Science.gov

Sample records for gas emissions monitoring

  1. Architectural design of flue gas continuous emission monitoring system

    NASA Astrophysics Data System (ADS)

    Zhou, Hongfu; Jiang, Liangzhong; Tang, Yong; Yao, Xifan

    2008-10-01

    The paper presents the architectural design of flue gas continuous emission monitoring system, which uses computer, acquisition card and serial port communication card as hardware in the flue gas continuous emission monitoring system. In the CEMS, continuous emission monitoring system, it monitors dust in the flue gas, SO2, NOX, and some parameter on the flue gas emission, which includes mass flow, pressure, and temperature. For the software in the monitoring system, the research designs monitoring program in VC++, and realizes flue gas monitor with the architecture.

  2. [Monitoring gas concentration from carbon emissions by remote sensing].

    PubMed

    Wang, Li-Wen; Wei, Ya-Xing

    2012-06-01

    Global climate warming has become the focus question of international global climate change research, and is an important factor influencing world economy, political situation, and ecological environment. Produced carbon emission gases such as CO2, CH4, N2O, etc. caused by human activity are the main reason for global warming. In order to forecast future climate change and construct accurate carbon cycle model, monitoring accuracy of gas concentration from carbon emission must be improved. In the present paper, the newest progress in the international research results about monitoring gas concentration from carbon emissions by remote sensing was considered, monitoring method for carbon emissions was introduced, and remotely sensed monitoring technology about gas concentration from carbon emissions (including thermal infrared, sun spectrum, active remote sensing monitoring technology) was stated. In detail, several present and future satellite sensors were introduced (including TOVS, AIRS, IASI, SCIAMACHY, GOSAT, OCO, A-SCOPE and ASCENDS), and monitoring results achieved by these sensors were analyzed. PMID:22870656

  3. Monitoring soil greenhouse gas emissions from managed grasslands

    NASA Astrophysics Data System (ADS)

    Díaz-Pinés, Eugenio; Lu, Haiyan; Butterbach-Bahl, Klaus; Kiese, Ralf

    2014-05-01

    Grasslands in Central Europe are of enormous social, ecological and economical importance. They are intensively managed, but the influence of different common practices (i.e. fertilization, harvesting) on the total greenhouse gas budget of grasslands is not fully understood, yet. In addition, it is unknown how these ecosystems will react due to climate change. Increasing temperatures and changing precipitation will likely have an effect on productivity of grasslands and on bio-geo-chemical processes responsible for emissions of carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O). In the frame of the TERENO Project (www.tereno.net), a long-term observatory has been implemented in the Ammer catchment, southern Germany. Acting as an in situ global change experiment, 36 big lysimeters (1 m2 section, 150 cm height) have been translocated along an altitudinal gradient, including three sites ranging from 600 to 860 meters above sea level. In addition, two treatments have been considered, corresponding to different management intensities. The overall aim of the pre-alpine TERENO observatory is improving our understanding of the consequences of climate change and management on productivity, greenhouse gas balance, soil nutritional status, nutrient leaching and hydrology of grasslands. Two of the sites are equipped with a fully automated measurement system in order to continuously and accurately monitor the soil-atmosphere greenhouse gas exchange. Thus, a stainless steel chamber (1 m2 section, 80 cm height) is controlled by a robotized system. The chamber is hanging on a metal structure which can move both vertically and horizontally, so that the chamber is able to be set onto each of the lysimeters placed on the field. Furthermore, the headspace of the chamber is connected with a gas tube to a Quantum Cascade Laser, which continuously measures CO2, CH4, N2O and H2O mixing ratios. The chamber acts as a static chamber and sets for 15 minutes onto each lysimeter

  4. Mass-spectrometer-based continuous emissions monitoring system for acid-gas emissions and DRE demonstration

    NASA Astrophysics Data System (ADS)

    Bartman, Candace D.; Connolly, Erin; Renfroe, Jim; Harlow, George

    1993-03-01

    The objective of the work presented here was to develop a technology for continuous measurement of stack gas emissions for compounds such as HCl, SO2, and NOx that was also capable of monitoring toxic hydrocarbons. The goal was to assure operators and local communities that the emission source is routinely operating in compliance with and well within the U.S. Environmental Protection Agency guidelines. A mass spectrometer-based continuous emissions monitoring system (CEMS) and its sample extraction system developed as a result of this work are described. Results of calibration drift, linearity, and accuracy tests for HCl, SO2, and NOx are presented. Results of CEMS tests are described that show the system has the performance capabilities necessary for a relatively inexpensive and frequent DRE demonstration.

  5. 40 CFR 60.107a - Monitoring of emissions and operations for fuel gas combustion devices.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... statement that there are no crossover or entry points for sour gas (high H2S content) to be introduced into... for fuel gas combustion devices. 60.107a Section 60.107a Protection of Environment ENVIRONMENTAL... Commenced After May 14, 2007 § 60.107a Monitoring of emissions and operations for fuel gas...

  6. 40 CFR 60.107a - Monitoring of emissions and operations for fuel gas combustion devices.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... statement that there are no crossover or entry points for sour gas (high H2S content) to be introduced into... for fuel gas combustion devices. 60.107a Section 60.107a Protection of Environment ENVIRONMENTAL... Commenced After May 14, 2007 § 60.107a Monitoring of emissions and operations for fuel gas...

  7. Sensor-based analyzer for continuous emission monitoring in gas pipeline applications

    SciTech Connect

    Schubert, P.F.; Sheridan, D.R.; Cooper, M.D.; Banchieri, A.J.

    1998-04-01

    Continuous emissions monitoring of gas turbine engines in pipeline service have typically been monitored using either laboratory derived instruments (CEMS), or predicted using data from low cost sensors on the engines and algorithms generated by mapping engine performance (PEMS). A new cost-effective system developed under a program sponsored by the Gas Research Institute (Chicago) combines the advantages of both systems to monitor engine emissions in gas transmission service. This hybrid system is a sensor-based analyzer that uses a sensor array, including a newly developed NO{sub x} sensor, to directly monitor NO{sub x}, CO, and O{sub 2} emissions at the stack. The gases are measured hot and wet. The new systems were installed and tested on a gas-fired Rolls Royce Spey turbine engine and on Ingersoll-Rand KVG-410 and Cooper GMVH-10 reciprocating engines in gas transmission service. These systems passed the Relative Accuracy Test (Part B) required under US EPA regulations (40 CFR 60).

  8. Monitoring of Emissions from Natural Gas Production Facilities in Barnett Shale Area for Population Exposure Assessment

    NASA Astrophysics Data System (ADS)

    Zielinska, B.; Fujita, E.; Campbell, D.; Samburova, V.; Hendler, E.; Beskid, C. S.

    2010-12-01

    The Barnett Shale study was conducted in April-May 2010 to provide a better understanding of population exposure to air toxics associated with gas production operations in the Barnett Shale region of North Texas. The Barnett Shale is a geological formation that stretches form Dallas to west of Fort Worth and southward, covering 5,000 square miles and 18 counties in the Fort Worth Basin. Oil and gas experts have suggested that it may be the largest onshore natural gas field in the US, containing not only natural gas but also condensate and light oil. Gas production wells in the Barnett Shale area number in the thousands and are spread over a large areas of North Texas. Emissions can occur during various stages in the life of any single well and along various points of the production stream from extraction of raw gas at the well to distribution of commercial grade natural gas at central gathering and processing plants. In the first phase of this study we characterized the emissions from major gas production facilities in the area. An initial survey was performed using a mobile sampling vehicle to identify facilities with measurable emissions. Source-oriented volatile organic compounds (VOC) samples were collected at several facilities with confirmed emissions measured with our continuous survey monitors. In the second phase we conducted saturation monitoring (multiple fixed-ambient sampling locations using passive sampling systems) downwind of gas production areas. One location was near a well with emissions from condensate tanks that were well characterized during Phase 1. A single private residence was located a short distance downwind of this well and was away from other emission sources that might interfere with the measured gradient of emissions from the well. The measurement at this site serves as a case study of the pollutant gradient from a well characterized emission source at various distances downwind of the source relative to the upwind pollutant

  9. Use of UAVs for greenhouse gas monitoring at hotspot emissions zones

    NASA Astrophysics Data System (ADS)

    Pitt, J. R.; Allen, G.; Mead, M. I.; Hollingsworth, P.; Kabbabe, K.; Roberts, G.; Shallcross, D. E.

    2015-12-01

    Measuring greenhouse gas emissions from individual localised sources, or "hotspots", is important for both compliance monitoring and validating the techniques used to compile national emission inventories. Frequently ground based techniques are used, such as flux chamber measurements, which suffer from issues regarding sample representativeness, and tracer release methods, which for area sources rely heavily on release site configuration. Obtaining vertically resolved data can enable the use of a mass balance method to calculate greenhouse gas fluxes. This has been achieved using remote sensing techniques, but this usually requires the deployment of expensive, bulky instrumentation. Here we evaluate the suitability of using UAVs, in conjunction with emerging miniaturised sensor technology, as a highly manoeuvrable, low cost alternative for measuring hotspot greenhouse gas emissions. We describe a case study performed at a UK landfill site, where greenhouse gas measurements made on board a fixed wing UAV were used to estimate the bulk CH4 emission rate. Details of the mass balance technique employed, along with the key uncertainties associated with it, are discussed. This work is part of an ongoing study at the University of Manchester into the application of UAVs in atmospheric research, with the rapid advancement in miniaturised sensor technology providing new opportunities for integrating trace gas measurement with existing lightweight UAVs.

  10. Novel microelectrode-based online system for monitoring N2O gas emissions during wastewater treatment.

    PubMed

    Marques, Ricardo; Oehmen, Adrian; Pijuan, Maite

    2014-11-01

    Clark-type nitrous oxide (N2O) microelectrodes are commonly used for measuring dissolved N2O levels, but have not previously been tested for gas-phase applications, where the N2O emitted from wastewater systems can be directly quantified. In this study, N2O microelectrodes were tested and validated for online gas measurements, and assessed with respect to their temperature, gas flow, composition dependence, gas pressure, and humidity. An exponential correlation between temperature and sensor signal was found, whereas gas flow, composition, pressure, and humidity did not have any influence on the signal. Two of the sensors were tested at different N2O concentration ranges (0-422.3, 0-50, 0-10, and 0-2 ppmv N2O) and exhibited a linear response over each range. The N2O emission dynamics from two laboratory scale sequencing batch reactors performing ammonia or nitrite oxidation were also monitored using one of the microsensors and results were compared with two other analytical methods. Results show that N2O emissions were accurately described with these microelectrodes and support their application for assessing gaseous N2O emissions from wastewater treatment systems. Advantages of the sensors as compared to conventional measurement techniques include a wider quantification range of N2O fluxes, and a single measurement system that can assess both liquid and gas-phase N2O dynamics. PMID:25317738

  11. Continuous emission monitoring technologies applicable to the natural gas transmission industry. Topical report, September 1993-September 1994

    SciTech Connect

    1995-04-01

    All major sources of nitrogen oxide (NOx) and carbon monoxide (CO) emissions must obtain operating permits under Title V of the 1990 Clean Air Act Amendments. Each permit application must contain a plan for monitoring emissions that will demonstrate the source`s compliance with its permitted emission limits. Several established methods for demonstrating compliance are available, including the use of continuous emission monitoring (CEM) systems--sampling and analytical equipment that allows gaseous emissions to be measured directly and continuously. In response to pending regulations, the Gas Research Institute recently sponsored a study on the types of CEM systems currently available to the natural gas industry for continuously monitoring NOx and CO emissions. The report describes various advantages and disadvantages of using particular types of continuous monitoring equipment for reciprocating engines and gas turbines.

