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Sample records for fuel fabrication phase

  1. Solid polymer electrolyte (SPE) fuel cell technology program, phase 1/1A. [design and fabrication

    NASA Technical Reports Server (NTRS)

    1975-01-01

    A solid polymer electrolyte fuel cell was studied for the purpose of improving the characteristics of the technology. Several facets were evaluated, namely: (1) reduced fuel cell costs; (2) reduced fuel cell weight; (3) improved fuel cell efficiency; and (4) increased systems compatibility. Demonstrated advances were incorporated into a full scale hardware design. A single cell unit was fabricated. A substantial degree of success was demonstrated.

  2. Monolithic Fuel Fabrication Process Development

    SciTech Connect

    C. R. Clark; N. P. Hallinan; J. F. Jue; D. D. Keiser; J. M. Wight

    2006-05-01

    The pursuit of a high uranium density research reactor fuel plate has led to monolithic fuel, which possesses the greatest possible uranium density in the fuel region. Process developments in fabrication development include friction stir welding tool geometry and cooling improvements and a reduction in the length of time required to complete the transient liquid phase bonding process. Annealing effects on the microstructures of the U-10Mo foil and friction stir welded aluminum 6061 cladding are also examined.

  3. Update On Monolithic Fuel Fabrication Development

    SciTech Connect

    C. R Clark; J. M. Wight; G. C. Knighton; G. A. Moore; J. F. Jue

    2005-11-01

    Efforts to develop a viable monolithic research reactor fuel plate have continued at Idaho National Laboratory. These efforts have concentrated on both fabrication process refinement and scale-up to produce full sized fuel plates. Advancements have been made in the production of U-Mo foil including full sized foils. Progress has also been made in the friction stir welding and transient liquid phase bonding fabrication processes resulting in better bonding, more stable processes and the ability to fabricate larger fuel plates.

  4. Automated breeder fuel fabrication

    SciTech Connect

    Goldmann, L.H.; Frederickson, J.R.

    1983-09-01

    The objective of the Secure Automated Fabrication (SAF) Project is to develop remotely operated equipment for the processing and manufacturing of breeder reactor fuel pins. The SAF line will be installed in the Fuels and Materials Examination Facility (FMEF). The FMEF is presently under construction at the Department of Energy's (DOE) Hanford site near Richland, Washington, and is operated by the Westinghouse Hanford Company (WHC). The fabrication and support systems of the SAF line are designed for computer-controlled operation from a centralized control room. Remote and automated fuel fabriction operations will result in: reduced radiation exposure to workers; enhanced safeguards; improved product quality; near real-time accountability, and increased productivity. The present schedule calls for installation of SAF line equipment in the FMEF beginning in 1984, with qualifying runs starting in 1986 and production commencing in 1987. 5 figures.

  5. Fabrication and characterization of anode-supported micro-tubular solide oxide fuel cell by phase inversion method

    NASA Astrophysics Data System (ADS)

    Ren, Cong

    Nowadays, the micro-tubular solid oxide fuel cells (MT-SOFCs), especially the anode supported MT-SOFCs have been extensively developed to be applied for SOFC stacks designation, which can be potentially used for portable power sources and vehicle power supply. To prepare MT-SOFCs with high electrochemical performance, one of the main strategies is to optimize the microstructure of the anode support. Recently, a novel phase inversion method has been applied to prepare the anode support with a unique asymmetrical microstructure, which can improve the electrochemical performance of the MT-SOFCs. Since several process parameters of the phase inversion method can influence the pore formation mechanism and final microstructure, it is essential and necessary to systematically investigate the relationship between phase inversion process parameters and final microstructure of the anode supports. The objective of this study is aiming at correlating the process parameters and microstructure and further preparing MT-SOFCs with enhanced electrochemical performance. Non-solvent, which is used to trigger the phase separation process, can significantly influence the microstructure of the anode support fabricated by phase inversion method. To investigate the mechanism of non-solvent affecting the microstructure, water and ethanol/water mixture were selected for the NiO-YSZ anode supports fabrication. The presence of ethanol in non-solvent can inhibit the growth of the finger-like pores in the tubes. With the increasing of the ethanol concentration in the non-solvent, a relatively dense layer can be observed both in the outside and inside of the tubes. The mechanism of pores growth and morphology obtained by using non-solvent with high concentration ethanol was explained based on the inter-diffusivity between solvent and non-solvent. Solvent and non-solvent pair with larger Dm value is benefit for the growth of finger-like pores. Three cells with different anode geometries was

  6. Neutronic fuel element fabrication

    DOEpatents

    Korton, George

    2004-02-24

    This disclosure describes a method for metallurgically bonding a complete leak-tight enclosure to a matrix-type fuel element penetrated longitudinally by a multiplicity of coolant channels. Coolant tubes containing solid filler pins are disposed in the coolant channels. A leak-tight metal enclosure is then formed about the entire assembly of fuel matrix, coolant tubes and pins. The completely enclosed and sealed assembly is exposed to a high temperature and pressure gas environment to effect a metallurgical bond between all contacting surfaces therein. The ends of the assembly are then machined away to expose the pin ends which are chemically leached from the coolant tubes to leave the coolant tubes with internal coolant passageways. The invention described herein was made in the course of, or under, a contract with the U.S. Atomic Energy Commission. It relates generally to fuel elements for neutronic reactors and more particularly to a method for providing a leak-tight metal enclosure for a high-performance matrix-type fuel element penetrated longitudinally by a multiplicity of coolant tubes. The planned utilization of nuclear energy in high-performance, compact-propulsion and mobile power-generation systems has necessitated the development of fuel elements capable of operating at high power densities. High power densities in turn require fuel elements having high thermal conductivities and good fuel retention capabilities at high temperatures. A metal clad fuel element containing a ceramic phase of fuel intimately mixed with and bonded to a continuous refractory metal matrix has been found to satisfy the above requirements. Metal coolant tubes penetrate the matrix to afford internal cooling to the fuel element while providing positive fuel retention and containment of fission products generated within the fuel matrix. Metal header plates are bonded to the coolant tubes at each end of the fuel element and a metal cladding or can completes the fuel-matrix enclosure

  7. FUEL ELEMENT FABRICATION METHOD

    DOEpatents

    Hix, J.N.; Cooley, G.E.; Cunningham, J.E.

    1960-05-31

    A method is given for assembling and fabricating a fuel element comprising a plurality of spaced parallel fuel plates of a bowed configuration supported by and between a pair of transperse aluminum side plates. In this method, a brasing alloy is preplated on one surface of the aluminum side plates in the form of a cladding or layer-of uniform thickness. Grooves are then cut into the side plates through the alloy layer and into the base aluminum which results in the utilization of thinner aluminum side plates since a portion of the necessary groove depth is supplied by the brazing alloy.

  8. Fabrication of particle dispersed inert matrix fuel based on liquid phase sintered SiC

    NASA Astrophysics Data System (ADS)

    Pavlyuchkov, D.; Baney, R. H.; Tulenko, J. S.; Seifert, H. J.

    2011-08-01

    In the present work, liquid phase sintered SiC (LPS-SiC) was proposed as an inert matrix for the particle dispersed inert matrix fuel (IMF). The fuel particles containing plutonium and minor actinides were substituted with pure yttria stabilized zirconia beads. The LPS-SiC matrix was produced from the initial mixtures prepared using submicron sized α-SiC powder and oxide additives Al 2O 3, Y 2O 3 in the amount of 10 wt.% with the molar ratio 1Y 2O 3/1Al 2O 3. Powder mixtures were sintered using two sintering methods; namely conventional high temperature sintering and novel spark plasma sintering at different temperatures depending on the method applied in order to obtain dense samples. The phase reaction products were identified using X-ray diffraction (XRD) and microstructures were investigated using light microscopy and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM/EDX) techniques. The influence of powder mixing methods, sintering temperatures, pressures applied and holding time on the density of the obtained pellets was investigated. The samples sintered by slow conventional sintering show lower relative density and more pronounced interaction between the fuel particles and matrix in comparison with those obtained with the fast spark plasma sintering method.

  9. Fabrication of thorium bearing carbide fuels

    DOEpatents

    Gutierrez, R.L.; Herbst, R.J.; Johnson, K.W.R.

    Thorium-uranium carbide and thorium-plutonium carbide fuel pellets have been fabricated by the carbothermic reduction process. Temperatures of 1750/sup 0/C and 2000/sup 0/C were used during the reduction cycle. Sintering temperatures of 1800/sup 0/C and 2000/sup 0/C were used to prepare fuel pellet densities of 87% and > 94% of theoretical, respectively. The process allows the fabrication of kilogram quantities of fuel with good reproductibility of chemical and phase composition.

  10. Fabrication and characterization of anode-supported micro-tubular solide oxide fuel cell by phase inversion method

    NASA Astrophysics Data System (ADS)

    Ren, Cong

    Nowadays, the micro-tubular solid oxide fuel cells (MT-SOFCs), especially the anode supported MT-SOFCs have been extensively developed to be applied for SOFC stacks designation, which can be potentially used for portable power sources and vehicle power supply. To prepare MT-SOFCs with high electrochemical performance, one of the main strategies is to optimize the microstructure of the anode support. Recently, a novel phase inversion method has been applied to prepare the anode support with a unique asymmetrical microstructure, which can improve the electrochemical performance of the MT-SOFCs. Since several process parameters of the phase inversion method can influence the pore formation mechanism and final microstructure, it is essential and necessary to systematically investigate the relationship between phase inversion process parameters and final microstructure of the anode supports. The objective of this study is aiming at correlating the process parameters and microstructure and further preparing MT-SOFCs with enhanced electrochemical performance. Non-solvent, which is used to trigger the phase separation process, can significantly influence the microstructure of the anode support fabricated by phase inversion method. To investigate the mechanism of non-solvent affecting the microstructure, water and ethanol/water mixture were selected for the NiO-YSZ anode supports fabrication. The presence of ethanol in non-solvent can inhibit the growth of the finger-like pores in the tubes. With the increasing of the ethanol concentration in the non-solvent, a relatively dense layer can be observed both in the outside and inside of the tubes. The mechanism of pores growth and morphology obtained by using non-solvent with high concentration ethanol was explained based on the inter-diffusivity between solvent and non-solvent. Solvent and non-solvent pair with larger Dm value is benefit for the growth of finger-like pores. Three cells with different anode geometries was

  11. Innovative concepts for fuel plate fabrication

    SciTech Connect

    Domagala, R.F.; Wiencek, T.C.; Thresh, H.R.

    1987-10-01

    A number of fabrication concepts have been and are being explored at ANL. Although specific processes were addressed with silicide fuels in mind, most are applicable to fabrication with any fuel type. Processes include improved comminution procedures for converting U-Si alloy ingots to powder using a roll crusher and an impact mill. Aluminizing of core compacts by ion vapor deposition techniques in vacuum offers prospects for improved plate quality. Other items examined include the possible use of coatings on fuel particles, matrices different from pure Al, and ductile fuel alloys which might be used to produce fuel plates with uranium loadings higher than possible with conventional dispersed-phase powder metallurgy technology.

  12. Fabrication of thorium bearing carbide fuels

    DOEpatents

    Gutierrez, Rueben L.; Herbst, Richard J.; Johnson, Karl W. R.

    1981-01-01

    Thorium-uranium carbide and thorium-plutonium carbide fuel pellets have been fabricated by the carbothermic reduction process. Temperatures of 1750.degree. C. and 2000.degree. C. were used during the reduction cycle. Sintering temperatures of 1800.degree. C. and 2000.degree. C. were used to prepare fuel pellet densities of 87% and >94% of theoretical, respectively. The process allows the fabrication of kilogram quantities of fuel with good reproducibility of chemicals and phase composition. Methods employing liquid techniques that form carbide microspheres or alloying-techniques which form alloys of thorium-uranium or thorium-plutonium suffer from limitation on the quantities processed of because of criticality concerns and lack of precise control of process conditions, respectively.

  13. Integrated Recycling Test Fuel Fabrication

    SciTech Connect

    R.S. Fielding; K.H. Kim; B. Grover; J. Smith; J. King; K. Wendt; D. Chapman; L. Zirker

    2013-03-01

    The Integrated Recycling Test is a collaborative irradiation test that will electrochemically recycle used light water reactor fuel into metallic fuel feedstock. The feedstock will be fabricated into a metallic fast reactor type fuel that will be irradiation tested in a drop in capsule test in the Advanced Test Reactor on the Idaho National Laboratory site. This paper will summarize the fuel fabrication activities and design efforts. Casting development will include developing a casting process and system. The closure welding system will be based on the gas tungsten arc burst welding process. The settler/bonder system has been designed to be a simple system which provides heating and controllable impact energy to ensure wetting between the fuel and cladding. The final major pieces of equipment to be designed are the weld and sodium bond inspection system. Both x-radiography and ultrasonic inspection techniques have been examine experimentally and found to be feasible, however the final remote system has not been designed. Conceptual designs for radiography and an ultrasonic system have been made.

  14. Fuel Fabrication Capability Research and Development Plan

    SciTech Connect

    Senor, David J.; Burkes, Douglas

    2013-06-28

    The purpose of this document is to provide a comprehensive review of the mission of the Fuel Fabrication Capability (FFC) within the Global Threat Reduction Initiative (GTRI) Convert Program, along with research and development (R&D) needs that have been identified as necessary to ensuring mission success. The design and fabrication of successful nuclear fuels must be closely linked endeavors.

  15. UPDATE ON MONOLITHIC FUEL FABRICATION METHODS

    SciTech Connect

    C. R. Clark; J. F. Jue; G. A. Moore; N. P. Hallinan; B. H. Park; D. E. Burkes

    2006-10-01

    Efforts to develop a viable monolithic research reactor fuel plate have continued at Idaho National Laboratory. These efforts have concentrated on both fabrication process refinement and scale-up to produce full sized fuel plates. Progress at INL has led to fabrication of hot isostatic pressed uranium-molybdenum bearing monolithic fuel plates. These miniplates are part of the RERTR-8 miniplate irradiation test. Further progress has also been made on friction stir weld processing which has been used to fabricate full size fuel plates which will be irradiated in the ATR and OSIRIS reactors.

  16. Design, Fabrication, and Operation of Innovative Microalgae Culture Experiments for the Purpose of Producing Fuels: Final Report, Phase I

    SciTech Connect

    Not Available

    1985-01-01

    A conceptual design was developed for a 1000-acre (water surface) algae culture facility for the production of fuels. The system is modeled after the shallow raceway system with mixing foils that is now being operated at the University of Hawaii. A computer economic model was created to calculate the discounted breakeven price of algae or fuels produced by the culture facility. A sensitivity analysis was done to estimate the impact of changes in important biological, engineering, and financial parameters on product price.

  17. Electric Fuel Rod Simulator Fabrication at ORNL

    SciTech Connect

    Ott, Larry J.; McCulloch, Reg

    2004-02-04

    Commercial vendors could not supply the high-quality, highly instrumented electric fuel rod simulators (FRS) required for large thermal-hydraulic safety-oriented experiments at the Oak Ridge National Laboratory (ORNL) in the 1970s and early 1980s. Staff at ORNL designed, developed, and manufactured the simulators utilized in these safety experiments. Important FRS design requirements include (1) materials of construction, (2) test power requirements and availability, (3) experimental test objectives, (4) supporting thermal analyses, and (5) extensive quality control throughout all phases of FRS fabrication. This paper will present an overview of these requirements (design, analytics, and quality control) as practiced at ORNL to produce a durable high-quality FRS.

  18. Electric Fuel Rod Simulator Fabrication at ORNL

    NASA Astrophysics Data System (ADS)

    Ott, Larry J.; McCulloch, Reg

    2004-02-01

    Commercial vendors could not supply the high-quality, highly instrumented electric fuel rod simulators (FRS) required for large thermal-hydraulic safety-oriented experiments at the Oak Ridge National Laboratory (ORNL) in the 1970s and early 1980s. Staff at ORNL designed, developed, and manufactured the simulators utilized in these safety experiments. Important FRS design requirements include (1) materials of construction, (2) test power requirements and availability, (3) experimental test objectives, (4) supporting thermal analyses, and (5) extensive quality control throughout all phases of FRS fabrication. This paper will present an overview of these requirements (design, analytics, and quality control) as practiced at ORNL to produce a durable high-quality FRS.

  19. Fabrication of FFTF fuel pin wire wrap

    SciTech Connect

    Epperson, E.M.

    1980-06-01

    Lateral spacing between FFTF fuel pins is required to provide a passageway for the sodium coolant to flow over each pin to remove heat generated by the fission process. This spacing is provided by wrapping each fuel pin with type 316 stainless steel wire. This wire has a 1.435mm (0.0565 in.) to 1.448mm (0.0570 in.) diameter, contains 17 +- 2% cold work and was fabricated and tested to exacting RDT Standards. About 500 kg (1100 lbs) or 39 Km (24 miles) of fuel pin wrap wire is used in each core loading. Fabrication procedures and quality assurance tests are described.

  20. Cermet fuel for fast reactor - Fabrication and characterization

    NASA Astrophysics Data System (ADS)

    Mishra, Sudhir; Kutty, P. S.; Kutty, T. R. G.; Das, Shantanu; Dey, G. K.; Kumar, Arun

    2013-11-01

    (U, Pu)O2 ceramic fuel is the well-established fuel for the fast reactors and (U, Pu, Zr) metallic fuel is the future fuel. Both the fuels have their own merits and demerits. Optimal solution may lie in opting for a fuel which combines the favorable features of both fuel systems. The choice may be the use of cermet fuel which can be either (U, PuO2) or (Enriched U, UO2). In the present study, attempt has been made to fabricate (Natural U, UO2) cermet fuel by powder metallurgy route. Characterization of the fuel has been carried out using dilatometer, differential thermal analyzer, X-ray diffractometer, and Scanning Electron Microscope. The results show a high solidus temperature, high thermal expansion, presence of porosities, etc. in the fuel. The thermal conductivity of the fuel has also been measured. X-ray diffraction study on the fuel compact reveals presence of α U and UO2 phases in the matrix of the fuel.

  1. Fabrication of capsule assemblies, phase 3

    NASA Technical Reports Server (NTRS)

    Keeton, A. R.; Stemann, L. G.

    1973-01-01

    Thirteen capsule assemblies were fabricated for evaluation of fuel pin design concepts for a fast spectrum lithium cooled compact space power reactor. These instrumented assemblies were designed for real time test of prototype fuel pins. Uranium mononitride fuel pins were encased in AISI 304L stainless steel capsules. Fabrication procedures were fully qualified by process development and assembly qualification tests. Instrumentation reliability was achieved utilizing specially processed and closely controlled thermocouple hot zone fabrication and by thermal screening tests. Overall capsule reliability was achieved with an all electron beam welded assembly.

  2. Method to fabricate high performance tubular solid oxide fuel cells

    SciTech Connect

    Chen, Fanglin; Yang, Chenghao; Jin, Chao

    2013-06-18

    In accordance with the present disclosure, a method for fabricating a solid oxide fuel cell is described. The method includes forming an asymmetric porous ceramic tube by using a phase inversion process. The method further includes forming an asymmetric porous ceramic layer on a surface of the asymmetric porous ceramic tube by using a phase inversion process. The tube is co-sintered to form a structure having a first porous layer, a second porous layer, and a dense layer positioned therebetween.

  3. Secure automated fabrication: remote fabrication of breeder-reactor fuel

    SciTech Connect

    Gerber, E.W.; Rice, L.H.; Horgos, R.M.; Nagamoto, T.T.; Graham, R.A.

    1981-05-01

    The Secure Automated Fabrication (SAF) Program was initiated at the Hanford Engineering Development Laboratory (HEDL) to develop and demonstrate an advanced manufacturing line (SAF line) for plutonium oxide breeder reactor fuel pins. The SAF line is to be installed in the Fuels and Materials Examination Facility (FMEF) at Hanford and will utilize technology that focuses on improved safety features for plant operating personnel, the public, and the environment. Equipment and process improvements incorporated by the SAF line will yield significant gains in nuclear materials safeguards, product quality and productivity.

  4. Fabrication of oxide dispersion strengthened ferritic clad fuel pins

    SciTech Connect

    Zirker, L.R. ); Bottcher, J.H. ); Shikakura, S. ); Tsai, C.L. . Dept. of Welding Engineering); Hamilton, M.L. )

    1991-01-01

    A resistance butt welding procedure was developed and qualified for joining ferritic fuel pin cladding to end caps. The cladding are INCO MA957 and PNC ODS lots 63DSA and 1DK1, ferritic stainless steels strengthened by oxide dispersion, while the end caps are HT9 a martensitic stainless steel. With adequate parameter control the weld is formed without a residual melt phase and its strength approaches that of the cladding. This welding process required a new design for fuel pin end cap and weld joint. Summaries of the development, characterization, and fabrication processes are given for these fuel pins. 13 refs., 6 figs., 1 tab.

  5. Fuel Fabrication Capability Research and Development Plan

    SciTech Connect

    Senor, David J.; Burkes, Douglas

    2014-04-17

    The purpose of this document is to provide a comprehensive review of the mission of the Fuel Fabrication Capability (FFC) within the Global Threat Reduction Initiative Convert Program, along with research and development (R&D) needs that have been identified as necessary to ensuring mission success. The design and fabrication of successful nuclear fuels must be closely linked endeavors. Therefore, the overriding motivation behind the FFC R&D program described in this plan is to foster closer integration between fuel design and fabrication to reduce programmatic risk. These motivating factors are all interrelated, and progress addressing one will aid understanding of the others. The FFC R&D needs fall into two principal categories, 1) baseline process optimization, to refine the existing fabrication technologies, and 2) manufacturing process alternatives, to evaluate new fabrication technologies that could provide improvements in quality, repeatability, material utilization, or cost. The FFC R&D Plan examines efforts currently under way in regard to coupon, foil, plate, and fuel element manufacturing, and provides recommendations for a number of R&D topics that are of high priority but not currently funded (i.e., knowledge gaps). The plan ties all FFC R&D efforts into a unified vision that supports the overall Convert Program schedule in general, and the fabrication schedule leading up to the MP-1 and FSP-1 irradiation experiments specifically. The fabrication technology decision gates and down-selection logic and schedules are tied to the schedule for fabricating the MP-1 fuel plates, which will provide the necessary data to make a final fuel fabrication process down-selection. Because of the short turnaround between MP-1 and the follow-on FSP-1 and MP-2 experiments, the suite of specimen types that will be available for MP-1 will be the same as those available for FSP-1 and MP-2. Therefore, the only opportunity to explore parameter space and alternative processing

  6. Gas-Fast Reactor Fuel Fabrication

    SciTech Connect

    Randall Fielding; Mitchell Meyer; Ramprashad Prabhakaran; Jim Miller; Sean McDeavitt

    2005-11-01

    The gas-cooled fast reactor is a high temperature helium cooled Generation IV reactor concept. Operating parameters for this type of reactor are well beyond those of current fuels so a novel fuel must be developed. One fuel concept calls for UC particles dispersed throughout a SiC matrix. This study examines a hybrid reaction bonding process as a possible fabrication route for this fuel. Processing parameters are also optimized. The process combines carbon and SiC powders and a carbon yielding polymer. In order to obtain dense reaction bonded SiC samples the porosity to carbon ratio in the preform must be large enough to accommodate SiC formation from the carbon present in the sample, however too much porosity reduces mechanical integrity which leads to poor infiltration properties . The porosity must also be of a suitable size to allow silicon transport throughout the sample but keep residual silicon to a minimum.

  7. Update on US High Density Fuel Fabrication Development

    SciTech Connect

    C.R. Clark; G.A. Moore; J.F. Jue; B.H. Park; N.P. Hallinan; D.M. Wachs; D.E. Burkes

    2007-03-01

    Second generation uranium molybdenum fuel has shown excellent in-reactor irradiation performance. This metallic fuel type is capable of being fabricated at much higher loadings than any presently used research reactor fuel. Due to the broad range of fuel types this alloy system encompasses—fuel powder to monolithic foil and binary fuel systems to multiple element additions—significant amounts of research and development have been conducted on the fabrication of these fuels. This paper presents an update of the US RERTR effort to develop fabrication techniques and the fabrication methods used for the RERTR-9A miniplate test.

  8. Nuclear Fuel Plate Fabrication Employing Friction Welding

    SciTech Connect

    Douglas E. Burkes; Neil P. Hallinan; Curtis R. Clark

    2008-09-01

    This paper provides an overview of the friction bonding process, a novel modification of the more conventional friction stir welding process. The process has been modified to enable the fabrication of plate-type nuclear fuels for the conversion of research and test reactors currently operating using highly enriched uranium to low-enriched uranium. Discussions related to the specific modifications of the friction bonding process have been provided, in addition to challenges associated with these modifications. Progression of the process and solutions to the challenges are provided so that users of the friction stir welding process and those investigating fabrication of other laminar composites, where joining of one or more layers is essential, might draw from the authors’ experiences discussed in this paper.

  9. Phase Change Fabrics Control Temperature

    NASA Technical Reports Server (NTRS)

    2009-01-01

    Originally featured in Spinoff in 1997, Outlast Technologies Inc. (formerly Gateway Technologies Inc.) has built its entire product line on microencapsulated phase change materials, developed in Small Business Innovation Research (SBIR) contracts with Johnson Space Center after initial development for the U.S. Air Force. The Boulder, Colorado-based company acquired the exclusive patent rights and now integrates these materials into textiles or onto finished apparel, providing temperature regulation in bedding materials and a full line of apparel for both ordinary and extreme conditions.

  10. MONOLITHIC FUEL FABRICATION PROCESS DEVELOPMENT AT THE IDAHO NATIONAL LABORATORY

    SciTech Connect

    Glenn A. Moore; Francine J. Rice; Nicolas E. Woolstenhulme; W. David SwanK; DeLon C. Haggard; Jan-Fong Jue; Blair H. Park; Steven E. Steffler; N. Pat Hallinan; Michael D. Chapple; Douglas E. Burkes

    2008-10-01

    Within the Reduced Enrichment for Research and Test Reactors (RERTR) program directed by the US Department of Energy (DOE), UMo fuel-foils are being developed in an effort to realize high density monolithic fuel plates for use in high-flux research and test reactors. Namely, targeted are reactors that are not amenable to Low Enriched Uranium (LEU) fuel conversion via utilization of high density dispersion-based fuels, i.e. 8-9 gU/cc. LEU conversion of reactors having a need for >8-9 gU/cc fuel density will only be possible by way of monolithic fuel forms. The UMo fuel foils under development afford fuel meat density of ~16 gU/cc and thus have the potential to facilitate LEU conversions without any significant reactor-performance penalty. Two primary challenges have been established with respect to UMo monolithic fuel development; namely, fuel element fabrication and in-reactor fuel element performance. Both issues are being addressed concurrently at the Idaho National Laboratory. An overview is provided of the ongoing monolithic UMo fuel development effort at the Idaho National Laboratory (INL); including development of complex/graded fuel foils. Fabrication processes to be discussed include: UMo alloying and casting, foil fabrication via hot rolling, fuel-clad interlayer application via co-rolling and thermal spray processes, clad bonding via Hot Isostatic Pressing (HIP) and Friction Bonding (FB), and fuel plate finishing.

  11. Status of high-density fuel plates fabrication

    SciTech Connect

    Wiencek, T.C.; Domagala, R.F.; Thresh, H.R.

    1989-09-01

    Progress has continued on the fabrication of fuel plates with fuel zone loadings approaching 9gU/cm{sup 3}. Using Hot Isostatic Pressing (HIPping) successful diffusion bonds have been made with 110 Al and 6061 Al alloys. These bonds demonstrated the most critical processing step for proof-of-concept hardware. Two types of prototype highly-loaded fuel plates have been fabricated. First, a fuel plate in which 0.030 in. (0.76 mm) uranium compound wires are bonded within an aluminum cladding and second, a dispersion fuel plate with uniform cladding and fuel zone thickness. The successful fabrication of these fuel plates derives from the unique ability of the HIPping process to produce diffusion bonds with minimal deformation. 2 refs., 3 figs.

  12. Advanced Safeguards Approaches for New TRU Fuel Fabrication Facilities

    SciTech Connect

    Durst, Philip C.; Ehinger, Michael H.; Boyer, Brian; Therios, Ike; Bean, Robert; Dougan, A.; Tolk, K.

    2007-12-15

    This second report in a series of three reviews possible safeguards approaches for the new transuranic (TRU) fuel fabrication processes to be deployed at AFCF – specifically, the ceramic TRU (MOX) fuel fabrication line and the metallic (pyroprocessing) line. The most common TRU fuel has been fuel composed of mixed plutonium and uranium dioxide, referred to as “MOX”. However, under the Advanced Fuel Cycle projects custom-made fuels with higher contents of neptunium, americium, and curium may also be produced to evaluate if these “minor actinides” can be effectively burned and transmuted through irradiation in the ABR. A third and final report in this series will evaluate and review the advanced safeguards approach options for the ABR. In reviewing and developing the advanced safeguards approach for the new TRU fuel fabrication processes envisioned for AFCF, the existing international (IAEA) safeguards approach at the Plutonium Fuel Production Facility (PFPF) and the conceptual approach planned for the new J-MOX facility in Japan have been considered as a starting point of reference. The pyro-metallurgical reprocessing and fuel fabrication process at EBR-II near Idaho Falls also provided insight for safeguarding the additional metallic pyroprocessing fuel fabrication line planned for AFCF.

  13. MONOLITHIC FUEL FABRICATION PROCESS DEVELOPMENT AT THE IDAHO NATIONAL LABORATORY_

    SciTech Connect

    G. A. Moore; F. J. Rice; N. E. Woolstenhulme; J-F. Jue; B. H. Park; S. E. Steffler; N. P. Hallinan; M. D. Chapple; M. C. Marshall; B. L. Mackowiak; C. R. Clark; B. H. Rabin

    2009-11-01

    Full-size/prototypic U10Mo monolithic fuel-foils and aluminum clad fuel plates are being developed at the Idaho National Laboratory’s (INL) Materials and Fuels Complex (MFC). These efforts are focused on realizing Low Enriched Uranium (LEU) high density monolithic fuel plates for use in High Performance Research and Test Reactors. The U10Mo fuel foils under development afford a fuel meat density of ~16 gU/cc and thus have the potential to facilitate LEU conversions without any significant reactor-performance penalty. An overview is provided of the ongoing monolithic UMo fuel development effort, including application of a zirconium barrier layer on fuel foils, fabrication scale-up efforts, and development of complex/graded fuel foils. Fuel plate clad bonding processes to be discussed include: Hot Isostatic Pressing (HIP) and Friction Bonding (FB).

  14. A US perspective on fast reactor fuel fabrication technology and experience. Part II: Ceramic fuels

    NASA Astrophysics Data System (ADS)

    Burkes, Douglas E.; Fielding, Randall S.; Porter, Douglas L.; Meyer, Mitchell K.; Makenas, Bruce J.

    2009-08-01

    This paper is Part II of a review focusing on the United States experience with oxide, carbide, and nitride fast reactor fuel fabrication. Over 60 years of research in fuel fabrication by government, national laboratories, industry, and academia has culminated in a foundation of research and resulted in significant improvements to the technologies employed to fabricate these fuel types. This part of the review documents the current state of fuel fabrication technologies in the United States for each of these fuel types, some of the challenges faced by previous researchers, and how these were overcome. Knowledge gained from reviewing previous investigations will aid both researchers and policy makers in forming future decisions relating to nuclear fuel fabrication technologies.

  15. SEM and TEM Characterization of As-Fabricated U-7Mo Disperson Fuel Plates

    SciTech Connect

    D. D. Keiser, Jr.; B. Yao; E. Perez; Y. H. Sohn

    2009-11-01

    The starting microstructure of a dispersion fuel plate can have a dramatic impact on the overall performance of the plate during irradiation. To improve the understanding of the as-fabricated microstructures of dispersion fuel plates, SEM and TEM analysis have been performed on RERTR-9A archive fuel plates, which went through an additional hot isostatic procsssing (HIP) step during fabrication. The fuel plates had depleted U-7Mo fuel particles dispersed in either Al-2Si or 4043 Al alloy matrix. For the characterized samples, it was observed that a large fraction of the ?-phase U-7Mo alloy particles had decomposed during fabrication, and in areas near the fuel/matrix interface where the transformation products were present significant fuel/matrix interaction had occurred. Relatively thin Si-rich interaction layers were also observed around the U-7Mo particles. In the thick interaction layers, (U)(Al,Si)3 and U6Mo4Al43 were identified, and in the thin interaction layers U(Al,Si)3, U3Si3Al2, U3Si5, and USi1.88-type phases were observed. The U3Si3Al2 phase contained some Mo. Based on the results of this work, exposure of dispersion fuel plates to relatively high temperatures during fabrication impacts the overall microstructure, particularly the nature of the interaction layers around the fuel particles. The time and temperature of fabrication should be carefully controlled in order to produce the most uniform Si-rich layers around the U-7Mo particles.

  16. Fabrication and Characterization of Fully Ceramic Microencapsulated Fuels

    SciTech Connect

    Terrani, Kurt A; Kiggans, Jim; Katoh, Yutai; Shimoda, Kazuya; Montgomery, Fred C; Armstrong, Beth L; Parish, Chad M; Hinoki, Tatsuya; Hunn, John D; Snead, Lance Lewis

    2012-01-01

    The current generation of fully ceramic microencapsulated fuels, consisting of Tristructural Isotropic fuel particles embedded in a silicon carbide matrix, is fabricated by hot pressing. Matrix powder feedstock is comprised of alumina - yttria additives thoroughly mixed with silicon carbide nanopowder using polyethyleneimine as a dispersing agent. Fuel compacts are fabricated by hot pressing the powder - fuel particle mixture at a temperature of 1800-1900 C using compaction pressures of 10-20 MPa. Detailed microstructural characterization of the final fuel compacts shows that oxide additives are limited in extent and are distributed uniformly at silicon carbide grain boundaries, at triple joints between silicon carbide grains, and at the fuel particle-matrix interface.

  17. Fabrication and characterization of fully ceramic microencapsulated fuels

    NASA Astrophysics Data System (ADS)

    Terrani, K. A.; Kiggans, J. O.; Katoh, Y.; Shimoda, K.; Montgomery, F. C.; Armstrong, B. L.; Parish, C. M.; Hinoki, T.; Hunn, J. D.; Snead, L. L.

    2012-07-01

    The current generation of fully ceramic microencapsulated fuels, consisting of Tristructural Isotropic fuel particles embedded in a silicon carbide matrix, is fabricated by hot pressing. Matrix powder feedstock is comprised of alumina-yttria additives thoroughly mixed with silicon carbide nanopowder using polyethyleneimine as a dispersing agent. Fuel compacts are fabricated by hot pressing the powder-fuel particle mixture at a temperature of 1800-1900 °C using compaction pressures of 10-20 MPa. Detailed microstructural characterization of the final fuel compacts shows that oxide additives are limited in extent and are distributed uniformly at silicon carbide grain boundaries, at triple joints between silicon carbide grains, and at the fuel particle-matrix interface.

  18. Fabrication and Characterization of Surrogate Fuel Particles Using the Spark Erosion Method

    NASA Astrophysics Data System (ADS)

    Metzger, Kathryn E.

    In light of the disaster at the Fukushima Daiichi Nuclear Plant, the Department of Energy's Advanced Fuels Program has shifted its interest from enhanced performance fuels to enhanced accident tolerance fuels. Dispersion fuels possess higher thermal conductivities than traditional light water reactor fuel and as a result, offer improved safety margins. The benefits of a dispersion fuel are due to the presence of the secondary non-fissile phase (matrix), which serves as a barrier to fission products and improves the overall thermal performance of the fuel. However, the presence of a matrix material reduces the fuel volume, which lowers the fissile content of dispersion. This issue can be remedied through the development of higher density fuel phases or through an optimization of fuel particle size and volume loading. The latter requirement necessitates the development of fabrication methods to produce small, micron-order fuel particles. This research examines the capabilities of the spark erosion process to fabricate particles on the order of 10 μm. A custom-built spark erosion device by CT Electromechanica was used to produce stainless steel surrogate fuel particles in a deionized water dielectric. Three arc intensities were evaluated to determine the effect on particle size. Particles were filtered from the dielectric using a polycarbonate membrane filter and vacuum filtration system. Fabricated particles were characterized via field emission scanning electron microscopy (FESEM), laser light particle size analysis, energy-dispersive spectroscopy (EDS), X-ray diffraction analysis (XRD), and gas pycnometry. FESEM images reveal that the spark erosion process produces highly spherical particles on the order of 10 microns. These findings are substantiated by the results of particle size analysis. Additionally, EDS and XRD results indicate the presence of oxide phases, which suggests the dielectric reacted with the molten debris during particle formation.

  19. Coated U(Mo) Fuel: As-Fabricated Microstructures

    SciTech Connect

    Emmanuel Perez; Dennis D. Keiser, Jr.; Ann Leenaers; Sven Van den Berghe; Tom Wiencek

    2014-04-01

    As part of the development of low-enriched uranium fuels, fuel plates have recently been tested in the BR-2 reactor as part of the SELENIUM experiment. These fuel plates contained fuel particles with either Si or ZrN thin film coating (up to 1 µm thickness) around the U-7Mo fuel particles. In order to best understand irradiation performance, it is important to determine the starting microstructure that can be observed in as-fabricated fuel plates. To this end, detailed microstructural characterization was performed on ZrN and Si-coated U-7Mo powder in samples taken from AA6061-clad fuel plates fabricated at 500°C. Of interest was the condition of the thin film coatings after fabrication at a relatively high temperature. Both scanning electron microscopy and transmission electron microscopy were employed. The ZrN thin film coating was observed to consist of columns comprised of very fine ZrN grains. Relatively large amounts of porosity could be found in some areas of the thin film, along with an enrichment of oxygen around each of the the ZrN columns. In the case of the pure Si thin film coating sample, a (U,Mo,Al,Si) interaction layer was observed around the U-7Mo particles. Apparently, the Si reacted with the U-7Mo and Al matrix during fuel plate fabrication at 500°C to form this layer. The microstructure of the formed layer is very similar to those that form in U-7Mo versus Al-Si alloy diffusion couples annealed at higher temperatures and as-fabricated U-7Mo dispersion fuel plates with Al-Si alloy matrix fabricated at 500°C.

  20. Fabrication of Monolithic RERTR Fuels by Hot Isostatic Pressing

    SciTech Connect

    Jan-Fong Jue; Blair H. Park; Curtis R. Clark; Glenn A. Moore; Dennis D. Keiser, Jr.

    2010-11-01

    The RERTR (Reduced Enrichment for Research and Test Reactors) Program is developing advanced nuclear fuels for high-power test reactors. Monolithic fuel design provides higher uranium loading than that of the traditional dispersion fuel design. Hot isostatic pressing is a promising process for low-cost batch fabrication of monolithic RERTR fuel plates for these high-power reactors. Bonding U Mo fuel foil and 6061 Al cladding by hot isostatic press bonding was successfully developed at Idaho National Laboratory. Due to the relatively high processing temperature, the interaction between fuel meat and aluminum cladding is a concern. Two different methods were employed to mitigate this effect: (1) a diffusion barrier and (2) a doping addition to the interface. Both types of fuel plates have been fabricated by hot isostatic press bonding. Preliminary results show that the direct fuel/cladding interaction during the bonding process was eliminated by introducing a thin zirconium diffusion barrier layer between the fuel and the cladding. Fuel plates were also produced and characterized with a silicon-rich interlayer between fuel and cladding. This paper reports the recent progress of this developmental effort and identifies the areas that need further attention.

  1. Fabrication and Preliminary Evaluation of Metal Matrix Microencapsulated Fuels

    SciTech Connect

    Terrani, Kurt A; Kiggans, Jim; Snead, Lance Lewis

    2012-01-01

    The metal matrix microencapsulated (M3) fuel concept for light water reactors (LWRs), consisting of coated fuel particles dispersed in a zirconium metal matrix, is introduced. Fabrication of M3 fuels by hot pressing, hot isostatic pressing, or extrusion methodologies has been demonstrated over the temperature range 800-1050 C. Various types of coated fuel particles with outermost layers of pyrocarbon, SiC, ZrC, and TiN have been incorporated into the zirconium metal matrix. Mechanical particle-particle and chemical particle-matrix interactions have been observed during the preliminary characterization of as-fabricated M3 specimens. Irradiation of three M3 rodlets with surrogate coated fuel particles was carried out at mean rod temperature of 400 C to 4.6 dpa in the zirconium metal matrix. Due to absence of texture in the metal matrix no irradiation growth strain (<0.09%) was detected during the post-irradiation examination.

  2. Redundancy of Supply in the International Nuclear Fuel Fabrication Market: Are Fabrication Services Assured?

    SciTech Connect

    Seward, Amy M.; Toomey, Christopher; Ford, Benjamin E.; Wood, Thomas W.; Perkins, Casey J.

    2011-11-14

    For several years, Pacific Northwest National Laboratory (PNNL) has been assessing the reliability of nuclear fuel supply in support of the U.S. Department of Energy/National Nuclear Security Administration. Three international low enriched uranium reserves, which are intended back up the existing and well-functioning nuclear fuel market, are currently moving toward implementation. These backup reserves are intended to provide countries credible assurance that of the uninterrupted supply of nuclear fuel to operate their nuclear power reactors in the event that their primary fuel supply is disrupted, whether for political or other reasons. The efficacy of these backup reserves, however, may be constrained without redundant fabrication services. This report presents the findings of a recent PNNL study that simulated outages of varying durations at specific nuclear fuel fabrication plants. The modeling specifically enabled prediction and visualization of the reactors affected and the degree of fuel delivery delay. The results thus provide insight on the extent of vulnerability to nuclear fuel supply disruption at the level of individual fabrication plants, reactors, and countries. The simulation studies demonstrate that, when a reasonable set of qualification criteria are applied, existing fabrication plants are technically qualified to provide backup fabrication services to the majority of the world's power reactors. The report concludes with an assessment of the redundancy of fuel supply in the nuclear fuel market, and a description of potential extra-market mechanisms to enhance the security of fuel supply in cases where it may be warranted. This report is an assessment of the ability of the existing market to respond to supply disruptions that occur for technical reasons. A forthcoming report will address political disruption scenarios.

  3. Dispersion type zirconium matrix fuels fabricated by capillary impregnation method

    NASA Astrophysics Data System (ADS)

    Savchenko, A.; Konovalov, I.; Vatulin, A.; Morozov, A.; Orlov, V.; Uferov, O.; Ershov, S.; Laushkin, A.; Kulakov, G.; Maranchak, S.; Petrova, Z.

    2007-05-01

    Several novel dispersion fuel compositions with a high uranium content fuel (U9Mo, U5Zr5Nb, U3Si) and a zirconium alloy matrix with low melting point (1063-1133 K) have been developed at A.A. Bochvar Institute using a capillary impregnation fabrication method. The capillary impregnation method introduces fuel granules and granules of a zirconium alloy into a fuel element followed by a short-term anneal at a temperature above the melting temperature of alloy. The alloy melts down and under capillary forces moves into the joints between the fuel element components to form metallurgical bonds. The volume ratios between the components are: 55-65% fuel, 10-20% matrix, and 15-30% pores. Fuel elements produced by capillary impregnation method have a high uranium content (9-10 g cm-3) and a high thermal conductivity (18-22 W m-1 K-1), which, when used as PWR or BWR fuels allow the fuel temperature to be lowered to 723-773 K. They also feature porosity to accommodate swelling. The metallurgical fuel-cladding bond makes the fuel elements serviceable in power transients. The primary advantages for PWR, BWR and CANDU use of these fuels elements, would be the high uranium content, low fuel temperature and serviceability under transient conditions. Consideration is given to their applicability in Floating Nuclear Power Plants (FNPP) as well as for the feasibility of burning civil and weapon grade plutonium.

  4. Alcohol Transportation Fuels Demonstration Program. Phase 1

    SciTech Connect

    Kinoshita, C.M.

    1990-12-31

    Hawaii has abundant natural energy resources, especially biomass, that could be used to produce alternative fuels for ground transportation and electricity. This report summarizes activities performed during 1988 to June 1991 in the first phase of the Alcohol Transportation Fuels Demonstration Program. The Alcohol Transportation Fuels Demonstration Program was funded initially by the Energy Division of the State of Hawaii`s Department of Business, Economic Development and Tourism, and then by the US Department of Energy. This program was intended to support the transition to an altemative transportation fuel, methanol, by demonstrating the use of methanol fuel and methanol-fueled vehicles, and solving the problems associated with that fuel. Specific objectives include surveying renewable energy resources and ground transportation in Hawaii; installing a model methanol fueling station; demonstrating a methanol-fueled fleet of (spark-ignition engine) vehicles; evaluating modification strategies for methanol-fueled diesel engines and fuel additives; and investigating the transition to methanol fueling. All major objectives of Phase I were met (survey of local renewable resources and ground transportation, installation of methanol refueling station, fleet demonstration, diesel engine modification and additive evaluation, and dissemination of information on alternative fueling), and some specific problems (e.g., relating to methanol fuel contamination during handling and refueling) were identified and solved. Several key issues emerging from Phase I (e.g., methanol corrosion, flame luminosity, and methanol-transition technoeconomics) were recommended as topics for follow-on research in subsequent phases of this program.

  5. Greenfield Alternative Study LEU-Mo Fuel Fabrication Facility

    SciTech Connect

    Washington Division of URS

    2008-07-01

    This report provides the initial “first look” of the design of the Greenfield Alternative of the Fuel Fabrication Capability (FFC); a facility to be built at a Greenfield DOE National Laboratory site. The FFC is designed to fabricate LEU-Mo monolithic fuel for the 5 US High Performance Research Reactors (HPRRs). This report provides a pre-conceptual design of the site, facility, process and equipment systems of the FFC; along with a preliminary hazards evaluation, risk assessment as well as the ROM cost and schedule estimate.

  6. FABRICATION OF TUBE TYPE FUEL ELEMENT FOR NUCLEAR REACTORS

    DOEpatents

    Loeb, E.; Nicklas, J.H.

    1959-02-01

    A method of fabricating a nuclear reactor fuel element is given. It consists essentially of fixing two tubes in concentric relationship with respect to one another to provide an annulus therebetween, filling the annulus with a fissionablematerial-containing powder, compacting the powder material within the annulus and closing the ends thereof. The powder material is further compacted by swaging the inner surface of the inner tube to increase its diameter while maintaining the original size of the outer tube. This process results in reduced fabrication costs of powdered fissionable material type fuel elements and a substantial reduction in the peak core temperatures while materially enhancing the heat removal characteristics.

  7. Uranium nitride fuel fabrication for SP-100 reactors

    NASA Technical Reports Server (NTRS)

    Mason, Richard E.; Chidester, Kenneth M.; Hoth, Carl W.; Matthews, Bruce R.

    1987-01-01

    Fuel pins of uranium mononitride clad in Nb-1 percent Zr were fabricated for irradiation tests in EBR-II. Laboratory scale process parameters to synthesize UN powders and fabricate UN pellets were developed. Uranium mononitride was prepared by converting UO2 to UN. Fuel pellets were prepared by communition of UN briquettes, uniaxial pressing, and high temperature sintering. Techniques for machining, cleaning, and welding Nb-1 percent Zr cladding components were developed. End caps were electron beam welded to the tubing. Helium back-fill holes were sealed with a laser weld.

  8. Impact of fuel fabrication and fuel management technologies on uranium utilization

    SciTech Connect

    Arnsberger, P.L.; Stucker, D.L.

    1994-12-31

    Uranium utilization in commercial pressurized water reactors is a complex function of original NSSS design, utility energy requirements, fuel assembly design, fuel fabrication materials and fuel management optimization. Fuel design and fabrication technologies have reacted to the resulting market forcing functions with a combination of design and material changes. The technologies employed have included ever-increasing fuel discharge burnup, non-parasitic structural materials, burnable absorbers, and fissile material core zoning schemes (both in the axial and radial direction). The result of these technological advances has improved uranium utilization by roughly sixty percent from the infancy days of nuclear power to present fuel management. Fuel management optimization technologies have also been developed in recent years which provide fuel utilization improvements due to core loading pattern optimization. This paper describes the development and impact of technology advances upon uranium utilization in modem pressurized water reactors.

  9. Fabrication of Uranium Oxycarbide Kernels for HTR Fuel

    SciTech Connect

    Charles Barnes; CLay Richardson; Scott Nagley; John Hunn; Eric Shaber

    2010-10-01

    Babcock and Wilcox (B&W) has been producing high quality uranium oxycarbide (UCO) kernels for Advanced Gas Reactor (AGR) fuel tests at the Idaho National Laboratory. In 2005, 350-µm, 19.7% 235U-enriched UCO kernels were produced for the AGR-1 test fuel. Following coating of these kernels and forming the coated-particles into compacts, this fuel was irradiated in the Advanced Test Reactor (ATR) from December 2006 until November 2009. B&W produced 425-µm, 14% enriched UCO kernels in 2008, and these kernels were used to produce fuel for the AGR-2 experiment that was inserted in ATR in 2010. B&W also produced 500-µm, 9.6% enriched UO2 kernels for the AGR-2 experiments. Kernels of the same size and enrichment as AGR-1 were also produced for the AGR-3/4 experiment. In addition to fabricating enriched UCO and UO2 kernels, B&W has produced more than 100 kg of natural uranium UCO kernels which are being used in coating development tests. Successive lots of kernels have demonstrated consistent high quality and also allowed for fabrication process improvements. Improvements in kernel forming were made subsequent to AGR-1 kernel production. Following fabrication of AGR-2 kernels, incremental increases in sintering furnace charge size have been demonstrated. Recently small scale sintering tests using a small development furnace equipped with a residual gas analyzer (RGA) has increased understanding of how kernel sintering parameters affect sintered kernel properties. The steps taken to increase throughput and process knowledge have reduced kernel production costs. Studies have been performed of additional modifications toward the goal of increasing capacity of the current fabrication line to use for production of first core fuel for the Next Generation Nuclear Plant (NGNP) and providing a basis for the design of a full scale fuel fabrication facility.

  10. Summary report on fuel development and miniplate fabrication for the RERTR Program, 1978 to 1990

    SciTech Connect

    Wiencek, T.C.

    1995-08-01

    This report summarizes the efforts of the Fabrication Technology Section at Argonne National Laboratory in the program of Reduced Enrichment Research and Test Reactors (RERTR). The main objective of this program was to reduce the amount of high enriched ({approx}93% {sup 235}U) uranium (HEU) used in nonpower reactors. Conversion from low-density (0.8--1.6 g U/cm{sup 3}) HEU fuel elements to highly loaded (up to 7 g U/cm{sup 3}) low-enrichment (<20% {sup 235}U) uranium (LEU) fuel elements allows the same reactor power levels, core designs and sizes to be retained while greatly reducing the possibility of illicit diversion of HEU nuclear fuel. This document is intended as an overview of the period 1978--1990, during which the Section supported this project by fabricating mainly powder metallurgy uranium-silicide dispersion fuel plates. Most of the subjects covered in detail are fabrication-related studies of uranium silicide fuels and fuel plate properties. Some data are included for out-of-pile experiments such as corrosion and compatibility tests. Also briefly covered are most other aspects of the RERTR program such as irradiation tests, full-core demonstrations, and technology transfer. References included are for further information on most aspects of the entire program. A significant portion of the report is devoted to data that were never published in their entirety. The appendices contain a list of previous RERTR reports, ANL fabrication procedures, calculations for phases present in two-phase fuels, chemical analysis of fuels, miniplate characteristics, and a summary of bonding runs made by hot isostatic pressing.

  11. Process development and fabrication for sphere-pac fuel rods. [PWR; BWR

    SciTech Connect

    Welty, R.K.; Campbell, M.H.

    1981-06-01

    Uranium fuel rods containing sphere-pac fuel have been fabricated for in-reactor tests and demonstrations. A process for the development, qualification, and fabrication of acceptable sphere-pac fuel rods is described. Special equipment to control fuel contamination with moisture or air and the equipment layout needed for rod fabrication is described and tests for assuring the uniformity of the fuel column are discussed. Fuel retainers required for sphere-pac fuel column stability and instrumentation to measure fuel column smear density are described. Results of sphere-pac fuel rod fabrication campaigns are reviewed and recommended improvements for high throughput production are noted.

  12. Fuel Fabrication for Surrogate Sphere-Pac Rodlet

    SciTech Connect

    Del Cul, G.D.

    2005-07-19

    Sphere-pac fuel consists of a blend of spheres of two or three different size fractions contained in a fuel rod. The smear density of the sphere-pac fuel column can be adjusted to the values obtained for light-water reactor (LWR) pellets (91-95%) by using three size fractions, and to values typical of the fast-reactor oxide fuel column ({approx}85%) by using two size fractions. For optimum binary packing, the diameters of the two sphere fractions must differ by at least a factor of 7 (ref. 3). Blending of spheres with smaller-diameter ratios results in difficult blending, nonuniform loading, and lower packing fractions. A mixture of about 70 vol% coarse spheres and 30 vol% fine spheres is needed to obtain high packing fractions. The limiting smear density for binary packing is 86%, with about 82% achieved in practice. Ternary packing provides greater smear densities, with theoretical values ranging from 93 to 95%. Sphere-pac technology was developed in the 1960-1990 period for thermal and fast spectrum reactors of nearly all types (U-Th and U-Pu fuel cycles, oxide and carbide fuels), but development of this technology was most strongly motivated by the need for remote fabrication in the thorium fuel cycle. The application to LWR fuels as part of the DOE Fuel Performance Improvement Program did not result in commercial deployment for a number of reasons, but the relatively low production cost of existing UO{sub 2} pellet fuel is probably the most important factor. In the case of transmutation fuels, however, sphere-pac technology has the potential to be a lower-cost alternative while also offering great flexibility in tailoring the fuel elements to match the exact requirements of any particular reactor core at any given time in the cycle. In fact, the blend of spheres can be adjusted to offer a different composition for each fuel pin or group of pins in a given fuel element. Moreover, it can even provide a vertical gradient of composition in a single fuel pin. For

  13. Remote fabrication and irradiation test of recycled nuclear fuel prepared by the oxidation and reduction of spent oxide fuel

    NASA Astrophysics Data System (ADS)

    Jin Ryu, Ho; Chan Song, Kee; Il Park, Geun; Won Lee, Jung; Seung Yang, Myung

    2005-02-01

    A direct dry recycling process was developed in order to reuse spent pressurized light water reactor (LWR) nuclear fuel in CANDU reactors without the separation of sensitive nuclear materials such as plutonium. The benefits of the dry recycling process are the saving of uranium resources and the reduction of spent fuel accumulation as well as a higher proliferation resistance. In the process of direct dry recycling, fuel pellets separated from spent LWR fuel rods are oxidized from UO2 to U3O8 at 500 °C in an air atmosphere and reduced into UO2 at 700 °C in a hydrogen atmosphere, which is called OREOX (oxidation and reduction of oxide fuel). The pellets are pulverized during the oxidation and reduction processes due to the phase transformation between cubic UO2 and orthorhombic U3O8. Using the oxide powder prepared from the OREOX process, the compaction and sintering processes are performed in a remote manner in a shielded hot cell due to the high radioactivity of the spent fuel. Most of the fission gas and volatile fission products are removed during the OREOX and sintering processes. The mini-elements fabricated by the direct dry recycling process are irradiated in the HANARO research reactor for the performance evaluation of the recycled fuel pellets. Post-irradiation examination of the irradiated fuel showed that microstructural evolution and fission gas release behavior of the dry-recycled fuel were similar to high burnup UO2 fuel.

  14. Nuclear Cryogenic Propulsion Stage Fuel Design and Fabrication

    NASA Technical Reports Server (NTRS)

    Hickman, Robert; Broadway, Jeramie; Mireles, Omar; Webb, Jon; Qualls, Lou

    2012-01-01

    Nuclear Cryogenic Propulsion Stage (NCPS) is a game changing technology for space exploration. Goal of assessing the affordability and viability of an NCPS includes these overall tasks: (1) Pre-conceptual design of the NCPS and architecture integration (2) NCPS Fuel Design and Testing (3) Nuclear Thermal Rocket Element Environmental Simulator (NTREES) (4) Affordable NCPS Development and Qualification Strategy (5) Second Generation NCPS Concepts. There is a critical need for fuels development. Fuel task objectives are to demonstrate capabilities and critical technologies using full scale element fabrication and testing.

  15. Nuclear Cryogenic Propulsion Stage Fuel Design and Fabrication

    NASA Technical Reports Server (NTRS)

    Hickman, Robert; Broadway, Jeramie; Mireles, Omar; Webb, Jon; Qualls, Lou

    2012-01-01

    Nuclear Cryogenic Propulsion Stage (NCPS) is a game changing technology for space exploration. Goal of assessing the affordability and viability of an NCPS includes thses overall tasks: (1) Pre-conceptual design of the NCPS and architecture integration (2) NCPS Fuel Design and Testing (3) Nuclear Thermal Rocket Element Environmental Simulator (NTREES) (4) Affordable NCPS Development and Qualification Strategy (5) Second Generation NCPS Concepts. There is a critical need for fuels development. Fuel task objectives are to demonstrate capabilities and critical technologies using full scale element fabrication and testing.

  16. CHARACTERIZATION OF EMISSIONS FROM PLUTONIUM-URANIUM OXIDE FUEL FABRICATION

    EPA Science Inventory

    To develop accurate monitoring techniques for the radioactive emissions from new types of nuclear facilities, it is necessary to characterize those emissions as completely as possible. The first facility selected was a mixed-oxide fuel fabrication plant. In-stack, standard hi-vol...

  17. Design and fabrication of high density uranium dispersion fuels

    SciTech Connect

    Trybus, C.L.; Meyer, M.K.; Clark, C.R.; Wlencek, T.C.; McGann, D.J.

    1997-11-01

    Twelve different uranium alloys and compounds with uranium densities greater than 13.8 g/cc were fabricated into fuel plates. Sixty-four experimental fuel plates, referred to as microplates, with overall dimensions of 76.2 mm x 22.2 mm x 1.3 mm and elliptical fuel zone of nominal dimensions of 51 mm x 9.5 mm, began irradiation in the Advanced Test Reactor on August 23, 1997. The fuel test matrix consists of machined or comminuted (compositions are in weight %) U-10Mo, U-8Mo, U-6Mo, U-4Mo, U-9Nb-3Zr, U-6Nb-4Zr, U-5Nb-3Zr, U-6Mo-1Pt, U6Mo-0.6 Ru, U-10Mo-0.05Sn, U{sub 2}Mo and U{sub 3}Si{sub 2} (as a control). The low enriched ({sup 235}U < 20%) fuel materials were cast, powdered, mixed with aluminum dispersant at a volume ratio of 1:3, compacted and hot rolled to form the microplates. Spherical atomized powders of two fuels, U-10Mo and U{sub 3}Si{sub 2}, were utilized to make microplates and included in the irradiation test as well. The experimental design and fabrication steps employed in the selection and production of the fueled microplates is discussed.

  18. Composite nuclear fuel fabrication methodology for gas fast reactors

    NASA Astrophysics Data System (ADS)

    Vasudevamurthy, Gokul

    An advanced fuel form for use in Gas Fast Reactors (GFR) was investigated. Criteria for the fuel includes operation at high temperature (˜1400°C) and high burnup (˜150 MWD/MTHM) with effective retention of fission products even during transient temperatures exceeding 1600°C. The GFR fuel is expected to contain up to 20% transuranics for a closed fuel cycle. Earlier evaluations of reference fuels for the GFR have included ceramic-ceramic (cercer) dispersion type composite fuels of mixed carbide or nitride microspheres coated with SiC in a SiC matrix. Studies have indicated that ZrC is a potential replacement for SiC on account of its higher melting point, increased fission product corrosion resistance and better chemical stability. The present work investigated natural uranium carbide microspheres in a ZrC matrix instead of SiC. Known issues of minor actinide volatility during traditional fabrication procedures necessitated the investigation of still high temperature but more rapid fabrication techniques to minimize these anticipated losses. In this regard, fabrication of ZrC matrix by combustion synthesis from zirconium and graphite powders was studied. Criteria were established to obtain sufficient matrix density with UC microsphere volume fractions up to 30%. Tests involving production of microspheres by spark erosion method (similar to electrodischarge machining) showed the inability of the method to produce UC microspheres in the desired range of 300 to 1200 mum. A rotating electrode device was developed using a minimum current of 80A and rotating at speeds up to 1500 rpm to fabricate microspheres between 355 and 1200 mum. Using the ZrC process knowledge, UC electrodes were fabricated and studied for use in the rotating electrode device to produce UC microspheres. Fabrication of the cercer composite form was studied using microsphere volume fractions of 10%, 20%, and 30%. The macrostructure of the composite and individual components at various stages were

  19. Fabrication and electrochemical behavior of nitride fuel for future applications

    NASA Astrophysics Data System (ADS)

    Arai, Yasuo; Minato, Kazuo

    2005-09-01

    Mononitride is the first candidate of fuel material in the accelerator driven system (ADS) for minor actinide (MA) transmutation designed by JAERI, being coupled with pyrochemical process for treatment of spent fuel. This paper summarizes recent R&D on the fabrication and electrochemical behavior of nitride fuel carried out in JAERI. Mononitride of U, Np, Pu, Am, Cm and their solid solutions have been prepared by carbothermic reduction from their dioxides. Mononitride containing diluent material such as ZrN also has been prepared and characterized. Electrode behavior of nitride fuel in the LiCl-KCl eutectic melt has been investigated by electrochemical measurements in order to apply pyrochemical process to nitride fuel cycle for MA transmutation.

  20. Fabrication of high exposure nuclear fuel pellets

    DOEpatents

    Frederickson, James R.

    1987-01-01

    A method is disclosed for making a fuel pellet for a nuclear reactor. A mixture is prepared of PuO.sub.2 and UO.sub.2 powders, where the mixture contains at least about 30% PuO.sub.2, and where at least about 12% of the Pu is the Pu.sup.240 isotope. To this mixture is added about 0.3 to about 5% of a binder having a melting point of at least about 250.degree. F. The mixture is pressed to form a slug and the slug is granulated. Up to about 4.7% of a lubricant having a melting point of at least about 330.degree. F. is added to the granulated slug. Both the binder and the lubricant are selected from a group consisting of polyvinyl carboxylate, polyvinyl alcohol, naturally occurring high molecular weight cellulosic polymers, chemically modified high molecular weight cellulosic polymers, and mixtures thereof. The mixture is pressed to form a pellet and the pellet is sintered.

  1. Fabrication and characterization of micro-orifices for diesel fuel injectors.

    SciTech Connect

    Fenske, G.; Woodford, J.; Wang, J.; El-Hannouny, E.; Schaefer, R.; Hamady, F.; National Vehicle and Fuel Emissions Lab.

    2007-04-01

    Stringent emission standards are driving the development of diesel-fuel injection concepts to mitigate in-cylinder formation of particulates. While research has demonstrated significant reduction in particulate formation using micro-orifice technology, implementation requires development of industrial processes to fabricate micro-orifices with diameters as low as 50 gmm and with large length-to-diameter ratios. This paper reviews the different processes being pursued to fabricate micro-orifices and the advanced techniques applied to characterize the performance of micro-orifices. The latter include the use of phase-contrast x-ray imaging of electroless nickel-plated, micro-orifices and laser imaging of fuel sprays at elevated pressures. The experimental results demonstrate an industrially viable process to create small uniform orifices that improve spray formation for fuel injection.

  2. Development of advanced fuel cell system, phase 2

    NASA Technical Reports Server (NTRS)

    Handley, L. M.; Meyer, A. P.; Bell, W. F.

    1973-01-01

    A multiple task research and development program was performed to improve the weight, life, and performance characteristics of hydrogen-oxygen alkaline fuel cells for advanced power systems. Development and characterization of a very stable gold alloy catalyst was continued from Phase I of the program. A polymer material for fabrication of cell structural components was identified and its long term compatibility with the fuel cell environment was demonstrated in cell tests. Full scale partial cell stacks, with advanced design closed cycle evaporative coolers, were tested. The characteristics demonstrated in these tests verified the feasibility of developing the engineering model system concept into an advanced lightweight long life powerplant.

  3. Microencapsulation and fabrication of fuel pellets for inertial confinement fusion.

    PubMed

    Nolen, R L; Kool, L B

    1981-04-01

    Various microencapsulation techniques were evaluated for fabrication of thermonuclear fuel pellets for use in existing experimental facilities studying inertial confinement fusion and in future fusion-power reactors. Coacervation, spray drying, in situ polymerization, and physical microencapsulation methods were employed. Highly spherical, hollow polymeric shells were fabricated ranging in size from 20 to 7000 micron. In situ polymerization microencapsulation with poly(methyl methacrylate) provided large shells, but problems with local wall defects still must be solved. Extension to other polymeric systems met with limited success. Requirements for inertial confinement fusion targets are described, as are the methods that were used. PMID:7229942

  4. Metallic Fast Reactor Fuel Fabrication for Global Nuclear Energy Partnership

    SciTech Connect

    Douglas E. Burkes; Randall S. Fielding; Douglas L. Porter

    2009-07-01

    Fast reactors are once again being considered for nuclear power generation, in addition to transmutation of long-lived fission products resident in spent nuclear fuels. This re-consideration follows with intense developmental programs for both fuel and reactor design. One of the two leading candidates for next generation fast reactor fuel is metal alloys, resulting primarily from the successes achieved in the 1960s to early 1990s with both the experimental breeding reactor-II and the fast flux test facility. The goal of the current program is to develop and qualify a nuclear fuel system that performs all of the functions of a conventional, fast-spectrum nuclear fuel while destroying recycled actinides, thereby closing the nuclear fuel cycle. In order to meet this goal, the program must develop efficient and safe fuel fabrication processes designed for remote operation. This paper provides an overview of advanced casting processes investigated in the past, and the development of a gaseous diffusion calculation that demonstrates how straightforward process parameter modification can mitigate the loss of volatile minor actinides in the metal alloy melt.

  5. Fabrication of small-orifice fuel injectors for diesel engines.

    SciTech Connect

    Woodford, J. B.; Fenske, G. R.

    2005-04-08

    Diesel fuel injector nozzles with spray hole diameters of 50-75 {micro}m have been fabricated via electroless nickel plating of conventionally made nozzles. Thick layers of nickel are deposited onto the orifice interior surfaces, reducing the diameter from {approx}200 {micro}m to the target diameter. The nickel plate is hard, smooth, and adherent, and covers the orifice interior surfaces uniformly.

