Mapping the evolution of scientific fields.

PubMed

Herrera, Mark; Roberts, David C; Gulbahce, Natali

2010-05-04

Despite the apparent cross-disciplinary interactions among scientific fields, a formal description of their evolution is lacking. Here we describe a novel approach to study the dynamics and evolution of scientific fields using a network-based analysis. We build an idea network consisting of American Physical Society Physics and Astronomy Classification Scheme (PACS) numbers as nodes representing scientific concepts. Two PACS numbers are linked if there exist publications that reference them simultaneously. We locate scientific fields using a community finding algorithm, and describe the time evolution of these fields over the course of 1985-2006. The communities we identify map to known scientific fields, and their age depends on their size and activity. We expect our approach to quantifying the evolution of ideas to be relevant for making predictions about the future of science and thus help to guide its development.

Development of a Field-Deployable Methane Carbon Isotope Analyzer

NASA Astrophysics Data System (ADS)

Dong, Feng; Baer, Douglas

2010-05-01

Methane is a potent greenhouse gas, whose atmospheric surface mixing ratio has almost doubled compared with preindustrial values. Methane can be produced by biogenic processes, thermogenic processes or biomass, with different isotopic signatures. As a key molecule involved in the radiative forcing in the atmosphere, methane is thus one of the most important molecules linking the biosphere and atmosphere. Therefore precise measurements of mixing ratios and isotopic compositions will help scientists to better understand methane sources and sinks. To date, high precision isotope measurements have been exclusively performed with conventional isotope ratio mass spectrometry, which involves intensive labor and is not readily field deployable. Optical studies using infrared laser spectroscopy have also been reported to measure the isotopic ratios. However, the precision of optical-based analyses, to date, is typically unsatisfactory without pre-concentration procedures. We present characterization of the performance of a portable Methane Carbon Isotope Analyzer (MCIA), based on cavity enhanced laser absorption spectroscopy technique, that provides in-situ measurements of the carbon isotope ratio (13C/12C or del_13C) and methane mixing ratio (CH4). The sample is introduced to the analyzer directly without any requirement for pretreatment or preconcentration. A typical precision of less than 1 per mill (< 0.1%) with a 10-ppm methane sample can be achieved in a measurement time of less than 100 seconds. The MCIA can report carbon isotope ratio and concentration measurements over a very wide range of methane concentrations. Results of laboratory tests and field measurements will be presented.

Mapping the Evolution of Scientific Fields

PubMed Central

Herrera, Mark; Roberts, David C.; Gulbahce, Natali

2010-01-01

Despite the apparent cross-disciplinary interactions among scientific fields, a formal description of their evolution is lacking. Here we describe a novel approach to study the dynamics and evolution of scientific fields using a network-based analysis. We build an idea network consisting of American Physical Society Physics and Astronomy Classification Scheme (PACS) numbers as nodes representing scientific concepts. Two PACS numbers are linked if there exist publications that reference them simultaneously. We locate scientific fields using a community finding algorithm, and describe the time evolution of these fields over the course of 1985–2006. The communities we identify map to known scientific fields, and their age depends on their size and activity. We expect our approach to quantifying the evolution of ideas to be relevant for making predictions about the future of science and thus help to guide its development. PMID:20463949

Stable isotope paleoaltimetry and the evolution of landscapes and life

NASA Astrophysics Data System (ADS)

Mulch, Andreas

2016-01-01

circulation and associated teleconnections in the global climate system that affect δ18O or δD of precipitation; (2) Evaluating on a case-by-case basis if temporal and spatial changes in isotope lapse rates influence interpretations of paleoelevation; (3) Interfacing with phylogenetic techniques to evaluate competing hypotheses with respect to the timing of surface uplift and the diversification of lineages; (4) Characterizing feedbacks between changes in surface elevation and atmospheric circulation as these are likely to be equally important to the diversification of lineages than changes in surface elevation alone. Tackling these challenges will benefit from the accelerating pace of improved data-model comparisons and rapidly evolving geochemical techniques for reconstructing precipitation patterns. Most importantly, stable isotope paleoaltimetry has the potential to develop into a truly interdisciplinary field if innovative tectonic/paleoclimatic and evolutionary biology/phylogenetic approaches are integrated into a common research framework. It therefore, opens new avenues to study the long-term evolution of landscapes and life.

High-frequency field-deployable isotope analyzer for hydrological applications

Treesearch

Elena S.F. Berman; Manish Gupta; Chris Gabrielli; Tina Garland; Jeffrey J. McDonnell

2009-01-01

A high-frequency, field-deployable liquid water isotope analyzer was developed. The instrument was deployed for 4 contiguous weeks in the H. J. Andrews Experimental Forest Long-term Ecological Research site in western Oregon, where it was used for real-time measurement of the isotope ratios of precipitation and stream water during three large storm events. We were able...

The sources and time-integrated evolution of diamond-forming fluids - Trace elements and isotopic evidence

NASA Astrophysics Data System (ADS)

Klein-BenDavid, Ofra; Pearson, D. Graham; Nowell, Geoff M.; Ottley, Chris; McNeill, John C. R.; Logvinova, Alla; Sobolev, Nikolay V.

2014-01-01

Sub-micrometer inclusions in fibrous diamond growth zones carry high-density fluids (HDF) from which the host diamonds have precipitated. The chemistry of these fluids is our best opportunity of characterizing the diamond-forming environment. The major and trace element patterns of diamond-forming fluids vary widely. Such elemental signatures can be easily modified by a variety of mantle processes whereas radiogenic isotopes give a clear fingerprint of the time-integrated evolution of the fluid source region. Thus, the combination of elemental and isotope data is a powerful tool in constraining the origin of fluids from which diamonds precipitate. Here we present combined trace element composition (34 diamonds) and Sr isotopic data (23 diamonds) for fluid-rich diamonds from six worldwide locations. The Nd and Pb isotopic composition of two of the diamonds were also obtained. Several of the samples were analyzed in at least 2 locations to investigate variations in the fluid during diamond growth. The data was acquired using an off-line laser sampling technique followed by solution ICPMS and TIMS analysis. The Sr isotopic compositions of diamond fluids from the different suites range between convecting mantle values for Udachnaya (87Sr/86Sr363 = 0.70300 ± 16 to 0.70361 ± 4), to highly enriched values, up to 87Sr/86Sr = 0.72330 ± 3, for a diamond from Congo. No isochronous relationships were observed in any of the suites. The lowest Nd isotopic composition recorded so far in a diamond is from Congo (εNd71 = -40.4), which also contains the most radiogenic Sr isotopic composition. In contrast, a less enriched but still rather unradiogenic Nd isotope composition (εNd540 = -11) was obtained for a diamond from Snap Lake, which has moderately radiogenic Sr isotopic enrichment (87Sr/86Sr540 = 0.70821 ± 1). The Pb isotopic system measured in one diamond indicates a complex evolution for the fluid source, with extreme 207Pb/204Pb ratio (15.810 ± 3) and moderate

Mg-Fe Isotope Systems of Mantle Xenoliths: Constrains on the Evolution of Siberian Craton

NASA Astrophysics Data System (ADS)

An, Y.; Kiseeva, E. S.; Sobolev, N. V.; Zhang, Z.

2017-12-01

Mantle xenoliths bring to the surface a variety of lithologies (dunites, lherzolites, harzburgites, wehrlites, eclogites, pyroxenites, and websterites) and represent snapshots of the geochemical processes that occur deep within the Earth. Recent improvements in the precision of the MC-ICP-MS measurements have allowed us to expand the amount of data on Mg and Fe isotopes for mantle-derived samples. For instance, to constrain the isotopic composition of the Earth based on the study of spinel and garnet peridotites (An et al., 2017; Teng et al., 2010), to trace the origin and to investigate the isotopic fractionation mechanism during metamorphic process using cratonic or orogenic eclogites (Li et al., 2011; Wang et al., 2012) and to reveal the metasomatism-induced mantle heterogeneity by pyroxenites (Hu et al., 2016). Numerous multi-stage modification events and mantle layering are detected in the subcontinental lithospheric mantle under the Siberian craton (Ashchepkov et al., 2008a; Sobolev et al., 1975, etc). Combined analyses of Mg and Fe isotopic systems could provide new constraints on the formation and evolution of the ancient cratonic mantle. In order to better constrain the magnitude and mechanism of inter-mineral Mg and Fe isotopic fractionations at high temperatures, systematic studies of mantle xenoliths are needed. For example, theoretical calculations and natural samples measurements have shown that large equilibrium Mg isotope fractionations controlled by the difference in coordination number of Mg among minerals could exist (Huang et al., 2013; Li et al., 2011). Thus, the Mg isotope geothermometer could help us trace the evolution history of ancient cratons. In this study we present Mg and Fe isotopic data for whole rocks and separated minerals (clinopyroxene (cpx) and garnet (grt)) from different types of mantle xenoliths (garnet pyroxenites, eclogites, grospydites and garnet peridotites) from a number of kimberlite pipes in Siberian craton (Udachnaya

Ca Isotopes Fingerprinting the Earliest Crustal Evolution

NASA Astrophysics Data System (ADS)

Kreissig, K.; Elliott, T. R.

2001-12-01

The mechanisms of continent formation remain unclear and can be explained in two contrasting ways, using either a steady state crustal growth model involving massive crustal recycling or continuous crustal growth models. Recent developments in mass spectrometry manifest in the new Finnigan-Triton allow Ca isotopic measurements precise enough to use the K-Ca isotope system to address the problem of early Archaean crustal evolution. Due to a strong fractionation of 40K and 40Ca during continent formation and a non-linear growth of 40Ca, Archaean continental crust should show radiogenic initial Ca isotopic composition if large volumes of it have already been existed 3.6 Ga ago. Simple 15-step calculations predict a difference in 40Ca /44Ca of 9 epsilon units at 3.6 Ga between the two crustal growth models. To test this, as well as to study the earliest crust formation processes, plagioclase separates from Archaean provinces reflecting the initial Ca isotopic composition and a range of different whole rock samples have been analysed. Preliminary data for ~ 3.6 Ga old TTGs from Zimbabwe show 40Ca /44Ca indistinguishable from the mantle. This is in agreement with rather chondritic initial Sr and Nd data and might reflect a short residence time of the juvenile mafic oceanic crust before partial melting forming the first continental crust. In contrast, the first results for 3.65 Ga old samples from the Itsaq Gneiss Complex of southern West Greenland yield a more evolved radiogenic Ca signature. This can be interpreted in two different ways. Either as partial melting of juvenile mafic crust shortly after its formation but incorporating already existing crust as also suggested by the existence of older inherited zircons in these rocks and negative ɛ Hf values. Partial melting of mafic oceanic crust long after its formation so that 40K and 40Ca had time to evolve would be an alternative explanation. Importantly, there is no evidence so far for high growth and recycling rates

Isotopic evolution of Mauna Loa Volcano: A view from the submarine southwest rift zone

NASA Astrophysics Data System (ADS)

Kurz, Mark D.; Kenna, T. C.; Kammer, D. P.; Rhodes, J. Michael; Garcia, Michael O.

New isotopic and trace element measurements on lavas from the submarine southwest rift zone (SWR) of Mauna Loa continue the temporal trends of subaerial Mauna Loa flows, extending the known compositional range for this volcano, and suggesting that many of the SWR lavas are older than any exposed on land. He and Nd isotopic compositions are similar to those in the oldest subaerial Mauna Loa lavas (Kahuku and Ninole Basalts), while 87Sr/86Sr ratios are slightly lower (as low as .7036) and Pb isotopes are higher (206Pb'204Pb up to 18.30). The coherence of all the isotopes suggests that helium behaves as an incompatible element, and that helium isotopic variations in the Hawaiian lavas are produced by melting and mantle processes, rather than magma chamber or metasomatic processes unique to the gaseous elements. The variations of He, Sr, and Nd are most pronounced in lavas of approximately 10 ka age range [Kurz and Kammer, 1991], but the largest Pb isotopic variation occurs earlier. These variations are interpreted as resulting from the diminishing contribution from the upwelling mantle plume material as the shield building ends at Mauna Loa. The order of reduction in the plume isotopic signature is inferred to be Pb (at >100 ka), He (at ˜14 ka), Sr (at ˜9 ka), and Nd (at ˜8 ka); the different timing may relate to silicate/melt partition coefficients, with most incompatible elements removed first, and also to concentration variations within the plume. Zr/Nb, Sr/Nb, and fractionation-corrected Nb concentrations, correlate with the isotopes and are significantly higher in some of the submarine SWR lavas, suggesting temporal variability on time scales similar to the Pb isotopes (i.e. ˜ 100 ka). Historical lavas define trace element and isotopic trends that are distinct from the longer term (10 to 100 ka) variations, suggesting that different processes cause the short term variability. The temporal evolution of Mauna Loa, and particularly the new data from the

Evolution of deformation in neutron-rich Ba isotopes up to A =150

NASA Astrophysics Data System (ADS)

Licǎ, R.; Benzoni, G.; Rodríguez, T. R.; Borge, M. J. G.; Fraile, L. M.; Mach, H.; Morales, A. I.; Madurga, M.; Sotty, C. O.; Vedia, V.; De Witte, H.; Benito, J.; Bernard, R. N.; Berry, T.; Bracco, A.; Camera, F.; Ceruti, S.; Charviakova, V.; Cieplicka-Oryńczak, N.; Costache, C.; Crespi, F. C. L.; Creswell, J.; Fernandez-Martínez, G.; Fynbo, H.; Greenlees, P. T.; Homm, I.; Huyse, M.; Jolie, J.; Karayonchev, V.; Köster, U.; Konki, J.; Kröll, T.; Kurcewicz, J.; Kurtukian-Nieto, T.; Lazarus, I.; Lund, M. V.; Mǎrginean, N.; Mǎrginean, R.; Mihai, C.; Mihai, R. E.; Negret, A.; Orduz, A.; Patyk, Z.; Pascu, S.; Pucknell, V.; Rahkila, P.; Rapisarda, E.; Regis, J. M.; Robledo, L. M.; Rotaru, F.; Saed-Samii, N.; Sánchez-Tembleque, V.; Stanoiu, M.; Tengblad, O.; Thuerauf, M.; Turturica, A.; Van Duppen, P.; Warr, N.; IDS Collaboration

2018-02-01

The occurrence of octupolar shapes in the Ba isotopic chain was recently established experimentally up to N =90 . To further extend the systematics, the evolution of shapes in the most neutron-rich members of the Z =56 isotopic chain accessible at present, Ba,150148, has been studied via β decay at the ISOLDE Decay Station. This paper reports on the first measurement of the positive- and negative-parity low-spin excited states of 150Ba and presents an extension of the β -decay scheme of 148Cs. Employing the fast timing technique, half-lives for the 21+ level in both nuclei have been determined, resulting in T1 /2=1.51 (1 ) ns for 148Ba and T1 /2=3.4 (2 ) ns for 150Ba. The systematics of low-spin states, together with the experimental determination of the B (E 2 :2+→0+) transition probabilities, indicate an increasing collectivity in Ba-150148, towards prolate deformed shapes. The experimental data are compared to symmetry conserving configuration mixing (SCCM) calculations, confirming an evolution of increasingly quadrupole deformed shapes with a definite octupolar character.

Plutonium isotopes in the atmosphere of Central Europe: Isotopic composition and time evolution vs. circulation factors.

PubMed

Kierepko, Renata; Mietelski, Jerzy W; Ustrnul, Zbigniew; Anczkiewicz, Robert; Wershofen, Herbert; Holgye, Zoltan; Kapała, Jacek; Isajenko, Krzysztof

2016-11-01

This paper reports evidence of Pu isotopes in the lower part of the troposphere of Central Europe. The data were obtained based on atmospheric aerosol fraction samples collected from four places in three countries (participating in the informal European network known as the Ring of Five (Ro5)) forming a cell with a surface area of about 200,000km(2). We compared our original data sets from Krakow (Poland, 1990-2007) and Bialystok (Poland, 1991-2007) with the results from two other locations, Prague (Czech Republic; 1997-2004) and Braunschweig (Germany; 1990-2003) to find time evolution of the Pu isotopes. The levels of the activity concentration for (238)Pu and for ((239+240))Pu were estimated to be a few and some tens of nBqm(-3), respectively. However, we also noted some results were much higher (even about 70 times higher) than the average concentration of (238)Pu in the atmosphere. The achieved complex data sets were used to test a new approach to the problem of solving mixing isotopic traces from various sources (here up to three) in one sample. Results of our model, supported by mesoscale atmospheric circulation parameters, suggest that Pu from nuclear weapon accidents or tests and nuclear burnt-up fuel are present in the air. Copyright © 2016 Elsevier B.V. All rights reserved.

Low-lying structure and shape evolution in neutron-rich Se isotopes

NASA Astrophysics Data System (ADS)

Chen, S.; Doornenbal, P.; Obertelli, A.; Rodríguez, T. R.; Authelet, G.; Baba, H.; Calvet, D.; Château, F.; Corsi, A.; Delbart, A.; Gheller, J.-M.; Giganon, A.; Gillibert, A.; Lapoux, V.; Motobayashi, T.; Niikura, M.; Paul, N.; Roussé, J.-Y.; Sakurai, H.; Santamaria, C.; Steppenbeck, D.; Taniuchi, R.; Uesaka, T.; Ando, T.; Arici, T.; Blazhev, A.; Browne, F.; Bruce, A. M.; Caroll, R.; Chung, L. X.; Cortés, M. L.; Dewald, M.; Ding, B.; Flavigny, F.; Franchoo, S.; Górska, M.; Gottardo, A.; Jungclaus, A.; Lee, J.; Lettmann, M.; Linh, B. D.; Liu, J.; Liu, Z.; Lizarazo, C.; Momiyama, S.; Moschner, K.; Nagamine, S.; Nakatsuka, N.; Nita, C. R.; Nobs, C.; Olivier, L.; Orlandi, R.; Patel, Z.; Podolyak, Zs.; Rudigier, M.; Saito, T.; Shand, C.; Söderström, P.-A.; Stefan, I.; Vaquero, V.; Werner, V.; Wimmer, K.; Xu, Z.

2017-04-01

Neutron-rich 88,90,92,94Se isotopes were studied via in-beam γ -ray spectroscopy after nucleon removal reactions at intermediate energies at the Radioactive Isotope Beam Factory. Based on γ -γ coincidence analysis, low-lying excitation level schemes are proposed for these nuclei, including the 21+, 41+ states and 22+ states at remarkably low energies. The low-lying 22+ states, along with other features, indicate triaxiality in these nuclei. The experimental results are in good overall agreement with self-consistent beyond-mean-field calculations based on the Gogny D1S interaction, which suggests both triaxial degree of freedom and shape coexistence playing important roles in the description of intrinsic deformations in neutron-rich Se isotopes.

Coupled thermochemical, isotopic evolution and heat transfer simulations in highly irradiated UO2 nuclear fuel

NASA Astrophysics Data System (ADS)

Piro, M. H. A.; Banfield, J.; Clarno, K. T.; Simunovic, S.; Besmann, T. M.; Lewis, B. J.; Thompson, W. T.

2013-10-01

Predictive capabilities for simulating irradiated nuclear fuel behavior are enhanced in the current work by coupling thermochemistry, isotopic evolution and heat transfer. Thermodynamic models that are incorporated into this framework not only predict the departure from stoichiometry of UO2, but also consider dissolved fission and activation products in the fluorite oxide phase, noble metal inclusions, secondary oxides including uranates, zirconates, molybdates and the gas phase. Thermochemical computations utilize the spatial and temporal evolution of the fission and activation product inventory in the pellet, which is typically neglected in nuclear fuel performance simulations. Isotopic computations encompass the depletion, decay and transmutation of more than 2000 isotopes that are calculated at every point in space and time. These computations take into consideration neutron flux depression and the increased production of fissile plutonium near the fuel pellet periphery (i.e., the so-called “rim effect”). Thermochemical and isotopic predictions are in very good agreement with reported experimental measurements of highly irradiated UO2 fuel with an average burnup of 102 GW d t(U)-1. Simulation results demonstrate that predictions are considerably enhanced when coupling thermochemical and isotopic computations in comparison to empirical correlations. Notice: This manuscript has been authored by UT-Battelle, LLC, under Contract No. DE-AC05-00OR22725 with the U.S. Department of Energy. The United States Government retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a non-exclusive, paid-up, irrevocable, world-wide license to publish or reproduce the published form of this manuscript, or allow others to do so, for United States Government purposes.

Detecting Isotopic Signatures and Measuring Isotopic Ratios on Solid Icy Surfaces:Implications for Origin and Evolution

NASA Astrophysics Data System (ADS)

Clark, R. N.; Brown, R. H.; Swayze, G. A.; Cruikshank, D. P.

2017-12-01

result in more fractionation, depending upona given isotope and the physical processes involved, potentially withimplications for origin and evolution.

Modeling aeolian dune and dune field evolution

NASA Astrophysics Data System (ADS)

Diniega, Serina

Aeolian sand dune morphologies and sizes are strongly connected to the environmental context and physical processes active since dune formation. As such, the patterns and measurable features found within dunes and dune fields can be interpreted as records of environmental conditions. Using mathematical models of dune and dune field evolution, it should be possible to quantitatively predict dune field dynamics from current conditions or to determine past field conditions based on present-day observations. In this dissertation, we focus on the construction and quantitative analysis of a continuum dune evolution model. We then apply this model towards interpretation of the formative history of terrestrial and martian dunes and dune fields. Our first aim is to identify the controls for the characteristic lengthscales seen in patterned dune fields. Variations in sand flux, binary dune interactions, and topography are evaluated with respect to evolution of individual dunes. Through the use of both quantitative and qualitative multiscale models, these results are then extended to determine the role such processes may play in (de)stabilization of the dune field. We find that sand flux variations and topography generally destabilize dune fields, while dune collisions can yield more similarly-sized dunes. We construct and apply a phenomenological macroscale dune evolution model to then quantitatively demonstrate how dune collisions cause a dune field to evolve into a set of uniformly-sized dunes. Our second goal is to investigate the influence of reversing winds and polar processes in relation to dune slope and morphology. Using numerical experiments, we investigate possible causes of distinctive morphologies seen in Antarctic and martian polar dunes. Finally, we discuss possible model extensions and needed observations that will enable the inclusion of more realistic physical environments in the dune and dune field evolution models. By elucidating the qualitative and

Mg Isotope Evolution During Water-Rock Interaction in a Carbonate Aquifer

NASA Astrophysics Data System (ADS)

Zhang, Z.; Jacobson, A. D.; Lundstrom, C. C.; Huang, F.

2008-12-01

To better understand how Mg isotopes behave during weathering and aqueous transport, we used a Nu Plasma MC-ICP-MS to measure δ26Mg values (relative to DSM-3) in water samples along a 236 km flow path in the Madison aquifer of South Dakota, a confined carbonate aquifer recharging in the igneous Black Hills. We also analyzed local granite and dolomite samples to characterize the Mg isotope composition of source rocks constituting the recharge zone and aquifer, respectively. Repeated analyses of Mg standard solutions yielded external precisions (2σ) better than 0.1 permil for δ26Mg(CAM-1, - 2.584±0.071, n=13; UIMg-1, -2.217±0.087, n=9.). The Madison aquifer provides a unique opportunity to quantify Mg isotope effects during water-rock interaction because (1) fluids and rock have chemically equilibrated over a much longer timescale (up to ~15 kyr) than can be simulated in laboratory experiments and (2) previous studies have determined the rates and mass-balances of de- dolomitization and other geochemical reactions controlling solute evolution along the flow path. Reactions important for changing the concentration and isotope composition of Mg include dolomite dissolution, Mg-for- Na ion exchange, calcite precipitation, and isotope exchange. δ26Mg values within the recharge region (0-17 km along flow path) vary between -1.08 and -1.63 permil, and then remain essentially constant at -1.408±0.010 permil(1σ, 5 samples) from 17 to 189 km. A final sample at 236 km shows an increase to -1.09 permil. Either mixing between different recharge waters or rapid isotope exchange between infiltrating waters and dolomite could control δ26Mg variability between 0 and 17 km. Likewise, reactive transport modeling suggests that preferential uptake of 24Mg during Mg-for-Na ion exchange might cause an increase in δ26Mg between 189 and 236 km. However, unchanging δ26Mg values observed throughout most of the aquifer clearly demonstrate that Mg isotopes are not fractionated during

Stable isotope evolution and paleolimnology of ancient Lake Creede

USGS Publications Warehouse

Rye, Robert O.; Bethke, Philip M.; Finkelstein, David B.

2000-01-01

The lacustrine carbonate and travertine (tufa) deposits of ancient Lake Creede preserve a remarkable record of the isotopic evolution of the lake. That record indicates that the δ18O of the lake water, and by analogy its salinity, evolved through evaporation. Limited and less reliable data on hydrous minerals and fluid inclusions in early diagenetic carbonates indicate that the δD of the lake waters also evolved through evaporation. The isotope data place restrictions on models of the physical limnology of the lake and its evolution.The closed-basin Lake Creede formed shortly after collapse of the 26.9 Ma Creede caldera. Throughout most of its history it occupied the northern three quarters of the moat between the resurgent dome and wall of the caldera. The Creede Formation was deposited in the basin, dominantly as lacustrine sediments. Travertine mounds interfinger with Creede Formation sediments along the inner and outer margins of the lake basin. An estimated one-half of the original thickness of the Creede Formation has been lost mainly to erosion although scattered remnants of the upper portion remain on the caldera walls. Two diamond core holes (CCM-1 and CCM-2) sampled the uneroded portion of the Creede Formation as part of the U.S. Continental Drilling Program. Volcaniclastic material, including tuff units deposited directly into the lake and ash washed in from the watershed, compose the main lithologies of the Creede Formation. These volcaniclastic strata were produced by episodic ring-fracture volcanism.Lacustrine carbonates make up about 15% of the section sampled by drill core. They occur as 1 mm to 2 cm low-Mg calcite laminae alternating with siliciclastic laminae in scattered intervals throughout the preserved section. The carbonate laminae are accumulations of 5–20 µm crystallites (microsparites) and brine shrimp fecal pellets (peloids) composed mainly of microsparite particles. Low-Mg calcite also occurs as an early diagenetic replacement of

Negative Oxygen Isotope Effect in Manganites with an Ordered Cation Arrangement in a High Magnetic Field

NASA Astrophysics Data System (ADS)

Taldenkov, A. N.; Snegirev, V. V.; Babushkina, N. A.; Kalitka, V. S.; Kaul', A. R.

2018-03-01

The oxygen isotope effect in PrBaMn2 16-18 O5.97 manganite with an ordered cation arrangement is studied. The field dependences of magnetic susceptibility and magnetization are measured in the temperature range 100-270 K and magnetic fields up to 32 T. A significant increase in the temperature of the spin-reorientation antiferromagnet-ferromagnet phase transition is detected in samples enriched in heavy oxygen 18O (negative isotope effect). The transition temperature and the isotope effect depend strongly on the magnetic field. An H-T phase diagram is plotted for samples with various isotope compositions. An analysis of the experimental results demonstrates that the detected negative isotope effect and the giant positive isotope effect revealed earlier in doped manganites have the same nature. The mechanisms of appearance of isotope effects are discussed in terms of the double exchange model under a polaron narrowing of the free carrier band.

Lead isotope evolution across the Neoproterozoic boundary between craton and juvenile crust, Bayuda Desert, Sudan

NASA Astrophysics Data System (ADS)

Evuk, David; Lucassen, Friedrich; Franz, Gerhard

2017-11-01

Metaigneous mafic and ultramafic rocks from the juvenile Neoproterozoic Arabian Nubian Shield (ANS) and the Proterozoic, reworked Saharan Metacraton (SMC) have been analysed for major- and trace elements and Sr, Nd, and Pb isotopes. Most of the rocks are amphibolites metamorphosed at amphibolite facies conditions, some with relicts of a granulite facies stage. The other rocks are metapyroxenites, metagabbros, and some ultramafic rocks. Trace element compositions of the metabasaltic (dominantly tholeiitic) rocks resemble the patterns of island arcs and primitive lavas from continental arcs. Variable Sr and Nd isotope ratios indicate depleted mantle dominance for most of the samples. 207Pb/204Pb signatures distinguish between the influence of high 207Pb/204Pb old SMC crust and depleted mantle signatures of the juvenile ANS crust. The Pb isotope signatures for most metabasaltic rocks, metapyroxenites and metagabbros from SMC indicate an autochthonous formation. The interpretation of the new data together with published evidence from mafic xenoliths on SMC and ophiolite from ANS allows an extrapolation of mantle evolution in time. There are two lines of evolution in the regional mantle, one, which incorporates potential upper crust material during Neoproterozoic, and a second one with a depleted mantle signature since pre-Neoproterozoic that still is present in the Red Sea and Gulf of Aden spreading centres.

MAGNETAR FIELD EVOLUTION AND CRUSTAL PLASTICITY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lander, S. K., E-mail: skl@soton.ac.uk

2016-06-20

The activity of magnetars is believed to be powered by colossal magnetic energy reservoirs. We sketch an evolutionary picture in which internal field evolution in magnetars generates a twisted corona, from which energy may be released suddenly in a single giant flare, or more gradually through smaller outbursts and persistent emission. Given the ages of magnetars and the energy of their giant flares, we suggest that their evolution is driven by a novel mechanism: magnetic flux transport/decay due to persistent plastic flow in the crust, which would invalidate the common assumption that the crustal lattice is static and evolves onlymore » under Hall drift and Ohmic decay. We estimate the field strength required to induce plastic flow as a function of crustal depth, and the viscosity of the plastic phase. The star’s superconducting core may also play a role in magnetar field evolution, depending on the star’s spindown history and how rotational vortices and magnetic fluxtubes interact.« less

A preliminary study on isotopic evolution of ice by a melting experiment

NASA Astrophysics Data System (ADS)

Ham, J. Y.; Lee, J.; Lee, W. S.; Han, Y.; Hur, S. D.

2016-12-01

Evidences of melted snow at surface were found on some ice cores. Melted layers may generate a significant error when paleo-temperature was retrieved from ice cores using stable water isotopes. To resolve this problem, it is necessary to understand the isotopic changes of ice and its meltwater that is made during the ice and snow melting. Isotopic fractionations between liquid water and snow have been discussed by Taylor et al. (2002) and Lee et al. (2009). The goal of this work is to understand isotopic evolution of ice and its meltwater. Melting experiments in a cold room were designed and conducted with heat source (infrared lamp) to mimic solar radiation. Melting rates were calculated in terms of specific discharge (g/min). To control melting rates, distances between ice surface and heat source were adjusted in various conditions (1 cm, 10 cm and 20 cm). The experiments were conducted by three different melting rates, 1.6 g/min, 3.5 g/min and 5.8 g/min. We used cubic ice that has 3 cm in width, length and height in dimension with 1.5 kg or 2 kg of ice used totally. The total time spent melting the whole ice was 592, 783, and 1180 minutes, respectively. Cold room temperature was range of -1 to 1°C, which removes an effect of air temperature. Meltwater samples were collected and isotopic compositions of oxygen and hydrogen were determined by a cavity ring down spectrometer (Picarro L-1120) installed at the Korea Polar Research Institute. We also analyzed bulk water and bulk ice to make the ice used in the experiments (-8.20 ‰ and -58.73 ‰ for oxygen and hydrogen isotopes, respectively). The isotopic compositions of meltwater increased linearly or to a second degree polynomial. The isotopic variations were larger in the lower melting rates, compared to the higher melting rates (0.65 of lower melting rates vs. 0.35 higher melting rates for oxygen isotope). The slope of linear regression between oxygen and hydrogen ranged 6.2, 7.3 and 6.2, which is less than

Partitioning evapotranspiration fluxes with water stable isotopic measurements: from the lab to the field

NASA Astrophysics Data System (ADS)

Quade, M. E.; Brueggemann, N.; Graf, A.; Rothfuss, Y.

2017-12-01

Water stable isotopes are powerful tools for partitioning net into raw water fluxes such as evapotranspiration (ET) into soil evaporation (E) and plant transpiration (T). The isotopic methodology for ET partitioning is based on the fact that E and T have distinct water stable isotopic compositions, which in turn relies on the fact that each flux is differently affected by isotopic kinetic effects. An important work to be performed in parallel to field measurements is to better characterize these kinetic effects in the laboratory under controlled conditions. A soil evaporation laboratory experiment was conducted to retrieve characteristic values of the kinetic fractionation factor (αK) under varying soil and atmospheric water conditions. For this we used a combined soil and atmosphere column to monitor the soil and atmospheric water isotopic composition profiles at a high temporal and vertical resolution in a nondestructive manner by combining micro-porous membranes and laser spectroscopy. αK was calculated by using a well-known isotopic evaporation model in an inverse mode with the isotopic composition of E as one input variable, which was determined using a micro-Keeling regression plot. Knowledge on αK was further used in the field (Selhausen, North Rhine-Westphalia, Germany) to partition ET of catch crops and sugar beet (Beta vulgaris) during one growing season. Soil and atmospheric water isotopic profiles were measured automatically across depths and heights following a similar modus operandi as in the laboratory experiment. Additionally, a newly developed continuously moving elevator was used to obtain water vapor isotopic composition profiles with a high vertical resolution between soil surface, plant canopy and atmosphere. Finally, soil and plant samples were collected destructively to provide a comparison with the traditional isotopic methods. Our results illustrate the changing proportions of T and E along the growing season and demonstrate the

Temperature evolution and the oxygen isotope composition of Phanerozoic oceans from carbonate clumped isotope thermometry

NASA Astrophysics Data System (ADS)

Henkes, Gregory A.; Passey, Benjamin H.; Grossman, Ethan L.; Shenton, Brock J.; Yancey, Thomas E.; Pérez-Huerta, Alberto

2018-05-01

Surface temperature is among the most important parameters describing planetary climate and habitability, and yet there remains considerable debate about the temperature evolution of the Earth's oceans during the Phanerozoic Eon (541 million years ago to present), the time during which complex metazoan life radiated on Earth. Here we critically assess the emerging record of Phanerozoic ocean temperatures based on carbonate clumped isotope thermometry of fossil brachiopod and mollusk shells, and we present new data that fill important gaps in the Late Paleozoic record. We evaluate and reject the hypothesis that solid-state reordering of 13C-18O bonds has destroyed the primary clumped isotope temperature signal of most fossils during sedimentary burial at elevated temperatures. The resulting Phanerozoic record, which shows a general coupling between tropical seawater temperatures and atmospheric carbon dioxide (CO2) levels since the Paleozoic, indicates that tropical temperatures during the icehouse climate of the Carboniferous period were broadly similar to present (∼25-30 °C), and suggests that benthic metazoans were able to thrive at temperatures of 35-40 °C during intervals of the early and possibly the latest Paleozoic when CO2 levels were likely 5-10× higher than present-day values. Equally important, there is no resolvable trend in seawater oxygen isotope ratios (δ18 O) over the past ∼500 million years, indicating that the average temperature of oxygen exchange between seawater and the oceanic crust has been high (∼270 °C) since at least the early Paleozoic, which points to mid-ocean ridges as the dominant locus of water-rock interaction over the past half-billion years.

Magnetic field evolution in white dwarfs: The hall effect and complexity of the field

NASA Technical Reports Server (NTRS)

Muslimov, A. G.; Van Horn, H. M.; Wood, M. A.

1995-01-01

We calculate the evolution of the magnetic fields in white dwarfs, taking into account the Hall effect. Because this effect depends nonlinearly upon the magnetic field strength B, the time dependences of the various multipole field components are coupled. The evolution of the field is thus significantly more complicated than has been indicated by previous investigations. Our calculations employ recent white dwarf evolutionary sequences computed for stars with masses 0.4, 0.6, 0.8, and 1.0 solar mass. We show that in the presence of a strong (up to approximately 10(exp 9) G) internal toroidal magnetic field; the evolution of even the lowest order poloidal modes can be substantially changed by the Hall effect. As an example, we compute the evolution of an initially weak quadrupole component, which we take arbitrarily to be approximately 0.1%-1% of the strength of a dominant dipole field. We find that coupling provided by the Hall effect can produce growth of the ratio of the quadrupole to the dipole component of the surface value of the magnetic field strength by more than a factor of 10 over the 10(exp 9) to 10(exp 10) year cooling lifetime of the white dwarf. Some consequences of these results for the process of magnetic-field evolution in white dwarfs are briefly discussed.

Application of stable isotope tools for evaluating natural and stimulated biodegradation of organic pollutants in field studies.

PubMed

Fischer, Anko; Manefield, Mike; Bombach, Petra

2016-10-01

Stable isotope tools are increasingly applied for in-depth evaluation of biodegradation of organic pollutants at contaminated field sites. They can be divided into three methods i) determination of changes in natural abundance of stable isotopes using compound-specific stable isotope analysis (CSIA), ii) detection of incorporation of stable-isotope label from a stable-isotope labelled target compound into degradation and/or mineralisation products and iii) determination of stable-isotope label incorporation into biomarkers using stable isotope probing (SIP). Stable isotope tools have been applied as key monitoring tools for multiple-line-of-evidence-approaches (MLEA) for sensitive evaluation of pollutant biodegradation. This review highlights the application of CSIA, SIP and MLEA including stable isotope tools for assessing natural and stimulated biodegradation of organic pollutants in field studies dealing with soil and groundwater contaminations. Copyright © 2016 Elsevier Ltd. All rights reserved.

Neodymium isotope evolution of NW Tethyan upper ocean waters throughout the Cretaceous

NASA Astrophysics Data System (ADS)

Pucéat, Emmanuelle; Lécuyer, Christophe; Reisberg, Laurie

2005-08-01

Neodymium isotope compositions of twenty-four fish teeth, nineteen from the NW Tethys and five from different locations within the Tethys, are interpreted to reflect the evolution of Tethyan upper ocean water composition during the Cretaceous and used to track changes in erosional inputs to the NW Tethys and in oceanic circulation throughout the Cretaceous. The rather high ɛNd (up to - 7.6) of the NW Tethyan upper ocean waters recorded from the Late Berriasian to the Early Aptian and the absence of negative excursions during this interval support the presence of a permanent westward flowing Tethys Circumglobal Current (TCC). This implies that temperature variations during this time period, inferred from the oxygen isotope analysis of fish tooth enamel, were not driven by changes in surface oceanic currents, but rather by global climatic changes. The results presented here represent a significant advance over previously published Cretaceous seawater Nd isotope records. Our newly acquired data now allow the identification of two stages of low ɛNd values in the NW Tethys, during the Early Albian-Middle Albian interval (down to - 10) and the Santonian-Early Campanian (down to - 11.4), which alternate with two stages of higher ɛNd values (up to - 9) during the Late Albian-Turonian interval and the Maastrichtian. Used in conjunction with the oxygen isotope record, the fluctuations of ɛNd values can be related to major climatic, oceanographic, and tectonic events that appeared in the western Tethyan domain.

Processes and time scales of magmatic evolution as revealed by Fe-Mg chemical and isotopic zoning in natural olivines

NASA Astrophysics Data System (ADS)

Oeser, Martin; Dohmen, Ralf; Horn, Ingo; Schuth, Stephan; Weyer, Stefan

2015-04-01

In this study, we applied high-precision in situ Fe and Mg isotope analyses by femtosecond laser ablation (fs-LA) MC-ICP-MS on chemically zoned olivine xeno- and phenocrysts from intra-plate volcanic regions in order to investigate the magnitude of Fe and Mg isotope fractionation and its suitability to gain information on magma evolution. Our results show that chemical zoning (i.e., Mg#) in magmatic olivines is commonly associated with significant zoning in δ56Fe and δ26Mg (up to 1.7‰ and 0.7‰, respectively). We explored different cases of kinetic fractionation of Fe and Mg isotopes by modeling diffusion in the melt or olivine and simultaneous growth or dissolution. Combining the information of chemical and isotopic zoning in olivine allows to distinguish between various processes that may occur during magma evolution, namely diffusive Fe-Mg exchange between olivine and melt, rapid crystal growth, and Fe-Mg inter-diffusion simultaneous to crystal dissolution or growth. Chemical diffusion in olivine appears to be the dominant process that drives isotope fractionation in magmatic olivine. Simplified modeling of Fe and Mg diffusion is suitable to reproduce both the chemical and the isotopic zoning in most of the investigated olivines and, additionally, provides time information about magmatic processes. For the Massif Central (France), modeling of diffusive re-equilibration of mantle olivines in basanites revealed a short time span (<2 years) between the entrainment of a mantle xenolith in an intra-plate basaltic magma and the eruption of the magma. Furthermore, we determined high cooling rates (on the order of a few tens to hundreds of °C per year) for basanite samples from a single large outcrop in the Massif Central, which probably reflects the cooling of a massive lava flow after eruption. Results from the modeling of Fe and Mg isotope fractionation in olivine point to a systematic difference between βFe and βMg (i.e., βFe/βMg ≈ 2), implying that the

Isotopic evolution of the protoplanetary disk and the building blocks of Earth and the Moon.

PubMed

Schiller, Martin; Bizzarro, Martin; Fernandes, Vera Assis

2018-03-21

Nucleosynthetic isotope variability among Solar System objects is often used to probe the genetic relationship between meteorite groups and the rocky planets (Mercury, Venus, Earth and Mars), which, in turn, may provide insights into the building blocks of the Earth-Moon system. Using this approach, it has been inferred that no primitive meteorite matches the terrestrial composition and the protoplanetary disk material from which Earth and the Moon accreted is therefore largely unconstrained. This conclusion, however, is based on the assumption that the observed nucleosynthetic variability of inner-Solar-System objects predominantly reflects spatial heterogeneity. Here we use the isotopic composition of the refractory element calcium to show that the nucleosynthetic variability in the inner Solar System primarily reflects a rapid change in the mass-independent calcium isotope composition of protoplanetary disk solids associated with early mass accretion to the proto-Sun. We measure the mass-independent 48 Ca/ 44 Ca ratios of samples originating from the parent bodies of ureilite and angrite meteorites, as well as from Vesta, Mars and Earth, and find that they are positively correlated with the masses of their parent asteroids and planets, which are a proxy of their accretion timescales. This correlation implies a secular evolution of the bulk calcium isotope composition of the protoplanetary disk in the terrestrial planet-forming region. Individual chondrules from ordinary chondrites formed within one million years of the collapse of the proto-Sun reveal the full range of inner-Solar-System mass-independent 48 Ca/ 44 Ca ratios, indicating a rapid change in the composition of the material of the protoplanetary disk. We infer that this secular evolution reflects admixing of pristine outer-Solar-System material into the thermally processed inner protoplanetary disk associated with the accretion of mass to the proto-Sun. The identical calcium isotope composition of

Isotopic evolution of the protoplanetary disk and the building blocks of Earth and the Moon

NASA Astrophysics Data System (ADS)

Schiller, Martin; Bizzarro, Martin; Fernandes, Vera Assis

2018-03-01

Nucleosynthetic isotope variability among Solar System objects is often used to probe the genetic relationship between meteorite groups and the rocky planets (Mercury, Venus, Earth and Mars), which, in turn, may provide insights into the building blocks of the Earth–Moon system. Using this approach, it has been inferred that no primitive meteorite matches the terrestrial composition and the protoplanetary disk material from which Earth and the Moon accreted is therefore largely unconstrained. This conclusion, however, is based on the assumption that the observed nucleosynthetic variability of inner-Solar-System objects predominantly reflects spatial heterogeneity. Here we use the isotopic composition of the refractory element calcium to show that the nucleosynthetic variability in the inner Solar System primarily reflects a rapid change in the mass-independent calcium isotope composition of protoplanetary disk solids associated with early mass accretion to the proto-Sun. We measure the mass-independent 48Ca/44Ca ratios of samples originating from the parent bodies of ureilite and angrite meteorites, as well as from Vesta, Mars and Earth, and find that they are positively correlated with the masses of their parent asteroids and planets, which are a proxy of their accretion timescales. This correlation implies a secular evolution of the bulk calcium isotope composition of the protoplanetary disk in the terrestrial planet-forming region. Individual chondrules from ordinary chondrites formed within one million years of the collapse of the proto-Sun reveal the full range of inner-Solar-System mass-independent 48Ca/44Ca ratios, indicating a rapid change in the composition of the material of the protoplanetary disk. We infer that this secular evolution reflects admixing of pristine outer-Solar-System material into the thermally processed inner protoplanetary disk associated with the accretion of mass to the proto-Sun. The identical calcium isotope composition of Earth

Lead Isotopes in Olivine-Phyric Shergottite Tissint: Implications for the Geochemical Evolution of the Shergottite Source Mantle

NASA Technical Reports Server (NTRS)

Moriwaki, R.; Usui, T.; Simon, J. I.; Jones, J. H.; Yokoyama, T.

2015-01-01

Geochemically-depleted shergottites are basaltic rocks derived from a martian mantle source reservoir. Geochemical evolution of the martian mantle has been investigated mainly based on the Rb-Sr, Sm-Nd, and Lu-Hf isotope systematics of the shergottites [1]. Although potentially informative, U-Th- Pb isotope systematics have been limited because of difficulties in interpreting the analyses of depleted meteorite samples that are more susceptible to the effects of near-surface processes and terrestrial contamination. This study conducts a 5-step sequential acid leaching experiment of the first witnessed fall of the geochemically-depleted olivinephyric shergottite Tissint to minimize the effect of low temperature distrubence. Trace element analyses of the Tissint acid residue (mostly pyroxene) indicate that Pb isotope compositions of the residue do not contain either a martian surface or terrestrial component, but represent the Tissint magma source [2]. The residue has relatively unradiogenic initial Pb isotopic compositions (e.g., 206Pb/204Pb = 10.8136) that fall within the Pb isotope space of other geochemically-depleted shergottites. An initial µ-value (238U/204Pb = 1.5) of Tissint at the time of crystallization (472 Ma [3]) is similar to a time-integrated mu- value (1.72 at 472 Ma) of the Tissint source mantle calculated based on the two-stage mantle evolution model [1]. On the other hand, the other geochemically-depleted shergottites (e.g., QUE 94201 [4]) have initial µ-values of their parental magmas distinctly lower than those of their modeled source mantle. These results suggest that only Tissint potentially reflects the geochemical signature of the shergottite mantle source that originated from cumulates of the martian magma ocean

The evolution of Phanerozoic seawater - Isotope paleothermometry finds consensus on Early Paleozoic warmth and constant seawater δ18O

NASA Astrophysics Data System (ADS)

Grossman, E. L.; Henkes, G. A.; Passey, B. H.; Shenton, B.; Yancey, T. E.; Perez-Huerta, A.

2015-12-01

Evolution of metazoan life is closely linked to the Phanerozoic evolution of ocean temperatures and chemistry. Oxygen isotopic evidence for early Phanerozoic paleotemperatures has been equivocal, with decreasing δ18O values with age being interpreted as warmer early oceans, decreasing seawater δ18O with age, or increasing diagenetic alteration in older samples. Here we compare an updated compilation of oxygen isotope data for carbonate and phosphate fossils and microfossils (Grossman, 2012, Geol. Time Scale, Elsevier, 195-220) with a compilation of new and existing clumped isotope data. Importantly, these data are curated based on sample preservation with special consideration given to screening techniques, and tectonic and burial history. Burial history is critical in the preservation of carbonate clumped isotope temperatures in particular, which can undergo reordering in the solid state. We use a model derived for reordering kinetics (Henkes et al., 2014, Geochim. Cosmochim. Acta 139:362-382) to screen clumped isotope data for the effects of solid-state burial alteration. With minor but significant exceptions (Late Cretaceous, Early Triassic), average δ18O values (4 m.y. window, 2 m.y. steps) for post-Devonian brachiopods, belemnites, and foraminifera, representing tropical-subtropical surface ocean conditions, yield average isotopic temperatures below 30°C (assuming a seawater δ18O value [ -1‰ VSMOW] of an "ice-free" world). In contrast, Ordovician to Devonian data show sustained temperatures of 35-40°C. Likewise, isotopic paleotemperatures from conodont apatite, known to be resistant to isotopic exchange, follow the same pattern. Clumped isotope data derived from Paleozoic brachiopod shells that experienced minimal burial (< 100 °C) and <1% reordering according to the taxon-specific clumped isotope reordering model yield typical temperatures of 25-30°C for the Carboniferous, and 35-40°C for the Ordovician-Silurian. Inserting clumped temperatures and

Distinctive aspects of the evolution of galactic magnetic fields

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yar-Mukhamedov, D., E-mail: danial.su@gmail.com

2016-11-15

We perform an in-depth analysis of the evolution of galactic magnetic fields within a semi-analytic galaxy formation and evolution framework, determine various distinctive aspects of the evolution process, and obtain analytic solutions for a wide range of possible evolution scenarios.

Stable isotope measurements of evapotranspiration partitioning in a maize field

NASA Astrophysics Data System (ADS)

Hogan, Patrick; Parajka, Juraj; Oismüller, Markus; Strauss, Peter; Heng, Lee; Blöschl, Günter

2017-04-01

Evapotranspiration (ET) is one of the most important processes in describing land surface - atmosphere interactions as it connects the energy and water balances. Furthermore knowledge of the individual components of evapotranspiration is important for ecohydrological modelling and agriculture, particularly for irrigation efficiency and crop productivity. In this study, we tested the application of the stable isotope method for evapotranspiration partitioning to a maize crop during the vegetative stage, using sap flow sensors as a comparison technique. Field scale ET was measured using an eddy covariance device and then partitioned using high frequency in-situ measurements of the isotopic signal of the canopy water vapor. The fraction of transpiration (Ft) calculated with the stable isotope method showed good agreement with the sap flow method. High correlation coefficient values were found between the two techniques, indicating the stable isotope method can successfully be applied in maize. The results show the changes in transpiration as a fraction of evapotranspiration after rain events and during the subsequent drying conditions as well as the relationship between transpiration and solar radiation and vapor pressure deficit.

Collectivity of light Ge and As isotopes

NASA Astrophysics Data System (ADS)

Corsi, A.; Delaroche, J.-P.; Obertelli, A.; Baugher, T.; Bazin, D.; Boissinot, S.; Flavigny, F.; Gade, A.; Girod, M.; Glasmacher, T.; Grinyer, G. F.; Korten, W.; Libert, J.; Ljungvall, J.; McDaniel, S.; Ratkiewicz, A.; Signoracci, A.; Stroberg, R.; Sulignano, B.; Weisshaar, D.

2013-10-01

Background: The self-conjugate nuclei of the A˜70 mass region display rapid shape evolution over isotopic or isotonic chains. Shape coexistence has been observed in Se and Kr isotopes reflecting the existence of deformed subshell gaps corresponding to different shell configurations. As and Ge isotopes are located halfway between such deformed nuclei and the Z=28 shell closure.Purpose: The present work aims at clarifying the low-lying spectroscopy of 66Ge and 67As, and providing a better insight into the evolution of collectivity in light even-even Ge and even-odd As isotopes.Methods: We investigate the low-lying levels and collectivity of the neutron deficient 67As and 66Ge through intermediate-energy Coulomb excitation, inelastic scattering, and proton knockout measurements. The experiment was performed using a cocktail beam of 68Se, 67As, and 66Ge nuclei at an energy of 70-80 MeV/nucleon. Spectroscopic properties of the low-lying states are compared to those calculated via shell model with the JUN45 interaction and beyond-mean-field calculations with the five-dimensional collective Hamiltonian method implemented using the Gogny D1S interaction. The structure evolution of the lower-mass Ge and As isotopes is discussed.Results: Reduced electric quadrupole transition probabilities B(E2) have been extracted from the Coulomb-excitation cross sections measured in 66Ge and 67As. The value obtained for the B(E2;01+→21+) in 66Ge is in agreement with a recent measurement, ruling out the existence of a minimum at N=34 in the B(E2) systematics as previously observed. New transitions have been found in 67As and were assigned to the decay of low-lying negative-parity states.

The size-isotopic evolution connection among layered mafic instrusions: Clues from a Sr-Nd isotopic study of a small complex

NASA Astrophysics Data System (ADS)

Poitrasson, Franck; Pin, Christian; Duthou, Jean-Louis; Platevoet, Bernard

1994-05-01

Several theoretical and experimental works have focused on the processes occuring in continental mafic magma chambers. In contrast, systematic isotopic studies of natural remnants of these latter remain scarce, although they can give fundamental constraints for theoretical studies. This is especially true if different layered complex with contrasting characteristics (e.g., different size) are compared. For this reason, we present the results of a Sr-Nd isotopic profile across a small layered mafic intrusion of Permian age exposed near Fozzano (SW Corsica). In the main zone of the layered section, decreasing Sr-87/Sr(sub i)-86 and increasing Nd-143/Nd(sub i)-144 are observed from less evolved (bottom) to more evolved (top) rocks. This peculiar pattern precludes assimilation and fractional crystallization (AFC) as a dominant mechanism in the petrogenesis of this body. Instead, we interpret this trend as reflecting the dilution of an early stage contaminated magma by several reinjections of fresh basalt in the chamber. In agreement with mineralogical and structural data, every cyclic unit is interpreted as a new magmatic input. On the basis of rough refill and fractional crystallization (RFC) calculations, the average volume for each reinjection is estimated to have been about 0.04 cu km. The cumulative volume of these injections would amount to about 75% of the total volume of the layered complex. This implies that reinjections were accompanied by an important increase of the volume of the chamber or by magma withdrawal by surface eruptions. The RFC mechanism documented within this small layered body constrasts with the isotopic pattern observed between several intrusions at the regional scale in SW Corsica, and within large continental mafic magma chambers elsewhere. In these cases the isotopic evolution is dominated by AFC processes, and there is no clear isotopic evidence for reinjections, unless major influx of fresh magma occurred. It is suggested that there is

Evolution of the Campanian Ignimbrite Magmatic System II: Trace Element and Th Isotopic Evidence for Open-System Processes

NASA Astrophysics Data System (ADS)

Bohrson, W. A.; Spera, F. J.; Fowler, S.; Belkin, H.; de Vivo, B.

2005-12-01

The Campanian Ignimbrite, a large volume (~200 km3 DRE) trachytic to phonolitic ignimbrite was deposited at ~39.3 ka and represents the largest of a number of highly explosive volcanic events in the region near Naples, Italy. Thermodynamic modeling of the major element evolution using the MELTS algorithm (see companion contribution by Fowler et al.) provides detailed information about the identity of and changes in proportions of solids along the liquid line of descent during isobaric fractional crystallization. We have derived trace element mass balance equations that explicitly accommodate changing mineral-melt bulk distribution coefficients during crystallization and also simultaneously satisfy energy and major element mass conservation. Although major element patterns are reasonably modeled assuming closed system fractional crystallization, modeling of trace elements that represent a range of behaviors (e.g. Zr, Nb, Th, U, Rb, Sm, Sr) yields trends for closed system fractionation that are distinct from those observed. These results suggest open-system processes were also important in the evolution of the Campanian magmatic system. Th isotope data yield an apparent isochron that is ~20 kyr younger than the age of the deposit, and age-corrected Th isotope data indicate that the magma body was an open-system at the time of eruption. Because open-system processes can profoundly change isotopic characteristics of a magma body, these results illustrate that it is critical to understand the contribution that open-system processes make to silicic magma bodies prior to assigning relevance to age or timescale information derived from isotope systematics. Fluid-magma interaction has been proposed as a mechanism to change isotopic and elemental characteristics of magma bodies, but an evaluation of the mass and thermal constraints on such a process suggest large-scale fluid-melt interaction at liquidus temperatures is unlikely. In the case of the magma body associated with

Hydrogen Isotopic Constraints on the Evolution of Surface and Subsurface Water on Mars

NASA Technical Reports Server (NTRS)

Usui, T.; Kurokawa, H.; Wang, J.; Alexander, C. M. O’D.; Simon, J. I.; Jones, J. H.

2017-01-01

The geology and geomorphology of Mars provide clear evidence for the presence of liquid water on its surface during the Noachian and Hesperien eras (i.e., >3 Ga). In contrast to the ancient watery environment, today the surface of Mars is relatively dry. The current desert-like surface conditions, however, do not necessarily indicate a lack of surface or near-surface water/ice. In fact, massive deposits of ground ice and/or icy sediments have been proposed based on subsurface radar sounder observations. Hence, accurate knowledge of both the evolution of the distribution of water and of the global water inventory is crucial to our understanding of the evolution of the climate and near-surface environments and the potential habitability of Mars. This study presents insights from hydrogen isotopes for the interactive evolution of Martian water reservoirs. In particular, based on our new measurement of the D/H ratio of 4 Ga-old Noachian water, we constrain the atmospheric loss and possible exchange of surface and subsurface water through time.

The Upper Mantle Flow Field around South-Africa as Reflected by Isotopic Provinciality

NASA Astrophysics Data System (ADS)

Meyzen, C.; Blichert-Toft, J.; Ludden, J.; Humler, E.; Mevel, C.; Albarede, F.

2006-12-01

Isotopic studies of MORB have established the existence of broad isotopic provinces within the underlying asthenosphere, such as in the Indian Ocean (DUPAL). How these features relate to mantle circulation is, however, still unknown. The steepness of the transition between such isotopic provinces will define the geometry of the velocity field in the upper mantle. In this respect, the transition between the Indian and South Atlantic provinces, two domains that are isotopically contrasted, should be readily identifiable over this long ridge segment. Here, we present Hf isotope data for 60 samples dredged along the SWIR between 35° and 69°E. The new Hf isotope data show that the Indian asthenosphere does not spill directly into the South Atlantic upper mantle: the general decreasing southward gradient observed for ^{176}Hf/^{177}Hf down the mid- Atlantic Ridge, and also for Sr isotopes and model Th/U ratios (derived from Pb isotopes), is overprinted by material with radiogenic Sr, unradiogenic Hf and high Th/U. The Indian domain grades into the South Atlantic around Bouvet, while the South Atlantic collides with the Atlantic province around Tristan. We interpret these features to represent fronts between three adjacent isotopic provinces similar to what has been suggested for the Australian-Antarctic Discordance. The common DUPAL signature of MORB and OIB from the Indian province and the geochemistry of Gulf of Aden MORB and the Afar plume suggest that the source of this distinctive mantle component is deep and lies to the north of the province. This is also what the three-dimensional flow field computed by Behn et al. (2004) from shear-wave splitting shows with a major lower mantle upwelling radiating at the base of the asthenosphere under the Afar plume. Lower mantle gushing out from this source flows southward unimpeded along the Indian ridges, whereas it only reaches the South Atlantic ridge after first having been deflected under the deep roots of the South

Magmatic Fluid Source of the Chingshui Geothermal Field: Evidence of Carbonate Isotope data

NASA Astrophysics Data System (ADS)

Song, S. R.; Lu, Y. C.; Wang, P. L.; John, C. M.; MacDonald, J.

2015-12-01

The Chingshui geothermal field is located at the northern tip of the Miocene Lushan Slate Formation, which was part of the Eurasian continental margin subject to the Plio-Pleistocene collision associated with the Luzon Arc. The remnant heat of the Taiwan orogeny has long been considered to drive the circulation of hydrothermal fluids in the Chingshui geothermal field. However, recent studies based on magnetic anomalies and helium isotopic ratios suggest that the heat might instead be derived from igneous bodies. By examining isotope data of calcite veins and scaling in geothermal wells, this study aimed to clarify the fluid origin and possible heat source accounting for the geothermal fluids in the Chingshui geothermal field. Carbon and oxygen isotope analyses indicate that veins from outcrops and scalings in geothermal wells have high and low d values, respectively. Data for veins in drilled cores fall in between outcrop veins and scalings values. Such an isotopic pattern could be interpreted as the mixing of two end member fluids. The clumped isotope analysis of calcite veins from the outcrops yielded precipitation temperatures of up to 232 ± 16 ℃ and a reconstructed d18O fluid value of 9.5 ‰(magmatic fluid: 6-11 ‰; metamorphic fluid: 5-28 ‰ by Taylor, 1974). The inferred d18O values of hot fluids for the vein formation are significantly different from that of meteoric water in Chingshui area (around -5.4 ‰) as well as the scaling in geothermal wells (around -7.6 ‰). Previous study of magnetotelluric image demonstrated two possible fluid reservoirs at different depths (Chen et al. 2012). Our isotope data combined with these lines of evidence suggest that the scaling in geothermal wells could be derived from fluids originating from the shallower reservoir. In contrast, the veins present at outcrops could have been formed from 18O-enriched, deeply-sourced fluids related to either metamorphic dehydration or magmatic processes.

Isotope Geochemistry for Comparative Planetology of Exoplanets

NASA Technical Reports Server (NTRS)

Mandt, K. E.; Atreya, S.; Luspay-Kuti, A.; Mousis, O.; Simon, A.; Hofstadter, M. D.

2017-01-01

Isotope geochemistry has played a critical role in understanding processes at work in and the history of solar system bodies. Application of these techniques to exoplanets would be revolutionary and would allow comparative planetology with the formation and evolution of exoplanet systems. The roadmap for comparative planetology of the origins and workings of exoplanets involves isotopic geochemistry efforts in three areas: (1) technology development to expand observations of the isotopic composition of solar system bodies and expand observations to isotopic composition of exoplanet atmospheres; (2) theoretical modeling of how isotopes fractionate and the role they play in evolution of exoplanetary systems, atmospheres, surfaces and interiors; and (3) laboratory studies to constrain isotopic fractionation due to processes at work throughout the solar system.

Compound specific isotope analysis to investigate pesticide degradation in lysimeter experiments at field conditions

NASA Astrophysics Data System (ADS)

Ryabenko, Evgenia; Elsner, Martin; Bakkour, Rani; Hofstetter, Thomas; Torrento, Clara; Hunkeler, Daniel

2015-04-01

The frequent detection of organic micropollutants such as pesticides, consumer care products or pharmaceuticals in water is an increasing concern for human and ecosystem health. Degradation analysis of these compounds can be challenging in complex systems due to the fact that metabolites are not always found and mass balances frequently cannot be closed. Many abiotic and biotic degradation pathways cause, however, distinct isotope fractionation, where light isotopes are transferred preferentially from the reactant to the product pool (normal isotope fractionation). Compound-specific isotope analysis (CSIA) of multiple elements is a particularly powerful method to evaluate organic micropollutant transformation, because it can even give pathway-specific isotope fractionation (1,2). Available CSIA field studies, however, have focused almost exclusively on volatile petroleum and chlorinated hydrocarbons, which are present in high concentrations in the environment and can be extracted easily from water for GC-IRMS analysis. In the case of micropollutants, such as pesticides, CSIA in more challenging since it needs to be conducted at lower concentrations and requires pre-concentration, purification and high chromatographic performance (3). In this study we used lysimeters experiments to analyze transformation of atrazine, acetochlor, metolachlor and chloridazone by studying associated isotope fractionation. The project combines a) analytical method development for CSIA, b) identification of pathways of micropollutant degradation and c) quantification of transformation processes under field condition. The pesticides were applied both, at the soil surface and below the top soil under field-relevant concentrations in May 2014. After typical irrigation of the lysimeters, seepage water was collected in 50L bottles and stored for further SPE and CSIA. Here we present the very first result of a) analytical method development, b) improvement of SPE methods for complex pesticide

Chemical and isotopic evolution of a layered eastern U.S. snowpack and its relation to stream-water composition

USGS Publications Warehouse

Shanley, J.B.; Kendall, C.; Albert, M.R.; Hardy, J.P.

1995-01-01

The chemical, isotopic, and morphologic evolution of a layered snowpack was investigated during the winter of 1993-94 at Sleepers River Research Watershed in Danville, Vermont. The snowpack was monitored at two small basins: a forested basin at 525 m elevation, and an agricultural basin at 292 m elevation. At each site, the snowpack morphology was characterized and individual layers were sampled seven times during the season. Nitrate and 8d18O profiles in the snowpack remained relatively stable until peak accumulation in mid-March, except near the snow surface, where rain-on-snow events caused water and nitrate movement down to impeding ice layers. Subsequently, water and nitrate moved more readily through the ripening snowpack. As the snowpack evolved, combined processes of preferential ion elution, isotopic fractionation, and infiltration of isotopically heavy rainfall caused the pack to become depleted in solutes and isotopically enriched. The release of nitrate and isotopically depleted water was reflected in patterns of nitrate concentrations and ??18O of meltwater and stream water. Results supported data from the previous year which suggested that streamflow in the forested basin during snowmelt was dominated by groundwater discharge.

Strontium isotopic signatures of oil-field waters: Applications for reservoir characterization

USGS Publications Warehouse

Barnaby, R.J.; Oetting, G.C.; Gao, G.

2004-01-01

The 87Sr/86Sr compositions of formation waters that were collected from 71 wells producing from a Pennsylvanian carbonate reservoir in New Mexico display a well-defined distribution, with radiogenic waters (up to 0.710129) at the updip western part of the reservoir, grading downdip to less radiogenic waters (as low as 0.708903 to the east. Salinity (2800-50,000 mg/L) displays a parallel trend; saline waters to the west pass downdip to brackish waters. Elemental and isotopic data indicate that the waters originated as meteoric precipitation and acquired their salinity and radiogenic 87Sr through dissolution of Upper Permian evaporites. These meteoric-derived waters descended, perhaps along deeply penetrating faults, driven by gravity and density, to depths of more than 7000 ft (2100 m). The 87 Sr/86Sr and salinity trends record influx of these waters along the western field margin and downdip flow across the field, consistent with the strong water drive, potentiometric gradient, and tilted gas-oil-water contacts. The formation water 87Sr/86Sr composition can be useful to evaluate subsurface flow and reservoir behavior, especially in immature fields with scarce pressure and production data. In mature reservoirs, Sr Sr isotopes can be used to differentiate original formation water from injected water for waterflood surveillance. Strontium isotopes thus provide a valuable tool for both static and dynamic reservoir characterization in conjunction with conventional studies using seismic, log, core, engineering, and production data. Copyright ??2004. The American Association of Petroleum Geologist. All rights reserved.

Tracing the secular evolution of the UCC using the iron isotope composition of ancient glacial diamictites

NASA Astrophysics Data System (ADS)

Liu, X. M.; Gaschnig, R. M.; Rudnick, R. L.; Hazen, R. M.; Shahar, A.

2014-12-01

Iron is the fourth most abundant element in the continental crust and influences global climate and biogeochemical cycles in the ocean1. Continental inputs, including river waters, sediments and atmospheric dust are dominant sources (>95%) of iron into the ocean2. Therefore, understanding how continental inputs may have changed through time is important in understanding the secular evolution of the marine Fe cycle. We analysed the Fe isotopic composition of twenty-four glacial diamictite composites, upper continental crust (UCC) proxies, with ages ranging from the Mesoarchean to the Paleozoic eras to characterize the secular evolution of the UCC. The diamictites all have elevated chemical index of alteration (CIA) and other characteristics of weathered regolith (e.g., strong depletion in soluble elements such as Sr), which they inherited from their upper crustal source region3. δ56Fe in the diamictite composites range from -0.59 to +0.23‰, however, most diamictites cluster with an average δ56Fe of 0.11± 0.20 (2s), overlapping juvenile continental material such as island arc basalts (IABs), which show a narrow range in δ56Fe from -0.04 to +0.14 ‰4. There is no obvious correlation between δ56Fe of the glacial diamictites and the CIA, except that the diamictite with the lowest δ56Fe at -0.59 ‰ also has the highest CIA = 89 (the Paleoproterozoic Makganyene Fm.). The data suggest that the Fe isotope compositions in the upper continental crust did not vary throughout Earth history. Interestingly, chemical weathering and sedimentary transport likely play only a minor role in producing Fe isotope variations in the upper continental crust. Anoxic weathering pre-GOE (Great Oxidation Event) does not seem to generate different Fe isotopic signatures from the post-GOE oxidative weathering environment in the upper continental crust. Therefore, large Fe isotopic fractionations observed in various marine sedimentary records are likely due to other processes occurring

Tracing the secular evolution of the UCC using the iron isotope composition of ancient glacial diamictites

NASA Astrophysics Data System (ADS)

Liu, X. M.; Gaschnig, R. M.; Rudnick, R. L.; Hazen, R. M.; Shahar, A.

2015-12-01

Iron is the fourth most abundant element in the continental crust and influences global climate and biogeochemical cycles in the ocean1. Continental inputs, including river waters, sediments and atmospheric dust are dominant sources (>95%) of iron into the ocean2. Therefore, understanding how continental inputs may have changed through time is important in understanding the secular evolution of the marine Fe cycle. We analysed the Fe isotopic composition of twenty-four glacial diamictite composites, upper continental crust (UCC) proxies, with ages ranging from the Mesoarchean to the Paleozoic eras to characterize the secular evolution of the UCC. The diamictites all have elevated chemical index of alteration (CIA) and other characteristics of weathered regolith (e.g., strong depletion in soluble elements such as Sr), which they inherited from their upper crustal source region3. δ56Fe in the diamictite composites range from -0.59 to +0.23‰, however, most diamictites cluster with an average δ56Fe of 0.11± 0.20 (2s), overlapping juvenile continental material such as island arc basalts (IABs), which show a narrow range in δ56Fe from -0.04 to +0.14 ‰4. There is no obvious correlation between δ56Fe of the glacial diamictites and the CIA, except that the diamictite with the lowest δ56Fe at -0.59 ‰ also has the highest CIA = 89 (the Paleoproterozoic Makganyene Fm.). The data suggest that the Fe isotope compositions in the upper continental crust did not vary throughout Earth history. Interestingly, chemical weathering and sedimentary transport likely play only a minor role in producing Fe isotope variations in the upper continental crust. Anoxic weathering pre-GOE (Great Oxidation Event) does not seem to generate different Fe isotopic signatures from the post-GOE oxidative weathering environment in the upper continental crust. Therefore, large Fe isotopic fractionations observed in various marine sedimentary records are likely due to other processes occurring

Long-term evolution of the heliospheric magnetic field inferred from cosmogenic 44Ti activity in meteorites

NASA Astrophysics Data System (ADS)

Mancuso, S.; Taricco, C.; Colombetti, P.; Rubinetti, S.; Sinha, N.; Bhandari, N.