  12. Industrial SO2 emission monitoring through a portable multichannel gas analyzer with an optimized retrieval algorithm

    NASA Astrophysics Data System (ADS)

    Sun, Youwen; Liu, Cheng; Xie, Pinhua; Hartl, Andreas; Chan, Kalok; Tian, Yuan; Wang, Wei; Qin, Min; Liu, Jianguo; Liu, Wenqing

    2016-03-01

    SO2 variability over a large concentration range and interferences from other gases have been major limitations in industrial SO2 emission monitoring. This study demonstrates accurate industrial SO2 emission monitoring through a portable multichannel gas analyzer with an optimized retrieval algorithm. The proposed analyzer features a large dynamic measurement range and correction of interferences from other coexisting infrared absorbers such as NO, CO, CO2, NO2, CH4, HC, N2O, and H2O. The multichannel gas analyzer measures 11 different wavelength channels simultaneously to correct several major problems of an infrared gas analyzer including system drift, conflict of sensitivity, interferences among different infrared absorbers, and limitation of measurement range. The optimized algorithm uses a third polynomial instead of a constant factor to quantify gas-to-gas interference. Measurement results show good performance in the linear and nonlinear ranges, thereby solving the problem that the conventional interference correction is restricted by the linearity of the intended and interfering channels. The results imply that the measurement range of the developed multichannel analyzer can be extended to the nonlinear absorption region. The measurement range and accuracy are evaluated through experimental laboratory calibration. Excellent agreement was achieved, with a Pearson correlation coefficient (r2) of 0.99977 with a measurement range from approximately 5 to 10 000 ppmv and a measurement error of less than 2 %. The instrument was also deployed for field measurement. Emissions from three different factories were measured. The emissions of these factories have been characterized by different coexisting infrared absorbers, covering a wide range of concentration levels. We compared our measurements with commercial SO2 analyzers. Overall, good agreement was achieved.

  13. Mobile monitoring of fugitive methane emissions from natural gas consumer industries

    NASA Astrophysics Data System (ADS)

    Zhou, X.; Albertson, J. D.; Gaylord, A.; von Fischer, J.; Rudek, J.; Thoma, E. D.

    2015-12-01

    Natural gas is used as a feedstock for major industrial processes, such as ammonia and fertilizer production. However, fugitive methane emissions from many major end-use sectors of the natural gas supply chain have not been quantified yet. This presentation introduces new tools for estimating emission rates from mobile methane measurements, and examines results from recent field measurements conducted downwind of several industrial plants using a specialized vehicle equipped with fast response methane sensor. Using these data along with local meteorological data measured by a 3-D sonic anemometer, a Bayesian approach is applied to probabilistically infer methane emission rates based on a modified Gaussian dispersion model. Source rates are updated recursively with repeated traversals of the downwind methane plume when the vehicle was circling around the targeted facilities. Data from controlled tracer release experiments are presented and used to validate the approach. With access via public roads, this mobile monitoring method is able to quickly assess the emission strength of facilities along the sensor path. This work is developing the capacity for efficient regional coverage of potential methane emission rates in support of leak detection and mitigation efforts.

  14. Results of a survey of natural gas transmission companies operating continuous emission monitoring systems. Topical report, January-June 1994

    SciTech Connect

    1994-10-01

    A summary is presented to the results of a survey of continuous emission monitoring (CEM) systems operating on reciprocating engines and turbines of gas transmission companies. For this survey, three natural gas transmission companies were visited. Information on various aspects of CEM systems within the industry was gathered. It included characteristics of emission sources with emission reduction techniques where applied; CEM system outdoor shelters; monitoring techniques; costs; installation and startup; personnel training; operations and maintenance; performance evaluations and quality assurance; and data acquisition systems. The survey finds that the industry`s experience with CEM systems remains limited. Some recommendations are presented for the future, when the use of CEM systems may increase.

  15. 40 CFR 60.107a - Monitoring of emissions and operations for fuel gas combustion devices and flares.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... process heater, 60 ppmv and, if monitored according to § 60.107a(d), 0.060 lb/MMBtu; and (iii) For a co... for fuel gas combustion devices and flares. 60.107a Section 60.107a Protection of Environment... Modification Commenced After May 14, 2007 § 60.107a Monitoring of emissions and operations for fuel...

  16. 40 CFR 60.107a - Monitoring of emissions and operations for fuel gas combustion devices and flares.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... process heater, 60 ppmv and, if monitored according to § 60.107a(d), 0.060 lb/MMBtu; and (iii) For a co... for fuel gas combustion devices and flares. 60.107a Section 60.107a Protection of Environment... Modification Commenced After May 14, 2007 § 60.107a Monitoring of emissions and operations for fuel...

  17. Application network for monitoring of green house gas emission from lithosphere in Khibina territories

    NASA Astrophysics Data System (ADS)

    Asavin, Alex; Nivin, Valentin; Litvinov, Artur; Chesalova, Elena; Baskov, Sergey

    2015-04-01

    The aim of project is to estimate the contribution of lithospheric flue gas emission of gases CH4, CO2, H2 in the general composition of atmospheric pollution of Arctic zone. The main task is organization of the ecological monitoring in the area of exploitation of large apatite and rare earth ore deposit from Khibine massive on the base of modern WSN (wireless sensor network) technologies. Application network consist from sensors of gas H2, CH4, CO2, complex autonomous equipment for measurement temperature, pressure, humidity and network of telecommunications (used ZigBee protocol). Our project offer technical decisions for experimentally-methodical monitoring network on the base of WSN and the high-sensitive sensors of hydrogen and methane, software and electronic equipment with a transmitter network. This work is the first project in Russia. The advantages of this technology is autonomous work (to several months and more), high-frequency programmable measurement of gas sensor, low cost (on one node of network), possibility to connect to one node of supervision a several types of sensors. And as a result is complex monitoring of environment. It has long been known that the pollution in Arctic Khibine and Lovosero region contains unusually high levels of hydrocarbon gases (HCG) [Petersilie,1964]. The presence of these gases has a number of practical implications and it is therefore important to understand their source and distribution. Among alkaline intrusive complexes with high (for magmatic rocks) concentrations of hydrocarbon and hydrogen- hydrocarbon gases occluded as fluid inclusions in minerals. The Khibina and Lovozero massives are well known, as region of spontaneous emissions of these gases from lithosphere [Khitarov et al., 1979; Ikorskii et al., 1992; Beeskow 2007; Nivin 2005, 2009]. The presence of the HCG, however, raises a number of questions and possibilities. It is unclear how homogeneously the HCG are distributed through the complex? What is the

  18. Acoustic monitoring of gas emissions from the seafloor. Part I: quantifying the volumetric flow of bubbles

    NASA Astrophysics Data System (ADS)

    Leblond, Isabelle; Scalabrin, Carla; Berger, Laurent

    2014-09-01

    Three decades of continuous ocean exploration have led us to identify subsurface fluid related processes as a key phenomenon in marine earth science research. The number of seep areas located on the seafloor has been constantly increasing with the use of multi-scale imagery techniques. Due to recent advances in transducer technology and computer processing, multibeam echosounders are now commonly used to detect submarine gas seeps escaping from the seafloor into the water column. A growing number of en- route surveys shows that sites of gas emissions escaping from the seafloor are much more numerous than previously thought. Estimating the temporal variability of the gas flow rate and volumes escaping from the seafloor has thus become a challenge of relevant interest which could be addressed by sea-floor continuous acoustic monitoring. Here, we investigate the feasibility of estimating the volumetric flow rates of gas emissions from horizontal backscattered acoustic signals. Different models based on the acoustic backscattering theory of bubbles are presented. The forward volume backscattering strength and the inversion volumetric flow rate solutions were validated with acoustic measurements from artificial gas flow rates generated in controlled sea-water tank experiments. A sensitivity analysis was carried out to investigate the behavior of the 120-kHz forward solution with respect to model input parameters (horizontal distance between transducer and bubble stream, bubble size distribution and ascent rate). The most sensitive parameter was found to be the distance of the bubble stream which can affect the volume backscattering strength by 20 dB within the horizontal range of 0-200 m. Results were used to derive the detection probability of a bubble stream for a given volume backscattering strength threshold according to different bubble flow rates and horizontal distance.

  19. An Air Plasma Off-Gas Emission Monitor (APO-GEM) For On-line Toxic Metal Monitoring

    NASA Astrophysics Data System (ADS)

    Miller, G. P.; Zhu, Z.; Baldwin, D. P.

    1998-10-01

    Increasing regulatory demands requiring significant reductions in the emission of hazardous air pollutants have led to the need for techniques capable of providing real-time monitoring of toxic metals in combustion gas streams. These waste streams range from coal-fired boilers, municipal waste combustors to plasma vitrification systems used for the remediation of low level radioactive waste. Our solution to this problem is the development of APO-GEM. This instrument incorporates an atmospheric-pressure inductively-coupled air plasma powered by a 3.5 kW solid-state 27.12 MHz rf generator coupled with an isokinetic sampling system. The detection system includes both a 1-m monochromator and a novel solid-state AOTF high-resolution spectrometer. The air plasma readily tolerates the introduction of combustion gases as well as the significant particle loading that can be present in exhaust streams. Plasma properties and performance characteristics, including results obtained recently at the DOE/EPA-sponsored Demonstration of Toxic Metal Continuous Emission Monitors, will be discussed.

  20. A greenhouse-gas information system monitoring and validating emissions reporting and mitigation

    SciTech Connect

    Jonietz, Karl K; Dimotakis, Paul E; Walker, Bruce C

    2011-09-26

    Current GHG-mitigating regimes, whether internationally agreed or self-imposed, rely on the aggregation of self-reported data, with limited checks for consistency and accuracy, for monitoring. As nations commit to more stringent GHG emissions-mitigation actions and as economic rewards or penalties are attached to emission levels, self-reported data will require independent confirmation that they are accurate and reliable, if they are to provide the basis for critical choices and actions that may be required. Supporting emissions-mitigation efforts and agreements, as well as monitoring energy- and fossil-fuel intensive national and global activities would be best achieved by a process of: (1) monitoring of emissions and emission-mitigation actions, based, in part, on, (2) (self-) reporting of pertinent bottom-up inventory data, (3) verification that reported data derive from and are consistent with agreed-upon processes and procedures, and (4) validation that reported emissions and emissions-mitigation action data are correct, based on independent measurements (top-down) derived from a suite of sensors in space, air, land, and, possibly, sea, used to deduce and attribute anthropogenic emissions. These data would be assessed and used to deduce and attribute measured GHG concentrations to anthropogenic emissions, attributed geographically and, to the extent possible, by economic sector. The validation element is needed to provide independent assurance that emissions are in accord with reported values, and should be considered as an important addition to the accepted MRV process, leading to a MRV&V process. This study and report focus on attributes of a greenhouse-gas information system (GHGIS) needed to support MRV&V needs. These needs set the function of such a system apart from scientific/research monitoring of GHGs and carbon-cycle systems, and include (not exclusively): the need for a GHGIS that is operational, as required for decision-support; the need for a

  1. The Mobile Monitoring of fugitive methane emissions from natural gas consumer industries

    EPA Science Inventory

    Natural gas is used as a feedstock for major industrial processes, such as ammonia and fertilizer production. However, fugitive methane emissions from many major end-use sectors of the natural gas supply chain have not been quantified yet. This presentation introduces new tools ...

  2. Mobile monitoring of fugitive methane emissions from natural gas consumer industries

    EPA Science Inventory

    Natural gas is used as a feedstock for major industrial processes, such as ammonia and fertilizer production. However, fugitive methane emissions from many major end-use sectors of the natural gas supply chain have not yet been well quantified. This presentation introduces new m...

  3. Detection and quantification of fugitive emissions from Colorado oil and gas production operations using remote monitoring

    EPA Science Inventory

    Western states contain vast amounts of oil and gas production. For example, Weld County Colorado contains approximately 25,000 active oil and gas well sites with associated production operations. There is little information on the air pollutant emission potential from this source...