  6. Nitration by a simulated fuel technique for nitride fuel re-fabrication

    NASA Astrophysics Data System (ADS)

    Lee, Young.-Woo; Ryu, Ho Jin; Lee, Jae Won; Lee, Jung Won; Park, Geun Il

    2009-07-01

    Nitration reaction of a spent nuclear oxide fuel through a carbothermic reduction and the change in thermal conductivity of the resultant nitride specimens were investigated by a simulated fuel technique for use in nitride fuel re-fabrication from spent oxide fuel. The simulated spent oxide fuel was formed by compacting and sintering a powder mixture of UO 2 and stable oxide fission product impurities. It was pulverized by a 3-cycle successive oxidation-reduction treatment and converted into nitride pellet specimens through the carbothermic reduction. The rate of the nitration reaction of the simulated spent oxide fuel was decreased due to the fission product impurities when compared with pure uranium dioxide. The amount of Ba and Sr in the simulated spent oxide fuel was considerably reduced after the nitride fuel re-fabrication. The thermal conductivity of the nitride pellet specimen in the range 295-373 K was lower than that of the pure uranium nitride but higher than the simulated spent oxide fuel containing fission product impurities.

  7. A color phase shift profilometry for the fabric defect detection

    NASA Astrophysics Data System (ADS)

    Song, Li-mei; Li, Zong-yan; Chang, Yu-lan; Xing, Guang-xin; Wang, Peng-qiang; Xi, Jiang-tao; Zhu, Teng-da

    2014-07-01

    For fabric defect identification in the textile industry, a three-dimensional (3D) color phase shift profilometry (CPSP) method is proposed. The detecting system is mainly composed of one CCD camera and one digital-light-processing (DLP) projector. Before detection, the system should be calibrated to make sure the camera parameters. The CPSP color grating is projected to the measured fabric by DLP projector, and then it is collected by CCD camera to obtain the grating phase. The 3D measurement can be completed by the grating phase difference. In image acquisition, only invariable grating is projected to the object. In order to eliminate the interference from background light during the image acquisition, the brightness correction method is researched for improving the detection accuracy. The experimental results show that the false rate of detecting the fabric defects is 5.78%, the correct rates of detecting the fabric defects of hole and qualified fabric are both 100%, and the correct rates of detecting the fabric defect of scratch and fold are 98% and 96%, respectively. The experiment proves that the proposed method can accurately identify fabric defects.

  8. FULL SIZE U-10MO MONOLITHIC FUEL FOIL AND FUEL PLATE FABRICATION-TECHNOLOGY DEVELOPMENT

    SciTech Connect

    G. A. Moore; J-F Jue; B. H. Rabin; M. J. Nilles

    2010-03-01

    Full-size U10Mo foils are being developed for use in high density LEU monolithic fuel plates. The application of a zirconium barrier layer too the foil is applied using a hot co-rolling process. Aluminum clad fuel plates are fabricated using Hot Isostatic Pressing (HIP) or a Friction Bonding (FB) process. An overview is provided of ongoing technology development activities, including: the co-rolling process, foil shearing/slitting and polishing, cladding bonding processes, plate forming, plate-assembly swaging, and fuel plate characterization. Characterization techniques being employed include, Ultrasonic Testing (UT), radiography, and microscopy.

  9. Fuel cell collector plate and method of fabrication

    DOEpatents

    Braun, James C.; Zabriskie, Jr., John E.; Neutzler, Jay K.; Fuchs, Michel; Gustafson, Robert C.

    2001-01-01

    An improved molding composition is provided for compression molding or injection molding a current collector plate for a polymer electrolyte membrane fuel cell. The molding composition is comprised of a polymer resin combined with a low surface area, highly-conductive carbon and/or graphite powder filler. The low viscosity of the thermoplastic resin combined with the reduced filler particle surface area provide a moldable composition which can be fabricated into a current collector plate having improved current collecting capacity vis-a-vis comparable fluoropolymer molding compositions.

  10. Binary phase digital reflection holograms - Fabrication and potential applications

    NASA Technical Reports Server (NTRS)

    Gallagher, N. C., Jr.; Angus, J. C.; Coffield, F. E.; Edwards, R. V.; Mann, J. A., Jr.

    1977-01-01

    A novel technique for the fabrication of binary-phase computer-generated reflection holograms is described. By use of integrated circuit technology, the holographic pattern is etched into a silicon wafer and then aluminum coated to make a reflection hologram. Because these holograms reflect virtually all the incident radiation, they may find application in machining with high-power lasers. A number of possible modifications of the hologram fabrication procedure are discussed.

  11. Epitaxial solar-cell fabrication, phase 2

    NASA Technical Reports Server (NTRS)

    Daiello, R. V.; Robinson, P. H.; Kressel, H.

    1977-01-01

    Dichlorosilane (SiH2Cl2) was used as the silicon source material in all of the epitaxial growths. Both n/p/p(+) and p/n/n(+) structures were studied. Correlations were made between the measured profiles and the solar cell parameters, especially cell open-circuit voltage. It was found that in order to obtain consistently high open-circuit voltage, the epitaxial techniques used to grow the surface layer must be altered to obtain very abrupt doping profiles in the vicinity of the junction. With these techniques, it was possible to grow reproducibly both p/n/n(+) and n/p/p(+) solar cell structures having open-circuit voltages in the 610- to 630-mV range, with fill-factors in excess of 0.80 and AM-1 efficiencies of about 13%. Combinations and comparisons of epitaxial and diffused surface layers were also made. Using such surface layers, we found that the blue response of epitaxial cells could be improved, resulting in AM-1 short-circuit current densities of about 30 mA/cm sq. The best cells fabricated in this manner had AM-1 efficiency of 14.1%.

  12. A U. S. Perspective on Fast Reactor Fuel Fabrication Technology and Experience Part I: Metal Fuels and Assembly Design

    SciTech Connect

    Douglas E. Burkes; Randall S. Fielding; Douglas L. Porter; Douglas C. Crawford; Mitchell K. Meyer

    2009-06-01

    This paper is Part I of a review focusing on the United States experience with metallic fast reactor fuel fabrication and assembly design for the Experimental Breeder Reactor-II and the Fast Flux Test Facility, and it also refers to the impact of development in other nations. Experience with metal fuel fabrication in the United States is extensive, including over 60 years of research conducted by the government, national laboratories, industry, and academia. This experience has culminated into a foundation of research and resulted in significant improvements to the technologies employed to fabricate metallic fast reactor fuel. This part of the review documents the current state of fuel fabrication technologies for metallic fuels, some of the challenges faced by previous researchers, and how these were overcome. Knowledge gained from reviewing previous investigations will aid both researchers and policy makers in forming future decisions relating to nuclear fuel fabrication technologies.

  13. A US perspective on fast reactor fuel fabrication technology and experience part I: metal fuels and assembly design

    NASA Astrophysics Data System (ADS)

    Burkes, Douglas E.; Fielding, Randall S.; Porter, Douglas L.; Crawford, Douglas C.; Meyer, Mitchell K.

    2009-06-01

    This paper is part I of a review focusing on the United States experience with metallic fast reactor fuel fabrication and assembly design for the Experimental Breeder Reactor-II (EBR-II) and the Fast Flux Test Facility (FFTF). Experience with metal fuel fabrication in the United States is extensive, including over 60 years of research conducted by the government, national laboratories, industry, and academia. This experience has culminated in a considerable amount of research that resulted in significant improvements to the technologies employed to fabricate metallic fast reactor fuel. This part of the review documents the current state of fuel fabrication technologies for metallic fuels, some of the challenges faced by previous researchers, and how these were overcome. Knowledge gained from reviewing previous investigations will aid both researchers and policy makers in forming future decisions relating to nuclear fuel fabrication technologies.

  14. Fabrication Characteristics of Large Grain DUPIC Fuel Using SIMFUEL

    SciTech Connect

    Park, Geun IL; Lee, Jung Won; Lee, Jae Won; Yang, Myung Seung; Song, Kee Chan

    2007-07-01

    Fabrication characteristics to improve the density and grain size of DUPIC fuel with relation to its fuel performance were experimentally evaluated using SIMFUEL as a surrogate for an actual spent PWR fuel due to the high radioactivity of a spent fuel. Hence, SIMFUELs with a burn-up of 35,000 MWd/tU and 60,000 MWd/tU were used to investigate the influence of fission products contents as an impurity on the fuel powder properties and on the density and grain size of a simulated DUPIC pellet. In order to improve the densification and grain growth of the simulated DUPIC fuel, the effect of the addition of sintering aids was investigated. The specific surface area of the OREOX powders was increased with an increase of the impurities by the dissolved oxides in UO{sub 2} among the impurity groups. The specific surface area of the powders milled after the OXREOX treatment was slightly higher than the UO{sub 2} powder used for a nuclear power plant, thus resulting in sintered pellets with a higher than 95% T.D. (theoretical density). The grain size of the sintered pellets was significantly decreased with increasing amount of the metallic and oxide precipitates. However, on adding the sintering aids such as TiO{sub 2} and Nb{sub 2}O{sub 5}, the grain size of the sintering aids-doped pellets was greatly improved by up to around 3 times that of the raw pellets and their sintered density was also increased by up to 2%. (authors)

  15. US-Russian collaboration in MPC & A enhancements at the Elektrostal Uranium Fuel-Fabrication Plant

    SciTech Connect

    Smith, H.; Murray, W.; Whiteson, R.

    1997-11-01

    Enhancement of the nuclear materials protection, control, and accounting of (MPC&A) at the Elektrostal Machine-Building Plant (ELEMASH) has proceeded in two phases. Initially, Elektrostal served as the model facility at which to test US/Russian collaboration and to demonstrate MPC&A technologies available for safeguards enhancements at Russian facilities. This phase addressed material control and accounting (MC&A) in the low-enriched uranium (LEU) fuel-fabrication processes and the physical protection (PP) of part of the (higher-enrichment) breeder-fuel process. The second phase, identified later in the broader US/Russian agreement for expanded MPC&A cooperation. includes implementation of appropriate MC&A and PP systems in the breeder-fuel fabrication processes. Within the past year, an automated physical protection system has been installed and demonstrated in building 274, and an automated MC&A system has been designed and is being installed and will be tested in the LEU process. Attention has now turned to assuring longterm sustainability for the first phase and beginning MPC&A upgrades for the second phase. Sustainability measures establish the infrastructure for operation, maintenance, and repair of the installed systems-with US support for the lifetime of the US/Russian Agreement, but evolving toward full Russian operation of the system over the long term. For phase 2, which will address higher enrichments, projects have been identified to characterize the facilities, design MPC&A systems, procure appropriate equipment, and install and test final systems. One goal in phase 2 will be to build on initial work to create shared, plant-wide MPC&A assets for operation, maintenance, and evaluation of all safeguards systems.

  16. Fabrication and Characterization of Dual Phase Magnesia-Zirconia Ceramics Doped with Plutonia

    SciTech Connect

    P. G. Medvedev; J. F. Jue; S. M. Frank; M.K. Meyer

    2005-05-01

    Dual phase magnesia-zirconia ceramics doped with plutonia are being studied as an inert matrix fuel (IMF) for light water reactors. The motivation of this work is to develop an IMF with a thermal conductivity superior to that of the fuels based on yttria stabilized zirconia. The concept uses the MgO phase as an efficient heat conductor to increase thermal conductivity of the composite. In this paper ceramic fabrication and characterization by scanning electron microscopy, energy and wavelength dispersive xray spectroscopy is discussed. Characterization shows that the ceramics consist of the two-phase matrix and PuO2-rich inclusions. The matrix is comprised of pure MgO phase and MgO-ZrO2-PuO2 solid solution. The PuO2-rich inclusion contained dissolved MgO and ZrO2.

  17. Fabrication and characterization of dual phase magnesia zirconia ceramics doped with plutonia

    NASA Astrophysics Data System (ADS)

    Medvedev, P. G.; Jue, J. F.; Frank, S. M.; Meyer, M. K.

    2006-06-01

    Dual phase magnesia-zirconia ceramics doped with plutonia are being studied as an inert matrix fuel (IMF) for light water reactors. The motivation of this work is to develop an IMF with a thermal conductivity superior to that of the fuels based on yttria stabilized zirconia. The concept uses the MgO phase as an efficient heat conductor to increase thermal conductivity of the composite. In this paper ceramic fabrication and characterization by scanning electron microscopy, energy and wavelength dispersive X-ray spectroscopy is discussed. Characterization shows that the ceramics consist of the two-phase matrix and PuO2-rich inclusions. The matrix is comprised of pure MgO phase and MgO-ZrO2-PuO2 solid solution. The PuO2-rich inclusion contained dissolved MgO and ZrO2.

  18. Multi-fuel reformers for fuel cells used in transportation. Phase 1: Multi-fuel reformers

    NASA Astrophysics Data System (ADS)

    1994-05-01

    DOE has established the goal, through the Fuel Cells in Transportation Program, of fostering the rapid development and commercialization of fuel cells as economic competitors for the internal combustion engine. Central to this goal is a safe feasible means of supplying hydrogen of the required purity to the vehicular fuel cell system. Two basic strategies are being considered: (1) on-board fuel processing whereby alternative fuels such as methanol, ethanol or natural gas stored on the vehicle undergo reformation and subsequent processing to produce hydrogen, and (2) on-board storage of pure hydrogen provided by stationary fuel processing plants. This report analyzes fuel processor technologies, types of fuel and fuel cell options for on-board reformation. As the Phase 1 of a multi-phased program to develop a prototype multi-fuel reformer system for a fuel cell powered vehicle, the objective of this program was to evaluate the feasibility of a multi-fuel reformer concept and to select a reforming technology for further development in the Phase 2 program, with the ultimate goal of integration with a DOE-designated fuel cell and vehicle configuration. The basic reformer processes examined in this study included catalytic steam reforming (SR), non-catalytic partial oxidation (POX) and catalytic partial oxidation (also known as Autothermal Reforming, or ATR). Fuels under consideration in this study included methanol, ethanol, and natural gas. A systematic evaluation of reforming technologies, fuels, and transportation fuel cell applications was conducted for the purpose of selecting a suitable multi-fuel processor for further development and demonstration in a transportation application.

  19. Electron Microscopy Characterization of an As-Fabricated Research Reactor Fuel Plate Comprised of U-7Mo Particles Dispersed in an Al-2Si Alloy Matrix

    SciTech Connect

    Dennis D. Keiser, Jr.; J. Gan; J. F. Jue; B. D. Miller

    2010-11-01

    To understand the microstructural development of nuclear fuel plates during irradiation, it is imperative to know the microstructure of a fuel plate after all the fabrication steps have been completed and before it is inserted into the reactor. To this end, a U–7 wt.% Mo alloy research reactor dispersion fuel plate with Al–2 wt.% Si matrix was destructively examined using scanning and transmission electron microscopy to characterize the developed microstructure after fabrication. Of particular interest for this study was how the Si that was added to the fuel matrix partitioned between the various fuel plate phases during fabrication. Si was added to the matrix so that the microstructure that developed during fuel fabrication would exhibit good irradiation behavior. SEM analysis was used to identify the representative microstructure, the compositions of the various phases, and the partitioning behavior of the fuel and matrix constituents. TEM analysis was employed to definitively identify the phases in the U–7Mo alloy and the phases that formed due to diffusional interactions between the fuel particles and matrix during fuel plate fabrication. The TEM results are the first reported for an as-fabricated U–7 wt.% Mo dispersion fuel plate with an Al alloy matrix. SEM results showed that a significant portion of the original ?-(U–Mo) fuel particles had transformed to a lamellar microstructure, comprised of a-U and either ? or ?' phases, and the fuel/matrix interaction layers were enriched in Si. TEM analysis identified an ordered fcc (U–Mo)(Al–Si)3 type of phase, which formed at the decomposed U–7Mo/matrix interface and extended into the lamellar microstructure. Some regions of the U–7Mo particles retained the single-phase ?-(U–Mo). Small precipitate phases were observed in the fuel meat matrix that contained Fe, Al, and Si. The Si that is added to the matrix of a U–Mo dispersion fuel plate to improve irradiation performance appears to result in

  20. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOEpatents

    Riley, B.; Szreders, B.E.

    1988-04-26

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (/approximately/1100/degree/ /minus/ 1300/degree/C) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20--50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  1. Environmental assessment for radioisotope heat source fuel processing and fabrication

    SciTech Connect

    Not Available

    1991-07-01

    DOE has prepared an Environmental Assessment (EA) for radioisotope heat source fuel processing and fabrication involving existing facilities at the Savannah River Site (SRS) near Aiken, South Carolina and the Los Alamos National Laboratory (LANL) near Los Alamos, New Mexico. The proposed action is needed to provide Radioisotope Thermoelectric Generators (RTG) to support the National Aeronautics and Space Administration's (NASA) CRAF and Cassini Missions. Based on the analysis in the EA, DOE has determined that the proposed action does not constitute a major Federal action significantly affecting the quality of the human environment within the meaning of the National Environmental Policy Act (NEPA) of 1969. Therefore, an Environmental Impact Statement is not required. 30 refs., 5 figs.

  2. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOEpatents

    Brian, Riley; Szreders, Bernard E.

    1989-01-01

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100.degree.-1300.degree. C.) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  3. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    NASA Astrophysics Data System (ADS)

    Riley, Brian; Szreders, Bernard E.

    1988-04-01

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approx. 1100 to 1300 C) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20 and 50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  4. The thermomechanical stability of micro-solid oxide fuel cells fabricated on anodized aluminum oxide membranes

    NASA Astrophysics Data System (ADS)

    Kwon, Chang-Woo; Lee, Jae-Il; Kim, Ki-Bum; Lee, Hae-Weon; Lee, Jong-Ho; Son, Ji-Won

    2012-07-01

    The thermomechanical stability of micro-solid oxide fuel cells (micro-SOFCs) fabricated on an anodized aluminum oxide (AAO) membrane template is investigated. The full structure consists of the following layers: AAO membrane (600 nm)/Pt anode/YSZ electrolyte (900 nm)/porous Pt cathode. The utilization of a 600-nm-thick AAO membrane significantly improves the thermomechanical stability due to its well-known honeycomb-shaped nanopore structure. Moreover, the Pt anode layer deposited in between the AAO membrane and the YSZ electrolyte preserves its integrity in terms of maintaining the triple-phase boundary (TPB) and electrical conductivity during high-temperature operation. Both of these results guarantee thermomechanical stability of the micro-SOFC and extend the cell lifetime, which is one of the most critical issues in the fabrication of freestanding membrane-type micro-SOFCs.

  5. Description of fuel element brush assembly`s fabrication for 105-K west

    SciTech Connect

    Maassen, D. P.

    1997-10-15

    This report is a description of the process to redesign and fabricate, as well as, describe the features of the Fuel Element Brush Assembly used in the 105-K West Basin. This narrative description will identify problems that occurred during the redesigning and fabrication of the 105-K West Basin Fuel Element Brush Assembly and specifically address their solutions.

  6. 76 FR 65544 - Standard Format and Content of License Applications for Mixed Oxide Fuel Fabrication Facilities

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-10-21

    ... issuance of the guide (74 FR 36780). The comment period closed on September 21, 2009. The staff's responses... COMMISSION Standard Format and Content of License Applications for Mixed Oxide Fuel Fabrication Facilities... Format and Content of License Applications for Mixed Oxide Fuel Fabrication Facilities.'' This...

  7. Development of DIPRES feed for the fabrication of mixed-oxide fuels for fast breeder reactors

    SciTech Connect

    Griffin, C W; Rasmussen, D E; Lloyd, M H

    1983-01-01

    The DIrect PREss Spheroidized feed process combines the conversion of uranium-plutonium solutions into spheres by internal gelation with conventional pellet fabrication techniques. In this manner, gel spheres could replace conventional powders as the feed material for pellet fabrication of nuclear fuels. Objective of the DIPRES feed program is to develop and qualify a process to produce mixed-oxide fuel pellets from gel spheres for fast breeder reactors. This process development includes both conversion and fabrication activities.

  8. Photoelectrochemical fabrication of spectroscopic diffraction gratings, phase 2

    NASA Technical Reports Server (NTRS)

    Rauh, R. David; Carrabba, Michael M.; Li, Jianguo; Cartland, Robert F.; Hachey, John P.; Mathew, Sam

    1990-01-01

    This program was directed toward the production of Echelle diffraction gratings by a light-driven, electrochemical etching technique (photoelectrochemical etching). Etching is carried out in single crystal materials, and the differential rate of etching of the different crystallographic planes used to define the groove profiles. Etching of V-groove profiles was first discovered by us during the first phase of this project, which was initially conceived as a general exploration of photoelectrochemical etching techniques for grating fabrication. This highly controllable V-groove etching process was considered to be of high significance for producing low pitch Echelles, and provided the basis for a more extensive Phase 2 investigation.

  9. 10 CFR 140.13a - Amount of financial protection required for plutonium processing and fuel fabrication plants.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... plutonium processing and fuel fabrication plant is required to have and maintain financial protection in the... use plutonium at two or more plutonium processing and fuel fabrication plants at the same location... protection covers all such plants at the location....

  10. 10 CFR 140.13a - Amount of financial protection required for plutonium processing and fuel fabrication plants.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... plutonium processing and fuel fabrication plant is required to have and maintain financial protection in the... use plutonium at two or more plutonium processing and fuel fabrication plants at the same location... protection covers all such plants at the location....

  11. 10 CFR 140.13a - Amount of financial protection required for plutonium processing and fuel fabrication plants.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... plutonium processing and fuel fabrication plant is required to have and maintain financial protection in the... use plutonium at two or more plutonium processing and fuel fabrication plants at the same location... protection covers all such plants at the location....

  12. Fabrication procedures for manufacturing High Flux Isotope Reactor fuel elements - 2

    SciTech Connect

    Knight, R.W.; Morin, R.A.

    1999-12-01

    The original fabrication procedures written in 1968 delineated the manufacturing procedures at that time. Since 1968, there have been a number of procedural changes. This rewrite of the fabrication procedures incorporates these changes. The entire fuel core of this reactor is made up of two fuel elements. Each element consists of one annular array of fuel plates. These annuli are identified as the inner and outer fuel elements, since one fits inside the other. The inner element consists of 171 identical fuel plates, and the outer element contains 369 identical fuel plates differing slightly from those in the inner element. Both sets of fuel plates contain U{sub 3}O{sub 8} powder as the fuel, dispersed in an aluminum powder matrix and clad with aluminum. Procedures for manufacturing and inspection of the fuel elements are described and illustrated.

  13. Development of Core Cladding Fabrication Techniques for Phase I Fission Propulsion Systems

    NASA Technical Reports Server (NTRS)

    Salvail, Patrick G.; Reid, Robert S.; Ring, Peter J.; Gentz, Steven J. (Technical Monitor)

    2001-01-01

    Phase I fission propulsion systems focus on safety, timely development, and affordability. Prototype and flight units can be tested at full thrust, using resistance heaters to closely simulate heat from a fission reaction. In Phase I ground testing, one goal is to establish a reliable and affordable manufacturing technique for fabricating a flight-like core. A refractory metal (Mo) has been suggested for the core substrate, primarily due to the existence of a significant database for Mo/LJ02 fuel. The core can be fabricated by bundling Mo tubes with a bonding system that meets preliminary test goals. These criteria include materials compatibility, ability to maintain thermal and structural integrity during 10,000 hours of operation, and fabrication with existing facilities. This paper describes an effort to investigate several fabrication techniques in a cost-effective manner. First, inexpensive materials were tested at low temperatures to determine the relative effectiveness of such techniques as welding, brazing, plating, and vacuum plasma spraying (VPSing). Promising techniques were chosen for further evaluation, including thermal and structural studies, using ceramic tubing at intermediate temperatures. The most desirable technique will be tested on actual Mo tubing at anticipated operating temperatures. This work is being performed by the National Aeronautics & Space Administration (NASA) at George C. Marshall Space Flight Center (MSFC), Los Alamos National Laboratory (LANL), and Advanced Methods & Materials (AMM), Inc.

  14. An Overview of Current and Past W-UO[2] CERMET Fuel Fabrication Technology

    SciTech Connect

    Douglas E. Burkes; Daniel M. Wachs; James E. Werner; Steven D. Howe

    2007-06-01

    Studies dating back to the late 1940s performed by a number of different organizations and laboratories have established the major advantages of Nuclear Thermal Propulsion (NTP) systems, particularly for manned missions. A number of NTP projects have been initiated since this time; none have had any sustained fuel development work that appreciably contributed to fuel fabrication or performance data from this era. As interest in these missions returns and previous space nuclear power researchers begin to retire, fuel fabrication technologies must be revisited, so that established technologies can be transferred to young researchers seamlessly and updated, more advanced processes can be employed to develop successful NTP fuels. CERMET fuels, specifically W-UO2, are of particular interest to the next generation NTP plans since these fuels have shown significant advantages over other fuel types, such as relatively high burnup, no significant failures under severe transient conditions, capability of accommodating a large fission product inventory during irradiation and compatibility with flowing hot hydrogen. Examples of previous fabrication routes involved with CERMET fuels include hot isostatic pressing (HIPing) and press and sinter, whereas newer technologies, such as spark plasma sintering, combustion synthesis and microsphere fabrication might be well suited to produce high quality, effective fuel elements. These advanced technologies may address common issues with CERMET fuels, such as grain growth, ductile to brittle transition temperature and UO2 stoichiometry, more effectively than the commonly accepted ‘traditional’ fabrication routes. Bonding of fuel elements, especially if the fabrication process demands production of smaller element segments, must be investigated. Advanced brazing techniques and compounds are now available that could produce a higher quality bond segment with increased ease in joining. This paper will briefly address the history of

  15. Apparatus for the premixed gas phase combustion of liquid fuels

    SciTech Connect

    Roffe, G.A.; Trucco, H.A.

    1981-04-21

    This invention relates to improvements in the art of liquid fuel combustion and, more particularly, concerns a method and apparatus for the controlled gasification of liquid fuels, the thorough premixing of the then gasified fuel with air and the subsequent gas-phase combustion of the mixture to produce a flame substantially free of soot, carbon monoxide, nitric oxide and unburned fuel.

  16. Inhalation of U aerosols from UO2 fuel element fabrication.

    PubMed

    Schieferdecker, H; Dilger, H; Doerfel, H; Rudolph, W; Anton, R

    1985-01-01

    Publication No. 30 of the International Commission on Radiological Protection (ICRP) assigns the uranium oxides UO2 and U3O8 to transportability class Y, i.e. the half-life of these compounds in the lungs is about 500 days. This assignment seemed not to be in accordance with our experience resulting from incorporation surveillance during UO2 fuel element fabrication. Persons who worked in atmospheres containing UO2 aerosols with activity concentrations significantly above the derived air concentrations (DAC) for class Y U showed much lower activity in the lungs than would be expected according to the ICRP. To understand this discrepancy, aerosol concentrations and aerosol particle-size distributions at work places with the possibility of UO2 incorporation, the activity of urine and feces and the lung activity of persons working at these places were measured in an investigation program. The results are only consistent with the ICRP lung model if one uses a measured biological half-life in the lungs of 109 days and a measured AMAD of 8.2 micron instead of the ICRP standard assumptions of 500 days and 1.0 micron, respectively. ICRP Publication No. 30 recommends application of specific parameters for health physics instead of standard model values. For the special conditions in our UO2 fuel fabrication plant we therefore derive limits of air concentrations, lung activities and fecal and urinary activity concentrations by applying our measured particle-size and lung-retention parameters to the ICRP model. Our special derived limits in comparison to class Y limits for U after ICRP Publication No. 30 for a 1-micron AMAD and 500-day half-life (in brackets) are: (a) annual limit of intake: 6 X 10(4) Bq/y (1 X 10(3) Bq/y); (b) derived air concentration: 20 Bq/m3 (0.6 Bq/m3); (c) derived lung activity: 1.6 X 10(3) Bq; (d) derived fecal activity: 14 Bq/day; and (e) derived urine activity: 8.9 Bq/day. The committed dose equivalents calculated from our measured data and from our

  17. Fabrication and Testing of Full-Length Single-Cell Externally Fueled Converters for Thermionic Reactors

    SciTech Connect

    Schock, Alfred

    1995-08-01

    Paper presented at the 29th IECEC in Monterey, CA in August 1994. The present paper describes the fabrication and testing of full-length prototypcial converters, both unfueled and fueled, and presents parametric results of electrically heated tests.

  18. Prediction of dose and field mapping around a shielded plutonium fuel fabrication glovebox

    SciTech Connect

    Strode, J.N.; Soldat, K.L.; Brackenbush, L.W.

    1984-04-25

    Westinghouse Hanford Company, as the Department of Energy's (DOE) prime contractor for the operation of the Hanford Engineering Development Laboratory (HEDL), is responsible for the development of the Secure Automated Fabrication (SAF) Line which is to be installed in the recently constructed Fuels and Materials Examination Facility (FMEF). The SAF Line will fabricate mixed-oxide (MOX) fuel pins for the Fast Flux Test Facility (FFTF) at an annual throughput rate of six (6) metric tons (MT) of MOX. The SAF Line will also demonstrate the automated manufacture of fuel pins on a production-scale. This paper describes some of the techniques used to reduce personnel exposure on the SAF Line, as well as the prediction and field mapping of doses from a shielded fuel fabrication glovebox. Tables are also presented from which exposure rate estimates can be made for plutonium recovered from fuels having different isotopic compositions as a result of varied burnup.

  19. 10 CFR 72.236 - Specific requirements for spent fuel storage cask approval and fabrication.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 10 Energy 2 2011-01-01 2011-01-01 false Specific requirements for spent fuel storage cask approval and fabrication. 72.236 Section 72.236 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) LICENSING REQUIREMENTS FOR THE INDEPENDENT STORAGE OF SPENT NUCLEAR FUEL, HIGH-LEVEL RADIOACTIVE WASTE, AND...

  20. 10 CFR 72.236 - Specific requirements for spent fuel storage cask approval and fabrication.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 10 Energy 2 2010-01-01 2010-01-01 false Specific requirements for spent fuel storage cask approval and fabrication. 72.236 Section 72.236 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) LICENSING REQUIREMENTS FOR THE INDEPENDENT STORAGE OF SPENT NUCLEAR FUEL, HIGH-LEVEL RADIOACTIVE WASTE, AND...

  1. 10 CFR 72.236 - Specific requirements for spent fuel storage cask approval and fabrication.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 10 Energy 2 2014-01-01 2014-01-01 false Specific requirements for spent fuel storage cask approval and fabrication. 72.236 Section 72.236 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) LICENSING REQUIREMENTS FOR THE INDEPENDENT STORAGE OF SPENT NUCLEAR FUEL, HIGH-LEVEL RADIOACTIVE WASTE, AND REACTOR-RELATED GREATER THAN CLASS C WASTE...

  2. 10 CFR 72.236 - Specific requirements for spent fuel storage cask approval and fabrication.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 10 Energy 2 2013-01-01 2013-01-01 false Specific requirements for spent fuel storage cask approval and fabrication. 72.236 Section 72.236 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) LICENSING REQUIREMENTS FOR THE INDEPENDENT STORAGE OF SPENT NUCLEAR FUEL, HIGH-LEVEL RADIOACTIVE WASTE, AND...

  3. Operation of N Reactor and Fuels Fabrication Facilities, Hanford Reservation, Richland, Benton County, Washington: Environmental assessment

    SciTech Connect

    Not Available

    1980-08-01

    Environmental data, calculations and analyses show no significant adverse radiological or nonradiological impacts from current or projected future operations resulting from N Reactor, Fuels Fabrication and Spent Fuel Storage Facilities. Nonoccupational radiation exposures resulting from 1978 N Reactor operations are summarized and compared to allowable exposure limits.

  4. Current status of U{sub 3}Si{sub 2} fuel element fabrication in Brazil

    SciTech Connect

    Durazzo, M.; Carvalho, E.F. Urano de; Saliba-Silva, A.M.; Souza, J.A.B

    2008-07-15

    IPEN has been working for increasing radioisotope production in order to supply the expanding demand for radiopharmaceutical medicines requested by the Brazilian welfare. To reach this objective, the IEA-R1 research reactor power capacity was recently increased from 2 MW to 4 MW. Since 1988 IPEN has been manufacturing its own fuel element, initially based on U{sub 3}O{sub 8}-Al dispersion fuel plates with 2.3 gU/cm{sup 3}. To support the reactor power increase, higher uranium density in the fuel plate meat had to be achieved for better irradiation flux and also to minimize the irradiated fuel elements to be stored. Uranium silicide was the chosen option and the fuel fabrication development started with the support of the IAEA BRA/4/047 Technical Cooperation Project. This paper describes the results of this program and the current status of silicide fuel fabrication and its qualification. (author)

  5. Interdiffusion Behavior in y-Phase U-Mo Alloy Versus Al-6061 Alloy Couples Fabricated by Friction Stir Welding

    SciTech Connect

    Dennis D. Keiser, Jr.

    2007-09-01

    To better understand interactions between fuel and cladding in research reactor fuels, diffusion couples between y-phase U-7 wt% Mo and U-10 wt% Mo alloy fuels and a Si-bearing, Al alloy were fabricated using a friction stir welding technique. The advantage of such a fabrication technique is that it can potentially reduce the amount of aluminum-oxide that might be present at the diffusion couple interface. The presence of oxides at the interface can affect the interdiffusion process. These couples were annealed and characterized using a scanning electron microscope equipped with energy-dispersive and wavelength-dispersive spectrometers. Images were taken of the developed diffusion structures; x-ray maps were generated to identify partitioning behavior of the various components; and, point-to-point analysis was employed to generate composition profiles and to determine phase compositions. To try and determine how the presence of Si in an Al alloy affects the interdiffusion behavior of fuel and cladding components in research reactor nuclear fuels, the results from this study were compared to those from earlier diffusion studies using U-Mo alloys and Al. The formed diffusion zones in some samples annealed for 30 minutes are comprised of Si-rich aluminide phases that appear to be (U,Mo)0.9(Al,Si)4 and (U,Mo)(Si,Al)2, based on composition. The diffusion rates observed and the types of phases that form can be correlated to the stability of the y-U phase, which is a metastable phase. For a sample annealed for a much longer time, large diffusion structures formed and no Si-rich phases were observed.

  6. Fabrication of (U, Zr) C-fueled/tungsten-clad specimens for irradiation in the Plum Brook Reactor Facility

    NASA Technical Reports Server (NTRS)

    1972-01-01

    Fuel samples, 90UC - 10 ZrC, and chemically vapor deposited tungsten fuel cups were fabricated for the study of the long term dimensional stability and compatibility of the carbide-tungsten fuel-cladding systems under irradiation. These fuel samples and fuel cups were assembled into the fuel pins of two capsules, designated as V-2E and V-2F, for irradiation in NASA Plum Brook Reactor Facility at a fission power density of 172 watts/c.c. and a miximum cladding temperature of 1823 K. Fabrication methods and characteristics of the fuel samples and fuel cups prepared are described.

  7. The Role of Friction Stir Welding in Nuclear Fuel Plate Fabrication

    SciTech Connect

    D Burkes; P Medvedev; M Chapple; A Amritkar; P Wells; I Charit

    2009-02-01

    The friction bonding process combines desirable attributes of both friction stir welding and friction stir processing. The development of the process is spurred on by the need to fabricate thin, high density, reduced enrichment fuel plates for nuclear research reactors. The work seeks to convert research and test reactors currently operating on highly enriched uranium fuel to operate on low enriched uranium fuel without significant loss in reactor performance, safety characteristics, or significant increase in cost. In doing so, the threat of global nuclear material proliferation will be reduced. Feasibility studies performed on the process show that this is a viable option for mass production of plate-type nuclear fuel. Adapting the friction stir weld process for nuclear fuel fabrication has resulted in the development of several unique ideas and observations. Preliminary results of this adaptation and process model development are discussed.

  8. STAGING OF FUEL CELLS - PHASE II

    SciTech Connect

    Per Onnerud; Suresh Sriramulu

    2002-08-29

    TIAX has executed a laboratory-based development program aiming at the improvement of stationary fuel cell systems. The two-year long development program resulted in an improved understanding of staged fuel cells and inorganic proton conductors through evaluation of results from a number of laboratory tasks: (1) Development of a fuel cell modeling tool--Multi-scale model was developed, capable of analyzing the effects of materials and operating conditions; and this model allowed studying various ''what-if'' conditions for hypothetically staged fuel cells; (2) Study of new high temperature proton conductor--TIAX discovery of a new class of sulfonated inorganics capable of conducting protons when exposed to water; and study involved synthesis and conductivity measurements of novel compounds up to 140 C; (3) Electrochemical fuel cell measurements--the feasibility of staged fuel cells was tested in TIAX's fuel cell laboratories experimental design was based on results from modeling.

  9. Characterization of candidate DOE sites for fabricating MOX fuel for lead assemblies

    SciTech Connect

    Holdaway, R.F.; Miller, J.W.; Sease, J.D.; Moses, R.J.; O`Connor, D.G.; Carrell, R.D.; Jaeger, C.D.; Thompson, M.L.; Strasser, A.A.

    1998-03-01

    The Office of Fissile Materials Disposition (MD) of the Department of Energy (DOE) is directing the program to disposition US surplus weapons-usable plutonium. For the reactor option for disposition of this surplus plutonium, MD is seeking to contract with a consortium, which would include a mixed-oxide (MOX) fuel fabricator and a commercial US reactor operator, to fabricate and burn MOX fuel in existing commercial nuclear reactors. This option would entail establishing a MOX fuel fabrication facility under the direction of the consortium on an existing DOE site. Because of the lead time required to establish a MOX fuel fabrication facility and the need to qualify the MOX fuel for use in a commercial reactor, MD is considering the early fabrication of lead assemblies (LAs) in existing DOE facilities under the technical direction of the consortium. The LA facility would be expected to produce a minimum of 1 metric ton heavy metal per year and must be operational by June 2003. DOE operations offices were asked to identify candidate sites and facilities to be evaluated for suitability to fabricate MOX fuel LAs. Savannah River Site, Argonne National Laboratory-West, Hanford, Lawrence Livermore National Laboratory, and Los Alamos National Laboratory were identified as final candidates to host the LA project. A Site Evaluation Team (SET) worked with each site to develop viable plans for the LA project. SET then characterized the suitability of each of the five plans for fabricating MOX LAs using 28 attributes and documented the characterization to aid DOE and the consortium in selecting the site for the LA project. SET concluded that each option has relative advantages and disadvantages in comparison with other options; however, each could meet the requirements of the LA project as outlined by MD and SET.

  10. LOW COST MULTI-LAYER FABRICATION METHOD FOR SOLID OXIDE FUEL CELLS

    SciTech Connect

    Christopher Milliken; Robert Ruhl; Jennifer Hillman

    2002-06-01

    Technology Management, Inc has evaluated the practical fabrication advantages and potential economic impact of a multi-pass screen printing process on the costs of fabricating planar solid oxide fuel cell stacks. During this program, multiple catalyzed binder systems were considered. Preliminary screening experiments resulted in four systems being selected for further evaluation. Inks were formulated using these binders in combination with at least three fuel cell materials (anode, cathode, and seal material). Reactivity of the binder with catalyst and fuel cell materials was evaluated. Cell tests indicated that the catalyzed binders did not negatively impact cell performance. Tests were conducted demonstrating single cell performance comparable with standard cell fabrication technology. Tailored patterns were also demonstrated. Economic evaluation indicated that a significant reduction in cost could be achieved, primarily through reduced capital equipment needs.

  11. Hawaii alternative fuels utilization program. Phase 3, final report

    SciTech Connect

    Kinoshita, C.M.; Staackmann, M.

    1996-08-01

    The Hawaii Alternative Fuels Utilization Program originated as a five-year grant awarded by the US Department of Energy (USDOE) to the Hawaii Natural Energy Institute (HNEI) of the University of Hawaii at Manoa. The overall program included research and demonstration efforts aimed at encouraging and sustaining the use of alternative (i.e., substitutes for gasoline and diesel) ground transportation fuels in Hawaii. Originally, research aimed at overcoming technical impediments to the widespread adoption of alternative fuels was an important facet of this program. Demonstration activities centered on the use of methanol-based fuels in alternative fuel vehicles (AFVs). In the present phase, operations were expanded to include flexible fuel vehicles (FFVs) which can operate on M85 or regular unleaded gasoline or any combination of these two fuels. Additional demonstration work was accomplished in attempting to involve other elements of Hawaii in the promotion and use of alcohol fuels for ground transportation in Hawaii.

  12. Fabrication and Testing of CERMET Fuel Materials for Nuclear Thermal Propulsion

    NASA Technical Reports Server (NTRS)

    Hickman, Robert; Broadway, Jeramie; Mireles, Omar

    2012-01-01

    A first generation Nuclear Cryogenic Propulsion Stage (NCPS) based on Nuclear Thermal Propulsion (NTP) is currently being developed for Advanced Space Exploration Systems. The overall goal of the project is to address critical NTP technology challenges and programmatic issues to establish confidence in the affordability and viability of NTP systems. The current technology roadmap for NTP identifies the development of a robust fuel form as a critical near term need. The lack of a qualified nuclear fuel is a significant technical risk that will require a considerable fraction of program resources to mitigate. Due to these risks and the cost for qualification, the development and selection of a primary fuel must begin prior to Authority to Proceed (ATP) for a specific mission. The fuel development is a progressive approach to incrementally reduce risk, converge the fuel materials, and mature the design and fabrication process of the fuel element. A key objective of the current project is to advance the maturity of CERMET fuels. The work includes fuel processing development and characterization, fuel specimen hot hydrogen screening, and prototypic fuel element testing. Early fuel materials development is critical to help validate requirements and fuel performance. The purpose of this paper is to provide an overview and status of the work at Marshall Space Flight Center (MSFC).

  13. Unirradiated characteristics of U-Si alloys as dispersed-phase fuels

    SciTech Connect

    Domagala, R.F.; Wiencek, T.C.

    1987-06-01

    To satisfy the power demands of many research reactors, a new LEU fuel with a high density and U content was needed. Any fuel must be compatible with Al and its alloys so that it may be fabricable as a dispersed-phase in Al alloy and Al matrix plate-type elements following, as nearly as possible, established commercial manufacturing techniques. U-Si and U-Si-Al alloys at or near the composition of U/sub 3/Si were immediately attractive because of work documented by the Canadians. 8 refs., 2 figs.

  14. SP-100 coated-particle fuel development. Phase I. Final report

    SciTech Connect

    Not Available

    1983-03-01

    This document is the final report of Phase I of the SP-100 Coated-Particle Fuel Development Program conducted by GA Technologies Inc. for the US Department of Energy under contract DE-AT03-82SF11690. The general objective of the study conducted between September and December 1982 was to evaluate coated-particle type fuel as an alternate or backup fuel to the UO/sub 2/ tile-and-fin arrangement currently incorporated into the reference design of the SP-100 reactor core. This report presents and discusses the following topics in the order listed: the need for an alternative fuel for the SP-100 nuclear reactor; an abbreviated description of the reference and coated-particle fuel module concepts; the bases and results of the study and analysis leading to the preliminary design of a coated particle suitable for the SP-100 space power reactor; incorporation of the fuel particles into compacts and heat-pipe-cooled modules; initial efforts and plans to fabricate coated-particle fuel and fuel compacts; the design and performance of the proposed alternative core relative that of the reference fuel; and a summary of critical issues and conclusions consistent with the level of effort and duration of the study.

  15. Broad specification fuels technology program, phase 1

    NASA Technical Reports Server (NTRS)

    Lohmann, R. P.; Jeroszko, R. A.

    1982-01-01

    An experimental evaluation was conducted to assess the impact of the use of broadened properties fuels on combustor design concepts. Emphasis was placed on establishing the viability of design modifications to current combustor concepts and the use of advanced technology concepts to facilitate operation on Experimental Referee Broad Specification (ERBS) fuel while meeting exhaust emissions and performance specifications and maintaining acceptable durability. Three different combustor concepts, representative of progressively more aggressive technology levels, were evaluated. When operated on ERBS rather than Jet A fuel, a single stage combustor typical of that in the most recent versions of the JT9D-7 engine was found to produce excess carbon monoxide emissions at idle and elevated liner temperatures at high power levels that were projected to reduced liner life by 13 percent. The introduction of improved component technology, such as refined fuel injectors and advanced liner cooling concepts were shown to have the potential of enhancing the fuel flexibility of the single stage combustor.

  16. Method of fabricating a monolithic solid oxide fuel cell

    DOEpatents

    Minh, Nguyen Q.; Horne, Craig R.

    1994-01-01

    In a two-step densifying process of making a monolithic solid oxide fuel cell, a limited number of anode-electrolyte-cathode cells separated by an interconnect layer are formed and partially densified. Subsequently, the partially densified cells are stacked and further densified to form a monolithic array.

  17. Method of fabricating a monolithic solid oxide fuel cell

    DOEpatents

    Minh, N.Q.; Horne, C.R.

    1994-03-01

    In a two-step densifying process of making a monolithic solid oxide fuel cell, a limited number of anode-electrolyte-cathode cells separated by an interconnect layer are formed and partially densified. Subsequently, the partially densified cells are stacked and further densified to form a monolithic array. 10 figures.

  18. Microstructural Examination to Aid in Understanding Friction Bonding Fabrication Technique for Monolithic Nuclear Fuel

    SciTech Connect

    Karen L. Shropshire

    2008-04-01

    Monolithic nuclear fuel is currently being developed for use in research reactors, and friction bonding (FB) is a technique being developed to help in this fuel’s fabrication. Since both FB and monolithic fuel are new concepts, research is needed to understand the impact of varying FB fabrication parameters on fuel plate characteristics. This thesis research provides insight into the FB process and its application to the monolithic fuel design by recognizing and understanding the microstructural effects of varying fabrication parameters (a) FB tool load, and (b) FB tool face alloy. These two fabrication parameters help drive material temperature during fabrication, and thus the material properties, bond strength, and possible formation of interface reaction layers. This study analyzed temperatures and tool loads measured during those FB processes and examined microstructural characteristics of materials and bonds in samples taken from the resulting fuel plates. This study shows that higher tool load increases aluminum plasticization and forging during FB, and that the tool face alloy helps determine the tool’s heat extraction efficacy. The study concludes that successful aluminum bonds can be attained in fuel plates using a wide range of FB tool loads. The range of tool loads yielding successful uranium-aluminum bonding was not established, but it was demonstrated that such bonding can be attained with FB tool load of 48,900 N (11,000 lbf) when using a FB tool faced with a tungsten alloy. This tool successfully performed FB, and with better results than tools faced with other materials. Results of this study correlate well with results reported for similar aluminum bonding techniques. This study’s results also provide support and validation for other nuclear fuel development studies and conclusions. Recommendations are offered for further research.

  19. Design and fabrication of specific ceramic?metallic fuels and targets

    NASA Astrophysics Data System (ADS)

    Fernández, A.; Konings, R. J. M.; Somers, J.

    2003-06-01

    The fabrication of ceramic-metallic (cermet) composite fuel, containing (Y,An,Zr)O 2- x spheres, by dust free processes has been studied. The influence of several process parameters, such as, ceramic volume fraction, compaction pressure and sintering temperature, on the microstructure of the final composite have been investigated and optimised using cerium as a stand for americium and two metal matrices namely molybdenum and stainless steel. In addition, a cermet fuel with (near) spherical (Y,Pu,Zr)O 2- x particles, dispersed in stainless steel matrix, has been successfully fabricated and characterized.

  20. Dual phase MgO-ZrO 2 ceramics for use in LWR inert matrix fuel

    NASA Astrophysics Data System (ADS)

    Medvedev, P. G.; Frank, S. M.; O'Holleran, T. P.; Meyer, M. K.

    2005-06-01

    To address the low thermal conductivity of the ZrO 2-based inert matrix fuel and the instability in water of the MgO-based inert matrix fuel, the dual-phase MgO-ZrO 2 ceramics are proposed as a matrix for light water reactor fuel for actinide transmutation and Pu burning. It is envisioned that in a dual-phase system MgO will act as efficient heat conductor while ZrO 2 will provide protection from the coolant attack. This paper describes results of fabrication, characterization and hydration testing of MgO-ZrO 2 ceramics containing 30-70 wt% of MgO.

  1. Recent progress on minor-actinide-bearing oxide fuel fabrication at CEA Marcoule

    NASA Astrophysics Data System (ADS)

    Lebreton, Florent; Prieur, Damien; Horlait, Denis; Delahaye, Thibaud; Jankowiak, Aurélien; Léorier, Caroline; Jorion, Frédéric; Gavilan, Elisabeth; Desmoulière, François

    2013-07-01

    Partitioning and transmutation (P&T) of minor actinides (MA: americium, neptunium and curium) in fast neutron reactors or accelerator-driven systems is a route envisaged to reduce nuclear waste inventory. Over the years, several modes of P&T were proposed, each being based on the use of dedicated fuels such as inert-matrix fuels, MA-bearing MOX or MA-bearing blankets. In this context, progress on the manufacturing of such fuels is a key-challenge in order to render P&T viable at the industrial scale. Here, MA-bearing oxide fuel fabrication and characterization conducted in the CEA Marcoule Atalante facility is reviewed. A particular attention is also given to the research conducted on uranium-americium mixed-oxides fuels, which are now considered the reference fuels for MA transmutation in France.

  2. Design Evolutuion of Hot Isotatic Press Cans for NTP Cermet Fuel Fabrication

    NASA Technical Reports Server (NTRS)

    Mireles, O. R.; Broadway, J.; Hickman, R.

    2014-01-01

    Nuclear Thermal Propulsion (NTP) is under consideration for potential use in deep space exploration missions due to desirable performance properties such as a high specific impulse (> 850 seconds). Tungsten (W)-60vol%UO2 cermet fuel elements are under development, with efforts emphasizing fabrication, performance testing and process optimization to meet NTP service life requirements [1]. Fuel elements incorporate design features that provide redundant protection from crack initiation, crack propagation potentially resulting in hot hydrogen (H2) reduction of UO2 kernels. Fuel erosion and fission product retention barriers include W coated UO2 fuel kernels, W clad internal flow channels and fuel element external W clad resulting in a fully encapsulated fuel element design as shown.

  3. External fuel vaporization study, phase 2

    NASA Technical Reports Server (NTRS)

    Szetela, E. J.; Chiappetta, L.

    1981-01-01

    An analytical study was conducted to evaluate the effect of variations in fuel properties on the design of an external fuel vaporizaton system. The fuel properties that were considered included thermal stability, critical temperature, enthalpy a critical conditions, volatility, and viscosity. The design parameters that were evaluated included vaporizer weight and the impact on engine requirement such as maintenance, transient response, performance, and altitude relight. The baseline fuel properties were those of Jet A. The variation in thermal stability was taken as the thermal stability variation for Experimental Referee Broad Specification (ERBS) fuel. The results of the analysis indicate that a change in thermal stability equivalent to that of ERBS would increase the vaporization system weight by 20 percent, decrease oprating time between cleaning by 40 percent and make altitude relight more difficult. An increase in fuel critical temperature of 39 K would require a 40 percent increase in vaporization system weight. The assumed increase in enthalpy and volatility would also increase vaporizer weight by 40 percent and make altitude relight extremely difficult. The variation in fuel viscosity would have a negligible effect on the design parameters.

  4. Literature on fabrication of tungsten for application in pyrochemical processing of spent nuclear fuels

    SciTech Connect

    Edstrom, C.M.; Phillips, A.G.; Johnson, L.D.; Corle, R.R.

    1980-10-11

    The pyrochemical processing of nuclear fuels requires crucibles, stirrers, and transfer tubing that will withstand the temperature and the chemical attack from molten salts and metals used in the process. This report summarizes the literature that pertains to fabrication (joining, chemical vapor deposition, plasma spraying, forming, and spinning) is the main theme. This report also summarizes a sampling of literature on molbdenum and the work previously performed at Argonne National Laboratory on other container materials used for pyrochemical processing of spent nuclear fuels.

  5. 30 CFR 250.917 - What are the CVA's primary duties during the fabrication phase?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 2 2011-07-01 2011-07-01 false What are the CVA's primary duties during the fabrication phase? 250.917 Section 250.917 Mineral Resources BUREAU OF OCEAN ENERGY MANAGEMENT, REGULATION... duties during the fabrication phase? (a) The CVA must use good engineering judgement and practices...

  6. Multi-fuel reformers for fuel cells used in transportation. Multi-fuel reformers: Phase 1 -- Final report

    SciTech Connect

    Not Available

    1994-05-01

    DOE has established the goal, through the Fuel Cells in Transportation Program, of fostering the rapid development and commercialization of fuel cells as economic competitors for the internal combustion engine. Central to this goal is a safe feasible means of supplying hydrogen of the required purity to the vehicular fuel cell system. Two basic strategies are being considered: (1) on-board fuel processing whereby alternative fuels such as methanol, ethanol or natural gas stored on the vehicle undergo reformation and subsequent processing to produce hydrogen, and (2) on-board storage of pure hydrogen provided by stationary fuel processing plants. This report analyzes fuel processor technologies, types of fuel and fuel cell options for on-board reformation. As the Phase 1 of a multi-phased program to develop a prototype multi-fuel reformer system for a fuel cell powered vehicle, the objective of this program was to evaluate the feasibility of a multi-fuel reformer concept and to select a reforming technology for further development in the Phase 2 program, with the ultimate goal of integration with a DOE-designated fuel cell and vehicle configuration. The basic reformer processes examined in this study included catalytic steam reforming (SR), non-catalytic partial oxidation (POX) and catalytic partial oxidation (also known as Autothermal Reforming, or ATR). Fuels under consideration in this study included methanol, ethanol, and natural gas. A systematic evaluation of reforming technologies, fuels, and transportation fuel cell applications was conducted for the purpose of selecting a suitable multi-fuel processor for further development and demonstration in a transportation application.

  7. Evaluation of LANL Capabilities for Fabrication of TREAT Conversion Fuel

    SciTech Connect

    Luther, Erik Paul; Leckie, Rafael M.; Dombrowski, David E.

    2014-03-06

    This report estimates costs and schedule associated with scale up and fabrication of a low-enriched uranium (LEU) core for the Transient Reactor Test Facility (TREAT) reactor. This study considers facilities available at Los Alamos National Laboratory, facility upgrades, equipment, installation and staffing costs. Not included are costs associated with raw materials and off-site shipping. These estimates are considered a rough of magnitude. At this time, no specifications for the LEU core have been made and the final schedule needed by the national program. The estimate range (+/-100%) reflects this large uncertainty and is subject to change as the project scope becomes more defined.

  8. Application of Self-Propagating High Temperature Synthesis to the Fabrication of Actinide Bearing Nitride and Other Ceramic Nuclear Fuels

    SciTech Connect

    Moore, John J.; Reigel, Marissa M.; Donohoue, Collin D.

    2009-04-30

    The project uses an exothermic combustion synthesis reaction, termed self-propagating high-temperature synthesis (SHS), to produce high quality, reproducible nitride fuels and other ceramic type nuclear fuels (cercers and cermets, etc.) in conjunction with the fabrication of transmutation fuels. The major research objective of the project is determining the fundamental SHS processing parameters by first using manganese as a surrogate for americium to produce dense Zr-Mn-N ceramic compounds. These fundamental principles will then be transferred to the production of dense Zr-Am-N ceramic materials. A further research objective in the research program is generating fundamental SHS processing data to the synthesis of (i) Pu-Am-Zr-N and (ii) U-Pu-Am-N ceramic fuels. In this case, Ce will be used as the surrogate for Pu, Mn as the surrogate for Am, and depleted uranium as the surrogate for U. Once sufficient fundamental data has been determined for these surrogate systems, the information will be transferred to Idaho National Laboratory (INL) for synthesis of Zr-Am-N, Pu-Am-Zr-N and U-Pu-Am-N ceramic fuels. The high vapor pressures of americium (Am) and americium nitride (AmN) are cause for concern in producing nitride ceramic nuclear fuel that contains Am. Along with the problem of Am retention during the sintering phases of current processing methods, are additional concerns of producing a consistent product of desirable homogeneity, density and porosity. Similar difficulties have been experienced during the laboratory scale process development stage of producing metal alloys containing Am wherein compact powder sintering methods had to be abandoned. Therefore, there is an urgent need to develop a low-temperature or low–heat fuel fabrication process for the synthesis of Am-containing ceramic fuels. Self-propagating high temperature synthesis (SHS), also called combustion synthesis, offers such an alternative process for the synthesis of Am nitride fuels. Although SHS

  9. Airborne ultrasonic phased arrays using ferroelectrets: a new fabrication approach.

    PubMed

    Ealo, Joao L; Camacho, Jorge J; Fritsch, Carlos

    2009-04-01

    In this work, a novel procedure that considerably simplifies the fabrication process of ferroelectret-based multielement array transducers is proposed and evaluated. Also, the potential of ferroelectrets being used as active material for air-coupled ultrasonic transducer design is demonstrated. The new construction method of multi-element transducers introduces 2 distinctive improvements. First, active ferroelectret material is not discretized into elements, and second, the need of structuring upper and/or lower electrodes in advance of the permanent polarization of the film is removed. The aperture discretization and the mechanical connection are achieved in one step using a through-thickness conductive tape. To validate the procedure, 2 linear array prototypes of 32 elements, with a pitch of 3.43 mm and a wide usable frequency range from 30 to 300 kHz, were built and evaluated using a commercial phased-array system. A low crosstalk among elements, below -30 dB, was measured by interferometry. Likewise, a homogeneous response of the array elements, with a maximum deviation of +/-1.8 dB, was obtained. Acoustic beam steering measurements were accomplished at different deflection angles using a calibrated microphone. The ultrasonic beam parameters, namely, lateral resolution, side lobe level, grating lobes, and focus depth, were congruent with theory. Acoustic images of a single reflector were obtained using one of the array elements as the receiver. Resulting images are also in accordance with numerical simulation, demonstrating the feasibility of using these arrays in pulse-echo mode. The proposed procedure simplifies the manufacturing of multidimensional arrays with arbitrary shape elements and not uniformly distributed. Furthermore, this concept can be extended to nonflat arrays as long as the transducer substrate conforms to a developable surface. PMID:19406714

  10. Development of Hot Pressing as a Low Cost Processing Technique for Fuel Cell Fabrication

    SciTech Connect

    Sarin, V

    2003-01-14

    Dependable, plentiful, and economical energy has been the driving force for financial, industrial, and political growth in the US since the mid 19th century. For a country whose progress is so deeply rooted in abundant energy and whose current political agenda involves stabilizing world fossil fuel prices, the development of a reliable, efficient and environmentally friendly power generating source seems compulsory. The maturing of high technology fuel cells may be the panacea the country will find indispensable to free itself from foreign dependence. Fuel cells offer an efficient, combustion-less, virtually pollution-free power source, capable of being sited in downtown urban areas or in remote regions. Fuel cells have few moving parts and run almost silently. Fuel cells are electrochemical devices that convert the chemical energy of a fuel directly to electrical energy. Unlike batteries, which store a finite amount of energy, fuel cells will generate electricity continuously, as long as fuel and oxidant are available to the electrodes. Additionally, fuel cells offer clean, efficient, and reliable power and they can be operated using a variety of fuels. Hence, the fuel cell is an extremely promising technology. Over the course of this research, the fundamental knowledge related to ceramic processing, sintering, and hot pressing to successfully hot press a single operational SOFC in one step has been developed. Ceramic powder processing for each of the components of an SOFC has bene tailored towards this goal. Processing parameter for the electrolyte and cathode have been studied and developed until they converted. Several anode fabrication techniques have been developed. Additionally, a novel anode structured has been developed and refined. These individual processes have been cultivated until a single cell SOFC has been fabricated in one step.

  11. PRELIMINARY DATA CALL REPORT ADVANCED BURNER REACTOR START UP FUEL FABRICATION FACILITY

    SciTech Connect

    S. T. Khericha

    2007-04-01

    The purpose of this report is to provide data for preparation of a NEPA Environmental Impact Statement in support the U. S. Department of Energy (DOE) Global Nuclear Energy Partnership (GNEP). One of the GNEP objectives is to reduce the inventory of long lived actinide from the light water reactor (LWR) spent fuel. The LWR spent fuel contains Plutonium (Pu) -239 and other transuranics (TRU) such as Americium-241. One of the options is to transmute or burn these actinides in fast neutron spectra as well as generate the electricity. A sodium-cooled Advanced Recycling Reactor (ARR) concept has been proposed to achieve this goal. However, fuel with relatively high TRU content has not been used in the fast reactor. To demonstrate the utilization of TRU fuel in a fast reactor, an Advanced Burner Reactor (ABR) prototype of ARR is proposed, which would necessarily be started up using weapons grade (WG) Pu fuel. The WG Pu is distinguished by relatively highest proportions of Pu-239 and lesser amount of other actinides. The WG Pu will be used as the startup fuel along with TRU fuel in lead test assemblies. Because such fuel is not currently being produced in the US, a new facility (or new capability in an existing facility) is being considered for fabrication of WG Pu fuel for the ABR. This report is provided in response to ‘Data Call’ for the construction of startup fuel fabrication facility. It is anticipated that the facility will provide the startup fuel for 10-15 years and will take to 3 to 5 years to construct.

  12. Fabrication of catalytic electrodes for molten carbonate fuel cells

    DOEpatents

    Smith, James L.

    1988-01-01

    A porous layer of catalyst material suitable for use as an electrode in a molten carbonate fuel cell includes elongated pores substantially extending across the layer thickness. The catalyst layer is prepared by depositing particulate catalyst material into polymeric flocking on a substrate surface by a procedure such as tape casting. The loaded substrate is heated in a series of steps with rising temperatures to set the tape, thermally decompose the substrate with flocking and sinter bond the catalyst particles into a porous catalytic layer with elongated pores across its thickness. Employed as an electrode, the elongated pores provide distribution of reactant gas into contact with catalyst particles wetted by molten electrolyte.

  13. Automated catalyst processing for cloud electrode fabrication for fuel cells

    DOEpatents

    Goller, Glen J.; Breault, Richard D.

    1980-01-01

    A process for making dry carbon/polytetrafluoroethylene floc material, particularly useful in the manufacture of fuel cell electrodes, comprises of the steps of floccing a co-suspension of carbon particles and polytetrafluoroethylene particles, filtering excess liquids from the co-suspension, molding pellet shapes from the remaining wet floc solids without using significant pressure during the molding, drying the wet floc pellet shapes within the mold at temperatures no greater than about 150.degree. F., and removing the dry pellets from the mold.

  14. Conductivity fuel cell collector plate and method of fabrication

    DOEpatents

    Braun, James C.

    2002-01-01

    An improved method of manufacturing a PEM fuel cell collector plate is disclosed. During molding a highly conductive polymer composite is formed having a relatively high polymer concentration along its external surfaces. After molding the polymer rich layer is removed from the land areas by machining, grinding or similar process. This layer removal results in increased overall conductivity of the molded collector plate. The polymer rich surface remains in the collector plate channels, providing increased mechanical strength and other benefits to the channels. The improved method also permits greater mold cavity thickness providing a number of advantages during the molding process.

  15. 76 FR 22735 - Shaw AREVA MOX Services, Mixed Oxide Fuel Fabrication Facility; License Amendment Request, Notice...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-04-22

    ... NRC E-Filing rule (72 FR 49139, August 28, 2007). The E-Filing process requires participants to submit... filing requirements of the NRC's E-Filing Rule (72 FR 49139; August 28, 2007) apply to appeals of NRC... CAMOX-001 authorizes the construction of a plutonium processing and fuel fabrication plant....

  16. Improved Phase-Mask Fabrication of Fiber Bragg Gratings

    NASA Technical Reports Server (NTRS)

    Grant, Joseph; Wang, Ying; Sharma, Anup

    2004-01-01

    An improved method of fabrication of Bragg gratings in optical fibers combines the best features of two prior methods: one that involves the use of a phase mask and one that involves interference between the two coherent laser beams. The improved method affords flexibility for tailoring Bragg wavelengths and bandwidths over wide ranges. A Bragg grating in an optical fiber is a periodic longitudinal variation in the index of refraction of the fiber core. The spatial period (Bragg wavelength) is chosen to obtain enhanced reflection of light of a given wavelength that would otherwise propagate relatively unimpeded along the core. Optionally, the spatial period of the index modulation can be made to vary gradually along the grating (such a grating is said to be chirped ) in order to obtain enhanced reflection across a wavelength band, the width of which is determined by the difference between the maximum and minimum Bragg wavelengths. In the present method as in both prior methods, a Bragg grating is formed by exposing an optical fiber to an ultraviolet-light interference field. The Bragg grating coincides with the pattern of exposure of the fiber core to ultraviolet light; in other words, the Bragg grating coincides with the interference fringes. Hence, the problem of tailoring the Bragg wavelength and bandwidth is largely one of tailoring the interference pattern and the placement of the fiber in the interference pattern. In the prior two-beam interferometric method, a single laser beam is split into two beams, which are subsequently recombined to produce an interference pattern at the location of an optical fiber. In the prior phase-mask method, a phase mask is used to diffract a laser beam mainly into two first orders, the interference between which creates the pattern to which an optical fiber is exposed. The prior two-beam interferometric method offers the advantage that the period of the interference pattern can be adjusted to produce gratings over a wide range

  17. External fuel vaporization study, phase 1

    NASA Technical Reports Server (NTRS)

    Szetela, E. J.; Chiappetta, L.

    1980-01-01

    A conceptual design study was conducted to devise and evaluate techniques for the external vaporization of fuel for use in an aircraft gas turbine with characteristics similar to the Energy Efficient Engine (E(3)). Three vaporizer concepts were selected and they were analyzed from the standpoint of fuel thermal stability, integration of the vaporizer system into the aircraft engine, engine and vaporizer dynamic response, startup and altitude restart, engine performance, control requirements, safety, and maintenance. One of the concepts was found to improve the performance of the baseline E(3) engine without seriously compromising engine startup and power change response. Increased maintenance is required because of the need for frequent pyrolytic cleaning of the surfaces in contact with hot fuel.

  18. Conceptual study of measures against heat generation for TRU fuel fabrication system

    SciTech Connect

    Kawaguchi, Koichi; Namekawa, Takashi

    2007-07-01

    To lower the reprocessing cost and the environmental burden, the Japan Atomic Energy Agency (JAEA) has developed low decontamination TRU fuel fabrication system. TRU fuel contains MA of 1.2 to 5 wt% and its decay heat is estimated a few tens W/kg-HM. As the heat affects fuel quality through oxidation of fuel material and members, it is necessary to remove decay heat. In this work, authors designed concepts of the measures against heat generation at typical equipments using with the thermal hydraulics analysis technique. As a result, it is shown that it is possible to cool fuel materials with specific heat generation up to 20 W/kg-HM enough, though more detailed study is required for comprehensive equipments. (authors)

  19. Process Developed for Fabricating Engineered Pore Structures for High- Fuel-Utilization Solid Oxide Fuel Cells

    NASA Technical Reports Server (NTRS)

    Sofie, Stephen W.; Cable, Thomas L.; Salamone, Sam M.

    2005-01-01

    Solid oxide fuel cells (SOFCs) have tremendous commercial potential because of their high efficiency, high energy density, and flexible fuel capability (ability to use fossil fuels). The drive for high-power-utilizing, ultrathin electrolytes (less than 10 microns), has placed an increased demand on the anode to provide structural support, yet allow sufficient fuel entry for sustained power generation. Concentration polarization, a condition where the fuel demand exceeds the supply, is evident in all commercial-based anode-supported cells, and it presents a significant roadblock to SOFC commercialization.