2018-02-01

Typical reconstructions of historic heliospheric magnetic field (HMF) BHMF are based on the analysis of the sunspot activity, geomagnetic data or on measurement of cosmogenic isotopes stored in terrestrial reservoirs like trees (14C) and ice cores (10Be). The various reconstructions of BHMF are however discordant both in strength and trend. Cosmogenic isotopes, which are produced by galactic cosmic rays impacting on meteoroids and whose production rate is modulated by the varying HMF convected outward by the solar wind, may offer an alternative tool for the investigation of the HMF in the past centuries. In this work, we aim to evaluate the long-term evolution of BHMF over a period covering the past twenty-two solar cycles by using measurements of the cosmogenic 44Ti activity (τ1/2 = 59.2 ± 0.6 yr) measured in 20 meteorites which fell between 1766 and 2001. Within the given uncertainties, our result is compatible with a HMF increase from 4.87-0.30+0.24 nT in 1766 to 6.83-0.11+0.13 nT in 2001, thus implying an overall average increment of 1.96-0.35+0.43 nT over 235 years since 1766 reflecting the modern Grand maximum. The BHMF trend thus obtained is then compared with the most recent reconstructions of the near-Earth HMF strength based on geomagnetic, sunspot number, and cosmogenic isotope data.

Cenozoic climate evolution in Asian region and its influence on isotopic composition of precipitation

NASA Astrophysics Data System (ADS)

Botsyun, Svetlana; Donnadieu, Yannick; Sepulchre, Pierre; Risi, Camille; Fluteau, Frédéric

2015-04-01

The evolution of Asian climate during the Cenozoic as well as the onset of monsoon systems in this area is highly debated. Factors that control climate include the geographical position of continents, the land-sea distribution and altitude of orogens. In tern, several climatic parameters such as air temperature, precipitation amount and isotopic fractionation through mass-dependent processes impact precipitation δ18O lapse rate. Stable oxygen paleoaltimetry is considered to be a very efficient and widely applied technique, but the link between stable oxygen composition of precipitation and climate is not well established. To quantify the influence of paleogeography changes on climate and precipitation δ18O over Asia, the atmospheric general circulation model LMDZ-iso, with embedded stable oxygen isotopes, was used. For more realistic experiments, sea surface temperatures were calculated with the fully coupled model FOAM. Various scenarios of TP growth have been applied together with Paleocene, Eocene, Oligocene and Miocene boundary conditions. The results of our numerical modelling show a significant influence of paleogeography changes on the Asian climate. The retreat of the Paratethys ocean, the changes in latitudinal position of India, and the height of the Tibetan Plateau most likely control precipitation patterns over Asia and cause spatial and temporal isotopic variations linked with the amount effect. Indian Ocean currents restructuring during the Eocene induces a substantial warming over Asian continent. The adiabatic and non-adiabatic temperature effects explain some of δ18O signal variations. We highlight the importance of these multiple factor on paleoelevations estimates derived using oxygen stable isotopes.

Ages and Growth of the Continental Crust from Radiogenic Isotopes

NASA Astrophysics Data System (ADS)

Patchett, P. J.; Samson, S. D.

2003-12-01

The development and application of radiogenic isotopes to dating of geologic events, and to questions of growth, evolution, and recycling processes in the continental crust are mature areas of scientific inquiry. By this we understand that many of the approaches used to date rocks and constrain the evolution of the continents are well established, even routine, and that the scope of data available on age and evolution of continents is very large. This is not to say that new approaches have not been developed in recent years, or that new approaches and/or insights cannot be developed in the future. However, the science of continental crustal evolution is definitely a domain where many of the problems are well defined, the power of the techniques used to solve them are well known, and the limitations of field and laboratory databases, as well as the preserved geologic record, are understood.From the very early days of crustal evolution studies, it was innovations and improvements in laboratory techniques that drove the pace of discovery (e.g., Holmes, 1911; Nier, 1939). This remained true through all the increments in capability reviewed in this chapter, up to the present day. Thus, continental crustal evolution is an area of Earth science where a species of very laboratory-oriented investigator, the "radiogenic isotope geologist" or "geochronologist," has made major advances, even breakthroughs, in understanding. This is true in spite of the fact that many of the individuals of the species may have lacked field expertise, or even more than a primitive level of geologic background. Because design and building of instruments like radiation detectors or mass spectrometers requires a knowledge of physics, many of the early practitioners of rock dating were physicists, like Alfred Nier (cited above). Since the 1970s, essentially all mass spectrometers have been constructed by specialized commercial firms, and the level of physics expertise among isotope geologists has

Isotopic evolution of Mauna Kea volcano: Results from the initial phase of the Hawaii Scientific Drilling Project

USGS Publications Warehouse

Lassiter, J.C.; DePaolo, D.J.; Tatsumoto, M.

1996-01-01

We have examined the Sr, Nd, and Pb isotopic compositions of Mauna Kea lavas recovered by the first drilling phase of the Hawaii Scientific Drilling Project. These lavas, which range in age from ???200 to 400 ka, provide a detailed record of chemical and isotopic changes in basalt composition during the shied/postshield transition and extend our record of Mauna Kea volcanism to a late-shield period roughly equivalent to the last ???100 ka of Mauna Loa activity. Stratigraphic variations in isotopic composition reveal a gradual shift over time toward a more depleted source composition (e.g., higher 143Nd/144Nd, lower 87Sr/86Sr, and lower 3He/4He). This gradual evolution is in sharp contrast with the abrupt appearance of alkalic lavas at ???240 ka recorded by the upper 50 m of Mauna Kea lavas from the core. Intercalated tholeiitic and alkalic lavas from the uppermost Mauna Kea section are isotopically indistinguishable. Combined with major element evidence (e.g., decreasing SiO2 and increasing FeO) that the depth of melt segregation increased during the transition from tholeiitic to alkalic volcanism, the isotopic similarity of tholeiitic and alkalic lavas argues against significant lithosphere involvement during melt generation. Instead, the depleted isotopic signatures found in late shield-stage lavas are best explained by increasing the proportion of melt generated from a depleted upper mantle component entrained and heated by the rising central plume. Direct comparison of Mauna Kea and Mauna Loa lavas erupted at equivalent stages in these volcanoes' life cycles reveals persistent chemical and isotopic differences independent of the temporal evolution of each volcano. The oldest lavas recovered from the drillcore are similar to modern Kilauea lavas, but are distinct from Mauna Loa lavas. Mauna Kea lavas have higher 143Nd/144Nd and 206Pb/204Pb and lower 87Sr/86Sr. Higher concentrations of incompatible trace elements in primary magmas, lower SiO2, and higher FeO also

Multiple sulfur isotopes monitor fluid evolution of an Archean orogenic gold deposit

NASA Astrophysics Data System (ADS)

LaFlamme, Crystal; Sugiono, Dennis; Thébaud, Nicolas; Caruso, Stefano; Fiorentini, Marco; Selvaraja, Vikraman; Jeon, Heejin; Voute, François; Martin, Laure

2018-02-01

The evolution of a gold-bearing hydrothermal fluid from its source to the locus of gold deposition is complex as it experiences rapid changes in thermochemical conditions during ascent through the crust. Although it is well established that orogenic gold deposits are generated during time periods of abundant crustal growth and/or reworking, the source of fluid and the thermochemical processes that control gold precipitation remain poorly understood. In situ analyses of multiple sulfur isotopes offer a new window into the relationship between source reservoirs of Au-bearing fluids and the thermochemical processes that occur along their pathway to the final site of mineralisation. Whereas δ34S is able to track changes in the evolution of the thermodynamic conditions of ore-forming fluids, Δ33S is virtually indelible and can uniquely fingerprint an Archean sedimentary reservoir that has undergone mass independent fractionation of sulfur (MIF-S). We combine these two tracers (δ34S and Δ33S) to characterise a gold-bearing laminated quartz breccia ore zone and its sulfide-bearing alteration halo in the (+6 Moz Au) structurally-controlled Archean Waroonga deposit located in the Eastern Goldfields Superterrane of the Yilgarn Craton, Western Australia. Over 250 analyses of gold-associated sulfides yield a δ34S shift from what is interpreted as an early pre-mineralisation phase, with chalcopyrite-pyrrhotite (δ34S = +0.7‰ to +2.9‰) and arsenopyrite cores (δ34S = ∼-0.5‰), to a syn-mineralisation stage, reflected in Au-bearing arsenopyrite rims (δ34S = -7.6‰ to +1.5‰). This shift coincides with an unchanging Δ33S value (Δ33S = +0.3‰), both temporally throughout the Au-hosting hydrothermal sulfide paragenesis and spatially across the Au ore zone. These results indicate that sulfur is at least partially recycled from MIF-S-bearing Archean sediments. Further, the invariant nature of the observed MIF-S signature demonstrates that sulfur is derived from a

The effectiveness of using carbonate isotope measurements of body tissues to infer diet in human evolution: Evidence from wild western chimpanzees (Pan troglodytes verus).

PubMed

Fahy, Geraldine E; Boesch, Christophe; Hublin, Jean-Jacques; Richards, Michael P

2015-11-01

Changes in diet throughout hominin evolution have been linked with important evolutionary changes. Stable carbon isotope analysis of inorganic apatite carbonate is the main isotopic method used to reconstruct fossil hominin diets; to test its effectiveness as a paleodietary indicator we present bone and enamel carbonate carbon isotope data from a well-studied population of modern wild western chimpanzees (Pan troglodytes verus) of known sex and age from Taï, Cote d'Ivoire. We found a significant effect of age class on bone carbonate values, with adult chimpanzees being more (13)C- and (18)O-depleted compared to juveniles. Further, to investigate habitat effects, we compared our data to existing apatite data on eastern chimpanzees (P. troglodytes schweinfurthii) and found that the Taï chimpanzees are significantly more depleted in enamel δ(13)Cap and δ(18)Oap compared to their eastern counterparts. Our data are the first to present a range of tissue-specific isotope data from the same group of wild western chimpanzees and, as such, add new data to the growing number of modern non-human primate comparative isotope datasets providing valuable information for the interpretation of diet throughout hominin evolution. By comparing our data to published isotope data on fossil hominins we found that our modern chimpanzee bone and enamel data support hypotheses that the trend towards increased consumption of C4 foods after 4 Ma (millions of years ago) is unique to hominins. Copyright © 2015 Elsevier Ltd. All rights reserved.

Mantle evolution on Mars: Constraints from Lu-Hf and Sm-Nd isotope systematics of SNC meteorites

NASA Astrophysics Data System (ADS)

Scherer, E. E.; Kurahashi, E.; Mezger, K.

2012-12-01

The long-lived 176Lu-176Hf and 147Sm-143Nd isotope systems are commonly employed to track the evolution of complementary mantle and crust reservoirs. The four elements involved are refractory and lithophile, and thus their relative abundances are not expected to have been changed by accretion or core formation. Subsequent silicate differentiation processes, however, e.g., the formation of crust by extraction of melts from the mantle, will fractionate Lu/Hf and Sm/Nd. This typically leaves a depleted mantle with higher Lu/Hf and Sm/Nd values than those of the undifferentiated, presumably chondritic parental reservoir. On the other hand, these same values in crustal rocks tend to be lower than those of their source. (Apparent exceptions are the Martian shergottites, which tend to have lower Lu/Hf as expected, but Sm/Nd higher than their presumed sources. Such decoupling of the two isotope systems may be explained by two-stage melting [e.g., 1, 5].) The ensuing chemical variability among secondary and later generation silicate reservoirs causes their isotopic compositions (e.g., 176Hf/177Hf and 143Nd/144Nd) to diverge from that of the bulk silicate planet over hundreds of millions of years. The resulting isotopic diversity preserved (SNC) meteorites is being used to constrain the differentiation history, melting mineralogy, and dynamics of the Martian mantle [e.g., 1-8]. However, interpretations based on the initial isotope compositions of Hf and Nd strongly depend on the accuracy of crystallization ages. The ages of shergottites in particular are debated (e.g., [3,4,7]). To resolve this issue and gain a better understanding of Martian mantle evolution, we are investigating the Lu-Hf and Sm-Nd systematics of bulk SNC meteorites and constructing internal (mineral) isochrons. Eleven bulk Martian meteorites (5 shergottites, 4 nakhlites, and 2 chassignites) were digested without prior leaching in high-pressure autoclaves for 5 days. Initial ɛ176Hf and ɛ143Nd values

Stable isotopic composition of perchlorate and nitrate accumulated in plants: Hydroponic experiments and field data.

PubMed

Estrada, Nubia Luz; Böhlke, J K; Sturchio, Neil C; Gu, Baohua; Harvey, Greg; Burkey, Kent O; Grantz, David A; McGrath, Margaret T; Anderson, Todd A; Rao, Balaji; Sevanthi, Ritesh; Hatzinger, Paul B; Jackson, W Andrew

2017-10-01

Natural perchlorate (ClO 4 - ) in soil and groundwater exhibits a wide range in stable isotopic compositions (δ 37 Cl, δ 18 O, and Δ 17 O), indicating that ClO 4 - may be formed through more than one pathway and/or undergoes post-depositional isotopic alteration. Plants are known to accumulate ClO 4 - , but little is known about their ability to alter its isotopic composition. We examined the potential for plants to alter the isotopic composition of ClO 4 - in hydroponic and field experiments conducted with snap beans (Phaseolus vulgaris L.). In hydroponic studies, anion ratios indicated that ClO 4 - was transported from solutions into plants similarly to NO 3 - but preferentially to Cl - (4-fold). The ClO 4 - isotopic compositions of initial ClO 4 - reagents, final growth solutions, and aqueous extracts from plant tissues were essentially indistinguishable, indicating no significant isotope effects during ClO 4 - uptake or accumulation. The ClO 4 - isotopic composition of field-grown snap beans was also consistent with that of ClO 4 - in varying proportions from irrigation water and precipitation. NO 3 - uptake had little or no effect on NO 3 - isotopic compositions in hydroponic solutions. However, a large fractionation effect with an apparent ε ( 15 N/ 18 O) ratio of 1.05 was observed between NO 3 - in hydroponic solutions and leaf extracts, consistent with partial NO 3 - reduction during assimilation within plant tissue. We also explored the feasibility of evaluating sources of ClO 4 - in commercial produce, as illustrated by spinach, for which the ClO 4 - isotopic composition was similar to that of indigenous natural ClO 4 - . Our results indicate that some types of plants can accumulate and (presumably) release ClO 4 - to soil and groundwater without altering its isotopic characteristics. Concentrations and isotopic compositions of ClO 4 - and NO 3 - in plants may be useful for determining sources of fertilizers and sources of ClO 4 - in their growth

Stable isotopic composition of perchlorate and nitrate accumulated in plants: Hydroponic experiments and field data

USGS Publications Warehouse

Estrada, Nubia Luz; Böhlke, John Karl; Sturchio, Neil C.; Gu, Baohua; Harvey, Greg; Burkey, Kent O.; Grantz, David A.; McGrath, Margaret T.; Anderson, Todd A.; Rao, Balaji; Sevanthi, Ritesh; Hatzinger, Paul B.; Jackson, W. Andrew

2017-01-01

Natural perchlorate (ClO4−) in soil and groundwater exhibits a wide range in stable isotopic compositions (δ37Cl, δ18O, and Δ17O), indicating that ClO4− may be formed through more than one pathway and/or undergoes post-depositional isotopic alteration. Plants are known to accumulate ClO4−, but little is known about their ability to alter its isotopic composition. We examined the potential for plants to alter the isotopic composition of ClO4− in hydroponic and field experiments conducted with snap beans (Phaseolus vulgaris L.). In hydroponic studies, anion ratios indicated that ClO4− was transported from solutions into plants similarly to NO3− but preferentially to Cl− (4-fold). The ClO4− isotopic compositions of initial ClO4− reagents, final growth solutions, and aqueous extracts from plant tissues were essentially indistinguishable, indicating no significant isotope effects during ClO4− uptake or accumulation. The ClO4− isotopic composition of field-grown snap beans was also consistent with that of ClO4− in varying proportions from irrigation water and precipitation. NO3− uptake had little or no effect on NO3− isotopic compositions in hydroponic solutions. However, a large fractionation effect with an apparent ε (15N/18O) ratio of 1.05 was observed between NO3− in hydroponic solutions and leaf extracts, consistent with partial NO3− reduction during assimilation within plant tissue. We also explored the feasibility of evaluating sources of ClO4− in commercial produce, as illustrated by spinach, for which the ClO4− isotopic composition was similar to that of indigenous natural ClO4−. Our results indicate that some types of plants can accumulate and (presumably) release ClO4− to soil and groundwater without altering its isotopic characteristics. Concentrations and isotopic compositions of ClO4−and NO3− in plants may be useful for determining sources of fertilizers and sources of ClO4− in their growth environments and

Shape Evolution in Neutron-Rich Krypton Isotopes Beyond N =60 : First Spectroscopy of Kr,10098

NASA Astrophysics Data System (ADS)

Flavigny, F.; Doornenbal, P.; Obertelli, A.; Delaroche, J.-P.; Girod, M.; Libert, J.; Rodriguez, T. R.; Authelet, G.; Baba, H.; Calvet, D.; Château, F.; Chen, S.; Corsi, A.; Delbart, A.; Gheller, J.-M.; Giganon, A.; Gillibert, A.; Lapoux, V.; Motobayashi, T.; Niikura, M.; Paul, N.; Roussé, J.-Y.; Sakurai, H.; Santamaria, C.; Steppenbeck, D.; Taniuchi, R.; Uesaka, T.; Ando, T.; Arici, T.; Blazhev, A.; Browne, F.; Bruce, A.; Carroll, R.; Chung, L. X.; Cortés, M. L.; Dewald, M.; Ding, B.; Franchoo, S.; Górska, M.; Gottardo, A.; Jungclaus, A.; Lee, J.; Lettmann, M.; Linh, B. D.; Liu, J.; Liu, Z.; Lizarazo, C.; Momiyama, S.; Moschner, K.; Nagamine, S.; Nakatsuka, N.; Nita, C.; Nobs, C. R.; Olivier, L.; Orlandi, R.; Patel, Z.; Podolyák, Zs.; Rudigier, M.; Saito, T.; Shand, C.; Söderström, P. A.; Stefan, I.; Vaquero, V.; Werner, V.; Wimmer, K.; Xu, Z.

2017-06-01

We report on the first γ -ray spectroscopy of low-lying states in neutron-rich Kr,10098 isotopes obtained from Rb,10199(p ,2 p ) reactions at ˜220 MeV /nucleon . A reduction of the 21+ state energies beyond N =60 demonstrates a significant increase of deformation, shifted in neutron number compared to the sharper transition observed in strontium and zirconium isotopes. State-of-the-art beyond-mean-field calculations using the Gogny D1S interaction predict level energies in good agreement with experimental results. The identification of a low-lying (02+, 22+) state in Kr 98 provides the first experimental evidence of a competing configuration at low energy in neutron-rich krypton isotopes consistent with the oblate-prolate shape coexistence picture suggested by theory.

Historical Evolution of the Field View and Textbook Accounts.

ERIC Educational Resources Information Center

Pocovi, M. Cecilia; Finley, Fred N.

2003-01-01

Analyzes how two electromagnetism textbooks approach the concept of electric field. Uses historical evolution of the field representation. Indicates that one textbook mixes up the historical and pedagogical reasons for the introduction of the concept of field while the other one presents a sketch that might lead students to understand the field…

Real-time isotope monitoring network at the Biosphere 2 Landscape Evolution Observatory resolves meter-to-catchment scale flow dynamics

NASA Astrophysics Data System (ADS)

Volkmann, T. H. M.; Van Haren, J. L. M.; Kim, M.; Harman, C. J.; Pangle, L.; Meredith, L. K.; Troch, P. A.

2017-12-01

Stable isotope analysis is a powerful tool for tracking flow pathways, residence times, and the partitioning of water resources through catchments. However, the capacity of stable isotopes to characterize catchment hydrological dynamics has not been fully exploited as commonly used methodologies constrain the frequency and extent at which isotopic data is available across hydrologically-relevant compartments (e.g. soil, plants, atmosphere, streams). Here, building upon significant recent developments in laser spectroscopy and sampling techniques, we present a fully automated monitoring network for tracing water isotopes through the three model catchments of the Landscape Evolution Observatory (LEO) at the Biosphere 2, University of Arizona. The network implements state-of-the-art techniques for monitoring in great spatiotemporal detail the stable isotope composition of water in the subsurface soil, the discharge outflow, and the atmosphere above the bare soil surface of each of the 330-m2 catchments. The extensive valving and probing systems facilitate repeated isotope measurements from a total of more than five-hundred locations across the LEO domain, complementing an already dense array of hydrometric and other sensors installed on, within, and above each catchment. The isotope monitoring network is operational and was leveraged during several months of experimentation with deuterium-labelled rain pulse applications. Data obtained during the experiments demonstrate the capacity of the monitoring network to resolve sub-meter to whole-catchment scale flow and transport dynamics in continuous time. Over the years to come, the isotope monitoring network is expected to serve as an essential tool for collaborative interdisciplinary Earth science at LEO, allowing us to disentangle changes in hydrological behavior as the model catchments evolve in time through weathering and colonization by plant communities.

Thermal evolution of old white dwarfs

NASA Astrophysics Data System (ADS)

Kozhberov, Andrew

2017-11-01

This work is devoted to a description of thermodynamic properties of Coulomb crystals which are expected to form in white dwarf interiors. Effects of magnetic field, isotopic impurities, polarization of the electron background and crystal lattice type on the thermal evolution of white dwarfs are discussed. It is shown that the electron polarization could play a noticeable role in the cooling process. While other parameters in concern do not make a significant impact.

Using environmental isotopes along with major hydro-geochemical compositions to assess deep groundwater formation and evolution in eastern coastal China

NASA Astrophysics Data System (ADS)

Xu, Naizheng; Gong, Jianshi; Yang, Guoqiang

2018-01-01

Hydrochemical analysis and environmental isotopic tracing are successfully applied to study groundwater evolution processes. Located in eastern China, the Jiangsu Coastal Plain is characterized by an extensively exploited deep groundwater system, and groundwater salinization has become the primary water environmental problem. This paper provides a case study on the use of a hydrochemical and environmental isotopic approach to assess possible mixing and evolution processes at Yoco Port, Jiangsu Province, China. Hydrochemical and isotopic patterns of deep groundwater allow one to distinguish different origins in deep water systems. HCO3- is the dominant anion in the freshwater samples, whereas Na+ and Cl- are the dominant major ions in the saline samples. According to δ18O, δ2H and 14C dating, the fresh water is derived from precipitation under a colder climate during the Glacial Maximum (Dali Glacial), while the saline groundwater is influenced by glacial-interglacial cycles during the Holocene Hypsithermal. The δ18O, δ2H and 3H data confirm that deep groundwater in some boreholes is mixed with overlying saline water. The deep groundwater reservoir can be divided into a saline water sector and a fresh water sector, and each show distinct hydrochemical and isotopic compositions. The saline groundwater found in the deep aquifer cannot be associated with present seawater intrusion. Since the Last Glacial Maximum in the Late Pleistocene, the deep groundwater flow system has evolved to its current status with the decrease in ice cover and the rising of sea level. However, the hydraulic connection is strengthened by continuous overexploitation, and deep groundwater is mixed with shallow groundwater at some points.

Using environmental isotopes along with major hydro-geochemical compositions to assess deep groundwater formation and evolution in eastern coastal China.

PubMed

Xu, Naizheng; Gong, Jianshi; Yang, Guoqiang

2018-01-01

Hydrochemical analysis and environmental isotopic tracing are successfully applied to study groundwater evolution processes. Located in eastern China, the Jiangsu Coastal Plain is characterized by an extensively exploited deep groundwater system, and groundwater salinization has become the primary water environmental problem. This paper provides a case study on the use of a hydrochemical and environmental isotopic approach to assess possible mixing and evolution processes at Yoco Port, Jiangsu Province, China. Hydrochemical and isotopic patterns of deep groundwater allow one to distinguish different origins in deep water systems. HCO 3 - is the dominant anion in the freshwater samples, whereas Na + and Cl - are the dominant major ions in the saline samples. According to δ 18 O, δ 2 H and 14 C dating, the fresh water is derived from precipitation under a colder climate during the Glacial Maximum (Dali Glacial), while the saline groundwater is influenced by glacial-interglacial cycles during the Holocene Hypsithermal. The δ 18 O, δ 2 H and 3 H data confirm that deep groundwater in some boreholes is mixed with overlying saline water. The deep groundwater reservoir can be divided into a saline water sector and a fresh water sector, and each show distinct hydrochemical and isotopic compositions. The saline groundwater found in the deep aquifer cannot be associated with present seawater intrusion. Since the Last Glacial Maximum in the Late Pleistocene, the deep groundwater flow system has evolved to its current status with the decrease in ice cover and the rising of sea level. However, the hydraulic connection is strengthened by continuous overexploitation, and deep groundwater is mixed with shallow groundwater at some points. Copyright © 2017 Elsevier B.V. All rights reserved.

The Evolution of Water in Martian Atmosphere, Hydrosphere, and Cryosphere: Insights from Hydrogen Isotopes

NASA Astrophysics Data System (ADS)

Usui, T.; Kurokawa, H.; Alexander, C.; Simon, J. I.; Wang, J.; Jones, J. H.

2016-12-01

Mars exploration missions provide compelling evidence for the presence of liquid water during the earliest geologic era (Noachian: > 3.9 Ga) of Mars. The amount and stability of liquid water on the surface is strongly influenced by the composition and pressure of the atmosphere. However, the evolution of Noachian atmosphere has been poorly constrained due to uncertainties of atmospheric loss regimes and internal/external factors such as impact flux and volcanic degassing. We can trace the evolution of the early Martian atmosphere and its interaction with the hydrosphere and cryosphere with hydrogen isotope ratios (D/H) because they fractionate during atmospheric escape and during hydrological cycling between the atmosphere, surface waters, and the polar ice caps. This study reports D/H ratios of primordial and 4 Ga-old atmosphere by ion microprobe analyses of Martian meteorites. Analyses of olivine-hosted glass inclusions in the most primitive shergottite (Yamato 980459) provide a near-chondritic D/H ratio (1.3×SMOW) for the 4.5 Ga primordial water preserved in the mantle. On the other hand, carbonates in Allan Hills 84001 provide a D/H range (1.5-2.0×SMOW) for the Noachian surface water that was isotopically equilibrated with the 4 Ga atmosphere. The latter observation requires that even after the Noachian period the hydrogen isotopes were fractionated significantly to reach the present-day value of 6×SMOW. Using the one-reservoir model of Kurokawa et al. (2014) we can provide minimum estimates on the amounts of hydrogen loss before and after 4 Ga based on the D/H data from the meteorites (1.3×SMOW at 4.5 Ga and 1.5-2.0×SMOW at 4 Ga) assuming the volume of polar surface-ice (20-30 m global equivalent layers, GEL). The model indicates that the hydrogen loss during the first 0.5 billion years (16-54 m GEL) was comparable to those (42-93 mGEL) in the remaining Martian history. These values are distinctly lower than the geological estimates on the volumes of

Evolution of protoplanetary disks with dynamo magnetic fields

NASA Technical Reports Server (NTRS)

Reyes-Ruiz, M.; Stepinski, Tomasz F.

1994-01-01

The notion that planetary systems are formed within dusty disks is certainly not a new one; the modern planet formation paradigm is based on suggestions made by Laplace more than 200 years ago. More recently, the foundations of accretion disk theory where initially developed with this problem in mind, and in the last decade astronomical observations have indicated that many young stars have disks around them. Such observations support the generally accepted model of a viscous Keplerian accretion disk for the early stages of planetary system formation. However, one of the major uncertainties remaining in understanding the dynamical evolution of protoplanetary disks is the mechanism responsible for the transport of angular momentum and subsequent mass accretion through the disk. This is a fundamental piece of the planetary system genesis problem since such mechanisms will determine the environment in which planets are formed. Among the mechanisms suggested for this effect is the Maxwell stress associated with a magnetic field treading the disk. Due to the low internal temperatures through most of the disk, even the question of the existence of a magnetic field must be seriously studied before including magnetic effects in the disk dynamics. On the other hand, from meteoritic evidence it is believed that magnetic fields of significant magnitude existed in the earliest, PP-disk-like, stage of our own solar system's evolution. Hence, the hypothesis that PP disks are magnetized is not made solely on the basis of theory. Previous studies have addressed the problem of the existence of a magnetic field in a steady-state disk and have found that the low conductivity results in a fast diffusion of the magnetic field on timescales much shorter than the evolutionary timescale. Hence the only way for a magnetic field to exist in PP disks for a considerable portion of their lifetimes is for it to be continuously regenerated. In the present work, we present results on the self

Quadrupole collectivity beyond N = 50 in neutron- rich Se and Kr isotopes

NASA Astrophysics Data System (ADS)

Elman, Brandon; Gade, A.; Barofsky, D.; Bender, P. C.; Bowry, M.; Hjorth-Jensen, M.; Kemper, K. W.; Lipschutz, S.; Lunderberg, E.; Sachmpazidi, N.; Terpstra, N.; Walters, W. B.; Weisshaar, D.; Westerberg, A.; Williams, S. J.; Wimmer, K.

2017-09-01

We will present results on measuring the B (E 2 ;01+ ->2n+) strength for the neutron-rich 88,90Kr and 86Se isotopes from intermediate-energy Coulomb excitation. The electric quadrupole transition strengths to the first 2+ state complete, with considerably improved uncertainties, the evolution of quadrupole collectivity in the Kr and Se isotopes approaching N = 60 , for which 90Kr and 86Se had previously been the most uncertain. We also report significant excitation strength to several higher lying 2+ states in the krypton isotopes. The results confirm shell model calculations in the π (fpg) - ν (sdg) shell with only a minimally tuned shell model setup that is based on a nucleon-nucleon interaction derived from effective field theory with effective charges adjusted to 86Kr.

Workshop on Evolution of Martian Volatiles. Part 1

NASA Technical Reports Server (NTRS)

Jakosky, B. (Editor); Treiman, A. (Editor)

1996-01-01

This volume contains papers that were presented on February 12-14, 1996 at the Evolution for Martian Volatiles Workshop. Topics in this volume include: returned Martian samples; acidic volatiles and the Mars soil; solar EUV Radiation; the ancient Mars Thermosphere; primitive methane atmospheres on Earth and Mars; the evolution of Martian water; the role of SO2 for the climate history of Mars; impact crater morphology; the formation of the Martian drainage system; atmospheric dust-water ice Interactions; volatiles and volcanos; accretion of interplanetary dust particles; Mars' ionosphere; simulations with the NASA Ames Mars General Circulation Model; modeling the Martian water cycle; the evolution of Martian atmosphere; isotopic composition; solar occultation; magnetic fields; photochemical weathering; NASA's Mars Surveyor Program; iron formations; measurements of Martian atmospheric water vapor; and the thermal evolution Models of Mars.

Importance of the Lu-Hf isotopic system in studies of planetary chronology and chemical evolution

USGS Publications Warehouse

Patchett, P.J.

1983-01-01

The 176Lu-176Hf isotope method and its applications in earth sciences are discussed. Greater fractionation of Lu/Hf than Sm/Nd in planetary magmatic processes makes 176Hf 177Hf a powerful geochemical tracer. In general, proportional variations of 176Hf 177Hf exceed those of 143Nd l44Nd by factors of 1.5-3 in terrestrial and lunar materials. Lu-Hf studies therefore have a major contribution to make in understanding of terrestrial and other planetary evolution through time, and this is the principal importance of Lu-Hf. New data on basalts from oceanic islands show unequivocally that whereas considerable divergences occur in 176Hf 177Hf- 87Sr 86Sr and 143Nd l44Nd- 87Sr 86Sr diagrams, 176Hf 177Hf and 143Nd 144Nd display a single, linear isotopic variation in the suboceanic mantle. These discordant 87Sr 86Sr relationships may allow, with the acquisition of further Hf-Nd-Sr isotopic data, a distinction between processes such as mantle metasomatism, influence of seawater-altered material in the magma source, or recycling of sediments into the mantle. In order to evaluate the Hf-Nd isotopic correlation in terms of mantle fractionation history, there is a need for measurements of Hf distribution coefficients between silicate minerals and liquids, and specifically for a knowledge of Hf behavior in relation to rareearth elements. For studying ancient terrestrial Hf isotopic variations, the best quality Hf isotope data are obtained from granitoid rocks or zircons. New data show that very U-Pb discordant zircons may have upwardly-biased 176Hf 177Hf, but that at least concordant to slightly discordant zircons appear to be reliable carriers of initial 176Hf 177Hf. Until the controls on addition of radiogenic Hf to zircon are understood, combined zircon-whole rock studies are recommended. Lu-Hf has been demonstrated as a viable tool for dating of ancient terrestrial and extraterrestrial samples, but because it offers little advantage over existing methods, is unlikely to find

Tachyon field in loop quantum cosmology: Inflation and evolution picture

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xiong Huaui; Zhu Jianyang

2007-04-15

Loop quantum cosmology (LQC) predicts a nonsingular evolution of the universne through a bounce in the high energy region. We show that this is always true in tachyon matter LQC. Differing from the classical Friedman-Robertson-Walker (FRW) cosmology, the super inflation can appear in the tachyon matter LQC; furthermore, the inflation can be extended to the region where classical inflation stops. Using the numerical method, we give an evolution picture of the tachyon field with an exponential potential in the context of LQC. It indicates that the quantum dynamical solutions have the same attractive behavior as the classical solutions do. Themore » whole evolution of the tachyon field is that in the distant past, the tachyon field--being in the contracting cosmology--accelerates to climb up the potential hill with a negative velocity; then at the boundary the tachyon field is bounced into an expanding universe with positive velocity rolling down to the bottom of the potential. In the slow roll limit, we compare the quantum inflation with the classical case in both an analytic and a numerical way.« less

A climate and environmental context for hominid evolution: Preliminary biomarker and compound specific isotope data from Lake Magadi, Kenya

NASA Astrophysics Data System (ADS)

Werne, J. P.; Ferland, T.; Cohen, A. S.; Lowenstein, T. K.; Deocampo, D.; Renaut, R.; Bernhart, O. R.

2016-12-01

The Hominid Sites and Paleolakes Drilling Project (HSPDP) seeks to understand the paleoclimatic and paleoenvironmental context of human evolution and development by analysis of paleolacustrine cores taken near key hominin fossil and artifact localities in Kenya and Ethiopia. Here, we present biomarker and compound specific isotope data from a 200 m drill core from Lake Magadi, Kenya. Located 20 km from the Koora Plain in the southern Kenya Rift, and adjacent to the Olorgesailie basin, Lake Magadi is in one of the richest Early-Late Pleistocene archaeological localities in Africa, a region that has been key in debates about the relationship between climate and evolution. Preliminary biomarker work has shown promising abundances of leaf waxes, whose isotopic compositions of hydrogen and carbon are commonly used as proxies for paleoprecipitation and watershed vegetation composition, respectively. A complementary record of glycerol dialkyl glycerol tetraethers (GDGTs), which can serve as a proxy for temperature, soil input, and/or pH, will be presented alongside the leaf wax data to enhance the paleoenvironmental reconstruction of Lake Magadi. Present-day Lake Magadi is a saline pan, a descendant of a series of paleolakes that have occupied its drainage basin for approximately one million years. Hominid evolution milestones such as the mastering of fire as a tool, rapid encephalization, and the emergence of Homo sapiens all are thought to have occurred in the time frame encompassed by our record.

Planetary Magnetic Fields and Climate Evolution

NASA Astrophysics Data System (ADS)

Brain, D. A.; Leblanc, F.; Luhmann, J. G.; Moore, T. E.; Tian, F.

participate in chemical reactions that produce carbon monoxide (CO) and carbon dioxide (CO2). Models of the entire atmosphere system (including planetary plasma interactions) should continue to shed light on the connections between magnetic fields and climate, as well as models that consider a single planetary body in both magnetized and unmagnetized states. Future measurements, such as those that will be made by the Mars Atmosphere and Volatile Evolution (MAVEN) spacecraft to Mars, will provide better constraints on the importance of magnetic fields in the evolution of atmospheres.

A combined geodynamical-geochemical modelling approach to investigating the Lu-Hf isotopic evolution of the terrestrial mantle and crust

NASA Astrophysics Data System (ADS)

Jones, R.; Van Keken, P. E.; Hauri, E.; Vervoort, J. D.; Ballentine, C. J.

2017-12-01

The chemical and isotopic evolution of the Earth's mantle is largely influenced by the formation of oceanic and continental crust at spreading ridges and through arc volcanism, and the subsequent recycling of this crust back into the mantle via subduction. In this study we use a combined geodynamical-geochemical modelling approach to investigate the Lu-Hf isotopic evolution of the terrestrial mantle and crust. We utilise the geodynamic mantle convection model developed by Brandenburg et al., 2008. This model satisfies the geophysical constraints of oceanic heat flow and average plate velocities, as well as geochemical observations such as 40Ar in the atmosphere. It has also been shown to reproduce the observed geochemical distributions in multiple isotope systems (U-Th-Pb, Rb-Sr, Sm-Nd, and Re-Os) that define the DMM, HIMU and EM1 mantle endmembers. We go on to extend this application to investigate the Lu-Hf isotope system, specifically in combination with Sm-Nd. The model has been updated to include a self-consistent reorganisation of the plates with regions of up-/down-wellings. The model is initiated at 4.55 Ga, assumes continental crust is produced from 4 Ga and that a transition from `dry' to `wet' subduction occurs at 3 Ga. The results of the geodynamic model suggest that the ƐHf composition and evolution of the upper mantle can be generated through the extraction and recycling of oceanic crust, which creates an enriched and radiogenic reservoir at the core-mantle boundary. The formation of continental crust, which is extracted at each time-step from the oceanic crust to imitate subduction zone processes, and the recycling of this continental crust as sediments, plays a lesser role. Depending on the selected partition coefficients DMM, FOZO and HIMU mantle endmember compositions are also produced via the simple extraction and recycling of oceanic crust. The formation of continental crust produces spread in the ƐNd vs. ƐHf array and extends the model

The origin, evolution and signatures of primordial magnetic fields.

PubMed

Subramanian, Kandaswamy

2016-07-01

The universe is magnetized on all scales probed so far. On the largest scales, galaxies and galaxy clusters host magnetic fields at the micro Gauss level coherent on scales up to ten kpc. Recent observational evidence suggests that even the intergalactic medium in voids could host a weak  ∼  10(-16) Gauss magnetic field, coherent on Mpc scales. An intriguing possibility is that these observed magnetic fields are a relic from the early universe, albeit one which has been subsequently amplified and maintained by a dynamo in collapsed objects. We review here the origin, evolution and signatures of primordial magnetic fields. After a brief summary of magnetohydrodynamics in the expanding universe, we turn to magnetic field generation during inflation and phase transitions. We trace the linear and nonlinear evolution of the generated primordial fields through the radiation era, including viscous effects. Sensitive observational signatures of primordial magnetic fields on the cosmic microwave background, including current constraints from Planck, are discussed. After recombination, primordial magnetic fields could strongly influence structure formation, especially on dwarf galaxy scales. The resulting signatures on reionization, the redshifted 21 cm line, weak lensing and the Lyman-α forest are outlined. Constraints from radio and γ-ray astronomy are summarized. Astrophysical batteries and the role of dynamos in reshaping the primordial field are briefly considered. The review ends with some final thoughts on primordial magnetic fields.

Concerns about Quadrupole ICP-MS Lead Isotopic Data and Interpretations in the Environment and Health Fields.

PubMed

Gulson, Brian; Kamenov, George D; Manton, William; Rabinowitz, Michael

2018-04-11

There has been a massive increase in recent years of the use of lead (Pb) isotopes in attempts to better understand sources and pathways of Pb in the environment and in man or experimental animals. Unfortunately, there have been many cases where the quality of the isotopic data, especially that obtained by quadrupole inductively coupled plasma mass spectrometry (Q-ICP-MS), are questionable, resulting in questionable identification of potential sources, which, in turn, impacts study interpretation and conclusions. We present several cases where the isotopic data have compromised interpretation because of the use of only the major isotopes 208 Pb/ 206 Pb and 207 Pb/ 206 Pb, or their graphing in other combinations. We also present some examples comparing high precision data from thermal ionization (TIMS) or multi-collector plasma mass spectrometry (MC-ICP-MS) to illustrate the deficiency in the Q-ICP-MS data. In addition, we present cases where Pb isotopic ratios measured on Q-ICP-MS are virtually impossible for terrestrial samples. We also evaluate the Pb isotopic data for rat studies, which had concluded that Pb isotopic fractionation occurs between different organs and suggest that this notion of biological fractionation of Pb as an explanation for isotopic differences is not valid. Overall, the brief review of these case studies shows that Q-ICP-MS as commonly practiced is not a suitable technique for precise and accurate Pb isotopic analysis in the environment and health fields.

Concerns about Quadrupole ICP-MS Lead Isotopic Data and Interpretations in the Environment and Health Fields

PubMed Central

Gulson, Brian; Manton, William; Rabinowitz, Michael

2018-01-01

There has been a massive increase in recent years of the use of lead (Pb) isotopes in attempts to better understand sources and pathways of Pb in the environment and in man or experimental animals. Unfortunately, there have been many cases where the quality of the isotopic data, especially that obtained by quadrupole inductively coupled plasma mass spectrometry (Q-ICP-MS), are questionable, resulting in questionable identification of potential sources, which, in turn, impacts study interpretation and conclusions. We present several cases where the isotopic data have compromised interpretation because of the use of only the major isotopes 208Pb/206Pb and 207Pb/206Pb, or their graphing in other combinations. We also present some examples comparing high precision data from thermal ionization (TIMS) or multi-collector plasma mass spectrometry (MC-ICP-MS) to illustrate the deficiency in the Q-ICP-MS data. In addition, we present cases where Pb isotopic ratios measured on Q-ICP-MS are virtually impossible for terrestrial samples. We also evaluate the Pb isotopic data for rat studies, which had concluded that Pb isotopic fractionation occurs between different organs and suggest that this notion of biological fractionation of Pb as an explanation for isotopic differences is not valid. Overall, the brief review of these case studies shows that Q-ICP-MS as commonly practiced is not a suitable technique for precise and accurate Pb isotopic analysis in the environment and health fields. PMID:29641487

The evolution of the global selenium cycle: Secular trends in Se isotopes and abundances

NASA Astrophysics Data System (ADS)

Stüeken, E. E.; Buick, R.; Bekker, A.; Catling, D.; Foriel, J.; Guy, B. M.; Kah, L. C.; Machel, H. G.; Montañez, I. P.; Poulton, S. W.

2015-08-01

The Earth's surface has undergone major transitions in its redox state over the past three billion years, which have affected the mobility and distribution of many elements. Here we use Se isotopic and abundance measurements of marine and non-marine mudrocks to reconstruct the evolution of the biogeochemical Se cycle from ∼3.2 Gyr onwards. The six stable isotopes of Se are predominantly fractionated during redox reactions under suboxic conditions, which makes Se a potentially valuable new tool for identifying intermediate stages from an anoxic to a fully oxygenated world. δ82/78Se shows small fractionations of mostly less than 2‰ throughout Earth's history and all are mass-dependent within error. In the Archean, especially after 2.7 Gyr, we find an isotopic enrichment in marine (+0.37 ± 0.27‰) relative to non-marine samples (-0.28 ± 0.67‰), paired with increasing Se abundances. Student t-tests show that these trends are statistically significant. Although we cannot completely rule out the possibility of volcanic Se addition, these trends may indicate the onset of oxidative weathering on land, followed by non-quantitative reduction of Se oxyanions during fluvial transport. The Paleoproterozoic Great Oxidation Event (GOE) is not reflected in the marine δ82/78Se record. However, we find a major inflection in the secular δ82/78Se trend during the Neoproterozoic, from a Precambrian mean of +0.42 ± 0.45‰ to a Phanerozoic mean of -0.19 ± 0.59‰. This drop probably reflects the oxygenation of the deep ocean at this time, stabilizing Se oxyanions throughout the water column. Since then, reduction of Se oxyanions has likely been restricted to anoxic basins and diagenetic environments in sediments. In light of recent Cr isotope data, it is likely that oxidative weathering before the Neoproterozoic produced Se oxyanions in the intermediate redox state SeIV, whereas the fully oxidized species SeVI became more abundant after the Neoproterozoic rise of

N-C isotopic investigation of a zeolite-amended agricultural field

NASA Astrophysics Data System (ADS)

Ferretti, Giacomo; Natali, Claudio; Faccini, Barbara; Di Giuseppe, Dario; Bianchini, Gianluca; Coltorti, Massimo

2016-04-01

In this study, a C and N isotopic investigation in the soil-plant system of the ZeoLIFE project experimental field have been carried out. Since many years, natural and NH4-enriched zeolites have been used as soil amendant in agricultural context in order to reduce N losses, increase NUE (Nitrogen Use Efficiency) and crop yield. Nevertheless up to now there are no studies that, using the stable isotopes approach, highlighted the interaction between zeolites and plants in agricultural systems. The main aims of this study is to verify if natural zeolites amendment can enhance chemical fertilization efficiency and if N transfer from NH4-enriched zeolites to plants really occurs. Plants grown following traditional cultivation methods (with no zeolite addition) and plants grown on soils amended with natural and NH4-enriched zeolites (the latter obtained after mixing with pig-slurry with a very high 15N) were compared for two cultivation cycles (maize and wheat). As widely known, plants grown under conventional farming systems (use of chemical fertilizers as urea) and plants grown under organic farming can be discriminated by the isotopic signatures of plant tissues. For both years the main results of the study reveals that plants grown on plots amended with natural zeolites generally have their nitrogen isotopic signature more similar to that of the chemical fertilizers employed during the cultivation with respect to the plants cultivated in the non-amended plot. This suggests an enhanced N uptake by the plant from this specific N source with respect to the non-amended plot. On the other hand, plants grown on NH4-enriched zeolites registered a higher 15N, approaching the pig-slurry isotopic signature, confirming that this material can constitute an N pool for plants at least for two cultivation cycles. The distinct agricultural practices seem to be reflected in the plant physiology as recorded by the carbon discrimination factor (13C) which generally increases

Preferential flow pathways revealed by field based stable isotope analysis of CO2 by mid-infrared laser spectroscopy

NASA Astrophysics Data System (ADS)

van Geldern, Robert; Nowak, Martin; Zimmer, Martin; Szizybalski, Alexandra; Myrttinen, Anssi; Barth, Johannes A. C.; Jost, Hj

2016-04-01

A newly developed and commercially available isotope ratio laser spectrometer for CO2 analyses has been tested during a 10-day field monitoring campaign at the Ketzin pilot site for CO2 storage in northern Germany. The laser instrument is based on tunable laser direct absorption in the mid-infrared. The instrument recorded a continuous 10-day carbon stable isotope data set with 30 minutes resolution directly on-site in a field-based laboratory container during a tracer experiment. To test the instruments performance and accuracy the monitoring campaign was accompanied by daily CO2 sampling for laboratory analyses with isotope ratio mass spectrometry (IRMS). The carbon stable isotope ratios measured by conventional IRMS technique and by the new mid-infrared laser spectrometer agree remarkably well within 2σ analytical precision (<0.3 ‰). This proves the capability of the new mid-infrared direct absorption technique to measure high precision and accurate real-time table isotope data directly in the field. The injected CO2 tracer had a distinct δ13C value that was largely different from the reservoir background value. The laser spectroscopy data revealed a prior to this study unknown, intensive dynamic with fast changing δ13C values. The arrival pattern of the tracer suggest that the observed fluctuations were probably caused by migration along separate and distinct preferential flow paths between injection well and observation well. The new technique might contribute to a better tracing of the migration of the underground CO2 plume and help to ensure the long-term integrity of the reservoir.

Production waters associated with the Ferron coalbed methane fields, central Utah: Chemical and isotopic composition and volumes

USGS Publications Warehouse

Rice, C.A.

2003-01-01

This study investigated the composition of water co-produced with coalbed methane (CBM) from the Upper Cretaceous Ferron Sandstone Member of the Mancos Shale in east-central Utah to better understand coalbed methane reservoirs. The Ferron coalbed methane play currently has more than 600 wells producing an average of 240 bbl/day/well water. Water samples collected from 28 wellheads in three fields (Buzzards Bench, Drunkards Wash, and Helper State) of the northeast-southwest trending play were analyzed for chemical and stable isotopic composition.Water produced from coalbed methane wells is a Na-Cl-HCO3 type. Water from the Drunkards Wash field has the lowest total dissolved solids (TDS) (6300 mg/l) increasing in value to the southeast and northeast. In the Helper State field, about 6 miles northeast, water has the highest total dissolved solids (43,000 mg/l), and major ion abundance indicates the possible influence of evaporite dissolution or mixing with a saline brine. In the southern Buzzards Bench field, water has variable total dissolved solids that are not correlated with depth or spatial distance. Significant differences in the relative compositions are present between the three fields implying varying origins of solutes and/or different water-rock interactions along multiple flow paths.Stable isotopic values of water from the Ferron range from +0.9??? to -11.4??? ?? 18O and -32??? to -90??? ?? 2H and plot below the global meteoric water line (GMWL) on a line near, but above values of present-day meteoric water. Isotopic values of Ferron water are consistent with modification of meteoric water along a flow path by mixing with an evolved seawater brine and/or interaction with carbonate minerals. Analysis of isotopic values versus chloride (conservative element) and total dissolved solids concentrations indicates that recharge water in the Buzzards Bench area is distinct from recharge water in Drunkards Wash and is about 3 ??C warmer. These variations in

Compound-Specific Carbon and Hydrogen Isotope Analysis - Field Evidence of MTBE Bioremediation

NASA Astrophysics Data System (ADS)

Kuder, T.; Kolhatkar, R. V.; Philp, P.; Wilson, J. T.; Landmeyer, J. E.; Allen, J.

2002-12-01

Compound-specific stable isotope analysis allows opportunity to determine the isotopic ratios of individual contaminants. The technique has been applied to confirm biodegradation in studies of chlorinated solvents and recently BTEX, MTBE and TBA. Chemical reactions (including bio- and inorganic degradation) tend to favor molecules with the lighter isotopic species (e.g., 12C, 1H), resulting with enrichment of the unreacted substrate in the heavier isotopic species (13C, D), referred to as kinetic isotopic fractionation, so that the extent of fractionation may be used as a proxy for biodegradation. Processes such as volatilization, sorption etc., result in minimal degree of fractionation and do not interfere with the isotopic signal due to biodegradation. The results presented here show the first successful applications of compound-specific isotope analysis to understanding MTBE biodegradation in the field, at both aerobic and anaerobic sites. Observed fractionations suggest that two different biodegradation pathways may be involved. At a number of anaerobic locations major fractionation effects were observed for both C and H; enrichment factors Ÿnfor both elements were approaching or exceeding -10. A laboratory microcosm study using an enrichment culture yielded similar results (C data only). A characteristic feature of these sites was the presence of high concentrations of TBA. Conversely, at a number of sites, the C composition remained stable with little fractionation and stayed within the analytical precision range or changed minimally, while H displayed significant fractionation in excess of 60 per mil. Moderate agreement of the data with Rayleigh fractionation model was observed, suggesting that biodegradation effect was distorted by variability at the source or the plume was not homogeneous. The enrichment factor calculated for these data is similar to the one Ÿnpublished for aerobic microcosm of MTBE-degrading culture from Vandenberg AFB by Gray et al

Isotope separation apparatus

DOEpatents

Arnush, Donald; MacKenzie, Kenneth R.; Wuerker, Ralph F.

1980-01-01

Isotope separation apparatus consisting of a plurality of cells disposed adjacent to each other in an evacuated container. A common magnetic field is established extending through all of the cells. A source of energetic electrons at one end of the container generates electrons which pass through the cells along the magnetic field lines. Each cell includes an array of collector plates arranged in parallel or in tandem within a common magnetic field. Sets of collector plates are disposed adjacent to each other in each cell. Means are provided for differentially energizing ions of a desired isotope by applying energy at the cyclotron resonant frequency of the desired isotope. As a result, the energized desired ions are preferentially collected by the collector plates.

Modeling Hf-W Evolution for Earth, Moon and Mars in Grand Tack Accretion Simulations: The Isotopic Consequences of Rapid Accretion

NASA Astrophysics Data System (ADS)

Zube, N.; Nimmo, F.; Jacobson, S. A.; Fischer, R. A.

2017-12-01

Short-lived isotopes, such as the decay of lithophile 182Hf into siderophile 182W with a half-life of 9 My, can provide constraints on the timescales of planetary core formation and accretion. Classical accretion scenarios have produced Hf-W isotopic outcomes like those measured presently on the Earth [2,3]. We examine Grand Tack accretion simulations [4,5] and determine the mantle equilibration conditions necessary to produce the observed tungsten isotopic anomaly. Additionally, we follow Hf-W evolution for pairs of bodies that experience a last giant impact fitting the conditions of Earth's Moon-forming collision. In this way, we determine the likelihood of producing the observed almost indistinguishable W isotope anomalies of the Earth and Moon mantles [6]. We model Hf-W evolution for growing planets in 141 N-body simulations during late accretion in the Grand Tack scenario. For each case, we vary the equilibration factor during collisions—the fraction of impactor core that experiences re-equilibration with the entire target mantle—in steps ranging from none (cores merging) to complete equilibration. For Earth-like and Mars-like surviving planets, we find that cases with a high equilibration factor (k > 0.8) and an intermediate (2:1 - 4:1) ratio of initial embryo mass to planetesimal mass were most frequently able to approximate the observed W measurements for Earth and Mars. The equilibration factor required is more restrictive than the one found for classical accretion scenarios [2,3] and may not be consistent with fluid-dynamical predictions [7]. Moons made of impactor material from Earth's last giant impact are only able to result in an Earth-Moon pair having sufficiently similar W anomalies with a likelihood of 8% or less across all simulations. This indicates that a scenario where the Moon isotopically equilibrated with the Earth's mantle after the impact [8] may be required to explain the measured values. [1] Kleine et al. 2009 [2] Nimmo et al. 2010

The evolution of 13C and 18O isotope composition of DIC in a calcite depositing film of water with isotope exchange between the DIC and a CO2 containing atmosphere, and simultaneous evaporation of the water. Implication to climate proxies from stalagmites: A theoretical model

NASA Astrophysics Data System (ADS)

Dreybrodt, Wolfgang; Romanov, Douchko

2016-12-01

The most widely applied climate proxies in speleothems are the isotope compositions of carbon and oxygen expressed by δ13C and δ18O values. However, mechanisms, which are not related to climate changes, overlay the climate signal. One is the temporal increase of both, δ13C and δ18O values by kinetic processes during precipitation of calcite. Isotope exchange between DIC in the water and the CO2 in the surrounding cave atmosphere can also change isotope composition. Here we present a theoretical model of the temporal isotope evolution of DIC in a thin water layer during precipitation of calcite and simultaneous isotope exchange with the cave atmosphere, and simultaneous evaporation of water. The exchange of oxygen isotopes in the DIC with those in the water is also considered.

From Titan’s tholins to Titan’s aerosols: Isotopic study and chemical evolution at Titan’s surface

NASA Astrophysics Data System (ADS)

Nguyen, Mai-Julie; Raulin, François; Coll, Patrice; Derenne, Sylvie; Szopa, Cyril; Cernogora, Guy; Israël, Guy; Bernard, Jean-Michel

2008-07-01

In the present work, we focused on the possible isotopic fractionation of carbon during the processes involved in the formation of Titan’s tholins. We present the first results obtained on the 12C/13C isotopic ratios measured on Titan’s tholins synthesized in laboratory with cold plasma discharges. Measurements of isotopic ratio 12C/13C, done both on tholins and on the initial gas mixture (N2:CH4 (98:2)) used to produce them, do not show any evident deficit or enrichment in 13C relatively to 12C in the synthesized tholins, compared to the initial gas mixture. This observation allows to go further in the analyses of the ACP experiment data, including part of the Cassini Huygens mission. We also focused on the chemical evolution of the aerosols at Titan surface by studying species coming from acid hydrolysis treatment of Titan’s tholins. Preliminary results show a wide diversity of chemical families, going from carboxylic acids to amino acids. Advanced studies could bring at short-term clues on the still unidentified mixture that induces the decrease of the reflectivity as measure by the DISR instrument [Tomasko, M.G., Archinal, B., Becker, T., Bézard, B., Bushroe, M., Combes, M., Cook, D., Coustenis, A., de Bergh, C., Dafoe, L.E., Doose, L., Douté, S., Eibl, A., Engel, S., Gliem, F., Grieger, B., Holso, K., Howington-Kraus, E., Karkoschka, E., Keller, H.U., Kirk, R., Kramm, R., Küppers, M., Lanagan, P., Lellouch, E., Lemmon, M., Lunine, J., McFarlane, E., Moores, J., Prout, G.M., Rizk, B., Rosiek, M., Rueffer, P., Schröder, S.E., Schmitt, B., See, C., Smith, P., Soderblom, L., Thomas, N., West, R. Rain, winds and haze during the Huygens probe’s descent to Titan’s surface. Nature 438(7069), 765 778, 2005]. At longer-term it could allow to better understand the possible chemical evolution of the Titan’s aerosols after falling down at the surface when brought into contact with water.

Decay properties and reaction dynamics of zirconium isotopes in the relativistic mean-field model

NASA Astrophysics Data System (ADS)

Panigrahi, M.; Panda, R. N.; Kumar, Bharat; Patra, S. K.

In the framework of relativistic mean-field theory, the ground state properties like binding energy, charge radius and quadrupole deformation parameter for various isotopes of zirconium from the valley of stability to drip-line region have been studied. The results are compared with the experimental data and we found reasonable agreement. The calculations are carried out for β-decay energy and β-decay half-life up to the drip-line. Total reaction and elastic differential cross-sections are also studied for few zirconium isotopes as projectiles with 12C as target, using different parameter sets namely NL3*, DD-ME2 and DD-PC1 in conjunction with Glauber model.

Isotopic and trace element compositions of upper mantle and lower crustal xenoliths, Cima volcanic field, California: Implications for evolution of the subcontinental lithospheric mantle

USGS Publications Warehouse

Mukasa, S.B.; Wilshire, H.G.

1997-01-01

Ultramafic and mafic xenoliths from the Cima volcanic field, southern California, provide evidence of episodic modification of the upper mantle and underplating of the crust beneath a portion of the southern Basin and Range province. The upper mantle xenoliths include spinel peridotite and anhydrous and hydrous pyroxenite, some cut by igneous-textured pyroxenite-gabbro veins and dikes and some by veins of amphibole ?? plagioclase. Igneous-textured pyroxenites and gabbros like the dike rocks also occur abundantly as isolated xenoliths inferred to represent underplated crust. Mineral and whole rock trace element compositions among and within the different groups of xenoliths are highly variable, reflecting multiple processes that include magma-mantle wall rock reactions, episodic intrusion and it filtration of basaltic melts of varied sources into the mantle wall rock, and fractionation. Nd, Sr, and Pb isotopic compositions mostly of clinopyroxene and plagioclase mineral separates show distinct differences between mantle xenoliths (??Nd = -5.7 to +3.4; 87Sr/86Sr = 0.7051 - 0.7073; 206Pb/204Pb = 19.045 - 19.195) and the igneous-textured xenoliths (??Nd = +7.7 to +11.7; 87Sr/86Sr = 0.7027 - 0.7036 with one carbonate-affected outlier at 0.7054; and 206Pb/204Pb = 18.751 - 19.068), so that they cannot be related. The igneous-textured pyroxenites and gabbros are similar in their isotopic compositions to the host basaltic rocks, which have ??Nd of+5.1 to +9.3; 87Sr/86Sr of 0.7028 - 0.7050, and 206Pb/204Pb of 18.685 - 21.050. The igneous-textured pyroxenites and gabbros are therefore inferred to be related to the host rocks as earlier cogenetic intrusions in the mantle and in the lower crust. Two samples of peridotite, one modally metasomatized by amphibole and the other by plagioclase, have isotopic compositions intermediate between the igneous-textured xenoliths and the mantle rock, suggesting mixing, but also derivation of the metasomatizing magmas from two separate and

Isotopic homogeneity of iron in the early solar nebula.

PubMed

Zhu, X K; Guo, Y; O'Nions, R K; Young, E D; Ash, R D

2001-07-19

The chemical and isotopic homogeneity of the early solar nebula, and the processes producing fractionation during its evolution, are central issues of cosmochemistry. Studies of the relative abundance variations of three or more isotopes of an element can in principle determine if the initial reservoir of material was a homogeneous mixture or if it contained several distinct sources of precursor material. For example, widespread anomalies observed in the oxygen isotopes of meteorites have been interpreted as resulting from the mixing of a solid phase that was enriched in 16O with a gas phase in which 16O was depleted, or as an isotopic 'memory' of Galactic evolution. In either case, these anomalies are regarded as strong evidence that the early solar nebula was not initially homogeneous. Here we present measurements of the relative abundances of three iron isotopes in meteoritic and terrestrial samples. We show that significant variations of iron isotopes exist in both terrestrial and extraterrestrial materials. But when plotted in a three-isotope diagram, all of the data for these Solar System materials fall on a single mass-fractionation line, showing that homogenization of iron isotopes occurred in the solar nebula before both planetesimal accretion and chondrule formation.

Modelling the isotopic evolution of the Earth.

PubMed

Paul, Debajyoti; White, William M; Turcotte, Donald L

2002-11-15

We present a flexible multi-reservoir (primitive lower mantle, depleted upper mantle, upper continental crust, lower continental crust and atmosphere) forward-transport model of the Earth, incorporating the Sm-Nd, Rb-Sr, U-Th-Pb-He and K-Ar isotope-decay systematics. Mathematically, the model consists of a series of differential equations, describing the changing abundance of each nuclide in each reservoir, which are solved repeatedly over the history of the Earth. Fluxes between reservoirs are keyed to heat production and further constrained by estimates of present-day fluxes (e.g. subduction, plume flux) and current sizes of reservoirs. Elemental transport is tied to these fluxes through 'enrichment factors', which allow for fractionation between species. A principal goal of the model is to reproduce the Pb-isotope systematics of the depleted upper mantle, which has not been done in earlier models. At present, the depleted upper mantle has low (238)U/(204)Pb (mu) and (232)Th/(238)U (kappa) ratios, but Pb-isotope ratios reflect high time-integrated values of these ratios. These features are reproduced in the model and are a consequence of preferential subduction of U and of radiogenic Pb from the upper continental crust into the depleted upper mantle. At the same time, the model reproduces the observed Sr-, Nd-, Ar- and He-isotope ratios of the atmosphere, continental crust and mantle. We show that both steady-state and time-variant concentrations of incompatible-element concentrations and ratios in the continental crust and upper mantle are possible. Indeed, in some cases, incompatible-element concentrations and ratios increase with time in the depleted mantle. Hence, assumptions of a progressively depleting or steady-state upper mantle are not justified. A ubiquitous feature of this model, as well as other evolutionary models, is early rapid depletion of the upper mantle in highly incompatible elements; hence, a near-chondritic Th/U ratio in the upper mantle

Carbon Retention and Isotopic Evolution in Deeply Subducted Sediments: Evidence from the Italian Alps

NASA Astrophysics Data System (ADS)

Cook-Kollars, J.; Bebout, G. E.; Agard, P.; Angiboust, S.

2012-12-01

increasing grade, metapelitic carbonaceous matter shows an increase in δ13CVPDB, ranging from about -25‰ in low-grade Schistes Lustres samples to -16‰ in the highest-grade Cignana samples. Carbonate in the entire suite shows decrease in δ18OSMOW, from marine carbonate values > 25‰ to values of 17-22‰ independent of the carbonate content of the rocks. This shift could possibly be explained by isotopic exchange with silicate phases in the same rocks [Henry et al. (1996), Chem. Geol.]. Metapelitic rocks in this suite experienced moderate amounts of dehydration (20-50%) largely related to breakdown of chlorite and carpholite [Bebout et al. (in press), Chem. Geol. (abstract in this session); Angiboust and Agard (2010), Lithos], conceivably providing a source for infiltrating H2O-rich fluids producing negative shifts in calcite δ18O in interlayered metacarbonates. These results indicate that relatively little decarbonation occurred in carbonate-bearing sediments subducted to depths greater than 100 km, arguing against any model of extensive decarbonation driven by infiltration of the sediments by H2O-rich fluids released from mafic and ultramafic parts of the underlying subducting slab. This study provides field evidence for the efficient retention of C in subducting shale-carbonate sequences through forearc depths, potentially affecting the C budget and isotopic evolution of the deeper mantle.

Isotopic Analysis and Evolved Gases

NASA Technical Reports Server (NTRS)

Swindle, Timothy D.; Boynton, William V.; Chutjian, Ara; Hoffman, John H.; Jordan, Jim L.; Kargel, Jeffrey S.; McEntire, Richard W.; Nyquist, Larry

1996-01-01

Precise measurements of the chemical, elemental, and isotopic composition of planetary surface material and gases, and observed variations in these compositions, can contribute significantly to our knowledge of the source(s), ages, and evolution of solar system materials. The analyses discussed in this paper are mostly made by mass spectrometers or some other type of mass analyzer, and address three broad areas of interest: (1) atmospheric composition - isotopic, elemental, and molecular, (2) gases evolved from solids, and (3) solids. Current isotopic data on nine elements, mostly from in situ analysis, but also from meteorites and telescopic observations are summarized. Potential instruments for isotopic analysis of lunar, Martian, Venusian, Mercury, and Pluto surfaces, along with asteroid, cometary and icy satellites, surfaces are discussed.

Unraveling the Complexity of the Evolution of the Sun's Photospheric Magnetic Field

NASA Astrophysics Data System (ADS)

Hathaway, David H.

2016-10-01

Given the emergence of tilted, bipolar active regions, surface flux transport has been shown to reproduce much of the complex evolution of the Sun's photospheric magnetic field. Surface flux is transported by flows in the surface shear layer - the axisymmetric differential rotation and meridional flow and the non-axisymmetric convective motions (granules, supergranules, and giant cells). We have measured these flows by correlation tracking of the magnetic elements themselves, correlation tracking of the Doppler features (supergranules), and by direct Doppler measurements using SDO/HMI data. These measurements fully constrain (with no free parameters) the flows used in our surface flux transport code - the Advective Flux Transport or AFT code. Here we show the up-to-date evolution of these flows, their impact on the detailed evolution of the Sun's photospheric magnetic field, and predictions for what the polar fields will be at the next minimum in 2020.

Lower crustal mush generation and evolution

NASA Astrophysics Data System (ADS)

Karakas, Ozge; Bachmann, Olivier; Dufek, Josef; Wright, Heather; Mangan, Margaret

2016-04-01

Recent seismic, field, and petrologic studies on several active and fossil volcanic settings provide important constraints on the time, volume, and melt fraction of their lower crustal magma bodies. However, these studies provide an incomplete picture of the time and length scales involved during their thermal and compositional evolution. What has been lacking is a thermal model that explains the temporal evolution and state of the lower crustal magma bodies during their growth. Here we use a two-dimensional thermal model and quantify the time and length scales involved in the long-term thermal and compositional evolution of the lower crustal mush regions underlying the Salton Sea Geothermal Field (USA), Mt St Helens (USA), and the Ivrea-Verbano Zone (North Italy). Although a number of seismic, tectonic, petrologic, and field studies explained the tectonic and magmatic evolution of these regions, controversy remains on their lower crustal heat sources, melt fraction, and origin of erupted magmas. Our thermal modeling results suggest that given a geologically reasonable range of basalt fluxes (~10^-3 to 10^-4 km3/yr), a long-lived (>105 yr) crystalline mush is formed in the lower crust. The state of the lower crustal mush is strongly influenced by the magma flux, crustal thickness, and water content of intruded basalt, giving an average melt fraction of <0.2 in thin crust with dry injections (Salton Sea Geothermal Field) and up to 0.4-0.5 in thicker crust with wet injections (Mt St Helens and Ivrea Zone). The melt in the lower crustal mush is mainly evolving through fractional crystallization of basalt with minor crustal assimilation in all regions, in agreement with isotopic studies. Quantification of the lower crustal mush regions is key to understanding the mass and heat balance in the crust, evolution of magma plumbing systems, and geothermal energy exploration.

Nutrient Concentrations and Stable Isotopes of Runoff from a Midwest Tile-Drained Corn Field

NASA Astrophysics Data System (ADS)

Wilkins, B. P.; Woo, D.; Li, J.; Michalski, G. M.; Kumar, P.; Conroy, J. L.; Keefer, D. A.; Keefer, L. L.; Hodson, T. O.

2017-12-01

Tile drains are a common crop drainage device used in Midwest agroecosystems. While efficient at drainage, the tiles provide a quick path for nutrient runoff, reducing the time available for microbes to use nutrients (e.g., NO3- and PO43-) and reduce export to riverine systems. Thus, understanding the effects of tile drains on nutrient runoff is critical to achieve nutrient reduction goals. Here we present isotopic and concentration data collected from tile drain runoff of a corn field located near Monticello, IL. Tile flow samples were measured for anion concentrations and stable isotopes of H2O and NO3-, while precipitation was measured for dual isotopes of H2O. Results demonstrate early tile flow from rain events have a low Cl- concentration (<20ppm) with water isotopic values reflecting precipitation, indicating preferential flow (>60% contribution) in the beginning of the hydrograph. As flow continues H2O isotopic values reflect pre-event water (ground and soil water), and Cl- concentrations increase representing a greater influence by matrix flow (60-90% contribution). Nitrate concentrations change dramatically, especially during the growing season, and do not follow a similar trend as the conservative Cl-, often decreasing days before, which represents missing nitrate in the upper surface portion of the soil. Nitrate isotopic data shows significant changes in 15N (4‰) and 18O (4‰) during individual hydrological events, representing that in addition to plant uptake and leaching, considerate NO3- is lost through denitrification. It is notable, that throughout the season d15N and d18O of nitrate change significantly representing that seasonally, substantial denitrification occurs.

Lithospheric evolution of the Northern Arabian Shield: Chemical and isotopic evidence from basalts, xenoliths and granites

NASA Technical Reports Server (NTRS)

Stein, M.

1988-01-01

The evolution of the upper-mantle and the lower-crust (the conteinental lithosphere), is the area of Israel and Sinai was studied, using the chemical composition and the Nd-Sr isotopic systematics from mantle and crustal nodules, their host basalts, and granites. The magmatism and the metasomatism making the lithosphere are related to uprise of mantle diapirs in the uppermost mantle of the area. These diapirs heated the base of the lithosphere, eroded, and replaced it with new hot material. It caused a domal uplift of the lithosphere (and the crust). The doming resulted in tensional stresses that in turn might develop transport channels for the basalt.

