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Sample records for frequency oxygen plasma

  1. Atomic Oxygen Energy in Low Frequency Hyperthermal Plasma Ashers

    NASA Technical Reports Server (NTRS)

    Banks, Bruce A.; Miller, Sharon K R.; Kneubel, Christian A.

    2014-01-01

    Experimental and analytical analysis of the atomic oxygen erosion of pyrolytic graphite as well as Monte Carlo computational modeling of the erosion of Kapton H (DuPont, Wilmington, DE) polyimide was performed to determine the hyperthermal energy of low frequency (30 to 35 kHz) plasma ashers operating on air. It was concluded that hyperthermal energies in the range of 0.3 to 0.9 eV are produced in the low frequency air plasmas which results in texturing similar to that in low Earth orbit (LEO). Monte Carlo computational modeling also indicated that such low energy directed ions are fully capable of producing the experimentally observed textured surfaces in low frequency plasmas.

  2. A spectral study of a radio-frequency plasma-generated flux of atomic oxygen

    NASA Technical Reports Server (NTRS)

    Batten, Carmen E.; Brown, Kenneth G.; Lewis, Beverley W.

    1994-01-01

    The active environment of a radio-frequency (RF) plasma generator, with and without low-pressure oxygen, has been characterized through the identification of emission lines in the spectral region from 250 to 900 nm. The environment is shown to be dependent on the partial pressure of oxygen and the power applied to the RF generator. Atomic oxygen has been found in significant amounts as well as atomic hydrogen and the molecular oxygen species O2((sup 1)Sigma). The only charged species observed was the singly charged molecular ion O2(+). With a polymer specimen in the plasma chamber, carbon monoxide was also observed. The significance of these observations with respect to previous studies using this type of generator to stimulate material degradation in space is discussed. The possibility of using these generators as atomic oxygen sources in the development of oxygen atom fluorescence sensors is explored.

  3. Influence of oxygen traces on an atmospheric-pressure radio-frequency capacitive argon plasma discharge

    SciTech Connect

    Li Shouzhe; Wu Qi; Yan Wen; Wang Dezhen; Uhm, Han S.

    2011-10-15

    An atmospheric-pressure capacitive discharge source driven by radio-frequency power supply at 13.56 MHz has been developed experimentally that is capable of producing a homogeneous and cold glow discharge in O{sub 2}/Ar. With respect to the influence of oxygen component when diluted into argon plasma discharge on the discharge characteristics, the measurements of the electrical parameters (impedance, phase angle, resistance, and reactance) are made systematically and the densities of the metastable and resonant state of argon are determined by means of optical emission spectroscopy (OES). It is shown that the admixture of oxygen into argon plasma not only changes the electric characteristics but also alters the optical emission spectra greatly due to strong interaction between the oxygen content and the argon in the plasma environment.

  4. Treatment of Second-Order Structures of Proteins Using Oxygen Radio Frequency Plasma

    NASA Astrophysics Data System (ADS)

    Hayashi, Nobuya; Nakahigashi, Akari; Liu, Hao; Goto, Masaaki

    2010-08-01

    Decomposition characteristics of second-order structures of proteins are determined using an oxygen radio frequency (RF) plasma sterilizer in order to prevent infectious proteins from contaminating medical equipment in hospitals. The removal of casein protein as a test protein with a concentration of 50 mg/cm2 on the plane substrate requires approximately 8 h when singlet atomic oxygen is irradiated. The peak intensity of Fourier transform infrared spectroscopy (FTIR) spectra of the β-sheet structures decreases at approximately the same rate as those of the α-helix and first-order structures of proteins. Active oxygen has a sufficient oxidation energy to dissociate hydrogen bonds within the β-sheet structure.

  5. Particle modelling of magnetically confined oxygen plasma in low pressure radio frequency discharge

    SciTech Connect

    Benyoucef, Djilali; Yousfi, Mohammed

    2015-01-15

    The main objective of this paper is the modelling and simulation of a radio frequency (RF) discharge in oxygen at low pressure and at room temperature, including the effect of crossed electric and magnetic fields for generation and confinement of oxygen plasma. The particle model takes into account one axial dimension along the electric field axis and three velocity components during the Monte Carlo treatment of the collisions between charged particles and background gas. The simulation by this developed code allows us not only to determine the electrodynamics characteristics of the RF discharge, but also to obtain kinetics and energetic description of reactive oxygen plasma at low pressure. These information are very important for the control of the deep reactive-ion etching technology of the silicon to manufacture capacitors with high density and for the deposition thick insulating films or thick metal to manufacture micro-coils. The simulation conditions are as follows: RF peak voltage of 200 V, frequency of 13.56 MHz, crossed magnetic field varying from 0 to 50 Gauss, and oxygen pressure of 13.8 Pa. In the presence of magnetic field, the results show an increase of the plasma density, a decrease of the electron mean energy, and also a reduction of the ratio between electron density and positive ion density. Finally in order to validate, the results are successfully compared with measurements already carried out in the literature. The conditions of comparison are from 100 to 300 V of the peak voltage at 13.56 MHz under a pressure of 13.8 Pa and a gap distance of 2.5 cm.

  6. Pulsed Discharge Effects on Bacteria Inactivation in Low-Pressure Radio-Frequency Oxygen Plasma

    NASA Astrophysics Data System (ADS)

    Vicoveanu, Dragos; Ohtsu, Yasunori; Fujita, Hiroharu

    2008-02-01

    The sporicidal effects of low-pressure radio frequency (RF) discharges in oxygen, produced by the application of continuous and pulsed RF power, were evaluated. For all cases, the survival curves showed a biphasic evolution. The maximum efficiency for bacteria sterilization was obtained when the RF power was injected in the continuous wave mode, while in the pulsed mode the lowest treatment temperature was ensured. The inactivation rates were calculated from the microorganism survival curves and their dependencies on the pulse characteristics (i.e., pulse frequency and duty cycle) were compared with those of the plasma parameters. The results indicated that the inactivation rate corresponding to the first phase of the survival curves is related to the time-averaged intensity of the light emission by the excited neutral atoms in the pulsed plasma, whereas the inactivation rate calculated from the second slope of the survival curves and the time-averaged plasma density have similar behaviors, when the pulse parameters were modified.

  7. A ground-based radio frequency inductively coupled plasma apparatus for atomic oxygen simulation in low Earth orbit

    NASA Astrophysics Data System (ADS)

    Huang, Yongxian; Tian, Xiubo; Yang, Shiqin; Chu, Paul K.

    2007-10-01

    A radio frequency (rf) inductively coupled plasma apparatus has been developed to simulate the atomic oxygen environment encountered in low Earth orbit (LEO). Basing on the novel design, the apparatus can achieve stable, long lasting operation, pure and high density oxygen plasma beam. Furthermore, the effective atomic oxygen flux can be regulated. The equivalent effective atomic oxygen flux may reach (2.289-2.984)×1016at./cm2s at an oxygen pressure of 1.5Pa and rf power of 400W. The equivalent atomic oxygen flux is about 100 times than that in the LEO environment. The mass loss measured from the polyimide sample changes linearly with the exposure time, while the density of the eroded holes becomes smaller. The erosion mechanism of the polymeric materials by atomic oxygen is complex and involves initial reactions at the gas-surface interface as well as steady-state material removal.

  8. A ground-based radio frequency inductively coupled plasma apparatus for atomic oxygen simulation in low Earth orbit.

    PubMed

    Huang, Yongxian; Tian, Xiubo; Yang, Shiqin; Chu, Paul K

    2007-10-01

    A radio frequency (rf) inductively coupled plasma apparatus has been developed to simulate the atomic oxygen environment encountered in low Earth orbit (LEO). Basing on the novel design, the apparatus can achieve stable, long lasting operation, pure and high density oxygen plasma beam. Furthermore, the effective atomic oxygen flux can be regulated. The equivalent effective atomic oxygen flux may reach (2.289-2.984) x 10(16) at.cm(2) s at an oxygen pressure of 1.5 Pa and rf power of 400 W. The equivalent atomic oxygen flux is about 100 times than that in the LEO environment. The mass loss measured from the polyimide sample changes linearly with the exposure time, while the density of the eroded holes becomes smaller. The erosion mechanism of the polymeric materials by atomic oxygen is complex and involves initial reactions at the gas-surface interface as well as steady-state material removal. PMID:17979410

  9. Reduced leakage in epitaxial BiFeO{sub 3} films following oxygen radio frequency plasma treatment

    SciTech Connect

    Kothari, Deepti; UGC-DAE Consortium for Scientific Research, University Campus, Khandwa Road, Indore 452 017 ; Upadhyay, Sanjay K.; Raghavendra Reddy, V.; Jariwala, C.; Raole, P. M.

    2013-06-07

    Epitaxial BiFeO{sub 3} (BFO) films were deposited using pulsed laser deposition method. The prepared films were characterized using x-ray diffraction, x-ray reflectivity, ferroelectric loop tracer, and leakage current measurements before and after oxygen plasma treatment. The leakage current of the films, a crucial parameter in device applications, is observed to be reduced by two orders of magnitude with oxygen plasma treatment at room temperature. P-E hysteresis loops were observed in oxygen plasma treated BFO films. The observed results indicate the usefulness of oxygen radio frequency plasma treatment (RF 13.56 MHz), which is an effective and low temperature processing technique, in such lossy ferroelectric thin films.

  10. Influence of surface conditions on plasma dynamics and electron heating in a radio-frequency driven capacitively coupled oxygen plasma

    NASA Astrophysics Data System (ADS)

    Greb, Arthur; Gibson, Andrew Robert; Niemi, Kari; O'Connell, Deborah; Gans, Timo

    2015-08-01

    The impact of changing surface condition on plasma dynamics and electron heating is investigated by means of numerical simulations, based on a semi-kinetic fluid model approach, and compared with measurements of the nanosecond electron dynamics in the plasma-surface interface region using phase resolved optical emission spectroscopy (PROES). The simulations are conducted in a one-dimensional domain and account for a geometrical asymmetry comparable to the experimental setup of a radio-frequency driven capacitively coupled plasma in a gaseous electronics conference reference cell. A simple reaction scheme is considered, including electrons, \\text{O}2+ positive ions, {{\\text{O}}-} negative ions and {{\\text{O}}2}{≤ft(1Δ\\right)} metastable singlet delta oxygen (SDO) as individual species. The role of surface loss and effective lifetime of SDO is discussed. To simulate different surface conditions, the SDO surface loss probability and the secondary electron emission coefficient were varied in the model. It is found that a change in surface condition significantly influences the metastable concentration, electronegativity, spatial particle distributions and densities as well as the ionization and electron heating dynamics. The excitation dynamics obtained from simulations are compared with PROES measurements. This allows to determine experimentally relevant SDO surface loss probabilities and secondary electron emission coefficient values in-situ and is demonstrated for two different surface materials, namely aluminum and Teflon.

  11. ESCA study of Kapton exposed to atomic oxygen in low earth orbit or downstream from a radio-frequency oxygen plasma

    NASA Technical Reports Server (NTRS)

    Golub, Morton A.; Wydeven, Theodore; Cormia, Robert D.

    1988-01-01

    The ESCA spectra of Kapton polyimide film exposed to atomic oxygen O(3P), either in low earth orbit (LEO) on the STS-8 Space Shuttle or downstream from a radio-frequency oxygen plasma, were compared. The major difference in surface chemistry induced by the two types of exposure to O(3P), both of which caused surface recession (etching), was a much larger uptake of oxygen by Kapton etched in the O2 plasma than in LEO. This difference is attributed to the presence of molecular oxygen in the plasma reactor and its absence in LEO: in the former case, O2 can react with radicals generated in the Kapton molecule as it etches, become incorporated in the etched polymer, and thereby yield a higher steady-state 'surface oxidation' level than in LEO.

  12. The influence of surface properties on the plasma dynamics in radio-frequency driven oxygen plasmas: Measurements and simulations

    SciTech Connect

    Greb, Arthur; Niemi, Kari; O'Connell, Deborah; Gans, Timo

    2013-12-09

    Plasma parameters and dynamics in capacitively coupled oxygen plasmas are investigated for different surface conditions. Metastable species concentration, electronegativity, spatial distribution of particle densities as well as the ionization dynamics are significantly influenced by the surface loss probability of metastable singlet delta oxygen (SDO). Simulated surface conditions are compared to experiments in the plasma-surface interface region using phase resolved optical emission spectroscopy. It is demonstrated how in-situ measurements of excitation features can be used to determine SDO surface loss probabilities for different surface materials.

  13. ESCA study of several fluorocarbon polymers exposed to atomic oxygen in low earth orbit or within or downstream from a radio-frequency oxygen plasma

    NASA Technical Reports Server (NTRS)

    Golub, Morton A.; Wydeven, Theodore; Cormia, Robert D.

    1989-01-01

    The ESCA (electron spectroscopy for chemical analysis) spectra of films of Tedlar, tetrafluoroethylene-hexafluoropropylene copolymer (in the form of a Teflon FEP coating on Kapton H, i.e., Kapton F), and polytetrafluoroethylene (Teflon or Teflon TFE), exposed to atomic oxygen O(3P) either in LEO on the STS-8 Space Shuttle or within or downstream from a radio-frequency oxygen plasma, were compared. The major difference in surface chemistry of Tedlar induced by the various exposures to O(3P) was a much larger uptake of oxygen when etched either in or out of the glow of an O2 plasma than when etched in LEO. In contrast, Kapton F exhibited very little surface oxidation during any of the three different exposures to O(3P), while Teflon was scarcely oxidized.

  14. A computational analysis of the vibrational levels of molecular oxygen in low-pressure stationary and transient radio-frequency oxygen plasma

    NASA Astrophysics Data System (ADS)

    Kemaneci, Efe; Booth, Jean-Paul; Chabert, Pascal; van Dijk, Jan; Mussenbrock, Thomas; Brinkmann, Ralf Peter

    2016-04-01

    Vibrational levels of molecular oxygen, O2(v  <  42), are investigated in continuous and pulse-modulated low-pressure radio-frequency oxygen plasma with a global modelling approach. The model is benchmarked against a variety of pressure-, power- and time-resolved measurements of several inductive and asymmetric capacitive discharges available in the literature, and a good agreement is obtained. The sensitivity of the model with respect to the vibrational kinetics, the wall reactions and the spatial inhomogeneity of the charged particles are presented. The simulations without the vibrational levels are also shown for the sake of comparison.

  15. The effect of oxygen flow rate and radio frequency plasma power on cubic ZnMgO ultraviolet sensors grown by plasma-enhanced molecular beam epitaxy

    SciTech Connect

    Casey Boutwell, R.; Wei Ming; Schoenfeld, Winston V.

    2013-07-15

    Cubic Zn{sub 1-x}Mg{sub x}O thin films were produced by Plasma-Enhanced Molecular Beam Epitaxy. Oxygen flow rate and applied Radio-Frequency (RF) plasma power were varied to investigate the impact on film growth and optoelectronic device performance. Solar-blind and visible-blind detectors were fabricated with metal-semiconductor-metal interdigitated Ni/Mg/Au contacts and responsivity is compared under different growth conditions. Increasing oxygen flow rate and RF plasma power increased Zn incorporation in the film, which leads to phase segregation at relatively high Zn/Mg ratio. Responsivity as high as 61 A/W was measured in phase-segregated ZnMgO visible-blind detectors.

  16. Energetic electron avalanches and mode transitions in planar inductively coupled radio-frequency driven plasmas operated in oxygen

    SciTech Connect

    Zaka-ul-Islam, M.; Niemi, K.; Gans, T.; O'Connell, D.

    2011-07-25

    Space and phase resolved optical emission spectroscopic measurements reveal that in certain parameter regimes, inductively coupled radio-frequency driven plasmas exhibit three distinct operation modes. At low powers, the plasma operates as an alpha-mode capacitively coupled plasma driven through the dynamics of the plasma boundary sheath potential in front of the antenna. At high powers, the plasma operates in inductive mode sustained through induced electric fields due to the time varying currents and associated magnetic fields from the antenna. At intermediate powers, close to the often observed capacitive to inductive (E-H) transition regime, energetic electron avalanches are identified to play a significant role in plasma sustainment, similar to gamma-mode capacitively coupled plasmas. These energetic electrons traverse the whole plasma gap, potentially influencing plasma surface interactions as exploited in technological applications.

  17. Low Pressure Radio-Frequency Oxygen Plasma Induced Oxidation of Titanium – Surface Characteristics and Biological Effects

    PubMed Central

    Tseng, Wan-Yu; Hsu, Sheng-Hao; Huang, Chieh-Hsiun; Tu, Yu-Chieh; Tseng, Shao-Chin; Chen, Hsuen-Li; Chen, Min-Huey; Su, Wei-Fang; Lin, Li-Deh

    2013-01-01

    Objective This research was designed to investigate the effects of low pressure radio-frequency (RF) oxygen plasma treatment (OPT) on the surface of commercially pure titanium (CP-Ti) and Ti6Al4V. Surface topography, elemental composition, water contact angle, cell viability, and cell morphology were surveyed to evaluate the biocompatibility of titanium samples with different lengths of OP treating time. Materials and Methods CP-Ti and Ti6Al4V discs were both classified into 4 groups: untreated, treated with OP generated by using oxygen (99.98%) for 5, 10, and 30 min, respectively. After OPT on CP-Ti and Ti6Al4V samples, scanning probe microscopy, X-ray photoelectron spectrometry (XPS), and contact angle tests were conducted to determine the surface topography, elemental composition and hydrophilicity, respectively. The change of surface morphology was further studied using sputtered titanium on silicon wafers. 3-[4,5-dimethylthiazol-2-yl]-2,5-diphenyltetrazolium bromide (MTT) assay and F-actin immunofluorescence stain were performed to investigate the viability and spreading behavior of cultivated MG-63 cells on the samples. Results The surface roughness was most prominent after 5 min OPT in both CP-Ti and Ti6Al4V, and the surface morphology of sputtered Ti sharpened after the 5 min treatment. From the XPS results, the intensity of Ti°, Ti2+, and Ti3+ of the samples’ surface decreased indicating the oxidation of titanium after OPT. The water contact angles of both CP-Ti and Ti6Al4V were increased after 5 min OPT. The results of MTT assay demonstrated MG-63 cells proliferated best on the 5 min OP treated titanium sample. The F-actin immunofluorescence stain revealed the cultivated cell number of 5 min treated CP-Ti/Ti6Al4V was greater than other groups and most of the cultivated cells were spindle-shaped. Conclusions Low pressure RF oxygen plasma modified both the composition and the morphology of titanium samples’ surface. The CP-Ti/Ti6Al4V treated with 5 min

  18. The Role of Helium Metastable States in Radio-Frequency Helium-Oxygen Atmospheric Pressure Plasma Jets: Measurement and Numerical Simulation

    NASA Astrophysics Data System (ADS)

    Niemi, Kari; Waskoenig, Jochen; Sadeghi, Nader; Gans, Timo; O'Connell, Deborah

    2011-10-01

    Absolute densities of metastable He atoms were measured line-of sight integrated along the plasma channel of a capacitively-coupled radio-frequency driven atmospheric pressure plasma jet operated in helium oxygen mixtures by tunable diode-laser absorption spectroscopy. Dependencies of the He metastable density with oxygen admixtures up to 1 percent were investigated. Results are compared to a 1-d numerical simulation, which includes a semi-kinetical treatment of the electron dynamics and the complex plasma chemistry (20 species, 184 reactions), and very good agreement is found. The main formation mechanisms for the helium metastables are identified and analyzed, including their pronounced spatio-temporal dynamics. Penning ionization through helium metastables is found to be significant for plasma sustainment, while it is revealed that helium metastables are not an important energy carrying species into the jet effluent and therefore will not play a direct role in remote surface treatments.

  19. Sterilization by oxygen plasma

    NASA Astrophysics Data System (ADS)

    Moreira, Adir José; Mansano, Ronaldo Domingues; Andreoli Pinto, Terezinha de Jesus; Ruas, Ronaldo; Zambon, Luis da Silva; da Silva, Mônica Valero; Verdonck, Patrick Bernard

    2004-07-01

    The use of polymeric medical devices has stimulated the development of new sterilization methods. The traditional techniques rely on ethylene oxide, but there are many questions concerning the carcinogenic properties of the ethylene oxide residues adsorbed on the materials after processing. Another common technique is the gamma irradiation process, but it is costly, its safe operation requires an isolated site and it also affects the bulk properties of the polymers. The use of a gas plasma is an elegant alternative sterilization technique. The plasma promotes an efficient inactivation of the micro-organisms, minimises the damage to the materials and presents very little danger for personnel and the environment. Pure oxygen reactive ion etching type of plasmas were applied to inactivate a biologic indicator, the Bacillus stearothermophilus, to confirm the efficiency of this process. The sterilization processes took a short time, in a few minutes the mortality was complete. In situ analysis of the micro-organisms' inactivating time was possible using emission spectrophotometry. The increase in the intensity of the 777.5 nm oxygen line shows the end of the oxidation of the biologic materials. The results were also observed and corroborated by scanning electron microscopy.

  20. Absolute atomic oxygen and nitrogen densities in radio-frequency driven atmospheric pressure cold plasmas: Synchrotron vacuum ultra-violet high-resolution Fourier-transform absorption measurements

    SciTech Connect

    Niemi, K.; O'Connell, D.; Gans, T.; Oliveira, N. de; Joyeux, D.; Nahon, L.; Booth, J. P.

    2013-07-15

    Reactive atomic species play a key role in emerging cold atmospheric pressure plasma applications, in particular, in plasma medicine. Absolute densities of atomic oxygen and atomic nitrogen were measured in a radio-frequency driven non-equilibrium plasma operated at atmospheric pressure using vacuum ultra-violet (VUV) absorption spectroscopy. The experiment was conducted on the DESIRS synchrotron beamline using a unique VUV Fourier-transform spectrometer. Measurements were carried out in plasmas operated in helium with air-like N{sub 2}/O{sub 2} (4:1) admixtures. A maximum in the O-atom concentration of (9.1 {+-} 0.7) Multiplication-Sign 10{sup 20} m{sup -3} was found at admixtures of 0.35 vol. %, while the N-atom concentration exhibits a maximum of (5.7 {+-} 0.4) Multiplication-Sign 10{sup 19} m{sup -3} at 0.1 vol. %.

  1. The role of helium metastable states in radio-frequency driven helium-oxygen atmospheric pressure plasma jets: measurement and numerical simulation

    NASA Astrophysics Data System (ADS)

    Niemi, K.; Waskoenig, J.; Sadeghi, N.; Gans, T.; O'Connell, D.

    2011-10-01

    Absolute densities of metastable He(23S1) atoms were measured line-of-sight integrated along the discharge channel of a capacitively coupled radio-frequency driven atmospheric pressure plasma jet operated in technologically relevant helium-oxygen mixtures by tunable diode-laser absorption spectroscopy. The dependences of the He(23S1) density in the homogeneous-glow-like α-mode plasma with oxygen admixtures up to 1% were investigated. The results are compared with a one-dimensional numerical simulation, which includes a semi-kinetical treatment of the pronounced electron dynamics and the complex plasma chemistry (in total 20 species and 184 reactions). Very good agreement between measurement and simulation is found. The main formation mechanisms for metastable helium atoms are identified and analyzed, including their pronounced spatio-temporal dynamics. Penning ionization through helium metastables is found to be significant for plasma sustainment, while it is revealed that helium metastables are not an important energy carrying species into the jet effluent and therefore will not play a direct role in remote surface treatments.

  2. Energy resolved actinometry for simultaneous measurement of atomic oxygen densities and local mean electron energies in radio-frequency driven plasmas

    SciTech Connect

    Greb, Arthur Niemi, Kari; O'Connell, Deborah; Gans, Timo

    2014-12-08

    A diagnostic method for the simultaneous determination of atomic oxygen densities and mean electron energies is demonstrated for an atmospheric pressure radio-frequency plasma jet. The proposed method is based on phase resolved optical emission measurements of the direct and dissociative electron-impact excitation dynamics of three distinct emission lines, namely, Ar 750.4 nm, O 777.4 nm, and O 844.6 nm. The energy dependence of these lines serves as basis for analysis by taking into account two line ratios. In this frame, the method is highly adaptable with regard to pressure and gas composition. Results are benchmarked against independent numerical simulations and two-photon absorption laser-induced fluorescence experiments.

  3. Variable frequency microwave excited plasma

    SciTech Connect

    Gathi, Z.; Wei, J.; Garard, S.; Lauf, R.J.; Clausing, R.; McMillan, A.

    1995-12-31

    This paper reports on the use of an agile frequency source in generating plasma. A Traveling Wave Tube (TWT) provides approximately one octave bandwidth and variable power level up to 2 KW. By controlling the frequency, efficient coupling to the load (materials and/or plasma) can be maintained even as the load is changing in properties or position. Furthermore, the variable frequency power source allows the localization of the plasma discharge in precise areas of interest to specific processes. The excitation frequencies can be continuously swept to scan the plasma across an arbitrary-shaped target surface. Plasma generation and position control is reviewed and experimental results on variable frequency microwave excited plasma are presented.

  4. Oxygen Plasma Interactions with Molybdenum: Formation of Volatile Molybdenum Oxides

    NASA Astrophysics Data System (ADS)

    Saburi, Tei; Murata, Hirotoshi; Suzuki, Tatsuya; Fujii, Yasuhiko; Kiuchi, Kiyoshi

    The oxidation of molybdenum by oxygen plasma was studied. The oxygen plasma was discharged by helicon wave at the frequency of 18.1 MHz and at the power of 200W. The weight change of molybdenum in oxygen plasma was measured at 400 °C and at oxygen pressure of 5 Pa. The specimen was found to be oxidized and to lose it's weight drastically with the oxygen plasma, while the weight change of the specimen in the oxidation without plasma was not observed under the same conditions. The energetic species of oxygen atoms generated by rf plasma is regarded to accelerate the oxidation of molybdenum and the oxidation leads to the formation of volatile molybdenum trioxide at the surface.

  5. A New Radio Frequency Plasma Oxygen Primary Ion Source on Nano Secondary Ion Mass Spectrometry for Improved Lateral Resolution and Detection of Electropositive Elements at Single Cell Level.

    PubMed

    Malherbe, Julien; Penen, Florent; Isaure, Marie-Pierre; Frank, Julia; Hause, Gerd; Dobritzsch, Dirk; Gontier, Etienne; Horréard, François; Hillion, François; Schaumlöffel, Dirk

    2016-07-19

    An important application field of secondary ion mass spectrometry at the nanometer scale (NanoSIMS) is the detection of chemical elements and, in particular, metals at the subcellular level in biological samples. The detection of many trace metals requires an oxygen primary ion source to allow the generation of positive secondary ions with high yield in the NanoSIMS. The duoplasmatron oxygen source is commonly used in this ion microprobe but cannot achieve the same quality of images as the cesium primary ion source used to produce negative secondary ions (C(-), CN(-), S(-), P(-)) due to a larger primary ion beam size. In this paper, a new type of an oxygen ion source using a rf plasma is fitted and characterized on a NanoSIMS50L. The performances of this primary ion source in terms of current density and achievable lateral resolution have been characterized and compared to the conventional duoplasmatron and cesium sources. The new rf plasma oxygen source offered a net improvement in terms of primary beam current density compared to the commonly used duoplasmatron source, which resulted in higher ultimate lateral resolutions down to 37 nm and which provided a 5-45 times higher apparent sensitivity for electropositive elements. Other advantages include a better long-term stability and reduced maintenance. This new rf plasma oxygen primary ion source has been applied to the localization of essential macroelements and trace metals at basal levels in two biological models, cells of Chlamydomonas reinhardtii and Arabidopsis thaliana. PMID:27291826

  6. Instabilities in a capacitively coupled oxygen plasma

    SciTech Connect

    Küllig, C. Wegner, Th. Meichsner, J.

    2015-04-15

    Periodic fluctuations in the frequency range from 0.3 to 3 kHz were experimentally investigated in capacitively coupled radio frequency (13.56 MHz) oxygen plasma. The Gaussian beam microwave interferometry directly provides the line integrated electron density fluctuations. A system of two Langmuir probes measured the floating potential spatially (axial, radial) and temporally resolved. Hence, the floating potential fluctuation development is mapped within the discharge volume and provides a kind of discharge breathing and no wave propagation. Finally, it was measured the optical emission pattern of atomic oxygen during the fluctuation as well as the RF phase resolved optical emission intensity at selected phase position of the fluctuation by an intensified charge-coupled device camera. The deduced excitation rate pattern reveals the RF sheath dynamics and electron heating mechanisms, which is changing between low and high electronegativity during a fluctuation cycle. A perturbation calculation was taken into account using a global model with 15 elementary collision processes in the balance equations for the charged plasma species (O{sub 2}{sup +}, e, O{sup −}, O{sub 2}{sup −}) and a harmonic perturbation. The calculated frequencies agree with the experimentally observed frequencies. Whereby, the electron attachment/detachment processes are important for the generation of this instability.

  7. Instabilities in a capacitively coupled oxygen plasma

    NASA Astrophysics Data System (ADS)

    Küllig, C.; Wegner, Th.; Meichsner, J.

    2015-04-01

    Periodic fluctuations in the frequency range from 0.3 to 3 kHz were experimentally investigated in capacitively coupled radio frequency (13.56 MHz) oxygen plasma. The Gaussian beam microwave interferometry directly provides the line integrated electron density fluctuations. A system of two Langmuir probes measured the floating potential spatially (axial, radial) and temporally resolved. Hence, the floating potential fluctuation development is mapped within the discharge volume and provides a kind of discharge breathing and no wave propagation. Finally, it was measured the optical emission pattern of atomic oxygen during the fluctuation as well as the RF phase resolved optical emission intensity at selected phase position of the fluctuation by an intensified charge-coupled device camera. The deduced excitation rate pattern reveals the RF sheath dynamics and electron heating mechanisms, which is changing between low and high electronegativity during a fluctuation cycle. A perturbation calculation was taken into account using a global model with 15 elementary collision processes in the balance equations for the charged plasma species ( O2+, e , O-, O2- ) and a harmonic perturbation. The calculated frequencies agree with the experimentally observed frequencies. Whereby, the electron attachment/detachment processes are important for the generation of this instability.

  8. [Study of plasma temperature measurements for oxygen discharge].

    PubMed

    Li, Liu-Cheng; Wang, Zeng-Qiang; Li, Gu-Fu; Duo, Li-Ping

    2011-10-01

    A radio-frequency discharge setup was constructed by two shell-shaped copper electrodes and a 30 cm long pyrex glass tube (i. d. = 1.65 cm) to examine the gas temperature of oxygen plasma in electric discharge oxygen iodine laser. The discharge was supplied by a 500 watt, 13.56 MHz radio-frequency power. The gas pressure in the discharge cavity was 1 330 Pa. The temperature of oxygen discharge plasma was measured by using the P branch of O2 (b, v = 0) rotational emission spectrum. Two methods were used to deduce the oxygen gas temperature. They are Boltzman plotting method and computer simulating spectrum method, respectively. Gauss fitting method was used to distinguish spectrum peaks for lower resolution spectrum. The spectrum peak area was used to characterize the optical emission intensity. The gas temperature of oxygen discharge plasma was obtained by Boltzmann plotting method. Alternatively, the optical emission spectrum was simulated by computer modeling with spectrometer slit function which was obtained by He-Ne laser. Consequently, the gas temperature of oxygen plasma was obtained by comparing the computer simulating spectrum and the experimentally observed spectrum according to the least square fitting rule. The measurement results with the two methods agree well. It was concluded that the simple optical technique can be used conveniently in the temperature diagnostics of oxygen radio-frequency discharge plasma. PMID:22250527

  9. Laser frequency modulation with electron plasma

    NASA Technical Reports Server (NTRS)

    Burgess, T. J.; Latorre, V. R.

    1972-01-01

    When laser beam passes through electron plasma its frequency shifts by amount proportional to plasma density. This density varies with modulating signal resulting in corresponding modulation of laser beam frequency. Necessary apparatus is relatively inexpensive since crystals are not required.

  10. Cleaning Carbon Nanotubes by Use of Mild Oxygen Plasmas

    NASA Technical Reports Server (NTRS)

    Petkov, Mihail

    2006-01-01

    Experiments have shown that it is feasible to use oxygen radicals (specifically, monatomic oxygen) from mild oxygen plasmas to remove organic contaminants and chemical fabrication residues from the surfaces of carbon nanotubes (CNTs) and metal/CNT interfaces. A capability for such cleaning is essential to the manufacture of reproducible CNT-based electronic devices. The use of oxygen radicals to clean surfaces of other materials is fairly well established. However, previously, cleaning of CNTs and of graphite by use of oxygen plasmas had not been attempted because both of these forms of carbon were known to be vulnerable to destruction by oxygen plasmas. The key to success of the present technique is, apparently, to ensure that the plasma is mild . that is to say, that the kinetic and internal energies of the oxygen radicals in the plasma are as low as possible. The plasma oxygen-radical source used in the experiments was a commercial one marketed for use in removing hydrocarbons and other organic contaminants from vacuum systems and from electron microscopes and other objects placed inside vacuum systems. In use, the source is installed in a vacuum system and air is leaked into the system at such a rate as to maintain a background pressure of .0.56 torr (.75 Pa). In the source, oxygen from the air is decomposed into monatomic oxygen by radio-frequency excitation of a resonance of the O2 molecule (N2 is not affected). Hence, what is produced is a mild (non-energetic) oxygen plasma. The oxygen radicals are transported along with the air molecules in the flow created by the vacuum pump. In the experiments, exposure to the oxygen plasma in this system was shown to remove organic contaminants and chemical fabrication residues from several specimens. Many high-magnification scanning electron microscope (SEM) images of CNTs were taken before and after exposure to the oxygen plasma. As in the example shown in the figure, none of these images showed evidence of degradation

  11. Dynamics of ion bombardment-induced modifications of Si(001) at the radio-frequency-biased electrode in low-pressure oxygen plasmas: In situ spectroscopic ellipsometry and Monte Carlo study

    NASA Astrophysics Data System (ADS)

    Amassian, A.; Svec, M.; Desjardins, P.; Martinu, L.

    2006-09-01

    Low-pressure O2 plasma exposures were performed on c-Si(001) at a radio frequency (rf)-powered electrode in the presence of substrate self-biasing (VB) from VB=-60to-600V, in order to evaluate ion-surface interactions at the growth surface under ion bombardment conditions suitable for the fabrication of high quality optical coatings. The plasma-surface interactions were monitored in situ using real-time spectroscopic ellipsometry (RTSE), which reveals time- and ion-fluence-resolved information about depth-dependent modifications, such as damage and oxidation below the c-Si substrate surface. RTSE analysis indicates almost immediate damage formation (≪1s ) to a depth of a few nanometers below the surface after exposure to a low oxygen ion fluence (˜5×1014Ocm-2). Oxide growth is detected at intermediate fluence (˜1015-1016Ocm-2) and is attributed to O subplantation (shallow implantation); it forms near the surface of the target on top of an O-deficient interfacial damage layer (DL). Both layers experience a self-limiting growth behavior at high fluence (>1017cm-2) as oxide and DL thicknesses reach bias-dependent steady-state values, determined by the maximum ion penetration depth, which increases from ˜3.6to9.5nm for VB=-60to-600V. The in situ experimental study was complemented by Monte Carlo TRIDYN simulations based on the binary collision approximation, which were modified to calculate dynamic changes in the composition of a target exposed to a broad-energy ion source (rf plasma source) at high fluence. Simulation results are found to agree exceptionally well with experiment. In addition, they reveal that the 1.2-3.5-nm-thick DL formed in the steady-state regime is a result of (1) damage formation due to the presence of a small number of high energy O+ ions in the plasma environment, capable of penetrating and damaging up to 3nm deeper than the majority ion population (O2+), and (2) because of important surface motion resulting from oxidation

  12. Inductive coupled radio frequency plasma bridge neutralizer.

    PubMed

    Scholze, F; Tartz, M; Neumann, H

    2008-02-01

    A 13.56 MHz radio frequency plasma bridge neutralizer (rf-PBN) for ion thruster applications as well as ion beam surface processing of insulating materials is presented. The energy for the plasma excitation is inductively coupled into the plasma chamber. Because no components are located inside the plasma, the lifetime of the rf-PBN is expected to be very long. A compact tuning system adapts the input power to the plasma impedance. The electron current may be controlled over a wide range by the rf input power. An electron current of up to 1.6 A has been extracted. PMID:18315215

  13. Atomic Oxygen Durability Evaluation of Protected Polymers Using Thermal Energy Plasma Systems

    NASA Technical Reports Server (NTRS)

    Banks, Bruce A.; Rutledge, Sharon K.; Degroh, Kim K.; Stidham, Curtis R.; Gebauer, Linda; Lamoreaux, Cynthia M.

    1995-01-01

    The durability evaluation of protected polymers intended for use in low Earth orbit (LEO) has necessitated the use of large-area, high-fluence, atomic oxygen exposure systems. Two thermal energy atomic oxygen exposure systems which are frequently used for such evaluations are radio frequency (RF) plasma ashers and electron cyclotron resonance plasma sources. Plasma source testing practices such as ample preparation, effective fluence prediction, atomic oxygen flux determination, erosion measurement, operational considerations, and erosion yield measurements are presented. Issues which influence the prediction of in-space durability based on ground laboratory thermal energy plasma system testing are also addressed.

  14. Sub millimeter absorption spectroscopy of oxygen containing fluorocarbon etching plasmas

    NASA Astrophysics Data System (ADS)

    Benck, Eric; Siegrist, Karen

    2004-09-01

    The role of oxygen in fluorocarbon etching plasmas is investigated using sub millimeter wavelength absorption spectroscopy. The plasmas were created in a specially modified capacitively coupled Gaseous Electronics Conference (GEC) Reference Reactor with a commercial electrostatic chuck. Photoresist and SiO2 blanket coated wafers were etched in C_4F_8/O_2/Ar, C_5F_8/O_2/Ar, and C_4F_6/O_2/Ar discharges. The absolute density of various radicals (CF, CF_2, CHF_3, COF_2, CO, etc.) were measured as a function of the percentage of oxygen in the feed gas mixture using a sub millimeter source based on a 48x frequency multiplication chain. These results are also compared with C_xF_y/O_2/Xe mixtures.

  15. Transparency of Magnetized Plasma at Cyclotron Frequency

    SciTech Connect

    G. Shvets; J.S. Wurtele

    2002-03-14

    Electromagnetic radiation is strongly absorbed by a magnetized plasma if the radiation frequency equals the cyclotron frequency of plasma electrons. It is demonstrated that absorption can be completely canceled in the presence of a magnetostatic field of an undulator or a second radiation beam, resulting in plasma transparency at the cyclotron frequency. This effect is reminiscent of the electromagnetically induced transparency (EIT) of the three-level atomic systems, except that it occurs in a completely classical plasma. Unlike the atomic systems, where all the excited levels required for EIT exist in each atom, this classical EIT requires the excitation of the nonlocal plasma oscillation. The complexity of the plasma system results in an index of refraction at the cyclotron frequency that differs from unity. Lagrangian description was used to elucidate the physics and enable numerical simulation of the plasma transparency and control of group and phase velocity. This control naturally leads to applications for electromagnetic pulse compression in the plasma and electron/ion acceleration.

  16. Biochar activated by oxygen plasma for supercapacitors

    NASA Astrophysics Data System (ADS)

    Gupta, Rakesh Kumar; Dubey, Mukul; Kharel, Parashu; Gu, Zhengrong; Fan, Qi Hua

    2015-01-01

    Biochar, also known as black carbon, is a byproduct of biomass pyrolysis. As a low-cost, environmental-friendly material, biochar has the potential to replace more expensive synthesized carbon nanomaterials (e.g. carbon nanotubes) for use in future supercapacitors. To achieve high capacitance, biochar requires proper activation. A conventional approach involves mixing biochar with a strong base and baking at a high temperature. However, this process is time consuming and energy inefficient (requiring temperatures >900 °C). This work demonstrates a low-temperature (<150 °C) plasma treatment that efficiently activates a yellow pine biochar. Particularly, the effects of oxygen plasma on the biochar microstructure and supercapacitor characteristics are studied. Significant enhancement of the capacitance is achieved: 171.4 F g-1 for a 5-min oxygen plasma activation, in comparison to 99.5 F g-1 for a conventional chemical activation and 60.4 F g-1 for untreated biochar. This enhancement of the charge storage capacity is attributed to the creation of a broad distribution in pore size and a larger surface area. The plasma activation mechanisms in terms of the evolution of the biochar surface and microstructure are further discussed.

  17. A low-energy linear oxygen plasma source

    SciTech Connect

    Anders, Andre; Yushkov, Georgy Yu.

    2007-01-08

    A new version of a Constricted Plasma Source is described,characterized by all metal-ceramic construction, a linear slit exit of180 mm length, and cw-operation (typically 50 kHz) at an average power of1.5 kW. The plasma source is here operated with oxygen gas, producingstreaming plasma that contains mainly positive molecular and atomic ions,and to a much lesser degree, negative ions. The maximum total ion currentobtained was about 0.5 A. The fraction of atomic ions reached more than10 percent of all ions when the flow rate was less then 10 sccm O2,corresponding to a chamber pressure of about 0.5 Pa for the selectedpumping speed. The energy distribution functions of the different ionspecies were measured with a combinedmass spectrometer and energyanalyzer. The time-averaged distribution functions were broad and rangedfrom about 30eV to 90 eV at 200 kHz and higher frequencies, while theywere only several eV broad at 50 kHz and lower frequencies, with themaximum located at about 40 eV for the grounded anode case. This maximumwas shifted down to about 7 eV when the anode was floating, indicatingthe important role of the plasma potential for the ion energy for a givensubstrate potential. The source could be scaled to greater length and maybe useful for functionalization of surfaces and plasma-assisteddeposition of compound films.

  18. High Frequency Plasma Generators for Ion Thrusters

    NASA Technical Reports Server (NTRS)

    Divergilio, W. F.; Goede, H.; Fosnight, V. V.

    1981-01-01

    The results of a one year program to experimentally adapt two new types of high frequency plasma generators to Argon ion thrusters and to analytically study a third high frequency source concept are presented. Conventional 30 cm two grid ion extraction was utilized or proposed for all three sources. The two plasma generating methods selected for experimental study were a radio frequency induction (RFI) source, operating at about 1 MHz, and an electron cyclotron heated (ECH) plasma source operating at about 5 GHz. Both sources utilize multi-linecusp permanent magnet configurations for plasma confinement. The plasma characteristics, plasma loading of the rf antenna, and the rf frequency dependence of source efficiency and antenna circuit efficiency are described for the RFI Multi-cusp source. In a series of tests of this source at Lewis Research Center, minimum discharge losses of 220+/-10 eV/ion were obtained with propellant utilization of .45 at a beam current of 3 amperes. Possible improvement modifications are discussed.

  19. Plasma effects in high frequency radiative transfer

    SciTech Connect

    Alonso, C.T.

    1981-02-08

    This paper is intended as a survey of collective plasma processes which can affect the transfer of high frequency radiation in a hot dense plasma. We are rapidly approaching an era when this subject will become important in the laboratory. For pedagogical reasons we have chosen to examine plasma processes by relating them to a particular reference plasma which will consist of fully ionized carbon at a temperature kT=1 KeV (10/sup 70/K) and an electron density N = 3 x 10/sup 23/cm/sup -3/, (which corresponds to a mass density rho = 1 gm/cm/sup 3/ and an ion density N/sub i/ = 5 x 10/sup 22/ cm/sup -3/). We will consider the transport in such a plasma of photons ranging from 1 eV to 1 KeV in energy. Such photons will probably be frequently used as diagnostic probes of hot dense laboratory plasmas.

  20. Atmospheric oxygen plasma activation of silicon (100) surfaces

    SciTech Connect

    Habib, Sara B.; Gonzalez, Eleazar II; Hicks, Robert F.

    2010-05-15

    Silicon (100) surfaces were converted to a hydrophilic state with a water contact angle of <5 deg. by treatment with a radio frequency, atmospheric pressure helium, and oxygen plasma. A 2 in. wide plasma beam, operating at 250 W, 1.0 l/min O{sub 2}, 30 l/min He, and a source-to-sample distance of 3{+-}0.1 mm, was scanned over the sample at 100{+-}2 mm/s. Plasma oxidation of HF-etched silicon caused the dispersive component of the surface energy to decrease from 55.1 to 25.8 dyn/cm, whereas the polar component of the surface energy increased from 0.3 to 42.1 dyn/cm. X-ray photoelectron spectroscopy revealed that the treatment generated a monolayer of covalently bonded oxygen on the Si(100) surface 0.15{+-}0.10 nm thick. The surface oxidation kinetics have been measured by monitoring the change in water contact angle with treatment time, and are consistent with a process that is limited by the mass transfer of ground-state oxygen atoms to the silicon surface.

  1. High frequency plasma generator for ion thrusters

    NASA Technical Reports Server (NTRS)

    Goede, H.; Divergilio, W. F.; Fosnight, V. V.; Komatsu, G.

    1984-01-01

    The results of a program to experimentally develop two new types of plasma generators for 30 cm electrostatic argon ion thrusters are presented. The two plasma generating methods selected for this study were by radio frequency induction (RFI), operating at an input power frequency of 1 MHz, and by electron cyclotron heating (ECH) at an operating frequency of 5.0 GHz. Both of these generators utilize multiline cusp permanent magnet configurations for plasma confinement and beam profile optimization. The program goals were to develop a plasma generator possessing the characteristics of high electrical efficiency (low eV/ion) and simplicity of operation while maintaining the reliability and durability of the conventional hollow cathode plasma sources. The RFI plasma generator has achieved minimum discharge losses of 120 eV/ion while the ECH generator has obtained 145 eV/ion, assuming a 90% ion optical transparency of the electrostatic acceleration system. Details of experimental tests with a variety of magnet configurations are presented.

  2. Cutoff frequency of toroidal plasma waveguide

    SciTech Connect

    Zakeri-Khatir, H.; Aghamir, F. M.

    2015-02-15

    The cutoff frequencies of E and H-modes of empty and plasma filled toroidal waveguides are evaluated. The effects of space curvature and plasma density on cutoff frequencies for both modes are investigated. Using a suitable variable change, a scalar wave equation in the direction of propagation was obtained. The study indicates that the curvature in the direction of wave propagation in toroidal waveguide has an analogous effect as a straight waveguide filled with anisotropic media. The Rayleigh-Schrodinger perturbation method was employed to solve for cutoff frequencies in the first order of approximation. In the limit of small space curvature, the toroidal waveguide cutoff frequencies for both E and H-modes approach those of TM and TE modes of empty cylindrical waveguide with a radius equal to toroidal waveguide minor radius. The analysis shows that the curvature in the direction of propagation in toroidal waveguides leads to the removal of the degeneracy between E and H-modes.

  3. Low-Frequency Waves in Space Plasmas

    NASA Astrophysics Data System (ADS)

    Keiling, Andreas; Lee, Dong-Hun; Nakariakov, Valery

    2016-02-01

    Low-frequency waves in space plasmas have been studied for several decades, and our knowledge gain has been incremental with several paradigm-changing leaps forward. In our solar system, such waves occur in the ionospheres and magnetospheres of planets, and around our Moon. They occur in the solar wind, and more recently, they have been confirmed in the Sun's atmosphere as well. The goal of wave research is to understand their generation, their propagation, and their interaction with the surrounding plasma. Low-frequency Waves in Space Plasmas presents a concise and authoritative up-to-date look on where wave research stands: What have we learned in the last decade? What are unanswered questions? While in the past waves in different astrophysical plasmas have been largely treated in separate books, the unique feature of this monograph is that it covers waves in many plasma regions, including: Waves in geospace, including ionosphere and magnetosphere Waves in planetary magnetospheres Waves at the Moon Waves in the solar wind Waves in the solar atmosphere Because of the breadth of topics covered, this volume should appeal to a broad community of space scientists and students, and it should also be of interest to astronomers/astrophysicists who are studying space plasmas beyond our Solar System.

  4. Radio-frequency Plasma Sheath Studies

    NASA Astrophysics Data System (ADS)

    Hicks, Nathaniel

    2015-09-01

    The response of ion-electron plasma as well as two-component plasma to RF fields is studied via PIC simulation. In each case, the light species responds strongly to the RF and the heavy species does not. By varying the external electrode geometry, RF waveform, and driving voltage and frequency, light species of certain charge-to-mass ratios may experience a trapping effect within the RF structure. The space charge of this species creates a potential well for the oppositely-charged, heavy species. Simulation results are presented, as well as plans for experimental investigation of the same effect. Applications to plasma processes in which a plasma boundary is subjected to external RF fields are discussed.

  5. Frequency effects on the production of reactive oxygen species in atmospheric radio frequency helium-oxygen discharges

    SciTech Connect

    Zhang, Yuantao T.; He Jin

    2013-01-15

    Several experimental and computational studies have shown that increasing frequency can effectively enhance the discharge stability in atmospheric radio-frequency (rf) discharges, but the frequency effects on the reactivity of rf discharges, represented by the densities of reactive oxygen species (ROS), are still far from fully understood. In this paper, a one-dimensional fluid model with 17 species and 65 reactions taken into account is used to explore the influences of the driving frequency on the production and destruction of ROS in atmospheric rf helium-oxygen discharges. From the computational results, with an increase in the frequency the densities of ROS decrease always at a constant power density, however, in the relatively higher frequency discharges the densities of ROS can be effectively improved by increasing the input power density with an expanded oxygen admixture range, while the discharges operate in the {alpha} mode, and the numerical data also show the optimal oxygen admixture for ground state atomic oxygen, at which the peak atomic oxygen density can be obtained, increases with the driving frequency.

  6. High-frequency plasma-heating apparatus

    DOEpatents

    Brambilla, Marco; Lallia, Pascal

    1978-01-01

    An array of adjacent wave guides feed high-frequency energy into a vacuum chamber in which a toroidal plasma is confined by a magnetic field, the wave guide array being located between two toroidal current windings. Waves are excited in the wave guide at a frequency substantially equal to the lower frequency hybrid wave of the plasma and a substantially equal phase shift is provided from one guide to the next between the waves therein. For plasmas of low peripheral density gradient, the guides are excited in the TE.sub.01 mode and the output electric field is parallel to the direction of the toroidal magnetic field. For exciting waves in plasmas of high peripheral density gradient, the guides are excited in the TM.sub.01 mode and the magnetic field at the wave guide outlets is parallel to the direction of the toroidal magnetic field. The wave excited at the outlet of the wave guide array is a progressive wave propagating in the direction opposite to that of the toroidal current and is, therefore, not absorbed by so-called "runaway" electrons.

  7. Replacement of hydrogen peroxide cleaning with oxygen plasma

    NASA Astrophysics Data System (ADS)

    Adams, B. E.

    1992-03-01

    Comparison between the standard peroxide cleaning method and an oxygen plasma modified version was run on thin film bond monitors. The plasma modified version substituted oxygen plasma for the peroxide cleaning step in the process and reduced the DI rinse water temperature from 75 C to 25 C. A direct surface cleanliness comparison was made between the two cleaning methods using Auger spectroscopy. A beam lead and ribbon bonding experiment was also run on plasma-cleaned networks. Results of both experiments indicate that plasma cleaning is superior to peroxide cleaning and that reliable bonding can be done on plasma-cleaned thin film networks.

  8. Generation of singlet oxygen for an oxygen-iodine laser in a radio-frequency discharge

    SciTech Connect

    Braginskii, O V; Vasil'eva, A N; Klopovskii, K S; Kovalev, A S; Lopaev, D V; Mankelevich, Yu A; Popov, N A; Rakhimov, Aleksandr T; Rakhimova, T V

    2005-01-31

    The generation of singlet oxygen (SO) in a radio-frequency discharge (13.56 MHz) in the gas flow was investigated experimentally and theoretically. The oxygen pressure was varied from 2 to 20 Torr and the energy deposition in gas from 10 to 2000 J mmol{sup -1}. The saturation of the SO concentration with increasing the energy deposition was shown to arise from the three-body process of SO quenching by atomic oxygen. Removing atomic oxygen allowed a 2.5-fold increase in the ultimate SO concentration at the discharge output. For an oxygen pressure of 15 Torr, the SO fraction amounts to 10%. (active media. lasers)

  9. Analysis of blood plasma at terahertz frequencies

    NASA Astrophysics Data System (ADS)

    Cherkasova, O. P.; Nazarov, M. M.; Angeluts, A. A.; Shkurinov, A. P.

    2016-01-01

    Terahertz time-domain spectroscopy in the 0.05-2.5 THz frequency range was employed to analyze blood plasma samples obtained from laboratory animals with experimental diabetes and from healthy controls. It was found that transmission and reflection coefficients of samples from rats with diabetes differed significantly from control values in both amplitude and phase. The cause of the detected differences is discussed with respect to variation in the terahertz response of water.

  10. Plasma processing of superconducting radio frequency cavities

    NASA Astrophysics Data System (ADS)

    Upadhyay, Janardan

    The development of plasma processing technology of superconducting radio frequency (SRF) cavities not only provides a chemical free and less expensive processing method, but also opens up the possibility for controlled modification of the inner surfaces of the cavity for better superconducting properties. The research was focused on the transition of plasma etching from two dimensional flat surfaces to inner surfaces of three dimensional (3D) structures. The results could be applicable to a variety of inner surfaces of 3D structures other than SRF cavities. Understanding the Ar/Cl2 plasma etching mechanism is crucial for achieving the desired modification of Nb SRF cavities. In the process of developing plasma etching technology, an apparatus was built and a method was developed to plasma etch a single cell Pill Box cavity. The plasma characterization was done with the help of optical emission spectroscopy. The Nb etch rate at various points of this cavity was measured before processing the SRF cavity. Cylindrical ring-type samples of Nb placed on the inner surface of the outer wall were used to measure the dependence of the process parameters on plasma etching. The measured etch rate dependence on the pressure, rf power, dc bias, temperature, Cl2 concentration and diameter of the inner electrode was determined. The etch rate mechanism was studied by varying the temperature of the outer wall, the dc bias on the inner electrode and gas conditions. In a coaxial plasma reactor, uniform plasma etching along the cylindrical structure is a challenging task due to depletion of the active radicals along the gas flow direction. The dependence of etch rate uniformity along the cylindrical axis was determined as a function of process parameters. The formation of dc self-biases due to surface area asymmetry in this type of plasma and its variation on the pressure, rf power and gas composition was measured. Enhancing the surface area of the inner electrode to reduce the

  11. RFQ (radio-frequency quadrupole) accelerators for heating thermonuclear plasmas

    SciTech Connect

    Stokes, R.H.; Wangler, T.P.; Crandall, K.R.

    1987-01-01

    The radio-frequency quadrupole (RFQ) accelerator has been developed to generate high-current ion beams for a wide variety of applications. It has also been suggested that this type of accelerator could be used to produce megawatt ion beams to heat thermonuclear reactor plasmas. For a tokamak reactor, an RFQ accelerator can be designed to provide negative deuterium ions that are neutralized before injection through the tokamak magentic field. Also, it may be possible to use singly charged, positive, heavier ions that trasverse the magnetic field with minimal deflection and then become multiply ionized upon striking the tokamak plasma. We present preliminary RFQ beam-dynamics designs for both deuterium and oxygen ions.

  12. Growth Enhancement of Radish Sprouts Induced by Low Pressure O2 Radio Frequency Discharge Plasma Irradiation

    NASA Astrophysics Data System (ADS)

    Kitazaki, Satoshi; Koga, Kazunori; Shiratani, Masaharu; Hayashi, Nobuya

    2012-01-01

    We studied growth enhancement of radish sprouts (Raphanus sativus L.) induced by low pressure O2 radio frequency (RF) discharge plasma irradiation. The average length of radish sprouts cultivated for 7 days after O2 plasma irradiation is 30-60% greater than that without irradiation. O2 plasma irradiation does not affect seed germination. The experimental results reveal that oxygen related radicals strongly enhance growth, whereas ions and photons do not.

  13. Cold atmospheric pressure plasma jets as sources of singlet delta oxygen for biomedical applications

    SciTech Connect

    Sousa, J. S.; Niemi, K.; Cox, L. J.; Algwari, Q. Th.; Gans, T.; O'Connell, D.

    2011-06-15

    Absolute densities of singlet delta oxygen (SDO) molecules were measured using infrared optical emission spectroscopy in the flowing effluents of two different atmospheric-pressure plasma jets (APPJs): a capacitively coupled radio-frequency-driven jet (rf-APPJ) and a lower frequency kilohertz-driven dielectric barrier discharge jet. The plasma jets were operated in helium, with small admixtures of molecular oxygen (O{sub 2} < 2%). High absolute SDO densities of up to 6.2 x 10{sup 15} cm{sup -3} were measured at approximately 10 cm downstream. The rf-APPJ seems to be much more efficient in producing SDO. The influence of different parameters, such as gas flows and mixtures and power coupled to the plasmas, on the production of SDO by the two APPJs has been investigated. Despite the considerable differences between the two plasma jets (excitation frequency, electric field direction, inter-electrode distance, plasma propagation), similar dependencies on the oxygen admixture and on the dissipated power were found in both APPJs. However, opposite trends were observed for the gas flow dependence. The results presented in this paper show that the control of the external operating conditions of each APPJ enables the tailoring of the SDO composition of both plasma effluents. This provides scope to tune the plasma jets for desired applications, e.g., in biomedicine.

  14. Surface functionalization of organic materials by weakly ionized highly dissociated oxygen plasma

    NASA Astrophysics Data System (ADS)

    Vesel, A.; Mozetic, M.

    2009-04-01

    A review on surface modification of different polymers by treatment in oxygen plasma is presented. Plasma is created in a high frequency inductively coupled gaseous discharge at the power of about 200 W. In such discharge created in pure oxygen, plasma with the following parameters is obtained: the electron temperature of about 50.000 K, the charged particle density around 1x1016 m-3, and the neutral oxygen atom density of the order of 1021 m-3. A huge flux of neutral oxygen atoms on the surface of samples exposed to plasma assures for rapid interaction with polymer materials. The modification of surface properties of the following polymers was studied: polyethyleneterephthalate (PET), polyethersulphone (PES), polyphenylenesulfide (PPS), Nylon 6 polyamide (PA6), polytetrafluoroethylene (PTFE), polystyrene (PS), polypropylene (PP) and cellulose (ink-jet paper and textile). The polymer samples were treated for 3 s in oxygen plasma at a pressure of 75 Pa where the O-atom density was the largest at 4x1021 m-3. The appearance of the functional groups on the surface of the samples was monitored by high resolution X-ray photoelectron spectroscopy (XPS). The results show that oxygen plasma treatment is an effective tool for surface modification. On all polymer surfaces increased concentration of oxygen is detected. The high resolution C1s peaks indicate formation of several new oxygen-containing functional groups. On all polymers groups like C-O, C=O and O=C-O are observed. The concentration of these groups depends on the type of polymer. The highest uptake of oxygen by the polymer was found for cellulose and the lowest for polypropylene. The only exception was polymer PTFE where practically no chemical changes were observed after plasma treatment.

  15. Molecular oxygen detection using frequency modulation diode laser spectroscopy

    NASA Technical Reports Server (NTRS)

    Wang, Liang-Guo; Sachse, Glen

    1990-01-01

    A high-sensitivity spectroscopic measurement of O2 using two-tone frequency modulation spectroscopy with a GaAlAs diode laser is presented. An oxygen sensor based on this technique would be non-intrusive, compact and possess high sensitivity and fast time response.

  16. Radio Frequency Plasma Applications for Space Propulsion

    SciTech Connect

    Baity, F.W., Jr.; Barber, G.C.; Carter, M.D.; Chang-Diaz, F.R.; Goulding, R.H.; Ilin, A.V.; Jaeger, E.F.; Sparks, D.O.; Squire, J.P.

    1999-09-13

    Recent developments in solid-state radio frequency (RF) power technologies allow for the practical consideration of RF heated plasmas for space propulsion. These technologies permit the use of any electrical power source, de-couple the power and propellant sources, and allow for the effcient use of both the propellant mass and power. Effcient use of the propellant is obtained by expelling the rocket exhaust at the highest possible velocity, which can be orders of magnitude higher than those achieved in chemical rockets. Handling the hot plasma exhaust requires the use of magnetic nozzles, and the basic physics of ion detachment from the magnetic eld is discussed. The plasma can be generated by RF using helicon waves to heat electrons. Further direct heating of the ions helps to reduce the line radiation losses, and the magnetic geometry is tailored to allow ion cyclotron resonance heating. RF eld and ion trajectory calculations are presented to give a reasonably self-consistent picture of the ion acceleration process.

  17. FREQUENCY CONTROL OF RF HEATING OF GASEOUS PLASMA

    DOEpatents

    Herold, E.W.

    1962-09-01

    This invention relates to the heating of gaseous plasma by radiofrequency ion-cyclotron resonance heating. The cyclotron resonance frequencies are varied and this invention provides means for automatically controlling the frequency of the radiofrequency to maximize the rate of heating. To this end, a servo-loop is provided to sense the direction of plasma heating with frequency and a control signal is derived to set the center frequency of the radiofrequency energy employed to heat the plasma. (AEC)

  18. Long-distance oxygen plasma sterilization: Effects and mechanisms

    NASA Astrophysics Data System (ADS)

    Liu, Hongxia; Chen, Jierong; Yang, Liqing; Zhou, Yuan

    2008-01-01

    The distribution of electrons, ions and oxygen radicals in long-distance oxygen plasma and the germicidal effect (GE) of Escherichia coli on the surface of medical poly(tetrafluoroethylene) (PTFE) film were studied. The quantity of protein leakage and the production of lipid peroxide in bacterial suspension as well as the state of DNA were measured after sterilization to analyse the inactivation mechanisms. The results showed that the concentration of electrons and ions decreased rapidly with increasing the distance from the center of induction coil, which approximated to 0 at 30 cm, whereas the concentration of oxygen radicals reduced slowly, i.e. decreased 30% within 40 cm. GE value reached 3.42 in the active discharge zone (0 cm) and exceeded 3.32 within 40 cm when plasma treatment parameters were set as follows: plasma rf power at 100 W, treatment time at 60 s and oxygen flux at 40 cm 3/min. Fast etching action on cell membrane by electrons, ions and attacking polyunsaturation fatty acid (PUFA) in cell membrane by oxygen radicals are primary reasons of oxygen plasma sterilization in the active discharge and the afterglow zone, respectively. The GE of UV radiation in long-distance oxygen plasma is feebleness.

  19. Modification of the Surface Properties of Polyimide Films using POSS Deposition and Oxygen Plasma Exposure

    NASA Technical Reports Server (NTRS)

    Wohl, Christopher J.; Belcher, Marcus A.; Ghose, Sayata; Connell, John W.

    2008-01-01

    Topographically rich surfaces were generated by spray-coating organic solutions of a polyhedral oligomeric silsesquioxane, octakis (dimethylsilyloxy) silsesquioxane (POSS), on Kapton HN films and exposing them to radio frequency generated oxygen plasma. Changes in both surface chemistry and topography were observed. High-resolution scanning electron microscopy indicated substantial modification of the POSS-coated polyimide surface topographies as a result of oxygen plasma exposure. Water contact angles varied from 104 deg for unexposed POSS-coated surfaces to approximately 5 deg, for samples exposed for 5 h. Modulation of the dispersive and polar contributions to the surface energy was determined using van Oss Good Chaudhury theory.

  20. Oxygen plasmas used to synthesize superoxides

    NASA Technical Reports Server (NTRS)

    Hollahan, J. R.; Wydeven, T.

    1972-01-01

    Production of alkali metal superoxides by interaction of molecular oxygen with alkali metals or their salts is discussed. Diagram of reactor to show components and operating principles is provided. Analysis of chemical reactions involved is developed.

  1. The influence of substrate material on bacteria sterilization in an oxygen plasma glow discharge

    NASA Astrophysics Data System (ADS)

    Cvelbar, U.; Vujosevic, D.; Vratnica, Z.; Mozetic, M.

    2006-08-01

    A critical approach to plasma sterilization is presented with the aim of sterilizing biocompatible materials such as TiO2 and polymer implants. Oxygen plasma was applied to sterilize glass and aluminium samples containing Bacillus subtilis spores. Sterilization was performed with a low pressure weakly ionized oxygen plasma created with a RF generator with an output power of 300 W and frequency 27.12 MHz. The density of charged particles, density of neutral oxygen atoms and the electron temperature were about 1 × 1016 m-3, 1.5 × 1022 m-3 and 5 eV, respectively. The sterilization effects were observed by SEM and by bacterial cultivation. It was found that the surface recombination of O-atoms plays an important role, since it causes temperature changes in the substrate. The sterilization efficiency increased with increasing plasma exposure time. The results showed that the sterilization efficiency is not necessarily just the effect of oxygen plasma radical interactions, but also of the sample heating due to radical interaction with the substrate. Plasma sterilization should be done differently according to the substrate material used for sterilization.

  2. Atomic oxygen patterning from a biomedical needle-plasma source

    NASA Astrophysics Data System (ADS)

    Kelly, Seán; Turner, Miles M.

    2013-09-01

    A "plasma needle" is a cold plasma source operating at atmospheric pressure. Such sources interact strongly with living cells, but experimental studies on bacterial samples show that this interaction has a surprising pattern resulting in circular or annular killing structures. This paper presents numerical simulations showing that this pattern occurs because biologically active reactive oxygen and nitrogen species are produced dominantly where effluent from the plasma needle interacts with ambient air. A novel solution strategy is utilised coupling plasma produced neutral (uncharged) reactive species to the gas dynamics solving for steady state profiles at the treated biological surface. Numerical results are compared with experimental reports corroborating evidence for atomic oxygen as a key bactericidal species. Surface losses are considered for interaction of plasma produced reactants with reactive solid and liquid interfaces. Atomic oxygen surface reactions on a reactive solid surface with adsorption probabilities above 0.1 are shown to be limited by the flux of atomic oxygen from the plasma. Interaction of the source with an aqueous surface showed hydrogen peroxide as the dominant species at this interface.

  3. Atomic oxygen patterning from a biomedical needle-plasma source

    SciTech Connect

    Kelly, Seán; Turner, Miles M.

    2013-09-28

    A “plasma needle” is a cold plasma source operating at atmospheric pressure. Such sources interact strongly with living cells, but experimental studies on bacterial samples show that this interaction has a surprising pattern resulting in circular or annular killing structures. This paper presents numerical simulations showing that this pattern occurs because biologically active reactive oxygen and nitrogen species are produced dominantly where effluent from the plasma needle interacts with ambient air. A novel solution strategy is utilised coupling plasma produced neutral (uncharged) reactive species to the gas dynamics solving for steady state profiles at the treated biological surface. Numerical results are compared with experimental reports corroborating evidence for atomic oxygen as a key bactericidal species. Surface losses are considered for interaction of plasma produced reactants with reactive solid and liquid interfaces. Atomic oxygen surface reactions on a reactive solid surface with adsorption probabilities above 0.1 are shown to be limited by the flux of atomic oxygen from the plasma. Interaction of the source with an aqueous surface showed hydrogen peroxide as the dominant species at this interface.

  4. Dual radio frequency plasma source: Understanding via electrical asymmetry effect

    SciTech Connect

    Bora, B.; Bhuyan, H.; Favre, M.; Wyndham, E.; Wong, C. S.

    2013-04-21

    On the basis of the global model, the influences of driving voltage and frequency on electron heating in geometrically symmetrical dual capacitively coupled radio frequency plasma have been investigated. Consistent with the experimental and simulation results, non-monotonic behavior of dc self bias and plasma heating with increasing high frequency is observed. In addition to the local maxima of plasma parameters for the integer values of the ratio between the frequencies ({xi}), ourstudies also predict local maxima for odd integer values of 2{xi} as a consequence of the electrical asymmetry effect produced by dual frequency voltage sources.

  5. Tailoring surface properties of polyethylene separator by low pressure 13.56 MHz RF oxygen plasma glow discharge

    NASA Astrophysics Data System (ADS)

    Li, Chun; Liang, Chia-Han; Huang, Chun

    2016-01-01

    Low-pressure plasma surface modification in a radio-frequency capacitively coupled glow discharge of oxygen gas was carried out to induce polar functional groups onto polyethylene membrane separator surfaces to enhance its hydrophilicity. The surface changes in surface free energy were monitored by static contact angle measurement. A significant increase in the surface energy of polyethylene membrane separators caused by the oxygen gas plasma modifications was observed. The static water contact angle of the plasma-modified membrane separator significantly decreased with the increase in treatment duration and plasma power. An obvious increase in the surface energy of the membrane separators owing to the oxidative effect of oxygen-gas-plasma modifications was also observed. Optical emission spectroscopy was carried out to analyze the chemical species generated by oxygen gas plasma surface modification. The variations in the surface morphology and chemical structure of the separators were confirmed by scanning electron microscopy, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy (XPS). XPS showed significantly higher surface concentrations of oxygen functional groups in the oxygen-gas-plasma-modified polymeric separator surfaces than in the unmodified polymeric separator surface. The experimental results show the important role of chemical species in the interaction between oxygen gas plasmas and the separator surface, which can be controlled by surface modification to tailor the hydrophilicity of the separator.

  6. Low-frequency fluctuations in plasma magnetic fields

    SciTech Connect

    Cable, S.; Tajima, T.

    1992-02-01

    It is shown that even a non-magnetized plasma with temperature T sustains zero-frequency magnetic fluctuations in thermal equilibrium. Fluctuations in electric and magnetic fields, as well as in densities, are computed. Four cases are studied: a cold, gaseous, isotropic, non-magnetized plasma; a cold, gaseous plasma in a uniform magnetic field; a warm, gaseous plasma described by kinetic theory; and a degenerate electron plasma. For the simple gaseous plasma, the fluctuation strength of the magnetic field as a function of frequency and wavenumber is calculated with the aid of the fluctuation-dissipation theorem. This calculation is done for both collisional and collisionless plasmas. The magnetic field fluctuation spectrum of each plasma has a large zero-frequency peak. The peak is a Dirac {delta}-function in the collisionless plasma; it is broadened into a Lorentzian curve in the collisional plasma. The plasma causes a low frequency cutoff in the typical black-body radiation spectrum, and the energy under the discovered peak approximates the energy lost in this cutoff. When the imposed magnetic field is weak, the magnetic field were vector fluctuation spectra of the two lowest modes are independent of the strength of the imposed field. Further, these modes contain finite energy even when the imposed field is zero. It is the energy of these modes which forms the non-magnetized zero-frequency peak of the isotropic plasma. In deriving these results, a simple relationship between the dispersion relation and the fluctuation power spectrum of electromagnetic waves if found. The warm plasma is shown, by kinetic theory, to exhibit a zero-frequency peak in its magnetic field fluctuation spectrum as well. For the degenerate plasma, we find that electric field fluctuations and number density fluctuations vanish at zero frequency; however, the magnetic field power spectrum diverges at zero frequency.

  7. Material Compatibility of Medical Sterilizer Using Oxygen Plasma

    NASA Astrophysics Data System (ADS)

    Tanaka, Hiroshi; Ono, Reoto; Hayashi, Nobuya; Hanada, Yasushi; Noda, Minoru; Goto, Masaaki

    2015-09-01

    Material compatibility of oxygen plasma sterilizer is investigated comparing with hydrogen peroxide (H2O2) sterilizers and a gaseous H2O2 sterilizer. Organic materials such as ABS, PE, PP, and PET are used as sample materials, and are irradiated by active oxygen species produced in oxygen plasma. After plasma irradiation, surface of the sample materials is observed using a scanning electron microscope and FTIR spectroscopy. Strengths of the organic materials are evaluated by the tension test. Also, H2O2 plasma sterilizer and a gaseous H2O2 sterilizer those are commercially available are utilized to compare the material compatibility, especially organic compounds. The ABS resin becomes slightly soft after irradiation by both plasmas and gaseous H2O2. Also, PET material becomes soften by each sterilization treatment. Decrease of peak heights of CH around 1200 and 1730 cm-1 and increase of that of OH at 3300 cm-1 in FTIR spectra indicates the oxidation of ABS resin by both plasma and gaseous H2O2. In the case of PET material, treatment by the plasma has not modified chemical composition but changed the crystal structure. The gaseous H2O2 is completely friendly for the PET material.