  20. Fabrication of fuel cell electrodes and other catalytic structures

    DOEpatents

    Smith, J.L.

    1987-02-11

    A porous layer of catalyst material suitable for use as an electrode in a molten carbonate fuel cell includes elongated pores substantially extending across the layer thickness. The catalyst layer is prepared by depositing particulate catalyst material into polymeric flocking on a substrate surface by a procedure such as tape casting. The loaded substrate is heated in a series of steps with rising temperatures to set the tape, thermally decompose the substrate with flocking and sinter bond the catalyst particles into a porous catalytic layer with elongated pores across its thickness. Employed as an electrode, the elongated pores provide distribution of reactant gas into contact with catalyst particles wetted by molten electrolyte. 1 fig.

  1. Fabrication of large aperture kinoform phase plates in fused silica for smoothing focal plane intensity profiles

    SciTech Connect

    Rushford, M.; Dixit, S.; Thomas, I.; Perry, M.

    1996-04-26

    We have fabricated large aperture (40-cm) kinoform phase plates for producing super-Gaussian focal plane intensity profiles. The continuous phase screen, designed using a new iterative procedure, was fabricated in fused silica as a 16-level, one-wave deep rewrapped phase profile using a lithographic process and wet etching in buffered hydrofluoric acid. The observed far-field contains 94% of the incident energy inside the desired spot.

  2. Design, fabrication and testing of a liquid hydrogen fuel tank for a long duration aircraft

    NASA Astrophysics Data System (ADS)

    Mills, Gary L.; Buchholtz, Brian; Olsen, Al

    2012-06-01

    Liquid hydrogen has distinct advantages as an aircraft fuel. These include a specific heat of combustion 2.8 times greater than gasoline or jet fuel and zero carbon emissions. It can be utilized by fuel cells, turbine engines and internal combustion engines. The high heat of combustion is particularly important in the design of long endurance aircraft with liquid hydrogen enabling cruise endurance of several days. However, the mass advantage of the liquid hydrogen fuel will result in a mass advantage for the fuel system only if the liquid hydrogen tank and insulation mass is a small fraction of the hydrogen mass. The challenge is producing a tank that meets the mass requirement while insulating the cryogenic liquid hydrogen well enough to prevent excessive heat leak and boil off. In this paper, we report on the design, fabrication and testing of a liquid hydrogen fuel tank for a prototype high altitude long endurance (HALE) demonstration aircraft. Design options on tank geometry, tank wall material and insulation systems are discussed. The final design is an aluminum sphere insulated with spray on foam insulation (SOFI). Several steps and organizations were involved in the tank fabrication and test. The tank was cold shocked, helium leak checked and proof pressure tested. The overall thermal performance was verified with a boil off test using liquid hydrogen.

  3. Binder Jetting: A Novel Solid Oxide Fuel-Cell Fabrication Process and Evaluation

    NASA Astrophysics Data System (ADS)

    Manogharan, Guha; Kioko, Meshack; Linkous, Clovis

    2015-03-01

    With an ever-growing concern to find a more efficient and less polluting means of producing electricity, fuel cells have constantly been of great interest. Fuel cells electrochemically convert chemical energy directly into electricity and heat without resorting to combustion/mechanical cycling. This article studies the solid oxide fuel cell (SOFC), which is a high-temperature (100°C to 1000°C) ceramic cell made from all solid-state components and can operate under a wide range of fuel sources such as hydrogen, methanol, gasoline, diesel, and gasified coal. Traditionally, SOFCs are fabricated using processes such as tape casting, calendaring, extrusion, and warm pressing for substrate support, followed by screen printing, slurry coating, spray techniques, vapor deposition, and sputter techniques, which have limited control in substrate microstructure. In this article, the feasibility of engineering the porosity and configuration of an SOFC via an additive manufacturing (AM) method known as binder jet printing was explored. The anode, cathode and oxygen ion-conducting electrolyte layers were fabricated through AM sequentially as a complete fuel cell unit. The cell performance was measured in two modes: (I) as an electrolytic oxygen pump and (II) as a galvanic electricity generator using hydrogen gas as the fuel. An analysis on influence of porosity was performed through SEM studies and permeability testing. An additional study on fuel cell material composition was conducted to verify the effects of binder jetting through SEM-EDS. Electrical discharge of the AM fabricated SOFC and nonlinearity of permeability tests show that, with additional work, the porosity of the cell can be modified for optimal performance at operating flow and temperature conditions.

  4. Design and Fabrication of the First Commercial-Scale Liquid Phase Methanol (LPMEOH) Reactor

    SciTech Connect

    1998-12-21

    The Liquid Phase Methanol (LPMEOHT) process uses a slurry bubble column reactor to convert synthesis gas (syngas), primarily a mixture of carbon monoxide and hydrogen, to methanol. Because of its superior heat management the process can utilize directly the carbon monoxide (CO)-rich syngas characteristic of the gasification of coal, petroleum coke, residual oil, wastes, or other hydrocarbon feedstocks. The LPMEOHM Demonstration Project at Kingsport, Tennessee, is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L.P., a partnership between Air Products and Chemicals, Inc. and Eastman Chemical Company, to produce methanol from coal-derived syngas. Construction of the LPMEOH~ Process Demonstration Plant at Eastman's chemicals-from-coal complex in Kingsport was completed in January 1997. Following commissioning and shakedown activities, the fwst production of methanol from the facility occurred on April 2, 1997. Nameplate capacity of 260 short tons per day (TPD) was achieved on April 6, 1997, and production rates have exceeded 300 TPD of methanol at times. This report describes the design, fabrication, and installation of the Kingsport LPMEOEFM reactor, which is the first commercial-scale LPMEOEPM reaetor ever built. The vessel is 7.5 feet in diameter and 70 feet tall with design conditions of 1000 psig at 600 `F. These dimensions represent a significant scale-up from prior experience at the DOE-owned Alternative Fuels Development Unit in LaPorte, Texas, where 18-inch and 22-inch diameter reactors have been tested successfidly over thousands of hours. The biggest obstacles discovered during the scale- up, however, were encountered during fabrication of the vessel. The lessons learned during this process must be considered in tailoring the design for future sites, where the reactor dimensions may grow by yet another factor of two.

  5. LOW COST MULTI-LAYER FABRICATION METHOD FOR SOLID OXIDE FUEL CELLS (SOFC)

    SciTech Connect

    Dr. Christopher E. Milliken; Dr. Robert C. Ruhl

    2001-05-16

    Under this program, Technology Management, Inc, is evaluating the economic advantages of a multi-pass printing process on the costs of fabricating planar solid oxide fuel cell stacks. The technique, still unproven technically, uses a ''green-field'' or build-up approach. Other more mature processes were considered to obtain some baseline assumptions. Based on this analysis, TMI has shown that multi-pass printing can offer substantial economic advantages over many existing fabrication processes and can reduce costs. By impacting overall production costs, the time is compressed to penetrate early low volume niche markets and more mature high-volume market applications.

  6. Actinide partitioning-transmutation program final report. IV. Miscellaneous aspects. [Transport; fuel fabrication; decay; policy; economics

    SciTech Connect

    Alexander, C.W.; Croff, A.G.

    1980-09-01

    This report discusses seven aspects of actinide partitioning-transmutation (P-T) which are important in any complete evaluation of this waste treatment option but which do not fall within other major topical areas concerning P-T. The so-called miscellaneous aspects considered are (1) the conceptual design of a shipping cask for highly neutron-active fresh and spent P-T fuels, (2) the possible impacts of P-T on mixed-oxide fuel fabrication, (3) alternatives for handling the existing and to-be-produced spent fuel and/or wastes until implementation of P-T, (4) the decay and dose characteristics of P-T and standard reactor fuels, (5) the implications of P-T on currently existing nuclear policy in the United States, (6) the summary costs of P-T, and (7) methods for comparing the risks, costs, and benefits of P-T.

  7. ECAS Phase I fuel cell results. [Energy Conservation Alternatives Study

    NASA Technical Reports Server (NTRS)

    Warshay, M.

    1978-01-01

    This paper summarizes and discusses the fuel cell system results of Phase I of the Energy Conversion Alternatives Study (ECAS). Ten advanced electric powerplant systems for central-station baseload generation using coal were studied by NASA in ECAS. Three types of low-temperature fuel cells (solid polymer electrolyte, SPE, aqueous alkaline, and phosphoric acid) and two types of high-temperature fuel cells (molten carbonate, MC, and zirconia solid electrolyte, SE) were studied. The results indicate that (1) overall efficiency increases with fuel cell temperature, and (2) scale-up in powerplant size can produce a significant reduction in cost of electricity (COE) only when it is accompanied by utilization of waste fuel cell heat through a steam bottoming cycle and/or integration with a gasifier. For low-temperature fuel cell systems, the use of hydrogen results in the highest efficiency and lowest COE. In spite of higher efficiencies, because of higher fuel cell replacement costs integrated SE systems have higher projected COEs than do integrated MC systems. Present data indicate that life can be projected to over 30,000 hr for MC fuel cells, but data are not yet sufficient for similarly projecting SE fuel cell life expectancy.

  8. A Blueprint for GNEP Advanced Burner Reactor Startup Fuel Fabrication Facility

    SciTech Connect

    S. Khericha

    2010-12-01

    The purpose of this article is to identify the requirements and issues associated with design of GNEP Advanced Burner Reactor Fuel Facility. The report was prepared in support of providing data for preparation of a NEPA Environmental Impact Statement in support the U. S. Department of Energy (DOE) Global Nuclear Energy Partnership (GNEP). One of the GNEP objectives was to reduce the inventory of long lived actinide from the light water reactor (LWR) spent fuel. The LWR spent fuel contains Plutonium (Pu) -239 and other transuranics (TRU) such as Americium-241. One of the options is to transmute or burn these actinides in fast neutron spectra as well as generate the electricity. A sodium-cooled Advanced Recycling Reactor (ARR) concept was proposed to achieve this goal. However, fuel with relatively high TRU content has not been used in the fast reactor. To demonstrate the utilization of TRU fuel in a fast reactor, an Advanced Burner Reactor (ABR) prototype of ARR was proposed, which would necessarily be started up using weapons grade (WG) Pu fuel. The WG Pu is distinguished by relatively highest proportions of Pu-239 and lesser amount of other actinides. The WG Pu was assumed to be used as the startup fuel along with TRU fuel in lead test assemblies. Because such fuel is not currently being produced in the US, a new facility (or new capability in an existing facility) was being considered for fabrication of WG Pu fuel for the ABR. It was estimated that the facility will provide the startup fuel for 10-15 years and would take 3 to 5 years to construct.

  9. Oxidation Protection of Uranium Nitride Fuel using Liquid Phase Sintering

    SciTech Connect

    Dr. Paul A. Lessing

    2012-03-01

    Two methods are proposed to increase the oxidation resistance of uranium nitride (UN) nuclear fuel. These paths are: (1) Addition of USi{sub x} (e.g. U3Si2) to UN nitride powder, followed by liquid phase sintering, and (2) 'alloying' UN nitride with various compounds (followed by densification via Spark Plasma Sintering or Liquid Phase Sintering) that will greatly increase oxidation resistance. The advantages (high thermal conductivity, very high melting point, and high density) of nitride fuel have long been recognized. The sodium cooled BR-10 reactor in Russia operated for 18 years on uranium nitride fuel (UN was used as the driver fuel for two core loads). However, the potential advantages (large power up-grade, increased cycle lengths, possible high burn-ups) as a Light Water Reactor (LWR) fuel are offset by uranium nitride's extremely low oxidation resistance (UN powders oxidize in air and UN pellets decompose in hot water). Innovative research is proposed to solve this problem and thereby provide an accident tolerant LWR fuel that would resist water leaks and high temperature steam oxidation/spalling during an accident. It is proposed that we investigate two methods to increase the oxidation resistance of UN: (1) Addition of USi{sub x} (e.g. U{sub 3}Si{sub 2}) to UN nitride powder, followed by liquid phase sintering, and (2) 'alloying' UN nitride with compounds (followed by densification via Spark Plasma Sintering) that will greatly increase oxidation resistance.

  10. Low NO/sub x/ Heavy Fuel Combustor Concept Program. Phase I. Final report

    SciTech Connect

    Cutrone, M B

    1981-10-01

    Six combustor concepts were designed, fabricated, and underwent a series of combustion tests with the objective of evaluating and developing a combustor capable of meeting US New Source Performance Standards (NSPS), dry, for high-nitrogen liquid fuels. Three rich/lean and three lean/lean two-stage combustors were tested with ERBS distillate, petroleum residual, and SRC-II coal derived liquid (CDL) fuels with fuel-bound nitrogen contents of 0.0054, 0.23, and 0.87 weight percent, respectively. A lean/lean concept was demonstrated with ultralow NO/sub x/ emissions, dry, of 5 gm NO/sub x/kg fuel on ERBS, and NO/sub x/ emissions meeting the NSPS NO/sub x/ standard on residual fuel. This combustor concept met operational goals for pressure drop, smoke, exhaust pattern factor, and combustion efficiency. A rich/lean concept was identified and developed which demonstrated NO/sub x/ emissions approaching the NSPS standards, dry, for all liquid fuels including the 0.87 weight percent nitrogen SRC-II coal-derived liquid. Exhaust pattern factor and pressure drop met or approached goals. Smoke emissions were higher than the program goal. However, a significant improvement was made with only a minor modification of the fuel injector/air swirler system, and further development should result in meeting smoke goals for all fuels. Liner metal temperatures were higher than allowable for commercial application. Conceptual designs for further development of these two rich/lean and lean/lean concepts have been completed which address smoke and metal temperature concerns, and are available for the next phase of this NASA-sponsored, DOE-funded program. Tests of a rich/lean concept, and a catalytic combustor concept using low- and intermediate-Btu simulated coal-derived gases will be completed during the ongoing Phase IA extension of this program.

  11. Calculation of parameters for inspection planning and evaluation: mixed-oxide fuel fabrication facilities

    SciTech Connect

    Reardon, P.T.; Mullen, M.F.

    1982-08-01

    As part of Task C.35 (Calculation of Parameters for Inspection Planning and Evaluation) of the US Program of Technical Assistance to IAEA Safeguards, Pacific Northwest Laboratory has performed some quantitative analyses of IAEA inspection activities for mixed-oxide fuel fabrication facilities. There were four distinct efforts involved in this task. These were as follows: show the effect on a material balance verification of using two variables measurement methods in some strata; perform additional calculations for the reference facility described in STR-89; modify the INSPECT computer programs to be used as an after-inspection analysis tool, as well as a preinspection planning tool; provide written comments and explantations of text and graphs of the first draft of STR-89, Safeguards Considerations for Mixed-Oxide Fuel Element Fabrication Facilities, by W. Bahm, T. Shea, and D. Tolchenkov, System Studies Section, IAEA.

  12. Fabrication and Testing of a Bi-Conductive Polymer Membrane Fuel Cell

    NASA Astrophysics Data System (ADS)

    Hamel, S.; Tsukamoto, T.; Tanaka, T.; Fréchette, L. G.

    2014-11-01

    This paper reports the fabrication process and testing of a bi-conductive polymer membrane (BCPM) fuel cell that integrates lateral current collectors on both sides with an ionic conductive path through the membrane. The new membrane shows major advantages over standard Nafion® membranes used in Polymer Electrolyte Fuel Cells (PEMFCs). In addition to being mechanically stable when wet, the flexible BCPM integrates efficient thin film current collectors (ICCs) on an ionic conductive membrane with a high active area ratio. Also, ICCs leave all the surface of the electrode free to eventually integrate a more efficient water and gas management system than traditional gas diffusion layers. Moreover, the fabricated membrane has shown superior volumetric power density than standard PEMFC (0.76 vs 0.47 mW/cm2μm).

  13. Hazard analysis for 300 Area N Reactor Fuel Fabrication and Storage Facilty

    SciTech Connect

    Johnson, D.J.; Brehm, J.R.

    1994-01-25

    This hazard analysis (HA) has been prepared for the 300 Area N Reactor Fuel Fabrication and Storage Facility (Facility), in compliance with the requirements of Westinghouse Hanford Company (Westinghouse Hanford) controlled manual WHC-CM-4-46, Nonreactor Facility Safety Analysis Manual, and to the direction of WHC-IP-0690, Safety Analysis and Regulation Desk Instructions, (WHC 1992). An HA identifies potentially hazardous conditions in a facility and the associated potential accident scenarios. Unlike the Facility hazard classification documented in WHC-SD-NR-HC-004, Hazard Classification for 300 Area N Reactor Fuel Fabrication and Storage Facility, (Huang 1993), which is based on unmitigated consequences, credit is taken in an HA for administrative controls or engineered safety features planned or in place. The HA is the foundation for the accident analysis. The significant event scenarios identified by this HA will be further evaluated in a subsequent accident analysis.

  14. High Accuracy Fuel Flowmeter, Phase 1

    NASA Technical Reports Server (NTRS)

    Mayer, C.; Rose, L.; Chan, A.; Chin, B.; Gregory, W.

    1983-01-01

    Technology related to aircraft fuel mass - flowmeters was reviewed to determine what flowmeter types could provide 0.25%-of-point accuracy over a 50 to one range in flowrates. Three types were selected and were further analyzed to determine what problem areas prevented them from meeting the high accuracy requirement, and what the further development needs were for each. A dual-turbine volumetric flowmeter with densi-viscometer and microprocessor compensation was selected for its relative simplicity and fast response time. An angular momentum type with a motor-driven, spring-restrained turbine and viscosity shroud was selected for its direct mass-flow output. This concept also employed a turbine for fast response and a microcomputer for accurate viscosity compensation. The third concept employed a vortex precession volumetric flowmeter and was selected for its unobtrusive design. Like the turbine flowmeter, it uses a densi-viscometer and microprocessor for density correction and accurate viscosity compensation.

  15. Design, fabrication, and test of lightweight shell structure, phase 2

    NASA Technical Reports Server (NTRS)

    1974-01-01

    A cylindrical shell skirt structure 4.57 m (180 in.) in diameter and 3.66 m (144 in.) high was subjected to a design and analysis study using a wide variety of structural materials and concepts. The design loading of 1225.8 N/cm (700 lb/in.) axial compression and 245.2 N/cm (140 lb/in.) torsion is representative of that expected on a typical space tug skirt section. Structural concepts evaluated included honeycomb sandwich, truss, isogrid, and skin/stringer/frame. The materials considered included a wide variety of structural metals as well as glass, graphite, and boron-reinforced composites. The most unique characteristic of the candidate designs is that they involve the use of very thin-gage material. Fabrication and structural test of small panels and components representative of many of the candidate designs served to demonstrate proposed fabrication techniques and to verify design and analysis methods.

  16. Mechanical properties and XRD studies of silicon carbide inert matrix fuel fabricated by a low temperature polymer precursor route

    NASA Astrophysics Data System (ADS)

    Shih, Chunghao; Rohbeck, Nadia; Gopalakrishnan, Karthik; Tulenko, James S.; Baney, Ronald H.

    2013-01-01

    The mechanical properties of silicon carbide (SiC) inert matrix fuel (IMF) pellets fabricated by a low temperature (1050 °C) polymer precursor route were evaluated at room temperature. The Vickers hardness was mainly related to the chemical bonding strength between the amorphous SiC phase and the β-SiC particles. The biaxial fracture strength with pre-notch and fracture toughness were found to be mostly controlled by the pellet density. The maximum Vickers hardness, biaxial fracture strength with pre-notch and fracture toughness achieved were 5.6 GPa, 201 MPa and 2.9 MPa m1/2 respectively. These values appear to be superior to the reference MOX or UO2 fuels. Excellent thermal shock resistance for the fabricated SiC IMF was proven and the values were compared to conventional UO2 pellets. XRD studies showed that ceria (PuO2 surrogate) chemically reacted with the polymer precursor during sintering, forming cerium oxysilicate. Whether PuO2 will chemically react in a similar manner remains unclear.

  17. Fabrication and Comparison of Fuels for Advanced Gas Reactor Irradiation Tests

    SciTech Connect

    Jeffrey Phillips; Charles Barnes; John Hunn

    2010-10-01

    As part of the program to demonstrate TRISO-coated fuel for the Next Generation Nuclear Plant, a series of irradiation tests of Advanced Gas Reactor (AGR) fuel are being performed in the Advanced Test Reactor (ATR) at the Idaho National Laboratory. In the first test, called “AGR-1,” graphite compacts containing approximately 300,000 coated particles were irradiated from December 2006 until November 2009. Development of AGR-1 fuel sought to replicate the properties of German TRISO-coated particles. No particle failures were seen in the nearly 3-year irradiation to a burn up of 19%. The AGR-1 particles were coated in a two-inch diameter coater. Following fabrication of AGR-1 fuel, process improvements and changes were made in each of the fabrication processes. Changes in the kernel fabrication process included replacing the carbon black powder feed with a surface-modified carbon slurry and shortening the sintering schedule. AGR-2 TRISO particles were produced in a six-inch diameter coater using a change size about twenty-one times that of the two-inch diameter coater used to coat AGR-1 particles. Changes were also made in the compacting process, including increasing the temperature and pressure of pressing and using a different type of press. Irradiation of AGR-2 fuel began in late spring 2010. Properties of AGR-2 fuel compare favorably with AGR-1 and historic German fuel. Kernels are more homogeneous in shape, chemistry and density. TRISO-particle sphericity, layer thickness standard deviations, and defect fractions are also comparable. In a sample of 317,000 particles from deconsolidated AGR-2 compacts, 3 exposed kernels were found in a leach test. No SiC defects were found in a sample of 250,000 deconsolidated particles, and no IPyC defects in a sample of 64,000 particles. The primary difference in properties between AGR-1 and AGR-2 compacts is that AGR-2 compacts have a higher matrix density, 1.6 g/cm3 compared to about 1.3 g/cm3 for AGR-1 compacts. Based on

  18. Paper-based membraneless hydrogen peroxide fuel cell prepared by micro-fabrication

    NASA Astrophysics Data System (ADS)

    Mousavi Ehteshami, Seyyed Mohsen; Asadnia, Mohsen; Tan, Swee Ngin; Chan, Siew Hwa

    2016-01-01

    A paper-based membraneless single-compartment hydrogen peroxide power source prepared by micro-electromechanical systems (MEMS) technology is reported. The cell utilizes hydrogen peroxide as both fuel and oxidant in a low volume cell fabricated on paper. The fabrication method used is a simple method where precise, small-sized patterns are produced which include the hydrophilic paper bounded by hydrophobic resin. Open circuit potentials of 0.61 V and 0.32 V are achieved for the cells fabricated with Prussian Blue as the cathode and aluminium/nickel as the anode materials, respectively. The power produced by the cells is 0.81 mW cm-2 at 0.26 V and 0.38 mW cm-2 at 0.14 V, respectively, even after the cell is bent or distorted. Such a fuel cell provides an easily fabricated, environmentally friendly, flexible and cost saving power source. The cell may be integrated within a self-sustained diagnostic system to provide the on-demand power for future bio-sensing applications.

  19. Method and device for fabricating dispersion fuel comprising fission product collection spaces

    SciTech Connect

    Shaber, Eric L; Fielding, Randall S

    2015-05-05

    A method of fabricating a nuclear fuel comprising a fissile material, one or more hollow microballoons, a phenolic resin, and metal matrix. The fissile material, phenolic resin and the one or more hollow microballoons are combined. The combined fissile material, phenolic resin and the hollow microballoons are heated sufficiently to form at least some fissile material carbides creating a nuclear fuel particle. The resulting nuclear fuel particle comprises one or more fission product collection spaces. In a preferred embodiment, the fissile material, phenolic resin and the one or more hollow microballoons are combined by forming the fissile material into microspheres. The fissile material microspheres are then overcoated with the phenolic resin and microballoon. In another preferred embodiment, the fissile material, phenolic resin and the one or more hollow microballoons are combined by overcoating the microballoon with the fissile material, and phenolic resin.

  20. Fuel Fabrication Capability WBS 01.02.01.05 - HIP Bonding Experiments Final Report

    SciTech Connect

    Dickerson, Patricia O'Donnell; Summa, Deborah Ann; Liu, Cheng; Tucker, Laura Arias; Chen, Ching-Fong; Aikin, Beverly; Aragon, Daniel Adrian; Beard, Timothy Vance; Montalvo, Joel Dwayne; Pena, Maria Isela; Dombrowski, David E.

    2015-06-10

    The goals of this project were to demonstrate reliable, reproducible solid state bonding of aluminum 6061 alloy plates together to encapsulate DU-10 wt% Mo surrogate fuel foils. This was done as part of the CONVERT Fuel Fabrication Capability effort in Process Baseline Development . Bonding was done using Hot Isotatic Pressing (HIP) of evacuated stainless steel cans (a.k.a HIP cans) containing fuel plate components and strongbacks. Gross macroscopic measurements of HIP cans prior to HIP and after HIP were used as part of this demonstration, and were used to determine the accuracy of a finitie element model of the HIP bonding process. The quality of the bonding was measured by controlled miniature bulge testing for Al-Al, Al-Zr, and Zr-DU bonds. A special objective was to determine if the HIP process consistently produces good quality bonding and to determine the best characterization techniques for technology transfer.

  1. Broad Specification Fuels Combustion Technology Program, Phase 2

    NASA Technical Reports Server (NTRS)

    Lohmann, R. P.; Jeroszko, R. A.; Kennedy, J. B.

    1990-01-01

    An experimental evaluation of two advanced technology combustor concepts was conducted to evolve and assess their capability for operation on broadened properties fuels. The concepts were based on the results of Phase 1 of the Broad Specification Fuel Combustor Technology Program which indicated that combustors with variable geometry or staged combustion zones had a flexibility of operation that could facilitate operation on these fuels. Emphasis in defining these concepts included the use of single pipe as opposed to duplex or staged fuels systems to avoid the risk of coking associated with the reduction in thermal stability expected in broadened properties fuels. The first concept was a variable geometry combustor in which the airflow into the primary zone could be altered through valves on the front while the second was an outgrowth of the staged Vorbix combustor, evolved under the NASA/P&W ECCP and EEE programs incorporating simplified fuel and air introduction. The results of the investigation, which involved the use of Experimental Referee Broad Specification (ERBS) fuel, indicated that in the form initially conceived, both of these combustor concepts were deficient in performance relative to many of the program goals for performance emissions. However, variations of both combustors were evaluated that incorporated features to simulate conceptual enhancement to demonstrate the long range potential of the combustor. In both cases, significant improvements relative to the program goals were observed.

  2. A study of the effect of fabrication variables on the void content and quality of fuel plates

    SciTech Connect

    Wiencek, T.C.

    1986-10-01

    The control of void content and quality of dispersion type fuel plates fabricated for research and test reactors are issues of concern to plate fabricators. These two variables were studied by examining the data for various geometries of fuel plates fabricated at ANL. It was found that the porosity of a fuel plate can be increased by: (1) decreasing the fuel particle size, (2) increasing the fuel particle surface roughness, (3) increasing the matrix strength, (4) decreasing the rolling temperature, (5) decreasing the final fuel zone thickness, and (6) increasing the volume percentage of the fuel. Porosity formation is controlled by bulk movement and deformation and/or fracture of particles. The most important factor is the flow stress of the matrix material. Lowering the flow stress will decrease the plate porosity. The percentage of plates with fuel-out-of-zone is a function of the fuel material and the loading. The highest percentage of plates with fuel-out-of-zone were those with U3Si2 which is at this time the most commonly used silicide fuel.

  3. Fabrication of defects in periodic photonic crystals using a phase only spatial light modulator

    NASA Astrophysics Data System (ADS)

    George, David; Lutkenhaus, Jeffrey; Arigong, Bayaner; Zhang, Hualiang; Philipose, Usha; Lin, Yuankun

    2014-03-01

    Here we present single exposure holographic fabrication of embedded defects in photonic crystal structures in a negative photoresist using a spatial light modulator (SLM). A phase pattern is engineered to form a desired interference pattern and displayed on a phase-only SLM. The resulting first order beams at the Fourier plane are used to recreate the interference pattern. Negative and positive defects are added to the photonic crystal in the following ways. A void-type defect is produced in two dimensional photonic crystal structures by replacing the phase of the engineered phase pattern with a constant value at the points where the defect is desired. And a positive bump defect can be made by allowing the zeroth order beam to interfere with the first order beams. Through these methods, it is possible to fabricate arbitrary shaped defect structures in photonic crystals through a single exposure process, thus improving cost effectiveness and simplifying the fabrication process of integrated photonics.

  4. Silicon Solar Cell Process Development, Fabrication and Analysis, Phase 1

    NASA Technical Reports Server (NTRS)

    Yoo, H. I.; Iles, P. A.; Tanner, D. P.

    1979-01-01

    Solar cells from RTR ribbons, EFG (RF and RH) ribbons, dendritic webs, Silso wafers, cast silicon by HEM, silicon on ceramic, and continuous Czochralski ingots were fabricated using a standard process typical of those used currently in the silicon solar cell industry. Back surface field (BSF) processing and other process modifications were included to give preliminary indications of possible improved performance. The parameters measured included open circuit voltage, short circuit current, curve fill factor, and conversion efficiency (all taken under AM0 illumination). Also measured for typical cells were spectral response, dark I-V characteristics, minority carrier diffusion length, and photoresponse by fine light spot scanning. the results were compared to the properties of cells made from conventional single crystalline Czochralski silicon with an emphasis on statistical evaluation. Limited efforts were made to identify growth defects which will influence solar cell performance.

  5. Fabrication and Testing of Full-Length Single-Cell Externally Fueled Converters for Thermionic Reactors

    SciTech Connect

    Schock, Alfred

    1994-06-01

    The preceding paper described designs and analyses of thermionic reactors employing full-core-length single-cell converters with their heated emitters located on the outside of their internally cooled collectors, and it presented results of detailed parametric analyses which illustrate the benefits of this unconventional design. The present paper describes the fabrication and testing of full-length prototypical converters, both unfueled and fueled, and presents parametric results of electrically heated tests. The unfueled converter tests demonstrated the practicality of operating such long converters without shorting across a 0.3-mm interelectrode gap. They produced a measured peak output of 751 watts(e) from a single diode and a peak efficiency of 15.4%. The fueled converter tests measured the parametric performance of prototypic UO(subscript 2)-fueled converters designed for subsequent in-pile testing. They employed revolver-shaped tungsten elements with a central emitter hole surrounded by six fuel chambers. The full-length converters were heated by a water-cooled RF-induction coil inside an ion-pumped vacuum chamber. This required development of high-vacuum coaxial RF feedthroughs. In-pile test rules required multiple containment of the UO (subscript 2)-fuel, which complicated the fabrication of the test article and required successful development of techniques for welding tungsten and other refractory components. The test measured a peak power output of 530 watts(e) or 7.1 watts/cm (superscript 2) at an efficiency of 11.5%. There are three copies in the file. Cross-Reference a copy FSC-ESD-217-94-529 in the ESD files with a CID #8574.

  6. Design and fabrication of miniaturized PEM fuel cell combined microreactor with self-regulated hydrogen mechanism

    NASA Astrophysics Data System (ADS)

    Balakrishnan, A.; Frei, M.; Kerzenmacher, S.; Reinecke, H.; Mueller, C.

    2015-12-01

    In this work we present the design and fabrication of the miniaturized PEM fuel cell combined microreactor system with hydrogen regulation mechanism and testing of prototype microreactor. The system consists of two components (i) fuel cell component and (ii) microreactor component. The fuel cell component represents the miniaturized PEM fuel cell system (combination of screen printed fuel cell assembly and an on-board hydrogen storage medium). Hydrogen production based on catalytic hydrolysis of chemical hydride takes place in the microreactor component. The self-regulated hydrogen mechanism based on the gaseous hydrogen produced from the catalytic hydrolysis of sodium borohydride (NaBH4) gets accumulated as bubbles at the vicinity of the hydrophobic coated hydrogen exhaust holes. When the built up hydrogen bubbles pressure exceeds the burst pressure at the hydrogen exhaust holes the bubble collapses. This collapse causes a surge of fresh NaBH4 solution onto the catalyst surface leading to the removal of the reaction by-products formed at the active sites of the catalyst. The catalyst used in the system is platinum deposited on a base substrate. Nickel foam, carbon porous medium (CPM) and ceramic plate were selected as candidates for base substrate for developing a robust catalyst surface. For the first time the platinum layer fabricated by pulsed electrodeposition and dealloying (EPDD) technique is used for hydrolysis of NaBH4. The major advantages of such platinum catalyst layers are its high surface area and their mechanical stability. Prototype microreactor system with self-regulated hydrogen mechanism is demonstrated.

  7. The reasons for the high power density of fuel cells fabricated with directly deposited membranes

    NASA Astrophysics Data System (ADS)

    Vierrath, Severin; Breitwieser, Matthias; Klingele, Matthias; Britton, Benjamin; Holdcroft, Steven; Zengerle, Roland; Thiele, Simon

    2016-09-01

    In a previous study, we reported that polymer electrolyte fuel cells prepared by direct membrane deposition (DMD) produced power densities in excess of 4 W/cm2. In this study, the underlying origins that give rise to these high power densities are investigated and reported. The membranes of high power, DMD-fabricated fuel cells are relatively thin (12 μm) compared to typical benchmark, commercially available membranes. Electrochemical impedance spectroscopy, at high current densities (2.2 A/cm2) reveals that mass transport resistance was half that of reference, catalyst-coated-membranes (CCM). This is attributed to an improved oxygen supply in the cathode catalyst layer by way of a reduced propensity of flooding, and which is facilitated by an enhancement in the back diffusion of water from cathode to anode through the thin directly deposited membrane. DMD-fabricated membrane-electrode-assemblies possess 50% reduction in ionic resistance (15 mΩcm2) compared to conventional CCMs, with contributions of 9 mΩcm2 for the membrane resistance and 6 mΩcm2 for the contact resistance of the membrane and catalyst layer ionomer. The improved mass transport is responsible for 90% of the increase in power density of the DMD fuel cell, while the reduced ionic resistance accounts for a 10% of the improvement.

  8. 10 CFR Appendix O to Part 110 - Illustrative List of Fuel Element Fabrication Plant Equipment and Components Under NRC's Export...

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 10 Energy 2 2013-01-01 2013-01-01 false Illustrative List of Fuel Element Fabrication Plant Equipment and Components Under NRC's Export Licensing Authority O Appendix O to Part 110 Energy NUCLEAR... the integrity of completed fuel pins (or rods). This item typically includes equipment for: (i)...

  9. 10 CFR Appendix O to Part 110 - Illustrative List of Fuel Element Fabrication Plant Equipment and Components Under NRC's Export...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 10 Energy 2 2011-01-01 2011-01-01 false Illustrative List of Fuel Element Fabrication Plant Equipment and Components Under NRC's Export Licensing Authority O Appendix O to Part 110 Energy NUCLEAR... the integrity of completed fuel pins (or rods). This item typically includes equipment for: (i)...

  10. 10 CFR Appendix O to Part 110 - Illustrative List of Fuel Element Fabrication Plant Equipment and Components Under NRC's Export...

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 10 Energy 2 2010-01-01 2010-01-01 false Illustrative List of Fuel Element Fabrication Plant Equipment and Components Under NRC's Export Licensing Authority O Appendix O to Part 110 Energy NUCLEAR... the integrity of completed fuel pins (or rods). This item typically includes equipment for: (i)...

  11. 10 CFR Appendix O to Part 110 - Illustrative List of Fuel Element Fabrication Plant Equipment and Components Under NRC's Export...

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 10 Energy 2 2014-01-01 2014-01-01 false Illustrative List of Fuel Element Fabrication Plant Equipment and Components Under NRC's Export Licensing Authority O Appendix O to Part 110 Energy NUCLEAR... the integrity of completed fuel pins (or rods). This item typically includes equipment for: (i)...

  12. 10 CFR Appendix O to Part 110 - Illustrative List of Fuel Element Fabrication Plant Equipment and Components Under NRC's Export...

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 10 Energy 2 2012-01-01 2012-01-01 false Illustrative List of Fuel Element Fabrication Plant Equipment and Components Under NRC's Export Licensing Authority O Appendix O to Part 110 Energy NUCLEAR... the integrity of completed fuel pins (or rods). This item typically includes equipment for: (i)...

  13. In-phase waves: Their behavior, internal stratification and fabric

    SciTech Connect

    Cheel, R.J. . Dept. of Earth Sciences); Udri, A. . Dept. of Geologie)

    1993-03-01

    Experiments were conducted in 0.305m wide, 9m long recirculating sediment flume on a bed of quartz sand (mean diameter of 0.18mm). The experiments included eight runs over the following range of conditions: 0.0605m [<=] depth [<=] 0.068m, 0.51m/s [<=] mean flow velocity [<=] 0.90m/s and 0.63 [<=] Froze Number (F) [<=] 1.1. For F < 0.83 dunes were the dominant bedform and these became longer and lower as F increased. At F = 0.83 the bed was nominally plane but locally and temporarily developed low in-phase waves or dunes. Post-run bed profiles showed symmetrical bedwaves with average length (L) of 0.26m and average height (H) of 0.005m. A complete cycle was characterized by: increased height of bed and water surface waves [r arrow] upstream migration [r arrow] breaking or decay [r arrow] planing of bed surface [r arrow] growth of new in-phase waves (initially migrating downstream and then remaining stationary during continued vertical growth). Each in-phase wave normally behaved independently of other waves although less commonly a breaking wave would trigger breaking of the next downstream wave. For F > 1.0 in-phase waves behaved as described above but a breaking wave would more commonly cause breaking of other waves. With increasing F it became more common for waves to break and rebuild quickly without complete planing of the bed surface. However, complete cycles occurred frequently with the following significant differences: (1) the upstream-migrating antidune developed upstream slopes that approached 25[degree]; (2) planing was accomplished by the rapid migration of a low, asymmetrical bedform through the antidune trough.

  14. Electrocatalytic activity of ordered intermetallic phases for fuel cell applications.

    PubMed

    Casado-Rivera, Emerilis; Volpe, David J; Alden, Laif; Lind, Cora; Downie, Craig; Vázquez-Alvarez, Terannie; Angelo, Antonio C D; DiSalvo, Francis J; Abruña, Héctor D

    2004-03-31

    The electrocatalytic activities of a wide range of ordered intermetallic phases toward a variety of potential fuels have been studied, and results have been compared to those of a pure polycrystalline platinum (Pt(pc)) electrode. A significant number of the ordered intermetallic phases exhibited enhanced electrocatalytic activity when compared to that of Pt, in terms of both oxidation onset potential and current density. The PtBi, PtIn, and PtPb ordered intermetallic phases appeared to be the most promising electrocatalysts tested thus far for fuel cell applications. PtPb, in particular, showed an onset potential that was 100 mV less positive and a peak current density approximately 40 times higher than those observed for Pt in the case of methanol oxidation. The ability to control the geometric and electronic structures of the electrocatalytic material by using ordered intermetallic phases has been shown to be a promising direction of inquiry in the search for superior electrocatalysts for fuel cell applications. PMID:15038758

  15. Fabrication and microstructure characterization of inert matrix fuel based on yttria stabilized zirconia

    NASA Astrophysics Data System (ADS)

    Hellwig, Ch.; Pouchon, M.; Restani, R.; Ingold, F.; Bart, G.

    2005-04-01

    The deployment of a suitable, Pu-bearing inert matrix fuel (IMF) could offer an attractive option as a single-recycling LWR strategy aimed at reducing the currently growing plutonium stockpiles. A development programme focusing on yttria stabilized zirconia (YSZ)-based IMF is conducted at PSI. YSZ-based IMF has so far been irradiated in two test reactors. The fabrication routes as well as the characterization of the irradiated material by ceramography, electronprobe microanalysis, and X-ray diffraction are presented. IMF fabrication by attrition milling of the oxide constituents is possible, but high sintering temperatures are required to achieve homogeneity. X-ray diffraction is a suitable tool to monitor the homogeneity. Extra efforts are needed to increase the density.

  16. Key Differences in the Fabrication, Irradiation, and Safety Testing of U.S. and German TRISO-coated Particle Fuel and Their Implications on Fuel Performance

    SciTech Connect

    Petti, David Andrew; Maki, John Thomas; Buongiorno, Jacopo; Hobbins, Richard Redfield

    2002-06-01

    High temperature gas reactor technology is achieving a renaissance around the world. This technology relies on high quality production and performance of coated particle fuel. Historically, the irradiation performance of TRISO-coated gas reactor particle fuel in Germany has been superior to that in the United States. German fuel generally displayed in-pile gas release values that were three orders of magnitude lower than U.S. fuel. Thus, we have critically examined the TRISO-coated fuel fabrication processes in the U.S. and Germany and the associated irradiation database with a goal of understanding why the German fuel behaves acceptably, why the U.S. fuel has not faired as well, and what process/ production parameters impart the reliable performance to this fuel form. The postirradiation examination results are also reviewed to identify failure mechanisms that may be the cause of the poorer U.S. irradiation performance. This comparison will help determine the roles that particle fuel process/product attributes and irradiation conditions (burnup, fast neutron fluence, temperature, and degree of acceleration) have on the behavior of the fuel during irradiation and provide a more quantitative linkage between acceptable processing parameters, as-fabricated fuel properties and subsequent in-reactor performance.

  17. Microstructural characterization of a thin film ZrN diffusion barrier in an As-fabricated U–7Mo/Al matrix dispersion fuel plate

    SciTech Connect

    Keiser, Dennis D.; Perez, Emmanuel; Wiencek, Tom; Leenaers, Ann; Van den Berghe, Sven

    2015-03-01

    The United States High Performance Research Reactor Fuel Development program is developing low enriched uranium fuels for application in research and test reactors. One concept utilizes U–7 wt.% Mo (U–7Mo) fuel particles dispersed in Al matrix, where the fuel particles are coated with a 1 μm-thick ZrN coating. The ZrN serves as a diffusion barrier to eliminate a deleterious reaction that can occur between U–7Mo and Al when a dispersion fuel is irradiated under aggressive reactor conditions. To investigate the final microstructure of a physically-vapor-deposited ZrN coating in a dispersion fuel plate after it was fabricated using a rolling process, characterization samples were taken from a fuel plate that was fabricated at 500 °C using ZrN-coated U–7Mo particles, Al matrix and AA6061 cladding. Scanning electron and transmission electron microscopy analysis were performed. Data from these analyses will be used to support future microstructural examinations of irradiated fuel plates, in terms of understanding the effects of irradiation on the ZrN microstructure, and to determine the role of diffusion barrier microstructure in eliminating fuel/matrix interactions during irradiation. The as-fabricated coating was determined to be cubic-ZrN (cF8) phase. It exhibited a columnar microstructure comprised of nanometer-sized grains and a region of relatively high porosity, mainly near the Al matrix. Small impurity-containing phases were observed at the U–7Mo/ZrN interface, and no interaction zone was observed at the ZrN/Al interface. The bonding between the U–7Mo and ZrN appeared to be mechanical in nature. A relatively high level of oxygen was observed in the ZrN coating, extending from the Al matrix in the ZrN coating in decreasing concentration. The above microstructural characteristics are discussed in terms of what may be most optimal for a diffusion barrier in a dispersion fuel plate application.

  18. Microstructural characterization of a thin film ZrN diffusion barrier in an As-fabricated U-7Mo/Al matrix dispersion fuel plate

    NASA Astrophysics Data System (ADS)

    Keiser, Dennis D.; Perez, Emmanuel; Wiencek, Tom; Leenaers, Ann; Van den Berghe, Sven

    2015-03-01

    The United States High Performance Research Reactor Fuel Development program is developing low enriched uranium fuels for application in research and test reactors. One concept utilizes U-7 wt.% Mo (U-7Mo) fuel particles dispersed in Al matrix, where the fuel particles are coated with a 1 μm-thick ZrN coating. The ZrN serves as a diffusion barrier to eliminate a deleterious reaction that can occur between U-7Mo and Al when a dispersion fuel is irradiated under aggressive reactor conditions. To investigate the final microstructure of a physically-vapor-deposited ZrN coating in a dispersion fuel plate after it was fabricated using a rolling process, characterization samples were taken from a fuel plate that was fabricated at 500 °C using ZrN-coated U-7Mo particles, Al matrix and AA6061 cladding. Scanning electron and transmission electron microscopy analysis were performed. Data from these analyses will be used to support future microstructural examinations of irradiated fuel plates, in terms of understanding the effects of irradiation on the ZrN microstructure, and to determine the role of diffusion barrier microstructure in eliminating fuel/matrix interactions during irradiation. The as-fabricated coating was determined to be cubic-ZrN (cF8) phase. It exhibited a columnar microstructure comprised of nanometer-sized grains and a region of relatively high porosity, mainly near the Al matrix. Small impurity-containing phases were observed at the U-7Mo/ZrN interface, and no interaction zone was observed at the ZrN/Al interface. The bonding between the U-7Mo and ZrN appeared to be mechanical in nature. A relatively high level of oxygen was observed in the ZrN coating, extending from the Al matrix in the ZrN coating in decreasing concentration. The above microstructural characteristics are discussed in terms of what may be most optimal for a diffusion barrier in a dispersion fuel plate application.

  19. Fabrication and characterization of americium, neptunium and curium bearing MOX fuels obtained by powder metallurgy process

    NASA Astrophysics Data System (ADS)

    Lebreton, Florent; Prieur, Damien; Jankowiak, Aurélien; Tribet, Magaly; Leorier, Caroline; Delahaye, Thibaud; Donnet, Louis; Dehaudt, Philippe

    2012-01-01

    MOX fuel pellets containing up to 1.4 wt% of Minor Actinides (MA), i.e. Am, Np and Cm, were fabricated to demonstrate the technical feasibility of powder metallurgy process involving, pelletizing and sintering in controlled atmosphere. The compounds were then characterized using XRD, SEM and EDX/EPMA. Dense pellets were obtained which closed porosity mean size is equal to 7 μm. The results indicate the formation of (U, Pu)O 2 solid solution. However, microstructure contains some isolated UO 2 grains. The distribution of Am and Cm appears to be homogeneous whereas Np was found to be clustered at some locations.

  20. Fabrication of optical multilayer for two-color phase plate in super-resolution microscope

    NASA Astrophysics Data System (ADS)

    Iketaki, Yoshinori; Kitagawa, Katsuichi; Hidaka, Kohjiro; Kato, Naoki; Hirabayashi, Akira; Bokor, Nandor

    2014-07-01

    In super-resolution microscopy based on fluorescence depletion, the two-color phase plate (TPP) is an indispensable optical element, which can independently control the phase shifts for two beams of different color, i.e., the pump and erase beams. By controlling a phase shift of the erase beam through the TPP, the erase beam can be modulated into a doughnut shape, while the pump beam maintains the initial Gaussian shape. To obtain a reliable optical multiplayer (ML) for the TPP, we designed a ML with only two optical layers by performing numerical optimization. The measured phase shifts generated by the fabricated ML using interferometry correspond to the design values. The beam profiles in the focal plane are also consistent with theoretical results. Although the fabricated ML consists of only two optical layers, the ML can provide a suitable phase modulation function for the TPP in a practical super-resolution microscope.

  1. Fabrication of optical multilayer for two-color phase plate in super-resolution microscope

    SciTech Connect

    Iketaki, Yoshinori; Kitagawa, Katsuichi; Hidaka, Kohjiro; Kato, Naoki; Hirabayashi, Akira; Bokor, Nandor

    2014-07-15

    In super-resolution microscopy based on fluorescence depletion, the two-color phase plate (TPP) is an indispensable optical element, which can independently control the phase shifts for two beams of different color, i.e., the pump and erase beams. By controlling a phase shift of the erase beam through the TPP, the erase beam can be modulated into a doughnut shape, while the pump beam maintains the initial Gaussian shape. To obtain a reliable optical multiplayer (ML) for the TPP, we designed a ML with only two optical layers by performing numerical optimization. The measured phase shifts generated by the fabricated ML using interferometry correspond to the design values. The beam profiles in the focal plane are also consistent with theoretical results. Although the fabricated ML consists of only two optical layers, the ML can provide a suitable phase modulation function for the TPP in a practical super-resolution microscope.

  2. Operational comparison of TLD albedo dosemeters and solid state nuclear tracks detectors in fuel fabrication facilities.

    PubMed

    Tsujimura, N; Takada, C; Yoshida, T; Momose, T

    2007-01-01

    The authors carried out an operational study that compared the use of TLD albedo dosemeters and solid state nuclear tracks detector in plutonium environments of Japan Nuclear Cycle Development Institute, Tokai Works. A selected group of workers engaged in the fabrication process of MOX (Plutonium-Uranium mixed oxide) fuel wore both TLD albedo dosemeters and solid state nuclear tracks detectors. The TL readings were generally proportional to the counted etch-pits, and thus the dose equivalent results obtained from TLD albedo dosemeter agreed with those from solid state nuclear tracks detector within a factor of 1.5. This result indicates that, in the workplaces of the MOX fuel plants, the neutron spectrum remained almost constant in terms of time and space, and the appropriate range of field-specific correction with spectrum variations was small in albedo dosimetry. PMID:17337735

  3. Submicrometer photonic structure fabrication by phase spatial-light-modulator-based interference lithography.

    PubMed

    Behera, Saraswati; Kumar, Manish; Joseph, Joby

    2016-04-15

    We present a large-area and single-step fabrication approach based on phase spatial light modulator (SLM)-assisted interference lithography for the realization of submicrometer photonic structures on photoresist. A multimirror beam steering unit is used to reflect the SLM-generated phase-engineered beams leading to a large angle between interfering beams while also preserving the large area of the interfering plane beams. Both translational and rotational periodic submicrometer structures are experimentally realized. This approach increases the flexibility of interference lithography to fabricate more complex submicrometer photonic structures and photonic metamaterial structures for future applications. PMID:27082372

  4. Fabrication of protic ionic liquid/sulfonated polyimide composite membranes for non-humidified fuel cells

    NASA Astrophysics Data System (ADS)

    Lee, Seung-Yul; Yasuda, Tomohiro; Watanabe, Masayoshi

    We have demonstrated that a protic ionic liquid, diethylmethylammonium trifluoromethanesulfonate ([dema][TfO]) functions as a proton conductor and is suitable for use as an electrolyte in H 2/O 2 fuel cells, which can be operated at temperatures higher than 100 °C under non-humidified conditions. In this study, in order to fabricate a polymer electrolyte fuel cell, matrix polymers for [dema][TfO] are explored and sulfonated polyimides (SPI), in which the sulfonic acid groups are in diethylmethylammonium form, are found to be highly compatible with [dema][TfO]. Polymer electrolyte membranes for non-humidified fuel cells are prepared by the solvent casting method using SPI and [dema][TfO]. The SPI, with an ion exchange capacity of 2.27 meq g -1, can retain four times its own weight of [dema][TfO] and produces uniform, tough, and transparent composite membranes. The composite membranes have good thermal stability (>300 °C) and ionic conductivity (>10 -2 S cm -1 at 120 °C when the [dema][TfO] content is higher than 67 wt%) under anhydrous conditions. In the H 2/O 2 fuel cell operation using a composite membrane without humidification, a current density higher than 240 mA cm -2 is achieved with a maximum power density of 100 mW cm -2 at 80 °C.

  5. The FUTURIX-FTA experiment in Phenix: status of oxides fuels fabrication

    SciTech Connect

    Jorion, F.; Donnet, L.

    2007-07-01

    Eliminating long-lived radionuclides by transmuting them into nonradioactive or short-lived nuclei is a reference approach in nuclear waste management. FUTURIX/FTA (FUels for Transmutation of transuranium elements in Phenix / Fortes Teneurs en Actinides [high actinide content]) is an international program intended to demonstrate the technical feasibility, primarily with regard to fuel behavior, of transmuting minor actinides in fast neutron reactors. This research is carried out in collaboration with the US Department of Energy (DOE), the Japan Atomic Energy Research Institute (JAERI), the Institute for Transuranium Elements (ITU) in Germany, and the Commissariat a l'Energie Atomique (CEA) in France. In this context, the CEA investigated four ceramic/ceramic (cercer) compositions ((Pu{sub 0.5}Am{sub 0.5})O{sub 2-x} + 80 vol% MgO), (Pu{sub 0.5}Am{sub 0.5})O{sub 2-x} + 70 vol% MgO), (Pu{sub 0.2}Am{sub 0.8})O{sub 2-x} + 75 vol% MgO), (Pu{sub 0.2}Am{sub 0.8})O{sub 2-x} + 65 vol% MgO) and fabricated two fuel pins. The mixed actinide oxides were synthesized by oxalate co-conversion and incorporated into a magnesia matrix by classical powder metallurgy. The resulting fuel pellets were subjected to chemical, dimensional, structural and microstructural characterization. The results for each composition were interpreted and compared. (authors)

  6. DIRECT INVESTIGATIONS OF THE IMMOBILIZATION OF RADIONUCLIDES IN THE ALTERATION PHASES OF SPENT NUCLEAR FUEL

    EPA Science Inventory

    DOE is the custodian of several thousand tons of spent nuclear fuel that is intended for geological disposal. The direct disposal of spent nuclear fuel or of mixed oxide fuel (fabricated for the disposal of excess weapons plutonium) requires a careful analysis of the role of spen...

  7. Design, Fabrication and Prototype testing of a Chip Integrated Micro PEM Fuel Cell Accumulator combined On-Board Range Extender

    NASA Astrophysics Data System (ADS)

    Balakrishnan, A.; Mueller, C.; Reinecke, H.

    2014-11-01

    In this work we present the design, fabrication and prototype testing of Chip Integrated Micro PEM Fuel Cell Accumulator (CIμ-PFCA) combined On-Board Range Extender (O-BRE). CIμ-PFCA is silicon based micro-PEM fuel cell system with an integrated hydrogen storage feature (palladium metal hydride), the run time of CIμ-PFCA is dependent on the stored hydrogen, and in order to extend its run time an O-BRE is realized (catalytic hydrolysis of chemical hydride, NaBH4. Combining the CIμ-PFCA and O-BRE on a system level have few important design requirements to be considered; hydrogen regulation, gas -liquid separator between the CIμ-PFCA and the O-RE. The usage of traditional techniques to regulate hydrogen (tubes), gas-liquid phase membranes (porous membrane separators) are less desirable in the micro domain, due to its space constraint. Our approach is to use a passive hydrogen regulation and gas-liquid phase separation concept; to use palladium membrane. Palladium regulates hydrogen by concentration diffusion, and its property to selectively adsorb only hydrogen is used as a passive gas-liquid phase separator. Proof of concept is shown by realizing a prototype system. The system is an assembly of CIμ-PFCA, palladium membrane and the O-BRE. The CIμ-PFCA consist of 2 individually processed silicon chips, copper supported palladium membrane realized by electroplating followed by high temperature annealing process under inter atmosphere and the O-BRE is realized out of a polymer substrate by micromilling process with platinum coated structures, which functions as a catalyst for the hydrolysis of NaBH4. The functionality of the assembled prototype system is demonstrated by the measuring a unit cell (area 1 mm2) when driven by the catalytic hydrolysis of chemical hydride (NaBH4 and the prototype system shows run time more than 15 hours.

  8. A new method for measuring the thermal regulatory properties of phase change material (PCM) fabrics

    NASA Astrophysics Data System (ADS)

    Wan, X.; Fan, J.

    2009-02-01

    Several methods already exist for the measurement of the thermal regulatory properties of fabrics containing phase change materials (PCMs). However, they do not adequately simulate the actual use condition; consequently the measurements may not have relevance to the performance of PCM fabrics in actual use. Here we report on the development of a new method, which better simulates the real use situation. In this method, a hot plate, simulating the human body, generates a constant amount of heat depending on the type of human activity to be simulated. The hot plate covered by the PCM fabric is then exposed to a thermal transient simulating a wearer moving from one thermal environment to another; the changes of surface temperature and heat loss of the hot plate are then recorded and used to characterize the thermal regulatory properties of the PCM fabrics.

  9. Fabrication

    NASA Technical Reports Server (NTRS)

    Angel, Roger; Helms, Richard; Bilbro, Jim; Brown, Norman; Eng, Sverre; Hinman, Steve; Hull-Allen, Greg; Jacobs, Stephen; Keim, Robert; Ulmer, Melville

    1992-01-01

    What aspects of optical fabrication technology need to be developed so as to facilitate existing planned missions, or enable new ones? Throughout the submillimeter to UV wavelengths, the common goal is to push technology to the limits to make the largest possible apertures that are diffraction limited. At any one wavelength, the accuracy of the surface must be better than lambda/30 (rms error). The wavelength range is huge, covering four orders of magnitude from 1 mm to 100 nm. At the longer wavelengths, diffraction limited surfaces can be shaped with relatively crude techniques. The challenge in their fabrication is to make as large as possible a reflector, given the weight and volume constraints of the launch vehicle. The limited cargo diameter of the shuttle has led in the past to emphasis on deployable or erectable concepts such as the Large Deployable Reflector (LDR), which was studied by NASA for a submillimeter astrophysics mission. Replication techniques that can be used to produce light, low-cost reflecting panels are of great interest for this class of mission. At shorter wavelengths, in the optical and ultraviolet, optical fabrication will tax to the limit the most refined polishing methods. Methods of mechanical and thermal stabilization of the substrate will be severely stressed. In the thermal infrared, the need for large aperture is tempered by the even stronger need to control the telescope's thermal emission by cooled or cryogenic operation. Thus, the SIRTF mirror at 1 meter is not large and does not require unusually high accuracy, but the fabrication process must produce a mirror that is the right shape at a temperature of 4 K. Future large cooled mirrors will present more severe problems, especially if they must also be accurate enough to work at optical wavelengths. At the very shortest wavelengths accessible to reflecting optics, in the x-ray domain, the very low count fluxes of high energy photons place a premium on the collecting area. It is

  10. Release and disposal of materials during decommissioning of Siemens MOX fuel fabrication plant at Hanau, Germany

    SciTech Connect

    Koenig, Werner; Baumann, Roland

    2007-07-01

    In September 2006, decommissioning and dismantling of the Siemens MOX Fuel Fabrication Plant in Hanau were completed. The process equipment and the fabrication buildings were completely decommissioned and dismantled. The other buildings were emptied in whole or in part, although they were not demolished. Overall, the decommissioning process produced approximately 8500 Mg of radioactive waste (including inactive matrix material); clearance measurements were also performed for approximately 5400 Mg of material covering a wide range of types. All the equipment in which nuclear fuels had been handled was disposed of as radioactive waste. The radioactive waste was conditioned on the basis of the requirements specified for the projected German final disposal site 'Schachtanlage Konrad'. During the pre-conditioning, familiar processes such as incineration, compacting and melting were used. It has been shown that on account of consistently applied activity containment (barrier concept) during operation and dismantling, there has been no significant unexpected contamination of the plant. Therefore almost all the materials that were not a priori destined for radioactive waste were released without restriction on the basis of the applicable legal regulations (chap. 29 of the Radiation Protection Ordinance), along with the buildings and the plant site. (authors)

  11. Fabrication processes of MEMS phase shifters on polymer-based substrates

    NASA Astrophysics Data System (ADS)

    Wang, Jianqun; Ativanichayaphong, Thermpon; Cai, Ying; Huang, Wen-Ding; Hsu, Lun-Chen; Davis, W. Alan; Chiao, Mu; Chiao, J.-C.

    2006-12-01

    RF phase shifters find wide applications in telecommunications, satellite systems, personal wireless communication systems, radar systems, tracking systems, and sensors. They have been conventionally manufactured by semiconductor technologies which suffer from high insertion losses due to high RF series resistances. They are expensive due to fabrication and assembly costs. The RF MEMS phase shifters provide low insertion losses, low fabrication costs and high linearity compared with the semiconductor ones. Furthermore, polymer materials have demonstrated low material costs and low RF attenuations. In this work, we proposed to build RF MEMS phase shifters on polymer substrates. The proposed devices were successfully manufactured and tested from DC to 26 GHz. Our experimental results indicated more than 35 degrees phase shifts and low insertion losses.

  12. Fabrication and Testing of Binary-Phase Fourier Gratings for Nonuniform Array Generation

    NASA Technical Reports Server (NTRS)

    Keys, Andrew S.; Crow, Robert W.; Ashley, Paul R.; Nelson, Tom R., Jr.; Parker, Jack H.; Beecher, Elizabeth A.

    2004-01-01

    This effort describes the fabrication and testing of binary-phase Fourier gratings designed to generate an incoherent array of output source points with nonuniform user-defined intensities, symmetric about the zeroth order. Like Dammann fanout gratings, these binary-phase Fourier gratings employ only two phase levels to generate a defined output array. Unlike Dammann fanout gratings, these gratings generate an array of nonuniform, user-defined intensities when projected into the far-field regime. The paper describes the process of design, fabrication, and testing for two different version of the binary-phase grating; one designed for a 12 micron wavelength, referred to as the Long-Wavelength Infrared (LWIR) grating, and one designed for a 5 micron wavelength, referred to as the Mid-Wavelength Infrared Grating (MWIR).

  13. Fabrication of microchannels by space-selective control of phase separation in glass.

    PubMed

    Yu, Yongze; Chen, Yeqin; Chen, Jiejie; Lv, Shichao; Feng, Xu; Qi, Yuzhong; Qiu, Jianrong; Zhou, Shifeng

    2016-07-15

    Microchannels have important scientific applications in many fields, because they enable precise control, manipulation, and analysis of fluid on a micrometer scale. Herein, we demonstrate an effective strategy for fabrication of microchannels, based on the space-selective phase separation in glass induced by a femtosecond laser. The proposed method shows its abilities in fabrication of three-dimensional microchannels with ∼5  mm length scale and a uniform cross section. Moreover, we also achieve the modulation of the morphology on the inner surface of microchannels by using objective lenses with various numerical-apertures. The physical mechanism of the phase separation and microstructure evolution is discussed. Our method provides new opportunities to fabricate microchannels with complex structures and multifunctional integration. PMID:27420538

  14. Fabrication of UO/sub 2/-stainless steel fuel for a fast-reactor safety test

    SciTech Connect

    Rhude, H.V.; O'Keefe, G.B.; Noland, R.A.

    1983-01-01

    As part of its fast breeder reactor (LMFBR) safety research program, Argonne National Laboratory is conducting a series of tests in the TREAT Reactor to clarify the boilup and freezing behavior of UO/sub 2/ fuel and stainless steel in the transition phase of an accident sequence. Although much work has been done on UO/sub 2/ dispersed in a stainless steel matrix, no references could be found on work relating to the dispersal of stainless steel in a UO/sub 2/ matrix. Consequently a development program was started to produce the necessary fuel. The major difficulty encountered is attributable to the melting range of 316 stainless steel (1391 to 1399/sup 0/C) which is well below the normal sintering temperature of UO/sub 2/ (1750/sup 0/C). Attempts to produce the required fuel pellets by standard sintering techniques did not work. Alternative approaches to sintering were investigated to determine the density achievable without sintering.

  15. Application for approval for construction of the Fueled Clad Fabrication System, the Radioisotope Power Systems Facility, and the Fuel Assembly Area

    SciTech Connect

    Not Available

    1989-08-01

    The following ''Application for Approval of Construction'' is being submitted by the US Department of Energy-Richland Operations Office, pursuant to 40 CFR 61.07, for three new sources of airborne radionuclide emissions at the Hanford Site in Washington State. The three new sources, the Fueled Clad Fabrication System (FCFS), the Radioisotope Power Systems Facility (RPSF), and the Fuel Assembly Area (FAA), will be located in one facility, the Fuels and Materials Examination Facility (FMEF) of the 400 Area. The FMEF was originally designed to provide for post-irradiation examination and fabrication of breeder reactor fuels. These FMEF missions were canceled before the introduction of any fuel materials or any irradiated material. The current plans are to use the facility to fabricate power supplies to be used in space applications and to produce Fast Flux Test Facility (FFTF) fuel and target assemblies. The FCFS and the RPSF will produce materials and assemblies for application in space. The FAA project will produce FFTF fuel and target assemblies. The FCFS and the RPSF will share the same building and stack and, in certain cases, the same floor space. Given this relationship, these systems will be dealt with separately to the extent possible. The FAA is a comparatively independent operation though it will share the FMEF complex. 2 refs., 16 figs., 12 tabs.

  16. Supplemental information for a notice of construction for the Fueled Clad Fabrication System, the Radioisotope Power Systems Facility, and the Fuel Assembly Area

    SciTech Connect

    Not Available

    1989-08-01

    This ''Notice of Construction'' has been submitted by the US Department of Energy-Richland Operations Office (P.O. Box 550, Richland, Washington 99352), pursuant to WAC 402-80-070, for three new sources of radionuclide emissions at the Hanford Site in Washington State (Figure 1). The three new sources, the Fueled Clad Fabrication System (FCFS) the Radioisotope Power Systems Facility (RPSF) and the Fuel Assembly Area (FAA) will be located in one facility, the Fuels and materials Examination Facility (FMEF) of the 400 Area. The FMEF was originally designed to provide for post- irradiation examination and fabrication of breeder reactor fuels. These FMEF missions were cancelled before the introduction of any fuel materials or any irradiated material. The current plans are to use the facility to fabricate power supplies to be used in space applications and to produce Fast Flux Test Facility (FFTF) fuel and target assemblies. The FCFS and the RPSF will produce materials and assemblies for application in space. The FAA project will produce FFTF fuel and target assemblies. The FCFS and the RPSF will share the same building, stack, and, in certain cases, the same floor space. Given this relationship, to the extent possible, these systems will be dealt with separately. The FAA is a comparatively independent operation though it will share the FMEF complex.

  17. Prevention of significant deterioration permit application for the Fueled Clad Fabrication System, the Radioisotope Power Systems Facility, and the Fuel Assembly Area

    SciTech Connect

    Not Available

    1989-08-01

    This New Source Review'' has been submitted by the US Department of Energy-Richland Operations Office (PO Box 550, Richland, Washington 99352), pursuant to WAC 173-403-050 and in compliance with the Department of Ecology Guide to Processing A Prevention Of Significant Deterioration (PSD) Permit'' for three new sources of radionuclide emissions at the Hanford Site in Washington State. The three new sources, the Fueled Clad Fabrication System (FCFS), the Radioisotope Power Systems Facility (RPSF), and the Fuel Assembly Area (FAA), will be located in one facility, the Fuels and Materials Examination Facility (FMEF) of the 400 Area. The FMEF was originally designed to provide for post-irradiation examination and fabrication of breeder reactor fuels. These FMEF missions were cancelled before the introduction of any fuel materials or any irradiated material. The current plans are to use the facility to fabricate power supplies for use in space applications and to produce Fast Flux Test Facility (FFTF) fuel and target assemblies. The FCFS and the RPSF will produce materials and assemblies for application in space. The FAA project will produce FFTF fuel and target assemblies. The FCFS and the RPSF will share the same building, stack, and, in certain cases, the same floor space. Given this relationship, these systems will be dealt with separately to the extent possible. The FAA is a comparatively independent operation though it will share the FMEF complex.

  18. Fabric phase sorptive extraction: Two practical sample pretreatment techniques for brominated flame retardants in water.