Variation in the terrestrial isotopic composition and atomic weight of argon

USGS Publications Warehouse

Böhlke, John Karl

2014-01-01

The isotopic composition and atomic weight of argon (Ar) are variable in terrestrial materials. Those variations are a source of uncertainty in the assignment of standard properties for Ar, but they provide useful information in many areas of science. Variations in the stable isotopic composition and atomic weight of Ar are caused by several different processes, including (1) isotope production from other elements by radioactive decay (radiogenic isotopes) or other nuclear transformations (e.g., nucleogenic isotopes), and (2) isotopic fractionation by physical-chemical processes such as diffusion or phase equilibria. Physical-chemical processes cause correlated mass-dependent variations in the Ar isotope-amount ratios (40Ar/36Ar, 38Ar/36Ar), whereas nuclear transformation processes cause non-mass-dependent variations. While atmospheric Ar can serve as an abundant and homogeneous isotopic reference, deviations from the atmospheric isotopic ratios in other Ar occurrences limit the precision with which a standard atomic weight can be given for Ar. Published data indicate variation of Ar atomic weights in normal terrestrial materials between about 39.7931 and 39.9624. The upper bound of this interval is given by the atomic mass of 40Ar, as some samples contain almost pure radiogenic 40Ar. The lower bound is derived from analyses of pitchblende (uranium mineral) containing large amounts of nucleogenic 36Ar and 38Ar. Within this interval, measurements of different isotope ratios (40Ar/36Ar or 38Ar/36Ar) at various levels of precision are widely used for studies in geochronology, water–rock interaction, atmospheric evolution, and other fields.

Phylomemetic patterns in science evolution--the rise and fall of scientific fields.

PubMed

Chavalarias, David; Cointet, Jean-Philippe

2013-01-01

We introduce an automated method for the bottom-up reconstruction of the cognitive evolution of science, based on big-data issued from digital libraries, and modeled as lineage relationships between scientific fields. We refer to these dynamic structures as phylomemetic networks or phylomemies, by analogy with biological evolution; and we show that they exhibit strong regularities, with clearly identifiable phylomemetic patterns. Some structural properties of the scientific fields - in particular their density -, which are defined independently of the phylomemy reconstruction, are clearly correlated with their status and their fate in the phylomemy (like their age or their short term survival). Within the framework of a quantitative epistemology, this approach raises the question of predictibility for science evolution, and sketches a prototypical life cycle of the scientific fields: an increase of their cohesion after their emergence, the renewal of their conceptual background through branching or merging events, before decaying when their density is getting too low.

Isotopic and paleomagnetic constraints on the Mesozoic tectonic evolution of south China

NASA Astrophysics Data System (ADS)

Gilder, Stuart A.; Gill, James; Coe, Robert S.; Zhao, Xixi; Liu, Zhongwei; Wang, Genxian; Yuan, Kuirong; Liu, Wenlong; Kuang, Guodun; Wu, Haoruo

1996-07-01

In order to better constrain the paleogeographic evolution of south China we measured Sm-Nd and Rb-Sr isotopic compositions for 23 Mesozoic granites that crop out throughout the area. Tightly grouped neodymium depleted mantle model ages (1.4 ± 0.3 Ga) suggest the region is underlain by relatively homogeneous Proterozoic crust and fail to define crustal provinces. Neither the isotopic nor geologic data suggest that a Mesozoic suture exists. However, granites possessing anomalously high Sm (>8 ppm) and Nd (>45 ppm) concentrations, relatively high initial epsilon neodymium (-4 to -8), and high but variable initial 87Sr/86Sr (0.759 to 0.713) form a northeast trending zone that coincides with two prominent Mesozoic basins. Southeast of the zone lie the majority of Mesozoic intrusives and Upper Triassic to Lower Cretaceous extensional basins found in south China. Mesozoic paleomagnetic poles are well clustered northwest of the zone. Pre-Cretaceous poles southeast of it are discordant with respect to those from the northwest. The only recognized tectonostratigraphic terrane in south China lies southeast of the zone. The terrane is bordered by a northeast trending sinistral fault that was active in the Mesozoic. Other faults in south China have similar attitudes, ages, and sense of shear. Together, the observations suggest that the Mesozoic tectonic regime in south China consisted of strike-slip activity plus concomitant rifting as terranes or fragments of similar crust were transported north along sinistral faults. The zone, defined by the granites enriched in Nd and Sm, demarcates displaced terranes to the southeast from relatively stable land to the northwest.

Can the evolution of nitrogen cycle be traced by the N isotopic composition in mica?

NASA Astrophysics Data System (ADS)

Pinti, D. L.; Hashizume, K.

2011-12-01

A significant portion of nitrogen present in sedimentary rocks has a biological origin, trapped either in organic form, or as ammonium ion substituting potassium in mica. Mica might preserve biological N isotopic signatures (δ15N) in the geological record, allowing the evolution of the N cycle to be traced. However, diagenetic or metamorphic events can modify the pristine N isotopic signature leading to inaccurate interpretations. For example, devolatilization of the rock leads to a reduction in the N abundance and a contemporary increase of the δ15N because 14N escapes faster than 15N. We measured N isotopic compositions in whole rock, mica and feldspars separates from two Archean suites of cherts: 3.5 Ga Kitty's Gap and North Pole sequences in Pilbara, Western Australia and from the 3.45 Ga Hooggenoeg Fm, Barberton Greenstone Belt, South Africa. N was compared with the argon elemental and isotopic composition, because a relation between NH4+, which replaces K+ and radiogenic 40Ar*, which is produced by electron capture of K+ is expected. Both Pilbara and Barberton cherts show a clear correlation between N and 40Ar*, confirming the occurrence of a common speciation. K-Ar dating of the Hooggenoeg Formation mica and feldspars give ages of 2.1 and 1.1 Ga, respectively, indicating that loosely-bounded noble gas 40Ar* is lost from the host mineral during known metamorphic events. Observed correlations between 40Ar* and N suggests that nitrogen, although more strongly bounded as ammonium is also lost, possibly leading to isotopic fractionation. Measured δ15N values, however, are relatively constant (+8.1±0.6% for whole rock and +10.9±1.2% for mica) and do not display an inverse correlation with N abundances. This suggests either 1) that isotopic fractionation is not produced during N loss or; 2) that a process other than devolatilization fractionate N isotopes. Measured δ15N values are at levels far greater than those expected for Early Archean kerogens (0±2

Formation waters from Mississippian-Pennsylvanian reservoirs, Illinois basin, USA: Chemical and isotopic constraints on evolution and migration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stueber, A.M.; Walter, L.M.; Huston, T.J.

1993-02-01

We have analyzed a suite of seventy-four formation-water samples from Mississippian and Pennsylvanian carbonate and siliciclastic strata in the Illinois basin for major, minor, and trace element concentrations and for strontium isotopic composition. A subset of these samples was also analyzed for boron isotopic composition. Data are used to interpret origin of salinity and chemical and Sr isotopic evolution of the brines and in comparison with a similar data set from an earlier study of basin formation waters from Silurian-Devonian reservoirs. Systematics of Cl-Br-Na show that present Mississippian-Pennsylvanian brine salinity can be explained by a combination of subaerial seawater evaporationmore » short of halite saturation and subsurface dissolution of halite from an evaporite zone in the middle Mississippian St. Louis Limestone, along with extensive dilution by mixing with meteoric waters. Additional diagenetic modifications in the subsurface interpreted from cation/Br ratios include K depletion through interaction with clay minerals, Ca enrichment, and Mg depletion by dolomitization, and Sr enrichment through CaCO[sub 3] recrystallization and dolomitization. Ste. Genevieve Limestone (middle Mississippian) formation waters show [sup 87]Sr/[sup 86]Sr ratios in the range 0.70782-0.70900, whereas waters from the siliciclastic reservoirs are in the rante 0.70900-0.71052. Inverse correlations between [sup 87]Sr/[sup 86]Sr and B,Li, and Mg concentrations suggest that the brines acquired radiogenic [sup 87]Sr through interaction with siliciclastic minerals. Completely unsystematic relations between [sup 87]Fr/[sup 86]Sr and 1/Sr are observed; Sr concentrations in Ste. Genevieve and Aux Vases (middle Mississippian) waters appear to be buffered by equilibrium with respect to SrSo[sub 4]. These formation waters are distinguished from Silurian-Devonian brines in the basin by elevated Cl/Br and Na/Br ratios and by unsystematic Sr isotope relationships.« less

Isotopic Evidence for Platform Exposure and Diagenesis in the Miocene: Implications for South-East Asian Platform Evolution.

NASA Astrophysics Data System (ADS)

Prince, K.; Laya, J. C.; Betzler, C.; Eberli, G. P.; Zarikian, C.; Swart, P. K.; Blättler, C. L.; Reolid, J.; Reijmer, J.

2017-12-01

The Maldives record nearly continuous carbonate deposition from the Eocene to the Holocene, and its stable tectonic regime and lack of clastic input make it an ideal example for understanding the depositional and diagenetic dynamics of isolated carbonate platforms. The Kardiva platform ultimately drowned, but the amplitude and frequency of sea-level changes in the Miocene make it likely that subaerial exposure occurred during its evolution. Abundant moldic porosity has been interpreted as meteoric diagenesis, but stable isotope evidence to support this has not been reported. Using bulk stable isotope analyses and petrographic methods, we sought to identify evidence of meteoric diagenesis by investigating the variations in grains, cements, porosity, δ13C, and δ18O at IODP Sites U1645, U1469, and U1470. Within the platform, grain distribution is variable with algae, benthic foraminifera, and corals representing the most abundant grain types. Cement abundance generally increases while porosity decreases with depth, with some variability. δ18O and δ13C range from -7.0‰ to 3.2‰ and -7‰ to 2.5‰, respectively. Petrography and isotope values show evidence for subaerial exposure and alteration by meteoric fluids, with a cross-plot of δ13C and δ18O showing the characteristic inverted "J" trend associated with dissolution and precipitation reactions mediated by meteoric fluids, resulting in more negative values. These results are compared to isotopic values for unaltered red algae and corals to account for the possibility of vital effects, but vital effects alone do not yield such low values. This evidence for meteoric diagenesis of the Kardiva Platform indicates variation between wet and dry periods, and also potential high-amplitude sea-level fluctuations during the Miocene in the Indo-Pacific region.

ISOTOPE SEPARATORS

DOEpatents

Bacon, C.G.

1958-08-26

An improvement is presented in the structure of an isotope separation apparatus and, in particular, is concerned with a magnetically operated shutter associated with a window which is provided for the purpose of enabling the operator to view the processes going on within the interior of the apparatus. The shutier is mounted to close under the force of gravity in the absence of any other force. By closing an electrical circuit to a coil mouated on the shutter the magnetic field of the isotope separating apparatus coacts with the magnetic field of the coil to force the shutter to the open position.

The evolution of CNO isotopes: a new window on cosmic star formation history and the stellar IMF in the age of ALMA

NASA Astrophysics Data System (ADS)

Romano, D.; Matteucci, F.; Zhang, Z.-Y.; Papadopoulos, P. P.; Ivison, R. J.

2017-09-01

We use state-of-the-art chemical models to track the cosmic evolution of the CNO isotopes in the interstellar medium of galaxies, yielding powerful constraints on their stellar initial mass function (IMF). We re-assess the relative roles of massive stars, asymptotic giant branch (AGB) stars and novae in the production of rare isotopes such as 13C, 15N, 17O and 18O, along with 12C, 14N and 16O. The CNO isotope yields of super-AGB stars, novae and fast-rotating massive stars are included. Having reproduced the available isotope enrichment data in the solar neighbourhood, and across the Galaxy, and having assessed the sensitivity of our models to the remaining uncertainties, e.g. nova yields and star formation history, we show that we can meaningfully constrain the stellar IMF in galaxies using C, O and N isotope abundance ratios. In starburst galaxies, where data for multiple isotopologue lines are available, we find compelling new evidence for a top-heavy stellar IMF, with profound implications for their star formation rates and efficiencies, perhaps also their stellar masses. Neither chemical fractionation nor selective photodissociation can significantly perturb globally averaged isotopologue abundance ratios away from the corresponding isotope ones, as both these processes will typically affect only small mass fractions of molecular clouds in galaxies. Thus, the Atacama Large Millimeter Array now stands ready to probe the stellar IMF, and even the ages of specific starburst events in star-forming galaxies across cosmic time unaffected by the dust obscuration effects that plague optical/near-infrared studies.

Timescales for the evolution of oxygen isotope compositions in the solar nebula

NASA Astrophysics Data System (ADS)

Lyons, J. R.; Bergin, E. A.; Ciesla, F. J.; Davis, A. M.; Desch, S. J.; Hashizume, K.; Lee, J.-E.

2009-09-01

We review two models for the origin of the calcium-, aluminum-rich inclusion (CAI) oxygen isotope mixing line in the solar nebula: (1) CO self-shielding, and (2) chemical mass-independent fractionation (MIF). We consider the timescales associated with formation of an isotopically anomalous water reservoir derived from CO self-shielding, and also the vertical and radial transport timescales of gas and solids in the nebula. The timescales for chemical MIF are very rapid. CO self-shielding models predict that the Sun has Δ 17O SMOW ˜ -20‰ (Clayton, 2002), and chemical mass-independent fractionation models predict Δ 17O SMOW ˜0‰. Preliminary Genesis results have been reported by McKeegan et al. (McKeegan K. D., Coath C. D., Heber, V., Jarzebinski G., Kallio A. P., Kunihiro T., Mao P. H. and Burnett D. S. (2008b) The oxygen isotopic composition of captured solar wind: first results from the Genesis. EOS Trans. AGU 89(53), Fall Meet. Suppl., P42A-07 (abstr)) and yield a Δ 17O SMOW of ˜ -25‰, consistent with a CO self-shielding scenario. Assuming that subsequent Genesis analyses support the preliminary results, it then remains to determine the relative contributions of CO self-shielding from the X-point, the surface of the solar nebula and the parent molecular cloud. The relative formation ages of chondritic components can be related to several timescales in the self-shielding theories. Most importantly the age difference of ˜1-3 My between CAIs and chondrules is consistent with radial transport from the outer solar nebula (>10 AU) to the meteorite-forming region, which supports both the nebular surface and parent cloud self-shielding scenarios. An elevated radiation field intensity is predicted by the surface shielding model, and yields substantial CO photolysis (˜50%) on timescales of 0.1-1 My. An elevated radiation field is also consistent with the parent cloud model. The elevated radiation intensities may indicate solar nebula birth in a medium to large

Evolution of Palaeoproterozoic mafic intrusions located within the thermal aureole of the Sudbury Igneous Complex, Canada: Isotopic, geochronological and geochemical evidence

NASA Astrophysics Data System (ADS)

Prevec, Stephen A.; Baadsgaard, Halfdan

2005-07-01

Impact cratering and their resultant geological phenomena are recognised as significant factors in the lithological and biologic evolution of the earth. Age-dating of impact events is critical in correlating cause and effects for these catastrophic processes. The Falconbridge and Drury Township (Twp) intrusions were emplaced at the contact between Neoarchaean basement and Palaeoproterozoic volcanosedimentary rocks, and also lie at the southeast and southwest edges of the Sudbury Igneous Complex (SIC), within its thermal contact aureole. The Falconbridge Twp intrusion is dated at 2441 ± 3 Ma by U-Pb zircon, with evidence of Archaean inheritance from its host granitoids. Granitoids from the southernmost Abitibi Subprovince are dated here between 2670 ± 11 Ma for an undeformed Algoman granite, and 2696 ± 18 Ma for a foliated granitoid, consistent with existing data from the Abitibi Greenstone Belt and from the Wawa Subprovince. Major and trace element geochemical evidence, common-Pb isotopic compositions, and ɛNd2440 values between 0 and -1 are all consistent with a Palaeoproterozoic origin for the Falconbridge Twp intrusion, and support inclusion in the East Bull Lake-type suite of leucogabbroic plutons and sills. In contrast, the Drury Twp intrusion gives a U-Pb zircon age of 1859 ± 13 Ma, coincident with the date of SIC-emplacement. While the major and trace element compositions are comparable to the Falconbridge data, the Drury displays significant heterogeneity in ɛNd2440, with values ranging from +3.7 to -0.1, and contains more radiogenic Pb isotopic compositions. Field, geochemical and isotopic evidence clearly distinguishes this intrusion from constituents of the SIC itself, and indicates that the Drury too is a Palaeoproterozoic intrusion. This requires that apparently unshocked, undeformed magmatic-looking zircon has been grown or reset in a postmagmatic setting. This has significant implications for the identification of mantle-derived magmas and

Stable isotope probing in the metagenomics era: a bridge towards improved bioremediation

PubMed Central

Uhlik, Ondrej; Leewis, Mary-Cathrine; Strejcek, Michal; Musilova, Lucie; Mackova, Martina; Leigh, Mary Beth; Macek, Tomas

2012-01-01

Microbial biodegradation and biotransformation reactions are essential to most bioremediation processes, yet the specific organisms, genes, and mechanisms involved are often not well understood. Stable isotope probing (SIP) enables researchers to directly link microbial metabolic capability to phylogenetic and metagenomic information within a community context by tracking isotopically labeled substances into phylogenetically and functionally informative biomarkers. SIP is thus applicable as a tool for the identification of active members of the microbial community and associated genes integral to the community functional potential, such as biodegradative processes. The rapid evolution of SIP over the last decade and integration with metagenomics provides researchers with a much deeper insight into potential biodegradative genes, processes, and applications, thereby enabling an improved mechanistic understanding that can facilitate advances in the field of bioremediation. PMID:23022353

Nonequilibrium evolution of scalar fields in FRW cosmologies

NASA Astrophysics Data System (ADS)

Boyanovsky, D.; de Vega, H. J.; Holman, R.

1994-03-01

We derive the effective equations for the out of equilibrium time evolution of the order parameter and the fluctuations of a scalar field theory in spatially flat FRW cosmologies. The calculation is performed both to one loop and in a nonperturbative, self-consistent Hartree approximation. The method consists of evolving an initial functional thermal density matrix in time and is suitable for studying phase transitions out of equilibrium. The renormalization aspects are studied in detail and we find that the counterterms depend on the initial state. We investigate the high temperature expansion and show that it breaks down at long times. We also obtain the time evolution of the initial Boltzmann distribution functions, and argue that to one-loop order or in the Hartree approximation the time evolved state is a ``squeezed'' state. We illustrate the departure from thermal equilibrium by numerically studying the case of a free massive scalar field in de Sitter and radiation-dominated cosmologies. It is found that a suitably defined nonequilibrium entropy per mode increases linearly with comoving time in a de Sitter cosmology, whereas it is not a monotonically increasing function in the radiation-dominated case.

Shape evolution for neutron-deficient bismuth isotopes studied by resonance laser ionization spectroscopy

NASA Astrophysics Data System (ADS)

Molkanov, P. L.; Barzakh, A. E.; Fedorov, D. V.; Ivanov, V. S.; Moroz, F. V.; Orlov, S. Yu.; Panteleev, V. N.; Seliverstov, M. D.; Volkov, Yu. M.

2017-11-01

In-source laser spectroscopy experiments for bismuth isotopes at the 306.77 nm atomic transition has been carried out at the IRIS (Investigation of Radioactive Isotopes at Synchrocyclotron) facility of Petersburg Nuclear Physics Institute. New data on isotope shifts for 189-198,211Bi isotopes and isomers have been obtained. The changes in the mean-square charge radii were deduced. The large isomer shift has been observed for the intruder isomer states of Bi with spin I = 1/2 ( A = 193, 195, 197). This testifies to the shape coexistence in these nuclei with the intruder isomer states more deformed than the ground states. Marked deviation from the nearly spherical behavior for ground states of the even-neutron Bi isotopes at N < 109 is demonstrated, in contrast to the Pb and Tl isotopic chains.

Isotopic Evolution of Soil Organic Matter Affects Paleo-vegetation and Paleo-pCO2 Reconstructions

NASA Astrophysics Data System (ADS)

Bowen, G. J.; Beerling, D. J.

2004-12-01

The stable carbon isotope ratio (\\delta13C) of fossil terrestrial organic matter is used to study several aspects of biosphere/atmosphere coupling in the geologic past. These range from vegetation response to climatic and pCO2 shifts to reconstruction of paleo-pCO2 levels. Although screening for diagenesis is typical in these studies, few have taken into account the ubiquitous but poorly understood phenomenon of progressive 13C-enrichment of soil organic matter during its decay, which is observed in modern soils worldwide. We present a simple model that describes this phenomenon and the interaction of soil organic carbon and CO2 concentrations, fluxes and \\delta13C values. At its most basic level, the model suggests that bulk organic matter from sub-surface soil horizons will be variably enriched in 13C relative to the vegetation living on the soil surface. This complicates interpretation of paleo-isotopic records used in C3/C4 vegetation reconstructions, and may account for anomalously heavy fossil organic carbon isotope values measured in some paleosols pre-dating the end-Miocene expansion of C4 floras. The model also demonstrates that the \\delta13C evolution of soil organic carbon during its decay generates 2 types of biases that may affect soil mineral paleo-pCO2 proxies. The first type of bias results from a steady-state inequality between the \\delta13C of organic carbon at a single depth within the soil and that of respired CO2 in the soil. This bias is present when fossil organic matter is used to reconstruct the \\delta13C of soil-respired carbon, and can be minimized with appropriate sampling methods. The second type of bias results from a dynamic, seasonal imbalance in respiration, which may cause the soil \\delta13CO2 flux during times of soil mineral formation to deviate from that of the annually integrated flux. At present, this bias can not be fully described or corrected for due to inadequacies in our knowledge of soil \\delta13C dynamics and the

The evolution of the North Atlantic Oscillation for the last 700 years inferred from D/H isotopes in the sedimentary record of Lake Azul (Azores archipelago, Portugal).

NASA Astrophysics Data System (ADS)

Rubio de Ingles, Maria Jesus; Shanahan, Timothy M.; Sáez, Alberto; José Pueyo, Juan; Raposeiro, Pedro M.; Gonçalves, Vitor M.; Hernández, Armand; Trigo, Ricardo; Sánchez López, Guiomar; Francus, Pierre; Giralt, Santiago

2015-04-01

The δD plant leaf wax variations provide insights on precipitation and evaporation evolution through time. This proxy has been used to reconstruct the temporal evolution of the North Atlantic Oscillation (NAO) climate mode since this mode rules most of the climate variability in the central North Atlantic area. A total lipid extraction preparation and the correspondent analyses in the IRMS have been done for 100 samples from the uppermost 1.5 m of the sedimentary infill of Lake Azul (Azores archipelago, Portugal). According to the chronological model, established by 210Pb profile and 4 AMS 14C dates, this record contains the environmental history of the last 730 years. The reconstructed precipitation variations obtained from D/H isotope values, suggest that this area has suffered significant changes in its distribution and intensity rainfall patterns through time. The end of the Medieval Climate Anomaly (MCA, 1100- 1300 AD) is characterized by a progressive enrichmentof D/H isotope values which meant decreasing arid conditions. These rainfalls' increase might be interpreted by a shift from positive to negative dominance of the NAO. The Little Ice Age (LIA, 1300 - 1850 AD) was characterized by two humid periods (1300- 1550 AD and 1650 - 1850 AD) separated by a relatively dry period. These precipitation oscillations are clearly visible by marked changes in the D/H isotope values. The LIA was followed by the persistence of the positive NAO mode, exhibited by the depletion of the D/H isotope signal, which indicated an overall decrease of the precipitation in the central North Atlantic area. Surprisingly, the D/H of the last 100 years, characterized by the present global warming and a persistent positive NAO mode, display large fluctuations most possibly linked to an enhancement of the storminess which is in concordance with the data fluctuations observed in the instrumental record for the last 80 years in the archipelago. This climatic evolution is in accordance with

Simulation of dual carbon-bromine stable isotope fractionation during 1,2-dibromoethane degradation.

PubMed

Jin, Biao; Nijenhuis, Ivonne; Rolle, Massimo

2018-06-01

We performed a model-based investigation to simultaneously predict the evolution of concentration, as well as stable carbon and bromine isotope fractionation during 1,2-dibromoethane (EDB, ethylene dibromide) transformation in a closed system. The modelling approach considers bond-cleavage mechanisms during different reactions and allows evaluating dual carbon-bromine isotopic signals for chemical and biotic reactions, including aerobic and anaerobic biological transformation, dibromoelimination by Zn(0) and alkaline hydrolysis. The proposed model allowed us to accurately simulate the evolution of concentrations and isotope data observed in a previous laboratory study and to successfully identify different reaction pathways. Furthermore, we illustrated the model capabilities in degradation scenarios involving complex reaction systems. Specifically, we examined (i) the case of sequential multistep transformation of EDB and the isotopic evolution of the parent compound, the intermediate and the reaction product and (ii) the case of parallel competing abiotic pathways of EDB transformation in alkaline solution.

Use of radium isotopes to determine the age and origin of radioactive barite at oil-field production sites

USGS Publications Warehouse

Zielinski, R.A.; Otton, J.K.; Budahn, J.R.

2001-01-01

Radium-bearing barite (radiobarite) is a common constituent of scale and sludge deposits that form in oil-field production equipment. The barite forms as a precipitate from radium-bearing, saline formation water that is pumped to the surface along with oil. Radioactivity levels in some oil-field equipment and in soils contaminated by scale and sludge can be sufficiently high to pose a potential health threat. Accurate determinations of radium isotopes (226Ra+228Ra) in soils are required to establish the level of soil contamination and the volume of soil that may exceed regulatory limits for total radium content. In this study the radium isotopic data are used to provide estimates of the age of formation of the radiobarite contaminant. Age estimates require that highly insoluble radiobarite approximates a chemically closed system from the time of its formation. Age estimates are based on the decay of short-lived 228Ra (half-life=5.76 years) compared to 226Ra (half-life=1600 years). Present activity ratios of 228Ra/226Ra in radiobarite-rich scale or highly contaminated soil are compared to initial ratios at the time of radiobarite precipitation. Initial ratios are estimated by measurements of saline water or recent barite precipitates at the site or by considering a range of probable initial ratios based on reported values in modern oil-field brines. At sites that contain two distinct radiobarite sources of different age, the soils containing mixtures of sources can be identified, and mixing proportions quantified using radium concentration and isotopic data. These uses of radium isotope data provide more description of contamination history and can possibly address liability issues. Copyright ?? 2000 .

Common Pb isotope mapping of UHP metamorphic zones in Dabie orogen, Central China: Implication for Pb isotopic structure of subducted continental crust

NASA Astrophysics Data System (ADS)

Shen, Ji; Wang, Ying; Li, Shu-Guang

2014-10-01

We report Pb isotopic compositions for feldspars separated from 57 orthogneisses and 2 paragneisses from three exhumed UHPM slices representing the North Dabie zone, the Central Dabie zone and the South Dabie zone of the Dabie orogen, central-east China. The feldspars from the gneisses were recrystallized during Triassic continental subduction and UHP metamorphism. Precursors of the orthogneisses are products of Neoproterozoic bimodal magmatic events, those in north Dabie zone emplaced into the lower crust and those in central and south Dabie zones into middle or upper crust, respectively. On a 207Pb/204Pb vs. 206Pb/204Pb diagram, almost all orthogneisses data lie to the left of the 0.23 Ga paleogeochron and plot along the model mantle evolution curve with the major portion of the data plotting below it. On a 208Pb/204Pb vs. 206Pb/204Pb diagram the most of data of north Dabie zone extend in elongate arrays along the lower crustal curve and others extend between the lower crustal curve to near the mantle evolution curve for the plumbotectonics model. This pattern demonstrates that the Pb isotopic evolution of the feldspars essentially ended at 0.23 Ga and the orthogneiss protoliths were principally dominated by reworking of ancient lower crust with some addition of juvenile mantle in the Neoproterozoic rifting tectonic zone. According to geological evolution history of the locally Dabie orogen, a four-stage Pb isotope evolution model including a long time evolution between 2.0 and 0.8 Ga with a lower crust type U/Pb ratio (μ = 5-6) suggests that magmatic emplacement levels of the protoliths of the orthogneisses in the Dabie orogen at 0.8 Ga also play an important role in the Pb evolution of the exhumed UHPM slices, corresponding to their respective Pb characters at ca. 0.8-0.23 Ga. For example, north Dabie zone requires low μ values (3.4-9.6), while central and south Dabie zones require high μ values (10.9-17.2). On the other hand, Pb isotopic mixing between

Measuring carbon and oxygen isotope signals of photosynthesis and respiration: first field results from a chamber system coupled to tunable diode laser spectrometers

NASA Astrophysics Data System (ADS)

Wingate, L.; Burlett, R.; Bosc, A.; Cross, A.; Devaux, M.; Grace, J.; Loustau, D.; Seibt, U.; Ogée, J.

2007-12-01

Studying the carbon and oxygen stable isotope signals from plants and soils can help us gain insight to mechanistic processes responsible for the net exchange of CO2 and water cycled between terrestrial ecosystems and the atmosphere. Chamber field measurements of component fluxes and their isotopic composition have been reported for a few ecosystems. These observations have revealed that isotopic signals for carbon and oxygen are dynamic over relatively short time scales (hrs and days) for both branches and soils (Seibt et al., 2006a; 2006b; Wingate et al., 2007), and not fully explained by currently available models (Seibt et al., 2006b; Wingate et al., 2007). Ecosystem isotope studies have been limited by flask sampling requirements in the past. To evaluate and refine our models of isotopic fractionation by plants and soil, we need high resolution continuous isotopic measurements over the growing season for different ecosystems. In this study, we coupled chambers with tunable diode laser spectroscopy techniques in the field to continuously capture the isotopic signals from the most important component fluxes contributing to the net ecosystem exchange of CO2 in a Pinus pinaster forest in south-west France. We obtained profiles of the carbon and oxygen isotope content of CO2 within and above the forest canopy. In addition, we measured branch photosynthetic 13C and 18O discrimination alongside the 13C and 18O isotopic composition of the branch, stem and soil respiration during a 6-month period in 2007. In this talk, we will present the first results from this field campaign. References Seibt, U., Wingate, L., Berry, J.A. and Lloyd, J. (2006a) Non steady state effects in diurnal 18O discrimination by Picea sitchensis branches in the field. Plant, Cell and Environment Vol 29, 928-939. Seibt, U., Wingate, L., Lloyd, J. and Berry, J.A. (2006b) Diurnally variable δ18O signatures of soil CO2 fluxes indicate carbonic anhydrase activity in a forest soil. JGR

Oxygen isotope evolution of the Lake Owyhee volcanic field, Oregon, and implications for low-δ18O magmas of the Snake River Plain - Yellowstone hotspot

NASA Astrophysics Data System (ADS)

Blum, T.; Kitajima, K.; Nakashima, D.; Valley, J. W.

2013-12-01

The Snake River Plain - Yellowstone (SRP-Y) hotspot trend is one of the largest known low-δ18O magmatic provinces, yet the timing and distribution of hydrothermal alteration relative to hotspot magmatism remains incompletely understood. Existing models for SRP-Y low-δ18O magma genesis differ regarding the timing of protolith alteration (e.g. Eocene vs. present), depth at which alteration occurs (e.g. 15 km vs. <5 km), and physical controls on the extent of alteration (e.g. caldera collapse, crustal scale fluid flow, etc.). We expand the existing oxygen isotope data set for zircon in the Lake Owyhee volcanic field (LOVF) of east central Oregon to further identify magmatic oxygen isotope trends within the field. These data offer insight into the timing of alteration and the extent of the greater SRP-Y low-δ18O province, as well as the conditions that generate large low-δ18O provinces. 16-14 Ma silicic volcanism in the LOVF is linked to the pre-14 Ma SRP-Y hotspot, with volcanism partially overlapping extension in the north-south trending Oregon-Idaho Graben (OIG). Ion microprobe analyses of zircons from 16 LOVF silicic lavas and tuffs reveal homogeneous zircons on both the single grain and hand sample scales: individual samples have 2 S.D. for δ18O ranging from 0.27 to 0.96‰ (SMOW), and sample averages ranging from 1.8 to 6.0‰, excluding texturally chaotic and/or porous zircons which have δ18O values as low as 0.0‰. All low-δ18O LOVF magmas, including the caldera-forming Tuff of Leslie Gulch and Tuff of Spring Creek, are confined to the OIG, although not all zircons from within the OIG have low δ18O values. The presence and sequence of low-δ18O magmas in the LOVF and adjacent central Snake River Plain (CSRP) cannot be explained by existing caldera subsidence or pre-hotspot source models. These data, however, combined with volumetrically limited low-δ18O material in the adjacent Idaho Batholith and Basin and Range, are consistent with low-δ18O magmas

To See a World in a Grain of Sand: Insights into Solar System Formation and Evolution from Isotopic Analyses of Planetary Materials

NASA Astrophysics Data System (ADS)

Wadhwa, M.

2016-12-01

The last few decades have seen revolutionary advances in the planetary sciences through remote observations (by spacecraft and Earth-based observatories) of many Solar System destinations and, in more recent years, even exoplanets around other stars. In parallel with this, ground-breaking developments in analytical capabilities and access to a greater variety of Solar System materials (through systematic and sustained meteorite collection programs as well as sample return missions) have led to significant insights that are complementary to those from remote observations and measurements. I will discuss two examples where the combination of remote observations and sample analyses has the potential to provide a more holistic picture of Solar System formation and evolution: 1) High-precision analyses of radiogenic isotopes in primitive and differentiated meteoritic materials, which are yielding a detailed high-resolution chronology of the first 10 million years of Solar System history. Such investigations are providing the chronological framework for the formation and evolution of small bodies (including comets, asteroids and Kuiper Belt Objects) in our Solar System that are the targets of recent spacecraft missions such as NASA's Dawn and New Horizons missions and ESA's Rosetta mission. 2) In-situ analyses of hydrogen isotope compositions and H2O abundances in meteorites from Mars and Vesta, which are giving constraints on the inventory and source of water and other volatiles in these planetary bodies. These studies are providing insights complementary to those about Mars from NASA's Mars Science Laboratory and Mars Atmosphere and Volatile Evolution (MAVEN) missions, and about Vesta from NASA's Dawn mission.

Isotope-Identifying neutron reflectometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nikitenko, Yu. V., E-mail: nikiten@nf.jinr.ru; Petrenko, A. V.; Gundorin, N. A.

2015-07-15

The possibilities of an isotope-indentifying study of layered structures in different regimes of a neutron wave field are considered. The detection of specularly reflected neutrons and secondary radiation (caused by neutron capture) in the form of charged particles, γ quanta, and nuclear fission fragments, as well as neutrons spin-flipped in a noncollinear magnetic field and on nuclei of elements with spin, makes it possible to implement isotope-indentifying neutron reflectometry.

Variations of geothermometry and chemical-isotopic compositions of hot spring fluids in the Rehai geothermal field, southwestern China

NASA Astrophysics Data System (ADS)

Du, Jianguo; Liu, Congqiang; Fu, Bihong; Ninomiya, Yoshiki; Zhang, Youlian; Wang, Chuanyuan; Wang, Hualiu; Sun, Zigang

2005-04-01

Geothermal variations, origins of carbon-bearing components and reservoir temperatures in the Rehai geothermal field (RGF) of Tengchong volcanic area, Yunnan Province, southwestern China, are discussed on the basis of carbon isotope compositions, combined with helium isotope ratios and geothermal data from 1973 to 2000. δ 13C values of CO 2, CH 4, HCO 3-, CO 3= and travertine in the hot springs range from -7.6‰ to -1.18‰, -56.9‰ to -19.48‰, -6.7‰ to -4.2‰, -6.4‰ to -4.2‰ and -27.1‰ to +0.6‰, respectively. The carbon dioxide probably has a mantle/magma origin, but CH 4 and He have multiple origins. HCO 3- and CO 3= in RGF thermal fluids are predominantly derived from igneous carbon dioxide, but other ions originate from rocks through which the fluids circulate. The 13C values of CO 2, HCO 3- (aq) and CO 3= (aq) illustrate that isotopic equilibriums between CO 2 and HCO 3- (aq), and CO 3= (aq) and between DIC and travertine were not achieved, and no carbon isotope fractionation between HCO 3- (aq) and CO 3= (aq) of the hot springs in RGF was found. Using various geothermometers, temperatures of the geothermal reservoirs are estimated in a wide range from 69 °C to 450 °C that fluctuated from time to time. The best estimate of subsurface reservoir temperature may be 250-300 °C. Contributions of mantle fluids and shallow crust fluids in Rehai geothermal field varied with time, which resulted in variations of chemical and isotopic compositions and reservoir temperatures.

Evolution of carbon isotope signatures during reactive transport of hydrocarbons in heterogeneous aquifers.

PubMed

Höyng, Dominik; Prommer, Henning; Blum, Philipp; Grathwohl, Peter; D'Affonseca, Fernando Mazo

2015-03-01

Compound-specific isotope analysis (CSIA) of organic pollutants has become a well-established tool for assessing the occurrence and extent of biodegradation processes in contaminated aquifers. However, the precision of CSIA is influenced by the degree to which assumptions underlying CSIA data interpretation hold under realistic field-scale conditions. For the first time this study demonstrates how aquifer analogs combined with reactive transport models offer an underexplored way to develop generic process understanding, evaluate monitoring and quantification strategies in highly heterogeneous subsurface settings. Data from high-resolution aquifer analogs were used in numerical experiments to track the propagation of a representative oxidizable organic compound (toluene) within a variety of realistic heterogeneous aquifers and to investigate its detailed fate. The simulations were used to analyze (1) the effects of physical aquifer heterogeneities on spatiotemporal patterns of contaminant concentrations and isotope signatures, (2) the performance of the commonly applied Rayleigh equation and (3) the applicability of an extension of the Rayleigh equation for complex hydrogeological conditions. The results indicate that if field-derived enrichment factors are applied without corrections for dilution, the conventional Rayleigh equation is inaccurate and estimates for biodegradation are typically overestimated and unreliable in heterogeneous aquifers. Underestimations can occur due to the partial source zone depletion. In contrast, if dilution can be accurately accounted for, field-derived enrichment factors comprise a suitable alternative to laboratory-derived and redox-specific enrichment factors. The study also examines to what extent variations in monitoring/sampling strategies influence the obtained results. Especially measurements from long-screened wells (>1 m) reveal to be inappropriate for the application of the Rayleigh equation in the investigated aquifer

Using stable isotopes and major ions to identify hydrological processes and geochemical characteristics in a typical karstic basin, Guizhou, Southwest China.

PubMed

Han, Zhiwei; Tang, Changyuan; Wu, Pan; Zhang, Ruixue; Zhang, Chipeng

2014-01-01

The investigation of hydrological processes is very important for water resource development in karst basins. In order to understand these processes associated with complex hydrogeochemical evolution, a typical basin was chosen in Houzai, southwest China. The basin was hydrogeologically classified into three zones based on hydrogen and oxygen isotopes as well as the field surveys. Isotopic values were found to be enriched in zone 2 where paddy fields were prevailing with well-developed underground flow systems, and heavier than those in zone 1. Zone 3 was considered as the mixture of zones 1 and 2 with isotopic values falling in the range between the two zones. A conceptual hydrological model was thus proposed to reveal the probable hydrological cycle in the basin. In addition, major processes of long-term chemical weathering in the karstic basin were discussed, and reactions between water and carbonate rocks proved to be the main geochemical processes in karst aquifers.

Fractionation of Cu and Mo isotopes caused by vapor-liquid partitioning, evidence from the Dahutang W-Cu-Mo ore field

NASA Astrophysics Data System (ADS)

Yao, Junming; Mathur, Ryan; Sun, Weidong; Song, Weile; Chen, Huayong; Mutti, Laurence; Xiang, Xinkui; Luo, Xiaohong

2016-05-01

The study presents δ65Cu and δ97Mo isotope values from cogenetic chalcopyrite and molybdenite found in veins and breccias of the Dahutang W-Cu-Mo ore field in China. The samples span a 3-4 km range. Both isotopes show a significant degree of fractionation. Cu isotope values in the chalcopyrite range from -0.31‰ to +1.48‰, and Mo isotope values in the molybdenite range from -0.03‰ to +1.06‰. For the cogenetic sulfide veined samples, a negative slope relationship exists between δ65Cu and δ97Mo values, which suggest a similar fluid history. Rayleigh distillation models the vein samples' change in isotope values. The breccia samples do not fall on the trend, thus indicating a different source mineralization event. Measured fluid inclusion and δD and δ18O data from cogenetic quartz indicate changes in temperature, and mixing of fluids do not appear to cause the isotopic shifts measure. Related equilibrium processes associated with the partitioning of metal between the vapor-fluid in the hydrothermal system could be the probable cause for the relationship seen between the two isotope systems.

Field-based stable isotope analysis of carbon dioxide by mid-infrared laser spectroscopy for carbon capture and storage monitoring.

PubMed

van Geldern, Robert; Nowak, Martin E; Zimmer, Martin; Szizybalski, Alexandra; Myrttinen, Anssi; Barth, Johannes A C; Jost, Hans-Jürg

2014-12-16

A newly developed isotope ratio laser spectrometer for CO2 analyses has been tested during a tracer experiment at the Ketzin pilot site (northern Germany) for CO2 storage. For the experiment, 500 tons of CO2 from a natural CO2 reservoir was injected in supercritical state into the reservoir. The carbon stable isotope value (δ(13)C) of injected CO2 was significantly different from background values. In order to observe the breakthrough of the isotope tracer continuously, the new instruments were connected to a stainless steel riser tube that was installed in an observation well. The laser instrument is based on tunable laser direct absorption in the mid-infrared. The instrument recorded a continuous 10 day carbon stable isotope data set with 30 min resolution directly on-site in a field-based laboratory container during a tracer experiment. To test the instruments performance and accuracy the monitoring campaign was accompanied by daily CO2 sampling for laboratory analyses with isotope ratio mass spectrometry (IRMS). The carbon stable isotope ratios measured by conventional IRMS technique and by the new mid-infrared laser spectrometer agree remarkably well within analytical precision. This proves the capability of the new mid-infrared direct absorption technique to measure high precision and accurate real-time stable isotope data directly in the field. The laser spectroscopy data revealed for the first time a prior to this experiment unknown, intensive dynamic with fast changing δ(13)C values. The arrival pattern of the tracer suggest that the observed fluctuations were probably caused by migration along separate and distinct preferential flow paths between injection well and observation well. The short-term variances as observed in this study might have been missed during previous works that applied laboratory-based IRMS analysis. The new technique could contribute to a better tracing of the migration of the underground CO2 plume and help to ensure the long

Modeling the isotopic evolution of snowpack and snowmelt: Testing a spatially distributed parsimonious approach.

PubMed

Ala-Aho, Pertti; Tetzlaff, Doerthe; McNamara, James P; Laudon, Hjalmar; Kormos, Patrick; Soulsby, Chris

2017-07-01

Use of stable water isotopes has become increasingly popular in quantifying water flow paths and travel times in hydrological systems using tracer-aided modeling. In snow-influenced catchments, snowmelt produces a traceable isotopic signal, which differs from original snowfall isotopic composition because of isotopic fractionation in the snowpack. These fractionation processes in snow are relatively well understood, but representing their spatiotemporal variability in tracer-aided studies remains a challenge. We present a novel, parsimonious modeling method to account for the snowpack isotope fractionation and estimate isotope ratios in snowmelt water in a fully spatially distributed manner. Our model introduces two calibration parameters that alone account for the isotopic fractionation caused by sublimation from interception and ground snow storage, and snowmelt fractionation progressively enriching the snowmelt runoff. The isotope routines are linked to a generic process-based snow interception-accumulation-melt model facilitating simulation of spatially distributed snowmelt runoff. We use a synthetic modeling experiment to demonstrate the functionality of the model algorithms in different landscape locations and under different canopy characteristics. We also provide a proof-of-concept model test and successfully reproduce isotopic ratios in snowmelt runoff sampled with snowmelt lysimeters in two long-term experimental catchment with contrasting winter conditions. To our knowledge, the method is the first such tool to allow estimation of the spatially distributed nature of isotopic fractionation in snowpacks and the resulting isotope ratios in snowmelt runoff. The method can thus provide a useful tool for tracer-aided modeling to better understand the integrated nature of flow, mixing, and transport processes in snow-influenced catchments.

Hydrogen isotopic fractionation during crystallization of the terrestrial magma ocean

NASA Astrophysics Data System (ADS)

Pahlevan, K.; Karato, S. I.

2016-12-01

Models of the Moon-forming giant impact extensively melt and partially vaporize the silicate Earth and deliver a substantial mass of metal to the Earth's core. The subsequent evolution of the terrestrial magma ocean and overlying vapor atmosphere over the ensuing 105-6 years has been largely constrained by theoretical models with remnant signatures from this epoch proving somewhat elusive. We have calculated equilibrium hydrogen isotopic fractionation between the magma ocean and overlying steam atmosphere to determine the extent to which H isotopes trace the evolution during this epoch. By analogy with the modern silicate Earth, the magma ocean-steam atmosphere system is often assumed to be chemically oxidized (log fO2 QFM) with the dominant atmospheric vapor species taken to be water vapor. However, the terrestrial magma ocean - having held metallic droplets in suspension - may also exhibit a much more reducing character (log fO2 IW) such that equilibration with the overlying atmosphere renders molecular hydrogen the dominant H-bearing vapor species. This variable - the redox state of the magma ocean - has not been explicitly included in prior models of the coupled evolution of the magma ocean-steam atmosphere system. We find that the redox state of the magma ocean influences not only the vapor speciation and liquid-vapor partitioning of hydrogen but also the equilibrium isotopic fractionation during the crystallization epoch. The liquid-vapor isotopic fractionation of H is substantial under reducing conditions and can generate measurable D/H signatures in the crystallization products but is largely muted in an oxidizing magma ocean and steam atmosphere. We couple equilibrium isotopic fractionation with magma ocean crystallization calculations to forward model the behavior of hydrogen isotopes during this epoch and find that the distribution of H isotopes in the silicate Earth immediately following crystallization represents an oxybarometer for the terrestrial

Measurement of the Isotopic Signature of Soil Carbon Dioxide: Methods Development and Initial Field Results

NASA Astrophysics Data System (ADS)

Kayler, Z.; Rugh, W.; Mix, A. C.; Bond, B. J.; Sulzman, E. W.

2005-12-01

Soil respiration is a significant component of ecosystem respiration and its isotopic composition is likely to lend insight into ecosystem processes. We have designed probes to determine the isotopic signature of soil-respired CO2 using a two end-member mixing model approach (i.e., Keeling plot). Each probe consists of three 35 ml PVC chambers cased in fiberglass mesh and connected to the soil surface via stainless steel tubing with a septa-lined swagelok fitting. Chambers are vertically connected such that they sample gases at depth intervals centered on 5, 15, and 30 cm. Gases are sampled via a hand vacuum pump equipped with a two-way valve, which allows vials pre-filled with N2 gas in the laboratory to be evacuated and re-filled with only a single septa puncture in the field. Data indicate samples can be stored reliably for up to three days if punctured septa are coated in silicone sealant. To test whether this field sampling method was robust, we constructed a carbon-free sand column out of PVC pipe into which we plumbed a tank of known CO2 concentration and isotopic composition. We have tested the effects of wetting and flow rate on our ability to reproduce tank values. A linear model (geometric mean regression) yielded a more negative isotopic value than the actual gas, but a simple polynomial curve fit the tank value. After laboratory testing, the probes were established in a steep drainage in the H.J. Andrews LTER site in the Cascade Mountains of western Oregon (as part of the Andrews Airshed project). We established a transect of five 10 m2 plots with four soil probes and a companion respiration collar and measured soil CO2 efflux and soil δ13CO2 values biweekly from June-Sept. Results indicate there is a clear difference in isotopic and respiration flux patterns between the north- and south-facing slopes, with the north facing slope exhibiting higher fluxes and more 13C enriched respiration. The temporal pattern of respiration correlates well with

Evolution of complexity following a quantum quench in free field theory

NASA Astrophysics Data System (ADS)

Alves, Daniel W. F.; Camilo, Giancarlo

2018-06-01

Using a recent proposal of circuit complexity in quantum field theories introduced by Jefferson and Myers, we compute the time evolution of the complexity following a smooth mass quench characterized by a time scale δ t in a free scalar field theory. We show that the dynamics has two distinct phases, namely an early regime of approximately linear evolution followed by a saturation phase characterized by oscillations around a mean value. The behavior is similar to previous conjectures for the complexity growth in chaotic and holographic systems, although here we have found that the complexity may grow or decrease depending on whether the quench increases or decreases the mass, and also that the time scale for saturation of the complexity is of order δ t (not parametrically larger).

Integrating isotopic fingerprinting with petrology: how do igneous rocks evolve?

NASA Astrophysics Data System (ADS)

Davidson, J. P.

2002-12-01

In the title of his seminal work, N.L. Bowen recognized the fundamental importance of magmatic evolution in producing the spectrum of igneous rocks. Indeed it is difficult to imagine a hot highly reactive fluid passing through c. 100 km of a chemically distinct medium (lithosphere) without evolving through cooling, crystallization and interaction with the wall rocks. The fact that magmas evolve - almost invariably through open system processes - has been largely marginalized in the past 30 years by the desire to use them as probes of mantle source regions. This perspective has been driven principally by advances offered by isotope geochemistry, through which components and sources can be effectively fingerprinted. Two fundamental observations urge caution in ignoring differentiation effects; 1) the scarcity of truly primary magmas according to geochemical criteria (recognized long ago by petrologists), and 2) the common occurrence of petrographic criteria attesting to open system evolution. Recent advances in multicollector mass spectrometry permit integration of the powerful diagnostic tools of isotope geochemistry with petrographic observations through accurate and precise analysis of small samples. Laser ablation and microdrilling enable sampling within and between mineral phases. The results of our microsampling investigations give widespread support for open system evolution of magmas, and provide insights into the mechanisms and timescales over which this occurs. For example; 1) core-rim decreases in 87Sr/86Sr in zoned plagioclase crystals from 1982 lavas of El Chichon volcano, Mexico, argue that the zoning and isotopic changes are in response to magma recharge mixing with an originally contaminated resident magma; 2) Single grain and intra-grain isotopic analyses of mineral phases from Ngauruhoe andesites (New Zealand) are highly variable, arguing that bulk rock data reflect mechanical aggregations of components which have evolved in discrete domains of the

Ca, Sr, O and D isotope approach to defining the chemical evolution of hydrothermal fluids: example from Long Valley, CA, USA

USGS Publications Warehouse

Brown, Shaun T.; Kennedy, B. Mack; DePaolo, Donald J.; Hurwitz, Shaul; Evans, William C.

2013-01-01

We present chemical and isotopic data for fluids, minerals and rocks from the Long Valley meteoric-hydrothermal system. The samples encompass the presumed hydrothermal upwelling zone in the west moat of the caldera, the Casa Diablo geothermal field, and a series of wells defining a nearly linear, ∼16 km long, west-to-east trend along the likely fluid flow path. Fluid samples were analyzed for the isotopes of water, Sr, and Ca, the concentrations of major cations and anions, alkalinity, and total CO2. Water isotope data conform to trends documented in earlier studies, interpreted as indicating a single hydrothermal fluid mixing with local groundwater. Sr isotopes show subtle changes along the flow path, which requires rapid fluid flow and minimal reaction between the channelized fluids and the wallrocks. Sr and O isotopes are used to calculate fracture spacing using a dual porosity model. Calculated fracture spacing and temperature data for hydrothermal fluids indicate the system is (approximately) at steady-state. Correlated variations among total CO2, and the concentration and isotopic composition of Ca suggest progressive fluid degassing (loss of CO2), which drives calcite precipitation as the fluid flows west-to-east and cools. The shifts in Ca isotopes require that calcite precipitated at temperatures of 150–180 °C is fractionated by ca. −0.3‰ to −0.5‰ relative to aqueous species. Our data are the first evidence that Ca isotopes undergo kinetic fractionation at high temperatures (>100 °C) and can be used to trace calcite precipitation along hydrothermal fluid flow paths.

Isotope geochronology of the Precambrian

NASA Astrophysics Data System (ADS)

Levskii, L. K.; Levchenkov, O. A.

This symposium discusses the use of isotope methods for establishing the geochronology of Precambrian formations, with special consideration given to geochronological studies of the early phases of the earth's core evolution in the Baltic and Vitim-Aldan shields and the Enderby Land (Antarctica). Attention is also given to the Early Archean Vodlozero gneiss complex and its structural-metamorphic evolution, the influence of geological events during the Proterozoic on the state of the U-Pb and Rb-Sr systems in the Archean postkinematic granites of Karelia, the Rb-Sr systems in the andesite basalts of the Suna-Semch' region (Karelia), and the geochronology of the Karelian granite-greenstone region. Also discussed are the petrogenesis and age of the rocks from the Kola ultradeep borehole, the isotope-geochronological evidence for the early Precambrian history of the Aldan-Olekma region, the Rb-Sr systems in metasedimentary rocks of the Khani graben, and the U-Pb ages of zircons from polymetamorphic rocks of the Archean granulite complex of Enderby Land.

The evolution of Carbon isotopes in calcite in the presence of cyanobacteria

NASA Astrophysics Data System (ADS)

Grimm, Christian; Mavromatis, Vasileios; Pokrovsky, Oleg S.; Oelkers, Eric H.

2016-04-01

Stable isotopic compositions in carbonates are widely used as indicators of environmental conditions prevailing during mineral formation. This reconstruction is substantially based on the assumption that there is no change in the mineral composition over geological time. However, recent experimental studies have shown that carbon and magnesium isotopes in hydrous Mg-carbonates undergo continuous re-equilibration with the ambient solution even after mineral precipitation stopped ([1] and [2], respectively). To verify whether this holds true for anhydrous Ca-bearing carbonates which readily form at earth's surface environments, a series of batch system calcite precipitation experiments were performed in the presence of actively growing cyanobacteria Synechococcus sp. The bacteria were grown at ambient temperature in a BG11 culture medium (SIGMA C3061) and continuous stirring, air-bubbling and illumination. Calcite precipitation was initiated by the addition of 8.5mM CaCl2 and 0-50 mM NaHCO3 or NaHCO3-Na2CO3 mixtures. The presence of cyanobacteria is on one hand promoting CaCO3 formation due to increasing pH resulting from photosynthesis. On the other hand, actively growing cyanobacteria drastically change carbon isotope signature of the aqueous fluid phase by preferably incorporating the lighter 12C isotope into biomass [1]. This study explores the effect of continuously changing carbon isotope compositions in dissolved inorganic carbon (DIC) on precipitated calcite which is in chemical equilibrium with the ambient fluid phase. [1] Mavromatis et al. (2015). The continuous re-equilibration of carbon isotope compositions of hydrous Mg-carbonates in the presence of cyanobacteria. Chem. Geol. 404, 41-51 [2] Mavromatis et al. (2012). Magnesium isotope fractionation during hydrous magnesium carbonate precipitation with and without cyanobacteria. Geochim. Cosmochim. Acta 76, 161-174

Isotopically (δ13C and δ18O) heavy volcanic plumes from Central Andean volcanoes: a field study

NASA Astrophysics Data System (ADS)

Schipper, C. Ian; Moussallam, Yves; Curtis, Aaron; Peters, Nial; Barnie, Talfan; Bani, Philipson; Jost, H. J.; Hamilton, Doug; Aiuppa, Alessandro; Tamburello, Giancarlo; Giudice, Gaetano

2017-08-01

Stable isotopes of carbon and oxygen in volcanic gases are key tracers of volatile transfer between Earth's interior and atmosphere. Although important, these data are available for few volcanoes because they have traditionally been difficult to obtain and are usually measured on gas samples collected from fumaroles. We present new field measurements of bulk plume composition and stable isotopes (δ13CCO2 and δ18OH2O+CO2) carried out at three northern Chilean volcanoes using MultiGAS and isotope ratio infrared spectroscopy. Carbon and oxygen in magmatic gas plumes of Lastarria and Isluga volcanoes have δ13C in CO2 of +0.76‰ to +0.77‰ (VPDB), similar to slab carbonate; and δ18O in the H2O + CO2 system ranging from +12.2‰ to +20.7‰ (VSMOW), suggesting significant contributions from altered slab pore water and carbonate. The hydrothermal plume at Tacora has lower δ13CCO2 of -3.2‰ and δ18OH2O+CO2 of +7.0‰, reflecting various scrubbing, kinetic fractionation, and contamination processes. We show the isotopic characterization of volcanic gases in the field to be a practical complement to traditional sampling methods, with the potential to remove sampling bias that is a risk when only a few samples from accessible fumaroles are used to characterize a given volcano's volatile output. Our results indicate that there is a previously unrecognized, relatively heavy isotopic signature to bulk volcanic gas plumes in the Central Andes, which can be attributed to a strong influence from components of the subducting slab, but may also reflect some local crustal contamination. The techniques we describe open new avenues for quantifying the roles that subduction zones and arc volcanoes play in the global carbon cycle.

Sulfur isotopes in coal constrain the evolution of the Phanerozoic sulfur cycle

PubMed Central

Canfield, Donald E.

2013-01-01

Sulfate is the second most abundant anion (behind chloride) in modern seawater, and its cycling is intimately coupled to the cycling of organic matter and oxygen at the Earth’s surface. For example, the reduction of sulfide by microbes oxidizes vast amounts of organic carbon and the subsequent reaction of sulfide with iron produces pyrite whose burial in sediments is an important oxygen source to the atmosphere. The concentrations of seawater sulfate and the operation of sulfur cycle have experienced dynamic changes through Earth’s history, and our understanding of this history is based mainly on interpretations of the isotope record of seawater sulfates and sedimentary pyrites. The isotope record, however, does not give a complete picture of the ancient sulfur cycle. This is because, in standard isotope mass balance models, there are more variables than constraints. Typically, in interpretations of the isotope record and in the absence of better information, one assumes that the isotopic composition of the input sulfate to the oceans has remained constant through time. It is argued here that this assumption has a constraint over the last 390 Ma from the isotopic composition of sulfur in coal. Indeed, these compositions do not deviate substantially from the modern surface-water input to the oceans. When applied to mass balance models, these results support previous interpretations of sulfur cycle operation and counter recent suggestions that sulfate has been a minor player in sulfur cycling through the Phanerozoic Eon. PMID:23650346

Rapid evolution of analog circuits configured on a field programmable transistor array

NASA Technical Reports Server (NTRS)

Stoica, A.; Ferguson, M. I.; Zebulum, R. S.; Keymeulen, D.; Duong, V.; Daud, T.

2002-01-01

The purpose of this paper is to illustrate evolution of analog circuits on a stand-alone board-level evolvable system (SABLES). SABLES is part of an effort to achieve integrated evolvable systems. SABLES provides autonomous, fast (tens to hundreds of seconds), on-chip circuit evolution involving about 100,000 circuit evaluations. Its main components are a JPL Field Programmable Transistor Array (FPTA) chip used as transistor-level reconfigurable hardware, and a TI DSP that implements the evolutionary algorithm controlling the FPTA reconfiguration. The paper details an example of evolution on SABLES and points out to certain transient and memory effects that affect the stability of solutions obtained reusing the same piece of hardware for rapid testing of individuals during evolution.

A lab in the field: high-frequency analysis of water quality and stable isotopes in stream water and precipitation

NASA Astrophysics Data System (ADS)

von Freyberg, Jana; Studer, Bjørn; Kirchner, James W.

2017-03-01

High-frequency measurements of solutes and isotopes (18O and 2H) in rainfall and streamflow can shed important light on catchment flow pathways and travel times, but the workload and sample storage artifacts involved in collecting, transporting, and analyzing thousands of bottled samples severely constrain catchment studies in which conventional sampling methods are employed. However, recent developments towards more compact and robust analyzers have now made it possible to measure chemistry and water isotopes in the field at sub-hourly frequencies over extended periods. Here, we present laboratory and field tests of a membrane-vaporization continuous water sampler coupled to a cavity ring-down spectrometer for real-time measurements of δ18O and δ2H combined with a dual-channel ion chromatograph (IC) for the synchronous analysis of major cations and anions. The precision of the isotope analyzer was typically better than 0.03 ‰ for δ18O and 0.17 ‰ for δ2H in 10 min average readings taken at intervals of 30 min. Carryover effects were less than 1.2 % between isotopically contrasting water samples for 30 min sampling intervals, and instrument drift could be corrected through periodic analysis of secondary reference standards. The precision of the ion chromatograph was typically ˜ 0.1-1 ppm or better, with relative standard deviations of ˜ 1 % or better for most major ions in stream water, which is sufficient to detect subtle biogeochemical signals in catchment runoff. We installed the coupled isotope analyzer/IC system in an uninsulated hut next to a stream of a small catchment and analyzed stream water and precipitation samples every 30 min over 28 days. These high-frequency measurements facilitated a detailed comparison of event-water fractions via endmember mixing analysis with both chemical and isotope tracers. For two events with relatively dry antecedent moisture conditions, the event-water fractions were < 21 % based on isotope tracers but were

New paleomagnetic constraints on the lunar magnetic field evolution

NASA Astrophysics Data System (ADS)

Lepaulard, C.; Gattacceca, J.; Weiss, B. P.

2017-12-01

In the 1970s, the first paleomagnetic analyses of lunar samples from the Apollo missions allowed a glimpse of the global evolution of the Moon's magnetic field over time, with evidence for a past dynamo activity [Fuller et Cisowski, 1987]. During the last a decade, a new set of paleomagnetic studies has provided a more refined view of the evolution of the lunar dynamo activity (chronology, intensity) [Weiss et Tikoo, 2014]. The aim of this study is to further refine the knowledge of the lunar dynamo by providing new paleomagnetic data. Based on measurements of the natural remanent magnetization of the main masses of 135 Apollo samples (mass between 50 g and 5 kg) with a portable magnetometer, we have selected nine samples for laboratory analyzes. The selected Apollo samples are: 10018, 15505, 61195 (regolith breccia); 61015 (dimict breccia); 14169 (crystalline matrix breccia); 65055 (basaltic impact melt); 12005, 12021 and 15529 (basalts). Paleointensity of the lunar magnetic fields were obtained by demagnetization by alternative field and normalization with laboratory magnetizations; as well as thermal demagnetization under controlled oxygen fugacity (Thellier-Thellier method) for selected samples. Preliminary results indicate that only three samples (10018, 15505, and 15529) possess a stable high coercivity / high temperature component of magnetization. We estimated the following paleointensities: 1.5 µT for 15505, 13 µT for 15529 (both with alternating field-based methods), and 1 µT for 10018 (thermal demagnetization with the Thellier-Thellier method). The other samples provide only an upper limit for the lunar surface field. These data will be discussed in view of the age of the samples (ages from the literature, and additional dating in progress). References :Fuller, M., and S.M. Cisowski, 1987. Lunar paleomagnetism. Geomagnetism 2, 307-455. Weiss, B.P., and S.M. Tikoo, 2014. The lunar dynamo. Science, 346, doi: 10.1126/science.1246753.

An evolution strategy for lunar nuclear surface power

NASA Technical Reports Server (NTRS)

Mason, Lee S.

1992-01-01

The production and transmission of electric power for a permanently inhabited lunar base poses a significant challenge which can best be met through an evolution strategy. Nuclear systems offer the best opportunity for evolution in terms of both life and performance. Applicable nuclear power technology options include isotope systems (either radioisotope thermoelectric generators or dynamic isotope power systems) and reactor systems with either static (thermoelectric or thermionic) or dynamic (Brayton, Stirling, Rankine) conversion. A power system integration approach that takes evolution into account would benefit by reduced development and operations cost, progressive flight experience, and simplified logistics, and would permit unrestrained base expansion. For the purposes of defining a nuclear power system evolution strategy, the lunar base development shall consist of four phases: precursor, emplacement, consolidation, and operations.

A review: applications of the phase field method in predicting microstructure and property evolution of irradiated nuclear materials

DOE PAGES

Li, Yulan; Hu, Shenyang; Sun, Xin; ...

2017-04-14

Here, complex microstructure changes occur in nuclear fuel and structural materials due to the extreme environments of intense irradiation and high temperature. This paper evaluates the role of the phase field method in predicting the microstructure evolution of irradiated nuclear materials and the impact on their mechanical, thermal, and magnetic properties. The paper starts with an overview of the important physical mechanisms of defect evolution and the significant gaps in simulating microstructure evolution in irradiated nuclear materials. Then, the phase field method is introduced as a powerful and predictive tool and its applications to microstructure and property evolution in irradiatedmore » nuclear materials are reviewed. The review shows that (1) Phase field models can correctly describe important phenomena such as spatial-dependent generation, migration, and recombination of defects, radiation-induced dissolution, the Soret effect, strong interfacial energy anisotropy, and elastic interaction; (2) The phase field method can qualitatively and quantitatively simulate two-dimensional and three-dimensional microstructure evolution, including radiation-induced segregation, second phase nucleation, void migration, void and gas bubble superlattice formation, interstitial loop evolution, hydrate formation, and grain growth, and (3) The Phase field method correctly predicts the relationships between microstructures and properties. The final section is dedicated to a discussion of the strengths and limitations of the phase field method, as applied to irradiation effects in nuclear materials.« less

A review: applications of the phase field method in predicting microstructure and property evolution of irradiated nuclear materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Yulan; Hu, Shenyang; Sun, Xin

Here, complex microstructure changes occur in nuclear fuel and structural materials due to the extreme environments of intense irradiation and high temperature. This paper evaluates the role of the phase field method in predicting the microstructure evolution of irradiated nuclear materials and the impact on their mechanical, thermal, and magnetic properties. The paper starts with an overview of the important physical mechanisms of defect evolution and the significant gaps in simulating microstructure evolution in irradiated nuclear materials. Then, the phase field method is introduced as a powerful and predictive tool and its applications to microstructure and property evolution in irradiatedmore » nuclear materials are reviewed. The review shows that (1) Phase field models can correctly describe important phenomena such as spatial-dependent generation, migration, and recombination of defects, radiation-induced dissolution, the Soret effect, strong interfacial energy anisotropy, and elastic interaction; (2) The phase field method can qualitatively and quantitatively simulate two-dimensional and three-dimensional microstructure evolution, including radiation-induced segregation, second phase nucleation, void migration, void and gas bubble superlattice formation, interstitial loop evolution, hydrate formation, and grain growth, and (3) The Phase field method correctly predicts the relationships between microstructures and properties. The final section is dedicated to a discussion of the strengths and limitations of the phase field method, as applied to irradiation effects in nuclear materials.« less

Hydrocarbon degassing of the earth and origin of oil-gas fields (isotope-geochemical and geodynamic aspects)

NASA Astrophysics Data System (ADS)

Valyaev, Boris; Dremin, Ivan

2016-04-01

More than half a century ago, Academician PN Kropotkin substantiated the relationship of the formation and distribution of oil and gas fields with the processes of emanation hydrocarbon degassing of the Earth. Over the years, the concept of PN Kropotkin received further development and recognition of studies based on new factual material. Of particular importance are the following factors: a) the results of studies on global and regional uneven processes of traditional oil and gas and the role of deep faults in controlling the spread of oil and gas fields; b) the results of the research on gigantic volumes and localization of the discharges of hydrocarbon fluids (mud volcanoes, seeps) on land and into the atmosphere and through the bottom of the World ocean; c) the results of the studies on grand volumes of the spread of unconventional hydrocarbon resources in their non-traditional fields, especially on near-surface interval of unconventional oil and gas accumulation with gas hydrates, heavy oil and bitumen, as well as extraordinary resources of oil and gas in the shale and tight rocks. Deep mantle-crust nature of oil and gas in traditional and nontraditional deposits thus received further substantiation of geological and geophysical data and research results. However, isotopic and geochemical data are still interpreted in favor of the concept of the genesis of oil and gas in the processes of thermal catalytic conversion of organic matter of sedimentary rocks, at temperatures up to 200°C. In this report an alternative interpretation of the isotope carbon-hydrogen system (δ13C-δD) for gas and of oil deposits, isotope carbon system for methane and carbon dioxide (δ13C1-δ13C0) will be presented. An alternative interpretation will also be presented for the data on carbon-helium isotope geochemical system for oil and gas fields, volcanoes and mud volcanoes. These constructions agree with the geological data on the nature of deep hydrocarbon fluids involved in the

Standoff Detection of Uranium and its Isotopes by Femtosecond Filament Laser Ablation Molecular Isotopic Spectrometry

DOE PAGES

Hartig, Kyle C.; Ghebregziabher, Isaac; Jovanovic, Igor

2017-03-08

The ability to perform not only elementally but also isotopically sensitive detection and analysis at standoff distances is important for remote sensing applications in diverse ares, such as nuclear nonproliferation, environmental monitoring, geophysics, and planetary science. We demonstrate isotopically sensitive real-time standoff detection of uranium by the use of femtosecond filament-induced laser ablation molecular isotopic spectrometry. A uranium oxide molecular emission isotope shift of 0.05 ± 0.007 nm is reported at 593.6 nm. We implement both spectroscopic and acoustic diagnostics to characterize the properties of uranium plasma generated at different filament- uranium interaction points. The resulting uranium oxide emission exhibitsmore » a nearly constant signal-to-background ratio over the length of the filament, unlike the uranium atomic and ionic emission, for which the signal-to-background ratio varies significantly along the filament propagation. This is explained by the different rates of increase of plasma density and uranium oxide density along the filament length resulting from spectral and temporal evolution of the filament along its propagation. Lastly, the results provide a basis for the optimal use of filaments for standoff detection and analysis of uranium isotopes and indicate the potential of the technique for a wider range of remote sensing applications that require isotopic sensitivity.« less

Standoff Detection of Uranium and its Isotopes by Femtosecond Filament Laser Ablation Molecular Isotopic Spectrometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hartig, Kyle C.; Ghebregziabher, Isaac; Jovanovic, Igor

The ability to perform not only elementally but also isotopically sensitive detection and analysis at standoff distances is important for remote sensing applications in diverse ares, such as nuclear nonproliferation, environmental monitoring, geophysics, and planetary science. We demonstrate isotopically sensitive real-time standoff detection of uranium by the use of femtosecond filament-induced laser ablation molecular isotopic spectrometry. A uranium oxide molecular emission isotope shift of 0.05 ± 0.007 nm is reported at 593.6 nm. We implement both spectroscopic and acoustic diagnostics to characterize the properties of uranium plasma generated at different filament- uranium interaction points. The resulting uranium oxide emission exhibitsmore » a nearly constant signal-to-background ratio over the length of the filament, unlike the uranium atomic and ionic emission, for which the signal-to-background ratio varies significantly along the filament propagation. This is explained by the different rates of increase of plasma density and uranium oxide density along the filament length resulting from spectral and temporal evolution of the filament along its propagation. Lastly, the results provide a basis for the optimal use of filaments for standoff detection and analysis of uranium isotopes and indicate the potential of the technique for a wider range of remote sensing applications that require isotopic sensitivity.« less

Standoff Detection of Uranium and its Isotopes by Femtosecond Filament Laser Ablation Molecular Isotopic Spectrometry

NASA Astrophysics Data System (ADS)

Hartig, Kyle C.; Ghebregziabher, Isaac; Jovanovic, Igor

2017-03-01

The ability to perform not only elementally but also isotopically sensitive detection and analysis at standoff distances is impor-tant for remote sensing applications in diverse ares, such as nuclear nonproliferation, environmental monitoring, geophysics, and planetary science. We demonstrate isotopically sensitive real-time standoff detection of uranium by the use of femtosecond filament-induced laser ablation molecular isotopic spectrometry. A uranium oxide molecular emission isotope shift of 0.05 ± 0.007 nm is reported at 593.6 nm. We implement both spectroscopic and acoustic diagnostics to characterize the properties of uranium plasma generated at different filament-uranium interaction points. The resulting uranium oxide emis-sion exhibits a nearly constant signal-to-background ratio over the length of the filament, unlike the uranium atomic and ionic emission, for which the signal-to-background ratio varies significantly along the filament propagation. This is explained by the different rates of increase of plasma density and uranium oxide density along the filament length resulting from spectral and temporal evolution of the filament along its propagation. The results provide a basis for the optimal use of filaments for standoff detection and analysis of uranium isotopes and indicate the potential of the technique for a wider range of remote sensing applications that require isotopic sensitivity.