  4. Application network for monitoring of green house gas emission from lithosphere in Khibina territories

    NASA Astrophysics Data System (ADS)

    Asavin, Alex; Nivin, Valentin; Litvinov, Artur; Chesalova, Elena; Baskov, Sergey

    2015-04-01

    The aim of project is to estimate the contribution of lithospheric flue gas emission of gases CH4, CO2, H2 in the general composition of atmospheric pollution of Arctic zone. The main task is organization of the ecological monitoring in the area of exploitation of large apatite and rare earth ore deposit from Khibine massive on the base of modern WSN (wireless sensor network) technologies. Application network consist from sensors of gas H2, CH4, CO2, complex autonomous equipment for measurement temperature, pressure, humidity and network of telecommunications (used ZigBee protocol). Our project offer technical decisions for experimentally-methodical monitoring network on the base of WSN and the high-sensitive sensors of hydrogen and methane, software and electronic equipment with a transmitter network. This work is the first project in Russia. The advantages of this technology is autonomous work (to several months and more), high-frequency programmable measurement of gas sensor, low cost (on one node of network), possibility to connect to one node of supervision a several types of sensors. And as a result is complex monitoring of environment. It has long been known that the pollution in Arctic Khibine and Lovosero region contains unusually high levels of hydrocarbon gases (HCG) [Petersilie,1964]. The presence of these gases has a number of practical implications and it is therefore important to understand their source and distribution. Among alkaline intrusive complexes with high (for magmatic rocks) concentrations of hydrocarbon and hydrogen- hydrocarbon gases occluded as fluid inclusions in minerals. The Khibina and Lovozero massives are well known, as region of spontaneous emissions of these gases from lithosphere [Khitarov et al., 1979; Ikorskii et al., 1992; Beeskow 2007; Nivin 2005, 2009]. The presence of the HCG, however, raises a number of questions and possibilities. It is unclear how homogeneously the HCG are distributed through the complex? What is the

  5. Continuous Monitoring of CH4 Emissions from Marcellus Shale Gas Extraction in South West Pennsylvania Using Top Down Methodology

    NASA Astrophysics Data System (ADS)

    Sarmiento, D. P.; Belmecheri, S.; Lauvaux, T.; Sowers, T. A.; Bryant, S.; Miles, N. L.; Richardson, S.; Aikins, J.; Sweeney, C.; Petron, G.; Davis, K. J.

    2012-12-01

    Natural gas extraction from shale formations via hydraulic-fracturing (fracking) is expanding rapidly in several regions of North America. In Pennsylvania, the number of wells drilled to extract natural gas from the Marcellus shale has grown from 195 in 2008 to 1,386 in 2010. The gas extraction process using the fracking technology results in the escape of methane (CH4), a potent greenhouse gas and the principal component of natural gas, into the atmosphere. Emissions of methane from fracking operations remain poorly quantified, leading to a large range of scenarios for the contribution of fracking to climate change. A mobile measurement campaign provided insights on methane leakage rates and an improved understanding of the spatio-temporal variability in active drilling areas in the South West of Pennsylvania. Two towers were then instrumented to monitor fugitive emissions of methane from well pads, pipelines, and other infrastructures in the area. The towers, one within a drilling region and one upwind of active drilling, measured atmospheric CH4 mixing ratios continuously. Isotopic measurements from air flasks were also collected. Data from the initial mobile campaign were used to estimate emission rates from single sites such as wells and compressor stations. Tower data will be used to construct a simple atmospheric inversion for regional methane emissions. Our results show the daily variability in emissions and allow us to estimate leakage rates over a one month period in South West Pennsylvania. We discuss potential deployment strategies in drilling zones to monitor emissions of methane over longer periods of time.

  6. Strategies to meet the challenges of monitoring greenhouse gas emissions in agriculture

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Quantifying and predicting soil carbon sequestration and greenhouse gas emissions from agricultural systems have been research goals for numerous institutions, especially since the turn of the millennium. Cost, time, and politics are variables that have limited the rapid development of robust quant...

  7. Diffuse gas emissions at the Ukinrek Maars, Alaska: Implications for magmatic degassing and volcanic monitoring

    USGS Publications Warehouse

    Evans, William C.; Bergfeld, D.; McGimsey, R.G.; Hunt, A.G.

    2009-01-01

    Diffuse CO2 efflux near the Ukinrek Maars, two small volcanic craters that formed in 1977 in a remote part of the Alaska Peninsula, was investigated using accumulation chamber measurements. High CO2 efflux, in many places exceeding 1000 g m-2 d-1, was found in conspicuous zones of plant damage or kill that cover 30,000-50,000 m2 in area. Total diffuse CO2 emission was estimated at 21-44 t d-1. Gas vents 3-km away at The Gas Rocks produce 0.5 t d-1 of CO2 that probably derives from the Ukinrek Maars basalt based on similar ??13C values (???-6???), 3He/4He ratios (5.9-7.2 RA), and CO2/3He ratios (1-2 ?? 109) in the two areas. A lower 3He/4He ratio (2.7 RA) and much higher CO2/3He ratio (9 ?? 1010) in gas from the nearest arc-front volcanic center (Mount Peulik/Ugashik) provide a useful comparison. The large diffuse CO2 emission at Ukinrek has important implications for magmatic degassing, subsurface gas transport, and local toxicity hazards. Gas-water-rock interactions play a major role in the location, magnitude and chemistry of the emissions.

  8. Fugitive emissions monitoring trends

    SciTech Connect

    Brown, K.H.

    1997-02-01

    New Clean Air Act requirements are pushing facilities to reevaluate their monitoring programs. A description of the fugitive emission guidelines is included in this article, along with ideas about monitoring.

  9. Industrial SO2 emissions monitoring using a portable multi-channel gas analyzer with an optimized retrieval algorithm

    NASA Astrophysics Data System (ADS)

    Sun, Y. W.; Liu, C.; Xie, P. H.; Hartl, A.; Chan, K. L.; Tian, Y.; Wang, W.; Qin, M.; Liu, J. G.; Liu, W. Q.

    2015-12-01

    In this paper, we demonstrate achieving accurate industrial SO2 emissions monitoring using a portable multi-channel gas analyzer with an optimized retrieval algorithm. The introduced analyzer features with large dynamic measurement range and correction of interferences from other co-existing infrared absorbers, e.g., NO, CO, CO2, NO2, CH4, HC, N2O and H2O. Both effects have been the major limitations of industrial SO2 emissions monitoring. The multi-channel gas analyzer measures 11 different wavelength channels simultaneously in order to achieve correction of several major problems of an infrared gas analyzer, including system drift, conflict of sensitivity, interferences among different infrared absorbers and limitation of measurement range. The optimized algorithm makes use of a 3rd polynomial rather than a constant factor to quantify gas-to-gas interference. The measurement results show good performance in both linear and nonlinear range, thereby solving the problem that the conventional interference correction is restricted by the linearity of both intended and interfering channels. The result implies that the measurement range of the developed multi-channel analyzer can be extended to the nonlinear absorption region. The measurement range and accuracy are evaluated by experimental laboratory calibration. An excellent agreement was achieved with a Pearson correlation coefficient (r2) of 0.99977 with measurement range from ~5 ppmv to 10 000 ppmv and measurement error <2 %. The instrument was also deployed for field measurement. Emissions from 3 different factories were measured. The emissions of these factories have been characterized with different co-existing infrared absorbers, covering a wide range of concentration levels. We compared our measurements with the commercial SO2 analyzers. The overall good agreements are achieved.

  10. Fugitive coke oven gas emission profile by continuous line averaged open-path Fourier transform infrared monitoring.

    PubMed

    Lin, Chitsan; Liou, Naiwei; Chang, Pao-Erh; Yang, Jen-Chin; Sun, Endy

    2007-04-01

    Although most coke oven research is focused on the emission of polycyclic aromatic hydrocarbons, well-known carcinogens, little has been done on the emission of volatile organic compounds, some of which are also thought to be hazardous to workers and the environment. To profile coke oven gas (COG) emissions, we set up an open-path Fourier transform infrared (OP-FTIR) system on top of a battery of coke ovens at a steel mill located in Southern Taiwan and monitored average emissions in a coke processing area for 16.5 hr. Nine COGs were identified, including ammonia, CO, methane, ethane, ethylene, acetylene, propylene, cyclohexane, and O-xylene. Time series plots indicated that the type of pollutants differed over time, suggesting that different emission sources (e.g., coke pushing, quench tower, etc.) were involved at different times over the study period. This observation was confirmed by the low cross-correlation coefficients of the COGs. It was also found that, with the help of meteorological analysis, the data collected by the OP-FTIR system could be analyzed effectively to characterize differences in the location of sources. Although the traditional single-point samplings of emissions involves sampling various sources in a coke processing area at several different times and is a credible profiling of emissions, our findings strongly suggest that they are not nearly as efficient or as cost-effective as the continuous line average method used in this study. This method would make it easier and cheaper for engineers and health risk assessors to identify and to control fugitive volatile organic compound emissions and to improve environmental health. PMID:17458466

  11. Study of Differential Column Measurements for Urban Greenhouse Gas Emission Monitoring

    NASA Astrophysics Data System (ADS)

    Chen, Jia; Hedelius, Jacob K.; Viatte, Camille; Jones, Taylor; Franklin, Jonathan E.; Parker, Harrison; Wennberg, Paul O.; Gottlieb, Elaine W.; Dubey, Manvendra K.; Wofsy, Steven C.

    2016-04-01

    Urban areas are home to 54% of the total global population and account for ˜ 70% of total fossil fuel emissions. Accurate methods for measuring urban and regional scale carbon fluxes are required in order to design and implement policies for emissions reduction initiatives. In this paper, we demonstrate novel applications of compact solar-tracking Fourier transform spectrometers (Bruker EM27/SUN) for differential measurements of the column-averaged dry-air mole fractions (DMFs) of CH4 and CO2 within urban areas. Our differential column method uses at least two spectrometers to make simultaneous measurements of CO2, CH4 and O2 column number densities. We then compute the column-averaged DMFs XG for a gas G and the differences ΔXG between downwind and upwind stations. By accurately measuring the small differences in integrated column amounts across local and regional sources, we directly observe the mass loading of the atmosphere due to the influence of emissions in the intervening locale. The inference of the source strength is much more direct than inversion modeling using only surface concentrations, and less subject to errors associated with modeling small-scale transport phenomena. We characterize the differential sensor system using Allan variance analysis and show that the differential column measurement has a precision of 0.01% for XCO2 and XCH4 using an optimum integration time of 10 min, which corresponds to standard deviations of 0.04 ppm, and 0.2 ppb, respectively. The sensor system is very stable over time and after relocation across the contiguous US, i.e. the scaling factors between the two Harvard EM27/SUNs and the measured instrument line function parameters are consistent. We use the differential column measurements to determine the emission of an area source. We measure the downwind minus upwind column gradient ΔXCH4 (˜ 2 ppb, 0.1%) across dairy farms in the Chino California area, and input the data to a simple column model for comparison with

  12. Automatic semi-continuous accumulation chamber for diffuse gas emissions monitoring in volcanic and non-volcanic areas

    NASA Astrophysics Data System (ADS)

    Lelli, Matteo; Raco, Brunella; Norelli, Francesco; Virgili, Giorgio; Continanza, Davide

    2016-04-01

    Since various decades the accumulation chamber method is intensively used in monitoring activities of diffuse gas emissions in volcanic areas. Although some improvements have been performed in terms of sensitivity and reproducibility of the detectors, the equipment used for measurement of gas emissions temporal variation usually requires expensive and bulky equipment. The unit described in this work is a low cost, easy to install-and-manage instrument that will make possible the creation of low-cost monitoring networks. The Non-Dispersive Infrared detector used has a concentration range of 0-5% CO2, but the substitution with other detector (range 0-5000 ppm) is possible and very easy. Power supply unit has a 12V, 7Ah battery, which is recharged by a 35W solar panel (equipped with charge regulator). The control unit contains a custom programmed CPU and the remote transmission is assured by a GPRS modem. The chamber is activated by DataLogger unit, using a linear actuator between the closed position (sampling) and closed position (idle). A probe for the measure of soil temperature, soil electrical conductivity, soil volumetric water content, air pressure and air temperature is assembled on the device, which is already arranged for the connection of others external sensors, including an automatic weather station. The automatic station has been tested on the field at Lipari island (Sicily, Italy) during a period of three months, performing CO2 flux measurement (and also weather parameters), each 1 hour. The possibility to measure in semi-continuous mode, and at the same time, the gas fluxes from soil and many external parameters, helps the time series analysis aimed to the identification of gas flux anomalies due to variations in deep system (e.g. onset of volcanic crises) from those triggered by external conditions.