    PubMed

    Huang, Guiqi; Dong, Sheying; Zhang, Mengfei; Zhang, Haihan; Huang, Tinglin

    2016-09-15

    Sample pretreatment is the critical section for residue monitoring of hazardous pollutants. In this paper, using the cellulose fabric as host matrix, three extraction sorbents such as poly (tetrahydrofuran) (PTHF), poly (ethylene glycol) (PEG) and poly (dimethyldiphenylsiloxane) (PDMDPS), were prepared on the surface of the cellulose fabric. Two practical extraction techniques including stir bar fabric phase sorptive extraction (stir bar-FPSE) and magnetic stir fabric phase sorptive extraction (magnetic stir-FPSE) have been designed, which allow stirring of fabric phase sorbent during the whole extraction process. In the meantime, three brominated flame retardants (BFRs) [tetrabromobisphenol A (TBBPA), tetrabromobisphenol A bisallylether (TBBPA-BAE), tetrabromobisphenol A bis(2,3-dibromopropyl)ether (TBBPA-BDBPE)] in the water sample were selected as model analytes for the practical evaluation of the proposed two techniques using high-performance liquid chromatography (HPLC). Moreover, various experimental conditions affecting extraction process such as the type of fabric phase, extraction time, the amount of salt and elution conditions were also investigated. Due to the large sorbent loading capacity and unique stirring performance, both techniques possessed high extraction capability and fast extraction equilibrium. Under the optimized conditions, high recoveries (90-99%) and low limits of detection (LODs) (0.01-0.05 μg L(-1)) were achieved. In addition, the reproducibility was obtained by evaluating the intraday and interday precisions with relative standard deviations (RSDs) less than 5.1% and 6.8%, respectively. The results indicated that two pretreatment techniques were promising and practical for monitoring of hazardous pollutants in the water sample. Due to low solvent consumption and high repeated use performance, proposed techniques also could meet green analytical criteria. PMID:27300591

  19. Fabrication of Janus droplets by evaporation driven liquid-liquid phase separation.

    PubMed

    Zhang, Qingquan; Xu, Meng; Liu, Xiaojun; Zhao, Wenfeng; Zong, Chenghua; Yu, Yang; Wang, Qi; Gai, Hongwei

    2016-04-11

    We present a universal and scalable method to fabricate Janus droplets based on evaporation driven liquid-liquid phase separation. In this work, the morphologies and chemical properties of separate parts of the Janus droplets can be flexibly regulated, and more complex Janus droplets (such as core-shell Janus droplets, ternary Janus droplets, and multiple Janus droplets) can be constructed easily. PMID:26983706

  20. Granulation and infiltration processes for the fabrication of minor actinide fuels, targets and conditioning matrices

    NASA Astrophysics Data System (ADS)

    Nästren, C.; Fernandez, A.; Haas, D.; Somers, J.; Walter, M.

    2007-05-01

    The impact of Pu and Am, two elements that potentially pose a long term hazard for the disposal of spent nuclear fuel, can be abated by their reintroduction into the fuel cycle for transmutation. Such transmutation targets can be fabricated by a sol gel method for the production of porous inactive beads, which are then infiltrated by Am solutions. Following calcination, compaction into pellets and sintering, the product is obtained. At its heart, the sol gel process relies on an ammonia precipitation, so that it is not universally applicable. Therefore, an alternative is sought not just to overcome this chemical limitation, but also to simplify the process and reduce waste streams. The new concept utilises powder metallurgy routes (compaction, crushing and sieving) to produce porous, almost, dust free granules, which are infiltrated with the actinide nitrate. The method has been developed using yttria stabilised zirconia and alumina, and has been demonstrated for the production of Al2O3-AmO2 targets for neutron capture investigations. The results are very promising and meet light water reactor fuel specifications. In addition, the process is ideally suited for the production of ceramic matrices for conditioning actinides for geological disposal.

  1. International safeguards for a modern MOX (mixed-oxide) fuel fabrication facility

    SciTech Connect

    Pillay, K.K.S.; Stirpe, D.; Picard, R.R.

    1987-03-01

    Bulk-handling facilities that process plutonium for commercial fuel cycles offer considerable challenges to nuclear materials safeguards. Modern fuel fabrication facilities that handle mixed oxides of plutonium and uranium (MOX) often have large inventories of special nuclear materials in their process lines and in storage areas for feed and product materials. In addition, the remote automated processing prevalent at new MOX facilities, which is necessary to minimize radiation exposures to personnel, tends to limit access for measurements and inspections. The facility design considered in this study incorporates all these features as well as state-of-the-art measurement technologies for materials accounting. Key elements of International Atomic Energy Agency (IAEA) safeguards for such a fuel-cycle facility have been identified in this report, and several issues of primary importance to materials accountancy and IAEA verifications have been examined. We have calculated detection sensitivities for abrupt and protracted diversions of plutonium assuming a single materials balance area for all processing areas. To help achieve optimal use of limited IAEA inspection resources, we have calculated sampling plans for attributes/variables verification. In addition, we have demonstrated the usefulness of calculating sigma/sub (MUF-D)/ and detection probabilities corresponding to specified material-loss scenarios and resource allocations. The data developed and the analyses performed during this study can assist both the facility operator and the IAEA in formulating necessary safeguards approaches and verification procedures to implement international safeguards for special nuclear materials.

  2. Structural-phase state and creep of mixed nitride fuel

    NASA Astrophysics Data System (ADS)

    Konovalov, I. I.; Tarasov, B. A.; Glagovsky, E. M.

    2016-04-01

    By the analysis of thermal creep data in conjunction with structural-phase state the most likely mechanisms of UN creep are considered. An equation relating the thermal and radiation creep of nitride fuel with such important parameters as plutonium content, porosity, grain size, the content of impurities of transition metals and oxygen, the carbon content has been suggested. At stationary operating parameters in reactor the creep of nitride fuel with technical purity is defined by the thermal component at mechanism of intergranular slip and by the radiation component, which plays a significant role at temperatures below 1100°C. Both types of creep in a first approximation have a linear dependence on the stress.

  3. High-transparency, self-standable gel-SLIPS fabricated by a facile nanoscale phase separation.

    PubMed

    Okada, Issei; Shiratori, Seimei

    2014-02-12

    Slippery liquid-infused porous surfaces (SLIPSs) that were both highly transparent and free-standing (self-standability) were fabricated by an extremely simple process using non-solvent-induced phase separation (NIPS) of a poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP)/di-n-butyl phthalate solution. We call these "Gel-SLIPS" because the porous PVDF-HFP film fabricated using the NIPS process has been used as a gel electrolyte in a lithium-ion battery. In previous reports, SLIPS fabrication required complex processes, high annealing temperatures, and drying. Gel-SLIPS can be fabricated from the adjusted solution and the lubricant at room temperature and pressure in 5 min by squeegee, cast, or dip methods. NIPS is based on a quick phase separation process in situ, and reduction of the surface energy is not required because of the considerable fluorine in PVDF-HFP. Moreover, because of the flexible nanonetwork structure of PVDF-HFP, Gel-SLIPS exhibited self-standability and high transmittance (>87% at 600 nm). Gel-SLIPS is thus highly versatile in terms of the fabrication process and film characteristics. PMID:24377307

  4. An integrated optical CO2 sensor. Phase 0: Design and fabrication of critical elements

    NASA Technical Reports Server (NTRS)

    Murphy, Michael C.; Kelly, Kevin W.; Li, B. Q.; Ma, EN; Wang, Wanjun; Vladimirsky, Yuli; Vladimirsky, Olga

    1994-01-01

    Significant progress has been made toward all of the goals for the first phase of the project short of actual fabrication of a light path. Two alternative approaches to fabricating gold mirrors using the basic LIGA process were developed, one using electroplated solid gold mirrors and the second using gold plated over a nickel base. A new method of fabrication, the transfer mask process, was developed and demonstrated. Analysis of the projected surface roughness and beam divergence effects was completed. With gold surface with low surface roughness scattering losses are expected to be insignificant. Beam divergence due to diffraction will require a modification of the original design, but should be eliminated by fabricating mirrors 1000 mu m in height by 1000 mu m in width and using a source with an initial beam radius greater than 300 mu m. This may eliminate any need for focusing optics. Since the modified design does not affect the mask layout, ordering of the mask and fabrication of the test structures can begin immediately at the start of Phase 1.

  5. High-temperature Chemical Compatibility of As-fabricated TRIGA Fuel and Type 304 Stainless Steel Cladding

    SciTech Connect

    Dennis D. Keiser, Jr.; Jan-Fong Jue; Eric Woolstenhulme; Kurt Terrani; Glenn A. Moore

    2012-09-01

    Chemical interaction between TRIGA fuel and Type-304 stainless steel cladding at relatively high temperatures is of interest from the point of view of understanding fuel behavior during different TRIGA reactor transient scenarios. Since TRIGA fuel comes into close contact with the cladding during irradiation, there is an opportunity for interdiffusion between the U in the fuel and the Fe in the cladding to form an interaction zone that contains U-Fe phases. Based on the equilibrium U-Fe phase diagram, a eutectic can develop at a composition between the U6Fe and UFe2 phases. This eutectic composition can become a liquid at around 725°C. From the standpoint of safe operation of TRIGA fuel, it is of interest to develop better understanding of how a phase with this composition may develop in irradiated TRIGA fuel at relatively high temperatures. One technique for investigating the development of a eutectic phase at the fuel/cladding interface is to perform out-of-pile diffusion-couple experiments at relatively high temperatures. This information is most relevant for lightly irradiated fuel that just starts to touch the cladding due to fuel swelling. Similar testing using fuel irradiated to different fission densities should be tested in a similar fashion to generate data more relevant to more heavily irradiated fuel. This report describes the results for TRIGA fuel/Type-304 stainless steel diffusion couples that were annealed for one hour at 730 and 800°C. Scanning electron microscopy with energy- and wavelength-dispersive spectroscopy was employed to characterize the fuel/cladding interface for each diffusion couple to look for evidence of any chemical interaction. Overall, negligible fuel/cladding interaction was observed for each diffusion couple.

  6. Manipulating mammalian cell by phase transformed titanium surface fabricated through ultra-short pulsed laser synthesis.

    PubMed

    Chinnakkannu Vijayakumar, Sivaprasad; Venkatakrishnan, Krishnan; Tan, Bo

    2016-01-15

    Developing cell sensitive indicators on interacting substrates that allows specific cell manipulation by a combination of physical, chemical or mechanical cues is a challenge for current biomaterials. Hence, various fabrication approaches have been created on a variety of substrates to mimic or create cell specific cues. However, to achieve cell specific cues a multistep process or a post-chemical treatment is often necessitated. So, a simple approach without any chemical or biological treatment would go a long way in developing bio-functionalized substrates to effectively modulate cell adhesion and interaction. The present investigation is aimed to study the manipulative activity induced by phase transformed titanium surface. An ultra-short laser is used to fabricate the phase transformed titanium surface where a polymorphic titanium oxide phases with titanium monoxide (TiO), tri-titanium oxide (Ti3O) and titanium dioxide (TiO2) have been synthesized on commercially pure titanium. Control over oxide phase transformed area was demonstrated via a combination of laser scanning time (laser pulse interaction time) and laser pulse widths (laser pulse to pulse separation time). The interaction of phase transformed titanium surface with NIH3T3 fibroblasts and MC3T3-E1 osteoblast cells developed a new bio-functionalized platforms on titanium based biomaterials to modulate cell migration and adhesion. The synthesized phase transformed titanium surface on the whole appeared to induce directional cues for cell migration with unique preferential cell adhesion unseen by other fabrication approaches. The precise bio-functionalization controllability exhibited during fabrication offers perceptible edge for developing a variety of smart bio-medical devices, implants and cardiovascular stents where the need in supressing specific cell adhesion and proliferation is of great demand. PMID:26546983

  7. Multi-fuel reformers for fuel cells used in transportation: Assessment of hydrogen storage technologies. Phase 2: Final report

    SciTech Connect

    1995-05-01

    During Phase 1 of this program, the authors evaluated all known hydrogen storage technologies (including those that are now practiced and those that are development) in the context of fuel cell vehicles. They determined that among the development technologies, carbon sorbents could most benefit from closer scrutiny. During Phase 2 of this program, they tested ten different carbon sorbents at various practical temperatures and pressures, and developed the concept of the usable Capacity Ratio, which is the ratio of the mass of hydrogen that can be released from a carbon-filled tank to the mass of hydrogen that can be released from an empty tank. The authors also commissioned the design, fabrication, and NGV2 (Natural Gas Vehicle) testing of an aluminum-lined, carbon-composite, full-wrapped pressure vessel to store hydrogen at 78 K and 3,000 psi. They constructed a facility to pressure cycle the tank at 78 K and to temperature cycle the tank at 3,000 psi, tested one such tank, and submitted it for a burst test. Finally, they devised a means by which cryogenic compressed hydrogen gas tanks can be filled and discharged using standard hardware--that is, without using filters, valves, or pressure regulators that must operate at both low temperature and high pressure. This report describes test methods and test results of carbon sorbents and the design of tanks for cold storage. 7 refs., 91 figs., 10 tabs.

  8. Evaluation of existing United States` facilities for use as a mixed-oxide (MOX) fuel fabrication facility for plutonium disposition

    SciTech Connect

    Beard, C.A.; Buksa, J.J.; Chidester, K.; Eaton, S.L.; Motley, F.E.; Siebe, D.A.

    1995-12-31

    A number of existing US facilities were evaluated for use as a mixed-oxide fuel fabrication facility for plutonium disposition. These facilities include the Fuels Material Examination Facility (FMEF) at Hanford, the Washington Power Supply Unit 1 (WNP-1) facility at Hanford, the Barnwell Nuclear Fuel Plant (BNFP) at Barnwell, SC, the Fuel Processing Facility (FPF) at Idaho National Engineering Laboratory (INEL), the Device Assembly Facility (DAF) at the Nevada Test Site (NTS), and the P-reactor at the Savannah River Site (SRS). The study consisted of evaluating each facility in terms of available process space, available building support systems (i.e., HVAC, security systems, existing process equipment, etc.), available regional infrastructure (i.e., emergency response teams, protective force teams, available transportation routes, etc.), and ability to integrate the MOX fabrication process into the facility in an operationally-sound manner that requires a minimum amount of structural modifications.

  9. Infrared Frequency Selective Surfaces Fabricated using Optical Lithography and Phase-Shift Masks

    SciTech Connect

    S.J. Spector; D.K. Astolfi; S.P. Doran; T.M. Lyszczarz; J.E. Raynolds

    2001-06-15

    A frequency selective surface (FSS) structure has been fabricated for use in a thermophotovoltaic system. The FSS provides a means for reflecting the unusable light below the bandgap of the thermophotovoltaic cell while transmitting the usable light above the bandgap. This behavior is relatively independent of the light's incident angle. The fabrication of the FSS was done using optical lithography and a phase-shift mask. The FSS cell consisted of circular slits spaced by 1100 nm. The diameters and widths of the circular slits were 870 nm and 120 nm, respectively. The FSS was predicted to pass wavelengths near 7 {micro}m and reflect wavelengths outside of this pass-band. The FSSs fabricated performed as expected with a pass-band centered near 5 {micro}m.

  10. Cast and 3D printed ion exchange membranes for monolithic microbial fuel cell fabrication

    NASA Astrophysics Data System (ADS)

    Philamore, Hemma; Rossiter, Jonathan; Walters, Peter; Winfield, Jonathan; Ieropoulos, Ioannis

    2015-09-01

    We present novel solutions to a key challenge in microbial fuel cell (MFC) technology; greater power density through increased relative surface area of the ion exchange membrane that separates the anode and cathode electrodes. The first use of a 3D printed polymer and a cast latex membrane are compared to a conventionally used cation exchange membrane. These new techniques significantly expand the geometric versatility available to ion exchange membranes in MFCs, which may be instrumental in answering challenges in the design of MFCs including miniaturisation, cost and ease of fabrication. Under electrical load conditions selected for optimal power transfer, peak power production (mean 10 batch feeds) was 11.39 μW (CEM), 10.51 μW (latex) and 0.92 μW (Tangoplus). Change in conductivity and pH of anolyte were correlated with MFC power production. Digital and environmental scanning electron microscopy show structural changes to and biological precipitation on membrane materials following long term use in an MFC. The cost of the novel membranes was lower than the conventional CEM. The efficacy of two novel membranes for ion exchange indicates that further characterisation of these materials and their fabrication techniques, shows great potential to significantly increase the range and type of MFCs that can be produced.

  11. A Novel Hybrid Axial-Radial Atmospheric Plasma Spraying Technique for the Fabrication of Solid Oxide Fuel Cell Anodes Containing Cu, Co, Ni, and Samaria-Doped Ceria

    NASA Astrophysics Data System (ADS)

    Cuglietta, Mark; Kuhn, Joel; Kesler, Olivera

    2013-06-01

    Composite coatings containing Cu, Co, Ni, and samaria-doped ceria (SDC) have been fabricated using a novel hybrid atmospheric plasma spraying technique, in which a multi-component aqueous suspension of CuO, Co3O4, and NiO was injected axially simultaneously with SDC injected radially in a dry powder form. Coatings were characterized for their microstructure, permeability, porosity, and composition over a range of plasma spray conditions. Deposition efficiency of the metal oxides and SDC was also estimated. Depending on the conditions, coatings displayed either layering or high levels of mixing between the SDC and metal phases. The deposition efficiencies of both feedstock types were strongly dependent on the nozzle diameter. Plasma-sprayed metal-supported solid oxide fuel cells utilizing anodes fabricated with this technique demonstrated power densities at 0.7 V as high as 366 and 113 mW/cm2 in humidified hydrogen and methane, respectively, at 800 °C.

  12. Atomic layer deposition on phase-shift lithography generated photoresist patterns for 1D nanochannel fabrication.

    PubMed

    Güder, Firat; Yang, Yang; Krüger, Michael; Stevens, Gregory B; Zacharias, Margit

    2010-12-01

    A versatile, low-cost, and flexible approach is presented for the fabrication of millimeter-long, sub-100 nm wide 1D nanochannels with tunable wall properties (wall thickness and material) over wafer-scale areas on glass, alumina, and silicon surfaces. This approach includes three fabrication steps. First, sub-100 nm photoresist line patterns were generated by near-field contact phase-shift lithography (NFC-PSL) using an inexpensive homemade borosilicate mask (NFC-PSM). Second, various metal oxides were directly coated on the resist patterns with low-temperature atomic layer deposition (ALD). Finally, the remaining photoresist was removed via an acetone dip, and then planar nanochannel arrays were formed on the substrate. In contrast to all the previous fabrication routes, the sub-100 nm photoresist line patterns produced by NFC-PSL are directly employed as a sacrificial layer for the creation of nanochannels. Because both the NFC-PSL and the ALD deposition are highly reproducible processes, the strategy proposed here can be regarded as a general route for nanochannel fabrication in a simplified and reliable manner. In addition, the fabricated nanochannels were used as templates to synthesize various organic and inorganic 1D nanostructures on the substrate surface. PMID:21047101

  13. Cellulosic fabrics printing with multifunctional encapsulated phthalocyanine pigment blue using phase separation method.

    PubMed

    Haroun, Ahmed A; Diab, H A; Hakeim, O A

    2016-08-01

    Aqueous dispersions of citric-acrylate (CAC) oligomer encapsulating C.I. Pigment Blue 15:3 (PB15:3) in the presence of glutaraldhyde were formulated using the phase separation method. FT-IR spectroscopy and centrifuge sedimentation are performed to confirm the encapsulation of pigment into CAC oligomer. The prepared capsules were characterized using thermal gravimetric analysis (TGA) and transmission electron microscope (TEM). The results revealed that the encapsulated pigment had a profound multifunctional impact and minimized the driving force of pigment printing on the cellulosic fabrics. Besides, the encapsulated pigment accelerated the pigment fixation on cellulosic fabrics without drying in one step and reduced the required amount of the binder, compared with the control sample. Furthermore, the printed fabrics exhibited good antibacterial performance against both Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). The presence of the crosslinker could be stabilized the encapsulated pigment on the cellulosic fabrics. Moreover, the light and washing fastness for the printed fabrics using encapsulated pigment are higher than that in case of using control samples. PMID:27112855

  14. Options for converting excess plutonium to feed for the MOX fuel fabrication facility

    SciTech Connect

    Watts, Joe A; Smith, Paul H; Psaras, John D; Jarvinen, Gordon D; Costa, David A; Joyce, Jr., Edward L

    2009-01-01

    The storage and safekeeping of excess plutonium in the United States represents a multibillion-dollar lifecycle cost to the taxpayers and poses challenges to National Security and Nuclear Non-Proliferation. Los Alamos National Laboratory is considering options for converting some portion of the 13 metric tons of excess plutonium that was previously destined for long-term waste disposition into feed for the MOX Fuel Fabrication Facility (MFFF). This approach could reduce storage costs and security ri sks, and produce fuel for nuclear energy at the same time. Over the course of 30 years of weapons related plutonium production, Los Alamos has developed a number of flow sheets aimed at separation and purification of plutonium. Flow sheets for converting metal to oxide and for removing chloride and fluoride from plutonium residues have been developed and withstood the test oftime. This presentation will address some potential options for utilizing processes and infrastructure developed by Defense Programs to transform a large variety of highly impure plutonium into feedstock for the MFFF.

  15. Fabrication of Dual Phase Magnesia-Zirconia Ceramics Doped with Plutonia and Erbia

    SciTech Connect

    Paul A. Lessing; Timothy A. Hyde

    2006-06-01

    Dual phase magnesia-zirconia ceramics doped with plutonia and erbia are being evaluated as an inert matrix fuel (IMF) for light water reactors (LWR). The motivation for this work is to develop an IMF with a thermal conductivity superior to that of the fuels based on single-phase yttria stabilized zirconia. The innovative fuel developed at INL is comprised of two major phases: pure MgO and quaternary solid solution consisting of MgO, ZrO{sub 2}, Er{sub 2}O{sub 3} and PuO{sub 2}. Pure MgO phase acts as an efficient heat conductor. It has been shown [1] that dual phase MgO-ZrO{sub 2} ceramics have the thermal conductivity superior to that of UO{sub 2} and have notable chemical resistance to water at the temperature of 573 K and pressure 8.6 MPa, which makes them attractive for use as an IMF matrix in LWRs.

  16. Fabrication of dual phase magnesia-zirconia ceramics doped with plutonia and erbia

    SciTech Connect

    P. G. Medvedev; J. F. Jue; S. M. Frank

    2006-06-01

    Dual phase magnesia-zirconia ceramics doped with plutonia and erbia are being evaluated as an inert matrix fuel (IMF) for light water reactors (LWR). The motivation for this work is to develop an IMF with a thermal conductivity superior to that of the fuels based on single-phase yttria stabilized zirconia. The innovative fuel developed at INL is comprised of two major phases: pure MgO and quaternary solid solution consisting of MgO, ZrO{sub 2}, Er{sub 2}O{sub 3} and PuO{sub 2}. Pure MgO phase acts as an efficient heat conductor. It has been shown [1] that dual phase MgO-ZrO{sub 2} ceramics have the thermal conductivity superior to that of UO{sub 2} and have notable chemical resistance to water at the temperature of 573 K and pressure 8.6 MPa, which makes them attractive for use as an IMF matrix in LWRs.

  17. Phase Change Nanodot Arrays Fabricated Using a Self-Assembly Diblock Copolymer Approach

    SciTech Connect

    Zhang,Y.; Wong, H.; Raoux, S.; Cha, J.; Rettner, C.; Krupp, L.; Topuria, T.; Milliron, D.; Rice, P.; Jordan-Sweet, J.

    2007-01-01

    Self-assembling diblock copolymer, polystyrene-b-poly-4-vinylpyridine (PS-b-P4VP), was used as the template for fabricating phase change nanostructures. The high density GeSb nanodots were formed by etching into an amorphous GeSb thin film using silica hard mask which was patterned on top of polymer. The nanodot arrays are 15 nm in diameter with 30 nm spacing. This is smaller than most structures obtained by e-beam lithography. Time-resolved x-ray diffraction studies showed that the phase transition occurred at 235 {sup o}C, which is 5 {sup o}C lower than blanket GeSb film but higher than that of Ge{sub 2}Sb{sub 2}Te{sub 5} (150 {sup o}C). GeSb showed good temperature stability for fabrication of small memory devices.

  18. Tunable tissue scaffolds fabricated by in situ crosslink in phase separation system

    PubMed Central

    Liu, Xifeng; Chen, Wenjian; Gustafson, Carl T.; Miller, A. Lee; Waletzki, Brian E.; Yaszemski, Michael J.; Lu, Lichun

    2015-01-01

    Three-dimensional (3-D) scaffolds with intrinsic porous structures are desirable in various tissue regeneration applications. In this study, a unique method that combines thermally induced phase separation with a photocrosslinking process was developed for the fabrication of 3-D crosslinked polymer scaffolds with densely interconnected porous structures. Biodegradable poly(propylene fumarate)-co-poly(L-lactic acid) with crosslinkable fumarate bonds were used as the structural polymer material and a dioxane/water binary system was applied for the phase separation. By altering the polymer composition (9, 5 and 3 wt%), different types of scaffolds with distinct morphology, mechanical strength, degradation rate, cell growth and morphology, and extracellular matrix production were fabricated. These crosslinked 3-D porous scaffolds with tunable strength and biological responses show promise for potential applications in regenerative therapies, including bone and neural tissue engineering. PMID:26989479

  19. X-ray phase imaging using a Gd-based absorption grating fabricated by imprinting technique

    NASA Astrophysics Data System (ADS)

    Yashiro, Wataru; Kato, Kosuke; Sadeghilaridjani, Maryam; Momose, Atsushi; Shinohara, Takenao; Kato, Hidemi

    2016-04-01

    A high-aspect-ratio absorption grating with a pitch of several µm is a key component of X-ray grating interferometery, which is an X-ray phase imaging technique that allows for highly sensitive X-ray imaging with a compact laboratory X-ray source. Here, we report that X-ray phase imaging was successfully performed at 15 keV by using a 23 ± 1-µm-height, 9-µm-pitch absorption grating (10 × 10 mm2) based on Gd (Gd60Cu25Al15) fabricated by a metallic glass imprinting technique. The imprinting technique is cost-efficient and has a high-production rate, and will be widely used for fabricating gratings not only for X-rays but also neutrons in the near future.

  20. Fabrication of zero power reactor fuel elements containing /sup 233/U/sub 3/O/sub 8/ powder

    SciTech Connect

    Nicol, R G; Parrott, J R; Krichinsky, A M; Box, W D; Martin, C W; Whitson, W R

    1982-05-01

    Oak Ridge National Laboratory, under contract with Argonne National Laboratory, completed the fabrication of 1743 fuel elements for use in their Zero Power Reactor. The contract also included recovery of 20 kg of /sup 233/U from rejected elements. This report describes the steps associated with conversion of purified uranyl nitrate (as solution) to U/sub 3/O/sub 8/ powder (suitable for fuel) and subsequent charging, sealing, decontamination, and testing of the fuel elements (packets) preparatory to shipment. The nuclear safety, radiation exposures, and quality assurance aspects of the program are discussed.

  1. 77 FR 70193 - Shaw Areva MOX Services (Mixed Oxide Fuel Fabrication Facility); Notice of Atomic Safety and...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-11-23

    ... COMMISSION Shaw Areva MOX Services (Mixed Oxide Fuel Fabrication Facility); Notice of Atomic Safety and Licensing Board Reconstitution Pursuant to 10 CFR 2.313(c) and 2.321(b), the Atomic Safety and Licensing... Administrative Judge, Atomic Safety and Licensing Board Panel. BILLING CODE 7590-01-P...

  2. Plan offered to revive nukes. [US DOE would fabricate fuel from weapons for WNP-1 and 3

    SciTech Connect

    Not Available

    1993-09-20

    This article discusses a new plan that would allow work to resume on two uncompleted nuclear power units in Washington state at a cost of $3.3 billion under an agreement with the federal government. If approved, the Department of Energy would fabricate plutonium from US and former Soviet Union weapons into fuel.

  3. 10 CFR 140.13a - Amount of financial protection required for plutonium processing and fuel fabrication plants.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 10 Energy 2 2010-01-01 2010-01-01 false Amount of financial protection required for plutonium... of financial protection required for plutonium processing and fuel fabrication plants. (a) Each holder of a license issued pursuant to part 70 of this chapter to possess and use plutonium at...

  4. 10 CFR 140.13a - Amount of financial protection required for plutonium processing and fuel fabrication plants.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 10 Energy 2 2011-01-01 2011-01-01 false Amount of financial protection required for plutonium... of financial protection required for plutonium processing and fuel fabrication plants. (a) Each holder of a license issued pursuant to part 70 of this chapter to possess and use plutonium at...

  5. Design and fabrication of a high temperature leading edge heating array, phase 1

    NASA Technical Reports Server (NTRS)

    1972-01-01

    Progress during a Phase 1 program to design a high temperature heating array is reported for environmentally testing full-scale shuttle leading edges (30 inch span, 6 to 15 inch radius) at flight heating rates and pressures. Heat transfer analyses of the heating array, individual modules, and the shuttle leading edge were performed, which influenced the array design, and the design, fabrication, and testing of a prototype heater module.

  6. Fabrication of phase-change Ge2Sb2Te5 nano-rings.

    PubMed

    Chu, Cheng Hung; Tseng, Ming Lun; Shiue, Chiun Da; Chen, Shuan Wei; Chiang, Hai-Pang; Mansuripur, Masud; Tsai, Din Ping

    2011-06-20

    Phase-change material Ge2Sb2Te5 rings with nanometer-scale thickness have been fabricated using the photo-thermal effect of a focused laser beam followed by differential chemical etching. Laser irradiation conditions and etching process parameters are varied to control the geometric characteristics of the rings. We demonstrate the possibility of arranging the rings in specific geometric patterns, and also their release from the original substrate. PMID:21716507

  7. Effect of PEG additive on anode microstructure and cell performance of anode-supported MT-SOFCs fabricated by phase inversion method

    NASA Astrophysics Data System (ADS)

    Ren, Cong; Liu, Tong; Maturavongsadit, Panita; Luckanagul, Jittima Amie; Chen, Fanglin

    2015-04-01

    Anode-supported micro-tubular solid oxide fuel cells (MT-SOFCs) have been fabricated by phase inversion method. For the anode support preparation, N-methyl-2-pyrrolidone (NMP), polyethersulfone (PESf) and poly ethylene glycol (PEG) were applied as solvent, polymer binder and additive, respectively. The effect of molecular weight and amount of PEG additive on the thermodynamics of the casting solutions was characterized by measuring the coagulation value. Viscosity of the casting slurries was also measured and the influence of PEG additive on viscosity was studied and discussed. The presence of PEG in the casting slurry can significantly influence the final anode support microstructure. Based on the microstructure result and the measured gas permeation value, two anode supports were selected for cell fabrication. For cell with the anode support fabricated using slurry with PEG additive, a maximum cell power density of 704 mW cm-2 is obtained at 750 °C with humidified hydrogen as fuel and ambient air as oxidant; cell fabricated without any PEG additive shows the peak cell power density of 331 mW cm-2. The relationship between anode microstructure and cell performance was discussed.

  8. Fabrication of submicron metallic grids with interference and phase-mask holography

    SciTech Connect

    Park, Joong-Mok; Kim, Tae-Geun; Constant, Kristen; Ho, Kai-Ming

    2011-01-25

    Complex, submicron Cu metallic mesh nanostructures are made by electrochemical deposition using polymer templates made from photoresist. The polymer templates are fabricated with photoresist using two-beam interference holography and phase mask holography with three diffracted beams. Freestanding metallic mesh structures are made in two separate electrodepositions with perpendicular photoresist grating templates. Cu mesh square nanostructures having large (52.6%) open areas are also made by single electrodeposition with a photoresist template made with a phase mask. These structures have potential as electrodes in photonic devices.

  9. Phase behavior of SWNT-superacid solutions and fabrication of aligned macrostructures

    NASA Astrophysics Data System (ADS)

    Dan, Budhadipta; Pasquali, Matteo

    2010-03-01

    Single-wall carbon nanotubes (SWNTs) are carbon based molecules which possess very high aspect ratio, high persistence length and behave as rigid rods when dispersed in a liquid phase. Superacids (oleum, chlorosulfonic acid etc) have been shown as one of the most effective solvents for dispersing and dissolving SWNTs. The SWNT-superacid systems exhibit a very rich phase behavior with well defined isotropic, bi-phasic and liquid crystalline phases, and controlled by factors like the SWNT concentration, SWNT length and strength of the acid (solvent). We report the fabrication of SWNT macrostructures with high degree of alignment by self assembly and exploiting the phase behavior of SWNT-superacid solutions. Phase transitions were induced in SWNT-superacid solutions in a controlled manner by gradually changing the strength of the acid solvent. This resulted in the precipitation of SWNT flakes and fibrils which exhibit a high degree of alignment. Detailed characterization of these macrostructures was performed using Raman spectroscopy and polarized optical microscopy. The above method presents a self-assembly based route for fabrication of aligned SWNT based structures from SWNT-superacid systems.

  10. Fabrication of single-phase titanium carbide layers from MWCNTs using high DC pulse

    NASA Astrophysics Data System (ADS)

    Kim, Woo Sik; Moon, Sook Young; Lee, Jeong Hoon; Bang, Sin Young; Choi, Bong Geun; Ham, Heon; Sekino, Tohru; Shim, Kwang Bo

    2010-02-01

    Single-phase layered titanium carbide (TiC) was successfully synthesized by reacting carbon nanotubes (CNTs) and titanium dioxide (TiO2) under a high direct current (DC) pulse. Single-phase TiC layer fabrication is confirmed as the transformation of multi-layered graphene from MWCNTs. Therefore its thickness and width is almost identical to those of transformed graphene layers. This is the first report on the formation of single-phase layered nano-TiC. Scanning electron microscopy (SEM), x-ray diffraction (XRD), x-ray photoelectron spectroscopy (XPS) and high-resolution transmission electron microscopy (HR-TEM) were used for the characteristic analysis of single-phase layered TiC structures.

  11. Development of advanced fuel cell system, phase 3

    NASA Technical Reports Server (NTRS)

    Handley, L. M.; Meyer, A. P.; Bell, W. F.

    1975-01-01

    A multiple task research and development program was performed to improve the weight, life, and performance characteristics of hydrogen-oxygen alkaline fuel cells for advanced power systems. Gradual wetting of the anode structure and subsequent long-term performance loss was determined to be caused by deposition of a silicon-containing material on the anode. This deposit was attributed to degradation of the asbestos matrix, and attention was therefore placed on development of a substitute matrix of potassium titanate. An 80 percent gold 20 percent platinum catalyst cathode was developed which has the same performance and stability as the standard 90 percent gold - 10 percent platinum cathode but at half the loading. A hybrid polysulfone/epoxy-glass fiber frame was developed which combines the resistance to the cell environment of pure polysulfone with the fabricating ease of epoxy-glass fiber laminate. These cell components were evaluated in various configurations of full-size cells. The ways in which the baseline engineering model system would be modified to accommodate the requirements of the space tug application are identified.

  12. Fabrication of low-temperature solid oxide fuel cells with a nanothin protective layer by atomic layer deposition.

    PubMed

    Ji, Sanghoon; Chang, Ikwhang; Lee, Yoon Ho; Park, Joonho; Paek, Jun Yeol; Lee, Min Hwan; Cha, Suk Won

    2013-01-01

    Anode aluminum oxide-supported thin-film fuel cells having a sub-500-nm-thick bilayered electrolyte comprising a gadolinium-doped ceria (GDC) layer and an yttria-stabilized zirconia (YSZ) layer were fabricated and electrochemically characterized in order to investigate the effect of the YSZ protective layer. The highly dense and thin YSZ layer acted as a blockage against electron and oxygen permeation between the anode and GDC electrolyte. Dense GDC and YSZ thin films were fabricated using radio frequency sputtering and atomic layer deposition techniques, respectively. The resulting bilayered thin-film fuel cell generated a significantly higher open circuit voltage of approximately 1.07 V compared with a thin-film fuel cell with a single-layered GDC electrolyte (approximately 0.3 V). PMID:23342963

  13. Fabrication of low-temperature solid oxide fuel cells with a nanothin protective layer by atomic layer deposition

    NASA Astrophysics Data System (ADS)

    Ji, Sanghoon; Chang, Ikwhang; Lee, Yoon Ho; Park, Joonho; Paek, Jun Yeol; Lee, Min Hwan; Cha, Suk Won

    2013-01-01

    Anode aluminum oxide-supported thin-film fuel cells having a sub-500-nm-thick bilayered electrolyte comprising a gadolinium-doped ceria (GDC) layer and an yttria-stabilized zirconia (YSZ) layer were fabricated and electrochemically characterized in order to investigate the effect of the YSZ protective layer. The highly dense and thin YSZ layer acted as a blockage against electron and oxygen permeation between the anode and GDC electrolyte. Dense GDC and YSZ thin films were fabricated using radio frequency sputtering and atomic layer deposition techniques, respectively. The resulting bilayered thin-film fuel cell generated a significantly higher open circuit voltage of approximately 1.07 V compared with a thin-film fuel cell with a single-layered GDC electrolyte (approximately 0.3 V).

  14. Development of Advanced Fuel Cell System (Phase 4)

    NASA Technical Reports Server (NTRS)

    Meyer, A. P.; Bell, W. F.

    1976-01-01

    A multiple-task research and development program was performed to improve the weight, life, and performance characteristics of hydrogen-oxygen alkaline fuel cells for advanced power systems. During Phase 4, the lowest stabilized degradation rate observed in all the testing completed during four phases of the program, 1 microvolt/hour, was demonstrated. This test continues after 5,000 hours of operation. The cell incorporates a PPf anode, a 90Au/10Pt cathode, a hybrid frame, and a Fybex matrix. These elements were developed under this program to extend cell life. The result demonstrated that the 80Au/20Pt cathode is as stable as a 90Au/10Pt cathode of twice the precious metal loading, was confirmed in full-scale cells. A hybrid frame two-cell plaque with dedicated flow fields and manifolds for all fluids was demonstrated to prevent the cell-to cell electrolyte transfer that limited the endurance of multicell plaques. At the conclusion of Phase 4, more than 90,900 hours of testing had been completed and twelve different cell designs had been evaluated. A technology base has been established which is ready for evaluation at the powerplant level.

  15. Uranium silicide pellet fabrication by powder metallurgy for accident tolerant fuel evaluation and irradiation

    DOE PAGESBeta

    Harp, Jason Michael; Lessing, Paul Alan; Hoggan, Rita Elaine

    2015-06-21

    In collaboration with industry, Idaho National Laboratory is investigating uranium silicide for use in future light water reactor fuels as a more accident resistant alternative to uranium oxide base fuels. Specifically this project was focused on producing uranium silicide (U3Si2) pellets by conventional powder metallurgy with a density greater than 94% of the theoretical density. This work has produced a process to consistently produce pellets with the desired density through careful optimization of the process. Milling of the U3Si2 has been optimized and high phase purity U3Si2 has been successfully produced. Results are presented from sintering studies and microstructural examinationsmore » that illustrate the need for a finely ground reproducible particle size distribution in the source powder. The optimized process was used to produce pellets for the Accident Tolerant Fuel-1 irradiation experiment. The average density of these pellets was 11.54 ±0.06 g/cm3. Additional characterization of the pellets by scaning electron microscopy and X-ray diffraction has also been performed. As a result, pellets produced in this work have been encapsulated for irradiation, and irradiation in the Advanced Test Reactor is expected soon.« less

  16. Uranium silicide pellet fabrication by powder metallurgy for accident tolerant fuel evaluation and irradiation

    NASA Astrophysics Data System (ADS)

    Harp, Jason M.; Lessing, Paul A.; Hoggan, Rita E.

    2015-11-01

    In collaboration with industry, Idaho National Laboratory is investigating uranium silicide for use in future light water reactor fuels as a more accident resistant alternative to uranium oxide base fuels. Specifically this project was focused on producing uranium silicide (U3Si2) pellets by conventional powder metallurgy with a density greater than 94% of the theoretical density. This work has produced a process to consistently produce pellets with the desired density through careful optimization of the process. Milling of the U3Si2 has been optimized and high phase purity U3Si2 has been successfully produced. Results are presented from sintering studies and microstructural examinations that illustrate the need for a finely ground reproducible particle size distribution in the source powder. The optimized process was used to produce pellets for the Accident Tolerant Fuel-1 irradiation experiment. The average density of these pellets was 11.54 ± 0.06 g/cm3. Additional characterization of the pellets by scanning electron microscopy and X-ray diffraction has also been performed. Pellets produced in this work have been encapsulated for irradiation, and irradiation in the Advanced Test Reactor is expected soon.

  17. Uranium silicide pellet fabrication by powder metallurgy for accident tolerant fuel evaluation and irradiation

    SciTech Connect

    Harp, Jason Michael; Lessing, Paul Alan; Hoggan, Rita Elaine

    2015-06-21

    In collaboration with industry, Idaho National Laboratory is investigating uranium silicide for use in future light water reactor fuels as a more accident resistant alternative to uranium oxide base fuels. Specifically this project was focused on producing uranium silicide (U3Si2) pellets by conventional powder metallurgy with a density greater than 94% of the theoretical density. This work has produced a process to consistently produce pellets with the desired density through careful optimization of the process. Milling of the U3Si2 has been optimized and high phase purity U3Si2 has been successfully produced. Results are presented from sintering studies and microstructural examinations that illustrate the need for a finely ground reproducible particle size distribution in the source powder. The optimized process was used to produce pellets for the Accident Tolerant Fuel-1 irradiation experiment. The average density of these pellets was 11.54 ±0.06 g/cm3. Additional characterization of the pellets by scaning electron microscopy and X-ray diffraction has also been performed. As a result, pellets produced in this work have been encapsulated for irradiation, and irradiation in the Advanced Test Reactor is expected soon.

  18. Fossil fuel derivatives with reduced carbon. Phase I final report

    SciTech Connect

    Kennel, E.B.; Zondlo, J.W.; Cessna, T.J.

    1999-06-30

    This project involves the simultaneous production of clean fossil fuel derivatives with reduced carbon and sulfur, along with value-added carbon nanofibers. This can be accomplished because the nanofiber production process removes carbon via a catalyzed pyrolysis reaction, which also has the effect of removing 99.9% of the sulfur, which is trapped in the nanofibers. The reaction is mildly endothermic, meaning that net energy production with real reductions in greenhouse emissions are possible. In Phase I research, the feasibility of generating clean fossil fuel derivatives with reduced carbon was demonstrated by the successful design, construction and operation of a facility capable of utilizing coal as well as natural gas as an inlet feedstock. In the case of coal, for example, reductions in CO{sub 2} emissions can be as much as 70% (normalized according to kilowatts produced), with the majority of carbon safely sequestered in the form of carbon nanofibers or coke. Both of these products are value-added commodities, indicating that low-emission coal fuel can be done at a profit rather than a loss as is the case with most clean-up schemes. The main results of this project were as follows: (1) It was shown that the nanofiber production process produces hydrogen as a byproduct. (2) The hydrogen, or hydrogen-rich hydrocarbon mixture can be consumed with net release of enthalpy. (3) The greenhouse gas emissions from both coal and natural gas are significantly reduced. Because coal consumption also creates coke, the carbon emission can be reduced by 75% per kilowatt-hour of power produced.

  19. Rapid fabrication of graphene on dielectric substrates via solid-phase processes

    NASA Astrophysics Data System (ADS)

    Xiong, W.; Zhou, Y. S.; Hou, W. J.; Lu, Y. F.

    2015-03-01

    To unleash the full potential of graphene in functional devices, high-quality graphene sheets and patterns are frequently required to be deposited on dielectric substrates. However, it generally calls for post-growth catalyst etching and graphene transfer steps in currently existing approaches, which are very time consuming and costly for fabricating functional graphene devices. We developed a rapid and cost-effective growth method to achieve the graphene formation directly on various kinds of dielectric substrates via a novel solid-phase transformation mechanism based on Ni/C thin films. High-quality graphene was obtained uniformly on whole surface of wafers with a controlled number of graphene layers. The monolayer graphene, as obtained, exhibits a low sheet resistance of about 50 Ω/sq and a high optical transmittance of 95.8% at 550 nm. Graphene patterns were successfully fabricated simply by either conventional photolithography or laser direct writing techniques. Various graphene patterns, including texts, spirals, line arrays, and even large-scale integrated circuit patterns, with a feature line width of 800 nm and a low sheet resistance of 205 ohm/sq, were achieved. The developed method provides a facile and cost-effective way to fabricate complex and high-quality graphene patterns directly on target substrates, which opens a door for fabricating various advanced optoelectronic devices.

  20. Magnesium-solution phase catholyte semi-fuel cell for undersea vehicles

    NASA Astrophysics Data System (ADS)

    Medeiros, Maria G.; Bessette, Russell R.; Deschenes, Craig M.; Patrissi, Charles J.; Carreiro, Louis G.; Tucker, Steven P.; Atwater, Delmas W.

    A magnesium-solution phase catholyte semi-fuel cell (SFC) is under development at the Naval Undersea Warfare Center (NUWC) as an energetic electrochemical system for low rate, long endurance undersea vehicle applications. This electrochemical system consists of a magnesium anode, a sodium chloride anolyte, a conductive membrane, a catalyzed carbon current collector, and a catholyte of sodium chloride, sulfuric acid and hydrogen peroxide. Bipolar electrode fabrication to minimize cell stack volume, long duration testing, and scale-up of electrodes from 77 to 1000 cm 2 have been the objectives of this project. Single cell and multi-cell testing at the 77 cm 2 configuration have been utilized to optimize all testing parameters including start-up conditions, flow rates, temperatures, and electrolyte concentrations while maintaining high voltages and efficiencies. The fabrication and testing of bipolar electrodes and operating parameter optimization for large electrode area cells will be presented. Designs for 1000 cm 2 electrodes, electrolyte flow patterns and current/voltage distribution across these large area cells will also be discussed.

  1. Gas phase carbonyl compounds in ship emissions: Differences between diesel fuel and heavy fuel oil operation

    NASA Astrophysics Data System (ADS)

    Reda, Ahmed A.; Schnelle-Kreis, J.; Orasche, J.; Abbaszade, G.; Lintelmann, J.; Arteaga-Salas, J. M.; Stengel, B.; Rabe, R.; Harndorf, H.; Sippula, O.; Streibel, T.; Zimmermann, R.

    2014-09-01

    Gas phase emission samples of carbonyl compounds (CCs) were collected from a research ship diesel engine at Rostock University, Germany. The ship engine was operated using two different types of fuels, heavy fuel oil (HFO) and diesel fuel (DF). Sampling of CCs was performed from diluted exhaust using cartridges and impingers. Both sampling methods involved the derivatization of CCs with 2,4-Dinitrophenylhydrazine (DNPH). The CCs-hydrazone derivatives were analyzed by two analytical techniques: High Performance Liquid Chromatography-Diode Array Detector (HPLC-DAD) and Gas Chromatography-Selective Ion Monitoring-Mass Spectrometry (GC-SIM-MS). Analysis of DNPH cartridges by GC-SIM-MS method has resulted in the identification of 19 CCs in both fuel operations. These CCs include ten aliphatic aldehydes (formaldehyde, acetaldehyde, propanal, isobutanal, butanal, isopentanal, pentanal, hexanal, octanal, nonanal), three unsaturated aldehydes (acrolein, methacrolein, crotonaldehyde), three aromatic aldehyde (benzaldehyde, p-tolualdehyde, m,o-molualdehyde), two ketones (acetone, butanone) and one heterocyclic aldehyde (furfural). In general, all CCs under investigation were detected with higher emission factors in HFO than DF. The total carbonyl emission factor was determined and found to be 6050 and 2300 μg MJ-1 for the operation with HFO and DF respectively. Formaldehyde and acetaldehyde were found to be the dominant carbonyls in the gas phase of ship engine emission. Formaldehyde emissions factor varied from 3500 μg MJ-1 in HFO operation to 1540 μg MJ-1 in DF operation, which is 4-30 times higher than those of other carbonyls. Emission profile contribution of CCs showed also a different pattern between HFO and DF operation. The contribution of formaldehyde was found to be 58% of the emission profile of HFO and about 67% of the emission profile of DF. Acetaldehyde showed opposite behavior with higher contribution of 16% in HFO compared to 11% for DF. Heavier carbonyls

  2. Application of high velocity oxygen fuel flame (HVOF) spraying to fabrication of La0.8Sr0.2Ga0.8Mg0.2O3 electrolyte for solid oxide fuel cells

    NASA Astrophysics Data System (ADS)

    Zhang, Shan-Lin; Li, Cheng-Xin; Li, Chang-Jiu; Yang, Guan-Jun; Liu, Meilin

    2016-01-01

    La0.8Sr0.2Ga0.8Mg0.2O3 (LSGM) is considered a promising electrolyte for intermediate-temperature solid oxide fuel cells (IT-SOFCs) due to its high ionic conductivity and stability under fuel cell operating conditions. Here we report our findings in investigating the feasibility of using a high velocity oxygen fuel flame (HVOF) spraying process for cost-effective fabrication of dense LSGM electrolyte membranes. The flame and in-flight particle behavior were simulated numerically to optimize the microstructure and phase compositions of the LSGM deposits. The measured gas leakage rate of an LSGM deposit is ∼7 × 10-7 cm4gf-1 s-1. The single cell assembled with 50-55 μm HVOF-sprayed LSGM electrolyte shows open circuit voltage (OCV) of 1.08 V at 800 °C, suggesting that the as-sprayed LSGM deposit is dense enough for direct application as SOFC electrolyte. At 800 °C, the ionic conductivity of the sprayed LSGM deposit is ∼0.04 S cm-1, indicating that the HVOF spraying is a promising process for low-temperature fabrication of dense LSGM electrolyte membranes for IT-SOFCs.

  3. Tunable phase-shifted fiber Bragg grating based on femtosecond laser fabricated in-grating bubble.

    PubMed

    Liao, Changrui; Xu, Lei; Wang, Chao; Wang, D N; Wang, Yiping; Wang, Qiao; Yang, Kaiming; Li, Zhengyong; Zhong, Xiaoyong; Zhou, Jiangtao; Liu, Yingjie

    2013-11-01

    We present a type of phase-shifted fiber Bragg gratings based on an in-grating bubble fabricated by femtosecond (fs) laser ablation together with a fusion-splicing technique. A microchannel vertically crossing the bubble is drilled by fs laser to allow liquid to flow in or out. By filling different refractive index (RI) liquid into the bubble, the phase-shift peak is found to experience a linear red shift with the increase of RI, while little contribution to the change of phase shift comes from the temperature and axial strain. Therefore, such a PS-FBG could be used to develop a promising tunable optical filter and sensor. PMID:24177122

  4. Fabrication and phase transition of Gd2Zr2O7 ceramics immobilized various simulated radionuclides

    NASA Astrophysics Data System (ADS)

    Fan, Long; Shu, Xiaoyan; Ding, Yi; Duan, Tao; Song, Mianxin; Lu, Xirui

    2015-01-01

    To investigate the feasibility of Gd2Zr2O7 used for disposal waste of multi-nuclides with multi-valence, simulated trialkyl phosphine oxides (TRPO) waste was chosen to research the fabrication method and phase evolution. A series of (Gd,A)2(Zr,B)2O7 ceramics were successfully fabricated through a solid-state reaction sintering at 1500 °C for 72 h. XRD studies reveal that the compositions containing up to 35 wt.% simulated TRPO waste exhibit a single pyrochlore structure, while the doping content varies from 35 to 65 wt.%, the samples adopt a single defect fluorite structure. In the discussed range, the lattice parameter decreases with the increased doping content, and the rA/rB ratio decreases from 1.43 to 1.27, while the degree order increases in turn. Furthermore, the densification and grain growth in pyrochlore structure are promoted by an enhanced doping content.

  5. Fabrication of a phase transmission holographic optical element in polycarbonate and its characterization.

    PubMed

    Vadivelan, V; Chandar Shekar, B

    2016-08-10

    The phase transmission holographic optical element in silver halide holographic emulsion, especially for holographic collimator sights, is fabricated and the desired diffraction efficiency is obtained with very high transmission. One of the main drawbacks of these holograms are that they become dark by being exposed under sunlight, and this darkness drastically reduces the visible transmission and diffraction efficiency of a holographic optical element, hence it is not suitable for weapon sight application. To overcome this problem, we transferred a holographic optical element with a reticle image from silver halide into polycarbonate by using copying, electroforming, and recombination techniques. The holographic optical element in polycarbonate has many advantages; the detailed method of fabrication, transfer, and its characterization are presented. The very interesting result of diffraction efficiency variation with angle obtained in polycarbonate is discussed. PMID:27534494

  6. Massive Fabrication of Polymer Microdiscs by Phase Separation and Freestanding Process.

    PubMed

    Zhang, Hong; Fujii, Mao; Okamura, Yosuke; Zhang, Li; Takeoka, Shinji

    2016-06-29

    We present a facile method to fabricate polymer thin films with tens of nanometers thickness and several micrometers size (also called "microdiscs" herein) by applying phase separation of polymer blend. A water-soluble supporting layer is employed to obtain a freestanding microdisc suspension. Owing to their miniaturized size, microdiscs can be injected through a syringe needle. Herein, poly(d,l-lactic acid) microdiscs were fabricated with various thicknesses and sizes, in the range from ca. 10 to 60 nm and from ca. 1.0 to 10.0 μm, respectively. Magnetic nanoparticles were deposited on polymer microdiscs with a surface coating method. The magnetic manipulation of microdiscs in a liquid environment under an external magnetic field was achieved with controllable velocity by adjusting the microdisc dimensions and the loading amount of magnetic components. Such biocompatible polymer microdiscs are expected to serve as injectable vehicles for targeted drug delivery. PMID:27267217

  7. Report on Development of Concepts for the Advanced Casting System in Support of the Deployment of a Remotely Operable Research Scale Fuel Fabrication Facility for Metal Fuel

    SciTech Connect

    Ken Marsden

    2007-03-01

    Demonstration of recycle processes with low transuranic losses is key to the successful implementation of the Global Nuclear Energy Partnership strategy to manage spent fuel. It is probable that these recycle processes will include remote fuel fabrication. This report outlines the strategy to develop and implement a remote metal fuel casting process with minimal transuranic losses. The approach includes a bench-scale casting system to develop materials, methods, and perform tests with transuranics, and an engineering-scale casting system to demonstrate scalability and remote operability. These systems will be built as flexible test beds allowing exploration of multiple fuel casting approaches. The final component of the remote fuel fabrication demonstration culminates in the installation of an advanced casting system in a hot cell to provide integrated remote operation experience with low transuranic loss. Design efforts and technology planning have begun for the bench-scale casting system, and this will become operational in fiscal year 2008, assuming appropriate funding. Installation of the engineering-scale system will follow in late fiscal year 2008, and utilize materials and process knowledge gained in the bench-scale system. Assuming appropriate funding, the advanced casting system will be installed in a remote hot cell at the end of fiscal year 2009.

  8. Effects of anode fabrication parameters on the performance and redox behavior of solid oxide fuel cells

    NASA Astrophysics Data System (ADS)

    Timurkutluk, Bora; Mat, Mahmut D.

    2014-07-01

    Anode supported solid oxide fuel cells (SOFCs) having various anode support porosities and electrolyte thicknesses are developed and their effects on the cell performance and redox behavior of the cell are investigated experimentally. An yttria stabilized zirconia based anode supported membrane electrode group (MEG) is developed with the tape casting, co-sintering and screen printing methodologies. For comparison, various anode supported cells with different electrolyte thickness and anode support porosities are also fabricated. An experimental setup is devised for the performance measurement of the cells before and after redox cycling. The mechanical performance of the cell before and after redox cycling is also measured via three point bending tests. Experimental results reveal that the porosity of the anode support and the thickness of the electrolyte should be carefully decided by considering not only the cell performances but also the redox stability. In addition, after single redox cycle the decrease in the mechanical properties of the cell is found to be around 50% while the same cell shows only around 10% electrochemical performance loss.

  9. Test Operation of Oxygen-Enriched Incinerator for Wastes From Nuclear Fuel Fabrication Facility

    SciTech Connect

    Kim, J.-G.; Yang, H.cC.; Park, G.-I.; Kim, I.-T.; Kim, J.-K.

    2002-02-26

    The oxygen-enriched combustion concept, which can minimize off-gas production, has been applied to the incineration of combustible uranium-containing wastes from a nuclear fuel fabrication facility. A simulation for oxygen combustion shows the off-gas production can be reduced by a factor of 6.7 theoretically, compared with conventional air combustion. The laboratory-scale oxygen enriched incineration (OEI) process with a thermal capacity of 350 MJ/h is composed of an oxygen feeding and control system, a combustion chamber, a quencher, a ceramic filter, an induced draft fan, a condenser, a stack, an off-gas recycle path, and a measurement and control system. Test burning with cleaning paper and office paper in this OEI process shows that the thermal capacity is about 320 MJ/h, 90 % of design value and the off-gas reduces by a factor of 3.5, compared with air combustion. The CO concentration for oxygen combustion is lower than that of air combustion, while the O2 concentration in off-gas is kept above 25 vol % for a simple incineration process without any grate. The NOx concentration in an off-gas stream does not reduce significantly due to air incoming by leakage, and the volume and weight reduction factors are not changed significantly, which suggests a need for an improvement in sealing.

  10. Fabrication of large-scale multilevel phase-type Fresnel zone plate arrays by femtosecond laser direct writing

    NASA Astrophysics Data System (ADS)

    Yu, Yan-Hao; Tian, Zhen-Nan; Jiang, Tong; Niu, Li-Gang; Gao, Bing-Rong

    2016-03-01

    We report on the fabrication of large-scale eight-level phase-type Fresnel zone plate arrays (FZPAs) by femtosecond-laser direct writing technology. A high-speed galvanometer scanning system was used to fabricate each Fresnel zone plate to realize high fabrication efficiency. To overcome the limited fabrication scale in the case of galvanometer scanning, inter-plate movements were controlled by multi-axis air-bearing precise positioning stages. With the system, FZPAs whose fill-factor was designed to be 100% realized a diffraction efficiency of 89%. The focusing and imaging properties of the FZPAs were also evaluated, and the FZPAs showed high fidelity.

  11. Fabrication of fiber optic long period gratings operating at the phase matching turning point using an amplitude mask

    NASA Astrophysics Data System (ADS)

    Hromadka, J.; Correia, R.; Korposh, S.

    2016-05-01

    A fast method for the fabrication of the long period gratings (LPG) optical fibres operating at or near the phase matching turning point (PMTP) with the period of 109.0, 109.5 and 110.0 μm based on an amplitude mask writing system is described. The proposed system allows fabricating 3 cm long LPG sensors operating at PMPT within 20 min that is approximately 8 times faster than point-by-point approach. The reproducibility of the fabrication process was thoroughly studied. The response of the fabricated LPGs to the external change of the refractive index was investigated using water and methanol.

  12. Effect of the fabrication process on fatigue performance of U 3Si 2 fuel plate with sandwich structure

    NASA Astrophysics Data System (ADS)

    Wang, Xi-Shu; Li, Shuang-Shou; Wang, Qing-Yuan; Xu, Yong

    2005-06-01

    U 3Si 2-Al fuel plate is one of the dispersion fuel structure materials recently developed and widely used in research reactors. The mechanical properties of this structural material, especially the fatigue performance, are strongly dependent on its fabrication process. To investigate the effects of these processing technologies, the fatigue tests for the different specimens were carried out. The S- N curves indicate that the fabrication processing technologies of U 3Si 2 fuel plate, such as the addition of U 3Si 2 particles into aluminum powder to form the fuel meat, holding and rolling the processes of meat and cladding of 6061-Al alloy, plays an important role in improving the mechanical properties and fatigue performance of this fuel plate. In addition, some factors that influence the crack initiation and propagation are summarized based on the fatigue images that are in situ observations with SEM. The critical criterion for fatigue damage is proposed based on the fatigue data of the structural material, which were obtained at the different conditions.

  13. Fabrication of ORNL Fuel Irradiated in the Peach Bottom Reactor and Postirradiation Examination of Recycle Test Elements 7 and 4

    SciTech Connect

    Long, Jr. E.L.

    2001-10-25

    Seven full-sized Peach Bottom Reactor. fuel elements were fabricated in a cooperative effort by Oak Ridge National Laboratory (ORNL) and Gulf General Atomic (GGA) as part of the National HTGR Fuel Recycle Development Program. These elements contain bonded fuel rods and loose beds of particles made from several combinations of fertile and fissile particles of interest for present and future use in the High-Temperature Gas-Cooled Reactor (HTGR). The portion of the fuel prepared for these elements by ORNL is described in detail in this report, and it is in conjunction with the GGA report (GA-10109) a complete fabrication description of the test. In addition, this report describes the results obtained to date from postirradiation examination of the first two elements removed from the Peach Bottom Reactor, RTE-7 and -4. The fuel examined had relatively low exposure, up to about 1.5 x 10{sup 21} neutrons/cm* fast (>0.18 MeV) fluence, compared with the peak anticipated HTGR fluence of 8.0 x 10{sup 21}, but it has performed well at this exposure. Dimensional data indicate greater irradiation shrinkage than expected from accelerated test data to higher exposures. This suggests that either the method of extrapolation of the higher exposure data back to low exposure is faulty, or the behavior of the coated particles in the neutron spectrum characteristic of the accelerated tests does not adequately represent the behavior in an HTGR spectrum.

  14. Comparative Study of Laboratory-Scale and Prototypic Production-Scale Fuel Fabrication Processes and Product Characteristics

    SciTech Connect

    Douglas W. Marshall

    2014-10-01

    An objective of the High Temperature Gas Reactor fuel development and qualification program for the United States Department of Energy has been to qualify fuel fabricated in prototypic production-scale equipment. The quality and characteristics of the tristructural isotropic coatings on fuel kernels are influenced by the equipment scale and processing parameters. Some characteristics affecting product quality were suppressed while others have become more significant in the larger equipment. Changes to the composition and method of producing resinated graphite matrix material has eliminated the use of hazardous, flammable liquids and enabled it to be procured as a vendor-supplied feed stock. A new method of overcoating TRISO particles with the resinated graphite matrix eliminates the use of hazardous, flammable liquids, produces highly spherical particles with a narrow size distribution, and attains product yields in excess of 99%. Compact fabrication processes have been scaled-up and automated with relatively minor changes to compact quality to manual laboratory-scale processes. The impact on statistical variability of the processes and the products as equipment was scaled are discussed. The prototypic production-scale processes produce test fuels that meet fuel quality specifications.

  15. Affordable Fabrication and Properties of Silicon Carbide-Based Interpenetrating Phase Composites

    NASA Technical Reports Server (NTRS)

    Singh, Mrityunjay

    1998-01-01

    An affordable processing technique for the fabrication of silicon carbide-based interpenetrating phase composites (IPCs) is presented. This process consists of the production of microporous carbon preforms and subsequent infiltration with liquid silicon or silicon-refractory metal alloys. The microporous preforms are made by the pyrolysis of a polymerized resin mixture for which methods to control pore volume and pore size have been established. The process gives good control of microstructure and morphology of silicon carbide-based composite materials. Room and high temperature mechanical properties (flexural strength, compressive strength, and flexural creep) of low and high silicon-silicon carbide composites will be discussed.

  16. Advanced ceramic fabric body mounted radiator for Space Station Freedom Phase O design

    SciTech Connect

    Webb, B.J.; Antoniak, Z.I.; Pauley, K.A.

    1990-06-01

    A body mounted radiator concept constructed of advanced ceramic fabric materials for use with the Phase 0 design of Space Station Freedom is described. The radiator is expected to weigh between 1.4 and 3.5 kg/m{sup 2} of single sided radiating surface, use ammonia working fluid, be highly deployable, and exhibit good reliability characteristics. This compares well with the 11.8 kg/m{sup 2} for two sided radiators proposed for the current space station design.

  17. Fabrication of triple layered vascular scaffolds by combining electrospinning, braiding, and thermally induced phase separation

    NASA Astrophysics Data System (ADS)

    Mi, Hao-Yang; Jing, Xin; Yu, Emily; McNulty, Jason; Turng, Lih-Sheng

    2015-12-01

    Triple layered small diameter vascular scaffolds, which consisted of thermoplastic polyurethane (TPU) and silk, were fabricated in this study for the first time by combining electrospinning, braiding, and thermally induced phase separation methods. These novel vascular scaffolds, which possess three layers of different structures (nanofibrous inner layer, woven silk filament middle layer, and porous outer layer) have a desired toe region in the tensile test and sufficient suture retention and burst pressure for vascular graft applications. The endothelia cell culture tests showed that a cell layer could form on the inner surface of a scaffold with high cell viability. Furthermore, the cells showed favorable morphology on the scaffold.

  18. Zinc oxide nanowires and nanorods fabricated by vapour-phase transport at low temperature

    NASA Astrophysics Data System (ADS)

    Xu, C. X.; Sun, X. W.; Dong, Z. L.; Yu, M. B.; My, T. D.; Zhang, X. H.; Chua, S. J.; White, T. J.

    2004-07-01

    Using zinc chloride as source material, zinc oxide nanowires and nanorods were fabricated by a vapour-phase transport method at low temperature. The nanowires grown on gold-coated silicon showed a uniform diameter of about 40 nm, and the nanorods on copper-coated silicon grew upwards to form flower-like arrays. The x-ray diffraction and transmission electron microscopy analyses demonstrated that the nanostructural zinc oxide grew along the [0001] direction. The growth process was attributed to a vapour-liquid-solid mechanism. Distinct photoluminescent behaviours were observed for zinc oxide nanostructures grown on gold-coated and copper-coated silicon wafers.

  19. Optical on-line method of ethyl mercaptan detection in liquid phase in motor fuels

    NASA Astrophysics Data System (ADS)

    Kireev, S. V.; Shnyrev, S. L.

    2015-11-01

    The letter reports on the experimental research of the absorption spectra of ethyl mercaptan in liquid phase in various motor fuels (petrol, kerosene, and diesel fuel). The values of ethyl mercaptan absorption sections were obtained in the above-mentioned fuels in the spectral range of 280-475 nm, and the dependences of ethyl mercaptan absorption coefficients on its part in the analyzed mixture with motor fuels were researched. On the basis of the obtained results we propose an optical on-line method of ethyl mercaptan detection in motor fuels. The optimal spectral ranges for the highest sensitivity of ethyl mercaptan detection in various motor fuels were determined.

  20. Wafer scale fabrication of submicron chessboard gratings using phase masks in proximity lithography

    NASA Astrophysics Data System (ADS)

    Stuerzebecher, Lorenz; Harzendorf, Torsten; Fuchs, Frank; Zeitner, Uwe D.