  8. Electron-vibration relaxation in oxygen plasmas

    NASA Astrophysics Data System (ADS)

    Laporta, V.; Heritier, K. L.; Panesi, M.

    2016-06-01

    An ideal chemical reactor model is used to study the vibrational relaxation of oxygen molecules in their ground electronic state, X3 Σg-, in presence of free electrons. The model accounts for vibrational non-equilibrium between the translational energy mode of the gas and the vibrational energy mode of individual molecules. The vibrational levels of the molecules are treated as separate species, allowing for non-Boltzmann distributions of their population. The electron and vibrational temperatures are varied in the range [0-20,000] K. Numerical results show a fast energy transfer between oxygen molecules and free electron, which causes strong deviation of the vibrational distribution function from Boltzmann distribution, both in heating and cooling conditions. Comparison with Landau-Teller model is considered showing a good agreement for electron temperature range [2000-12,000] K. Finally analytical fit of the vibrational relaxation time is given.

  9. Oxygen impurity radiation from Tokamak-like plasmas

    NASA Technical Reports Server (NTRS)

    Rogerson, J. E.; Davis, J.; Jacobs, V. L.

    1977-01-01

    We have constructed a nonhydrodynamic coronal model for calculating radiation from impurity atoms in a heated plasma. Some recent developments in the calculation of dielectronic recombination rate coefficients and collisional excitation rate coefficients are included. The model is applied to oxygen impurity radiation during the first few milliseconds of a TFR Tokamak plasma discharge, and good agreement with experimental results is obtained. Estimates of total line and continuum radiation from the oxygen impurity are given. It is shown that impurity radiation represents a considerable energy loss.

  10. Theoretical approach for plasma series resonance effect in geometrically symmetric dual radio frequency plasma

    SciTech Connect

    Bora, B.; Bhuyan, H.; Favre, M.; Wyndham, E.; Chuaqui, H.

    2012-02-27

    Plasma series resonance (PSR) effect is well known in geometrically asymmetric capacitively couple radio frequency plasma. However, plasma series resonance effect in geometrically symmetric plasma has not been properly investigated. In this work, a theoretical approach is made to investigate the plasma series resonance effect and its influence on Ohmic and stochastic heating in geometrically symmetric discharge. Electrical asymmetry effect by means of dual frequency voltage waveform is applied to excite the plasma series resonance. The results show considerable variation in heating with phase difference between the voltage waveforms, which may be applicable in controlling the plasma parameters in such plasma.

  11. Experimental investigations of driving frequency effect in low-pressure capacitively coupled oxygen discharges

    SciTech Connect

    Liu, Jia; Liu, Yong-Xin; Liu, Gang-Hu; Gao, Fei; Wang, You-Nian

    2015-04-14

    The effect of driving frequency on the electron density is investigated in low-pressure capacitively coupled oxygen plasmas by utilizing a floating hairpin probe. The power absorbed by the plasma is investigated and it is found that the power lost in the matching network can reach 50% or higher under certain conditions. The effect of driving frequency on the electron density is studied from two aspects, i.e., constant absorbed power and electrode voltage. In the former case, the electron density increases with the driving frequency increasing from 13.56 to 40.68 MHz and slightly changes depending on the gas pressures with the frequency further increasing to 100 MHz. In the latter case, the electron density rapidly increases when the driving frequency increases from 13.56 to 40.68 MHz, and then decreases with the frequency further increasing to 100 MHz. The electron series resonance is observed at 40.68 MHz and can be attributed to the higher electron density. And the standing wave effect also plays an important role in increasing electron density at 100 MHz and 2.6 Pa.

  12. Experimental investigations of driving frequency effect in low-pressure capacitively coupled oxygen discharges

    NASA Astrophysics Data System (ADS)

    Liu, Jia; Liu, Yong-Xin; Liu, Gang-Hu; Gao, Fei; Wang, You-Nian

    2015-04-01

    The effect of driving frequency on the electron density is investigated in low-pressure capacitively coupled oxygen plasmas by utilizing a floating hairpin probe. The power absorbed by the plasma is investigated and it is found that the power lost in the matching network can reach 50% or higher under certain conditions. The effect of driving frequency on the electron density is studied from two aspects, i.e., constant absorbed power and electrode voltage. In the former case, the electron density increases with the driving frequency increasing from 13.56 to 40.68 MHz and slightly changes depending on the gas pressures with the frequency further increasing to 100 MHz. In the latter case, the electron density rapidly increases when the driving frequency increases from 13.56 to 40.68 MHz, and then decreases with the frequency further increasing to 100 MHz. The electron series resonance is observed at 40.68 MHz and can be attributed to the higher electron density. And the standing wave effect also plays an important role in increasing electron density at 100 MHz and 2.6 Pa.

  13. Oxide growth on silicides in oxygen plasma

    NASA Astrophysics Data System (ADS)

    Climent, A.; Enard, J. P.; Lavernhe, B.; Perriere, J.; Straboni, A.; Vuillermoz, B.; Levy, D.

    We have shown the possibility of growing thick oxide films on refractory metal silicides by plasma oxidation in the 500-900°C temperature range. Thin layers of Si-rich silicides TiSi x and WSi y ( x, y > 2) deposited onto Si or SiO 2 by cosputtering have been oxidized in and RF plasma at floating potential. The oxide growth rate, composition and thickness, and the depth distribution of cations were determined by the complementary use of nuclear reaction analysis and RBS. We have found that silicon in excess in the films diffuses through the silicide towards the surface to form a SiO 2 passivating overlayer. The Si oxide growth rate is diffusion limited, while for long treatment oxidation of the silicide itself occurs with the formation of an oxide mixture (metal oxide and SiO 2).

  14. Fluorophore-based sensor for oxygen radicals in processing plasmas

    SciTech Connect

    Choudhury, Faraz A.; Shohet, J. Leon; Sabat, Grzegorz; Sussman, Michael R.; Nishi, Yoshio

    2015-11-15

    A high concentration of radicals is present in many processing plasmas, which affects the processing conditions and the properties of materials exposed to the plasma. Determining the types and concentrations of free radicals present in the plasma is critical in order to determine their effects on the materials being processed. Current methods for detecting free radicals in a plasma require multiple expensive and bulky instruments, complex setups, and often, modifications to the plasma reactor. This work presents a simple technique that detects reactive-oxygen radicals incident on a surface from a plasma. The measurements are made using a fluorophore dye that is commonly used in biological and cellular systems for assay labeling in liquids. Using fluorometric analysis, it was found that the fluorophore reacts with oxygen radicals incident from the plasma, which is indicated by degradation of its fluorescence. As plasma power was increased, the quenching of the fluorescence significantly increased. Both immobilized and nonimmobilized fluorophore dyes were used and the results indicate that both states function effectively under vacuum conditions. The reaction mechanism is very similar to that of the liquid dye.

  15. Surface energy increase of oxygen-plasma-treated PET

    SciTech Connect

    Cioffi, M.O.H.; Voorwald, H.J.C.; Mota, R.P

    2003-03-15

    Prosthetic composite is a widely used biomaterial that satisfies the criteria for application as an organic implant without adverse reactions. Polyethylene therephthalate (PET) fiber-reinforced composites have been used because of the excellent cell adhesion, biodegradability and biocompatibility. The chemical inertness and low surface energy of PET in general are associated with inadequate bonds for polymer reinforcements. It is recognized that the high strength of composites, which results from the interaction between the constituents, is directly related to the interfacial condition or to the interphase. A radio frequency plasma reactor using oxygen was used to treat PET fibers for 5, 20, 30 and 100 s. The treatment conditions were 13.56 MHz, 50 W, 40 Pa and 3.33x10{sup -7} m{sup 3}/s. A Rame-Hart goniometer was used to measure the contact angle and surface energy variation of fibers treated for different times. The experimental results showed contact angle values from 47 deg. to 13 deg. and surface energies from 6.4x10{sup -6} to 8.3x10{sup -6} J for the range of 5 to 100 s, respectively. These results were confirmed by the average ultimate tensile strength of the PET fiber/ polymethylmethacrylate (PMMA) matrix composite tested in tensile mode and by scanning electron microscopy.

  16. Poly (ethylene terephthalate) decomposition process in oxygen plasma; emission spectroscopic and surface analysis for oxygen-plasma reaction

    NASA Astrophysics Data System (ADS)

    Kumagai, Hidetoshi; Hiroki, Denbo; Fujii, Nobuyuki; Kobayashi, Takaomi

    2004-01-01

    Emission spectroscopy was applied to observe the reaction process of poly (ethylene terephthalate) (PET) in an oxygen (O2) plasma generated by a microwave discharge. As the PET was exposed in the O2 plasma flow, light emitted from the PET surface was monitored. In the diagnosis measurement, several emission peaks assigned to the Hα atomic line at 652 nm, Hβ at 486 nm, OH (2Σ-->2Π) transition near 244-343 nm and CO (b3 Σ-->a3 Σ) near 283-370 nm were observed and measured at various discharge times. These results indicated that after the plasma etching, the PET sample was decomposed by the oxygen plasma reaction, and then, hydrogen abstraction and carbon oxidation processes. We also observed the time profile of oxygen atom, as the atom-emission intensity at 777 nm was monitored. As Hβ atomic and OH molecule lines appeared in the presence of PET, the O atom intensity was significantly reduced. In the surface analysis on Fourier transform infrared and x-ray photoelectron spectroscopy measurements, it was found that for the PET surface treated by O2 plasma containing excited atomic oxygen species, ester bands were broken and carbonization formed on the PET surface. .

  17. Minimizing permeability of PET substrates using Oxygen plasma treatment

    NASA Astrophysics Data System (ADS)

    Sanaee, Z.; Mohajerzadeh, S.; Zand, K.; Gard, F. S.; Pajouhi, H.

    2011-01-01

    Surface plasma treatment in a reactive ion etching system is used to observe a considerable decrease in permeability of polyethylene terephthalate to gases. The effects of oxygen plasma on the surface properties and morphology of PET polymers are investigated by scanning electron microscopy (SEM), x-ray photo-electron spectroscopy (XPS) and atomic force microscopy (AFM). In addition, the optical transmission properties of the treated samples have been investigated corroborating the findings of SEM and AFM analyses. Moreover, the penetration of air through the treated substrates was investigated using a vacuum test. The treated PET substrates can be used to realize flexible plasma display panels.

  18. Effects of oxygen plasma etching on Sb2Te3 explored by torque detected quantum oscillations

    NASA Astrophysics Data System (ADS)

    Yan, Yuan; Heintze, Eric; Pracht, Uwe S.; Blankenhorn, Marian; Dressel, Martin

    2016-04-01

    De Haas-van Alphen measurements evidence that oxygen plasma etching strongly affects the properties of the three-dimensional topological insulator Sb2Te3. The quantum oscillations in magnetization down to low temperature (T ≥ 2 K) and high magnetic field (B ≤ 7 T) have been systematically investigated using a high-sensitive cantilever torque magnetometer. The effective mass and the oscillation frequency obtained from de Haas-van Alphen measurements first increase and then decrease as the oxygen plasma etching time increases from 0 to 12 min, corresponding to an up- and down-shift of the Dirac point. We establish the cantilever torque magnetometer as a powerful contactless tool to investigate the oxygen sensitivity of the surface state in topological insulators.

  19. High-frequency Probing Diagnostic for Hall Current Plasma Thrusters

    SciTech Connect

    A.A. Litvak; Y. Raitses; N.J. Fisch

    2001-10-25

    High-frequency oscillations (1-100 MHz) in Hall thrusters have apparently eluded significant experimental scrutiny. A diagnostic setup, consisting of a single Langmuir probe, a special shielded probe connector-positioner, and an electronic impedance-matching circuit, was successfully built and calibrated. Through simultaneous high-frequency probing of the Hall thruster plasma at multiple locations, high-frequency plasma waves have been identified and characterized for various thruster operating conditions.

  20. Oxygen plasma power dependence on ZnO grown on porous silicon substrates by plasma-assisted molecular beam epitaxy

    SciTech Connect

    Nam, Giwoong; Kim, Min Su; Kim, Do Yeob; Yim, Kwang Gug; Kim, Soaram; Kim, Sung-O.; Lee, Dong-Yul; Leem, Jae-Young; Department of Nano Systems Engineering, Center for Nano Manufacturing, Inje University, Gimhae, Gyungnam 621-749

    2012-10-15

    ZnO thin films were deposited on porous silicon by plasma-assisted molecular beam epitaxy using different radio frequency power settings. Optical emission spectrometry was applied to study the characteristics of the oxygen plasma, and the effects of the radio frequency power on the properties of the ZnO thin films were evaluated by X-ray diffraction, scanning electron microscopy, and photoluminescence. The grain sizes for radio frequency powers of 100, 200, and 300 W were 46, 48, and 62 nm, respectively. In addition, the photoluminescence intensities of the ultraviolet and the visible range increased at 300 W, because the density of the atomic oxygen transitions increased. The quality of the ZnO thin films was enhanced, but the deep-level emission peaks increased with increasing radio frequency power. The structural and optical properties of the ZnO thin films were improved at the radio frequency power of 300 W. Moreover, the optical properties of the ZnO thin films were improved with porous silicon, instead of Si.

  1. Plasma effects on the generation of reactive oxygen and nitrogen species in cancer cells in-vitro exposed by atmospheric pressure pulsed plasma jets

    NASA Astrophysics Data System (ADS)

    Kim, Sun Ja; Chung, T. H.

    2015-08-01

    Atmospheric pressure pulsed helium plasma jets are utilized for plasma-cell interactions. The effect of operating parameters such as applied voltage, pulse repetition frequency, and duty ratio on the generation of specific reactive oxygen and nitrogen species in gas and liquid phases and within cells is investigated. The apoptotic changes detected by terminal deoxynucleotidyl transferase (TdT)-mediated dUTP nick-end labeling assay in cells caused by plasma exposure are observed to correlate well with the levels of extracellular and intracellular reactive oxygen and nitrogen species.

  2. Antioxidants may Attenuate Plasma Erythropoietin Decline after Hyperbaric Oxygen Diving.

    PubMed

    Mutzbauer, T S; Schneider, M; Neubauer, B; Weiss, M; Tetzlaff, K

    2015-11-01

    According to previous studies, plasma erythropoietin (EPO) may decrease after hyperbaric oxygen exposure due to oxidative stress. It is hypothesized that the decrease of EPO can be attenuated by oxygen free radical scavengers.The aim of the present study was to evaluate whether EPO plasma levels can be influenced by oral application of vitamin C and E before repeated hyperbaric oxygen exposure during diving. 16 healthy male police task force divers performed 3 morning dives on oxygen within a regular diving schedule on 3 consecutive days. They were randomized into either the placebo group or the vitamin group, receiving 1 g ascorbic acid and 600 IU D-α-tocopherol orally 60 min before the dive. Blood samples for EPO measurement were taken on days 1, 2, and 3 at T1, T3 and T5 60 min before and at T2, T4 and T6 60 min after each dive, respectively. A moderate decrease of EPO was observed beginning at T3 until T6 in the placebo group. The EPO concentrations in the vitamin group did not show relevant variations compared to baseline. Radical scavenging vitamins C and D may counteract hyperbaric oxygen related mechanisms reducing EPO production in hyperbaric oxygen exposure during diving. PMID:26258821

  3. Nonlinear frequency coupling in dual radio-frequency driven atmospheric pressure plasmas

    SciTech Connect

    Waskoenig, J.; Gans, T.

    2010-05-03

    Plasma ionization, and associated mode transitions, in dual radio-frequency driven atmospheric pressure plasmas are governed through nonlinear frequency coupling in the dynamics of the plasma boundary sheath. Ionization in low-power mode is determined by the nonlinear coupling of electron heating and the momentary local plasma density. Ionization in high-power mode is driven by electron avalanches during phases of transient high electric fields within the boundary sheath. The transition between these distinctly different modes is controlled by the total voltage of both frequency components.

  4. Band gap effects of hexagonal boron nitride using oxygen plasma

    SciTech Connect

    Sevak Singh, Ram; Leong Chow, Wai; Yingjie Tay, Roland; Hon Tsang, Siu; Mallick, Govind; Tong Teo, Edwin Hang

    2014-04-21

    Tuning of band gap of hexagonal boron nitride (h-BN) has been a challenging problem due to its inherent chemical stability and inertness. In this work, we report the changes in band gaps in a few layers of chemical vapor deposition processed as-grown h-BN using a simple oxygen plasma treatment. Optical absorption spectra show a trend of band gap narrowing monotonically from 6 eV of pristine h-BN to 4.31 eV when exposed to oxygen plasma for 12 s. The narrowing of band gap causes the reduction in electrical resistance by ∼100 fold. The x-ray photoelectron spectroscopy results of plasma treated hexagonal boron nitride surface show the predominant doping of oxygen for the nitrogen vacancy. Energy sub-band formations inside the band gap of h-BN, due to the incorporation of oxygen dopants, cause a red shift in absorption edge corresponding to the band gap narrowing.

  5. Measurements of the Plasma Parameters and Low Frequency Oscillations in the Fisk Plasma Source

    NASA Technical Reports Server (NTRS)

    Thomas, Edward, Jr.; Wallace, Kent; Lampkin, Gregory; Watson, Michael

    1998-01-01

    A new plasma device, the Fisk Plasma Source (FPS), has been developed at Fisk University. This plasma device is used to study the physics of low temperature plasmas and plasma-material interactions. The FPS device is a stainless steel vacuum 6-way cross vacuum vessel with at 10-inch inner diameter. Low temperature argon plasmas are generated using DC glow discharge and thermionic filament techniques. Spatial profiles of the plasma density, plasma potential, and electron temperature are measured using Langmuir probes. We present initial experimental measurements of density and temperature profiles in the FPS device. Experimental and theoretical studies of low frequency oscillations observed in the FPS device are also presented.

  6. Characteristics of ITO films with oxygen plasma treatment for thin film solar cell applications

    SciTech Connect

    Park, Yong Seob; Kim, Eungkwon; Hong, Byungyou; Lee, Jaehyoeng

    2013-12-15

    Graphical abstract: The effect of O{sub 2} plasma treatment on the surface and the work function of ITO films. - Highlights: • ITO films were prepared on the glass substrate by RF magnetron sputtering method. • Effects of O{sub 2} plasma treatment on the properties of ITO films were investigated. • The work function of ITO film was changed from 4.67 to 5.66 eV by plasma treatment. - Abstract: The influence of oxygen plasma treatment on the electro-optical and structural properties of indium-tin-oxide films deposited by radio frequency magnetron sputtering method were investigated. The films were exposed at different O{sub 2} plasma powers and for various durations by using the plasma enhanced chemical vapor deposition (PECVD) system. The resistivity of the ITO films was almost constant, regardless of the plasma treatment conditions. Although the optical transmittance of ITO films was little changed by the plasma power, the prolonged treatment slightly increased the transmittance. The work function of ITO film was changed from 4.67 eV to 5.66 eV at the plasma treatment conditions of 300 W and 60 min.

  7. Plasma discharge characteristics in compact SF6 radio-frequency plasma source for plasma etching application

    NASA Astrophysics Data System (ADS)

    Motomura, Taisei; Takahashi, Kazunori; Kasashima, Yuji; Uesugi, Fumihiko; Ando, Akira

    2015-09-01

    In order to create a compact plasma etching reactor, plasma discharge characteristics in compact SF6 radio-frequency (RF) plasma source which has a chamber diameter of 40 mm have been studied. Convergent magnetic field configuration produced by a solenoid coil and a permanent magnet located behind substrate is employed for efficient plasma transport downstream of plasma source. A discharge characteristics with the changes in relative emission intensity of fluorine atom of FI at 703.7 nm in compact SF6 plasma source are discussed: the dependence of relative emission intensity on the magnetic field strength, the RF input power, and the mass flow rate of the SF6 gas. The relative emission intensity was significantly increased when the RF input power is ~150 W. We present the fundamental etching performance (especially etching rate) of compact plasma source, and then the etching rate of 0.1-1.0 μm/min was obtained under the condition of a RF input power of 50-200 W, a mass flow rate of SF6 of 5.5 sccm and a bias RF power of 20 W. The results of test etching will be shown in presentation.

  8. Cyclotron Mode Frequency Shifts in Multi-Species Ion Plasmas

    NASA Astrophysics Data System (ADS)

    Affolter, Matthew

    2014-10-01

    Plasmas exhibit a variety of cyclotron modes, which are used in a broad range of devices to manipulate and diagnose charged particles. Here we discuss cyclotron modes in trapped plasmas with a single sign of charge. Collective effects and electric fields shift these cyclotron mode frequencies away from the ``bare'' cyclotron frequencies Ωs ≡ qB /ms c for each species s. These electric fields may arise from applied trap potentials, from space charge including collective effects, and from image charge in the trap walls. We will describe a new laser-thermal cyclotron spectroscopy technique, applied to well-diagnosed pure ion plasmas. This technique enables detailed observations of cos (mθ) surface cyclotron modes with m = 0 , 1, and 2 in near rigid-rotor multi-species ion plasmas. For each species s, we observe cyclotron mode frequency shifts which are dependent on the plasma density through the E × B rotation frequency, and on the charge concentration of species s, in close agreement with recent theory. This includes the novel m = 0 radial ``breathing'' mode, which generates no external electric field except at the plasma ends. These cyclotron frequencies can be used to determine the plasma E × B rotation frequency and the species charge concentrations, in close agreement with our laser diagnostics. Here, this plasma characterization permits a determination of the ``bare'' cyclotron frequencies to an accuracy of 2 parts in 104. These new results give a physical basis for the ``space charge'' and ``amplitude'' calibration equations of cyclotron mass spectroscopy, widely used in molecular chemistry and biology. Also, at high temperatures there is preliminary evidence that radially-standing electrostatic Bernstein waves couple to the surface cyclotron modes, producing new resonant frequencies. Supported by NSF/DOE Partnership grants PHY-0903877 and DE-SC0002451.

  9. Effect of Radio Frequency Waves on Plasma Instabilities

    NASA Astrophysics Data System (ADS)

    Sen, S.

    2015-11-01

    The effect of Radio Frequency waves on low frequency plasma instabilities and turbulence is studied. It is shown that the ponderomotive force can stabilize or destabilize instabilities depending on the power deposition profile and no RF induced flow generation hypothesis is required. Its possible consequence on space and fusion plasma will be discussed. Collaborations with George Vahala from William & Mary, Julio Martinell from UNAM and Atsushi Fukuyama from Kyoto University are acknowledged.

  10. Oxygen plasma resistant phosphine oxide containing imide/arylene copolymers

    NASA Technical Reports Server (NTRS)

    Jensen, Brian J.

    1993-01-01

    A series of oxygen plasma resistant imide/arylene ether copolymers were prepared by reacting anhydride-terminated poly(amide acids) and amine-terminated polyarylene ethers containing phosphine oxide units. Inherent viscosities for these copolymers ranged from 0.42 to 0.80 dL/g. After curing, the resulting copolymers had glass transition temperatures ranging from 224 C to 228 C. Solution cast films of the block copolymers were tough and flexible with tensile strength, tensile moduli, and elongation at break up to 16.1 ksi, 439 ksi, and 23 percent, respectively at 25 C and 9.1 ksi, 308 ksi and 97 percent, respectively at 150 C. The copolymers show a significant improvement in resistance to oxygen plasma when compared to the commercial polyimide Kapton. The imide/arylene ether copolymers containing phosphine oxide units are suitable as coatings, films, adhesives, and composite matrices.

  11. Surface plasma source with saddle antenna radio frequency plasma generator.

    PubMed

    Dudnikov, V; Johnson, R P; Murray, S; Pennisi, T; Piller, C; Santana, M; Stockli, M; Welton, R

    2012-02-01

    A prototype RF H(-) surface plasma source (SPS) with saddle (SA) RF antenna is developed which will provide better power efficiency for high pulsed and average current, higher brightness with longer lifetime and higher reliability. Several versions of new plasma generators with small AlN discharge chambers and different antennas and magnetic field configurations were tested in the plasma source test stand. A prototype SA SPS was installed in the Spallation Neutron Source (SNS) ion source test stand with a larger, normal-sized SNS AlN chamber that achieved unanalyzed peak currents of up to 67 mA with an apparent efficiency up to 1.6 mA∕kW. Control experiments with H(-) beam produced by SNS SPS with internal and external antennas were conducted. A new version of the RF triggering plasma gun has been designed. A saddle antenna SPS with water cooling is fabricated for high duty factor testing. PMID:22380221

  12. Surface plasma source with saddle antenna radio frequency plasma generator

    SciTech Connect

    Dudnikov, V.; Johnson, R. P.; Murray, S.; Pennisi, T.; Piller, C.; Santana, M.; Stockli, M.; Welton, R.

    2012-02-15

    A prototype RF H{sup -} surface plasma source (SPS) with saddle (SA) RF antenna is developed which will provide better power efficiency for high pulsed and average current, higher brightness with longer lifetime and higher reliability. Several versions of new plasma generators with small AlN discharge chambers and different antennas and magnetic field configurations were tested in the plasma source test stand. A prototype SA SPS was installed in the Spallation Neutron Source (SNS) ion source test stand with a larger, normal-sized SNS AlN chamber that achieved unanalyzed peak currents of up to 67 mA with an apparent efficiency up to 1.6 mA/kW. Control experiments with H{sup -} beam produced by SNS SPS with internal and external antennas were conducted. A new version of the RF triggering plasma gun has been designed. A saddle antenna SPS with water cooling is fabricated for high duty factor testing.

  13. Coupled microwave ECR and radio-frequency plasma source for plasma processing

    DOEpatents

    Tsai, Chin-Chi; Haselton, Halsey H.

    1994-01-01

    In a dual plasma device, the first plasma is a microwave discharge having its own means of plasma initiation and control. The microwave discharge operates at electron cyclotron resonance (ECR), and generates a uniform plasma over a large area of about 1000 cm.sup.2 at low pressures below 0.1 mtorr. The ECR microwave plasma initiates the second plasma, a radio frequency (RF) plasma maintained between parallel plates. The ECR microwave plasma acts as a source of charged particles, supplying copious amounts of a desired charged excited species in uniform manner to the RF plasma. The parallel plate portion of the apparatus includes a magnetic filter with static magnetic field structure that aids the formation of ECR zones in the two plasma regions, and also assists in the RF plasma also operating at electron cyclotron resonance.

  14. Coupled microwave ECR and radio-frequency plasma source for plasma processing

    DOEpatents

    Tsai, C.C.; Haselton, H.H.

    1994-03-08

    In a dual plasma device, the first plasma is a microwave discharge having its own means of plasma initiation and control. The microwave discharge operates at electron cyclotron resonance (ECR), and generates a uniform plasma over a large area of about 1000 cm[sup 2] at low pressures below 0.1 mtorr. The ECR microwave plasma initiates the second plasma, a radio frequency (RF) plasma maintained between parallel plates. The ECR microwave plasma acts as a source of charged particles, supplying copious amounts of a desired charged excited species in uniform manner to the RF plasma. The parallel plate portion of the apparatus includes a magnetic filter with static magnetic field structure that aids the formation of ECR zones in the two plasma regions, and also assists in the RF plasma also operating at electron cyclotron resonance. 4 figures.

  15. Laser Diagnostics of Atomic Hydrogen and Oxygen Production in RF and Microwave Plasma Discharges

    NASA Astrophysics Data System (ADS)

    Preppernau, Bryan Lee

    1993-01-01

    The research for this thesis involved the application of two-photon allowed laser-induced fluorescence (TALIF) to the study of atomic hydrogen and oxygen production in industrial scale radio-frequency and microwave plasma discharge apparatus. Absolute atomic hydrogen concentration profiles were measured in a Gaseous Electronics Conference Reference Cell installed at Wright-Patterson AFB, Ohio operating with a simple H_2 discharge. Two -dimensional atomic hydrogen concentration profiles were also measured in an ASTEX HPMM microwave plasma diamond deposition reactor during actual diamond growth. In addition, absolute atomic oxygen concentrations were measured in the ASTEX system. Particular attention was paid to refining the concentration calibration technique and in determining a correction to account for the collisional quenching of excited state fluorescence in high pressure gases.

  16. Oxygen Plasma Modification of Poss-Coated Kapton(Registered TradeMark) HN Films

    NASA Technical Reports Server (NTRS)

    Wohl, C. J.; Belcher, M. A.; Ghose, S.; Connell, J. W.

    2008-01-01

    The surface energy of a material depends on both surface composition and topographic features. In an effort to modify the surface topography of Kapton(Registered TradeMark) HN film, organic solutions of a polyhedral oligomeric silsesquioxane, octakis(dimethylsilyloxy)silsesquioxane (POSS), were spray-coated onto the Kapton(Registered TradeMark) HN surface. Prior to POSS application, the Kapton(Registered TradeMark) HN film was activated by exposure to radio frequency (RF)-generated oxygen plasma. After POSS deposition and solvent evaporation, the films were exposed to various durations of RF-generated oxygen plasma to create a topographically rich surface. The modified films were characterized using optical microscopy, attenuated total reflection infrared (ATR-IR) spectroscopy, and high-resolution scanning electron microscopy (HRSEM). The physical properties of the modified films will be presented.

  17. Optical emission study of radio-frequency excited toluene plasma.

    PubMed

    Lee, Szetsen; Liu, Shiao-Jun; Liang, Rui-Ji

    2008-12-25

    UV-visible emission spectra of radio-frequency (rf) excited toluene plasma were studied. Benzyl radicals as well as toluene monomer and excimer were observed in toluene plasma. It was found that the intensities, peak positions, and linewidths of monomer and excimer emission bands exhibit strong dependence on rf power and plasma processing time. This can be ascribed to photochemical reactions in plasma. Gas-chromatographic analysis of the deposition products from toluene plasma indicated that the main component was bibenzyl. Spectroscopic evidence has shown that the bibenzyl molecule was formed by the coupling reaction between two benzyl radicals in plasma. The spectroscopic characteristics of toluene monomer and excimer are correlated with a kinetic model in plasma. PMID:19049320

  18. Optical Frequency Domain Visualization of Electron Beam Driven Plasma Wakefields

    NASA Astrophysics Data System (ADS)

    Zgadzaj, Rafal; Downer, M. C.; Muggli, Patric; Yakimenko, Vitaly; Babzien, Marcus; Kusche, Karl; Fedurin, Mikhail

    2010-11-01

    Beam-driven plasma wakefield accelerators (PWFA), such as the ``plasma afterburner,'' are a promising approach for significantly increasing the particle energies of conventional accelerators. The study and optimization of PWFA would benefit from an experimental correlation between the parameters of the drive bunch, the accelerated bunch and the corresponding, accelerating plasma wave structure. However, the plasma wave structure has not yet been observed directly in PWFA. We will report our current work on noninvasive optical Frequency Domain Interferometric (FDI) and Holographic (FDH) visualization of beam-driven plasma waves. Both techniques employ two laser pulses (probe and reference) co-propagating with the particle drive-beam and its plasma wake. The reference pulse precedes the drive bunch, while the probe overlaps the plasma wave and maps its longitudinal and transverse structure. The experiment is being developed at the BNL/ATF Linac to visualize wakes generated by two and multi-bunch drive beams.

  19. Operating a radio-frequency plasma source on water vapor.

    PubMed

    Nguyen, Sonca V T; Foster, John E; Gallimore, Alec D

    2009-08-01

    A magnetically enhanced radio-frequency (rf) plasma source operating on water vapor has an extensive list of potential applications. In this work, the use of a rf plasma source to dissociate water vapor for hydrogen production is investigated. This paper describes a rf plasma source operated on water vapor and characterizes its plasma properties using a Langmuir probe, a residual gas analyzer, and a spectrometer. The plasma source operated first on argon and then on water vapor at operating pressures just over 300 mtorr. Argon and water vapor plasma number densities differ significantly. In the electropositive argon plasma, quasineutrality requires n(i) approximately = n(e), where n(i) is the positive ion density. But in the electronegative water plasma, quasineutrality requires n(i+) = n(i-) + n(e). The positive ion density and electron density of the water vapor plasma are approximately one and two orders of magnitude lower, respectively, than those of argon plasma. These results suggest that attachment and dissociative attachment are present in electronegative water vapor plasma. The electron temperature for this water vapor plasma source is between 1.5 and 4 eV. Without an applied axial magnetic field, hydrogen production increases linearly with rf power. With an axial magnetic field, hydrogen production jumps to a maximum value at 500 W and then saturates with rf power. The presence of the applied axial magnetic field is therefore shown to enhance hydrogen production. PMID:19725651

  20. Measuring ionospheric electron density using the plasma frequency probe

    SciTech Connect

    Jensen, M.D.; Baker, K.D. )

    1992-02-01

    During the past decade, the plasma frequency probe (PFP) has evolved into an accurate, proven method of measuring electron density in the ionosphere above about 90 km. The instrument uses an electrically short antenna mounted on a sounding rocket that is immersed in the plasma and notes the frequency where the antenna impedance is large and nonreactive. This frequency is closely related to the plasma frequency, which is a direct function of free electron concentration. The probe uses phase-locked loop technology to follow a changing electron density. Several sections of the plasma frequency probe circuitry are unique, especially the voltage-controlled oscillator that uses both an electronically tuned capacitor and inductor to give the wide tuning range needed for electron density measurements. The results from two recent sounding rocket flights (Thunderstorm II and CRIT II) under vastly different plasma conditions demonstrate the capabilities of the PFP and show the importance of in situ electron density measurements of understanding plasma processes. 9 refs.

  1. Electromagnetic radiation trapped in the magnetosphere above the plasma frequency

    NASA Technical Reports Server (NTRS)

    Gurnett, D. A.; Shaw, R. R.

    1973-01-01

    An electromagnetic noise band is frequently observed in the outer magnetosphere by the Imp 6 spacecraft at frequencies from about 5 to 20 kHz. This noise band generally extends throughout the region from near the plasmapause boundary to near the magnetopause boundary. The noise typically has a broadband field strength of about 5 microvolts/meter. The noise band often has a sharp lower cutoff frequency at about 5 to 10 kHz, and this cutoff has been identified as the local electron plasma frequency. Since the plasma frequency in the plasmasphere and solar wind is usually above 20 kHz, it is concluded that this noise must be trapped in the low-density region between the plasmapause and magnetopause boundaries. The noise bands often contain a harmonic frequency structure which suggests that the radiation is associated with harmonics of the electron cyclotron frequency.

  2. Reactive oxygen species controllable non-thermal helium plasmas for evaluation of plasmid DNA strand breaks

    NASA Astrophysics Data System (ADS)

    Young Kim, Jae; Lee, Dong-Hoon; Ballato, John; Cao, Weiguo; Kim, Sung-O.

    2012-11-01

    Non-thermal, oxygen-rich helium plasmas were investigated to achieve an enhanced reactive oxygen species concentration at low voltage driving conditions. A non-thermal plasma device was fabricated based on a theta-shaped tube, and its potential was investigated for use in topological alteration of plasmid DNA. The optical emission spectra of the plasma showed that the oxygen flow affected the plasma properties, even though an oxygen plasma was not produced. The plasmid DNA strand breaks became more significant with the addition of oxygen flow to the helium in a single hollow, theta-shaped tube with other experimental conditions being unchanged.

  3. Variable dual-frequency electrostatic wave launcher for plasma applications.

    PubMed

    Jorns, Benjamin; Sorenson, Robert; Choueiri, Edgar

    2011-12-01

    A variable tuning system is presented for launching two electrostatic waves concurrently in a magnetized plasma. The purpose of this system is to satisfy the wave launching requirements for plasma applications where maximal power must be coupled into two carefully tuned electrostatic waves while minimizing erosion to the launching antenna. Two parallel LC traps with fixed inductors and variable capacitors are used to provide an impedance match between a two-wave source and a loop antenna placed outside the plasma. Equivalent circuit analysis is then employed to derive an analytical expression for the normalized, average magnetic flux density produced by the antenna in this system as a function of capacitance and frequency. It is found with this metric that the wave launcher can couple to electrostatic modes at two variable frequencies concurrently while attenuating noise from the source signal at undesired frequencies. An example based on an experiment for plasma heating with two electrostatic waves is used to demonstrate a procedure for tailoring the wave launcher to accommodate the frequency range and flux densities of a specific two-wave application. This example is also used to illustrate a method based on averaging over wave frequencies for evaluating the overall efficacy of the system. The wave launcher is shown to be particularly effective for the illustrative example--generating magnetic flux densities in excess of 50% of the ideal case at two variable frequencies concurrently--with a high adaptability to a number of plasma dynamics and heating applications. PMID:22225213

  4. Simulation of Plasma Characteristics for Inductively Coupled Argon Plasma Using Dual-Frequency Antennas

    NASA Astrophysics Data System (ADS)

    Li, Xue-Chun; Sun, Xiao-Yan; Wang, You-Nian

    2014-10-01

    A large-area wafer size is necessary for plasma processing in the micro-electronics industry. However, it is one of the most important issues to obtain uniform plasma over a large-area substrate in addition to high-density plasmas for the plasma processing. Recently, the experimental study on the dual-frequency inductively coupled plasma (ICP) has been reported as a mean of improving the plasma uniformity over the large-area substrate. In this work, we develop a self-consistent method combined with the electromagnetic theory and fluid model to simulate the plasma characteristics for dual-frequency inductively coupled argon plasma. In the model, the ICP source consists of two planar-spiral coils. We investigate the plasma uniformity problem by adjusting the parameters of the two coils, such as the RF current, the position of the coils and the RF frequency ratio. It was found that the uniformity of the ion density over the wafer is improved with dual-frequency antennas comparing with a single-frequency antenna. The plasma uniformity increases when the coils are located farther from the centre of the ICP source. It is consistent with the experimental study. This work was supported by the National Natural Science Foundation of China (No. 11175034, No. 11075029).

  5. Optical emission spectroscopy characterization of oxygen plasma during degradation of Escherichia coli

    SciTech Connect

    Vujosevic, D.; Mozetic, M.; Cvelbar, U.; Krstulovic, N.; Milosevic, S.

    2007-05-15

    Optical emission spectroscopy was applied for plasma characterization during sterilization of substrates contaminated with bacteria. The amount of 10{sup 10}/ml cells of Escherichia coli was carefully applied to glass substrates and exposed to oxygen plasma glow discharge at different pressures between 30 and 200 Pa. Plasma was created in a glass discharge tube by an inductively coupled rf generator at the frequency of 27.12 MHz and output power of about 250 W. The electron temperature and plasma density were estimated with a double Langmuir probe. They were between 3 and 5 eV and 2 and 35x10{sup 15} m{sup -3}. Density of neutral oxygen atoms was measured with a catalytic probe, and was between 2 and 6x10{sup 21} m{sup -3}. Optical emission spectroscopy was performed with a low resolution spectrometer. The emission from carbon monoxide and nitrogen molecules was used to monitor the evolution of bacteria degradation. Both signals expressed a well defined maximum corresponding to peak erosion of bacteria by plasma radicals. As the sterilization was accomplished, both CO and N{sub 2} lines fell below the detection limit of the spectrometer. The bacteria degradation was also monitored by scanning electron microscope (SEM) and culturing. The SEM images corresponded well with the evolution of CO and N{sub 2} lines so the optical emission spectroscopy found a reliable tool for monitoring the sterilization process.

  6. Optical emission spectroscopy characterization of oxygen plasma during degradation of Escherichia coli

    NASA Astrophysics Data System (ADS)

    Vujošević, D.; Mozetič, M.; Cvelbar, U.; Krstulović, N.; Milošević, S.

    2007-05-01

    Optical emission spectroscopy was applied for plasma characterization during sterilization of substrates contaminated with bacteria. The amount of 1010/ml cells of Escherichia coli was carefully applied to glass substrates and exposed to oxygen plasma glow discharge at different pressures between 30 and 200Pa. Plasma was created in a glass discharge tube by an inductively coupled rf generator at the frequency of 27.12MHz and output power of about 250W. The electron temperature and plasma density were estimated with a double Langmuir probe. They were between 3 and 5eV and 2 and 35×1015m-3. Density of neutral oxygen atoms was measured with a catalytic probe, and was between 2 and 6×1021m-3. Optical emission spectroscopy was performed with a low resolution spectrometer. The emission from carbon monoxide and nitrogen molecules was used to monitor the evolution of bacteria degradation. Both signals expressed a well defined maximum corresponding to peak erosion of bacteria by plasma radicals. As the sterilization was accomplished, both CO and N2 lines fell below the detection limit of the spectrometer. The bacteria degradation was also monitored by scanning electron microscope (SEM) and culturing. The SEM images corresponded well with the evolution of CO and N2 lines so the optical emission spectroscopy found a reliable tool for monitoring the sterilization process.

  7. Surface modification of argon/oxygen plasma treated vulcanized ethylene propylene diene polymethylene surfaces for improved adhesion with natural rubber

    NASA Astrophysics Data System (ADS)

    Basak, Ganesh C.; Bandyopadhyay, Abhijit; Neogi, Sudarsan; Bhowmick, Anil K.

    2011-01-01

    Vulcanized ethylene propylene diene polymethylene (EPDM) rubber surface was treated in a radio frequency capacitatively coupled low pressure argon/oxygen plasma to improve adhesion with compounded natural rubber (NR) during co-vulcanization. The plasma modified surfaces were analyzed by means of contact angle measurement, surface energy, attenuated total reflection-infrared spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, energy dispersive X-ray sulfur mapping and atomic force microscopy. Several experimental variables such as plasma power, length of exposure time and composition of the argon-oxygen gas mixture were considered. It was delineated that plasma treatment changed both surface composition and roughness, and consequently increased peel strength. The change in surface composition was mainly ascribed to the formation of C-O and -Cdbnd O functional groups on the vulcanized surfaces. A maximum of 98% improvement in peel strength was observed after plasma treatment.

  8. Treatment Characteristics of Polysaccharides and Endotoxin Using Oxygen Plasma Produced by RF Discharge

    SciTech Connect

    Kitazaki, Satoshi; Hayashi, Nobuya; Goto, Masaaki

    2010-10-13

    Treatment of polysaccharides and endotoxin were attempted using oxygen plasma produced by RF discharge. Oxygen radicals observed by optical light emission spectra are factors of decomposition of polysaccharides and endotoxin. Fourier transform infrared spectra indicate that most of chemical bonds in the polysaccharides are dissociated after irradiation of the oxygen plasma. Also, the decomposition rate of endotoxin was approximately 90% after irradiation of the oxygen plasma for 180 min.

  9. High-frequency instability of the sheath-plasma resonance

    NASA Technical Reports Server (NTRS)

    Stenzel, R. L.

    1989-01-01

    Coherent high frequency oscillations near the electron plasma frequency (omega approx. less than omega sub p) are generated by electrodes with positive dc bias immersed in a uniform Maxwellian afterglow plasma. The instability occurs at the sheath-plasma resonance and is driven by a negative RF sheath resistance associated with the electron inertia in the diode-like electron-rich sheath. With increasing dc bias, i.e., electron transit time, the instability exhibits a hard threshold, downward frequency pulling, line broadening and copious harmonics. The fundamental instability is a bounded oscillation due to wave evanescence, but the harmonics are radiated as electromagnetic waves from the electrodes acting like antennas. Wavelength and polarization measurements confirm the emission process. Electromagnetic waves are excited by electrodes of various geometries (planes, cylinders, spheres) which excludes other radiation mechanisms such as orbitrons or beam-plasma instabilities. The line broadening mechanism was identified as a frequency modulation via the electron transit time by dynamic ions. Ion oscillations at the sheath edge give rise to burst-like RF emissions. These laboratory observations of a new instability are important for antennas in space plasmas, generation of coherent beams with diodes, and plasma diagnostics.

  10. Microwave radiation measurements near the electron plasma frequency of the NASA Lewis bumpy torus plasma

    NASA Technical Reports Server (NTRS)

    Mallavarpu, R.; Roth, J. R.

    1978-01-01

    Microwave emission near the electron plasma frequency was observed, and its relation to the average electron density and the dc toroidal magnetic field was examined. The emission was detected using a spectrum analyzer and a 50 omega miniature coaxial probe. The radiation appeared as a broad amplitude peak that shifted in frequency as the plasma parameters were varied. The observed radiation scanned an average plasma density ranging from 10 million/cu cm to 8 hundred million/cu cm. A linear relation was observed betweeen the density calculated from the emission frequency and the average plasma density measured with a microwave interferometer. With the aid of a relative density profile measurement of the plasma, it was determined that the emissions occurred from the outer periphery of the plasma.

  11. Plasma Characteristics Using Superimposed Dual Frequency Inductively Coupled Plasma Source for Next Generation Device Processing.

    PubMed

    Lee, Seung Min; Lee, Chul Hee; Kim, Tae Hyung; Yeom, Geun Young; Kim, Kyong Nam

    2015-11-01

    U-shaped inductively coupled plasma (ICP) source was investigated as a linear plasma source for the next generation roll-to-toll flexible display processing. For the radio frequency power to the source, the dual frequency composed of 13.56 MHz and 2 MHz was used and the effect of dual frequency to the U-shaped ICP source on the plasma density, electron temperature, and plasma uniformity was investigated. As the operating condition, 200 mTorr Ar was used without operating turbo pumps. The use of superimposed dual frequency composed of 13.56 MHz + 2 MHz instead the single frequency of 13.56 MHz increased the plasma density slightly at the same total power. In addition, the addition of 2 MHz rf power to 0.4 kW while maintaining 1 kW 13.56 MHz rf power not only decreased electron temperature but also improved both the plasma uniformity and the process uniformity measured by photoresist etching. Therefore, by using the dual frequency to the U-shaped ICP source, not only the plasma density but also plasma uniformity could be improved in addition to the decrease of possible damage to the substrate. PMID:26726573

  12. High-frequency extensions of magnetorotational instability in astrophysical plasmas

    SciTech Connect

    Mikhailovskii, A. B.; Lominadze, J. G.; Churikov, A. P.; Pustovitov, V. D.; Erokhin, N. N.; Tsypin, V. S.; Galvao, R. M. O.

    2008-08-15

    High-frequency extensions of magnetorotational instability driven by the Velikhov effect beyond the standard magnetohydrodynamic (MHD) regime are studied. The existence of the well-known Hall regime and a new electron inertia regime is demonstrated. The electron inertia regime is realized for a lesser plasma magnetization of rotating plasma than that in the Hall regime. It includes the subregime of nonmagnetized electrons. It is shown that, in contrast to the standard MHD regime and the Hall regime, magnetorotational instability in this subregime can be driven only at positive values of dln{Omega}/dlnr, where {Omega} is the plasma rotation frequency and r is the radial coordinate. The permittivity of rotating plasma beyond the standard MHD regime, including both the Hall regime and the electron inertia regime, is calculated.

  13. Artificial plasma formed by connected metallic wires at infrared frequencies

    NASA Astrophysics Data System (ADS)

    Silveirinha, Mário G.

    2009-01-01

    In this work, we investigate the influence of the plasmonic properties of metal and the effect of metal loss in the effective-medium properties of wire media formed by an array of connected rods at infrared frequencies. Using homogenization techniques, it is demonstrated that the plasmonic properties of metals may enable the design of artificial plasmas that mimic more closely the behavior of a continuous isotropic medium with negative permittivity. It is shown that when the plasmonic properties of the metal are dominant, the electrical length of the unit cell may be a very small fraction of the operating wavelength near the plasma frequency of the wire medium and that the spatial dispersion effects may be relatively weak. In addition, we investigate the possibility operating the artificial plasma in the regime Re{ɛ}=-1 to obtain a superlensing effect at infrared frequencies analogous to that characteristic of the silver lens.

  14. Oxygen acoustic solitary waves in a magnetized plasma

    NASA Technical Reports Server (NTRS)

    Qian, S.; Lotko, W.; Hudson, M. K.

    1989-01-01

    Ion-acoustic solitary waves in a magnetized plasma containing an arbitrary mixture of H(+) and O(+) ions are studied. A nonlinear wave equation has been derived from the Poisson-Vlasov equations, including a uniform magnetic field and dissipation due to reflected electrons. When dissipation is ignored, the equation has soliton solutions associated with both oxygen and hydrogen acoustic modes, which can be either rarefactive or compressive depending on the ion concentrations and the electron/ion temperature ratio and, more weakly, on the bulk drifts of the species. If electron reflection is included, the solitary wave can be intensified. Under somewhat restrictive conditions the oxygen solitary wave is rarefactive and propagates with a velocity comparable to that observed by the Viking satellite. The three-dimensional solitons obey a relation of scales parallel to the magnetic field and in the transverse direction. Computer simulations of one-dimensional versions of the nonlinear wave equation are presented.

  15. Overview of Spontaneous Frequency Chirping in Confined Plasmas

    NASA Astrophysics Data System (ADS)

    Berk, Herbert

    2012-10-01

    Spontaneous rapid frequency chirping is now a commonly observed phenomenon in plasmas with an energetic particle component. These particles typically induce so called weak instabilities, where they excite background waves that the plasma can support such as shear Alfven waves. The explanation for this phenomenon attributes the frequency chirping to the formation of phase space structures in the form of holes and clumps. Normally a saturated mode, in the presence of background dissipation, would be expected decay after saturation as the background plasma absorbs the energy of the excited wave. However the phase space structures take an alternate route, and move to a regions of phase space that are lower energy states of the energetic particle distribution. Through the wave-resonant particle interaction, this movement is locked to the frequency observed by the wave. This phenomenon implies that alternate mechanisms for plasma relaxation need to be considered for plasma states new marginal stability. It is also possible that these chirping mechanisms can be used to advantage to externally control states of plasma.

  16. Low-frequency instabilities and plasma turbulence

    NASA Technical Reports Server (NTRS)

    Ilic, D. B.

    1973-01-01

    A theoretical and experimental study is reported of steady-state and time-dependent characteristics of the positive column and the hollow cathode discharge (HCD). The steady state of a non-isothermal, cylindrical positive column in an axial magnetic field is described by three moment equations in the plasma approximation. Volume generation of electron-ion pairs by single-stage ionization, the presence of axial current, and collisions with neutrals are considered. The theory covers the range from the low pressure, collisionless regime to the intermediate pressure, collisional regime. It yields radial profiles of the charged particle velocities, density, potential, electron and ion temperatures, and demonstrates similarity laws for the positive column. The results are compared with two moment theories and with experimental data on He, Ar and Hg found in the literature for a wide range of pressures. A simple generalization of the isothermal theory for an infinitely long cylinder in an axial magnetic field to the case of a finite column with axial current flow is also demonstrated.

  17. Frequency Domain Tomography Of Evolving Laser-Plasma Accelerator Structures

    SciTech Connect

    Dong Peng; Reed, Stephen; Kalmykov, Serguei; Shvets, Gennady; Downer, Mike

    2009-01-22

    Frequency Domain Holography (FDH), a technique for visualizing quasistatic objects propagating near the speed of light, has produced 'snapshots' of laser wakefields, but they are averaged over structural variations that occur during propagation through the plasma medium. Here we explore via simulations a generalization of FDH--that we call Frequency Domain Tomography (FDT)--that can potentially record a time sequence of quasistatic snapshots, like the frames of a movie, of the wake structure as it propagates through the plasma. FDT utilizes a several probe-reference pulse pairs that propagate obliquely to the drive pulse and wakefield, along with tomographic reconstruction algorithms similar to those used in medical CAT scans.

  18. Low-frequency flute instabilities of a bounded plasma column.

    NASA Technical Reports Server (NTRS)

    Rognlien, T. D.

    1973-01-01

    Derivation of exact solutions for unstable waves (called flute waves) which occur in a radially bounded plasma column at frequencies below the ion cyclotron frequency. Both analytical and numerical solutions are presented for the m = 1 and m = 2 azimuthal modes for a variety of radial electric field profiles. It is shown that the behavior of the flute waves can depend sensitively on the radial extent of the plasma column. Moreover, it is found that the m = 1 mode and the m = 2 mode do not respond in the same way to changes in the radial boundary position or in the electric field profile.

  19. Plasma-generated reactive oxygen species for biomedical applications

    NASA Astrophysics Data System (ADS)

    Sousa, J. S.; Hammer, M. U.; Winter, J.; Tresp, H.; Duennbier, M.; Iseni, S.; Martin, V.; Puech, V.; Weltmann, K. D.; Reuter, S.

    2012-10-01

    To get a better insight into the effects of reactive oxygen species (ROS) on cellular components, fundamental studies are essential to determine the nature and concentration of plasma-generated ROS, and the chemistry induced in biological liquids by those ROS. In this context, we have measured the absolute density of the main ROS created in three different atmospheric pressure plasma sources: two geometrically distinct RF-driven microplasma jets (μ-APPJ [1] and kinpen [2]), and an array of microcathode sustained discharges [3]. Optical diagnostics of the plasma volumes and effluent regions have been performed: UV absorption for O3 and IR emission for O2(a^1δ) [4]. High concentrations of both ROS have been obtained (10^14--10^17cm-3). The effect of different parameters, such as gas flows and mixtures and power coupled to the plasmas, has been studied. For plasma biomedicine, the determination of the reactive species present in plasma-treated liquids is of great importance. In this work, we focused on the measurement of the concentration of H2O2 and NOX radicals, generated in physiological solutions like NaCl and PBS.[4pt] [1] N. Knake et al., J. Phys. D: App. Phys. 41, 194006 (2008)[0pt] [2] K.D. Weltmann et al., Pure Appl. Chem. 82, 1223 (2010)[0pt] [3] J.S. Sousa et al., Appl. Phys. Lett. 97, 141502 (2010)[0pt] [4] J.S. Sousa et al., Appl. Phys. Lett. 93, 011502 (2008)

  20. Effective bacterial inactivation using low temperature radio frequency plasma.

    PubMed

    Sureshkumar, A; Sankar, R; Mandal, Mahitosh; Neogi, Sudarsan

    2010-08-30

    Staphylococcus aureus is one of the most common pathogens responsible for hospital-acquired infections. In this study, S. aureus was exposed to 13.56MHz radiofrequency (RF) plasma generated by two different gases namely nitrogen and nitrogen-oxygen mixture and their sterilization efficacies were compared. Nitrogen plasma had a significant effect on sterilization due to generation of ultraviolet (UV) radiation. However, the addition of 2% oxygen showed enhanced effect on the sterilization of bacteria through nitric oxide (NO) emission and various reactive species. The presence of these reactive species was confirmed by optical emission spectroscopy (OES). Scanning electron microscopy (SEM) analysis was carried out to study the morphological changes of bacteria after plasma treatment. From the SEM results, it was observed that the bacterial cells treated by N(2)-O(2) mixture plasma were severely damaged. As a result, a log(10) reduction factor of 6 was achieved using N(2)-O(2) plasma after 5min treatment with 100W RF power. PMID:20609423

  1. Afterglow chemistry of atmospheric-pressure helium-oxygen plasmas with humid air impurity

    NASA Astrophysics Data System (ADS)

    Murakami, Tomoyuki; Niemi, Kari; Gans, Timo; O'Connell, Deborah; Graham, William G.

    2014-04-01

    The formation of reactive species in the afterglow of a radio-frequency-driven atmospheric-pressure plasma in a fixed helium-oxygen feed gas mixture (He+0.5%O2) with humid air impurity (a few hundred ppm) is investigated by means of an extensive global plasma chemical kinetics model. As an original objective, we explore the effects of humid air impurity on the biologically relevant reactive species in an oxygen-dependent system. After a few milliseconds in the afterglow environment, the densities of atomic oxygen (O) decreases from 1015 to 1013 cm-3 and singlet delta molecular oxygen (O2(1D)) of the order of 1015 cm-3 decreases by a factor of two, while the ozone (O3) density increases from 1014 to 1015 cm-3. Electrons and oxygen ionic species, initially of the order of 1011 cm-3, recombine much faster on the time scale of some microseconds. The formation of atomic hydrogen (H), hydroxyl radical (OH), hydroperoxyl (HO2), hydrogen peroxide (H2O2), nitric oxide (NO) and nitric acid (HNO3) resulting from the humid air impurity as well as the influence on the afterglow chemistry is clarified with particular emphasis on the formation of dominant reactive oxygen species (ROS). The model suggests that the reactive species predominantly formed in the afterglow are major ROS O2(1D) and O3 (of the order of 1015 cm-3) and rather minor hydrogen- and nitrogen-based reactive species OH, H2O2, HNO3 and NO2/NO3, of which densities are comparable to the O-atom density (of the order of 1013 cm-3). Furthermore, the model quantitatively reproduces the experimental results of independent O and O3 density measurements.

  2. Optical Frequency Domain Visualization of Electron Beam Driven Plasma Wakefields

    NASA Astrophysics Data System (ADS)

    Zgadzaj, Rafal; Downer, Michael C.; Muggli, Patric; Yakimenko, Vitaly; Kusche, Karl; Fedurin, Michhail; Babzien, Marcus

    2010-11-01

    Bunch driven plasma wakefield accelerators (PWFA), such as the "plasma afterburner," are a promising emerging method for significantly increasing the energy output of conventional particle accelerators [1]. The study and optimization of this method would benefit from an experimental correlation of the drive bunch parameters and the accelerated particle parameters with the corresponding plasma wave structure. However, the plasma wave structure has not been observed directly so far. We will report ongoing development of a noninvasive optical Frequency Domain Interferometric (FDI) [2] and Holographic (FDH) [3] diagnostics of bunch driven plasma wakes. Both FDI and FDH have been previously demonstrated in the case of laser driven wakes. These techniques employ two laser pulses co-propagating with the drive particle bunch and the trailing plasma wave. One pulse propagates ahead of the drive bunch and serves as a reference, while the second is overlapped with the plasma wave and probes its structure. The multi-shot FDI and single-shot FDH diagnostics permit direct noninvasive observation of longitudinal and transverse structure of the plasma wakes. The experiment is being developed at the 70 MeV Linac in the Accelerator Test Facility at Brookhaven National Laboratory to visualize wakes generated by two [4] and multi-bunch [5] drive beams.

  3. Optical Frequency Domain Visualization of Electron Beam Driven Plasma Wakefields

    SciTech Connect

    Zgadzaj, Rafal; Downer, Michael C.; Muggli, Patric; Yakimenko, Vitaly; Kusche, Karl; Fedurin, Michhail; Babzien, Marcus

    2010-11-04

    Bunch driven plasma wakefield accelerators (PWFA), such as the 'plasma afterburner', are a promising emerging method for significantly increasing the energy output of conventional particle accelerators. The study and optimization of this method would benefit from an experimental correlation of the drive bunch parameters and the accelerated particle parameters with the corresponding plasma wave structure. However, the plasma wave structure has not been observed directly so far. We will report ongoing development of a noninvasive optical Frequency Domain Interferometric (FDI) and Holographic (FDH) diagnostics of bunch driven plasma wakes. Both FDI and FDH have been previously demonstrated in the case of laser driven wakes. These techniques employ two laser pulses co-propagating with the drive particle bunch and the trailing plasma wave. One pulse propagates ahead of the drive bunch and serves as a reference, while the second is overlapped with the plasma wave and probes its structure. The multi-shot FDI and single-shot FDH diagnostics permit direct noninvasive observation of longitudinal and transverse structure of the plasma wakes. The experiment is being developed at the 70 MeV Linac in the Accelerator Test Facility at Brookhaven National Laboratory to visualize wakes generated by two and multi-bunch drive beams.

  4. External control of ion waves in a plasma by high frequency fields

    DOEpatents

    Kaw, P.K.; Dawson, J.M.

    1973-12-18

    An apparatus and method are described for stabilizing plasma instabilities, in a magnetically confined plasma column by transmitting into the plasma high frequency electromagnetic waves at a frequency close to the electron plasma frequency. The said frequencies, e.g., are between the plasma frequency and 1.5 times the plasma frequency at a power level below the level for producing parametric instabilities in a plasma having temperatures from below 10 eV to about 10 keV or more, at densities from below 10/sup 13/ to above 10/sup 18/ particles/cm/sup 3/. (Official Gazette)

  5. Excitation and Ionisation dynamics in high-frequency plasmas

    NASA Astrophysics Data System (ADS)

    O'Connell, D.

    2008-07-01

    Non-thermal low temperature plasmas are widely used for technological applications. Increased demands on plasma technology have resulted in the development of various discharge concepts based on different power coupling mechanisms. Despite this, power dissipation mechanisms in these discharges are not yet fully understood. Of particular interest are low pressure radio-frequency (rf) discharges. The limited understanding of these discharges is predominantly due to the complexity of the underlying mechanisms and difficult diagnostic access to important parameters. Optical measurements are a powerful diagnostic tool offering high spatial and temporal resolution. Optical emission spectroscopy (OES) provides non-intrusive access, to the physics of the plasma, with comparatively simple experimental requirements. Improved advances in technology and modern diagnostics now allow deeper insight into fundamental mechanisms. In low pressure rf discharges insight into the electron dynamics within the rf cycle can yield vital information. This requires high temporal resolution on a nano-second time scale. The optical emission from rf discharges exhibits temporal variations within the rf cycle. These variations are particularly strong, in for example capacitively coupled plasmas (CCPs), but also easily observable in inductively coupled plasmas (ICPs), and can be exploited for insight into power dissipation. Interesting kinetic and non-linear coupling effects are revealed in capacitive systems. The electron dynamics exhibits a complex spatio-temporal structure. Excitation and ionisation, and, therefore, plasma sustainment is dominated through directed energetic electrons created through the dynamics of the plasma boundary sheath. In the relatively simple case of an asymmetric capacitively coupled rf plasma the complexity of the power dissipation is exposed and various mode transitions can be clearly observed and investigated. At higher pressure secondary electrons dominate the

  6. Exponential frequency spectrum and Lorentzian pulses in magnetized plasmas

    SciTech Connect

    Pace, D. C.; Shi, M.; Maggs, J. E.; Morales, G. J.; Carter, T. A.

    2008-12-15

    Two different experiments involving pressure gradients across the confinement magnetic field in a large plasma column are found to exhibit a broadband turbulence that displays an exponential frequency spectrum for frequencies below the ion cyclotron frequency. The exponential feature has been traced to the presence of solitary pulses having a Lorentzian temporal signature. These pulses arise from nonlinear interactions of drift-Alfven waves driven by the pressure gradients. In both experiments the width of the pulses is narrowly distributed resulting in exponential spectra with a single characteristic time scale. The temporal width of the pulses is measured to be a fraction of a period of the drift-Alfven waves. The experiments are performed in the Large Plasma Device (LAPD-U) [W. Gekelman et al., Rev. Sci. Instrum. 62, 2875 (1991)] operated by the Basic Plasma Science Facility at the University of California, Los Angeles. One experiment involves a controlled, pure electron temperature gradient associated with a microscopic (6 mm gradient length) hot electron temperature filament created by the injection a small electron beam embedded in the center of a large, cold magnetized plasma. The other experiment is a macroscopic (3.5 cm gradient length) limiter-edge experiment in which a density gradient is established by inserting a metallic plate at the edge of the nominal plasma column of the LAPD-U. The temperature filament experiment permits a detailed study of the transition from coherent to turbulent behavior and the concomitant change from classical to anomalous transport. In the limiter experiment the turbulence sampled is always fully developed. The similarity of the results in the two experiments strongly suggests a universal feature of pressure-gradient driven turbulence in magnetized plasmas that results in nondiffusive cross-field transport. This may explain previous observations in helical confinement devices, research tokamaks, and arc plasmas.

  7. Low frequency drift instabilities in a dusty plasma

    SciTech Connect

    Rosenberg, M.; Krall, N.A.

    1996-02-01

    Low frequency drift instabilities are investigated in a dusty magnetized plasma with negatively charged grains in which locally there is an electron density gradient which is opposite in sign to a dust density gradient. Frequencies less than the ion gyrofrequency but much larger than the dust gyrofrequency are considered. Two different equilibria are considered that are characterized by {rho}{sub {ital d}}{lt_or_gt}{ital L}{sub {ital nd}}, where {rho}{sub {ital d}} is the dust gyroradius and {ital L}{sub {ital nd}} is the dust density scale length. Instabilities analogous to the universal instability and to the lower-hybrid-drift instability (with the lower-hybrid frequency in this case associated with the dust) are investigated. Possible applications to dusty space plasmas such as the spoke regions of Saturn{close_quote}s B-ring are discussed. {copyright} {ital 1996 American Institute of Physics.}

  8. A new low-frequency backward mode in inhomogeneous plasmas

    SciTech Connect

    Vranjes, J.

    2014-07-15

    When an electromagnetic transverse wave propagates through an inhomogeneous plasma so that its electric field has a component in the direction of the background density gradient, there appears a disbalance of charge in every plasma layer, caused by the density gradient. Due to this, some additional longitudinal electric field component appears in the direction of the wave vector. This longitudinal field may couple with the usual electrostatic longitudinal perturbations like the ion acoustic, electron Langmuir, and ion plasma waves. As a result, these standard electrostatic waves are modified and in addition to this a completely new low-frequency mode appears. Some basic features of the coupling and modification of the ion acoustic wave, and properties of the new mode are discussed here, in ordinary electron-ion and in pair plasmas.

  9. Low radio frequency biased electron cyclotron resonance plasma etching

    NASA Astrophysics Data System (ADS)

    Samukawa, Seiji; Toyosato, Tomohiko; Wani, Etsuo

    1991-03-01

    A radio frequency (rf) biased electron cyclotron resonance (ECR) plasma etching technology has been developed to realize an efficient ion acceleration in high density and uniform ECR plasma for accurate Al-Si-Cu alloy film etching. In this technology, the substrate is located at the ECR position (875 G position) and the etching is carried out with a 400 kHz rf bias power. This Al-Si-Cu etching technology achieves a high etching rate (more than 5000 A/min), excellent etching uniformity (within ±5%), highly anisotropic etching, and Cu residue-free etching in only Cl2 gas plasma. These etching characteristics are accomplished by the combination of the dense and uniform ECR plasma generation at the ECR position with the efficient accelerated ion flux at the ECR position by using 400 kHz rf bias.

  10. Radio-Frequency Sustainment of Laser Initiated, High-Pressure Air Constituent Plasmas*

    NASA Astrophysics Data System (ADS)

    Akhtar, Kamran; Scharer, John; Tysk, Shane; Denning, Mark

    2003-10-01

    We investigate the feasibility of creating a high-density sim 10^12 -10^14 /cc, large volume plasma in air constituents by laser (300 mJ, 20(+/-2) ns) preionization of an organic gas. Tetrakis (dimethyl-amino) ethylene (TMAE) is seeded in high-pressure air constituent gases and then sustained by the efficient absorption of the radio-frequency (RF) power (1-25 kW pulsed) through inductive coupling of the wave fields, thereby reducing the rf initiation power budget.1 A multi-turn helical antenna is used to couple rf power through a capacitive matching network to sustain the plasma. Plasma density and decay recombination mechanisms with and without the background gas are examined using a 105 GHz interferometr.2 The effect of gas heating on plasma life-time enhancement through reduced formation of negative oxygen ions will also be presented. Optical emission spectroscopy is employed to study the process of delayed ionization of the seed gas and RF creation of air constituent plasma and calculate the plasma temperature. RF wave penetration and projection of plasma away from the source region are also examined for different gas flow rates. 1. Kelly K, Scharer J, Paller E, and Ding G, J. App. Phys., 92,698(2002). 2. Akhtar K, Scharer J, Tysk S., and Kho E., Rev. Sci. Instrum., 74, 996 (2003).

  11. Sterilization Effect of Wet Oxygen Plasma in the Bubbling Method.

    PubMed

    Tamazawa, Kaoru; Shintani, Hideharu; Tamazawa, Yoshinori; Shimauchi, Hidetoshi

    2015-01-01

    A new low-temperature sterilization method to replace the ethylene oxide gas sterilization is needed. Strong bactericidal effects of OH and O2H radicals are well known. The purpose of this study was to evaluate the sterilization effect of wet oxygen ("O2+H2O") plasma in the bubbling method, confirming the effect of humidity. Sterility assurance was confirmed by using a biological indicator (Geobacillus stearothermophilus ATCC7953, Namsa, USA). One hundred and eight samples (10(5) spores/carrier) were divided into three groups of 36 in each for treatment with a different type of gas (O2, O2+H2O, Air+H2O). Plasma processing was conducted using a plasma ashing apparatus (13.56 MHz, PACK-3(®), Y. A. C., Japan) under various gas pressures (13, 25, 50 Pa) and gas flows (50, 100, 200 sccm). Fixed plasma treatment parameters were power at 150 W, temperature of 60 ℃, treatment time of 10 min. The samples after treatment were incubated in trypticase soy broth at 58 ℃ for 72 h. The negative culture rate in the "O2+H2O" group was significantly (Mantel-Haenszel procedure, p<0.001) higher than in the other gas groups. It is suggested that the significant sterilization effect of the "O2+H2O" group depends on the bubbling method which is the method of introducing vapor into the chamber. The bubbling method seems able to generate OH and O2H radicals in a stable way. PMID:26699857

  12. Electron scattering cross sections for the modelling of oxygen-containing plasmas

    NASA Astrophysics Data System (ADS)

    Lemos Alves, Luís; Coche, Philippe; Ridenti, Marco Antonio; Guerra, Vasco

    2016-05-01

    This work proposes a set of electron scattering cross sections for molecular and atomic oxygen, with interest for the modelling of oxygen-containing plasmas. These cross sections, compiled for kinetic energies up to 1 keV, are part of the IST-LISBON database with LXCat, being used as input data to the LoKI (LisbOn KInetics) numerical code. The cross sections for ground-state molecular oxygen describe elastic and inelastic collision mechanisms, the latter including rotational excitations/de-excitations (treated using either a discrete or a continuous approach), vibrational and electronic excitations (including dissociation), dissociative attachment and ionisation. This set yields calculated swarm parameters that reproduce measurements within 5-20% (transport parameters) and within a factor of 2 difference (Townsend coefficients), for reduced electric fields in the range 10-3-103 Td. The cross sections describing the kinetics of atomic oxygen by electron-impact comprise elastic mechanisms, electronic excitation and ionisation from O(3P) ground-state, dissociation of O2(X,a,b) (including dissociative ionisation and attachment) and of O3, and detachment. These cross sections are indirectly validated, together with other elementary data for oxygen, by comparing the densities of O((4S0)3p 5P) obtained from the self-consistent modelling and from calibrated optical emission spectroscopy diagnostics of microwave-sustained micro-plasmas in dry air (80% N2: 20% O2), produced using a surface-wave excitation (2.45 GHz frequency) within a small radius capillary (R = 345 μm) at low pressure (p = 300 Pa). The calculated densities are in good qualitative agreement with measurements, overestimating them by a factor ˜1.5. Contribution to the Topical Issue "Advances in Positron and Electron Scattering", edited by Paulo Limao-Vieira, Gustavo Garcia, E. Krishnakumar, James Sullivan, Hajime Tanuma and Zoran Petrovic.

  13. Electron scattering cross sections for the modelling of oxygen-containing plasmas*

    NASA Astrophysics Data System (ADS)

    Alves, Luís Lemos; Coche, Philippe; Ridenti, Marco Antonio; Guerra, Vasco

    2016-06-01

    This work proposes a set of electron scattering cross sections for molecular and atomic oxygen, with interest for the modelling of oxygen-containing plasmas. These cross sections, compiled for kinetic energies up to 1 keV, are part of the IST-LISBON database with LXCat, being used as input data to the LoKI (LisbOn KInetics) numerical code. The cross sections for ground-state molecular oxygen describe elastic and inelastic collision mechanisms, the latter including rotational excitations/de-excitations (treated using either a discrete or a continuous approach), vibrational and electronic excitations (including dissociation), dissociative attachment and ionisation. This set yields calculated swarm parameters that reproduce measurements within 5-20% (transport parameters) and within a factor of 2 difference (Townsend coefficients), for reduced electric fields in the range 10-3-103 Td. The cross sections describing the kinetics of atomic oxygen by electron-impact comprise elastic mechanisms, electronic excitation and ionisation from O(3P) ground-state, dissociation of O2(X,a,b) (including dissociative ionisation and attachment) and of O3, and detachment. These cross sections are indirectly validated, together with other elementary data for oxygen, by comparing the densities of O((4S0)3 p 5P) obtained from the self-consistent modelling and from calibrated optical emission spectroscopy diagnostics of microwave-sustained micro-plasmas in dry air (80% N2: 20% O2), produced using a surface-wave excitation (2.45 GHz frequency) within a small radius capillary ( R = 345 μm) at low pressure ( p = 300 Pa). The calculated densities are in good qualitative agreement with measurements, overestimating them by a factor ˜1.5.