  13. Acoustic monitoring of gas emissions from the seafloor. Part II: a case study from the Sea of Marmara

    NASA Astrophysics Data System (ADS)

    Bayrakci, Gaye; Scalabrin, Carla; Dupré, Stéphanie; Leblond, Isabelle; Tary, Jean-Baptiste; Lanteri, Nadine; Augustin, Jean-Marie; Berger, Laurent; Cros, Estelle; Ogor, André; Tsabaris, Christos; Lescanne, Marc; Géli, Louis

    2014-09-01

    A rotating, acoustic gas bubble detector, BOB (Bubble OBservatory) module was deployed during two surveys, conducted in 2009 and 2011 respectively, to study the temporal variations of gas emissions from the Marmara seafloor, along the North Anatolian Fault zone. The echosounder mounted on the instrument insonifies an angular sector of 7° during a given duration (of about 1 h). Then it rotates to the next, near-by angular sector and so forth. When the full angular domain is insonified, the "pan and tilt system" rotates back to its initial position, in order to start a new cycle (of about 1 day). The acoustic data reveal that gas emission is not a steady process, with observed temporal variations ranging between a few minutes and 24 h (from one cycle to the other). Echo-integration and inversion performed on the acoustic data as described in the companion paper of Leblond et al. (Mar Geophys Res, 2014), also indicate important variations in, respectively, the target strength and the volumetric flow rates of individual sources. However, the observed temporal variations may not be related to the properties of the gas source only, but reflect possible variations in sea-bottom currents, which could deviate the bubble train towards the neighboring sector. During the 2011 survey, a 4-component ocean bottom seismometer (OBS) was co-located at the seafloor, 59 m away from the BOB module. The acoustic data from our rotating, monitoring system support, but do not provide undisputable evidence to confirm, the hypothesis formulated by Tary et al. (2012), that the short-duration, non-seismic micro-events recorded by the OBS are likely produced by gas-related processes within the near seabed sediments. Hence, the use of a multibeam echosounder, or of several split beam echosounders should be preferred to rotating systems, for future experiments.

  14. Realtime Gas Emission Monitoring at Hazardous Sites Using a Distributed Point-Source Sensing Infrastructure.

    PubMed

    Manes, Gianfranco; Collodi, Giovanni; Gelpi, Leonardo; Fusco, Rosanna; Ricci, Giuseppe; Manes, Antonio; Passafiume, Marco

    2016-01-01

    This paper describes a distributed point-source monitoring platform for gas level and leakage detection in hazardous environments. The platform, based on a wireless sensor network (WSN) architecture, is organised into sub-networks to be positioned in the plant's critical areas; each sub-net includes a gateway unit wirelessly connected to the WSN nodes, hence providing an easily deployable, stand-alone infrastructure featuring a high degree of scalability and reconfigurability. Furthermore, the system provides automated calibration routines which can be accomplished by non-specialized maintenance operators without system reliability reduction issues. Internet connectivity is provided via TCP/IP over GPRS (Internet standard protocols over mobile networks) gateways at a one-minute sampling rate. Environmental and process data are forwarded to a remote server and made available to authenticated users through a user interface that provides data rendering in various formats and multi-sensor data fusion. The platform is able to provide real-time plant management with an effective; accurate tool for immediate warning in case of critical events. PMID:26805832

  15. Realtime Gas Emission Monitoring at Hazardous Sites Using a Distributed Point-Source Sensing Infrastructure

    PubMed Central

    Manes, Gianfranco; Collodi, Giovanni; Gelpi, Leonardo; Fusco, Rosanna; Ricci, Giuseppe; Manes, Antonio; Passafiume, Marco

    2016-01-01

    This paper describes a distributed point-source monitoring platform for gas level and leakage detection in hazardous environments. The platform, based on a wireless sensor network (WSN) architecture, is organised into sub-networks to be positioned in the plant’s critical areas; each sub-net includes a gateway unit wirelessly connected to the WSN nodes, hence providing an easily deployable, stand-alone infrastructure featuring a high degree of scalability and reconfigurability. Furthermore, the system provides automated calibration routines which can be accomplished by non-specialized maintenance operators without system reliability reduction issues. Internet connectivity is provided via TCP/IP over GPRS (Internet standard protocols over mobile networks) gateways at a one-minute sampling rate. Environmental and process data are forwarded to a remote server and made available to authenticated users through a user interface that provides data rendering in various formats and multi-sensor data fusion. The platform is able to provide real-time plant management with an effective; accurate tool for immediate warning in case of critical events. PMID:26805832

  16. A Greenhouse-Gas Information System: Monitoring and Validating Emissions Reporting and Mitigation

    SciTech Connect

    Jonietz, Karl K.; Dimotakis, Paul E.; Walker, Bruce C.

    2011-09-26

    This study and report focus on attributes of a greenhouse-gas information system (GHGIS) needed to support MRV&V needs. These needs set the function of such a system apart from scientific/research monitoring of GHGs and carbon-cycle systems, and include (not exclusively): the need for a GHGIS that is operational, as required for decision-support; the need for a system that meets specifications derived from imposed requirements; the need for rigorous calibration, verification, and validation (CV&V) standards, processes, and records for all measurement and modeling/data-inversion data; the need to develop and adopt an uncertainty-quantification (UQ) regimen for all measurement and modeling data; and the requirement that GHGIS products can be subjected to third-party questioning and scientific scrutiny. This report examines and assesses presently available capabilities that could contribute to a future GHGIS. These capabilities include sensors and measurement technologies; data analysis and data uncertainty quantification (UQ) practices and methods; and model-based data-inversion practices, methods, and their associated UQ. The report further examines the need for traceable calibration, verification, and validation processes and attached metadata; differences between present science-/research-oriented needs and those that would be required for an operational GHGIS; the development, operation, and maintenance of a GHGIS missions-operations center (GMOC); and the complex systems engineering and integration that would be required to develop, operate, and evolve a future GHGIS.

  17. Adaptation of an ambient ion monitor for detection of amines in gas and particulate agricultural emissions

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Volatile amines are emitted from many sources including agricultural facilities. Recent work has shown that amines may be important players in secondary aerosol formation. Because amine emissions are significantly lower than ammonia, previous measurements and emission studies at agricultural facilit...

  18. MONITORING OF INCINERATOR EMISSIONS

    EPA Science Inventory

    Monitoring of Incinerator Emissions is a chapter to be included in a book entitled Hazardous Waste Incineration, edited by A. Sarofim and D. Pershing, and published by John Wiley and Sons. he chapter describes stack sampling and analysis procedures in use on hazardous waste incin...

  19. EPA’s Hg Gas Traceability Approach for Source Emissions Measurement and Monitoring

    EPA Science Inventory

    Solicited presentation (special topic) at the International Conference on Mercury as a Global Pollutant on how EPA establishes the NIST traceability of reference materials used to support regulatory mercury emissions measurements.

  20. GREENHOUSE GAS (GHG) VERIFICATION GUIDELINE SERIES: ANR Pipeline Company PARAMETRIC EMISSIONS MONITORING SYSTEM (PEMS) VERSION 1.0

    EPA Science Inventory

    The Environmental Technology Verification report discusses the technology and performance of the Parametric Emissions Monitoring System (PEMS) manufactured by ANR Pipeline Company, a subsidiary of Coastal Corporation, now El Paso Corporation. The PEMS predicts carbon doixide (CO2...

  1. Acoustic emission monitoring system

    DOEpatents

    Romrell, Delwin M.

    1977-07-05

    Methods and apparatus for identifying the source location of acoustic emissions generated within an acoustically conductive medium. A plurality of acoustic receivers are communicably coupled to the surface of the medium at a corresponding number of spaced locations. The differences in the reception time of the respective sensors in response to a given acoustic event are measured among various sensor combinations prescribed by the monitoring mode employed. Acoustic reception response encountered subsequent to the reception by a predetermined number of the prescribed sensor combinations are inhibited from being communicated to the processing circuitry, while the time measurements obtained from the prescribed sensor combinations are translated into a position measurement representative of the location on the surface most proximate the source of the emission. The apparatus is programmable to function in six separate and five distinct operating modes employing either two, three or four sensory locations. In its preferred arrangement the apparatus of this invention will re-initiate a monitoring interval if the predetermined number of sensors do not respond to a particular emission within a given time period.

  2. Greenhouse gas emissions tool

    NASA Astrophysics Data System (ADS)

    Showstack, Randy

    2012-01-01

    Power plants were the largest stationary source of direct greenhouse gas (GHG) emissions in the United States in 2010, according to data from the Environmental Protection Agency's (EPA) GHG Reporting Program, the agency announced on 11 January. The GHG data set, which includes reports from more than 6700 facilities, provides information that the public can search to identify local sources of emissions and that businesses can use to track emissions. Gina McCarthy, assistant administrator for EPA's Office of Air and Radiation, said the program is “a transparent, powerful data resource available to the public” and that it provides “a critical tool” for businesses and others to find efficiencies to reduce emissions.

  3. CONTINUOUS EMISSION MONITORING DEMONSTRATION PROGRAM

    EPA Science Inventory

    Continuous emissions monitoring of hazardous and mixed waste thermal treatment processes is desired for verification of emission compliance, process control, and public safety perception. pecies of particular interest include trace metals and organic compounds resulting from inco...

  4. Continuous particulate monitoring for emission control

    SciTech Connect

    Bock, A.H. )

    1993-08-01

    An optical continuous particle monitoring system has been developed to overcome common problems associated with emissions monitoring equipment. Opacity monitors generally use a single- or double-pass system to analyze the presence of dust particles in the flue gas stream. The particles scatter and absorb light as it passes through the stack. As the particle content in the gas stream increases due to bag failure or some other problem, the amount of light that is blocked also increases. The opacity monitor compares the amount of lost light energy to the total energy of the light available and translates the signal to percentage of opacity. Opacity monitors are typically installed to meet the requirements set forth by pollution control agencies. Most opacity monitors are designed to meet all of the requirements of the Environmental Protection Agency (EPA) 40 CFR, Part 60, Appendix B, Performance Specification. The new continuous particle monitor (CPM) increases the accuracy of emission monitoring and overcomes typical problems found in conventional emission monitoring devices. The CPM is an optically based, calibratible, continuous dust monitor that uses a microprocessor, transmitter head, and receiver head. When calibrated with an isokinetic sample, a continuous readout of particulate concentration (in mg/m[sup 3]) in the exhaust gas is provided. The system can be used as a filter bag failure system or a long-term emission trend analyzer. Formal testing was conducted to evaluate the effectiveness of the optically based CPM. The monitor was calibrated using particles of a range of compositions, size distributions, and concentrations. The feasibility of using the instrument to measure particle concentration as low as 10 mg/m[sup 3] was examined.

  5. 40 CFR 60.73 - Emission monitoring.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... continuous monitoring system for measuring nitrogen oxides (NOX). The pollutant gas mixtures under Performance Specification 2 and for calibration checks under § 60.13(d) of this part shall be nitrogen dioxide... defined as any 3-hour period during which the average nitrogen oxides emissions (arithmetic average...

  6. Development and characterization of a mobile photoacoustic sensor for on-line soot emission monitoring in diesel exhaust gas.

