Science.gov

Sample records for fuel temperature peaking

  1. Determination of the bias in LOFT fuel peak cladding temperature data from the blowdown phase of large-break LOCA experiments

    SciTech Connect

    Berta, V.T.; Hanson, R.G.; Johnsen, G.W.; Schultz, R.R.

    1993-05-01

    Data from the Loss-of-Fluid Test (LOFT) Program help quantify the margin of safety inherent in pressurized water reactors during postulated loss-of-coolant accidents (LOCAs). As early as 1979, questions arose concerning the accuracy of LOFT fuel rod cladding temperature data during several large-break LOCA experiments. This report analyzes how well externally-mounted fuel rod cladding thermocouples in LOFT accurately reflected actual cladding surface temperature during large-break LOCA experiments. In particular, the validity of the apparent core-wide fuel rod cladding quench exhibited during blowdown in LOFT Experiments L2-2 and L2-3 is studied. Also addressed is the question of whether the externally-mounted thermocouples might have influenced cladding temperature. The analysis makes use of data and information from several sources, including later, similar LOFT Experiments in which fuel centerline temperature measurements were made, experiments in other facilities, and results from a detailed FRAP-T6 model of the LOFT fuel rod. The analysis shows that there can be a significant difference (referred to as bias) between the surface-mounted thermocouple reading and the actual cladding temperature, and that the magnitude of this bias depends on the rate of heat transfer between the fuel rod cladding and coolant. The results of the analysis demonstrate clearly that a core-wide cladding quench did occur in Experiments L2-2 and L2-3. Further, it is shown that, in terms of peak cladding temperature recording during LOFT large-break LOCA experiments, the mean bias is 11.4 {plus_minus} 16.2K (20.5 {plus_minus} 29.2{degrees} F). The best-estimate value of peak cladding temperature for LOFT LP-02-6 is 1,104.8 K. The best-estimate peak cladding temperature for LOFT LP-LB-1 is 1284.0 K.

  2. FEMAXI-V benchmarking study on peak temperature and fission gas release prediction of PWR rod fuel

    SciTech Connect

    Suwardi; Dewayatna, W.; Briyatmoko, B.

    2012-06-06

    The present paper reports a study of FEMAXI-V code and related report on code benchmarking. Capabilities of the FEMAXI-V code to predict the thermal and fission gas release have been tested on MOX fuels in LWRs which has been done in SCK{center_dot}CEN and Belgonucleaire by using PRIMO MOX rod BD8 irradiation experiment after V Sobolev as reported O. J. Ott. Base irradiation in the BR3 reactor, the BD8 rod was transported to CEA-Saclay for irradiation in the OSIRIS reactor (ramp power excursion). The irradiation device used for the PRIMO ramps was the ISABELLE 1 loop, installed on a movable structure of the core periphery. The power variations were obtained by inwards/backwards movements of the loop in the core water. The preconditioning phase for rod BD8 occurred at a peak power level of 189 W/cm with a hold time of 27 hours. The subsequent power excursion rate amounted to 77 W/ (cm.min), reaching a terminal peak power level of 395 W/cm that lasted for 20 hours.

  3. Measurements of fuel pin/water hole worths and power peaking, void coefficients, and temperature coefficients for 4. 81 wt% enriched UO[sub 2] fuel rods

    SciTech Connect

    Harris, D.R.; Rohr, R.R.; Angelo, P.L.; Patrou, N.T.; Buckwheat, K.W.; Hayes, D.K.

    1990-01-01

    The Rensselaer Polytechnic Institute reactor critical facility is currently the only facility in North America providing critical measurement data in support of the light water reactor electric power industry. The reactor is fueled by 4.81 wt% [sup 235]U enriched UO[sub 2] high-density pellets in stainless steel clad fuel rods at the present time, although experiments with other fuels are being analyzed. The fuel pins are supported by inexpensive stainless steel lattice plates in a large open water tank. Three sets of lattice plates have been fabricated for fuel pins in square array with pitches 0.585, 0.613, and 0.640 in. (1.486, 0.613, and 1.656 cm, respectively) to provide a relevant range of water-to-fuel volume ratios. The measurements reported here are for the first of these, a relatively tight lattice of considerable interest for reactor physics methods for advanced fuels and reactors.

  4. On the off-stoichiometric peaking of adiabatic flame temperature

    SciTech Connect

    Law, C.K.; Lu, T.F.; Makino, A.

    2006-06-15

    The characteristic rich shifting of the maximum adiabatic flame temperature from the stoichiometric value for mixtures of hydrocarbon and air is demonstrated to be caused by product dissociation and hence reduced amount of heat release. Since the extent of dissociation is greater on the lean side as a result of the stoichiometry of dissociated products, the peaking occurs on the rich side. The specific heat per unit mass of the mixture is shown to increase monotonically with increasing fuel concentration, and as such tends to shift the peak toward the lean side. It is further shown that this is the cause for the lean shifting of the adiabatic flame temperature of oxidizer-enriched mixtures of N{sub m}H{sub n} and F{sub 2} and of NH{sub 3} and O{sub 2}, with various amounts of inert dilution, even though their maximum heat release still peaks on the rich side. (author)

  5. Linearity between temperature peak and bioenergy CO2 emission rates

    NASA Astrophysics Data System (ADS)

    Cherubini, Francesco; Gasser, Thomas; Bright, Ryan M.; Ciais, Philippe; Strømman, Anders H.

    2014-11-01

    Many future energy and emission scenarios envisage an increase of bioenergy in the global primary energy mix. In most climate impact assessment models and policies, bioenergy systems are assumed to be carbon neutral, thus ignoring the time lag between CO2 emissions from biomass combustion and CO2 uptake by vegetation. Here, we show that the temperature peak caused by CO2 emissions from bioenergy is proportional to the maximum rate at which emissions occur and is almost insensitive to cumulative emissions. Whereas the carbon-climate response (CCR; ref. ) to fossil fuel emissions is approximately constant, the CCR to bioenergy emissions depends on time, biomass turnover times, and emission scenarios. The linearity between temperature peak and bioenergy CO2 emission rates resembles the characteristic of the temperature response to short-lived climate forcers. As for the latter, the timing of CO2 emissions from bioenergy matters. Under the international agreement to limit global warming to 2 °C by 2100, early emissions from bioenergy thus have smaller contributions on the targeted temperature than emissions postponed later into the future, especially when bioenergy is sourced from biomass with medium (50-60 years) or long turnover times (100 years).

  6. Back-Up/ Peak Shaving Fuel Cell System

    SciTech Connect

    Staudt, Rhonda L.

    2008-05-28

    This Final Report covers the work executed by Plug Power from 8/11/03 – 10/31/07 statement of work for Topic 2: advancing the state of the art of fuel cell technology with the development of a new generation of commercially viable, stationary, Back-up/Peak-Shaving fuel cell systems, the GenCore II. The Program cost was $7.2 M with the Department of Energy share being $3.6M and Plug Power’s share being $3.6 M. The Program started in August of 2003 and was scheduled to end in January of 2006. The actual program end date was October of 2007. A no cost extension was grated. The Department of Energy barriers addressed as part of this program are: Technical Barriers for Distributed Generation Systems: o Durability o Power Electronics o Start up time Technical Barriers for Fuel Cell Components: o Stack Material and Manufacturing Cost o Durability o Thermal and water management Background The next generation GenCore backup fuel cell system to be designed, developed and tested by Plug Power under the program is the first, mass-manufacturable design implementation of Plug Power’s GenCore architected platform targeted for battery and small generator replacement applications in the telecommunications, broadband and UPS markets. The next generation GenCore will be a standalone, H2 in-DC-out system. In designing the next generation GenCore specifically for the telecommunications market, Plug Power is teaming with BellSouth Telecommunications, Inc., a leading industry end user. The final next generation GenCore system is expected to represent a market-entry, mass-manufacturable and economically viable design. The technology will incorporate: • A cost-reduced, polymer electrolyte membrane (PEM) fuel cell stack tailored to hydrogen fuel use • An advanced electrical energy storage system • A modular, scalable power conditioning system tailored to market requirements • A scaled-down, cost-reduced balance of plant (BOP) • Network Equipment Building Standards (NEBS), UL

  7. Cryogenic precision digital temperature control with peaked frequency response

    NASA Astrophysics Data System (ADS)

    Li, Jie; Lockhart, James M.; Boretsky, Peter

    2004-05-01

    A high precision temperature control system capable of maintaining the temperature of superconducting quantum interference devices (SQUIDs) constant to within 1.0 μK root-mean square over a narrow frequency band was designed and built for use with the superconducting readout system of the Gravity Probe B experiment. The system utilizes an analog ac temperature bridge with a digital proportional-integral control loop which incorporates a peaking filter. A disturbance attenuation factor of 86 or greater over the required frequency band was demonstrated in system tests with the cryogenic hardware, allowing the SQUID system to achieve the required stability. The control system was robust against variations in the thermal characteristics of the cryogenic hardware.

  8. Fuel Temperature Coefficient of Reactivity

    SciTech Connect

    Loewe, W.E.

    2001-07-31

    A method for measuring the fuel temperature coefficient of reactivity in a heterogeneous nuclear reactor is presented. The method, which is used during normal operation, requires that calibrated control rods be oscillated in a special way at a high reactor power level. The value of the fuel temperature coefficient of reactivity is found from the measured flux responses to these oscillations. Application of the method in a Savannah River reactor charged with natural uranium is discussed.

  9. Inflight fuel tank temperature survey data

    NASA Technical Reports Server (NTRS)

    Pasion, A. J.

    1979-01-01

    Statistical summaries of the fuel and air temperature data for twelve different routes and for different aircraft models (B747, B707, DC-10 and DC-8), are given. The minimum fuel, total air and static air temperature expected for a 0.3% probability were summarized in table form. Minimum fuel temperature extremes agreed with calculated predictions and the minimum fuel temperature did not necessarily equal the minimum total air temperature even for extreme weather, long range flights.

  10. A wedged-peak-pulse design with medium fuel adiabat for indirect-drive fusion

    SciTech Connect

    Fan, Zhengfeng; Ren, Guoli; Liu, Bin; Wu, Junfeng; He, X. T.; Liu, Jie; Wang, L. F.; Ye, Wenhua

    2014-10-15

    In the present letter, we propose the design of a wedged-peak pulse at the late stage of indirect drive. Our simulations of one- and two-dimensional radiation hydrodynamics show that the wedged-peak-pulse design can raise the drive pressure and capsule implosion velocity without significantly raising the fuel adiabat. It can thus balance the energy requirement and hydrodynamic instability control at both ablator/fuel interface and hot-spot/fuel interface. This investigation has implication in the fusion ignition at current mega-joule laser facilities.

  11. Peak fire temperatures and effects on annual plants in the Mojave Desert

    USGS Publications Warehouse

    Brooks, M.L.

    2002-01-01

    Very little is known about the behavior and effects of fire in the Mojave Desert, because fire was historically uncommon. However, fire has become more frequent since the 1970s with increased dominance of the invasive annual grasses Bromus rubens and Schismus spp., and land managers are concerned about its ecological effect. In this paper, I describe patterns of peak fire temperature and their effect on annual plants in creosote bush scrub vegetation of the Mojave Desert. Temperatures were monitored among microhabitats and distances from the soil surface, and between spring and summer. Microhabitats ranged from high amounts of fuel beneath creosote bush (Larrea tridentata) canopies, to intermediate amounts at the canopy drip line, to low amounts in the interspaces between them. Distances from the soil surface were within the vertical range where most annual plant seeds occur (-2, 0, 5, and 10 cm). I also compare temperature patterns with postfire changes in soil properties and annual plant biomass and species richness to infer potential mechanisms by which fires affect annual plants. Peak fire temperatures were most affected by the microhabitat fuel gradient, and the effects of fire on annual plants varied among microhabitats. Beneath creosote bushes, lethal fire temperatures for annual plant seeds occurred above- and belowground, resulting in four postfire years of reduced annual plant biomass and species richness due most likely to seed mortality, especially of Bromus rubens and native forbs. At the canopy drip line, lethal fire temperatures occurred only aboveground, reducing annual plant biomass for 1 yr and species richness for 2 yr, and increasing biomass of Schismus sp., the alien forb Erodium cicutarium, and native annuals after 3 yr. Negligible changes were caused by fire in interspaces or between spring and summer. Fire effects models for creosote bush scrub vegetation must account for patterns of peak fire temperature along the shrub-intershrub gradient

  12. Peak-Seeking Optimization of Trim for Reduced Fuel Consumption: Architecture and Performance Predictions

    NASA Technical Reports Server (NTRS)

    Schaefer, Jacob; Brown, Nelson A.

    2013-01-01

    A peak-seeking control approach for real-time trim configuration optimization for reduced fuel consumption has been developed by researchers at the National Aeronautics and Space Administration (NASA) Dryden Flight Research Center to address the goals of the NASA Environmentally Responsible Aviation project to reduce fuel burn and emissions. The peak-seeking control approach is based on a steepest-descent algorithm using a time-varying Kalman filter to estimate the gradient of a performance function of fuel flow versus control surface positions. In real-time operation, deflections of symmetric ailerons, trailing-edge flaps, and leading-edge flaps of an F/A-18 airplane (McDonnell Douglas, now The Boeing Company, Chicago, Illinois) are controlled for optimization of fuel flow. This paper presents the design and integration of this peak-seeking controller on a modified NASA F/A-18 airplane with research flight control computers. A research flight was performed to collect data to build a realistic model of the performance function and characterize measurement noise. This model was then implemented into a nonlinear six-degree-of-freedom F/A-18 simulation along with the peak-seeking control algorithm. With the goal of eventual flight tests, the algorithm was first evaluated in the improved simulation environment. Results from the simulation predict good convergence on minimum fuel flow with a 2.5-percent reduction in fuel flow relative to the baseline trim of the aircraft.

  13. Peak-Seeking Optimization of Trim for Reduced Fuel Consumption: Architecture and Performance Predictions

    NASA Technical Reports Server (NTRS)

    Schaefer, Jacob; Brown, Nelson

    2013-01-01

    A peak-seeking control approach for real-time trim configuration optimization for reduced fuel consumption has been developed by researchers at the National Aeronautics and Space Administration (NASA) Dryden Flight Research Center to address the goals of the NASA Environmentally Responsible Aviation project to reduce fuel burn and emissions. The peak-seeking control approach is based on a steepest-descent algorithm using a time-varying Kalman filter to estimate the gradient of a performance function of fuel flow versus control surface positions. In real-time operation, deflections of symmetric ailerons, trailing-edge flaps, and leading-edge flaps of an FA-18 airplane (McDonnell Douglas, now The Boeing Company, Chicago, Illinois) are controlled for optimization of fuel flow. This presentation presents the design and integration of this peak-seeking controller on a modified NASA FA-18 airplane with research flight control computers. A research flight was performed to collect data to build a realistic model of the performance function and characterize measurement noise. This model was then implemented into a nonlinear six-degree-of-freedom FA-18 simulation along with the peak-seeking control algorithm. With the goal of eventual flight tests, the algorithm was first evaluated in the improved simulation environment. Results from the simulation predict good convergence on minimum fuel flow with a 2.5-percent reduction in fuel flow relative to the baseline trim of the aircraft.

  14. Sensitivity and System Response of Pin Power Peaking in VVER-1000 Fuel Assembly Using TSUNAMI-2D

    NASA Astrophysics Data System (ADS)

    Frybort, J.

    2014-04-01

    Pin power peaking in a VVER-1000 fuel assembly and its sensitivity and uncertainty was analyzed by TSUNAMI-2D code. Several types of fuel assemblies were considered. They differ in number and position of gadolinium fuel pins. The calculations were repeated for several fuel compositions obtained by fuel depletion calculation. The results are quantified sensitivity data, which can be used for enrichment profiling.

  15. EXTENDING SODIUM FAST REACTOR DRIVER FUEL USE TO HIGHER TEMPERATURES

    SciTech Connect

    Douglas L. Porter

    2011-02-01

    Calculations of potential sodium-cooled fast reactor fuel temperatures were performed to estimate the effects of increasing the outlet temperature of a given fast reactor design by increasing pin power, decreasing assembly flow, or increasing inlet temperature. Based upon experience in the U.S., both metal and mixed oxide (MOX) fuel types are discussed in terms of potential performance effects created by the increased operating temperatures. Assembly outlet temperatures of 600, 650 and 700 °C were used as goal temperatures. Fuel/cladding chemical interaction (FCCI) and fuel melting, as well as challenges to the mechanical integrity of the cladding material, were identified as the limiting phenomena. For example, starting with a recent 1000 MWth fast reactor design, raising the outlet temperature to 650 °C through pin power increase increased the MOX centerline temperature to more than 3300 °C and the metal fuel peak cladding temperature to more than 700 °C. These exceeded limitations to fuel performance; fuel melting was limiting for MOX and FCCI for metal fuel. Both could be alleviated by design ‘fixes’, such as using a barrier inside the cladding to minimize FCCI in the metal fuel, or using annular fuel in the case of MOX. Both would also require an advanced cladding material with improved stress rupture properties. While some of these are costly, the benefits of having a high-temperature reactor which can support hydrogen production, or other missions requiring high process heat may make the extra costs justified.

  16. Nuclear fuels for very high temperature applications

    SciTech Connect

    Lundberg, L.B.; Hobbins, R.R.

    1992-08-01

    The success of the development of nuclear thermal propulsion devices and thermionic space nuclear power generation systems depends on the successful utilization of nuclear fuel materials at temperatures in the range 2000 to 3500 K. Problems associated with the utilization of uranium bearing fuel materials at these very high temperatures while maintaining them in the solid state for the required operating times are addressed. The critical issues addressed include evaporation, melting, reactor neutron spectrum, high temperature chemical stability, fabrication, fission induced swelling, fission product release, high temperature creep, thermal shock resistance, and fuel density, both mass and fissile atom. Candidate fuel materials for this temperature range are based on UO{sub 2} or uranium carbides. Evaporation suppression, such as a sealed cladding, is required for either fuel base. Nuclear performance data needed for design are sparse for all candidate fuel forms in this temperature range, especially at the higher temperatures.

  17. Nuclear fuels for very high temperature applications

    SciTech Connect

    Lundberg, L.B.; Hobbins, R.R.

    1992-01-01

    The success of the development of nuclear thermal propulsion devices and thermionic space nuclear power generation systems depends on the successful utilization of nuclear fuel materials at temperatures in the range 2000 to 3500 K. Problems associated with the utilization of uranium bearing fuel materials at these very high temperatures while maintaining them in the solid state for the required operating times are addressed. The critical issues addressed include evaporation, melting, reactor neutron spectrum, high temperature chemical stability, fabrication, fission induced swelling, fission product release, high temperature creep, thermal shock resistance, and fuel density, both mass and fissile atom. Candidate fuel materials for this temperature range are based on UO{sub 2} or uranium carbides. Evaporation suppression, such as a sealed cladding, is required for either fuel base. Nuclear performance data needed for design are sparse for all candidate fuel forms in this temperature range, especially at the higher temperatures.

  18. Peak-Seeking Optimization of Trim for Reduced Fuel Consumption: Flight-test Results

    NASA Technical Reports Server (NTRS)

    Brown, Nelson Andrew; Schaefer, Jacob Robert

    2013-01-01

    A peak-seeking control algorithm for real-time trim optimization for reduced fuel consumption has been developed by researchers at the National Aeronautics and Space Administration (NASA) Dryden Flight Research Center to address the goals of the NASA Environmentally Responsible Aviation project to reduce fuel burn and emissions. The peak-seeking control algorithm is based on a steepest-descent algorithm using a time-varying Kalman filter to estimate the gradient of a performance function of fuel flow versus control surface positions. In real-time operation, deflections of symmetric ailerons, trailing-edge flaps, and leading-edge flaps of an F/A-18 airplane (McDonnell Douglas, now The Boeing Company, Chicago, Illinois) are used for optimization of fuel flow. Results from six research flights are presented herein. The optimization algorithm found a trim configuration that required approximately 3 percent less fuel flow than the baseline trim at the same flight condition. The algorithm consistently rediscovered the solution from several initial conditions. These results show that the algorithm has good performance in a relevant environment.

  19. Peak-Seeking Optimization of Trim for Reduced Fuel Consumption: Flight-Test Results

    NASA Technical Reports Server (NTRS)

    Brown, Nelson Andrew; Schaefer, Jacob Robert

    2013-01-01

    A peak-seeking control algorithm for real-time trim optimization for reduced fuel consumption has been developed by researchers at the National Aeronautics and Space Administration (NASA) Dryden Flight Research Center to address the goals of the NASA Environmentally Responsible Aviation project to reduce fuel burn and emissions. The peak-seeking control algorithm is based on a steepest-descent algorithm using a time-varying Kalman filter to estimate the gradient of a performance function of fuel flow versus control surface positions. In real-time operation, deflections of symmetric ailerons, trailing-edge flaps, and leading-edge flaps of an F/A-18 airplane (McDonnell Douglas, now The Boeing Company, Chicago, Illinois) are used for optimization of fuel flow. Results from six research flights are presented herein. The optimization algorithm found a trim configuration that required approximately 3 percent less fuel flow than the baseline trim at the same flight condition. The algorithm consistently rediscovered the solution from several initial conditions. These results show that the algorithm has good performance in a relevant environment.

  20. Effective thermal conductivity method for predicting spent nuclear fuel cladding temperatures in a dry fill gas

    SciTech Connect

    Bahney, Robert

    1997-12-19

    This paper summarizes the development of a reliable methodology for the prediction of peak spent nuclear fuel cladding temperature within the waste disposal package. The effective thermal conductivity method replaces other older methodologies.

  1. The Fuel Accident Condition Simulator (FACS) furnace system for high temperature performance testing of VHTR fuel

    SciTech Connect

    Paul A. Demkowicz; David V. Laug; Dawn M. Scates; Edward L. Reber; Lyle G. Roybal; John B. Walter; Jason M. Harp; Robert N. Morris

    2012-10-01

    The AGR-1 irradiation of TRISO-coated particle fuel specimens was recently completed and represents the most successful such irradiation in US history, reaching peak burnups of greater than 19% FIMA with zero failures out of 300,000 particles. An extensive post-irradiation examination (PIE) campaign will be conducted on the AGR-1 fuel in order to characterize the irradiated fuel properties, assess the in-pile fuel performance in terms of coating integrity and fission metals release, and determine the fission product retention behavior during high temperature safety testing. A new furnace system has been designed, built, and tested to perform high temperature accident tests. The Fuel Accident Condition Simulator furnace system is designed to heat fuel specimens at temperatures up to 2000 degrees C in helium while monitoring the release of volatile fission metals (e.g. Cs, Ag, Sr, and Eu), iodine, and fission gases (Kr, Xe). Fission gases released from the fuel to the sweep gas are monitored in real time using dual cryogenic traps fitted with high purity germanium detectors. Condensable fission products are collected on a plate attached to a water-cooled cold finger that can be exchanged periodically without interrupting the test. Analysis of fission products on the condensation plates involves dry gamma counting followed by chemical analysis of selected isotopes. This paper will describe design and operational details of the Fuel Accident Condition Simulator furnace system and the associated fission gas monitoring system, as well as preliminary system calibration results.

  2. A universal scaling behavior in magnetic resonance peak in high temperature superconductivity

    NASA Astrophysics Data System (ADS)

    Shin, Seung Joon; Salk, Sung-Ho Suck

    2015-08-01

    Eminent inelastic neutron scattering (INS) measurements of high temperature cuprates currently lacking theoretical interpretations are the observed temperature dependence of magnetic resonance peak and linear scaling relation between the resonance peak energy, Eres and the superconducting transition temperature, Tc. Using our slave-boson approach of the t-J Hamiltonian (Phys. Rev. 64, 052501 (2001)) for this study, we show that starting from the pseudogap temperature T∗, the magnetic resonance peak increases with decreasing temperature, revealing its inflection point at Tc and that spin pairing correlations are responsible for d-wave superconductivity. We find that there exists a universal linear scaling behavior of Eres/Tc = const., irrespective of the Heisenberg exchange coupling.

  3. The shape of CMB temperature and polarization peaks on the sphere

    NASA Astrophysics Data System (ADS)

    Marcos-Caballero, A.; Fernández-Cobos, R.; Martínez-González, E.; Vielva, P.

    2016-04-01

    We present a theoretical study of CMB temperature peaks, including its effect over the polarization field, and allowing nonzero eccentricity. The formalism is developed in harmonic space and using the covariant derivative on the sphere, which guarantees that the expressions obtained are completely valid at large scales (i.e., no flat approximation). The expected patterns induced by the peak, either in temperature or polarization, are calculated, as well as their covariances. It is found that the eccentricity introduces a quadrupolar dependence in the peak shape, which is proportional to a complex bias parameter bepsilon, characterizing the peak asymmetry and orientation. In addition, the one-point statistics of the variables defining the peak on the sphere is reviewed, finding some differences with respect to the flat case for large peaks. Finally, we present a mechanism to simulate constrained CMB maps with a particular peak on the field, which is an interesting tool for analysing the statistical properties of the peaks present in the data.

  4. What we can learn from peak temperatures profiles in inverted metamorphic sequences

    NASA Astrophysics Data System (ADS)

    Duprat-Oualid, Sylvia; Yamato, Philippe

    2016-04-01

    Inverted metamorphic sequences correspond to the stacking of structural units through which the metamorphic peak temperatures progressively increase upwards. Such thermal profiles, already studied for years, are characteristic of lithospheric-scale thrust zones. Nevertheless, the processes allowing their formation still remain contentious. Several processes can, indeed, lead to peak temperatures inversion: heat advection, shear heating, in-depth accretion and/or erosion (allowing the exhumation of the overthrusting block). Furthermore, heat diffusion also has an important effect on temperatures distribution on both sides of the thrust. Each one of these processes distinctly impacts on the metamorphic thermal field in the vicinity of the thrust zone. However, their respective influences were never clearly analyzed and compared despite their crucial importance for the interpretation of the inverted peak temperatures signatures. Here, we thus propose to address this shortcoming by using two-dimensional numerical models simulating intra-continental thrusts systems. To do so, we combine a parametric numerical study and the "analytical characterization" of the computed inverted peak temperatures recorded, in our models, along profiles perpendicular to the thrust zone. The parametric combinations, including kinematic setting (i.e., convergence, erosion and accretion), thermal properties, mechanical strength and heat sources, control the processes into play during the thrust activity whose relative importances can be quantified. When the resulting peak temperatures profiles present a noticeable inversion, they are converted into a function of approximation characterized by six parameters. These six outputs then constitute the keys to quantitatively decipher the inversions features, not only in terms of spatial extent and intensity over time, but also by characterizing the peak temperatures trends on either sides of the domain of inversion. This numerical and analytical

  5. Contribution For Arc Temperature Affected By Current Increment Ratio At Peak Current In Pulsed Arc

    NASA Astrophysics Data System (ADS)

    Kano, Ryota; Mitubori, Hironori; Iwao, Toru

    2015-11-01

    Tungsten Inert Gas (TIG) Welding is one of the high quality welding. However, parameters of the pulsed arc welding are many and complicated. if the welding parameters are not appropriate, the welding pool shape becomes wide and shallow.the convection of driving force contributes to the welding pool shape. However, in the case of changing current waveform as the pulse high frequency TIG welding, the arc temperature does not follow the change of the current. Other result of the calculation, in particular, the arc temperature at the reaching time of peak current is based on these considerations. Thus, the accurate measurement of the temperature at the time is required. Therefore, the objective of this research is the elucidation of contribution for arc temperature affected by current increment ratio at peak current in pulsed arc. It should obtain a detail knowledge of the welding model in pulsed arc. The temperature in the case of increment of the peak current from the base current is measured by using spectroscopy. As a result, when the arc current increases from 100 A to 150 A at 120 ms, the transient response of the temperature didn't occur during increasing current. Thus, during the current rise, it has been verified by measuring. Therefore, the contribution for arc temperature affected by current increment ratio at peak current in pulsed arc was elucidated in order to obtain more knowledge of welding model of pulsed arc.

  6. Origin of low-temperature shoulder internal friction peak of Snoek-Köster peak in a medium carbon high alloyed steel

    NASA Astrophysics Data System (ADS)

    Lu, Xianwen; Jin, Mingjiang; Zhao, Hongshan; Li, Wei; Jin, Xuejun

    2014-10-01

    A distinct internal friction peak located at the low-temperature shoulder of Snoek-Köster peak (LTS-SK) was found in Fe-0.39C-9.8Ni-1.56Si-2.0Mn steel and its evolution with respect to various aging treatments was investigated. The LTS-SK internal friction peak was found to occur when aged below 373 K. TEM observation confirmed that the ε-carbide precipitated beyond 373 K, providing an evidence that the LTS-SK peak cannot be caused by ε-carbide precipitation. The corresponding evolution on the S-K peak and thermoelectric power (TEP) illustrated that the carbon content in the solid solution decreases due to carbon atoms segregation on the surrounding dislocations during low-temperature aging. The origin of the LTS-SK peak is likely attributed to the interaction between the carbon atoms and twin boundaries in martensite.

  7. Temperature for Spent Fuel Dry Storage

    Energy Science and Technology Software Center (ESTSC)

    1992-07-13

    DATING (Determining Allowable Temperatures in Inert and Nitrogen Gases) calculates allowable initial temperatures for dry storage of light-water-reactor spent fuel and the cumulative damage fraction of Zircaloy cladding for specified initial storage temperature and stress and cooling histories. It is made available to ensure compliance with NUREG 10CFR Part 72, Licensing Requirements for the Storage of Spent Fuel in an Independent Spent Fuel Storage Installation (ISFSI). Although the program''s principal purpose is to calculate estimatesmore » of allowable temperature limits, estimates for creep strain, annealing fraction, and life fraction as a function of storage time are also provided. Equations for the temperature of spent fuel in inert and nitrogen gas storage are included explicitly in the code; in addition, an option is included for a user-specified cooling history in tabular form, and tables of the temperature and stress dependencies of creep-strain rate and creep-rupture time for Zircaloy at constant temperature and constant stress or constant ratio of stress/modulus can be created. DATING includes the GEAR package for the numerical solution of the rate equations and DPLOT for plotting the time-dependence of the calculated cumulative damage-fraction, creep strain, radiation damage recovery, and temperature decay.« less

  8. Temperature for Spent Fuel Dry Storage

    SciTech Connect

    1992-07-13

    DATING (Determining Allowable Temperatures in Inert and Nitrogen Gases) calculates allowable initial temperatures for dry storage of light-water-reactor spent fuel and the cumulative damage fraction of Zircaloy cladding for specified initial storage temperature and stress and cooling histories. It is made available to ensure compliance with NUREG 10CFR Part 72, Licensing Requirements for the Storage of Spent Fuel in an Independent Spent Fuel Storage Installation (ISFSI). Although the program''s principal purpose is to calculate estimates of allowable temperature limits, estimates for creep strain, annealing fraction, and life fraction as a function of storage time are also provided. Equations for the temperature of spent fuel in inert and nitrogen gas storage are included explicitly in the code; in addition, an option is included for a user-specified cooling history in tabular form, and tables of the temperature and stress dependencies of creep-strain rate and creep-rupture time for Zircaloy at constant temperature and constant stress or constant ratio of stress/modulus can be created. DATING includes the GEAR package for the numerical solution of the rate equations and DPLOT for plotting the time-dependence of the calculated cumulative damage-fraction, creep strain, radiation damage recovery, and temperature decay.

  9. Ion Size Effect on Glow Peak Temperature in Dielectric Binary Mixed Crystals Doped With Divalent Europium

    NASA Astrophysics Data System (ADS)

    Rodriguez-Mijangos, Ricardo; Perez-Salas, Raul

    2008-03-01

    Thermoluminiscence measurements at room temperature of ``beta'' irradiated divalent Europium doped binary mixed alkali halides with RbCl and KBr components at several concentrations x in molar fraction are carried out. The experiments have been carried out to identify the effect of composition in thermoluminiscense glow peaks. A typical glow peak has been distinguished for each composition. A linear dependence of its temperature on the composition x has been found. This is principally associated with the radii size change of halogen ions. Comparison with results in mixed KCl:KBr. KBr:RbBr and KCl:RbCl support that assertion.

  10. A relationship between peak temperature drop and velocity differential in a microburst

    NASA Technical Reports Server (NTRS)

    Proctor, Fred H.

    1989-01-01

    Results from numerical microburst simulations using the Terminal Area Simulation System (Proctor, 1987) are used to develop a relationship between wind velocity differential and peak temperature drop. The numerical model and the relationships derived from the model are described. The relationship between peak temperature drop and differential wind velocity is shown to be valid during microburst development, for all precipitation shaft intensities and diameters. It is found that the relationship is not valid for low-reflectivity microburst events or in the presence of ground-based stable layers. The use of the relationship in IR wind shear detection systems is considered.

  11. Peak Seeking Control for Reduced Fuel Consumption with Preliminary Flight Test Results

    NASA Technical Reports Server (NTRS)

    Brown, Nelson

    2012-01-01

    The Environmentally Responsible Aviation project seeks to accomplish the simultaneous reduction of fuel burn, noise, and emissions. A project at NASA Dryden Flight Research Center is contributing to ERAs goals by exploring the practical application of real-time trim configuration optimization for enhanced performance and reduced fuel consumption. This peak-seeking control approach is based on Newton-Raphson algorithm using a time-varying Kalman filter to estimate the gradient of the performance function. In real-time operation, deflection of symmetric ailerons, trailing-edge flaps, and leading-edge flaps of a modified F-18 are directly optimized, and the horizontal stabilators and angle of attack are indirectly optimized. Preliminary results from three research flights are presented herein. The optimization system found a trim configuration that required approximately 3.5% less fuel flow than the baseline trim at the given flight condition. The algorithm consistently rediscovered the solution from several initial conditions. These preliminary results show the algorithm has good performance and is expected to show similar results at other flight conditions and aircraft configurations.

  12. Intermediate temperature solid oxide fuel cells.

    PubMed

    Brett, Daniel J L; Atkinson, Alan; Brandon, Nigel P; Skinner, Stephen J

    2008-08-01

    High temperature solid oxide fuel cells (SOFCs), typified by developers such as Siemens Westinghouse and Rolls-Royce, operate in the temperature region of 850-1000 degrees C. For such systems, very high efficiencies can be achieved from integration with gas turbines for large-scale stationary applications. However, high temperature operation means that the components of the stack need to be predominantly ceramic and high temperature metal alloys are needed for many balance-of-plant components. For smaller scale applications, where integration with a heat engine is not appropriate, there is a trend to move to lower temperatures of operation, into the so-called intermediate temperature (IT) range of 500-750 degrees C. This expands the choice of materials and stack geometries that can be used, offering reduced system cost and, in principle, reducing the corrosion rate of stack and system components. This review introduces the IT-SOFC and explains the advantages of operation in this temperature regime. The main advances made in materials chemistry that have made IT operation possible are described and some of the engineering issues and the new opportunities that reduced temperature operation affords are discussed. This tutorial review examines the advances being made in materials and engineering that are allowing solid oxide fuel cells to operate at lower temperature. The challenges and advantages of operating in the so-called 'intermediate temperature' range of 500-750 degrees C are discussed and the opportunities for applications not traditionally associated with solid oxide fuel cells are highlighted. This article serves as an introduction for scientists and engineers interested in intermediate temperature solid oxide fuel cells and the challenges and opportunities of reduced temperature operation. PMID:18648682

  13. Effects of fictive temperature and halogen doping on the boson peak in silica glass

    NASA Astrophysics Data System (ADS)

    Shimodaira, N.; Saito, K.; Hiramitsu, N.; Matsushita, S.; Ikushima, A. J.

    2005-01-01

    We have investigated the effect of structural disorder on the boson peak in the Raman scattering of silica glass. The structural disorder was controlled in two ways: fictive temperature (Tf) and concentration of doped halogen element (F or Cl). As results, it has been simply demonstrated from nonreduced Raman spectra that (1) the peak position and full width at half maximum of the boson peak linearly increase with increasing Tf irrespective of the halogen concentrations, and in contrast, (2) the intensity is rather strongly dependent on the halogen concentrations than Tf . Since the result in (1) is much similar to the dependence on Tf and fluorine concentration for the IR absorption around 2260cm-1 , it has been concluded that the boson peak in silica glass is microscopically related to the average magnitude and distribution of Si-O-Si bond angles in glass network. The intensity enhancement in (2) has suggested two possibilities about the contribution of the doped halogen element to the boson peak: One is a direct contribution of F or Cl atoms due to diffusive motions falling within the range of the boson peak. The other is an indirect contribution introduced by the termination of Si-O-Si bridges to some sort of vibrational motions, which may be related to the boson peak.

  14. A regression approach to the analysis of serial peak flow among fuel oil ash exposed workers.

    PubMed

    Hauser, R; Daskalakis, C; Christiani, D C

    1996-10-01

    We investigated the association between exposure to fuel oil ash and acute airway obstruction in 31 boilermakers and 31 utility workers during the overhaul of a large oil-fired boiler. Air flow was assessed with self-recorded serial peak expiratory flow rate measurements (PEFR) using a mini-Wright meter. Exposure to thoracic particulates with an aerodynamic diameter of 10 gm or smaller (PM10) was assessed using personal sampling devices and detailed work diaries. All subjects were male, with an average age of 43 yr, and an average of 18 yr at their current trade. Average PM10 exposure on work days was 2.75 mg/m3 for boilermakers and 0.57 mg/m3 for utility workers. Three daily PEFR measurements (start-of-shift, end-of-shift, and bed-time) were analyzed simultaneously, using Huber linear regression. After adjustment for job title, welder status, age, height, smoking, and weld-years, for each mg/m3 increase in PM10, the estimated decline in PEFR was 13.2 L/min (p = 0.008) for end-of-shift, 9.9 L/min (p = 0.045) for bed-time, and 6.6 L/min (p = 0.26) for start-of-shift of the following day. This decline of the exposure effect over the 24-h period that follows was statistically significant (p = 0.004). No other factors were found to significantly modify the effect of exposure. Our results suggest that occupational exposure to fuel oil ash is associated with significant acute decrements in peak flow. PMID:8887594

  15. Validation of the BISON 3D Fuel Performance Code: Temperature Comparisons for Concentrically and Eccentrically Located Fuel Pellets

    SciTech Connect

    J. D. Hales; D. M. Perez; R. L. Williamson; S. R. Novascone; B. W. Spencer

    2013-03-01

    BISON is a modern finite-element based nuclear fuel performance code that has been under development at the Idaho National Laboratory (USA) since 2009. The code is applicable to both steady and transient fuel behaviour and is used to analyse either 2D axisymmetric or 3D geometries. BISON has been applied to a variety of fuel forms including LWR fuel rods, TRISO-coated fuel particles, and metallic fuel in both rod and plate geometries. Code validation is currently in progress, principally by comparison to instrumented LWR fuel rods. Halden IFA experiments constitute a large percentage of the current BISON validation base. The validation emphasis here is centreline temperatures at the beginning of fuel life, with comparisons made to seven rods from the IFA-431 and 432 assemblies. The principal focus is IFA-431 Rod 4, which included concentric and eccentrically located fuel pellets. This experiment provides an opportunity to explore 3D thermomechanical behaviour and assess the 3D simulation capabilities of BISON. Analysis results agree with experimental results showing lower fuel centreline temperatures for eccentric fuel with the peak temperature shifted from the centreline. The comparison confirms with modern 3D analysis tools that the measured temperature difference between concentric and eccentric pellets is not an artefact and provides a quantitative explanation for the difference.

  16. Analysis of the change in peak corneal temperature during excimer laser ablation in porcine eyes

    NASA Astrophysics Data System (ADS)

    Mosquera, Samuel Arba; Verma, Shwetabh

    2015-07-01

    The objective is to characterize the impact of different ablation parameters on the thermal load during corneal refractive surgery by means of excimer laser ablation on porcine eyes. One hundred eleven ablations were performed in 105 porcine eyes. Each ablation was recorded using infrared thermography and analyzed mainly based on the two tested local frequencies (40 Hz, clinical local frequency; 1000 Hz, no local frequency). The change in peak corneal temperature was analyzed with respect to varying ablation parameters [local frequency, system repetition rate, pulse energy, optical zone (OZ) size, and refractive correction]. Transepithelial ablations were also compared to intrastromal ablations. The average of the baseline temperature across all eyes was 20.5°C±1.1 (17.7°C to 22.2°C). Average of the change in peak corneal temperature for all clinical local frequency ablations was 5.8°C±0.8 (p=3.3E-53 to baseline), whereas the average was 9.0°C±1.5 for all no local frequency ablations (p=1.8E-35 to baseline, 1.6E-16 to clinical local frequency ablations). A logarithmic relationship was observed between the changes in peak corneal temperature with increasing local frequency. For clinical local frequency, change in peak corneal temperature was comparatively flat (r2=0.68 with a range of 1.5°C) with increasing system repetition rate and increased linearly with increasing OZ size (r2=0.95 with a range of 2.4°C). Local frequency controls help maintain safe corneal temperature increase during excimer laser ablations. Transepithelial ablations induce higher thermal load compared to intrastromal ablations, indicating a need for stronger thermal controls in transepithelial refractive procedures.

  17. Relationship between peak spatial-averaged specific absorption rate and peak temperature elevation in human head in frequency range of 1–30 GHz

    NASA Astrophysics Data System (ADS)

    Morimoto, Ryota; Laakso, Ilkka; De Santis, Valerio; Hirata, Akimasa

    2016-07-01

    This study investigates the relationship between the peak temperature elevation and the peak specific absorption rate (SAR) averaged over 10 g of tissue in human head models in the frequency range of 1–30 GHz. As a wave source, a half-wave dipole antenna resonant at the respective frequencies is located in the proximity of the pinna. The bioheat equation is used to evaluate the temperature elevation by employing the SAR, which is computed by electromagnetic analysis, as a heat source. The computed SAR is post-processed by calculating the peak spatial-averaged SAR with six averaging algorithms that consider different descriptions provided in international guidelines and standards, e.g. the number of tissues allowed in the averaging volume, different averaging shapes, and the consideration of the pinna. The computational results show that the SAR averaging algorithms excluding the pinna are essential when correlating the peak temperature elevation in the head excluding the pinna. In the averaging scheme considering an arbitrary shape, for better correlation, multiple tissues should be included in the averaging volume rather than a single tissue. For frequencies higher than 3–4 GHz, the correlation for peak temperature elevation in the head excluding the pinna is modest for the different algorithms. The 95th percentile value of the heating factor as well as the mean and median values derived here would be helpful for estimating the possible temperature elevation in the head.

  18. Portable peak flow meters: physical characteristics, influence of temperature, altitude, and humidity.

    PubMed

    Pedersen, O F; Miller, M R; Sigsgaard, T; Tidley, M; Harding, R M

    1994-05-01

    Little is known about the linearity of portable peak flow meters, or about physical gas factors affecting peak expiratory flow (PEF) readings. We therefore tested five portable peak flow meters of three types in an altitude chamber (sea level to 5,500 m) and in a climate chamber at sea level (7-37 degrees C) to determine the influence of the physical conditions of the gas on the reading of the meters. The nonlinear response of the variable orifice meters was confirmed and, when this was corrected for, the readings of these meters were found to be significantly reduced by higher altitude and lower temperature. The readings from a turbine type of peak flow meter were not affected by altitude but were reduced at low temperature. A mathematical model for the variable orifice meters could correct for both their nonlinear behaviour and the effect of gas density (altitude, temperature and humidity). The model showed that correction is not necessary for the differences in gas conditions between calibration and taking of measurements under normal laboratory conditions. All the meters tested had impedances higher than recommended (0.05 kPa.l-1.s) and this may influence PEF at high flows. The mean uncorrected PEF of six healthy subjects when measured with a Mini Wright peak flow meter at sea level and at 3,000 m fell by 5%, but the mean corrected PEF increased by 12%. This increase in PEF was about 60% of that predicted for fully density-dependent flow and agreed with the findings of other similar studies.(ABSTRACT TRUNCATED AT 250 WORDS) PMID:8050558

  19. Technical Basis for Peak Reactivity Burnup Credit for BWR Spent Nuclear Fuel in Storage and Transportation Systems

    SciTech Connect

    Marshall, William BJ J; Ade, Brian J; Bowman, Stephen M; Gauld, Ian C; Ilas, Germina; Mertyurek, Ugur; Radulescu, Georgeta

    2015-01-01

    Oak Ridge National Laboratory and the United States Nuclear Regulatory Commission have initiated a multiyear project to investigate application of burnup credit for boiling-water reactor (BWR) fuel in storage and transportation casks. This project includes two phases. The first phase (1) investigates applicability of peak reactivity methods currently used in spent fuel pools (SFPs) to storage and transportation systems and (2) evaluates validation of both reactivity (keff) calculations and burnup credit nuclide concentrations within these methods. The second phase will focus on extending burnup credit beyond peak reactivity. This paper documents the first phase, including an analysis of lattice design parameters and depletion effects, as well as both validation components. Initial efforts related to extended burnup credit are discussed in a companion paper. Peak reactivity analyses have been used in criticality analyses for licensing of BWR fuel in SFPs over the last 20 years. These analyses typically combine credit for the gadolinium burnable absorber present in the fuel with a modest amount of burnup credit. Gadolinium burnable absorbers are used in BWR assemblies to control core reactivity. The burnable absorber significantly reduces assembly reactivity at beginning of life, potentially leading to significant increases in assembly reactivity for burnups less than 15–20 GWd/MTU. The reactivity of each fuel lattice is dependent on gadolinium loading. The number of gadolinium-bearing fuel pins lowers initial lattice reactivity, but it has a small impact on the burnup and reactivity of the peak. The gadolinium concentration in each pin has a small impact on initial lattice reactivity but a significant effect on the reactivity of the peak and the burnup at which the peak occurs. The importance of the lattice parameters and depletion conditions are primarily determined by their impact on the gadolinium depletion. Criticality code validation for BWR burnup

  20. Ion Size Effect in Glow Peak Temperature in Binary Mixed Crystals Doped with Divalente Europium

    NASA Astrophysics Data System (ADS)

    Rodriguez-Mijangos, Ricardo; Perez-Salas, Raul

    2006-03-01

    Thermoluminiscence measurements at room temperature of ``beta'' irradiated divalent Europium doped binary mixed alkali halides with KCl and KBr components at several concentrations x in molar fraction. The experiments have been carried out to identify the effect of composition of glow peaks. A typical glow peak has been distinguished for each composition. A linear dependence of its temperature on the composition x has been found. This is associated with the size change of ions Cl and Br. Initial comparative cathodoluminiscent measurement was carried out irradiating a single sample with electrons in an electron microscopy using a 30 KV voltage. With the present results is speculated the behavior of the mixed binary crystals with components KCl and RbCl, doped with divalent Europium.

  1. Intermediate Temperature Solid Oxide Fuel Cell Development

    SciTech Connect

    S. Elangovan; Scott Barnett; Sossina Haile

    2008-06-30

    Solid oxide fuel cells (SOFCs) are high efficiency energy conversion devices. Present materials set, using yttria stabilized zirconia (YSZ) electrolyte, limit the cell operating temperatures to 800 C or higher. It has become increasingly evident however that lowering the operating temperature would provide a more expeditious route to commercialization. The advantages of intermediate temperature (600 to 800 C) operation are related to both economic and materials issues. Lower operating temperature allows the use of low cost materials for the balance of plant and limits degradation arising from materials interactions. When the SOFC operating temperature is in the range of 600 to 700 C, it is also possible to partially reform hydrocarbon fuels within the stack providing additional system cost savings by reducing the air preheat heat-exchanger and blower size. The promise of Sr and Mg doped lanthanum gallate (LSGM) electrolyte materials, based on their high ionic conductivity and oxygen transference number at the intermediate temperature is well recognized. The focus of the present project was two-fold: (a) Identify a cell fabrication technique to achieve the benefits of lanthanum gallate material, and (b) Investigate alternative cathode materials that demonstrate low cathode polarization losses at the intermediate temperature. A porous matrix supported, thin film cell configuration was fabricated. The electrode material precursor was infiltrated into the porous matrix and the counter electrode was screen printed. Both anode and cathode infiltration produced high performance cells. Comparison of the two approaches showed that an infiltrated cathode cells may have advantages in high fuel utilization operations. Two new cathode materials were evaluated. Northwestern University investigated LSGM-ceria composite cathode while Caltech evaluated Ba-Sr-Co-Fe (BSCF) based pervoskite cathode. Both cathode materials showed lower polarization losses at temperatures as low as 600

  2. 40 CFR 1066.950 - Fuel temperature profile.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Test Procedures for Motor Vehicles § 1066.950 Fuel temperature profile. Develop fuel temperature profiles for running loss testing as described in 40 CFR 86.129-94(d). ... 40 Protection of Environment 33 2014-07-01 2014-07-01 false Fuel temperature profile....

  3. Transient response of high temperature PEM fuel cell

    NASA Astrophysics Data System (ADS)

    Peng, J.; Shin, J. Y.; Song, T. W.

    A transient three-dimensional, single-phase and non-isothermal numerical model of polymer electrolyte membrane (PEM) fuel cell with high operating temperature has been developed and implemented in computational fluid dynamic (CFD) code. The model accounts for transient convective and diffusive transport, and allows prediction of species concentration. Electrochemical charge double-layer effect is considered. Heat generation according to electrochemical reaction and ohmic loss are involved. Water transportation across membrane is ignored due to low water electro-osmosis drag force of polymer polybenzimidazole (PBI) membrane. The prediction shows transient in current density which overshoots (undershoots) the stabilized state value when cell voltage is abruptly decreased (increased). The result shows that the peak of overshoot (undershoot) is related with cathode air stoichiometric mass flow rate instead of anode hydrogen stoichiometric mass flow rate. Current is moved smoothly and there are no overshoot or undershoot with the influence of charge double-layer effect. The maximum temperature is located in cathode catalyst layer and both fuel cell average temperature and temperature deviation are increased with increasing of current load.

  4. Peak temperature in intracratonic basins constrained by magnetic studies:Example of the Illinois Basin

    NASA Astrophysics Data System (ADS)

    Uz, E.; Ferre, E. C.; Rimmer, S.; Morse, D. G.; Crockett, J. E.

    2012-12-01

    consists in baking series of aliquot crushed unmetamorphosed sandstones at step-wise temperatures (11 steps) to determine their overall pattern of magnetic changes with temperature. The possible roles of basinal fluids and pressure are ignored in the current experiments. The choice of crushed material as opposed to oriented samples is motivated by the need for the new method to be applicable to drilling chips that are typically produced in oil and gas exploration. The specimens were cemented and baked at step temperatures from 75 to 400 degrees Celsius. The results of these experiments serve to build calibration curves for the method. The burial temperature of specimens of unknown burial temperature is obtained by comparison with those of the calibration runs. Although the new method provides only information on peak burial temperatures, as opposed to complete heating history, this shortfall is common to all existing low-temperature geothermometers.

  5. MELT WIRE SENSORS AVAILABLE TO DETERMINE PEAK TEMPERATURES IN ATR IRRADIATION TESTING

    SciTech Connect

    K. L. Davis; D. Knudson; J. Daw; J. Palmer; J. L. Rempe

    2012-07-01

    In April 2007, the Department of Energy (DOE) designated the Advanced Test Reactor (ATR) a National Scientific User Facility (NSUF) to advance US leadership in nuclear science and technology. By attracting new users from universities, laboratories, and industry, the ATR will support basic and applied nuclear research and development and help address the nation's energy security needs. In support of this new program, the Idaho National Laboratory (INL) has developed in-house capabilities to fabricate, test, and qualify new and enhanced temperature sensors for irradiation testing. Although most efforts emphasize sensors capable of providing real-time data, selected tasks have been completed to enhance sensors provided in irradiation locations where instrumentation leads cannot be included, such as drop-in capsule and Hydraulic Shuttle Irradiation System (HSIS) or 'rabbit' locations. To meet the need for these locations, the INL has developed melt wire temperature sensors for use in ATR irradiation testing. Differential scanning calorimetry and environmental testing of prototypical sensors was used to develop a library of 28 melt wire materials, capable of detecting peak irradiation temperatures ranging from 85 to 1500°C. This paper will discuss the development work and present test results.

  6. Temperature Stratification in a Cryogenic Fuel Tank

    NASA Technical Reports Server (NTRS)

    Daigle, Matthew John; Smelyanskiy, Vadim; Boschee, Jacob; Foygel, Michael Gregory

    2013-01-01

    A reduced dynamical model describing temperature stratification effects driven by natural convection in a liquid hydrogen cryogenic fuel tank has been developed. It accounts for cryogenic propellant loading, storage, and unloading in the conditions of normal, increased, and micro- gravity. The model involves multiple horizontal control volumes in both liquid and ullage spaces. Temperature and velocity boundary layers at the tank walls are taken into account by using correlation relations. Heat exchange involving the tank wall is considered by means of the lumped-parameter method. By employing basic conservation laws, the model takes into consideration the major multi-phase mass and energy exchange processes involved, such as condensation-evaporation of the hydrogen, as well as flows of hydrogen liquid and vapor in the presence of pressurizing helium gas. The model involves a liquid hydrogen feed line and a tank ullage vent valve for pressure control. The temperature stratification effects are investigated, including in the presence of vent valve oscillations. A simulation of temperature stratification effects in a generic cryogenic tank has been implemented in Matlab and results are presented for various tank conditions.

  7. Peak metamorphic temperature and thermal history of the Southern Alps (New Zealand)

    NASA Astrophysics Data System (ADS)

    Beyssac, O.; Cox, S. C.; Vry, J.; Herman, F.

    2016-04-01

    The Southern Alps orogen of New Zealand results from late Cenozoic convergence between the Indo-Australian and Pacific plates and is one of the most active mountain belts in the world. Metamorphic rocks carrying a polymetamorphic legacy, ranging from low-greenschist to high-grade amphibolites, are exhumed in the hanging wall of the Alpine Fault. On a regional scale, the metamorphic grade has previously been described in terms of metamorphic zones and mineral isograds; application of quantitative petrology being severely limited owing to unfavorable quartzofeldspathic lithologies. This study quantifies peak metamorphic temperatures (T) in a 300 × 20 km area, based on samples forming 13 transects along-strike from Haast in the south to Hokitika in the north, using thermometry based on Raman spectroscopy of carbonaceous material (RSCM). Peak metamorphic T decreases across each transect from ≥ 640 °C locally in the direct vicinity of the Alpine Fault to less than 330 °C at the drainage divide 15-20 km southeast of the fault. Thermal field gradients exhibit a degree of similarity from the southernmost to the northernmost transects, are greater in low-grade semischist than high-grade schist, are affected by folding or discontinuous juxtaposition of metamorphic zones, and contain limited information on crustal-scale geothermal gradients. Temperatures derived by RSCM thermometry are slightly (≤ 50 °C) higher than those derived by traditional quantitative petrology using garnet-biotite thermometry and THERMOCALC modeling. The age of RSCM T appears to be mostly pre-Cenozoic over most of the area except in central Southern Alps (Franz Josef-Fox area), where the amphibolite facies schists have T of likely Cenozoic age. The RSCM T data place some constraints on the mode of exhumation along the Alpine Fault and have implications for models of Southern Alps tectonics.

  8. Temperature feedback of TRIGA MARK-II fuel

    NASA Astrophysics Data System (ADS)

    Usang, M. D.; Minhat, M. S.; Rabir, M. H.; M. Rawi M., Z.

    2016-01-01

    We study the amount of temperature feedback on reactivity for the three types of TRIGA fuel i.. ST8, ST12 and LEU fuel, are used in the TRIGA MARK II reactor in Malaysia Nuclear Agency. We employ WIMSD-5B for the calculation of kin f for a single TRIGA fuel surrounded by water. Typical calculations of TRIGA fuel reactivity are usually limited to ST8 fuel, but in this paper our investigation extends to ST12 and LEU fuel. We look at the kin f of our model at various fuel temperatures and calculate the amount reactivity removed. In one instance, the water temperature is kept at room temperature of 300K to simulate sudden reactivity increase from startup. In another instance, we simulate the sudden temperature increase during normal operation where the water temperature is approximately 320K while observing the kin f at various fuel temperatures. For accidents, two cases are simulated. The first case is for water temperature at 370K and the other is without any water. We observe that the higher Uranium content fuel such as the ST12 and LEU have much smaller contribution to the reactivity in comparison to the often studied ST8 fuel. In fact the negative reactivity coefficient for LEU fuel at high temperature in water is only slightly larger to the negative reactivity coefficient for ST8 fuel in void. The performance of ST8 fuel in terms of negative reactivity coefficient is cut almost by half when it is in void. These results are essential in the safety evaluation of the reactor and should be carefully considered when choices of fuel for core reconfiguration are made.

  9. Novel Low Temperature Solid State Fuel Cells

    SciTech Connect

    Chen, Chonglin; Nash, Patrick; Liu, Jian; Collins, Gregory

    2009-12-15

    We have successfully fabricated (PrBa)Co{sub 2}O{sub 5+{delta}} and (LaBa)Co{sub 2}O{sub 5+{deleta}} epitaxial thin film on various single crystal substrates. Physical and electrochemical properties characterizations were carried out. Highly conductive oxygen-deficient double perovskite LnBaCo2O5+? thin films were grown on single crystal (001) SrTiO{sub 3} (STO), (001) MgO, (001) LaAlO{sub 3} and (110) NdGaO{sub 3} substrate by pulsed laser deposition. Microstructure studies from synchrotron X-ray diffraction and Transmission electron microscopy. High temperature transport properties was carried in different atmosphere (O{sub 2},Air, N{sub 2}) up to ~900K. Resistance response of (LaBa)Co{sub 2}O{sub 5+{delta}} epitaxial thin film was characterized in oxygen, nitrogen and 4% hydrogen over a wide range of temperature from 400�C up to 800�C. To determine the electrode performance and oxygen exchange kinetics of PrBaCo{sub 2}O{sub 5+{delta}}, multi-layered thin film based half cell was deposited on LaAlO{sub 3}(001) substrate. The temperature dependence of the resistance of this half ?cell structure was characterized by electrochemical impedance spectroscopy (EIS) within different temperature and gas environments. Anode supported fuel cells, with GCO:YSZ multilayer thin film as electrolyte and PBCO thin film as electrode, are fabricated on tape casted NiO/YSZ substrate. Full cell performance is characterized up to 800�C.

  10. Measurement and correlation of jet fuel viscosities at low temperatures

    NASA Technical Reports Server (NTRS)

    Schruben, D. L.

    1985-01-01

    Apparatus and procedures were developed to measure jet fuel viscosity for eight current and future jet fuels at temperatures from ambient to near -60 C by shear viscometry. Viscosity data showed good reproducibility even at temperatures a few degrees below the measured freezing point. The viscosity-temperature relationship could be correlated by two linear segments when plotted as a standard log-log type representation (ASTM D 341). At high temperatures, the viscosity-temperature slope is low. At low temperatures, where wax precipitation is significant, the slope is higher. The breakpoint between temperature regions is the filter flow temperature, a fuel characteristic approximated by the freezing point. A generalization of the representation for the eight experimental fuels provided a predictive correlation for low-temperature viscosity, considered sufficiently accurate for many design or performance calculations.

  11. Dependence of curing time, peak temperature, and mechanical properties on the composition of bone cement.

    PubMed

    Brauer, G M; Steinberger, D R; Stansbury, J W

    1986-01-01

    Commercial bone cements usually contain hydroquinone as the polymerization inhibitor and N,N-dimethyl-p-toluidine as the accelerator in the benzoyl peroxide-initiated redox polymerization. The former compounds have certain shortcomings in their biocompatibility profile. Measurements of the setting times, polymerization exotherms, and postpolymerization strengths of the cured monomer-polymer compositions show that the hydroquinone can be replaced by food grade di-tert-butyl-p-cresol (BHT). The more reactive 4-N,N-(dimethylamino)phenethanol can replace 4-N,N-dimethyl-p-toluidine, yielding cements with shorter setting times and increased strengths. Excessive heat liberated on polymerization can be reduced by partial substitution of higher-molecular-weight methacrylates, e.g., dicyclopentenyloxyethyl methacrylate for methyl methacrylate, but there is a decrease in strength of the resulting polymer. More successful has been the addition to the monomer of 1% or 2% of the chain transfer agent pentaerythritol tetra(3-mercaptopropionate), which lowers the peak temperature without changing the physical properties of the cement. Compositions with short curing times, lower exotherms, and mechanical properties that exceed those of a commercial material have been formulated. PMID:3722218

  12. Preparation of high temperature gas-cooled reactor fuel element

    DOEpatents

    Bradley, Ronnie A.; Sease, John D.

    1976-01-01

    This invention relates to a method for the preparation of high temperature gas-cooled reactor (HTGR) fuel elements wherein uncarbonized fuel rods are inserted in appropriate channels of an HTGR fuel element block and the entire block is inserted in an autoclave for in situ carbonization under high pressure. The method is particularly applicable to remote handling techniques.

  13. Mixed field peronnel dosimetry: Part 1, High temperature peak characteristics of the reader-annealed TLD-600

    SciTech Connect

    Liu, J.C. ); Sims, C.S. )

    1991-02-01

    The high temperature peaks (TL peaks 6--7) of TLD-600 are known to have higher responses to high LET radiation than to low LET radiation. These high temperature peak characteristics were studied for the automatic reader-annealed Harshaw albedo neutron TLD. The high temperature peaks response is linear for neutrons over the dose equivalent range tested (0.05--3 mSv of a {sup 252}Cf source moderated by a 15 cm radius polyethylene sphere), but is supralinear above 20 mSv of {sup 137}Cs photons. The peaks ratio (peaks 6--7/peaks 3--5) of TLD-600 is 0.15 for neutrons of any incident energy, 0.01 for {sup 137}Cs gammas, and 0.02 for M-150 x-rays. Based on the high temperature peak characteristics, a mixed field neutron-photon personnel dosimetry methodology using a single TLD-600 element was developed. The dosimetric method was evaluated in mixed {sup 238}PuBe + {sup 137}Cs fields with four neutron-gamma dose equivalent ratios, and the neutron, photon and total dose equivalent estimations are better than 20% except in one case. However, it was found that the neutron and photon dose equivalent estimations are sensitive to the neutron and photon peaks ratios, depending on the neutron-photon dose equivalent ratio and the neutron source in the mixed field. Therefore, a successful use of this method requires knowledge of the photon and neutron energies in the mixed field. 13 refs., 6 figs., 2 tabs.

  14. Estimating peak and solidification temperatures for anatectic pelitic migmatites using phase diagrams: sampling heterogeneous migmatites and confronting melt loss

    NASA Astrophysics Data System (ADS)

    Hamilton, Brett M.; Pattison, David R. M.

    2016-04-01

    Calculating a pressure-temperature phase diagram relevant to an anatectic pelitic migmatite sampled in outcrop is challenging because it is unclear what constitutes a meaningful bulk composition. Melt loss during metamorphism may have changed the bulk composition. The heterogeneous nature of migmatites, with light and dark coloured domains (leucosome and melanosome), means a choice must be made regarding how a migmatitic outcrop should be sampled. To address these issues, migmatites were simulated using thermodynamic modelling techniques for different melting and crystallization scenarios and bulk compositions. Using phase diagrams calculated for varying proportions of simulated melanosome and leucosome, temperatures of interest were estimated and compared with known values. Our modelling suggests: (1) It is generally possible to constrain the peak temperature using phase diagrams calculated with the composition of the melanosome; the more leucosome that is incorporated, the more innaccurate the estimate. For phase diagrams calculated using a combination of leucosome and melanosome material, peak temperature estimates differ from actual peak conditions by ‑25 to +50°C. In certain of these cases, such as those involving high proportions of leucosome to melanosome, or in which solid K-feldspar was absent at peak conditions, but is now present in the rock due to later crystallization from melt, it is not possible to estimate peak temperature. (2) The solidification temperature, whether due to crystallization of the last melt or physical loss of the melt during crystallization, will fall between the peak temperature and the water-saturated solidus (~660°C) if the melt and solids chemically interacted during cooling. This temperature can be accurately constrained from the phase diagram. If the melt crystallized in chemical isolation from the melanosome, the solidification temperature is the water-saturated solidus (625-645°C); however, physical melt loss during

  15. Performance of HT9 clad metallic fuel at high temperature

    SciTech Connect

    Pahl, R.G.; Lahm, C.E.; Hayes, S.L.

    1992-12-01

    Steady-state testing of HT9 clad metallic fuel at high temperatures was initiated in EBR-II in November of 1987. At that time U-10 wt. % Zr fuel clad with the low-swelling ferritic/martensitic alloy HT9 was being considered as driver fuel options for both EBR-II and FFTF. The objective of the X447 test described here was to determine the lifetime of HT9 cladding when operated with metallic fuel at beginning of life inside wall temperatures approaching {approximately}660{degree}C. Though stress-temperature design limits for HT9 preclude its use for high burnup applications under these conditions due to excessive thermal creep, the X447 test was carried out to obtain data on high temperature breach phenomena involving metallic fuel since little data existed in that area.

  16. Performance of HT9 clad metallic fuel at high temperature

    SciTech Connect

    Pahl, R.G.; Lahm, C.E.; Hayes, S.L.

    1992-01-01

    Steady-state testing of HT9 clad metallic fuel at high temperatures was initiated in EBR-II in November of 1987. At that time U-10 wt. % Zr fuel clad with the low-swelling ferritic/martensitic alloy HT9 was being considered as driver fuel options for both EBR-II and FFTF. The objective of the X447 test described here was to determine the lifetime of HT9 cladding when operated with metallic fuel at beginning of life inside wall temperatures approaching [approximately]660[degree]C. Though stress-temperature design limits for HT9 preclude its use for high burnup applications under these conditions due to excessive thermal creep, the X447 test was carried out to obtain data on high temperature breach phenomena involving metallic fuel since little data existed in that area.

  17. In vitro infrared thermography assessment of temperature peaks during the intra-oral welding of titanium abutments

    NASA Astrophysics Data System (ADS)

    Degidi, Marco; Nardi, Diego; Sighinolfi, Gianluca; Merla, Arcangelo; Piattelli, Adriano

    2012-07-01

    Control of heat dissipation and transmission to the peri-implant area during intra-oral welding is very important to limit potential damage to the surrounding tissue. The aim of this in vitro study was to assess, by means of thermal infrared imaging, the tissue temperature peaks associated with the thermal propagation pathway through the implants, the abutments and the walls of the slot of the scaffold, generated during the welding process, in three different implant systems. An in vitro polyurethane mandible model was prepared with a 7.0 mm v-shape slot. Effects on the maximum temperature by a single welding procedure were studied using different power supplies and abutments. A total of 36 welding procedures were tested on three different implant systems. The lowest peak temperature along the walls of the 7.0 mm v-shaped groove (31.6 ± 2 °C) was assessed in the specimens irrigated with sterile saline solution. The highest peak temperature (42.8 ± 2 °C) was assessed in the samples with a contemporaneous power overflow and premature pincers removal. The results of our study suggest that the procedures used until now appear to be effective to avoid thermal bone injuries. The peak tissue temperature of the in vitro model did not surpass the threshold limits above which tissue injury could occur.

  18. Children and adults exposed to electromagnetic fields at the ICNIRP reference levels: theoretical assessment of the induced peak temperature increase.

    PubMed

    Bakker, J F; Paulides, M M; Neufeld, E; Christ, A; Kuster, N; van Rhoon, G C

    2011-08-01

    To avoid potentially adverse health effects of electromagnetic fields (EMF), the International Commission on Non-Ionizing Radiation Protection (ICNIRP) has defined EMF reference levels. Restrictions on induced whole-body-averaged specific absorption rate (SAR(wb)) are provided to keep the whole-body temperature increase (T(body, incr)) under 1 °C during 30 min. Additional restrictions on the peak 10 g spatial-averaged SAR (SAR(10g)) are provided to prevent excessive localized tissue heating. The objective of this study is to assess the localized peak temperature increase (T(incr, max)) in children upon exposure at the reference levels. Finite-difference time-domain modeling was used to calculate T(incr, max) in six children and two adults exposed to orthogonal plane-wave configurations. We performed a sensitivity study and Monte Carlo analysis to assess the uncertainty of the results. Considering the uncertainties in the model parameters, we found that a peak temperature increase as high as 1 °C can occur for worst-case scenarios at the ICNIRP reference levels. Since the guidelines are deduced from temperature increase, we used T(incr, max) as being a better metric to prevent excessive localized tissue heating instead of localized peak SAR. However, we note that the exposure time should also be considered in future guidelines. Hence, we advise defining limits on T(incr, max) for specified durations of exposure. PMID:21772085

  19. Solid oxide fuel cell operable over wide temperature range

    DOEpatents

    Baozhen, Li; Ruka, Roswell J.; Singhal, Subhash C.

    2001-01-01

    Solid oxide fuel cells having improved low-temperature operation are disclosed. In one embodiment, an interfacial layer of terbia-stabilized zirconia is located between the air electrode and electrolyte of the solid oxide fuel cell. The interfacial layer provides a barrier which controls interaction between the air electrode and electrolyte. The interfacial layer also reduces polarization loss through the reduction of the air electrode/electrolyte interfacial electrical resistance. In another embodiment, the solid oxide fuel cell comprises a scandia-stabilized zirconia electrolyte having high electrical conductivity. The scandia-stabilized zirconia electrolyte may be provided as a very thin layer in order to reduce resistance. The scandia-stabilized electrolyte is preferably used in combination with the terbia-stabilized interfacial layer. The solid oxide fuel cells are operable over wider temperature ranges and wider temperature gradients in comparison with conventional fuel cells.

  20. Fuel processor temperature monitoring and control

    DOEpatents

    Keskula, Donald H.; Doan, Tien M.; Clingerman, Bruce J.

    2002-01-01

    In one embodiment, the method of the invention monitors one or more of the following conditions: a relatively low temperature value of the gas stream; a relatively high temperature value of the gas stream; and a rate-of-change of monitored temperature. In a preferred embodiment, the rate of temperature change is monitored to prevent the occurrence of an unacceptably high or low temperature condition. Here, at least two temperatures of the recirculating gas stream are monitored over a period of time. The rate-of-change of temperature versus time is determined. Then the monitored rate-of-change of temperature is compared to a preselected rate-of-change of value. The monitoring of rate-of-change of temperature provides proactive means for preventing occurrence of an unacceptably high temperature in the catalytic reactor.

  1. Temperature and Burnup Correlated FCCI in U-10Zr Metallic Fuel

    SciTech Connect

    William J. Carmack

    2012-05-01

    the EBR-II and study of the differences between the two fuel systems is critical for design of large advanced sodium cooled fast reactor systems. Comparing FCCI layer formation data between FFTF and EBR-II indicates that the same diffusion model can be used to represent the two systems when considering time, temperature, burnup history, and axial temperature and power profiles. This dissertation shows that FCCI formation peaks further below the top of the fuel column in FFTF experiments than has been observed in EBR-II experiments. The work provided in this dissertation will help forward the design of advanced metallic fuel systems for advanced sodium cooled fast reactors by allowing the prediction of FCCI layer formation in full length reactor designs. This will allow the accurate lifetime prediction of fuel performance capability for new advanced sodium cooled fast reactors with extended core designs.

  2. System for controlling the operating temperature of a fuel cell

    DOEpatents

    Fabis, Thomas R.; Makiel, Joseph M.; Veyo, Stephen E.

    2006-06-06

    A method and system are provided for improved control of the operating temperature of a fuel cell (32) utilizing an improved temperature control system (30) that varies the flow rate of inlet air entering the fuel cell (32) in response to changes in the operating temperature of the fuel cell (32). Consistent with the invention an improved temperature control system (30) is provided that includes a controller (37) that receives an indication of the temperature of the inlet air from a temperature sensor (39) and varies the heat output by at least one heat source (34, 36) to maintain the temperature of the inlet air at a set-point T.sub.inset. The controller (37) also receives an indication of the operating temperature of the fuel cell (32) and varies the flow output by an adjustable air mover (33), within a predetermined range around a set-point F.sub.set, in order to maintain the operating temperature of the fuel cell (32) at a set-point T.sub.opset.

  3. Lowering the temperature of solid oxide fuel cells.

    PubMed

    Wachsman, Eric D; Lee, Kang Taek

    2011-11-18

    Fuel cells are uniquely capable of overcoming combustion efficiency limitations (e.g., the Carnot cycle). However, the linking of fuel cells (an energy conversion device) and hydrogen (an energy carrier) has emphasized investment in proton-exchange membrane fuel cells as part of a larger hydrogen economy and thus relegated fuel cells to a future technology. In contrast, solid oxide fuel cells are capable of operating on conventional fuels (as well as hydrogen) today. The main issue for solid oxide fuel cells is high operating temperature (about 800°C) and the resulting materials and cost limitations and operating complexities (e.g., thermal cycling). Recent solid oxide fuel cells results have demonstrated extremely high power densities of about 2 watts per square centimeter at 650°C along with flexible fueling, thus enabling higher efficiency within the current fuel infrastructure. Newly developed, high-conductivity electrolytes and nanostructured electrode designs provide a path for further performance improvement at much lower temperatures, down to ~350°C, thus providing opportunity to transform the way we convert and store energy. PMID:22096189

  4. Thermodynamic analysis of biofuels as fuels for high temperature fuel cells

    NASA Astrophysics Data System (ADS)

    Milewski, Jarosław; Bujalski, Wojciech; Lewandowski, Janusz

    2013-02-01

    Based on mathematical modeling and numerical simulations, applicativity of various biofuels on high temperature fuel cell performance are presented. Governing equations of high temperature fuel cell modeling are given. Adequate simulators of both solid oxide fuel cell (SOFC) and molten carbonate fuel cell (MCFC) have been done and described. Performance of these fuel cells with different biofuels is shown. Some characteristics are given and described. Advantages and disadvantages of various biofuels from the system performance point of view are pointed out. An analysis of various biofuels as potential fuels for SOFC and MCFC is presented. The results are compared with both methane and hydrogen as the reference fuels. The biofuels are characterized by both lower efficiency and lower fuel utilization factors compared with methane. The presented results are based on a 0D mathematical model in the design point calculation. The governing equations of the model are also presented. Technical and financial analysis of high temperature fuel cells (SOFC and MCFC) are shown. High temperature fuel cells can be fed by biofuels like: biogas, bioethanol, and biomethanol. Operational costs and possible incomes of those installation types were estimated and analyzed. A comparison against classic power generation units is shown. A basic indicator net present value (NPV) for projects was estimated and commented.

