channel is sequentially formed through an intermediate state C++O and the selective charge distribution is the result of electron distribution in CO when exposed to intense laser fields.

  13. Graphene field effect transistors with niobium contacts and asymmetric transfer characteristics.

    PubMed

    Bartolomeo, Antonio Di; Giubileo, Filippo; Romeo, Francesco; Sabatino, Paolo; Carapella, Giovanni; Iemmo, Laura; Schroeder, Thomas; Lupina, Grzegorz

    2015-11-27

    We fabricate back-gated field effect transistors using niobium electrodes on mechanically exfoliated monolayer graphene and perform electrical characterization in the pressure range from atmospheric down to 10(-4) mbar. We study the effect of room temperature vacuum degassing and report asymmetric transfer characteristics with a resistance plateau in the n-branch. We show that weakly chemisorbed Nb acts as p-dopant on graphene and explain the transistor characteristics by Nb/graphene interaction with unpinned Fermi level at the interface. PMID:26535591

  14. Three dimensional imaging technique suitable for the measurements of the internal energies of asymmetrical diatomic molecular ions

    NASA Astrophysics Data System (ADS)

    Sauza, J. B.; Panchenko, D. I.; Duot, A. C.; Strom, R. A.; Andrianarijaona, V. M.

    2015-05-01

    We propose a three dimensional imaging technique that could be used to measure the internal energy of asymmetrical diatomic molecular ions such as HeH+ and CO+. The detection scheme is similar to the one used for symmetrical diatomic molecular ions, which accesses the internal energy of the ion through the kinetic energy release in a resonant dissociative charge transfer (see for instance). In that technique, the fragments hit two detectors which send the positions of the impacts along with the difference between the times of impacts to a computer. The computed kinetic energy release is related to the vibrational excitation level of the initial molecular ion. In the case of an asymmetrical ion, the lighter fragment has a higher recoil velocity and goes further away transversally from the center of mass direction. The heavier fragment would not hit the first detector if the beam is judiciously misaligned. Therefore, we make distinction between the two particles. Details of the technique will be presented. Authors wish to give special thanks to Pacific Union College Student Senate for their financial support.

  15. Surface potential at a ferroelectric grain due to asymmetric screening of depolarization fields

    SciTech Connect

    Genenko, Yuri A. Hirsch, Ofer; Erhart, Paul

    2014-03-14

    Nonlinear screening of electric depolarization fields, generated by a stripe domain structure in a ferroelectric grain of a polycrystalline material, is studied within a semiconductor model of ferroelectrics. It is shown that the maximum strength of local depolarization fields is rather determined by the electronic band gap than by the spontaneous polarization magnitude. Furthermore, field screening due to electronic band bending and due to presence of intrinsic defects leads to asymmetric space charge regions near the grain boundary, which produce an effective dipole layer at the surface of the grain. This results in the formation of a potential difference between the grain surface and its interior of the order of 1 V, which can be of either sign depending on defect transition levels and concentrations. Exemplary acceptor doping of BaTiO{sub 3} is shown to allow tuning of the said surface potential in the region between 0.1 and 1.3 V.

  16. Asymmetrical response of dayside ion precipitation to a large rotation of the IMF

    NASA Astrophysics Data System (ADS)

    Berchem, J.; Richard, R. L.; Escoubet, C. P.; Wing, S.; Pitout, F.

    2016-01-01

    We have carried out global magnetohydrodynamics (MHD) simulations together with large-scale kinetic simulations to investigate the response of the dayside magnetospheric ion precipitation to a large rotation (135°) of the interplanetary magnetic field (IMF). The study uses simplified global MHD model (no dipole tilt and constant ionospheric conductance) and idealized solar wind conditions where the IMF rotates smoothly from a southward toward a northward direction (BX = 0) to clearly identify the effects of the impact of the discontinuity on the magnetopause. Results of the global simulations reveal that a strong north-south asymmetry develops in the pattern of precipitating ions during the interaction of the IMF rotation with the magnetopause. For a counterclockwise IMF rotation from its original southward direction (BY < 0), a spot of high-energy particle injections occurs in the Northern Hemisphere but not in the Southern Hemisphere. The spot moves poleward and dawnward as the interacting field rotates. In that case, reconnection is found close to the poleward edge of the northern cusp, while it occurs farther tailward in the Southern Hemisphere. Tracing magnetic field lines shows an asymmetry in the tilt of the cusps and indicates that the draping and subsequent double reconnection of newly opened field lines from the Southern Hemisphere over the dayside magnetosphere cause the symmetry breaking. The reverse north-south asymmetry is found for a clockwise IMF rotation from its original southward direction (BY > 0). Trends observed in the ion dispersions predicted from the simulations are in good agreement with Cluster observations of the midaltitude northern cusp, which motivated the study.

  17. Control of photoelectron interference in asymmetric momentum distributions using two-color laser fields

    NASA Astrophysics Data System (ADS)

    Zheng, Xu; Liu, Ming-Ming; Xie, Hui; Ge, Peipei; Li, Min; Liu, Yunquan

    2015-11-01

    We theoretically study the control of photoelectron interference of atoms ionized by a two-color laser field with parallel polarizations. Based on both the quantum-trajectory Monte Carlo model and an ab initio simulation with numerically solving the time-dependent Schrödinger equation, we show that the photoelectron angular distributions can be controlled by changing the relative phase of the two frequency components. The high-energy and low-energy photoelectrons show different modulations with respect to the relative phase. Tracing back to the initial coordinates (the ionization time with respect to the laser phase and the initial momentum) of photoelectrons, we have studied the physical origin of the asymmetric structure in photoelectron angular distributions and the dynamics of controlling photoelectron emission using the two-color laser fields. We show that the long tail of the Coulomb potential plays a minor role in the position of the high-energy cutoff in the backward scattering, whereas it is of great importance in the formation of the asymmetric structures of the low-energy photoelectrons.

  18. Particle Diffusion in Chaotic Magnetic Fields Generated by Asymmetric Current Configurations

    NASA Astrophysics Data System (ADS)

    Ram, A. K.; Dasgupta, B.

    2008-12-01

    The observed cross-field diffusion of charged particles in cosmic rays is assumed to be due to the chaotic nature of the interplanetary/intergalactic magnetic fields. Among the classic works on this subject have been those of Parker [1] and Jokipii [2]. Parker considered the passage of cosmic ray particles and energetic solar particles in a large scale magnetic field containing small scale irregularities. In the context of cosmic ray propagation, Jokipii considered a small fluctuating component, added on to a uniform magnetic field, to study the spatial transport of particles. In these studies the irregular component of the magnetic field is prescribed in an ad hoc fashion. In contrast, we consider asymmetric, nonlinear, steady-state magnetic fields, in three spatial dimensions, generated by currents flowing in circular loops and straight lines [3]. These magnetic fields are completely deterministic and, for certain range of parameters, chaotic. We will present analytical and numerical studies on the spatial characteristics of these fields. The motion of charged particles in the nonlinear and chaotic magnetic fields is determined using the Lorentz equation. A particle moving in a deterministic chaotic magnetic field superposed on a uniform background magnetic field is found to undergo spatial transport. This shows that chaotic magnetic fields generated by simple current configurations can produce cross-field diffusion. A detailed analysis of particle motion and diffusion along with application to space plasmas will be presented. [1] E.N. Parker, Planet. Space Sci. 13, 9 (1965). [2] J.R. Jokipii, Astrophys. J. 146, 480 (1966), and J.R. Jokipii, Astrophys. J. 149, 405 (1967). [3] A.K. Ram and B. Dasgupta, Eos Trans. AGU 87 (52), Fall Meet. Suppl. Abstract NG31B-1593 (2006); and Eos Trans. AGU 88 (52), Fall Meet. Suppl. Abstract NG21B-0522 (2007).

  19. Ions in a binary asymmetric dipolar mixture: Mole fraction dependent Born energy of solvation and partial solvent polarization structure

    NASA Astrophysics Data System (ADS)

    Kashyap, Hemant K.; Biswas, Ranjit

    2007-11-01

    Mean spherical approximation (MSA) for electrolyte solution has been extended to investigate the role of partial solvent polarization densities around an ion in a completely asymmetric binary dipolar mixture. The differences in solvent diameters, dipole moments, and ionic size are incorporated systematically within the MSA framework in the present theory for the first time. In addition to the contributions due to difference in dipole moments, the solvent-solvent and ion-solvent size ratios are found to significantly affect the nonideality in binary dipolar mixtures. Subsequently, the theory is used to investigate the role of ion-solvent and solvent-solvent size ratios in determining the nonideality in Born free energy of solvation of a unipositive rigid ion in alcohol-water and dimethyl sulfoxide-acetonitrile mixtures, where the solvent components are represented only by their molecular diameters and dipole moments. Nonideality in Born free energy of solvation in such simplified mixtures is found to be stronger for smaller ions. The slope of the nonideality for smaller alkali metal ions in methanol-water mixture is found to be opposite to that for larger ion, such as quaternary tertiary butyl ammonium ion. For ethanol-water mixtures, the slopes are in the same direction for all the ions studied here. These results are in qualitative agreement with experiments, which is surprising as the present MSA approach does not include the hydrogen bonding and hydrophobic interactions present in the real mixtures. The calculated partial polarization densities around a unipositive ion also show the characteristic deviation from ideality and reveal the microscopic origin of the ion and solvent size dependent preferential solvation. Also, the excess free energy of mixing (in the absence of any ion) for these binary mixtures has been calculated and a good agreement between theory and experiment has been found.

  20. Dielectrophoretic field-flow method for separating particle populations in a chip with asymmetric electrodes

    PubMed Central

    Iliescu, Ciprian; Tresset, Guillaume; Xu, Guolin

    2009-01-01

    This paper presents a field-flow method for separating particle populations in a dielectrophoretic (DEP) chip with asymmetric electrodes under continuous flow. The structure of the DEP device (with one thick electrode that defines the walls of the microfluidic channel and one thin electrode), as well as the fabrication and characterization of the device, was previously described. A characteristic of this structure is that it generates an increased gradient of electric field in the vertical plane that can levitate the particles experiencing negative DEP. The separation method consists of trapping one population to the bottom of the microfluidic channel using positive DEP, while the other population that exhibits negative DEP is levitated and flowed out. Viable and nonviable yeast cells were used for testing of the separation method. PMID:20216966

  1. Selective ionization/dissociation of oriented N2O molecules by asymmetric fs laser field.

    PubMed

    Kotsina, N; Kaziannis, S; Danakas, S; Kosmidis, C

    2013-09-14

    We report on the selective ionization of oriented nitrous oxide (N2O) molecules in gas phase by the use of an intense asymmetric two-color ω/2ω 40 fs laser field. By means of a time-of-flight mass spectrometer the induced N2O mass spectra have been recorded as a function of the relative phase of the two-color laser fields. It is found that the applied method facilitates the distinction of different dissociation channels that result in fragments with the same mass and kinetic energy. Thus, the potential of the employed technique for phase control of the molecular excitation for the case of N2O is explored. PMID:24050350

  2. Selective ionization/dissociation of oriented N2O molecules by asymmetric fs laser field

    NASA Astrophysics Data System (ADS)

    Kotsina, N.; Kaziannis, S.; Danakas, S.; Kosmidis, C.

    2013-09-01

    We report on the selective ionization of oriented nitrous oxide (N2O) molecules in gas phase by the use of an intense asymmetric two-color ω/2ω 40 fs laser field. By means of a time-of-flight mass spectrometer the induced N2O mass spectra have been recorded as a function of the relative phase of the two-color laser fields. It is found that the applied method facilitates the distinction of different dissociation channels that result in fragments with the same mass and kinetic energy. Thus, the potential of the employed technique for phase control of the molecular excitation for the case of N2O is explored.

  3. The non-dominance of counterions in charge-asymmetric electrolytes: non-monotonic precedence of electrostatic screening and local inversion of the electric field by multivalent coions.

    PubMed

    Guerrero-García, Guillermo Iván; González-Tovar, Enrique; Quesada-Pérez, Manuel; Martín-Molina, Alberto

    2016-08-01

    The asymptotic convergence of the thermodynamic and structural properties of unequally-sized charge-symmetric ions in strong electric fields was postulated more than thirty years ago by Valleau and Torrie as the dominance of counterions via the non-linear Poisson-Boltzmann theory [Valleau and Torrie, J. Chem. Phys., 1982, 76, 4623]. According to this mean field prescription, the properties of the electrical double layer near a highly charged electrode immersed in a size-asymmetric binary electrolyte converge to those of a size-symmetric electrolyte if the properties of counterions are the same in both instances. On the other hand, some of the present authors have shown that, in fact, counterions do not dominate the electrical properties of a spherical macroion in the presence of unequally-sized ions, symmetric in valence, if ion correlations and ionic excluded volume effects are taken into account consistently. These ingredients are neglected in the classical Poisson-Boltzmann picture. In the present work, we show the occurrence of the non-dominance of counterions in the opposite scenario, that is, when ions are equally-sized but asymmetric in valence. This is performed in the presence of highly charged colloidal surfaces of spherical and planar geometries for different ionic volume fractions. In addition to the phenomenon of non-dominance of counterions, our simulations and theoretical data also exhibit a non-monotonic order or precedence in the mean electrostatic potential, or electrostatic screening, at the Helmholtz plane of a charged colloid. This interesting behaviour is analyzed as a function of the coion's valence, the ionic volume fraction, and the charge and size of the colloidal particle. All these phenomena are explained in terms of the decay of the electric field near the colloidal surface, and by the appearance of a local inversion of both the electric field and the integrated surface charge density of the colloidal particle in the presence of

  4. Design and fabrication of a holographic head-up display with asymmetric field of view.

    PubMed

    Peng, Haichao; Cheng, Dewen; Han, Jian; Xu, Chen; Song, Weitao; Ha, Liuzhu; Yang, Jian; Hu, Quanxing; Wang, Yongtian

    2014-10-10

    It is difficult to design and fabricate a head-up display (HUD) with a large asymmetric field of view (FOV) while maintaining a good image quality. In this paper, we design and develop such a holographic HUD system. To improve luminance and enhance the environmental adaptability of the HUD, we use a liquid crystal display with high brightness as well as a holographic reflection element. The vertical FOV is tilted to an angle of -7°, which is consistent with the actual view of the pilot. The decentration and tilt of the optical relay system effectively compensate for the distortion and off-axis aberration due to the asymmetric FOV and tilted, curved combiner. The transition plates used in the mechanical structure significantly decrease the difficulty in fabrication and alignment, and virtual prototyping greatly reduces the risk and shortens the development cycle. Experimental results demonstrate that this prototype achieves a total FOV of 30° (horizontal) ×24° (vertical), a resolution of 1280×1024, and a 5% distortion. PMID:25322417

  5. Rational strategy for characterization of nanoscale particles by asymmetric-flow field flow fractionation: a tutorial.

    PubMed

    Gigault, Julien; Pettibone, John M; Schmitt, Charlène; Hackley, Vincent A

    2014-01-27

    This tutorial proposes a comprehensive and rational measurement strategy that provides specific guidance for the application of asymmetric-flow field flow fractionation (A4F) to the size-dependent separation and characterization of nanoscale particles (NPs) dispersed in aqueous media. A range of fractionation conditions are considered, and challenging applications, including industrially relevant materials (e.g., metal NPs, asymmetric NPs), are utilized in order to validate and illustrate this approach. We demonstrate that optimization is material dependent and that polystyrene NPs, widely used as a reference standard for retention calibration in A4F, in fact represent a class of materials with unique selectivity, recovery and optimal conditions for fractionation; thus use of these standards to calibrate retention for other materials must be validated a posteriori. We discuss the use and relevance of different detection modalities that can potentially yield multi-dimensional and complementary information on NP systems. We illustrate the fractionation of atomically precise nanoclusters, which are the lower limit of the nanoscale regime. Conversely, we address the upper size limit for normal mode elution in A4F. The protocol for A4F fractionation, including the methods described in the present work is proposed as a standardized strategy to realize interlaboratory comparability and to facilitate the selection and validation of material-specific measurement parameters and conditions. It is intended for both novice and advanced users of this measurement technology. PMID:24418128

  6. Measurement of the Charge Reduction and Asymmetrical Interaction Force Created by the Ion Wakefield in a Dusty Plasma

    NASA Astrophysics Data System (ADS)

    Chen, Mudi; Yousefi, Razieh; Kong, Jie; Qiao, Ke; Carmona-Reyes, Jorge; Matthews, Lorin; Hyde, Truell

    2014-10-01

    The manner in which the ion wakefield forms has strong implications on the structure, stability and dynamics of a complex plasma. The majority of vertically aligned, ordered dust particle structures observed in a complex plasma result from a combination of the ion wakefield and the external confinement. The ion wakefield is also responsible for other interesting phenomena, such as the reduction in charge seen for a down-stream particle in a vertically aligned dust particle chain and the asymmetrical interaction force between the up-stream and down-stream particles. Unfortunately, few experimental measurements of these phenomena are available. In this experiment, one dimensional (1-D) dust particle structures (i.e., particle chains) are formed in a GEC RF reference cell within a glass box sitting on the powered, lower electrode. The charge reduction on the downstream particle and the asymmetric interaction force are examined using an externally produced DC bias applied to the lower electrode and a diode pumped solid state laser (Coherent VERDI) for perturbation.

  7. The influence of intense electric fields on three-dimensional asymmetric magnetic reconnection

    SciTech Connect

    Pritchett, P. L.

    2013-06-15

    A three-dimensional particle-in-cell simulation of magnetic reconnection in an asymmetric configuration without a guide field and with temperature ratio T{sub i}/T{sub e}>1 demonstrates that intense perpendicular electric fields are produced on the low-density side of the current layer where there is a strong gradient in the plasma density. The simulation shows that the 3-D reconnection rate is unaffected by these intense electric fields, that the electron current layer near the X line remains coherent and does not break up, but that localized regions of strong energy dissipation exist along the low-density separatrices. Near the X line the dominant term in the generalized Ohm's law for the reconnection electric field remains the off-diagonal electron pressure gradient ∂P{sub exy}/∂x. On the low-beta separatrix, however, the anomalous drag −<δnδE{sub y}>/ makes an equally important contribution to that of the pressure gradient to the average E{sub y} field.

  8. The Electric Fields of Radio Pulsars with Asymmetric Nondipolar Magnetic Fields

    NASA Astrophysics Data System (ADS)

    Kantor, E. M.; Tsygan, A. I.

    2003-07-01

    The effect of the curvature of open magnetic field lines on the generation of electric fields in radio pulsars is considered in the framework of a Goldreich-Julian model, for both a regime with a free outflow of electrons from the neutron-star surface and the case of a small thermoemission current. An expression for the electron thermoemission current in a strong magnetic field is derived. The electric field associated with the curvature of the magnetic flux tubes is comparable to the field generated by the relativistic dragging of the inertial frames.

  9. Adiabatic Field-Free Alignment of Asymmetric Top Molecules with an Optical Centrifuge.

    PubMed

    Korobenko, A; Milner, V

    2016-05-01

    We use an optical centrifuge to align asymmetric top SO_{2} molecules by adiabatically spinning their most polarizable O-O axis. The effective centrifugal potential in the rotating frame confines the sulfur atoms to the plane of the laser-induced rotation, leading to the planar molecular alignment that persists after the molecules are released from the centrifuge. The periodic appearance of the full three-dimensional alignment, typically observed only with linear and symmetric top molecules, is also detected. Together with strong in-plane centrifugal forces, which bend the molecules by up to 10 deg, permanent field-free alignment offers new ways of controlling molecules with laser light. PMID:27203318

  10. Nanoparticle separation with a miniaturized asymmetrical flow field-flow fractionation cartridge

    PubMed Central

    Müller, David; Cattaneo, Stefano; Meier, Florian; Welz, Roland; de Mello, Andrew J.

    2015-01-01

    Asymmetrical Flow Field-Flow Fractionation (AF4) is a separation technique applicable to particles over a wide size range. Despite the many advantages of AF4, its adoption in routine particle analysis is somewhat limited by the large footprint of currently available separation cartridges, extended analysis times and significant solvent consumption. To address these issues, we describe the fabrication and characterization of miniaturized AF4 cartridges. Key features of the down-scaled platform include simplified cartridge and reagent handling, reduced analysis costs and higher throughput capacities. The separation performance of the miniaturized cartridge is assessed using certified gold and silver nanoparticle standards. Analysis of gold nanoparticle populations indicates shorter analysis times and increased sensitivity compared to conventional AF4 separation schemes. Moreover, nanoparticulate titanium dioxide populations exhibiting broad size distributions are analyzed in a rapid and efficient manner. Finally, the repeatability and reproducibility of the miniaturized platform are investigated with respect to analysis time and separation efficiency. PMID:26258119

  11. Nanoparticle separation with a miniaturized asymmetrical flow field-flow fractionation cartridge.

    PubMed

    Müller, David; Cattaneo, Stefano; Meier, Florian; Welz, Roland; de Mello, Andrew J

    2015-01-01

    Asymmetrical Flow Field-Flow Fractionation (AF4) is a separation technique applicable to particles over a wide size range. Despite the many advantages of AF4, its adoption in routine particle analysis is somewhat limited by the large footprint of currently available separation cartridges, extended analysis times and significant solvent consumption. To address these issues, we describe the fabrication and characterization of miniaturized AF4 cartridges. Key features of the down-scaled platform include simplified cartridge and reagent handling, reduced analysis costs and higher throughput capacities. The separation performance of the miniaturized cartridge is assessed using certified gold and silver nanoparticle standards. Analysis of gold nanoparticle populations indicates shorter analysis times and increased sensitivity compared to conventional AF4 separation schemes. Moreover, nanoparticulate titanium dioxide populations exhibiting broad size distributions are analyzed in a rapid and efficient manner. Finally, the repeatability and reproducibility of the miniaturized platform are investigated with respect to analysis time and separation efficiency. PMID:26258119

  12. Nanoparticle separation with a miniaturized asymmetrical flow field-flow fractionation cartridge

    NASA Astrophysics Data System (ADS)

    Müller, David; Cattaneo, Stefano; Meier, Florian; Welz, Roland; deMello, Andrew

    2015-07-01

    Asymmetrical Flow Field-Flow Fractionation (AF4) is a separation technique applicable to particles over a wide size range. Despite the many advantages of AF4, its adoption in routine particle analysis is somewhat limited by the large footprint of currently available separation cartridges, extended analysis times and significant solvent consumption. To address these issues, we describe the fabrication and characterization of miniaturized AF4 cartridges. Key features of the scale-down platform include simplified cartridge and reagent handling, reduced analysis costs and higher throughput capacities. The separation performance of the miniaturized cartridge is assessed using certified gold and silver nanoparticle standards. Analysis of gold nanoparticle populations indicates shorter analysis times and increased sensitivity compared to conventional AF4 separation schemes. Moreover, nanoparticulate titanium dioxide populations exhibiting broad size distributions are analyzed in a rapid and efficient manner. Finally, the repeatability and reproducibility of the miniaturized platform are investigated with respect to analysis time and separation efficiency.

  13. Factors affecting measurement of channel thickness in asymmetrical flow field-flow fractionation.

    PubMed

    Dou, Haiyang; Jung, Euo Chang; Lee, Seungho

    2015-05-01

    Asymmetrical flow field-flow fractionation (AF4) has been considered to be a useful tool for simultaneous separation and characterization of polydisperse macromolecules or colloidal nanoparticles. AF4 analysis requires the knowledge of the channel thickness (w), which is usually measured by injecting a standard with known diffusion coefficient (D) or hydrodynamic diameter (dh). An accurate w determination is a challenge due to its uncertainties arising from the membrane's compressibility, which may vary with experimental condition. In the present study, influence of factors including the size and type of the standard on the measurement of w was systematically investigated. The results revealed that steric effect and the particles-membrane interaction by van der Waals or electrostatic force may result in an error in w measurement. PMID:25817708

  14. Bashful Ballerina: The asymmetric global solar magnetic field viewed from the heliosphere

    NASA Astrophysics Data System (ADS)

    Mursula, K.

    2008-05-01

    Long-term observations of the heliospheric magnetic field (HMF) at 1 AU have depicted interesting systematic hemispheric and longitudinal asymmetries that have far-reaching implications for the understanding of solar magnetism. It has been found that the HMF sector of the northern solar hemisphere dominates the observed HMF sector occurrence in the heliosphere for about three years during the late declining to minimum phase of the solar cycle. This leads to a persistent southward shift or coning of the heliospheric current sheet at these times, which has been described by the concept of the bashful ballerina. Measurements of the solar surface fields have verified that, at these times, the average field intensity is smaller and the area larger in the northern than in the southern solar hemisphere. They have also shown that a persistent global quadrupole moment, oppositely oriented with respect to the dipole moment, appears at these times. Long-term observations of the geomagnetic field can yield information on the HMF sector structure in the pre- satellite era, and show that the ballerina was bashful at least since 1930s. In addition to the hemispheric asymmetries, the Sun is systematically asymmetric in longitude. The HMF has persistent active longitudes whose dominance depicts an oscillation with a period of about 3.2 years. Similar flip-flopping is also seen in the longitudinal distribution of sunspots and stellar observations show that this is a general pattern for sun-like cool stars. We describe these phenomena and discuss their theoretical implications.

  15. Bashful Ballerina: The asymmetric global solar magnetic field viewed from the heliosphere

    NASA Astrophysics Data System (ADS)

    Mursula, Kalevi

    Long-term observations of the heliospheric magnetic field (HMF) at 1 AU have depicted interesting systematic hemispheric and longitudinal asymmetries that have far-reaching implications for the understanding of solar magnetism. It has been found that the HMF sector of the northern solar hemisphere dominates the observed HMF sector occurrence in the heliosphere for about three years during the late declining to minimum phase of the solar cycle. This leads to a persistent southward shift or coning of the heliospheric current sheet at these times, which has been described by the concept of the bashful ballerina. Measurements of the solar surface fields have verified that, at these times, the average field intensity is smaller and the area larger in the northern than in the southern solar hemisphere. They have also shown that a persistent global quadrupole moment, oppositely oriented with respect to the dipole moment, appears at these times. Long-term observations of the geomagnetic field can yield information on the HMF sector structure in the pre-satellite era, and show that the ballerina was bashful at least since 1930s. In addition to the hemispheric asymmetries, the Sun is systematically asymmetric in longitude. The HMF has persistent active longitudes whose dominance depicts an oscillation with a period of about 3.2 years. Similar flip-flopping is also seen in the longitudinal distribution of sunspots and stellar observations show that this is a general pattern for sun-like cool stars. We describe these phenomena and discuss their theoretical implications.

  16. Standard and nonstandard nematic electrohydrodynamic convection in the presence of asymmetric ac electric fields

    NASA Astrophysics Data System (ADS)

    Low, Jonathan; Hogan, S. John

    2008-10-01

    In planar nematic electrohydrodynamic convection (EHC), a microscopic liquid crystal cell is driven by a homogeneous ac electric field, which, if strong enough, causes the fluid to destabilize into a regular pattern-forming state. We consider asymmetric electric fields E(t)=E(t+T)≠-E(t+T/2) , which leads to the possibility of three different types of instabilities at onset: conductive, dielectric, and subharmonic. The first two are already well known as they are easily produced when the system is driven by symmetric electric fields; the third can only occur when the electric field symmetry is broken. We present theoretical results on EHC using linear stability analysis and Floquet theory. We consider rigid and free boundary conditions, extending the model to two Fourier modes in the vertical plane, the inclusion of flexoelectricity, and using standard (nematic electric conductivity σa>0 and dielectric anisotorpy γa<0 ) and nonstandard (σa<0) material parameters. We make full use of a three-dimensional linear model where two mutually perpendicular planar wave numbers q and p can be varied. Our results show that there is a qualitative difference between the boundary conditions used, which is also dependent on how many vertical Fourier modes were used in the model. We have obtained threshold values favoring oblique rolls in subharmonic and dielectric regimes in parameter space. For the nonstandard EHC parameter values, both conduction and subharmonic regimes disappear and only the dielectric threshold exists.

  17. Dynamical simulation of energy dissipation in asymmetric heavy-ion induced fission of {sup 200}Pb, {sup 213}Fr, and {sup 251}Es

    SciTech Connect

    Mirfathi, S. M.; Pahlavani, M. R.

    2008-12-15

    The dynamical model based on the asymmetric mass division has been applied to calculate pre-scission neutron multiplicity from heavy-ion induced fusion-fission reactions. Links between the pre-scission neutron multiplicity, excitation energy, and asymmetric mass distribution are clarified based on the Monte Carlo simulation and Langevin dynamics. The pre-scission neutron multiplicity is calculated and compared with the respective experimental data over a wide range of excitation energy and nonconstant viscosity. The analysis indicates a different effect for the application of asymmetric mass division in different energy regions of such processes.

  18. 0114 + 074 - A very asymmetric galaxy in the field of an intermediate-redshift QSO

    SciTech Connect

    Akujor, C.E. Max-Planck-Institut fuer Radioastronomie, Bonn )

    1989-10-01

    New radio-continuum observations of 0114 + 074 (4C 07.4) are presented. It is shown that this radio source consists of two distinct objects: a point source identified with an 18.0 mag QSO and a highly asymmetric 18.5 mag galaxy. The patently asymmetric structure of the galaxy is most plausibly due to intrinsically asymmetric energy funding of the lobes by the central machine or nucleus, rather than external influences. 41 refs.

  19. An IST Model of the Formation of Magnetic Depressions from Rotationally Asymmetric Fields

    NASA Astrophysics Data System (ADS)

    Hamilton, R.; Jovanovich, P.

    2014-12-01

    Magnetic holes have been observed in the solar wind from 0.3 AU to 17 AU, in the magnetosheath of comet Halley, in the heliosheath and also at high heliocentric latitudes. It has been reported that only about 30% of magnetic holes have a small change in the direction of the magnetic field across them. This case had previously been modeled [DOI: 10.1029/2008JA013582] using the 1D-DNLS equation including the effects of dissipation which showed that any profile with a nonlinear component will inevitably lead to the formation of a train of so-called one-parameter dark solitons with a corresponding decrease in field strength. We report on an extension of this earlier work to the rotationally asymmetric case. The magnetic field structure for 'solitons' in this case has not been developed in the literature, but we have found that the direct scattering problem shows the same dynamics as the symmetric case. Connections between these results and magnetic decreases observed in our numerical simulations will be presented.

  20. Evidence for a sedimentary fingerprint of an asymmetric flow field surrounding a short seamount

    NASA Astrophysics Data System (ADS)

    Turnewitsch, Robert; Reyss, Jean-Louis; Chapman, David C.; Thomson, John; Lampitt, Richard S.

    2004-06-01

    Physical oceanographic modeling and field studies have shown that kilometer-scale seafloor elevations of comparable breadth and width (abyssal hills, knolls, seamounts) are surrounded by complex flow fields. Asymmetric flow fields, reversed flow and closed streamlines around the topographic feature (Taylor caps), and resonantly amplified tidal currents around the seamount rim potentially control near-bottom particle dynamics, particle deposition at the seafloor and, consequently, the formation of the sedimentary record. We combine numerical modeling and field data to study how such topographically controlled flow-field features are reflected in the sedimentary record. Sediment deposition on a topographically isolated abyssal knoll (height: 900 m) on the Porcupine Abyssal Plain in the Northeast Atlantic (water depth above the abyssal plain: 4850 m) was studied, (1) by comparing the spatial distribution of 210Pb fluxes, calculated from inventories of sedimentary excess 210Pb, with 210Pb input from the water column as recorded by sediment traps; and (2) by comparing sedimentary grain-size distributions and Zr/Al ratios (an indicator for contents of the heavy mineral zircon) at slope, summit and far-field sites. Given Rossby numbers ≥0.23, a fractional seamount height of ˜0.2, and the absence of diurnal tides it is concluded that an asymmetric flow field without Taylor cap and without amplified tidal currents around the seamount rim is the principal flow-field feature at this knoll. The results and conclusions are as follows: (1) Geochemical and grain-size patterns in the sedimentary record largely agree with the predicted pattern of flow intensity around the topographic elevation: with increasing current strength (erosiveness) there is evidence for a growing discrepancy between water column-derived and sediment-derived 210Pb fluxes, and for increasing contents of larger and heavier particles. The topographically controlled flow field distorts a homogeneous particle

  1. Misfit strain-temperature phase diagrams and domain stability of asymmetric ferroelectric capacitors: Thermodynamic calculation and phase-field simulation

    SciTech Connect

    Chen, W. J.; Zheng, Yue Wu, C. M.; Wang, B. Ma, D. C.

    2014-03-07

    Thermodynamic calculation and phase-field simulation have been conducted to investigate the misfit strain-temperature phase diagrams, dielectric property, and domain stability of asymmetric ferroelectric capacitors (FCs), with considering the effects of dissimilar screening properties and work function steps at the two interfaces. The distinct features of asymmetric FCs from their symmetric counterparts have been revealed and discussed. Polar states with nonzero out-of-plane polarization in parallel with the built-in field are found preferential to form in asymmetric FCs. Meanwhile, the built-in field breaks the degeneracy of states with out-of-plane polarization in anti-directions. This leads to the necessity of redefining phases according to the bistability of out-of-plane polarization. Moreover, the phase stability as well as the dielectric behavior can be significantly controlled by the properties of electrodes, misfit strain, and temperature. The phase-field simulation result also shows that polydomain instability would happen in asymmetric FCs as the equivalence of domain stability in anti-directions is destroyed.

  2. Determining Aqueous Fullerene Particle Size Distributions by Asymmetric Flow Field-Flow Fractionation (AF4) without Surfactants

    EPA Science Inventory

    To determine the behavior of nanoparticles in environmental systems, methods must be developed to measure nanoparticle size. Asymmetric Flow Field Flow Fractionation (AF4) is an aqueous compatible size separation technique which is able to separate particles from 1 nm to 10 µm in...

  3. Dynamics of a reconnection-driven runaway ion tail in a reversed field pinch plasma

    NASA Astrophysics Data System (ADS)

    Anderson, Jay

    2015-11-01

    Non-collisional heating and energization of ions is a powerful process in reversed-field pinch (RFP) plasmas and in many astrophysical settings. Tearing activity in the RFP (including linearly and nonlinearly driven modes which span the plasma column) saturates through dynamo-like feedback on the current density profile, rapidly releasing magnetic energy and inducing a strong impulsive, parallel-to-B electric field as poloidal magnetic flux is converted to toroidal flux. The global reconnection leads to strong ion heating with a known anisotropy in temperature (T⊥ >T| |), suggestive of a perpendicular bulk heating mechanism. In the subset of strongest reconnection events, multiple mechanisms combine to create a most interesting ion distribution. Runaway of the reduced-friction naturally-heated ions generates an asymmetric ion tail with E|| >>E⊥ . The tail is reinforced by a confinement asymmetry where runaway ions approach the limit of classical cross-field transport despite magnetic stochasticity from the broad spectrum of tearing modes. Confinement is lower in other regions of the v⊥ /v| | plane and reduces to Rechester-Rosenbluth-like transport experienced by thermal particles. Experiments with neutral beam injection elegantly confirm the ion runaway process and fast ion confinement characteristics in MST. Neutral particle analyzers measure an unrestricted parallel acceleration of the fast test particle distribution during the reconnection event. The energy gain is larger for higher initial ion energy (reduced drag), and deceleration is observed with reversed electric field (counter-current injection) according to runaway dynamics and confirmed with Fokker-Planck modeling. Full orbit test particle tracing in the 3D time evolving electric and magnetic fields (from visco-resistive MHD simulations) corroborates the understanding of fast ion confinement. Work supported by by US DoE and NSF.

  4. Integrated field emission array for ion desorption

    DOEpatents

    Resnick, Paul J; Hertz, Kristin L; Holland, Christopher; Chichester, David; Schwoebel, Paul

    2013-09-17

    An integrated field emission array for ion desorption includes an electrically conductive substrate; a dielectric layer lying over the electrically conductive substrate comprising a plurality of laterally separated cavities extending through the dielectric layer; a like plurality of conically-shaped emitter tips on posts, each emitter tip/post disposed concentrically within a laterally separated cavity and electrically contacting the substrate; and a gate electrode structure lying over the dielectric layer, including a like plurality of circular gate apertures, each gate aperture disposed concentrically above an emitter tip/post to provide a like plurality of annular gate electrodes and wherein the lower edge of each annular gate electrode proximate the like emitter tip/post is rounded. Also disclosed herein are methods for fabricating an integrated field emission array.

  5. Integrated field emission array for ion desorption

    DOEpatents

    Resnick, Paul J; Hertz, Kristin L.; Holland, Christopher; Chichester, David

    2016-08-23

    An integrated field emission array for ion desorption includes an electrically conductive substrate; a dielectric layer lying over the electrically conductive substrate comprising a plurality of laterally separated cavities extending through the dielectric layer; a like plurality of conically-shaped emitter tips on posts, each emitter tip/post disposed concentrically within a laterally separated cavity and electrically contacting the substrate; and a gate electrode structure lying over the dielectric layer, including a like plurality of circular gate apertures, each gate aperture disposed concentrically above an emitter tip/post to provide a like plurality of annular gate electrodes and wherein the lower edge of each annular gate electrode proximate the like emitter tip/post is rounded. Also disclosed herein are methods for fabricating an integrated field emission array.

  6. Ion beam probing of electrostatic fields

    NASA Technical Reports Server (NTRS)

    Persson, H.

    1979-01-01

    The determination of a cylindrically symmetric, time-independent electrostatic potential V in a magnetic field B with the same symmetry by measurements of the deflection of a primary beam of ions is analyzed and substantiated by examples. Special attention is given to the requirements on canonical angular momentum and total energy set by an arbitrary, nonmonotone V, to scaling laws obtained by normalization, and to the analogy with ionospheric sounding. The inversion procedure with the Abel analysis of an equivalent problem with a one-dimensional fictitious potential is used in a numerical experiment with application to the NASA Lewis Modified Penning Discharge. The determination of V from a study of secondary beams of ions with increased charge produced by hot plasma electrons is also analyzed, both from a general point of view and with application to the NASA Lewis SUMMA experiment. Simple formulas and geometrical constructions are given for the minimum energy necessary to reach the axis, the whole plasma, and any point in the magnetic field. The common, simplifying assumption that V is a small perturbation is critically and constructively analyzed; an iteration scheme for successively correcting the orbits and points of ionization for the electrostatic potential is suggested.

  7. Effect of asymmetrical flow field-flow fractionation channel geometry on separation efficiency.

    PubMed

    Ahn, Ji Yeon; Kim, Ki Hun; Lee, Ju Yong; Williams, P Stephen; Moon, Myeong Hee

    2010-06-11

    The separation efficiencies of three different asymmetrical flow field-flow fractionation (AF4) channel designs were evaluated using polystyrene latex standards. Channel breadth was held constant for one channel (rectangular profile), and was reduced either linearly (trapezoidal profile) or exponentially (exponential profile) along the length for the other two. The effective void volumes of the three channel types were designed to be equivalent. Theoretically, under certain flow conditions, the mean channel flow velocity of the exponential channel could be arranged to remain constant along the channel length, thereby improving separation in AF4. Particle separation obtained with the exponential channel was compared with particle separation obtained with the trapezoidal and rectangular channels. We demonstrated that at a certain flow rate condition (outflow/inflow rate=0.2), the exponential channel design indeed provided better performance with respect to the separation of polystyrene nanoparticles in terms of reducing band broadening. While the trapezoidal channel exhibited a little poorer performance than the exponential, the strongly decreasing mean flow velocity in the rectangular channel resulted in serious band broadening, a delay in retention time, and even failure of larger particles to elute. PMID:20439106

  8. Simple functionalization strategies for enhancing nanoparticle separation and recovery with asymmetric flow field flow fractionation.

    PubMed

    Mudalige, Thilak K; Qu, Haiou; Sánchez-Pomales, Germarie; Sisco, Patrick N; Linder, Sean W

    2015-02-01

    Due to the increasing use of engineered nanomaterials in consumer products, regulatory agencies and other research organizations have determined that the development of robust, reliable, and accurate methodologies to characterize nanoparticles in complex matrices is a top priority. Of particular interest are methods that can separate and determine the size of nanomaterials in samples that contain polydisperse and/or multimodal nanoparticle populations. Asymmetric-flow field flow fractionation (AF4) has shown promise for the separation of nanoparticles with wide size range distributions; however, low analyte recoveries and decreased membrane lifetimes, due to membrane fouling, have limited its application. Herein, we report straightforward strategies to minimize membrane fouling and improve nanoparticle recovery by functionalizing the surface of the nanoparticles, as well as that of the AF4 membranes. Gold nanoparticles (AuNP) were stabilized through functionalization with a phosphine molecule, whereas the surface of the membranes was coated with a negatively charged polystyrenesulfonate polymer. Improved nanoparticle separation, recoveries of 99.1 (±0.5) %, and a detection limit of 6 μg/kg were demonstrated by analyzing AuNP reference materials of different sizes (e.g., 10, 30, and 60 nm), obtained from the National Institute of Standards and Technology (NIST). Furthermore, the stability of the polymer coating and its specificity toward minimizing membrane fouling were demonstrated. PMID:25556296

  9. Asymmetric flow field-flow fractionation of superferrimagnetic iron oxide multicore nanoparticles.

    PubMed

    Dutz, Silvio; Kuntsche, Judith; Eberbeck, Dietmar; Müller, Robert; Zeisberger, Matthias

    2012-09-01

    Magnetic nanoparticles are very useful for various medical applications where each application requires particles with specific magnetic properties. In this paper we describe the modification of the magnetic properties of magnetic multicore nanoparticles (MCNPs) by size dependent fractionation. This classification was carried out by means of asymmetric flow field-flow fractionation (AF4). A clear increase of the particle size with increasing elution time was confirmed by multi-angle laser light scattering coupled to the AF4 system, dynamic light scattering and Brownian diameters determined by magnetorelaxometry. In this way 16 fractions of particles with different hydrodynamic diameters, ranging between around 100 and 500 nm, were obtained. A high reproducibility of the method was confirmed by the comparison of the mean diameters of fractions of several fractionation runs under identical conditions. The hysteresis curves were measured by vibrating sample magnetometry. Starting from a coercivity of 1.41 kA m(-1) for the original MCNPs the coercivity of the particles in the different fractions varied from 0.41 to 3.83 kA m(-1). In our paper it is shown for the first time that fractions obtained from a broad size distributed MCNP fluid classified by AF4 show a strong correlation between hydrodynamic diameter and magnetic properties. Thus we state that AF4 is a suitable technology for reproducible size dependent classification of magnetic multicore nanoparticles suspended as ferrofluids. PMID:22875740

  10. Size characterization and quantification of exosomes by asymmetrical-flow field-flow fractionation.

    PubMed

    Sitar, Simona; Kejžar, Anja; Pahovnik, David; Kogej, Ksenija; Tušek-Žnidarič, Magda; Lenassi, Metka; Žagar, Ema

    2015-09-15

    In the past few years extracellular vesicles called exosomes have gained huge interest of scientific community since they show a great potential for human diagnostic and therapeutic applications. However, an ongoing challenge is accurate size characterization and quantification of exosomes because of the lack of reliable characterization techniques. In this work, the emphasis was focused on a method development to size-separate, characterize, and quantify small amounts of exosomes by asymmetrical-flow field-flow fractionation (AF4) technique coupled to a multidetection system (UV and MALS). Batch DLS (dynamic light-scattering) and NTA (nanoparticle tracking analysis) analyses of unfractionated exosomes were also conducted to evaluate their shape and internal structure, as well as their number density. The results show significant influence of cross-flow conditions and channel thickness on fractionation quality of exosomes, whereas the focusing time has less impact. The AF4/UV-MALS and DLS results display the presence of two particles subpopulations, that is, the larger exosomes and the smaller vesicle-like particles, which coeluted in AF4 together with impurities in early eluting peak. Compared to DLS and AF4-MALS results, NTA somewhat overestimates the size and the number density for larger exosome population, but it discriminates the smaller particle population. PMID:26291637

  11. Asymmetrical flow field-flow fractionation for the analysis of PEG-asparaginase.

    PubMed

    John, C; Herz, T; Boos, J; Langer, K; Hempel, G

    2016-01-01

    Monomethoxypolyethylene glycol L-asparaginase (PEG-ASNASE) is the PEGylated version of the enzyme L-asparaginase (ASNASE). Both are used for remission induction in acute lymphoblastic leukemia (ALL) and non-Hodgkin's lymphoma (NHL). The treatment control is generally carried out by performing activity assays, though methods to determine the actual enzyme rather than its activity are rare. Using asymmetrical flow field-flow fractionation (AF4) offered the chance to develop a method capable of simultaneously measuring PEG-ASNASE and PEG. A method validation was performed in accordance with FDA guidelines for PEG-ASNASE from non-biological solutions. The method unfolded a linearity of 15-750 U/mL with coefficients of correlation of r(2)>0.99. The coefficients of variation (CV) for within-run and between-run variability were 1.18-10.15% and 2.43-8.73%, respectively. Furthermore, the method was used to perform stability tests of the product Oncaspar® (PEG-ASNASE) and estimation of the molecular weight by multi-angle light scattering (MALS) of stressed samples to correlate them with the corresponding activity. The findings indicate that Oncaspar® stock solution should not be stored any longer than 24 h at room temperature and cannot be frozen in pure aqueous media. The validated method might be useful for the pharmaceutical industry and its quality control of PEG-ASNASE production. PMID:26695272

  12. Study on beam emittance evolution in a nonlinear plasma wake field accelerator with mobile plasma ions

    NASA Astrophysics Data System (ADS)

    An, Weiming; Joshi, Chan; Mori, Warren; Lu, Wei

    2014-10-01

    We study the electron beam evolution in a nonlinear blowout PWFA when the accelerated beam has a very small matched spot size that can cause the plasma ions collapsing towards the beam. Contrary to the common belief, very small emittance growth of the accelerated electron beam is found when the plasma ion collapsing destroys the perfect linear focusing force in the plasma wake field. The improved quasi-static PIC code QuickPIC also allows us to use very high resolution and to model asymmetric spot sizes. Simulation results show that the accelerated beam will reach a steady state after several cm propagation in the plasma (which is why we can do simulations and not let the drive beam evolve). We find that for round beams the ion density (which is Li+) enhancement is indeed by factors of 100, but that the emittance only grows by around 20 percent. For asymmetric spot sizes, the ion collapse is less and emittance growth is zero in the plane with the largest emittance and about 20 percent in the other plane.

  13. Helium in chirped laser fields as a time-asymmetric atomic switch

    SciTech Connect

    Kaprálová-Žďánská, Petra Ruth; Moiseyev, Nimrod

    2014-07-07

    Tuning the laser parameters exceptional points in the spectrum of the dressed laser helium atom are obtained. The weak linearly polarized laser couples the ground state and the doubly excited P-states of helium. We show here that for specific chirped laser pulses that encircle an exceptional point one can get the time-asymmetric phenomenon, where for a negative chirped laser pulse the ground state is transformed into the doubly excited auto-ionization state, while for a positive chirped laser pulse the resonance state is not populated and the neutral helium atoms remains in the ground state as the laser pulse is turned off. Moreover, we show that the results are very sensitive to the closed contour we choose. This time-asymmetric state exchange phenomenon can be considered as a time-asymmetric atomic switch. The optimal time-asymmetric switch is obtained when the closed loop that encircles the exceptional point is large, while for the smallest loops, the time-asymmetric phenomenon does not take place. A systematic way for studying the effect of the chosen closed contour that encircles the exceptional point on the time-asymmetric phenomenon is proposed.

  14. Polycrystalline silicon ion sensitive field effect transistors

    NASA Astrophysics Data System (ADS)

    Yan, F.; Estrela, P.; Mo, Y.; Migliorato, P.; Maeda, H.; Inoue, S.; Shimoda, T.

    2005-01-01

    We report the operation of polycrystalline silicon ion sensitive field effect transistors. These devices can be fabricated on inexpensive disposable substrates such as glass or plastics and are, therefore, promising candidates for low cost single-use intelligent multisensors. In this work we have developed an extended gate structure with a Si3N4 sensing layer. Nearly ideal pH sensitivity (54mV /pH) and stable operation have been achieved. Temperature effects have been characterized. A penicillin sensor has been fabricated by functionalizing the sensing area with penicillinase. The sensitivity to penicillin G is about 10mV/mM, in solutions with concentration lower than the saturation value, which is about 7 mM.

  15. Electrical conductivity and asymmetric material changes upon irradiation of Mg-doped lithium niobate crystals with low-mass, high-energy ions

    SciTech Connect

    Jentjens, L.; Raeth, N. L.; Peithmann, K.; Maier, K.

    2011-06-15

    Radiation damage in magnesium-doped lithium niobate crystals, created by low-mass, high-energy ions which have transmitted the entire crystal thickness, leads to an enhanced electrical dark conductivity as well as an enhanced photoconductivity. Experimental results on the electrical properties after ion exposure are given, and an asymmetric dependence of the conductivity as well as refractive index changes on the irradiation geometry with respect to the ferroelectric axis is revealed.

  16. Experimental study of the asymmetric charge transfer reaction between Ar+ ions and Fe atoms.

    PubMed

    Korolov, I; Bánó, G; Donkó, Z; Derzsi, A; Hartmann, P

    2011-02-14

    We investigate the Ar(+)-Fe asymmetric charge transfer (ACT) reaction using a combination of plasma diagnostics methods and a kinetic model of the afterglow plasma, which allow monitoring of the temporal evolution of the densities of different species. The iron vapor is created inside a discharge cell by cathode sputtering; its density is measured by atomic absorption spectroscopy. The rate coefficient of the reaction is evaluated from the emission intensity decay of Fe(+)∗ lines pumped by the ACT process in the He-Ar-Fe and Ar-Fe afterglow plasmas. The measurements yield a rate coefficient k = 7.6( ± 3.0) × 10(-9) cm(3) s(-1) at T = 300 K. PMID:21322681

  17. Ion heating perpendicular to the magnetic field. Technical report

    SciTech Connect

    Andre, M.; Chang, T.

    1994-03-28

    Several theories of ion heating perpendicular to the geomagnetic field are briefly reviewed and assessed. Perpendicular heating of ions leading to the formation of ion conics is common in the ionosphere and magnetosphere. Ion conics at altitudes above a few thousand kilometers are often associated with waves around the ion gyrofrequency. It is concluded that the majority of these ion conics that are locally heated or generated over extended altitude regimes, may be best explained by ion cyclotron resonance heating. At lower altitudes, particularly in the region of discrete auroras, energization by turbulence around the lower hybrid frequency seems to be an important heating mechanism.

  18. Asymmetric flow field-flow fractionation of manufactured silver nanoparticles spiked into soil solution.

    PubMed

    Koopmans, G F; Hiemstra, T; Regelink, I C; Molleman, B; Comans, R N J

    2015-05-01

    Manufactured metallic silver nanoparticles (AgNP) are intensively utilized in consumer products and this will inevitably lead to their release to soils. To assess the environmental risks of AgNP in soils, quantification of both their concentration and size in soil solution is essential. We developed a methodology consisting of asymmetric flow field-flow fractionation (AF4) in combination with on-line detection by UV-vis spectroscopy and off-line HR-ICP-MS measurements to quantify the concentration and size of AgNP, coated with either citrate or polyvinylpyrrolidone (PVP), in water extracts of three different soils. The type of mobile phase was a critical factor in the fractionation of AgNP by AF4. In synthetic systems, fractionation of a series of virgin citrate- and PVP-coated AgNP (10-90 nm) with reasonably high recoveries could only be achieved with ultrahigh purity water as a mobile phase. For the soil water extracts, 0.01% (w:v) sodium dodecyl sulfate (SDS) at pH 8 was the key to a successful fractionation of the AgNP. With SDS, the primary size of AgNP in all soil water extracts could be determined by AF4, except for PVP-coated AgNP when clay colloids were present. The PVP-coated AgNP interacted with colloidal clay minerals, leading to an overestimation of their primary size. Similar interactions between PVP-coated AgNP and clay colloids can take place in the environment and facilitate their transport in soils, aquifers, and surface waters. In conclusion, AF4 in combination with UV-vis spectroscopy and HR-ICP-MS measurements is a powerful tool to characterize AgNP in soil solution if the appropriate mobile phase is used. PMID:25798868

  19. Optimization and evaluation of asymmetric flow field-flow fractionation of silver nanoparticles.

    PubMed

    Loeschner, Katrin; Navratilova, Jana; Legros, Samuel; Wagner, Stephan; Grombe, Ringo; Snell, James; von der Kammer, Frank; Larsen, Erik H

    2013-01-11

    Asymmetric flow field-flow fractionation (AF(4)) in combination with on-line optical detection and mass spectrometry is one of the most promising methods for separation and quantification of nanoparticles (NPs) in complex matrices including food. However, to obtain meaningful results regarding especially the NP size distribution a number of parameters influencing the separation need to be optimized. This paper describes the development of a separation method for polyvinylpyrrolidone-stabilized silver nanoparticles (AgNPs) in aqueous suspension. Carrier liquid composition, membrane material, cross flow rate and spacer height were shown to have a significant influence on the recoveries and retention times of the nanoparticles. Focus time and focus flow rate were optimized with regard to minimum elution of AgNPs in the void volume. The developed method was successfully tested for injected masses of AgNPs from 0.2 to 5.0 μg. The on-line combination of AF(4) with detection methods including ICP-MS, light absorbance and light scattering was helpful because each detector provided different types of information about the eluting NP fraction. Differences in the time-resolved appearance of the signals obtained by the three detection methods were explained based on the physical origin of the signal. Two different approaches for conversion of retention times of AgNPs to their corresponding sizes and size distributions were tested and compared, namely size calibration with polystyrene nanoparticles (PSNPs) and calculations of size based on AF(4) theory. Fraction collection followed by transmission electron microscopy was performed to confirm the obtained size distributions and to obtain further information regarding the AgNP shape. Characteristics of the absorbance spectra were used to confirm the presence of non-spherical AgNP. PMID:23261297

  20. Quantum dot agglomerates in biological media and their characterization by asymmetrical flow field-flow fractionation.

    PubMed

    Moquin, Alexandre; Neibert, Kevin D; Maysinger, Dusica; Winnik, Françoise M

    2015-01-01

    The molecular composition of the biological environment of nanoparticles influences their physical properties and changes their pristine physicochemical identity. In order to understand, or predict, the interactions of cells with specific nanoparticles, it is critical to know their size, shape, and agglomeration state not only in their nascent state but also in biological media. Here, we use asymmetrical flow field-flow fractionation (AF4) with on-line multiangle light scattering (MALS), dynamic light scattering (DLS) and UV-Visible absorption detections to determine the relative concentration of isolated nanoparticles and agglomerates in the case of three types of semi-conductor quantum dots (QDs) dispersed in Dulbecco's Modified Eagle Media (DMEM) containing 10% of fetal bovine serum (DMEM-FBS). AF4 analysis also yielded the size and size distribution of the agglomerates as a function of the time of QDs incubation in DMEM-FBS. The preferred modes of internalization of the QDs are assessed for three cell-types, N9 microglia, human hepatocellular carcinoma cells (HepG2) and human embryonic kidney cells (Hek293), by confocal fluorescence imaging of live cells, quantitative determination of the intracellular QD concentration, and flow cytometry. There is an excellent correlation between the agglomeration status of the three types of QDs in DMEM-FBS determined by AF4 analysis and their preferred mode of uptake by the three cell lines, which suggests that AF4 yields an accurate description of the nanoparticles as they encounter cells and advocates its use as a means to characterize particles under evaluation. PMID:25542679

  1. Quantifying uranium complexation by groundwater dissolved organic carbon using asymmetrical flow field-flow fractionation

    NASA Astrophysics Data System (ADS)

    Ranville, James F.; Hendry, M. Jim; Reszat, Thorsten N.; Xie, Qianli; Honeyman, Bruce D.

    2007-05-01

    The long-term mobility of actinides in groundwaters is important for siting nuclear waste facilities and managing waste-rock piles at uranium mines. Dissolved organic carbon (DOC) may influence the mobility of uranium, but few field-based studies have been undertaken to examine this in typical groundwaters. In addition, few techniques are available to isolate DOC and directly quantify the metals complexed to it. Determination of U-organic matter association constants from analysis of field-collected samples compliments laboratory measurements, and these constants are needed for accurate transport calculations. The partitioning of U to DOC in a clay-rich aquitard was investigated in 10 groundwater samples collected between 2 and 30 m depths at one test site. A positive correlation was observed between the DOC (4-132 mg/L) and U concentrations (20-603 μg/L). The association of U and DOC was examined directly using on-line coupling of Asymmetrical Flow Field-Flow Fractionation (AsFlFFF) with UV absorbance (UVA) and inductively coupled plasma-mass spectrometer (ICP-MS) detectors. This method has the advantages of utilizing very small sample volumes (20-50 μL) as well as giving molecular weight information on U-organic matter complexes. AsFlFFF-UVA results showed that 47-98% of the DOC (4-136 mg C/L) was recovered in the AsFlFFF analysis, of which 25-64% occurred in the resolvable peak. This peak corresponded to a weight-average molecular weight of about 900-1400 Daltons (Da). In all cases, AsFlFFF-ICP-MS suggested that ≤ 2% of the U, likely present as U(VI), was complexed with the DOC. This result was in good agreement with the U speciation modeling performed on the sample taken from the 2.3 m depth, which predicted approximately 3% DOC-complexed U. This good agreement suggests that the AsFlFFF-ICP-MS method may be very useful for determining U-organic matter association in small volume samples. Because the pH (7.0-8.1) and carbonate concentrations of these waters

  2. Field applications of ion-mobility spectrometry

    NASA Astrophysics Data System (ADS)

    Brown, Patricia A.