    PubMed

    Beck, H A; Niessner, R; Haisch, C

    2003-04-01

    Upcoming regulations for vehicle exhaust emission demand substantial reduction of particle emission in diesel exhaust. To achieve these emission levels, the car manufacturing industry is developing new combustion concepts and exhaust after-treatment techniques such as the use of catalysts and particle filters. Many of the state-of-the-art analytical instruments do not meet the required detection limits, in combination with a high temporal resolution necessary for engine optimization. This paper reports a new detection system and the first results of its application to on-line diesel exhaust soot measurements on a engine test bench (MAN diesel engine facility Nürnberg, Germany). The instrument is based on differential photoacoustic (PA) spectroscopy of black carbon aerosol. It contains two identical PA cells, one for the measurement of the aerosol particles and one which analyses the particle-free gas. Thus, a potential cross-sensitivity to gaseous absorbers in the exhaust gas can be excluded. The PA cells were characterized in a laboratory set-up, with water vapor as reference gas and artificial soot generated by a spark discharge generator. The detection limit was found to be 2 microg m(-3) BC (for diesel soot) with a sampling rate of 3 Hz. The temporal response of the system was found to be in the order of 1 s. After full characterization of the cells, the system was transferred into a mobile 19"-rack. Characterization of the mobile sensor system under real-world conditions was performed during several measurement campaigns at an engine test bench for heavy-duty diesel engines. Results for the limit of detection, the time resolution, accuracy, repeatability, and robustness of the sensor system are very promising with regards to a routine application of the system in engine development. PMID:12733029

  7. Urban Greenhouse Gas Emissions Monitoring in Davos, Switzerland, Before, During and After the World Economic Forum Annual Meeting 2012

    NASA Astrophysics Data System (ADS)

    Jacobson, Gloria; Davis, Ken; Richardson, Scott; Miles, Natasha; Lauvaux, Thomas; Deng, Aijun; Calonder, Gian-Paul; Ruesch, Marc; Lehning, Michael; Bals, Andre; DeCola, Phil; Rella, Chris

    2013-04-01

    Efforts to reduce anthropogenic greenhouse gas emissions require validation. Atmospheric measurements capture all emissions, and provide a unique and powerful means of continuous validation and feedback. To demonstrate the utility of real time greenhouse gas measurements, in-situ GHG mixing ratio instruments were deployed in Davos, Switzerland to measure emissions from the city before, during and after the World Economic Forum (WEF). Three Instruments were deployed at two separate locations over 3 months (late December 2011 to February 2012). One site was located in the middle of the Davos urban area and a second site was located out of the valley in the surrounding mountains. Carbon Dioxide (CO2), Methane (CH4), Carbon Monoxide (CO) and water vapor (H2O) were measured continuously by Picarro G2401 instruments at both sites. Additionally, a Picarro flux analyzer was deployed in the city to evaluate the inverse fluxes. The mesoscale atmospheric model, WRF nudged to meteorological observations (WRF-FDDA), was used to simulate the transport of GHG over the valley of Davos at 1.3km resolution. A Mini Micro Pulse LiDAR (MiniMPL) from Sigma Space was deployed to evaluate the simulated planetary boundary layer depth from the WRF-FDDA model. The initial flux estimates for CO2 were constructed based on inventories reported for 2005. CO2 mixing ratio measurements prior to WEF suggest the difference between modeled (real-time) and inventory (annual) emissions to be on the order of +40%. The enhancement is likely due to the increased use of heating fuel in the winter. We present here the temporal variability in the inverse fluxes, which are correlated with a cold wave severely affecting Western Europe during the past winter, as well as changes in anthropogenic activities during the week of the WEF meeting. Also presented are new analyses of composite diurnal cycles of hourly CO/CO2 ratios, which provide additional information on the contributions of traffic relative to heating

  8. High-accuracy, high-precision, high-resolution, continuous monitoring of urban greenhouse gas emissions? Results to date from INFLUX

    NASA Astrophysics Data System (ADS)

    Davis, K. J.; Brewer, A.; Cambaliza, M. O. L.; Deng, A.; Hardesty, M.; Gurney, K. R.; Heimburger, A. M. F.; Karion, A.; Lauvaux, T.; Lopez-Coto, I.; McKain, K.; Miles, N. L.; Patarasuk, R.; Prasad, K.; Razlivanov, I. N.; Richardson, S.; Sarmiento, D. P.; Shepson, P. B.; Sweeney, C.; Turnbull, J. C.; Whetstone, J. R.; Wu, K.

    2015-12-01

    The Indianapolis Flux Experiment (INFLUX) is testing the boundaries of our ability to use atmospheric measurements to quantify urban greenhouse gas (GHG) emissions. The project brings together inventory assessments, tower-based and aircraft-based atmospheric measurements, and atmospheric modeling to provide high-accuracy, high-resolution, continuous monitoring of emissions of GHGs from the city. Results to date include a multi-year record of tower and aircraft based measurements of the urban CO2 and CH4 signal, long-term atmospheric modeling of GHG transport, and emission estimates for both CO2 and CH4 based on both tower and aircraft measurements. We will present these emissions estimates, the uncertainties in each, and our assessment of the primary needs for improvements in these emissions estimates. We will also present ongoing efforts to improve our understanding of atmospheric transport and background atmospheric GHG mole fractions, and to disaggregate GHG sources (e.g. biogenic vs. fossil fuel CO2 fluxes), topics that promise significant improvement in urban GHG emissions estimates.

  9. Monitoring Welding-Gas Quality

    NASA Technical Reports Server (NTRS)

    Huddleston, Kevin L.

    1988-01-01

    System monitors welding gas to ensure characteristics within predetermined values. Responds to changes that might go unnoticed by human operator and acts quickly to prevent weld defects. Electronic pressure controller employs various amounts of gain, equalization, and compensation to respond to changes in gas-supply pressure. Works in conjuction with pressure/oxygen/moisture monitor.

  10. Software solutions for emission monitoring

    SciTech Connect

    DeFriez, H.; Schillinger, S.; Seraji, H.

    1996-12-31

    Industry and state and federal environmental regulatory agencies are becoming ever more conciliatory due to the high cost of implementing the Clean Air Act Amendments of 1990 (CAAA) for the operation of Continuous Emissions Monitoring Systems (CEMS). In many cases the modifications do nothing to reduce emissions or even to measure the pollution, but simply let the source owner or operator and the permitting authority agree on a monitoring method and/or program. The EPA methods and standards developed under the Code of Federal Regulations (CFRs) have proven to be extremely costly and burdensome. Now, the USEPA and state agencies are making efforts to assure that emissions data has a strong technical basis to demonstrate compliance with regulations such as Title V.

  11. 40 CFR 60.73 - Emission monitoring.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Emission monitoring. 60.73 Section 60... Emission monitoring. (a) The source owner or operator shall install, calibrate, maintain, and operate a... measuring emissions with the continuous monitoring system concurrent with measuring emissions with...

  12. Continuous emission monitor for incinerators

    SciTech Connect

    Demirgian, J.

    1992-01-01

    This paper describes the development of Fourier transform infrared (FTIR) spectroscopy to continuous monitoring of incinerator emissions. Fourier transform infrared spectroscopy is well suited to this application because it can identify and quantify selected target analytes in a complex mixture without first separating the components in the mixture. Currently, there is no on-stream method to determine the destruction of hazardous substances, such as benzene, or to continuously monitor for hazardous products of incomplete combustion (PICs) in incinerator exhaust emissions. This capability is especially important because of Federal regulations in the Clean Air Act of 1990, which requires the monitoring of air toxics (Title III), the Resource Conservation and Recovery Act (RCRA), and the Toxic Substances Control Act (TSCA). An on-stream continuous emission monitor (CEM) that can differentiate species in the ppm and ppb range and can calculate the destruction and removal efficiency (DRE) could be used to determine the safety and reliability of incinerators. This information can be used to address reasonable public concern about incinerator safety and aid in the permitting process.

  13. Continuous emission monitor for incinerators

    SciTech Connect

    Demirgian, J.

    1992-07-01

    This paper describes the development of Fourier transform infrared (FTIR) spectroscopy to continuous monitoring of incinerator emissions. Fourier transform infrared spectroscopy is well suited to this application because it can identify and quantify selected target analytes in a complex mixture without first separating the components in the mixture. Currently, there is no on-stream method to determine the destruction of hazardous substances, such as benzene, or to continuously monitor for hazardous products of incomplete combustion (PICs) in incinerator exhaust emissions. This capability is especially important because of Federal regulations in the Clean Air Act of 1990, which requires the monitoring of air toxics (Title III), the Resource Conservation and Recovery Act (RCRA), and the Toxic Substances Control Act (TSCA). An on-stream continuous emission monitor (CEM) that can differentiate species in the ppm and ppb range and can calculate the destruction and removal efficiency (DRE) could be used to determine the safety and reliability of incinerators. This information can be used to address reasonable public concern about incinerator safety and aid in the permitting process.

  14. ENVIRONMENTAL TECHNOLOGY VERIFICATION REPORT ANR PIPELINE COMPANY PARAMETRIC EMISSIONS MONITORING SYSTEM (PEMS)

    EPA Science Inventory

    The Environmental Technology Verification report discusses the technology and performance of a gaseous-emissions monitoring system for large, natural-gas-fired internal combustion engines. The device tested is the Parametric Emissions Monitoring System (PEMS) manufactured by ANR ...

  15. 40 CFR 61.68 - Emission monitoring.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Vinyl Chloride § 61.68 Emission monitoring. (a) A vinyl chloride monitoring system is to be used to monitor on a... ducted in § 61.65 (b)(1)(ii), and (b)(2), (b)(5), (b)(6) (ii), and (b)(9)(ii). (b) The vinyl...

  16. 40 CFR 61.68 - Emission monitoring.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ...) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Vinyl Chloride § 61.68 Emission monitoring. (a) A vinyl chloride monitoring system is to be used to monitor on a... ducted in § 61.65 (b)(1)(ii), and (b)(2), (b)(5), (b)(6) (ii), and (b)(9)(ii). (b) The vinyl...

  17. 40 CFR 61.68 - Emission monitoring.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Vinyl Chloride § 61.68 Emission monitoring. (a) A vinyl chloride monitoring system is to be used to monitor on a... ducted in § 61.65 (b)(1)(ii), and (b)(2), (b)(5), (b)(6) (ii), and (b)(9)(ii). (b) The vinyl...

  18. 40 CFR 61.68 - Emission monitoring.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 9 2013-07-01 2013-07-01 false Emission monitoring. 61.68 Section 61.68 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Vinyl Chloride § 61.68 Emission monitoring. (a) A vinyl...

  19. Development of a tunable diode laser absorption sensor for online monitoring of industrial gas total emissions based on optical scintillation cross-correlation technique.

    PubMed

    Zhang, Zhirong; Pang, Tao; Yang, Yang; Xia, Hua; Cui, Xiaojuan; Sun, Pengshuai; Wu, Bian; Wang, Yu; Sigrist, Markus W; Dong, Fengzhong

    2016-05-16

    We report the first application of gas total emission using a DFB diode laser for gas concentration measurements combined with two LEDs for gas velocity measurements. In situ gas total emissions and particle density measurements in an industrial pipeline using simultaneous tunable diode laser absorption spectroscopy (TDLAS) and optical scintillation cross-correlation technique (OSCC) are presented. Velocity mean values obtained are 7.59 m/s (OSCC, standard deviation is 1.37 m/s) and 8.20 m/s (Pitot tube, standard deviation is 1.47 m/s) in a steel plant pipeline for comparison. Our experiments demonstrate that the combined system of TDLAS and OSCC provides a new versatile tool for accurate measurements of total gas emissions. PMID:27409967

  20. Gas House Autonomous System Monitoring

    NASA Technical Reports Server (NTRS)

    Miller, Luke; Edsall, Ashley

    2015-01-01

    Gas House Autonomous System Monitoring (GHASM) will employ Integrated System Health Monitoring (ISHM) of cryogenic fluids in the High Pressure Gas Facility at Stennis Space Center. The preliminary focus of development incorporates the passive monitoring and eventual commanding of the Nitrogen System. ISHM offers generic system awareness, adept at using concepts rather than specific error cases. As an enabler for autonomy, ISHM provides capabilities inclusive of anomaly detection, diagnosis, and abnormality prediction. Advancing ISHM and Autonomous Operation functional capabilities enhances quality of data, optimizes safety, improves cost effectiveness, and has direct benefits to a wide spectrum of aerospace applications.

  1. Trace Gas Monitoring

    NASA Technical Reports Server (NTRS)

    1976-01-01

    Space technology is contributing to air pollution control primarily through improved detectors and analysis methods. Miniaturized mass spectrometer is under development to monitor vinyl chloride and other hydrocarbon contaminants in an airborne laboratory. Miniaturized mass spectrometer can be used to protect personnel in naval and medical operations as well as aboard aircraft.

  2. 40 CFR 60.403 - Monitoring of emissions and operations.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... measurement of the pressure loss of the gas stream through the scrubber. The monitoring device must be... device. The monitoring device must be accurate within ±5 percent of design scrubbing liquid supply... operator of any affected phosphate rock facility using a wet scrubbing emission control device shall not...