  5. Thermodynamic analysis of biofuels as fuels for high temperature fuel cells

    NASA Astrophysics Data System (ADS)

    Milewski, Jarosław; Bujalski, Wojciech; Lewandowski, Janusz

    2011-11-01

    Based on mathematical modeling and numerical simulations, applicativity of various biofuels on high temperature fuel cell performance are presented. Governing equations of high temperature fuel cell modeling are given. Adequate simulators of both solid oxide fuel cell (SOFC) and molten carbonate fuel cell (MCFC) have been done and described. Performance of these fuel cells with different biofuels is shown. Some characteristics are given and described. Advantages and disadvantages of various biofuels from the system performance point of view are pointed out. An analysis of various biofuels as potential fuels for SOFC and MCFC is presented. The results are compared with both methane and hydrogen as the reference fuels. The biofuels are characterized by both lower efficiency and lower fuel utilization factors compared with methane. The presented results are based on a 0D mathematical model in the design point calculation. The governing equations of the model are also presented. Technical and financial analysis of high temperature fuel cells (SOFC and MCFC) are shown. High temperature fuel cells can be fed by biofuels like: biogas, bioethanol, and biomethanol. Operational costs and possible incomes of those installation types were estimated and analyzed. A comparison against classic power generation units is shown. A basic indicator net present value (NPV) for projects was estimated and commented.

  6. High temperature solid electrolyte fuel cell configurations and interconnections

    DOEpatents

    Isenberg, Arnold O.

    1984-01-01

    High temperature fuel cell configurations and interconnections are made including annular cells having a solid electrolyte sandwiched between thin film electrodes. The cells are electrically interconnected along an elongated axial outer surface.

  7. Temperature measuring analysis of the nuclear reactor fuel assembly

    SciTech Connect

    Urban, F. E-mail: zdenko.zavodny@stuba.sk; Kučák, L. E-mail: zdenko.zavodny@stuba.sk; Bereznai, J. E-mail: zdenko.zavodny@stuba.sk; Závodný, Z. E-mail: zdenko.zavodny@stuba.sk; Muškát, P. E-mail: zdenko.zavodny@stuba.sk

    2014-08-06

    Study was based on rapid changes of measured temperature values from the thermocouple in the VVER 440 nuclear reactor fuel assembly. Task was to determine origin of fluctuations of the temperature values by experiments on physical model of the fuel assembly. During an experiment, heated water was circulating in the system and cold water inlet through central tube to record sensitivity of the temperature sensor. Two positions of the sensor was used. First, just above the central tube in the physical model fuel assembly axis and second at the position of the thermocouple in the VVER 440 nuclear reactor fuel assembly. Dependency of the temperature values on time are presented in the diagram form in the paper.

  8. Feedback control of solid oxide fuel cell spatial temperature variation

    NASA Astrophysics Data System (ADS)

    Fardadi, Mahshid; Mueller, Fabian; Jabbari, Faryar

    A high performance feedback controller has been developed to minimize SOFC spatial temperature variation following significant load perturbations. For thermal management, spatial temperature variation along SOFC cannot be avoided. However, results indicate that feedback control can be used to manipulate the fuel cell air flow and inlet fuel cell air temperature to maintain a nearly constant SOFC electrode electrolyte assembly temperature profile. For example temperature variations of less than 5 K are obtained for load perturbations of ±25% from nominal. These results are obtained using a centralized control strategy to regulate a distributed temperature profile and manage actuator interactions. The controller is based on H-infinity synthesis using a physical based dynamic model of a single co-flow SOFC repeat cell. The model of the fuel cell spatial temperature response needed for control synthesis was linearized and reduced from nonlinear model of the fuel cell assembly. A single 11 state feedback linear system tested in the full nonlinear model was found to be effective and stable over a wide fuel cell operating envelope (0.82-0.6 V). Overall, simulation of the advanced controller resulted in small and smooth monotonic temperature response to rapid and large load perturbations. This indicates that future SOFC systems can be designed and controlled to have superb load following characteristic with less than previously expected thermal stresses.

  9. Effects of Fuel Temperature on Injection Process and Combustion of Dimethyl Ether Engine.

    PubMed

    Guangxin, Gao; Zhulin, Yuan; Apeng, Zhou; Shenghua, Liu; Yanju, Wei

    2013-12-01

    To investigate the effects of fuel temperature on the injection process in the fuel-injection pipe and the combustion characteristics of compression ignition (CI) engine, tests on a four stroke, direct injection dimethyl ether (DME) engine were conducted. Experimental results show that as the fuel temperature increases from 20 to 40 °C, the sound speed is decreased by 12.2%, the peak line pressure at pump and nozzle sides are decreased by 7.2% and 5.6%, respectively. Meanwhile, the injection timing is retarded by 2.2 °CA and the injection duration is extended by 0.8 °CA. Accordingly, the ignition delay and the combustion duration are extended by 0.7 °CA and 4.0 °CA, respectively. The cylinder peak pressure is decreased by 5.4%. As a result, the effective thermal efficiency is decreased, especially for temperature above 40 °C. Before beginning an experiment, the fuel properties of DME, including the density, the bulk modulus, and the sound speed were calculated by "ThermoData." The calculated result of sound speed is consistent with the experimental results. PMID:23918238

  10. Temperature Profile in Fuel and Tie-Tubes for Nuclear Thermal Propulsion Systems

    SciTech Connect

    Vishal Patel

    2015-02-01

    A finite element method to calculate temperature profiles in heterogeneous geometries of tie-tube moderated LEU nuclear thermal propulsion systems and HEU designs with tie-tubes is developed and implemented in MATLAB. This new method is compared to previous methods to demonstrate shortcomings in those methods. Typical methods to analyze peak fuel centerline temperature in hexagonal geometries rely on spatial homogenization to derive an analytical expression. These methods are not applicable to cores with tie-tube elements because conduction to tie-tubes cannot be accurately modeled with the homogenized models. The fuel centerline temperature directly impacts safety and performance so it must be predicted carefully. The temperature profile in tie-tubes is also important when high temperatures are expected in the fuel because conduction to the tie-tubes may cause melting in tie-tubes, which may set maximum allowable performance. Estimations of maximum tie-tube temperature can be found from equivalent tube methods, however this method tends to be approximate and overly conservative. A finite element model of heat conduction on a unit cell can model spatial dependence and non-linear conductivity for fuel and tie-tube systems allowing for higher design fidelity of Nuclear Thermal Propulsion.

  11. The low-temperature partial-oxidation reforming of fuels for transportation fuel cell systems

    SciTech Connect

    Kumar, R.; Ahmed, S.; Krumpelt, M.

    1996-12-31

    Passenger cars powered by fuel cell propulsion systems with high efficiency offer superior fuel economy, very low to zero pollutant emissions, and the option to operate on alternative and/or renewable fuels. Although the fuel cell operates on hydrogen, a liquid fuel such as methanol or gasoline is more attractive for automotive use because of the convenience in handling and vehicle refueling. Such a liquid fuel must be dynamically converted (reformed) to hydrogen on board the vehicle in real time to meet fluctuating power demands. This paper describes the low-temperature Argonne partial-oxidation reformer (APOR) developed for this application. The APOR is a rapid-start, compact, lightweight, catalytic device that is efficient and dynamically responsive. The reformer is easily controlled by varying the feed rates of the fuel, water, and air to satisfy the rapidly changing system power demands during the vehicle`s driving cycle.

  12. Method and apparatus for determining peak temperature along an optical fiber

    DOEpatents

    Fox, Richard J.

    1985-01-01

    The invention relates to a new method and new apparatus for determining the hottest temperature or the coldest temperature prevailing along the length of an optical-fiber light guide. The invention is conducted with an optical fiber capable of supporting multidiode propagation of light and comprising a core, a cladding, and a jacket. The core is selected to have (1) a higher refractive index than the core and the cladding and (2) a relatively high negative temperature coefficient of refractive index. A light beam capable of establishing substantially single-mode propagation in the core is launched into an end thereof at an angle to the axis. The angle is increased to effect the onset of light refraction from the core into the cladding. The value of the launch angle corresponding to the onset is determined and then used to establish the refractive index of the core corresponding to the onset angle. The maximum temperature prevailing along the fiber then is determined from the (1) refractive index so determined and (2) the temperature coefficient of refractive index for the core. The invention is based on the finding that the launch angle corresponding to the onset of refraction into the cladding is uniquely determined by the maximum value of the ratio of the core refractive index to the cladding refractive index, which maximum occurs at the hottest point along the fiber.

  13. Method and apparatus for determining peak temperature along an optical fiber

    DOEpatents

    Fox, R.J.

    1982-07-29

    The invention relates to a new method and new apparatus for determining the hottest temperature or the coldest temperature prevailing along the length of an optical-fiber light guide. The invention is conducted with an optical fiber capable of supporting multidiode propagation of light and comprising a core, a cladding, and a jacket. The core is selected to have (1) a higher refractive index than the core and the cladding and (2) a relatively high negative temperature coefficient of refractive index. A light beam capable of establishing substantially single-mode propagation in the core is launched into an end thereof at an angle to the axis. The angle is increased to effect the onset of light fraction from the core into the cladding. The value of the launch angle corresponding to the onset is determined and then used to establish the refractive index of the core corresponding to the onset angle. The maximum temperature prevailing along the fiber then is determined from the (1) refractive index so determined and (2) the temperature coefficient of refractive index for the core. The invention is based on the finding that the launch angle corresponding to the onset of refraction into the cladding is uniquely determined by the maximum value of the ratio of the core refractive index to the cladding refractive index, which maximum occurs at the hottest point along the fiber.

  14. Advanced Anodes for High-Temperature Fuel Cells

    SciTech Connect

    Atkinson, Alan; Barnett, Scott A.; Gorte, Raymond J.; Irvine, John T.; McEvoy, Augustin J.; Mogensen, Mogens; Singhal, Subhash C.; Vohs, John M.

    2004-01-04

    Fuel cells will undoubtedly find widespread use in this new millenium in the conversion of chemical to electrical energy, as they offer very high efficiencies and have unique scalability in electricity-generation applications. The solid-oxide fuel cell (SOFC) is one of the most exciting of these energy technologies; it is an all-ceramic device that operates at temperatures in the range 500-1000 C. The SOFC offers certain advantages over lower temperature fuel cells, notably its ability to use carbon monoxide as a fuel rather than being poisoned by it, and the availability of high-grade exhaust heat for combined heat and power, or combined cycle gas-turbine applications. Although cost is clearly the most important barrier to widespread SOFC implementation, perhaps the most important technical barriers currently being addressed relate to the electrodes, particularly the fuel electrode or anode. In terms of mitigating global warming, the ability of the SOFC to use commonly available fuels at high efficiency promises an effective and early reduction in carbon dioxide emissions and,hence, is one of the lead new technologies for improving the environment. Here, we discuss recent developments of SOFC fuel electrodes that will enable the better use of readily available fuels.

  15. Advanced anodes for high-temperature fuel cells.

    PubMed

    Atkinson, A; Barnett, S; Gorte, R J; Irvine, J T S; McEvoy, A J; Mogensen, M; Singhal, S C; Vohs, J

    2004-01-01

    Fuel cells will undoubtedly find widespread use in this new millennium in the conversion of chemical to electrical energy, as they offer very high efficiencies and have unique scalability in electricity-generation applications. The solid-oxide fuel cell (SOFC) is one of the most exciting of these energy technologies; it is an all-ceramic device that operates at temperatures in the range 500-1,000 degrees C. The SOFC offers certain advantages over lower temperature fuel cells, notably its ability to use carbon monoxide as a fuel rather than being poisoned by it, and the availability of high-grade exhaust heat for combined heat and power, or combined cycle gas-turbine applications. Although cost is clearly the most important barrier to widespread SOFC implementation, perhaps the most important technical barriers currently being addressed relate to the electrodes, particularly the fuel electrode or anode. In terms of mitigating global warming, the ability of the SOFC to use commonly available fuels at high efficiency, promises an effective and early reduction in carbon dioxide emissions, and hence is one of the lead new technologies for improving the environment. Here, we discuss recent developments of SOFC fuel electrodes that will enable the better use of readily available fuels. PMID:14704781

  16. 40 CFR 1065.120 - Fuel properties and fuel temperature and pressure.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 34 2013-07-01 2013-07-01 false Fuel properties and fuel temperature and pressure. 1065.120 Section 1065.120 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Equipment Specifications § 1065.120...

  17. 40 CFR 1065.120 - Fuel properties and fuel temperature and pressure.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 34 2012-07-01 2012-07-01 false Fuel properties and fuel temperature and pressure. 1065.120 Section 1065.120 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Equipment Specifications § 1065.120...

  18. 40 CFR 1065.120 - Fuel properties and fuel temperature and pressure.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 33 2014-07-01 2014-07-01 false Fuel properties and fuel temperature and pressure. 1065.120 Section 1065.120 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Equipment Specifications § 1065.120...

  19. 40 CFR 1065.120 - Fuel properties and fuel temperature and pressure.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 33 2011-07-01 2011-07-01 false Fuel properties and fuel temperature and pressure. 1065.120 Section 1065.120 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Equipment Specifications § 1065.120...

  20. 40 CFR 1065.120 - Fuel properties and fuel temperature and pressure.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 32 2010-07-01 2010-07-01 false Fuel properties and fuel temperature and pressure. 1065.120 Section 1065.120 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Equipment Specifications § 1065.120...

  1. Fuel temperature reactivity coefficient calculation by Monte Carlo perturbation techniques

    SciTech Connect

    Shim, H. J.; Kim, C. H.

    2013-07-01

    We present an efficient method to estimate the fuel temperature reactivity coefficient (FTC) by the Monte Carlo adjoint-weighted correlated sampling method. In this method, a fuel temperature change is regarded as variations of the microscopic cross sections and the temperature in the free gas model which is adopted to correct the asymptotic double differential scattering kernel. The effectiveness of the new method is examined through the continuous energy MC neutronics calculations for PWR pin cell problems. The isotope-wise and reaction-type-wise contributions to the FTCs are investigated for two free gas models - the constant scattering cross section model and the exact model. It is shown that the proposed method can efficiently predict the reactivity change due to the fuel temperature variation. (authors)

  2. Materials for Intermediate-Temperature Solid-Oxide Fuel Cells

    NASA Astrophysics Data System (ADS)

    Kilner, John A.; Burriel, Mónica

    2014-07-01

    Solid-oxide fuel cells are devices for the efficient conversion of chemical energy to electrical energy and heat. Research efforts are currently addressed toward the optimization of cells operating at temperatures in the region of 600°C, known as intermediate-temperature solid-oxide fuel cells, for which materials requirements are very stringent. In addition to the requirements of mechanical and chemical compatibility, the materials must show a high degree of oxide ion mobility and electrochemical activity at this low temperature. Here we mainly examine the criteria for the development of two key components of intermediate-temperature solid-oxide fuel cells: the electrolyte and the cathode. We limit the discussion to novel approaches to materials optimization and focus on the fluorite oxide for electrolytes, principally those based on ceria and zirconia, and on perovskites and perovskite-related families in the case of cathodes.

  3. Temperature characteristics for PTC material heating diesel fuel

    NASA Astrophysics Data System (ADS)

    Gu, Lefeng; Li, Xiaolu; Wang, Jun; Li, Ying; Li, Ming

    2010-08-01

    This paper gives a way which utilizes the PTC (Positive Temperature Coefficient) material to preheat diesel fuel in the injector in order to improve the cold starting and emissions of engine. A new injector is also designed. In order to understand the preheating process in this new injector, a dynamic temperature testing system combined with the MSP430F149 data acquisition system is developed for PTC material heating diesel fuel. Especially, the corresponding software and hardware circuits are explained. The temperature of diesel fuel preheating by PTC ceramics is measured under different voltages and distances, which Curie point is 75 °C. Diesel fuel is heated by self-defined temperature around the Curie point of PTC ceramics. The diesel fuel temperature rises rapidly in 2 minutes of the beginning, then can reach 60 °C within 5 minutes as its distance is 5mm away from the surface of PTC ceramics. However, there are a lot of fundamental studies and technology to be resolved in order to apply PTC material in the injector successfully.

  4. Comment on "Origin of low-temperature shoulder internal friction peak of Snoek-Köster peak in a medium carbon high alloyed steel" by Lu et al. [Solid State Communications 195 (2014) 31

    NASA Astrophysics Data System (ADS)

    Hoyos, J. J.; Mari, D.

    2016-01-01

    We want to discuss the interpretation of low-temperature shoulder internal friction peak of Snoek-Köster peak (LTS-SK). Lu et al. (2015) [1] attributed it to the interaction between the carbon atoms and twin boundaries in martensite. Nevertheless, the decrease of the amplitude of LTS-SK peak due to carbon segregation is correlated with the interstitial carbon content in solid solution in martensite (Hoyos et al., 2015 [2]). Therefore, this peak can also be attributed to the presence of an internal friction athermal background, which is proportional to the concentration of interstitial carbon in solid solution (Tkalcec et al., 2015 [2,3]). In addition, they used an alloyed steel, in which ε carbide precipitated above of the LTS-SK peak temperature. As this behavior cannot be generalized for carbon and high alloyed steels, the carbide precipitates could made an additional contribution to the internal friction.

  5. Weekly cycles in peak time temperatures and urban heat island intensity

    NASA Astrophysics Data System (ADS)

    Earl, Nick; Simmonds, Ian; Tapper, Nigel

    2016-07-01

    Regular diurnal and weekly cycles (WCs) in temperature provide valuable insights into the consequences of anthropogenic activity on the urban environment. Different locations experience a range of identified WCs and have very different structures. Two important sources of urban heat are those associated with the effect of large urban structures on the radiation budget and energy storage and those from the heat generated as a consequence of anthropogenic activity. The former forcing will remain relatively constant, but a WC will appear in the latter. WCs for specific times of day and the urban heat island (UHI) have not been analysed heretofore. We use three-hourly surface (2 m) temperature data to analyse the WCs of seven major Australian cities at different times of day and to determine to what extent one of our major city’s (Melbourne) UHI exhibits a WC. We show that the WC of temperature in major cities differs according to the time of day and that the UHI intensity of Melbourne is affected on a WC. This provides crucial information that can contribute toward the push for healthier urban environments in the face of a more extreme climate.

  6. Measurement of the D-D fusion neutron energy spectrum and variation of the peak width with plasma ion temperature

    NASA Astrophysics Data System (ADS)

    Fisher, W. A.; Chen, S. H.; Gwinn, D.; Parker, R. R.

    1983-11-01

    We report a set of neutron spectrum measurements made at the Alcator-C tokamak under Ohmic-heating conditions. It has been found that the width of the D-D fusion neutron peak increases with the plasma ion temperature consistent with the theoretical prediction. In particular, the neutron spectra resulting from the sum of many plasma discharges with ion temperatures of 780 and 1050 eV have been obtained. The width for the 780-eV case is 64+ 9-11 keV and that of the 1050-eV case, 81+10-14 keV (full width at half maximum), corresponding to ion temperatures of 740 and 1190 eV, respectively.

  7. Li zoning in zircon as a potential geospeedometer and peak temperature indicator

    NASA Astrophysics Data System (ADS)

    Trail, Dustin; Cherniak, Daniele J.; Watson, E. Bruce; Harrison, T. Mark; Weiss, Benjamin P.; Szumila, Ian

    2016-03-01

    Zircon Li concentrations and δ7Li values may potentially trace crustal recycling because continental and mantle-derived zircons yield distinct values. The usefulness of these differences may depend upon the retentivity of zircon to Li concentrations and isotopic ratios. Given the relatively high Li diffusivities measured by Cherniak and Watson (Contrib Mineral Petrol 160: 383-390, 2010), we sought to discover the scenarios under which Li mobility might be inhibited by charge-compensating cations. Toward this end, we conducted "in" diffusion experiments in which Li depth profiles of synthetic Lu-doped, P-doped, and undoped zircon were determined by nuclear reaction analysis. In separate experiments, Li was ion-implanted at depth within polished natural zircon slabs to form a Gaussian Li concentration profile. Diffusively relaxed concentration profiles were measured after heating the slabs to determine diffusivities. In all experiments, which ranged from 920 to 650 °C, calculated diffusivities are in agreement with a previously established Arrhenius relationship calibrated on trace-element-poor Mud Tank zircon. Our revised Arrhenius relationship that includes both datasets is: D_{Li} = 9.60 × 10^{ - 7} exp [ {{ - 278 ± 8{{kJ}/{mol}^{ - 1} }}{RT}} ]{m}^{ 2} {{s}}^{ - 1} We also observed that synthetic sector-zoned zircon exhibits near-step-function Li concentration profiles across sectors that correlate with changes in the rare earth element (REE) and P concentrations. This allowed us to examine how Li diffusion might couple with REE diffusion in a manner different than that described above. In particular, re-heating these grains revealed significant Li migration, but no detectable migration of the rare earth elements. Thus, unlike most elements in zircon which are not mobile at the micrometer scale under most time-temperature paths in the crust, Li zoning, relaxation of zoning, or lack of zoning altogether could be used to reveal time-temperature information

  8. Formation of monitoring and evening electron temperature peaks in the low latitude F region during 19-21 March 1988

    NASA Astrophysics Data System (ADS)

    Pavlov, A. V.; Fukao, S.; Kawamura, S.

    A comparison between the election, T_e, and ion, T_i, temperatures measured by the middle and upper atmosphere (MU) radar Shigaraki (34.85° N, 136.10° E, Japan) and those produced by the model of the ionosphere and plasmasphere is presented for 19-21 March 1988. We compare the modeled NmF2 and hmF2 with those observed bz the Akita, Kokubunji, Yamagawa,Okinawa, Chung-Li, Manila, Vanimo, and Darwin sounders and by the MU radar during the the 19-21 March 1988 geomagnetically quiet time period near 201° geomagnetic longitude. The variations of T_e are characterized by morning and evening peaks over the Darwin Yamagawa, Kokubunji and Akita ionosonde stations and over the MU radar while the model produces morning and daytime peaks in T_e above the Vanimo, Manila, Chung-Li, and Okinawa, ionosonde stations. There is a rapid heating of daytime electrons by photoelectrons, and the difference between T_e and T_i is increased after sunrise because the night-time electron density, N_e, is less than that by day, and the resulting electron cooling is less than that by day. After the abrupt morning increase, T_e decreases due to the electron cooling increase caused by the increase in N_e. We found that the night-time downward ExB drift causes the decrease in NmF2 before sunrise and the resulting increase in the magnitude, of the T_e morning peak. This plasma drift becomes more effective in lowering N_e with lowering the geomagnetic latitude, ϕ, i. e. the decrease in |ϕ| leads to the decrease in the night-time N_e before sunrise and the resulting increase in the magnitude of the morning T_e peak. The effect of the plasma drift, W, due to the neutral wind on the formation of the morning T_e peak is decreased with lowering ϕ. The increase in |ϕ| leads to the increase of the effect to the night-time W on N_e, the increase in the night-time N_e before sunrise, and the resulting decrease in the morning T_e peak, created by an evening N_e decrease, becomes strong. The decrease in

  9. High temperature solid oxide fuel development activities

    SciTech Connect

    Ray, E.R.

    1993-11-01

    This paper presents an overview of the Westinghouse tubular SOFC development activities and current program status. Goal is to develop a cell that can operate for 50,000 to 100,000 h. Test results are presented for multiple single cell tests which have now successfully exceeded 40,000 hours of continuous power operation at temperature. Two 25-kW SOFC customer tests units were delivered in 1992; a 20-kW SOFC system is bein manufactured and will be operated by Southern California Edison in 1995. Megawatt class generators are being developed.

  10. Platinum-based nanocomposite electrodes for low-temperature solid oxide fuel cells with extended lifetime

    NASA Astrophysics Data System (ADS)

    Lee, Yoon Ho; Cho, Gu Young; Chang, Ikwhang; Ji, Sanghoon; Kim, Young Beom; Cha, Suk Won

    2016-03-01

    Due to its high catalytic activity and convenient fabrication procedure that uses physical vapor deposition (PVD), nanofabricated platinum (Pt) is widely used for low temperature operating solid oxide fuel cells (LT-SOFC). However, the poor thermal stability of nanofabricated Pt accelerates cell performance degradation. To solve this problem, we apply a thermal barrier coating and use the dispersion hardening process for the nanofabrication of Pt by sputter device. Through morphological and electrochemical data, GDC modified nano-porous Pt electrodes shows improved performance and thermal stability at the operating temperature of 500 °C. While the peak power density of pure Pt sample is 6.16 mW cm-2 with a performance degradation of 43% in an hour, the peak power density of the GDC modified Pt electrodes are in range of 7.42-7.91 mW cm-2 with a 7-16% of performance degradation.

  11. Gain-guided broad area quantum cascade lasers emitting 23.5 W peak power at room temperature.

    PubMed

    Sergachev, Ilia; Maulini, Richard; Bismuto, Alfredo; Blaser, Stephane; Gresch, Tobias; Muller, Antoine

    2016-08-22

    We report gain-guided broad area quantum cascade lasers at 4.55 μm. The devices were processed in a buried heterostructure configuration with a current injector section much narrower than the active region. They demonstrate 23.5 W peak power at a temperature of 20°C and duty cycle of 1%, while their far field consists of a single symmetric lobe centered on the optical axis. These experimental results are supported well by 2D numerical simulations of electric currents and optical fields in a device cross-section. PMID:27557186

  12. Behaviour of irradiated PHWR fuel pins during high temperature heating

    NASA Astrophysics Data System (ADS)

    Viswanathan, U. K.; Unnikrishnan, K.; Mishra, Prerna; Banerjee, Suparna; Anantharaman, S.; Sah, D. N.

    2008-12-01

    Fuel pins removed from an irradiated pressurised heavy water reactor (PHWR) fuel bundle discharged after an extended burn up of 15,000 MWd/tU have been subjected to isothermal heating tests in temperature range 700-1300 °C inside hot-cells. The heating of the fuel pins was carried out using a specially designed remotely operable furnace, which allowed localized heating of about 100 mm length of the fuel pin at one end under flowing argon gas or in air atmosphere. Post-test examination performed in the hot-cells included visual examination, leak testing, dimension measurement and optical and scanning electron microscopy. Fuel pins having internal pressure of 2.1-2.7 MPa due to fission gas release underwent ballooning and micro cracking during heating for 10 min at 800 °C and 900 °C but not at 700 °C. Fuel pin heated at 1300 °C showed complete disruption of cladding in heating zone, due to the embrittlement of the cladding. The examination of fuel from the pin tested at 1300 °C showed presence of large number of bubbles; both intragranular as well as intergranular bubbles. Details of the experiments and the results are presented in this paper.

  13. Temperature and burnup correlated fuel-cladding chemical interaction in U-10ZR metallic fuel

    NASA Astrophysics Data System (ADS)

    Carmack, William J.

    Metallic fuels are proposed for use in advanced sodium cooled fast reactors and provide a number of advantages over other fuel types considering their fabricability, performance, recyclability, and safety. Resistance to cladding "breach" and subsequent release of fission products and fuel constituents to the nuclear power plant primary coolant system is a key performance parameter for a nuclear fuel system. In metallic fuel, FCCI weakens the cladding, especially at high power-high temperature operation, contributing to fuel pin breach. Empirical relationships for FCCI have been developed from a large body of data collected from in-pile (EBR-II) and out-of-pile experiments [1]. However, these relationships are unreliable in predicting FCCI outside the range of EBR-II experimental data. This dissertation examines new FCCI data extracted from the MFF-series of prototypic length metallic fuel irradiations performed in the Fast Flux Test Facility (FFTF). The fuel in these assemblies operated a temperature and burnup conditions similar to that in EBR-II but with axial fuel height three times longer than EBR-II experiments. Comparing FCCI formation data from FFTF and EBR-II provides new insight into FCCI formation kinetics. A model is developed combining both production and diffusion of lanthanides to the fuel-cladding interface and subsequent reaction with the cladding. The model allows these phenomena to be influenced by fuel burnup (lanthanide concentrations) and operating temperature. Parameters in the model are adjusted to reproduce measured FCCI layer thicknesses from EBR-II and FFTF. The model predicts that, under appropriate conditions, rate of FCCI formation can be controlled by either fission product transport or by the reaction rate of the interaction species at the fuel-cladding interface. This dissertation will help forward the design of metallic fuel systems for advanced sodium cooled fast reactors by allowing the prediction of FCCI layer formation in full

  14. Handling Temperature Bursts Reaching 464°C: Different Microbial Strategies in the Sisters Peak Hydrothermal Chimney

    PubMed Central

    Kurtz, Stefan; LaRoche, Julie

    2014-01-01

    The active venting Sisters Peak (SP) chimney on the Mid-Atlantic Ridge holds the current temperature record for the hottest ever measured hydrothermal fluids (400°C, accompanied by sudden temperature bursts reaching 464°C). Given the unprecedented temperature regime, we investigated the biome of this chimney with a focus on special microbial adaptations for thermal tolerance. The SP metagenome reveals considerable differences in the taxonomic composition from those of other hydrothermal vent and subsurface samples; these could be better explained by temperature than by other available abiotic parameters. The most common species to which SP genes were assigned were thermophilic Aciduliprofundum sp. strain MAR08-339 (11.8%), Hippea maritima (3.8%), Caldisericum exile (1.5%), and Caminibacter mediatlanticus (1.4%) as well as to the mesophilic Niastella koreensis (2.8%). A statistical analysis of associations between taxonomic and functional gene assignments revealed specific overrepresented functional categories: for Aciduliprofundum, protein biosynthesis, nucleotide metabolism, and energy metabolism genes; for Hippea and Caminibacter, cell motility and/or DNA replication and repair system genes; and for Niastella, cell wall and membrane biogenesis genes. Cultured representatives of these organisms inhabit different thermal niches; i.e., Aciduliprofundum has an optimal growth temperature of 70°C, Hippea and Caminibacter have optimal growth temperatures around 55°C, and Niastella grows between 10 and 37°C. Therefore, we posit that the different enrichment profiles of functional categories reflect distinct microbial strategies to deal with the different impacts of the local sudden temperature bursts in disparate regions of the chimney. PMID:24837379

  15. Improvements to the RELAP5/MOD3 reflood model and uncertainty quantification of reflood peak clad temperature

    SciTech Connect

    Chung, Bub Dong; Lee, Young Lee; Park, Chan Eok; Lee, Sang Yong

    1996-10-01

    Assessment of the original REAP/N4OD3.1 code against the FLECHT SEASET series of experiments has identified some weaknesses of the reflood model, such as the lack of a quenching temperature model, the shortcoming of the Chen transition boiling model, and the incorrect prediction of droplet size and interfacial heat transfer. Also, high temperature spikes during the reflood calculation resulted in high steam flow oscillation and liquid carryover. An effort had been made to improve the code with respect to the above weakness, and the necessary model for the wall heat transfer package and the numerical scheme had been modified. Some important FLECHT-SEASET experiments were assessed using the improved version and standard version. The result from the improved REAP/MOD3.1 shows the weaknesses of REAP/N4OD3.1 were much improved when compared to the standard MOD3.1 code. The prediction of void profile and cladding temperature agreed better with test data, especially for the gravity feed test. The scatter diagram of peak cladding temperatures (PCTs) is made from the comparison of all the calculated PCTs and the corresponding experimental values. The deviation between experimental and calculated PCTs were calculated for 2793 data points. The deviations are shown to be normally distributed, and used to quantify statistically the PCT uncertainty of the code. The upper limit of PCT uncertainty at 95% confidence level is evaluated to be about 99K.

  16. Immobilization of imidazole moieties in polymer electrolyte composite membrane for elevated temperature fuel cells

    NASA Astrophysics Data System (ADS)

    Li, Ke; Zhou, Bei; Ye, Gongbo; Pan, Mu; Zhang, Haining

    2015-12-01

    Development of membrane electrolyte with reasonable proton conductivity at elevated temperature without external humidification is essential for practical applications of elevated temperature proton exchange membrane fuel cells. Herein, a novel polymer electrolyte composite membrane using imidazole as anhydrous proton carriers for elevated temperature fuel cells is investigated. The imidazole moieties are immobilized inside the Nafion/poly(tetrafluoroethylene) (PTFE) composite membrane through in situ formation of imidazole functionalized silica nanoparticles in Nafion dispersion. The thus-formed membrane exhibits strong Coulombic interaction between negatively charged sulfonic acid groups of Nafion and protonated imidazole moieties, leading to an anhydrous proton conductivity of 0.018 S cm-1 at 180 °C. With the introduction of PTFE matrix, the mechanical strength of the membrane is greatly improved. The peak power density of a single cell assembled from the hybrid membrane is observed to be 130 mW cm-2 under 350 mA cm-2 at 110 °C without external humidification and it remains stable for 20 h continuous operation. The obtained results demonstrate that the developed composite membranes could be utilized as promising membrane electrolytes for elevated temperature fuel cells.

  17. Carbon dioxide separation from high temperature fuel cell power plants

    NASA Astrophysics Data System (ADS)

    Campanari, Stefano

    High temperature fuel cell technologies, solid oxide fuel cells (SOFCs) and molten carbonate fuel cells (MCFCs), are considered for their potential application to carbon dioxide emission control. Both technologies feature electrochemical oxidisation of natural gas reformed fuels, avoiding the mixture of air and fuel flows and dilution with nitrogen and oxygen of the oxidised products; a preliminary analysis shows how the different mechanism of ion transport attributes each technology a specific advantage for the application to CO 2 separation. The paper then compares in the first part the most promising cycle configurations based on high efficiency integrated SOFC/gas turbine "hybrid" cycles, where CO 2 is separated with absorption systems or with the eventual adoption of a second SOFC module acting as an "afterburner". The second part of the paper discusses how a MCFC plant could be "retrofitted" to a conventional fossil-fuel power station, giving the possibility of draining the majority of CO 2 from the stack exhaust while keeping the overall cycle electrical efficiency approximately unchanged.

  18. Engineered Nanostructured MEA Technology for Low Temperature Fuel Cells

    SciTech Connect

    Zhu, Yimin

    2009-07-16

    The objective of this project is to develop a novel catalyst support technology based on unique engineered nanostructures for low temperature fuel cells which: (1) Achieves high catalyst activity and performance; (2) Improves catalyst durability over current technologies; and (3) Reduces catalyst cost. This project is directed at the development of durable catalysts supported by novel support that improves the catalyst utilization and hence reduce the catalyst loading. This project will develop a solid fundamental knowledge base necessary for the synthetic effort while at the same time demonstrating the catalyst advantages in Direct Methanol Fuel Cells (DMFCs).

  19. In-flight and simulated aircraft fuel temperature measurements

    NASA Technical Reports Server (NTRS)

    Svehla, Roger A.

    1990-01-01

    Fuel tank measurements from ten flights of an L1011 commercial aircraft are reported for the first time. The flights were conducted from 1981 to 1983. A thermocouple rake was installed in an inboard wing tank and another in an outboard tank. During the test periods of either 2 or 5 hr, at altitudes of 10,700 m (35,000 ft) or higher, either the inboard or the outboard tank remained full. Fuel temperature profiles generally developed in the expected manner. The bulk fuel was mixed by natural convection to a nearly uniform temperature, especially in the outboard tank, and a gradient existed at the bottom conduction zone. The data indicated that when full, the upper surface of the inboard tank was wetted and the outboard tank was unwetted. Companion NASA Lewis Research Center tests were conducted in a 0.20 cubic meter (52 gal) tank simulator of the outboard tank, chilled on the top and bottom, and insulated on the sides. Even though the simulator tank had no internal components corresponding to the wing tank, temperatures agreed with the flight measurements for wetted upper surface conditions, but not for unwetted conditions. It was concluded that if boundary conditions are carefully controlled, simulators are a useful way of evaluating actual flight temperatures.

  20. High performance internal reforming unit for high temperature fuel cells

    DOEpatents

    Ma, Zhiwen; Venkataraman, Ramakrishnan; Novacco, Lawrence J.

    2008-10-07

    A fuel reformer having an enclosure with first and second opposing surfaces, a sidewall connecting the first and second opposing surfaces and an inlet port and an outlet port in the sidewall. A plate assembly supporting a catalyst and baffles are also disposed in the enclosure. A main baffle extends into the enclosure from a point of the sidewall between the inlet and outlet ports. The main baffle cooperates with the enclosure and the plate assembly to establish a path for the flow of fuel gas through the reformer from the inlet port to the outlet port. At least a first directing baffle extends in the enclosure from one of the sidewall and the main baffle and cooperates with the plate assembly and the enclosure to alter the gas flow path. Desired graded catalyst loading pattern has been defined for optimized thermal management for the internal reforming high temperature fuel cells so as to achieve high cell performance.

  1. Gasoline Ultra Efficient Fuel Vehicle with Advanced Low Temperature Combustion

    SciTech Connect

    Confer, Keith

    2014-09-30

    The objective of this program was to develop, implement and demonstrate fuel consumption reduction technologies which are focused on reduction of friction and parasitic losses and on the improvement of thermal efficiency from in-cylinder combustion. The program was executed in two phases. The conclusion of each phase was marked by an on-vehicle technology demonstration. Phase I concentrated on short term goals to achieve technologies to reduce friction and parasitic losses. The duration of Phase I was approximately two years and the target fuel economy improvement over the baseline was 20% for the Phase I demonstration. Phase II was focused on the development and demonstration of a breakthrough low temperature combustion process called Gasoline Direct- Injection Compression Ignition (GDCI). The duration of Phase II was approximately four years and the targeted fuel economy improvement was 35% over the baseline for the Phase II demonstration vehicle. The targeted tailpipe emissions for this demonstration were Tier 2 Bin 2 emissions standards.

  2. High temperature dilatometry of simulated oxide nuclear fuel

    NASA Astrophysics Data System (ADS)

    Tenishev, A. V.; Baranov, V. G.; Kuzmin, R. S.; Pokrovskiy, S. A.

    2016-04-01

    High temperature dilatometry of model systems based on uranium dioxide with additives of burnable neutron absorbers both as Gd2O3 and as AlGdO3, and fission products simulators (FPS) was performed. It shown that in some cases instead of high temperature samples shrinkage there is a sharp transition to the expansion, which is associated with an increase of the samples volume due to the formation of liquid phases. The beginning of a complex composition eutectic melting starts at temperatures from 1950 to 2250 °C in the uranium dioxide samples containing significant amounts of Al, Gd, and FPS. Thus, in the analysis of oxide nuclear fuel behavior at high temperatures should be considered that the formation of liquid phases is possible at a temperature of 1000 °C lower than a melting point of pure stoichiometric uranium dioxide if its initial composition became more complex.

  3. Peak-Seeking Control For Reduced Fuel Consumption: Flight-Test Results For The Full-Scale Advanced Systems Testbed FA-18 Airplane

    NASA Technical Reports Server (NTRS)

    Brown, Nelson

    2013-01-01

    A peak-seeking control algorithm for real-time trim optimization for reduced fuel consumption has been developed by researchers at the National Aeronautics and Space Administration (NASA) Dryden Flight Research Center to address the goals of the NASA Environmentally Responsible Aviation project to reduce fuel burn and emissions. The peak-seeking control algorithm is based on a steepest-descent algorithm using a time-varying Kalman filter to estimate the gradient of a performance function of fuel flow versus control surface positions. In real-time operation, deflections of symmetric ailerons, trailing-edge flaps, and leading-edge flaps of an F/A-18 airplane are used for optimization of fuel flow. Results from six research flights are presented herein. The optimization algorithm found a trim configuration that required approximately 3 percent less fuel flow than the baseline trim at the same flight condition. This presentation also focuses on the design of the flight experiment and the practical challenges of conducting the experiment.

  4. Assessment of temperature peaks reached during a wildfire. An approach using X-ray diffraction and differential thermal analysis

    NASA Astrophysics Data System (ADS)

    Jiménez-González, Marco A.; Jordán, Antonio; Zavala, Lorena M.; Mataix-Solera, Jorge; Bárcenas-Moreno, Gema; Jiménez-Morillo, Nicasio T.; Bellinfante, Nicolás

    2014-05-01

    1. INTRODUCTION Wildfires may induce important chemical and physical changes in soils, including changes in the soil composition, mineralogical changes, soil water repellency, aggregate stability or textural changes (Bodí et al., 2013; Granged et al., 2011a, 2011b, 2011c; Jordán et al., 2011, 2013; Mataix-Solera et al., 2011). As these changes usually occur after threshold temperature peaks, the assessment of these helps to explain many of the processes occurring during burning and in the postfire (Pereira et al., 2012, 2013; Shakesby, 2011). In July 2011, a wildfire burnt a pine forested area (50 ha) in Gorga (Alicante, SW Spain), approximately at 38° 44.3' N and 0° 20.7' W. Main soil type is Lithic Xerorthent developed from limestone. The study of mineralogical changes in soil after a wildfire should help to assess fire temperature peaks reached during burning. In order to study the impact of fire temperature on mineralogical changes and determine temperature peaks during burning, burnt soil plots under shrubland were randomly collected (0-5 cm deep). Control samples from adjacent unburnt areas were also collected for control. 2. METHODS Soil samples were ground using an agate mortar and then sieved (< 0.002mm) and analyzed by X-ray diffraction (XRD). XRD was conducted on a Bruker (model D8 advance A25) powder θ:θ diffractometer, which uses a Cu anticathode (40KV, 30mA), Ni filter in the diffracted bean and lineal detector. Powder samples were scanned from 3 to 70° 2θ, using a step size of 0.015° 2θ and a scan speed of 0.15° 2θ s-1. Mineralogical phase identification and quantification of minerals was carried out with XPowder. In order to study other possible reaction in burnt soil, unburnt soil samples were exposed to temperatures of 300, 500 and 700 °C in a Mufla furnace during 20 minutes. Unburnt control and treated samples were analyzed by differential thermal analysis (DTA) and thermogravimetric analysis (TG). 3. RESULTS Diffractograms show that

  5. Temperature and flow measurements on near-freezing aviation fuels in a wing-tank model

    NASA Technical Reports Server (NTRS)

    Friedman, R.; Stockemer, F. J.

    1980-01-01

    Freezing behavior, pumpability, and temperature profiles for aviation turbine fuels were measured in a 190-liter tank, to simulate internal temperature gradients encountered in commercial airplane wing tanks. Two low-temperature situations were observed. Where the bulk of the fuel is above the specification freezing point, pumpout of the fuel removes all fuel except a layer adhering to the bottom chilled surfaces, and the unpumpable fraction depends on the fuel temperature near these surfaces. Where the bulk of the fuel is at or below the freezing point, pumpout ceases when solids block the pump inlet, and the unpumpable fraction depends on the overall average temperature.

  6. High Temperature Polymers for use in Fuel Cells

    NASA Technical Reports Server (NTRS)

    Peplowski, Katherine M.

    2004-01-01

    NASA Glenn Research Center (GRC) is currently working on polymers for fuel cell and lithium battery applications. The desire for more efficient, higher power density, and a lower environmental impact power sources has led to interest in proton exchanges membrane fuels cells (PEMFC) and lithium batteries. A PEMFC has many advantages as a power source. The fuel cell uses oxygen and hydrogen as reactants. The resulting products are electricity, heat, and water. The PEMFC consists of electrodes with a catalyst, and an electrolyte. The electrolyte is an ion-conducting polymer that transports protons from the anode to the cathode. Typically, a PEMFC is operated at a temperature of about 80 C. There is intense interest in developing a fuel cell membrane that can operate at higher temperatures in the range of 80 C- 120 C. Operating the he1 cell at higher temperatures increases the kinetics of the fuel cell reaction as well as decreasing the susceptibility of the catalyst to be poisoned by impurities. Currently, Nafion made by Dupont is the most widely used polymer membrane in PEMFC. Nafion does not function well above 80 C due to a significant decrease in the conductivity of the membrane from a loss of hydration. In addition to the loss of conductivity at high temperatures, the long term stability and relatively high cost of Nafion have stimulated many researches to find a substitute for Nafion. Lithium ion batteries are popular for use in portable electronic devices, such as laptop computers and mobile phones. The high power density of lithium batteries makes them ideal for the high power demand of today s advanced electronics. NASA is developing a solid polymer electrolyte that can be used for lithium batteries. Solid polymer electrolytes have many advantages over the current gel or liquid based systems that are used currently. Among these advantages are the potential for increased power density and design flexibility. Automobiles, computers, and cell phones require

  7. Improving low temperature properties of synthetic diesel fuels derived from oil shale. Alternative fuels utilization program

    SciTech Connect

    Frankenfeld, J.W.; Taylor, W.F.

    1980-11-01

    The ability of additives to improve the cold flow properties of shale oil derived fuels boiling in the diesel fuel range was evaluated. Because a commercial shale oil industry did not exist to provide actual samples of finished fuels, a representative range of hydroprocessed shale oil fractions was prepared for use in the additive testing work. Crude oil shale from Occidental Shale Company was fractionated to give three liquids in the diesel fuel boiling range. The initial boiling point in each case was 325/sup 0/F (163/sup 0/C). The final boiling points were 640/sup 0/F (338/sup 0/C), 670/sup 0/F (354/sup 0/C) and 700/sup 0/F (371/sup 0/F). Each fraction was hydrotreated to three different severities (800, 1200 and 1500 psi total pressure) over a Shell 324 nickel molybdate on alumina catalyst at 710 to 750/sup 0/F to afford 9 different model fuels. A variety of commercial and experimental additives were evaluated as cold flow improvers in the model fuels at treat levels of 0.04 to 0.4 wt %. Both the standard pour point test (ASTM D97) and a more severe low temperature flow test (LTFT) were employed. Reductions in pour points of up to 70/sup 0/F and improvements in LTFT temperatures up to 16/sup 0/F were achieved. It is concluded that flow improver additives can play an important role in improving the cold flow properties of future synthetic fuels of the diesel type derived from oil shale.

  8. Very High Temperature Reactor (VHTR) Deep Burn Core and Fuel Analysis -- Complete Design Selection for the Pebble Bed Reactor

    SciTech Connect

    B. Boer; A. M. Ougouag

    2010-09-01

    The Deep-Burn (DB) concept focuses on the destruction of transuranic nuclides from used light water reactor fuel. These transuranic nuclides are incorporated into TRISO coated fuel particles and used in gas-cooled reactors with the aim of a fractional fuel burnup of 60 to 70% in fissions per initial metal atom (FIMA). This high performance is expected through the use of multiple recirculation passes of the fuel in pebble form without any physical or chemical changes between passes. In particular, the concept does not call for reprocessing of the fuel between passes. In principle, the DB pebble bed concept employs the same reactor designs as the presently envisioned low-enriched uranium core designs, such as the 400 MWth Pebble Bed Modular Reactor (PBMR-400). Although it has been shown in the previous Fiscal Year (2009) that a PuO2 fueled pebble bed reactor concept is viable, achieving a high fuel burnup, while remaining within safety-imposed prescribed operational limits for fuel temperature, power peaking and temperature reactivity feedback coefficients for the entire temperature range, is challenging. The presence of the isotopes 239-Pu, 240-Pu and 241-Pu that have resonances in the thermal energy range significantly modifies the neutron thermal energy spectrum as compared to a ”standard,” UO2-fueled core. Therefore, the DB pebble bed core exhibits a relatively hard neutron energy spectrum. However, regions within the pebble bed that are near the graphite reflectors experience a locally softer spectrum. This can lead to power and temperature peaking in these regions. Furthermore, a shift of the thermal energy spectrum with increasing temperature can lead to increased absorption in the resonances of the fissile Pu isotopes. This can lead to a positive temperature reactivity coefficient for the graphite moderator under certain operating conditions. The effort of this task in FY 2010 has focused on the optimization of the core to maximize the pebble discharge

  9. High temperature seals for solid oxide fuel cells

    NASA Astrophysics Data System (ADS)

    Parihar, Shailendra S.

    Solid Oxide Fuel cells (SOFCs) represent a clean and efficient alternative to existing methods of energy production. But, they need hermetic seals to prevent fuel-oxidant mixing within the stack. Glasses are attractive options for fabrication of these high temperature seals but suffer from their inherent brittleness and tend to crack during thermal cycling. In this study, an innovative concept of self-healing glass seals is developed to solve the problem of cracking of glasses in a SOFC seal. Rationale behind this concept is that a glass of suitable viscosity characteristics can flow and heal cracks at SOFC operating temperatures and thus can provide seals which can self-repair. A novel method, based on in-situ video imaging of cracks on the glass surface during high temperature treatment is developed and used to select and evaluate the suitability of different glasses for making self-healing seals. Promising glasses are studied experimentally to determine kinetics of healing of Vickers indented cracks at various temperatures. In addition, the effect of crystallization of glass on its healing kinetics is studied. A model is developed for crack healing behavior and is used to validate the experimental data. Studies on Cracks healing and crystallization of glasses showed that glasses with no crystallization tendency show fast crack healing response, whereas glasses which crystallize display sluggish healing. A glass displaying fast healing kinetics and good stability against crystallization is used to fabricate self healing glass seals for SOFCs. Seals fabricated using this glass not only remained hermetic but also maintained their self i healing ability for as long as 3000 hours at 800°C and 300 thermal cycles between room temperature and 800°C. These results clearly indicated that self-healing glasses are promising candidates for SOFC seals. Key words. Solid Oxide Fuel Cells, Glass Seals, Self-Healing Glasses, Seal Leak Testing.

  10. Multifunctional fuel additives derived from aminodiols to improve the low-temperature properties of distillate fuels

    SciTech Connect

    Baillargeon, D.J.; Cardis, A.B.; Heck, D.B.

    1991-03-19

    This patent describes a liquid hydrocarbyl fuel composition comprising a major amount of a combustible liquid hydrocarbon fuel and a minor low-temperature properties improving amount of from about 0.001% to about 10 wt % based on the total weight of the composition of an additive comprising a product of reaction made by reacting comonomers. It comprises: an aminodiol or combination or mixture of aminodiols with a reactive acid/anhydride product alone or in combination with other monomers derived from the reaction of benzophenone tetracarboxylic dianhydride or its acid equivalent.

  11. Nonhumidified intermediate temperature fuel cells using protic ionic liquids.

    PubMed

    Lee, Seung-Yul; Ogawa, Atsushi; Kanno, Michihiro; Nakamoto, Hirofumi; Yasuda, Tomohiro; Watanabe, Masayoshi

    2010-07-21

    In this paper, the characterization of a protic ionic liquid, diethylmethylammonium trifluoromethanesulfonate ([dema][TfO]), as a proton conductor for a fuel cell and the fabrication of a membrane-type fuel cell system using [dema][TfO] under nonhumidified conditions at intermediate temperatures are described in detail. In terms of physicochemical and electrochemical properties, [dema][TfO] exhibits high activity for fuel cell electrode reactions (i.e., the hydrogen oxidation reaction (HOR) and oxygen reduction reaction (ORR)) at a Pt electrode, and the open circuit voltage (OCV) of a liquid fuel cell is 1.03 V at 150 degrees C, as has reported in ref 27. However, diethylmethylammonium bis(trifluoromethane sulfonyl)amide ([dema][NTf(2)]) has relatively low HOR and ORR activity, and thus, the OCV is ca. 0.7 V, although [dema][NTf(2)] and [dema][TfO] have an identical cation ([dema]) and similar thermal and bulk-transport properties. Proton conduction occurs mainly via the vehicle mechanism in [dema][TfO] and the proton transference number (t(+)) is 0.5-0.6. This relatively low t(+) appears to be more disadvantageous for a proton conductor than for other electrolytes such as hydrated sulfonated polymer electrolyte membranes (t(+) = 1.0). However, fast proton-exchange reactions occur between ammonium cations and amines in a model compound. This indicates that the proton-exchange mechanism contributes to the fuel cell system under operation, where deprotonated amines are continuously generated by the cathodic reaction, and that polarization of the cell is avoided. Six-membered sulfonated polyimides in the diethylmethylammonium form exhibit excellent compatibility with [dema][TfO]. The composite membranes can be obtained up to a [dema][TfO] content of 80 wt % and exhibit good thermal stability, high ionic conductivity, and mechanical strength and gas permeation comparable to those of hydrated Nafion. H(2)/O(2) fuel cells prepared using the composite membranes can

  12. Temperature peaking at beginning of breakdown in 2.45 GHz pulsed off-resonance electron cyclotron resonance ion source hydrogen plasma

    SciTech Connect

    Cortazar, O. D.

    2012-10-15

    An experimental study of temperature and density evolution during breakdown in off-resonance ECR hydrogen plasma is presented. Under square 2.45 GHz microwave excitation pulses with a frequency of 50 Hz and relative high microwave power, unexpected transient temperature peaks that reach 18 eV during 20 {mu}s are reported at very beginning of plasma breakdown. Decays of such peaks reach final stable temperatures of 5 eV at flat top microwave excitation pulse. Evidence of interplay between incoming power and duty cycle giving different kind of plasma parameters evolutions engaged to microwave coupling times is observed. Under relative high power conditions where short microwave coupling times are recorded, high temperature peaks are measured. However, for lower incoming powers and longer coupling times, temperature evolves gradually to a higher final temperature without peaking. On the other hand, the early instant where temperature peaks are observed also suggest a possible connection with preglow processes during breakdown in ECRIS plasmas.

  13. Temperature and flow measurements on near-freezing aviation fuels in a wing-tank model

    NASA Technical Reports Server (NTRS)

    Friedman, R.; Stockemer, F. J.

    1980-01-01

    Freezing behavior, pumpability, and temperature profiles for aviation turbine fuels were measured in a 190-liter tank chilled to simulate internal temperature gradients encountered in commercial airplane wing tanks. When the bulk of the fuel was above the specification freezing point, pumpout of the fuel removed all fuel except a layer adhering to the bottom chilled surfaces, and the unpumpable fraction depended on the fuel temperature near these surfaces. When the bulk of the fuel was at or below the freezing point, pumpout ceased when solids blocked the pump inlet, and the unpumpable fraction depended on the overall average temperature.

  14. HIGH-TEMPERATURE TUBULAR SOLID OXIDE FUEL CELL GENERATOR DEVELOPMENT

    SciTech Connect

    S.E. Veyo

    1998-09-01

    During the Westinghouse/USDOE Cooperative Agreement period of November 1, 1990 through November 30, 1997, the Westinghouse solid oxide fuel cell has evolved from a 16 mm diameter, 50 cm length cell with a peak power of 1.27 watts/cm to the 22 mm diameter, 150 cm length dimensions of today's commercial prototype cell with a peak power of 1.40 watts/cm. Accompanying the increase in size and power density was the elimination of an expensive EVD step in the manufacturing process. Demonstrated performance of Westinghouse's tubular SOFC includes a lifetime cell test which ran for a period in excess of 69,000 hours, and a fully integrated 25 kWe-class system field test which operated for over 13,000 hours at 90% availability with less than 2% performance degradation over the entire period. Concluding the agreement period, a 100 kW SOFC system successfully passed its factory acceptance test in October 1997 and was delivered in November to its demonstration site in Westervoort, The Netherlands.

  15. The relation between the bolometric flux and the blackbody temperature at the peak of type II bursts from the Rapid Burster

    NASA Technical Reports Server (NTRS)

    Lubin, Lori M.; Lewin, Walter H. G.; Dotani, Tadayasu; Oosterbroek, Tim; Mitsuda, Kazuhisa; Magnier, Eugene; Van Paradijs, Jan; Van Der Klis, Michiel

    1992-01-01

    During about 6 hr of Ginga observations of the Rapid Burster in August 1988, the source emitted type II bursts with durations between about 3 and about 35 s and with peak fluxes which varied by factors of about 5. The Rapid Burster was active in two bursting modes as defined by Marshall et al. (1979): mode I characterize by a burst energy distribution which is 'double-peaked' and mode II by a distribution which is 'single-peaked'. A study of the relationship between the maximum bolometric burst flux, F(max), and the associated blackbody temperature, Tc, shows that mode I bursts consistently show higher Tc values than bursts of mode II. These results, together with previous work, suggest that the relation between F(max) and Tc is dependent on mode. In mode I the color temperature is approximately independent of the burst peak flux, whereas in mode II the two properties are correlated.

  16. Bio-Fuel Production Assisted with High Temperature Steam Electrolysis

    SciTech Connect

    Grant Hawkes; James O'Brien; Michael McKellar

    2012-06-01

    Two hybrid energy processes that enable production of synthetic liquid fuels that are compatible with the existing conventional liquid transportation fuels infrastructure are presented. Using biomass as a renewable carbon source, and supplemental hydrogen from high-temperature steam electrolysis (HTSE), these two hybrid energy processes have the potential to provide a significant alternative petroleum source that could reduce dependence on imported oil. The first process discusses a hydropyrolysis unit with hydrogen addition from HTSE. Non-food biomass is pyrolyzed and converted to pyrolysis oil. The pyrolysis oil is upgraded with hydrogen addition from HTSE. This addition of hydrogen deoxygenates the pyrolysis oil and increases the pH to a tolerable level for transportation. The final product is synthetic crude that could then be transported to a refinery and input into the already used transportation fuel infrastructure. The second process discusses a process named Bio-Syntrolysis. The Bio-Syntrolysis process combines hydrogen from HTSE with CO from an oxygen-blown biomass gasifier that yields syngas to be used as a feedstock for synthesis of liquid synthetic crude. Conversion of syngas to liquid synthetic crude, using a biomass-based carbon source, expands the application of renewable energy beyond the grid to include transportation fuels. It can also contribute to grid stability associated with non-dispatchable power generation. The use of supplemental hydrogen from HTSE enables greater than 90% utilization of the biomass carbon content which is about 2.5 times higher than carbon utilization associated with traditional cellulosic ethanol production. If the electrical power source needed for HTSE is based on nuclear or renewable energy, the process is carbon neutral. INL has demonstrated improved biomass processing prior to gasification. Recyclable biomass in the form of crop residue or energy crops would serve as the feedstock for this process. A process model

  17. The influence of igneous intrusions on the peak temperatures of host rocks: Finite-time emplacement, evaporation, dehydration, and decarbonation

    NASA Astrophysics Data System (ADS)

    Wang, Dayong; Song, Yongchen; Liu, Yu; Zhao, Minglong; Qi, Tian; Liu, Weiguo

    2012-01-01

    Using a 13-m-thick basic sill and its limestone host rocks of the Permian Irati Formation from the Parana Basin, South America, as an example, this paper presents a numerical investigation based on heat conduction models on the effect of the emplacement mechanism of igneous intrusions, pore-water evaporation, and dehydration and decarbonation of host rocks on the peak temperature ( Tpeak) of host rocks. Our results demonstrate that: (1) the finite-time intrusion mechanism of magma can lower the predicted Tpeak of host rocks by up to 100 °C relative to the instantaneous intrusion mechanism, and although pore-water evaporation together with dehydration and decarbonation reactions can also depress the thermal effect of the sill on its host rocks, the maximum effect of these mechanisms on Tpeak only reaches approximately 50 °C. (2) The effect of pore-water evaporation on Tpeak is obviously greater than that of the dehydration and decarbonation reactions: the former can cause a maximum deviation of 40 °C in the predicted Tpeak, whereas the deviation due to the latter is less than 20 °C. Further, the effect of the dehydration and decarbonation reactions on Tpeak is less than 10 °C if pore-water evaporation is allowed simultaneously in the models and can hence be ignored in thermal modeling. (3) The finite-time intrusion mechanism of magma probably represents the natural condition of the sill. Pore-water evaporation and dehydration and decarbonation of host rocks are also likely to play important roles in lowering the thermal effect of the sill.

  18. An optical gas temperature probe for high temperature fossil fuel process streams

    SciTech Connect

    Bauman, L.E.; Cook, R.L.; Lineberry, J.T.; Litchford, R.J.

    1995-12-31

    Reported here are the results of a feasibility study of a modular optical gas temperature probe for direct measurement of gas temperature in fossil-fueled combustion streams. A probe based upon the spectroscopic technique of line reversal would be superior to currently available gas temperature technology. The study concluded that a modular form of the line reversal optical temperature probe is feasible and, as such. the probe should be a commercially viable product with potential economic benefits from improved monitoring and control of utility furnaces. Such a probe will have the capability of making direct measurements of gas temperature in hot (>1500 K) process streams of coal combustion systems and large-scale power plant facilities.

  19. High-temperature seals for solid oxide fuel cells (SOFC)

    NASA Astrophysics Data System (ADS)

    Singh, Raj N.

    2006-08-01

    A functioning solid oxide fuel-cell (SOFC) may require all types of seals, such as metal-metal, metal-ceramic, and ceramic-ceramic. These seals must function at high temperatures between 600 and 900 °C and in the oxidizing and reducing environments of fuels and air. Among the different types of seals, the metal-metal seals can be readily fabricated using metal joining, soldering, and brazing techniques. However, metal-ceramic and ceramic-ceramic seals require significant research and development because the brittle nature of ceramics/glasses can lead to fracture and loss of seal integrity and functionality. Consequently, any seals involving ceramics/glasses also require significant attention and technology development for reliable SOFC operation. This paper is prepared to primarily address the needs and possible approaches for high-temperature seals for SOFC and seals fabricated using some of these approaches. A new concept of self-healing glass seals is proposed for making seals among material combinations with a significant expansion mismatches.

  20. Spent fuel dry storage technology development: fuel temperature measurements under imposed dry storage conditions (I kW PWR spent fuel assembly)

    SciTech Connect

    Unterzuber, R.; Wright, J.B.

    1980-09-01

    A spent fuel assembly temperature test under imposed dry storage conditions was conducted at the Engine Maintenance Assembly and Disassembly (E-MAD) facility on the Nevada Test Site in support of spent fuel dry storage technology development. This document presents the test data and results obtained from an approximately 1.0 kW decay heat level PWR spent fuel assembly. A spent fuel test apparatus was designed to utilize a representative stainless steel spent fuel canister, a canister lid containing internal temperature instrumentation to measure fuel cladding temperatures, and a carbon steel liner that encloses the canister and lid. Electrical heaters along the liner length, on the lid, and below the canister are used to impose dry storage canister temperature profiles. Temperature instrumentation is provided on the liner and canister. The liner and canister are supported by a test stand in one of the large hot cells (West Process Cell) inside E-MAD. Fuel temperature measurements have been performed using imposed canister temperature profiles from the electrically heated and spent fuel drywell tests being conducted at E-MAD as well as for four constant canister temperature profiles, each with a vacuum, helium and air backfill. Computer models have been utilized in conjunction with the test to predict the thermal response of the fuel cladding. Computer predictions are presented, and they show good agreement with the test data.

  1. Refinements to temperature calculations of spent fuel assemblies when in a stagnant gas environment

    SciTech Connect

    Rhodes, C.A.; Haire, M.J.

    1984-01-01

    Undesirably high temperatures are possible in irradiated fuel assemblies because of the radioactive decay of fission products formed while in the reactor. The COXPRO computer code has been used for some time to calculate temperatures in spent fuel when the fuel is suspended in a stagnant gas environment. This code assumed radiation to be the only mode of heat dissipation within the fuel pin bundle. Refinements have been made to include conduction as well as radiation heat transfer within this code. Comparison of calculated and measured temperatures in four separate and independent tests indicate that maximum fuel assembly temperatures can be predicted to within about 6%. 2 references, 5 figures.

  2. Performance of vapor-fed direct dimethyl ether fuel cell utilizing high temperature polybenzimidazole polymer electrolyte membrane

    NASA Astrophysics Data System (ADS)

    Neutzler, Jay; Qian, Guoqing; Huang, Kevin; Benicewicz, Brian

    2012-10-01

    There is increasing interest in dimethyl ether (DME) as a synthetic fuel. It has present-day relevance and introduces an effective path forward as an energy-dense, low-pressure hydrogen carrier/storage fuel for fuel cells with applications in transportation, stationary, and portable power. Direct reaction DME fuel cells have particular relevance to portable power. This study presents the performance of the vapor-fed direct reaction of DME using high temperature Polybenzimidazole (PBI) Polymer Electrolyte Membrane (PEM). Catalyzed PBI membrane utilized a Pt/Ru black anode and a Pt/C supported cathode. Performance was evaluated from temperatures of 180 °C-210 °C and at pressures from 100 kPa to 300 kPa. A strong performance correlation was observed in this study for these temperatures and pressures. A peak power density of 50 mW cm-2 was achieved at 180 °C without back pressure, whereas, an increase to 129 mW cm-2 was achieved at 210 °C at 300 kPa pressure. The performance of high temperature PBI PEMFCs with direct vapor-fed DME are investigated with emphasis on the critical variables of cell operation; temperature, back pressure, and humidity.

  3. Effect of increased fuel temperature on emissions of oxides of nitrogen from a gas turbine combustor burning ASTM jet-A fuel

    NASA Technical Reports Server (NTRS)

    Marchionna, N. R.

    1974-01-01

    An annular gas turbine combustor was tested with heated ASTM Jet-A fuel to determine the effect of increased fuel temperature on the formation of oxides of nitrogen. Fuel temperature ranged from ambient to 700 K. The NOx emission index increased at a rate of 6 percent per 100 K increase in fuel temperature.

  4. Thermal Analysis of a TREAT Fuel Assembly

    SciTech Connect

    Papadias, Dionissios; Wright, Arthur E.

    2014-07-09

    The objective of this study was to explore options as to reduce peak cladding temperatures despite an increase in peak fuel temperatures. A 3D thermal-hydraulic model for a single TREAT fuel assembly was benchmarked to reproduce results obtained with previous thermal models developed for a TREAT HEU fuel assembly. In exercising this model, and variants thereof depending on the scope of analysis, various options were explored to reduce the peak cladding temperatures.

  5. New Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells

    SciTech Connect

    Allan J. Jacobson

    2005-11-17

    Operation of SOFCs at intermediate temperatures (500-800 C) requires new combinations of electrolyte and electrode materials that will provide both rapid ion transport across the electrolyte and electrode--electrolyte interfaces and efficient electrocatalysis of the oxygen reduction and fuel oxidation reactions. This project concentrates on materials and issues associated with cathode performance that are known to become limiting factors as the operating temperature is reduced. The specific objectives of the proposed research are to develop cathode materials that meet the electrode performance targets of 1.0 W/cm{sup 2} at 0.7 V in combination with YSZ at 700 C and with GDC, LSGM or bismuth oxide based electrolytes at 600 C. The performance targets imply an area specific resistance of {approx}0.5 {Omega}cm{sup 2} for the total cell. The research strategy is to investigate both established classes of materials and new candidates as cathodes, to determine fundamental performance parameters such as bulk diffusion, surface reactivity and interfacial transfer, and to couple these parameters to performance in single cell tests. In this report, the oxygen exchange kinetics of a P2 composition are described in detail. The oxygen exchange kinetics of the oxygen deficient double perovskite LnBaCo{sub 2}O{sub 5.5+{delta}} (Ln=Pr and Nd) have been determined by electrical conductivity relaxation. The high electronic conductivity and rapid diffusion and surface exchange kinetics of PBCO suggest its application as cathode material in intermediate temperature solid oxide fuel cells.

  6. Irradiation performance of AGR-1 high temperature reactor fuel

    SciTech Connect

    Paul A. Demkowicz; John D. Hunn; Robert N. Morris; Charles A. Baldwin; Philip L. Winston; Jason M. Harp; Scott A. Ploger; Tyler Gerczak; Isabella J. van Rooyen; Fred C. Montgomery; Chinthaka M. Silva

    2014-10-01

    The AGR-1 experiment contained 72 low-enriched uranium oxide/uranium carbide TRISO-coated particle fuel compacts in six capsules irradiated to burnups of 11.2 to 19.5% FIMA, with zero TRISO coating failures detected during the irradiation. The irradiation performance of the fuel–including the extent of fission product release and the evolution of kernel and coating microstructures–was evaluated based on detailed examination of the irradiation capsules, the fuel compacts, and individual particles. Fractional release of 110mAg from the fuel compacts was often significant, with capsule-average values ranging from 0.01 to 0.38. Analysis of silver release from individual compacts indicated that it was primarily dependent on fuel temperature history. Europium and strontium were released in small amounts through intact coatings, but were found to be significantly retained in the outer pyrocrabon and compact matrix. The capsule-average fractional release from the compacts was 1×10 4 to 5×10 4 for 154Eu and 8×10 7 to 3×10 5 for 90Sr. The average 134Cs release from compacts was <3×10 6 when all particles maintained intact SiC. An estimated four particles out of 2.98×105 experienced partial cesium release due to SiC failure during the irradiation, driving 134Cs release in two capsules to approximately 10 5. Identification and characterization of these particles has provided unprecedented insight into the nature and causes of SiC coating failure in high-quality TRISO fuel. In general, changes in coating morphology were found to be dominated by the behavior of the buffer and inner pyrolytic carbon (IPyC), and infrequently observed SiC layer damage was usually related to cracks in the IPyC. Palladium attack of the SiC layer was relatively minor, except for the particles that released cesium during irradiation, where SiC corrosion was found adjacent to IPyC cracks. Palladium, silver, and uranium were found in the SiC layer of irradiated particles, and characterization

  7. On the flexibility of high temperature reactor cores for high-and low-enriched fuel

    SciTech Connect

    Bzandes, S.; Lonhert, G.

    1982-07-01

    The operational flexibility of a high temperature reactor (HTR) is not restricted to either a low- or a high-enriched fuel cycle. Both fuel cycles are possible for the same core design. The fuel cycle cost is, however, penalized for low-enriched fuel; in addition, higher uranium consumption is required. Hence, an HTR is most economical to operate in the high-enriched thorium-uranium fuel cycle.

  8. Direct fired reciprocating engine and bottoming high temperature fuel cell hybrid

    DOEpatents

    Geisbrecht, Rodney A.; Holcombe, Norman T.

    2006-02-07

    A system of a fuel cell bottoming an internal combustion engine. The engine exhaust gas may be combined in varying degrees with air and fed as input to a fuel cell. Reformer and oxidizers may be combined with heat exchangers to accommodate rich and lean burn conditions in the engine in peaking and base load conditions without producing high concentrations of harmful emissions.

  9. New Optimal Sensor Suite for Ultrahigh Temperature Fossil Fuel Applications

    SciTech Connect

    John Coggin; Jonas Ivasauskas; Russell G. May; Michael B. Miller; Rena Wilson

    2006-09-30

    Accomplishments during Phase II of a program to develop and demonstrate photonic sensor technology for the instrumentation of advanced powerplants are described. The goal of this project is the research and development of advanced, robust photonic sensors based on improved sapphire optical waveguides, and the identification and demonstration of applications of the new sensors in advanced fossil fuel power plants, where the new technology will contribute to improvements in process control and monitoring. During this program work period, major progress has been experienced in the development of the sensor hardware, and the planning of the system installation and operation. The major focus of the next work period will be the installation of sensors in the Hamilton, Ohio power plant, and demonstration of high-temperature strain gages during mechanical testing of SOFC components.

  10. Carbide fuel pin and capsule design for irradiations at thermionic temperatures

    NASA Technical Reports Server (NTRS)

    Siegel, B. L.; Slaby, J. G.; Mattson, W. F.; Dilanni, D. C.

    1973-01-01

    The design of a capsule assembly to evaluate tungsten-emitter - carbide-fuel combinations for thermionic fuel elements is presented. An inpile fuel pin evaluation program concerned with clad temperture, neutron spectrum, carbide fuel composition, fuel geometry,fuel density, and clad thickness is discussed. The capsule design was a compromise involving considerations between heat transfer, instrumentation, materials compatibility, and test location. Heat-transfer calculations were instrumental in determining the method of support of the fuel pin to minimize axial temperature variations. The capsule design was easily fabricable and utilized existing state-of-the-art experience from previous programs.

  11. Controlling for peak power extraction from microbial fuel cells can increase stack voltage and avoid cell reversal

    NASA Astrophysics Data System (ADS)

    Boghani, Hitesh C.; Papaharalabos, George; Michie, Iain; Fradler, Katrin R.; Dinsdale, Richard M.; Guwy, Alan J.; Ieropoulos, Ioannis; Greenman, John; Premier, Giuliano C.

    2014-12-01

    Microbial fuel cells (MFCs) are bioelectrochemical systems which can degrade organic materials and are increasingly seen as potential contributors to low carbon technologies, particularly in energy recovery from and treatment of wastewaters. The theoretical maximum open circuit voltage from MFCs lies in the region of 1.1 V, but is reduced substantially by overvoltage losses. Practical use of the power requires stacking or other means to increase voltage. Series stacking of MFCs with typically encountered variability in operating conditions and performance raises the risk of cell reversal, which diminishes overall power performance. A novel strategy of MFC subsystem series connectivity along with maximum power point tracking (MPPT) generates increased power from individual MFCs whilst eliminating cell reversal. MFCs fed with lower concentrations of substrate experienced voltage reversal when connected in normal series connection with one common load, but when MFCs and loads together were connected in series, the underperforming cell is effectively bypassed and maximum power is made available. It is concluded that stack voltage may be increased and cell reversal avoided using the hybrid connectivity along with MPPT. This approach may be suitable for stacked MFC operations in the event that large scale arrays/modules are deployed in treating real wastewaters.

  12. SU-E-T-354: Peak Temperature Ratio of TLD Glow Curves to Investigate the Spatial Dependence of LET in a Clinical Proton Beam

    SciTech Connect

    Reft, C; Pankuch, M; Ramirez, H

    2014-06-01

    Purpose: Use the ratio of the two high temperature peaks (HTR) in TLD 700 glow curves to investigate spatial dependence of the linear energy transfer (LET) in proton beams. Studies show that the relative biological effectiveness (RBE) depends upon the physical dose as well as its spatial distribution. Although proton therapy uses a spatially invariant RBE of 1.1, studies suggest that the RBE increases in the distal edge of a spread out Bragg peak (SOBP) due to the increased LET. Methods: Glow curve studies in TLD 700 show that the 280 C temperature peak is more sensitive to LET radiation than the 210 C temperature peak. Therefore, the areas under the individual temperature peaks for TLDs irradiated in a proton beam normalized to the peak ratio for 6 MV photons are used to determine the HTR to obtain information on its LET. TLD 700 chips with dimensions 0.31×0.31×0.038 cc are irradiated with 90 MeV protons at varying depths in a specially designed blue wax phantom to investigate LET spatial dependence. Results: Five TLDs were placed at five different depths of the percent depth dose curve (PDD) of range 16.2 cm: center of the SOPB and approximately at the 99% distal edge, 90%, 75% and 25% of the PDD, respectively. HTR was 1.3 at the center of the SOBP and varied from 2.2 to 3.9 which can be related to an LET variation from 0.5 to 18 KeV/μ via calibration with radiation beams of varying LET. Conclusion: HTR data show a spatially invariant LET slightly greater than the 6 MV radiations in the SOBP, but a rapidly increasing LET at the end of the proton range. These results indicate a spatial variation in RBE with potential treatment consequences when selecting treatment margins to minimize the uncertainties in proton RBE.