    2012-03-01

    One and two dimensional grating structures with submicron period have a huge number of applications in optics and photonics. Such structures are conventionally fabricated using interference or e-beam lithography. However, both technologies have significant drawbacks. Interference lithography is limited to rather simple geometries and the sequential writing scheme of e-beam lithography leads to time consuming exposures for each grating. We present a novel fabrication technique for this class of microstructures which is based on proximity lithography in a mask aligner. The technology is capable to pattern a complete wafer within less than one minute of exposure time and offers thereby high lateral resolution and a reliable process. Our advancements compared to standard mask aligner lithography are twofold: First of all, we are using periodic binary phase masks instead of chromium masks to generate an aerial image of high resolution and exceptional light efficiency at certain distances behind the mask. Second, a special mask aligner illumination set-up is employed which allows to precisely control the incidence angles of the exposure light. This degree of freedom allows both, to shape the aerial image (e. g. transformation of a periodic spot pattern into a chessboard pattern) and to increase its depth of focus considerably. That way, our technology enables the fabrication of high quality gratings with arbitrary geometry in a fast and stable wafer scale process.

  1. Evaluation of UF{sub 6}-to-UO{sub 2} conversion capability at commercial nuclear fuel fabrication facilities.

    SciTech Connect

    Ranek, N. L.; Monette, F. A.

    2001-06-08

    This report examines the capabilities of existing commercial nuclear fuel fabrication facilities to convert depleted uranium hexafluoride (UF{sub 6}) to uranium oxide (UO{sub 2}). The U.S. Department of Energy (DOE) needs this information to determine whether using such capacity to convert DOE's inventory of depleted UF{sub 6} to a more stable form is a reasonable alternative that should be considered in the site-specific environmental impact statement for construction and operation of depleted UF{sub 6} conversion facilities. Publicly available information sources were consulted to ascertain the information summarized in this report. For domestic facilities, the information summarized includes currently operating capacity to convert depleted UF{sub 6} to UO{sub 2}; transportation distances from depleted UF{sub 6} storage locations near Oak Ridge, Tennessee, Portsmouth, Ohio, and Paducah, Kentucky, to the facilities; and regulatory requirements applicable to nuclear fuel fabrication and transportation of depleted UF{sub 6}. The report concludes that the total currently operating capability of U.S. commercial nuclear fuel fabricators to convert UF{sub 6} to UO{sub 2} is approximately 5,200 metric tons of UF{sub 6} per annum (tUF{sub 6}/a). This total includes 666 tUF{sub 6}/a scheduled for shutdown by the end of 2001. However, only about 300 tUF{sub 6}/a of this capacity could be confirmed as being possibly available to DOE. The report also provides some limited descriptions of the capabilities of foreign fuel fabrication plants to convert UF{sub 6} to uranium oxide forms.

  2. Green fabrication of composite cathode with attractive performance for solid oxide fuel cells through facile inkjet printing

    NASA Astrophysics Data System (ADS)

    Li, Chao; Chen, Huili; Shi, Huangang; Tade, Moses O.; Shao, Zongping

    2015-01-01

    The inkjet printing technique has numerous advantages and is attractive in solid oxide fuel cell (SOFC) fabrication, especially for the dense thin electrolyte layer because of its ultrafine powder size. In this study, we exploited the technique for the fabrication of a porous SDC/SSC composite cathode layer using environmentally friendly water-based ink. An optimized powder synthesis method was applied to the preparation of the well-dispersed suspension. In view of the easy sintering of the thin film layer prepared by inkjet printing, 10 wt.% pore former was introduced to the ink. The results indicate that the cell with the inkjet printing cathode layer exhibits a fantastic electrochemical performance, with a PPD as high as 940 mW cm-2 at 750 °C, which is comparable to that of a cell prepared using the conventional wet powder spraying method, suggesting a promising application of inkjet printing on electrode layer fabrication.

  3. Homeotropically aligning phase separated columnar structures for fabrication of flexible electrooptical devices

    NASA Astrophysics Data System (ADS)

    Acharya, Bharat R.; Choi, Hyunchul; Srinivasarao, Mohan; Kumar, Satyendra

    2011-11-01

    A method of achieving homeotropic alignment of liquid crystals (LCs) by ultraviolet light induced phase separation of LC from its mixture with photo-curable pre-polymer is reported. Vertical polymer columns and micro-fibrils developed during the phase separation promote homeotropic alignment of the LC director (i.e., alignment perpendicular to the LC-substrate interface), suitable for devices based on LCs possessing negative dielectric anisotropy. These vertical structures extend between two substrates and permit the fabrication of highly flexible electro-optical devices with high contrast coupled with fast response times. This simple single-step technique eliminates the need for the traditional polymer alignment layer pre-deposited on substrates.

  4. Sensitivity analysis and optimization method for the fabrication of one-dimensional beam-splitting phase gratings

    PubMed Central

    Pacheco, Shaun; Brand, Jonathan F.; Zaverton, Melissa; Milster, Tom; Liang, Rongguang

    2015-01-01

    A method to design one-dimensional beam-spitting phase gratings with low sensitivity to fabrication errors is described. The method optimizes the phase function of a grating by minimizing the integrated variance of the energy of each output beam over a range of fabrication errors. Numerical results for three 1x9 beam splitting phase gratings are given. Two optimized gratings with low sensitivity to fabrication errors were compared with a grating designed for optimal efficiency. These three gratings were fabricated using gray-scale photolithography. The standard deviation of the 9 outgoing beam energies in the optimized gratings were 2.3 and 3.4 times lower than the optimal efficiency grating. PMID:25969268

  5. Polyurethane/poly(lactic-co-glycolic) acid composite scaffolds fabricated by thermally induced phase separation.

    PubMed

    Rowlands, A S; Lim, S A; Martin, D; Cooper-White, J J

    2007-04-01

    In this study, we present a novel composite scaffold fabricated using a thermally induced phase separation (TIPS) process from poly(lactic-co-glycolic) (PLGA) and biomedical polyurethane (PU). This processing method has been tuned to allow intimate (molecular) mixing of these two very different polymers, giving rise to a unique morphology that can be manipulated by controlling the phase separation behaviour of an initially homogenous polymer solution. Pure PLGA scaffolds possessed a smooth, directional fibrous sheet-like structure with pore sizes of 0.1-200mum, a porous Young's modulus of 93.5kPa and were relatively brittle to touch. Pure PU scaffolds had an isotropic emulsion-like structure, a porous Young's modulus of 15.7kPa and were much more elastic than the PLGA scaffolds. The composite PLGA/PU scaffold exhibits advantageous morphological, mechanical and cell adhesion and growth supporting properties, when compared with scaffolds fabricated from PLGA or PU alone. This novel method provides a mechanism for the formation of tailored bioactive scaffolds from nominally incompatible polymers, representing a significant step forward in scaffold processing for tissue-engineering applications. PMID:17258315

  6. Fabrication and characterization of all-ceramic solid oxide fuel cells based on composite oxide anode

    NASA Astrophysics Data System (ADS)

    Kim, Jeonghee; Shin, Dongwook; Son, Ji-Won; Lee, Jong-Ho; Kim, Byung-Kook; Je, Hae-June; Lee, Hae-Weon; Yoon, Kyung Joong

    2013-11-01

    All-ceramic solid oxide fuel cells (SOFCs), which offer advantages in carbon tolerance, sulfur resistance and redox stability, are fabricated and evaluated. The electrolyte-supported cells are composed of a La0.75Sr0.25Cr0.5Mn0.5O3-δ (LSCM)-Ce0.9Gd0.1O1.95-δ (GDC) anode, an Y2O3-stabilized ZrO2 (YSZ) electrolyte, a GDC interdiffusion barrier layer, and a La0.8Sr0.2Co0.2Fe0.8O3-δ (LSCF)-GDC cathode. A particle-dispersed glycine-nitrate process is developed to synthesize extremely fine and homogeneous LSCM-GDC ceramic composite powders. The electrochemical performance of the LSCM-GDC anode is comparable to that of conventional Ni-based anodes. The impedance spectra of the all-ceramic SOFCs are successfully interpreted by the independent characterization of the individual electrodes via half-cell measurements. The impedance of the LSCM-GDC anode is dominated by a low-frequency arc originating from the “chemical capacitance”, which is associated with the variation of the oxygen nonstoichiometry in the mixed conducting ceramic electrode. In addition, the impedance arc associated with the electrode-gas interaction is observed in the LSCM-GDC anode. The rate-limiting processes for the LSCF-GDC cathode are observed to be solid-state oxygen diffusion and surface chemical exchange. Herein, the reaction mechanisms and rate-limiting processes of the all-ceramic SOFCs are discussed in detail and compared with those of conventional Ni-based SOFCs.

  7. Past research and fabrication conducted at SCK•CEN on ferritic ODS alloys used as cladding for FBR's fuel pins

    NASA Astrophysics Data System (ADS)

    De Bremaecker, Anne

    2012-09-01

    In the 1960s in the frame of the sodium-cooled fast breeders, SCK•CEN decided to develop claddings made with ferritic stainless materials because of their specific properties, namely a higher thermal conductivity, a lower thermal expansion, a lower tendency to He-embrittlement, and a lower swelling than the austenitic stainless steels. To enhance their lower creep resistance at 650-700 °C arose the idea to strengthen the microstructure by oxide dispersions. This was the starting point of an ambitious programme where both the matrix and the dispersions were optimized. A purely ferritic 13 wt% Cr matrix was selected and its mechanical strength was improved through addition of ferritizing elements. Results of tensile and stress-rupture tests showed that Ti and Mo were the most beneficial elements, partly because of the chi-phase precipitation. In 1973 the optimized matrix composition was Fe-13Cr-3.5Ti-2Mo. To reach creep properties similar to those of AISI 316, different dispersions and methods were tested: internal oxidation (that was not conclusive), and the direct mixing of metallic and oxide powders (Al2O3, MgO, ZrO2, TiO2, ZrSiO4) followed by pressing, sintering, and extrusion. The compression and extrusion parameters were determined: extrusion as hollow at 1050 °C, solution annealing at 1050 °C/15 min, cleaning, cold drawing to the final dimensions with intermediate annealings at 1050 °C, final annealing at 1050 °C, straightening and final aging at 800 °C. The choice of titania and yttria powders and their concentrations were finalized on the basis of their out-of-pile and in-pile creep and tensile strength. As soon as a resistance butt welding machine was developed and installed in a glove-box, fuel segments with PuO2 were loaded in the Belgian MTR BR2. The fabrication parameters were continuously optimized: milling and beating, lubrication, cold drawing (partial and final reduction rates, temperature, duration, atmosphere and furnace). Specific non

  8. Transmutation, Burn-Up and Fuel Fabrication Trade-Offs in Reduced-Moderation Water Reactor Thorium Fuel Cycles - 13502

    SciTech Connect

    Lindley, Benjamin A.; Parks, Geoffrey T.; Franceschini, Fausto

    2013-07-01

    Multiple recycle of long-lived actinides has the potential to greatly reduce the required storage time for spent nuclear fuel or high level nuclear waste. This is generally thought to require fast reactors as most transuranic (TRU) isotopes have low fission probabilities in thermal reactors. Reduced-moderation LWRs are a potential alternative to fast reactors with reduced time to deployment as they are based on commercially mature LWR technology. Thorium (Th) fuel is neutronically advantageous for TRU multiple recycle in LWRs due to a large improvement in the void coefficient. If Th fuel is used in reduced-moderation LWRs, it appears neutronically feasible to achieve full actinide recycle while burning an external supply of TRU, with related potential improvements in waste management and fuel utilization. In this paper, the fuel cycle of TRU-bearing Th fuel is analysed for reduced-moderation PWRs and BWRs (RMPWRs and RBWRs). RMPWRs have the advantage of relatively rapid implementation and intrinsically low conversion ratios. However, it is challenging to simultaneously satisfy operational and fuel cycle constraints. An RBWR may potentially take longer to implement than an RMPWR due to more extensive changes from current BWR technology. However, the harder neutron spectrum can lead to favourable fuel cycle performance. A two-stage fuel cycle, where the first pass is Th-Pu MOX, is a technically reasonable implementation of either concept. The first stage of the fuel cycle can therefore be implemented at relatively low cost as a Pu disposal option, with a further policy option of full recycle in the medium term. (authors)

  9. A miniature fuel cell with monolithically fabricated Si electrodes - Reduction of residual porous Si on catalyst layer

    NASA Astrophysics Data System (ADS)

    Kobayashi, Masahiro; Suzuki, Takahiro; Hayase, Masanori

    2014-12-01

    Higher performance was obtained in our miniature fuel cells by reducing the residual porous Si on catalyst layers. We have developed a miniature polymer electrolyte fuel cell by forming monolithic Si electrodes with MEMS techniques, in which a catalyst layer was synthesized on a Si chip by modifying porous Si to porous Pt by a wet plating process. As a result of technical limitations in the fabrication process, porous Si was left on the porous Pt catalyst layer. The residual porous Si was intended to lower the fuel cell performance by blocking reactant gas supply, and the effect of the residual porous Si on fuel cell performance was studied. The anodization conditions for porous Si formation were varied, and several prototype fuel cells were prepared with residual porous Si of different thickness. It was confirmed that a thick residual porous Si layer reduced cell performance, and high power density comparable to conventional large scale fuel cells was obtained with the least residual porous Si.

  10. SPS Fabrication of Tungsten-Rhenium Alloys in Support of NTR Fuels Development

    SciTech Connect

    Jonathan A. Webb; Indrajit Charit; Cory Sparks; Darryl P. Butt; Megan Frary; Mark Carroll

    2011-02-01

    Abstract. Tungsten metal slugs were fabricated via Spark Plasma Sintering (SPS) of powdered metals at temperatures ranging from 1575 K to 1975 K and hold times of 5 minutes to 30 minutes, using powders with an average diameter of 7.8 ?m. Sintered tungsten specimens were found to have relative densities ranging from 83 % to 94 % of the theoretical density for tungsten. Consolidated specimens were also tested for their Vickers Hardness Number (VHN), which was fitted as a function of relative density; the fully consolidated VHN was extrapolated to be 381.45 kg/mm2. Concurrently, tungsten and rhenium powders with average respective diameters of 0.5 ?m and 13.3 ?m were pre-processed either by High-Energy-Ball-Milling (HEBM) or by homogeneous mixing to yield W-25at.%Re mixtures. The powder batches were sintered at temperatures of 1975 K and 2175 K for hold times ranging from 0 minutes to 60 minutes yielding relative densities ranging from 94% to 97%. The combination of HEBM and sintering showed a significant decrease in the inter-metallic phases compared to that of the homogenous mixing and sintering.

  11. Fabrication of phase-change chalcogenide Ge2Sb2Te5 patterns by laser-induced forward transfer.

    PubMed

    Tseng, Ming Lun; Chen, Bo Han; Chu, Cheng Hung; Chang, Chia Min; Lin, Wei Chih; Chu, Nien-Nan; Mansuripur, Masud; Liu, Ai Qun; Tsai, Din Ping

    2011-08-29

    Femtosecond laser pulses are focused on a thin film of Ge2Sb2Te5 phase-change material, and the transfer of the illuminated material to a nearby substrate is investigated. The size, shape, and phase-state of the fabricated pattern can be effectively controlled by the laser fluence and by the thickness of the Ge2Sb2Te5 film. Results show multi-level electrical and optical reflection states of the fabricated patterns, which may provide a simple and efficient foundation for patterning future phase-change devices. PMID:21935057

  12. Analytical fuel property effects: Small combustors, phase 2

    NASA Technical Reports Server (NTRS)

    Hill, T. G.; Monty, J. D.; Morton, H. L.

    1985-01-01

    The effects of non-standard aviation fuels on a typical small gas turbine combustor were studied and the effectiveness of design changes intended to counter the effects of these fuels was evaluated. The T700/CT7 turboprop engine family was chosen as being representative of the class of aircraft power plants desired for this study. Fuel properties, as specified by NASA, are characterized by low hydrogen content and high aromatics levels. No. 2 diesel fuel was also evaluated in this program. Results demonstrated the anticipated higher than normal smoke output and flame radiation intensity with resulting increased metal temperatures on the baseline T700 combustor. Three new designs were evaluated using the non standard fuels. The three designs incorporated enhanced cooling features and smoke reduction features. All three designs, when burning the broad specification fuels, exhibited metal temperatures at or below the baseline combustor temperatures on JP-5. Smoke levels were acceptable but higher than predicted.

  13. 10 CFR 72.236 - Specific requirements for spent fuel storage cask approval and fabrication.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... REQUIREMENTS FOR THE INDEPENDENT STORAGE OF SPENT NUCLEAR FUEL, HIGH-LEVEL RADIOACTIVE WASTE, AND REACTOR-RELATED GREATER THAN CLASS C WASTE Approval of Spent Fuel Storage Casks § 72.236 Specific requirements for... storage cask, maximum heat designed to be dissipated, maximum spent fuel loading limit, condition of...

  14. Effect of fabrication technique on direct methanol fuel cells designed to operate at low airflow

    NASA Technical Reports Server (NTRS)

    Valdez, T. I.; Narayanan, S. R.

    2002-01-01

    This study investigates the effects of catalyst ink constituents and MEA fabrication techniques on improving cell performance. Particular attention was focused on increasing the overall cell efficiency.

  15. XeF2 vapor phase silicon etch used in the fabrication of movable SOI structures.

    SciTech Connect

    Wiwi, M.; Sanchez, Carlos Anthony; Plut, Thomas Alvin; Salazar, M.; Stevens, Jeffrey; Bauer, Todd M.; Ford, C.; Shul, Randy John; Grossetete, Grant David

    2010-10-01

    Vapor phase XeF{sub 2} has been used in the fabrication of various types of devices including MEMS, resonators, RF switches, and micro-fluidics, and for wafer level packaging. In this presentation we demonstrate the use of XeF{sub 2} Si etch in conjunction with deep reactive ion etch (DRIE) to release single crystal Si structures on Silicon On Insulator (SOI) wafers. XeF{sub 2} vapor phase etching is conducive to the release of movable SOI structures due to the isotropy of the etch, the high etch selectivity to silicon dioxide (SiO{sub 2}) and fluorocarbon (FC) polymer etch masks, and the ability to undercut large structures at high rates. Also, since XeF{sub 2} etching is a vapor phase process, stiction problems often associated with wet chemical release processes are avoided. Monolithic single crystal Si features were fabricated by etching continuous trenches in the device layer of an SOI wafer using a DRIE process optimized to stop on the buried SiO{sub 2}. The buried SiO{sub 2} was then etched to handle Si using an anisotropic plasma etch process. The sidewalls of the device Si features were then protected with a conformal passivation layer of either FC polymer or SiO{sub 2}. FC polymer was deposited from C4F8 gas precursor in an inductively coupled plasma reactor, and SiO{sub 2} was deposited by plasma enhanced chemical vapor deposition (PECVD). A relatively high ion energy, directional reactive ion etch (RIE) plasma was used to remove the passivation film on surfaces normal to the direction of the ions while leaving the sidewall passivation intact. After the bottom of the trench was cleared to the underlying Si handle wafer, XeF{sub 2} was used to isotropically etch the handle Si, thus undercutting and releasing the features patterned in the device Si layer. The released device Si structures were not etched by the XeF{sub 2} due to protection from the top SiO{sub 2} mask, sidewall passivation, and the buried SiO{sub 2} layer. Optimization of the XeF{sub 2

  16. Large-scale controlled fabrication of highly roughened flower-like silver nanostructures in liquid crystalline phase

    PubMed Central

    Yang, Chengliang; Xiang, Xiangjun; Zhang, Ying; Peng, Zenghui; Cao, Zhaoliang; Wang, Junlin; Xuan, Li

    2015-01-01

    Large-scale controllable fabrication of highly roughened flower-like silver nanostructures is demonstrated experimentally via electrodeposition in the liquid crystalline phase. Different sizes of silver flowers are fabricated by adjusting the deposition time and the concentration of the silver nitrate solution. The density of the silver flowers in the sample is also controllable in this work. The flower-like silver nanostructures can serve as effective surface-enhanced Raman scattering and surface-enhanced fluorescence substrates because of their local surface plasmon resonance, and they may have applications in photoluminescence and catalysis. This liquid crystalline phase is used as a soft template for fabricating flower-like silver nanostructures for the first time, and this approach is suitable for large-scale uniform fabrication up to several centimetres. PMID:26216669

  17. Low NOx heavy fuel combustor concept program, phase 1

    NASA Technical Reports Server (NTRS)

    Cutrone, M. B.

    1981-01-01

    Combustion tests were completed with seven concepts, including three rich/lean concepts, three lean/lean concepts, and one catalytic combustor concept. Testing was conducted with ERBS petroleum distillate, petroleum residual, and SRC-II coal-derived liquid fuels over a range of operating conditions for the 12:1 pressure ratio General Electric MS7001E heavy-duty turbine. Blends of ERBS and SRC-II fuels were used to vary fuel properties over a wide range. In addition, pyridine was added to the ERBS and residual fuels to vary nitrogen level while holding other fuel properties constant. Test results indicate that low levels of NOx and fuel-bound nitrogen conversion can be achieved with the rich/lean combustor concepts for fuels with nitrogen contents up to 1.0% by weight. Multinozzle rich/lean Concept 2 demonstrated dry low Nox emissions within 10-15% of the EPA New Source Performance Standards goals for SRC-II fuel, with yields of approximately 15%, while meeting program goals for combustion efficiency, pressure drop, and exhaust gas temperature profile. Similar, if not superior, potential was demonstrated by Concept 3, which is a promising rich/lean combustor design.

  18. Fabrication of wafer-scale nanopatterned sapphire substrate through phase separation lithography

    NASA Astrophysics Data System (ADS)

    Guo, Xu; Ni, Mengyang; Zhuang, Zhe; Dai, Jiangping; Wu, Feixiang; Cui, Yushuang; Yuan, Changsheng; Ge, Haixiong; Chen, Yanfeng

    2016-04-01

    A phase separation lithography (PSL) based on polymer blend provides an extremely simple, low-cost, and high-throughput way to fabricate wafer-scale disordered nanopatterns. This method was introduced to fabricate nanopatterned sapphire substrates (NPSSs) for GaN-based light-emitting diodes (LEDs). The PSL process only involved in spin-coating of polystyrene (PS)/polyethylene glycol (PEG) polymer blend on sapphire substrate and followed by a development with deionized water to remove PEG moiety. The PS nanoporous network was facilely obtained, and the structural parameters could be effectively tuned by controlling the PS/PEG weight ratio of the spin-coating solution. 2-in. wafer-scale NPSSs were conveniently achieved through the PS nanoporous network in combination with traditional nanofabrication methods, such as O2 reactive ion etching (RIE), e-beam evaporation deposition, liftoff, and chlorine-based RIE. In order to investigate the performance of such NPSSs, typical blue LEDs with emission wavelengths of ~450 nm were grown on the NPSS and a flat sapphire substrate (FSS) by metal-organic chemical vapor deposition, respectively. The integral photoluminescence (PL) intensity of the NPSS LED was enhanced by 32.3 % compared to that of the FSS-LED. The low relative standard deviation of 4.7 % for PL mappings of NPSS LED indicated the high uniformity of PL data across the whole 2-in. wafer. Extremely simple, low cost, and high throughput of the process and the ability to fabricate at the wafer scale make PSL a potential method for production of nanopatterned sapphire substrates.

  19. Experimental clean combustor program, alternate fuels addendum, phase 2

    NASA Technical Reports Server (NTRS)

    Gleason, C. C.; Bahr, D. W.

    1976-01-01

    The characteristics of current and advanced low-emissions combustors when operated with special test fuels simulating broader range combustion properties of petroleum or coal derived fuels were studied. Five fuels were evaluated; conventional JP-5, conventional No. 2 Diesel, two different blends of Jet A and commercial aromatic mixtures - zylene bottoms and haphthalene charge stock, and a fuel derived from shale oil crude which was refined to Jet A specifications. Three CF6-50 engine size combustor types were evaluated; the standard production combustor, a radial/axial staged combustor, and a double annular combustor. Performance and pollutant emissons characteristics at idle and simulated takeoff conditions were evaluated in a full annular combustor rig. Altitude relight characteristics were evaluated in a 60 degree sector combustor rig. Carboning and flashback characteristics at simulated takeoff conditions were evaluated in a 12 degree sector combustor rig. For the five fuels tested, effects were moderate, but well defined.

  20. Fabrication and photoluminescence of strong phase-separated InGaN based nanopillar LEDs

    NASA Astrophysics Data System (ADS)

    Wang, Qiang; Zhu, Chuanrui; Zhou, Yufan; Wang, Xuesong; Liu, Baoli; Wang, Xuelin; Lv, Yuanjie; Feng, Zhihong; Xu, Xiangang; Ji, Ziwu

    2015-12-01

    A strong phase-separated InGaN/GaN multiple quantum well (MQW) light-emitting diode (LED) producing a blue-green dual-wavelength spectrum has been grown, and fabricated into two nanopillar array structures with different etching depths: one fabricated only on the p-GaN layer and the other penetrating through the active layers. Micro-photoluminescence (μ-PL) spectra have shown that compared with the as-grown (planar) LED, light extraction efficiency (LEE) is improved for both the shorter and the longer nanopillar array structures due to the increased light-extracting surface area and light-guiding effect, in contrast, internal quantum efficiency (IQE) is improved for only the longer one due to the relaxation of strain in the MQWs embedded in the nanopillars. Furthermore, the strain relaxation-induced peak blue-shift value is smaller for the green emission from In-rich quantum dots (QDs) than the blue emission from the InGaN matrix, and decreases for both the emissions with increasing temperature. The former is attributed to the quantum-confined Stark effect (QCSE) in the strong localized QDs of small size being smaller than in the InGaN matrix, the latter is due to the decrease of the thermal-mismatch strain in the MQWs with increasing temperature.

  1. Cotton fabrics treated with novel oxidic phases acting as effective smoke suppressants.

    PubMed

    Alongi, Jenny; Malucelli, Giulio

    2012-09-01

    Sol-gel processes have been applied to cotton fabrics in order to coat the fibres with a silica film, able to improve their thermo-oxidative resistance and their combustion behaviour under the irradiative heat flow of a cone calorimeter. To this aim, tetramethoxysilane, inorganic precursor of the silica phase, has been employed alone or coupled with species having either smoke suppressant features (namely, zinc oxide, zinc acetate dihydrate and zinc borate) or well known flame retardant properties (like ammonium pentaborate octahydrate, boron phosphate, ammonium polyphosphate and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide). In addition, the use of barium sulphate, which is a smoke suppressant and, at the same time, a flame retardant, has been investigated. Cone calorimetry turned out to be a suitable technique for assessing the flammability and smoke production of the treated fabrics (particularly when referring to total smoke release, smoke production rate and CO and CO2 yields). The composition and morphology of the deposited coatings, assessed by scanning electron microscopy, have been found to influence their combustion behaviour, as well as their thermal and thermo-oxidative stability evaluated by thermogravimetric analysis in nitrogen and air, respectively. PMID:24751038

  2. Design and fabrication of an optical probe with a phase filter for extended depth of focus.

    PubMed

    Xing, Jingchao; Kim, Junyoung; Yoo, Hongki

    2016-01-25

    The trade-off between spot size and depth of focus (DOF) often limits the performance of optical systems, such as optical coherence tomography and optical tweezers. Although researchers have proposed various methods to extend the DOF in free-space optics, many are difficult to implement in miniaturized optical probes due to space limitations. In this study, we present an optical probe with an extended DOF using a binary phase spatial filter (BPSF). The BPSF pattern was fabricated on the distal tip of an optical probe with a diameter of 1 mm by replica molding soft lithography, which can be easily implemented in a miniaturized optical probe due to its simple configuration. We optimized the BPSF pattern to enhance DOF, spot diameter, and light efficiency. To evaluate the fabricated endoscopic optical probe, we measured the three-dimensional point spread function of the BPSF probe and compared it with a probe without BPSF. The BPSF probe has a spot diameter of 3.56 μm and a DOF of 199.7 μm, while the probe without BPSF has a spot diameter of 3.69 μm and a DOF of 73.9 μm, representing a DOF gain of 2.7. We anticipate that this optical probe can be used in biomedical applications, including optical imaging and optical trapping techniques. PMID:26832486

  3. MATERIALS, FABRICATION, AND MANUFACTURING OF MICRO/NANOSTRUCTURED SURFACES FOR PHASE-CHANGE HEAT TRANSFER ENHANCEMENT

    SciTech Connect

    McCarthy, M; Gerasopoulos, K; Maroo, SC; Hart, AJ

    2014-07-23

    This article describes the most prominent materials, fabrication methods, and manufacturing schemes for micro- and nanostructured surfaces that can be employed to enhance phase-change heat transfer phenomena. The numerous processes include traditional microfabrication techniques such as thin-film deposition, lithography, and etching, as well as template-assisted and template-free nanofabrication techniques. The creation of complex, hierarchical, and heterogeneous surface structures using advanced techniques is also reviewed. Additionally, research needs in the field and future directions necessary to translate these approaches from the laboratory to high-performance applications are identified. Particular focus is placed on the extension of these techniques to the design of micro/nanostructures for increased performance, manufacturability, and reliability. The current research needs and goals are detailed, and potential pathways forward are suggested.

  4. Material synthesis and fabrication method development for intermediate temperature solid oxide fuel cells

    NASA Astrophysics Data System (ADS)

    Ding, Hanping

    of 0.1 Ω cm2, improved power density of 1535 mW cm-2 at 650 °C in hydrogen and good thermal-cycle stability. Furthermore, this novel nano-scale platinum current collector can be extensively applied to other cathode materials and cell structures while showing the capability of being scaled up for mass productions due to the easily operated spraying process. The SOFCs with metal oxide as anodes are usually electrolyte-supported design. This design requires relatively thick electrolyte of 300˜500 mum to support the entire cell, leading to significant ohmic resistance. Accordingly, high temperatures (800-900 °C) are needed to reduce the ohmic loss for high power outputs. Anode-supported designs may effectively reduce the ohmic loss with thin electrolyte membrane while lowering the operating temperatures. However, the anode-supported designs with metal oxides as anode materials are difficult to fabricate. In general, high sintering temperature is needed to co-fire the anode substrate/electrolyte assembly to densify the thin electrolyte, which in turn may induce the densification of the porous anode substrate, resulting in anode porosity loss. In this work, a ceramic anode supported SOFC based on perovksite oxide of La0.75Sr0.25Cr 0.5Mn0.5O3-delta (LSCM) has been prepared to evaluate the superiority of this new cell design. The cell exhibits the power density of 596 mW cm-2 and 381 mW cm-2 at 700 °C with wet hydrogen and methane as the fuel respectively, the highest performance up to date for the cells with metal oxide anodes at this temperature.

  5. Determination of alternative fuels combustion products: Phase 3 report

    SciTech Connect

    Whitney, K.A.

    1997-12-01

    This report describes the laboratory efforts to characterize particulate and gaseous exhaust emissions from a passenger vehicle operating on alternative fuels. Tests were conducted at room temperature (nominally 72 F) and 20 F utilizing the chassis dynamometer portion of the FTP for light-duty vehicles. Fuels evaluated include Federal RFG, LPG meeting HD-5 specifications, a national average blend of CNG, E85, and M85. Exhaust particulate generated at room temperature was further characterized to determine polynuclear aromatic content, trace element content, and trace organic constituents. For all fuels except M85, the room temperature particulate emission rate from this vehicle was about 2 to 3 mg/mile. On M85, the particulate emission rate was more than 6 mg/mile. In addition, elemental analysis of particulate revealed an order of magnitude more sulfur and calcium from M85 than any other fuel. The sulfur and calcium indicate that these higher emissions might be due to engine lubricating oil in the exhaust. For RFG, particulate emissions at 20 F were more than six times higher than at room temperature. For alcohol fuels, particulate emissions at 20 F were two to three times higher than at room temperature. For CNG and LPG, particulate emissions were virtually the same at 72 F and 20 F. However, PAH emissions from CNG and LPG were higher than expected. Both gaseous fuels had larger amounts of pyrene, 1-nitropyrene, and benzo(g,h,i)perylene in their emissions than the other fuels.

  6. A review of composite and metallic bipolar plates in proton exchange membrane fuel cell: Materials, fabrication, and material selection

    NASA Astrophysics Data System (ADS)

    Taherian, Reza

    2014-11-01

    Proton exchange membrane (PEM) fuel cells offer exceptional potential for a clean, efficient, and reliable power source. The bipolar plate (BP) is a key component in this device, as it connects each cell electrically, supplies reactant gases to both anode and cathode, and removes reaction products from the cell. BPs have primarily been fabricated from high-density graphite, but in recent years, much attention has been paid to develop the cost-effective and feasible alternative materials. Recently, two different classes of materials have been attracted attention: metals and composite materials. This paper offers a comprehensive review of the current researches being carried out on the metallic and composite BPs, covering materials and fabrication methods. In this research, the phenomenon of ionic contamination due to the release of the corrosion products of metallic BP and relative impact on the durability as well as performance of PEM fuel cells is extensively investigated. Furthermore, in this paper, upon several effective parameters on commercialization of PEM fuel cells, such as stack cost, weight, volume, durability, strength, ohmic resistance, and ionic contamination, a material selection is performed among the most common BPs currently being used. This material selection is conducted by using Simple Additive Weighting Method (SAWM).

  7. Polarization Sensitive THz TDS and Fabrication of Alignment Cells for Solution Phase THz Spectroscopy

    NASA Astrophysics Data System (ADS)

    George, Deepu Koshy

    sense that it makes use of the polarization state of THz pulse which is also the case for the alignment spectroscopy. PMOTS technique detects the rotation and change in ellipticity to the incident polarization from which the hall coefficients of the sample can be calculated. The final section deals with the fabrication of Dynamical Alignment Terahertz Spectroscopy cells for solution phase measurements. Design, fabrication and process optimization are detailed. Micro-fabrication based on optical lithography and SU-8 negative photoresist has been explored.

  8. Technology development for phosphoric acid fuel cell powerplant (phase 2)

    NASA Technical Reports Server (NTRS)

    Christner, L.

    1979-01-01

    The status of technology for the manufacturing and testing of 1200 sq. cm cell materials, components, and stacks for on-site integrated energy systems is assessed. Topics covered include: (1) preparation of thin layers of silicon carbide; (2) definition and control schemes for volume changes in phosphoric acid fuel cells; (3) preparation of low resin content graphite phenolic resin composites; (4) chemical corrosion of graphite-phenolic resin composites in hot phosphoric acid; (5) analysis of electrical resistance of composite materials for fuel cells; and (6) fuel cell performance and testing.

  9. Electron-beam synthesis of fuel in the gas phase

    NASA Astrophysics Data System (ADS)

    Ponomarev, A. V.; Holodkova, E. M.; Ershov, B. G.

    2012-09-01

    Electron-beam synthesis of liquid fuel from gaseous alkanes was upgraded for formation of conventional and alternative fuel from biomass or pyrolysis oil. Bio-feedstock conversion algorithm includes two consecutive stages: (1) initial macromolecules' transformation to low-molecular-weight intermediates; (2) transformation of these intermediates to stable fuel in gaseous alkanes' atmosphere. Radicals originated from alkanes participate in alkylation/hydrogenation of biomass intermediates. Chemical fixation of gaseous alkanes is amplified in the presence of biomass derivatives due to suppression of gas regeneration reactions, higher molar mass of reagents and lower volatility of radiolytic intermediates.

  10. Fuel cell power systems for remote applications. Phase 1 final report and business plan

    SciTech Connect

    1998-02-01

    The goal of the Fuel Cell Power Systems for Remote Applications project is to commercialize a 0.1--5 kW integrated fuel cell power system (FCPS). The project targets high value niche markets, including natural gas and oil pipelines, off-grid homes, yachts, telecommunication stations and recreational vehicles. Phase 1 includes the market research, technical and financial analysis of the fuel cell power system, technical and financial requirements to establish manufacturing capability, the business plan, and teaming arrangements. Phase 1 also includes project planning, scope of work, and budgets for Phases 2--4. The project is a cooperative effort of Teledyne Brown Engineering--Energy Systems, Schatz Energy Research Center, Hydrogen Burner Technology, and the City of Palm Desert. Phases 2 through 4 are designed to utilize the results of Phase 1, to further the commercial potential of the fuel cell power system. Phase 2 focuses on research and development of the reformer and fuel cell and is divided into three related, but potentially separate tasks. Budgets and timelines for Phase 2 can be found in section 4 of this report. Phase 2 includes: Task A--Develop a reformate tolerant fuel cell stack and 5 kW reformer; Task B--Assemble and deliver a fuel cell that operates on pure hydrogen to the University of Alaska or another site in Alaska; Task C--Provide support and training to the University of Alaska in the setting up and operating a fuel cell test lab. The Phase 1 research examined the market for power systems for off-grid homes, yachts, telecommunication stations and recreational vehicles. Also included in this report are summaries of the previously conducted market reports that examined power needs for remote locations along natural gas and oil pipelines. A list of highlights from the research can be found in the executive summary of the business plan.

  11. Results from a Field Trial of the Radio Frequency Based Cylinder Accountability and Tracking System at the Global Nuclear Fuel Americas Fuel Fabrication Facility

    SciTech Connect

    Fitzgerald, Peter; Laughter, Mark D; Martyn, Rose; Pickett, Chris A; Rowe, Nathan C; Younkin, James R; Shephard, Adam M

    2010-01-01

    The Cylinder Accountability and Tracking System (CATS) is a tool designed for use by the International Atomic Energy Agency (IAEA) to improve overall inspector efficiency through real-time unattended monitoring of cylinder movements, site specific rules-based event detection, and the capability to integrate many types of monitoring technologies. The system is based on the tracking of cylinder movements using (radio frequency) RF tags, and the collection of data, such as accountability weights, that can be associated with the cylinders. This presentation will cover the installation and evaluation of the CATS at the Global Nuclear Fuels (GNF) fuel fabrication facility in Wilmington, NC. This system was installed to evaluate its safeguards applicability, operational durability under operating conditions, and overall performance. An overview of the system design and elements specific to the GNF deployment will be presented along with lessons learned from the installation process and results from the field trial.

  12. Co-Rolled U10Mo/Zirconium-Barrier-Layer Monolithic Fuel Foil Fabrication Process

    SciTech Connect

    G. A. Moore; M. C. Marshall

    2010-01-01

    Integral to the current UMo fuel foil processing scheme being developed at Idaho National Laboratory (INL) is the incorporation of a zirconium barrier layer for the purpose of controlling UMo-Al interdiffusion at the fuel-meat/cladding interface. A hot “co-rolling” process is employed to establish a ~25-µm-thick zirconium barrier layer on each face of the ~0.3-mm-thick U10Mo fuel foil.

  13. CFD prediction of flow and phase distribution in fuel assemblies with spacers

    SciTech Connect

    Anglart, H.; Nylund, O.; Kurul, N.

    1995-09-01

    This paper is concerned with the modeling and computation of multi-dimensional two-phase flows in BWR fuel assemblies. The modeling principles are presented based on using a two-fluid model in which lateral interfacial effects are accounted for. This model has been used to evaluate the velocity fields of both vapor and liquid phases, as well as phase distribution, between fuel elements in geometries similar to BWR fuel bundles. Furthermore, this model has been used to predict, in a detailed mechanistic manner, the effects of spacers on flow and phase distribution between, and pressure drop along, fuel elements. The related numerical simulations have been performed using a CFD computer code, CFDS-FLOW3D.

  14. A novel approach to fabricating fuel compacts for the next generation nuclear plant (NGNP)

    NASA Astrophysics Data System (ADS)

    Pappano, P. J.; Burchell, T. D.; Hunn, J. D.; Trammell, M. P.

    2008-10-01

    The next generation nuclear plant (NGNP) is a combined complex of a very high temperature reactor (VHTR) and hydrogen production facility. The VHTR can have a prismatic or pebble bed design and is powered by TRISO fuel in the form of a fuel compact (prismatic) or pebble (pebble bed). The US is scheduled to build a demonstration VHTR at the Idaho National Laboratory site by 2020. The first step toward building of this facility is development and qualification of the fuel for the reactor. This paper summarizes the research and development efforts performed at Oak Ridge National Laboratory (ORNL) toward development of a qualified fuel compact for a VHTR.

  15. Program for refan JT8D engine design, fabrication and test, phase 2

    NASA Technical Reports Server (NTRS)

    Glass, J. A.; Zimmerman, E. S.; Scaramella, V. M.

    1975-01-01

    The objective of the JT8D refan program was to design, fabricate, and test certifiable modifications of the JT8D engine which would reduce noise generated by JT8D powered aircraft. This was to be accomplished without affecting reliability and maintainability, at minimum retrofit cost, and with no performance penalty. The mechanical design, engine performance and stability characteristics at sea-level and altitude, and the engine noise characteristics of the test engines are documented. Results confirmed the structural integrity of the JT8D-109. Engine operation was stable throughout the airplane flight envelope. Fuel consumption of the test engines was higher than that required to meet the goal of no airplane performance penalty, but the causes were identified and corrected during a normal pre-certification engine development program. Compared to the baseline JT8D-109 engine, the acoustically treated JT8D-109 engine showed noise reductions of 6 PNdB at takeoff and 11 PNdB at a typical approach power setting.

  16. Micro solid oxide fuel cell fabricated on porous stainless steel: a new strategy for enhanced thermal cycling ability

    PubMed Central

    Kim, Kun Joong; Park, Byung Hyun; Kim, Sun Jae; Lee, Younki; Bae, Hongyeul; Choi, Gyeong Man

    2016-01-01

    Miniaturized solid oxide fuel cells (micro-SOFCs) are being extensively studied as a promising alternative to Li batteries for next generation portable power. A new micro-SOFC is designed and fabricated which shows enhanced thermal robustness by employing oxide-based thin-film electrode and porous stainless steel (STS) substrate. To deposit gas-tight thin-film electrolyte on STS, nano-porous composite oxide is proposed and applied as a new contact layer on STS. The micro-SOFC fabricated on composite oxide- STS dual layer substrate shows the peak power density of 560 mW cm−2 at 550 °C and maintains this power density during rapid thermal cycles. This cell may be suitable for portable electronic device that requires high power-density and fast thermal cycling. PMID:26928921

  17. Micro solid oxide fuel cell fabricated on porous stainless steel: a new strategy for enhanced thermal cycling ability.

    PubMed

    Kim, Kun Joong; Park, Byung Hyun; Kim, Sun Jae; Lee, Younki; Bae, Hongyeul; Choi, Gyeong Man

    2016-01-01

    Miniaturized solid oxide fuel cells (micro-SOFCs) are being extensively studied as a promising alternative to Li batteries for next generation portable power. A new micro-SOFC is designed and fabricated which shows enhanced thermal robustness by employing oxide-based thin-film electrode and porous stainless steel (STS) substrate. To deposit gas-tight thin-film electrolyte on STS, nano-porous composite oxide is proposed and applied as a new contact layer on STS. The micro-SOFC fabricated on composite oxide- STS dual layer substrate shows the peak power density of 560 mW cm(-2) at 550 °C and maintains this power density during rapid thermal cycles. This cell may be suitable for portable electronic device that requires high power-density and fast thermal cycling. PMID:26928921

  18. Micro solid oxide fuel cell fabricated on porous stainless steel: a new strategy for enhanced thermal cycling ability

    NASA Astrophysics Data System (ADS)

    Kim, Kun Joong; Park, Byung Hyun; Kim, Sun Jae; Lee, Younki; Bae, Hongyeul; Choi, Gyeong Man

    2016-03-01

    Miniaturized solid oxide fuel cells (micro-SOFCs) are being extensively studied as a promising alternative to Li batteries for next generation portable power. A new micro-SOFC is designed and fabricated which shows enhanced thermal robustness by employing oxide-based thin-film electrode and porous stainless steel (STS) substrate. To deposit gas-tight thin-film electrolyte on STS, nano-porous composite oxide is proposed and applied as a new contact layer on STS. The micro-SOFC fabricated on composite oxide- STS dual layer substrate shows the peak power density of 560 mW cm-2 at 550 °C and maintains this power density during rapid thermal cycles. This cell may be suitable for portable electronic device that requires high power-density and fast thermal cycling.

  19. Mulled coal: A beneficiated coal form for use as a fuel or fuel intermediate. Phase 3, Final report

    SciTech Connect

    Not Available

    1993-08-01

    Energy International Corporation (El) was awarded a contract to evaluate a new concept for utilization of the fine coal wetcake produced by many of the physical beneficiation processes now under development. EI proposed development of a stabilized wetcake with properties that would facilitate storage, handling, transport, and subsequent conversion of the material into Coal-Water Fuel (CWF) at the point of use. The effort was performed in three phases. Phase I established the technical feasibility of stabilizing the fine coal ``wetcake`` in a form that can be readily handled and converted into a desired fuel form at the combustion site. The preferred form of stabilized ``wetcake`` was a granular free flowing material with the moisture encapsulated with the fine coal particles. The product was termed Mulled Coal. Phase I results indicated that the Mulled Coal was not only suitable as a CWF intermediate, but also had potential as a solid fuel. Phase II demonstrated the utilization of the Mulled Coal process to store and move fine coal products as a stable ``wetcake.`` Tasks in this phase tested components of the various systems required for storage, handling and combustion of the fine coals. Phase III expanded the technology by: 1. Evaluating Mulled Coal from representative coals from all producing regions in the US. 2. Development of bench-scale tests. 3. Design, construction, and operation of a 1 ton/hr continuous processing unit. 4. Evaluation of the effects of beneficiation. and 5. Developing an estimate of capital and operating costs for commercial units.

  20. Development of carbon slurry fuels for transportation (hybrid fuels, phase 2)

    NASA Technical Reports Server (NTRS)

    Ryan, T. W., III; Dodge, L. G.

    1984-01-01

    Slurry fuels of various forms of solids in diesel fuel are developed and evaluated for their relative potential as fuel for diesel engines. Thirteen test fuels with different solids concentrations are formulated using eight different materials. A variety of properties are examined including ash content, sulfur content, particle size distribution, and rheological properties. Attempts are made to determine the effects of these variations on these fuel properties on injection, atomization, and combustion processes. The slurries are also tested in a single cylinder CLR engine in both direct injection and prechamber configurations. The data includes the normal performance parameters as well as heat release rates and emissions. The slurries perform very much like the baseline fuel. The combustion data indicate that a large fraction (90 percent or more) of the solids are burning in the engine. It appears that the prechamber engine configuration is more tolerant of the slurries than the direct injection configuration.

  1. Gas phase dynamics of laser-generated nanoparticle populations and its application to nanomaterials fabrication

    NASA Astrophysics Data System (ADS)

    Bulut, Mevlut

    Naturally occurring materials often derive their outstanding properties from optimal anisotropic arrangements of nanoscale constituents. This requires a hierarchical organization of matter over several length scales, which is difficult to achieve in artificial materials made by conventional physical and chemical methods. This dissertation explores the combination of laser and aerosol processes as a novel approach to make thin film materials with a level of microscopic organization similar to that found in nature. Through a systematic investigation of the behavior of the gas-phase dynamics of nanoparticles generated by laser ablation of solid target materials in background gases and a study of the physical processes involved in gas-phase nanoparticle processing, a new instrument integrating a laser ablation source and an aerosol spectrometer was designed and implemented. Film deposition and nanoparticle deposition processes can be manipulated independently affording greater flexibility for materials fabrication than other laser methods. The integrated laser-aerosol method is very flexible and can be used in the synthesis of a variety of materials. In this dissertation it is applied to the deposition of nanocomposite thin films comprising tetrahedral amorphous carbon (ta-C) with embedded metal nanoparticles. The controlled incorporation of metal nanoparticles enables the modulation of the electrical conductivity of ta-C over four orders of magnitude without significantly or adversely affecting its mechanical properties.

  2. Design, fabrication, and testing of an external fuel (UO2), full-length thermionic converter

    NASA Technical Reports Server (NTRS)

    Schock, A.; Raab, B.

    1971-01-01

    The development of a full-length external-fuel thermionic converter for in-pile testing is described. The development program includes out-of-pile performance testing of the fully fueled-converter, using RF-induction heating, before its installation in the in-pile test capsule. The external-fuel converter is cylindrical in shape, and consists of an inner, centrally cooled collector, and an outer emitter surrounded by nuclear fuel. The term full-length denotes that the converter is long enough to extend over the full height of the reactor core. Thus, the converter is not a scaled-down test device, but a full-scale fuel element of the thermionic reactor. The external-fuel converter concept permits a number of different design options, particularly with respect to the fuel composition and shape, and the collector cooling arrangement. The converter described was developed for the Jet Propulsion Laboratory, and is based on their concept for a thermionic reactor with uninsulated collector cooling as previously described. The converter is double-ended, with through-flow cooling, and with ceramic seals and emitter and collector power take-offs at both ends. The design uses a revolver-shaped tungsten emitter body, with the central emitter hole surrounded by six peripheral fuel holes loaded with cylindrical UO2 pellets.

  3. A new fabrication route for SFR fuel using (U, Pu)O2 powder obtained by oxalic co-conversion

    NASA Astrophysics Data System (ADS)

    Vaudez, Stéphane; Belin, Renaud C.; Aufore, Laurence; Sornay, Philippe; Grandjean, Stéphane

    2013-11-01

    The standard powder metallurgy preparation of SFR (Sodium Fast Reactor) oxide fuel involves UO2 and PuO2 co-milling. An alternative route, using a solid-solution of mixed oxide obtained by oxalic co-conversion as the starting material, is presented. It was used to manufacture nuclear fuels for the "COPIX" irradiation conducted in the Phenix SFR. Two processes using co-converted powders were tested to elaborate fuel pellets: (1) the Direct Process that consists in pressing and sintering the mixed oxide with the final Pu content and (2) the Dilution Process, which involves the dilution of a high Pu content mixed oxide with UO2. After studying the structural and microstructural evolution with temperature of these innovative raw materials, the elaboration parameters were adjusted to obtain final pellets in accordance with the Phenix fuel specifications. This study demonstrates the feasibility of such new fabrication route at laboratory scale and, from a more fundamental prospect, allows a better understanding of the underlying phenomena involved during sintering.

  4. Fabrication of defect-free full-field pixelated phase mask

    NASA Astrophysics Data System (ADS)

    Cheng, Wen-Hao; Farnsworth, Jeff; Kwok, Wai; Jamieson, Andrew; Wilcox, Nathan; Vernon, Matt; Yung, Karmen; Liu, Yi-Ping; Kim, Jun; Frendberg, Eric; Chegwidden, Scott; Schenker, Richard; Borodovsky, Yan

    2008-03-01

    Pixelated phase masks rendered from computational lithography techniques demand one generation-ahead mask technology development. In this paper, we reveal the accomplishment of fabricating Cr-less, full field, defect-free pixilated phase masks, including integration of tapeout, front-end patterning and backend defect inspection, repair, disposition and clean. This work was part of a comprehensive program within Intel which demonstrated microprocessor device yield. To pattern mask pixels with lateral sizes <100nm and vertical depth of 170nm, tapeout data management, ebeam write time management, aggressive pattern resolution scaling, etch improvement, new tool insertion and process integration were co-optimized to ensure good linearity of lateral, vertical dimensions and sidewall angle of glass pixels of arbitrary pixelated layout, including singlets, doublets, triplets, touch-corners and larger scale features of structural tones including pit/trench and pillar/mesa. The final residual systematic mask patterning imperfections were corrected and integrated upstream in the optical model and design layout. The volume of 100nm phase pixels on a full field reticle is on the order tera-scale magnitude. Multiple breakthroughs in backend mask technology were required to achieve a defect free full field mask. Specifically, integration of aerial image-based defect inspection, 3D optical model-based high resolution ebeam repair and disposition were introduced. Significant reduction of pixel mask specific defect modes, such as electro static discharge and glass pattern collapse, were executed to drive defect level down to single digit before attempt of repair. The defect printability and repair yield were verified downstream through silicon wafer print test to validate defect free mask performance.

  5. Analytical fuel property effects, small combustors, phase 1

    NASA Technical Reports Server (NTRS)

    Cohen, J. D.

    1983-01-01

    The effects of nonstandard aviation fuels on a typical small gas turbine combustor was analyzed. The T700/CT7 engine family was chosen as being representative of the class of aircraft power plants desired. Fuel properties, as specified by NASA, are characterized by low hydrogen content and high aromatics levels. Higher than normal smoke output and flame radiation intensity for the current T700 combustor which serves as a baseline were anticipated. It is, therefore, predicted that out of specification smoke visibility and higher than normal shell temperatures will exist when using NASA ERBS fuels with a consequence of severe reduction in cyclic life. Three new designs are proposed to compensate for the deficiencies expected with the existing design. They have emerged as the best of the eight originally proposed redesigns or combinations thereof. After the five choices that were originally made by NASA on the basis of competing performance factors, General Electric narrowed the field to the three proposed.

  6. 30 CFR 250.917 - What are the CVA's primary duties during the fabrication phase?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... major modification to ensure that it has been built according to the approved design and the fabrication plan. If the CVA finds that fabrication procedures are changed or design specifications are modified...) Confirm or deny compliance with the design specifications and the approved fabrication plan; (5) In...

  7. 30 CFR 250.917 - What are the CVA's primary duties during the fabrication phase?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... major modification to ensure that it has been built according to the approved design and the fabrication plan. If the CVA finds that fabrication procedures are changed or design specifications are modified...) Confirm or deny compliance with the design specifications and the approved fabrication plan; (5) In...

  8. Technology Development for Phosphoric Acid Fuel Cell Powerplant, Phase 2

    NASA Technical Reports Server (NTRS)

    Christner, L.

    1980-01-01

    The technology development for materials, cells, and reformers for on site integrated energy systems is described. The carbonization of 25 cu cm, 350 cu cm, and 1200 cu cm cell test hardware was accomplished and the performance of 25 cu cm fuel cells was improved. Electrochemical corrosion rates of graphite/phenolic resin composites in phosphoric acid were determined. Three cells (5 in by 15 in stacks) were operated for longer than 7000 hours. Specified endurance stacks completed a total of 4000 hours. An electrically heated reformer was tested and is to provide hydrogen for 23 cell fuel cell stack.

  9. Determination of alternative fuels combustion products: Phase 1 report

    SciTech Connect

    Whitney, K.A.

    1997-09-01

    This report describes the laboratory effort to identify and quantify organic exhaust species generated from alternative-fueled light-duty vehicles operating over the Federal Test Procedure on compressed natural gas, liquefied petroleum gas, methanol, ethanol, and reformulated gasoline. The exhaust species from these vehicles were identified and quantified for fuel/air equivalence ratios of 0.8, 1.0, and 1.2, nominally, and were analyzed with and without a vehicle catalyst in place to determine the influence of a catalytic converter on species formation.

  10. Microscale phase change of fuels for MEMS power applications

    NASA Astrophysics Data System (ADS)

    Haendler, Brenda

    As portable electronics technology advances, systems are becoming smaller and more energy intensive. While batteries are currently the only commercial power source for these applications, work is being done to create liquid fuel based portable power packs. These systems would leverage the higher energy density (W-hr/l) and specific energy (W-hr/kg) of liquid hydrocarbon fuels over available battery chemistries. For micro engines and small fuels cells there are advantages to preheating and vaporizing the fuel in a microchannel. The work presented in this dissertation focuses on understanding and characterizing the temperature and pressure signatures that result from microscale boiling of fuels in etched silicon channels approximately 100 mm in diameter. Building on previous microscale boiling work which used water as the working fluid for electronics cooling applications, the studies presented in this dissertation use both water and fuels including methanol, ethanol, and octane. Results are presented in the form of pressure and temperature measurements for a range of working fluids, volumetric flow rates, superheat temperatures and channel geometries. From a Fourier transform analysis of the pressure signatures, it was found that the frequency of the pressure fluctuations increases with superheat for ethanol as the working fluid while for methanol the frequency increases with volumetric flow rate. Tests were also conducted with sudden expansion geometries, which reduce the amplitude of the pressure fluctuations and create a localized cooling in the working fluid. Results are compared using fluid properties, including surface tension and heat of vaporization, and non-dimensional numbers including the Weber and the Jakob number. This study presents a significant contribution to the body of knowledge on microscale boiling. One application of microscale boiling for portable power technologies is also presented. Fuel cracking, breaking apart of long hydrocarbon chain

  11. Surfactant-free alternative fuel: Phase behavior and diffusion properties.

    PubMed

    Kayali, Ibrahim; Jyothi, Chemboli K; Qamhieh, Khawla; Olsson, Ulf

    2016-02-01

    Phase behavior of the three components, 1-propanol, water and oil is studied at 10, 25, and 40°C. Biodiesel, limonene and diesel are used as oil phases. NMR self-diffusion measurements are performed to investigate the microstructure of the one-phase regions. Tie lines in the two-phase regions are determined both by proton NMR analysis and compared with theoretical calculations. NMR self-diffusion results for the different components in these systems do not show any sign of confinement or obstructions, demonstrating these mixtures to be structureless solutions. A good agreement between the experimental and calculated phase behavior is obtained. The determined tie lines in the two-phase regions show higher affinity of 1-propanol to water than to oil. PMID:26520824

  12. Status Report on the Fabrication of Fuel Cladding Chemical Interaction Test Articles for ATR Irradiations

    SciTech Connect

    Field, Kevin G.; Howard, Richard H.

    2015-09-28

    FeCrAl alloys are a promising new class of alloys for light water reactor (LWR) applications due to their superior oxidation and corrosion resistance in high temperature environments. The current R&D efforts have focused on the alloy composition and processing routes to generate nuclear grade FeCrAl alloys with optimized properties for enhanced accident tolerance while maintaining properties needed for normal operation conditions. Therefore, the composition and processing routes must be optimized to maintain the high temperature steam oxidation (typically achieved by increasing the Cr and Al content) while still exhibiting properties conducive to normal operation in a LWR (such as radiation tolerance where reducing Cr content is favorable). Within this balancing act is the addition of understanding the influence on composition and processing routes on the FeCrAl alloys for fuel-cladding chemical interactions (FCCI). Currently, limited knowledge exists on FCCI for the FeCrAl-UO2 clad-fuel system. To overcome the knowledge gaps on the FCCI for the FeCrAl-UO2 clad-fuel system a series of fueled irradiation tests have been developed for irradiation in the Advanced Test Reactor (ATR) housed at the Idaho National Laboratory (INL). The first series of tests has already been reported. These tests used miniaturized 17x17 PWR fuel geometry rodlets of second-generation FeCrAl alloys fueled with industrial Westinghouse UO2 fuel. These rodlets were encapsulated within a stainless steel housing.To provide high fidelity experiments and more robust testing, a new series of rodlets have been developed deemed the Accident Tolerant Fuel Experiment #1 Oak Ridge National Laboratory FCCI test (ATF-1 ORNL FCCI). The main driving factor, which is discussed in detail, was to provide a radiation environment where prototypical fuel-clad interface temperatures are met while still maintaining constant contact between industrial fuel and the candidate cladding alloys

  13. NASA Broad Specification Fuels Combustion Technology program - Pratt and Whitney Aircraft Phase I results and status

    NASA Technical Reports Server (NTRS)

    Lohmann, R. P.; Fear, J. S.

    1982-01-01

    In connection with increases in the cost of fuels and the reduced availability of high quality petroleum crude, a modification of fuel specifications has been considered to allow acceptance of poorer quality fuels. To obtain the information upon which a selection of appropriate fuels for aircraft can be based, the Broad Specification Fuels Combustion Technology program was formulated by NASA. A description is presented of program-related investigations conducted by an American aerospace company. The specific objective of Phase I of this program has been to evaluate the impact of the use of broadened properties fuels on combustor design through comprehensive combustor rig testing. Attention is given to combustor concepts, experimental evaluation, results obtained with single stage combustors, the stage combustor concept, and the capability of a variable geometry combustor.

  14. Fabrication and characterization of a fuel flexible micro-reformer fully integrated in silicon for micro-solid oxide fuel cell applications

    NASA Astrophysics Data System (ADS)

    Pla, D.; Salleras, M.; Garbayo, I.; Morata, A.; Sabaté, N.; Divins, N. J.; Llorca, J.; Tarancón, A.

    2015-05-01

    A novel design of a fuel-flexible micro-reactor for hydrogen generation from ethanol and methane is proposed in this work. The micro-reactor is fully fabricated with mainstream MEMS technology and consists of an array of more than 20000 through-silicon vertically aligned micro-channels per cm2 of 50 μm in diameter. Due to this unique configuration, the micro-reformer presents a total surface per projected area of 16 cm2/cm2 and per volume of 320 cm2/cm3. The active surface of the micro-reformer, i.e. the walls of the micro-channels, is homogenously coated with a thin film of Rh- Pd/CeO2 catalyst. Excellent steam reforming of ethanol and dry reforming of methane are presented with hydrogen production rates above 3 mL/min·cm2 and hydrogen selectivity of ca. 50% on a dry basis at operations conditions suitable for application in micro-solid oxide fuel cells (micro-SOFCs), i.e. 700-800ºC and fuel flows of 0.02 mLL/min for ethanol and 36 mLG/min for methane (corresponding to a system able to produce one electrical watt).

  15. DEMONSTRATION OF FUEL CELLS TO RECOVER ENERGY FROM LANDFILL GAS: PHASE II. PRETREATMENT SYSTEM PERFORMANCE MEASUREMENT

    EPA Science Inventory

    The report describes-Phase II of a demonstration of the utilization of commercial phosphoric acid fuel cells to recover energy from landfill gas. his phase consisted primarily of the construction and testing of a Gas Pretreatment Unit (GPU) whose function is to remove those impur...

  16. DEMONSTRATION OF FUEL CELLS TO RECOVER ENERGY FROM LANDFILL GAS: PHASE II. PRETREATMENT SYSTEM PERFORMANCE MEASUREMENT

    EPA Science Inventory

    The report describes Phase II of a demonstration of the utilization of commercial phosphoric acid fuel cells to recover energy from landfill gas. This phase consisted primarily of the construction and testing of a Gas Pretreatment Unit (GPU) whose function is to remove those impu...

  17. Facile Fabrication of Graphene-Containing Foam as a High-Performance Anode for Microbial Fuel Cells.

    PubMed

    Yang, Lu; Wang, Shuqin; Peng, Shuqin; Jiang, Hongmei; Zhang, Youming; Deng, Wenfang; Tan, Yueming; Ma, Ming; Xie, Qingji

    2015-07-20

    Facile fabrication of novel three-dimensional anode materials to increase the bacterial loading capacity and improve substrate transport in microbial fuel cells (MFCs) is of great interest and importance. Herein, a novel graphene-containing foam (GCF) was fabricated easily by freeze-drying and pyrolysis of a graphene oxide-agarose gel. Owing to the involvement of graphene and stainless-steel mesh in the GCF, the GCF shows high electrical conductivity, enabling the GCF to be a conductive electrode for MFC applications. With the aid of agarose, the GCF electrode possesses a supermacroporous structure with pore sizes ranging from 100-200 μm and a high surface area, which greatly increase the bacterial loading capacity. Cell viability measurements indicate that the GCF possesses excellent biocompatibility. The MFC, equipped with a 0.4 mm-thick GCF anode, shows a maximum area power density of 786 mW m(-2) , which is 4.1 times that of a MFC equipped with a commercial carbon cloth anode. The simple fabrication route in combination with the outstanding electrochemical performance of the GCF indicates a promising anode for MFC applications. PMID:26095648

  18. Fabrication of mixed phase TiO2 heterojunction nanorods and their enhanced photoactivities.

    PubMed

    Tiwari, Amritanjali; Mondal, Indranil; Ghosh, Saptarshi; Chattopadhyay, Nitin; Pal, Ujjwal

    2016-06-01

    Substantial efforts have been made in recent times in solving the major limiting factors affecting the efficiency of a photocatalyst. The fabrication of efficient junction architectures is one of the viable approaches to resolve this setback. We have developed a facile and systematic approach for the synthesis of anatase TiO2 () nanoparticles and 1-D anatase and rutile TiO2 () heterojunction nanorods to enhance the interfacial contact area by adjusting the titanium(iv) butoxide (TBOT) to titanium chloride (TiCl4) volume ratio. Their narrower band gap, increasing surface area and anatase phase composition engineered by adjusting the relative concentrations of titanium butoxide (TBOT) and titanium chloride (TiCl4) (TBOT/TiCl4, 1 : 0, 1 : 0.25, 1 : 1 and 1 : 4 v/v for , , and respectively) are also addressed. The materials showed impressive photocatalytic activity for H2 evolution from water/methanol and the photodegradation of organic pollutants like rhodamine B (RhB) and methylene blue (MB) dyes. showed superior activity (16.4 mmol g(-1) h(-1)) with an apparent quantum efficiency (AQE) of 7.7% together with its long-term stability. This is attributed to the synergistic effect observed in the mixed phase nanorod heterojunction photocatalyst. Methyl viologen (MV(2+)) has been used as a probe to elucidate the photocatalytic activities and highlight the heterojunction driven separation of photo-excited charge carriers for enhanced hydrogen production. PMID:27212470

  19. Fabrication of a superhydrophobic surface from porous polymer using phase separation

    NASA Astrophysics Data System (ADS)

    Liu, Jianfeng; Xiao, Xinyan; Shi, Yinlong; Wan, Caixia

    2014-04-01

    The present work reports a simple method to fabricate superhydrophobic porous polymeric surfaces by a phase separation process. The method involves the in situ polymerization of butyl methacrylate (BMA) and ethylene dimethacrylate (EDMA) in the presence of co-porogens of 1,4-butanediol (BDO) and N-methyl-2-pyrrolidone (NMP) to afford superhydrophobic surfaces with the micro/nano roughness structure. The influences of the polymerization mixture on the morphology and hydrophobicity were investigated by adjusting the composition of the co-porogens and the mass ratio of monomers to co-porogens, respectively. And a precise description of the underlying mechanism of the microstructure formation was presented. The as-prepared surface shows a superhydrophobicity with water contact angle (WCA) of 159.5° and low sliding angle (SA) of 3.1°. Moreover, the superhydrophobic surface shows good chemical stability with better resistance to acid, alkali or salt aqueous solutions and excellent thermal stability. The method is simple and low-cost and can be used for the preparation of the self-cleaning superhydrophobic surfaces.