Magnetic field evolution and reversals in spiral galaxies

NASA Astrophysics Data System (ADS)

Dobbs, C. L.; Price, D. J.; Pettitt, A. R.; Bate, M. R.; Tricco, T. S.

2016-10-01

We study the evolution of galactic magnetic fields using 3D smoothed particle magnetohydrodynamics (SPMHD) simulations of galaxies with an imposed spiral potential. We consider the appearance of reversals of the field, and amplification of the field. We find that magnetic field reversals occur when the velocity jump across the spiral shock is above ≈20 km s-1, occurring where the velocity change is highest, typically at the inner Lindblad resonance in our models. Reversals also occur at corotation, where the direction of the velocity field reverses in the corotating frame of a spiral arm. They occur earlier with a stronger amplitude spiral potential, and later or not at all with weaker or no spiral arms. The presence of a reversal at radii of around 4-6 kpc in our fiducial model is consistent with a reversal identified in the Milky Way, though we caution that alternative Galaxy models could give a similar reversal. We find that relatively high resolution, a few million particles in SPMHD, is required to produce consistent behaviour of the magnetic field. Amplification of the magnetic field occurs in the models, and while some may be genuinely attributable to differential rotation or spiral arms, some may be a numerical artefact. We check our results using ATHENA, finding reversals but less amplification of the field, suggesting that some of the amplification of the field with SPMHD is numerical.

Chiral three-nucleon forces and the evolution of correlations along the oxygen isotopic chain

NASA Astrophysics Data System (ADS)

Cipollone, A.; Barbieri, C.; Navrátil, P.

2015-07-01

Background: Three-nucleon forces (3NFs) have nontrivial implications on the evolution of correlations at extreme proton-neutron asymmetries. Recent ab initio calculations show that leading-order chiral interactions are crucial to obtain the correct binding energies and neutron driplines along the O, N, and F chains [A. Cipollone, C. Barbieri, and P. Navrátil, Phys. Rev. Lett. 111, 062501 (2013), 10.1103/PhysRevLett.111.062501]. Purpose: Here we discuss the impact of 3NFs along the oxygen chain for other quantities of interest, such has the spectral distribution for attachment and removal of a nucleon, spectroscopic factors, and radii. The objective is to better delineate the general effects of 3NFs on nuclear correlations. Methods: We employ self-consistent Green's function (SCGF) theory which allows a comprehensive calculation of the single-particle spectral function. For the closed subshell isotopes, 14O, 16O, 22O, 24O, and 28O, we perform calculations with the Dyson-ADC(3) method, which is fully nonperturbative and is the state of the art for both nuclear physics and quantum chemistry applications. The remaining open-shell isotopes are studied using the newly developed Gorkov-SCGF formalism up to second order. Results: We produce complete plots for the spectral distributions. The spectroscopic factors for the dominant quasiparticle peaks are found to depend very little on the leading-order (NNLO) chiral 3NFs. The latter have small impact on the calculated matter radii, which, however, are consistently obtained smaller than experiment. Similarly, single-particle spectra tend to be too spread with respect to the experiment. This effect might hinder, to some extent, the onset of correlations and screen the quenching of calculated spectroscopic factors. The most important effect of 3NFs is thus the fine tuning of the energies for the dominant quasiparticle states, which governs the shell evolution and the position of driplines. Conclusions: Although present chiral

The Physical and Petrologic Evolution of a Multi-vent Volcanic Field Associated With Yellowstone-Newberry Volcanism

NASA Astrophysics Data System (ADS)

Brueseke, M. E.; Hart, W. K.

2004-12-01

The Santa Rosa-Calico volcanic field (SC) of northern Nevada is perhaps the most chemically and physically diverse of all volcanic fields associated with mid-Miocene northwestern USA volcanism. SC volcanism occurred from 16.5 to 14 Ma and was characterized by the eruption of a complete compositional spectrum from basalt through high-Si rhyolite. Locally derived tholeiitic lava flows and shallow intrusive bodies are chemically and isotopically identical to the Steens Basalt (87/86Sri=<0.7040), the Oregon Plateau-wide mid-Miocene flood basalt. Andesite-dacite lava flows are exposed as at least four geographically and chemically distinct packages representing products of multiple, discrete magmatic systems. The most voluminous of these is calc-alkaline and characterized by abundant granitoid and mafic xenoliths/xenocrysts and radiogenic Sr isotopic ratios. Subalkaline silicic lava flows, domes, and shallow intrusive bodies define three diffuse north-south trending zones. Textural, chemical, and isotopic variability within the silicic units is linked to their spatial and temporal distribution, again necessitating the existence of multiple magmatic systems. The youngest locally derived silicic units are ash flows exposed in the central portion of the SC that erupted in actively forming sedimentary basins at ˜15.4 Ma. Underlying the 400-1500m thick package of SC volcanic rocks are temporally ( ˜103 and ˜85 Ma), chemically, and isotopically (87/86Sr at 16 Ma= 0.7045 to 0.7058 and 0.7061 to >0.7070) heterogeneous granitoid plutons and a package of ˜20-23 Ma calc-alkaline, arc-related intermediate lava flows. The observed disequilibrium textures, xenoliths, and chemical/isotopic diversity suggests that upwelling Steens magma interacted with local crust, siliceous crustal melts, and the mafic plutonic roots of early Miocene arc volcanism in multiple magmatic systems characterized by heterogeneous open system processes. The formation of these systems is tectonically

Isotopic and trace element constraints on the petrogenesis of lavas from the Mount Adams volcanic field, Washington

USGS Publications Warehouse

Jicha, B.R.; Hart, G.L.; Johnson, C.M.; Hildreth, Wes; Beard, B.L.; Shirey, S.B.; Valley, J.W.

2009-01-01

Strontium, Nd, Pb, Hf, Os, and O isotope compositions for 30 Quaternary lava flows from the Mount Adams stratovolcano and its basaltic periphery in the Cascade arc, southern Washington, USA indicate a major component from intraplate mantle sources, a relatively small subduction component, and interaction with young mafic crust at depth. Major- and trace-element patterns for Mount Adams lavas are distinct from the rear-arc Simcoe volcanic field and other nearby volcanic centers in the Cascade arc such as Mount St. Helens. Radiogenic isotope (Sr, Nd, Pb, and Hf) compositions do not correlate with geochemical indicators of slab-fluids such as (Sr/P)n and Ba/Nb. Mass-balance modeling calculations, coupled with trace-element and isotopic data, indicate that although the mantle source for the calc-alkaline Adams basalts has been modified with a fluid derived from subducted sediment, the extent of modification is significantly less than what is documented in the southern Cascades. The isotopic and trace-element compositions of most Mount Adams lavas require the presence of enriched and depleted mantle sources, and based on volume-weighted chemical and isotopic compositions for Mount Adams lavas through time, an intraplate mantle source contributed the major magmatic mass of the system. Generation of basaltic andesites to dacites at Mount Adams occurred by assimilation and fractional crystallization in the lower crust, but wholesale crustal melting did not occur. Most lavas have Tb/Yb ratios that are significantly higher than those of MORB, which is consistent with partial melting of the mantle in the presence of residual garnet. ??18O values for olivine phenocrysts in Mount Adams lavas are within the range of typical upper mantle peridotites, precluding involvement of upper crustal sedimentary material or accreted terrane during magma ascent. The restricted Nd and Hf isotope compositions of Mount Adams lavas indicate that these isotope systems are insensitive to crustal

Core surface magnetic field evolution 2000-2010

NASA Astrophysics Data System (ADS)

Finlay, C. C.; Jackson, A.; Gillet, N.; Olsen, N.

2012-05-01

We present new dedicated core surface field models spanning the decade from 2000.0 to 2010.0. These models, called gufm-sat, are based on CHAMP, Ørsted and SAC-C satellite observations along with annual differences of processed observatory monthly means. A spatial parametrization of spherical harmonics up to degree and order 24 and a temporal parametrization of sixth-order B-splines with 0.25 yr knot spacing is employed. Models were constructed by minimizing an absolute deviation measure of misfit along with measures of spatial and temporal complexity at the core surface. We investigate traditional quadratic or maximum entropy regularization in space, and second or third time derivative regularization in time. Entropy regularization allows the construction of models with approximately constant spectral slope at the core surface, avoiding both the divergence characteristic of the crustal field and the unrealistic rapid decay typical of quadratic regularization at degrees above 12. We describe in detail aspects of the models that are relevant to core dynamics. Secular variation and secular acceleration are found to be of lower amplitude under the Pacific hemisphere where the core field is weaker. Rapid field evolution is observed under the eastern Indian Ocean associated with the growth and drift of an intense low latitude flux patch. We also find that the present axial dipole decay arises from a combination of subtle changes in the southern hemisphere field morphology.

Magnetic field effects on plant growth, development, and evolution

PubMed Central

Maffei, Massimo E.

2014-01-01

The geomagnetic field (GMF) is a natural component of our environment. Plants, which are known to sense different wavelengths of light, respond to gravity, react to touch and electrical signaling, cannot escape the effect of GMF. While phototropism, gravitropism, and tigmotropism have been thoroughly studied, the impact of GMF on plant growth and development is not well-understood. This review describes the effects of altering magnetic field (MF) conditions on plants by considering plant responses to MF values either lower or higher than those of the GMF. The possible role of GMF on plant evolution and the nature of the magnetoreceptor is also discussed. PMID:25237317

Temperature dependence of the isotope chemistry of the heavy elements.

PubMed Central

Bigeleisen, J

1996-01-01

The temperature coefficient of equilibrium isotope fractionation in the heavy elements is shown to be larger at high temperatures than that expected from the well-studied vibrational isotope effects. The difference in the isotopic behavior of the heavy elements as compared with the light elements is due to the large nuclear isotope field shifts in the heavy elements. The field shifts introduce new mechanisms for maxima, minima, crossovers, and large mass-independent isotope effects in the isotope chemistry of the heavy elements. The generalizations are illustrated by the temperature dependence of the isotopic fractionation in the redox reaction between U(VI) and U(IV) ions. PMID:8790340

EVOLUTION OF THE MAGNETIC FIELD LINE DIFFUSION COEFFICIENT AND NON-GAUSSIAN STATISTICS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Snodin, A. P.; Ruffolo, D.; Matthaeus, W. H.

The magnetic field line random walk (FLRW) plays an important role in the transport of energy and particles in turbulent plasmas. For magnetic fluctuations that are transverse or almost transverse to a large-scale mean magnetic field, theories describing the FLRW usually predict asymptotic diffusion of magnetic field lines perpendicular to the mean field. Such theories often depend on the assumption that one can relate the Lagrangian and Eulerian statistics of the magnetic field via Corrsin’s hypothesis, and additionally take the distribution of magnetic field line displacements to be Gaussian. Here we take an ordinary differential equation (ODE) model with thesemore » underlying assumptions and test how well it describes the evolution of the magnetic field line diffusion coefficient in 2D+slab magnetic turbulence, by comparisons to computer simulations that do not involve such assumptions. In addition, we directly test the accuracy of the Corrsin approximation to the Lagrangian correlation. Over much of the studied parameter space we find that the ODE model is in fairly good agreement with computer simulations, in terms of both the evolution and asymptotic values of the diffusion coefficient. When there is poor agreement, we show that this can be largely attributed to the failure of Corrsin’s hypothesis rather than the assumption of Gaussian statistics of field line displacements. The degree of non-Gaussianity, which we measure in terms of the kurtosis, appears to be an indicator of how well Corrsin’s approximation works.« less

Shape coexistence, shape evolution and Gamow-Teller {beta}-decay of neutron-rich A Asymptotically-Equal-To 100 nuclei

DOE Office of Scientific and Technical Information (OSTI.GOV)

Petrovici, A.; Schmid, K. W.; Faessler, A.

The structure of neutron-rich nuclei in the A Asymptotically-Equal-To 100 mass region relevant for the astrophysical r process manifests drastic changes in some isotopic chains and often sudden variations of particular nuclear properties have been identified. For a realistic description of the evolution in structure with increasing energy, spin, and isospin determined by shape coexistence and mixing beyond-mean-field approaches are required. Our recent studies represent an attempt to the self-consistent description of the shape coexistence phenomena in neutron-rich A Asymptotically-Equal-To 100 nuclei within the complex Excited Vampir variational model with symmetry projection before variation using a realistic effective interaction basedmore » on the Bonn A potential in a large model space. Results concerning the triple shape coexistence and the shape evolution in the N=58 Sr and Zr isotopes, the shape evolution in a chain of Zr nuclei, as well as the Gamow-Teller {beta}-decay properties of neutron-rich Zr and Tc nuclei are presented.« less

COMPOUND-SPECIFIC CARBON AND HYDROGEN ISOTOPE ANALYSIS-FIELD EVIDENCE OF MTBE BIOREMEDIATION

EPA Science Inventory

Chemical reactions (including bio- and abiotic degradation) tend to favor molecules with the lighter isotopic species (e.g., 12C, 1H), resulting in enrichment of the heavier isotopic species (13C, D) in the unreacted substrate, referred to as isotopic fractionation. On the other ...

Do Hf isotopes in magmatic zircons represent those of their host rocks?

NASA Astrophysics Data System (ADS)

Wang, Di; Wang, Xiao-Lei; Cai, Yue; Goldstein, Steven L.; Yang, Tao

2018-04-01

Lu-Hf isotopic system in zircon is a powerful and widely used geochemical tracer in studying petrogenesis of magmatic rocks and crustal evolution, assuming that zircon Hf isotopes can represent initial Hf isotopes of their parental whole rock. However, this assumption may not always be valid. Disequilibrium partial melting of continental crust would preferentially melt out non-zircon minerals with high time-integrated Lu/Hf ratios and generate partial melts with Hf isotope compositions that are more radiogenic than those of its magma source. Dissolution experiments (with hotplate, bomb and sintering procedures) of zircon-bearing samples demonstrate this disequilibrium effect where partial dissolution yielded variable and more radiogenic Hf isotope compositions than fully dissolved samples. A case study from the Neoproterozoic Jiuling batholith in southern China shows that about half of the investigated samples show decoupled Hf isotopes between zircons and the bulk rocks. This decoupling could reflect complex and prolonged magmatic processes, such as crustal assimilation, magma mixing, and disequilibrium melting, which are consistent with the wide temperature spectrum from ∼630 °C to ∼900 °C by Ti-in-zircon thermometer. We suggest that magmatic zircons may only record the Hf isotopic composition of their surrounding melt during crystallization and it is uncertain whether their Hf isotopic compositions can represent the primary Hf isotopic compositions of the bulk magmas. In this regard, using zircon Hf isotopic compositions to trace crustal evolution may be biased since most of these could be originally from disequilibrium partial melts.

Effects of the Stark Shift on the Evolution of the Field Entropy and Entanglement in the Two-Photon Jaynes-Cummings Model

NASA Technical Reports Server (NTRS)

Fang, Mao Fa

1996-01-01

The evolution of the field entropy in the two-photon JCM in the presence of the Stark shift is investigated, and the effects of the dynamic Stark shift on the evolution of the field entropy and entanglement between the atom and field, are examined. The results show that the dynamic Stark shift plays an important role in the evolution of the field entropy in two-photon processes.

Geochemical and NdSr isotopic composition of deep-sea turbidites: Crustal evolution and plate tectonic associations

NASA Astrophysics Data System (ADS)

McLennan, S. M.; Taylor, S. R.; McCulloch, M. T.; Maynard, J. B.

1990-07-01

turbidites in several important ways. Modern turbidites have less uniformity, for example, in Th/Sc ratios. On average, modern turbidites have greater depletions in Eu (lower Eu/Eu ∗) than do Archean turbidites, suggesting that the processes of intracrustal differentiation (involving plagioclase fractionation) are of greater importance for crustal evolution at modern continental margins than they were during the Archean. Modern turbidites do not display HREE depletion, a feature commonly seen in Archean data. HREE depletion ( Gd N/Yb N > 2.0 ) in Archean sediments results from incorporation of felsic igneous rocks that were in equilibrium (or their sources were in equilibrium) with garnet sometime in their history. Absence of HREE depletion at modern continental margins suggests that processes of crust formation (or mantle source compositions) may have differed. Differences in trace element abundances for Archean and modern turbidites add support to suggestions that upper continental crust compositions and major processes responsible for continental crust differentiation differed during the Archean. Neodymium model ages, thought to approximate average provenance age, are highly variable ( TDMND = 0-2.6 Ga) in modern turbidites, in contrast with studies that indicate Nd-model ages of lithified Phanerozoic sediment are fairly constant at about 1.5-2.0 Ga. This variability indicates that continental margin sediments incorporate new mantle-derived components, as well as continental crust of widely varying age, during recycling. The apparent dearth of ancient sediments with Nd-model age similar to stratigraphic age supports the suggestion that preservation potential of sediments is related to tectonic setting. Many samples from active settings have isotopic compositions similar to or only slightly evolved from mantle-derived igneous rocks. Subduction of active margin turbidites should be considered in models of crust-mantle recycling. For short-term recycling, such as that

Seasonal progression of uranium series isotopes in subglacial meltwater: Implications for subglacial storage time

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arendt, Carli A.; Aciego, Sarah M.; Sims, Kenneth W. W.

The residence time of subglacial meltwater impacts aquifer recharge, nutrient production, and chemical signals that reflect underlying bedrock/substrate, but is inaccessible to direct observation. We report the seasonal evolution of subglacial meltwater chemistry from the 2011 melt season at the terminus of the Athabasca Glacier, Canada. We also measured major and trace analytes and U-series isotopes for twenty-nine bulk meltwater samples collected over the duration of the melt season. This dataset, which is the longest time-series record of ( 234U/ 238U) isotopes in a glacial meltwater system, provides insight into the hydrologic evolution of the subglacial system during active melting.more » Meltwater samples, measured from the outflow, were analyzed for ( 238U), ( 222Rn) and ( 234U/ 238U)activity, conductivity, alkalinity, pH and major cations. Subglacial meltwater varied in [238U] and (222Rn) from 23 to 832 ppt and 9 to 171 pCi/L, respectively. Activity ratios of ( 234U/ 238U) ranged from 1.003 to 1.040, with the highest ( 238U), ( 222Rn) and ( 234U/ 238U)activity values occurring in early May when delayed-flow basal meltwater composed a significant portion of the bulk melt. Furthemore, from the chemical evolution of the meltwater, we posit that the relative subglacial water residence times decrease over the course of the melt season. This decrease in qualitative residence time during active melt is consistent with prior field studies and model-predicted channel switching from a delayed, distributed network to a fast, channelized network flow. As such, our study provides support for linking U-series isotopes to storage lengths of meltwater beneath glacial systems as subglacial hydrologic networks evolve with increased melting and channel network efficiency.« less

Seasonal progression of uranium series isotopes in subglacial meltwater: Implications for subglacial storage time

DOE PAGES

Arendt, Carli A.; Aciego, Sarah M.; Sims, Kenneth W. W.; ...

2017-07-31

The residence time of subglacial meltwater impacts aquifer recharge, nutrient production, and chemical signals that reflect underlying bedrock/substrate, but is inaccessible to direct observation. We report the seasonal evolution of subglacial meltwater chemistry from the 2011 melt season at the terminus of the Athabasca Glacier, Canada. We also measured major and trace analytes and U-series isotopes for twenty-nine bulk meltwater samples collected over the duration of the melt season. This dataset, which is the longest time-series record of ( 234U/ 238U) isotopes in a glacial meltwater system, provides insight into the hydrologic evolution of the subglacial system during active melting.more » Meltwater samples, measured from the outflow, were analyzed for ( 238U), ( 222Rn) and ( 234U/ 238U)activity, conductivity, alkalinity, pH and major cations. Subglacial meltwater varied in [238U] and (222Rn) from 23 to 832 ppt and 9 to 171 pCi/L, respectively. Activity ratios of ( 234U/ 238U) ranged from 1.003 to 1.040, with the highest ( 238U), ( 222Rn) and ( 234U/ 238U)activity values occurring in early May when delayed-flow basal meltwater composed a significant portion of the bulk melt. Furthemore, from the chemical evolution of the meltwater, we posit that the relative subglacial water residence times decrease over the course of the melt season. This decrease in qualitative residence time during active melt is consistent with prior field studies and model-predicted channel switching from a delayed, distributed network to a fast, channelized network flow. As such, our study provides support for linking U-series isotopes to storage lengths of meltwater beneath glacial systems as subglacial hydrologic networks evolve with increased melting and channel network efficiency.« less

Sr isotopic composition of Afar volcanics and its implication for mantle evolution

NASA Astrophysics Data System (ADS)

Barberi, F.; Civetta, L.; Varet, J.

1980-10-01

Investigations of Rb-Sr systematics of basalts from the Afar depression (Ethiopia) indicate the presence of a heterogeneous mantle source region. The Sr isotopic compositions of the basalts from the Afar axial and transverse ranges identify source regions which are enriched in LIL elements and radiogenic Sr (axial ranges) and others which are relatively depleted (transverse ranges). Sr isotopic composition of basalts from the Red Sea, Gulf of Aden and Gulf of Tadjoura, which range from 0.70300 to 0.70340 are also reported and compared with the more radiogenic Afar region, which is characterized by 87Sr/ 86Sr ranging from 0.70328 to 0.70410. Available geochemical and isotopic data suggest that a relation exists between magma composition and the advancement of the rifting process through progressive lithosphere attenuation leading to continental break-up. However, the petrogenetic process is not simple and probably implies a vertically zoned mantle beneath the Afar region. Sr isotopic evidence suggests that the vertically zoned mantle is more radiogenic and enriched in LIL elements in its upper part.

Singular cosmological evolution using canonical and ghost scalar fields

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nojiri, Shin'ichi; Odintsov, S.D.; Oikonomou, V.K.

2015-09-01

We demonstrate that finite time singularities of Type IV can be consistently incorporated in the Universe's cosmological evolution, either appearing in the inflationary era, or in the late-time regime. While using only one scalar field instabilities can in principle occur at the time of the phantom-divide crossing, when two fields are involved we are able to avoid such instabilities. Additionally, the two-field scalar-tensor theories prove to be able to offer a plethora of possible viable cosmological scenarios, at which various types of cosmological singularities can be realized. Amongst others, it is possible to describe inflation with the appearance of amore » Type IV singularity, and phantom late-time acceleration which ends in a Big Rip. Finally, for completeness, we also present the Type IV realization in the context of suitably reconstructed F(R) gravity.« less

Evolution of the upper mantle beneath the southern Baikal rift zone: an Sr-Nd isotope study of xenoliths from the Bartoy volcanoes

NASA Astrophysics Data System (ADS)

Ionov, D. A.; Kramm, U.; Stosch, H.-G.

1992-06-01

Anhydrous and amphibole-bearing peridotite xenoliths occur in roughly equal quantitites in the Bartoy volcanic field about 100 km south of the southern tip of Lake Baikal in Siberia (Russia). Whole-rock samples and pure mineral separates from nine xenoliths have been analyzed for Sr and Nd isotopes in order to characterize the upper mantle beneath the southern Baikal rift zone. In an Sr-Nd isotope diagram both dry and hydrous xenoliths from Bartoy plot at the junction between the fields of MORB and ocean island basalts. This contrasts with data available on two other localities around Lake Baikal (Tariat and Vitim) where peridotites typically have Sr-Nd isotope compositions indicative of strong long-term depletion in incompatible elements. Our data indicate significant chemical and isotopic heterogeneity in the mantle beneath Bartoy that may be attributed to its position close to an ancient suture zone separating the Siberian Platform from the Mongol-Okhotsk mobile belt and occupied now by the Baikal rift. Two peridotites have clinopyroxenes depleted in light rare earth elements (LREE) with Sr and Nd model ages of about 2 Ga and seem to retain the trace element and isotopic signatures of old depleted lithospheric mantle, while all other xenoliths show different degrees of LREE-enrichment. Amphiboles and clinopyroxenes in the hydrous peridotites are in Sr-Nd isotopic disequilibrium. If this reflects in situ decay of 147Sm and 87Rb rather than heterogeneities produced by recent metasomatic formation of amphiboles then 300 400 Ma have passed since the minerals were last in equilibrium. This age range then indicates an old enrichment episode or repeated events during the Paleozoic in the lithospheric mantle initially depleted maybe ˜2 Ga ago. The Bartoy hydrous and enriched dry peridotites, therefore, are unlikely to represent fragments of a young asthenospheric bulge which, according to seismic reflection studies, reached the Moho at the axis of the Baikal rift zone

Early Proterozoic crustal evolution: Geochemical and NdPb isotopic evidence from metasedimentary rocks, southwestern North America

NASA Astrophysics Data System (ADS)

McLennan, S. M.; Hemming, S. R.; Taylor, S. R.; Eriksson, K. A.

1995-03-01

any sample. This older crustal component may be derived either by direct erosion of Archean rocks, such as the Wyoming Province, or indirectly through assimilation into Early Proterozoic igneous rocks. Although the stable shelf sedimentary rocks are derived from a provenance with similar ages as the volcanogenic turbidites, the geochemical characteristics of the provenance are significantly different. Accordingly, these data are consistent with especially rapid and widespread crustal growth and evolution in southwestern North America during the period 1.9-1.7 Ga. Several samples from the Hondo Group and Uncompahgre Formation have REE patterns that are rotated to LREE depletion and perhaps HREE enrichment. The change in REEs correlate with Mo, U, and V abundances and Pb isotopic characteristics suggesting sedimentary processes similar to those operating in black shales affected these REE patterns. REE patterns and Th/U ratios of Early Proterozoic volcanogenic turbidites examined in this and other studies differ on average from turbidites found in Archean greenstone belts. Negative Eu-anomalies are common, HREE-depletion is seen but comparatively rare, and Th/U ratios are commonly below 3.0. Accordingly, these data are consistent with models suggesting that the upper crust had a different composition in the Archean.

Standoff Detection of Uranium and its Isotopes by Femtosecond Filament Laser Ablation Molecular Isotopic Spectrometry

PubMed Central

Hartig, Kyle C.; Ghebregziabher, Isaac; Jovanovic, Igor

2017-01-01

The ability to perform not only elementally but also isotopically sensitive detection and analysis at standoff distances is impor-tant for remote sensing applications in diverse ares, such as nuclear nonproliferation, environmental monitoring, geophysics, and planetary science. We demonstrate isotopically sensitive real-time standoff detection of uranium by the use of femtosecond filament-induced laser ablation molecular isotopic spectrometry. A uranium oxide molecular emission isotope shift of 0.05 ± 0.007 nm is reported at 593.6 nm. We implement both spectroscopic and acoustic diagnostics to characterize the properties of uranium plasma generated at different filament-uranium interaction points. The resulting uranium oxide emis-sion exhibits a nearly constant signal-to-background ratio over the length of the filament, unlike the uranium atomic and ionic emission, for which the signal-to-background ratio varies significantly along the filament propagation. This is explained by the different rates of increase of plasma density and uranium oxide density along the filament length resulting from spectral and temporal evolution of the filament along its propagation. The results provide a basis for the optimal use of filaments for standoff detection and analysis of uranium isotopes and indicate the potential of the technique for a wider range of remote sensing applications that require isotopic sensitivity. PMID:28272450

ICT: isotope correction toolbox.

PubMed

Jungreuthmayer, Christian; Neubauer, Stefan; Mairinger, Teresa; Zanghellini, Jürgen; Hann, Stephan

2016-01-01

Isotope tracer experiments are an invaluable technique to analyze and study the metabolism of biological systems. However, isotope labeling experiments are often affected by naturally abundant isotopes especially in cases where mass spectrometric methods make use of derivatization. The correction of these additive interferences--in particular for complex isotopic systems--is numerically challenging and still an emerging field of research. When positional information is generated via collision-induced dissociation, even more complex calculations for isotopic interference correction are necessary. So far, no freely available tools can handle tandem mass spectrometry data. We present isotope correction toolbox, a program that corrects tandem mass isotopomer data from tandem mass spectrometry experiments. Isotope correction toolbox is written in the multi-platform programming language Perl and, therefore, can be used on all commonly available computer platforms. Source code and documentation can be freely obtained under the Artistic License or the GNU General Public License from: https://github.com/jungreuc/isotope_correction_toolbox/ {christian.jungreuthmayer@boku.ac.at,juergen.zanghellini@boku.ac.at} Supplementary data are available at Bioinformatics online. © The Author 2015. Published by Oxford University Press. All rights reserved. For Permissions, please e-mail: journals.permissions@oup.com.

Evolution of Large-Scale Magnetic Fields and State Transitions in Black Hole X-Ray Binaries

NASA Astrophysics Data System (ADS)

Wang, Ding-Xiong; Huang, Chang-Yin; Wang, Jiu-Zhou

2010-04-01

The state transitions of black hole (BH) X-ray binaries are discussed based on the evolution of large-scale magnetic fields, in which the combination of three energy mechanisms are involved: (1) the Blandford-Znajek (BZ) process related to the open field lines connecting a rotating BH with remote astrophysical loads, (2) the magnetic coupling (MC) process related to the closed field lines connecting the BH with its surrounding accretion disk, and (3) the Blandford-Payne (BP) process related to the open field lines connecting the disk with remote astrophysical loads. It turns out that each spectral state of the BH binaries corresponds to each configuration of magnetic field in BH magnetosphere, and the main characteristics of low/hard (LH) state, hard intermediate (HIM) state and steep power law (SPL) state are roughly fitted based on the evolution of large-scale magnetic fields associated with disk accretion.

Evolution of chemical and isotopic composition of inorganic carbon in a complex semi-arid zone environment: Consequences for groundwater dating using radiocarbon

NASA Astrophysics Data System (ADS)

Meredith, K. T.; Han, L. F.; Hollins, S. E.; Cendón, D. I.; Jacobsen, G. E.; Baker, A.

2016-09-01

Estimating groundwater age is important for any groundwater resource assessment and radiocarbon (14C) dating of dissolved inorganic carbon (DIC) can provide this information. In semi-arid zone (i.e. water-limited environments), there are a multitude of reasons why 14C dating of groundwater and traditional correction models may not be directly transferable. Some include; (1) the complex hydrological responses of these systems that lead to a mixture of different ages in the aquifer(s), (2) the varied sources, origins and ages of organic matter in the unsaturated zone and (3) high evaporation rates. These all influence the evolution of DIC and are not easily accounted for in traditional correction models. In this study, we determined carbon isotope data for; DIC in water, carbonate minerals in the sediments, sediment organic matter, soil gas CO2 from the unsaturated zone, and vegetation samples. The samples were collected after an extended drought, and again after a flood event, to capture the evolution of DIC after varying hydrological regimes. A graphical method (Han et al., 2012) was applied for interpretation of the carbon geochemical and isotopic data. Simple forward mass-balance modelling was carried out on key geochemical processes involving carbon and agreed well with observed data. High values of DIC and δ13CDIC, and low 14CDIC could not be explained by a simple carbonate mineral-CO2 gas dissolution process. Instead it is suggested that during extended drought, water-sediment interaction leads to ion exchange processes within the top ∼10-20 m of the aquifer which promotes greater calcite dissolution in saline groundwater. This process was found to contribute more than half of the DIC, which is from a mostly 'dead' carbon source. DIC is also influenced by carbon exchange between DIC in water and carbonate minerals found in the top 2 m of the unsaturated zone. This process occurs because of repeated dissolution/precipitation of carbonate that is dependent on

Barium isotope abundances in meteorites and their implications for early Solar System evolution

NASA Astrophysics Data System (ADS)

Bermingham, K. R.; Mezger, K.; Scherer, E. E.; Horan, M. F.; Carlson, R. W.; Upadhyay, D.; Magna, T.; Pack, A.

2016-02-01

Several nucleosynthetic processes contributed material to the Solar System, but the relative contributions of each process, the timing of their input into the solar nebula, and how well these components were homogenized in the solar nebula remain only partially constrained. The Ba isotope system is particularly useful in addressing these issues because Ba isotopes are synthesized via three nucleosynthetic processes (s-, r-, p-process). In this study, high precision Ba isotope analyses of 22 different whole rock chondrites and achondrites (carbonaceous chondrites, ordinary chondrites, enstatite chondrites, Martian meteorites, and eucrites) were performed to constrain the distribution of Ba isotopes on the regional scale in the Solar System. A melting method using aerodynamic levitation and CO2-laser heating was used to oxidize SiC, a primary carrier of Ba among presolar grains in carbonaceous chondrites. Destruction of these grains during the fusion process enabled the complete digestion of these samples. The Ba isotope data presented here are thus the first for which complete dissolution of the bulk meteorite samples was certain. Enstatite chondrites, ordinary chondrites, and all achondrites measured here possess Ba isotope compositions that are not resolved from the terrestrial composition. Barium isotope anomalies are evident in most of the carbonaceous chondrites analyzed, but the 135Ba anomalies are generally smaller than previously reported for similarly sized splits of CM2 meteorites. Variation in the size of the 135Ba anomaly is also apparent in fused samples from the same parent body (e.g., CM2 meteorites) and in different pieces from the same meteorite (e.g., Orgueil, CI). Here, we investigate the potential causes of variability in 135Ba, including the contribution of radiogenic 135Ba from the decay of 135Cs and incomplete homogenization of the presolar components on the <0.8 g sample scale.

Odd-even parity splittings and octupole correlations in neutron-rich Ba isotopes

NASA Astrophysics Data System (ADS)

Fu, Y.; Wang, H.; Wang, L.-J.; Yao, J. M.

2018-02-01

The odd-even parity splittings in low-lying parity-doublet states of atomic nuclei with octupole correlations have usually been interpreted as rotational excitations on top of octupole vibration in the language of collective models. In this paper, we report a deep analysis of the odd-even parity splittings in the parity-doublet states of neutron-rich Ba isotopes around neutron number N =88 within a full microscopic framework of beyond-mean-field multireference covariant energy density functional theory. The dynamical correlations related to symmetry restoration and quadrupole-octupole shape fluctuation are taken into account with a generator coordinate method combined with parity, particle-number, and angular-momentum projections. We show that the behavior of odd-even parity splittings is governed by the interplay of rotation, quantum tunneling, and shape evolution. Similar to 224Ra, a picture of rotation-induced octupole shape stabilization in the positive-parity states is exhibited in the neutron-rich Ba isotopes.

Crustal contamination and crystal entrapment during polybaric magma evolution at Mt. Somma-Vesuvius volcano, Italy: Geochemical and Sr isotope evidence

USGS Publications Warehouse

Piochi, M.; Ayuso, R.A.; de Vivo, B.; Somma, R.

2006-01-01

New major and trace element analyses and Sr-isotope determinations of rocks from Mt. Somma-Vesuvius volcano produced from 25 ky BP to 1944 AD are part of an extensive database documenting the geochemical evolution of this classic region. Volcanic rocks include silica undersaturated, potassic and ultrapotassic lavas and tephras characterized by variable mineralogy and different crystal abundance, as well as by wide ranges of trace element contents and a wide span of initial Sr-isotopic compositions. Both the degree of undersaturation in silica and the crystal content increase through time, being higher in rocks produced after the eruption at 472 AD (Pollena eruption). Compositional variations have been generally thought to reflect contributions from diverse types of mantle and crust. Magma mixing is commonly invoked as a fundamental process affecting the magmas, in addition to crystal fractionation. Our assessment of geochemical and Sr-isotopic data indicates that compositional variability also reflects the influence of crustal contamination during magma evolution during upward migration to shallow crustal levels and/or by entrapment of crystal mush generated during previous magma storage in the crust. Using a variant of the assimilation fractional crystallization model (Energy Conservation-Assimilation Fractional Crystallization; [Spera and Bohrson, 2001. Energy-constrained open-system magmatic processes I: General model and energy-constrained assimilation and fractional crystallization (EC-AFC) formulation. J. Petrol. 999-1018]; [Bohrson, W.A. and Spera, F.J., 2001. Energy-constrained open-system magmatic process II: application of energy-constrained assimilation-fractional crystallization (EC-AFC) model to magmatic systems. J. Petrol. 1019-1041]) we estimated the contributions from the crust and suggest that contamination by carbonate rocks that underlie the volcano (2 km down to 9-10 km) is a fundamental process controlling magma compositions at Mt. Somma

Paleoproxies: Heavy Stable Isotope Perspectives

NASA Astrophysics Data System (ADS)

Nagler, T. F.; Hippler, D.; Siebert, C.; Kramers, J. D.

2002-12-01

Recent advances in isotope ratio mass spectrometry, namely multiple collector ICP-MS and refined TIMS techniques, will significantly enhance the ability to measure heavy stable isotope fractionation, which will lead to the development of a wide array of process-identifying (bio)-geochemical tools. Thus far research in this area is not easily assessable to scientists outside the isotope field. This is due to the fact that analyzing heavy stable isotopes does not provide routine numbers which are per se true (the preciser the truer) but is still a highly experimental field. On the other hand resolving earth science problems requires specialists familiar with the environment being studied. So what is in there for paleoceanographers? In a first order approach, relating isotope variations to physical processes is straightforward. A prominent example are oxygen isotope variations with temperature. The total geological signal is of course far more complicated. At low temperatures, heavy stable isotopes variations have been reported for e.g. Ca, Cr, Fe, Cu, Zn, Mo and Tl. Fractionation mechanisms and physical parameters responsible for the observed variations are not yet resolved for most elements. Significant equilibrium isotope fractionation is expected from redox reactions of transition metals. However a difference in coordination number between two coexisting speciations of an element in the same oxidation state can also cause fractionation. Protonation of dissolved Mo is one case currently discussed. For paleoceanography studies, a principal distinction between transition metals essential for life (V to Zn plus Mo) or not will be helpful. In case of the former group, distinction between biogenic and abiogenic isotope fractionation will remain an important issue. For example, abiotic Fe redox reactions result in isotope fractionations indistinguishable in direction and magnitude from microbial effects. Only a combination of different stable isotope systems bears the

Impacts of changes in groundwater recharge on the isotopic composition and geochemistry of seasonally ice-covered lakes: insights for sustainable management

NASA Astrophysics Data System (ADS)

Arnoux, Marie; Barbecot, Florent; Gibert-Brunet, Elisabeth; Gibson, John; Noret, Aurélie

2017-11-01

Lakes are under increasing pressure due to widespread anthropogenic impacts related to rapid development and population growth. Accordingly, many lakes are currently undergoing a systematic decline in water quality. Recent studies have highlighted that global warming and the subsequent changes in water use may further exacerbate eutrophication in lakes. Lake evolution depends strongly on hydrologic balance, and therefore on groundwater connectivity. Groundwater also influences the sensitivity of lacustrine ecosystems to climate and environmental changes, and governs their resilience. Improved characterization of groundwater exchange with lakes is needed today for lake preservation, lake restoration, and sustainable management of lake water quality into the future. In this context, the aim of the present paper is to determine if the future evolution of the climate, the population, and the recharge could modify the geochemistry of lakes (mainly isotopic signature and quality via phosphorous load) and if the isotopic monitoring of lakes could be an efficient tool to highlight the variability of the water budget and quality. Small groundwater-connected lakes were chosen to simulate changes in water balance and water quality expected under future climate change scenarios, namely representative concentration pathways (RCPs) 4.5 and 8.5. Contemporary baseline conditions, including isotope mass balance and geochemical characteristics, were determined through an intensive field-based research program prior to the simulations. Results highlight that future lake geochemistry and isotopic composition trends will depend on four main parameters: location (and therefore climate conditions), lake catchment size (which impacts the intensity of the flux change), lake volume (which impacts the range of variation), and lake G index (i.e., the percentage of groundwater that makes up total lake inflows), the latter being the dominant control on water balance conditions, as revealed by

Effect of deformation on structure and reaction of Al isotopes using relativistic mean field densities in Glauber model

NASA Astrophysics Data System (ADS)

Panda, R. N.; Sharma, Mahesh K.; Panigrahi, M.; Patra, S. K.

2018-06-01

We have examined the ground state properties of Al isotopes towards the proton rich side from A = 22 to 28 using the well known relativistic mean field (RMF) formalism with NLSH parameter set. The calculated results are compared with the predictions of finite range droplet model and experimental data. The calculation is extended to estimate the reaction cross section for ^{22-28}Al as projectiles with ^{12}C as target. The incident energy of the projectiles are taken as 950 MeV/nucleon, for both spherical and deformed RMF densities as inputs in the Glauber model approximation. Further investigation of enhanced values of total reaction cross section for ^{23}Al and ^{24}Al in comparison to rest of the isotopes indicates the proton skin structure of these isotopes. Specifically, the large value of root mean square radius and total reaction cross section of ^{23}Al could not be ruled out the formation of proton halo.

Effect of deformation on structure and reaction of Al isotopes using relativistic mean field densities in Glauber model

NASA Astrophysics Data System (ADS)

Panda, R. N.; Sharma, Mahesh K.; Panigrahi, M.; Patra, S. K.

2018-02-01

We have examined the ground state properties of Al isotopes towards the proton rich side from A = 22 to 28 using the well known relativistic mean field (RMF) formalism with NLSH parameter set. The calculated results are compared with the predictions of finite range droplet model and experimental data. The calculation is extended to estimate the reaction cross section for ^{22-28} Al as projectiles with ^{12} C as target. The incident energy of the projectiles are taken as 950 MeV/nucleon, for both spherical and deformed RMF densities as inputs in the Glauber model approximation. Further investigation of enhanced values of total reaction cross section for ^{23} Al and ^{24} Al in comparison to rest of the isotopes indicates the proton skin structure of these isotopes. Specifically, the large value of root mean square radius and total reaction cross section of ^{23} Al could not be ruled out the formation of proton halo.

Evolution of the magnetic field generated by the Kelvin-Helmholtz instability

DOE Office of Scientific and Technical Information (OSTI.GOV)

Modestov, M.; Bychkov, V.; Brodin, G.

2014-07-15

The Kelvin-Helmholtz instability in an ionized plasma is studied with a focus on the magnetic field generation via the Biermann battery (baroclinic) mechanism. The problem is solved by using direct numerical simulations of two counter-directed flows in 2D geometry. The simulations demonstrate the formation of eddies and their further interaction and merging resulting in a large single vortex. In contrast to general belief, it is found that the instability generated magnetic field may exhibit significantly different structures from the vorticity field, despite the mathematically identical equations controlling the magnetic field and vorticity evolution. At later stages of the nonlinear instabilitymore » development, the magnetic field may keep growing even after the hydrodynamic vortex strength has reached its maximum and started decaying due to dissipation.« less

Lagrangian model for the evolution of turbulent magnetic and passive scalar fields

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hater, T.; Grauer, R.; Homann, H.

2011-01-15

In this Brief Report we present an extension of the recent fluid deformation (RFD) closure introduced by Chevillard and Meneveau [L. Chevillard and C. Meneveau, Phys. Rev. Lett. 97, 174501 (2006)] which was developed for modeling the time evolution of Lagrangian fluctuations in incompressible Navier-Stokes turbulence. We apply the RFD closure to study the evolution of magnetic and passive scalar fluctuations. This comparison is especially interesting since the stretching term for the magnetic field and for the gradient of the passive scalar are similar but differ by a sign such that the effect of stretching and compression by the turbulentmore » velocity field is reversed. Probability density functions (PDFs) of magnetic fluctuations and fluctuations of the gradient of the passive scalar obtained from the RFD closure are compared against PDFs obtained from direct numerical simulations.« less

Martian carbon dioxide: Clues from isotopes in SNC meteorites

NASA Technical Reports Server (NTRS)

Karlsson, H. R.; Clayton, R. N.; Mayeda, T. K.; Jull, A. J. T.; Gibson, E. K., Jr.

1993-01-01

Attempts to unravel the origin and evolution of the atmosphere and hydrosphere on Mars from isotopic data have been hampered by the impreciseness of the measurements made by the Viking Lander and by Earth-based telescopes. The SNC meteorites which are possibly pieces of the Martian surface offer a unique opportunity to obtain more precise estimates of the planet's volatile inventory and isotopic composition. Recently, we reported results on oxygen isotopes of water extracted by pyrolysis from samples of Shergotty, Zagami, Nakhla, Chassigny, Lafayette, and EETA-79001. Now we describe complementary results on the stable isotopic composition of carbon dioxide extracted simultaneously from those same samples. We will also report on C-14 abundances obtained by accelerator mass spectrometry (AMS) for some of these CO2 samples.

Presupernova Evolution of Differentially Rotating Massive Stars Including Magnetic Fields

NASA Astrophysics Data System (ADS)

Heger, A.; Woosley, S. E.; Spruit, H. C.

2005-06-01

As a massive star evolves through multiple stages of nuclear burning on its way to becoming a supernova, a complex, differentially rotating structure is set up. Angular momentum is transported by a variety of classic instabilities and also by magnetic torques from fields generated by the differential rotation. We present the first stellar evolution calculations to follow the evolution of rotating massive stars including, at least approximately, all these effects, magnetic and nonmagnetic, from the zero-age main sequence until the onset of iron-core collapse. The evolution and action of the magnetic fields is as described by Spruit in 2002, and a range of uncertain parameters is explored. In general, we find that magnetic torques decrease the final rotation rate of the collapsing iron core by about a factor of 30-50 when compared with the nonmagnetic counterparts. Angular momentum in that part of the presupernova star destined to become a neutron star is an increasing function of main-sequence mass. That is, pulsars derived from more massive stars rotate faster and rotation plays a more important role in the star's explosion. The final angular momentum of the core has been determined-to within a factor of 2-by the time the star ignites carbon burning. For the lighter stars studied, around 15 Msolar, we predict pulsar periods at birth near 15 ms, though a factor of 2 range is easily tolerated by the uncertainties. Several mechanisms for additional braking in a young neutron star, especially by fallback, are explored.

Multi-Isotopic evidence from West Eifel Xenoliths

NASA Astrophysics Data System (ADS)

Thiemens, M. M.; Sprung, P.

2015-12-01

Mantle Xenoliths from the West Eifel intraplate volcanic field of Germany provide insights into the nature and evolution of the regional continental lithospheric mantle. Previous isotope studies have suggested a primary Paleoproterozoic depletion age, a second partial melting event in the early Cambrian, and a Variscan metasomatic overprint. Textural and Sr-Nd isotopic observations further suggest two episodes of melt infiltration of early Cretaceous and Quaternary age. We have investigated anhydrous, vein-free lherzolites from this region, focusing on the Dreiser Weiher and Meerfelder Maar localities. Hand separated spinel, olivine, ortho- and clinopryoxene, along with host and bulk rocks were dissolved and purified for Rb-Sr, Sm-Nd, and Lu-Hf analysis on the Cologne/Bonn Neptune MC-ICP-MS. We find an unexpected discontinuity between mineral separates and whole rocks. While the latter have significantly more radiogenic ɛNd and ɛHf, mineral separates imply close-to chondritic compositions. Our Lu-Hf data imply resetting of the Lu-Hf systematic after 200 Ma. Given the vein-free nature of the lherzolites, this appears to date to the second youngest metasomatic episode. We suggest that markedly radiogenic Nd and Hf were introduced during the Quarternary metasomatic episode and most likely reside on grain boundaries.

Model for origin and evolution of water at volcanoes in São Miguel, Azores (Portugal), based on geochemical and isotopic data set

NASA Astrophysics Data System (ADS)

Woitischek, Julia; Dietzel, Martin; Virgílio Cruz, J.; Inguaggiato, Salvatore; Leis, Albrecht; Böttcher, Michael E.

2016-04-01

A conceptual model is presented to better constrain the origin and evolution of discharges at Sete Cidades, Fogo and Furnas Volcano, using geochemical and isotopic analyses of rock and water as well as recalculated gas composition. The evolution of thermal water clearly reveals that Na-HCO3 and Na-SO4 type of springs have their origin in meteoric water as isotope data are close to the local meteoric water line (δ 18OH2O =-3 ± 1 ‰ V-SMOW; δ DH2O= -13 ± 7 ‰ V-SMOW) with exception of a Na-Cl spring named Ferraria, Sete Cidades area (δ 18OH2O = 0.45 ‰ V-SMOW ; δ DH2O= 4.18 ‰ V-SMOW). Analysed solutions are chemical evolved by evaporation, uptake of volcanic gas, leaching of local basaltic rocks, precipitation of solids, partly admixture of sea water and/or biological activity. Following the individual concentrations supports this model e.g.: HCO3 concentration and the recalculated isotopic composition of gaseous CO2 (δ 13CCO_2 = -4 ± 2.5 ‰ V-PDB) reflect evolved magmatic CO2 uptake and the subsequent leaching progress; High SO42- concentration of up to 16.5 mmol L-1 with δ 34SSO4 = 0.35 ± 0.3 ‰ (V-CDT) reflects magmatic origin which mainly control water chemistry of boiling pools of both Fogo and Furnas lake; δ 18OSO4 = 10.5 ‰ (V-SMOW) suggests organic origin and fits together with the observation of stromatolitic structures in the related precipitates; Molar Mg/Caratio (≈ 0.77) of all thermal discharges reflects leaching of analysed local basalt (Mg/Ca≈ 0.78). Furthermore, shallow and evolved outgassing effects can be distinguished. Equilibrium temperatures for various minerals given in SI vs. T plots and further geothermometers (e.g. Na-K, Na-K-Ca geothermometers) were discussed to estimate temperatures of reservoirs.

Unexpectedly large charge radii of neutron-rich calcium isotopes

DOE PAGES

Garcia Ruiz, R. F.; Bissell, M. L.; Blaum, K.; ...

2016-02-08

Here, despite being a complex many-body system, the atomic nucleus exhibits simple structures for certain ‘magic’ numbers of protons and neutrons. The calcium chain in particular is both unique and puzzling: evidence of doubly magic features are known in 40,48Ca, and recently suggested in two radioactive isotopes, 52,54Ca. Although many properties of experimentally known calcium isotopes have been successfully described by nuclear theory, it is still a challenge to predict the evolution of their charge radii. Here we present the first measurements of the charge radii of 49,51,52Ca, obtained from laser spectroscopy experiments at ISOLDE, CERN. The experimental results aremore » complemented by state-of-the-art theoretical calculations. The large and unexpected increase of the size of the neutron-rich calcium isotopes beyond N = 28 challenges the doubly magic nature of 52Ca and opens new intriguing questions on the evolution of nuclear sizes away from stability, which are of importance for our understanding of neutron-rich atomic nuclei.« less

Microscopic description of triaxiality in Ru isotopes with covariant energy density functional theory

NASA Astrophysics Data System (ADS)

Shi, Z.; Li, Z. P.

2018-03-01

Background: Triaxiality in nuclear low-lying states has attracted great interest for many years. Recently, reduced transition probabilities for levels near the ground state in 110Ru have been measured and provided strong evidence of a triaxial shape of this nucleus. Purpose: The aim of this work is to provide a microscopic study of low-lying states for Ru isotopes with A ≈100 and to examine in detail the role of triaxiality and the evolution of quadrupole shapes with the isospin and spin degrees of freedom. Method: Low-lying excitation spectra and transition probabilities of even-even Ru isotopes are described at the beyond-mean-field level by solving a five-dimensional collective Hamiltonian with parameters determined by constrained self-consistent mean-field calculations based on the relativistic energy density functional PC-PK1. Results: The calculated energy surfaces, low-energy spectra, and intraband and interband transition rates, as well as some characteristic collective observables, such as E (4g.s . +) /E (2g.s . +) ,E (2γ+) /E (4g.s . +) , and B (E 2 ;2g.s . +→0g.s . +) and γ -band staggerings, are in good agreement with the available experimental data. Conclusions: The main features of the experimental low-lying excitation spectra and electric transition rates are well reproduced and, thus, strongly support the onset of triaxiality in the low-lying excited states of Ru isotopes around 110Ru.

Evolution of the magnetic field structure of the Crab pulsar.

PubMed

Lyne, Andrew; Graham-Smith, Francis; Weltevrede, Patrick; Jordan, Christine; Stappers, Ben; Bassa, Cees; Kramer, Michael

2013-11-01

Pulsars are highly magnetized rotating neutron stars and are well known for the stability of their signature pulse shapes, allowing high-precision studies of their rotation. However, during the past 22 years, the radio pulse profile of the Crab pulsar has shown a steady increase in the separation of the main pulse and interpulse components at 0.62° ± 0.03° per century. There are also secular changes in the relative strengths of several components of the profile. The changing component separation indicates that the axis of the dipolar magnetic field, embedded in the neutron star, is moving toward the stellar equator. This evolution of the magnetic field could explain why the pulsar does not spin down as expected from simple braking by a rotating dipolar magnetic field.

δ2H isotopic flux partitioning of evapotranspiration over a grass field following a water pulse and subsequent dry down

NASA Astrophysics Data System (ADS)

Good, Stephen P.; Soderberg, Keir; Guan, Kaiyu; King, Elizabeth G.; Scanlon, Todd M.; Caylor, Kelly K.

2014-02-01

The partitioning of surface vapor flux (FET) into evaporation (FE) and transpiration (FT) is theoretically possible because of distinct differences in end-member stable isotope composition. In this study, we combine high-frequency laser spectroscopy with eddy covariance techniques to critically evaluate isotope flux partitioning of FET over a grass field during a 15 day experiment. Following the application of a 30 mm water pulse, green grass coverage at the study site increased from 0 to 10% of ground surface area after 6 days and then began to senesce. Using isotope flux partitioning, transpiration increased as a fraction of total vapor flux from 0% to 40% during the green-up phase, after which this ratio decreased while exhibiting hysteresis with respect to green grass coverage. Daily daytime leaf-level gas exchange measurements compare well with daily isotope flux partitioning averages (RMSE = 0.0018 g m-2 s-1). Overall the average ratio of FT to FET was 29%, where uncertainties in Keeling plot intercepts and transpiration composition resulted in an average of uncertainty of ˜5% in our isotopic partitioning of FET. Flux-variance similarity partitioning was partially consistent with the isotope-based approach, with divergence occurring after rainfall and when the grass was stressed. Over the average diurnal cycle, local meteorological conditions, particularly net radiation and relative humidity, are shown to control partitioning. At longer time scales, green leaf area and available soil water control FT/FET. Finally, we demonstrate the feasibility of combining isotope flux partitioning and flux-variance similarity theory to estimate water use efficiency at the landscape scale.

Tracing fluid transfer across subduction zones using iron and zinc stable isotopes

NASA Astrophysics Data System (ADS)

Williams, H. M.; Debret, B.; Pons, M. L.; Bouilhol, P.

2016-12-01

In subduction zones, serpentinite devolatilization within the downgoing slab and the fluids released play a fundamental role in volatile transfer as well as the redox evolution of the sub-arc mantle. Constraining subduction-related serpentinite devolatilisation is essential in order to better understand of the nature and composition of slab-derived fluids and fluid/rock interactions. Fe and Zn stable isotopes can trace fluid composition and speciation as isotope partitioning is driven by changes in oxidation state, coordination, and bonding environment. In the case of serpentinite devolatilisation, Fe isotope fractionation should reflect changes in Fe redox state and the formation of Fe-Cl- and SO42- complexes (Hill et al., GCA 2010); Zn isotope fractionation should be sensitive to complexation with CO32-, HS- and SO42- anions (Fujii et al., GCA 2011). We targeted samples from Western Alps ophiolite complexes, interpreted as remnants of serpentinized oceanic lithosphere metamorphosed and devolatilized during subduction (Hattori and Guillot, G3 2007; Debret et al., Chem. Geol. 2013). A striking negative correlation is present between bulk serpentinite Fe isotope composition and Fe3+/Fetot, with the highest grade samples displaying the heaviest Fe isotope compositions and lowest Fe3+/Fetot (Debret et al., Geology, 2016). The same samples also display a corresponding variation in Zn isotopes, with the highest grade samples displaying isotopically light compositions (Pons et al., in revision). The negative correlation between Fe and Zn isotopes and decrease in Fe3+/Fetot can explained by serpentinite sulfide breakdown and the release of fluids enriched in isotopically light Fe and heavy Zn sulphate complexes. The migration of these SOX-bearing fluids from the slab to the slab-mantle interface or mantle wedge has important implications for the redox evolution of the sub-arc mantle and the transport of metals from the subducting slab.

The isotopic and chemical evolution of Mount St. Helens

USGS Publications Warehouse

Halliday, A.N.; Fallick, A.E.; Dickin, A.P.; Mackenzie, A.B.; Stephens, W.E.; Hildreth, W.

1983-01-01

Isotopic and major and trace element analysis of nine samples of eruptive products spanning the history of the Mt. St. Helens volcano suggest three different episodes; (1) 40,000-2500 years ago: eruptions of dacite with ??{lunate}Nd = +5, ??{lunate}Sr = -10, variable ??18O, 206Pb/204Pb ??? 18.76, Ca/Sr ??? 60, Rb/Ba ??? 0.1, La/Yb ??? 18, (2) 2500-1000 years ago: eruptions of basalt, andesite and dacite with ??{lunate}Nd = +4 to +8, ??{lunate}Sr = -7 to -22, variable ??18O (thought to represent melting of differing mantle-crust reservoirs), 206Pb/204Pb = 18.81-18.87, variable Ca/Sr, Rb/Ba, La/Yb and high Zr, (3) 1000 years ago to present day: eruptions of andesite and dacite with ??{lunate}Nd = +6, ??{lunate}Sr = -13, ??18O ???6???, variable 206Pb/204Pb, Ca/Sr ??? 77, Rb/Ba = 0.1, La/Yb ??? 11. None of the products exhibit Eu anomalies and all are LREE enriched. There is a strong correlation between 87Sr/86Sr and differentiation indices. These data are interpreted in terms of a mantle heat source melting young crust bearing zircon and garnet, but not feldspar, followed by intrusion of this crustal reservoir by mantle-derived magma which caused further crustal melting and contaminated the crustal magma system with mafic components. Since 1000 years ago all the eruptions have been from the same reservoir which has displayed a much more gradual re-equilibration of Pb isotopic compositions than other components suggesting that Pb is being transported via a fluid phase. The Nd and Sr isotopic compositions lie along the mantle array and suggest that the mantle underneath Mt. St. Helens is not as depleted as MORB sources. There is no indication of seawater involvement in the source region. ?? 1983.

Origin and Evolution of Magnetic Field in PMS Stars: Influence of Rotation and Structural Changes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Emeriau-Viard, Constance; Brun, Allan Sacha, E-mail: constance.emeriau@cea.fr, E-mail: sacha.brun@cea.fr

During stellar evolution, especially in the pre-main-sequence phase, stellar structure and rotation evolve significantly, causing major changes in the dynamics and global flows of the star. We wish to assess the consequences of these changes on stellar dynamo, internal magnetic field topology, and activity level. To do so, we have performed a series of 3D HD and MHD simulations with the ASH code. We choose five different models characterized by the radius of their radiative zone following an evolutionary track computed by a 1D stellar evolution code. These models characterized stellar evolution from 1 to 50 Myr. By introducing amore » seed magnetic field in the fully convective model and spreading its evolved state through all four remaining cases, we observe systematic variations in the dynamical properties and magnetic field amplitude and topology of the models. The five MHD simulations develop a strong dynamo field that can reach an equipartition state between the kinetic and magnetic energies and even superequipartition levels in the faster-rotating cases. We find that the magnetic field amplitude increases as it evolves toward the zero-age main sequence. Moreover, the magnetic field topology becomes more complex, with a decreasing axisymmetric component and a nonaxisymmetric one becoming predominant. The dipolar components decrease as the rotation rate and the size of the radiative core increase. The magnetic fields possess a mixed poloidal-toroidal topology with no obvious dominant component. Moreover, the relaxation of the vestige dynamo magnetic field within the radiative core is found to satisfy MHD stability criteria. Hence, it does not experience a global reconfiguration but slowly relaxes by retaining its mixed stable poloidal-toroidal topology.« less

Application of {sup 87}Sr/{sup 86}Sr, {delta}{sup 18}O and {delta}{sup 13}C Isotopes to diagenesis, correlation and connectivity of a fractured chalk reservoir, the Sidi El Kilani Field Tunisia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mearns, E.W.; Mcbride, J.J.; Bramwell, M.

1995-08-01

Strontium Stratigraphy Analysis of the primary matrix chalk of the Abiod Formation reservoir in the Sidi El Kilani Field indicate a Campanian to Maastrichtian age (Upper Cretaceous). A resolution of {+-}1Ma has been achieved and results suggest that there are no major stratigraphic breaks in the studied sequences. Sr-O-C isotope data from early fracture-filling calcite cements suggest they may have formed by the redistribution of CaCO{sub 3} from underlying carbonate sequences and may have precipitated at temperatures in the region of 35-55{degrees}C. The {sup 87}Sr/{sup 86}Sr isotope ratios of formation waters determined by residual salt analysis (SrRSA) suggest that themore » chemical evolution of waters during reservoir filling was controlled by the influx of basinal waters as opposed to in situ water-rock interaction. Late, fracture-filling dolomite and barite cements have Sr-O-C isotope characteristics consistent with precipitation from these migrating basinal fluids at temperatures similar to current reservoir conditions (70-75{degrees}C). Sr RSA results suggest that the reservoir section in two of the wells may have been in direct lateral communication at the time of oil emplacement. These wells however are separated by a strike-slip fault. The SrRSA results therefore suggest that the fault is a partial barrier which has restricted pressure equilibration in the relatively short timescale of oil production, but which may have allowed homogenization of Sr isotope ratios in formation water.« less

Strontium isotope systematics of mixing groundwater and oil-field brine at Goose Lake in northeastern Montana, USA

USGS Publications Warehouse

Peterman, Zell E.; Thamke, Joanna N.; Futa, Kiyoto; Preston, Todd

2012-01-01

Groundwater, surface water, and soil in the Goose Lake oil field in northeastern Montana have been affected by Cl−-rich oil-field brines during long-term petroleum production. Ongoing multidisciplinary geochemical and geophysical studies have identified the degree and local extent of interaction between brine and groundwater. Fourteen samples representing groundwater, surface water, and brine were collected for Sr isotope analyses to evaluate the usefulness of 87Sr/86Sr in detecting small amounts of brine. Differences in Sr concentrations and 87Sr/86Sr are optimal at this site for the experiment. Strontium concentrations range from 0.13 to 36.9 mg/L, and corresponding 87Sr/86Sr values range from 0.71097 to 0.70828. The local brine has 168 mg/L Sr and a 87Sr/86Sr value of 0.70802. Mixing relationships are evident in the data set and illustrate the sensitivity of Sr in detecting small amounts of brine in groundwater. The location of data points on a Sr isotope-concentration plot is readily explained by an evaporation-mixing model. The model is supported by the variation in concentrations of most of the other solutes.

New Insights Into the Genesis and Compositional Evolution of I-type Granitic magmas in the Lachlan Fold Belt (SE Australia) by in situ Hf Isotopic Analysis of Zircon

NASA Astrophysics Data System (ADS)

Kemp, T. I.; Hawkesworth, C. J.; Hergt, J. M.; Woodhead, J.

2004-05-01

Isotope studies have proved of enormous benefit in fingerprinting the source rocks of silicic magmas and tracing open system petrogenetic processes, such as crustal assimilation or magma mixing. Quantification of these processes, especially the role of mantle-derived magmas, is essential to formulating realistic models for the thermal regime and compositional evolution of the continental crust. However, this remains problematic, since whole-rock isotopic data registers the final state of the magmatic system but gives no information on the pathways by which this state was attained. For example, the eNd - initial 87Sr/86Sr isotopic array defined by the classic I- and S-type granites of the Lachlan Fold Belt has been variously interpreted to reflect (1) mixing between two end-member magmas, one depleted mantle-like, the other evolved and continental crust-like, (2) mixing between a juvenile magma and a magma sourced from mafic lower crust, accompanied by sediment assimilation, (3) derivation of the granites from mixed source rocks and (4) derivation from a sequence of protoliths of various ages and sedimentary maturity. The implications of these possibilities for crustal architecture, and whether granitic magmatism was associated with the recycling or growth of new continental crust are drastically different. One way to now resolve such ambiguities is by unravelling the isotopic information encoded in the fine-scale growth zoning of minerals such as zircon, which potentially tracks the processes operative during crystallisation. To this end we report the first laser-ablation ICP-MS study into the Hf isotope stratigraphy of zircons hosted by LFB I-type granites and their mafic enclaves. This is integrated with a prior U-Pb isotope study and trace element concentrations measured on the same zircons. Two suites were investigated, the Cobargo and Why Worry Suites of the Bega Batholith. Although the bulk rock isotopic variation within these suites is restricted, this study

The calcium isotope evolution of Lake Lisan, the Dead Sea glacial precursor

NASA Astrophysics Data System (ADS)

Bradbury, H. J.; Turchyn, A. V.; Wong, K.; Torfstein, A.

2016-12-01

Calcium is a stoichiometric component of carbonate minerals whose calcium isotopic composition reflects changes in the calcium isotope composition of the water from which it precipitates as well as the calcium isotope fractionation factor during precipitation. The lacustrine deposits of the last glacial Dead Sea (Lisan Formation) are dominated by carbonate minerals (aragonite) that record the geochemical history of the lake. The sediment sequence comprises alternating laminae of aragonite and clay-rich marls, interspersed with primary gypsum beds and disseminated secondary gypsum crystals. The aragonite precipitated annually during high lake stands associated with wet periods, while the primary gypsum precipitated during low lake conditions (arid periods). We report the calcium isotopic composition (δ44Ca in ‰ relative to bulk silicate earth) of primary aragonite laminae, primary gypsum and secondary gypsum at 1-5kyr resolution throughout the Lisan Formation sampled at the Masada section (70 - 14.5 ka). The δ44Ca of the primary gypsum averages +0.29‰, and displays smaller temporal variations than the aragonite, which averages -0.35‰ but ranges between +0.18‰ and -0.68‰. The aragonite δ44Ca changes temporally in sync with the previously reconstructed lake level suggesting the aragonite δ44Ca reflects changes in the lake calcium balance during lake level changes. The secondary gypsum composition (-0.3‰) corresponds to coeval aragonite samples. For the secondary gypsum to have a similar δ44Ca to the aragonite it is likely that the calcium derived from the aragonite in a near quantitative fashion through recrystallization of the aragonite to gypsum. A numerical box model is used to explore the effect of changing lake water levels on the calcium isotope composition of the aragonite and gypsum over the time interval studied.

Microbes: Agents of Isotopic Change

NASA Astrophysics Data System (ADS)

Fogel, M. L.

2012-12-01

Microbes drive many of the important oxidation and reduction reactions on Earth; digest almost all forms of organic matter; and can serve as both primary and secondary producers. Because of their versatile biochemistry and physiology, they impart unique isotopic signatures to organic and inorganic materials, which have proven to be key measurements for understanding elemental cycling now and throughout Earth's history. Understanding microbial isotope fractionations in laboratory experiments has been important for interpreting isotopic patterns measured in natural settings. In fact, the pairing of simple experiment with natural observation has been the pathway for interpreting the fingerprint of microbial processes in ancient sediments and rocks. Examples of how key experiments have explained stable isotope fractionations by microbes and advanced the field of microbial ecology will be presented. Learning the isotopic signatures of Earth's microbes is a valuable exercise for predicting what isotopic signatures could be displayed by possible extant or extinct extraterrestrial life. Given the potential for discovery on Mars, Enceladus, and other solar system bodies, new methods and techniques for pinpointing what is unique about microbial isotope signatures is particularly relevant.

Mass-independent isotope fractionation of Mo, Ru, Cd, and Te

NASA Astrophysics Data System (ADS)

Fujii, T.; Moynier, F.; Albarède, F.

2006-12-01

The variation of the mean charge distribution in the nucleus with the neutron number of different isotopes induces a tenuous shift of the nuclear field. The mass fractionation induced during phase changes is irregular, notably with 'staggering' between odd and even masses, and becomes increasingly non-linear for neutron-rich isotopes. A strong correlation is observed between the deviation of the isotopic effects from the linear dependence with mass and the corresponding nuclear charge radii. We first demonstrated on a number of elements the existence of such mass-independent isotope fractionation in laboratory experiments of solvent extraction with a macrocyclic compound. The isotope ratios were analyzed by multiple-collector inductively coupled plasma mass spectrometry with a typical precision of <100 ppm. The isotopes of odd and even atomic masses are enriched in the solvent to an extent that closely follows the variation of their nuclear charge radii. The present results fit Bigeleisen's (1996) model, which is the standard mass-dependent theory modified to include a correction term named the nuclear field shift effect. For heavy elements like uranium, the mass-independent effect is important enough to dominate the mass-dependent effect. We subsequently set out to compare the predictions of Bigeleisen's theory with the isotopic anomalies found in meteorites. Some of these anomalies are clearly inconsistent with nucleosynthetic effects (either s- or r-processes). Isotopic variations of Mo and Ru in meteorites, especially in Allende (CV3), show a clear indication of nucleosynthetic components. However, the mass-independent anomaly of Ru observed in Murchison (CM2) is a remarkable exception which cannot be explained by the nucleosynthetic model, but fits the nuclear field shift theory extremely well. The abundances of the even atomic mass Te isotopes in the leachates of carbonaceous chondrites, Allende, Murchison, and Orgueil, fit a mass-dependent law well, but the

Assessing Past Fracture Connectivity in Geothermal Reservoirs Using Clumped Isotopes: Proof of Concept in the Blue Mountain Geothermal Field, Nevada USA

NASA Astrophysics Data System (ADS)

Huntington, K. W.; Sumner, K. K.; Camp, E. R.; Cladouhos, T. T.; Uddenberg, M.; Swyer, M.; Garrison, G. H.