  3. 40 CFR 60.403 - Monitoring of emissions and operations.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... measurement of the pressure loss of the gas stream through the scrubber. The monitoring device must be... device. The monitoring device must be accurate within ±5 percent of design scrubbing liquid supply... operator of any affected phosphate rock facility using a wet scrubbing emission control device shall not...

  4. 40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... for a NOX continuous emission monitoring system (CEMS) for each affected coal-fired unit, gas-fired... moisture content is needed to properly calculate the NOX emission rate in lb/mmBtu, e.g., if the...

  5. 40 CFR 60.49Da - Emission monitoring.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... affected unit that qualifies as a gas-fired or oil-fired unit, as defined in 40 CFR 72.2, may use, as an... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Emission monitoring. 60.49Da Section 60... Generating Units § 60.49Da Emission monitoring. (a) An owner or operator of an affected facility subject...

  6. 40 CFR 60.49Da - Emission monitoring.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... affected unit that qualifies as a gas-fired or oil-fired unit, as defined in 40 CFR 72.2, may use, as an... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Emission monitoring. 60.49Da Section 60... Generating Units § 60.49Da Emission monitoring. (a) An owner or operator of an affected facility subject...

  7. 40 CFR 60.264 - Emission monitoring.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Emission monitoring. 60.264 Section 60... Facilities § 60.264 Emission monitoring. (a) The owner or operator subject to the provisions of this subpart... opacity of emissions discharged into the atmosphere from the control device(s). (b) For the purpose...

  8. A continuous sampling air-ICP for metals emission monitoring

    SciTech Connect

    Baldwin, D.P.; Zamzow, D.S.; Eckels, D.E.; Miller, G.P.

    1999-09-19

    An air-inductively coupled plasma (air-ICP) system has been developed for continuous sampling and monitoring of metals as a continuous emission monitor (CEM). The plasma is contained in a metal enclosure to allow reduced-pressure operation. The enclosure and plasma are operated at a pressure slightly less than atmospheric using a Roots blower, so that sample gas is continuously drawn into the plasma. A Teflon sampling chamber, equipped with a sampling pump, is connected to the stack that is to be monitored to isokinetically sample gas from the exhaust line and introduce the sample into the air-ICP. Optical emission from metals in the sampled gas stream is detected and monitored using an acousto-optic tunable filter (AOTF)--echelle spectrometer system. A description of the continuous sampling air-ICP system is given, along with some preliminary laboratory data for continuous monitoring of metals.

  9. Continuous sampling air-ICP for metals emission monitoring

    NASA Astrophysics Data System (ADS)

    Baldwin, David P.; Zamzow, Daniel S.; Eckels, David E.; Miller, George P.

    1999-12-01

    An air-inductively coupled plasma (air-ICP) system has been developed for continuous sampling and monitoring of metals as a continuous emission monitor (CEM). The plasma is contained in a metal enclosure to allow reduced-pressure operation. The enclosure and plasma are operated at a pressure slightly less than atmospheric using a Roots blower, so that sample gas is continuously drawn into the plasma. A Teflon sampling chamber, equipped with a sampling pump, is connected to the stack that is to be monitored to isokinetically sample gas from the exhaust line and introduce the sample into the air-ICP. Optical emission from metals in the sampled gas stream is detected and monitored using an acousto-optic tunable filter (AOTF)-echelle spectrometer system. A description of the continuous sampling air-ICP system is given, along with some preliminary laboratory data for continuous monitoring of metals.

  10. 40 CFR 61.183 - Emission monitoring.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... CFR part 60. (2) Comply with the provisions of § 60.13(d) of 40 CFR part 60. (3) Except for system...) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Inorganic Arsenic Emissions From Arsenic Trioxide and Metallic Arsenic Production Facilities § 61.183 Emission monitoring....

  11. 40 CFR 61.183 - Emission monitoring.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... CFR part 60. (2) Comply with the provisions of § 60.13(d) of 40 CFR part 60. (3) Except for system...) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Inorganic Arsenic Emissions From Arsenic Trioxide and Metallic Arsenic Production Facilities § 61.183 Emission monitoring....

  12. 40 CFR 61.183 - Emission monitoring.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... CFR part 60. (2) Comply with the provisions of § 60.13(d) of 40 CFR part 60. (3) Except for system...) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Inorganic Arsenic Emissions From Arsenic Trioxide and Metallic Arsenic Production Facilities § 61.183 Emission monitoring....

  13. 40 CFR 61.183 - Emission monitoring.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... CFR part 60. (2) Comply with the provisions of § 60.13(d) of 40 CFR part 60. (3) Except for system...) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Inorganic Arsenic Emissions From Arsenic Trioxide and Metallic Arsenic Production Facilities § 61.183 Emission monitoring....

  14. EDITORIAL: Tropical deforestation and greenhouse gas emissions

    NASA Astrophysics Data System (ADS)

    Gibbs, Holly K.; Herold, Martin

    2007-10-01

    Carbon emissions from tropical deforestation have long been recognized as a key component of the global carbon budget, and more recently of our global climate system. Tropical forest clearing accounts for roughly 20% of anthropogenic carbon emissions and destroys globally significant carbon sinks (IPCC 2007). Global climate policy initiatives are now being proposed to address these emissions and to more actively include developing countries in greenhouse gas mitigation (e.g. Santilli et al 2005, Gullison et al 2007). In 2005, at the Conference of the Parties (COP) in Montreal, the United Nations Framework Convention on Climate Change (UNFCCC) launched a new initiative to assess the scientific and technical methods and issues for developing policy approaches and incentives to reduce emissions from deforestation and degradation (REDD) in developing countries (Gullison et al 2007). Over the last two years the methods and tools needed to estimate reductions in greenhouse gas emissions from deforestation have quickly evolved, as the scientific community responded to the UNFCCC policy needs. This focus issue highlights those advancements, covering some of the most important technical issues for measuring and monitoring emissions from deforestation and forest degradation and emphasizing immediately available methods and data, as well as future challenges. Elements for effective long-term implementation of a REDD mechanism related to both environmental and political concerns are discussed in Mollicone et al. Herold and Johns synthesize viewpoints of national parties to the UNFCCC on REDD and expand upon key issues for linking policy requirements and forest monitoring capabilities. In response to these expressed policy needs, they discuss a remote-sensing-based observation framework to start REDD implementation activities and build historical deforestation databases on the national level. Achard et al offer an assessment of remote sensing measurements across the world

  15. A Novel Infrared Gas Monitor

    NASA Astrophysics Data System (ADS)

    Wang, Yingding; Zhong, Hongjie

    2000-03-01

    In the paper a novel non-dispersive infrared(IR) gas monitor is described.It is based on the principle that certain gases absorb IR radiation at specific(and often unique) wavelengths.Conventional devices typically include several primary components:a broadband source, usually an incandescent filament,a rotating chopper shutter,a narrow-band filter,a sample tube and a detector. We have developed a number of IR light emitting diodes(LED) having narrow optical bandwidths and which can be intensity modulated by electrical means,for example InAsSbP(4.2 micron)LED.The IR LED can thus replace the thermal source,narrow-band filter and chopper assembly of the conventional IR gas monitor,yielding a solid state,low- powered,compact and almost maintenance-free instrument with high sensitivity and stability and which free of the effects of mechanical vibration too. The detector used in the IR gas monitor is the solid-state detector,such as PbS,PbSe, InSb,HgCdTe,TGS,LT and PZT detector etc. The different configuration of the IR gas monitor is designed.For example,two-path version for measuring methane concentration by monitoring the 3.31 micron absorption band,it can eliminate the interference effects,such as to compensate for LED intensity changes caused by power and temperature variations,and for signal fluctuations due to changes in detector bias. we also have designed portable single-beam version without the sample tube.Its most primary advantage is very cheap(about cost USD 30 ).It measures carbon dioxide concentration by monitoring the 4.25 micron absorption band.Thought its precisions is low,it is used to control carbon dioxide concentration in the air in the green houses and plastic houses(there are about twenty millon one in the China).Because more carbon dioxide will increase the quanity of vegetable and flower production to a greatextent. It also is used in medical,sanitary and antiepidemic applications,such as hospital, store,hotel,cabin and ballroom etc. Key words

  16. 40 CFR 60.273 - Emission monitoring.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Furnaces Constructed After October 21, 1974, and On or Before August 17, 1983 § 60.273 Emission monitoring... when the furnace is operating in the melting and refining period. All visible emissions observations... furnace static pressure monitoring device is not required on any EAF equipped with a DEC system...

  17. 40 CFR 60.273 - Emission monitoring.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Furnaces Constructed After October 21, 1974, and On or Before August 17, 1983 § 60.273 Emission monitoring... when the furnace is operating in the melting and refining period. All visible emissions observations... furnace static pressure monitoring device is not required on any EAF equipped with a DEC system...

  18. 40 CFR 60.273 - Emission monitoring.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Furnaces Constructed After October 21, 1974, and On or Before August 17, 1983 § 60.273 Emission monitoring... when the furnace is operating in the melting and refining period. All visible emissions observations... furnace static pressure monitoring device is not required on any EAF equipped with a DEC system...

  19. 40 CFR 60.273 - Emission monitoring.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Furnaces Constructed After October 21, 1974, and On or Before August 17, 1983 § 60.273 Emission monitoring... when the furnace is operating in the melting and refining period. All visible emissions observations... furnace static pressure monitoring device is not required on any EAF equipped with a DEC system...

  20. 40 CFR 60.273 - Emission monitoring.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Furnaces Constructed After October 21, 1974, and On or Before August 17, 1983 § 60.273 Emission monitoring... when the furnace is operating in the melting and refining period. All visible emissions observations... furnace static pressure monitoring device is not required on any EAF equipped with a DEC system...

  1. 76 FR 18415 - Continuous Emission Monitoring

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-04-04

    ... From the Federal Register Online via the Government Publishing Office ENVIRONMENTAL PROTECTION AGENCY 40 CFR Part 75 Continuous Emission Monitoring CFR Correction In Title 40 of the Code of Federal... read as follows: Sec. 75.11 Specific provisions for monitoring SO 2 emissions. * * * * * (f)...

  2. 40 CFR 60.264 - Emission monitoring.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 7 2012-07-01 2012-07-01 false Emission monitoring. 60.264 Section 60.264 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED... Facilities § 60.264 Emission monitoring. (a) The owner or operator subject to the provisions of this...

  3. 40 CFR 60.73 - Emission monitoring.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 7 2012-07-01 2012-07-01 false Emission monitoring. 60.73 Section 60.73 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED... Emission monitoring. (a) The source owner or operator shall install, calibrate, maintain, and operate...

  4. 40 CFR 60.264 - Emission monitoring.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Emission monitoring. 60.264 Section 60.264 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED... Facilities § 60.264 Emission monitoring. (a) The owner or operator subject to the provisions of this...

  5. 40 CFR 60.73 - Emission monitoring.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Emission monitoring. 60.73 Section 60.73 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED... Emission monitoring. (a) The source owner or operator shall install, calibrate, maintain, and operate...

  6. 40 CFR 60.264 - Emission monitoring.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Emission monitoring. 60.264 Section 60.264 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED... Facilities § 60.264 Emission monitoring. (a) The owner or operator subject to the provisions of this...

  7. 40 CFR 60.264 - Emission monitoring.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Emission monitoring. 60.264 Section 60.264 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED... Facilities § 60.264 Emission monitoring. (a) The owner or operator subject to the provisions of this...

  8. 40 CFR 60.73 - Emission monitoring.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Emission monitoring. 60.73 Section 60.73 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED... Emission monitoring. (a) The source owner or operator shall install, calibrate, maintain, and operate...

  9. PIGC™ - A low cost fugitive emissions and methane detection system using advanced gas filter correlation techniques for local and wide area monitoring

    NASA Astrophysics Data System (ADS)

    Lachance, R. L.; Gordley, L. L.; Marshall, B. T.; Fisher, J.; Paxton, G.; Gubeli, J. F.