  13. On the influence of temperature on PEM fuel cell operation

    NASA Astrophysics Data System (ADS)

    Coppo, M.; Siegel, N. P.; Spakovsky, M. R. von

    The 3D implementation of a previously developed 2D PEMFC model [N.P. Siegel, M.W. Ellis, D.J. Nelson, M.R. von Spakovsky, A two-dimensional computational model of a PEMFC with liquid water transport, J. Power Sources 128 (2) (2004) 173-184; N.P. Siegel, M.W. Ellis, D.J. Nelson, M.R. von Spakovsky, Single domain PEMFC model based on agglomerate catalyst geometry, J. Power Sources 115 (2003) 81-89] has been used to analyze the various pathways by which temperature affects the operation of a proton exchange membrane fuel cell [M. Coppo, CFD analysis and experimental investigation of proton exchange membrane fuel cells, Ph.D. Dissertation, Politecnico di Torino, Turin, Italy, 2005]. The original model, implemented in a specially modified version of CFDesign ® [CFDesign ® V5.1, Blue Ridge Numerics, 2003] , accounts for all of the major transport processes including: (i) a three-phase model for water transport in the liquid, vapor and dissolved phases, (ii) proton transport, (iii) gaseous species transport and reaction, (iv) an agglomerate model for the catalyst layers and (v) gas phase momentum transport. Since the details of it have been published earlier [N.P. Siegel, M.W. Ellis, D.J. Nelson, M.R. von Spakovsky, A two-dimensional computational model of a PEMFC with liquid water transport, J. Power Sources 128 (2) (2004) 173-184; N.P. Siegel, M.W. Ellis, D.J. Nelson, M.R. von Spakovsky, Single domain PEMFC model based on agglomerate catalyst geometry, J. Power Sources 115 (2003) 81-89; N.P. Siegel, Development and validation of a computational model for a proton exchange membrane fuel cell, Ph.D. Dissertation, Virginia Polytechnic Institute and State University, Blacksburg, VA, 2003], only new features are briefly discussed in the present work. In particular, the model has been extended in order to account for the temperature dependence of all of the physical properties involved in the model formulation. Moreover, a novel model has been developed to describe liquid

  14. High temperature tubular solid oxide fuel cell development

    SciTech Connect

    Ray, E.R.

    1992-01-01

    Important to the development commercialization of any new technology is a field test program. This is a mutually beneficial program for both the developer and the prospective user. The developer is able to acquire valuable field operating experience that is not available in a laboratory while the user has the opportunity to become familiar with the new technology and gains a working knowledge of it through hands-on experience. Westinghouse, recognizing these benefits, initiated a program in 1986 by supplying a 400 W SOFC generator to Tennessee Valley Authority. This generator operated for approximately 1,760 hours and was constructed of twenty-four 30 cm thick-wall PST cells. In 1987, three, 3 kW SOFC generators were installed and operated at the facilities of the Tokyo Gas Company and the Osaka Gas Company. At Osaka Gas, two generators were used. First a training generator, operated for 2900 hours before it was replaced on a preplanned schedule with the second generator. The second generator operated for 3,600 hours. Tokyo Gas generator was operated for 4,900 hours. These generators had a 98% availability and measured NO{sub x} levels of less than 1.3 ppM. The 3 kW SOFC generators were constructed of 144 36 cm thick-wall PST cells. The 3 kW generators, as was the TVA generator, were fueled with hydrogen and carbon monoxide. The next major milestone in the field unit program was reached in early 1992 with the delivery to The UTILITIES, a consortium of the Kansai Electric Power company, the Tokyo Gas Company, and the Osaka Gas Company, of a natural gas fueled all electric SOFC system. This system is rated at a nominal 25 kW dc with a peak capacity of 40 kW dc. The NO{sub x} was measured at <0.3 ppM (corrected to 15% oxygen). The system consists of 1152 cells (thin-wall PST) of 50 cm active length, manufactured at the PPMF. Cells are contained in two independently controlled and operated generators. 2,300 hours of stable operation has been obtained on the first unit.

  15. High temperature tubular solid oxide fuel cell development

    SciTech Connect

    Ray, E.R.

    1992-09-01

    Important to the development commercialization of any new technology is a field test program. This is a mutually beneficial program for both the developer and the prospective user. The developer is able to acquire valuable field operating experience that is not available in a laboratory while the user has the opportunity to become familiar with the new technology and gains a working knowledge of it through hands-on experience. Westinghouse, recognizing these benefits, initiated a program in 1986 by supplying a 400 W SOFC generator to Tennessee Valley Authority. This generator operated for approximately 1,760 hours and was constructed of twenty-four 30 cm thick-wall PST cells. In 1987, three, 3 kW SOFC generators were installed and operated at the facilities of the Tokyo Gas Company and the Osaka Gas Company. At Osaka Gas, two generators were used. First a training generator, operated for 2900 hours before it was replaced on a preplanned schedule with the second generator. The second generator operated for 3,600 hours. Tokyo Gas generator was operated for 4,900 hours. These generators had a 98% availability and measured NO{sub x} levels of less than 1.3 ppM. The 3 kW SOFC generators were constructed of 144 36 cm thick-wall PST cells. The 3 kW generators, as was the TVA generator, were fueled with hydrogen and carbon monoxide. The next major milestone in the field unit program was reached in early 1992 with the delivery to The UTILITIES, a consortium of the Kansai Electric Power company, the Tokyo Gas Company, and the Osaka Gas Company, of a natural gas fueled all electric SOFC system. This system is rated at a nominal 25 kW dc with a peak capacity of 40 kW dc. The NO{sub x} was measured at <0.3 ppM (corrected to 15% oxygen). The system consists of 1152 cells (thin-wall PST) of 50 cm active length, manufactured at the PPMF. Cells are contained in two independently controlled and operated generators. 2,300 hours of stable operation has been obtained on the first unit.

  16. Low-temperature α peak of the internal friction in niobium and its relation to the relaxation of kinks in dislocations

    NASA Astrophysics Data System (ADS)

    Natsik, V. D.; Pal'-Val', P. P.; Pal'-Val', L. N.; Semerenko, Yu. A.

    2001-05-01

    The influence of impurities on the parameters of the α peak of the internal friction in single-crystal and polycrystalline niobium is investigated; the internal friction is recorded in the temperature range 200-250 K at a vibrational frequency of ≈80 kHz. It is found that increasing the purity of the samples leads to an increase of the peak location temperature and to an increase of its width and amplitude. The structural sensitivity of this peak was observed previously in a study of the influence on this peak of a preliminary plastic deformation, thermocycling, and low-temperature recovery. A statistical description of the whole set of experimental data is proposed, which takes into account the dependence of the activation energy and attempt period on the impurity concentration and on the characteristic value and statistical scatter of the internal stresses. A new algorithm is developed for analyzing the experimental data to obtain empirical estimates for the values of the activation energy, its variance, the attempt period, and relaxation strength for the different structural states of the samples. It is shown that the α peak is a consequence of the resonant interaction of elastic vibrations with the thermally activated nucleation of kink pairs on dislocation segments lying in the valleys of the Peierls potential relief. Empirical estimates are obtained for the values of the main parameters characterizing this process. It is found that the properties of the α peak in niobium are in qualitative agreement with Engelke's theory of the nucleation and relaxation of dislocation kinks.

  17. Materials System for Intermediate Temperature Solid Oxide Fuel Cell

    SciTech Connect

    Uday B. Pal; Srikanth Gopalan

    2005-01-24

    AC complex impedance spectroscopy studies were conducted between 600-800 C on symmetrical cells that employed strontium-and-magnesium-doped lanthanum gallate electrolyte, La{sub 0.9}Sr{sub 0.1}Ga{sub 0.8}Mg{sub 0.2}O{sub 3} (LSGM). The objective of the study was to identify the materials system for fabrication and evaluation of intermediate temperature (600-800 C) solid oxide fuel cells (SOFCs). The slurry-coated electrode materials had fine porosity to enhance catalytic activity. Cathode materials investigated include La{sub 1-x}Sr{sub x}MnO{sub 3} (LSM), LSCF (La{sub 1-x}Sr{sub x}Co{sub y}Fe{sub 1-y}O{sub 3}), a two-phase particulate composite consisting of LSM-doped-lanthanum gallate (LSGM), and LSCF-LSGM. The anode materials were Ni-Ce{sub 0.85}Gd{sub 0.15}O{sub 2} (Ni-GDC) and Ni-Ce{sub 0.6}La{sub 0.4}O{sub 2} (Ni-LDC) composites. Experiments conducted with the anode materials investigated the effect of having a barrier layer of GDC or LDC in between the LSGM electrolyte and the Ni-composite anode to prevent adverse reaction of the Ni with lanthanum in LSGM. For proper interpretation of the beneficial effects of the barrier layer, similar measurements were performed without the barrier layer. The ohmic and the polarization resistances of the system were obtained over time as a function of temperature (600-800 C), firing temperature, thickness, and the composition of the electrodes. The study revealed important details pertaining to the ohmic and the polarization resistances of the electrode as they relate to stability and the charge-transfer reactions that occur in such electrode structures.

  18. Low platinum loading for high temperature proton exchange membrane fuel cell developed by ultrasonic spray coating technique

    NASA Astrophysics Data System (ADS)

    Su, Huaneng; Jao, Ting-Chu; Barron, Olivia; Pollet, Bruno G.; Pasupathi, Sivakumar

    2014-12-01

    This paper reports use of an ultrasonic-spray for producing low Pt loadings membrane electrode assemblies (MEAs) with the catalyst coated substrate (CCS) fabrication technique. The main MEA sub-components (catalyst, membrane and gas diffusion layer (GDL)) are supplied from commercial manufacturers. In this study, high temperature (HT) MEAs with phosphoric acid (PA)-doped poly(2,5-benzimidazole) (AB-PBI) membrane are fabricated and tested under 160 °C, hydrogen and air feed 100 and 250 cc min-1 and ambient pressure conditions. Four different Pt loadings (from 0.138 to 1.208 mg cm-2) are investigated in this study. The experiment data are determined by in-situ electrochemical methods such as polarization curve, electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV). The high Pt loading MEA exhibits higher performance at high voltage operating conditions but lower performances at peak power due to the poor mass transfer. The Pt loading 0.350 mg cm-2 GDE performs the peak power density and peak cathode mass power to 0.339 W cm-2 and 0.967 W mgPt-1, respectively. This work presents impressive cathode mass power and high fuel cell performance for high temperature proton exchange membrane fuel cells (HT-PEMFCs) with low Pt loadings.

  19. Observed Temperature Effects on Hourly Residential Electric LoadReduction in Response to an Experimental Critical Peak PricingTariff

    SciTech Connect

    Herter, Karen B.; McAuliffe, Patrick K.; Rosenfeld, Arthur H.

    2005-11-14

    The goal of this investigation was to characterize themanual and automated response of residential customers to high-price"critical" events dispatched under critical peak pricing tariffs testedin the 2003-2004 California Statewide Pricing Pilot. The 15-monthexperimental tariff gave customers a discounted two-price time-of-userate on 430 days in exchange for 27 critical days, during which the peakperiod price (2 p.m. to 7 p.m.) was increased to about three times thenormal time-of-use peak price. We calculated response by five-degreetemperature bins as the difference between peak usage on normal andcritical weekdays. Results indicatedthat manual response to criticalperiods reached -0.23 kW per home (-13 percent) in hot weather(95-104.9oF), -0.03 kW per home (-4 percent) in mild weather (60-94.9oF),and -0.07 kW per home (-9 percent) during cold weather (50-59.9oF).Separately, we analyzed response enhanced by programmable communicatingthermostats in high-use homes with air-conditioning. Between 90oF and94.9oF, the response of this group reached -0.56 kW per home (-25percent) for five-hour critical periods and -0.89 kW/home (-41 percent)for two-hour critical periods.

  20. Effects of chemical equilibrium on turbine engine performance for various fuels and combustor temperatures

    NASA Technical Reports Server (NTRS)

    Tran, Donald H.; Snyder, Christopher A.

    1992-01-01

    A study was performed to quantify the differences in turbine engine performance with and without the chemical dissociation effects for various fuel types over a range of combustor temperatures. Both turbojet and turbofan engines were studied with hydrocarbon fuels and cryogenic, nonhydrocarbon fuels. Results of the study indicate that accuracy of engine performance decreases when nonhydrocarbon fuels are used, especially at high temperatures where chemical dissociation becomes more significant. For instance, the deviation in net thrust for liquid hydrogen fuel can become as high as 20 percent at 4160 R. This study reveals that computer central processing unit (CPU) time increases significantly when dissociation effects are included in the cycle analysis.

  1. Interconnects for intermediate temperature solid oxide fuel cells

    NASA Astrophysics Data System (ADS)

    Huang, Wenhua

    Presently, one of the principal goals of solid oxide fuel cells (SOFCs) research is to reduce the stack operating temperature to between 600 and 800°C. However, one of the principal technological barriers is the non-availability of a suitable material satisfying all of the stability requirements for the interconnect. In this work two approaches for intermediate temperature SOFC interconnects have been explored. The first approach comprises an interconnect consisting of a bi-layer structure, a p-type oxide (La0.96Sr0.08MnO 2.001/LSM) layer exposed to a cathodic environment, and an n-type oxide (Y0.08Sr0.88Ti0.95Al0.05O 3-delta/YSTA) layer exposed to anodic conditions. Theoretical analysis based on the bi-layer structure has established design criteria to implement this approach. The analysis shows that the interfacial oxygen partial pressure, which determines the interconnect stability, is independent of the electronic conductivities of both layers but dependent on the oxygen ion layer interconnects, the oxygen ion conductivities of LSM and YSTA were measured as a function of temperature and oxygen partial pressure. Based on the measured data, it has been determined that if the thickness of YSTA layer is around 0.1cm, the thickness of LSM layer should be around 0.6 mum in order to maintain the stability of LSM. In a second approach, a less expensive stainless steel interconnect has been studied. However, one of the major concerns associated with the use of metallic interconnects is the development of a semi-conducting or insulating oxide scale and chromium volatility during extended exposure to the SOFC operating environment. Dense and well adhered Mn-Cu spinet oxide coatings were successfully deposited on stainless steel by an electrophoretic deposition (EPD) technique. It was found that the Mn-Cu-O coating significantly reduced the oxidation rate of the stainless steel and the volatility of chromium. The area specific resistance (ASR) of coated Crofer 22 APU is

  2. Direct Utilization of Coal Syngas in High Temperature Fuel Cells

    SciTech Connect

    Celik, Ismail B.

    2014-10-30

    This EPSCoR project had two primary goals: (i) to build infrastructure and work force at WVU to support long-term research in the area of fuel cells and related sciences; (ii) study effects of various impurities found in coal-syngas on performance of Solid Oxide Fuel Cells (SOFC). As detailed in this report the WVU research team has made significant accomplishments in both of these areas. What follows is a brief summary of these accomplishments: State-of-the-art test facilities and diagnostic tools have been built and put into use. These include cell manufacturing, half-cell and full-cell test benches, XPS, XRD, TEM, Raman, EDAX, SEM, EIS, and ESEM equipment, unique in-situ measurement techniques and test benches (Environmental EM, Transient Mass-Spectrometer-MS, and IR Optical Temperature measurements). In addition, computational capabilities have been developed culminating in a multi-scale multi-physics fuel cell simulation code, DREAM-SOFC, as well as a Beowulf cluster with 64 CPU units. We have trained 16 graduate students, 10 postdoctoral fellows, and recruited 4 new young faculty members who have actively participated in the EPSCoR project. All four of these faculty members have already been promoted to the tenured associate professor level. With the help of these faculty and students, we were able to secure 14 research awards/contracts amounting to a total of circa $5.0 Million external funding in closely related areas of research. Using the facilities mentioned above, the effects of PH3, HCl, Cl2, and H2S on cell performance have been studied in detail, mechanisms have been identified, and also remedies have been proposed and demonstrated in the laboratory. For example, it has been determined that PH3 reacts rapidly with Ni to from secondary compounds which may become softer or even melt at high temperature and then induce Ni migration to the surface of the cell changing the material and micro-structural properties of the cell drastically. It is found that

  3. Platinum redispersion on metal oxides in low temperature fuel cells.

    PubMed

    Tripković, Vladimir; Cerri, Isotta; Nagami, Tetsuo; Bligaard, Thomas; Rossmeisl, Jan

    2013-03-01

    We have analyzed the aptitude of several metal oxide supports (TiO(2), SnO(2), NbO(2), ZrO(2), SiO(2), Ta(2)O(5) and Nb(2)O(5)) to redisperse platinum under electrochemical conditions pertinent to the Proton Exchange Membrane Fuel Cell (PEMFC) cathode. The redispersion on oxide supports in air has been studied in detail; however, due to different operating conditions it is not straightforward to link the chemical and the electrochemical environment. The largest differences reflect in (1) the oxidation state of the surface (the oxygen species coverage), (2) temperature and (3) the possibility of platinum dissolution at high potentials and the interference of redispersion with normal working potential of the PEMFC cathode. We have calculated the PtO(x) (x = 0, 1, 2) adsorption energies on different metal oxides' surface terminations as well as inside the metal oxides' bulk, and we have concluded that NbO(2) might be a good support for platinum redispersion at PEMFC cathodes. PMID:23358311

  4. Analysis of higher than normal fuel temperatures in the hexagonal geometry TRIGA reactor

    SciTech Connect

    Hughes, D.; Boyle, P.; Levine, S.H.

    1996-12-31

    The 1-MW Pennsylvania State University TRIGA has hexagonal geometry and a water-filled central thimble. It was operated with all 8.5 wt% U fuel from December 1965 until July 1972, when 12 wt% U fuel elements replaced the 8.5 wt% U fuel in the centermost ring, the B ring. Although the power density of the 12 wt% U fuel was {approximately}35% greater than the corresponding 8.5 wt% U fuel, its maximum steady-state fuel temperature was always below 500{degrees}C when operating at 1 MW. Since that time, the core has been successfully loaded by placing six 12 wt% U fuel elements in the B ring. The used 12 wt% U fuel moved outward. Recently, however, a new instrumented 12 wt% U fuel element initially read a much higher fuel temperature than all previous similar fuel elements. The purpose of this paper is to present the calculations and experiments performed to correlate calculations with experimental data and to determine the cause of the higher fuel temperature for this element.

  5. Experimental Study of the Stability of Aircraft Fuels at Elevated Temperatures

    NASA Technical Reports Server (NTRS)

    Vranos, A.; Marteney, P. J.

    1980-01-01

    An experimental study of fuel stability was conducted in an apparatus which simulated an aircraft gas turbine fuel system. Two fuels were tested: Jet A and Number 2 Home Heating oil. Jet A is an aircraft gas turbine fuel currently in wide use. No. 2HH was selected to represent the properties of future turbine fuels, particularly experimental Reference Broad Specification, which, under NASA sponsorship, was considered as a possible next-generation fuel. Tests were conducted with varying fuel flow rates, delivery pressures and fuel pretreatments (including preheating and deoxygenation). Simulator wall temperatures were varied between 422K and 672K at fuel flows of 0.022 to 0.22 Kg/sec. Coking rate was determined at four equally-spaced locations along the length of the simulator. Fuel samples were collected for infrared analysis. The dependence of coking rate in Jet A may be correlated with surface temperature via an activation energy of 9 to 10 kcal/mole, although the results indicate that both bulk fluid and surface temperature affect the rate of decomposition. As a consequence, flow rate, which controls bulk temperature, must also be considered. Taken together, these results suggest that the decomposition reactions are initiated on the surface and continue in the bulk fluid. The coking rate data for No. 2 HH oil are very highly temperature dependent above approximately 533K. This suggests that bulk phase reactions can become controlling in the formation of coke.

  6. Low-Enriched Fuel Design Concept for the Prismatic Very High Temperature Reactor Core

    SciTech Connect

    Sterbentz, James W

    2007-05-01

    A new non-TRISO fuel and clad design concept is proposed for the prismatic, heliumcooled Very High Temperature Reactor core. The new concept could substantially reduce the current 10-20 wt% TRISO uranium enrichments down to 4-6 wt% for both initial and reload cores. The proposed fuel form would be a high-temperature, high-density uranium ceramic, for example UO2, configured into very small diameter cylindrical rods. The small diameter fuel rods significantly increase core reactivity through improved neutron moderation and fuel lumping. Although a high-temperature clad system for the concept remains to be developed, recent success in tube fabrication and preliminary irradiation testing of silicon carbide (SiC) cladding for light water reactor applications offers good potential for this application, and for future development of other carbide clad designs. A high-temperature ceramic fuel, together with a high-temperature clad material, could also lead to higher thermal safety margins during both normal and transient reactor conditions relative to TRISO fuel. The calculated neutronic results show that the lowenrichment, small diameter fuel rods and low thermal neutron absorbing clad retain the strong negative Doppler fuel temperature coefficient of reactivity that ensures inherent safe operation of the VHTR, and depletion studies demonstrate that an 18-month power cycle can be achieved with the lower enrichment fuel.

  7. Nonhumidified High-Temperature Membranes Developed for Proton Exchange Membrane Fuel Cells

    NASA Technical Reports Server (NTRS)

    Kinder, James D.

    2005-01-01

    Fuel cells are being considered for a wide variety of aerospace applications. One of the most versatile types of fuel cells is the proton-exchange-membrane (PEM) fuel cell. PEM fuel cells can be easily scaled to meet the power and space requirements of a specific application. For example, small 100-W PEM fuel cells are being considered for personal power for extravehicular activity suit applications, whereas larger PEM fuel cells are being designed for primary power in airplanes and in uninhabited air vehicles. Typically, PEM fuel cells operate at temperatures up to 80 C. To increase the efficiency and power density of the fuel cell system, researchers are pursuing methods to extend the operating temperature of the PEM fuel cell to 180 C. The most widely used membranes in PEM fuel cells are Nafion 112 and Nafion 117--sulfonated perfluorinated polyethers that were developed by DuPont. In addition to their relatively high cost, the properties of these membranes limit their use in a PEM fuel cell to around 80 C. The proton conductivity of Nafion membranes significantly decreases above 80 C because the membrane dehydrates. The useful operating range of Nafion-based PEM fuel cells can be extended to over 100 C if ancillary equipment, such as compressors and humidifiers, is added to maintain moisture levels within the membrane. However, the addition of these components reduces the power density and increases the complexity of the fuel cell system.

  8. High temperature polymers for proton exchange membrane fuel cells

    NASA Astrophysics Data System (ADS)

    Einsla, Brian Russel

    Novel proton exchange membranes (PEMs) were investigated that show potential for operating at higher temperatures in both direct methanol (DMFC) and H 2/air PEM fuel cells. The need for thermally stable polymers immediately suggests the possibility of heterocyclic polymers bearing appropriate ion conducting sites. Accordingly, monomers and random disulfonated poly(arylene ether) copolymers containing either naphthalimide, benzoxazole or benzimidazole moieties were synthesized via direct copolymerization. The ion exchange capacity (IEC) was varied by simply changing the ratio of disulfonated monomer to nonsulfonated monomer in the copolymerization step. Water uptake and proton conductivity of cast membranes increased with IEC. The water uptake of these heterocyclic copolymers was lower than that of comparable disulfonated poly(arylene ether) systems, which is a desirable improvement for PEMs. Membrane electrode assemblies were prepared and the initial fuel cell performance of the disulfonated polyimide and polybenzoxazole (PBO) copolymers was very promising at 80°C compared to the state-of-the-art PEM (NafionRTM); nevertheless these membranes became brittle under operating conditions. Several series of poly(arylene ether)s based on disodium-3,3'-disulfonate-4,4 '-dichlorodiphenylsulfone (S-DCDPS) and a benzimidazole-containing bisphenol were synthesized and afforded copolymers with enhanced stability. Selected properties of these membranes were compared to separately prepared miscible blends of disulfonated poly(arylene ether sulfone) copolymers and polybenzimidazole (PBI). Complexation of the sulfonic acid groups with the PBI structure reduced water swelling and proton conductivity. The enhanced proton conductivity of NafionRTM membranes has been proposed to be due to the aggregation of the highly acidic side-chain sulfonic acid sites to form ion channels. A series of side-chain sulfonated poly(arylene ether sulfone) copolymers based on methoxyhydroquinone was

  9. Additional experiments on flowability improvements of aviation fuels at low temperatures, volume 2

    NASA Technical Reports Server (NTRS)

    Stockemer, F. J.; Deane, R. L.

    1982-01-01

    An investigation was performed to study flow improver additives and scale-model fuel heating systems for use with aviation hydrocarbon fuel at low temperatures. Test were performed in a facility that simulated the heat transfer and temperature profiles anticipated in wing fuel tanks during flight of long-range commercial aircraft. The results are presented of experiments conducted in a test tank simulating a section of an outer wing integral fuel tank approximately full-scale in height, chilled through heat exchange panels bonded to the upper and lower horizontal surfaces. A separate system heated lubricating oil externally by a controllable electric heater, to transfer heat to fuel pumped from the test tank through an oil-to-fuel heat exchanger, and to recirculate the heated fuel back to the test tank.

  10. Rate and peak concentrations of off-gas emissions in stored wood pellets--sensitivities to temperature, relative humidity, and headspace volume.

    PubMed

    Kuang, Xingya; Shankar, Tumuluru Jaya; Bi, Xiaotao T; Lim, C Jim; Sokhansanj, Shahab; Melin, Staffan

    2009-11-01

    Wood pellets emit CO, CO(2), CH(4), and other volatiles during storage. Increased concentration of these gases in a sealed storage causes depletion of concentration of oxygen. The storage environment becomes toxic to those who operate in and around these storages. The objective of this study was to investigate the effects of temperature, moisture, and the relative size of storage headspace on emissions from wood pellets in an enclosed space. Twelve 10-l plastic containers were used to study the effects of headspace ratio (25, 50, and 75% of container volume) and temperatures (10-50 degrees C). Another eight containers were set in uncontrolled storage relative humidity (RH) and temperature. Concentrations of CO(2), CO, and CH(4) were measured by gas chromatography (GC). The results showed that emissions of CO(2), CO, and CH(4) from stored wood pellets are more sensitive to storage temperature than to RH and the relative volume of headspace. Higher peak emission factors are associated with higher temperatures. Increased headspace volume ratio increases peak off-gas emissions because of the availability of oxygen associated with pellet decomposition. Increased RH in the enclosed container increases the rate of off-gas emissions of CO(2), CO, and CH(4) and oxygen depletion. PMID:19656803

  11. Rate and peak concentrations of off-gas emissions in stored wood pellets sensitivities to temperature, relative humidity, and headspace volume

    SciTech Connect

    Kuang, Xingya; Shankar, T.J.; Bi, X.T.; Lim, C. Jim; Sokhansanj, Shahabaddine; Melin, Staffan

    2009-08-01

    Wood pellets emit CO, CO2, CH4 and other volatiles during storage. Increased concentration of these gases in a sealed storage causes depletion of concentration of oxygen. The storage environment becomes toxic to those who operate in and around these storages. The objective of this study was to investigate the effects of temperature, moisture and storage headspace on emissions from wood pellets in an enclosed space. Twelve 10-liter plastic containers were used to study the effects of headspace ratio (25%, 50%, and 75% of container volume) and temperatures (10-50oC). Another eight containers were set in uncontrolled storage relative humidity and temperature. Concentrations of CO2, CO and CH4 were measured by a gas chromatography (GC). The results showed that emissions of CO2, CO and CH4 from stored wood pellets are most sensitive to storage temperature. Higher peak emission factors are associated with higher temperatures. Increased headspace volume ratio increases peak off-gas emissions because of the availability of oxygen for pellet decomposition. Increased relative humidity in the enclosed container increases the rate of off-gas emissions of CO2, CO and CH4 and oxygen depletion.

  12. TEMP: a computer code to calculate fuel pin temperatures during a transient. [LMFBR

    SciTech Connect

    Bard, F E; Christensen, B Y; Gneiting, B C

    1980-04-01

    The computer code TEMP calculates fuel pin temperatures during a transient. It was developed to accommodate temperature calculations in any system of axi-symmetric concentric cylinders. When used to calculate fuel pin temperatures, the code will handle a fuel pin as simple as a solid cylinder or as complex as a central void surrounded by fuel that is broken into three regions by two circumferential cracks. Any fuel situation between these two extremes can be analyzed along with additional cladding, heat sink, coolant or capsule regions surrounding the fuel. The one-region version of the code accurately calculates the solution to two problems having closed-form solutions. The code uses an implicit method, an explicit method and a Crank-Nicolson (implicit-explicit) method.

  13. Fuel properties effect on the performance of a small high temperature rise combustor

    NASA Technical Reports Server (NTRS)

    Acosta, Waldo A.; Beckel, Stephen A.

    1989-01-01

    The performance of an advanced small high temperature rise combustor was experimentally determined at NASA-Lewis. The combustor was designed to meet the requirements of advanced high temperature, high pressure ratio turboshaft engines. The combustor featured an advanced fuel injector and an advanced segmented liner design. The full size combustor was evaluated at power conditions ranging from idle to maximum power. The effect of broad fuel properties was studied by evaluating the combustor with three different fuels. The fuels used were JP-5, a blend of Diesel Fuel Marine/Home Heating Oil, and a blend of Suntec C/Home Heating Oil. The fuel properties effect on the performance of the combustion in terms of pattern factor, liner temperatures, and exhaust emissions are documented.

  14. A reduced temperature solid oxide fuel cell with three-dimensionally ordered macroporous cathode

    SciTech Connect

    Liang, B.; Suzuki, T.; Hamamoto, K.; Yamaguchi, T.; Sumi, H.; Fujishiro, Y.; Ingram, B. J.; Carter, J. D.

    2012-01-01

    Three-dimensionally ordered macroporous cathode was fabricated for a zirconia based micro-tubular solid oxide fuel cells (SOFCs). Three different cathodes (cathode A, no pore former; cathode B, with pore former (1.5 {micro}m in diameter); cathode C, with pore former (0.8 {micro}m in diameter)) were compared to investigate how the microstructure of it affected the cell performance at various operating temperatures. Micro-sized pores were well distributed within cathode B and C. The total porosity of cathode A is 35%, while it respectively reached 42 and 50% for cathodes B and C. At the same time, the specific surface area of them was 28.8 and 52.0% larger than that of the cathode A. As a result, the peak power density of the zirconia based cell, with cathode C, was 0.25 and 0.56 W cm{sup -2} at 550 and 600 C, while the respective value was just 0.11 and 0.30 W cm{sup -2} for the cell with cathode A. Thus, optimizing microstructure of cathode should be one of the best approaches for lowering the operating temperature for SOFCs.

  15. Experimental Study of Fuel Heating at Low Temperatures in a Wing Tank Model, Volume 1

    NASA Technical Reports Server (NTRS)

    Stockemer, F. J.

    1981-01-01

    Scale model fuel heating systems for use with aviation hydrocarbon fuel at low temperatures were investigated. The effectiveness of the heating systems in providing flowability and pumpability at extreme low temperature when some freezing of the fuel would otherwise occur is evaluated. The test tank simulated a section of an outer wing tank, and was chilled on the upper and lower surfaces. Turbine engine lubricating oil was heated, and recirculating fuel transferred the heat. Fuels included: a commercial Jet A; an intermediate freeze point distillate; a higher freeze point distillate blended according to Experimental Referee Broadened Specification guidelines; and a higher freeze point paraffinic distillate used in a preceding investigation. Each fuel was chilled to selected temperature to evaluate unpumpable solid formation (holdup). Tests simulating extreme cold weather flight, without heating, provided baseline fuel holdup data. Heating and recirculating fuel increased bulk temperature significantly; it had a relatively small effect on temperature near the bottom of the tank. Methods which increased penetration of heated fuel into the lower boundary layer improved the capability for reducing holdup.

  16. Influence of temperature on growth and peak oil biosynthesis in a carbon-limited medium by Pythium irregulare'

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Kinetic analysis was investigated for a carbon-limited medium, with a carbon-to-nitrogen ratio of 5.0, supporting the growth of the 5,8,11,14,17-eicosapentaenoic acid (20:5; omega-3)accumulating fungal organism Pythium irregulare. The productivity and yield parameters at three temperatures, 14, 21, ...

  17. Materials System for Intermediate Temperature Solid Oxide Fuel Cell

    SciTech Connect

    Uday B. Pal; Srikanth Gopalan

    2006-01-12

    The objective of this work was to obtain a stable materials system for intermediate temperature solid oxide fuel cell (SOFC) capable of operating between 600-800 C with a power density greater than 0.2 W/cm{sup 2}. The solid electrolyte chosen for this system was La{sub 0.9}Sr{sub 0.1}Ga{sub 0.8}Mg{sub 0.2}O{sub 3}, (LSGM). To select the right electrode materials from a group of possible candidate materials, AC complex impedance spectroscopy studies were conducted between 600-800 C on symmetrical cells that employed the LSGM electrolyte. Based on the results of the investigation, LSGM electrolyte supported SOFCs were fabricated with La{sub 0.6}Sr{sub 0.4}Co{sub 0.8}Fe{sub 0.2}O{sub 3}-La{sub 0.9}Sr{sub 0.1}Ga{sub 0.8}Mg{sub 0.2}O{sub 3} (LSCF-LSGM) composite cathode and Nickel-Ce{sub 0.6}La{sub 0.4}O{sub 3} (Ni-LDC) composite anode having a barrier layer of Ce{sub 0.6}La{sub 0.4}O{sub 3} (LDC) between the LSGM electrolyte and the Ni-LDC anode. Electrical performance and stability of these cells were determined and the electrode polarization behavior as a function of cell current was modeled between 600-800 C. The electrical performance of the anode-supported SOFC was simulated assuming an electrode polarization behavior identical to the LSGM-electrolyte-supported SOFC. The simulated electrical performance indicated that the selected material system would provide a stable cell capable of operating between 600-800 C with a power density between 0.2 to 1 W/cm{sup 2}.

  18. Testing of uranium nitride fuel in T-111 cladding at 1200 K cladding temperature

    NASA Technical Reports Server (NTRS)

    Rohal, R. G.; Tambling, T. N.; Smith, R. L.

    1973-01-01

    Two groups of six fuel pins each were assembled, encapsulated, and irradiated in the Plum Brook Reactor. The fuel pins employed uranium mononitride (UN) in a tantalum alloy clad. The first group of fuel pins was irradiated for 1500 hours to a maximum burnup of 0.7-atom-percent uranium. The second group of fuel pins was irradiated for about 3000 hours to a maximum burnup of 1.0-atom-percent uranium. The average clad surface temperature during irradiation of both groups of fuel pins was approximately 1200 K. The postirradiation examination revealed the following: no clad failures or fuel swelling occurred; less than 1 percent of the fission gases escaped from the fuel; and the clad of the first group of fuel pins experienced clad embrittlement whereas the second group, which had modified assembly and fabrication procedures to minimize contamination, had a ductile clad after irradiation.

  19. An A-site-deficient perovskite offers high activity and stability for low-temperature solid-oxide fuel cells.

    PubMed

    Zhu, Yinlong; Chen, Zhi-Gang; Zhou, Wei; Jiang, Shanshan; Zou, Jin; Shao, Zongping

    2013-12-01

    Solid oxide fuel cells (SOFCs) directly convert fossil and/or renewable fuels into electricity and/or high-quality heat in an environmentally friendly way. However, high operating temperatures result in high cost and material issues, which have limited the commercialization of SOFCs. To lower their operating temperatures, highly active and stable cathodes are required to maintain a reasonable power output. Here, we report a layer-structured A-site deficient perovskite Sr0.95 Nb0.1 Co0.9 O3-δ (SNC0.95) prepared by solid-state reactions that shows not only high activity towards the oxygen reduction reaction (ORR) at operating temperatures below 600 °C, but also offers excellent structural stability and compatibility, and improved CO2 resistivity. An anode-supported fuel cell with SNC0.95 cathode delivers a peak power density as high as 1016 mW cm(-2) with an electrode-area-specific resistance of 0.052 Ω cm(2) at 500 °C. PMID:24155098

  20. Ortigalita Peak gabbro, Franciscan complex: U-Pb dates of intrusion and high-pressure low-temperature metamorphism

    NASA Astrophysics Data System (ADS)

    Mattinson, James M.; Echeverria, Lina M.

    1980-12-01

    Paleontological and isotopic age data from the Franciscan complex in the Ortigalita Peak quadrangle, Diablo Range, California, provide new insight into the tectonic evolution of at least part of the Franciscan complex. Graywacke, shale, pillowed greenstone, and chert in the quadrangle were deposited in Late Jurassic (Tithonian) time, about 135 to 150 m.y. ago, on the basis of radiolaria. These rocks then were incorporated in an accretionary wedge prior to the intrusion of gabbroic magma 95 m.y. ago (U-Pb dating on zircons). Subduction (metamorphism of gabbro and surrounding sedimentary rocks to blueschist grade) closely followed intrusion at about 92 m.y. ago (U-Pb dating on metamorphic titanite and “plagioclase” = albite + pumpellyite ± quartz). The brief interval between intrusion and subduction confirms the idea that the gabbro was intruded into the accretionary wedge, essentially at the site of plate convergence. The much longer interval (about 40 to 55 m.y.) between deposition and subduction reveals that the Franciscan had a long presubduction history and provides a time frame within which more speculative concepts such as extensive northward translation of the Franciscan must be constrained.

  1. Effects of Thermal Mass, Window Size, and Night-Time Ventilation on Peak Indoor Air Temperature in the Warm-Humid Climate of Ghana

    PubMed Central

    Amos-Abanyie, S.; Akuffo, F. O.; Kutin-Sanwu, V.

    2013-01-01

    Most office buildings in the warm-humid sub-Saharan countries experience high cooling load because of the predominant use of sandcrete blocks which are of low thermal mass in construction and extensive use of glazing. Relatively, low night-time temperatures are not harnessed in cooling buildings because office openings remain closed after work hours. An optimization was performed through a sensitivity analysis-based simulation, using the Energy Plus (E+) simulation software to assess the effects of thermal mass, window size, and night ventilation on peak indoor air temperature (PIAT). An experimental system was designed based on the features of the most promising simulation model, constructed and monitored, and the experimental data used to validate the simulation model. The results show that an optimization of thermal mass and window size coupled with activation of night-time ventilation provides a synergistic effect to obtain reduced peak indoor air temperature. An expression that predicts, indoor maximum temperature has been derived for models of various thermal masses. PMID:23878528

  2. Spent fuel temperature and age determination from the analysis of uranium and plutonium isotopics

    SciTech Connect

    Scott, Mark R; Eccleston, George W; Bedell, Jeffrey J; Lockard, Chanelle M

    2009-01-01

    The capability to determine the age (time since irradiation) of spent fuel can be useful for verification and safeguards. While the age of spent fuel can be determined based on measurements of short-lived fission products, these measurements are not routinely done nor generally reported. As an alternative, age can also be determined if the uranium (U) and plutonium (Pu) isotopic values are available. Uranium isotopics are not strongly affected by fuel temperature, and bumup is determined from the {sup 235}U and {sup 236}U isotopic values. Age is calculated after estimating the {sup 241}Pu at the end of irradiation while accounting for the fuel temperature, which is determined from {sup 239}Pu or {sup 240}Pu. Burnup and age determinations are calibrated to reactor models that provide uranium and plutonium isotopics over the range of fuel irradiation. The reactor model must contain sufficient fidelity on details of the reactor type, fuel burnup, irradiation history, initial fuel enrichment and fuel temperature to obtain accurate isotopic calculations. If the latter four are unknown, they can be derived from the uranium and plutonium isotopics. Fuel temperature has a significant affect on the production of plutonium isotopics; therefore, one group cross section reactor models, such as ORIGEN, cannot be used for these calculations. Multi-group cross section set codes, such as Oak Ridge National Laboratory's TRITON code, must be used.

  3. Real time monitoring of temperature of a micro proton exchange membrane fuel cell.

    PubMed

    Lee, Chi-Yuan; Lee, Shuo-Jen; Hu, Yuh-Chung; Shih, Wen-Pin; Fan, Wei-Yuan; Chuang, Chih-Wei

    2009-01-01

    Silicon micro-hole arrays (Si-MHA) were fabricated as a gas diffusion layer (GDL) in a micro fuel cell using the micro-electro-mechanical-systems (MEMS) fabrication technique. The resistance temperature detector (RTD) sensor was integrated with the GDL on a bipolar plate to measure the temperature inside the fuel cell. Experimental results demonstrate that temperature was generally linearly related to resistance and that accuracy and sensitivity were within 0.5 °C and 1.68×10(-3)/°C, respectively. The best experimental performance was 9.37 mW/cm(2) at an H(2)/O(2) dry gas flow rate of 30/30 SCCM. Fuel cell temperature during operation was 27 °C, as measured using thermocouples in contact with the backside of the electrode. Fuel cell operating temperature measured in situ was 30.5 °C. PMID:22573963

  4. New Optical Sensor Suite for Ultrahigh Temperature Fossil Fuel Application

    SciTech Connect

    John Coggin; Tom Flynn; Jonas Ivasauskas; Daniel Kominsky; Carrie Kozikowski; Russell May; Michael Miller; Tony Peng; Gary Pickrell; Raymond Rumpf; Kelly Stinson-Bagby; Dan Thorsen; Rena Wilson

    2007-12-31

    Accomplishments of a program to develop and demonstrate photonic sensor technology for the instrumentation of advanced powerplants and solid oxide fuel cells are described. The goal of this project is the research and development of advanced, robust photonic sensors based on improved sapphire optical waveguides, and the identification and demonstration of applications of the new sensors in advanced fossil fuel power plants, where the new technology will contribute to improvements in process control and monitoring.

  5. A Sharp Peak of the Zero-Temperature Penetration Depth at Optimal Composition in BaFe2(As1-xPx)2

    SciTech Connect

    Hashimoto, K.; Cho, K.; Shibauchi, T.; Kasahara, S.; Mizukami, Y.; Katsumata, R.; Tsuruhara, Y.; Terashima, T.; Ikeda, H.; Tanatar, M. A.; Kitano, H.; Salovich, N.; Giannetta, R. W.; Walmsley, P.; Carrington, A.; Prozorov, R.; Matsuda, Y.

    2012-06-21

    In a superconductor, the ratio of the carrier density, n, to its effective mass, m*, is a fundamental property directly reflecting the length scale of the superfluid flow, the London penetration depth, lL. In two-dimensional systems, this ratio n/m* (~1/lL 2) determines the effective Fermi temperature, TF. We report a sharp peak in the x-dependence of lL at zero temperature in clean samples of BaFe2(As1–xPx)2 at the optimum composition x = 0.30, where the superconducting transition temperature Tc reaches a maximum of 30 kelvin. This structure may arise from quantum fluctuations associated with a quantum critical point. The ratio of Tc/TF at x = 0.30 is enhanced, implying a possible crossover toward the Bose-Einstein condensate limit driven by quantum criticality.

  6. New Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells

    SciTech Connect

    Allan J. Jacobson

    2006-09-30

    Operation of SOFCs at intermediate temperatures (500-800 C) requires new combinations of electrolyte and electrode materials that will provide both rapid ion transport across the electrolyte and electrode-electrolyte interfaces and efficient electrocatalysis of the oxygen reduction and fuel oxidation reactions. This project concentrates on materials and issues associated with cathode performance that are known to become limiting factors as the operating temperature is reduced. The specific objectives of the proposed research are to develop cathode materials that meet the electrode performance targets of 1.0 W/cm{sup 2} at 0.7 V in combination with YSZ at 700 C and with GDC, LSGM or bismuth oxide based electrolytes at 600 C. The performance targets imply an area specific resistance of {approx}0.5 {Omega}cm{sup 2} for the total cell. The research strategy is to investigate both established classes of materials and new candidates as cathodes, to determine fundamental performance parameters such as bulk diffusion, surface reactivity and interfacial transfer, and to couple these parameters to performance in single cell tests. The initial choices for study were perovskite oxides based on substituted LaFeO{sub 3} (P1 compositions), where significant data in single cell tests exist at PNNL for example, for La{sub 0.8}Sr{sub 0.2}FeO{sub 3} cathodes on both YSZ and CSO/YSZ. The materials selection was then extended to La{sub 2}NiO{sub 4} compositions (K1 compositions), and then in a longer range task we evaluated the possibility of completely unexplored group of materials that are also perovskite related, the ABM{sub 2}O{sub 5+{delta}}. A key component of the research strategy was to evaluate for each cathode material composition, the key performance parameters, including ionic and electronic conductivity, surface exchange rates, stability with respect to the specific electrolyte choice, and thermal expansion coefficients. In the initial phase, we did this in parallel with

  7. Cold temperature diesel performance/combustion with Canadian low ignition quality fuels

    SciTech Connect

    Neill, W.S.; Wolf, W.M.; Webster, G.D.

    1986-01-01

    Three Canadian tar sands derived experimental diesel fuels with cetane numbers (CN) of 36, 31 and 26 and a reference fuel with a 47 CN were tested in a Deutz F1L511D, single cylinder, 4 stroke, naturally aspirated, diesel engine. Tests were performed with intake and cooling air temperatures of 0/sup 0/C and -12/sup 0/C over the entire engine operating range. Performance and combustion behaviour with the 36 CN fuel was marginally acceptable at 0/sup 0/C and unacceptable at -12/sup 0/C. High maximum combustion pressures and rates of combustion pressure rise were encountered at the low engine speed, high load condition with the experimental fuels. Poor combustion behaviour was also experienced with the two low CN fuels at light loads. Operation of this engine configuration with the 31 and 26 CN fuels is not recommended at 0/sup 0/C and lower intake air temperatures.

  8. Long term deposit formation in aviation turbine fuel at elevated temperature

    NASA Technical Reports Server (NTRS)

    Giovanetti, A. J.; Szetela, E. J.

    1986-01-01

    An experimental characterization is conducted for the relationships between deposit mass, operating time, and temperature, in coking associated with aviation fuels under conditions simulating those typical of turbine engine fuel systems. Jet A and Suntech A fuels were tested in stainless steel tubing heated to 420-750 K, over test durations of between 3 and 730 hr and at fuel velocities of 0.07-1.3 m/sec. Deposit rates are noted to be a strong function of tube temperature; for a given set of test conditions, deposition rates for Suntech A exceed those of Jet A by a factor of 10. Deposition rates increased markedly with test duration for both fuels. The heated tube data obtained are used to develop a global chemical kinetic model for fuel oxidation and carbon deposition.

  9. In-situ monitoring of internal local temperature and voltage of proton exchange membrane fuel cells.

    PubMed

    Lee, Chi-Yuan; Fan, Wei-Yuan; Hsieh, Wei-Jung

    2010-01-01

    The distribution of temperature and voltage of a fuel cell are key factors that influence performance. Conventional sensors are normally large, and are also useful only for making external measurements of fuel cells. Centimeter-scale sensors for making invasive measurements are frequently unable to accurately measure the interior changes of a fuel cell. This work focuses mainly on fabricating flexible multi-functional microsensors (for temperature and voltage) to measure variations in the local temperature and voltage of proton exchange membrane fuel cells (PEMFC) that are based on micro-electro-mechanical systems (MEMS). The power density at 0.5 V without a sensor is 450 mW/cm(2), and that with a sensor is 426 mW/cm(2). Since the reaction area of a fuel cell with a sensor is approximately 12% smaller than that without a sensor, but the performance of the former is only 5% worse. PMID:22163556

  10. Electrode Design for Low Temperature Direct-Hydrocarbon Solid Oxide Fuel Cells

    NASA Technical Reports Server (NTRS)

    Chen, Fanglin (Inventor); Zhao, Fei (Inventor); Liu, Qiang (Inventor)

    2015-01-01

    In certain embodiments of the present disclosure, a solid oxide fuel cell is described. The solid oxide fuel cell includes a hierarchically porous cathode support having an impregnated cobaltite cathode deposited thereon, an electrolyte, and an anode support. The anode support includes hydrocarbon oxidation catalyst deposited thereon, wherein the cathode support, electrolyte, and anode support are joined together and wherein the solid oxide fuel cell operates a temperature of 600.degree. C. or less.

  11. High temperature solid oxide regenerative fuel cell for solar photovoltaic energy storage

    NASA Technical Reports Server (NTRS)

    Bents, David J.

    1987-01-01

    A hydrogen-oxygen regenerative fuel cell (RFC) energy storage system based on high temperature solid oxide fuel cell (SOFC) technology is described. The reactants are stored as gases in lightweight insulated pressure vessels. The product water is stored as a liquid in saturated equilibrium with the fuel gas. The system functions as a secondary battery and is applicable to darkside energy storage for solar photovoltaics.

  12. Electrode design for low temperature direct-hydrocarbon solid oxide fuel cells

    SciTech Connect

    Chen, Fanglin; Zhao, Fei; Liu, Qiang

    2015-10-06

    In certain embodiments of the present disclosure, a solid oxide fuel cell is described. The solid oxide fuel cell includes a hierarchically porous cathode support having an impregnated cobaltite cathode deposited thereon, an electrolyte, and an anode support. The anode support includes hydrocarbon oxidation catalyst deposited thereon, wherein the cathode support, electrolyte, and anode support are joined together and wherein the solid oxide fuel cell operates a temperature of 600.degree. C. or less.

  13. On0Line Fuel Failure Monitor for Fuel Testing and Monitoring of Gas Cooled Very High Temperature Reactor

    SciTech Connect

    Ayman I. Hawari; Mohamed A. Bourham

    2010-04-22

    IVery High Temperature Reactors (VHTR) utilize the TRISO microsphere as the fundamental fuel unit in the core. The TRISO microsphere (~ 1- mm diameter) is composed of a UO2 kernel surrounded by a porous pyrolytic graphite buffer, an inner pyrolytic graphite layer, a silicon carbide (SiC) coating, and an outer pyrolytic graphite layer. The U-235 enrichment of the fuel is expected to range from 4% – 10% (higher enrichments are also being considered). The layer/coating system that surrounds the UO2 kernel acts as the containment and main barrier against the environmental release of radioactivity. To understand better the behavior of this fuel under in-core conditions (e.g., high temperature, intense fast neutron flux, etc.), the US Department of Energy (DOE) is launching a fuel testing program that will take place at the Advanced Test Reactor (ATR) located at Idaho National Laboratory (INL). During this project North Carolina State University (NCSU) researchers will collaborate with INL staff for establishing an optimized system for fuel monitoring for the ATR tests. In addition, it is expected that the developed system and methods will be of general use for fuel failure monitoring in gas cooled VHTRs.

  14. Peak performance.

    PubMed

    Milewski, Mary

    2006-10-01

    Earlier this year, a Pittsburgh-based adventurer became the first American with diabetes to reach the top of Mount Everest. He proved that nothing--not record-breaking winds, freezing temperatures, dangerous ice, or his disease--would slow him down. PMID:17039621

  15. Investigations into the low temperature behavior of jet fuels: Visualization, modeling, and viscosity studies

    NASA Astrophysics Data System (ADS)

    Atkins, Daniel L.

    Aircraft operation in arctic regions or at high altitudes exposes jet fuel to temperatures below freeze point temperature specifications. Fuel constituents may solidify and remain within tanks or block fuel system components. Military and scientific requirements have been met with costly, low freeze point specialty jet fuels. Commercial airline interest in polar routes and the use of high altitude unmanned aerial vehicles (UAVs) has spurred interest in the effects of low temperatures and low-temperature additives on jet fuel. The solidification of jet fuel due to freezing is not well understood and limited visualization of fuel freezing existed prior to the research presented in this dissertation. Consequently, computational fluid dynamics (CFD) modeling that simulates jet fuel freezing and model validation were incomplete prior to the present work. The ability to simulate jet fuel freezing is a necessary tool for fuel system designers. An additional impediment to the understanding and simulation of jet fuel freezing has been the absence of published low-temperature thermo-physical properties, including viscosity, which the present work addresses. The dissertation is subdivided into three major segments covering visualization, modeling and validation, and viscosity studies. In the first segment samples of jet fuel, JPTS, kerosene, Jet A and Jet A containing additives, were cooled below their freeze point temperatures in a rectangular, optical cell. Images and temperature data recorded during the solidification process provided information on crystal habit, crystallization behavior, and the influence of the buoyancy-driven flow on freezing. N-alkane composition of the samples was determined. The Jet A sample contained the least n-alkane mass. The cooling of JPTS resulted in the least wax formation while the cooling of kerosene yielded the greatest wax formation. The JPTS and kerosene samples exhibited similar crystallization behavior and crystal habits during

  16. Fission product release and microstructure changes of irradiated MOX fuel at high temperatures

    NASA Astrophysics Data System (ADS)

    Colle, J.-Y.; Hiernaut, J.-P.; Wiss, T.; Beneš, O.; Thiele, H.; Papaioannou, D.; Rondinella, V. V.; Sasahara, A.; Sonoda, T.; Konings, R. J. M.

    2013-11-01

    Samples of irradiated MOX fuel of 44.5 GWd/tHM mean burn-up were prepared by core drilling at three different radial positions of a fuel pellet. They were subsequently heated in a Knudsen effusion mass spectrometer up to complete vaporisation of the sample (˜2600 K) and the release of fission gas (krypton and xenon) as well as helium was measured. Scanning electron microscopy was used in parallel to investigate the evolution of the microstructure of a sample heated under the same condition up to given key temperatures as determined from the gas release profiles. A clear initial difference for fission gas release and microstructure was observed as a function of the radial position of the samples and therefore of irradiation temperature. A good correlation between the microstructure evolution and the gas release peaks could be established as a function of the temperature of irradiation and (laboratory) heating. The region closest to the cladding (0.58 < r/r0 < 0.96), designated as sample type A in Fig. 1. It represents the "cooler" part of the fuel pellet. The irradiation temperatures (Tirrad) in this range are from 854 to 1312 K (ΔT: 458 K). The intermediate radial zone of the pellet (0.42 < r/r0 < 0.81), designated sample type B in Fig. 1, has a Tirrad ranging from 1068 to 1434 K (ΔT: 365 K). The central zone of the pellet (0.003 < r/r0 < 0.41), designated sample type C in Fig. 1, which was close to the hottest part of the pellet, has a Tirrad ranging from 1442 to 1572 K (ΔT: 131 K). The sample irradiation temperatures were determined from the calculated temperature profile (exponential function) knowing the core temperature of the fuel (1573 K) [11], the standard temperature for this type of fuel at the inner side of the cladding (800 K). The average burnup was calculated with TRANSURANUS code [12] and the PA burnup is the average burnup multiplied by the ratio of the fissile Pu concentration in PA over average fissile Pu concentration in fuel [11]. Calculated

  17. Modeling of Spent Fuel Oxidation at Low Temperature

    SciTech Connect

    Poulesquen, Arnaud; Ferry, Cecile; Desgranges, Lionel

    2007-07-01

    During dry storage, the oxidation of the spent fuel in case of cladding and container failure (accidental scenario) could be detrimental for further handling of the spent fuel rod and for the safety of the facilities. Depending on whether the uranium dioxide is under the form of powder or pellet, irradiated or unirradiated, the weight gain curves do not present the same shape. To account for these different behaviours, two models have been developed. Firstly, the oxidation of unirradiated powders has been modelled based on the coexistence, during the oxidation, of two intermediate products, U{sub 4}O{sub 9} and U{sub 3}O{sub 7}. The comparison between the calculation and the literature data is good in terms of weight gain curves and chemical diffusion coefficient of oxygen within the two phases. Secondly, the oxidation of spent fuel fragments is approached by a convolution procedure between a grain oxidation model and an empirical parameter which represents the linear oxidation speed of grain boundary or an average distance able to cover the entire spent fuel fragment. This procedure of calculation allows in one hand to account for the incubation period noticed on unirradiated pellets or spent fuel and in another hand to link the empirical parameter to physical as porosity, cracks or linear power, or operational parameters such as fission gas release (FGR) respectively. A comparison of this new modelling with experimental data will be proposed. (authors)

  18. Efficient Conversion of Lignin to Electricity Using a Novel Direct Biomass Fuel Cell Mediated by Polyoxometalates at Low Temperatures.

    PubMed

    Zhao, Xuebing; Zhu, J Y

    2016-01-01

    A novel polyoxometalates (POMs) mediated direct biomass fuel cell (DBFC) was used in this study to directly convert lignin to electricity at low temperatures with high power output and Faradaic efficiency. When phosphomolybdic acid H3 PMo12 O40 (PMo12) was used as the electron and proton carrier in the anode solution with a carbon electrode, and O2 was directly used as the final electron acceptor under the catalysis of Pt, the peak power density reached 0.96 mW cm(-2), 560 times higher than that of phenol-fueled microbial fuel cells (MFCs). When the cathode reaction was catalyzed by PMo12, the power density could be greatly enhanced to 5 mW cm(-2). Continuous operation demonstrated that this novel fuel cell was promising as a stable electrochemical power source. Structure analysis of the lignin indicated that the hydroxyl group content was reduced whereas the carbonyl group content increased. Both condensation and depolymerization takes place during the PMo12 oxidation of lignin. PMID:26692572

  19. Deep Burn Develpment of Transuranic Fuel for High-Temperature Helium-Cooled Reactors - July 2010

    SciTech Connect

    Snead, Lance Lewis; Besmann, Theodore M; Collins, Emory D; Bell, Gary L

    2010-08-01

    The DB Program Quarterly Progress Report for April - June 2010, ORNL/TM/2010/140, was distributed to program participants on August 4. This report discusses the following: (1) TRU (transuranic elements) HTR (high temperature helium-cooled reactor) Fuel Modeling - (a) Thermochemical Modeling, (b) 5.3 Radiation Damage and Properties; (2) TRU HTR Fuel Qualification - (a) TRU Kernel Development, (b) Coating Development, (c) ZrC Properties and Handbook; and (3) HTR Fuel Recycle - (a) Recycle Processes, (b) Graphite Recycle, (c) Pyrochemical Reprocessing - METROX (metal recovery from oxide fuel) Process Development.

  20. Performance, durability and low temperature evaluation of sunflower oil as a diesel fuel extender

    SciTech Connect

    Baranescu, R.A.; Lusco, J.J.

    1982-01-01

    The paper presents the results of a research project to evaluate performance and durability of direct injection turbocharged diesel engines using sunflower oil and blends thereof. Alcaline refined sunflower oil and three different blends of sunflower oil and diesel fuel were comparatively tested against No. 2 diesel fuel for: physical and chemical characteristics, fuel injection system performance, short term engine performance, propensity to nozzle deposits buildup, limited durability operation and low temperature starting capability. Results are presented for the various phases of the project and correlations between the fuel characteristics and engine accept-ability are discussed. 19 figures, 2 tables.

  1. Hospital admissions due to diseases of arteries and veins peaked at physiological equivalent temperature -10 to 10 °C in Germany in 2009-2011.

    PubMed

    Shiue, Ivy; Perkins, David R; Bearman, Nick

    2016-04-01

    We aimed to understand relationships of the weather as biometeorological and hospital admissions due to diseases of arteries and veins by subtypes, which have been scarcely studied, in a national setting in recent years. This is an ecological study. Ten percent of daily hospital admissions from the included hospitals (n = 1,618) across Germany that were available between 1 January 2009 and 31 December 2011 (n = 5,235,600) were extracted from Statistisches Bundesamt, Germany. We identified I70-I79 Diseases of arteries, arterioles and capillaries and I80-I89 Diseases of veins, lymphatic vessels and lymph nodes by International Classification of Diseases version 10 as the study outcomes. Daily weather data from 64 weather stations that covered 13 German states including air temperature, humidity, wind speed, cloud cover, radiation flux and vapour pressure were obtained and generated into physiologically equivalent temperature (PET). Two-way fractional-polynomial prediction was plotted with 95 % confidence intervals. For most of the subtypes from diseases of arteries and veins, hospital admissions slightly peaked in spring and dropped when PET was at 10 °C. There were no other large differences across 12 months. Admissions of peripheral vascular diseases, arterial embolism and thrombosis, phlebitis and thrombophlebitis, oesophageal varices and nonspecific lymphadenitis peaked when PET was between 0 and -10 °C, while others peaked when PET was between 0 and 10 °C. More medical resources could have been needed on days when PETs were at -10 to 10 °C than on other days. Adaptation to such weather change for health professionals and the general public would seem to be imperative. PMID:26631019

  2. Analysis of the Effect of Time, Temperature, and Fuel Age on Helium Release from 238-Plutonium Dioxide Fuel

    NASA Astrophysics Data System (ADS)

    Barklay, Chadwick D.; Kramer, Daniel P.; Ruhkamp, Joseph D.

    2005-02-01

    The compound 238-plutonium dioxide has been employed over the last several decades as the fuel of choice in fabricating nuclear powered thermal to electrical converters. The alpha decay of 238-plutonium results in the generation of helium ions as a function of time. While the quantity of helium formed within the fuel can be easily calculated, its diffusion and/or release mechanism as a function of time, temperature, fuel quantity and age needs to be characterized. Within the scope of this paper the principle interest centers on determining the expected quantity of helium that will be released from solid 238-plutonium dioxide fuel forms enclosed within a primary containment vessel (PCV) under Hypothetical Accident Conditions (HAC) as described in 10 CFR 71.73(4). Once the quantity of helium released during HAC has been determined, the partial pressure increase due to the helium release can be calculated for a given shipping configuration. This partial pressure increase due to helium release during HAC for a selected shipping configuration can then be used to determine if the structural integrity of the package will be maintained or compromised during HAC. However, it is important to recognize that helium release is not a function of a particular shipping package, but as shall be demonstrated is a function of time, temperature, and fuel quantity and age.

  3. Analysis of the Effect of Time, Temperature, and Fuel Age on Helium Release from 238-Plutonium Dioxide Fuel

    SciTech Connect

    Barklay, Chadwick D.; Kramer, Daniel P.; Ruhkamp, Joseph D.

    2005-02-06

    The compound 238-plutonium dioxide has been employed over the last several decades as the fuel of choice in fabricating nuclear powered thermal to electrical converters. The alpha decay of 238-plutonium results in the generation of helium ions as a function of time. While the quantity of helium formed within the fuel can be easily calculated, its diffusion and/or release mechanism as a function of time, temperature, fuel quantity and age needs to be characterized. Within the scope of this paper the principle interest centers on determining the expected quantity of helium that will be released from solid 238-plutonium dioxide fuel forms enclosed within a primary containment vessel (PCV) under Hypothetical Accident Conditions (HAC) as described in 10 CFR 71.73(4). Once the quantity of helium released during HAC has been determined, the partial pressure increase due to the helium release can be calculated for a given shipping configuration. This partial pressure increase due to helium release during HAC for a selected shipping configuration can then be used to determine if the structural integrity of the package will be maintained or compromised during HAC. However, it is important to recognize that helium release is not a function of a particular shipping package, but as shall be demonstrated is a function of time, temperature, and fuel quantity and age.

  4. Charring temperatures are driven by the fuel types burned in a peatland wildfire

    PubMed Central

    Hudspith, Victoria A.; Belcher, Claire M.; Yearsley, Jonathan M.

    2014-01-01

    Peatlands represent a globally important carbon store; however, the human exploitation of this ecosystem is increasing both the frequency and severity of fires on drained peatlands. Yet, the interactions between the hydrological conditions (ecotopes), the fuel types being burned, the burn severity, and the charring temperatures (pyrolysis intensity) remain poorly understood. Here we present a post-burn assessment of a fire on a lowland raised bog in Co. Offaly, Ireland (All Saints Bog). Three burn severities were identified in the field (light, moderate, and deeply burned), and surface charcoals were taken from 17 sites across all burn severities. Charcoals were classified into two fuel type categories (either ground or aboveground fuel) and the reflectance of each charcoal particle was measured under oil using reflectance microscopy. Charcoal reflectance shows a positive relationship with charring temperature and as such can be used as a temperature proxy to reconstruct minimum charring temperatures after a fire event. Resulting median reflectance values for ground fuels are 1.09 ± 0.32%Romedian, corresponding to estimated minimum charring temperatures of 447°C ± 49°C. In contrast, the median charring temperatures of aboveground fuels were found to be considerably higher, 646°C ± 73°C (3.58 ± 0.77%Romedian). A mixed-effects modeling approach was used to demonstrate that the interaction effects of burn severity, as well as ecotope classes, on the charcoal reflectance is small compared to the main effect of fuel type. Our findings reveal that the different fuel types on raised bogs are capable of charring at different temperatures within the same fire, and that the pyrolysis intensity of the fire on All Saints Bog was primarily driven by the fuel types burning, with only a weak association to the burn severity or ecotope classes. PMID:25566288

  5. Porous nuclear fuel element for high-temperature gas-cooled nuclear reactors

    DOEpatents

    Youchison, Dennis L.; Williams, Brian E.; Benander, Robert E.

    2011-03-01

    Porous nuclear fuel elements for use in advanced high temperature gas-cooled nuclear reactors (HTGR's), and to processes for fabricating them. Advanced uranium bi-carbide, uranium tri-carbide and uranium carbonitride nuclear fuels can be used. These fuels have high melting temperatures, high thermal conductivity, and high resistance to erosion by hot hydrogen gas. Tri-carbide fuels, such as (U,Zr,Nb)C, can be fabricated using chemical vapor infiltration (CVI) to simultaneously deposit each of the three separate carbides, e.g., UC, ZrC, and NbC in a single CVI step. By using CVI, the nuclear fuel may be deposited inside of a highly porous skeletal structure made of, for example, reticulated vitreous carbon foam.

  6. Porous nuclear fuel element with internal skeleton for high-temperature gas-cooled nuclear reactors

    SciTech Connect

    Youchison, Dennis L.; Williams, Brian E.; Benander, Robert E.

    2013-09-03

    Porous nuclear fuel elements for use in advanced high temperature gas-cooled nuclear reactors (HTGR's), and to processes for fabricating them. Advanced uranium bi-carbide, uranium tri-carbide and uranium carbonitride nuclear fuels can be used. These fuels have high melting temperatures, high thermal conductivity, and high resistance to erosion by hot hydrogen gas. Tri-carbide fuels, such as (U,Zr,Nb)C, can be fabricated using chemical vapor infiltration (CVI) to simultaneously deposit each of the three separate carbides, e.g., UC, ZrC, and NbC in a single CVI step. By using CVI, the nuclear fuel may be deposited inside of a highly porous skeletal structure made of, for example, reticulated vitreous carbon foam.

  7. Methods for manufacturing porous nuclear fuel elements for high-temperature gas-cooled nuclear reactors

    DOEpatents

    Youchison, Dennis L.; Williams, Brian E.; Benander, Robert E.

    2010-02-23

    Methods for manufacturing porous nuclear fuel elements for use in advanced high temperature gas-cooled nuclear reactors (HTGR's). Advanced uranium bi-carbide, uranium tri-carbide and uranium carbonitride nuclear fuels can be used. These fuels have high melting temperatures, high thermal conductivity, and high resistance to erosion by hot hydrogen gas. Tri-carbide fuels, such as (U,Zr,Nb)C, can be fabricated using chemical vapor infiltration (CVI) to simultaneously deposit each of the three separate carbides, e.g., UC, ZrC, and NbC in a single CVI step. By using CVI, a thin coating of nuclear fuel may be deposited inside of a highly porous skeletal structure made, for example, of reticulated vitreous carbon foam.

  8. Temperature and voltage responses of a molten carbonate fuel cell in the presence of a hydrogen fuel leakage

    NASA Astrophysics Data System (ADS)

    Law, M. C.; Liang, G. V. Y.; Lee, V. C. C.; Wee, S. K.

    2015-04-01

    A two dimensional (2-D), dynamic model of a molten carbonate fuel cell (MCFC) was developed using COMSOL Multi-physics. The model was used to investigate the dynamic behaviour of the MCFC in the presence of hydrogen fuel leakage. A leakage was modelled as a known outflow velocity at the anode gas channel. The effects of leakage velocity and the leakage location were investigated. The simulations show that anode electrode temperature increases as the leakage velocity increases. The voltage generated is shown to decrease at the start of the leakage occurrence due to loss of hydrogen gas. Later the voltage increases as the anode temperature increases. The results also show that the changes of temperature and voltage are more significant if a leakage occurs nearer to the inlet compared to that at the outlet of anode gas channel.

  9. Sensitivity Analysis of Fuel Centerline Temperatures in SuperCritical Water-cooled Reactors (SCWRs)

    NASA Astrophysics Data System (ADS)

    Abdalla, Ayman

    SuperCritical Water-cooled Reactors (SCWRs) are one of the six nuclear-reactor concepts currently being developed under the Generation-IV International Forum (GIF). A main advantage of SCW Nuclear Power Plants (NPPs) is that they offer higher thermal efficiencies compared to those of current conventional NPPs. Unlike today's conventional NPPs, which have thermal efficiencies between 30 - 35%, SCW NPPs will have thermal efficiencies within a range of 45 - 50%, owing to high operating temperatures and pressures (i.e., coolant temperatures as high as 625°C at 25 MPa pressure). The use of current fuel bundles with UO2 fuel at the high operating parameters of SCWRs may cause high fuel centerline temperatures, which could lead to fuel failure and fission gas release. Studies have shown that when the Variant-20 (43-element) fuel bundle was examined at SCW conditions, the fuel centerline temperature industry limit of 1850°C for UO2 and the sheath temperature design limit of 850°C might be exceeded. Therefore, new fuel-bundle designs, which comply with the design requirements, are required for future use in SCWRs. The main objective of this study to conduct a sensitivity analysis in order to identify the main factors that leads to fuel centerline temperature reduction. Therefore, a 54-element fuel bundle with smaller diameter of fuel elements compared to that of the 43-element bundle was designed and various nuclear fuels are examined for future use in a generic Pressure Tube (PT) SCWR. The 54-element bundle consists of 53 heated fuel elements with an outer diameter of 9.5 mm and one central unheated element of 20-mm outer diameter which contains burnable poison. The 54-element fuel bundle has an outer diameter of 103.45 mm, which is the same as the outer diameter of the 43-element fuel bundle. After developing the 54-element fuel bundle, one-dimensional heat-transfer analysis was conducted using MATLAB and NIST REFPROP programs. As a result, the Heat Transfer

  10. Liquid Fuel Production from Biomass via High Temperature Steam Electrolysis

    SciTech Connect

    Grant L. Hawkes; Michael G. McKellar

    2009-11-01

    A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Hydrogen from electrolysis allows a high utilization of the biomass carbon for syngas production. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-fed biomass gasifier. Based on the gasifier temperature, 94% to 95% of the carbon in the biomass becomes carbon monoxide in the syngas (carbon monoxide and hydrogen). Assuming the thermal efficiency of the power cycle for electricity generation is 50%, (as expected from GEN IV nuclear reactors), the syngas production efficiency ranges from 70% to 73% as the gasifier temperature decreases from 1900 K to 1500 K. Parametric studies of system pressure, biomass moisture content and low temperature alkaline electrolysis are also presented.

  11. Effect of increased fuel temperature on emissions of oxides of nitrogen from a gas turbine combustor burning natural gas

    NASA Technical Reports Server (NTRS)

    Marchionna, N. R.

    1973-01-01

    An annular gas turbine combustor was tested with heated natural gas fuel to determine the effect of increasing fuel temperature on the formation of oxides of nitrogen. Fuel temperatures ranged from ambient to 800 K (980 F). Combustor pressure was 6 atmospheres and the inlet air temperature ranged from 589 to 894 K (600 to 1150 F). The NOx emission index increased with fuel temperature at a rate of 4 to 9 percent per 100 K (180 F), depending on the inlet air temperature. The rate of increase in NOx was lowest at the highest inlet air temperature tested.

  12. Computational fluid dynamics simulations of jet fuel flow near the freeze point temperature

    NASA Astrophysics Data System (ADS)

    Assudani, Rajee

    2006-12-01

    Under low-temperature environmental conditions, the cooling of aircraft fuel results in reduced fluidity with the potential for freezing. Therefore, it is important to study the flow and heat transfer phenomena that occur in an aircraft fuel tank near the freeze point temperature of jet fuels. The purpose of this dissertation is to study the effects of low temperatures on the flow, heat transfer and freezing of commercial and military jet fuels. The research is accomplished with the help of computational models of a thermal simulator tank and a quartz duct. Experimental results with the thermal simulator tank show that fuel flowability and pumpability decrease substantially as temperature is reduced. Time-dependent temperature and velocity distributions were numerically simulated for static cooling. Measured properties were used in all the computational fluid dynamics simulations. The calculations show that stringers, ribs, and other structures strongly promote fuel cooling. Also, the cooler, denser fuel resides near the bottom surface of the fuel tank simulator. The presence of an ullage space within the tank was found to strongly influence the fuel temperature profile by sometimes reducing cooling from the upper surface. Moreover, since the presence of ullage space is an explosion risk, some military aircraft fuel tanks are fitted with explosion suppressant polyurethane foam. To study the effect of foam on the flowability and heat transfer inside the simulator tank, the wing tank thermal simulator was filled with military specified polyurethane foam. The tank was simultaneously drained and cooled and the mass flow rate results showed that flowability of the fuel is not affected by the presence of foam. However, the presence of foam certainly affected the heat transfer phenomenon inside the fuel tank when the simulator tank was cooled and drained simultaneously. To study the freezing behavior of jet fuel under forced flow conditions, a quartz duct was fabricated

  13. Use of a commercial heat transfer code to predict horizontally oriented spent fuel rod surface temperatures

    SciTech Connect

    Wix, S.D.; Koski, J.A.

    1993-03-01

    Radioactive spent fuel assemblies are a source of hazardous waste that will have to be dealt with in the near future. It is anticipated that the spent fuel assemblies will be transported to disposal sites in spent fuel transportation casks. In order to design a reliable and safe transportation cask, the maximum cladding temperature of the spent fuel rod arrays must be calculated. A comparison between numerical calculations using commercial thermal analysis software packages and experimental data simulating a horizontally oriented spent fuel rod array was performed. Twelve cases were analyzed using air and helium for the fill gas, with three different heat dissipation levels. The numerically predicted temperatures are higher than the experimental data for all levels of heat dissipation with air as the fill gas. The temperature differences are 4{degree}C and 23{degree}C for the low heat dissipation and high heat dissipation, respectively. The temperature predictions using helium as a fill gas are lower for the low and medium heat dissipation levels, but higher at the high heat dissipation. The temperature differences are 1{degree}C and 6{degree}C for the low and medium heat dissipation, respectively. For the high heat dissipation level, the temperature predictions are 16{degree}C higher than the experimental data. Differences between the predicted and experimental temperatures can be attributed to several factors. These factors include experimental uncertainty in the temperature and heat dissipation measurements, actual convection effects not included in the model, and axial heat flow in the experimental data. This work demonstrates that horizontally oriented spent fuel rod surface temperature predictions can be made using existing commercial software packages. This work also shows that end effects will be increasingly important as the amount of dissipated heat increases.