    1997-02-01

    Ion mobility spectrometry (IMS) is an excellent tool for detection of controlled substances under field conditions. Plasmagrams and tables showing the results of field applications will be discussed. Residues of drugs, such as cocaine and heroin, can be left anywhere including vehicles, boats, and houses. In houses, the carpets, walls, and floors are good locations for residues to adhere. Individual clothing can also be contaminated with drug residue. Vehicles that are suspected of having previously smuggled illegal substances can be vacuumed and screened. Tablets that look similar and respond the same when screened with the Marquis reagent can be differentiated by IMS. With Southern California being the 'methamphetamine capital of the world' and the resurgence of phencyclidine, IMS has proven extremely valuable in the screening of abandoned clandestine laboratory sites and vehicles in which the clandestine laboratories; chemicals and glassware were transported. IMS is very responsive to ephedrine/pseudophedrine, a precursor of methamphetamine and 1-piperidinocyclohexanecarbonitrile, an intermediate of phencyclidine. Once residues are detected, vacuum samples, and/or methanol wipes are collected and analyzed at the DEA Laboratory for confirmation of the suspected substance using GC-IRD or Mass Spectrometry.

  3. METHOD AND APPARATUS FOR TRAPPING IONS IN A MAGNETIC FIELD

    DOEpatents

    Luce, J.S.

    1962-04-17

    A method and apparatus are described for trapping ions within an evacuated container and within a magnetic field utilizing dissociation and/or ionization of molecular ions to form atomic ions and energetic neutral particles. The atomic ions are magnetically trapped as a result of a change of charge-to- mass ratio. The molecular ions are injected into the container and into the path of an energetic carbon arc discharge which dissociates and/or ionizes a portion of the molecular ions into atomic ions and energetic neutrals. The resulting atomic ions are trapped by the magnetic field to form a circulating beam of atomic ions, and the energetic neutrals pass out of the system and may be utilized in a particle accelerator. (AEC)

  4. Retention ratio and nonequilibrium bandspreading in asymmetrical flow field-flow fractionation.

    PubMed

    Williams, P Stephen

    2015-06-01

    In asymmetrical flow field-flow fractionation (As-FlFFF), only the membrane-covered accumulation wall is permeable to fluid; the opposite channel wall is impermeable. Fluid enters the channel at the inlet and exits partly through the membrane-covered accumulation wall and partly through the channel outlet. This means that not only does the volumetric channel flow rate decrease along the channel length as fluid exits through the membrane but also the cross-channel component to fluid velocity must approach zero at the impermeable wall. This dependence of cross-channel fluid velocity on distance across the channel thickness influences the equilibrium concentration profile for the sample components introduced to the channel. The concentration profile departs from the exponential profile predicted for the ideal model of field-flow fractionation. This influences both the retention ratio and the principal contribution to bandspreading--the nonequilibrium contribution. The derivation of an equation for the nonequilibrium bandspreading parameter χ in As-FlFFF is presented, and its numerical solution graphed. At high retention, it is shown that the solutions for both retention ratio R and χ converge on those for the ideal model, as expected. At lower levels of retention, the departures from the ideal model are significant, particularly for bandspreading. For example, at a level of retention corresponding to a retention parameter λ of 0.05, R is almost 4% higher than for the ideal model (0.28047 as compared to 0.27000) but the value of χ is almost 60% higher. The equations presented for both R and χ include a first-order correction for the finite size of the particles--the steric exclusion correction. These corrections are shown to be significant for particle sizes eluting well before steric inversion. For example, particles of half the inversion diameter are predicted to elute 25% slower and to show almost 40% higher bandspreading when steric effects are not accounted

  5. Intense laser effects on the optical properties of asymmetric GaAs double quantum dots under applied electric field

    NASA Astrophysics Data System (ADS)

    Bejan, Doina; Niculescu, Ecaterina Cornelia

    2016-06-01

    We investigated the combined effects of a non-resonant intense laser field and a static electric field on the electronic structure and the nonlinear optical properties (absorption, optical rectification) of a GaAs asymmetric double quantum dot under a strong probe field excitation. The calculations were performed within the compact density-matrix formalism under steady state conditions using the effective mass approximation. Our results show that: (i) the electronic structure and optical properties are sensitive to the dressed potential; (ii) under applied electric fields, an increase of the laser intensity induces a redshift of the optical absorption and rectification spectra; (iii) the augment of the electric field strength leads to a blueshift of the spectra; (iv) for high electric fields the optical spectra show a shoulder-like feature, related with the occurrence of an anti-crossing between the two first excited levels.

  6. Electron jet of asymmetric reconnection

    NASA Astrophysics Data System (ADS)

    Khotyaintsev, Yu. V.; Graham, D. B.; Norgren, C.; Eriksson, E.; Li, W.; Johlander, A.; Vaivads, A.; André, M.; Pritchett, P. L.; Retinò, A.; Phan, T. D.; Ergun, R. E.; Goodrich, K.; Lindqvist, P.-A.; Marklund, G. T.; Le Contel, O.; Plaschke, F.; Magnes, W.; Strangeway, R. J.; Russell, C. T.; Vaith, H.; Argall, M. R.; Kletzing, C. A.; Nakamura, R.; Torbert, R. B.; Paterson, W. R.; Gershman, D. J.; Dorelli, J. C.; Avanov, L. A.; Lavraud, B.; Saito, Y.; Giles, B. L.; Pollock, C. J.; Turner, D. L.; Blake, J. D.; Fennell, J. F.; Jaynes, A.; Mauk, B. H.; Burch, J. L.

    2016-06-01

    We present Magnetospheric Multiscale observations of an electron-scale current sheet and electron outflow jet for asymmetric reconnection with guide field at the subsolar magnetopause. The electron jet observed within the reconnection region has an electron Mach number of 0.35 and is associated with electron agyrotropy. The jet is unstable to an electrostatic instability which generates intense waves with E∥ amplitudes reaching up to 300 mV m-1 and potentials up to 20% of the electron thermal energy. We see evidence of interaction between the waves and the electron beam, leading to quick thermalization of the beam and stabilization of the instability. The wave phase speed is comparable to the ion thermal speed, suggesting that the instability is of Buneman type, and therefore introduces electron-ion drag and leads to braking of the electron flow. Our observations demonstrate that electrostatic turbulence plays an important role in the electron-scale physics of asymmetric reconnection.

  7. Driving toroidally asymmetric current through the tokamak scrape-off layer, Part II: Magnetic field structure and spectrum

    SciTech Connect

    Joseph, I

    2009-04-08

    The structure of the magnetic field perturbations due to non-axisymmetric field-aligned currents in the tokamak scrape-off layer (SOL) are analytically calculated near the X-point. Part I [I. Joseph, et al., submitted to Phys. Plasmas (2008)] demonstrated that biasing divertor target plates in a toroidally asymmetric fashion can generate an appreciable toroidally asymmetric parallel current density in the SOL along the separatrix. Here, the magnetic field perturbation caused by a SOL current channel of finite width and step-wise constant amplitude at the target plate is derived. Flux expansion amplifies the magnetic perturbation near the X-point, while phase interference causes the SOL amplitude to be reduced at large toroidal mode number. Far enough from the current channel, the magnetic field can be approximated as arising from a surface current near the separatrix with differing amplitudes in the SOL and the divertor leg. The perturbation spectrum and resonant components of this field are computed analytically asymptotically close to the separatrix in magnetic flux coordinates. The size of the stochastic layer due to the applied perturbation that would result without self-consistent plasma shielding is also estimated. If enough resonant field is generated, control of the edge pressure gradient may allow stabilization of edge localized modes.

  8. High-Resolution Differential Ion Mobility Separations Using Planar Analyzers at Elevated Dispersion Field

    PubMed Central

    Prior, David C.; Tang, Keqi; Smith, Richard D.

    2010-01-01

    The ion mobility spectrometry (IMS) methods are grouped into conventional IMS, based on the absolute ion mobility, and differential or field asymmetric waveform IMS (FAIMS), based on the mobility difference in strong and weak electric fields. A key attraction of FAIMS is substantial orthogonality to mass spectrometry (MS). Although several FAIMS/MS platforms were commercialized, their utility was limited by FAIMS resolving power, typically ∼10 - 20. Recently, gas mixtures comprising up to 75% He has enabled resolving power >100 that permits separation of numerous heretofore “co-eluting” isomers. This performance opens major new proteomic and other biological applications. Here, we show that raising the separation field by ∼35% over the previous 21 kV/cm provides similar or better resolution (with resolving powers of >200 for multiply-charged peptides) using only 50% He, which avoids problems due to elevated pressure and He content in the mass spectrometer. The heating of ions by the separation field in this regime exceeds that at higher He content but weaker field, inducing greater izomerization of labile species. PMID:20666414

  9. Chip-type asymmetrical flow field-flow fractionation channel coupled with mass spectrometry for top-down protein identification.

    PubMed

    Kim, Ki Hun; Moon, Myeong Hee

    2011-11-15

    A chip-type design asymmetrical flow field-flow fractionation (AF4) channel has been developed for high-speed separation of proteins and top-down proteomic analysis using online coupled electrospray ionization mass spectrometry (ESI-MS). The new miniaturized AF4 channel was assembled by stacking multilayer thin stainless steel (SS, 1.5 mm each) plates embedded with an SS frit in such a way that the total thickness of the channel assembly was about 6 mm. The efficiency of the miniaturized AF4 channel at different channel lengths was examined with the separation of protein standards by adjusting flow rates in which an identical effective channel flow rate or an identical void time can be maintained at different channels. Detection limit, overloading effect, reproducibility, and influence of channel membrane materials on separation efficiency were investigated. Desalting and purification of proteins achieved during the AF4 operation by the action of an exiting crossflow and the use of aqueous mass-spectrometry-compatible (MS-compatible) buffer were advantageous for online coupling of the chip-type AF4 with ESI-MS. The direct coupling of AF4 and ESI-MS capabilities was demonstrated for the high-speed separation and identification of carbonic anhydrase (29 kDa) and transferrin (78 kDa) by full scan MS and for the first top-down identification of proteins with AF4-ESI-MS-MS using collision-induced fragmentation (CID). The presence of intact dimers (156 kDa) of transferrin was confirmed by AF4-ESI-MS via size separation of the dimers from monomers, followed by multiply charged ion spectral analysis of the dimers and molecular mass determinations. It was also found from these experiments that AF4-ESI-MS analysis of transferrin exhibited an increased signal-to-noise ratio compared to that of direct ESI-MS analysis due to online purification of the protein sample and size separation of dimers with AF4. PMID:21981549

  10. Energetic-particle-driven instabilities and induced fast-ion transport in a reversed field pinch

    SciTech Connect

    Lin, L.; Brower, D. L.; Ding, W. X.; Anderson, J. K.; Capecchi, W.; Eilerman, S.; Forest, C. B.; Koliner, J. J.; Nornberg, M. D.; Reusch, J.; Sarff, J. S.; Liu, D.

    2014-05-15

    Multiple bursty energetic-particle (EP) driven modes with fishbone-like structure are observed during 1 MW tangential neutral-beam injection in a reversed field pinch (RFP) device. The distinguishing features of the RFP, including large magnetic shear (tending to add stability) and weak toroidal magnetic field (leading to stronger drive), provide a complementary environment to tokamak and stellarator configurations for exploring basic understanding of EP instabilities. Detailed measurements of the EP mode characteristics and temporal-spatial dynamics reveal their influence on fast ion transport. Density fluctuations exhibit a dynamically evolving, inboard-outboard asymmetric spatial structure that peaks in the core where fast ions reside. The measured mode frequencies are close to the computed shear Alfvén frequency, a feature consistent with continuum modes destabilized by strong drive. The frequency pattern of the dominant mode depends on the fast-ion species. Multiple frequencies occur with deuterium fast ions compared to single frequency for hydrogen fast ions. Furthermore, as the safety factor (q) decreases, the toroidal mode number of the dominant EP mode transits from n=5 to n=6 while retaining the same poloidal mode number m=1. The transition occurs when the m=1, n=5 wave-particle resonance condition cannot be satisfied as the fast-ion safety factor (q{sub fi}) decreases. The fast-ion temporal dynamics, measured by a neutral particle analyzer, resemble a classical predator-prey relaxation oscillation. It contains a slow-growth phase arising from the beam fueling followed by a rapid drop when the EP modes peak, indicating that the fluctuation-induced transport maintains a stiff fast-ion density profile. The inferred transport rate is strongly enhanced with the onset of multiple EP modes.

  11. On the Electrons Dynamics during Rapid Island Coalescence in Asymmetric Magnetic Reconnection: Case With and With No Guide Field

    NASA Astrophysics Data System (ADS)

    Cazzola, E.; Innocenti, M. E.; Markidis, S.; Goldman, M. V.; Newman, D. L.; Lapenta, G.

    2015-12-01

    We present a set of fully kinetic 2.5D simulations of electron dynamics during rapid magnetic islands coalescence in asymmetric conditions. Simulations are performed using the massively parallel fully kinetic implicit moment method code iPIC3D (Markidis et al. 2010). The domain is a double periodic box with two current sheets initially representing two different reconnection conditions with the same asymmetric ratio. In the upper sheet the conventional hyperbolic continuous functions for magnetic field and density are initialised across the layer (e.g. Pritchett 2008). In the lower layer the same asymmetric conditions are used the presence of an extremely steep gradient describing a pure tangential discontinuity.Cases with and without guide field are compared. While the upper layer shows the typical reconnection evolution of an asymmetric configuration, the lower layer very soon develops not-uniformly distributed multiple reconnection points which rapidly evolve in a series of magnetic islands. Quick islands coalescence follows. Even though the electrons dynamics during island merging has been studied in both symmetric and asymmetric conditions (e.g. Pritchett 2007, 2008b, Drake et al. 2006, Oka et al. 2010, Huang et al. 2014), these simulations show new interesting features such as the presence of three distinct regions, here named X, M and D, with very different properties. Regions X and M manifest typical signatures of ongoing reconnection, distinguishable thanks to the direct comparison with the outcomes of the upper layer. In particular, M-type regions are different because reconnection occurs between two merging islands in a vertical fashion with respect to the direction of the current sheets initially set. In contrast, regions D present a quite diverse features, not showing the typical signatures of a occurring reconnection. The present work is supported by the NASA MMS Grant NNX08AO84G. Additional support for the KULeuven team is provided by the European

  12. A field evaporation deuterium ion source for neutron generators

    SciTech Connect

    Reichenbach, Birk; Solano, I.; Schwoebel, P. R.

    2008-05-01

    Proof-of-principle experiments have demonstrated an electrostatic field evaporation based deuterium ion source for use in compact, high-output deuterium-tritium neutron generators. The ion source produces principally atomic deuterium and titanium ions. More than 100 ML of deuterated titanium thin film can be removed and ionized from a single tip in less than 20 ns. The measurements indicate that with the use of microfabricated tip arrays the deuterium ion source could provide sufficient ion current to produce 10{sup 9}-10{sup 10} n/cm{sup 2} of tip array area.

  13. A field evaporation deuterium ion source for neutron generators

    NASA Astrophysics Data System (ADS)

    Reichenbach, Birk; Solano, I.; Schwoebel, P. R.

    2008-05-01

    Proof-of-principle experiments have demonstrated an electrostatic field evaporation based deuterium ion source for use in compact, high-output deuterium-tritium neutron generators. The ion source produces principally atomic deuterium and titanium ions. More than 100 ML of deuterated titanium thin film can be removed and ionized from a single tip in less than 20 ns. The measurements indicate that with the use of microfabricated tip arrays the deuterium ion source could provide sufficient ion current to produce 109-1010 n/cm2 of tip array area.

  14. Membrane curvature generated by asymmetric depletion layers of ions, small molecules, and nanoparticles.

    PubMed

    Różycki, Bartosz; Lipowsky, Reinhard

    2016-08-21

    Biomimetic and biological membranes consist of molecular bilayers with two leaflets that are typically exposed to different aqueous solutions. We consider solutions of "particles" that experience effectively repulsive interactions with these membranes and form depletion layers in front of the membrane leaflets. The particles considered here are water-soluble, have a size between a few angstrom and a few nanometers as well as a rigid, more or less globular shape, and do neither adsorb onto the membranes nor permeate these membranes. Examples are provided by ions, small sugar molecules, globular proteins, or inorganic nanoparticles with a hydrophilic surface. We first study depletion layers in a hard-core system based on ideal particle solutions as well as hard-wall interactions between these particles and the membrane. For this system, we obtain exact expressions for the coverages and tensions of the two leaflets as well as for the spontaneous curvature of the bilayer membrane. All of these quantities depend linearly on the particle concentrations. The exact results for the hard-core system also show that the spontaneous curvature can be directly deduced from the planar membrane geometry. Our results for the hard-core system apply both to ions and solutes that are small compared to the membrane thickness and to nanoparticles with a size that is comparable to the membrane thickness, provided the particle solutions are sufficiently dilute. We then corroborate the different relationships found for the hard-core system by extensive simulations of a soft-core particle system using dissipative particle dynamics. The simulations confirm the linear relationships obtained for the hard-core system. Both our analytical and our simulation results show that the spontaneous curvature induced by a single particle species can be quite large. When one leaflet of the membrane is exposed, e.g., to a 100 mM solution of glucose, a lipid bilayer can acquire a spontaneous curvature of ±1

  15. Analysis of the light-field intensity dependence of catastrophic optical damage in high-power AlGaInP lasers using an asymmetrical tapered laser

    NASA Astrophysics Data System (ADS)

    Bou Sanayeh, Marwan

    2016-04-01

    Catastrophic optical damage (COD) in semiconductor lasers is a major limiting effect for high-power operation. Several techniques like microphotoluminescence (μPL) mapping, focused ion beam (FIB) microscopy, and micro- Raman spectroscopy were employed to reveal the physics behind catastrophic optical damage, its related temperature dynamics, as well as associated defect and near-field patterns. High-resolution μPL images demonstrated that during COD, nonradiative dark line defects (DLDs) originate from the front mirror of the laser and propagate deep inside the cavity. Furthermore, FIB microscopy identified the epitaxial layers affected by COD, revealing that the DLDs are confined to the active region. In addition, deep-etching uncovered the DLDs by making them visible, and showed that they are composed of complex dislocation networks. Lasers that underwent a spontaneous breakdown where also studied. One missing piece to complete the characterization of COD is to analyze if the DLDs actually follow certain crystal direction lines inside the laser cavity, which are in general perpendicular to the output facet, or follow the path of the light-field intensity-maximum. Using a specially designed innovative device, namely an asymmetrical AlGaInP tapered laser, it is proven in this study that the COD is strongly dependent on the light-field intensity inside the laser cavity and not on certain crystal direction lines.

  16. Measurement of ultra-low ion energy of decelerated ion beam using a deflecting electric field

    NASA Astrophysics Data System (ADS)

    Thopan, P.; Suwannakachorn, D.; Tippawan, U.; Yu, L. D.

    2015-12-01

    In investigation on ultra-low-energy ion bombardment effect on DNA, an ion beam deceleration lens was developed for high-quality ultra-low-energy ion beam. Measurement of the ion energy after deceleration was necessary to confirm the ion beam really decelerated as theoretically predicted. In contrast to conventional methods, this work used a simple deflecting electrostatic field after the deceleration lens to bend the ion beam. The beam bending distance depended on the ion energy and was described and simulated. A system for the measurement of the ion beam energy was constructed. It consisted of a pair of parallel electrode plates to generate the deflecting electrical field, a copper rod measurement piece to detect ion beam current, a vernier caliper to mark the beam position, a stepping motor to translate the measurement rod, and a webcam-camera to read the beam bending distance. The entire system was installed after the ion-beam deceleration lens inside the large chamber of the bioengineering vertical ion beam line. Moving the measurement rod across the decelerated ion beam enabled to obtain beam profiles, from which the beam bending distance could be known and the ion beam energy could be calculated. The measurement results were in good agreement with theoretical and simulated results.

  17. Dissociation Dynamics of Molecular Ions in High dc Electric Field.

    PubMed

    Blum, Ivan; Rigutti, Lorenzo; Vurpillot, François; Vella, Angela; Gaillard, Aurore; Deconihout, Bernard

    2016-05-26

    In an atom probe, molecular ions can be field evaporated from the analyzed material and, then, can dissociate under the very intense electric field close to the field emitter. In this work, field evaporation of ZnO reveals the emission of Zn2O2(2+) ions and their dissociation into ZnO(+) ions. It is shown that the repulsion between the produced ZnO(+) ions is large enough to have a measurable effect on both the ion trajectories and times of flight. Comparison with numerical simulations of the ion trajectories gives information on the lifetime of the parent ions, the energy released by the dissociation and repulsion, and also the dissociation direction. This study not only opens the way to a new method to obtain information on the behavior of molecular ions in high electric fields by using an atom probe, but also opens up the interesting perspective to apply this technique to a wide class of materials and molecules. PMID:27136453

  18. Test ion transport in a collisional, field-reversed configuration

    NASA Astrophysics Data System (ADS)

    Roche, T.; McWilliams, R.; Heidbrink, W. W.; Bolte, N.; Garate, E. P.; Morehouse, M.; Slepchenkov, M.; Wessel, F.

    2014-08-01

    Diffusion of test-ions in a flux-coil generated, collisional, field-reversed configuration is measured via time-resolved tomographic reconstruction of Ar+ optical emission in the predominantly nitrogen plasma. Azimuthal test ion diffusion across magnetic field lines is found to be classical during the stable period of the discharge. Test ion radial confinement is enhanced by a radial electric field, reducing the observed outward radial transport rate below predictions based solely on classical cross-field diffusion rates. Test ion diffusion is ˜500 m2 s-1 during the stable period of the discharge. The electric field inferred from plasma potential measurements and from equilibrium calculations is consistent with the observed reduction in argon transport.

  19. Effects of H+, He+ ion reflection at the lunar surface and pickup ion dynamics in case of oblique/quasi-parallel magnetic field: 3-D hybrid kinetic modeling

    NASA Astrophysics Data System (ADS)

    Lipatov, A. S.; Cooper, J. F.; Sittler, E. C.; Hartle, R. E.; Sarantos, M.

    2013-12-01

    The hybrid kinetic model used here supports comprehensive simulation of the interaction between different spatial and energetic elements of the moon-solar wind-magnetosphere of the Earth system. This involves variable upstream magnetic field and solar wind plasma, including energetic ions, electrons, and neutral atoms. This capability is critical to improved interpretation of existing measurements for surface and atmospheric composition from previous missions and planning future missions. Recently, MAP-PAGE-IMA (Plasma energy Angle and Composition Experiment, and Ion Mass Analyzer) onboard Japanese lunar orbiter SELENE (KAGUYA) detected Moon originating ions at 100 km altitude. Ion species of H+, He++, He+, C+, O+, Na+, K+, and Ar+ were definitively identified. The first portion of our modeling devotes to a study of the H+, H2+, He+, Na+ pickup ion dynamics in cases of flow with a oblique and quasi-parallel magnetic field. In the second series of modeling we also take into account collisions between ions and the surface of the moon and further sputtering of fragments from the surface of the moon. The ion reflection at the lunar surface is also responsible for wave activity in the upstream flow. The solar wind parameters are chosen from ARTEMIS observations. The hybrid kinetic model allows us to take into account the finite gyroradius effects of pickup ions and to estimate correctly the ions velocity distribution and the fluxes along the magnetic field. Modeling shows the asymmetric Mach cone, pickup and reflected ion tails, and presents another type of lunar-solar wind interaction. Our simulation may be also important for the study of the interaction between the solar wind and very weak comets, Mercury and Pluto.

  20. Exciton-related nonlinear optical properties in cylindrical quantum dots with asymmetric axial potential: combined effects of hydrostatic pressure, intense laser field, and applied electric field.

    PubMed

    Zapata, Alejandro; Acosta, Ruben E; Mora-Ramos, Miguel E; Duque, Carlos A

    2012-01-01

    : The exciton binding energy of an asymmetrical GaAs-Ga1-xAlxAs cylindrical quantum dot is studied with the use of the effective mass approximation and a variational calculation procedure. The influence on this quantity of the application of a direct-current electric field along the growth direction of the cylinder, together with that of an intense laser field, is particularly considered. The resulting states are used to calculate the exciton-related nonlinear optical absorption and optical rectification, whose corresponding resonant peaks are reported as functions of the external probes, the quantum dot dimensions, and the aluminum molar fraction in the potential barrier regions. PMID:22971418

  1. Ion recognition: application of symmetric and asymmetric schiff bases and their complexes for the fabrication of cationic and anionic membrane sensors to determine ions in real samples.

    PubMed

    Faridbod, Farnoush; Ganjali, Mohammad Reza; Dinarvand, Rassoul; Norouzi, Parviz

    2007-08-01

    Schiff base compounds refer to the branch of supra-molecules and can be used as sensing material in the construction of potentiometric ion selective electrodes (ISEs). This relatively modern field has been subject to extensive research in the period of 1999-2007 when more than 100 ISEs employing Schiff bases were constructed. The quantitative high-throughput detection of 29 cations and 7 anions has been demonstrated in various scientific branches, such as biomedicine, pharmacy, biochemistry, pharmacology, environmental chemistry, food technology, and agriculture. This review discusses Schiff base compounds and their applications in the design and development of ion selective sensors and microsensors. PMID:17979636

  2. Combination of Metal Coordination Tetrahedra and Asymmetric Coordination Geometries of Sb(III) in the Organically Directed Chalcogenidometalates: Structural Diversity and Ion-exchange Properties.

    PubMed

    Feng, Mei-Ling; Wang, Kai-Yao; Huang, Xiao-Ying

    2016-04-01

    Chalcogenidometalates exhibit rich and diverse structures and properties applicable to ion exchange, thermoelectrics, photocatalysis, nonlinear optics, and so on. This personal account summarizes our recent progress in constructing chalcogenidometalates by combining metal coordination tetrahedra and the asymmetric coordination geometries of Sb(3+) in the presence of organic species (typically organic amines and metal-organic amine complexes), which has been demonstrated as an effective strategy for synthesizing chalcogenidometalates with diversified structures and interesting properties. The linkage modes of asymmetric SbQn (n = 3, 4) geometries and group 13 (or 14) metal coordination tetrahedra are analyzed, and the secondary building units (SBUs), with different compositions and architectures, are clarified. The crucial role and function of organic species in the formation of chalcogenidometalates are explored, with an emphasis on their powerful structure-directing features. In particular, some chalcogenidometalates in this family exhibit excellent ion-exchange properties for Cs(+) and/or Sr(2+) ions; the factors affecting ion-exchange properties are discussed to understand the underlying ion-exchange mechanism. PMID:26809360

  3. Comment on "Effects of Magnetic Field Gradient on Ion Beam Current in Cylindrical Hall Ion Source

    SciTech Connect

    Raitses, Y.; Smirnov A.; Fisch, N.J.

    2008-08-29

    It is argued that the key difference of the cylindrical Hall thruster (CHT) as compared to the end-Hall ion source cannot be exclusively attributed to the magnetic field topology [Tang et al. J. Appl. Phys., 102, 123305 (2007)]. With a similar mirror-type topology, the CHT configuration provides the electric field with nearly equipotential magnetic field surfaces and a better suppression of the electron cross-field transport, as compared to both the end-Hall ion source and the cylindrical Hall ion source of Tang et al.

  4. Quantum Simulation of Quantum Field Theories in Trapped Ions

    SciTech Connect

    Casanova, J.; Lamata, L.; Egusquiza, I. L.; Gerritsma, R.; Roos, C. F.; Garcia-Ripoll, J. J.; Solano, E.

    2011-12-23

    We propose the quantum simulation of fermion and antifermion field modes interacting via a bosonic field mode, and present a possible implementation with two trapped ions. This quantum platform allows for the scalable add up of bosonic and fermionic modes, and represents an avenue towards quantum simulations of quantum field theories in perturbative and nonperturbative regimes.

  5. Role of ions in a crossed-field diode.

    PubMed

    Lau, Y Y; Luginsland, J W; Cartwright, K L; Haworth, M D

    2007-01-01

    The effect of ions in a magnetically insulated crossed-field gap is studied using a single particle orbit model, shear flow model, and particle-in-cell simulation. It is found that, in general, the presence of ions in a crossed-field gap always increases the electrons' excursion toward the anode region, regardless of the location of the ions. Thus, the rate at which the electrons migrate toward the anode, which is a measure of the diode closure rate, is related to the rate at which ions are introduced into the crossed-field gap. This anode migration of electrons is unrelated to crossed-field ambipolar diffusion. The implications of these findings are explored, such as pulse shortening in relativistic magnetrons and bipolar flows in pulsed-power systems. PMID:17358481

  6. High electric field deuterium ion sources for neutron generators

    NASA Astrophysics Data System (ADS)

    Reichenbach, Birk

    Active interrogation systems for highly enriched uranium require improved fieldable neutron sources. The target technology for deuterium-tritium neutron generators is well understood and the most significant improvement can be achieved by improving the deuterium ion source through increased output and, in some cases, lifetime of the ion source. We are developing a new approach to a deuterium ion sources based upon the field desorption/evaporation of deuterium from the surfaces of metal tips. Electrostatic field desorption (EFD) desorbs previously adsorbed deuterium as ions under the influence of high electric fields (several V/A), without removing tip material. Single etched wire tip experiments have been performed and have shown that this is difficult but can be achieved with molybdenum and tungsten tips. Electrostatic field evaporation (EFE) evaporates ultra thin deuterated titanium films as ions. It has been shown that several 10s of atomic layers can be removed within a few nanoseconds from etched tungsten tips. In the course of these studies titanium deposition and deuteration methods were studied and new detection methods developed. Space charge effects resulting from the large ion currents were identified to be the most likely cause of some unusual ion emission characteristics. In addition, on W < 110 > oriented substrates a surprising body-centered cubic crystal structure of the titanium film was found and studied. The ion currents required for neutron generator applications can be achieved by microfabrication of metal tip arrays. Field desorption studies of microfabricated field emitter tip arrays have been conducted for the first time. Maximum fields of 3 V/A have been applied to the array tip surfaces to date, although fields of ˜ 2 V/A to ˜ 2.5 V/A are more typical. Desorption of atomic deuterium ions has been observed at fields of roughly 2 V/A at room temperature. The desorption of common surface adsorbates, such as hydrogen, carbon, water, and

  7. Influence of electrical fields and asymmetric application of mucilage on curvature of primary roots of Zea mays

    NASA Technical Reports Server (NTRS)

    Marcum, H.; Moore, R.

    1990-01-01

    Primary roots of Zea mays cv. Yellow Dent growing in an electric field curve towards the anode. Roots treated with EDTA and growing in electric field do not curve. When root cap mucilage is applied asymmetrically to tips of vertically-oriented roots, the roots curve toward the mucilage. Roots treated with EDTA curve toward the side receiving mucilage and toward blocks containing 10 mM CaCl2, but not toward "empty" agar blocks or the cut surfaces of severed root tips. These results suggest that 1) free calcium (Ca) is necessary for root electrotropism, 2) mucilage contains effector(s) that induce gravitropiclike curvature, and 3) mucilage can replace gravitropic effectors chelated by EDTA. These results are consistent with the hypothesis that the downward movement of gravitropic effectors to the lower sides of tips of horizontally-oriented roots occurs at least partially in the apoplast.

  8. Separation and characterization of poly(tetrafluoroethylene) latex particles by asymmetric flow field flow fractionation with light-scattering detection.

    PubMed

    Collins, Melissa E; Soto-Cantu, Erick; Cueto, Rafael; Russo, Paul S

    2014-04-01

    Poly(tetrafluoroethylene) (PTFE) latex particles have been analyzed and sorted according to size using asymmetric flow field flow fractionation (AF4) coupled with multiple-angle light scattering (MALS). Characterization of fractions by regular and depolarized dynamic light scattering confirmed that smaller particles elute prior to larger ones, as expected for field flow fractionation. The measured radii of the optically and geometrically anisotropic particles are consistent with those determined from transmission electron microscopy (TEM). A certain amount of heterogeneity remains in the fractions, but their uniformity for use as diffusion probes is improved. Full characterization of PTFE colloids will require a difficult assessment of the distribution, even within fractions, of the optical anisotropy. A general method to obtain number versus size distributions is presented. This approach is valid even when an online concentration detector is not available or ineffective. The procedure is adaptable to particles of almost any regular shape. PMID:24635125

  9. Electric field by pick-up ions and electrons

    NASA Astrophysics Data System (ADS)

    Yamauchi, Masatoshi; Behar, Etienne; Nilsson, Hans; Holmstrom, Mats

    2016-04-01

    Observations by the Rosetta Plasma Consortium (RPC) showed increasing distortion of the solar wind flow as Rosetta approached the Sun, i.e., as the density of the newly born ions increased. This indicates azimuthal momentum transfer from the solar wind to the newly born ions because they are displaced by the solar wind electric field up to the ion gyroradius this the solar wind velocity, and conservation of the momentum (center of the mass) makes the solar wind to azimuthally shift by "counter action" of these pick-up ion motions. To understand this azimuthal momentum transfer, it is inevitable to model the electric field by the displacement of these pick-up ions and electrons. Although the E×B drift does not make charge separation when the scale size is larger than the ion gyroradius, ions and electrons move in the opposite direction to each other within the short distance up to a gyroradius, and therefore, the charge separation occurs. Thus, the newly-ionized neutrals (ion-electron pairs) create the electric field in the opposite (shielding) direction to the solar wind electric field (like the ionopause of Venus and Mars). However, such a newly induced "shielding" electric field will simultaneously be weakened by the solar wind electrons because the solar wind is also moved by this shielding electric field to reduce it, in the same way as the plasma oscillation (time scale of about 10‑4 s). In other words, the solar wind tries to maintain the solar wind electric field as far as the momentum allows. These two opposite effects must be combined when modelling the azimuthal electric field, and resultant ion/electron motions within a gyroradius, like the case for ROSETTA. Furthermore, the effect of the induced electric field by the pick-up ions and electrons will be different when the newly born ions are created as the result of photo-ionization and of the charge exchange because the electron effect is different between them. In the presentation, we model the

  10. Linear electric field time-of-flight ion mass spectrometer

    DOEpatents

    Funsten, Herbert O.; Feldman, William C.

    2008-06-10

    A linear electric field ion mass spectrometer having an evacuated enclosure with means for generating a linear electric field located in the evacuated enclosure and means for injecting a sample material into the linear electric field. A source of pulsed ionizing radiation injects ionizing radiation into the linear electric field to ionize atoms or molecules of the sample material, and timing means determine the time elapsed between ionization of atoms or molecules and arrival of an ion out of the ionized atoms or molecules at a predetermined position.

  11. Electromagnetic instabilities attributed to a cross-field ion drift

    NASA Technical Reports Server (NTRS)

    Chang, C. L.; Wong, H. K.; Wu, C. S.

    1990-01-01

    Instabilities due to a cross-field ion flow are reexamined by including the electromagnetic response of the ions, which has been ignored in existing discussions. It is found that this effect can lead to significant enhancement of the growth rate. Among the new results, a purely growing, electromagnetic unstable mode with a wave vector k parallel to the ambient magnetic field is found. The plasma configuration under consideration is similar to that used in the discussion of the well-known modified-two-stream instability. This instability has a growth rate faster than the ion cyclotron frequency, and is not susceptible to high-plasma-beta stabilization.

  12. Zero-field optical manipulation of magnetic ions in semiconductors.

    PubMed

    Myers, R C; Mikkelsen, M H; Tang, J-M; Gossard, A C; Flatté, M E; Awschalom, D D

    2008-03-01

    Controlling and monitoring individual spins is desirable for building spin-based devices, as well as implementing quantum information processing schemes. As with trapped ions in cold gases, magnetic ions trapped on a semiconductor lattice have uniform properties and relatively long spin lifetimes. Furthermore, diluted magnetic moments in semiconductors can be strongly coupled to the surrounding host, permitting optical or electrical spin manipulation. Here we describe the zero-field optical manipulation of a few hundred manganese ions in a single gallium arsenide quantum well. Optically created mobile electron spins dynamically generate an energy splitting of the ion spins and enable magnetic moment orientation solely by changing either photon helicity or energy. These polarized manganese spins precess in a transverse field, enabling measurements of the spin lifetimes. As the magnetic ion concentration is reduced and the manganese spin lifetime increases, coherent optical control and readout of single manganese spins in gallium arsenide should be possible. PMID:18278049

  13. The Effects of Ion heating in Martian Magnetic Crustal Fields: Particle Tracing and Ion Distributions

    NASA Astrophysics Data System (ADS)

    Fowler, C. M.; Andersson, L.

    2014-12-01

    Ion heating is a process that may allow low energy ions within the Martian ionosphere to be accelerated and escape. Ion heating can be especially efficient if the ions stay in the heating region for long time durations. With this in mind, the magnetic crustal field regions on Mars are particularly interesting. We focus on ions present within these regions, where changes in magnetic field strength and direction can heat these ions. Since crustal magnetic fields can maintain a trapped particle population it is unclear how efficiently plasma can be built up that can later escape to space. We investigate here two drivers: rotation of the planet and the solar wind pressure. As crustal fields rotate from the wake of the planet to the sub solar point and back, they experience compression and expansion over time scales of ~24 hours. The solar wind pressure on the other hand can cause variations over much shorter time scales (minutes). The effect of these two drivers using a particle tracing simulation that solves the Lorentz force is presented. O+ ions are seeded within the simulation box. The magnetic environment is a linear sum of a dipole field and a solar wind magnetic field. The dipole field represents the magnetic crustal field and the dipole strength is chosen to be consistent with MGS magnetometer observations of Martian crustal field regions. By increasing the solar wind strength the magnetic dipole is compressed. Decreasing solar wind strength allows the dipole to expand. Small magnitude, short time scale variations can be imposed over the top of this larger variation to represent short time scale solar wind variations. Since the purpose of this analysis is to understand the changes of the ion distribution inside the crustal field, simplistic assumptions of the field outside the crustal field can be made. Initial results are presented, with the focus on two main questions: (a) can low energy ions be heated and escape the closed dipole field lines as a result of

  14. Ion Beam Neutralization Using FEAs and Mirror Magnetic Fields

    NASA Astrophysics Data System (ADS)

    Nicolaescu, Dan; Sakai, Shigeki; Gotoh, Yasuhito; Ishikawa, Junzo

    2011-01-01

    Advanced implantation systems used for semiconductor processing require transportation of ion beams which are quasi-parallel and have low energy, such as (11B+,31P+,75As+) with energy in the range Eion = 200-1000 eV. Compensation of ion beam divergence may be obtained through electron injection and confinement in regions of non-uniform magnetic fields. Field emitter arrays with special properties are used as electron sources. The present study shows that electron confinement takes place in regions of gradient magnetic field, such as nearby analyzing, collimator and final energy magnets of the ion beam line. Modeling results have been obtained using Opera3D/Tosca/Scala. In regions of gradient magnetic field, electrons have helical trajectories which are confined like a cloud inside curved "magnetic bottles". An optimal range of positions with respect to the magnet for placing electron sources in gradient magnetic field has been shown to exist.

  15. Atom probe field ion microscopy and related topics: A bibliography 1991

    SciTech Connect

    Russell, K.F.; Miller, M.K.

    1993-01-01

    This report contains a bibliography for 1991 on the following topics: Atom probe field ion microscopy; field desorption mass spectrometry; field emission; field ion microscopy; and field emission theory.

  16. Critical current density and trapped field in HTS with asymmetric magnetization loops

    NASA Astrophysics Data System (ADS)

    Gokhfeld, D.

    2016-03-01

    Applications of the extended critical state model are considered. The trapped magnetic field, the penetration field and the field dependence of the critical current density are analysed. The critical current density and the trapped field in superconducting grains depend on the grain size. Asymmetry of the hysteresis curves relative to the M = 0 axis is related to the scale of the current circulation.

  17. Generation of periodic ultrashort electron bunches and strongly asymmetric ion Coulomb explosion in nanometer foils interacting with ultra-intense laser pulse

    SciTech Connect

    Tian Youwei; Yu Wei; Xu Han; Lei Anle; Shen Baifei; Wang Xin; Lu Peixiang; Senecha, Vinod

    2008-05-15

    The interaction of a linearly polarized intense laser pulse with an ultrathin nanometer plasma layer is investigated to understand the physics of the ion acceleration. It is shown by the computer simulation that the plasma response to the laser pulse comprises two steps. First, due to the vxB effect, electrons in the plasma layer are extracted and periodic ultrashort relativistic electron bunches are generated every half of a laser period. Second, strongly asymmetric Coulomb explosion of ions in the foil occurs due to the strong electrostatic charge separation, once the foil is burnt through. Followed by the laser accelerated electron bunch, the ion expansion in the forward direction occurs along the laser beam that is much stronger as compared to the backward direction.

  18. Measuring Fast Ion Losses in a Reversed Field Pinch Plasma

    NASA Astrophysics Data System (ADS)

    Bonofiglo, P. J.; Anderson, J. K.; Almagri, A. F.; Kim, J.; Clark, J.; Capecchi, W.; Sears, S. H.

    2015-11-01

    The reversed field pinch (RFP) provides a unique environment to study fast ion confinement and transport. The RFP's weak toroidal field, strong magnetic shear, and ability to enter a 3D state provide a wide range of dynamics to study fast ions. Core-localized, 25 keV fast ions are sourced into MST by a tangentially injected hydrogen/deuterium neutral beam. Neutral particle analysis and measured fusion neutron flux indicate enhanced fast ion transport in the plasma core. Past experiments point to a dynamic loss of fast ions associated with the RFP's transition to a 3D state and with beam-driven, bursting magnetic modes. Consequently, fast ion transport and losses in the RFP have garnered recent attention. Valuable information on fast-ion loss, such as energy and pitch distributions, are sought to provide a better understanding of the transport mechanisms at hand. We have constructed and implemented two fast ion loss detectors (FILDs) for use on MST. The FILDs have two, independent, design concepts: collecting particles as a function of v⊥ or with pitch greater than 0.8. In this work, we present our preliminary findings and results from our FILDs on MST. This research is supported by US DOE.

  19. Field evaporation ion source with possible application to electrostatic propulsion

    NASA Technical Reports Server (NTRS)

    Weizer, V. G.

    1971-01-01

    Field evaporation of solid metal electrodes has been proposed as an ion source for an electrostatic propulsion device. The chief advantage over existing ion sources is the prospect of 100 percent fuel utilization efficiency. This advantage arises as a result of the elimination of the need for a gaseous precursor state for propellant ionization. The attainment of required high surface field strengths is achieved through field-induced extrusion of the electrode geometry at elevated temperatures. Contributions of both surface and bulk transport mechanisms are taken into account.

  20. Cusped magnetic field mercury ion thruster. Ph.D. Thesis

    NASA Technical Reports Server (NTRS)

    Beattie, J. R.

    1976-01-01

    The importance of a uniform current density profile in the exhaust beam of an electrostatic ion thruster is discussed in terms of thrust level and accelerator system lifetime. A residence time approach is used to explain the nonuniform beam current density profile of the divergent magnetic field thruster. Mathematical expressions are derived which relate the thruster discharge power loss, propellant utilization, and double to single ion density ratio to the geometry and plasma properties of the discharge chamber. These relationships are applied to a cylindrical discharge chamber model of the thruster. Experimental results are presented for a wide range of the discharge chamber length. The thruster designed for this investigation was operated with a cusped magnetic field as well as a divergent field geometry, and the cusped field geometry is shown to be superior from the standpoint of beam profile uniformity, performance, and double ion population.

  1. Multiple ion species plasmas with thermal ions in an oblique magnetic field

    SciTech Connect

    Hatami, M. M.

    2013-08-15

    Using a three-fluid model, the combined effects of an oblique magnetic field and finite temperature of positive ion species on the characteristics of the sheath region of multi-component plasmas are investigated numerically. It is assumed that the ion species are singly charged and have different masses. In the presence of an external magnetic field, it is shown that the density distribution of positive ion species (especially the lighter ion species) begins to fluctuate and does not decrease monotonically towards the wall. Also, it is shown that by increasing the magnetic field, the amplitude of fluctuation increases and its position moves towards the sheath edge. Moreover, it is illustrated that the presence of the magnetic field affects the sheath width and by increasing the magnetic field, the sheath width decreases. In addition, the results show that in the presence of the magnetic field, the increase of temperature of positive ion species has an infinitesimal effect on the sheath width and density distribution of positive ion species.

  2. Asymmetric fluorocyclizations of alkenes.

    PubMed

    Wolstenhulme, Jamie R; Gouverneur, Véronique

    2014-12-16

    CONSPECTUS: The vicinal fluorofunctionalization of alkenes is an attractive transformation that converts feedstock olefins into valuable cyclic fluorinated molecules for application in the pharmaceutical, agrochemical, medical, and material sectors. The challenges associated with asymmetric fluorocyclizations induced by F(+) reagents are distinct from other types of halocyclizations. Processes initiated by the addition of an F(+) reagent onto an alkene do not involve the reversible formation of bridged fluoronium ions but generate acyclic β-fluorocationic intermediates. This mechanistic feature implies that fluorocyclizations are not stereospecific. A discontinuity exists between the importance of this class of fluorocyclization and the activation modes currently available to implement successful catalysis. Progress toward fluorocyclization has been achieved by investing in neutral and cationic [NF] reagent development. The body of work on asymmetric fluorination using chiral cationic [NF](+) reagents prepared by fluorine transfer from the dicationic [NF](2+) reagent Selectfluor to quinuclidines, inspired the development of asymmetric F(+)-induced fluorocyclizations catalyzed by cinchona alkaloids; for catalysis, the use of N-fluorobenzenesulfonimide, which is less reactive than Selectfluor, ensures that the achiral F(+) source remains unreactive toward the alkene. These organocatalyzed enantioselective fluorocyclizations can be applied to indoles to install the fluorine on a quaternary benzylic stereogenic carbon center and to afford fluorinated analogues of natural products featuring the hexahydropyrrolo[2,3-b]indole or the tetrahydro-2H-furo[2,3-b]indole skeleton. In an alternative approach, the poor solubility of dicationic Selectfluor bis(tetrafluoroborate) in nonpolar solvent was exploited with anionic phase transfer catalysis as the operating activation mode. Exchange of the tetrafluoroborate ions of Selectfluor with bulky lipophilic chiral anions (e

  3. Sharpening of field emitter tips using high-energy ions

    DOEpatents

    Musket, Ronald G.

    1999-11-30

    A process for sharpening arrays of field emitter tips of field emission cathodes, such as found in field-emission, flat-panel video displays. The process uses sputtering by high-energy (more than 30 keV) ions incident along or near the longitudinal axis of the field emitter to sharpen the emitter with a taper from the tip or top of the emitter down to the shank of the emitter. The process is particularly applicable to sharpening tips of emitters having cylindrical or similar (e.g., pyramidal) symmetry. The process will sharpen tips down to radii of less than 12 nm with an included angle of about 20 degrees. Because the ions are incident along or near the longitudinal axis of each emitter, the tips of gated arrays can be sharpened by high-energy ion beams rastered over the arrays using standard ion implantation equipment. While the process is particularly applicable for sharpening of arrays of field emitters in field-emission flat-panel displays, it can be effectively utilized in the fabrication of other vacuum microelectronic devices that rely on field emission of electrons.

  4. Evaluation of neutron radiation field in carbon ion therapy

    NASA Astrophysics Data System (ADS)

    Xu, Jun-Kui; Su, You-Wu; Li, Wu-Yuan; Yan, Wei-Wei; Chen, Xi-Meng; Mao, Wang; Pang, Cheng-Guo

    2016-01-01

    Carbon ions have significant advantages in tumor therapy because of their physical and biological properties. In view of the radiation protection, the safety of patients is the most important issue in therapy processes. Therefore, the effects of the secondary particles produced by the carbon ions in the tumor therapy should be carefully considered, especially for the neutrons. In the present work, the neutron radiation field induced by carbon ions was evaluated by using the FLUKA code. The simulated results of neutron energy spectra and neutron dose was found to be in good agreement with the experiment data. In addition, energy deposition of carbon ions and neutrons in tissue-like media was studied, it is found that the secondary neutron energy deposition is not expected to exceed 1% of the carbon ion energy deposition in a typical treatment.

  5. Quantifying vorticity in magnetic particle suspensions driven by symmetric and asymmetric multiaxial fields.

    DOE PAGESBeta

    Martin, James E.; Solis, Kyle Jameson

    2015-08-07

    We recently reported two methods of inducing vigorous fluid vorticity in magnetic particle suspensions. The first method employs symmetry-breaking rational fields. These fields are comprised of two orthogonal ac components whose frequencies form a rational number and an orthogonal dc field that breaks the symmetry of the biaxial ac field to create the parity required to induce deterministic vorticity. The second method is based on rational triads, which are fields comprised of three orthogonal ac components whose frequency ratios are rational (e.g., 1 : 2 : 3). For each method a symmetry theory has been developed that enables the predictionmore » of the direction and sign of vorticity as functions of the field frequencies and phases. However, this theory has its limitations. It only applies to those particular phase angles that give rise to fields whose Lissajous plots, or principal 2-d projections thereof, have a high degree of symmetry. Nor can symmetry theory provide a measure of the magnitude of the torque density induced by the field. In this paper a functional of the multiaxial magnetic field is proposed that not only is consistent with all of the predictions of the symmetry theories, but also quantifies the torque density. This functional can be applied to fields whose Lissajous plots lack symmetry and can thus be used to predict a variety of effects and trends that cannot be predicted from the symmetry theories. These trends include the dependence of the magnitude of the torque density on the various frequency ratios, the unexpected reversal of flow with increasing dc field amplitude for certain symmetry-breaking fields, and the existence of off-axis vorticity for rational triads, such as 1 : 3 : 5, that do not have the symmetry required to analyze by symmetry theory. As a result, experimental data are given that show the degree to which this functional is successful in predicting observed trends.« less

  6. Quantifying vorticity in magnetic particle suspensions driven by symmetric and asymmetric multiaxial fields.

    SciTech Connect

    Martin, James E.; Solis, Kyle Jameson

    2015-08-07

    We recently reported two methods of inducing vigorous fluid vorticity in magnetic particle suspensions. The first method employs symmetry-breaking rational fields. These fields are comprised of two orthogonal ac components whose frequencies form a rational number and an orthogonal dc field that breaks the symmetry of the biaxial ac field to create the parity required to induce deterministic vorticity. The second method is based on rational triads, which are fields comprised of three orthogonal ac components whose frequency ratios are rational (e.g., 1 : 2 : 3). For each method a symmetry theory has been developed that enables the prediction of the direction and sign of vorticity as functions of the field frequencies and phases. However, this theory has its limitations. It only applies to those particular phase angles that give rise to fields whose Lissajous plots, or principal 2-d projections thereof, have a high degree of symmetry. Nor can symmetry theory provide a measure of the magnitude of the torque density induced by the field. In this paper a functional of the multiaxial magnetic field is proposed that not only is consistent with all of the predictions of the symmetry theories, but also quantifies the torque density. This functional can be applied to fields whose Lissajous plots lack symmetry and can thus be used to predict a variety of effects and trends that cannot be predicted from the symmetry theories. These trends include the dependence of the magnitude of the torque density on the various frequency ratios, the unexpected reversal of flow with increasing dc field amplitude for certain symmetry-breaking fields, and the existence of off-axis vorticity for rational triads, such as 1 : 3 : 5, that do not have the symmetry required to analyze by symmetry theory. As a result, experimental data are given that show the degree to which this functional is successful in predicting observed trends.

  7. Asymmetric neutrino production in magnetized proto-neutron stars in fully relativistic mean-field approach

    SciTech Connect

    Maruyama, Tomoyuki; Kajino, Toshitaka; Hidaka, Jun; Takiwaki, Tomoya; Yasutake, Nobutoshi; Kuroda, Takami; Cheoun, Myung-Ki; Ryu, Chung-Yeol; Mathews, Grant J.

    2014-05-02

    We calculate the neutrino production cross-section in the proto-neutron-star matter under a strong magnetic field in the relativistic mean-field approach. We introduce a new parameter-set which can reproduce the 1.96 solar mass neutron star. We find that the production process increases emitted neutrinos along the direction parallel to the magnetic field and decrease those along its opposite direction. It means that resultant asymmetry due to the neutrino absorption and scattering process in the magnetic field becomes larger by the addition of the neutrino production process.

  8. Spherical probes at ion saturation in E × B fields

    NASA Astrophysics Data System (ADS)

    Patacchini, Leonardo; Hutchinson, Ian H.

    2010-03-01

    The ion saturation current to a spherical probe in the entire range of ion magnetization is computed with SCEPTIC3D, a new three-dimensional version of the kinetic code SCEPTIC designed to study transverse plasma flows. Results are compared with prior two-dimensional calculations valid in the magnetic-free regime (Hutchinson 2002 Plasma Phys. Control. Fusion 44 1953), and with recent semi-analytic solutions to the strongly magnetized transverse Mach probe problem (Patacchini and Hutchinson 2009 Phys. Rev. E 80 036403). At intermediate magnetization (ion Larmor radius close to the probe radius) the plasma density profiles show a complex three-dimensional structure that SCEPTIC3D can fully resolve, and, contrary to intuition, the ion current peaks provided the ion temperature is low enough. Our results are conveniently condensed in a single factor Mc, function of ion temperature and magnetic field only, providing the theoretical calibration for a transverse Mach probe with four electrodes placed at 45° to the magnetic field in a plane of flow and magnetic field.

  9. Effect of magnetic field inhomogeneity on ion cyclotron motion coherence at high magnetic field.

    PubMed

    Vladimirov, Gleb; Kostyukevich, Yury; Hendrickson, Christopher L; Blakney, Greg T; Nikolaev, Eugene

    2015-01-01

    A three-dimensional code based on the particle-in-cell algorithm modified to account for the inhomogeneity of the magnetic field was applied to determine the effect of Z(1), Z(2), Z(3), Z(4), X, Y, ZX, ZY, XZ(2) YZ(2), XY and X(2)-Y(2) components of an orthogonal magnetic field expansion on ion motion during detection in an FT-ICR cell. Simulations were performed for magnetic field strengths of 4.7, 7, 14.5 and 21 Tesla, including experimentally determined magnetic field spatial distributions for existing 4.7 T and 14.5 T magnets. The effect of magnetic field inhomogeneity on ion cloud stabilization ("ion condensation") at high numbers of ions was investigated by direct simulations of individual ion trajectories. Z(1), Z(2), Z(3) and Z(4) components have the largest effect (especially Z(1)) on ion cloud stability. Higher magnetic field strength and lower m/z demand higher relative magnetic field homogeneity to maintain cloud coherence for a fixed time period. The dependence of mass resolving power upper limit on Z(1) inhomogeneity is evaluated for different magnetic fields and m/z. The results serve to set the homogeneity requirements for various orthogonal magnetic field components (shims) for future FT-ICR magnet design. PMID:26307725

  10. Linear and nonlinear optical properties in an asymmetric double quantum well under intense laser field: Effects of applied electric and magnetic fields

    NASA Astrophysics Data System (ADS)

    Yesilgul, U.; Al, E. B.; Martínez-Orozco, J. C.; Restrepo, R. L.; Mora-Ramos, M. E.; Duque, C. A.; Ungan, F.; Kasapoglu, E.

    2016-08-01

    In the present study, the effects of electric and magnetic fields on the linear and third-order nonlinear optical absorption coefficients and relative change of the refractive index in asymmetric GaAs/GaAlAs double quantum wells under intense laser fields are theoretically investigated. The electric field is oriented along the growth direction of the heterostructure while the magnetic field is taken in-plane. The intense laser field is linear polarization along the growth direction. Our calculations are made using the effective-mass approximation and the compact density-matrix approach. Intense laser effects on the system are investigated with the use of the Floquet method with the consequent change in the confinement potential of heterostructures. Our results show that the increase of the electric and magnetic fields blue-shifts the peak positions of the total absorption coefficient and of the total refractive index while the increase of the intense laser field firstly blue-shifts the peak positions and later results in their red-shifting.

  11. Mechanism of DNA Trapping in Nanoporous Structures during Asymmetric Pulsed-Field Electrophoresis

    NASA Astrophysics Data System (ADS)

    Zhou, Ya; Harrison, D. Jed

    2014-03-01

    DNA molecules (>100kbp) are trapped in separation sieves when high electric fields are applied in pulsed field electrophoresis, seriously limiting the speed of separation. Using crystalline particle arrays, to generate interstitial pores for molecular sieving, allows higher electric fields than in gels, (e.g 40 vs 5 V/cm), however trapping still limits the field strength. Using reverse pulses, which release DNA from being fully-stretched, allows higher fields (140 V/cm). We investigate the trapping mechanism of individual DNA molecules in ordered nanoporous structures. Two prerequisites for trapping are revealed by the dynamics of single trapped DNA, hernia formation and fully-stretched U/J shapes. Fully stretched DNA has longer unhooking times than expected by simple models. We propose a dielectrophoretic (DEP) force reduces the mobility of segments at the apex of the U or J, where field gradients are highest, based on simulations. A modified model for unhooking time is obtained after the DEP force is introduced. The new model explains the unhooking time data by predicting an infinite trapping time when the ratio of arm length differences (of the U or J) to molecule length Δx / L < β . β is a DEP parameter that is found to strongly increase with electric field. The work was supported by grant from Natural Sciences and Engineering Research Council of Canada (NSERC) and the National Institute for Nanotechnology (NINT).