  20. New insights in Microbial Fuel Cells: novel solid phase anolyte.

    PubMed

    Tommasi, Tonia; Salvador, Gian Paolo; Quaglio, Marzia

    2016-01-01

    For the development of long lasting portable microbial fuel cells (MFCs) new strategies are necessary to overcome critical issues such as hydraulic pump system and the biochemical substrate retrieval overtime to sustain bacteria metabolism. The present work proposes the use of a synthetic solid anolyte (SSA), constituted by agar, carbonaceous and nitrogen sources dissolved into diluted seawater. Results of a month-test showed the potential of the new SSA-MFC as a long lasting low energy consuming system. PMID:27375205

  1. New insights in Microbial Fuel Cells: novel solid phase anolyte

    PubMed Central

    Tommasi, Tonia; Salvador, Gian Paolo; Quaglio, Marzia

    2016-01-01

    For the development of long lasting portable microbial fuel cells (MFCs) new strategies are necessary to overcome critical issues such as hydraulic pump system and the biochemical substrate retrieval overtime to sustain bacteria metabolism. The present work proposes the use of a synthetic solid anolyte (SSA), constituted by agar, carbonaceous and nitrogen sources dissolved into diluted seawater. Results of a month-test showed the potential of the new SSA-MFC as a long lasting low energy consuming system. PMID:27375205

  2. New insights in Microbial Fuel Cells: novel solid phase anolyte

    NASA Astrophysics Data System (ADS)

    Tommasi, Tonia; Salvador, Gian Paolo; Quaglio, Marzia

    2016-07-01

    For the development of long lasting portable microbial fuel cells (MFCs) new strategies are necessary to overcome critical issues such as hydraulic pump system and the biochemical substrate retrieval overtime to sustain bacteria metabolism. The present work proposes the use of a synthetic solid anolyte (SSA), constituted by agar, carbonaceous and nitrogen sources dissolved into diluted seawater. Results of a month-test showed the potential of the new SSA-MFC as a long lasting low energy consuming system.

  3. Fabrication of Fiber-Optic Tilted Bragg Grating Filter in 40 nm Range with A Single Phase Mask

    NASA Technical Reports Server (NTRS)

    Grant, Joseph; Wang, Y.; Sharma, A.; Burdine, Robert V. (Technical Monitor)

    2002-01-01

    Fiber-optic Bragg grating filters are fabricated with a range of Bragg wavelength between 1296 and 1336 nm, using a single phase mask. 30 mW of continuous-wave light at 244 nm is used from a frequency-doubled argon-ion laser having an intracavity etalon. Gratings are fabricated by tilting the photosensitive fiber with respect to the phase mask up to an angle of 15 degrees. The variation of Bragg wavelength with the fiber-tilt is explained with a simple formula. High spatial coherence of 244 nm light makes it possible to displace the fiber as much as 6 mm in front of the phase mask and tilt the fiber by as much as 15 degrees. This results in nearly constant band-width and near 100% reflectively for all gratings throughout the 40 nm range.

  4. Low temperature fabrication & photocatalytical activity of carbon fiber-supported TiO2 with different phase compositions.

    PubMed

    Wang, Zhifeng; Yoshinaga, Kohji; Bu, Xiu R; Zhang, Ming

    2015-06-15

    Crystalline TiO2 nanoparticles with different phase compositions were fabricated on carbon fibers. The fabrication is achieved at low temperature. The process includes the treatment of Ti(OH)4 with hydrogen peroxide in the presence of carbon fibers. Neither additional acids nor bases, or additives are used during the process. Carbon fibers prior to and after TiO2 loading are characterized by FE-SEM, XRD, and UV-vis absorption spectroscopy. The photocatalytic activity was assessed via photocatalytic degradation of methyl orange solution, and found to be phase composition-dependent & pH dependent. Carbon fibers loaded with mixed-phase TiO2 led to the best photocatalytic performance. HRTEM reveals the anatase/rutile heterojunction which helps explain the high efficiency of photocatalysis. They have been demonstrated to be re-usable in the continuous photocatalytic degradation process. PMID:25791498

  5. McDonnell 40-kW Giromill Wind System. Phase II. Fabrication and test

    SciTech Connect

    Brulle, R

    1980-06-01

    A 40 kW vertical axis windmill called a ''Giromill'' was fabricated, erected, and tested. The system design is described as well as some design changes made during fabrication. Manufacturing cost estimates are updated. Fabrication of the turbine blades, support arms, and fixed and rotating tower is described as well as the tests. Testing included control systems acceptance tests; Giromill system acceptance tests; structural, mechanical, control system and electric generation operational tests; and performance tests connected to the utility grid. (LEW)

  6. Two-Phase PIV: Fuel-Spray Interaction with Surrounding Air

    NASA Astrophysics Data System (ADS)

    Dankers, Stefan; Gotthardt, Mark; Stengler, Thomas; Ohmstede, Gerhard; Hentschel, Werner

    The demand for improvement of combustion-engine processes leads to a great need for detailed experimental information about the complicated processes of injection, breakup and propagation of the fuel jet and the vaporization of the fuel. Thus, in the presented work it was the aim to visualize the air flow that is induced by the injected fuel jet and also to explore the air entrainment into the fuel spray. This was done using two-phase PIV (particle image velocimetry). The fuel jet was illuminated with a Nd:YAG PIV-laser and PIV analysis was done by simply measuring the elastically scattered light of the fuel droplets. For the investigation of the surrounding air propylene-carbonate doped with DCM-dye was dispersed and the droplets were added to the continuous gas flow upstream of the chamber. Scattered and fluorescence signals, respectively, were detected perpendicular to the laser sheet with a CCD camera. To detect the gas flow, the scattered light from the liquid fuel was suppressed by an OG 590 longpass filter glass that transmits the fluorescence signal of the DCM-dye. It was possible to measure both the fuel jet and the gas flow in the presence of the fuel spray and a clear separation of the two phases could be achieved. In both (fuel and air) vector pictures corresponding vortices could be identified near the air/fuel boundary layer. Maximum velocities in the jet are depending on the operation conditions up to 150ms-1 and the gas flow has typically a velocity of 1 to 10ms-1. In the region next to the injector the air was pressed away during the injection. After the end of the injection a strong fast air entrainment flow into this region can be observed that compensates the pressure difference.

  7. 30 CFR 250.917 - What are the CVA's primary duties during the fabrication phase?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... CVA must . . . (1) For all fixed platforms and non-ship-shaped floating facilities Make periodic... appropriate: (i) Quality control by lessee and builder; (ii) Fabrication site facilities; (iii) Material quality and identification methods; (iv) Fabrication procedures specified in the approved plan,...

  8. Phase-induced amplitude apodization complex mask coronagraph mask fabrication, characterization, and modeling for WFIRST-AFTA

    NASA Astrophysics Data System (ADS)

    Kern, Brian; Guyon, Olivier; Belikov, Ruslan; Wilson, Daniel; Muller, Richard; Sidick, Erkin; Balasubramanian, Bala; Krist, John; Poberezhskiy, Ilya; Tang, Hong

    2016-01-01

    This work describes the fabrication, characterization, and modeling of a second-generation occulting mask for a phase-induced amplitude apodization complex mask coronagraph, designed for use on the WFIRST-AFTA mission. The mask has many small features (˜micron lateral scales) and was fabricated at the Jet Propulsion Laboratory Microdevices Laboratory, then characterized using a scanning electron microscope, atomic force microscope, and optical interferometric microscope. The measured fabrication errors were then fed to a wavefront control model which predicts the contrast performance of a full coronagraph. The expected coronagraphic performance using this mask is consistent with observing ˜15 planetary targets with WFIRST-AFTA in a reasonable time (<1 day/target).

  9. Life Cycle Assessment of Vehicle Lightweighting: Novel Mathematical Methods to Estimate Use-Phase Fuel Consumption.

    PubMed

    Kim, Hyung Chul; Wallington, Timothy J; Sullivan, John L; Keoleian, Gregory A

    2015-08-18

    Lightweighting is a key strategy to improve vehicle fuel economy. Assessing the life-cycle benefits of lightweighting requires a quantitative description of the use-phase fuel consumption reduction associated with mass reduction. We present novel methods of estimating mass-induced fuel consumption (MIF) and fuel reduction values (FRVs) from fuel economy and dynamometer test data in the U.S. Environmental Protection Agency (EPA) database. In the past, FRVs have been measured using experimental testing. We demonstrate that FRVs can be mathematically derived from coast down coefficients in the EPA vehicle test database avoiding additional testing. MIF and FRVs calculated for 83 different 2013 MY vehicles are in the ranges 0.22-0.43 and 0.15-0.26 L/(100 km 100 kg), respectively, and increase to 0.27-0.53 L/(100 km 100 kg) with powertrain resizing to retain equivalent vehicle performance. We show how use-phase fuel consumption can be estimated using MIF and FRVs in life cycle assessments (LCAs) of vehicle lightweighting from total vehicle and vehicle component perspectives with, and without, powertrain resizing. The mass-induced fuel consumption model is illustrated by estimating lifecycle greenhouse gas (GHG) emission benefits from lightweighting a grille opening reinforcement component using magnesium or carbon fiber composite for 83 different vehicle models. PMID:26168234

  10. Fabrication and performance of a miniaturized 64-element high-frequency endoscopic phased array.

    PubMed

    Bezanson, Andre; Adamson, Rob; Brown, Jeremy

    2014-01-01

    We have developed a 40-MHz, 64-element phased-array transducer packaged in a 2.5 x 3.1 mm endoscopic form factor. The array is a forward-looking semi-kerfed design based on a 0.68Pb(Mg(1/3)Nb(2/3))O(3) - 0.32PbTiO3 (PMN-32%PT) single-crystal wafer with an element-to-element pitch of 38 µm. To achieve a miniaturized form factor, a novel technique of wire bonding the array elements to a polyimide flexible circuit board oriented parallel to the forward looking ultrasound beam and perpendicular to the array was developed. A technique of partially dicing into the back of the array was also implemented to improve the directivity of the array elements. The array was fabricated with a single-layer P(VDF-TrFE)-copolymer matching layer and a polymethylpentene (TPX) lens for passive elevation focusing to a depth of 7 mm. The two-way -6-dB pulse bandwidth was measured to be 55% and the average electromechanical coupling (k(eff)) for the individual elements was measured to be 0.62. The one-way -6-dB directivities from several array elements were measured to be ±20°, which was shown to be an improvement over an identical kerfless array. The -3-dB elevation focus resulting from the TPX lens was measured to be 152 µm at the focal depth, and the focused lateral resolution was measured to be 80 µm at a steering angle of 0°. To generate beam profiles and images, the probe was connected to a commercial ultrasound imaging platform which was reprogrammed to allow for phased array transmit beamforming and receive data collection. The collected RF data were then processed offline using a numerical computing script to generate sector images. The radiation pattern for the beamformed transmit pulse was collected along with images of wire phantoms in water and tissue-equivalent medium with a dynamic range of 60 dB. Finally, ex vivo tissue images were generated of porcine brain tissue. PMID:24402894

  11. Fabrication of thin yttria-stabilized-zirconia dense electrolyte layers by inkjet printing for high performing solid oxide fuel cells

    NASA Astrophysics Data System (ADS)

    Esposito, Vincenzo; Gadea, Christophe; Hjelm, Johan; Marani, Debora; Hu, Qiang; Agersted, Karsten; Ramousse, Severine; Jensen, Søren Højgaard

    2015-01-01

    In this work, we present how a low-cost HP Deskjet 1000 inkjet printer was used to fabricate a 1.2 μm thin, dense and gas tight 16 cm2 solid oxide fuel cells (SOFC) electrolyte. The electrolyte was printed using an ink made of highly diluted (<4 vol.%) nanometric yttria stabilized zirconia (YSZ) powders (50 nm in size) in an aqueous medium. The ink was designed to be a highly dispersed, long term stable colloidal suspension, with optimal printability characteristics. The electrolyte was made by a multiple printing procedure, which ensures coverage of the several flaws occurring in a single printing pass. Together with an optimized sintering procedure this resulted in good adhesion and densification of the electrolyte. The SOFC exhibited a close-to-theoretical open circuit voltage and a remarkable peak power density above 1.5 W cm-2 at 800 °C.

  12. Design and evaluation of improved barrier fabrics for protection against toxic aerosols and biological agents. Phase 2. Final report, January 1993-December 1994

    SciTech Connect

    Hersh, S.P.; Tucker, P.A.

    1995-05-01

    The ultimate objective of this research is to develop semipermeable barrier fabrics which provide better protection for chemical protective clothing applications. In order to understand the relationship between the aerosol particle penetration and the structure of barrier fabrics, the research activities in Phase I focused on measuring the transmission of aerosols through test fabrics, determining the penetration mechanisms, and evaluating the pore size distributions in the fabrics. Based on the knowledge gained in Phase I, a set of 32 fabrics was designed, fabricated, and evaluated in Phase II using a 2-level, 7-factor, statistical design. Five additional outer fabrics and a carbon foam liner supplied by the U.S. Army Natick RDE Center (Natick) were evaluated to provide further insights into the effect of dual layers of fabrics and their relative orientations on aerosol penetration. The results of this research have been described in a Doctoral Dissertation by Dr. Surinder M. Maini (based on the 32 statistically designed fabrics) 1 and in a Master of Science thesis by Ms. Amelia Tosti 2 (on the fabrics supplied by Natick) in accordance with the research proposal. Abstracts of these two documents are presented in Section 2.0. The rest of this report describes the work and results conducted during Phase II. pg14. JMD.

  13. TRIGA FUEL PHASE I AND II CRITICALITY CALCULATION

    SciTech Connect

    L. Angers

    1999-11-23

    The purpose of this calculation is to characterize the criticality aspect of the codisposal of TRIGA (Training, Research, Isotopes, General Atomic) reactor spent nuclear fuel (SNF) with Savannah River Site (SRS) high-level waste (HLW). The TRIGA SNF is loaded into a Department of Energy (DOE) standardized SNF canister which is centrally positioned inside a five-canister defense SRS HLW waste package (WP). The objective of the calculation is to investigate the criticality issues for the WP containing the five SRS HLW and DOE SNF canisters in various stages of degradation. This calculation will support the analysis that will be performed to demonstrate the viability of the codisposal concept for the Monitored Geologic Repository (MGR).

  14. Technology development for phosphoric acid fuel cell powerplant, phase 2

    NASA Technical Reports Server (NTRS)

    Christner, L.

    1981-01-01

    The development of materials, cell components, and reformers for on site integrated energy systems is described. Progress includes: (1) heat-treatment of 25 sq cm, 350 sq cm and 1200 sq cm cell test hardware was accomplished. Performance of fuel cells is improved by using this material; (2) electrochemical and chemical corrosion rates of heat-treated and as-molded graphite/phenolic resin composites in phosphoric acid were determined; (3) three cell, 5 in. x 15 in. stacks operated for up to 10,000 hours and 12 in. x 17 in. five cell stacks were tested for 5,000 hours; (4) a three cell 5 in. x 15 in. stack with 0.12 mg Pt/sq cm anodes and 0.25 mg Pt/sq cm cathodes was operated for 4,500 hours; and (5) an ERC proprietary high bubble pressure matrix, MAT-1, was tested for up to 10,000 hours.

  15. Determination of alternative fuels combustion products: Phase 2 final report

    SciTech Connect

    Whitney, K.A.

    1997-06-01

    This report describes the laboratory efforts to accomplish four independent tasks: (1) speciation of hydrocarbon exhaust emissions from a light-duty vehicle operated over the chassis dynamometer portion of the light-duty FTP after modifications for operation on butane and butane blends; (2) evaluation of NREL`s Variable Conductance Vacuum Insulated Catalytic Converter Test Article 4 for the reduction of cold-start FTP exhaust emissions after extended soak periods for a Ford FFV Taurus operating on E85; (3) support of UDRI in an attempt to define correlations between engine-out combustion products identified by SwRI during chassis dynamometer testing, and those found during flow tube reactor experiments conducted by UDRI; and (4) characterization of small-diameter particulate matter from a Ford Taurus FFV operating in a simulated fuel-rich failure mode on CNG, LPG, M85, E85, and reformulated gasoline. 22 refs., 18 figs., 17 tabs.

  16. CONVERSION OF RUSSIAN WEAPON-GRADE PLUTONIUM INTO OXIDE FOR MIXED OXIDE (MOX) FUEL FABRICATION.

    SciTech Connect

    Glagovski, E.; Kolotilov, Y.; Glagolenko, Y.; Zygmunt, Stanley J.; Mason, C. F. V.; Hahn, W. K.; Durrer, R. E.; Thomas, S.; Sicard, B.; Herlet, N.; Fraize, G.; Villa, A.

    2001-01-01

    Progress has been made in the Russian Federation towards the conversion of weapons-grade plutonium (w-Pu) into plutonium oxide (PuO{sub 2}) suitable for further manufacture into mixed oxide (MOX) fuels. This program is funded both by French Commissariat x 1'Energie Atomique (CEA) and the US National Nuclear Security Administration (NNSA). The French program was started as a way to make available their expertise gained from manufacturing MOX fuel. The US program was started in 1998 in response to US proliferation concerns and the acknowledged international need to decrease available w-Pu. Russia has selected both the conversion process and the manufacturing site. This paper discusses the present state of development towards fulfilling this mission: the demonstration plant designed to process small amounts of Pu and validate all process stages and the industrial plant that will process up to 5 metric tons of Pu per year.

  17. Miniature fuel cell with monolithically fabricated Si electrodes - Uniformity of Catalyst Layer Thickness -

    NASA Astrophysics Data System (ADS)

    Morisawa, Itsuki; Suzuki, Takahiro; Katayama, Noboru; Dowaki, Kiyoshi; Hayase, Masanori

    2014-11-01

    Uniformity of catalyst layer thickness was improved to obtained higher output with our miniature fuel cells. Though the miniature fuel cells demonstrated high power density about 500mW/cm2 with 1 mm2 reaction area, it was difficult to maintain the power density with larger reaction area and careful observation of the prototypes revealed that the porous Si layer, which should be etched away completely, remained on the channel bottoms. Nonuniform porous Pt catalyst layer thickness was suspicious for the residual porous Si, and rotation of the plating vessel in the Pt deposition process was performed to mitigate variation of the catalyst layer thickness. Though the power density was still low with larger reaction area, the larger output was successfully obtained with the vessel rotation.

  18. Fabrication of Yttria stabilized zirconia thin films on poroussubstrates for fuel cell applications

    SciTech Connect

    Leming, Andres

    2003-06-16

    A process for the deposition of yttria stabilized zirconia (YSZ) films, on porous substrates, has been developed. These films have possible applications as electrolyte membranes in fuel cells. The films were deposited from colloidal suspensions through the vacuum infiltration technique. Films were deposited on both fully sintered and partially sintered substrates. A critical cracking thickness for the films was identified and strategies are presented to overcome this barrier. Green film density was also examined, and a method for improving green density by changing suspension pH and surfactant was developed. A dependence of film density on film thickness was observed, and materials interactions are suggested as a possible cause. Non-shorted YSZ films were obtained on co-fired substrates, and a cathode supported solid oxide fuel cell was constructed and characterized.

  19. The NASA broad-specification fuels combustion technology program: An assessment of phase 1 test results

    NASA Technical Reports Server (NTRS)

    Fear, J. S.

    1983-01-01

    An assessment is made of the results of Phase 1 screening testing of current and advanced combustion system concepts using several broadened-properties fuels. The severity of each of several fuels-properties effects on combustor performance or liner life is discussed, as well as design techniques with the potential to offset these adverse effects. The selection of concepts to be pursued in Phase 2 refinement testing is described. This selection takes into account the relative costs and complexities of the concepts, the current outlook on pollutant emissions control, and practical operational problems.

  20. CERAMIC FUEL ELEMENT MATERIAL FOR A NEUTRONIC REACTOR AND METHOD OF FABRICATING SAME

    DOEpatents

    Duckworth, W.H.

    1957-12-01

    This patent relates to ceramic composition, and to neutronic reactor fuel elements formed therefrom. These ceramic elements have high density and excellent strength characteristics and are formed by conventional ceramic casting and sintering at a temperature of about 2700 deg F in a nitrogen atmosphere. The composition consists of silicon carbide, silicon, uranium oxide and a very small percentage of molybdenum. Compositions containing molybdenum are markedly stronger than those lacking this ingredient.

  1. Safeguards instrumentation for continuous unattended monitoring in plutonium fuel fabrication plants

    SciTech Connect

    Menlove, H.O.; Miller, M.C.; Ohtani, T.; Seya, M.; Takahashi, S.

    1993-06-01

    Nondestructive assay (NDA) systems have been developed for use in an automated mixed oxide fabrication facility. Unique features have been developed for the NDA systems to accommodate robotic sample handling and remote operation. In addition, the systems have been designed to obtain International Atomic Energy Agency inspection data without the need for an inspector at the facility at the time of the measurements. The equipment is being designed to operate continuously in an unattended mode with data storage for periods of up to one month. The design, performance characteristics, and authentication of the NDA systems are described. The data related to reliability, precision, and accuracy are presented.

  2. DEMONSTRATION OF FUEL CELLS TO RECOVER ENERGY FROM LANDFILL GAS - PHASE III. DEMONSTRATION TESTS - PHASE IV. GUIDELINES AND RECOMMENDATIONS- VOLUME 1. TECHNICAL REPORT

    EPA Science Inventory

    The report summarizes the results of a four-phase program to demonstrate that fuel cell energy recovery using a commercial phosphoric acid fuel cell is both environmentally sound and commercially feasible. Phase I, a conceptual design and evaluation study, addressed the technical...

  3. DEMONSTRATION OF FUEL CELLS TO RECOVER ENERGY FROM LANDFILL GAS - PHASE III. DEMONSTRATION TESTS - PHASE IV. GUIDELINES AND DEMONSTRATIONS - VOLUME 2. APPENDICES

    EPA Science Inventory

    The report summarizes the results of a four-phase program to demonstrate that fuel cell energy recovery using a commercial phosphoric acid fuel cell is both environmentally sound and commercially feasible. Phase I, a conceptual design and evaluation study, addressed the technical...

  4. Kaman 40-kW wind system. Phase II. Fabrication and tests. Volume II. Technical report

    SciTech Connect

    Howes, H; Perley, R

    1981-01-01

    A program is underway to design, fabricate and test a horizontal axis Wind Turbine Generator (WTG) capable of producing 40 kW electrical output power in a 20 mph wind. Results are presented of the program effort covering fabrication and testing of the Wing Turbine Generator designed earlier. A minimum of difficulties were experienced during fabrication and, after successful completion of Contractor tests through 20 mph winds, the WTG was shipped to Rocky Flats, assembled and operated there. The 40 kW WTG is presently undergoing extended tests at Rockwell's Rocky Flats test facility.

  5. Chemical reactions during ThO{sub 2} and ThO{sub 2}-UO{sub 2} fuel fabrication

    SciTech Connect

    Clayton, J.C.

    1994-08-01

    The chemical reactions that occur during the fabrication of fuel pellets for the Shipping port Light Water Breeder Reactor are discussed. These include (1) precipitation and pyrolysis of thorium oxalate, (2) precipitation, calcination, and hydrogen reduction of ammonium diuranate, (3) comminution, granulation with an organic binder, and cold compaction of ThO{sub 2} and ThO{sub 2}-UO{sub 2} powders, (4) decarburization of the organic binder in CO{sub 2} at temperature up to 925 C, and (5) sintering in moist hydrogen at temperature up to 1790 C. Thorium oxalate precipitation and pyrolysis temperatures were the primary process variables for controlling the resulting thoria powder properties. Coprecipitated metal sulfates were converted to transition metal sulfides during calcining - the conversion of thorium oxalate to thorium oxide. The critical variable for controlling the urania powder properties was the hydrogen reduction temperature. Thermodynamic analyses showed that the efficiency of carbon removal from cold-compacted ThO{sub 2} and ThO{sub 2}-UO{sub 2} pellets by CO{sub 2} oxidation increases with temperature and, at temperatures around 900 C, substantially complete oxidation of carbon to carbon monoxide gas should occur. The carbon content of the ThO{sub 2} and ThO{sub 2}-UO{sub 2} fuels was further reduced during the initial heating in the hydrogen sintering cycle through the formation of methane gas. Additions of water vapor to the hydrogen sintering atmosphere also aided in carbon removal.

  6. Development and fabrication of improved Schottky power diodes, phases I and II

    NASA Technical Reports Server (NTRS)

    Cordes, L. F.; Garfinkle, M.; Taft, E. A.

    1974-01-01

    Reproducible methods for the fabrication of silicon Schottky diodes were developed for the metals tungsten, aluminum, conventional platinum silicide and low temperature platinum silicide. Barrier heights and barrier lowering were measured permitting the accurate prediction of ideal forward and reverse diode performance. Processing procedures were developed which permit the fabrication of large area (approximately 1 sqcm) mesa-geometry power Schottky diodes with forward and reverse characteristics that approach theoretical values.

  7. Fabrication of 1/3 scale boron/epoxy booster thrust structure, phase 2

    NASA Technical Reports Server (NTRS)

    1974-01-01

    The design, materials, tooling, various manufacturing processes, quality control, test procedures, and results associated with the fabrication and testing of a 1/3 scale boron/epoxy, booster thrust structure are described. A complete two-dimensional truss type thrust structure, comprised of nine boron/epoxy tubular members and six apex fittings, was fabricated. This resulted in structurally representative flight hardware, and verified the manufacturing feasibility and projected weight savings (30%) for this type of structure.

  8. Design and fabrication of transmission quarter phase retarder at wavelength 1064 nm, using optical nanometric thin films

    NASA Astrophysics Data System (ADS)

    Moradi, Zahra; Jahanshah, Fariborz; Fallah, Hamid Reza; Haji Mahmoodzade, Morteza; Sahraee, Masoume; Zabolian, Hosein

    2016-08-01

    We designed and fabricated the transmission quarter-wave plate phase retarder at 1064 nm using optical nanometric thin films of silicon oxide and titanium oxide. Final design consists of 32 layers. Transmissions of polarizations are equal and ≥99 % and their phase difference is 90°. System consists of two 16 layers systems that coated with the same condition on BK7 glass substrates then attached together with optical glue. Electron beam evaporation method was used for depositing materials. Photo spectrometer was used for measuring transmission spectrum of system. Transmission of polarizations was ≥95 % and equal. A polarimeter was used for testing systems. Polarization of beam was circular.

  9. Fabrication and characterization of protonic-ceramic fuel cells and electrolysis cells utilizing infiltrated lanthanum nickelate electrodes

    NASA Astrophysics Data System (ADS)

    Babiniec, Sean M.

    High-temperature protonic ceramics (HTPCs) have gained interest as fuel cell and electrolysis cell electrolytes, as well as hydrogen separation membranes. The transport of hydrogen as opposed to oxygen results in several benefits and applications, including higher fuel efficiency, dehydrogenation of fuel streams, and hydrogen-based chemical synthesis. However, limited work has been done in the development of air/steam electrodes for these devices. This work presents the characterization of lanthanum nickelate, La 2NiO4+delta (LN), as a potential air/steam electrode material for use with BaCe0.2Zr0.7Y0.1O3-delta (BCZY27) HTPC electrolytes fabricated by the solid-state reactive sintering technique. Two types of devices were made; a symmetric cell used for electrode characterization, and a full fuel cell/electrolysis cell used for device performance characterization. The symmetric cell consists of a 1 mm thick BCZY27 substrate with identical air/steam electrodes on both sides. Air/steam electrodes were made by infiltrating ˜ 50 nm lanthanum nickelate nanoparticles into a BCZY27 porous backbone. The fuel cell/electrolysis cell consists of a 1mm thick Ni/BCZY27 anode support, a 25 mum thick BCZY27 electrolyte, and a 50 mum thick porous BCZY27 backbone infiltrated with lanthanum nickelate. Through symmetric cell testing, it was found that the electrode polarization resistance decreases with increasing oxygen content, indicating good oxygen reduction reaction characteristics. A minimum polarization resistance was found as 2.58 Ohm-cm2 in 3% humidied oxygen at 700 °C. Full cell testing revealed a peak power density of 27 mW-cm-2 at 700 °C. Hydrogen flux measurements were also taken in the both galvanic/post-galvanic and electrolytic operation. Galvanic/post-galvanic fluxes exhibit a very high faradaic efficiency. However, electrolytic hydrogen fluxes were much lower than the calculated hydrogen faradaic flux, indicating a different charge carrier other than protons is

  10. Hot Isostatic Press Manufacturing Process Development for Fabrication of RERTR Monolithic Fuel Plates

    SciTech Connect

    Crapps, Justin M.; Clarke, Kester D.; Katz, Joel D.; Alexander, David J.; Aikin, Beverly; Vargas, Victor D.; Montalvo, Joel D.; Dombrowski, David E.; Mihaila, Bogdan

    2012-06-06

    We use experimentation and finite element modeling to study a Hot Isostatic Press (HIP) manufacturing process for U-10Mo Monolithic Fuel Plates. Finite element simulations are used to identify the material properties affecting the process and improve the process geometry. Accounting for the high temperature material properties and plasticity is important to obtain qualitative agreement between model and experimental results. The model allows us to improve the process geometry and provide guidance on selection of material and finish conditions for the process strongbacks. We conclude that the HIP can must be fully filled to provide uniform normal stress across the bonding interface.

  11. Design, fabrication, and properties of 2-2 connectivity cement/polymer based piezoelectric composites with varied piezoelectric phase distribution

    PubMed Central

    Dongyu, Xu; Xin, Cheng; Banerjee, Sourav; Shifeng, Huang

    2014-01-01

    The laminated 2-2 connectivity cement/polymer based piezoelectric composites with varied piezoelectric phase distribution were fabricated by employing Lead Zirconium Titanate ceramic as active phase, and mixture of cement powder, epoxy resin, and hardener as matrix phase with a mass proportion of 4:4:1. The dielectric, piezoelectric, and electromechanical coupling properties of the composites were studied. The composites with large total volume fraction of piezoelectric phase have large piezoelectric strain constant and relative permittivity, and the piezoelectric and dielectric properties of the composites are independent of the dimensional variations of the piezoelectric ceramic layer. The composites with small total volume fraction of piezoelectric phase have large piezoelectric voltage constant, but also large dielectric loss. The composite with gradually increased dimension of piezoelectric ceramic layer has the smallest dielectric loss, and that with the gradually increased dimension of matrix layer has the largest piezoelectric voltage constant. The novel piezoelectric composites show potential applications in fabricating ultrasonic transducers with varied surface vibration amplitude of the transducer. PMID:25565725

  12. Design, fabrication, and properties of 2-2 connectivity cement/polymer based piezoelectric composites with varied piezoelectric phase distribution

    SciTech Connect

    Dongyu, Xu; Xin, Cheng; Shifeng, Huang; Banerjee, Sourav

    2014-12-28

    The laminated 2-2 connectivity cement/polymer based piezoelectric composites with varied piezoelectric phase distribution were fabricated by employing Lead Zirconium Titanate ceramic as active phase, and mixture of cement powder, epoxy resin, and hardener as matrix phase with a mass proportion of 4:4:1. The dielectric, piezoelectric, and electromechanical coupling properties of the composites were studied. The composites with large total volume fraction of piezoelectric phase have large piezoelectric strain constant and relative permittivity, and the piezoelectric and dielectric properties of the composites are independent of the dimensional variations of the piezoelectric ceramic layer. The composites with small total volume fraction of piezoelectric phase have large piezoelectric voltage constant, but also large dielectric loss. The composite with gradually increased dimension of piezoelectric ceramic layer has the smallest dielectric loss, and that with the gradually increased dimension of matrix layer has the largest piezoelectric voltage constant. The novel piezoelectric composites show potential applications in fabricating ultrasonic transducers with varied surface vibration amplitude of the transducer.

  13. Aerothermal modeling program, phase 2. Element C: Fuel injector-air swirl characterization

    NASA Technical Reports Server (NTRS)

    Mostafa, A. A.; Mongia, H. C.; Mcdonnell, V. G.; Samuelsen, G. S.

    1986-01-01

    The main objectives of the NASA-sponsored Aerothermal Modeling Program, Phase 2--Element C, are experimental evaluation of the air swirler interaction with a fuel injector in a simulated combustor chamber, assessment of the current two-phase models, and verification of the improved spray evaporation/dispersion models. This experimental and numerical program consists of five major tasks. Brief descriptions of the five tasks are given.

  14. Thermodynamic analysis of fuels in gas phase: ethanol, gasoline and ethanol - gasoline predicted by DFT method.

    PubMed

    Neto, A F G; Lopes, F S; Carvalho, E V; Huda, M N; Neto, A M J C; Machado, N T

    2015-10-01

    This paper presents a theoretical study using density functional theory to calculate thermodynamics properties of major molecules compounds at gas phase of fuels like gasoline, ethanol, and gasoline-ethanol mixture in thermal equilibrium on temperature range up to 1500 K. We simulated a composition of gasoline mixture with ethanol for a thorough study of thermal energy, enthalpy, Gibbs free energy, entropy, heat capacity at constant pressure with respect to temperature in order to study the influence caused by ethanol as an additive to gasoline. We used semi-empirical computational methods as well in order to know the efficiency of other methods to simulate fuels through this methodology. In addition, the ethanol influence through the changes in percentage fractions of chemical energy released in combustion reaction and the variations on thermal properties for autoignition temperatures of fuels was analyzed. We verified how ethanol reduces the chemical energy released by gasoline combustion and how at low temperatures the gas phase fuels in thermal equilibrium have similar thermodynamic behavior. Theoretical results were compared with experimental data, when available, and showed agreement. Graphical Abstract Thermodynamic analysis of fuels in gas phase. PMID:26386958

  15. Data collection plan for Phase 2 Alternative Fuels Bus Data Collection Program. Final report

    SciTech Connect

    Krenelka, T

    1993-07-01

    This document constitutes the plan for collecting and reporting data associated with a special set of transit bus demonstrations to be conducted under the Urban Bus Program of the Alternative Motor Fuels Act (AMFA) of 1988. This program, called the Phase 2 Bus Data Collection Program, serves as an adjunct to the Phase I Bus Data Collection Program, collecting detailed data on just a few buses to augment and enhance the Phase 1 data in fulfilling the urban bus requirements of AMFA. Demonstrations will be conducted at a few transit system locations throughout the US and will use alternative fuels and associated technologies to reduce undesirable transit bus exhaust emissions. Several organizations will be involved in the data collection; NREL will manage the program, analyze and store vehicle data, and make these data available through the Alternative Fuels Data Center. This information will enable transit agencies, equipment manufacturers, fuel suppliers, and government policy makers to make informed decisions about buying and using alternative fuels.

  16. Novel characterization of the aerosol and gas-phase composition of aerosolized jet fuel.

    PubMed

    Tremblay, Raphael T; Martin, Sheppard A; Fisher, Jeffrey W

    2010-04-01

    Few robust methods are available to characterize the composition of aerosolized complex hydrocarbon mixtures. The difficulty in separating the droplets from their surrounding vapors and preserving their content is challenging, more so with fuels, which contain hydrocarbons ranging from very low to very high volatility. Presented here is a novel method that uses commercially available absorbent tubes to measure a series of hydrocarbons in the vapor and droplets from aerosolized jet fuels. Aerosol composition and concentrations were calculated from the differential between measured total (aerosol and gas-phase) and measured gas-phase concentrations. Total samples were collected directly, whereas gas-phase only samples were collected behind a glass fiber filter to remove droplets. All samples were collected for 1 min at 400 ml min(-1) and quantified using thermal desorption-gas chromatography-mass spectrometry. This method was validated for the quantification of the vapor and droplet content from 4-h aerosolized jet fuel exposure to JP-8 and S-8 at total concentrations ranging from 200 to 1000 mg/m(3). Paired samples (gas-phase only and total) were collected every approximately 40 min. Calibrations were performed with neat fuel to calculate total concentration and also with a series of authentic standards to calculate specific compound concentrations. Accuracy was good when compared to an online GC-FID (gas chromatography-flame ionization detection) technique. Variability was 15% or less for total concentrations, the sum of all gas-phase compounds, and for most specific compound concentrations in both phases. Although validated for jet fuels, this method can be adapted to other hydrocarbon-based mixtures. PMID:20218763

  17. Metallizing porous scaffolds as an alternative fabrication method for solid oxide fuel cell anodes

    NASA Astrophysics Data System (ADS)

    Ruiz-Trejo, Enrique; Atkinson, Alan; Brandon, Nigel P.

    2015-04-01

    A combination of electroless and electrolytic techniques is used to incorporate nickel into a porous Ce0.9Gd0.1O1.90 scaffold. First a porous backbone was screen printed into a YSZ electrolyte using an ink that contains sacrificial pore formers. Once sintered, the scaffold was coated with silver using Tollens' reaction followed by electrodeposition of nickel in a Watts bath. At high temperatures the silver forms droplets enabling direct contact between the gadolinia-doped ceria and nickel. Using impedance spectroscopy analysis in a symmetrical cell a total area specific resistance of 1 Ωcm2 at 700 °C in 97% H2 with 3% H2O was found, indicating the potential of this fabrication method for scaling up.

  18. Aerosol size distribution in a uranium processing and fuel fabrication facility.

    PubMed

    Prasad, K Vishwa; Balbudhe, A Y; Srivastava, G K; Tripathi, R M; Puranik, V D

    2010-08-01

    In the nuclear fuel complex, magnesium diuranate is processed to produce UO(2) through different chemical and metallurgical processes. UO(2) powder is compacted to produce uranium pallets as fuel. International Commission on Radiological Protection has considered default particle size of 5-mum activity median aerodynamic diameter (AMAD) and 2.5 of geometric standard deviation (GSD) for working out dose coefficients. There is a likelihood of variation in the particle size during each stage of operation. The present study is undertaken to determine the prevailing uranium aerosol size distribution at every stage of operation using Anderson impactor with glass fibre filter paper as collection substrate. AMAD and respective GSD were determined. Aerosol size distribution was studied. Airborne uranium concentration was found to be higher for higher particle sizes in all areas. Average AMAD for different locations varied from 5.8 to 7.7 mum with GSD from 1.63 to 6.73 and the ratio of calculated ALI to standard varies from 1.13 to 1.55. PMID:20406743

  19. Strategy for decommissioning of the glove-boxes in the Belgonucleaire Dessel MOX fuel fabrication plant

    SciTech Connect

    Vandergheynst, Alain; Cuchet, Jean-Marie

    2007-07-01

    Available in abstract form only. Full text of publication follows: BELGONUCLEAIRE has been operating the Dessel plant from the mid-80's at industrial scale. In this period, over 35 metric tons of plutonium (HM) was processed into almost 100 reloads of MOX fuel for commercial West-European Light Water Reactors. In late 2005, the decision was made to stop the production because of the shortage of MOX fuel market remaining accessible to BELGONUCLEAIRE after the successive capacity increases of the MELOX plant (France) and the commissioning of the SMP plant (UK). As a significant part of the decommissioning project of this Dessel plant, about 170 medium-sized glove-boxes are planned for dismantling. In this paper, after having reviewed the different specifications of {+-}-contaminated waste in Belgium, the authors introduce the different options considered for cleaning, size reduction and packaging of the glove-boxes, and the main decision criteria (process, {alpha}-containment, mechanization and radiation protection, safety aspects, generation of secondary waste, etc) are analyzed. The selected strategy consists in using cold cutting techniques and manual operation in shielded disposable glove-tents, and packaging {alpha}-waste in 200-liter drums for off-site conditioning and intermediate disposal. (authors)

  20. Method of fabricating a monolithic core for a solid oxide fuel cell

    DOEpatents

    Zwick, Stanley A.; Ackerman, John P.

    1985-01-01

    A method is disclosed for forming a core for use in a solid oxide fuel cell that electrochemically combines fuel and oxidant for generating galvanic output. The core has an array of electrolyte and interconnect walls that are substantially devoid of any composite inert materials for support consisting instead only of the active anode, cathode, electrolyte and interconnect materials. Each electrolyte wall consists of cathode and anode materials sandwiching electrolyte material therebetween, and each interconnect wall consists of the cathode and anode materials sandwiching interconnect material therebetween. The electrolyte and interconnect walls define a plurality of substantially parallel core passageways alternately having respectively the inside faces thereof with only the anode material or with only the cathode material exposed. In the wall structure, the electrolyte and interconnect materials are only 0.002-0.01 cm thick; and the cathode and anode materials are only 0.002-0.05 cm thick. The method consists of building up the electrolyte and interconnect walls by depositing each material on individually and endwise of the wall itself, where each material deposit is sequentially applied for one cycle; and where the depositing cycle is repeated many times until the material buildup is sufficient to formulate the core. The core is heat cured to become dimensionally and structurally stable.

  1. NASA/General Electric broad-specification fuels combustion technology program - Phase I results and status

    NASA Technical Reports Server (NTRS)

    Dodds, W. J.; Ekstedt, E. E.; Bahr, D. W.; Fear, J. S.

    1982-01-01

    A program is being conducted to develop the technology required to utilize fuels with broadened properties in aircraft gas turbine engines. The first phase of this program consisted of the experimental evaluation of three different combustor concepts to determine their potential for meeting several specific emissions and performance goals, when operated on broadened property fuels. The three concepts were a single annular combustor; a double annular combustor; and a short single annular combustor with variable geometry. All of these concepts were sized for the General Electric CF6-80 engine. A total of 24 different configurations of these concepts were evaluated in a high pressure test facility, using four test fuels having hydrogen contents between 11.8 and 14%. Fuel effects on combustor performance, durability and emissions, and combustor design features to offset these effects were demonstrated.

  2. SPECIATION OF GAS-PHASE AND FINE PARTICLE EMISSIONS FROM BURNING OF FOLIAR FUELS: JOURNAL ARTICLE

    EPA Science Inventory

    NRMRL-RTP-P- 620 Hays**, M.D., Geron*, C.D., Linna**, K.J., Smith*, N.D., and Schauer, J.J. Speciation of Gas-Phase and Fine Particle Emissions from Burning of Foliar Fuels. Submitted to: Environmental Science & Technology EPA/600/J-02/234, http://pubs.acs.org/journals/esthag/...

  3. Effects of inoculum size on solid-phase fermentation of fodder beets for fuel ethanol production

    SciTech Connect

    Gibbons, W.R.; Westby, C.A.

    1986-10-01

    This fuel ethanol study examined the effects of Saccharomyces cerevisiae inoculum size on solid-phase fermentation of fodder beet pulp. A 5% inoculum (wt/wt) resulted in rapid yeast and ethanol (9.1% (vol/vol)) production. Higher inocula showed no advantages. Lower inocula resulted in lowered final yeast populations and increased fermentation times.

  4. Fabric phase sorptive extraction followed by UHPLC-MS/MS for the analysis of benzotriazole UV stabilizers in sewage samples.

    PubMed

    Montesdeoca-Esponda, Sarah; Sosa-Ferrera, Zoraida; Kabir, Abuzar; Furton, Kenneth G; Santana-Rodríguez, José Juan

    2015-10-01

    A fast and sensitive sample preparation strategy using fabric phase sorptive extraction followed by ultra-high-performance liquid chromatography and tandem mass spectrometry detection has been developed to analyse benzotriazole UV stabilizer compounds in aqueous samples. Benzotriazole UV stabilizer compounds are a group of compounds added to sunscreens and other personal care products which may present detrimental effects to aquatic ecosystems. Fabric phase sorptive extraction is a novel solvent minimized sample preparation approach that integrates the advantages of sol-gel derived hybrid inorganic-organic nanocomposite sorbents and the flexible, permeable and hydrophobic surface chemistry of polyester fabric. It is a highly sensitive, fast, efficient and inexpensive device that can be reused and does not suffer from coating damage, unlike SPME fibres or stir bars. In this paper, we optimized the extraction of seven benzotriazole UV filters evaluating the majority of the parameters involved in the extraction process, such as sorbent chemistry selection, extraction time, back-extraction solvent, back-extraction time and the impact of ionic strength. Under the optimized conditions, fabric phase sorptive extraction allows enrichment factors of 10 times with detection limits ranging from 6.01 to 60.7 ng L(-1) and intra- and inter-day % RSDs lower than 11 and 30 % for all compounds, respectively. The optimized sample preparation technique followed by ultra-high-performance liquid chromatography and tandem mass spectrometry detection was applied to determine the target analytes in sewage samples from wastewater treatment plants with different purification processes of Gran Canaria Island (Spain). Two UV stabilizer compounds were measured in ranges 17.0-60.5 ng mL(-1) (UV 328) and 69.3-99.2 ng mL(-1) (UV 360) in the three sewage water samples analysed. PMID:26345441

  5. Fabrication and microstructural analysis of UN-U3Si2 composites for accident tolerant fuel applications

    NASA Astrophysics Data System (ADS)

    Johnson, Kyle D.; Raftery, Alicia M.; Lopes, Denise Adorno; Wallenius, Janne

    2016-08-01

    In this study, U3Si2 was synthesized via the use of arc-melting and mixed with UN powders, which together were sintered using the SPS method. The study revealed a number of interesting conclusions regarding the stability of the system - namely the formation of a probable but as yet unidentified ternary phase coupled with the reduction of the stoichiometry in the nitride phase - as well as some insights into the mechanics of the sintering process itself. By milling the silicide powders and reducing its particle size ratio compared to UN, it was possible to form a high density UN-U3Si2 composite, with desirable microstructural characteristics for accident tolerant fuel applications.

  6. Method of Fabrication of High Power Density Solid Oxide Fuel Cells

    DOEpatents

    Pham, Ai Quoc; Glass, Robert S.

    2008-09-09

    A method for producing ultra-high power density solid oxide fuel cells (SOFCs). The method involves the formation of a multilayer structure cells wherein a buffer layer of doped-ceria is deposited intermediate a zirconia electrolyte and a cobalt iron based electrode using a colloidal spray deposition (CSD) technique. For example, a cobalt iron based cathode composed of (La,Sr)(Co,Fe)O(LSCF) may be deposited on a zirconia electrolyte via a buffer layer of doped-ceria deposited by the CSD technique. The thus formed SOFC have a power density of 1400 mW/cm.sup.2 at 600.degree. C. and 900 mW/cm.sup.2 at 700.degree. C. which constitutes a 2-3 times increased in power density over conventionally produced SOFCs.

  7. An ultra-fast fabrication technique for anode support solid oxide fuel cells by microwave

    NASA Astrophysics Data System (ADS)

    Jiao, Zhenjun; Shikazono, Naoki; Kasagi, Nobuhide

    An effective and facile technique has been developed for high temperature anode-electrolyte co-sintering of anode support solid oxide fuel cells by using microwave activated sparking plasma. A high sintering temperature of 1600 °C can be achieved in a few minutes time by discharging effect. Anode support substrate pellet is uniaxially pressed, and then dip-coated with a 10 μm yttria stabilized zirconia electrolyte layer. After the microwave co-sintering, La 0.8Sr 0.2MnO x cathode is screen-printed onto electrolyte and sintered by conventional thermal method. The cell has stably operated in 3% humidified hydrogen for more than 130 h.

  8. Miniature fuel cell with monolithically fabricated Si electrodes - Alloy catalyst formation -

    NASA Astrophysics Data System (ADS)

    Ogura, Daiki; Suzuki, Takahiro; Katayama, Noboru; Dowaki, Kiyoshi; Hayase, Masanori

    2013-12-01

    A novel Pd-Pt catalyst formation process was proposed for reduction of Pt usage. In our miniature fuel cells, porous Pt was used as the catalyst, and the Pt usage was quite high. To reduce the Pt usage, we have attempted to deposit Pt on porous Pd by galvanic replacement, and relatively large output was demonstrated. In this study, in order to reduce more Pt usage and explore the alloy catalyst formation process, atomic layer deposition by UPD-SLRR (Under Potential Deposition - Surface Limited Redox Replacement) was applied to the Pd-Pt catalyst formation. The new process was verified at each process steps by EDS elemental analysis, and the expected spectra were obtained. Prototype cells were constructed by the new process, and cell output was raised to 420mW/cm2 by the Pd-Pt catalyst from 125mW/cm2 with Pd catalyst.

  9. Method of fabricating an integral gas seal for fuel cell gas distribution assemblies

    DOEpatents

    Dettling, Charles J.; Terry, Peter L.

    1988-03-22

    A porous gas distribution plate assembly for a fuel cell, such as a bipolar assembly, includes an inner impervious region wherein the bipolar assembly has good surface porosity but no through-plane porosity and wherein electrical conductivity through the impervious region is maintained. A hot-pressing process for forming the bipolar assembly includes placing a layer of thermoplastic sealant material between a pair of porous, electrically conductive plates, applying pressure to the assembly at elevated temperature, and allowing the assembly to cool before removing the pressure whereby the layer of sealant material is melted and diffused into the porous plates to form an impervious bond along a common interface between the plates holding the porous plates together. The distribution of sealant within the pores along the surface of the plates provides an effective barrier at their common interface against through-plane transmission of gas.

  10. Integral gas seal for fuel cell gas distribution assemblies and method of fabrication

    DOEpatents

    Dettling, Charles J.; Terry, Peter L.

    1985-03-19

    A porous gas distribution plate assembly for a fuel cell, such as a bipolar assembly, includes an inner impervious region wherein the bipolar assembly has good surface porosity but no through-plane porosity and wherein electrical conductivity through the impervious region is maintained. A hot-pressing process for forming the bipolar assembly includes placing a layer of thermoplastic sealant material between a pair of porous, electrically conductive plates, applying pressure to the assembly at elevated temperature, and allowing the assembly to cool before removing the pressure whereby the layer of sealant material is melted and diffused into the porous plates to form an impervious bond along a common interface between the plates holding the porous plates together. The distribution of sealant within the pores along the surface of the plates provides an effective barrier at their common interface against through-plane transmission of gas.

  11. Application of rigorously optimized phase masks for the fabrication of binary and blazed gratings with diffractive proximity lithography

    NASA Astrophysics Data System (ADS)

    Stuerzebecher, Lorenz; Fuchs, Frank; Harzendorf, Torsten; Meyer, Stefan; Zeitner, Uwe D.

    2014-03-01

    Gratings with binary and blazed profiles and periods in the low micron and sub-micron range define a class of microstructures with a huge application potential. We present a mask based photolithographic fabrication method for these demanding grating geometries. It combines the advantages of electron beam lithography and holographic exposure, which are superior homogeneity, high resolution and pattern flexibility on one hand, and a fast, large aerial exposure with the option for smooth profiles on the other hand. This is accomplished by the use of an electron beam written phase mask which contains a very homogeneous pattern of diffractive features and is used for a full-field exposure in a proximity mask aligner. The key for the beneficial use of the technology is the proper design of the phase mask surface profile which can have a binary or multilevel geometry. Since the patterns to be exposed are periodic, this is also the case for the phase mask which allows calculating their physical light transmission with exact methods like rigorous coupled wave analysis. An optimization algorithm has been developed which can find mask geometries that synthesize a desired complex aerial image in the proximity distance of choice. Aerial images offering e.g. high resolution features, phase shifts, and tilted propagation directions can be realized that way. This technology has been successfully used to fabricate e.g. binary gratings of very high quality with a period of 800 nm as well as blazed gratings with a period of 3 μm.

  12. Chromium doped nano-phase separated yttria-alumina-silica glass based optical fiber preform: fabrication and characterization

    NASA Astrophysics Data System (ADS)

    Dutta, Debjit; Dhar, Anirban; Das, Shyamal; Bysakh, Sandip; Kir'yanov, Alexandar; Paul, Mukul Chandra

    2015-06-01

    Transition metal (TM) doping in silica core optical fiber is one of the research area which has been studied for long time and Chromium (Cr) doping specially attracts a lot of research interest due to their broad emission band covering U, C and L band with many potential application such as saturable absorber or broadband amplifier etc. This paper present fabrication of Cr doped nano-phase separated silica fiber within yttria-alumina-silica core glass through conventional Modified Chemical Vapor Deposition (MCVD) process coupled with solution doping technique along with different material and optical characterization. For the first time scanning electron microscope (SEM) / energy dispersive X-ray (EDX) analysis of porous soot sample and final preform has been utilized to investigate incorporation mechanism of Crions with special emphasis on Cr-species evaporation at different stages of fabrication. We also report that optimized annealing condition of our fabricated preform exhibited enhanced fluorescence emission and a broad band within 550- 800 nm wavelength region under pumping at 532 nm wavelength due to nano-phase restructuration.

  13. Surrogate/spent fuel sabotage aerosol ratio testing:phase 1 summary and results.

    SciTech Connect

    Vigil, Manuel Gilbert; Sorenson, Ken Bryce; Lange, F. , Germany); Nolte, O. (Fraunhofer Institut fur Toxikologie und Experimentelle Medizin, Germany); Koch, W. (Fraunhofer Institut fur Toxikologie und Experimentelle Medizin, Germany); Dickey, Roy R.; Yoshimura, Richard Hiroyuki; Molecke, Martin Alan; Autrusson, Bruno (Institut de Radioprotection et de Surete Nucleaire , France); Young, F. I.; Pretzsch, Gunter Guido (Gesellschaft fur Anlagen- und reaktorsicherheit , Germany)

    2005-10-01

    This multinational test program is quantifying the aerosol particulates produced when a high energy density device (HEDD) impacts surrogate material and actual spent fuel test rodlets. The experimental work, performed in four consecutive test phases, has been in progress for several years. The overall program provides needed data that are relevant to some sabotage scenarios in relation to spent fuel transport and storage casks, and associated risk assessments. This program also provides significant political benefits in international cooperation for nuclear security related evaluations. The spent fuel sabotage--aerosol test program is coordinated with the international Working Group for Sabotage Concerns of Transport and Storage Casks (WGSTSC), and supported by both the U.S. Department of Energy and Nuclear Regulatory Commission. This report summarizes the preliminary, Phase 1 work performed in 2001 and 2002 at Sandia National Laboratories and the Fraunhofer Institute, Germany, and documents the experimental results obtained, observations, and preliminary interpretations. Phase 1 testing included: performance quantifications of the HEDD devices; characterization of the HEDD or conical shaped charge (CSC) jet properties with multiple tests; refinement of the aerosol particle collection apparatus being used; and, CSC jet-aerosol tests using leaded glass plates and glass pellets, serving as representative brittle materials. Phase 1 testing was quite important for the design and performance of the following Phase 2 test program and test apparatus.

  14. Application of Phase-field Method in Predicting Gas Bubble Microstructure Evolution in Nuclear Fuels

    SciTech Connect

    Hu, Shenyang Y.; Li, Yulan; Sun, Xin; Gao, Fei; Devanathan, Ramaswami; Henager, Charles H.; Khaleel, Mohammad A.

    2010-04-30

    Fission product accumulation and gas bubble microstructure evolution in nuclear fuels strongly affect thermo-mechanical properties such as thermal conductivity, gas release, volumetric swelling and cracking, and hence the fuel performance. In this paper, a general phase-field model is developed to predict gas bubble formation and evolution. Important materials processes and thermodynamic properties including the generation of gas atoms and vacancies, sinks for vacancies and gas atoms, the elastic interaction among defects, gas re-solution, and inhomogeneity of elasticity and diffusivity are accounted for in the model. The simulations demonstrate the potential application of the phase-field method in investigating 1) heterogeneous nucleation of gas bubbles at defects; 2) effect of elastic interaction, inhomogeneity of material properties, and gas re-solution on gas bubble microstructures; and 3) effective properties from the output of phase-field simulations such as distribution of defects, gas bubbles, and stress fields.

  15. Effects of Random Circuit Fabrication Errors on Small Signal Gain and on Output Phase In a Traveling Wave Tube

    NASA Astrophysics Data System (ADS)

    Rittersdorf, I. M.; Antonsen, T. M., Jr.; Chernin, D.; Lau, Y. Y.

    2011-10-01

    Random fabrication errors may have detrimental effects on the performance of traveling-wave tubes (TWTs) of all types. A new scaling law for the modification in the average small signal gain and in the output phase is derived from the third order ordinary differential equation that governs the forward wave interaction in a TWT in the presence of random error that is distributed along the axis of the tube. Analytical results compare favorably with numerical results, in both gain and phase modifications as a result of random error in the phase velocity of the slow wave circuit. Results on the effect of the reverse-propagating circuit mode will be reported. This work supported by AFOSR, ONR, L-3 Communications Electron Devices, and Northrop Grumman Corporation.

  16. Fabrication of Uniform Janus Micorparticles by Photopolymerization-Driven Phase Separation and their Asymmetric Hybridization with Metal Nanoparticles

    NASA Astrophysics Data System (ADS)

    Cho, Jangwoo; Kim, Jeong Won; Kim, Jin Woong

    2015-03-01

    In the field of colloid science, there is growing interest in synthesis of anisotropic particles, since they are desirable for controlling light scattering. These anisotropic particles have been developed by using sophisticated techniques, including clusterization, stamping, microfluidics, and controlled nucleation and precipitation. This study introduces a facile approach for fabrication of uniform Janus microparticles with anisotropic phases as well as selected surface chemistry. The technique we employed to synthesize these microparticles was the seeded swelling and polymerization method, in which complete compartmentalization of the particles into two distinct phases occurred upon polymerizing the monomer-swollen droplets. Then, we patched nanoparticles, such as gold nanoparticles and magnetic nanoparticles, onto one of the compartmentalized phases of the Janus microparticles. Finally we demonstrate that these asymmetrically hybridized Janus microparticles are of great importance and play a role in the designated colloidal 2D array.

  17. Development and transfer of fuel fabrication and utilization technology for research reactors

    SciTech Connect

    Travelli, A.; Domagala, R.F.; Matos, J.E.; Snelgrove, J.L.

    1982-01-01

    Approximately 300 research reactors supplied with US-enriched uranium are currently in operation in about 40 countries, with a variety of types, sizes, experiment capabilities and applications. Despite the usefulness and popularity of research reactors, relatively few innovations in their core design have been made in the last fifteen years. The main reason can be better understood by reviewing briefly the history of research reactor fuel technology and enrichment levels. Stringent requirements on the enrichment of the uranium to be used in research reactors were considered and a program was launched to assist research reactors in continuing their operation with the new requirements and with minimum penalties. The goal of the new program, the Reduced Enrichment Research and Test Reactor (RERTR) Program, is to develop the technical means to utilize LEU instead of HEU in research reactors without significant penalties in experiment performance, operating costs, reactor modifications, and safety characteristics. This paper reviews briefly the RERTR Program activities with special emphasis on the technology transfer aspects of interest to this conference.

  18. Hazard categorization for 300 area N reactor fuel fabrication and storage facility

    SciTech Connect

    Brehm, J.R., Fluor Daniel Hanford

    1997-02-12

    A final hazard categorization has been prepared for the 300 Area Fuel Supply Shutdown (FSS) facility in accordance with DOE-STD-1027-92, ''Hazard Categorization and Accident Analysis Techniques for Compliance with DOE Order 5480.23, Nuclear Safety Analysis Reports'' (DOE 1992). Prior to using the hazard category methodology, hazard classifications were prepared in accordance with the requirements of the Westinghouse Hanford Company (Westinghouse Hanford) controlled manual, WHC-CM-4-46, ''Safety Analysis Manual'', Chapter 4.0, ''Hazard Classification.'' A hazard classification (Huang 1995) was previously prepared for the FSS in accordance with WHC-CM-4-46. The analysis lead to the conclusion that the FSS should be declared a Nuclear facility with a Moderate Hazard Class rating. The analysis and results contained in the hazard classification can be used to provide additional information to support other safety analysis documentation. Also, the hazard classification provides analyses of the toxicological hazards inherent with the FSS inventory: whereas, a hazard categorization prepared in accordance with DOE-STD-1027-92, considers only the radiological component of the inventory.

  19. Solid-phase bioremediation of diesel fuel-contaminated soil utilizing indigenous microorganisms

    SciTech Connect

    Cagnetta, P.J.; Laubacher, R.C.

    1995-12-31

    In the spring of 1993, R.E. Wright Environmental, Inc. (REWEI) was retained by BP Oil Company (BP) to evaluate the use of bioremediation technology to remediate approximately 3,000 cubic yards (yd{sup 3}) of soil impacted with diesel fuel. The impacted soil resulted from the release of several hundred gallons of diesel fuel from a ruptured valve on an aboveground pipeline within a terminal. The overland flow of the diesel fuel resulted in a significant area of soil being impacted by the fuel. Immediate response activities limited vertical migration of the fuel through the excavation and stockpiling of the surface-impacted soil. The nature of the contaminant -- an unweathered, refined petroleum product comprised primarily of alkanes of a medium chain length -- and the biodegradable nature of the diesel fuel made bioremediation a cost-effective and technically feasible remedial option. The objective of the project was to reduce the concentrations of the petroleum hydrocarbons to below the Pennsylvania Department of Environmental Protection (DEP) soil cleanup levels in order to reuse the soil on-site as fill. Basic agronomic principles were applied throughout all phases of the project in order to successfully biodegrade the hydrocarbon.

  20. Yb-doped large-mode-area laser fiber fabricated by halide-gas-phase-doping technique

    NASA Astrophysics Data System (ADS)

    Peng, Kun; Wang, Yuying; Ni, Li; Wang, Zhen; Gao, Cong; Zhan, Huan; Wang, Jianjun; Jing, Feng; Lin, Aoxiang

    2015-06-01

    In this manuscript, we designed a rare-earth-halide gas-phase-doping setup to fabricate a large-mode-area fiber for high power laser applications. YbCl3 and AlCl3 halides are evaporated, carried respectively and finally mixed with usual host gas material SiCl4 at the hot zone of MCVD system. Owing to the all-gas-phasing reaction process and environment, the home-made Yb-doped fiber preform has a homogeneous large core and modulated refractive index profile to keep high beam quality. The drawn fiber core has a small numerical aperture of 0.07 and high Yb concentration of 9500 ppm. By using a master oscillator power amplifier system, nearly kW-level (951 W) laser output power was obtained with a slope efficiency of 83.3% at 1063.8 nm, indicating the competition and potential of the halide-gas-phase-doping technique for high power laser fiber fabrication.

  1. Spiral phase plates with radial discontinuities for the generation of multiring orbital angular momentum beams: fabrication, characterization, and application

    NASA Astrophysics Data System (ADS)

    Ruffato, Gianluca; Massari, Michele; Carli, Marta; Romanato, Filippo

    2015-11-01

    A design of spiral phase plates for the generation of multiring beams carrying orbital angular momentum (OAM) is presented. Besides the usual helical profile, these phase plates present radial π-discontinuities in correspondence of the zeros of the associated Laguerre polynomials. Samples were fabricated by electron beam lithography over glass substrates coated with a polymethylmethacrylate resist layer. The optical response was analyzed and the purity of the generated beams was investigated in terms of Laguerre-Gaussian modes contributions. The far-field intensity pattern was compared with theoretical models and numerical simulations, while the expected phase features were confirmed by interferometric analysis with a Mach-Zehnder setup. The high quality of the output beams confirms the applicability of these phase plates for the generation of high-order OAM beams with nonzero radial index. An application consisting of the design of computer-generated holograms encoding information for light beams carrying phase singularities is presented and described. A numerical code based on an iterative Fourier transform algorithm has been developed for the computation of phase-only diffractive optical element for illumination under OAM beams. Numerical analysis and preliminary experimental results confirm the applicability of these devices as high-security optical elements for anticounterfeiting applications.

  2. The effect of fuel and chlorinated hydrocarbons on a vapor phase carbon adsorption system

    SciTech Connect

    Crawford, W.J.; Cheney, J.L.; Taggart, D.B.

    1995-12-31

    A soil vapor extraction (SVE) system installed at the South Tacoma Well 12A Superfund Site was designed to recover 1,2-dichloroethylene (DCE), trichloroethylene (TCE), tetrachloroethylene (PCE), and 1,1,2,2-tetrachloroethane (1,1,2,2-TCA) from the vadose zone. The basic system consisted of twenty-two extraction wells, three centrifugal blowers, and three carbon adsorbers. The carbon adsorbers were regenerated on site by steam stripping. The mixture of steam and stripped organics was condensed and then decanted to separate the water from the organic phase. The recovered water was air stripped to remove the dissolved organics prior to discharge to the city storm sewer. The recovered organic phase was then shipped off site for thermal destruction. Previous reports described operating difficulties with the decanter, and air strippers. Sampling and analyses were performed which identified the problem as the simultaneous recovery of unexpected fuel hydrocarbons in addition to the solvents. Recovery of fuels resulted in a light phase in the decanter in addition to the water and heavy solvent phases. This required redesign of the decanter to handle the third phase. The effectiveness of desorption of the carbon beds by steam stripping gradually decreased as the remediation progressed into the second year of operation. Samples were collected from the carbon beds to evaluate the effect of the fuel and chlorinated hydrocarbons on the activated carbon. This report describes the results of these analyses. The data indicated that both 1,1,2,2-TCA and fuel hydrocarbons in the C-9 to C-24 range remained in the carbon beds after steam regeneration in sufficient quantities to require replacing the carbon.

  3. Demonstration of fuel resistant to pellet-cladding interaction: Phase 2. Third semiannual report, January-June 1980

    SciTech Connect

    Rosenbaum, H.S.

    1980-09-01

    Two fuel concepts are being developed for possible demonstration within this program: (a) Cu-barrier fuel and (b) Zr-liner fuel. These advanced fuels (known collectively as barrier fuels) have special fuel cladding designed to avoid the harmful effects of localized stress and reactive fission products during reactor service. Within the work scope of this program one of these concepts is to be selected for demonstration in a commercial power reactor. It was decided to demonstrate Zr-liner in 132 bundles which have liners of either crystal-bar zirconium or of low-oxygen sponge zirconium in the reload for Quad Cities Unit 2, Cycle 6. Irradiation testing or barrier fuel was continued, and the superior PCI resistance of Zr-liner fuel was further substantiated in the current report period. Furthermore, an irradiation experiment in which Zr-liner fuel, having a deliberately fabricated cladding perforation, was operated at a linear heat generation rate of 35 kW/m to a burnup of approx. 3 MWd/kg U showed no unusual signs of degradation compared with a similarly defected reference fuel rod. Four lead test assemblies of barrier fuel (two of Zr-liner and two of Cu-barrier), presently under irradiation in Quad Cities Unit 1, have achieved a burnup of 11 MWd/kg U.

  4. High performance anode-supported tubular solid oxide fuel cells fabricated by a novel slurry-casting method

    NASA Astrophysics Data System (ADS)

    Duan, Nan-Qi; Yan, Dong; Chi, Bo; Pu, Jian; Jian, Li

    2015-02-01

    Tubular solid oxide fuel cells were fabricated and evaluated for their microstructure and electrochemical performance. The tubular substrate was prepared by casting NiO-Y2O3 stabilized ZrO2 (YSZ) slurry on the inner wall of a plastic mold (tube). The wall thickness and uniformity were controlled by slurry viscosity and rotation speed of the tube. The cells consisted of Ni-YSZ functional anode, YSZ electrolyte and (La0.8Sr0.2)0.95MnO3-δ (LSM)-YSZ cathode prepared in sequence on the substrate by dip-coating and sintering. Their dimension was 50 mm in length, 0.8 mm in thickness and 10.5 mm in outside diameter. The peak power density of the cell at temperatures between 650 and 850°C was in the range from 85 to 522 mW cm-2 and was greatly enhanced to the range from 308 to 1220 mW cm-2 by impregnating PdO into LSM-YSZ cathode. During a cell testing at 0.7 A cm-2 and 750°C for 282 h, the impregnated PdO particles grew by coalescence, which increased the cathode polarization resistance and so that decreased the cell performance. According to the degradation tendency, the cell performance will be stabilized in a longer run.

  5. Determination of uranium in urine samples of fuel element fabrication workers by beta-delayed neutron counting

    NASA Astrophysics Data System (ADS)

    Gabelmann, H.; Lerch, M.; Kratz, K.-L.; Rudolph, W.