2015-12-01

Subsurface fluid flow is strongly influenced by faults and fractures, yet the transmissivity of faults and fractures changes through time due to deformation and cement precipitation, making flow paths difficult to predict. Here we assess past fracture connectivity in an active hydrothermal system in the Basin and Range, Nevada, USA, using clumped isotope geochemistry and cold cathodoluminescence (CL) analysis of fracture filling cements from the Blue Mountain geothermal field. Calcite cements were sampled from drill cuttings and two cores at varying distances from faults. CL microscopy of some of the cements shows banding parallel to the fracture walls as well as brecciation, indicating that the cements record variations in the composition and source of fluids that moved through the fractures as they opened episodically. CL microscopy, δ13C and δ18O values were used to screen homogeneous samples for clumped isotope analysis. Clumped isotope thermometry of most samples indicates paleofluid temperatures of around 150°C, with several wells peaking at above 200°C. We suggest that the consistency of these temperatures is related to upwelling of fluids in the convective hydrothermal system, and interpret the similarity of the clumped isotope temperatures to modern geothermal fluid temperatures of ~160-180°C as evidence that average reservoir temperatures have changed little since precipitation of the calcite cements. In contrast, two samples, one of which was associated with fault gauge observed in drill logs, record significantly cooler temperatures of 19 and 73°C and anomalous δ13C and δ18Owater values, which point to fault-controlled pathways for downwelling meteoric fluid. Finally, we interpret correspondence of paleofluid temperatures and δ18Owater values constrained by clumped isotope thermometry of calcite from different wells to suggest past connectivity of fractures among wells within the geothermal field. Results show the ability of clumped isotope

A quantum cascade laser infrared spectrometer for CO2 stable isotope analysis: Field implementation at a hydrocarbon contaminated site under bio-remediation.

PubMed

Guimbaud, Christophe; Noel, Cécile; Chartier, Michel; Catoire, Valéry; Blessing, Michaela; Gourry, Jean Christophe; Robert, Claude

2016-02-01

Real-time methods to monitor stable isotope ratios of CO2 are needed to identify biogeochemical origins of CO2 emissions from the soil-air interface. An isotope ratio infra-red spectrometer (IRIS) has been developed to measure CO2 mixing ratio with δ(13)C isotopic signature, in addition to mixing ratios of other greenhouse gases (CH4, N2O). The original aspects of the instrument as well as its precision and accuracy for the determination of the isotopic signature δ(13)C of CO2 are discussed. A first application to biodegradation of hydrocarbons is presented, tested on a hydrocarbon contaminated site under aerobic bio-treatment. CO2 flux measurements using closed chamber method is combined with the determination of the isotopic signature δ(13)C of the CO2 emission to propose a non-intrusive method to monitor in situ biodegradation of hydrocarbons. In the contaminated area, high CO2 emissions have been measured with an isotopic signature δ(13)C suggesting that CO2 comes from petroleum hydrocarbon biodegradation. This first field implementation shows that rapid and accurate measurement of isotopic signature of CO2 emissions is particularly useful in assessing the contribution of contaminant degradation to the measured CO2 efflux and is promising as a monitoring tool for aerobic bio-treatment. Copyright © 2016. Published by Elsevier B.V.

Formation and Evolution of the Continental Lithospheric Mantle: Perspectives From Radiogenic Isotopes of Silicate and Sulfide Inclusions in Macrodiamonds

NASA Astrophysics Data System (ADS)

Shirey, S. B.; Richardson, S. H.

2007-12-01

Silicate and sulfide inclusions that occur in diamonds comprise the oldest (>3 Ga), deepest (>140 km) samples of mantle-derived minerals available for study. Their relevance to the evolution of the continental lithosphere is clear because terrestrial macrodiamonds are confined to regions of the Earth with continental lithospheric mantle keels. The goals of analytical work on inclusions in diamond are to obtain paragenesis constraints, radiogenic ages, and initial isotopic compositions. The purpose is to place diamond formation episodes into the broader framework of the geological processes that create and modify the continental lithosphere and to relate the source of the C and N in diamond-forming fluids to understanding the Earth's C and N cycles in the Archean. Although sulfide and silicate inclusions rarely occur in the same diamond, they both can be grouped according to their geochemical similarity with the chief rock types that comprise the mantle keel: peridotite and eclogite. Silicate inclusions are classified as harzburgitic (depleted; olivine > Fo91, garnet Cr2O3 > 3 wt% and CaO from 0 to 5 wt%), lherzolitic (fertile), or eclogitic (basaltic; garnet Cr2O3 < 2 wt% and CaO from 3 to 15 wt%, clinopyroxene with higher Na2O, Al2O3, and FeO); they are amenable for trace element study by SIMS and for Sm-Nd and Rb-Sr analysis by conventional P-TIMS after grouping by mineralogical similarity. Sulfide inclusions (chiefly FeS with lesser Ni, Cu, and Co) are classified as peridotitic (Ni > 14 wt%; Os > 2 ppm) versus eclogitic (Ni < 10 wt%; Os < 200 ppb); single sulfides are amenable for S isotopic study by SIMS or TIMS, and Re-Os analysis by N-TIMS. Work on inclusions in diamonds depends on the distribution of mined, diamond-bearing kimberlites, and the generosity of mining companies because of the extreme rarity of inclusions in suites of mostly gem-quality diamonds. Most isotopic work has been on the Kaapvaal-Zimbabwe craton with lesser work on the Slave, Siberian

Osmium isotope variations in the oceans recorded by Fe-Mn crusts

USGS Publications Warehouse

Burton, K.W.; Bourdon, B.; Birck, J.-L.; Allegre, C.J.; Hein, J.R.

1999-01-01

This study presents osmium (Os) isotope data for recent growth surfaces of hydrogenetic ferromanganese (Fe-Mn) crusts from the Pacific, Atlantic and Indian Oceans. In general, these data indicate a relatively uniform Os isotopic composition for modern seawater, but suggest that North Atlantic seawater is slightly more radiogenic than that of the Pacific and Indian Oceans. The systematic difference in the Os isotopic composition between the major oceans probably reflects a greater input of old continental material with a high Re/Os ratio in the North Atlantic Ocean, consistent with the distribution of Nd and Pb isotopes. This spatial variation in the Os isotope composition in seawater is consistent with a residence time for Os of between 2 and 60 kyr. Indian Ocean samples show no evidence of a local source of radiogenic Os, which suggests that the present-day riverine input from the Himalaya-Tibet region is not a major source for Os. Recently formed Fe-Mn crusts from the TAG hydrothermal field in the North Atlantic yield an Os isotopic composition close to that of modern seawater, which indicates that, in this area, the input of unradiogenic Os from the hydrothermal alteration of oceanic crust is small. However, some samples from the deep Pacific (???4 km) possess a remarkably unradiogenic Os isotope composition (187Os/186Os ratios as low as 4.3). The compositional control of Os incorporation into the crusts and mixing relationships suggest that this unradiogenic composition is most likely due to the direct incorporation of micrometeoritic or abyssal peridotite particles, rather than indicating the presence of an unradiogenic deep-water mass. Moreover, this unradiogenic signal appears to be temporary, and local, and has had little apparent effect on the overall evolution of seawater. These results confirm that input of continental material through erosion is the dominant source of Os in seawater, but it is not clear whether global Os variations are due to the input

Assessing the isotopic evolution of S-type granites of the Carlos Chagas Batholith, SE Brazil: Clues from U-Pb, Hf isotopes, Ti geothermometry and trace element composition of zircon

NASA Astrophysics Data System (ADS)

Melo, Marilane G.; Lana, Cristiano; Stevens, Gary; Pedrosa-Soares, Antônio C.; Gerdes, Axel; Alkmin, Leonardo A.; Nalini, Hermínio A.; Alkmim, Fernando F.

2017-07-01

The Carlos Chagas batholith (CCB) is a very large ( 14,000 km2) S-type granitic body formed during the syn-collisional stage of the Araçuaí orogen (southeastern Brazil). Zircons extracted from the CCB record a wide range of U-Pb ages (from 825 to 490 Ma), indicating a complex history of inheritance, magmatic crystallization and partial melting during the evolution of the orogeny. Magmatic zircons (ca. 578-588 Ma) are marked by similar Hf isotope compositions and REE patterns to those of inherited cores (ca. 825-600 Ma), indicating that these aspects of the chemical signature of the magmatic zircons have likely been inherited from the source. The U-Pb ages and initial 176Hf/177Hf ratios from anatectic and metamorphic zircon domains are consistent with a two-stage metamorphic evolution marked by contrasting mechanisms of zircon growth and recrystallization during the orogeny. Ti-in-zircon thermometry is consistent with the findings of previous metamorphic work and indicates that the two metamorphic events in the batholith reached granulite facies conditions (> 800 °C) producing two generations of garnet via fluid-absent partial melting reactions. The oldest metamorphic episode (ca. 570-550 Ma) is recorded by development of thin anatectic overgrowths on older cores and by growth of new anatectic zircon crystals. Both domains have higher initial 176Hf/177Hf values compared to relict cores and display REE patterns typical of zircon that grew contemporaneously with peritectic garnet through biotite-absent fluid partial melting reactions. Hf isotopic and chemical evidences indicate that a second anatectic episode (ca. 535-500 Ma) is only recorded in parts from the CCB. In these rocks, the growth of new anatectic zircon and/or overgrowths is marked by high initial 176Hf/177Hf values and also by formation of second generation of garnet, as indicated by petrographic observations and REE patterns. In addition, some rocks contain zircon crystals formed by solid

Isotopic and noble gas geochemistry in geothermal research

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kennedy, B.M.; DePaolo, D.J.

1997-12-31

The objective of this program is to provide, through isotopic analyses of fluids, fluid inclusions, and rocks and minerals coupled with improved methods for geochemical data analysis, needed information regarding sources of geothermal heat and fluids, the spatial distribution of fluid types, subsurface flow, water-rock reaction paths and rates, and the temporal evolution of geothermal systems. Isotopic studies of geothermal fluids have previously been limited to the light stable isotopes of H, C, and O. However, other isotopic systems such as the noble gases (He, Ne, Ar, Kr and Xe) and reactive elements (e.g. B, N, S, Sr and Pb)more » are complementary and may even be more important in some geothermal systems. The chemistry and isotopic composition of a fluid moving through the crust will change in space and time in response to varying chemical and physical parameters or by mixing with additional fluids. The chemically inert noble gases often see through these variations, making them excellent tracers for heat and fluid sources. Whereas, the isotopic compositions of reactive elements are useful tools in characterizing water-rock interaction and modeling the movement of fluids through a geothermal reservoir.« less

Optical magnetic resonances induced by the interference of reactive components in the near radiation-field zone of atoms in a glow discharge of a mixture of even neon isotopes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saprykin, E. G., E-mail: Saprykin@gorodok.net

2016-02-15

Four types of anomalous optical magnetic resonances shifted with respect to the zero magnetic field and with different shapes are found in radiation of a glow discharge in a mixture of even neon isotopes placed in a swept longitudinal magnetic field. This testifies to the manifestation of collective processes of synchronous light emission by oscillators belonging to isotopically different spatially separated atoms in discharge plasma. The origin of resonances is associated with nonstationary interference of reactive fields in the near radiation-field zones of emission of atoms, averaged over the lifetime of the fields (interference), while different types of resonances aremore » associated with different methods of synchronization of the phases of the fields.« less

First field determination of the 13C/12C isotope ratio in volcanic CO2 by diode-laser.

PubMed

Castrillo, A; Casa, G; van Burgel, M; Tedesco, D; Gianfrani, L

2004-12-27

Carbon isotope ratio analysis using a laser-based technique has been performed in the field, on the gaseous emissions from an active volcano. We here describe that 13CO2/12CO2 determinations can be carried out in a quasi-continuous regime using a compact, selective and sensitive diode laser spectrometer at a wavelength of 2 mum. Within the Solfatara crater (near Naples, Italy), in a very harsh environment, we were able to determine relative 13CO2/12CO2 values, on the highest flux fumarole, with an accuracy of 0.5 per thousand. Regular and frequent observations of the carbon isotopes in volcanic gases, which become possible with our methodology, are of the utmost importance for geochemical surveillance of volcanoes.

Applications of stable isotopes in hydrological studies of Mt. Apo geothermal field, Philippines

DOE Office of Scientific and Technical Information (OSTI.GOV)

Salonga, N.D.; Aragon, G.M.; Nogara, J.B.

1996-12-31

The local precipitation in Mt. Apo is depleted of heavy isotopes owing to high elevation and landward location of the field. Rainwaters infiltrate the shallow grounds, circulate in short distances with almost no interaction with the host bed rocks, and effuse in the surface as cold springs. Lakes and rivers are affected by surface evaporation while the acid SO{sub 4} springs are affected by both evaporation and steam-heating. Only the neutral-pH Cl springs have the signature of the deep thermal fluids. The parent fluids of the deep thermal brine contain Cl of 4,800 to 5,000 mg/kg, {delta}{sup 18}O of -4.62more » to -4.13 {per_thousand} and {delta}{sup 2}H of -60.0 to -57.8 {per_thousand}. Inside the Sandawa Collapse, boiling of the parent fluids resulted in a two-phase reservoir with lighter isotope contents. The thermal fluids laterally flow towards the west where they are affected by cooling and mixing of cold waters. Deep water recharge has {delta}{sup 18}O of -10.00 {per_thousand} and {delta}{sup 2}H = -61.20 {per_thousand} which come from the upper slopes of Sandawa Collapse (1580-1700 mASL).« less

Methane Production Pathways in a California Rice Paddy: Isotopic Evidence for Substantial CO2 Reduction as Cause for Isotopically Light Emitted CH4 Carbon

NASA Astrophysics Data System (ADS)

Tyler, S. C.; McMillan, A. M.; Bearden, K.; Chidthaisong, A.; Macalady, J.

2003-12-01

We report measurements of δ 13C of emitted CH4 and sediment CH4 and CO2 during the 1999 rice-growing season near Maxwell, CA. Two treatments, one with rice straw incorporated from the previous season and one without rice straw were studied. The δ 13C value of emitted CH4 was consistently lighter isotopically (-67‰ to -83‰ throughout the season) in both straw incorporated and straw removed (burned) plots than in fields we have studied in Texas, Kenya, and Japan. Measured isotopic values of the production zone CH4 were compared to a two-point mixing curve representative of isotopic CH4 produced from either pure methyl-group fermentation or CO2 reduction pathways to partition the production pathways and to track seasonal changes in the production processes. Our sediment CH4 and CO2 isotope data indicate that fermentation was rarely the dominant methanogenic pathway - on the contrary CO2 reduction with H2 was more prevalent than fermentation methanogenesis throughout most of the season. The relatively isotopically light CH4 emitted by the paddy fields is also a product of oxidation and stem-transport processes which have isotopic effects of their own. These effects are discussed in context with the methanogenic isotope effects to provide a complete picture of the paddy field CH4 carbon isotope system.

Fossil black smoker yields oxygen isotopic composition of Neoproterozoic seawater.

PubMed

Hodel, F; Macouin, M; Trindade, R I F; Triantafyllou, A; Ganne, J; Chavagnac, V; Berger, J; Rospabé, M; Destrigneville, C; Carlut, J; Ennih, N; Agrinier, P

2018-04-13

The evolution of the seawater oxygen isotopic composition (δ 18 O) through geological time remains controversial. Yet, the past δ 18 O seawater is key to assess past seawater temperatures, providing insights into past climate change and life evolution. Here we provide a new and unprecedentedly precise δ 18 O value of -1.33 ± 0.98‰ for the Neoproterozoic bottom seawater supporting a constant oxygen isotope composition through time. We demonstrate that the Aït Ahmane ultramafic unit of the ca. 760 Ma Bou Azzer ophiolite (Morocco) host a fossil black smoker-type hydrothermal system. In this system we analyzed an untapped archive for the ocean oxygen isotopic composition consisting in pure magnetite veins directly precipitated from a Neoproterozoic seawater-derived fluid. Our results suggest that, while δ 18 O seawater and submarine hydrothermal processes were likely similar to present day, Neoproterozoic oceans were 15-30 °C warmer on the eve of the Sturtian glaciation and the major life diversification that followed.

Flux Chamber Measurements of Methane Emissions and Stable Isotope Composition from an Arctic Wetland Using Field-Deployed Real-Time CRDS Vs Lab Measurements

NASA Astrophysics Data System (ADS)

Thompson, H. A.; Stern, J. C.; Graham, H. V.; Pratt, L. M.; White, J. R.

2014-12-01

The emission of CH4 from Arctic landscapes under warming climate is an important feedback in Earth's climate system. Studies of CH4 flux from Arctic wetlands have been growing in recent years, but few provide details on biogeochemical controls. Stable isotopic measurements help elucidate methane production and consumption pathways and offer important understanding about dynamics of CH4 cycling in Arctic systems. In order to demonstrate the possible instrumental approaches to measuring methane dynamics of wetlands in the Arctic, a fringing wetland of a small lake near the Russell Glacier in Southwestern Greenland was outfitted with static flux chambers and instrumented with a field-deployable Cavity Ring Down Spectrometer (CRDS) to measure real-time concentrations of CH4 and CO2 and their stable carbon isotopes. Several different wetland plant communities were included in the flux chamber experiments and field tests were conducted during several weeks in July 2014. Analytical measurements by CRDS were compared to batch samples analyzed in the laboratory using both Off-Axis Integrated Cavity Output Spectroscopy (ICOS) and Gas Chromatography-Combustion-Isotope Ratio Mass Spectrometry (GC-C-IRMS) with cryogenic pre-concentration. Results from flux chamber deployments will be presented and comparisons between the real-time field measurements and laboratory instrumental techniques will be evaluated.

Compilation of gas geochemistry and isotopic analyses from The Geysers geothermal field: 1978-1991

USGS Publications Warehouse

Lowenstern, Jacob B.; Janik, Cathy; Fahlquist, Lynne; Johnson, Linda S.

1999-01-01

We present 45 chemical and isotopic analyses from well discharges at The Geysers geothermal field and summarize the most notable geochemical trends. H2 and H2S concentrations are highest in the Southeast Geysers, where steam samples have δD and δ18O values that reflect replenishment by meteoric water. In the Northwest Geysers, samples are enriched in gas/steam, CO2, CH4, and N2/Ar relative to the rest of the field, and contain steam that is elevated in δD and δ18O, most likely due to substantial contributions from Franciscan-derived fluids. The δ13C of CO2, trends in CH4 vs. N2, and abundance of NH3 indicate that the bulk of the non-condensable gases are derived from thermal breakdown of organic materials in Franciscan meta-sediments.

Isotope composition and volume of Earth's early oceans.

PubMed

Pope, Emily C; Bird, Dennis K; Rosing, Minik T

2012-03-20

Oxygen and hydrogen isotope compositions of Earth's seawater are controlled by volatile fluxes among mantle, lithospheric (oceanic and continental crust), and atmospheric reservoirs. Throughout geologic time the oxygen mass budget was likely conserved within these Earth system reservoirs, but hydrogen's was not, as it can escape to space. Isotopic properties of serpentine from the approximately 3.8 Ga Isua Supracrustal Belt in West Greenland are used to characterize hydrogen and oxygen isotope compositions of ancient seawater. Archaean oceans were depleted in deuterium [expressed as δD relative to Vienna standard mean ocean water (VSMOW)] by at most 25 ± 5‰, but oxygen isotope ratios were comparable to modern oceans. Mass balance of the global hydrogen budget constrains the contribution of continental growth and planetary hydrogen loss to the secular evolution of hydrogen isotope ratios in Earth's oceans. Our calculations predict that the oceans of early Earth were up to 26% more voluminous, and atmospheric CH(4) and CO(2) concentrations determined from limits on hydrogen escape to space are consistent with clement conditions on Archaean Earth.

On the diversity of compact objects within supernova remnants - I. A parametric model for magnetic field evolution

NASA Astrophysics Data System (ADS)

Rogers, Adam; Safi-Harb, Samar

2016-04-01

A wealth of X-ray and radio observations has revealed in the past decade a growing diversity of neutron stars (NSs) with properties spanning orders of magnitude in magnetic field strength and ages, and with emission processes explained by a range of mechanisms dictating their radiation properties. However, serious difficulties exist with the magneto-dipole model of isolated NS fields and their inferred ages, such as a large range of observed braking indices (n, with values often <3) and a mismatch between the NS and associated supernova remnant (SNR) ages. This problem arises primarily from the assumptions of a constant magnetic field with n = 3, and an initial spin period that is much smaller than the observed current period. It has been suggested that a solution to this problem involves magnetic field evolution, with some NSs having magnetic fields buried within the crust by accretion of fall-back supernova material following their birth. In this work, we explore a parametric phenomenological model for magnetic field growth that generalizes previous suggested field evolution functions, and apply it to a variety of NSs with both secure SNR associations and known ages. We explore the flexibility of the model by recovering the results of previous work on buried magnetic fields in young NSs. Our model fits suggest that apparently disparate classes of NSs may be related to one another through the time evolution of the magnetic field.

Introduction to Chemistry and Applications in Nature of Mass Independent Isotope Effects Special Feature

PubMed Central

Thiemens, Mark H.

2013-01-01

Stable isotope ratio variations are regulated by physical and chemical laws. These rules depend on a relation with mass differences between isotopes. New classes of isotope variation effects that deviate from mass dependent laws, termed mass independent isotope effects, were discovered in 1983 and have a wide range of applications in basic chemistry and nature. In this special edition, new applications of these effects to physical chemistry, solar system origin models, terrestrial atmospheric and biogenic evolution, polar paleo climatology, snowball earth geology, and present day atmospheric sciences are presented. PMID:24167299

Introduction to chemistry and applications in nature of mass independent isotope effects special feature.

PubMed

Thiemens, Mark H

2013-10-29

Stable isotope ratio variations are regulated by physical and chemical laws. These rules depend on a relation with mass differences between isotopes. New classes of isotope variation effects that deviate from mass dependent laws, termed mass independent isotope effects, were discovered in 1983 and have a wide range of applications in basic chemistry and nature. In this special edition, new applications of these effects to physical chemistry, solar system origin models, terrestrial atmospheric and biogenic evolution, polar paleo climatology, snowball earth geology, and present day atmospheric sciences are presented.

Distinct Dual C-Cl Isotope Fractionation Patterns during Anaerobic Biodegradation of 1,2-Dichloroethane: Potential To Characterize Microbial Degradation in the Field.

PubMed

Palau, J; Yu, R; Hatijah Mortan, S; Shouakar-Stash, O; Rosell, M; Freedman, D L; Sbarbati, C; Fiorenza, S; Aravena, R; Marco-Urrea, E; Elsner, M; Soler, A; Hunkeler, D

2017-03-07

This study investigates, for the first time, dual C-Cl isotope fractionation during anaerobic biodegradation of 1,2-dichloroethane (1,2-DCA) via dihaloelimination by Dehalococcoides and Dehalogenimonas-containing enrichment cultures. Isotopic fractionation of 1,2-DCA (ε bulk C and ε bulk Cl ) for Dehalococcoides (-33.0 ± 0.4‰ and -5.1 ± 0.1‰) and Dehalogenimonas-containing microcosms (-23 ± 2‰ and -12.0 ± 0.8‰) resulted in distinctly different dual element C-Cl isotope correlations (Λ = Δδ 13 C/Δδ 37 Cl ≈ ε bulk C /ε bulk Cl ), 6.8 ± 0.2 and 1.89 ± 0.02, respectively. Determined isotope effects and detected products suggest that the difference on the obtained Λ values for biodihaloelimination could be associated with a different mode of concerted bond cleavage rather than two different reaction pathways (i.e., stepwise vs concerted). Λ values of 1,2-DCA were, for the first time, determined in two field sites under reducing conditions (2.1 ± 0.1 and 2.2 ± 2.9). They were similar to the one obtained for the Dehalogenimonas-containing microcosms (1.89 ± 0.02) and very different from those reported for aerobic degradation pathways in a previous laboratory study (7.6 ± 0.1 and 0.78 ± 0.03). Thus, this study illustrates the potential of a dual isotope analysis to differentiate between aerobic and anaerobic biodegradation pathways of 1,2-DCA in the field and suggests that this approach might also be used to characterize dihaloelimination of 1,2-DCA by different bacteria, which needs to be confirmed in future studies.

The IRHUM (Isotopic Reconstruction of Human Migration) database - bioavailable strontium isotope ratios for geochemical fingerprinting in France

NASA Astrophysics Data System (ADS)

Willmes, M.; McMorrow, L.; Kinsley, L.; Armstrong, R.; Aubert, M.; Eggins, S.; Falguères, C.; Maureille, B.; Moffat, I.; Grün, R.

2013-11-01

Strontium isotope ratios (87Sr/86Sr) are a key geochemical tracer used in a wide range of fields including archaeology, ecology, food and forensic sciences. These applications are based on the principle that the Sr isotopic ratios of natural materials reflect the sources of strontium available during their formation. A major constraint for current studies is the lack of robust reference maps to evaluate the source of strontium isotope ratios measured in the samples. Here we provide a new dataset of bioavailable Sr isotope ratios for the major geologic units of France, based on plant and soil samples (Pangaea data repository doi:10.1594/PANGAEA.819142). The IRHUM (Isotopic Reconstruction of Human Migration) database is a web platform to access, explore and map our dataset. The database provides the spatial context and metadata for each sample, allowing the user to evaluate the suitability of the sample for their specific study. In addition, it allows users to upload and share their own datasets and data products, which will enhance collaboration across the different research fields. This article describes the sampling and analytical methods used to generate the dataset and how to use and access of the dataset through the IRHUM database. Any interpretation of the isotope dataset is outside the scope of this publication.

Isotopic composition of Pb and Th in interplinian volcanics from Somma-Vesuvius volcano, Italy

USGS Publications Warehouse

Cortini, M.; Ayuso, R.A.; de Vivo, B.; Holden, P.; Somma, R.

2004-01-01

We present a detailed isotopic study of volcanic rocks emitted from Somma-Vesuvius volcano during three periods of interplinian activity: "Protohistoric" (3550 y B.P. to 79 A.D.), "Ancient Historic" (79 to 472 A.D.) and "Medieval" (472 to 1631 A.D.). Pb isotopic compositions of two acid leached fractions and whole rock residues of 37 whole rock samples (determined by Somma et al., 2001) show that each of the three interplinian periods is distinguished by small, systematic, and unique uranogenic and thorogenic Pb isotopic trends. This key and novel feature is compatible with the notion that the Pb isotopic data reflect small-scale source heterogeneity operating over relatively short periods of time. From this representative group of samples, a selected set of nine whole rocks were analysed for Th isotopes. 232Th/238U ratios in the source can be obtained independently from Pb and from Th isotopes. Those obtained from Pb isotopes represent source ratios, time-integrated over the whole age of the Earth; they range from 3.9 to 4.1. 232Th/238U obtained from Th isotopes are those of the present source. They are lower, and cluster around 3.5; this difference probably indicates recent U enrichment of the present source. The behaviour of Pb, as inferred by its isotopic ratios, is quite distinct from that of Sr and Nd isotopes: Pb isotope variations are not correlated to Sr or Nd isotope variations. The isotopic contrast is compatible with the idea that the isotopes were decoupled during magmatic production, evolution, and ascent through the crust. Thus, the Pb isotopes do not reflect the effects of the same processes as in the case of the Sr and Nd isotopes, or, as we also favor, they do not necessarily reflect the same source contributions into the magmas. Moreover, the Pb isotopic evolution of the interplinian rocks chiefly reflects mixing, driven by processes that are superimposed on, and independent of, other source contributions that determine the isotopic compositions

Isotope shifts in francium isotopes Fr 206 - 213 and Fr 221

DOE PAGES

Collister, R.; Gwinner, G.; Tandecki, M.; ...

2014-11-07

We present the isotope shifts of the 7s 1/2 to 7p 1/2 transition for francium isotopes ²⁰⁶⁻²¹³Fr with reference to ²²¹Fr collected from two experimental periods. The shifts are measured on a sample of atoms prepared within a magneto-optical trap by a fast sweep of radio-frequency sidebands applied to a carrier laser. King plot analysis, which includes literature values for 7s 1/2 to 7p 3/2 isotope shifts, provides a field shift constant ratio of 1.0520(10) and a difference between the specific mass shift constants of 170(100) GHz amu between the D₁ and D₂ transitions, of sufficient precision to differentiate betweenmore » ab initio calculations.« less

A model for osmium isotopic evolution of metallic solids at the core-mantle boundary

NASA Astrophysics Data System (ADS)

Humayun, Munir

2011-03-01

Some plumes are thought to originate at the core-mantle boundary, but geochemical evidence of core-mantle interaction is limited to Os isotopes in samples from Hawaii, Gorgona (89 Ma), and Kostomuksha (2.7 Ga). The Os isotopes have been explained by physical entrainment of Earth's liquid outer core into mantle plumes. This model has come into conflict with geophysical estimates of the timing of core formation, high-pressure experimental determinations of the solid metal-liquid metal partition coefficients (D), and the absence of expected 182W anomalies. A new model is proposed where metallic liquid from the outer core is partially trapped in a compacting cumulate pile of Fe-rich nonmetallic precipitates (FeO, FeS, Fe3Si, etc.) at the top of the core and undergoes fractional crystallization precipitating solid metal grains, followed by expulsion of the residual metallic liquid back to the outer core. The Os isotopic composition of the solids and liquids in the cumulate pile is modeled as a function of the residual liquid remaining and the emplacement age using 1 bar D values, with variable amounts of oxygen (0-10 wt %) as the light element. The precipitated solids evolve Os isotope compositions that match the trends for Hawaii (at an emplacement age of 3.5-4.5 Ga; 5%-10% oxygen) and Gorgona (emplacement age < 1.5 Ga; 0%-5% oxygen). The Fe-rich matrix of the cumulate pile dilutes the precipitated solid metal decoupling the Fe/Mn ratio from Os and W isotopes. The advantages to using precipitated solid metal as the Os host include a lower platinum group element and Ni content to the mantle source region relative to excess iron, miniscule anomalies in 182W (<0.1 ɛ), and no effects for Pb isotopes, etc. A gradual thermomechanical erosion of the cumulate pile results in incorporation of this material into the base of the mantle, where mantle plumes subsequently entrain it. Fractional crystallization of metallic liquids within the CMB provides a consistent explanation of

Chemical and isotopic evidence for hydrogeochemical processes occurring in the Lincolnshire Limestone

NASA Astrophysics Data System (ADS)

Bishop, Philip K.; Lloyd, John W.

1990-12-01

Over 150 groundwater samples from the Lincolnshire Limestone have been analysed for pH, major ions and δ 13C ratios. Where possible, field E h and iodide concentrations were measured and methane concentrations were determined for 12 samples. Stable isotope ratios were determined for soil and rock carbonate samples. A system of zonation allows the division of hydrogeochemical processes occurring in the aquifer. The use of hydrochemical and isotope data in modelling exercises enables the re-evaluation and possible enhancement of the understanding of hydrogeochemical processes. The carbonate chemistry of outcrop groundwaters is explained by calcite saturation being achieved under open-system conditions in the soil zone. δ 13C ratios in the range - 15.99 to - 10.57‰ may be generated from a stoichiometric reaction with possible additional partial and/or simultaneous exchange with soil CO 2 or carbonate. The isotopic composition of soil carbonate shows the effects of precipitation from soil waters. The incongruent dissolution of primary depositional limestone carbonate results in increasing magnesium and strontium concentrations and increasing δ 13C ratios for the groundwaters with flow down the hydraulic gradient. As a result of incongruent dissolution, secondary calcite may be precipitated onto fissure surfaces. Significant nitrate and sulphate reduction in non-saline groundwaters is not supported by the results of hydrochemical and isotope modelling exercises. However, sulphate reduction and methane fermentation may be affecting the isotopic and chemical compositions of saline groundwaters. Sodium-calcium ion exchange leads to limited calcite dissolution deep in the aquifer, but the evolution of these groundwaters is confused by the uncertain effects of oxidation of organic carbon and mixing with a saline end-member solution.

Observations of two-dimensional magnetic field evolution in a plasma opening switch

NASA Astrophysics Data System (ADS)

Shpitalnik, R.; Weingarten, A.; Gomberoff, K.; Krasik, Ya.; Maron, Y.

1998-03-01

The time dependent magnetic field distribution was studied in a coaxial 100-ns positive-polarity Plasma Opening Switch (POS) by observing the Zeeman effect in ionic line emission. Measurements local in three dimensions are obtained by doping the plasma using laser evaporation techniques. Fast magnetic field penetration with a relatively sharp magnetic field front (⩽1 cm) is observed at the early stages of the pulse (t≲25). Later in the pulse, the magnetic field is observed at the load-side edge of the plasma, leaving "islands" of low magnetic field at the plasma center that last for about 10 ns. The two-dimensional (2-D) structure of the magnetic field in the r,z plane is compared to the results of an analytical model based on electron-magneto-hydrodynamics, that utilizes the measured 2-D plasma density distribution and assumes fast magnetic field penetration along both POS electrodes. The model results provide quantitative explanation for the magnetic field evolution observed.

Isotope Tales: Remaining Problems, Unsolvable Questions, and Gentle Successes

NASA Astrophysics Data System (ADS)

fogel, marilyn; bradley, christina; newsome, seth; filipp, fabian

2014-05-01

Earth's biomes function and adapt today as climate changes and ecosystems and the organisms within them adapt. Stable isotope biogeochemistry has had a major influence in understanding climate perturbations and continues to be an active area of research on many fronts. Banking on the success of compound specific stable isotope analyses of amino acids, nitrogen, carbon, and hydrogen isotopes continue to reveal subtle shifts in oceanic food webs and metabolic changes in microbes, plants, and animals. A biochemical understanding of exactly how organisms process and partition stable isotopes during metabolism remains unsolved, but is required if this field is to move beyond description to quantitation. Although the patterns of carbon and nitrogen isotopes are fairly well established in the common amino acids, we need to consider specifics: How do shifting metabolic pathways (metabolomics) influence the outcome of stable isotope partitioning? What influence does the gut microflora in animals have on isotopic labeling? What are the intramolecular isotope patterns of common amino acids and what do they tell us? What can be learned with other isotope systems, such as hydrogen? Results and ideas of how to move forward in this field will be presented starting at the molecular level and ending with ecosystems.

The 12C/13C Ratio in Sgr B2(N): Constraints for Galactic Chemical Evolution and Isotopic Chemistry

NASA Astrophysics Data System (ADS)

Halfen, D. T.; Woolf, N. J.; Ziurys, L. M.

2017-08-01

A study has been conducted of 12C/13C ratios in five complex molecules in the Galactic center. H2CS, CH3CCH, NH2CHO, CH2CHCN, and CH3CH2CN and their 13C-substituted species have been observed in numerous transitions at 1, 2, and 3 mm, acquired in a spectral-line survey of Sgr B2(N), conducted with the telescopes of the Arizona Radio Observatory (ARO). Between 22 and 54 individual, unblended lines for the 12C species and 2-54 for 13C-substituted analogs were modeled in a global radiative transfer analysis. All five molecules were found to consistently exhibit two velocity components near V LSR ˜ 64 and 73 km s-1, with column densities ranging from N tot ˜ 3 × 1014 - 4 × 1017 cm-2 and ˜2 × 1013 - 1 × 1017 cm-2 for the 12C and 13C species, respectively. Based on 14 different isotopic combinations, ratios were obtained in the range 12C/13C = 15 ± 5 to 33 ± 13, with an average value of 24 ± 7, based on comparison of column densities. These measurements better anchor the 12C/13C ratio at the Galactic center, and suggest a slightly revised isotope gradient of 12C/13C = 5.21(0.52) D GC + 22.6(3.3). As indicated by the column densities, no preferential 13C enrichment was found on the differing carbon sites of CH3CCH, CH2CHCN, and CH3CH2CN. Because of the elevated temperatures in Sgr B2(N), 13C isotopic substitution is effectively “scrambled,” diminishing chemical fractionation effects. The resulting ratios thus reflect stellar nucleosynthesis and Galactic chemical evolution, as is likely the case for most warm clouds.

Helium-strontium isotope constraints on mantle evolution beneath the Roman Comagmatic Province, Italy

NASA Astrophysics Data System (ADS)

Martelli, M.; Nuccio, P. M.; Stuart, F. M.; Burgess, R.; Ellam, R. M.; Italiano, F.

2004-08-01

A study of the He isotopic ratios of fluid inclusions in olivine and pyroxene from the Roman Comagmatic Province (RCP), Italy, is presented together with 87Sr/ 86Sr isotope compositions of the whole rock or pyroxene phenocrysts. A clear covariation in He and Sr isotopes is apparent, with a strong northward increase in radiogenic He and Sr being evident. He and Sr isotopes ratios range from 3He/ 4He=5.2 Ra and 87Sr/ 86Sr=0.7056 in south Campania, to 3He/ 4He=0.44 Ra and 87Sr/ 86Sr=0.715905 in the northernmost Latium. Helium isotope ratios are significantly lower than MORB values and are among the lowest yet measured in subduction zone volcanism. The 3He/ 4He of olivine and pyroxene phenocryst-hosted volatiles appear to be little influenced by posteruptive processes and magma-crust interaction. The 3He/ 4He- 87Sr/ 86Sr covariation is consistent with binary mixing between an asthenospheric mantle similar to HIMU ocean island basalts, and an enriched (radiogenic) mantle end member generated from subduction of the Ionian/Adriatic plate. The contribution of radiogenic He from metasomatic fluids and postmetasomatism radiogenic ingrowth in the wedge is strongly dependent on the initial He concentration of the mantle. Only when asthenosphere He concentrations are substantially lower than the MORB source mantle, and metasomatism occurred at the beginning of the subduction (˜30 Ma), can ingrowth in the mantle wedge account for the 3He/ 4He of the most radiogenic basalts.

Evolution of the Active Region NOAA 12443 based on magnetic field extrapolations: preliminary results

NASA Astrophysics Data System (ADS)

Chicrala, André; Dallaqua, Renato Sergio; Antunes Vieira, Luis Eduardo; Dal Lago, Alisson; Rodríguez Gómez, Jenny Marcela; Palacios, Judith; Coelho Stekel, Tardelli Ronan; Rezende Costa, Joaquim Eduardo; da Silva Rockenbach, Marlos

2017-10-01

The behavior of Active Regions (ARs) is directly related to the occurrence of some remarkable phenomena in the Sun such as solar flares or coronal mass ejections (CME). In this sense, changes in the magnetic field of the region can be used to uncover other relevant features like the evolution of the ARs magnetic structure and the plasma flow related to it. In this work we describe the evolution of the magnetic structure of the active region AR NOAA12443 observed from 2015/10/30 to 2015/11/10, which may be associated with several X-ray flares of classes C and M. The analysis is based on observations of the solar surface and atmosphere provided by HMI and AIA instruments on board of the SDO spacecraft. In order to investigate the magnetic energy buildup and release of the ARs, we shall employ potential and linear force free extrapolations based on the solar surface magnetic field distribution and the photospheric velocity fields.

The evolution of surface magnetic fields in young solar-type stars II: the early main sequence (250-650 Myr)

NASA Astrophysics Data System (ADS)

Folsom, C. P.; Bouvier, J.; Petit, P.; Lèbre, A.; Amard, L.; Palacios, A.; Morin, J.; Donati, J.-F.; Vidotto, A. A.

2018-03-01

There is a large change in surface rotation rates of sun-like stars on the pre-main sequence and early main sequence. Since these stars have dynamo-driven magnetic fields, this implies a strong evolution of their magnetic properties over this time period. The spin-down of these stars is controlled by interactions between stellar and magnetic fields, thus magnetic evolution in turn plays an important role in rotational evolution. We present here the second part of a study investigating the evolution of large-scale surface magnetic fields in this critical time period. We observed stars in open clusters and stellar associations with known ages between 120 and 650 Myr, and used spectropolarimetry and Zeeman Doppler Imaging to characterize their large-scale magnetic field strength and geometry. We report 15 stars with magnetic detections here. These stars have masses from 0.8 to 0.95 M⊙, rotation periods from 0.326 to 10.6 d, and we find large-scale magnetic field strengths from 8.5 to 195 G with a wide range of geometries. We find a clear trend towards decreasing magnetic field strength with age, and a power law decrease in magnetic field strength with Rossby number. There is some tentative evidence for saturation of the large-scale magnetic field strength at Rossby numbers below 0.1, although the saturation point is not yet well defined. Comparing to younger classical T Tauri stars, we support the hypothesis that differences in internal structure produce large differences in observed magnetic fields, however for weak-lined T Tauri stars this is less clear.

The Chlorine Isotopic Composition Of Lunar UrKREEP

NASA Technical Reports Server (NTRS)

Barnes, J. J.; Tartese, R.; Anand, M.; McCubbin, F. M.; Neal, C. R.; Franchi, I. A.

2016-01-01

Since the long standing paradigm of an anhydrous Moon was challenged there has been a renewed focus on investigating volatiles in a variety of lunar samples. However, the current models for the Moon’s formation have yet to fully account for its thermal evolution in the presence of H2O and other volatiles. When compared to chondritic meteorites and terrestrial rocks, lunar samples have exotic chlorine isotope compositions, which are difficult to explain in light of the abundance and isotopic composition of other volatile species, especially H, and the current estimates for chlorine and H2O in the bulk silicate Moon. In order to better understand the processes involved in giving rise to the heavy chlorine isotope compositions of lunar samples, we have performed a comprehensive in situ high precision study of chlorine isotopes, using NanoSIMS (Nanoscale Secondary Ion Mass Spectrometry) of lunar apatite from a suite of Apollo samples covering a range of geochemical characteristics and petrologic types.

Iron isotope biogeochemistry of Neoproterozoic marine shales

NASA Astrophysics Data System (ADS)

Kunzmann, Marcus; Gibson, Timothy M.; Halverson, Galen P.; Hodgskiss, Malcolm S. W.; Bui, Thi Hao; Carozza, David A.; Sperling, Erik A.; Poirier, André; Cox, Grant M.; Wing, Boswell A.

2017-07-01

Iron isotopes have been widely applied to investigate the redox evolution of Earth's surface environments. However, it is still unclear whether iron cycling in the water column or during diagenesis represents the major control on the iron isotope composition of sediments and sedimentary rocks. Interpretation of isotopic data in terms of oceanic redox conditions is only possible if water column processes dominate the isotopic composition, whereas redox interpretations are less straightforward if diagenetic iron cycling controls the isotopic composition. In the latter scenario, iron isotope data is more directly related to microbial processes such as dissimilatory iron reduction. Here we present bulk rock iron isotope data from late Proterozoic marine shales from Svalbard, northwestern Canada, and Siberia, to better understand the controls on iron isotope fractionation in late Proterozoic marine environments. Bulk shales span a δ 56Fe range from -0.45 ‰ to +1.04 ‰ . Although δ 56Fe values show significant variation within individual stratigraphic units, their mean value is closer to that of bulk crust and hydrothermal iron in samples post-dating the ca. 717-660 Ma Sturtian glaciation compared to older samples. After correcting for the highly reactive iron content in our samples based on iron speciation data, more than 90% of the calculated δ 56Fe compositions of highly reactive iron falls in the range from ca. -0.8 ‰ to +3 ‰ . An isotope mass-balance model indicates that diagenetic iron cycling can only change the isotopic composition of highly reactive iron by < 1 ‰ , suggesting that water column processes, namely the degree of oxidation of the ferrous seawater iron reservoir, control the isotopic composition of highly reactive iron. Considering a long-term decrease in the isotopic composition of the iron source to the dissolved seawater Fe(II) reservoir to be unlikely, we offer two possible explanations for the Neoproterozoic δ 56Fe trend. First, a

Isotopic constraints on ice age fluids in active geothermal systems: Reykjanes, Iceland

NASA Astrophysics Data System (ADS)

Pope, Emily C.; Bird, Dennis K.; Arnórsson, Stefán; Fridriksson, Thráinn; Elders, Wilfred A.; Fridleifsson, Gudmundur Ó.

2009-08-01

The Reykjanes geothermal system is located on the landward extension of the Mid-Atlantic Ridge in southwest Iceland, and provides an on-land proxy to high-temperature hydrothermal systems of oceanic spreading centers. Previous studies of elemental composition and salinity have shown that Reykjanes geothermal fluids are likely hydrothermally modified seawater. However, δD values of these fluids are as low as -23‰, which is indicative of a meteoric water component. Here we constrain the origin of Reykjanes hydrothermal solutions by analysis of hydrogen and oxygen isotope compositions of hydrothermal epidote from geothermal drillholes at depths between 1 and 3 km. δDEPIDOTE values from wells RN-8, -9, -10 and -17 collectively range from -60 to -78‰, and δ18OEPIDOTE in these wells are between -3.0 and 2.3‰. The δD values of epidote generally increase along a NE trend through the geothermal field, whereas δ18O values generally decrease, suggesting a southwest to northeast migration of the geothermal upflow zone with time that is consistent with present-day temperatures and observed hydrothermal mineral zones. For comparative analysis, the meteoric-water dominated Nesjavellir and Krafla geothermal systems, which have a δDFLUID of ˜ -79‰ and -89‰, respectively, show δDEPIDOTE values of -115‰ and -125‰. In contrast, δDEPIDOTE from the mixed meteoric-seawater Svartsengi geothermal system is -68‰; comparable to δDEPIDOTE from well RN-10 at Reykjanes. Stable isotope compositions of geothermal fluids in isotopic equilibrium with the epidotes at Reykjanes are computed using published temperature dependent hydrogen and oxygen isotope fractionation curves for epidote-water, measured isotope composition of the epidotes and temperatures approximated from the boiling point curve with depth. Calculated δD and δ18O of geothermal fluids are less than 0‰, suggesting that fluids of meteoric or glacial origin are a significant component of the geothermal

Helium isotope study of geothermal features in Chile with field and laboratory data

DOE Data Explorer

Dobson, Patrick

2013-02-11

Helium isotope and stable isotope data from the El Tatio, Tinginguirica, Chillan, and Tolhuaca geothermal systems, Chile. Data from this submission are discussed in: Dobson, P.F., Kennedy, B.M., Reich, M., Sanchez, P., and Morata, D. (2013) Effects of volcanism, crustal thickness, and large scale faulting on the He isotope signatures of geothermal systems in Chile. Proceedings, 38th Workshop on Geothermal Reservoir Engineering, Stanford University, Feb. 11-13, 2013

The evolution of stable magnetic fields in stars: an analytical approach

NASA Astrophysics Data System (ADS)

Mestel, Leon; Moss, David

2010-07-01

The absence of a rigorous proof of the existence of dynamically stable, large-scale magnetic fields in radiative stars has been for many years a missing element in the fossil field theory for the magnetic Ap/Bp stars. Recent numerical simulations, by Braithwaite & Spruit and Braithwaite & Nordlund, have largely filled this gap, demonstrating convincingly that coherent global scale fields can survive for times of the order of the main-sequence lifetimes of A stars. These dynamically stable configurations take the form of magnetic tori, with linked poloidal and toroidal fields, that slowly rise towards the stellar surface. This paper studies a simple analytical model of such a torus, designed to elucidate the physical processes that govern its evolution. It is found that one-dimensional numerical calculations reproduce some key features of the numerical simulations, with radiative heat transfer, Archimedes' principle, Lorentz force and Ohmic decay all playing significant roles.

Role of electric fields in the MHD evolution of the kink instability

DOE PAGES

Lapenta, Giovanni; Skender, Marina

2017-02-17

Here, the discovery of electrostatic fields playing a crucial role in establishing plasma motion in the flux conversion and dynamo processes in reversed field pinches is revisited. In order to further elucidate the role of the electrostatic fields, a flux rope configuration susceptible to the kink instability is numerically studied with anMHDcode. Simulated nonlinear evolution of the kink instability is found to confirm the crucial role of the electrostatic fields. Anew insight is gained on the special function of the electrostatic fields: they lead the plasma towards the reconnection site at the mode resonant surface. Without this step the plasmamore » column could not relax to its nonlinear state, since no other agent is present to perform this role. While the inductive field generated directly by the kink instability is the dominant flow driver, the electrostatic field is found to allow the motion in the vicinity of the reconnection region.« less

Role of electric fields in the MHD evolution of the kink instability

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lapenta, Giovanni; Skender, Marina

Here, the discovery of electrostatic fields playing a crucial role in establishing plasma motion in the flux conversion and dynamo processes in reversed field pinches is revisited. In order to further elucidate the role of the electrostatic fields, a flux rope configuration susceptible to the kink instability is numerically studied with anMHDcode. Simulated nonlinear evolution of the kink instability is found to confirm the crucial role of the electrostatic fields. Anew insight is gained on the special function of the electrostatic fields: they lead the plasma towards the reconnection site at the mode resonant surface. Without this step the plasmamore » column could not relax to its nonlinear state, since no other agent is present to perform this role. While the inductive field generated directly by the kink instability is the dominant flow driver, the electrostatic field is found to allow the motion in the vicinity of the reconnection region.« less

Zinc isotope fractionation during magmatic differentiation and the isotopic composition of the bulk Earth

USGS Publications Warehouse

Chen, Heng; Savage, Paul S.; Teng, Fang-Zehn; Helz, Rosalind T.; Moynier, Frédéric

2013-01-01

he zinc stable isotope system has been successfully applied to many and varied fields in geochemistry, but to date it is still not completely clear how this isotope system is affected by igneous processes. In order to evaluate the potential application of Zn isotopes as a proxy for planetary differentiation and volatile history, it is important to constrain the magnitude of Zn isotopic fractionation induced by magmatic differentiation. In this study we present high-precision Zn isotope analyses of two sets of chemically diverse, cogenetic samples from Kilauea Iki lava lake, Hawaii, and Hekla volcano, Iceland, which both show clear evidence of having undergone variable and significant degrees of magmatic differentiation. The Kilauea Iki samples display small but resolvable variations in Zn isotope composition (0.26‰66Zn66Zn defined as the per mille deviation of a sample's 66Zn/64Zn compositional ratio from the JMC-Lyon standard), with the most differentiated lithologies exhibiting more positive δ66Zn values. This fractionation is likely a result of the crystallization of olivine and/or Fe–Ti oxides, which can both host Zn in their crystal structures. Samples from Hekla have a similar range of isotopic variation (0.22‰66Zn66Zn=0.28±0.05‰ (2s.d.).

Iron isotope fingerprints of redox and biogeochemical cycling in the soil-water-rice plant system of a paddy field.

PubMed

Garnier, J; Garnier, J-M; Vieira, C L; Akerman, A; Chmeleff, J; Ruiz, R I; Poitrasson, F

2017-01-01

The iron isotope composition was used to investigate dissimilatory iron reduction (DIR) processes in an iron-rich waterlogged paddy soil, the iron uptake strategies of plants and its translocation in the different parts of the rice plant along its growth. Fe concentration and isotope composition (δ 56 Fe) in irrigation water, precipitates from irrigation water, soil, pore water solution at different depths under the surface water, iron plaque on rice roots, rice roots, stems, leaves and grains were measured. Over the 8.5-10cm of the vertical profiles investigated, the iron pore water concentration (0.01 to 24.3mg·l -1 ) and δ 56 Fe (-0.80 to -3.40‰) varied over a large range. The significant linear co-variation between Ln[Fe] and δ 56 Fe suggests an apparent Rayleigh-type behavior of the DIR processes. An average net fractionation factor between the pore water and the soil substrate of Δ 56 Fe≈-1.15‰ was obtained, taking the average of all the δ 56 Fe values weighted by the amount of Fe for each sample. These results provide a robust field study confirmation of the conceptual model of Crosby et al. (2005, 2007) for interpreting the iron isotope fractionation observed during DIR, established from a series of laboratories experiments. In addition, the strong enrichment of heavy Fe isotope measured in the root relative to the soil solution suggest that the iron uptake by roots is more likely supplied by iron from plaque and not from the plant-available iron in the pore water. Opposite to what was previously observed for plants following strategy II for iron uptake from soils, an iron isotope fractionation factor of -0.9‰ was found from the roots to the rice grains, pointing to isotope fractionation during rice plant growth. All these features highlight the insights iron isotope composition provides into the biogeochemical Fe cycling in the soil-water-rice plant systems studied in nature. Copyright © 2016 Elsevier B.V. All rights reserved.

Boundary-value problem for a counterrotating electrical discharge in an axial magnetic field. [plasma centrifuge for isotope separation

NASA Technical Reports Server (NTRS)

Hong, S. H.; Wilhelm, H. E.

1978-01-01

An electrical discharge between two ring electrodes embedded in the mantle of a cylindrical chamber is considered, in which the plasma in the anode and cathode regions rotates in opposite directions under the influence of an external axial magnetic field. The associated boundary-value problem for the coupled partial differential equations describing the azimuthal velocity and radial current-density fields is solved in closed form. The velocity, current density, induced magnetic induction, and electric fields are presented for typical Hartmann numbers, magnetic Reynolds numbers, and geometry parameters. The discharge is shown to produce anodic and cathodic plasma sections rotating at speeds of the order 1,000,000 cm/sec for conventional magnetic field intensities. Possible application of the magnetoactive discharge as a plasma centrifuge for isotope separation is discussed.

Isotopic Discrimination During Leaf Litter Decomposition

NASA Astrophysics Data System (ADS)

Ngao, J.; Rubino, M.

2006-12-01

Methods involving stable isotopes have been successfully applied since decades in various research fields. Tracing 13C natural abundance in ecosystem compartments greatly enhanced the understanding of the C fluxes in the plant-soil-atmosphere C exchanges when compartments present different C isotopic signatures (i.e. atmospheric CO2 vs photosynthetic leaves, C3 vs C4; etc.). However, the assumption that no isotopic discrimination occurs during respiration is commonly made in numbers of C isotope-based ecological studies. Furthermore, verifications of such assumption are sparse and not enough reliable. The aim of our study is to assess the potential isotopic discrimination that may occur during litter decomposition. Leaf litter from an Arbutus unedo (L.) stand (Tolfa, Italy) was incubated in 1L jars, under constant laboratory conditions (i.e. 25 ° C and 135% WC). During the entire incubation period, gravimetric mass loss, litter respiration rates and the isotopic composition of respired CO2 are monitored at regular intervals. Data from 7 months of incubation will be presented and discussed. After two months, the litter mass loss averaged 16% of initial dry mass. During the same time-period, the respiration rate decreased significantly by 58% of the initial respiration rate. Isotopic compositions of respired CO2 ranged between -27.95‰ and - 25.69‰. Mean values did not differ significantly among the sampling days, in spite of an apparent enrichment in 13C of respired CO2 with time. The significance of these isotopic enrichment will be determined at a longer time scale. They may reveal both/either a direct microbial discrimination during respiration processes and/or a use of different litter compounds as C source along time. Further chemical and compound-specific isotopic analysis of dry matter will be performed in order to clarify these hypotheses. This work is part of the "ALICE" project, funded by the European Union's Marie Curie Fellowship Actions that aims to

Conceptual models of the evolution of transgressive dune field systems

NASA Astrophysics Data System (ADS)

A. Hesp, Patrick

2013-10-01

This paper examines the evolutionary paths of some transgressive dune fields that have formed on different coasts of the world, and presents some initial conceptual models of system dynamics for transgressive dune sheets and dune fields. Various evolutionary pathways are conceptualized based on a visual examination of dune fields from around the world. On coasts with high sediment supply, dune sheets and dune fields tend to accumulate as large scale barrier systems with little colonization of vegetation in arid-hyper to arid climate regimes, and as multiple, active discrete phases of dune field and deflation plain couplets in temperate to tropical environments. Active dune fields tend to be singular entities on coasts with low to moderate sediment supply. Landscape complexity and vegetation richness and diversity increases as dune fields evolve from simple active sheets and dunes to single and multiple deflation plains and basins, precipitation ridges, nebkha fields and a host of other dune types associated with vegetation (e.g. trailing ridges, slacks, remnant knobs, gegenwalle ridges and dune track ridges, ‘tree islands' and ‘bush pockets'). Three principal scenarios of transgressive dune sheet and dune field development are discussed, including dune sheets or dune fields evolving directly from the backshore, development following foredune and/or dune field erosion, and development from the breakdown or merging of parabolic dunes. Various stages of evolution are outlined for each scenario. Knowledge of evolutionary patterns and stages in coastal dune fields is very limited and caution is urged in attempts to reverse, change and/or modify dune fields to ‘restore' some perceived loss of ecosystem or dune functioning.

Conceptual models of the evolution of transgressive dune field systems

NASA Astrophysics Data System (ADS)

Hesp, Patrick A.

2013-10-01

This paper examines the evolutionary paths of some transgressive dune fields that have formed on different coasts of the world, and presents some initial conceptual models of system dynamics for transgressive dune sheets and dune fields. Various evolutionary pathways are conceptualized based on a visual examination of dune fields from around the world. On coasts with high sediment supply, dune sheets and dune fields tend to accumulate as large scale barrier systems with little colonization of vegetation in arid-hyper to arid climate regimes, and as multiple, active discrete phases of dune field and deflation plain couplets in temperate to tropical environments. Active dune fields tend to be singular entities on coasts with low to moderate sediment supply. Landscape complexity and vegetation richness and diversity increases as dune fields evolve from simple active sheets and dunes to single and multiple deflation plains and basins, precipitation ridges, nebkha fields and a host of other dune types associated with vegetation (e.g. trailing ridges, slacks, remnant knobs, gegenwalle ridges and dune track ridges, 'tree islands' and 'bush pockets'). Three principal scenarios of transgressive dune sheet and dune field development are discussed, including dune sheets or dune fields evolving directly from the backshore, development following foredune and/or dune field erosion, and development from the breakdown or merging of parabolic dunes. Various stages of evolution are outlined for each scenario. Knowledge of evolutionary patterns and stages in coastal dune fields is very limited and caution is urged in attempts to reverse, change and/or modify dune fields to 'restore' some perceived loss of ecosystem or dune functioning.

The IRHUM (Isotopic Reconstruction of Human Migration) database - bioavailable strontium isotope ratios for geochemical fingerprinting in France

NASA Astrophysics Data System (ADS)

Willmes, M.; McMorrow, L.; Kinsley, L.; Armstrong, R.; Aubert, M.; Eggins, S.; Falguères, C.; Maureille, B.; Moffat, I.; Grün, R.

2014-03-01

Strontium isotope ratios (87Sr / 86Sr) are a key geochemical tracer used in a wide range of fields including archaeology, ecology, food and forensic sciences. These applications are based on the principle that the Sr isotopic ratios of natural materials reflect the sources of strontium available during their formation. A major constraint for current studies is the lack of robust reference maps to evaluate the source of strontium isotope ratios measured in the samples. Here we provide a new data set of bioavailable Sr isotope ratios for the major geologic units of France, based on plant and soil samples (Pangaea data repository doi:10.1594/PANGAEA.819142). The IRHUM (Isotopic Reconstruction of Human Migration) database is a web platform to access, explore and map our data set. The database provides the spatial context and metadata for each sample, allowing the user to evaluate the suitability of the sample for their specific study. In addition, it allows users to upload and share their own data sets and data products, which will enhance collaboration across the different research fields. This article describes the sampling and analytical methods used to generate the data set and how to use and access the data set through the IRHUM database. Any interpretation of the isotope data set is outside the scope of this publication.

Modeling of microstructure evolution in direct metal laser sintering: A phase field approach

NASA Astrophysics Data System (ADS)

Nandy, Jyotirmoy; Sarangi, Hrushikesh; Sahoo, Seshadev

2017-02-01

Direct Metal Laser Sintering (DMLS) is a new technology in the field of additive manufacturing, which builds metal parts in a layer by layer fashion directly from the powder bed. The process occurs within a very short time period with rapid solidification rate. Slight variations in the process parameters may cause enormous change in the final build parts. The physical and mechanical properties of the final build parts are dependent on the solidification rate which directly affects the microstructure of the material. Thus, the evolving of microstructure plays a vital role in the process parameters optimization. Nowadays, the increase in computational power allows for direct simulations of microstructures during materials processing for specific manufacturing conditions. In this study, modeling of microstructure evolution of Al-Si-10Mg powder in DMLS process was carried out by using a phase field approach. A MATLAB code was developed to solve the set of phase field equations, where simulation parameters include temperature gradient, laser scan speed and laser power. The effects of temperature gradient on microstructure evolution were studied and found that with increase in temperature gradient, the dendritic tip grows at a faster rate.

Structure and evolution of the large scale solar and heliospheric magnetic fields. Ph.D. Thesis

NASA Technical Reports Server (NTRS)

Hoeksema, J. T.

1984-01-01

Structure and evolution of large scale photospheric and coronal magnetic fields in the interval 1976-1983 were studied using observations from the Stanford Solar Observatory and a potential field model. The solar wind in the heliosphere is organized into large regions in which the magnetic field has a componenet either toward or away from the sun. The model predicts the location of the current sheet separating these regions. Near solar minimum, in 1976, the current sheet lay within a few degrees of the solar equator having two extensions north and south of the equator. Soon after minimum the latitudinal extent began to increase. The sheet reached to at least 50 deg from 1978 through 1983. The complex structure near maximum occasionally included multiple current sheets. Large scale structures persist for up to two years during the entire interval. To minimize errors in determining the structure of the heliospheric field particular attention was paid to decreasing the distorting effects of rapid field evolution, finding the optimum source surface radius, determining the correction to the sun's polar field, and handling missing data. The predicted structure agrees with direct interplanetary field measurements taken near the ecliptic and with coronameter and interplanetary scintillation measurements which infer the three dimensional interplanetary magnetic structure. During most of the solar cycle the heliospheric field cannot be adequately described as a dipole.

Mladotice Lake, Czechia: The unique genesis and evolution of the lake basin

NASA Astrophysics Data System (ADS)

Janský, Bohumír; Šobr, Miroslav; Kliment, Zdeněk; Chalupová, Dagmar

2016-04-01

The Mladotice Lake is a lake of unique genetic type in Czechia. In May 1872 a landslide as a result an extreme rainfall event occurred in western Czechia, blocking the Mladoticky stream valley and creating the Mladotice Lake. The 1952 and 1975 air images document that collective farming had a great impact on the lake basin evolution when balks and field terraces were removed and fields were made much larger. Because of this change in land use we expected higher soil erosion and a related increase in the sedimentation rate. First bathymetric measurements of the newly created lake were carried out in 1972 and were repeated in 1999, in 2003 and in 2014. Our analysis of the sedimentary record aims to identify the sediment stratigraphy, its basic physical and chemical properties, isotope content and thin sections yield a detailed temporal resolution of the sedimentation chronology. In some areas a sediment thickness of 4 m was detected. Hence, the average sedimentation rate is from 2.2 to 2.7 cm per year. KEY WORDS: Mladotice Lake - extreme rainfall event - landslide - land use changes - flood events - bathymetric measurements - sedimentation dynamics - stratigraphy and geochemistry of lake sediments - analyses of isotopes - sedimentation rates.

Conception of eroded protocore and magnetic field evolution in the terrestrial planets

NASA Astrophysics Data System (ADS)

Pushkarev, Y. D.; Starchenko, S. V.

2011-10-01

Identification of the superheated and lightweight material streams in the Earth interiors named as plumes, has put up the problem of the energy source for such overheating. Plume origin at core-mantle boundary suggests that such source is the core, which, apparently, is overheated in comparison with bottom of the low mantle. Magmatic derivatives of the mantle material sometimes contain primary noble gases and in particular the isotope 129J (the decay product of the short-lived 129J). It demonstrates that somewhere in the Earth there is a material which became geochemically closed with regard to noble gases before 129J complete decay, i.e. not later than through 150 million years after the beginning of accretion and which subsequently was never mixed with the mantle material. Properly speaking, such material is the material of the core, to be exact of its solid internal part. At the same time Hf-W and U-Pb isotope systems show that the formation of a liquid core has taken place during first 100-120 million years after accretion [2]. Along with it there are evidences of existence of an ancient geomagnetic field [3, 6, etc.] up to the early Archean [11], which intensity is identical to the modern one. This information contradicts the generally accepted ideas according to which the geodynamo, generating the modern magnetic field of the Earth, is produced by the compositional convection caused due to crystallization of a liquid core [1, 8, 10]. The most probable time of excitation of compositional convection is estimated about 1 Ga, but not earlier than 2 Ga [7, 10]. It follows that before this time the geomagnetic intensity should have had the lower value because it was generated only by inefficient thermal convection. Thus, if the compositional convection is required to generate the Archean geomagnetic field, intensity of which is close to the modern one, this convection should have any other nature.

Assessing human weaning practices with calcium isotopes in tooth enamel

PubMed Central

Tacail, Théo; Thivichon-Prince, Béatrice; Martin, Jeremy E.; Charles, Cyril; Viriot, Laurent

2017-01-01

Weaning practices differ among great apes and likely diverged during the course of human evolution, but behavioral inference from the fossil record is hampered by a lack of unambiguous biomarkers. Here, we show that early-life dietary transitions are recorded in human deciduous tooth enamel as marked variations in Ca isotope ratios (δ44/42Ca). Using a sequential microsampling method along the enamel growth axis, we collected more than 150 enamel microsamples from 51 deciduous teeth of 12 different modern human individuals of known dietary histories, as well as nine enamel samples from permanent third molars. We measured and reconstructed the evolution of 44Ca/42Ca ratios in enamel from in utero development to first months of postnatal development. We show that the observed variations of δ44/42Ca record a transition from placental nutrition to an adult-like diet and that Ca isotopes reflect the duration of the breastfeeding period experienced by each infant. Typically, the δ44/42Ca values of individuals briefly or not breastfed show a systematic increase during the first 5–10 mo, whereas individuals with long breastfeeding histories display no measurable variation in δ44/42Ca of enamel formed during this time. The use of Ca isotope analysis in tooth enamel allows microsampling and offers an independent approach to tackle challenging questions related to past population dynamics and evolution of weaning practices in hominins. PMID:28559355

Advances in primate stable isotope ecology-Achievements and future prospects.

PubMed

Crowley, Brooke E; Reitsema, Laurie J; Oelze, Vicky M; Sponheimer, Matt

2016-10-01

Stable isotope biogeochemistry has been used to investigate foraging ecology in non-human primates for nearly 30 years. Whereas early studies focused on diet, more recently, isotopic analysis has been used to address a diversity of ecological questions ranging from niche partitioning to nutritional status to variability in life history traits. With this increasing array of applications, stable isotope analysis stands to make major contributions to our understanding of primate behavior and biology. Most notably, isotopic data provide novel insights into primate feeding behaviors that may not otherwise be detectable. This special issue brings together some of the recent advances in this relatively new field. In this introduction to the special issue, we review the state of isotopic applications in primatology and its origins and describe some developing methodological issues, including techniques for analyzing different tissue types, statistical approaches, and isotopic baselines. We then discuss the future directions we envision for the field of primate isotope ecology. Am. J. Primatol. 78:995-1003, 2016. © 2015 Wiley Periodicals, Inc. © 2015 Wiley Periodicals, Inc.

Cosmological evolution of a complex scalar field with repulsive or attractive self-interaction

NASA Astrophysics Data System (ADS)

Suárez, Abril; Chavanis, Pierre-Henri

2017-03-01

We study the cosmological evolution of a complex scalar field with a self-interaction potential V (|φ |2) , possibly describing self-gravitating Bose-Einstein condensates, using a fully general relativistic treatment. We generalize the hydrodynamic representation of the Klein-Gordon-Einstein equations in the weak field approximation developed in our previous paper [A. Suárez and P.-H. Chavanis, Phys. Rev. D 92, 023510 (2015), 10.1103/PhysRevD.92.023510]. We establish the general equations governing the evolution of a spatially homogeneous complex scalar field in an expanding background. We show how they can be simplified in the fast oscillation regime (equivalent to the Thomas-Fermi, or semiclassical, approximation) and derive the equation of state of the scalar field in parametric form for an arbitrary potential V (|φ |2) . We explicitly consider the case of a quartic potential with repulsive or attractive self-interaction. For repulsive self-interaction, the scalar field undergoes a stiff matter era followed by a pressureless dark matter era in the weakly self-interacting regime and a stiff matter era followed by a radiationlike era and a pressureless dark matter era in the strongly self-interacting regime. For attractive self-interaction, the scalar field undergoes an inflation era followed by a stiff matter era and a pressureless dark matter era in the weakly self-interacting regime and an inflation era followed by a cosmic stringlike era and a pressureless dark matter era in the strongly self-interacting regime (the inflation era is suggested, not demonstrated). We also find a peculiar branch on which the scalar field emerges suddenly at a nonzero scale factor with a finite energy density. At early times, it behaves as a gas of cosmic strings. At later times, it behaves as dark energy with an almost constant energy density giving rise to a de Sitter evolution. This is due to spintessence. We derive the effective cosmological constant produced by the scalar

CNO isotopes in red giant stars

NASA Technical Reports Server (NTRS)

Wannier, P. G.

1985-01-01

Observational data on CNO abundance ratios in red giants and the interstellar medium (ISM) are analyzed for the implications for the production and distribution of CNO nuclides. The data included isotope abundance measurements for the atmospheres and recent ejecta of cool giants, e.g., carbon stars, S-type stars, red supergiants and oxygen-rich giants beginning an ascent of the giant branch. The contribution of intermediate-mass stars to galactic nuclear evolution is discussed after comparing red giant abundances with ISM abundances, particularly the isotopes O-16, -17 and -18. The O-12/O-18 ratios of red giants are distinctly different from those in interstellar molecular clouds. The CNO values also vary widely from the values found in the solar system.

Magnesium isotopic composition of the mantle

NASA Astrophysics Data System (ADS)

Teng, F.; Li, W.; Ke, S.; Marty, B.; Huang, S.; Dauphas, N.; Wu, F.; Helz, R. L.