  12. Effects of 3D Toroidally Asymmetric Magnetic Field on Tokamak Magnetic Surfaces

    NASA Astrophysics Data System (ADS)

    Lao, L. L.

    2005-10-01

    The effects of 3D error magnetic field on magnetic surfaces are investigated using the DIII-D internal coils (I-Coils). Slowly rotating n=1 traveling waves at 5 Hz and various amplitudes were applied to systematically perturb the edge surfaces by programming the I-Coil currents. The vertical separatrix location difference between EFIT magnetic reconstructions that assumes toroidal symmetry and Thomson scattering Te measurements responds in phase to the applied perturbed field. The oscillation amplitudes increase with the strength of the applied field but are much smaller than those expected from the applied field alone. The results indicate that plasma response is important. Various plasma response models based on results from the MHD codes MARS and GATO are being developed and compared to the experimental observations. To more accurately evaluate the effects of magnetic measurement errors, a new form of the magnetic uncertainty matrix is also being implemented into EFIT. Details will be presented.

  13. Electron-ion collision operator in strong electromagnetic fields

    NASA Astrophysics Data System (ADS)

    Fraiman, Gennadiy; Balakin, Alexey

    2012-10-01

    The pair electron-ion collision operator is found for the kinetic equation describing the one-particle drift distribution in strong electromagnetic fields [1]. The pair collisions are studied under the conditions when the oscillation velocity of an electron driven by an external electromagnetic wave is much larger than the electron drift velocity. The operator is presented in the Boltzmann form and describes collisions with both small and large changes of the particle momentum. In contrast with the Landau collision operator, which describes diffusion in the momentum space, the collision operator that we propose describes a new and very important effect, namely, Coulomb attraction of a wave-driven oscillating electron to an ion due to multiple returns of the electron to the same ion. This effect leads to a large increase of the collision cross-section of electron-ion collisions in strong laser fields, to increased efficiency of the Joule heating in plasma, to the generation of fast electrons through e-i collisions, etc. [4pt] [1] A. A. Balakin and G. M. Fraiman, Electron-ion collision operator in strong electromagnetic fields, EPL 93, 35001 (2011).

  14. Ion transferring in polyelectrolyte networks in electric fields

    NASA Astrophysics Data System (ADS)

    Li, Honghao; Erbas, Aykut; Zwanikken, Jos; Olvera de La Cruz, Monica

    Ion-conducting polyelectrolyte gels have drawn the attention of many researchers in the last few decades as they have wide applications not only in lithium batteries but also as stretchable, transparent ionic conductor or ionic cables devices. However, ion dynamics in polyelectrolyte gels has been much less studied analytically or computationally due to the complicated interplay of long-range electrostatic and short-range interactions. Here we propose a coarse-grained non-equilibrium molecular dynamics simulation to study the ion dynamics in polyelectrolyte gels under external electric fields. We found a nonlinear response region where the molar conductivity of polyelectrolyte gels increases with external fields. We propose counterion redistribution under electric fields as the driving mechanism. We also found the ionic conductivity to be modulated by changing polylelectrolyte network topology such as the chain length. Our discovery reveals the essential difference of ion dynamics between electrolytes and polyelectrolyte gels. These results will expand our understanding in charged polymeric systems and help in designing ion-conducting devices with higher conductivity.

  15. A Systematic Investigation of Quaternary Ammonium Ions as Asymmetric Phase Transfer Catalysts. Synthesis of Catalyst Libraries and Evaluation of Catalyst Activity

    PubMed Central

    Denmark, Scott E.; Gould, Nathan D.; Wolf, Larry M.

    2011-01-01

    Despite over three decades of research into asymmetric phase transfer catalysis (APTC), a fundamental understanding of the factors that affect the rate and stereoselectivity of this important process are still obscure. This paper describes the initial stages of a long-term program aimed at elucidating the physical organic foundations of APTC employing a chemoinformatic analysis of the alkylation of a protected glycine imine with a libraries of enantiomerically enriched quaternary ammonium ions. The synthesis of the quaternary ammonium ions follows a diversity oriented approach wherein the tandem inter[4+2]/intra[3+2] cycloaddition of nitroalkenes serves as the key transformation. A two part synthetic strategy comprised of: (1) preparation of enantioenriched scaffolds and (2) development of parallel synthesis procedures is described. The strategy allows for the facile introduction of four variable groups in the vicinity of a stereogenic quaternary ammonium ion. The quaternary ammonium ions exhibited a wide range of activity and to a lesser degree enantioselectivity. Catalyst activity and selectivity are rationalized in a qualitative way based on the effective positive potential of the ammonium ion. PMID:21446721

  16. Near-surface density profiling of Fe ion irradiated Si (100) using extremely asymmetric x-ray diffraction by variation of the wavelength

    SciTech Connect

    Khanbabaee, B. Pietsch, U.; Facsko, S.; Doyle, S.

    2014-10-20

    In this work, we report on correlations between surface density variations and ion parameters during ion beam-induced surface patterning process. The near-surface density variations of irradiated Si(100) surfaces were investigated after off-normal irradiation with 5 keV Fe ions at different fluences. In order to reduce the x-ray probing depth to a thickness below 5 nm, the extremely asymmetrical x-ray diffraction by variation of wavelength was applied, exploiting x-ray refraction at the air-sample interface. Depth profiling was achieved by measuring x-ray rocking curves as function of varying wavelengths providing incidence angles down to 0°. The density variation was extracted from the deviations from kinematical Bragg angle at grazing incidence angles due to refraction of the x-ray beam at the air-sample interface. The simulations based on the dynamical theory of x-ray diffraction revealed that while a net near-surface density decreases with increasing ion fluence which is accompanied by surface patterning, there is a certain threshold of ion fluence to surface density modulation. Our finding suggests that the surface density variation can be relevant with the mechanism of pattern formation.

  17. Strain evolution in Si substrate due to implantation of MeV ion observed by extremely asymmetric x-ray diffraction

    SciTech Connect

    Emoto, T.; Ghatak, J.; Satyam, P. V.; Akimoto, K.

    2009-08-15

    We studied the strain introduced in a Si(111) substrate due to MeV ion implantation using extremely asymmetric x-ray diffraction and measured the rocking curves of asymmetrical 113 diffraction for the Si substrates implanted with a 1.5 MeV Au{sup 2+} ion at fluence values of 1x10{sup 13}, 5x10{sup 13}, and 1x10{sup 14}/cm{sup 2}. The measured curves consisted of a bulk peak and accompanying subpeak with an interference fringe. The positional relationship of the bulk peak to the subpeak and the intensity variation of those peaks with respect to the wavelengths of the x rays indicated that crystal lattices near the surface were strained; the lattice spacing of surface normal (111) planes near the surface was larger than that of the bulk. Detailed strain profiles along the depth direction were successfully estimated using a curve-fitting method based on Darwin's dynamical diffraction theory. Comparing the shapes of resultant strain profiles, we found that a strain evolution rapidly occurred within a depth of approx300 nm at fluence values between 1x10{sup 13} and 5x10{sup 13}/cm{sup 2}. This indicates that formation of the complex defects progressed near the surface when the fluence value went beyond a critical value between 1x10{sup 13} and 5x10{sup 13}/cm{sup 2} and the defects brought a large strain to the substrate.

  18. Spin wave mode coexistence: A consequence of the Oersted field induced asymmetric energy landscape

    NASA Astrophysics Data System (ADS)

    Dumas, Randy; Iacocca, Ezio; Bonetti, Stefano; Sani, Sohrab; Mohseni, Majid; Eklund, Anders; Persson, Johan; Heinonen, Olle; Akerman, Johan

    2013-03-01

    The emerging field of magnonics relies on the systematic generation, manipulation, and detection of spin waves (SWs). Nanocontact spin torque oscillators (NC-STOs) provide an ideal platform to study spin transfer torque induced SW emission. In analogy to two species competing for the same food supply it has been argued that only one SW mode can survive in the steady state. However, as evidenced in many experiments clear signatures of mode-hopping are often observed. We present a third possibility, namely that under the correct experimental conditions, mode coexistence can be realized. Micromagnetic simulations reveal that the SW modes are spatially separated under the NC. Mode coexistence is facilitated by the local field asymmetries induced by the spatially inhomogeneous Oersted field in the vicinity of the NC and further promoted by SW localization. Finally, both simulation and experiment reveal a weak low frequency signal exactly at the difference of the mode frequencies, consistent with inter-modulation of two coexistent modes.

  19. Phase transition and critical end point driven by an external magnetic field in asymmetric quark matter

    NASA Astrophysics Data System (ADS)

    Costa, Pedro; Ferreira, Márcio; Hansen, Hubert; Menezes, Débora P.; Providência, Constança

    2014-03-01

    The location of the critical end point (CEP) in the QCD phase diagram is determined under different scenarios. The effect of strangeness, isospin/charge asymmetry and an external magnetic field is investigated. The discussion is performed within the 2+1 flavor Nambu-Jona-Lasinio model with Polyakov loop. It is shown that isospin asymmetry shifts the CEP to larger baryonic chemical potentials and smaller temperatures. At large asymmetries the CEP disappears. However, a strong enough magnetic field drives the system into a first order phase transition.

  20. The influence of stray magnetic fields on ion beam neutralization

    NASA Technical Reports Server (NTRS)

    Feng, Y.-C.; Wilbur, P. J.

    1982-01-01

    An experimental investigation is described of a comparison between the ion beam neutralization characteristics of a local neutralizer (within approximately 5 cm of the beam edge) and those associated with a distant one (approximately 1 meter away from the thruster). The influence of magnetic fields in the vicinity of the neutralizer cathode orifice which are either parallel or normal to the neutralizer axis is assessed. The plasma property profiles which reflect the influence of the magnetic fields are measured. The results suggest that magnetic fields at the region of a neutralizer cathode orifice influence its ability to couple to the ion beam. They reveal that there is a potential jump from the neutralizer cathode orifice to the plasma which exists close to the orifice. This potential drop is found to increase as the axial component of magnetic flux density increases. A magnetic field perpendicular to the neutralizer axis induces a potential rise a few centimeters downstream from the neutralizer cathode.

  1. In-situ phase transformation in the field ion microscope.

    NASA Astrophysics Data System (ADS)

    Miller, M. K.; Russell, K. F.

    1991-04-01

    Many materials undergo an athermal martensite transformation when cooled. This transformation has been observed in the Tishomingo meteorite during cooling to cryogenic temperatures. The meteorite is unstable when cooled to the cryogenic temperatures (40 - 85K) suitable for field ion imaging since the martensite start temperature of this material (Fe-32.5 wt%Ni) is approximately 235K.

  2. Electrostatic ion acceleration across a diverging magnetic field

    NASA Astrophysics Data System (ADS)

    Ichihara, D.; Uchigashima, A.; Iwakawa, A.; Sasoh, A.

    2016-08-01

    Electrostatic ion acceleration across a diverging magnetic field, which is generated by a solenoid coil, permanent magnets, and a yoke between an upstream ring anode and a downstream off-axis hollow cathode, is investigated. The cathode is set in an almost magnetic-field-free region surrounded by a cusp. Inside the ring anode, an insulating wall is set to form an annular slit through which the working gas is injected along the anode inner surface, so the ionization of the working gas is enhanced there. By supplying 1.0 Aeq of argon as working gas with a discharge voltage of 225 V, the ion beam energy reached about 60% of a discharge voltage. In spite of this unique combination of electrodes and magnetic field, a large electrical potential drop is formed almost in the axial direction, located slightly upstream of the magnetic-field-free region. The ion beam current almost equals the equivalent working gas flow rate. These ion acceleration characteristics are useful for electric propulsion in space.

  3. Manipulating electron-ion recollision in a midinfrared laser field

    NASA Astrophysics Data System (ADS)

    Zheng, Yinghui; Diao, Hanhu; Zeng, Zhinan; Ge, Xiaochun; Li, Ruxin; Xu, Zhizhan

    2015-09-01

    As one of the most important physical processes of strong-field laser-matter interaction, laser-driven electron-ion recollision depends sensitively on the polarization of the laser field and can be effectively manipulated via an orthogonally polarized two-color (OTC) laser field. Here we present an extension of recollision manipulation in an OTC field to the midinfrared laser field regime, and demonstrate that only a few recollisions occur in a multicycle 1800 /900 nm OTC laser field. The number of recollisions can be controlled by simply tuning the relative delay of the two-color laser pulses, and this manipulation process can be visualized by measuring the high-order harmonic spectra. When the intensity of a midinfrared OTC field is further increased, a single recollision can be correlated to one hump in the harmonic spectrum, which will help to increase the measurement accuracy of time-resolved dynamics in atoms and molecules.

  4. Solar wind control of the low-latitude asymmetric magnetic disturbance field

    NASA Technical Reports Server (NTRS)

    Clauer, C. R.; Mcpherron, R. L.; Searls, C.

    1983-01-01

    The extent to which the low latitude dawn-dusk magnetic asymmetry is controlled by the dawn-dusk solar wind motional electric field VBs and/or substorm processes measured by the westward auroral electrojet index AL is studied using the technique of empirical linear prediction filters. A new index, (ASYM), defined as the difference between dawn and dusk deviations in the X (geomagnetic Northward) magnetic field component, is used to measure the dawn-dusk asymmetry. Quantitative information which characterizes the coupling processes are provided by the empirically determined filters obtained from this analysis. Results indicate that some currents are directly driven by the solar wind-magnetosphere interaction and that their magnetic perturbations contribute to both the AL and ASYM indices. However, a portion of the AL index that is uncorrelated with VBs is correlated with ASYM which suggests that internal magnetospheric processes also contribute to AL and ASYM.

  5. Origin of Asymmetric Solvation Effects for Ions in Water and Organic Solvents Investigated Using Molecular Dynamics Simulations: The Swain Acity-Basity Scale Revisited.

    PubMed

    Reif, Maria M; Hünenberger, Philippe H

    2016-08-25

    The asymmetric solvation of ions can be defined as the tendency of a solvent to preferentially solvate anions over cations or cations over anions, at identical ionic charge magnitudes and effective sizes. Taking water as a reference, these effects are quantified experimentally for many solvents by the relative acity (A) and basity (B) parameters of the Swain scale. The goal of the present study is to investigate the asymmetric solvation of ions using molecular dynamics simulations, and to connect the results to this empirical scale. To this purpose, the charging free energies of alkali and halide ions, and of their hypothetical oppositely charged counterparts, are calculated in a variety of solvents. In a first set of calculations, artificial solvent models are considered that present either a charge or a shape asymmetry at the molecular level. The solvation asymmetry, probed by the difference in charging free energy between the two oppositely charged ions, is found to encompass a term quadratic in the ion charge, related to the different solvation structures around the anion and cation, and a term linear in the ion charge, related to the solvation structure around the uncharged ion-sized cavity. For these simple solvent models, the two terms are systematically counteracting each other, and it is argued that only the quadratic term should be retained when comparing the results of simulations involving physical solvents to experimental data. In a second set of calculations, 16 physical solvents are considered. The theoretical estimates for the acity A are found to correlate very well with the Swain parameters, whereas the correlation for B is very poor. Based on this observation, the Swain scale is reformulated into a new scale involving an asymmetry parameter Σ, positive for acitic solvents and negative for basitic ones, and a polarity parameter Π. This revised scale has the same predictive power as the original scale, but it characterizes asymmetry in an

  6. ac-Field-induced fluid pumping in microsystems with asymmetric temperature gradients.

    PubMed

    Holtappels, Moritz; Stubbe, Marco; Gimsa, Jan

    2009-02-01

    We present two different designs of electrohydrodynamic micropumps for microfluidic systems. The micropumps have no movable parts, and their simple design allows for fabrication by microsystems technology. The pumps are operated by ac voltages from 1 to 60 V and were tested with aqueous solutions in the conductivity range of 1-112 mS m(-1). The pump effect is induced by an ac electric field across a fluid medium with an inhomogeneous temperature distribution. It is constant over a wide range of the ac field frequency with a conductivity-dependent drop-off at high frequencies. The temperature-dependent conductivity and permittivity distributions in the fluid induce space charges that interact with the electric field and induce fluid motion. The temperature distribution can be generated either by Joule heating in the medium or by external heating. We present experimental results obtained with two prototypes featuring Joule heating and external heating by a heating filament. Experimental and numerical results are compared with an analytical model. PMID:19391842

  7. Magnetic Field Would Reduce Electron Backstreaming in Ion Thrusters

    NASA Technical Reports Server (NTRS)

    Foster, John E.

    2003-01-01

    The imposition of a magnetic field has been proposed as a means of reducing the electron backstreaming problem in ion thrusters. Electron backstreaming refers to the backflow of electrons into the ion thruster. Backstreaming electrons are accelerated by the large potential difference that exists between the ion-thruster acceleration electrodes, which otherwise accelerates positive ions out of the engine to develop thrust. The energetic beam formed by the backstreaming electrons can damage the discharge cathode, as well as other discharge surfaces upstream of the acceleration electrodes. The electron-backstreaming condition occurs when the center potential of the ion accelerator grid is no longer sufficiently negative to prevent electron diffusion back into the ion thruster. This typically occurs over extended periods of operation as accelerator-grid apertures enlarge due to erosion. As a result, ion thrusters are required to operate at increasingly negative accelerator-grid voltages in order to prevent electron backstreaming. These larger negative voltages give rise to higher accelerator grid erosion rates, which in turn accelerates aperture enlargement. Electron backstreaming due to accelerator-gridhole enlargement has been identified as a failure mechanism that will limit ionthruster service lifetime. The proposed method would make it possible to not only reduce the electron backstreaming current at and below the backstreaming voltage limit, but also reduce the backstreaming voltage limit itself. This reduction in the voltage at which electron backstreaming occurs provides operating margin and thereby reduces the magnitude of negative voltage that must be placed on the accelerator grid. Such a reduction reduces accelerator- grid erosion rates. The basic idea behind the proposed method is to impose a spatially uniform magnetic field downstream of the accelerator electrode that is oriented transverse to the thruster axis. The magnetic field must be sufficiently

  8. Ion temperature fluctuation measurements using a retarding field analyzer.

    PubMed

    Nedzelskiy, I S; Silva, C; Duarte, P; Fernandes, H

    2011-04-01

    The retarding field analyzer (RFA) is a widely used diagnostic tool for the ion temperature measurement in the scrape-off-layer (SOL) of the thermonuclear plasma devices. However, the temporal resolution in the standard RFA application is restricted to the ms timescale. In this paper, a dc operation of the RFA is considered, which allows for the measurement of the plasma ion temperature fluctuations. The method is based on the relation for the RFA current-voltage (I-V) characteristic resulted from a common RFA model of shifted Maxwellian distribution of the analyzed ions, and the measurements of two points on the exponentially decaying region of the I-V characteristic with two differently dc biased RFA electrodes. The method has been tested and compared with conventional RFA measurements of the ion temperature in the tokamak ISTTOK SOL plasma. An ion temperature of T(i) = 17 eV is obtained near the limiter position. The agreement between the results of the two methods is within ∼25%. The amplitude of the ion temperature fluctuations is found to be around 5 eV at this location. The method has been validated by taking into account the effect of fluctuations in the plasma potential and the noise contamination, proving the reliability of the results obtained. Finally, constrains to the method application are discussed that include a negligible electron emission from the RFA grids and the restriction to operate in the exponentially decaying region of the I-V characteristic. PMID:21529006

  9. Asymmetric photoelectron momentum distribution driven by two-color XUV fields

    NASA Astrophysics Data System (ADS)

    Wu, Wan-Yang; He, Feng

    2016-02-01

    The photoionization of He+ in two-color XUV fields is studied by numerically solving the time-dependent Schrödinger equation. He+ may be ionized by directly absorbing one high-energetic photon or by absorbing two photons sequentially by mediating an excited state. The interference of these two pathways results in either enhancement or suppression of photoionization, depending on the propagating direction of the photoelectron and the relative phase of two pulses. The two-pathway interference also induces the split of photoelectron momenta. This study shows that the participation of intermediate states may substantially change photoionization processes.

  10. Near field properties in relativistic heavy ion collisions

    NASA Astrophysics Data System (ADS)

    Li, Yang; Fries, Rainer; Kapusta, Joseph

    2006-04-01

    We study the properties of the soft gluon field produced in relativistic heavy ion collisions. In the spirit of McLerran-Venugopalan model, we write the field potential in a power series of the proper time τ and solve the Yang-Mills equation along with color current conservation equations simultaneously. We find that the classical gluon field at small τ, i.e., the near field, is mainly longitudinal. We also calculate the energy-momentum tensor of the field. This gluon field will decay and thermalize into a quark gluon plasma. Our results can be used as the initial conditions for the consequent relativistic hydrodynamic description of the dense parton matter.

  11. Ion Thruster Discharge Performance Per Magnetic Field Topography

    NASA Technical Reports Server (NTRS)

    Wirz, Richard E.; Goebel, Dan

    2006-01-01

    DC-ION is a detailed computational model for predicting the plasma characteristics of rain-cusp ion thrusters. The advanced magnetic field meshing algorithm used by DC-ION allows precise treatment of the secondary electron flow. This capability allows self-consistent estimates of plasma potential that improves the overall consistency of the results of the discharge model described in Reference [refJPC05mod1]. Plasma potential estimates allow the model to predict the onset of plasma instabilities, and important shortcoming of the previous model for optimizing the design of discharge chambers. A magnetic field mesh simplifies the plasma flow calculations, for both the ions and the secondary electrons, and significantly reduces numerical diffusion that can occur with meshes not aligned with the magnetic field. Comparing the results of this model to experimental data shows that the behavior of the primary electrons, and the precise manner of their confinement, dictates the fundamental efficiency of ring-cusp. This correlation is evident in simulations of the conventionally sized NSTAR thruster (30 cm diameter) and the miniature MiXI thruster (3 cm diameter).

  12. Electron and ion kinetics and anode plasma formation in two applied Br field ion diodes

    NASA Astrophysics Data System (ADS)

    Johnson, D. J.; Quintenz, J. P.; Sweeney, M. A.

    1985-02-01

    Two magnetically insulated ion diodes that utilize a radial applied-B field are described. Both diodes generate an annular beam that is extracted along the diode axis. The first diode operated at 1.2 MV and 600 kA for 25 ns and generated a 300-kA ion beam. The second operated at 300 kV, 100 kA and generated 15 kA of ion current. The first diode was used to study diode performance as a function of inner and outer anode-cathode gaps, the applied-B field, and transmission line current ratios. The second diode was used to study anode plasma formation. The diodes were operated below Bcrit, resulting in electron leakage to the anode, especially near the outer cathode. A definition of Bcrit applicable to extraction diodes is given and methods of improving ion production efficiency in these diodes are suggested. The strong correlation of ion production with visible light emission suggests, however, that the electron loss played an important role in anode turn-on. The breakdown of neutral gas desorbed by electron impact is thought to be the anode plasma production mechanism. The grazing incidence leakage electrons affect the breakdown by significantly enhancing space-charge-induced electric fields in the dielectric-filled anode grooves.

  13. Observations of asymmetric velocity fields and gas cooling in the NGC 4636 galaxy group X-ray halo

    NASA Astrophysics Data System (ADS)

    Ahoranta, Jussi; Finoguenov, Alexis; Pinto, Ciro; Sanders, Jeremy; Kaastra, Jelle; de Plaa, Jelle; Fabian, Andrew

    2016-08-01

    Aims: This study aims to probe the thermodynamic properties of the hot intragroup medium (IGM) plasma in the core regions of the NGC 4636 galaxy group by detailed measurements of several emission lines and their relative intensities. Methods: We analyzed deep XMM-Newton Reflection Grating Spectrometer (RGS) data in five adjacent spectral regions in the central parts of the NGC 4636 galaxy group. We examined the suppression of the Fe xvii resonance line (15.01 Å) as compared to the forbidden lines of the same ion (17.05 Å and 17.10 Å). The presence and radial dependence of the cooling flow was investigated through spectral modeling. Parallel analysis with deep Chandra Advances CCD Imaging Spectrometer (ACIS) data was conducted to gain additional information about the thermodynamical properties of the IGM. Results: The plasma at the group center to the north shows efficient Fe xvii ion resonant scattering, yielding (Iλ17.05 + Iλ17.10) /Iλ15.01 line ratios up to 2.9 ± 0.4, corresponding toabout twice the predicted line ratio. In contrast, no resonant scattering was detected at the south side. The regions featuring resonant scattering coincide with those embodying large amounts of cool (kT ≲ 0.4 keV) gas phases, and the spectral imprints of cooling gas with a total mass deposition rate of ~0.8 M⊙ yr-1 within the examined region of 2.4' × 5.0'. Conclusions: We interpret the results as possible evidence of asymmetric turbulence distribution in the NGC 4636 IGM: turbulence dominates the gas dynamics to the south, while collective gas motions characterize the dynamics to the north. X-ray images show imprints of energetic AGN at both sides, yet we find evidence of turbulence heating at the south and gas cooling at the north of the core. We infer that the observed asymmetry may be the result of the specific observation angle to the source, or arise from the turbulence driven by core sloshing at south side.

  14. Characterization of sodium hyaluronate blends using frit inlet asymmetrical flow field-flow fractionation and multiangle light scattering.

    PubMed

    Ali, Muhammad; Hwang, Euijin; Cho, Il-Hwan; Moon, Myeong Hee

    2012-01-01

    We characterized ultrahigh molecular weight sodium hyaluronate (NaHA) and blended pharmaceutical products containing NaHA using flow field-flow fractionation and multiangle light scattering-differential refractive index (FlFFF-MALS-DRI). NaHA is a water-soluble polysaccharide with a range of molecular weights (MW; 10(5)~10(8) Da) that is found in body fluids and tissues. NaHA is also used commercially in pharmaceutical and cosmetic applications. We used a frit inlet asymmetrical FlFFF channel to separate aqueous polymers according to their hydrodynamic size, and we used on-line measurements of light scattering to obtain the MW distribution (MWD) as well as structural information about NaHA in aqueous solution. In this study, we investigated NaHA and anti-adhesive blend mixtures of NaHA (a commercial NaHA blend mixture containing sodium carboxymethyl cellulose and a new blend with hydroxyethyl starch (HES)) to determine the molecular weight distribution MWD of NaHA and the blend mixtures and to obtain structural information about these compounds in aqueous solution. We also examined the characteristics of NaHA-HES-polylactic-co-glycolic acid film products exposed to gamma radiation for sterilization purposes. PMID:22101460

  15. Study on steric transition in asymmetrical flow field-flow fractionation and application to characterization of high-energy material.

    PubMed

    Dou, Haiyang; Lee, Yong-Ju; Jung, Euo Chang; Lee, Byung-Chul; Lee, Seungho

    2013-08-23

    In field-flow fractionation (FFF), there is the 'steric transition' phenomenon where the sample elution mode changes from the normal to steric/hyperlayer mode. Accurate analysis by FFF requires understanding of the steric transition phenomenon, particularly when the sample has a broad size distribution, for which the effect by combination of different modes may become complicated to interpret. In this study, the steric transition phenomenon in asymmetrical flow FFF (AF4) was studied using polystyrene (PS) latex beads. The retention ratio (R) gradually decreases as the particle size increases (normal mode) and reaches a minimum (Ri) at diameter around 0.5μm, after which R increases with increasing diameter (steric/hyperlayer mode). It was found that the size-based selectivity (Sd) tends to increase as the channel thickness (w) increases. The retention behavior of cyclo-1,3,5-trimethylene-2,4,6-trinitramine (commonly called 'research department explosive' (RDX)) particles in AF4 was investigated by varying experimental parameters including w and flow rates. AF4 showed a good reproducibility in size determination of RDX particles with the relative standard deviation of 4.1%. The reliability of separation obtained by AF4 was evaluated by transmission electron microscopy (TEM). PMID:23871284

  16. Aggregation behavior of fullerenes in aqueous solutions: a capillary electrophoresis and asymmetric flow field-flow fractionation study.

    PubMed

    Astefanei, Alina; Núñez, Oscar; Galceran, Maria Teresa; Kok, Wim Th; Schoenmakers, Peter J

    2015-10-01

    In this work, the electrophoretic behavior of hydrophobic fullerenes [buckminsterfullerene (C60), C70, and N-methyl-fulleropyrrolidine (C60-pyrr)] and water-soluble fullerenes [fullerol (C60(OH)24); polyhydroxy small gap fullerene, hydrated (C120(OH)30); C60 pyrrolidine tris acid (C60-pyrr tris acid); and (1,2-methanofullerene C60)-61-carboxylic acid (C60CHCOOH)] in micellar electrokinetic capillary chromatography (MECC) was evaluated. The aggregation behavior of the water-soluble compounds in MECC at different buffer and sodium dodecyl sulfate (SDS) concentrations and pH values of the background electrolyte (BGE) was studied by monitoring the changes observed in the electrophoretic pattern of the peaks. Broad and distorted peaks that can be attributed to fullerene aggregation were obtained in MECC which became narrower and more symmetric by working at low buffer and SDS concentrations (below the critical micelle concentration, capillary zone electrophoresis (CZE) conditions). For the characterization of the suspected aggregates formed (size and shape), asymmetrical flow field-flow fractionation (AF4) and transmission electron microscopy (TEM) were used. The results showed that the increase in the buffer concentration promoted the aggregation of the particles, while the presence of SDS micelles revealed multiple peaks corresponding to particles of different aggregation degrees. Furthermore, MECC has been applied for the first time for the analysis of C60 in two different cosmetic products (i.e., anti-aging serum and facial mask). PMID:26314484

  17. Study on aggregation behavior of Cytochrome C-conjugated silver nanoparticles using asymmetrical flow field-flow fractionation.

    PubMed

    Kim, Sun Tae; Lee, Yong-Ju; Hwang, Yu-Sik; Lee, Seungho

    2015-01-01

    In this study, 40 nm silver nanoparticles (AgNPs) were synthesized using the citrate reduction method and then the surface of AgNPs was modified by conjugating Cytochrome C (Cyto C) to improve stability and to enhance bioactivity and biocompatibility of AgNPs. It is known that Cyto C may undergo conformational changes under various conditions of pH, temperature, ionic strength, etc., resulting in aggregation of the particles. These parameters also affect the size and size distribution of Cyto C-conjugated AgNPs (Cyto C-AgNP). ζ-potential measurement revealed that the adsorption of Cyto C on the surface of AgNPs is saturated at the molar ratio [Cyto C]/[AgNPs] above about 300. Asymmetrical flow field-flow fractionation (AsFlFFF) analysis showed that hydrodynamic diameter of AgNPs increases by about 4 nm when the particle is saturated by Cyto C. The aggregation behavior of Cyto C-AgNP at various conditions of pH, temperature and ionic strength were investigated using AsFlFFF and UV-vis spectroscopy. It was found that the aggregation of Cyto C-AgNP increases with decreasing pH, increasing temperature and ionic strength due to denaturation of Cyto C on AgNPs and reduction in the thickness of electrostatic double layer on the surface of Cyto C-AgNP. PMID:25476400

  18. Development and evaluation of methods for starch dissolution using asymmetrical flow field-flow fractionation. Part II: Dissolution of amylose.

    PubMed

    Perez-Rea, Daysi; Bergenståhl, Björn; Nilsson, Lars

    2016-02-01

    In this paper, we investigate whether dissolution in water under autoclaving conditions (140 °C, 20 min) or in dimethyl sulfoxide, DMSO (100 °C, 1 h), is preferable for characterization of amylose. Two types of amylose, potato and maize, were dissolved either in water using an autoclave or in DMSO. On the aqueous solutions obtained, the extent of molecular dissolution of the sample (referred to as the dissolution yield) was determined by enzymatic analysis as well as the molecular properties, such as molar mass and root-mean-square radius, obtained with asymmetrical flow field-flow fractionation coupled to multi-angle light scattering and differential refractive index detection (AF4-MALS-dRI). The results showed that both dissolution methods are efficient at dissolving amylose. However, AF4-MALS-dRI analysis revealed substantial differences. Amylose aqueous solutions obtained by dissolution in DMSO were relatively stable over time, but the dissolution method in autoclave caused some degradation of the molecules, and their solutions display a high tendency to retrograde. PMID:26232931

  19. Development and evaluation of methods for starch dissolution using asymmetrical flow field-flow fractionation. Part I: Dissolution of amylopectin.

    PubMed

    Perez-Rea, Daysi; Bergenståhl, Björn; Nilsson, Lars

    2015-06-01

    We have investigated methods of starch dissolution with the aim of finding an optimum method to completely dissolve starch granules to form a molecularly dissolved starch solution without degradation of the polymers. Glycogen was used as a model molecule for amylopectin, to identify the dissolution conditions under which the degradation of the polymers was limited or not present. Dissolution was performed in water with temperatures up to 200 °C, facilitated by the use of heating in an autoclave or a microwave oven, or in dimethyl sulfoxide (DMSO) at 100 °C. Waxy maize starch was chosen due to its high content of amylopectin and very low content of amylose. The degree of starch dissolution under different conditions was determined enzymatically. The effect of different dissolution conditions on the molar mass and root-mean-square radius of the polymers was determined with asymmetrical flow field-flow fractionation coupled to multi-angle light scattering and differential refractive index (AF4-MALS-dRI) detectors under aqueous conditions. The results suggest that reliable and accurate size separation and characterization of amylopectin can be obtained by dissolution of starch granules in an aqueous environment at 140 °C by autoclaving or in DMSO at 100 °C. The results also clearly show an upper limit for heat treatment of starch, above which degradation cannot be avoided. PMID:25925852

  20. Dipole Field Effects on Ion Ejections from a Paul Ion Trap

    NASA Technical Reports Server (NTRS)

    MacAskill, J. A.; Chutjian, A.

    2011-01-01

    Attempts at improving the quality of mass spectra obtained from a Paul trap mass spectrometer prompted an investigation of the effects of additional fields to supplement the primary rf quadrupole trapping field. Reported here are the results of the first in a series of tests that focuses on the application of a single dipole field to augment the trapping and subsequent ejections of ions stored within a Paul trap. Measurements are presented for a fixed quadrupole frequency with varying dipole frequencies. The presence of the dipole field during the quadrupole trapping phase causes ion ejections of single m/z species at discrete dipole frequencies. During the mass analysis phase, the varying dipole frequency produces a complex set of resonant structures that impact ejection time (mass range), as well as mass spectral peak intensity and width

  1. Pulsed magnetic field-electron cyclotron resonance ion source operation

    SciTech Connect

    Muehle, C.; Ratzinger, U.; Joest, G.; Leible, K.; Schennach, S.; Wolf, B.H.

    1996-03-01

    The pulsed magnetic field (PuMa)-electron cyclotron resonance (ECR) ion source uses a pulsed coil to improve the peak current by opening the magnetic bottle along the beam axis. After demonstration of the principle of the pulsed magnetic extraction, the ion source was tested with different gases. We received promising results from helium to krypton. The influence of the current in the pulsed coil on the analyzed ion current was measured. With increased current levels within the pulsed coil not only the pulse height of the PuMa pulse, but the pulse length can also be controlled. By using the pulsed coil the maximum of the charge state distribution can be shifted to higher charge states. {copyright} {ital 1996 American Institute of Physics.}

  2. Density Fluctuation in Asymmetric Nozzle Plumes and Correlation with Far Field Noise

    NASA Technical Reports Server (NTRS)

    Panda, J.; Zaman, K. B. M. Q.

    2001-01-01

    A comparative experimental study of air density fluctuations in the unheated plumes of a circular, 4-tabbed-circular, chevron-circular and 10-lobed rectangular nozzles was performed at a fixed Mach number of 0.95 using a recently developed Rayleigh scattering based technique. Subsequently, the flow density fluctuations are cross-correlated with the far field sound pressure fluctuations to determine sources for acoustics emission. The nearly identical noise spectra from the baseline circular and the chevron nozzles are found to be in agreement with the similarity in spreading, turbulence fluctuations, and flow-sound correlations measured in the plumes. The lobed nozzle produced the least low frequency noise, in agreement with the weakest overall density fluctuations and flow-sound correlation. The tabbed nozzle took an intermediate position in the hierarchy of noise generation, intensity of turbulent fluctuation and flow-sound correlation. Some of the features in the 4-tabbed nozzle are found to be explainable in terms of splitting of the jet in a central large core and 4 side jetlets.

  3. Asymmetric dipolar ring

    DOEpatents

    Prosandeev, Sergey A.; Ponomareva, Inna V.; Kornev, Igor A.; Bellaiche, Laurent M.

    2010-11-16

    A device having a dipolar ring surrounding an interior region that is disposed asymmetrically on the ring. The dipolar ring generates a toroidal moment switchable between at least two stable states by a homogeneous field applied to the dipolar ring in the plane of the ring. The ring may be made of ferroelectric or magnetic material. In the former case, the homogeneous field is an electric field and in the latter case, the homogeneous field is a magnetic field.

  4. Characterization of colloidal phosphorus species in drainage waters from a clay soil using asymmetric flow field-flow fractionation.

    PubMed

    Regelink, Inge C; Koopmans, Gerwin F; van der Salm, Caroline; Weng, Liping; van Riemsdijk, Willem H

    2013-01-01

    Phosphorus transport from agricultural land contributes to eutrophication of surface waters. Pipe drain and trench waters from a grassland field on a heavy clay soil in the Netherlands were sampled before and after manure application. Phosphorus speciation was analyzed by physicochemical P fractionation, and the colloidal P fraction in the dissolved fraction (<0.45 μm) was analyzed by asymmetric flow field-flow fractionation (AF4) coupled to high-resolution inductively coupled plasma-mass spectrometry and ultraviolet diode array detector. When no manure was applied for almost 7 mo, total P (TP) concentrations were low (<21 μmol L), and TP was almost evenly distributed among dissolved reactive P (DRP), dissolved unreactive P (DUP), and particulate P (PP). Total P concentrations increased by a factor of 60 and 4 when rainfall followed shortly after application of cattle slurry or its solid fraction, respectively. Under these conditions, DRP contributed 50% or more to TP. The P speciation within the DUP and PP fractions varied among the different sampling times. Phosphorus associated with dissolved organic matter, probably via cation bridging, comprised a small fraction of DUP at all sampling times. Colloidal P coeluted with clay particles when P application was withheld for almost 7 mo and after application of the solid cattle slurry fraction. At these sampling times, PP correlated well with particulate Fe, Al, and Si, indicating that P is associated with colloidal clay particles. After cattle slurry application, part of DUP was probably present as phospholipids. Physicochemical fractionation combined with AF4 analysis is a promising tool to unravel the speciation of colloidal P in environmental water samples. PMID:23673839

  5. Models for asymmetric hybrid brane

    NASA Astrophysics Data System (ADS)

    Bazeia, D.; Marques, M. A.; Menezes, R.

    2015-10-01

    We deal with relativistic models described by a single real scalar field, searching for topological structures that behave asymmetrically, connecting minima with a distinct profile. We use such features to build a new braneworld scenario, in which the source scalar field contributes to generate asymmetric hybrid brane.

  6. Laser measurement of H{sup -} ions in a field-effect-transistor based radio frequency ion source

    SciTech Connect

    Tanaka, N.; Matsuno, T.; Funaoi, T.; Ando, A.; Tauchi, Y.; Nakano, H.; Tsumori, K.; Takeiri, Y.

    2012-02-15

    Hydrogen negative ion density measurements are required to clarify the characteristics of negative ion production and ion source performance. Both of laser photodetachment and cavity ring down (CRD) measurements have been implemented to a field-effect-transistor based radio-frequency ion source. The density ratio of negative hydrogen ions to electrons was successfully measured by laser photodetachment and effect of magnetic filter field on negative ion density was confirmed. The calculated CRD signal showed that CRD mirrors with >99.990% reflectivity are required and loss of reflectivity due to cesium contamination should be minimized.

  7. Field-free junctions for surface electrode ion traps

    NASA Astrophysics Data System (ADS)

    Jordens, Robert; Schmied, R.; Blain, M. G.; Leibfried, D.; Wineland, D.

    2015-05-01

    Intersections between transport guides in a network of RF ion traps are a key ingredient to many implementations of scalable quantum information processing with trapped ions. Several junction architectures demonstrated so far are limited by varying radial secular frequencies, a reduced trap depth, or a non-vanishing RF field along the transport channel. We report on the design and progress in implementing a configurable microfabricated surface electrode Y-junction that employs switchable RF electrodes. An essentially RF-field-free pseudopotential guide between any two legs of the junction can be established by applying RF potential to a suitable pair of electrodes. The transport channel's height above the electrodes, its depth and radial curvature are constant to within 15%. Supported by IARPA, Sandia, NSA, ONR, and the NIST Quantum Information Program.

  8. Optomechanical Entanglement Between an Ion and an Optical Cavity Field

    NASA Astrophysics Data System (ADS)

    Bhattacherjee, Aranya B.

    2016-04-01

    I study an optomechanical system in which the mechanical motion of a single trapped ion is coupled to a cavity field for the realization of a strongly quantum correlated two-mode system. I show that for large pump intensities the steady state photon number exhibits bistable behaviour. I further analyze the occurrence of normal mode splitting (NMS) due to mixing of the fluctuations of the cavity field and the fluctuations of the ion motion which indicates a coherent energy exchange. I also find that in the parameter regime where NMS exists, the steady state of the system shows continuous variable entanglement. Such a two-mode optomechanical system can be used for the realization of continuous variable quantum information interfaces and networks.

  9. Cubic zero-field splitting of a 6state ion

    NASA Astrophysics Data System (ADS)

    Yu, Wan-Lun

    1989-01-01

    The zero-field splitting of a 6state ion in a cubic field has been studied in detail within the d5 configuration. It is found that the splitting arises mainly from the coupling among the excited states 4T1, 2T2, and 2E and the ground state 6A1 via the spin-orbit interaction. The splitting parameter a can be expressed approximately as F0ζ4+F1ζ5, where F0 and F1 are independent of the spin-orbit coupling constant ζ and have a property ||F0||>>||F1||. Analytical formulas of F0 and F1 are derived by a perturbation calculation with the help of the procedure suggested by Macfarlane. Based on this, a very simple expression of a is obtained semiempirically. Calculations are carried out for the splittings of Fe3+ and Mn2+ ions substituted as impurities in several octahedrally coordinated lattices and for the splitting parameter dependences on pressure for Fe3+ and Mn2+ in MgO crystals. The results are in good agreement with the values observed experimentally, indicating a successful interpretation of the crystal-field theory for the cubic zero-field splittings of 6state ions in octahedral coordinations. The power law a~R-m has been investigated on a theoretical basis. This is indicated to be able to reasonably account for the observed data for a system that has Dq or a values close to each other. In particular, a reasonable value m=12+/-2 is expected for Mn2+ ions having Dq<~B.

  10. Magnetic field measurement techniques with heavy ion beam probes

    SciTech Connect

    Crowley, T.P.

    1988-08-01

    Spatially (0.1 cm/sup 3/) and temporally (1 ..mu..s) resolved magnetic field measurement techniques using a heavy ion beam probe as a test particle source are described. The measurement of both steady-state and time-varying fields is discussed. The plasma flux function can be determined by measuring the toroidal velocity of the beam ion in an axisymmetric device, because the canonical angular momentum of a particle, P/sub phi/ = qpsi+M..nu../sub phi/R, is conserved in an axisymmetric system. Corrections due to nonaxisymmetry can be significant in tokamaks and must be taken into account for the current profile and fluctuation measurements. The requirements and design of a toroidal velocity detector are discussed. The signals expected in experiments using the Texas Experimental Tokamak (TEXT) heavy ion beam probe with a velocity detector have been calculated, and they are at least two orders of magnitude higher than the amplifier noise for dc measurements of poloidal and ergodic magnetic limiter fields and for sawtooth and MHD oscillations. Low-level turbulence is expected to produce signals below the noise level.

  11. Galactic heavy-ion shielding using electrostatic fields

    NASA Technical Reports Server (NTRS)

    Townsend, L. W.

    1984-01-01

    The shielding of spacecraft against galactic heavy ions, particularly high-energy Fe(56) nuclei, by electrostatic fields is analyzed for an arrangement of spherical concentric shells. Vacuum breakdown considerations are found to limit the minimum radii of the spheres to over 100 m. This limitation makes it impractical to use the fields for shielding small spacecraft. The voltages necessary to repel these Fe(56) nuclei exceed present electrostatic generating capabilities by over 2 orders of magnitude and render the concept useless as an alternative to traditional bulk-material shielding methods.

  12. Synthetic gauge fields for vibrational excitations of trapped ions.

    PubMed

    Bermudez, Alejandro; Schaetz, Tobias; Porras, Diego

    2011-10-01

    The vibrations of a collection of ions in a microtrap array can be described in terms of tunneling phonons. We show that the vibrational couplings may be tailored by using a gradient of the trap frequencies together with a periodic driving of the trapping potentials. These ingredients allow us to induce effective gauge fields on the vibrational excitations, such that phonons mimic the behavior of charged particles in a magnetic field. In particular, microtrap arrays are well suited to realize a quantum simulator of the famous Aharonov-Bohm effect and observe the paradigmatic edge states typical from quantum-Hall samples and topological insulators. PMID:22107274

  13. Ion-Sensitive Field-Effect Transistor for Biological Sensing

    PubMed Central

    Lee, Chang-Soo; Kim, Sang Kyu; Kim, Moonil

    2009-01-01

    In recent years there has been great progress in applying FET-type biosensors for highly sensitive biological detection. Among them, the ISFET (ion-sensitive field-effect transistor) is one of the most intriguing approaches in electrical biosensing technology. Here, we review some of the main advances in this field over the past few years, explore its application prospects, and discuss the main issues, approaches, and challenges, with the aim of stimulating a broader interest in developing ISFET-based biosensors and extending their applications for reliable and sensitive analysis of various biomolecules such as DNA, proteins, enzymes, and cells. PMID:22423205

  14. Characterization of Silver Nanoparticles under Environmentally Relevant Conditions Using Asymmetrical Flow Field-Flow Fractionation (AF4)

    PubMed Central

    Jang, Min-Hee; Lee, Seungho; Hwang, Yu Sik

    2015-01-01

    The development of methods to monitor manufactured nanomaterials in the environment is one of the crucial areas for the assessment of their risk. More specifically, particle size analysis is a key element, because many properties of nanomaterial are size dependent. The sizing of nanomaterials in real environments is challenging due to their heterogeneity and reactivity with other environmental components. In this study, the fractionation and characterization of a mixture of polyvinylpyrrolidone-coated silver nanoparticles (PVP-AgNPs) of three different sizes were investigated using asymmetrical flow field-flow fractionation (AF4) coupled with UV-Vis spectrophotometry. In particular, the effects of electrolyte composition and natural organic matter (NOM) on the particle size and stability were evaluated. The fractogram peaks (i.e., stability) of three different AgNPs decreased in the presence of both 10 mM NaCl and 10mM CaCl2, while increased with increasing concentration of humic acid (HA). In addition, the hydrodynamic diameters of AgNPs in both electrolytes slightly increased with an increase of HA concentration, suggesting the adsorption (coating) of HA onto the particle surface. It is also interesting to note that an increase in the particle size depended on the types of electrolyte, which could be explained by the conformational characteristics of the adsorbed HA layers. Consistent these results, AgNPs suspended in lake water containing relatively high concentration of organic carbon (TOC) showed higher particle stability and larger particle size (i.e., by approximately 4nm) than those in river water. In conclusion, the application of AF4 coupled with highly sensitive detectors could be a powerful method to characterize nanoparticles in natural waters. PMID:26575993

  15. Characterization of Silver Nanoparticles under Environmentally Relevant Conditions Using Asymmetrical Flow Field-Flow Fractionation (AF4).

    PubMed

    Jang, Min-Hee; Lee, Seungho; Hwang, Yu Sik

    2015-01-01

    The development of methods to monitor manufactured nanomaterials in the environment is one of the crucial areas for the assessment of their risk. More specifically, particle size analysis is a key element, because many properties of nanomaterial are size dependent. The sizing of nanomaterials in real environments is challenging due to their heterogeneity and reactivity with other environmental components. In this study, the fractionation and characterization of a mixture of polyvinylpyrrolidone-coated silver nanoparticles (PVP-AgNPs) of three different sizes were investigated using asymmetrical flow field-flow fractionation (AF4) coupled with UV-Vis spectrophotometry. In particular, the effects of electrolyte composition and natural organic matter (NOM) on the particle size and stability were evaluated. The fractogram peaks (i.e., stability) of three different AgNPs decreased in the presence of both 10 mM NaCl and 10 mM CaCl2, while increased with increasing concentration of humic acid (HA). In addition, the hydrodynamic diameters of AgNPs in both electrolytes slightly increased with an increase of HA concentration, suggesting the adsorption (coating) of HA onto the particle surface. It is also interesting to note that an increase in the particle size depended on the types of electrolyte, which could be explained by the conformational characteristics of the adsorbed HA layers. Consistent these results, AgNPs suspended in lake water containing relatively high concentration of organic carbon (TOC) showed higher particle stability and larger particle size (i.e., by approximately 4 nm) than those in river water. In conclusion, the application of AF4 coupled with highly sensitive detectors could be a powerful method to characterize nanoparticles in natural waters. PMID:26575993

  16. Fractionating power and outlet stream polydispersity in asymmetrical flow field-flow fractionation. Part I: isocratic operation.

    PubMed

    Williams, P Stephen

    2016-05-01

    Asymmetrical flow field-flow fractionation (As-FlFFF) has become the most commonly used of the field-flow fractionation techniques. However, because of the interdependence of the channel flow and the cross flow through the accumulation wall, it is the most difficult of the techniques to optimize, particularly for programmed cross flow operation. For the analysis of polydisperse samples, the optimization should ideally be guided by the predicted fractionating power. Many experimentalists, however, neglect fractionating power and rely on light scattering detection simply to confirm apparent selectivity across the breadth of the eluted peak. The size information returned by the light scattering software is assumed to dispense with any reliance on theory to predict retention, and any departure of theoretical predictions from experimental observations is therefore considered of no importance. Separation depends on efficiency as well as selectivity, however, and efficiency can be a strong function of retention. The fractionation of a polydisperse sample by field-flow fractionation never provides a perfectly separated series of monodisperse fractions at the channel outlet. The outlet stream has some residual polydispersity, and it will be shown in this manuscript that the residual polydispersity is inversely related to the fractionating power. Due to the strong dependence of light scattering intensity and its angular distribution on the size of the scattering species, the outlet polydispersity must be minimized if reliable size data are to be obtained from the light scattering detector signal. It is shown that light scattering detection should be used with careful control of fractionating power to obtain optimized analysis of polydisperse samples. Part I is concerned with isocratic operation of As-FlFFF, and part II with programmed operation. Graphical abstract The dash-dotted blue curve describes an assumed log-normal sample molecular weight distribution (right axis

  17. Behavior of molecules and molecular ions near a field emitter

    NASA Astrophysics Data System (ADS)

    Gault, Baptiste; Saxey, David W.; Ashton, Michael W.; Sinnott, Susan B.; Chiaramonti, Ann N.; Moody, Michael P.; Schreiber, Daniel K.

    2016-03-01

    The cold emission of particles from surfaces under intense electric fields is a process which underpins a variety of applications including atom probe tomography (APT), an analytical microscopy technique with near-atomic spatial resolution. Increasingly relying on fast laser pulsing to trigger the emission, APT experiments often incorporate the detection of molecular ions emitted from the specimen, in particular from covalently or ionically bonded materials. Notably, it has been proposed that neutral molecules can also be emitted during this process. However, this remains a contentious issue. To investigate the validity of this hypothesis, a careful review of the literature is combined with the development of new methods to treat experimental APT data, the modeling of ion trajectories, and the application of density-functional theory simulations to derive molecular ion energetics. It is shown that the direct thermal emission of neutral molecules is extremely unlikely. However, neutrals can still be formed in the course of an APT experiment by dissociation of metastable molecular ions. This work is a partial contribution of the US Government and therefore is not subject to copyright in the United States.

  18. Electrostatic ion-cyclotron waves in a nonuniform magnetic field

    NASA Technical Reports Server (NTRS)

    Cartier, S. L.; Dangelo, N.; Merlino, R. L.

    1985-01-01

    The properties of electrostatic ion-cyclotron waves excited in a single-ended cesium Q machine with a nonuniform magnetic field are described. The electrostatic ion-cyclotron waves are generated in the usual manner by drawing an electron current to a small exciter disk immersed in the plasma column. The parallel and perpendicular (to B) wavelengths and phase velocities are determined by mapping out two-dimensional wave phase contours. The wave frequency f depends on the location of the exciter disk in the nonuniform magnetic field, and propagating waves are only observed in the region where f is approximately greater than fci, where fci is the local ion-cyclotron frequency. The parallel phase velocity is in the direction of the electron drift. From measurements of the plasma properties along the axis, it is inferred that the electron drift velocity is not uniform along the entire current channel. The evidence suggests that the waves begin being excited at that axial position where the critical drift velocity is first exceeded, consistent with a current-driven excitation mechanism.

  19. Novel symmetric diimine-Schiff bases and asymmetric triimine-Schiff bases as chemosensors for the detection of various metal ions

    NASA Astrophysics Data System (ADS)

    Özdemir, Özlem

    2016-12-01

    In this study, two symmetric diimine-Schiff bases (D1, D2) containing nitro group were synthesized by a simple one-pot condensation of 4-nitro-o-phenylenediamine with substituted-salicylaldehyde (5-Cl, 5-CH3) in 1:2 ratio. After the selective reduction of nitro group to amino group by using sodium dithionite and forming the new imine bond by adding substituted-salicylaldehyde or 2-hydroxy-1-naphthaldehyde, four asymmetric triimine-Schiff bases (T1s, T1n, T2s, and T2n) were obtained. Results of the newly synthesized compounds established by elemental analyses, FT-IR, UV-vis, 2D NMR (HMQC), 1H-NMR, 13C-NMR and TOF-mass spectroscopic experiments were consistent with their chemical structures. The tautomeric equilibria were also studied. The sensor properties of all Schiff bases were examined upon addition of the metal ions, such as Cr3+, Fe2+, Fe3+, Co2+, Ni2+, Cu2+, Zn2+, and Pb2+. The interactions between receptors and ions are easily monitored by UV-vis method. The receptor D2 showed colour changes from yellow to intense deep orange colour for Cu2+, a orange colour for Co2+ and dark yellow colour for other ions. Although metal ions caused no change in colour of T2s, the main absorption band of receptor shifted from 351 nm to 343-372 nm T2n underwent colour changes from yellow to light yellow on gradual addition of Fe3+.

  20. Field Emitter Arrays and Displays Produced by Ion Tracking Lithography

    SciTech Connect

    Felter, T E; Musket, R G; Bernhardt, A F

    2004-12-28

    When ions of sufficient electronic energy loss traverse a dielectric film or foil, they alter the chemical bonding along their nominally straight path within the material. A suitable etchant can quickly dissolve these so-called latent tracks leaving holes of small diameter ({approx}10nm) but long length - several microns. Continuing the etching process gradually increases the diameter reproducibly and uniformly. The trackable medium can be applied as a uniform film onto large substrates. The small, monodisperse holes produced by this track etching can be used in conjunction with additional thin film processing to create functional structures attached to the substrate. For example, Lawrence Livermore National Laboratory and Candescent Technologies Corporation (CTC) co-developed a process to make arrays of gated field emitters ({approx}100nm diameter electron guns) for CTC's ThinCRT{trademark} displays, which have been fabricated to diagonal dimensions > 13. Additional technological applications of ion tracking lithography will be briefly covered.

  1. A critical evaluation of an asymmetrical flow field-flow fractionation system for colloidal size characterization of natural organic matter.

    PubMed

    Zhou, Zhengzhen; Guo, Laodong

    2015-06-19

    Colloidal retention characteristics, recovery and size distribution of model macromolecules and natural dissolved organic matter (DOM) were systematically examined using an asymmetrical flow field-flow fractionation (AFlFFF) system under various membrane size cutoffs and carrier solutions. Polystyrene sulfonate (PSS) standards with known molecular weights (MW) were used to determine their permeation and recovery rates by membranes with different nominal MW cutoffs (NMWCO) within the AFlFFF system. Based on a ≥90% recovery rate for PSS standards by the AFlFFF system, the actual NMWCOs were determined to be 1.9 kDa for the 0.3 kDa membrane, 2.7 kDa for the 1 kDa membrane, and 33 kDa for the 10 kDa membrane, respectively. After membrane calibration, natural DOM samples were analyzed with the AFlFFF system to determine their colloidal size distribution and the influence from membrane NMWCOs and carrier solutions. Size partitioning of DOM samples showed a predominant colloidal size fraction in the <5 nm or <10 kDa size range, consistent with the size characteristics of humic substances as the main terrestrial DOM component. Recovery of DOM by the AFlFFF system, as determined by UV-absorbance at 254 nm, decreased significantly with increasing membrane NMWCO, from 45% by the 0.3 kDa membrane to 2-3% by the 10 kDa membrane. Since natural DOM is mostly composed of lower MW substances (<10 kDa) and the actual membrane cutoffs are normally larger than their manufacturer ratings, a 0.3 kDa membrane (with an actual NMWCO of 1.9 kDa) is highly recommended for colloidal size characterization of natural DOM. Among the three carrier solutions, borate buffer seemed to provide the highest recovery and optimal separation of DOM. Rigorous calibration with macromolecular standards and optimization of system conditions are a prerequisite for quantifying colloidal size distribution using the flow field-flow fractionation technique. In addition, the coupling of AFlFFF with fluorescence

  2. Solenoidal Fields for Ion Beam Transport and Focusing

    SciTech Connect

    Lee, Edward P.; Leitner, Matthaeus

    2007-11-01

    In this report we calculate time-independent fields of solenoidal magnets that are suitable for ion beam transport and focusing. There are many excellent Electricity and Magnetism textbooks that present the formalism for magnetic field calculations and apply it to simple geometries [1-1], but they do not include enough relevant detail to be used for designing a charged particle transport system. This requires accurate estimates of fringe field aberrations, misaligned and tilted fields, peak fields in wire coils and iron, external fields, and more. Specialized books on magnet design, technology, and numerical computations [1-2] provide such information, and some of that is presented here. The AIP Conference Proceedings of the US Particle Accelerator Schools [1-3] contain extensive discussions of design and technology of magnets for ion beams - except for solenoids. This lack may be due to the fact that solenoids have been used primarily to transport and focus particles of relatively low momenta, e.g. electrons of less than 50 MeV and protons or H- of less than 1.0 MeV, although this situation may be changing with the commercial availability of superconducting solenoids with up to 20T bore field [1-4]. Internal reports from federal laboratories and industry treat solenoid design in detail for specific applications. The present report is intended to be a resource for the design of ion beam drivers for Inertial Fusion Energy [1-5] and Warm Dense Matter experiments [1-6], although it should also be useful for a broader range of applications. The field produced by specified currents and material magnetization can always be evaluated by solving Maxwell's equations numerically, but it is also desirable to have reasonably accurate, simple formulas for conceptual system design and fast-running beam dynamics codes, as well as for general understanding. Most of this report is devoted to such formulas, but an introduction to the Tosca{copyright} code [1-7] and some numerical

  3. Pencil lead tips: A field ion and field electron emission microscopic study

    NASA Astrophysics Data System (ADS)

    Khairnar, Rajendra S.; Dharmadhikari, C. V.; Joag, Dilip S.