    1984-06-01

    Within the health physics examination of fuel element fabrication workers, the control of uranium incorporation is of importance. This is commonly performed by the determination of the alpha activity concentration of uranium excreted in the urine. However, since the chemical separation procedure and the preparation of alpha-counting samples are complicated and time-consuming, this method may imply restrictions on the routine control of large numbers of persons. Therefore, we have investigated the applicability of measuring the beta-delayed neutrons from thermal neutron induced fission of the 235U in the urine samples. The uranium was separated by coprecipitation with Fe(OH) 3 from the urine samples and irradiated in a rabbit system of the Mainz TRIGA reactor. The neutrons were counted with a 3He long counter. The detection limit of 0.3 to 0.9 pCi 1 -1 is comparable to that of alpha spectrometry, but the time required for one sample, from preparation to data evaluation is less than 25 min.

  6. High performance anode-supported tubular solid oxide fuel cells fabricated by a novel slurry-casting method

    PubMed Central

    Duan, Nan-Qi; Yan, Dong; Chi, Bo; Pu, Jian; Jian, Li

    2015-01-01

    Tubular solid oxide fuel cells were fabricated and evaluated for their microstructure and electrochemical performance. The tubular substrate was prepared by casting NiO-Y2O3 stabilized ZrO2 (YSZ) slurry on the inner wall of a plastic mold (tube). The wall thickness and uniformity were controlled by slurry viscosity and rotation speed of the tube. The cells consisted of Ni-YSZ functional anode, YSZ electrolyte and (La0.8Sr0.2)0.95MnO3-δ (LSM)-YSZ cathode prepared in sequence on the substrate by dip-coating and sintering. Their dimension was 50 mm in length, 0.8 mm in thickness and 10.5 mm in outside diameter. The peak power density of the cell at temperatures between 650 and 850°C was in the range from 85 to 522 mW cm−2 and was greatly enhanced to the range from 308 to 1220 mW cm−2 by impregnating PdO into LSM-YSZ cathode. During a cell testing at 0.7 A cm−2 and 750°C for 282 h, the impregnated PdO particles grew by coalescence, which increased the cathode polarization resistance and so that decreased the cell performance. According to the degradation tendency, the cell performance will be stabilized in a longer run. PMID:25640168

  7. Self-organized nanocomb of ZnO fabricated by Au-catalyzed vapor-phase transport

    NASA Astrophysics Data System (ADS)

    Xu, C. X.; Sun, X. W.; Dong, Z. L.; Yu, M. B.

    2004-10-01

    Based on a vapor-phase transport process, self-organized nanocomb structures of ZnO were fabricated on Au-coated Si substrate by employing a mixture of ZnO and graphite powders as source materials. The morphology of the product showed a ribbon-like stem and nanorod array aligned evenly along one side of the nanoribbon. It was found that the nanoribbon grew mainly along [ 1 0 1 bar 0 ] direction and the self-assembled branching nanorods grew epitaxially along [0 0 0 1] orientation from the (0 0 0 2) plane of the stem. The growth process was analyzed in detail.

  8. Three dimensional silicon photonic crystals fabricated by two photon phase mask lithography.

    SciTech Connect

    Wiltzius, P.; Braun, P. V.; Liao, H.; Brzezinski, A.; Chen, Y. C.; Nelson, E.; Shir, D.; Rogers, J. A.; Bogart, Katherine Huderle Andersen

    2008-08-01

    We describe the fabrication of silicon three dimensional photonic crystals using polymer templates defined by a single step, two-photon exposure through a layer of photopolymer with relief molded on its surface. The resulting crystals exhibit high structural quality over large areas, displaying geometries consistent with calculation. Spectroscopic measurements of transmission and reflection through the silicon and polymer structures reveal excellent optical properties, approaching properties predicted by simulations that assume ideal layouts.

  9. A novel route for fabricating metal-polymer composite nanoparticles with phase-separated structures.

    PubMed

    Yabu, Hiroshi; Koike, Kazutaka; Motoyoshi, Kiwamu; Higuchi, Takeshi; Shimomura, Masatsugu

    2010-07-15

    Au nanoparticles (NPs) and polymer composite particles with phase-separation structures were prepared based on phase separation structures. Au NPs were successfully synthesized in amphiphilic block-copolymer micelles, and then composite particles were formed by a simple solvent evaporation process from Au NPs and polymer solution. The phase separated structures (Janus and Core-shell) were controlled by changing the combination of polymers having differing hydrophobicity. PMID:21567522

  10. Optimizing photo-Fenton like process for the removal of diesel fuel from the aqueous phase

    PubMed Central

    2014-01-01

    Background In recent years, pollution of soil and groundwater caused by fuel leakage from old underground storage tanks, oil extraction process, refineries, fuel distribution terminals, improper disposal and also spills during transferring has been reported. Diesel fuel has created many problems for water resources. The main objectives of this research were focused on assessing the feasibility of using photo-Fenton like method using nano zero-valent iron (nZVI/UV/H2O2) in removing total petroleum hydrocarbons (TPH) and determining the optimal conditions using Taguchi method. Results The influence of different parameters including the initial concentration of TPH (0.1-1 mg/L), H2O2 concentration (5-20 mmole/L), nZVI concentration (10-100 mg/L), pH (3-9), and reaction time (15-120 min) on TPH reduction rate in diesel fuel were investigated. The variance analysis suggests that the optimal conditions for TPH reduction rate from diesel fuel in the aqueous phase are as follows: the initial TPH concentration equals to 0.7 mg/L, nZVI concentration 20 mg/L, H2O2 concentration equals to 5 mmol/L, pH 3, and the reaction time of 60 min and degree of significance for the study parameters are 7.643, 9.33, 13.318, 15.185 and 6.588%, respectively. The predicted removal rate in the optimal conditions was 95.8% and confirmed by data obtained in this study which was between 95-100%. Conclusion In conclusion, photo-Fenton like process using nZVI process may enhance the rate of diesel degradation in polluted water and could be used as a pretreatment step for the biological removal of TPH from diesel fuel in the aqueous phase. PMID:24955242

  11. Phase-field Modeling of Gas Bubbles and Thermal Conductivity Evolution in Nuclear Fuels

    SciTech Connect

    Hu, Shenyang Y.; Henager, Charles H.; Heinisch, Howard L.; Stan, Marius; Baskes, Michael I.; Valone, Steven

    2009-07-15

    The major factors that influence the thermal conductivity of the ceramics and metals are temperature, stoichiometry, microstructure, porosity, and point defects. Nuclear fuels and structure materials are subject to a severe radiation environment and their properties, including thermal conductivity change significantly with time and irradiation level. In particular, the accumulation of fission products and the formation of He bubbles can decrease the heat transfer, leading to overheating of the fuel element. In this work, we use the phase-field method to study the effect of microstructural changes on thermal conductivity. We developed a phase-field model to simulate the He bubble formation and growth in a single/polycrystalline material with defects. The model takes into account the generation of gas atoms and defects, gas atom diffusivity inhomogeneity, gas atom segregation, and gas bubble nucleation. With the model, we simulated the gas bubble and temperature evolution, and calculated the effect of gas bubble volume fraction on effective thermal conductivity.

  12. Enhancing Tabletop X-Ray Phase Contrast Imaging with Nano-Fabrication

    NASA Astrophysics Data System (ADS)

    Miao, Houxun; Gomella, Andrew A.; Harmon, Katherine J.; Bennett, Eric E.; Chedid, Nicholas; Znati, Sami; Panna, Alireza; Foster, Barbara A.; Bhandarkar, Priya; Wen, Han

    2015-08-01

    X-ray phase-contrast imaging is a promising approach for improving soft-tissue contrast and lowering radiation dose in biomedical applications. While current tabletop imaging systems adapt to common x-ray tubes and large-area detectors by employing absorptive elements such as absorption gratings or monolithic crystals to filter the beam, we developed nanometric phase gratings which enable tabletop x-ray far-field interferometry with only phase-shifting elements, leading to a substantial enhancement in the performance of phase contrast imaging. In a general sense the method transfers the demands on the spatial coherence of the x-ray source and the detector resolution to the feature size of x-ray phase masks. We demonstrate its capabilities in hard x-ray imaging experiments at a fraction of clinical dose levels and present comparisons with the existing Talbot-Lau interferometer and with conventional digital radiography.

  13. Enhancing Tabletop X-Ray Phase Contrast Imaging with Nano-Fabrication.

    PubMed

    Miao, Houxun; Gomella, Andrew A; Harmon, Katherine J; Bennett, Eric E; Chedid, Nicholas; Znati, Sami; Panna, Alireza; Foster, Barbara A; Bhandarkar, Priya; Wen, Han

    2015-01-01

    X-ray phase-contrast imaging is a promising approach for improving soft-tissue contrast and lowering radiation dose in biomedical applications. While current tabletop imaging systems adapt to common x-ray tubes and large-area detectors by employing absorptive elements such as absorption gratings or monolithic crystals to filter the beam, we developed nanometric phase gratings which enable tabletop x-ray far-field interferometry with only phase-shifting elements, leading to a substantial enhancement in the performance of phase contrast imaging. In a general sense the method transfers the demands on the spatial coherence of the x-ray source and the detector resolution to the feature size of x-ray phase masks. We demonstrate its capabilities in hard x-ray imaging experiments at a fraction of clinical dose levels and present comparisons with the existing Talbot-Lau interferometer and with conventional digital radiography. PMID:26315891

  14. Enhancing Tabletop X-Ray Phase Contrast Imaging with Nano-Fabrication

    PubMed Central

    Miao, Houxun; Gomella, Andrew A.; Harmon, Katherine J.; Bennett, Eric E.; Chedid, Nicholas; Znati, Sami; Panna, Alireza; Foster, Barbara A.; Bhandarkar, Priya; Wen, Han

    2015-01-01

    X-ray phase-contrast imaging is a promising approach for improving soft-tissue contrast and lowering radiation dose in biomedical applications. While current tabletop imaging systems adapt to common x-ray tubes and large-area detectors by employing absorptive elements such as absorption gratings or monolithic crystals to filter the beam, we developed nanometric phase gratings which enable tabletop x-ray far-field interferometry with only phase-shifting elements, leading to a substantial enhancement in the performance of phase contrast imaging. In a general sense the method transfers the demands on the spatial coherence of the x-ray source and the detector resolution to the feature size of x-ray phase masks. We demonstrate its capabilities in hard x-ray imaging experiments at a fraction of clinical dose levels and present comparisons with the existing Talbot-Lau interferometer and with conventional digital radiography. PMID:26315891

  15. TEM identification of subsurface phases in ternary U-Pu-Zr fuel

    NASA Astrophysics Data System (ADS)

    Aitkaliyeva, Assel; Madden, James W.; Papesch, Cynthia A.; Cole, James I.

    2016-05-01

    Phases and microstructure in as-cast, annealed at 850 °C, and subsequently cooled U-23Pu-9Zr fuel were characterized using scanning and transmission electron microscopy techniques. SEM examination shows formation of three phases in the alloy that were identified in TEM using selective area diffraction pattern analysis: α-Zr globular and elongated δ-UZr2 inclusions and a thick oxide layer formed on top of β-Pu phase, which has been initially assumed to be ζ-(U, Pu). However, further examination of the cross-sectional TEM specimens identified the matrix phases as δ-UZr2, β-Pu, and (U, Zr)ht. Two types of inclusions were observed in the immediate vicinity of the specimen surface and they were consistent with α-Zr and ζ-(U, Pu).

  16. Surrogate/spent fuel sabotage : aerosol ratio test program and Phase 2 test results.

    SciTech Connect

    Borek, Theodore Thaddeus III; Thompson, N. Slater; Sorenson, Ken Bryce; Hibbs, R.S.; Nolte, Oliver; Molecke, Martin Alan; Autrusson, Bruno; Young, F. I.; Koch, Wolfgang; Brochard, Didier; Pretzsch, Gunter Guido; Lange, Florentin

    2004-05-01

    A multinational test program is in progress to quantify the aerosol particulates produced when a high energy density device, HEDD, impacts surrogate material and actual spent fuel test rodlets. This program provides needed data that are relevant to some sabotage scenarios in relation to spent fuel transport and storage casks, and associated risk assessments; the program also provides significant political benefits in international cooperation. We are quantifying the spent fuel ratio, SFR, the ratio of the aerosol particles released from HEDD-impacted actual spent fuel to the aerosol particles produced from surrogate materials, measured under closely matched test conditions. In addition, we are measuring the amounts, nuclide content, size distribution of the released aerosol materials, and enhanced sorption of volatile fission product nuclides onto specific aerosol particle size fractions. These data are crucial for predicting radiological impacts. This document includes a thorough description of the test program, including the current, detailed test plan, concept and design, plus a description of all test components, and requirements for future components and related nuclear facility needs. It also serves as a program status report as of the end of FY 2003. All available test results, observations, and analyses - primarily for surrogate material Phase 2 tests using cerium oxide sintered ceramic pellets are included. This spent fuel sabotage - aerosol test program is coordinated with the international Working Group for Sabotage Concerns of Transport and Storage Casks, WGSTSC, and supported by both the U.S. Department of Energy and Nuclear Regulatory Commission.

  17. Characterization of polycrystalline VO2 thin film with low phase transition temperature fabricated by high power impulse magnetron sputtering

    NASA Astrophysics Data System (ADS)

    Lin, Tiegui; Wang, Langping; Wang, Xiaofeng; Zhang, Yufen

    2016-04-01

    VO2 is a unique material that undergoes a reversible phase transformation around 68∘C. Currently, applications of VO2 on smart windows are limited by its high transition temperature. In order to reduce the temperature, VO2 thin film was fabricated on quartz glass substrate by high power impulse magnetron sputtering with a modulated pulsed power. The phase transition temperature has been reduced to as low as 32∘C. In addition, the VO2 film possesses a typical metal-insulator transition. X-ray diffraction and selected area electron diffraction patterns reveal that an obvious lattice distortion has been formed in the as-deposited polycrystalline VO2 thin film. X-ray photoelectron spectroscopy proves that oxygen vacancies have been formed in the as-deposited thin film, which will induce a lattice distortion in the VO2 thin film.

  18. AFIP-4 Fabrication Summary Report

    SciTech Connect

    Glenn A. Moore

    2010-02-01

    The AFIP-4 (ATR Full –size-plate In center flux trap Position) experiment was designed to evaluate the performance of monolithic fuels at a scale prototypic of research reactor fuel plates. Twelve qualified fueled plates were fabricated for the AFIP-4 experiment; to be irradiated in the INL Advanced Test Reactor (ATR). This report provides details of the fuel fabrication efforts; including material selection, fabrication processes, and fuel plate qualification.

  19. AFIP-2 Fabrication Summary Report

    SciTech Connect

    Glenn Moore

    2010-02-01

    The Advanced Test Reactor (ATR) Full-size Plate In Center Flux Trap Position (AFIP)-2 experiment was designed to evaluate the performance of monolithic fuels at a scale prototypic of research reactor fuel plates. Two qualified fueled plates were fabricated for the AFIP 2 experiment to be irradiated in the Idaho National Laboratory ATR. This report provides details of the fuel fabrication efforts, including material selection, fabrication processes, and fuel plate qualification.

  20. AFIP-6 Fabrication Summary Report

    SciTech Connect

    Glenn A. Moore; M. Craig Marshall

    2011-09-01

    The AFIP-6 (ATR Full-size plate In center flux trap Position) experiment was designed to evaluate the performance of monolithic fuels at a scale prototypic of research reactor fuel plates. Two qualified fueled plates were fabricated for the AFIP-6 experiment; to be irradiated in the INL Advanced Test Reactor (ATR). This report provides details of the fuel fabrication efforts, including material selection, fabrication processes, and fuel plate qualification.

  1. Novel functionalized polymeric fabric and fiber material as solid support for solid-phase synthesis and biomedical applications

    NASA Astrophysics Data System (ADS)

    Xiang, Bei

    The aim of the research is to develop novel polymer solid support by modifying or fabricating polymeric fibrous materials for peptide synthesis and biomedical applications. Originally chemical inert isotactic polypropylene (iPP) fabric was utilized and modified to serve as a functional flexible planar solid support for solid phase peptide synthesis. The modification was achieved through thermal initiated radical grafting polymerization using acrylic acid, poly (ethylene glycol) diacrylate as monomers, and benzoyl peroxide as radical initiator. The iPP fabric was successfully functionalized and possessing as high as 0.7mmol/g carboxylic acid groups. Peptide ligand LHPQF was successfully synthesized on the new functional planar support. Specific enzyme immobilization was fulfilled on the functional iPP fabric support. A commercially available ethylene-acrylic acid copolymer was made into ultrafine copolymer fiber bundles which are composed of nanofibers with diameters ranging from 200nm to 800nm. Various mixing ratios of copolymer/matrix materials were utilized to explore the effect on the final nanofiber physical properties including morphology and stability in solvents. The surface carboxylic acid groups were further converted to amino groups before the functional nanofibers can be applied in solid phase peptide synthesis. Two peptide ligands, LHPQF and HWRGWV, were also successfully synthesized on the nanofiber bundles. Streptavidin and human immunoglobulin G specific binding with the corresponding ligand which was anchored on the nanofibers was conducted successfully to illustrate the potential applications of the nanofiber materials in biomedical field. Further study on the dispersion of the ethylene-acrylic acid nanofiber bundles was pursued to take advantage of the super high active surface area of functional nanofibers. To manipulate the polymer nanofibers during synthesis and bio-assays, a technique was developed to controllably assemble and disperse the

  2. Two-phase flow and transport in the air cathode of proton exchange membrane fuel cells

    SciTech Connect

    WANG,Z.H.; WANG,C.Y.; CHEN,KEN S.

    2000-03-20

    Two-phase flow and transport of reactants and products in the air cathode of proton exchange membrane (PEM) fuel cells is studied analytically and numerically. Four regimes of water distribution and transport are classified by defining three threshold current densities and a maximum current density. They correspond to first appearance of liquid water at the membrane/cathode interface, extension of the gas-liquid two-phase zone to the cathode/channel interface, saturated moist air exiting the gas channel, and complete consumption of oxygen by the electrochemical reaction. When the cell operates above the first threshold current density, liquid water appears and a two-phase zone forms within the porous cathode. A two-phase, multi-component mixture model in conjunction with a finite-volume-based computational fluid dynamics (CFD) technique is applied to simulate the cathode operation in this regime. The model is able to handle the situation where a single-phase region co-exists with a two-phase zone in the air cathode. For the first time, the polarization curve as well as water and oxygen concentration distributions encompassing both single- and two-phase regimes of the air cathode are presented. Capillary action is found to be the dominant mechanism for water transport inside the two-phase zone. The liquid water saturation within the cathode is predicted to reach 6.3% at 1.4 A/cm{sup 2}.

  3. Fabrication and Structure Characterization of Alumina-Aluminum Interpenetrating Phase Composites

    NASA Astrophysics Data System (ADS)

    Dolata, Anna J.

    2016-01-01

    Alumina-Aluminum composites with interpenetrating networks structure belong to advanced materials with potentially better properties when compared with composites reinforced by particles or fibers. The paper presents the experimental results of fabrication and structure characterization of Al matrix composites locally reinforced via Al2O3 ceramic foam. The composites were obtained using centrifugal infiltration of porous ceramics by liquid aluminum alloy. Both scanning electron microscopy (SEM + EDS) and x-ray tomography were used to determine the structure of foams and composites especially in reinforced areas. The quality of castings, degree of pore filling in ceramic foams by Al alloy, and microstructure in area of interface were assessed.

  4. Fabrication of platinum nanoparticles in aqueous solution and solid phase using amphiphilic PB-b-PEO copolymer nanoreactors

    SciTech Connect

    Hoda, Numan; Budama, Leyla; Çakır, Burçin Acar; Topel, Önder; Ozisik, Rahmi

    2013-09-01

    Graphical abstract: TEM image of Pt nanoparticles produced by reducing by NaBH{sub 4} within PB-b-PEO micelles in aqueous media (scale bar 1 nm). - Highlights: • Pt nanoparticles were synthesized within amphiphilic diblock copolymer micelles. • The effects of reducing agents and precursor dose on Pt np size were investigated. • The effect on fabrication of Pt np by reducing in aqueous and solid phases was compared. • The size of nanoparticles was about 1.4 nm for all doses and reducing agents types. - Abstract: Fabrication of Pt nanoparticles using an amphiphilic copolymer template in aqueous solution was achieved via polybutadiene-block-polyethyleneoxide copolymer micelles, which acted as nanoreactors. In addition, Pt nanoparticles were synthesized using hydrogen gas as the reducing agent in solid state for the first time to compare against solution synthesis. The influences of loaded precursor salt amount to micelles and the type of reducing agent on the size of nanoparticles were investigated through transmission electron microscopy. It was found that increasing the ratio of precursor salt to copolymer and using different type of reducing agent, even in solid phase reduction, did not affect the nanoparticle size. The average size of Pt nanoparticles was estimated to be 1.4 ± 0.1 nm. The reason for getting same sized nanoparticles was discussed in the light of nucleation, growth process, stabilization and diffusion of nanoparticles within micelles.

  5. Dynamic fabric phase sorptive extraction for a group of pharmaceuticals and personal care products from environmental waters.

    PubMed

    Lakade, Sameer S; Borrull, Francesc; Furton, Kenneth G; Kabir, Abuzar; Marcé, Rosa Maria; Fontanals, Núria

    2016-07-22

    This paper describes for the first time the use of a new extraction technique, based on fabric phase sorptive extraction (FPSE). This new mode proposes the extraction of the analytes in dynamic mode in order to reduce the extraction time. Dynamic fabric phase sorptive extraction (DFPSE) followed by liquid chromatography-tandem mass spectrometry was evaluated for the extraction of a group of pharmaceuticals and personal care products (PPCPs) from environmental water samples. Different parameters affecting the extraction were optimized and best conditions were achieved when 50mL of sample at pH 3 was passed through 3 disks and analytes retained were eluted with 10mL of ethyl acetate. The recoveries were higher than 60% for most of compounds with the exception of the most polar ones (between 8% and 38%). The analytical method was validated with environmental samples such as river water and effluent and influent wastewater, and good performance was obtained. The analysis of samples revealed the presence of some PPCPs at low ngL(-1) concentrations. PMID:27295962

  6. Fine pattern fabrication property of binary mask and attenuated phase shift mask

    NASA Astrophysics Data System (ADS)

    Yamazaki, Taichi; Kojima, Yosuke; Yamana, Mitsuharu; Haraguchi, Takashi; Tanaka, Tsuyoshi

    2009-04-01

    For 45nm and 32nm node technology, the challenges for resolution and CD control of mask patterns become the steeper mountain path. Especially, Sub Resolution Assist Feature (SRAF) is the smallest pattern on mask and amplifies the difficulty of mask fabrication. In order to improve the resolution of fine patterns, the influence of wet processing cannot be neglected, because it causes the pattern collapsing. Wet processing of mask-making can be divided into resist development and cleaning. In this study, the root causes of pattern collapsing are investigated at each wet processing. It is confirmed that thin resist can enhance the resolution limit of resist pattern and hard-mask blank, such as OMOG: Opaque MoSi On Glass, is suitable for thinner resist under 1500A. The pattern collapsing of OMOG is compared with that of Att.PSM at the cleaning before and after Cr stripping. Mask inspection finds that pattern collapsing can be suppressed by OMOG at both cleanings. It is because OMOG has lower cleaning stress than Att.PSM due to lower aspect-ratio. This benefit is demonstrated by cleaning stress simulation. Additionally, it is found that the SRAF size of OMOG can be wider than Att.PSM by optical simulation. From these results, OMOG has much advantage of fine pattern fabrication and is the optimal blank for 32nm node and beyond.

  7. Phase Formation and Transformations in Transmutation Fuel Materials for the LIFE Engine Part I - Path Forward

    SciTech Connect

    Turchi, P E; Kaufman, L; Fluss, M J

    2008-11-10

    The current specifications of the LLNL fusion-fission hybrid proposal, namely LIFE, impose severe constraints on materials, and in particular on the nuclear fissile or fertile nuclear fuel and its immediate environment. This constitutes the focus of the present report with special emphasis on phase formation and phase transformations of the transmutation fuel and their consequences on particle and pebble thermal, chemical and mechanical integrities. We first review the work that has been done in recent years to improve materials properties under the Gen-IV project, and with in particular applications to HTGR and MSR, and also under GNEP and AFCI in the USA. Our goal is to assess the nuclear fuel options that currently exist together with their issues. Among the options, it is worth mentioning TRISO, IMF, and molten salts. The later option will not be discussed in details since an entire report is dedicated to it. Then, in a second part, with the specific LIFE specifications in mind, the various fuel options with their most critical issues are revisited with a path forward for each of them in terms of research, both experimental and theoretical. Since LIFE is applicable to very high burn-up of various fuels, distinctions will be made depending on the mission, i.e., energy production or incineration. Finally a few conclusions are drawn in terms of the specific needs for integrated materials modeling and the in depth knowledge on time-evolution thermochemistry that controls and drastically affects the performance of the nuclear materials and their immediate environment. Although LIFE demands materials that very likely have not yet been fully optimized, the challenge are not insurmountable and a well concerted experimental-modeling effort should lead to dramatic advances that should well serve other fission programs such as Gen-IV, GNEP, AFCI as well as the international fusion program, ITER.

  8. Fuel Injector: Air swirl characterization aerothermal modeling, phase 2, volume 2

    NASA Technical Reports Server (NTRS)

    Nikjooy, M.; Mongia, H. C.; Mcdonell, V. G.; Samuelson, G. S.

    1993-01-01

    A well integrated experimental/analytical investigation was conducted to provide benchmark quality data relevant to prefilming type airblast fuel nozzle and its interaction with combustor dome air swirler. The experimental investigation included a systematic study of both single-phase flows that involved single and twin co-axial jets with and without swirl. A two-component Phase Doppler Particle Analyzer (PDPA) equipment was used to document the interaction of single and co-axial air jets with glass beads that simulate nonevaporating spray and simultaneously avoid the complexities associated with fuel atomization processes and attendant issues about the specification of relevant boundary conditions. The interaction of jets with methanol spray produced by practical airblast nozzle was also documented in the spatial domain of practical interest. Model assessment activities included the use of three turbulence models (k-epsilon, algebraic second moment (ASM) and differential second moment (DSM)) for the carrier phase, deterministic or stochastic Lagrangian treatment of the dispersed phase, and advanced numerical schemes. Although qualitatively good comparison with data was obtained for most of the cases investigated, the model deficiencies in regard to modeled dissipation rate transport equation, single length scale, pressure-strain correlation, and other critical closure issues need to be resolved before one can achieve the degree of accuracy required to analytically design combustion systems.

  9. Fuel injector: Air swirl characterization aerothermal modeling, phase 2, volume 1

    NASA Technical Reports Server (NTRS)

    Nikjooy, M.; Mongia, H. C.; Mcdonell, V. G.; Samuelsen, G. S.

    1993-01-01

    A well integrated experimental/analytical investigation was conducted to provide benchmark quality relevant to a prefilming type airblast fuel nozzle and its interaction with the combustor dome air swirler. The experimental investigation included a systematic study of both single-phase flows that involved single and twin co-axial jets with and without swirl. A two-component Phase Doppler Particle Analyzer (PDPA) was used to document the interaction of single and co-axial air jets with glass beads that simulate nonevaporating spray and simultaneously avoid the complexities associated with fuel atomization processes and attendant issues about the specification of relevant boundary conditions. The interaction of jets with methanol spray produced by practical airblast nozzle was also documented in the spatial domain of practical interest. Model assessment activities included the use of three turbulence models (k-epsilon, algebraic second moment (ASM), and differential second moment (DSM)) for the carrier phase, deterministic or stochastic Lagrangian treatment of the dispersed phase, and advanced numerical schemes. Although qualitatively good comparison with data was obtained for most of the cases investigated, the model deficiencies in regard to modeled dissipation rate transport equation, single length scale, pressure-strain correlation, and other critical closure issues need to be resolved before one can achieve the degree of accuracy required to analytically design combustion systems.

  10. Enertech 2-kW high-reliability wind system. Phase II. Fabrication and testing

    SciTech Connect

    Cordes, J A; Johnson, B A

    1981-06-01

    A high-reliability wind machine rated for 2 kW in a 9 m/s wind has been developed. Activities are summarized that are centered on the fabrication and testing of prototypes of the wind machine. The test results verified that the wind machine met the power output specification and that the variable-pitch rotor effectively controlled the rotor speed for wind speeds up to 50 mph. Three prototypes of the wind machine were shipped to the Rocky Flats test center in September through November of 1979. Work was also performed to reduce the start-up wind speed. The start-up wind speed to the Enertech facility has been reduced to 4.5 m/s.

  11. Design, fabrication and test of graphite/epoxy metering truss structure components, phase 3

    NASA Technical Reports Server (NTRS)

    1974-01-01

    The design, materials, tooling, manufacturing processes, quality control, test procedures, and results associated with the fabrication and test of graphite/epoxy metering truss structure components exhibiting a near zero coefficient of thermal expansion are described. Analytical methods were utilized, with the aid of a computer program, to define the most efficient laminate configurations in terms of thermal behavior and structural requirements. This was followed by an extensive material characterization and selection program, conducted for several graphite/graphite/hybrid laminate systems to obtain experimental data in support of the analytical predictions. Mechanical property tests as well as the coefficient of thermal expansion tests were run on each laminate under study, the results of which were used as the selection criteria for the single most promising laminate. Further coefficient of thermal expansion measurement was successfully performed on three subcomponent tubes utilizing the selected laminate.

  12. Design, fabrication, and characterization of a planar, silicon-based, monolithically integrated micro laminar flow fuel cell with a bridge-shaped microchannel cross-section

    NASA Astrophysics Data System (ADS)

    López-Montesinos, P. O.; Yossakda, N.; Schmidt, A.; Brushett, F. R.; Pelton, W. E.; Kenis, P. J. A.

    2011-05-01

    We report the fabrication of a planar, silicon-based, monolithically integrated micro laminar flow fuel cell (μLFFC) using standard MEMS and IC-compatible fabrication technologies. The μLFFC operates with acid supported solutions of formic acid and potassium permanganate, as a fuel and oxidant respectively. The micro-fuel cell design features two in-plane anodic and cathodic microchannels connected via a bridge to confine the diffusive liquid-liquid interface away from the electrode areas and to minimize crossover. Palladium high-active-surface-area catalyst was selectively integrated into the anodic microchannel by electrodeposition, whereas no catalyst was required in the cathodic microchannel. A three-dimensional (3D) diffusion-convection model was developed to study the behavior of the diffusion zone and to extract appropriate cell-design parameters and operating conditions. Experimentally, we observed peak power densities as high as 26 mW cm-2 when operating single cells at a flow rate of 60 μL min-1 at room temperature. The miniature membraneless fuel cell design presented herein offers potential for on-chip power generation, which has long been prohibited by integration complexities associated with the membrane.

  13. CHEMICALLY ACTIVE FLUID-BED PROCESS FOR SULPHUR REMOVAL DURING GASIFICATION OF HEAVY FUEL OIL - THIRD PHASE

    EPA Science Inventory

    The report describes the third phase of studies on the CAFB process for desulfurization/gasification of heavy fuel oil in a bed of hot lime. Major conclusions relating to process performance and operability are: (1) water, either in the fuel or in the fluidizing air, has a strong...

  14. The effects of hygroscopicity of fossil fuel BC on mixed-phase and cirrus ice clouds

    NASA Astrophysics Data System (ADS)

    Yun, Y.; Penner, J. E.

    2010-12-01

    Fossil fuel burning BC aerosols are often emitted together with sulfate, which coats the surface of these BC particles and changes their hygroscopicity. The ice forming capability of the fossil fuel burning BC can differ widely as a result of the amount of soluble coating on their surface. Due to the abundance of fossil fuel burning BC particles, a small change in their activated fraction can produce a large difference in their climate forcing. To better quantify the role of fossil fuel burning BC in climate change, a 3-BC (hydrophobic, hydrophilic and hygroscopic BC) scheme is developed to replace the 1-BC scheme in a coupled climate and aerosol transport model (CAM-IMPACT). The new scheme explicitly calculates the condensation and coagulation of sulfate on BC particles and keeps track of their coating in the 3-BC states. The hygroscopicity of BC is determined by the layers of sulfate coating on their surface according to criteria developed in laboratory observations. The ice formation scheme in mixed-phase and cirrus clouds is also updated to treat the 3 hygroscopicity BC groups separately according to their different ice freezing capabilities. This paper will report the climate forcing associated with the new BC scheme as well as comparison with observations.

  15. Unlimited-bandwidth distributed optical phase modulators and detectors: Design and fabrication issues

    SciTech Connect

    Vawter, G.A.; Hietala, V.M.; Kravitz, S.H.; Armendariz, M.G.

    1994-08-01

    Practical and theoretical limits on the bandwidth of distributed optical phase modulators and traveling-wave photodetectors are given. For the case of perfect velocity matching, RF transmission losses are the main performance-limiting factor. However, some high-performance modulators require highly-capacitive transmission lines making proper slow-wave operation difficult to achieve.

  16. Phase 1A Final Report for the AREVA Team Enhanced Accident Tolerant Fuels Concepts

    SciTech Connect

    Morrell, Mike E.

    2015-03-19

    plants large scale investment by the fuel vendors is difficult to justify. Specific EATF enhancements considered by the AREVA team were; Improved performance in DB and BDB conditions; Reduced release to the environment in a catastrophic accident; Improved performance during normal operating conditions; Improved performance if US reactors start to load follow; Equal or improved economics of the fuel; and Improvements to the fuel behavior to support future transportation and storage of the used nuclear fuel (UNF). In pursuit of the above enhancements, EATF technology concepts that our team considered were; Additives to the fuel pellets which included; Chromia doping to increase fission gas retention. Chromia doping has the potential to improve load following characteristics, improve performance of the fuel pellet during clad failure, and potentially lock up cesium into the fuel matrix; Silicon Carbide (SiC) Fibers to improve thermal heat transfer in normal operating conditions which also improves margin in accident conditions and the potential to lock up iodine into the fuel matrix; Nano-diamond particles to enhance thermal conductivity; Coatings on the fuel cladding; and Nine coatings on the existing Zircaloy cladding to increase coping time and reduce clad oxidation and hydrogen generation during accident conditions, as well as reduce hydrogen pickup and mitigate hydride reorientation in the cladding. To facilitate the development process AREVA adopted a formal “Gate Review Process” (GR) that was used to review results and focus resources onto promising technologies to reduce costs and identify the technologies that would potentially be carried forward to LFAs within a 10 year period. During the initial discovery phase of the project AREVA took the decision to be relatively hands off and allow our university and National Laboratory partners to be free thinking and consider options that would not be constrained by preconceived ideas from the fuel vendor. To counter

  17. Facile fabrication of network film electrodes with ultrathin Au nanowires for nonenzymatic glucose sensing and glucose/O2 fuel cell.

    PubMed

    Yang, Lu; Zhang, Yijia; Chu, Mi; Deng, Wenfang; Tan, Yueming; Ma, Ming; Su, Xiaoli; Xie, Qingji; Yao, Shuozhuo

    2014-02-15

    We report here on the facile fabrication of network film electrodes with ultrathin Au nanowires (AuNWs) and their electrochemical applications for high-performance nonenzymatic glucose sensing and glucose/O2 fuel cell under physiological conditions (pH 7.4, containing 0.15M Cl(-)). AuNWs with an average diameter of ~7 or 2 nm were prepared and can self-assemble into robust network films on common electrodes. The network film electrode fabricated with 2-nm AuNWs exhibits high sensitivity (56.0 μA cm(-2)mM(-1)), low detection limit (20 μM), short response time (within 10s), excellent selectivity, and good storage stability for nonenzymatic glucose sensing. Glucose/O2 fuel cells were constructed using network film electrodes as the anode and commercial Pt/C catalyst modified glassy carbon electrode as cathode. The glucose/O2 fuel cell using 2-nm AuNWs as anode catalyst output a maximum power density of is 126 μW cm(-2), an open-circuit cell voltage of 0.425 V, and a short-circuit current density of 1.34 mA cm(-2), respectively. Due to the higher specific electroactive surface area of 2-nm AuNWs, the network film electrode fabricated with 2-nm AuNWs exhibited higher electrocatalytic activity toward glucose oxidation than the network film electrode fabricated with 7-nm AuNWs. The network film electrode exhibits high electrocatalytic activity toward glucose oxidation under physiological conditions, which is helpful for constructing implantable electronic devices. PMID:24035853

  18. Fabrication of fiber composites with a MAX phase matrix by reactive melt infiltration

    NASA Astrophysics Data System (ADS)

    Lenz, F.; Krenkel, W.

    2011-10-01

    Due to the inherent brittleness of ceramics it is very desirable to increase the damage tolerance of ceramics. The ternary MAX phases are a promising group of materials with high fracture toughness. The topic of this study is the development of ceramic matrix composites (CMCs) with a matrix containing MAX phases, to achieve a damage tolerant structural composite material. For this purpose carbon fiber reinforced preforms with a carbon-titanium carbide matrix (C/C-TiC) were developed and infiltrated with silicon by a pressureless reactive melt infiltration. Finally liquid silicon caused the formation of SiC, TiSi2 and Ti3SiC2 in the matrix of the composite.

  19. Advanced Fabrication Method for the Preparation of MOF Thin Films: Liquid-Phase Epitaxy Approach Meets Spin Coating Method.

    PubMed

    Chernikova, Valeriya; Shekhah, Osama; Eddaoudi, Mohamed

    2016-08-10

    Here, we report a new and advanced method for the fabrication of highly oriented/polycrystalline metal-organic framework (MOF) thin films. Building on the attractive features of the liquid-phase epitaxy (LPE) approach, a facile spin coating method was implemented to generate MOF thin films in a high-throughput fashion. Advantageously, this approach offers a great prospective to cost-effectively construct thin-films with a significantly shortened preparation time and a lessened chemicals and solvents consumption, as compared to the conventional LPE-process. Certainly, this new spin-coating approach has been implemented successfully to construct various MOF thin films, ranging in thickness from a few micrometers down to the nanometer scale, spanning 2-D and 3-D benchmark MOF materials including Cu2(bdc)2·xH2O, Zn2(bdc)2·xH2O, HKUST-1, and ZIF-8. This method was appraised and proved effective on a variety of substrates comprising functionalized gold, silicon, glass, porous stainless steel, and aluminum oxide. The facile, high-throughput and cost-effective nature of this approach, coupled with the successful thin film growth and substrate versatility, represents the next generation of methods for MOF thin film fabrication. Therefore, paving the way for these unique MOF materials to address a wide range of challenges in the areas of sensing devices and membrane technology. PMID:27415640

  20. Fabrication of SiC matrix composites by liquid phase infiltration with a polymeric precursor

    SciTech Connect

    Interrante, L.V.; Whitmarsh, C.W.; Sherwood, W.

    1995-10-01

    A process for the fabrication of SiC matrix composites has been developed which employs a liquid, highly branched, polycarbosilane (AHPCS). This polymer thermosets on heating at 200--400 C (or at 100 C with catalyst) and yields an amorphous SiC with low excess C and O content in 60--80% yield on pyrolysis to 1,000 C. Preforms consisting of C-coated Nicalon SiC fiber cloth, unidirectional Textron SiC SCS-6 fiber layups, or Mo boats packed with SiC whiskers, were infiltrated with the polymer, cured in an autoclave, and pyrolized to 1,000 C. Five to eight infiltration cycles gave net shape composites with final densities at 85--94% of theoretical. The results of 4-point flexure tests on the as-prepared Nicalon composites indicate flexure strengths (aver. 378 MPa) that are comparable to or better than similarly reinforced CVI-SiC matrix composites. The whisker and SCS-6 composites showed a small weight loss (10--20%) on heating to 1,500 C in Ar and little or no weight change or obvious embrittlement in air at 1,000 C.

  1. Significance of chamber pressure to complex multi-phase physics in jet engine fuel injection processes

    NASA Astrophysics Data System (ADS)

    Dahms, Rainer; Oefelein, Joseph

    2014-11-01

    Injection processes in jet engines at chamber pressures in excess of the thermodynamic critical pressure of the liquid fuel are not well understood. Under some conditions, a distinct two-phase interface may not exist anymore which eliminates the presence of classical spray atomization phenomena. A comprehensive model for jet engine fuel injections is derived to quantify the conditions under which the interfacial dynamics transition to diffusion-dominated mixing processes without surface tension. At certain conditions, the model shows two-phase interfaces with substantially increased thicknesses and distinctively reduced mean free paths in comparison to ambient pressure conditions. Then, the underlying assumptions of a distinct two-phase interface do not apply anymore and the interface along with its surface tension is shown to deteriorate as it broadens substantially. As a consequence of this physical complexity, the conceptual view of spray atomization and evaporation as an appropriate model for jet engine injection processes is, contrary to conventional wisdom, questionable at certain operating conditions. Instead, a Large Eddy Simulation using a dense-fluid approximation is applied which takes the complex thermo-physics of real-fluid behavior into account.

  2. Imidazolium-containing, hydrophobic-ionic-hydrophilic ABC triblock copolymers: synthesis, ordered phase-separation, and supported membrane fabrication

    SciTech Connect

    Wiesenauer, EF; Nguyen, PT; Newell, BS; Bailey, TS; Nobleb, RD; Gin, DL

    2013-01-01

    Novel ABC triblock copolymers containing hydrophobic, imidazolium ionic liquid (IL)-based ionic, and non-charged hydrophilic blocks were synthesized by direct sequential, ring-opening metathesis polymerization (ROMP) of three chemically immiscible norborene monomers. The resulting ABC triblock copolymers were found by small-angle X-ray scattering to phase-separate into different nanostructures in their pure melt states, depending on their block sequence and compositions. Supported composite membranes of these triblock copolymers were successfully fabricated with defect-free, <= 20 microns thick top coatings. Preliminary CO2/light gas transport studies demonstrated the potential of this new type of IL-based block copolymer material for gas separation applications.

  3. Fabrication of Quasi-Phase-Matching Structure during Paraelectric Borate Crystal Growth

    NASA Astrophysics Data System (ADS)

    Maeda, Kensaku; Uda, Satoshi; Fujiwara, Kozo; Nozawa, Jun; Koizumi, Haruhiko; Sato, Shun-ichi; Kozawa, Yuichi; Nakamura, Takahiro

    2013-01-01

    We report an unconventional approach to produce a periodically twinned crystal of a non-ferroelectric material that can function as a quasi-phase matching (QPM) device. A twin boundary control method was developed based on the twin boundary formation mechanism during crystallization, and a periodically twinned QPM structure was realized in a non-ferroelectric lithium tetraborate (Li2B4O7; LB4) crystal. It was demonstrated that the periodically twinned LB4 crystal can function as a QPM device, and the second-harmonic generation (SHG) light of a Nd:YAG laser was observed.

  4. Application of charge-dissipation material in MEBES phase-shift mask fabrication

    NASA Astrophysics Data System (ADS)

    Tan, Zoilo C. H.; Sauer, Charles A.

    1994-12-01

    Several charge dissipation materials were evaluated for their ability to improve the overlay accuracy during phase shift mask (PSM) registered writing on a MEBES system. These included an organic conductive polymer and a number of thin inorganic films, which were applied above or below the resist on a coated mask. When used with the resists, all conductive materials evaluated were capable of providing adequate charge dissipation during registered writing. Overlay accuracy of mean + 3 sigma

  5. Re-evaluating neptunium in uranyl phases derived from corroded spent fuel.

    SciTech Connect

    Fortner, J. A.; Finch, R. J.; Kropf, A. J.; Cunnane, J. C.; Chemical Engineering

    2004-11-01

    Interest in mechanisms that may control radioelement release from corroded commercial spent nuclear fuel (CSNF) has been heightened by the selection of the Yucca Mountain site in Nevada as the repository for high-level nuclear waste in the United States. Neptunium is an important radionuclide in repository models owing to its relatively long half-life and its high aqueous mobility as neptunyl [Np(V)O+2]. The possibility of neptunium sequestration into uranyl alteration phases produced by corroding CSNF would suggest-a process for lowering neptunium concentration and subsequent migration from a geologic repository. However, there remains little experimental evidence that uranyl compounds will, in fact, serve as long-term host phases for the retention of neptunium under conditions expected in a deep geologic repository. To directly explore this possibility, we examined specimens of uranyl alteration phases derived from humid-air-corroded CSNF by X-ray absorption spectroscopy to better determine neptunium uptake in these phases. Although neptunium fluorescence was readily observed from as-received CSNF, it was not observed from the uranyl alteration rind. We establish upper limits for neptunium incorporation into CSNF alteration phases that are significantly below previously reported concentrations obtained by using electron energy loss spectroscopy (EELS). We attribute the discrepancy to a plural-scattering event that creates a spurious EELS peak at the neptunium-MV energy.

  6. Re-Evaluating Neptunium in Uranyl Phases Derived from Corroded Spent Fuel

    SciTech Connect

    Fortner, Jeffrey A.; Finch, Robert J.; Kropf, A. Jeremy; Cunnane, James C.

    2004-11-15

    Interest in mechanisms that may control radioelement release from corroded commercial spent nuclear fuel (CSNF) has been heightened by the selection of the Yucca Mountain site in Nevada as the repository for high-level nuclear waste in the United States. Neptunium is an important radionuclide in repository models owing to its relatively long half-life and its high aqueous mobility as neptunyl [Np(V)O{sub 2}{sup +}]. The possibility of neptunium sequestration into uranyl alteration phases produced by corroding CSNF would suggest a process for lowering neptunium concentration and subsequent migration from a geologic repository. However, there remains little experimental evidence that uranyl compounds will, in fact, serve as long-term host phases for the retention of neptunium under conditions expected in a deep geologic repository. To directly explore this possibility, we examined specimens of uranyl alteration phases derived from humid-air-corroded CSNF by X-ray absorption spectroscopy to better determine neptunium uptake in these phases. Although neptunium fluorescence was readily observed from as-received CSNF, it was not observed from the uranyl alteration rind. We establish upper limits for neptunium incorporation into CSNF alteration phases that are significantly below previously reported concentrations obtained by using electron energy loss spectroscopy (EELS). We attribute the discrepancy to a plural-scattering event that creates a spurious EELS peak at the neptunium-M{sub V} energy.

  7. Soot and liquid-phase fuel distributions in a newly designed optically accessible D.I. diesel engine

    SciTech Connect

    Dec, J.E.; Espey, C.

    1993-10-01

    Two-dimensional (2-D) laser-sheet imaging has been used to examine the soot and liquid-phase fuel distributions in a newly designed, optically accessible, direct-injection Diesel engine of the heavy-duty size class. The design of this engine preserves the intake port geometry and basic dimensions of a Cummins N-series production engine. It also includes several unique features to provide considerable optical access. Liquid-phase fuel and soot distribution studies were conducted at a medium speed (1,200 rpm) using a Cummins closed-nozzle fuel injector. The scattering was used to obtain planar images of the liquid-phase fuel distribution. These images show that the leading edge of the liquid-phase portion of the fuel jet reaches a maximum length of 24 mm, which is about half the combustion bowl radius for this engine. Beyond this point virtually all the fuel has vaporized. Soot distribution measurements were made at a high load condition using three imaging diagnostics: natural flame luminosity, 2-D laser-induced incandescence, and 2-D elastic scattering. This investigation showed that the soot distribution in the combusting fuel jet develops through three stages. First, just after the onset of luminous combustion, soot particles are small and nearly uniformly distributed throughout the luminous region of the fuel jet. Second, after about 2 crank angle degrees a pattern develops of a higher soot concentration of larger sized particles in the head vortex region of the jet and a lower soot concentration of smaller sized particles upstream toward the injector. Third, after fuel injection ends, both the soot concentration and soot particle size increase rapidly in the upstream portion of the fuel jet.

  8. Fabrication of solid-phase-sintered SiC-based composites with short carbon fibers

    NASA Astrophysics Data System (ADS)

    Li, Xian-hui; Yan, Qing-zhi; Han, Yong-jun; Cao, Mei-qi; Ge, Chang-chun

    2014-11-01

    Solid-phase-sintered SiC-based composites with short carbon fibers (Csf/SSiC) in concentrations ranging from 0 to 10wt% were prepared by pressureless sintering at 2100°C. The phase composition, microstructure, density, and flexural strength of the composites with different Csf contents were investigated. SEM micrographs showed that the Csf distributed in the SSiC matrix homogeneously with some gaps at the fiber/matrix interfaces. The densities of the composites decreased with increasing Csf content. However, the bending strength first increased and then decreased with increasing Csf content, reaching a maximum value of 390 MPa at a Csf content of 5wt%, which was 60 MPa higher than that of SSiC because of the pull-out strengthening mechanism. Notably, Csf was graphitized and damaged during the sintering process because of the high temperature and reaction with boron derived from the sintering additive B4C; this graphitization degraded the fiber strengthening effect.

  9. Liquid-phase catalytic processing of biomass-derived oxygenated hydrocarbons to fuels and chemicals.

    PubMed

    Chheda, Juben N; Huber, George W; Dumesic, James A

    2007-01-01

    Biomass has the potential to serve as a sustainable source of energy and organic carbon for our industrialized society. The focus of this Review is to present an overview of chemical catalytic transformations of biomass-derived oxygenated feedstocks (primarily sugars and sugar-alcohols) in the liquid phase to value-added chemicals and fuels, with specific examples emphasizing the development of catalytic processes based on an understanding of the fundamental reaction chemistry. The key reactions involved in the processing of biomass are hydrolysis, dehydration, isomerization, aldol condensation, reforming, hydrogenation, and oxidation. Further, it is discussed how ideas based on fundamental chemical and catalytic concepts lead to strategies for the control of reaction pathways and process conditions to produce H(2)/CO(2) or H(2)/CO gas mixtures by aqueous-phase reforming, to produce furan compounds by selective dehydration of carbohydrates, and to produce liquid alkanes by the combination of aldol condensation and dehydration/hydrogenation processes. PMID:17659519

  10. Heterogeneous Catalytic Conversion of Biobased Chemicals into Liquid Fuels in the Aqueous Phase.

    PubMed

    Wu, Kejing; Wu, Yulong; Chen, Yu; Chen, Hao; Wang, Jianlong; Yang, Mingde

    2016-06-22

    Different biobased chemicals are produced during the conversion of biomass into fuels through various feasible technologies (e.g., hydrolysis, hydrothermal liquefaction, and pyrolysis). The challenge of transforming these biobased chemicals with high hydrophilicity is ascribed to the high water content of the feedstock and the inevitable formation of water. Therefore, aqueous-phase processing is an interesting technology for the heterogeneous catalytic conversion of biobased chemicals. Different reactions, such as dehydration, isomerization, aldol condensation, ketonization, and hydrogenation, are applied for the conversion of sugars, furfural/hydroxymethylfurfural, acids, phenolics, and so on over heterogeneous catalysts. The activity, stability, and reusability of the heterogeneous catalysts in water are summarized, and deactivation processes and several strategies are introduced to improve the stability of heterogeneous catalysts in the aqueous phase. PMID:27158985

  11. Microstructured photopolymer films of electrochemically active monomers. Fabrication of an electrochemically switchable phase grating

    SciTech Connect

    Schanze, K.S.; Bergstedt, T.S.; Hauser, B.T.

    1995-12-01

    Contact photolithography is used to create thin polymeric films comprised of viologen and co-monomer (1:1 mole ratio). The poly-1/2 films are 100 - 150 nm thick with 5 {mu}m linewidths. Films of poly-1/2 supported on In-SnO{sub 2} display a quasi-reversible wave at -0.25 V vs. Ag/AgCl for the (2+/1+{sm_bullet}) couple of the viologen. Grating patterned poly-1/2 films with a spatial frequency of 100 lines/mm diffract light. The diffraction efficiency of these phase gratings increases substantially concomitant with electrochemical reduction of the viologen sites. The change in diffraction efficiency is reversible and is attributed to an electrochemically induced change in refractive index of the film.

  12. Phase separation predicted to induce water-rich channels in fuel cell membranes

    NASA Astrophysics Data System (ADS)

    Herbst, Daniel; Witten, Thomas; Tsai, Tsung-Han; Coughlin, Bryan; Maes, Ashley; Herring, Andrew

    2015-03-01

    Fuel cells are a promising alternative energy technology that convert chemical fuel directly into electric power. One important fundamental property is exactly how and where water is absorbed in the polyelectrolyte membrane. Previous theoretical studies have used idealized parameters. In this talk, I show how we made a rigorous connection to experiment to make parameter-free predictions of the water-swelling behavior, using self-consistent field theory. The model block co-polymers we studied form alternating hydrophilic/hydrophobic lamellar domains that absorb water in humid air. I will show how simple measurements of the hydrophilic portion in solution lead to predictions of non-uniform water distribution in the membrane, and compare the results to x-ray scattering. The results suggest locally near-uniform water distributions. In special cases, however, each hydrophilic lamella phase-separates, forming an additional water-rich lamella down the center, a beneficial arrangement for ion conductivity. A small amount of water enhances conductivity most when it is partitioned into such channels, improving fuel-cell performance. MURI #W911NF-10-1-0520.

  13. Fabrication development for high-level nuclear waste containers for the tuff repository; Phase 1 final report

    SciTech Connect

    Domian, H.A.; Holbrook, R.L.; LaCount, D.F. |

    1990-09-01

    This final report completes Phase 1 of an engineering study of potential manufacturing processes for the fabrication of containers for the long-term storage of nuclear waste. An extensive literature and industry review was conducted to identify and characterize various processes. A technical specification was prepared using the American Society of Mechanical Engineers Boiler & Pressure Vessel Code (ASME BPVC) to develop the requirements. A complex weighting and evaluation system was devised as a preliminary method to assess the processes. The system takes into account the likelihood and severity of each possible failure mechanism in service and the effects of various processes on the microstructural features. It is concluded that an integral, seamless lower unit of the container made by back extrusion has potential performance advantages but is also very high in cost. A welded construction offers lower cost and may be adequate for the application. Recommendations are made for the processes to be further evaluated in the next phase when mock-up trials will be conducted to address key concerns with various processes and materials before selecting a primary manufacturing process. 43 refs., 26 figs., 34 tabs.

  14. Analysis of an energy recovery system for reformate-based PEM fuel cells involving a binary two-phase mixture

    NASA Astrophysics Data System (ADS)

    Cao, Yiding

    A comprehensive analysis on a novel energy recovery system for reformate-based proton exchange membrane (PEM) fuel cell systems is presented. The energy recovery system includes a throttling valve, a heat exchanger, a compressor, and is coupled with a coolant loop for the fuel cell stack. The feed stock of the fuel reformer, which is primarily a mixture of water and fuel, is vaporized in the heat exchanger and is then compressed to a sufficiently high pressure before it is ducted into the fuel reformer. The analysis includes the throttling of two-phase fuel/water mixture and vaporization in the heat exchanger to obtain the temperature and pressure of the mixture at the inlet of the compressor. The results indicate that the power plant efficiency with the energy recovery system can be increased by more than 20% compared to that of a fuel cell power plant without the energy recovery system. Additionally, more than 25% of the waste heat generated by the fuel cell stack can be removed due to the energy recovery system, and the fuel burned for the fuel reforming purpose is reduced by more than 70%.

  15. Design, fabrication, and operation of capsules for the irradiation testing of candidate advanced space reactor fuel pins

    NASA Technical Reports Server (NTRS)

    Thoms, K. R.

    1975-01-01

    Fuel irradiation experiments were designed, built, and operated to test uranium mononitride (UN) fuel clad in tungsten-lined T-111 and uranium dioxide fuel clad in both tungsten-lined T-111 and tungsten-lined Nb-1% Zr. A total of nine fuel pins was irradiated at average cladding temperatures ranging from 931 to 1015 C. The UN experiments, capsules UN-4 and -5, operated for 10,480 and 10,037 hr, respectively, at an average linear heat generation rate of 10 kW/ft. The UO2 experiment, capsule UN-6, operated for 8333 hr at an average linear heat generation rate of approximately 5 kW/ft. Following irradiation, the nine fuel pins were removed from their capsules, externally examined, and sent to the NASA Plum Brook Facility for more detailed postirradiation examination. During visual examination, it was discovered that the cladding of the fuel pin containing dense UN in each of capsules UN-4 and -5 had failed, exposing the UN fuel to the NaK in which the pins were submerged and permitting the release of fission gas from the failed pins. A rough analysis of the fission gas seen in samples of the gas in the fuel pin region indicated fission gas release-to-birth rates from these fuel pins in the range of .00001.

  16. Serum Profiling of Rat Dermal Exposure to JP-8 Fuel Reveals an Acute-Phase Response.

    PubMed

    Larabee, Jason L; Hocker, James R; Cheung, John Y; Gallucci, Randle M; Hanas, Jay S

    2008-01-01

    ABSTRACT Dermal exposure to JP-8 petroleum jet fuel leads to toxicological responses in humans and rodents. Serum profiling is a molecular analysis of changes in the levels of serum proteins and other molecules in response to changes in physiology. This present study utilizes serum profiling approaches to examine biomolecular changes in the sera of rats exposed to dermal applications of JP-8 (jet propulsion fuel-8). Using gel electrophoresis and electrospray ionization (ESI) mass spectrometry (MS), levels of serum proteins as well as low-mass constituents were found to change after dermal exposures to JP-8. The serum protein levels altered included the acute-phase response proteins haptoglobin, ceruloplasmin, alpha(1)-inhibitor III, and apolipoprotein A-IV. Haptoglobin levels increased after a 1-day JP-8 dermal exposure and continued to increase through 7 days of exposure. Ceruloplasmin levels increased after 5 days of exposure. Serum alpha(1)-inhibitor III was reduced after a 1-day exposure and the depletion continued after 7 days of exposure. Apolipoprotein A-IV increased after a 1-day exposure and then returned to basal levels after 3- and 5-day exposures of JP-8. Levels of the acute-phase protein alpha(2)-macroglobulin were found to not vary over these time course studies. Using ESI-MS analysis directly on the sera from rats exposed to dermal JP-8, low-mass sera constituents were found to correlate with control (acetone) or JP-8 exposure. PMID:20020890

  17. International comparison of a depletion calculation benchmark devoted to fuel cycle issues results from the phase 1 dedicated to PWR-UOx fuels

    SciTech Connect

    Roque, B.; Kilger, R.; Laugier, F.; Marimbeau, P.; Riffard, C.; Thro, J. F.; Yudkevich, M.; Hesketh, K.; Sartori, E.

    2006-07-01

    This paper presents the results from the first phase of an international depletion calculations comparison devoted to PWR-UOx fuel cycle issues. This 'benchmark' has been defined within the NEA/OECD Working Party on Scientific Issues in Reactors Systems (WPRS). The aim is to investigate a large range of isotopes, physics quantities and fuel types applied to fuel and back-end cycle configurations. The results analyses have shown that there is a good agreement between participants for the mass calculation of many isotopes. However, it is interesting to observe that better agreement is obtained for isotopes which benefit from experimental validation. In this benchmark, the poorest agreement is obtained in calculating activation products originating from fuel impurities. Some discrepancies on neutron emission rates were also observed, mainly due to the discrepancies on masses calculations. Good agreement was obtained for the total decay heat calculation. (authors)

  18. Carbon nanotubes reinforced poly(L-lactide) scaffolds fabricated by thermally induced phase separation

    NASA Astrophysics Data System (ADS)

    Ma, Haiyun; Xue, Li

    2015-01-01

    In tissue engineering, porous nanocomposite scaffolds can potentially mimic aspects of the nanoscale architecture of the extra-cellular matrix, as well as enhance the mechanical properties required for successful weight-bearing implants. In this paper, we demonstrate that highly porous thermoplastic poly(L-lactide) nanocomposite scaffolds containing different types of functionalized multi-walled carbon nanotubes (CNTs). The nanocomposite scaffolds were manufactured by a thermally induced phase separation method. This experiment produced an uniform distribution of CNTs throughout the scaffold without obvious aggregations for funtionalized CNTs filled scaffolds by scanning electron microscope observation. The CNTs were frequently located on the pore surface, forming rough, hairy nano-textures. The pore size was reduced with the increasing of CNT loading. Parts of PLLA matrix was induced into nanofibrous structures from solid-walled state, which reduced the crystallinity of the PLLA characterized by DSC measurement. The CNT incorporation significantly improved the compression modulus of the nanocomposite scaffolds, especially the functionalized CNTs. The capacity of protein adsorption is significantly improved when the concentration of the CNTs was higher than 1.0 wt.% and the cell attachment was also enhanced by the addition of CNTs, especially N-CNT.

  19. Carbon nanotubes reinforced poly(L-lactide) scaffolds fabricated by thermally induced phase separation.

    PubMed

    Ma, Haiyun; Xue, Li

    2015-01-16

    In tissue engineering, porous nanocomposite scaffolds can potentially mimic aspects of the nanoscale architecture of the extra-cellular matrix, as well as enhance the mechanical properties required for successful weight-bearing implants. In this paper, we demonstrate that highly porous thermoplastic poly(L-lactide) nanocomposite scaffolds containing different types of functionalized multi-walled carbon nanotubes (CNTs). The nanocomposite scaffolds were manufactured by a thermally induced phase separation method. This experiment produced an uniform distribution of CNTs throughout the scaffold without obvious aggregations for funtionalized CNTs filled scaffolds by scanning electron microscope observation. The CNTs were frequently located on the pore surface, forming rough, hairy nano-textures. The pore size was reduced with the increasing of CNT loading. Parts of PLLA matrix was induced into nanofibrous structures from solid-walled state, which reduced the crystallinity of the PLLA characterized by DSC measurement. The CNT incorporation significantly improved the compression modulus of the nanocomposite scaffolds, especially the functionalized CNTs. The capacity of protein adsorption is significantly improved when the concentration of the CNTs was higher than 1.0 wt.% and the cell attachment was also enhanced by the addition of CNTs, especially N-CNT. PMID:25525708

  20. Phase field modeling of microstructure evolution of electrocatalyst-infiltrated solid oxide fuel cell cathodes

    NASA Astrophysics Data System (ADS)

    Liang, Linyun; Li, Qun; Hu, Jiamian; Lee, Shiwoo; Gerdes, Kirk; Chen, Long-Qing

    2015-02-01

    A phase field model is developed to examine microstructural evolution of an infiltrated solid oxide fuel cell cathode. It is employed to generate the three-phase backbone microstructures and morphology of infiltrate nano-particles [La1-xSrxMnO3 (LSM)]. Two-phase Y2O3 + ZrO2 and LSM backbones composed of 0.5-1 μm particles are first generated and then seeded with infiltrate, and evolution is compared for starting infiltrate particle diameters of 5 nm and 10 nm. The computed lifetime triple phase boundary (3PB) density of the infiltrated cathode is then compared to the cathode backbone. Results indicate that initial coarsening of infiltrate nano-particles is the primary evolution process, and infiltrate coarsening is the majority contributor to 3PB reduction. However, at all times, the infiltrated cathode possesses significantly greater 3PB length than even the uncoarsened backbone. Infiltrate particle size effects indicate that the smaller particle size produces greater 3PB length for the same infiltration amount, consistent with intuition. A maximum 3PB enhancement is reached when increasing infiltrate particle loading, and the maximum enhancement depends on infiltrate particle size. It is found that architectural degradation modes will insignificantly affect the lifetime performance of infiltrated cathodes. This work suggests that lifetime optimized particle size/loading combinations are identifiable, and can be precise if additional fundamental data become available.

  1. Tunable complex magnetic states of epitaxial core-shell metal oxide nanocrystals fabricated by the phase decomposition method

    NASA Astrophysics Data System (ADS)

    Chang, S. J.; Lam, T. N.; Yang, C. Y.; Chen, Y. L.; Chu, Y. H.; Chueh, Y. L.; Tseng, Y. C.

    2016-07-01

    We report on the successful fabrication of epitaxial-discrete Co x Fe3‑x O4/CoO magnetic nanostructures on a SrTiO3 substrate as well as the results of a thorough investigation of the magnetic cross-reactions of the two phases in the vicinity of the epitaxial junction. These nanostructures were originally prepared as Fe3O4-CoO core-shell structures through the phase decomposition of bismuth perovskite precursors by pulsed-laser deposition. An antiphase boundary emerged during the structural/electronic transition from the CoO core to the Co1‑x Fe2+X O4 shell; this then developed into a ferrimagnetic/antiferromagnetic interface. Uncompensated spins (UCS) arose from the Co x Fe3‑x O4/CoO interface as a result of strong ferrimagnetic–antiferromagnetic interactions. A notable exchange bias as well as a significant exchange enhancement was observed owing to the UCS, which had a locking effect because of the decoupling of the Co1‑x Fe2+X O4/CoO reversal from the antiphase boundary. Control of the precursor ratio allowed for the fine-tuning of the Co1‑x Fe2+X O4 phase and the associated locking behaviors. This, in turn, allowed the anisotropy and coercivity of the nanostructures to be manipulated. Thus, we were able to create and thoroughly understand a complex epitaxial configuration with tunable structural and magnetic properties. This study should open new opportunities with regard to current magnetic oxide technology, which requires novel methods for pursuing extremity of controllable properties over an atomic landscape.

  2. DELTA PHASE PLUTONIUM ALLOYS

    DOEpatents

    Cramer, E.M.; Ellinger, F.H.; Land. C.C.

    1960-03-22

    Delta-phase plutonium alloys were developed suitable for use as reactor fuels. The alloys consist of from 1 to 4 at.% zinc and the balance plutonium. The alloys have good neutronic, corrosion, and fabrication characteristics snd possess good dimensional characteristics throughout an operating temperature range from 300 to 490 deg C.

  3. [Rapid fabrication of molecularly imprinted polymer fibers for solid phase microextraction of bisphenol A].

    PubMed

    Hu, Mei; Zhang, Yijun; Yang, Jinghua; Zhou, Xiaomao; Wei, Zhuqing; Ding, Xiaoqing; Zhang, Yuping

    2015-02-01

    The rapid preparation of molecularly imprinted polymer (MIP) fibers was reported using bisphenol A (BPA) as the template molecular, acetonitrile (ACN) as the porogenic solvent, α-methacrylic acid (MAA) as the functional monomer, ethylene dimethacrylate (EDMA) as the crosslinker, and azodiisobutyronitrile (AIBN) as the thermal initiator. It was carried out within a capillary of 530 µm inner diameter (I. D.) by microwave irradiation in 7 min. The resulted BPA-MIP fibers were pushed out from the capillary, eluted in a vial and inserted in the capillary again followed by the application of the solid phase microextraction (SPME) procedure. The extraction performance was investigated in detail by varying the molar ratios between the template and the monomer (BPA/MAA), the concentration of NaCl, the extraction and desorption time, the pH value and the desorption solvents. The selectivity of the prepared MIP and non-molecularly imprinted polymer (NIP) fibers was comparatively evaluated by selecting two structurally-related compounds, phenol (P) and 4-phenylphenol (PP), and non-analogue dicyandiamide (DCD). The established method was successfully applied for the pretreatment and determination of BPA from beverage samples coupled to high performance liquid chromatography (HPLC). Under the optimal conditions, the linear range of BPA was 10-400 µg/L; the detection limit (LOD) was 0.45 µg/L and the recoveries spiked in the mineral water were 88.4%-102. 8%. The results demonstrated that the developed method can determine BPA in real samples with some advantages of simple pretreatment, rapid analysis, low limit of detection and low consumption of materials. PMID:25989683

  4. Poly(cyclohexyl 2-cyanoacrylate-co-ethoxyethyl 2-cyanoacrylate) as a positive-tone electron beam resist for phase-shift mask fabrication

    NASA Astrophysics Data System (ADS)

    Tamura, Akira; Yonezawa, Masaji; Sato, Mitsuyoshi; Okuyama, T.