  14. Experimental investigation on circumferential and axial temperature gradient over fuel channel under LOCA

    NASA Astrophysics Data System (ADS)

    Yadav, Ashwini Kumar; kumar, Ravi; Gupta, Akhilesh; Chatterjee, Barun; Mukhopadhyay, Deb; Lele, H. G.

    2014-06-01

    In a nuclear reactor temperature rises drastically in fuel channels under loss of coolant accident due to failure of primary heat transportation system. Present investigation has been carried out to capture circumferential and axial temperature gradients during fully and partially voiding conditions in a fuel channel using 19 pin fuel element simulator. A series of experiments were carried out by supplying power to outer, middle and center rods of 19 pin fuel simulator in ratio of 1.4:1.1:1. The temperature at upper periphery of pressure tube (PT) was slightly higher than at bottom due to increase in local equivalent thermal conductivity from top to bottom of PT. To simulate fully voided conditions PT was pressurized at 2.0 MPa pressure with 17.5 kW power injection. Ballooning initiated from center and then propagates towards the ends and hence axial temperature difference has been observed along the length of PT. For asymmetric heating, upper eight rods of fuel simulator were activated and temperature difference up-to 250 °C has been observed from top to bottom periphery of PT. Such situation creates steep circumferential temperature gradient over PT and could lead to breaching of PT under high pressure.

  15. New Optical Sensor Suite for Ultrahigh Temperature Fossil Fuel Applications

    SciTech Connect

    Russell G. May; Tony Peng; Gary Pickrell

    2005-10-31

    Development of practical, high-temperature optical claddings for improved waveguiding in sapphire fibers continued during the reporting period. A set of designed experiments using the Taguchi method was undertaken to efficiently determine the optimal set of processing variables to yield clad fibers with good optical and mechanical properties. Eighteen samples of sapphire fibers were prepared with spinel claddings, each with a unique set of variables. Statistical analyses of the results were then used to predict the set of factors that would result in a spinel cladding with the optimal geometrical, mechanical, and optical properties. To confirm the predictions of the Taguchi analysis, sapphire fibers were clad with the magnesium aluminate spinel coating using the predicted optimal set of factors. In general, the clad fibers demonstrated high quality, exceeding the best results obtained during the Phase I effort. Tests of the high-temperature stability of the clad fibers were also conducted. The results indicated that the clad fibers were stable at temperatures up to 1300 C for the duration of the three day test. At the higher temperatures, some changes in the geometry of the fibers were observed. The design, fabrication, and testing of a sapphire sensor for measurement of temperature was undertaken. The specific sensor configuration uses a polished sapphire wafer as the temperature-sensitive element. The wafer is attached to a sapphire fiber (clad or unclad), and interrogated as a Fabry-Perot sensor. Methods for assembling the sensor were investigated. A prototype sensor was fabricated and tested at room temperature and elevated temperatures. Results were difficult to interpret, due to the presence of modal noise which was found to result from the use of a spectrometer that was not designed for use with multimode fibers. A spectrometer optimized for use of multimode fiber has been obtained, and further evaluation of the sapphire temperature sensor is continuing.

  16. The Effects of Engine Speed and Mixture Temperature on the Knocking Characteristics of Several Fuels

    NASA Technical Reports Server (NTRS)

    Lee, Dana W

    1940-01-01

    Six 100-octane and two 87-octane aviation engine fuels were tested in a modified C.F.R. variable-compression engine at 1,500, 2,000 and 2,500 rpm. The mixture temperature was raised from 50 to 300 F in approximately 50 degree steps and, at each temperature, the compression ratio was adjusted to give incipient knock as shown by a cathode ray indicator. The results are presented in tabular form. The results are analyzed on the assumption that the conditions which determine whether a given fuel will knock are the maximum values of density and temperature reached by the burning gases. A maximum permissible density factor, proportional to the maximum density of the burning gases just prior to incipient knock, and the temperature of the burning gases at that time were computed for each of the test conditions. Values of the density factors were plotted against the corresponding end-gas temperatures for the three engine speeds and also against engine speed for several and end-gas temperatures. The maximum permissible density factor varied only slightly with engine speed but decreased rapidly with an increase in the end-gas temperature. The effect of changing the mixture temperature was different for fuels of different types. The results emphasize the desirability of determining the anti knock values of fuels over a wide range of engine and intake-air conditions rather that at a single set of conditions.

  17. High temperature solid electrolyte fuel cell with ceramic electrodes

    DOEpatents

    Marchant, David D.; Bates, J. Lambert

    1984-01-01

    A solid oxide electrolyte fuel cell is described having a central electrolyte comprised of a HfO.sub.2 or ZrO.sub.2 ceramic stabilized and rendered ionically conductive by the addition of Ca, Mg, Y, La, Nd, Sm, Gd, Dy Er, or Yb. The electrolyte is sandwiched between porous electrodes of a HfO.sub.2 or ZrO.sub.2 ceramic stabilized by the addition of a rare earth and rendered electronically conductive by the addition of In.sub.2 O.sub.3. Alternatively, the anode electrode may be made of a metal such as Co, Ni, Ir Pt, or Pd.

  18. High temperature solid electrolyte fuel cell with ceramic electrodes

    DOEpatents

    Bates, J.L.; Marchant, D.D.

    A solid oxide electrolyte fuel cell is described having a central electrolyte comprised of a HfO/sub 2/ or ZrO/sub 2/ ceramic stabilized and rendered ionically conductive by the addition of Ca, Mg, Y, La, Nd, Sm, Gd, Dy Er, or Yb. The electrolyte is sandwiched between porous electrodes of a HfO/sub 2/ or ZrO/sub 2/ ceramic stabilized by the addition of a rare earth and rendered electronically conductive by the addition of In/sub 2/O/sub 3/. Alternatively, the anode electrode may be made of a metal such as Co, Ni, Ir Pt, or Pd.

  19. Low-temperature ignition of droplets of suspension organic water-carbon fuels

    NASA Astrophysics Data System (ADS)

    Nakoryakov, V. E.; Glushkov, D. O.; Kuznetsov, G. V.; Strizhak, P. A.

    2016-07-01

    The conditions and integral characteristics of stable low-temperature ignition of droplets of suspension organic water-coal fuels are established by using the means of high-speed video-detection. The oxidizer temperature for these conditions varies in the range of 600-900 K (much below the temperatures in furnace chambers of modern power installations exceeding 1200 K). The velocity of the oxidizer-flow motion varies from 0.5 to 5 m/s, and the sizes (conditional radii) of droplets vary from 0.5 to 1.5 mm. The times of initiation of burning under conditions of low-temperature heating and the duration of the complete combustion of droplets of the corresponding compositions of organic water-coal fuels are determined. The necessary and sufficient conditions of stable ignition are singled out for promising organic water-coal fuels.

  20. Determination of the Effects of Speed, Temperature, and Fuel Factors on Exhaust Emissions

    NASA Astrophysics Data System (ADS)

    Chou, Chia-Yang David

    1995-11-01

    This study provided a comprehensive approach to examining the relative significance and possible synergistic effects of speed, temperature, and fuel on mobile source emissions modeling. Eleven passenger vehicles from three fuel delivery system control groups were tested, namely, three from carburetor (CARBU), three from throttle body injection (TBI), and five from multi-port fuel injection (MPFI) group. A minimum of 90 tests were conducted on each vehicle with a random combination of three fuel types (Phase 1, Phase 2, and Indolene), three temperatures (50 F, 75 F, and 100 F), and ten speed cycles. Each vehicle was repeated for ten speed cycles (75 F and Indolene). In general, exhaust emissions descended in the order of CARBU, TBI, and MPFI. All vehicles in the CARBU group contained a "dead" catalyst, which probably explained why vehicles in CARBU were "high emitters.". Results from the paired t-test indicated that exhaust emissions difference between Phase 1 and Phase 2 fuels for all vehicles was significant. The net exhaust emissions reduction of Phase 2 over Phase 1 fuel for HC and NOx was 21% and 12%, respectively; which is in good agreements with the CARB projected 17% HC (including evaporative and exhaust emissions) and 11% CO emissions reduction based on 1996 calendar year when Phase 2 fuel is introduced. Temperature had minimal effects on exhaust emissions especially the test cycles were in hot-stabilized mode. Nevertheless, exhaust emissions from cold-start mode were higher than hot-start mode because the catalyst had not reached to optimal operating temperature during the cold-start mode. The relative contributions of speed, temperature, and fuel to exhaust emissions were determined using analysis of variance (ANOVA) and it was found interaction terms among fuel, speed, and temperature were statistically insignificant. Individually, the temperature and fuel factor played a minor role in exhaust emission modeling. Speed and vehicle type were the two

  1. Effect of particle size on activation energy and peak temperature of the thermoluminescence glow curve of undoped ZnS nanoparticles.

    PubMed

    Chandra, B P; Chandrakar, Raju Kumar; Chandra, V K; Baghel, R N

    2016-03-01

    This paper reports the effect of particle size on the thermoluminescence (TL) of undoped ZnS nanoparticles. ZnS nanoparticles were prepared using a chemical precipitation method in which mercaptoethanol was used as the capping agent. The nanoparticles were characterized by X-ray diffraction, field emission gun-scanning electron microscopy and high-resolution transmission electron microscopy. When the concentrations of mercaptoethanol used are 0, 0.005, 0.01, 0.015, 0.025, 0.040 and 0.060 M, the sizes of the nanoparticles are 2.86, 2.81, 2.69, 2.40, 2.10, 1.90 and 1.80 nm, respectively. Initially, the TL intensity of UV-irradiated ZnS nanoparticles increases with temperature, attains a peak value Im for a particular temperature Tm, and then decreases with further increases in temperature. The values of both Im and Tm increase with decreasing nanoparticle size. Whereas the activation energy decreases slightly with decreasing nanoparticle size, the frequency factor decreases significantly as the nanoparticle size is reduced. The order of kinetics for the TL glow curve of ZnS nanoparticles is 2. Expressions are derived for the dependence of activation energy (Ea) and Tm on nanoparticle size, and good agreement is found between the experimental and theoretical results. PMID:26332287

  2. NEW OPTICAL SENSOR SUITE FOR ULTRAHIGH TEMPERATURE FOSSIL FUEL APPLICATIONS

    SciTech Connect

    Russell G. May; Tony Peng; Tom Flynn

    2004-12-01

    Accomplishments during the Phase I of a program to develop and demonstrate technology for the instrumentation of advanced powerplants are described. Engineers from Prime Research, LC and Babcock and Wilcox Research Center collaborated to generate a list of potential applications for robust photonic sensors in existing and future boiler plants. From that list, three applications were identified as primary candidates for initial development and demonstration of high-temperature sensors in an ultrasupercritical power plant. A matrix of potential fiber optic sensor approaches was derived, and a data set of specifications for high-temperature optical fiber was produced. Several fiber optic sensor configurations, including interferometric (extrinsic and intrinsic Fabry-Perot interferometer), gratings (fiber Bragg gratings and long period gratings), and microbend sensors, were evaluated in the laboratory. In addition, progress was made in the development of materials and methods to apply high-temperature optical claddings to sapphire fibers, in order to improve their optical waveguiding properties so that they can be used in the design and fabrication of high-temperature sensors. Through refinements in the processing steps, the quality of the interface between core and cladding of the fibers was improved, which is expected to reduce scattering and attenuation in the fibers. Numerical aperture measurements of both clad and unclad sapphire fibers were obtained and used to estimate the reduction in mode volume afforded by the cladding. High-temperature sensors based on sapphire fibers were also investigated. The fabrication of an intrinsic Fabry-Perot cavity within sapphire fibers was attempted by the bulk diffusion of magnesium oxide into short localized segments of longer sapphire fibers. Fourier analysis of the fringes that resulted when the treated fiber was interrogated by a swept laser spectrometer suggested that an intrinsic cavity had been formed in the fiber. Also

  3. Temperature Distributions in LMR Fuel Pin Bundles as Modeled by COBRA-IV-I

    NASA Astrophysics Data System (ADS)

    Wright, Steven A.; Stout, Sherry

    2005-02-01

    Most pin type reactor designs for space power or terrestrial applications group the fuel pins into a number of relatively large fuel pin bundles or subassemblies. Fuel bundles for terrestrial liquid metal fast breeders reactors typically use 217 - 271 pins per sub-assembly, while some SP100 designs use up to 331 pins in a central subassembly that was surrounded by partial assemblies. Because thermal creep is exponentially related to temperature, small changes in fuel pin cladding temperature can make large differences in the lifetime in a high temperature liquid metal reactor (LMR). This paper uses the COBRA-IV-I computer code to determine the temperature distribution within LMR fuel bundles. COBRA-IV-I uses the sub-channel analysis approach to determine the enthalpy (or temperature) and flow distribution in rod bundles for both steady-state and transient conditions. The COBRA code runs in only a few seconds and has been benchmarked and tested extensively over a wide range of flow conditions. In this report the flow and temperature distributions for two types of lithium cooled space reactor core designs were calculated. One design uses a very tight fuel pin packing that has a pitch to diameter ratio of 1.05 (small wire wrap with a diameter of 392 μm) as proposed in SP100. The other design uses a larger pitch to diameter ratio of 1.09 with a larger more conventional sized wire wrap diameter of 1 mm. The results of the COBRA pin bundle calculations show that the larger pitch-to-diameter fuel bundle designs are more tolerant to local flow blockages, and in addition they are less sensitive to mal-flow distributions that occur near the edges of the subassembly.

  4. Temperature Distributions in LMR Fuel Pin Bundles as Modeled by COBRA-IV-I

    SciTech Connect

    Wright, Steven A.; Stout, Sherry

    2005-02-06

    Most pin type reactor designs for space power or terrestrial applications group the fuel pins into a number of relatively large fuel pin bundles or subassemblies. Fuel bundles for terrestrial liquid metal fast breeders reactors typically use 217 - 271 pins per sub-assembly, while some SP100 designs use up to 331 pins in a central subassembly that was surrounded by partial assemblies. Because thermal creep is exponentially related to temperature, small changes in fuel pin cladding temperature can make large differences in the lifetime in a high temperature liquid metal reactor (LMR). This paper uses the COBRA-IV-I computer code to determine the temperature distribution within LMR fuel bundles. COBRA-IV-I uses the sub-channel analysis approach to determine the enthalpy (or temperature) and flow distribution in rod bundles for both steady-state and transient conditions. The COBRA code runs in only a few seconds and has been benchmarked and tested extensively over a wide range of flow conditions. In this report the flow and temperature distributions for two types of lithium cooled space reactor core designs were calculated. One design uses a very tight fuel pin packing that has a pitch to diameter ratio of 1.05 (small wire wrap with a diameter of 392 {mu}m) as proposed in SP100. The other design uses a larger pitch to diameter ratio of 1.09 with a larger more conventional sized wire wrap diameter of 1 mm. The results of the COBRA pin bundle calculations show that the larger pitch-to-diameter fuel bundle designs are more tolerant to local flow blockages, and in addition they are less sensitive to mal-flow distributions that occur near the edges of the subassembly.

  5. Novel Electrode Materials for Low-Temperature Solid-Oxide Fuel Cells

    SciTech Connect

    Shaowu Zha; Meilin Liu

    2005-03-23

    Composites electrodes consisting of silver and bismuth vanadates exhibit remarkable catalytic activity for oxygen reduction at 500-550 C and greatly reduce the cathode-electrolyte (doped ceria) resistances of low temperature SOFCs, down to about 0.53 {omega}cm{sup 2} at 500 C and 0.21 {omega}cm{sup 2} at 550 C. The observed power densities of 231, 332, and 443 mWcm-2 at 500, 525 and 550 C, respectively, make it possible to operate SOFCs at temperatures about 500 C. Fuel cell performance depends strongly on the anode microstructure, which is determined by the anode compositions and fabrication conditions. Four types of anodes with two kinds of NiO and GDC powders were investigated. By carefully adjusting the anode microstructure, the GDC electrolyte/anode interfacial polarization resistances reduced dramatically. The interfacial resistance at 600 C decreased from 1.61 {omega} cm{sup 2} for the anodes prepared using commercially available powders to 0.06 {omega} cm{sup 2} for those prepared using powders derived from a glycine-nitrate process. Although steam reforming or partial oxidation is effective in avoiding carbon deposition of hydrocarbon fuels, it increases the operating cost and reduces the energy efficiency. Anode-supported SOFCs with an electrolyte of 20 {micro}m-thick Gd-doped ceria (GDC) were fabricated by co-pressing. A catalyst (1 %wt Pt dispersed on porous Gd-doped ceria) for pre-reforming of propane was developed with relatively low steam to carbon (S/C) ratio ({approx}0.5), coupled with direct utilization of the reformate in low-temperature SOFCs. Propane was converted to smaller molecules during pre-reforming, including H{sub 2}, CH{sub 4}, CO, and CO{sub 2}. A peak power density of 247 mW/cm{sup 2} was observed when pre-reformed propane was directly fed to an SOFC operated at 600 C. No carbon deposition was observed in the fuel cell for a continuous operation of 10 hours at 600 C. The ability of producing vastly different microstructures and

  6. Novel Method for Measuring Temperature Distribution within Fuel Cell using Microsensors

    NASA Astrophysics Data System (ADS)

    Lee, Chi-Yuan; Hsieh, Chi-Lieh; Wu, Guan-Wei

    2007-05-01

    A fuel cell has the potential to become an important source of electric power. However, measuring the temperature inside the fuel cell is difficult. Hence, in this investigation, an array of microsensors is set up inside the fuel cell to measure the temperature distribution. The substrate of a bipolar plate in the fuel cell is stainless steel (SS-316) and an electroforming technique is implemented to fabricate channels in the stainless steel substrate. Then micro-electro-mechanical system (MEMS) technologies are employed to fabricate a platinum temperature sensor on the rib of a channel in the stainless steel substrate. In this experiment, the temperature of microsensor is measured to range from 31 to 80 °C and its resistance ranges from 0.593 to 0.649 Ω. Experimental results demonstrate that temperature is almost linearly related to resistance and that accuracy and sensitivity are 0.5 °C and 1.93× 10-3/°C, respectively. The performance curves of a single fuel cell operating at 34 °C and H2/O2 gas flow rates of 50/50 ml/min are determined. The maximum power density is 170 mW/cm2 and the current density is 513 mA/cm2.

  7. Ignition of blended-fuel droplet in high-temperature atmosphere

    SciTech Connect

    Takei, M.; Tsukamoto, T.; Niioka, T. )

    1993-04-01

    Ignition time of a suspended fuel droplet is obtained experimentally with high ambient temperature. A stationary fuel droplet suspended by a fine silica fiber is taken into a furnace moving on rail and is quickly exposed to high ambient temperature. Blended fuels of n-heptane and n-hexadecane are used, and the effects of fuel mixture ratio, initial droplet diameter, and ambient air temperature on ignition time are observed. For pure hexadecane droplets, ignition time increases with the increase in initial droplet diameter. On the other hand, it decreases for pure heptane, especially under lower ambient temperatures. For the case of mixed fuel, the variation of ignition time with the initial droplet diameter has a characteristic feature, namely the results show that an initial droplet diameter exists at which the ignition time has the maximum value and that this diameter increases with a decrease of the heptane concentration or the ambient temperature. The maximum ignition time is also confirmed by the combination of ethylalcohol and decylalcohol.

  8. An earthquake transient method for pebble-bed reactors and a fuel temperature model for TRISO fueled reactors

    NASA Astrophysics Data System (ADS)

    Ortensi, Javier

    This investigation is divided into two general topics: (1) a new method for analyzing the safe shutdown earthquake event in a pebble bed reactor core, and (2) the development of an explicit tristructural-isotropic fuel model for high temperature reactors. The safe shutdown earthquake event is one of the design basis accidents for the pebble bed reactor. The new method captures the dynamic geometric compaction of the pebble bed core. The neutronic and thermal-fluids grids are dynamically re-meshed to simulate the re-arrangement of the pebbles in the reactor during the earthquake. Results are shown for the PBMR-400 assuming it is subjected to the Idaho National Laboratory's design basis earthquake. The study concludes that the PBMR-400 can safely withstand the reactivity insertions induced by the slumping of the core and the resulting relative withdrawal of the control rods. This characteristic stems from the large negative Doppler feedback of the fuel. This Doppler feedback mechanism is a major contributor to the passive safety of gas-cooled, graphite-moderated, high-temperature reactors that use fuel based on TRISO particles. The correct prediction of the magnitude and time-dependence of this feedback effect is essential to the conduct of safety analyses for these reactors. An explicit TRISO fuel temperature model named THETRIS has been developed in this work and incorporated in the CYNOD-THERMIX-KONVEK suite of coupled codes. The new model yields similar results to those obtained with more complex methods, requiring multi-TRISO calculations within one control volume. The performance of the code during fast and moderately-slow transients is verified. These analyses show how explicit TRISO models improve the predictions of the fuel temperature, and consequently, of the power escalation. In addition, a brief study of the potential effects on the transient behavior of high-temperature reactors due to the presence of a gap inside the TRISO particles is included

  9. Photo-Activated Low Temperature, Micro Fuel Cell Power Source

    SciTech Connect

    Harry L. Tuller

    2007-03-30

    A Key objective of this program is to identify electrodes that will make it possible to significantly reduce the operating temperature of micro-SOFC and thin film-based SOFCs. Towards this end, efforts are directed towards: (a) identifying the key rate limiting steps which limit presently utilized electrodes from performing at reduced temperatures, as well as, (b) investigating the use of optical, as opposed to thermal energy, as a means for photocatalyzing electrode reactions and enabling reduced operating temperatures. During Phase I, the following objectives were achieved: (a) assembly and testing of our unique Microprobe Thin Film Characterization System; (b) fabrication of the model cathode materials system in thin film form by both PLD and ink jet printing; and (c) the successful configuration and testing of the model materials as cathodes in electrochemical cells. A further key objective (d) to test the potential of illumination in enhancing electrode performance was also achieved.

  10. NEW OPTICAL SENSOR SUITE FOR ULTRAHIGH TEMPERATURE FOSSIL FUEL APPLICATIONS

    SciTech Connect

    Russell G. May; Tony Peng; Tom Flynn

    2004-04-01

    Accomplishments during the first six months of a program to develop and demonstrate technology for the instrumentation of advanced powerplants are described. Engineers from Prime Research, LC and Babcock and Wilcox Research Center collaborated to generate a list of potential applications for robust photonic sensors in existing and future boiler plants. From that list, three applications were identified as primary candidates for initial development and demonstration of high-temperature sensors in an ultrasupercritical power plant. In addition, progress was made in the development of materials and methods to apply high-temperature optical claddings to sapphire fibers, in order to improve their optical waveguiding properties so that they can be used in the design and fabrication of high-temperature sensors. Through refinements in the processing steps, the quality of the interface between core and cladding of the fibers was improved, which is expected to reduce scattering and attenuation in the fibers.

  11. Durability of symmetrically and asymmetrically porous polybenzimidazole membranes for high temperature proton exchange membrane fuel cells

    NASA Astrophysics Data System (ADS)

    Jheng, Li-Cheng; Chang, Wesley Jen-Yang; Hsu, Steve Lien-Chung; Cheng, Po-Yang

    2016-08-01

    Two types of porous polybenzimidazole (PBI) membranes with symmetric and asymmetric morphologies were fabricated by the template-leaching method and characterized by scanning electron microscope (SEM). Their physicochemical properties were compared in terms of acid-doping level, proton conductivity, mechanical strength, and oxidative stability. The durability of fuel cell operation is one of the most challenging for the PBI based membrane electrode assembly (MEA) used in high-temperature proton exchange membrane fuel cells (HT-PEMFCs). In the present work, we carried out a long-term steady-state fuel cell test to compare the effect of membrane structure on the cell voltage degradation. It has also been demonstrated that the asymmetrically porous PBI could bring some notable improvements on the durability of fuel cell operation, the fuel crossover problem, and the phosphoric acid leakage.

  12. High temperature gas-cooled reactor (HTGR) graphite pebble fuel: Review of technologies for reprocessing

    SciTech Connect

    Mcwilliams, A. J.

    2015-09-08

    This report reviews literature on reprocessing high temperature gas-cooled reactor graphite fuel components. A basic review of the various fuel components used in the pebble bed type reactors is provided along with a survey of synthesis methods for the fabrication of the fuel components. Several disposal options are considered for the graphite pebble fuel elements including the storage of intact pebbles, volume reduction by separating the graphite from fuel kernels, and complete processing of the pebbles for waste storage. Existing methods for graphite removal are presented and generally consist of mechanical separation techniques such as crushing and grinding chemical techniques through the use of acid digestion and oxidation. Potential methods for reprocessing the graphite pebbles include improvements to existing methods and novel technologies that have not previously been investigated for nuclear graphite waste applications. The best overall method will be dependent on the desired final waste form and needs to factor in the technical efficiency, political concerns, cost, and implementation.

  13. Development of low temperature solid oxide fuel cells

    SciTech Connect

    Bakker, W.T.; Goldstein, R.

    1996-12-31

    The historical focus of the electric utility industry has been central station power plants. These plants are usually sited outside urban areas and electricity was delivered via high voltage transmission lines. Several things are beginning to change this historical precedent One is the popular concern with EMF as a health hazard. This has rendered the construction of new lines as well as upgrading old ones very difficult. Installation of power generating equipment near the customer enables the utility to better utilize existing transmission and distribution networks and defer investments. Power quality and lark of disturbances and interruptions is also becoming increasingly more important to many customers. Grid connected, but dedicated small power plants can greatly improve power quality. Finally the development of high efficiency, low emission, modular fuel cells promises near pollution free localized power generation with an efficiency equal to or exceeding that of even the most efficient central power stations.

  14. Infrared spectroscopic and conductivity studies of ureasil-based proton conducting membranes for medium temperature fuel cell applications.

    PubMed

    Vince, Jelica; Vuk, Angela Šurca; Stangar, Urška Lavrenčič; Perše, Lidija Slemenik; Orel, Boris; Hočevar, Stanko

    2010-12-01

    Proton conducting membranes for fuel cells were prepared by the sol-gel process from two different ureasil organic-inorganic hybrid precursors: bis[(N-(3-triethoxysilylpropyl)ureido]-terminated poly(propylene glycol) 4000 (PPGU) and bis[3-(N-(3-triethoxysilylpropyl)ureido)propyl]-terminated poly(dimethylsiloxane) 1000 (PDMSU). Heteropoly silicotungstic acid was added to actuate the reactions of hydrolysis and condensation and to introduce proton conductivity. XRD measurements of membranes revealed the presence of a diffraction peak at 6.3°, which could be ascribed to gradual formation of R-(SiO3/2) silsesquioxane clusters, i.e. arrangement of the Si-O-Si skeleton on the nano-scale. TG and DSC measurements showed thermal stability of the membranes above 120 °C. Proton conductivities at room temperature were of the order of 10-4 to 10-3 S/cm, classifying the membranes in the group of super ionic conductors. At elevated temperatures up to 160 °C and at conditions of autogenous pressure, conductivities increased up to values acceptable for fuel cells of 10-1 S/cm, which could be the result of the presence of H3O+ ions. The protonation of the urea groups and the formation of amidonium ions [C(OH)=NH+] were followed using IR ATR spectroscopy. PMID:24061888

  15. Proposal of the Atmospheric Pressure Turbine (APT) and High Temperature Fuel Cell Hybrid System

    NASA Astrophysics Data System (ADS)

    Tsujikawa, Yoshiharu; Kaneko, Ken-Ichi; Suzuki, Jun

    Solid oxide fuel cell (SOFC) has been extensively developed in many countries as an ultra-high efficient energy converter. Such high temperature fuel cell can be operated as a hybrid system of integrating of turbo machinery. A major decision is whether to place the cell stack in pressurized or unpressurized section. This paper discusses the exhaust energy recovery from fuel cells by use of turbo machines under unpressurized conditions, working with inverted Brayton cycle in which turbine expansion, cooling by heat exchanger and draft by compressor are made in an open cycle mode. It is denoted as “atmospheric pressure turbine (APT)”.

  16. Fuel performance models for high-temperature gas-cooled reactor core design

    SciTech Connect

    Stansfield, O.M.; Simon, W.A.; Baxter, A.M.

    1983-09-01

    Mechanistic fuel performance models are used in high-temperature gas-cooled reactor core design and licensing to predict failure and fission product release. Fuel particles manufactured with defective or missing SiC, IPyC, or fuel dispersion in the buffer fail at a level of less than 5 x 10/sup -4/ fraction. These failed particles primarily release metallic fission products because the OPyC remains intact on 90% of the particles and retains gaseous isotopes. The predicted failure of particles using performance models appears to be conservative relative to operating reactor experience.

  17. Full-length high-temperature severe fuel damage test No. 5

    SciTech Connect

    Lanning, D.D.; Lombardo, N.J.; Hensley, W.K.; Fitzsimmons, D.E.; Panisko, F.E.; Hartwell, J.K.

    1993-09-01

    This report describes and presents data from a severe fuel damage test that was conducted in the National Research Universal (NRU) reactor at Chalk River Nuclear Laboratories (CRNL), Ontario, Canada. The test, designated FLHT-5, was the fourth in a series of full-length high-temperature (FLHT) tests on light-water reactor fuel. The tests were designed and performed by staff from the US Department of Energy`s Pacific Northwest Laboratory (PNL), operated by Battelle Memorial Institute. The test operation and test results are described in this report. The fuel bundle in the FLHT-5 experiment included 10 unirradiated full-length pressurized-water reactor (PWR) rods, 1 irradiated PWR rod and 1 dummy gamma thermometer. The fuel rods were subjected to a very low coolant flow while operating at low fission power. This caused coolant boilaway, rod dryout and overheating to temperatures above 2600 K, severe fuel rod damage, hydrogen generation, and fission product release. The test assembly and its effluent path were extensively instrumented to record temperatures, pressures, flow rates, hydrogen evolution, and fission product release during the boilaway/heatup transient. Post-test gamma scanning of the upper plenum indicated significant iodine and cesium release and deposition. Both stack gas activity and on-line gamma spectrometer data indicated significant ({approximately}50%) release of noble fission gases. Post-test visual examination of one side of the fuel bundle revealed no massive relocation and flow blockage; however, rundown of molten cladding was evident.

  18. High Temperature Corrosion Problem of Boiler Components in presence of Sulfur and Alkali based Fuels

    NASA Astrophysics Data System (ADS)

    Ghosh, Debashis; Mitra, Swapan Kumar

    2011-04-01

    Material degradation and ageing is of particular concern for fossil fuel fired power plant components. New techniques/approaches have been explored in recent years for Residual Life assessment of aged components and material degradation due to different damage mechanism like creep, fatigue, corrosion and erosion etc. Apart from the creep, the high temperature corrosion problem in a fossil fuel fired boiler is a matter of great concern if the fuel contains sulfur, chlorine sodium, potassium and vanadium etc. This paper discusses the material degradation due to high temperature corrosion in different critical components of boiler like water wall, superheater and reheater tubes and also remedial measures to avoid the premature failure. This paper also high lights the Residual Life Assessment (RLA) methodology of the components based on high temperature fireside corrosion. of different critical components of boiler.

  19. The coupling influence of airflow and temperature on the wall-wetted fuel film distribution

    SciTech Connect

    Cheng, Yong-sheng; Deng, Kangyao; Li, Tao

    2010-02-15

    The coupling influence of airflow and temperature on the two-dimensional distribution of the film resulted from fuel spray impinging on a horizontal flat wall was studied with experiments. The horizontal airflow direction was perpendicular to the vertical axis of the injection spray. The results show that, as air velocity increases, the film shape turns from a circle to an oblong. As wall temperature increases, the film area shrinks. Film thickness decreases as wall temperature or air velocity increases. The boiling point of the fuel is an important temperature to affect the film area and the film thickness. Film center moves more far away in the downstream direction as air velocity increases. For a certain air velocity, film center moves less far away as wall temperature increases. (author)

  20. Combustion studies of coal derived solid fuels by thermogravimetric analysis. III. Correlation between burnout temperature and carbon combustion efficiency

    USGS Publications Warehouse

    Rostam-Abadi, M.; DeBarr, J.A.; Chen, W.T.

    1990-01-01

    Burning profiles of 35-53 ??m size fractions of an Illinois coal and three partially devolatilized coals prepared from the original coal were obtained using a thermogravimetric analyzer. The burning profile burnout temperatures were higher for lower volatile fuels and correlated well with carbon combustion efficiencies of the fuels when burned in a laboratory-scale laminar flow reactor. Fuels with higher burnout temperatures had lower carbon combustion efficiencies under various time-temperature conditions in the laboratory-scale reactor. ?? 1990.

  1. Promotion of Oxygen Reduction by Exsolved Silver Nanoparticles on a Perovskite Scaffold for Low-Temperature Solid Oxide Fuel Cells.

    PubMed

    Zhu, Yinlong; Zhou, Wei; Ran, Ran; Chen, Yubo; Shao, Zongping; Liu, Meilin

    2016-01-13

    Solid oxide fuel cells (SOFCs) have potential to be the cleanest and most efficient electrochemical energy conversion devices with excellent fuel flexibility. To make SOFC systems more durable and economically competitive, however, the operation temperature must be significantly reduced, which depends sensitively on the development of highly active electrocatalysts for oxygen reduction reaction (ORR) at low temperatures. Here we report a novel silver nanoparticle-decorated perovskite oxide, prepared via a facile exsolution process from a Sr0.95Ag0.05Nb0.1Co0.9O3-δ (SANC) perovskite precursor, as a highly active and robust ORR electrocatalyst for low-temperature SOFCs. The exsolved Sr0.95Ag0.05Nb0.1Co0.9O3-δ (denoted as e-SANC) electrode is very active for ORR, achieving a very low area specific resistance (∼0.214 Ω cm(2) at 500 °C). An anode-supported cell with the new heterostructured cathode demonstrates very high peak power density (1116 mW cm(-2) at 500 °C) and stable operation for 140 h at a current density of 625 mA cm(-2). The superior ORR activity and stability are attributed to the fast oxygen surface exchange kinetics and the firm adhesion of the Ag nanoparticles to the Sr0.95Nb0.1Co0.9O3-δ (SNC0.95) support. Moreover, the e-SANC cathode displays improved tolerance to CO2. These unique features make the new heterostructured material a highly promising cathode for low-temperature SOFCs. PMID:26619096

  2. Processing of FRG high-temperature gas-cooled reactor fuel elements at General Atomic under the US/FRG cooperative agreement for spent fuel elements

    SciTech Connect

    Holder, N.D.; Strand, J.B.; Schwarz, F.A.; Drake, R.N.

    1981-11-01

    The Federal Republic of Germany (FRG) and the United States (US) are cooperating on certain aspects of gas-cooled reactor technology under an umbrella agreement. Under the spent fuel treatment development section of the agreement, both FRG mixed uranium/ thorium and low-enriched uranium fuel spheres have been processed in the Department of Energy-sponsored cold pilot plant for high-temperature gas-cooled reactor (HTGR) fuel processing at General Atomic Company in San Diego, California. The FRG fuel spheres were crushed and burned to recover coated fuel particles suitable for further treatment for uranium recovery. Successful completion of the tests described in this paper demonstrated certain modifications to the US HTGR fuel burining process necessary for FRG fuel treatment. Results of the tests will be used in the design of a US/FRG joint prototype headend facility for HTGR fuel.

  3. MATERIALS SYSTEM FOR INTERMEDIATE TEMPERATURE SOLID OXIDE FUEL CELL

    SciTech Connect

    Uday B. Pal; Srikanth Gopalan

    2004-02-15

    AC complex impedance spectroscopy studies were conducted on symmetrical cells of the type [gas, electrode/LSGM electrolyte/electrode, gas]. The electrode materials were slurry-coated on both sides of the LSGM electrolyte support. The electrodes selected for this investigation are candidate materials for SOFC electrodes. Cathode materials include La{sub 1-x}Sr{sub x}MnO{sub 3} (LSM), LSCF (La{sub 1-x}Sr{sub x}Co{sub y}Fe{sub 1-y}O{sub 3}), a two-phase particulate composite consisting of LSM + doped-lanthanum gallate (LSGM), and LSCF + LSGM. Pt metal electrodes were also used for the purpose of comparison. Anode material investigated was the Ni + GDC composite. The study revealed important details pertaining to the charge-transfer reactions that occur in such electrodes. The information obtained can be used to design electrodes for intermediate temperature SOFCs based on LSGM electrolyte.

  4. High temperature electrolyzer/fuel cell power cycle: Preliminary design considerations

    NASA Technical Reports Server (NTRS)

    Morehouse, Jeffrey H.

    1987-01-01

    A model of a high temperature electrolyzer/fuel cell, hydrogen/oxygen, thermally regenerative power cycle is developed and used to simulate system performance for varying system parameters. Initial estimates of system efficiency, weight, and volume are provided for a one KWe module assuming specific electrolyzer and fuel cell characteristics, both current and future. Specific interest is placed on examining the system responses to changes in device voltage versus current density operating curves, and the associated optimum operating ranges. The performance of a solar-powered, space based system in low earth orbit is examined in terms of the light-dark periods requiring storage. The storage design tradeoffs between thermal energy, electrical energy, and hydrogen/oxygen mass storage are examined. The current technology module is based on the 1000 C solid oxide electrolyzer cell and the alkaline fuel cell. The Future Technology system examines benefits involved with developing a 1800K electrolyzer operating with an advanced fuel cell.

  5. Investigation of Bio-Diesel Fueled Engines under Low-Temperature Combustion Strategies

    SciTech Connect

    Chia-fon F. Lee; Alan C. Hansen

    2010-09-30

    In accordance with meeting DOE technical targets this research was aimed at developing and optimizing new fuel injection technologies and strategies for the combustion of clean burning renewable fuels in diesel engines. In addition a simultaneous minimum 20% improvement in fuel economy was targeted with the aid of this novel advanced combustion system. Biodiesel and other renewable fuels have unique properties that can be leveraged to reduce emissions and increase engine efficiency. This research is an investigation into the combustion characteristics of biodiesel and its impacts on the performance of a Low Temperature Combustion (LTC) engine, which is a novel engine configuration that incorporates technologies and strategies for simultaneously reducing NOx and particulate emissions while increasing engine efficiency. Generating fundamental knowledge about the properties of biodiesel and blends with petroleum-derived diesel and their impact on in-cylinder fuel atomization and combustion processes was an important initial step to being able to optimize fuel injection strategies as well as introduce new technologies. With the benefit of this knowledge experiments were performed on both optical and metal LTC engines in which combustion and emissions could be observed and measured under realistic conditions. With the aid these experiments and detailed combustion models strategies were identified and applied in order to improve fuel economy and simultaneously reduce emissions.

  6. STABLE HIGH CONDUCTIVITY BILAYERED ELECTROLYTES FOR LOW TEMPERATURE SOLID OXIDE FUEL CELLS

    SciTech Connect

    Eric D. Wachsman; Keith L. Duncan

    2001-09-30

    Solid oxide fuel cells (SOFCs) are the future of energy production in America. They offer great promise as a clean and efficient process for directly converting chemical energy to electricity while providing significant environmental benefits (they produce negligible hydrocarbons, CO, or NO{sub x} and, as a result of their high efficiency, produce about one-third less CO{sub 2} per kilowatt hour than internal combustion engines). Unfortunately, the current SOFC technology, based on a stabilized zirconia electrolyte, must operate in the region of 1000 C to avoid unacceptably high ohmic losses. These high temperatures demand (a) specialized (expensive) materials for the fuel cell interconnects and insulation, (b) time to heat up to the operating temperature and (c) energy input to arrive at the operating temperature. Therefore, if fuel cells could be designed to give a reasonable power output at low to intermediate1 temperatures tremendous benefits may be accrued. At low temperatures, in particular, it becomes feasible to use ferritic steel for interconnects instead of expensive and brittle ceramic materials such as those based on LaCrO{sub 3}. In addition, sealing the fuel cell becomes easier and more reliable; rapid start-up is facilitated; thermal stresses (e.g., those caused by thermal expansion mismatches) are reduced; radiative losses ({approx}T{sup 4}) become minimal; electrode sintering becomes negligible and (due to a smaller thermodynamic penalty) the SOFC operating cycle (heating from ambient) would be more efficient. Combined, all these improvements further result in reduced initial and operating costs. The problem is, at lower temperatures the conductivity of the conventional stabilized zirconia electrolyte decreases to the point where it cannot supply electrical current efficiently to an external load. The primary objectives of the proposed research are to develop a stable high conductivity (> 0.05 S cm{sup -1} at {le} 550 C) electrolyte for lower

  7. Study of the effects of fuel vortex film cooling on high temperature coating durability

    NASA Technical Reports Server (NTRS)

    1974-01-01

    A report on the effects of fuel vortex film cooling on high temperature coating durability is presented. The program evaluated candidate high temperature oxidation resistant reaction control system engine thrust chamber material. As a result of the evaluation, the current and future programs may be optimized from the materials standpoint. Engine firing data for the evaluation of one material system is generated. The subjects considered are: (1) screening of materials, (2) thrust chamber fabrication, (3) engine testing, and (4) analysis of the data.

  8. Full-length high-temperature severe fuel damage test No. 2. Final safety analysis

    SciTech Connect

    Hesson, G.M.; Lombardo, N.J.; Pilger, J.P.; Rausch, W.N.; King, L.L.; Hurley, D.E.; Parchen, L.J.; Panisko, F.E.

    1993-09-01

    Hazardous conditions associated with performing the Full-Length High- Temperature (FLHT). Severe Fuel Damage Test No. 2 experiment have been analyzed. Major hazards that could cause harm or damage are (1) radioactive fission products, (2) radiation fields, (3) reactivity changes, (4) hydrogen generation, (5) materials at high temperature, (6) steam explosion, and (7) steam pressure pulse. As a result of this analysis, it is concluded that with proper precautions the FLHT- 2 test can be safely conducted.

  9. Air oxidation behavior of fuel for the High Temperature Engineering Test Reactor (HTTR)

    NASA Astrophysics Data System (ADS)

    Kikuchi, Hironobu; Hayashi, Kimio; Fukuda, Kousaku

    1992-08-01

    The oxidation behavior of the HTTR fuel was studied with respect to the scenario of an air ingress accident which had been assessed in the HTTR safety analysis. The coated fuel particles were heated under a sufficient air flow in the temperature range of 900-1400 C for maximum duration of 600 h (at 1300 C). Failure fractions of the SiC coating layer after the heat treatments remained within the fraction at the fuel production. And the failure behavior of the SiC layer did not depend on such heating conditions as the temperature and the duration in the present experiment. It was confirmed by scanning electron microscopy (SEM), X-ray diffraction, and laser Raman spectroscopy that a thin oxide film was formed on the SiC layer by the heat treatments.

  10. Pu-Zr alloy for high-temperature foil-type fuel

    DOEpatents

    McCuaig, Franklin D.

    1977-01-01

    A nuclear reactor fuel alloy consists essentially of from slightly greater than 7 to about 4 w/o zirconium, balance plutonium, and is characterized in that the alloy is castable and is rollable to thin foils. A preferred embodiment of about 7 w/o zirconium, balance plutonium, has a melting point substantially above the melting point of plutonium, is rollable to foils as thin as 0.0005 inch thick, and is compatible with cladding material when repeatedly cycled to temperatures above 650.degree. C. Neutron reflux densities across a reactor core can be determined with a high-temperature activation-measurement foil which consists of a fuel alloy foil core sandwiched and sealed between two cladding material jackets, the fuel alloy foil core being a 7 w/o zirconium, plutonium foil which is from 0.005 to 0.0005 inch thick.

  11. Effects of coolant parameters on steady state temperature distribution in phospheric-acid fuel cell electrode

    NASA Technical Reports Server (NTRS)

    Alkasab, K. A.; Abdul-Aziz, A.

    1991-01-01

    The influence of thermophysical properties and flow rate on the steady-state temperature distribution in a phosphoric-acid fuel cell electrode plate was experimentally investigated. An experimental setup that simulates the operating conditions prevailing in a phosphoric-acid fuel cell stack was used. The fuel cell cooling system utilized three types of coolants to remove excess heat generated in the cell electrode and to maintain a reasonably uniform temperature distribution in the electrode plate. The coolants used were water, engine oil, and air. These coolants were circulated at Reynolds number ranging from 1165 to 6165 for water; 3070 to 6864 for air; and 15 to 79 for oil. Experimental results are presented.

  12. An evaluation of near-field host rock temperatures for a spent fuel repository

    SciTech Connect

    Altenhofen, M.K.; Lowery, P.S.

    1988-11-01

    A repository heat transfer analysis has been performed by the Pacific Northwest Laboratory (PNL) for the US Department of Energy's Performance Assessment Scientific Support Program. The objective of this study was to evaluate the near-field thermal environmental conditions for a spent fuel repository system. A spent fuel logistics analysis was performed using a waste management system simulation model, WASTES-II, to evaluate the thermal characteristics of spent fuel received at the repository. A repository-scale thermal analysis was performed using a finite difference heat transfer code, TEMPEST, to evaluate the near-field host rock temperature. The calculated temporal and spatial distributions of near-field host rock temperatures provide input to the repository source term model in evaluations of engineered barrier system performance. 9 refs., 10 figs., 2 tabs.

  13. New High-Temperature Membranes Developed for Proton Exchange Membrane Fuel Cells

    NASA Technical Reports Server (NTRS)

    Kinder, James D.

    2004-01-01

    Fuel cells are receiving a considerable amount of attention for potential use in a variety of areas, including the automotive industry, commercial power generation, and personal electronics. Research at the NASA Glenn Research Center has focused on the development of fuel cells for use in aerospace power systems for aircraft, unmanned air vehicles, and space transportation systems. These applications require fuel cells with higher power densities and better durability than what is required for nonaerospace uses. In addition, membrane cost is a concern for any fuel cell application. The most widely used membrane materials for proton exchange membrane (PEM) fuel cells are based on sulfonated perfluorinated polyethers, typically Nafion 117, Flemion, or Aciplex. However, these polymers are costly and do not function well at temperatures above 80 C. At higher temperatures, conventional membrane materials dry out and lose their ability to conduct protons, essential for the operation of the fuel cell. Increasing the operating temperature of PEM fuel cells from 80 to 120 C would significantly increase their power densities and enhance their durability by reducing the susceptibility of the electrode catalysts to carbon monoxide poisoning. Glenn's Polymers Branch has focused on developing new, low-cost membranes that can operate at these higher temperatures. A new series of organically modified siloxane (ORMOSIL) polymers were synthesized for use as membrane materials in a high-temperature PEM fuel cell. These polymers have an organic portion that can allow protons to transport through the polymer film and a cross-linked silica network that gives the polymers dimensional stability. These flexible xerogel polymer films are thermally stable, with decomposition onset as high as 380 C. Two types of proton-conducting ORMOSIL films have been produced: (1) NASA-A, which can coordinate many highly acid inorganic salts that facilitate proton conduction and (2) NASA-B, which has been

  14. Coherent anti-Stokes Raman spectroscopy temperature measurements in a hydrogen-fueled supersonic combustor

    NASA Technical Reports Server (NTRS)

    Smith, Michael W.; Jarrett, Olin, Jr.; Antcliff, Richard R.; Northam, G. B.; Cutler, Andrew D.; Taylor, David J.

    1993-01-01

    Coherent anti-Stokes Raman spectroscopy (CARS) thermometry has been used to obtain static temperature cross sections in a three-dimensional supersonic combustor flowfield. Data were obtained in three spanwise planes downstream of a single normal fuel injector which was located downstream of a rearward-facing step. The freestream flow was nominally Mach 2 and was combustion heated to a total temperature of 1440 K (yielding a static temperature of about 800 K in the freestream) to simulate the inflow to a combustor operating at a flight Mach number of about 5.4. Since a broadband probe laser was used an instantaneous temperature sample was obtained with each laser shot at a repetition rate of 10 Hz. Thus root-mean-square (rms) temperatures and temperature probability density functions (pdf's) were obtained in addition to mean temperatures.

  15. High-Temperature-Turbine Technology Program: Phase II. Technology test and support studies. Design and development of the liquid-fueled high-temperature combustor for the Turbine Spool Technology Rig

    SciTech Connect

    1981-06-01

    The concept selected by Curtiss-Wright for this DOE sponsored High Temperature Turbine Technology (HTTT) Program utilizes transpiration air-cooling of the turbine subsystem airfoils. With moderate quantities of cooling air, this method of cooling has been demonstrated to be effective in a 2600 to 3000/sup 0/F gas stream. Test results show that transpiration air-cooling also protects turbine components from the aggressive environment produced by the combustion of coal-derived fuels. A new single-stage, high work transpiration air-cooled turbine has been designed and fabricated for evaluation in a rotating test vehicle designated the Turbine Spool Technology Rig (TSTR). The design and development of the annular combustor for the TSTR are described. Some pertinent design characteristics of the combustor are: fuel, Jet A; inlet temperature, 525/sup 0/F; inlet pressure, 7.5 Atm; temperature rise, 2475/sup 0/F; efficiency, 98.5%; exit temperature pattern, 0.25; and exit mass flow, 92.7 pps. The development program was conducted on a 60/sup 0/ sector of the full-round annular combustor. Most design goals were achieved, with the exception of the peak gas exit temperature and local metal temperatures at the rear of the inner liner, both of which were higher than the design values. Subsequent turbine vane cascade testing established the need to reduce both the peak gas temperature (for optimum vane cooling) and the inner liner metal temperature (for combustor durability). Further development of the 60/sup 0/ combustor sector achieved the required temperature reductions and the final configuration was incorporated in the TSTR full-annular burner.

  16. Novel Gas Sensors for High-Temperature Fossil Fuel Applications

    SciTech Connect

    Palitha Jayaweera; Francis Tanzella

    2005-03-01

    SRI International (SRI) is developing ceramic-based microsensors to detect exhaust gases such as NO, NO{sub 2}, and CO in advanced combustion and gasification systems under this DOE NETL-sponsored research project. The sensors detect the electrochemical activity of the exhaust gas species on catalytic electrodes attached to a solid state electrolyte and are designed to operate at the high temperatures, elevated pressures, and corrosive environments typical of large power generation exhausts. The sensors can be easily integrated into online monitoring systems for active emission control. The ultimate objective is to develop sensors for multiple gas detection in a single package, along with data acquisition and control software and hardware, so that the information can be used for closed-loop control in novel advanced power generation systems. This report details the Phase I Proof-of-Concept, research activities performed from October 2003 to March 2005. SRI's research work includes synthesis of catalytic materials, sensor design and fabrication, software development, and demonstration of pulse voltammetric analysis of NO, NO{sub 2}, and CO gases on catalytic electrodes.

  17. Hospital admissions of hypertension, angina, myocardial infarction and ischemic heart disease peaked at physiologically equivalent temperature 0°C in Germany in 2009-2011.

    PubMed

    Shiue, Ivy; Perkins, David R; Bearman, Nick

    2016-01-01

    We aimed to understand and to provide evidence on relationships of the weather as biometeorological and hospital admissions due to hypertension, angina, myocardial infarction and ischemic heart disease in a national setting in recent years that might help indicate when to expect more admissions for health professionals and the general public. This is an ecological study. Ten percent of daily hospital admissions from the included hospitals (n = 1618) across Germany that were available between 1 January 2009 and 31 December 2011 (n = 5,235,600) were extracted from Statistisches Bundesamt, Germany. We identified I11 hypertensive heart disease, I13 hypertensive heart and renal disease, I15 secondary hypertension, I20 angina pectoris, I21 acute myocardial infarction and I25 chronic ischemic heart disease by International Classification of Diseases version 10 as the study outcomes. Daily weather data from 64 weather stations that covered 13 German States including air temperature, humidity, wind speed, cloud cover, radiation flux and vapour pressure were obtained and generated into physiologically equivalent temperature (PET). Two-way fractional-polynomial prediction was plotted with 95% confidence intervals. Hospital admissions of hypertension, angina, myocardial infarction, heart disease peaked in winter and early spring when PETs were around 0°C. Admissions had an apparent drop when PETs reached 10°C. More medical resources could have been needed on days when PETs were around 0°C than on other days. While adaptation to such weather change for health professionals and the general public would seem to be imperative, future research with a longitudinal monitoring would still be needed. PMID:26286805

  18. Kidney stone ablation times and peak saline temperatures during Holmium:YAG and Thulium fiber laser lithotripsy, in vitro, in a ureteral model

    NASA Astrophysics Data System (ADS)

    Hardy, Luke A.; Wilson, Christopher R.; Irby, Pierce B.; Fried, Nathaniel M.

    2015-02-01

    Using a validated in vitro ureter model for laser lithotripsy, the performance of an experimental Thulium fiber laser (TFL) was studied and compared to clinical gold standard Holmium:YAG laser. The Holmium laser (λ = 2120 nm) was operated with standard parameters of 600 mJ, 350 μs, 6 Hz, and 270-μm-core optical fiber. TFL (λ = 1908 nm) was operated with 35 mJ, 500 μs, 150-500 Hz, and 100-μm-core fiber. Urinary stones (60% calcium oxalate monohydrate / 40% calcium phosphate), of uniform mass and diameter (4-5 mm) were laser ablated with fibers through a flexible video-ureteroscope under saline irrigation with flow rates of 22.7 ml/min and 13.7 ml/min for the TFL and Holmium laser, respectively. The temperature 3 mm from tube's center and 1 mm above mesh sieve was measured by a thermocouple and recorded during experiments. Total laser and operation times were recorded once all stone fragments passed through a 1.5-mm sieve. Holmium laser time measured 167 +/- 41 s (n = 12). TFL times measured 111 +/- 49 s, 39 +/- 11 s, and 23 +/- 4 s, for pulse rates of 150, 300, and 500 Hz (n = 12 each). Mean peak saline irrigation temperatures reached 24 +/- 1 °C for Holmium, and 33 +/- 3 °C, 33 +/- 7 °C, and 39 +/- 6 °C, for TFL at pulse rates of 150, 300, and 500 Hz. To avoid thermal buildup and provide a sufficient safety margin, TFL lithotripsy should be performed with pulse rates below 500 Hz and/or increased saline irrigation rates. The TFL rapidly fragmented kidney stones due in part to its high pulse rate, high power density, high average power, and reduced stone retropulsion, and may provide a clinical alternative to the conventional Holmium laser for lithotripsy.

  19. CARCINOGENICITY OF HOUSEHOLD SOLID FUEL COMBUSTION AND OF HIGH-TEMPERATURE FRYING

    EPA Science Inventory

    In October, 2006, 19 scientists from eight countries met at the International Agency for Research on Cancer (IARC) in Lyon, France, to assess the carcinogenicity of household solid fuel combustion (coal and biomass) and of high-temperature frying. These assessments will be publi...

  20. 40 CFR 86.1229-85 - Dynamometer load determination and fuel temperature profile.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 20 2013-07-01 2013-07-01 false Dynamometer load determination and fuel temperature profile. 86.1229-85 Section 86.1229-85 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) Evaporative...

  1. Molten carbonate fuel cells: A high temperature fuel cell on the edge to commercialization

    NASA Astrophysics Data System (ADS)

    Bischoff, Manfred

    The Molten Carbonate Fuel Cell (MCFC) technology has been developed in USA, Japan, Korea and Europe for many years. What has started about 30 years ago as an interesting laboratory object has now matured to a potential alternative to conventional power generation systems. Especially the combined heat and power (CHP) generation is an area, where MCFC power plants can be applied with great advantage, due to the high efficiencies which can be achieved. It was demonstrated by several manufacturers that in the sub-MW region MCFC power plants can reach electrical efficiencies of 47%. By making use of the heat generated by the system, total efficiencies of more than 80% can be achieved. The present paper will discuss some aspects of the development work going on with a focus on the role of the molten carbonate contained in the cells. An outlook will be given for the future prospects of this young technology in a changing energy market.

  2. Options for treating high-temperature gas-cooled reactor fuel for repository disposal

    SciTech Connect

    Lotts, A.L.; Bond, W.D.; Forsberg, C.W.; Glass, R.W.; Harrington, F.E.; Micheals, G.E.; Notz, K.J.; Wymer, R.G.

    1992-02-01

    This report describes the options that can reasonably be considered for disposal of high-temperature gas-cooled reactor (HTGR) fuel in a repository. The options include whole-block disposal, disposal with removal of graphite (either mechanically or by burning), and reprocessing of spent fuel to separate the fuel and fission products. The report summarizes what is known about the options without extensively projecting or analyzing actual performance of waste forms in a repository. The report also summarizes the processes involved in convert spent HTGR fuel into the various waste forms and projects relative schedules and costs for deployment of the various options. Fort St. Vrain Reactor fuel, which utilizes highly-enriched {sup 235}U (plus thorium) and is contained in a prismatic graphite block geometry, was used as the baseline for evaluation, but the major conclusions would not be significantly different for low- or medium-enriched {sup 235}U (without thorium) or for the German pebble-bed fuel. Future US HTGRs will be based on the Fort St. Vrain (FSV) fuel form. The whole block appears to be a satisfactory waste form for disposal in a repository and may perform better than light-water reactor (LWR) spent fuel. From the standpoint of process cost and schedule (not considering repository cost or value of fuel that might be recycled), the options are ranked as follows in order of increased cost and longer schedule to perform the option: (1) whole block, (2a) physical separation, (2b) chemical separation, and (3) complete chemical processing.

  3. Fuel-Cycle and Nuclear Material Disposition Issues Associated with High-Temperature Gas Reactors

    SciTech Connect

    Shropshire, D.E.; Herring, J.S.

    2004-10-03

    The objective of this paper is to facilitate a better understanding of the fuel-cycle and nuclear material disposition issues associated with high-temperature gas reactors (HTGRs). This paper reviews the nuclear fuel cycles supporting early and present day gas reactors, and identifies challenges for the advanced fuel cycles and waste management systems supporting the next generation of HTGRs, including the Very High Temperature Reactor, which is under development in the Generation IV Program. The earliest gas-cooled reactors were the carbon dioxide (CO2)-cooled reactors. Historical experience is available from over 1,000 reactor-years of operation from 52 electricity-generating, CO2-cooled reactor plants that were placed in operation worldwide. Following the CO2 reactor development, seven HTGR plants were built and operated. The HTGR came about from the combination of helium coolant and graphite moderator. Helium was used instead of air or CO2 as the coolant. The helium gas has a significant technical base due to the experience gained in the United States from the 40-MWe Peach Bottom and 330-MWe Fort St. Vrain reactors designed by General Atomics. Germany also built and operated the 15-MWe Arbeitsgemeinschaft Versuchsreaktor (AVR) and the 300-MWe Thorium High-Temperature Reactor (THTR) power plants. The AVR, THTR, Peach Bottom and Fort St. Vrain all used fuel containing thorium in various forms (i.e., carbides, oxides, thorium particles) and mixtures with highly enriched uranium. The operational experience gained from these early gas reactors can be applied to the next generation of nuclear power systems. HTGR systems are being developed in South Africa, China, Japan, the United States, and Russia. Elements of the HTGR system evaluated included fuel demands on uranium ore mining and milling, conversion, enrichment services, and fuel fabrication; fuel management in-core; spent fuel characteristics affecting fuel recycling and refabrication, fuel handling, interim

  4. Enhanced performance and stability of high temperature proton exchange membrane fuel cell by incorporating zirconium hydrogen phosphate in catalyst layer

    NASA Astrophysics Data System (ADS)

    Barron, Olivia; Su, Huaneng; Linkov, Vladimir; Pollet, Bruno G.; Pasupathi, Sivakumar

    2015-03-01

    Zirconium hydrogen phosphate (ZHP) together with polytetrafluoroethylene (PTFE) polymer binder is incorporated into the catalyst layers (CLs) of ABPBI (poly(2,5-benzimidazole))-based high temperature polymer electrolyte membrane fuel cell (HT-PEMFCs) to improve its performance and durability. The influence of ZHP content (normalised with respect to dry PTFE) on the CL properties are structurally characterised by scanning electron microscopy (SEM) and mercury intrusion porosimetry. Electrochemical analyses of the resultant membrane electrode assemblies (MEAs) are performed by recording polarisation curves and impedance spectra at 160 °C, ambient pressure and humidity. The result show that a 30 wt.% ZHP/PTFE content in the CL is optimum for improving fuel cell performance, the resultant MEA delivers a peak power of 592 mW cm-2 at a cell voltage of 380 mV. Electrochemical impedance spectra (EIS) indicate that 30% ZHP in the CL can increase the proton conductivity compared to the pristine PTFE-gas diffusion electrode (GDE). A short term stability test (∼500 h) on the 30 wt.% ZHP/PTFE-GDE shows a remarkable high durability with a degradation rate as low as ∼19 μV h-1 at 0.2 A cm-2, while 195 μV h-1 was obtained for the pristine GDE.

  5. Effect of calcination temperature on oxidation state of cobalt in calcium cobaltite and relevant performance as intermediate-temperature solid oxide fuel cell cathodes

    NASA Astrophysics Data System (ADS)

    Yu, Shancheng; He, Shoucheng; Chen, Han; Guo, Lucun

    2015-04-01

    Calcium cobaltite materials are synthesized by calcining the mixture of CaCO3 and Co3O4 with the Ca: Co ratio of 3:4. The reactivity of CaCO3 with Co3O4 is evaluated by thermogravimetric analysis (TGA), X-ray powder diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Thermal expansion coefficient (TEC), electrical conductivity and electrochemical performance as intermediate-temperature solid oxide fuel cells (IT-SOFCs) cathode of as-prepared materials are characterized. The experiment results show that simultaneous decomposition of CaCO3 with calcium cobaltite formation occurs at 650-900 °C. The average valence for Co ions of calcium cobaltite increases with temperature in the range of 750-900 °C, involved in the formation of the compounds Ca3Co4O9 and Ca9Co12O28 at 800 and 900 °C, respectively. The performance of calcium cobaltite cathodes applied in IT-SOFCs is significantly effected by the oxidation state of cobalt ions. As a result, Ca9Co12O28 cathode has a lower area specific resistance (e.g. 41.8% lower at 800 °C) and higher peak power density (e.g. 45.0% higher at 800 °C) than the cathode of Ca3Co4O9.

  6. Deep Burn: Development of Transuranic Fuel for High-Temperature Helium-Cooled Reactors- Monthly Highlights October 2010

    SciTech Connect

    Snead, Lance Lewis; Besmann, Theodore M; Collins, Emory D; Bell, Gary L

    2010-11-01

    The DB Program monthly highlights report for September 2010, ORNL/TM-2010/252, was distributed to program participants by email on October 26. This report discusses: (1) Core and Fuel Analysis; (2) Spent Fuel Management; (3) Fuel Cycle Integration of the HTR (high temperature helium-cooled reactor); (4) TRU (transuranic elements) HTR Fuel Qualification; (5) HTR Spent Fuel Recycle - (a) TRU Kernel Development (ORNL), (b) Coating Development (ORNL), (c) Characterization Development and Support, (d) ZrC Properties and Handbook; and (6) HTR Fuel Recycle.

  7. Improved Prediction of the Temperature Feedback in TRISO-Fueled Reactors

    SciTech Connect

    Javier Ortensi; Abderrafi M. Ougouag

    2009-08-01

    The Doppler feedback mechanism is a major contributor to the passive safety of gas-cooled, graphite-moderated high temperature reactors that use fuel based on Tristructural-Isotropic coated particles. It follows that the correct prediction of the magnitude and time-dependence of this feedback effect is essential to the conduct of safety analyses for these reactors. We present a fuel conduction model for obtaining better estimates of the temperature feedback during moderate and fast transients. The fuel model has been incorporated in the CYNOD-THERMIX-KONVEK suite of coupled codes as a single TRISO particle within each calculation cell. The heat generation rate is scaled down from the neutronic solution and a Dirichlet boundary condition is imposed as the bulk graphite temperature from the thermal-hydraulic solution. This simplified approach yields similar results to those obtained with more complex methods, requiring multi-TRISO calculations within one control volume, but with much less computational effort. An analysis of the hypothetical total control ejection in the PBMR-400 design verifies the performance of the code during fast transients. In addition, the analysis of the earthquake-initiated event in the PBMR-400 design verifies the performance of the code during slow transients. These events clearly depict the improvement in the predictions of the fuel temperature, and consequently, of the power escalations. In addition, a brief study of the potential effects of particle layer de-bonding on the transient behavior of high temperature reactors is included. Although the formation of a gap occurs under special conditions its consequences on the dynamic behavior of the reactor should be analyzed. The presence of a gap in the fuel can cause some unusual reactor behavior during fast transients, but still the reactor shuts down due to the strong feedback effects.

  8. The Challenges Associated with High Burnup and High Temperature for UO2 TRISO-Coated Particle Fuel

    SciTech Connect

    David Petti; John Maki

    2005-02-01

    The fuel service conditions for the DOE Next Generation Nuclear Plant (NGNP) will be challenging. All major fuel related design parameters (burnup, temperature, fast neutron fluence, power density, particle packing fraction) exceed the values that were qualified in the successful German UO2 TRISO-coated particle fuel development program in the 1980s. While TRISO-coated particle fuel has been irradiated at NGNP relevant levels for two or three of the design parameters, no data exist for TRISO-coated particle fuel for all five parameters simultaneously. Of particular concern are the high burnup and high temperatures expected in the NGNP. In this paper, where possible, we evaluate the challenges associated with high burnup and high temperature quantitatively by examining the performance of the fuel in terms of different known failure mechanisms. Potential design solutions to ameliorate the negative effects of high burnup and high temperature are also discussed.

  9. Effect of Dissolved Oxygen on the Filterability of Jet Fuels for Temperatures Between 300 Degrees and 400 Degrees F

    NASA Technical Reports Server (NTRS)

    Mckeown, Anderson B; Hibbard, Robert R

    1955-01-01

    The effect of dissolved oxygen in the filter-clogging characteristics of three JP-4 and two JP-5 fuels was studied at 300 degrees to 400 degrees F in a bench- scale rig, employing filter paper as the filter medium. The residence time of the fuel at the high temperature was approximately 6 seconds. For these conditions, the clogging characteristics of the fuels increased with both increasing temperature and increasing concentration of dissolved oxygen. The amount of insoluble material formed at high temperatures necessary to produce clogging of filters was very small, of the order of 1 milligram per gallon of fuel.

  10. Mechanical and transport properties of NafionRTM for PEM fuel cells; temperature and hydration effects

    NASA Astrophysics Data System (ADS)

    Majsztrik, Paul William

    This work investigates the mechanical and water transport properties of Nafion, a fully fluorinated ion conducting polymer used as a membrane material in proton exchange membrane fuel cells (PEMFCs). Both of these properties are extremely important to the short and long term operation of fuel cells. Nafion is a viscoelastic material, responding to stress in a time-dependant manner. The result is that Nafion flows under stress and responds dynamically to changes in hydration and stress. Stresses applied to the membrane of a PEM fuel cell, both from clamping as well as strain from changing levels of hydration, cause Nafion to flow. This results in thinning in spots and sometimes leads to the development of pinholes or contact problems between membrane and electrode. Temperature and water content strongly affect Nafion's viscoelastic response, of direct importance for operating PEM fuel cells. The viscoelastic response of Nafion was measured over a range of temperature and hydration using viscoelastic creep. A specially designed creep apparatus with environmental controls was used. It was found that the effects of temperature and hydration on Nafion's viscoelastic response are very complicated. Around room temperature, water acts to plasticize Nafion; elastic modulus and resistance to creep decrease with increasing hydration. As temperature increases, water has the opposite effect on mechanical response; hydration acts to stabilize the material. Mechanical property values are reported over a range of temperature and hydration germane to the operation of PEMFCs. Additionally, the data is used to infer molecular level interactions and the effects of temperature and hydration on microstructure. Hydration of Nafion and other PEMFC materials is required for the high proton conductivity needed for fuel cell operation. Uptake of water by Nafion results in volumetric swelling. Water transport through Nafion was directly measured by permeation. Both liquid and vapor phase

  11. Analytical Solution of Fick's Law of the TRISO-Coated Fuel Particles and Fuel Elements in Pebble-Bed High Temperature Gas-Cooled Reactors

    NASA Astrophysics Data System (ADS)

    Cao, Jian-Zhu; Fang, Chao; Sun, Li-Feng

    2011-05-01

    Two kinds of approaches are built to solve the fission products diffusion models (Fick's equation) based on sphere fuel particles and sphere fuel elements exactly. Two models for homogenous TRISO-coated fuel particles and fuel elements used in pebble-bed high temperature gas-cooled reactors are presented, respectively. The analytical solution of Fick's equation for fission products diffusion in fuel particles is derived by variables separation. In the fuel element system, a modification of the diffusion coefficient from D to D/r is made to characterize the difference of diffusion rates in distinct areas and it is shown that the Laplace and Hankel transformations are effective as the diffusion coefficient in Fick's equation is dependant on the radius of the fuel element. Both the solutions are useful for the prediction of the fission product behaviors and could be programmed in the corresponding engineering calculations.

  12. Mechanical properties of solid oxide fuel cell glass-ceramic seal at high temperatures

    SciTech Connect

    Milhans, Jacqueline; Li, Dongsheng; Khaleel, Mohammad A.; Sun, Xin; Al-Haik, Marwan; Harris, Adrian; Garmestani, Hamid

    2011-04-20

    Mechanical properties of solid oxide fuel cell glass-ceramic seal material, G18, are studied at high temperatures. Samples of G18 are aged for either 4h or 100h, resulting in samples with different crystallinity. Reduced modulus, hardness, and time-dependent behavior are measured by nanoindentation. The nanoindentation is performed at room temperature, 550, 650, and 750°C, using loading rates of 5 mN/s and 25 mN/s. Results show a decrease in reduced modulus with increasing temperature, with significant decrease above the glass transition temperature (Tg). Hardness generally decreases with increasing temperature, with a slight increase before Tg for the 4h aged sample. Dwell tests show that creep increases with increasing temperature, but decrease with further aging.

  13. Strength and Young's modulus of silicon carbide layers of HTGR fuel particles at high temperatures

    NASA Astrophysics Data System (ADS)

    Minato, Kazuo; Fukuda, Kousaku

    1991-06-01

    Strength and Young's modulus of chemically vapor deposited silicon carbide layers of coated fuel particles for high temperature gas-cooled reactors (HTGR) were measured from room temperature up to 1480°C (1753 K) in helium atmosphere. The diametrical compression test was applied to micro-specimens of ring shaped SiC. Young's modulus decreased slightly from room temperature up to around 1200 °C (1473 K) and decreased rapidly above this temperature. The strength remained almost unchanged from room temperature up to around 1300°C (1573 K) and decreased rapidly above this temperature. The fracture surfaces indicated that fracture mechanisms changed from transgranular to intergranular, which corresponded with the rapid decrease in strength.

  14. Quantitative Surface Emissivity and Temperature Measurements of a Burning Solid Fuel Accompanied by Soot Formation

    NASA Technical Reports Server (NTRS)

    Piltch, Nancy D.; Pettegrew, Richard D.; Ferkul, Paul; Sacksteder, K. (Technical Monitor)

    2001-01-01

    Surface radiometry is an established technique for noncontact temperature measurement of solids. We adapt this technique to the study of solid surface combustion where the solid fuel undergoes physical and chemical changes as pyrolysis proceeds, and additionally may produce soot. The physical and chemical changes alter the fuel surface emissivity, and soot contributes to the infrared signature in the same spectral band as the signal of interest. We have developed a measurement that isolates the fuel's surface emissions in the presence of soot, and determine the surface emissivity as a function of temperature. A commercially available infrared camera images the two-dimensional surface of ashless filter paper burning in concurrent flow. The camera is sensitive in the 2 to 5 gm band, but spectrally filtered to reduce the interference from hot gas phase combustion products. Results show a strong functional dependence of emissivity on temperature, attributed to the combined effects of thermal and oxidative processes. Using the measured emissivity, radiance measurements from several burning samples were corrected for the presence of soot and for changes in emissivity, to yield quantitative surface temperature measurements. Ultimately the results will be used to develop a full-field, non-contact temperature measurement that will be used in spacebased combustion investigations.

  15. Management of the spent fuel elements of the thorium high temperature reactor THTR-300

    SciTech Connect

    Quaassdorff, P.; Mielisch, M.; Dietrich, G.; Heske, M.; Jacobsen, W.

    1995-12-31

    In a world-wide unique campaign ca. 620,000 spent fuel elements of the thorium high temperature reactor THTR 300 which is being decommissioned, were being transferred within a short period of time to the Ahaus fuel element interim store (BZA) for interim storage. In order to optimize the technical and logistic procedures as part of the pre-decommissioning operation in 1992 and 1993, 42,000 fuel elements which had already been removed from the reactor core were transferred to Ahaus in transport and storage casks of the CASTOR THTR/AVR type that have been specially designed for this purpose. The experiences gained with loading, processing and transport of 20 transport and storage casks during this optimization and testing period led the team to expect a smooth management of the remaining fuel elements. In January 1994, the routine operation of the outward transfer commenced. Until mid-November 1994, 554,400 spent fuel elements were transferred outward into altogether 264 transport and storage casks of the CASTOR THTR/AVR type and transported to Ahaus for interim storage. This was followed by processing of another 21 transport and storage casks until April 1995, accommodating damaged fuel elements and special elements. The work mentioned above was performed by SFEAG Kernenergie GmbH, Essen, on behalf of the reactor operator Hochtemperatur-Kernkraftwerk GmbH, Hamm. The removal of the nuclear fuel from the thorium high temperature reactor THTR-300 marks the completion of the first part of the necessary actions for the decommissioning of the reactor (safe enclosure).