  14. Mechanisms of polymer degradation using an oxygen plasma generator

    NASA Technical Reports Server (NTRS)

    Colony, Joe A.; Sanford, Edward L.

    1987-01-01

    An RF oxygen plasma generator was used to produce polymer degradation which appears to be similar to that which has been observed in low Earth orbit. Mechanisms of this type of degradation were studied by collecting the reaction products in a cryogenic trap and identifying the molecular species using infrared, mass spectral, and X-ray diffraction techniques. No structurally dependent species were found from Kapton, Teflon, or Saran polymers. However, very reactive free radical entities are produced during the polymer degradation, as well as carbon dioxide and water. Reactions of the free radicals with the glass reaction vessel, with copper metal in the cold trap, and with a triphenyl phosphate scavenger in the cold trap, demonstrated the reactivity of the primary products.

  15. Development of A Pulse Radio-Frequency Plasma Jet

    NASA Astrophysics Data System (ADS)

    Wang, Shou-Guo; Zhao, Ling-Li; Yang, Jing-Hua

    2013-09-01

    A small pulse plasma jet was driven by new developed radio-frequency (RF) power supply of 6.78 MHz. In contrast to the conventional RF 13.56 MHz atmospheric pressure plasma jet (APPJ), the power supply was highly simplified by eliminating the matching unit of the RF power supply and using a new circuit, moreover, a pulse controller was added to the circuit to produce the pulse discharge. The plasma jet was operated in a capacitively coupled manner and exhibited low power requirement of 5 W at atmospheric pressure using argon as a carrier gas. The pulse plasma plume temperature remained at less than 45 °C for an extended period of operation without using water to cool the electrodes. Optical emission spectrum measured at a wide range of 200-1000 nm indicated various excited species which were helpful in applying the plasma jet for surface sterilization to human skin or other sensitive materials. Institude of Plasma Physics, Chinese Academy of Science, Hefei, China.

  16. Low frequency hybrid instability in quantum magneto semiconductor plasmas

    NASA Astrophysics Data System (ADS)

    Rasheed, A.; Jamil, M.; Areeb, F.; Siddique, M.; Salimullah, M.

    2016-05-01

    The excitation of electrostatic, comparatively low frequency, lower-hybrid waves (LHWs) induced by electron beam in semiconductor plasma is examined using a quantum hydrodynamic model. Various quantum effects are taken into account including the recoil effect, Fermi degenerate pressure, and exchange-correlation potential. The effects of different parameters like the electron-to-hole number density ratio, scaled electron beam temperature and streaming speed, propagation angle and cyclotron frequency over the growth, and phase speed of LHWs are investigated. It is noticed that an increase in the electron number density and streaming speed enhance the instability. Similar effects are observed on decreasing the propagation angle with magnetic field.

  17. Surface Evaluation by X-Ray Photoelectron Spectroscopy of High Performance Polyimide Foams After Exposure to Oxygen Plasma

    NASA Technical Reports Server (NTRS)

    Melendez, Orlando; Hampton, Michael D.; Williams, Martha K.; Brown, Sylvia F.; Nelson, Gordon L.; Weiser, Erik S.

    2002-01-01

    Aromatic polyimides have been attractive in the aerospace and electronics industries for applications such as cryogenic insulation, flame retardant panels and structural subcomponents. Newer to the arena of polyimides is the synthesis of polyimide foams and their applications. In the present work, three different, closely related, polyimide foams developed by NASA Langley Research Center (LaRC) are studied by X-ray Photoelectron Spectroscopy (XPS) after exposure to radio frequency generated Oxygen Plasma. Although polyimide films exposure to atomic oxygen and plasma have been studied previously and reported, the data relate to films and not foams. Foams have much more surface area and thus present new information to be explored. Understanding degradation mechanisms and properties versus structure, foam versus solid is of interest and fundamental to the application and protection of foams exposed to atomic oxygen in Low Earth Orbit (LEO).

  18. Importance of atomic oxygen in preheating zone in plasma-assisted combustion of a steady-state premixed burner flame

    NASA Astrophysics Data System (ADS)

    Zaima, K.; Akashi, H.; Sasaki, K.

    2015-09-01

    It is widely believed that electron impact processes play essential roles in plasma-assisted combustion. However, the concrete roles of high-energy electrons have not been fully understood yet. In this work, we examined the density of atomic oxygen in a premixed burner flame with the superposition of dielectric barrier discharge (DBD). The density of atomic oxygen in the reaction zone was not affected by the superposition of DBD, indicating that the amount of atomic oxygen produced by combustion reactions was much larger than that produced by electron impact processes. On the other hand, in the preheating zone, we observed high-frequency oscillation of the density of atomic oxygen at the timings of the pulsed current of DBD. The oscillation suggests the rapid consumption of additional atomic oxygen by combustion reactions. A numerical simulation using Chemkin indicates the shortened ignition delay time when adding additional atomic oxygen in the period of low-temperature oxidation. The present results reveals the importance of atomic oxygen, which is produced by the effect of high-energy electrons, in the preheating zone in plasma-assisted combustion of the steady-state premixed burner flame.

  19. Effect of oxygen plasma on the properties of tantalum oxide films

    SciTech Connect

    Kalygina, V. M. Zarubin, A. N.; Novikov, V. A.; Petrova, Yu. S.; Skakunov, M. S.; Tolbanov, O. P.; Tyazhev, A. V.; Yaskevich, T. M.

    2010-09-15

    The effect of oxygen plasma on the leakage current, permittivity, and the dielectric loss tangent of Ta{sub 2}O{sub 5} thin layers (300-400 nm) is studied. It is suggested to treat tantalum oxide films in oxygen plasma to control their electrical and dielectric characteristics.

  20. Magnetic fields, plasma densities, and plasma beta parameters estimated from high-frequency zebra fine structures

    NASA Astrophysics Data System (ADS)

    Karlický, M.; Jiricka, K.

    2002-10-01

    Using the recent model of the radio zebra fine structures (Ledenev et al. 2001) the magnetic fields, plasma densities, and plasma beta parameters are estimated from high-frequency zebra fine structures. It was found that in the flare radio source of high-frequency (1-2 GHz) zebras the densities and magnetic fields vary in the intervals of (1-4)×1010 cm-3 and 40-230 G, respectively. Assuming then the flare temperature as about of 107K, the plasma beta parameters in the zebra radio sources are in the 0.05-0.81 interval. Thus the plasma pressure effects in such radio sources, especially in those with many zebra lines, are not negligible.

  1. Spectroscopic Measurements of Radio Frequency Plasmas in Supercritical Fluids

    SciTech Connect

    Maehara, Tsunehiro; Iwamae, Atsushi; Kawashima, Ayato

    2010-10-29

    Spectroscopic measurements of radio frequency (rf) plasma were performed under high pressure CO{sub 2} conditions (5 and 7 MPa) and supercritical (sc)CO{sub 2} conditions (8-20 MPa). The temperatures evaluated from C{sub 2} Swan bands increased from 3600 K to 4600 K with increasing pressure. The broadening and shifting of the O I line profile ({approx}777 nm) of rf plasma was observed under scCO{sub 2} conditions. The width of the line profile increased with increasing pressure. The reason for the broadening and shifting is still unclear because the present theory used to explain them is not valid for such high pressure conditions. Further, the broadening of the Ar I line profile ({approx}811.5 nm) in rf plasmas was observed under atmospheric Ar (0.1 MPa), high pressure Ar conditions (1-4 MPa), and scAr condition (5 MPa); the observation of the O I line profile in CO{sub 2} plasmas is difficult in this pressure range owing to its weak intensity therein. Similar to the case of the O I line in CO{sub 2} plasmas, the reason for the broadening of the Ar I line profile at 5 MPa is unclear.

  2. Low Frequency Turbulence as the Source of High Frequency Waves in Multi-Component Space Plasmas

    NASA Technical Reports Server (NTRS)

    Khazanov, George V.; Krivorutsky, Emmanuel N.; Uritsky, Vadim M.

    2011-01-01

    Space plasmas support a wide variety of waves, and wave-particle interactions as well as wavewave interactions are of crucial importance to magnetospheric and ionospheric plasma behavior. High frequency wave turbulence generation by the low frequency (LF) turbulence is restricted by two interconnected requirements: the turbulence should be strong enough and/or the coherent wave trains should have the appropriate length. These requirements are strongly relaxed in the multi-component plasmas, due to the heavy ions large drift velocity in the field of LF wave. The excitation of lower hybrid waves (LHWs), in particular, is a widely discussed mechanism of interaction between plasma species in space and is one of the unresolved questions of magnetospheric multi-ion plasmas. It is demonstrated that large-amplitude Alfven waves, in particular those associated with LF turbulence, may generate LHW s in the auroral zone and ring current region and in some cases (particularly in the inner magnetosphere) this serves as the Alfven wave saturation mechanism. We also argue that the described scenario can playa vital role in various parts of the outer magnetosphere featuring strong LF turbulence accompanied by LHW activity. Using the data from THEMIS spacecraft, we validate the conditions for such cross-scale coupling in the near-Earth "flow-braking" magnetotail region during the passage of sharp injection/dipolarization fronts, as well as in the turbulent outflow region of the midtail reconnection site.

  3. Effect of radio frequency discharge power on dusty plasma parameters

    SciTech Connect

    Sheridan, T. E.

    2009-08-01

    The parameters of a two-dimensional dusty plasma consisting of six, 9 mum diameter particles trapped inside a radio frequency (rf) plasma sheath have been measured as a function of rf power in a 13.5 mtorr (1.8 Pa) argon discharge. The center-of-mass and breathing frequencies are found by projecting the cluster's Brownian motion onto the associated normal mode. The center-of-mass frequency (i.e., radial confinement) is insensitive to rf power. The Debye shielding parameter kappa, as found from the breathing frequency, increases from approx =0.5 to 2 as the square root of rf power. The Debye length decreases from approx =2.7 to 0.7 mm as the inverse of the square root of rf power. The average particle charge qapprox =-17 000e is effectively independent of rf power. These results are consistent with an electron temperature that is independent of rf power and an ion density that is directly proportional to rf power, where the Debye length is determined by the ion density in combination with the electron temperature.

  4. Reactive Plasma Etching of SiC in a Tetrafluoroethane / Oxygen Plasma

    NASA Astrophysics Data System (ADS)

    Galloway, Heather C.; Radican, Kevin P.; Donnelly, David; Koeck, Deborah C.

    2003-03-01

    The etch rate as a function of oxygen concentration was investigated in the RF magnetron plasma etching of SiC with tetrafluoroethane gas. The etch rate and surface roughness was measured with atomic force microscopy, while evidence of polymer deposition was analyzed with FTIR. Etch rates of > 10 nm/sec can be achieved with high selectivity with respect to an aluminum mask, near infinite selectivity with respect to silicon. This has also been found to be compatible with some low-k dielectric films. Tetrafluoroethane is of interest due to its high fluorine content. It is also a nontoxic, ozone friendly gas with a short atmospheric lifetime. The role of oxygen in the etching process will be discussed and this etching process will be compared to other SiC etches that have been previously reported

  5. Improved fluid simulations of radio-frequency plasmas using energy dependent ion mobilities

    SciTech Connect

    Greb, Arthur; Niemi, Kari; O'Connell, Deborah; Gans, Timo; Ennis, Gerard J.; MacGearailt, Niall

    2013-05-15

    Symmetric and asymmetric capacitively coupled radio-frequency plasmas in oxygen at 40 Pa, 300 V voltage amplitude and a discharge gap of 40 mm are investigated by means of one-dimensional numerical semi-kinetic fluid modeling on the basis of a simplified reaction scheme including the dominant positive and negative ions, background gas, and electrons. An improved treatment, by accounting for the dependence of ion mobilities on E/N, is compared to the standard approach, based on using zero-field mobility values only. The charged particle dynamics as a result of direct electron impact ionization of oxygen, secondary electron release from the electrodes, the spatial distribution of all involved particles as well as impact of geometry and model modification on ion energies is analyzed and compared to independent simulations and experiments.

  6. Reactive Plasma Etching of SiC in a Tetrafluoroethane / Oxygen Plasma

    NASA Astrophysics Data System (ADS)

    McDonald, James S.; Radican, Kevin; Botello, Eric; Koeck, Deborah C.; Donnelly, David; Geerts, Wilhelmus; Spencer, Gregory; Galloway, Heather C.

    2003-10-01

    Fabrication of waveguides for electrical characterization of dielectric thin films requires a method of etching SiC and SiCN. A method of RF plasma etching was developed to ensure proper ground contact between the substrate and the ground lines. A constant flow of HFC 134a was investigated as compared to various oxygen flow rates, in order to determine the right mixture of HFC 134a and O_2, and the respective etch rate. This presentation will describe the method and techniques that were implemented using a magnetron gun attached to an RF network as a plasma source and a mixture of tetrafluoroethane or HFC 134a and O2 as the process gas.

  7. Characterizing low frequency plasma waves at Mars with MAVEN

    NASA Astrophysics Data System (ADS)

    Ruhunusiri, Suranga; Halekas, Jasper; Connerney, Jack; Espley, Jared; Larson, Davin; Mitchell, David L.

    2015-04-01

    We use the measurements from the Solar Wind Ion Analyzer (SWIA) and the magnetometer (MAG) instruments aboard the MAVEN spacecraft to characterize plasma waves in the Martian magnetosphere. SWIA is a toroidal energy analyzer that measures 3-d ion velocity distributions, and we use it for measuring ion moment fluctuations. MAG instrument, on the other hand, is a fluxgate magnetometer, and we use it for measuring magnetic field fluctuations. Mars is unique in the solar system because of two characteristics: it only has an induced magnetosphere with strong crustal fields at low altitudes, and it has an extended atmosphere due to its lower gravity. Due to these two characteristics, Mars presents a unique environment to study the interaction of a planetary magnetosphere and an exosphere with the solar wind. One consequence of this interaction is the excitation of low frequency plasma waves which have highest power near and below the proton gyrofrequency. Studying these waves is of interest because they can play a vital role in the mass and energy transport in the Martian magnetosphere. In this investigation, we use both ion moment fluctuations (density and velocity) and the magnetic field fluctuations to characterize these low frequency plasma waves.

  8. Solar Astronomy at DSES: Plasma Motion Detection at Radio Frequencies

    NASA Astrophysics Data System (ADS)

    Howe, Rodney

    2008-05-01

    This article discusses a proposed study of solar plasma motion, a radio receiving system designed to detect plasma motion-driven microwaves, and the initial radio analysis to understand the receiving system characteristics. A phenomenon of interest is the increasing temperature from the solar photosphere to the solar corona. I've been thinking about testable hypothesis[es] for how to measure the different altitudes (via a temperature scale) of the transition zone (between photosphere and corona) of the sun. I think if we choose the appropriate frequencies, one close to the surface, say 11.7 GHz and one above the 2km breakpoint, say 12.7 GHz we might test for a couple of possible phenomena: (1) At Extremely Low Frequencies (ELF), are we seeing a Doppler shifting in the phase of plasma motions, and (2) in a polarized recording of data, can we measure electro- magnetic waves in both electric and magnetic components. The temperatures that are being measured at 11.7 GHz are approximately 15,000 Kelvin and the temperature at 12.7 GHz is approximately 17,000 Kelvin.

  9. Effects of long pulse width and high pulsing frequency on surface superhydrophobicity of polytetrafluoroethylene in quasi-direct-current plasma immersion ion implantation

    SciTech Connect

    Kwok, Dixon T. K.; Wang Huaiyu; Yeung, Kelvin W. K.; Chu, Paul K.; Zhang Yumei

    2009-03-01

    Long pulse, high frequency quasi-direct-current (dc) oxygen plasma immersion ion implantation (PIII) is utilized to create a superhydrophobic polytetrafluoroethylene (PTFE) surface with a water contact angle of over 150 deg. This technique allows the use of a high duty cycle without deleterious effects such as extensive sample heating encountered in conventional PIII. Scanning electron microscopy images review submicrometer-nanometer structures on the PTFE surface after long pulse, high frequency PIII indicative of ion implantation. On the other hand, plasma modification is the dominant effect in short pulse, low frequency PIII. Quasi-dc PIII is demonstrated to offer adjustable synergistic plasma and ion beam effects.

  10. Ionospheric nf sub H resonances: Frequency shifts versus plasma conditions

    NASA Technical Reports Server (NTRS)

    Benson, R. F.

    1971-01-01

    The Alouette 2 resonances observed near the harmonics of the electron cyclotron frequency f sub H reveal frequency shifts (relative to the n(f sub H) values derived from model field calculations) which can be interpreted in terms of plasma wave dispersion effects. These effects are observed on the 2(f sub H) resonance when it is near the resonance observed close to the upper hybrid frequency f sub T. The observations suggest that an oblique echo model may be required to give a proper interpretation of the 2(f sub H) resonance. Cyclotron damping can be ignored only when the angle between the propagation vector and the direction perpendicular to the earth's magnetic field B is less than a few degrees for the 2(f sub H) wave, and less than a few tenths of a degree for the n(f sub H) waves with n 2. The negative offset of the absolute value of B inferred from the plasma resonance observations is consistent with expectations based on recent OGO 3 and OGO 5 rubidium magnetometer observations at higher altitudes in the equatorial regions.

  11. Spectroscopic measurements of high frequency plasma in supercritical carbon dioxide

    SciTech Connect

    Maehara, T.; Mukasa, S.; Takemori, T.; Watanabe, T.; Kurokawa, K.; Toyota, H.; Nomura, S.; Kawashima, A.; Iwamae, A.

    2009-03-15

    Spectroscopic measurements of high frequency (hf) plasma were performed under high pressure conditions (5 and 7 MPa) and supercritical (sc) CO{sub 2} conditions (8-20 MPa). Temperature evaluated from C{sub 2} Swan bands (d {sup 3}{pi}{sub g}{yields}a {sup 3}{pi}{sub u}) increased from 3600 to 4600 K with an increase in pressure. The first observation of broadening and shifting of the O I line profile (3p {sup 5} P{sub 3,2,1}{yields}3s {sup 5} S{sub 2}{sup 0}) of hf plasma under sc CO{sub 2} conditions was carried out. However, the origin of broadening and the shifting cannot be understood because the present theory explaining them is not valid for such high pressure conditions.

  12. Investigation of plasma diagnostics using a dual frequency harmonic technique

    SciTech Connect

    Kim, Dong-Hwan; Kim, Young-Do; Cho, Sung-Won; Kim, Yu-Sin; Chung, Chin-Wook

    2014-09-07

    Plasma diagnostic methods using harmonic currents analysis of electrostatic probes were experimentally investigated to understand the differences in their measurement of the plasma parameters. When dual frequency voltage (ω{sub 1},ω{sub 2}) was applied to a probe, various harmonic currents (ω{sub 1}, 2ω{sub 1},ω{sub 2}, 2ω{sub 2},ω{sub 2}±ω{sub 1},ω{sub 2}±2ω{sub 1}) were generated due to the non-linearity of the probe sheath. The electron temperature can be obtained from the ratio of the two harmonics of the probe currents. According to the combinations of the two harmonics, the sensitivities in the measurement of the electron temperature differed, and this results in a difference of the electron temperature. From experiments and simulation, it is shown that this difference is caused by the systematic and random noise.

  13. The role of the relative voltage and phase for frequency coupling in a dual-frequency capacitively coupled plasma

    SciTech Connect

    O'Connell, D.; Gans, T.; Semmler, E.; Awakowicz, P.

    2008-08-25

    Frequency coupling in multifrequency discharges is a complex nonlinear interaction of the different frequency components. An alpha-mode low pressure rf capacitively coupled plasma operated simultaneously with two frequencies is investigated and the coupling of the two frequencies is observed to greatly influence the excitation and ionization within the discharge. Through this, plasma production and sustainment are dictated by the corresponding electron dynamics and can be manipulated through the dual-frequency sheath. These mechanisms are influenced by the relative voltage and also the relative phase of the two frequencies.

  14. High frequency drift instabilities in a dusty plasma

    NASA Technical Reports Server (NTRS)

    Rosenberg, M.; Krall, N. A.

    1994-01-01

    High frequency drift instabilities with omega(sub ce) much greater than omega which is greater than omega(sub ci) are investigated in a dusty magnetized plasma in which locally there is an electron density gradient which is opposite in sign to a dust density gradient. Two different equilibria are considered, characterized by rho(sub d) greater than L(sub d) and less than L(sub d), where rho(sub d) is the dust gyroradius and L(sub nd) is the dust density scale length. Possible application to Saturn's F-ring is discussed.

  15. Plasma-Induced Oxygen Vacancies in Ultrathin Hematite Nanoflakes Promoting Photoelectrochemical Water Oxidation.

    PubMed

    Zhu, Changqing; Li, Changli; Zheng, Maojun; Delaunay, Jean-Jacques

    2015-10-14

    The incorporation of oxygen vacancies in hematite has been investigated as a promising route to improve oxygen evolution reaction activity of hematite photoanodes used in photoelectrochemical water oxidation. However, introducing oxygen vacancies intentionally in α-Fe2O3 for active solar water splitting through facile and effective methods remains a challenge. Herein, air plasma treatment is shown to produce oxygen vacancies in α-Fe2O3, and ultrathin α-Fe2O3 nanoflakes are used to investigate the effect of oxygen vacancies on the performance of photoelectrochemical oxygen oxidation. Increasing the plasma treatment duration and power is found to increase the density of oxygen vacancies and leads to a significant enhancement of the photocurrent response. The nanoflake photoanode with the optimized plasma treatment yields an incident photo-to-current conversion efficiency of 35.4% at 350 nm under 1.6 V vs RHE without resorting to any other cocatalysts, an efficiency far exceeding that of the pristine α-Fe2O3 nanoflakes (∼2.2%). Evidence for the presence of high density of oxygen vacancies confined in nanoflakes is clarified by X-ray photoelectron spectroscopy. The increased number of oxygen vacancies after plasma treatment resulting in an increased carrier density is interpreted as the main cause for the enhanced oxygen evolution reaction activity. PMID:26400020

  16. Treatment Characteristics of Second Order Structure of Proteins Using Low-Pressure Oxygen RF Plasma

    NASA Astrophysics Data System (ADS)

    Hayashi, Nobuya; Nakahigashi, Akari; Kawaguchi, Ryutaro; Goto, Masaaki

    2010-10-01

    Removal of proteins from the surface of medical equipments is attempted using oxygen plasma produced by RF discharge. FTIR spectra indicate that the bonding of C-H and N-H in the casein protein is reduced after irradiation of oxygen plasma. Also, the second order structure of a protein such as α-helix and β-sheet are modified by the oxygen plasma. Complete removal of casein protein with the concentration of 0.016 mg/cm2 that is equivalent to remnants on the medical equipment requires two hours avoiding the damage to medical equipments.

  17. Treatment Characteristics of Second Order Structure of Proteins Using Low-Pressure Oxygen RF Plasma

    SciTech Connect

    Hayashi, Nobuya; Nakahigashi, Akari; Kawaguchi, Ryutaro; Goto, Masaaki

    2010-10-13

    Removal of proteins from the surface of medical equipments is attempted using oxygen plasma produced by RF discharge. FTIR spectra indicate that the bonding of C-H and N-H in the casein protein is reduced after irradiation of oxygen plasma. Also, the second order structure of a protein such as {alpha}-helix and {beta}-sheet are modified by the oxygen plasma. Complete removal of casein protein with the concentration of 0.016 mg/cm{sup 2} that is equivalent to remnants on the medical equipment requires two hours avoiding the damage to medical equipments.

  18. Low-temperature oxygen-plasma effects on surveyor plasmo-clay coating

    NASA Technical Reports Server (NTRS)

    Gillette, R. B.

    1972-01-01

    The objective was to determine whether the reflectance of the degraded plasmo-clay thermal control coating could be restored by exposing it to an oxygen plasma. An experiment was conducted to determine whether bulk radiation damage would be removed by a reabsorption of oxygen ions into the pigment crystal lattice. Results show that the oxygen plasma treatment can eliminate some of the lunar environment-induced degradation on the plasmo-clay coating. Visual observations of the lunar soil on the surface after plasma treatment indicated that it was still highly absorbent to light. Therefore, part of the residual discoloration could be due to lunar soil.

  19. Radio Frequency Field Calculations for Plasma Heating Simulations in VASIMR

    NASA Astrophysics Data System (ADS)

    Ilin, A. V.; Díaz, F. R. Chang; Squire, J. P.; Carter, M. D.

    2002-01-01

    (VASIMR)1 is plasma heating by ion-cyclotron RF heating (ICRF). Mathematical simulation helps to design an ICRF antenna, i.e. make maximal absorption of RF power into the plasma in the resonance area. Another goal of a particle simulation is design of a magnetic nozzle and optimize the performance of VASIMR2. field in the plasma, 2) ion density and velocity, 3) ion-cyclotron radio-frequency electromagnetic field. The assumptions of quasineutral and collisionless plasma are based on the range of operating VASIMR parameters. Carlo simulations for systems of million of particles in a reasonable time and without the need for a powerful supercomputer. The particle to grid weighting method is used for calculating the ion density, which is used for recalculation of the electric potential and RF field. dimensional problem to a weighted sum over two-dimensional solutions. Absorption is introduced in the cold plasma model by adding an imaginary collision frequency to the RF driven frequency, which is equivalent to adding an imaginary particle mass in the dielectric tensor elements. static and RF fields using the VASIMR code2. The VASIMR and EMIR codes are then iterated to estimate the ICRF effects on the plasma density. The iteration is performed by calculating the RF fields with the EMIR code, and using these fields to follow nonlinear ion trajectories with the VASIMR code on the gyro-frequency time scale. The ion trajectories are used to generate RF power absorption values and a density input for the next EMIR calculation. The codes are iterated until the density profile becomes reasonably stable, then the collisional absorption parameter in the EMIR code is adjusted and the iteration is continued until the power deposited by the RF system matches the power absorbed by the ion trajectories in a global sense. electric field. The solved algebraic system of equations is represented by ill-conditioned 18-diagonal matrix with complex elements. Since early development of the

  20. Low-Temperature Sterilization with Surface-Wave-Excited Oxygen Plasma

    NASA Astrophysics Data System (ADS)

    Nagatsu, Masaaki; Terashita, Fumie; Koide, Yukio

    2003-07-01

    Low-temperature plasma sterilization has been experimentally demonstrated using surface-wave plasma excited by a 2.45 GHz microwave. With the spores of Bacillus stearothermophilus and Bacillus subtilis as biological indicators, we have carried out the plasma sterilization experiments by varying the irradiation period of oxygen plasma discharges. It was experimentally confirmed that the spores with a population of 1.5 × 106 were sterilized by irradiating them with oxygen plasma discharges generated with a microwave power of 700 W at a pressure of 60-80 mTorr for 3 min or longer. From the scanning electron microscopy (SEM) analysis of the spores, we found that the sterilized spores clearly had different sizes and shapes compared with those before the plasma irradiation. Furthermore, present experiments suggested that the changes of spore shapes were mainly attributed to the reactive interactions with oxygen radicals.

  1. Scattering of radio frequency waves by blobs in tokamak plasmas

    SciTech Connect

    Ram, Abhay K.; Hizanidis, Kyriakos; Kominis, Yannis

    2013-05-15

    The density fluctuations and blobs present in the edge region of magnetic fusion devices can scatter radio frequency (RF) waves through refraction, reflection, diffraction, and coupling to other plasma waves. This, in turn, affects the spectrum of the RF waves and the electromagnetic power that reaches the core of the plasma. The usual geometric optics analysis of RF scattering by density blobs accounts for only refractive effects. It is valid when the amplitude of the fluctuations is small, of the order of 10%, compared to the background density. In experiments, density fluctuations with much larger amplitudes are routinely observed, so that a more general treatment of the scattering process is needed. In this paper, a full-wave model for the scattering of RF waves by a blob is developed. The full-wave approach extends the range of validity well beyond that of geometric optics; however, it is theoretically and computationally much more challenging. The theoretical procedure, although similar to that followed for the Mie solution of Maxwell's equations, is generalized to plasmas in a magnetic field. Besides diffraction and reflection, the model includes coupling to a different plasma wave than the one imposed by the external antenna structure. In the model, it is assumed that the RF waves interact with a spherical blob. The plasma inside and around the blob is cold, homogeneous, and imbedded in a uniform magnetic field. After formulating the complete analytical theory, the effect of the blob on short wavelength electron cyclotron waves and longer wavelength lower hybrid waves is studied numerically.

  2. Collisionless expansion of pulsed radio frequency plasmas. I. Front formation

    NASA Astrophysics Data System (ADS)

    Schröder, T.; Grulke, O.; Klinger, T.; Boswell, R. W.; Charles, C.

    2016-01-01

    The dynamics during plasma expansion are studied with the use of a versatile particle-in-cell simulation with a variable neutral gas density profile. The simulation is tailored to a radio frequency plasma expansion experiment [Schröder et al., J. Phys. D: Appl. Phys. 47(5), 055207 (2014)]. The experiment has shown the existence of a propagating ion front. The ion front features a strong electric field and features a sharp plasma potential drop similar to a double layer. However, the presented results of a first principle simulation show that, in general, the ion front does not have to be entangled with an electric field. The propagating electric field reflects the downstream ions, which stream with velocities up to twice as high as that of the ion front propagation. The observed ion density peak forms due to the accumulation of the reflected ions. The simulation shows that the ion front formation strongly depends on the initial ion density profile and is subject to a wave-breaking phenomenon. Virtual diagnostics in the code allow for a direct comparison with experimental results. Using this technique, the plateau forming in the wake of the plasma front could be indirectly verified in the expansion experiment. Although the simulation considers profiles only in one spatial dimensional, its results are qualitatively in a very good agreement with the laboratory experiment. It can successfully reproduce findings obtained by independent numerical models and simulations. This indicates that the effects of magnetic field structures and tangential inhomogeneities are not essential for the general expansion dynamic. The presented simulation will be used for a detailed parameter study dealt with in Paper II [Schröder et al., Phys. Plasma 23, 013512 (2016)] of this series.

  3. Low-frequency ultrasound induces oxygen vacancies formation and visible light absorption in TiO2 P-25 nanoparticles.

    PubMed

    Osorio-Vargas, Paula A; Pulgarin, Cesar; Sienkiewicz, Andrzej; Pizzio, Luis R; Blanco, Mirta N; Torres-Palma, Ricardo A; Pétrier, Christian; Rengifo-Herrera, Julián A

    2012-05-01

    Low-frequency ultrasound (LFUS) irradiation induces morphological, optical and surface changes in the commercial nano-TiO(2)-based photocatalyst, Evonik-Degussa P-25. Low-temperature electron spin resonance (ESR) measurements performed on this material provided the first experimental evidence for the formation of oxygen vacancies (V(o)), which were also found responsible for the visible-light absorption. The V(o) surface defects might result from high-speed inter-particle collisions and shock waves generated by LFUS sonication impacting the TiO(2) particles. This is in contrast to a number of well-established technologies, where the formation of oxygen vacancies on the TiO(2) surface often requires harsh technological conditions and complicated procedures, such as annealing at high temperatures, radio-frequency-induced plasma or ion sputtering. Thus, this study reports for the first time the preparation of visible-light responsive TiO(2)-based photocatalysts by using a simple LFUS-based approach to induce oxygen vacancies at the nano-TiO(2) surface. These findings might open new avenues for synthesis of novel nano-TiO(2)-based photocatalysts capable of destroying water or airborne pollutants and microorganisms under visible light illumination. PMID:22192787

  4. Analyzing low frequency waves associated with plasma sheet flow channels

    NASA Astrophysics Data System (ADS)

    Xing, X.; Liang, J.; Wang, C. P.; Lyons, L. R.; Angelopoulos, V.

    2014-12-01

    Low frequency (0.006~0.02 Hz) magnetic oscillations are frequently observed to be associated with the substorm-related dipolarization in the near-Earth plasma sheet. It has been suggested that these oscillations are possibly triggered by ballooning instability in the transition region. However, our multi-point observations using THEMIS spacecraft have shown that similar oscillations are observed to be associated with the earthward moving flow channels as they penetrate from middle tail to the transition region. Linear MHD wave analysis suggested that these oscillations ahead of the dipolarization front are magnetosonic waves. For most of the cases, the thermal pressure and magnetic pressures variations are anti-phase, indicating slow mode waves. However, by taking advantage of the spacecraft located very close in X-Y plane and slightly away from the central plasma sheet, we found that for many events the phase relation between the thermal and magnetic pressure variations is Z-dependent, which suggests that the observational evidence for slow mode may not be applicable. In order to further examine these waves, we performed a MHD analysis in inhomogeneous plasma sheet. The calculation shows that for Harris Sheet configuration, the thermal and magnetic pressures variations can be anti-phase for any wave other than slow mode waves where the vertical velocity disturbance reaches its maximum, thus this phase relation may not be used as an identifier of magnetosonic wave modes. We will show the dispersion relation and wave generated disturbances obtained from the numerical calculations.

  5. Radio-frequency heating of the coronal plasma during flares

    NASA Technical Reports Server (NTRS)

    Melrose, D. B.; Dulk, G. A.

    1984-01-01

    A model is developed for the radio-frequency (RF) heating of soft X-ray emitting plasma in solar flares due to absorption of amplified cyclotron radiation. The radiation, carrying approximately 10 to the 27th to approximately 10 to the 30th erg/s, is generated through maser emission following partial precipitation of electrons in one or more flaring loops. The maser operates in a large number of small regions, each producing an 'elementary burst' (EB) of short duration. This radiation propagates either directly or after reflection to the second-harmonic absorption layer, where it is absorbed by thermal electrons. The properties of EBs and the heating of the electrons in the absorption layer are discussed in detail. RF heating and evaporation models for the production of soft X-ray emitting plasma are compared. Properties of the RF heating model that explain observed features are energy transport across field lines, rapid heating (in approximately 1 s) of coronal plasma to approximately 3 x 10 to the 7th K, and instigation of turbulent velocities up to the ion sound speed.

  6. Reduction and degradation of amyloid aggregates by a pulsed radio-frequency cold atmospheric plasma jet

    NASA Astrophysics Data System (ADS)

    Bayliss, D. L.; Walsh, J. L.; Shama, G.; Iza, F.; Kong, M. G.

    2009-11-01

    Surface-borne amyloid aggregates with mature fibrils are used as a non-infectious prion model to evaluate cold atmospheric plasmas (CAPs) as a prion inactivation strategy. Using a helium-oxygen CAP jet with pulsed radio-frequency (RF) excitation, amyloid aggregates deposited on freshly cleaved mica discs are reduced substantially leaving only a few spherical fragments of sub-micrometer sizes in areas directly treated by the CAP jet. Outside the light-emitting part of the CAP jet, plasma treatment results in a 'skeleton' of much reduced amyloid stacks with clear evidence of fibril fragmentation. Analysis of possible plasma species and the physical configuration of the jet-sample interaction suggests that the skeleton structures observed are unlikely to have arisen as a result of physical forces of detachment, but instead by progressive diffusion of oxidizing plasma species into porous amyloid aggregates. Composition of chemical bonds of this reduced amyloid sample is very different from that of intact amyloid aggregates. These suggest the possibility of on-site degradation by CAP treatment with little possibility of spreading contamination elsewhere , thus offering a new reaction chemistry route to protein infectivity control with desirable implications for the practical implementation of CAP-based sterilization systems.

  7. Analytic model and frequency characteristics of plasma synthetic jet actuator

    NASA Astrophysics Data System (ADS)

    Zong, Hao-hua; Wu, Yun; Li, Ying-hong; Song, Hui-min; Zhang, Zhi-bo; Jia, Min

    2015-02-01

    This paper reports a novel analytic model of a plasma synthetic jet actuator (PSJA), considering both the heat transfer effect and the inertia of the throat gas. Both the whole cycle characteristics and the repetitive working process of PSJA can be predicted with this model. The frequency characteristics of a PSJA with 87 mm3 volume and different orifice diameters are investigated based on the analytic model combined with experiments. In the repetitive working mode, the actuator works initially in the transitional stage with 20 cycles and then in the dynamic balanced stage. During the transitional stage, major performance parameters of PSJA experience stepped growth, while during the dynamic balanced stage, these parameters are characterized by periodic variation. With a constant discharge energy of 6.9 mJ, there exists a saturated frequency of 4 kHz/6 kHz for an orifice diameter of 1 mm/1.5 mm, at which the time-averaged total pressure of the pulsed jet reaches a maximum. Between 0.5 mm and 1.5 mm, a larger orifice diameter leads to a higher saturated frequency due to the reduced jet duration time. As the actuation frequency increases, both the time-averaged cavity temperature and the peak jet velocity initially increase and then remain almost unchanged at 1600 K and 280 m/s, respectively. Besides, with increasing frequency, the mechanical energy incorporated in single pulsed jet, the expelled mass per pulse, and the time-averaged density in the cavity, decline in a stair stepping way, which is caused by the intermittent decrease of refresh stage duration in one period.

  8. Observation of upper drift modes in radio frequency produced magnetized plasmas with frequency above ion cyclotron frequency

    NASA Astrophysics Data System (ADS)

    Ghosh, Abhijit; Saha, S. K.; Chowdhury, S.; Janaki, M. S.

    2015-12-01

    In a RF produced magnetized argon plasma expanding into a larger expansion chamber, electrostatic modes propagating azimuthally in the direction of the electron diamagnetic drift and frequency greater than the ion cyclotron frequency are observed. In the radial direction, the mode amplitude peaks at a location where the radial density gradient is maximum. The modes are detected at axial locations up to 16 cm away from the entrance aperture. For fixed values of the neutral pressure and magnetic field, the mode frequency is found to be independent of the location at which it is measured. The modes exhibit drift wave characteristics revealing a radial structure with the azimuthal mode number m = 1 at the lower radial locations (r ˜ 3.0 cm) while the m = 2 mode is located in the outer region. Theoretical modeling using a local dispersion relation based on the fluid equations predicts destabilization of the modes with frequency greater than the ion-cyclotron frequency by electron-neutral collisions and exhibiting other drift wave features.

  9. Observation of upper drift modes in radio frequency produced magnetized plasmas with frequency above ion cyclotron frequency

    SciTech Connect

    Ghosh, Abhijit; Saha, S. K.; Chowdhury, S.; Janaki, M. S.

    2015-12-15

    In a RF produced magnetized argon plasma expanding into a larger expansion chamber, electrostatic modes propagating azimuthally in the direction of the electron diamagnetic drift and frequency greater than the ion cyclotron frequency are observed. In the radial direction, the mode amplitude peaks at a location where the radial density gradient is maximum. The modes are detected at axial locations up to 16 cm away from the entrance aperture. For fixed values of the neutral pressure and magnetic field, the mode frequency is found to be independent of the location at which it is measured. The modes exhibit drift wave characteristics revealing a radial structure with the azimuthal mode number m = 1 at the lower radial locations (r ∼ 3.0 cm) while the m = 2 mode is located in the outer region. Theoretical modeling using a local dispersion relation based on the fluid equations predicts destabilization of the modes with frequency greater than the ion-cyclotron frequency by electron-neutral collisions and exhibiting other drift wave features.

  10. The reaction pathways of the oxygen plasma pulse in the hafnium oxide atomic layer deposition process

    SciTech Connect

    Jeon, Hyeongtag; Won, Youngdo

    2008-09-22

    The plasma enhanced atomic layer deposition process for the HfO{sub 2} thin film is modeled as simple reactions between Hf(OH){sub 3}NH{sub 2} and reactive oxygen species. The density functional theory calculation was performed for plausible reaction pathways to construct the reaction profile. While the triplet molecular oxygen is unlikely to form a reactive complex, the singlet molecular oxygen forms the stable adduct that goes through the transition state and completes the reaction pathway to the products. Either two singlet or two triplet oxygen atoms make the singlet adduct complex, which follows the same pathway to the product as the singlet molecular oxygen reacts.

  11. A linear radio frequency plasma reactor for potential and current mapping in a magnetized plasma

    SciTech Connect

    Faudot, E.; Devaux, S.; Moritz, J.; Heuraux, S.; Molina Cabrera, P.; Brochard, F.

    2015-06-15

    Langmuir probe measurements in front of high power ion cyclotron resonant frequency antennas are not possible or simply too noisy to be analyzed properly. A linear experiment is a radio frequency (RF) magnetized plasma discharge reactor designed to probe the rectified potential in front of such antennas but at low power level (1 kW) to next improve antenna design and mitigate sheath effects. The maximum magnetic field is 0.1 T, and the RF amplifier can work between 10 kHz and 250 MHz allowing ion cyclotron resonances for argon or helium. The first measurements with no magnetic field are presented here, especially 2D potential maps extracted from the RF compensated probe measurements yield ni ≈ 10{sup 15} m{sup −3} and Te ≈ 2 eV for RF power lower than 100 W. Series resonances in the chamber are highlighted and allow to deduce the plasma parameters from a simple equivalent impedance model of the plasma in helium gas. Next studies will be focused on magnetized plasmas and especially magnetized RF sheaths.

  12. A linear radio frequency plasma reactor for potential and current mapping in a magnetized plasma.

    PubMed

    Faudot, E; Devaux, S; Moritz, J; Heuraux, S; Molina Cabrera, P; Brochard, F

    2015-06-01

    Langmuir probe measurements in front of high power ion cyclotron resonant frequency antennas are not possible or simply too noisy to be analyzed properly. A linear experiment is a radio frequency (RF) magnetized plasma discharge reactor designed to probe the rectified potential in front of such antennas but at low power level (1 kW) to next improve antenna design and mitigate sheath effects. The maximum magnetic field is 0.1 T, and the RF amplifier can work between 10 kHz and 250 MHz allowing ion cyclotron resonances for argon or helium. The first measurements with no magnetic field are presented here, especially 2D potential maps extracted from the RF compensated probe measurements yield ni ≈ 10(15) m(-3) and Te ≈ 2 eV for RF power lower than 100 W. Series resonances in the chamber are highlighted and allow to deduce the plasma parameters from a simple equivalent impedance model of the plasma in helium gas. Next studies will be focused on magnetized plasmas and especially magnetized RF sheaths. PMID:26133834

  13. A mechanism for plasma waves at the harmonics of the plasma frequency foreshock boundary

    NASA Technical Reports Server (NTRS)

    Klimas, A. J.

    1982-01-01

    A bump-on-tail unstable reduced velocity distribution, constructed from data obtained at the upstream boundary of the electron foreshock by the GSFC electron spectrometer experiment on the ISEE-1 satellite, is used as the initial plasma state for a numerical integration of the 1D-Vlasov-Maxwell system of equations. The integration is carried through the growth of the instability, beyond its saturation, and well into the stabilized plasma regime. A power spectrum computed for the electric field of the stabilized plasma is dominated by a narrow peak at the Bohm-Gross frequency of the unstable field mode but also contains significant power at the harmonics of the Bohm-Gross frequency. The harmonic power is in sharp peaks which are split into closely spaced doublets. The fundamental peak at the Bohm-Gross frequency is split into a closely spaced triplet. The mechanism for excitation of the second harmonic is shown to be second order wave-wave coupling.

  14. Plasma and cyclotron frequency effects on output power of the plasma wave-pumped free-electron lasers

    NASA Astrophysics Data System (ADS)

    Zolghadr, S. H.; Jafari, S.; Raghavi, A.

    2016-05-01

    Significant progress has been made employing plasmas in the free-electron lasers (FELs) interaction region. In this regard, we study the output power and saturation length of the plasma whistler wave-pumped FEL in a magnetized plasma channel. The small wavelength of the whistler wave (in sub-μm range) in plasma allows obtaining higher radiation frequency than conventional wiggler FELs. This configuration has a higher tunability by adjusting the plasma density relative to the conventional ones. A set of coupled nonlinear differential equations is employed which governs on the self-consistent evolution of an electromagnetic wave. The electron bunching process of the whistler-pumped FEL has been investigated numerically. The result reveals that for a long wiggler length, the bunching factor can appreciably change as the electron beam propagates through the wiggler. The effects of plasma frequency (or plasma density) and cyclotron frequency on the output power and saturation length have been studied. Simulation results indicate that with increasing the plasma frequency, the power increases and the saturation length decreases. In addition, when density of background plasma is higher than the electron beam density (i.e., for a dense plasma channel), the plasma effects are more pronounced and the FEL-power is significantly high. It is also found that with increasing the strength of the external magnetic field frequency, the power decreases and the saturation length increases, noticeably.

  15. A parametric study of the destruction efficiency of Bacillus spores in low pressure oxygen-based plasmas.

    PubMed

    Hury, S; Vidal, D R; Desor, F; Pelletier, J; Lagarde, T

    1998-06-01

    The destruction of Bacillus spores in oxygen-based plasmas sustained in the millitorr pressure range has been studied as functions of various biological and plasma parameters, namely Bacillus species, surface concentration of spores, treatment temperature, and gas composition. In an oxygen plasma, Bacillus stearothermophilus appears less plasma-resistant than the other spores tested. Oxygen, H2O2 and chiefly CO2 plasmas are clearly shown to be much more efficient in destroying Bacillus subtilis spores than pure argon plasma. The bacterial surface concentration on the spore carriers and the treatment temperature also lead to significant variations in the destruction efficiency of spores when using CO2 plasma. PMID:9717311

  16. Simulating NIF laser-plasma interaction with multiple SRS frequencies

    SciTech Connect

    Still, C H; Hinkel, D E; Langdon, A B; Palastro, J P; Williams, E A

    2009-10-05

    Understanding the energetics of a NIF ignition hohlraum is important to achieving ignition. Laser-plasma interactions (LPI) can reduce the radiation drive if backscatter occurs, and can also affect the hohlraum energetics by modifying the laser beam energy deposition which in turn can alter the implosion symmetry. The addition of a second SRS frequency to the modeling code pF3d can capture physics which would otherwise have been omitted. In the case of a wide or bi-modal SRS spectrum, this physics can be important. We discuss the modifications to the pF3d computational model, and exhibit its effect in a NIF ignition-relevant LPI simulation.

  17. Oxygen post-treatment of plastic surface coated with plasma polymerized silicon-containing monomers

    NASA Technical Reports Server (NTRS)

    Wydeven, T. J.; Hollanhan, J. R., Jr. (Inventor)

    1979-01-01

    The abrasion resistance of plastic surfaces coated with polymerized organosilanes can be significantly improved by post-treatment of the polymerized silane in an oxygen plasma. For optical purposes, the advantages of this post-treatment are developed with a transparent polycarbonate resin substrate coated with plasma polymerized vinyltrimethoxysilane.

  18. EEDF evolution in pulsed radio-frequency plasmas

    NASA Astrophysics Data System (ADS)

    El Otell, Ziad; Bowden, Mark; Braithwaite, Nicholas

    2012-10-01

    We investigate the evolution of the electron energy distribution function (EEDF) in pulsed radio-frequency plasmas using a simple form of trace rare gas optical emission spectroscopy. For steady-state discharges, methods exist to determine electron temperatures and EEDFs using emission measurements and collisional radiative models. However, these methods rely on the EEDF being stable and are difficult to use in the rapidly changing transients in a pulsed discharge. We assess a simpler technique in which we compare the time-dependence of emission from different plasma species in order to infer information about the evolution of the EEDF. The study was carried out in a capacitively coupled rf discharge generated in a Gaseous Electronic Conference (GEC) reference reactor. The gas mixture consisted of mainly argon with small amounts of xenon and krypton. Emission was measured on specific lines from argon, krypton and xenon, chosen due to their emission being predominantly due to direct excitation from the ground state. For the case of square pulse excitation, the EEDF in the early part of each pulse was dominated by beam-like electrons with high energy. This beam-like EEDF phase was absent when a pulse with a less steep rise time was used.

  19. Radio-Frequency Plasma Cleaning of a Penning Malmberg Trap

    NASA Technical Reports Server (NTRS)

    Sims, William Herbert, III; Martin, James; Pearson, J. Boise; Lewis, Raymond

    2005-01-01

    Radio-frequency-generated plasma has been demonstrated to be a promising means of cleaning the interior surfaces of a Penning-Malmberg trap that is used in experiments on the confinement of antimatter. {Such a trap was reported in Modified Penning-Malmberg Trap for Storing Antiprotons (MFS-31780), NASA Tech Briefs, Vol. 29, No. 3 (March 2005), page 66.} Cleaning of the interior surfaces is necessary to minimize numbers of contaminant atoms and molecules, which reduce confinement times by engaging in matter/antimatter-annihilation reactions with confined antimatter particles. A modified Penning-Malmberg trap like the one described in the cited prior article includes several collinear ring electrodes (some of which are segmented) inside a tubular vacuum chamber, as illustrated in Figure 1. During operation of the trap, a small cloud of charged antiparticles (e.g., antiprotons or positrons) is confined to a spheroidal central region by means of a magnetic field in combination with DC and radiofrequency (RF) electric fields applied via the electrodes. In the present developmental method of cleaning by use of RF-generated plasma, one evacuates the vacuum chamber, backfills the chamber with hydrogen at a suitable low pressure, and uses an RF-signal generator and baluns to apply RF voltages to the ring electrodes. Each ring is excited in the polarity opposite that of the adjacent ring. The electric field generated by the RF signal creates a discharge in the low-pressure gas. The RF power and gas pressure are adjusted so that the plasma generated in the discharge (see Figure 2) physically and chemically attacks any solid, liquid, and gaseous contaminant layers on the electrode surfaces. The products of the physical and chemical cleaning reactions are gaseous and are removed by the vacuum pumps.

  20. Oxygen plasma surface modification enhances immobilization of simvastatin acid.

    PubMed

    Yoshinari, Masao; Hayakawa, Tohru; Matsuzaka, Kenichi; Inoue, Takashi; Oda, Yutaka; Shimono, Masaki; Ide, Takaharu; Tanaka, Teruo

    2006-02-01

    Simvastatin acid (SVA) has been reported to stimulate bone formation with increased expression of BMP-2. Therefore, immobilization of SVA onto dental implants is expected to promote osteogenesis at the bone tissue/implant interface. The aim of this study was to evaluate the immobilization behavior of SVA onto titanium (Ti), O(2)-plasma treated titanium (Ti + O(2)), thin-film coatings of hexamethyldisiloxane (HMDSO), and O(2)-plasma treated HMDSO (HMDSO + O(2)) by using the quartz crystal microbalance-dissipation (QCM-D) technique. HMDSO surfaces were activated by the introduction of an OH group and/or O(2)-functional groups by O(2)-plasma treatment. In contrast, titanium surfaces showed no appreciable compositional changes by O(2)-plasma treatment. The QCM-D technique enabled evaluation even at the adsorption behavior of a substance with a low molecular weight such as simvastatin. The largest amount of SVA was adsorbed on O(2)-plasma treated HMDSO surfaces compared to untreated titanium, HMDSO-coated titanium, and O(2)-plasma treated titanium. These findings suggested that the adsorption of SVA was enhanced on more hydrophilic surfaces concomitant with the presence of an OH group and/or O(2)-functional group resulting from the O(2)-plasma treatment, and that an organic film of HMDSO followed by O(2)-plasma treatment is a promising method for the adsorption of SVA in dental implant systems. PMID:16543663

  1. Oxygen plasma ashing effects on aluminum and titanium space protective coatings

    NASA Technical Reports Server (NTRS)

    Synowicki, R.; Kubik, R. D.; Hale, J. S.; Peterkin, Jane; Nafis, S.; Woollam, John A.; Zaat, S.

    1991-01-01

    Using variable angle spectroscopic ellipsometry and atomic force microscopy (AFM), the surface roughness and oxidation of aluminum and titanium thin films have been studied as a function of substrate deposition temperature and oxygen plasma exposure. Increasing substrate deposition temperatures affect film microstructure by greatly increasing grain size. Short exposures to an oxygen plasma environment produce sharp spikes rising rapidly above the surface as seen by AFM. Ellipsometric measurements were made over a wide range of plasma exposure times, and results at longer exposure times suggest that the surface is greater than 30% void. This is qualitatively verified by the AFM images.

  2. Relationship between the discharge mode and the spatial oxygen plasma distribution in a large size ferrite inductively coupled plasmas

    SciTech Connect

    Kim, Hyun Jun; Hwang, Hye Ju; Cho, Jeong Hee; Chae, Hee Sun; Kim, Dong Hwan; Chung, Chin-Wook

    2015-04-15

    The electrical characteristics and the spatial distribution of oxygen plasma according to the number of turns in ferrite inductively coupled plasmas (ferrite ICPs) are investigated. Through a new ICP model, which includes the capacitive coupling and the power loss of the ferrite material with the conventional ICP model, the variation of the oxygen discharge characteristics depending on the number of turns is simply understood by the electrical measurement, such as the antenna voltages and the currents. As the number of the turns increases, the capacitive coupling dominantly affects the spatial plasma distribution. This capacitive coupling results in a center focused density profile along the radial direction. In spite of the same discharge conditions (discharge chamber, neutral gas, and pressure), the spatial plasma distribution over 450 mm has drastic changes by increasing number of the turns. In addition, the effect of the negative species to the density profile is compared with the argon discharge characteristics at the same discharge configuration.

  3. Plasma corticosteroid dynamics in channel catfish, Ictalurus punctatus (Rafinesque), during and after oxygen depletion

    USGS Publications Warehouse

    Tomasso J.R., Davis, K. B.; Parker, N.C.

    1981-01-01

    Plasma corticosteroid concentrations in channel catfish, Ictalurus punctatus, (normally 1.0 ± 0.3 μg/100 ml) increased significantly (to 5.9 ± 1.2μg/100 ml) in response to acute oxygen depletion and then returned to control levels within 30 min after the dissolved oxygen concentration was increased; however, a secondary increase in plasma corticosteroid levels was observed 6 h after exposure. Corticosteroid levels also increased in fish exposed to dissolved oxygen concentration of <0.2 mg/1 for three days. Methylene blue was not effective in preventing interrenal response to low dissolved oxygen. No diurnal plasma corticosteroid rhythm was observed in fish exposed to diurnal chemical rhythms of culture ponds.

  4. Sensitivity enhancement of carbon nanotube based ammonium ion sensors through surface modification by using oxygen plasma treatment

    SciTech Connect

    Yeo, Sanghak; Woong Jang, Chi; Lee, Seok; Min Jhon, Young; Choi, Changrok

    2013-02-18

    We have shown that the sensitivity of carbon nanotube (CNT) based sensors can be enhanced as high as 74 times through surface modification by using the inductively coupled plasma chemical vapor deposition method with oxygen. The plasma treatment power was maintained as low as 10 W within 20 s, and the oxygen plasma was generated far away from the sensors to minimize the plasma damage. From X-ray photoelectron spectroscopy analysis, we found that the concentration of oxygen increased with the plasma treatment time, which implies that oxygen functional groups or defect sites were generated on the CNT surface.

  5. High-frequency electrostatic modes in non-neutral plasmas

    NASA Astrophysics Data System (ADS)

    Book, David L.

    1995-05-01

    A fluid description is employed to derive the dispersion relation for cyclotron modes in a cylindrical non-neutral plasma of radius R confined by a uniform magnetic field B=B0ez inside a chamber with conducting walls of radius R0. In contrast to the theory of Gould and LaPointe [Phys. Rev. Lett. 67, 3685 (1991); Phys. Fluids B 4, 2038 (1992)] the model includes the diamagnetic drift but omits finite Larmor radius effects. The density and the temperature of the unperturbed state are taken to be n(r)=n0(1-r2/R2) and T(r)=T0(1-r2/R2)γ-1, where γ is the adiabatic index, so that the r-dependent slow rotation frequency is ωr≊-[δ(1-r2/2R2)+ɛ(1-r2/R2)γ-2]Ω/2, where Ω=qB0/Mc is the ion gyrofrequency, δ=4πn0q2/MΩ2, and ɛ=4γT0/MΩ2R2. For the linearized fluid equations together with the Poisson equation the eigenvalue problem is solved in the limit δ≪1, ɛ≪1. The eigenfrequencies for high-frequency electrostatic modes with wave vectors satisfying kṡB=0 (Bernstein modes) are found in the form ω=-Ω+Δω, where Δω/Ω contains terms proportional to δ and ɛ. Solutions are obtained and compared with experiment and the theory of Gould and LaPointe. The present theory predicts that at a given T0 modes with m≳1 propagate only when the density is less than a critical value that increases with m, and that Δω normalized by the diocotron frequency depends only on the ratio of the Debye length to the plasma radius and hence is independent of B and M. The predictions of the two theories differ in several other respects; future observations may serve to decide between them.

  6. Nightmares and oxygen desaturations: is sleep apnea related to heightened nightmare frequency?

    PubMed

    Schredl, Michael; Schmitt, Judith; Hein, Gerhard; Schmoll, Tina; Eller, Sabine; Haaf, Janina

    2006-12-01

    In the 19th century, several authors held the view that nightmares are caused by oxygen shortage. The present study was designed to study nightmare frequency in patients with obstructive sleep apnea syndrome and its relationship to respiratory parameters. A brief questionnaire was administered to 323 patients with sleep apnea syndrome before their first laboratory night. The reduction in nightmare frequency in the sleep apnea group was explained by the reduced dream recall frequency. Despite some illustrative examples of a correlation between oxygen desaturation and dream content, the respiratory parameters as measures of sleep apnea syndrome severity did not correlate substantially with nightmare frequency. Psychiatric comorbidity and an intake of psychotropic medication were associated with heightened nightmare frequency in this sample. It must be concluded that the oxygen hypothesis did not play a major role in explaining the occurrence of nightmares. As this might be partly explained by adaptation to the nightly desaturation periods, it will be fruitful to apply experimental procedures that interrupt airflow during (rapid eye movement) REM sleep for short periods in a systematic way without the knowledge of the sleeper and to then study their effects on dream content. Some patients reported a correlation between daytime stressors and nightmares, which is in line with modern etiological models of nightmares. PMID:17061140

  7. Dynamics of a pulsed laser generated tin plasma expanding in an oxygen atmosphere

    NASA Astrophysics Data System (ADS)

    Barreca, F.; Fazio, E.; Neri, F.; Barletta, E.; Trusso, S.; Fazio, B.

    2005-10-01

    Semiconducting tin oxide can be successfully deposited by means of the laser ablation technique. In particular by ablating metallic tin in a controlled oxygen atmosphere, thin films of SnOx have been deposited. The partial oxygen pressure at which the films are deposited strongly influences both the stoichiometry and the structural properties of the films. In this work, we present a study of the expansion dynamics of the plasma generated by ablating a tin target by means of a pulsed laser using time and space resolved optical emission spectroscopy and fast photography imaging of the expanding plasma. Both Sn I and Sn II optical emission lines have been observed from the time-integrated spectroscopy. Time resolved-measurements revealed the dynamics of the expanding plasma in the ambient oxygen atmosphere. Stoichiometry of the films has been determined by means of X-ray photoelectron spectroscopy and correlated to the expansion dynamics of the plasma.

  8. First-in-human pilot study of a spatial frequency domain oxygenation imaging system

    PubMed Central

    Gioux, Sylvain; Mazhar, Amaan; Lee, Bernard T.; Lin, Samuel J.; Tobias, Adam M.; Cuccia, David J.; Stockdale, Alan; Oketokoun, Rafiou; Ashitate, Yoshitomo; Kelly, Edward; Weinmann, Maxwell; Durr, Nicholas J.; Moffitt, Lorissa A.; Durkin, Anthony J.; Tromberg, Bruce J.; Frangioni, John V.

    2011-01-01

    Oxygenation measurements are widely used in patient care. However, most clinically available instruments currently consist of contact probes that only provide global monitoring of the patient (e.g., pulse oximetry probes) or local monitoring of small areas (e.g., spectroscopy-based probes). Visualization of oxygenation over large areas of tissue, without a priori knowledge of the location of defects, has the potential to improve patient management in many surgical and critical care applications. In this study, we present a clinically compatible multispectral spatial frequency domain imaging (SFDI) system optimized for surgical oxygenation imaging. This system was used to image tissue oxygenation over a large area (16×12 cm) and was validated during preclinical studies by comparing results obtained with an FDA-approved clinical oxygenation probe. Skin flap, bowel, and liver vascular occlusion experiments were performed on Yorkshire pigs and demonstrated that over the course of the experiment, relative changes in oxygen saturation measured using SFDI had an accuracy within 10% of those made using the FDA-approved device. Finally, the new SFDI system was translated to the clinic in a first-in-human pilot study that imaged skin flap oxygenation during reconstructive breast surgery. Overall, this study lays the foundation for clinical translation of endogenous contrast imaging using SFDI. PMID:21895327

  9. First-in-human pilot study of a spatial frequency domain oxygenation imaging system

    NASA Astrophysics Data System (ADS)

    Gioux, Sylvain; Mazhar, Amaan; Lee, Bernard T.; Lin, Samuel J.; Tobias, Adam M.; Cuccia, David J.; Stockdale, Alan; Oketokoun, Rafiou; Ashitate, Yoshitomo; Kelly, Edward; Weinmann, Maxwell; Durr, Nicholas J.; Moffitt, Lorissa A.; Durkin, Anthony J.; Tromberg, Bruce J.; Frangioni, John V.

    2011-08-01

    Oxygenation measurements are widely used in patient care. However, most clinically available instruments currently consist of contact probes that only provide global monitoring of the patient (e.g., pulse oximetry probes) or local monitoring of small areas (e.g., spectroscopy-based probes). Visualization of oxygenation over large areas of tissue, without a priori knowledge of the location of defects, has the potential to improve patient management in many surgical and critical care applications. In this study, we present a clinically compatible multispectral spatial frequency domain imaging (SFDI) system optimized for surgical oxygenation imaging. This system was used to image tissue oxygenation over a large area (16×12 cm) and was validated during preclinical studies by comparing results obtained with an FDA-approved clinical oxygenation probe. Skin flap, bowel, and liver vascular occlusion experiments were performed on Yorkshire pigs and demonstrated that over the course of the experiment, relative changes in oxygen saturation measured using SFDI had an accuracy within 10% of those made using the FDA-approved device. Finally, the new SFDI system was translated to the clinic in a first-in-human pilot study that imaged skin flap oxygenation during reconstructive breast surgery. Overall, this study lays the foundation for clinical translation of endogenous contrast imaging using SFDI.

  10. Effects of oxygen radicals in low-pressure surface-wave plasma on sterilization

    SciTech Connect

    Nagatsu, Masaaki; Terashita, Fumie; Nonaka, Hiroyuki; Xu, Lei; Nagata, Toshi; Koide, Yukio

    2005-05-23

    The effects of oxygen radicals on sterilization were studied using a 2.45 GHz surface-wave oxygen plasma. A population of 1.5x10{sup 6} Bacillus stearothermophilus spores was irradiated for 3 min or more with oxygen plasma, generated at pressures between 6 and 14 Pa. The decimal reduction value (D value), a measure of the effectiveness of sterilization, was determined to be about 15-25 s. Using only oxygen radicals, excluding all charged particles, the 1.5x10{sup 6} spores were sterilized with a D value of 30-45 s after 5 min or more of irradiation. On scanning electron microscopy, the length and width of the spores changed significantly due to chemical etching by oxygen radicals.

  11. Effects of oxygen radicals in low-pressure surface-wave plasma on sterilization

    NASA Astrophysics Data System (ADS)

    Nagatsu, Masaaki; Terashita, Fumie; Nonaka, Hiroyuki; Xu, Lei; Nagata, Toshi; Koide, Yukio

    2005-05-01

    The effects of oxygen radicals on sterilization were studied using a 2.45GHz surface-wave oxygen plasma. A population of 1.5×106 Bacillus stearothermophilus spores was irradiated for 3min or more with oxygen plasma, generated at pressures between 6 and 14Pa. The decimal reduction value (D value), a measure of the effectiveness of sterilization, was determined to be about 15-25s. Using only oxygen radicals, excluding all charged particles, the 1.5×106 spores were sterilized with a D value of 30-45s after 5min or more of irradiation. On scanning electron microscopy, the length and width of the spores changed significantly due to chemical etching by oxygen radicals.

  12. Ponderomotive Force and Lower Hybrid Turbulence Effects in Space Plasmas Subjected to Large-Amplitude Low-Frequency Waves

    NASA Technical Reports Server (NTRS)

    Khazanov, G. V.; Khazanov, George; Liemohn, M. W.; Stone, N. H.; Coffey, V. N.

    1997-01-01

    In the auroral region, simultaneous occurrences of upward-flowing ions and field-aligned electrons have been observed by the Viking satellite. The occurrence is strongly correlated with large amplitude low frequency fluctuations of the electric field. Large-amplitude shear Alfven waves have also been observed by sounding rockets in the auroral ionosphere. When such LF waves are propagating in a plasma, a ponderomotive force and other types of waves are produced which may lead to significant effects on the plasma. This force is directed toward decreasing density, providing the electromagnetic lift of the background plasma and an increase of collisionless plasma expansion. We find that even for modest wave strengths, the influence on the outflowing oxygen ions can be dramatic, increasing the high-altitude density by orders of magnitude. It is also demonstrated that large-amplitude low-frequency waves (LFW) may generate lower hybrid waves (LHW) in the auroral zone. The excitation of LHW by a LF wave may lead to the appearance of an additional channel of energy transfer from, for example, Alfven or fast magnetosonic waves, to particles. This process then influences the formation of the plasma distribution function at the expense of acceleration in the tail of the distribution during the collapse of the LHW. The ion energization due to the LHW can be comparable with that produced by the ponderomotive force of the LFW. It is shown that the LH turbulence leads to equalization of the ponderomotive acceleration of the different ion species. The mechanism of LHW excitation due to the oxygen ion relative drift in a plasma subjected to low-frequency waves is used for analysis of Viking satellite data for events in the cusp/cleft region. It is found that, in some cases, such a mechanism leads to LHW energy densities and ion distribution functions close to those observed.

  13. Ion cyclotron range of frequencies heating of plasma with small impurity production

    DOEpatents

    Ohkawa, Tihiro

    1987-01-01

    Plasma including plasma ions is magnetically confined by a magnetic field. The plasma has a defined outer surface and is intersected by resonance surfaces of respective common ion cyclotron frequency of a predetermined species of plasma ions moving in the magnetic field. A radio frequency source provides radio frequency power at a radio frequency corresponding to the ion cyclotron frequency of the predetermined species of plasma ions moving in the field at a respective said resonance surface. RF launchers coupled to the radio frequency source radiate radio frequency energy at the resonance frequency onto the respective resonance surface within the plasma from a plurality of locations located outside the plasma at such respective distances from the intersections of the respective resonance surface and the defined outer surface and at such relative phases that the resulting interference pattern provides substantially null net radio frequency energy over regions near and including substantial portions of the intersections relative to the radio frequency energy provided thereby at other portions of the respective resonance surface within the plasma.

  14. Chaos and catastrophe near the plasma frequency in the rf-biased Josephson junction

    SciTech Connect

    Kautz, R.L.; Monaco, R.

    1989-03-01

    At bias frequencies much higher than the plasma frequency, the zero-voltage state of the rf-biased Josephson junction is known to span a range of dc bias proportional to the zero-order Bessel function of the rf amplitude. This pattern is modified at frequencies near the plasma frequency by the onset of chaotic instabilities and by the presence of cusp catastrophes.

  15. Solar Corona and plasma effects on Radio Frequency waves

    NASA Astrophysics Data System (ADS)

    Nkono, C.; Rosenblatt, P.; Dehant, V. M.

    2009-12-01

    Solar corona (plasma) effects on radio signal waves for three different frequency bands S (2.3 GHz), X (8.4 GHz), and Ka (32 GHz), currently used to track probes in the solar system, have been computed using different models of the total electron content (TEC) along the propagation path between the Earth and Mars. The Earth-Mars-Sun configuration has been obtained from the planetary ephemerides DE421 (using SPICE kernels) for the period from September 2004 to September 2006. This configuration is expressed as a function of the Sun-Earth-Probe (SEP) angles (the probe being in close orbit to Mars). We used the TEC values provided by the different models proposed in the literature in order to estimate the TEC along the propagation path (STEC, for Slant TEC). From these model-dependent STEC estimates, the time delay on the wave propagation as well as the associated frequency shift with a 10 seconds sampling time have been obtained for each of the three frequency bands. For the X-band mostly used in radio science, we have obtained estimates differing by up to several orders of magnitude due to the different STEC values derived from different models of TEC. For example, if the propagation path passes near the Sun such that SEP angle is 1.55° the STEC is ranging from 4.6x1020 electron/m2 to 6.07x1016 electron/m2, which corresponds to a time delay range between 0.87 μs and 1.15x10-4 μs, respectively. For SEP angles between 2° and 8°, the range of the different time delay values reduces to 2.8x10-1 μs and becomes as small as 1.6x10-2 μs for SEP angles larger than 8° (1x10-2 μs is about the order of magnitude of the radioscience instrument precision). These results show that the correction of the solar corona effect on radio frequency waves can be reliably done on usual X-band tracking data of spacecraft for SEP angles >12°, but should be use with caution for lower SEP angles, especially lower than 2°.

  16. Combined effect of protein and oxygen on reactive oxygen and nitrogen species in the plasma treatment of tissue

    NASA Astrophysics Data System (ADS)

    Gaur, Nishtha; Szili, Endre J.; Oh, Jun-Seok; Hong, Sung-Ha; Michelmore, Andrew; Graves, David B.; Hatta, Akimitsu; Short, Robert D.

    2015-09-01

    The influence of protein and molecular, ground state oxygen (O2) on the plasma generation, and transport of reactive oxygen and nitrogen species (RONS) in tissue are investigated. A tissue target, comprising a 1 mm thick gelatin film (a surrogate for real tissue), is placed on top of a 96-well plate; each well is filled with phosphate buffered saline (PBS, pH 7.4) containing one fluorescent or colorimetric reporter that is specific for one of three RONS (i.e., H2O2, NO2-, or OH•) or a broad spectrum reactive oxygen species reporter (2,7-dichlorodihydrofluorescein). A helium cold atmospheric plasma (CAP) jet contacts the top of the gelatin surface, and the concentrations of RONS generated in PBS are measured on a microplate reader. The data show that H2O2, NO2-, or OH• are generated in PBS underneath the target. Independently, measurements are made of the O2 concentration in the PBS with and without the gelatin target. Adding bovine serum albumin protein to the PBS or gelatin shows that protein either raises or inhibits RONS depending upon the O2 concentration. Our results are discussed in the context of plasma-soft tissue interactions that are important in the development of CAP technology for medicine, biology, and food manufacturing.

  17. Low temperature oxidation of silicon in a microwave-discharged oxygen plasma

    SciTech Connect

    Kimura, S.I.; Miyake, K.; Murakami, E.; Sunami, H.; Tokuyama, T.; Warabisako, T.

    1985-06-01

    Silicon dioxide growth in an oxygen plasma is investigated using newly developed microwave discharge equipment with electron cyclotron resonance. It is found that the plasma oxidation kinetics can be explained by the Cabrera-Mott model, in which the drift motion of ions is assumed, rather than by the Deal-Grove thermal oxidation model. The drift motion of oxygen ions across the oxide film under the influence of self-bias in the plasma is considered to be the plasma oxidation mechanism. Infrared absorption and etch-rate measurements reveal that the physica properties of plasma oxidized SiO/sub 2/ at 600/sup 0/C are structurally quite comparable to those of thermally oxidized SiO/sub 2/.

  18. Identification of higher frequency plasma waves inside a Kelvin-Helmholtz vortex responsible for plasma heating and mixing

    NASA Astrophysics Data System (ADS)

    Moore, T.; Nykyri, K.; Dimmock, A. P.

    2014-12-01

    The magnetopause marks the boundary between the shocked solar wind and magnetospheric plasma. Understanding the dynamics of the plasma processes at the magnetopause boundary is crucial to the study of plasma transport into the magnetosphere. Previous studies have shown that there exists a temperature asymmetry in the plasma sheet. During northward IMF, the cold component ions are 30-40% hotter in the dawn flank plasma sheet compared to the dusk flank. However, the mechanisms responsible are still not entirely clear. Recent work has shown that reconnection in Kelvin-Helmholtz (KH) vortices can transport plasma into the magnetosphere. Previous studies have also shown that mode conversion at the magnetopause can generate kinetic Alfvén wave activity. Both magnetic reconnection and plasma wave activity can heat plasma. For the first time we have determined from observations the dispersion relation of higher frequency waves responsible for plasma mixing and heating within a KH vortex.