    1989-06-01

    Pencil lead tips composed of graphite flakes were subjected to field ion and field emission microscopic investigations. The ion micrographs showed elongated images of ledge atoms of the graphite flakes due to uneven magnification over the layers of the flake. The gross features of the field evaporated tip surface were observed by scanning electron microscopy. The field emission pattern showed emitting lobes which displayed intensity fluctuations consisting of a combination of emission spots turning on and off randomly and a localized flicker of individual spots. These effects gave rise to noise in the emission current involving isolated spikes of rapid rise time and trains of digital pulses of constant height. The variation of noise with residual gas pressure, emission current, and temperature has also been investigated. The results are discussed in view of the microtopography of the pencil lead tips and the nature of the emitting sites on the surface.

  4. Electromagnetic field evolution in relativistic heavy-ion collisions

    SciTech Connect

    Voronyuk, V.; Toneev, V. D.; Cassing, W.; Bratkovskaya, E. L.; Konchakovski, V. P.; Voloshin, S. A.

    2011-05-15

    The hadron string dynamics (HSD) model is generalized to include the creation and evolution of retarded electromagnetic fields as well as the influence of the magnetic and electric fields on the quasiparticle propagation. The time-space structure of the fields is analyzed in detail for noncentral Au + Au collisions at {radical}(s{sub NN})=200 GeV. It is shown that the created magnetic field is highly inhomogeneous, but in the central region of the overlapping nuclei it changes relatively weakly in the transverse direction. For the impact parameter b=10 fm, the maximal magnetic field - perpendicularly to the reaction plane - is obtained of order eB{sub y}/m{sub {pi}}{sup 2}{approx}5 for a very short time {approx}0.2 fm/c, which roughly corresponds to the time of a maximal overlap of the colliding nuclei. We find that at any time, the location of the maximum in the eB{sub y} distribution correlates with that of the energy density of the created particles. In contrast, the electric field distribution, being also highly inhomogeneous, has a minimum in the center of the overlap region. Furthermore, the field characteristics are presented as a function of the collision energy and the centrality of the collisions. To explore the effect of the back reaction of the fields on hadronic observables, a comparison of HSD results with and without fields is exemplified. Our actual calculations show no noticeable influence of the electromagnetic fields--created in heavy-ion collisions--on the effect of the electric charge separation with respect to the reaction plane.

  5. Experimental studies on ion acceleration and stream line detachment in a diverging magnetic field

    PubMed Central

    Terasaka, K.; Yoshimura, S.; Ogiwara, K.; Aramaki, M.; Tanaka, M. Y.

    2010-01-01

    The flow structure of ions in a diverging magnetic field has been experimentally studied in an electron cyclotron resonance plasma. The flow velocity field of ions has been measured with directional Langmuir probes calibrated with the laser induced fluorescence spectroscopy. For low ion-temperature plasmas, it is concluded that the ion acceleration due to the axial electric field is important compared with that of gas dynamic effect. It has also been found that the detachment of ion stream line from the magnetic field line takes place when the parameter |fciLB∕Vi| becomes order unity, where fci, LB, and Vi are the ion cyclotron frequency, the characteristic scale length of magnetic field inhomogeneity, and the ion flow velocity, respectively. In the detachment region, a radial electric field is generated in the plasma and the ions move straight with the E×B rotation driven by the radial electric field. PMID:20838424

  6. Simulation of Ions Confined by Quadrupole Electric Fields

    NASA Astrophysics Data System (ADS)

    Cummings, Michael David

    Computer simulations are routinely used to develop physical insight into ionic systems confined by static and time-varying quadrupole electric fields. However, after nearly 30 years of numerical exploration, three questions remain: which numerical techniques produce accurate simulations for the least computational expense? How can thermal equilibrium initial conditions be generated? How should temperature be calculated? Trapped ion simulations generally employ molecular dynamics techniques, where ion trajectories are numerically calculated at discrete points in time. While many numerical methods have been applied to these systems, it is unclear which technique is fastest or what time-step is required. In this work, the computational speed of and time-step for 11 commonly used techniques are assessed through analysis of four numerical error components. The most rapid method and required step-size depend strongly on the system parameters, with any one of the Beeman, Gear6, 5th-order Adams-Bashforth-Moulton, or 4th-order Runge-Kutta algorithms proving most appropriate. The 11 algorithms are then applied to a realistic multi-ion system and verify that the four tests accurately predict the required step size. When equilibrium properties are desired, simulations should commence from initial conditions that conform closely to thermal equilibrium; however little has been published on initial condition generation and assessment for the multi-ion system. A method is presented for generating thermal equilibrium via laser cooling and recoil heating, a ramp-down stage, where the heating and cooling are gradually reduced, and an equilibration phase where the ensemble is evolved under only the trapping forces. Furthermore, it is demonstrated that thermal equilibrium can be assessed using well-known tests of distribution normality. When time-varying fields are present, temperature calculation becomes difficult, as the ion motion contains both thermal and nonthermal components. The

  7. Asymmetric magnetoimpedance effect in CoFeSiB amorphous ribbons by combination of field and current annealing for sensor applications

    NASA Astrophysics Data System (ADS)

    Hajiali, Mohammadreza; Mohseni, S. Majid; Roozmeh, S. Ehsan; Moradi, Mehrdad

    2016-08-01

    The roles of applied magnetic field during the current annealing of Co68.15Fe4.35Si12.5B15 soft magnetic amorphous ribbons are studied. Samples heat treated by Joule heating effect in open air and simultaneously in the present of longitudinal external magnetic field showed asymmetric magnetoimpedance (AMI) behavior. The AMI profile can be related to the exchange bias interaction between the soft magnetic amorphous material and a harder magnetic crystalline phase formed on the surface of the ribbon. This effect stems from thermal effect, the transverse Oe field generated from the annealing current which is thickness dependent and the longitudinal external field. The single peak AMI with the field sensitivity of 101%/Oe for DC annealing current is achieved. Our results could address a simple way to achieve the AMI response toward developing high sensitive magnetic field sensors.

  8. Ground-state zero-field splitting for the Fe3+ ion in a cubic field

    NASA Astrophysics Data System (ADS)

    Xiao-Yu, Kuang; Zhong-Hou, Chen

    1987-07-01

    At present the parameter a of the Fe3+ ion in a crystal has still not been determined. In this paper we discuss this problem by diagonalizing the complete matrices for a ligand-field spin-orbit-coupling perturbation. The results obtained are in good agreement with experimental findings. Furthermore, possible resonances for the difference between our results and previous ones are given.

  9. Direct analysis of un-derivatized asymmetric dimethylarginine (ADMA) and L-arginine from plasma using mixed-mode ion-exchange liquid chromatography-tandem mass spectrometry.

    PubMed

    Bishop, Michael J; Crow, Brian; Norton, Dean; Paliakov, Ekaterina; George, Joe; Bralley, J A

    2007-11-15

    A high-throughput analytical method was developed for the measurement of asymmetric dimethylarginine (ADMA) and L-arginine (ARG) from plasma using LC/MS/MS. The sample preparation was simple and only required microfiltration prior to analysis. ADMA and ARG were assayed using mixed-mode ion-exchange chromatography which allowed for the retention of the un-derivatized compounds. The need for chromatographic separation of ADMA from symmetric dimethylarginine (SDMA) was avoided by using an ADMA specific product ion. As a result, the analytical method only required a total run time of 2 min. The method was validated by linearity, with r2>or=0.995 for both compounds, and accuracy, with no more than 7% deviation from the theoretical value. The estimated limit of detection and limit of quantification were suitable for clinical evaluations. The mean values of plasma ADMA and ARG taken from healthy volunteers (n=15) were 0.66+/-0.12 and 87+/-35 microM, respectively; the mean molar ratio of ARG to ADMA was 142+/-81. PMID:17931984

  10. Ion pump using cylindrically symmetric spindle magnetic field

    NASA Astrophysics Data System (ADS)

    Rashid, M. H.

    2012-11-01

    For all accelerators and many research and industries, excellent vacuum conditions are required and the highest possible pumping rates are necessary. For most applications the standard ion sputtering pump (ISP) meets these requirements and is optimal for financial point of view also. The physical principle of the ISP is well known and many companies manufacture variety of ISP. Most of them use dipole magnetic field produced by permanent magnet and electric dipole field between the electrodes in which tenuous plasma is created because of interaction of between the relatively fast electrons slow residual gas atoms. Performance of an ISP depends basically on the electron cloud density in between the titanium electrodes but in the available present configurations no consideration has been given to electron confinement which needs a mirror magnetic field. If this is incorporated it will make a robust ISP surely; furthermore, the requirement of constant feeding of high voltage to electrodes for supplying sufficient number of electrons will be reduced too. A study has been performed to create sufficient rotationally symmetric spindle magnetic field (SMF) with inherent presence of magnetic mirror effect to electron motion to confine them for longer time for enhancing the density of electron cloud between the electrodes. It will lessen the electric power feeding the electrodes and lengthen their life-time. Construction of further compact and robust ISP is envisaged herein. The field simulation using the commercially available permanent magnet together with simulation of electron motion in such field will be presented and discussed in the paper.

  11. Magnetized retarding field energy analyzer measuring the particle flux and ion energy distribution of both positive and negative ions

    SciTech Connect

    Rafalskyi, Dmytro; Aanesland, Ane; Dudin, Stanislav

    2015-05-15

    This paper presents the development of a magnetized retarding field energy analyzer (MRFEA) used for positive and negative ion analysis. The two-stage analyzer combines a magnetic electron barrier and an electrostatic ion energy barrier allowing both positive and negative ions to be analyzed without the influence of electrons (co-extracted or created downstream). An optimal design of the MRFEA for ion-ion beams has been achieved by a comparative study of three different MRFEA configurations, and from this, scaling laws of an optimal magnetic field strength and topology have been deduced. The optimal design consists of a uniform magnetic field barrier created in a rectangular channel and an electrostatic barrier consisting of a single grid and a collector placed behind the magnetic field. The magnetic barrier alone provides an electron suppression ratio inside the analyzer of up to 6000, while keeping the ion energy resolution below 5 eV. The effective ion transparency combining the magnetic and electrostatic sections of the MRFEA is measured as a function of the ion energy. It is found that the ion transparency of the magnetic barrier increases almost linearly with increasing ion energy in the low-energy range (below 200 eV) and saturates at high ion energies. The ion transparency of the electrostatic section is almost constant and close to the optical transparency of the entrance grid. We show here that the MRFEA can provide both accurate ion flux and ion energy distribution measurements in various experimental setups with ion beams or plasmas run at low pressure and with ion energies above 10 eV.

  12. Plasma physics on auroral field lines - The formation of ion conic distributions

    NASA Technical Reports Server (NTRS)

    Ashour-Abdalla, M.; Okuda, H.

    1983-01-01

    The formation of the conical distribution function and the acceleration of ions on aurora field lines are considered. Ion cyclotron waves were assumed to be excited by drifting electrons associated with the return current in the auroral zone. A theoretical analysis of ion cyclotron waves is given, and a simulation model is described. Simulation results are presented. The heating of ions and the evolution of ion cyclotron waves on auroral field lines and in the magnetosphere are discussed.

  13. Investigation of intermittent enhancement of ion emission from a tungsten surface using the field-ion microscope.

    NASA Technical Reports Server (NTRS)

    Weizer, V. G.

    1971-01-01

    The blinking effect, or the intermittent enhancement of ion emission, which is observed when a few parts per million neon are added to the imaging gas in a helium-tungsten field-ion microscope, has been investigated. Measurements of the characteristic quantities involved - i.e., blinking rate, voltage limits, etc. - and their variation with temperature, field, and gas pressure, are described.

  14. Photomask repair technology by using gas field ion source

    NASA Astrophysics Data System (ADS)

    Aramaki, Fumio; Kozakai, Tomokazu; Matsuda, Osamu; Takaoka, Osamu; Sugiyama, Yasuhiko; Oba, Hiroshi; Aita, Kazuo; Yasaka, Anto

    2012-06-01

    Recently, most of defects on high-end masks are repaired with electron beam (EB). The minimum repairable dimension of the current state-of-the-art repair systems is about 20-30 nm, but that dimension is not small enough to repair the next generation masks. Meanwhile, new molybdenum silicide (MoSi) films with high cleaning durability are going to be provided for an alternative technology, but the etching selectivity between new MoSi and quartz under EB repair process is not high enough to control etching depth. We developed the focused ion beam (FIB) technology that uses light ions emitted from a gas field ion source (GFIS). In this study, the performance of our developed GFIS mask repair system was investigated by using new MoSi (HOYA-A6L2). Specifically, the minimum repairable dimension, image resolution, imaging damage, etching material selectivity and through-focus behavior on AIMS were evaluated. The minimum repairable dimension was only 11 nm that is nearly half of that with EB. That result suggests that GFIS technology is a promising candidate for repairing the next generation masks. Meanwhile, the etching selectivity between A6L2 and quartz was 6:1. Additionally, the other evaluations on AIMS showed good results. Those results demonstrate that GFIS technology is a reliable solution of repairing new MoSi masks with high cleaning durability.

  15. Observation of synchronized atomic motions in the field ion microscope.

    PubMed

    Rahman, Fhm F; Notte, John A; Livengood, Richard H; Tan, Shida

    2013-03-01

    For over half a century, the field ion microscope (FIM) has been used to visualize atomic structures at the apex of a sharpened needle by way of the ion beams which are created at the most protruding atoms. In this paper we used a conventional FIM to study the emission characteristics of the neon ion beams produced within the FIM. The neon emission pattern is observed to be relatively short lived and subject to temporal and angular fluctuations. The nature of these fluctuations is complex, often with different parts of the emission pattern changing in a synchronized fashion over timescales spanning from milliseconds to a few tens of seconds. In this paper, we characterize the observed instability of the neon emission. We also offer a simple model of adsorbed atom mobility that explains much of these observations. And finally, we present a method by which the stability can be greatly improved so that the produced neon beam can be used effectively for nanomachining applications. PMID:23376401

  16. Asymmetric Flow-Field Flow Fractionation Hyphenated ICP-MS as an Alternative to Cloud Point Extraction for Quantification of Silver Nanoparticles and Silver Speciation: Application for Nanoparticles with a Protein Corona.

    PubMed

    Mudalige, Thilak K; Qu, Haiou; Linder, Sean W

    2015-07-21

    Production and application of nanoparticles in consumer products is at an all-time high due to the emerging field of nanotechnology. Direct detection and quantification of trace levels of nanoparticles within consumer products is very challenging and problematic. Although multiple methodologies are available for this purpose, each method has its own set of limitations. Herein, we developed an analytical platform consisting of asymmetric flow-field flow fractionation (AF4) coupled with inductively coupled plasma mass spectroscopy (ICP-MS) for the speciation and quantification of silver ions and silver nanoparticles at the ng/kg level (ppt). AF4 is utilized to concentrate the nanoparticles, and ICP-MS acts as the detector. The protein corona that forms upon exposure of nanoparticles to bovine serum albumin was utilized as a nanoparticle stabilization and AF4 recovery enhancement mechanism. Speciation of silver ions and nanoparticles was achieved with the assistance of penicillamine as a complexation ligand. The effect of nanoparticle size, surface coating, and ionization state toward the detection and quantification of the developed methodology was evaluated. The detection limit was found to be 4 ng/kg with the application of a 5 mL sample loop. Further application of this developed methodology on environmentally relevant samples was demonstrated by the analysis of Arkansas River water spiked with silver nanoparticles and nanoparticle spiked into humic acid solution (50 mg/L) at an environmentally relevant level. PMID:26095720

  17. Characterizing changes in levan physicochemical properties in different pH environments using asymmetric flow field-flow fractionation.

    PubMed

    Runyon, J Ray; Nilsson, Lars; Ulmius, Matilda; Castro, Alejandra; Ionescu, Ruxandra; Andersson, Claes; Schmidt, Christoph

    2014-02-01

    The purpose of this study was to assess the stability of the polyfructan levan under different pH solution conditions by monitoring changes in the levan physicochemical properties, such as molar mass (M), root mean square radius (r(rms)), hydrodynamic radius (r(h)), structure factor (r(rms)/r(h)), and aggregation state with respect to solution pH and hydrolysis time. A commercial levan produced from Z. Mobilis was characterized using asymmetric flow field-flow fractionation (AF4) in combination with online multiangle light scattering (MALS) and differential refractive index (dRI) detection. Under neutral pH solution conditions the levan was found to have a M ranging from 10(5) to 5 × 10(7) g/mol, a r(rms) ranging from ~25 to 100 nm and a r(h) from ~3 to 151 nm. Two populations were observed in the sample. One population with a M less than 106 g/mol which represented ~60 % of the sample and a second population with an ultrahigh M up to 5 × 10(7) g/mol, which comprised ~40 % of the sample. The measured r(rms)/r(h) structure factor decreased from 1.8 to 0.65 across the AF4 fractogram indicating that early eluting low M levan species had a random coil configuration and late eluting high M species had more homogeneous spherical structures. The measured apparent density values decreased from 80 to 10 kg/m(3) across the elution profile and suggest that the observed second population also contains aggregates. The stability of levan in different pH conditions ranging from 1.3 to 8.5 was assessed by tracking changes in the average M and r(h), and monitoring the formation of fructose over 1 week. The onset of levan acid hydrolysis was observed to occur sooner at lower pH conditions and no hydrolysis was observed for pH 5.5 and higher. PMID:24121433

  18. Syntheses, phase behavior, supramolecular chirality, and field-effect carrier mobility of asymmetrically end-capped mesogenic oligothiophenes.

    PubMed

    Meng, Qingwei; Sun, Xiao-Hua; Lu, Zhengyu; Xia, Ping-Fang; Shi, Zehua; Chen, Dongzhong; Wong, Man Shing; Wakim, Salem; Lu, Jianping; Baribeau, Jean-Marc; Tao, Ye

    2009-01-01

    A novel series of asymmetrically end-capped mesogenic oligothiophenes, with various oligothiophene core lengths, alkoxy tail lengths, and molecular polarities through introducing alkylsulfanyl or alkylsulfonyl functionalities as the terminal group, have been synthesized by palladium-catalyzed Suzuki cross-coupling and Kumada cross-coupling reactions as key steps. For the single end-capped oligothiophenes, C(m)O-Ar-OT(4)-H in which m=10, 12, 14, 16, and 18, all of these oligomers exhibited a broad temperature range of highly ordered smectic E and enantiotropic nematic phases, apart from the one with the longest octadecyloxy tail. For the double end-capped series C(10)O-Ar-OT(n)-R, R=Ph-SC(6) or Ph-SO(2)C(6) in which n=1, 2, 3, and 4, oligomers with more than one thiophene ring exhibited smectic A and smectic C phases, various crystal polymorphs and/or unusual low-temperature condensed phases. In the nonpolar, alkylsulfanylphenyl-substituted oligothiophene series, both the crystal/solid melting point and mesogenic clear point increased significantly with an increasing oligothiophene conjugation length. In the polar, alkylsulfonylphenyl-substituted oligothiophene series, all the oligomers showed increased melting points, but decreased mesogenic temperature intervals than those of their corresponding alkylsulfanyl counterparts. Remarkably, two different helical structures showing distinct striated textures or striped patterns were observed with a pitch of several to tens of micrometers under a polarized optical microscope upon cooling from their preceding fluidic smectic phases. The unusual twisted smectic layer structures in the thin solid films exhibiting distinct supramolecular chirality of both handednesses, revealed by circular dichroism measurements, were further confirmed by XRD analyses characterized by a sharp layer reflection together with its higher orders and diffuse wide-angle scatterings. In addition, initial studies showed that the highly ordered smectic

  19. Ion distribution function in a plasma with uniform electric field

    SciTech Connect

    Lampe, M.; Joyce, G.; Roecker, T. B.; Zhdanov, S. K.; Ivlev, A. V.; Morfill, G. E.

    2012-11-15

    For a homogeneous partially ionized plasma subject to a uniform electric field E, several methods and models are used to calculate the distribution function f(v) for ions subject to charge-exchange collisions. The exact solution for f(v), based on the energy-dependent cross section for Ar, is obtained by Monte Carlo (MC) simulation. This is compared to the MC results for f(v), based on either a constant cross section {sigma} or a constant collision frequency {nu}. The constant-{sigma} model is found to accurately represent f(v) for any value of E, whereas the constant-{nu} results are qualitatively incorrect for large fields. Under the constant-{sigma} assumption, a simple, easily solvable ordinary differential equation is obtained which reproduces the MC results with good accuracy.

  20. Transverse Flow of Gluon Fields in Heavy Ion Collision

    NASA Astrophysics Data System (ADS)

    Chen, Guangyao; Fries, Rainer J.

    2014-09-01

    We describe the dynamics of initial gluon fields in heavy ion collision using a formal recursive solution of the Yang Mills equations and solving for the energy momentum tensor analytically in a boost-invariant setup. We generalize the original McLerran-Venugopalan (MV) model in order to allow for realistic nuclear profiles. This leads to a transverse flow of gluon fields. This flow pattern is inherited by the quark gluon plasma fluid after thermalization. Its most interesting aspect is a rapidity-odd flow component. We show that this rapidity-odd flow does not break boost invariance and that it emerges naturally from the Yang Mills equations. It leads to directed flow of particles and introduces angular momentum to the system.

  1. Fragmentation of negative ions in a strong laser field

    NASA Astrophysics Data System (ADS)

    Berry, Ben; Jochim, Bethany; Severt, T.; Feizollah, Peyman; Rajput, Jyoti; Hayes, D.; Carnes, K. D.; Esry, B. D.; Ben-Itzhak, I.

    2016-05-01

    The fragmentation of negative ions in a strong laser field can provide a testing ground for a variety of unique phenomena. For example, anions with a loosely bound electron allow for the study of rescattering phenomena at lower laser intensities than for neutral targets. We study the behavior of keV anion beams in an ultrafast, intense laser field. The use of a fast-beam target facilitates the measurement of neutral fragments. This capability allows us to explore laser-induced dynamics in both ionic and neutral charge states. Using a coincidence 3D momentum imaging technique, we obtain the full 3D momentum of all nuclear fragments. In this preliminary work, we study atomic (H-) and molecular (H2-,F2-)systems with the goal of identifying and controlling their fragmentation pathways. This work was supported by the Chemical Sciences, Geosciences, and Biosciences Division, Office of Basic Energy Sciences, Office of Science, U.S. Department of Energy.

  2. A Statistical Model of the Electric Field and Field-aligned Ion Drift over Millstone Hill

    NASA Astrophysics Data System (ADS)

    Holt, J. M.; Zhang, S.

    2001-12-01

    All Millstone Hill incoherent scatter radar data collected since 1978 are available through the Madrigal Database at MIT Haystack Observatory. A set of empirical models for basic and derived incoherent scatter parameters, including electron density Ne, electron and ion temperatures Te and Ti, electric field and parallel ion drift is being developed from this extensive dataset. Such models of the average behavior of key ionosphere-thermosphere (IT) parameters, based on long term accumulated data, are important for space weather studies not only in terms of quantitative descriptions of the IT system but also in terms of clarifying several outstanding scientific problems. This paper presents statistical models of the local electric field and geomagnetic-field-aligned ion drift in the ionospheric F-layer. All local (radar elevation > 45 degrees) ion line-of sight measurements are sorted into bins. The binning parameters are local time (0000-2400 LT), and day of year (season). Each data point has a corresponding solar flux index F10.7 and geomagnetic activity index Ap. A least-squares fit to all the data in each bin is computed to determine the electric field as a function of Ap and the field-aligned drift as a function of F107 and Ap. Unlike previous Millstone Hill local electric field models, the components of the drift are determined in a statistical sense rather than by first computing the parallel and perpendicular drift components from triplets of line-of-sight measurements. We will present the data distribution in each bin and discuss the main features of the results.

  3. Linear and total intersubband transitions in the step-like GaAs/GaAlAs asymmetric quantum well as dependent on intense laser field

    NASA Astrophysics Data System (ADS)

    Ozturk, Emine

    2015-11-01

    In this study, for a step-like GaAs- Ga_{1-x}AlxAs asymmetric quantum well (AQW) the linear and total intersubband optical absorption coefficients and the refractive index changes are calculated as dependent on the intense laser field (ILF) and the right quantum well (RQW) width. Our results show that the location and the magnitude of all absorption coefficients and refractive index changes depend on ILF and the asymmetric parameter ( d=LR/LL). Also, we showed that both ILF and d provide an important effect on the electronic and optical properties of step-like quantum well, and the changes of the energy levels, the dipole moment matrix elements and the resonant peak values of the absorption coefficients are dependent on the shape of the confinement potential. While for different asymmetric parameters the intersubband absorption spectrum shows blue shift up to the different critical ILF values, this spectrum shows red shift for ILF values greater than certain values. By considering the variation of the energy difference as dependent on the RQW width, for step-like QW the absorption spectrum shows blue or red shift. Especially, step-like QWs are used for producing terahertz radiation from intersubband transitions and they have more tunable structure parameters (the left (right) quantum well width, LL(LR), and the confinement potential in the left (right) hand side, VL (VR) with respect to other asymmetric QWs (in the present study we used LR=LL/2, LL, 3 L L/2 and V R = 2 V L/3 values). This case provides a new degree of freedom for controlling the optical properties in quantum wells (QWs). In addition, the nonlinear optics underlying the application of the ILF to asymmetric potential heterostructures becomes a subject of present-day interest. In conclusion: i) The electronic and optical properties of the step-like AQW vary by increasing ILF. ii) ILF leads to major modifications on the shape of the confining potential. iii) The position and the size of all absorption

  4. CINEMA (Cubesat for Ion, Neutral, Electron, MAgnetic fields)

    NASA Astrophysics Data System (ADS)

    Lin, R. P.; Parks, G. K.; Halekas, J. S.; Larson, D. E.; Eastwood, J. P.; Wang, L.; Sample, J. G.; Horbury, T. S.; Roelof, E. C.; Lee, D.; Seon, J.; Hines, J.; Vo, H.; Tindall, C.; Ho, J.; Lee, J.; Kim, K.

    2009-12-01

    The NSF-funded CINEMA mission will provide cutting-edge magnetospheric science and critical space weather measurements, including high sensitivity mapping and high cadence movies of ring current, >4 keV Energetic Neutral Atom (ENA), as well as in situ measurements of suprathermal electrons (>~2 keV) and ions (>~ 4 keV) in the auroral and ring current precipitation regions, all with ~1 keV FWHM resolution and uniform response up to ~100 keV. A Suprathermal Electron, Ion, Neutral (STEIN) instrument adds an electrostatic deflection system to the STEREO STE (SupraThermal Electron) 4-pixel silicon semiconductor sensor to separate ions from electrons and from ENAs up to ~20 keV. In addition, inboard and outboard (on an extendable 1m boom) magnetoresistive sensor magnetometers will provide high cadence 3-axis magnetic field measurements. A new attitude control system (ACS) uses torque coils, a solar aspect sensor and the magnetometers to de-tumble the 3u CINEMA spacecraft, then spin it up to ~1 rpm with the spin axis perpendicular to the ecliptic, so STEIN can sweep across most of the sky every minute. Ideally, CINEMA will be placed into a high inclination low earth orbit that crosses the auroral zone and cusp. An S-band transmitter will be used to provide > ~8 kbps orbit-average data downlink to the ~11m diameter antenna of the Berkeley Ground Station. Two more identical CINEMA spacecraft will be built by Kyung Hee University (KHU) in Korea under their World Class University (WCU) program, to provide stereo ENA imaging and multi-point in situ measurements. Furthermore, CINEMA’s development of miniature particle and magnetic field sensors, and cubesat-size spinning spacecraft will be important for future nanosatellite space missions.

  5. Feasibility of asymmetric flow field-flow fractionation coupled to ICP-MS for the characterization of wear metal particles and metalloproteins in biofluids from hip replacement patients.

    PubMed

    Loeschner, Katrin; Harrington, Chris F; Kearney, Jacque-Lucca; Langton, David J; Larsen, Erik H

    2015-06-01

    Hip replacements are used to improve the quality of life of people with orthopaedic conditions, but the use of metal-on-metal (MoM) arthroplasty has led to poor outcomes for some patients. These problems are related to the generation of micro- to nanosized metal wear particles containing Cr, Co or other elements, but the current analytical methods used to investigate the processes involved do not provide sufficient information to understand the size or composition of the wear particles generated in vivo. In this qualitative feasibility study, asymmetric flow field-flow fractionation (AF(4)) coupled with inductively coupled plasma mass spectrometry (ICP-MS) was used to investigate metal protein binding and the size and composition of wear metal particles present in serum and hip aspirates from MoM hip replacement patients. A well-established HPLC anion exchange chromatography (AEC) separation system coupled to ICP-MS was used to confirm the metal-protein associations in the serum samples. Off-line single particle ICP-MS (spICP-MS) analysis was used to confirm the approximate size distribution indicated by AF(4) of the wear particles in hip aspirates. In the serum samples, AF(4) -ICP-MS suggested that Cr was associated with transferrin (Tf) and Co with albumin (Alb) and an unidentified species; AEC-ICP-MS confirmed these associations and also indicated an association of Cr with Alb. In the hip aspirate sample, AF(4)-ICP-MS suggested that Cr was associated with Alb and Tf and that Co was associated with Alb and two unidentified compounds; AEC analysis confirmed the Cr results and the association of Co with Alb and a second compound. Enzymatic digestion of the hip aspirate sample, followed by separation using AF(4) with detection by UV absorption (280 nm), multi-angle light scattering and ICP-MS, suggested that the sizes of the Cr-, Co- and Mo-containing wear particles in a hip aspirate sample were in the range 40-150 nm. Off-line spICP-MS was used to confirm these

  6. Application of ion-sensitive field effect transistors for ion channel screening.

    PubMed

    Walsh, Kenneth B; DeRoller, Nicholas; Zhu, Yihao; Koley, Goutam

    2014-04-15

    Cell-based screening assays are now widely used for identifying compounds that serve as ion channel modulators. However, instrumentation for the automated, real-time analysis of ion flux from clonal and primary cells is lacking. This study describes the initial development of an ion-sensitive field effect transistor (ISFET)-based screening assay for the acquisition of K(+) efflux data from cells cultured in multi-well plates. Silicon-based K(+)-sensitive ISFETs were tested for their electrical response to varying concentrations of KCl and were found to display a linear response relationship to KCl in the range of 10 µM-1 mM. The ISFETs, along with reference electrodes, were inserted into fast-flow chambers containing either human colonic T84 epithelial cells or U251-MG glioma cells. Application of the Ca(2+) ionophore A23187 (1 µM), to activate Ca(2+)-activated non-selective cation (NSC) channels (T84 cells) and large conductance Ca(2+)-activated K(+) (BK) channels (U251 cells), resulted in time-dependent increases in the extracellular K(+) concentration ([K(+)]o) as measured with the ISFETs. Treatment of the cells with blockers of either the NSC or BK channels, caused a strong inhibition of the A23187-induced increase in [K(+)]o. These results were consistent with ion current measurements obtained using the whole-cell arrangement of the patch clamp procedure. In addition, K(+) efflux data could be acquired in parallel from multiple cell chambers using the ISFET sensors. Given the non-invasive properties of the probes, the ISFET-based assay should be adaptable for screening ion channels in various cell types. PMID:24315877

  7. Influence of Heat Source, Thermal Radiation and Inclined Magnetic Field on Peristaltic Flow of a Hyperbolic Tangent Nanofluid in a Tapered Asymmetric Channel.

    PubMed

    Kothandapani, Munirathinam; Prakash, Jayavel

    2014-10-31

    In the present analytic thinking, we have modeled the governing equations of a two dimensional peristaltic transport of a Hyperbolic tangent nanofluid in the presence of a heat source/sink with the combined effects of thermal radiation and inclined magnetic field in a tapered asymmetric channel. The propagation of waves on the non-uniform walls to have different amplitudes and phase but the same wave speed is produced the tapered asymmetric channel. The equations of dimensionless temperature and nanoparticle concentration are solved analytically under assumptions of long wavelength and low Reynolds number. The governing equations of momentum of a hyperbolic tangent nanofluid for the tapered asymmetric channel have also been solved analytically using the regular perturbation method. The expression for average rise in pressure has been figured using numerical integrations. The effects of various physical parameters entering into the problem are discussed numerically and graphically. The phenomenon of trapping is also investigated. Furthermore, the received results show that the maximum pressure rise gets increased in case of non-Newtonian fluid when equated with Newtonian fluid. PMID:25373110

  8. Bidirectional migration of Au colloids and silicon microrods in liquid using asymmetrical alternating current electric field with insulated electrodes

    NASA Astrophysics Data System (ADS)

    Shibata, Akihide; Komiya, Kenji; Watanabe, Keiji; Sato, Takuya; Shiomi, Takeshi; Kotaki, Hiroshi; Schuele, Paul J.; Crowder, Mark A.; Zhan, Changqing; Hartzell, John W.

    2014-02-01

    In this study, we demonstrate the migration of Au colloids and silicon microrods in deionized (DI) water and isopropyl alcohol (IPA) by applying asymmetrical AC bias to two electrodes capped with a thin dielectric film. Both Au colloids and silicon microrods successfully migrate from one electrode to the other when asymmetrical AC bias is applied to the electrodes. Furthermore, the direction of the migration can be easily reversed by inverting the wave form. The insulated electrodes have the potential to prevent contamination and bubbling originating from electrochemical reactions, which makes the adoption of the technique for mass production processes easy and realistic. The bidirectional migration acts similarly to electrophoresis and is effective even in DI water and IPA in which conventional DC electrophoresis with insulated electrodes is ineffective. This technique is widely applicable to the positional control of small objects including nano- and micro-sized devices.

  9. Field theory for size- and charge-asymmetric primitive model of ionic systems: mean-field stability analysis and pretransitional effects.

    PubMed

    Ciach, A; Góźdź, W T; Stell, G

    2007-05-01

    The primitive model of ionic systems is investigated within a field-theoretic description for the whole range of diameter-, lambda , and charge, Z ratios of the two ionic species. Two order parameters (OP) are identified. The relation of the OP's to physically relevant quantities is nontrivial. Each OP is a linear combination of the charge density and the number-density waves. Instabilities of the disordered phase associated with the two OP's are determined in the mean-field approximation (MF). In MF a gas-liquid separation occurs for any Z and lambda is not equal to 1 . In addition, an instability with respect to various types of periodic ordering of the two kinds of ions is found. Depending on lambda and Z , one or the other transition is metastable in different thermodynamic states. For sufficiently large size disparity we find a sequence of fluid-crystal-fluid transitions for the increasing volume fraction of ions, in agreement with experimental observations. The instabilities found in MF represent weak ordering of the most probable instantaneous states, and are identified with structural loci associated with pretransitional effects. PMID:17677071

  10. Direct observation of the field-stimulated exoemission sites at tungsten surfaces using field ion microscopy

    NASA Astrophysics Data System (ADS)

    Shiota, T.; Umeno, M.; Dohkuni, K.; Tagawa, M.; Ohmae, N.

    2001-05-01

    The spatial distribution of the field-stimulated exoemission (FSEE) from the W tip surface annealed at 800 K for 600 s and the atomic arrangement of the emitting surface were correlated using field ion microscopy (FIM) and field emission microscopy. The FSEE was observed at around the (111) plane of the annealed W tip surface. FIM observation of the annealed W tip revealed the existence of a pyramid-like protrusion at the W(111) surface. From these experimental results, a new emission model of the FSEE was proposed relating to the field-assisted surface structural change. This model deals with the buildup/collapse of the pyramid-like protrusion at the W(111) surface under the effect of negative high electric field. The temperature dependence of the FSEE reported previously [Shiota et al., J. Appl. Phys. 85, 6811 (1999)] was qualitatively explained by this emission model.

  11. Stochastic Ion Heating in a Field-reversed Configuration Geometry by Rotating Magnetic Fields

    SciTech Connect

    S.A. Cohen, A.S. Landsman, and A.H. Glasser

    2007-06-25

    Ion heating by application of rotating magnetic fields (RMF) to a prolate field-reversed configuration(FRC) is explored by analytical and numerical techniques. For odd-parity RMF (RMFo), perturbation analysis shows ions in figure-8 orbits gain energy at resonances of the RMFo frequency, ωR, with the figure-8 orbital frequency, ω. Since figure-8 orbits tend to gain the most energy from the RMF and are unlikely to escape in the cusp region (where most losses occur), they are optimal candidates for rapid stochastic heating, as compared to cyclotron and betatron orbits. Comparisons are made between heating caused by even- and odd-parity RMFs and between heating in currently operating and in reactor-scale FRC devices.

  12. Softening of the tunneling gap in modulation-doped GaAs/AlGaAs asymmetric coupled double quantum wells in magnetic fields

    NASA Astrophysics Data System (ADS)

    Shin, Y. H.; Park, Y. H.; Perry, C. H.; Simmons, J. A.; Takamasu, T.; Kim, Yongmin

    2009-08-01

    Magnetophotoluminescence emissions were measured from modulation doped GaAs/AlGaAs asymmetric double quantum wells, wherein a thin barrier (25 Å) was sandwiched between a single quantum well (SQW) and a single heterojuction (SHJ). In the SQW, Landau level mixing is observed at the quantum Hall states. At ν <2, the lowest Landau level transition undergoes an exciton transition. For the SHJ region, the free carrier transitions become excitonic at the crossing point of the GaAs free exciton and the tunneling band gap shows a marked softening. An exciton-exciton interaction is shown to be responsible for the behavior of the subband energy levels in magnetic fields.

  13. Nano-textured high sensitivity ion sensitive field effect transistors

    NASA Astrophysics Data System (ADS)

    Hajmirzaheydarali, M.; Sadeghipari, M.; Akbari, M.; Shahsafi, A.; Mohajerzadeh, S.

    2016-02-01

    Nano-textured gate engineered ion sensitive field effect transistors (ISFETs), suitable for high sensitivity pH sensors, have been realized. Utilizing a mask-less deep reactive ion etching results in ultra-fine poly-Si features on the gate of ISFET devices where spacing of the order of 10 nm and less is achieved. Incorporation of these nano-sized features on the gate is responsible for high sensitivities up to 400 mV/pH in contrast to conventional planar structures. The fabrication process for this transistor is inexpensive, and it is fully compatible with standard complementary metal oxide semiconductor fabrication procedure. A theoretical modeling has also been presented to predict the extension of the diffuse layer into the electrolyte solution for highly featured structures and to correlate this extension with the high sensitivity of the device. The observed ultra-fine features by means of scanning electron microscopy and transmission electron microscopy tools corroborate the theoretical prediction.

  14. The quantum mechanics of ion-enhanced field emission and how it influences microscale gas breakdown

    SciTech Connect

    Li, Yingjie; Go, David B.

    2014-09-14

    The presence of a positive gas ion can enhance cold electron field emission by deforming the potential barrier and increasing the tunneling probability of electrons—a process known as ion-enhanced field emission. In microscale gas discharges, ion-enhanced field emission produces additional emission from the cathode and effectively reduces the voltage required to breakdown a gaseous medium at the microscale (<10 μm). In this work, we enhance classic field emission theory by determining the impact of a gaseous ion on electron tunneling and compute the effect of ion-enhanced field emission on the breakdown voltage. We reveal that the current density for ion-enhanced field emission retains the same scaling as vacuum cold field emission and that this leads to deviations from traditional breakdown theory at microscale dimensions.

  15. Optimizing direct intense-field laser acceleration of ions

    SciTech Connect

    Harman, Zoltan; Salamin, Yousef I.; Galow, Benjamin J.; Keitel, Christoph H.

    2011-11-15

    The dynamics of ion acceleration in tightly focused laser beams is investigated in relativistic simulations. Studies are performed to find the optimal parameters which maximize the energy gain, beam quality, and flux. The exit ionic kinetic energy and its uncertainty are improved and the number of accelerated particles is increased by orders of magnitude over our earlier results, especially when working with a longer laser wavelength. Laser beams of powers of 0.1-10 petawatts and focused to subwavelength spot radii are shown to directly accelerate protons and bare nuclei of helium, carbon, and oxygen from a few to several hundred MeV/nucleon. Variation of the volume of the initial ionic ensemble, as well as the introduction of a pulse shape on the laser fields, have been investigated and are shown to influence the exit particle kinetic energies only slightly.

  16. Ion orbit loss and the poloidal electric field in a tokamak

    SciTech Connect

    Xiao, H.; Hazeltine, R.D.; Valanju, P.M.

    1994-07-29

    Monte Carlo simulation studies for ion orbit loss in limiter tokamaks show a poloidal asymmetry in ion loss arising from differences in ion orbit geometry. Since electron loss to the limiter is uniformly distributed because of its tiny orbit width, the nonuniform ion loss could cause a poloidal electric field that would tend to make the ion loss to the limiter more uniform. A simple analytical derivation of this poloidal electric field and a discussion of its effects ion movement and transport are also presented.

  17. Effects of applied electric and magnetic fields on the nonlinear optical properties of asymmetric GaAs /Ga1-xAlx As double inverse parabolic quantum well

    NASA Astrophysics Data System (ADS)

    Al, E. B.; Ungan, F.; Yesilgul, U.; Kasapoglu, E.; Sari, H.; Sökmen, I.

    2015-09-01

    The combined effects of electric and magnetic fields on the optical absorption coefficients and refractive index changes related to the intersubband transitions within the conduction band of asymmetric GaAs /Ga1-xAlxAs double inverse parabolic quantum wells are studied using the effective-mass approximation and the compact density-matrix approach. The results are presented as a function of the incident photon energy for the different values of the electromagnetic fields and the structure parameters such as quantum well width and the Al concentration at the well center. It is found that the optical absorption coefficients and the refractive index changes are strongly affected not only by the magnitudes of the electric and magnetic fields but also by the structure parameters of the system.

  18. Radioelectric asymmetric conveyed fields and human adipose-derived stem cells obtained with a nonenzymatic method and device: a novel approach to multipotency.

    PubMed

    Maioli, Margherita; Rinaldi, Salvatore; Santaniello, Sara; Castagna, Alessandro; Pigliaru, Gianfranco; Delitala, Alessandro; Bianchi, Francesca; Tremolada, Carlo; Fontani, Vania; Ventura, Carlo

    2014-01-01

    Human adipose-derived stem cells (hASCs) have been recently proposed as a suitable tool for regenerative therapies for their simple isolation procedure and high proliferative capability in culture. Although hASCs can be committed into different lineages in vitro, the differentiation is a low-yield and often incomplete process. We have recently developed a novel nonenzymatic method and device, named Lipogems, to obtain a fat tissue derivative highly enriched in pericytes/mesenchymal stem cells by mild mechanical forces from human lipoaspirates. When compared to enzymatically dissociated cells, Lipogems-derived hASCs exhibited enhanced transcription of vasculogenic genes in response to provasculogenic molecules, suggesting that these cells may be amenable for further optimization of their multipotency. Here we exposed Lipogems-derived hASCs to a radioelectric asymmetric conveyer (REAC), an innovative device asymmetrically conveying radioelectric fields, affording both enhanced differentiating profiles in mouse embryonic stem cells and efficient direct multilineage reprogramming in human skin fibroblasts. We show that specific REAC exposure remarkably enhanced the transcription of prodynorphin, GATA-4, Nkx-2.5, VEGF, HGF, vWF, neurogenin-1, and myoD, indicating the commitment toward cardiac, vascular, neuronal, and skeletal muscle lineages, as inferred by the overexpression of a program of targeted marker proteins. REAC exposure also finely tuned the expression of stemness-related genes, including NANOG, SOX-2, and OCT-4. Noteworthy, the REAC-induced responses were fashioned at a significantly higher extent in Lipogems-derived than in enzymatically dissociated hASCs. Therefore, REAC-mediated interplay between radioelectric asymmetrically conveyed fields and Lipogems-derived hASCs appears to involve the generation of an ideal "milieu" to optimize multipotency expression from human adult stem cells in view of potential improvement of future cell therapy efforts. PMID

  19. Dark-Field Scanning Transmission Ion Microscopy via Direct Detection of Transmitted Helium Ions with a Multichannel Plate

    NASA Astrophysics Data System (ADS)

    Woehl, Taylor; White, Ryan; Keller, Robert

    A multichannel plate was used as an ion sensitive transmission detector in a commercial helium ion microscope for annular dark-field imaging of nanomaterials, i.e. scanning transmission ion microscopy. In contrast to previous transmission helium ion microscopy approaches that used secondary electron conversion holders, our new approach directly detects transmitted helium ions on an annular detector. Monte Carlo simulations are used to predict detector collection angles at which annular dark-field images with atomic number contrast are obtained. We demonstrate atomic number contrast imaging via scanning transmission ion imaging of silica-coated gold nanoparticles and magnetite nanoparticles. While the resolution of this transmission technique is limited by beam broadening in the substrate, we image magnetite nanoparticles with high contrast on a relatively thick silicon nitride substrate. We expect this new approach to annular dark-field scanning transmission ion microscopy will open avenues for more quantitative ion imaging techniques, such as direct mass-thickness determination, and advance fundamental understanding of underlying ion scattering mechanisms leading to image formation.

  20. Atom probe field ion microscopy and related topics: A bibliography 1992

    SciTech Connect

    Russell, K.F.; Godfrey, R.D.; Miller, M.K.

    1993-12-01

    This bibliography contains citations of books, conference proceedings, journals, and patents published in 1992 on the following types of microscopy: atom probe field ion microscopy (108 items); field emission microscopy (101 items); and field ion microscopy (48 items). An addendum of 34 items missed in previous bibliographies is included.

  1. Design and construction of cage environments for air ion and electric field research

    NASA Astrophysics Data System (ADS)

    Yost, M. G.; Kellogg, E. W.

    1987-06-01

    This report describes the design and construction of cage environments suitable for chronic exposures of large groups of mice to air ions and electric fields. These environments provide defined and reproducible ion densities, ion flux, DC electric fields, sound levels, air temperature and air quality. When used during a 2 year study, these cage environments served as a durable and reliable continuous exposure system. Three environmental chambers (cubicles) housed a total of 12 cages and provided control of air temperature, air purity and lighting. Exposure cages had grounded metal exterior walls, a plexiglass door and interior walls lined with formica. An internal isolated field plate supplemented with guard wires, energized with ca 1000 VDC, created about a 2 kV/m electric field at the grounded cage floor. Air ions resulted from the beta emission of sealed tritium foils mounted on the field plate. Cages provided high ion (1.3×105 ions/cc), low ion (1.6×103 ions/cc) and field only (ion depleted < 50 ions/cc) conditions for both polarities with similar electric fields in ionized and field only cages. Detailed mapping of the floor level ion flux using 100 cm2 flat probes gave average fluxes of 880 fA cm-2 in high ion cages and 10 fA cm-2 in low ion cages. Whole body currents measured using live anesthethized mice in high ion cages averaged 104±63 pA. Both ion flux and whole body currents remained constant over time, indicating no charge accumulation on body fur or cage wall surfaces in this exposure system.

  2. Atom probe field ion microscopy and related topics: A bibliography 1989

    SciTech Connect

    Miller, M.K.; Hawkins, A.R.; Russell, K.F.

    1990-12-01

    This bibliography includes references related to the following topics: atom probe field ion microscopy (APFIM), field ion spectroscopy (FIM), field emission microscopy (FEM), liquid metal ion sources (LMIS), scanning tunneling microscopy (STM), and theory. Technique-orientated studies and applications are included. This bibliography covers the period 1989. The references contained in this document were compiled from a variety of sources including computer searches and personal lists of publications.

  3. Asymmetric Ashes

    NASA Astrophysics Data System (ADS)

    2006-11-01

    that oscillate in certain directions. Reflection or scattering of light favours certain orientations of the electric and magnetic fields over others. This is why polarising sunglasses can filter out the glint of sunlight reflected off a pond. When light scatters through the expanding debris of a supernova, it retains information about the orientation of the scattering layers. If the supernova is spherically symmetric, all orientations will be present equally and will average out, so there will be no net polarisation. If, however, the gas shell is not round, a slight net polarisation will be imprinted on the light. This is what broad-band polarimetry can accomplish. If additional spectral information is available ('spectro-polarimetry'), one can determine whether the asymmetry is in the continuum light or in some spectral lines. In the case of the Type Ia supernovae, the astronomers found that the continuum polarisation is very small so that the overall shape of the explosion is crudely spherical. But the much larger polarization in strongly blue-shifted spectral lines evidences the presence, in the outer regions, of fast moving clumps with peculiar chemical composition. "Our study reveals that explosions of Type Ia supernovae are really three-dimensional phenomena," says Dietrich Baade. "The outer regions of the blast cloud is asymmetric, with different materials found in 'clumps', while the inner regions are smooth." "This study was possible because polarimetry could unfold its full strength thanks to the light-collecting power of the Very Large Telescope and the very precise calibration of the FORS instrument," he adds. The research team first spotted this asymmetry in 2003, as part of the same observational campaign (ESO PR 23/03 and ESO PR Photo 26/05). The new, more extensive results show that the degree of polarisation and, hence, the asphericity, correlates with the intrinsic brightness of the explosion. The brighter the supernova, the smoother, or less clumpy

  4. (In)validity of the constant field and constant currents assumptions in theories of ion transport.

    PubMed Central

    Syganow, A; von Kitzing, E

    1999-01-01

    Constant electric fields and constant ion currents are often considered in theories of ion transport. Therefore, it is important to understand the validity of these helpful concepts. The constant field assumption requires that the charge density of permeant ions and flexible polar groups is virtually voltage independent. We present analytic relations that indicate the conditions under which the constant field approximation applies. Barrier models are frequently fitted to experimental current-voltage curves to describe ion transport. These models are based on three fundamental characteristics: a constant electric field, negligible concerted motions of ions inside the channel (an ion can enter only an empty site), and concentration-independent energy profiles. An analysis of those fundamental assumptions of barrier models shows that those approximations require large barriers because the electrostatic interaction is strong and has a long range. In the constant currents assumption, the current of each permeating ion species is considered to be constant throughout the channel; thus ion pairing is explicitly ignored. In inhomogeneous steady-state systems, the association rate constant determines the strength of ion pairing. Among permeable ions, however, the ion association rate constants are not small, according to modern diffusion-limited reaction rate theories. A mathematical formulation of a constant currents condition indicates that ion pairing very likely has an effect but does not dominate ion transport. PMID:9929480

  5. Linear electronic field time-of-flight ion mass spectrometers

    DOEpatents

    Funsten, Herbert O.

    2010-08-24

    Time-of-flight mass spectrometer comprising a first drift region and a second drift region enclosed within an evacuation chamber; a means of introducing an analyte of interest into the first drift region; a pulsed ionization source which produces molecular ions from said analyte of interest; a first foil positioned between the first drift region and the second drift region, which dissociates said molecular ions into constituent atomic ions and emits secondary electrons; an electrode which produces secondary electrons upon contact with a constituent atomic ion in second drift region; a stop detector comprising a first ion detection region and a second ion detection region; and a timing means connected to the pulsed ionization source, to the first ion detection region, and to the second ion detection region.

  6. Dark-Field Scanning Transmission Ion Microscopy via Detection of Forward-Scattered Helium Ions with a Microchannel Plate.

    PubMed

    Woehl, Taylor J; White, Ryan M; Keller, Robert R

    2016-06-01

    A microchannel plate was used as an ion sensitive detector in a commercial helium ion microscope (HIM) for dark-field transmission imaging of nanomaterials, i.e. scanning transmission ion microscopy (STIM). In contrast to previous transmission HIM approaches that used secondary electron conversion holders, our new approach detects forward-scattered helium ions on a dedicated annular shaped ion sensitive detector. Minimum collection angles between 125 mrad and 325 mrad were obtained by varying the distance of the sample from the microchannel plate detector during imaging. Monte Carlo simulations were used to predict detector angular ranges at which dark-field images with atomic number contrast could be obtained. We demonstrate atomic number contrast imaging via scanning transmission ion imaging of silica-coated gold nanoparticles and magnetite nanoparticles. Although the resolution of STIM is known to be degraded by beam broadening in the substrate, we imaged magnetite nanoparticles with high contrast on a relatively thick silicon nitride substrate. We expect this new approach to annular dark-field STIM will open avenues for more quantitative ion imaging techniques and advance fundamental understanding of underlying ion scattering mechanisms leading to image formation. PMID:27153003

  7. Electric-field control of the occupancy of the upper laser subband in quantum-well structures with asymmetric barriers designed for unipolar laser operation

    SciTech Connect

    Aleshchenko, Yu. A. Zhukov, A. E.; Kapaev, V. V.; Kopaev, Yu. V.; Kop'ev, P. S.; Ustinov, V. M.

    2008-07-15

    Experimental and theoretical studies of triple-quantum-well structures implementing a prototype active element for a novel type of unipolar laser were carried out. Such a laser, whose design was suggested by us previously, is based on highly asymmetric quantum wells (with barriers of noticeably different heights). It is shown that application of an external electric field to the structures under study leads to an effect similar to the dimensionality-switching effect in a structure with optimum parameters. Despite the fact that barrier thicknesses in the structures under study exceed considerably the values corresponding to the optimum structure, the matrix-element product that determines the gain remains sufficiently large (175-200 A{sup 2} as compared to 250 A{sup 2} in the optimum structure) in a wide range of electric fields.

  8. The role of permanent dipoles on the intensity-dependent nonlinear optical properties in asymmetric coupled quantum wells under a static electric field

    NASA Astrophysics Data System (ADS)

    Karabulut, Ibrahim; Paspalakis, Emmanuel

    2016-07-01

    We study theoretically the intensity-dependent nonlinear optical properties of an asymmetric coupled quantum well under a static electric field. Effects such as nonlinear absorption, optical rectification and refractive index are investigated theoretically by using the density matrix equations including the permanent dipole terms. Our results show that the effects of the permanent dipoles on the corresponding optical processes depend crucially on the direction and strength of the static electric field, especially for large optical intensities. Another interesting result of this work is that the nonlinear optical spectra studied here saturate with an increasing optical intensity and specifically the optical spectra in the case that the permanent dipoles are considered reach saturation for lower intensities than when the permanent dipoles are not considered.

  9. Decomposition of cyclohexane ion induced by intense femtosecond laser fields by ion-trap time-of-flight mass spectrometry

    NASA Astrophysics Data System (ADS)

    Yamazaki, Takao; Watanabe, Yusuke; Kanya, Reika; Yamanouchi, Kaoru

    2016-01-01

    Decomposition of cyclohexane cations induced by intense femtosecond laser fields at the wavelength of 800 nm is investigated by ion-trap time-of-flight mass spectrometry in which cyclohexane cations C6H12+ stored in an ion trap are irradiated with intense femtosecond laser pulses and the generated fragment ions are recorded by time-of-flight mass spectrometry. The various fragment ion species, C5Hn+ (n = 7, 9), C4Hn+ (n = 5-8), C3Hn+ (n = 3-7), C2Hn+ (n = 2-6), and CH3+, identified in the mass spectra show that decomposition of C6H12+ proceeds efficiently by the photo-irradiation. From the laser intensity dependences of the yields of the fragment ion species, the numbers of photons required for producing the respective fragment ions are estimated.

  10. ALTERATIONS IN CALCIUM ION ACTIVITY BY ELF AND RF ELECTROMAGNETIC FIELDS

    EPA Science Inventory



    Alterations in calcium ion activity by ELF and RF electromagnetic fields

    Introduction

    Calcium ions play many important roles in biological systems. For example, calcium ion activity can be used as an indicator of second-messenger signal-transduction processe...