  16. Effect of secondary fuels and combustor temperature on mercury speciation in pulverized fuel co-combustion: part 1

    SciTech Connect

    Shishir P. Sable; Wiebren de Jong; Ruud Meij; Hartmut Spliethoff

    2007-08-15

    The present work mainly involves bench scale studies to investigate partitioning of mercury in pulverized fuel co-combustion at 1000 and 1300{sup o}C. High volatile bituminous coal is used as a reference case and chicken manure, olive residue, and B quality (demolition) wood are used as secondary fuels with 10 and 20% thermal shares. The combustion experiments are carried out in an entrained flow reactor with a fuel input of 7-8 kWth. Elemental and total gaseous mercury concentrations in the flue gas of the reactor are measured on-line, and ash is analyzed for particulate mercury along with other elemental and surface properties. Animal waste like chicken manure behaves very differently from plant waste. The higher chlorine contents of chicken manure cause higher ionic mercury concentrations whereas even with high unburnt carbon, particulate mercury reduces with increase in the chicken manure share. This might be a problem due to coarse fuel particles, low surface area, and iron contents. B-wood and olive residue cofiring reduces the emission of total gaseous mercury and increases particulate mercury capture due to unburnt carbon formed, fine particles, and iron contents of the ash. Calcium in chicken manure does not show any effect on particulate or gaseous mercury. It is probably due to a higher calcium sulfation rate in the presence of high sulfur and chlorine contents. However, in plant waste cofiring, calcium may have reacted with chlorine to reduce ionic mercury to its elemental form. According to thermodynamic predictions, almost 50% of the total ash is melted to form slag at 1300{sup o}C in cofiring because of high calcium, iron, and potassium and hence mercury and other remaining metals are concentrated in small amounts of ash and show an increase at higher temperatures. No slag formation was predicted at 1000{sup o}C. 24 refs., 8 figs., 4 tabs.

  17. Combustion of Gaseous Fuels with High Temperature Air in Normal- and Micro-gravity Conditions

    NASA Technical Reports Server (NTRS)

    Wang, Y.; Gupta, A. K.

    2001-01-01

    The objective of this study is determine the effect of air preheat temperature on flame characteristics in normal and microgravity conditions. We have obtained qualitative (global flame features) and some quantitative information on the features of flames using high temperature combustion air under normal gravity conditions with propane and methane as the fuels. This data will be compared with the data under microgravity conditions. The specific focus under normal gravity conditions has been on determining the global flame features as well as the spatial distribution of OH, CH, and C2 from flames using high temperature combustion air at different equivalence ratio.

  18. TRISO-Coated Fuel Processing to Support High Temperature Gas-Cooled Reactors

    SciTech Connect

    Del Cul, G.D.

    2002-10-01

    The initial objective of the work described herein was to identify potential methods and technologies needed to disassemble and dissolve graphite-encapsulated, ceramic-coated gas-cooled-reactor spent fuels so that the oxide fuel components can be separated by means of chemical processing. The purpose of this processing is to recover (1) unburned fuel for recycle, (2) long-lived actinides and fission products for transmutation, and (3) other fission products for disposal in acceptable waste forms. Follow-on objectives were to identify and select the most promising candidate flow sheets for experimental evaluation and demonstration and to address the needs to reduce technical risks of the selected technologies. High-temperature gas-cooled reactors (HTGRs) may be deployed in the next -20 years to (1) enable the use of highly efficient gas turbines for producing electricity and (2) provide high-temperature process heat for use in chemical processes, such as the production of hydrogen for use as clean-burning transportation fuel. Also, HTGR fuels are capable of significantly higher burn-up than light-water-reactor (LWR) fuels or fast-reactor (FR) fuels; thus, the HTGR fuels can be used efficiently for transmutation of fissile materials and long-lived actinides and fission products, thereby reducing the inventory of such hazardous and proliferation-prone materials. The ''deep-burn'' concept, described in this report, is an example of this capability. Processing of spent graphite-encapsulated, ceramic-coated fuels presents challenges different from those of processing spent LWR fuels. LWR fuels are processed commercially in Europe and Japan; however, similar infrastructure is not available for processing of the HTGR fuels. Laboratory studies on the processing of HTGR fuels were performed in the United States in the 1960s and 1970s, but no engineering-scale processes were demonstrated. Currently, new regulations concerning emissions will impact the technologies used in

  19. An intermediate-temperature solid oxide fuel cell with electrospun nanofiber cathode

    SciTech Connect

    Zhi, Mingjia; Lee, Shiwoo; Miller, Nicholas; Menzler, Norbert H.; Wu, Nianqiang

    2012-05-01

    Lanthanum strontium cobalt ferrite (LSCF) nanofibers have been fabricated by the electrospinning method and used as the cathode of an intermediate-temperature solid oxide fuel cell (SOFC) with yttria-stabilized zirconia (YSZ) electrolyte. The three-dimensional nanofiber network cathode has several advantages: (i) high porosity; (ii) high percolation; (iii) continuous pathway for charge transport; (iv) good thermal stability at the operating temperature; and (v) excellent scaffold for infiltration. The fuel cell with the monolithic LSCF nanofiber cathode exhibits a power density of 0.90 W cm{sup −2} at 1.9 A cm{sup −2} at 750 °C. The electrochemical performance of the fuel cell has been further improved by infiltration of 20 wt% of gadolinia-doped ceria (GDC) into the LSCF nanofiber cathode. The fuel cell with the LSCF–20% GDC composite cathode shows a power density of 1.07 W cm{sup −2} at 1.9 A cm{sup −2} at 750 °C. The results obtained show that one-dimensional nanostructures such as nanofibers hold great promise as electrode materials for intermediate-temperature SOFCs.

  20. Low-temperature pyrolysis of coal to produce diesel-fuel blends

    SciTech Connect

    Shafer, T.B.; Jett, O.J.; Wu, J.S.

    1982-10-01

    Low-temperature (623 to 773/sup 0/K) coal pyrolysis was investigated in a bench-scale retort. Factorially designed experiments were conducted to determine the effects of temperature, coal-particle size, and nitrogen flow rate on the yield of liquid products. Yield of condensable organic products relative to the proximate coal volatile matter increased by 3.1 and 6.4 wt % after increasing nitrogen purge flow rate from 0.465 to 1.68 L/min and retort temperature from 623 to 723/sup 0/K, respectively. The liquid product may be suitable for blending with diesel fuel. The viscosity and density of coal liquids produced at 723/sup 0/K were compared with those of diesel fuel. The coal liquids had a higher carbon-to-hydrogen ratio and a lower aliphatic-to-aromatic ratio than premium quality No. 2 diesel fuel. It was recommended that liquids from coal pyrolysis be blended with diesel fuel to determine stability of the mixture and performance of the blend in internal combustion engines.

  1. Convective Heat Transfer with and without Film Cooling in High Temperature, Fuel Rich and Lean Environments

    NASA Astrophysics Data System (ADS)

    Greiner, Nathan J.

    Modern turbine engines require high turbine inlet temperatures and pressures to maximize thermal efficiency. Increasing the turbine inlet temperature drives higher heat loads on the turbine surfaces. In addition, increasing pressure ratio increases the turbine coolant temperature such that the ability to remove heat decreases. As a result, highly effective external film cooling is required to reduce the heat transfer to turbine surfaces. Testing of film cooling on engine hardware at engine temperatures and pressures can be exceedingly difficult and expensive. Thus, modern studies of film cooling are often performed at near ambient conditions. However, these studies are missing an important aspect in their characterization of film cooling effectiveness. Namely, they do not model effect of thermal property variations that occur within the boundary and film cooling layers at engine conditions. Also, turbine surfaces can experience significant radiative heat transfer that is not trivial to estimate analytically. The present research first computationally examines the effect of large temperature variations on a turbulent boundary layer. Subsequently, a method to model the effect of large temperature variations within a turbulent boundary layer in an environment coupled with significant radiative heat transfer is proposed and experimentally validated. Next, a method to scale turbine cooling from ambient to engine conditions via non-dimensional matching is developed computationally and the experimentally validated at combustion temperatures. Increasing engine efficiency and thrust to weight ratio demands have driven increased combustor fuel-air ratios. Increased fuel-air ratios increase the possibility of unburned fuel species entering the turbine. Alternatively, advanced ultra-compact combustor designs have been proposed to decrease combustor length, increase thrust, or generate power for directed energy weapons. However, the ultra-compact combustor design requires a

  2. High temperature solid oxide regenerative fuel cell for solar photovoltaic energy storage

    NASA Technical Reports Server (NTRS)

    Bents, David J.

    1987-01-01

    A hydrogen-oxygen regenerative fuel cell energy storage system based on high temperature solid oxide fuel cell technology is discussed which has application to darkside energy storage for solar photovoltaics. The forward and reverse operating cycles are described, and heat flow, mass, and energy balance data are presented to characterize the system's performance and the variation of performance with changing reactant storage pressure. The present system weighs less than nickel hydrogen battery systems after 0.7 darkside operation, and it maintains a specific weight advantage over radioisotope generators for discharge periods up to 72 hours.

  3. Improved Electrodes for High Temperature Proton Exchange Membrane Fuel Cells using Carbon Nanospheres.

    PubMed

    Zamora, Héctor; Plaza, Jorge; Cañizares, Pablo; Lobato, Justo; Rodrigo, Manuel A

    2016-05-23

    This work evaluates the use of carbon nanospheres (CNS) in microporous layers (MPL) of high temperature proton exchange membrane fuel cell (HT-PEMFC) electrodes and compares the characteristics and performance with those obtained using conventional MPL based on carbon black. XRD, hydrophobicity, Brunauer-Emmett-Teller theory, and gas permeability of MPL prepared with CNS were the parameters evaluated. In addition, a short life test in a fuel cell was carried out to evaluate performance under accelerated stress conditions. The results demonstrate that CNS is a promising alternative to traditional carbonaceous materials because of its high electrochemical stability and good electrical conductivity, suitable to be used in this technology. PMID:27076055

  4. Measurement by room-temperature phosphorescence of polynuclear aromatics containing hydrocarbon fuels that permeate glove materials

    SciTech Connect

    Gammage, R.B.; White, D.A.; Vo-Dinh, T.

    1986-01-01

    Permeations of commonly used glove materials by polynuclear aromatic (PNA) compounds in hydrocarbon fuels were measured with solid-state dosemeters composed of filter paper. The permeated PNA were sorbed by the filter paper and analyzed in situ using room-temperature phosphorescence spectroscopy. This technique provided a simple, cost-effective, and very sensitive means for measuring breakthrough times and permeation rates of the class of potentially carcinogenic PNA in liquid fuels derived from crude petroleum, oil shale, and coal. 7 refs., 3 figs.

  5. High-Temperature Corrosion in Fossil Fuel Power Generation: Present and Future

    NASA Astrophysics Data System (ADS)

    Pint, B. A.

    2013-08-01

    Fossil fuels have historically represented two-thirds of all electricity generation in the United States and are projected to continue to play a similar role despite historically low projected growth rates in electricity demand and the recent dramatic shift from coal to more natural gas usage. Economic and environmental drivers will require more reliable and efficient fossil fuel generation systems in the future, likely with new system designs, higher operating temperatures, and more aggressive environments. Some of the current corrosion issues in power plants are reviewed along with research on materials solutions for systems envisioned for the near future, such as coal gasification and oxy-fired coal boilers.

  6. Investigation of high temperature operation of proton exchange membrane fuel cells

    NASA Astrophysics Data System (ADS)

    Adjemian, Kevork Tro

    Proton exchange membrane fuel cells (PEMFCs) have garnered much attention in the media over the past years as they can provide a clean, environmentally friendly alternative to internal combustion engines. PEMFCs also have the flexibility to operate on many different types of fuels, thereby diminishing our reliance on foreign oil. PEMFCs, however, suffer from many drawbacks which need to be overcome before mass production becomes viable. One drawback is the expense of the fuel cell system, costing several times more than existing technologies. Another problem is that if the fuel cell is running on reformed fuels, trace amounts of carbon monoxide (10 ppm) in the hydrogen gas stream will completely poison the anode electrocatalyst, killing the PEMFC. Also, as a lot of waste heat is generated, a very elaborate cooling system needs to be used, making the overall system more expensive and complex. A possible solution to both the carbon monoxide poisoning and thermal management of a PEMFC is to elevate its operating temperature above 100°C. Unfortunately, current state-of-the-art electrolytes used in PEMFCs, i.e. Nafion 115, rely on water for the conduction of protons and by elevating the temperature, water loss occurs due to evaporation resulting in inadequate PEMFC performance. This thesis delves into the modification of Nafion and similar electrolytes to permit PEMFC operation above 100°C. This was accomplished by impregnating the pores of the Nafion with hydrophilic inorganic materials-silicon oxide via sol-gel processing and various inorganic particles. By performing these modifications to the various electrolytes, several composite membranes performed exceptionally well at an operating temperature of 130°C and demonstrated carbon monoxide tolerance of up to 500 ppm. In addition, a theory on how these materials help improve the water management characteristics of Nafion was developed, laying the foundation for the development of a completely novel membrane to

  7. Experimental analysis and semicontinuous simulation of low-temperature droplet evaporation of multicomponent fuels

    NASA Astrophysics Data System (ADS)

    Lehmann, S.; Lorenz, S.; Rivard, E.; Brüggemann, D.

    2015-01-01

    Low-pollutant and efficient combustion not only in internal combustion engines requires a balanced gaseous mixture of fuel and oxidizer. As fuels may contain several hundred different chemical species with different physicochemical properties as well as defined amounts of biogenic additives, e.g., ethanol, a thorough understanding of liquid fuel droplet evaporation processes is necessary to allow further engine optimization. We have studied the evaporation of fuel droplets at low ambient temperature. A non-uniform temperature distribution inside the droplet was already considered by including a finite thermal conductivity in a one-dimensional radial evaporation model (Rivard and Brüggemann in Chem Eng Sci 65(18):5137-5145, 2010). For a detailed analysis of droplet evaporation, two non-laser-based experimental setups have been developed. They allow a fast and relatively simple but yet precise measurement of diameter decrease and composition change. The first method is based on collecting droplets in a diameter range from 70 to 150 µm by a high-precision scale. A simultaneous evaluation of mass increase is employed for an accurate average diameter value determination. Subsequently, a gas chromatographic analysis of the collected droplets was conducted. In the second experiment, evaporation of even smaller droplets was optically analyzed by a high-speed shadowgraphy/schlieren microscope setup. A detailed analysis of evaporating E85 (ethanol/gasoline in a mass ratio of 85 %/15 %) and surrogate fuel droplets over a wide range of initial droplet diameters and ambient temperatures was conducted. The comparison of experimental and numerical results shows the applicability of the developed model over a large range of diameters and temperatures.

  8. Fuel/cladding compatibility in high-burnup U-19Pu-10Zr/HT9-clad fuel at elevated temperatures

    SciTech Connect

    Cohen, A.B.; Tsai, H.; Neimark, L.A.

    1992-11-01

    This paper summarizes the most recent results of a continuing experimental effort to study compatibility issues of irradiated metallic fuel and cladding at elevated temperatures that may be encountered beyond those of nominal steady-state conditions.

  9. High temperature mechanical properties of zirconia tapes used for electrolyte supported solid oxide fuel cells

    NASA Astrophysics Data System (ADS)

    Fleischhauer, Felix; Bermejo, Raul; Danzer, Robert; Mai, Andreas; Graule, Thomas; Kuebler, Jakob

    2015-01-01

    Solid-Oxide-Fuel-Cell systems are efficient devices to convert the chemical energy stored in fuels into electricity. The functionality of the cell is related to the structural integrity of the ceramic electrolyte, since its failure can lead to drastic performance losses. The mechanical property which is of most interest is the strength distribution at all relevant temperatures and how it is affected with time due to the environment. This study investigates the impact of the temperature on the strength and the fracture toughness of different zirconia electrolytes as well as the change of the elastic constants. 3YSZ and 6ScSZ materials are characterised regarding the influence of sub critical crack growth (SCCG) as one of the main lifetime limiting effects for ceramics at elevated temperatures. In addition, the reliability of different zirconia tapes is assessed with respect to temperature and SCCG. It was found that the strength is only influenced by temperature through the change in fracture toughness. SCCG has a large influence on the strength and the lifetime for intermediate temperature, while its impact becomes limited at temperatures higher than 650 °C. In this context the tetragonal 3YSZ and 6ScSZ behave quite different than the cubic 10Sc1CeSZ, so that at 850 °C it can be regarded as competitive compared to the tetragonal compounds.

  10. An approach for restoring the proton conductivity of sintered tin pyrophosphate membranes for intermediate temperature fuel cells

    NASA Astrophysics Data System (ADS)

    Li, Wei; Bose, Anima B.; Rusakova, Irene A.

    2016-03-01

    Tin pyrophosphate (SnP2O7) membranes need a sintering process to achieve a required mechanical strength as the electrolyte of intermediate temperature fuel cells (IT-FCs) operating at temperatures of 200-300 °C at large scale. However, sintering causes a severe drop of proton conductivity due to the decomposition of SnP2O7 and release of residual fused phosphoric acid and/or phosphorous oxides. Here we demonstrate a route to restore the proton conductivity by introducing phosphoric acid inside a sintered SnP2O7 membrane to react with the degraded SnP2O7 for restoration. After restoration, the decomposition product SnO2 is converted back to SnP2O7 and fused phosphoric acid and/or phosphorous oxides (17.7-20.0%) is regenerated. The proton conductivity is tremendously enhanced from 9.7 × 10-4 S cm-1 to 0.061 S cm-1 at 225 °C. A planar IT-FC (active area = 5 cm2) with a restored membrane (thickness = 0.85 mm, diameter = 40 mm) generates a peak power density of 78 mW cm-2 without using intermediate catalyst layers at 225 °C. It can steadily run for 45 h at 100 mA cm-2 with a degradation rate of 0.7 mV h-1 at 225 °C. The fuel and oxidant are, respectively, H2 (50 sccm) and air (100 sccm) humidified at 30 °C.

  11. Thin-film electrolytes for reduced temperature solid oxide fuel cells

    SciTech Connect

    Visco, S.J.; Wang, L.S.; De Souza, S.; De Jonghe, L.C.

    1994-11-01

    Solid oxide fuel cells produce electricity at very high efficiency and have very low to negligible emissions, making them an attractive option for power generation for electric utilities. However, conventional SOFC`s are operated at 1000{degrees}C or more in order to attain reasonable power density. The high operating temperature of SOFC`s leads to complex materials problems which have been difficult to solve in a cost-effective manner. Accordingly, there is much interest in reducing the operating temperature of SOFC`s while still maintaining the power densities achieved at high temperatures. There are several approaches to reduced temperature operation including alternative solid electrolytes having higher ionic conductivity than yttria stabilized zirconia, thin solid electrolyte membranes, and improved electrode materials. Given the proven reliability of zirconia-based electrolytes (YSZ) in long-term SOFC tests, the use of stabilized zirconia electrolytes in reduced temperature fuel cells is a logical choice. In order to avoid compromising power density at intermediate temperatures, the thickness of the YSZ electrolyte must be reduced from that in conventional cells (100 to 200 {mu}m) to approximately 4 to 10 {mu}m. There are a number of approaches for depositing thin ceramic films onto porous supports including chemical vapor deposition/electrochemical vapor deposition, sol-gel deposition, sputter deposition, etc. In this paper we describe an inexpensive approach involving the use of colloidal dispersions of polycrystalline electrolyte for depositing 4 to 10 {mu}m electrolyte films onto porous electrode supports in a single deposition step. This technique leads to highly dense, conductive, electrolyte films which exhibit near theoretical open circuit voltages in H{sub 2}/air fuel cells. These electrolyte films exhibit bulk ionic conductivity, and may see application in reduced temperature SOFC`s, gas separation membranes, and fast response sensors.

  12. Temperature dependence of an abiotic glucose/air alkaline fuel cell

    NASA Astrophysics Data System (ADS)

    Orton, Dane; Scott, Daniel

    2015-11-01

    The temperature dependence of a previously developed glucose fuel cell is explored. This cell uses a small molecule dye mediator to transport oxidizable electrons from glucose to a carbon felt anode. This reaction is driven by an air breathing MnO2 cathode. This research investigates how the temperature of the system affects the power production of the fuel cell. Cell performance is observed using either methyl viologen, indigo carmine, trypan blue, or hydroquinone as a mediator at temperatures of 15, 19, 27, 32, 37, 42, and 49 °C. Cyclic voltammetry of the cell anode at the given temperatures with the individual dyes is also presented. The highest power production amongst all of the cells occurs at 32 °C. This occurs with the mediator indigo carmine or with the mediator methyl viologen. These sustained powers are 2.31 mW cm-2 and 2.39 mW cm-2, respectively. This is approximately a 350% increase for these cells compared to their power produced at room temperature. This dramatic increase is likely due to increased solubility of the mediator dye at higher temperatures.

  13. Proton conducting intermediate-temperature solid oxide fuel cells using new perovskite type cathodes

    NASA Astrophysics Data System (ADS)

    Li, Meiling; Ni, Meng; Su, Feng; Xia, Changrong

    2014-08-01

    Sr2Fe1.5Mo0.5O6-δ (SFM) is proposed as the electrodes for symmetric solid oxide fuel cells (SOFCs) based on oxygen-ion conducting electrolytes. In this work SFM is investigated as the cathodes for SOFCs with proton conducting BaZr0.1Ce0.7Y0.2O3-δ (BZCY) electrolyte. SFM is synthesized with a combined glycine and citric acid method and shows very good chemical compatibility with BZCY under 1100 °C. Anode-supported single cell (Ni-BZCY anode, BZCY electrolyte, and SFM-BZCY cathode) and symmetrical fuel cell (SFM-BZCY electrodes and BZCY electrolyte) are fabricated and their performances are measured. Impedance spectroscopy on symmetrical cell consisting of BZCY electrolyte and SFM-BZCY electrodes demonstrates low area-specific interfacial polarization resistance Rp, and the lowest Rp, 0.088 Ω cm2 is achieved at 800 °C when cathode is sintered at 900 °C for 2 h. The single fuel cell achieves 396 mW cm-2 at 800 °C in wet H2 (3 vol% H2O) at a co-sintering temperature of 1000 °C. This study demonstrates the potential of SFM-BZCY as a cathode material in proton-conducting intermediate-temperature solid oxide fuel cells.

  14. Long term testing of start-stop cycles on high temperature PEM fuel cell stack

    NASA Astrophysics Data System (ADS)

    Kannan, Arvind; Kabza, Alexander; Scholta, Joachim

    2015-03-01

    A PEM fuel cell with an operating temperature above 100 °C is desired for increasing the kinetics of reactions, reduced sensitivity to impurities of the fuel, as well as for the reduction of the requirements on thermal and water management systems. High Temperature Polymer Electrolyte Membrane Fuel Cells (HT-PEMFC) can effectively be combined with CHP systems to offer a simple system design and higher overall system efficiencies. For HT-PEMFC systems, the development of elaborated start/stop strategies is essential in mitigation of fuel cell degradation during these events. A 5 cell co-flow stack is assembled with BASF P1100W membrane electrode assembly (MEA) with an active area of 163.5 cm2. Continuous operation and more than 1500 start stop cycles have been performed in order to study the degradation effects of both continuous operation and of repeated start stops using a protective start-stop algorithm, which is designed to avoid the formation of aggressive cell potentials. The repeated use of this procedure led to a degradation of 26 μV/cycle at a current density of 0.25 A cm-2 and 11 μV/cycle at a current density of 0.03 A cm-2. At open circuit voltage (OCV), a higher degradation rate of 133 μV/cycle was observed.

  15. Fundamental research in the area of high temperature fuel cells in Russia

    SciTech Connect

    Dyomin, A.K.

    1996-04-01

    Research in the area of molten carbonate and solid oxide fuel cells has been conducted in Russia since the late 60`s. Institute of High Temperature Electrochemistry is the lead organisation in this area. Research in the area of materials used in fuel cells has allowed us to identify compositions of electrolytes, electrodes, current paths and transmitting, sealing and structural materials appropriate for long-term fuel cell applications. Studies of electrode processes resulted in better understanding of basic patterns of electrode reactions and in the development of a foundation for electrode structure optimization. We have developed methods to increase electrode activity levels that allowed us to reach current density levels of up to 1 amper/cm{sup 2}. Development of mathematical models of processes in high temperature fuel cells has allowed us to optimize their structure. The results of fundamental studies have been tested on laboratory mockups. MCFC mockups with up to 100 W capacity and SOFC mockups with up to 1 kW capacity have been manufactured and tested at IHTE. There are three SOFC structural options: tube, plate and modular.

  16. Initial conditioning of polymer eelectrolyte membrane fuel cell by temperature and potential cycling.

    PubMed

    Bezmalinović, Dario; Radošević, Jagoda; Barbir, Frano

    2015-01-01

    Polymer electrolyte membrane fuel cells need initial conditioning, activation or break-in the first time they are operated after being assembled. During this period performance of the fuel cell improves until it reaches its nominal performance. The exact mechanism of this initial conditioning is not completely understood, but it is assumed that during the conditioning process the polymer membrane, as well as the polymer in the catalyst layer, get humidified, and the number of active catalyst sites increases. Activation procedure proposed here consists of temperature and potential cycling. Temperature cycling is a new approach for the conditioning and the idea is to rapidly cool the running cell at some point to allow the membrane to equilibrate with condensed water which should result in higher intake of water within the membrane. The results show that proposed procedure is better or at least comparable to some conventional procedures for the initial conditioning. PMID:25830963

  17. STABLE HIGH CONDUCTIVITY BILAYERED ELECTROLYTES FOR LOW TEMPERATURE SOLID OXIDE FUEL CELLS

    SciTech Connect

    Eric D. Wachsman

    2000-10-01

    Solid oxide fuel cells (SOFCs) are the future of energy production in America. They offer great promise as a clean and efficient process for directly converting chemical energy to electricity while providing significant environmental benefits (they produce negligible CO, HC, or NOx and, as a result of their high efficiency, produce about one-third less CO{sub 2} per kilowatt hour than internal combustion engines). Unfortunately, the current SOFC technology, based on a stabilized zirconia electrolyte, must operate in the region of 1000 C to avoid unacceptably high ohmic losses. These high temperatures demand (a) specialized (expensive) materials for the fuel cell interconnects and insulation, (b) time to heat up to the operating temperature and (c) energy input to arrive at the operating temperature. Therefore, if fuel cells could be designed to give a reasonable power output at lower temperatures tremendous benefits may be accrued, not the least of which is reduced cost. The problem is, at lower temperatures the conductivity of the conventional stabilized zirconia electrolyte decreases to the point where it cannot supply electrical current efficiently to an external load. The primary objectives of the proposed research is to develop a stable high conductivity (>0.05 S cm{sup -1} at 550 C) electrolyte for lower temperature SOFCs. This objective is specifically directed toward meeting the lowest (and most difficult) temperature criteria for the 21st Century Fuel Cell Program. Meeting this objective provides a potential for future transportation applications of SOFCs, where their ability to directly use hydrocarbon fuels could permit refueling within the existing transportation infrastructure. In order to meet this objective we are developing a functionally gradient bilayer electrolyte comprised of bismuth oxide on the air side and ceria on the fuel side. Bismuth oxide and doped ceria are among the highest ionic conducting electrolytes and in fact bismuth oxide based

  18. Performance analysis results of a battery fuel gauge algorithm at multiple temperatures

    NASA Astrophysics Data System (ADS)

    Balasingam, B.; Avvari, G. V.; Pattipati, K. R.; Bar-Shalom, Y.

    2015-01-01

    Evaluating a battery fuel gauge (BFG) algorithm is a challenging problem due to the fact that there are no reliable mathematical models to represent the complex features of a Li-ion battery, such as hysteresis and relaxation effects, temperature effects on parameters, aging, power fade (PF), and capacity fade (CF) with respect to the chemical composition of the battery. The existing literature is largely focused on developing different BFG strategies and BFG validation has received little attention. In this paper, using hardware in the loop (HIL) data collected form three Li-ion batteries at nine different temperatures ranging from -20 °C to 40 °C, we demonstrate detailed validation results of a battery fuel gauge (BFG) algorithm. The BFG validation is based on three different BFG validation metrics; we provide implementation details of these three BFG evaluation metrics by proposing three different BFG validation load profiles that satisfy varying levels of user requirements.

  19. Coke-free direct formic acid solid oxide fuel cells operating at intermediate temperatures

    NASA Astrophysics Data System (ADS)

    Chen, Yubo; Su, Chao; Zheng, Tao; Shao, Zongping

    2012-12-01

    Formic acid is investigated as a fuel for Solid Oxide Fuel Cells (SOFCs) for the first time. Thermodynamic calculations demonstrate that carbon deposition is avoidable above 600 °C. The carbon deposition properties are also investigated experimentally by first treating a nickel plus yttria-stabilized zirconia (Ni-YSZ) anode material in particle form under a formic acid-containing atmosphere for a limited time at 500-800 °C and then analyzing the particles by O2-TPO. This analysis confirms that carbon deposition on Ni-YSZ is weak above 600 °C. We further treat half-cells composed of YSZ electrolyte and Ni-YSZ anode under formic acid-containing atmosphere at 600, 700 and 800 °C; the anodes maintain their original geometric shape and microstructure and show no obvious weight gain. It suggests that formic acid can be directly fed into SOFCs constructed with conventional nickel-based cermet anodes. I-V tests show that the cell delivers a promising peak power density of 571 mW cm-2 at 800 °C. In addition, the cells also show good performance stability. The results indicate that formic acid is highly promising as a direct fuel for SOFCs without the need for cell material modifications.

  20. Temperature of aircraft cargo flame exposure during accidents involving fuel spills

    SciTech Connect

    Mansfield, J.A.

    1993-01-01

    This report describes an evaluation of flame exposure temperatures of weapons contained in alert (parked) bombers due to accidents that involve aircraft fuel fires. The evaluation includes two types of accident, collisions into an alert aircraft by an aircraft that is on landing or take-off, and engine start accidents. Both the B-1B and B-52 alert aircraft are included in the evaluation.

  1. High-Temperature Desulfurization of Heavy Fuel-Derived Reformate Gas Streams for SOFC Applications

    NASA Technical Reports Server (NTRS)

    Flytzani-Stephanopoulos, Maria; Surgenor, Angela D.

    2007-01-01

    Desulfurization of the hot reformate gas produced by catalytic partial oxidation or autothermal reforming of heavy fuels, such as JP-8 and jet fuels, is required prior to using the gas in a solid oxide fuel cell (SOFC). Development of suitable sorbent materials involves the identification of sorbents with favorable sulfidation equilibria, good kinetics, and high structural stability and regenerability at the SOFC operating temperatures (650 to 800 C). Over the last two decades, a major barrier to the development of regenerable desulfurization sorbents has been the gradual loss of sorbent performance in cyclic sulfidation and regeneration at such high temperatures. Mixed oxide compositions based on ceria were examined in this work as regenerable sorbents in simulated reformate gas mixtures and temperatures greater than 650 C. Regeneration was carried out with dilute oxygen streams. We have shown that under oxidative regeneration conditions, high regeneration space velocities (greater than 80,000 h(sup -1)) can be used to suppress sulfate formation and shorten the total time required for sorbent regeneration. A major finding of this work is that the surface of ceria and lanthanan sorbents can be sulfided and regenerated completely, independent of the underlying bulk sorbent. This is due to reversible adsorption of H2S on the surface of these sorbents even at temperatures as high as 800 C. La-rich cerium oxide formulations are excellent for application to regenerative H2S removal from reformate gas streams at 650 to 800 C. These results create new opportunities for compact sorber/regenerator reactor designs to meet the requirements of solid oxide fuel cell systems at any scale.

  2. Coal-fuelled systems for peaking power with 100% CO2 capture through integration of solid oxide fuel cells with compressed air energy storage

    NASA Astrophysics Data System (ADS)

    Nease, Jake; Adams, Thomas A.

    2014-04-01

    In this study, a coal-fuelled integrated solid oxide fuel cell (SOFC) and compressed air energy storage (CAES) system in a load-following power production scenario is discussed. Sixteen SOFC-based plants with optional carbon capture and sequestration (CCS) and syngas shifting steps are simulated and compared to a state-of-the-art supercritical pulverised coal (SCPC) plant. Simulations are performed using a combination of MATLAB and Aspen Plus v7.3. It was found that adding CAES to a SOFC-based plant can provide load-following capabilities with relatively small effects on efficiencies (1-2% HHV depending on the system configuration) and levelized costs of electricity (∼0.35 ¢ kW-1 h-1). The load-following capabilities, as measured by least-squares metrics, show that this system may utilize coal and achieve excellent load-tracking that is not adversely affected by the inclusion of CCS. Adding CCS to the SOFC/CAES system reduces measurable direct CO2 emission to zero. A seasonal partial plant shutdown schedule is found to reduce fuel consumption by 9.5% while allowing for cleaning and maintenance windows for the SOFC stacks without significantly affecting the performance of the system (∼1% HHV reduction in efficiency). The SOFC-based systems with CCS are found to become economically attractive relative to SCPC above carbon taxes of 22 ton-1.

  3. LIQUID BIO-FUEL PRODUCTION FROM NON-FOOD BIOMASS VIA HIGH TEMPERATURE STEAM ELECTROLYSIS

    SciTech Connect

    G. L. Hawkes; J. E. O'Brien; M. G. McKellar

    2011-11-01

    Bio-Syntrolysis is a hybrid energy process that enables production of synthetic liquid fuels that are compatible with the existing conventional liquid transportation fuels infrastructure. Using biomass as a renewable carbon source, and supplemental hydrogen from high-temperature steam electrolysis (HTSE), bio-syntrolysis has the potential to provide a significant alternative petroleum source that could reduce US dependence on imported oil. Combining hydrogen from HTSE with CO from an oxygen-blown biomass gasifier yields syngas to be used as a feedstock for synthesis of liquid transportation fuels via a Fischer-Tropsch process. Conversion of syngas to liquid hydrocarbon fuels, using a biomass-based carbon source, expands the application of renewable energy beyond the grid to include transportation fuels. It can also contribute to grid stability associated with non-dispatchable power generation. The use of supplemental hydrogen from HTSE enables greater than 90% utilization of the biomass carbon content which is about 2.5 times higher than carbon utilization associated with traditional cellulosic ethanol production. If the electrical power source needed for HTSE is based on nuclear or renewable energy, the process is carbon neutral. INL has demonstrated improved biomass processing prior to gasification. Recyclable biomass in the form of crop residue or energy crops would serve as the feedstock for this process. A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-blown biomass gasifier. Based on the gasifier temperature, 94% to 95% of the carbon in the biomass becomes carbon monoxide in the syngas (carbon monoxide and hydrogen). Assuming the thermal efficiency of the power

  4. Composite electrolyte with proton conductivity for low-temperature solid oxide fuel cell

    SciTech Connect

    Raza, Rizwan; Ahmed, Akhlaq; Akram, Nadeem; Saleem, Muhammad; Niaz Akhtar, Majid; Ajmal Khan, M.; Abbas, Ghazanfar; Alvi, Farah; Yasir Rafique, M.; Sherazi, Tauqir A.; Shakir, Imran; Mohsin, Munazza; Javed, Muhammad Sufyan; Zhu, Bin E-mail: zhubin@hubu.edu.cn

    2015-11-02

    In the present work, cost-effective nanocomposite electrolyte (Ba-SDC) oxide is developed for efficient low-temperature solid oxide fuel cells (LTSOFCs). Analysis has shown that dual phase conduction of O{sup −2} (oxygen ions) and H{sup +} (protons) plays a significant role in the development of advanced LTSOFCs. Comparatively high proton ion conductivity (0.19 s/cm) for LTSOFCs was achieved at low temperature (460 °C). In this article, the ionic conduction behaviour of LTSOFCs is explained by carrying out electrochemical impedance spectroscopy measurements. Further, the phase and structure analysis are investigated by X-ray diffraction and scanning electron microscopy techniques. Finally, we achieved an ionic transport number of the composite electrolyte for LTSOFCs as high as 0.95 and energy and power density of 90% and 550 mW/cm{sup 2}, respectively, after sintering the composite electrolyte at 800 °C for 4 h, which is promising. Our current effort toward the development of an efficient, green, low-temperature solid oxide fuel cell with the incorporation of high proton conductivity composite electrolyte may open frontiers in the fields of energy and fuel cell technology.

  5. Morphology studies on high-temperature polymer electrolyte membrane fuel cell electrodes

    NASA Astrophysics Data System (ADS)

    Mack, Florian; Klages, Merle; Scholta, Joachim; Jörissen, Ludwig; Morawietz, Tobias; Hiesgen, Renate; Kramer, Dominik; Zeis, Roswitha

    2014-06-01

    The electrode morphology influences the properties and performance of polymer electrolyte membrane fuel cells (PEMFC). Here we report our studies of two different electrodes for high-temperature PEMFC prepared by spraying and coating and their impact on the fuel cell performance. Differences in 3D microstructure and adhesion between catalyst layer and gas diffusion layer (GDL) of the electrodes were studied with X-ray microtomography. Scanning electrode microscope investigations show hairline cracks between agglomerates on the surface of the sprayed electrode, whereas the coated electrode shows a network of shrinkage cracks in the catalyst layer. The distribution of the electrode binder polytetrafluoroethylene (PTFE) is related to the locally resolved conductivity, which was determined by scanning the electrode surfaces with a conductive atomic force microscopy (AFM) tip. The macrostructures of the sprayed and coated electrodes are different but contain similar pore structures. The coated electrode has a higher PTFE concentration on the top region, which tends to form a nonconductive and less wettable "skin" on the electrode surface and delays the start-up of the fuel cell. In contrast to low-temperature PEMFC, the electrode morphology has only a minor impact on the steady-state cell performance of high-temperature PEMFC.

  6. High-Temperature, Dual-Atmosphere Corrosion of Solid-Oxide Fuel Cell Interconnects

    NASA Astrophysics Data System (ADS)

    Gannon, Paul; Amendola, Roberta

    2012-12-01

    High-temperature corrosion of ferritic stainless steel (FSS) surfaces can be accelerated and anomalous when it is simultaneously subjected to different gaseous environments, e.g., when separating fuel (hydrogen) and oxidant (air) streams, in comparison with single-atmosphere exposures, e.g., air only. This so-called "dual-atmosphere" exposure is realized in many energy-conversion systems including turbines, boilers, gasifiers, heat exchangers, and particularly in intermediate temperature (600-800°C) planar solid-oxide fuel cell (SOFC) stacks. It is generally accepted that hydrogen transport through the FSS (plate or tube) and its subsequent integration into the growing air-side surface oxide layer can promote accelerated and anomalous corrosion—relative to single-atmosphere exposure—via defect chemistry changes, such as increased cation vacancy concentrations, decreased oxygen activity, and steam formation within the growing surface oxide layers. Establishment of a continuous and dense surface oxide layer on the fuel side of the FSS can inhibit hydrogen transport and the associated effects on the air side. Minor differences in FSS composition, microstructure, and surface conditions can all have dramatic influences on dual-atmosphere corrosion behaviors. This article reviews high-temperature, dual-atmosphere corrosion phenomena and discusses implications for SOFC stacks, related applications, and future research.

  7. STABLE HIGH CONDUCTIVITY BILAYERED ELECTROLYTES FOR LOW TEMPERATURE SOLID OXIDE FUEL CELLS

    SciTech Connect

    Eric D. Wachsman; Keith L. Duncan

    2002-03-31

    Solid oxide fuel cells (SOFCs) are the future of energy production in America. They offer great promise as a clean and efficient process for directly converting chemical energy to electricity while providing significant environmental benefits (they produce negligible hydrocarbons, CO, or NO{sub x} and, as a result of their high efficiency, produce about one-third less CO{sub 2} per kilowatt hour than internal combustion engines). Unfortunately, the current SOFC technology, based on a stabilized zirconia electrolyte, must operate in the region of 1000 C to avoid unacceptably high ohmic losses. These high temperatures demand (a) specialized (expensive) materials for the fuel cell interconnects and insulation, (b) time to heat up to the operating temperature and (c) energy input to arrive at the operating temperature. Therefore, if fuel cells could be designed to give a reasonable power output at low to intermediate temperatures tremendous benefits may be accrued. At low temperatures, in particular, it becomes feasible to use ferritic steel for interconnects instead of expensive and brittle ceramic materials such as those based on LaCrO{sub 3}. In addition, sealing the fuel cell becomes easier and more reliable; rapid startup is facilitated; thermal stresses (e.g., those caused by thermal expansion mismatches) are reduced; radiative losses ({approx}T{sup 4}) become minimal; electrode sintering becomes negligible and (due to a smaller thermodynamic penalty) the SOFC operating cycle (heating from ambient) would be more efficient. Combined, all these improvements further result in reduced initial and operating costs. The problem is, at lower temperatures the conductivity of the conventional stabilized zirconia electrolyte decreases to the point where it cannot supply electrical current efficiently to an external load. The primary objectives of the proposed research is to develop a stable high conductivity (> 0.05 S cm{sup -1} at {le} 550 C) electrolyte for lower

  8. Transient fuel-pin temperature calculations using describing functions. Final report. [PWR; BWR

    SciTech Connect

    Guidotti, T.E.; Peddicord, K.L.; Nielsen, L.H.

    1982-02-01

    Temperature dependent properties make the transient thermal analysis of reactor fuel pins nonlinear. Traditionally, finite difference or finite element methods have been used to solve this system. An analytically based method is presented in which the transient temperature profiles are calculated using describing functions to characterize the system nonlinearities. In the past the describing functions approach has been used exclusively in the solution of ordinary differential equation systems. This study appears to be the first application of describing functions in the solution of partial differential equations.

  9. Some Effects of Air and Fuel Oil Temperatures on Spray Penetration and Dispersion

    NASA Technical Reports Server (NTRS)

    Gelalles, A G

    1930-01-01

    Presented here are experimental results obtained from a brief investigation of the appearance, penetration, and dispersion of oil sprays injected into a chamber of highly heated air at atmospheric pressure. The development of single sprays injected into a chamber containing air at room temperature and at high temperature was recorded by spray photography equipment. A comparison of spray records showed that with the air at the higher temperature, the spray assumed the appearance of thin, transparent cloud, the greatest part of which rapidly disappeared from view. With the chamber air at room temperature, a compact spray with an opaque core was obtained. Measurements of the records showed a decrease in penetration and an increase in the dispersion of the spray injected into the heated air. No ignition of the fuel injected was observed or recorded until the spray particles came in contact with the much hotter walls of the chamber about 0.3 second after the start of injection.

  10. Investigation of breadboard temperature profiling system for SSME fuel preburner diagnostics

    NASA Technical Reports Server (NTRS)

    Shirley, J. A.

    1986-01-01

    The feasibility of measuring temperatures in the space shuttle main engine (SSME) fuel preburner using spontaneous Raman scattering from molecular hydrogen was studied. Laser radiation is transmitted to the preburner through a multimode optical fiber. Backscattered Raman-shifted light is collected and focused into a second fiber which connects to a remote-located spectrograph and a mutlichannel optical detector. Optics collimate and focus laser light from the transmitter fiber defining the probe volume. The high pressure, high temperature preburner environment was simulated by a heated pressure cell. Temperatures determined by the distribution of Q-branch co-vibrational transitions demonstrate precision and accuracy of 3%. It is indicated heat preburner temperatures can be determined with 5% accuracy with spatial resolution less than 1 cm and temporal resolution of 10 millisec at the nominal preburner operation conditions.

  11. High-temperature Chemical Compatibility of As-fabricated TRIGA Fuel and Type 304 Stainless Steel Cladding

    SciTech Connect

    Dennis D. Keiser, Jr.; Jan-Fong Jue; Eric Woolstenhulme; Kurt Terrani; Glenn A. Moore

    2012-09-01

    Chemical interaction between TRIGA fuel and Type-304 stainless steel cladding at relatively high temperatures is of interest from the point of view of understanding fuel behavior during different TRIGA reactor transient scenarios. Since TRIGA fuel comes into close contact with the cladding during irradiation, there is an opportunity for interdiffusion between the U in the fuel and the Fe in the cladding to form an interaction zone that contains U-Fe phases. Based on the equilibrium U-Fe phase diagram, a eutectic can develop at a composition between the U6Fe and UFe2 phases. This eutectic composition can become a liquid at around 725°C. From the standpoint of safe operation of TRIGA fuel, it is of interest to develop better understanding of how a phase with this composition may develop in irradiated TRIGA fuel at relatively high temperatures. One technique for investigating the development of a eutectic phase at the fuel/cladding interface is to perform out-of-pile diffusion-couple experiments at relatively high temperatures. This information is most relevant for lightly irradiated fuel that just starts to touch the cladding due to fuel swelling. Similar testing using fuel irradiated to different fission densities should be tested in a similar fashion to generate data more relevant to more heavily irradiated fuel. This report describes the results for TRIGA fuel/Type-304 stainless steel diffusion couples that were annealed for one hour at 730 and 800°C. Scanning electron microscopy with energy- and wavelength-dispersive spectroscopy was employed to characterize the fuel/cladding interface for each diffusion couple to look for evidence of any chemical interaction. Overall, negligible fuel/cladding interaction was observed for each diffusion couple.

  12. Combustion Temperature Measurement by Spontaneous Raman Scattering in a Jet-A Fueled Gas Turbine Combustor Sector

    NASA Technical Reports Server (NTRS)

    Hicks, Yolanda R.; DeGroot, Wilhelmus A.; Locke, Randy J.; Anderson, Robert C.

    2002-01-01

    Spontaneous vibrational Raman scattering was used to measure temperature in an aviation combustor sector burning jet fuel. The inlet temperature ranged from 670 K (750 F) to 756 K (900 F) and pressures from 13 to 55 bar. With the exception of a discrepancy that we attribute to soot, good agreement was seen between the Raman-derived temperatures and the theoretical temperatures calculated from the inlet conditions. The technique used to obtain the temperature uses the relationship between the N2 anti-Stokes and Stokes signals, within a given Raman spectrum. The test was performed using a NASA-concept fuel injector and Jet-A fuel over a range of fuel/air ratios. This work represents the first such measurements in a high-pressure, research aero-combustor facility.

  13. An analytical study of volatile metallic fission product release from very high temperature gas-cooled reactor fuel and core

    SciTech Connect

    Mitake, S.; Okamoto, F.

    1988-04-01

    Release characteristics of volatile metallic fission products from the coated fuel particle and the reactor core for a very high temperature gas-cooled reactor during its power operation has been studied using numerical analysis. A computer code FORNAX, based on Fick's diffusion law and the evaporation mass transfer relation, has been developed, which considers, in particular, distribution and time histories of power density, fuel temperature, and failed and degraded fuel particle fractions in the core. Applicability of the code to evaluate the core design has been shown and the following have been indicated on the release of cesium from the reactor: 1. The release from the intact fuel particles by diffusion through their intact coatings shows larger contribution in the total core release at higher temperature. 2. The diffusion release from the intact particle is governed not only by the diffusion in the silicon carbide layer but also by that in the fuel kernel.

  14. Studies of Temperature Elevation Due to the Pre-flame Reaction in a Spark-ignition Engine with CARS Temperature Measurements Using Fuels of Various Octane Numbers

    NASA Astrophysics Data System (ADS)

    Choi, Inyong; Chun, Kwang Min; Hahn, Jae Won; Park, Chul-Woung

    The unburned end-gas temperatures in a combustion chamber of a conventional 4-cylinder DOHC spark-ignition engine were measured using the broadband CARS temperature measurement technique. The test engine was fueled with primary reference fuel 80 and gasoline with research octane numbers of 70.9, 83.4, 91.5 and 100.4. The measured CARS temperatures were compared with the adiabatic core temperatures calculated from the measured pressures. Significant heating by pre-flame reaction in the end gas zone was observed in the late part of compression stroke under both knocking and non-knocking conditions. The measured CARS temperatures when the cylinder pressures were above 1400kPa were higher than the calculated adiabatic core temperatures. These results indicate that some exothermic reactions exist in relatively low pressure and temperature regions. The CARS temperatures began to be higher than the adiabatic core temperature when the end-gas temperatures reached 700K. The temperature elevation due to the pre-flame reaction correlated well with the unburned gas CARS temperature for different research octane number fuels tested.

  15. Investigation of the feasibility of temperature profiling optical diagnostics in the SSME fuel pre-burner

    NASA Technical Reports Server (NTRS)

    Shirley, J. A.

    1983-01-01

    Results of an analytical investigation to determine the feasibility of temperature profiling in the space shuttle main engine (SSME) fuel preburner are presented. In this application it is desirable to measure temperature in the preburner combustor with a remote, nonintrusive optical technique. Several techniques using laser excitation were examined with a consideration of the constraints imposed by optical access in the fuel preburner and the problems associated with operation near the functioning space shuttle engine. The potential performance of practical diagnostic systems based on spontaneous Raman backscattering, laser induced fluorescence, and coherent anti-Stokes Raman spectroscopy were compared analytically. A system using collection of spontaneous Raman backscattering excited by a remotely located 5 to 10 watt laser propagated to the SSME through a small diameter optical fiber was selected as the best approach. Difficulties normally associated with Raman scattering: weak signal strength and interference due to background radiation are not expected to be problematic due to the very high density in this application, and the low flame luminosity expected in the fuel rich hydrogen oxygen flame.

  16. Evaluation of lower flammability limits of fuel-air-diluent mixtures using calculated adiabatic flame temperatures.

    PubMed

    Vidal, M; Wong, W; Rogers, W J; Mannan, M S

    2006-03-17

    The lower flammability limit (LFL) of a fuel is the minimum composition in air over which a flame can propagate. Calculated adiabatic flame temperatures (CAFT) are a powerful tool to estimate the LFL of gas mixtures. Different CAFT values are used for the estimation of LFL. SuperChems is used by industry to perform flammability calculations under different initial conditions which depends on the selection of a threshold temperature. In this work, the CAFT at the LFL is suggested for mixtures of fuel-air and fuel-air-diluents. These CAFT can be used as the threshold values in SuperChems to calculate the LFL. This paper discusses an approach to evaluate the LFL in the presence of diluents such as N2 and CO2 by an algebraic method and by the application of SuperChems using CAFT as the basis of the calculations. The CAFT for different paraffinic and unsaturated hydrocarbons are presented as well as an average value per family of chemicals. PMID:16309829

  17. NanoCapillary Network Proton Conducting Membranes for High Temperature Hydrogen/Air Fuel Cells

    SciTech Connect

    Pintauro, Peter

    2012-07-09

    The objective of this proposal is to fabricate and characterize a new class of NanoCapillary Network (NCN) proton conducting membranes for hydrogen/air fuel cells that operate under high temperature, low humidity conditions. The membranes will be intelligently designed, where a high density interconnecting 3-D network of nm-diameter electrospun proton conducting polymer fibers is embedded in an inert (uncharged) water/gas impermeable polymer matrix. The high density of fibers in the resulting mat and the high ion-exchange capacity of the fiber polymer will ensure high proton conductivity. To further enhance water retention, molecular silica will be added to the sulfonated polymer fibers. The uncharged matrix material will control water swelling of the high ion-exchange capacity proton conducting polymer fibers and will impart toughness to the final nanocapillary composite membrane. Thus, unlike other fuel cell membranes, the role of the polymer support matrix will be decoupled from that of the proton-conducting channels. The expected final outcome of this 5-year project is the fabrication of fuel cell membranes with properties that exceed the DOE’s technical targets, in particular a proton conductivity of 0.1 S/cm at a temperature less than or equal to120°C and 25-50% relative humidity.

  18. Ignition experiment of a fuel droplet in high-pressure high-temperature ambient

    SciTech Connect

    Nakanishi, Ryota; Kobayashi, Hideaki; Kato, Shinichiro; Niioka, Takashi

    1994-12-31

    In order to obtain the ignition behavior at supercritical pressures, ignition times of a single fuel droplet were measured in high-pressure high-temperature ambient. A suspended droplet of n-hexadecane or n-heptane with a diameter of 0.35--1.4 min was quickly immersed in an electric furnace with a temperature up to 950 K. Attachment of the droplet, movement of the furnace, and ignition measurement were carried out in an air vessel with pressures up to 3 MPa. At low pressures, ignition times of both fuels decreased with the initial droplet diameter and then increased. Therefore, the ignition time variation with the initial droplet diameter has a minimum. This phenomenon, however, disappeared at high pressures. Also, the ignitable limit of droplet diameter, below which the droplet vaporized completely before ignition, decreased as pressure increased. In the case of a droplet burning at high pressures, the preceding experiment showed that the burning rate constant increased and had a maximum around the critical pressure of fuel. This is significantly caused by variable properties around the critical point such as thermal conductivity and diffusion coefficient; and therefore, the present ignition time was expected to show similar characteristics due to the same reason. Ignition time, however, decreased monotonously with pressure, and even at supercritical pressures, the ignition time behavior did not change much. Being different from the case of combustion, it is suggested that drastic changes of properties did not take place in ignition processes.

  19. Studies in new materials for intermediate temperature solid oxide fuel cells

    NASA Astrophysics Data System (ADS)

    Skinner, Alex W.

    Ceramic materials have historically been of interest for their thermal and mechanical properties. However, certain ceramic materials can have very interesting electrical, magnetic and optical properties, leading to a new subclass, the electroceramics. Perovskites, in particular, have become the subject of intense research in this field. Specifically, doped barium zirconates have shown high proton conductivity in the intermediate temperature range (600--800°C), making them advantageous for use in solid oxide fuel cells. Solid oxide fuel cells (SOFCs) are electrochemical devices that convert chemical energy into electricity using ion-conducting oxide ceramics as electrolytes. The anode component of the cell is also of interest. Cermets or ceramic metals can serve a dual role as substrates for thin film electrolytes and anodes in the cell. Thin films of gadolinium and ytterbium doped barium zirconate were deposited using pulsed laser deposition (KrF; 1--3 J/cm2) on several substrates, including cermets developed in our lab, in a 10--400 mTorr oxygen environment with various substrate temperatures. Crystalline structure and chemical composition was determined by X-ray diffraction (XRD) and energy dispersive x-ray analysis, respectively. Preliminary electrical measurements of the electrolyte/cermet structure were taken using electrochemical impedance spectroscopy. Keywords: solid oxide fuel cells (SOFCs), perovskites, proton conductors, electroceramics, gadolinium-doped barium zirconate (BZG).

  20. Portable peak flow meters.

    PubMed

    McNaughton, J P

    1997-02-01

    There are several portable peak flow meters available. These instruments vary in construction and performance. Guidelines are recommended for minimum performance and testing of portable peak flow meters, with the aim of establishing a procedure for standardizing all peak flow meters. Future studies to clarify the usefulness of mechanical test apparatus and clinical trials of peak flow meters are also recommended. PMID:9098706

  1. 40 CFR 1066.710 - Cold temperature testing procedures for measuring CO and NMHC emissions and determining fuel...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... CFR 86.1840 if a vehicle's climate control system is not compatible with the provisions of this... testing as specified 40 CFR Part 1065, subpart H. The temperature of the dispensed test fuel must be at or... for measuring CO and NMHC emissions and determining fuel economy. 1066.710 Section 1066.710...

  2. AuPd/polyaniline as the anode in an ethylene glycol microfluidic fuel cell operated at room temperature.

    PubMed

    Arjona, N; Palacios, A; Moreno-Zuria, A; Guerra-Balcázar, M; Ledesma-García, J; Arriaga, L G

    2014-08-01

    AuPd/polyaniline was used for the first time, for ethylene glycol (EG) electrooxidation in a novel microfluidic fuel cell (MFC) operated at room temperature. The device exhibits high electrocatalytic performance and stability for the conversion of cheap and fully available EG as fuel. PMID:24923468

  3. Temperature modeling for analysis and design of the sintering furnance in HTR fuel type of ball

    SciTech Connect

    Saragi, Elfrida; Setiadji, Moch

    2013-09-09

    One of the factors that determine the safety of the operation of the sintering furnace fuel HTR ball is the temperature distribution in the ceramic tube furnace. The temperature distribution must be determined at design stage. The tube has a temperature of 1600 °C at one end and about 40 °C at the other end. The outside of the tube was cooled by air through natural convection. The tube is a furnace ceramic tube which its geometry are 0.08, 0.09 and 0.5 m correspondingly for the inner tube diameter, outer tube diameter and tube length. The temperature distribution of the tube is determined by the natural convection coefficient (NCF), which is difficult to be calculated manually. The determination of NCF includes the Grasshoff, Prandtl, and Nusselt numbers which is a function of the temperature difference between the surrounding air with the ceramic tube. If the temperature vary along the tube, the complexity of the calculations increases. Thus the proposed modeling was performed to determine the temperature distribution along the tube and heat transfer coefficient using a self-developed software which permit the design process easier.

  4. Air Ingress Accident in a High Temperature Reactor with Prismatic Fuel

    SciTech Connect

    Haque, H.; Brinkmann, G.

    2006-07-01

    In this paper, the safety behavior of the new generation high temperature reactors (HTRs) with prismatic fuels during air ingress accident conditions has been investigated. These reactors conceived primarily for the production of hydrogen, are characterized by their inherent safety features with respect to passive decay heat removal through conduction, radiation and natural convection. Air ingress is an HTR specific event. The potential threat posed by air ingress lies in the chemical reaction of oxygen with hot graphite at a temperature above 500 deg. C leading to reaction heat and graphite corrosion. A substantial amount of graphite burn-off can take place only if sufficient amount of air enters into the core. In order to better assess the phenomena of air ingress into the reactor, it is postulated that breaks are present above and below the reactor core and that unobstructed ingress of air through them is possible. It is obvious that the air ingress incident has to be preceded by a depressurization accident. For this hypothetical scenario the maximum possible air flow rate through the core resulting solely from the pressure losses in the core is determined as a function of the break cross sections exposed above and below the core. This paper demonstrates the thermal behavior of the ANTARES reactor (operating inlet/outlet temperatures 450/850 deg. C) for various air flow rates with respect to graphite burn-off and maximum temperatures of fuel and bottom reflector region. It indicates the limiting time at which the graphite layer of fuel will be completely burnt-off and the pellets exposed. (authors)

  5. Novel Integration Approach for In situ Monitoring of Temperature in Micro-direct Methanol Fuel Cell

    NASA Astrophysics Data System (ADS)

    Lee, Chi-Yuan; Huang, Ren-De; Chuang, Chih-Wei

    2007-10-01

    In this work, a porous silicon layer is fabricated as the gas diffusion layer (GDL) of a micro-direct methanol fuel cell (μDMFC) using micro-electro-mechanical-systems (MEMS) technology. Platinum is deposited on surface of the porous silicon layer to improve the electrical conductivity of the μDMFC. Physical vapor deposition (PVD) was utilized to deposit Pt metal and wet etching was adopted to form the conductive layer and micro-thermal sensors. The Pt acted both as a current collector and a micro-thermal sensor. We fabricated a resistance temperature detector (RTD) sensor for integration with the gas diffusion layer on the bipolar plate to measure the temperature inside the μDMFC. GDLs with pores of various sizes (10, 30, and 50 μm) were considered to test the performance of the μDMFC. A silicon wafer (500 μm) was etched using KOH wet etching to yield fuel channels with a depth of 450 μm and a width of 200 μm. Then, a porous silicon layer was formed by deep reactive ion etching (DRIE) to act as the GDL of the μDMFC. The experimental results obtained at various fuel flow rates, pore sizes and other operating conditions demonstrate that the maximum power density of the μDMFC is 1.784 mW/cm2, which was reached at 203 mV with 50-μm-diameter holes. The microsensor temperature was determined to be in the range from 20 to 46 °C and the resistance of the microsensor was in the range from 7.524 to 7.677 kΩ. Experimental results demonstrate that temperature is almost linearly related to resistance and that accuracy and sensitivity are 0.3 °C and 7.82× 10-4/°C, respectively.

  6. Development of new proton conducting chalcogenide based materials for use in intermediate temperature fuel cells

    NASA Astrophysics Data System (ADS)

    Martindale, Chad Andrew

    As the world endures higher oil and gas prices, more people in the scientific and industrial communities have turned to fuel cells as a possible alternative. The intermediate temperature fuel cell operating between 100°C and 400°C offers the ability to lower costs through higher efficiencies, cheaper catalysts, and reduced need for expensive scrubbing equipment to remove CO and S impurities. However, there are currently very few known solid-state proton conductors with high conductivities over this temperature range. This work covers the development of two new groups of chalcogenide materials sought to have high proton conductivity over the intermediate temperature range. Anhydrous protonated thioborates based on meta-thioboric acid (HBS 2)3 was the first group of materials explored. Various materials were added to increase the glass forming ability (GeS2, B 2S3) and conductivity (SnI2, GeI2, GeI4). The systems were studied using IR, Raman, NMR, and impedance spectroscopy. A 47% GeI2, + HBS2 sample achieved the highest conductivity of ˜10-6 (O CM)-1. The second group of materials was created from the reaction of an alkali metal hydrosulfide (MSH) and metal oxide powder (GeO2, SiO 2, TiO2) in deionized water. The reaction produced a hydrated amorphous material of the general formula MxRSx(OH) 4-x·yH2O. These materials were found to have a conductivity of 10-3 to 10-2 (O cm)-1 over a 100 to 270°C temperature range. The conducting species, mechanism, reaction, and thermal stability were studied by SEM, 1H and 133Cs NMR, and deuterium exchange. The alkali thio-metallates are promising candidates for use in intermediate fuel cells due to their high conductivity and good thermal stability.

  7. Temperature distribution on anodic surface of membrane electrode assembly in proton exchange membrane fuel cell with interdigitated flow bed

    NASA Astrophysics Data System (ADS)

    Guo, Hang; Wang, Mao Hai; Liu, Jia Xing; Nie, Zhi Hua; Ye, Fang; Ma, Chong Fang

    2015-01-01

    Temperature distribution on the surface of a membrane electrode assembly (MEA) significantly influences the performance, lifetime, and reliability of proton exchange membrane fuel cells (PEMFCs). Entire temperature fields on the surface of an MEA anode side under an interdigitated flow field are experimentally measured at non-humidification conditions with a self-designed PEMFC and infrared imaging technology. The highest temperature on the surface of the MEA anode side appears in the bottom bordered two side channels, and the lowest temperature exists in the area closed to the inlet of the middle channel. The hot region on the surface of the MEA anode side is easy to locate in the infrared temperature image. The reason for the temperature distribution under the interdigitated flow field is analyzed. The temperature of the MEA, the non-uniformity of temperature distribution on the surface of the MEA anode side, and the fuel cell temperature increase with the loaded current density.

  8. Spontaneous ignition temperature limits of jet A fuel in research-combustor segment

    NASA Technical Reports Server (NTRS)

    Ingebo, R. D.

    1974-01-01

    The effects of inlet-air pressure and reference velocity on the spontaneous-ignition temperature limits of Jet A fuel were determined in a combustor segment with a primary-zone length of 0.076 m (3 in.). At a constant reference velocity of 21.4 m/sec (170 ft/sec), increasing the inlet-air pressure from 21 to 207 N/sq cm decreased the spontaneous-ignition temperature limit from approximately 700 to 555 K. At a constant inlet-air pressure of 41 N/sq cm, increasing the reference velocity from 12.2 to 30.5 m/sec increased the spontaneous-ignition temperature limit from approximately 575 to 800 K. Results are compared with other data in the literature.

  9. Chemical stability of glass seal interfaces in intermediate temperature solid oxide fuel cells

    NASA Astrophysics Data System (ADS)

    Yang, Zhenguo; Xia, Guanguang; Meinhardt, Kerry D.; Weil, K. Scott; Stevenson, Jeff W.

    2004-06-01

    In intermediate temperature planar solid oxide fuel cell (SOFC) stacks, the interconnect, which is typically made from cost-effective, oxidation-resistant, high-temperature alloys, is typically sealed to the ceramic positive electrode-electrolyte-negative electrode (PEN) by a sealing glass. To maintain the structural stability and minimize the degradation of stack performance, the sealing glass has to be chemically compatible with the PEN and alloy interconnects. In the present study, the chemical compatibility of a barium-calcium-aluminosilicate (BCAS) based glass-ceramic (specifically developed as a sealant in SOFC stacks) with a number of selected oxidation resistant high temperature alloys (and the yttria-stabilized zirconia electrolyte) was evaluated. This paper reports the results of that study, with a particular focus on Crofer22 APU, a new ferritic stainless steel that was developed specifically for SOFC interconnect applications.

  10. Lowering the platinum loading of high temperature polymer electrolyte membrane fuel cells with acid doped polybenzimidazole membranes

    NASA Astrophysics Data System (ADS)

    Martin, S.; Li, Q.; Jensen, J. O.

    2015-10-01

    Membrane electrode assemblies (MEAs) with ultra-low Pt loading electrodes were prepared for high temperature polymer electrolyte membrane fuel cells (HT-PEMFCs) based on acid doped polybenzimidazole. With no electrode binders or ionomers, the triple phase boundary of the catalyst layer was established by the acid transfer from the acid doped membrane to the electrodes and can therefore be tailored by using catalysts with varied Pt to C ratios. With a loading of ca. 0.1 mgPtcm-2 on each electrode the best performance was obtained with electrodes prepared from 10 wt.% Pt/C due to the improved Pt dispersion, extended triple phase boundary upon the acid transfer and the alleviated acid flooding of the catalytic layer. The MEA delivered a peak power density of 482 mW cm-2 for H2/O2 and 321 mW cm-2 for H2/air, corresponding to an overall Pt utilization of 2.5 and 1.7 kW gPt-1, respectively. The durability test revealed no net voltage decay during more than 1700 h of uninterrupted operation at 200 mA cm-2 and 160 °C.

  11. Investigating Methods of Heat Recovery from Low-Temperature PEM Fuel Cells in CHP Applications

    SciTech Connect

    Jalalzadeh-Azar, A. A.

    2004-01-01

    Heat recovery from low-temperature proton exchange membrane (PEM) fuel cells poses a number of challenges. In response to these challenges, thermodynamic assessments of proposed heat recovery methods are studied in the context of combined heat and power (CHP) for building applications. Preheating combustion air in conjunction with desiccant dehumidification and absorption cooling technologies is one of the two strategies examined in this study. The other approach integrates the PEM fuel cell with a water-loop heat pump (WLHP) for direct heat recovery. As the primary objective, energy-saving potentials of the adopted heat recovery strategies are estimated with respect to various benchmarks. The quantified energy-saving potentials are translated into effective CHP performance indices and compared with those typically specified by the manufacturers for service hot water applications. The need for developing CHP performance protocols is also discussed in light of the proposed energy recovery techniques - thereby, accomplishing the secondary objective.

  12. Accelerator-Based Irradiation Creep of Pyrolytic Carbon Used in TRISO Fuel Particles for the (VHTR) Very Hight Temperature Reactors

    SciTech Connect

    Lumin Wang; Gary Was

    2010-07-30

    Pyrolytic carbon (PyC) is one of the important structural materials in the TRISO fuel particles which will be used in the next generation of gas-cooled very-high-temperature reactors (VHTR). When the TRISO particles are under irradiation at high temperatures, creep of the PyC layers may cause radial cracking leading to catastrophic particle failure. Therefore, a fundamental understanding of the creep behavior of PyC during irradiation is required to predict the overall fuel performance.

  13. Models for the Configuration and Integrity of Partially Oxidized Fuel Rod Cladding at High Temperatures

    SciTech Connect

    Siefken, L.J.

    1999-01-01

    Models were designed to resolve deficiencies in the SCDAP/RELAP5/MOD3.2 calculations of the configuration and integrity of hot, partially oxidized cladding. These models are expected to improve the calculations of several important aspects of fuel rod behavior. First, an improved mapping was established from a compilation of PIE results from severe fuel damage tests of the configuration of melted metallic cladding that is retained by an oxide layer. The improved mapping accounts for the relocation of melted cladding in the circumferential direction. Then, rules based on PIE results were established for calculating the effect of cladding that has relocated from above on the oxidation and integrity of the lower intact cladding upon which it solidifies. Next, three different methods were identified for calculating the extent of dissolution of the oxidic part of the cladding due to its contact with the metallic part. The extent of dissolution effects the stress and thus the integrity of the oxidic part of the cladding. Then, an empirical equation was presented for calculating the stress in the oxidic part of the cladding and evaluating its integrity based on this calculated stress. This empirical equation replaces the current criterion for loss of integrity which is based on temperature and extent of oxidation. Finally, a new rule based on theoretical and experimental results was established for identifying the regions of a fuel rod with oxidation of both the inside and outside surfaces of the cladding. The implementation of these models is expected to eliminate the tendency of the SCDAP/RELAP5 code to overpredict the extent of oxidation of the upper part of fuel rods and to underpredict the extent of oxidation of the lower part of fuel rods and the part with a high concentration of relocated material. This report is a revision and reissue of the report entitled, Improvements in Modeling of Cladding Oxidation and Meltdown.

  14. Binderless electrodes for high-temperature polymer electrolyte membrane fuel cells

    NASA Astrophysics Data System (ADS)

    Martin, S.; Li, Q.; Steenberg, T.; Jensen, J. O.

    2014-12-01

    A new electrode concept was proved with no polymeric binder in the catalyst layer for acid-doped polybenzimidazole (PBI) membrane fuel cells. It shows that a stable interface between the membrane and the catalyst layer can be retained when a proton conducting acid phase is established. The absence of the polymer in the catalytic layer turned out to be beneficial for the PBI cell performance particularly under high load operation. The influence on performance of the Pt loading of the cathode was studied in a range from 0.11 to 2.04 mgPt cm-2 showing saturation of the maximum performance for Pt loadings higher than 0.5 mgPt cm-2. For fuel cell operation on H2 and air supplied under ambient pressure, a peak power density as high as 471 mW cm-2 was measured. The tolerance to carbon monoxide (CO) was also studied with Pt loadings of the anode ranging from 0.24 to 1.82 mgPt cm-2. Lifetime test for a MEA loaded with 0.96 mgPt cm-2 on both electrodes revealed no voltage decay during 900 h of uninterrupted operation at 200 mA cm-2 and 160 °C.

  15. Improving the Sensitivity, Resolution, and Peak Capacity of Gradient Elution in Capillary Liquid Chromatography with Large-Volume Injections by Using Temperature-Assisted On-Column Solute Focusing.

    PubMed

    Wilson, Rachael E; Groskreutz, Stephen R; Weber, Stephen G

    2016-05-17

    Capillary HPLC (cLC) with gradient elution is the separation method of choice for the fields of proteomics and metabolomics. This is due to the complementary nature of cLC flow rates and electrospray or nanospray ionization mass spectrometry (ESI-MS). The small column diameters result in good mass sensitivity. Good concentration sensitivity is also possible by injection of relatively large volumes of solution and relying on solvent-based solute focusing. However, if the injection volume is too large or solutes are poorly retained during injection, volume overload occurs which leads to altered peak shapes, decreased sensitivity, and lower peak capacity. Solutes that elute early even with the use of a solvent gradient are especially vulnerable to this problem. In this paper, we describe a simple, automated instrumental method, temperature-assisted on-column solute focusing (TASF), that is capable of focusing large volume injections of small molecules and peptides under gradient conditions. By injecting a large sample volume while cooling a short segment of the column inlet at subambient temperatures, solutes are concentrated into narrow bands at the head of the column. Rapidly raising the temperature of this segment of the column leads to separations with less peak broadening in comparison to solvent focusing alone. For large volume injections of both mixtures of small molecules and a bovine serum albumin tryptic digest, TASF improved the peak shape and resolution in chromatograms. TASF showed the most dramatic improvements with shallow gradients, which is particularly useful for biological applications. Results demonstrate the ability of TASF with gradient elution to improve the sensitivity, resolution, and peak capacity of volume overloaded samples beyond gradient compression alone. Additionally, we have developed and validated a double extrapolation method for predicting retention factors at extremes of temperature and mobile phase composition. Using this method

  16. Development of Anodic Flux and Temperature Controlling System for Micro Direct Methanol Fuel Cell

    NASA Astrophysics Data System (ADS)

    Li, M. M.; Liu, C.; Liang, J. S.; Wu, C. B.; Xu, Z.

    2006-10-01

    Micro Direct Methanol Fuel Cell (μDMFC) is a kind of newly developed power sources, which effective apparatus for its performance evaluation is still in urgent need at present. In this study, a testing system was established for the purpose of testing the continuous working performance such as micro flux and temperature of μDMFC. In view of the temperature controlling for micro-flux liquid fuel, a heating block with labyrinth-like single pass channel inside for heating up the methanol solution was fabricated. A semiconductorrefrigerating chip was utilized to heat and cool the liquid flow during testing procedures. On the other hand, the two channels of a high accuracy double-channel syringe pump that can suck and pump in turn so as to transport methanol solution continuously was adopted. Based on the requirements of wide-ranged temperature and micro flux controlling, the solenoid valves and the correlative component were used. A hydraulic circuit, which can circulate the fed methanol cold to hot in turn, has also been constructed to test the fatigue life of the μDMFC. The automatic control was actualized by software module written with Visual C++. Experimental results show that the system is perfect in stability and it may provide an important and advanced evaluation apparatus to satisfy the needs for real time performance testing of μDMFC.

  17. Dependence of high-temperature PEM fuel cell performance on Nafion ® content

    NASA Astrophysics Data System (ADS)

    Song, Ying; Xu, Hui; Wei, Yu; Kunz, H. Russell; Bonville, Leonard J.; Fenton, James M.

    Operating a proton exchange membrane (PEM) fuel cell at elevated temperatures (above 100 °C) has significant advantages, such as reduced CO poisoning, increased reaction rates, faster heat rejection, easier and more efficient water management and more useful waste heat. Catalyst materials and membrane electrode assembly (MEA) structure must be considered to improve PEM fuel cell performance. As one of the most important electrode design parameters, Nafion ® content was optimized in the high-temperature electrodes in order to achieve high performance. The effect of Nafion ® content on the electrode performance in H 2/air or H 2/O 2 operation was studied under three different operation conditions (cell temperature (°C)/anode (%RH)/cathode (%RH)): 80/100/75, 100/70/70 and 120/35/35, all at atmospheric pressure. Different Nafion ® contents in the cathode catalyst layers, 15-40 wt%, were evaluated. For electrodes with 0.5 mg cm -2 Pt loading, cell voltages of 0.70, 0.68 and 0.60 V at a current density of 400 mA cm -2 were obtained at 35 wt% Nafion ® ionomer loading, when the cells were operated at the three test conditions, respectively. Cyclic voltammetry was conducted to evaluate the electrochemical surface area. The experimental polarization curves were analyzed by Tafel slope, catalyst activity and diffusion capability to determine the influence of the Nafion ® loading, mainly associated with the cathode.

  18. Comparative studies of peak intensities and chromatographic separation of proteolytic digests, PTMs, and intact proteins obtained by nanoLC-ESI MS analysis at room and elevated temperatures.