  19. Plasma-Engraved Co3 O4 Nanosheets with Oxygen Vacancies and High Surface Area for the Oxygen Evolution Reaction.

    PubMed

    Xu, Lei; Jiang, Qianqian; Xiao, Zhaohui; Li, Xingyue; Huo, Jia; Wang, Shuangyin; Dai, Liming

    2016-04-18

    Co3 O4 , which is of mixed valences Co(2+) and Co(3+) , has been extensively investigated as an efficient electrocatalyst for the oxygen evolution reaction (OER). The proper control of Co(2+) /Co(3+) ratio in Co3 O4 could lead to modifications on its electronic and thus catalytic properties. Herein, we designed an efficient Co3 O4 -based OER electrocatalyst by a plasma-engraving strategy, which not only produced higher surface area, but also generated oxygen vacancies on Co3 O4 surface with more Co(2+) formed. The increased surface area ensures the Co3 O4 has more sites for OER, and generated oxygen vacancies on Co3 O4 surface improve the electronic conductivity and create more active defects for OER. Compared to pristine Co3 O4 , the engraved Co3 O4 exhibits a much higher current density and a lower onset potential. The specific activity of the plasma-engraved Co3 O4 nanosheets (0.055 mA cm(-2) BET at 1.6 V) is 10 times higher than that of pristine Co3 O4 , which is contributed by the surface oxygen vacancies. PMID:26990905

  20. Changes in oxygen saturation and heart frequency during sleep in young normal subjects.

    PubMed Central

    Gimeno, F; Peset, R

    1984-01-01

    Changes in oxygen saturation and heart frequency were measured during sleep in a group of 21 normal subjects (9 women and 12 men) aged 19-25. At the time of the investigation all were non-smokers, they had no respiratory complaints, and indices of lung function (lung volumes, volume-pressure diagram, and diffusing capacity for carbon monoxide) were within normal limits. In contrast to published data, there were no major changes in oxygen saturation and no differences between men and women. PMID:6474401

  1. Assessment of plasma impedance probe for measuring electron density and collision frequency in a plasma with spatial and temporal gradients

    SciTech Connect

    Hopkins, Mark A. King, Lyon B.

    2014-05-15

    Numerical simulations and experimental measurements were combined to determine the ability of a plasma impedance probe (PIP) to measure plasma density and electron collision frequency in a plasma containing spatial gradients as well as time-varying oscillations in the plasma density. A PIP is sensitive to collision frequency through the width of the parallel resonance in the Re[Z]-vs.-frequency characteristic, while also being sensitive to electron density through the zero-crossing of the Im[Z]-vs.-frequency characteristic at parallel resonance. Simulations of the probe characteristic in a linear plasma gradient indicated that the broadening of Re[Z] due to the spatial gradient obscured the broadening due to electron collision frequency, preventing a quantitative measurement of the absolute collision frequency for gradients considered in this study. Simulation results also showed that the PIP is sensitive to relative changes in electron collision frequency in a spatial density gradient, but a second broadening effect due to time-varying oscillations made collision frequency measurements impossible. The time-varying oscillations had the effect of causing multiple zero-crossings in Im[Z] at parallel resonance. Results of experiments and simulations indicated that the lowest-frequency zero-crossing represented the lowest plasma density in the oscillations and the highest-frequency zero-crossing represented the highest plasma density in the oscillations, thus the PIP probe was found to be an effective tool to measure both the average plasma density as well as the maximum and minimum densities due to temporal oscillations.

  2. Assessment of plasma impedance probe for measuring electron density and collision frequency in a plasma with spatial and temporal gradients

    NASA Astrophysics Data System (ADS)

    Hopkins, Mark A.; King, Lyon B.

    2014-05-01

    Numerical simulations and experimental measurements were combined to determine the ability of a plasma impedance probe (PIP) to measure plasma density and electron collision frequency in a plasma containing spatial gradients as well as time-varying oscillations in the plasma density. A PIP is sensitive to collision frequency through the width of the parallel resonance in the Re[Z]-vs.-frequency characteristic, while also being sensitive to electron density through the zero-crossing of the Im[Z]-vs.-frequency characteristic at parallel resonance. Simulations of the probe characteristic in a linear plasma gradient indicated that the broadening of Re[Z] due to the spatial gradient obscured the broadening due to electron collision frequency, preventing a quantitative measurement of the absolute collision frequency for gradients considered in this study. Simulation results also showed that the PIP is sensitive to relative changes in electron collision frequency in a spatial density gradient, but a second broadening effect due to time-varying oscillations made collision frequency measurements impossible. The time-varying oscillations had the effect of causing multiple zero-crossings in Im[Z] at parallel resonance. Results of experiments and simulations indicated that the lowest-frequency zero-crossing represented the lowest plasma density in the oscillations and the highest-frequency zero-crossing represented the highest plasma density in the oscillations, thus the PIP probe was found to be an effective tool to measure both the average plasma density as well as the maximum and minimum densities due to temporal oscillations.

  3. Influence of oxygen in atmospheric-pressure argon plasma jet on sterilization of Bacillus atrophaeous spores

    SciTech Connect

    Lim, Jin-Pyo; Uhm, Han S.; Li, Shou-Zhe

    2007-09-15

    A nonequilibrium Ar/O{sub 2} plasma discharge at atmospheric pressure was carried out in a coaxial cylindrical reactor with a stepped electrode configuration powered by a 13.56 MHz rf power supplier. The argon glow discharge with high electron density produces oxygen reactive species in large quantities. Argon plasma jets penetrate deep into ambient air and create a path for oxygen radicals to sterilize microbes. A sterilization experiment with bacterial endospores indicates that an argon-oxygen plasma jet very effectively kills endospores of Bacillus atrophaeus (ATCC 9372), thereby demonstrating its capability to clean surfaces and its usefulness for reinstating contaminated equipment as free from toxic biological warfare agents. The decimal reduction time (D values) of the Ar/O{sub 2} plasma jet at an exposure distance of 0.5-1.5 cm ranges from 5 to 57 s. An actinometric comparison of the sterilization data shows that atomic oxygen radicals play a significant role in plasma sterilization. When observed under a scanning electron microscope, the average size of the spores appears to be greatly reduced due to chemical reactions with the oxygen radicals.

  4. Oxygen transport in the internal xenon plasma of a dispenser hollow cathode

    SciTech Connect

    Capece, Angela M. Shepherd, Joseph E.; Polk, James E.; Mikellides, Ioannis G.

    2014-04-21

    Reactive gases such as oxygen and water vapor modify the surface morphology of BaO dispenser cathodes and degrade the electron emission properties. For vacuum cathodes operating at fixed temperature, the emission current drops rapidly when oxygen adsorbs on top of the low work function surface. Previous experiments have shown that plasma cathodes are more resistant to oxygen poisoning and can operate with O{sub 2} partial pressures one to two orders of magnitude higher than vacuum cathodes before the onset of poisoning occurs. Plasma cathodes used for electric thrusters are typically operated with xenon; however, gas phase barium, oxygen, and tungsten species may be found in small concentrations. The densities of these minor species are small compared with the plasma density, and thus, their presence in the discharge does not significantly alter the xenon plasma parameters. It is important, however, to consider the transport of these minor species as they may deposit on the emitter surface and affect the electron emission properties. In this work, we present the results of a material transport model used to predict oxygen fluxes to the cathode surface by solving the species conservation equations in a cathode with a 2.25 mm diameter orifice operated at a discharge current of 15 A, a Xe flow rate of 3.7 sccm, and 100 ppm of O{sub 2}. The dominant ionization process for O{sub 2} is resonant charge exchange with xenon ions. Ba is effectively recycled in the plasma; however, BaO and O{sub 2} are not. The model shows that the oxygen flux to the surface is not diffusion-limited; therefore, the high resistance to oxygen poisoning observed in plasma cathodes likely results from surface processes not considered here.

  5. Oxygen transport in the internal xenon plasma of a dispenser hollow cathode

    NASA Astrophysics Data System (ADS)

    Capece, Angela M.; Polk, James E.; Mikellides, Ioannis G.; Shepherd, Joseph E.

    2014-04-01

    Reactive gases such as oxygen and water vapor modify the surface morphology of BaO dispenser cathodes and degrade the electron emission properties. For vacuum cathodes operating at fixed temperature, the emission current drops rapidly when oxygen adsorbs on top of the low work function surface. Previous experiments have shown that plasma cathodes are more resistant to oxygen poisoning and can operate with O2 partial pressures one to two orders of magnitude higher than vacuum cathodes before the onset of poisoning occurs. Plasma cathodes used for electric thrusters are typically operated with xenon; however, gas phase barium, oxygen, and tungsten species may be found in small concentrations. The densities of these minor species are small compared with the plasma density, and thus, their presence in the discharge does not significantly alter the xenon plasma parameters. It is important, however, to consider the transport of these minor species as they may deposit on the emitter surface and affect the electron emission properties. In this work, we present the results of a material transport model used to predict oxygen fluxes to the cathode surface by solving the species conservation equations in a cathode with a 2.25 mm diameter orifice operated at a discharge current of 15 A, a Xe flow rate of 3.7 sccm, and 100 ppm of O2. The dominant ionization process for O2 is resonant charge exchange with xenon ions. Ba is effectively recycled in the plasma; however, BaO and O2 are not. The model shows that the oxygen flux to the surface is not diffusion-limited; therefore, the high resistance to oxygen poisoning observed in plasma cathodes likely results from surface processes not considered here.

  6. Treatment of enterococcus faecalis bacteria by a helium atmospheric cold plasma brush with oxygen addition

    SciTech Connect

    Chen Wei; Huang Jun; Wang Xingquan; Lv Guohua; Zhang Guoping; Du Ning; Liu Xiaodi; Guo Lihong; Yang Size

    2012-07-01

    An atmospheric cold plasma brush suitable for large area and low-temperature plasma-based sterilization is designed. Results demonstrate that the He/O{sub 2} plasma more effectively kills Enterococcus faecalis than the pure He plasma. In addition, the sterilization efficiency values of the He/O{sub 2} plasma depend on the oxygen fraction in Helium gas. The atmospheric cold plasma brush using a proper ratio of He/O{sub 2} (2.5%) reaches the optimum sterilization efficiency. After plasma treatment, the cell structure and morphology changes can be observed by the scanning electron microscopy. Optical emission measurements indicate that reactive species such as O and OH play a significant role in the sterilization process.

  7. Treatment of enterococcus faecalis bacteria by a helium atmospheric cold plasma brush with oxygen addition

    NASA Astrophysics Data System (ADS)

    Chen, Wei; Huang, Jun; Du, Ning; Liu, Xiao-Di; Wang, Xing-Quan; Lv, Guo-Hua; Zhang, Guo-Ping; Guo, Li-Hong; Yang, Si-Ze

    2012-07-01

    An atmospheric cold plasma brush suitable for large area and low-temperature plasma-based sterilization is designed. Results demonstrate that the He/O2 plasma more effectively kills Enterococcus faecalis than the pure He plasma. In addition, the sterilization efficiency values of the He/O2 plasma depend on the oxygen fraction in Helium gas. The atmospheric cold plasma brush using a proper ratio of He/O2 (2.5%) reaches the optimum sterilization efficiency. After plasma treatment, the cell structure and morphology changes can be observed by the scanning electron microscopy. Optical emission measurements indicate that reactive species such as O and OH play a significant role in the sterilization process.

  8. Optical Properties of Oxygen Plasma-Treated Carbon Nanowalls Grown on Glass Substrates.

    PubMed

    Jung, Yong Ho; Choi, Won Seok

    2016-05-01

    In this paper, we investigated the effect of oxygen (02) plasma treatment on a synthesized carbon nanowall (CNW). A microwave plasma-enhanced chemical vapor deposition (PECVD) system was facilitated to grow CNWs on a glass, using a mixture of CH4 and H2 gases. First, the CNWs were post-plasma-treated for different treatment durations, and then their optical properties were analyzed. In addition, the cross-sectional and planar images of the CNWs were examined via field-emission scanning electron microscopy (FE-SEM) depending on the different post-plasma-treatment durations. Then the structural characteristics were analyzed via Raman spectroscopy, and the changes in the light transmittance depending on the O2 plasma treatment durations were analyzed using UV-Vis spectroscopy. The effects of the post-plasma treatments on the synthesized CNWs were evaluated. The results confirmed that O2 gas is effective for plasma etching of CNWs. PMID:27483919

  9. Synergistic effect of EUV from the laser-sustained detonation plasma in a ground-based atomic oxygen simulation on fluorinated polymers

    SciTech Connect

    Tagawa, Masahito; Abe, Shingo; Kishida, Kazuhiro; Yokota, Kumiko; Okamoto, Akio

    2009-01-05

    The contribution of extreme ultraviolet (EUV) from a laser-sustained plasma on the mass loss phenomenon of fluorinated polymer in a ground-based laser-detonation atomic oxygen beam source was evaluated. The atomic oxygen beam and EUV from the oxygen plasma were separated by the high-speed chopper wheel installed in the beam source. The mass changes of the fluorinated polymer and polyimide were measured from the frequency shift of the quartz crystal microbalance during the beam exposures. It has been made clear that the fluorinated polymer erodes by EUV exposure alone. In contrast, no erosion was detected for polyimide by EUV alone. The atomic oxygen-induced erosion was measured for both materials even without EUV exposure. However, no strong synergistic effect was observed for a fluorinated polymer even under the simultaneous exposure condition of atomic oxygen and EUV. Similar results were observed even in simultaneous exposure of atomic oxygen (without EUV) and 172 nm vacuum ultraviolet (VUV) from an excimer lamp. These experiments suggest that the primary origin of the accelerated erosion of fluorinated polymer observed in a laser detonation atomic oxygen source is not the EUV from the laser-sustained plasma.

  10. Estimation of Electron Temperature and Frequency Components in a Dual Frequency Capacitively-Coupled Plasma Processing Reactor

    NASA Astrophysics Data System (ADS)

    Ito, Toru; Mo, Yun; Masahiro, Horigome

    2008-10-01

    The measurement of electron temperature in RF plasma sources with Langmuir probes is difficult because of the influence of rf noise. We attempted to estimate the electron temperature in a capacitively-coupled plasma processing reactor with a Surface Wave Probe [1] which employs microwaves. We also estimated the frequency spectrum with the sensitive PAP [1, 2]. We measured the harmonics which appeared in the bulk plasma for various experimental conditions in the dual-frequency [60 MHz and 2MHz] capacitively-coupled plasma processing reactor. We estimated RF power spectra for several experimental conditions like RF power [500-2000W], gas pressure [3-20Pa], and gas species [Ar, CF4]. The measurement results suggest the existence of energy transport among several frequency spectrum. [1ex] [1] K. Nakamura, M. Ohata, and H. Sugai: J. Vac. Sci. Technol. A 21, 325 (2003). [0pt] [2] T. Shirakawa and H. Sugai : Jpn. J. Appl. Phys. 32, 5129 (1993).

  11. Cold atmospheric pressure plasma jets: Interaction with plasmid DNA and tailored electron heating using dual-frequency excitation

    NASA Astrophysics Data System (ADS)

    Niemi, K.; O'Neill, C.; Cox, L. J.; Waskoenig, J.; Hyland, W. B.; McMahon, S. J.; Reuter, S.; Currell, F. J.; Graham, W. G.; O'Connell, D.; Gans, T.

    2012-05-01

    Recent progress in plasma science and technology has enabled the development of a new generation of stable cold non-equilibrium plasmas operating at ambient atmospheric pressure. This opens horizons for new plasma technologies, in particular in the emerging field of plasma medicine. These non-equilibrium plasmas are very efficient sources for energy transport through reactive neutral particles (radicals and metastables), charged particles (ions and electrons), UV radiation, and electro-magnetic fields. The effect of a cold radio frequency-driven atmospheric pressure plasma jet on plasmid DNA has been investigated. The formation of double strand breaks correlates well with the atomic oxygen density. Taken with other measurements, this indicates that neutral components in the jet are effective in inducing double strand breaks. Plasma manipulation techniques for controlled energy delivery are highly desirable. Numerical simulations are employed for detailed investigations of the electron dynamics, which determines the generation of reactive species. New concepts based on nonlinear power dissipation promise superior strategies to control energy transport for tailored technological exploitations.

  12. Cold atmospheric pressure plasma jets: Interaction with plasmid DNA and tailored electron heating using dual-frequency excitation

    SciTech Connect

    Niemi, K.; O'Neill, C.; Cox, L. J.; Waskoenig, J.; Hyland, W. B.; McMahon, S. J.; Reuter, S.; Currell, F. J.; Graham, W. G.; O'Connell, D.; Gans, T.

    2012-05-25

    Recent progress in plasma science and technology has enabled the development of a new generation of stable cold non-equilibrium plasmas operating at ambient atmospheric pressure. This opens horizons for new plasma technologies, in particular in the emerging field of plasma medicine. These non-equilibrium plasmas are very efficient sources for energy transport through reactive neutral particles (radicals and metastables), charged particles (ions and electrons), UV radiation, and electro-magnetic fields. The effect of a cold radio frequency-driven atmospheric pressure plasma jet on plasmid DNA has been investigated. The formation of double strand breaks correlates well with the atomic oxygen density. Taken with other measurements, this indicates that neutral components in the jet are effective in inducing double strand breaks. Plasma manipulation techniques for controlled energy delivery are highly desirable. Numerical simulations are employed for detailed investigations of the electron dynamics, which determines the generation of reactive species. New concepts based on nonlinear power dissipation promise superior strategies to control energy transport for tailored technological exploitations.

  13. Method and apparatus for upshifting light frequency by rapid plasma creation

    DOEpatents

    Dawson, John M.; Wilks, Scott C.; Mori, Warren B.; Joshi, Chandrasekhar J.; Sessler, Andrew M.

    1990-01-01

    Photons of an electromagnetic source wave are frequency-upshifted as a plasma is rapidly created around the path of this propagating source wave. The final frequency can be controlled by adjusting the gas density. A controlled time-varying frequency (chirped) pulse can be produced by using a controlled spatially varying gas density. The plasma must be created in a time which is short compared to the transit time of the light through the plasmas region. For very fast creation over one to at most a few light periods of an overdense plasma, static magnetic fields with short wavelengths are created.

  14. Induced hydrophobic recovery of oxygen plasma-treated surfaces

    PubMed Central

    Guckenberger, David J.; Berthier, Erwin; Young, Edmond W. K.; Beebe, David J.

    2014-01-01

    Plasma treatment is a widely used method in microfabrication laboratories and the plasticware industry to functionalize surfaces for device bonding and preparation for mammalian cell culture. However, spatial control of plasma treatment is challenging because it typically requires a tedious masking step that is prone to alignment errors. Currently, there are no available methods to actively revert a surface from a treated hydrophilic state to its original hydrophobic state. Here, we describe a method that relies on physical contact treatment (PCT) to actively induce hydrophobic recovery of plasma-treated surfaces. PCT involves applying brushing and peeling processes with common wipers and tapes to reverse the wettability of hydrophilized surfaces while simultaneously preserving hydrophilicity of non-contacted surfaces. We demonstrate that PCT is a user-friendly method that allows 2D and 3D surface patterning of hydrophobic regions, and the protection of hydrophilic surfaces from unwanted PCT-induced recovery. This method will be useful in academic and industrial settings where plasma treatment is frequently used. PMID:22592853

  15. A theoretical study of hot plasma spheroids in the presence of low-frequency electromagnetic waves

    NASA Astrophysics Data System (ADS)

    Ahmadizadeh, Y.; Jazi, B.; Barjesteh, S.

    2016-07-01

    While taking into account thermal motion of electrons, scattering of electromagnetic waves with low frequency from hot plasma spheroids is investigated. In this theoretical research, ions are heavy to respond to electromagnetic fluctuations. The solution of scalar wave equation in spheroidal coordinates for electric potential inside the plasma spheroids are obtained. The variations of resonance frequencies vs. Debye length are studied and consistency between the obtained results in this paper and the results for the well-known plasma objects such as plasma column and spherical plasma have been proved.

  16. Optimizing the synthesis of vanadium-oxygen nanostructures by plasma plume dynamics using optical imaging

    NASA Astrophysics Data System (ADS)

    Masina, Bathusile N.; Lafane, Slimane; Wu, Lorinda; Abdelli-Messaci, Samira; Kerdja, Tahar; Forbes, Andrew

    2015-03-01

    The effect of an oxygen atmosphere on the expansion dynamics of a laser-produced vanadium-oxygen plasma has been investigated using a fast intensified charged-coupled device camera. We find regimes of the plasma plume expansion ranging from a free plume at vacuum and low oxygen pressures, through collisional and shock-wave-like hydrodynamic regimes at intermediate oxygen pressure, finally reaching a confined plume with subsequent thermalization of the plume particles at the highest pressure of the oxygen gas. Vanadium oxide nanostructures thin films were synthesized from this plasma and the resulting vanadium oxide phases studied as a function of the plume dynamics. We found monoclinic vanadium dioxide (VO2) (M1) and VO2 (B) nanoparticles in thin films deposited at 0.05 mbar. Pure phases of vanadium trioxide (V2O3) smooth and pentoxide (V2O5) nanorods thin films were detected at 0.01 and 0.1 to 0.2 mbar, respectively. Thin films containing VO2 (M1) were found to have a reversible metal-to-insulator transition at 61°C. This work paves the way to VO phase control by judicious choice of laser and plasma conditions.

  17. Deposition of Lanthanum Strontium Cobalt Ferrite (LSCF) Using Suspension Plasma Spraying for Oxygen Transport Membrane Applications

    NASA Astrophysics Data System (ADS)

    Fan, E. S. C.; Kesler, O.

    2015-08-01

    Suspension plasma spray deposition was utilized to fabricate dense lanthanum strontium cobalt ferrite oxygen separation membranes (OSMs) on porous metal substrates for mechanical support. The as-sprayed membranes had negligible and/or reversible material decomposition. At the longer stand-off distance (80 mm), smooth and dense membranes could be manufactured using a plasma with power below approximately 81 kW. Moreover, a membrane of 55 μm was observed to have very low gas leakage rates desirable for OSM applications. This thickness could potentially be decreased further to improve oxygen diffusion by using metal substrates with finer surface pores.

  18. Surface characterization and adhesion of oxygen plasma-modified LARC-TPI

    NASA Technical Reports Server (NTRS)

    Chin, J. W.; Wightman, J. P.

    1992-01-01

    LARC-TPI, an aromatic thermoplastic polyimide, was exposed to an oxygen plasma as a surface pretreatment for adhesive bonding. Chemical and physical changes which occurred in the polyimide surface as a result of the plasma treatment were investigated using X-ray photoelectron spectroscopy (XPS), infrared reflection-absorption spectroscopy (IR-RAS), contact-angle analysis, ellipsometry, and high resolution SEM. A 180-deg peel test with an acrylate-based pressure sensitive adhesive as a flexible adherent was utilized to study the interactions of the plasma-treated polyimide surface with other polymeric materials. The surface characterization and adhesion testing results showed that the oxygen plasma treatment, while creating a more hydrophilic, polar surface, also caused chain scission, resulting in the formation of a weak boundary layer which inhibited adhesion.

  19. Cold plasma processing of local planetary ores for oxygen and metallurgically important metals

    NASA Technical Reports Server (NTRS)

    Lynch, D. C.; Bullard, D.; Ortega, R.

    1990-01-01

    The utilization of a cold plasma in chlorination processing is described. Essential equipment and instruments were received, the experimental apparatus assembled and tested, and preliminary experiments conducted. The results of the latter lend support to the original hypothesis: a cold plasma can both significantly enhance and bias chemical reactions. In two separate experiments, a cold plasma was used to reduce TiCl4 vapor and chlorinate ilmenite. The latter, reacted in an argon-chlorine plasma, yielded oxygen. The former experiment reveals that chlorine can be recovered as HCl vapor from metal chlorides in a hydrogen plasma. Furthermore, the success of the hydrogen experiments has lead to an analysis of the feasibility of direct hydrogen reduction of metal oxides in a cold plasma. That process would produce water vapor and numerous metal by-products.

  20. Magnetic-field-dependent plasma composition of a pulsed aluminum arc in an oxygen ambient

    NASA Astrophysics Data System (ADS)

    Schneider, Jochen M.; Anders, André; Yushkov, George Yu.

    2001-01-01

    A variety of plasma-based deposition techniques utilize magnetic fields to affect the degree of ionization as well as for focusing and guiding of plasma beams. Here we use time-of-flight charge-to-mass spectrometry to describe the effect of a magnetic field on the plasma composition of a pulsed Al plasma stream in an ambient containing intentionally introduced oxygen as well as for high vacuum conditions typical residual gas. The plasma composition evolution was found to be strongly dependent on the magnetic field strength and can be understood by invoking two electron impact ionization routes: ionization of the intentionally introduced gas as well as ionization of the residual gas. These results are characteristic of plasma-based techniques where magnetic fields are employed in a high-vacuum ambient. In effect, the impurity incorporation during reactive thin-film growth pertains to the present findings.

  1. Restructured graphene sheets embedded carbon film by oxygen plasma etching and its tribological properties

    NASA Astrophysics Data System (ADS)

    Guo, Meiling; Diao, Dongfeng; Yang, Lei; Fan, Xue

    2015-12-01

    An oxygen plasma etching technique was introduced for improving the tribological properties of the graphene sheets embedded carbon (GSEC) film in electron cyclotron resonance plasma processing system. The nanostructural changing in the film caused by oxygen plasma etching was examined by transmission electron microscope, Raman spectroscopy and X-ray photoelectron spectroscopy, showing that the 3 nm thick top surface layer was restructured with smaller graphene nanocrystallite size as well as higher sp3 bond fraction. The surface roughness, mechanical behavior and tribological properties of the original GSEC and oxygen plasma treated GSEC films were compared. The results indicated that after the oxygen plasma treatment, the average roughness decreased from 20.8 ± 1.1 nm to 1.9 ± 0.1 nm, the hardness increased from 2.3 ± 0.1 GPa to 2.9 ± 0.1 GPa, the nanoscratch depth decreased from 64.5 ± 5.4 nm to 9.9 ± 0.9 nm, and the wear life increased from 930 ± 390 cycles to more than 15,000 frictional cycles. The origin of the improved tribological behavior was ascribed to the 3 nm thick graphene nanocrystallite film. This finding can be expected for wide applications in nanoscale surface engineering.

  2. Plasma acceleration using a radio frequency self-bias effect

    NASA Astrophysics Data System (ADS)

    Rafalskyi, D.; Aanesland, A.

    2015-06-01

    In this work plasma acceleration using a RF self-bias effect is experimentally studied. The experiments are conducted using a novel plasma accelerator system, called Neptune, consisting of an inductively coupled plasma source and a RF-biased set of grids. The plasma accelerator can operate in a steady state mode, producing a plasma flow with separately controlled plasma flux and velocity without any magnetic configuration. The operating pressure at the source output is as low as 0.2 mTorr and can further be decreased. The ion and electron flows are investigated by measuring the ion and electron energy distribution functions both space resolved and with different orientations with respect to the flow direction. It is found that the flow of electrons from the source is highly anisotropic and directed along the ion flow and this global flow of accelerated plasma is well localized in the plasma transport chamber. The maximum flux is about 7.5.1015 ions s-1 m-2 (at standard conditions) on the axis and decreasing to almost zero at a radial distances of more than 15 cm from the flow axis. Varying the RF acceleration voltage in the range 20-350 V, the plasma flow velocity can be changed between 10 and 35 km/s. The system is prospective for different technology such as space propulsion and surface modification and also interesting for fundamental studies for space-related plasma simulations and investigation of the dynamo effect using accelerated rotating plasmas.

  3. Measurements of time average series resonance effect in capacitively coupled radio frequency discharge plasma

    SciTech Connect

    Bora, B.; Bhuyan, H.; Favre, M.; Wyndham, E.; Chuaqui, H.; Kakati, M.

    2011-10-15

    Self-excited plasma series resonance is observed in low pressure capacitvely coupled radio frequency discharges as high-frequency oscillations superimposed on the normal radio frequency current. This high-frequency contribution to the radio frequency current is generated by a series resonance between the capacitive sheath and the inductive and resistive bulk plasma. In this report, we present an experimental method to measure the plasma series resonance in a capacitively coupled radio frequency argon plasma by modifying the homogeneous discharge model. The homogeneous discharge model is modified by introducing a correction factor to the plasma resistance. Plasma parameters are also calculated by considering the plasma series resonances effect. Experimental measurements show that the self-excitation of the plasma series resonance, which arises in capacitive discharge due to the nonlinear interaction of plasma bulk and sheath, significantly enhances both the Ohmic and stochastic heating. The experimentally measured total dissipation, which is the sum of the Ohmic and stochastic heating, is found to increase significantly with decreasing pressure.

  4. Method for minimizing decarburization and other high temperature oxygen reactions in a plasma sprayed material

    DOEpatents

    Lenling, William J.; Henfling, Joseph A.; Smith, Mark F.

    1993-06-08

    A method is disclosed for spray coating material which employs a plasma gun that has a cathode, an anode, an arc gas inlet, a first powder injection port, and a second powder injection port. A suitable arc gas is introduced through the arc gas inlet, and ionization of the arc gas between the cathode and the anode forms a plasma. The plasma is directed to emenate from an open-ended chamber defined by the boundary of the anode. A coating is deposited upon a base metal part by suspending a binder powder within a carrier gas that is fed into the plasma through the first powder injection port; a material subject to degradation by high temperature oxygen reactions is suspended within a carrier gas that is fed into the plasma through the second injection port. The material fed through the second injection port experiences a cooler portion of the plasma and has a shorter dwell time within the plasma to minimize high temperature oxygen reactions. The material of the first port and the material of the second port intermingle within the plasma to form a uniform coating having constituent percentages related to the powder-feed rates of the materials through the respective ports.

  5. High-frequency electrostatic modes in non-neutral plasmas

    SciTech Connect

    Book, D.L.

    1995-05-01

    A fluid description is employed to derive the dispersion relation for cyclotron modes in a cylindrical non-neutral plasma of radius {ital R} confined by a uniform magnetic field {bold B}={ital B}{sub 0}{bold e}{sub {ital z}} inside a chamber with conducting walls of radius {ital R}{sub 0}. In contrast to the theory of Gould and LaPointe [Phys. Rev. Lett. {bold 67}, 3685 (1991); Phys. Fluids B {bold 4}, 2038 (1992)] the model includes the diamagnetic drift but omits finite Larmor radius effects. The density and the temperature of the unperturbed state are taken to be {ital n}({ital r})={ital n}{sub 0}(1{minus}{ital r}{sup 2}/{ital R}{sup 2}) and {ital T}({ital r})={ital T}{sub 0}(1{minus}{ital r}{sup 2}/{ital R}{sup 2}){sup {gamma}{minus}1}, where {gamma} is the adiabatic index, so that the {ital r}-dependent slow rotation frequency is {omega}{sub {ital r}}{approx}{minus}[{delta}(1{minus}{ital r}{sup 2}/2{ital R}{sup 2})+{epsilon}(1{minus}{ital r}{sup 2}/{ital R}{sup 2}){sup {gamma}{minus}2}]{Omega}/2, where {Omega}={ital qB}{sub 0}/{ital Mc} is the ion gyrofrequency, {delta}=4{pi}{ital n}{sub 0}{ital q}{sup 2}/{ital M}{Omega}{sup 2}, and {epsilon}=4{gamma}{ital T}{sub 0}/{ital M}{Omega}{sup 2}{ital R}{sup 2}. For the linearized fluid equations together with the Poisson equation the eigenvalue problem is solved in the limit {delta}{much_lt}1, {epsilon}{much_lt}1. The eigenfrequencies for high-frequency electrostatic modes with wave vectors satisfying {bold k}{center_dot}{bold B}=0 (Bernstein modes) are found in the form {omega}={minus}{Omega}+{Delta}{omega}, where {Delta}{omega}/{Omega} contains terms proportional to {delta} and {epsilon}. Solutions are obtained and compared with experiment and the theory of Gould and LaPointe. (Abstract Truncated)

  6. Control of plasma properties in capacitively coupled oxygen discharges via the electrical asymmetry effect

    NASA Astrophysics Data System (ADS)

    Schüngel, E.; Zhang, Q.-Z.; Iwashita, S.; Schulze, J.; Hou, L.-J.; Wang, Y.-N.; Czarnetzki, U.

    2011-07-01

    Using a combined experimental, numerical and analytical approach, we investigate the control of plasma properties via the electrical asymmetry effect (EAE) in a capacitively coupled oxygen discharge. In particular, we present the first experimental investigation of the EAE in electronegative discharges. A dual-frequency voltage source of 13.56 MHz and 27.12 MHz is applied to the powered electrode and the discharge symmetry is controlled by adjusting the phase angle θ between the two harmonics. It is found that the bulk position and density profiles of positive ions, negative ions, and electrons have a clear dependence on θ, while the peak densities and the electronegativity stay rather constant, largely due to the fact that the time-averaged power absorption by electrons is almost independent of θ. This indicates that the ion flux towards the powered electrode remains almost constant. Meanwhile, the dc self-bias and, consequently, the sheath widths and potential profile can be effectively tuned by varying θ. This enables a flexible control of the ion bombarding energy at the electrode. Therefore, our work proves the effectiveness of the EAE to realize separate control of ion flux and ion energy in electronegative discharges. At low pressure, the strength of resonance oscillations, which are found in the current of asymmetric discharges, can be controlled with θ.

  7. Endotoxin removal by radio frequency gas plasma (glow discharge)

    NASA Astrophysics Data System (ADS)

    Poon, Angela

    2011-12-01

    Contaminants remaining on implantable medical devices, even following sterilization, include dangerous fever-causing residues of the outer lipopolysaccharide-rich membranes of Gram-negative bacteria such as the common gut microorganism E. coli. The conventional method for endotoxin removal is by Food & Drug Administration (FDA)-recommended dry-heat depyrogenation at 250°C for at least 45 minutes, an excessively time-consuming high-temperature technique not suitable for low-melting or heat-distortable biomaterials. This investigation evaluated the mechanism by which E. coli endotoxin contamination can be eliminated from surfaces during ambient temperature single 3-minute to cumulative 15-minute exposures to radio-frequency glow discharge (RFGD)-generated residual room air plasmas activated at 0.1-0.2 torr in a 35MHz electrodeless chamber. The main analytical technique for retained pyrogenic bio-activity was the Kinetic Chromogenic Limulus Amebocyte Lysate (LAL) Assay, sufficiently sensitive to document compliance with FDA-required Endotoxin Unit (EU) titers less than 20 EU per medical device by optical detection of enzymatic color development corresponding to < 0.5 EU/ml in sterile water extracts of each device. The main analytical technique for identification of chemical compositions, amounts, and changes during sequential reference Endotoxin additions and subsequent RFGD-treatment removals from infrared (IR)-transparent germanium (Ge) prisms was Multiple Attenuated Internal Reflection (MAIR) infrared spectroscopy sensitive to even monolayer amounts of retained bio-contaminant. KimaxRTM 60 mm x 15 mm and 50mm x 15mm laboratory glass dishes and germanium internal reflection prisms were inoculated with E. coli bacterial endotoxin water suspensions at increments of 0.005, 0.05, 0.5, and 5 EU, and characterized by MAIR-IR spectroscopy of the dried residues on the Ge prisms and LAL Assay of sterile water extracts from both glass and Ge specimens. The Ge prism MAIR

  8. Two-dimensional lateral heterojunction through bandgap engineering of MoS2 via oxygen plasma.

    PubMed

    Choudhary, Nitin; Islam, Muhammad R; Kang, Narae; Tetard, Laurene; Jung, Yeonwoong; Khondaker, Saiful I

    2016-09-14

    The present study explores the structural, optical (photoluminescence (PL)), and electrical properties of lateral heterojunctions fabricated by selective exposure of mechanically exfoliated few layer two-dimensional (2D) molybdenum disulfide (MoS2) flakes under oxygen (O2)-plasma. Raman spectra of the plasma exposed MoS2 flakes show a significant loss in the structural quality due to lattice distortion and creation of oxygen-containing domains in comparison to the pristine part of the same flake. The PL mapping evidences the complete quenching of peak A and B consistent with a change in the exciton states of MoS2 after the plasma treatment, indicating a significant change in its band gap properties. The electrical transport measurements performed across the pristine and the plasma-exposed MoS2 flake exhibit a gate tunable current rectification behavior with a rectification ratio up to 1.3  ×  10(3) due to the band-offset at the pristine and plasma-exposed MoS2 interface. Our Raman, PL, and electrical transport data confirm the formation of an excellent lateral heterojunction in 2D MoS2 through its bandgap modulation via oxygen plasma. PMID:27392099

  9. Two-dimensional lateral heterojunction through bandgap engineering of MoS2 via oxygen plasma

    NASA Astrophysics Data System (ADS)

    Choudhary, Nitin; Islam, Muhammad R.; Kang, Narae; Tetard, Laurene; Jung, Yeonwoong; Khondaker, Saiful I.

    2016-09-01

    The present study explores the structural, optical (photoluminescence (PL)), and electrical properties of lateral heterojunctions fabricated by selective exposure of mechanically exfoliated few layer two-dimensional (2D) molybdenum disulfide (MoS2) flakes under oxygen (O2)-plasma. Raman spectra of the plasma exposed MoS2 flakes show a significant loss in the structural quality due to lattice distortion and creation of oxygen-containing domains in comparison to the pristine part of the same flake. The PL mapping evidences the complete quenching of peak A and B consistent with a change in the exciton states of MoS2 after the plasma treatment, indicating a significant change in its band gap properties. The electrical transport measurements performed across the pristine and the plasma-exposed MoS2 flake exhibit a gate tunable current rectification behavior with a rectification ratio up to 1.3  ×  103 due to the band-offset at the pristine and plasma-exposed MoS2 interface. Our Raman, PL, and electrical transport data confirm the formation of an excellent lateral heterojunction in 2D MoS2 through its bandgap modulation via oxygen plasma.

  10. Influence of the oxygen plasma parameters on the atomic layer deposition of titanium dioxide.

    PubMed

    Ratzsch, Stephan; Kley, Ernst-Bernhard; Tünnermann, Andreas; Szeghalmi, Adriana

    2015-01-16

    The influence of the oxygen plasma parameters on the morphology and optical properties of TiO2 thin films has been extensively analyzed in plasma enhanced atomic layer deposition (PEALD) processes. Crystalline aggregates with the anatase phase have been identified on the film surface at a low deposition temperature (down to 70 °C) under specific plasma conditions. Up to 70% surface coverage by anatase crystallites is obtained at low oxygen gas flow rates and high plasma power. The hillocks abundance is correlated with high ion flux and electron density and with the resulting enhanced ion bombardment of the surface. Altering the plasma conditions is an important parameter besides temperature to control the morphology of the titania film for specific applications such as photocatalysis or functional optical coatings. Specifically, photocatalytic titania coatings on polymer substrates could benefit of such low temperature PEALD processes with abundant anatase crystallites; whereas optical coatings require smooth, high refractive index titania as obtained with low plasma power and high oxygen flow rate. PMID:25525676

  11. Characterization of an oxygen plasma process for cleaning packaged semiconductor devices. Final report

    SciTech Connect

    Adams, B.E.

    1996-11-01

    The purpose of this research was to experimentally determine the operating {open_quotes}window{close_quotes} for an oxygen plasma cleaning process to be used on microelectronics components just prior to wire bonding. The process was being developed to replace one that used vapor degreasing with trichlorotrifluoroethane, an ozone-depleting substance. A Box-Behnken experimental design was used to generate data from which the oxygen plasma cleaning process could be characterized. Auger electron spectrophotometry was used to measure the contamination thickness on the dice after cleaning. An empirical equation correlating the contamination thickness on the die surface with the operating parameters of the plasma system was developed from the collected Auger data, and optimum settings for cleaning semiconductor devices were determined. Devices were also tested for undesirable changes in electrical parameters resulting from cleaning in the plasma system. An increase in leakage current occurred for bipolar transistors and diodes after exposure to the oxygen plasma. Although an increase in leakage current occurred, each device`s parameter remained well below the acceptable specification limit. Based upon the experimental results, the optimum settings for the plasma cleaning process were determined to be 200 watts of power applied for five minutes in an enclosure maintained at 0.7 torr. At these settings, all measurable contamination was removed without compromising the reliability of the devices.

  12. Reaction mechanisms of oxygen plasma interaction with organosilicate low-k materials containing organic crosslinking groups

    SciTech Connect

    Chaudhari, Mrunalkumar; Du Jincheng

    2012-11-15

    Integration of low dielectric constant (k) materials such as organosilicate glasses (OSG) into microelectronic processing demands a better of understanding the plasma/OSG interactions during plasma etching and ashing of these materials, based on which low-k materials with higher radiation resistance and better mechanical behaviors can be developed and optimized plasma processing conditions can be introduced to ensure continued miniaturization of semiconductor devices. Introducing organic crosslinking (e.g., -CH{sub 2}-) in OSG has been shown to be an effective measure to improve the mechanical properties but their effect on plasma interaction is still not fully understood. In this paper, ab initio based molecular dynamics simulations have been employed to investigate the effect of the oxygen plasma on the carbon-bridged silicate networks in the OSG material. The results show that organic crosslinking in the Si-O-Si network leads to lower energy reaction pathways with atomic oxygen radicals that result in breakage of Si-CH{sub 2}-Si linkages instead of Si-CH{sub 3} bonds and, consequently, a decrease in carbon removal. The incorporation of organic crosslinking groups can thus improve the resistance to oxygen plasma damage of OSG and, together with better mechanical properties, can lead to the design of stronger low-k dielectric films.

  13. Collisionless expansion of pulsed radio frequency plasmas. II. Parameter study

    NASA Astrophysics Data System (ADS)

    Schröder, T.; Grulke, O.; Klinger, T.; Boswell, R. W.; Charles, C.

    2016-01-01

    The plasma parameter dependencies of the dynamics during the expansion of plasma are studied with the use of a versatile particle-in-cell simulation tailored to a plasma expansion experiment [Schröder et al., J. Phys. D: Appl. Phys. 47, 055207 (2014); Schröder et al., Phys. Plasmas 23, 013511 (2016)]. The plasma expansion into a low-density ambient plasma features a propagating ion front that is preceding a density plateau. It has been shown that the front formation is entangled with a wave-breaking mechanism, i.e., an ion collapse [Sack and Schamel, Plasma Phys. Controlled Fusion 27, 717 (1985); Sack and Schamel, Phys. Lett. A 110, 206 (1985)], and the launch of an ion burst [Schröder et al., Phys. Plasmas 23, 013511 (2016)]. The systematic parameter study presented in this paper focuses on the influence on this mechanism its effect on the maximum velocity of the ion front and burst. It is shown that, apart from the well known dependency of the front propagation on the ion sound velocity, it also depends sensitively on the density ratio between main and ambient plasma density. The maximum ion velocity depends further on the initial potential gradient, being mostly influenced by the plasma density ratio in the source and expansion regions. The results of the study are compared with independent numerical studies.

  14. Development, diagnostic and applications of radio-frequency plasma reactor

    NASA Astrophysics Data System (ADS)

    Puac, N.

    2008-07-01

    In many areas of the industry, plasma processing of materials is a vital technology. Nonequilibrium plasmas proved to be able to produce chemically reactive species at a low gas temperature while maintaining highly uniform reaction rates over relatively large areas (Makabe and Petrovic 2006). At the same time nonequilibrium plasmas provide means for good and precise control of the properties of active particles that determine the surface modification. Plasma needle is one of the atmospheric pressure sources that can be used for treatment of the living matter which is highly sensitive when it comes to low pressure or high temperatures (above 40 C). Dependent on plasma conditions, several refined cell responses are induced in mammalian cells (Sladek et al. 2005). It appears that plasma treatment may find many biomedical applications. However, there are few data in the literature about plasma effects on plant cells and tissues. So far, only the effect of low pressure plasmas on seeds was investigated. It was shown that short duration pretreatments by non equilibrium low temperature air plasma were stimulative in light induced germination of Paulownia tomentosa seeds (Puac et al. 2005). As membranes of plants have different properties to those of animals and as they show a wide range of properties we have tried to survey some of the effects of typical plasma which is envisaged to be used in biotechnological applications on plant cells. In this paper we will make a comparison between two configurations of plasma needle that we have used in treatment of biological samples (Puac et al. 2006). Difference between these two configurations is in the additional copper ring that we have placed around glass tube at the tip of the needle. We will show some of the electrical characteristics of the plasma needle (with and without additional copper ring) and, also, plasma emission intensity obtained by using fast ICCD camera.

  15. Inactivation of Pathogenic Bacteria on Seeds by Active Oxygen Species Generated in Low-Pressure Plasma

    NASA Astrophysics Data System (ADS)

    Ono, Reoto; Uchida, Shohei; Hayashi, Nobuya; Kosaka, Rina; Soeda, Yasutaka

    2015-09-01

    The inactivation of bacteria on seeds by active oxygen species generated by a low-pressure oxygen plasma is investigated. Species of active oxygen contributing to the inactivation of bacteria are attempted to be identified. Cylindrical stainless chamber with the internal volume of 17 L is used and RF antenna is set inside the chamber. The oxygen gas pressure is 20-100 Pa. RF power of 13.56 MHz is supplied to RF antenna and CCP is generated. After irradiation, bacteria are extracted from seeds and cultivated on nutrient agars. The number of colonies on these agars is counted after 48 h incubation. The number of bacteria on seeds decreases to less than 10-3 after plasma irradiation for 45 min comparing with that of control. The tendency of the reduction rate of bacteria on seeds has positive correlation with that of the light emission intensity of the singlet excited oxygen molecule as the oxygen gas pressure is varied. It is supposed that the singlet excited oxygen molecule would be one of the major factors for the inactivation of bacteria on seeds.

  16. Numerical analysis of radio-frequency sheath-plasma interactions in the ion cyclotron range of frequencies

    SciTech Connect

    Kohno, H.; Myra, J. R.; D'Ippolito, D. A.

    2012-01-15

    A new finite element numerical scheme for analyzing self-consistent radio-frequency (RF) sheath-plasma interaction problems in the ion cyclotron range of frequencies is applied to various problems represented by simplified models for the tokamak scrape-off layer. The present code incorporates a modified boundary condition, which is called a sheath boundary condition, that couples the radio-frequency waves and sheaths at the material boundaries by treating the sheath as a thin vacuum layer. A series of numerical analyses in one- and two-dimensional domains show several important physical properties, such as the existence of multiple roots, hysteresis effects, presence and characteristics of the sheath-plasma waves, and the phase shift of a reflected slow wave, some of which are newly identified by introducing a spatially varying plasma density and background magnetic field.

  17. Spectral line shapes and frequencies of the molecular oxygen B-band R-branch transitions

    NASA Astrophysics Data System (ADS)

    Domysławska, Jolanta; Wójtewicz, Szymon; Masłowski, Piotr; Cygan, Agata; Bielska, Katarzyna; Trawiński, Ryszard S.; Ciuryło, Roman; Lisak, Daniel

    2015-04-01

    We present the line-shape parameters for the first 11 lines of the oxygen B-band R-branch self-broadened transitions measured at low pressures by the Pound-Drever-Hall-locked frequency-stabilized cavity ring-down spectrometer (PDH-locked FS-CRDS) linked to the optical frequency comb. The collisional self-broadening, shifting and narrowing parameters were determined together with the quadratic speed-dependence as well as phase- and velocity-changing correlations parameters. The absolute frequencies of the transitions with combined standard uncertainties below 150 kHz are reported. Dependence of line parameters on choice of the line-shape model is discussed.

  18. Hierarchical regrowth of flowerlike nanographene sheets on oxygen-plasma-treated carbon nanowalls

    NASA Astrophysics Data System (ADS)

    Shimoeda, Hironao; Kondo, Hiroki; Ishikawa, Kenji; Hiramatsu, Mineo; Sekine, Makoto; Hori, Masaru

    2014-04-01

    Cauliflorous nanographene sheets were hierarchically regrown on the spearlike structures of carbon nanowalls (CNWs) produced by O2-plasma etching. The spears on the CNWs acted as a stem for the growth of flowerlike flaky nanographene sheets, where the root of the nanoflower was located at a defect or disordered site. The defects on the graphitic structures were induced by irradiation with oxygen-related radicals and ions in the O2-based plasmas and acted as sites for the nucleation of flowerlike nanographene. The porous carbon nanostructures regrown after O2-plasma treatment have a relatively higher surface area and are thus promising materials for electrochemical applications.

  19. Comparative study on the performance of pyrolyzed and plasma-treated iron(II) phthalocyanine-based catalysts for oxygen reduction in pH neutral electrolyte solutions

    NASA Astrophysics Data System (ADS)

    Harnisch, Falk; Savastenko, Natalie A.; Zhao, Feng; Steffen, Hartmut; Brüser, Volker; Schröder, Uwe

    The performance of pyrolyzed and plasma-treated non-precious catalysts for the oxygen reduction is discussed in the light of their application in microbial fuel cells. An Ar-radio frequency (RF) plasma treatment is applied to enhance the electrochemical activity of iron(II) phthalocyanine (FePc)-based catalysts. The electrochemical properties of the catalysts are analyzed by galvanodynamic linear sweep voltammetry and chronoamperometric experiments. Surface elemental analysis of the catalysts is examined by means of X-ray photoelectron spectroscopy (XPS). The influence of plasma power and treatment time on the elemental surface concentration and performance of the catalysts is investigated. The electrochemical activity, expressed in terms of the current density at 0 V vs. Ag/AgCl, is up to 40% higher for the plasma-treated samples than for pyrolyzed ones. It is found that optimal treatment time was 30 min and optimal plasma power was 150 W for the best electroactivity of FePc-based catalysts. From the results of XPS data, it is revealed that Ar-plasma treatment of the catalysts leads to an increase in the oxygen and nitrogen concentration on the catalysts surface. A correlation is found between the activity and surface concentration of oxygen and nitrogen on the catalysts' surface.

  20. Characterization of low-pressure microwave and radio frequency discharges in oxygen applying optical emission spectroscopy and multipole resonance probe

    NASA Astrophysics Data System (ADS)

    Steves, Simon; Styrnoll, Tim; Mitschker, Felix; Bienholz, Stefan; Nikita, Bibinov; Awakowicz, Peter

    2013-11-01

    Optical emission spectroscopy (OES) and multipole resonance probe (MRP) are adopted to characterize low-pressure microwave (MW) and radio frequency (RF) discharges in oxygen. In this context, both discharges are usually applied for the deposition of permeation barrier SiOx films on plastic foils or the inner surface of plastic bottles. For technological reasons the MW excitation is modulated and a continuous wave (cw) RF bias is used. The RF voltage produces a stationary low-density plasma, whereas the high-density MW discharge is pulsed. For the optimization of deposition process and the quality of the deposited barrier films, plasma conditions are characterized using OES and MRP. To simplify the comparison of applied diagnostics, both MW and RF discharges are studied separately in cw mode. The OES and MRP diagnostic methods complement each other and provide reliable information about electron density and electron temperature. In the MW case, electron density amounts to ne = (1.25 ± 0.26) × 1017 m-3, and kTe to 1.93 ± 0.20 eV, in the RF case ne = (6.8 ± 1.8)×1015 m-3 and kTe = 2.6 ± 0.35 eV. The corresponding gas temperatures are 760±40 K and 440±20 K.

  1. Non-thermal Plasma Induces Apoptosis in Melanoma Cells via Production of Intracellular Reactive Oxygen Species

    PubMed Central

    Sensenig, Rachel; Kalghatgi, Sameer; Cerchar, Ekaterina; Fridman, Gregory; Shereshevsky, Alexey; Torabi, Behzad; Arjunan, Krishna Priya; Podolsky, Erica; Fridman, Alexander; Friedman, Gary; Azizkhan-Clifford, Jane; Brooks, Ari D.

    2012-01-01

    Non-thermal atmospheric pressure dielectric barrier discharge (DBD) plasma may provide a novel approach to treat malignancies via induction of apoptosis. The purpose of this study was to evaluate the potential of DBD plasma to induce apoptosis in melanoma cells. Melanoma cells were exposed to plasma at doses that did not induce necrosis, and cell viability and apoptotic activity were evaluated by Trypan blue exclusion test, Annexin-V/PI staining, caspase-3 cleavage, and TUNEL® analysis. Trypan blue staining revealed that non-thermal plasma treatment significantly decreased the viability of cells in a dose-dependent manner 3 and 24 h after plasma treatment. Annexin-V/PI staining revealed a significant increase in apoptosis in plasma-treated cells at 24, 48, and 72 h post-treatment (p<0.001). Caspase-3 cleavage was observed 48 h post-plasma treatment at a dose of 15 J/cm2. TUNEL® analysis of plasma-treated cells demonstrated an increase in apoptosis at 48 and 72 h post-treatment (p<0.001) at a dose of 15 J/cm2. Pre-treatment with N-acetyl-L-cysteine (NAC), an intracellular reactive oxygen species (ROS) scavenger, significantly decreased apoptosis in plasma-treated cells at 5 and 15 J/cm2. Plasma treatment induces apoptosis in melanoma cells through a pathway that appears to be dependent on production of intracellular ROS. DBD plasma production of intracellular ROS leads to dose-dependent DNA damage in melanoma cells, detected by γ-H2AX, which was completely abrogated by pre-treating cells with ROS scavenger, NAC. Plasma-induced DNA damage in turn may lead to the observed plasma-induced apoptosis. Since plasma is non-thermal, it may be used to selectively treat malignancies. PMID:21046465

  2. Generation of low-frequency nonlinear currents in plasma by an ultrashort pulse of high-frequency radiation

    SciTech Connect

    Grishkov, V. E.; Uryupin, S. A.

    2015-07-15

    A kinetic theory of low-frequency currents induced in plasma by an ultrashort high-frequency radiation pulse is developed. General expressions for the currents flowing along the propagation direction of the pulse and along the gradient of the field energy density are analyzed both analytically and numerically for pulse durations longer or shorter than or comparable with the electron collision time in plasma. It is demonstrated that the nonlinear current flowing along the gradient of the field energy density can be described correctly only when the modification of the isotropic part of the electron distribution function is taken into account.

  3. Plasma acceleration using a radio frequency self-bias effect

    SciTech Connect

    Rafalskyi, D.; Aanesland, A.

    2015-06-15

    In this work plasma acceleration using a RF self-bias effect is experimentally studied. The experiments are conducted using a novel plasma accelerator system, called Neptune, consisting of an inductively coupled plasma source and a RF-biased set of grids. The plasma accelerator can operate in a steady state mode, producing a plasma flow with separately controlled plasma flux and velocity without any magnetic configuration. The operating pressure at the source output is as low as 0.2 mTorr and can further be decreased. The ion and electron flows are investigated by measuring the ion and electron energy distribution functions both space resolved and with different orientations with respect to the flow direction. It is found that the flow of electrons from the source is highly anisotropic and directed along the ion flow and this global flow of accelerated plasma is well localized in the plasma transport chamber. The maximum flux is about 7.5·10{sup 15} ions s{sup −1} m{sup −2} (at standard conditions) on the axis and decreasing to almost zero at a radial distances of more than 15 cm from the flow axis. Varying the RF acceleration voltage in the range 20–350 V, the plasma flow velocity can be changed between 10 and 35 km/s. The system is prospective for different technology such as space propulsion and surface modification and also interesting for fundamental studies for space-related plasma simulations and investigation of the dynamo effect using accelerated rotating plasmas.

  4. Surface Modification of Polypropylene Membrane by RF Methane/Oxygen Mixture Plasma Treatment

    NASA Astrophysics Data System (ADS)

    Tsai, Ching-Yuan; Juang, Ruey-Shin; Huang, Chun

    2011-08-01

    The hydrophilic surface modification of micro-porous polypropylene (PP) membranes is achieved by low-pressure 13.56 MHz RF methane (CH4)/oxygen (O2) gas mixture plasma treatment. The changes in surface wettability and surface free energy were examined by static contact angle analysis. The static water contact angle of the plasma modified membrane notably decreased with increases in treatment time and plasma power. The obvious increase in the surface energy of polypropylene membranes due to CH4/O2 mixture gas plasma treatments was also observed. Optical emission spectroscopy (OES) was used to analyze the chemical species of CH4/O2 mixture gas plasma treatment. The variations in the surface morphology and chemical structure of the micro-porous PP membranes were confirmed by confocal laser scanning microscopy (CLSM), Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS) measurements. XPS analysis showed significantly higher surface concentrations of oxygen functional groups for CH4/O2 mixture gas plasma-modified polypropylene membrane surfaces than for the originally unmodified polypropylene membrane surface. The experimental results show the important role of chemical species in the interaction between a CH4/O2 mixture gas plasma and a membrane surface, which can be controlled by surface modification to tailor the hydrophilicity of the membrane to the requirements of various applications.

  5. MICROPLATE-BASED OXYGEN RADICAL ABSORBANCE CAPACITY (ORAC) ASSAY OF HYDROPHILIC AND LIPOPHILIC COMPARTMENTS IN PLASMA

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Methods have been developed to evaluate the total antioxidant capacity of foods and plasma but limitations are associated with their ability to determine precisely the contribution of lipophilic antioxidants in a lipid milieu as well as interactions among them. Thus, we modified the Oxygen Radical ...

  6. Fine structure in plasma waves and radiation near the plasma frequency in Earth's foreshock

    NASA Technical Reports Server (NTRS)

    Cairns, Iver H.

    1994-01-01

    Novel observations are presented of intrunsic fine structure in the frequency spectrum of electomagnetic (EM) radiation and plasma waves near the electron plasma frequency f(sub p) during a period of unusually high interplanetary magnetic field strength. Measured using the wideband receiver on the International Sun-Earth Explorer (ISEE) 1 spacecraft, fine-structured emissions are observed both in the solar wind and the foreshock, The fine structure is shown to correspond to emissions spaced above f(sub p) near half harmonies of the electon cyclotron frequency f(sub ce), i.e., near f(sub p) + nf(sub ce)/2. These appear to be the first space physics observations of emissions spaced by f(sub ce)/2. Indirect but strong arguments are used to discriminate between EM and electrostatic (ES) signals, to identify whether ISEE 1 is in the solar wind or the foreshock, and to determine the relative frequencies of the emissions and the local f(sub p). The data are consistent with generation of the ES and EM emissions in the foreshock, with subsequent propagation of the EM emissions into the solar wind. It remains possible that some emissions currently identified as ES have significant EM character. The ES and EM emisions often merge into one another with minimal changes in frequency, arguing that their source regions and generation mechanisms are related and imposing significant constraints on theories. The f(sub ce)/2 ES and EM fine structures observed may be intrinsic to the emission mechanisms or to superposition of two series of signals with f(sub ce) spacing that differ in starting frequency by f(sub ce)/2. Present theories for nonlinear wave coupling processes, cyclotron maser emission, and other linear instability processes are all unable to explain multiple EM and/or ES components spaced by approximately f(sub ce)/2 above f(sub p) for f(sub p)/f(sub ce) much greater than 1 and typical for shock beams parameters. Suitable avenues for further theoretical research are

  7. Degradation of organic fibers in radio frequency plasma

    SciTech Connect

    Finch, J.F.; Poulsen, G.G.; Pitt, W.G. )

    1992-01-01

    Plasma processing can be used to increase adhesion of organic fibers in composite materials, but prolonged exposure can also degrade the fibers, counteracting any adhesive gains. This study investigated the safe upper bounds of plasma processing on four common organic reinforcing fibers: Kevlar 49, Spectra 900, Dacron and Nylon 6. The possible causes of fiber degradation during plasma processing were also examined. Two tests were designed to evaluate fiber tensile strength during and after prolonged exposure to an argon plasma. The first of these tests was a dynamic processing tensile test in which filaments were loaded and exposed to plasma until they failed. The other was a post processing tensile test in which exposed filaments were tensile tested at ambient conditions. These studies determined that all the fibers were adversely affected by the plasma treatment. The degree of degradation was dependent upon the type of fiber, fiber loading, plasma power, and exposure time. The failure of Dacron and Kevlar during plasma processing was dependent upon the applied load. These fibers also showed significant reduction in diameter at failure. In the same type of test the Spectra and Nylon showed no dependency upon load and appeared to fail by melting.

  8. Operational stability in pentacene thin-film transistors with threshold voltages tuned by oxygen plasma treatment

    NASA Astrophysics Data System (ADS)

    Kimura, Yoshinari; Kitamura, Masatoshi; Kitani, Asahi; Arakawa, Yasuhiko

    2016-02-01

    Pentacene-based organic thin-film transistors (TFTs) having a SiO2 gate dielectric treated with oxygen plasma have been investigated for control of the threshold voltage. The threshold voltage changed in the wide range from -15 to 80 V, depending on plasma treatment time, AC power for plasma generation, and gate dielectric thickness. The threshold voltage change was attributed to negative charges induced on and/or near the surface of the gate dielectric. The threshold voltage change on the order of 1 V was particularly proportional to plasma treatment time. The predictable change enables the control of threshold voltage in this range. In addition, the effect of gate bias stress on threshold voltage was examined. The results suggested that gate bias stress does not negate the threshold voltage change induced by plasma treatment.

  9. The Effect of Electroacupuncture with Different Frequencies on Muscle Oxygenation in Humans

    PubMed Central

    Kimura, Kenichi; Ryujin, Takayoshi; Uno, Makoto; Wakayama, Ikuro

    2015-01-01

    The aim of the present study was to investigate the effect of electroacupuncture (EA) with different frequencies on muscle oxygenation in humans. The subjects were 8 healthy male volunteers. Muscle oxygenation was measured using near-infrared spectroscopy (NIRS). Blood pressure (BP) and heart rate (HR) were monitored simultaneously. After baseline recording, EA was given for 15 min and recovery was measured for 20 minutes. The procedure of EA at 1 Hz, at 20 Hz, and at control followed in the same subjects. Tissue oxygenation index (TOI) decreased during EA at 20 Hz (P < 0.05) and increased during the recovery period. Normalized tissue hemoglobin index (nTHI) also decreased during EA at 20 Hz and increased during the recovery period (P < 0.05), whereas TOI and nTHI in the EA at 1 Hz did not change significantly throughout the experiment. The peak TOI and nTHI values at 20 Hz during the recovery period were higher than the values at 1 Hz and in the control (P < 0.05). BP and HR remained constant. These data suggest that the supply of oxygen to muscle decreased during EA at 20 Hz and increased after EA at 20 Hz, without any changes in HR and BP. PMID:25821493

  10. Oxygen plasma immersion ion implantation treatment to enhance data retention of tungsten nanocrystal nonvolatile memory

    SciTech Connect

    Wang, Jer-Chyi Chang, Wei-Cheng; Lai, Chao-Sung; Chang, Li-Chun; Ai, Chi-Fong; Tsai, Wen-Fa

    2014-03-15

    Data retention characteristics of tungsten nanocrystal (W-NC) memory devices using an oxygen plasma immersion ion implantation (PIII) treatment are investigated. With an increase of oxygen PIII bias voltage and treatment time, the capacitance–voltage hysteresis memory window is increased but the data retention characteristics become degraded. High-resolution transmission electron microscopy images show that this poor data retention is a result of plasma damage on the tunneling oxide layer, which can be prevented by lowering the bias voltage to 7 kV. In addition, by using the elevated temperature retention measurement technique, the effective charge trapping level of the WO{sub 3} film surrounding the W-NCs can be extracted. This measurement reveals that a higher oxygen PIII bias voltage and treatment time induces more shallow traps within the WO{sub 3} film, degrading the retention behavior of the W-NC memory.

  11. A New Mid-UV Resist With Oxygen Plasma Resistance

    NASA Astrophysics Data System (ADS)

    Liu, J. M.; Tzeng, Chao Huei

    1989-08-01

    A new silyl ether of resorcinol novolak resin (SERN) and a new photoactive compound (S-55NQ) have been developed for a bilayer resist system. The SERN resin is an addition-condensation type terpolymer from resorcinol, hexamethylenetetramine, and phenyl silyl ether (PSE), which is a reaction product of resorcinol and chlorosilane, under acid catalyzed condition. The S-55NQ sensitizer is a sulfonate ester of spiroglycol and naphthoquinone diazide. This alkaline soluble Si-containing resist, useful in the mid-UV region, shows high dry etching resistance to O2 plasma and O2 RIE. An etching rate ratio of 4.5 or higher based on HPR-204 as the bottom layer is obtained.

  12. Ground-Based Tests of Spacecraft Polymeric Materials under OXY-GEN Plasma-Beam

    NASA Astrophysics Data System (ADS)

    Chernik, Vladimir; Novikov, Lev; Gaidar, Anna

    2016-07-01

    Spacecraft LEO mission is accompanied by destruction of polymeric material surface under influence of atomic oxygen flow. Sources of molecular, plasma and ion beams are used for the accelerated ground-based tests of spacecraft materials. In the work application of oxygen plasma accelerator of a duoplasmatron type is described. Plasma particles have been accelerated up to average speed of 13-16 km/s. Influence of such beam on materials leads to more intensive destruction of polymers than in LEO. This fact allows to execute tests in the accelerated time scale by a method of an effective fluence. Special measures were given to decrease a concentration of both gaseous and electrode material impurities in the oxygen beam. In the work the results of simulative tests of spacecraft materials and experiments on LEO are considered. Comparison of plasma beam simulation with LEO data has shown conformity for structures of a number of polymeric materials. The relative erosion yields (normalized with respect to polyimide) of the tested materials are shown practically equal to those in LEO. The obtained results give grounds for using the plasma-generation mode with ion energies of 20-30 eV to accelerated testing of spacecraft materials for long -term LEO missions.

  13. Hydrogen and oxygen trapping and retention in stainless steel and graphite materials irradiated in plasma

    NASA Astrophysics Data System (ADS)

    Begrambekov, L.; Ayrapetov, A.; Ermakov, V.; Kaplevsky, A.; Sadovsky, Ya.; Shigin, P.

    2013-11-01

    The paper presents the results of experimental investigation of energy and flux dependences of hydrogen isotopes and oxygen trapping in carbon materials (carbon fiber composite and pyrolitic graphite), and metals (stainless steel and nickel) under irradiation in the deuterium gas discharge plasma with and without oxygen addition. The dependence of hydrogen trapping on ion energy, ion current density, oxygen addition in deuterium plasma are presented and analyzed. The sorbed molecules, containing hydrogen atoms from the residual gas and deuterium atoms of the working gas are shown to be the important source of hydrogen trapping in both carbon based materials and stainless steel. Irradiation of the SS vacuum vessel with the neutrals or/and ions of (D2 + O2) plasma initiate the hydrogen diffusion from the vessel wall and H2, HD, D2O, HDO, H2O molecule formation on the wall surface. Trapping of the low energy plasma particles and the particles from the sorbed molecules as well as modification of working gas composition are considered as the processes provided at the expense of the potential energy of plasma particles with respect to the surface and occurred through their inelastic collisions with the surface. The hydrogen trapping occurred due to “potential” processes was named as “potential”, and in contrast the trapping of fast particles due to their kinetic energy was labeled as “kinetic”.

  14. Plasma jet-induced tissue oxygenation: potentialities for new therapeutic strategies

    NASA Astrophysics Data System (ADS)

    Collet, G.; Robert, E.; Lenoir, A.; Vandamme, M.; Darny, T.; Dozias, S.; Kieda, C.; Pouvesle, J. M.

    2014-02-01

    The lack of oxygen is a major reason for the resistance of tumor cells to treatments such as radiotherapies. A large number of recent publications on non-thermal plasma applications in medicine report cell behavior modifications and modulation of soluble factors. This in vivo study tested whether such modifications can lead to vascular changes in response to plasma application. Two in situ optical-based methods were used simultaneously, in real time, to assess the effect of non-thermal plasma on tissue vasculature. Tissue oxygen partial pressure (pO2) was measured using a time-resolved luminescence-based optical probe, and the microvascular erythrocyte flow was determined by laser Doppler flowmetry. When plasma treatment was applied on mouse skin, a rapid pO2 increase (up to 4 times) was subcutaneously measured and correlated with blood flow improvement. Such short duration, i.e. 5 min, plasma-induced effects were shown to be locally restricted to the treated area and lasted over 120 min. Further investigations should elucidate the molecular mechanisms of these processes. However, improvement of oxygenation and perfusion open new opportunities for tumor treatments in combination with radiotherapy, and for tumor blood vessel normalization based strategies.

  15. Theory and Observations of High Frequency Alfven Eigenmodes in Low Aspect Ratio Plasma

    SciTech Connect

    N.N. Gorelenkov; E. Fredrickson; E. Belova; C.Z. Cheng; D. Gates; S. Kaye; R. White

    2003-06-27

    New observations of sub-cyclotron frequency instability in low aspect ratio plasma in National Spherical Torus Experiments (NSTX) are reported. The frequencies of observed instabilities correlate with the characteristic Alfven velocity of the plasma. A theory of localized Compressional Alfven Eigenmodes (CAE) and Global shear Alfven Eigenmodes (GAE) in low aspect ratio plasma is presented to explain the observed high frequency instabilities. CAE's/GAE's are driven by the velocity space gradient of energetic super-Alfvenic beam ions via Doppler shifted cyclotron resonances. One of the main damping mechanisms of GAE's, the continuum damping, is treated perturbatively within the framework of ideal MHD. Properties of these cyclotron instabilities ions are presented.

  16. Propagation of terahertz electromagnetic wave in plasma with inhomogeneous collision frequency

    SciTech Connect

    Tian, Yuan; Han, YiPing; Ling, YingJie; Ai, Xia

    2014-02-15

    In this paper, we investigate the absorption spectra of terahertz electromagnetic wave in plasma with inhomogeneous collision frequency. Profiles are introduced to describe the non-uniformity of collision frequency. It is interesting to find that when the plasma is collision frequency inhomogeneous, the absorption spectrum would decreases faster than that in uniform plasma. And the rate of decreasing would be different when the profile changes. Two parameters are set up to predict how the profiles affect the absorption spectra. Furthermore, the effects of electron density are also considered.

  17. Low frequency vibrational modes of oxygenated myoglobin, hemoglobins, and modified derivatives.

    PubMed

    Jeyarajah, S; Proniewicz, L M; Bronder, H; Kincaid, J R

    1994-12-01

    The low frequency resonance Raman spectra of the dioxygen adducts of myoglobin, hemoglobin, its isolated subunits, mesoheme-substituted hemoglobin, and several deuteriated heme derivatives are reported. The observed oxygen isotopic shifts are used to assign the iron-oxygen stretching (approximately 570 cm-1) and the heretofore unobserved delta (Fe-O-O) bending (approximately 420 cm-1) modes. Although the delta (Fe-O-O) is not enhanced in the case of oxymyoglobin, it is observed for all the hemoglobin derivatives, its exact frequency being relatively invariable among the derivatives. The lack of sensitivity to H2O/D2O buffer exchange is consistent with our previous interpretation of H2O/D2O-induced shifts of v(O-O) in the resonance Raman spectra of dioxygen adducts of cobalt-substituted heme proteins; namely, that those shifts are associated with alterations in vibrational coupling of v(O-O) with internal modes of proximal histidyl imidazole rather than to steric or electronic effects of H/D exchange at the active site. No evidence is obtained for enhancement of the v(Fe-N) stretching frequency of the linkage between the heme iron and the imidazole group of the proximal histidine. PMID:7983043

  18. A Fiber Optic Catalytic Sensor for Neutral Atom Measurements in Oxygen Plasma

    PubMed Central

    Zaplotnik, Rok; Vesel, Alenka; Mozetic, Miran

    2012-01-01

    The presented sensor for neutral oxygen atom measurement in oxygen plasma is a catalytic probe which uses fiber optics and infrared detection system to measure the gray body radiation of the catalyst. The density of neutral atoms can be determined from the temperature curve of the probe, because the catalyst is heated predominantly by the dissipation of energy caused by the heterogeneous surface recombination of neutral atoms. The advantages of this sensor are that it is simple, reliable, easy to use, noninvasive, quantitative and can be used in plasma discharge regions. By using different catalyst materials the sensor can also be applied for detection of neutral atoms in other plasmas. Sensor design, operation, example measurements and new measurement procedure for systematic characterization are presented. PMID:22666005

  19. A Comparison of Atomic Oxygen Degradation in Low Earth Orbit and in a Plasma Etcher

    NASA Technical Reports Server (NTRS)

    Townsend, Jacqueline A.; Park, Gloria

    1997-01-01

    In low Earth orbit (LEO) significant degradation of certain materials occurs from exposure to atomic oxygen (AO). Orbital opportunities to study this degradation for specific materials are limited and expensive. While plasma etchers are commonly used in ground-based studies because of their low cost and convenience, the environment produced in an etcher chamber differs greatly from the LEO environment. Because of the differences in environment, the validity of using etcher data has remained an open question. In this paper, degradation data for 22 materials from the orbital experiment Evaluation of Oxygen Interaction with Materials (EOIM-3) are compared with data from EOIM-3 control specimens exposed in a typical plasma etcher. This comparison indicates that, when carefully considered, plasma etcher results can produce order-of-magnitude estimates of orbital degradation. This allows the etcher to be used to screen unacceptable materials from further, more expensive tests.