  11. Renormalized theory of ion temperature gradient instability of the magnetic-field-aligned plasma shear flow with hot ions

    SciTech Connect

    Mikhailenko, V. V. Mikhailenko, V. S.; Lee, Hae June

    2015-10-15

    The developed kinetic theory for the stability of a magnetic-field-aligned (parallel) shear flow with inhomogeneous ion temperature [Mikhailenko et al., Phys. Plasmas 21, 072117 (2014)] predicted that a kinetic instability arises from the coupled reinforcing action of the flow velocity shear and ion temperature gradient in the cases where comparable ion and electron temperatures exist. In the present paper, the nonlinear theory was developed for the instability caused by the combined effects of ion-temperature-gradient and shear-flow (ITG–SF). The level of the electrostatic turbulence is determined for the saturation state of the instability on the basis of the nonlinear dispersion equation, which accounts for a nonlinear scattering of ions by the developed turbulence in a sheared flow. The renormalized quasilinear equation for the ion distribution function, which accounts for the turbulent scattering of ions by ITG–SF driven turbulence, was derived and employed for the estimation of the turbulent ion viscosity, the anomalous ion thermal conductivity, and anomalous ion heating rate at the saturation state of the instability.

  12. On the Electron Dynamics during Rapid Asymmetric Magnetic Island Coalescence: Insights on the Electrons Agyrotropy with the Presence of a Guide Field

    NASA Astrophysics Data System (ADS)

    Cazzola, Emanuele; Lapenta, Giovanni; Innocenti, Maria Elena; Goldman, Martin; Newman, David; Markidis, Stefano

    2016-04-01

    The work presents a fully kinetic analysis of the electrons dynamics during rapid island coalescence in asymmetric magnetic reconnection, especially focused on the comparison between the case with and with no initial guide field. Formation and growth of the islands are caused by an intentionally unstable initial configuration across the current sheet with the same asymmetric profiles as those traditionally proposed in the literature (e.g. Pritchett, 2008). Particular attentions is given to the different evolution of the presumed reconnection sites. Three main regions are eventually identified, named by X-, D- and M-regions, which describe, respectively, the regions featuring a traditional reconnection event, those showing an opposite behavior with respect to the former and the reconnection regions occurring between two magnetic islands (Cazzola et al., 2015). Further analysis is mainly addressed to evaluate both the electrons departure from the isotropic and gyrotropic behavior. Whether the first quantity has been clearly established and confirmed by observations, the latter has always appeared of difficult interpretation, and an ultimate accepted method on how to render it from PIC simulations still seems far to be achieved. In light of the upcoming data from the freshly launched MMS NASA mission, outcomes from some of the main techniques to spot agyrotropic regions are here compared to highligh the presence of possible relevant differences (Scudder and Daughton, 2008; Swisdak, 2015). References [1] P. Pritchett, "Collisionless magnetic reconnection in an asymmetric current sheet," Journal of Geophysical Research: Space Physics (1978-2012), vol. 113, no. A6, 2008. [2] E. Cazzola, M. E. Innocenti, S. Markidis, M. V. Goldman, D. L. Newman, and G. Lapenta, "On the electron dynamics during island coalescence in asymmetric magnetic reconnection," Physics of Plasmas (1994-present), vol. 22, no. 9, p. 092901, 2015. [3] J. Scudder and W. Daughton, "Illuminating electron

  13. Ion-implanted GaN junction field effect transistor

    SciTech Connect

    Zolper, J.C.; Shul, R.J.; Baca, A.G.; Wilson, R.G.; Pearton, S.J.; Stall, R.A.

    1996-04-01

    Selective area ion implantation doping has been used to fabricate GaN junction field effect transistors (JFETs). {ital p}-type and {ital n}-type doping was achieved with Ca and Si implantation, respectively, followed by a 1150{degree}C rapid thermal anneal. A refractory W gate contact was employed that allows the {ital p}-gate region to be self-aligned to the gate contact. A gate turn-on voltage of 1.84 V at 1 mA/mm of gate current was achieved. For a {approximately}1.7 {mu}m{times}50 {mu}m JFET with a {minus}6 V threshold voltage, a maximum transconductance of 7 mS/mm at {ital V}{sub GS}={minus} 2V and saturation current of 33 mA/mm at {ital V}{sub GS}=0 V were measured. These results were limited by excess access resistance and can be expected to be improved with optimized {ital n}{sup +} implants in the source and drain regions. {copyright} {ital 1996 American Institute of Physics.}

  14. Ion adsorption and its influence on direct current electric field induced deformations of flexoelectric nematic layers

    NASA Astrophysics Data System (ADS)

    Derfel, Grzegorz; Buczkowska, Mariola

    2011-07-01

    The influence of ion adsorption on the behavior of the nematic liquid crystal layers is studied numerically. The homeotropic flexoelectric layer subjected to the dc electric field is considered. Selective adsorption of positive ions is assumed. The analysis is based on the free energy formalism for ion adsorption. The distributions of director orientation angle, electric potential, and ion concentrations are calculated by numerical resolving of suitable torques equations and Poisson equation. The threshold voltages for the deformations are also determined. It was shown that adsorption affects the distributions of both cations and anions. Sufficiently large number of adsorbed ions leads to spontaneous deformation arising without any threshold if the total number of ions creates sufficiently strong electric field with significant field gradients in the neighborhood of electrodes. The spontaneous deformations are favored by strong flexoelectricity, large thickness, large ion concentrations, weak anchoring, and large adsorption energy.

  15. Confinement of laser plasma by solenoidal field for laser ion source

    SciTech Connect

    Okamura, M.; Kanesue,T.; Kondo, K.; Dabrowski, R.

    2010-05-23

    A laser ion source can provide high current, highly charged ions with a simple structure. However, it was not easy to control the ion pulse width. To provide a longer ion beam pulse, the plasma drift length, which is the distance between laser target and extraction point, has to be extended and as a result the plasma is diluted severely. Previously, we applied a solenoid field to prevent reduction of ion density at the extraction point. Although a current enhancement by a solenoid field was observed, plasma behavior after a solenoid magnet was unclear because plasma behavior can be different from usual ion beam dynamics. We measured a transverse ion distribution along the beam axis to understand plasma motion in the presence of a solenoid field.

  16. Asymmetrical Capacitors for Propulsion

    NASA Technical Reports Server (NTRS)

    Canning, Francis X.; Melcher, Cory; Winet, Edwin

    2004-01-01

    Asymmetrical Capacitor Thrusters have been proposed as a source of propulsion. For over eighty years, it has been known that a thrust results when a high voltage is placed across an asymmetrical capacitor, when that voltage causes a leakage current to flow. However, there is surprisingly little experimental or theoretical data explaining this effect. This paper reports on the results of tests of several Asymmetrical Capacitor Thrusters (ACTs). The thrust they produce has been measured for various voltages, polarities, and ground configurations and their radiation in the VHF range has been recorded. These tests were performed at atmospheric pressure and at various reduced pressures. A simple model for the thrust was developed. The model assumed the thrust was due to electrostatic forces on the leakage current flowing across the capacitor. It was further assumed that this current involves charged ions which undergo multiple collisions with air. These collisions transfer momentum. All of the measured data was consistent with this model. Many configurations were tested, and the results suggest general design principles for ACTs to be used for a variety of purposes.

  17. On Alfvenic Waves and Stochastic Ion Heating with 1Re Observations of Strong Field-aligned Currents, Electric Fields, and O+ ions

    NASA Technical Reports Server (NTRS)

    Coffey, Victoria; Chandler, Michael; Singh, Nagendra

    2008-01-01

    The role that the cleft/cusp has in ionosphere/magnetosphere coupling makes it a very dynamic region having similar fundamental processes to those within the auroral regions. With Polar passing through the cusp at 1 Re in the Spring of 1996, we observe a strong correlation between ion heating and broadband ELF (BBELF) emissions. This commonly observed relationship led to the study of the coupling of large field-aligned currents, burst electric fields, and the thermal O+ ions. We demonstrate the role of these measurements to Alfvenic waves and stochastic ion heating. Finally we will show the properties of the resulting density cavities.

  18. Gas field ion source current stability for trimer and single atom terminated W(111) tips

    SciTech Connect

    Urban, Radovan; Wolkow, Robert A.; Pitters, Jason L.

    2012-06-25

    Tungsten W(111) oriented trimer-terminated tips as well as single atom tips, fabricated by a gas and field assisted etching and evaporation process, were investigated with a view to scanning ion microscopy and ion beam writing applications. In particular, ion current stability was studied for helium and neon imaging gases. Large ion current fluctuations from individual atomic sites were observed when a trimer-terminated tip was used for the creation of neon ion beam. However, neon ion current was stable when a single atom tip was employed. No such current oscillations were observed for either a trimer or a single atom tip when imaged with helium.

  19. Free-Standing Bilayered Nanoparticle Superlattice Nanosheets with Asymmetric Ionic Transport Behaviors.

    PubMed

    Rao, Siyuan; Si, Kae Jye; Yap, Lim Wei; Xiang, Yan; Cheng, Wenlong

    2015-11-24

    Natural cell membranes can directionally and selectively regulate the ion transport, which is critical for the functioning of living cells. Here, we report on the fabrication of an artificial membrane based on an asymmetric nanoparticle superlattice bilayered nanosheet, which exhibits similar ion transport characteristics. The superlattice nanosheets were fabricated via a drying-mediated self-assembly of polystyrene-capped gold nanoparticles at the liquid-air interface. By adopting a layer-by-layer assembly process, an asymmetric nanomembrane could be obtained consisting of two nanosheets with different nanoparticle size. The resulting nanomembranes exhibit an asymmetric ion transport behavior, and diode-like current-voltage curves were observed. The asymmetric ion transport is attributed to the cone-like nanochannels formed within the membranes, upon which a simulation map was established to illustrate the relationship between the channel structure and the ionic selectivity, in consistency with our experimental results. Our superlattice nanosheet-based design presents a promising strategy for the fabrication of next-generation smart nanomembranes for rationally and selectively regulating the ion transport even at a large ion flux, with potential applications in a wide range of fields, including biosensor devices, energy conversion, biophotonics, and bioelectronics. PMID:26486960

  20. Ion heating in the field-reversed configuration (FRC) by rotating magnetic fields (RMF) near cyclotron resonance

    SciTech Connect

    Samuel A. Cohen; Alan H. Glasser

    2000-07-20

    The trajectories of ions confined in a Solovev FRC equilibrium magnetic geometry and heated with a small-amplitude, odd-parity rotating magnetic field, have been studied with a Hamiltonian computer code. When the RMF frequency is in the ion-cyclotron range, explosive heating occurs. Higher-energy ions are found to have betatron-type orbits, preferentially localized near the FRC midplane. These results are relevant to a compact magnetic-fusion-reactor design.

  1. Single ion as a shot-noise-limited magnetic-field-gradient probe

    SciTech Connect

    Walther, A.; Poschinger, U.; Ziesel, F.; Hettrich, M.; Wiens, A.; Welzel, J.; Schmidt-Kaler, F.

    2011-06-15

    It is expected that ion-trap quantum computing can be made scalable through protocols that make use of transport of ion qubits between subregions within the ion trap. In this scenario, any magnetic field inhomogeneity the ion experiences during the transport may lead to dephasing and loss of fidelity. Here we demonstrate how to measure, and compensate for, magnetic field gradients inside a segmented ion trap, by transporting a single ion over variable distances. We attain a relative magnetic field sensitivity of {Delta}B/B{sub 0{approx}}5x10{sup -7} over a test distance of 140 {mu}m, which can be extended to the mm range, still with sub-{mu}m resolution. A fast experimental sequence is presented, facilitating its use as a magnetic-field-gradient calibration routine, and it is demonstrated that the main limitation is the quantum shot noise.

  2. Transport coefficients of gaseous ions in an electric field

    NASA Technical Reports Server (NTRS)

    Whealton, J. H.; Mason, E. A.

    1974-01-01

    A general theory of ion mobility formulated by Kihara (1953) is extended to ion diffusion and to mixtures of neutral gases. The theory assumes that only binary collisions between ions and neutral particles need to be taken into account and that the velocity distribution function of the neutral particles is Maxwellian. These assumptions make it possible to use a linearized Boltzmann equation. Questions of mobility are considered along with aspects of diffusion and deviations from Fick's law of diffusion.

  3. Analyzing the influence of PEG molecular weight on the separation of PEGylated gold nanoparticles by asymmetric-flow field-flow fractionation.

    PubMed

    Hansen, Matthew; Smith, Mackensie C; Crist, Rachael M; Clogston, Jeffrey D; McNeil, Scott E

    2015-11-01

    Polyethylene glycol (PEG) is an important tool for increasing the biocompatibility of nanoparticle therapeutics. Understanding how these potential nanomedicines will react after they have been introduced into the bloodstream is a critical component of the preclinical evaluation process. Hence, it is paramount that better methods for separating, characterizing, and analyzing these complex and polydisperse formulations are developed. We present a method for separating nominal 30-nm gold nanoparticles coated with various molecular weight PEG moieties that uses only phosphate-buffered saline as the mobile phase, without the need for stabilizing surfactants. The optimized asymmetric-flow field-flow fractionation technique using in-line multiangle light scattering, dynamic light scattering, refractive index, and UV-vis detectors allowed successful separation and detection of a mixture of nanoparticles coated with 2-, 5-, 10-, and 20-kDa PEG. The particles coated with the larger PEG species (10 and 20 kDa) were eluted at times significantly earlier than predicted by field-flow fractionation theory. This was attributed to a lower-density PEG shell for the higher molecular weight PEGylated nanoparticles, which allows a more fluid PEG surface that can be greater influenced by external forces. Hence, the apparent particle hydrodynamic size may fluctuate significantly depending on the overall density of the stabilizing surface coating when an external force is applied. This has considerable implications for PEGylated nanoparticles intended for in vivo application, as nanoparticle size is important for determining circulation times, accumulation sites, and routes of excretion, and highlights the importance and value of the use of secondary size detectors when one is working with complex samples in asymmetric-flow field-flow fractionation. PMID:26449845

  4. Dynamic characteristics of double-barrier nanostructures with asymmetric barriers of finite height and widths in a strong ac electric field

    SciTech Connect

    Chuenkov, V. A.

    2013-12-15

    The theory of the interaction of a monoenergetic flow of injected electrons with a strong high-frequency ac electric field in resonant-tunneling diode (RTD) structures with asymmetric barriers of finite height and width is generalized. In the quasi-classical approximation, electron wavefunctions and tunneling functions in the quantum well and barriers are found. Analytical expressions for polarization currents in RTDs are derived in both the general case and in a number of limiting cases. It is shown that the polarization currents and radiation power in RTDs with asymmetric barriers strongly depend on the ratio of the probabilities of electron tunneling through the emitter and collector barriers. In the quantum mode, when δ = ε − ε{sub r} = ħω ≪ Γ (ε is the energy of electrons injected in the RTD, ħ is Planck’s constant, ω is the ac field frequency, ε{sub r} and Γ are the energy and width of the resonance level, respectively), the active polarization current in a field of E ≈ 2.8ħω/ea (e is the electron charge and a is the quantum-well width) reaches a maximum equal in magnitude to 84% of the direct resonant current, if the probability of electron tunneling through the emitter barrier is much higher than that through the collector barrier. The radiation-generation power at frequencies of ω = 10{sup 12}–10{sup 13} s{sup −1} can reach 10{sup 5}–10{sup 6} W/cm{sup 2} in this case.

  5. Heating of heavy ions on auroral field lines

    SciTech Connect

    Nishikawa, K.I.; Okuda, H., Hasegawa, A.

    1983-01-01

    Heating of heavy ions is studied in the presence of large amplitude hydrogen cyclotron waves. A three wave decay process, in which a large amplitude pump hydrogen cyclotron wave decays into a daughter hydrogen cyclotron wave and a low frequency oxygen cyclotron wave, is studied theoretically and by numerical simulations. The numerical simulations show a decay instability resulting in strong heating of both the oxygen ions and the hydrogen ions. In particular, the high energy tail of the oxygen ions is observed in the perpendicular distribution.

  6. Optimization of operation conditions for extracting lithium ions from calcium chloride-type oil field brine

    NASA Astrophysics Data System (ADS)

    Yang, Hong-jun; Li, Qing-hai; Li, Bing; Guo, Feng-qin; Meng, Qing-fen; Li, Wu

    2012-04-01

    Al(OH)3 was prepared to extract lithium ions from calcium chloride-type oil field brine. The influences of four factors, namely temperature, Al3+/Li+ molar ratio, OH-/Al3+ molar ratio, and contact time between Al(OH)3 and the brine, on the yield of lithium ions were investigated. It is found that their optimal values are 35°C, 4.5, 2.6, and 6 h, respectively. In the course of the experiment, the apparent pH value was observed. The results reveal that the apparent pH value has no remarkable influence on the yield of lithium ions. Meanwhile, the effects of the concentrations of calcium ions and magnesium ions in the brine on lithium recovery were studied. The results indicate that calcium ions have minor negative influence on the yield of lithium ions under optimal conditions, and magnesium ions slightly influence the yield of lithium ions.

  7. Measurement of deposition rate and ion energy distribution in a pulsed dc magnetron sputtering system using a retarding field analyzer with embedded quartz crystal microbalance.

    PubMed

    Sharma, Shailesh; Gahan, David; Scullin, Paul; Doyle, James; Lennon, Jj; Vijayaraghavan, Rajani K; Daniels, Stephen; Hopkins, M B

    2016-04-01

    A compact retarding field analyzer with embedded quartz crystal microbalance has been developed to measure deposition rate, ionized flux fraction, and ion energy distribution arriving at the substrate location. The sensor can be placed on grounded, electrically floating, or radio frequency (rf) biased electrodes. A calibration method is presented to compensate for temperature effects in the quartz crystal. The metal deposition rate, metal ionization fraction, and energy distribution of the ions arriving at the substrate location are investigated in an asymmetric bipolar pulsed dc magnetron sputtering reactor under grounded, floating, and rf biased conditions. The diagnostic presented in this research work does not suffer from complications caused by water cooling arrangements to maintain constant temperature and is an attractive technique for characterizing a thin film deposition system. PMID:27131678

  8. Measurement of deposition rate and ion energy distribution in a pulsed dc magnetron sputtering system using a retarding field analyzer with embedded quartz crystal microbalance

    NASA Astrophysics Data System (ADS)

    Sharma, Shailesh; Gahan, David; Scullin, Paul; Doyle, James; Lennon, Jj; Vijayaraghavan, Rajani K.; Daniels, Stephen; Hopkins, M. B.

    2016-04-01

    A compact retarding field analyzer with embedded quartz crystal microbalance has been developed to measure deposition rate, ionized flux fraction, and ion energy distribution arriving at the substrate location. The sensor can be placed on grounded, electrically floating, or radio frequency (rf) biased electrodes. A calibration method is presented to compensate for temperature effects in the quartz crystal. The metal deposition rate, metal ionization fraction, and energy distribution of the ions arriving at the substrate location are investigated in an asymmetric bipolar pulsed dc magnetron sputtering reactor under grounded, floating, and rf biased conditions. The diagnostic presented in this research work does not suffer from complications caused by water cooling arrangements to maintain constant temperature and is an attractive technique for characterizing a thin film deposition system.

  9. Electric field measurement in microwave discharge ion thruster with electro-optic probe.

    PubMed

    Ise, Toshiyuki; Tsukizaki, Ryudo; Togo, Hiroyoshi; Koizumi, Hiroyuki; Kuninaka, Hitoshi

    2012-12-01

    In order to understand the internal phenomena in a microwave discharge ion thruster, it is important to measure the distribution of the microwave electric field inside the discharge chamber, which is directly related to the plasma production. In this study, we proposed a novel method of measuring a microwave electric field with an electro-optic (EO) probe based on the Pockels effect. The probe, including a cooling system, contains no metal and can be accessed in the discharge chamber with less disruption to the microwave distribution. This method enables measurement of the electric field profile under ion beam acceleration. We first verified the measurement with the EO probe by a comparison with a finite-difference time domain numerical simulation of the microwave electric field in atmosphere. Second, we showed that the deviations of the reflected microwave power and the beam current were less than 8% due to inserting the EO probe into the ion thruster under ion beam acceleration. Finally, we successfully demonstrated the measurement of the electric-field profile in the ion thruster under ion beam acceleration. These measurements show that the electric field distribution in the thruster dramatically changes in the ion thruster under ion beam acceleration as the propellant mass flow rate increases. These results indicate that this new method using an EO probe can provide a useful guide for improving the propulsion of microwave discharge ion thrusters. PMID:23278009

  10. Electric field measurement in microwave discharge ion thruster with electro-optic probe

    SciTech Connect

    Ise, Toshiyuki; Tsukizaki, Ryudo; Koizumi, Hiroyuki; Togo, Hiroyoshi; Kuninaka, Hitoshi

    2012-12-15

    In order to understand the internal phenomena in a microwave discharge ion thruster, it is important to measure the distribution of the microwave electric field inside the discharge chamber, which is directly related to the plasma production. In this study, we proposed a novel method of measuring a microwave electric field with an electro-optic (EO) probe based on the Pockels effect. The probe, including a cooling system, contains no metal and can be accessed in the discharge chamber with less disruption to the microwave distribution. This method enables measurement of the electric field profile under ion beam acceleration. We first verified the measurement with the EO probe by a comparison with a finite-difference time domain numerical simulation of the microwave electric field in atmosphere. Second, we showed that the deviations of the reflected microwave power and the beam current were less than 8% due to inserting the EO probe into the ion thruster under ion beam acceleration. Finally, we successfully demonstrated the measurement of the electric-field profile in the ion thruster under ion beam acceleration. These measurements show that the electric field distribution in the thruster dramatically changes in the ion thruster under ion beam acceleration as the propellant mass flow rate increases. These results indicate that this new method using an EO probe can provide a useful guide for improving the propulsion of microwave discharge ion thrusters.

  11. Field ion spectrometry: a new technology for cocaine and heroin detection

    NASA Astrophysics Data System (ADS)

    Carnahan, Byron L.; Day, Stephen; Kouznetsov, Viktor; Tarassov, Alexandre

    1997-02-01

    Field ion spectrometry, also known as transverse field compensation ion mobility spectrometry, is a new technique for trace gas analysis that can be applied to the detection of cocaine and heroin. Its principle is based on filtering ion species according to the functional dependence of their mobilities with electric field strength. Field ion spectrometry eliminates the gating electrodes needed in conventional IMS to pulse ions into the spectrometer; instead, ions are injected in to the spectrometer and reach the detector continuously, resulting in improved sensitivity. The technique enables analyses that are difficult with conventional constant field strength ion mobility spectrometers. We have shown that a filed ion spectrometer can selectively detect the vapors from cocaine and heroin emitted from both their base and hydrochloride forms. The estimated volumetric limits of detection are in the low pptv range, based on testing with standardized drug vapor generation systems. The spectrometer can detect cocaine base in the vapor phase, at concentrations well below its estimated 100 pptv vapor pressure equivalent at 20 degrees C. This paper describes the underlying principles of field ion spectrometry in relation to narcotic drug detection, and recent results obtained for cocaine and heroin. The work has been sponsored in part by the United States Advanced Research Projects Agency under contract DAAB10-95C-0004, for the DOD Counterdrug Technology Development Program.

  12. Field ionization characteristics of an ion source array for neutron generators

    SciTech Connect

    B. Bargsten Johnson; P. R. Schwoebel; P. J. Resnick; C. E. Holland; L. Hertz; D. L. Chichester

    2013-11-01

    A new deuterium ion source is being developed to improve the performance of existing compact neutron generators. The ion source is a microfabricated array of metal tips with an integrated gate (i.e., grid) and produces deuterium ions by field ionizing (or field desorbing) a supply of deuterium gas. Deuterium field ion currents from arrays at source temperatures of 77?K and 293?K are studied. Ion currents from single etched-wire tips operating under the same conditions are used to help understand array results. I-F characteristics of the arrays were found to follow trends similar to those of the better understood single etched-wire tip results; however, the fields achieved by the arrays are limited by electrical breakdown of the structure. Neutron production by field ionization at 293?K was demonstrated for the first time from microfabricated array structures with integrated gates.

  13. Field ionization characteristics of an ion source array for neutron generators

    SciTech Connect

    Bargsten Johnson, B.; Schwoebel, P. R.; Resnick, P. J.; Holland, C. E.; Hertz, K. L.; Chichester, D. L.

    2013-11-07

    A new deuterium ion source is being developed to improve the performance of existing compact neutron generators. The ion source is a microfabricated array of metal tips with an integrated gate (i.e., grid) and produces deuterium ions by field ionizing (or field desorbing) a supply of deuterium gas. Deuterium field ion currents from arrays at source temperatures of 77 K and 293 K are studied. Ion currents from single etched-wire tips operating under the same conditions are used to help understand array results. I-F characteristics of the arrays were found to follow trends similar to those of the better understood single etched-wire tip results; however, the fields achieved by the arrays are limited by electrical breakdown of the structure. Neutron production by field ionization at 293 K was demonstrated for the first time from microfabricated array structures with integrated gates.

  14. Accelerated ions from pulsed-power-driven fast plasma flow in perpendicular magnetic field

    NASA Astrophysics Data System (ADS)

    Takezaki, Taichi; Takahashi, Kazumasa; Sasaki, Toru; Kikuchi, Takashi; Harada, Nob.

    2016-06-01

    To understand the interaction between fast plasma flow and perpendicular magnetic field, we have investigated the behavior of a one-dimensional fast plasma flow in a perpendicular magnetic field by a laboratory-scale experiment using a pulsed-power discharge. The velocity of the plasma flow generated by a tapered cone plasma focus device is about 30 km/s, and the magnetic Reynolds number is estimated to be 8.8. After flow through the perpendicular magnetic field, the accelerated ions are measured by an ion collector. To clarify the behavior of the accelerated ions and the electromagnetic fields, numerical simulations based on an electromagnetic hybrid particle-in-cell method have been carried out. The results show that the behavior of the accelerated ions corresponds qualitatively to the experimental results. Faster ions in the plasma flow are accelerated by the induced electromagnetic fields modulated with the plasma flow.

  15. Field-Reversal Source for Negative Halogen Ions

    NASA Technical Reports Server (NTRS)

    Chutjian, A.; Orient, O. J.; Aladzhadzhyan, S. H.

    1987-01-01

    Large zero-energy electron-attachment cross sections result in intense ion beams. Concept for producing negative halogen ions takes advantage of large cross sections at zero kinetic energy for dissociative attachment of electrons to such halogen-containing gases as SF6, CFCI3, and CCI4.

  16. Ion wake field effects on the dust-ion-acoustic surface mode in a semi-bounded Lorentzian dusty plasma

    NASA Astrophysics Data System (ADS)

    Lee, Myoung-Jae; Jung, Young-Dae

    2016-03-01

    The dispersion relation for the dust ion-acoustic surface waves propagating at the interface of semi-bounded Lorentzian dusty plasma with supersonic ion flow has been kinetically derived to investigate the nonthermal property and the ion wake field effect. We found that the supersonic ion flow creates the upper and the lower modes. The increase in the nonthermal particles decreases the wave frequency for the upper mode whereas it increases the frequency for the lower mode. The increase in the supersonic ion flow velocity is found to enhance the wave frequency for both modes. We also found that the increase in nonthermal plasmas is found to enhance the group velocity of the upper mode. However, the nonthermal particles suppress the lower mode group velocity. The nonthermal effects on the group velocity will be reduced in the limit of small or large wavelength limit.

  17. Octupole degree of freedom for the critical-point candidate nucleus {sup 152}Sm in a reflection-asymmetric relativistic mean-field approach

    SciTech Connect

    Zhang, W.; Li, Z. P.; Zhang, S. Q.; Meng, J.

    2010-03-15

    The potential energy surfaces of even-even {sup 146-156}Sm are investigated in the constrained reflection-asymmetric relativistic mean-field approach with parameter set PK1. It is shown that the critical-point candidate nucleus {sup 152}Sm marks the shape/phase transition not only from U(5) to SU(3) symmetry, but also from the octupole-deformed ground state in {sup 150}Sm to the quadrupole-deformed ground state in {sup 154}Sm. By including the octupole degree of freedom, an energy gap near the Fermi surface for single-particle levels in {sup 152}Sm with beta{sub 2}=0.14approx0.26 is found and the important role of the octupole deformation driving pair nu2f{sub 7/2} and nu1i{sub 13/2} is demonstrated.

  18. Electric field induced oscillating electron mobility in asymmetric wide GaAs/Al{sub x}Ga{sub 1−x}As quantum well structure

    SciTech Connect

    Sahoo, Narayan; Sahu, Trinath

    2014-07-28

    For the first time, we show that an oscillatory enhancement of low temperature electron mobility μ can be achieved in an asymmetric GaAs/Al{sub x}Ga{sub 1−x}As wide quantum well structure by applying an external electric field F perpendicular to the interface plane. We show that the oscillating nature of μ as a function of F is mostly due to the contribution of the higher subband through intersubband effects when there is double subband occupancy. We further show that the wavy nature of μ can be enhanced by increasing the well width, surface electron density, and also by considering a double quantum well structure. Our results can be utilized for low temperature device applications.

  19. Atom probe field ion microscopy and related topics: A bibliography 1990

    SciTech Connect

    Russell, K.F.; Miller, M.K.

    1991-12-01

    This bibliography includes references related to the following topics: atom probe field ion microscopy (APFIM), field ion microscopy (FIM), field emission (FE), ion sources, and field desorption mass microscopy (FDMM). Technique-orientated studies and applications are included. The bibliography covers the period 1990. The references contained in this document were compiled from a variety of sources including computer searches and personal lists of publications. To reduce the length of this document, the references have been reduced to the minimum necessary to locate the articles. The references, listed alphabetically by authors, are subdivided into the categories listed in paragraph one above. An Addendum of references missed in previous bibliographies is included.

  20. Electromagnetic fields and anomalous transports in heavy-ion collisions-a pedagogical review.

    PubMed

    Huang, Xu-Guang

    2016-07-01

    The hot and dense matter generated in heavy-ion collisions may contain domains which are not invariant under P and CP transformations. Moreover, heavy-ion collisions can generate extremely strong magnetic fields as well as electric fields. The interplay between the electromagnetic field and triangle anomaly leads to a number of macroscopic quantum phenomena in these P- and CP-odd domains known as anomalous transports. The purpose of this article is to give a pedagogical review of various properties of the electromagnetic fields, the anomalous transport phenomena, and their experimental signatures in heavy-ion collisions. PMID:27275776

  1. Electromagnetic fields and anomalous transports in heavy-ion collisions—a pedagogical review

    NASA Astrophysics Data System (ADS)

    Huang, Xu-Guang

    2016-07-01

    The hot and dense matter generated in heavy-ion collisions may contain domains which are not invariant under P and CP transformations. Moreover, heavy-ion collisions can generate extremely strong magnetic fields as well as electric fields. The interplay between the electromagnetic field and triangle anomaly leads to a number of macroscopic quantum phenomena in these P- and CP-odd domains known as anomalous transports. The purpose of this article is to give a pedagogical review of various properties of the electromagnetic fields, the anomalous transport phenomena, and their experimental signatures in heavy-ion collisions.

  2. Electrostatic ion instabilities in the presence of parallel currents and transverse electric fields

    NASA Technical Reports Server (NTRS)

    Ganguli, G.; Palmadesso, P. J.

    1988-01-01

    The electrostatic ion instabilities are studied for oblique propagation in the presence of magnetic field-aligned currents and transverse localized electric fields in a weakly collisional plasma. The presence of transverse electric fields result in mode excitation for magnetic field aligned current values that are otherwise stable. The electron collisions enhance the growth while ion collisions have a damping effect. These results are discussed in the context of observations of low frequency ion modes in the auroral ionosphere by radar and rocket experiments.

  3. Ion mobility sensor system

    DOEpatents

    Xu, Jun; Watson, David B.; Whitten, William B.

    2013-01-22

    An ion mobility sensor system including an ion mobility spectrometer and a differential mobility spectrometer coupled to the ion mobility spectrometer. The ion mobility spectrometer has a first chamber having first end and a second end extending along a first direction, and a first electrode system that generates a constant electric field parallel to the first direction. The differential mobility spectrometer includes a second chamber having a third end and a fourth end configured such that a fluid may flow in a second direction from the third end to the fourth end, and a second electrode system that generates an asymmetric electric field within an interior of the second chamber. Additionally, the ion mobility spectrometer and the differential mobility spectrometer form an interface region. Also, the first end and the third end are positioned facing one another so that the constant electric field enters the third end and overlaps the fluid flowing in the second direction.

  4. Measurements accounting for the impediment of ion spin-up in rotating magnetic field driven field reversed configurations

    SciTech Connect

    Deards, C. L.; Hoffman, A. L.; Steinhauer, L. C.

    2011-11-15

    Improved vacuum hygiene, wall conditioning, and reduced recycling in the rotating magnetic field (RMF) driven translation, confinement, and sustainment-upgrade (TCSU) field reversed configuration experiment have made possible a more accurate assessment of the forces affecting ion spin-up. This issue is critical in plasmas sustained by RMFs, such as TCSU since ion spin-up can substantially reduce or cancel the RMF current drive effect. Several diagnostics are brought to bear, including a 3-axis translatable magnetic probe allowing the first experimental measurement of the end shorting effect. These results show that the ion rotation is determined by a balance between electron-ion friction, the end shorting effect, and ion drag against neutrals.

  5. Measurements accounting for the impediment of ion spin-up in rotating magnetic field driven field reversed configurations

    NASA Astrophysics Data System (ADS)

    Deards, C. L.; Hoffman, A. L.; Steinhauer, L. C.

    2011-11-01

    Improved vacuum hygiene, wall conditioning, and reduced recycling in the rotating magnetic field (RMF) driven translation, confinement, and sustainment-upgrade (TCSU) field reversed configuration experiment have made possible a more accurate assessment of the forces affecting ion spin-up. This issue is critical in plasmas sustained by RMFs, such as TCSU since ion spin-up can substantially reduce or cancel the RMF current drive effect. Several diagnostics are brought to bear, including a 3-axis translatable magnetic probe allowing the first experimental measurement of the end shorting effect. These results show that the ion rotation is determined by a balance between electron-ion friction, the end shorting effect, and ion drag against neutrals.

  6. Kr II and Xe II axial velocity distribution functions in a cross-field ion source

    SciTech Connect

    Lejeune, A.; Bourgeois, G.; Mazouffre, S.

    2012-07-15

    Laser induced fluorescence measurements were carried out in a cross-field ion source to examine the behaviour of the axial ion velocity distribution functions (VDFs) in the expanding plasma. In the present paper, we focus on the axial VDFs of Kr II and Xe II ions. We examine the contourplots in a 1D-phase space (x,v{sub x}) representation in front of the exhaust channel and along the centerline of the ion source. The main ion beam, whose momentum corresponds to the ions that are accelerated through the whole potential drop, is observed. A secondary structure reveals the ions coming from the opposite side of the channel. We show that the formation of the neutralized ion flow is governed by the annular geometry. The assumption of a collisionless shock or a double layer due to supersonic beam interaction is not necessary. A non-negligible fraction of slow ions originates in local ionization or charge-exchange collision events between ions of the expanding plasma and atoms of the background residual gas. Slow ions that are produced near the centerline in the vicinity of the exit plane are accelerated toward the source body with a negative velocity leading to a high sputtering of front face. On the contrary, the ions that are produced in the vicinity of the channel exit plane are partially accelerated by the extended electric field.

  7. Kr II and Xe II axial velocity distribution functions in a cross-field ion source

    NASA Astrophysics Data System (ADS)

    Lejeune, A.; Bourgeois, G.; Mazouffre, S.

    2012-07-01

    Laser induced fluorescence measurements were carried out in a cross-field ion source to examine the behaviour of the axial ion velocity distribution functions (VDFs) in the expanding plasma. In the present paper, we focus on the axial VDFs of Kr II and Xe II ions. We examine the contourplots in a 1D-phase space (x,vx) representation in front of the exhaust channel and along the centerline of the ion source. The main ion beam, whose momentum corresponds to the ions that are accelerated through the whole potential drop, is observed. A secondary structure reveals the ions coming from the opposite side of the channel. We show that the formation of the neutralized ion flow is governed by the annular geometry. The assumption of a collisionless shock or a double layer due to supersonic beam interaction is not necessary. A non-negligible fraction of slow ions originates in local ionization or charge-exchange collision events between ions of the expanding plasma and atoms of the background residual gas. Slow ions that are produced near the centerline in the vicinity of the exit plane are accelerated toward the source body with a negative velocity leading to a high sputtering of front face. On the contrary, the ions that are produced in the vicinity of the channel exit plane are partially accelerated by the extended electric field.

  8. The onset of ion heating during magnetic reconnection with a strong guide field

    SciTech Connect

    Drake, J. F.; Swisdak, M.

    2014-07-15

    The onset of the acceleration of ions during magnetic reconnection is explored via particle-in-cell simulations in the limit of a strong ambient guide field that self-consistently and simultaneously follow the motions of protons and α particles. Heating parallel to the local magnetic field during reconnection with a guide field is strongly reduced compared with the reconnection of anti-parallel magnetic fields. The dominant heating of thermal ions during guide field reconnection results from pickup behavior of ions during their entry into reconnection exhausts and dominantly produces heating perpendicular rather than parallel to the local magnetic field. Pickup behavior requires that the ion transit time across the exhaust boundary (with a transverse scale of the order of the ion sound Larmor radius) be short compared with the ion cyclotron period. This translates into a threshold in the strength of reconnecting magnetic field that favors the heating of ions with high mass-to-charge. A simulation with a broad initial current layer produces a reconnecting system in which the amplitude of the reconnecting magnetic field just upstream of the dissipation region increases with time as reconnection proceeds. The sharp onset of perpendicular heating when the pickup threshold is crossed is documented. A comparison of the time variation of the parallel and perpendicular ion heating with that predicted based on the strength of the reconnecting field establishes the scaling of ion heating with ambient parameters both below and above the pickup threshold. The relevance to observations of ion heating in the solar corona is discussed.

  9. Neutralization of Space Charge Effects for Low Energy Ion Beams Using Field Emitters

    SciTech Connect

    Nicolaescu, D.; Sakai, S.; Matsuda, K.; Gotoh, Y.; Ishikawa, J.

    2008-11-03

    The paper presents models and computations for neutralization of space charge effects using electrons provided by field emitter arrays. Different ion species ({sup 11}B{sup +},{sup 31}P{sup +},{sup 75}As{sup +}) with energy in the range E{sub ion} = 200 eV-1 keV have been considered. The ion beam divergence is studied as a function of electron beam geometry and physical parameters (electron and ion energy, electron/ion current ratio I{sub el}/I{sub ion}). The electron beam geometry takes into account electron source positions and initial launching angles. It is shown that optimal ion beam neutralization occurs for low energy electrons emitted parallel to the ion beam.

  10. Ablation plasma transport using multicusp magnetic field for laser ion source

    NASA Astrophysics Data System (ADS)

    Takahashi, K.; Umezawa, M.; Uchino, T.; Ikegami, K.; Sasaki, T.; Kikuchi, T.; Harada, N.

    2016-05-01

    We propose a plasma guiding method using multicusp magnetic field to transport the ablation plasma keeping the density for developing laser ion sources. To investigate the effect of guiding using the magnetic field on the ablation plasma, we demonstrated the transport of the laser ablation plasma in the multicusp magnetic field. The magnetic field was formed with eight permanent magnets and arranged to limit the plasma expansion in the radial direction. We investigated the variation of the plasma ion current density and charge distribution during transport in the magnetic field. The results indicate that the plasma is confined in the radial direction during the transport in the multicusp magnetic field.

  11. On the analysis of inhomogeneous magnetic field spectrometer for laser-driven ion acceleration

    SciTech Connect

    Jung, D.; Senje, L.; McCormack, O.; Dromey, B.; Zepf, M.; Yin, L.; Albright, B. J.; Letzring, S.; Gautier, D. C.; Fernandez, J. C.; Toncian, T.; Hegelich, B. M.

    2015-03-15

    We present a detailed study of the use of a non-parallel, inhomogeneous magnetic field spectrometer for the investigation of laser-accelerated ion beams. Employing a wedged yoke design, we demonstrate the feasibility of an in-situ self-calibration technique of the non-uniform magnetic field and show that high-precision measurements of ion energies are possible in a wide-angle configuration. We also discuss the implications of a stacked detector system for unambiguous identification of different ion species present in the ion beam and explore the feasibility of detection of high energy particles beyond 100 MeV/amu in radiation harsh environments.

  12. Effects of the crustal magnetic fields on the Martian atmospheric ion escape rate

    NASA Astrophysics Data System (ADS)

    Ramstad, R.; Barbash, S.; Futaana, Y.; Nilsson, H.; Holmstrom, M.

    2015-12-01

    Eight years (2007-2015) of ion flux measurements from Mars Express are used to empirically investigate the influence of the Martian crustal magnetic fields on the atmospheric ion escape rate. We combine ASPERA-3/IMA (Analyzer of Space Plasmas and Energetic Atoms/Ion Mass Analyzer) measurements taken during nominal upstream solar wind and solar Extreme Ultraviolet (EUV) conditions to compute global average ion distribution functions for varying solar zenith angles (SZA) of the strongest crustal field. Escape rates are subsequently calculated from each of the average distribution functions. A statistically significant increase in escape rate is found for high dayside SZA, compared to low SZA.

  13. Building bio-inspired artificial functional nanochannels: from symmetric to asymmetric modification.

    PubMed

    Hou, Xu; Zhang, Huacheng; Jiang, Lei

    2012-05-29

    Over millions of years, complex processes of intelligent control have evolved in nature. Learning from nature is a continuing theme in the development of smart materials and intelligent systems. For example, biological nanochannels, which are typically ion channels, play a very important role in basic biochemical processes in cells. Inspired by ion channels, in which the components are asymmetrically distributed between the membrane surfaces, the generation of biomimetic smart nanochannels is a broad and varied scientific research field. The design and development of new biomimetic channels includes the use of different shapes of channels, different stimuli-responsive molecules, and different symmetric/asymmetric modification methods. In this Minireview, we summarize recent developments in building functional nanochannels by applying various symmetric and asymmetric modifications. PMID:22505178

  14. Influence of magnetic field on peristaltic flow of a Casson fluid in an asymmetric channel: Application in crude oil refinement

    NASA Astrophysics Data System (ADS)

    Sher Akbar, Noreen

    2015-03-01

    The influence of magnetic field on peristaltic flow of a Casson fluid model is considered. The model for peristaltic literature is modelled first time. The governing coupled equations are constructed under long wavelength and low Reynold's number approximation. Exact solutions are evaluated for stream function and pressure gradient. The important findings in this study are the variation of the Hartmann number M, Casson fluid parameter ζ and amplitudes a, b, d and ϕ. The velocity field increases due to increase in Hartmann number M near the channel walls while velocity field decreases at the centre of the channel.

  15. Transport of ions in presence of induced electric field and electrostatic turbulence - Source of ions injected into ring current

    NASA Technical Reports Server (NTRS)

    Cladis, J. B.; Francis, W. E.

    1985-01-01

    The transport of ions from the polar ionosphere to the inner magnetosphere during stormtime conditions has been computed using a Monte Carlo diffusion code. The effect of the electrostatic turbulence assumed to be present during the substorm expansion phase was simulated by a process that accelerated the ions stochastically perpendicular to the magnetic field with a diffusion coefficient proportional to the energization rate of the ions by the induced electric field. This diffusion process was continued as the ions were convected from the plasma sheet boundary layer to the double-spiral injection boundary. Inward of the injection boundary, the ions were convected adiabatically. By using as input an O(+) flux of 2.8 x 10 to the 8th per sq cm per s (w greater than 10 eV) and an H(+) flux of 5.5 x 10 to the 8th per sq cm per s (w greater than 0.63 eV), the computed distribution functions of the ions in the ring current were found to be in good agreement, over a wide range in L (4 to 8), with measurements made with the ISEE-1 satellite during a storm. This O(+) flux and a large part of the H(+) flux are consistent with the DE satellite measurements of the polar ionospheric outflow during disturbed times.

  16. Kinetic simulation of capacitively coupled plasmas driven by trapezoidal asymmetric voltage pulses

    SciTech Connect

    Diomede, Paola Economou, Demetre J.

    2014-06-21

    A kinetic Particle-In-Cell simulation with Monte Carlo Collisions was performed of a geometrically symmetric capacitively coupled, parallel-plate discharge in argon, driven by trapezoidal asymmetric voltage pulses with a period of 200 ns. The discharge was electrically asymmetric, making the ion energy distributions at the two electrodes different from one another. The fraction of the period (α), during which the voltage was kept at a constant (top-flat) positive value, was a critical control parameter. For the parameter range investigated, as α increased, the mean ion energy on the grounded electrode increased and the ions became more directional, whereas the opposite was found for the ions striking the powered electrode. The absolute value of the DC self-bias voltage decreased as α increased. Plasma instabilities, promoted by local double layers and electric field reversals during the time of the positive voltage excursion, were characterized by electron plasma waves launched from the sheath edge.

  17. Kinetic simulation of capacitively coupled plasmas driven by trapezoidal asymmetric voltage pulses

    NASA Astrophysics Data System (ADS)

    Diomede, Paola; Economou, Demetre J.

    2014-06-01

    A kinetic Particle-In-Cell simulation with Monte Carlo Collisions was performed of a geometrically symmetric capacitively coupled, parallel-plate discharge in argon, driven by trapezoidal asymmetric voltage pulses with a period of 200 ns. The discharge was electrically asymmetric, making the ion energy distributions at the two electrodes different from one another. The fraction of the period (α), during which the voltage was kept at a constant (top-flat) positive value, was a critical control parameter. For the parameter range investigated, as α increased, the mean ion energy on the grounded electrode increased and the ions became more directional, whereas the opposite was found for the ions striking the powered electrode. The absolute value of the DC self-bias voltage decreased as α increased. Plasma instabilities, promoted by local double layers and electric field reversals during the time of the positive voltage excursion, were characterized by electron plasma waves launched from the sheath edge.

  18. Heterogeneous and asymmetric crustal accretion: New constraints from multibeam bathymetry and potential field data from the Rainbow area of the Mid-Atlantic Ridge (36°15'N)

    NASA Astrophysics Data System (ADS)

    Paulatto, Michele; Canales, Juan Pablo; Dunn, Robert A.; Sohn, Robert A.

    2015-09-01

    At slow-spreading mid-ocean ridges, crustal accretion style can vary significantly along and across ridge segments. In magma-poor regions, seafloor spreading can be accommodated largely by tectonic processes, however, the internal structure and formation mechanism of such highly tectonized crust are not fully understood. We analyze multibeam bathymetry and potential field data from the Rainbow area of the Mid-Atlantic Ridge (35°40'N-36°40'N), a section of the ridge that shows diverse accretion styles. We identify volcanic, tectonized and sedimented terrain and measure exposed fault area to estimate the tectonic strain, T, and the fraction of magmatic accretion, M. Estimated T values range from 0.2-0.4 on ridge segments to 0.6-0.8 at the Rainbow nontransform discontinuity (NTD). At segment ends T is asymmetric, reflecting asymmetries in accretion rate, topography and faulting between inside and outside offset corners. Detachment faults have formed preferentially at inside corners, where tectonic strain is higher. We identify at least two oceanic core complexes on the fossil trace of the NTD, in addition to the Rainbow massif, which occupies the offset today. A gravity high and low magnetization suggest that the Rainbow massif, which hosts a high-temperature hydrothermal system, was uplifted by a west dipping detachment fault. Asymmetric plate ages indicate localization of tectonic strain at the inside corners and migration of the detachment toward and across the ridge axis, which may have caused emplacement of magma into the footwall. Hydrothermal circulation and heat extraction is possibly favored by increased permeability generated by fracturing of the footwall and deep-penetrating second-generation faults.

  19. Oscillating asymmetric dark matter

    SciTech Connect

    Tulin, Sean; Yu, Hai-Bo; Zurek, Kathryn M. E-mail: haiboyu@umich.edu

    2012-05-01

    We study the dynamics of dark matter (DM) particle-antiparticle oscillations within the context of asymmetric DM. Oscillations arise due to small DM number-violating Majorana-type mass terms, and can lead to recoupling of annihilation after freeze-out and washout of the DM density. Asymmetric DM oscillations 'interpolate' between symmetric and asymmetric DM freeze-out scenarios, and allow for a larger DM model-building parameter space. We derive the density matrix equations for DM oscillations and freeze-out from first principles using nonequilibrium field theory, and our results are qualitatively different than in previous studies. DM dynamics exhibits particle-vs-antiparticle 'flavor' effects, depending on the interaction type, analogous to neutrino oscillations in a medium. 'Flavor-sensitive' DM interactions include scattering or annihilation through a new vector boson, while 'flavor-blind' interactions include scattering or s-channel annihilation through a new scalar boson. In particular, we find that flavor-sensitive annihilation does not recouple when coherent oscillations begin, and that flavor-blind scattering does not lead to decoherence.

  20. Observations of the Ion Signatures of Double Merging and the Formation of Newly Closed Field Lines

    NASA Technical Reports Server (NTRS)

    Chandler, Michael O.; Avanov, Levon A.; Craven, Paul D.

    2007-01-01

    Observations from the Polar spacecraft, taken during a period of northward interplanetary magnetic field (IMF) show magnetosheath ions within the magnetosphere with velocity distributions resulting from multiple merging sites along the same field line. The observations from the TIDE instrument show two separate ion energy-time dispersions that are attributed to two widely separated (-20Re) merging sites. Estimates of the initial merging times show that they occurred nearly simultaneously (within 5 minutes.) Along with these populations, cold, ionospheric ions were observed counterstreaming along the field lines. The presence of such ions is evidence that these field lines are connected to the ionosphere on both ends. These results are consistent with the hypothesis that double merging can produce closed field lines populated by solar wind plasma. While the merging sites cannot be unambiguously located, the observations and analyses favor one site poleward of the northern cusp and a second site at low latitudes.

  1. Atmospheric Pressure Ion Source Development: Experimental Validation of Simulated Ion Trajectories within Complex Flow and Electrical Fields

    NASA Astrophysics Data System (ADS)

    Wissdorf, Walter; Lorenz, Matthias; Pöhler, Thorsten; Hönen, Herwart; Benter, Thorsten

    2013-10-01

    Three-dimensionally (3D) resolved ion trajectory calculations within the complex viscous flow field of an atmospheric pressure ion source are presented. The model calculations are validated with spatially resolved measurements of the relative sensitivity distribution within the source enclosure, referred to as the distribution of ion acceptance (DIA) of the mass analyzer. In previous work, we have shown that the DIA shapes as well as the maximum signal strengths strongly depend on ion source operational parameters such as gas flows and temperatures, as well as electrical field gradients established by various source electrode potentials (e.g., capillary inlet port potential and spray shield potential). In all cases studied, distinct, reproducible, and, to some extent, surprising DIA patterns were observed. We have thus attempted to model selected experimental operational source modes (called operational points) using a validated computational flow dynamics derived 3D-velocity field as an input parameter set for SIMION/SDS, along with a suite of custom software for data analysis and parameter set processing. Despite the complexity of the system, the modeling results reproduce the experimentally derived DIA unexpectedly well. It is concluded that SIMION/SDS in combination with accurate computational fluid dynamics (CFD) input data and adequate analysis software is capable of successfully modeling operational points of an atmospheric pressure ion (API) source. This approach should be very useful in the computer-aided design of future API sources.

  2. A new polarizable force field for alkali and halide ions

    SciTech Connect

    Kiss, Péter T.; Baranyai, András

    2014-09-21

    We developed transferable potentials for alkali and halide ions which are consistent with our recent model of water [P. T. Kiss and A. Baranyai, J. Chem. Phys. 138, 204507 (2013)]. Following the approach used for the water potential, we applied Gaussian charge distributions, exponential repulsion, and r{sup −6} attraction. One of the two charges of the ions is fixed to the center of the particle, while the other is connected to this charge by a harmonic spring to express polarization. Polarizability is taken from quantum chemical calculations. The repulsion between different species is expressed by the combining rule of Kong [J. Chem. Phys. 59, 2464 (1972)]. Our primary target was the hydration free energy of ions which is correct within the error of calculations. We calculated water-ion clusters up to 6 water molecules, and, as a crosscheck, we determined the density and internal energy of alkali-halide crystals at ambient conditions with acceptable accuracy. The structure of hydrated ions was also discussed.

  3. A new polarizable force field for alkali and halide ions

    NASA Astrophysics Data System (ADS)

    Kiss, Péter T.; Baranyai, András

    2014-09-01

    We developed transferable potentials for alkali and halide ions which are consistent with our recent model of water [P. T. Kiss and A. Baranyai, J. Chem. Phys. 138, 204507 (2013)]. Following the approach used for the water potential, we applied Gaussian charge distributions, exponential repulsion, and r-6 attraction. One of the two charges of the ions is fixed to the center of the particle, while the other is connected to this charge by a harmonic spring to express polarization. Polarizability is taken from quantum chemical calculations. The repulsion between different species is expressed by the combining rule of Kong [J. Chem. Phys. 59, 2464 (1972)]. Our primary target was the hydration free energy of ions which is correct within the error of calculations. We calculated water-ion clusters up to 6 water molecules, and, as a crosscheck, we determined the density and internal energy of alkali-halide crystals at ambient conditions with acceptable accuracy. The structure of hydrated ions was also discussed.

  4. Hydrogen migration in methanol studied under asymmetric fs laser irradiation

    NASA Astrophysics Data System (ADS)

    Kotsina, N.; Kaziannis, S.; Kosmidis, C.

    2014-06-01

    Hydrogen migration processes in deuterated methanol (CH3OD) under the irradiation of ultrashort (30 fs) two color (400/800 nm) laser field have been investigated by means of time-of-flight mass spectrometry. The utilization of an asymmetric ω/2ω laser field contributes to a better understanding of hydrogen migration processes. Based on the comparative study of the asymmetry dependence and the angular distributions of the H2D+, HOD+ and H2OD+ fragment ions, whose formation requires hydrogen migration, it was feasible to distinguish the most probable site of the molecular skeleton where the hydrogen migrates from.

  5. Self-organized field structures in electron-depleted multi-ion dusty plasma

    NASA Astrophysics Data System (ADS)

    Iqbal, M.; Gondal, S. M.; Shuaib, A.; Qurat-Ul-Ain

    2015-06-01

    It is shown that there exists a strong interaction between the magnetic and kinetic aspects of a multi-ion plasma. The interaction appears as a system of simultaneous equations which show the alignment of vortices to flows and satisfy the Beltrami condition. Solving these equations lead to a non-force-free magnetic field which can be cast as a superposition of three multiscale force-free magnetic field configurations. It is the consequence of different Beltrami parameters of positive and negative ion fluids. It is also shown that self-organized paramagnetic and diamagnetic field structures could be created by varying the vorticities and flows of ion fluids.

  6. Electric field-controlled water permeation coupled to ion transport through a nanopore

    NASA Astrophysics Data System (ADS)

    Dzubiella, J.; Allen, R. J.; Hansen, J.-P.

    2004-03-01

    We report molecular dynamics simulations of a generic hydrophobic nanopore connecting two reservoirs which are initially at different Na+ concentrations, as in a biological cell. The nanopore is impermeable to water under equilibrium conditions, but the strong electric field caused by the ionic concentration gradient drives water molecules in. The density and structure of water in the pore are highly field dependent. In a typical simulation run, we observe a succession of cation passages through the pore, characterized by approximately bulk mobility. These ion passages reduce the electric field, until the pore empties of water and closes to further ion transport, thus providing a possible mechanism for biological ion channel gating.

  7. Ion exchange with the solar wind for planets with negligible intrinsic magnetic fields

    NASA Technical Reports Server (NTRS)

    Nisbet, J. S.

    1979-01-01

    The exchange of ions between the ionosphere of a planet with negligible intrinsic magnetic field, and the solar wind is examined. It is suggested that a balance exists between the outflow of ionospheric ions at the plasmapause and ions from the solar wind in a restricted region close to the subsolar point. This results in a current system towards the subsolar point on the surface of the ionopause and a toroidal magnetic field. Simple calculations are made of the current and field configuration that might result from the system for conditions similar to those encountered on the Viking 1 and 2 transits of the Mars ionosphere.

  8. Asymmetric Flow Field Flow Fractionation of Aqueous C60 Nanoparticles with Size Determination by Dynamic Light Scattering and Quantification by Liquid Chromatography Atmospheric Pressure Photo-Ionization Mass Spectrometry

    EPA Science Inventory

    A size separation method was developed for aqueous C60 fullerene aggregates (aqu/C60) using asymmetric flow field flow fractionation (AF4) coupled to a dynamic light scattering detector in flow through mode. Surfactants, which are commonly used in AF4, were avoided as they may al...

  9. Highly Charged Ions from Laser-Cluster Interactions: Local-Field-Enhanced Impact Ionization and Frustrated Electron-Ion Recombination

    SciTech Connect

    Fennel, Thomas; Ramunno, Lora; Brabec, Thomas

    2007-12-07

    Our molecular dynamics analysis of Xe{sub 147-5083} clusters identifies two mechanisms that contribute to the yet unexplained observation of extremely highly charged ions in intense laser cluster experiments. First, electron impact ionization is enhanced by the local cluster electric field, increasing the highest charge states by up to 40%; a corresponding theoretical method is developed. Second, electron-ion recombination after the laser pulse is frustrated by acceleration electric fields typically used in ion detectors. This increases the highest charge states by up to 90%, as compared to the usual assumption of total recombination of all cluster-bound electrons. Both effects together augment the highest charge states by up to 120%, in reasonable agreement with experiments.

  10. Plasma wave, magnetic field and energetic ion observations in the ion pick-up region of Comet Giacobini-Zinner

    NASA Astrophysics Data System (ADS)

    Richardson, I. G.; Cowley, S. W. H.; Wenzel, K.-P.; Scarf, F. L.; Smith, E. J.; Tsurutani, B. T.; Sanderson, T. R.; Hynds, R. J.