2009-12-01

Studies of Mg isotopic composition of the Earth not only are important for understanding its geochemistry but also can shed light on the accretion history of the Earth as well as the evolution of the Earth-Moon system. However, to date, the Mg isotopic composition of the Earth is still poorly constrained and highly debated. There is uncertainty in the magnitude of Mg isotope fractionation at mantle temperatures and whether the Earth has a chondritic Mg isotopic composition or not. To constrain further the Mg isotopic composition of the mantle and investigate the behavior of Mg isotopes during igneous differentiation, we report >200 high-precision (δ26Mg < 0.1‰, 2SD) analyses of Mg isotopes on 1) global mid-ocean ridge basalts covering major ridge segments of the world and spanning a broad range in latitudes, chemical and radiogenic isotopic compositions; 2) ocean island basalts from Hawaiian (Koolau, Kilauea and Loihi) and French Polynesian volcanoes (Society island and Cook Austral chain); 3) olivine grains from Hawaiian volcanoes (Kilauea, Koolau and Loihi) and 4) peridotite xenoliths from Australia, China, France, Tanzania and USA. Global oceanic basalts and peridotite xenoliths have a limited (<0.2 ‰) variation in Mg isotopic composition, with an average δ26Mg = -0.25 relative to DSM3. Olivines from Hawaiian lavas have δ26Mg ranging from -0.43 to +0.03, with most having compositions identical to basalts and peridotites. Therefore, the mantle’s δ26Mg value is estimated to be ~ -0.25 ± 0.1 (2SD), different from that reported by Wiechert and Halliday (2007; δ26Mg = ~ 0) but similar to more recent studies (δ26Mg = -0.27 to -0.33) (Teng et al. 2007; Handler et al. 2009; Yang et al., 2009). Moreover, we suggest the Earth, as represented by the mantle, has a Mg isotopic composition similar to chondrites (δ26Mg = ~-0.33). The need for a model such as that of Wiechert and Halliday (2007) that involves sorting of chondrules and calcium

Monitoring Natural Biodegradation of TCE in Fractured Sedimentary Rocks Using delta 13C of TCE and its Degradation Products: Estimating Isotopic Fractionation Factor under Field Conditions

NASA Astrophysics Data System (ADS)

Revesz, K.; Shapiro, A. M.; Tiedeman, C.; Goode, D. J.; Lacombe, P. J.; Imbrigiotta, T. E.

2008-12-01

The isotopic ratio of 13C/12C, expressed in delta13CVPDB per mill for trichloroethene (TCE), can differentiate between microbial degradation and other processes (dilution, dispersion, and sorption) that can also affect the concentration of TCE and its degradation products. The delta13C of TCE isotopically fractionates during microbial degradation; however, it remains practically unchanged during other processes. The isotope fractionation factor (alpha) estimated under laboratory conditions, however, may not be representative of microbial degradation in natural ground waters. Estimating alpha under field conditions provides evidence of the presence or absence of in situ microbial degradation and provides valuable information on the in situ processes that affect the fate and transport of chlorinated hydrocarbons. Our modified analytical method of analyzing for the isotopic ratio proved to be comparable to previously published methods. Isotope values were stable within analytical uncertainty in sample sizes ranging from 22 to 2200 nanomoles. Prepared standard mixtures of TCE and DCEs (trans- and cis- dichloroethene) were analyzed after every five field samples, and were stable during the time period that field samples were processed (a year). Water samples were collected from multiple boreholes completed in the fractured mudstone underlying the former Naval Air Warfare Center, West Trenton, NJ, and analyzed for delta13C of the chlorinated hydrocarbons. The results showed an ongoing natural microbial degradation following the typical dehalogenation pathway: TCE to DCE (trans- and cis-dichloroethene) to VC (vinyl chloride). The carbon isotope enrichment due to fractionation was smaller between TCE to DCE degradation than the enrichment between DCE to VC degradation, which is consistent with previous investigations. Results also showed a correlation between delta13C of TCE and the transmissivity of the boreholes where water samples were collected. We assumed that

Evolution of nuclear structure in neutron-rich odd-Zn isotopes and isomers

NASA Astrophysics Data System (ADS)

Wraith, C.; Yang, X. F.; Xie, L.; Babcock, C.; Bieroń, J.; Billowes, J.; Bissell, M. L.; Blaum, K.; Cheal, B.; Filippin, L.; Garcia Ruiz, R. F.; Gins, W.; Grob, L. K.; Gaigalas, G.; Godefroid, M.; Gorges, C.; Heylen, H.; Honma, M.; Jönsson, P.; Kaufmann, S.; Kowalska, M.; Krämer, J.; Malbrunot-Ettenauer, S.; Neugart, R.; Neyens, G.; Nörtershäuser, W.; Nowacki, F.; Otsuka, T.; Papuga, J.; Sánchez, R.; Tsunoda, Y.; Yordanov, D. T.

2017-08-01

Collinear laser spectroscopy was performed on Zn (Z = 30) isotopes at ISOLDE, CERN. The study of hyperfine spectra of nuclei across the Zn isotopic chain, N = 33- 49, allowed the measurement of nuclear spins for the ground and isomeric states in odd-A neutron-rich nuclei up to N = 50. Exactly one long-lived (>10 ms) isomeric state has been established in each 69-79Zn isotope. The nuclear magnetic dipole moments and spectroscopic quadrupole moments are well reproduced by large-scale shell-model calculations in the f5pg9 and fpg9d5 model spaces, thus establishing the dominant term in their wave function. The magnetic moment of the intruder Iπ = 1 /2+ isomer in 79Zn is reproduced only if the νs1/2 orbital is added to the valence space, as realized in the recently developed PFSDG-U interaction. The spin and moments of the low-lying isomeric state in 73Zn suggest a strong onset of deformation at N = 43, while the progression towards 79Zn points to the stability of the Z = 28 and N = 50 shell gaps, supporting the magicity of 78Ni.

Reinterpreting the Early Cretaceous Sulfur Isotope Records: Implications for the Evolution of Seawater Chemistry

NASA Astrophysics Data System (ADS)

Mills, J. V.; Gomes, M. L.; Sageman, B. B.; Jacobson, A. D.; Hurtgen, M. T.

2013-12-01

The geologic record of the Cretaceous is punctuated by several periods of high organic carbon burial interpreted to represent global Ocean Anoxic Events (OAEs). In addition to the short-term (<1-Myr) changes in carbon (C) cycling associated with OAEs, evidence from a number of geochemical proxies has been interpreted to represent large-scale changes in ocean chemistry during the period. Specifically, the sulfur (S) isotope composition of early Cretaceous seawater sulfate as recorded in marine barite exhibits an ~5 permil shift in d34Ssulfate that persists for ~15Myr before returning to pre-excursion values. Superimposed upon this long-term shift in S-isotopes is OAE1a, the second major anoxic event recognized in the Cretaceous. Two hypotheses have been proposed to explain this S isotope perturbation: (1) massive evaporite deposition associated with rifting during the opening of the South Atlantic and a corresponding decrease in pyrite burial rates and (2) increased inputs of volcanic-derived S due to extensive LIP-volcanism. While there is geologic evidence for both evaporite deposition and enhanced hydrothermal activity, the relative influence of these potential driving factors remains largely unconstrained. Variation in the strontium (Sr) isotope composition of marine carbonates provides a tool for distinguishing between these influences. We examine the S isotope composition of carbonate-associated sulfate (CAS) spanning the Barremian through Aptian from Resolution Guyot (ODP Site 866) and compare the S isotope record to time equivalent records of carbon and strontium isotopes. Correlative changes in the C, S, and Sr cycles are observed: an ~5 permil shift in d34Ssulfate, which begins at the onset of OAE1a and continues after the positive d13Ccarb excursion, is accompanied by a contemporaneous, parallel shift in 87Sr/86Sr to unradiogenic values. The tight coupling observed between S and Sr throughout the interval is highly suggestive of a common driving mechanism

VELOCITY SELECTOR METHOD FOR THE SEPARATION OF ISOTOPES

DOEpatents

Britten, R.J.

1957-12-31

A velocity selector apparatus is described for separating and collecting an enriched fraction of the isotope of a particular element. The invention has the advantage over conventional mass spectrometers in that a magnetic field is not used, doing away with the attendant problems of magnetic field variation. The apparatus separates the isotopes by selectively accelerating the ionized constituents present in a beam of the polyisotopic substance that are of uniform kinetic energy, the acceleration being applied intermittently and at spaced points along the beam and in a direction normal to the direction of the propagation of the uniform energy beam whereby a transverse displacement of the isotopic constituents of different mass is obtained.

The Isotopic Record of Elevation Thresholds in Continental Plateaus to Atmospheric Circulation

NASA Astrophysics Data System (ADS)

Mulch, A.; Chamberlain, C. P.; Graham, S. A.; Teyssier, C.; Cosca, M. A.

2011-12-01

High-elevation orogenic plateaus and mountain ranges exert a strong control on global climate and precipitation patterns and interact with lithospheric and upper mantle tectonic processes as well as atmospheric circulation. Reconstructing the history of surface elevation thus not only provides a critical link between erosional and tectonic processes but also ties Earth surface processes to the long-term climate history of our planet. This interaction, however, has important implications when using stable isotopes (O, H) as proxies for landscape and terrestrial climate evolution as interacting land surface properties (elevation, relief, vegetation cover) and atmospheric circulation patterns (upstream moisture path) may attain threshold conditions that can cloak or amplify the impact of topography on isotopes in precipitation. A large number of stable isotope studies in lacustrine and pedogenic environments of intermontane basins record the isotopic and sedimentologic fingerprint of the evolving landscape of the Cenozoic western North American Cordillera. In general we observe the onset of strong oxygen isotope in precipitation gradients along the eastward and westward flanks of the Cordilleran orogen and associated 18O-depleted moisture within the Cordilleran hinterland to develop no later than 50-55 Ma in British Columbia and Washington, 49 Ma in Montana, and 39-40 Ma in Nevada. However, some of these shifts to very low oxygen isotope compositions in meteoric water occur at rates that by far exceed those that could be attributed to tectonic surface uplift alone. Here we present a multi-proxy approach from the Elko Basin (NV) that ties stable and radiogenic tracers of landscape evolution with high resolution Ar-Ar geochronology. In pedogenic and lacustrine deposits of the Elko basin we observe a change in oxygen isotope ratios that is far too large (6-8 %) and rapid (<200 000 a) to be solely due to changes in elevation. Rather we suggest that the combined effects of

Gas and Isotope Geochemistry of 81 Steam Samples from Wells in The Geysers Geothermal Field, Sonoma and Lake Counties, California

USGS Publications Warehouse

Lowenstern, Jacob B.; Janik, Cathy J.; Fahlquist, Lynne; Johnson, Linda S.

1999-01-01

The Geysers geothermal field in northern California, with about 2000-MW electrical capacity, is the largest geothermal field in the world. Despite its importance as a resource and as an example of a vapor-dominated reservoir, very few complete geochemical analyses of the steam have been published (Allen and Day, 1927; Truesdell and others, 1987). This report presents data from 90 steam, gas, and condensate samples from wells in The Geysers geothermal field in northern California. Samples were collected between 1978 and 1991. Well attributes include sampling date, well name, location, total depth, and the wellhead temperature and pressure at which the sample was collected. Geochemical characteristics include the steam/gas ratio, composition of noncondensable gas (relative proportions of CO2, H2S, He, H2, O2, Ar, N2, CH4, and NH3), and isotopic values for deltaD and delta18O of H2O, delta13C of CO2, and delta34S of H2S. The compilation includes 81 analyses from 74 different production wells, 9 isotopic analyses of steam condensate pumped into injection wells, and 5 complete geochemical analyses on gases from surface fumaroles and bubbling pools. Most samples were collected as saturated steam and plot along the liquid-water/steam boiling curve. Steam-togas ratios are highest in the southeastern part of the geothermal field and lowest in the northwest, consistent with other studies. Wells in the Northwest Geysers are also enriched in N2/Ar, CO2 and CH4, deltaD, and delta18O. Well discharges from the Southeast Geysers are high in steam/gas and have isotopic compositions and N2/Ar ratios consistent with recharge by local meteoric waters. Samples from the Central Geysers show characteristics found in both the Southeast and Northwest Geysers. Gas and steam characteristics of well discharges from the Northwest Geysers are consistent with input of components from a high-temperature reservoir containing carbonrich gases derived from the host Franciscan rocks. Throughout the

Isotope effect of mercury diffusion in air

PubMed Central

Koster van Groos, Paul G.; Esser, Bradley K.; Williams, Ross W.; Hunt, James R.

2014-01-01

Identifying and reducing impacts from mercury sources in the environment remains a considerable challenge and requires process based models to quantify mercury stocks and flows. The stable isotope composition of mercury in environmental samples can help address this challenge by serving as a tracer of specific sources and processes. Mercury isotope variations are small and result only from isotope fractionation during transport, equilibrium, and transformation processes. Because these processes occur in both industrial and environmental settings, knowledge of their associated isotope effects is required to interpret mercury isotope data. To improve the mechanistic modeling of mercury isotope effects during gas phase diffusion, an experimental program tested the applicability of kinetic gas theory. Gas-phase elemental mercury diffusion through small bore needles from finite sources demonstrated mass dependent diffusivities leading to isotope fractionation described by a Rayleigh distillation model. The measured relative atomic diffusivities among mercury isotopes in air are large and in agreement with kinetic gas theory. Mercury diffusion in air offers a reasonable explanation of recent field results reported in the literature. PMID:24364380

Isotope effect of mercury diffusion in air.

PubMed

Koster van Groos, Paul G; Esser, Bradley K; Williams, Ross W; Hunt, James R

2014-01-01

Identifying and reducing impacts from mercury sources in the environment remains a considerable challenge and requires process based models to quantify mercury stocks and flows. The stable isotope composition of mercury in environmental samples can help address this challenge by serving as a tracer of specific sources and processes. Mercury isotope variations are small and result only from isotope fractionation during transport, equilibrium, and transformation processes. Because these processes occur in both industrial and environmental settings, knowledge of their associated isotope effects is required to interpret mercury isotope data. To improve the mechanistic modeling of mercury isotope effects during gas phase diffusion, an experimental program tested the applicability of kinetic gas theory. Gas-phase elemental mercury diffusion through small bore needles from finite sources demonstrated mass dependent diffusivities leading to isotope fractionation described by a Rayleigh distillation model. The measured relative atomic diffusivities among mercury isotopes in air are large and in agreement with kinetic gas theory. Mercury diffusion in air offers a reasonable explanation of recent field results reported in the literature.

Multiple stable isotope fronts during non-isothermal fluid flow

NASA Astrophysics Data System (ADS)

Fekete, Szandra; Weis, Philipp; Scott, Samuel; Driesner, Thomas

2018-02-01

develop in kinetically limited systems, which propagates with the advection speed of the incoming fluid and is, therefore, traveling fastest. The results show that oxygen isotope signatures at thermal fronts recorded in rocks and veins that experienced isotope exchange with fluids can easily be misinterpreted, namely if bulk analytical techniques are applied. However, stable isotope microanalysis on precipitated minerals may - if later isotope exchange is kinetically limited - provide a valuable archive of the transient thermal and hydrological evolution of a system.

Environment-Assisted Speed-up of the Field Evolution in Cavity Quantum Electrodynamics

DOE PAGES

Cimmarusti, A. D.; Yan, Z.; Patterson, B. D.; ...

2015-06-11

We measure the quantum speed of the state evolution of the field in a weakly-driven optical cavity QED system. To this end, the mode of the electromagnetic field is considered as a quantum system of interest with a preferential coupling to a tunable environment: the atoms. By controlling the environment, i.e., changing the number of atoms coupled to the optical cavity mode, an environment assisted speed-up is realized: the quantum speed of the state re-population in the optical cavity increases with the coupling strength between the optical cavity mode and this non-Markovian environment (the number of atoms).

Stable isotopes in nitrous oxide emitted from tropical rain forest soils and agricultural fields: Implications for the global atmospheric nitrous oxide budget

NASA Astrophysics Data System (ADS)

Perez, Tibisay Josefina

Nitrous oxide (N2O) is an important greenhouse gas and is the primary source of NOx in the stratosphere. Large uncertainties exist in the global N2O budget, mainly due to the high uncertainty associated with source estimates. Recently, stable isotopes of 15N and 18O have been proposed as a tool to better constrain the N2O global budget. This thesis develops analytical methods for constraining and measuring stable isotopes in N2O emitted from soils and reports initial investigations of N2O isotopes from the largest sources in the global N2O budget: tropical rain forest soils and agricultural fields. We found significant differences in the isotopic composition of N 2O emitted from tropical rain forest soils and fertilized agricultural fields. Differences were largest for 15N. Emission-weighted δ 15N-N2O were -26 +/- 2.5‰ s.d., n = 3 (Costa Rican forest), -6.6 +/- 11.3‰ s.d. n = 14 (Brazilian forest) and -36.7 +/- 9.2‰ s.d. n = 19 (Mexican agricultural field and Costa Rican Papaya plantation). We attribute the large range in δ 15N from tropical rain forests, where denitrification is the main source of N2O, to differences in the degree of N2O to N2 reduction. We attribute the very light δ15N values in fertilized agricultural fields to the enhanced nitrogen availability in the soils which facilitates higher fractionation between substrates and products. Similarly, in the Brazilian tropical forest lighter δ 15N-N2O from a local area of enhanced emission is attributed to locally more abundant N- substrate in that particular soil site. If the increase of N2O in the troposphere over the past 100 years is attributable to increased use of N fertilizer, and assuming that light δ 15N- N2O isotopic values are associated with agricultural practices, we expect the δ15N-N2O in the troposphere to have decreased since pre-industrial times. Theoretically, comparison of 15N and 18O signature of emitted N2O with precursors species (NO3 -, NH4+, H2O and O 2) should uniquely

Evolution of scalar fields surrounding black holes on compactified constant mean curvature hypersurfaces

NASA Astrophysics Data System (ADS)

Morales, Manuel D.; Sarbach, Olivier

2017-02-01

Motivated by the goal for high accuracy modeling of gravitational radiation emitted by isolated systems, recently, there has been renewed interest in the numerical solution of the hyperboloidal initial value problem for Einstein's field equations in which the outer boundary of the numerical grid is placed at null infinity. In this article, we numerically implement the tetrad-based approach presented by Bardeen, Sarbach, and Buchman [Phys. Rev. D 83, 104045 (2011), 10.1103/PhysRevD.83.104045] for a spherically symmetric, minimally coupled, self-gravitating scalar field. When this field is massless, the evolution system reduces to a regular, first-order symmetric hyperbolic system of equations for the conformally rescaled scalar field which is coupled to a set of singular elliptic constraints for the metric coefficients. We show how to solve this system based on a numerical finite-difference approximation, obtaining stable numerical evolutions for initial black hole configurations which are surrounded by a spherical shell of scalar field, part of which disperses to infinity and part of which is accreted by the black hole. As a nontrivial test, we study the tail decay of the scalar field along different curves, including one along the marginally trapped tube, one describing the world line of a timelike observer at a finite radius outside the horizon, and one corresponding to a generator of null infinity. Our results are in perfect agreement with the usual power-law decay discussed in previous work. This article also contains a detailed analysis for the asymptotic behavior and regularity of the lapse, conformal factor, extrinsic curvature and the Misner-Sharp mass function along constant mean curvature slices.

Integrated carbon and chlorine isotope modeling: applications to chlorinated aliphatic hydrocarbons dechlorination.

PubMed

Jin, Biao; Haderlein, Stefan B; Rolle, Massimo

2013-02-05

We propose a self-consistent method to predict the evolution of carbon and chlorine isotope ratios during degradation of chlorinated hydrocarbons. The method treats explicitly the cleavage of isotopically different C-Cl bonds and thus considers, simultaneously, combined carbon-chlorine isotopologues. To illustrate the proposed modeling approach we focus on the reductive dehalogenation of chlorinated ethenes. We compare our method with the currently available approach, in which carbon and chlorine isotopologues are treated separately. The new approach provides an accurate description of dual-isotope effects regardless of the extent of the isotope fractionation and physical characteristics of the experimental system. We successfully applied the new approach to published experimental results on dehalogenation of chlorinated ethenes both in well-mixed systems and in situations where mass-transfer limitations control the overall rate of biodegradation. The advantages of our self-consistent dual isotope modeling approach proved to be most evident when isotope fractionation factors of carbon and chlorine differed significantly and for systems with mass-transfer limitations, where both physical and (bio)chemical transformation processes affect the observed isotopic values.

Isotopic Abundances as Tracers of the Processes of Lunar Formation

NASA Astrophysics Data System (ADS)

Pahlevan, K.

2011-12-01

Ever since Apollo, isotopic abundances have been used as tracers to study lunar formation, in particular, to study the sources of the lunar material. In the last decade, however, a number of isotopic similarities have been observed between the lunar samples and the Earth's mantle such that these two reservoirs are now known to be indistinguishable from one another to high precision for a variety of isotopic tracers. This occurs against the backdrop of a Solar System that exhibits widespread heterogeneity with respect to these tracers, a situation that strongly argues that the source of the lunar material is the silicate Earth. To reconcile this observation with the fact that the Moon is thought to result from the collision of two isotopically distinct planetary bodies, a scenario has emerged in which the material from the Moon-forming impactor and the proto-Earth are homogenized in the aftermath of the giant impact. This takes place via turbulent mixing in the time after the giant impact but before lunar accretion while the Earth-Moon system exists in the form of a continuous, high-temperature fluid. Importantly, this high-temperature phase of the evolution occurs in the presence of at least two phases (liquid + vapor) making possible chemical and isotopic fractionation. While equilibrium isotopic fractionation tends to zero at high temperatures, and the post giant impact environment experiences some of the highest temperatures encountered in the Earth sciences, there are several factors that nevertheless make equilibrium isotope effects important probes of this early evolution. (1) Because the vaporization of silicates involves decomposition reactions, the bonding environment for elements in the liquid is often very different from that in the vapor. This difference makes the magnitude of isotopic fractionation intrinsically large, even at the relevant temperatures. (2) Since the isotopic composition of a silicate liquid and co-existing vapor are distinctly

Uranium Isotope Ratios in Modern and Precambrian Soils

NASA Astrophysics Data System (ADS)

DeCorte, B.; Planavsky, N.; Wang, X.; Auerbach, D. J.; Knudsen, A. C.

2015-12-01

Uranium isotopes (δ238U values) are an emerging paleoredox proxy that can help to better understand the redox evolution of Earth's surface environment. Recently, uranium isotopes have been used to reconstruct ocean and atmospheric redox conditions (Montoya-Pino et al., 2010; Brennecka et al., 2011; Kendall et al., 2013; Dahl et al., 2014). However, to date, there have not been studies on paleosols, despite that paleosols are, arguably better suited to directly tracking the redox conditions of the atmosphere. Sedimentary δ238U variability requires the formation of the soluble, oxidized form of U, U(VI). The formation of U(VI) is generally thought to require oxygen levels orders of magnitude higher than prebiotic levels. Without significant U mobility, it would have been impossible to develop isotopically distinct pools of uranium in ancient Earth environments. Conversely, an active U redox cycle leads to significant variability in δ238U values. Here we present a temporally and geographically expansive uranium isotope record from paleosols and modern soils to better constrain atmospheric oxygen levels during the Precambrian. Preliminary U isotope measurements of paleosols are unfractionated (relative to igneous rocks), possibly because of limited fractionation during oxidation (e.g., {Wang, 2015 #478}) or insufficient atmospheric oxygen levels to oxidize U(IV)-bearing minerals in the bedrock. Further U isotope measurements of paleosols with comparison to modern soils will resolve this issue.

Optical spectroscopy of laser-produced plasmas for standoff isotopic analysis

NASA Astrophysics Data System (ADS)

Harilal, S. S.; Brumfield, B. E.; LaHaye, N. L.; Hartig, K. C.; Phillips, M. C.

2018-06-01

Rapid, in-field, and non-contact isotopic analysis of solid materials is extremely important to a large number of applications, such as nuclear nonproliferation monitoring and forensics, geochemistry, archaeology, and biochemistry. Presently, isotopic measurements for these and many other fields are performed in laboratory settings. Rapid, in-field, and non-contact isotopic analysis of solid material is possible with optical spectroscopy tools when combined with laser ablation. Laser ablation generates a transient vapor of any solid material when a powerful laser interacts with a sample of interest. Analysis of atoms, ions, and molecules in a laser-produced plasma using optical spectroscopy tools can provide isotopic information with the advantages of real-time analysis, standoff capability, and no sample preparation requirement. Both emission and absorption spectroscopy methods can be used for isotopic analysis of solid materials. However, applying optical spectroscopy to the measurement of isotope ratios from solid materials presents numerous challenges. Isotope shifts arise primarily due to variation in nuclear charge distribution caused by different numbers of neutrons, but the small proportional nuclear mass differences between nuclei of various isotopes lead to correspondingly small differences in optical transition wavelengths. Along with this, various line broadening mechanisms in laser-produced plasmas and instrumental broadening generated by the detection system are technical challenges frequently encountered with emission-based optical diagnostics. These challenges can be overcome by measuring the isotope shifts associated with the vibronic emission bands from molecules or by using the techniques of laser-based absorption/fluorescence spectroscopy to marginalize the effect of instrumental broadening. Absorption and fluorescence spectroscopy probe the ground state atoms existing in the plasma when it is cooler, which inherently provides narrower

Genetic variation in carbon isotope discrimination and its relationship to growth under field conditions in full-sib families of Picea mariana

Treesearch

Lawrence B. Flanagan; Kurt H. Johnsen

1995-01-01

Measurements of the stable carbon isotope composition of leaf tissue were made on Picea mariana (Mill.) B.S.P. trees from four full-sib families grown on three different field sites at the Petawawa National Forestry Institute, Ontario, Canada. The four families chosen exhibited genetic variation for growth characteristics. Genetic...

Origin and thermal evolution of Mars

NASA Technical Reports Server (NTRS)

Schubert, G.; Solomon, Sean C.; Turcotte, D. L.; Drake, M. J.; Sleep, N. H.

1993-01-01

The thermal evolution of Mars is governed by subsolidus mantle convection beneath a thick lithosphere. Models of the interior evolution are developed by parameterizing mantle convective heat transport in terms of mantle viscosity, the superadiabatic temperature rise across the mantle and mantle heat production. Geological, geophysical, and geochemical observations of the composition and structure of the interior and of the timing of major events in Martian evolution, such as global differentiation, atmospheric outgassing and the formation of the hemispherical dichotomy and Tharsis, are used to constrain the model computations. Isotope systematics of SNC meteorites suggest core formation essentially contemporaneously with the completion of accretion. Other aspects of this investigation are discussed.

Biodegradation of Chlorofluorocarbons in a Groundwater Plume using Compound Specific Carbon Isotope Analysis

NASA Astrophysics Data System (ADS)

Phillips, E.; Manna, J.; Horst, A.; Gilevska, T.; Sherwood Lollar, B.; Mack, E. E.; Seger, E.; Lutz, E. J.; Norcoss, S.; Morgan, S. E.; West, K. A.; Dworatzek, S.; Webb, J.

2017-12-01

Compound specific isotope analysis (CSIA) measures isotope ratios of organic hydrocarbons to monitor intrinsic bioremediation processes that can transform contaminants in field settings. The fraction of original contaminant remaining can be determined using the measured isotope ratio of the contaminant by an experimentally determined fractionation factor. In this study, two separate biotransformation experiments were performed in the Stable Isotope Laboratory at the University of Toronto using CSIA. In these two experiments, a mixed culture derived from a contaminated site was amended with trichlorotrifluoroethane (CFC-113), or trichlorofluoromethane (CFC-11), respectively. The concentrations and carbon isotope ratios of CFC-113, or CFC-11 were analyzed to calculate the fractionation factor for the transformation of each compound. Subsequently, groundwater samples from 9 wells at a historically contaminated site were collected and analyzed. The experimentally determined fractionation factors were then used to evaluate the extent of transformation that had occurred at the field site. In the laboratory studies, significant carbon isotope fractionation was observed for both CFC-113 and CFC-11 as biotransformation proceeded. This significant fractionation is beneficial when evaluating biotransformation at field sites as it can be clearly differentiated from the effects of other physical processes such as transport, or volatilization. Although there was significant variation in the carbon isotope values of CFC-113 between different well locations at the field site, these variations may be due to differences in source carbon isotope signatures. For CFC-11, much more significant isotopic variation was observed within the same well and between wells, showing trends consistent with in situ biotransformation. Results from this study demonstrate that CSIA can be successfully applied to evaluate the extent of transformation of chlorofluorocarbons (CFCs) at contaminated field

Carbon isotopic studies of organic matter in Precambrian rocks.

NASA Technical Reports Server (NTRS)

Oehler, D. Z.; Schopf, J. W.; Kvenvolden, K. A.

1972-01-01

A survey has been undertaken of the carbon composition of the total organic fraction of a suite of Precambrian sediments to detect isotopic trends possibly correlative with early evolutionary events. Early Precambrian cherts of the Fig Tree and upper and middle Onverwacht groups of South Africa were examined for this purpose. Reduced carbon in these cherts was found to be isotopically similar to photosynthetically produced organic matter of younger geological age. Reduced carbon in lower Onverwacht cherts was found to be anomalously heavy; it is suggested that this discontinuity may reflect a major event in biological evolution.

Deformation-induced spatiotemporal fluctuation, evolution and localization of strain fields in a bulk metallic glass

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wu, Yuan; Bei, Hongbin; Wang, Yanli

Deformation behavior and local strain evolutions upon loading and unloading of a bulk metallic glass (BMG) were systematically investigated by in situ digital image correlation (DIC). Distinct fluctuations and irreversible local strains were observed before the onset of macroscopic yielding. Statistical analysis shows that these fluctuations might be related to intrinsic structural heterogeneities, and that the evolution history and characteristics of local strain fields play an important role in the subsequent initiation of shear bands. Effects of sample size, pre-strain, and loading conditions were systematically analyzed in terms of the probability distributions of the resulting local strain fields. It ismore » found that a higher degree of local shear strain heterogeneity corresponds to a more ductile stressestrain curve. Implications of these findings are discussed for the design of new materials.« less

Deformation-induced spatiotemporal fluctuation, evolution and localization of strain fields in a bulk metallic glass

DOE PAGES

Wu, Yuan; Bei, Hongbin; Wang, Yanli; ...

2015-05-16

Deformation behavior and local strain evolutions upon loading and unloading of a bulk metallic glass (BMG) were systematically investigated by in situ digital image correlation (DIC). Distinct fluctuations and irreversible local strains were observed before the onset of macroscopic yielding. Statistical analysis shows that these fluctuations might be related to intrinsic structural heterogeneities, and that the evolution history and characteristics of local strain fields play an important role in the subsequent initiation of shear bands. Effects of sample size, pre-strain, and loading conditions were systematically analyzed in terms of the probability distributions of the resulting local strain fields. It ismore » found that a higher degree of local shear strain heterogeneity corresponds to a more ductile stressestrain curve. Implications of these findings are discussed for the design of new materials.« less

Development and Deployment of a Portable Water Isotope Analyzer for Accurate, Continuous and High-Frequency Oxygen and Hydrogen Isotope Measurements in Water Vapor and Liquid Water

NASA Astrophysics Data System (ADS)

Dong, Feng; Baer, Douglas

2010-05-01

Stable isotopes of water in liquid and vapor samples are powerful tracers to investigate the hydrological cycle and ecological processes. Therefore, continuous, in-situ and accurate measurements of del_18O and del_2H are critical to advance the understanding of water cycle dynamics around the globe. Furthermore, the combination of meteorological techniques and high-frequency isotopic water measurements can provide detailed time-resolved information on the eco-physiological performance of plants and enable improved understanding of water fluxes at ecosystem scales. In this work, we present recent laboratory development and field deployment of a novel Water Vapor Isotope Analyzer (WVIA), based on cavity enhanced laser absorption spectroscopy, capable of simultaneous in-situ measurements of del_18O and del_2H and water mixing ratio with high precision and high frequency (up to 10 Hz measurement rate). In addition, to ensure the accuracy of the water vapor isotope measurements, a novel Water Vapor Isotope Standard Source (WVISS), based on the instantaneous evaporation of micro-droplets of liquid water (with known isotope composition), has been developed to provide the reference water vapor with widely adjustable mixing ratio (500-30,000 ppmv) for real-time calibration of the WVIA. The comprehensive system that includes the WVIA and WVISS has been validated in extensive laboratory and field studies to be insensitive to ambient temperature changes (5-40 C) and to changes in water mixing ratio over a wide range of mixing ratios. In addition, by operating in the dual inlet mode, measurement drift has essentially been eliminated. The system (WVIA+WVISS) has also been deployed for long-term unattended continuous measurements in the field. In addition to water vapor isotope measurements, the new Water Vapor Isotopic Standard Source (WVISS) may be combined with the WVIA to provide continuous isotopic measurements of liquid water samples at rapid data rate. The availability of

Evolution of vector magnetic fields and the August 27 1990 X-3 flare

NASA Technical Reports Server (NTRS)

Wang, Haimin

1992-01-01

Vector magnetic fields in an active region of the sun are studied by means of continuous observations of magnetic-field evolution emphasizing magnetic shear build-up. The vector magnetograms are shown to measure magnetic fields correctly based on concurrent observations and a comparison of the transverse field with the H alpha fibril structure. The morphology and velocity pattern are examined, and these data and the shear build-up suggest that the active region's two major footprints are separated by a region with flows, new flux emergence, and several neutral lines. The magnetic shear appears to be caused by the collision and shear motion of two poles of opposite polarities. The transverse field is shown to turn from potential to sheared during the process of flux cancellation, and this effect can be incorporated into existing models of magnetic flux cancellation.

C-isotope composition of fossil sedges and grasses

NASA Astrophysics Data System (ADS)

Kurschner, Wolfram M.

2010-05-01

C4 plants differ from C3 plants regarding their anatomy and their C-isotope composition. Both features can be used in the geological record to determine the presence of C4 plants. Yet, the evolution of the C4 pathway in the fossil record is enigmatic as palaeobotanical and geological evidence for C4 plants is sparse. The oldest structural evidence for Kranz anatomy has been found in Late Miocene permineralized grass leaf remains. But studies on the C-isotope composition of sedimentary organic matter indicate that abundant C4 biomass was present in N-America and Asia throughout the Miocene in expanding savannahs and grasslands. The success of C4 plants appears to be related also to an increasing seasonal aridity in the tropical climate belts and the co-evolution of grazers. However, C- isotope composition of palaeosols or vertebrate teeth only allows to estimate the abundance of C4 plant biomass in the vegetation or in the diet without further taxonomical specification which plant groups would have had C4 metabolism. In this contribution the first extensive C-isotope analysis of fossil seeds of sedges and a few grasses are presented. The age of the carpological material ranges from Late Eocene to Pliocene and was collected from several central European brown coal deposits. The 52 different taxa studied include several species of Carex, Cladiocarya, Eriopherum, Eleocharis, Scirpus, Sparganium. Most of them representing herbaceous elements of a (sub)tropical vegetation growing near the edge of a lake. The C-isotope composition of the fossil seeds varies between -30 and -23 o/oo indicating C3 photosynthesis. This first systematic inventory shows that C4 plants were absent in the European (sub)tropical brown coal forming wetland vegetation during the Tertiary. These preliminary data are in agreement with phylogenetic studies which predict the origin of C4 plants outside the European realm.

Reservoir computer predictions for the Three Meter magnetic field time evolution

NASA Astrophysics Data System (ADS)

Perevalov, A.; Rojas, R.; Lathrop, D. P.; Shani, I.; Hunt, B. R.

2017-12-01

The source of the Earth's magnetic field is the turbulent flow of liquid metal in the outer core. Our experiment's goal is to create Earth-like dynamo, to explore the mechanisms and to understand the dynamics of the magnetic and velocity fields. Since it is a complicated system, predictions of the magnetic field is a challenging problem. We present results of mimicking the three Meter experiment by a reservoir computer deep learning algorithm. The experiment is a three-meter diameter outer sphere and a one-meter diameter inner sphere with the gap filled with liquid sodium. The spheres can rotate up to 4 and 14 Hz respectively, giving a Reynolds number near to 108. Two external electromagnets apply magnetic fields, while an array of 31 external and 2 internal Hall sensors measure the resulting induced fields. We use this magnetic probe data to train a reservoir computer to predict the 3M time evolution and mimic waves in the experiment. Surprisingly accurate predictions can be made for several magnetic dipole time scales. This shows that such a complicated MHD system's behavior can be predicted. We gratefully acknowledge support from NSF EAR-1417148.

Geochemical Evolution of the Louisville Seamount Chain

NASA Astrophysics Data System (ADS)

Vanderkluysen, L.; Mahoney, J. J.; Koppers, A. A.; Lonsdale, P. F.

2007-12-01

The Louisville seamount chain is a 4300 km long chain of submarine volcanoes in the southwestern Pacific that is commonly thought to represent a hotspot track. It spans an ~80 Myr age range, comparable to that of the Hawaiian-Emperor chain (Koppers et al., G-cubed, 5 (6), 2004). The few previously dredged igneous samples are dominantly basaltic and alkalic, and have been inferred to represent post-shield volcanism (Hawkins et al., AGU Monograph, 43, 235, 1987). Their isotope and trace element signatures suggest an unusually homogenous mantle source (Cheng et al., AGU Monograph, 43, 283, 1987). Dredging in 2006, during the AMAT02RR cruise of the R.V. Revelle, was carried out in the hope of recovering both shield and post-shield samples and of exploring the geochemical evolution of the chain. Igneous rocks were recovered from 33 stations on 23 seamounts covering some 47 Myr of the chain's history. Our study, focusing on the major and trace element and Sr, Nd and Pb isotopic characteristics of these samples, shows that all are alkalic basalts, basanites and tephrites containing normative nepheline. Variations in major and trace elements appear to be controlled predominantly by variable extents of melting and fractional crystallization, with little influence from mantle source heterogeneity. Indeed, age-corrected isotopic values define only a narrow range, in agreement with long-term source homogeneity relative to the scale of melting; e.g., ɛNd varies from +4.1 to +5.7, 206Pb/204Pb from 19.048 to 19.281, and 87Sr/86Sr from 0.70362 to 0.70398. These values broadly fall within the fields of the proposed "C" or "FOZO" mantle end-members. However, small variations are present, with less radiogenic Nd and Pb isotope ratios at the older, western end of the chain, defining a trend toward a broadly EM2-like composition. Although some workers have postulated that the Louisville hotspot was the source of the ~120 Myr Ontong Java Plateau, our samples are isotopically distinct

Isotope composition and volume of Earth’s early oceans

PubMed Central

Pope, Emily C.; Bird, Dennis K.; Rosing, Minik T.

2012-01-01

Oxygen and hydrogen isotope compositions of Earth’s seawater are controlled by volatile fluxes among mantle, lithospheric (oceanic and continental crust), and atmospheric reservoirs. Throughout geologic time the oxygen mass budget was likely conserved within these Earth system reservoirs, but hydrogen’s was not, as it can escape to space. Isotopic properties of serpentine from the approximately 3.8 Ga Isua Supracrustal Belt in West Greenland are used to characterize hydrogen and oxygen isotope compositions of ancient seawater. Archaean oceans were depleted in deuterium [expressed as δD relative to Vienna standard mean ocean water (VSMOW)] by at most 25 ± 5‰, but oxygen isotope ratios were comparable to modern oceans. Mass balance of the global hydrogen budget constrains the contribution of continental growth and planetary hydrogen loss to the secular evolution of hydrogen isotope ratios in Earth’s oceans. Our calculations predict that the oceans of early Earth were up to 26% more voluminous, and atmospheric CH4 and CO2 concentrations determined from limits on hydrogen escape to space are consistent with clement conditions on Archaean Earth. PMID:22392985

The evolution of magma during continental rifting: New constraints from the isotopic and trace element signatures of silicic magmas from Ethiopian volcanoes

NASA Astrophysics Data System (ADS)

Hutchison, William; Mather, Tamsin A.; Pyle, David M.; Boyce, Adrian J.; Gleeson, Matthew L. M.; Yirgu, Gezahegn; Blundy, Jon D.; Ferguson, David J.; Vye-Brown, Charlotte; Millar, Ian L.; Sims, Kenneth W. W.; Finch, Adrian A.

2018-05-01

Magma plays a vital role in the break-up of continental lithosphere. However, significant uncertainty remains about how magma-crust interactions and melt evolution vary during the development of a rift system. Ethiopia captures the transition from continental rifting to incipient sea-floor spreading and has witnessed the eruption of large volumes of silicic volcanic rocks across the region over ∼45 Ma. The petrogenesis of these silicic rocks sheds light on the role of magmatism in rift development, by providing information on crustal interactions, melt fluxes and magmatic differentiation. We report new trace element and Sr-Nd-O isotopic data for volcanic rocks, glasses and minerals along and across active segments of the Main Ethiopian (MER) and Afar Rifts. Most δ18 O data for mineral and glass separates from these active rift zones fall within the bounds of modelled fractional crystallization trajectories from basaltic parent magmas (i.e., 5.5-6.5‰) with scant evidence for assimilation of Pan-African Precambrian crustal material (δ18 O of 7-18‰). Radiogenic isotopes (εNd = 0.92- 6.52; 87Sr/86Sr = 0.7037-0.7072) and incompatible trace element ratios (Rb/Nb <1.5) are consistent with δ18 O data and emphasize limited interaction with Pan-African crust. However, there are important regional variations in melt evolution revealed by incompatible elements (e.g., Th and Zr) and peralkalinity (molar Na2 O +K2 O /Al2O3). The most chemically-evolved peralkaline compositions are associated with the MER volcanoes (Aluto, Gedemsa and Kone) and an off-axis volcano of the Afar Rift (Badi). On-axis silicic volcanoes of the Afar Rift (e.g., Dabbahu) generate less-evolved melts. While at Erta Ale, the most mature rift setting, peralkaline magmas are rare. We find that melt evolution is enhanced in less mature continental rifts (where parental magmas are of transitional rather than tholeiitic composition) and regions of low magma flux (due to reduced mantle melt productivity

Coupled extremely light Ca and Fe isotopes in peridotites

NASA Astrophysics Data System (ADS)

Zhao, Xinmiao; Zhang, Zhaofeng; Huang, Shichun; Liu, Yufei; Li, Xin; Zhang, Hongfu

2017-07-01

Large metal stable isotopic variations have been observed in both extraterrestrial and terrestrial samples. For example, Ca exhibits large mass-dependent isotopic variation in terrestrial igneous rocks and mantle minerals (on the order of ∼2‰ variation in 44Ca/40Ca). A thorough assessment and understanding of such isotopic variations in peridotites provides important constraints on the evolution and compositon of the Earth's mantle. In order to better understand the Ca and Fe isotopic variations in terrestrial silicate rocks, we report Ca isotopic compositions in a set of peridotitic xenoliths from North China Craton (NCC), which have been studied for Fe isotopes. These NCC peridotites have large Ca and Fe isotopic variations, with δ44/40Ca ranging from -0.08 to 0.92 (delta value relative to SRM915a) and δ57/54Fe (delta value relative to IRMM-014) ranging from -0.61 to 0.16, and these isotopic variations are correlated with large Mg# (100 × Mg/(Mg + Fe) molar ratio) variation, ranging from 80 to 90. Importantly, NCC Fe-rich peridotites have the lowest 44Ca/40Ca and 57Fe/54Fe ratios in all terrestrial silicate rocks. In contrast, although ureilites, mantle rocks from a now broken differentiated asteroid(s), have large Mg# variation, from 70 to 92, they have very limited δ57Fe/54Fe variation (0.03-0.21, delta value relative to IRMM-014). Our model calculations show that the coupled extremely light Ca-Fe isotopic signatures in NCC Fe-rich peridotites most likely reflect kinetic isotopic fractionation during melt-peridotite reaction on a timescale of several to 104 years. In addition, our new data and compiled literature data show a possible compositional effect on the inter-mineral Ca isotopic fractionation between co-existing clinopyroxene and orthopyroxene pairs.

A field-deployable compound-specific isotope analyzer based on quantum cascade laser and hollow waveguide

NASA Astrophysics Data System (ADS)

Wu, Sheng; Deev, Andrei

2013-01-01

A field deployable Compound Specific Isotope Analyzer (CSIA) coupled with capillary chromatogrpahy based on Quantum Cascade (QC) lasers and Hollow Waveguide (HWG) with precision and chemical resolution matching mature Mass Spectroscopy has been achieved in our laboratory. The system could realize 0.3 per mil accuracy for 12C/13C for a Gas Chromatography (GC) peak lasting as short as 5 seconds with carbon molar concentration in the GC peak less than 0.5%. Spectroscopic advantages of HWG when working with QC lasers, i.e. single mode transmission, noiseless measurement and small sample volume, are compared with traditional free space and multipass spectroscopy methods.

Temperature effects on the fractionation of multiple sulfur isotopes by Thermodesulfobacterium and Desulfovibrio strains

NASA Astrophysics Data System (ADS)

Wang, P.; Sun, C.; Ono, S.; Lin, L.

2012-12-01

Microbial dissimilatory sulfate reduction is one of the major mechanisms driving anaerobic mineralization of organic matter in global ocean. While sulfate-reducing prokaryotes are well known to fractionate sulfur isotopes during dissimilatory sulfate reduction, unraveling the isotopic compositions of sulfur-bearing minerals preserved in sedimentary records could provide invaluable constraints on the evolution of seawater chemistry and metabolic pathways. Variations in the sulfur isotope fractionations are partly due to inherent differences among species and also affected by environmental conditions. The isotope fractionations caused by microbial sulfate reduction have been interpreted to be a sequence of enzyme-catalyzed isotope fractionation steps. Therefore, the fractionation factor depends on (1) the sulfate flux into and out of the cell, and (2) the flux of sulfur transformation between the internal pools. Whether the multiple sulfur isotope effect could be quantitatively predicted using such a metabolic flux model would provide insights into the cellular machinery catalyzing with sulfate reduction. This study examined the multiple sulfur isotope fractionation patterns associated with a thermophilic Thermodesulfobacterium-related strain and a mesophilic Desulfovibrio gigas over a wide temperature range. The Thermodesulfobacterium-related strain grew between 34 and 79°C with an optimal temperature at 72°C and the highest cell-specific sulfate reduction rate at 77°C. The 34ɛ values ranged between 8.2 and 31.6‰ with a maximum at 68°C. The D. gigas grew between 10 and 45 °C with an optimal temperature at 30°C and the highest cell-specific sulfate reduction rate at 41°C. The 34ɛ values ranged between 10.3 and 29.7‰ with higher magnitude at both lower and higher temperatures. The results of multiple sulfur isotope measurements expand the previously reported range and cannot be described by a solution field of the metabolic flux model, which calculates

Preliminary study on copper isotopes of the Zijinshan ore field, Fujian Province, SE China

NASA Astrophysics Data System (ADS)

Zhao, Hai-Xiang

2017-04-01

Zijinshan Cu-Au polymetallic ore field is located in Southeast China, tectonically belonging to the Interior Cathaysia Block. It is a complete porphyry-epithermal mineralization system, including Luoboling porphyry Cu-Mo deposit, Zijinshan high sulfidation Cu-Au deposit, Yueyang low sulfidation Ag-Au deposit, Wuziqilong and Longjiangting transitional style Cu deposits, etc. Main ore minerals from Zijinshan and Wuziqilong deposits are covellite and digenite. Copper isotopic compositions of these two minerals were analyzed. Copper isotope ratios are reported in the standard delta notation: δ65 Cu‰¯[ (65Cu/63Cu)Sample/(65Cu/63Cu) ERM-AE633-1] ×1000. The overall δ65Cu values for the analysed samples vary from -2.76 to 1.33‰Ṫhe Zijinshan Cu-Au deposit show large Cu isotopic variability (-2.76 to 1.33), among which covellite samples range from -2.76‰ to 0.38‰ with -0.79‰ in average and digenite samples range from -1.8‰ to 1.33‰ with -0.11‰ in average. During the leaching process of hypogene sulphides, 65Cu was leached more easily and then trapped in the supergene enrichment zone. Therefore, enrichment minerals should be enriched in 65Cu and the leached cap enriched in 63Cu. Thus the relationship of δ65Cu values for different Cu reservoirs should be leached cap minerals < hypogene sulphides < enrichment minerals. Nonexistence of enriched δ65Cu values indicate that the major copper minerals (mainly covellite and digenite) in the Zijinshan Cu-Au deposit and Wuziqilong Cu deposit are of hypogene origin rather than secondary origin. At the Wuziqilong Cu deposit, Cu isotopes has narrow range from 0.16‰ to 0.43‰ with 0.31‰ in average, which is typically of hypogene origin. Two coexisting covellite -digenite fractionations (δ65Cu =δ65Cucovellite - δ65Cudigenite) are 0.27‰ and 0.18‰ relatively. For minerals of the Cu-S system, from chalcocite (Cu2S) to covellite (CuS), proportions of Cu(II) become higher and higher. The classical definition of

The Evolution of Oblique Impact Flow Fields Using Maxwell's Z Model

NASA Technical Reports Server (NTRS)

Anderson, J. L. B.; Schultz, P. H.; Heineck, J. T.

2003-01-01

Oblique impacts are the norm rather than the exception for impact craters on planetary surfaces. This work focuses on the excavation of experimental oblique impact craters using the NASA Ames Vertical Gun Range (AVGR). Three-dimensional particle image velocimetry (3D PIV) is used to obtain quantitative data on ejection positions, three dimensional velocities and angles. These data are then used to constrain Maxwell's Z Model and follow the subsurface evolution of the excavation-stage flow-field center during oblique impacts.

Metal stable isotopes in low-temperature systems: A primer

USGS Publications Warehouse

Bullen, T.D.; Eisenhauer, A.

2009-01-01

Recent advances in mass spectrometry have allowed isotope scientists to precisely determine stable isotope variations in the metallic elements. Biologically infl uenced and truly inorganic isotope fractionation processes have been demonstrated over the mass range of metals. This Elements issue provides an overview of the application of metal stable isotopes to low-temperature systems, which extend across the borders of several science disciplines: geology, hydrology, biology, environmental science, and biomedicine. Information on instrumentation, fractionation processes, data-reporting terminology, and reference materials presented here will help the reader to better understand this rapidly evolving field.

The evolution of a calc-alkaline basic to silicic magma system: Geochemical and Rb-Sr, Sm-Nd, and 18O /16O isotopic evidence from the Late Hercynian Atesina-Cima d'Asta volcano-plutonic complex, northern Italy

NASA Astrophysics Data System (ADS)

Barth, Susanne; Oberli, Felix; Meier, Martin; Blattner, Peter; Bargossi, Giuseppe M.; Di Battistini, Gianfranco

1993-09-01

Geochemical and Sr-Nd-O isotopic data presented for basaltic andesitic to rhyolitic and for quartz noritic to monzogranitic rock suites from the Late Hercynian calc-alkaline Atesina volcanic complex (AVC) and the Cima d'Asta pluton (CAP), Southern Alps (northern Italy), provide information on both the primary magmatic processes and the effects of (mainly Triassic) hydrothermal overprint. Fluid infiltration led to mobilization of major and trace elements (K 2O, Na 2O, CaO, Rb, Sr, and Ba), opensystem behavior in total-rock Rb-Sr, and shift in δ18O to elevated values (total rock up to 16.6%. and volcanic matrix up to 17.8%.). Oxygen isotopic disequilibrium between quartz-feldspar pairs suggests water-rock interaction at medium/low temperatures. The δ18O values of quartz, the REE characterized by regular LREE enrichment/HREE depletion, and the Sm-Nd isotopic signatures, however, remained virtually unaffected by secondary processes. The initial ɛNd values (at 270 Ma) of the AVC and CAP magmatites are restricted to overlapping ranges of -3.6 to -6.5 and of -2.7 to -6.5, respectively, indicating significant crustal contribution; these values and associated T DM model ages of 1.1-1.6 Ga agree well with those of typical South Alpine lower crustal magmatites. The AVC and CAP rocks do not follow the "normal" trend of increasingly crustal Nd isotopic signatures with progressive degree of magma evolution expected for a single-stage AFC-type process, but instead display an inversion of this relationship. Geochemical and isotopic constraints favor a model of a large-scale MASH-type melting and mixing zone at or near the base of the continental crust. Distinct elemental enrichment/depletion and REE crossover patterns displayed by high-silica as compared to less silicic AVC rhyolites suggest subsequent magma evolution within a shallow-level compositionally zoned chamber.

Cosmic evolution of AGN with moderate-to-high radiative luminosity in the COSMOS field

NASA Astrophysics Data System (ADS)

Ceraj, L.; Smolčić, V.; Delvecchio, I.; Delhaize, J.; Novak, M.

2018-05-01

We study the moderate-to-high radiative luminosity active galactic nuclei (HLAGN) within the VLA-COSMOS 3 GHz Large Project. The survey covers 2.6 square degrees centered on the COSMOS field with a 1σ sensitivity of 2.3 μJy/beam across the field. This provides the simultaneously largest and deepest radio continuum survey available to date with exquisite multi-wavelength coverage. The survey yields 10,830 radio sources with signal-to-noise ratios >=5. A subsample of 1,604 HLAGN is analyzed here. These were selected via a combination of X-ray luminosity and mid-infrared colors. We derive luminosity functions for these AGN and constrain their cosmic evolution out to a redshift of z ~ 6, for the first time decomposing the star formation and AGN contributions to the radio continuum emission in the AGN. We study the evolution of number density and luminosity density finding a peak at z ~ 1.5 followed by a decrease out to a redshift z ~ 6.

Evidence From Hydrogen Isotopes in Meteorites for a Martian Permafrost

NASA Technical Reports Server (NTRS)

Usui, T.; Alexander, C. M. O'D.; Wang, J.; Simon, J. I.; Jones, J. H.

2014-01-01

Fluvial landforms on Mars suggest that it was once warm enough to maintain persistent liquid water on its surface. The transition to the present cold and dry Mars is closely linked to the history of surface water, yet the evolution of surficial water is poorly constrained. We have investigated the evolution of surface water/ ice and its interaction with the atmosphere by measurements of hydrogen isotope ratios (D/H: deuterium/ hydrogen) of martian meteorites. Hydrogen is a major component of water (H2O) and its isotopes fractionate significantly during hydrological cycling between the atmosphere, surface waters, ground ice, and polar cap ice. Based on in situ ion microprobe analyses of three geochemically different shergottites, we reported that there is a water/ice reservoir with an intermediate D/H ratio (delta D = 1,000?2500 %) on Mars. Here we present the possibility that this water/ice reservoir represents a ground-ice/permafrost that has existed relatively intact over geologic time.

Living on the Edge? Clumped Isotope and Oxygen Isotope Record of Early Cascade Topography (Eocene Chumstick Basin, WA, USA)

NASA Astrophysics Data System (ADS)

Methner, K.; Mulch, A.; Fiebig, J.; Wacker, U.; Umhoefer, P. J.; Chamberlain, C. P.

2014-12-01

The topographic evolution of the world's major orogens exerts a strong impact on atmospheric circulation and precipitation patterns and is a key element in reconstructing the interactions among tectonics, climate, and Earth surface processes. Using carbonate stable and clumped isotope data together with low-temperature thermochronology information from the terrestrial Eocene Chumstick Basin (Central Washington; USA), today located to the East of the Washington Cascades, we investigate the E-W extent of the western North American plateau region and the evolution of Cascade topography. Oxygen isotope measurements of Eocene (51 to 37 Ma) pedogenic carbonate concretions and calcic horizons yield low δ18Ocarbonate values of +9 to +13 ‰ (SMOW) despite the proximity of the Eocene Chumstick Basin to the Pacific moisture source and paleofloral data that indicate moderate elevations and montane rain forest conditions during a warm and rather wet, seasonal climate. This either suggests that 51-37 Ma ago Cascade-like topography characterized the western edge of the North American-Pacific plate margin to the West of the Chumstick Basin or that the δ18Ocarbonate data were variably reset or only formed during burial and diagenesis. Clumped isotope (Δ47) thermometry of pedogenic carbonate and carbonate concretions (n=11 samples) indicates spatially variable burial temperatures of 80 to 120 °C that correlate with vitrinite reflectance data in these sediments. In concordance with changes in depositional environment the youngest (<40 Ma) Chumstick sediments experienced a lesser degree of post-depositional burial and heating (ca. 70 - 80 °C) compared to the older Chumstick series (80 - 120 °C). Calculated δ18O values of the circulating fluids in the Chumstick basin sediments range from -6 ‰ (T ~100 °C at ca. 40-30 Ma) to -9 ‰ (T ~75 °C at ca. 25-15 Ma). These values suggest a low-altitude meteoric fluid source and as a consequence only moderate Cascade topography during

Isotopic evidence of early hominin diets

NASA Astrophysics Data System (ADS)

Sponheimer, Matt; Alemseged, Zeresenay; Cerling, Thure E.; Grine, Frederick E.; Kimbel, William H.; Leakey, Meave G.; Lee-Thorp, Julia A.; Kyalo Manthi, Fredrick; Reed, Kaye E.; Wood, Bernard A.; Wynn, Jonathan G.

2013-06-01

Carbon isotope studies of early hominins from southern Africa showed that their diets differed markedly from the diets of extant apes. Only recently, however, has a major influx of isotopic data from eastern Africa allowed for broad taxonomic, temporal, and regional comparisons among hominins. Before 4 Ma, hominins had diets that were dominated by C3 resources and were, in that sense, similar to extant chimpanzees. By about 3.5 Ma, multiple hominin taxa began incorporating 13C-enriched [C4 or crassulacean acid metabolism (CAM)] foods in their diets and had highly variable carbon isotope compositions which are atypical for African mammals. By about 2.5 Ma, Paranthropus in eastern Africa diverged toward C4/CAM specialization and occupied an isotopic niche unknown in catarrhine primates, except in the fossil relations of grass-eating geladas (Theropithecus gelada). At the same time, other taxa (e.g., Australopithecus africanus) continued to have highly mixed and varied C3/C4 diets. Overall, there is a trend toward greater consumption of 13C-enriched foods in early hominins over time, although this trend varies by region. Hominin carbon isotope ratios also increase with postcanine tooth area and mandibular cross-sectional area, which could indicate that these foods played a role in the evolution of australopith masticatory robusticity. The 13C-enriched resources that hominins ate remain unknown and must await additional integration of existing paleodietary proxy data and new research on the distribution, abundance, nutrition, and mechanical properties of C4 (and CAM) plants.

Isotopic evidence of early hominin diets

PubMed Central

Sponheimer, Matt; Alemseged, Zeresenay; Cerling, Thure E.; Grine, Frederick E.; Kimbel, William H.; Leakey, Meave G.; Lee-Thorp, Julia A.; Manthi, Fredrick Kyalo; Reed, Kaye E.; Wood, Bernard A.; Wynn, Jonathan G.

2013-01-01

Carbon isotope studies of early hominins from southern Africa showed that their diets differed markedly from the diets of extant apes. Only recently, however, has a major influx of isotopic data from eastern Africa allowed for broad taxonomic, temporal, and regional comparisons among hominins. Before 4 Ma, hominins had diets that were dominated by C3 resources and were, in that sense, similar to extant chimpanzees. By about 3.5 Ma, multiple hominin taxa began incorporating 13C-enriched [C4 or crassulacean acid metabolism (CAM)] foods in their diets and had highly variable carbon isotope compositions which are atypical for African mammals. By about 2.5 Ma, Paranthropus in eastern Africa diverged toward C4/CAM specialization and occupied an isotopic niche unknown in catarrhine primates, except in the fossil relations of grass-eating geladas (Theropithecus gelada). At the same time, other taxa (e.g., Australopithecus africanus) continued to have highly mixed and varied C3/C4 diets. Overall, there is a trend toward greater consumption of 13C-enriched foods in early hominins over time, although this trend varies by region. Hominin carbon isotope ratios also increase with postcanine tooth area and mandibular cross-sectional area, which could indicate that these foods played a role in the evolution of australopith masticatory robusticity. The 13C-enriched resources that hominins ate remain unknown and must await additional integration of existing paleodietary proxy data and new research on the distribution, abundance, nutrition, and mechanical properties of C4 (and CAM) plants.

Earth's Coming of Age: Isotopically Tracking the Global Transformation from the Hadean to the Geologically Modern Earth

NASA Astrophysics Data System (ADS)

Bennett, V. C.; Nutman, A. P.

2017-12-01

Some of the strongest direct evidence that documents fundamental changes in the chemistry and organisation of Earth's interior derives from radiogenic isotopic compositions that include both long-lived (particularly 176Lu-176Hf and 147Sm-143Nd) and short-lived, i.e., now extinct parent isotope, systems (182Hf-182W, 146Sm-142Nd). Changes in patterns of isotopic evolution are linked to changes in mantle dynamics such that tracking these signatures in geologically well-characterised rocks can be used to discover the the nature and evolution of tectonic processes. Over the past decade, intensive geochemical investigations by various groups focussing on the oldest (> 4.0 Ga to 3.6 Ga) rock record, as preserved in several localities, have revealed isotopic distinctions in the early Earth compared with those in Proterozoic and younger rocks. For example, whilst the major and trace element compositions of Eoarchean gneisses have analogs in younger rocks in accord with a continuum of crust formation processes, radiogenic isotopic signatures from both long and short half-life decay schemes record an image of the Earth in transition from early differentiation processes, likely associated with planetary accretion and formation, to more modern style characterised by plate tectonics. The emerging image is that many Eoarchean rocks possess extinct nuclide anomalies in the form of 142Nd and 182Hf isotopic signatures that are absent in modern terrestrial samples; these signatures are evidence of chemical fractionation processes occuring within the first ca. 10-300 million years of Solar System history. In addition, viewing the global database, patterns of long-half life isotope signatures i.e., 143Nd and 176Hf differ from those seen in younger (<3.6 Ga) rocks, again providing a tracer of mantle dynamics and reflecting the influence of early processes. It is becoming increasingly apparent that the well demonstrated "coupled" 176Hf-143Nd isotopic evolution generated by plate tectonic

Pb, Sr, and Nd isotopic compositions of a suite of Late Archean, igneous rocks, eastern Beartooth Mountains: implications for crust-mantle evolution

USGS Publications Warehouse

Wooden, J.L.; Mueller, P.A.

1988-01-01

A series of compositionally diverse, Late Archean rocks (2.74-2.79 Ga old) from the eastern Beartooth Mountains, Montana and Wyoming, U.S.A., have the same initial Pb, Sr, and Nd isotopic ratios. Lead and Sr initial ratios are higher and Nd initial ratios lower than would be expected for rocks derived from model mantle sources and strongly indicate the involvement of an older crustal reservoir in the genesis of these rocks. Crustal contamination during emplacement can be ruled out for a variety of reasons. Instead a model involving subduction of continental detritus and contamination of the overlying mantle as is often proposed for modern subduction environments is preferred. This contaminated mantle would have all the isotopic characteristics of mantle enriched by internal mantle metasomatism but would require no long-term growth or changes in parent to daughter element ratios. This contaminated mantle would make a good source for some of the Cenozoic mafic volcanics of the Columbia River, Snake River Plain, and Yellowstone volcanic fields that are proposed to come from ancient, enriched lithospheric mantle. The isotopic characteristics of the 2.70 Ga old Stillwater Complex are a perfect match for the proposed contaminated mantle which provides an alternative to crustal contamination during emplacement. The Pb isotopic characteristics of the Late Archean rocks of the eastern Beartooth Mountains are similar to those of other Late Archean rocks of the Wyoming Province and suggest that Early Archean, upper crustal rocks were common in this terrane. The isotopic signatures of Late Archean rocks in the Wyoming Province are distinctive from those of other Archean cratons in North America which are dominated by a MORB-like, Archean mantle source (Superior Province) and/or a long-term depleted crustal source (Greenland). ?? 1988.

Tracking Local Spatiotemporal Microfracturing Processes and Stress Field Evolution Before and After Laboratory Fault Slip

NASA Astrophysics Data System (ADS)

Kwiatek, G.; Orlecka-Sikora, B.; Goebel, T.; Martínez-Garzón, P.; Dresen, G.; Bohnhoff, M.

2017-12-01

In this study we investigate details of spatial and temporal evolution of the stress field and damage at a pre-existing fault plane in laboratory stick-slip friction experiments performed on Westerly Granite sample. Specimen of 10 cm height and 4 cm diameter was deformed at a constant strain rate of 3×10-6 s-1 and confining pressure of 150 MPa. Here we analyze a series of 6 macroscopic slip events occurring on a rough fault during the course of experiment. Each macroscopic slip was associated with an intense femtoseismic acoustic emission (AE) activity recorded using a 16-channel transient recording system. To monitor the the spatiotemporal damage evolution, and unravel the micromechanical processes governing nucleation and propagation of slip events, we analyzed AE source characteristics (magnitude, seismic moment tensors, focal mechanisms), as well as the statistical properties (b-, c-, d- value) of femtoseismicity. In addition, the calculated AE focal mechanisms were used to reveal the spatiotemporal evolution of local stress field orientations and stress shape ratio coefficients over the fault plane, as well as additional parameters quantifying proximity to failure of individual fault patches. The calculated characteristics are used to comprehensively describe the complexity of the spatial and temporal evolution of the stress over the fault plane, and properties of the corresponding seismicity before and after the macroscopic slips. The observed faulting processes and characteristics are discussed in the context of global strain and stress changes, fault maturation, and earthquake stress drop.

Assessment of diel chemical and isotopic techniques to investigate biogeochemical cycles in the upper Klamath River, Oregon, USA

USGS Publications Warehouse

Poulson, S.R.; Sullivan, A.B.

2009-01-01

The upper Klamath River experiences a cyanobacterial algal bloom and poor water quality during the summer. Diel chemical and isotopic techniques have been employed in order to investigate the rates of biogeochemical processes. Four diel measurements of field parameters (temperature, pH, dissolved oxygen concentrations, and alkalinity) and stable isotope compositions (dissolved oxygen-??18O and dissolved inorganic carbon-??13C) have been performed between June 2007 and August 2008. Significant diel variations of pH, dissolved oxygen (DO) concentration, and DO-??18O were observed, due to varying rates of primary productivity vs. respiration vs. gas exchange with air. Diel cycles are generally similar to those previously observed in river systems, although there are also differences compared to previous studies. In large part, these different diel signatures are the result of the low turbulence of the upper Klamath River. Observed changes in the diel signatures vs. sampling date reflect the evolution of the status of the algal bloom over the course of the summer. Results indicate the potential utility of applying diel chemical and stable isotope techniques to investigate the rates of biogeochemical cycles in slow-moving rivers, lakes, and reservoirs, but also illustrate the increased complexity of stable isotope dynamics in these low-turbulence systems compared to well-mixed aquatic systems. ?? 2009 Elsevier B.V.

Isotopic evolution of Mauna Loa and the chemical structure of the Hawaiian plume

NASA Astrophysics Data System (ADS)

Depaolo, Donald J.; Bryce, Julia G.; Dodson, Allen; Shuster, David L.; Kennedy, B. Mack

2001-07-01

New He isotopic data from the HSDP pilot hole core, lava accumulation rate models, and data from the literature are used to develop a 200,000 year isotopic record for the lava erupted from the Mauna Loa volcano. This record, coupled with an analogous record from Mauna Kea from the Hawaii Scientific Drilling Project (HSDP) pilot hole project and other literature data from the GEOROC database, are used to construct a "map" of lava isotopic compositions for the island of Hawaii. The isotopic map is converted to a map of the He and Nd isotopic compositions of melts from the mantle plume, which can be compared with a published melt supply map derived from geodynamic modeling. The resulting map of the plume indicates that values of helium 3He/4He > 20 Ra are confined to the core of the plume (radius ≈ 20-25 km) and correspond to potential temperatures >1565°C, suggesting the He isotopic signal is derived from deep in the mantle. The 3He/4He map has closed contours down to 10 Ra; the contours are teardrop-shaped and elongated in the general direction of plate motion. The closed contours indicate that most of the plume He signal is lost during the early stages of melting, which is consistent with helium behaving as a strongly incompatible element (KHe ≤ 0.001). The ɛNd contours (and by inference the contours for Sr, Pb, Hf, and Os) do not all close on the scale of the island of Hawaii but instead partially follow material flow lines within the plume beneath the lithosphere. The plume signal for Nd extends circa 100 km in the direction of plate motion, which is consistent with the moderately incompatible behavior of Nd (KNd ≈ 0.02). Downstream from the plume core epicenter, plume Nd occurs with asthenospheric He; this could be mistaken for an additional plume component, whereas it may be only a manifestation of differing incompatibility. Data from Mauna Loa suggest the presence of a low-3He/4He plume component that has low ɛNd and high 87Sr/86Sr. The plume map

Hydrogen Isotopes Record the History of the Martian Hydrosphere and Atmosphere

NASA Technical Reports Server (NTRS)

Usui, T.; Simon, J. I.; Jones, J. H.; Kurokawa, H.; Sato, M.; Alexander, C. M. O'D; Wang, J.

2015-01-01

The surface geology and geomorphology of Mars indicates that it was once warm enough to maintain a large body of liquid water on its surface, though such a warm environment might have been transient. The transition to the present cold and dry Mars is closely linked to the history of surface water, yet the evolution of surficial water is poorly constrained. This study presents insights from hydrogen isotopes for the origin and evolution of Martian water reservoirs.

Soil, the orphan hydrological compartment: evidence from O and H stable isotopes?

NASA Astrophysics Data System (ADS)

Hissler, Christophe; Legout, Arnaud; Barnich, François; Pfister, Laurent

2015-04-01

O and H stable isotopes have been successfully used for decades for studying the exchange of waters between the hydrosphere, the pedosphere and the biosphere. They greatly contribute to improve our understanding of soil-water-plant interactions. In particular, the recent hydrological concept of "two water worlds" (separation of meteoric water that infiltrates the soil as (i) mobile water, which can reach the groundwater and can enter the stream, and as (ii) tightly bound water, which is trapped in the soil microporosity and used by plants) calls for a substantial revision of our perceptual models of runoff generation. Nevertheless, there is a need for testing the applicability of this concept over a large range of ecosystemic contexts (i.e.soil and vegetation types). To date, many investigations have focused on the relationship between the various processes triggering isotope fractionation within soils. So far, the dominating perception is that the isotope profile of water observed in soils is solely due to evaporative fractionation and its shape is dependent on climate and soil parameters. However, as of today the influence of biogeochemical processes on the spatio-temporal variability of δ18O and δD of the soil solutions has been rarely quantified. O and H exchanges between soil water and other soil compartments (living organisms, minerals, exchange capacity, organic matter) remain poorly known and require deeper investigations. Eventually, we need to better understand the distribution of O and H isotopes throughout the soil matrix. In order to address these issues, we have designed and carried out two complementary isotope experiments that use one liter soil columns of a 2mm-sieved and air-dried soil. Our objectives were (1) to observe the temporal evolution of the water O and H isotopic composition starting from the field capacity to the complete drying of the soil and (2) to determine the impact of soil biogeochemical properties on the isotopic composition

The Evolution of a Snow Dune Field

NASA Astrophysics Data System (ADS)

Filhol, S.; Pirk, N.; Schuler, T.; Burkhart, J. F.