    PubMed

    Moskovets, Eugene V; Ivanov, Alexander R

    2016-06-01

    This work demonstrates that the chromatographic separation performed at highly stabilized elevated temperature results in significant improvements in sensitivity, quantitative accuracy, chromatographic resolution, and run-to-run reproducibility of nanoLC-MS analysis of complex peptides mixtures. A newly developed platform was shown to provide conditions for accurate temperature stabilization and temperature homogeneity when performing nanoLC-ESI MS analysis. We quantitatively assessed and compared the recovery of peptides and small proteins from nanoLC columns at room and elevated temperatures. We found that analyses performed at highly stabilized elevated temperatures led to improved detection sensitivity, reproducibility, and chromatographic resolution in reversed-phase LC separation of unmodified peptides (both hydrophilic and hydrophobic), post-translationally modified peptides (O-phosphorylated), and small intact proteins. The analytical benefits of elevated temperatures for qualitative and quantitative proteomic LC-MS profiling were demonstrated using mixtures of synthetic peptides, tryptic digests of mixtures of model proteins, and digested total lysates of isolated rat kidney mitochondria. The effect of elevated temperature on the ion suppression was also demonstrated. Graphical Abstract A fragment of overlaid LC retention time-m/z planar views demonstrates the improved separation performance in the analysis of a complex peptide mixture at elevated temperature. Retention time-m/z 2D peptide features detected at 60 °C (magenta) were matched and aligned with features detected at room temperature (green). PMID:26898204

  19. Pebble Fuel Handling and Reactivity Control for Salt-Cooled High Temperature Reactors

    SciTech Connect

    Peterson, Per; Greenspan, Ehud

    2015-02-09

    This report documents the work completed on the X-PREX facility under NEUP Project 11- 3172. This project seeks to demonstrate the viability of pebble fuel handling and reactivity control for fluoride salt-cooled high-temperature reactors (FHRs). The research results also improve the understanding of pebble motion in helium-cooled reactors, as well as the general, fundamental understanding of low-velocity granular flows. Successful use of pebble fuels in with salt coolants would bring major benefits for high-temperature reactor technology. Pebble fuels enable on-line refueling and operation with low excess reactivity, and thus simpler reactivity control and improved fuel utilization. If fixed fuel designs are used, the power density of salt- cooled reactors is limited to 10 MW/m3 to obtain adequate duration between refueling, but pebble fuels allow power densities in the range of 20 to 30 MW/m3. This can be compared to the typical modular helium reactor power density of 5 MW/m3. Pebble fuels also permit radial zoning in annular cores and use of thorium or graphite pebble blankets to reduce neutron fluences to outer radial reflectors and increase total power production. Combined with high power conversion efficiency, compact low-pressure primary and containment systems, and unique safety characteristics including very large thermal margins (>500°C) to fuel damage during transients and accidents, salt-cooled pebble fuel cores offer the potential to meet the major goals of the Advanced Reactor Concepts Development program to provide electricity at lower cost than light water reactors with improved safety and system performance.This report presents the facility description, experimental results, and supporting simulation methods of the new X-Ray Pebble Recirculation Experiment (X-PREX), which is now operational and being used to collect data on the behavior of slow dense granular flows relevant to pebble bed reactor core designs. The X

  20. Deep Burn: Development of Transuranic Fuel for High-Temperature Helium-Cooled Reactors- Monthly Highlights September 2010

    SciTech Connect

    Snead, Lance Lewis; Besmann, Theodore M; Collins, Emory D; Bell, Gary L

    2010-10-01

    The DB Program monthly highlights report for August 2010, ORNL/TM-2010/184, was distributed to program participants by email on September 17. This report discusses: (1) Core and Fuel Analysis - (a) Core Design Optimization in the HTR (high temperature helium-cooled reactor) Prismatic Design (Logos), (b) Core Design Optimization in the HTR Pebble Bed Design (INL), (c) Microfuel analysis for the DB HTR (INL, GA, Logos); (2) Spent Fuel Management - (a) TRISO (tri-structural isotropic) repository behavior (UNLV), (b) Repository performance of TRISO fuel (UCB); (3) Fuel Cycle Integration of the HTR (high temperature helium-cooled reactor) - Synergy with other reactor fuel cycles (GA, Logos); (4) TRU (transuranic elements) HTR Fuel Qualification - (a) Thermochemical Modeling, (b) Actinide and Fission Product Transport, (c) Radiation Damage and Properties; (5) HTR Spent Fuel Recycle - (a) TRU Kernel Development (ORNL), (b) Coating Development (ORNL), (c) Characterization Development and Support, (d) ZrC Properties and Handbook; and (6) HTR Fuel Recycle - (a) Graphite Recycle (ORNL), (b) Aqueous Reprocessing, (c) Pyrochemical Reprocessing METROX (metal recovery from oxide fuel) Process Development (ANL).

  1. Three-Dimensional Measurements of Fuel Distribution in High-Pressure, High- Temperature, Next-Generation Aviation Gas Turbine Combustors

    NASA Technical Reports Server (NTRS)

    Hicks, Yolanda R.; Locke, Randy J.; Anderson, Robert C.; Zaller, Michelle M.

    1998-01-01

    In our world-class, optically accessible combustion facility at the NASA Lewis Research Center, we have developed the unique capability of making three-dimensional fuel distribution measurements of aviation gas turbine fuel injectors at actual operating conditions. These measurements are made in situ at the actual operating temperatures and pressures using the JP-grade fuels of candidate next-generation advanced aircraft engines for the High Speed Research (HSR) and Advanced Subsonics Technology (AST) programs. The inlet temperature and pressure ranges used thus far are 300 to 1100 F and 80 to 250 psia. With these data, we can obtain the injector spray angles, the fuel mass distributions of liquid and vapor, the degree of fuel vaporization, and the degree to which fuel has been consumed. The data have been used to diagnose the performance of injectors designed both in-house and by major U.S. engine manufacturers and to design new fuel injectors with overall engine performance goals of increased efficiency and reduced environmental impact. Mie scattering is used to visualize the liquid fuel, and laser-induced fluorescence is used to visualize both liquid and fuel vapor.

  2. Steady state temperature profiles in two simulated liquid metal reactor fuel assemblies with identical design specifications

    SciTech Connect

    Levin, A.E.; Carbajo, J.J.; Lloyd, D.B.; Montgomery, B.H.; Rose, S.D.; Wantland, J.L.

    1985-01-01

    Temperature data from steady state tests in two parallel, simulated liquid metal reactor fuel assemblies with identical design specifications have been compared to determine the extent to which they agree. In general, good agreement was found in data at low flows and in bundle-center data at higher flows. Discrepancies in the data wre noted near the bundle edges at higher flows. An analysis of bundle thermal boundary conditions showed that the possible eccentric placement of one bundle within the housing could account for these discrepancies.

  3. Regulating the combustion temperature of the fuel in kilns for firing electrical porcelain

    SciTech Connect

    Etingen, L.A.; Koren, M.G.; Tishkevich, L.B.

    1986-11-01

    It can be assumed that the use of ballasted air in burner devices of kilns working with natural gas and equipped with low-pressure burners will give an increase in the consumption and pressure of the ballasted air compared with pure (nonballasted) air; there should be an improvement in the introduction of the fuel, its mixing conditions, and the combustion conditions. The proposed method of regulating the temperature in kilns can be used in other industries with similar heattreatment conditions for the goods.

  4. Performance and durability of PEM fuel cells operated at sub-freezing temperatures

    SciTech Connect

    Mukundan, Rangachary; Davey, John R; Lujan, Roger W; Spendelow, Jacob S

    2008-01-01

    The durability of polymer electrolyte membrane (PEM) fuel cells operated at sub-freezing temperatures has received increasing attention in recent years. The Department of Energy's PEM fuel cell stack technical targets for the year 2010 include unassisted start-up from -40 {sup o}C and startup from -20 {sup o}C ambient in as low as 30 seconds with < 5 MJ energy consumption. Moreover, the sub-freezing operations should not have any impact on acieving other technical targets including 5000 hours durability. The effect of MEA preparation on the performance of single-PEM fuel cells operated at sub-freezing temperatures is presented. The cell performance and durability are dependent on the MEA and are probably influenced by the porosity of the catalyst layers. When a cell is operated isothermally at -10 {sup o}C in constant current mode, the voltage gradually decreases over time and eventually drops to zero. AC impedance analysis indicated that the rate of voltage loss is initially due to an increase in the charge transfer resistance and is gradual. After a period, the rate of decay accelerates rapidly due to mass transport limitations at the catalyst and/or gas diffusion layers. The high frequency resistance also increases over time during the isothermal operation at sub-freezing temperatures and was a function of the initial membrane water content. LANL prepared MEAs showed very little loss in the catalyst surface area with multiple sub-freezing operations, whereas the commercial MEAs exhibited significant loss in cathode surface area with the anode being unaffected. These results indicate that catalyst layer ice formation is influenced strongly by the MEA and is responsible for the long-term degradation of fuel cells operated at sub-freezing temperatures. This ice formation was monitored using neutron radiography and was found to be concentrated near cell edges at the flow field turns. The water distribution also indicated that ice may be forming mainly in the GDLs at

  5. Copper cobalt spinel as a high performance cathode for intermediate temperature solid oxide fuel cells.

    PubMed

    Shao, Lin; Wang, Qi; Fan, Lishuang; Wang, Pengxiang; Zhang, Naiqing; Sun, Kening

    2016-06-30

    CuCo2O4 spinel prepared via an EDTA-citric acid process was studied as a candidate solid oxide fuel cell (SOFC) cathode material at intermediate temperatures (IT). CuCo2O4 cathodes were measured using thermal gravimetric analysis, X-ray diffraction and scanning electron microscopy. AC impedance spectroscopy and DC polarization measurements were used to study the electrode performance. The obtained value of the polarization resistances at 800 °C was 0.12 Ω cm(2) with a maximum power density of 972 mW cm(-2). PMID:27326915

  6. Neutronic assessment of stringer fuel assembly design for liquid-salt-cooledvery high temperature reactor (LS-VHTR).

    SciTech Connect

    Szakaly, F. J.; Kim, T. K.; Taiwo, T. A.

    2006-09-15

    Neutronic studies of 18-pin and 36-pin stringer fuel assemblies have been performed to ascertain that core design requirements for the Liquid-Salt Cooled Very High Temperature Reactor (LS-VHTR) can be met. Parametric studies were performed to determine core characteristics required to achieve a target core cycle length of 18 months and fuel discharge burnup greater than 100 GWd/t under the constraint that the uranium enrichment be less than 20% in order to support non-proliferation goals. The studies were done using the WIMS9 lattice code and the linear reactivity model to estimate the core reactivity balance, fuel composition, and discharge burnup. The results show that the design goals can be met using a 1-batch fuel management scheme, uranium enrichment of 15% and a fuel packing fraction of 30% or greater for the 36-pin stringer fuel assembly design.

  7. Investigation of an Alternative Fuel Form for the Liquid Salt Cooled Very High Temperature Reactor (LS-VHTR)

    SciTech Connect

    Casino, William A. Jr.

    2006-07-01

    Much of the recent studies investigating the use of liquid salts as reactor coolants have utilized a core configuration of graphite prismatic fuel block assemblies with TRISO particles embedded into cylindrical fuel compacts arranged in a triangular pitch lattice. Although many calculations have been performed for this fuel form in gas cooled reactors, it would be instructive to investigate whether an alternative fuel form may yield improved performance for the liquid salt-cooled Very High Temperature Reactor (LS-VHTR). This study investigates how variations in the fuel form will impact the performance of the LS-VHTR during normal and accident conditions and compares the results with a similar analysis that was recently completed for a LS-VHTR core made up of prismatic block fuel. (author)

  8. First elevated-temperature performance testing of coated particle fuel compacts from the AGR-1 irradiation experiment

    SciTech Connect

    Charles A. Baldwin; John D. Hunn; Robert N. Morris; Fred C. Montgomery; Chinthaka M. Silva; Paul A. Demkowicz

    2014-05-01

    In the AGR-1 irradiation experiment, 72 coated-particle fuel compacts were taken to a peak burnup of 19.5% fissions per initial metal atom with no in-pile failures. This paper discusses the first post-irradiation test of these mixed uranium oxide/uranium carbide fuel compacts at elevated temperature to examine the fuel performance under a simulated depressurized conduction cooldown event. A compact was heated for 400 h at 1600 degrees C. Release of 85Kr was monitored throughout the furnace test as an indicator of coating failure, while other fission product releases from the compact were periodically measured by capturing them on exchangeable, water-cooled deposition cups. No coating failure was detected during the furnace test, and this result was verified by subsequent electrolytic deconsolidation and acid leaching of the compact, which showed that all SiC layers were still intact. However, the deposition cups recovered significant quantities of silver, europium, and strontium. Based on comparison of calculated compact inventories at the end of irradiation versus analysis of these fission products released to the deposition cups and furnace internals, the minimum estimated fractional losses from the compact during the furnace test were 1.9 x 10-2 for silver, 1.4 x 10-3 for europium, and 1.1 x 10-5 for strontium. Other post-irradiation examination of AGR-1 compacts indicates that similar fractions of europium and silver may have already been released by the intact coated particles during irradiation, and it is therefore likely that the detected fission products released from the compact in this 1600 degrees C furnace test were from residual fission products in the matrix. Gamma analysis of coated particles deconsolidated from the compact after the heating test revealed that silver content within each particle varied considerably; a result that is probably not related to the furnace test, because it has also been observed in other as-irradiated AGR-1 compacts. X

  9. Low-temperature fuel cells: Outlook for application in energy storage systems and materials for their development

    NASA Astrophysics Data System (ADS)

    Stenina, I. A.; Safronova, E. Yu.; Levchenko, A. V.; Dobrovolsky, Yu. A.; Yaroslavtsev, A. B.

    2016-06-01

    Low-temperature fuel cells (FCs) are perspective alternative energy sources. They cannot, however, be considered as a primary energy source, because no hydrogen in pure form, used in their operation, exists in nature. The development of devices to autonomously supply and store energy can be considered as one of the most promising applications of low-temperature FCs. In the latter case, the primary purpose is to compensate differences in peaks of producing and consuming energy both in the seasons and time of day. The first part of the review describes this problem. The second part involves analyzing nanomaterials used in FCs, so that hybrid membranes, including inorganic nanoparticles, are high priority in this regard. Their incorporation into the pores of the membranes leads to an improvement in transport properties in many cases, including an increase in ionic conductivity and selectivity of transport processes. These properties of the hybrid membranes are discussed by using a model of limited elasticity of walls of the pores. Catalysts, being platinum nano-size particles, play an important role in the FC. To reduce their costs and increase activity, some approaches, implying decrease in particle sizes or using two-component particles, for example, alloys and `core-shell' particles, are used. In the latter case, platinum, localized on the surface, determines activity of the catalyst, whereas the second metal increases surface area and catalyst activity. The main reasons for changes in properties of the materials and effect of the catalyst support on electrochemical processes in FCs are also considered.

  10. A methodology for thermodynamic simulation of high temperature, internal reforming fuel cell systems

    NASA Astrophysics Data System (ADS)

    Matelli, José Alexandre; Bazzo, Edson

    This work presents a methodology for simulation of fuel cells to be used in power production in small on-site power/cogeneration plants that use natural gas as fuel. The methodology contemplates thermodynamics and electrochemical aspects related to molten carbonate and solid oxide fuel cells (MCFC and SOFC, respectively). Internal steam reforming of the natural gas hydrocarbons is considered for hydrogen production. From inputs as cell potential, cell power, number of cell in the stack, ancillary systems power consumption, reformed natural gas composition and hydrogen utilization factor, the simulation gives the natural gas consumption, anode and cathode stream gases temperature and composition, and thermodynamic, electrochemical and practical efficiencies. Both energetic and exergetic methods are considered for performance analysis. The results obtained from natural gas reforming thermodynamics simulation show that the hydrogen production is maximum around 700 °C, for a steam/carbon ratio equal to 3. As shown in the literature, the found results indicate that the SOFC is more efficient than MCFC.

  11. A boron phosphate-phosphoric acid composite membrane for medium temperature proton exchange membrane fuel cells

    NASA Astrophysics Data System (ADS)

    Mamlouk, M.; Scott, K.

    2015-07-01

    A composite membrane based on a non-stoichiometric composition of BPO4 with excess of PO4 (BPOx) was synthesised and characterised for medium temperature fuel cell use (120-180 °C). The electrolyte was characterised by FTIR, SS-NMR, TGA and XRD and showed that the B-O is tetrahedral, in agreement with reports in the literature that boron phosphorus oxide compounds at B:P < 1 are exclusively built of borate and phosphate tetrahedra. Platinum micro electrodes were used to study the electrolyte compatibility and stability towards oxygen reduction at 150 °C and to obtain kinetic and mass transport parameters. The conductivities of the pure BPOx membrane electrolyte and a Polybenzimidazole (PBI)-4BPOx composite membrane were 7.9 × 10-2 S cm-1 and 4.5 × 10-2 S cm-1 respectively at 150 °C, 5%RH. Fuel cell tests showed a significant enhancement in performance of BPOx over that of typical 5.6H3PO4-PBI membrane electrolyte. The enhancement is due to the improved ionic conductivity (3×), a higher exchange current density of the oxygen reduction (30×) and a lower membrane gas permeability (10×). Fuel cell current densities at 0.6 V were 706 and 425 mA cm-2 for BPOx and 5.6H3PO4-PBI, respectively, at 150 °C with O2 (atm).

  12. Peak flow meter (image)

    MedlinePlus

    A peak flow meter is commonly used by a person with asthma to measure the amount of air that can be ... become narrow or blocked due to asthma, peak flow values will drop because the person cannot blow ...

  13. Influence of gadolinium doping on the structure and defects of ceria under fuel cell operating temperature

    SciTech Connect

    Acharya, S. A. Gaikwad, V. M.; Sathe, V.; Kulkarni, S. K.

    2014-03-17

    Correlation between atomic positional shift, oxygen vacancy defects, and oxide ion conductivity in doped ceria system has been established in the gadolinium doped ceria system from X-ray diffraction (XRD) and Raman spectroscopy study at operating temperature (300–600 °C) of Intermediate Temperature Solid Oxide Fuel Cell (IT-SOFC). High temperature XRD data are used to quantify atomic positional shift from mean position with temperature. The Raman spectroscopy study shows additional vibration modes related to ordering of defect spaces (Gd{sub Ce}{sup ′}−V{sub o}{sup ••}){sup *} and (2Gd{sub Ce}{sup ′}−V{sub o}{sup ••}){sup x} generated due to association of oxygen vacancies and reduced cerium or dopant cations site (Gd{sup 3+}), which disappear at 450 °C; indicating oxygen vacancies dissociation from the defect complex. The experimental evidences of cation-anion positional shifting and oxygen vacancies dissociation from defect complex in the IT-SOFC operating temperature are discussed to correlate with activation energy for ionic conductivity.

  14. Tar-free fuel gas production from high temperature pyrolysis of sewage sludge

    SciTech Connect

    Zhang, Leguan; Xiao, Bo; Hu, Zhiquan; Liu, Shiming Cheng, Gong; He, Piwen; Sun, Lei

    2014-01-15

    Highlights: • High temperature pyrolysis of sewage sludge was efficient for producing tar-free fuel gas. • Complete tar removal and volatile matter release were at elevated temperature of 1300 °C. • Sewage sludge was converted to residual solid with high ash content. • 72.60% of energy conversion efficiency for gas production in high temperature pyrolysis. • Investment and costing for tar cleaning were reduced. - Abstract: Pyrolysis of sewage sludge was studied in a free-fall reactor at 1000–1400 °C. The results showed that the volatile matter in the sludge could be completely released to gaseous product at 1300 °C. The high temperature was in favor of H{sub 2} and CO in the produced gas. However, the low heating value (LHV) of the gas decreased from 15.68 MJ/N m{sup 3} to 9.10 MJ/N m{sup 3} with temperature increasing from 1000 °C to 1400 °C. The obtained residual solid was characterized by high ash content. The energy balance indicated that the most heating value in the sludge was in the gaseous product.

  15. Study of the effect of {sup 135}Xe poison on the temperature coefficient of TRIGA fuel

    SciTech Connect

    Iorgulis, Constantin

    1992-07-01

    A study of the influence of {sup 135}Xe on the prompt negative temperature coefficient of the 14-MW Romanian TRIGA reactor has been performed. Because of its large absorption cross section below 0.1 eV, we expected that {sup 135}Xe might make a positive contribution to the temperature coefficient because the higher-energy neutrons are less likely to be absorbed by the Xe. This effect would be largest about 16 hours after reactor shutdown. In order to investigate this phenomenon, we have performed cell and core calculations for various fuel temperatures, burnups, and {sup 135}Xe levels. These calculations indeed show a positive contribution of {sup 135}Xe to the temperature coefficient, especially for high burnups, where little {sup 167}Er remains to absorb the higher-energy neutrons. Work is in progress to evaluate the effect of the smaller negative temperature coefficient on the consequences of reactivity insertion accidents in unfavorable situations of {sup 135}Xe poisoning of the Romanian TRIGA core. (author)

  16. Ice formation in PEM fuel cells operated isothermally at sub-freezing temperatures

    SciTech Connect

    Mukundan, Rangachary; Luhan, Roger W; Davey, John R; Spendelow, Jacob S; Borup, Rodney L; Hussey, Daniel S; Jacobson, David L; Arif, Muhammad

    2009-01-01

    The effect of MEA and GDL structure and composition on the performance of single-PEM fuel cells operated isothermally at subfreezing temperatures is presented. The cell performance and durability are not only dependent on the MEA/GDL materials used but also on their interfaces. When a cell is operated isothermally at sub-freezing temperatures in constant current mode, the water formation due to the current density initially hydrates the membrane/ionomer and then forms ice in the catalyst layer/GDL. An increase in high frequency resistance was also observed in certain MEAs where there is a possibility of ice formation between the catalyst layer and GDL leading to a loss in contact area. The total water/ice holding capacity for any MEA was lower at lower temperatures and higher current densities. The durability of MEAs subjected to multiple isothermal starts was better for LANL prepared MEAs as compared to commercial MEAs, and cloth GDLs when compared to paper GDLs. The ice formation was monitored using high-resolution neutron radiography and was found to be concentrated near the cathode catalyst layer. However, there was significant ice formation in the GDLs especially at the higher temperature ({approx} -10 C) and lower current density (0.02 A/cm{sup 2}) operations. These results are consistent with the longer-term durability observations that show more severe degradation at the lower temperatures.

  17. CARS temperature measurements in the fuel preburner of the Space Shuttle main engine: A feasibility study

    NASA Technical Reports Server (NTRS)

    Beiting, E. J.; Luthe, J. C.

    1983-01-01

    This report discusses the feasibility of making temperature profile measurements in the fuel preburner of the main engine of the space shuttle (SSME) using coherent anti-Stokes Raman spectroscopy (CARS). The principal thrust of the work is to identify problems associated with making CARS measurements in high temperature gas phase hydrogen at very high pressures (approx 400 atmospheres). To this end a theoretical study was made of the characteristics of the CAR spectra of H2 as a function of temperature and pressure and the accuracy with which temperatures can be extracted from this spectra. In addition the experimental problems associated with carrying out these measurements on a SSME at NSTL were identified. A conceptual design of a CARS system suitable for this work is included. Many of the results of the calculations made in this report are plotted as a function of temperature. In the course of presenting these results, it was necessary to decide whether the number of density or the pressure should be treated as a fixed parameter.

  18. [Effect of temperature on performance of microbial fuel cell using beer wastewater].

    PubMed

    Wang, Xin; Feng, Yu-Jie; Qu, You-Peng; Li, Dong-Mei; Li, He; Ren, Nan-Qi

    2008-11-01

    The effects of temperature on performance and biological community structure were investigated in air-cathode microbial fuel cells (MFCs) using beer wastewater amended with 50 mmol/L phosphate buffer solution (PBS). The maximum power density decreased from 483 mW/m2 to 435 mW/m2 when the temperature varied from 30 degrees C to 20 degrees C, meanwhile just a little decreasing on coulombic efficiency and the COD removal rate were observed. Decreasing of temperature resulted in effects both on cathode potential and anode potential, but cathode potential behaved much more sensitive to temperature. The half-saturation constants (Ks) obtained from the fit of Monod-type equation were 228 mg/L (30 degrees C) and 293 mg/L (20 degrees C) respectively. Denaturing gradient gel electrophoresis (DGGE) analysis indicated that operating temperature not only affected the predominant population of the anodic bacterial community, but also had a great impact on the diversity of the cathodic microbial population. PMID:19186815

  19. Proton conducting, composite sulfonated polymer membrane for medium temperature and low relative humidity fuel cells

    NASA Astrophysics Data System (ADS)

    Shin, Dong Won; Kang, Na Rae; Lee, Kang Hyuck; Cho, Doo Hee; Kim, Ji Hoon; Lee, Won Hyo; Lee, Young Moo

    2014-09-01

    Inorganic-organic composite membranes are fabricated using zirconium acetylacetonate nanoparticles and biphenol-based sulfonated poly(arylene ether sulfone) as an inorganic, proton conducting nanomaterial and a polymer matrix, respectively. An amphiphilic surfactant (Pluronic®) induces distribution of the inorganic nanoparticles over the entire polymer membrane. The composite membranes are thermally stable up to 200 °C. Zirconium acetylacetonate improves inter-chain interactions and the robustness of polymer membranes resulting in excellent membrane mechanical properties. In addition, composite membranes show outstanding proton conductivity compared to that of the pristine membrane at medium temperatures (80-120 °C) and low relative humidity (<50%) conditions. This improvement is due to the presence of acetylacetonate anions, which bind water molecules and act as an additional proton conducting site and/or medium. Therefore, the composite membranes significantly outperform the pristine membrane in fuel cell performance tests at medium temperatures and low relative humidity.

  20. The use of a very high temperature nuclear reactor in the manufacture of synthetic fuels

    NASA Technical Reports Server (NTRS)

    Farbman, G. H.; Brecher, L. E.

    1976-01-01

    The three parts of a program directed toward creating a cost-effective nuclear hydrogen production system are described. The discussion covers the development of a very high temperature nuclear reactor (VHTR) as a nuclear heat and power source capable of producing the high temperature needed for hydrogen production and other processes; the development of a hydrogen generation process based on water decomposition, which can utilize the outputs of the VHTR and be integrated with many different ultimate hydrogen consuming processes; and the evaluation of the process applications of the nuclear hydrogen systems to assess the merits and potential payoffs. It is shown that the use of VHTR for the manufacture of synthetic fuels appears to have a very high probability of making a positive contribution to meeting the nation's energy needs in the future.

  1. Influence of Temperature on the Corrosion of Uranium Dioxide Nuclear Fuel

    SciTech Connect

    Broczkowski, Michael E.; Noel, Jamie J.; Shoesmith, David W.

    2007-07-01

    The anodic dissolution of UO{sub 2} has been studied at 60 deg. C and the results compared to previous observations at 22 deg. C. The rate of oxidation / dissolution was determined electrochemically at constant potentials in the range -500 mV to 500 mV (vs. SCE). The composition of the electrochemically oxidized surface was determined by X-Ray Photoelectron Spectroscopy (XPS). The onset of oxidation (UO{sub 2} {yields} UO{sub 2+x}) occurred at approximately the same potential (-400 mV) at both temperatures. However, the conversion of U{sub V} to U{sub VI}, and hence to soluble UO{sub 2}{sup 2+}, was accelerated by temperature. This acceleration of dissolution caused the development of acidity at localized sites on the fuel surface at lower (less oxidizing) potentials ({>=} 100 mV) at 60 deg. C than at 22 deg. C ({>=} 350 mV)

  2. Oxidation of Haynes 230 alloy in reduced temperature solid oxide fuel cell environments

    NASA Astrophysics Data System (ADS)

    Jian, Li; Jian, Pu; Jianzhong, Xiao; Xiaoliang, Qian

    Haynes 230 alloy was exposed to reducing and oxidizing environments at 750 °C for 1000 h, simulating the conditions in a reduced temperature solid oxide fuel cell (SOFC). The oxidized specimens were characterized in terms of the oxide morphology, composition and crystal structure. The oxide scale in each environment was identified as Cr 2O 3 with the existence of Cr 2MnO 4. Ni remained metallic in the reducing atmosphere, and NiO was detected in the sample exposed to air. The oxide scale is around 1 μm thick after 1000 h of oxidation in both situations. The area specific resistance (ASR) contributed by the oxide scale is expected less than 0.1 Ω cm 2 after 40,000 h of exposure when a parabolic oxide growth rate is assumed, demonstrating the suitability of the interconnect application of this alloy in the reduced temperature SOFCs.

  3. Metallography and fuel cladding chemical interaction in fast flux test facility irradiated metallic U-10Zr MFF-3 and MFF-5 fuel pins

    NASA Astrophysics Data System (ADS)

    Carmack, W. J.; Chichester, H. M.; Porter, D. L.; Wootan, D. W.

    2016-05-01

    The Mechanistic Fuel Failure (MFF) series of metal fuel irradiations conducted in the Fast Flux Test Facility (FFTF) provides an important comparison between data generated in the Experimental Breeder Reactor (EBR-II) and that expected in a larger-scale fast reactor. The MFF fuel operated with a peak cladding temperature at the top of the fuel column, but developed peak burnup at the centerline of the core. This places the peak fuel temperature midway between the core center and the top of fuel, lower in the fuel column than in EBR-II experiments. Data from the MFF-3 and MFF-5 assemblies are most comparable to the data obtained from the EBR-II X447 experiment. The two X447 pin breaches were strongly influenced by fuel/cladding chemical interaction (FCCI) at the top of the fuel column. Post irradiation examination data from MFF-3 and MFF-5 are presented and compared to historical EBR-II data.

  4. Anisotropic Azimuthal Power and Temperature distribution on FuelRod. Impact on Hydride Distribution

    SciTech Connect

    Motta, Arthur; Ivanov, Kostadin; Arramova, Maria; Hales, Jason

    2015-04-29

    The degradation of the zirconium cladding may limit nuclear fuel performance. In the high temperature environment of a reactor, the zirconium in the cladding corrodes, releasing hydrogen in the process. Some of this hydrogen is absorbed by the cladding in a highly inhomogeneous manner. The distribution of the absorbed hydrogen is extremely sensitive to temperature and stress concentration gradients. The absorbed hydrogen tends to concentrate near lower temperatures. This hydrogen absorption and hydride formation can cause cladding failure. This project set out to improve the hydrogen distribution prediction capabilities of the BISON fuel performance code. The project was split into two primary sections, first was the use of a high fidelity multi-physics coupling to accurately predict temperature gradients as a function of r, θ , and z, and the second was to use experimental data to create an analytical hydrogen precipitation model. The Penn State version of thermal hydraulics code COBRA-TF (CTF) was successfully coupled to the DeCART neutronics code. This coupled system was verified by testing and validated by comparison to FRAPCON data. The hydrogen diffusion and precipitation experiments successfully calculated the heat of transport and precipitation rate constant values to be used within the hydrogen model in BISON. These values can only be determined experimentally. These values were successfully implemented in precipitation, diffusion and dissolution kernels that were implemented in the BISON code. The coupled output was fed into BISON models and the hydrogen and hydride distributions behaved as expected. Simulations were conducted in the radial, axial and azimuthal directions to showcase the full capabilities of the hydrogen model.

  5. Numerical simulation of proton exchange membrane fuel cells at high operating temperature

    NASA Astrophysics Data System (ADS)

    Peng, Jie; Lee, Seung Jae

    A three-dimensional, single-phase, non-isothermal numerical model for proton exchange membrane (PEM) fuel cell at high operating temperature (T ≥ 393 K) was developed and implemented into a computational fluid dynamic (CFD) code. The model accounts for convective and diffusive transport and allows predicting the concentration of species. The heat generated from electrochemical reactions, entropic heat and ohmic heat arising from the electrolyte ionic resistance were considered. The heat transport model was coupled with the electrochemical and mass transport models. The product water was assumed to be vaporous and treated as ideal gas. Water transportation across the membrane was ignored because of its low water electro-osmosis drag force in the polymer polybenzimidazole (PBI) membrane. The results show that the thermal effects strongly affect the fuel cell performance. The current density increases with the increasing of operating temperature. In addition, numerical prediction reveals that the width and distribution of gas channel and current collector land area are key optimization parameters for the cell performance improvement.

  6. Accurate High-Temperature Reaction Networks for Alternative Fuels: Butanol Isomers

    SciTech Connect

    Van Geem, K. M.; Pyl, S. P.; Marin, G. B.; Harper, M. R.; Green, W. H.

    2010-11-03

    Oxygenated hydrocarbons, particularly alcohol compounds, are being studied extensively as alternatives and additives to conventional fuels due to their propensity of decreasing soot formation and improving the octane number of gasoline. However, oxygenated fuels also increase the production of toxic byproducts, such as formaldehyde. To gain a better understanding of the oxygenated functional group’s influence on combustion properties—e.g., ignition delay at temperatures above the negative temperature coefficient regime, and the rate of benzene production, which is the common precursor to soot formation—a detailed pressure-dependent reaction network for n-butanol, sec-butanol, and tert-butanol consisting of 281 species and 3608 reactions is presented. The reaction network is validated against shock tube ignition delays and doped methane flame concentration profiles reported previously in the literature, in addition to newly acquired pyrolysis data. Good agreement between simulated and experimental data is achieved in all cases. Flux and sensitivity analyses for each set of experiments have been performed, and high-pressure-limit reaction rate coefficients for important pathways, e.g., the dehydration reactions of the butanol isomers, have been computed using statistical mechanics and quantum chemistry. The different alcohol decomposition pathways, i.e., the pathways from primary, secondary, and tertiary alcohols, are discussed. Furthermore, comparisons between ethanol and n-butanol, two primary alcohols, are presented, as they relate to ignition delay.

  7. Development of high temperature air combustion technology in pulverized fossil fuel fired boilers

    SciTech Connect

    Hai Zhang; Guangxi Yue; Junfu Lu; Zhen Jia; Jiangxiong Mao; Toshiro Fujimori; Toshiyuki Suko; Takashi Kiga

    2007-07-01

    High temperature air combustion (HTAC) is a promising technology for energy saving, flame stability enhancement and NOx emission reduction. In a conventional HTAC system, the combustion air is highly preheated by using the recuperative or regenerative heat exchangers. However, such a preheating process is difficult to implement for pulverized fossil fuel fired boilers. In this paper, an alternative approach is proposed. In the proposed HTAC system, a special burner, named PRP burner is introduced to fulfill the preheating process. The PRP burner has a preheating chamber with one end connected with the primary air and the other end opened to the furnace. Inside the chamber, gas recirculation is effectively established such that hot flue gases in the furnace can be introduced. Combustible mixture instead of combustion air is highly preheated by the PRP burner. A series of experiments have been conducted in an industrial scale test facility, burning low volatile petroleum coke and an anthracite coal. Stable combustion was established for burning pure petroleum coke and anthracite coal, respectively. Inside the preheating chamber, the combustible mixture was rapidly heated up to a high temperature level close to that of the hot secondary air used in the conventional HTAC system. The rapid heating of the combustible mixture in the chamber facilitates pyrolysis, volatile matter release processes for the fuel particles, suppressing ignition delay and enhancing combustion stability. Moreover, compared with the results measured in the same facility but with a conventional low NOx burner, NOx concentration at the furnace exit was at the same level when petroleum coke was burnt and 50% less when anthracite was burnt. Practicability of the HTAC technology using the proposed approach was confirmed for efficiently and cleanly burning fossil fuels. 16 refs., 10 figs., 1 tab.

  8. LWR fuel assembly designs for the transmutation of LWR Spent Fuel TRU with FCM and UO{sub 2}-ThO{sub 2} Fuels

    SciTech Connect

    Bae, G.; Hong, S. G.

    2013-07-01

    In this paper, transmutation of transuranic (TRU) nuclides from LWR spent fuels is studied by using LWR fuel assemblies which consist of UO{sub 2}-ThO{sub 2} fuel pins and FCM (Fully Ceramic Microencapsulated) fuel pins. TRU from LWR spent fuel is loaded in the kernels of the TRISO particle fuels of FCM fuel pins. In the FCM fuel pins, the TRISO particle fuels are distributed in SiC matrix having high thermal conductivity. The loading patterns of fuel pins and the fuel compositions are searched to have high transmutation rate and feasible neutronic parameters including pin power peaking, temperature reactivity coefficients, and cycle length. All studies are done only in fuel assembly calculation level. The results show that our fuel assembly designs have good transmutation performances without multi-recycling and without degradation of the safety-related neutronic parameters. (authors)

  9. Low-temperature Ignition-delay Characteristics of Several Rocket Fuels with Mixed Acid in Modified Open-cup-type Apparatus

    NASA Technical Reports Server (NTRS)

    Miller, Riley O

    1950-01-01

    Summaries of low-temperature self-ignition data of various rocket fuels with mixed acid (nitric plus sulfuric) are presented. Several fuels are shown to have shorter ignition-delay intervals and less variation in delay intervals at moderate and sub-zero temperatures than crude N-ethylaniline (monoethylaniline),a rocket fuel in current use.

  10. Improvement in high temperature proton exchange membrane fuel cells cathode performance with ammonium carbonate

    NASA Astrophysics Data System (ADS)

    Song, Ying; Wei, Yu; Xu, Hui; Williams, Minkmas; Liu, Yuxiu; Bonville, Leonard J.; Russell Kunz, H.; Fenton, James M.

    Proton exchange membrane (PEM) fuel cells with optimized cathode structures can provide high performance at higher temperature (120 °C). A "pore-forming" material, ammonium carbonate, applied in the unsupported Pt cathode catalyst layer of a high temperature membrane electrode assembly enhanced the catalyst activity and minimized the mass-transport limitations. The ammonium carbonate amount and Nafion ® loading in the cathode were optimized for performance at two conditions: 80 °C cell temperature with 100% anode/75% cathode R.H. and 120 °C cell temperature with 35% anode/35% cathode R.H., both under ambient pressure. A cell with 20 wt.% ammonium carbonate and 20 wt.% Nafion ® operating at 80 °C and 120 °C presented the maximum cell performance. Hydrogen/air cell voltages at a current density of 400 mA cm -2 using the Ionomem/UConn membrane as the electrolyte with a cathode platinum loading of 0.5 mg cm -2 were 0.70 V and 0.57 V at the two conditions, respectively. This was a 19% cell voltage increase over a cathode without the "pore-forming" ammonium carbonate at the 120 °C operating condition.

  11. First high temperature safety tests of AGR-1 TRISO fuel with the Fuel Accident Condition Simulator (FACS) furnace

    SciTech Connect

    Demkowicz, Paul A.; Reber, Edward L.; Scates, Dawn M.; Scott, Les; Collin, Blaise P.

    2015-09-01

    Three TRISO fuel compacts from the AGR-1 irradiation experiment were subjected to safety tests at 1600 and 1800 °C for approximately 300 h to evaluate the fission product retention characteristics. Silver behavior was dominated by rapid release of an appreciable fraction of the compact inventory (3–34%) at the beginning of the tests, believed to be from inventory residing in the compact matrix and outer pyrocarbon (OPyC) prior to the safety test. Measurable release of silver from intact particles appears to become apparent only after ~60 h at 1800 °C. The release rate for europium and strontium was nearly constant for 300 h at 1600 °C (reaching maximum values of approximately 2×10⁻³ and 8×10⁻⁴ respectively), and at this temperature the release may be mostly limited to inventory in the compact matrix and OPyC prior to the safety test. The release rate for both elements increased after approximately 120 h at 1800 °C, possibly indicating additional measurable release through the intact particle coatings. Cesium fractional release from particles with intact coatings was <10⁻⁶ after 300 h at 1600 °C or 100 h at 1800 °C, but release from the rare particles that experienced SiC failure during the test could be significant. However, Kr release was still very low for 300 h 1600 °C (<2 × 10⁻⁶). At 1800 °C, krypton release increased noticeably after SiC failure, reflecting transport through the intact outer pyrocarbon layer. Nonetheless, the krypton and cesium release fractions remained less than approximately 10⁻³ after 277 h at 1800 °C.

  12. First high temperature safety tests of AGR-1 TRISO fuel with the Fuel Accident Condition Simulator (FACS) furnace

    NASA Astrophysics Data System (ADS)

    Demkowicz, Paul A.; Reber, Edward L.; Scates, Dawn M.; Scott, Les; Collin, Blaise P.

    2015-09-01

    Three TRISO fuel compacts from the AGR-1 irradiation experiment were subjected to safety tests at 1600 and 1800 °C for approximately 300 h to evaluate the fission product retention characteristics. Silver behavior was dominated by rapid release of an appreciable fraction of the compact inventory (3-34%) at the beginning of the tests, believed to be from inventory residing in the compact matrix and outer pyrocarbon (OPyC) prior to the safety test. Measurable release of silver from intact particles appears to become apparent only after ∼60 h at 1800 °C. The release rate for europium and strontium was nearly constant for 300 h at 1600 °C (reaching maximum values of approximately 2 × 10-3 and 8 × 10-4 respectively), and at this temperature the release may be mostly limited to inventory in the compact matrix and OPyC prior to the safety test. The release rate for both elements increased after approximately 120 h at 1800 °C, possibly indicating additional measurable release through the intact particle coatings. Cesium fractional release from particles with intact coatings was <10-6 after 300 h at 1600 °C or 100 h at 1800 °C, but release from the rare particles that experienced SiC failure during the test could be significant. However, Kr release was still very low for 300 h 1600 °C (<2 × 10-6). At 1800 °C, krypton release increased noticeably after SiC failure, reflecting transport through the intact outer pyrocarbon layer. Nonetheless, the krypton and cesium release fractions remained less than approximately 10-3 after 277 h at 1800 °C.

  13. Low Temperature Constrained Sintering of Cerium Gadolinium OxideFilms for Solid Oxide Fuel Cell Applications

    SciTech Connect

    Nicholas, Jason.D.

    2007-06-30

    Cerium gadolinium oxide (CGO) has been identified as an acceptable solid oxide fuel cell (SOFC) electrolyte at temperatures (500-700 C) where cheap, rigid, stainless steel interconnect substrates can be used. Unfortunately, both the high sintering temperature of pure CGO, >1200 C, and the fact that constraint during sintering often results in cracked, low density ceramic films, have complicated development of metal supported CGO SOFCs. The aim of this work was to find new sintering aids for Ce{sub 0.9}Gd{sub 0.1}O{sub 1.95}, and to evaluate whether they could be used to produce dense, constrained Ce{sub 0.9}Gd{sub 0.1}O{sub 1.95} films at temperatures below 1000 C. To find the optimal sintering aid, Ce{sub 0.9}Gd{sub 0.1}O{sub 1.95} was doped with a variety of elements, of which lithium was found to be the most effective. Dilatometric studies indicated that by doping CGO with 3mol% lithium nitrate, it was possible to sinter pellets to a relative density of 98.5% at 800 C--a full one hundred degrees below the previous low temperature sintering record for CGO. Further, it was also found that a sintering aid's effectiveness could be explained in terms of its size, charge and high temperature mobility. A closer examination of lithium doped Ce0.9Gd0.1O1.95 indicated that lithium affects sintering by producing a Li{sub 2}O-Gd{sub 2}O{sub 3}-CeO{sub 2} liquid at the CGO grain boundaries. Due to this liquid phase sintering, it was possible to produce dense, crack-free constrained films of CGO at the record low temperature of 950 C using cheap, colloidal spray deposition processes. This is the first time dense constrained CGO films have been produced below 1000 C and could help commercialize metal supported ceria based solid oxide fuel cells.

  14. Performance of AGR-1 High-Temperature Reactor Fuel During Post-Irradiation Heating Tests

    SciTech Connect

    Morris, Robert Noel; Baldwin, Charles A; Hunn, John D; Demkowicz, Paul; Reber, Edward

    2014-01-01

    The fission product retention of irradiated low-enriched uranium oxide/uranium carbide TRISO fuel compacts from the AGR-1 experiment has been evaluated at temperatures of 1600 1800 C during post-irradiation safety tests. Fourteen compacts (a total of ~58,000 particles) with a burnup ranging from 13.4 to 19.1% FIMA have been tested using dedicated furnace systems at Idaho National Laboratory and Oak Ridge National Laboratory. The release of fission products 110mAg, 134Cs, 137Cs, 154Eu, 155Eu, 90Sr, and 85Kr was monitored while heating the fuel specimens in flowing helium. The behavior of silver, europium, and strontium appears to be dominated by inventory that was originally released through intact SiC coating layers during irradiation, but was retained in the compact at the end of irradiation and subsequently released during the safety tests. However, at a test temperature of 1800 C, the data suggest that release of these elements through intact coatings may become significant after ~100 h. Cesium was very well retained by intact SiC layers, with a fractional release <5 10-6 after 300 h at 1600 C or 100 h at 1800 C. However, it was rapidly released from individual particles if the SiC layer failed, and therefore the overall cesium release fraction was dominated by the SiC defect and failure fractions in the fuel compacts. No complete TRISO coating layer failures were observed after 300 h at 1600 or 1700 C, and 85Kr release was very low during the tests (particles with breached SiC, but intact outer pyrocarbon, retained most of their krypton). Krypton release from TRISO failures was only observed after ~210 h at 1800 C in one compact. Post-safety-test examination of fuel compacts and particles has focused on identifying specific particles from each compact with notable fission product release and detailed analysis of the coating layers to understand particle behavior.

  15. Ionic liquids and ionic liquid acids with high temperature stability for fuel cell and other high temperature applications, method of making and cell employing same

    DOEpatents

    Angell, C. Austen; Xu, Wu; Belieres, Jean-Philippe; Yoshizawa, Masahiro

    2011-01-11

    Disclosed are developments in high temperature fuel cells including ionic liquids with high temperature stability and the storage of inorganic acids as di-anion salts of low volatility. The formation of ionically conducting liquids of this type having conductivities of unprecedented magnitude for non-aqueous systems is described. The stability of the di-anion configuration is shown to play a role in the high performance of the non-corrosive proton-transfer ionic liquids as high temperature fuel cell electrolytes. Performance of simple H.sub.2(g) electrolyte/O.sub.2(g) fuel cells with the new electrolytes is described. Superior performance both at ambient temperature and temperatures up to and above 200.degree. C. are achieved. Both neutral proton transfer salts and the acid salts with HSO.sup.-.sub.4 anions, give good results, the bisulphate case being particularly good at low temperatures and very high temperatures. The performance of all electrolytes is improved by the addition of a small amount of involatile base of pK.sub.a value intermediate between those of the acid and base that make the bulk electrolyte. The preferred case is the imidazole-doped ethylammonium hydrogensulfate which yields behavior superior in all respects to that of the industry standard phosphoric acid electrolyte.

  16. TINTE Uncertainty Analysis of the Maximum Fuel Temperature During a DLOFC Event for the 400 MW Pebble Bed Modular Reactor

    SciTech Connect

    Strydom, Gerhard

    2004-07-01

    The Pebble Bed Modular Reactor (PBMR) is a high temperature, helium cooled, graphite moderated pebbled bed reactor, using a multi-pass fuelling scheme. The aim of this paper is to quantify the effects of uncertainties inherent to various reactor and material parameters on the maximum fuel temperature during a De-pressurized Loss of Forced Cooling (DLOFC) event. The data is obtained by using the transient computer code TINTE, which was specifically developed to assess the nuclear and thermal-hydraulic transient behavior of pebble bed high temperature reactor designs. TINTE calculates time-dependent neutron fluxes, heat source distributions and heat transfer rates between solids and gasses in a 2- D r-z geometry to obtain the global transient core temperature behavior. This study is based on the 400 MW PBMR core design status as at April 2003, and includes DLOFC calculations over a wide range of reactor and material parameters. Some of the parameters investigated for their effect on the fuel temperature during the DLOFC are: reactor fission power and decay heat, control rod movements and scram scenarios, coolant mass flow rates and helium coolant and graphite reflector properties (conductivity, emissivity and specific heat capacity). The results of this study indicate that the current estimates for the total DLOFC maximum fuel temperature, for a 400 MW PBMR reactor operating at 105% power, are within an uncertainty band of {+-}107 deg. C for a DLOFC with scram. The three most important parameters influencing the maximum fuel temperatures during a DLOFC are (in sequence of importance): the reactor power level, the amount of decay heat generated by the nuclear fuel after shutdown, and the thermal conductivity of the pebble bed fuel spheres. (author)

  17. Neutronics and Depletion Methods for Parametric Studies of Fluoride Salt Cooled High Temperature Reactors with Slab Fuel Geometry and Multi-Batch Fuel Management Schemes

    SciTech Connect

    Cisneros, Anselmo T.; Ilas, Dan

    2013-01-01

    The Advanced High-Temperature Reactor (AHTR) is a 3400 MWth fluoride-salt-cooled high-temperature reactor (FHR) that uses TRISO particle fuel compacted into slabs rather than spherical or cylindrical fuel compacts. Simplified methods are required for parametric design studies such that analyzing the entire feasible design space for an AHTR is tractable. These simplifications include fuel homogenization techniques to increase the speed of neutron transport calculations in depletion analysis and equilibrium depletion analysis methods to analyze systems with multi-batch fuel management schemes. This paper presents three elements of significant novelty. First, the Reactivity-Equivalent Physical Transformation (RPT) methodology usually applied in systems with coated-particle fuel in cylindrical and spherical geometries has been extended to slab geometries. Secondly, based on this newly developed RPT method for slab geometries, a methodology that uses Monte Carlo depletion approaches was further developed to search for the maximum discharge burnup in a multi-batch system by iteratively estimating the beginning of equilibrium cycle (BOEC) composition and sampling different discharge burnups. This Iterative Equilibrium Depletion Search (IEDS) method fully defines an equilibrium fuel cycle (keff, power, flux, and composition evolutions) but is computationally demanding, although feasible on single-processor workstations. Finally, an analytical method, the Non-Linear Reactivity Model, was developed by expanding the linear reactivity model to include an arbitrary number of higher order terms so that single-batch depletion results could be extrapolated to estimate the maximum discharge burnup and BOEC keff in systems with multi-batch fuel management schemes. Results from this method were benchmarked against equilibrium depletion analysis results using the IEDS.

  18. Development and design of experiments optimization of a high temperature proton exchange membrane fuel cell auxiliary power unit with onboard fuel processor

    NASA Astrophysics Data System (ADS)

    Karstedt, Jörg; Ogrzewalla, Jürgen; Severin, Christopher; Pischinger, Stefan

    In this work, the concept development, system layout, component simulation and the overall DOE system optimization of a HT-PEM fuel cell APU with a net electric power output of 4.5 kW and an onboard methane fuel processor are presented. A highly integrated system layout has been developed that enables fast startup within 7.5 min, a closed system water balance and high fuel processor efficiencies of up to 85% due to the recuperation of the anode offgas burner heat. The integration of the system battery into the load management enhances the transient electric performance and the maximum electric power output of the APU system. Simulation models of the carbon monoxide influence on HT-PEM cell voltage, the concentration and temperature profiles within the autothermal reformer (ATR) and the CO conversion rates within the watergas shift stages (WGSs) have been developed. They enable the optimization of the CO concentration in the anode gas of the fuel cell in order to achieve maximum system efficiencies and an optimized dimensioning of the ATR and WGS reactors. Furthermore a DOE optimization of the global system parameters cathode stoichiometry, anode stoichiometry, air/fuel ratio and steam/carbon ratio of the fuel processing system has been performed in order to achieve maximum system efficiencies for all system operating points under given boundary conditions.

  19. Process Developed for Generating Ceramic Interconnects With Low Sintering Temperatures for Solid Oxide Fuel Cells

    NASA Technical Reports Server (NTRS)

    Zhong, Zhi-Min; Goldsby, Jon C.

    2005-01-01

    Solid oxide fuel cells (SOFCs) have been considered as premium future power generation devices because they have demonstrated high energy-conversion efficiency, high power density, and extremely low pollution, and have the flexibility of using hydrocarbon fuel. The Solid-State Energy Conversion Alliance (SECA) initiative, supported by the U.S. Department of Energy and private industries, is leading the development and commercialization of SOFCs for low-cost stationary and automotive markets. The targeted power density for the initiative is rather low, so that the SECA SOFC can be operated at a relatively low temperature (approx. 700 C) and inexpensive metallic interconnects can be utilized in the SOFC stack. As only NASA can, the agency is investigating SOFCs for aerospace applications. Considerable high power density is required for the applications. As a result, the NASA SOFC will be operated at a high temperature (approx. 900 C) and ceramic interconnects will be employed. Lanthanum chromite-based materials have emerged as a leading candidate for the ceramic interconnects. The interconnects are expected to co-sinter with zirconia electrolyte to mitigate the interface electric resistance and to simplify the processing procedure. Lanthanum chromites made by the traditional method are sintered at 1500 C or above. They react with zirconia electrolytes (which typically sinter between 1300 and 1400 C) at the sintering temperature of lanthanum chromites. It has been envisioned that lanthanum chromites with lower sintering temperatures can be co-fired with zirconia electrolyte. Nonstoichiometric lanthanum chromites can be sintered at lower temperatures, but they are unstable and react with zirconia electrolyte during co-sintering. NASA Glenn Research Center s Ceramics Branch investigated a glycine nitrate process to generate fine powder of the lanthanum-chromite-based materials. By simultaneously doping calcium on the lanthanum site, and cobalt and aluminum on the

  20. Material synthesis and fabrication method development for intermediate temperature solid oxide fuel cells

    NASA Astrophysics Data System (ADS)

    Ding, Hanping

    Solid oxide fuel cells (SOFCs) are operated in high temperature conditions (750-1000 °C). The high operating temperature in turn may lead to very complicated material degradation issues, significantly increasing the cost and reducing the durability of SOFC material systems. In order to widen material selections, reduce cost, and increase durability of SOFCs, there is a growing interest to develop intermediate temperature SOFCs (500-750 °C). However, lowering operating temperature will cause substantial increases of ohmic resistance of electrolyte and polarization resistance of electrodes. This dissertation aimed at developing high-performance intermediate-temperature SOFCs through the employment of a series of layered perovskite oxides as novel cathode materials to minimize the potential electrode polarization on oxygen reduction reaction resulting from the unique crystal structure. The high performance of such perovskites under lower temperatures lies in the fact that a simple cubic perovskite with randomly occupied A-sites transforming into a layered compound with ordered lanthanide and alkali-earth cations may reduce the oxygen bonding strength and provide disorder-free channels for oxygen ion migrations. In order to compromise the cell performance and chemical and mechanical stability, the substitution of Fe in B site was comprehensively investigated to explore the effects of Fe doping on the crystal structure, thermal and electrical properties, as well as electrochemical performance. Furthermore, a platinum nanowire network was successfully developed as an ultrathin electrochemically efficient current collector for SOFCs. The unique platinum network on cathode surface can connect the oxygen reduction reaction (ORR) sites at the nano-scale to the external circuit while being able to substantially avoid blocking the open pores of the cathode. The superior electrochemical performance was exhibited, including the highly reduced electrode polarization resistance

  1. Investigation of low temperature solid oxide fuel cells for air-independent UUV applications

    NASA Astrophysics Data System (ADS)

    Moton, Jennie Mariko

    Unmanned underwater vehicles (UUVs) will benefit greatly from high energy density (> 500 Wh/L) power systems utilizing high-energy-density fuels and air-independent oxidizers. Current battery-based systems have limited energy densities (< 400 Wh/L), which motivate development of alternative power systems such as solid oxide fuel cells (SOFCs). SOFC-based power systems have the potential to achieve the required UUV energy densities, and the current study explores how SOFCs based on gadolinia-doped ceria (GDC) electrolytes with operating temperatures of 650°C and lower may operate in the unique environments of a promising UUV power plant. The plant would contain a H 2O2 decomposition reactor to supply humidified O2 to the SOFC cathode and exothermic aluminum/H2O combustor to provide heated humidified H2 fuel to the anode. To characterize low-temperature SOFC performance with these unique O2 and H2 source, SOFC button cells based on nickel/GDC (Gd0.1Ce0.9O 1.95) anodes, GDC electrolytes, and lanthanum strontium cobalt ferrite (La0.6Sr0.4Co0.2Fe0.8O3-δ or LSCF)/GDC cathodes were fabricated and tested for performance and stability with humidity on both the anode and the cathode. Cells were also tested with various reactant concentrations of H2 and O2 to simulate gas depletion down the channel of an SOFC stack. Results showed that anode performance depended primarily on fuel concentration and less on the concentration of the associated increase in product H2O. O 2 depletion with humidified cathode flows also caused significant loss in cell current density at a given voltage. With the humidified flows in either the anode or cathode, stability tests of the button cells at 650 °C showed stable voltage is maintained at low operating current (0.17 A/cm2) at up to 50 % by mole H2O, but at higher current densities (0.34 A/cm2), irreversible voltage degradation occurred at rates of 0.8-3.7 mV/hour depending on exposure time. From these button cell results, estimated average

  2. Consideration of Lower Allowable Impact Temperature for DOP-26 Iridium Alloy Fueled Clads

    NASA Astrophysics Data System (ADS)

    Skrabek, Emanuel A.

    2005-02-01

    The current DOE General Purpose Heat Source (GPHS) was developed specifically for a SiGe Radioisotope Thermoelectric Generator (RTG) which was to be launched on a Space Shuttle. In such a launch, if the final stage of the deployed spacecraft failed to ignite, the spacecraft and RTG would reenter the atmosphere after about three months in a Shuttle parking orbit. The indium alloy clad containing the radioisotope fuel would have then been at about 1300° C for the entire time on orbit. This would lead to some grain growth in the clad material, which would tend to decrease its ductility. Due to these constraints, it was concluded by the heat source community that safety considerations would require that the clads be maintained at a temperature of at least 930° C through impact. The safety testing for the GPHS RTG programs was therefore conducted with these conditions as guides. Within this set of guidelines, the heat source was shown to be able to safely handle all credible launch and reentry accident events in these missions. Currently proposed missions plan to use different power conversion systems and launch scenarios that are able to utilize much lower operating temperatures. Imposing the high operating and impact temperatures required by the SiGe RTG onto these new systems would lead to unnecessary added design complexity and probably a less robust system. If the heat source is operated so that the iridium alloy clads are generally maintained at less than 1000° C, essentially no grain growth would be experienced over normal mission lifetimes, and the clads would stay more ductile and able to safely withstand the resulting lower impact temperatures. Therefore DOE has embarked on a study to determine the lowest safe operating and impact temperatures for the GPHS. This paper presents the historical background and some preliminary results of this study.

  3. A high-temperature gas-and-steam turbine plant operating on combined fuel

    NASA Astrophysics Data System (ADS)

    Klimenko, A. V.; Milman, O. O.; Shifrin, B. A.

    2015-11-01

    A high-temperature gas-steam turbine plant (GSTP) for ultrasupercritical steam conditions is proposed based on an analysis of prospects for the development of power engineering around the world and in Russia up to 2040. The performance indicators of a GSTP using steam from a coal-fired boiler with a temperature of 560-620°C with its superheating to 1000-1500°C by firing natural gas with oxygen in a mixingtype steam superheater are analyzed. The thermal process circuit and design of a GSTP for a capacity of 25 MW with the high- and intermediate-pressure high-temperature parts with the total efficiency equal to 51.7% and the natural gas utilization efficiency equal to 64-68% are developed. The principles of designing and the design arrangement of a 300 MW GSTP are developed. The effect of economic parameters (the level and ratio of prices for solid fuel and gas, and capital investments) on the net cost of electric energy is determined. The net cost of electric energy produced by the GSTP is lower than that produced by modern combined-cycle power plants in a wide variation range of these parameters. The components of a high-temperature GSTP the development of which determines the main features of such installations are pointed out: a chamber for combusting natural gas and oxygen in a mixture with steam, a vacuum device for condensing steam with a high content of nondensables, and a control system. The possibility of using domestically available gas turbine technologies for developing the GSTP's intermediate-pressure high-temperature part is pointed out. In regard of its environmental characteristics, the GSTP is more advantageous as compared with modern condensing power plants: it allows a flow of concentrated carbon dioxide to be obtained at its outlet, which can be reclaimed; in addition, this plant requires half as much consumption of fresh water.

  4. Comparative study of soot formation on the centerline of axisymmetric laminar diffusion flames: Fuel and temperature effects

    SciTech Connect

    Gomez, A.; Littman, M.G.; Glassman, I.

    1987-11-01

    The appearance of soot on the centerline aof axisymmetric laminar diffusion flames has been studied by monitoring (i) the gas temperature by thermocouples; (ii) the soot particle field by laser scattering/extinction; (iii) the presence of polycyclic aromatic hydrocarbons (PCAH) by laser induced fluorescence. Four fuels were used: butene, acetylene, butadiene, and benzene. All but one flame were at the smoke height condition and were characterized by different levels of N/sub 2/ dilution aimed at controlling the temperature field. It was observed that (i) soot nucleation occurs at the centerline; (ii) the soot onset on the centerline occurs when a characteristic temperature of 1350K is measured, regardless of fuel type or level of dilution; (iii) butene and benzene have similar fluorescence patterns, in contrast with premixed flame environments. These last two observations are consistent with the proposal that, though the extent of conversion of fuel into soot may significantly change from fuel to fuel, there is a common mechanism of soot formation for all fuels. Results are discussed.

  5. High temperature solid oxide fuel cell integrated with novel allothermal biomass gasification. Part I: Modelling and feasibility study

    NASA Astrophysics Data System (ADS)

    Panopoulos, K. D.; Fryda, L. E.; Karl, J.; Poulou, S.; Kakaras, E.

    Biomass gasification derived fuel gas is a renewable fuel that can be used by high temperature fuel cells. In this two-part work an attempt is made to investigate the integration of a near atmospheric pressure solid oxide fuel cell (SOFC) with a novel allothermal biomass steam gasification process into a combined heat and power (CHP) system of less than MW e nominal output range. Heat for steam gasification is supplied from SOFC depleted fuel into a fluidised bed combustor via high temperature sodium heat pipes. The integrated system model was built in Aspen Plus™ simulation software and is described in detail. Part I investigates the feasibility and critical aspects of the system based on modelling results. A low gasification steam to biomass ratio (STBR = 0.6) is used to avoid excess heat demands and to allow effective H 2S high temperature removal. Water vapour is added prior to the anode to avoid carbon deposition. The SOFC off gases adequately provide gasification heat when fuel utilisation factors are <0.75; otherwise extra biomass must be combusted with overall efficiency penalty. For SOFC operation with U f = 0.7 and current density 2500 A m -2 the electrical efficiency is estimated at 36% while thermal efficiency at 14%. An exergy analysis is presented in Part II.

  6. High performance zirconia-bismuth oxide nanocomposite electrolytes for lower temperature solid oxide fuel cells

    NASA Astrophysics Data System (ADS)

    Joh, Dong Woo; Park, Jeong Hwa; Kim, Do Yeub; Yun, Byung-Hyun; Lee, Kang Taek

    2016-07-01

    We develop a novel nanocomposite electrolyte, consisting of yttria-stabilized zirconia (YSZ) and erbia-stabilized bismuth oxide (ESB). The 20 mol% ESB-incorporated YSZ composite (20ESB-YSZ) achieves the high density (>97%) at the low sintering temperature of 800 °C. The microstructural analysis of 20ESB-YSZ reveals the characteristic nanocomposite structure of the highly percolated ESB phase at the YSZ grain boundaries (a few ∼ nm thick). The ionic conductivity of 20ESB-YSZ is increased by 5 times compared to that of the conventional YSZ due to the fast oxygen ion transport along the ESB phase. Moreover, this high conductivity is maintained up to 580 h, indicating high stability of the ESB-YSZ nanocomposite. In addition, the oxygen reduction reaction at the composite electrolyte/cathode interface is effectively enhanced (∼70%) at the temperature below 650 °C, mainly due to the fast dissociative oxygen adsorption on the ESB surface as well as the rapid oxygen ion incorporation into the ESB lattice. Thus, we believe this ESB-YSZ nanocomposite is a promising electrolyte for high performance solid oxide fuel cells at reduced temperatures.

  7. Carbon composite bipolar plate for high-temperature proton exchange membrane fuel cells (HT-PEMFCs)

    NASA Astrophysics Data System (ADS)

    Lee, Dongyoung; Lee, Dai Gil

    2016-09-01

    A carbon/epoxy composite bipolar plate is an ideal substitute for the brittle graphite bipolar plate for lightweight proton exchange membrane fuel cells (PEMFCs) because of its high specific strength and stiffness. However, conventional carbon/epoxy composite bipolar plates are not applicable for high-temperature PEMFCs (HT-PEMFCs) because these systems are operated at higher temperatures than the glass transition temperatures of conventional epoxies. Therefore, in this study, a cyanate ester-modified epoxy is adopted for the development of a carbon composite bipolar plate for HT-PEMFCs. The composite bipolar plate with exposed surface carbon fibers is produced without any surface treatments or coatings to increase the productivity and is integrated with a silicone gasket to reduce the assembly cost. The developed carbon composite bipolar plate exhibits not only superior electrical properties but also high thermo-mechanical properties. In addition, a unit cell test is performed, and the results are compared with those of the conventional graphite bipolar plate.

  8. Rapid self-start of polymer electrolyte fuel cells from sub-freezing temperatures.

    SciTech Connect

    Ahluwalia, R. K.; Wang, X.; Nuclear Engineering Division

    2005-01-01

    Polymer electrolyte fuel cell (PEFC) systems for light-duty vehicles must be able to start unassisted and rapidly from temperatures below -20 degrees C. Managing buildup of ice within the porous cathode catalyst and electrode structure is the key to self-starting a PEFC stack from subfreezing temperatures. The stack temperature must be raised above the melting point of ice before the ice completely covers the cathode catalyst and shuts down the electrochemical reaction. For rapid and robust self-start it is desirable to operate the stack near the short-circuit conditions. This mode of operation maximizes hydrogen utilization, favors production of waste heat that is absorbed by the stack, and delays complete loss of effective electrochemical surface area by causing a large fraction of the ice to form in the gas diffusion layer rather than in the cathode catalyst layer. Preheating the feed gases, using the power generated to electrically heat the stack, and operating pressures have only small effect on the ability to self-start or the startup time. In subfreezing weather, the stack shut-down protocol should include flowing ambient air through the hot cathode passages to vaporize liquid water remaining in the cathode catalyst. Self-start is faster and more robust if the bipolar plates are made from metal rather than graphite.

  9. Rapid self-start of polymer electrolyte fuel cell stacks from subfreezing temperatures

    NASA Astrophysics Data System (ADS)

    Ahluwalia, R. K.; Wang, X.

    Polymer electrolyte fuel cell (PEFC) systems for light-duty vehicles must be able to start unassisted and rapidly from temperatures below -20 °C. Managing buildup of ice within the porous cathode catalyst and electrode structure is the key to self-starting a PEFC stack from subfreezing temperatures. The stack temperature must be raised above the melting point of ice before the ice completely covers the cathode catalyst and shuts down the electrochemical reaction. For rapid and robust self-start it is desirable to operate the stack near the short-circuit conditions. This mode of operation maximizes hydrogen utilization, favors production of waste heat that is absorbed by the stack, and delays complete loss of effective electrochemical surface area by causing a large fraction of the ice to form in the gas diffusion layer rather than in the cathode catalyst layer. Preheating the feed gases, using the power generated to electrically heat the stack, and operating pressures have only small effect on the ability to self-start or the startup time. In subfreezing weather, the stack shut-down protocol should include flowing ambient air through the hot cathode passages to vaporize liquid water remaining in the cathode catalyst. Self-start is faster and more robust if the bipolar plates are made from metal rather than graphite.

  10. Modeling status and needs for temperature calculations within spent fuel disposal containers

    SciTech Connect

    Sullivan, T.M.; Pescatore, C.

    1989-10-01

    The Brookhaven National Laboratory (BNL) Waste Materials and Environment Modeling (WMEM) Program has been assigned the task of helping the DOE formulate and certify analytical tools needed to support and/or strengthen the Waste Package Licensing strategy. One objective of the WMEM program is to perform qualitative and quantitative analyses of processes related to the internal waste package environment, e.g., temperature, radiolysis effects, presence of moisture, etc. The primary objective of this report is to present the findings of a literature review of work pertinent to predicting intact waste package internal temperatures under spent fuel isolation conditions. Therefore, it is assumed that a repository scale thermal analysis has been conducted and the exterior temperature of the waste package is known. Thus, the problem reduces to one determined by the waste package and its properties. Secondary objectives of this report are to identify key parameters and methodologies for performing the thermal analysis within intact waste containers, and identify sources of uncertainty in these calculations. 37 refs., 6 figs., 2 tabs.

  11. A low-Cr metallic interconnect for intermediate-temperature solid oxide fuel cells

    SciTech Connect

    Geng, Shujiang; Zhu, Jiahong; Brady, Michael P; Anderson, Harlan; ZHOU, XIADONG; YANG, ZHENGUO

    2007-01-01

    Solid oxide fuel cells (SOFCs) have attracted significant attention due to the potential for environmentally-friendly power generation with high efficiency, fuel flexibility, and zero/no emissions. However, the main hurdles thwarting the commercial introduction of SOFCs are the stack cost and durability, particularly related to the long-term stability of stack/cell materials such as the interconnect 1-3. There has been recent interest in utilizing the Cr2O3-forming alloys as interconnect for intermediate-temperature SOFCs4-6. As a consequence, volatile Cr species from the Cr2O3 scale can cause severe degradation of electrical and catalytic properties of the cathode7-9. Here, we report a new low-Cr Fe-Co-Ni base alloy that demonstrates a close match in coefficient of thermal expansion (CTE) with adjacent cell components; good oxidation resistance; and low oxide scale area specific resistance (ASR). The formation of a Cr-free (Fe,Co,Ni)3O4 spinel outer layer over the chromia inner layer upon thermal exposure effectively reduces the chromium evaporation.

  12. Development and demonstration of a higher temperature PEM fuel cell stack

    NASA Astrophysics Data System (ADS)

    Bonville, Leonard J.; Kunz, H. Russell; Song, Ying; Mientek, Anthony; Williams, Minkmas; Ching, Albert; Fenton, James M.

    Research and development was conducted on a proton exchange membrane (PEM) fuel cell stack to demonstrate the capabilities of Ionomem Corporation's composite membrane to operate at 120 °C and ambient pressure for on-site electrical power generation with useful waste heat. The membrane was a composite of polytetrafluoroethylene (PTFE), Nafion ®, and phosphotungstic acid. Studies were first performed on the membrane, cathode catalyst layer, and gas diffusion layer to improve performance in 25 cm 2, subscale cells. This technology was then scaled-up to a commercial 300 cm 2 size and evaluated in multi-cell stacks. The resulting stack obtained a performance near that of the subscale cells, 0.60 V at 400 mA cm -2 at near 120 °C and ambient pressure with hydrogen and air reactants containing water at 35% relative humidity. The water used for cooling the stack resulted in available waste heat at 116 °C. The performance of the stack was verified. This was the first successful test of a higher-temperature, PEM, fuel-cell stack that did not use phosphoric acid electrolyte.

  13. Bismuth doped lanthanum ferrite perovskites as novel cathodes for intermediate-temperature solid oxide fuel cells.

    PubMed

    Li, Mei; Wang, Yao; Wang, Yunlong; Chen, Fanglin; Xia, Changrong

    2014-07-23

    Bismuth is doped to lanthanum strontium ferrite to produce ferrite-based perovskites with a composition of La(0.8-x)Bi(x)Sr0.2FeO(3-δ) (0 ≤ x ≤ 0.8) as novel cathode material for intermediate-temperature solid oxide fuel cells. The perovskite properties including oxygen nonstoichiometry coefficient (δ), average valence of Fe, sinterability, thermal expansion coefficient, electrical conductivity (σ), oxygen chemical surface exchange coefficient (K(chem)), and chemical diffusion coefficient (D(chem)) are explored as a function of bismuth content. While σ decreases with x due to the reduced Fe(4+) content, D(chem) and K(chem) increase since the oxygen vacancy concentration is increased by Bi doping. Consequently, the electrochemical performance is substantially improved and the interfacial polarization resistance is reduced from 1.0 to 0.10 Ω cm(2) at 700 °C with Bi doping. The perovskite with x = 0.4 is suggested as the most promising composition as solid oxide fuel cell cathode material since it has demonstrated high electrical conductivity and low interfacial polarization resistance. PMID:24971668

  14. High temperature postirradiation materials performance of spent pressurized water reactor fuel rods under dry storage conditions

    SciTech Connect

    Einziger, R.E.; Atkin, S.D.; Pasupathi, V.; Stellrecht, D.E.

    1982-04-01

    Postirradiation studies on failure mechanisms of well-characterized pressurized water reactor rods were conducted for up to a year at 482, 510, and 571/sup 0/C in limited air and inert gas atmospheres. No cladding breaches occurred even though the tests operated many orders of magnitude longer in time than the lifetime predicted by Blackburn's analyses. The extended lifetime is due to significant creep strain of the Zircaloy cladding, which decreases the internal rod pressure. The cladding creep also contributes to radial cracks, through the external oxide and internal fuel-cladding chemical interaction layers, which propagated into and arrested in an oxygen stabilized alpha-Zircaloy layer. There were no signs of either additional cladding hydriding, stress corrosion cracking, or fuel pellet degradation. If irradiation hardening does not reduce the stress rupture properties of Zircaloy, a conservative maximum storage temperature of 400/sup 0/C based on a stress-rupture mechanism is recommended to ensure a 1000-yr cladding lifetime.

  15. LOW-TEMPERATURE, ANODE-SUPPORTED HIGH POWER DENSITY SOLID OXIDE FUEL CELLS WITH NANOSTRUCTURED ELECTRODES

    SciTech Connect

    Prof. Anil V. Virkar

    2000-04-07

    This report contains the following three parts. (1) An investigation into the use of direct liquid hydrocarbon fuels in single cell tests. (2) An analysis of residual stresses in anode-supported solid oxide fuel cells. (3) A manuscript on the synthesis of nanosize ceramic (electrode and electrolyte) powders. Nanosize YSZ powder was prepared by a unique approach, in which yttria-doped BaZrO{sub 3} or yttria-doped Na{sub 2}ZrO{sub 3} precursors were first synthesized by a solid state reaction. Then, then the unwanted species, BaO or Na{sub 2}O, was leached away by washing the precursors in a dilute HNO{sub 3} solution or in water. This led to the formation of very fine, nanosize yttria-stabilized zirconia (YSZ). The particle size of the as-synthesized YSZ powders was a few nanometers and increased to tens of nanometers after thermal treatment at a temperature as high as 1000 C. The as-synthesized as well as heat-treated YSZ powder was of cubic crystal structure.