    Simultaneous plasma wave, magnetic field, and energetic ion observations made by the ICE spacecraft in the extended ion pick-up region surrounding comet Giacobini-Zinner are examined to determine the conditions under which two characteristic wave emissions, electrostatic waves at a few kHz, and electromagnetic waves at a few tens of Hz, are generated. The data are consistent with the view that the kHz electrostatic emissions result from an instability of the pick-up photoelectron 'beam' produced when the angle alpha between the magnetic field and the solar wind velocity vector is less than about 60 deg, while the behavior of the tens of Hz electromagnetic waves suggests that they are generated by the pick-up ion 'ring' which is present when alpha exceeds about 60 deg.

  11. High-order harmonic generation on atoms and ions with laser fields of relativistic intensities

    SciTech Connect

    Avetissian, H. K.; Markossian, A. G.; Mkrtchian, G. F.

    2011-07-15

    High-order harmonic generation (HHG) by hydrogenlike atoms or ions in the field of counterpropagating laser beams of standing-wave configuration, with linear polarizations and relativistic intensities, is studied. The relativistic quantum theory of HHG in such field configurations (homogeneous), at which the impeding factor of relativistic magnetic drift of superstrong laser fields can be eliminated, is presented.

  12. Effect of the inductive electric field on ion flow in tokamaks

    SciTech Connect

    Catto, Peter J.; Hastie, R. J.; Hutchinson, I. H.; Helander, P.

    2001-07-01

    The effect of the inductive electric field of a tokamak on the parallel (and poloidal) ion flow in the banana regime is evaluated. It is demonstrated that the flow is in the direction of the parallel current and is surprisingly large -- comparable to the usual banana regime ion temperature gradient drive.

  13. Modified ion-acoustic solitary waves in plasmas with field-aligned shear flows

    SciTech Connect

    Saleem, H.; Haque, Q.

    2015-08-15

    The nonlinear dynamics of ion-acoustic waves is investigated in a plasma having field-aligned shear flow. A Korteweg-deVries-type nonlinear equation for a modified ion-acoustic wave is obtained which admits a single pulse soliton solution. The theoretical result has been applied to solar wind plasma at 1 AU for illustration.

  14. Characterization of ultrahigh-molecular weight cationic polyacrylamide using frit-inlet asymmetrical flow field-flow fractionation and multi-angle light scattering.

    PubMed

    Woo, Sohee; Lee, Ju Yong; Choi, Woonjin; Moon, Myeong Hee

    2016-01-15

    In this study, frit inlet asymmetrical flow field-flow fractionation (FlFFF) with multi-angle light scattering (MALS) and differential refractive index (DRI) detection is utilized for size separation, determination of molecular weight (MW), and conformation of ultrahigh-MW (10(7)-10(9) g/mol) cationic polyacrylamides (C-PAMs), a class of water-soluble copolymers based on acrylamide and vinyl-type comonomers with quaternary ammonium cations that are widely used in wastewater treatment and in paper industries. Linear and branched C-PAM copolymers prepared in two different polymerization methods (solution and emulsion) from varying amounts of crosslinking agent and initiator were size fractionated by FlFFF with field-programming. It was found experimentally that the linear copolymers from both polymerization methods were less than 10(8) g/mol in MW with compact, nearly spherical structures, while the branched C-PAM copolymers from the emulsion polymerization showed a significant increase in average MW up to ∼ 10(9)g/mol, which was about 20-fold greater than those from the solution method, and the branched copolymers had more compact or shrunken conformations. While both linear and branched copolymers less than 10(8) g/mol MW were well resolved in an increasing order of MW (normal mode), it was noted that branched copolymers prepared through emulsion polymerization exhibited significantly larger MWs of 10(8-)10(9) g/mol and eluted in the steric/hyperlayer mode, in which the elution order is reversed in an extreme run condition (strong initial field strength followed by a fast field decay during programming). PMID:26724894

  15. Spin wave mode coexistence on the nanoscale: A consequence of the Oersted field induced asymmetric energy landscape

    NASA Astrophysics Data System (ADS)

    Dumas, Randy

    2014-03-01

    The emerging field of magnonics relies on the systematic generation, manipulation, and detection of spin waves (SWs). Nanocontact spin torque oscillators (NC-STOs) provide an ideal platform to study spin transfer torque induced SW emission. In analogy to two species competing for the same food supply it has been argued that only one SW mode can survive in the steady state. However, as evidenced in many experiments clear signatures of mode-hopping are often observed. Here, we present a third possibility, namely that under the correct experimental conditions, mode coexistencecan be realized in NC-STOs. Micromagnetic simulations reveal that the SW modes are spatially separated under the NC. Mode coexistence is facilitated by the local field asymmetries induced by the spatially inhomogeneous Oersted field in the vicinity of the NC and further promoted by SW localization. Finally, both simulation and experiment reveal a weak low frequency signal exactly at the difference of the mode frequencies, consistent with inter-modulation of two coexistent modes. The Swedish Research Council, The Swedish Foundation for Strategic Research, and the Knut and Alice Wallenberg Foundation are acknowledged. ANL is a US DOE Science Laboratory operated under contract no. DE-AC02-06CH11357 by UChicago Argonne, LLC.

  16. Correlated plasma wave, magnetic field, and energetic ion observations in the ion pickup region of Comet Giacobini-Zinner

    NASA Astrophysics Data System (ADS)

    Richardson, I. G.; Wenzel, K.-P.; Cowley, S. W. H.; Scarf, F. L.; Smith, E. J.; Tsurutani, B. T.; Sanderson, T. R.; Hynds, R. J.

    1989-01-01

    Relationships between simultaneous plasma wave, magnetic field, and energetic heavy ion data obtained by the International Cometary Explorer (ICE) spacecraft in the large-scale solar wind particle pickup region surrounding Comet Giacobini-Zinner are examined. In particular, consideration is given to the conditions under which electrostatic emissions at frequencies of a few kilohertz and electromagnetic waves at a few tens of hertz are observed. It is shown that the data are consistent with the view that the kilohertz electrostatic emissions result from a beam-type instability excited by the pickup photoelectron population when the angle alpha between the magnetic field and the plasma velocity vectors is not too large. The data also suggest that the few tens of hertz electromagnetic waves may be excited by a ring-type instability associated with the pickup ion population, which occurs when the magnetic field is near to orthogonality with the flow.

  17. Effect of mobile ions on the electric field needed to orient charged diblock copolymer thin films

    SciTech Connect

    Dehghan, Ashkan; Shi, An-Chang; Schick, M.

    2015-10-07

    We examine the behavior of lamellar phases of charged/neutral diblock copolymer thin films containing mobile ions in the presence of an external electric field. We employ self-consistent field theory and focus on the aligning effect of the electric field on the lamellae. Of particular interest are the effects of the mobile ions on the critical field, the value required to reorient the lamellae from the parallel configuration favored by the surface interaction to the perpendicular orientation favored by the field. We find that the critical field depends strongly on whether the neutral or charged species is favored by the substrates. In the case in which the neutral species is favored, the addition of charges decreases the critical electric field significantly. The effect is greater when the mobile ions are confined to the charged lamellae. In contrast, when the charged species is favored by the substrate, the addition of mobile ions stabilizes the parallel configuration and thus results in an increase in the critical electric field. The presence of ions in the system introduces a new mixed phase in addition to those reported previously.

  18. Formation of field-reversed ion rings in a magnetized background plasma

    SciTech Connect

    Omelchenko, Y.A.; Sudan, R.N.

    1995-07-01

    In typical field-reversed ion ring experiments, an intense annular ion beam is injected across a magnetic cusp into neutral gas immersed in a solenoidal magnetic field. In anticipation of a new experimental thrust to create strong field-reversed ion rings the beam evolution is investigated in a preformed background plasma on a time scale greater than an ion cyclotron period, using a new two and a half-dimensional (21/2-D) hybrid, particle-in-cell (PIC) code FIRE, in which the beam and background ions are treated as macro-particles and the electrons as a massless fluid. It is shown that under appropriate conditions axial beam bunching occurs in the downstream applied field and a compact field-reversed ring is formed. It is observed that the ring is reflected in a ramped magnetic field. Upon reflection its axial velocity is very much less than that expected from a single particle model due to the transfer of the mean axial momentum to the background ions. This increases the time available to apply a pulsed mirror for trapping the ring experimentally. {copyright} {ital 1995} {ital American} {ital Institute} {ital of} {ital Physics}.

  19. Generation of Isolated Attosecond Pulse from Asymmetric Molecular Ions by Introducing Half-Cycle-Like Laser Fields

    NASA Astrophysics Data System (ADS)

    Liu, Sha-Sha; Miao, Xiang-Yang

    2015-06-01

    Not Available Supported by the National Natural Science Foundation of China under Grant No 11404204, the Key Project of the Ministry of Education of China under Grant No 211025, the Research Fund for the Doctoral Program of Higher Education of China under Grant No 20111404120004, and the Natural Science Foundation for Young Scientists of Shanxi Province under Grant No 2009021005.

  20. Coupled acoustic-gravity field for dynamic evaluation of ion exchange with a single resin bead.

    PubMed

    Kanazaki, Takahiro; Hirawa, Shungo; Harada, Makoto; Okada, Tetsuo

    2010-06-01

    A coupled acoustic-gravity field is efficient for entrapping a particle at the position determined by its acoustic properties rather than its size. This field has been applied to the dynamic observation of ion-exchange reactions occurring in a single resin bead. The replacement of counterions in an ion-exchange resin induces changes in its acoustic properties, such as density and compressibility. Therefore, we can visually trace the advancement of an ion-exchange reaction as a time change in the levitation position of a resin bead entrapped in the field. Cation-exchange reactions occurring in resin beads with diameters of 40-120 microm are typically completed within 100-200 s. Ion-exchange equilibrium or kinetics is often evaluated with off-line chemical analyses, which require a batch amount of ion exchangers. Measurements with a single resin particle allow us to evaluate ion-exchange dynamics and kinetics of ions including those that are difficult to measure by usual off-line analyses. The diffusion properties of ions in resins have been successfully evaluated from the time change in the levitation positions of resin beads. PMID:20462180

  1. Systematically Asymmetric Heliospheric Magnetic Field: Evidence for a Quadrupole Mode and Non-Axisymmetry with Polarity Flip-Flops

    NASA Astrophysics Data System (ADS)

    Mursula, K.; Hiltula, T.

    2004-10-01

    Recent studies of the heliospheric magnetic field (HMF) have detected interesting, systematic hemispherical and longitudinal asymmetries which have a profound significance for the understanding of solar magnetic fields. The in situ HMF measurements since the 1960s show that the heliospheric current sheet (HCS) is systematically shifted (coned) southward during solar minimum times, leading to the concept of a bashful ballerina. While temporary shifts can be considerably larger, the average HCS shift (coning) angle is a few degrees, less than the 7.2∘ tilt of the solar rotation axis. Recent solar observations during the last two solar cycles verify these results and show that the magnetic areas in the northern solar hemisphere are larger and their intensity weaker than in the south during long intervals in the late declining to minimum phase. The multipole expansion reveals a strong quadrupole term which is oppositely directed to the dipole term. These results imply that the Sun has a symmetric quadrupole S0 dynamo mode that oscillates in phase with the dominant dipole A0 mode. Moreover, the heliospheric magnetic field has a strong tendency to produce solar tilts that are roughly opposite in longitudinal phase. This implies is a systematic longitudinal asymmetry and leads to a “flip-flop” type behaviour in the dominant HMF sector whose period is about 3.2 years. This agrees very well with the similar flip-flop period found recently in sunspots, as well as with the observed ratio of three between the activity cycle period and the flip-flop period of sun-like stars. Accordingly, these results require that the solar dynamo includes three modes, A0, S0 and a non-axisymmetric mode. Obviously, these results have a great impact on solar modelling.

  2. Kinetic response of ionospheric ions to onset of auroral electric fields

    NASA Technical Reports Server (NTRS)

    Chiu, Y. T.; Kan, J. R.

    1981-01-01

    By examining the exact analytic solution of a kinetic model of collisional interaction of ionospheric ions with atmospheric neutrals in the Bhatnagar-Gross-Krook approximation, we show that the onset of intense auroral electric fields in the topside ionosphere can produce the following kinetic effects: (1) heat the bulk ionospheric ions to approximately 2 eV, thus driving them up to higher altitudes where they can be subjected to collisionless plasma processes; (2) produce a non-Maxwellian superthermal tail in the distribution function; and (3) cause the ion distribution function to be anisotropic with respect to the magnetic field with the perpendicular average thermal energy exceeding the parallel thermal energy.

  3. Computation of two-dimensional electric field from the ion laser induced fluorescence measurements

    SciTech Connect

    Spektor, Rostislav

    2010-09-15

    This paper presents a method of computing two-dimensional electric field from ion laser induced fluorescence (LIF) measurements in a plasma flow. The expression for the field is derived by taking velocity moments of the Boltzmann equation for ions. It was found that the pressure tensor, related to the width of the ion velocity distribution, plays a critical role in the computation of the electric field. Even with the assumption of cold ion flow, the pressure tensor contribution may be significant when velocity spread is caused by other forces. Such a situation occurs in the flow of a Hall thruster, where velocity spread is caused by the ions born at different potentials. LIF measurements of the cylindrical hall thruster plume were used to demonstrate practical application of the derived method. Whenever the pressure tensor components are small as compared to the mean ion drift velocity, the electric field calculations reduce to a simple expression given in terms of mean ion drift velocity and its divergence.

  4. Electric Field-Controlled Ion Transport In TiO2 Nanochannel.

    PubMed

    Li, Dan; Jing, Wenheng; Li, Shuaiqiang; Shen, Hao; Xing, Weihong

    2015-06-01

    On the basis of biological ion channels, we constructed TiO2 membranes with rigid channels of 2.3 nm to mimic biomembranes with flexible channels; an external electric field was employed to regulate ion transport in the confined channels at a high ionic strength in the absence of electrical double layer overlap. Results show that transport rates for both Na+ and Mg2+ were decreased irrespective of the direction of the electric field. Furthermore, a voltage-gated selective ion channel was formed, the Mg2+ channel closed at -2 V, and a reversed relative electric field gradient was at the same order of the concentration gradient, whereas the Na+ with smaller Stokes radius and lower valence was less sensitive to the electric field and thus preferentially occupied and passed the channel. Thus, when an external electric field is applied, membranes with larger nanochannels have promising applications in selective separation of mixture salts at a high concentration. PMID:25961963

  5. Electric-Field-Induced Dissociation of Heavy Rydberg Ion-Pair States

    SciTech Connect

    Reinhold, Carlos O; Yoshida, S.; Dunning, F. B.

    2011-01-01

    A classical trajectory Monte Carlo approach is used to simulate the dissociation of H+..F and K+..Cl heavy Rydberg ion pairs induced by a ramped electric-field, a technique used experimentally to detect and probe ion-pair states. The simulations include the effects of the strong short-range repulsive interaction associated with ion-pair scattering and provide results in good agreement with experimental data for Stark wavepackets probed by a ramped field, demonstrating that many of the characteristics of field-induced dissociation can be well described using a purely classical model. The data also show that states with a given value of principal quantum number (i.e., binding energy) can dissociate over a broad range of applied fields, the exact field being governed by the initial orbital angular momentum and orientation of the state.

  6. Cellular defibrillation: interaction of micro-scale electric fields with voltage-gated ion channels.

    PubMed

    Kargol, Armin; Malkinski, Leszek; Eskandari, Rahmatollah; Carter, Maya; Livingston, Daniel

    2015-09-01

    We study the effect of micro-scale electric fields on voltage-gated ion channels in mammalian cell membranes. Such micro- and nano-scale electric fields mimic the effects of multiferroic nanoparticles that were recently proposed [1] as a novel way of controlling the function of voltage-sensing biomolecules such as ion channels. This article describes experimental procedures and initial results that reveal the effect of the electric field, in close proximity of cells, on the ion transport through voltage-gated ion channels. We present two configurations of the whole-cell patch-clamping apparatus that were used to detect the effect of external stimulation on ionic currents and discuss preliminary results that indicate modulation of the ionic currents consistent with the applied stimulus. PMID:26067055

  7. Fabrication of specimens of metamorphic magnetite crystals for field ion microscopy and atom probe microanalysis.

    PubMed

    Kuhlman, K R; Martens, R L; Kelly, T F; Evans, N D; Miller, M K

    2001-10-01

    Field ion specimens have been successfully fabricated from samples of metamorphic magnetite crystals (Fe3O4) extracted from a polymetamorphosed, granulite-facies marble with the use of a focused ion beam. These magnetite crystals contain nanometer-scale, disk-shaped inclusions making this magnetite particularly attractive for investigating the capabilities of atom probe field ion microscopy (APFIM) for geological materials. Field ion microscope images of these magnetite crystals were obtained in which the observed size and morphology of the precipitates agree with previous results. Samples were analyzed in the energy compensated optical position-sensitive atom probe. Mass spectra were obtained in which peaks for singly ionized 16O, 56Fe and 56FeO and doubly ionized 54Fe, 56Fe and 57Fe peaks were fully resolved. Manganese and aluminum were observed in a limited analysis of a precipitate in an energy compensated position sensitive atom probe. PMID:11770743

  8. Changes in mobile phase ion distribution when combining pressurized flow and electric field.

    PubMed

    Eriksson, Björn O; Dahl, Magnus; Andersson, Magnus B O; Blomberg, Lars G

    2004-10-01

    The distribution of ions in a capillary with both pressurized flow and an electric field has been studied. We have earlier reported that the overall concentration of ions increase in a capillary with high electric field and a pressurized flow. Now we describe how the ions are distributed in the capillary both along the capillary length and in the radial direction as a result of the parabolic flow profile. We have combined current measurements with finite element techniques in order to get better understanding of the system. We have found that the concentration of the ions that because of the electric mobility moves towards the flow primarily increases at the beginning of the electric field and close to the capillary wall. In view of the results we have proposed an alterative explanation of earlier published results concerning voltage-induced variation in capacity factors. PMID:15472979

  9. Nonthermal ions and associated magnetic field behavior at a quasi-parallel earth's bow shock

    NASA Technical Reports Server (NTRS)

    Wilkinson, W. P.; Pardaens, A. K.; Schwartz, S. J.; Burgess, D.; Luehr, H.; Kessel, R. L.; Dunlop, M.; Farrugia, C. J.

    1993-01-01

    Attention is given to ion and magnetic field measurements at the earth's bow shock from the AMPTE-UKS and -IRM spacecraft, which were examined in high time resolution during a 45-min interval when the field remained closely aligned with the model bow shock normal. Dense ion beams were detected almost exclusively in the midst of short-duration periods of turbulent magnetic field wave activity. Many examples of propagation at large elevation angles relative to the ecliptic plane, which is inconsistent with reflection in the standard model shock configuration, were discovered. The associated waves are elliptically polarized and are preferentially left-handed in the observer's frame of reference, but are less confined to the maximum variance plane than other previously studied foreshock waves. The association of the wave activity with the ion beams suggests that the former may be triggered by an ion-driven instability, and possible candidates are discussed.

  10. Measurements of the Ion Species of Cathodic Arc Plasma in an Axial Magnetic Field

    SciTech Connect

    Oks, Efim; Anders, Andre

    2010-10-19

    Metal and gas ion species and their charge state distributions were measured for pulsed copper cathodic arcs in argon background gas in the presence of an axial magnetic field. It was found that changing the cathode position relative to anode and ion extraction system as well as increasing the gas pressure did not much affect the arc burning voltage and the related power dissipation. However, the burning voltage and power dissipation greatly increased as the magnetic field strength was increased. The fraction of metal ions and the mean ion charge state were reduced as the discharge length was increased. The observations can be explained by the combination of charge exchange collisions and electron impact ionization. They confirm that previously published data on characteristic material-dependent charge state distributions (e.g., Anders and Yushkov, J. Appl. Phys., Vol. 91, pp. 4824-4832, 2002) are not universal but valid for high vacuum conditions and the specifics of the applied magnetic fields.

  11. Study on aggregation behavior of low density lipoprotein in hen egg yolk plasma by asymmetrical flow field-flow fractionation coupled with multiple detectors.

    PubMed

    Dou, Haiyang; Magnusson, Emma; Choi, Jaeyeong; Duan, Fei; Nilsson, Lars; Lee, Seungho

    2016-02-01

    In this study, asymmetrical flow field-flow fractionation (AF4) coupled online with UV, multiangle light scattering (MALS), and fluorescence (FS) detectors (AF4-UV-MALS-FS) was employed for separation and characterization of egg yolk plasma. AF4 provided separation of three major components of the egg yolk plasma i.e. soluble proteins, low density lipoproteins (LDL) and their aggregates, based on their respective hydrodynamic sizes. Identification of LDL was confirmed by staining the sample with a fluorescent dye, Nile Red. The effect of carrier liquids on aggregation of LDL was investigated. Collected fractions of soluble proteins were characterized using sodium dodecylsulfate polyacrylamide gel electrophoresis (SDS-PAGE). Moreover, the effect of heat and enzymatic treatment on egg yolk plasma was investigated. The results suggest that enzymatic treatment with phospholipase A2 (PLA2) significantly enhances the heat stability of LDL. The results show that AF4-UV-MALS-FS is a powerful tool for the fractionation and characterization of egg yolk plasma components. PMID:26304341

  12. Asymmetric flow field-flow fractionation coupled to inductively coupled plasma mass spectrometry for the quantification of quantum dots bioconjugation efficiency.

    PubMed

    Menéndez-Miranda, Mario; Encinar, Jorge Ruiz; Costa-Fernández, José M; Sanz-Medel, Alfredo

    2015-11-27

    Hyphenation of asymmetric flow field-flow fractionation (AF4) to an on-line elemental detection (inductively coupled plasma-mass spectrometry, ICP-MS) is proposed as a powerful diagnostic tool for quantum dots bioconjugation studies. In particular, conjugation effectiveness between a "model" monoclonal IgG antibody (Ab) and CdSe/ZnS core-shell Quantum Dots (QDs), surface-coated with an amphiphilic polymer, has been monitored here by such hybrid AF4-ICP-MS technique. Experimental conditions have been optimized searching for a proper separation between the sought bioconjugates from the eventual free reagents excesses employed during the bioconjugation (QDs and antibodies). Composition and pH of the carrier have been found to be critical parameters to ensure an efficient separation while ensuring high species recovery from the AF4 channel. An ICP-MS equipped with a triple quadropole was selected as elemental detector to enable sensitive and reliable simultaneous quantification of the elemental constituents, including sulfur, of the nanoparticulated species and the antibody. The hyphenated technique used provided nanoparticle size-based separation, elemental detection, and composition analysis capabilities that turned out to be instrumental in order to investigate in depth the Ab-QDs bioconjugation process. Moreover, the analytical strategy here proposed allowed us not only to clearly identify the bioconjugation reaction products but also to quantify nanoparticle:antibodies bioconjugation efficiency. This is a key issue in future development of analytical and bioanalytical photoluminescent QDs applications. PMID:26493473

  13. Ion-sensitive field effect transistors for pH and potassium ion concentration sensing: towards detection of myocardial ischemia

    NASA Astrophysics Data System (ADS)

    Rai, Pratyush; Jung, Soyoun; Ji, Taeksoo; Varadan, Vijay K.

    2008-03-01

    Ion Sensitive Field Effect Transistors (ISFETs) for sensing change in ionic concentration in biological systems can be used for detecting critical conditions like Myocardial Ischemia. Having the ability to yield steady signal characteristics can be used to observe the ionic concentration gradients which mark the onset of ischemia. Two ionic concentrations, pH and [K +], have been considered as the indicator for Myocardial Ischemia in this study. The ISFETs in this study have an organic semi-conductor film as the electronically active component. Poly-3 hexylthiophene was chosen for its compatibility to the solution processing, which is a simple and economical method of thin film fabrication. The gate electrode, which regulates the current in the active layer, has been employed as the sensor element. The devices under study here were fabricated on a flexible substrate PEN. The pH sensor was designed with the Tantalum Oxide gate dielectric as the ion selective component. The charge accumulated on the surface of the metal oxide acts as the source of the effecter electric field. The device was tested for pH values between 6.5 and 7.5, which comprises the variation observed during ischemic attack. The potassium ion sensor has got a floating gate electrode which is functionalized to be selective to potassium ion. The device was tested for potassium ion concentration between 5 and 25 mM, which constitutes the variation in extra cellular potassium ion concentration during ischemic attack. The device incorporated a monolayer of Valinomycin, a potassium specific ionophore, on top of the gate electrode.

  14. Role of the electric field in selective ion filtration in nanostructures.

    PubMed

    Park, Yong; Kim, Sueon; Jang, In Hyuk; Nam, Young Suk; Hong, Hiki; Choi, Dukhyun; Lee, Won Gu

    2016-02-21

    Nafion has received great attention as a proton conductor that can block negative ions. Here, we report the effect of a Nafion coating on an anodic aluminium oxide (AAO) nanoporous membrane on its function of ion rejection and filtering depending on the electric field. In our experiments, Nafion, once coated, was used to repel the negative ions (anions) from the coated surface, and then selectively allowed positive ions (cations) to pass through the nanopores in the presence of an electric field. To demonstrate the proof-of-concept validation, we coated Nafion solution onto the surface of AAO membranes with 20 nm nanopores average diameter at different solution concentration levels. Vacuum filtration methods for Nafion coating were vertically applied to the plane of an AAO membrane. An electric field was then applied to the upper surface of the Nafion-coated AAO membrane to investigate if ion rejection and filtering was affected by the presence of the electric field. Both anions and cations could pass through the AAO nanopores without an electric field applied. However, only cations could well pass through the AAO nanopores under an electric field, thus effectively blocking anions from passing through the nanopores. This result shows that ion filtration of electrons has been selectively performed while the system also works as a vital catalyst in reactivating Nafion via electrolysis. A saturated viscosity ratio of Nafion solution for the coating was also determined. We believe that this approach is potentially beneficial for better understanding the fundamentals of selective ion filtration in nanostructures and for promoting the use of nanostructures in potential applications such as ion-based water purification and desalination system at the nanoscale in a massively electrically integrated format. PMID:26813413

  15. Ion separation in imperfect fields of the quadrupole mass analyzer Part I. Ion beam dynamics in the phase-space

    NASA Astrophysics Data System (ADS)

    Titov, Vladimir V.

    1995-01-01

    The theoretical aspects of ion separation in imperfect fields of the quadrupole mass analyzer are discussed by applying analysis of the beam dynamics in a phase-space. The analytical method which uses an approximate solution of the Hill equation with a small heterogeneous part which indicates that the trap mechanism of ion separation is conditioned by the properties of characteristic solutions is improved. These solutions are reduced to an approximate solution in the form of a general solution of a homogeneous Mathieu equation with combined factors taking into account a small heterogeneous part which defines the region of beam capture (acceptance) in a phase-space. The estimation criterion of simulation accuracy is the relative deviation of an operating point on the Mathieu diagram from the top of a stability triangle. The infringement of independence principle of ion oscillations about each of the positional axes caused by distortions increases the cross-sectional area of the beam. The beam is cut out by the mass analyzer aperture. This causes transmission losses which depend on phase. Therefore, the ion current at the mass analyzer exit is amplitude modulated by the frequency of the alternate component of field. The maximum current is at zero phase. The modulation depth is proportional to the relative value of the distortions.

  16. Synthesis of nanowires via helium and neon focused ion beam induced deposition with the gas field ion microscope.

    PubMed

    Wu, H M; Stern, L A; Chen, J H; Huth, M; Schwalb, C H; Winhold, M; Porrati, F; Gonzalez, C M; Timilsina, R; Rack, P D

    2013-05-01

    The ion beam induced nanoscale synthesis of platinum nanowires using the trimethyl (methylcyclopentadienyl)platinum(IV) (MeCpPt(IV)Me3) precursor is investigated using helium and neon ion beams in the gas field ion microscope. The He(+) beam induced deposition resembles material deposited by electron beam induced deposition with very small platinum nanocrystallites suspended in a carbonaceous matrix. The He(+) deposited material composition was estimated to be 16% Pt in a matrix of amorphous carbon with a large room-temperature resistivity (∼3.5 × 10(4)-2.2 × 10(5) μΩ cm) and temperature-dependent transport behavior consistent with a granular material in the weak intergrain tunnel coupling regime. The Ne(+) deposited material has comparable composition (17%), however a much lower room-temperature resistivity (∼600-3.0 × 10(3) μΩ cm) and temperature-dependent electrical behavior representative of strong intergrain coupling. The Ne(+) deposited nanostructure has larger platinum nanoparticles and is rationalized via Monte Carlo ion-solid simulations which show that the neon energy density deposited during growth is much larger due to the smaller ion range and is dominated by nuclear stopping relative to helium which has a larger range and is dominated by electronic stopping. PMID:23548767

  17. Application of asymmetric flow field-flow fractionation (AsFlFFF) coupled to inductively coupled plasma mass spectrometry (ICPMS) to the quantitative characterization of natural colloids and synthetic nanoparticles.

    PubMed

    Bouby, M; Geckeis, H; Geyer, F W

    2008-12-01

    A straightforward quantification method is presented for the application of asymmetric flow field-flow fractionation (AsFlFFF) combined with inductively coupled plasma mass spectrometry (ICPMS) to the characterization of colloid-borne metal ions and nanoparticles. Reproducibility of the size calibration and recovery of elements are examined. Channel flow fluctuations are observed notably after initiation of the fractionation procedure. Their impact on quantification is considered by using (103)Rh as internal reference. Intensity ratios measured for various elements and Rh are calculated for each data point. These ratios turned out to be independent of the metal concentration and total sample solution flow introduced into the nebulizer within a range of 0.4-1.2 mL min(-1). The method is applied to study the interaction of Eu, U(VI) and Th with a mixture of humic acid and clay colloids and to the characterization of synthetic nanoparticles, namely CdSe/ZnS-MAA (mercaptoacetic acid) core/shell-coated quantum dots (QDs). Information is given not only on inorganic element composition but also on the effective hydrodynamic size under relevant conditions. Detection limits (DLs) are estimated for Ca, Al, Fe, the lanthanide Ce and the natural actinides Th and U in colloid-containing groundwater. For standard crossflow nebulizer, estimated values are 7 x 10(3), 20, 3 x 10(2), 0.1, 0.1 and 7 x 10(-2) microg L(-1), respectively. DLs for Zn and Cd in QD characterization are 28 and 11 microg L(-1), respectively. PMID:18931997

  18. Influence of high energy ion irradiation on the field emission characteristics of CVD diamond films

    NASA Astrophysics Data System (ADS)

    Koinkar, P. M.; Khairnar, R. S.; Khan, S. A.; Gupta, R. P.; Avasthi, D. K.; More, M. A.

    2006-03-01

    The field emission characteristics of ion-irradiated CVD diamond thin film deposited on silicon substrate has been studied. The diamond thin films, synthesized by hot filament chemical vapor deposition (HFCVD) method, were irradiated by high energy (100 MeV) silver ion (107Ag+ with charge state 9) in the fluence range of 3 × 1011-1 × 1013 ions/cm2. The CVD diamond films were characterized by Raman spectroscopy. The Raman spectra of irradiated samples clearly reveal structural damage due to ion irradiation, which is observed to be fluence dependent. However complete graphitization is not observed. The field emission current-voltage (I-V) characteristics were recorded in 'diode' configuration at base pressure ∼1 × 10-8 mbar. Upon ion irradiation the field emission current is observed to increase with the reduction in the threshold voltage, required to draw 1 μA current. The results indicate that ion irradiation leads to better emission characteristics and the structural damage caused by ion irradiation plays a significant role in emission behavior of CVD diamond films.

  19. Optical Field Ionization of Atoms and Ions Using Ultrashort Laser Pulses

    NASA Astrophysics Data System (ADS)

    Fittinghoff, David Neal

    This dissertation research is an investigation of the strong optical field ionization of atoms and ions by 120-fs, 614-nm laser pulses and 130-fs, 800-nm laser pulses. The experiments have shown ionization that is enhanced above the predictions of sequential tunneling models for He^{+2}, Ne ^{+2} and Ar^ {+2}. The ion yields for He^ {+1}, Ne^{+1} and Ar^{+1} agree well with the theoretical predictions of optical tunneling models. Investigation of the polarization dependence of the ionization indicates that the enhancements are consistent with a nonsequential ionization mechanism in which the linearly polarized field drives the electron wavefunction back toward the ion core and causes double ionization through inelastic e-2e scattering. These investigations have initiated a number of other studies by other groups and are of current scientific interest in the fields of high-irradiance laser -matter interactions and production of high-density plasmas. This work involved: (1) Understanding the characteristic nature of the ion yields produced by tunneling ionization through investigation of analytic solutions for tunneling at optical frequencies. (2) Extensive characterization of the pulses produced by 614-nm and 800-nm ultrashort pulse lasers. Absolute calibration of the irradiance scale produced shows the practicality of the inverse problem--measuring peak laser irradiance using ion yields. (3) Measuring the ion yields (number of ions produced versus irradiance) for three noble gases using linear, circular and elliptical polarizations of laser pulses.

  20. Rotational energy of the hydrogen molecular ion in a magnetic field

    SciTech Connect

    Maluendes, S.A.; Fernandez, F.M.; Castro, E.A.

    1983-10-01

    A general method which combines hypervirial relations with the Hellmann-Feynman theorem and perturbation theory is applied in order to calculate the rotational eigenvalues of the hydrogen molecular ion in a magnetic field. Analytical expressions as well as numerical results are presented for both low and high field strengths.

  1. EMPIRICAL TEST OF AN ION PARAMETRIC RESONANCE MODEL FOR MAGNETIC FIELD INTERACTIONS WITH PC-12 CELLS

    EPA Science Inventory

    A companion paper [Blanchard and B 19931 describes a predictive heuristic ion parametric resonance (IPR) model of magnetic field interactions with biological systems based on a selective relation between the ratio of the static magnetic field to the frequency of the AC magnetic f...

  2. Ion Viscosity Mediated by Tangled Magnetic Fields: An Application to Black Hole Accretion Disks

    NASA Technical Reports Server (NTRS)

    Subramanian, Prasad; Becker, Peter A.; Kafatos, Menas

    1996-01-01

    We examine the viscosity associated with the shear stress exerted by ions in the presence of a tangled magnetic field. As an application, we consider the effect of this mechanism on the structure of black hole accretion disks. We do not attempt to include a self-consistent description of the magnetic field. Instead, we assume the existence of a tangled field with coherence length lambda(sub coh), which is the average distance between the magnetic 'kinks' that scatter the particles. For simplicity, we assume that the field is self-similar, and take lambda(sub coh) to be a fixed fraction zeta of the local disk height H. Ion viscosity in the presence of magnetic fields is generally taken to be the cross-field viscosity, wherein the effective mean free path is the ion Larmor radius lambda(sub L), which is much less than the ion-ion Coulomb mean free path A(sub ii) in hot accretion disks. However, we arrive at a formulation for a 'hybrid' viscosity in which the tangled magnetic field acts as an intermediary in the transfer of momentum between different layers in the shear flow. The hybrid viscosity greatly exceeds the standard cross-field viscosity when (lambda/lambda(sub L)) much greater than (lambda(sub L)/lambda(sub ii)), where lambda = ((lambda(sub ii)(sup -1) + lambda(sub (coh)(sup -1))(sup -1) is the effective mean free path for the ions. This inequality is well satisfied in hot accretion disks, which suggests that the ions may play a much larger role in the momentum transfer process in the presence of magnetic fields than was previously thought. The effect of the hybrid viscosity on the structure of a steady-state, two-temperature, quasi-Keplerian accretion disk is analyzed. The hybrid viscosity is influenced by the degree to which the magnetic field is tangled (represented by zeta = lambda(sub coh)), and also by the relative accretion rate M/M(sub E), where M(sub E) = L(sub E)/c(sup 2) and L(sub E) is the Eddington luminosity. We find that ion viscosity in the

  3. The population of the magnetosphere by solar winds ions when the interplanetary magnetic field is northward

    NASA Technical Reports Server (NTRS)

    Richard, Robert L.; Walker, Raymond J.; Ashour-Abdalla, Maha

    1994-01-01

    We have examined some possible entry mechanisms of solar wind ions into the magnetosphere by calculating the trajectories of thousands of non-interacting ions in the magnetic and electric fields from a three dimensional global magnetohydrodynamic (MHD) simulation of the magnetosphere and the magnetosheath, under northward interplanetary magnetic field (IMF) conditions. Particles, launched in the solar wind, entered the magnetosphere and formed the low latitude boundary layer (LLBL), plasma sheet and a region of trapped particles near the Earth. The densities and temperatures we obtained in these regions were realistic, with the exception of trapped particle densities. The dominant entry mechanism was convection into the magnetosphere on reconnecting field lines.

  4. Asymmetric dark matter

    SciTech Connect

    Kumar, Jason

    2014-06-24

    We review the theoretical framework underlying models of asymmetric dark matter, describe astrophysical constraints which arise from observations of neutron stars, and discuss the prospects for detecting asymmetric dark matter.

  5. Designing asymmetric multiferroics with strong magnetoelectric coupling

    NASA Astrophysics Data System (ADS)

    Lu, X. Z.; Xiang, H. J.

    2014-09-01

    Multiferroics offer exciting opportunities for electric-field control of magnetism. Single-phase multiferroics suitable for such applications at room temperature need much more study. Here, we propose the concept of an alternative type of multiferroics, namely, the "asymmetric multiferroic." In asymmetric multiferroics, two locally stable ferroelectric states are not symmetrically equivalent, leading to different magnetic properties between these two states. Furthermore, we predict from first principles that a Fe-Cr-Mo superlattice with the LiNbO3-type structure is such an asymmetric multiferroic. The strong ferrimagnetism, high ferroelectric polarization, and significant dependence of the magnetic transition temperature on polarization make this asymmetric multiferroic an ideal candidate for realizing electric-field control of magnetism at room temperature. Our study suggests that the asymmetric multiferroic may provide an alternative playground for voltage control of magnetism and find its applications in spintronics and quantum computing.

  6. Designing asymmetric multiferroics with strong magnetoelectric coupling

    NASA Astrophysics Data System (ADS)

    Lu, Xuezeng; Xiang, Hongjun; Rondinelli, James; Materials Theory; Design Group Team

    2015-03-01

    Multiferroics offer exciting opportunities for electric-field control of magnetism. Single-phase multiferroics suitable for such applications at room temperature need much more study. Here, we propose the concept of an alternative type of multiferroics, namely, the ``asymmetric multiferroic.'' In asymmetric multiferroics, two locally stable ferroelectric states are not symmetrically equivalent, leading to different magnetic properties between these two states. Furthermore, we predict from first principles that a Fe-Cr-Mo superlattice with the LiNbO3-type structure is such an asymmetric multiferroic. The strong ferrimagnetism, high ferroelectric polarization, and significant dependence of the magnetic transition temperature on polarization make this asymmetric multiferroic an ideal candidate for realizing electric-field control of magnetism at room temperature. Our study suggests that the asymmetric multiferroic may provide an alternative playground for voltage control of magnetism and find its applications in spintronics and quantum computing.

  7. Behavior of moving plasma in solenoidal magnetic field in a laser ion source

    NASA Astrophysics Data System (ADS)

    Ikeda, S.; Takahashi, K.; Okamura, M.; Horioka, K.

    2016-02-01

    In a laser ion source, a solenoidal magnetic field is useful to guide the plasma and to control the extracted beam current. However, the behavior of the plasma drifting in the magnetic field has not been well understood. Therefore, to investigate the behavior, we measured the plasma ion current and the total charge within a single pulse in the solenoid by changing the distance from the entrance of the solenoid to a detector. We observed that the decrease of the total charge along the distance became smaller as the magnetic field became larger and then the charge became almost constant with a certain magnetic flux density. The results indicate that the transverse spreading speed of the plasma decreased with increasing the field and the plasma was confined transversely with the magnetic flux density. We found that the reason of the confinement was not magnetization of ions but an influence induced by electrons.

  8. Behavior of moving plasma in solenoidal magnetic field in a laser ion source.

    PubMed

    Ikeda, S; Takahashi, K; Okamura, M; Horioka, K

    2016-02-01

    In a laser ion source, a solenoidal magnetic field is useful to guide the plasma and to control the extracted beam current. However, the behavior of the plasma drifting in the magnetic field has not been well understood. Therefore, to investigate the behavior, we measured the plasma ion current and the total charge within a single pulse in the solenoid by changing the distance from the entrance of the solenoid to a detector. We observed that the decrease of the total charge along the distance became smaller as the magnetic field became larger and then the charge became almost constant with a certain magnetic flux density. The results indicate that the transverse spreading speed of the plasma decreased with increasing the field and the plasma was confined transversely with the magnetic flux density. We found that the reason of the confinement was not magnetization of ions but an influence induced by electrons. PMID:26931973

  9. Adhesion and transfer of polytetrafluoroethylene to tungsten studied by field ion microscopy

    NASA Technical Reports Server (NTRS)

    Brainard, W. A.; Buckley, D. H.

    1972-01-01

    Mechanical contacts between polytetrafluoroethylene (PTFE) and tungsten field ion tips were made in situ in the field ion microscope. Both load and force of adhesion were measured for varying contact times and for clean and contaminated tungsten tips. Strong adhesion between the PTFE and clean tungsten was observed at contact times greater than 2.5 min (forces of adhesion were greater than three times the load). For times less than 2.5 min, the force of adhesion was immeasurably small. The increase in adhesion with contact time after 2.5 min can be attributed to the increase in true contact area by creep of PTFE. No adhesion was measurable at long contact times with contaminated tungsten tips. Neon field ion micrographs taken after the contacts show many linear and branched arrays which appear to represent PTFE that remains adhered to the surface even at the high electric fields required for imaging.

  10. [Negative air ions generated by plants upon pulsed electric field stimulation applied to soil].

    PubMed

    Wu, Ren-ye; Deng, Chuan-yuan; Yang, Zhi-jian; Weng, Hai-yong; Zhu, Tie-jun-rong; Zheng, Jin-gui

    2015-02-01

    This paper investigated the capacity of plants (Schlumbergera truncata, Aloe vera var. chinensis, Chlorophytum comosum, Schlumbergera bridgesii, Gymnocalycium mihanovichii var. friedrichii, Aspidistra elatior, Cymbidium kanran, Echinocactus grusonii, Agave americana var. marginata, Asparagus setaceus) to generate negative air ions (NAI) under pulsed electric field stimulation. The results showed that single plant generated low amounts of NAI in natural condition. The capacity of C. comosum and G. mihanovichii var. friedrichii generated most NAI among the above ten species, with a daily average of 43 ion · cm(-3). The least one was A. americana var. marginata with the value of 19 ion · cm(-3). When proper pulsed electric field stimulation was applied to soil, the NAI of ten plant species were greatly improved. The effect of pulsed electric field u3 (average voltage over the pulse period was 2.0 x 10(4) V, pulse frequency was 1 Hz, and pulse duration was 50 ms) was the greatest. The mean NAI concentration of C. kanran was the highest 1454967 ion · cm(-3), which was 48498.9 times as much as that in natural condition. The lowest one was S. truncata with the value of 34567 ion · cm(-3), which was 843.1 times as much as that in natural condition. The capacity of the same plants to generate negative air ion varied extremely under different intensity pulsed electric fields. PMID:26094455

  11. Perspective on the Role of Negative Ions and Ion-Ion Plasmas in Heavy Ion Fusion Science, Magnetic Fusion Energy,and Related Fields

    SciTech Connect

    Grisham, L. R.; Kwan, J. W.

    2008-08-01

    Some years ago it was suggested that halogen negative ions could offer a feasible alternative path to positive ions as a heavy ion fusion driver beam which would not suffer degradation due to electron accumulation in the accelerator and beam transport system, and which could be converted to a neutral beam by photodetachment near the chamber entrance if desired. Since then, experiments have demonstrated that negative halogen beams can be extracted and accelerated away from the gas plume near the source with a surviving current density close to what could be achieved with a positive ion of similar mass, and with comparable optical quality. In demonstrating the feasibility of halogen negative ions as heavy ion driver beams, ion - ion plasmas, an interesting and somewhat novel state of matter, were produced. These plasmas, produced near the extractor plane of the sources, appear, based upon many lines of experimental evidence, to consist of almost equal densities of positive and negative chlorine ions, with only a small component of free electrons. Serendipitously, the need to extract beams from this plasma for driver development provides a unique diagnostic tool to investigate the plasma, since each component - positive ions, negative ions, and electrons - can be extracted and measured separately. We discuss the relevance of these observations to understanding negative ion beam extraction from electronegative plasmas such as halogens, or the more familiar hydrogen of magnetic fusion ion sources. We suggest a concept which might improve negative hydrogen extraction by the addition of a halogen. The possibility and challenges of producing ion - ion plasmas with thin targets of halogens or, perhaps, salt, is briefly addressed.

  12. Perspective on the Role of Negative Ions and Ion-Ion Plasmas in Heavy Ion Fusion Science, Magnetic Fusion Energy, and Related Fields

    SciTech Connect

    Grisham, L.R.; Kwan, J.W.

    2008-08-01

    Some years ago it was suggested that halogen negative ions [1]could offer a feasible alternative path to positive ions as a heavy ion fusion driver beam which would not suffer degradation due to electron accumulation in the accelerator and beam transport system, and which could be converted to a neutral beam by photodetachment near the chamber entrance if desired. Since then, experiments have demonstrated that negative halogen beams can be extracted and accelerated away from the gas plume near the source with a surviving current density close to what could be achieved with a positive ion of similar mass, and with comparable optical quality. In demonstrating the feasibility of halogen negative ions as heavy ion driver beams, ion - ion plasmas, an interesting and somewhat novel state of matter, were produced. These plasmas, produced near the extractor plane of the sources, appear, based upon many lines of experimental evidence, to consist of almost equal densities of positive and negative chlorine ions, with only a small component of free electrons. Serendipitously, the need to extract beams from this plasma for driver development provides a unique diagnostic tool to investigate the plasma, since each component - positive ions, negative ions, and electrons -- can be extracted and measured separately. We discuss the relevance of these observations to understanding negative ion beam extraction from electronegative plasmas such as halogens, or the more familiar hydrogen of magnetic fusion ion sources. We suggest a concept which might improve negative hydrogen extraction by the addition of a halogen. The possibility and challenges of producing ion-ion plasmas with thin targets of halogens or, perhaps, salt, is briefly addressed.

  13. Perspective on the Role of Negative Ions and Ion-Ion Plasmas in Heavy Ion Fusion Science, Magnetic Fusion Energy, and Related Fields

    SciTech Connect

    L. Grisham and J.W. Kwan

    2008-08-12

    Some years ago it was suggested that halogen negative ions [1] could offer a feasible alternative path to positive ions as a heavy ion fusion driver beam which would not suffer degradation due to electron accumulation in the accelerator and beam transport system, and which could be converted to a neutral beam by photodetachment near the chamber entrance if desired. Since then, experiments have demonstrated that negative halogen beams can be extracted and accelerated away from the gas plume near the source with a surviving current density close to what could be achieved with a positive ion of similar mass, and with comparable optical quality. In demonstrating the feasibility of halogen negative ions as heavy ion driver beams, ion - ion plasmas, an interesting and somewhat novel state of matter, were produced. These plasmas, produced near the extractor plane of the sources, appear, based upon many lines of experimental evidence, to consist of almost equal densities of positive and negative chlorine ions, with only a small component of free electrons. Serendipitously, the need to extract beams from this plasma for driver development provides a unique diagnostic tool to investigate the plasma, since each component - positive ions, negative ions, and electrons -- can be extracted and measured separately. We discuss the relevance of these observations to understanding negative ion beam extraction from electronegative plasmas such as halogens, or the more familiar hydrogen of magnetic fusion ion sources. We suggest a concept which might improve negative hydrogen extraction by the addition of a halogen. The possibility and challenges of producing ion-ion plasmas with thin targets of halogens or, perhaps, salt, is briefly addressed.

  14. Interaction modes between asymmetrically and oppositely charged rods

    NASA Astrophysics Data System (ADS)

    Antila, Hanne S.; Van Tassel, Paul R.; Sammalkorpi, Maria

    2016-02-01

    The interaction of oppositely and asymmetrically charged rods in salt—a simple model of (bio)macromolecular assembly—is observed via simulation to exhibit two free energy minima, separated by a repulsive barrier. In contrast to similar minima in the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory, the governing mechanism includes electrostatic attraction at large separation, osmotic repulsion at close range, and depletion attraction near contact. A model accounting for ion condensation and excluded volume is shown to be superior to a mean-field treatment in predicting the effect of charge asymmetry on the free-energy profile.

  15. Improved Differential Ion Mobility Separations Using Linked Scans of Carrier Gas Composition and Compensation Field

    NASA Astrophysics Data System (ADS)

    Santiago, Brandon G.; Harris, Rachel A.; Isenberg, Samantha L.; Ridgeway, Mark E.; Pilo, Alice L.; Kaplan, Desmond A.; Glish, Gary L.

    2015-07-01

    Differential ion mobility spectrometry (DIMS) separates ions based on differences in their mobilities in low and high electric fields. When coupled to mass spectrometric analyses, DIMS has the ability to improve signal-to-background by eliminating isobaric and isomeric compounds for analytes in complex mixtures. DIMS separation power, often measured by resolution and peak capacity, can be improved through increasing the fraction of helium in the nitrogen carrier gas. However, because the mobility of ions is higher in helium, a greater number of ions collide with the DIMS electrodes or housing, yielding losses in signal intensity. To take advantage of the benefits of helium addition on DIMS separations and reduce ion losses, linked scans were developed. In a linked scan the helium content of the carrier gas is reduced as the compensation field is increased. Linked scans were compared with conventional compensation field scans with constant helium content for the protein ubiquitin and a tryptic digest of bovine serum albumin (BSA). Linked scans yield better separation of ubiquitin charge states and enhanced peak capacities for the analysis of BSA compared with compensation field scans with constant helium carrier gas percentages. Linked scans also offer improved signal intensity retention in comparison to compensation field scans with constant helium percentages in the carrier gas.

  16. Hamiltonian description of ion motion in crossed electric and magnetic fields with cylindrical symmetry

    NASA Astrophysics Data System (ADS)

    Botman, J. I. M.; Hagedoorn, H. L.

    1992-02-01

    A Hamiltonian description is given of charged particle motion around a circular design trajectory in static electromagnetic systems possessing cylindrical symmetry. In particular the ion motion in a constant magnetic field in the z-direction and a hyperboloid electric potential, V(x,y,z) = {1}/{2}k 2z 2 - {1}/{4}k 2(x 2 + y 2) , where k2 is the potential strength parameter, is considered in Cartesian coordinates, to provide an exact solution to the Hamiltonian problem. The Wien filter can be considered as a special application of the system described. For a general electric field shape an expansion of the potential around the design orbit is required and a treatment in cylindrical coordinates seems more appropriate. Applications of these systems can be found in inflectors and deflectors in circular ion accelerators as well as in Wien filters or ion separators in various ion optical devices.

  17. Ion Species and Charge States of Vacuum Arc Plasma with Gas Feed and Longitudinal Magnetic Field

    SciTech Connect

    Oks, Efim; Anders, Andre

    2010-06-23

    The evolution of copper ion species and charge state distributions is measured for a long vacuum arc discharge plasma operated in the presence of a longitudinal magnetic field of several 10 mT and working gas (Ar). It was found that changing the cathode-anode distance within 20 cm as well as increasing the gas pressure did not affect the arc burning voltage and power dissipation by much. In contrast, burning voltage and power dissipation were greatly increased as the magnetic field was increased. The longer the discharge gap the greater was the fraction of gaseous ions and the lower the fraction of metal ions, while the mean ion charge state was reduced. It is argued that the results are affected by charge exchange collisions and electron impact ionization.

  18. Pairwise-additive force fields for selected aqueous monovalent ions from adaptive force matching

    NASA Astrophysics Data System (ADS)

    Li, Jicun; Wang, Feng

    2015-11-01

    Simple non-polarizable potentials were developed for Na+, K+, Cl-, and Br- using the adaptive force matching (AFM) method with ab initio MP2 method as reference. Our MP2-AFM force field predicts the solvation free energies of the four salts formed by the ions with an error of no more than 5%. Other properties such as the ion-water radial distribution functions, first solvation shell water tilt angle distributions, ion diffusion constants, concentration dependent diffusion constant of water, and concentration dependent surface tension of the solutions were calculated with this potential. Very good agreement was achieved for these properties. In particular, the diffusion constants of the ions are within 6% of experimental measurements. The model predicts bromide to be enriched at the interface in the 1.6M KBr solution but predicts the ion to be repelled for the surface at lower concentration.

  19. Effects of toroidal field ripple on suprathermal ions in tokamak plasmas

    SciTech Connect

    Goldston, R.J.; Towner, H.H.

    1980-02-01

    Analytic calculations of three important effects of toroidal field ripple on suprathermal ions in tokamak plasmas are presented. In the first process, collisional ripple-trapping, beam ions become trapped in local magnetic wells near their banana tips due to pitch-angle scattering as they traverse the ripple on barely unripple-trapped orbits. In the second process, collisionless ripple-trapping, near-perpendicular untrapped ions are captured (again near a banana tip) due to their finite orbits, which carry them out into regions of higher ripple. In the third process, banana-drift diffusion, fast-ion banana orbits fail to close precisely, due to a ripple-induced variable lingering period near the banana tips. These three mechanisms lead to substantial radial transport of banana-trapped, neutral-beam-injected ions when the quantity ..cap alpha..* identical with epsilon/sin theta/Nqdelta is of order unity or smaller.

  20. Podand-based dimeric chromium(III)-salen complex for asymmetric Henry reaction: cooperative catalysis promoted by complexation of alkali metal ions.

    PubMed

    Ouyang, Guang-Hui; He, Yan-Mei; Fan, Qing-Hua

    2014-12-01

    A new kind of podand-based dimeric salen ligand was synthesized, and its association with potassium cations was investigated by (1) H NMR spectroscopy. The corresponding Cr(III) -salen dimer was assembled by a supramolecular host-guest self-assembly process and was then used as a catalyst in highly efficient and enantioselective asymmetric Henry reactions. Regulation by KBArF (BArF =[3,5-(CF3 )2 C6 H3 ]4 B) led to remarkable improvements in yield (by up to 58 %) and enantioselectivity (for example, from 80 % ee to 96 % ee). PMID:25346533

  1. Compact Full-Field Ion Detector System for SmallSats Beyond LEO

    NASA Technical Reports Server (NTRS)

    Wrbanek, John D.; Wrbanek, Susan Y.; Fralick, Gustave C.; Clark, Pamela E.; McNeil, Roger R.

    2014-01-01

    NASA Glenn Research Center (GRC) is applying its expertise and facilities in harsh environment instrumentation to develop a Compact Full-Field Ion Detector System (CFIDS). The CFIDS is designed to be an extremely compact, low cost instrument, capable of being flown on a wide variety of deep space platforms, to provide multi-directional, comprehensive (composition, velocity, and direction) in-situ measurements of heavy ions in space plasma environments.

  2. Compact Full-Field Ion Detector System for CubeSat Science Beyond LEO

    NASA Technical Reports Server (NTRS)

    Wrbanek, John D.; Wrbanek, Susan Y.; Fralick, Gustave C.; Clark, Pamela E.

    2013-01-01

    NASA Glenn Research Center (GRC) is applying its expertise and facilities in harsh environment instrumentation to develop a Compact Full-Field Ion Detector System (CFIDS). The CFIDS is designed to be an extremely compact, low cost instrument, capable of being flown on a wide variety of deep space platforms, to provide comprehensive (composition, velocity, and direction) in situ measurements of heavy ions in space plasma environments with higher fidelity, than previously available.

  3. A description of a wide beam saddle field ion source used for nuclear target applications

    SciTech Connect

    Greene, J.P.; Schiel, S.L.; Thomas, G.E.

    1997-07-01

    A description is given of a new, wide beam saddle field sputter source used for the preparation of targets applied in nuclear physics experiments. The ion source characteristics are presented and compared with published results obtained with other sources. Deposition rates acquired utilizing this source are given for a variety of target materials encountered in nuclear target production. New applications involving target thinning and ion milling are discussed.

  4. Fast ion confinement and stability in a neutral beam injected reversed field pinch

    SciTech Connect

    Anderson, J. K.; Almagri, A. F.; Den Hartog, D. J.; Eilerman, S.; Forest, C. B.; Koliner, J. J.; Mirnov, V. V.; Morton, L. A.; Nornberg, M. D.; Parke, E.; Reusch, J. A.; Sarff, J. S.; Waksman, J.; Belykh, V.; Davydenko, V. I.; Ivanov, A. A.; Polosatkin, S. V.; Tsidulko, Y. A.; Lin, L.; Liu, D.; and others

    2013-05-15

    The behavior of energetic ions is fundamentally important in the study of fusion plasmas. While well-studied in tokamak, spherical torus, and stellarator plasmas, relatively little is known in reversed field pinch plasmas about the dynamics of fast ions and the effects they cause as a large population. These studies are now underway in the Madison Symmetric Torus with an intense 25 keV, 1 MW hydrogen neutral beam injector (NBI). Measurements of the time-resolved fast ion distribution via a high energy neutral particle analyzer, as well as beam-target neutron flux (when NBI fuel is doped with 3–5% D{sub 2}) both demonstrate that at low concentration the fast ion population is consistent with classical slowing of the fast ions, negligible cross-field transport, and charge exchange as the dominant ion loss mechanism. A significant population of fast ions develops; simulations predict a super-Alfvénic ion density of up to 25% of the electron density with both a significant velocity space gradient and a sharp radial density gradient. There are several effects on the background plasma including enhanced toroidal rotation, electron heating, and an altered current density profile. The abundant fast particles affect the plasma stability. Fast ions at the island of the core-most resonant tearing mode have a stabilizing effect, and up to 60% reduction in the magnetic fluctuation amplitude is observed during NBI. The sharp reduction in amplitude, however, has little effect on the underlying magnetic island structure. Simultaneously, beam driven instabilities are observed as repetitive ∼50 μs bursts which coincide with fast particle redistribution; data indicate a saturated core fast ion density well below purely classical predictions.