2017-12-01

On March 24, 2017 we observed the evolution of a snow dune field during a passing storm on the alpine plateau of Finse, Norway. With a terrestrial lidar we captured 15 high-resolution scans of the snow surface over an area of about 5000 m2 over the course of 7.5 hours from which we analyze morphological changes. An eddy covariance system located nearby at the Finse Alpine Research Station recorded wind and its turbulent structure, and measured the snow drifting flux with a FlowCapt sensor. This combined dataset provides novel insight into the responses and changes of the snow surface morphology exposed to storm constraints (e.g. wind speed, drifting flux). We found that individual dunes have moved 30 to 37 m over the course of 7.5 hours. The wavelength of the dunes varied from 10.3±3.1 m at the time of the first scan to 13.6±3.3 m at the last scan. Within this time period we observed individual dunes 1) migrating down wind, later becoming 2) temporarily nearly static as the wind speed dropped, and finally 3) migrating, growing, and merging into larger transverse dunes under strong wind conditions accompanied by large quantities of drifting snow. This dynamics can be considered analogous to sand dune behavior, however, on much shorter time scale (1h vs 10-100 years) and smaller spatial scale (10m vs 100m). The record of this event helps us to understand the morphological evolution of a snow surface during a blowing snow storm, and further illustrates the fate of self-sustained bedforms such as dunes in varying conditions. Such detailed description of erosion/deposition processes of the snow surface are crucial for improvements of land surface models, commonly applied to hydrological and ecological purposes.

Isotopic and chemical evidence concerning the genesis and contamination of basaltic and rhyolitic magma beneath the Yellowstone Plateau Volcanic Field

USGS Publications Warehouse

Hildreth, W.; Halliday, A.N.; Christiansen, R.L.

1991-01-01

Since 2.2 Ma, the Yellowstone Plateau Volcanic Field has produced ~6000 km3 of rhyolite tuffs and lavas in >60 separate eruptions, as well as ~100 km3 of tholeiitic basalt from >50 vents peripheral to the silicic focus. Intermediate eruptive products are absent. Early postcollapse rhyolites show large shifts in Nd, Sr, Pb, and O isotopic composition caused by assimilation of roof rocks and hydrothermal brines during collapse and resurgence. Younger intracaldera rhyolite lavas record partial isotopic recovery toward precaldera ratios. Thirteen extracaldera rhyolites show none of these effects and have sources independent of the subcaldera magma system. Contributions from the Archaean crust have extreme values and wide ranges of Nd-, Sr, and Pb-isotope ratios, but Yellowstone rhyolites have moderate values and limited ranges. This requires their deep-crustal sources to have been pervasively hybridized by distributed intrusion of Cenozoic basalt, most of which was probably contemporaneous with the Pliocene and Quaternary volcanism. Most Yellowstone basalts had undergone cryptic clinopyroxene fractionation in the lower crust or crust-mantle transition zone and, having also ascended through or adjacent to crustal zones of silicic-magma generation, most underwent some crustal contamination. -from Authors

Additional Sr Isotopic Heterogeneity in Zagami Olivine-Rich Lithology

NASA Technical Reports Server (NTRS)

Misawa, K.; Niihara, T.; Shih, C.-Y; Reese, Y. D.; Nyquist, L. E.; Yoneda, S.; Yamashita, H.

2012-01-01

Prior isotopic analyses of Zagami have established differing initial Sr-87/Sr-86 (ISr) ratios of among Zagami lithologies, fine-grained (FG), coarse-grained (CG), and dark mottled lithologies (DML)]. The Zagami sample (KPM-NLH000057) newly allocated from the Kanagawa Prefectural Museum of Natural History contained DML and the Ol-rich lithology which included more ferroan olivines (Ol-rich: Fa(sub 97- 99) vs late-stage melt pockets: Fa(sub 90-97)]). We have combined mineralogy-petrology and Rb-Sr isotopic studies on the Kanagawa Zagami sample, which will provide additional clues to the genesis of enriched shergottites and to the evolution of Martian crust and mantle

Origin of the Sudbury Complex by meteoritic impact: Neodymium isotopic evidence

USGS Publications Warehouse

Faggart, B.E.; Basu, A.R.; Tatsumoto, M.

1985-01-01

Samarium-neodymium isotopic data on whole rocks and minerals of the Sudbury Complex in Canada gave an igneous crystallization age of 1840 ?? 21 ?? 106 years. The initial epsilon neodymium values for 15 whole rocks are similar to those for average upper continental crust, falling on the crustal trend of neodymium isotopic evolution as defined by shales. The rare earth element concentration patterns of Sudbury rocks are also similar to upper crustal averages. These data suggest that the Sudbury Complex formed from melts generated in the upper crust and are consistent with a meteoritic impact.

Electric field driven evolution of topological domain structure in hexagonal manganites

NASA Astrophysics Data System (ADS)

Yang, K. L.; Zhang, Y.; Zheng, S. H.; Lin, L.; Yan, Z. B.; Liu, J.-M.; Cheong, S.-W.

2017-10-01

Controlling and manipulating the topological state represents an important topic in condensed matters for both fundamental researches and applications. In this work, we focus on the evolution of a real-space topological domain structure in hexagonal manganites driven by electric field, using the analytical and numerical calculations based on the Ginzburg-Landau theory. It is revealed that the electric field drives a transition of the topological domain structure from the type-I pattern to the type-II one. In particular, it is identified that a high electric field can enforce the two antiphase-plus-ferroelectric (AP +FE ) domain walls with Δ Φ =π /3 to approach each other and to merge into one domain wall with Δ Φ = 2 π /3 eventually if the electric field is sufficiently high, where Δ Φ is the difference in the trimerization phase between two neighboring domains. Our simulations also reveal that the vortex cores of the topological structure can be disabled at a sufficiently high critical electric field by suppressing the structural trimerization therein, beyond which the vortex core region is replaced by a single ferroelectric domain without structural trimerization (Q = 0 ). Our results provide a stimulating reference for understanding the manipulation of real-space topological domain structure in hexagonal manganites.

Nonlinear evolution of the coronal magnetic field under reconnective relaxation

NASA Technical Reports Server (NTRS)

Wolfson, R.; Vekstein, G. E.; Priest, E. R.

1994-01-01

Recently, Vekstein et al. (Vekstein, Priest, & Steele 1993) have developed a model for coronal heating in which the corona responds to photospheric footpoint motions by small-scale reconnection events that bring about a relaxed state while conserving magnetic helicity but not field-line connectivity. Vekstein et al. consider a partially open field configuration in which magnetic helicity is ejected to infinity on open field lines but retained in the closed-field region. Under this scheme, they describe the evolution of an initially potential field, in response to helicity injection, in the linear regime. The present work uses numerical calculations to extend the model of Vekstein et al. into the fully nonlinear regime. The results show a rise and bulging of the field lines of the closed-field region with increasing magnetic helicity, to a point where further solutions are impossible. We interpret these solution-sequence endpoints as indicating a possible loss of equilibrium, in the sense that a relaxed equilibrium state may no longer be available to the corona when sufficient helicity has been injected. The rise and bulging behavior is reminiscent of what is observed in a helmet streamer just before the start of a coronal mass ejection (CME), and so our model suggests that a catastrophic loss of magnetic equilibrium might be the initiation mechanism for CMEs. We also find that some choices of boundary conditions can result in qualitative changes in the magnetic topology, with the appearance of magnetic islands. Whether or not this behavior occurs depends on the relative strengths of the fields in the closed- and open-field regions; in particular, island formation is most likely when the open field (which is potential) is strong and thus acts to confine the force-free closed field. Finally, we show that the energy released through reconnective relaxation can be a substantial fraction of the magnetic energy injected into the corona through footpoint motions and may

THE NITROGEN ISOTOPIC COMPOSITION OF METEORITIC HCN

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pizzarello, Sandra, E-mail: pizzar@asu.edu

2014-12-01

HCN is ubiquitous in extraterrestrial environments and is central to current theories on the origin of early solar system organic compounds such as amino acids. These compounds, observed in carbonaceous meteorites, were likely important in the origin and/or evolution of early life. As part of our attempts to understand the origin(s) of meteoritic CN{sup –}, we have analyzed the {sup 15}N/{sup 14}N isotopic composition of HCN gas released from water extracts of the Murchison meteorite and found its value to be near those of the terrestrial atmosphere. The findings, when evaluated viz-a-viz molecular abundances and isotopic data of meteoritic organicmore » compounds, suggest that HCN formation could have occurred during the protracted water alteration processes known to have affected the mineralogy of many asteroidal bodies during their solar residence. This was an active synthetic stage, which likely involved simple gasses, organic molecules, their presolar precursors, as well as mineral catalysts and would have lead to the formation of molecules of differing isotopic composition, including some with solar values.« less

Interacting tachyon: Cosmological evolution for a tachyon and a scalar field

DOE Office of Scientific and Technical Information (OSTI.GOV)

Macorra, A. de la; Filobello, U.

2008-01-15

We study the cosmological evolution of a tachyon scalar field T with a Dirac-Born-Infeld type Lagrangian and potential V(T) coupled to a canonically normalized scalar field {phi} with an interaction term B(T,{phi}) in the presence of a barotropic fluid {rho}{sub b}, which can be matter or radiation. The force between the barotropic fluid and the scalar fields is only gravitational. We show that the dynamics is completely determined by only three parameters {lambda}{sub 1}=-V{sub T}/V{sup 3/2}, {lambda}{sub 2}=-B{sub T}/B{sup 3/2}, and {lambda}{sub 3}=-B{sub {phi}}/B. We determine analytically the conditions for {lambda}{sub i} under which the energy density of T, {phi},more » and {rho}{sub b} have the same redshift. We study the behavior of T and {phi} in the asymptotic limits for {lambda} and we show the numerical solution for different interesting cases. The effective equation of state for the tachyon field changes due to the interaction with the scalar field and we show that it is possible for a tachyon field to redshift as matter in the absence of an interaction term B and as radiation when B is turned on. This result solves then the tachyonic matter problem.« less

Late Proterozoic rise in atmospheric oxygen concentration inferred from phylogenetic and sulphur-isotope studies

NASA Technical Reports Server (NTRS)

Canfield, D. E.; Teske, A.

1996-01-01

The evolution of non-photosynthetic sulphide-oxidizing bacteria was contemporaneous with a large shift in the isotopic composition of biogenic sedimentary sulphides between 0.64 and 1.05 billion years ago. Both events were probably driven by a rise in atmospheric oxygen concentrations to greater than 5-18% of present levels--a change that may also have triggered the evolution of animals.

CNO isotopes in red giant stars

NASA Technical Reports Server (NTRS)

Wannier, P. G.

1985-01-01

The production and distribution of the CNO nuclides is discussed in light of observed abundance ratios in red giants and in the interstellar medium. Isotope abundances have been measured in the atmospheres and in the recent ejecta of cool giants, including carbon stars, S-type stars and red supergiants as well as in oxygen-rich giants making their first ascent of the giant branch. Several of the observations suggest revision of currently accepted nuclear cross-sections and of the mixing processes operating in giant envelopes. By comparing red giant abundances with high-quality observations of the interstellar medium, conclusions are reached about the contribution of intermediate-mass stars to galactic nuclear evolution. The three oxygen isotopes, O-16, -17 and -18, are particularly valuable for such comparison because they reflect three different stages of stellar nucleosynthesis. One remarkable result comes from observations of O-17/O-18 in several classes of red giant stars. The observed range of values for red giants excludes the entire range of values seen in interstellar molecular clouds. Furthermore, both the observations of stars and interstellar clouds exclude the isotopic ratio found in the solar system.

The Nd-, Sr- and Pb-isotopic character of lavas from Taal, Laguna de Bay and Arayat volcanoes, southwestern Luzon, Philippines: Implications for arc magma petrogenesis

USGS Publications Warehouse

Mukasa, S.B.; Flower, M.F.J.; Miklius, Asta

1994-01-01

Following the amalgamation of a collage of pre-Neogene terranes largely by strike-slip and convergence mechanisms to form the Philippine islands, volcanic chains, related to oppositely dipping subduction zones, developed along the eastern and western margins of the archipelago. There is ample field evidence that this volcanic activity, predominantly calc-alkaline in chemical character, had commenced by the Oligocene. Volcanoes resulting from subduction along the Manila-Negros trench in the west (e.g. Taal, Laguna de Bay and Arayat) form a high-angle linear array, trending away from the MORE field on Pb-isotopic covariation diagrams; have the highest Sr- and lowest Nd-isotopic compositions, of the two chains (but nevertheless plotting above bulk earth on the 87Sr/86Sr versus 143Nd/144Nd covariation diagram); and exhibit Sm/Nd and Rb/Sr values that are lower and higher, respectively, than the estimated values for bulk earth. While the Sm/Nd and Rb/Sr characteristics are common to both chains, volcanoes associated with the Philippine-East Luzon trench have Pb-isotopic compositions that fall in the Indian Ocean MORB field and that require time-integrated evolution in a high Th/U environment. They also have higher Nd- and lower Sr-isotopic ratios. The source materials of Philippine volcanoes, therefore, have undergone varied recent enrichments in LILE, as indicated by the decoupling of isotopic and elemental ratios. These enrichments, particularly for the western volcanoes, cannot be entirely due to small degrees of partial melting in the mantle wedge, considering that they were accompanied by elevations in radiogenic Pb. Elevated Pb ratios are best explained by the introduction of subducted, continentally derived sediments. The sedimentary component in the western volcanoes is probably the South China Sea sediments derived largely from Eurasia. That this component is not available in the Philippine-East Luzon trench is reflected by the fact that the eastern volcanoes

Minimalist coupled evolution model for stellar X-ray activity, rotation, mass loss, and magnetic field

NASA Astrophysics Data System (ADS)

Blackman, Eric G.; Owen, James E.

2016-05-01

Late-type main-sequence stars exhibit an X-ray to bolometric flux ratio that depends on {tilde{R}o}, the ratio of rotation period to convective turnover time, as {tilde{R}o}^{-ζ } with 2 ≤ ζ ≤ 3 for {tilde{R}o} > 0.13, but saturates with |ζ| < 0.2 for {tilde{R}o} < 0.13. Saturated stars are younger than unsaturated stars and show a broader spread of rotation rates and X-ray activity. The unsaturated stars have magnetic fields and rotation speeds that scale roughly with the square root of their age, though possibly flattening for stars older than the Sun. The connection between faster rotators, stronger fields, and higher activity has been established observationally, but a theory for the unified time-evolution of X-ray luminosity, rotation, magnetic field and mass loss that captures the above trends has been lacking. Here we derive a minimalist holistic framework for the time evolution of these quantities built from combining a Parker wind with new ingredients: (1) explicit sourcing of both the thermal energy launching the wind and the X-ray luminosity via dynamo produced magnetic fields; (2) explicit coupling of X-ray activity and mass-loss saturation to dynamo saturation (via magnetic helicity build-up and convection eddy shredding); (3) use of coronal equilibrium to determine how magnetic energy is divided into wind and X-ray contributions. For solar-type stars younger than the Sun, we infer conduction to be a subdominant power loss compared to X-rays and wind. For older stars, conduction is more important, possibly quenching the wind and reducing angular momentum loss. We focus on the time evolution for stars younger than the Sun, highlighting what is possible for further generalizations. Overall, the approach shows promise towards a unified explanation of all of the aforementioned observational trends.

Nuclear field shift in natural environments

NASA Astrophysics Data System (ADS)

Moynier, Frédéric; Fujii, Toshiyuki; Brennecka, Gregory A.; Nielsen, Sune G.

2013-03-01

The nuclear field shift (NFS) is an isotope shift in atomic energy levels caused by a combination of differences in nuclear size and shape and electron densities at the nucleus. The effect of NFS in isotope fractionation was theoretically established by Bigeleisen in 1996 [Bigeleisen J. (1996) J. Am. Chem. Soc. 118:3676-3680] and has been analytically measured in laboratory chemical exchange reactions. More recently, some isotopic variations of heavy elements (Hg, Tl, U) measured in natural systems as well as isotopic anomalies measured for lower-mass elements in meteorites have been attributed to the NFS effect. These isotopic variations open up new and exciting fields of investigations in Earth sciences. In this paper, we review the different natural systems in which NFS has been proposed to be the origin of isotopic variations.

Landscape evolution of Antarctica

USGS Publications Warehouse

Jamieson, S.S.R.; Sugden, D.E.

2007-01-01

shelf before retreating to its present dimensions at ~13.5 Ma. Subsequent changes in ice extent have been forced mainly by sea-level change. Weathering rates of exposed bedrock have been remarkably slow at high elevations around the margin of East Antarctica under the hyperarid polar climate of the last ~13.5 Ma, offering potential for a long quantitative record of ice-sheet evolution with techniques such as cosmogenic isotope analysis

Evolution of ectomycorrhizas as a driver of diversification and biogeographic patterns in the model mycorrhizal mushroom genus Laccaria.

PubMed

Wilson, Andrew W; Hosaka, Kentaro; Mueller, Gregory M

2017-03-01

A systematic and evolutionary ecology study of the model ectomycorrhizal (ECM) genus Laccaria was performed using herbarium material and field collections from over 30 countries covering its known geographic range. A four-gene (nrITS, 28S, RPB2, EF1α) nucleotide sequence dataset consisting of 232 Laccaria specimens was analyzed phylogenetically. The resulting Global Laccaria dataset was used for molecular dating and estimating diversification rates in the genus. Stable isotope analysis of carbon and nitrogen was used to evaluate the origin of Laccaria's ECM ecology. In all, 116 Laccaria molecular species were identified, resulting in a near 50% increase in its known diversity, including the new species described herein: Laccaria ambigua. Molecular dating indicates that the most recent common ancestor to Laccaria existed in the early Paleocene (56-66 million yr ago), probably in Australasia. At this time, Laccaria split into two lineages: one represented by the new species L. ambigua, and the other reflecting a large shift in diversification that resulted in the remainder of Laccaria. L. ambigua shows a different isotopic profile than all other Laccaria species. Isotopes and diversification results suggest that the evolution of the ECM ecology was a key innovation in the evolution of Laccaria. Diversification shifts associated with Laccaria's dispersal to the northern hemisphere are attributed to adaptations to new ecological niches. © 2016 The Authors. New Phytologist © 2016 New Phytologist Trust.

A field experiment demonstrating plant life-history evolution and its eco-evolutionary feedback to seed predator populations.

PubMed

Agrawal, Anurag A; Johnson, Marc T J; Hastings, Amy P; Maron, John L

2013-05-01

The extent to which evolutionary change occurs in a predictable manner under field conditions and how evolutionary changes feed back to influence ecological dynamics are fundamental, yet unresolved, questions. To address these issues, we established eight replicate populations of native common evening primrose (Oenothera biennis). Each population was planted with 18 genotypes in identical frequency. By tracking genotype frequencies with microsatellite DNA markers over the subsequent three years (up to three generations, ≈5,000 genotyped plants), we show rapid and consistent evolution of two heritable plant life-history traits (shorter life span and later flowering time). This rapid evolution was only partially the result of differential seed production; genotypic variation in seed germination also contributed to the observed evolutionary response. Since evening primrose genotypes exhibited heritable variation for resistance to insect herbivores, which was related to flowering time, we predicted that evolutionary changes in genotype frequencies would feed back to influence populations of a seed predator moth that specializes on O. biennis. By the conclusion of the experiment, variation in the genotypic composition among our eight replicate field populations was highly predictive of moth abundance. These results demonstrate how rapid evolution in field populations of a native plant can influence ecological interactions.

Laser-Assisted Field Evaporation and Three-Dimensional Atom-by-Atom Mapping of Diamond Isotopic Homojunctions.

PubMed

Mukherjee, Samik; Watanabe, Hideyuki; Isheim, Dieter; Seidman, David N; Moutanabbir, Oussama

2016-02-10

It addition to its high evaporation field, diamond is also known for its limited photoabsorption, strong covalent bonding, and wide bandgap. These characteristics have been thought for long to also complicate the field evaporation of diamond and make its control hardly achievable on the atomistic-level. Herein, we demonstrate that the unique behavior of nanoscale diamond and its interaction with pulsed laser lead to a controlled field evaporation thus enabling three-dimensional atom-by-atom mapping of diamond (12)C/(13)C homojunctions. We also show that one key element in this process is to operate the pulsed laser at high energy without letting the dc bias increase out of bounds for diamond nanotip to withstand. Herein, the role of the dc bias in evaporation of diamond is essentially to generate free charge carriers within the nanotip via impact ionization. The mobile free charges screen the internal electric field, eventually creating a hole rich surface where the pulsed laser is effectively absorbed leading to an increase in the nanotip surface temperature. The effect of this temperature on the uncertainty in the time-of-flight of an ion, the diffusion of atoms on the surface of the nanotip, is also discussed. In addition to paving the way toward a precise manipulation of isotopes in diamond-based nanoscale and quantum structures, this result also elucidates some of the basic properties of dielectric nanostructures under high electric field.

Isotope shifts from collinear laser spectroscopy of doubly charged yttrium isotopes

NASA Astrophysics Data System (ADS)

Vormawah, L. J.; Vilén, M.; Beerwerth, R.; Campbell, P.; Cheal, B.; Dicker, A.; Eronen, T.; Fritzsche, S.; Geldhof, S.; Jokinen, A.; Kelly, S.; Moore, I. D.; Reponen, M.; Rinta-Antila, S.; Stock, S. O.; Voss, A.

2018-04-01

Collinear laser spectroscopy has been performed on doubly charged ions of radioactive yttrium in order to study the isotope shifts of the 294.6-nm 5 s 1/2 2S →5 p 1/2 2P line. The potential of such an alkali-metal-like transition to improve the reliability of atomic-field-shift and mass-shift factor calculations, and hence the extraction of nuclear mean-square radii, is discussed. Production of yttrium ion beams for such studies is available at the IGISOL IV Accelerator Laboratory, Jyväskylä, Finland. This newly recommissioned facility is described here in relation to the on-line study of accelerator-produced short-lived isotopes using collinear laser spectroscopy and application of the technique to doubly charged ions.

The Evolution of Oblique Impact Flow Fields Using Maxwell's Z Model

NASA Technical Reports Server (NTRS)

Anderson, J. L. B.; Schultz, P. H.; Heineck, J. T.

2003-01-01

Oblique impacts are the norm rather than the exception for impact craters on planetary surfaces. This work focuses on the excavation of experimental oblique impact craters using the NASA Ames Vertical Gun Range (AVGR). Three-dimensional particle image velocimetry (3D PIV) is used to obtain quantitative data on ejection positions, three-dimensional velocities and angles. These data are then used to test the applicability and limitations of Maxwell's Z Model in representing the subsurface evolution of the excavation-stage flow-field center during vertical and oblique impacts.

The genetic link between the Azores Archipelago and the Southern Azores Seamount Chain (SASC): The elemental, isotopic and chronological evidences

NASA Astrophysics Data System (ADS)

Ribeiro, Luisa Pinto; Martins, Sofia; Hildenbrand, Anthony; Madureira, Pedro; Mata, João

2017-12-01

New geochemical, isotopic (Sr-Nd-Hf-Pb) and K-Ar data, are presented here on samples from the Southern Azores Seamount Chain (SASC) located south of the Azores Plateau. The SASC also includes the Great Meteor, Small Meteor and Closs seamounts, morphologically connected by a saddle at - 4100 m deep. We conclude that the SASC are characterized by a narrow isotopic variability that falls within the Azores isotopic field. Although each seamount has its own isotopic signature, their mantle source must comprise four local mantle end-members, three of which are common to the Azores, e.g. Plato isotopic signature results from the mixing between HIMU and N-MORB while Great Meteor signature results from this mix with the Azores Common Component (AzCC). A fourth end-member with high 208Pb/204Pb and decoupled Th/U ratios (Δ8/4 up to 59.2) is identified on Great Meteor northern flank. New K-Ar ages on Plato (33.4 ± 0.5 Ma) and Small Hyeres (31.6 ± 0.4 Ma) show nearly coeval volcanism, which is contemporaneous with the E-MORBs erupted at the MAR, drilled on oceanic crust with 30-34 Ma (DSDP82). This study endorses the genetic link between the Azores Archipelago and the SASC to the long-term activity of the Azores plume and the large-scale ridge-hotspot interaction, contributing to better constrain the temporal-spatial evolution of this region of the North Atlantic.

The isotopic and chemical evolution of planets: Mars as a missing link

NASA Technical Reports Server (NTRS)

Depaolo, D. J.

1988-01-01

The study of planetary bodies has advanced to a stage where it is possible to contemplate general models for the chemical and physical evolution of planetary interiors, which might be referred to as UMPES (Unified Models of Planetary Evolution and Structure). UMPES would be able to predict the internal evolution and structure of a planet given certain input parameters such as mass, distance from the sun, and a time scale for accretion. Such models are highly dependent on natural observations because the basic material properties of planetary interiors, and the processes that take place during the evolution of planets are imperfectly understood. The idea of UMPES was particularly unrealistic when the only information available was from the earth. However, advances have been made in the understanding of the general aspects of planetary evolution now that there is geochemical and petrological data available for the moon and for meteorites.

Evolution of Sulfur Isotopes and Oceanic Oxygenation Recorded in a Neoproterozoic Cap Carbonate From the Chaidam Block, China

NASA Astrophysics Data System (ADS)

Shen, B.; Xiao, S.; Kaufman, A.; Zhou, C.

2006-12-01

Neoproterozoic successions in the Chaidam Block, northwestern China, include the Hongtiegou Formation, which consists of a 20-meter thick, reddish diamictite with widespread dropstones and outsized clasts. The age of the Hongtiegou diamictite is unknown, but recent biostratigraphic correlations support a Neoproterozoic assignment. The glacial deposit is immediately overlain by a 5-meter thick carbonate of the basal Zhoujieshan Formation, which we interpret as a classic post-glacial cap carbonate. However, carbon isotope compositions of samples from this unit are near zero or slightly positive (up to ~ 2‰), which contrasts with the strongly negative (ca. -5‰) values recorded in the basal portions of most other post-glacial Neoproterozoic caps. Trace sulfate concentrations in samples of the carbonate are notably high, with an average of 366 ± 266 ppm. In the lower 2.5 meters of the Zhoujieshan cap (stage I) sulfur isotope compositions of both carbonate associated sulfate (CAS) and sulfides isolated from the same sample are indistinguishable from each other, and rise in concert by over 10% to values around +22‰. Above this level (stage II), 34S abundances of sulfides continue to increase to a peak of +27‰, but CAS values fall back to ~15‰. As a result isotopic differences between sulfides and sulfates are near zero in stage I and around 10% in stage II. The evolution of both systems in the lower half of the deposit suggests that seawater sulfate must have evolved to progressively heavier 34S compositions, and that sulfate in pore waters ¨C where sulfate reducing bacteria were active ¨C was quantitatively reduced to pyrite. This might result from the progressive distillation of sulfate from seawater by an enhanced rain of carbonate, in addition to bacterial reduction of sulfate, in the glacial aftermath. The anomalous isotope systematics of stage II are difficult to model, but might signal a new source and higher abundances of oceanic sulfate, based on

Workshop on Molecular Evolution

NASA Technical Reports Server (NTRS)

Cummings, Michael P.

2004-01-01

Molecular evolution has become the nexus of many areas of biological research. It both brings together and enriches such areas as biochemistry, molecular biology, microbiology, population genetics, systematics, developmental biology, genomics, bioinformatics, in vitro evolution, and molecular ecology. The Workshop provides an important contribution to these fields in that it promotes interdisciplinary research and interaction, and thus provides a glue that sticks together disparate fields. Due to the wide range of fields addressed by the study of molecular evolution, it is difficult to offer a comprehensive course in a university setting. It is rare for a single institution to maintain expertise in all necessary areas. In contrast, the Workshop is uniquely able to provide necessary breadth and depth by utilizing a large number of faculty with appropriate expertise. Furthermore, the flexible nature of the Workshop allows for rapid adaptation to changes in the dynamic field of molecular evolution. For example, the 2003 Workshop included recently emergent research areas of molecular evolution of development and genomics.

The temporal evolution of magnesium isotope fractionation during hydromagnesite dissolution, precipitation, and at equilibrium

NASA Astrophysics Data System (ADS)

Oelkers, Eric H.; Berninger, Ulf-Niklas; Pérez-Fernàndez, Andrea; Chmeleff, Jérôme; Mavromatis, Vasileios

2018-04-01

This study provides experimental evidence of the resetting of the magnesium (Mg) isotope signatures of hydromagnesite in the presence of an aqueous fluid during its congruent dissolution, precipitation, and at equilibrium at ambient temperatures over month-long timescales. All experiments were performed in batch reactors in aqueous sodium carbonate buffer solutions having a pH from 7.8 to 9.2. The fluid phase in all experiments attained bulk chemical equilibrium within analytical uncertainty with hydromagnesite within several days, but the experiments were allowed to continue for up to 575 days. During congruent hydromagnesite dissolution, the fluid first became enriched in isotopically light Mg compared to the dissolving hydromagnesite, but this Mg isotope composition became heavier after the fluid attained chemical equilibrium with the mineral. The δ26Mg composition of the fluid was up to ∼0.35‰ heavier than the initial dissolving hydromagnesite at the end of the dissolution experiments. Hydromagnesite precipitation was provoked during one experiment by increasing the reaction temperature from 4 to 50 °C. The δ26Mg composition of the fluid increased as hydromagnesite precipitated and continued to increase after the fluid attained bulk equilibrium with this phase. These observations are consistent with the hypothesis that mineral-fluid equilibrium is dynamic (i.e. dissolution and precipitation occur at equal, non-zero rates at equilibrium). Moreover the results presented in this study confirm (1) that the transfer of material from the solid to the fluid phase may not be conservative during stoichiometric dissolution, and (2) that the isotopic compositions of carbonate minerals can evolve even when the mineral is in bulk chemical equilibrium with its coexisting fluid. This latter observation suggests that the preservation of isotopic signatures of carbonate minerals in the geological record may require a combination of the isolation of fluid-mineral system

Insights into Paleogene biogeochemistry from coupled carbon and sulfur isotopes in foraminiferal calcite.

NASA Astrophysics Data System (ADS)

Rennie, V.; Paris, G.; Abramovitch, S.; Sessions, A. L.; Adkins, J. F.; Turchyn, A. V.

2014-12-01

The Paleogene witnessed large-scale environmental changes, including the beginning of long-term Cenozoic cooling. The carbon isotope composition of foraminiferal calcite suggests a major reorganization of the carbon cycle over the Paleogene, with enhanced organic carbon burial in the Paleocene, and subsequent oxidation of this organic carbon or increased volcanism throughout the Eocene. The sulfur cycle is linked to the carbon cycle via the breakdown of organic carbon during bacterial sulfate reduction. Over geological time, carbon and sulfur isotopic shifts are often coupled due to enhanced pyrite burial being coupled to enhanced organic carbon burial, and enhanced pyrite weathering being coupled to enhanced organic carbon weathering. However, over the Paleogene, carbon and sulfur isotopes are fully decoupled, with the sulfur isotope record showing only one major shift in the early Eocene, after most of the carbon isotope variability is complete. One complication of interpreting the evolution of the sulfur cycle over the Cenozoic, is the fact that the mineral proxies used (typically barite) may not be temporally coincident with those used to reconstruct the carbon cycle (typically carbonate). Furthermore, these minerals are preserved in different locations, and therefore often must be extracted from different sediment cores in different ocean basins, leading to age-model uncertainty when the records are merged. To properly ascertain the phasing between early Cenozoic changes in the carbon cycle and the sulfur cycle, we would ideally measure all isotope records on the same mineral. A new sulfur isotope analytical technique [1] has been optimised for foraminiferal calcite as a proxy for seawater δ34SSO4. The δ34SSO4 in foraminiferal calcite can then be tied to records of carbon isotopes from stratigraphically identical samples, resolving previous age model uncertainties. We present coupled carbon and sulfur isotope records from the same core over the early

The carbon isotope biogeochemistry of methane production in anoxic sediments. 1: Field observations

NASA Technical Reports Server (NTRS)

Blair, Neal E.; Boehme, Susan E.; Carter, W. Dale, Jr.

1993-01-01

The natural abundance C-13/C-12 ratio of methane from anoxic marine and freshwater sediments in temperate climates varies seasonally. Carbon isotopic measurements of the methanogenic precursors, acetate and dissolved inorganic carbon, from the marine sediments of Cape Lookout Bight, North Carolina were used to determine the sources of the seasonal variations at that site. Movement of the methanogenic zone over an isotopic gradient within the dissolved CO2 pool appears to be the dominant control of the methane C-13/C-12 ratio from February to June. The onset of acetoclastic methane-production is a second important controlling process during mid-summer. An apparent temperature dependence on the fractionation factor for CO2-reduction may have a significant influence on the isotopic composition of methane throughout the year.

Investigating yellow dung fly body size evolution in the field: Response to climate change?

PubMed

Blanckenhorn, Wolf U

2015-08-01

Uncovering genetic responses to selection in wild populations typically requires tracking individuals over generations and use of animal models. Our group monitored the body size of one Swiss Yellow Dung Fly (Scathophaga stercoraria; Diptera: Scathophagidae) field population over 15 years, including intermittent common-garden rearing in the laboratory to assess body size with minimized environmental and maximized genetic variation. Contrary to expectations based on repeated heritability and phenotypic selection assessments over the years (reported elsewhere), field body sizes declined by >10% and common-garden laboratory sizes by >5% from 1993 to 2009. Our results confirm the temperature-size rule (smaller when warmer) and, albeit entirely correlational, could be mediated by climate change, as over this period mean temperature at the site increased by 0.5°C, although alternative systematic environmental changes cannot be entirely excluded. Monitoring genetic responses to selection in wild invertebrate populations is thus possible, though indirect, and wild populations may evolve in directions not consistent with strongly positive directional selection favoring large body size. © 2015 The Author(s). Evolution © 2015 The Society for the Study of Evolution.

Groundwater processes and landscape evolution in Saharan Africa: Remote sensing, isotopic and geophysical constraints

NASA Astrophysics Data System (ADS)

Farag, A. Z.; Sultan, M.; El Kadiri, R.; Mohamed, L.

2013-12-01

Paleoclimatic regimes of the North African Sahara Desert alternated between dry and wet periods throughout the Pleistocene Epoch and it is during these wet periods that the fossil aquifers in North Africa were recharged. The largest of these aquifer systems is the Nubian Sandstone Aquifer System (NSAS; area: 2.2 million km2) in Egypt, Libya, Sudan and Chad and the North Western Sahara Aquifer (NWSA; area: 1 million km2) in Algeria, Tunisia and Libya. These aquifers have similar stratigraphic and hydrogeologic settings: (1) the main aquifer is composed largely of older clastic sediments (NAS: Nubian Sandstone; CI: Continental Intercalaire Aquifer) that is overlain by non-clastic carbonates with intercalations of clays and marls ( PNAS: Post Nubian Aquifer System, CT: Complexe Terminal) (2) unconfined conditions in the south that give way to confined conditions in the north, and (3) during wet periods, the NAS and the CI were recharged, groundwater levels rose, and groundwater flowed from the south to the north. In this study we present evidences (remote sensing, field, geophysical, isotopic) to support the hypothesis that in wet periods: (1) groundwater under high hydrostatic pressures access deep seated deep structures and discharge at the near surface causing sapping features and in the overlying carbonate sequences causing karstic features, and (2) many of the present topographic features including natural depressions across the NSAS and the NWSA were largely controlled by the groundwater system processes in previous wet climatic features. Evidences include: (1) Stubby-looking channels with U- shaped valley floors and theater-like valley heads indicative of sapping processes were mapped (using high spatial resolution IKONOS images, ASTER Digital Elevation Model (DEM), slope, hill shade and Landsat mosaics) along scarps in Egypt and Libya (scarp length: 2190 km) and in Algeria (scarp length: 400 km), (2) many of the mapped channel networks (length up to 50 km

Efficient mixing of the solar nebula from uniform Mo isotopic composition of meteorites.

PubMed

Becker, Harry; Walker, Richard J

2003-09-11

The abundances of elements and their isotopes in our Galaxy show wide variations, reflecting different nucleosynthetic processes in stars and the effects of Galactic evolution. These variations contrast with the uniformity of stable isotope abundances for many elements in the Solar System, which implies that processes efficiently homogenized dust and gas from different stellar sources within the young solar nebula. However, isotopic heterogeneity has been recognized on the subcentimetre scale in primitive meteorites, indicating that these preserve a compositional memory of their stellar sources. Small differences in the abundance of stable molybdenum isotopes in bulk rocks of some primitive and differentiated meteorites, relative to terrestrial Mo, suggest large-scale Mo isotopic heterogeneity between some inner Solar System bodies, which implies physical conditions that did not permit efficient mixing of gas and dust. Here we report Mo isotopic data for bulk samples of primitive and differentiated meteorites that show no resolvable deviations from terrestrial Mo. This suggests efficient mixing of gas and dust in the solar nebula at least to 3 au from the Sun, possibly induced by magnetohydrodynamic instabilities. These mixing processes must have occurred before isotopic fractionation of gas-phase elements and volatility-controlled chemical fractionations were established.

Ba isotopic compositions in stardust SiC grains from the Murchison meteorite: Insights into the stellar origins of large SiC grains

NASA Astrophysics Data System (ADS)

Ávila, Janaína N.; Ireland, Trevor R.; Gyngard, Frank; Zinner, Ernst; Mallmann, Guilherme; Lugaro, Maria; Holden, Peter; Amari, Sachiko

2013-11-01

We report barium isotopic measurements in 12 large (7-58 μm) stardust silicon carbide grains recovered from the Murchison carbonaceous chondrite. The C-, N-, and Si-isotopic compositions indicate that all 12 grains belong to the mainstream population and, as such, are interpreted to have condensed in the outflows of low-mass carbon-rich asymptotic giant branch (AGB) stars with close-to-solar metallicity. Barium isotopic analyses were carried out on the Sensitive High Resolution Ion Microprobe - Reverse Geometry (SHRIMP-RG) with combined high mass resolution and energy filtering to eliminate isobaric interferences from molecular ions. Contrary to previous measurements in small (<5 μm) mainstream grains, the analyzed large SiC grains do not show the classical s-process enrichment, having near solar Ba isotopic compositions. While contamination with solar material is a common explanation for the lack of large isotopic anomalies in stardust SiC grains, particularly for these large grains which have low trace element abundances, our results are consistent with previous observations that Ba isotopic ratios are dependent on grain size. We have compared the SiC data with theoretical predictions of the evolution of Ba isotopic ratios in the envelopes of low-mass AGB stars with a range of stellar masses and metallicities. The Ba isotopic measurements obtained for large SiC grains from the LS + LU fractions are consistent with grain condensation in the envelope of very low-mass AGB stars (1.25 M⊙) with close-to-solar metallicity, which suggests that conditions for growth of large SiC might be more favorable in very low-mass AGB stars during the early C-rich stages of AGB evolution or in stable structures around AGB stars whose evolution was cut short due to binary interaction, before the AGB envelope had already been largely enriched with the products of s-process nucleosynthesis.

Microscopic derivation of IBM and structural evolution in nuclei

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nomura, Kosuke

A Hamiltonian of the interacting boson model (IBM) is derived based on the mean-field calculations with nuclear energy density functionals (EDFs). The multi-nucleon dynamics of the surface deformation is simulated in terms of the boson degrees of freedom. The interaction strengths of the IBM Hamiltonian are determined by mapping the potential energy surfaces (PESs) of a given EDF with quadrupole degrees of freedom onto the corresponding PES of IBM. A fermion-to-boson mapping for a rotational nucleus is discussed in terms of the rotational response, which reflects a specific time-dependent feature. Ground-state correlation energy is evaluated as a signature of structuralmore » evolution. Some examples resulting from the present spectroscopic calculations are shown for neutron-rich Pt, Os and W isotopes including exotic ones.« less

Stabile Chlorine Isotope Study of Martian Shergottites and Nakhlites; Whole Rock and Acid Leachates and Residues

NASA Technical Reports Server (NTRS)

Nakamura, N.; Nyquist, L. E.; Reese, Y.; Shih, C-Y; Fujitani, T.; Okano, O.

2011-01-01

We have established a precise analytical technique for stable chlorine isotope measurements of tiny planetary materials by TIMS (Thermal Ionization Mass Spectrometry) [1], for which the results are basically consistent with the IRMS tech-nique (gas source mass spectrometry) [2,3,4]. We present here results for Martian shergottites and nakhlites; whole rocks, HNO3-leachates and residues, and discuss the chlorine isotope evolution of planetary Mars.

Effects of must concentration techniques on wine isotopic parameters.

PubMed

Guyon, Francois; Douet, Christine; Colas, Sebastien; Salagoïty, Marie-Hélène; Medina, Bernard

2006-12-27

Despite the robustness of isotopic methods applied in the field of wine control, isotopic values can be slightly influenced by enological practices. For this reason, must concentration technique effects on wine isotopic parameters were studied. The two studied concentration techniques were reverse osmosis (RO) and high-vacuum evaporation (HVE). Samples (must and extracted water) have been collected in various French vineyards. Musts were microfermented at the laboratory, and isotope parameters were determined on the obtained wine. Deuterium and carbon-13 isotope ratios were studied on distilled ethanol by nuclear magnetic resonance (NMR) and isotope ratio mass spectrometry (IRMS), respectively. The oxygen-18 ratio was determined on extracted and wine water using IRMS apparatus. The study showed that the RO technique has a very low effect on isotopic parameters, indicating that this concentration technique does not create any isotopic fractionation, neither at sugar level nor at water level. The effect is notable for must submitted to HVE concentration: water evaporation leads to a modification of the oxygen-18 ratio of the must and, as a consequence, ethanol deuterium concentration is also modified.

Application of non-traditional stable isotopes in analytical ecogeochemistry assessed by MC ICP-MS--A critical review.

PubMed

Irrgeher, Johanna; Prohaska, Thomas

2016-01-01

Analytical ecogeochemistry is an evolving scientific field dedicated to the development of analytical methods and tools and their application to ecological questions. Traditional stable isotopic systems have been widely explored and have undergone continuous development during the last century. The variations of the isotopic composition of light elements (H, O, N, C, and S) have provided the foundation of stable isotope analysis followed by the analysis of traditional geochemical isotope tracers (e.g., Pb, Sr, Nd, Hf). Questions in a considerable diversity of scientific fields have been addressed, many of which can be assigned to the field of ecogeochemistry. Over the past 15 years, other stable isotopes (e.g., Li, Zn, Cu, Cl) have emerged gradually as novel tools for the investigation of scientific topics that arise in ecosystem research and have enabled novel discoveries and explorations. These systems are often referred to as non-traditional isotopes. The small isotopic differences of interest that are increasingly being addressed for a growing number of isotopic systems represent a challenge to the analytical scientist and push the limits of today's instruments constantly. This underlines the importance of a metrologically sound concept of analytical protocols and procedures and a solid foundation of data processing strategies and uncertainty considerations before these small isotopic variations can be interpreted in the context of applied ecosystem research. This review focuses on the development of isotope research in ecogeochemistry, the requirements for successful detection of small isotopic shifts, and highlights the most recent and innovative applications in the field.

Sediment Tracking Using Carbon and Nitrogen Stable Isotopes

NASA Astrophysics Data System (ADS)

Fox, J. F.; Papanicolaou, A.

2002-12-01

As landscapes are stripped of valuable, nutrient rich topsoils and streams are clouded with habitat degrading fine sediment, it becomes increasingly important to identify and mitigate erosive surfaces. Particle tracking using vegetative derived carbon (C) and nitrogen (N) isotopic signatures and carbon/nitrogen (C/N) atomic ratios offer a promising technique to identify such problematic sources. Consultants and researchers successfully use C, N, and other stable isotopes of water for hydrologic purposes, such as quantifying groundwater vs. surface water contribution to a hydrograph. Recently, C and N isotopes and C/N atomic ratios of sediment were used to determine sediment mass balance within estuarine environments. The current research investigates C and N isotopes and C/N atomic ratios of source sediment for two primary purposes: (1) to establish a blueprint methodology for estimating sediment source and erosion rates within a watershed using this isotopic technology coupled with mineralogy fingerprinting techniques, radionuclide transport monitoring, and erosion-transport models, and (2) to complete field studies of upland erosion processes, such as, solifluction, mass wasting, creep, fluvial erosion, and vegetative induced erosion. Upland and floodplain sediment profiles and riverine suspended sediment were sampled on two occasions, May 2002 and August 2002, in the upper Palouse River watershed of northern Idaho. Over 300 samples were obtained from deep intermountain valley (i.e. forest) and rolling crop field (i.e. agriculture) locations. Preliminary sample treatment was completed at the Washington State University Water Quality Laboratory where samples were dried, removed of organic constituents, and prepared for isotopic analysis. C and N isotope and C/N atomic ratio analyses was performed at the University of Idaho Natural Resources Stable Isotope Laboratory using a Costech 4010 Elemental Combustion System connected with a continuous flow inlet system to

Phase field modeling of microstructure evolution and concomitant effective conductivity change in solid oxide fuel cell electrodes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lei, Yinkai; Cheng, Tian -Le; Wen, You -Hai

Microstructure evolution plays an important role in the performance degradation of SOFC electrodes. In this work, we propose a much improved phase field model to simulate the microstructure evolution in the electrodes of solid oxide fuel cell. We demonstrate that the tunability of the interfacial energy in this model has been significantly enhanced. Parameters are set to fit for the interfacial energies of a typical Ni-YSZ anode, an LSM-YSZ cathode and an artificial reference electrode, respectively. The contact angles at various triple junctions and the microstructure evolutions in two dimensions are calibrated to verify the model. As a demonstration ofmore » the capabilities of the model, three dimensional microstructure evolutions are simulated applying the model to the three different electrodes. The time evolutions of grain size and triple phase boundary density are analyzed. In addition, a recently proposed bound charge successive approximation algorithm is employed to calculate the effective conductivity of the electrodes during microstructure evolution. Furthermore, the effective conductivity of all electrodes are found to decrease during the microstructure evolution, which is attributed to the increased tortuosity and the loss of percolated volume fraction of the electrode phase.« less

Phase field modeling of microstructure evolution and concomitant effective conductivity change in solid oxide fuel cell electrodes

DOE PAGES

Lei, Yinkai; Cheng, Tian -Le; Wen, You -Hai

2017-02-13

Microstructure evolution plays an important role in the performance degradation of SOFC electrodes. In this work, we propose a much improved phase field model to simulate the microstructure evolution in the electrodes of solid oxide fuel cell. We demonstrate that the tunability of the interfacial energy in this model has been significantly enhanced. Parameters are set to fit for the interfacial energies of a typical Ni-YSZ anode, an LSM-YSZ cathode and an artificial reference electrode, respectively. The contact angles at various triple junctions and the microstructure evolutions in two dimensions are calibrated to verify the model. As a demonstration ofmore » the capabilities of the model, three dimensional microstructure evolutions are simulated applying the model to the three different electrodes. The time evolutions of grain size and triple phase boundary density are analyzed. In addition, a recently proposed bound charge successive approximation algorithm is employed to calculate the effective conductivity of the electrodes during microstructure evolution. Furthermore, the effective conductivity of all electrodes are found to decrease during the microstructure evolution, which is attributed to the increased tortuosity and the loss of percolated volume fraction of the electrode phase.« less

Constraints of lithium isotopes on petrogenesis of the Northern Luzon arc in Eastern Taiwan

NASA Astrophysics Data System (ADS)

Hsiao, C. C.; Chu, M. F.; Lai, Y. M.; Lin, T. H.

2017-12-01

Lithium stable isotopes have great potential as a tracer of terrestrial materials in crust-mantle recycling. However, the causes of their variations in arc magmatism remain controversial. The Northern Luzon arc has long been demonstrated incorporation of the sediment melt into its sub-arc mantle. The Li isotopes of volcanic rocks in the Coastal Range, located in Eastern Taiwan, thus are studied to examine the effects of sediment melt on the evolution of Li isotopes in subduction zone and also to constrain the petrogenesis of the northernmost part of Northern Luzon arc. It is worth to note that we had ruled out samples that were significantly influenced by crustal contamination according to the proportion of inherited zircons, trace-elemental and Sr-Nd isotopic geochemistry. Concerning that Li isotopic fractionation is negligible during fractional crystallization and partial melting, the variation of Li/Y and δ7Li in rock samples of this study mainly reflects the geochemistry of magma sources. The overall range of δ7Li is very restricted (δ7Li = +2.9 +5.8) and consistent with that of N-MORB. In addition, ɛNd of the Coastal Range volcanic rocks lowers not only with increasing values of sediment-melt indicators (e.g., Th/Ce, Th/Yb and La/Sm), but also Li/Y (from 0.5 to 1.1 ppm). This suggests the involvement of sediment melt with equivalent δ7Li to and higher Li/Y than those of N-MORB, in magma source of the Coastal Range arc volcanism. In summary, the Li isotopic compositions of the Coastal Range volcanic rocks demonstrate that (1) Li/Y commonly treated as a tracer of fluid in arc magmatism indeed can be significantly affected by the input of sediment melt as well, and (2) sediment melt played a key role in the evolution of Li/Y and lithium isotopes in the mantle wedge, but showed least influence on Li isotopic variation possibly as a result of the similarity between δ7Li of sediments subducted and of the upper mantle.

Devonian climate and reef evolution: Insights from oxygen isotopes in apatite

NASA Astrophysics Data System (ADS)

Joachimski, M. M.; Breisig, S.; Buggisch, W.; Talent, J. A.; Mawson, R.; Gereke, M.; Morrow, J. R.; Day, J.; Weddige, K.

2009-07-01

Conodonts, microfossils composed of carbonate-fluor apatite, are abundant in Palaeozoic-Triassic sediments and have a high potential to preserve primary oxygen isotope signals. In order to reconstruct the palaeotemperature history of the Devonian, the oxygen isotope composition of apatite phosphate was measured on 639 conodont samples from sequences in Europe, North America and Australia. The Early Devonian (Lochkovian; 416-411 Myr) was characterized by warm tropical temperatures of around 30 °C. A cooling trend started in the Pragian (410 Myr) with intermediate temperatures around 23 to 25 °C reconstructed for the Middle Devonian (397-385 Myr). During the Frasnian (383-375 Myr), temperatures increased again with temperatures to 30 °C calculated for the Frasnian-Famennian transition (375 Myr). During the Famennian (375-359 Myr), surface water temperatures slightly decreased. Reconstructed Devonian palaeotemperatures do not support earlier views suggesting the Middle Devonian was a supergreenhouse interval, an interpretation based partly on the development of extensive tropical coral-stromatoporoid communities during the Middle Devonian. Instead, the Devonian palaeotemperature record suggests that Middle Devonian coral-stromatoporoid reefs flourished during cooler time intervals whereas microbial reefs dominated during the warm to very warm Early and Late Devonian.

Transmitted light relaxation and microstructure evolution of ferrofluids under gradient magnetic fields

NASA Astrophysics Data System (ADS)

Huang, Yan; Li, Decai; Li, Feng; Zhu, Quanshui; Xie, Yu

2015-03-01

Using light transmission experiments and optical microscope observations with a longitudinal gradient magnetic field configuration, the relationship between the behavior of the transmitted light relaxation and the microstructure evolution of ionic ferrofluids in the central region of an axisymmetric field is investigated. Under a low-gradient magnetic field, there are two types of relaxation process. When a field is applied, the transmitted light intensity decreases to a minimum within a time on the order of 101-102 s. It is then gradually restored, approaching its initial value within a time on the order of 102 s. This is type I relaxation, which corresponds to the formation of magnetic columns. After the transmission reaches this value, it either increases or decreases slowly, stabilizing within a time on the order of 103 s, according to the direction of the field gradient. This is a type II relaxation, which results from the shadowing effect, corresponding to the motion of the magnetic columns under the application of a gradient force. Under a magnetic field with a centripetal high-gradient (magnetic materials subjected to a force pointing toward the center of the axisymmetric field), the transmitted light intensity decreases monotonously and more slowly than that under a low-gradient field. Magnetic transport and separation resulted from magnetophoresis under high-gradient fields, changing the formation dynamics of the local columns and influencing the final state of the column system.

Oxygen Isotope Evidence for the Relationship between CM and CO Chondrites: Could they Both Coexist on a Single Asteroid

NASA Technical Reports Server (NTRS)

Greenwood, R. C.; Howard, K. T.; Franchi, I. A.; Zolensky, M. E.; Buchanan, P. C.; Gibson, J. M.

2014-01-01

Water played a critical role in the early evolution of asteroids and planets, as well as being an essential ingredient for life on Earth. However, despite its importance, the source of water in the inner solar system remains controversial. Delivery of water to Earth via comets is inconsistent with their relatively elevated D/H ratios, whereas carbonaceous chondrites (CCs) have more terrestrial-like D/H ratios [1]. Of the eight groups into which the CCs are divided, only three (CI, CM, CR) show evidence of extensive aqueous alteration. Of these, the CMs form the single most important group, representing 34% of all CC falls and a similar percentage of finds (Met. Bull. Database). CM material also dominates the population of CC clasts in extraterrestrial samples [2, 3]. The Antarctic micrometeorites population is also dominated by CM and CI-like material and similar particles may have transported water and volatiles to the early Earth [4]. CCs, and CMs in particular, offer the best opportunity for investigating the evolution of water reservoirs in the early solar system. An important aspect of this problem involves identifying the anhydrous silicate component which co-accreted with ice in the CM parent body. A genetic relationship between the essentially anhydrous CO group and the CMs was proposed on the basis of oxygen isotope evidence [5]. However, previous CM whole-rock oxygen isotope data scattered about a line of approximately 0.5 that did not intersect the field of CO chondrites [5]. Here we discuss new oxygen isotope data which provides additional constraints on the relationship between CO and CM chondrites.

The geologic evolution of the moon

NASA Technical Reports Server (NTRS)

Lowman, P. D., Jr.

1971-01-01

A synthesis of pre- and post-Apollo 11 studies is presented to produce an outline of the moon's geologic evolution from three lines of evidence: (1) relative ages of lunar landforms and rock types, (2) absolute ages of returned lunar samples, and (3) petrography, chemistry, and isotopic ratios of lunar rocks and soils. It is assumed that the ray craters, circular mare basins, and most intermediate circular landforms are primarily of impact origin, although many other landforms are volcanic or of hybrid origin. The moon's evolution is divided into four main stages, each including several distinct but overlapping events or processes.

Magnetic field evolution in dwarf and Magellanic-type galaxies

NASA Astrophysics Data System (ADS)

Siejkowski, H.; Soida, M.; Chyży, K. T.

2018-03-01

Aims: Low-mass galaxies radio observations show in many cases surprisingly high levels of magnetic field. The mass and kinematics of such objects do not favour the development of effective large-scale dynamo action. We attempted to check if the cosmic-ray-driven dynamo can be responsible for measured magnetization in this class of poorly investigated objects. We investigated how starburst events on the whole, as well as when part of the galactic disk, influence the magnetic field evolution. Methods: We created a model of a dwarf/Magellanic-type galaxy described by gravitational potential constituted from two components: the stars and the dark-matter halo. The model is evolved by solving a three-dimensional (3D) magnetohydrodynamic equation with an additional cosmic-ray component, which is approximated as a fluid. The turbulence is generated in the system via supernova explosions manifested by the injection of cosmic-rays. Results: The cosmic-ray-driven dynamo works efficiently enough to amplify the magnetic field even in low-mass dwarf/Magellanic-type galaxies. The e-folding times of magnetic energy growth are 0.50 and 0.25 Gyr for the slow (50 km s-1) and fast (100 km s-1) rotators, respectively. The amplification is being suppressed as the system reaches the equipartition level between kinetic, magnetic, and cosmic-ray energies. An episode of star formation burst amplifies the magnetic field but only for a short time while increased star formation activity holds. We find that a substantial amount of gas is expelled from the galactic disk, and that the starburst events increase the efficiency of this process.

Comparison of pore water samplers and cryogenic distillation under laboratory and field conditions for soil water stable isotope analysis.

PubMed

Thoma, Michael; Frentress, Jay; Tagliavini, Massimo; Scandellari, Francesca

2018-02-15

We used pore water samplers (PWS) to sample for isotope analysis (1) only water, (2) soil under laboratory conditions, and (3) soil in the field comparing the results with cryogenic extraction (CE). In (1) and (2), no significant differences between source and water extracted with PWS were detected with a mean absolute difference (MAD) always lower than 2 ‰ for δ 2 H and 1 ‰ for δ 18 O. In (2), CE water was more enriched than PWS-extracted water, with a MAD respect to source water of roughly 8 ‰ for δ 2 H and 4 ‰ for δ 18 O. In (3), PWS water was enriched relative to CE water by 3 ‰ for δ 2 H and 0.9 ‰ for δ 18 O. The latter result may be due to the distinct water portions sampled by the two methods. Large pores, easily sampled by PWS, likely retain recent, and enriched, summer precipitation while small pores, only sampled by CE, possibly retain isotopically depleted water from previous winter precipitation or irrigation inputs. Accuracy and precision were greater for PWS relative to CE. PWS is therefore suggested as viable tool to extract soil water for stable isotope analysis, particularly for soils used in this study (sandy and silty loams).

Future stable water isotope projection with an isotope-AGCM driven by CMIP5 SSTs

NASA Astrophysics Data System (ADS)

Yoshimura, K.

2016-12-01

Stable water isotope ratios (dD and d18O) are widely used as proxy of past climate changes, and it is extremely important to understand and predict the mechanism of current isotopic spatio-temporal behavior with regard to the on-going climate change. However, as compared many studies on reproduction of isotopes for the past, there are few studies on future projection of isotopes. Therefore, in this study, a set of experiments using an isotope-incorporate AGCM (IsoGSM) with SST and sea ice field simulated from multiple CMIP5 models, namely MIROC5, CCSM4, and MRI-CGCM3, were conducted for the end of 20th century (1980-1990) and the end of 21st century (2080-2090) under RCP2.6 and RCP8.5 scenarios. Thus the responses in stable water isotope ratio in precipitation and water vapor in accordance to the global warming were investigated. As results, the changes in global surface air temperature were about +1K and +3K with RCP2.6 and RCP8.5, respectively. Similarly, the global precipitation changes were about +0.07mm/day (about +2%) and +0.18mm/day (about +5%), and the global precipitable water changes were about +2mm (+7%) and +6mm (+24%), respectively. The moisture was increased in accordance to the Clausius-Clapayron theory (7%/K), but the increase in precipitation is not that large. This indicates that the global hydrological cycle was slowed down in the globally warmed experiments. On the other hand, for the isotopic signals, the changes in globally averaged d18O in precipitation were about 0.2‰ and 0.4‰, and those in precipitable water were 0.2‰ and 0.5‰, in RCP2.6 and RCP8.5, respectively. It is well-known that there are temperature effect (positive correlation in air temperature and precipitation isotopes) and amount effect (negative correlation in precipitation amount and isotopes), but in the globally warmed world, these effects were offset, and only weaker temperature effect was appeared in the global mean isotope signals. Regional details will be shown

Hydrogen Isotope Fractionation during the Biodegradation of 1,2-Dichloroethane: Potential for Pathway Identification Using a Multi-element (C, Cl, and H) Isotope Approach.

PubMed

Palau, Jordi; Shouakar-Stash, Orfan; Hatijah Mortan, Siti; Yu, Rong; Rosell, Monica; Marco-Urrea, Ernest; Freedman, David L; Aravena, Ramon; Soler, Albert; Hunkeler, Daniel

2017-09-19

Even though multi-element isotope fractionation patterns provide crucial information with which to identify contaminant degradation pathways in the field, those involving hydrogen are still lacking for many halogenated groundwater contaminants and degradation pathways. This study investigates for the first time hydrogen isotope fractionation during both aerobic and anaerobic biodegradation of 1,2-dichloroethane (1,2-DCA) using five microbial cultures. Transformation-associated isotope fractionation values (ε bulk H ) were -115 ± 18‰ (aerobic C-H bond oxidation), -34 ± 4‰ and -38 ± 4‰ (aerobic C-Cl bond cleavage via hydrolytic dehalogenation), and -57 ± 3‰ and -77 ± 9‰ (anaerobic C-Cl bond cleavage via reductive dihaloelimination). The dual-element C-H isotope approach (Λ C-H = Δδ 2 H/Δδ 13 C ≈ ε bulk H /ε bulk C , where Δδ 2 H and Δδ 13 C are changes in isotope ratios during degradation) resulted in clearly different Λ C-H values: 28 ± 4 (oxidation), 0.7 ± 0.1 and 0.9 ± 0.1 (hydrolytic dehalogenation), and 1.76 ± 0.05 and 3.5 ± 0.1 (dihaloelimination). This result highlights the potential of this approach to identify 1,2-DCA degradation pathways in the field. In addition, distinct trends were also observed in a multi- (i.e., Δδ 2 H versus Δδ 37 Cl versus Δδ 13 C) isotope plot, which opens further possibilities for pathway identification in future field studies. This is crucial information to understand the mechanisms controlling natural attenuation of 1,2-DCA and to design appropriate strategies to enhance biodegradation.

Chemical evolution of Mg isotopes versus the time variation of the fine structure constant.

PubMed

Ashenfelter, T; Mathews, Grant J; Olive, Keith A

2004-01-30

We show that the synthesis of (25,26)Mg at the base of the convective envelope in low-metallicity asymptotic giant branch stars can produce the isotopic ratios needed to explain the low-z subset (with z<1.8) of the many-multiplet data from quasar absorption systems without invoking a time variation of the fine structure constant. This is supported by observations of high abundances of the neutron-rich Mg isotopes in metal-poor globular-cluster stars. We conclude that the quasar absorption spectra may be providing interesting information on the nucleosynthetic history of such systems.

Carbon isotope geochemistry of hydrocarbons in the Cerro Prieto geothermal field, Baja California Norte, Mexico

NASA Technical Reports Server (NTRS)

Des Marais, D. J.; Stallard, M. L.; Nehring, N. L.; Truesdell, A. H.

1988-01-01

Hydrocarbon abundances and stable-isotopic compositions were measured in wells M5, M26, M35 and M102, which represent a range of depths (1270-2000 m) and temperatures (275-330 degrees C) in the field. In order to simulate the production of the geothermal hydrocarbons, gases were collected from the pyrolysis of lignite in the laboratory. This lignite was obtained from a well which sampled rock strata which are identical to those occurring in the field, but which have experienced much lower subsurface temperatures. In both the well and the laboratory observations, high-temperature environments favored higher relative concentrations of methane, ethane and benzene and generally higher delta 13C-values in the individual hydrocarbons. The best correlation between the laboratory and well data is obtained when laboratory-produced gases from experiments conducted at lower (400 degrees C) and higher (600 degrees C) temperatures are mixed. This improved correlation suggests that the wells are sampling hydrocarbons produced from a spectrum of depths and temperatures in the sediments.

Isotope Reanalysis for 20th century: Reproduction of isotopic time series in corals, tree-rings, and tropical ice cores

NASA Astrophysics Data System (ADS)

Yoshimura, K.

2012-04-01

In the present study, an isotope-incorporated GCM simulation for AD1871 to AD2008 nudged toward the so-called "20th Century Reanalysis (20CR)" atmospheric fields is conducted. Beforehand the long-term integration, a method to downscale ensemble mean fields is proposed, since 20CR is a product of 56-member ensemble Kalman filtering data assimilation. The method applies a correction to one of the ensemble members in such a way that the seasonal mean is equal to that of the ensemble mean, and then the corrected member is inputted into the isotope-incorporated GCM (i.e., IsoGSM) with the global spectral nudging technique. Use of the method clearly improves the skill than the cases of using only a single member and of using the ensemble means; the skill becomes equivalent to when 3-6 members are directly used. By comparing with GNIP precipitation isotope database, it is confirmed that the 20C Isotope Reanalysis's performance for latter half of the 20th century is just comparable to the other latest studies. For more comparisons for older periods, proxy records including corals, tree-rings, and tropical ice cores are used. First for corals: the 20C Isotope Reanalysis successfully reproduced the δ18O in surface sea water recorded in the corals at many sites covering large parts of global tropical oceans. The comparison suggests that coral records represent past hydrologic balance information where interannual variability in precipitation is large. Secondly for tree-rings: δ18O of cellulose extracted from the annual rings of the long-lived Bristlecone Pine from White Mountain in Southern California is well reproduced by 20C Isotope Reanalysis. Similar good performance is obtained for Cambodia, too. However, the mechanisms driving the isotopic variations are different over California and Cambodia; for California, Hadley cell's expansion and consequent meridional shift of the submerging dry zone and changes in water vapor source is the dominant control, but in Cambodia

Equilibrium stable-isotope fractionation of thallium and mercury

NASA Astrophysics Data System (ADS)

Schauble, E. A.

2005-12-01

In this study first-principles quantum mechanical and empirical force-field models are used to estimate equilibrium mass-dependent isotopic fractionations among a variety of thallium and mercury compounds. High-precision MC-ICP-MS measurements have recently uncovered evidence of stable isotope fractionation for many elements, including 2-4‰ variability in the isotopic compositions of thallium[1] (atomic no. 81) and mercury[2] (atomic no. 80). The observed thallium- and mercury-isotope fractionations are remarkable, given that the magnitude of isotopic fractionation typically decreases as atomic number increases[3]. Stable isotope measurements could improve our understanding of geochemical and biogeochemical cycling of both elements, but little is known about the mechanisms driving these fractionations. A better understanding of the chemical processes controlling stable isotope compositions could help maximize the utility of these new geochemical tracers. Standard equilibrium stable isotope fractionation theory holds that the energy driving fractionation comes from isotopic effects on vibrational frequencies, which have generally not been measured. In the present study both quantum-mechanical and empirical force fields are used to estimate unknown frequencies. Results suggest that thallium and mercury fractionations of ≥ 0.5‰ are likely during the relevant redox reactions Tl+ ↔ Tl3+ and HgO ↔ Hg2+. Methyl-mercury and mercury-halide compounds like CH3HgCl will have ~ 1‰ higher 202Hg/198Hg than atomic vapor at room temperature. Fractionations between coexisting Hg2+ species appear to be much smaller, however. 205Tl/203Tl in Tl(H2O)_63+ is predicted to be ~0.5‰ higher than in coexisting Tl+-bearing substances. This result is in qualitative agreement with data from ferromanganese crusts [1], suggesting that Tl3+ in manganese-oxides will have higher 205Tl/203Tl than aqueous Tl+. Equilibrium fractionations for both elements are much smaller than the observed

Modelling and intepreting the isotopic composition of water vapour in convective updrafts

NASA Astrophysics Data System (ADS)

Bolot, M.; Legras, B.; Moyer, E. J.

2012-08-01

The isotopic compositions of water vapour and its condensates have long been used as tracers of the global hydrological cycle, but may also be useful for understanding processes within individual convective clouds. We review here the representation of processes that alter water isotopic compositions during processing of air in convective updrafts and present a unified model for water vapour isotopic evolution within undiluted deep convective cores, with a special focus on the out-of-equilibrium conditions of mixed phase zones where metastable liquid water and ice coexist. We use our model to show that a combination of water isotopologue measurements can constrain critical convective parameters including degree of supersaturation, supercooled water content and glaciation temperature. Important isotopic processes in updrafts include kinetic effects that are a consequence of diffusive growth or decay of cloud particles within a supersaturated or subsaturated environment; isotopic re-equilibration between vapour and supercooled droplets, which buffers isotopic distillation; and differing mechanisms of glaciation (droplet freezing vs. the Wegener-Bergeron-Findeisen process). As all of these processes are related to updraft strength, droplet size distribution and the retention of supercooled water, isotopic measurements can serve as a probe of in-cloud conditions of importance to convective processes. We study the sensitivity of the profile of water vapour isotopic composition to differing model assumptions and show how measurements of isotopic composition at cloud base and cloud top alone may be sufficient to retrieve key cloud parameters.

Modelling and interpreting the isotopic composition of water vapour in convective updrafts

NASA Astrophysics Data System (ADS)

Bolot, M.; Legras, B.; Moyer, E. J.

2013-08-01

The isotopic compositions of water vapour and its condensates have long been used as tracers of the global hydrological cycle, but may also be useful for understanding processes within individual convective clouds. We review here the representation of processes that alter water isotopic compositions during processing of air in convective updrafts and present a unified model for water vapour isotopic evolution within undiluted deep convective cores, with a special focus on the out-of-equilibrium conditions of mixed-phase zones where metastable liquid water and ice coexist. We use our model to show that a combination of water isotopologue measurements can constrain critical convective parameters, including degree of supersaturation, supercooled water content and glaciation temperature. Important isotopic processes in updrafts include kinetic effects that are a consequence of diffusive growth or decay of cloud particles within a supersaturated or subsaturated environment; isotopic re-equilibration between vapour and supercooled droplets, which buffers isotopic distillation; and differing mechanisms of glaciation (droplet freezing vs. the Wegener-Bergeron-Findeisen process). As all of these processes are related to updraft strength, particle size distribution and the retention of supercooled water, isotopic measurements can serve as a probe of in-cloud conditions of importance to convective processes. We study the sensitivity of the profile of water vapour isotopic composition to differing model assumptions and show how measurements of isotopic composition at cloud base and cloud top alone may be sufficient to retrieve key cloud parameters.

Measurement of isotope ratio of Ca{sup +} ions in a linear Paul Trap

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hashimoto, Y.; Minamino, K.; Nagamoto, D.

2009-03-17

Measurement of isotope ratios of Calcium is very useful in many fields. So we demonstrated the measurement of isotope ratios of {sup 40}Ca{sup +}(abundance 96.4%) to {sup 44}Ca{sup +}(2.09%) ions in a linear Paul trap with several laser lights tuning to the isotope shifts. And we found that the experimental parameters had large influences on the measurement of the isotope ratios.

Evolution of atmospheric xenon and other noble gases inferred from Archean to Paleoproterozoic rocks

NASA Astrophysics Data System (ADS)

Avice, G.; Marty, B.; Burgess, R.; Hofmann, A.; Philippot, P.; Zahnle, K.; Zakharov, D.