  20. Surface Plasma Arc by Radio-Frequency Control Study (SPARCS)

    SciTech Connect

    Ruzic, David N.

    2013-04-29

    This paper is to summarize the work carried out between April 2012 and April 2013 for development of an experimental device to simulate interactions of o -normal detrimental events in a tokamak and ICRF antenna. The work was mainly focused on development of a pulsed plasma source using theta pinch and coaxial plasma gun. This device, once completed, will have a possible application as a test stand for high voltage breakdown of an ICRF antenna in extreme events in a tokamak such as edge-localized modes or disruption. Currently, DEVeX does not produce plasma with high temperature enough to requirement for an ELM simulator. However, theta pinch is a good way to produce high temperature ions. The unique characteristic of plasma heating by a theta pinch is advantageous for an ELM simulator due to its effective ion heating. The objective of the proposed work, therefore, is to build a test facility using the existing theta pinch facility in addition to a coaxial plasma gun. It is expected to produce a similar pulsed-plasma heat load to the extreme events in tokamaks and to be applied for studying interactions of hot plasma and ICRF antennas.

  1. Low-pressure line-shape study in molecular oxygen with absolute frequency reference

    NASA Astrophysics Data System (ADS)

    Domysławska, J.; Wójtewicz, S.; Cygan, A.; Bielska, K.; Lisak, D.; Masłowski, P.; Trawiński, R. S.; Ciuryło, R.

    2013-11-01

    We present a line-shape analysis of the rovibronic R1 Q2 transition of the oxygen B band resolved by the Pound-Drever-Hall-locked frequency-stabilized cavity ring-down spectroscopy technique in the low pressure range. The frequency axis of the spectra is linked by the ultra-narrow diode laser to the optical frequency comb in order to measure the absolute frequency at each point of the recorded spectra. Experimental spectra are fitted with various line-shape models: the Voigt profile, the Galatry profile, the Nelkin-Ghatak profile, the speed-dependent Voigt profile, and the speed-dependent Nelkin-Ghatak profile with quadratic and hypergeometric approximations for the speed dependence of collisional broadening and shifting. The influences of Dicke narrowing, speed-dependent effects, and correlation between phase- and velocity-changing collisions on the line shape are investigated. Values of line-shape parameters, including the absolute frequency of the transition 435685.24828(46) GHz, are reported.

  2. Properties of radio-frequency heated argon confined uranium plasmas

    NASA Technical Reports Server (NTRS)

    1976-01-01

    Pure uranium hexafluoride (UF6) was injected into an argon confined, steady state, rf-heated plasma within a fused silica peripheral wall test chamber. Exploratory tests conducted using an 80 kW rf facility and different test chamber flow configurations permitted selection of the configuration demonstrating the best confinement characteristics and minimum uranium compound wall coating. The overall test results demonstrated applicable flow schemes and associated diagnostic techniques were developed for the fluid mechanical confinement and characterization of uranium within an rf plasma discharge when pure UF6 is injected for long test times into an argon-confined, high-temperature, high-pressure, rf-heated plasma.

  3. Real-time frequency domain temperature and oxygen sensor with a single optical fiber.

    PubMed

    Liao, S C; Xu, Z; Izatt, J A; Alcala, J R

    1997-11-01

    The combined excited-state phosphorescence life-times of an alexandrite crystal and platinum tetraphenylporphyrin Pt(TPP) in a single-fiber sensor are used to monitor temperature and oxygen concentration in the physiological range from 15-45 degrees C and 0-50% O2 with precision of 0.24 degree C and 0.15% O2 and accuracy of 0.28 degree C and 0.2% O2. A 500-micron cubic alexandrite crystal bound to the distal end of a 750-micron-diameter optical fiber core and the Pt(TPP) coated circumferentially with a length of 1 cm from the end of the same fiber are excited with pulsed super-bright blue LED light. This apparatus uses a 125-kHz sampler for data acquisition and frequency domain methods for signal processing. The instrument amplifies both the dc and ac components of the photomultiplier output and band limits the signal to 20 kHz. The fundamental frequency of the excitation is set to 488.3 Hz and the highest harmonic used is the 35th. This bandlimited signal is sampled and averaged over a few hundred cycles in the time domain. The frequency domain representation of the data is obtained by employing fast Fourier transform algorithms. The phase delay and the modulation ratio of each sampled harmonic are then computed. At least four log-spaced harmonic phases or modulations are averaged before decoding the two lifetimes of temperature and oxygen phosphorescent sensors. A component of zero lifetime is introduced to account for the excitation backscatter leakage through optical interference filters seen by the photodetector. Linear and second-order empirical polynomials are employed to compute the temperatures and oxygen concentrations from the inverse lifetimes. In the situation of constant oxygen concentration, the lifetime of Pt(TPP) changes with temperature but can be compensated using the measured temperature lifetime. The system drift is 0.24 degree C for the temperature measurement and 0.59% for the oxygen concentration measurement over 30 h of continuous operation

  4. Studies on the effect of finite geometrical asymmetry in dual capacitively coupled radio frequency plasma

    NASA Astrophysics Data System (ADS)

    Bora, B.

    2015-10-01

    In recent years, dual capacitively coupled radio frequency (CCRF) glow discharge plasma has been widely studied in the laboratory because of its simpler design and high efficiency for different material processing applications such as thin-film deposition, plasma etching, sputtering of insulating materials etc. The main objective of studies on dual frequency CCRF plasma has been the independent control of ion energy and ion flux using an electrical asymmetry effect (EAE). Most studies have been reported in electrode configurations that are either geometrically symmetric (both electrodes are equal) or completely asymmetric (one electrode is infinitely bigger than the other). However, it seems that most of the laboratory CCRF plasmas have finite electrode geometry. In addition, plasma series resonance (PSR) and electron bounce resonance (EBR) heating also come into play as a result of geometrical asymmetry as well as EAE. In this study, a dual frequency CCRF plasma has been studied in which the dual frequency CCRF has been coupled to the lumped circuit model of the plasma and the time-independent fluid model of the plasma sheath, in order to study the effect of finite geometrical asymmetry on the generation of dc-self bias and plasma heating. The dc self-bias is found to strongly depend on the ratio of the area between the electrodes. The dc self-bias is found to depend on the phase angle between the two applied voltage waveforms. The EAE and geometrical asymmetry are found to work differently in controlling the dc self-bias. It can be concluded that the phase angle between the two voltage waveforms in dual CCRF plasmas has an important role in determining the dc self-bias and may be used for controlling the plasma properties in the dual frequency CCRF plasma.

  5. Cl atom recombination on silicon oxy-chloride layers deposited on chamber walls in chlorine-oxygen plasmas

    SciTech Connect

    Khare, Rohit; Srivastava, Ashutosh; Donnelly, Vincent M.

    2012-09-15

    Chlorine atom recombination coefficients were measured on silicon oxy-chloride surfaces deposited in a chlorine inductively coupled plasma (ICP) with varying oxygen concentrations, using the spinning wall technique. A small cylinder embedded in the walls of the plasma reactor chamber was rapidly rotated, repetitively exposing its surface to the plasma chamber and a differentially pumped analysis chamber housing a quadruple mass spectrometer for line-of-sight desorbing species detection, or an Auger electron spectrometer for in situ surface analysis. The spinning wall frequency was varied from 800 to 30 000 rpm resulting in a detection time, t (the time a point on the surface takes to rotate from plasma chamber to the position facing the mass or Auger spectrometer), of {approx}1-40 ms. Desorbing Cl{sub 2}, due to Langmuir-Hinshelwood (LH) Cl atom recombination on the reactor wall surfaces, was detected by the mass spectrometer and also by a pressure rise in one of the differentially pumped chambers. LH Cl recombination coefficients were calculated by extrapolating time-resolved desorption decay curves to t = 0. A silicon-covered electrode immersed in the plasma was either powered at 13 MHz, creating a dc bias of -119 V, or allowed to electrically float with no bias power. After long exposure to a Cl{sub 2} ICP without substrate bias, slow etching of the Si wafer coats the chamber and spinning wall surfaces with an Si-chloride layer with a relatively small amount of oxygen (due to a slow erosion of the quartz discharge tube) with a stoichiometry of Si:O:Cl = 1:0.38:0.38. On this low-oxygen-coverage surface, any Cl{sub 2} desorption after LH recombination of Cl was below the detection limit. Adding 5% O{sub 2} to the Cl{sub 2} feed gas stopped etching of the Si wafer (with no rf bias) and increased the oxygen content of the wall deposits, while decreasing the Cl content (Si:O:Cl = 1:1.09:0.08). Cl{sub 2} desorption was detectable for Cl recombination on the spinning

  6. Nanopore formation process in artificial cell membrane induced by plasma-generated reactive oxygen species.

    PubMed

    Tero, Ryugo; Yamashita, Ryuma; Hashizume, Hiroshi; Suda, Yoshiyuki; Takikawa, Hirofumi; Hori, Masaru; Ito, Masafumi

    2016-09-01

    We investigated morphological change of an artificial lipid bilayer membrane induced by oxygen radicals which were generated by non-equilibrium atmospheric pressure plasma. Neutral oxygen species, O((3)Pj) and O2((1)Δg), were irradiated of a supported lipid bilayer existing under a buffer solution at various conditions of dose time and distances, at which the dose amounts of the oxygen species were calculated quantitatively. Observation using an atomic force microscope and a fluorescence microscope revealed that dose of the neutral oxygen species generated nanopores with the diameter of 10-50 nm in a phospholipid bilayer, and finally destructed the bilayer structure. We found that protrusions appeared on the lipid bilayer surface prior to the formation of nanopores, and we attributed the protrusions to the precursor of the nanopores. We propose a mechanism of the pore formation induced by lipid oxidation on the basis of previous experimental and theoretical studies. PMID:27216034

  7. Diagnostics of silane and germane radio frequency plasmas by coherent anti-Stokes Raman spectroscopy

    NASA Astrophysics Data System (ADS)

    Perry, Joseph W.; Shing, Y. H.; Allevato, C. E.

    1988-06-01

    In situ plasma diagnostics using coherent anti-Stokes Raman spectroscopy have shown different dissociation characteristics for GeH4 and SiH4 in radio frequency (rf) plasma-enhanced chemical vapor deposition of amorphous silicon germanium alloy (a-SiGe:H) thin films. The GeH4 dissociation rate in rf plasmas is a factor of about 3 larger than that of SiH4. Plasma diagnostics have revealed that the hydrogen dilution of the SiH4 and GeH4 mixed plasma plays a critical role in suppressing the gas phase polymerization and enhancing the GeH4 dissociation.

  8. Diagnostics of silane and germane radio frequency plasmas by coherent anti-Stokes Raman spectroscopy

    NASA Technical Reports Server (NTRS)

    Perry, Joseph W.; Shing, Y. H.; Allevato, C. E.

    1988-01-01

    In situ plasma diagnostics using coherent anti-Stokes Raman spectroscopy have shown different dissociation characteristics for GeH4 and SiH4 in radio frequency (rf) plasma-enhanced chemical vapor deposition of amorphous silicon germanium alloy (a-SiGe:H) thin films. The GeH4 dissociation rate in rf plasmas is a factor of about 3 larger than that of SiH4. Plasma diagnostics have revealed that the hydrogen dilution of the SiH4 and GeH4 mixed plasma plays a critical role in suppressing the gas phase polymerization and enhancing the GeH4 dissociation.

  9. Effect of axial finiteness on electron heating in low-frequency inductively coupled plasmas

    SciTech Connect

    Aman-ur-Rehman; Pu, Y.-K.

    2006-10-15

    Total power absorption inside the plasma (by taking the thermal motion of the electrons into account) has been calculated using different inductively coupled plasma models. The comparison shows that in the low-frequency region the results of the semi-infinite plasma models are different from those of the finite-length plasma models. The semi-infinite plasma models show net reduction of heating in the low-frequency region, due to thermal motion of the electrons from inside the skin region to outside the skin region. The finite-length plasma models on the other hand (due to change in the skin depth owing to the boundary condition of E=0 at z=L, and reflection of electrons from the plasma boundary) show that the decrease in heating due to the motion of the electrons from inside the skin depth to outside the skin depth is recovered by the reflection of the electrons from the plasma boundary. Hence, it is concluded that the results of the semi-infinite plasma models presented by Tyshetskiy et al. [Phys Rev. Lett. 90, 255002 (2003)] can be misleading (in the low-frequency region), since they overlooked the effect of axial finiteness of the plasma.

  10. Aging of oxygen and hydrogen plasma discharge treated a-C:H and ta-C coatings

    NASA Astrophysics Data System (ADS)

    Bachmann, Svenja; Schulze, Marcus; Morasch, Jan; Hesse, Sabine; Hussein, Laith; Krell, Lisa; Schnagl, Johann; Stark, Robert W.; Narayan, Suman

    2016-05-01

    Surface modification with gas plasma is an efficient and easy way to improve the surface energy and the tribological behavior of diamond-like carbon (DLC) coatings, e.g., in biomedical implants or as protective coatings. However, the long-term performance of the plasma treated DLC coatings is not fully clear. We thus studied the long-term stability of two kinds of DLC coatings, namely (a) hydrogenated amorphous carbon (a-C:H) and (b) tetrahedral amorphous carbon (ta-C) treated at different radio frequency (RF) power and time of oxygen (O2) and hydrogen (H2) plasma. Their surface properties, e.g. surface wettability, structure and tribological behavior, were studied at regular intervals for a period of two months using contact angle goniometer, Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), lateral force microscopy (LFM) and ball on disc apparatus. The surface energy of both the coatings decreased upon aging. The higher the RF power and time of treatment, the higher was the hydrophobicity upon aging. XPS analysis showed that the increase in hydrophobicity could be due to adsorption of unavoidable volatile organic components in the atmosphere. The H2 plasma treated ta-C was capable of rearranging its structural bonds upon aging. The nano-friction measurements by LFM showed that the coefficient of friction of plasma treated a-C:H and ta-C decreased upon aging. The results indicate that the surface properties of plasma treated a-C:H and ta-C are not stable on long-term and are influenced by the environmental conditions.

  11. Versatile high rate plasma deposition and processing with very high frequency excitation

    SciTech Connect

    Heintze, M.

    1997-07-01

    The interest in plasma deposition using very high frequency (VHF) excitation arose after the preparation of a-Si:H at high growth rates was demonstrated. Subsequently the improved process flexibility and the control of material properties offered by the variation of the plasma excitation frequency was recognized. The preparation of amorphous and microcrystalline thin films in a VHF-plasma is described. The increased growth rates have been attributed to an enhancement of film precursor formation at VHF, to the decreased sheath thickness as well as to an enhancement of the surface reactivity by positive ions. Plasma diagnostic investigations show that the parameters mainly affected by the excitation frequency are the ion flux to the electrodes as well as the sheaths potentials and widths, rather than the plasma density. 55 refs., 13 figs.

  12. Elimination of transmissible spongiform encephalopathy infectivity and decontamination of surgical instruments by using radio-frequency gas-plasma treatment.

    PubMed

    Baxter, H C; Campbell, G A; Whittaker, A G; Jones, A C; Aitken, A; Simpson, A H; Casey, M; Bountiff, L; Gibbard, L; Baxter, R L

    2005-08-01

    It has now been established that transmissible spongiform encephalopathy (TSE) infectivity, which is highly resistant to conventional methods of deactivation, can be transmitted iatrogenically by contaminated stainless steel. It is important that new methods are evaluated for effective removal of protein residues from surgical instruments. Here, radio-frequency (RF) gas-plasma treatment was investigated as a method of removing both the protein debris and TSE infectivity. Stainless-steel spheres contaminated with the 263K strain of scrapie and a variety of used surgical instruments, which had been cleaned by a hospital sterile-services department, were examined both before and after treatment by RF gas plasma, using scanning electron microscopy and energy-dispersive X-ray spectroscopic analysis. Transmission of scrapie from the contaminated spheres was examined in hamsters by the peripheral route of infection. RF gas-plasma treatment effectively removed residual organic residues on reprocessed surgical instruments and gross contamination both from orthopaedic blades and from the experimentally contaminated spheres. In vivo testing showed that RF gas-plasma treatment of scrapie-infected spheres eliminated transmission of infectivity. The infectivity of the TSE agent adsorbed on metal spheres could be removed effectively by gas-plasma cleaning with argon/oxygen mixtures. This treatment can effectively remove 'stubborn' residual contamination on surgical instruments. PMID:16033987

  13. Self-consistent electrodynamics of large-area high-frequency capacitive plasma discharge

    SciTech Connect

    Chen Zhigang; Rauf, Shahid; Collins, Ken

    2010-10-15

    Capacitively coupled plasmas (CCPs) generated using high frequency (3-30 MHz) and very high frequency (30-300 MHz) radio-frequency (rf) sources are used for many plasma processing applications including thin film etching and deposition. When chamber dimensions become commensurate with the effective rf wavelength in the plasma, electromagnetic wave effects impose a significant influence on plasma behavior. Because the effective rf wavelength in plasma depends upon both rf and plasma process conditions (e.g., rf power and gas pressure), a self-consistent model including both the rf power delivery system and the plasma discharge is highly desirable to capture a more complete physical picture of the plasma behavior. A three-dimensional model for self-consistently studying both electrodynamic and plasma dynamic behavior of large-area (Gen 10, >8 m{sup 2}) CCP is described in this paper. This model includes Maxwell's equations and transport equations for charged and neutral species, which are coupled and solved in the time domain. The complete rf plasma discharge chamber including the rf power delivery subsystem, rf feed, electrodes, and the plasma domain is modeled as an integrated system. Based on this full-wave solution model, important limitations for processing uniformity imposed by electromagnetic wave propagation effects in a large-area CCP (3.05x2.85 m{sup 2} electrode size) are studied. The behavior of H{sub 2} plasmas in such a reactor is examined from 13.56 to 200 MHz. It is shown that various rectangular harmonics of electromagnetic fields can be excited in a large-area rectangular reactor as the rf or power is increased. The rectangular harmonics can create not only center-high plasma distribution but also high plasma density at the corners and along the edges of the reactor.

  14. Temperature of hydrogen radio frequency plasma under dechlorination process of polychlorinated biphenyls

    SciTech Connect

    Inada, Y. Abe, K.; Kumada, A.; Hidaka, K.; Amano, K.; Itoh, K.; Oono, T.

    2014-10-27

    It has been reported that RF (radio frequency) hydrogen plasmas promote the dechlorination process of PCBs (polychlorinated biphenyls) under irradiation of MW (microwave). A relative emission intensity spectroscope system was used for single-shot imaging of two-dimensional temperature distributions of RF hydrogen plasmas generated in chemical solutions with several mixing ratios of isopropyl alcohol (IPA) and insulation oil under MW irradiation. Our experimental results showed that the plasma generation frequencies for the oil-contaminating solutions were higher than that for the pure IPA solution. In addition, the plasma temperature in the compound liquids including both oil and IPA was higher than that in the pure IPA and oil solutions. A combination of the plasma temperature measurements and plasma composition analysis indicated that the hydrogen radicals generated in a chemical solution containing the equal volumes of IPA and oil were almost the same amounts of H and H{sup +}, while those produced in the other solutions were mainly H.

  15. New waves at multiples of the plasma frequency upstream of the earth's bow shock

    NASA Technical Reports Server (NTRS)

    Cairns, I. H.

    1986-01-01

    The first observations of waves at harmonics higher than the second of the electron plasma frequency are reported. The observations were made by the ISEE 1 spacecraft upstream of the earth's bow shock. The waves are interpreted as electromagnetic radiation at the fundamental and up to the fifth harmonic of the plasma frequency, with effective temperatures decreasing from 5 x 10 to the 17th K to 10 billion K over this range. Two models are proposed for the emission of the waves.

  16. Ozone-stimulated emission due to atomic oxygen population inversions in an argon microwave plasma torch

    SciTech Connect

    Lukina, N. A.; Sergeichev, K. F.

    2008-06-15

    It is shown that, in a microwave torch discharge in an argon jet injected into an oxygen atmosphere at normal pressure, quasi-resonant energy transfer from metastable argon atoms to molecules of oxygen and ozone generated in the torch shell and, then, to oxygen atoms produced via the dissociation of molecular oxygen and ozone leads to the inverse population of metastable levels of atomic oxygen. As a result, the excited atomic oxygen with population inversions becomes a gain medium for lasing at wavelengths of 844.6 and 777.3 nm (the 3{sup 3}P-3{sup 3}S and 3{sup 5}P-3{sup 5}S transitions). It is shown that an increase in the ozone density is accompanied by an increase in both the lasing efficiency at these wavelength and the emission intensity of the plasma-forming argon at a wavelength of 811.15 nm (the {sup 2}P{sup 0}4s-{sup 2}P{sup 0}4p transition). When the torch operates unstably, the production of singlet oxygen suppresses ozone generation; as a result, the lasing effect at these wavelengths disappears.

  17. Ionized gas (plasma) delivery of reactive oxygen species (ROS) into artificial cells

    NASA Astrophysics Data System (ADS)

    Hong, Sung-Ha; Szili, Endre J.; Jenkins, A. Toby A.; Short, Robert D.

    2014-09-01

    This study was designed to enhance our understanding of how reactive oxygen species (ROS), generated ex situ by ionized gas (plasma), can affect the regulation of signalling processes within cells. A model system, comprising of a suspension of phospholipid vesicles (cell mimics) encapsulating a ROS reporter, was developed to study the plasma delivery of ROS into cells. For the first time it was shown that plasma unequivocally delivers ROS into cells over a sustained period and without compromising cell membrane integrity. An important consideration in cell and biological assays is the presence of serum, which significantly reduced the transfer efficiency of ROS into the vesicles. These results are key to understanding how plasma treatments can be tailored for specific medical or biotechnology applications. Further, the phospholipid vesicle ROS reporter system may find use in other studies involving the application of free radicals in biology and medicine.

  18. Low-frequency electromagnetic plasma waves at comet P/Grigg-Skjellerup: Analysis and interpretation

    NASA Technical Reports Server (NTRS)

    Neubauer, Fritz M.; Glassmeier, Karl-Heinz; Coates, A. J.; Johnstone, A. D.

    1993-01-01

    The propagation and polarization characteristic of low-frequency electromagnetic wave fields near comet P/Grigg-Skjellerup (P/GS) are analyzed using magnetic field and plasma observations obtained by the Giotto magnetometer experiment and the Johnstone plasma analyzer during the encounter at the comet on July 10, 1992. The results have been physically interpreted.

  19. Low frequency electrostatic and electromagnetic modes in nonuniform cold quantum plasmas

    SciTech Connect

    Saleem, H.; Ahmad, Ali; Khan, S. A.

    2008-01-15

    The low frequency electrostatic and electromagnetic linear modes in a nonuniform cold quantum electron-ion plasma are studied. The effect of stationary dust on an electrostatic mode is also investigated. The quantum corrections in the linear dispersion relations of a cold dense plasma are presented with possible applications.

  20. Non-thermal dielectric barrier discharge plasma induces angiogenesis through reactive oxygen species

    PubMed Central

    Arjunan, Krishna Priya; Friedman, Gary; Fridman, Alexander; Clyne, Alisa Morss

    2012-01-01

    Vascularization plays a key role in processes such as wound healing and tissue engineering. Non-thermal plasma, which primarily produces reactive oxygen species (ROS), has recently emerged as an efficient tool in medical applications including blood coagulation, sterilization and malignant cell apoptosis. Liquids and porcine aortic endothelial cells were treated with a non-thermal dielectric barrier discharge plasma in vitro. Plasma treatment of phosphate-buffered saline (PBS) and serum-free medium increased ROS concentration in a dose-dependent manner, with a higher concentration observed in serum-free medium compared with PBS. Species concentration inside cells peaked 1 h after treatment, followed by a decrease 3 h post treatment. Endothelial cells treated with a plasma dose of 4.2 J cm–2 had 1.7 times more cells than untreated samples 5 days after plasma treatment. The 4.2 J cm–2 plasma dose increased two-dimensional migration distance by 40 per cent compared with untreated control, while the number of cells that migrated through a three-dimensional collagen gel increased by 15 per cent. Tube formation was also enhanced by plasma treatment, with tube lengths in plasma-treated samples measuring 2.6 times longer than control samples. A fibroblast growth factor-2 (FGF-2) neutralizing antibody and ROS scavengers abrogated these angiogenic effects. These data indicate that plasma enhanced proliferation, migration and tube formation is due to FGF-2 release induced by plasma-produced ROS. Non-thermal plasma may be used as a potential tool for applying ROS in precise doses to enhance vascularization. PMID:21653568

  1. Spectroscopic measurement of high-frequency electric fields in the interaction of explosive debris plasma with magnetized background plasma

    SciTech Connect

    Bondarenko, A. S. Schaeffer, D. B.; Everson, E. T.; Clark, S. E.; Constantin, C. G.; Niemann, C.

    2014-12-15

    The collision-less transfer of momentum and energy from explosive debris plasma to magnetized background plasma is a salient feature of various astrophysical and space environments. While much theoretical and computational work has investigated collision-less coupling mechanisms and relevant parameters, an experimental validation of the results demands the measurement of the complex, collective electric fields associated with debris-background plasma interaction. Emission spectroscopy offers a non-interfering diagnostic of electric fields via the Stark effect. A unique experiment at the University of California, Los Angeles, that combines the Large Plasma Device (LAPD) and the Phoenix laser facility has investigated the marginally super-Alfvénic, quasi-perpendicular expansion of a laser-produced carbon (C) debris plasma through a preformed, magnetized helium (He) background plasma via emission spectroscopy. Spectral profiles of the He II 468.6 nm line measured at the maximum extent of the diamagnetic cavity are observed to intensify, broaden, and develop equally spaced modulations in response to the explosive C debris, indicative of an energetic electron population and strong oscillatory electric fields. The profiles are analyzed via time-dependent Stark effect models corresponding to single-mode and multi-mode monochromatic (single frequency) electric fields, yielding temporally resolved magnitudes and frequencies. The proximity of the measured frequencies to the expected electron plasma frequency suggests the development of the electron beam-plasma instability, and a simple saturation model demonstrates that the measured magnitudes are feasible provided that a sufficiently fast electron population is generated during C debris–He background interaction. Potential sources of the fast electrons, which likely correspond to collision-less coupling mechanisms, are briefly considered.

  2. Plasma Parameters of SRF Cavities for Radio-Frequency Discharge Processing

    NASA Astrophysics Data System (ADS)

    Upadhyay, Janardan; Popovic, Svetozar; Vuskovic, Lepsha; Valente-Feliciano, Anne-Marie; Phillips, Larry

    2012-10-01

    Superconducting radio frequency (SRF) cavities of bulk Niobium are accelerating field-generating components of particle accelerators. Cavities are designed to support TM modes at a resonant frequency, which usually serve as their identifier. RF plasma surface modification dry-etching technology as an alternative to the currently existing wet etching technology requires a different RF coupling regime. The choice of power generator frequency greatly affects the field and plasma parameters distribution over the cavity. These are adjusted by a coaxial centerline antenna to provide for optimum level of plasma sheath uniformity. In the search for best etching conditions, we are opting for radio frequency (13.56 MHz, 100 MHz) and microwave frequency plasma (2.45 GHz) in Ar/Cl2 gas mixture. We have developed five optical probes for simultaneous spectroscopic measurements of the plasma properties at five points inside the cavity. The electron temperature and density measurement at the same set of points will be also measured with a Langmuir probe. The measurement of plasma parameters at different pressure and power for the chosen frequency set with varying chlorine content will be presented.

  3. Low frequency electromagnetic oscillations in dense degenerate electron-positron pair plasma, with and without ions

    NASA Astrophysics Data System (ADS)

    Khan, S. A.; Ayub, M. K.; Ahmad, Ali

    2012-10-01

    Quantum plasma oscillations are studied in a strongly magnetized, ultra-dense plasma with degenerate electrons and positrons. The dispersive role of electron and positron quantum effects on low frequency (in comparison to electron cyclotron frequency) shear electromagnetic wave is investigated by employing hydrodynamic formulation. In the presence of ions, the density balance changes, and the electromagnetic wave (with frequency lower than the ion cyclotron frequency) is shown to couple with electrostatic ion mode under certain conditions. For such low frequency waves, it is also seen that the contribution of electron and positron degeneracy pressure is dominant as compared to their diffraction effects. The results are analyzed numerically for illustrative purpose pointing out their relevance to the dense laboratory (e.g., super-intense laser-dense matter interactions) and astrophysical plasmas.

  4. Low frequency electromagnetic oscillations in dense degenerate electron-positron pair plasma, with and without ions

    SciTech Connect

    Khan, S. A.; Ayub, M. K.; Ahmad, Ali

    2012-10-15

    Quantum plasma oscillations are studied in a strongly magnetized, ultra-dense plasma with degenerate electrons and positrons. The dispersive role of electron and positron quantum effects on low frequency (in comparison to electron cyclotron frequency) shear electromagnetic wave is investigated by employing hydrodynamic formulation. In the presence of ions, the density balance changes, and the electromagnetic wave (with frequency lower than the ion cyclotron frequency) is shown to couple with electrostatic ion mode under certain conditions. For such low frequency waves, it is also seen that the contribution of electron and positron degeneracy pressure is dominant as compared to their diffraction effects. The results are analyzed numerically for illustrative purpose pointing out their relevance to the dense laboratory (e.g., super-intense laser-dense matter interactions) and astrophysical plasmas.

  5. Nonequilibrium atmospheric pressure plasma jet using a combination of 50 kHz/2 MHz dual-frequency power sources

    SciTech Connect

    Zhou, Yong-Jie; Yuan, Qiang-Hua; Li, Fei; Wang, Xiao-Min; Yin, Gui-Qin; Dong, Chen-Zhong

    2013-11-15

    An atmospheric pressure plasma jet is generated by dual sinusoidal wave (50 kHz and 2 MHz). The dual-frequency plasma jet exhibits the advantages of both low frequency and radio frequency plasmas, namely, the long plasma plume and the high electron density. The radio frequency ignition voltage can be reduced significantly by using dual-frequency excitation compared to the conventional radio frequency without the aid of the low frequency excitation source. A larger operating range of α mode discharge can be obtained using dual-frequency excitation which is important to obtain homogeneous and low-temperature plasma. A larger controllable range of the gas temperature of atmospheric pressure plasma could also be obtained using dual-frequency excitation.

  6. In-situ plasma processing to increase the accelerating gradients of superconducting radio-frequency cavities

    NASA Astrophysics Data System (ADS)

    Doleans, M.; Tyagi, P. V.; Afanador, R.; McMahan, C. J.; Ball, J. A.; Barnhart, D. L.; Blokland, W.; Crofford, M. T.; Degraff, B. D.; Gold, S. W.; Hannah, B. S.; Howell, M. P.; Kim, S.-H.; Lee, S.-W.; Mammosser, J.; Neustadt, T. S.; Saunders, J. W.; Stewart, S.; Strong, W. H.; Vandygriff, D. J.; Vandygriff, D. M.

    2016-03-01

    A new in-situ plasma processing technique is being developed at the Spallation Neutron Source (SNS) to improve the performance of the cavities in operation. The technique utilizes a low-density reactive oxygen plasma at room temperature to remove top surface hydrocarbons. The plasma processing technique increases the work function of the cavity surface and reduces the overall amount of vacuum and electron activity during cavity operation; in particular it increases the field emission onset, which enables cavity operation at higher accelerating gradients. Experimental evidence also suggests that the SEY of the Nb surface decreases after plasma processing which helps mitigating multipacting issues. In this article, the main developments and results from the plasma processing R&D are presented and experimental results for in-situ plasma processing of dressed cavities in the SNS horizontal test apparatus are discussed.

  7. Plasma reactivity in high-power impulse magnetron sputtering through oxygen kinetics

    SciTech Connect

    Vitelaru, Catalin; Lundin, Daniel; Brenning, Nils; Minea, Tiberiu

    2013-09-02

    The atomic oxygen metastable dynamics in a Reactive High-Power Impulse Magnetron Sputtering (R-HiPIMS) discharge has been characterized using time-resolved diode laser absorption in an Ar/O{sub 2} gas mixture with a Ti target. Two plasma regions are identified: the ionization region (IR) close to the target and further out the diffusion region (DR), separated by a transition region. The μs temporal resolution allows identifying the main atomic oxygen production and destruction routes, which are found to be very different during the pulse as compared to the afterglow as deduced from their evolution in space and time.

  8. Phase diagram of carbon-oxygen plasma mixtures in white dwarf stars

    NASA Astrophysics Data System (ADS)

    Schneider, A. S.; Horowitz, C. J.; Hughto, J.; Berry, D. K.

    2012-12-01

    The liquid-solid phase-diagram of dense carbon-oxygen plasma mixtures found in white dwarf stars interiors is determined from molecular dynamics (MD) simulations. Our MD simulations consist of boxes with 55296 ions with different carbon to oxygen ratios. Finite size effects are estimated comparing the new MD simulations results to previous smaller simulations. We use bond angle metric to identify whether an ion is in the solid, liquid or interface and study non-equilibrium effects by obtaining the diffusion coefficients in the different phases. Our phase diagram agrees with predictions from Medin and Cumming obtained by an independent method.

  9. Estimation of electron concentration in plasma and plasma frequency in the vicinity of a hypersonic aircraft that moves in atmosphere and analysis of propagation frequencies of electromagnetic waves in such plasma

    NASA Astrophysics Data System (ADS)

    Fedorov, V. A.

    2016-05-01

    Electron concentration in plasma and plasma frequency are estimated for the plasma that is formed in the vicinity of a hypersonic aircraft that moves in atmosphere. The frequencies of electromagnetic waves that may propagate in plasma emerging in the vicinity of the aircraft are determined. Formulas that make it possible to analytically (rather than graphically) calculate electron concentration in plasma at altitudes of 30, 60, and 90 km are derived for two speeds. Several specific features of variations in the electron concentration in plasma depending on the above altitudes and speeds are presented. Quasi-periodic variations in the plasma concentration can be obtained using an increase and decrease in the speed of aircraft.

  10. Effect of additive oxygen gas on cellular response of lung cancer cells induced by atmospheric pressure helium plasma jet.

    PubMed

    Joh, Hea Min; Choi, Ji Ye; Kim, Sun Ja; Chung, T H; Kang, Tae-Hong

    2014-01-01

    The atmospheric pressure helium plasma jet driven by pulsed dc voltage was utilized to treat human lung cancer cells in vitro. The properties of plasma plume were adjusted by the injection type and flow rate of additive oxygen gas in atmospheric pressure helium plasma jet. The plasma characteristics such as plume length, electric current and optical emission spectra (OES) were measured at different flow rates of additive oxygen to helium. The plasma plume length and total current decreased with an increase in the additive oxygen flow rate. The electron excitation temperature estimated by the Boltzmann plot from several excited helium emission lines increased slightly with the additive oxygen flow. The oxygen atom density in the gas phase estimated by actinometry utilizing argon was observed to increase with the additive oxygen flow. The concentration of intracellular reactive oxygen species (ROS) measured by fluorescence assay was found to be not exactly proportional to that of extracellular ROS (measured by OES), but both correlated considerably. It was also observed that the expression levels of p53 and the phospho-p53 were enhanced in the presence of additive oxygen flow compared with those from the pure helium plasma treatment. PMID:25319447

  11. Effect of additive oxygen gas on cellular response of lung cancer cells induced by atmospheric pressure helium plasma jet

    NASA Astrophysics Data System (ADS)

    Joh, Hea Min; Choi, Ji Ye; Kim, Sun Ja; Chung, T. H.; Kang, Tae-Hong

    2014-10-01

    The atmospheric pressure helium plasma jet driven by pulsed dc voltage was utilized to treat human lung cancer cells in vitro. The properties of plasma plume were adjusted by the injection type and flow rate of additive oxygen gas in atmospheric pressure helium plasma jet. The plasma characteristics such as plume length, electric current and optical emission spectra (OES) were measured at different flow rates of additive oxygen to helium. The plasma plume length and total current decreased with an increase in the additive oxygen flow rate. The electron excitation temperature estimated by the Boltzmann plot from several excited helium emission lines increased slightly with the additive oxygen flow. The oxygen atom density in the gas phase estimated by actinometry utilizing argon was observed to increase with the additive oxygen flow. The concentration of intracellular reactive oxygen species (ROS) measured by fluorescence assay was found to be not exactly proportional to that of extracellular ROS (measured by OES), but both correlated considerably. It was also observed that the expression levels of p53 and the phospho-p53 were enhanced in the presence of additive oxygen flow compared with those from the pure helium plasma treatment.

  12. Effect of additive oxygen gas on cellular response of lung cancer cells induced by atmospheric pressure helium plasma jet

    PubMed Central

    Joh, Hea Min; Choi, Ji Ye; Kim, Sun Ja; Chung, T. H.; Kang, Tae-Hong

    2014-01-01

    The atmospheric pressure helium plasma jet driven by pulsed dc voltage was utilized to treat human lung cancer cells in vitro. The properties of plasma plume were adjusted by the injection type and flow rate of additive oxygen gas in atmospheric pressure helium plasma jet. The plasma characteristics such as plume length, electric current and optical emission spectra (OES) were measured at different flow rates of additive oxygen to helium. The plasma plume length and total current decreased with an increase in the additive oxygen flow rate. The electron excitation temperature estimated by the Boltzmann plot from several excited helium emission lines increased slightly with the additive oxygen flow. The oxygen atom density in the gas phase estimated by actinometry utilizing argon was observed to increase with the additive oxygen flow. The concentration of intracellular reactive oxygen species (ROS) measured by fluorescence assay was found to be not exactly proportional to that of extracellular ROS (measured by OES), but both correlated considerably. It was also observed that the expression levels of p53 and the phospho-p53 were enhanced in the presence of additive oxygen flow compared with those from the pure helium plasma treatment. PMID:25319447

  13. Modulations of the plasma uniformity by low frequency sources in a large-area dual frequency inductively coupled plasma based on fluid simulations

    SciTech Connect

    Sun, Xiao-Yan; Zhang, Yu-Ru; Li, Xue-Chun; Wang, You-Nian

    2015-05-15

    As the wafer size increases, dual frequency (DF) inductively coupled plasma (ICP) sources have been proposed as an effective method to achieve large-area uniform plasma processing. A two-dimensional (2D) self-consistent fluid model, combined with an electromagnetic module, has been employed to investigate the influence of the low frequency (LF) source on the plasma radial uniformity in an argon DF discharge. When the DF antenna current is fixed at 10 A, the bulk plasma density decreases significantly with the LF due to the less efficient heating, and the best radial uniformity is obtained at 3.39 MHz. As the LF decreases to 2.26 MHz, the plasma density is characterized by an edge-high profile, and meanwhile the maximum of the electron temperature appears below the outer two-turn coil. Moreover, the axial ion flux at 3.39 MHz is rather uniform in the center region except at the radial edge of the substrate, where a higher ion flux is observed. When the inner five-turn coil frequency is fixed at 2.26 MHz, the plasma density profiles shift from edge-high over uniform to center-high as the LF coil current increases from 6 A to 18 A, and the best plasma uniformity is obtained at 14 A. In addition, the maximum of the electron temperature becomes lower with a second peak appears at the radial position of r = 9 cm at 18 A.

  14. Observation of inactivation of Bacillus sbtilis spores under exposures of oxygen added argon atmospheric pressure plasma jet

    NASA Astrophysics Data System (ADS)

    Shen, Jie; Cheng, Cheng; Zhao, Ying; Xiao, Dezhi; Lan, Yan; Xie, Hongbing; Cheng, Junli; Meng, Yuedong; Li, Jiangang; Chu, Paul K.

    2014-11-01

    The inactivation of Bacillus subtilis spores by an Ar plasma jet mixed with different amounts of oxygen is reported. 5.8 × 106 B. subtilis spores are sterilized by an Ar/O2 (8.7%) plasma jet after exposure for 2 min. The densities of ozone and oxygen radicals in the Ar/O2 plasma jet increase with oxygen concentration and are estimated by optical spectroscopy diagnostic. The malondialdehyde (MDA) test shows that oxygen radicals participate in bacterial inactivation. Scanning electron microscopy (SEM) reveals the deformation of the spore shape due to etching by oxygen radicals and the dependence of the degree of deformation on the density of oxygen radicals.

  15. Oxygen transport through polyethylene terephthalate (PET) coated with plasma-polymerized acetylene at atmospheric pressure

    NASA Astrophysics Data System (ADS)

    Wemlinger, Erik; Pedrow, Patrick; Garcia-Pérez, Manuel; Sablani, Shyam

    2011-10-01

    Moser et al. have shown that oxygen transport through polyethyleneterephthalate (PET) is reduced by a factor of up to 120 when, at reduced pressure, hydrogenated amorphous carbon film with thickness less than 100 nm is applied to the PET substrate. Our work includes using atmospheric pressure cold plasma to grow a plasma-polymerized acetylene film on PET substrate and measuring reductions in oxygen transport. The reactor utilizes corona discharges and is operated at 60 Hz with a maximum voltage of 10 kV RMS. Corona streamers emanate from an array of needles with an average radius of curvature of 50 μm. The reactor utilizes a cylindrical reaction chamber with a vertical orientation such that argon carrier gas and acetylene precursor gas are introduced at the top then pass through the cold plasma activation zone and then through a grounded stainless steel mesh. Acetylene radicals are incident on the PET substrate and form plasma-polymerized acetylene film. Moser et al. have shown that oxygen transport through polyethyleneterephthalate (PET) is reduced by a factor of up to 120 when, at reduced pressure, hydrogenated amorphous carbon film with thickness less than 100 nm is applied to the PET substrate. Our work includes using atmospheric pressure cold plasma to grow a plasma-polymerized acetylene film on PET substrate and measuring reductions in oxygen transport. The reactor utilizes corona discharges and is operated at 60 Hz with a maximum voltage of 10 kV RMS. Corona streamers emanate from an array of needles with an average radius of curvature of 50 μm. The reactor utilizes a cylindrical reaction chamber with a vertical orientation such that argon carrier gas and acetylene precursor gas are introduced at the top then pass through the cold plasma activation zone and then through a grounded stainless steel mesh. Acetylene radicals are incident on the PET substrate and form plasma-polymerized acetylene film. E.M. Moser, R. Urech, E. Hack, H. Künzli, E. Müller, Thin

  16. Cleaning of diamond nanoindentation probes with oxygen plasma and carbon dioxide snow

    SciTech Connect

    Morris, Dylan J.

    2009-12-15

    Diamond nanoindentation probes may perform thousands of indentations over years of service life. There is a broad agreement that the probes need frequent cleaning, but techniques for doing so are mostly anecdotes shared between experimentalists. In preparation for the measurement of the shape of a nanoindentation probe by a scanning probe microscope, cleaning by carbon dioxide snow jets and oxygen plasma was investigated. Repeated indentation on a thumbprint-contaminated surface formed a compound that was very resistant to removal by solvents, CO{sub 2} snow, and plasma. CO{sub 2} snow cleaning is found to be a generally effective cleaning procedure.

  17. Characteristics of dual-frequency capacitively coupled SF6/O2 plasma and plasma texturing of multi-crystalline silicon

    NASA Astrophysics Data System (ADS)

    Xu, Dong-Sheng; Zou, Shuai; Xin, Yu; Su, Xiao-Dong; Wang, Xu-Sheng

    2014-06-01

    Due to it being environmentally friendly, much attention has been paid to the dry plasma texturing technique serving as an alternative candidate for multicrystalline silicon (mc-Si) surface texturing. In this paper, capacitively coupled plasma (CCP) driven by a dual frequency (DF) of 40.68 MHz and 13.56 MHz is first used for plasma texturing of mc-Si with SF6/O2 gas mixture. Using a hairpin resonant probe and optical emission techniques, DF-CCP characteristics and their influence on mc-silicon surface plasma texturing are investigated at different flow rate ratios, pressures, and radio-frequency (RF) input powers. Experimental results show that suitable plasma texturing of mc-silicon occurs only in a narrow range of plasma parameters, where electron density ne must be larger than 6.3 × 109 cm-3 and the spectral intensity ratio of the F atom to that of the O atom ([F]/[O]) in the plasma must be between 0.8 and 0.3. Out of this range, no cone-like structure is formed on the mc-silicon surface. In our experiments, the lowest reflectance of about 7.3% for mc-silicon surface texturing is obtained at an [F]/[O] of 0.5 and ne of 6.9 × 109 cm-3.

  18. Synthesis of silicon nitride particles in pulsed radio frequency plasmas

    SciTech Connect

    Buss, R.J.; Babu, S.V.

    1996-03-01

    Silicon nitride (hydrogenated) particles are synthesized using a pulsed 13.56 MHz glow discharge. The plasma is modulated with a square-wave on/off cycle of varying period to study the growth kinetics. {ital In} {ital situ} laser light scattering and {ital ex} {ital situ} particle analysis are used to study the nucleation and growth. For SiH{sub 4}/Ar and SiH{sub 4}/NH{sub 3} plasmas, an initial very rapid growth phase is followed by slower growth, approaching the rate of thin film deposition on adjacent flat surfaces. The average particle size can be controlled in the 10{endash}100 nm range by adjusting the plasma-on time. The size dispersion of the particles is large and is consistent with a process of continuous nucleation during the plasma-on period. The large polydispersity is also reported for silicon particles from silane and differs from that reported in other laboratories. The silicon nitride particle morphology is compared to that of silicon and silicon carbide particles generated by the same technique. Whereas Si particles appear as rough clusters of smaller subunits, the SiC particles are smooth spheres, and the Si{sub 3}N{sub 4} particles are smooth but nonspherical. Postplasma oxidation kinetics of the particles are studied with Fourier transform infrared spectra and are consistent with a hydrolysis mechanism proposed in earlier work with continuous plasmas. Heat treatment of the powder in an ammonia atmosphere results in the elimination of hydrogen, rendering the silicon nitride resistant to atmospheric oxidation. {copyright} {ital 1996 American Vacuum Society}

  19. Self-consistent simulation of high-frequency driven plasma sheaths

    NASA Astrophysics Data System (ADS)

    Shihab, Mohammed; Eremin, Denis; Mussenbrock, Thomas; Brinkmann, Ralf

    2011-10-01

    Low pressure capacitively coupled plasmas are widely used in plasma processing and microelectronics industry. Understanding the dynamics of the boundary sheath is a fundamental problem. It controls the energy and angular distribution of ions bombarding the electrode, which in turn affects the surface reaction rate and the profile of microscopic features. In this contribution, we investigate the dynamics of plasma boundary sheaths by means of a kinetic self-consistent model, which is able to resolve the ion dynamics. Asymmetric sheath dynamics is observed for the intermediate RF regime, i.e., in the regime where the ion plasma frequency is equal to the driving frequency. The ion inertia causes an additional phase difference between the expansion and the contraction phase of the plasma sheath and an asymmetry for the ion energy distribution bimodal shape. A comparison with experimental results and particle in cell simulations is performed. Low pressure capacitively coupled plasmas are widely used in plasma processing and microelectronics industry. Understanding the dynamics of the boundary sheath is a fundamental problem. It controls the energy and angular distribution of ions bombarding the electrode, which in turn affects the surface reaction rate and the profile of microscopic features. In this contribution, we investigate the dynamics of plasma boundary sheaths by means of a kinetic self-consistent model, which is able to resolve the ion dynamics. Asymmetric sheath dynamics is observed for the intermediate RF regime, i.e., in the regime where the ion plasma frequency is equal to the driving frequency. The ion inertia causes an additional phase difference between the expansion and the contraction phase of the plasma sheath and an asymmetry for the ion energy distribution bimodal shape. A comparison with experimental results and particle in cell simulations is performed. The financial support from the Federal Ministry of Education and Research within the frame of

  20. Phase-shift effect in capacitively coupled plasmas with two radio frequency or very high frequency sources

    SciTech Connect

    Xu Xiang; Zhao Shuxia; Zhang Yuru; Wang Younian

    2010-08-15

    A two-dimensional fluid model was built to study the argon discharge in a capacitively coupled plasma reactor and the full set of Maxwell equations is included in the model to understand the electromagnetic effect in the capacitive discharge. Two electrical sources are applied to the top and bottom electrodes in our simulations and the phase-shift effect is focused on. We distinguish the difference of the phase-shift effect on the plasma uniformity in the traditional radio frequency discharge and in the very high frequency discharge where the standing wave effect dominates. It is found that in the discharges with frequency 13.56 MHz, the control of phase difference can less the influence of the electrostatic edge effect, and it gets the best radial uniformity of plasma density at the phase difference {pi}. But in the very high frequency discharges, the standing wave effect plays an important role. The standing wave effect can be counteracted at the phase difference 0, and be enhanced at the phase difference {pi}. The standing wave effect and the edge effect are balanced at some phase-shift value between 0 and {pi}, which is determined by discharge parameters.

  1. Fast frequency-step-tunable gyrotrons for plasma heating and fusion diagnostics

    SciTech Connect

    Dumbrajs, O.; Heikkinen, J.

    1994-11-01

    Usefulness of frequency tunable sources for plasma heating and fusion diagnostics is studied. Applicability of fast frequency-step-tunable gyrotrons for these purposes is examined. A gyrotron based on a coaxial cavity with impedance rod is considered as an example.

  2. The effect of dielectric top lids on materials processing in a low frequency inductively coupled plasma (LF-ICP) reactor

    NASA Astrophysics Data System (ADS)

    Lim, J. W. M.; Chan, C. S.; Xu, L.; Xu, S.

    2014-08-01

    The advent of the plasma revolution began in the 1970's with the exploitation of plasma sources for anisotropic etching and processing of materials. In recent years, plasma processing has gained popularity, with research institutions adopting projects in the field and industries implementing dry processing in their production lines. The advantages of utilizing plasma sources would be uniform processing over a large exposed surface area, and the reduction of toxic emissions. This leads to reduced costs borne by manufacturers which could be passed down as consumer savings, and a reduction in negative environmental impacts. Yet, one constraint that plagues the industry would be the control of contaminants in a plasma reactor which becomes evident when reactions are conducted in a clean vacuum environment. In this work, amorphous silicon (a-Si) thin films were grown on glass substrates in a low frequency inductively coupled plasma (LF-ICP) reactor with a top lid made of quartz. Even though the chamber was kept at high vacuum ( 10-4 Pa), it was evident through secondary ion mass spectroscopy (SIMS) and Fourier-transform infra-red spectroscopy (FTIR) that oxygen contaminants were present. With the aid of optical emission spectroscopy (OES) the contaminant species were identified. The design of the LF-ICP reactor was then modified to incorporate an Alumina (Al2O3) lid. Results indicate that there were reduced amounts of contaminants present in the reactor, and that an added benefit of increased power transfer to the plasma, improving deposition rate of thin films was realized. The results of this study is conclusive in showing that Al2O3 is a good alternative as a top-lid of an LF-ICP reactor, and offers industries a solution in improving quality and rate of growth of thin films.

  3. Oxygen plasma flow properties deduced from laser-induced fluorescence and probe measurements.

    PubMed

    Löhle, Stefan; Eichhorn, Christoph; Steinbeck, Andreas; Lein, Sebastian; Herdrich, Georg; Röser, Hans-Peter; Auweter-Kurtz, Monika

    2008-04-10

    Estimation of the local dissociation degree and the local mass-specific enthalpy of a pure oxygen plasma flow determined mainly from laser-induced fluorescence measurements are reported. Measurements have been conducted for several generator parameters in an inductively heated plasma wind tunnel. Additional probe measurements of total pressure together with the deduced translational temperature are used to estimate the local mass-specific enthalpy. For a reference condition, full dissociation has been measured. The measured translational temperature of atomic oxygen for this condition is T = 3500 K. Subsequently, the local mass-specific enthalpy has been derived using these local density and temperature measurements. For the reference condition the estimated value of h = 27 MJ/kg is in good agreement with the probe measurements and results from diode laser absorption spectroscopy. PMID:18404183

  4. Photooxidation of plasma polymerized polydimethylsiloxane film by 172 nm vacuum ultraviolet light irradiation in dilute oxygen

    NASA Astrophysics Data System (ADS)

    Ichikawa, S.

    2006-08-01

    Plasma polymerized polydimethylsiloxane films irradiated under different partial pressures of oxygen with a 172nm vacuum ultraviolet light were investigated in order to clarify the roles of molecular oxygen and photons in photooxidation. The thickness, densities, surface roughness, elemental compositions, and molecular structures of the irradiated and unirradiated films were examined by using glazing incidence x-ray reflectivity, Rutherford backscattering, infrared, and x-ray absorption (XAS) spectroscopies. Photooxidation is hardly promoted by irradiation in a high vacuum of 1×10-4Pa, though photodesorption of the methyl group and formation of Si-H bonds were observed. Silica films thicker than 140nm were formed at room temperature by irradiating them in low pressure oxygen gases. The degree of oxidation was smaller for the oxygen pressure of 10kPa than for 83Pa. Si K-edge XAS was performed to clarify the change of coordination environment of silicon by photooxidation in dilute oxygen flow containing less than 5ppm of molecular oxygen.

  5. Novel plasma-based frequency upshift methods for short pulse lasers

    SciTech Connect

    Wilks, S.C. ); Dawson, J.M.; Mori, W.B. . Dept. of Physics)

    1990-06-04

    We discuss various novel methods of frequency upshifting short ({le} 1 picosecond) pulses of laser light. All of these methods make use of either the sudden creation of a plasma or relativistic plasma waves. The first method discussed is known as photon acceleration. This method makes use of the fact that a laser pulse moving in a plasma can be thought of as a packet of photons, each possessing an effective mass of m{sub {gamma}} = {h bar}{omega}{sub pe}/c{sup 2} and moving with the group velocity of the laser pulse. These photons experience a force acting on them when in the presence of a gradient in the plasma density. By using a relativistic plasma wave (i.e., a moving density gradient) traveling with the photons, the energy of the photons (thus the frequency) can be continuously increased. We then discuss the sudden creation of a plasma in a region where there exists an electromagnetic wave. This results in a frequency shift of the wave. A similar method is the creation of an ionization front moving near the speed of light, whereby the interaction of this plasma front with an EM wave also results in a frequency upshift of the original wave. 21 refs.

  6. Spectral evolution of two-dimensional kinetic plasma turbulence in the wavenumber-frequency domain

    SciTech Connect

    Comişel, H.; Verscharen, D.; Narita, Y.; Motschmann, U.

    2013-09-15

    We present a method for studying the evolution of plasma turbulence by tracking dispersion relations in the energy spectrum in the wavenumber-frequency domain. We apply hybrid plasma simulations in a simplified two-dimensional geometry to demonstrate our method and its applicability to plasma turbulence in the ion kinetic regime. We identify four dispersion relations: ion-Bernstein waves, oblique whistler waves, oblique Alfvén/ion-cyclotron waves, and a zero-frequency mode. The energy partition and frequency broadening are evaluated for these modes. The method allows us to determine the evolution of decaying plasma turbulence in our restricted geometry and shows that it cascades along the dispersion relations during the early phase with an increasing broadening around the dispersion relations.

  7. Propagation characteristics of a Gaussian laser beam in plasma with modulated collision frequency

    NASA Astrophysics Data System (ADS)

    Wang, Ying; Yuan, Chengxun; Zhou, Zhongxiang; Gao, Ruilin; Li, Lei; Du, Yanwei

    2012-08-01

    The propagation characteristics of a Gaussian laser beam in cold plasma with the electron collision frequency modulated by laser intensity are presented. The nonlinear dynamics of the ponderomotive force, which induce nonlinear self-focusing as opposed to spatial diffraction, are considered. The effective dielectric function of the Drude model and complex eikonal function are adopted in deriving coupled differential equations of the varying laser beam parameters. In the framework of ponderomotive nonlinearity, the frequency of electron collision in plasmas, which is proportional to the spatial electron density, is strongly interrelated with the laser beam propagation characteristics. Hence, the propagation properties of the laser beam and the modulated electron collision frequency distribution in plasma were studied and explained in depth. Employing this self-consistent method, the obtained simulation results approach practical conditions, which is of significance to the study of laser-plasma interactions.

  8. High frequency operation of a hot filament cathode for a magnetized plasma ion source

    SciTech Connect

    Takahashi, Y.; Miyamoto, N.; Kasuya, T.; Wada, M.

    2012-02-15

    A tungsten filament cathode has been operated with an ac heating current to excite a plasma in a linear magnetic field. Both the discharge current and the ion saturation current in plasma near the extraction hole of the ion source exhibited fluctuations. The discharge current fluctuated with the amplitude less than 2% of the average, and the frequency two times the frequency of the heating current. Fluctuation amplitude of the ion saturation current was about 10% of the average, while the frequency was the same as that of the heating current. The ac operation has prolonged the lifetime of a hot filament cathode by about 50%.

  9. Influence of finite geometrical asymmetry of the electrodes in capacitively coupled radio frequency plasma

    SciTech Connect

    Bora, B. Soto, L.

    2014-08-15

    Capacitively coupled radio frequency (CCRF) plasmas are widely studied in last decades due to the versatile applicability of energetic ions, chemically active species, radicals, and also energetic neutral species in many material processing fields including microelectronics, aerospace, and biology. A dc self-bias is known to generate naturally in geometrically asymmetric CCRF plasma because of the difference in electrode sizes known as geometrical asymmetry of the electrodes in order to compensate electron and ion flux to each electrode within one rf period. The plasma series resonance effect is also come into play due to the geometrical asymmetry and excited several harmonics of the fundamental in low pressure CCRF plasma. In this work, a 13.56 MHz CCRF plasma is studied on the based on the nonlinear global model of asymmetric CCRF discharge to understand the influences of finite geometrical asymmetry of the electrodes in terms of generation of dc self-bias and plasma heating. The nonlinear global model on asymmetric discharge has been modified by considering the sheath at the grounded electrode to taking account the finite geometrical asymmetry of the electrodes. The ion density inside both the sheaths has been taken into account by incorporating the steady-state fluid equations for ions considering that the applied rf frequency is higher than the typical ion plasma frequency. Details results on the influences of geometrical asymmetry on the generation of dc self-bias and plasma heating are discussed.

  10. Radio-frequency plasma chemical vapor deposition growth of diamond

    NASA Technical Reports Server (NTRS)

    Meyer, Duane E.; Dillon, Rodney O.; Woollam, John A.

    1989-01-01

    Plasma chemical vapor deposition (CVD) at 13.56 MHz has been used to produce diamond particles in two different inductively coupled systems with a mixture of methane and hydrogen. The effect of a diamondlike carbon (DLC) overcoating on silicon, niobium, and stainless-steel substrates has been investigated and in the case of silicon has been found to enhance particle formation as compared to uncoated polished silicon. In addition the use of carbon monoxide in hydrogen has been found to produce well-defined individual faceted particles as well as polycrystalline films on quartz and DLC coated silicon substrates. Plasma CVD is a competitive approach to production of diamond films. It has the advantage over microwave systems of being easily scaled to large volume and high power.

  11. Breakdown voltages for discharges initiated from plasma pulses produced by high-frequency excimer lasers

    SciTech Connect

    Yamaura, Michiteru

    2006-06-19

    The triggering ability under the different electric field was investigated using a KrF excimer laser with a high repetition rate of kilohertz order. Measurements were made of the magnitude of impulse voltages that were required to initiate a discharge from plasmas produced by a high-frequency excimer laser. Breakdown voltages were found to be reduced by 50% through the production of plasmas in the discharge gap by a high-frequency excimer laser. However, under direct-current electric field, triggering ability decreased drastically due to low plasma density. It is considered that such laser operation applied for laser-triggered lightning due to the produced location of plasma channel is formed under the impulse electric field since an electric field of the location drastically reduces temporary when the downward leader from thunderclouds propagates to the plasma channel.

  12. Argon–oxygen dc magnetron discharge plasma probed with ion acoustic waves

    SciTech Connect

    Saikia, Partha Saikia, Bipul Kumar; Goswami, Kalyan Sindhu; Phukan, Arindam

    2014-05-15

    The precise determination of the relative concentration of negative ions is very important for the optimization of magnetron sputtering processes, especially for those undertaken in a multicomponent background produced by adding electronegative gases, such as oxygen, to the discharge. The temporal behavior of an ion acoustic wave excited from a stainless steel grid inside the plasma chamber is used to determine the relative negative ion concentration in the magnetron discharge plasma. The phase velocity of the ion acoustic wave in the presence of negative ions is found to be faster than in a pure argon plasma, and the phase velocity increases with the oxygen partial pressure. Optical emission spectroscopy further confirms the increase in the oxygen negative ion density, along with a decrease in the argon positive ion density under the same discharge conditions. The relative negative ion concentration values measured by ion acoustic waves are compared with those measured by a single Langmuir probe, and a similarity in the results obtained by both techniques is observed.

  13. Surface monofunctionalized polymethyl pentene hollow fiber membranes by plasma treatment and hemocompatibility modification for membrane oxygenators

    NASA Astrophysics Data System (ADS)

    Huang, Xin; Wang, Weiping; Zheng, Zhi; Fan, Wenling; Mao, Chun; Shi, Jialiang; Li, Lei

    2016-01-01

    The hemocompatibility of polymethyl pentene (PMP) hollow fiber membranes (HFMs) was improved through surface modification for membrane oxygenator applications. The modification was performed stepwise with the following: (1) oxygen plasma treatment, (2) functionalization of monosort hydroxyl groups through NaBH4 reduction, and (3) grafting 2-methacryloyloxyethyl phosphorylcholine (MPC) or heparin. SEM, ATR-FTIR, and XPS analyses were conducted to confirm successful grafting during the modification. The hemocompatibility of PMP HFMs was analyzed and compared through protein adsorption, platelet adhesion, and coagulation tests. Pure CO2 and O2 permeation rates, as well as in vitro gas exchange rates, were determined to evaluate the mass transfer properties of PMP HFMs. SEM results showed that different nanofibril topographies were introduced on the HFM surface. ATR-FTIR and XPS spectra indicated the presence of functionalization of monosort hydroxyl group and the grafting of MPC and heparin. Hemocompatibility evaluation results showed that the modified PMP HFMs presented optimal hemocompatibility compared with pristine HFMs. Gas permeation results revealed that gas permeation flux increased in the modified HFMs because of dense surface etching during the plasma treatment. The results of in vitro gas exchange rates showed that all modified PMP HFMs presented decreased gas exchange rates because of potential surface fluid wetting. The proposed strategy exhibits a potential for fabricating membrane oxygenators for biomedical applications to prevent coagulation formation and alter plasma-induced surface topology and composition.

  14. Electron properties and air mixing in radio frequency driven argon plasma jets at atmospheric pressure

    SciTech Connect

    Gessel, Bram van; Bruggeman, Peter; Brandenburg, Ronny

    2013-08-05

    A time modulated radio frequency (RF) plasma jet operated with an Ar mixture is investigated by measuring the electron density and electron temperature using Thomson scattering. The measurements have been performed spatially resolved for two different electrode configurations and as a function of the plasma dissipated power and air concentration admixed to the Ar. Time resolved measurements of electron densities and temperatures during the RF cycle and after plasma power switch-off are presented. Furthermore, the influence of the plasma on the air entrainment into the effluent is studied using Raman scattering.

  15. Magnetoresistive polyaniline-silicon carbide metacomposites: plasma frequency determination and high magnetic field sensitivity.

    PubMed

    Gu, Hongbo; Guo, Jiang; Khan, Mojammel Alam; Young, David P; Shen, T D; Wei, Suying; Guo, Zhanhu

    2016-07-20

    The Drude model modified by Debye relaxation time was introduced to determine the plasma frequency (ωp) in the surface initiated polymerization (SIP) synthesized β-silicon carbide (β-SiC)/polyaniline (PANI) metacomposites. The calculated plasma frequency for these metacomposites with different loadings of β-SiC nanoparticles was ranging from 6.11 × 10(4) to 1.53 × 10(5) rad s(-1). The relationship between the negative permittivity and plasma frequency indicates the existence of switching frequency, at which the permittivity was changed from negative to positive. More interestingly, the synthesized non-magnetic metacomposites, observed to follow the 3-dimensional (3-D) Mott variable range hopping (VRH) electrical conduction mechanism, demonstrated high positive magnetoresistance (MR) values of up to 57.48% and high MR sensitivity at low magnetic field regimes. PMID:27386820

  16. Self-consistent modeling of radio-frequency plasma generation in stellarators

    SciTech Connect

    Moiseenko, V. E. Stadnik, Yu. S.; Lysoivan, A. I.; Korovin, V. B.

    2013-11-15

    A self-consistent model of radio-frequency (RF) plasma generation in stellarators in the ion cyclotron frequency range is described. The model includes equations for the particle and energy balance and boundary conditions for Maxwell’s equations. The equation of charged particle balance takes into account the influx of particles due to ionization and their loss via diffusion and convection. The equation of electron energy balance takes into account the RF heating power source, as well as energy losses due to the excitation and electron-impact ionization of gas atoms, energy exchange via Coulomb collisions, and plasma heat conduction. The deposited RF power is calculated by solving the boundary problem for Maxwell’s equations. When describing the dissipation of the energy of the RF field, collisional absorption and Landau damping are taken into account. At each time step, Maxwell’s equations are solved for the current profiles of the plasma density and plasma temperature. The calculations are performed for a cylindrical plasma. The plasma is assumed to be axisymmetric and homogeneous along the plasma column. The system of balance equations is solved using the Crank-Nicholson scheme. Maxwell’s equations are solved in a one-dimensional approximation by using the Fourier transformation along the azimuthal and longitudinal coordinates. Results of simulations of RF plasma generation in the Uragan-2M stellarator by using a frame antenna operating at frequencies lower than the ion cyclotron frequency are presented. The calculations show that the slow wave generated by the antenna is efficiently absorbed at the periphery of the plasma column, due to which only a small fraction of the input power reaches the confinement region. As a result, the temperature on the axis of the plasma column remains low, whereas at the periphery it is substantially higher. This leads to strong absorption of the RF field at the periphery via the Landau mechanism.

  17. Comparison of CO2 and oxygen DC submerged thermal plasmas for decomposition of carboxylic acid in aqueous solution

    NASA Astrophysics Data System (ADS)

    Safa, S.; Hekmat-Ardakan, A.; Soucy, G.

    2014-11-01

    The feasibility of the carboxylic acid decomposition with two different direct current (DC) thermal plasma torches was investigated. An oxygen DC submerged thermal plasma torch and a newly designed submerged DC plasma torch operating with a mixture of carbon dioxide and methane (CO2/CH4) were used. Sebacic acid was selected as a representative of pollutants in the most wastewater produced by chemical process industries. The effect of different operational conditions including treatment time, the reactor pressure as well as the role of oxidizing agents such as (H2O2) were investigated on the decomposition rate of sebacic acid. Concentration of sebacic acid was quantified by Ion Chromatography/Mass Spectrometry (IC/MS). The oxygen plasma showed higher decomposition rate in basic medium. Adding H2O2 into aqueous solution enhanced the sebacic acid decomposition rate with the CO2/CH4 plasma up to the same decomposition rate of the oxygen plasma. Increasing the pressure also increased the decomposition rate for both plasmas with an increase twice higher for the CO2/CH4 plasma than that of the oxygen plasma. This work therefore presents the conditions in which these plasmas can provide the same decomposition rate for contaminants in aqueous solution.

  18. Particle formation and its control in dual frequency plasma etching reactors

    SciTech Connect

    Kim, Munsu; Cheong, Hee-Woon; Whang, Ki-Woong

    2015-07-15

    The behavior of a particle cloud in plasma etching reactors at the moment when radio frequency (RF) power changes, that is, turning off and transition steps, was observed using the laser-light-scattering method. Two types of reactors, dual-frequency capacitively coupled plasma (CCP) and the hybrid CCP/inductively coupled plasma (ICP), were set up for experiments. In the hybrid CCP/ICP reactor (hereafter ICP reactor), the position and shape of the cloud were strongly dependent on the RF frequency. The particle cloud becomes larger and approaches the electrode as the RF frequency increases. By turning the lower frequency power off later with a small delay time, the particle cloud is made to move away from the electrode. Maintaining lower frequency RF power only was also helpful to reduce the particle cloud size during this transition step. In the ICP reactor, a sufficient bias power is necessary to make a particle trap appear. A similar particle cloud to that in the CCP reactor was observed around the sheath region of the lower electrode. The authors can also use the low-frequency effect to move the particle cloud away from the substrate holder if two or more bias powers are applied to the substrate holder. The dependence of the particle behavior on the RF frequencies suggests that choosing the proper frequency at the right moment during RF power changes can reduce particle contamination effectively.

  19. Two-photon absorption laser induced fluorescence measurement of atomic oxygen density in an atmospheric pressure air plasma jet

    NASA Astrophysics Data System (ADS)

    Conway, J.; Gogna, G. S.; Gaman, C.; Turner, M. M.; Daniels, S.

    2016-08-01

    Atomic oxygen number density [O] is measured in an air atmospheric pressure plasma jet (APPJ) using two-photon absorption laser induced fluorescence (TALIF). Gas flow is fixed at 8 slpm, the RF power coupled into the plasma jet varied between 5 W and 20 W, and the resulting changes in atomic oxygen density measured. Photolysis of molecular oxygen is employed to allow in situ calibration of the TALIF system. During calibration, O2 photo-dissociation and two-photon excitation of the resulting oxygen atoms are achieved within the same laser pulse. The atomic oxygen density produced by photolysis is time varying and spatially non-uniform which needs to be corrected for to calibrate the TALIF system for measurement of atomic oxygen density in plasma. Knowledge of the laser pulse intensity I 0(t), wavelength, and focal spot size allows correction factors to be determined using a rate equation model. Atomic oxygen is used for calibration and measurement, so the laser intensity can be increased outside the TALIF quadratic laser power dependence region without affecting the calibration reliability as the laser power dependence will still be the same for both. The atomic O density results obtained are not directly benchmarked against other known density measurement techniques. The results show that the plasma jet atomic oxygen content increases as the RF power coupled into the plasma increases.

  20. Morphological evolution of self-deposition Bi2Se3 nanosheets by oxygen plasma treatment

    PubMed Central

    Jia, Guozhi; Wu, Zengna; Wang, Peng; Yao, Jianghong; Chang, Kai

    2016-01-01

    Bi2Se3 nanosheets were successfully synthesized by a microwave-assisted approach in the presence of polyvinylpyrroli done at a temperature of 180 °C for 2 h. The thin film was prepared on a silicon wafer via a self-deposition process in a Bi2Se3 nanosheet ink solution using the evaporation-induced self-assembly method. The structure and morphology of the obtained products were characterized by X-ray diffraction, scanning electron microscopy (SEM), x-ray photoelectron spectroscopy, and Raman spectroscopy. The highly uniform Bi2Se3 particles could be formed by controlling the oxygen plasma treatment time. After the plasma pretreatment from 10 to 20 s, the surface of Bi2Se3 film evolved from the worm-like structure to particles. The highly uniform thin film was formed on further increasing the plasma treatment time, which is consistent with the observed SEM results. Several important processes can result in the morphological evolution of Bi2Se3 nanosheets: (1) formation of Bi2Se3 oxide layer; (2) self-assembly of oxide nanoparticles under the action of high-energy oxygen plasma; and (3) electrostatic interaction and etching mechanism. PMID:26923325

  1. Morphological evolution of self-deposition Bi2Se3 nanosheets by oxygen plasma treatment

    NASA Astrophysics Data System (ADS)

    Jia, Guozhi; Wu, Zengna; Wang, Peng; Yao, Jianghong; Chang, Kai

    2016-02-01

    Bi2Se3 nanosheets were successfully synthesized by a microwave-assisted approach in the presence of polyvinylpyrroli done at a temperature of 180 °C for 2 h. The thin film was prepared on a silicon wafer via a self-deposition process in a Bi2Se3 nanosheet ink solution using the evaporation-induced self-assembly method. The structure and morphology of the obtained products were characterized by X-ray diffraction, scanning electron microscopy (SEM), x-ray photoelectron spectroscopy, and Raman spectroscopy. The highly uniform Bi2Se3 particles could be formed by controlling the oxygen plasma treatment time. After the plasma pretreatment from 10 to 20 s, the surface of Bi2Se3 film evolved from the worm-like structure to particles. The highly uniform thin film was formed on further increasing the plasma treatment time, which is consistent with the observed SEM results. Several important processes can result in the morphological evolution of Bi2Se3 nanosheets: (1) formation of Bi2Se3 oxide layer; (2) self-assembly of oxide nanoparticles under the action of high-energy oxygen plasma; and (3) electrostatic interaction and etching mechanism.