  16. DNS of moderate-temperature gaseous mixing layers laden with multicomponent-fuel drops

    NASA Technical Reports Server (NTRS)

    Clercq, P. C. Le; Bellan, J.

    2004-01-01

    A formulation representing multicomponent-fuel (MC-fuel) composition as a Probability Distribution Function (PDF) depending on the molar weight is used to construct a model of a large number of MC-fuel drops evaporating in a gas flow, so as to assess the extent of fuel specificity on the vapor composition.

  17. The electrolyte challenge for a direct methanol-air polymer electrolyte fuel cell operating at temperatures up to 200 C

    NASA Technical Reports Server (NTRS)

    Savinell, Robert; Yeager, Ernest; Tryk, Donald; Landau, Uziel; Wainright, Jesse; Gervasio, Dominic; Cahan, Boris; Litt, Morton; Rogers, Charles; Scherson, Daniel

    1993-01-01

    Novel polymer electrolytes are being evaluated for use in a direct methanol-air fuel cell operating at temperatures in excess of 100 C. The evaluation includes tests of thermal stability, ionic conductivity, and vapor transport characteristics. The preliminary results obtained to date indicate that a high temperature polymer electrolyte fuel cell is feasible. For example, Nafion 117 when equilibrated with phosphoric acid has a conductivity of at least 0.4 Omega(exp -1)cm(exp -1) at temperatures up to 200 C in the presence of 400 torr of water vapor and methanol vapor cross over equivalent to 1 mA/cm(exp 2) under a one atmosphere methanol pressure differential at 135 C. Novel polymers are also showing similar encouraging results. The flexibility to modify and optimize the properties by custom synthesis of these novel polymers presents an exciting opportunity to develop an efficient and compact methanol fuel cell.

  18. Effect of Fuel-Air Ratio, Inlet Temperature, and Exhaust Pressure on Detonation

    NASA Technical Reports Server (NTRS)

    Taylor, E S; Leary, W A; Diver, J R

    1940-01-01

    An accurate determination of the end-gas condition was attempted by applying a refined method of analysis to experimental results. The results are compared with those obtained in Technical Report no. 655. The experimental technique employed afforded excellent control over the engine variables and unusual cyclic reproducibility. This, in conjunction with the new analysis, made possible the determination of the state of the end-gas at any instant to a fair degree of precision. Results showed that for any given maximum pressure the maximum permissible end-gas temperature increased as the fuel-air ratio was increased. The tendency to detonate was slightly reduced by an increase in residual gas content resulting from an increase in exhaust backpressure with inlet pressure constant.

  19. Peak shifted properties of the "low background NaI(Tl) detectors": An experimental study of response function behavior in different temperature and acquisition time

    NASA Astrophysics Data System (ADS)

    Rezaei Moghaddam, Y.; Rafat Motavalli, L.; Miri Hakimabadi, H.

    2016-09-01

    Due to the necessity of using low background NaI detector in sensitive and accurate measurements, study on the response function variations in different conditions is very important. These types of detectors have different responses in various measurement conditions, including time, temperature and high voltage. In this study, the response function of 76 B 76 LB NaI (SCIONIX) in different conditions is discussed. According to the channel shifting in these detectors and its direct effect on degrading the resolution, the most convenient measurement condition for these detectors, is proposed. Finally, it is recommended that before long-time measurements a "waiting time" is needed to avoid the channel shifting effects.

  20. Depletion Analysis of Modular High Temperature Gas-cooled Reactor Loaded with LEU/Thorium Fuel

    SciTech Connect

    Sonat Sen; Gilles Youinou

    2013-02-01

    Thorium based fuel has been considered as an option to uranium-based fuel, based on considerations of resource utilization (Thorium is more widely available when compared to Uranium). The fertile isotope of Thorium (Th-232) can be converted to fissile isotope U-233 by neutron capture during the operation of a suitable nuclear reactor such as High Temperature Gas-cooled Reactor (HTGR). However, the fertile Thorium needs a fissile supporter to start and maintain the conversion process such as U-235 or Pu-239. This report presents the results of a study that analyzed the thorium utilization in a prismatic HTGR, namely Modular High Temperature Gas-Cooled Reactor (MHTGR) that was designed by General Atomics (GA). The collected for the modeling of this design come from Chapter 4 of MHTGR Preliminary Safety Information Document that GA sent to Department of Energy (DOE) on 1995. Both full core and unit cell models were used to perform this analysis using SCALE 6.1 and Serpent 1.1.18. Because of the long mean free paths (and migration lengths) of neutrons in HTRs, using a unit cell to represent a whole core can be non-trivial. The sizes of these cells were set to match the spectral index between unit cell and full core domains. It was found that for the purposes of this study an adjusted unit cell model is adequate. Discharge isotopics and one-group cross-sections were delivered to the transmutation analysis team. This report provides documentation for these calculations

  1. Peak Experience Project

    ERIC Educational Resources Information Center

    Scott, Daniel G.; Evans, Jessica

    2010-01-01

    This paper emerges from the continued analysis of data collected in a series of international studies concerning Childhood Peak Experiences (CPEs) based on developments in understanding peak experiences in Maslow's hierarchy of needs initiated by Dr Edward Hoffman. Bridging from the series of studies, Canadian researchers explore collected…

  2. New fuel cells system for portable application with low temperature cofired ceramic (LTCC) technology

    NASA Astrophysics Data System (ADS)

    Gao, Yong

    Miniature direct methanol fuel cells (DMFCs) are promising micro power sources for portable appliction. Low temperature cofired ceramic (LTCC), a competitive technology for current MEMS based fabrication, provides cost-effective mass manufacturing route for miniature DMFCs. Porous silver tape is adapted as electrodes to replace the traditional porous carbon electrodes due to its compatibility to LTCC processing and other electrochemical advantages. Electrochemical evaluation of silver under DMFCs operating conditions demonstrated that silver is a good electrode for DMFCs because of its reasonable corrosion resistance, low passivating current, and enhanced catalytic effect. Two catalyst loading methods (cofiring and postfiring) of the platinum and ruthenium catalysts are evaluated for LTCC based processing. The electrochemical analysis exhibits that the cofired path out-performs the postfiring path both at the anode and cathode. The reason is the formation of high surface area precipitated whiskers. Self-constraint sintering is utilized to overcome the difficulties of the large difference of coefficient of thermal expansion (CTE) between silver and LTCC (Dupont 951) tape during cofiring. The graphite sheet employed as a cavity fugitive insert guarantees cavity dimension conservation. Finally, performance of the membrane electrode assembly (MEA) with the porous silver electrode in the regular graphite electrode based cell and the integrated cofired cell is measured under passive fuel feeding condition. The MEA of the regular cell performs better as the electrode porosity and temperature increased. The power density of 10 mWcm-2 was obtained at ambient conditions with 1M methanol and it increased to 16 mWcm -2 at 50°C from an open circuit voltage of 0.58V. For the integrated prototype cell, the best performance, which depends on the balance methanol crossover and mass transfer at different temperatures and methanol concentrations, reaches 1.13 mWcm-2 at 2M methanol

  3. Simplified Reference Electrode for Electrorefining of Spent Nuclear Fuel in High Temperature Molten Salt

    SciTech Connect

    Kim Davies; Shelly X Li

    2007-09-01

    Pyrochemical processing plays an important role in development of proliferation- resistant nuclear fuel cycles. At the Idaho National Laboratory (INL), a pyrochemical process has been implemented for the treatment of spent fuel from the Experimental Breeder Reactor II (EBR-II) in the last decade. Electrorefining in a high temperature molten salt is considered a signature or central technology in pyroprocessing fuel cycles. Separation of actinides from fission products is being demonstrated by electrorefining the spent fuel in a molten UCl3-LiCl-KCl electrolyte in two engineering scale electrorefiners (ERs). The electrorefining process is current controlled. The reference electrode provides process information through monitoring of the voltage difference between the reference and the anode and cathode electrodes. This information is essential for monitoring the reactions occurring at the electrodes, investigating separation efficiency, controlling the process rate, and determining the process end-point. The original reference electrode has provided good life expectancy and signal stability, but is not easily replaceable. The reference electrode used a vycor-glass ion-permeable membrane containing a high purity silver wire with one end positioned in ~2 grams of LiCl/KCl salt electrolyte with a low concentration (~1%) AgCl. It was, however, a complex assembly requiring specialized skill and talent to fabricate. The construction involved multiple small pieces, glass joints, ceramic to glass joints, and ceramic to metal joints all assembled in a high purity inert gas environment. As original electrodes reached end-of-life it was uncertain if the skills and knowledge were readily available to successfully fabricate replacements. Experimental work has been conducted to identify a simpler electrode design while retaining the needed long life and signal stability. This improved design, based on an ion-permeable membrane of mullite has been completed. Use of the silver wire

  4. Performance enhancement of low temperature polymer electrolyte membrane fuel cells by catalyst and support layer modifications

    NASA Astrophysics Data System (ADS)

    Hall, Timothy David

    Possible enhancement of low temperature polymer electrolyte membrane fuel cells (PEMFC) or direct methanol fuel cells (DMFC) was investigated by modifying catalyst and support layers. Platinum (Pt) and platinum cobalt (Pt xCo1-x) alloys were prepared by pulsed electrodeposition onto Toray carbon paper. Composite supports composed of either commercial multi-walled nanofiber (MWNF) mats or MWNF layers on a commercial backing were also investigated. X-ray diffraction (XRD), scanning electron microscopy (SEM), inductively coupled plasma-optical emission spectroscopy (ICP-OES), and energy dispersive x-ray (EDX) were used to characterize the surface structure, composition, and catalyst loading. Various electrochemical techniques with a wet electrochemical cell, a Nuvant multi-array system, and a Scribner fuel cell system were used to study and rank the effectiveness of the catalysts and supports toward both the methanol oxidation reaction and the oxygen reduction reaction. The activity toward methanol oxidation of the electrodeposited Pt catalyst was found to be dependent on the deposited mass. Further comparisons between commercial electrodes in the Nuvant system showed these deposits can yield activities comparable to those of commercially available electrodes. The structure of the Pt electrodeposits was highly non-uniform due to the H2 evolution during the deposition process blocking the cathodes surface. The activities of the planar structured PtxCo1-x deposits were insignificant for both oxygen reduction and methanol oxidation. The composition of the deposits ranged from 5 to 15 at% Pt. It was found by both the Nuvant and Scribner systems that the addition of a thin hydrophilic MWNF layer to a hydrophobic electrode would enhance the performance of a DMFC anode. In the Nuvant system, the addition of a thin hydrophilic MWNF layer to a hydrophobic electrode also enhanced the PEM cathode activity. This however was not corroborated by Scribner analysis, showing a

  5. Off-design temperature effects on nuclear fuel pins for an advanced space-power-reactor concept

    NASA Technical Reports Server (NTRS)

    Bowles, K. J.

    1974-01-01

    An exploratory out-of-reactor investigation was made of the effects of short-time temperature excursions above the nominal operating temperature of 990 C on the compatibility of advanced nuclear space-power reactor fuel pin materials. This information is required for formulating a reliable reactor safety analysis and designing an emergency core cooling system. Simulated uranium mononitride (UN) fuel pins, clad with tungsten-lined T-111 (Ta-8W-2Hf) showed no compatibility problems after heating for 8 hours at 2400 C. At 2520 C and above, reactions occurred in 1 hour or less. Under these conditions free uranium formed, redistributed, and attacked the cladding.

  6. New approaches towards novel composite and multilayer membranes for intermediate temperature-polymer electrolyte fuel cells and direct methanol fuel cells

    NASA Astrophysics Data System (ADS)

    Branco, Carolina Musse; Sharma, Surbhi; de Camargo Forte, Maria Madalena; Steinberger-Wilckens, Robert

    2016-06-01

    This review analyses the current and existing literature on novel composite and multilayer membranes for Polymer Electrolyte Fuel Cell applications, including intermediate temperature polymer electrolyte fuel cell (IT-PEFC) and direct methanol fuel cell (DMFC) systems. It provides a concise scrutiny of the vast body of literature available on organic and inorganic filler based polymer membranes and links it to the new emerging trend towards novel combinations of multilayered polymer membranes for applications in DMFC and IT-PEFC. The paper carefully explores the advantages and disadvantages of the most common preparation techniques reported for multilayered membranes such as hot-pressing, casting and dip-coating and also summarises various other fresh and unique techniques employed for multilayer membrane preparation.

  7. Ignition of lean fuel-air mixtures in a premixing-prevaporizing duct at temperatures up to 1000 K

    NASA Technical Reports Server (NTRS)

    Tacina, R. R.

    1980-01-01

    Conditions were determined in a premixing prevaporizing fuel preparation duct at which ignition occurred. An air blast type fuel injector with nineteen fuel injection points was used to provide a uniform spatial fuel air mixture. The range of inlet conditions where ignition occurred were: inlet air temperatures of 600 to 1000 K air pressures of 180 to 660 kPa, equivalence ratios (fuel air ratio divided by stoichiometric fuel air ratio) from 0.12 to 1.05, and velocities from 3.5 to 30 m/s. The duct was insulated and the diameter was 12 cm. Mixing lengths were varied from 16.5 to 47.6 and residence times ranged from 4.6 to 107 ms. The fuel was no. 2 diesel. Results show a strong effect of equivalence ratio, pressure and temperature on the conditions where ignition occurred. The data did not fit the most commonly used model of auto-ignition. A correlation of the conditions where ignition would occur which apply to this test apparatus over the conditions tested is (p/V) phi to the 1.3 power = 0.62 e to the 2804/T power where p is the pressure in kPa, V is the velocity in m/e, phi is the equivalence ratio, and T is the temperature in K. The data scatter was considerable, varying by a maximum value of 5 at a given temperature and equivalence ratio. There was wide spread in the autoignition data contained in the references.

  8. Electrical heating tests of uranium dioxide external fuel configuration at emitter temperature of 1900 K

    NASA Technical Reports Server (NTRS)

    Diianni, D. C.; Mayer, J. T.

    1974-01-01

    Testing of two fuel clad specimens for thermionic reactor application is described. The annular UO2 fuel was clad on both sides with tungsten; heat rejection was radially inward. The tests were intended to study inner clad stability, fuel redistribution, and fuel melting problems. The specimens were tested in a vacuum chamber using electron bombardment heating. Fuel structural changes were studied using periodic gammagraphs and posttest metallography. The first specimen test was terminated at 50 hours because of a braze failure. The second specimen was tested for 240 hours when an outer clad leak developed due to a tungsten-water reaction. The fuel developed numerous cracks on cooldown but the inner clad remained dimensionally stable. The fuel cover gas did not impede the rate of fuel redistribution. Posttest examination showed the fuel had not melted during operation.

  9. Effects of outside storage on the energy potential of hardwood particulate fuels: part 1. Moisture content and temperature

    SciTech Connect

    White, M.S.; Curtis, M.L.; Sarles, R.L.; Green, D.W.

    1983-06-01

    Widespread use of woody materials for industrial fuels has generated interest and concern about the energy value of fuels stored outdoors. This paper reports on the effect of storage for periods up to 1 year on the temperature and moisture content (MC) of wood particulate fuels in cone-shaped piles according to the type of fuel and height of pile. Three fuels - hardwood whole-tree chips, bark, and sawdust - were stored in piles 10, 15, and 20 feet high. The experimental piles were built during the late summer of 1978 at the Union Camp woodyard in Ford, Virginia. Internal pile temperatures rose rapidly during the first weeks to highs of 45 degrees C for whole-tree chips and 73 degrees C for bark and sawdust. In the bark and chip piles these temperatures fluctuated seasonally. The interior temperature of the sawdust pile was insensitive to ambient temperature changes and declined slowly throughout the remainder of the study. Within the first 60 to 120 days of storage, the surfaces of all piles became saturated with moisture. The interior zones of the bark and sawdust piles remained at or slightly above the original MC while the corresponding regions of the chip pile exhibited some drying. After 1 year's time, the weighted average MCs of chips, bark, and sawdust increased by 84, 108, and 191 percent, respectively, over the original MCs. To minimize increases of MC in stored woody fuels, storage time should be kept to less than 60 days, chips should be preferred to bark and sawdust, and piles should be built as high as possible consistent with available space and storage procedures which limit the potential for spontaneous combustion.

  10. Study on the ignition of a fuel droplet in high temperature stagnant gas

    SciTech Connect

    Yoshizawa, Y.; Tomita, M.; Kawada, H.

    1981-07-01

    This study aimed to clarify the effects of the fuel vapor, which had evaporated in advance and formed combustible mixture around the condensed phase, on the ignition of a fuel droplet under the gas dynamic compression. A soap bubble was utilized to make a heterogeneously distributed fuel vapor pocket in oxidizer gas which offered a model of the vapor cloud around the fuel droplet. Induction periods for the onset of strong emission were measured for fuel droplets, and the models and their ignition processes were examined precisely by means of the interferometric measurement of the fuel concentration field.

  11. Fluoride-Salt-Cooled High-Temperature Reactor (FHR) with Silicon-Carbide-Matrix Coated-Particle Fuel

    SciTech Connect

    Forsberg, C. W.; Terrani, Kurt A; Snead, Lance Lewis; Katoh, Yutai

    2012-01-01

    The FHR is a new reactor concept that uses coated-particle fuel and a low-pressure liquid-salt coolant. Its neutronics are similar to a high-temperature gas-cooled reactor (HTGR). The power density is 5 to 10 times higher because of the superior cooling properties of liquids versus gases. The leading candidate coolant salt is a mixture of {sup 7}LiF and BeF{sub 2} (FLiBe) possessing a boiling point above 1300 C and the figure of merit {rho}C{sub p} (volumetric heat capacity) for the salt slightly superior to water. Studies are underway to define a near-term base-line concept while understanding longer-term options. Near-term options use graphite-matrix coated-particle fuel where the graphite is both a structural component and the primary neutron moderator. It is the same basic fuel used in HTGRs. The fuel can take several geometric forms with a pebble bed being the leading contender. Recent work on silicon-carbide-matrix (SiCm) coated-particle fuel may create a second longer-term fuel option. SiCm coated-particle fuels are currently being investigated for use in light-water reactors. The replacement of the graphite matrix with a SiCm creates a new family of fuels. The first motivation behind the effort is to take advantage of the superior radiation resistance of SiC compared to graphite in order to provide a stable matrix for hosting coated fuel particles. The second motivation is a much more rugged fuel under accident, repository, and other conditions.

  12. Powering a wireless temperature sensor using sediment microbial fuel cells with vertical arrangement of electrodes

    NASA Astrophysics Data System (ADS)

    Zhang, Fei; Tian, Lei; He, Zhen

    The application of wireless sensors is an important approach for monitoring natural water systems in remote locations; however, limited power sources are a key challenge for successful application of these sensors. Sediment microbial fuel cells (SMFCs) have shown potential as a sustainable power source with low maintenance requirements to power wireless sensors. This study examines electricity generation in lab-scale SMFCs with the sediment from Lake Michigan. Two SMFCs are operated in parallel with a difference in cathode arrangement (floating cathode vs. bottom cathode). The data show that the SMFC with a floating cathode produces more electricity and results in a shorter charging time when an ultracapacitor is connected to the circuit. To control electricity delivery and voltage elevation to a value that can drive a wireless temperature sensor, a power management system (PMS) is developed. With the PMS, both SMFCs can consistently power the wireless temperature sensor for data transmission to a computer, although the number of recorded data within the same period differs. This research provides an effective PMS for power control and valuable experience in SMFC configurations for the next onsite test of the developed SMFCs in Lake Michigan.

  13. Release of fuel-bound nitrogen in biomass during high temperature pyrolysis and gasification

    SciTech Connect

    Zhou, J.; Masutani, S.M.; Ishimura, D.M.; Turn, S.Q.; Kinoshita, C.M.

    1997-12-31

    Pyrolysis and gasification of two biomass feedstocks with significantly different fuel-bound nitrogen (FBN) content were investigated to determine the effect of operating conditions on the partitioning of FBN among gas species. Experiments were performed in a bench-scale, indirectly-heated, fluidized bed reactor. Data were obtained over a range of temperatures and equivalence ratios representative of commercial biomass gasification processes. An assay of all major nitrogenous components of the gasification products was performed for the first time, providing a clear accounting of the evolution of FBN. Results indicate that: (1) NH{sub 3} is the dominant nitrogenous gas species produced during pyrolysis of biomass; (2) the majority of FBN is converted to NH{sub 3} or N{sub 2} during gasification; relative levels of NH{sub 3} and N{sub 2} are determined by thermochemical reactions which are affected strongly by temperature; (3) N{sub 2} appears to be produced from NH{sub 3} in the gas phase.

  14. High performance catalyzed-reaction layer for medium temperature operating solid oxide fuel cells

    SciTech Connect

    Watanabe, M.; Uchida, H.; Shibata, M.; Mochizuki, N.; Amikura, K. . Lab. of Electrochemical Energy Conversion)

    1994-02-01

    New concepts for a high performance catalyzed-reaction layer for medium temperature operating solid oxide fuel cells were proposed. Mixed conducting oxide particles, samaria-doped ceria (SDC), were employed as the anode material utilizing highly dispersed noble metal catalysts on their surface. As the cathode material, Sr-doped LaMnO[sub 3] (LSM) particles catalyzed with microcrystalline Pt were employed. Performances of the anode or cathode were examined in the cell using yttria-stabilized zirconia electrolyte at a series of operating temperatures. It was found that the anodic polarization resistance and its activation energy were greatly decreased by loading only a small amount of the catalysts (such as Ru, Rh, and Pt) onto the SDC particles. The polarization loss at the anode showed a minimum value by using the SDC particles with a mean diameter of 1.5 to 2.0 [mu]m. A large depolarizing effect was also observed with a Pt-catalyzed LSM cathode, especially at high current densities.

  15. Mesoporous NiO-samaria doped ceria for low-temperature solid oxide fuel cells.

    PubMed

    Kim, Jin-Yeop; Kim, Ji Hyeon; Choi, Hyung Wook; Kim, Kyung Hwan; Park, Sang Joon

    2014-08-01

    In order to prepare anode material for low-temperature solid oxide fuel cells (SOFCs), the mesoporous NiO-SDC was synthesized using a cationic surfactant (cetyltrimethyl-ammonium bromide; CTAB) for obtaining wide triple-phase boundary (TPB). In addition, Ni-SDC anode-supported SOFC single cells with YSZ electrolyte and LSM cathode were fabricated and the performance of single cells was evaluated at 600 °C. The microstructure of NiO-SDC was characterized by XRD, EDX, SEM, and BET, and the results showed that the mesoporous NiO-SDC with 10 nm pores could be obtained. It was found that the surface area and the electrical performance were strongly influenced by the Ni content in Ni-SDC cermets. After calcined at 600 °C, the surface area of NiO-SDC was between 90-117 m2/g at 35-45 Ni wt%, which was sufficiently high for providing large TPB in SOFC anode. The optimum Ni content for cell performance was around 45 wt% and the corresponding MPD was 0.36 W/cm2. Indeed, the mesoporous NiO-SDC cermet may be of interest for use as an anode for low-temperature SOFCs. PMID:25936125

  16. Materials and characterization techniques for high-temperature polymer electrolyte membrane fuel cells

    PubMed Central

    2015-01-01

    Summary The performance of high-temperature polymer electrolyte membrane fuel cells (HT-PEMFC) is critically dependent on the selection of materials and optimization of individual components. A conventional high-temperature membrane electrode assembly (HT-MEA) primarily consists of a polybenzimidazole (PBI)-type membrane containing phosphoric acid and two gas diffusion electrodes (GDE), the anode and the cathode, attached to the two surfaces of the membrane. This review article provides a survey on the materials implemented in state-of-the-art HT-MEAs. These materials must meet extremely demanding requirements because of the severe operating conditions of HT-PEMFCs. They need to be electrochemically and thermally stable in highly acidic environment. The polymer membranes should exhibit high proton conductivity in low-hydration and even anhydrous states. Of special concern for phosphoric-acid-doped PBI-type membranes is the acid loss and management during operation. The slow oxygen reduction reaction in HT-PEMFCs remains a challenge. Phosphoric acid tends to adsorb onto the surface of the platinum catalyst and therefore hampers the reaction kinetics. Additionally, the binder material plays a key role in regulating the hydrophobicity and hydrophilicity of the catalyst layer. Subsequently, the binder controls the electrode–membrane interface that establishes the triple phase boundary between proton conductive electrolyte, electron conductive catalyst, and reactant gases. Moreover, the elevated operating temperatures promote carbon corrosion and therefore degrade the integrity of the catalyst support. These are only some examples how materials properties affect the stability and performance of HT-PEMFCs. For this reason, materials characterization techniques for HT-PEMFCs, either in situ or ex situ, are highly beneficial. Significant progress has recently been made in this field, which enables us to gain a better understanding of underlying processes occurring during

  17. Composite cathode materials development for intermediate temperature solid oxide fuel cell systems

    NASA Astrophysics Data System (ADS)

    Qin, Ya

    Solid oxide fuel cell (SOFC) systems are of particular interest as electrochemical power systems that can operate on various hydrocarbon fuels with high fuel-to-electrical energy conversion efficiency. Within the SOFC stack, La0.8Sr 0.2Ga0.8Mg0.115Co0.085O3-delta (LSGMC) has been reported as an optimized composition of lanthanum gallate based electrolytes to achieve higher oxygen ionic conductivity at intermediate temperatures, i.e., 500-700°C. The electrocatalytic properties of interfaces between LSGMC electrolytes and various candidate intermediate-temperature SOFC cathodes have been investigated. Sm0.5Sr0.5CoO 3-delta (SSC), and La0.6Sr0.4Co0.2Fe 0.8O3-delta (LSCF), in both pure and composite forms with LSGMC, were investigated with regards to both oxygen reduction and evolution, A range of composite cathode compositions, having ratios of SSC (in wt.%) with LSGMC (wt.%) spanning the compositions 9:1, 8:2, 7:3, 6:4 and 5:5, were investigated to determine the optimal cathode-electrolyte interface performance at intermediate temperatures. All LSGMC electrolyte and cathode powders were synthesized using the glycine-nitrate process (GNP). Symmetrical electrochemical cells were investigated with three-electrode linear dc polarization and ac impedance spectroscopy to characterize the kinetics of the interfacial reactions in detail. Composite cathodes were found to perform better than the single phase cathodes due to significantly reduced polarization resistances. Among those composite SSC-LSGMC cathodes, the 7:3 composition has demonstrated the highest current density at the equivalent overpotential values, indicating that 7:3 is an optimal mixing ratio of the composite cathode materials to achieve the best performance. For the composite SC-LSGMC cathode/LSGMC interface, the cathodic overpotential under 1 A/cm2 current density was as low as 0.085 V at 700°C, 0.062V at 750°C and 0.051V at 800°C in air. Composite LSCF-LSGMC cathode/LSGMC interfaces were found to have

  18. Application of Self-Propagating High Temperature Synthesis to the Fabrication of Actinide Bearing Nitride and Other Ceramic Nuclear Fuels

    SciTech Connect

    Moore, John J.; Reigel, Marissa M.; Donohoue, Collin D.

    2009-04-30

    The project uses an exothermic combustion synthesis reaction, termed self-propagating high-temperature synthesis (SHS), to produce high quality, reproducible nitride fuels and other ceramic type nuclear fuels (cercers and cermets, etc.) in conjunction with the fabrication of transmutation fuels. The major research objective of the project is determining the fundamental SHS processing parameters by first using manganese as a surrogate for americium to produce dense Zr-Mn-N ceramic compounds. These fundamental principles will then be transferred to the production of dense Zr-Am-N ceramic materials. A further research objective in the research program is generating fundamental SHS processing data to the synthesis of (i) Pu-Am-Zr-N and (ii) U-Pu-Am-N ceramic fuels. In this case, Ce will be used as the surrogate for Pu, Mn as the surrogate for Am, and depleted uranium as the surrogate for U. Once sufficient fundamental data has been determined for these surrogate systems, the information will be transferred to Idaho National Laboratory (INL) for synthesis of Zr-Am-N, Pu-Am-Zr-N and U-Pu-Am-N ceramic fuels. The high vapor pressures of americium (Am) and americium nitride (AmN) are cause for concern in producing nitride ceramic nuclear fuel that contains Am. Along with the problem of Am retention during the sintering phases of current processing methods, are additional concerns of producing a consistent product of desirable homogeneity, density and porosity. Similar difficulties have been experienced during the laboratory scale process development stage of producing metal alloys containing Am wherein compact powder sintering methods had to be abandoned. Therefore, there is an urgent need to develop a low-temperature or low–heat fuel fabrication process for the synthesis of Am-containing ceramic fuels. Self-propagating high temperature synthesis (SHS), also called combustion synthesis, offers such an alternative process for the synthesis of Am nitride fuels. Although SHS

  19. High Temperature Reactor (HTR) Deep Burn Core and Fuel Analysis: Design Selection for the Prismatic Block Reactor

    SciTech Connect

    Francesco Venneri; Chang-Keun Jo; Jae-Man Noh; Yonghee Kim; Claudio Filippone; Jonghwa Chang; Chris Hamilton; Young-Min Kim; Ji-Su Jun; Moon-Sung Cho; Hong-Sik Lim; MIchael A. Pope; Abderrafi M. Ougouag; Vincent Descotes; Brian Boer

    2010-09-01

    The Deep Burn (DB) Project is a U.S. Department of Energy sponsored feasibility study of Transuranic Management using high burnup fuel in the high temperature helium cooled reactor (HTR). The DB Project consists of seven tasks: project management, core and fuel analysis, spent fuel management, fuel cycle integration, TRU fuel modeling, TRU fuel qualification, and HTR fuel recycle. In the Phase II of the Project, we conducted nuclear analysis of TRU destruction/utilization in the HTR prismatic block design (Task 2.1), deep burn fuel/TRISO microanalysis (Task 2.3), and synergy with fast reactors (Task 4.2). The Task 2.1 covers the core physics design, thermo-hydraulic CFD analysis, and the thermofluid and safety analysis (low pressure conduction cooling, LPCC) of the HTR prismatic block design. The Task 2.3 covers the analysis of the structural behavior of TRISO fuel containing TRU at very high burnup level, i.e. exceeding 50% of FIMA. The Task 4.2 includes the self-cleaning HTR based on recycle of HTR-generated TRU in the same HTR. Chapter IV contains the design and analysis results of the 600MWth DB-HTR core physics with the cycle length, the average discharged burnup, heavy metal and plutonium consumptions, radial and axial power distributions, temperature reactivity coefficients. Also, it contains the analysis results of the 450MWth DB-HTR core physics and the analysis of the decay heat of a TRU loaded DB-HTR core. The evaluation of the hot spot fuel temperature of the fuel block in the DB-HTR (Deep-Burn High Temperature Reactor) core under full operating power conditions are described in Chapter V. The investigated designs are the 600MWth and 460MWth DB-HTRs. In Chapter VI, the thermo-fluid and safety of the 600MWth DB-HTRs has been analyzed to investigate a thermal-fluid design performance at the steady state and a passive safety performance during an LPCC event. Chapter VII describes the analysis results of the TRISO fuel microanalysis of the 600MWth and 450

  20. Combustion Characteristics and Performance of Low-Swirl Injectors with Natural Gas and Alternative Fuels At Elevated Pressures and Temperatures

    NASA Astrophysics Data System (ADS)

    Beerer, David Joseph

    Stationary power-generating gas turbines in the United States have historically been fueled with natural gas, but due to its increasing price and the need to reduce carbon emissions, interest in alternative fuels is increasing. In order to effectively operate engines with these fuels their combustion characteristics need be well understood, especially at elevated pressures and temperatures. In this dissertation, the performance of blends of natural gas / methane with hydrogen and carbon dioxide, to simulate syngas and biogas, are evaluated in a model low-swirl stabilized combustor inside an optically accessible high-pressure vessel. The flashback and lean blow out limits, along with pollutant emissions, flow field, and turbulent displacement flame speeds, are measured as a function of fuel composition, pressure, inlet temperature, firing temperature, and flow rate in the range from 1 to 8 atm, 294 to 600K, 1350 to 1950K, and 20 to 60 m/s, respectively. These properties are quantified as a function of the inlet parameters. The lean blow-out limits are independent of pressure and inlet temperature but are weakly dependent on velocity. NOX emissions for both fuels were found to be exponentially dependent upon firing temperature, but emissions for the high-hydrogen flames were consistently higher than those of natural gas flames. The flashback limits for a 90%/10% (by volume) hydrogen/methane mixture increase with velocity and inlet temperature, but decrease with pressure. Correspondingly, the flame position progresses toward the combustor nozzle with increasing pressure and flame temperature, but away with increasing inlet temperature and velocity. Flashback occurred when the leading edge of the flame entered the nozzle. Local displacement turbulent flame speeds scale linearly with the turbulent fluctuating velocities, u', at the leading edge of the flame. Turbulent flame speeds for high-hydrogen fuels are twice that of natural gas for the same inlet conditions. The

  1. Peak power ratio generator

    DOEpatents

    Moyer, R.D.

    A peak power ratio generator is described for measuring, in combination with a conventional power meter, the peak power level of extremely narrow pulses in the gigahertz radio frequency bands. The present invention in a preferred embodiment utilizes a tunnel diode and a back diode combination in a detector circuit as the only high speed elements. The high speed tunnel diode provides a bistable signal and serves as a memory device of the input pulses for the remaining, slower components. A hybrid digital and analog loop maintains the peak power level of a reference channel at a known amount. Thus, by measuring the average power levels of the reference signal and the source signal, the peak power level of the source signal can be determined.

  2. Peak power ratio generator

    DOEpatents

    Moyer, Robert D.

    1985-01-01

    A peak power ratio generator is described for measuring, in combination with a conventional power meter, the peak power level of extremely narrow pulses in the gigahertz radio frequency bands. The present invention in a preferred embodiment utilizes a tunnel diode and a back diode combination in a detector circuit as the only high speed elements. The high speed tunnel diode provides a bistable signal and serves as a memory device of the input pulses for the remaining, slower components. A hybrid digital and analog loop maintains the peak power level of a reference channel at a known amount. Thus, by measuring the average power levels of the reference signal and the source signal, the peak power level of the source signal can be determined.

  3. Peak Oil, Peak Coal and Climate Change

    NASA Astrophysics Data System (ADS)

    Murray, J. W.

    2009-05-01

    Research on future climate change is driven by the family of scenarios developed for the IPCC assessment reports. These scenarios create projections of future energy demand using different story lines consisting of government policies, population projections, and economic models. None of these scenarios consider resources to be limiting. In many of these scenarios oil production is still increasing to 2100. Resource limitation (in a geological sense) is a real possibility that needs more serious consideration. The concept of 'Peak Oil' has been discussed since M. King Hubbert proposed in 1956 that US oil production would peak in 1970. His prediction was accurate. This concept is about production rate not reserves. For many oil producing countries (and all OPEC countries) reserves are closely guarded state secrets and appear to be overstated. Claims that the reserves are 'proven' cannot be independently verified. Hubbert's Linearization Model can be used to predict when half the ultimate oil will be produced and what the ultimate total cumulative production (Qt) will be. US oil production can be used as an example. This conceptual model shows that 90% of the ultimate US oil production (Qt = 225 billion barrels) will have occurred by 2011. This approach can then be used to suggest that total global production will be about 2200 billion barrels and that the half way point will be reached by about 2010. This amount is about 5 to 7 times less than assumed by the IPCC scenarios. The decline of Non-OPEC oil production appears to have started in 2004. Of the OPEC countries, only Saudi Arabia may have spare capacity, but even that is uncertain, because of lack of data transparency. The concept of 'Peak Coal' is more controversial, but even the US National Academy Report in 2007 concluded only a small fraction of previously estimated reserves in the US are actually minable reserves and that US reserves should be reassessed using modern methods. British coal production can be

  4. Unrestrained swelling of uranium-nitride fuel irradiated at temperatures ranging from 1100 to 1400 K (1980 to 2520 R)

    NASA Technical Reports Server (NTRS)

    Rohal, R. G.; Tambling, T. N.

    1973-01-01

    Six fuel pins were assembled, encapsulated, and irradiated in the Plum Brook Reactor. The fuel pins employed uranium mononitride (UN) in a stainless steel (type 304L) clad. The pins were irradiated for approximately 4000 hours to burnups of about 2.0 atom percent uranium. The average clad surface temperature during irradiation was about 1100 K (1980 deg R). Since stainless steel has a very low creep strength relative to that of UN at this temperature, these tests simulated unrestrained swelling of UN. The tests indicated that at 1 percent uranium atom burnup the unrestrained diametrical swelling of UN is about 0.5, 0.8, and 1.0 percent at 1223, 1264, and 1306 K (2200, deg 2273 deg, and 2350 deg R), respectively. The tests also indicated that the irradiation induced swelling of unrestrained UN fuel pellets appears to be isotropic.

  5. Irradiation dose and temperature dependence of fracture toughness in high dose HT9 steel from the fuel duct of FFTF

    SciTech Connect

    Byun, Thak Sang; Toloczko, Mychailo B.; Saleh, Tarik A.; Maloy, Stuart A.

    2013-01-14

    To expand the knowledge base for fast reactor core materials, fracture toughness has been evaluated for high dose HT9 steel using miniature disk compact tension (DCT) specimens. The HT9 steel DCT specimens were machined from the ACO-3 fuel duct of the Fast Flux Test Facility (FFTF), which achieved high doses in the range of 3–148 dpa at 378–504 C. The static fracture resistance (J-R) tests have been performed in a servohydraulic testing machine in vacuum at selected temperatures including room temperature, 200 C, and each irradiation temperature. Brittle fracture with a low toughness less than 50 MPa pm occurred in room temperature tests when irradiation temperature was below 400 C, while ductile fracture with stable crack growth was observed when irradiation temperature was higher. No fracture toughness less than 100 MPa pm was measured when the irradiation temperature was above 430 C. It was shown that the influence of irradiation temperature was dominant in fracture toughness while the irradiation dose has only limited influence over the wide dose range 3–148 dpa. A slow decrease of fracture toughness with test temperature above room temperature was observed for the nonirradiated and high temperature (>430 *C) irradiation cases, which indicates that the ductile–brittle transition temperatures (DBTTs) in those conditions are lower than room temperature. A comparison with the collection of existing data confirmed the dominance of irradiation temperature in the fracture toughness of HT9 steels.

  6. 40 CFR 600.113-08 - Fuel economy calculations for FTP, HFET, US06, SC03 and cold temperature FTP tests.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 29 2010-07-01 2010-07-01 false Fuel economy calculations for FTP, HFET, US06, SC03 and cold temperature FTP tests. 600.113-08 Section 600.113-08 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) ENERGY POLICY FUEL ECONOMY AND CARBON-RELATED EXHAUST EMISSIONS OF MOTOR VEHICLES Fuel...

  7. Temperature effects on particulate emissions from DPF-equipped diesel trucks operating on conventional and biodiesel fuels

    EPA Science Inventory

    Two diesel trucks equipped with a particulate filter (DPF) were tested at two ambient temperatures (70oF and 20oF), fuels (ultra low sulfur diesel (ULSD) and biodiesel (B20)) and operating loads (a heavy and light weight). The test procedure included three driving cycles, a cold ...

  8. Perovskite Sr₁-xCexCoO₃-δ (0.05 ≤ x ≤ 0.15) as superior cathodes for intermediate temperature solid oxide fuel cells.

    PubMed

    Yang, Wei; Hong, Tao; Li, Shuai; Ma, Zhaohui; Sun, Chunwen; Xia, Changrong; Chen, Liquan

    2013-02-01

    Perovskite Sr(1-x)Ce(x)CoO(3-δ) (0.05 ≤ x ≤ 0.15) have been prepared by a sol-gel method and studied as cathodes for intermediate temperature solid oxide fuel cells. As SOFC cathodes, Sr(1-x)Ce(x)CoO(3-δ) materials have sufficiently high electronic conductivities and excellent chemical compatibility with SDC electrolyte. The peak power density of cells with Sr(0.95)Ce(0.05)CoO(3-δ) is 0.625 W cm(-2) at 700 °C. By forming a composite cathode with an oxygen ion conductor SDC, the peak power density of the cell with Sr(0.95)Ce(0.05)CoO(3-δ)-30 wt %SDC composite cathode, reaches 1.01 W cm(-2) at 700 °C, better than that of Sm(0.5)Sr(0.5)CoO(3)-based cathode. All these results demonstrates that Sr(1-x)Ce(x)CoO(3-δ) (0.05 ≤ x ≤ 0.15)-based materials are promising cathodes for an IT-SOFC. PMID:23336216

  9. Microstructural engineering of composite cathode systems for intermediate and low-temperature solid oxide fuel cells

    NASA Astrophysics Data System (ADS)

    Camaratta, Matthew

    Solid oxide fuel cells (SOFCs) are electrochemical devices with the potential to generate power at high efficiency with little environmental impact. However, in order to improve their commercial appeal, operating temperatures must be lowered from the 800-1000°C temperature range to 500-700°C and below. Due to the high bond strength of oxygen molecules, the kinetics of oxygen reduction are orders of magnitude slower than those of fuel oxidation. Consequently, much research in the reduced-temperature SOFC field is aimed at enhancing cathode performance. A composite cathode makes use of an electronic conducting phase as well as an ion conducting phase in order to spread the 3PB reaction zone beyond the cathode/electrolyte interface. Silver-stabilized bismuth oxide composite cathodes exhibit low resistance to oxygen reduction due to a combination of high catalytic activity for oxygen reduction of both phases, as well as high ionic conductivity of the bismuth oxide phase. Isothermal comparisons were made between pure silver cathodes, silver-yttrium stabilized bismuth oxide (YSB) cathodes, and silver-erbium stabilized bismuth oxides (ESB) at 650°C. The performance of all cathodes was shown to degrade with time. Cathode area specific resistance (ASR) of both the Ag-YSB and Ag-ESB electrodes increased by around 70%, while the pure Ag system experienced a near fourfold increase during the same length of time under open circuit conditions. In light of the electrochemical, microstructural, and chemical evidence presented, it was concluded that electrode microstructural evolution due to growth, agglomeration, and coalescence of the silver phase, rather than chemical reactivity of the bismuth oxide phase, was responsible for the observed degradation in electrochemical performance. Attempts were made to reduce the microstructural evolution of the silver phase in Ag-ESB20 composites by introduction of small particles (nano-size 8YSZ or vibratory-milled ESB20 particles) into

  10. The oxidation and hydriding of zircaloy fuel cladding in high temperature aqueous solutions

    NASA Astrophysics Data System (ADS)

    Chen, Yingzi

    Nearly 90% of today's fission reactors use Zr based fuel cladding materials. The Boiling Water Reactors (BWRs) and Pressurized Water Reactors (PWRs) are the two most common water-cooled nuclear reactors. Corrosion is the principal threat to the failure of the fuel in these reactors, resulting in the release of fission products to the coolant and hence to the establishment of radiation fields in out-of-core regions of the coolant circuit (e.g., steam generators in PWRs and turbines in BWRs). As is well known, corrosion is an electrochemical phenomenon; however, electrochemical effects are often neglected in corrosion studies on zirconium and its alloys, because of the difficulty in performing well-defined experiments under the appropriate conditions (high temperatures and pressures). In-situ studies have been carried out to examine the electrochemistry of passive zirconium under simulated BWR and PWR coolant conditions by using a controlled hydrodynamic, high temperature/high pressure test cell. The oxidation/hydriding mechanisms are elucidated by measuring the current, impedance, and capacitance of passive zirconium as a function of formation potential. The data are interpreted in terms of a modified point defect model (PDM) that recognize the existence of a passive film comprising a thick oxide outer layer over a thin barrier layer. From the composition of the zirconium passive film and thermodynamic analysis, it is postulated that a hydride barrier layer forms under PWR coolant conditions whereas an oxide barrier layer forms under BWR primary coolant conditions. Transients in current density and the thickness of the passive film formed on zirconium, when stepping the potential in either the positive or negative directions, have confirmed that the rate law afforded by the PDM adequately describes the growth and thinning of the passive film at high temperatures. The experimental results demonstrate that the kinetics of either oxygen or hydrogen vacancy generation

  11. High-temperature compatibility between liquid metal as PWR fuel gap filler and stainless steel and high-density concrete

    NASA Astrophysics Data System (ADS)

    Wongsawaeng, Doonyapong; Jumpee, Chayanit; Jitpukdee, Manit

    2014-08-01

    In conventional nuclear fuel rods for light-water reactors, a helium-filled as-fabricated gap between the fuel and the cladding inner surface accommodates fuel swelling and cladding creep down. Because helium exhibits a very low thermal conductivity, it results in a large temperature rise in the gap. Liquid metal (LM; 1/3 weight portion each of lead, tin, and bismuth) has been proposed to be a gap filler because of its high thermal conductivity (∼100 times that of He), low melting point (∼100 °C), and lack of chemical reactivity with UO2 and water. With the presence of LM, the temperature drop across the gap is virtually eliminated and the fuel is operated at a lower temperature at the same power output, resulting in safer fuel, delayed fission gas release and prevention of massive secondary hydriding. During normal reactor operation, should an LM-bonded fuel rod failure occurs resulting in a discharge of liquid metal into the bottom of the reactor pressure vessel, it should not corrode stainless steel. An experiment was conducted to confirm that at 315 °C, LM in contact with 304 stainless steel in the PWR water chemistry environment for up to 30 days resulted in no observable corrosion. Moreover, during a hypothetical core-melt accident assuming that the liquid metal with elevated temperature between 1000 and 1600 °C is spread on a high-density concrete basement of the power plant, a small-scale experiment was performed to demonstrate that the LM-concrete interaction at 1000 °C for as long as 12 h resulted in no penetration. At 1200 °C for 5 h, the LM penetrated a distance of ∼1.3 cm, but the penetration appeared to stop. At 1400 °C the penetration rate was ∼0.7 cm/h. At 1600 °C, the penetration rate was ∼17 cm/h. No corrosion based on chemical reactions with high-density concrete occurred, and, hence, the only physical interaction between high-temperature LM and high-density concrete was from tiny cracks generated from thermal stress. Moreover

  12. Comparative evaluation of pebble-bed and prismatic fueled high-temperature gas-cooled reactors

    SciTech Connect

    Kasten, P.R.; Bartine, D.E.

    1981-01-01

    A comparative evaluation has been performed of the HTGR and the Federal Republic of Germany's Pebble Bed Reactor (PBR) for potential commercial applications in the US. The evaluation considered two reactor sizes (1000 and 3000 MW(t)) and three process applications (steam cycle, direct cycle, and process heat, with outlet coolant temperatures of 750, 850, and 950/sup 0/C, respectively). The primary criterion for the comparison was the levelized (15-year) cost of producing electricity or process heat. Emphasis was placed on the cost impact of differences between the prismatic-type HTGR core, which requires periodic refuelings during reactor shutdowns, and the pebble bed PBR core, which is refueled continuously during reactor operations. Detailed studies of key technical issues using reference HTGR and PBR designs revealed that two cost components contributing to the levelized power costs are higher for the PBR: capital costs and operation and maintenance costs. A third cost component, associated with nonavailability penalties, tended to be higher for the PBR except for the process heat application, for which there is a large uncertainty in the HTGR nonavailability penalty at the 950/sup 0/C outlet coolant temperature. A fourth cost component, fuel cycle costs, is lower for the PBR, but not sufficiently lower to offset the capital cost component. Thus the HTGR appears to be slightly superior to the PBR in economic performance. Because of the advanced development of the HTGR concept, large HTGRs could also be commercialized in the US with lower R and D costs and shorter lead times than could large PBRs. It is recommended that the US gas-cooled thermal reactor program continue giving primary support to the HTGR, while also maintaining its cooperative PBR program with FRG.

  13. Ceria based inverse opals for thermochemical fuel production: Quantification and prediction of high temperature behavior

    NASA Astrophysics Data System (ADS)

    Casillas, Danielle Courtney

    Solar energy has the potential to supply more than enough energy to meet humanity's energy demands. Here, a method for thermochemical solar energy storage through fuel production is presented. A porous non-stoichiometric oxide, ceria, undergoes partial thermal reduction and oxidation with concentrated solar energy as a heat source, and water as an oxidant. The resulting yields for hydrogen fuel and oxygen are produced in two discrete steps, while the starting material maintains its original phase. Ordered porosity has been shown superior to random porosity for thermochemical fuel production applications, but stability limits for these structures are currently undefined. Ceria-based inverse opals are currently being investigated to assess the architectural influence on thermochemical hydrogen production. Low tortuosity and continuous interconnected pore network allow for facile gas transport and improved reaction kinetics. Ceria-based ordered materials have recently been shown to increase maximum hydrogen production over non-ordered porous ceria. Thermal stability of ordered porosity was quantified using quantitative image analysis. Fourier analysis was applied to SEM images of the material. The algorithm results in an order parameter gamma that describes the degree of long range order maintained by these structures, where gamma>4 signifies ordered porosity. According to this metric, a minimum zirconium content of 20 atomic percent (at%) is necessary for these architectures to survive aggressive annealing up to 1000°C. Zirconium substituted ceria (ZSC) with Zr loadings in excess of 20at% developed undesired tetragonal phases. Through gamma, we were able to find a balance between the benefit of zirconium additions on structural stability and its negative impact on phase. This work demonstrates the stability of seemingly delicate architectures, and the operational limit for ceria based inverse opals to be 1000°C for 1microm pore size. Inverse opals having sub

  14. Energetics of Intermediate Temperature Solid Oxide Fuel Cell Electrolytes: Singly and Doubly doped Ceria Systems

    NASA Astrophysics Data System (ADS)

    Buyukkilic, Salih

    Solid oxide fuel cells (SOFCs) have potential to convert chemical energy directly to electrical energy with high efficiency, with only water vapor as a by-product. However, the requirement of extremely high operating temperatures (~1000 °C) limits the use of SOFCs to only in large scale stationary applications. In order to make SOFCs a viable energy solution, enormous effort has been focused on lowering the operating temperatures below 700 °C. A low temperature operation would reduce manufacturing costs by slowing component degradation, lessening thermal mismatch problems, and sharply reducing costs of operation. In order to optimize SOFC applications, it is critical to understand the thermodynamic stabilities of electrolytes since they directly influence device stability, sustainability and performance. Rare-earth doped ceria electrolytes have emerged as promising materials for SOFC applications due to their high ionic conductivity at the intermediate temperatures (500--700 °C). However there is a fundamental lack of understanding regarding their structure, thermodynamic stability and properties. Therefore, the enthalpies of formation from constituent oxides and ionic conductivities were determined to investigate a relationship between the stability, composition, structural defects and ionic conductivity in rare earth doped ceria systems. For singly doped ceria electrolytes, we investigated the solid solution phase of bulk Ce1-xLnxO2-0.5x where Ln = Sm and Nd (0 ≤ x ≤ 0.30) and analyzed their enthalpies of formation, mixing and association, and bulk ionic conductivities while considering cation size mismatch and defect associations. It was shown that for ambient temperatures in the dilute dopant region, the positive heat of formation reaches a maximum as the system becomes increasingly less stable due to size mismatch. In concentrated region, stabilization to a certain solubility limit was observed probably due to the defect association of trivalent cations

  15. Neutronics assessment of stringer fuel assembly designs for the liquid-salt-cooled very high temperature reactor (LS-VHTR).

    SciTech Connect

    Szakaly, F. J.; Kim, T. K.; Taiwo, T. A.; Nuclear Engineering Division

    2007-01-01

    Neutronic studies of 18-pin and 36-pin stringer fuel assemblies have been performed to ascertain that core design requirements for the Liquid-Salt Cooled Very High Temperature Reactor (LS-VHTR) can be met. Parametric studies were performed to determine core characteristics required to achieve a target core cycle length of 18 months and fuel discharge burnup greater than 100 GWd/t under the constraint that the uranium enrichment be less than 20% in order to support non-proliferation goals. The studies were done using the WIMS9 lattice code and the linear reactivity model to estimate the core reactivity balance, fuel composition, and discharge burnup. The results show that the design goals can be met using a 1-batch fuel management scheme, uranium enrichment of 15% and a fuel packing fraction of 30% or greater for the 36-pin stringer fuel assembly design.Evaluations of a liquid-salt- (molten-salt-) cooled version of the prismatic-block type VHTR, the LS-VHTR, are ongoing at U.S. national laboratories, universities, and industry. These evaluations have included core and passive safety studies and balance of plant conceptual designs.

  16. Performance and degradation of high temperature polymer electrolyte fuel cell catalysts

    NASA Astrophysics Data System (ADS)

    Aricò, A. S.; Stassi, A.; Modica, E.; Ornelas, R.; Gatto, I.; Passalacqua, E.; Antonucci, V.

    An investigation of carbon-supported Pt/C and PtCo/C catalysts was carried out with the aim to evaluate their stability under high temperature polymer electrolyte membrane fuel cell (PEMFC) operation. Carbon-supported nanosized Pt and PtCo particles with a mean particle size between 1.5 nm and 3 nm were prepared by using a colloidal route. A suitable degree of alloying was obtained for the PtCo catalyst by using a carbothermal reduction. The catalyst stability was investigated to understand the influence of carbon black corrosion, platinum dissolution and sintering in gas-fed sulphuric acid electrolyte half-cell at 75 °C and in PEMFC at 130 °C. Electrochemical active surface area and catalyst performance were determined in PEMFC at 80 °C and 130 °C. A maximum power density of about 700 mW cm -2 at 130 °C and 3 bar abs. O 2 pressure with 0.3 mg Pt cm -2 loading was achieved. The PtCo alloy showed a better stability than Pt in sulphuric acid after cycling; yet, the PtCo/C catalyst showed a degradation after the carbon corrosion test. The PtCo/C catalyst showed smaller sintering effects than Pt/C after accelerated degradation tests in PEMFC at 130 °C.

  17. Temperature and Humidity Sensor Powered by an Individual Microbial Fuel Cell in a Power Management System.

    PubMed

    Zheng, Qi; Xiong, Lei; Mo, Bing; Lu, Weihong; Kim, Suki; Wang, Zhenyu

    2015-01-01

    Microbial fuel cells (MFCs) are of increasing interest as bioelectrochemical systems for decomposing organic materials and converting chemical energy into electricity. The main challenge for this technology is that the low power and voltage of the devices restricts the use of MFCs in practical applications. In this paper, a power management system (PMS) is developed to store the energy and export an increased voltage. The designed PMS successfully increases the low voltage generated by an individual MFC to a high potential of 5 V, capable of driving a wireless temperature and humidity sensor based on nRF24L01 data transmission modules. With the PMS, MFCs can intermittently power the sensor for data transmission to a remote receiver. It is concluded that even an individual MFC can supply the energy required to power the sensor and telemetry system with the designed PMS. The presented PMS can be widely used for unmanned environmental monitoring such as wild rivers, lakes, and adjacent water areas, and offers promise for further advances in MFC technology. PMID:26378546

  18. Temperature and Humidity Sensor Powered by an Individual Microbial Fuel Cell in a Power Management System

    PubMed Central

    Zheng, Qi; Xiong, Lei; Mo, Bing; Lu, Weihong; Kim, Suki; Wang, Zhenyu

    2015-01-01

    Microbial fuel cells (MFCs) are of increasing interest as bioelectrochemical systems for decomposing organic materials and converting chemical energy into electricity. The main challenge for this technology is that the low power and voltage of the devices restricts the use of MFCs in practical applications. In this paper, a power management system (PMS) is developed to store the energy and export an increased voltage. The designed PMS successfully increases the low voltage generated by an individual MFC to a high potential of 5 V, capable of driving a wireless temperature and humidity sensor based on nRF24L01 data transmission modules. With the PMS, MFCs can intermittently power the sensor for data transmission to a remote receiver. It is concluded that even an individual MFC can supply the energy required to power the sensor and telemetry system with the designed PMS. The presented PMS can be widely used for unmanned environmental monitoring such as wild rivers, lakes, and adjacent water areas, and offers promise for further advances in MFC technology. PMID:26378546

  19. Promising alloys for intermediate-temperature solid oxide fuel cell interconnect application

    NASA Astrophysics Data System (ADS)

    Geng, Shujiang; Zhu, Jiahong

    The formation of a low Cr-volatility and electrically conductive oxide outer layer atop an inner chromia layer via thermal oxidation is highly desirable for preventing chromium evaporation from solid oxide fuel cell (SOFC) metallic interconnects at the SOFC operation temperatures. In this paper, a number of ferritic Fe-22Cr alloys with different levels of Mn and Ti as well as a Ni-based alloy Haynes 242 were cyclically oxidized in air at 800 °C for twenty 100-h cycles. No oxide scale spallation was observed during thermal cycling for any of these alloys. A mixed Mn 2O 3/TiO 2 surface layer and/or a (Mn, Cr) 3O 4 spinel outer layer atop a Cr 2O 3 inner layer was formed for the Fe-22Cr series alloys, while an NiO outer layer with a Cr 2O 3 inner layer was developed for Haynes 242 after cyclic oxidation. For the Fe-22Cr series alloys, the effects of Mn and Ti contents as well as alloy purity on the oxidation resistance and scale area specific resistance were evaluated. The performance of the ferritic alloys was compared with that of Haynes 242. The mismatch in thermal expansion coefficient between the different layers in the oxide scale was identified as a potential concern for these otherwise promising alloys.

  20. Microbial fuel cells as power supply of a low-power temperature sensor

    NASA Astrophysics Data System (ADS)

    Khaled, Firas; Ondel, Olivier; Allard, Bruno

    2016-02-01

    Microbial fuel cells (MFCs) show great promise as a concomitant process for water treatment and as renewable energy sources for environmental sensors. The small energy produced by MFCs and the low output voltage limit the applications of MFCs. Specific converter topologies are required to step-up the output voltage of a MFC. A Power Management Unit (PMU) is proposed for operation at low input voltage and at very low power in a completely autonomous way to capture energy from MFCs with the highest possible efficiency. The application of sensors for monitoring systems in remote locations is an important approach. MFCs could be an alternative energy source in this case. Powering a sensor with MFCs may prove the fact that wastewater may be partly turned into renewable energy for realistic applications. The Power Management Unit is demonstrated for 3.6 V output voltage at 1 mW continuous power, based on a low-cost 0.7-L MFC. A temperature sensor may operate continuously on 2-MFCs in continuous flow mode. A flyback converter under discontinuous conduction mode is also tested to power the sensor. One continuously fed MFC was able to efficiently and continuously power the sensor.

  1. Low temperature combustion using nitrogen enrichment to mitigate NOx from large bore natural gas fueled engines.

    SciTech Connect

    Biruduganti, M.; Gupta, S.; Sekar, R.; Energy Systems

    2010-01-01

    Low temperature combustion is identified as one of the pathways to meet the mandatory ultra low NO{sub x} emissions levels set by the regulatory agencies. Exhaust gas recirculation (EGR) is a well known technique to realize low NO{sub x} emissions. However, EGR has many built-in adverse ramifications that negate its advantages in the long term. This paper discusses nitrogen enrichment of intake air using air separation membranes as a better alternative to the mature EGR technique. This investigation was undertaken to determine the maximum acceptable level of nitrogen enrichment of air for a single-cylinder spark-ignited natural gas engine. NO{sub x} reduction as high as 70% was realized with a modest 2% nitrogen enrichment while maintaining power density and simultaneously improving fuel conversion efficiency (FCE). Any enrichment beyond this level degraded engine performance in terms of power density, FCE, and unburned hydrocarbon emissions. The effect of ignition timing was also studied with and without N{sub 2} enrichment. Finally, lean burn versus stoichiometric operation utilizing nitrogen enrichment was compared. Analysis showed that lean burn operation along with nitrogen enrichment is one of the effective pathways for realizing better FCE and lower NO{sub x} emissions.

  2. Tailpipe emissions from gasoline direct injection (GDI) and port fuel injection (PFI) vehicles at both low and high ambient temperatures.

    PubMed

    Zhu, Rencheng; Hu, Jingnan; Bao, Xiaofeng; He, Liqiang; Lai, Yitu; Zu, Lei; Li, Yufei; Su, Sheng

    2016-09-01

    Vehicle emissions are greatly influenced by various factors that are related to engine technology and driving conditions. Only the fuel injection method and ambient temperature are investigated in this research. Regulated gaseous and particulate matter (PM) emissions from two advanced gasoline-fueled vehicles, one with direct fuel injection (GDI) and the other with port fuel injection (PFI), are tested with conventional gasoline and ethanol-blended gasoline (E10) at both -7 °C and 30 °C. The total particle number (PN) concentrations and size distributions are monitored with an Electrical Low Pressure Impactor (ELPI(+)). The solid PN concentrations are measured with a condensation particle counter (CPC) after removing volatile matters through the particle measurement program (PMP) system. The results indicate that decreasing the ambient temperature from 30 °C to -7 °C significantly increases the fuel consumption and all measured emissions except for NOx. The GDI vehicle exhibits lower fuel consumption than the PFI vehicle but emits more total hydrocarbons (THC), PM mass and solid PN emissions at 30 °C. The adaptability of GDI technology appears to be better than that of PFI technology at low ambient temperature. For example, the CO, THC and PM mass emission factors of the PFI vehicle are higher than those of the GDI vehicle and the solid PN emission factors are comparable in the cold-start tests at -7 °C. Specifically, during start-up the particulate matter emissions of the PFI are much higher than the GDI. In most cases, the geometric mean diameter (GMD) of the accumulation mode particles is 58-86 nm for both vehicles, and the GMD of the nucleation mode particles is 10-20 nm. The results suggest that the gaseous and particulate emissions from the PFI vehicle should not be neglected compared to those from the GDI vehicle especially in a cold environment. PMID:27267738

  3. Make peak flow a habit!

    MedlinePlus

    Asthma - make peak flow a habit; Reactive airway disease - peak flow; Bronchial asthma - peak flow ... your airways are narrowed and blocked due to asthma, your peak flow values drop. You can check ...

  4. Design and Development of Highly Sulfonated Polymers as Proton Exchange Membranes for High Temperature Fuel Cell Applications

    NASA Astrophysics Data System (ADS)

    Dang, Thuy D.; Bai, Zongwu; Yoonessi, Mitra

    A series of high molecular weight, highly sulfonated poly(arylenethioethersulfone) (SPTES) polymers were synthesized by polycondensation, which allowed controlled sulfonation of up to 100 mol %. The SPTES polymers were prepared via step growth polymerization of sulfonated aromatic difluorosulfone, aromatic difluorosulfone, and 4,4 '-thiobisbenzenthiol in sulfolane solvent at the temperature up to 180 °C. The composition and incorporation of the sulfonated repeat unit into the polymers were confirmed by 1H nuclear magnetic resonance (NMR) and Fourier transform infrared (FTIR) spectroscopy. Solubility tests on the SPTES polymers confirmed that no cross-linking and probably no branching occurred during the polymerizations. The end-capping groups were introduced in the SPTES polymers to control the molecular weight distribution and reduce the water solubility of the polymers. Tough, ductile membranes formed via solvent-casting exhibited increased water absorption with increasing degrees of sulfonation. The polymerizations conducted with the introduction of end-capping groups resulted in a wide variation in polymer proton conductivity, which spanned a range of 100 -300 mS cm-1, measured at 65 °C and 85 % relative humidity. The measured proton conductivities at elevated temperatures and high relative humidities are up to three times higher than that of the state-of-the-art Nafion-H proton exchange membrane under nearly comparable conditions. The thermal and mechanical properties of the SPTES polymers were investigated by TGA, DMA, and tensile measurements. The SPTES polymers show high glass transition temperatures (Tg), ˜220 °C, depending on the degree of sulfonation in polymerization. SPTES-50 polymer shows a Tg of 223 °C, with high tensile modulus, high tensile strengths at break and at yield as well as elongation at break. Wide angle X-ray scattering of the polymers shows two broad scattering features centered at 4.5 Å and 3.3 Å, the latter peak being

  5. Hale Central Peak

    NASA Technical Reports Server (NTRS)

    2004-01-01

    19 September 2004 This Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) image shows some of the mountains that make up the central peak region of Hale Crater, located near 35.8oS, 36.5oW. Dark, smooth-surfaced sand dunes are seen to be climbing up the mountainous slopes. The central peak of a crater consists of rock brought up during the impact from below the crater floor. This autumn image is illuminated from the upper left and covers an area approximately 3 km (1.9 mi) across.

  6. Comparison of HYDRA predictions to temperature data from two single-assembly spent fuel heat transfer tests

    SciTech Connect

    McCann, R.A.

    1986-12-01

    The HYDRA computer code was used to simulate the thermal performance of an actual and a model spent fuel assembly. The HYDRA-predicted temperatures were then compared with measured data from two single-assembly test sections. The objective of this effort was to further verify the predictive capabilities of the HYDRA code for use in assessments of the hydrothermal performance of spent fuel dry storage systems. After HYDRA has been adequately evaluated and validated, the code will be documented to permit design and licensing safety analyses.

  7. Surface characterization of palladium-alumina sorbents for high-temperature capture of mercury and arsenic from fuel gas

    SciTech Connect

    John P. Baltrus; Evan J. Granite; , Henry W. Pennline; Dennis Stanko; Hugh Hamilton; Liz Rowsell; Stephen Poulston; Andrew Smith; Wilson Chu

    2010-06-01

    Coal gasification with subsequent cleanup of the resulting fuel gas is a way to reduce the impact of mercury and arsenic in the environment during power generation and on downstream catalytic processes in chemical production. The interactions of mercury and arsenic with Pd/Al2O3 model thin film sorbents and Pd/Al2O3 powders have been studied to determine the relative affinities of palladium for mercury and arsenic, and how they are affected by temperature and the presence of hydrogen sulfide in the fuel gas. The implications of the results on strategies for capturing the toxic metals using a sorbent bed are discussed.

  8. Surface characterizatin of palladium-alumina sorbents for high-temperature capture of mercury and arsenic from fuel gas

    SciTech Connect

    Baltrus, J.P.; Granite, E.J.; Pennline, H.W.; Stanko, D.; Hamilton, H.; Rowsell, L.; Poulston, S.; Smith, A.; Chu, W.

    2010-01-01

    Coal gasification with subsequent cleanup of the resulting fuel gas is a way to reduce the impact of mercury and arsenic in the environment during power generation and on downstream catalytic processes in chemical production, The interactions of mercury and arsenic with PdlAl2D3 model thin film sorbents and PdlAh03 powders have been studied to determine the relative affinities of palladium for mercury and arsenic, and how they are affected by temperature and the presence of hydrogen sulfide in the fuel gas. The implications of the results on strategies for capturing the toxic metals using a sorbent bed are discussed.

  9. High-speed mixture fraction and temperature imaging of pulsed, turbulent fuel jets auto-igniting in high-temperature, vitiated co-flows

    NASA Astrophysics Data System (ADS)

    Papageorge, Michael J.; Arndt, Christoph; Fuest, Frederik; Meier, Wolfgang; Sutton, Jeffrey A.

    2014-07-01

    In this manuscript, we describe an experimental approach to simultaneously measure high-speed image sequences of the mixture fraction and temperature fields during pulsed, turbulent fuel injection into a high-temperature, co-flowing, and vitiated oxidizer stream. The quantitative mixture fraction and temperature measurements are determined from 10-kHz-rate planar Rayleigh scattering and a robust data processing methodology which is accurate from fuel injection to the onset of auto-ignition. In addition, the data processing is shown to yield accurate temperature measurements following ignition to observe the initial evolution of the "burning" temperature field. High-speed OH* chemiluminescence (CL) was used to determine the spatial location of the initial auto-ignition kernel. In order to ensure that the ignition kernel formed inside of the Rayleigh scattering laser light sheet, OH* CL was observed in two viewing planes, one near-parallel to the laser sheet and one perpendicular to the laser sheet. The high-speed laser measurements are enabled through the use of the unique high-energy pulse burst laser system which generates long-duration bursts of ultra-high pulse energies at 532 nm (>1 J) suitable for planar Rayleigh scattering imaging. A particular focus of this study was to characterize the fidelity of the measurements both in the context of the precision and accuracy, which includes facility operating and boundary conditions and measurement of signal-to-noise ratio (SNR). The mixture fraction and temperature fields deduced from the high-speed planar Rayleigh scattering measurements exhibited SNR values greater than 100 at temperatures exceeding 1,300 K. The accuracy of the measurements was determined by comparing the current mixture fraction results to that of "cold", isothermal, non-reacting jets. All profiles, when properly normalized, exhibited self-similarity and collapsed upon one another. Finally, example mixture fraction, temperature, and OH* emission

  10. Cross spectra between pressure and temperature in a constant-area duct downstream of a hydrogen-fueled combustor

    NASA Technical Reports Server (NTRS)

    Miles, J. H.; Wasserbauer, C. A.; Krejsa, E. A.

    1983-01-01

    Pressure temperature cross spectra are necessary in predicting noise propagation in regions of velocity gradients downstream of combustors if the effect of convective entropy disturbances is included. Pressure temperature cross spectra and coherences were measured at spatially separated points in a combustion rig fueled with hydrogen. Temperature-temperature and pressure-pressure cross spectra and coherences between the spatially separated points as well as temperature and pressure autospectra were measured. These test results were compared with previous results obtained in the same combustion rig using Jet A fuel in order to investigate their dependence on the type of combustion process. The phase relationships are not consistent with a simple source model that assumes that pressure and temperature are in phase at a point in the combustor and at all other points downstream are related to one another by only a time delay due to convection of temperature disturbances. Thus these test results indicate that a more complex model of the source is required.

  11. Fuel Rod Melt Progression Simulation Using Low-Temperature Melting Metal Alloy

    SciTech Connect

    Seung Dong Lee; Suh, Kune Y.; GoonCherl Park; Un Chul Lee

    2002-07-01

    The TMI-2 accident and various severe fuel damage experiments have shown that core damage is likely to proceed through various states before the core slumps into the lower head. Numerous experiments were conducted to address when and how the core can lose its original geometry, what geometries are formed, and in what processes the core materials are transported to the lower plenum of the reactor pressure vessel. Core degradation progresses along the line of clad ballooning, clad oxidation, material interaction, metallic blockage, molten pool formation, melt progression, and relocation to the lower head. Relocation into the lower plenum may occur from the lateral periphery or from the bottom of the core depending upon the thermal and physical states of the pool. Determining the quantities and rate of molten material transfer to the lower head is important since significant amounts of molten material relocated to the lower head can threaten the vessel integrity by steam explosion and thermal and mechanical attack of the melt. In this paper the focus is placed on the melt flow regime on a cylindrical fuel rod utilizing the LAMDA (Lumped Analysis of Melting in Degrading Assemblies) facility at the Seoul National University. The downward relocation of the molten material is a combination of the external film flow and the internal pipe flow. The heater rods are 0.8 m long and are coated by a low-temperature melting metal alloy. The electrical internal heating method is employed during the test. External heating is adopted to simulate the exothermic Zircaloy-steam reaction. Tests are conducted in several quasi-steady-state conditions. Given the variable boundary conditions including the heat flux and the water level, observation is made for the melting location, progression, and the mass of molten material. Finally, the core melt progression model is developed from the visual inspection and quantitative analysis of the experimental data. As the core material relocates

  12. Safeguards-by-Design: Guidance for High Temperature Gas Reactors (HTGRs) With Pebble Fuel

    SciTech Connect

    Philip Casey Durst; Mark Schanfein

    2012-08-01

    The following is a guidance document from a series prepared for the U.S. Department of Energy (DOE) National Nuclear Security Administration (NNSA), under the Next Generation Safeguards Initiative (NGSI), to assist facility designers and operators in implementing international Safeguards-by-Design (SBD). SBD has two main objectives: (1) to avoid costly and time consuming redesign work or retrofits of new nuclear fuel cycle facilities and (2) to make the implementation of international safeguards more effective and efficient at such facilities. In the long term, the attainment of these goals would save industry and the International Atomic Energy Agency (IAEA) time, money, and resources and be mutually beneficial. This particular safeguards guidance document focuses on pebble fuel high temperature gas reactors (HTGR). The purpose of the IAEA safeguards system is to provide credible assurance to the international community that nuclear material and other specified items are not diverted from peaceful nuclear uses. The safeguards system consists of the IAEA’s statutory authority to establish safeguards; safeguards rights and obligations in safeguards agreements and additional protocols; and technical measures implemented pursuant to those agreements. Of foremost importance is the international safeguards agreement between the country and the IAEA, concluded pursuant to the Treaty on the Non-Proliferation of Nuclear Weapons (NPT). According to a 1992 IAEA Board of Governors decision, countries must: notify the IAEA of a decision to construct a new nuclear facility as soon as such decision is taken; provide design information on such facilities as the designs develop; and provide detailed design information based on construction plans at least 180 days prior to the start of construction, and on "as-built" designs at least 180 days before the first receipt of nuclear material. Ultimately, the design information will be captured in an IAEA Design Information

  13. Development of Metal Oxide Nanostructure-based Optical Sensors for Fossil Fuel Derived Gases Measurement at High Temperature

    SciTech Connect

    Chen, Kevin

    2014-08-31

    operation temperature up to 750oC, first distributed chemical measurements at the record high temperature up to 700oC, first distributed pressure measurement at the record high temperature up to 800oC, and the fiber laser sensors with the record high operation temperature up to 700oC. The research performed by this program dramatically expand the functionality, adaptability, and applicability of distributed fiber optical sensors with potential applications in a number of high-temperature energy systems such as fossil-fuel power generation, high-temperature fuel cell applications, and potential for nuclear energy systems.