2018-07-01

We have analyzed ancient atmospheric gases trapped in fluid inclusions contained in minerals of Archean (3.3 Ga) to Paleozoic (404 Ma) rocks in an attempt to document the evolution of the elemental composition and isotopic signature of the atmosphere with time. Doing so, we aimed at understanding how physical and chemical processes acted over geological time to shape the modern atmosphere. Modern atmospheric xenon is enriched in heavy isotopes by 30-40‰ u-1 relative to Solar or Chondritic xenon. Previous studies demonstrated that, 3.3 Ga ago, atmospheric xenon was isotopically fractionated (enriched in the light isotopes) relative to the modern atmosphere, by 12.9 ± 1.2 (1σ) ‰ u-1, whereas krypton was isotopically identical to modern atmospheric Kr. Details about the specific and progressive isotopic fractionation of Xe during the Archean, originally proposed by Pujol et al. (2011), are now well established by this work. Xe isotope fractionation has evolved from 21‰ u-1 at 3.5 Ga to 12.9‰ u-1 at 3.3 Ga. The current dataset provides some evidence for stabilization of the Xe fractionation between 3.3 and 2.7 Ga. However, further studies will be needed to confirm this observation. After 2.7 Ga, the composition kept evolving and reach the modern-like atmospheric Xe composition at around 2.1 Ga ago. Xenon may be the second atmospheric element, after sulfur, to show a secular isotope evolution during the Archean that ended shortly after the Archean-Proterozoic transition. Fractionation of xenon indicates that xenon escaped from Earth, probably as an ion, and that Xe escape stopped when the atmosphere became oxygen-rich. We speculate that the Xe escape was enabled by a vigorous hydrogen escape on the early anoxic Earth. Organic hazes, scavenging isotopically heavy Xe, could also have played a role in the evolution of atmospheric Xe. For 3.3 Ga-old samples, Ar-N2 correlations are consistent with a partial pressure of nitrogen (pN2) in the Archean atmosphere

Mg Isotope variations of Marinoan Cap Carbonates: implications for the chemical evolution of Neoproterozoic Ocean after snowball earth

NASA Astrophysics Data System (ADS)

Liu, C.; Macdonald, F. A.; Raub, T.; Wang, Z.; Evans, D. A.

2012-12-01

We report Mg isotope profiles of two cap-carbonates: Nuccaleena formation from south Australia (mostly dolostones) and Tsagaan Oloom Formation from southwest Mongolia (including dolostones, aragonite crystal fans, and lime-mudstones). These data provide additional constraints on the chemical evolution of Neoproterozoic Oceans after the Marinoan deglaciation. An incremental leaching technique using ammonium acetate and various concentrations of acetic acid and hydrochloric acid was applied to separate metals in various forms from cap-carbonates (including surface adsorbed phases, calcite, dolomite and clay minerals). The leachates were then passed through chromatographic columns to extract pure Mg and Sr, which were then analyzed for their isotopic compositions by MC-ICP-MS (Neptune) at Yale University. Elemental ratios (Mg/Ca and Sr/Ca) in each leaching steps were also measured. Our results show that small variations of δ26MgDSM3 with leaching steps were observed in most dolostone samples when secondary calcite is absent. In contrast, large Mg isotope variations (up to 1.5 per mil) were shown in the leaching steps of limestone and crystal fans. The primary δ26MgDSM3 value of each sample was chosen from the leachate that has the lowest 87Sr/86Sr ratios. The δ26MgDSM3 value of Nuccaleena dolostone increases from -2.2‰ at the basal part of the section to -1.7‰ in the middle, and then turns back to -2.0‰ on the top, with a positive correlation between 26Mg/24Mg and 87Sr/86Sr ratios, implying that the high δ26MgDSM3 values may be caused by alteration or inherit from continental-derived fluids. In contrast, small δ26MgDSM3 variations in Tsagaan Oloom dolostones were exhibited in different leaching steps or cross the section (~-1.7‰), with high 87Sr/86Sr ratios (~0.7090), resembling cap dolostones from middle part of Nuccaleena dolostone, implying that they are formed in a similar environment. However, the δ26MgDSM3 value of upper lime-mudstones and crystal

Kinetic field theory: exact free evolution of Gaussian phase-space correlations

NASA Astrophysics Data System (ADS)

Fabis, Felix; Kozlikin, Elena; Lilow, Robert; Bartelmann, Matthias

2018-04-01

In recent work we developed a description of cosmic large-scale structure formation in terms of non-equilibrium ensembles of classical particles, with time evolution obtained in the framework of a statistical field theory. In these works, the initial correlations between particles sampled from random Gaussian density and velocity fields have so far been treated perturbatively or restricted to pure momentum correlations. Here we treat the correlations between all phase-space coordinates exactly by adopting a diagrammatic language for the different forms of correlations, directly inspired by the Mayer cluster expansion. We will demonstrate that explicit expressions for phase-space density cumulants of arbitrary n-point order, which fully capture the non-linear coupling of free streaming kinematics due to initial correlations, can be obtained from a simple set of Feynman rules. These cumulants will be the foundation for future investigations of perturbation theory in particle interactions.

Variability of Fe isotope compositions of hydrothermal sulfides and oxidation products at mid-ocean ridges

NASA Astrophysics Data System (ADS)

Li, Xiaohu; Wang, Jianqiang; Chu, Fengyou; Wang, Hao; Li, Zhenggang; Yu, Xing; Bi, Dongwei; He, Yongsheng

2018-04-01

Significant Fe isotopic fractionation occurs during the precipitation and oxidative weathering of modern seafloor hydrothermal sulfides, which has an important impact on the cycling of Fe isotopes in the ocean. This study reports the Fe-isotope compositions of whole-rock sulfides and single-mineral pyrite collected from hydrothermal fields at the South Mid-Atlantic Ridge (SMAR) and the East Pacific Rise (EPR) and discusses the impacts of precipitation and late-stage oxidative weathering of sulfide minerals on Fe isotopic fractionation. The results show large variation in the Fe-isotope compositions of the sulfides from the different hydrothermal fields on the mid-oceanic ridges, indicating that relatively significant isotope fractionation occurs during the sulfide precipitation and oxidative weathering processes. The Fe-isotope compositions of the sulfides from the study area at the SMAR vary across a relatively small range, with an average value of 0.01‰. This Fe-isotope composition is similar to the Fe-isotope composition of mid-oceanic ridge basalt, which suggests that Fe was mainly leached from basalt. In contrast, the Fe-isotope composition of the sulfides from the study area at the EPR are significantly enriched in light Fe isotopes (average value - 1.63‰), mainly due to the kinetic fractionation during the rapid precipitation process of hydrothermal sulfide. In addition, the pyrite from different hydrothermal fields is enriched in light Fe isotopes, which is consistent with the phenomenon in which light Fe isotopes are preferentially enriched during the precipitation of pyrite. The red oxides have the heaviest Fe-isotope compositions (up to 0.80‰), indicating that heavy Fe isotopes are preferentially enriched in the oxidation product during the late-stage oxidation process. The data obtained from this study and previous studies show a significant difference between the Fe-isotope compositions of the sulfides from the SMAR and EPR. The relatively heavy

Chlorine Isotope Ratios in M Giants and S Stars

NASA Astrophysics Data System (ADS)

Maas, Zachary; Pilachowski, C. A.

2018-01-01

Chlorine is an odd-Z, light element that has been poorly studied in stars. Recently, the first stellar abundance measurements of the isotopologue 35Cl were made and the 35Cl/37Cl ratio was derived in RZ Ari (Maas et al. 2016). Additional abundance measurements are necessary to understand the Galactic chemical evolution and complex nucleosynthesis of Cl. The Cl isotope ratio in particular is important in distinguishing contributions from different nucleosynthesis sites to the surface abundances of stars. For example, current nucloesynthesis models predict that both isotopes of Cl are produced primarily during core collapse supernovae (CCSNe) with the energy and progenitor mass impacting the isotopic ratio of the ejected material. In addition to CCSNe, 37Cl is formed by the s-process both in massive stars and in AGB stars, and 35Cl may be produced from neutrino spallation. Understanding the formation of the Cl isotopes is also important to studies of the interstellar medium (ISM). A range of Cl isotope ratios mainly between 2 - 3.5 have been measured in star forming regions, in the circumstellar envelopes of evolved stars, and in proto-stellar cores using Cl bearing molecules. Additional measurements of the Cl isotope ratio in nearby stars will test nucleosynthesis models and allow comparisons with the range of isotope ratios observed in the ISM.We build on the results of Maas et al. (2016) by measuring the Cl isotope ratio in six M giants and four S stars using R~50,000 resolution spectra from Phoenix on Gemini South. We find no significant difference between the average Cl isotope ratios in the M stars and S stars and our measurements are consistent with the range of values seen in the ISM. We also find the average Cl ratio to be larger than the predicted isotope ratio of 1.8 for the solar neighborhood. Finally, two S stars, GG Pup and WY Pyx, show anomalously strong HCl features with equivalent widths ~3-5 times larger than the HCl features of other stars of

Hydrogen Isotopic Systematics of Nominally Anhydrous Phases in Martian Meteorites

NASA Astrophysics Data System (ADS)

Tucker, Kera

Hydrogen isotope compositions of the martian atmosphere and crustal materials can provide unique insights into the hydrological and geological evolution of Mars. While the present-day deuterium-to-hydrogen ratio (D/H) of the Mars atmosphere is well constrained (~6 times that of terrestrial ocean water), that of its deep silicate interior (specifically, the mantle) is less so. In fact, the hydrogen isotope composition of the primordial martian mantle is of great interest since it has implications for the origin and abundance of water on that planet. Martian meteorites could provide key constraints in this regard, since they crystallized from melts originating from the martian mantle and contain phases that potentially record the evolution of the H 2O content and isotopic composition of the interior of the planet over time. Examined here are the hydrogen isotopic compositions of Nominally Anhydrous Phases (NAPs) in eight martian meteorites (five shergottites and three nakhlites) using Secondary Ion Mass Spectrometry (SIMS). This study presents a total of 113 individual analyses of H2O contents and hydrogen isotopic compositions of NAPs in the shergottites Zagami, Los Angeles, QUE 94201, SaU 005, and Tissint, and the nakhlites Nakhla, Lafayette, and Yamato 000593. The hydrogen isotopic variation between and within meteorites may be due to one or more processes including: interaction with the martian atmosphere, magmatic degassing, subsolidus alteration (including shock), and/or terrestrial contamination. Taking into consideration the effects of these processes, the hydrogen isotope composition of the martian mantle may be similar to that of the Earth. Additionally, this study calculated upper limits on the H2O contents of the shergottite and nakhlite parent melts based on the measured minimum H2O abundances in their maskelynites and pyroxenes, respectively. These calculations, along with some petrogenetic assumptions based on previous studies, were subsequently used

Temporal evolution of the electric field accelerating electrons away from the auroral ionosphere.

PubMed

Marklund, G T; Ivchenko, N; Karlsson, T; Fazakerley, A; Dunlop, M; Lindqvist, P A; Buchert, S; Owen, C; Taylor, M; Vaivalds, A; Carter, P; André, M; Balogh, A

2001-12-13

The bright night-time aurorae that are visible to the unaided eye are caused by electrons accelerated towards Earth by an upward-pointing electric field. On adjacent geomagnetic field lines the reverse process occurs: a downward-pointing electric field accelerates electrons away from Earth. Such magnetic-field-aligned electric fields in the collisionless plasma above the auroral ionosphere have been predicted, but how they could be maintained is still a matter for debate. The spatial and temporal behaviour of the electric fields-a knowledge of which is crucial to an understanding of their nature-cannot be resolved uniquely by single satellite measurements. Here we report on the first observations by a formation of identically instrumented satellites crossing a beam of upward-accelerated electrons. The structure of the electric potential accelerating the beam grew in magnitude and width for about 200 s, accompanied by a widening of the downward-current sheet, with the total current remaining constant. The 200-s timescale suggests that the evacuation of the electrons from the ionosphere contributes to the formation of the downward-pointing magnetic-field-aligned electric fields. This evolution implies a growing load in the downward leg of the current circuit, which may affect the visible discrete aurorae.

Multiconfiguration calculations of electronic isotope shift factors in Al i

NASA Astrophysics Data System (ADS)

Filippin, Livio; Beerwerth, Randolf; Ekman, Jörgen; Fritzsche, Stephan; Godefroid, Michel; Jönsson, Per

2016-12-01

The present work reports results from systematic multiconfiguration Dirac-Hartree-Fock calculations of electronic isotope shift factors for a set of transitions between low-lying levels of neutral aluminium. These electronic quantities together with observed isotope shifts between different pairs of isotopes provide the changes in mean-square charge radii of the atomic nuclei. Two computational approaches are adopted for the estimation of the mass- and field-shift factors. Within these approaches, different models for electron correlation are explored in a systematic way to determine a reliable computational strategy and to estimate theoretical error bars of the isotope shift factors.

Radiogenic isotopic approaches for quantifying radionuclide transport (Invited)

NASA Astrophysics Data System (ADS)

Maher, K.; Depaolo, D. J.; Singleton, M. J.; Christensen, J. N.; Conrad, M. E.

2009-12-01

Naturally occurring variations in the isotopic compositions of U and Sr provide unique opportunities for assessing the fate and transport of radionuclides at field-scale conditions. When coupled with reactive transport models, U and Sr isotopes may also provide additional constraints on the rates of sediment-fluid or sediment-waste interactions. Such isotopic approaches can be useful for sites where subsurface characterization is complicated by a lack of accessibility or the presence of substantial heterogeneity. In addition, a variety of quantitative modeling approaches of different complexity can be used to evaluate experimentally determined parameters for radionuclide mobility at the field-scale. At the Hanford Site in eastern Washington, 87Sr/86Sr and 234U/238U ratios have been used to quantify the residence time of Sr and U in the unsaturated zone, the long-term background infiltration rate through the unsaturated zone, and to assess the influence of enhanced wastewater discharge on the regional unconfined aquifer. As a result of different processing techniques or due to interactions between caustic waste and the natural sediment, waste plumes may also inherit isotopic fingerprints (e.g. 234U/238U, 235U/238U, 236U/238U; δ15N & δ18O of nitrate) that can be used to resolve multiple sources of contamination. Finally, enriched isotopic tracers can be applied to experimental manipulations to assess the retardation of a variety of contaminants. Collectively this isotopic data contributes unique perspectives on both the hydrologic conditions across the site and the mobility of key radionuclides. Predicting the long-term fate and transport of radionuclides in the environment is often challenging due to natural heterogeneity and incomplete characterization of the subsurface, however detailed analysis of isotopic variations can provide one additional means of characterizing the subsurface.

Evolution of Nd and Pb isotopes in Central Pacific seawater from ferromanganese crusts

USGS Publications Warehouse

Ling, H.F.; Burton, K.W.; O'Nions, R. K.; Kamber, B.S.; Von Blanckenburg, F.; Gibb, A.J.; Hein, J.R.

1997-01-01

Hydrogenetic ferromanganese crusts incorporate elements from ambient seawater during their growth on seamounts. By analysing Nd, Pb and Be isotope profiles within crusts it is possible to reconstruct seawater tracer histories. Depth profiles of 10Be/9Be ratios in three Pacific ferromanganese crusts have been used to obtain growth rates which are between 1.4 and 3.8 mm/Ma. Nd and Pb isotopes provide intact records of isotopic variations in Pacific seawater over the last 20 Ma or more. There were only small changes in Pb isotope composition in the last 20 Ma. This indicates a constant Pb composition for the erosional sources and suggests further that erosional Nd inputs may have been uniform too. ??ND values vary considerably with time and most probably reflect changes in ocean circulation. The ??ND values of the crusts not only vary as a function of age but also as a function of water depth. From 25 to 0 Ma, crust VA13/2 from 4.8 km water depth has a similar pattern of ??ND variation to the two shallower crusts from 1.8 and 2.3 km, but about 1.0 to 1.5 units more negative. This suggests that ??ND stratification in Pacific seawater, as demonstrated for the present day, has been maintained for at least 20 Ma. Each crust shows a decrease in ??ND from 3-5 Ma to the present, which is interpreted in terms of an increase in the NADW component present in the Pacific. From 10 to 3-5 Ma ago the crusts show an increase in ??ND. This suggests a decreasing role for a deep water source with ??ND less than circum-Pacific sources. In this regard the Panamanian gateway restriction from ???10 Ma with final closure at 3-5 Ma may have played an important role in reducing access of Atlantic-derived Nd to the Pacific.

Carbon Isotope Chemistry in Molecular Clouds

NASA Technical Reports Server (NTRS)

Robertson, Amy N.; Willacy, Karen

2012-01-01

Few details of carbon isotope chemistry are known, especially the chemical processes that occur in astronomical environments like molecular clouds. Observational evidence shows that the C-12/C-13 abundance ratios vary due to the location of the C-13 atom within the molecular structure. The different abundances are a result of the diverse formation pathways that can occur. Modeling can be used to explore the production pathways of carbon molecules in an effort to understand and explain the chemical evolution of molecular clouds.

Sulphur isotope applications in two Philippine geothermal systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bayon, F.E.B.

1996-12-31

A general and very preliminary study of sulphur isotope geochemistry is presented in this paper. Data from the Mt. Apo and Palinpinon geothermal fields are used to demonstrate the use of sulphur isotopes in geothermometry and correlation of sulphur species. Sulphur and oxygen isotope geothermometers applied to Mt. Apo data show very good agreement with temperatures estimated using other established geothermometers, as well as bore measured temperatures. This signifies that sulphur isotopes in S-species in fluids of the Mt. Apo hydrothermal system are in equilibrium at drilled depths. In Palinpinon, on the other hand, temperature estimates from fluid and mineralmore » sulphur isotope geothermometry calculations do not agree with, and are commonly higher than, well measured temperatures and temperatures estimated from other geothermometers. Sulphur isotopes in the presently-exploited Palinpinon fluid are not in equilibrium, and sulphur isotope geothermometry may be reflective of isotopic equilibrium of the deeper portions of the hydrothermal system. Dissolved sulphate in both the Palinpinon and Mt. Apo geothermal fluids appear to originate from the disproportionation of magmatic SO{sub 2} at temperatures below 400{degrees}C. Hydrogen sulphide in well discharge fluids are dominantly directly derived from the magma, with a minor amount coming from SO{sub 2} disproportionation.« less

Fundamental studies on kinetic isotope effect (KIE) of hydrogen isotope fractionation in natural gas systems

USGS Publications Warehouse

Ni, Y.; Ma, Q.; Ellis, G.S.; Dai, J.; Katz, B.; Zhang, S.; Tang, Y.

2011-01-01

Based on quantum chemistry calculations for normal octane homolytic cracking, a kinetic hydrogen isotope fractionation model for methane, ethane, and propane formation is proposed. The activation energy differences between D-substitute and non-substituted methane, ethane, and propane are 318.6, 281.7, and 280.2cal/mol, respectively. In order to determine the effect of the entropy contribution for hydrogen isotopic substitution, a transition state for ethane bond rupture was determined based on density function theory (DFT) calculations. The kinetic isotope effect (KIE) associated with bond rupture in D and H substituted ethane results in a frequency factor ratio of 1.07. Based on the proposed mathematical model of hydrogen isotope fractionation, one can potentially quantify natural gas thermal maturity from measured hydrogen isotope values. Calculated gas maturity values determined by the proposed mathematical model using ??D values in ethane from several basins in the world are in close agreement with similar predictions based on the ??13C composition of ethane. However, gas maturity values calculated from field data of methane and propane using both hydrogen and carbon kinetic isotopic models do not agree as closely. It is possible that ??D values in methane may be affected by microbial mixing and that propane values might be more susceptible to hydrogen exchange with water or to analytical errors. Although the model used in this study is quite preliminary, the results demonstrate that kinetic isotope fractionation effects in hydrogen may be useful in quantitative models of natural gas generation, and that ??D values in ethane might be more suitable for modeling than comparable values in methane and propane. ?? 2011 Elsevier Ltd.

The effect of strobilurins on leaf gas exchange, water use efficiency and ABA content in grapevine under field conditions.

PubMed

Diaz-Espejo, Antonio; Cuevas, María Victoria; Ribas-Carbo, Miquel; Flexas, Jaume; Martorell, Sebastian; Fernández, José Enrique

2012-03-01

Strobilurins are one of the most important classes of agricultural fungicides. In addition to their anti-fungal effect, strobilurins have been reported to produce simultaneous effects in plant physiology. This study investigated whether the use of strobilurin fungicide improved water use efficiency in leaves of grapevines grown under field conditions in a Mediterranean climate in southern Spain. Fungicide was applied three times in the vineyard and measurements of leaf gas exchange, plant water status, abscisic acid concentration in sap ([ABA]), and carbon isotope composition in leaves were performed before and after applications. No clear effect on stomatal conductance, leaf water potential and intrinsic water use efficiency was found after three fungicide applications. ABA concentration was observed to increase after fungicide application on the first day, vanishing three days later. Despite this transient effect, evolution of [ABA] matched well with the evolution of leaf carbon isotope ratio, which can be used as a surrogate for plant water use efficiency. Morning stomatal conductance was negatively correlated to [ABA]. Yield was enhanced in strobilurin treated plants, whereas fruit quality remained unaltered. Published by Elsevier GmbH.

Reflections on the Evolution of Higher Education as a Field of Study in Canada

ERIC Educational Resources Information Center

Jones, Glen A.

2012-01-01

This paper provides a reflective analysis of the evolution of higher education as a field of scholarship in Canada. The first professors of higher education in Canada were appointed in the mid-1960s and, by the early-1970s, a small higher-education research community had emerged, with the creation of a national association and a scholarly journal.…

Future evolution in a backreaction model and the analogous scalar field cosmology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ali, Amna; Majumdar, A.S., E-mail: amnaalig@gmail.com, E-mail: archan@bose.res.in

We investigate the future evolution of the universe using the Buchert framework for averaged backreaction in the context of a two-domain partition of the universe. We show that this approach allows for the possibility of the global acceleration vanishing at a finite future time, provided that none of the subdomains accelerate individually. The model at large scales is analogously described in terms of a homogeneous scalar field emerging with a potential that is fixed and free from phenomenological parametrization. The dynamics of this scalar field is explored in the analogous FLRW cosmology. We use observational data from Type Ia Supernovae,more » Baryon Acoustic Oscillations, and Cosmic Microwave Background to constrain the parameters of the model for a viable cosmology, providing the corresponding likelihood contours.« less

A theoretical model and phase field simulation on the evolution of interface roughness in the oxidation process

NASA Astrophysics Data System (ADS)

Yang, Fan; Fang, Dai-Ning; Liu, Bin

2012-01-01

An oxidation kinetics model is developed to account for the effects of the oxidation interface curvature and the oxidation-induced volume change or Pilling-Bedworth ratio. For the oxidation of Fe-Cr-Al-Y alloy fiber, the predictions agree well with experimental results. By considering the influence of the oxidation interface curvature on oxidation rates, the evolution of fluctuant oxidation interface is predicted. We also developed the phase field method (PFM) to simulate the evolution of the interface roughness. Both the theoretical model and the PFM results show that the interface will become smooth during high temperature oxidation. Stress distribution and evolution are calculated by PFM, which indicates that the stress level decreases as the interface morphology evolves.

Evaluating the skills of isotope-enabled general circulation models against in situ atmospheric water vapor isotope observations

NASA Astrophysics Data System (ADS)

Steen-Larsen, H. C.; Risi, C.; Werner, M.; Yoshimura, K.; Masson-Delmotte, V.

2017-01-01

The skills of isotope-enabled general circulation models are evaluated against atmospheric water vapor isotopes. We have combined in situ observations of surface water vapor isotopes spanning multiple field seasons (2010, 2011, and 2012) from the top of the Greenland Ice Sheet (NEEM site: 77.45°N, 51.05°W, 2484 m above sea level) with observations from the marine boundary layer of the North Atlantic and Arctic Ocean (Bermuda Islands 32.26°N, 64.88°W, year: 2012; south coast of Iceland 63.83°N, 21.47°W, year: 2012; South Greenland 61.21°N, 47.17°W, year: 2012; Svalbard 78.92°N, 11.92°E, year: 2014). This allows us to benchmark the ability to simulate the daily water vapor isotope variations from five different simulations using isotope-enabled general circulation models. Our model-data comparison documents clear isotope biases both on top of the Greenland Ice Sheet (1-11‰ for δ18O and 4-19‰ for d-excess depending on model and season) and in the marine boundary layer (maximum differences for the following: Bermuda δ18O = 1‰, d-excess = 3‰; South coast of Iceland δ18O = 2‰, d-excess = 5‰; South Greenland δ18O = 4‰, d-excess = 7‰; Svalbard δ18O = 2‰, d-excess = 7‰). We find that the simulated isotope biases are not just explained by simulated biases in temperature and humidity. Instead, we argue that these isotope biases are related to a poor simulation of the spatial structure of the marine boundary layer water vapor isotopic composition. Furthermore, we specifically show that the marine boundary layer water vapor isotopes of the Baffin Bay region show strong influence on the water vapor isotopes at the NEEM deep ice core-drilling site in northwest Greenland. Our evaluation of the simulations using isotope-enabled general circulation models also documents wide intermodel spatial variability in the Arctic. This stresses the importance of a coordinated water vapor isotope-monitoring network in order to discriminate amongst these model

General relativistic treatment of the thermal, magnetic and rotational evolution of isolated neutron stars with crustal magnetic fields

NASA Astrophysics Data System (ADS)

Page, D.; Geppert, U.; Zannias, T.

2000-08-01

We investigate the thermal, magnetic and rotational evolution of isolated neutron stars assuming that the dipolar magnetic field is confined to the crust. Our treatment, for the first time, uses a fully general relativistic formalism not only for the thermal but also for the magnetic part, and includes partial general relativistic effects in the rotational part. Due to the fact that the combined evolution depends crucially upon the compactness of the star, three different equations of state have been employed in the calculations. In the absence of general relativistic effects, while upon increasing compactness a decrease of the crust thickness takes place leading into an accelerating field decay, the inclusion of general relativistic effects intend to "decelerate this acceleration". As a consequence we find that, within the crustal field hypothesis, a given equation of state is compatible with the observed distribution of pulsar periods P and period derivative &mathaccent "705Frelax dot; provided the initial field strength and current location as well as the magnitude of the impurity content are appropriately constrained. Finally, we access the flexibility of the soft, medium and stiff classes of equations of state as candidates in describing the state of the matter in the neutron star interiors. The comparison of our model calculations with observations, together with the consideration of independent information about neutron star evolution, suggests that a not too soft equation of state describes neutron star interiors and its cooling proceeds along the `standard' scenario.

Paleogene Seawater Osmium Isotope Records

NASA Astrophysics Data System (ADS)

Rolewicz, Z.; Thomas, D. J.; Marcantonio, F.

2012-12-01

Paleoceanographic reconstructions of the Late Cretaceous and early Cenozoic require enhanced geographic coverage, particularly in the Pacific, in order to better constrain meridional variations in environmental conditions. The challenge with the existing inventory of Pacific deep-sea cores is that they consist almost exclusively of pelagic clay with little existing age control. Pelagic clay sequences are useful for reconstructions of dust accumulation and water mass composition, but accurate correlation of these records to other sites requires improved age control. Recent work indicates that seawater Os isotope analyses provide useful age control for red clay sequences. The residence time of Os in seawater is relatively long compared to oceanic mixing, therefore the global seawater 187Os/188Os composition is practically homogeneous. A growing body of Late Cretaceous and Cenozoic data has constrained the evolution of the seawater Os isotopic composition and this curve is now a viable stratigraphic tool, employed in dating layers of Fe-Mn crusts (e.g., Klemm et al., 2005). Ravizza (2007) also demonstrated that the seawater Os isotopic composition can be extracted reliably from pelagic red clay sediments by analyzing the leached oxide minerals. The drawback to using seawater Os isotope stratigraphy to date Paleogene age sediments is that the compilation of existing data has some significant temporal gaps, notably between ~38 and 55 Ma. To improve the temporal resolution of the seawater Os isotope curve, we present new data from Ocean Drilling Program (ODP) Site 865 in the equatorial Pacific. Site 865 has excellent biostratigraphic age control over the interval ~38-55Ma. Preliminary data indicate an increase in the seawater composition from 0.427 at 53.4 Ma to 0.499 by 43 Ma, consistent with the apparent trend in the few existing data points. We also analyzed the Os isotopic composition recorded by oxide minerals at Integrated Ocean Drilling Program (IODP) Site U1370

Isotopic tracing of perchlorate in the environment

USGS Publications Warehouse

Sturchio, Neil C.; Böhlke, John Karl; Gu, Baohua; Hatzinger, Paul B.; Jackson, W. Andrew; Baskaran, Mark

2012-01-01

Isotopic measurements can be used for tracing the sources and behavior of environmental contaminants. Perchlorate (ClO 4 − ) has been detected widely in groundwater, soils, fertilizers, plants, milk, and human urine since 1997, when improved analytical methods for analyzing ClO 4 −concentration became available for routine use. Perchlorate ingestion poses a risk to human health because of its interference with thyroidal hormone production. Consequently, methods for isotopic analysis of ClO 4 − have been developed and applied to assist evaluation of the origin and migration of this common contaminant. Isotopic data are now available for stable isotopes of oxygen and chlorine, as well as 36Cl isotopic abundances, in ClO 4 − samples from a variety of natural and synthetic sources. These isotopic data provide a basis for distinguishing sources of ClO 4 − found in the environment, and for understanding the origin of natural ClO 4 − . In addition, the isotope effects of microbial ClO 4 − reduction have been measured in laboratory and field experiments, providing a tool for assessing ClO 4 − attenuation in the environment. Isotopic data have been used successfully in some areas for identifying major sources of ClO 4 − contamination in drinking water supplies. Questions about the origin and global biogeochemical cycle of natural ClO 4 − remain to be addressed; such work would benefit from the development of methods for preparation and isotopic analysis of ClO 4 − in samples with low concentrations and complex matrices.

Regional hydrology of the Dixie Valley geothermal field, Nevada: preliminary interpretations of chemical and isotopic data

USGS Publications Warehouse

Nimz, Gregory; Janik, Cathy; Goff, Fraser; Dunlap, Charles; Huebner, Mark; Counce, Dale; Johnson, Stuart D.

1999-01-01

Chemical and isotopic analyses of Dixie Valley regional waters indicated several distinct groups ranging in recharge age from Pleistocene (1000a). Geothermal field fluids (~12-14 ka) appear derived from water similar in composition to non thermal groundwater observed today in valley artesian well (also ~14 ka). Geothermal fluid interaction with mafic rocks (Humboldt Lopolith) appears to be common, and significant reaction with granodiorite may also occur. Despite widespread occurrence of carbonate rocks, large scale chemical interaction appears minor. Age asymmetry of the range, more extensive interaction with deep seated waters in the west, and distribution of springs and artesian wells suggest the existence of a regional upward hydrologic gradient with an axis in proximity to the Stillwater range.

Nitrogen isotope ratio and its evolution on Titan

NASA Astrophysics Data System (ADS)

Krasnopolsky, V.

2017-09-01

14N/15N ratios in the Sun, Jupiter, comets, and the inner planets indicate that Earth, Venus, and Mars got their nitrogen as N2 gas and NH3 ice in proportion 3 : 1. An alternative explanation is that planetesimals were another reservoir of N with 14N/15N = 270. 14N/15N = 168 in N2 and 60 in HCN on Titan, and the great difference is explained by strong enrichment in 15N by a factor of 8 in predissociation of N2 at 80-100 nm (Liang et al. 2007) and no fractionation in other 12 processes that form N. The calculated 14N/15N = 57 in nitriles, in perfect agreement with the observations. Modeling of nitrogen isotope fractionation by formation of nitriles and sputtering through the history of Titan with the much greater solar EUV and wind in the earlier epochs supports ammonia similar to that in comets as a source of nitrogen on Titan.

An evaporite-based high-resolution sulfur isotope record of Late Permian and Triassic seawater sulfate

NASA Astrophysics Data System (ADS)

Bernasconi, Stefano M.; Meier, Irene; Wohlwend, Stephan; Brack, Peter; Hochuli, Peter A.; Bläsi, Hansruedi; Wortmann, Ulrich G.; Ramseyer, Karl

2017-05-01

Variations in the sulfur isotope composition of dissolved marine sulfate through time reflect changes in the global sulfur cycle and are intimately related to changes in the carbon and oxygen cycles. A large shift in the sulfur isotope composition of sulfate at the Permian/Triassic boundary has been recognized for long time and a number of studies were carried out to understand the causes and significance of this shift. However, data for the Middle and Late Triassic are very sparse and the stratigraphic evolution of the sulfur isotope composition of seawater is poorly constrained due to the small number of samples analyzed and/or due to the limited stratigraphic intervals studied. Moreover, in the last few years the Triassic timescale has significantly changed due to a wealth of new radiometric and stratigraphic data. In this study we show that for the Late Permian and the Triassic it is possible to obtain a precise reconstruction of the evolution of the sulfur cycle, for parts of it at sub-million year resolution, by analyzing exclusively gypsum and anhydrite deposits. We base our reconstruction on new data from the Middle and Late Triassic evaporites of Northern Switzerland and literature data from evaporites from Germany, Austria, Italy and the Middle East. We propose a revised correlation between the well-dated marine Tethyan sections in northern Italy and the evaporites from Northern Switzerland and from the Germanic Basin calibrated to the newest radiometric absolute age scale. This new correlation allows for a precise dating of the evaporites and constructing a composite sulfur isotope evolution of seawater sulfate from the latest Permian (Lopingian Epoch) to the Norian. We show that a rapid positive shift of approximately 24‰ at the Permian-Triassic boundary can be used to constrain seawater sulfate concentrations in the range of 2-6 mM, thus higher than previous estimates but with less rapid changes. Finally, we discuss two possible evolution scenarios

Potential energy surfaces of Polonium isotopes

NASA Astrophysics Data System (ADS)

Nerlo-Pomorska, B.; Pomorski, K.; Schmitt, C.; Bartel, J.

2015-11-01

The evolution of the potential energy landscape is analysed in detail for ten even-even polonium isotopes in the mass range 188\\lt A\\lt 220 as obtained within the macroscopic-microscopic approach, relying on the Lublin-Strasbourg drop model and the Yukawa-folded single-particle energies for calculating the microscopic shell and pairing corrections. A variant of the modified Funny-Hills nuclear shape parametrization is used to efficiently map possible fission paths. The approach explains the main features of the fragment partition as measured in low-energy fission along the polonium chain. The latter lies in a transitional region of the nuclear chart, and will be essential to consistently understand the evolution of fission properties from neutron-deficient mercury to heavy actinides. The ability of our method to predict fission observables over such an extended region looks promising.

What Mantle Processes Determine Isotopic

NASA Astrophysics Data System (ADS)

Tackley, P. J.; Xie, S.

2003-12-01

Isotopic measurements on Mid Ocean Ridge Basalts and Ocean Island Basalts indicate effective `ages' (from e.g., U-Pb or Sm-Nd systems) in the range 1-2 billion years- much less than the age of the Earth, even though melting should have been much more vigorous early on and skewed the mean time since melting to older values. This relatively young `age' has generally been explained in terms of stretching of heterogeneities by mantle convection, which might reduce them to dimensions too small to be individually distinguishable in short timescales of less than 1 Gyr. On the other hand, published numerical models that use tracers to track differentiated material (Christensen and Hofmann, 1994, Davies, 2002) suggest that Earth-like `ages' can be obtained without taking stretching-induced erasure of tracer signatures into account, although this might effectively happen if the lengthscale for sampling the isotope systems was large enough. In those models, the only explicit mechanism for resetting isotope systems was re-melting, but for this to explain the isotopic ages observed for basalts, the global rate of melting in the recent past would have had to be very much higher than present-day values. To investigate stretching vs. re-melting we have conducted numerical experiments of a cooling mantle with plate tectonics, differentiation and evolution of important isotopic systems. The time of last melting and the total strain is tracked on each tracer (in addition to isotopic information). The results confirm that a model matching today's crustal production rate and with a reasonable secular cooling history generates `ages' that are substantially larger than those observed, with the extent of crustal settling above the CMB making some difference but not enough. The effect of sampling lengthscale on observed `age' is also tested and found to be insufficient to explain the data. Thus, these results reaffirm the importance of stretching as a key mechanism for effectively deleting

Use of Field-Based Stable Isotope Probing To Identify Adapted Populations and Track Carbon Flow through a Phenol-Degrading Soil Microbial Community

PubMed Central

DeRito, Christopher M.; Pumphrey, Graham M.; Madsen, Eugene L.

2005-01-01

The goal of this field study was to provide insight into three distinct populations of microorganisms involved in in situ metabolism of phenol. Our approach measured 13CO2 respired from [13C]phenol and stable isotope probing (SIP) of soil DNA at an agricultural field site. Traditionally, SIP-based investigations have been subject to the uncertainties posed by carbon cross-feeding. By altering our field-based, substrate-dosing methodologies, experiments were designed to look beyond primary degraders to detect trophically related populations in the food chain. Using gas chromatography-mass spectrometry (GC/MS), it was shown that 13C-labeled biomass, derived from primary phenol degraders in soil, was a suitable growth substrate for other members of the soil microbial community. Next, three dosing regimes were designed to examine active members of the microbial community involved in phenol metabolism in situ: (i) 1 dose of [13C]phenol, (ii) 11 daily doses of unlabeled phenol followed by 1 dose of [13C]phenol, and (iii) 12 daily doses of [13C]phenol. GC/MS analysis demonstrated that prior exposure to phenol boosted 13CO2 evolution by a factor of 10. Furthermore, imaging of 13C-treated soil using secondary ion mass spectrometry (SIMS) verified that individual bacteria incorporated 13C into their biomass. PCR amplification and 16S rRNA gene sequencing of 13C-labeled soil DNA from the 3 dosing regimes revealed three distinct clone libraries: (i) unenriched, primary phenol degraders were most diverse, consisting of α-, β-, and γ-proteobacteria and high-G+C-content gram-positive bacteria, (ii) enriched primary phenol degraders were dominated by members of the genera Kocuria and Staphylococcus, and (iii) trophically related (carbon cross-feeders) were dominated by members of the genus Pseudomonas. These data show that SIP has the potential to document population shifts caused by substrate preexposure and to follow the flow of carbon through terrestrial microbial food

Evolution of magnetic fields in collapsing star-forming clouds under different environments

NASA Astrophysics Data System (ADS)

Higuchi, Koki; Machida, Masahiro N.; Susa, Hajime

2018-04-01

In nearby star-forming clouds, amplification and dissipation of the magnetic field are known to play crucial roles in the star-formation process. The star-forming environment varies from place to place and era to era in galaxies. In this study, amplification and dissipation of magnetic fields in star-forming clouds are investigated under different environments using magnetohydrodynamics (MHD) simulations. We consider various star-forming environments in combination with the metallicity and the ionization strength, and prepare prestellar clouds having two different mass-to-flux ratios. We calculate the cloud collapse until protostar formation using ideal and non-ideal (inclusion and exclusion of ohmic dissipation and ambipolar diffusion) MHD calculations to investigate the evolution of the magnetic field. We perform 288 runs in total and show the diversity of the density range within which the magnetic field effectively dissipates, depending on the environment. In addition, the dominant dissipation process (Ohmic dissipation or ambipolar diffusion) is shown to strongly depend on the star-forming environment. Especially, for the primordial case, magnetic field rarely dissipates without ionization source, while it efficiently dissipates when very weak ionization sources exist in the surrounding environment. The results of this study help to clarify star formation in various environments.

Multiple Nebular Gas Reservoirs Recorded by Oxygen Isotope Variation in a Spinel-rich CAI in CO3 MIL 090019

NASA Technical Reports Server (NTRS)

Simon, J. I.; Simon, S. B.; Nguyen, A. N.; Ross, D. K.; Messenger, S.

2017-01-01

We conducted NanoSIMS O-isotopic imaging of a primitive spinel-rich CAI spherule (27-2) from the MIL 090019 CO3 chondrite. Inclusions such as 27-2 are proposed to record inner nebula processes during an epoch of rapid solar nebula evolution. Mineralogical and textural analyses suggest that this CAI formed by high temperature reactions, partial melting, and condensation. This CAI exhibits radial O-isotopic heterogeneity among multiple occurrences of the same mineral, reflecting interactions with distinct nebular O-isotopic reservoirs.

In Situ Missions For Investigation of the Climate, Geology and Evolution of Venus

NASA Astrophysics Data System (ADS)

Grinspoon, David

2017-10-01

In situ Exploration of Venus has been recommended by the Decadal Study of the National Research Council. Many high priority measurements, addressing outstanding first-order, fundamental questions about current processes and evolution of Venus can only be made from in situ platforms such as entry probes, balloons or landers. These include: measuring noble gases and their isotopes to constrain origin and evolution; measuring stable isotopes to constrain the history of water and other volatiles; measuring trace gas profiles and sulfur compounds for chemical cycles and surface-atmosphere interactions, constraining the coupling of radiation, dynamics and chemistry, making visible and infrared descent images, and measuring surface and sub-surface composition. Such measurements will allow us deepen our understanding of the origin and evolution of Venus in the context of the terrestrial planets and extrasolar planets, to determine the level and style of current geological activity and to characterize the divergent climate evolution of Venus and Earth and extend our knowledge of the limits of habitability on hot terrestrial planets.

Stable isotope evidence for an amphibious phase in early proboscidean evolution.

PubMed

Liu, Alexander G S C; Seiffert, Erik R; Simons, Elwyn L

2008-04-15

The order Proboscidea includes extant elephants and their extinct relatives and is closely related to the aquatic sirenians (manatees and dugongs) and terrestrial hyracoids (hyraxes). Some analyses of embryological, morphological, and paleontological data suggest that proboscideans and sirenians shared an aquatic or semiaquatic common ancestor, but independent tests of this hypothesis have proven elusive. Here we test the hypothesis of an aquatic ancestry for advanced proboscideans by measuring delta(18)O in tooth enamel of two late Eocene proboscidean genera, Barytherium and Moeritherium, which are sister taxa of Oligocene-to-Recent proboscideans. The combination of low delta(18)O values and low delta(18)O standard deviations in Barytherium and Moeritherium matches the isotopic pattern seen in aquatic and semiaquatic mammals, and differs from that of terrestrial mammals. delta(13)C values of these early proboscideans suggest that both genera are likely to have consumed freshwater plants, although a component of C(3) terrestrial vegetation cannot be ruled out. The simplest explanation for the combined evidence from isotopes, dental functional morphology, and depositional environments is that Barytherium and Moeritherium were at least semiaquatic and lived in freshwater swamp or riverine environments, where they grazed on freshwater vegetation. These results lend new support to the hypothesis that Oligocene-to-Recent proboscideans are derived from amphibious ancestors.

Magnesium isotopic evidence for chemical disequilibrium among cumulus minerals in layered mafic intrusion

NASA Astrophysics Data System (ADS)

Chen, Lie-Meng; Teng, Fang-Zhen; Song, Xie-Yan; Hu, Rui-Zhong; Yu, Song-Yue; Zhu, Dan; Kang, Jian

2018-04-01

Magnesium isotopic compositions of olivine, clinopyroxene, and ilmenite from the Baima intrusion, SW China, for the first time, are investigated to constrain the magnitude and mechanisms of Mg isotope fractionation among cumulus minerals in layered mafic intrusions and to evaluate their geological implications. Olivine and clinopyroxene have limited Mg isotope variations, with δ26Mg ranging from -0.33 to +0.05‰ and from -0.29 to -0.13‰, respectively, similar to those of mantle xenolithic peridotites. By contrast, ilmenites display extremely large Mg isotopic variation, with δ26Mg ranging from -0.50 to +1.90‰. The large inter-mineral fractionations of Mg isotopes between ilmenite and silicates may reflect both equilibrium and kinetic processes. A few ilmenites have lighter Mg isotopic compositions than coexisting silicates and contain high MgO contents without compositional zoning, indicating equilibrium fractionation. The implication is that the light Mg isotopic compositions of lunar high-Ti basalts may result from an isotopically light source enriched in cumulate ilmenites. On the other hand, most ilmenites have heavy Mg isotopic compositions, coupled with high MgO concentration and chemical zoning, which can be quantitatively modeled by kinetic Mg isotope fractionations induced by subsolidus Mg-Fe exchange between ilmenite and ferromagnesian silicates during the cooling of the Baima intrusion. The extensive occurrence of kinetic Mg isotope fractionation in ilmenites implies the possibility of widespread compositional disequilibrium among igneous minerals in magma chambers. Consequently, disequilibrium effects need to be considered in studies of basaltic magma evolution, magma chamber processes, and magmatic Fe-Ti oxide ore genesis.

Conceptualisation of Snowpack Isotope Dynamics in Spatially Distributed Tracer-Aided Runoff Models in Snow Influenced Northern Cathments

NASA Astrophysics Data System (ADS)

Ala-aho, P. O. A.; Tetzlaff, D.; Laudon, H.; McNamara, J. P.; Soulsby, C.

2016-12-01

We use the Spatially distributed Tracer-Aided Rainfall-Runoff (STARR) modelling framework to explore non-stationary flow and isotope response in three northern headwater catchments. The model simulates dynamic, spatially variable tracer concentration in different water stores and fluxes within a catchment, which can constrain internal catchment mixing processes, flow paths and associated water ages. To date, a major limitation in using such models in snow-dominated catchments has been the difficulties in paramaterising the isotopic transformations in snowpack accumulation and melt. We use high quality long term datasets for hydrometrics and stable water isotopes collected in three northern study catchments for model calibration and testing. The three catchments exhibit different hydroclimatic conditions, soil and vegetation types, and topographic relief, which brings about variable degree of snow dominance across the catchments. To account for the snow influence we develop novel formulations to estimate the isotope evolution in the snowpack and melt. Algorithms for the isotopic evolution parameterize an isotopic offset between snow evaporation and melt fluxes and the remaining snow storage. The model for each catchment is calibrated to match both streamflow and tracer concentration at the stream outlet to ensure internal consistency of the system behaviour. The model is able to reproduce the streamflow along with the spatio-temporal differences in tracer concentrations across the three studies catchments reasonably well. Incorporating the spatially distributed snowmelt processes and associated isotope transformations proved essential in capturing the stream tracer reponse for strongly snow-influenced cathments. This provides a transferrable tool which can be used to understand spatio-temporal variability of mixing and water ages for different storages and flow paths in other snow influenced, environments.

Chromium isotope fractionation in ferruginous sediments

NASA Astrophysics Data System (ADS)

Bauer, Kohen W.; Gueguen, Bleuenn; Cole, Devon B.; Francois, Roger; Kallmeyer, Jens; Planavsky, Noah; Crowe, Sean A.

2018-02-01

Ferrous Fe is a potent reductant of Cr(VI), and while a number of laboratory studies have characterized Cr isotope fractionation associated with Cr(VI) reduction by ferrous iron, the expression of this fractionation in real-world ferrous Fe-rich environments remains unconstrained. Here we determine the isotope fractionation associated with Cr(VI) reduction in modern ferrous Fe-rich sediments obtained from the previously well studied Lake Matano, Indonesia. Whole core incubations demonstrate that reduction of Cr(VI) within ferruginous sediments provides a sink for Cr(VI) leading to Cr(VI) concentration gradients and diffusive Cr(VI) fluxes across the sediment water interface. As reduction proceeded, Cr(VI) remaining in the overlying lake water became progressively enriched in the heavy isotope (53Cr), increasing δ53Cr by 2.0 ± 0.1‰ at the end of the incubation. Rayleigh distillation modelling of the evolution of Cr isotope ratios and Cr(VI) concentrations in the overlying water yields an effective isotope fractionation of εeff = 1.1 ± 0.2‰ (53Cr/52Cr), whereas more detailed diagenetic modelling implies an intrinsic isotope fractionation of εint = 1.80 ± 0.04‰. Parallel slurry experiments performed using anoxic ferruginous sediment yield an intrinsic isotope fractionation of εint = 2.2 ± 0.1‰. These modelled isotope fractionations are corroborated by direct measurement of the δ53Cr composition on the upper 0.5 cm of Lake Matano sediment, revealing an isotopic offset from the lake water of Δ53Cr = 0.21-1.81‰. The data and models reveal that effective isotope fractionations depend on the depth at which Cr(VI) reduction takes place below the sediment water interface-the deeper the oxic non-reactive zone, the smaller the effective fractionation relative to the intrinsic fractionation. Based on the geochemistry of the sediment we suggest the electron donors responsible for reduction are a combination of dissolved Fe(II) and 0.5 M HCl extractable (solid

Multiple S and O isotope constraints on O2 at 2.25 Ga

NASA Astrophysics Data System (ADS)

Killingsworth, B.; Sansjofre, P.; Philippot, P.; Thomazo, C.; Cartigny, P.; Lalonde, S.

2017-12-01

The composition of Earth's atmosphere around the time of the Great Oxidation Event (GOE) at the Archean-Proterozoic boundary is of great interest for reconstructing the redox evolution of the Earth. Sulfate has been shown to be a valuable recorder of isotopic signals of atmospheric O2 but its records are sparse around the time of the GOE. To constrain O2 around the GOE, we have measured quadruple sulfur and triple oxygen isotopes of sulfate from barite in sedimentary drill core from the Turee Creek Group, Australia from 2.25 Ga. A combined sulfur and oxygen approach for estimating the triple oxygen isotope composition of O2 at 2.25 Ga will be presented and its implications for the Paleoproterozoic atmosphere will be discussed.

Petrography of isotopically-dated clasts in the Kapoeta howardite and petrologic constraints on the evolution of its parent body

NASA Technical Reports Server (NTRS)

Dymek, R. F.; Albee, A. L.; Chodos, A. A.; Wasserburg, G. J.

1976-01-01

Results are presented for petrographic and electron microprobe studies of the isotopically dated A, B, C, and rho basaltic rock fragments separated from the howardite Kapoeta. Other lithic clasts and numerous mineral fragments in thin sections of Kapoeta are investigated in order to outline the range in lithology and chemistry of the source materials from which the Kapoeta meteorite is derived. The data obtained are compared to those from other meteorite and lunar samples, with particular reference to the observational consequences for the evolution of the Kapoeta parent body. A major conclusion is that there is no clearcut evidence for young magmatism on the Kapoeta parent body. The observations preclude the interpretation that the Kapoeta is a simple mixture of eucrites and diogenites. In contrast to the moon, a source of anorthositic rocks does not appear to have been present on the Kapoeta parent body which involved chiefly pyroxene. The FeO-MnO relationships suggest that the source of the materials in the Kapoeta parent planet are fundamentally related.

Thermal-field propagation in an exocontact zone of a magmatic body and its impact on radiogenic isotope concentrations in minerals.

PubMed

Brandt, I S; Rasskazov, S V; Brandt, S B; Ivanov, A V

2002-03-01

In application of radioactive isotope systems (K-Ar, Rb-Sr etc.) during the last decades, experience was gained not only on their geochronometrical uses, but also on estimations of some important parameters of geological processes, especially temperatures and durations of superimposed thermal events. In this paper, the formation of an exocontact thermal field of a magmatic intrusion is considered as a spreading of a thermal source delta-function. Appropriate solutions of the heat-transfer equation are deduced and correlated with diffusion parameters of the radiogenic argon, coupling radioactive, thermal and kinetic parameters in an exocontant zone of a magmatic body. These solutions were used for quantitative reinterpretations of data taken from Hart's classical paper [The petrology and isotopic mineral age relations of a contact zone in the Front Range, Colorado. J. Geol., 1964, v. 72, pp. 493-525]. Theoretic and measured radiogenic argon and strontium concentrations within exocontact aureoles are found to be in good concordance.

Multi-Phase Field Models and Microstructural Evolution with Applications in Fuel Cell Technology

NASA Astrophysics Data System (ADS)

Davis, Ryan Scott

The solid oxide fuel cell (SOFC) has shown tremendous potential as an efficient energy conversion device that may be instrumental in the transition to renewable resources. However, commercialization is hindered by many degradation mechanisms that plague long term stability. In this dissertation, computation methods are used to explore the relationship between the microstructure of the fuel cell anode and performance critical metrics. The phase field method and standard modeling procedures are introduced using a classic model of spinodal decomposition. This is further developed into a complete, multi-phase modeling framework designed for the complex microstructural evolution of SOFC anode systems. High-temperature coarsening of the metallic phase in the state-of-the-art SOFC cermet anode is investigated using our phase field model. A systematic study into the effects of interface properties on microstructural evolution is accomplished by altering the contact angle between constituent phases. It is found that metrics of catalytic activity and conductivity display undesirable minima near the contact angle of conventional SOFC materials. These results suggest that tailoring the interface properties of the constituent phases could lead to a significant increase in the performance and lifetime of SOFCs. Supported-metal catalyst systems are investigated in the first detailed study of their long-term stability and application to SOFC anode design. Porous support structures are numerically sintered to mimic specific fabrication techniques, and these structures are then infiltrated with a nanoscale catalyst phase ranging from 2% to 21% loading. Initially, these systems exhibit enhanced potential for catalytic activity relative to conventional cells. However, extended evolution results in severe degradation, and we show that Ostwald ripening and particle migration are key kinetic processes. Strong geometric heterogeneity in the support structure via a novel approach to

Marked spatial gradient in the topographic evolution of the Andes spanning the Chilean flat-slab transition: evidence from stable isotope paleoaltimetry and zircon double dating

NASA Astrophysics Data System (ADS)

Hoke, G. D.; McPhillips, D. F.; Giambiagi, L.; Garzione, C. N.; Mahoney, J. B.; Strecker, M. R.

2015-12-01

The major changes in the subduction angle of the Nazca plate are often hypothesized to have important consequences for the tectonic evolution of the Andes. Temporal and spatial patterns of topographic growth and exhumation are indicators that should help elucidate any linkages to subduction angle. Here, we combine observations from stable isotope paleoaltimetry with detrital zircon double dating between 30 and 35°S to demonstrate a consistent increase in surface and rock uplift in the Andes south of 32°S. The stable isotope data are from Miocene pedogenic carbonates collected from seven different basin sequences spanning different tectonic and topographic positions in the range. Paleoelevations between 1 km and 1.9 km are calculated using modern local isotope-elevation gradients along with carbonate-formation temperatures determined from clumped isotope studies in modern soils. Present day, low elevation foreland localities were at their present elevations during the Miocene, while three of the intermontane basins experienced up to 2 km of surface uplift between the end of deposition during the late Miocene and present. Detrital zircon (U-Th-Sm)/He and U-Pb double dating in three modern drainage basins (Tunuyán, Arroyo Grande and Río de los Patos) reveals clear Miocene exhumation signals south of the flat slab with no recent exhumation apparent at 32°S. The exhumation pattern is consistent with paleoaltimetry results. Interestingly, the maximum inferred surface uplift is greatest where the crust is thinnest, and the timing of the observed changes in elevation and exhumation has not been linked to any documented episodes of large-magnitude crustal shortening in the eastern half of the range. The spatial pattern of surface uplift and exhumation seems to mimic the Pampean flat slab's geometry, however, it could be equally well explained by eastward migration of a crustal root via ductile deformation in the lower crust and is not related to flat-slab subduction.

Binary Black Hole Mergers from Field Triples: Properties, Rates, and the Impact of Stellar Evolution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Antonini, Fabio; Toonen, Silvia; Hamers, Adrian S.

We consider the formation of binary black hole (BH) mergers through the evolution of field massive triple stars. In this scenario, favorable conditions for the inspiral of a BH binary are initiated by its gravitational interaction with a distant companion, rather than by a common-envelope phase invoked in standard binary evolution models. We use a code that follows self-consistently the evolution of massive triple stars, combining the secular triple dynamics (Lidov–Kozai cycles) with stellar evolution. After a BH triple is formed, its dynamical evolution is computed using either the orbit-averaged equations of motion, or a high-precision direct integrator for triplesmore » with weaker hierarchies for which the secular perturbation theory breaks down. Most BH mergers in our models are produced in the latter non-secular dynamical regime. We derive the properties of the merging binaries and compute a BH merger rate in the range (0.3–1.3) Gpc{sup −3} yr{sup −1}, or up to ≈2.5 Gpc{sup −3} yr{sup −1} if the BH orbital planes have initially random orientation. Finally, we show that BH mergers from the triple channel have significantly higher eccentricities than those formed through the evolution of massive binaries or in dense star clusters. Measured eccentricities could therefore be used to uniquely identify binary mergers formed through the evolution of triple stars. While our results suggest up to ≈10 detections per year with Advanced-LIGO, the high eccentricities could render the merging binaries harder to detect with planned space based interferometers such as LISA.« less

Trace sulfate in mid-Proterozoic carbonates and the sulfur isotope record of biospheric evolution

NASA Astrophysics Data System (ADS)

Gellatly, Anne M.; Lyons, Timothy W.

2005-08-01

Concentrations of oceanic and atmospheric oxygen have varied over geologic time as a function of sulfur and carbon cycling at or near the Earth's surface. This balance is expressed in the sulfur isotope composition of seawater sulfate. Given the near absence of gypsum in pre-Phanerozoic sediments, trace amounts of carbonate-associated sulfate (CAS) within limestones or dolostones provide the best available constraints on the isotopic composition of sulfate in Precambrian seawater. Although absolute CAS concentrations, which range from those below detection to ˜120 ppm sulfate in this study, may be compromised by diagenesis, the sulfur isotope compositions can be buffered sufficiently to retain primary values. Stratigraphically controlled δ 34S measurements for CAS from three mid-Proterozoic carbonate successions (˜1.2 Ga Mescal Limestone, Apache Group, Arizona, USA; ˜1.45-1.47 Ga Helena and Newland formations, Belt Supergroup, Montana, USA; and ˜1.65 Ga Paradise Creek Formation, McNamara Group, NW Queensland, Australia) show large isotopic variability (+9.1‰ to +18.9‰, -1.1‰ to +27.3‰, and +14.1‰ to +37.3‰, respectively) over stratigraphic intervals of ˜50 to 450 m. This rapid variability, ranging from scattered to highly systematic, and overall low CAS abundances can be linked to sulfate concentrations in the mid-Proterozoic ocean that were substantially lower than those of the Phanerozoic but higher than values inferred for the Archean. Results from the Belt Supergroup specifically corroborate previous arguments for seawater contributions to the basin. Limited sulfate availability that tracks the oxygenation history of the early atmosphere is also consistent with the possibility of extensive deep-ocean sulfate reduction, the scarcity of bedded gypsum, and the stratigraphic δ 34S trends and 34S enrichments commonly observed for iron sulfides of mid-Proterozoic age.

Gradual plasmon evolution and huge infrared near-field enhancement of metallic bridged nanoparticle dimers.

PubMed

Huang, Yu; Ma, Lingwei; Hou, Mengjing; Xie, Zheng; Zhang, Zhengjun

2016-01-28

By three-dimensional (3D) finite element method (FEM) plasmon mapping, gradual plasmon evolutions of both bonding dipole plasmon (BDP) and charge transfer plasmon (CTP) modes are visualized. In particular, the evolved BDP mode provides a physical insight into the rapid degeneration of electromagnetic hot spots in practical applications, while the rising CTP mode enables a huge near-field enhancement for potential plasmonic devices at infrared wavelengths.

Estimation and Validation of \\delta18O Global Distribution with Rayleigh-type two Dimensional Isotope Circulation Model

NASA Astrophysics Data System (ADS)

Yoshimura, K.; Oki, T.; Ohte, N.; Kanae, S.; Ichiyanagi, K.

2004-12-01

A simple water isotope circulation model on a global scale that includes a Rayleigh equation and the use of _grealistic_h external meteorological forcings estimates short-term variability of precipitation 18O. The results are validated by Global Network of Isotopes in Precipitation (GNIP) monthly observations and by daily observations at three sites in Thailand. This good agreement highlights the importance of large scale transport and mixing of vapor masses as a control factor for spatial and temporal variability of precipitation isotopes, rather than in-cloud micro processes. It also indicates the usefulness of the model and the isotopes observation databases for evaluation of two-dimensional atmospheric water circulation fields in forcing datasets. In this regard, two offline simulations for 1978-1993 with major reanalyses, i.e. NCEP and ERA15, were implemented, and the results show that, over Europe ERA15 better matched observations at both monthly and interannual time scales, mainly owing to better precipitation fields in ERA15, while in the tropics both produced similarly accurate isotopic fields. The isotope analyses diagnose accuracy of two-dimensional water circulation fields in datasets with a particular focus on precipitation processes.

Photospheric and coronal magnetic fields in six magnetographs. I. Consistent evolution of the bashful ballerina

NASA Astrophysics Data System (ADS)

Virtanen, Ilpo; Mursula, Kalevi

2016-06-01

Aims: We study the long-term evolution of photospheric and coronal magnetic fields and the heliospheric current sheet (HCS), especially its north-south asymmetry. Special attention is paid to the reliability of the six data sets used in this study and to the consistency of the results based on these data sets. Methods: We use synoptic maps constructed from Wilcox Solar Observatory (WSO), Mount Wilson Observatory (MWO), Kitt Peak (KP), SOLIS, SOHO/MDI, and SDO/HMI measurements of the photospheric field and the potential field source surface (PFSS) model. Results: The six data sets depict a fairly similar long-term evolution of magnetic fields and the heliospheric current sheet, including polarity reversals and hemispheric asymmetry. However, there are time intervals of several years long, when first KP measurements in the 1970s and 1980s, and later WSO measurements in the 1990s and early 2000s, significantly deviate from the other simultaneous data sets, reflecting likely errors at these times. All of the six magnetographs agree on the southward shift of the heliospheric current sheet (the so-called bashful ballerina phenomenon) in the declining to minimum phase of the solar cycle during a few years of the five included cycles. We show that during solar cycles 20-22, the southward shift of the HCS is mainly due to the axial quadrupole term, reflecting the stronger magnetic field intensity at the southern pole during these times. During cycle 23 the asymmetry is less persistent and mainly due to higher harmonics than the quadrupole term. Currently, in the early declining phase of cycle 24, the HCS is also shifted southward and is mainly due to the axial quadrupole as for most earlier cycles. This further emphasizes the special character of the global solar field during cycle 23.

Carbon isotope fractionation between Fe-carbide and diamond; a light C isotope reservoir in the deep Earth and Core?

NASA Astrophysics Data System (ADS)

Mikhail, S.; Jones, A. P.; Hunt, S. A.; Guillermier, C.; Dobson, D. P.; Tomlinson, E.; Dan, H.; Milledge, H.; Franchi, I.; Wood, I.; Beard, A.; Verchovsky, S.

2010-12-01

The largest accessible reservoir for terrestrial carbon is the mantle; however the core may yield even more. Carbon is commonly proposed as the light element (or one of) to make up the observed density deficit in the earth’s metallic core (NAKAJIMA et al., 2009). The potential isotopic effects of carbon incorporation into the core have not yet been investigated. In-situ ion probe (nanoSIMS) mapping and imaging of carbon isotope variations across rare sub-mm-scale Fe-rich carbide inclusions in mantle diamond (from Jagersfontein, South Africa) show the carbide to be significantly depleted in 13C relative to their diamond host. Distinctive textures suggest metallic liquid precipitates similar in geometry to (giant) nitrogen platelets, controlled by the octahedral symmetry of diamond, which we interpret as syngenic formation. The difference in δ13C values between the two natural phases for diamond-Fe carbide, gives an isotopic fractionation factor (ΔC) which agrees well with HPHT multi-anvil experiments (5-9 GPa and >1400°C). Our measured ΔC between Fe-carbide and diamond may only have local significance, but the measured isotopic values represent characterization of the highest PT carbide known (i.e. > minimum depth of the diamond stability field ≈ 150 km). The direction and magnitude of ΔC agrees with observations of the ΔC between cohenite-graphite in iron meteorites (DEINES and WICKMAN, 1975) and both agree with HPHT experiments, thus suggesting that carbon in the deep Earth, and particularly in the core, may be similarly fractionated (i.e. depleted in the 13C). Since metallic liquid drained from the silicate mantle to form the core during the early Earth, we can use our values as a proxy to constrain evolution of deep carbon reservoirs such as the core and bulk silicate Earth. For example, we can test the suggestion of Grady et al (2004) that the upper mantle value of δ13C ≈ -5 ‰ may not be representative of the bulk Earth, since solar system

Stable isotope and hydro chemical variability along the Calueque-Oshakati Canal in the Cuvelai-Etosha Basin, Namibia

NASA Astrophysics Data System (ADS)

Koeniger, Paul; Beyer, Matthias; Gaj, Marcel; Hamutoko, Josefina; Uugulu, Shoopi; Wanke, Heike; Huber, Markus; Lohe, Christoph; Quinger, Martin; Himmelsbach, Thomas

2014-05-01

Since 1973 Kunene River water (currently between 47 and 63 Million m3 per year [1]) is carried from the Calueque Dam in Angola along a 150 km concrete canal to Oshakati in the Cuvelai-Etosha Basin which supplies the most densely populated area of Namibia with drinking water. Backup storage is held in the Olushandja Dam and in water towers at Ogongo, Oshakati and Ondangwa and about 4,000 km of pipelines radiate out from purification schemes and supply most of the people and the livestock [2, 3]. The canal is open along most of its course to Oshakati, allowing livestock and people living nearby to make free use of the water. During the rainy season, flood water from the vast Oshana drainage system swashes into the canal bearing a potential health risk when consumed untreated. Within the SASSCAL project (Southern African Science Service Centre for Climate Change and Adaptive Land Management - www.sasscal.org) water samples were collected during a field campaign from 18th to 20th November 2013 right before the onset of the rainy season 2013/14, to gain information on water evolution, evaporation and mixing influences as well as to characterize input concentrations for indirect recharge in this area. Water samples were collected at 14 sites along the canal (about every 10 km) and the Kunene River for stable water isotopes (deuterium and oxygen-18) and hydro chemical analyzes. Coordinates and altitude, temperature, conductivity, pH-value, and oxygen content were measured in the field. Hydro chemical and stable isotope analyzes were conducted later on in the laboratory. For stable isotopes a Picarro L2120-i water vapor analyzer was used with accuracies of 0.2o and 0.8o for δ18O and δ2H, respectively. Further campaigns within and after the rainy season are planned. A discussion of isotope and hydro chemical evolution of canal water in comparison to local rain and available groundwater composition will be presented. [1] Directorate of Rural Water Supply (2004

Effects of basin-forming impacts on the thermal evolution and magnetic field of Mars

NASA Astrophysics Data System (ADS)

Roberts, J. H.; Arkani-Hamed, J.

2017-11-01

The youngest of the giant impact basins on Mars are either weakly magnetized or completely demagnetized, indicating that a global magnetic field was not present at the time those basins formed. Eight basins are sufficiently large that the impact heating associated with their formation could have penetrated below the core-mantle boundary (CMB). Here we investigate the thermal evolution of the martian interior and the fate of the global magnetic field using 3D mantle convection models coupled to a parameterized 1D core thermal evolution model. We find that the survival of the impact-induced temperature anomalies in the upper mantle is strongly controlled by the mantle viscosity. Impact heating from subsequent impacts can accumulate in stiffer mantles faster than it can be advected away, resulting in a thermal blanket that insulates an entire hemisphere. The impact heating in the core will halt dynamo activity, at least temporarily. If the mantle is initially cold, and the core initially superheated, dynamo activity may resume as quickly as a few Myr after each impact. However unless the lower mantle has either a low viscosity or a high thermal conductivity, this restored dynamo will last for only a few hundred Myr after the end of the sequence of impacts. Thus, we find that the longevity of the magnetic field is more strongly controlled by the lower mantle properties and relatively insensitive to the impact-induced temperature anomalies in the upper mantle.

COMPOUND-SPECIFIC ISOTOPE ANALYSIS OF MTBE AND TBA FOR BIOREMEDIATION STUDIES

EPA Science Inventory

The utility of stable isotope ratios to detect biodegradation for a number of chemical compounds including MTBE and TBA has been demonstrated in a number of laboratory or field studies. Chemical reactions tend to favor molecules with the lighter isotopic species (e.g., 12C, 1H), ...

Understanding Copper Isotope Behavior in the High Temperature Magmatic-Hydrothermal Porphyry Environment

NASA Astrophysics Data System (ADS)

Gregory, Melissa J.; Mathur, Ryan

2017-11-01

Copper stable isotope geochemistry has the potential to constrain aspects of ore deposit formation once variations in the isotopic data can be related to the physiochemical conditions during metal deposition. This study presents Cu isotope ratios for samples from the Pebble porphyry Cu-Au-Mo deposit in Alaska. The δ65Cu values for hypogene copper sulfides range from -2.09‰ to 1.11‰ and show linear correlations with the δ18O isotope ratios calculated for the fluid in equilibrium with the hydrothermal alteration minerals in each sample. Samples with sodic-potassic, potassic, and illite alteration display a negative linear correlation between the Cu and O isotope results. This suggests that fractionation of Cu isotopes between the fluid and precipitating chalcopyrite is positive as the hydrothermal fluid is evolving from magmatic to mixed magmatic-meteoric compositions. Samples with advanced argillic alteration display a weak positive linear correlation between Cu and O isotope results consistent with small negative fluid-chalcopyrite Cu isotope fractionation during fluid evolution. The hydrothermal fluids that formed sodic-potassic, potassic, and illite alteration likely transported Cu as CuHS0. Hydrothermal fluids that resulted in advanced argillic alteration likely transport Cu as CuCl2-. The pH conditions also control Cu isotope fractionation, consistent with previous experimental work. Larger fractionation factors were found between fluids and chalcopyrite precipitating under neutral conditions contrasting with small fractionation factors calculated between fluids and chalcopyrite precipitating under acidic conditions. Therefore, this study proposes that hydrothermal fluid compositions and pH conditions are related to Cu isotope variations in high temperature magmatic-hydrothermal deposits.

Stable Isotope Anatomy of Tropical Cyclone Ita, North-Eastern Australia, April 2014

PubMed Central

Munksgaard, Niels C.; Zwart, Costijn; Kurita, Naoyuki; Bass, Adrian; Nott, Jon; Bird, Michael I.

2015-01-01

The isotope signatures registered in speleothems during tropical cyclones (TC) provides information about the frequency and intensity of past TCs but the precise relationship between isotopic composition and the meteorology of TCs remain uncertain. Here we present continuous δ18O and δ2H data in rainfall and water vapour, as well as in discrete rainfall samples, during the passage of TC Ita and relate the evolution in isotopic compositions to local and synoptic scale meteorological observations. High-resolution data revealed a close relationship between isotopic compositions and cyclonic features such as spiral rainbands, periods of stratiform rainfall and the arrival of subtropical and tropical air masses with changing oceanic and continental moisture sources. The isotopic compositions in discrete rainfall samples were remarkably constant along the ~450 km overland path of the cyclone when taking into account the direction and distance to the eye of the cyclone at each sampling time. Near simultaneous variations in δ18O and δ2H values in rainfall and vapour and a near-equilibrium rainfall-vapour isotope fractionation indicates strong isotopic exchange between rainfall and surface inflow of vapour during the approach of the cyclone. In contrast, after the passage of spiral rainbands close to the eye of the cyclone, different moisture sources for rainfall and vapour are reflected in diverging d-excess values. High-resolution isotope studies of modern TCs refine the interpretation of stable isotope signatures found in speleothems and other paleo archives and should aim to further investigate the influence of cyclone intensity and longevity on the isotopic composition of associated rainfall. PMID:25742628