  2. Morphological evolution of self-deposition Bi2Se3 nanosheets by oxygen plasma treatment.

    PubMed

    Jia, Guozhi; Wu, Zengna; Wang, Peng; Yao, Jianghong; Chang, Kai

    2016-01-01

    Bi2Se3 nanosheets were successfully synthesized by a microwave-assisted approach in the presence of polyvinylpyrroli done at a temperature of 180 °C for 2 h. The thin film was prepared on a silicon wafer via a self-deposition process in a Bi2Se3 nanosheet ink solution using the evaporation-induced self-assembly method. The structure and morphology of the obtained products were characterized by X-ray diffraction, scanning electron microscopy (SEM), x-ray photoelectron spectroscopy, and Raman spectroscopy. The highly uniform Bi2Se3 particles could be formed by controlling the oxygen plasma treatment time. After the plasma pretreatment from 10 to 20 s, the surface of Bi2Se3 film evolved from the worm-like structure to particles. The highly uniform thin film was formed on further increasing the plasma treatment time, which is consistent with the observed SEM results. Several important processes can result in the morphological evolution of Bi2Se3 nanosheets: (1) formation of Bi2Se3 oxide layer; (2) self-assembly of oxide nanoparticles under the action of high-energy oxygen plasma; and (3) electrostatic interaction and etching mechanism. PMID:26923325

  3. Modelling chemical reactions in dc plasma inside oxygen bubbles in water

    NASA Astrophysics Data System (ADS)

    Takeuchi, N.; Ishii, Y.; Yasuoka, K.

    2012-02-01

    Plasmas generated inside oxygen bubbles in water have been developed for water purification. Zero-dimensional numerical simulations were used to investigate the chemical reactions in plasmas driven by dc voltage. The numerical and experimental results of the concentrations of hydrogen peroxide and ozone in the solution were compared with a discharge current between 1 and 7 mA. Upon increasing the water vapour concentration inside bubbles, we saw from the numerical results that the concentration of hydrogen peroxide increased with discharge current, whereas the concentration of ozone decreased. This finding agreed with the experimental results. With an increase in the discharge current, the heat flux from the plasma to the solution increased, and a large amount of water was probably vaporized into the bubbles.

  4. Tissue blood flow and oxygen consumption measured with near-infrared frequency-domain spectroscopy

    NASA Astrophysics Data System (ADS)

    Paunescu, Lelia Adelina

    2001-12-01

    For decades, researchers have contributed with new ways of applying physics' principles to medicine. Moreover, researchers were involved in developing new, non-invasive instrumentation for medical applications. Recently, application of optical techniques in biology and medicine became an important field. Researchers found a non- invasive approach of using visible and near-infrared light as a probe for tissue investigation. Optical methods can contribute to medicine by offering the possibility of rapid, low-resolution, functional images and real-time devices. Near-infrared spectroscopy (NIRS) is a useful technique for the investigation of biological tissues because of the relatively low absorption of water and high absorption of oxy- and deoxy-hemoglobin in the near- infrared region of 750-900 nm. Due to these properties, the near-infrared light can penetrate biological tissues in the range of 0.5-2 cm, offering investigation possibility of deep tissues and differentiate among healthy and diseased tissues. This work represents the initial steps towards understanding and improving of the promising near- infrared frequency-domain technique. This instrument has a very important advantage: it can be used non-invasively to investigate many parts of the human body, including the brain. My research consists primarily of in vivo measurements of optical parameters such as absorption and reduced scattering coefficients and consequently, blood parameters such as oxy, deoxy, and total hemoglobin concentrations, tissue oxygen saturation, blood flow and oxygen consumption of skeletal muscle of healthy and diseased subjects. This research gives a solid background towards a ready- to-use instrument that can continuously, in real-time, measure blood parameters and especially blood oxygenation. This is a very important information in emergency medicine, for persons under intensive care, or undergoing surgery, organ transplant or other interventions.

  5. Characteristics of pulsed dual frequency inductively coupled plasma

    NASA Astrophysics Data System (ADS)

    Seo, Jin Seok; Kim, Kyoung Nam; Kim, Ki Seok; Kim, Tae Hyung; Yeom, Geun Young

    2015-01-01

    To control the plasma characteristics more efficiently, a dual antenna inductively coupled plasma (DF-ICP) source composed of a 12-turn inner antenna operated at 2 MHz and a 3-turn outer antenna at 13.56 MHz was pulsed. The effects of pulsing to each antenna on the change of plasma characteristics and SiO2 etch characteristics using Ar/C4F8 gas mixtures were investigated. When the duty percentage was decreased from continuous wave (CW) mode to 30% for the inner or outer ICP antenna, decrease of the average electron temperature was observed for the pulsing of each antenna. Increase of the CF2/F ratio was also observed with decreasing duty percentage of each antenna, indicating decreased dissociation of the C4F8 gas due to the decreased average electron temperature. When SiO2 etching was investigated as a function of pulse duty percentage, increase of the etch selectivity of SiO2 over amorphous carbon layer (ACL) was observed while decreasing the SiO2 etch rate. The increase of etch selectivity was related to the change of gas dissociation characteristics, as observed by the decrease of average electron temperature and consequent increase of the CF2/F ratio. The decrease of the SiO2 etch rate could be compensated for by using the rf power compensated mode, that is, by maintaining the same time-average rf power during pulsing, instead of using the conventional pulsing mode. Through use of the power compensated mode, increased etch selectivity of SiO2/ACL similar to the conventional pulsing mode could be observed without significant decrease of the SiO2 etch rate. Finally, by using the rf power compensated mode while pulsing rf powers to both antennas, the plasma uniformity over the 300 mm diameter substrate could be improved from 7% for the CW conditions to about around 3.3% with the duty percentage of 30%.

  6. Ion cyclotron range of frequencies heating and flow generation in deuterium{endash}tritium plasmas

    SciTech Connect

    Wilson, J.R.; Bell, R.E.; Bernabei, S.; Hill, K.; Hosea, J.C.; LeBlanc, B.; Majeski, R.; Nazikian, R.; Ono, M.; Phillips, C.K.; Schilling, G.; von Goeler, S.; Bush, C.E.; Hanson, G.R.

    1998-05-01

    Recent radio-frequency heating experiments on the Tokamak Fusion Test Reactor (TFTR) [Hawryluk {ital et al.}, Plasma Phys. Controlled Fusion {bold 33}, 1509 (1991)] have focused on developing tools for both pressure and current profile control in deuterium{endash}tritium (DT) plasmas. A new antenna was added to investigate pressure profile control utilizing direct ion Bernstein wave (IBW) heating. This was the first time direct IBW heating was explored on TFTR. Plasma heating and driven poloidal flows are observed. Previously heating and current drive via mode-converted IBW waves had been demonstrated in non-DT plasmas but efforts in DT plasmas had been unsuccessful. This lack of success had been ascribed to the presence of a small {sup 7}Li minority ion population. In the most recent experiments {sup 6}Li was used exclusively for machine conditioning and mode-conversion heating consistent with theory is now observed in DT plasmas. {copyright} {ital 1998 American Institute of Physics.}

  7. Plasma acceleration from radio-frequency discharge in dielectric capillary

    SciTech Connect

    Dunaevsky, A.; Raitses, Y.; Fisch, N.J.

    2006-06-19

    A capacitive rf discharge was demonstrated in a dielectric capillary for generation of quasineutral plasma flow with energies of several tens of eV. A potential gradient at the open end of the capillary and high-temperature electrons in the capillary discharge promote the ion acceleration. The plasma flow was generated from a ceramic capillary with inner diameter of {approx}0.8 mm and a length of {approx}10 mm, at a gas flow rate of 2-10 SCCM (SCCM denotes cubic centimeter per minute at STP) and input power of 15-20 W. The ion energy spectrum consists of high-energy accelerated ions and a low-energy tail formed due to ionization in the acceleration region. The relatively wide plume angle of {approx}65 deg. indicates that the acceleration region is placed outside the capillary and has a convex shape. Estimated total efficiency at 2 SCCM Xe flow rate and 15 W input power reaches 2%-3%. This approach may be attractive for micropropulsion applications due to its simplicity, low weight and small dimensions of the source, and the absence of a cathode neutralizer.

  8. Oxygen sensitivity of zinc oxide nanoparticles produced via laser-ablated plasma in pressurized liquid

    NASA Astrophysics Data System (ADS)

    Goto, Taku; Shimizu, Yoshiki; Ito, Tsuyohito

    2015-09-01

    While traditional semiconductor oxygen sensor operate only with elevated temperature (= 700 K), the room-temperature operation of the ZnO oxygen sensors have been demonstrated with the help of UV light irradiation. Especially, ZnO nanotubes and nanoparticles have attracted much attentions as highly sensitive oxygen sensors and photodetectors. To the best of our knowledge, the reported works of gas sensors with ZnO nanostructures have been mostly intended for revealing effects of the morphology/shape and the size of the nanostructures. For further improvements of the ZnO-based gas sensors, it is probably required to understand effects of microscopic structures, such as densities of various defects. In this study, we synthesized the ZnO nanoparticles with various defects by means of laser-ablated plasma in pressurized water-ethanol mixture. The results indicate that the defects in ZnO affect oxygen sensitivity, and especially VO + defects seem to be mostly responsible for the resistance change of ZnO nanoparticles. We demonstrate that partial oxygen pressure can be measured with high sensitivity.

  9. Surface cleaning for enhanced adhesion to packaging surfaces: Effect of oxygen and ammonia plasma

    SciTech Connect

    Gaddam, Sneha; Dong, Bin; Driver, Marcus; Kelber, Jeffry; Kazi, Haseeb

    2015-03-15

    The effects of direct plasma chemistries on carbon removal from silicon nitride (SiN{sub x}) and oxynitride (SiO{sub x}N{sub y}) surfaces have been studied by in-situ x-ray photoelectron spectroscopy (XPS) and ex-situ contact angle measurements. The data indicate that O{sub 2} and NH{sub 3} capacitively coupled plasmas are effective at removing adventitious carbon from silicon nitride (SiN{sub x}) and Si oxynitride (SiO{sub x}N{sub y}) surfaces. O{sub 2} plasma treatment results in the formation of a silica overlayer. In contrast, the exposure to NH{sub 3} plasma results in negligible additional oxidation of the SiN{sub x} or SiO{sub x}N{sub y} surface. Ex-situ contact angle measurements show that SiN{sub x} and SiO{sub x}N{sub y} surfaces exposed to oxygen plasma are initially more hydrophilic than surfaces exposed to NH{sub 3} plasma, indicating that the O{sub 2} plasma-induced SiO{sub 2} overlayer is highly reactive toward ambient. At longer ambient exposures (≳10 h), however, surfaces treated by either O{sub 2} or NH{sub 3} plasma exhibit similar steady state contact angles, correlated with rapid uptake of adventitious carbon, as determined by XPS. Surface passivation by exposure to molecular hydrogen prior to ambient exposure significantly retards the increase in contact angle upon exposure to ambient. The results suggest a practical route to enhancing the time available for effective bonding to surfaces in microelectronics packaging applications.

  10. Electron heating via self-excited plasma series resonance in geometrically symmetric multi-frequency capacitive plasmas

    NASA Astrophysics Data System (ADS)

    Schüngel, E.; Brandt, S.; Donkó, Z.; Korolov, I.; Derzsi, A.; Schulze, J.

    2015-08-01

    The self-excitation of plasma series resonance (PSR) oscillations plays an important role in the electron heating dynamics in capacitively coupled radio-frequency (CCRF) plasmas. In a combined approach of PIC/MCC simulations and a theoretical model based on an equivalent circuit, we investigate the self-excitation of PSR oscillations and their effect on the electron heating in geometrically symmetric CCRF plasmas driven by multiple consecutive harmonics. The discharge symmetry is controlled via the electrical asymmetry effect (EAE), i.e. by varying the total number of harmonics and tuning the phase shifts between them. It is demonstrated that PSR oscillations will be self-excited under both symmetric and asymmetric conditions, if (i) the charge-voltage relation of the plasma sheaths deviates from a simple quadratic behavior and (ii) the inductance of the plasma bulk exhibits a temporal modulation. These two effects have been neglected up to now, but we show that they must be included in the model in order to properly describe the nonlinear series resonance circuit and reproduce the self-excitation of PSR oscillations, which are observed in the electron current density resulting from simulations of geometrically symmetric CCRF plasmas. Furthermore, the effect of PSR self-excitation on the discharge current and the plasma properties, such as the potential profile, is illustrated by applying Fourier analysis. High-frequency oscillations in the entire spectrum between the applied frequencies and the local electron plasma frequency are observed. As a consequence, the electron heating is strongly enhanced by the presence of PSR oscillations. A complex electron heating dynamics is found during the expansion phase of the sheath, which is fully collapsed, when the PSR is initially self-excited. The nonlinear electron resonance heating (NERH) associated with the PSR oscillations causes a spatial asymmetry in the electron heating. By discussing the resulting ionization

  11. Spin Biochemistry Modulates Reactive Oxygen Species (ROS) Production by Radio Frequency Magnetic Fields

    PubMed Central

    Usselman, Robert J.; Hill, Iain; Singel, David J.; Martino, Carlos F.

    2014-01-01

    The effects of weak magnetic fields on the biological production of reactive oxygen species (ROS) from intracellular superoxide (O2•−) and extracellular hydrogen peroxide (H2O2) were investigated in vitro with rat pulmonary arterial smooth muscle cells (rPASMC). A decrease in O2•− and an increase in H2O2 concentrations were observed in the presence of a 7 MHz radio frequency (RF) at 10 μTRMS and static 45 μT magnetic fields. We propose that O2•− and H2O2 production in some metabolic processes occur through singlet-triplet modulation of semiquinone flavin (FADH•) enzymes and O2•− spin-correlated radical pairs. Spin-radical pair products are modulated by the 7 MHz RF magnetic fields that presumably decouple flavin hyperfine interactions during spin coherence. RF flavin hyperfine decoupling results in an increase of H2O2 singlet state products, which creates cellular oxidative stress and acts as a secondary messenger that affects cellular proliferation. This study demonstrates the interplay between O2•− and H2O2 production when influenced by RF magnetic fields and underscores the subtle effects of low-frequency magnetic fields on oxidative metabolism, ROS signaling, and cellular growth. PMID:24681944

  12. In situ measurement of gas composition changes in radio frequency plasmas using a quartz sensor

    SciTech Connect

    Suzuki, Atsushi; Nonaka, Hidehiko

    2009-09-15

    A simple method using a quartz sensor (Q-sensor) was developed to observe gas composition changes in radio frequency (rf) plasmas. The output depends on the gases' absolute pressure, molecular weight, and viscosity. The pressure-normalized quartz sensor output depends only on the molecular weight and viscosity of the gas. Consequently, gas composition changes can be detected in the plasmas if a sensor can be used in the plasmas. Influences imparted by the plasmas on the sensor, such as those by reactive particles (e.g., radicals and ions), excited species, electrons, temperature, and electric potentials during measurements were investigated to test the applicability of this quartz sensor measurement to plasma. The Q-sensor measurement results for rf plasmas with argon, hydrogen, and their mixtures are reproducible, demonstrating that the Q-sensor measurement is applicable for plasmas. In this work, pressure- and temperature-normalized Q-sensor output (NQO) were used to obtain the gas composition information of plasma. Temperature-normalization of the Q-sensor output enabled quartz sensor measurements near plasma electrodes, where the quartz sensor temperature increases. The changes in NQO agreed with results obtained by gas analysis using a quadrupole mass spectrometer. Results confirmed that the change in NQO is mainly attributable to changes in the densities and kinds of gas molecules in the plasma gas phase, not by other extrinsic influences of plasma. For argon, hydrogen, and argon-hydrogen plasmas, these changes correspond to reduction in nitrogen, production of carbon monoxide, and dissociation of hydrogen molecules, respectively. These changes in NQO qualitatively and somewhat quantitatively agreed with results obtained using gas analysis, indicting that the measurement has a potential application to obtain the gas composition in plasmas without disturbing industrial plasma processes.

  13. Self-excited nonlinear plasma series resonance oscillations in geometrically symmetric capacitively coupled radio frequency discharges

    SciTech Connect

    Donko, Z.; Schulze, J.; Czarnetzki, U.; Luggenhoelscher, D.

    2009-03-30

    At low pressures, nonlinear self-excited plasma series resonance (PSR) oscillations are known to drastically enhance electron heating in geometrically asymmetric capacitively coupled radio frequency discharges by nonlinear electron resonance heating (NERH). Here we demonstrate via particle-in-cell simulations that high-frequency PSR oscillations can also be excited in geometrically symmetric discharges if the driving voltage waveform makes the discharge electrically asymmetric. This can be achieved by a dual-frequency (f+2f) excitation, when PSR oscillations and NERH are turned on and off depending on the electrical discharge asymmetry, controlled by the phase difference of the driving frequencies.

  14. High-frequency electromagnetic surface waves in a semi-bounded weakly ionized plasma

    SciTech Connect

    Moaied, M.; Tyshetskiy, Yu.; Vladimirov, S. V.

    2013-02-15

    High-frequency electromagnetic surface waves (SWs) in a weakly ionized plasma half-space with Maxwellian electrons are studied taking into account elastic electron-neutral collisions. The SWs spectrum and damping rate are obtained numerically for a wide range of wavelengths, and the asymptotes of damping rate are analytically calculated in some limits. It is shown that the high-frequency SWs become strongly damped at wavelengths {lambda}<{lambda}{sub Min}, where {lambda}{sub Min} significantly depends on plasma parameters (e.g., electron temperature and electron and neutral atom density). The relative importance of collisional and Cherenkov (collisionless) damping of SWs is investigated and is graphically shown for a range of plasma parameters and SW wavelengths. The behavior of weakly ionized plasma with respect to the SW propagation has been recovered for the collisional parameter {eta}.

  15. Electrostatic noise at the plasma frequency beyond the earth's bow shock

    NASA Technical Reports Server (NTRS)

    Filbert, P. C.; Kellogg, P. J.

    1979-01-01

    Scarf et al. (1971) and Dunckel (1974) have shown that there are, very frequently, intense electrostatic waves whose frequency is near the plasma frequency upstream of the earth's bow shock and that these waves are correlated with the presence of energetic electrons from the bow shock. Also, Fredericks et al. (1971) have postulated a two-stream instability. The paper investigates these phenomena further, by comparing electrostatic noise at or near the ambient solar wind plasma frequency with times when the interplanetary magnetic field probably connects to the shock. Evidence is presented that Scarf et al. and Fredericks et al. were correct in their explanation of the phenomenon, and that the double-humped distribution would be expected only in a region too small to be resolved by the plasma measurements made so far.

  16. Low-frequency magnetic fluctuation spectra in the magnetosheath and plasma depletion layer

    NASA Technical Reports Server (NTRS)

    Denton, Richard E.; Gary, S. Peter; Anderson, Brian J.; Fuselier, Stephen A.; Hudson, Mary K.

    1994-01-01

    Recent observations have delineated several different kinds of enhanced magnetic fluctuation spectra below the proton cyclotron frequency in the terrestrial magnetosheath. A model is presented that represents the variation of plasma parameters across the plasma depletion layer and into the magnetosheath proper. Using this model, we find that many of the properties of the observed spectra follow directly from the predictions of linear Vlasov instability theory. The observed progression of spectral features is a natural progression from mirror mode to merged (in frequency range) proton and He(2+) cyclotron modes to bifurcated (in frequency range) cyclotron modes as plasma convects earthward in the magnetosheath. The necessary change in dispersion surface topology from separated proton and He(2+) cyclotron surfaces at low beta to merged surfaces at high beta is described.

  17. Equivalent circuit of radio frequency-plasma with the transformer model.

    PubMed

    Nishida, K; Mochizuki, S; Ohta, M; Yasumoto, M; Lettry, J; Mattei, S; Hatayama, A

    2014-02-01

    LINAC4 H(-) source is radio frequency (RF) driven type source. In the RF system, it is required to match the load impedance, which includes H(-) source, to that of final amplifier. We model RF plasma inside the H(-) source as circuit elements using transformer model so that characteristics of the load impedance become calculable. It has been shown that the modeling based on the transformer model works well to predict the resistance and inductance of the plasma. PMID:24593557

  18. Electron-ion collision-frequency for x-ray Thomson scattering in dense plasmas

    NASA Astrophysics Data System (ADS)

    Faussurier, Gérald; Blancard, Christophe

    2016-01-01

    Two methods are presented to calculate the electron-ion collision-frequency in dense plasmas using an average-atom model. The first one is based on the Kubo-Greenwood approach. The second one uses the Born and Lenard-Balescu approximations. The two methods are used to calculate x-ray Thomson scattering spectra. Illustrations are shown for dense beryllium and aluminum plasmas. Comparisons with experiment are presented in the case of an x-ray Thomson scattering spectrum.

  19. Improvement of the lifetime of radio frequency antenna for plasma generation

    SciTech Connect

    Reijonen, J.; Eardley, M.; Gough, R.; Keller, R.; Leung, K.; Thomae, R.; Pickard, D.; Williams, M. D.

    2000-02-01

    At Lawrence Berkeley National Laboratory different antenna protection schemes have been investigated for the radio frequency-driven multicusp ion source. It was found that the antenna lifetime can be greatly enhanced by an additional shielding, which consists of porcelain, quartz or boron nitride. Different antenna configurations and their influence on the plasma generation will be discussed. Antenna life time greater than 500 hours continuous wave operation has been demonstrated in hydrogen plasma using a novel quartz antenna design. (c)

  20. Selective Reduction of NOx in Oxygen Rich Environment with Plasma-Assisted Catalysis: Role of Plasma and Reactive Intermediates

    SciTech Connect

    Panov, Alexander G.; Tonkyn, Russell G.; Balmer, Marilou L.; Peden, Charles HF.; Malkin, A; Hoard, John; Balmer, M.L.; Fisher, G.; Hoard, J.

    2001-09-01

    Catalytic activity of selected materials (BaY and NaY zeolites, and g-Alumina) for selective NOx reduction in combination with a non-thermal plasma was investigated. Our studies suggest that aldehydes formed during the plasma treatment of simulated diesel exhaust are the important species for the reduction of NOx to N2. Indeed, all materials that are active in plasma-assisted catalysis were found to be very effective in the thermal reduction of NOx in the presence of aldehydes. For example, the thermal catalytic activity of a BaY zeolite with aldehydes gives 80-90% NOx removal at 250 C with 200ppm NOx at the inlet, 1000ppm of C1 as acetaldehyde, propionaldehyde, and butyraldehyde, and SV=12,000 h?. The hydrocarbon reductants, n-octane and 1-propyl alcohol have also shown high thermal catalytic activity for NOx removal over BaY, NaY and g-alumina. We believe that this activity is due to the fact that in an oxygen rich environment these compounds can be thermally oxidized over the catalysts to form the important aldehyde reaction intermediates.

  1. Cyclotron mode frequencies and resonant absorption in multi-species ion plasmas

    SciTech Connect

    Affolter, M.; Anderegg, F.; Dubin, D. H. E.; Driscoll, C. F.

    2015-05-15

    Cyclotron mode frequencies are studied on trapped rigid-rotor multi-species ion plasmas. Collective effects and radial electric fields shift the mode frequencies away from the “bare” cyclotron frequencies 2πF{sub c}{sup (s)}≡(q{sub s}B/M{sub s}c) for each species s. These frequency shifts are measured on the distinct cyclotron modes (m=0,1, and 2) with cos(mθ) azimuthal dependence. We find that for radially uniform plasmas the frequency shifts corroborate a simple theory expression, in which collective effects enter only through the E × B rotation frequency f{sub E} and the species fraction δ{sub s}. The m = 1 center-of-mass mode is in agreement with a simple “clump” model. Additionally, ultra-cold ion plasmas exhibit centrifugal separation by mass, and additional frequency shifts are observed, in agreement with a more general theory.

  2. Optimizing Pulse Waveforms in Plasma Jets for Reactive Oxygen Species (ROS) Production

    NASA Astrophysics Data System (ADS)

    Norberg, Seth; Babaeva, Natalia Yu.; Kushner, Mark J.

    2012-10-01

    Reactive oxygen species (ROS) are desired in numerous applications from the destruction of harmful proteins and bacteria for sterilization in the medical field to taking advantage of the metastable characteristics of O2(^1δ) to transfer energy to other species. Advances in atmospheric pressure plasma jets in recent years show the possibility of using this application as a source of reactive oxygen species. In this paper, we report on results from a computational investigation of atmospheric pressure plasma jets in a dielectric barrier discharge (DBD) configuration. The computer model used in this study, nonPDPSIM, solves transport equations for charged and neutral species, Poisson's equation for the electric potential, the electron energy conservation equation for the electron temperature, and Navier-Stokes equations for the neutral gas flow. A Monte Carlo simulation is used to track sheath accelerated secondary electrons emitted from surfaces and the energy of ions incident onto surfaces. Rate coefficients and transport coefficients for the bulk plasma are obtained from local solutions of Boltzmann's equation for the electron energy distribution. Radiation transport is addressed using a Green's function approach. Various waveforms for the voltage source were examined in analogy to spiker-sustainer systems used at lower gas pressures.

  3. Identification of deep trap energies and influences of oxygen plasma ashing on semiconductor carrier lifetime

    NASA Astrophysics Data System (ADS)

    Koprowski, A.; Humbel, O.; Plappert, M.; Krenn, H.

    2015-03-01

    We have performed an analytical study of the effects of oxygen plasma ashing processes in semiconductor device fabrication and its impact on minority carrier lifetime in high voltage semiconductor devices. Our work includes a critical background study of life time killing mechanisms by deep traps imparted into the semiconductor by barrel plasma ashing. The Elymat technique provides the opportunity to measure lifetime and diffusion length of minority carriers and surface photo voltage (SPV) measurement was used to analyse influences of process parameters such as photoresist, time budget and positioning in the process chamber. It was shown that in microwave plasma processes the diffusion length changes severely with tempering at 200 °C, whereas RF-plasma processes show a significant process time-dependence. Batch tools in general suffer from a strong first wafer effect which could be correlated with the static electrical parameters of the semiconductor devices. The trap identities were detected by using deep level transient spectroscopy and the chemical species of the traps has been proven by inductive coupled plasma mass spectrometry. The deep-bandgap trap energies are reliable fingerprints of the chosen process parameters such as process time and of resist-influences. By microwave plasma processes intrinsic Fe and FeB-complex levels were identified and a good agreement with the SPV-measurement and electrical device characteristic was shown. RF-plasma processes impart levels attributed to Pt levels and an additional level, which could be identified as a trap level probably forming a complex of Pt and H.

  4. Emissive Probe Measurements in a Dual-Frequency-Confined Capacitively-Coupled-Plasma System

    NASA Astrophysics Data System (ADS)

    Linnane, Shane; Ellingboe, Albert R.

    2002-10-01

    Dual frequency confined capacitively coupled plasmas (DFC-CCP) are increasingly used in semiconductor manufacturing for dielectric etching, allowing greater (and independent) control of ion energies and ion flux on the etched substrate. The powered electrode is driven with the summation of 27MHz and 2MHz sinusoidal voltages, while the other electrode is grounded. The electrode areas are similar in size, giving an electrode aspect ratio less than 2. Because of this low aspect ratio, there are large oscillations in the plasma potential. The expectation is for sinusoidal oscillations at the higher driving frequency, due to capacitive sheaths, while a rectified oscillation is expected at the lower driving frequency.(E. Kawamura, V. Vahedi, M. A. Lieberman and C. K. Birdsall, Plasma Sources Sci. Technology. 8 (1999) R45-R64 Work Supported by EURATOM.) Measurements of rf oscillation in the plasma potential taken with a floating emissive probe will be presented. The emissive probe and circuitry allows direct realtime measurement of plasma potential oscillation at both driving frequencies and the harmonics of each, thus allowing measurement of the actual potential on the driven electrode and ion energy incident on grounded electrode.

  5. Electron Transport by Radio Frequency Waves in Tokamak Plasmas

    SciTech Connect

    Ram, A. K.; Kominis, Y.; Hizanidis, K.

    2009-11-26

    A relativistic kinetic description for momentum and spatial diffusion of electrons by radio frequency (RF) waves and non-axisymmetric magnetic field perturbations in a tokamak is formulated. The Lie perturbation technique is used to obtain a non-singular, time dependent evolution equation for resonant and non-resonant electron diffusion in momentum space and diffusion in configuration space. The kinetic equation for the electron distribution function is different from the usual quasilinear equations as it includes interactions that are non-Markovian. It is suitable for studying wave-particle interaction in present tokamaks and in ITER. A primary goal of RF waves, and, in particular, of electron cyclotron waves, in ITER is to control instabilities like the neoclassical tearing mode (NTM). Non-axisymmetric effects due to NTMs are included in the kinetic formalism.

  6. Surface modification of poly(ethylene terephthalate) fibers induced by radio frequency air plasma treatment

    NASA Astrophysics Data System (ADS)

    Riccardi, Claudia; Barni, Ruggero; Selli, Elena; Mazzone, Giovanni; Massafra, Maria Rosaria; Marcandalli, Bruno; Poletti, Giulio

    2003-04-01

    The surface chemical and physical modifications of poly(ethylene terephthalate) (PET) fibers induced by radiofrequency air plasma treatments were correlated with the characteristics of the discharge parameters and the chemical composition of the plasma itself, to identify the plasma-induced surface processes prevailing under different operating conditions. Treated polymer surfaces were characterized by water droplet absorption time measurements and XPS analysis, as a function of the aging time in different media, and by AFM analysis. They exhibited a remarkable increase in hydrophilicity, accompanied by extensive etching and by the implantation of both oxygen- and nitrogen-containing polar groups. Etching was mainly a consequence of ion bombardment, yielding low molecular weight, water soluble oxidation products, while surface chemical modifications were mainly due to the action of neutral species on the plasma-activated polymer surface.

  7. Experimental, theoretical and computational study of frequency upshift of electromagnetic radiation using plasma techniques

    SciTech Connect

    Joshi, C.

    1992-09-01

    This is a second year progress report on Experimental, Theoretical and Computational Study of Frequency Upshift of Electromagnetic Radiation Using Plasma Techniques.'' The highlights are: (I) Ionization fronts have been shown to frequency upshift e.m. radiation by greater than a factor 5. In the experiments, 33 GHz microwave radiation is upshifted to more than 175 GHz using a relativistically propagating ionization front created by a laser beam. (II) A Letter describing the results has been published in Physical Review Letters and an invited'' paper has been submitted to IEEE Trans. in Plasma Science.

  8. Rescaling effects on a low-frequency drift wave in dusty plasmas

    NASA Astrophysics Data System (ADS)

    Qiu, Xin; Liu, Sanqiu

    2015-03-01

    The effect of dust on the low-frequency drift wave in inhomogeneous magnetized dusty plasmas is investigated. It is shown that a low-frequency drift wave can be modeled by the Hasegawa-Mima equation (HME) both in mobile and immobile dusty plasmas, which are dust-modified HME and HME in dusty background, respectively. The former is rescaled significantly by the presence of the dust and the space-time scale greatly increases with the increasing density and mass of dust, while the latter is not rescaled, but an additional driving force appears to drive the drift waves.

  9. The kinetic response of a stochastic plasma to low frequency perturbations

    NASA Technical Reports Server (NTRS)

    Hurricane, Omar A.; Pellat, Rene; Coroniti, Ferdinand V.

    1994-01-01

    Following suggestion that substorm breakup might be caused by an interchange or ballooning instability, several magnetohydrodynamic (MHD) and gyro-kinetic stability analysis have been performed for plasma sheet magnetic field geometries. However, the stochastic ion dynamics in the highly stressed, thin high-beta near earth plasma sheet violate the locality requirements of MHD and the invarience of the magnetic moment, mu, required by gyro-kinetic theories. In this paper we develop a new linear Vlasov kinetic theory (for low frequency modes omega less than omega(sub b), omega(sub b) being the bounce frequency) which includes the dynamics of stochastic ions.

  10. Helium-based cold atmospheric plasma-induced reactive oxygen species-mediated apoptotic pathway attenuated by platinum nanoparticles.

    PubMed

    Jawaid, Paras; Rehman, Mati Ur; Zhao, Qing Li; Takeda, Keigo; Ishikawa, Kenji; Hori, Masaru; Shimizu, Tadamichi; Kondo, Takashi

    2016-09-01

    Plasma is generated by ionizing gas molecules. Helium (He)-based cold atmospheric plasma (CAP) was generated using a high-voltage power supply with low-frequency excitation (60 Hz at 7 kV) and He flow at 2 l/min. Platinum nanoparticles (Pt-NPs) are potent antioxidants due to their unique ability to scavenge superoxides and peroxides. These features make them useful for the protection against oxidative stress-associated pathologies. Here, the effects of Pt-NPs on He-CAP-induced apoptosis and the underlying mechanism were examined in human lymphoma U937 cells. Apoptosis was measured after cells were exposed to He-CAP in the presence or absence of Pt-NPs. The effects of combined treatment were determined by observing the changes in intracellular reactive oxygen species (ROS) and both mitochondrial and Fas dependent pathway. The results indicate that Pt-NPs substantially scavenge He-CAP-induced superoxides and peroxides and inhibit all the pathways involved in apoptosis execution. This might be because of the SOD/catalase mimetic effects of Pt-NPs. These results showed that the Pt-NPs can induce He-CAP desensitization in human lymphoma U937 cells. PMID:27256594

  11. Strong Field-Induced Frequency Conversion of Laser Radiation in Plasma Plumes: Recent Achievements

    PubMed Central

    Ganeev, R. A.

    2013-01-01

    New findings in plasma harmonics studies using strong laser fields are reviewed. We discuss recent achievements in the growth of the efficiency of coherent extreme ultraviolet (XUV) radiation sources based on frequency conversion of the ultrashort pulses in the laser-produced plasmas, which allowed for the spectral and structural studies of matter through the high-order harmonic generation (HHG) spectroscopy. These studies showed that plasma HHG can open new opportunities in many unexpected areas of laser-matter interaction. Besides being considered as an alternative method for generation of coherent XUV radiation, it can be used as a powerful tool for various spectroscopic and analytical applications. PMID:23864818

  12. Experimental Observation and Computational Analysis of Striations in Electronegative Capacitively Coupled Radio-Frequency Plasmas

    NASA Astrophysics Data System (ADS)

    Liu, Yong-Xin; Schüngel, Edmund; Korolov, Ihor; Donkó, Zoltán; Wang, You-Nian; Schulze, Julian

    2016-06-01

    Self-organized spatial structures in the light emission from the ion-ion capacitive rf plasma of a strongly electronegative gas (CF4 ) are observed experimentally for the first time. Their formation is analyzed and understood based on particle-based kinetic simulations. These "striations" are found to be generated by the resonance between the driving radio frequency and the eigenfrequency of the ion-ion plasma (derived from an analytical model) that establishes a modulation of the electric field, the ion densities, as well as the energy gain and loss processes of electrons in the plasma. The growth of the instability is followed by the numerical simulations.

  13. Degradation of methylene blue by radio frequency plasmas in water under ultraviolet irradiation.

    PubMed

    Maehara, Tsunehiro; Nishiyama, Kyohei; Onishi, Shingo; Mukasa, Shinobu; Toyota, Hiromichi; Kuramoto, Makoto; Nomura, Shinfuku; Kawashima, Ayato

    2010-02-15

    The degradation of methylene blue by radio frequency (RF) plasmas in water under ultraviolet (UV) irradiation was studied experimentally. When the methylene blue solution was exposed to RF plasma, UV irradiation from a mercury vapor lamp enhanced degradation significantly. A lamp without power supply also enhanced degradation since weak UV light was emitted weakly from the lamp due to the excitation of mercury vapor by stray RF power. Such an enhancement is explained by the fact that after hydrogen peroxide is produced via the recombination process of OH radicals around the plasma, OH radicals reproduced from hydrogen peroxide via the photolysis process degrade methylene blue. PMID:19819072

  14. High frequency atmospheric cold plasma treatment system for materials surface processing

    NASA Astrophysics Data System (ADS)

    Tudoran, Cristian D.; Surducan, Vasile; Anghel, Sorin D.

    2012-02-01

    The paper presents a new laboratory-made plasma treatment system. The power source which generates the plasma is based on a modern half-bridge type inverter circuit working at a frequency of 4 MHz, and giving an output power of about 200 W. The inverter is fed directly from the mains voltage and features high speed protection circuits for both over voltage and over current protection, making the system light and easy to operate. The output of the inverter is connected to the resonant circuit formed by a Tesla coil and the dielectric barrier discharge plasma chamber. The plasma is generated at atmospheric pressure in argon, helium or mixtures of helium and small quantities of argon. It is a cold discharge (Tgas < 150°C) with a homogeneous structure. The plasma generates chemically active species, especially O and OH, which could be important in various applications such as the treatment and processing of materials surfaces.

  15. Two-dimensional profile measurement of plasma parameters in radio frequency-driven argon atmospheric pressure plasma jet

    SciTech Connect

    Seo, B. H.; Kim, J. H.; Kim, D. W.; You, S. J.

    2015-09-15

    The two-dimensional profiles of the electron density, electron temperature, neutral translational temperature, and molecular rotational temperature are investigated in an argon atmospheric pressure plasma jet, which is driven by the radio frequency of 13.56 MHz by means of the laser scattering methods of Thomson, Rayleigh, and Raman. All measured parameters have maximum values at the center of the discharge and decrease toward the plasma edge. The results for the electron temperature profile are contrary to the results for the microwave-driven plasma. From our experimental results, the profiles of the plasma parameters arise from the radial contraction of plasmas and the time averaged profile of the electric field, which is obtained by a microwave simulation performed under identical conditions to the plasma jet. In the case of the neutral temperature, a higher translational temperature than the rotational temperature is measured, and its discrepancy is tentatively explained in terms of the low ion-neutral charge exchange rate and the additional degrees of freedom of the molecules. The description of our experimental results and the underlying physics are addressed in detail.

  16. Spectroscopic Measurement of High-Frequency Electric Fields in the Interaction of Explosive Debris Plasma with Ambient, Magnetized Background Plasma

    NASA Astrophysics Data System (ADS)

    Bondarenko, Anton; Schaeffer, Derek; Everson, Erik; Clark, Eric; Vincena, Stephen; van Compernolle, Bart; Tripathi, Shreekrishna; Constantin, Carmen; Niemann, Chris

    2014-10-01

    The explosive expansion of dense, high-beta debris plasma into relatively tenuous, magnetized background plasma is relevant to a wide variety of astrophysical and space environments. Electric fields play a fundamental role in the coupling of momentum and energy from debris to background, and emission spectroscopy provides a powerful diagnostic for assessing electric fields via the Stark effect. A recent experiment utilizing a unique experimental platform at UCLA that combines the Large Plasma Device and the Raptor laser facility has investigated the super-Alfvénic, quasi-perpendicular expansion of a laser-produced carbon (C) debris plasma through a preformed, ambient, magnetized helium (He) background plasma via emission spectroscopy. Spectral profiles of the He II 468.6 nm line have been analyzed via single-mode and multi-mode time-dependent Stark broadening models for hydrogen-like ions, yielding large magnitude (~100 kV/cm), high-frequency (~100 GHz) electric fields. The measurements suggest the development of an electron beam-plasma instability, and a simple instability saturation model demonstrates that the measured electric field magnitudes are feasible under the experimental conditions.

  17. Low temperature synthesis of silicon quantum dots with plasma chemistry control in dual frequency non-thermal plasmas.

    PubMed

    Sahu, Bibhuti Bhusan; Yin, Yongyi; Han, Jeon Geon; Shiratani, Masaharu

    2016-06-21

    The advanced materials process by non-thermal plasmas with a high plasma density allows the synthesis of small-to-big sized Si quantum dots by combining low-temperature deposition with superior crystalline quality in the background of an amorphous hydrogenated silicon nitride matrix. Here, we make quantum dot thin films in a reactive mixture of ammonia/silane/hydrogen utilizing dual-frequency capacitively coupled plasmas with high atomic hydrogen and nitrogen radical densities. Systematic data analysis using different film and plasma characterization tools reveals that the quantum dots with different sizes exhibit size dependent film properties, which are sensitively dependent on plasma characteristics. These films exhibit intense photoluminescence in the visible range with violet to orange colors and with narrow to broad widths (∼0.3-0.9 eV). The observed luminescence behavior can come from the quantum confinement effect, quasi-direct band-to-band recombination, and variation of atomic hydrogen and nitrogen radicals in the film growth network. The high luminescence yields in the visible range of the spectrum and size-tunable low-temperature synthesis with plasma and radical control make these quantum dot films good candidates for light emitting applications. PMID:27226277

  18. Treatment of Second Order Structures of Protein on Medical Equipments Using Oxygen Plasma

    NASA Astrophysics Data System (ADS)

    Hayashi, Nobuya; Kitazaki, Satoshi; Goto, Masaaki; Yagyu, Yoshihito; Yonesu, Akira

    2009-10-01

    Removal of proteins from the surface of medical equipments are attempted using an RF plasma. Oxygen gas is introduced into a vacuum chamber with dimensions of 450 mm in length, 200 mm in diameter and 20L of capacity. When an RF power (13.56 MHz, 60W) is applied to an ICP type antenna, oxygen radicals (atomic oxygen and excited oxygen molecule) are produced below the antenna. The characteristics of removing protein from the medical equipments was investigated using casein and heat-resistive keratin proteins. Initial concentration of the proteins on a CaF2 substrate is several mg/cm2. The treatment effect of proteins is determined by the peak height of chemical bonds in amide and second order structures appeared on FTIR spectra. The second order structure of a protein such as alpha-helix and beta-sheet are decomposed with the treatment period. Complete treatment of proteins including the second order structure requires several hours avoiding the damage to medical equipments.

  19. Increased Oxygen Recovery from Sabatier Systems Using Plasma Pyrolysis Technology and Metal Hydride Separation

    NASA Technical Reports Server (NTRS)

    Greenwood, Zachary W.; Abney, Morgan B.; Perry, Jay L.; Miller, Lee A.; Dahl, Roger W.; Hadley, Neal M.; Wambolt, Spencer R.; Wheeler, Richard R.

    2015-01-01

    State-of-the-art life support carbon dioxide (CO2) reduction technology is based on the Sabatier reaction where less than 50% of the oxygen required for the crew is recovered from metabolic CO2. The reaction produces water as the primary product and methane as a byproduct. Oxygen recovery is constrained by the limited availability of reactant hydrogen. This is further exacerbated when Sabatier methane (CH4) is vented as a waste product resulting in a continuous loss of reactant hydrogen. Post-processing methane with the Plasma Pyrolysis Assembly (PPA) to recover hydrogen has the potential to dramatically increase oxygen recovery and thus drastically reduce the logistical challenges associated with oxygen resupply. The PPA decomposes methane into predominantly hydrogen and acetylene. Due to the highly unstable nature of acetylene, a separation system is necessary to purify hydrogen before it is recycled back to the Sabatier reactor. Testing and evaluation of a full-scale Third Generation PPA is reported and investigations into metal hydride hydrogen separation technology is discussed.

  20. A new method for determining the plasma electron density using optical frequency comb interferometer

    SciTech Connect

    Arakawa, Hiroyuki Tojo, Hiroshi; Sasao, Hajime; Kawano, Yasunori; Itami, Kiyoshi

    2014-04-15

    A new method of plasma electron density measurement using interferometric phases (fractional fringes) of an optical frequency comb interferometer is proposed. Using the characteristics of the optical frequency comb laser, high density measurement can be achieved without fringe counting errors. Simulations show that the short wavelength and wide wavelength range of the laser source and low noise in interferometric phases measurements are effective to reduce ambiguity of measured density.

  1. Sum frequency generation and coherent anti-Stokes Raman spectroscopic studies on plasma-treated plasticized polyvinyl chloride films.

    PubMed

    Hankett, Jeanne M; Zhang, Chi; Chen, Zhan

    2012-03-13

    Polyvinyl chloride (PVC) is a widely used polymer to which various phthalates are extensively applied as plasticizers. PVC materials are often treated with plasma to vary the hydrophobicity or for cleaning purposes, but little is known of the nature of the surface molecular structures after treatment. This research characterizes molecular surface structures of PVC and bis-2-ethylhexyl phthalate (DEHP)-plasticized PVC films in air before annealing, after annealing, and after exposure to air-generated glow discharge plasma using sum frequency generation (SFG) vibrational spectroscopy. In addition, we compare the vibrational molecular signatures on the surfaces of PVC with DEHP (at a variety of percent loadings) to those of the bulk detected using coherent anti-Stokes Raman scattering (CARS). X-ray photoelectron spectroscopy (XPS) and contact angle measurements have been used to analyze PVC surfaces to supplement SFG data. Our results indicate that DEHP was found on the surfaces of PVC films even at low weight percentages (5 wt %) and that DEHP segregates on surfaces after annealing. The treatment of these films with glow discharge plasma resulted in surface-sensitive reactions involving the removal of chlorine atoms, the addition of oxygen atoms, and C-H bond rearrangement. CARS data demonstrate that the bulk of our films remained undisturbed during the plasma treatment. For the first time, we probed the molecular structure of the surface and the bulk of a PVC material using combined SFG and CARS studies on the same sample in exactly the same environment. In addition, the methodology used in this research can be applied to characterize various plasticizers in a wide variety of polymer systems to understand their surface and bulk structures before and after systematic applications of heat, plasma, or other treatments. PMID:22309397

  2. A Hilbert-Vlasov code for the study of high-frequency plasma beatwave accelerator

    SciTech Connect

    Ghizzo, A.; Bertrand, P.; Begue, M.L.; Johnston, T.W.; Shoucri, M.

    1996-04-01

    High-frequency beatwave simulations relevant to the University of California at Los Angeles (UCLA) experiment with relativistic eulerian hybrid Vlasov code are presented. These Hilbert-Vlasov simulations revealed a rich variety of phenomena associated with the fast particle dynamics induced by beatwave experiment for a high ratio of driver frequency to plasma frequency {omega}{sub pump}/{omega}{sub pump} {approx} 33. The present model allows one to extend detailed modeling to frequency ratios greater than the current practical maximum of 10 or so, for Vlasov or particle-in-cell (PIC) codes, by replacing the Maxwell equations by mode equations for the electromagnetic Vlasov code. Numerical results, including beat frequency chirping (i.e., pump frequency linearly decreasing with time), show that the amplitude limit due to relativistic detuning can be enhanced with accelerated particles up to the ultrarelativistic energies with a high-acceleration gradient of more than 25 GeV/m.

  3. Analysis by oxygen atom number density measurement of high-speed hydrophilic treatment of polyimide using atmospheric pressure microwave plasma

    SciTech Connect

    Ono, S.

    2015-03-30

    This paper describes the fundamental experimental data of the plasma surface modification of the polyimide using atmospheric pressure microwave plasma source. The experimental results were discussed from the point of view of the radical’s behavior, which significantly affects the modification mechanism. The purpose of the study is to examine how the value of the oxygen atom density will affect the hydrophilic treatment in the upstream region of the plasma where gas temperature is very high. The surface modification experiments were performed by setting the polyimide film sample in the downstream region of the plasma. The degree of the modification was measured by a water contact angle measurement. The water contact angle decreased less than 30 degrees within 1 second treatment time in the upstream region. Very high speed modification was observed. The reason of this high speed modification seems that the high density radical which contributes the surface modification exist in the upstream region of the plasma. This tendency is supposed to the measured relatively high electron density (~10{sup 15}cm{sup −3}) at the center of the plasma. We used the electric heating catalytic probe method for oxygen radical measurement. An absolute value of oxygen radical density was determined by catalytic probe measurement and the results show that ~10{sup 15}cm{sup −3} of the oxygen radical density in the upstream region and decreases toward downstream region. The experimental results of the relation of the oxygen radical density and hydrophilic modification of polyimide was discussed.

  4. Preliminary study on the effects of ageing cold oxygen plasma treated PET/PP with respect to protein adsorption.

    PubMed

    Chen, Rui; Bayon, Yves; Hunt, John A

    2012-08-01

    Surfaces of polyethylene terephthalate (PET) and polypropylene (PP) have been modified by oxygen plasma. The surface hydrophilicity and changes in topography during up to 90 days storage in water and in dry air in a desiccator were analysed by dynamic contact angle test and atomic force microscopy (AFM). Clear ageing effects on the plasma treated surface were observed as increases in contact angle and changes in roughness as functions of increasing storage time. However, the effect of oxygen plasma treatment to increase the hydrophilicity of surface was still evident on the treated surfaces even after 90 days storage either in dry air or in water. In protein adsorption experiments, human serum albumin (HSA) and fibrinogen (Fg) were adsorbed on untreated and oxygen plasma treated PET and PP surfaces. The quantified ATR-FTIR results showed that both HSA and Fg adsorption on PET and PP surfaces decreased after oxygen plasma treatment, with the effect most evident for HSA. Although for both proteins adsorption increased with ageing, the amount of adsorbed proteins was still lower than untreated surface at 30 days. This suggests the shelf life of oxygen plasma treated samples could be as long as 30 days. PMID:22521680

  5. Anchoring gold nanoparticles onto a mica surface by oxygen plasma ashing for sequential nanocomponent assembly

    NASA Astrophysics Data System (ADS)

    Takagi, Akihiko; Ojima, Kaoru; Mikamo, Eriko; Matsumoto, Takuya; Kawai, Tomoji

    2007-01-01

    Water-soluble gold nanoparticles were immobilized in both polar (water) and nonpolar (chloroform) liquids on hydrophilic mica surface by oxygen plasma ashing. It is then demonstrated that a DNA with a thiol at an extremity is attached to the immobilized nanoparticles due to the gold-thiol coupling and stretched in the flow direction of the following water rinse. This technique allows a sequential integration of nanoparticles and molecules for various solutions, since the nanoparticles remain on a solid surface rather than dissolve into the solution.

  6. Anchoring gold nanoparticles onto a mica surface by oxygen plasma ashing for sequential nanocomponent assembly

    SciTech Connect

    Takagi, Akihiko; Ojima, Kaoru; Mikamo, Eriko; Matsumoto, Takuya; Kawai, Tomoji

    2007-01-22

    Water-soluble gold nanoparticles were immobilized in both polar (water) and nonpolar (chloroform) liquids on hydrophilic mica surface by oxygen plasma ashing. It is then demonstrated that a DNA with a thiol at an extremity is attached to the immobilized nanoparticles due to the gold-thiol coupling and stretched in the flow direction of the following water rinse. This technique allows a sequential integration of nanoparticles and molecules for various solutions, since the nanoparticles remain on a solid surface rather than dissolve into the solution.

  7. Excitation of High Frequency Waves and Plasma Wave Spectroscopy in the Collisionless Terrella Experiment

    NASA Astrophysics Data System (ADS)

    Maslovsky, Dmitry; Galayda, S.; Mauel, M.; Socrates, A.; Steinvurzel, P.; Leong, P.

    1998-11-01

    A broad-band antenna with m = 3 symmetry installed at one magnetic pole of the Collisionless Terrella Experiment(H. P. Warren and M. E. Mauel, Phys. Plasmas), 2 (1995) 4185. (CTX) is used to excite waves with frequencies between the ion and electron cyclotron frequencies (10-1000 MHz). Typically, waves are launched using a 100 W amplifier and a coherent signal generator capable of linear frequency sweeping. Launched waves are detected using movable electric and magnetic probes. In CTX, a population of energetic electrons is created using electron cyclotron resonance heating. We have focused on the the excitation of waves bounce-resonant with the energetic electrons which might change the saturation of lower-frequency hot electron interchange instabilities. For example, the inward propagation of ``phase-space holes'' associated with natural frequency sweeping should be arrested by the application of sufficiently intense waves. We report results of plasma wave spectroscopy between 10 MHz - 1 GHz and the identification of natural frequencies of the dipole-confined plasma.

  8. Sterilization characteristics of dental instruments using oxygen plasma produced by narrow gap RF discharge

    NASA Astrophysics Data System (ADS)

    Sakai, Yasuhiro; Liu, Zhen; Goto, Masaaki; Hayashi, Nobuya

    2016-07-01

    Sterilization characteristics and material compatibility of low-pressure RF oxygen plasma sterilization method for dental instruments are investigated. Regarding the characteristics of the plasma sterilizer for dental instruments, it is small and can rapidly sterilize owing to a narrow gap discharge. Sterilization of vial-type biological indicators is achieved for the shortest treatment period of 40 min at an RF power of 80 W at a temperature of 70 °C. At a temperature lower than 60 °C, a sterilization period of 90 min is required using a water-cooled electrode. No surface modifications of dental instruments such as chemical composition and deterioration of fine crystals of a diamond bar were observed under a scanning electron microscope.

  9. Effect of oxygen plasma and thermal oxidation on shallow nitrogen-vacancy centers in diamond

    SciTech Connect

    Kim, M.; Rugar, D.; Mamin, H. J.; Sherwood, M. H.; Rettner, C. T.; Frommer, J.

    2014-07-28

    We investigate the effect of two different surface treatments on shallow nitrogen-vacancy (NV) centers in diamond. Short duration oxygen plasma exposure is found to damage near-surface NV centers, resulting in their disappearance in fluorescence images. Subsequent annealing creates large numbers of new NV centers, attributed to plasma-induced vacancy creation. By tracking individual NV centers during thermal oxidation, we show that oxidation at 550 °C results in modest improvement of spin coherence. Higher temperature oxidations correlate with gradual decline in spin coherence and eventual instability of NV centers before ultimate disappearance. This is indicative of a reduction of the NV-to-surface distance due to oxidative etching. Thermal oxidation can offer controlled access to near-surface NV spins at the nanometer scale, an important requirement for many applications of NV-based nanomagnetometry.

  10. Generation of Alfven waves by high power pulse at the electron plasma frequency

    NASA Astrophysics Data System (ADS)

    van Compernolle, Bart Gilbert

    The physics of the interaction between plasmas and high power waves with frequencies in the electron plasma frequency range is of importance in many areas of space and plasma physics. A great deal of laboratory research has been done on the interaction of microwaves in a density gradient when o = ope in unmagnetized plasmas. [SWK74, WS78, KSW74]. Extensive studies of HF-ionospheric modifications have been performed [Fej79] as evidenced by experiments at Arecibo [HMD92, BHK86, CDF92, FGI85], at the HAARP facility [RKK98] in Alaska, at the EISCAT observatory in Norway [IHR99], and at SURA in Russia [FKS99]. This dissertation focusses on the interaction with a fully magnetized plasma, capable of supporting Alfven waves. The experiment is performed in the upgraded LArge Plasma Device (LAPD) at UCLA [GPL91] (Helium, n = 1012 cm-3, B = 1 kG - 2.5 kG). A number of experiments have been done at LAPD using antennas, skin depth scale currents and laser produced plasmas to generate Alfven waves [LGM99, GVL97a, GVL97b, VGV01]. In this work a high power pulse 6th, frequency in the electron plasma frequency range is launched into the radial density gradient, perpendicular to the background magnetic field. The microwave pulses last on the order of one ion gyro period and has a maximum power of |E|2/ nT ≃ .5 in the afterglow. The absorption of these waves leads to a pulse of field aligned suprathermal electrons. This electron current pulse then launches with Alfven wave with o ≤ o ci. The experiment was performed bath in ordinary node (O-mode) and extraordinary (X-mode), for different background magnetic fields B0, different temperatures (afterglow vs discharge) and different power levels of the incoming microwaves. It was found that the Alfven wave generation can be explained by Cherenkov radiation of Alfven waves by the suprathermal electron pulse. Theoretical solutions for the perturbed magnetic field due to a pulse of field aligned electrons were obtained, and shown to be

  11. Oxidation of Inconel 625 superalloy upon treatment with oxygen or hydrogen plasma at high temperature

    NASA Astrophysics Data System (ADS)

    Vesel, Alenka; Drenik, Aleksander; Elersic, Kristina; Mozetic, Miran; Kovac, Janez; Gyergyek, Tomaz; Stockel, Jan; Varju, Jozef; Panek, Radomir; Balat-Pichelin, Marianne

    2014-06-01

    Initial stages of Inconel 625 superalloy (Ni60Cr30Mo10Ni4Nb1) oxidation upon short treatment with gaseous plasma at different temperatures up to about 1600 K were studied. Samples were treated for different periods up to a minute by oxygen or hydrogen plasma created with a microwave discharge in the standing-wave mode at a pressure of 40 Pa and a power 500 W. Simultaneous heating of the samples was realized by focusing concentrated solar radiation from a 5 kW solar furnace directly onto the samples. The morphological changes upon treatment were monitored using scanning electron microscopy, compositional depth profiling was performed using Auger electron spectroscopy, while structural changes were determined by X-ray diffraction. The treatment in oxygen plasma caused formation of metal oxide clusters of three dimensional crystallites initially rich in nickel oxide with the increasing chromium oxide content as the temperature was increasing. At about 1100 K iron and niobium oxides prevailed on the surface causing a drop of the material emissivity at 5 μm. Simultaneously the NiCr2O4 compound started growing at the interface between the oxide film and bulk alloy and the compound persisted up to temperatures close to the Inconel melting point. Intensive migration of minority alloying elements such as Fe and Ti was observed at 1600 K forming mixed surface oxides of sub-micrometer dimensions. The treatment in hydrogen plasma with small admixture of water vapor did not cause much modification unless the temperature was close to the melting point. At such conditions aluminum segregated on the surface and formed well-defined Al2O3 crystals.

  12. A mechanism for plasma waves at the harmonics of the plasma frequency in the electron foreshock boundary

    NASA Technical Reports Server (NTRS)

    Klimas, A. J.

    1983-01-01

    A bump-on-tail unstable reduced velocity distribution, constructed from data obtained at the upstream boundary of the electron foreshock by the GSFC electron spectrometer experiment on the ISEE-1 satellite, is used as the initial plasma state for a numerical integration of the 1D-Vlasov-Maxwell system of equations. The integration is carried through the growth of the instability, beyond its saturation, and well into the stabilized plasma regime. A power spectrum computed for the electric field of the stabilized plasma is dominated by a narrow peak at the Bohm-Gross frequency of the unstable field mode but also contains significant power at the harmonics of the Bohm-Gross frequency. The harmonic power is in sharp peaks which are split into closely spaced doublets. The fundamental peak at the Bohm-Gross frequency is split into a closely spaced triplet. The mechanism for excitation of the second harmonic is shown to be second order wave-wave coupling. Previously announced in STAR as N83-17315

  13. A bifractal nature of reticular patterns induced by oxygen plasma on polymer films

    NASA Astrophysics Data System (ADS)

    Bae, Junwan; Lee, I. J.

    2015-05-01

    Plasma etching was demonstrated to be a promising tool for generating self-organized nano-patterns on various commercial films. Unfortunately, dynamic scaling approach toward fundamental understanding of the formation and growth of the plasma-induced nano-structure has not always been straightforward. The temporal evolution of self-aligned nano-patterns may often evolve with an additional scale-invariance, which leads to breakdown of the well-established dynamic scaling law. The concept of a bifractal interface is successfully applied to reticular patterns induced by oxygen plasma on the surface of polymer films. The reticular pattern, composed of nano-size self-aligned protuberances and underlying structure, develops two types of anomalous dynamic scaling characterized by super-roughening and intrinsic anomalous scaling, respectively. The diffusion and aggregation of short-cleaved chains under the plasma environment are responsible for the regular distribution of the nano-size protuberances. Remarkably, it is uncovered that the dynamic roughening of the underlying structure is governed by a relaxation mechanism described by the Edwards-Wilkinson universality class with a conservative noise. The evidence for the basic phase, characterized by the negative roughness and growth exponents, has been elusive since its first theoretical consideration more than two decades ago.

  14. Production characteristics of reactive oxygen/nitrogen species in water using atmospheric pressure discharge plasmas

    NASA Astrophysics Data System (ADS)

    Takahashi, Kazuhiro; Satoh, Kohki; Itoh, Hidenori; Kawaguchi, Hideki; Timoshkin, Igor; Given, Martin; MacGregor, Scott

    2016-07-01

    A pulsed discharge, a DC corona discharge, and a plasma jet are separately generated above a water surface, and reactive oxygen species and reactive nitrogen species (ROS/RNS) in the water are investigated. ROS/RNS in water after the sparging of the off-gas of a packed-bed dielectric barrier discharge (PB-DBD) are also investigated. H2O2, NO2 ‑, and NO3 ‑ are detected after plasma exposure and only NO3 ‑ after off-gas sparging. Short-lifetime species in plasma are found to play an important role in H2O2 and NO2 ‑ production and long-lifetime species in NO3 ‑ production. NO x may inhibit H2O2 production through OH consumption to produce HNO2 and HNO3. O3 does not contribute to ROS/RNS production. The pulsed plasma exposure is found to be effective for the production of H2O2 and NO2 ‑, and the off-gas sparging of the PB-DBD for the production of NO3 ‑.

  15. Effect of an oxygen plasma treatment on the specific surface of platinum electrodeposits for fuel cells

    NASA Astrophysics Data System (ADS)

    Massoni, Nicolas; Beaumont-Martinent, Audrey; Laurent, Jean-Yves

    Fuel cells involve electrochemical reactions often catalysed by platinum whose surface has to be maximized. In this paper, platinum nano-particles are deposited onto graphite by a potentiostatic reduction of a dilute 1.0 mM solution of hexachloroplatinate acid. Some samples are pre-treated by highly dissociated oxygen plasma and exhibit an increase of their specific surface compared to the untreated ones. The gain factor on specific surface reaches 3.6 and even 4.4 when the plasma treatment is coupled with the impregnation technique. Surface functionalization made by the plasma treatment lead to denser deposits thanks to an organized nucleation and growth of platinum nuclei. XPS analyses suggest the existence of C-O bonds in the platinum clusters. Although the testing conditions were not optimized, we have measured the performances of a microfuel cell made with the optimized catalyst. The Scharifker and Hills electrocrystallisation model was used to fit the current transients. Untreated samples transients were correctly fitted by the model whereas plasma treated samples transients did not have the requested shape for this model. Hence, nucleation mechanism was determined and confirmed by observation on untreated samples only. The calculated value of the diffusion coefficient of the Pt(IV) anion PtCl 6 2- determined by the Cottrell theory was close to the literature, i.e. 2.6 ± 0.6 × 10 -6 cm 2 s -1.

  16. A bifractal nature of reticular patterns induced by oxygen plasma on polymer films

    PubMed Central

    Bae, Junwan; Lee, I. J.

    2015-01-01

    Plasma etching was demonstrated to be a promising tool for generating self-organized nano-patterns on various commercial films. Unfortunately, dynamic scaling approach toward fundamental understanding of the formation and growth of the plasma-induced nano-structure has not always been straightforward. The temporal evolution of self-aligned nano-patterns may often evolve with an additional scale-invariance, which leads to breakdown of the well-established dynamic scaling law. The concept of a bifractal interface is successfully applied to reticular patterns induced by oxygen plasma on the surface of polymer films. The reticular pattern, composed of nano-size self-aligned protuberances and underlying structure, develops two types of anomalous dynamic scaling characterized by super-roughening and intrinsic anomalous scaling, respectively. The diffusion and aggregation of short-cleaved chains under the plasma environment are responsible for the regular distribution of the nano-size protuberances. Remarkably, it is uncovered that the dynamic roughening of the underlying structure is governed by a relaxation mechanism described by the Edwards-Wilkinson universality class with a conservative noise. The evidence for the basic phase, characterized by the negative roughness and growth exponents, has been elusive since its first theoretical consideration more than two decades ago. PMID:25997075

  17. Modeling and simulation of high-frequency surface waves in bounded plasmas

    NASA Astrophysics Data System (ADS)

    Cooperberg, David Jeffrey

    In the work presented here, we shall make a careful examination of an intrinsic property of bounded plasmas. Specifically, we will be studying a set of high frequency (electron) waves which propagate at the boundary of metal bounded plasmas. This study relies heavily on particle- in-cell simulation wit;h Monte-Carlo collisions (PIC-MCC) (1-3). Among the benefits of the PIC-MCC scheme are an adherence to first-principles, which allows a wide range of kinetic behavior to be accurately modeled including the electron energy probability function which is known to depart from Maxwellian in low pressure discharges (58) (85). This work has two main objectives. The first is to clarify the structure of these waves. It is also hoped that this use of simulation in the study of electron surface waves will further our general understanding of these waves in both metal and dielectric bound plasmas. Our second objective is to study how these natural modes may be used to sustain a plasma discharge suitable for plasma processing. Current 'surface wave plasmas' are produced in glass tubes (42). Our analysis of surface waves in planar metal bounded plasma slabs enables us to simulate new types of surface wave sustained discharges which may operate at low pressures with low sheath potentials and may be scalable to large areas without compromising plasma uniformity. An outline of this work follows. Chapter 1 presents an overview of past and current work on electron surface oscillations and waves in bounded plasmas. In Chapter 2 we initiate our study of waves in the metal bound slab using a matrix sheath model. Next a more realistic model for the plasma and sheath is developed in Chapter 3. The result is the identification of a new set of surface modes which exist only in the non-uniform, thermal, bounded plasma. We then move from the study of surface wave characteristics to a study of surface wave sustained discharges. In Chapter 4 we consider the 1d3v plasma which is sustained at the

  18. High-frequency electron resonances and surface waves in unmagnetized bounded plasmas

    NASA Astrophysics Data System (ADS)

    Bowers, Kevin James

    2001-10-01

    As all laboratory and industrial plasma devices have boundaries, understanding the plasma-wall interaction is critical. This thesis explores high frequency (beyond the ion plasma frequency) resonances and surface waves in unmagnetized bounded plasmas. Special emphasis is placed on low-temperature plasmas in planar systems as such are useful for materials processing. Chapter 1, Chapter 2 and Chapter 3 conduct simulation studies of electron series resonance sustained discharges with comparisons to theory and experiment. These plasmas have many desirable characteristics (resistive V-I phase, frequency tunable density, low-temperature, low- pressure). Surface wave plasmas are the natural extension to resonant plasmas and are promising for use in large-area plasma sources. Appropriate for large-area device modeling, an electromagnetic theory of surface wave propagation in a warm non-uniform plasma is developed and compared to previous theoretical work (Chapter 4 and Chapter 5). In Chapter 6, several PIC simulations are conducted to validate the electromagnetic theory. In Chapter 7, numerical techniques suitable for computing the wave dispersion and impedance in a large-area low- temperature plasma are developed. Utilizing much of the research conducted here, Chapter 8 demonstrates a novel application of surface waves. Through a resonant wave-particle interaction (``Landau resonant heating''), the electron velocity distribution function is controllably modified by a standing surface wave excited with a distributed periodic electrode. Simulation results indicate this Landau resonant heating can be used to dramatically enhance important reactions in low-temperature low- pressure plasmas including electron-impact excitation and electron-impact ionization. In conducting this research, an algorithm to effectively eliminate cache thrashing in a particle-in-cell simulation was developed, resulting in a 40 to 70 percent performance gain on typical workstations. The algorithm is

  19. Kinetic interpretation of resonance phenomena in low pressure capacitively coupled radio frequency plasmas

    NASA Astrophysics Data System (ADS)

    Wilczek, Sebastian; Trieschmann, Jan; Eremin, Denis; Brinkmann, Ralf Peter; Schulze, Julian; Schuengel, Edmund; Derzsi, Aranka; Korolov, Ihor; Hartmann, Peter; Donkó, Zoltán; Mussenbrock, Thomas

    2016-06-01

    Low pressure capacitive radio frequency (RF) plasmas are often described by equivalent circuit models based on fluid approaches that predict the self-excitation of resonances, e.g., high frequency oscillations of the total current in asymmetric discharges, but do not provide a kinetic interpretation of these effects. In fact, they leave important questions open: How is current continuity ensured in the presence of energetic electron beams generated by the expanding sheaths that lead to a local enhancement of the conduction current propagating through the bulk? How do the beam electrons interact with cold bulk electrons? What is the kinetic origin of resonance phenomena? Based on kinetic simulations, we find that the energetic beam electrons interact with cold bulk electrons (modulated on a timescale of the inverse local electron plasma frequency) via a time dependent electric field outside the sheaths. This electric field is caused by the electron beam itself, which leaves behind a positive space charge, that attracts cold bulk electrons towards the expanding sheath. The resulting displacement current ensures current continuity by locally compensating the enhancement of the conduction current. The backflow of cold electrons and their interaction with the nonlinear plasma sheath cause the generation of multiple electron beams during one phase of sheath expansion and contribute to a strongly non-sinusoidal RF current. These kinetic mechanisms are the basis for a fundamental understanding of the electron power absorption dynamics and resonance phenomena in such plasmas, which are found to occur in discharges of different symmetries including perfectly symmetric plasmas.

  20. Frequency of cell treatment with cold microwave argon plasma is important for the final outcome

    NASA Astrophysics Data System (ADS)

    Sysolyatina, E.; Vasiliev, M.; Kurnaeva, M.; Kornienko, I.; Petrov, O.; Fortov, V.; Gintsburg, A.; Petersen, E.; Ermolaeva, S.

    2016-07-01

    The purpose of this work was to establish the influence of a regime of cold microwave argon plasma treatments on the physiological characteristics of human fibroblasts and keratinocytes. We used three regimes of plasma application: a single treatment, double treatment with a 48 h interval, and daily treatments for 3 d. Cell proliferation after plasma application was quantified in real time, and immunohistochemistry was used to establish the viability of the cells and determine changes in their physiology. It was established that the frequency of cell treatments is important for the outcome. In the samples treated with single plasma application and double plasma applications with a 48 h interval, a 42.6% and 32.0% increase was observed in the number of cells, respectively. In addition, there were no signs of deoxyribonucleic acid breaks immediately after plasma application. In contrast, plasma application increased the accumulation of cells in the active phases of the cell cycle. The activation of proliferation correlated with a decrease in the level of β-galactosidase, a senescence marker. This could be due to cell renovation after plasma application. Daily treatment decreased cell proliferation up to 29.1% in comparison with the control after 3 d.

  1. Preface to Special Topic: Advances in Radio Frequency Physics in Fusion Plasmas

    SciTech Connect

    Tuccillo, Angelo A.; Ceccuzzi, Silvio; Phillips, Cynthia K.