  14. Impact Crater with Peak

    NASA Technical Reports Server (NTRS)

    2002-01-01

    (Released 14 June 2002) The Science This THEMIS visible image shows a classic example of a martian impact crater with a central peak. Central peaks are common in large, fresh craters on both Mars and the Moon. This peak formed during the extremely high-energy impact cratering event. In many martian craters the central peak has been either eroded or buried by later sedimentary processes, so the presence of a peak in this crater indicates that the crater is relatively young and has experienced little degradation. Observations of large craters on the Earth and the Moon, as well as computer modeling of the impact process, show that the central peak contains material brought from deep beneath the surface. The material exposed in these peaks will provide an excellent opportunity to study the composition of the martian interior using THEMIS multi-spectral infrared observations. The ejecta material around the crater can is well preserved, again indicating relatively little modification of this landform since its initial creation. The inner walls of this approximately 18 km diameter crater show complex slumping that likely occurred during the impact event. Since that time there has been some downslope movement of material to form the small chutes and gullies that can be seen on the inner crater wall. Small (50-100 m) mega-ripples composed of mobile material can be seen on the floor of the crater. Much of this material may have come from the walls of the crater itself, or may have been blown into the crater by the wind. The Story When a meteor smacked into the surface of Mars with extremely high energy, pow! Not only did it punch an 11-mile-wide crater in the smoother terrain, it created a central peak in the middle of the crater. This peak forms kind of on the 'rebound.' You can see this same effect if you drop a single drop of milk into a glass of milk. With craters, in the heat and fury of the impact, some of the land material can even liquefy. Central peaks like the one

  15. Analytical evaluation of effect of equivalence ratio inlet-air temperature and combustion pressure on performance of several possible ram-jet fuels

    NASA Technical Reports Server (NTRS)

    Tower, Leonard K; Gammon, Benson E

    1953-01-01

    The results of an analytical investigation of the theoretical air specific impulse performance and adiabatic combustion temperatures of several possible ram-jet fuels over a range of equivalence ratios, inlet-air temperatures, and combustion pressures, is presented herein. The fuels include octane-1, 50-percent-magnesium slurry, boron, pentaborane, diborane, hydrogen, carbon, and aluminum. Thermal effects from high combustion temperatures were found to effect considerably the combustion performance of all the fuels. An increase in combustion pressure was beneficial to air specific impulse at high combustion temperatures. The use of these theoretical data in engine operation and in the evaluation of experimental data is described.

  16. Reaching peak emissions

    NASA Astrophysics Data System (ADS)

    Jackson, Robert B.; Canadell, Josep G.; Le Quéré, Corinne; Andrew, Robbie M.; Korsbakken, Jan Ivar; Peters, Glen P.; Nakicenovic, Nebojsa

    2016-01-01

    Rapid growth in global CO2 emissions from fossil fuels and industry ceased in the past two years, despite continued economic growth. Decreased coal use in China was largely responsible, coupled with slower global growth in petroleum and faster growth in renewables.

  17. Optimum Reflector Configurations for Minimizing Fission Power Peaking in a Lithium-Cooled, Liquid-Metal Reactor with Sliding Reflectors

    SciTech Connect

    Fensin, Michael L.; Poston, David I.

    2005-02-06

    Many design constraints limit the development of a space fission power system optimized for fuel performance, system reliability, and mission cost. These design constraints include fuel mass provisions to meet cycle-length requirements, fuel centerline and clad temperatures, and clad creep from fission gas generation. Decreasing the fission power peaking of the reactor system enhances all of the mentioned parameters. This design study identifies the cause, determines the reflector configurations for reactor criticality, and generates worth curves for minimized fission-power-peaking configuration in a lithium-cooled liquid-metal reactor that uses sliding reflectors. Because of the characteristics of the core axial power distribution and axial power distortions inherent to the sliding reflector design, minimizing the power peaking of the reactor involves placing the reflectors in a position that least distorts the axial power distribution. The views expressed in this document are those of the author and do not necessarily reflect agreement by the Government.

  18. Effect of fuel/air nonuniformity on nitric oxide emissions

    NASA Technical Reports Server (NTRS)

    Lyons, V. J.

    1979-01-01

    A flame tube combustor holding jet A fuel was used in experiments performed at a pressure of .3 Mpa and a reference velocity of 25 meters/second for three inlet air temperatures of 600, 700, and 800 K. The gas sample measurements were taken at locations 18 cm and 48 cm downstream of the perforated plate flameholder. Nonuniform fuel/air profiles were produced using a fuel injector by separately fueling the inner five fuel tubes and the outer ring of twelve fuel tubes. Six fuel/air profiles were produced for nominal overall equivalence ratios of .5 and .6. An example of three of three of these profiles and their resultant nitric oxide NOx emissions are presented. The uniform fuel/air profile cases produced uniform and relatively low profile levels. When the profiles were either center-peaked or edge-peaked, the overall mass-weighted nitric oxide levels increased.

  19. The single cell of low temperature solid oxide fuel cell with sodium carbonate-SDC (samarium-doped ceria) as electrolyte and biodiesel as fuel

    NASA Astrophysics Data System (ADS)

    Rahmawati, F.; Nuryanto, A.; Nugrahaningtyas, K. D.

    2016-02-01

    In this research NSDC (composite of Na2CO3-SDC) was prepared by the sol-gel method to produce NSDC1 and also by the ceramic method to produce NSDC2. The prepared NSDC then were analyzed by XRD embedded with Le Bail refinement to study the change of characteristic peaks, their crystal structure, and their cell parameters. Meanwhile, the measurement of impedance was conducted to study the electrical conductivity of the prepared materials. A single cell was prepared by coating NSDC-L (a composite of NSDC with Li0.2Ni0.7Cu0.1O2) on both surfaces of NSDC. The NSDC-L was used as anode and cathode. The ionic conductivity of NSDC1 and NSDC2 at 400 oC are 4.1109 x 10-2 S.cm-1 and 1.6231 x 10-2 S.cm-1, respectively. Both electrolytes have ionic conductivity higher than 1 x 10-4 S.cm-1, therefore, can be categorized as good electrolyte [1]. However, the NSDC1 shows electrodeelectrolyte conduction. It indicates the existence of electronic migration from electrolyte- electrode or vice versa. Those may cause a short circuit during fuel cell operation and will reduce the fuel cell performance fastly. The single cell tests were conducted at 300, 400, 500 and 600 °C. The single fuel cell with NSDC1 and NSDC2 as electrolyte show maximum power density at 400 °C with the power density of 3.736 x 10-2 mW.cm-2 and 2.245 x 10-2 mW.cm-2, respectively.

  20. Analysis of overall heat balance in self-heated proton-exchange-membrane fuel cells for temperature predictions

    NASA Astrophysics Data System (ADS)

    Koh, Joon-Ho; Hsu, Andrew T.; Akay, Hasan U.; Liou, May-Fun

    The effect of self-heating and cooling by natural convection on a sustainable temperature of PEM fuel cell stacks was studied. Overall mass and heat balance equations are combined to predict self-heated temperatures at various operating conditions. Analyses show that the effect of a heat loss coefficient is more important than other variables such as air flow rate and surrounding temperature. The stack design variables such as active cell area and number of cells also have significant influence on self-controlled temperature. A lower Ohmic resistance of cells is expected to allow a wider range of current load applications. The proposed model can also be used to evaluate heat loss coefficient from measured stack performance and temperature data. Experiments performed on a seven-cell stack of 50 cm 2 active area were used to provide data for the validation of the model.

  1. The Effect of Fuel Consumption on Cylinder Temperatures and Performance of a Cowled Wright J-5 Engine

    NASA Technical Reports Server (NTRS)

    Schey, Oscar W

    1929-01-01

    Given here are the results of tests made to determine the effect of fuel consumption on the cylinder temperatures and the performance of a cowled Wright J-5 engine. The results of these tests indicate that enriching the mixture by increasing the carburetor size results in a reduction in cylinder head and barrel temperatures. The cylinders shielded by the magnetos or the points on the cylinder that do not receive a free flow of cooling air increase most rapidly in temperature as the mixture is leaned. A free flow of air past the cylinders is essential for satisfactory operation on a lean mixture. The results of these tests show that the Wright J-5 engine can withstand severe temperatures for short periods of operation. The test results also show to what extent destructive temperatures may be avoided by enriching the mixture.

  2. Temperature-based on-column solute focusing in capillary liquid chromatography reduces peak broadening from precolumn dispersion and volume overload when used alone or with solvent-based focusing

    PubMed Central

    Groskreutz, Stephen R.; Horner, Anthony R.; Weber, Stephen G.

    2015-01-01

    On-column focusing is essential for satisfactory performance using capillary scale columns. On-column focusing results from generating transient conditions at the head of the column that lead to high solute retention. Solvent-based on-column focusing is a well-known approach to achieve this. Temperature-assisted on-column focusing (TASF) can also be effective. TASF improves focusing by cooling a short segment of the column inlet to a temperature that is lower than the column temperature during the injection and then rapidly heating the focusing segment to the match the column temperature. A troublesome feature of an earlier implementation of TASF was the need to leave the capillary column unpacked in that portion of the column inside the fitting connecting it to the injection valve. We have overcome that problem in this work by packing the head of the column with solid silica spheres. In addition, technical improvements to the TASF instrumentation include: selection of a more powerful thermo-electric cooler to create faster temperature changes and electronic control for easy incorporation into conventional capillary instruments. Used in conjunction with solvent-based focusing and with isocratic elution, volumes of paraben samples (esters of p-hydroxybenzoic acid) up to 4.5-times the column liquid volume can be injected without significant bandspreading due to volume overload. Interestingly, the shapes of the peaks from the lowest volume injections that we can make, 30 nL, are improved when using TASF. TASF is very effective at reducing the detrimental effects of precolumn dispersion using isocratic elution. Finally, we show that TASF can be used to focus the neuropeptide galanin in a sample solvent with elution strength stronger than the mobile phase. Here, the stronger solvent is necessitated by the need to prevent peptide adsorption prior to and during analysis. PMID:26091787

  3. Low-temperature Flow Properties of Biodiesel/Jet Fuel (BioJet) Blends

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Biodiesel is a renewable fuel that is made from transesterification of vegetable oil, animal fat or other lipid feedstocks with a simple alcohol such as methanol. Biodiesel may be blended with jet fuel (JP-8) to reduce dependence on petroleum imports and improve ground-level emissions. Biodiesel i...

  4. Modeling of Two-Phase Flow and Heat Transfer in Low-Temperature Oxygen-Fuel Spray Process

    NASA Astrophysics Data System (ADS)

    Shan, Y. G.; Shen, C. H.; Jia, L. B.; Mostaghimi, J.

    2014-01-01

    The low-temperature oxygen-fuel (LTOF) spray is a modification of high velocity oxygen fuel spray. In this process, the high-temperature gas is accelerated to supersonic speed through a Laval nozzle followed by a straight barrel. By injecting room temperature gas into the mixing chamber, the temperature of the gas can be controlled in a range of about 1000-2500 K, so that some oxygen and temperature-sensitive materials, such as titanium and copper, can avoid oxidation or decomposition during the spraying process. The purpose of this paper is to establish a 2-D mathematical model to simulate the supersonic gas dynamics and particles behavior in LTOF process. The temperature and velocity of the flow fields, and the trajectory and heating of in-flight particles are predicted for different operating parameters. The model is validated by experimental data in the literature. Effects of the mixing gas flow rates, particle sizes, and injection conditions on this process were investigated as well.

  5. Predicting Peak Flows following Forest Fires

    NASA Astrophysics Data System (ADS)

    Elliot, William J.; Miller, Mary Ellen; Dobre, Mariana

    2016-04-01

    Following forest fires, peak flows in perennial and ephemeral streams often increase by a factor of 10 or more. This increase in peak flow rate may overwhelm existing downstream structures, such as road culverts, causing serious damage to road fills at stream crossings. In order to predict peak flow rates following wildfires, we have applied two different tools. One is based on the U.S.D.A Natural Resource Conservation Service Curve Number Method (CN), and the other is by applying the Water Erosion Prediction Project (WEPP) to the watershed. In our presentation, we will describe the science behind the two methods, and present the main variables for each model. We will then provide an example of a comparison of the two methods to a fire-prone watershed upstream of the City of Flagstaff, Arizona, USA, where a fire spread model was applied for current fuel loads, and for likely fuel loads following a fuel reduction treatment. When applying the curve number method, determining the time to peak flow can be problematic for low severity fires because the runoff flow paths are both surface and through shallow lateral flow. The WEPP watershed version incorporates shallow lateral flow into stream channels. However, the version of the WEPP model that was used for this study did not have channel routing capabilities, but rather relied on regression relationships to estimate peak flows from individual hillslope polygon peak runoff rates. We found that the two methods gave similar results if applied correctly, with the WEPP predictions somewhat greater than the CN predictions. Later releases of the WEPP model have incorporated alternative methods for routing peak flows that need to be evaluated.

  6. Fuel cell-fuel cell hybrid system

    DOEpatents

    Geisbrecht, Rodney A.; Williams, Mark C.

    2003-09-23

    A device for converting chemical energy to electricity is provided, the device comprising a high temperature fuel cell with the ability for partially oxidizing and completely reforming fuel, and a low temperature fuel cell juxtaposed to said high temperature fuel cell so as to utilize remaining reformed fuel from the high temperature fuel cell. Also provided is a method for producing electricity comprising directing fuel to a first fuel cell, completely oxidizing a first portion of the fuel and partially oxidizing a second portion of the fuel, directing the second fuel portion to a second fuel cell, allowing the first fuel cell to utilize the first portion of the fuel to produce electricity; and allowing the second fuel cell to utilize the second portion of the fuel to produce electricity.

  7. PEAK READING VOLTMETER

    DOEpatents

    Dyer, A.L.

    1958-07-29

    An improvement in peak reading voltmeters is described, which provides for storing an electrical charge representative of the magnitude of a transient voltage pulse and thereafter measuring the stored charge, drawing oniy negligible energy from the storage element. The incoming voltage is rectified and stored in a condenser. The voltage of the capacitor is applied across a piezoelectric crystal between two parallel plates. Amy change in the voltage of the capacitor is reflected in a change in the dielectric constant of the crystal and the capacitance between a second pair of plates affixed to the crystal is altered. The latter capacitor forms part of the frequency determlning circuit of an oscillator and means is provided for indicating the frequency deviation which is a measure of the peak voltage applied to the voltmeter.

  8. INDIAN PEAKS WILDERNESS, COLORADO.

    USGS Publications Warehouse

    Pearson, Robert C.; Speltz, Charles N.

    1984-01-01

    The Indian Peaks Wilderness northwest of Denver is partly within the Colorado Mineral Belt, and the southeast part of it contains all the geologic characteristics associated with the several nearby mining districts. Two deposits have demonstrated mineral resources, one of copper and the other of uranium; both are surrounded by areas with probable potential. Two other areas have probable resource potential for copper, gold, and possibly molydenum. Detailed gravity and magnetic studies in the southeast part of the Indian Peaks Wilderness might detect in the subsurface igneous bodies that may be mineralized. Physical exploration such as drilling would be necessary to determine more precisely the copper resources at the Roaring Fork locality and uranium resources at Wheeler Basin.

  9. Peak of Desire

    PubMed Central

    Huang, Julie Y.; Bargh, John A.

    2008-01-01

    In three studies, we explore the existence of an evolved sensitivity to the peak as consistent with the evolutionary origins of many of our basic preferences. Activating the evolved motive of mating activates related adaptive mechanisms, including a general sensitivity to cues of growth and decay associated with determining mate value in human courtship. We establish that priming the mating goal also activates as well an evaluative bias that influences how people evaluate cues of growth. Specifically, living kinds that are immature or past their prime are devalued, whereas living kinds at their peak become increasingly valued. Study 1 establishes this goal-driven effect for human stimuli indirectly related to the mating goal. Studies 2 and 3 establish that the evaluative bias produced by the active mating goal extends to living kinds but not artifacts. PMID:18578847

  10. PEAK LIMITING AMPLIFIER

    DOEpatents

    Goldsworthy, W.W.; Robinson, J.B.

    1959-03-31

    A peak voltage amplitude limiting system adapted for use with a cascade type amplifier is described. In its detailed aspects, the invention includes an amplifier having at least a first triode tube and a second triode tube, the cathode of the second tube being connected to the anode of the first tube. A peak limiter triode tube has its control grid coupled to thc anode of the second tube and its anode connected to the cathode of the second tube. The operation of the limiter is controlled by a bias voltage source connected to the control grid of the limiter tube and the output of the system is taken from the anode of the second tube.

  11. Highly efficient and robust cathode materials for low-temperature solid oxide fuel cells: PrBa0.5Sr0.5Co2-xFexO5+δ

    NASA Astrophysics Data System (ADS)

    Choi, Sihyuk; Yoo, Seonyoung; Kim, Jiyoun; Park, Seonhye; Jun, Areum; Sengodan, Sivaprakash; Kim, Junyoung; Shin, Jeeyoung; Jeong, Hu Young; Choi, Yongman; Kim, Guntae; Liu, Meilin

    2013-08-01

    Solid oxide fuel cells (SOFC) are the cleanest, most efficient, and cost-effective option for direct conversion to electricity of a wide variety of fuels. While significant progress has been made in anode materials with enhanced tolerance to coking and contaminant poisoning, cathodic polarization still contributes considerably to energy loss, more so at lower operating temperatures. Here we report a synergistic effect of co-doping in a cation-ordered double-perovskite material, PrBa0.5Sr0.5Co2-xFexO5+δ, which has created pore channels that dramatically enhance oxygen ion diffusion and surface oxygen exchange while maintaining excellent compatibility and stability under operating conditions. Test cells based on these cathode materials demonstrate peak power densities ~2.2 W cm-2 at 600°C, representing an important step toward commercially viable SOFC technologies.

  12. Highly efficient and robust cathode materials for low-temperature solid oxide fuel cells: PrBa0.5Sr0.5Co2−xFexO5+δ

    PubMed Central

    Choi, Sihyuk; Yoo, Seonyoung; Kim, Jiyoun; Park, Seonhye; Jun, Areum; Sengodan, Sivaprakash; Kim, Junyoung; Shin, Jeeyoung; Jeong, Hu Young; Choi, YongMan; Kim, Guntae; Liu, Meilin

    2013-01-01

    Solid oxide fuel cells (SOFC) are the cleanest, most efficient, and cost-effective option for direct conversion to electricity of a wide variety of fuels. While significant progress has been made in anode materials with enhanced tolerance to coking and contaminant poisoning, cathodic polarization still contributes considerably to energy loss, more so at lower operating temperatures. Here we report a synergistic effect of co-doping in a cation-ordered double-perovskite material, PrBa0.5Sr0.5Co2−xFexO5+δ, which has created pore channels that dramatically enhance oxygen ion diffusion and surface oxygen exchange while maintaining excellent compatibility and stability under operating conditions. Test cells based on these cathode materials demonstrate peak power densities ~2.2 W cm−2 at 600°C, representing an important step toward commercially viable SOFC technologies. PMID:23945630

  13. DIAMOND PEAK WILDERNESS, OREGON.

    USGS Publications Warehouse

    Sherrod, David R.; Moyle, Phillip R.

    1984-01-01

    No metallic mineral resources were identified during a mineral survey of the Diamond Peak Wilderness in Oregon. Cinder cones within the wilderness contain substantial cinder resources, but similar deposits that are more accessible occur outside the wilderness. The area could have geothermal resources, but available data are insufficient to evaluate their potential. Several deep holes could be drilled in areas of the High Cascades outside the wilderness, from which extrapolations of the geothermal potential of the several Cascade wilderness could be made.

  14. Fueling characteristics of supersonic gas puffing applied to large high-temperature plasmas in the Large Helical Device

    NASA Astrophysics Data System (ADS)

    Murakami, A.; Miyazawa, J.; Suzuki, C.; Yamada, I.; Morisaki, T.; Sakamoto, R.; Yamada, H.; Group LHD Experiment

    2012-05-01

    Supersonic gas puffing (SSGP), where a high-pressure gas is ejected through a fast solenoid valve equipped with a Laval nozzle, has been applied to large high-temperature plasmas and its fueling characteristics have been investigated in the Large Helical Device. The fueling efficiency of SSGP depends on the target plasma density and decreases as the density increases. This is due to the fueling mechanism of SSGP, where the fuel particles are supplied to the plasma edge region and then transported to the core region by diffusion. SSGP locally supplies a large number of particles to the edge region within a short time on the order of milliseconds. A fueling efficiency of ˜20% can be achieved by SSGP at a low initial density of ˜1.5 × 1019 m-3, which is more than twice as high as that of ordinary gas puffing at a similar density. Furthermore, this property leads to the additional effect of edge cooling to SSGP that will be beneficial for divertor heat load reduction.

  15. Experimental Study of Injection Characteristics of a Multi-hole port injector on various Fuel Injection pressures and Temperatures

    NASA Astrophysics Data System (ADS)

    Movahednejad, E.; Ommi, F.; Nekofar, K.

    2013-04-01

    The structures of the port injector spray dominates the mixture preparation process and strongly affect the subsequent engine combustion characteristics over a wide range of operating conditions in port-injection gasoline engines. All these spray characteristics are determined by particular injector design and operating conditions. In this paper, an experimental study is made to characterize the breakup mechanism and spray characteristics of a injector with multi-disc nozzle (SAGEM,D2159MA). A comparison was made on injection characteristics of the multi-hole injectors and its effects on various fuel pressure and temperature. The distributions of the droplet size and velocity and volume flux were characterized using phase Doppler anemometry (PDA) technique. Through this work, it was found that the injector produces a finer spray with a wide spray angle in higher fuel pressure and temperature.

  16. Irradiation dose and temperature dependence of fracture toughness in high dose HT9 steel from the fuel duct of FFTF

    NASA Astrophysics Data System (ADS)

    Byun, Thak Sang; Toloczko, Mychailo B.; Saleh, Tarik A.; Maloy, Stuart A.

    2013-01-01

    To expand the knowledge base for fast reactor core materials, fracture toughness has been evaluated for high dose HT9 steel using miniature disk compact tension (DCT) specimens. The HT9 steel DCT specimens were machined from the ACO-3 fuel duct of the Fast Flux Test Facility (FFTF), which achieved high doses in the range of 3-148 dpa at 378-504 °C. The static fracture resistance (J-R) tests have been performed in a servohydraulic testing machine in vacuum at selected temperatures including room temperature, 200 °C, and each irradiation temperature. Brittle fracture with a low toughness less than 50 MPa √m occurred in room temperature tests when irradiation temperature was below 400 °C, while ductile fracture with stable crack growth was observed when irradiation temperature was higher. No fracture toughness less than 100 MPa √m was measured when the irradiation temperature was above 430 °C. It was shown that the influence of irradiation temperature was dominant in fracture toughness while the irradiation dose has only limited influence over the wide dose range 3-148 dpa. A slow decrease of fracture toughness with test temperature above room temperature was observed for the nonirradiated and high temperature (>430 °C) irradiation cases, which indicates that the ductile-brittle transition temperatures (DBTTs) in those conditions are lower than room temperature. A comparison with the collection of existing data confirmed the dominance of irradiation temperature in the fracture toughness of HT9 steels.

  17. Cosmic microwave background acoustic peak locations

    NASA Astrophysics Data System (ADS)

    Pan, Z.; Knox, L.; Mulroe, B.; Narimani, A.

    2016-07-01

    The Planck collaboration has measured the temperature and polarization of the cosmic microwave background well enough to determine the locations of eight peaks in the temperature (TT) power spectrum, five peaks in the polarization (EE) power spectrum and 12 extrema in the cross (TE) power spectrum. The relative locations of these extrema give a striking, and beautiful, demonstration of what we expect from acoustic oscillations in the plasma; e.g. that EE peaks fall half way between TT peaks. We expect this because the temperature map is predominantly sourced by temperature variations in the last scattering surface, while the polarization map is predominantly sourced by gradients in the velocity field, and the harmonic oscillations have temperature and velocity 90 deg out of phase. However, there are large differences in expectations for extrema locations from simple analytic models versus numerical calculations. Here, we quantitatively explore the origin of these differences in gravitational potential transients, neutrino free-streaming, the breakdown of tight coupling, the shape of the primordial power spectrum, details of the geometric projection from three to two dimensions, and the thickness of the last scattering surface. We also compare the peak locations determined from Planck measurements to expectations under the Λ cold dark matter model. Taking into account how the peak locations were determined, we find them to be in agreement.

  18. Will peak oil accelerate carbon dioxide emissions?

    NASA Astrophysics Data System (ADS)

    Caldeira, K.; Davis, S. J.; Cao, L.

    2008-12-01

    The relative scarcity of oil suggests that oil production is peaking and will decline thereafter. Some have suggested that this represents an opportunity to reduce carbon dioxide emissions. However, in the absence of constraints on carbon dioxide emission, "peak oil" may drive a shift towards increased reliance on coal as a primary energy source. Because coal per unit energy, in the absence of carbon capture and disposal, releases more carbon dioxide to the atmosphere than oil, "peak oil" may lead to an acceleration of carbon dioxide emissions. We will never run out of oil. As oil becomes increasingly scarce, prices will rise and therefore consumption will diminish. As prices rise, other primary energy sources will become increasingly competitive with oil. The developed world uses oil primarily as a source of transportation fuels. The developing world uses oil primarily for heat and power, but the trend is towards increasing reliance on oil for transportation. Liquid fuels, including petroleum derivatives such as gasoline and diesel fuel, are attractive as transportation fuels because of their relative abundance of energy per unit mass and volume. Such considerations are especially important for the air transport industry. Today, there is little that can compete with petroleum-derived transportation fuels. Future CO2 emissions from the transportation sector largely depend on what replaces oil as a source of fuel. Some have suggested that biomass-derived ethanol, hydrogen, or electricity could play this role. Each of these potential substitutes has its own drawbacks (e.g., low power density per unit area in the case of biomass, low power density per unit volume in the case of hydrogen, and low power density per unit mass in the case of battery storage). Thus, it is entirely likely that liquefaction of coal could become the primary means by which transportation fuels are produced. Since the burning of coal produces more CO2 per unit energy than does the burning of

  19. Autoignition in a premixing-prevaporizing fuel duct using 3 different fuel injection systems at inlet air temperatures to 1250 K

    NASA Technical Reports Server (NTRS)

    Tacina, R. R.

    1983-01-01

    Conditions were determined in a continuous-flow, premixing-prevaporizing duct at which autoignition occurred. Test conditions were representative of an advanced, regenerative-cycle, automotive gas turbine. The test conditions inlet air temperatures from 600 to 1250 K (a vitiated preheater was used), pressures from 170 to 600 kPa, air velocities of 10 to 30 m/sec, equivalence ratios from 0.3 to 1.0, mixing lengths from 10 to 60 cm, and residence times of 2 to 100 ms. The fuel was diesel number 2. The duct was insulated and had an inside diameter of 12 cm. Three different fuel injection systems were used: One was a single simplex pressure atomizer, and the other two were multiple-source injectors. The data obtained with the simplex and one of the multiple-source injectors agreed satisfactorily with the references and correlated with an Arrenhius expression. The data obtained with the other multiple source injector, which used multiple cones to improve the fuel-air distribution, did not correlate well with residence time.

  20. In Brief: Timing of peak oil uncertain

    NASA Astrophysics Data System (ADS)

    Zielinski, Sarah

    2007-04-01

    According to the Hubbert peak theory, oil production in any geographic area will follow a bellshaped curve. The timing of the `peak' in global oil production is important because after that point, there will be less and less oil available for consumption. A new report from the U.S. Government Accountability Office found that most studies estimate that peak oil production will occur sometime between now and 2040. The uncertainty in these estimates could be reduced with better information about worldwide supply and demand, and alternative fuels and transportation technologies could mitigate the effects of a global decline in oil production. However, the report found no coordinated U.S. federal strategy to address these issues. The report, ``Uncertainty about Future Oil Supply Makes It Important to Develop a Strategy for Addressing a Peak and Decline in Oil Production,'' is available at http://www.gao.gov/cgi-bin/getrpt?GAO-07-283

  1. Low-temperature fuel cell systems for commercial airplane auxiliary power.

    SciTech Connect

    Curgus, Dita Brigitte; Pratt, Joseph William; Akhil, Abbas Ali; Klebanoff, Leonard E.

    2010-11-01

    This presentation briefly describes the ongoing study of fuel cell systems on-board a commercial airplane. Sandia's current project is focused on Proton Exchange Membrane (PEM) fuel cells applied to specific on-board electrical power needs. They are trying to understand how having a fuel cell on an airplane would affect overall performance. The fuel required to accomplish a mission is used to quantify the performance. Our analysis shows the differences between the base airplane and the airplane with the fuel cell. There are many ways of designing a system, depending on what you do with the waste heat. A system that requires ram air cooling has a large mass penalty due to increased drag. The bottom-line impact can be expressed as additional fuel required to complete the mission. Early results suggest PEM fuel cells can be used on airplanes with manageable performance impact if heat is rejected properly. For PEMs on aircraft, we are continuing to perform: (1) thermodynamic analysis (investigate configurations); (2) integrated electrical design (with dynamic modeling of the micro grid); (3) hardware assessment (performance, weight, and volume); and (4) galley and peaker application.

  2. Cell integrated multi-junction thermocouple array for solid oxide fuel cell temperature sensing: N+1 architecture

    NASA Astrophysics Data System (ADS)

    Ranaweera, Manoj; Kim, Jung-Sik

    2016-05-01

    Understanding the cell temperature distribution of solid oxide fuel cell (SOFC) stacks during normal operation has multifaceted advantages in performance and degradation studies. Present efforts on measuring temperature from operating SOFCs measure only the gas channel temperature and do not reveal the cell level temperature distribution, which is more important for understanding a cell's performance and its temperature-related degradation. The authors propose a cell-integrated, multi-junction thermocouple array for in-situ cell surface temperature monitoring of an operational SOFC. The proposed thermocouple array requires far fewer numbers of thermoelements than that required by sets of thermocouples for the same number of temperature sensing points. Hence, the proposed array causes lower disturbance to cell performance than thermocouples. The thermoelement array was sputter deposited on the cathode of a commercial SOFC using alumel (Ni:Al:Mn:Si - 95:2:2:1 by wt.) and chromel (Ni:Cr - 90:10 by wt.). The thermocouple array was tested in a furnace over the entire operating temperature range of a typical SOFC. The individual sensing points of the array were shown to measure temperature independently from each other with equivalent accuracy to a thermocouple. Thus, the concept of multi-junction thermocouples is experimentally validated and its stability on a porous SOFC cathode is confirmed.

  3. Laminar Flame Speed of Primary Reference Fuels and Gasoline Surrogates at Elevated Temperatures Measured with the Flat Flame Method

    NASA Astrophysics Data System (ADS)

    Liao, Ying-Hao; Roberts, William

    2013-11-01

    The laminar flame speed is a key target data for validating relevant kinetic mechanisms of the combustion of future fuel formulations since this fundamental parameter contains information for the reactivity, diffusivity, and exothermicity of the fuel mixture. The current work presents the flat flame method, which produces a one-dimensional flat flame free of stretch, to measure laminar flame speeds of the Primary Reference Fuels (PRFs), PRF blends, and gasoline surrogates at elevated temperatures. The flat flame is produced by a McKenna porous plug burner. The laminar flame speed was measured experimentally at atmospheric pressure over a range of equivalence ratios and a range of unburned gas temperatures up to 470 K. To determine the laminar flame speed, a technique with heat extraction through the cooling water, similar to that described by Botha and Spalding (1954), was employed and the adiabatic laminar flame speed was obtained by extrapolation. In addition, the experimental data is compared to simulations using kinetic mechanisms available in the literature. Preliminary results of laminar flame speeds for methane/air and n-heptane/air mixtures at room temperature show good agreement with both of experimental and numerical data available in the literature. Clean Combustion Research Center.

  4. High performance of SDC and GDC core shell type composite electrolytes using methane as a fuel for low temperature SOFC

    NASA Astrophysics Data System (ADS)

    Irshad, Muneeb; Siraj, Khurram; Raza, Rizwan; Javed, Fayyaz; Ahsan, Muhammad; Shakir, Imran; Rafique, Muhammad Shahid

    2016-02-01

    Nanocomposites Samarium doped Ceria (SDC), Gadolinium doped Ceria (GDC), core shell SDC amorphous Na2CO3 (SDCC) and GDC amorphous Na2CO3 (GDCC) were synthesized using co-precipitation method and then compared to obtain better solid oxide electrolytes materials for low temperature Solid Oxide Fuel Cell (SOFCs). The comparison is done in terms of structure, crystallanity, thermal stability, conductivity and cell performance. In present work, XRD analysis confirmed proper doping of Sm and Gd in both single phase (SDC, GDC) and dual phase core shell (SDCC, GDCC) electrolyte materials. EDX analysis validated the presence of Sm and Gd in both single and dual phase electrolyte materials; also confirming the presence of amorphous Na2CO3 in SDCC and GDCC. From TGA analysis a steep weight loss is observed in case of SDCC and GDCC when temperature rises above 725 °C while SDC and GDC do not show any loss. The ionic conductivity and cell performance of single phase SDC and GDC nanocomposite were compared with core shell GDC/amorphous Na2CO3 and SDC/ amorphous Na2CO3 nanocomposites using methane fuel. It is observed that dual phase core shell electrolytes materials (SDCC, GDCC) show better performance in low temperature range than their corresponding single phase electrolyte materials (SDC, GDC) with methane fuel.

  5. Transient infrared temperature measurements of liquid-fuel surfaces: results of studies of flames spread over liquids.

    PubMed

    Konishi, T; Ito, A; Saito, K

    2000-08-20

    An infrared thermograph technique with an 8-12-microm spectral range was used to measure transient two-dimensional profiles of liquid (1-propanol) surface temperatures. An IR camera was placed over the liquid, allowing us to observe the fuel surface through propanol vapor. To use this technique, one must know the emissivity of the liquid surface and the IR absorption of both the liquid propanol and the propanol vapor. The emissivity of the liquid propanol was determined with a fine thermocouple temperature measurement, IR absorption with the propanol vapor was calibrated with a blackbody source, and IR absorption with a liquid propanol was theoretically estimated. The accuracy of our infrared thermograph technique proved to be better than 97% in detecting the liquid-surface temperature with a temperature sensitivity of 0.1 degrees C and a time response of 30 ms. PMID:18350009

  6. Kitt Peak speckle camera

    NASA Technical Reports Server (NTRS)

    Breckinridge, J. B.; Mcalister, H. A.; Robinson, W. G.

    1979-01-01

    The speckle camera in regular use at Kitt Peak National Observatory since 1974 is described in detail. The design of the atmospheric dispersion compensation prisms, the use of film as a recording medium, the accuracy of double star measurements, and the next generation speckle camera are discussed. Photographs of double star speckle patterns with separations from 1.4 sec of arc to 4.7 sec of arc are shown to illustrate the quality of image formation with this camera, the effects of seeing on the patterns, and to illustrate the isoplanatic patch of the atmosphere.

  7. Assessment of perovskite-type La0.8Sr0.2ScxMn1-xO3-δ oxides as anodes for intermediate-temperature solid oxide fuel cells using hydrocarbon fuels

    NASA Astrophysics Data System (ADS)

    Sengodan, S.; Yeo, H. J.; Shin, J. Y.; Kim, G.

    2011-03-01

    Composites formed by the infiltration of 40 wt% La0.8Sr0.2ScxMn1-xO3-δ (LSSM) oxides (x = 0.1, 0.2, 0.3) into 65% porous yttria-stabilized zirconia (YSZ) are investigated as anode materials for intermediate-temperature solid oxide fuel cells for hydrocarbon oxidation. The oxygen non-stoichiometry and electrical conductivity of each LSSM-YSZ composite are determined by coulometric titration. As the concentration of Sc increases, the composites show higher phase stability and the electrical conductivity of LSSM is significantly affected by the Sc doping, the non-stoichiometric oxygen content, and oxygen partial pressure (p(O2)). To achieve better electrochemical performance, it is necessary to add ceria-supported palladium catalyst for operation with humidified CH4. Anode polarization resistance increases with Sc doping due to a decrease in electrical conductivity. An electrolyte-supported cell with a LSSM-YSZ composite anode delivers peak power densities of 395 and 340 mW cm-2 at 923 K in humidified (3% H2O) H2 and CH4, respectively, at a flow rate of 20 mL min-1.

  8. The influence of operating temperature on the efficiency of a combined heat and power fuel cell plant

    NASA Astrophysics Data System (ADS)

    Au, S. F.; McPhail, S. J.; Woudstra, N.; Hemmes, K.

    It is generally accepted that the ideal operating temperature of a molten carbonate fuel cell (MCFC) is 650 °C. Nevertheless, when waste heat utilization in the form of an expander and steam production cycle is introduced in the system, another temperature level might prove more productive. This article is a first attempt to the optimization of MCFC operating temperatures of a MCFC system by presenting a case study in which the efficiency of a combined heat and power (CHP) plant is analyzed. The fuel cell plant under investigation is designed around a 250 kW-class MCFC fuelled by natural gas, which is externally reformed by a heat exchange reformer (HER). The operating temperature of the MCFC is varied over a temperature range between 600 and 700 °C while keeping the rest of the system the same as far as possible. Changes in energetic efficiency are given and the causes of these changes are further analyzed. Furthermore, the exergetic efficiencies of the system and the distribution of exergy losses in the system are given. Flowsheet calculations show that there is little dependency on the temperature in the first order. Both the net electrical performance and the overall exergetic performance show a maximum at approximately 675 °C, with an electrical efficiency of 51.9% (LHV), and an exergy efficiency of 58.7%. The overall thermal efficiency of this CHP plant increases from 87.1% at 600 °C to 88.9% at 700 °C. Overall, the change in performance is small in this typical range of MCFC operating temperature.

  9. Shape-Dependent Activity of Ceria for Hydrogen Electro-Oxidation in Reduced-Temperature Solid Oxide Fuel Cells.

    PubMed

    Tong, Xiaofeng; Luo, Ting; Meng, Xie; Wu, Hao; Li, Junliang; Liu, Xuejiao; Ji, Xiaona; Wang, Jianqiang; Chen, Chusheng; Zhan, Zhongliang

    2015-11-01

    Single crystalline ceria nanooctahedra, nanocubes, and nanorods are hydrothermally synthesized, colloidally impregnated into the porous La0.9Sr0.1Ga0.8Mg0.2O3-δ (LSGM) scaffolds, and electrochemically evaluated as the anode catalysts for reduced temperature solid oxide fuel cells (SOFCs). Well-defined surface terminations are confirmed by the high-resolution transmission electron microscopy--(111) for nanooctahedra, (100) for nanocubes, and both (110) and (100) for nanorods. Temperature-programmed reduction in H2 shows the highest reducibility for nanorods, followed sequentially by nanocubes and nanooctahedra. Measurements of the anode polarization resistances and the fuel cell power densities reveal different orders of activity of ceria nanocrystals at high and low temperatures for hydrogen electro-oxidation, i.e., nanorods > nanocubes > nanooctahedra at T ≤ 450 °C and nanooctahedra > nanorods > nanocubes at T ≥ 500 °C. Such shape-dependent activities of these ceria nanocrystals have been correlated to their difference in the local structure distortions and thus in the reducibility. These findings will open up a new strategy for design of advanced catalysts for reduced-temperature SOFCs by elaborately engineering the shape of nanocrystals and thus selectively exposing the crystal facets. PMID:26307555

  10. 40 CFR 600.113-08 - Fuel economy calculations for FTP, HFET, US06, SC03 and cold temperature FTP tests.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ..., HFET, US06, SC03 and cold temperature FTP tests. 600.113-08 Section 600.113-08 Protection of... Fuel economy calculations for FTP, HFET, US06, SC03 and cold temperature FTP tests. The Administrator... (NMHC) and methane (CH4) for the FTP, HFET, US06, SC03 and cold temperature FTP tests. Additionally,...

  11. 40 CFR 600.113-08 - Fuel economy calculations for FTP, HFET, US06, SC03 and cold temperature FTP tests.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ..., HFET, US06, SC03 and cold temperature FTP tests. 600.113-08 Section 600.113-08 Protection of... Fuel economy calculations for FTP, HFET, US06, SC03 and cold temperature FTP tests. The Administrator... (NMHC) and methane (CH4) for the FTP, HFET, US06, SC03 and cold temperature FTP tests. Additionally,...

  12. A micro-nano porous oxide hybrid for efficient oxygen reduction in reduced-temperature solid oxide fuel cells

    PubMed Central

    Da Han; Liu, Xuejiao; Zeng, Fanrong; Qian, Jiqin; Wu, Tianzhi; Zhan, Zhongliang

    2012-01-01

    Tremendous efforts to develop high-efficiency reduced-temperature (≤ 600°C) solid oxide fuel cells are motivated by their potentials for reduced materials cost, less engineering challenge, and better performance durability. A key obstacle to such fuel cells arises from sluggish oxygen reduction reaction kinetics on the cathodes. Here we reported that an oxide hybrid, featuring a nanoporous Sm0.5Sr0.5CoO3−δ (SSC) catalyst coating bonded onto the internal surface of a high-porosity La0.9Sr0.1Ga0.8Mg0.2O3−δ (LSGM) backbone, exhibited superior catalytic activity for oxygen reduction reactions and thereby yielded low interfacial resistances in air, e.g., 0.021 Ω cm2 at 650°C and 0.043 Ω cm2 at 600°C. We further demonstrated that such a micro-nano porous hybrid, adopted as the cathode in a thin LSGM electrolyte fuel cell, produced impressive power densities of 2.02 W cm−2 at 650°C and 1.46 W cm−2 at 600°C when operated on humidified hydrogen fuel and air oxidant. PMID:22708057

  13. The Boson peak in supercooled water.

    PubMed

    Kumar, Pradeep; Wikfeldt, K Thor; Schlesinger, Daniel; Pettersson, Lars G M; Stanley, H Eugene

    2013-01-01

    We perform extensive molecular dynamics simulations of the TIP4P/2005 model of water to investigate the origin of the Boson peak reported in experiments on supercooled water in nanoconfined pores, and in hydration water around proteins. We find that the onset of the Boson peak in supercooled bulk water coincides with the crossover to a predominantly low-density-like liquid below the Widom line TW. The frequency and onset temperature of the Boson peak in our simulations of bulk water agree well with the results from experiments on nanoconfined water. Our results suggest that the Boson peak in water is not an exclusive effect of confinement. We further find that, similar to other glass-forming liquids, the vibrational modes corresponding to the Boson peak are spatially extended and are related to transverse phonons found in the parent crystal, here ice Ih. PMID:23771033

  14. Nanocomposite membranes based on polybenzimidazole and ZrO2 for high-temperature proton exchange membrane fuel cells.

    PubMed

    Nawn, Graeme; Pace, Giuseppe; Lavina, Sandra; Vezzù, Keti; Negro, Enrico; Bertasi, Federico; Polizzi, Stefano; Di Noto, Vito

    2015-04-24

    Owing to the numerous benefits obtained when operating proton exchange membrane fuel cells at elevated temperature (>100 °C), the development of thermally stable proton exchange membranes that demonstrate conductivity under anhydrous conditions remains a significant goal for fuel cell technology. This paper presents composite membranes consisting of poly[2,2'-(m-phenylene)-5,5'-bibenzimidazole] (PBI4N) impregnated with a ZrO2 nanofiller of varying content (ranging from 0 to 22 wt %). The structure-property relationships of the acid-doped and undoped composite membranes have been studied using thermogravimetric analysis, differential scanning calorimetry, dynamic mechanical analysis, wide-angle X-ray scattering, infrared spectroscopy, and broadband electrical spectroscopy. Results indicate that the level of nanofiller has a significant effect on the membrane properties. From 0 to 8 wt %, the acid uptake as well as the thermal and mechanical properties of the membrane increase. As the nanofiller level is increased from 8 to 22 wt % the opposite effect is observed. At 185 °C, the ionic conductivity of [PBI4N(ZrO2 )0.231 ](H3 PO4 )13 is found to be 1.04×10(-1)  S cm(-1) . This renders membranes of this type promising candidates for use in high-temperature proton exchange membrane fuel cells. PMID:25801848

  15. Evaluation of a 2.5 kWel automotive low temperature PEM fuel cell stack with extended operating temperature range up to 120 °C

    NASA Astrophysics Data System (ADS)

    Ruiu, Tiziana; Dreizler, Andreas M.; Mitzel, Jens; Gülzow, Erich

    2016-01-01

    Nowadays, the operating temperature of polymer electrolyte membrane fuel cell stacks is typically limited to 80 °C due to water management issues of membrane materials. In the present work, short-term operation at elevated temperatures up to 120 °C and long-term steady-state operation under automotive relevant conditions at 80 °C are examined using a 30-cell stack developed at DLR. The high temperature behavior is investigated by using temperature cycles between 90 and 120 °C without adjustment of the gases dew points, to simulate a short-period temperature increase, possibly caused by an extended power demand and/or limited heat removal. This galvanostatic test demonstrates a fully reversible performance decrease of 21 ± 1% during each thermal cycle. The irreversible degradation rate is about a factor of 6 higher compared to the one determined by the long-term test. The 1200-h test at 80 °C demonstrates linear stack voltage decay with acceptable degradation rate, apart from a malfunction of the air compressor, which results in increased catalyst degradation effects on individual cells. This interpretation is based on an end-of-life characterization, aimed to investigate catalyst, electrode and membrane degradation, by determining hydrogen crossover rates, high frequency resistances, electrochemically active surface areas and catalyst particle sizes.

  16. Study of temperature, air dew point temperature and reactant flow effects on proton exchange membrane fuel cell performances using electrochemical spectroscopy and voltammetry techniques

    NASA Astrophysics Data System (ADS)

    Wasterlain, S.; Candusso, D.; Hissel, D.; Harel, F.; Bergman, P.; Menard, P.; Anwar, M.

    A single PEMFC has been operated by varying the assembly temperature, the air dew point temperature and the anode/cathode stoichiometry rates with the aim to identify the parameters and combinations of factors affecting the cell performance. Some of the experiments were conducted with low humidified reactants (relative humidity of 12%). The FC characterizations tests have been conducted using in situ electrochemical methods based on load current and cell voltage signal analysis, namely: polarization curves, EIS measurements, cyclic and linear sweep voltammetries (CV and LSV). The impacts of the parameters on the global FC performances were observed using the polarization curves whereas EIS, CV and LSV test results were used to discriminate the different voltage loss sources. The test results suggest that some parameter sets allow maximal output voltages but can also induce material degradation. For instance, higher FC temperature and air flow values can induce significant electrical efficiency benefits, notably by increasing the reversible potential and the reaction kinetics. However, raising the cell temperature can also gradually dry the FC and increase the risk of membrane failure. LSV has also shown that elevated FC temperature and relative humidity can also accelerate the electrolyte degradation (i.e. slightly higher fuel crossover rate) and reduce the lifetime consequently.

  17. Spontaneous ignition in afterburner segment tests at an inlet temperature of 1240 K and a pressure of 1 atmosphere with ASTM jet-A fuel

    NASA Technical Reports Server (NTRS)

    Schultz, D. F.; Branstetter, J. R.

    1973-01-01

    A brief testing program was undertaken to determine if spontaneous ignition and stable combustion could be obtained in a jet engine afterburning operating with an inlet temperature of 1240 K and a pressure of 1 atmosphere with ASTM Jet-A fuel. Spontaneous ignition with 100-percent combustion efficiency and stable burning was obtained using water-cooled fuel spraybars as flameholders.

  18. Materials, Proton Conductivity and Electrocatalysis in High-Temperature PEM Fuel Cells

    NASA Astrophysics Data System (ADS)

    Daletou, Maria K.; Kallitsis, Joannis; Neophytides, Stylianos G.

    Fuel cells (FCs) are interesting alternatives to existing power conversion systems since they combine high efficiency with the usage of renewable fuels. Fuel cells can generate power from a fraction of a watt to hundreds of kilowatts and can be used in automotive, stationary or portable applications.1,2,3,4,5,6 A FC is an electrochemical device that converts in a continuous manner the free energy of a chemical reaction into electrical energy (via an electrical current). This galvanic cell consists of an electrolyte (liquid or solid) sandwiched between two porous electrodes. In order to reach desirable amounts of energy power, single cell assemblies can be mechanically compressed across electrically conductive separators to fabricate stacks.

  19. Measurement of the spatial dependence of temperature and gas and soot concentrations within large open hydrocarbon fuel fires

    NASA Technical Reports Server (NTRS)

    Johnson, H. T.; Linley, L. J.; Mansfield, J. A.

    1982-01-01

    A series of large-scale JP-4 fuel pool fire tests was conducted to refine existing mathematical models of large fires. Seven tests were conducted to make chemical concentration and temperature measurements in 7.5 and 15 meter-diameter pool fires. Measurements were made at heights of 0.7, 1.4, 2.9, 5.7, 11.4, and 21.3 meters above the fires. Temperatures were measured at up to 50 locations each second during the fires. Chemistry samples were taken at up to 23 locations within the fires and analyzed for combustion chemistry and soot concentration. Temperature and combustion chemistry profiles obtained during two 7.5 meter-diameter and two 15 meter-diameter fires are included.

  20. LOW-TEMPERATURE, ANODE-SUPPORTED HIGH POWER DENSITY SOLID OXIDE FUEL CELLS WITH NANOSTRUCTURED ELECTRODES

    SciTech Connect

    Anil V. Virkar

    2001-09-26

    Anode-supported solid oxide fuel cells with Ni + yttria-stabilized zirconia (YSZ) anode, YSZ-samaria-doped ceria (SDC) bi-layer electrolyte and Sr-doped LaCoO{sub 3} (LSC) + SDC cathode were fabricated. Fuel used consisted of H{sub 2} diluted with He, N{sub 2}, H{sub 2}O or CO{sub 2}, mixtures of H{sub 2} and CO, and mixtures of CO and CO{sub 2}. Cell performance was measured at 800 C with above-mentioned fuel gas mixtures and air as oxidant. For a given concentration of the diluent, the cell performance was higher with He as the diluent than with N{sub 2} as the diluent. Mass transport through porous Ni-YSZ anode for H{sub 2}-H{sub 2}O, CO-CO{sub 2} binary systems and H{sub 2}-H{sub 2}O-diluent gas ternary systems was analyzed using multicomponent gas diffusion theory. At high concentrations of the diluent, the maximum achievable current density was limited by the anodic concentration polarization. From this measured limiting current density, the corresponding effective gas diffusivity was estimated. Highest effective diffusivity was estimated for fuel gas mixtures containing H{sub 2}-H{sub 2}O-He mixtures ({approx}0.34 cm{sup 2}/s), and the lowest for CO-CO{sub 2} mixtures ({approx}0.07 cm{sup 2}/s). The lowest performance was observed with CO-CO{sub 2} mixture as a fuel, which in part was attributed to the lowest effective diffusivity of the fuels tested.

  1. Cerium and niobium doped SrCoO3-δ as a potential cathode for intermediate temperature solid oxide fuel cells

    NASA Astrophysics Data System (ADS)

    Huang, Shouguo; Feng, Shuangjiu; Lu, Qiliang; Li, Yide; Wang, Hong; Wang, Chunchang

    2014-04-01

    Sr0.9Ce0.1Co0.9Nb0.1O3-δ (SCCN) has been synthesized using solid state reaction, and investigated as a new cathode material for intermediate temperature solid oxide fuel cells (ITSOFCs). SCCN material exhibits sufficiently high electronic conductivity and excellent chemical compatibility with SDC electrolyte. Highly charged Ce4+ and Nb5+ successfully stabilize the perovskite structure to avoid order-disorder phase transition. The electrical conductivity reaches a high value of 516 S cm-1 at 300 °C in air. The area specific resistances of the SCCN-50 wt.% Ce0.8Sm0.2O1.9 (SDC) cathode are as low as 0.027, 0.049, and 0.094 Ω cm2 at 700, 650, and 600 °C, respectively, with the corresponding peak power densities of 1074, 905, and 589 mW cm-2. A relatively low thermal expansion coefficient of SCCN-SDC is 14.3 × 10-6 K-1 in air. All these results imply that SCCN holds tremendous promise as a cathode material for ITSOFCs.

  2. Bioconversion of solar energy into gaseous fuel (biogas) at elevated temperatures

    NASA Astrophysics Data System (ADS)

    Pantskhava, E. S.

    Various bacterial systems that can be used to convert proteins, lipids, and polysaccharides into gaseous fuel (biogas) and thus to replace the diminishing sources of natural fuels are discussed. Consideration is given to the individual reaction stages (i.e., the hydrolytic, acidogenic, and methanogenic steps) of the anaerobic fermentation process that produces methane and CO2 from raw biochemicals and to particular bacterial cultures responsible for these reactions. Special attention is given to the effects of various conditions of culture maintenance, such as hydrogenation and the rate and the manner of substrate renewal, on the yield of CH4 in the industrial production of biogas.

  3. Aid for electrical contacting of high-temperature fuel cells and method for production thereof

    DOEpatents

    Becker, Ines; Schillig, Cora

    2014-03-18

    A double-sided adhesive metal-based tape for use as contacting aid for SOFC fuel cells is provided. The double-sided metal-based adhesive tape is suitable for simplifying the construction of cell bundles. The double-sided metal-based adhesive tape is used for electrical contacting of the cell connector with the anode and for electrical contacting of the interconnector of the fuel cells with the cell connector. A method for producing the double-sided adhesive metal-base tape is also provided.

  4. Silver-praseodymium oxy-sulfate cermet: A new composite cathode for intermediate temperature solid oxide fuel cells

    NASA Astrophysics Data System (ADS)

    Yang, Tao; Shaula, Aliaksandr L.; Mikhalev, Sergey M.; Ramasamy, Devaraj; Fagg, Duncan P.

    2016-02-01

    Ag-Pr2O2SO4 is identified as a promising new composite material to enhance the cathodic oxygen reduction reaction in solid oxide fuel cells. Ag-Pr2O2SO4 was studied in terms of synthesis, stability of Pr2O2SO4 in CO2, and electrochemical behavior as a cathode. The performance of the composite cathode was assessed as a function of temperature by A.C. impedance using a symmetrical cell arrangement in oxygen. The global performance of an anode-supported fuel cell Ag-Pr2O2SO4/CGO/NiO-CGO was also assessed, the highest power density being 1.5 W cm-2 at 800 °C. A longevity test of this cell performed at 800 °C under load for 24 days demonstrated high stability with Ag-Pr2O2SO4 cathode.

  5. Surface characterization of palladium–alumina sorbents for high-temperature capture of mercury and arsenic from fuel gas

    SciTech Connect

    Baltrus, John P.; Granite, Evan J.; Pennline, Henry W.; Stanko, Dennis; Hamilton, Hugh; Rowsell, Liz; Poulston, Stephen; Smith, Andrew; Chu, Wilson

    2010-06-01

    Coal gasification with subsequent cleanup of the resulting fuel gas is a way to reduce the impact of mercury and arsenic in the environment during power generation and on downstream catalytic processes in chemical production. The interactions of mercury and arsenic with Pd/Al2O3 model thin film sorbents and Pd/Al2O3 powders have been studied to determine the relative affinities of palladium for mercury and arsenic, and how they are affected by temperature and the presence of hydrogen sulfide in the fuel gas. The implications of the results on strategies for capturing the toxic metals using a sorbent bed are discussed.

  6. Combustion studies of coal-derived solid fuels. Part IV. Correlation of ignition temperatures from thermogravimetry and free-floating experiments

    USGS Publications Warehouse

    Rostam-Abadi, M.; DeBarr, J.A.; Chen, W.T.

    1992-01-01

    The usefulness of TG as an efficient and practical method to characterize the combustion properties of fuels used in large-scale combustors is of considerable interest. Relative ignition temperatures of a lignite, an anthracite, a bituminous coal and three chars derived from this coal were measured by a free-floating technique. These temperatures were correlated with those estimated from TG burning profiles of the fuels. ?? 1992.

  7. Degradation analysis of anode-supported intermediate temperature-solid oxide fuel cells under various failure modes

    NASA Astrophysics Data System (ADS)

    Lee, Tae-Hee; Park, Ka-Young; Kim, Ji-Tae; Seo, Yongho; Kim, Ki Buem; Song, Sun-Ju; Park, Byoungnam; Park, Jun-Young

    2015-02-01

    This study focuses on mechanisms and symptoms of several simulated failure modes, which may have significant influences on the long-term durability and operational stability of intermediate temperature-solid oxide fuel cells (IT-SOFCs), including fuel/oxidation starvation by breakdown of fuel/air supply components and wet and dry cycling atmospheres. Anode-supported IT-SOFCs consisting of a Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF)-Nd0.1Ce0.9O2-δ (NDC) composite cathode with an NDC electrolyte on a Ni-NDC anode substrate are fabricated via dry-pressings followed by the co-firing method. Comprehensive and systematic research based on the failure mode and effect analysis (FMEA) of anode-supported IT-SOFCs is conducted using various electrochemical and physiochemical analysis techniques to extend our understanding of the major mechanisms of performance deterioration under SOFC operating conditions. The fuel-starvation condition in the fuel-pump failure mode causes irreversible mechanical degradation of the electrolyte and cathode interface by the dimensional expansion of the anode support due to the oxidation of Ni metal to NiO. In contrast, the BSCF cathode shows poor stability under wet and dry cycling modes of cathode air due to the strong electroactivity of SrO with H2O. On the other hand, the air-depletion phenomena under air-pump failure mode results in the recovery of cell performance during the long-term operation without the visible microstructural transformation through the reduction of anode overvoltage.

  8. Influence of temperature and atmosphere on the strength and elastic modulus of solid oxide fuel cell anode supports

    NASA Astrophysics Data System (ADS)

    Ni, De-Wei; Charlas, Benoit; Kwok, Kawai; Molla, Tesfaye Tadesse; Hendriksen, Peter Vang; Frandsen, Henrik Lund

    2016-04-01

    Solid Oxide Fuel Cells are subjected to significant stresses during production and operation. The various stress-generating conditions impose strength requirements on the cell components, and thus the mechanical properties of the critical load bearing materials at relevant operational conditions need to be characterized to ensure reliable operation. In this study, the effect of reduction temperature on microstructural stability, high temperature strength and elastic modulus of Ni-YSZ anode supports were investigated. The statistical distribution of strength was determined from a large number of samples (∼30) at each condition to ensure high statistical validity. It is revealed that the microstructure and mechanical properties of the Ni-YSZ strongly depend on the reduction temperature. Further studies were conducted to investigate the temperature dependence of the strength and elastic modulus for both the unreduced and reduced Ni(O)-YSZ anode supports. With increasing temperature, the strength and elastic modulus of the reduced Ni-YSZ specimens drop almost linearly. In contrast, the strength and elastic modulus of the unreduced NiO-YSZ remain almost constant over the investigated temperature range. Compared to the NiO-YSZ, a significantly lower strength and elastic modulus of the reduced Ni-YSZ is observed; while reduction leads to a remarkable increase in failure strain of the anode support.

  9. The effects of temperature and swimming speed on instantaneous fuel use and nitrogenous waste excretion of the Nile tilapia.

    PubMed

    Alsop, D H; Kieffer, J D; Wood, C M

    1999-01-01

    The effects of acclimation temperature (30 degrees, 20 degrees, and 15 degrees C) and swimming speed on the aerobic fuel use of the Nile tilapia (Oreochromis niloticus; 8-10 g, 8-9-cm fork length) were investigated using a respirometric approach. As acclimation temperature was decreased from 30 degrees C to 15 degrees C, resting oxygen consumption (Mo2) and carbon dioxide excretion (Mco2) decreased approximately twofold, while nitrogenous waste excretion (ammonia-N plus urea-N) decreased approximately fourfold. Instantaneous aerobic fuel usage was calculated from respiratory gas exchange. At 30 degrees C, resting Mo2 was fueled by 42% lipids, 27% carbohydrates, and 31% protein. At 15 degrees C, lipid use decreased to 21%, carbohydrate use increased greatly to 63%, and protein use decreased to 16%. These patterns at 30 degrees C and 15 degrees C in tilapia paralleled fuel use previously reported in rainbow trout acclimated to 15 degrees C and 5 degrees C, respectively. Temperature also had a pronounced effect on critical swimming speed (UCrit). Tilapia acclimated to 30 degrees C had a UCrit of 5.63+/-0. 06 body lengths/s (BL/s), while, at 20 degrees C, UCrit was significantly lower at 4.21+/-0.14 BL/s. Tilapia acclimated to 15 degrees C were unable or unwilling to swim. As tilapia swam at greater speeds, Mo2 increased exponentially; Mo2min and Mo2max were 5.8+/-0.6 and 21.2+/-1.5 micromol O2/g/h, respectively. Nitrogenous waste excretion increased to a lesser extent with swimming speed. At 30 degrees C, instantaneous protein use while swimming at 15 cm/s ( approximately 1.7 BL/s) was 23%, and at UCrit (5.6 BL/s), protein use dropped slightly to 17%. During a 48-h swim at 25 cm/s (2.7 BL/s, approximately 50% UCrit), Mo2 and urea excretion remained unchanged, while ammonia excretion more than doubled by 24 h and remained elevated 24 h later. These results revealed a shift to greater reliance on protein as an aerobic fuel during prolonged swimming. PMID:10438675

  10. Real-Time Remote Monitoring of Temperature and Humidity Within a Proton Exchange Membrane Fuel Cell Using Flexible Sensors

    PubMed Central

    Kuo, Long-Sheng; Huang, Hao-Hsiu; Yang, Cheng-Hao; Chen, Ping-Hei

    2011-01-01

    This study developed portable, non-invasive flexible humidity and temperature microsensors and an in situ wireless sensing system for a proton exchange membrane fuel cell (PEMFC). The system integrated three parts: a flexible capacitive humidity microsensor, a flexible resistive temperature microsensor, and a radio frequency (RF) module for signal transmission. The results show that the capacitive humidity microsensor has a high sensitivity of 0.83 pF%RH−1 and the resistive temperature microsensor also exhibits a high sensitivity of 2.94 × 10−3 °C−1. The established RF module transmits the signals from the two microsensors. The transmission distance can reach 4 m and the response time is less than 0.25 s. The performance measurements demonstrate that the maximum power density of the fuel cell with and without these microsensors are 14.76 mW·cm−2 and 15.90 mW·cm−2, with only 7.17% power loss. PMID:22164099

  11. Real-time remote monitoring of temperature and humidity within a proton exchange membrane fuel cell using flexible sensors.

    PubMed

    Kuo, Long-Sheng; Huang, Hao-Hsiu; Yang, Cheng-Hao; Chen, Ping-Hei

    2011-01-01

    This study developed portable, non-invasive flexible humidity and temperature microsensors and an in situ wireless sensing system for a proton exchange membrane fuel cell (PEMFC). The system integrated three parts: a flexible capacitive humidity microsensor, a flexible resistive temperature microsensor, and a radio frequency (RF) module for signal transmission. The results show that the capacitive humidity microsensor has a high sensitivity of 0.83 pF%RH(-1) and the resistive temperature microsensor also exhibits a high sensitivity of 2.94 × 10(-3) °C(-1). The established RF module transmits the signals from the two microsensors. The transmission distance can reach 4 m and the response time is less than 0.25 s. The performance measurements demonstrate that the maximum power density of the fuel cell with and without these microsensors are 14.76 mW·cm(-2) and 15.90 mW·cm(-2), with only 7.17% power loss. PMID:22164099

  12. Native and domestic browsers and grazers reduce fuels, fire temperatures, and acacia ant mortality in an African savanna.

    PubMed

    Kimuyu, Duncan M; Sensenig, Ryan L; Riginos, Corinna; Veblen, Kari E; Young, Truman P

    2014-06-01

    Despite the importance of fire and herbivory in structuring savanna systems, few replicated experiments have examined the interactive effects of herbivory and fire on plant dynamics. In addition, the effects of fire on associated ant-tree mutualisms have been largely unexplored. We carried out small controlled burns in each of 18 herbivore treatment plots of the Kenya Long-term Exclosure Experiment (KLEE), where experimentally excluding elephants has resulted in 42% greater tree densities. The KLEE design includes six different herbivore treatments that allowed us to examine how different combinations of megaherbivore wildlife, mesoherbivore wildlife, and cattle affect fire temperatures and subsequent loss of ant symbionts from Acacia trees. Before burning, we quantified herbaceous fuel loads and plant community composition. We tagged all trees, measured their height and basal diameter, and identified the resident ant species on each. We recorded weather conditions during the burns and used ceramic tiles painted with fire-sensitive paints to estimate fire temperatures at different heights and in different microsites (under vs. between trees). Across all treatments, fire temperatures were highest at 0-50 cm off the ground and hotter in the grass under trees than in the grassy areas between trees. Plots with more trees burned hotter than plots with fewer trees, perhaps because of greater fine woody debris. Plots grazed by wildlife and by cattle prior to burning had lower herbaceous fuel loads and experienced lower burn temperatures than ungrazed plots. Many trees lost their ant colonies during the burns. Ant survivorship differed by ant species and at the plot level was positively associated with previous herbivory (and lower fire temperatures). Across all treatments, ant colonies on taller trees were more likely to survive, but even some of the tallest trees lost their ant colonies. Our study marks a significant step in understanding the mechanisms that underlie the

  13. Pt and Pt-Ru/Carbon Nanotube Nanocomposites Synthesized in Supercritical Fluid as Electrocatalysts for Low-Temperature Fuel Cells

    SciTech Connect

    Lin, Yuehe; Cui, Xiaoli; Wang, Jun; Yen, Clive; Wai, Chien M.

    2006-06-01

    In recent years, the use of supercritical fluids (SCFs) for the synthesis and processing of nanomaterials has proven to be a rapid, direct, and clean approach to develop nanomaterials and nanocomposites. The application of supercritical fluid technology can result in products (and processes) that are cleaner, less expensive, and of higher quality than those that are produced using conventional technologies and solvents. In this work, carbon nanotube (CNT)-supported Pt and Pt-Ru nanoparticles catalysts have been synthesized in supercritical carbon dioxide (scCO2). The experimental results demonstrate that Pt, Pt-Ru/CNT nanocomposites synthesized in supercritical carbon dioxide are effective electrocatalysts for low-temperature fuel cells.

  14. Low-temperature plasma synthesis of carbon nanotubes and graphene based materials and their fuel cell applications.

    PubMed

    Wang, Qi; Wang, Xiangke; Chai, Zhifang; Hu, Wenping

    2013-12-01

    Carbon nanotubes (CNTs) and graphene, and materials based on these, are largely used in multidisciplinary fields. Many techniques have been put forward to synthesize them. Among all kinds of approaches, the low-temperature plasma approach is widely used due to its numerous advantages, such as highly distributed active species, reduced energy requirements, enhanced catalyst activation, shortened operation time and decreased environmental pollution. This tutorial review focuses on the recent development of plasma synthesis of CNTs and graphene based materials and their electrochemical application in fuel cells. PMID:23959435

  15. Peak metamorphic temperatures from Raman Spectroscopy on Carbonaceous Matter (RSCM) and δ18O and δ13C (carb) isotope composition of a major mélange zone in the South Norwegian Caledonides

    NASA Astrophysics Data System (ADS)

    Jakob, Johannes; Beyssac, Olivier; Boulvais, Philippe; Andersen, Torgeir B.

    2016-04-01

    A mélange in southern Norway comprises a matrix of garnet, mica- and black carbonaceous schists and phyllites of abyssal origin, interlayered with originally coarser grained siliciclastic metasediments, serpentinite conglomerates and sandstones, solitary metaperidotites and thin slivers of gneisses. Several models for the formation of the mélange have been suggested, including formation as a) an ophiolitic mélange formed during ophiolite obduction, b) an unconformable post-obduction transgressive sequence or c) a mélange formed during hyperextension along the pre-Caledonian margin of Baltica. In the past, the mélange has therefore not been treated as one single tectonic unit, but has been assigned to various tectonic positions with both outboard Iapetus and inboard Baltican origins. In this study we argue that the mélange occupies a tectonostratigraphic position below major Baltican basement nappe-complexes previously assigned to the Middle Allochthon. Furthermore, we present new consistent results on the peak metamorphic temperatures (T ˜ 500° C), based on RSCM, and a characteristic δ18Ocarb isotope composition (11-15.5 ‰ SMOW), both consistent for more than 250 km along strike of the mélange. δ13Ccarb values fall within three clusters around 1, ‑ 2 , and ‑ 7 ‰ (PDB), respectively. The stable isotope investigation presented here was carried out in order to explore if pre-Caledonian isotope signatures in various generations of carbonate veins and the early Ordovician fossils at Otta, could have been preserved through a later Caledonian metamorphic overprint. The results presented here however, suggest that re-equilibration of the carbonates took place in the Silurian, most likely coeval with peak metamorphism of ˜ 500° C at ˜ 420 Ma, and the main fabric development close to the base of the nappe-stack. Re-equilibration of the carbonates was assisted by the presence a pervasive static fluid, allowing for oxygen isotope exchange with the

  16. A Raman-Based Portable Fuel Analyzer

    NASA Astrophysics Data System (ADS)

    Farquharson, Stuart

    2010-08-01

    Fuel is the single most import supply during war. Consider that the US Military is employing over 25,000 vehicles in Iraq and Afghanistan. Most fuel is obtained locally, and must be characterized to ensure proper operation of these vehicles. Fuel properties are currently determined using a deployed chemical laboratory. Unfortunately, each sample requires in excess of 6 hours to characterize. To overcome this limitation, we have developed a portable fuel analyzer capable of determine 7 fuel properties that allow determining fuel usage. The analyzer uses Raman spectroscopy to measure the fuel samples without preparation in 2 minutes. The challenge, however, is that as distilled fractions of crude oil, all fuels are composed of hundreds of hydrocarbon components that boil at similar temperatures, and performance properties can not be simply correlated to a single component, and certainly not to specific Raman peaks. To meet this challenge, we measured over 800 diesel and jet fuels from around the world and used chemometrics to correlate the Raman spectra to fuel properties. Critical to the success of this approach is laser excitation at 1064 nm to avoid fluorescence interference (many fuels fluoresce) and a rugged interferometer that provides 0.1 cm-1 wavenumber (x-axis) accuracy to guarantee accurate correlations. Here we describe the portable fuel analyzer, the chemometric models, and the successful determination of these 7 fuel properties for over 100 unknown samples provided by the US Marine Corps, US Navy, and US Army.

  17. High temperature corrosion of metallic materials in molten carbonate fuel cells environment

    NASA Astrophysics Data System (ADS)

    Durante, G.; Vegni, S.; Capobianco, P.; Golgovici, F.

    Molten carbonate fuel cells (MCFCs) are electrochemical devices that convert energy of a chemical reaction into electricity without any kind of combustion. So, MCFCs are promising for their high efficiency and their low environmental pollution. A limiting aspect for reaching the goal of 40,000 h of life-time is the corrosion of metallic parts of MCFC, especially for current collectors and separator plates. Generally, this corrosion leads to metal loss and to an important increase of the electrical resistance due to the formation of resistive oxides. One of the most critic components in a MCFC is the anodic side metallic components. More used choice for these components is actually a sheet of AISI310S cladded at both sides by a Ni layer. The analysis of the behaviour of this material after different steps of corrosion in a typical molten carbonate fuel cell environment could be important to understand some phenomena that cause the damage of the anodic current collector.

  18. Heavy fuels ash deposit formation and removal in watercooled high-temperature gas turbines

    SciTech Connect

    Blanton, J.C.; Durgin, G.A.; Palko, J.E.

    1983-01-01

    Experimental data obtained in heavy fuels operation of a gas turbine simulator with a water-cooled, transonic turbine nozzle cascade are presented. The ash fouling is characterized by the rate of decrease of the aerodynamic throat area. Particular attention is given to the cleanability of the ash deposits. A simple heat transfer analysis was performed to assist in evaluating the data. The rate of ash fouling in the water-cooled nozzle was found to be of the same order of magntude as for conventional air-cooled designs. Cleanability, both on and off-line, was found to be significantly enhanced, thus making the water-cooled gas turbine an attractive alternative for heavy fuels applications.

  19. Evaluating temperature and fuel stratification for heat-release rate control in a reactivity-controlled compression-ignition engine using optical diagnostics and chemical kinetics modeling

    SciTech Connect

    Musculus, Mark P. B.; Kokjohn, Sage L.; Reitz, Rolf D.

    2015-04-23

    We investigated the combustion process in a dual-fuel, reactivity-controlled compression-ignition (RCCI) engine using a combination of optical diagnostics and chemical kinetics modeling to explain the role of equivalence ratio, temperature, and fuel reactivity stratification for heat-release rate control. An optically accessible engine is operated in the RCCI combustion mode using gasoline primary reference fuels (PRF). A well-mixed charge of iso-octane (PRF = 100) is created by injecting fuel into the engine cylinder during the intake stroke using a gasoline-type direct injector. Later in the cycle, n-heptane (PRF = 0) is delivered through a centrally mounted diesel-type common-rail injector. This injection strategy generates stratification in equivalence ratio, fuel blend, and temperature. The first part of this study uses a high-speed camera to image the injection events and record high-temperature combustion chemiluminescence. Moreover, the chemiluminescence imaging showed that, at the operating condition studied in the present work, mixtures in the squish region ignite first, and the reaction zone proceeds inward toward the center of the combustion chamber. The second part of this study investigates the charge preparation of the RCCI strategy using planar laser-induced fluorescence (PLIF) of a fuel tracer under non-reacting conditions to quantify fuel concentration distributions prior to ignition. The fuel-tracer PLIF data show that the combustion event proceeds down gradients in the n-heptane distribution. The third part of the study uses chemical kinetics modeling over a range of mixtures spanning the distributions observed from the fuel-tracer fluorescence imaging to isolate the roles of temperature, equivalence ratio, and PRF number stratification. The simulations predict that PRF number stratification is the dominant factor controlling the ignition location and growth rate of the reaction zone. Equivalence ratio has a smaller, but still significant

  20. Potential Usage of Thermoelectric Devices in a High-Temperature Polymer Electrolyte Membrane (PEM) Fuel Cell System: Two Case Studies

    NASA Astrophysics Data System (ADS)

    Gao, Xin; Chen, Min; Andreasen, Søren Juhl; Kær, Søren Knudsen

    2012-06-01

    Methanol-fueled, high-temperature polymer electrolyte membrane fuel cell (HTPEMFC) power systems are promising as the next generation of vehicle engines, efficient and environmentally friendly. Currently, their performance still needs to be improved, and they still rely on a large Li-ion battery for system startup. In this article, to handle these two issues, the potential of thermoelectric (TE) devices applied in a HTPEMFC power system has been preliminarily evaluated. First, right after the fuel cell stack or the methanol reformer, thermoelectric generators (TEGs) are embedded inside a gas-liquid heat exchanger to form a heat recovery subsystem jointly for electricity production. It is calculated that the recovered power can increase the system efficiency and mitigate the dependence on Li-ion battery during system startup. To improve the TEG subsystem performance, a finite-difference model is then employed and two main parameters are identified. Second, TE coolers are integrated into the methanol steam reformer to regulate heat fluxes herein and improve the system dynamic performance. Similar modification is also done on the evaporator to improve its dynamic performance as well as to reduce the heat loss during system startup. The results demonstrate that the TE-assisted heat flux regulation and heat-loss reduction can also effectively help solve the abovementioned two issues. The preliminary analysis in this article shows that a TE device application inside HTPEMFC power systems is of great value and worthy of further study.