    2015-12-01

    Currently there is no efficient and affordable way to monitor gas releases over small to large areas. We have demonstrated the ability to accurately measure key greenhouse and pollutant gasses with low cost solar observations using the breakthrough sensor technology called the "Pupil Imaging Gas Correlation", PIGC™, which provides size and complexity reduction while providing exceptional resolution and coverage for various gas sensing applications. It is a practical implementation of the well-known Gas Filter Correlation Radiometry (GFCR) technique used for the HALOE and MOPITT satellite instruments that were flown on successful NASA missions in the early 2000s. This strong space heritage brings performance and reliability to the ground instrument design. A methane (CH4) abundance sensitivity of 0.5% or better of ambient column with uncooled microbolometers has been demonstrated with 1 second direct solar observations. These under $10 k sensors can be deployed in precisely balanced autonomous grids to monitor the flow of chosen gasses, and infer their source locations. Measureable gases include CH4, 13CO2, N2O, NO, NH3, CO, H2S, HCN, HCl, HF, HDO and others. A single instrument operates in a dual operation mode, at no additional cost, for continuous (real-time 24/7) local area perimeter monitoring for the detection of leaks for safety & security needs, looking at an artificial light source (for example a simple 60 W light bulb placed 100 m away), while simultaneously allowing solar observation for quasi-continuous wide area total atmospheric column scanning (3-D) for environmental monitoring (fixed and mobile configurations). The second mode of operation continuously quantifies the concentration and flux of specific gases over different ground locations, determined the amount of targeted gas being released from the area or getting into the area from outside locations, allowing better tracking of plumes and identification of sources. This paper reviews the

  10. Dairy gas emissions model: reference manual

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The Dairy Gas Emissions Model (DairyGEM) is a software tool for estimating ammonia, hydrogen sulfide, and greenhouse gas (GHG) emissions of dairy production systems as influenced by climate and farm management. A production system is defined to include emissions during the production of all feeds wh...

  11. An automated SO2 camera system for continuous, real-time monitoring of gas emissions from Kīlauea Volcano's summit Overlook Crater

    NASA Astrophysics Data System (ADS)

    Kern, Christoph; Sutton, Jeff; Elias, Tamar; Lee, Lopaka; Kamibayashi, Kevan; Antolik, Loren; Werner, Cynthia

    2015-07-01

    SO2 camera systems allow rapid two-dimensional imaging of sulfur dioxide (SO2) emitted from volcanic vents. Here, we describe the development of an SO2 camera system specifically designed for semi-permanent field installation and continuous use. The integration of innovative but largely "off-the-shelf" components allowed us to assemble a robust and highly customizable instrument capable of continuous, long-term deployment at Kīlauea Volcano's summit Overlook Crater. Recorded imagery is telemetered to the USGS Hawaiian Volcano Observatory (HVO) where a novel automatic retrieval algorithm derives SO2 column densities and emission rates in real-time. Imagery and corresponding emission rates displayed in the HVO operations center and on the internal observatory website provide HVO staff with useful information for assessing the volcano's current activity. The ever-growing archive of continuous imagery and high-resolution emission rates in combination with continuous data from other monitoring techniques provides insight into shallow volcanic processes occurring at the Overlook Crater. An exemplary dataset from September 2013 is discussed in which a variation in the efficiency of shallow circulation and convection, the processes that transport volatile-rich magma to the surface of the summit lava lake, appears to have caused two distinctly different phases of lake activity and degassing. This first successful deployment of an SO2 camera for continuous, real-time volcano monitoring shows how this versatile technique might soon be adapted and applied to monitor SO2 degassing at other volcanoes around the world.

  12. 40 CFR 60.49Da - Emission monitoring.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... affected unit that qualifies as a gas-fired or oil-fired unit, as defined in 40 CFR 72.2, may use, as an... § 60.58b(i)(3) of subpart Eb of this part. (ii) Each 1-hour CO emissions average is calculated using... 40 Protection of Environment 7 2012-07-01 2012-07-01 false Emission monitoring. 60.49Da Section...

  13. 40 CFR 60.49Da - Emission monitoring.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... affected unit that qualifies as a gas-fired or oil-fired unit, as defined in 40 CFR 72.2, may use, as an... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Emission monitoring. 60.49Da Section 60... Generating Units for Which Construction is Commenced After September 18, 1978 § 60.49Da Emission...

  14. Magmatic gas scrubbing: Implications for volcano monitoring

    USGS Publications Warehouse

    Symonds, R.B.; Gerlach, T.M.; Reed, M.H.

    2001-01-01

    Despite the abundance of SO2(g) in magmatic gases, precursory increases in magmatic SO2(g) are not always observed prior to volcanic eruption, probably because many terrestrial volcanoes contain abundant groundwater or surface water that scrubs magmatic gases until a dry pathway to the atmosphere is established. To better understand scrubbing and its implications for volcano monitoring, we model thermochemically the reaction of magmatic gases with water. First, we inject a 915??C magmatic gas from Merapi volcano into 25??C air-saturated water (ASW) over a wide range of gas/water mass ratios from 0.0002 to 100 and at a total pressure of 0.1 MPa. Then we model closed-system cooling of the magmatic gas, magmatic gas-ASW mixing at 5.0 MPa, runs with varied temperature and composition of the ASW, a case with a wide range of magmatic-gas compositions, and a reaction of a magmatic gas-ASW mixture with rock. The modeling predicts gas and water compositions, and, in one case, alteration assemblages for a wide range of scrubbing conditions; these results can be compared directly with samples from degassing volcanoes. The modeling suggests that CO2(g) is the main species to monitor when scrubbing exists; another candidate is H2S(g), but it can be affected by reactions with aqueous ferrous iron. In contrast, scrubbing by water will prevent significant SO2(g) and most HCl(g) emissions until dry pathways are established, except for moderate HCl(g) degassing from pH 100 t/d (tons per day) of SO2(g) in addition to CO2(g) and H2S(g) should be taken as a criterion of magma intrusion. Finally, the modeling suggests that the interpretation of gas-ratio data requires a case-by-case evaluation since ratio changes can often be produced by several mechanisms; nevertheless, several gas ratios may provide useful indices for monitoring the drying out of gas pathways. Published by Elsevier Science B.V.

  15. Select a continuous emissions monitoring system

    SciTech Connect

    Walker, K.

    1996-02-01

    The Environmental Protection Agency (EPA) is incorporating flexibility in the new regulations it is writing to implement the monitoring requirements of Title VII of the Clean Air Act Amendments of 1990. These requirements are commonly known as compliance assurance monitoring (CAM), which is the new name for enhanced monitoring. The new flexibility being written into the CAM regulations is likely to result in reduced costs for industry and additional headaches for the engineer or manager responsible for implementing CAM. Continuous emissions monitoring systems (CEMS) were once the only choice available for continuous compliance monitoring. The primary monitoring strategies expected to be allowed under the CAM rules include not only CEMS, but also predictive emissions monitoring systems, parametric monitoring, and operation and maintenance recordkeeping. These four methods are discussed and compared.

  16. Parametric modeling of exhaust gas emission from natural gas fired gas turbines

    SciTech Connect

    Bakken, L.E.; Skogly, L.

    1996-07-01

    Increased focus on air pollution from gas turbines in the Norwegian sector of the North Sea has resulted in taxes on CO{sub 2}. Statements made by the Norwegian authorities imply regulations and/or taxes on NO{sub x} emissions in the near future. The existing CO{sub 2} tax of NOK 0.82/Sm{sup 3} (US Dollars 0.12/Sm{sup 3}) and possible future tax on NO{sub x} are analyzed mainly with respect to operating and maintenance costs for the gas turbine. Depending on actual tax levels, the machine should be operated on full load/optimum thermal efficiency or part load to reduce specific exhaust emissions. Based on field measurements, exhaust emissions (CO{sub 2}, CO, NO{sub x}, N{sub 2}O, UHC, etc.) are established with respect to load and gas turbine performance, including performance degradation. Different NO{sub x} emission correlations are analyzed based on test results, and a proposed prediction model presented. The impact of machinery performance degradation on emission levels is particularly analyzed. Good agreement is achieved between measured and predicted NO{sub x} emissions from the proposed correlation. To achieve continuous exhaust emission control, the proposed NO{sub x} model is implemented to the on-line condition monitoring system on the Sleipner A platform, rather than introducing sensitive emission sensors in the exhaust gas stack. The on-line condition monitoring system forms an important tool in detecting machinery condition/degradation and air pollution, and achieving optimum energy conservation.

  17. 40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Specific provisions for monitoring NOX... provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... for a NOX continuous emission monitoring system (CEMS) for each affected coal-fired unit,...

  18. 40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 16 2011-07-01 2011-07-01 false Specific provisions for monitoring NOX... provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... for a NOX continuous emission monitoring system (CEMS) for each affected coal-fired unit,...

  19. Acoustic emission monitoring of polymer composite materials

    NASA Technical Reports Server (NTRS)

    Bardenheier, R.

    1981-01-01

    The techniques of acoustic emission monitoring of polymer composite materials is described. It is highly sensitive, quasi-nondestructive testing method that indicates the origin and behavior of flaws in such materials when submitted to different load exposures. With the use of sophisticated signal analysis methods it is possible the distinguish between different types of failure mechanisms, such as fiber fracture delamination or fiber pull-out. Imperfections can be detected while monitoring complex composite structures by acoustic emission measurements.

  20. An automated SO2 camera system for continuous, real-time monitoring of gas emissions from Kīlauea Volcano's summit Overlook Crater

    USGS Publications Warehouse

    Kern, Christoph; Sutton, Jeff; Elias, Tamar; Lee, Robert Lopaka; Kamibayashi, Kevan P.; Antolik, Loren; Werner, Cynthia A.

    2015-01-01

    SO2 camera systems allow rapid two-dimensional imaging of sulfur dioxide (SO2) emitted from volcanic vents. Here, we describe the development of an SO2 camera system specifically designed for semi-permanent field installation and continuous use. The integration of innovative but largely “off-the-shelf” components allowed us to assemble a robust and highly customizable instrument capable of continuous, long-term deployment at Kīlauea Volcano's summit Overlook Crater. Recorded imagery is telemetered to the USGS Hawaiian Volcano Observatory (HVO) where a novel automatic retrieval algorithm derives SO2 column densities and emission rates in real-time. Imagery and corresponding emission rates displayed in the HVO operations center and on the internal observatory website provide HVO staff with useful information for assessing the volcano's current activity. The ever-growing archive of continuous imagery and high-resolution emission rates in combination with continuous data from other monitoring techniques provides insight into shallow volcanic processes occurring at the Overlook Crater. An exemplary dataset from September 2013 is discussed in which a variation in the efficiency of shallow circulation and convection, the processes that transport volatile-rich magma to the surface of the summit lava lake, appears to have caused two distinctly different phases of lake activity and degassing. This first successful deployment of an SO2 camera for continuous, real-time volcano monitoring shows how this versatile technique might soon be adapted and applied to monitor SO2 degassing at other volcanoes around the world.

  1. Monitoring the progress of emission inventories

    SciTech Connect

    Levy, J.A. Jr.; Solomon, D.; Husk, M.; Irving, B.; Kruger, D.; Levin. L.

    2006-12-15

    This issue of EM contains three articles which focus on the latest improvements on the emissions inventory process. The first, 'Building the national emissions inventory: challenges and plans for improvements' by Doug Solomon and Martin Husk (pages 8-11), looks at the US national emissions inventory. The next, 'Greenhouse gas inventories - a historical perspective and assessment of improvements since 1990' by Bill Irving and Dina Kruger (pages 12-19) assesses improvements in national and international greenhouse gas emissions inventories over the last 15 years. The third article, 'The global mercury emissions inventory' by Leonard Levin (pages 20-25) gives an overview of the challenges associated with conducting a worldwide inventory of mercury emissions.

  2. Magmatic gas scrubbing: implications for volcano monitoring

    NASA Astrophysics Data System (ADS)

    Symonds, R. B.; Gerlach, T. M.; Reed, M. H.