  5. Generation of elliptically polarized nitrogen ion laser fields using two-color femtosecond laser pulses

    PubMed Central

    Li, Ziting; Zeng, Bin; Chu, Wei; Xie, Hongqiang; Yao, Jinping; Li, Guihua; Qiao, Lingling; Wang, Zhanshan; Cheng, Ya

    2016-01-01

    We experimentally investigate generation of nitrogen molecular ion () lasers with two femtosecond laser pulses at different wavelengths. The first pulse serves as the pump which ionizes the nitrogen molecules and excites the molecular ions to excited electronic states. The second pulse serves as the probe which leads to stimulated emission from the excited molecular ions. We observe that changing the angle between the polarization directions of the two pulses gives rise to elliptically polarized laser fields, which is interpreted as a result of strong birefringence of the gain medium near the wavelengths of the laser. PMID:26888182

  6. Acceleration and stability of a high-current ion beam in induction fields

    NASA Astrophysics Data System (ADS)

    Karas', V. I.; Manuilenko, O. V.; Tarakanov, V. P.; Federovskaya, O. V.

    2013-03-01

    A one-dimensional nonlinear analytic theory of the filamentation instability of a high-current ion beam is formulated. The results of 2.5-dimensional numerical particle-in-cell simulations of acceleration and stability of an annular compensated ion beam (CIB) in a linear induction particle accelerator are presented. It is shown that additional transverse injection of electron beams in magnetically insulated gaps (cusps) improves the quality of the ion-beam distribution function and provides uniform beam acceleration along the accelerator. The CIB filamentation instability in both the presence and the absence of an external magnetic field is considered.

  7. Acceleration and stability of a high-current ion beam in induction fields

    SciTech Connect

    Karas', V. I.; Manuilenko, O. V.; Tarakanov, V. P.; Federovskaya, O. V.

    2013-03-15

    A one-dimensional nonlinear analytic theory of the filamentation instability of a high-current ion beam is formulated. The results of 2.5-dimensional numerical particle-in-cell simulations of acceleration and stability of an annular compensated ion beam (CIB) in a linear induction particle accelerator are presented. It is shown that additional transverse injection of electron beams in magnetically insulated gaps (cusps) improves the quality of the ion-beam distribution function and provides uniform beam acceleration along the accelerator. The CIB filamentation instability in both the presence and the absence of an external magnetic field is considered.

  8. Fast ion loss associated with perturbed field by resonant magnetic perturbation coils in KSTAR

    NASA Astrophysics Data System (ADS)

    Kim, Jun Young; Kim, Junghee; Rhee, Tongnyeol; Yoon, S. W.; Park, G. Y.; Jeon, Y. M.; Isobe, M.; Shimizu, A.; Ogawa, K.; Park, J.-K.; Garcia-Munoz, M.

    2013-10-01

    Resonant magnetic perturbation (RMP) is the most promising strategies for ELM mitigation/suppression. However, it has been found through the modeling and the experiments that RMP for the ELM mitigation can enhance the toroidally localized fast ion loss. During KSTAR experimental campaigns in 2011 and 2012, sudden increase or decrease of the fast ion loss has been observed by the scintillator-based fast ion loss detector (FILD) when the RMP is applied. Three-dimensional perturbed magnetic field by RMP coil in vacuum is calculated by Biot-Savart's law embedded in the Lorentz orbit code (LORBIT). The LORBIT code which is based on gyro-orbit following motion has been used for the simulation of the three-dimensional fast ion trajectories in presence of non-axisymmetric magnetic perturbation. It seems the measured fast ion loss rate at the localized position depends on not only the RMP field configuration but also the plasma profile such as safety factor and so on, varying the ratio between radial drift and stochastization of the fat-ion orbits. The simulation results of fast ion orbit under magnetic perturbation w/ and w/o plasma responses will be presented and compared with KSTAR FILD measurement results in various cases.

  9. Plasma and Energetic Particle Behaviors During Asymmetric Magnetic Reconnection at the Magnetopause

    NASA Technical Reports Server (NTRS)

    Lee, S. H.; Zhang, H.; Zong, Q.-G.; Otto, A.; Sibeck, D. G.; Wang, Y.; Glassmeier, K.-H.; Daly, P.W.; Reme, H.

    2014-01-01

    The factors controlling asymmetric reconnection and the role of the cold plasma population in the reconnection process are two outstanding questions. We present a case study of multipoint Cluster observations demonstrating that the separatrix and flow boundary angles are greater on the magnetosheath than on the magnetospheric side of the magnetopause, probably due to the stronger density than magnetic field asymmetry at this boundary. The motion of cold plasmaspheric ions entering the reconnection region differs from that of warmer magnetosheath and magnetospheric ions. In contrast to the warmer ions, which are probably accelerated by reconnection in the diffusion region near the subsolar magnetopause, the colder ions are simply entrained by ??×?? drifts at high latitudes on the recently reconnected magnetic field lines. This indicates that plasmaspheric ions can sometimes play only a very limited role in asymmetric reconnection, in contrast to previous simulation studies. Three cold ion populations (probably H+, He+, and O+) appear in the energy spectrum, consistent with ion acceleration to a common velocity.

  10. Tail-ion transport and Knudsen layer formation in the presence of magnetic fields

    NASA Astrophysics Data System (ADS)

    Schmit, Paul; Molvig, Kim

    2013-10-01

    The impact of magnetic fields on Knudsen layer formation in ICF-relevant plasma is investigated for the first time. Magnetic fields change the energy scaling of the ion diffusivity in a way that eliminates the preferential losses of fast ions compared to thermal ions. Simple threshold criteria give conditions such that the restoration of the ion tail distribution is sufficient to recover much of the lost fusion reactivity. The tail-ion kinetic equations are solved for hot fuel bounded by a cold, nonreacting wall using a numerical stochastic differential equation solver, and the modified fusion reactivities are calculated. We find that modest magnetic fields too weak to magnetize thermal ions are still sufficient to restore much of the lost reactivity, consistent with the threshold conditions. We also find that the Maxwell-averaged fusion reactivities are recovered more fully in cylindrical targets compared to spherical targets. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

  11. Detection and Quantification of Silver Nanoparticles at Environmentally Relevant Concentrations Using Asymmetric Flow Field-Flow Fractionation Online with Single Particle Inductively Coupled Plasma Mass Spectrometry.

    PubMed

    Huynh, Khanh An; Siska, Emily; Heithmar, Edward; Tadjiki, Soheyl; Pergantis, Spiros A

    2016-05-01

    The presence of silver nanoparticles (AgNPs) in aquatic environments could potentially cause adverse impacts on ecosystems and human health. However, current understanding of the environmental fate and transport of AgNPs is still limited because their properties in complex environmental samples cannot be accurately determined. In this study, the feasibility of using asymmetric flow field-flow fractionation (AF4) connected online with single particle inductively coupled plasma mass spectrometry (spICPMS) to detect and quantify AgNPs at environmentally relevant concentrations was investigated. The AF4 channel had a thickness of 350 μm and its accumulation wall was a 10 kDa regenerated cellulose membrane. A 0.02% FL-70 surfactant solution was used as an AF4 carrier. With 1.2 mL/min AF4 cross-flow rate, 1.5 mL/min AF4 channel flow rate, and 5 ms spICPMS dwell time, the AF4-spICPMS can detect and quantify 40-80 nm AgNPs, as well as Ag-SiO2 core-shell nanoparticles (51.0 nm diameter Ag core and 21.6 nm SiO2 shell), with good recovery within 30 min. This system was not only effective in differentiating and quantifying different types of AgNPs with similar hydrodynamic diameters, such as in mixtures containing Ag-SiO2 core-shell nanoparticles and 40-80 nm AgNPs, but also suitable for differentiating between 40 nm AgNPs and elevated Ag(+) content. The study results indicate that AF4-spICPMS is capable of detecting and quantifying AgNPs and other engineered metal nanomaterials in environmental samples. Nevertheless, further studies are needed before AF4-spICPMS can become a routine analytical technique. PMID:27104795

  12. Physicochemical characterization of titanium dioxide pigments using various techniques for size determination and asymmetric flow field flow fractionation hyphenated with inductively coupled plasma mass spectrometry.

    PubMed

    Helsper, Johannes P F G; Peters, Ruud J B; van Bemmel, Margaretha E M; Rivera, Zahira E Herrera; Wagner, Stephan; von der Kammer, Frank; Tromp, Peter C; Hofmann, Thilo; Weigel, Stefan

    2016-09-01

    Seven commercial titanium dioxide pigments and two other well-defined TiO2 materials (TiMs) were physicochemically characterised using asymmetric flow field flow fractionation (aF4) for separation, various techniques to determine size distribution and inductively coupled plasma mass spectrometry (ICPMS) for chemical characterization. The aF4-ICPMS conditions were optimised and validated for linearity, limit of detection, recovery, repeatability and reproducibility, all indicating good performance. Multi-element detection with aF4-ICPMS showed that some commercial pigments contained zirconium co-eluting with titanium in aF4. The other two TiMs, NM103 and NM104, contained aluminium as integral part of the titanium peak eluting in aF4. The materials were characterised using various size determination techniques: retention time in aF4, aF4 hyphenated with multi-angle laser light spectrometry (MALS), single particle ICPMS (spICPMS), scanning electron microscopy (SEM) and particle tracking analysis (PTA). PTA appeared inappropriate. For the other techniques, size distribution patterns were quite similar, i.e. high polydispersity with diameters from 20 to >700 nm, a modal peak between 200 and 500 nm and a shoulder at 600 nm. Number-based size distribution techniques as spICPMS and SEM showed smaller modal diameters than aF4-UV, from which mass-based diameters are calculated. With aF4-MALS calculated, light-scattering-based "diameters of gyration" (Øg) are similar to hydrodynamic diameters (Øh) from aF4-UV analyses and diameters observed with SEM, but much larger than with spICPMS. A Øg/Øh ratio of about 1 indicates that the TiMs are oblate spheres or fractal aggregates. SEM observations confirm the latter structure. The rationale for differences in modal peak diameter is discussed. PMID:27469116

  13. Combining asymmetrical flow field-flow fractionation with on- and off-line fluorescence detection to examine biodegradation of riverine dissolved and particulate organic matter.

    PubMed

    Lee, Sang Tak; Yang, Boram; Kim, Jin-Yong; Park, Ji-Hyung; Moon, Myeong Hee

    2015-08-28

    This study demonstrated that asymmetrical flow field-flow fractionation (AF4) coupled with on-line UV and fluorescence detection (FLD) and off-line excitation-emission matrix (EEM) fluorescence spectroscopy can be employed to analyze the influence of microbial metabolic activity on the consumption and production of freshwater organic matter. With the AF4 system, organic matter is on-line enriched during a focusing/relaxation period, which is an essential process prior to separation. Size-fractionated chromophoric and fluorophoric organic materials were simultaneously monitored during the 30-min AF4 separation process. Two fractions of different sizes (dissolved organic matter (DOM) and particulate organic matter (POM)) of freshwater samples from three locations (up-, mid-, and downstream) along the Han River basin of Korea were incubated with the same inoculum for 14 days to analyze fraction-specific alterations in optical properties using AF4-UV-FLD. A comparison of AF4 fractograms obtained from pre- and post-incubation samples revealed that POM-derived DOM were more susceptible to microbial metabolic activity than was DOM. Preferential microbial consumption of protein-like DOM components concurred with enhanced peaks of chromophoric and humic-like fluorescent components, presumably formed as by-products of microbial processing. AF4-UV-FLD combined with off-line identification of microbially processed components using EEM fluorescence spectroscopy provides a powerful tool to study the relationship between microbial activity and composition as well as biodegradability of DOM and POM-derived DOM from different origins, especially for the analysis of chromophoric and fluorophoric organic matter that are consumed and produced by microbial metabolic activity. The proposed AF4 system can be applied to organic matter in freshwater samples having low concentration range (0.3-2.5ppm of total organic carbon) without a pre-concentration procedure. PMID:26233252

  14. Feasibility of asymmetrical flow field-flow fractionation as a method for detecting protective antigen by direct recognition of size-increased target-captured nanoprobes.

    PubMed

    Shin, Kayeong; Choi, Jaeyeong; Cho, Jun-Haeng; Yoon, Moon-Young; Lee, Seungho; Chung, Hoeil

    2015-11-27

    Asymmetrical flow field-flow fractionation (AF4) was evaluated as a potential analytical method for detection of a protective antigen (PA), an Anthrax biomarker. The scheme was based on the recognition of altered AF4 retention through the generation of the size-increased Au nanoparticle probes as a result of PA binding, in which a PA-selective peptide was conjugated on the probe surface. In the visible absorption-based AF4 fractograms, the band position shifted to a longer retention time as the PA concentration increased due to the presence of probe bound with PAs. The shift was insignificant when the concentration was relatively low at 84.3pM. To improve sensitivity, two separate probes conjugated with two different peptides able to bind on different PA epitopes were used together. The band shift then became distinguishable even at 84.3pM of PA sample. The formation of larger PA-probe inter-connected species using the dual-probe system was responsible for the enhanced band shift. In parallel, the feasibility of surface-enhanced Raman scattering (SERS) as a potential AF4 detection method was also evaluated. In the off-line SERS fractogram constructed using fractions collected during AF4 separation, a band shift was also observed for the 84.3pM PA sample, and the band intensity was higher when using the dual-probe system. The combination of AF4 and SERS is promising for the detection of PA and will become a potential tool if the reproducibility of SERS measurement is improved. PMID:26482872

  15. Production of flickering aurora and field-aligned electron flux by electromagnetic ion cyclotron waves

    NASA Technical Reports Server (NTRS)

    Temerin, M.; Mcfadden, J.; Boehm, M.; Carlson, C. W.; Lotko, W.

    1986-01-01

    Recent observations have suggested that flickering aurora is produced by a modulation of the field-aligned component of the electron flux within an auroral arc. It is proposed that a portion of the field-aligned electrons are of ionospheric origin and that these electrons are accelerated and their flux modulated by electromagnetic ion cyclotron waves that occur below the main acceleration region on auroral arc field lines. A model of the electromagnetic ion cyclotron wave shows that the parallel phase velocity of the wave increase as the wave propagates toward the ionosphere. A test particle calculation shows that ionospheric electrons trapped or reflected by the wave are accelerated to energies of several keV and that their flux is modulated at the wave frequency. The relative amplitudes of the model wave electric fields are consistent with the observations of small-scale low-frequency ionospheric and magnetospheric electric fields near auroral arcs of approximately 10 mV/m and 100 mV/m, respectively. The large-amplitude ion cyclotron waves also produce a ponderomotive force and a self-consistent ambipolar electric field. Energy considerations show that the downward energy flux in the electromagnetic ion cyclotron wave can be several percent of the total downward auroral electron energy flux.

  16. Ion acceleration by Alfvén waves on auroral field lines

    NASA Astrophysics Data System (ADS)

    Bingham, Robert; Eliasson, Bengt; Tito Mendonça, José; Stenflo, Lennart

    2013-05-01

    Observations of ion acceleration along auroral field lines at the boundary of the plasma sheet and tail lobe of the Earth show that the energy of the ions increases with decreasing density. The observations can be explained by ion acceleration through Landau resonance with kinetic Alfvén waves (KAWs) such that kA·vi = ωA, where kA is the wave vector, vi is the ion resonance velocity and ωA is the Alfvén wave frequency. The ion resonance velocities are proportional to the Alfvén velocity which increases with decreasing density. This is in agreement with the data if the process is occurring at the plasma sheet tail lobe boundary. A quasi-linear theory of ion acceleration by KAWs is presented. These ions propagate both down towards and away from the Earth. The paths of the Freja and Polar satellites indicate that the acceleration takes place between the two satellites, between 1Re and 5Re. The downward propagating ions develop a horseshoe-type of distribution which has a positive slope in the perpendicular direction. This type of distribution can produce intense lower hybrid wave activity, which is also observed. Finally, the filamentation of shear Alfvén waves is considered. It may be responsible for large-scale density striations. In memory of Padma Kant Shukla, a great scientist and a good friend.

  17. Inhomogeneous magnetic-field-aligned ion flow measured in a Q machine

    NASA Astrophysics Data System (ADS)

    Koepke, M. E.; Zintl, M. W.; Teodorescu, C.; Reynolds, E. W.; Wang, G.; Good, T. N.

    2002-08-01

    Radial profiles of ion flow vd(r) are measured with laser-induced fluorescence for cases in which the flow direction is parallel (vd>0) and/or antiparallel (vd<0) to the equilibrium magnetic field. Experiments are conducted in the barium-ion plasma of a double-ended Q machine. In cases where the ionizers associated with the two ends are not biased relative to each other, two distinct, counterstreaming ion-beam populations are evident. The insertion of blocking electrodes introduces inhomogeneity into the density profiles of the ion populations without effecting the homogeneity of the radial profile of each population's drift velocity. In cases where the two ionizers are biased relative to each other, a single ion population exists. Variation in the radial profile of the ion population's parallel drift velocity vd is produced such that (dvd/dr) can be negative or positive with magnitudes 0-70% of the ion gyrofrequency ωci. These results are discussed in the context of beam-driven and velocity-shear-driven instabilities. Laboratory and space measurements of sheared parallel flow and counterstreaming ion beams are compared.

  18. Transport of ions through a (6,6) carbon nanotube under electric fields

    NASA Astrophysics Data System (ADS)

    Shen, Li; Xu, Zhen; Zhou, Zhe-Wei; Hu, Guo-Hui

    2014-11-01

    The transport of water and ions through carbon nanotubes (CNTs) is crucial in nanotechnology and biotechnology. Previous investigation indicated that the ions can hardly pass through (6,6) CNTs due to their hydrated shells. In the present study, utilizing molecular dynamics simulation, it is shown that the energy barrier mainly originating from the hydrated water molecules could be overcome by applying an electric field large enough in the CNT axis direction. Potential of mean force is calculated to show the reduction of energy barrier when the electric field is present for (Na+, K+, Cl-) ions. Consequently, ionic flux through (6,6) CNTs can be found once the electric field becomes larger than a threshold value. The variation of the coordination numbers of ions at different locations from the bulk to the center of the CNT is also explored to elaborate this dynamic process. The thresholds of the electric field are different for Na+, K+, and Cl- due to their characteristics. This consequence might be potentially applied in ion selectivity in the future.

  19. Electric-field-induced electron detachment of 800-MeV H{sup {minus}} ions

    SciTech Connect

    Keating, P.B.; Gulley, M.S.; Bryant, H.C.; MacKerrow, E.P.; Miller, W.A.; Rislove, D.C.; Cohen, S.; Donahue, J.B.; Fitzgerald, D.H.; Funk, D.J.; Frankle, S.C.; Hutson, R.L.; Macek, R.J.; Plum, M.A.; Stanciu, N.G.; van Dyck, O.B.; Wilkinson, C.A.

    1995-12-01

    The lifetime of 800-MeV H{sup {minus}} ions against electron detachment in a static electric field was measured over a range of eight orders of magnitude in experiments at the High Resolution Atomic Beam Facility of the Los Alamos Meson Physics Facility. The ions traversed a linear gradient magnetic field of 1.3-T peak strength resulting in a 6-MV/cm peak rest-frame electric field capable of stripping a large fraction of H{sup {minus}} ions. The unstripped H{sup {minus}} ions, neutral H{sup 0} atoms, and protons were detected 5.5 m from the magnet. This spectrum was analyzed to determine the lifetime of the H{sup {minus}} ion versus electric-field strength and the results were compared with previous studies. Three parametrizations of the lifetime formula based on an existing theory were used to calculate the stripping probability. The data were fit to the lifetime formula and good agreement with theoretical predictions was found. Finally, a possible experiment for observing excited states of H{sup {minus}} is briefly discussed.

  20. The influence of magnetic fields on the wake field and stopping power of an ion-beam pulse in plasmas

    SciTech Connect

    Zhao, Xiao-ying; Zhang, Ya-ling; Duan, Wen-shan; Qi, Xin E-mail: lyang@impcas.ac.cn; Shi, Jian; Zhang, Ling-yu; Yang, Lei E-mail: lyang@impcas.ac.cn

    2015-09-15

    We performed two-dimensional particle-in-cell simulations to investigate how a magnetic field affects the wake field and stopping power of an ion-beam pulse moving in plasmas. The corresponding density of plasma electrons is investigated. At a weak magnetic field, the wakes exhibit typical V-shaped cone structures. As the magnetic field strengthens, the wakes spread and lose their typical V-shaped structures. At a sufficiently strong magnetic field, the wakes exhibit conversed V-shaped structures. Additionally, strengthening the magnetic field reduces the stopping power in regions of low and high beam density. However, the influence of the magnetic field becomes complicated in regions of moderate beam density. The stopping power increases in a weak magnetic field, but it decreases in a strong magnetic field. At high beam density and moderate magnetic field, two low-density channels of plasma electrons appear on both sides of the incident beam pulse trajectory. This is because electrons near the beam pulses will be attracted and move along with the beam pulses, while other electrons nearby are restricted by the magnetic field and cannot fill the gap.

  1. Comment on 'Effects of magnetic field gradient on ion beam current in cylindrical Hall ion source' [J. Appl. Phys. 102, 123305 (2007)

    SciTech Connect

    Raitses, Y.; Smirnov, A.; Fisch, N. J.

    2008-09-15

    It is argued that the key difference in the cylindrical Hall thruster (CHT) as compared to the end-Hall ion source cannot be exclusively attributed to the magnetic field topology [Tang et al., J. Appl. Phys. 102, 123305 (2007)]. With a similar mirror-type topology, the CHT configuration provides the electric field with nearly equipotential magnetic field surfaces and a better suppression of the electron cross-field transport, as compared to both the end-Hall ion source and the cylindrical Hall ion source of [Tang et al., J. Appl. Phys. 102, 123305 (2007)].

  2. Controlling electron-ion rescattering in two-color circularly polarized femtosecond laser fields

    NASA Astrophysics Data System (ADS)

    Mancuso, Christopher A.; Hickstein, Daniel D.; Dorney, Kevin M.; Ellis, Jennifer L.; Hasović, Elvedin; Knut, Ronny; Grychtol, Patrik; Gentry, Christian; Gopalakrishnan, Maithreyi; Zusin, Dmitriy; Dollar, Franklin J.; Tong, Xiao-Min; Milošević, Dejan B.; Becker, Wilhelm; Kapteyn, Henry C.; Murnane, Margaret M.

    2016-05-01

    High-harmonic generation driven by two-color counter-rotating circularly polarized laser fields was recently demonstrated experimentally as a breakthrough source of bright, coherent, circularly polarized beams in the extreme ultraviolet and soft-x-ray regions. However, the conditions for optimizing the single-atom yield are significantly more complex than for linearly polarized driving lasers and are not fully understood. Here we present a comprehensive study of strong-field ionization—the complementary process to high-harmonic generation—driven by two-color circularly polarized fields. We uncover the conditions that lead to enhanced electron-ion rescattering, which should correspond to the highest single-atom harmonic flux. Using a velocity map imaging photoelectron spectrometer and tomographic reconstruction techniques, we record three-dimensional photoelectron distributions resulting from the strong-field ionization of argon atoms across a broad range of driving laser intensity ratios. In combination with analytical predictions and advanced numerical simulations, we show that "hard" electron-ion rescattering is optimized when the second-harmonic field has an intensity approximately four times higher than that of the fundamental driving field. We also investigate electron-ion rescattering with co-rotating fields, and find that rescattering is significantly suppressed when compared with counter-rotating fields.

  3. Field-aligned ion beams upstream of the earth's bow shock Evidence for a magnetosheath source

    NASA Technical Reports Server (NTRS)

    Thomsen, M. F.; Gosling, J. T.; Bame, S. J.; Feldman, W. C.; Paschmann, G.; Sckopke, N.

    1983-01-01

    High time resolution ISEE-1 and -2 observations of upstream field-aligned ion beams at several crossings of the earth's bow shock indicate that some beams are due to high energy magnetosheath particles leaking through the shock into the upstream region. The distribution immediately downstream of these oblique shocks consists of a 'core' of directly transmitted, slightly heated ions, plus a crescent-shaped, high-velocity distribution, centered roughly on the magnetic field in the direction toward the upstream region, with a fairly well defined low velocity cutoff.

  4. Kinetic response of ionospheric ions to onset of auroral electric fields

    NASA Technical Reports Server (NTRS)

    Chiu, Y. T.; Kan, J. R.

    1981-01-01

    Examination of the exact analytic solution of a kinetic model of collisional interaction of ionospheric fions with atmospheric neutrals in the Bhatnagar-Gross-Krook approximation, shows that the onset of intense auroral electric fields in the topside ionosphere can produce the following kinetic effects: (1) heat the bulk ionospheric ions to approximately 2 eV, thus driving them up to higher altitudes where they can be subjected to collisionless plasma processes; (2) produce a nonMaxwellian superthermal tail in the distribution function; and (3) cause the ion distribution function to be anisotropic with respect to the magnetic field with the perpendicular average thermal energy exceeding the parallel thermal energy.

  5. Hydroxamic acids in asymmetric synthesis.

    PubMed

    Li, Zhi; Yamamoto, Hisashi

    2013-02-19

    Metal-catalyzed stereoselective reactions are a central theme in organic chemistry research. In these reactions, the stereoselection is achieved predominantly by introducing chiral ligands at the metal catalyst's center. For decades, researchers have sought better chiral ligands for asymmetric catalysis and have made great progress. Nevertheless, to achieve optimal stereoselectivity and to catalyze new reactions, new chiral ligands are needed. Because of their high metal affinity, hydroxamic acids play major roles across a broad spectrum of fields from biochemistry to metal extraction. Dr. K. Barry Sharpless first revealed their potential as chiral ligands for asymmetric synthesis in 1977: He published the chiral vanadium-hydroxamic-acid-catalyzed, enantioselective epoxidation of allylic alcohols before his discovery of Sharpless asymmetric epoxidation, which uses the titanium-tartrate complex as the chiral reagent. However, researchers have reported few highly enantioselective reactions using metal-hydroxamic acid as catalysts since then. This Account summarizes our research on metal-catalyzed asymmetric epoxidation using hydroxamic acids as chiral ligands. We designed and synthesized a series of new hydroxamic acids, most notably the C2-symmetric bis-hydroxamic acid (BHA) family. V-BHA-catalyzed epoxidation of allylic and homoallylic alcohols achieved higher activity and stereoselectivity than Sharpless asymmetric epoxidation in many cases. Changing the metal species led to a series of unprecedented asymmetric epoxidation reactions, such as (i) single olefins and sulfides with Mo-BHA, (ii) homoallylic and bishomoallylic alcohols with Zr- and Hf-BHA, and (iii) N-alkenyl sulfonamides and N-sulfonyl imines with Hf-BHA. These reactions produce uniquely functionalized chiral epoxides with good yields and enantioselectivities. PMID:23157425

  6. Hydroxamic Acids in Asymmetric Synthesis

    PubMed Central

    Li, Zhi; Yamamoto, Hisashi

    2012-01-01

    Metal-catalyzed stereoselective reactions are a central theme in organic chemistry research. In these reactions, the stereoselection is achieved predominantly by introducing chiral ligands at the metal catalyst’s center. For decades, researchers have sought better chiral ligands for asymmetric catalysis and have made great progress. Nevertheless, to achieve optimal stereoselectivity and to catalyze new reactions, new chiral ligands are needed. Due to their high metal affinity, hydroxamic acids play major roles across a broad spectrum of fields from biochemistry to metal extraction. Dr. K. Barry Sharpless first revealed their potential as chiral ligands for asymmetric synthesis in 1977: He published the chiral vanadium-hydroxamic-acid-catalyzed, enantioselective epoxidation of allylic alcohols before his discovery of Sharpless Asymmetric Epoxidation, which uses titanium-tartrate complex as the chiral reagent. However, researchers have reported few highly enantioselective reactions using metal-hydroxamic acid as catalysts since then. This Account summarizes our research on metal-catalyzed asymmetric epoxidation using hydroxamic acids as chiral ligands. We designed and synthesized a series of new hydroxamic acids, most notably the C2-symmetric bis-hydroxamic acid (BHA) family. V-BHA-catalyzed epoxidation of allylic and homoallylic alcohols achieved higher activity and stereoselectivity than Sharpless Asymmetric Epoxidation in many cases. Changing the metal species led to a series of unprecedented asymmetric epoxidation reactions, such as (i) single olefins and sulfides with Mo-BHA, (ii) homoallylic and bishomoallylic alcohols with Zr- and Hf-BHA, and (iii) N-alkenyl sulfonamides and N-sulfonyl imines with Hf-BHA. These reactions produce uniquely functionalized chiral epoxides with good yields and enantioselectivities. PMID:23157425

  7. The direct injection of intense ion beams from a high field electron cyclotron resonance ion source into a radio frequency quadrupole.

    PubMed

    Rodrigues, G; Becker, R; Hamm, R W; Baskaran, R; Kanjilal, D; Roy, A

    2014-02-01

    The ion current achievable from high intensity ECR sources for highly charged ions is limited by the high space charge. This makes classical extraction systems for the transport and subsequent matching to a radio frequency quadrupole (RFQ) accelerator less efficient. The direct plasma injection (DPI) method developed originally for the laser ion source avoids these problems and uses the combined focusing of the gap between the ion source and the RFQ vanes (or rods) and the focusing of the rf fields from the RFQ penetrating into this gap. For high performance ECR sources that use superconducting solenoids, the stray magnetic field of the source in addition to the DPI scheme provides focusing against the space charge blow-up of the beam. A combined extraction/matching system has been designed for a high performance ECR ion source injecting into an RFQ, allowing a total beam current of 10 mA from the ion source for the production of highly charged (238)U(40+) (1.33 mA) to be injected at an ion source voltage of 60 kV. In this design, the features of IGUN have been used to take into account the rf-focusing of an RFQ channel (without modulation), the electrostatic field between ion source extraction and the RFQ vanes, the magnetic stray field of the ECR superconducting solenoid, and the defocusing space charge of an ion beam. The stray magnetic field is shown to be critical in the case of a matched beam. PMID:24593474

  8. The direct injection of intense ion beams from a high field electron cyclotron resonance ion source into a radio frequency quadrupole

    SciTech Connect

    Rodrigues, G. Kanjilal, D.; Roy, A.; Becker, R.; Baskaran, R.

    2014-02-15

    The ion current achievable from high intensity ECR sources for highly charged ions is limited by the high space charge. This makes classical extraction systems for the transport and subsequent matching to a radio frequency quadrupole (RFQ) accelerator less efficient. The direct plasma injection (DPI) method developed originally for the laser ion source avoids these problems and uses the combined focusing of the gap between the ion source and the RFQ vanes (or rods) and the focusing of the rf fields from the RFQ penetrating into this gap. For high performance ECR sources that use superconducting solenoids, the stray magnetic field of the source in addition to the DPI scheme provides focusing against the space charge blow-up of the beam. A combined extraction/matching system has been designed for a high performance ECR ion source injecting into an RFQ, allowing a total beam current of 10 mA from the ion source for the production of highly charged {sup 238}U{sup 40+} (1.33 mA) to be injected at an ion source voltage of 60 kV. In this design, the features of IGUN have been used to take into account the rf-focusing of an RFQ channel (without modulation), the electrostatic field between ion source extraction and the RFQ vanes, the magnetic stray field of the ECR superconducting solenoid, and the defocusing space charge of an ion beam. The stray magnetic field is shown to be critical in the case of a matched beam.

  9. The direct injection of intense ion beams from a high field electron cyclotron resonance ion source into a radio frequency quadrupole

    NASA Astrophysics Data System (ADS)

    Rodrigues, G.; Becker, R.; Hamm, R. W.; Baskaran, R.; Kanjilal, D.; Roy, A.

    2014-02-01

    The ion current achievable from high intensity ECR sources for highly charged ions is limited by the high space charge. This makes classical extraction systems for the transport and subsequent matching to a radio frequency quadrupole (RFQ) accelerator less efficient. The direct plasma injection (DPI) method developed originally for the laser ion source avoids these problems and uses the combined focusing of the gap between the ion source and the RFQ vanes (or rods) and the focusing of the rf fields from the RFQ penetrating into this gap. For high performance ECR sources that use superconducting solenoids, the stray magnetic field of the source in addition to the DPI scheme provides focusing against the space charge blow-up of the beam. A combined extraction/matching system has been designed for a high performance ECR ion source injecting into an RFQ, allowing a total beam current of 10 mA from the ion source for the production of highly charged 238U40+ (1.33 mA) to be injected at an ion source voltage of 60 kV. In this design, the features of IGUN have been used to take into account the rf-focusing of an RFQ channel (without modulation), the electrostatic field between ion source extraction and the RFQ vanes, the magnetic stray field of the ECR superconducting solenoid, and the defocusing space charge of an ion beam. The stray magnetic field is shown to be critical in the case of a matched beam.

  10. Geometry optimization for the cylindrical ion trap: field calculations, simulations and experiments

    NASA Astrophysics Data System (ADS)

    Wu, Guangxiang; Cooks, R. Graham; Ouyang, Zheng

    2005-03-01

    Optimization of ion trap geometries for best analytical performance was studied in the specific case of the cylindrical ion trap (CIT). An optimization procedure was developed based on field calculations and simulations of ion motion. The electric field inside the CIT was calculated by using the Poisson/Superfish software package and geometrical effects, specifically the half thickness of the ring electrode (zb), the spacing (ds) between the ring electrode and the end-cap electrode, and the end-cap hole radius (rH), were systematically investigated. Appropriate compensation for higher-order field components, namely octapolar and dodecapolar fields, was achieved by refining the CIT geometry and improved mass resolution in scans using boundary and resonance ejection. Resolution for different CIT geometries was measured in both simulations and experiments and was evaluated from the separation between the major isotope peaks of 1,3-dichlorobenzene at m/z 146 and 148. Optimization of the CIT electric field via simple geometry changes involved exploration of several geometries and simulations using the ion trap simulation program (ITSIM) were used to confirm the results for each geometry and to predict experimental performance. Experiments are reported that confirm the enhanced performance achieved using the CITs optimized using the procedure developed in this study.

  11. Ion confinement and transport in a toroidal plasma with externally imposed radial electric fields

    NASA Technical Reports Server (NTRS)

    Roth, J. R.; Krawczonek, W. M.; Powers, E. J.; Kim, Y. C.; Hong, H. Y.

    1979-01-01

    Strong electric fields were imposed along the minor radius of the toroidal plasma by biasing it with electrodes maintained at kilovolt potentials. Coherent, low-frequency disturbances characteristic of various magnetohydrodynamic instabilities were absent in the high-density, well-confined regime. High, direct-current radial electric fields with magnitudes up to 135 volts per centimeter penetrated inward to at least one-half the plasma radius. When the electric field pointed radially toward, the ion transport was inward against a strong local density gradient; and the plasma density and confinement time were significantly enhanced. The radial transport along the electric field appeared to be consistent with fluctuation-induced transport. With negative electrode polarity the particle confinement was consistent with a balance of two processes: a radial infusion of ions, in those sectors of the plasma not containing electrodes, that resulted from the radially inward fields; and ion losses to the electrodes, each of the which acted as a sink and drew ions out of the plasma. A simple model of particle confinement was proposed in which the particle confinement time is proportional to the plasma volume. The scaling predicted by this model was consistent with experimental measurements.

  12. Acceleration of ions by electric field pulses in the inner magnetosphere

    NASA Astrophysics Data System (ADS)

    Artemyev, A. V.; Liu, J.; Angelopoulos, V.; Runov, A.

    2015-06-01

    Intense (˜5-15 mV/m), short-lived (≤1 min) electric field pulses have been observed to accompany earthward propagating, dipolarizing flux bundles (flux tubes with a strong magnetic field) before they are stopped by the strong dipole field. Using Time History of Events and Macroscale Interactions during Substorms observations and test particle modeling, we investigate particle acceleration around L shell ˜7-9 in the nightside magnetosphere and demonstrate that such pulses can effectively accelerate ions with tens of keV initial energy to hundreds of keV. This acceleration occurs because the ion gyroradius is comparable to the spatial scale of the localized electric field pulse at the leading edge of the flux bundle before it stops. The proposed acceleration mechanism can reproduce observed spectra of high-energy ions. We conclude that the electric field associated with dipolarizing flux bundles prior to their stoppage in the inner magnetosphere provides a natural site for intense local ion acceleration.

  13. Improvements of the magnetic field design for SPIDER and MITICA negative ion beam sources

    SciTech Connect

    Chitarin, G.; Agostinetti, P.; Aprile, D.; Marconato, N.; Veltri, P.

    2015-04-08

    The design of the magnetic field configuration in the SPIDER and MITICA negative ion beam sources has evolved considerably during the past four years. This evolution was driven by three factors: 1) the experimental results of the large RF-driven ion sources at IPP, which have provided valuable indications on the optimal magnetic configurations for reliable RF plasma source operation and for large negative ion current extraction, 2) the comprehensive beam optics and heat load simulations, which showed that the magnetic field configuration in the accelerator is crucial for keeping the heat load due to electrons on the accelerator grids within tolerable limits, without compromising the optics of the negative ion beam in the foreseen operating scenarios, 3) the progress of the detailed mechanical design of the accelerator, which stimulated the evaluation of different solutions for the correction of beamlet deflections of various origin and for beamlet aiming. On this basis, new requirements and solution concepts for the magnetic field configuration in the SPIDER and MITICA beam sources have been progressively introduced and updated until the design converged. The paper presents how these concepts have been integrated into a final design solution based on a horizontal “long-range” field (few mT) in combination with a “local” vertical field of some tens of mT on the acceleration grids.

  14. Improvements of the magnetic field design for SPIDER and MITICA negative ion beam sources

    NASA Astrophysics Data System (ADS)

    Chitarin, G.; Agostinetti, P.; Aprile, D.; Marconato, N.; Veltri, P.

    2015-04-01

    The design of the magnetic field configuration in the SPIDER and MITICA negative ion beam sources has evolved considerably during the past four years. This evolution was driven by three factors: 1) the experimental results of the large RF-driven ion sources at IPP, which have provided valuable indications on the optimal magnetic configurations for reliable RF plasma source operation and for large negative ion current extraction, 2) the comprehensive beam optics and heat load simulations, which showed that the magnetic field configuration in the accelerator is crucial for keeping the heat load due to electrons on the accelerator grids within tolerable limits, without compromising the optics of the negative ion beam in the foreseen operating scenarios, 3) the progress of the detailed mechanical design of the accelerator, which stimulated the evaluation of different solutions for the correction of beamlet deflections of various origin and for beamlet aiming. On this basis, new requirements and solution concepts for the magnetic field configuration in the SPIDER and MITICA beam sources have been progressively introduced and updated until the design converged. The paper presents how these concepts have been integrated into a final design solution based on a horizontal "long-range" field (few mT) in combination with a "local" vertical field of some tens of mT on the acceleration grids.

  15. Novel chiral N4S2- and N6S3-donor macrocyclic ligands: synthesis, protonation constants, metal-ion binding and asymmetric catalysis in the Henry reaction.

    PubMed

    Gao, Jian; Martell, A E

    2003-08-01

    New hydrophobic chiral macrocyclic ligands L1-L3 with chiral diamino and thiophene moieties have been synthesized by the Schiff base condensation approach. Protonation constants of L1 and L2 were determined by potentiometry titration. Metal-ion binding experiments exhibited that L1 and L3 are pronounced in selective recognition, Ag+, Cu2+ and Ca2+ ions among the surveyed metal ions (Cu2+, Co2+, Ni2+, Zn2+, Cd2+, Pb2+, Ag+, Li+, Na+, K+, and Ca2+). L1 was found to spectroscopically detect the presence of Cu2+ and Ca2+ to function as a multiple readout sensor. The detection limit for Ca2+ ions was found to be 9.8 x 10(-5) M in CH2Cl2-MeOH solution. The trimeric chiral ligand L3 has been shown to be an efficient auxiliary in a Zn(II)-mediated enantioselective Henry reaction. PMID:12948208

  16. Lightning Interaction with the Lower Ionosphere: Effects of Mesospheric Ions and Geomagnetic Field

    NASA Astrophysics Data System (ADS)

    Marshall, R. A.; Inan, U. S.

    2011-12-01

    The interaction between the lightning electromagnetic pulse (EMP) and quasi-electrostatic (QE) fields and the D-region ionosphere has been observed optically in the past 20 years through sprites, elves, and gigantic jets. Very-low-frequency (VLF) measurements have been used to measure direct ionospheric modification, which may comprise electron density changes and/or heating. In the same time period, a number of models have been used to study the lightning-ionosphere interaction. Here, we present new time-domain 2D and 3D models of the lightning-ionosphere interaction, including EMP and QE effects. These spherical-coordinate models include effects of Earth's magnetic field; effects of mesospheric and ionospheric electron and ion densities; and responses to arbitrary lightning amplitudes, waveforms, and orientations. In this paper, we use the new models to investigate the response of the ionosphere under varying conditions. First, we focus on the effects of different mesospheric ion density profiles. Mesospheric ions, for which measurements are nearly nonexistent, serve to reduce the amplitude of the electromagnetic pulse as it propagates towards the ionosphere; high ion densities will reduce the wave electric field enough that it does not exceed the breakdown field in the ionosphere. We demonstrate the relationship between the lightning parameters, ion density profile, and observed elve intensity, and show that elves are suppressed when the ion density is high. Second, we investigate the effects of the geomagnetic field magnitude and orientation on wave propagation in and through the ionosphere. We compare these simulation results with known global lightning distributions and compare to the observed whistler distributions onboard satellites.

  17. Tandem time-of-flight mass spectrometer (TOF-TOF) with a quadratic-field ion mirror

    NASA Astrophysics Data System (ADS)

    Giannakopulos, Anastassios E.; Thomas, Benjamin; Colburn, Alex W.; Reynolds, David J.; Raptakis, Emmanuel N.; Makarov, Alexander A.; Derrick, Peter J.

    2002-05-01

    A tandem time-of-flight (TOF-TOF) mass spectrometer comprised of two ion mirrors is described. The first ion mirror, which is a linear-field, single-stage mirror (MS1) with an intermediate collision cell, has been designed to provide the temporal focus necessary for the second, quadratic-field ion mirror (MS2) to function effectively. Due to the wide energy-range focusing capabilities of the quadratic field employed in the second ion mirror all the fragment ions can be collected in one spectrum without the need to step the reflecting working voltage of the MS2. The size of the active area of the microchannel plate detector used in the preliminary experiments was the limiting factor governing the collection efficiently of fragment ions. The use of the first ion mirror to provide temporal focusing of the precursor ion packet at the first focal point of the quadratic mirror used as the MS2 requires no alteration of the focusing conditions for different masses, in contrast to delayed extraction or postsource pulsed focusing. Precursor ions formed by matrix-assisted laser desorption/ionization were mass-selected with an ion gate located before the collision cell and the fragment ions were mass analyzed using the quadratic-field ion mirror. Experimental results demonstrating effective high-energy collision-induced dissociation of polymer and fullerene molecule-ions are presented.

  18. Heavy ions acceleration in RF wells of 2-frequency electromagnetic field and in the inverted FEL

    SciTech Connect

    Dzergach, A.I.; Kabanov, V.S.; Nikulin, M.G.; Vinogradov, S.V.

    1995-03-01

    Last results of the study of heavy ions acceleration by electrons trapped in moving 2-frequency 3-D RF wells are described. A linearized theoretical model of ions acceleration in a polarized spheroidal plasmoid is proposed. The equilibrium state of this plasmoid is described by the modified microcanonical distribution of the Courant-Snyder invariant ({open_quotes}quasienergy{close_quotes} of electrons). Some new results of computational simulation of the acceleration process are given. The method of computation takes into account the given cylindrical field E{sub 011}({var_phi},r,z) and the self fields of electrons and ions. The results of the computation at relatively short time intervals confirm the idea and estimated parameters of acceleration. The heavy ion accelerator using this principle may be constructed with the use of compact cm band iris-loaded and biperiodical waveguides with double-sided 2-frequency RF feeding. It can accelerate heavy ions with a charge number Z{sub i} from small initial energies {approximately} 50 keV/a.u. with the rate {approximately} Z{sub i} {center_dot} 10 MeV/m. Semirelativistic ions may be accelerated with similar rate also in the inverted FEL.

  19. Diffusivity in asymmetric Yukawa ionic mixtures in dense plasmas

    NASA Astrophysics Data System (ADS)

    Haxhimali, Tomorr; Rudd, Robert E.; Cabot, William H.; Graziani, Frank R.

    2014-08-01

    In this paper we present molecular dynamics (MD) calculations of the interdiffusion coefficient for asymmetric mixed plasma for thermodynamic conditions relevant to astrophysical and inertial confinement fusion plasmas. Specifically, we consider mixtures of deuterium and argon at temperatures of 100-500 eV and a number density ˜1025 ions/cm3. The motion of 30 000-120 000 ions is simulated in which the ions interact via the Yukawa (screened Coulomb) potential. The electric field of the electrons is included in this effective interaction; the electrons are not simulated explicitly. The species diffusivity is then calculated using the Green-Kubo approach using an integral of the interdiffusion current autocorrelation function, a quantity calculated in the equilibrium MD simulations. Our MD simulation results show that a widely used expression relating the interdiffusion coefficient with the concentration-weighted sum of self-diffusion coefficients overestimates the interdiffusion coefficient. We argue that this effect due to cross-correlation terms in velocities is characteristic of asymmetric mixed plasmas. Comparison of the MD results with predictions of kinetic theories also shows a discrepancy with MD giving effectively a larger Coulomb logarithm.

  20. Diffusivity in asymmetric Yukawa ionic mixtures in dense plasmas.

    PubMed

    Haxhimali, Tomorr; Rudd, Robert E; Cabot, William H; Graziani, Frank R

    2014-08-01

    In this paper we present molecular dynamics (MD) calculations of the interdiffusion coefficient for asymmetric mixed plasma for thermodynamic conditions relevant to astrophysical and inertial confinement fusion plasmas. Specifically, we consider mixtures of deuterium and argon at temperatures of 100-500 eV and a number density ∼10(25) ions/cm(3). The motion of 30,000-120,000 ions is simulated in which the ions interact via the Yukawa (screened Coulomb) potential. The electric field of the electrons is included in this effective interaction; the electrons are not simulated explicitly. The species diffusivity is then calculated using the Green-Kubo approach using an integral of the interdiffusion current autocorrelation function, a quantity calculated in the equilibrium MD simulations. Our MD simulation results show that a widely used expression relating the interdiffusion coefficient with the concentration-weighted sum of self-diffusion coefficients overestimates the interdiffusion coefficient. We argue that this effect due to cross-correlation terms in velocities is characteristic of asymmetric mixed plasmas. Comparison of the MD results with predictions of kinetic theories also shows a discrepancy with MD giving effectively a larger Coulomb logarithm. PMID:25215836

  1. The field evaporation of deuterated titanium as a neutron generator ion source

    NASA Astrophysics Data System (ADS)

    Reichenbach, B.; Johnson, B. Bargsten; Schwoebel, P. R.

    2010-11-01

    The field evaporation of deuterated titanium films is being investigated as a deuterium ion source for deuterium-tritium neutron generators. It has been found that titanium and deuterated titanium films having thicknesses of up to at least 70 layers assume a body-centered-cubic crystal structure when grown on ⟨110⟩ oriented tungsten substrates. Deuterated titanium films having thicknesses exceeding 50 atomic layers have been controllably field evaporated from the surface of tungsten tips in less than 20 ns. At ion current densities exceeding ˜106 A/cm2 and film thicknesses greater than ˜20 layers, space charge effects decrease the ratio of D to TiDx ions to less than 1. Decreasing the evaporation rate such that ion current densities are of the order of 105 A/cm2 increases the D to TiDx ratio for the evaporation of a film thickness of greater than ˜20 layers by the reduction in space charge effects that can inhibit the dissociation of titanium-deuterium complexes. Atomic deuterium ion yields of ˜10-7 μC of D+/tip have been observed and yields of >10-6 μC of D+/tip should be possible using larger tip radii. The field evaporation of titanium from an array of microfabricated tips has been demonstrated for the first time.

  2. Microwave Near-Field Quantum Control of Trapped-Ion Qubits

    NASA Astrophysics Data System (ADS)

    Warring, U.; Ospelkaus, C.; Brown, K. R.; Colombe, Y.; Amini, J. M.; Leibfried, D.; Wineland, D. J.

    2011-05-01

    A major concern in the development of a future quantum processor is the scalability toward large numbers of qubits; its structure should enable one- and multi-qubit gates on arbitrarily selected qubits. As for a classical processor, micro fabrication might lead to a promising route to build such a versatile ion-qubit quantum processor. Recent experiments with surface electrode ion traps have demonstrated the key ingredients for scalable ion loading, transporting, and trapping architecture. Here, we present an approach to incorporate also the ion-qubit manipulation into the surface-electrode structure. It is based on an oscillating magnetic field generated by microwave currents in electrodes of a micro fabricated surface-electrode trap. The homogeneous field component is used to implement single-qubit gates, while the field gradient leads to a coupling of the ions internal and motional states. With further improvements, this coupling can be deployed to entangle multi-qubits. Supported by IARPA, NSA, DARPA, ONR and the NIST Quantum Information Program.

  3. The dependence of solar wind ion entry on the direction of the interplanetary magnetic field

    NASA Astrophysics Data System (ADS)

    Peroomian, V.

    2003-04-01

    We have investigated the entry characteristics of solar wind ions into the magnetosphere by tracing particle orbits in time-dependent electric and magnetic fields obtained from a three-dimensional global magnetohydrodynamic (MHD) simulation of the magnetosphere. The MHD simulation used in the study began with a 2-hour period of northward interplanetary magnetic field (IMF). The IMF then rotated by 45^o every two hours. The final four hours of the simulation had southward IMF. Millions of ions were launched in the solar wind, upstream of the bowshock, at x = 17 R_E, at time intervals corresponding to the midpoint of each IMF interval and collected after crossing the magnetopause current layer. We found that the region of the upstream solar wind that mapped to the magnetopause entry regions was parallel to the y z orientation of the IMF. Moreover, ions entry into the magnetosphere was in general agreement with the regions identified by Luhmann et al. [1984]. However, there were significant asymmetries in the entry locations due to the direction of the interplanetary electric field and the acceleration experienced by ions in crossing the magnetopause current layer. In all cases the ions entering the magnetosphere did so in sufficient numbers to account for the plasma observed within that region and successfully populated the plasma sheet and ring current regions.

  4. The statistical relationship between magnetosheath ion temperatures and magnetic field perturbations throughout the dayside magnetosheath.

    NASA Astrophysics Data System (ADS)

    Dimmock, Andrew; Osmane, Adnane; Pulkkinen, Tuija; Nykyri, Katariina

    2016-04-01

    The magnetosheath layer functions as an interface between interplanetary and near Earth space. As a result, the magnetosheath plasma properties dictate the efficiency and occurrence of processes which regulate the energy and momentum transport to the inner magnetosphere. Two (and possibly correlated) magnetosheath plasma properties which may play a significant role are ion temperatures and magnetic field perturbations; both of which comfortably exceed their solar wind counterparts. It has been proposed that magnetic field fluctuations, particularly those close to ion gyro-scales, can heat ions. In some cases, especially close to the magnetopause, these may facilitate diffusive plasma transport via kinetic Alfvén waves. The results presented here describe a statistical study using THEMIS and OMNI data between 2008 through 2015 in which we study the statistical relationship between magnetosheath ion temperatures and magnetic field variations over Pc 1-5 scale lengths. We show that higher amplitude fluctuations behind the quasi-parallel shock can produce higher ion temperatures subsequently driving a dawn-dusk asymmetry. We will also determine which scale/s are more effective at driving higher temperatures. We ascertain whether this relationship varies with spatial location, and if there are any global implications.

  5. Broadscale resolving power performance of a high precision uniform field ion mobility-mass spectrometer.

    PubMed

    May, Jody C; Dodds, James N; Kurulugama, Ruwan T; Stafford, George C; Fjeldsted, John C; McLean, John A

    2015-10-21

    An extensive study of two current ion mobility resolving power theories ("conditional" and "semi-empirical") was undertaken using a recently developed drift tube ion mobility-mass spectrometer. The current study investigates the quantitative agreement between experiment and theory at reduced pressure (4 Torr) for a wide range of initial ion gate widths (100 to 500 μs), and ion mobility values (K0 from 0.50 to 3.0 cm(2) V(-1) s(-1)) representing measurements obtained in helium, nitrogen, and carbon dioxide drift gas. Results suggest that the conditional resolving power theory deviates from experimental results for low mobility ions (e.g., high mass analytes) and for initial ion gate widths beyond 200 μs. A semi-empirical resolving power theory provided close-correlation of predicted resolving powers to experimental results across the full range of mobilities and gate widths investigated. Interpreting the results from the semi-empirical theory, the performance of the current instrumentation was found to be highly linear for a wide range of analytes, with optimal resolving powers being accessible for a narrow range of drift fields between 14 and 17 V cm(-1). While developed using singly-charged ion mobility data, preliminary results suggest that the semi-empirical theory has broader applicability to higher-charge state systems. PMID:26191544

  6. Clinical evaluation of sodium ion selective field effect transistors for whole blood assay.

    PubMed

    Thompson, J M; Smith, S C; Cramb, R; Hutton, P

    1994-01-01

    Sodium ion selective field effect transistors (ISFETs) were evaluated for their performance in measurement of sodium ions in whole blood for 'near patient' analysis in operating theatres and intensive care units. Performance was evaluated in comparison with a standard clinical laboratory sodium/potassium ion analyser (Radiometer KNA1) and with sodium and potassium assays using flame photometry on the plasma from each whole blood specimen. The imprecisions (coefficients of variation) of three ISFETs for sodium ion assay were 1.08, 1.56 and 1.10%, respectively. Robust bivariate linear regression (reweighted least squares preceded by least median of squares) of the ISFET versus KNA1 sodium ion activity yielded a regression coefficient of 1.08 and an intercept of -18.2 mM. The influence of potassium, protein and lipid on the measurement of sodium ions by both ISFETs and the KNA1 was assessed using robust multiple regression (also based on reweighted least squares preceded by least median of squares). In the regression versus flame photometry, protein was found to be more influential for the KNA1 (glass sodium ion selective electrode) than for the ISFET. Potassium had no influence on assays using the ISFET, but had a weak negative influence on assays using the KNA1. Two ISFETs lasted for more than 200 assays each demonstrating their robustness in the assay of whole blood. PMID:8154847

  7. Field dependence of gaseous-ion mobility - Theoretical tests of approximate formulas.

    NASA Technical Reports Server (NTRS)

    Hahn, H.; Mason, E. A.

    1972-01-01

    The approximate formulas considered include relations based on the Wannier free-flight theory, the Kihara medium-field expansion, and the Frost-Patterson interpolation formulas. A few accurate theoretical results are available for testing the foregoing formulas. Cases concerning high fields, intermediate fields, and resonant charge transfer are examined. It is found that of the formulas tested, the one based on the Wannier free-flight theory is the most flexible, since it can be used for all fields and all ion-neutral force laws and mass ratios.

  8. Ion velocity and plasma potential measurements of a cylindrical cusped field thruster

    SciTech Connect

    MacDonald, N. A.; Young, C. V.; Cappelli, M. A.; Hargus, W. A. Jr.

    2012-05-01

    Measurements of the most probable time-averaged axial ion velocities and plasma potential within the acceleration channel and in the plume of a straight-channeled cylindrical cusped field thruster operating on xenon are presented. Ion velocities for the thruster are derived from laser-induced fluorescence measurements of the 5d[4]{sub 7/2}-6p[3]{sub 5/2} xenon ion excited state transition centered at {lambda}=834.72nm. Plasma potential measurements are made using a floating emissive probe with a thoriated-tungsten filament. The thruster is operated in a power matched condition with 300 V applied anode potential for comparison to previous krypton plasma potential measurements, and a low power condition with 150 V applied anode potential. Correlations are seen between the plasma potential drop outside of the thruster and kinetic energy contours of the accelerating ions.

  9. Selective detection of heavy metal ions by self assembled chemical field effect transistors

    NASA Astrophysics Data System (ADS)

    Ruan, Hang; Kang, Yuhong; Gladwin, Elizabeth; Claus, Richard O.

    2015-04-01

    Multiple layer-by-layer sensor material modifications were designed and implemented to achieve selectivity of semiconductor based chemical field effect transistors (ChemFETs) to particular heavy metal ions. The ChemFET sensors were fabricated and modified in three ways, with the intent to initially target first mercury and lead ions and then chromium ions, respectively. Sensor characterization was performed with the gate regions of the sensor elements exposed to different concentrations of target heavy metal ion solutions. A minimum detection level in the range of 0.1 ppm and a 10%-90% response time of less than 10 s were demonstrated. By combining layer-by-layer gold nanoparticles and lead ionophores, a sensor is produced that is sensitive and selective not only to chromium but also to Cr3+ and Cr6+. This result supports the claim that high selectivity can be achieved by designing self-assembled bonding for lead, arsenic, chromium, cesium, mercury, and cadmium.