    2014-06-15

    It has long been recognized that auxiliary plasma heating will be required to achieve the high temperature, high density conditions within a magnetically confined plasma in which a fusion “burn” may be sustained by copious fusion reactions. Consequently, the application of radio and microwave frequency electromagnetic waves to magnetically confined plasma, commonly referred to as RF, has been a major part of the program almost since its inception in the 1950s. These RF waves provide heating, current drive, plasma profile control, and Magnetohydrodynamics (MHD) stabilization. Fusion experiments employ electromagnetic radiation in a wide range of frequencies, from tens of MHz to hundreds of GHz. The fusion devices containing the plasma are typically tori, axisymmetric or non, in which the equilibrium magnetic fields are composed of a strong toroidal magnetic field generated by external coils, and a poloidal field created, at least in the symmetric configurations, by currents flowing in the plasma. The waves are excited in the peripheral regions of the plasma, by specially designed launching structures, and subsequently propagate into the core regions, where resonant wave-plasma interactions produce localized heating or other modification of the local equilibrium profiles. Experimental studies coupled with the development of theoretical models and advanced simulation codes over the past 40+ years have led to an unprecedented understanding of the physics of RF heating and current drive in the core of magnetic fusion devices. Nevertheless, there are serious gaps in our knowledge base that continue to have a negative impact on the success of ongoing experiments and that must be resolved as the program progresses to the next generation devices and ultimately to “demo” and “fusion power plant.” A serious gap, at least in the ion cyclotron (IC) range of frequencies and partially in the lower hybrid frequency ranges, is the difficulty in coupling large amount of

  2. Preface to Special Topic: Advances in Radio Frequency Physics in Fusion Plasmas

    NASA Astrophysics Data System (ADS)

    Tuccillo, Angelo A.; Phillips, Cynthia K.; Ceccuzzi, Silvio

    2014-06-01

    It has long been recognized that auxiliary plasma heating will be required to achieve the high temperature, high density conditions within a magnetically confined plasma in which a fusion "burn" may be sustained by copious fusion reactions. Consequently, the application of radio and microwave frequency electromagnetic waves to magnetically confined plasma, commonly referred to as RF, has been a major part of the program almost since its inception in the 1950s. These RF waves provide heating, current drive, plasma profile control, and Magnetohydrodynamics (MHD) stabilization. Fusion experiments employ electromagnetic radiation in a wide range of frequencies, from tens of MHz to hundreds of GHz. The fusion devices containing the plasma are typically tori, axisymmetric or non, in which the equilibrium magnetic fields are composed of a strong toroidal magnetic field generated by external coils, and a poloidal field created, at least in the symmetric configurations, by currents flowing in the plasma. The waves are excited in the peripheral regions of the plasma, by specially designed launching structures, and subsequently propagate into the core regions, where resonant wave-plasma interactions produce localized heating or other modification of the local equilibrium profiles. Experimental studies coupled with the development of theoretical models and advanced simulation codes over the past 40+ years have led to an unprecedented understanding of the physics of RF heating and current drive in the core of magnetic fusion devices. Nevertheless, there are serious gaps in our knowledge base that continue to have a negative impact on the success of ongoing experiments and that must be resolved as the program progresses to the next generation devices and ultimately to "demo" and "fusion power plant." A serious gap, at least in the ion cyclotron (IC) range of frequencies and partially in the lower hybrid frequency ranges, is the difficulty in coupling large amount of power to the

  3. Noise Suppression and Enhanced Focusability in Plasma Raman Amplifier with Multi-frequency Pump

    SciTech Connect

    A.A. Balakin; G.M. Fraiman; N.J. Fisch; V.M. Malkin

    2003-06-16

    Laser pulse compression/amplification through Raman backscattering in plasmas can be facilitated by using multi-frequency pump laser beams. The efficiency of amplification is increased by suppressing the Raman instability of thermal fluctuations and seed precursors. Also the focusability of the amplified radiation is enhanced due to the suppression of large-scale longitudinal speckles in the pump wave structure.

  4. Capacitively Coupled Radio Frequency Discharge Plasmas In Hydrogen: Particle Modeling and Negative Ion Kinetics

    SciTech Connect

    Diomede, P.; Longo, S.; Capitelli, M.

    2005-05-16

    We present a 1D(r)2D(v) particle code for capacitively coupled radio frequency discharge plasmas in hydrogen, which includes a rigorous kinetic modeling of ion transport and several solutions to speed up the convergence. In a test case the effect of surface atom recombination and molecule vibrational deactivation on H- concentration is investigated.

  5. Complex utilization of snf processing wastes in air plasma of high-frequency torch discharge

    NASA Astrophysics Data System (ADS)

    Karengin, A. G.; Karengin, A. A.; Podgornaya, O. D.; Shlotgauer, E. E.

    2014-10-01

    We present results of complex spent nuclear fuel wastes utilization process in air plasma of high-frequency torch discharge in form of dispersed water-organic compositions. We demonstrate the possibility to apply magnetic separation for effective extraction of obtained dispersed solid products including magnetic iron oxide from water suspension.

  6. Changes in ENSO Frequency and Character as Recorded in NE Indian Speleothem Oxygen Isotopes

    NASA Astrophysics Data System (ADS)

    Oster, J. L.; Myers, C. G.; Breitenbach, S. F. M.; Sharp, W. D.

    2014-12-01

    Oxygen isotopes (δ18O) from speleothems in monsoon regions such as NE India have provided important records of monsoon strength on decadal to multi-millennial timescales. However, recent precipitation and cave drip water studies suggest that regional rain and drip water δ18O variability may be driven by changes in moisture sources and transport pathways rather than mainly reflecting changes in rainfall amount. Hence, we compare a modern δ18O speleothem time-series with historical meteorological records and global climate indices to identify dominant influences on speleothem δ18O.We have constructed a high resolution (7-8 samples per year) δ18O time-series using a stalagmite (MAW 02-01) from Mawmluh Cave in NE India that grew during the ~50 years preceding collection in 2013. U-series dates (±1-2 years) provide an age model and confirm that visible stalagmite laminations are approximately annual. We compared the stalagmite time-series with local meteorologic records and indices of the El Niño/Southern Oscillation (Niño3, Niño4) and the Indian Ocean Dipole (IOD). Our record shows no significant correlation with rainfall amount and reveals the same seasonal signal observed in local rain and drip water δ18O. We observe significant positive correlations, with a 6 month lag, between our dataset and the Niño4 Sea Surface Temperature (SST) index (r = 0.49, p < 0.001) and the IOD (r = 0.41, p < 0.001). A cross-wavelet analysis between MAW 02-01 δ18O and Niño4 highlights a shared 4-6 year frequency throughout and a strong in-phase 8-12 year frequency beginning in 1990 and persisting for the duration of the record. The latter may reflect an increase in strength and frequency of central Pacific (CP) El Niño events since 1990. Such events, with stronger SST anomalies in the central Pacific, are more likely to restrict Indian Summer Monsoon (ISM) strength through enhanced westward migration of the descending arm of the Walker Cell. HYSPLIT back-trajectory analysis

  7. High-frequency spectral distribution of the equilibrium radiation energy in a plasma

    NASA Astrophysics Data System (ADS)

    Bobrov, V. B.; Trigger, S. A.

    2016-04-01

    We establish that the difference of the spectral distribution of the equilibrium radiation energy in matter from the Planck formula in the high-frequency range is determined by the imaginary part of the transverse dielectric permittivity of the matter. Based on this, we show that in a rarified high-temperature fully ionized nonrelativistic plasma, the high-frequency spectral distribution of the equilibrium radiation energy differs essentially from the Planck formula because of the power-law character of the decrease in the frequency, which is due to the presence of matter.

  8. Etching mechanism of niobium in coaxial Ar/Cl{sub 2} radio frequency plasma

    SciTech Connect

    Upadhyay, J.; Im, Do; Popović, S.; Vušković, L.; Valente-Feliciano, A.-M.; Phillips, L.

    2015-03-21

    The understanding of the Ar/Cl{sub 2} plasma etching mechanism is crucial for the desired modification of inner surface of the three dimensional niobium (Nb) superconductive radio frequency cavities. Uniform mass removal in cylindrical shaped structures is a challenging task because the etch rate varies along the direction of gas flow. The study is performed in the asymmetric coaxial radio-frequency (rf) discharge with two identical Nb rings acting as a part of the outer electrode. The dependence of etch rate uniformity on pressure, rf power, dc bias, Cl{sub 2} concentration, diameter of the inner electrode, temperature of the outer cylinder, and position of the samples in the structure is determined. To understand the plasma etching mechanisms, we have studied several factors that have important influence on the etch rate and uniformity, which include the plasma sheath potential, Nb surface temperature, and the gas flow rate.

  9. Improved Frequency Fluctuation Model for Spectral Line Shape Calculations in Fusion Plasmas

    NASA Astrophysics Data System (ADS)

    Ferri, S.; Calisti, A.; Mossé, C.; Talin, B.; Lisitsa, V.

    2010-10-01

    A very fast method to calculate spectral line shapes emitted by plasmas accounting for charge particle dynamics and effects of an external magnetic field is proposed. This method relies on a new formulation of the Frequency Fluctuation Model (FFM), which yields to an expression of the dynamic line profile as a functional of the static distribution function of frequencies. This highly efficient formalism, not limited to hydrogen-like systems, allows to calculate pure Stark and Stark-Zeeman line shapes for a wide range of density, temperature and magnetic field values, which is of importance in plasma physics and astrophysics. Various applications of this method are presented for conditions related to fusion plasmas.

  10. Heating of ions by low-frequency Alfven waves in partially ionized plasmas

    SciTech Connect

    Dong Chuanfei; Paty, Carol S.

    2011-03-15

    In the solar atmosphere, the chromospheric and coronal plasmas are much hotter than the visible photosphere. The heating of the solar atmosphere, including the partially ionized chromosphere and corona, remains largely unknown. In this letter, we demonstrate that the ions can be substantially heated by Alfven waves with very low frequencies in partially ionized low-beta plasmas. This differs from other Alfven wave related heating mechanisms such as ion-neutral collisional damping of Alfven waves and heating described by previous work on resonant Alfven wave heating. We find that the nonresonant Alfven wave heating is less efficient in partially ionized plasmas than when there are no ion-neutral collisions, and the heating efficiency depends on the ratio of the ion-neutral collision frequency to the ion gyrofrequency.

  11. Higher order contribution to the propagation characteristics of low frequency transverse waves in a dusty plasma

    NASA Astrophysics Data System (ADS)

    Misra, A. P.; Chowdhury, A. Roy; Paul, S. N.

    2004-09-01

    Characteristic features of low frequency transverse wave propagating in a magnetised dusty plasma have been analysed considering the effect of dust-charge fluctu- ation. The distinctive behaviours of both the left circularly polarised and right circularly polarised waves have been exhibited through the analysis of linear and non-linear disper- sion relations. The phase velocity, group velocity, and group travel time for the waves have been obtained and their propagation characteristics have been shown graphically with the variations of wave frequency, dust density and amplitude of the wave. The change in non-linear wave number shift and Faraday rotation angle have also been exhibited with respect to the plasma parameters. It is observed that the effects of dust particles are significant only when the higher order contributions are considered. This may be referred to as the `dust regime' in plasma.

  12. Etching mechanism of niobium in coaxial Ar/Cl2 radio frequency plasma

    SciTech Connect

    Upadhyay, Janardan; Im, Do; Popovic, Svetozar; Valente-Feliciano, Anne -Marie; Phillips, H. Larry; Vuskovic, Leposova

    2015-03-18

    The understanding of the Ar/Cl2 plasma etching mechanism is crucial for the desired modification of inner surface of the three dimensional niobium (Nb) superconductive radio frequency cavities. Uniform mass removal in cylindrical shaped structures is a challenging task because the etch rate varies along the direction of gas flow. The study is performed in the asymmetric coaxial radio-frequency (rf) discharge with two identical Nb rings acting as a part of the outer electrode. The dependence of etch rate uniformity on pressure, rf power, dc bias, Cl2 concentration, diameter of the inner electrode, temperature of the outer cylinder, and position of the samples in the structure is determined. Furthermore, to understand the plasma etching mechanisms, we have studied several factors that have important influence on the etch rate and uniformity, which include the plasma sheath potential, Nb surface temperature, and the gas flow rate.

  13. Focused excimer laser initiated and radio frequency sustained plasma formation in high pressure air

    NASA Astrophysics Data System (ADS)

    Giar, Ryan

    A doctoral thesis project was performed to experimentally investigate the feasibility of focused excimer laser initiation of air plasmas for radio frequency sustainment. A 193 nm, 15 MW, 300 mJ laser was focused with a 18 cm focal length lens to form a small, high density (ne ~ 10 14 cm--3) seed plasma. These laser plasmas were produced inside a borosilicate glass tube around which was wrapped a 5 turn helical antenna. This antenna was powered with 5 kW of 13.56 MHz of radiation for 1.5 s. This was accomplished at a pressure of 22 Torr, resulting in a large volume (300 cm3) air plasma. Diagnostic measurements of this air plasma determined an electron density of 5E10 cm-3 and an electron temperature 1.3 eV with a neutral temperature of 3500 K. The collision frequency was measured to be 9E10 Hz which resulted in a plasma-loaded antenna resistance of 6 O with a voltage reflection coefficient of 0.7.

  14. Influence of wall plasma on microwave frequency and power in relativistic backward wave oscillator

    SciTech Connect

    Sun, Jun; Cao, Yibing; Teng, Yan; Zhang, Yuchuan; Chen, Changhua; Wu, Ping

    2015-07-15

    The RF breakdown of the slow wave structure (SWS), which will lead to the generation of the wall plasma, is an important cause for pulse shortening in relativistic backward wave oscillators. Although many researchers have performed profitable studies about this issue, the influence mechanism of this factor on the microwave generation still remains not-so-clear. This paper simplifies the wall plasma with an “effective” permittivity and researches its influence on the microwave frequency and power. The dispersion relation of the SWS demonstrates that the introduction of the wall plasma will move the dispersion curves upward to some extent, which is confirmed by particle-in-cell (PIC) simulations and experiments. The plasma density and volume mainly affect the dispersion relation at the upper and lower frequency limits of each mode, respectively. Meanwhile, PIC simulations show that even though no direct power absorption exists since the wall plasma is assumed to be static, the introduction of the wall plasma may also lead to the decrease in microwave power by changing the electrodynamic property of the SWS.

  15. Reactive Ion Etching of Polymers in Oxygen Based Plasmas: a Study of Etch Mechanisms.

    NASA Astrophysics Data System (ADS)

    Graham, Sandra Wolterman

    The reactive ion etching of polymers has been studied in oxygen-based plasmas in an effort to understand the contributions of various mechanisms to the etching of these materials. Of the four active etch mechanisms; surface damage promoted etching, chemical sputtering, chemically enhanced physical sputtering, and direct reactive ion etching; the emphasis of this work has been on determining the relative contribution of direct reactive ion etching to the overall etching process. The etching of photoresist, polyimide, and amorphous carbon in O_2-CF_4 plasmas was studied in an asymmetrical reactive ion etcher at pressures ranging from 5 to 100 mtorr. Etch yield, ion flux, and oxygen atom concentration data were collected. The fit of this data to a linear model proposed by Joubert et al. (J. Appl. Phys., 65, 1989, 5096) was compared to the fit of the data to a nonlinear model proposed by the author. The linear model accounts for contribution due to three of the four etch mechanisms, but does not include contributions due to direct reactive ion etching. The nonlinear model accounts for contributions due to all four etch mechanisms. Experimental results indicate that the nonlinear model provides a better fit to the data than does the linear model. The relative contribution of direct reactive ion etching to the etching of photoresist ranges from 27% to 81% as the pressure decreases from 100 to 5 mtorr. Similar results are obtained for polyimide and amorphous carbon.

  16. Impact of plasma jet vacuum ultraviolet radiation on reactive oxygen species generation in bio-relevant liquids

    SciTech Connect

    Jablonowski, H.; Hammer, M. U.; Reuter, S.; Bussiahn, R.; Weltmann, K.-D.; Woedtke, Th. von

    2015-12-15

    Plasma medicine utilizes the combined interaction of plasma produced reactive components. These are reactive atoms, molecules, ions, metastable species, and radiation. Here, ultraviolet (UV, 100–400 nm) and, in particular, vacuum ultraviolet (VUV, 10–200 nm) radiation generated by an atmospheric pressure argon plasma jet were investigated regarding plasma emission, absorption in a humidified atmosphere and in solutions relevant for plasma medicine. The energy absorption was obtained for simple solutions like distilled water (dH{sub 2}O) or ultrapure water and sodium chloride (NaCl) solution as well as for more complex ones, for example, Rosewell Park Memorial Institute (RPMI 1640) cell culture media. As moderate stable reactive oxygen species, hydrogen peroxide (H{sub 2}O{sub 2}) was studied. Highly reactive oxygen radicals, namely, superoxide anion (O{sub 2}{sup •−}) and hydroxyl radicals ({sup •}OH), were investigated by the use of electron paramagnetic resonance spectroscopy. All species amounts were detected for three different treatment cases: Plasma jet generated VUV and UV radiation, plasma jet generated UV radiation without VUV part, and complete plasma jet including all reactive components additionally to VUV and UV radiation. It was found that a considerable amount of radicals are generated by the plasma generated photoemission. From the experiments, estimation on the low hazard potential of plasma generated VUV radiation is discussed.

  17. Impact of plasma jet vacuum ultraviolet radiation on reactive oxygen species generation in bio-relevant liquids

    NASA Astrophysics Data System (ADS)

    Jablonowski, H.; Bussiahn, R.; Hammer, M. U.; Weltmann, K.-D.; von Woedtke, Th.; Reuter, S.

    2015-12-01

    Plasma medicine utilizes the combined interaction of plasma produced reactive components. These are reactive atoms, molecules, ions, metastable species, and radiation. Here, ultraviolet (UV, 100-400 nm) and, in particular, vacuum ultraviolet (VUV, 10-200 nm) radiation generated by an atmospheric pressure argon plasma jet were investigated regarding plasma emission, absorption in a humidified atmosphere and in solutions relevant for plasma medicine. The energy absorption was obtained for simple solutions like distilled water (dH2O) or ultrapure water and sodium chloride (NaCl) solution as well as for more complex ones, for example, Rosewell Park Memorial Institute (RPMI 1640) cell culture media. As moderate stable reactive oxygen species, hydrogen peroxide (H2O2) was studied. Highly reactive oxygen radicals, namely, superoxide anion (O2•-) and hydroxyl radicals (•OH), were investigated by the use of electron paramagnetic resonance spectroscopy. All species amounts were detected for three different treatment cases: Plasma jet generated VUV and UV radiation, plasma jet generated UV radiation without VUV part, and complete plasma jet including all reactive components additionally to VUV and UV radiation. It was found that a considerable amount of radicals are generated by the plasma generated photoemission. From the experiments, estimation on the low hazard potential of plasma generated VUV radiation is discussed.

  18. Trapped electron plasma formation and equilibrium with a low-power radio-frequency drive

    SciTech Connect

    Romé, M.; Maero, G.; Paroli, B.; Pozzoli, R.; Chen, S.

    2015-06-29

    Penning-Malmberg traps confining electron plasmas usually rely on external sources like thermo- and photocathodes. It has been already demonstrated that electron plasmas of comparable densities can be produced by applying a radio-frequency (RF) power to any inner electrode of the trap. Such excitation may result in significant electron heating and ionization of the residual gas with the formation of a plasma column when the RF frequency is of the order or larger than the typical axial bounce frequencies of few-eV electrons, even at RF amplitude of few volts. While discharges are common in plasma generation at higher pressures and RF power, this mechanism is not yet well explored in our working conditions, namely ultra-high vacuum and very low RF power. This plasma production mechanism is very sensitive to the experimental conditions. Interesting phenomena can be observed: transition from a diffuse to a narrow-section, denser plasma column; presence of low-order diocotron modes in transient and steady-state plasmas; modulation of the m=1 diocotron mode and suppression of its instability despite the presence of positive ions and resistive loads. These observations are reported here, and possible explanations are discussed. In addition, a possible electron heating mechanism is investigated with a single-particle, one-dimensional model described by an area-preserving map where an electron bounces within a square potential well and the RF excitation is modelled by a time-oscillating square barrier. The low-energy part of the Poincaré plot includes both quasi-periodic and chaotic regions, where heating up to ionization energies is achievable. Results of a systematic analysis of the map extracting its chaotic properties and scaling laws as a function of the control parameters are reported.

  19. Kinetic theory of low-frequency cross-field instability in a weakly ionized plasma. II

    SciTech Connect

    Dimant, Y.S.; Sudan, R.N.

    1995-04-01

    The consistent kinetic approach developed in Paper I [Ya. S. Dimant and R. N. Sudan, Phys. Plasmas {bold 2}, 1157 (1995)] is applied to obtain the general dispersion relation of the two-stream {bold E}{times}{bold B} instability in collisionally dominated weakly ionized plasmas for wave frequencies small compared to the ion--neutral collision frequency. This dispersion relation covers the whole low-frequency band from the asymptotic short-wave limit studied in Paper I to the long-wave limit. Previous theories employing simplified kinetic theory or fluid equations for electron behavior are only correct in the long-wave limit. The principal new results are that the threshold conditions for this instability and the growth rates are altered from those predicted by earlier simplified theories. {copyright} {ital 1995} {ital American} {ital Institute} {ital of} {ital Physics}.

  20. Study of the Au Schottky contact formation on oxygen plasma treated n-type SnO{sub 2} (101) thin films

    SciTech Connect

    Nagata, Takahiro; Bierwagen, Oliver; White, Mark E.; Speck, James S.; Tsai, Min-Ying

    2010-02-15

    As-grown and oxygen plasma treated n-type tin dioxide (SnO{sub 2}) (101) thin films were investigated regarding the properties of Au contacts, surface structure, and band bending. The plasma treatment was performed in a conventional oxygen plasma cleaning system with maximum oxygen ion energies of 400 eV. Whereas the as-deposited SnO{sub 2} film formed non-Schottky contacts with Au, the oxygen plasma treated films formed Schottky contacts with Au. Capacitance-voltage and differential Hall measurements indicated the introduction of bulk electron traps up to several 100 nm below the surface due to the oxygen plasma treatment. Angle resolved x-ray photoelectron spectroscopy (AR-XPS) revealed a surface accumulation layer on the as-grown film that was absent after the plasma treatment. These measurements further revealed chemical differences between the as-deposited and the plasma treated SnO{sub 2} surfaces. All SnO{sub 2} films had Sn{sup 2+}-O bonds. The AR-XPS Sn{sup 2+}-O signal intensity increased after plasma treatment, indicating that the oxygen plasma damaged the SnO{sub 2} surface. Additionally, an O{sub 2} adlayer was formed due to the oxygen plasma treatment. The damaged layer due to oxygen ion bombardment, oxygen adsorption layer, and possibly bulk traps depleted the surface carriers which enabled the formation of a Schottky contact with Au.

  1. Reactive hydroxyl radical-driven oral bacterial inactivation by radio frequency atmospheric plasma

    NASA Astrophysics Data System (ADS)

    Kang, Sung Kil; Choi, Myeong Yeol; Koo, Il Gyo; Kim, Paul Y.; Kim, Yoonsun; Kim, Gon Jun; Mohamed, Abdel-Aleam H.; Collins, George J.; Lee, Jae Koo

    2011-04-01

    We demonstrated bacterial (Streptococcus mutans) inactivation by a radio frequency power driven atmospheric pressure plasma torch with H2O2 entrained in the feedstock gas. Optical emission spectroscopy identified substantial excited state •OH generation inside the plasma and relative •OH formation was verified by optical absorption. The bacterial inactivation rate increased with increasing •OH generation and reached a maximum 5-log10 reduction with 0.6% H2O2 vapor. Generation of large amounts of toxic ozone is drawback of plasma bacterial inactivation, thus it is significant that the ozone concentration falls within recommended safe allowable levels with addition of H2O2 vapor to the plasma.

  2. Self-precession and frequency shift for electromagnetic waves in homogeneous plasmas

    NASA Technical Reports Server (NTRS)

    Arons, J.; Max, C. E.

    1974-01-01

    The nonlinear propagation of an arbitrarily polarized electromagnetic wave in a uniform plasma is studied. It is shown that nonlinear effects cause precession of the polarization ellipse as the wave propagates. The ellipticity remains constant, but the orientation of the principal axes is rotated relative to its initial value. A relativistic Vlasov model is used to study nonlinear frequency shifts as well as self-precession, in a plasma of arbitrary temperature. Even when the electron temperature is much greater than the product of the electron mass times the square of the velocity of light, the qualitative nature of these two processes remains unchanged, although their dependence on the plasma density is altered in significant ways. Implications of these effects for plasma instabilities driven by strong electromagnetic waves are briefly discussed.

  3. Microwave frequency sweep interferometer for plasma density measurements in ECR ion sources: Design and preliminary results

    NASA Astrophysics Data System (ADS)

    Torrisi, Giuseppe; Mascali, David; Neri, Lorenzo; Leonardi, Ornella; Sorbello, Gino; Celona, Luigi; Castro, Giuseppe; Agnello, Riccardo; Caruso, Antonio; Passarello, Santi; Longhitano, Alberto; Isernia, Tommaso; Gammino, Santo

    2016-02-01

    The Electron Cyclotron Resonance Ion Sources (ECRISs) development is strictly related to the availability of new diagnostic tools, as the existing ones are not adequate to such compact machines and to their plasma characteristics. Microwave interferometry is a non-invasive method for plasma diagnostics and represents the best candidate for plasma density measurement in hostile environment. Interferometry in ECRISs is a challenging task mainly due to their compact size. The typical density of ECR plasmas is in the range 1011-1013 cm-3 and it needs a probing beam wavelength of the order of few centimetres, comparable to the chamber radius. The paper describes the design of a microwave interferometer developed at the LNS-INFN laboratories based on the so-called "frequency sweep" method to filter out the multipath contribution in the detected signals. The measurement technique and the preliminary results (calibration) obtained during the experimental tests will be presented.

  4. Microwave frequency sweep interferometer for plasma density measurements in ECR ion sources: Design and preliminary results.

    PubMed

    Torrisi, Giuseppe; Mascali, David; Neri, Lorenzo; Leonardi, Ornella; Sorbello, Gino; Celona, Luigi; Castro, Giuseppe; Agnello, Riccardo; Caruso, Antonio; Passarello, Santi; Longhitano, Alberto; Isernia, Tommaso; Gammino, Santo

    2016-02-01

    The Electron Cyclotron Resonance Ion Sources (ECRISs) development is strictly related to the availability of new diagnostic tools, as the existing ones are not adequate to such compact machines and to their plasma characteristics. Microwave interferometry is a non-invasive method for plasma diagnostics and represents the best candidate for plasma density measurement in hostile environment. Interferometry in ECRISs is a challenging task mainly due to their compact size. The typical density of ECR plasmas is in the range 10(11)-10(13) cm(-3) and it needs a probing beam wavelength of the order of few centimetres, comparable to the chamber radius. The paper describes the design of a microwave interferometer developed at the LNS-INFN laboratories based on the so-called "frequency sweep" method to filter out the multipath contribution in the detected signals. The measurement technique and the preliminary results (calibration) obtained during the experimental tests will be presented. PMID:26932081

  5. Reactive hydroxyl radical-driven oral bacterial inactivation by radio frequency atmospheric plasma

    SciTech Connect

    Kang, Sung Kil; Lee, Jae Koo; Choi, Myeong Yeol; Koo, Il Gyo; Kim, Paul Y.; Kim, Yoonsun; Kim, Gon Jun; Collins, George J.; Mohamed, Abdel-Aleam H.

    2011-04-04

    We demonstrated bacterial (Streptococcus mutans) inactivation by a radio frequency power driven atmospheric pressure plasma torch with H{sub 2}O{sub 2} entrained in the feedstock gas. Optical emission spectroscopy identified substantial excited state OH generation inside the plasma and relative OH formation was verified by optical absorption. The bacterial inactivation rate increased with increasing OH generation and reached a maximum 5-log{sub 10} reduction with 0.6%H{sub 2}O{sub 2} vapor. Generation of large amounts of toxic ozone is drawback of plasma bacterial inactivation, thus it is significant that the ozone concentration falls within recommended safe allowable levels with addition of H{sub 2}O{sub 2} vapor to the plasma.

  6. In vivo stimulation of bone formation by aluminum and oxygen plasma surface-modified magnesium implants.

    PubMed

    Wong, Hoi Man; Zhao, Ying; Tam, Vivian; Wu, Shuilin; Chu, Paul K; Zheng, Yufeng; To, Michael Kai Tsun; Leung, Frankie K L; Luk, Keith D K; Cheung, Kenneth M C; Yeung, Kelvin W K

    2013-12-01

    A newly developed magnesium implant is used to stimulate bone formation in vivo. The magnesium implant after undergoing dual aluminum and oxygen plasma implantation is able to suppress rapid corrosion, leaching of magnesium ions, as well as hydrogen gas release from the biodegradable alloy in simulated body fluid (SBF). No released aluminum is detected from the SBF extract and enhanced corrosion resistance properties are confirmed by electrochemical tests. In vitro studies reveal enhanced growth of GFP mouse osteoblasts on the aluminum oxide coated sample, but not on the untreated sample. In addition to that a small amount (50 ppm) of magnesium ions can enhance osteogenic differentiation as reported previously, our present data show a low concentration of hydrogen can give rise to the same effect. To compare the bone volume change between the plasma-treated magnesium implant and untreated control, micro-computed tomography is performed and the plasma-treated implant is found to induce significant new bone formation adjacent to the implant from day 1 until the end of the animal study. On the contrary, bone loss is observed during the first week post-operation from the untreated magnesium sample. Owing to the protection offered by the Al2O3 layer, the plasma-treated implant degrades more slowly and the small amount of released magnesium ions stimulate new bone formation locally as revealed by histological analyses. Scanning electron microscopy discloses that the Al2O3 layer at the bone-implant interface is still present two months after implantation. In addition, no inflammation or tissue necrosis is observed from both treated and untreated implants. These promising results suggest that the plasma-treated magnesium implant can stimulate bone formation in vivo in a minimal invasive way and without causing post-operative complications. PMID:24060425

  7. Titanium dioxide nanoparticles increase plasma glucose via reactive oxygen species-induced insulin resistance in mice.

    PubMed

    Hu, Hailong; Guo, Qian; Wang, Changlin; Ma, Xiao; He, Hongjuan; Oh, Yuri; Feng, Yujie; Wu, Qiong; Gu, Ning

    2015-10-01

    There have been few reports about the possible toxic effects of titanium dioxide (TiO2 ) nanoparticles on the endocrine system. We explored the endocrine effects of oral administration to mice of anatase TiO2 nanoparticles (0, 64 and 320 mg kg(-1) body weight per day to control, low-dose and high-dose groups, respectively, 7 days per week for 14 weeks). TiO2 nanoparticles were characterized by scanning and transmission electron microscopy (TEM) and dynamic light scattering (DLS), and their physiological distribution was investigated by inductively coupled plasma. Biochemical analyzes included plasma glucose, insulin, heart blood triglycerides (TG), free fatty acid (FFA), low-density lipoprotein cholesterol (LDL-C), high-density lipoprotein cholesterol (HDL-C), total cholesterol (TC), tumor necrosis factor-alpha (TNF-α), interleukin (IL)-6 and reactive oxygen species (ROS)-related markers (total SOD, GSH and MDA). Phosphorylation of IRS1, Akt, JNK1, and p38 MAPK were analyzed by western blotting. Increased titanium levels were found in the liver, spleen, small intestine, kidney and pancreas. Biochemical analyzes showed that plasma glucose significantly increased whereas there was no difference in plasma insulin secretion. Increased ROS levels were found in serum and the liver, as evidenced by reduced total SOD activity and GSH level and increased MDA content. Western blotting showed that oral administration of TiO2 nanoparticles induced insulin resistance (IR) in mouse liver, shown by increased phosphorylation of IRS1 (Ser307) and reduced phosphorylation of Akt (Ser473). The pathway by which TiO2 nanoparticles increase ROS-induced IR were included in the inflammatory response and phosphokinase, as shown by increased serum levels of TNF-α and IL-6 and increased phosphorylation of JNK1 and p38 MAPK in liver. These results show that oral administration of TiO2 nanoparticles increases ROS, resulting in IR and increasing plasma glucose in mice. PMID:25826740

  8. Excitation of Josephson Plasma Resonance in BISMUTH(2) STRONTIUM(2) Calcium COPPER(2) OXYGEN(8+DELTA)

    NASA Astrophysics Data System (ADS)

    Tsui, Ophelia Kwan Chui

    A novel magnetic resonance is observed in Bi_2Sr_2CaCu_2O_{8+ delta} single crystals exposed to microwave radiation (26 to 95 GHz) in the presence of a magnetic field. The resonance exhibits unconventional field and temperature dependence. At a fixed temperature below the melting transition of the vortex solid, T_ {m}(B), the resonance frequency decreases with the applied field and displays a power-law dependence, viz. omega~ B^{-mu }. The exponent was found to be 0.8 within 10% across all samples and temperatures studied. However, when the temperature is increased above T_ {m}(B), mu becomes sample dependent and is equal to 0.64 and 1.08 for the two samples studied. At fixed microwave frequencies, the resonance field, B_0 increases exponentially with temperature to a maximum at T_{m }(B) and decreases slowly with temperature above. We attribute the resonance to Josephson plasma oscillations excited along the sample c-axis. The model explains many features of the experiment. Recently, Bulaevskii et al. proposed an explanation for the field dependence of the Josephson plasma frequency. By assuming that disorder in vortex pancakes is caused by strong pinning at low temperatures, the authors obtained the power-law dependence of omega on B, which agrees with the experiment. Rotating the microwave E-field, { bf E}_{rf} relatively to the sample, we find maximum resonance absorption when {bf E}_{rf} has the maximum projection along the sample c-axis, and minimum when there is none. This identification of {bf E}_{rf} parallel to the sample c-axis as the one responsible for the resonance, supports the Josephson plasma hypothesis. The strongest evidence for the Josephson plasma model is obtained by tilting the magnetic field close to alignment with the ab-plane of the crystal. In that case, an unusual re-entrant cusp in B_0 is observed when the tilt angle is in the range -5.5^circ to 5.5^circ. This is consistent with Bulaevskii et al.'s calculation. They propose that pancake

  9. STUDENT AWARD FINALIST: Oxygen Pathways in Streamer Discharge for Transient Plasma Ignition

    NASA Astrophysics Data System (ADS)

    Pendleton, S. J.; Bowman, S.; Singleton, D.; Watrous, J.; Carter, C.; Lempert, W.; Gundersen, M. A.

    2011-10-01

    The use of streamers for the ignition of fuels, also known as transient plasma ignition (TPI), has been shown in a variety of engines to improve combustion through decreased ignition delay, increased lean burn capability and increased energy release relative to conventional spark ignition. The mechanisms behind these improvements, however, remain poorly understood. Temperature measurements by optical emission spectroscopy demonstrate that ignition by TPI is a nonthermal process, and thus is almost entirely dependent on the production and presence of electron impact-created active species in the discharge afterglow. Of particular interest are active oxygen species due to their relatively long lifetimes at high pressures and the pivotal role they play in combustion reactions. In order to elucidate the oxygen pathways, here we report the investigation of the temporal evolution of the populations of atomic oxygen and ozone by use of two-photon absorption laser induced fluorescence (TALIF) and UV absorption, respectively. Experimental results are presented and compared to kinetic modeling of the streamers. Future experiments are proposed to better understand the physics behind TPI. Supported by NSF, AFOSR, NumerEx-ONR, AFRL-WPAFB.

  10. Optical emission spectroscopy of oxygen plasma induced by IR CO2 pulsed laser

    NASA Astrophysics Data System (ADS)

    Camacho, J. J.; Santos, M.; Díaz, L.; Poyato, J. M. L.

    2008-11-01

    Laser-induced breakdown (LIB) spectroscopy in oxygen at room temperature and pressures ranging from 4.6 to 75 kPa was studied using a high-power transverse excitation atmospheric CO2 laser (λ = 9.621 and 10.591 µm τFWHM = 64 ns; power densities ranging from 0.87 to 6.31 GW cm-2). The spectrum of the generated plasma is dominated by emission of strong O, O+ and weak O2+ atomic lines. Excitation temperatures of 31 500 ± 1600 K and 23 000 ± 3000 K were estimated by means of O2+ and O+ ionic lines, respectively. Electron number densities of the order of (3.5-16.5) × 1016 cm-3 were deduced from the Stark broadening of several ionic O+ lines. The characteristics of the spectral emission intensities from different species have been investigated as functions of the oxygen pressure and laser irradiance. Optical breakdown threshold intensities in O2 at 10.591 µm have been determined. The physical processes leading to LIB of oxygen have been analysed.

  11. Pulsed and continuous wave acrylic acid radio frequency plasma deposits: plasma and surface chemistry.

    PubMed

    Voronin, Sergey A; Zelzer, Mischa; Fotea, Catalin; Alexander, Morgan R; Bradley, James W

    2007-04-01

    Plasma polymers have been formed from acrylic acid using a pulsed power source. An on-pulse duration of 100 micros was used with a range of discharge off-times between 0 (continuous wave) and 20,000 micros. X-ray photoelectron spectroscopy (XPS) has been used in combination with trifluoroethanol (TFE) derivatization to quantify the surface concentration of the carboxylic acid functionality in the deposit. Retention of this functionality from the monomer varied from 2% to 65%. When input power was expressed as the time-averaged energy per monomer molecule, E(mean), the deposit chemistry achieved could be described using a single relationship for all deposition conditions. Deposition rates were monitored using a quartz crystal microbalance, which revealed a range from 20 to 200 microg m(-2) s(-1), and these fell as COOH functional retention increased. The flow rate was found to be the major determinant of the deposition rate, rather than being uniquely defined by E(mean), connected to the rate at which fresh monomer enters the system in the monomer deficient regime. The neutral species were collected in a time-averaged manner. As the energy delivered per molecule in the system (E(mean)) decreased, the amount of intact monomer increased, with the average neutral mass approaching 72 amu as E(mean) tends to zero. No neutral oligomeric species were detected. Langmuir probes have been used to determine the temporal evolution of the density and temperature of the electrons in the plasma and the plasma potential adjacent to the depositing film. It has been found that even 500 micros into the afterglow period that ionic densities are still significant, 5-10% of the on-time density, and that ion accelerating sheath potentials fall from 40 V in the on-time to a few volts in the off-time. We have made the first detailed, time- and energy-resolved mass spectrometry measurements in depositing acrylic acid plasma. These have allowed us to identify and quantify the positive ion

  12. Surfatron Plasma Source Working at Frequency 2.45 GHz for Technological Applications

    SciTech Connect

    Stranak, V.; Tichy, M.; Blazek, J.; Adamek, P.; Navratil, Z.; Slavicek, P.; Spatenka, P.

    2006-01-15

    Plasma as an active medium is widely exploited in technological applications. We have developed a microwave plasma source which might be suitable for future technological application. Plasma is generated by commercial (Sairem) surfatron working at frequency 2.45 GHz. The surfatron is fed by microwave power in the range from several watts up to 300 watts. Plasma is created from working gas mixture; typical flow rate is kept constant at 600 sccm. Technical Ar is used as carrier gas, O2 or N2 as reactive gases. We present complex diagnostics of the plasma created by this plasma source: by means of Langmuir probe measurements and by optical emission spectroscopy. Single probe method was used for determination of basic plasma parameters (plasma potential Vpl, mean electron energy Em, electron density ne, electron temperature) at low pressures. For determination of electron temperature at higher pressures when ion-neutral collision processes in the probe sheath had to be taken into account the double probe method was used. The discharge plasma was investigated and the results are discussed in cw as well as in computer-controlled impulse regime (time-resolved measurements). The pulse regime of plasma source is one of the ways how to increase an instantaneous input power and at the same time prevent treated materials (especially thermal sensitive materials, e.g. plastics) against thermal damage. Rotational and vibrational temperatures as well as consistence of discharge and axial intensity development of particular spectral lines were revealed on base of optical emission spectroscopy in cw regime.

  13. Hyperbaric oxygen increases plasma exudation in rat trachea: involvement of nitric oxide

    PubMed Central

    Bernareggi, M; Radice, S; Rossoni, G; Oriani, G; Chiesara, E; Berti, F

    1999-01-01

    This study investigates the microvascular permeability changes in tracheal tissue of rats exposed to hyperbaric oxygen (HBO). Rats, following exposure to HBO or ambient air (control animals) for 1.5, 3 and 6 h, were prepared for recording of nitric oxide exhaled (FENO) in air using a chemiluminescence analyser. The level of FENO was not statistically different in the two groups. Plasma exudation, evaluated by measuring the leakage of Evans blue (EB) dye into the tracheal tissue, was significantly elevated (48, 86 and 105% at 1.5, 3 and 6 h, respectively) in HBO-treated rats. Plasma exudation in the trachea of control rats was significantly increased (42%, P<0.05) by NG-nitro-L-arginine methyl ester (L-NAME), whereas it was significantly reduced (31%, P<0.05) in rats exposed to HBO for 3 h. N-acetylcysteine (NAC) and flunisolide significantly prevented the increase in plasma leakage in HBO-treated rats. In contrast, indomethacin was devoid of anti-exudative activity in these experiments. Western immunoblot showed a significant increase in the level of inducible nitric oxide synthase (iNOS) protein in the tracheal homogenates of HBO-treated rats, as compared to basal levels. These results indicate that nitric oxide (NO) is involved in the maintenance of microvascular permeability in tracheal tissue of rats. The protective effect observed with the steroid seems to support this hypothesis. Furthermore, the beneficial action of NAC underlines that reactive oxygen species participate in the microvascular permeability changes observed in tracheal tissue of rats exposed to HBO. PMID:10188993

  14. Design, implementation, and applications of devices for generation of ultra high frequency miniature plasmas

    NASA Astrophysics Data System (ADS)

    Taghioskoui, Mazdak

    The main objectives of this research are: (1) to develop novel and application-specific sources for generation of ultra-high frequency miniature plasmas that operate in a wide pressure range (˜1 to 760 Torr) with power requirement of less than 10 W, (2) to investigate the active species of such miniature plasma sources using mass spectrometry and optical emission spectroscopy, and (3) to explore novel applications of such miniature plasma sources with an emphasis on their application in chemical analysis for identification of gaseous species and volatile organic compounds. First, a miniature inductively coupled plasma (ICP) sources was developed, operating at a pressure of 1 to 10 Torr and a power requirement of 2--8 W with carbon dioxide, helium and argon as the plasma gas. The plasma impedance was measured using Smith chart. Furthermore, the background emission of the miniature ICP sources was monitored to investigate the species in the carbon dioxide, argon, and helium miniature ICPs. Ethylene, neon, and hydrogen were introduced separately into the miniature carbon dioxide ICP for qualitative identification. Distinguishable peaks were observed at approximately 431, 585, and 656 nm for ethylene, neon, and hydrogen, respectively. Second, a miniature ICP operating under conditions mimicking the Martian atmosphere was investigated. The miniature ICP source was able to generate a stable plasma, operating at a pressure range of 4 to 16 Torr and a power requirement of less than 3.5 W. The quantitative analysis of trace amounts of methane sample was performed by interfacing the miniature ICP with a quadrupole mass spectrometer. The effects of pressure, plasma power, and skimmer voltage were investigated and optimized for obtaining analytical results. Excellent calibration curves were obtained for CH3+ at m/z of 15. A detection limit of 0.15 ppm for CH3 + at 16 Torr was achieved using a quadrupole mass spectrometer. In addition, a magnetic loop antenna was used to

  15. Suppression of ionization instability in a magnetohydrodynamic plasma by coupling with a radio-frequency electromagnetic field

    SciTech Connect

    Murakami, Tomoyuki; Okuno, Yoshihiro; Yamasaki, Hiroyuki

    2005-05-09

    We describe the suppression of ionization instability and the control of a magnetohydrodynamic electrical power-generating plasma by coupling with a radio-frequency (rf) electromagnetic field. The rf heating stabilizes the unstable plasma behavior and homogenizes the nonuniform plasma structure, whereby the power-generating performance is significantly improved.

  16. Low-frequency plasma conductivity in the average-atom approximation.

    PubMed

    Kuchiev, M Yu; Johnson, W R

    2008-08-01

    Low-frequency properties of a plasma are examined within the average-atom approximation, which presumes that scattering of a conducting electron on each atom takes place independently of other atoms. The relaxation time tau distinguishes a high-frequency region omegatau>1 , where the single-atom approximation is applicable explicitly, from extreme low frequencies omegatau<1 , where, naively, the single-atom approximation is invalid. A proposed generalization of the formalism, which takes into account many-atom collisions, is found to be accurate in all frequency regions, from omega=0 to omegatau>1 , reproducing the Ziman formula in the static limit, results based on the Kubo-Greenwood formula for high frequencies and satisfying the conductivity sum rule precisely. The correspondence between physical processes leading to the conventional Ohm's law and the infrared properties of QED is discussed. The suggested average-atom approach to frequency-dependent conductivity is illustrated by numerical calculations for an aluminum plasma in the temperature range 2-10eV . PMID:18850940

  17. Use of the absolute phase in frequency modulated continuous wave plasma reflectometry

    SciTech Connect

    Cunningham, G.

    2008-08-15

    In frequency modulated continuous wave reflectometry, used for density profile measurement in fusion plasmas, it is usual to measure the beat frequency between the launched wave and the reflected wave, and from this to calculate the position of the reflecting layer in the plasma. The absolute phase of the beat signal is usually neglected. The reason is that the phase shift between sweeps is usually comparable with or more than 2{pi}, leading to an ambiguity that is impossible to resolve. However, recent observations on the MAST tokamak have shown that, under quiet plasma conditions (this term has to be defined), the phase shift between sweeps is small compared with 2{pi} and the phase ambiguity can be readily resolved. The reflectometer signal is then being analyzed as an interferometer signal would normally be, and there is a substantial improvement in spatial resolution. The method is illustrated by application to small edge localized mode precursor and allows what is believed to be the first quantitative measurement of the displacement of the plasma boundary by such a precursor mode. The errors in both the absolute phase measurement and the more conventional frequency measurement are also estimated.

  18. Electrical studies and plasma characterization of an atmospheric pressure plasma jet operated at low frequency

    SciTech Connect

    Giuliani, L.; Xaubet, M.; Grondona, D.; Minotti, F.; Kelly, H.

    2013-06-15

    Low-temperature, high-pressure plasma jets have an extensive use in medical and biological applications. Much work has been devoted to study these applications while comparatively fewer studies appear to be directed to the discharge itself. In this work, in order to better understand the kind of electrical discharge and the plasma states existing in those devices, a study of the electrical characteristics of a typical plasma jet, operated at atmospheric pressure, using either air or argon, is reported. It is found that the experimentally determined electrical characteristics are consistent with the model of a thermal arc discharge, with a highly collisional cathode sheet. The only exception is the case of argon at the smallest electrode separation studied, around 1 mm in which case the discharge is better modeled as either a non-thermal arc or a high-pressure glow. Also, variations of the electrical behavior at different gas flow rates are interpreted, consistently with the arc model, in terms of the development of fluid turbulence in the external jet.

  19. Plasmas in saline solutions sustained using rectified ac voltages: polarity and frequency effects on the discharge behaviour

    NASA Astrophysics Data System (ADS)

    Chang, Hung-wen; Hsu, Cheng-che

    2012-06-01

    In this work, three major problems, namely severe electrode damage, poor plasma stability and excess power consumption, arising in ac-driven plasmas in saline solutions are solved using a rectified power source. Diagnostic studies on the effects of power source polarity and frequency on the plasma behaviour are performed. Examination of I-V characteristics and temporally resolved light emission shows that the polarity significantly influences the current amplitude when the plasma exists, while the frequency alters the bubble dynamics, which in turn affects the plasma ignition voltage. When the plasma is driven by a rectified ac power source, the electrode erosion is reduced substantially. With a low frequency, moderate applied voltage and positively rectified ac power source (e.g. 100 Hz and 350 V), a stable plasma is ignited in nearly every power cycle.

  20. Characterization of oxygenated metabolites of ginsenoside Rg1 in plasma and urine of rat.

    PubMed

    Wang, Jing-Rong; Tong, Tian-Tian; Yau, Lee-Fong; Chen, Cheng-Yu; Bai, Li-Ping; Ma, Jing; Hu, Ming; Liu, Liang; Jiang, Zhi-Hong

    2016-07-15

    This study describes the characterization of oxygenated metabolites of ginsenoside Rg1 in rat urine and plasma. These in vivo metabolites were profiled by using UHPLC-QTOF MS-based method. On the basis of high-resolution MS/MS data, and comparison with chemically synthesized authentic compounds, nine oxygenated metabolites of Rg1 were characterized as vinaginsenosides 21 and 22 (M1 and M2), vinaginsenoside R15 (M3), 6-O-(β-d-glucopyranosyl)-20-O-(β-d-glucopyranosyl) 3β, 6α, 12β, 20(S)-tetrahydroxy-24ξ-hydroxydammar-25-ene (M4 and M5), floralginsenoside A (M7 and M8), floralginsenoside B (M9) and epoxyginsenoside Rg1 (M13), respectively. Among these metabolites, M4, M5 and M13 are new ginsenosides and others were detected as in vivo metabolites of Rg1 for the first time. In addition, a series of oxygenated metabolites of Rh1 and deglycosylated metabolite of Rg1, were observed and characterized by comparing with compounds synthesized by us, which revealed an association between C-20 configuration and the extent of oxidation metabolism. Appearance of all these metabolites in blood stream and urine after i.v. dosing and oral administration of Rg1 was further examined, which clearly showed that mono-oxygenated metabolites of Rg1 were major circulating metabolites at the early stage after dosing. Characterization of exact chemical structures of these circulating metabolites contribute greatly to our understanding of chemical exposure after consumption of ginseng products, and provide valuable information for explaining multiple bioactivities of ginseng products. PMID:26809375

  1. Superhydrophilic poly(L-lactic acid) electrospun membranes for biomedical applications obtained by argon and oxygen plasma treatment

    NASA Astrophysics Data System (ADS)

    Correia, D. M.; Ribeiro, C.; Botelho, G.; Borges, J.; Lopes, C.; Vaz, F.; Carabineiro, S. A. C.; Machado, A. V.; Lanceros-Méndez, S.

    2016-05-01

    Poly(L-lactic acid), PLLA, electrospun membranes and films were plasma treated at different times and power with argon (Ar) and oxygen (O2), independently, in order to modify the hydrophobic nature of the PLLA membranes. Both Ar and O2 plasma treatments promote an increase in fiber average size of the electrospun membranes from 830 ± 282 nm to 866 ± 361 and 1179 ± 397 nm, respectively, for the maximum exposure time (970 s) and power (100 W). No influence of plasma treatment was detected in the physical-chemical characteristics of PLLA, such as chemical structure, polymer phase or degree of crystallinity. On the other hand, an increase in the roughness of the films was obtained both with argon and oxygen plasma treatments. Surface wettability studies revealed a decrease in the contact angle with increasing plasma treatment time for a given power and with increasing power for a given time in membranes and films and superhydrophilic electrospun fiber membranes were obtained. Results showed that the argon and oxygen plasma treatments can be used to tailor hydrophilicity of PLLA membranes for biomedical applications. MTT assay results indicated that plasma treatments under Ar and O2 do not influence the metabolic activity of MC3T3-E1 pre-osteoblast cells.

  2. As-grown Y-Ba-Cu-O thin films by reactive coevaporation with oxygen plasma cooling

    NASA Astrophysics Data System (ADS)

    Matsumoto, M.; Akoh, H.; Takada, S.

    1989-10-01

    We have developed a new fabrication process of as-grown Y-Ba-Cu-O thin films using a reactive coevaporation method specially with the rf-plasma cooling in the low oxygen pressure of 0.4 mTorr. By this O2 plasma cooling process, the transition temperature Tc is improved from 40 to 81 K for the film with a thickness of 1000 Å. The x-ray diffraction analysis shows that the activated oxygen species generated by the rf plasma make Y-Ba-Cu-O films oxidize sufficiently even in the low pressure of oxygen. In addition, we have studied the thickness dependence of Tc for as-grown films with various thicknesses of 60-2000 Å.

  3. As-grown Y-Ba-Cu-O thin films by reactive coevaporation with oxygen plasma cooling

    SciTech Connect

    Matsumoto, M.; Akoh, H.; Takada, S. )

    1989-10-15

    We have developed a new fabrication process of as-grown Y-Ba-Cu-O thin films using a reactive coevaporation method specially with the rf-plasma cooling in the low oxygen pressure of 0.4 mTorr. By this O{sub 2} plasma cooling process, the transition temperature {ital T}{sub {ital c}} is improved from 40 to 81 K for the film with a thickness of 1000 A. The x-ray diffraction analysis shows that the activated oxygen species generated by the rf plasma make Y-Ba-Cu-O films oxidize sufficiently even in the low pressure of oxygen. In addition, we have studied the thickness dependence of {ital T}{sub {ital c}} for as-grown films with various thicknesses of 60--2000 A.

  4. ESCA study of the effect of hydrocarbon contamination on poly(tetrafluoroethylene) exposed to atomic oxygen plasma

    NASA Technical Reports Server (NTRS)

    Golub, Morton A.; Wydeven, Theodore; Cormia, Robert D.

    1991-01-01

    The ESCA spectra and data obtained by Morra et al. (1989) on poly(tetrafluoroethylene) (PTFE) exposed to atomic oxygen plasma are closely reexamined. It is shown that the spikes observed in Morra et al. plots of O/C or F/C versus time of the exposure of PTFE to atomic oxygen plasma were not characteristic of PTFE per se but were instead a result of a contamination by hydrocarbon present in their PTFE samples. This was demonstrated experimentally by comparing data derived for a very clean PTFE sample exposed for 10, 20, and 30 min to oxygen plasma with data obtained on PTFE samples with very small amounts of hydrocarbon contamination.

  5. Influence of frequency on the characteristics of VHF capacitively coupled plasmas in a 300 mm chamber

    NASA Astrophysics Data System (ADS)

    Hebner, G. A.; Barnat, E. V.; Miller, P. A.; Paterson, A.; Holland, J.; Lill, T.

    2004-09-01

    We have investigated the characteristics of VHF capacitively coupled plasmas produced in a modified Applied Materials chamber. The chamber had a 14-inch diameter upper electrode (source) that was driven at 10 to 160 MHz and a 300 mm diameter electrostatic chuck with a ceramic process kit that was driven at 13.56 MHz (bias). Diagnostics employed include a microwave interferometer to measure the line-integrated electron density, a hairpin microwave resonator to measure the spatially resolved electron density, absorption spectroscopy to determine the argon metastable temperature and density, laser induced fluorescence (LIF) to determine the spatial distribution of the excited species, and spatially resolved optical emission. We found that for constant source rf power, the electron density increased with rf frequency. The argon 1s5 metastable temperature was slightly above room temperature (300 - 400K), significantly cooler than our previous measurements in inductively coupled plasmas. The metastable density was not a strong function of source frequency or rf power. The metastable spatial distribution was always peaked in the center of the chamber and had a weak dependence on frequency. Scaling of the plasma parameters with frequency, power and pressure, and implications to energy deposition models will be discussed. This work was supported by Applied Materials and Sandia National Laboratories, a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company for the United States Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

  6. Femtosecond, two-photon laser-induced-fluorescence imaging of atomic oxygen in an atmospheric-pressure plasma jet

    NASA Astrophysics Data System (ADS)

    Schmidt, Jacob B.; Sands, Brian L.; Kulatilaka, Waruna D.; Roy, Sukesh; Scofield, James; Gord, James R.

    2015-06-01

    Femtosecond, two-photon-absorption laser-induced-fluorescence (fs-TALIF) spectroscopy is employed to measure space- and time-resolved atomic-oxygen distributions in a nanosecond, repetitively pulsed, externally grounded, atmospheric-pressure plasma jet flowing helium with a variable oxygen admixture. The high-peak-intensity, low-average-energy femtosecond pulses result in increased TALIF signal with reduced photolytic inferences. This allows 2D imaging of absolute atomic-oxygen number densities ranging from 5.8   ×   1015 to 2.0   ×   1012cm-3 using a cooled CCD with an external intensifier. Xenon is used for signal and imaging-system calibrations to quantify the atomic-oxygen fluorescence signal. Initial results highlight a transition in discharge morphology from annular to filamentary, corresponding with a change in plasma chemistry from ozone to atomic oxygen production, as the concentration of oxygen in the feed gas is changed at a fixed voltage-pulse-repetition rate. In this configuration, significant concentrations of reactive oxygen species may be remotely generated by sustaining an active discharge beyond the confines of the dielectric capillary, which may benefit applications that require large concentrations of reactive oxygen species such as material processing or biomedical devices.

  7. Blood oxygen flux estimation with a combined photoacoustic and high-frequency ultrasound microscopy system: a phantom study

    NASA Astrophysics Data System (ADS)

    Jiang, Yan; Forbrich, Alex; Harrison, Tyler; Zemp, Roger J.

    2012-03-01

    The metabolic rate of oxygen consumption, an important indicator of tissue metabolism, can be expressed as the change of net blood oxygen flux into and out of a tissue region per 100 g of tissue. In this work, we propose a photoacoustic and Doppler ultrasound method for imaging local blood oxygen flux of a single vessel. An imaging system for combined photoacoustic and high-frequency ultrasound microscopy is presented. This system uses a swept-scan 25-MHz ultrasound transducer with confocal dark-field laser illumination optics. A pulse-sequencer enables ultrasonic and laser pulses to be interlaced so that photoacoustic and Doppler ultrasound images are co-registered. Since the mean flow speed can be measured by color Doppler ultrasound, the vessel cross-sectional area can be measured by power Doppler or structural photoacoustic imaging, and multi-wavelength photoacoustic methods can be used to estimate oxygen saturation (sO2) and total concentration of haemoglobin (CHb), all of the parameters necessary for oxygen flux estimation can be provided. The accuracy of the flow speed and sO2 estimation has been investigated. In vitro sheep blood phantom experiments have been performed at different sO2 levels and mean flow speeds. Blood oxygen flux has been estimated, and the uncertainty of the measurement has been quantified.

  8. Nonlinear low-frequency electrostatic wave dynamics in a two-dimensional quantum plasma

    NASA Astrophysics Data System (ADS)

    Ghosh, Samiran; Chakrabarti, Nikhil

    2016-08-01

    The problem of two-dimensional arbitrary amplitude low-frequency electrostatic oscillation in a quasi-neutral quantum plasma is solved exactly by elementary means. In such quantum plasmas we have treated electrons quantum mechanically and ions classically. The exact analytical solution of the nonlinear system exhibits the formation of dark and black solitons. Numerical simulation also predicts the possible periodic solution of the nonlinear system. Nonlinear analysis reveals that the system does have a bifurcation at a critical Mach number that depends on the angle of propagation of the wave. The small-amplitude limit leads to the formation of weakly nonlinear Kadomstev-Petviashvili solitons.

  9. Low-frequency wave modulations in an electronegative dusty plasma in the presence of charge variations.

    PubMed

    Ghosh, Samiran; Sarkar, Subrata; Khan, Manoranjan; Gupta, M R

    2011-12-01

    The effects of dust charge variations on low-frequency wave modulations in an electronegative dusty plasma are investigated. The dynamics of the modulated wave is governed by a nonlinear Schrödinger equation with a dissipative term. The dissipation arises due to the nonsteady (nonadiabatic) dust charge variations. Theoretical and numerical investigations predict the formation of dissipative bright (envelope) and dark solitons. The nonsteady charge-variation-induced dissipation reduces the modulational instability growth rate and introduces a characteristic time scale to observe bright solitons. Results are discussed in the context of electronegative dusty plasma experiments. PMID:22304202

  10. New generalized dispersion relation for low-frequency electromagnetic waves in Hall-magnetohydrodynamic dusty plasmas

    SciTech Connect

    Shukla, Padma Kant; Kourakis, Ioannis; Stenflo, Lennart

    2005-10-31

    A generalized linear theory for electromagnetic waves in a homogeneous dusty magnetoplasma is presented. The waves described are characterized by a frequency which is much smaller (larger) than the electron gyrofrequency (dust plasma and dust gyrofrequencies), and a long wavelength (in comparison with the ion gyroradius and the electron skin depth). The generalized Hall-magnetohydrodynamic (GH-MHD) equations are derived by assuming massive charged dust macroparticles to be immobile, and Fourier transformed to obtain a general dispersion relation. The latter is analyzed to understand the influence of immobile charged dust grains on various electromagnetic wave modes in a magnetized dusty plasma.

  11. Green frequency-doubled laser-beam propagation in high-temperature hohlraum plasmas.

    PubMed

    Niemann, C; Berger, R L; Divol, L; Froula, D H; Jones, O; Kirkwood, R K; Meezan, N; Moody, J D; Ross, J; Sorce, C; Suter, L J; Glenzer, S H

    2008-02-01

    We demonstrate propagation and small backscatter losses of a frequency-doubled (2omega) laser beam interacting with inertial confinement fusion hohlraum plasmas. The electron temperature of 3.3 keV, approximately a factor of 2 higher than achieved in previous experiments with open geometry targets, approaches plasma conditions of high-fusion yield hohlraums. In this new temperature regime, we measure 2omega laser-beam transmission approaching 80% with simultaneous backscattering losses of less than 10%. These findings suggest that good laser coupling into fusion hohlraums using 2omega light is possible. PMID:18352288

  12. Non-Destructive Testing with Atmospheric Pressure Radio-Frequency Plasma

    NASA Astrophysics Data System (ADS)

    May, A.; Andarawis, E.

    2007-03-01

    We summarize our recent work using radio-frequency (RF) atmospheric pressure plasma (APP) for non-destructive evaluation (NDE), specifically for: (1) Clearance sensing (0-5mm) on rotating components, and (2) Generation of broadband ultrasound in air at 900kHz. RF-APP showed potential in both of these common NDE requirements, but further work is required to better characterize and optimize the performance of the new techniques. Application of RF-APP to other NDE disciplines, such as plasma spectroscopy and gas flow measurement, is also likely to be advantageous, especially in harsh environments where existing approaches are prohibitively expensive or complex.

  13. Green Frequency-Doubled Laser-Beam Propagation in High-Temperature Hohlraum Plasmas

    SciTech Connect

    Niemann, C.; Berger, R. L.; Divol, L.; Froula, D. H.; Jones, O.; Kirkwood, R. K.; Meezan, N.; Moody, J. D.; Ross, J.; Sorce, C.; Suter, L. J.; Glenzer, S. H.

    2008-02-01

    We demonstrate propagation and small backscatter losses of a frequency-doubled (2{omega}) laser beam interacting with inertial confinement fusion hohlraum plasmas. The electron temperature of 3.3 keV, approximately a factor of 2 higher than achieved in previous experiments with open geometry targets, approaches plasma conditions of high-fusion yield hohlraums. In this new temperature regime, we measure 2{omega} laser-beam transmission approaching 80% with simultaneous backscattering losses of less than 10%. These findings suggest that good laser coupling into fusion hohlraums using 2{omega} light is possible.

  14. Combining oxygen plasma treatment with anchorage of cationized gelatin for enhancing cell affinity of poly(lactide-co-glycolide).

    PubMed

    Shen, Hong; Hu, Xixue; Yang, Fei; Bei, Jianzhong; Wang, Shenguo

    2007-10-01

    Surface characteristics greatly influence attachment and growth of cells on biomaterials. Although polylactone-type biodegradable polymers have been widely used as scaffold materials for tissue engineering, lack of cell recognition sites, poor hydrophilicity and low surface energy lead to a bad cell affinity of the polymers, which limit the usage of polymers as scaffolds in tissue engineering. In the present study, surface of poly (L-lactide-co-glycolide) (PLGA) was modified by a method of combining oxygen plasma treatment with anchorage of cationized gelatin. Modification effect of the method was compared with other methods of oxygen plasma treatment, cationized gelatin or gelatin coating and combining oxygen plasma treatment with anchorage of gelatin. The change of surface property was compared by contact angles, surface energy, X-ray photoelectron spectra (XPS), attenuated total reflection-Fourier transform infrared spectroscopy (ATR-FTIR) and scanning electron microscopy (SEM) measurement. The optimum oxygen pretreatment time determined by surface energy was 10 min when the power was 50 W and the oxygen pressure was 20 Pa. Analysis of the stability of gelatin and cationized gelatin anchored on PLGA by XPS, ATR-FTIR, contact angles and surface energy measurement indicated the cationized gelatin was more stable than gelatin. The result using mouse NIH 3T3 fibroblasts as model cells to evaluate cell affinity in vitro showed the cationized gelatin-anchored PLGA (OCG-PLGA) was more favorable for cell attachment and growth than oxygen plasma treated PLGA (O-PLGA) and gelatin-anchored PLGA (OG-PLGA). Moreover cell affinity of OCG-PLGA could match that of collagen-anchored PLGA (AC-PLGA). So the surface modification method combining oxygen plasma treatment with anchorage of cationized gelatin provides a universally effective way to enhance cell affinity of polylactone-type biodegradable polymers. PMID:17618682

  15. Heating of ions by high frequency electromagnetic waves in magnetized plasmas

    SciTech Connect

    Zestanakis, P. A.; Kominis, Y.; Hizanidis, K.; Ram, A. K.

    2013-07-15

    The heating of ions by high frequency electrostatic waves in magnetically confined plasmas has been a paradigm for studying nonlinear wave-particle interactions. The frequency of the waves is assumed to be much higher than the ion cyclotron frequency and the waves are taken to propagate across the magnetic field. In fusion type plasmas, electrostatic waves, like the lower hybrid wave, cannot access the core of the plasma. That is a domain for high harmonic fast waves or electron cyclotron waves—these are primarily electromagnetic waves. Previous studies on heating of ions by two or more electrostatic waves are extended to two electromagnetic waves that propagate directly across the confining magnetic field. While the ratio of the frequency of each wave to the ion cyclotron frequency is large, the frequency difference is assumed to be near the ion cyclotron frequency. The nonlinear wave-particle interaction is studied analytically using a two time-scale canonical perturbation theory. The theory elucidates the effects of various parameters on the gain in energy by the ions—parameters such as the amplitudes and polarizations of the waves, the ratio of the wave frequencies to the cyclotron frequency, the difference in the frequency of the two waves, and the wave numbers associated with the waves. For example, the ratio of the phase velocity of the envelope formed by the two waves to the phase velocity of the carrier wave is important for energization of ions. For a positive ratio, the energy range is much larger than for a negative ratio. So waves like the lower hybrid waves will impart very little energy to ions. The theoretical results are found to be in good agreement with numerical simulations of the exact dynamical equations. The analytical results are used to construct mapping equations, simplifying the derivation of the motion of ions, which are, subsequently, used to follow the evolution of an ion distribution function. The heating of ions can then be

  16. Scattering of radio frequency waves by cylindrical density filaments in tokamak plasmas

    NASA Astrophysics Data System (ADS)

    Ram, Abhay K.; Hizanidis, Kyriakos

    2016-02-01

    In tokamak fusion plasmas, coherent fluctuations in the form of blobs or filaments are routinely observed in the scrape-off layer. Radio frequency (RF) electromagnetic waves, excited by antenna structures placed near the wall of a tokamak, have to propagate through the scrape-off layer before reaching the core of the plasma. While the effect of fluctuations on the properties of RF waves has not been quantified experimentally, it is of interest to carry out a theoretical study to determine if fluctuations can affect the propagation characteristics of RF waves. Usually, the difference between the plasma density inside the filament and the background plasma density is sizable, the ratio of the density difference to the background density being of order one. Generally, this precludes the use of geometrical optics in determining the effect of fluctuations, since the relevant ratio has to be much less than one, typically, of the order of 10% or less. In this paper, a full-wave, analytical model is developed for the scattering of a RF plane wave by a cylindrical plasma filament. It is assumed that the plasma inside and outside the filament is cold and uniform and that the major axis of the filament is aligned along the toroidal magnetic field. The ratio of the density inside the filament to the density of the background plasma is not restricted. The theoretical framework applies to the scattering of any cold plasma wave. In order to satisfy the boundary conditions at the interface between the filament and the background plasma, the electromagnetic fields inside and outside the filament need to have the same k∥ , the wave vector parallel to the ambient magnetic field, as the incident plane wave. Consequently, in contrast to the scattering of a RF wave by a spherical blob [Ram et al., Phys. Plasmas 20, 056110-1-056110-10 (2013)], the scattering by a field-aligned filament does not broaden the k∥ spectrum. However, the filament induces side-scattering leading to surface

  17. Absorption and emission of extraordinary-mode electromagnetic waves near cyclotron frequency in nonequilibrium plasmas

    NASA Technical Reports Server (NTRS)

    Wu, C. S.; Lin, C. S.; Wong, H. K.; Tsai, S. T.; Zhou, R. L.

    1981-01-01

    An investigation is presented of two cases: (1) weakly relativistic electrons with a loss-cone type distribution, and (2) electrons with a drift velocity parallel to the ambient magnetic field. Numerical computations are given for physical parameters close to those in the polar region of the earth magnetosphere and laboratory experiments, with attention to the fast extraordinary-mode radiation whose frequency is near that of the electron cyclotron frequency. The fast extraordinary mode can escape from a strong field region to the weaker field region and may therefore be measured outside the plasma. It is found that the X mode radiation can be amplified by means of a cyclotron maser effect when the electrons have a loss-cone distribution, and it is concluded that, when the electron energy is sufficiently high, the X mode cutoff frequency may be lower than the cyclotron frequency.

  18. Mild oxygen plasma treated PEDOT:PSS as anode buffer layer for vacuum deposited organic light-emitting diodes

    NASA Astrophysics Data System (ADS)

    Zhou, Yunfei; Yuan, Yongbo; Lian, Jiarong; Zhang, Jie; Pang, Hongqi; Cao, Lingfang; Zhou, Xiang

    2006-08-01

    The surface morphology of PEDOT:PSS after mild oxygen plasma treatment were investigated by scanning electron microscopy and atomic force microscopy. The nanometer-scale islands on the surface of treated PEDOT:PSS were observed. Vacuum deposited organic light-emitting diodes (OLEDs) with treated PEDOT:PSS as anode buffer layer had been fabricated. The OLEDs with an appropriately treated PEDOT:PSS as anode buffer layer exhibited significantly enhanced lifetime and decreased driving voltage. The results suggest that the appropriate mild oxygen plasma treatment of PEDOT:PSS layers may be useful for the improvement of the interface with the hole transport layer and enhanced device performance.

  19. Impact of oxygen plasma treatment on the device performance of zinc oxide nanoparticle-based thin-film transistors.

    PubMed

    Faber, Hendrik; Hirschmann, Johannes; Klaumünzer, Martin; Braunschweig, Björn; Peukert, Wolfgang; Halik, Marcus

    2012-03-01

    Thin-films of zinc oxide nanoparticles were investigated by photoluminescence spectroscopy and a broad defect-related yellow-green emission was observed. Oxygen plasma treatment was applied in order to reduce the number of defects, and the emission intensity was quenched to 4% of the initial value. Thin-film transistors that incorporate the nanoparticles as active semiconducting layers show an improved device performance after oxygen plasma treatment. The maximum drain current and the charge carrier mobility increased more than 1 order of magnitude up to a nominal value of 23 cm(2) V(-1) s(-1) and the threshold voltage was lowered. PMID:22391057

  20. Irradiation of silver and agar/silver nanoparticles with argon, oxygen glow discharge plasma, and mercury lamp.

    PubMed

    Ahmad, Mahmoud M; Abdel-Wahab, Essam A; El-Maaref, A A; Rawway, Mohammed; Shaaban, Essam R

    2014-01-01

    The irradiation effect of argon, oxygen glow discharge plasma, and mercury lamp on silver and agar/silver nanoparticle samples is studied. The irradiation time dependence of the synthesized silver and agar/silver nanoparticle absorption spectra and their antibacterial effect are studied and compared. In the agar/silver nanoparticle sample, as the irradiation time of argon glow discharge plasma or mercury lamp increases, the peak intensity and the full width at half maximum, FWHM, of the surface plasmon resonance absorption band is increased, however a decrease of the peak intensity with oxygen glow plasma has been observed. In the silver nanoparticle sample, as the irradiation time of argon, oxygen glow discharge plasma or mercury lamp increases, the peak intensity of the surface plasmon resonance absorption band is increased, however, there is no significant change in the FWHM of the surface plasmon resonance absorption band. The SEM results for both samples showed nanoparticle formation with mean size about 50 nm and 40 nm respectively. Throughout the irradiation time with the argon, oxygen glow discharge plasma or mercury lamp, the antibacterial activity of several kinds of Gram-positive and Gram-negative bacteria has been examined. PMID:25184109

  1. Ion cyclotron range of frequencies heating and current drive in deuterium-tritium plasmas

    NASA Astrophysics Data System (ADS)

    Phillips, C. K.; Bell, M. G.; Bell, R.; Bretz, N.; Budny, R. V.; Darrow, D. S.; Grek, B.; Hammett, G.; Hosea, J. C.; Hsuan, H.; Ignat, D.; Majeski, R.; Mazzucato, E.; Nazikian, R.; Park, H.; Rogers, J. H.; Schilling, G.; Stevens, J. E.; Synakowski, E.; Taylor, G.; Wilson, J. R.; Zarnstorff, M. C.; Zweben, S. J.; Bush, C. E.; Goldfinger, R.; Jaeger, E. F.; Murakami, M.; Rasmussen, D.; Bettenhausen, M.; Lam, N. T.; Scharer, J.; Sund, R.; Sauter, O.