    1994-11-01

    Poly(cyclohexyl 2-cyanoacrylate) (PCHCA), a positive tone electron beam resist, has both high sensitivity and high dry-etching durability. Therefore, PCHCA has been successfully used for the fabrication of conventional chromium photomasks using dry-etching. However, when PCHCA was applied to the phase-shift mask fabrication, cracks were observed in resist patterns on the SiO2 shifter layer. The cyclic-alkyl group of PCHCA enhances dry-etching durability but causes the cracks in resist patterns. On the other hand, the noncyclic group prevent cracks, but reduces dry-etching durability. However, the copolymer of cyclohexyl 2- cyanoacrylate and ethoxyethyl 2-cyanoacrylate was delineated on SiO2 without generating cracks and reducing dry-etching durability, with high sensitivity. Using this copolymer, the phase-shift masks having SiO2 shifters with vertical walls were fabricated by dry-etching process in short time.

  5. Tracing Gas and Particle Phase Oxidation From Engine Sources as a Function of Fuel Type, Load, and Photochemical Age

    NASA Astrophysics Data System (ADS)

    Friedman, B.; Farmer, D.; Jathar, S.; Galang, A.; Fulgham, R.; Link, M.; Brophy, P.

    2015-12-01

    Motor vehicle emissions are an important source of anthropogenic gases and particles in the atmosphere. To study the gas and particle phase emissions, an HR-TOF-AMS and HR-TOF-CIMS were deployed at the CSU Engines Lab, along with an oxidative flow reactor, to measure emissions from a 4.5 L John Deere engine, which ran either diesel or biodiesel fuel. Concurrent gas-phase and particle-phase measurements allowed determination of the gas-phase and particle-phase oxidation properties as a function of fuel type, fuel load, and photochemical age. The impacts of particulate filers on composition and oxidation state were also assessed. While aerosol composition and associated oxidation properties for the biodiesel and diesel fuel types were similar, differences in photochemical production existed for the amount of load, or efficiency of the engine. The mean particulate oxygen to carbon ratios (O:C) and mean hydrogen to carbon ratios (H:C) moved from an initial 0.1 and 2 to a final 0.55 and 1.6, respectively, upon idle biodiesel and diesel engine exhaust exposure to approximately 7 days of OH exposure. The more efficient higher load biodiesel and diesel engine exhaust experienced less changes in the mean O:C and H:C values (an initial 0.1 and 2 to a final 0.3 and 1.7, respectively) with approximately the same amount of OH exposure. Despite largely scrubbing the majority of particles from the engine exhaust, experiments with engine particulate filters still showed photochemical production of oxidized particle-phase species at high photochemical ages, similar to that of idle engine exhaust without any particulate filters. Bulk gas-phase data was compared to bulk aerosol data in Van Krevelen space in order to understand how particle-phase oxidation traces gas-phase oxidation as a function of fuel type, engine load, and photochemical age.

  6. Assessment of PNGV fuels infrastructure. Phase 1 report: Additional capital needs and fuel-cycle energy and emissions impacts

    SciTech Connect

    Wang, M.; Stork, K.; Vyas, A.; Mintz, M.; Singh, M.; Johnson, L.

    1997-01-01

    This report presents the methodologies and results of Argonne`s assessment of additional capital needs and the fuel-cycle energy and emissions impacts of using six different fuels in the vehicles with tripled fuel economy (3X vehicles) that the Partnership for a New Generation of Vehicles is currently investigating. The six fuels included in this study are reformulated gasoline, low-sulfur diesel, methanol, ethanol, dimethyl ether, and hydrogen. Reformulated gasoline, methanol, and ethanol are assumed to be burned in spark-ignition, direct-injection engines. Diesel and dimethyl ether are assumed to be burned in compression-ignition, direct-injection engines. Hydrogen and methanol are assumed to be used in fuel-cell vehicles. The authors have analyzed fuels infrastructure impacts under a 3X vehicle low market share scenario and a high market share scenario. The assessment shows that if 3X vehicles are mass-introduced, a considerable amount of capital investment will be needed to build new fuel production plants and to establish distribution infrastructure for methanol, ethanol, dimethyl ether, and hydrogen. Capital needs for production facilities will far exceed those for distribution infrastructure. Among the four fuels, hydrogen will bear the largest capital needs. The fuel efficiency gain by 3X vehicles translates directly into reductions in total energy demand, fossil energy demand, and CO{sub 2} emissions. The combination of fuel substitution and fuel efficiency results in substantial petroleum displacement and large reductions in emissions of nitrogen oxide, carbon monoxide, volatile organic compounds, sulfur oxide, and particulate matter of size smaller than 10 microns.

  7. Research and development of proton-exchange membrane (PEM) fuel cell system for transportation applications. Phase I final report

    SciTech Connect

    1996-01-01

    Objective during Phase I was to develop a methanol-fueled 10-kW fuel cell power source and evaluate its feasibility for transportation applications. This report documents research on component (fuel cell stack, fuel processor, power source ancillaries and system sensors) development and the 10-kW power source system integration and test. The conceptual design study for a PEM fuel cell powered vehicle was documented in an earlier report (DOE/CH/10435-01) and is summarized herein. Major achievements in the program include development of advanced membrane and thin-film low Pt-loaded electrode assemblies that in reference cell testing with reformate-air reactants yielded performance exceeding the program target (0.7 V at 1000 amps/ft{sup 2}); identification of oxidation catalysts and operating conditions that routinely result in very low CO levels ({le} 10 ppm) in the fuel processor reformate, thus avoiding degradation of the fuel cell stack performance; and successful integrated operation of a 10-kW fuel cell stack on reformate from the fuel processor.

  8. Advanced Petroleum-Based Fuels--Diesel Emissions Control Project (APBF-DEC): Lubricants Project, Phase 1 Summary, July 2004

    SciTech Connect

    Not Available

    2004-07-01

    The Advanced Petroleum Based Fuels-Diesel Emission Control project is a government/industry collaborative project to identify the optimal combinations of low-sulfur diesel fuels, lubricants, diesel engines, and emission control systems to meet projected emission standards for the 2004-2010 time period. This summary describes the results of the first phase of the lubricants study investigating the impact on lubricant formulation on engine-out emissions.

  9. Kinetic Stabilization of Ordered Intermetallic Phases as Fuel Cell Anode Materials

    SciTech Connect

    Liu, Yi; Lowe, Michael A.; DiSalvo, Francis J.; Abruña, Héctor D.

    2010-08-16

    The influence of fuel molecules on the stability of the ordered intermetallic PtBi and PtPb phases has been extensively studied by synchrotron-based in situ X-ray grazing incidence diffraction under active electrochemical control. Cycling the potential to increasingly positive values resulted in little change to the surface composition and crystalline structure when specific fuel molecules (such as formic acid for PtBi and formic acid or methanol for PtPb) were oxidized at the intermetallic electrode surface. This was demonstrated by the absence of diffraction peaks due to Pt domains that would be generated by the leaching out of the less noble metal. This phenomenon has been rationalized as a competition process between the oxidation of fuel molecules at the electrode surface and corrosion and damage of the surface due to the electrochemical treatment. For example, PtBi electrodes, which exhibit excellent catalytic activity toward the oxidation of formic acid, could be kinetically stabilized to such a corrosion/degradation process in the presence of formic acid even at relatively positive potentials. An analogous effect was observed for PtPb in the presence of methanol as fuel. In the absence of fuel molecules (formic acid for PtBi and formic acid and/or methanol for PtPb), various surface layers were generated by different electrochemical pretreatments in the presence of only a supporting electrolyte. Crystalline oxidized bismuth species (such as Bi2O3) with an ~50 nm domain size were formed on the PtBi electrode surface by holding the potential at +1.00 V or beyond for at least 30 min. On the other hand, platinum nanopaticles with an ~5 nm crystalline domain size were formed when cycling the potential to higher values. In the case of PtPb, the only detected corrosion product was PbSO 4, whose diffraction peaks were utilized to qualitatively analyze the lead leaching-out and dissolution processes. No crystalline lead oxide species

  10. Multi-fuel reformers for fuel cells used in transportation: Assessment of hydrogen storage technologies. Phase 1, Final report

    SciTech Connect

    Not Available

    1994-03-01

    This report documents a portion of the work performed Multi-fuel Reformers for Fuel Cells Used in Transportation. One objective for development is to develop advanced fuel processing systems to reform methanol, ethanol, natural gas, and other hydrocarbons into hydrogen for use in transportation fuel cell systems, while a second objective is to develop better systems for on-board hydrogen storage. This report examines techniques and technology available for storage of pure hydrogen on board a vehicle as pure hydrogen of hydrides. The report focuses separately on near- and far-term technologies, with particular emphasis on the former. Development of lighter, more compact near-term storage systems is recommended to enhance competitiveness and simplify fuel cell design. The far-term storage technologies require substantial applied research in order to become serious contenders.

  11. Potential use of California lignite and other alternate fuel for enhanced oil recovery. Phase I and II. Final report. [As alternative fuels for steam generation in thermal EOR

    SciTech Connect

    Shelton, R.; Shimizu, A.; Briggs, A.

    1980-02-01

    The Nation's continued reliance on liquid fossil fuels and decreasing reserves of light oils gives increased impetus to improving the recovery of heavy oil. Thermal enhanced oil recovery EOR techniques, such as steam injection, have generally been the most effective for increasing heavy oil production. However, conventional steam generation consumes a large fraction of the produced oil. The substitution of alternate (solid) fuels would release much of this consumed oil to market. This two-part report focuses on two solid fuels available in California, the site of most thermal EOR - petroleum coke and lignite. Phase I, entitled Economic Analysis, shows detailed cost comparisons between the two candidate fuels and also with Western coal. The analysis includes fuels characterizations, process designs for several combustion systems, and a thorough evaluation of the technical and economic uncertainties. In Phase II, many technical parameters of petroleum coke combustion were measured in a pilot-plant fluidized bed. The results of the study showed that petroleum coke combustion for EOR is feasible and cost effective in a fluidized bed combustor.

  12. Fabrication of an anode-supported yttria-stabilized zirconia thin film for solid-oxide fuel cells via wet powder spraying

    NASA Astrophysics Data System (ADS)

    Zhou, Wei; Shi, Huangang; Ran, Ran; Cai, Rui; Shao, Zongping; Jin, Wanqin

    The wet powder spraying (WPS) technique was used for the deposition of dense and thin (Y 2O 3) 0.08(ZrO 2) 0.92 (YSZ-8) films on an anode substrate being used for fuel cell applications. Both agglomeration of the powder and the presence of organics in the substrate have a significant effect on the quality and densification of the thin electrolyte layer. High-energy ball milling effectively broke up the agglomerates and enhanced the packing density of the green layer. Pre-calcination of the substrate at ∼1000 °C enhanced the match of sintering shrinkage between the electrolyte layer and the substrate and improved the quality of the YSZ-8 thin film significantly. Crack-free dual-layer assembly with a highly densified YSZ-8 film as thin as 10 μm was successfully fabricated by optimizing the fabrication parameters. The cells with a La 0.8Sr 0.2MnO 3 cathode showed a high open circuit voltage of 1.071 V and a peak power density of 894 mW cm -2 at 850 °C operated with hydrogen fuel.

  13. Process Modeling Phase I Summary Report for the Advanced Gas Reactor Fuel Development and Qualification Program

    SciTech Connect

    Pannala, Sreekanth; Daw, C Stuart; Boyalakuntla, Dhanunjay S; FINNEY, Charles E A

    2006-09-01

    This report summarizes the results of preliminary work at Oak Ridge National Laboratory (ORNL) to demonstrate application of computational fluid dynamics modeling to the scale-up of a Fluidized Bed Chemical Vapor Deposition (FBCVD) process for nuclear fuels coating. Specifically, this work, referred to as Modeling Scale-Up Phase I, was conducted between January 1, 2006 and March 31, 2006 in support of the Advanced Gas Reactor (AGR) Program. The objective was to develop, demonstrate and "freeze" a version of ORNL's computational model of the TRI ISOtropic (TRISO) fuel-particle coating process that can be specifically used to assist coater scale-up activities as part of the production of AGR-2 fuel. The results in this report are intended to serve as input for making decisions about initiating additional FBCVD modeling work (referred to as Modeling Scale-Up Phase II) in support of AGR-2. The main computational tool used to implement the model is the general-purpose multiphase fluid-dynamics computer code known as MFIX (Multiphase Flow with Interphase eXchanges), which is documented in detail on the DOE-sponsored website http://www.mfix.org. Additional computational tools are also being developed by ORNL for post-processing MFIX output to efficiently summarize the important information generated by the coater simulations. The summarized information includes quantitative spatial and temporal measures (referred to as discriminating characteristics, or DCs) by which different coater designs and operating conditions can be compared and correlated with trends in product quality. The ORNL FBCVD modeling work is being conducted in conjunction with experimental coater studies at ORNL with natural uranium CO (NUCO) and surrogate fuel kernels. Data are also being obtained from ambient-temperature, spouted-bed characterization experiments at the University of Tennessee and theoretical studies of carbon and silicon carbide chemical vapor deposition kinetics at Iowa State

  14. Phase evolution and microstructure of high Jc SiC doped MgB2 fabricated by hot pressing

    NASA Astrophysics Data System (ADS)

    Qu, B.; Sun, X. D.; Li, J.-G.; Xiu, Z. M.; Xue, C. P.

    2009-07-01

    We report the phase evolution, microstructure, and critical current density (Jc) of the SiC doped MgB2 superconductors. In our study, all samples were fabricated by hot pressing with a heating rate of 200 °C min-1. The results show that the reaction of 2Mg+SiC = Mg2Si+C can occur at about 500 °C, about 50 °C lower than the formation temperature of MgB2. On the other hand, according to the experimental results and thermodynamic calculations, boron (B) does not react with SiC to form B4C and Si, neither does MgB2 react with SiC to form Mg2Si and B4C. The MgB2 phase was formed via both a solid-solid reaction (during the heating process between about 500 and 650 °C) and a liquid-solid reaction (>650 °C) after the melting of Mg, and the two reactions resulted in differences in the grain size of the MgB2. From scanning electron microscopy, the Mg2Si particles are homogeneously distributed within the MgB2 matrix, with particle sizes ranging from 35 to 230 nm. From the perspective of superconductivity, the C substitution results in strong electron scattering centers in the MgB2 structure. It reduces the electron mean free path and thus may significantly enhance the magnetic Jc. The peak Jc of the 5 wt% SiC doped MgB2 reaches above 106 A cm-2 at 5 K, and decreases slowly with increasing field, remaining high, above 105 A cm-2, at 7 T.

  15. Fabricate and Install Yakima Basin Phase II Fish Screens; Washington Department of Fish and Wildlife, 2002-2003 Annual Report.

    SciTech Connect

    Schille, Patrick C.

    2004-03-01

    The goal of this project is to prevent mortality and/or injury to all life stages of anadromous and resident fish at irrigation diversions. Obsolete Yakima basin fish screens constructed in the 1930's, 40's, 50's, 60's, and 70's must be replaced or updated to comply with current regional fish screen biological protection criteria adopted by Columbia Basin Fish and Wildlife Authority (CBFWA), Fish Screening Oversight Committee (FSOC) in 1995. This goal is being accomplished through an on-going effort by the Yakima Basin Phase II Technical Work Group (TWG), which is comprised of local, state, federal, tribal and private groups who prioritizes and assign screening projects. Prioritized screening projects are completed through coordination between the Bureau of Reclamations (BOR), who design and permit, and the WDFW who fabricate the screens for these projects. The following is the 2004 fish screening facility construction schedule as proposed by the Bureau of Reclamation Design Group (USBR) and Fish Passage Technical Work Group (TWG).

  16. Fabrication of a Dipole-assisted Solid Phase Extraction Microchip for Trace Metal Analysis in Water Samples.

    PubMed

    Shih, Tsung-Ting; Hsu, I-Hsiang; Chen, Ping-Hung; Chen, Shun-Niang; Tseng, Sheng-Hao; Deng, Ming-Jay; Lin, Yang-Wei; Sun, Yuh-Chang

    2016-01-01

    This paper describes a fabrication protocol for a dipole-assisted solid phase extraction (SPE) microchip available for trace metal analysis in water samples. A brief overview of the evolution of chip-based SPE techniques is provided. This is followed by an introduction to specific polymeric materials and their role in SPE. To develop an innovative dipole-assisted SPE technique, a chlorine (Cl)-containing SPE functionality was implanted into a poly(methyl methacrylate) (PMMA) microchip. Herein, diverse analytical techniques including contact angle analysis, Raman spectroscopic analysis, and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) analysis were employed to validate the utility of the implantation protocol of the C-Cl moieties on the PMMA. The analytical results of the X-ray absorption near-edge structure (XANES) analysis also demonstrated the feasibility of the Cl-containing PMMA used as an extraction medium by virtue of the dipole-ion interactions between the highly electronegative C-Cl moieties and the positively charged metal ions. PMID:27584954

  17. Effect of water content on partial ternary phase diagram water-in-diesel microemulsion fuel

    NASA Astrophysics Data System (ADS)

    Mukayat, Hastinatun; Badri, Khairiah Haji; Raman, Ismail Ab.; Ramli, Suria

    2014-09-01

    Introduction of water in the fuel gave a significant effect to the reduction of pollutant such as NOx emission. In this work, water/diesel microemulsion fuels were prepared using compositional method by mixing water and diesel in the presence of non-ionic surfactant and co-surfactant. The effects of water composition on the partial ternary phase diagram were studied at 5%, 10%, 15% and 20% (w/w). The physical stability of the microemulsion was investigated at 45°C over a period of one month. The optimum formulae obtained were diesel/T80/1-penthanol/water 60:20:15:5 wt% (System 1), 55:20:15:10 wt% (System 2), 50:20:15:15 wt% (System 3) and 45:20:15:20 wt% (System 4). Physicochemical characterizations of optimum formulae were studied. The results showed that water content has a significant effect to the formation of microemulsion, its stability, droplet size and viscosity.

  18. Two-dimensional two-phase thermal model for passive direct methanol fuel cells

    NASA Astrophysics Data System (ADS)

    Chen, R.; Zhao, T. S.; Yang, W. W.; Xu, C.

    A two-dimensional two-phase thermal model is presented for direct methanol fuel cells (DMFC), in which the fuel and oxidant are fed in a passive manner. The inherently coupled heat and mass transport, along with the electrochemical reactions occurring in the passive DMFC is modeled based on the unsaturated flow theory in porous media. The model is solved numerically using a home-written computer code to investigate the effects of various operating and geometric design parameters, including methanol concentration as well as the open ratio and channel and rib width of the current collectors, on cell performance. The numerical results show that the cell performance increases with increasing methanol concentration from 1.0 to 4.0 M, due primarily to the increased operating temperature resulting from the exothermic reaction between the permeated methanol and oxygen on the cathode and the increased mass transfer rate of methanol. It is also shown that the cell performance upgrades with increasing the open ratio and with decreasing the rib width as the result of the increased mass transfer rate on both the anode and cathode.

  19. Fuel and power coproduction: The Liquid Phase Methanol (LPMEOH{trademark}) process demonstration at Kingsport

    SciTech Connect

    Drown, D.P.; Brown, W.R.; Heydorn, E.C.; Moore, R.B.; Schaub, E.S.; Brown, D.M.; Jones, W.C.; Kornosky, R.M.

    1997-12-31

    The Liquid Phase Methanol (LPMEOH{trademark}) process uses a slurry bubble column reactor to convert syngas (primarily a mixture of carbon monoxide and hydrogen) to methanol. Because of its superior heat management, the process is able to be designed to directly handle the carbon monoxide (CO)-rich syngas characteristic of the gasification of coal, petroleum coke, residual oil, wastes, or of other hydrocarbon feedstocks. When added to an integrated gasification combined cycle (IGCC) power plant, the LPMEOH{trademark} process converts a portion of the CO-rich syngas produced by the gasifier to methanol, and the remainder of the unconverted gas is used to fuel the gas turbine combined-cycle power plant. The LPMEOH{trademark} process has the flexibility to operate in a daily electricity demand load-following manner. Coproduction of power and methanol via IGCC and the LPMEOH{trademark} process provides opportunities for energy storage for electrical demand peak shaving, clean fuel for export, and/or chemical methanol sales.

  20. End plate assembly having a two-phase fluid-filled bladder and method for compressing a fuel cell stack

    DOEpatents

    Carlstrom, Jr., Charles M.

    2001-01-01

    An end plate assembly is disclosed for use in a fuel cell assembly in which the end plate assembly includes a housing having a cavity, and a bladder receivable in the cavity and engageable with the fuel cell stack. The bladder includes a two-phase fluid having a liquid portion and a vapor portion. Desirably, the two-phase fluid has a vapor pressure between about 100 psi and about 600 psi at a temperature between about 70 degrees C. to about 110 degrees C.

  1. Two-phase Flow Characteristics in a Gas-Flow Channel of Polymer Electrolyte Membrane Fuel Cells

    NASA Astrophysics Data System (ADS)

    Cho, Sung Chan

    Fuel cells, converting chemical energy of fuels directly into electricity, have become an integral part of alternative energy and energy efficiency. They provide a power source of high energy-conversion efficiency and zero emission, meeting the critical demands of a rapidly growing society. The proton exchange membrane (PEM) fuel cells, also called polymer electrolyte fuel cells (PEFCs), are the major type of fuel cells for transportation, portable and small-scale stationary applications. They provide high-power capability, work quietly at low temperatures, produce only water byproduct and no emission, and can be compactly assembled, making them one of the leading candidates for the next generation of power sources. Water management is one of the key issues in PEM fuel cells: appropriate humidification is critical for the ionic conductivity of membrane while excessive water causes flooding and consequently reduces cell performance. For efficient liquid water removal from gas flow channels of PEM fuel cells, in-depth understanding on droplet dynamics and two-phase flow characteristics is required. In this dissertation, theoretical analysis, numerical simulation, and experimental testing with visualization are carried out to understand the two-phase flow characteristics in PEM fuel cell channels. Two aspects of two-phase phenomena will be targeted: one is the droplet dynamics at the GDL surface; the other is the two-phase flow phenomena in gas flow channels. In the former, forces over a droplet, droplet deformation, and detachment are studied. Analytical solutions of droplet deformation and droplet detachment velocity are obtained. Both experiments and numerical simulation are conducted to validate analytical results. The effects of contact angle, channel geometry, superficial air velocity, properties of gas phase fluids are examined and criteria for the detachment velocity are derived to relate the Reynolds number to the Weber number. In the latter, two-phase flow

  2. Determination of aromatic compounds in water by solid phase microextraction and ultraviolet absorption spectroscopy. 2. Application to fuel aromatics

    SciTech Connect

    Wittkamp, B.L.; Tilotta, D.C.; Hawthorne, S.B.

    1997-03-15

    Solid phase microextraction is coupled with ultraviolet absorption spectroscopy to determine fuel aromatic hydrocarbons from unleaded gasoline, jet fuel (JP4), and no. 1 diesel fuel in water. A rectangular `chip` of poly(dimethylsiloxane) (OV-1) was used as the sorbent medium to selectively partition the various fuels from real water matrices without interferences from naturally occurring organics (e.g., humic and fulvic acids). Equilibration times are under 45 min for the majority of aromatic compounds and range from 150 to 300 min for the three fuels. However, it is shown that the fuels can be quantitated at significantly shorter extraction times (45 min), resulting in only a loss of nearly 2x in the detection limits. Detection limits for unleaded gasoline, JP4, and no. 1 diesel fuel (obtained at their 100% equilibration times) are 4.9, 17, and 9.0 ppb, respectively. In addition, recovery data for the aromatic components from unleaded gasoline, JP4, and no. 1 diesel fuel from two real water matrices are in the range of 87-106%, with RSDs in the range of 5.0-10%. 4 refs., 2 figs., 6 tabs.

  3. Synthesis of dimethyl ether and alternative fuels in the liquid phase from coal-derived synthesis gas. Final technical report

    SciTech Connect

    Not Available

    1993-02-01

    Through the mid-1980s, Air Products has brought the liquid phase approach to a number of other synthesis gas reactions where effective heat management is a key issue. In 1989, in response to DOE`s PRDA No. DE-RA22-88PC88805, Air Products proposed a research and development program entitled ``Synthesis of Dimethyl Ether and Alternative Fuels in the Liquid Phase from Coal Derived Syngas.`` The proposal aimed at extending the LPMEOH experience to convert coal-derived synthesis gas to other useful fuels and chemicals. The work proposed included development of a novel one-step synthesis of dimethyl ether (DME) from syngas, and exploration of other liquid phase synthesis of alternative fuel directly from syngas. The one-step DME process, conceived in 1986 at Air Products as a means of increasing syngas conversion to liquid products, envisioned the concept of converting product methanol in situ to DME in a single reactor. The slurry reactor based liquid phase technology is ideally suited for such an application, since the second reaction (methanol to DME) can be accomplished by adding a second catalyst with dehydration activity to the methanol producing reactor. An area of exploration for other alternative fuels directly from syngas was single-step slurry phase synthesis of hydrocarbons via methanol and DME as intermediates. Other possibilities included the direct synthesis of mixed alcohols and mixed ethers in a slurry reactor.

  4. Computational fluid dynamics modeling of two-phase flow in a BWR fuel assembly. Final CRADA Report.

    SciTech Connect

    Tentner, A.; Nuclear Engineering Division

    2009-10-13

    A direct numerical simulation capability for two-phase flows with heat transfer in complex geometries can considerably reduce the hardware development cycle, facilitate the optimization and reduce the costs of testing of various industrial facilities, such as nuclear power plants, steam generators, steam condensers, liquid cooling systems, heat exchangers, distillers, and boilers. Specifically, the phenomena occurring in a two-phase coolant flow in a BWR (Boiling Water Reactor) fuel assembly include coolant phase changes and multiple flow regimes which directly influence the coolant interaction with fuel assembly and, ultimately, the reactor performance. Traditionally, the best analysis tools for this purpose of two-phase flow phenomena inside the BWR fuel assembly have been the sub-channel codes. However, the resolution of these codes is too coarse for analyzing the detailed intra-assembly flow patterns, such as flow around a spacer element. Advanced CFD (Computational Fluid Dynamics) codes provide a potential for detailed 3D simulations of coolant flow inside a fuel assembly, including flow around a spacer element using more fundamental physical models of flow regimes and phase interactions than sub-channel codes. Such models can extend the code applicability to a wider range of situations, which is highly important for increasing the efficiency and to prevent accidents.

  5. Fabrication of photonic crystal structures by tertiary-butyl arsine-based metal–organic vapor-phase epitaxy for photonic crystal lasers

    NASA Astrophysics Data System (ADS)

    Yoshida, Masahiro; Kawasaki, Masato; De Zoysa, Menaka; Ishizaki, Kenji; Hatsuda, Ranko; Noda, Susumu

    2016-06-01

    The fabrication of air/semiconductor two-dimensional photonic crystal structures by air-hole-retained crystal regrowth using tertiary-butyl arsine-based metal–organic vapor-phase epitaxy for GaAs-based photonic crystal lasers is investigated. Photonic crystal air holes with filling factors of 10–13%, depths of ∼280 nm, and widths of 120–150 nm are successfully embedded. The embedded air holes exhibit characteristic shapes due to the anisotropy of crystal growth. Furthermore, a low lasing threshold of ∼0.5 kA/cm2 is achieved with the fabricated structures.

  6. RELAP5 Model of a Two-phase ThermoSyphon Experimental Facility for Fuels and Materials Irradiation

    SciTech Connect

    Carbajo, Juan J; McDuffee, Joel Lee

    2013-01-01

    The High Flux Isotope Reactor (HFIR) at Oak Ridge National Laboratory (ORNL) does not have a separate materials-irradiation flow loop and requires most materials and all fuel experiments to be placed inside a containment. This is necessary to ensure that internal contaminants such as fission products cannot be released into the primary coolant. As part of the safety basis justification, HFIR also requires that all experiments be able to withstand various accident conditions (e.g., loss of coolant) without generating vapor bubbles on the surface of the experiment in the primary coolant. As with any parallel flow system, HFIR is vulnerable to flow excursion events when vapor is generated in one of those flow paths. The effects of these requirements are to artificially increase experiment temperatures by introducing a barrier between the experimental materials and the HFIR coolant and to reduce experiment heat loads to ensure boiling doesn t occur. A new experimental facility for materials irradiation and testing in the HFIR is currently being developed to overcome these limitations. The new facility is unique in that it will have its own internal cooling flow totally independent of the reactor primary coolant and boiling is permitted. The reactor primary coolant will cool the outside of this facility without contacting the materials inside. The ThermoSyphon Test Loop (TSTL), a full scale prototype of the proposed irradiation facility to be tested outside the reactor, is being designed and fabricated (Ref. 1). The TSTL is a closed system working as a two-phase thermosyphon. A schematic is shown in Fig. 1. The bottom central part is the boiler/evaporator and contains three electric heaters. The vapor generated by the heaters will rise and be condensed in the upper condenser, the condensate will drain down the side walls and be circulated via a downcomer back into the bottom of the boiler. An external flow system provides coolant that simulates the HFIR primary coolant

  7. Gas-phase saturation and evaporative cooling effects during wet compression of a fuel aerosol under RCM conditions

    SciTech Connect

    Goldsborough, S.S.; Johnson, M.V.; Zhu, G.S.; Aggarwal, S.K.

    2011-01-15

    Wet compression of a fuel aerosol has been proposed as a means of creating gas-phase mixtures of involatile diesel-representative fuels and oxidizer + diluent gases for rapid compression machine (RCM) experiments. The use of high concentration aerosols (e.g., {proportional_to}0.1 mL{sub fuel}/L{sub gas}, {proportional_to}1 x 10{sup 9} droplets/L{sub gas} for stoichiometric fuel loading at ambient conditions) can result in droplet-droplet interactions which lead to significant gas-phase fuel saturation and evaporative cooling during the volumetric compression process. In addition, localized stratification (i.e., on the droplet scale) of the fuel vapor and of temperature can lead to non-homogeneous reaction and heat release processes - features which could prevent adequate segregation of the underlying chemical kinetic rates from rates of physical transport. These characteristics are dependent on many factors including physical parameters such as overall fuel loading and initial droplet size relative to the compression rate, as well as fuel and diluent properties such as the boiling curve, vaporization enthalpy, heat capacity, and mass and thermal diffusivities. This study investigates the physical issues, especially fuel saturation and evaporative cooling effects, using a spherically-symmetric, single-droplet wet compression model. n-Dodecane is used as the fuel with the gas containing 21% O{sub 2} and 79% N{sub 2}. An overall compression time and compression ratio of 15.3 ms and 13.4 are used, respectively. It is found that smaller droplets (d{sub 0}{proportional_to} 2-3 {mu}m) are more affected by 'far-field' saturation and cooling effects, while larger droplets (d{sub 0}{proportional_to} 14 {mu}m) result in greater localized stratification of the gas-phase due to the larger diffusion distances for heat and mass transport. Vaporization of larger droplets is more affected by the volumetric compression process since evaporation requires more time to be completed

  8. Comparison of Homogeneous and Heterogeneous CFD Fuel Models for Phase I of the IAEA CRP on HTR Uncertainties Benchmark

    SciTech Connect

    Gerhard Strydom; Su-Jong Yoon

    2014-04-01

    Computational Fluid Dynamics (CFD) evaluation of homogeneous and heterogeneous fuel models was performed as part of the Phase I calculations of the International Atomic Energy Agency (IAEA) Coordinate Research Program (CRP) on High Temperature Reactor (HTR) Uncertainties in Modeling (UAM). This study was focused on the nominal localized stand-alone fuel thermal response, as defined in Ex. I-3 and I-4 of the HTR UAM. The aim of the stand-alone thermal unit-cell simulation is to isolate the effect of material and boundary input uncertainties on a very simplified problem, before propagation of these uncertainties are performed in subsequent coupled neutronics/thermal fluids phases on the benchmark. In many of the previous studies for high temperature gas cooled reactors, the volume-averaged homogeneous mixture model of a single fuel compact has been applied. In the homogeneous model, the Tristructural Isotropic (TRISO) fuel particles in the fuel compact were not modeled directly and an effective thermal conductivity was employed for the thermo-physical properties of the fuel compact. On the contrary, in the heterogeneous model, the uranium carbide (UCO), inner and outer pyrolytic carbon (IPyC/OPyC) and silicon carbide (SiC) layers of the TRISO fuel particles are explicitly modeled. The fuel compact is modeled as a heterogeneous mixture of TRISO fuel kernels embedded in H-451 matrix graphite. In this study, a steady-state and transient CFD simulations were performed with both homogeneous and heterogeneous models to compare the thermal characteristics. The nominal values of the input parameters are used for this CFD analysis. In a future study, the effects of input uncertainties in the material properties and boundary parameters will be investigated and reported.

  9. Study of diffusion bond development in 6061 aluminum and its relationship to future high density fuels fabrication.

    SciTech Connect

    Prokofiev, I.; Wiencek, T.; McGann, D.

    1997-10-07

    Powder metallurgy dispersions of uranium alloys and silicides in an aluminum matrix have been developed by the RERTR program as a new generation of proliferation-resistant fuels. Testing is done with miniplate-type fuel plates to simulate standard fuel with cladding and matrix in plate-type configurations. In order to seal the dispersion fuel plates, a diffusion bond must exist between the aluminum coverplates surrounding the fuel meat. Four different variations in the standard method for roll-bonding 6061 aluminum were studied. They included mechanical cleaning, addition of a getter material, modifications to the standard chemical etching, and welding methods. Aluminum test pieces were subjected to a bend test after each rolling pass. Results, based on 400 samples, indicate that at least a 70% reduction in thickness is required to produce a diffusion bond using the standard rollbonding method versus a 60% reduction using the Type II method in which the assembly was welded 100% and contained open 9mm holes at frame corners.

  10. Application of the UMACS process to highly dense U1-xAmxO2±δ MABB fuel fabrication for the DIAMINO irradiation

    NASA Astrophysics Data System (ADS)

    Delahaye, Thibaud; Lebreton, Florent; Horlait, Denis; Herlet, Nathalie; Dehaudt, Philippe

    2013-01-01

    The DIAMINO irradiation program aims to assess the influence of Am content and microstructure on He release and fuel swelling for different irradiation temperatures during heterogeneous transmutation in the OSIRIS reactor. Such irradiation programs call for ceramic fuels compliant with strict specifications. In the case of the DIAMINO experiment, Am-bearing blanket fuels with two compositions (U1-xAmxO2±δ (x = 0.075, 0.15)) and two microstructures (dense and porous) were selected, corresponding with four sample sets. Porous samples (<85%TD) were fabricated using a process previously developed for a similar irradiation program while a new dedicated process, UMACS, was developed and applied to produce dense samples. Despite americium presence, this process, based on conventional sintering, produces samples with high density (˜96%TD) close to that usually obtained for UO2. In the case of Minor Actinide Bearing Blankets (MABB), such a result has never been obtained reproducibly even with reactive sintering or impregnation methods.

  11. Field test of short-notice random inspections for inventory-change verification at a low-enriched-uranium fuel-fabrication plant

    SciTech Connect

    Fishbone, L.G. |; Moussalli, G.; Naegele, G.

    1995-05-01

    An approach of short-notice random inspections (SNRIs) for inventory-change verification can enhance the effectiveness and efficiency of international safeguards at natural or low-enriched uranium (LEU) fuel fabrication plants. According to this approach, the plant operator declares the contents of nuclear material items before knowing if an inspection will occur to verify them. Additionally, items about which declarations are newly made should remain available for verification for an agreed time. Then a statistical inference can be made from verification results for items verified during SNRIs to the entire populations, i.e. the entire strata, even if inspectors were not present when many items were received or produced. A six-month field test of the feasibility of such SNRIs took place at the Westinghouse Electric Corporation Commercial Nuclear Fuel Division during 1993. Westinghouse personnel made daily declarations about both feed and product items, uranium hexafluoride cylinders and finished fuel assemblies, using a custom-designed computer ``mailbox``. Safeguards inspectors from the IAEA conducted eight SNRIs to verify these declarations. They arrived unannounced at the plant, in most cases immediately after travel from Canada, where the IAEA maintains a regional office. Items from both strata were verified during the SNRIs by meant of nondestructive assay equipment.

  12. Fabrication of phosphotungstic acid functionalized mesoporous silica composite membrane by alternative tape-casting incorporating phase inversion technique

    NASA Astrophysics Data System (ADS)

    Bai, Li; Zhang, Lan; He, Hong Quan; Rasheed, Raj Kamal S./O. Abdul; Zhang, Cai Zhi; Ding, Ovi Lian; Chan, Siew Hwa

    2014-01-01

    Meso-porous silica (MCM-41) membranes functionalized by phosphotungstic acid (HPW) for high temperature proton exchange membrane fuel cells (HT-PEMFCs) are successfully developed by a cost-effective tape-casting incorporating phase inversion and vacuum assisted wet impregnation techniques. The microstructure of the membrane is characterized by field emission scanning electron microscopy (FESEM). The effect of MCM-41 content on the tensile strength, ultimate elongation, and weight gain ratio and swelling ratio in water/methanol of the membranes are investigated in detail. The thermal stability of MCM-41 membrane with/without HPW is analyzed by thermogravimetric analysis (TGA) and derivative thermogravimetry (DTG) techniques. In particular, the effects of HPW loading and MCM-41 content on the proton conductivity of HPW/MCM-41 membranes are studied comprehensively. The results on the swelling ratio and tensile tension show that the developed membranes can be applied as an electrolyte membrane for HT-PEMFCs. The developed MCM-41 membrane, in which polyethersulfone (PESf) is used as the supporting backbone, is able to operate up to 200 °C. The single cell assembled from HPW/MCM-41 membrane with 70 wt.% HPW loading gives a peak output power of ∼230 mW cm-2 and ∼125 mW cm-2 in H2/air at 90 °C and in methanol/air at 150 °C without any humidification, respectively.

  13. Innovative fossil fuel fired vitrification technology for soil remediation. Phase 1

    SciTech Connect

    Not Available

    1994-01-01

    Vortec has successfully completed Phase 1 of the ``Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation`` program. The Combustion and Melting System (CMS) has processed 7000 pounds of material representative of contaminated soil that is found at DOE sites. The soil was spiked with Resource Conservation and Recovery Act (RCRA) metals surrogates, an organic contaminant, and a surrogate radionuclide. The samples taken during the tests confirmed that virtually all of the radionuclide was retained in the glass and that it did not leach to the environment-as confirmed by both ANS 16.1 and Toxicity Characteristic Leaching Procedure (TCLP) testing. The organic contaminant, anthracene, was destroyed during the test with a Destruction and Removal Efficiency (DRE) of at least 99.99%. RCRA metal surrogates, that were in the vitrified product, were retained and did not leach to the environment as confirmed by the TCLP testing. Semi-volatile RCRA metal surrogates were captured by the Air Pollution Control (APC) system, and data on the amount of metal oxide particulate and the chemical composition of the particulate were established for use in the Phase 2 APC subsystem design.

  14. Two-phase flow modeling for the cathode side of a polymer electrolyte fuel cell

    NASA Astrophysics Data System (ADS)

    Qin, Chaozhong; Rensink, Dirk; Fell, Stephan; Majid Hassanizadeh, S.

    2012-01-01

    Liquid water flooding in micro gas channels is an important issue in the water management of polymer electrolyte fuel cells (PEFCs). However, in most previous numerical studies liquid water transport in the gas channels (GC) has been simplified by the mist flow assumption. In this work, we present a two-phase flow model for the cathode side of a PEFC. The GC is assumed to be a structured porous medium with the porosity of 1.0. The two-phase Darcy's law is applied to both diffusion layers and GC. Based on the developed model, the liquid water flooding in the GC and its impact on the liquid water distribution in the diffusion layers are explored in detail. Furthermore, we study the effect of the immobile saturation on the predicted liquid water distribution in the diffusion layers. The results show that neglecting the GC flooding leads to an incorrect prediction of liquid water distribution in the diffusion layers and an overestimation of the cell performance. The gas flow rate in the GC can be optimized to achieve the best cell performance. Finally, when considering the immobile saturation in the model, more liquid water is predicted in the diffusion layers.

  15. Self-processing solgel material for one-step fabrication of micrometer-period sinusoidal phase gratings using the Lloyd's mirror scheme

    NASA Astrophysics Data System (ADS)

    He, Miao; Bu, Jing; Yuan, Xiaocong; Niu, Hanben; Peng, Xiang

    2005-10-01

    A novel self-processing silica-zirconia hybrid solgel material has been developed and employed in one-step fabrication of micrometer-period sinusoidal phase gratings. In the process, the gratings with a sinusoidal profile were corrugated on the surface of the solgel film by UV exposure using the Lloyd's mirror setup. No further development or etching step is needed to reveal the sinusoidal profile because the corrugation is formed due to the self-processing property of the solgel material, which is robust enough to be used as an end product. The period, amplitude, diffraction efficiency of the ±1 order, and surface roughness of one of the fabricated gratings are 0.99 µm, 330 nm, 30.56%, and 1.27 nm, respectively. The new self-processing material is practical and promising for fabrication of micro-optical elements.

  16. Self-processing solgel material for one-step fabrication of micrometer-period sinusoidal phase gratings using the Lloyd's mirror scheme.

    PubMed

    He, Miao; Bu, Jing; Yuan, Xiaocong; Niu, Hanben; Peng, Xiang

    2005-10-15

    A novel self-processing silica-zirconia hybrid solgel material has been developed and employed in one-step fabrication of micrometer-period sinusoidal phase gratings. In the process, the gratings with a sinusoidal profile were corrugated on the surface of the solgel film by UV exposure using the Lloyd's mirror setup. No further development or etching step is needed to reveal the sinusoidal profile because the corrugation is formed due to the self-processing property of the solgel material, which is robust enough to be used as an end product. The period, amplitude, diffraction efficiency of the +/-1 order, and surface roughness of one of the fabricated gratings are 0.99 microm, 330 nm, 30.56%, and 1.27 nm, respectively. The new self-processing material is practical and promising for fabrication of micro-optical elements. PMID:16252770

  17. Evaluation of a new method for chemical coating of aluminum wire with molecularly imprinted polymer layer. Application for the fabrication of triazines selective solid-phase microextraction fiber.

    PubMed

    Djozan, Djavanshir; Ebrahimi, Bahram; Mahkam, Mehrdad; Farajzadeh, Mir Ali

    2010-07-26

    A new solid-phase microextraction (SPME) fiber is fabricated through ultra violet irradiation polymerization of ametryn-molecularly imprinted polymer on the surface of anodized-silylated aluminum wire. The prepared fiber is durable with very good chemical and thermal stability which can be coupled to GC and GC/MS. The effective parameters on the fabrication and application procedures such as spraying mode, ultra violet irradiation (polymerization) time, number of sprayings and polymerizations, pH and ionic strength of sample and extraction time were optimized. This fiber shows high selectivity with great extraction capacity toward triazines. SPME and GC analysis of ametryn, prometryn, terbutryn, atrazine, simazine, propazine and cyanazine using the fabricated fiber result in the detection limits of 9, 32, 27, 43, 51, 74 and 85 ng mL(-1), respectively. The reliability of the prepared fiber in real samples has been investigated and proved by using spiked tap water, rice, maize and onion samples. PMID:20638497

  18. Analysis and control of a fuel delivery system considering a two-phase anode model of the polymer electrolyte membrane fuel cell stack

    NASA Astrophysics Data System (ADS)

    He, Jinglin; Ahn, Jongwoo; Choe, Song-Yul

    2011-05-01

    The fuel delivery system using both an ejector and a blower for a PEM fuel cell stack is introduced as a fuel efficiency configuration because of the possibility of hydrogen recirculation dependent upon load states. A high pressure difference between the cathode and anode could potentially damage the thin polymer electrolyte membrane. Therefore, the hydrogen pressure imposed to the stack should follow any change of the cathode pressure. In addition, stoichiometric ratio of the hydrogen should be maintained at a constant to prevent a fuel starvation at abrupt load changes. Furthermore, liquid water in the anode gas flow channels should be purged out in time to prevent flooding in the channels and other layers. The purging control also reduces the impurities concentration in cells to improve the cell performance. We developed a set of control oriented dynamic models that include a anode model considering the two-phase phenomenon and system components The model is used to design and optimize a state feedback controller along with an observer that controls the fuel pressure and stoichiometric ratio, whereby purging processes are also considered. Finally, included is static and dynamic analysis with respect to tracking and rejection performance of the proposed control.

  19. Phase Characteristics of a Number of U-Pu-Am-Np-Zr Metallic Alloys for Use as Fast Reactor Fuels

    SciTech Connect

    Douglas E. Burkes; J. Rory Kennedy; Thomas Hartmann; Cynthia A. Papesch; Denis D. Keiser, Jr.

    2010-01-01

    Metallic fuel alloys consisting of uranium, plutonium, and zirconium with minor additions of americium and neptunium are under evaluation for potential use to transmute long-lived transuranic actinide isotopes in fast reactors. A series of test designs for the Advanced Fuel Cycle Initiative (AFCI) have been irradiated in the Advanced Test Reactor (ATR), designated as the AFC-1 and AFC-2 designs. Metal fuel compositions in these designs have included varying amounts of U, Pu, Zr, and minor actinides (Am, Np). Investigations into the phase behavior and relationships based on the alloy constituents have been conducted using x-ray diffraction and differential thermal analysis. Results of these investigations, along with proposed relationships between observed behavior and alloy composition, are provided. In general, observed behaviors can be predicted by a ternary U-Pu-Zr phase diagram, with transition temperatures being most dependent on U content. Furthermore, the enthalpy associated with transitions is strongly dependent on the as-cast microstructural characteristics.

  20. Fabric phase sorptive extraction: An innovative sample preparation approach applied to the analysis of specific migration from food packaging.

    PubMed

    Aznar, M; Alfaro, P; Nerin, C; Kabir, A; Furton, K G

    2016-09-14

    Additives added to food packaging materials can migrate to food in contact with them during storage and shelf life. A novel simple, fast and sensitive analyte extraction method based on fabric phase sorptive extraction (FPSE), followed by analysis using ultra-high performance liquid chromatography and mass spectrometry detection (UPLC-MS) was applied to the analysis of 18 common non-volatile plastic additives. Three FPSE media coated with different sol-gel sorbents characterized with different polarities including sol-gel poly(dimethylsiloxane), sol-gel poly(ethylene glycol) and sol-gel poly(tetrahydrofuran) were studied. All three FPSE media showed very satisfactory results. In general, compounds with low logP values seemed to have higher enrichment factors (EFs), especially with poly(tetrahydrofuran) and poly(ethylene glycol) media. For compounds with high logP values, the use of sol-gel poly(dimethylsiloxane) improved the enrichment capacity. Sample preparation time was optimized at 20 min for sample extraction and 10 min for solvent desorption. Acetonitrile was selected as desorption solvent since recoveries were over 70% for 13 out of 18 selected compounds in all FPSE media. The best extraction recovery values were obtained when compounds were dissolved in aqueous acetic acid solution (3%), where 17 out of 18 compounds showed improvement in their signal intensity after FPSE extraction and 10 obtained enrichment factors above 3 for all the tested FPSE media. When FPSE extracts were concentrated under nitrogen, 11 out of 18 compounds reached EFs values above 100. PMID:27566344

  1. CHEMICALLY ACTIVE FLUID-BED PROCESS FOR SULPHUR REMOVAL DURING GASIFICATION OF HEAVY FUEL OIL - FOURTH PHASE

    EPA Science Inventory

    The report gives results of Phase 4 of a study on the CAFB process for gasification/desulfurization of liquid and solid fuels in a bed of hot lime. A new pilot unit was designed and constructed, incorporating such novel features as: a new fluidizing air distributor, high-flow/low...

  2. CHEMICALLY ACTIVE FLUID-BED PROCESS FOR SULPHUR REMOVAL DURING GASIFICATION OF HEAVY FUEL OIL - SECOND PHASE

    EPA Science Inventory

    The report describes the second phase of studies on the CAFB process for desulfurizing gasification of heavy fuel oil in a bed of hot lime. The first continuous pilot plant test with U.S. limestone BCR 1691 experienced local stone sintering and severe production of sticky dust du...

  3. REVIEW OF RESULTS FOR THE OECD/NEA PHASE VII BENCHMARK: STUDY OF SPENT FUEL COMPOSITIONS FOR LONG TERM DISPOSAL

    SciTech Connect

    Radulescu, Georgeta; Wagner, John C

    2011-01-01

    This paper summarizes the problem specification and compares participants results for the OECD/NEA/WPNCS Expert Group on Burn-up Credit Criticality Safety Phase VII Benchmark Study of Spent Fuel Compositions for Long-Term Disposal. The Phase VII benchmark was developed to study the ability of relevant computer codes and associated nuclear data to predict spent fuel isotopic compositions and corresponding keff values in a cask configuration over the time duration relevant to spent nuclear fuel (SNF) disposal. The benchmark was divided into two sets of calculations: (1) decay calculations out to 1,000,000 years for provided pressurized-water-reactor (PWR) UO2 discharged fuel compositions and (2) burnup credit criticality calculations for a representative cask model at selected time steps. Contributions from 15 organizations and companies in 10 countries were submitted to the Phase VII benchmark exercise. This paper provides a description of the Phase VII benchmark and detailed comparisons of the participants isotopic compositions and keff values that were calculated with a diversity of computer codes and nuclear data sets. Differences observed in the calculated time-dependent nuclide densities are attributed to different decay data or code-specific numerical approximations. The variability of the keff results is consistent with the evaluated uncertainty associated with cross-section data.

  4. DEMONSTRATION OF FUEL CELLS TO RECOVER ENERGY FROM ANAEROBIC DIGESTER GAS - PHASE I. CONCEPTUAL DESIGN, PRELIMINARY COST, AND EVALUATION STUDY

    EPA Science Inventory

    The report discusses Phase I (a conceptual design, preliminary cost, and evaluation study) of a program to demonstrate the recovery of energy from waste methane produced by anaerobic digestion of waste water treatment sludge. The fuel cell is being used for this application becau...

  5. Modeling of Selected Ceramic Processing Parameters Employed in the Fabrication of 238PuO 2 Fuel Pellets

    NASA Astrophysics Data System (ADS)

    Brockman, R. A.; Kramer, D. P.; Barklay, C. D.; Cairns-Gallimore, D.; Brown, J. L.; Huling, J. C.; Van Pelt, C. E.

    Recent deep space missions utilize the thermal output of the radioisotope plutonium-238 as the fuel in the thermal to electrical power system. Since the application of plutonium in its elemental state has several disadvantages, the fuel employed in these deep space power systems is typically in the oxide form such as plutonium-238 dioxide (238PuO2). As an oxide, the processing of the plutonium dioxide into fuel pellets is performed via "classical" ceramic processing unit operations such as sieving of the powder, pressing, sintering, etc. Modeling of these unit operations can be beneficial in the understanding and control of processing parameters with the goal of further enhancing the desired characteristics of the 238PuO2 fuel pellets. A finite element model has been used to help identify the time-temperature-stress profile within a pellet during a furnace operation taking into account that 238PuO2 itself has a significant thermal output. Results of the modeling efforts will be discussed.

  6. Modeling of selected ceramic processing parameters employed in the fabrication of 238PuO2 fuel pellets

    DOE PAGESBeta

    Brockman, R. A.; Kramer, D. P.; Barklay, C. D.; Cairns-Gallimore, D.; Brown, J. L.; Huling, J. C.; Van Pelt, C. E.

    2011-10-01

    Recent deep space missions utilize the thermal output of the radioisotope plutonium-238 as the fuel in the thermal to electrical power system. Since the application of plutonium in its elemental state has several disadvantages, the fuel employed in these deep space power systems is typically in the oxide form such as plutonium-238 dioxide (238PuO2). As an oxide, the processing of the plutonium dioxide into fuel pellets is performed via ''classical'' ceramic processing unit operations such as sieving of the powder, pressing, sintering, etc. Modeling of these unit operations can be beneficial in the understanding and control of processing parameters withmore » the goal of further enhancing the desired characteristics of the 238PuO2 fuel pellets. A finite element model has been used to help identify the time-temperature-stress profile within a pellet during a furnace operation taking into account that 238PuO2 itself has a significant thermal output. The results of the modeling efforts will be discussed.« less

  7. Evaluation of codisposal viability of MOX (FFTF) DOE-owned fuel: Phase 1 -- Intact mode calculations

    SciTech Connect

    Goluoglu, S.; Davis, J.W.; Montierth, L.M.

    1999-07-01

    The authors provide the intact criticality information that supports the disposal of spent nuclear fuel (SNF) from the US Department of Energy's (DOE's) Fast Flux Test Facility (FFTF) in the potential Monitored Geologic Repository at Yucca Mountain. FFTF is one of more than 250 forms of DOE-owned SNF. Because of the variety of the DOE SNF, the National Spent Nuclear Fuel Program has designated nine representative fuel groups for disposal criticality analyses based on fuel matrix, primary fissile isotope, and enrichment. The FFTF fuel is representative of the mixed-oxide fuel (MOX) group.

  8. The origin of organic pollutants from the combustion of alternative fuels: Phase 5/6 report

    SciTech Connect

    Sidhu, S.; Graham, J.; Taylor, P.; Dellinger, B.

    1998-05-01

    As part of the US Department of Energy National Renewable Energy Laboratory program on alternative automotive fuels, the subcontractor has been conducting studies on the origin and fate of organic pollutants from the combustion of alternative fuels. Laboratory experiments were conducted simulating cold start of four alterative fuels (compressed natural gas, liquefied petroleum gas, methanol-gasoline mix, and ethanol-gasoline mix) using a commercial three-way catalyst under fuel-lean conditions. This report summarizes the results of these experiments. It appears that temperature of the catalyst is a more important parameter for fuel conversion and pollutant formation than oxygen concentration or fuel composition.

  9. Explicit Finite Element Modeling of Multilayer Composite Fabric for Gas Turbine Engine Containment Systems, Phase II. Part 3; Material Model Development and Simulation of Experiments

    NASA Technical Reports Server (NTRS)

    Simmons, J.; Erlich, D.; Shockey, D.

    2009-01-01

    A team consisting of Arizona State University, Honeywell Engines, Systems & Services, the National Aeronautics and Space Administration Glenn Research Center, and SRI International collaborated to develop computational models and verification testing for designing and evaluating turbine engine fan blade fabric containment structures. This research was conducted under the Federal Aviation Administration Airworthiness Assurance Center of Excellence and was sponsored by the Aircraft Catastrophic Failure Prevention Program. The research was directed toward improving the modeling of a turbine engine fabric containment structure for an engine blade-out containment demonstration test required for certification of aircraft engines. The research conducted in Phase II began a new level of capability to design and develop fan blade containment systems for turbine engines. Significant progress was made in three areas: (1) further development of the ballistic fabric model to increase confidence and robustness in the material models for the Kevlar(TradeName) and Zylon(TradeName) material models developed in Phase I, (2) the capability was improved for finite element modeling of multiple layers of fabric using multiple layers of shell elements, and (3) large-scale simulations were performed. This report concentrates on the material model development and simulations of the impact tests.

  10. Separation of Corn Fiber and Conversion to Fuels and Chemicals Phase II: Pilot-scale Operation

    SciTech Connect

    Abbas, Charles; Beery, Kyle; Orth, Rick; Zacher, Alan

    2007-09-28

    The purpose of the Department of Energy (DOE)-supported corn fiber conversion project, “Separation of Corn Fiber and Conversion to Fuels and Chemicals Phase II: Pilot-scale Operation” is to develop and demonstrate an integrated, economical process for the separation of corn fiber into its principal components to produce higher value-added fuel (ethanol and biodiesel), nutraceuticals (phytosterols), chemicals (polyols), and animal feed (corn fiber molasses). This project has successfully demonstrated the corn fiber conversion process on the pilot scale, and ensured that the process will integrate well into existing ADM corn wet-mills. This process involves hydrolyzing the corn fiber to solubilize 50% of the corn fiber as oligosaccharides and soluble protein. The solubilized fiber is removed and the remaining fiber residue is solvent extracted to remove the corn fiber oil, which contains valuable phytosterols. The extracted oil is refined to separate the phytosterols and the remaining oil is converted to biodiesel. The de-oiled fiber is enzymatically hydrolyzed and remixed with the soluble oligosaccharides in a fermentation vessel where it is fermented by a recombinant yeast, which is capable of fermenting the glucose and xylose to produce ethanol. The fermentation broth is distilled to remove the ethanol. The stillage is centrifuged to separate the yeast cell mass from the soluble components. The yeast cell mass is sold as a high-protein yeast cream and the remaining sugars in the stillage can be purified to produce a feedstock for catalytic conversion of the sugars to polyols (mainly ethylene glycol and propylene glycol) if desirable. The remaining materials from the purification step and any materials remaining after catalytic conversion are concentrated and sold as a corn fiber molasses. Additional high-value products are being investigated for the use of the corn fiber as a dietary fiber sources.

  11. Low NO sub x heavy fuel combustor concept program. Phase 1A: Combustion technology generation coal gas fuels

    NASA Technical Reports Server (NTRS)

    Sherlock, T. P.

    1982-01-01

    Combustion tests of two scaled burners using actual coal gas from a 25 ton/day fluidized bed coal gasifier are described. The two combustor configurations studied were a ceramic lined, staged rich/lean burner and an integral, all metal multiannual swirl burner (MASB). The tests were conducted over a range of temperature and pressures representative of current industrial combustion turbine inlet conditions. Tests on the rich lean burner were conducted at three levels of product gas heating values: 104, 197 and 254 btu/scf. Corresponding levels of NOx emissions were 5, 20 and 70 ppmv. Nitrogen was added to the fuel in the form of ammonia, and conversion efficiencies of fuel nitrogen to NOx were on the order of 4 percent to 12 percent, which is somewhat lower than the 14 percent to 18 percent conversion efficiency when src-2 liquid fuel was used. The MASB was tested only on medium btu gas (220 to 270 btu/scf), and produced approximately 80 ppmv NOx at rated engine conditions. Both burners operated similarly on actual coal gas and erbs fuel, and all heating values tested can be successfully burned in current machines.

  12. Fabricating superhydrophilic wool fabrics.

    PubMed

    Chen, Dong; Tan, Longfei; Liu, Huiyu; Hu, Junyan; Li, Yi; Tang, Fangqiong

    2010-04-01

    A simple method for fabricating environmentally stable superhydrophilic wool fabrics is reported here. An ultrathin silica layer coated on the wool altered both the surface roughness and the surface energy of the fiber and endowed the wool fabrics with excellent water absorption. The process of coating silica sols was dependent on an acid solution of low pH, which influenced the electrostatic interactions between nanoparticles and wool fibers. The morphology and composition of silica-sol-coated wool fabrics were characterized by a combination of SEM, TEM, EDX, FTIR, and XPS measurements. The possible mechanism and size effect of silica nanoparticles on the hydrophilic property of wool fabric were discussed. The washing fastness of the superhydrophilic wool fabrics in perchlorethylene and water was also evaluated. This study shows that wool fabrics modified by optical transparence, chemical stability, and nontoxic silica sols are promising in constructing smart textiles. PMID:19908843

  13. Report of an investigation into deterioration of the Plutonium Fuel Form Fabrication Facility (PuFF) at the DOE Savannah River Site

    SciTech Connect

    Not Available

    1991-10-01

    This investigations of the Savannah River Site's Plutonium Fuel Form fabrication facility located in Building 235-F was initiated in April 1991. The purpose of the investigation was to determine whether, as has been alleged, operation of the facility's argon inert gas system was terminated with the knowledge that continued inoperability of the argon system would cause accelerated corrosion damage to the equipment in the plutonium 238 processing cells. The investigation quickly established that the decision to discontinue operation of the argon system, by not repairing it, was merely one of the measures, and not the most important one, which led to the current deteriorated state of the facility. As a result, the scope of the investigation was broadened to more identify and assess those factors which contributed to the facility's current condition. This document discusses the backgrounds, results, and recommendations of this investigation.

  14. Fabrication of lanthanum strontium cobalt ferrite (LSCF) cathodes for high performance solid oxide fuel cells using a low price commercial inkjet printer

    NASA Astrophysics Data System (ADS)

    Han, Gwon Deok; Neoh, Ke Chean; Bae, Kiho; Choi, Hyung Jong; Park, Suk Won; Son, Ji-Won; Shim, Joon Hyung

    2016-02-01

    In this study, we investigate a method to fabricate high quality lanthanum strontium cobalt ferrite (LSCF) cathodes for solid oxide fuel cells (SOFCs) using a commercial low price inkjet printer. The ink source is synthesized by dissolving the LSCF nanopowder in a water-based solvent with a proper amount of surfactants. Microstructures of the LSCF layer, including porosity and thickness per printing scan cycle, are adjusted by grayscale in the printing image. It is successfully demonstrated that anode-supported SOFCs with optimally printed LSCF cathodes can produce decent power output, i.e., a maximum peak power density of 377 mW cm-2 at 600 °C, in our experiment. We expect that this approach can support the quick and easy prototyping and evaluating of a variety of cathode materials in SOFC research.

  15. Measuring the noble metal and iodine composition of extracted noble metal phase from spent nuclear fuel using instrumental neutron activation analysis.

    PubMed

    Palomares, R I; Dayman, K J; Landsberger, S; Biegalski, S R; Soderquist, C Z; Casella, A J; Brady Raap, M C; Schwantes, J M

    2015-04-01

    Masses of noble metal and iodine nuclides in the metallic noble metal phase extracted from spent fuel are measured using instrumental neutron activation analysis. Nuclide presence is predicted using fission yield analysis, and radionuclides are identified and the masses quantified using neutron activation analysis. The nuclide compositions of noble metal phase derived from two dissolution methods, UO2 fuel dissolved in nitric acid and UO2 fuel dissolved in ammonium-carbonate and hydrogen-peroxide solution, are compared. PMID:25644079

  16. Design, simulation, fabrication, packaging, and characterization of a MEMS-based mirror array for femtosecond pulse-shaping in phase and amplitude.

    PubMed

    Weber, Stefan M; Bonacina, Luigi; Noell, Wilfried; Kiselev, Denis; Extermann, Jérôme; Jutzi, Fabio; Lani, Sébastien; Nenadl, Ondrej; Wolf, Jean-Pierre; de Rooij, Nico F

    2011-07-01

    We present an in-detail description of the design, simulation, fabrication, and packaging of a linear micromirror array specifically designed for temporal pulse shaping of ultrashort laser pulses. The innovative features of this device include a novel comb-drive actuator allowing both piston and tilt motion for phase- and amplitude-shaping, and an X-shaped laterally reinforced spring preventing lateral snap-in while providing high flexibility for both degrees of freedom. PMID:21806226

  17. Design, simulation, fabrication, packaging, and characterization of a MEMS-based mirror array for femtosecond pulse-shaping in phase and amplitude

    NASA Astrophysics Data System (ADS)

    Weber, Stefan M.; Bonacina, Luigi; Noell, Wilfried; Kiselev, Denis; Extermann, Jérôme; Jutzi, Fabio; Lani, Sébastien; Nenadl, Ondrej; Wolf, Jean-Pierre; de Rooij, Nico F.

    2011-07-01

    We present an in-detail description of the design, simulation, fabrication, and packaging of a linear micromirror array specifically designed for temporal pulse shaping of ultrashort laser pulses. The innovative features of this device include a novel comb-drive actuator allowing both piston and tilt motion for phase- and amplitude-shaping, and an X-shaped laterally reinforced spring preventing lateral snap-in while providing high flexibility for both degrees of freedom.

  18. Semi-Solid Metal Freeform Fabrication - Phase I Final Report for Period September 4, 1999--June 14, 2000

    SciTech Connect

    Chris S. Rice

    2000-07-25

    Semi-Solid Technologies, Inc. developed a semi-solid deposition system for semi-solid aluminum alloys. This technology addresses the direct, rapid, freeform fabrication of relatively large metallic components.

  19. RERTR Fuel Developmemt and Qualification Plan

    SciTech Connect

    Dan Wachs

    2007-01-01

    In late 2003 it became evident that U-Mo aluminum fuels under development exhibited significant fuel performance problems under the irradiation conditions required for conversion of most high-powered research reactors. Solutions to the fuel performance issue have been proposed and show promise in early testing. Based on these results, a Reduced Enrichment Research and Test Reactor (RERTR) program strategy has been mapped to allow generic fuel qualification to occur prior to the end of FY10 and reactor conversion to occur prior to the end of FY14. This strategy utilizes a diversity of technologies, test conditions, and test types. Scoping studies using miniature fuel plates will be completed in the time frame of 2006-2008. Irradiation of larger specimens will occur in the Advanced Test Reactor (ATR) in the United States, the Belgian Reactor-2 (BR2) reactor in Belgium, and in the OSIRIS reactor in France in 2006-2009. These scoping irradiation tests provide a large amount of data on the performance of advanced fuel types under irradiation and allow the down selection of technology for larger scale testing during the final stages of fuel qualification. In conjunction with irradiation testing, fabrication processes must be developed and made available to commercial fabricators. The commercial fabrication infrastructure must also be upgraded to ensure a reliable low enriched uranium (LEU) fuel supply. Final qualification of fuels will occur in two phases. Phase I will obtain generic approval for use of dispersion fuels with density less than 8.5 g-U/cm3. In order to obtain this approval, a larger scale demonstration of fuel performance and fabrication technology will be necessary. Several Materials Test Reactor (MTR) plate-type fuel assemblies will be irradiated in both the High Flux Reactor (HFR) and the ATR (other options include the BR2 and Russian Research Reactor, Dmitrovgrad, Russia [MIR] reactors) in 2008-2009. Following postirradiation examination, a report

  20. Fabrication of Alternating-Phase Fed Single-Layer Slotted Waveguide Arrays Using Plastic Materials with Metal-Plating

    NASA Astrophysics Data System (ADS)

    Zhang, Miao; Hirokawa, Jiro; Ando, Makoto

    Lightweight single-layer slotted waveguide array antennas are fabricated using plastic materials with metal-plating. A plastic material that has good heat-radiation properties is investigated. Three types of antennas are fabricated by milling, using ABS resin, heat-radiating plastic, and aluminum alloy. In measurements, all three types of antennas are confirmed to have almost the same VSWR and gain in the 25GHz frequency band.