  10. Ion source for neutral beam injection meant for plasma and magnetic field diagnostics

    SciTech Connect

    Vainionpaa, Jaakko Hannes; Leung, Ka Ngo; Gough, Richard A.; Kwan, Joe W.; Levinton, Fred

    2008-02-15

    At the Lawrence Berkeley National Laboratory a diagnostic neutral beam injection system for measuring plasma parameters, flow velocity, and local magnetic field is being developed. The system is designed to have a 90% proton fraction and small divergence with beam current at 5-6 A and a pulse length of {approx}1 s occurring once every 1-2 min. The ion source needs to generate uniform plasma over a large (8x5 cm{sup 2}) extraction area. For this application, we have compared rf driven multicusp ion sources operating with either an external or an internal antenna in similar ion source geometry. The ion beam will be made of an array of six sheet-shaped beamlets. The design is optimized using computer simulation programs.

  11. Ion Source for Neutral beam injection meant for plasma and magnetic field diagnostics

    SciTech Connect

    Vainionpaa, Jaakko Hannes; Leung, Ka Ngo; Gough, Richard A.; Kwan, Joe W.; Levinton, Fred

    2007-06-01

    At the Lawrence Berkeley National Laboratory (LBNL) a diagnostic neutral beam injection system for measuring plasma parameters, flow velocity, and local magnetic field is being developed. The systems is designed to have a 90 % proton fraction and small divergence with beam current at 5-6 A and a pulse length of {approx}1 s occurring once every 1-2 min. The ion source needs to generate uniform plasma over a large (8 cm x 5 cm) extraction area. For this application, we have compared RF driven multicusp ion sources operating with either an external or an internal antenna in similar ion source geometry. The ion beam will be made of an array of six sheet-shaped beamlets. The design is optimized using computer simulation programs.

  12. Electric-field-controlled water and ion permeation of a hydrophobic nanopore.

    PubMed

    Dzubiella, J; Hansen, J-P

    2005-06-15

    The permeation of hydrophobic, cylindrical nanopores by water molecules and ions is investigated under equilibrium and out-of-equilibrium conditions by extensive molecular-dynamics simulations. Neglecting the chemical structure of the confining pore surface, we focus on the effects of pore radius and electric field on permeation. The simulations confirm the intermittent filling of the pore by water, reported earlier under equilibrium conditions for pore radii larger than a critical radius R(c). Below this radius, water can still permeate the pore under the action of a strong electric field generated by an ion concentration imbalance at both ends of the pore embedded in a structureless membrane. The water driven into the channel undergoes considerable electrostriction characterized by a mean density up to twice the bulk density and by a dramatic drop in dielectric permittivity which can be traced back to a considerable distortion of the hydrogen-bond network inside the pore. The free-energy barrier to ion permeation is estimated by a variant of umbrella sampling for Na(+), K(+), Ca(2+), and Cl(-) ions, and correlates well with known solvation free energies in bulk water. Starting from an initial imbalance in ion concentration, equilibrium is gradually restored by successive ion passages through the water-filled pore. At each passage the electric field across the pore drops, reducing the initial electrostriction, until the pore, of radius less than R(c), closes to water and hence to ion transport, thus providing a possible mechanism for voltage-dependent gating of hydrophobic pores. PMID:16008472

  13. Concepts of magnetic filter fields in powerful negative ion sources for fusion

    NASA Astrophysics Data System (ADS)

    Kraus, W.; Fantz, U.; Heinemann, B.; Wünderlich, D.

    2016-02-01

    The performance of large negative ion sources used in neutral beam injection systems is in long pulses mainly determined by the increase of the currents of co-extracted electrons. This is in particular a problem in deuterium and limits the ion currents which are for long pulses below the requirements for the ITER source. In the source of the ELISE test facility, the magnetic field in front of the first grid, which is essential to reduce the electron current, is generated by a current of several kA flowing through the plasma facing grid. Weakening of this field by the addition of permanent magnets placed close to the lateral walls has led to a reduction of the electron current by a factor three without loss of ion current when source was operated in volume production. If this effect can be validated for the cesiated source, it would be a large step towards achieving the ITER parameter in long pulses.

  14. Vacuum and magnetic field constraints in a H -/light ion synchrotron

    NASA Astrophysics Data System (ADS)

    Arduini, G.; Martin, R. L.; Rossi, S.; Silari, M.

    1994-08-01

    Acceleration of H - ions in a synchrotron imposes severe restrictions on the level of residual pressure in the vacuum chamber and the maximum magnetic field in the magnets of the ring. Significant vacuum requirements are also imposed by the acceleration of ions. This paper discusses these two aspects of the design of a combined H -/light ion synchrotron for radiation therapy. The fractional loss of the accelerated beam induced by the two processes is evaluated on the basis of a general treatment of the physics of these phenomena. The values of the vacuum and magnetic field necessary for normal operation of the machine are specified and a discussion is given of the behaviour of the above quantities as a function of several parameters such as beam energy, composition and pressure of the residual gas in the vacuum chamber and beam extraction time.

  15. Field theory for zero sound and ion acoustic wave in astrophysical matter

    NASA Astrophysics Data System (ADS)

    Gabadadze, Gregory; Rosen, Rachel A.

    2016-02-01

    We set up a field theory model to describe the longitudinal low-energy modes in high density matter present in white dwarf stars. At the relevant scales, ions—the nuclei of oxygen, carbon, and helium—are treated as heavy pointlike spin-0 charged particles in an effective field theory approach, while the electron dynamics is described by the Dirac Lagrangian at the one-loop level. We show that there always exists a longitudinal gapless mode in the system irrespective of whether the ions are in a plasma, crystal, or quantum liquid state. For certain values of the parameters, the gapless mode can be interpreted as a zero sound mode and, for other values, as an ion acoustic wave; we show that the zero sound and ion acoustic wave are complementary to each other. We discuss possible physical consequences of these modes for properties of white dwarfs.

  16. Concepts of magnetic filter fields in powerful negative ion sources for fusion.

    PubMed

    Kraus, W; Fantz, U; Heinemann, B; Wünderlich, D

    2016-02-01

    The performance of large negative ion sources used in neutral beam injection systems is in long pulses mainly determined by the increase of the currents of co-extracted electrons. This is in particular a problem in deuterium and limits the ion currents which are for long pulses below the requirements for the ITER source. In the source of the ELISE test facility, the magnetic field in front of the first grid, which is essential to reduce the electron current, is generated by a current of several kA flowing through the plasma facing grid. Weakening of this field by the addition of permanent magnets placed close to the lateral walls has led to a reduction of the electron current by a factor three without loss of ion current when source was operated in volume production. If this effect can be validated for the cesiated source, it would be a large step towards achieving the ITER parameter in long pulses. PMID:26932043

  17. Crystal-field calculations for transition-metal ions by application of an opposing potential

    DOE PAGESBeta

    Zhou, Fei; Aberg, Daniel

    2016-02-16

    We propose a fully ab initio method, the opposing crystal potential (OCP), to calculate the crystal-field parameters of transition-metal impurities in insulator hosts. Through constrained density functional calculations, OCP obtains the constraining Lagrange multipliers, which act as a cancellation potential against the crystal field and lead to spherical d-electron distribution. Furthermore, the method is applied to several insulators doped with Mn4+ and Mn2+ ions and shown to be in good agreement with experiment.

  18. Sawtooth-Control Mechanism using Toroidally Propagating Ion-Cyclotron-Resonance Waves in Tokamaks

    SciTech Connect

    Graves, J. P.; Coda, S.; Chapman, I.

    2009-02-13

    The sawtooth control mechanism in plasmas employing off-axis toroidally propagating ion cyclotron resonance waves in tokamaks is reinvestigated. The radial drift excursion of energetic passing ions distributed asymmetrically in the velocity parallel to the magnetic field determines stability when the rational q=1 surface resides within a narrow region centered about the shifted fundamental cyclotron resonance.

  19. Simulations of ion acceleration at non-relativistic shocks. II. Magnetic field amplification

    SciTech Connect

    Caprioli, D.; Spitkovsky, A.

    2014-10-10

    We use large hybrid simulations to study ion acceleration and generation of magnetic turbulence due to the streaming of particles that are self-consistently accelerated at non-relativistic shocks. When acceleration is efficient, we find that the upstream magnetic field is significantly amplified. The total amplification factor is larger than 10 for shocks with Alfvénic Mach number M = 100, and scales with the square root of M. The spectral energy density of excited magnetic turbulence is determined by the energy distribution of accelerated particles, and for moderately strong shocks (M ≲ 30) agrees well with the prediction of resonant streaming instability, in the framework of quasilinear theory of diffusive shock acceleration. For M ≳ 30, instead, Bell's non-resonant hybrid (NRH) instability is predicted and found to grow faster than resonant instability. NRH modes are excited far upstream by escaping particles, and initially grow without disrupting the current, their typical wavelengths being much shorter than the current ions' gyroradii. Then, in the nonlinear stage, most unstable modes migrate to larger and larger wavelengths, eventually becoming resonant in wavelength with the driving ions, which start diffuse. Ahead of strong shocks we distinguish two regions, separated by the free-escape boundary: the far upstream, where field amplification is provided by the current of escaping ions via NRH instability, and the shock precursor, where energetic particles are effectively magnetized, and field amplification is provided by the current in diffusing ions. The presented scalings of magnetic field amplification enable the inclusion of self-consistent microphysics into phenomenological models of ion acceleration at non-relativistic shocks.

  20. Rocketborne observations of ion convection and electric fields in dayside and nightside visual auroral arcs

    SciTech Connect

    Yau, A.W.; Whalen, B.A.; Creutzberg, F.

    1981-08-01

    We present ionospheric ion convection measurements in a series of four rocket payloads in and near dayside and nightside auroral arcs: one at Cape Parry (75.4/sup 0/N invariant latitude) near 1300 MLT and three at Churchill (70.0/sup 0/N invariant latitude) between 1900 and 2200 MLT. Direct measurements were made of the ionospheric ion velocity distribution function, and the observed ion convection velocities and equivalent convective electric fields were correlated with the energetic particle precipitation, the optical morphology of the aurora, and the topology of the geomagnetic field. Both in the postnoon and premidnight sectors it was observed that (1) equatorward of the region(s) of precipitation the ion flow was predominantly westward, with velocity of about 1 km/s; (2) poleward of the region(s) the flow was predominantly westward, with velocity of about 1 km/s; (2) poleward of the region(s) the flow was predominantly eastward: (3) the change in the flow direction, where observed, occurred near though not exactly at the edges of the precipitation region; (4) the flow inside the precipitation region was lower; (5) the reversal of the ion flow, where observed, occurred on closed magnetic field lines; and (6) the convective electric field typically dropped from 40 to 80 mV/m outside the precipitation region to 10 to 30 mV/m within. In the dayside Cape Perry flight, where quantitative photometric measurements were available, detailed anticorrelation between the ion convection speed and the green line emission intensity was also observed.

  1. Representation of Ion-Protein Interactions Using the Drude Polarizable Force-Field.

    PubMed

    Li, Hui; Ngo, Van; Da Silva, Mauricio Chagas; Salahub, Dennis R; Callahan, Karen; Roux, Benoît; Noskov, Sergei Yu

    2015-07-23

    Small metal ions play critical roles in numerous biological processes. Of particular interest is how metalloenzymes are allosterically regulated by the binding of specific ions. Understanding how ion binding affects these biological processes requires atomic models that accurately treat the microscopic interactions with the protein ligands. Theoretical approaches at different levels of sophistication can contribute to a deeper understanding of these systems, although computational models must strike a balance between accuracy and efficiency in order to enable long molecular dynamics simulations. In this study, we present a systematic effort to optimize the parameters of a polarizable force field based on classical Drude oscillators to accurately represent the interactions between ions (K(+), Na(+), Ca(2+), and Cl(-)) and coordinating amino-acid residues for a set of 30 biologically important proteins. By combining ab initio calculations and experimental thermodynamic data, we derive a polarizable force field that is consistent with a wide range of properties, including the geometries and interaction energies of gas-phase ion/protein-like model compound clusters, and the experimental solvation free-energies of the cations in liquids. The resulting models display significant improvements relative to the fixed-atomic-charge additive CHARMM C36 force field, particularly in their ability to reproduce the many-body electrostatic nonadditivity effects estimated from ab initio calculations. The analysis clarifies the fundamental limitations of the pairwise additivity assumption inherent in classical fixed-charge force fields, and shows its dramatic failures in the case of Ca(2+) binding sites. These optimized polarizable models, amenable to computationally efficient large-scale MD simulations, set a firm foundation and offer a powerful avenue to study the roles of the ions in soluble and membrane transport proteins. PMID:25578354

  2. Probing High-Velocity Transient-Field Strength Using Heavy-ions Traversing Fe and Gd

    SciTech Connect

    Fiori, E.; Georgiev, G.; Cabaret, S.; Lozeva, R.; Jungclaus, A.; Modamio, V.; Walker, J.; Balabanski, D. L.; Blazhev, A.; Clement, E.; Grevy, S.; Stodel, C.; Thomas, J. C.; Danchev, M.; Daugas, J. M.; Hass, M.; Kumar, V.; Leske, J.; Pietralla, N.

    2009-08-26

    The transient field strength for {sup 76}Ge ions, passing through iron and gadolinium layers at velocities approxZv{sub 0}, has been measured. Although a sizeable value has been obtained for Gd, a vanishing strength has been observed in Fe.

  3. Field Ion Microscopy and Atom Probe Tomography of Metamorphic Magnetite Crystals

    NASA Technical Reports Server (NTRS)

    Kuhlman, K.; Martens, R. L.; Kelly, T. F.; Evans, N. D.; Miller, M. K.

    2001-01-01

    Magnetite has been analysed using Field Ion Microscopy (FIM) and Atom Probe Tomography (APT), highly attractive techniques for the nanoanalysis of geological materials despite the difficulties inherent in analyzing semiconducting and insulating materials. Additional information is contained in the original extended abstract.

  4. CLARIFICATION AND APPLICATION OF AN ION PARAMETRIC RESONANCE MODEL FOR MAGNETIC FIELD INTERACTIONS WITH BIOLOGICAL SYSTEMS

    EPA Science Inventory

    Theoretical models proposed to date have been unable to clearly predict expected biological results from exposure to low intensity electric and magnetic fields (EMF). n this paper we clarify a heuristic ion parametric resonance (IPR) model that describes the expected forms of res...

  5. Interaction of Fast Ions with Global Plasma Modes in the C-2 Field Reversed Configuration Experiment

    NASA Astrophysics Data System (ADS)

    Smirnov, Artem; Dettrick, Sean; Clary, Ryan; Korepanov, Sergey; Thompson, Matthew; Trask, Erik; Tuszewski, Michel

    2012-10-01

    A high-confinement operating regime [1] with plasma lifetimes significantly exceeding past empirical scaling laws was recently obtained by combining plasma gun edge biasing and tangential Neutral Beam Injection (NBI) in the C-2 field-reversed configuration (FRC) experiment [2, 3]. We present experimental and computational results on the interaction of fast ions with the n=2 rotational and n=1 wobble modes in the C-2 FRC. It is found that the n=2 mode is similar to quadrupole magnetic fields in its detrimental effect on the fast ion transport due to symmetry breaking. The plasma gun generates an inward radial electric field, thus stabilizing the n=2 rotational instability without applying the quadrupole magnetic fields. The resultant FRCs are nearly axisymmetric, which enables fast ion confinement. The NBI further suppresses the n=2 mode, improves the plasma confinement characteristics, and increases the plasma configuration lifetime [4]. The n=1 wobble mode has relatively little effect on the fast ion transport, likely due to the approximate axisymmetry about the displaced plasma column. [4pt] [1] M. Tuszewski et al., Phys. Rev. Lett. 108, 255008 (2012).[0pt] [2] M. Binderbauer et al., Phys. Rev. Lett. 105, 045003 (2010).[0pt] [3] H.Y. Guo et al., Phys. Plasmas 18, 056110 (2011).[0pt] [4] M. Tuszewski et al., Phys. Plasmas 19, 056108 (2012)

  6. Electron cyclotron resonance heating by magnetic filter field in a negative hydrogen ion source.

    PubMed

    Kim, June Young; Cho, Won-Hwi; Dang, Jeong-Jeung; Chung, Kyoung-Jae; Hwang, Y S

    2016-02-01

    The influence of magnetic filter field on plasma properties in the heating region has been investigated in a planar-type inductively coupled radio-frequency (RF) H(-) ion source. Besides filtering high energy electrons near the extraction region, the magnetic filter field is clearly observed to increase the electron temperature in the heating region at low pressure discharge. With increasing the operating pressure, enhancement of electron temperature in the heating region is reduced. The possibility of electron cyclotron resonance (ECR) heating in the heating region due to stray magnetic field generated by a filter magnet located at the extraction region is examined. It is found that ECR heating by RF wave field in the discharge region, where the strength of an axial magnetic field is approximately ∼4.8 G, can effectively heat low energy electrons. Depletion of low energy electrons in the electron energy distribution function measured at the heating region supports the occurrence of ECR heating. The present study suggests that addition of axial magnetic field as small as several G by an external electromagnet or permanent magnets can greatly increase the generation of highly ro-vibrationally excited hydrogen molecules in the heating region, thus improving the performance of H(-) ion generation in volume-produced negative hydrogen ion sources. PMID:26931999

  7. Noncontact measurement of electrostatic fields: Verification of modeled potentials within ion mobility spectrometer drift tube designs

    SciTech Connect

    Scott, Jill R.; Tremblay, Paul L.

    2007-03-15

    The heart of an ion mobility spectrometer is the drift region where ion separation occurs. While the electrostatic potentials within a drift tube design can be modeled, no method for independently validating the electrostatic field has previously been reported. Two basic drift tube designs were modeled using SIMION 7.0 to reveal the expected electrostatic fields: (1) A traditional alternating set of electrodes and insulators and (2) a truly linear drift tube. One version of the alternating electrode/insulator drift tube and two versions of linear drift tubes were then fabricated. The stacked alternating electrodes/insulators were connected through a resistor network to generate the electrostatic gradient in the drift tube. The two linear drift tube designs consisted of two types of resistive drift tubes with one tube consisting of a resistive coating within an insulating tube and the other tube composed of resistive ferrites. The electrostatic fields within each type of drift tube were then evaluated by a noncontact method using a Kelvin-Zisman type electrostatic voltmeter and probe (results for alternative measurement methods provided in supplementary material). The experimental results were then compared with the electrostatic fields predicted by SIMION. Both the modeling and experimental measurements reveal that the electrostatic fields within a stacked ion mobility spectrometer drift tube are only pseudo-linear, while the electrostatic fields within a resistive drift tube approach perfect linearity.

  8. Electron cyclotron resonance heating by magnetic filter field in a negative hydrogen ion source

    NASA Astrophysics Data System (ADS)

    Kim, June Young; Cho, Won-Hwi; Dang, Jeong-Jeung; Chung, Kyoung-Jae; Hwang, Y. S.

    2016-02-01

    The influence of magnetic filter field on plasma properties in the heating region has been investigated in a planar-type inductively coupled radio-frequency (RF) H- ion source. Besides filtering high energy electrons near the extraction region, the magnetic filter field is clearly observed to increase the electron temperature in the heating region at low pressure discharge. With increasing the operating pressure, enhancement of electron temperature in the heating region is reduced. The possibility of electron cyclotron resonance (ECR) heating in the heating region due to stray magnetic field generated by a filter magnet located at the extraction region is examined. It is found that ECR heating by RF wave field in the discharge region, where the strength of an axial magnetic field is approximately ˜4.8 G, can effectively heat low energy electrons. Depletion of low energy electrons in the electron energy distribution function measured at the heating region supports the occurrence of ECR heating. The present study suggests that addition of axial magnetic field as small as several G by an external electromagnet or permanent magnets can greatly increase the generation of highly ro-vibrationally excited hydrogen molecules in the heating region, thus improving the performance of H- ion generation in volume-produced negative hydrogen ion sources.

  9. Asymmetric particle fluxes from drifting ionization zones in sputtering magnetrons

    NASA Astrophysics Data System (ADS)

    Panjan, Matjaž; Franz, Robert; Anders, André

    2014-04-01

    Electron and ion fluxes from direct current and high-power impulse magnetron sputtering (dcMS and HiPIMS) plasmas were measured in the plane of the target surface. Biased collector probes and a particle energy and mass analyzer showed asymmetric emission of electrons and of singly and doubly charged ions. For both HiPIMS and dcMS discharges, higher fluxes of all types of particles were observed in the direction of the electrons' E × B drift. These results are put in the context with ionization zones that drift over the magnetron's racetrack. The measured currents of time-resolving collector probes suggest that a large fraction of the ion flux originates from drifting ionization zones, while energy-resolving mass spectrometry indicates that a large fraction of the ion energy is due to acceleration by an electric field. This supports the recently proposed hypothesis that each ionization zone is associated with a negative-positive-negative space charge structure, thereby producing an electric field that accelerates ions from the location where they were formed.

  10. Correlation of the asymmetric and symmetric POO{sup -} frequencies with the ionic potential of the metal ion in compounds of organophosphorus acid extractants : a short review.

    SciTech Connect

    Ferraro, J. R.; Herlinger, A. W.; Chiarizia, R.; Chemistry; Loyola Univ.

    1998-01-01

    The correlation between [VASYM(POO-) - VASYM (POO-)], Av, and the ionic potential of the metal ion in metal compounds of alkyl-substituted diphosphonic acid extractants is reviewed. Similar correlations of the ionic potential of the metal ion with {Delta}v in organosubstituted monophosphate, organosubstituted monophosphonate, carbonate and nitrate compounds have been previously demonstrated. In this paper, we discuss the origin, general validity, and utility of the correlation for organophosphorus compounds. Far-infrared and {sup 54}Fe -labeled data were used to identify metal-oxygen stretching vibrations and establish that for some metal ions, e.g., Fe(III) and possibly Th(IV), the metal-oxygen interaction has substantial covalent character. The correlation appears to be valid not only for materials in which the metal-oxygen interaction is predominantly ionic, but also for compounds characterized by a covalent metal-oxygen bonding as well as for polymeric materials, providing the POO- stretching vibrations are assignable.

  11. Quantitative characterization by asymmetrical flow field-flow fractionation of IgG thermal aggregation with and without polymer protective agents.

    PubMed

    Ma, Dewang; Martin, Nicolas; Tribet, Christophe; Winnik, Françoise M

    2014-11-01

    Complexes formed between poly(acrylates) and polyclonal immunoglobulin G (IgG) in its native conformation and after heat stress were characterized using asymmetric flow field-flow fractionation (AF4) coupled with on-line UV-Vis spectroscopy and multi-angle light-scattering detection (MALS). Mixtures of IgG and poly(acrylates) of increasing structural complexity, sodium poly(acrylate) (PAA), a sodium poly(acrylate) bearing at random 3 mol % n-octadecyl groups, and a random copolymer of sodium acrylate (35 mol%), N-n-octylacrylamide (25 mol%) and N-isopropylacrylamide (40 mol%), were fractionated in a sodium phosphate buffer (0.02 M, pH 6.8) in the presence, or not, of 0.1 M NaCl. The AF4 protocol developed allowed the fractionation of solutions containing free poly(acrylates), native IgG monomer and dimer, poly(acrylates)/IgG complexes made up of one IgG molecule and a few polymer chains, and/or larger poly(acrylates)/IgG aggregates. The molar mass and recovery of the soluble analytes were obtained for mixed solutions of poly(acrylates) and native IgG and for the same solutions incubated at 65 °C for 10 min. From the combined AF4 results, we concluded that in solutions of low ionic strength, the presence of PAA increased the recovery ratio of IgG after thermal stress because of the formation of electrostatically-driven PAA/IgG complexes, but PAA had no protective effect in the presence of 0.1 M NaCl. Poly(acrylates) bearing hydrophobic groups significantly increased IgG recovery after stress, independently of NaCl concentration, because of the synergistic effect of hydrophobic and electrostatic interactions. The AF4 results corroborate conclusions drawn from a previous study combining four analytical techniques. This study demonstrates that AF4 is an efficient tool for the analysis of protein formulations subjected to stress, an important achievement given the anticipated important role of proteins in near-future human therapies. PMID:25323742

  12. Characterization of aggregates of surface modified fullerenes by asymmetrical flow field-flow fractionation with multi-angle light scattering detection.

    PubMed

    Astefanei, Alina; Kok, Wim Th; Bäuerlein, Patrick; Núñez, Oscar; Galceran, Maria Teresa; de Voogt, Pim; Schoenmakers, Peter J

    2015-08-21

    Fullerenes are carbon nanoparticles with widespread biomedical, commercial and industrial applications. Attributes such as their tendency to aggregate and aggregate size and shape impact their ability to be transported into and through the environment and living tissues. Knowledge of these properties is therefore valuable for their human and environmental risk assessment as well as to control their synthesis and manufacture. In this work, asymmetrical flow-field flow fractionation (AF4) coupled to multi-angle light scattering (MALS) was used for the first time to study the size distribution of surface modified fullerenes with both polyhydroxyl and carboxyl functional groups in aqueous solutions having different pH (6.5-11) and ionic strength values (0-200mM) of environmental relevance. Fractionation key parameters such as flow rates, flow programming, and membrane material were optimized for the selected fullerenes. The aggregation of the compounds studied appeared to be indifferent to changes in solution pH, but was affected by changes in the ionic strength. Polyhydroxy-fullerenes were found to be present mostly as 4nm aggregates in water without added salt, but showed more aggregation at high ionic strength, with an up to 10-fold increase in their mean hydrodynamic radii (200mM), due to a decrease in the electrostatic repulsion between the nanoparticles. Carboxy-fullerenes showed a much stronger aggregation degree in water (50-100nm). Their average size and recoveries decreased with the increase in the salt concentration. This behavior can be due to enhanced adsorption of the large particles to the membrane at high ionic strength, because of their higher hydrophobicity and much larger particle sizes compared to polyhydroxy-fullerenes. The method performance was evaluated by calculating the run-to-run precision of the retention time (hydrodynamic radii), and the obtained RSD values were lower than 1%. MALS measurements showed aggregate sizes that were in good

  13. Asymmetric information and macroeconomic dynamics

    NASA Astrophysics Data System (ADS)

    Hawkins, Raymond J.; Aoki, Masanao; Roy Frieden, B.

    2010-09-01

    We show how macroeconomic dynamics can be derived from asymmetric information. As an illustration of the utility of this approach we derive the equilibrium density, non-equilibrium densities and the equation of motion for the response to a demand shock for productivity in a simple economy. Novel consequences of this approach include a natural incorporation of time dependence into macroeconomics and a common information-theoretic basis for economics and other fields seeking to link micro-dynamics and macro-observables.

  14. A laboratory study of ion energization by EIC waves and subsequent upstreaming along diverging magnetic field lines

    NASA Technical Reports Server (NTRS)

    Cartier, S. L.; Dangelo, N.; Merlino, R. L.

    1986-01-01

    A laboratory study related to energetic upstreaming ions in the ionosphere-magnetosphere system is described. The experiment was carried out in a cesium Q machine plasma with a region of nonuniform magnetic field. Electrostatic ion cyclotron waves were excited by drawing an electron current to a small biased exciter electrode. In the presence of the instability, ions are heated in the direction perpendicular to B. Using a gridded retarding potential ion energy analyzer, the evolution of the ion velocity distribution was followed as the ions passed through the heating region and subsequently flowed out along the diverging B field lines. As expected, the heated ions transfer their energy from perpendicular to parallel motion as they move through the region of diverging B field. Both their parallel thermal energy and the parallel drift energy increase at the expense of the perpendicular energy.

  15. Power deposition by neutral beam injected fast ions in field-reversed configurations

    NASA Astrophysics Data System (ADS)

    Takahashi, Toshiki; Kato, Takayuki; Kondoh, Yoshiomi; Iwasawa, Naotaka

    2004-08-01

    The effects of Coulomb collisions on neutral beam (NB) injected fast ions into field-reversed configuration (FRC) plasmas are investigated by calculating the single particle orbits, where the ions are subject to the slowing-down and pitch-angle collisions. The Monte Carlo method is used for the pitch-angle scattering, and the friction term is added to the equation of motion to show the effects of the slowing-down collision, such as the deposited power profile. The calculation parameters used are relevant to the NB injection on the FRC injection experiment device [T. Asai, Y. Suzuki, T. Yoneda, F. Kodera, M. Okubo, and S. Goto, Phys. Plasmas 7, 2294 (2000)]. It is found that the dominant local power deposition occurs in the open field region between the X point and the mirror point because of a concentration of fast ions and a longer duration travel at the mirror reflection point. In the present calculation, the maximum deposited power to the FRC plasma is about 10% of the injected power. Although the pitch-angle scattering by Coulomb collision destroys the mirror confinement of NB injected fast ions, this effect is found to be negligible. The loss mechanism due to nonadiabatic fast ion motion, which is intrinsic in nonuniform FRC plasmas, has a much greater effect than the pitch-angle scattering by Coulomb collision.

  16. Ion charge state distributions of pulsed vacuum arc plasmas in strong magnetic fields

    SciTech Connect

    Anders, A.; Yushkov, G.; Oks, E.; Nikolaev, A.; Brown, I.

    1998-02-01

    Vacuum arc plasmas with discharge currents of 300 A and duration 250 {mu}s have been produced in strong magnetic fields up to 4 T. Ion charge state distributions have been measured for C, Al, Ag, Ta, Pt, Ho, and Er with a time-of-flight charge-mass spectrometer. Our previous measurements have been confirmed which show that ion charge states can be considerably enhanced when increasing the magnetic field up to about 1 T. The new measurements address the question of whether or not the additional increase continues at even higher magnetic field strength. It has been found that the increase becomes insignificant for field strengths greater than 1 T. Ion charge state distributions are almost constant for magnetic field strengths between 2 and 4 T. The results are explained by comparing the free expansion length with the freezing length. The most significant changes of charge state distributions are observed when these lengths are similar. {copyright} {ital 1998 American Institute of Physics.}

  17. Balancing the interactions of ions, water, and DNA in the Drude polarizable force field.

    PubMed

    Savelyev, Alexey; MacKerell, Alexander D

    2014-06-19

    Recently we presented a first-generation all-atom Drude polarizable force field for DNA based on the classical Drude oscillator model, focusing on optimization of key dihedral angles followed by extensive validation of the force field parameters. Presently, we describe the procedure for balancing the electrostatic interactions between ions, water, and DNA as required for development of the Drude force field for DNA. The proper balance of these interactions is shown to impact DNA stability and subtler conformational properties, including the conformational equilibrium between the BI and BII states, and the A and B forms of DNA. The parametrization efforts were simultaneously guided by gas-phase quantum mechanics (QM) data on small model compounds and condensed-phase experimental data on the hydration and osmotic properties of biologically relevant ions and their solutions, as well as theoretical predictions for ionic distribution around DNA oligomer. In addition, fine-tuning of the internal base parameters was performed to obtain the final DNA model. Notably, the Drude model is shown to more accurately reproduce counterion condensation theory predictions of DNA charge neutralization by the condensed ions as compared to the CHARMM36 additive DNA force field, indicating an improved physical description of the forces dictating the ionic solvation of DNA due to the explicit treatment of electronic polarizability. In combination with the polarizable DNA force field, the availability of Drude polarizable parameters for proteins, lipids, and carbohydrates will allow for simulation studies of heterogeneous biological systems. PMID:24874104

  18. Balancing the Interactions of Ions, Water, and DNA in the Drude Polarizable Force Field

    PubMed Central

    2015-01-01

    Recently we presented a first-generation all-atom Drude polarizable force field for DNA based on the classical Drude oscillator model, focusing on optimization of key dihedral angles followed by extensive validation of the force field parameters. Presently, we describe the procedure for balancing the electrostatic interactions between ions, water, and DNA as required for development of the Drude force field for DNA. The proper balance of these interactions is shown to impact DNA stability and subtler conformational properties, including the conformational equilibrium between the BI and BII states, and the A and B forms of DNA. The parametrization efforts were simultaneously guided by gas-phase quantum mechanics (QM) data on small model compounds and condensed-phase experimental data on the hydration and osmotic properties of biologically relevant ions and their solutions, as well as theoretical predictions for ionic distribution around DNA oligomer. In addition, fine-tuning of the internal base parameters was performed to obtain the final DNA model. Notably, the Drude model is shown to more accurately reproduce counterion condensation theory predictions of DNA charge neutralization by the condensed ions as compared to the CHARMM36 additive DNA force field, indicating an improved physical description of the forces dictating the ionic solvation of DNA due to the explicit treatment of electronic polarizability. In combination with the polarizable DNA force field, the availability of Drude polarizable parameters for proteins, lipids, and carbohydrates will allow for simulation studies of heterogeneous biological systems. PMID:24874104

  19. Optical field ionization of atoms and ions using ultrashort laser pulses

    SciTech Connect

    Fittinghoff, D.N.

    1993-12-01

    This dissertation research is an investigation of the strong optical field ionization of atoms and ions by 120-fs, 614-run laser pulses and 130-fs, 800-nm laser pulses. The experiments have shown ionization that is enhanced above the predictions of sequential tunneling models for He{sup +2}, Ne{sup +2} and Ar{sup +2}. The ion yields for He{sup +l}, Ne{sup +l} and Ar{sup +l} agree well with the theoretical predictions of optical tunneling models. Investigation of the polarization dependence of the ionization indicates that the enhancements are consistent with a nonsequential ionization mechanism in which the linearly polarized field drives the electron wavefunction back toward the ion core and causes double ionization through inelastic e-2e scattering. These investigations have initiated a number of other studies by other groups and are of current scientific interest in the fields of high-irradiance laser-matter interactions and production of high-density plasmas. This work involved: (1) Understanding the characteristic nature of the ion yields produced by tunneling ionization through investigation of analytic solutions for tunneling at optical frequencies. (2) Extensive characterization of the pulses produced by 614-nm and 800-ran ultrashort pulse lasers. Absolute calibration of the irradiance scale produced shows the practicality of the inverse problem--measuring peak laser irradiance using ion yields. (3) Measuring the ion yields for three noble gases using linear, circular and elliptical polarizations of laser pulses at 614-nm and 800-nm. The measurements are some of the first measurements for pulse widths as low as 120-fs.

  20. Spin dynamics in relativistic ionization with highly charged ions in super-strong laser fields

    NASA Astrophysics Data System (ADS)

    Klaiber, Michael; Yakaboylu, Enderalp; Müller, Carsten; Bauke, Heiko; Paulus, Gerhard G.; Hatsagortsyan, Karen Z.

    2014-03-01

    Spin dynamics and induced spin effects in above-threshold ionization of hydrogenlike highly charged ions in super-strong laser fields are investigated. Spin-resolved ionization rates in the tunnelling regime are calculated by employing two versions of a relativistic Coulomb-corrected strong-field approximation (SFA). An intuitive simpleman model is developed which explains the derived scaling laws for spin flip and spin asymmetry effects. The intuitive model as well as our ab initio numerical simulations support the analytical results for the spin effects obtained in the dressed SFA where the impact of the laser field on the electron spin evolution in the bound state is taken into account. In contrast, the standard SFA is shown to fail in reproducing spin effects in ionization even at a qualitative level. The anticipated spin-effects are expected to be measurable with modern laser techniques combined with an ion storage facility.

  1. Simulation of electrostatic ion instabilities in the presence of parallel currents and transverse electric fields

    NASA Technical Reports Server (NTRS)

    Nishikawa, K.-I.; Ganguli, G.; Lee, Y. C.; Palmadesso, P. J.

    1989-01-01

    A spatially two-dimensional electrostatic PIC simulation code was used to study the stability of a plasma equilibrium characterized by a localized transverse dc electric field and a field-aligned drift for L is much less than Lx, where Lx is the simulation length in the x direction and L is the scale length associated with the dc electric field. It is found that the dc electric field and the field-aligned current can together play a synergistic role to enable the excitation of electrostatic waves even when the threshold values of the field aligned drift and the E x B drift are individually subcritical. The simulation results show that the growing ion waves are associated with small vortices in the linear stage, which evolve to the nonlinear stage dominated by larger vortices with lower frequencies.

  2. Novel electrostatic column for ion projection lithography

    SciTech Connect

    Chalupka, A.; Stengl, G.; Buschbeck, H.; Lammer, G.; Vonach, H.; Fischer, R.; Hammel, E.; Loeschner, H.; Nowak, R.; Wolf, P. ); Finkelstein, W.; Hill, R.W. ); Berry, I.L. ); Harriott, L.R. ); Melngailis, J. ); Randall, J.N. ); Wolfe, J.C. ); Stroh, H.; Wollnik, H. ); Mondelli, A.A.; Petillo, J.J. ); Leung, K. (Lawrence Berkeley Laboratory, University of Californi

    1994-11-01

    Ion projection lithography (IPL) is being considered for high volume sub-0.25-[mu]m lithography. A novel ion-optical column has been designed for exposing 20[times]20 mm[sup 2] fields at 3[times] reduction from stencil mask to wafer substrates. A diverging lens is realized by using the stencil mask as the first electrode of the ion-optical column. The second and third electrode form an accelerating field lens. The aberrations of the first two lenses (diverging lens and field lens) are compensated by an asymmetric Einzel lens projecting an ion image of the stencil mask openings onto the wafer substrate with better than 2 mrad telecentricity. Less than 30 nm intrafield distortion was calculated within 20[times]20 mm[sup 2] exposure fields. The calculation uncertainty is estimated to be about 10 nm. The calculation holds for helium ions with [approx]10 keV ion energy at the stencil mask and 150 keV ion energy at the wafer plane. A virtual ion source size of 10 [mu]m has been assumed. The calculated chromatic aberrations are less than 60 nm, assuming 6 eV energy spread of the ions extracted from a duoplasmatron source. Recently a multicusp ion source has been developed for which preliminary results indicate an energy spread of less than 2 eV. Thus, with a multicusp source chromatic aberrations of less than 20 nm are to be expected. The ion energy at the crossover between the field lens and the asymmetric Einzel lens is 200 keV. Therefore, stochastic space charge induced degradations in resolution can be kept sufficiently low. The divergence of the ion image projected to the wafer plane is less than 2 mrad. Thus, the usable'' depth of focus for the novel ion optics is in the order of 10 [mu]m.

  3. Chaotic behavior of collective ion dynamics in the presence of an external static magnetic field

    NASA Astrophysics Data System (ADS)

    Poria, Swarup; Ghosh, Samiran

    2016-06-01

    The two-dimensional nonlinear collective ion dynamics in the presence of external magnetic field in an electron-ion plasma is investigated. The analysis is performed for traveling plane waves to elucidate the various aspects of the phase-space dynamics. The presence of magnetic field makes the dynamics of the nonlinear wave complex with a complicated phase-space behavior. Thus, the nonlinear wave supports a wide class of nonlinear structures viz., single soliton, multi-soliton, periodic, and quasi-periodic oscillations depending on the values of M (Mach number) and Ω (the ratio of ion gyro-frequency to the ion plasma frequency). The computational results predict the chaotic behavior of the nonlinear wave and the transition to chaos takes place when Ω ≳ 0.35 depending on the direction of propagation and the value of M. The amplitude of the wave depends on the obliqueness of the propagation and Mach number, whereas the magnetic field changes the dispersion properties of the wave.

  4. Linear ion trap with added octopole field component: the property and method.

    PubMed

    Dang, Qiankun; Xu, Fuxing; Huang, Xiaohua; Fang, Xiang; Wang, Rizhi; Ding, Chuan-Fan

    2015-12-01

    It is well known that superimposition of some positive octopole field will benefit the performance of ion trap mass analyzer. In the radial-ejection linear ion trap (LIT), adding some octopole field component to the main quadrupole field is usually accomplished by stretching the ejection rod pair. In this study, the effect of octopole potential and some other higher order potential on the performance of LIT mass analyzer is investigated. A simple and effective method, which is to add some octopole component by building a LIT with a pair of rectangular electrodes and a pair of semi-circular electrodes, is reported. Its properties were studied by numerical simulations and experiments. The results showed that a certain amount of positive octopole component could be produced by simply adjusting the position and width of the rectangular electrodes. A resolution of over 1200 at m/z 609 (~1600 Da/s) was observed in this type of LIT. They also performed tandem mass spectrometry well. The device with optimum geometry for ion ejection from rectangular electrodes provided comparable performance to that for ion ejection from semi-circular electrodes. This type of LIT design is easy for fabrication and assembly. PMID:26634975

  5. Channel waveguides in glass via silver-sodium field-assisted ion exchange

    NASA Technical Reports Server (NTRS)

    Forrest, K.; Pagano, S. J.; Viehmann, W.

    1986-01-01

    Multimode channel waveguides have been formed in sodium aluminosilicate glass by field-assisted diffusion of Ag(+) ions from vacuum-evaporated Ag films. The two-dimensional refractive index profiles of the waveguides were controlled by varying the diffusion time, the diffusion temperature, and the electric field strength. Estimates of the diffusion rate through a strip aperture were obtained, assuming the electric field was strong 120-240 V/mm. The maximum change in refractive index in the sodium aluminosilicate glasses was estimated near 65 percent of the change in soda-lime silicate glass. The physical properties of the glasses are given in a table.

  6. Creation and recovery of a W(111) single atom gas field ion source

    SciTech Connect

    Pitters, Jason L.; Urban, Radovan; Wolkow, Robert A.

    2012-04-21

    Tungsten single atom tips have been prepared from a single crystal W(111) oriented wire using the chemical assisted field evaporation and etching method. Etching to a single atom tip occurs through a symmetric structure and leads to a predictable last atom unlike etching with polycrystalline tips. The single atom tip formation procedure is shown in an atom by atom removal process. Rebuilds of single atom tips occur on the same crystalline axis as the original tip such that ion emission emanates along a fixed direction for all tip rebuilds. This preparation method could be utilized and developed to prepare single atom tips for ion source development.

  7. Ion and electron emission from silver nanoparticles in intense laser fields

    SciTech Connect

    Doeppner, T.; Fennel, Th.; Radcliffe, P.; Tiggesbaeumker, J.; Meiwes-Broer, K.-H.

    2006-03-15

    By a comparative analysis of the emission of highly charged ions and energetic electrons the interaction dynamics of intense femtosecond laser fields (10{sup 13}-10{sup 14} W/cm{sup 2}) with nanometer-sized silver clusters is investigated. Using dual laser pulses with variable optical delay the time-dependent cluster response is resolved. A dramatic increase both in the atomic charge state of the ions and the maximum electron kinetic energy is observed for a certain delay of the pulses. Corresponding Vlasov calculations on a metal cluster model system indicate that enhanced cluster ionization as well as the generation of fast electrons coincide with resonant plasmon excitation.

  8. Electron-ion dynamics of H(2)(+) in intense laser fields

    NASA Astrophysics Data System (ADS)

    Khosravi, Shahram

    1997-12-01

    The interaction of the molecular hydrogen ion H2+ with intense laser fields is currently an area of active investigation. Since this interaction is highly nonlinear, nonperturbative techniques are required, which go beyond Fermi's golden rule and perturbation theory. In previous work, the Born-Oppenheimer approximation has been used to separate the molecular Schrodinger equation into two equations, one for the electron and one for the ions. This approximation has the following important shortcomings: First, it ignores the coupling between the electron dynamics and the ion dynamics, which is an important aspect of the system. Second, in the analysis of the electron dynamics, the ions are assumed to be fixed in space. Our simulations will show that the ions move significantly during the interaction. and that their motion has an important effect on the final outcome of the reaction. The first stage of the present work was the construction of a realistic and quantitatively accurate model for the relevant electronic states, as functions of the internuclear separation R. Then simulations were performed, with the dynamics of the electron and the ions treated through numerical solution of the time-dependent Schrodinger equation and Newton's equation of motion. Various initial conditions for the molecule were assumed, together with different intensities and durations for the laser pulse. Some of the more interesting runs are shown and discussed in this dissertation. We find a rich variety of phenomena, including ion trapping (on a subpicosecond time scale), sudden electronic transitions (as the system follows an adiabatic potential curve), above-threshold dissociation (ATD), bond softening, and harmonic generation (up to order 11 in the present simulations). Many of these phenomena can be understood using a dressed-state picture, or Floquet analysis. However, detailed understanding must be based on the intricate interplay between the dynamics of the electron and the ions, a

  9. Ion-cage interpretation for the structural and dynamic changes of ionic liquids under an external electric field.

    PubMed

    Shi, Rui; Wang, Yanting

    2013-05-01

    In many applications, ionic liquids (ILs) work in a nonequilibrium steady state driven by an external electric field. However, how the electric field changes the structure and dynamics of ILs and its underlying mechanism still remain poorly understood. In this paper, coarse-grained molecular dynamics simulations were performed to investigate the structure and dynamics of 1-ethyl-3-methylimidazolium nitrate ([EMIm][NO3]) under a static electric field. The ion cage structure was found to play an essential role in determining the structural and dynamic properties of the IL system. With a weak or moderate electric field (0-10(7) V/m), the external electric field is too weak to modify the ion cage structure in an influential way and thus the changes of structural and dynamic properties are negligible. With a strong electric field (10(7)-10(9) V/m) applied, ion cages expand and deform apparently, leading to the increase of ion mobility and self-diffusion coefficient with electric field, and the self-diffusion of ions along the electric field becomes faster than the other two directions due to the anisotropic deformation of ion cages. In addition, the Einstein relation connecting diffusion and mobility breaks down at strong electric fields, and it also breaks down for a single ion species even at moderate electric fields (linear-response region). PMID:23557150

  10. Electric field variations due to resonance between ground velocity and ions motion in the Earth's magnetic field

    NASA Astrophysics Data System (ADS)

    Matsushima, M.; Honkura, Y.; Kuriki, M.; Ogawa, Y.

    2011-12-01

    We have so far observed clear electric field variations coincident with the passage of seismic waves. Circular polarization of electric field is the distinguishing feature in this phenomenon which can be interpreted in terms of the so-called seismic dynamo effect proposed by Honkura et al. (2009). That is, circularly polarized electric field is caused by resonance-like motion of ion in groundwater under the Earth's magnetic field. Therefore, left-handed and right-handed circular polarizations, if seen towards the direction of the magnetic field, are associated with anions with negative charge and cations with positive charge, respectively. Such polarization may be inconsistent with seismoelectric signals due to the electrokinetic mechanism, because they are mainly found in the direction of transmission of seismic compressional waves, as pointed out by Strahser et al. (2007) who examined polarization of seismoelectric signals by recording the three components of electric field. However, even such circular polarization of electric field is somehow interpreted in terms of the electrokinetic mechanism. Therefore, further convincing evidence is required to support the seismic dynamo effect. On 25-26 July 2011, an experiment for studies of crustal seismic structure was made in central Japan. We carried out simultaneous observations of ground velocity and electric field on this occasion at three sites near a blasting point using 50 kg of dynamite; about 280 m east-southeast, about 190 m east, and about 360 m northwest from the blasting point. Taking into account typical frequencies of ground velocity for artificial earthquakes by blasting higher than those for natural earthquakes, we used data loggers with sampling rate of 1 kHz and could obtain the waveforms of ground velocity and electric field very clearly. We show characteristics of electric field variations, their dependence of azimuth angle with respect to the blasting point, and frequency response functions.

  11. Acidity field of soils as ion-exchange systems and the diagnostics of genetic soil horizons

    NASA Astrophysics Data System (ADS)

    Kokotov, Yu. A.; Sukhacheva, E. Yu.; Aparin, B. F.

    2014-12-01

    For the comprehensive description of the acidity of a two-phase ion-exchange system, we should analyze two curves of the ionite titration by a strong base in water and salt solutions and find the quantitative relationships between the corresponding pH characteristics. An idea of the three-dimensional field of acidity of ion-exchange systems (the phase space of the soil acidity characteristics) and its three two-dimensional projections is suggested. For soils, three interrelated characteristics—the pH values of the salt and water extracts and the degree of base saturation—can serve as spatial coordinates for the acidity field. Representation of factual data in this field makes it possible to compare and analyze the acidity characteristics of different soils and soil horizons and to determine their specific features. Differentiation of the field into separate volumes allows one to present the data in a discrete form. We have studied the distribution patterns of the groups of soil horizons from Leningrad oblast and other regions of northwestern Russia in the acidity field. The studied samples are grouped in different partially overlapping areas of the projections of the acidity field. The results of this grouping attest to the correctness of the modern classification of Russian soils. A notion of the characteristic soil area in the acidity field is suggested; it can be applied to all the soils with a leaching soil water regime.

  12. Energy loss of ions by electric-field fluctuations in a magnetized plasma

    SciTech Connect

    Nersisyan, Hrachya B.; Deutsch, Claude

    2011-06-15

    The results of a theoretical investigation of the energy loss of charged particles in a magnetized classical plasma due to the electric-field fluctuations are reported. The energy loss for a test particle is calculated through the linear-response theory. At vanishing magnetic field, the electric-field fluctuations lead to an energy gain of the charged particle for all velocities. It has been shown that in the presence of strong magnetic field, this effect occurs only at low velocities. In the case of high velocities, the test particle systematically loses its energy due to the interaction with a stochastic electric field. The net effect of the fluctuations is the systematic reduction of the total energy loss (i.e., the sum of the polarization and stochastic energy losses) at vanishing magnetic field and reduction or enhancement at strong field, depending on the velocity of the particle. It is found that the energy loss of the slow heavy ion contains an anomalous term that depends logarithmically on the projectile mass. The physical origin of this anomalous term is the coupling between the cyclotron motion of the plasma electrons and the long-wavelength, low-frequency fluctuations produced by the projectile ion. This effect may strongly enhance the stochastic energy gain of the particle.

  13. Models Ion Trajectories in 2D and 3D Electrostatic and Magnetic Fields

    Energy Science and Technology Software Center (ESTSC)

    2000-02-21

    SIMION3D7.0REV is a C based ion optics simulation program that can model complex problems using Laplace equation solutions for potential fields. The program uses an ion optics workbench that can hold up to 200 2D and/or 3D electrostatic/magnetic potential arrays. Arrays can have up to 50,000,000 points. SIMION3D7.0''s 32 bit virtual Graphics User Interface provides a highly interactive advanced user environment. All potential arrays are visualized as 3D objects that the user can cut awaymore » to inspect ion trajectories and potential energy surfaces. User programs allow the user to customize the program for specific simulations. A geometry file option supports the definition of highly complex array geometry. Algorithm modifications have improved this version''s computational speed and accuracy.« less

  14. Ion field-evaporation from ionic liquids infusing carbon xerogel microtips

    SciTech Connect

    Perez-Martinez, C. S. Lozano, P. C.

    2015-07-27

    Ionic liquid ion sources capable of producing positive and negative molecular ion beams from room-temperature molten salts have applications in diverse fields, from materials science to space propulsion. The electrostatic stressing of these ionic liquids places the liquid surfaces in a delicate balance that could yield unwanted droplet emission when not properly controlled. Micro-tip emitter configurations are required to guarantee that these sources will operate in a pure ionic regime with no additional droplets. Porous carbon based on resorcinol-formaldehyde xerogels is introduced as an emitter substrate. It is demonstrated that this material can be shaped to the required micron-sized geometry and has appropriate transport properties to favor pure ionic emission. Time-of-flight mass spectrometry is used to verify that charged particle beams contain solvated ions exclusively.

  15. Models Ion Trajectories in 2D and 3D Electrostatic and Magnetic Fields

    SciTech Connect

    Dahl, David

    2000-02-21

    SIMION3D7.0REV is a C based ion optics simulation program that can model complex problems using Laplace equation solutions for potential fields. The program uses an ion optics workbench that can hold up to 200 2D and/or 3D electrostatic/magnetic potential arrays. Arrays can have up to 50,000,000 points. SIMION3D7.0''s 32 bit virtual Graphics User Interface provides a highly interactive advanced user environment. All potential arrays are visualized as 3D objects that the user can cut away to inspect ion trajectories and potential energy surfaces. User programs allow the user to customize the program for specific simulations. A geometry file option supports the definition of highly complex array geometry. Algorithm modifications have improved this version''s computational speed and accuracy.

  16. A compact broadband ion beam focusing device based on laser-driven megagauss thermoelectric magnetic fields

    NASA Astrophysics Data System (ADS)

    Albertazzi, B.; d'Humières, E.; Lancia, L.; Dervieux, V.; Antici, P.; Böcker, J.; Bonlie, J.; Breil, J.; Cauble, B.; Chen, S. N.; Feugeas, J. L.; Nakatsutsumi, M.; Nicolaï, P.; Romagnani, L.; Shepherd, R.; Sentoku, Y.; Swantusch, M.; Tikhonchuk, V. T.; Borghesi, M.; Willi, O.; Pépin, H.; Fuchs, J.

    2015-04-01

    Ultra-intense lasers can nowadays routinely accelerate kiloampere ion beams. These unique sources of particle beams could impact many societal (e.g., proton-therapy or fuel recycling) and fundamental (e.g., neutron probing) domains. However, this requires overcoming the beam angular divergence at the source. This has been attempted, either with large-scale conventional setups or with compact plasma techniques that however have the restriction of short (<1 mm) focusing distances or a chromatic behavior. Here, we show that exploiting laser-triggered, long-lasting (>50 ps), thermoelectric multi-megagauss surface magnetic (B)-fields, compact capturing, and focusing of a diverging laser-driven multi-MeV ion beam can be achieved over a wide range of ion energies in the limit of a 5° acceptance angle.

  17. Ion field-evaporation from ionic liquids infusing carbon xerogel microtips

    NASA Astrophysics Data System (ADS)

    Perez-Martinez, C. S.; Lozano, P. C.

    2015-07-01

    Ionic liquid ion sources capable of producing positive and negative molecular ion beams from room-temperature molten salts have applications in diverse fields, from materials science to space propulsion. The electrostatic stressing of these ionic liquids places the liquid surfaces in a delicate balance that could yield unwanted droplet emission when not properly controlled. Micro-tip emitter configurations are required to guarantee that these sources will operate in a pure ionic regime with no additional droplets. Porous carbon based on resorcinol-formaldehyde xerogels is introduced as an emitter substrate. It is demonstrated that this material can be shaped to the required micron-sized geometry and has appropriate transport properties to favor pure ionic emission. Time-of-flight mass spectrometry is used to verify that charged particle beams contain solvated ions exclusively.

  18. A compact broadband ion beam focusing device based on laser-driven megagauss thermoelectric magnetic fields.

    PubMed

    Albertazzi, B; d'Humières, E; Lancia, L; Dervieux, V; Antici, P; Böcker, J; Bonlie, J; Breil, J; Cauble, B; Chen, S N; Feugeas, J L; Nakatsutsumi, M; Nicolaï, P; Romagnani, L; Shepherd, R; Sentoku, Y; Swantusch, M; Tikhonchuk, V T; Borghesi, M; Willi, O; Pépin, H; Fuchs, J

    2015-04-01

    Ultra-intense lasers can nowadays routinely accelerate kiloampere ion beams. These unique sources of particle beams could impact many societal (e.g., proton-therapy or fuel recycling) and fundamental (e.g., neutron probing) domains. However, this requires overcoming the beam angular divergence at the source. This has been attempted, either with large-scale conventional setups or with compact plasma techniques that however have the restriction of short (<1 mm) focusing distances or a chromatic behavior. Here, we show that exploiting laser-triggered, long-lasting (>50 ps), thermoelectric multi-megagauss surface magnetic (B)-fields, compact capturing, and focusing of a diverging laser-driven multi-MeV ion beam can be achieved over a wide range of ion energies in the limit of a 5° acceptance angle. PMID:25933857

  19. Mode conversion and absorption of fast waves at high ion cyclotron harmonics in inhomogeneous magnetic fields

    SciTech Connect

    Cho, Suwon; Kwak, Jong-Gu

    2014-04-15

    The propagation and absorption of high harmonic fast waves is of interest for non-inductive current drives in fusion experiments. The fast wave can be coupled with the ion Bernstein wave that propagates in the high magnetic field side of an ion cyclotron harmonic resonance layer. This coupling and the absorption are analyzed using the hot plasma dispersion relation and a wave equation that was converted from an approximate dispersion relation for the case where λ{sub i}=k{sub ⊥}{sup 2}ρ{sub i}{sup 2}/2≳1 (where k{sub ⊥} is the perpendicular wave number and ρ{sub i} is the ion Larmor radius). It is found that both reflection and conversion may occur near the harmonic resonance layer but that they decrease rapidly, giving rise to a sharp increase in the absorption as the parallel wave number increases.

  20. Manipulation of transport hysteresis on graphene field effect transistors with Ga ion irradiation

    SciTech Connect

    Wang, Quan; Liu, Shuai; Ren, Naifei

    2014-09-29

    We have studied the effect of Ga ion irradiation on the controllable hysteretic behavior of graphene field effect transistors fabricated on Si/SO{sub 2} substrates. The various densities of defects in graphene were monitored by Raman spectrum. It was found that the Dirac point shifted to the positive gate voltage constantly, while the hysteretic behavior was enhanced first and then weakened, with the dose of ion irradiation increasing. By contrasting the trap charges density induced by dopant and the total density of effective trap charges, it demonstrated that adsorbate doping was not the decisive factor that induced the hysteretic behavior. The tunneling between the defect sites induced by ion irradiation was also an important cause for the hysteresis.