    1995-06-01

    The first experiments utilizing high-power radio waves in the ion cyclotron range of frequencies to heat deuterium-tritium (D-T) plasmas have been completed on the Tokamak Fusion Test Reactor [Fusion Technol. 21, 13 (1992)]. Results from the initial series of experiments have demonstrated efficient core second harmonic tritium (2ΩT) heating in parameter regimes approaching those anticipated for the International Thermonuclear Experimental Reactor [D. E. Post, Plasma Physics and Controlled Nuclear Fusion Research, Proceedings of the 13th International Conference, Washington, DC, 1990 (International Atomic Energy Agency, Vienna, 1991), Vol. 3, p. 239]. Observations are consistent with modeling predictions for these plasmas. Efficient electron heating via mode conversion of fast waves to ion Bernstein waves has been observed in D-T, deuterium-deuterium (D-D), and deuterium-helium-4 (D-4He) plasmas with high concentrations of minority helium-3 (3He) (n3He/ne≳10%). Mode conversion current drive in D-T plasmas was simulated with experiments conducted in D-3He-4He plasmas. Results show a directed propagation of the mode converted ion Bernstein waves, in correlation with the antenna phasing.

  2. Plasma ionization frequency, edge-to-axis density ratio, and density on axis of a cylindrical gas discharge

    SciTech Connect

    Palacio Mizrahi, J. H.

    2014-06-15

    A rigorous derivation of expressions, starting from the governing equations, for the ionization frequency, edge-to-axis ratio of plasma density, plasma density at the axis, and radially averaged plasma density in a cylindrical gas discharge has been obtained. The derived expressions are simple and involve the relevant parameters of the discharge: Cylinder radius, axial current, and neutral gas pressure. The found expressions account for ion inertia, ion temperature, and changes in plasma ion collisionality.

  3. Roles of oxygen for methanol adsorption on polycrystalline copper surface revealed by sum frequency generation imaging microscopy

    NASA Astrophysics Data System (ADS)

    Fang, Ming; Santos, Greggy; Chen, Xiaole; Baldelli, Steven

    2016-06-01

    The adsorption of atmospheric pressure methanol on the polycrystalline copper surface has been studied by a combination of sum frequency generation imaging microscopy (SFGIM) and temperature programmed desorption (TPD). Methoxy species can be generated by exposing the polycrystalline copper surface to methanol vapor at room temperature. SFGIM results demonstrate that oxygen promotes the surface adsorption of methanol and the increase in the amount of methoxy produced on copper surface. SFGIM orientation analysis suggests the methoxy monolayer is oriented closer to the surface normal with introduction of oxygen. Employing the image statistical analysis approach, the heterogeneities and conformation distribution of methoxy monolayers on copper surface with and without oxygen adsorption are compared. These results illustrate SFGIM indeed could provide more insight for understanding the heterogeneous metal/metal oxide surface in the molecular level.

  4. Resonant instability near the two-ion crossover frequency in the Io plasma torus

    NASA Astrophysics Data System (ADS)

    Thorne, R. M.; Moses, J. J.

    1985-07-01

    Thorne and Scarf (1984) have presented evidence for the existence of intense low-frequency fluctuating electric fields in the Io plasma torus. Two distinct mechanisms have been proposed for this phenomenon, namely, ion cyclotron instability which occurs at intermediate latitude, and whistler instability near the equator. The present investigation is concerned with a quantitative appraisal of each of these mechanisms, taking into account an evaluation of the net convective growth rate of waves along ray paths which traverse the Io torus. Aspects of wave propagation near the crossover frequency are considered along with questions regarding the resonant interaction with energetic particles.

  5. The adhesion of oxygen-plasma treated poly(ethylene) and poly(ethylene terephthlate) films

    SciTech Connect

    Holton, S.L.; Kinloch, A.J.; Watts, J.F.

    1996-12-31

    The effects of low-pressure oxygen-plasma treatment on the surfaces of poly(ethylene) (PE) and poly(ethylene terephthlate) (PET) films and its influence on the adhesion of PE/PET laminates were assessed. The 90{degree} peel test was used to estimate the adhesive fracture energy, G{sub c} for the laminates. XPS, SEM and AFM were used to analyse the treated films and fracture surfaces. Significant improvements in bond strength occurred within very short treatment times (5s at 50W) with the maximum adhesion occurring after 300s. For longer treatment times the bond strengths decrease slightly. G{sub c} values were found to be low when PET was the peel arm. When PE was the peel arm, the G{sub c} values were substantially larger using the current analysis.

  6. Helium/oxygen atmospheric pressure plasma jet treatment for hydrophilicity improvement of grey cotton knitted fabric

    NASA Astrophysics Data System (ADS)

    Tian, Liqiang; Nie, Huali; Chatterton, Nicholas P.; Branford-White, Christopher J.; Qiu, Yiping; Zhu, Limin

    2011-06-01

    The influence of atmospheric pressure plasma jet (APPJ) treatment on the hydrophilicity of grey cotton knitted fabric (GCKF) was investigated. For comparison, specimens which had undergone different treatments were tested by contact angle measurement, scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), fourier-transform infrared attenuated total reflectance spectroscopy (FTIR-ATR) and X-ray diffraction (XRD). The results imply that helium/oxygen APPJ could improve the hydrophilicity of GCKF by modifying the surface properties. In addition, combining dewaxing processes with He/O 2 APPJ treatment was found to tremendously improve the hydrophilicity of GCKF. The mechanism of this was also confirmed by Ruthenium Red staining which showed most of pectic substances inside the cotton fiber existed beneath the waxy layer and on top of the cellulose microfibril.

  7. Electron energy distribution functions in low-pressure oxygen plasma columns sustained by propagating surface waves

    SciTech Connect

    Stafford, L.; Margot, J.; Moisan, M.; Khare, R.; Donnelly, V. M.

    2009-01-12

    Electron energy distribution functions (EEDFs) were measured in a 50 mTorr oxygen plasma column sustained by propagating surface waves. Trace-rare-gas-optical-emission spectroscopy was used to derive EEDFs by selecting lines to extract ''electron temperature''(T{sub e}) corresponding to either lower energy electrons that excite high-lying levels through stepwise excitation via metastable states or higher energy electrons that excite emission directly from the ground state. Lower energy T{sub e}'s decreased from 8 to 5.5 eV with distance from the wave launcher, while T{sub e}{approx_equal}6 eV for higher energy electrons and T{sub e}>20 eV for a high-energy tail. Mechanisms for such EEDFs are discussed.

  8. Oxygen-poor phase observed during plasma-sprayed physical vapor deposition of zirconia coatings

    NASA Astrophysics Data System (ADS)

    Good, Brian; Harder, Bryan

    2014-03-01

    When cubic zirconia is deposited using Plasma Spray-Physical Vapor Deposition (PS-PVD) under oxygen-poor conditions, a metastable phase is observed. We describe a combined experimental and computational approach aimed at determining the structure and composition of the phase. X-Ray analysis indicates that the phase exhibits cubic symmetry, and it is also found to be electrically conductive, in contrast to cubic zirconia, which is electrically insulating. We have performed electronic structure calculations aimed at identifying the metastable phase. Three cubic candidate ZrO structures were identified, and the lattice constants were optimized for each. The lowest-energy structure was found to be the NaCl structure. Projected density of states calculations show that the material is conductive, with conduction occurring within the Zr 4s band. Potential technological uses for the phase are discussed.

  9. Wave merging mechanism: formation of low-frequency Alfven and magnetosonic waves in cosmic plasmas

    SciTech Connect

    Tishchenko, V N; Shaikhislamov, I F

    2014-02-28

    We investigate the merging mechanism for the waves produced by a pulsating cosmic plasma source. A model with a separate background/source description is used in our calculations. The mechanism was shown to operate both for strong and weak source – background interactions. We revealed the effect of merging of individual Alfven waves into a narrow low-frequency wave, whose amplitude is maximal for a plasma expansion velocity equal to 0.5 – 1 of the Alfven Mach number. This wave is followed along the field by a narrow low-frequency magnetosonic wave, which contains the bulk of source energy. For low expansion velocities the wave contains background and source particles, but for high velocities it contains only the background particles. The wave lengths are much greater than their transverse dimension. (letters)

  10. Low-frequency, self-sustained oscillations in inductively coupled plasmas used for optical pumping

    SciTech Connect

    Coffer, J.; Encalada, N.; Huang, M.; Camparo, J.

    2014-10-28

    We have investigated very low frequency, on the order of one hertz, self-pulsing in alkali-metal inductively-coupled plasmas (i.e., rf-discharge lamps). This self-pulsing has the potential to significantly vary signal-to-noise ratios and (via the ac-Stark shift) resonant frequencies in optically pumped atomic clocks and magnetometers (e.g., the atomic clocks now flying on GPS and Galileo global navigation system satellites). The phenomenon arises from a nonlinear interaction between the atomic physics of radiation trapping and the plasma's electrical nature. To explain the effect, we have developed an evaporation/condensation theory (EC theory) of the self-pulsing phenomenon.

  11. Magnetic-field tunable multichannel filter in a plasma photonic crystal at microwave frequencies.

    PubMed

    Chang, Tsung-Wen; Chien, Jia-Ren Chang; Wu, Chien-Jang

    2016-02-01

    The microwave magnetic-field tunable filtering properties in a multichannel filter based on use of a one-dimensional finite magnetized plasma photonic crystal (PPC) are theoretically investigated. The considered PPC has a structure of air/(AB)N/air, where A is a dielectric layer, B is a plasma layer, and N is the stack number. First, in the absence of an externally applied magnetic field, the structure can work as a multichannel filter whose channel number is equal to N-1 for N>1. Next, in the presence of an externally applied field, the filtering properties become tunable, i.e., the channel frequencies can be shifted as a function of the applied magnetic field. We find that the effect of the magnetic field will cause the channel frequencies to be blue-shifted or red-shifted depending on the orientation of the applied magnetic field. PMID:26836104

  12. Dust removal in radio-frequency plasmas by a traveling potential modulation

    SciTech Connect

    Li Yangfang; Jiang Ke; Thomas, Hubertus M.; Morfill, Gregor E.

    2010-06-16

    The dust contamination in plasma deposition processes plays a crucial role in the quality and the yield of the products. To improve the quality and the yield of plasma processing, a favorable way is to remove the dust particles actively from the plasma reactors.Our recent experiments in the striped electrode device show that a traveling plasma modulation allows for a systematic particle removal independent of the reactor size. Besides the rf powered electrode, the striped electrode device includes a segmented electrode that consists of 100 electrically insulated narrow stripes. A traveling potential profile is produced by the modulation of the voltage signals applied on the stripes. The dust particles are trapped in the potential wells and transported with the traveling of the potential profile.The particle-in-cell (PIC) simulation on the potential above the segmented electrode indicates that the traveling potential profile can be realized either by applying low-frequency (0.1-10 Hz) voltage signals with a fixed phase shift between adjacent stripes or high-frequency (10 kHz a circumflex AS 100 MHz) signals with the amplitudes modulated by a low-frequency envelope. The transportation of the dust particles is simulated with a two-dimensional molecular dynamics (MD) code with the potential profile obtained from the PIC simulation. The MD results reproduce the experimental observations successfully.This technology allows for an active removal of the contaminating particles in processing plasmas and it is independent of the reactor size. The removal velocity is controllable by adjusting the parameters for the modulation.

  13. Competitive Low Pressure Oxygen Plasma Interactions with Different= Carbon-Carbon Double Bonds

    NASA Astrophysics Data System (ADS)

    Patiño, P.; Sifontes, A.; Gambús, G.

    1999-10-01

    Recently we have shown advances from reactions of O(^3P) with both, l ong-chain hydrocarbons and refinery residuum. The oxidation products of t he process, a mixture of alcohols, epoxides and carbonyl compounds, might have potential properties as additives in formulating fuels. This work s hows the results of the interactions of an oxygen plasma with double bond s, both olefin and aromatic, in the same compound. The reactions have bee n carried out by making the plasma, created by a high voltage glow discha rge, reach the low vapor pressure surface of liquid 4-phenyl-1-butene. Th is (3 mL) was cooled down to -45 ^oC in a glass reactor, applied power was 24 W, at an oxygen pressure of 20 Pa. Products were analyzed by IR, N MR and mass spectroscopies. Conversions were studied as a function of the reaction time, this ranging from 5 to 120 minutes. At short times the O( ^3P) atoms produced in the discharge only reacted with the alkene fra ction of the hydrocarbon, 4-phenyl-1,2-epoxibutane (52%) and 4-phenyl-bu tanal (48%) being the products. Reactions on the benzene ring were obser ved from about 30 minutes on, the corresponding phenols having being prod uced at ratios ortho:para:meta :: 4:1:0.7. At 120 minutes, the ol efin have been completely oxidized and a low fraction of the non-equivale nt two methylene groups have reacted to produce alcohols and ketones.

  14. Evaluation of fatty acid oxidation by reactive oxygen species induced in liquids using atmospheric-pressure nonthermal plasma jets

    NASA Astrophysics Data System (ADS)

    Tani, Atsushi; Fukui, Satoshi; Ikawa, Satoshi; Kitano, Katsuhisa

    2015-10-01

    We investigated fatty acid oxidation by atmospheric-pressure nonthermal helium plasma using linoleic acid, an unsaturated fatty acid, together with evaluating active species induced in liquids. If the ambient gas contains oxygen, direct plasma such as plasma jets coming into contact with the liquid surface supplies various active species, such as singlet oxygen, ozone, and superoxide anion radicals, to the liquid. The direct plasma easily oxidizes linoleic acid, indicating that fatty acid oxidation will occur in the direct plasma. In contrast, afterglow flow, where the plasma is terminated in a glass tube and does not touch the surface of the liquid sample, supplies mainly superoxide anion radicals. The fact that there was no clear observation of linoleic acid oxidation using the afterglow reveals that it may not affect lipids, even in an atmosphere containing oxygen. The afterglow flow can potentially be used for the sterilization of aqueous solutions using the reduced pH method, in medical and dental applications, because it provides bactericidal activity in the aqueous solution despite containing a smaller amount of active species.

  15. Low-frequency electromagnetic waves in a Hall-magnetohydrodynamic plasma with charged dust macroparticles

    SciTech Connect

    Shukla, P.K.; Kourakis, I.; Stenflo, L.

    2005-02-01

    A linear theory for intermediate-frequency [much smaller (larger) than the electron gyrofrequency (dust plasma and dust gyrofrequencies)], long wavelength (in comparison with the ion gyroradius and the electron skin depth) electromagnetic waves in a multicomponent, homogeneous electron-ion-dust magnetoplasma is presented. For this purpose, the generalized Hall-magnetohydrodynamic (GH-MHD) equations are derived for the case with immobile charged dust macroparticles. The GH-MHD equations in a quasineutral plasma consist of the ion continuity equation, the generalized ion momentum equation, and Faraday's law with the Hall term. The GH-MHD equations are Fourier transformed and combined to obtain a general dispersion relation. The latter is analyzed to understand the influence of immobile charged dust grains on various electromagnetic wave modes in a magnetized dusty plasma.

  16. Validation of the load-resilient ion cyclotron resonance frequency antenna concept on Tore Supra plasmas

    NASA Astrophysics Data System (ADS)

    Vulliez, K.; Argouarch, A.; Bosia, G.; Berger-By, G.; Bremond, S.; Colas, L.; Lombard, G.; Mendes, A.; Millon, L.; Mollard, P.; Volpe, D.; Beaumont, B.; Bécoulet, A.; Clairet, F.; Ekedahl, A.; Elkhaldi, M.; Gunn, J.; Hoang, G. T.; Tore Supra Team

    2008-06-01

    In the framework of the ion cyclotron resonance frequency heating development at CEA Cadarache, a prototype antenna based on the load-resilient electrical layout foreseen for ITER has been built. This prototype was recently tested in Tore Supra. The ITER-like electrical scheme has been validated during fast perturbations at the edge plasma. Clear load resilience properties are reported. The main conclusions and consequences learned from the development of the ITER antenna are discussed.

  17. Frequency-Domain Tomography for Single-shot, Ultrafast Imaging of Evolving Laser-Plasma Accelerators

    NASA Astrophysics Data System (ADS)

    Li, Zhengyan; Zgadzaj, Rafal; Wang, Xiaoming; Downer, Michael

    2011-10-01

    Intense laser pulses propagating through plasma create plasma wakefields that often evolve significantly, e.g. by expanding and contracting. However, such dynamics are known in detail only through intensive simulations. Laboratory visualization of evolving plasma wakes in the ``bubble'' regime is important for optimizing and scaling laser-plasma accelerators. Recently snap-shots of quasi-static wakes were recorded using frequency-domain holography (FDH). To visualize the wake's evolution, we have generalized FDH to frequency-domain tomography (FDT), which uses multiple probes propagating at different angles with respect to the pump pulse. Each probe records a phase streak, imprinting a partial record of the evolution of pump-created structures. We then topographically reconstruct the full evolution from all phase streaks. To prove the concept, a prototype experiment visualizing nonlinear index evolution in glass is demonstrated. Four probes propagating at 0, 0.6, 2, 14 degrees to the index ``bubble'' are angularly and temporally multiplexed to a single spectrometer to achieve cost-effective FDT. From these four phase streaks, an FDT algorithm analogous to conventional CT yields a single-shot movie of the pump's self-focusing dynamics.

  18. Focused excimer laser initiated, radio frequency sustained high pressure air plasmas

    SciTech Connect

    Giar, Ryan; Scharer, John

    2011-11-15

    Measurements and analysis of air breakdown processes and plasma production by focusing 193 nm, 300 mJ, 15 MW high power laser radiation inside a 6 cm diameter helical radio frequency (RF) coil are presented. Quantum resonant multi-photon ionization (REMPI) and collisional cascade laser ionization processes are exploited that have been shown to produce high-density (n{sub e} {approx} 7 x 10{sup 16}/cm{sup 3}) cylindrical seed plasmas at 760 Torr. Air breakdown in lower pressures (from 7-22 Torr), where REMPI is the dominant laser ionization process, is investigated using an UV 18 cm focal length lens, resulting in a laser flux of 5.5 GW/cm{sup 2} at the focal spot. The focused laser power absorption and associated shock wave produce seed plasmas for sustainment by the RF (5 kW incident power, 1.5 s) pulse. Measurements of the helical RF antenna load impedance in the inductive and capacitive coupling regimes are obtained by measuring the loaded antenna reflection coefficient. A 105 GHz interferometer is used to measure the plasma electron density and collision frequency. Spectroscopic measurements of the plasma and comparison with the SPECAIR code are made to determine translational, rotational, and vibrational neutral temperatures and the associated neutral gas temperature. From this and the associated measurement of the gas pressure the electron temperature is obtained. Experiments show that the laser-formed seed plasma allows RF sustainment at higher initial air pressures (up to 22 Torr) than that obtained via RF-only initiation (<18 Torr) by means of a 0.3 J UV laser pulse.

  19. Experimental Investigation on Electromagnetic Attenuation by Low Pressure Radio-Frequency Plasma for Cavity Structure

    NASA Astrophysics Data System (ADS)

    He, Xiang; Zhang, Yachun; Chen, Jianping; Chen, Yudong; Zeng, Xiaojun; Yao, Hong; Tang, Chunmei

    2016-01-01

    This paper reports on an experiment designed to test electromagnetic (EM) attenuation by radio-frequency (RF) plasma for cavity structures. A plasma reactor, in the shape of a hollow cylinder, filled with argon gas at low pressure, driven by a RF power source, was produced by wave-transmitting material. The detailed attenuations of EM waves were investigated under different conditions: the incident frequency is 1-4 GHz, the RF power supply is 13.56 MHz and 1.6-3 kW, and the argon pressure is 75-200 Pa. The experimental results indicate that 5-15 dB return loss can be obtained. From a first estimation, the electron density in the experiment is approximately (1.5-2.2) × 1016 m-3 and the collision frequency is about 11-30 GHz. The return loss of EM waves was calculated using a finite-difference time-domain (FDTD) method and it was found that it has a similar development with measurement. It can be confirmed that RF plasma is useful in the stealth of cavity structures such as jet-engine inlet. supported by National Natural Science Foundation of China (No. 51107033) and the Fundamental Research Funds for the Central Universities of China (No. 2013B33614)

  20. Plasma microRNA Expression and Micronuclei Frequency in Workers Exposed to Polycyclic Aromatic Hydrocarbons

    PubMed Central

    Deng, Qifei; Huang, Suli; Zhang, Xiao; Zhang, Wangzhen; Feng, Jing; Wang, Tian; Hu, Die; Guan, Lei; Li, Jun; Dai, Xiayun; Deng, Huaxin; Zhang, Xiaomin

    2014-01-01

    Background: Ubiquitous polycyclic aromatic hydrocarbons (PAHs) have been shown to alter gene expression patterns and elevate micronuclei (MN) frequency, but the underlying mechanisms are largely unknown. MicroRNAs (miRNAs) are key gene regulators that may be influenced by PAH exposures and mediate their effects on MN frequency. Objectives: We sought to identify PAH-associated miRNAs and evaluate their associations with MN frequency. Methods: We performed a two-stage study in healthy male coke oven workers to identify miRNAs associated with PAH exposures quantified using urinary monohydroxy-PAHs and plasma benzo[a]pyrene-r-7,t-8,c-10-tetrahydrotetrol-albumin (BPDE–Alb) adducts. In the discovery stage, we used Solexa sequencing to test differences in miRNA expression profiles between pooled plasma samples from 20 exposed workers and 20 controls. We then validated associations with eight selected miRNAs in 365 workers. We further evaluated associations between the PAH-associated miRNAs and MN frequency. Results: In the discovery stage, miRNA expression profiles differed between the exposed and control groups, with 68 miRNAs significantly down-regulated [fold change (FC) ≤ –5] and 3 miRNAs mildly up-regulated (+2 ≤ FC < +5) in the exposed group. In the validation analysis, urinary 4-hydroxyphenanthrene and/or plasma BPDE–Alb adducts were associated with lower miR-24-3p, miR-27a-3p, miR-142-5p, and miR-28-5p expression (p < 0.030). Urinary 1-hydroxynaphthalene, 2-hydroxynaphthalene, 2-hydroxyphenanthrene, and the sum of monohydroxy-PAHs were associated with higher miR-150-5p expression (p < 0.030). These miRNAs were associated with higher MN frequency (p < 0.005), with stronger associations in drinkers (pinteraction < 0.015). Conclusions: Associations of PAH exposures with miRNA expression, and of miRNA expression with MN frequency, suggest potential mechanisms of adverse effects of PAHs that are worthy of further investigation. Citation: Deng Q, Huang S

  1. Photoluminescence Quenching in Single-Layer MoS2 via Oxygen Plasma Treatment

    NASA Astrophysics Data System (ADS)

    Kang, Narae; Paudel, Hari P.; Leuenberger, Michael N.; Tetard, Laurene; Khondaker, Saiful I.

    2015-03-01

    Ultrathin two-dimensional (2D) layered transition dichalcogenides (TMDs) families have emerged as a new class of semiconducting candidates due to its intrinsic bandgap. The ability to control the properties of 2D TMDs will become a key in the development of future electronic and optoelectronic applications; however, altering the properties via creating and manipulating defects through external control is not fully investigated yet. In this work, we studied tunable optical properties of single-layer (SL) MoS2 by applying time-dependent oxygen plasma exposure. As the exposure time increased, the strong photoluminescence (PL) of SL MoS2 changed to complete quenching accompanied by clear changes in Raman spectra with gradual reduction of MoS2 peaks as well as an appearance of oxidization-induced peak of Mo-O bonds formation. Using band structure calculations, we found that the creation of MoO3 disordered-domains led to plasma-induced direct-to-indirect bandgap transition in defected SL MoS2, resulting in PL quenching with lattice distortion. Our results suggest new opportunities of tailoring and understanding the properties of 2D TMDs.

  2. Mitigation of electron attachment to oxygen in high pressure air plasmas by vibrational excitation

    NASA Astrophysics Data System (ADS)

    Frederickson, K.; Lee, W.; Palm, P.; Adamovich, I. V.; Rich, J. W.; Lempert, W. R.

    2007-05-01

    A series of time resolved microwave attenuation measurements are performed of the electron number density of an electron beam generated, CO laser excited nonequilibrium O2/N2 plasma. Resonant absorption of infrared radiation from the CO laser produces the nonequilibrium state, in which the heavy species vibrational modes are disproportionately excited, compared to the rotational and translational modes (Tvib≈2000-3000K vs TR /T≈300K). It is shown that this results in an increase in the plasma free electron lifetime by two orders of magnitude compared to the unexcited cold gas, an effect which is ascribed to complete mitigation of rapid three-body electron attachment to molecular oxygen. A series of heavy species filtered pure rotational Raman scattering measurements are also presented, which exhibit minimal temperature change (+50K), indicating that the observed lifetime increase cannot be due to heavy-species thermal effects. Finally, computational modeling results infer an increase in the rate of O2- detachment by four to five orders of magnitude, compared to the equilibrium value.

  3. Frequency up-conversion of a high-power microwave pulse propagating in a self-generated plasma

    NASA Technical Reports Server (NTRS)

    Kuo, S. P.; Ren, A.

    1992-01-01

    In the study of the propagation of a high-power microwave pulse, one of the main concerns is how to minimize the energy loss of the pulse before reaching the destination. A frequency autoconversion process that can lead to reflectionless propagation of powerful electromagnetic pulses in self-generated plasmas is studied. The theory shows that, under the proper condition, the carrier frequency omega of the pulse shifts upward during the growth of local plasma frequency omega(pe). Thus, the self-generated plasma remains underdense to the pulse. A chamber experiment to demonstrate the frequency autoconversion during the pulse propagation through the self-generated plasma is conducted. The detected frequency shift is compared with the theoretical result calculated by using the measured electron density distribution along the propagation path of the pulse. Good agreement is obtained.

  4. Study of electron current extraction from a radio frequency plasma cathode designed as a neutralizer for ion source applications

    NASA Astrophysics Data System (ADS)

    Jahanbakhsh, Sina; Satir, Mert; Celik, Murat

    2016-02-01

    Plasma cathodes are insert free devices that are developed to be employed as electron sources in electric propulsion and ion source applications as practical alternatives to more commonly used hollow cathodes. Inductively coupled plasma cathodes, or Radio Frequency (RF) plasma cathodes, are introduced in recent years. Because of its compact geometry, and simple and efficient plasma generation, RF plasma source is considered to be suitable for plasma cathode applications. In this study, numerous RF plasma cathodes have been designed and manufactured. Experimental measurements have been conducted to study the effects of geometric and operational parameters. Experimental results of this study show that the plasma generation and electron extraction characteristics of the RF plasma cathode device strongly depend on the geometric parameters such as chamber diameter, chamber length, orifice diameter, orifice length, as well as the operational parameters such as RF power and gas mass flow rate.

  5. Study of electron current extraction from a radio frequency plasma cathode designed as a neutralizer for ion source applications.

    PubMed

    Jahanbakhsh, Sina; Satir, Mert; Celik, Murat

    2016-02-01

    Plasma cathodes are insert free devices that are developed to be employed as electron sources in electric propulsion and ion source applications as practical alternatives to more commonly used hollow cathodes. Inductively coupled plasma cathodes, or Radio Frequency (RF) plasma cathodes, are introduced in recent years. Because of its compact geometry, and simple and efficient plasma generation, RF plasma source is considered to be suitable for plasma cathode applications. In this study, numerous RF plasma cathodes have been designed and manufactured. Experimental measurements have been conducted to study the effects of geometric and operational parameters. Experimental results of this study show that the plasma generation and electron extraction characteristics of the RF plasma cathode device strongly depend on the geometric parameters such as chamber diameter, chamber length, orifice diameter, orifice length, as well as the operational parameters such as RF power and gas mass flow rate. PMID:26932094

  6. Effect of source frequency and pulsing on the SiO2 etching characteristics of dual-frequency capacitive coupled plasma

    NASA Astrophysics Data System (ADS)

    Kim, Hoe Jun; Jeon, Min Hwan; Mishra, Anurag Kumar; Kim, In Jun; Sin, Tae Ho; Yeom, Geun Young

    2015-01-01

    A SiO2 layer masked with an amorphous carbon layer (ACL) has been etched in an Ar/C4F8 gas mixture with dual frequency capacitively coupled plasmas under variable frequency (13.56-60 MHz)/pulsed rf source power and 2 MHz continuous wave (CW) rf bias power, the effects of the frequency and pulsing of the source rf power on the SiO2 etch characteristics were investigated. By pulsing the rf power, an increased SiO2 etch selectivity was observed with decreasing SiO2 etch rate. However, when the rf power frequency was increased, not only a higher SiO2 etch rate but also higher SiO2 etch selectivity was observed for both CW and pulse modes. A higher CF2/F ratio and lower electron temperature were observed for both a higher source frequency mode and a pulsed plasma mode. Therefore, when the C 1s binding states of the etched SiO2 surfaces were investigated using X-ray photoelectron spectroscopy (XPS), the increase of C-Fx bonding on the SiO2 surface was observed for a higher source frequency operation similar to a pulsed plasma condition indicating the increase of SiO2 etch selectivity over the ACL. The increase of the SiO2 etch rate with increasing etch selectivity for the higher source frequency operation appears to be related to the increase of the total plasma density with increasing CF2/F ratio in the plasma. The SiO2 etch profile was also improved not only by using the pulsed plasma but also by increasing the source frequency.

  7. Microwave induced plasma discharge in multi-cell superconducting radio-frequency cavity

    SciTech Connect

    Ahmed, Shahid; Mammosser, John D.

    2015-07-15

    A R&D effort for in situ cleaning of 1.5 GHz Superconducting Radio Frequency (SRF) cavities at room temperature using the plasma processing technique has been initiated at Jefferson Lab. This is a step toward the cleaning of cryomodules installed in the Continuous Electron Beam Accelerator Facility (CEBAF). For this purpose, we have developed an understanding of plasma discharge in a 5-cell CEBAF-type SRF cavity having configurations similar to those in the main accelerator. The focus of this study involves the detailed investigations of developing a plasma discharge inside the cavity volume and avoids the breakdown condition in the vicinity of the ceramic RF window. A plasma discharge of the gas mixture Ar–O{sub 2} (90%:10%) can be established inside the cavity volume by the excitation of a resonant 4π/5 TM{sub 010}-mode driven by a klystron. The absence of any external magnetic field for generating the plasma is suitable for cleaning cavities installed in a complex cryomodule assembly. The procedures developed in these experimental investigations can be applied to any complex cavity structure. Details of these experimental measurements and the observations are discussed in the paper.

  8. Creating nanoporosity in silver nanocolumns by direct exposure to radio-frequency air plasma

    NASA Astrophysics Data System (ADS)

    El Mel, Abdel-Aziz; Stephant, Nicolas; Hamon, Jonathan; Thiry, Damien; Chauvin, Adrien; Chettab, Meriem; Gautron, Eric; Konstantinidis, Stephanos; Granier, Agnès; Tessier, Pierre-Yves

    2015-12-01

    Nanoporous materials are of great importance for a broad range of applications including catalysis, optical sensors and water filtration. Although several approaches already exist for the creation of nanoporous materials, the race for the development of versatile methods, more suitable for the nanoelectronics industry, is still ongoing. In this communication we report for the first time on the possibility of generating nanoporosity in silver nanocolumns using a dry approach based on the oxidation of silver by direct exposure to a commercially available radio-frequency air plasma. The silver nanocolumns are created by glancing angle deposition using magnetron sputtering of a silver target in pure argon plasma. We show that upon exposure to the rf air plasma, the nanocolumns transform from solid silver into nanoporous silver oxide. We further show that by tuning the plasma pressure and the exposure duration, the oxidation process can be finely adjusted allowing for precisely controlling the morphology and the nanoporosity of the silver oxide nanocolumns. The generation of porosity within the silver nanocolumns is explained according to a cracking-induced oxidation mechanism based on two repeated events occurring alternately during the oxidation process: (i) oxidation of silver upon exposure to the air plasma and (ii) generation of nanocracks and blisters within the oxide layer due to the high internal stress generated within the material during oxidation.

  9. Microwave induced plasma discharge in multi-cell superconducting radio-frequency cavity

    NASA Astrophysics Data System (ADS)

    Ahmed, Shahid; Mammosser, John D.

    2015-07-01

    A R&D effort for in situ cleaning of 1.5 GHz Superconducting Radio Frequency (SRF) cavities at room temperature using the plasma processing technique has been initiated at Jefferson Lab. This is a step toward the cleaning of cryomodules installed in the Continuous Electron Beam Accelerator Facility (CEBAF). For this purpose, we have developed an understanding of plasma discharge in a 5-cell CEBAF-type SRF cavity having configurations similar to those in the main accelerator. The focus of this study involves the detailed investigations of developing a plasma discharge inside the cavity volume and avoids the breakdown condition in the vicinity of the ceramic RF window. A plasma discharge of the gas mixture Ar-O2 (90%:10%) can be established inside the cavity volume by the excitation of a resonant 4π/5 TM010-mode driven by a klystron. The absence of any external magnetic field for generating the plasma is suitable for cleaning cavities installed in a complex cryomodule assembly. The procedures developed in these experimental investigations can be applied to any complex cavity structure. Details of these experimental measurements and the observations are discussed in the paper.

  10. Microwave induced plasma discharge in multi-cell superconducting radio-frequency cavity.

    PubMed

    Ahmed, Shahid; Mammosser, John D

    2015-07-01

    A R&D effort for in situ cleaning of 1.5 GHz Superconducting Radio Frequency (SRF) cavities at room temperature using the plasma processing technique has been initiated at Jefferson Lab. This is a step toward the cleaning of cryomodules installed in the Continuous Electron Beam Accelerator Facility (CEBAF). For this purpose, we have developed an understanding of plasma discharge in a 5-cell CEBAF-type SRF cavity having configurations similar to those in the main accelerator. The focus of this study involves the detailed investigations of developing a plasma discharge inside the cavity volume and avoids the breakdown condition in the vicinity of the ceramic RF window. A plasma discharge of the gas mixture Ar-O2 (90%:10%) can be established inside the cavity volume by the excitation of a resonant 4π/5 TM010-mode driven by a klystron. The absence of any external magnetic field for generating the plasma is suitable for cleaning cavities installed in a complex cryomodule assembly. The procedures developed in these experimental investigations can be applied to any complex cavity structure. Details of these experimental measurements and the observations are discussed in the paper. PMID:26233368

  11. Creating nanoporosity in silver nanocolumns by direct exposure to radio-frequency air plasma.

    PubMed

    El Mel, Abdel-Aziz; Stephant, Nicolas; Hamon, Jonathan; Thiry, Damien; Chauvin, Adrien; Chettab, Meriem; Gautron, Eric; Konstantinidis, Stephanos; Granier, Agnès; Tessier, Pierre-Yves

    2016-01-01

    Nanoporous materials are of great importance for a broad range of applications including catalysis, optical sensors and water filtration. Although several approaches already exist for the creation of nanoporous materials, the race for the development of versatile methods, more suitable for the nanoelectronics industry, is still ongoing. In this communication we report for the first time on the possibility of generating nanoporosity in silver nanocolumns using a dry approach based on the oxidation of silver by direct exposure to a commercially available radio-frequency air plasma. The silver nanocolumns are created by glancing angle deposition using magnetron sputtering of a silver target in pure argon plasma. We show that upon exposure to the rf air plasma, the nanocolumns transform from solid silver into nanoporous silver oxide. We further show that by tuning the plasma pressure and the exposure duration, the oxidation process can be finely adjusted allowing for precisely controlling the morphology and the nanoporosity of the silver oxide nanocolumns. The generation of porosity within the silver nanocolumns is explained according to a cracking-induced oxidation mechanism based on two repeated events occurring alternately during the oxidation process: (i) oxidation of silver upon exposure to the air plasma and (ii) generation of nanocracks and blisters within the oxide layer due to the high internal stress generated within the material during oxidation. PMID:26611109

  12. Investigation of modulated radio frequency plasma etching of GaAs using Langmuir probes

    SciTech Connect

    Law, V.J.; Braithwaite, N.St.J.; Ingram, S.G.

    1994-11-01

    Radio frequency ClCH{sub 3}/H{sub 2} plasma etching of GaAs is examined in the 10-140 mTorr pressure ranging using square-wave modulation of the excitation source to control the etching. A Langmuir probe is used to measure time-resolved electron density, characteristic temperature, and floating potential during the plasma afterglow period. The ClCH{sub 3}/H{sub 2} plasma electron energy is found to be 1.2 {+-} 0.3 eV. The near afterglow plasma density decay has a time constant in the order of {tau}=30 {mu}s at 140 mTorr for 10%-20% ClCh{sub 3} in H{sub 2} and {tau}=100 {mu}s for H{sub 2}. The floating potential continues to decay into the far afterglow, with a characteristic time of the order of milliseconds. The Langmuir probe measurements indicate that the ClCH{sub 3} plasmas the near afterglow is dominated by electron attachment, whereas the far afterglow is dominated by ambipolar diffusion. The GaAs etch rate experiments show that surface reactions continue into the far afterglow, dominating the behavior of the time average etch rate. 11 refs., 5 figs., 1 tab.

  13. In situ measurements of ionospheric plasma turbulence over five frequency decades: Heritage flight of the Plasma Local Anomalous Noise Experiment (PLANE)

    NASA Astrophysics Data System (ADS)

    Habash Krause, L.; Enloe, C. L.; McHarg, M. G.

    2013-12-01

    Observations of ionospheric plasma density and frequency-dependent broadband plasma turbulence made during the heritage flight of the Plasma Local Anomalous Noise Experiment (PLANE) are presented. Rather than record high frequency time series data, the experiment was designed to record Power Spectral Distributions (PSDs) in five decadal frequency bins with upper limits ranging from 1.0 Hz to 10 kHz. Additionally, PLANE was designed distinguish turbulence in the ambient plasma from that local to the spacecraft. The instrument consists of two retarding potential analyzers (RPAs) connected together via a feedback loop to force one analyzer into the I-V trace retardation region at all times. Fluctuations in this measurement are believed to be ambient only as the RPA's voltage would be too high for locally turbulent plasma to surmount the potential barrier, which is nominally at ram energy. The instrument requires pointing along the spacecraft's ram velocity vector to make this measurement, thus requiring stabilization in pitch and yaw. During PLANE's heritage flight, though the satellite's attitude control system failed early in the mission, plasma data were collected during opportune times in which the instrument rotated into and out of the ram. Observations of plasma density and PSDs of high frequency plasma turbulence were recorded on several occasions. Additionally, a plasma source onboard the satellite was used to generate artificial plasma turbulence, and the PLANE data observed periodic structure presumably associated with the rotation of the spacecraft during these source firings. A brief comparison with other high frequency in situ plasma instruments is presented.

  14. Diocotron modulation in an electron plasma through continuous radio-frequency excitation

    SciTech Connect

    Paroli, B. Maero, G.; Pozzoli, R.; Romé, M.

    2014-12-15

    The application of a radio-frequency (RF) excitation to any electrode of a Penning-Malmberg trap may result in significant electron heating and ionization of the residual gas with the formation of a plasma column when the RF frequency is of the order or larger than the typical axial bounce frequencies of few-eV electrons. The use of a quadrupolar excitation can induce additional phenomena, like formation of dense, narrow-cross section columns which exhibit an m{sub θ}=1 diocotron mode, i.e., a rotation of their center around the trap axis. A series of experiments is presented and discussed showing that the continuous application of such excitation causes a dramatic perturbation of the plasma equilibrium also involving continuous production and loss of particles in the trapping region. In particular, the growth of the first diocotron mode is suppressed even in the presence of ion resonance and resistive instability and the mode exhibits steady-state or underdamped amplitude and frequency modulations, typically in the Hertz range.

  15. Propagation in a shearing plasma. II - Turbulence and the frequency range of pulsar microstructure

    NASA Technical Reports Server (NTRS)

    Harding, A. K.; Tademaru, E.

    1980-01-01

    Numerical calculations are presented which explore the propagation of radio waves and pulses through a turbulent shearing plasma. A stochastic model is used to describe the turbulent velocity field, in which random fluctuations are superposed on a mean profile. Both Gaussian wave packets and shot-noise pulses polarized in the plane of shearing acquire quasi-periodic intensity modulations above the rest-frame plasma frequency. The frequency range over which these modulations appear is shown to depend on the spatial correlation length of the turbulent fluctuations and on their standard deviation from the mean velocity. The period of the modulations is variable from one realization of the random process to the next, and the average period is frequency dependent. The results of these calculations lend further support to a model for pulsar microstructure in which periodic micropulses are pure temporal modulations of the emitted radiation due to propagation effects in magnetospheric shearing regions. It is shown that turbulence on a scale of approximately 10 cm can produce these quasi-periodic modulations over a frequency range comparable to that of observed microstructure.

  16. Numerical investigation on electrical characterization of a capacitive coupled radio-frequency plasma

    NASA Astrophysics Data System (ADS)

    Yao, H.; He, X.; Chen, J. P.; Zhang, Y. C.

    2015-05-01

    This paper presents the main electrical features of capacitive coupled radio-frequency (CCRF) discharges in gas. A two-dimensional, time-dependent fluid model was established. Capacitive coupled plasmas (CCP) were produced by applying radio-frequency voltage to a pair of parallel plate electrodes which are separated from the plasma by dielectric layers. The electron equation and the electron transport equations were solved and yielded the electron number density and electron temperature. The electrostatic field was obtained by the solution of the Poisson equation. The distribution of electron temperature and electron number density was studied under different conditions: radio-frequency applied voltages (VRF=100-2000V), frequencies (f=3.0-40.68MHz), pressures (p=0.001-1torr), and gas species (O2, Ar, He, N2). The results show that electron number density presents a minimum near the electrodes, and presents a maximum between the positive and the negative electrodes. The distinguishing feature of CCP is the presence of oscillating sheaths near electrodes where displacement current dominates conduction current. These informations will help us to analyze the characters of CCP for application.

  17. Solitons and chaos of the Klein-Gordon-Zakharov system in a high-frequency plasma

    NASA Astrophysics Data System (ADS)

    Zhen, Hui-Ling; Tian, Bo; Sun, Ya; Chai, Jun; Wen, Xiao-Yong

    2015-10-01

    In this paper, we study the Klein-Gordon-Zakharov (KGZ) system, which describes the interaction between the Langmuir wave and ion sound wave in a high-frequency plasma. By means of the Hirota method and symbolic computation, bright and mixed-type soliton solutions are obtained. For the one soliton, amplitude of E is positively related to β 2 , and that of n is inversely related to β 2 , while they are both positively related to α, where E refers to the high-frequency part of the electrostatic potential of the electric field raised by the electrons, and n represents the deviation of ion density from its equilibrium, β 2 and α are the plasma frequency and ion sound speed, respectively. Head-on interactions between the two bright solitons and two mixed-type ones are respectively displayed. With β 2 increasing, the head-on interaction is transformed into an overtaking one. Bright bound-state solitons are investigated, and the interaction period decreases with α increasing. Furthermore, with the external forces Γ 1 ( t ) and Γ 2 ( t ) introduced, the perturbed KGZ system is studied numerically for its associated chaotic motions. Both the weak and developed chaotic motions can be observed. Γ 1 ( t ) and Γ 2 ( t ) have different effects on the chaotic motions: the chaotic motion can be weakened by decreasing the amplitude of Γ 1 ( t ) or increasing the amplitude and frequency of Γ 2 ( t ) .

  18. ICPP: Low-frequency, inductively coupled plasma sources: operation and applications

    NASA Astrophysics Data System (ADS)

    Xu, Shuyan

    2000-10-01

    Low-frequency, inductively coupled plasmas (LFICP) have recently attracted great attention in connection with the plasma processing of materials. The low-frequency sources feature high plasma density (10^18 - 10^19 m-3), excellent uniformity over large areas, low electron temperature, moderate plasma potential, deeper RF filed penetration and high power transfer efficiency. This work presents a comprehensive experimental and theoretical investigation of the electric/electromagnetic properties, electron density and temperature, and the optical emission in 500 kHz ICP sources. A series of experiments conducted in Ar/N_2/H2 and CH4 discharges show that the high-density plasmas are generated in the two distinctive E- and H- operating regimes. Near the mode transitions the power reflection coefficient exhibits resonant minima. The optical emission spectra of neutral atoms and ions together with global power balance arguments reveal that the step-wise ionization via excited states can be responsible for delaying the backward transition between the H- and E- discharge states, and, hence, lead to hysteresis. The experimental and theoretical results on the discharge mode transitions and hysteresis are discussed as well. It is demonstrated that the low-frequency ICP source is extremely efficient for nitriding of solid materials, especially of stainless steel. A low-temperature ( 350^oC) steel nitriding experiments undertaken in plasmas of various Ar/N_2/H2 gas mixtures show that very high nitriding rates, ranging from 40 μm/hour (stainless steel AISI304) to 90 μm/hour (AISI410), can be achieved. The microstructure, phases and composition of the nitrided surface layers have been characterized by Scanning Electron Microscopy, x-ray photoelectron spectroscopy, x-ray diffraction spectroscopy and energy dispersive x-ray spectroscopy. It has been shown that the crystalline phases of the nitrided layer can efficiently be controlled by the processing conditions. The nitrogen

  19. REACTIVE OXYGEN SPECIES IN WHOLE BLOOD, BLOOD PLASMA AND BREAST MILK: VALIDATION OF A POTENTIAL MARKER OF EXPOSURE AND EFFECT

    EPA Science Inventory

    Reactive oxygen species (ROS) are recognized to contribute to the pathobiology of many diseases. We have applied a simple chemiluminescent (CL) probe to detect ROS in various biological fluids (plasma, whole blood, urine and breast milk) in an environmental arsenic drinking wate...

  20. Dispersion relations and polarizations of low-frequency waves in two-fluid plasmas

    SciTech Connect

    Zhao, Jinsong

    2015-04-15

    Analytical expressions for the dispersion relations and polarizations of low-frequency waves in magnetized plasmas based on two-fluid model are obtained. The properties of waves propagating at different angles (to the ambient magnetic field B{sub 0}) and β (the ratio of the plasma to magnetic pressures) values are investigated. It is shown that two linearly polarized waves—namely, the fast and Alfvén modes in the low-β (β≪1) plasmas, the fast and slow modes in the β∼1 plasmas, and the Alfvén and slow modes in the high-β (β≫1) plasmas—become circularly polarized at the near-parallel (to B{sub 0}) propagation. The negative magnetic-helicity of the Alfvén mode occurs only at small or moderate angles in the low-β plasmas, and the ion cross-helicity of the slow mode is nearly the same as that of the Alfvén mode in the high-β plasmas. It is also shown that the electric polarization δE{sub z}/δE{sub y} decreases with the temperature ratio T{sub e}/T{sub i} for the long-wavelength waves, and the transition between left- and right-hand polarizations of the Alfvén mode in T{sub e}/T{sub i}≠0 plasmas can disappear when T{sub e}/T{sub i}=0. The approximate dispersion relations in the near-perpendicular propagation, low-β, and high-β limits can quite accurately describe the three modes.

  1. Effects of microwave and oxygen plasma treatments on capacitive characteristics of supercapacitor based on multiwalled carbon nanotubes

    NASA Astrophysics Data System (ADS)

    Dulyaseree, Paweena; Yordsri, Visittapong; Wongwiriyapan, Winadda

    2016-02-01

    The effects of microwave and oxygen plasma treatments on the capacitive characteristics of a supercapacitor based on multiwalled carbon nanotubes (MWNTs) were investigated. MWNTs were heat-treated under air ambient at 500 °C for 1 h, and subsequently microwave-treated at 650 W for 70 s (m-MWNTs). Another batch of MWNTs was treated by oxygen plasma for 30 min (p-MWNTs). Pristine MWNTs, m-MWNTs, and p-MWNTs were separately used as electrode materials for supercapacitors. Their cyclic voltammetry, galvanostatic charge/discharge, and electrochemical impedance spectroscopy results were analyzed. The p-MWNTs show the best performance with a specific capacitance of 238.23 F·g-1. The capacitance improvement is attributed to the increase in the number of oxygen-containing functional groups, as evidenced by Fourier transform-infrared spectroscopy and contact angle measurement. These results suggest that oxygen plasma treatment is a rapid and efficient method for oxygen functionalization.

  2. Metal-containing fluoropolymer films produced by simultaneous plasma etching and polymerization: Effects of hydrogen or oxygen

    NASA Astrophysics Data System (ADS)

    Kay, E.; Dilks, A.; Seybold, D.

    1980-11-01

    The formation of metal-containing fluoropolymer films by simultaneous plasma etching and polymerization in a radiofrequency diode reactor configuration is investigated as a function of additive scavenger gases. The addition of oxygen to plasmas excited in tetrafluoroethylene or perfluoropropane is found to enhance the etching rate at the excitation metal electrode and diminish the polymer film deposition rate at the grounded electrode. The overall effect is to increase the metal content of the films. The addition of hydrogen to plasmas excited in tetrafluoromethane or perfluoropropane has the opposite effect. X-ray photoelectron spectroscopy is employed to determine the composition and structure of the films, and this coupled with mass spectrometric analysis of the plasma gas phase chemistry has allowed the identification of the likely precursors to plasma polymerization for the systems studied.

  3. He+O{sub 2}+H{sub 2}O plasmas as a source of reactive oxygen species

    SciTech Connect

    Liu, D. X.; Wang, X. H.; Rong, M. Z.; Iza, F.; Kong, M. G.

    2011-05-30

    The effect of water in the chemistry of atmospheric-pressure He+O{sub 2} plasmas is studied by means of a comprehensive global model. Water enables the generation of reactive oxygen species (ROS) cocktails that are rich not only in O, O{sub 2}*, and O{sub 3} but also in OH and H{sub 2}O{sub 2}. Due to its polar nature, water also leads to cluster formation, possibly affecting the plasma dynamics. Since the lifetime of many of the ROS is short, the plasma chemistry plays two roles: (i) direct interaction with superficial cells and (ii) triggering of a secondary chemistry that propagates the plasma treatment to regions away from the plasma-surface interface.

  4. Fokker-Planck description of the scattering of radio frequency waves at the plasma edge

    SciTech Connect

    Hizanidis, Kyriakos; Kominis, Yannis; Tsironis, Christos; Ram, Abhay K.

    2010-02-15

    In magnetic fusion devices, radio frequency (rf) waves in the electron cyclotron (EC) and lower hybrid (LH) range of frequencies are being commonly used to modify the plasma current profile. In ITER, EC waves are expected to stabilize the neoclassical tearing mode (NTM) by providing current in the island region [R. Aymar et al., Nucl. Fusion 41, 1301 (2001)]. The appearance of NTMs severely limits the plasma pressure and leads to the degradation of plasma confinement. LH waves could be used in ITER to modify the current profile closer to the edge of the plasma. These rf waves propagate from the excitation structures to the core of the plasma through an edge region, which is characterized by turbulence--in particular, density fluctuations. These fluctuations, in the form of blobs, can modify the propagation properties of the waves by refraction. In this paper, the effect on rf due to randomly distributed blobs in the edge region is studied. The waves are represented as geometric optics rays and the refractive scattering from a distribution of blobs is formulated as a Fokker-Planck equation. The scattering can have two diffusive effects--one in real space and the other in wave vector space. The scattering can modify the trajectory of rays into the plasma and it can affect the wave vector spectrum. The refraction of EC waves, for example, could make them miss the intended target region where the NTMs occur. The broadening of the wave vector spectrum could broaden the wave generated current profile. The Fokker-Planck formalism for diffusion in real space and wave vector space is used to study the effect of density blobs on EC and LH waves in an ITER type of plasma environment. For EC waves the refractive effects become important since the distance of propagation from the edge to the core in ITER is of the order of a meter. The diffusion in wave vector space is small. For LH waves the refractive effects are insignificant but the diffusion in wave vector space is

  5. EDITORIAL: The interaction of radio-frequency fields with fusion plasmas: the JET experience The interaction of radio-frequency fields with fusion plasmas: the JET experience

    NASA Astrophysics Data System (ADS)

    Ongena, Jef

    2012-07-01

    The JET Task Force Heating is proud to present this special issue. It is the result of hard and dedicated work by everybody participating in the Task Force over the last four years and gives an overview of the experimental and theoretical results obtained in the period 2008-2010 with radio frequency heating of JET fusion plasmas. Topics studied and reported in this issue are: investigations into the operation of lower hybrid heating accompanied by new modeling results; new experimental results and insights into the physics of various ion cyclotron range of frequencies (ICRF) heating scenarios; progress in studies of intrinsic and ion cyclotron wave-induced plasma rotation and flows; a summary of the developments over the last years in designing an ion cyclotron radiofrequency heating (ICRH) system that can cope with the presence of fast load variations in the edge, as e.g. caused by pellets or edge localized modes (ELMs) during H-Mode operation; an overview of the results obtained with the ITER-like antenna operating in H-Mode with a packed array of straps and power densities close to those of the projected ITER ICRH antenna; and, finally, a summary of the results obtained in applying ion cyclotron waves for wall conditioning of the tokamak. This issue would not have been possible without the strong motivation and efforts (sometimes truly heroic) of all colleagues of the JET Task Force Heating. A sincere word of thanks, therefore, to all authors and co-authors involved in the experiments, analysis and compilation of the papers. It was a special privilege to work with all of them during the past very intense years. Thanks also to all other European and non-European scientists who contributed to the JET scientific programme, the operations team of JET and the colleagues of the Close Support Unit in Culham. Thanks also to the editors, Editorial Board and referees of Plasma Physics and Controlled Fusion, together with the publishing staff of IOPP, who have not only

  6. Biodegradability of oxygen-plasma treated cellulose textile functionalized with ZnO nanoparticles as antibacterial treatment

    NASA Astrophysics Data System (ADS)

    Primc, Gregor; Tomšič, Brigita; Vesel, Alenka; Mozetič, Miran; Ercegović Ražić, Sanja; Gorjanc, Marija

    2016-08-01

    Samples of bleached cellulose fabric were treated with weakly ionized highly dissociated oxygen plasma in order to improve the binding of ZnO nanoparticles, antibacterial properties and biodegradability. Low specific discharge power of about 24 W l‑1 was applied in order to minimize thermal effects following plasma treatment. Optical emission spectroscopy revealed weak etching of the fabric while x-ray photoelectron spectroscopy showed formation of oxygen-rich functional groups. Scanning electron microscopy revealed an improved uptake of ZnO nanoparticles and the standard transfer method highlighted excellent antimicrobial effects for Staphylococcus aureus and Escherichia coli. The biodegradability of all samples was determined using the standard ISO test and revealed excellent results for plasma-treated samples even in cases when they were functionalized using ZnO nanoparticles.

  7. Quantitative Determination of Density of Ground State Atomic Oxygen from Both TALIF and Emission Spectroscopy in Hot Air Plasma Generated by Microwave Resonant Cavity

    NASA Astrophysics Data System (ADS)

    Marchal, F.; Yousfi, M.; Merbahi, N.; Wattieaux, G.; Piquemal, A.

    2016-03-01

    Two experimental techniques have been used to quantify the atomic oxygen density in the case of hot air plasma generated by a microwave (MW) resonant cavity. The latter operates at a frequency of 2.45 GHz inside a cell of gas conditioning at a pressure of 600 mbar, an injected air flow of 12 L/min and an input MW power of 1 kW. The first technique is based on the standard two photon absorption laser induced fluorescence (TALIF) using xenon for calibration but applied for the first time in the present post discharge hot air plasma column having a temperature of about 4500 K near the axis of the nozzle. The second diagnostic technique is an actinometry method based on optical emission spectroscopy (OES). In this case, we compared the spectra intensities of a specific atomic oxygen line (844 nm) and the closest wavelength xenon line (823 nm). The two lines need to be collected under absolutely the same spectroscopic parameters. The xenon emission is due to the addition of a small proportion of xenon (1% Xe) of this chemically inert gas inside the air while a further small quantity of H2 (2%) is also added in the mixture in order to collect OH(A-X) and NH(A-X) spectra without noise. The latter molecular spectra are required to estimate gas and excitation temperatures. Optical emission spectroscopy measurements, at for instance the position z=12 mm on the axis plasma column that leads to a gas measured temperature equal to 3500 K, an excitation temperature of about 9500 K and an atomic oxygen density 2.09×1017±0.2×1017 cm-3. This is in very good agreement with the TALIF measurement, which is equal to 2.0×1017 cm-3.

  8. Impact of interstitial oxygen trapped in silicon during plasma growth of silicon oxy-nitride films for silicon solar cell passivation

    NASA Astrophysics Data System (ADS)

    Saseendran, Sandeep S.; Saravanan, S.; Raval, Mehul C.; Kottantharayil, Anil

    2016-03-01

    Low temperature oxidation of silicon in plasma ambient is a potential candidate for replacing thermally grown SiO2 films for surface passivation of crystalline silicon solar cells. In this work, we report the growth of silicon oxy-nitride (SiOxNy) film in N2O plasma ambient at 380 °C. However, this process results in trapping of interstitial oxygen within silicon. The impact of this trapped interstitial oxygen on the surface passivation quality is investigated. The interstitial oxygen trapped in silicon was seen to decrease for larger SiOxNy film thickness. Effective minority carrier lifetime (τeff) measurements on n-type float zone silicon wafers passivated by SiOxNy/silicon nitride (SiNv:H) stack showed a decrease in τeff from 347 μs to 68 μs, for larger SiOxNy film thickness due to degradation in interface properties. From high frequency capacitance-voltage measurements, it was concluded that the surface passivation quality was governed by the interface parameters (fixed charge density and interface state density). High temperature firing of the SiOxNy/SiNv:H stack resulted in a severe degradation in τeff due to migration of oxygen across the interface into silicon. However, on using the SiOxNy/SiNv:H stack for emitter surface passivation in screen printed p-type Si solar cells, an improvement in short wavelength response was observed in comparison to the passivation by SiNv:H alone, indicating an improvement in emitter surface passivation quality.

  9. Broadband frequency ECR ion source concepts with large resonant plasma volumes

    SciTech Connect

    Alton, G.D.

    1995-12-31

    New techniques are proposed for enhancing the performances of ECR ion sources. The techniques are based on the use of high-power, variable-frequency, multiple-discrete-frequency, or broadband microwave radiation, derived from standard TWT technology, to effect large resonant ``volume`` ECR sources. The creation of a large ECR plasma ``volume`` permits coupling of more power into the plasma, resulting in the heating of a much larger electron population to higher energies, the effect of which is to produce higher charge state distributions and much higher intensities within a particular charge state than possible in present forms of the ECR ion source. If successful, these developments could significantly impact future accelerator designs and accelerator-based, heavy-ion-research programs by providing multiply-charged ion beams with the energies and intensities required for nuclear physics research from existing ECR ion sources. The methods described in this article can be used to retrofit any ECR ion source predicated on B-minimum plasma confinement techniques.

  10. [Effect of radio frequency discharge plasma on surface properties and biocompatibility of polycaprolactone matrices].

    PubMed

    Bolbasov, E N; Antonova, L V; Matveeva, V G; Novikov, V A; Shesterikov, E V; Bogomolova, N L; Golovkin, A S; Tverdohlebov, S I; Barbarash, O L; Barbarash, L S

    2016-01-01

    Surface modification of bioresorbable polymer material (polycaprolactone, PCL) with abnormal glow discharge, initiated during radio-frequency magnetron sputtering of a hydroxyapatite target was investigated. Plasma treatment resulted in an increase of surface roughness of PCL, crystallite size, the surface free energy and hydrophilicity. Increased treatment time (30, 60, 150 seconds) provoked the polymer surface saturation with the sputtering target ions (calcium, phosphorus). The assessment of plasma exposure of PCL surface on bone marrow multipotent mesenchymal stromal cells behavior (BM MSCs) has been performed. Modification of the polymer surface with the abnormal glow discharge stimulated adhesion and subsequent proliferation of BM MSCs; thus, maximum values were achieved with the surface treatment for 60 s. This type of plasma modification did not affect cell viability (apoptosis, necrosis). Thus, the surface modification with abnormal glow discharge, initiated during radio-frequency magnetron sputtering of a hydroxyapatite target, appear to be a promising method of surface modification of bioresorbable polymer material (PCL) for tissue engineering. PMID:26973188

  11. Laser guiding due to transverse frequency chirp and plasma inhomogeneity: Relevance to laser wakefield acceleration

    NASA Astrophysics Data System (ADS)

    Bandhu Pathak, Vishwa; Vieira, Jorge; Fonseca, Ricardo; Silva, Luis

    2012-10-01

    Multi-dimensional particle-in-cell (PIC) simulations using OSIRIS show that the transverse frequency chirp can induce pulse front tilt (PFT) in the laser as it propagates. The PFT leads to transverse inhomogeneity in the electron density at the laser front such that the laser drifts in the transverse direction followed by its wake and the injected/self-injected electron beam inside the blowout region. We further investigate the effect of the chirp and transverse plasma inhomogeneities (linear density gradient and parabolic plasma channel) on the transverse drift by developing an analytical model based on a variational principle approach. Theory and simulations predict a linear dependence of the frequency chirp on the transverse drift. In the presence of a linear density gradient the laser drifts towards the decreasing plasma density. We show that an appropriate transverse chirp can balance the drift, and can reduce/nullify the injected electron beam pointing angle. In extreme scenarios, dispersion effects due to transverse chirp can filament the laser generating multiple bubble in the same transverse plane.

  12. Tailored voltage waveform capacitively coupled plasmas in electronegative gases: frequency dependence of asymmetry effects

    NASA Astrophysics Data System (ADS)

    Schüngel, E.; Korolov, I.; Bruneau, B.; Derzsi, A.; Johnson, E.; O’Connell, D.; Gans, T.; Booth, J.-P.; Donkó, Z.; Schulze, J.

    2016-07-01

    Capacitively coupled radio frequency plasmas operated in an electronegative gas (CF4) and driven by voltage waveforms composed of four consecutive harmonics are investigated for different fundamental driving frequencies using PIC/MCC simulations and an analytical model. As has been observed previously for electropositive gases, the application of peak-shaped waveforms (that are characterized by a strong amplitude asymmetry) results in the development of a DC self-bias due to the electrical asymmetry effect (EAE), which increases the energy of ions arriving at the powered electrode. In contrast to the electropositive case (Korolov et al 2012 J. Phys. D: Appl. Phys. 45 465202) the absolute value of the DC self-bias is found to increase as the fundamental frequency is reduced in this electronegative discharge, providing an increased range over which the DC self-bias can be controlled. The analytical model reveals that this increased DC self-bias is caused by changes in the spatial profile and the mean value of the net charge density in the grounded electrode sheath. The spatio-temporally resolved simulation data show that as the frequency is reduced the grounded electrode sheath region becomes electronegative. The presence of negative ions in this sheath leads to very different dynamics of the power absorption of electrons, which in turn enhances the local electronegativity and plasma density via ionization and attachment processes. The ion flux to the grounded electrode (where the ion energy is lowest) can be up to twice that to the powered electrode. At the same time, while the mean ion energies at both electrodes are quite different, their ratio remains approximately constant for all base frequencies studied here.

  13. Effect of plasma parameters on characteristics of silicon nitride film deposited by single and dual frequency plasma enhanced chemical vapor deposition

    NASA Astrophysics Data System (ADS)

    Sahu, B. B.; Yin, Yongyi; Han, Jeon G.

    2016-03-01

    This work investigates the deposition of hydrogenated amorphous silicon nitride films using various low-temperature plasmas. Utilizing radio-frequency (RF, 13.56 MHz) and ultra-high frequency (UHF, 320 MHz) powers, different plasma enhanced chemical vapor deposition processes are conducted in the mixture of reactive N2/NH3/SiH4 gases. The processes are extensively characterized using different plasma diagnostic tools to study their plasma and radical generation capabilities. A typical transition of the electron energy distribution function from single- to bi-Maxwellian type is achieved by combining RF and ultra-high powers. Data analysis revealed that the RF/UHF dual frequency power enhances the plasma surface heating and produces hot electron population with relatively low electron temperature and high plasma density. Using various film analysis methods, we have investigated the role of plasma parameters on the compositional, structural, and optical properties of the deposited films to optimize the process conditions. The presented results show that the dual frequency power is effective for enhancing dissociation and ionization of neutrals, which in turn helps in enabling high deposition rate and improving film properties.

  14. Kinetic theory of low-frequency cross-field instability in a weakly ionized plasma. I

    SciTech Connect

    Dimant, Y.S.; Sudan, R.N.

    1995-04-01

    A consistent kinetic theory is developed for the description of electrons under conditions of a low-frequency two-stream {bold E}{times}{bold B} instability in collisionally dominated, weakly ionized plasmas. Starting from the Boltzmann collision integral, a simplified kinetic equation for the electron distribution function has been derived, which takes into account strong pitch-angle scattering of electrons by neutrals, velocity dependence of the electron--neutral collision frequency, etc. Linearized equations describing small oscillations of the electron distribution function and ion density are presented. For the asymptotic case of short waves, the dispersion relation of the {bold E}{times}{bold B} instability has been obtained and analyzed under conditions typical for the lower ionosphere. Under certain conditions, the rigorous kinetic consideration yields substantial changes in results compared to previous theories. The general approach may be applied to other linear and nonlinear low-frequency processes in a weakly ionized plasma. {copyright} {ital 1995} {ital American} {ital Institute} {ital of} {ital Physics}.

  15. Self-excitation of the plasma series resonance in radio-frequency discharges: An analytical description

    SciTech Connect

    Czarnetzki, U.; Mussenbrock, T.; Brinkmann, R. P.

    2006-12-15

    Self-excited plasma series resonances (PSR) are observed in capacitve discharges as high-frequency oscillations superimposed on the normal rf current. This high-frequency contribution to the current is generated by a series resonance between the capacitive sheath and the inductive and ohmic bulk of the plasma. The nonlinearity of the sheath leads to a complex dynamic. The effect is applied, e.g., as a diagnostic technique in commercial etch reactors where analysis is performed by a numerical model. Here a simple analytical investigation is introduced. In order to solve the nonlinear equations analytically, a series of approximation is necessary. Nevertheless, the basic physics is conserved and excellent agreement with numerical solutions is found. The model provides explicit and simple formula for the current waveform and the spectral range of the oscillations. In particular, the dependence on the discharge parameters is shown. Further, the model gives insight into an additional dissipation channel opened by the high-frequency oscillations. With decreasing pressure, the ohmic resistance of the bulk decreases as well, while the amplitude of the PSR oscillations grows. This results in substantially higher power dissipation that exceeds the contribution of classical stochastic heating.

  16. Plasma characteristics of argon glow discharge produced by AC power supply operating at low frequencies

    SciTech Connect

    Kongpiboolkid, Watcharapon; Mongkolnavin, Rattachat

    2015-04-24

    Non-thermal properties of Argon glow discharge operating with various operating pressures were measured and presented in this work. The Argon plasma is produced by a parallel conducting electrodes coupling with a high voltage AC power supply. The power supply can generate high AC voltage at various frequencies. The frequencies for the operation are in the range of a few kHz. The system is capable of generating electric field between the two metal electrodes discharge system. The characteristics of plasma produced were measured by optical emission spectroscopy (OES) technique where electron temperature (T{sub e}) and electron number density (n{sub e}) can be determined by line intensity ratio method. The value of electron number density was then determined from the Saha-Eggert equation. Our results show that the electron number density of the discharge obtained is of the order of 10{sup −17} − 10{sup −18} m{sup −3} where the electron temperature is between 1.00−2.00 eV for various operating frequencies used which are in good agreement with similar results published earlier.

  17. High and low frequency instabilities driven by counter-streaming electron beams in space plasmas

    SciTech Connect

    Mbuli, L. N.; Maharaj, S. K.; Bharuthram, R.

    2014-05-15

    A four-component plasma composed of a drifting (parallel to ambient magnetic field) population of warm electrons, drifting (anti-parallel to ambient magnetic field) cool electrons, stationary hot electrons, and thermal ions is studied in an attempt to further our understanding of the excitation mechanisms of broadband electrostatic noise (BEN) in the Earth's magnetospheric regions such as the magnetosheath, plasmasphere, and plasma sheet boundary layer (PSBL). Using kinetic theory, beam-driven electrostatic instabilities such as the ion-acoustic, electron-acoustic instabilities are found to be supported in our multi-component model. The dependence of the instability growth rates and real frequencies on various plasma parameters such as beam speed, number density, temperature, and temperature anisotropy of the counter-streaming (relative to ambient magnetic field) cool electron beam are investigated. It is found that the number density of the anti-field aligned cool electron beam and drift speed play a central role in determining which instability is excited. Using plasma parameters which are closely correlated with the measurements made by the Cluster satellites in the PSBL region, we find that the electron-acoustic and ion-acoustic instabilities could account for the generation of BEN in this region.

  18. Pinch-plasma radiation source for extreme-ultraviolet lithography with a kilohertz repetition frequency.

    PubMed

    Bergmann, K; Rosier, O; Neff, W; Lebert, R

    2000-08-01

    An extreme-ultraviolet radiation source based on a xenon pinch plasma is discussed with respect to the demands on a radiation source for extreme-ultraviolet lithography. Operation of the discharge in a self-igniting-plasma mode and omitting a switch permits a very effective and low-inductive coupling of the electrically stored energy to the electrode system. The xenon plasma exhibits broadband emission characteristics that offer radiation near 11 and 13 nm. Both wavelengths are useful in combination with beryllium- and silicon-based multilayer mirrors. The plasma emits approximately 74 mW/sr at 11.5 nm and 40 mW/sr at 13.5 nm in a bandwidth of 2% when operated at a repetition frequency of 120 Hz. The source size is less than 500 microm in diameter (FWHM) when viewed from the axial direction. The pulse-to-pulse stability is better than 3.6%. First results with a repetition rate of as much as 6 kHz promise the possibility of scaling to the required emission power for extreme-ultraviolet lithography. PMID:18349959

  19. Surface modification of polyelectrolyte multilayers by high radio frequency air plasma treatment

    NASA Astrophysics Data System (ADS)

    Martins, Tiago Dias; Bataglioli, Rogério Aparecido; Taketa, Thiago Bezerra; Vasconcellos, Fernando da Cruz; Beppu, Marisa Masumi

    2015-02-01

    Low-temperature plasma treatments are used to perform surface modification on polymers, aiming to improve the surface properties according to the desired application. In this work, polyelectrolyte multilayers (PEMs), built by layer-by-layer deposition technique, were treated using high frequency low-temperature air plasma. We evaluated the effect of the exposure time (20 and 300 s) and its effects on PEMs with two different top layers: alginate and carboxymethylcellulose. Chitosan was used as the cationic polymer to build the LbL films with the oppositely charged anionic polymers, alginate and carboxymethylcellulose. Our results showed that the surface topology, wettability and free charges within layers are highly correlated to the polymer pair used. PEMs of the chitosan/alginate system are thinner and hydrophilic, and present a surface with wider peaks. We found that plasma treatment promotes substantial changes on the PEMs and that 20 s of exposure time is enough to perform these changes. In all cases, after plasma treatment, PEMs' thickness and free charge distribution were reduced and wettability was enhanced.

  20. Emissive sheath measurements in the afterglow of a radio frequency plasma

    SciTech Connect

    Sheehan, J. P. Hershkowitz, N.; Barnat, E. V.; Weatherford, B. R.; Kaganovich, I. D.

    2014-01-15

    The difference between the plasma potential and the floating potential of a highly emissive planar surface was measured in the afterglow of a radio frequency discharge. A Langmuir probe was used to measure the electron temperature and an emissive probe was used to measure the spatial distribution of the potential using the inflection point in the limit of zero emission technique. Time-resolved measurements were made using the slow-sweep method, a technique for measuring time-resolved current-voltage traces. This was the first time the inflection point in the limit of zero emission was used to make time-resolved measurements. Measurements of the potential profile of the presheath indicate that the potential penetrated approximately 50% farther into the plasma when a surface was emitting electrons. The experiments confirmed a recent kinetic theory of emissive sheaths, demonstrating that late in the afterglow as the plasma electron temperature approached the emitted electron temperature, the emissive sheath potential shrank to zero. However, the difference between the plasma potential and the floating potential of a highly emissive planar surface data appeared to be much less sensitive to the electron temperature ratio than the theory predicts.