    2001-08-01

    Despite the abundance of SO 2(g) in magmatic gases, precursory increases in magmatic SO 2(g) are not always observed prior to volcanic eruption, probably because many terrestrial volcanoes contain abundant groundwater or surface water that scrubs magmatic gases until a dry pathway to the atmosphere is established. To better understand scrubbing and its implications for volcano monitoring, we model thermochemically the reaction of magmatic gases with water. First, we inject a 915°C magmatic gas from Merapi volcano into 25°C air-saturated water (ASW) over a wide range of gas/water mass ratios from 0.0002 to 100 and at a total pressure of 0.1 MPa. Then we model closed-system cooling of the magmatic gas, magmatic gas-ASW mixing at 5.0 MPa, runs with varied temperature and composition of the ASW, a case with a wide range of magmatic-gas compositions, and a reaction of a magmatic gas-ASW mixture with rock. The modeling predicts gas and water compositions, and, in one case, alteration assemblages for a wide range of scrubbing conditions; these results can be compared directly with samples from degassing volcanoes. The modeling suggests that CO 2(g) is the main species to monitor when scrubbing exists; another candidate is H 2S (g), but it can be affected by reactions with aqueous ferrous iron. In contrast, scrubbing by water will prevent significant SO 2(g) and most HCl (g) emissions until dry pathways are established, except for moderate HCl (g) degassing from pH<0.5 hydrothermal waters. Furthermore, it appears that scrubbing will prevent much, if any, SO 2(g) degassing from long-resident boiling hydrothermal systems. Several processes can also decrease or increase H 2(g) emissions during scrubbing making H 2(g) a poor choice to detect changes in magma degassing. We applied the model results to interpret field observations and emission rate data from four eruptions: (1) Crater Peak on Mount Spurr (1992) where, except for a short post-eruptive period, scrubbing appears

  3. Tropospheric Emissions: Monitoring of Pollution (TEMPO)

    NASA Astrophysics Data System (ADS)

    Chance, Kelly; Liu, Xiong; Suleiman, Raid M.; Flittner, David E.; Al-Saadi, Jassim; Janz, Scott J.

    2014-06-01

    TEMPO, selected by NASA as the first Earth Venture Instrument, will measure atmospheric pollution for greater North America from space using ultraviolet and visible spectroscopy. TEMPO measures from Mexico City to the Canadian oil sands, and from the Atlantic to the Pacific, hourly and at high spatial resolution. TEMPO provides a tropospheric measurement suite that includes the key elements of tropospheric air pollution chemistry. Measurements are from geostationary (GEO) orbit, to capture the inherent high variability in the diurnal cycle of emissions and chemistry. The small product spatial footprint resolves pollution sources at sub-urban scale. Together, this temporal and spatial resolution improves emission inventories, monitors population exposure, and enables effective emission-control strategies. TEMPO takes advantage of a GEO host spacecraft to provide a modest-cost mission that measures the spectra required to retrieve O3, NO2, SO2, H2CO, C2H2O2, H2O, aerosols, cloud parameters, and UVB radiation. TEMPO thus measures the major elements, directly or by proxy, in the tropospheric O3 chemistry cycle. Multi-spectral observations provide sensitivity to O3 in the lowermost troposphere, reducing uncertainty in air quality predictions by 50 %. TEMPO quantifies and tracks the evolution of aerosol loading. It provides near-real-time air quality products that will be made widely, publicly available. TEMPO makes the first tropospheric trace gas measurements from GEO, by building on the heritage of five spectrometers flown in low-earth-orbit (LEO). These LEO instruments measure the needed spectra, although at coarse spatial and temporal resolutions, to the precisions required for TEMPO and use retrieval algorithms developed for them by TEMPO Science Team members and currently running in operational environments. This makes TEMPO an innovative use of a well-proven technique, able to produce a revolutionary data set. TEMPO provides much of the atmospheric measurement

  4. Tropospheric Emissions: Monitoring of Pollution (TEMPO)

    NASA Astrophysics Data System (ADS)

    Chance, K.; Liu, X.; Suleiman, R. M.; Flittner, D. E.; Janz, S. J.

    2012-12-01

    TEMPO is a proposed concept to measure pollution for greater North America using ultraviolet/visible spectroscopy. TEMPO measures from Mexico City to the Canadian tar/oil sands, and from the Atlantic to the Pacific, hourly and at high spatial resolution (9 km2). TEMPO provides a tropospheric measurement suite that includes the key elements of tropospheric air pollution chemistry. Measurements are from geostationary (GEO) orbit, to capture the inherent high variability in the diurnal cycle of emissions and chemistry. The small product spatial footprint resolves pollution sources at sub-urban scale. Together, this temporal and spatial resolution improves emission inventories, monitors population exposure, and enables effective emission-control strategies. TEMPO takes advantage of a GEO host spacecraft to provide a modest cost mission that measures the spectra required to retrieve O3, NO2, SO2, H2CO, C2H2O2, H2O, aerosols, cloud parameters, and UVB radiation. TEMPO thus measures the major elements, directly or by proxy, in the tropospheric O3 chemistry cycle. Multi-spectral observations provide sensitivity to O3 in the lowermost troposphere, reducing uncertainty in air quality predictions by 50%. TEMPO quantifies and tracks the evolution of aerosol loading. It provides near-real-time air quality products that will be made widely, publicly available. TEMPO makes the first tropospheric trace gas measurements from GEO, by building on the heritage of five spectrometers flown in low-earth-orbit (LEO). These LEO instruments measure the needed spectra, although at coarse spatial and temporal resolutions, to the precisions required for TEMPO and use retrieval algorithms developed for them by TEMPO Science Team members and currently running in operational environments. This makes TEMPO an innovative use of a well proven technique, able to produce a revolutionary data set. TEMPO provides much of the atmospheric measurement capability recommended for GEO-CAPE in the 2007

  5. Tropospheric Emissions: Monitoring of Pollution (TEMPO)

    NASA Astrophysics Data System (ADS)

    Chance, K.; Liu, X.; Suleiman, R. M.; Flittner, D. E.; Al-Saadi, J. A.; Janz, S. J.; Tempo Science Team

    2013-05-01

    TEMPO has been selected by NASA as the first Earth Venture Instrument. It will measure atmospheric pollution for greater North America from space using ultraviolet/visible spectroscopy. TEMPO measures from Mexico City to the Canadian tar/oil sands, and from the Atlantic to the Pacific, hourly and at high spatial resolution (Mexico City is measured at 1.6 km N/S by 4.5 km E/W). TEMPO provides a tropospheric measurement suite that includes the key elements of tropospheric air pollution chemistry. Measurements are from geostationary (GEO) orbit, to capture the inherent high variability in the diurnal cycle of emissions and chemistry. The small product spatial footprint resolves pollution sources at sub-urban scale. Together, this temporal and spatial resolution improves emission inventories, monitors population exposure, and enables effective emission-control strategies. TEMPO takes advantage of a GEO host spacecraft to provide a modest cost mission that measures the spectra required to retrieve O3, NO2, SO2, H2CO, C2H2O2, H2O, aerosols, cloud parameters, and UVB radiation. TEMPO thus measures the major elements, directly or by proxy, in the tropospheric O3 chemistry cycle. Multi-spectral observations provide sensitivity to O3 in the lowermost troposphere, reducing uncertainty in air quality predictions by 50%. TEMPO quantifies and tracks the evolution of aerosol loading. It provides near-real-time air quality products that will be made widely, publicly available. TEMPO makes the first tropospheric trace gas measurements from GEO, by building on the heritage of five spectrometers flown in low-earth-orbit (LEO). These LEO instruments measure the needed spectra, although at coarse spatial and temporal resolutions, to the precisions required for TEMPO and use retrieval algorithms developed for them by TEMPO Science Team members and currently running in operational environments. This makes TEMPO an innovative use of a well proven technique, able to produce a revolutionary

  6. Method and apparatus for monitoring mercury emissions

    DOEpatents

    Durham, Michael D.; Schlager, Richard J.; Sappey, Andrew D.; Sagan, Francis J.; Marmaro, Roger W.; Wilson, Kevin G.

    1997-01-01

    A mercury monitoring device that continuously monitors the total mercury concentration in a gas. The device uses the same chamber for converting speciated mercury into elemental mercury and for measurement of the mercury in the chamber by radiation absorption techniques. The interior of the chamber is resistant to the absorption of speciated and elemental mercury at the operating temperature of the chamber.

  7. Method and apparatus for monitoring mercury emissions

    DOEpatents

    Durham, M.D.; Schlager, R.J.; Sappey, A.D.; Sagan, F.J.; Marmaro, R.W.; Wilson, K.G.

    1997-10-21

    A mercury monitoring device that continuously monitors the total mercury concentration in a gas. The device uses the same chamber for converting speciated mercury into elemental mercury and for measurement of the mercury in the chamber by radiation absorption techniques. The interior of the chamber is resistant to the absorption of speciated and elemental mercury at the operating temperature of the chamber. 15 figs.

  8. Greenhouse Gas Emissions from Dairy Farms

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The reduction of greenhouse gas emissions is becoming more important world-wide. Although research suggests that farm land can serve as a sink for carbon, animal production is also an important source of emissions. Thus, strategies must be designed to reduce or eliminate net emissions of greenhouse ...

  9. Emissions control for ground power gas turbines

    NASA Technical Reports Server (NTRS)

    Rudney, R. A.; Priem, R. J.; Juhasz, A. J.; Anderson, D. N.; Mroz, T. S.; Mularz, E. J.

    1977-01-01

    The similarities and differences of emissions reduction technology for aircraft and ground power gas turbines is described. The capability of this technology to reduce ground power emissions to meet existing and proposed emissions standards is presented and discussed. Those areas where the developing aircraft gas turbine technology may have direct application to ground power and those areas where the needed technology may be unique to the ground power mission are pointed out. Emissions reduction technology varying from simple combustor modifications to the use of advanced combustor concepts, such as catalysis, is described and discussed.

  10. Effluent Treatment Facility tritium emissions monitoring

    SciTech Connect

    Dunn, D.L.

    1991-07-25

    An Environmental Protection Agency (EPA) approved sampling and analysis protocol was developed and executed to verify atmospheric emissions compliance for the new Savannah River Site (SRS) F/H area Effluent Treatment Facility. Sampling equipment was fabricated, installed, and tested at stack monitoring points for filtrable particulate radionuclides, radioactive iodine, and tritium. The only detectable anthropogenic radionuclides released from Effluent Treatment Facility stacks during monitoring were iodine-129 and tritium oxide. This paper only examines the collection and analysis of tritium oxide.

  11. Reservoir Greenhouse Gas Emissions at Russian HPP

    SciTech Connect

    Fedorov, M. P.; Elistratov, V. V.; Maslikov, V. I.; Sidorenko, G. I.; Chusov, A. N.; Atrashenok, V. P.; Molodtsov, D. V.; Savvichev, A. S.; Zinchenko, A. V.

    2015-05-15

    Studies of greenhouse-gas emissions from the surfaces of the world’s reservoirs, which has demonstrated ambiguity of assessments of the effect of reservoirs on greenhouse-gas emissions to the atmosphere, is analyzed. It is recommended that greenhouse- gas emissions from various reservoirs be assessed by the procedure “GHG Measurement Guidelines for Fresh Water Reservoirs” (2010) for the purpose of creating a data base with results of standardized measurements. Aprogram for research into greenhouse-gas emissions is being developed at the St. Petersburg Polytechnic University in conformity with the IHA procedure at the reservoirs impounded by the Sayano-Shushenskaya and Mainskaya HPP operated by the RusHydro Co.

  12. Gas turbine combustion and emission control

    NASA Astrophysics Data System (ADS)

    Schetter, B.

    The fundamentals of combustion are discussed in the context of gaseous and liquid fuels and gas turbine fuels. Methods for reducing the emission of pollutants in gas turbines are considered. These emissions are carbon monoxide, unburnt hydrocarbons, smoke/soot, nitrogen oxides, sulphur oxides, and carbon dioxide. The focus is on nitrogen oxides. The general principles of combustor and burner design are considered: aero/can type combustors, silo combustors, and annular combustors. Premix and diffusion flames are discussed.

  13. Greenhouse Gas Emissions from Pasture

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Carbon dioxide, nitrous oxide, and methane are the primary greenhouse gases associated with global climate change. Livestock production’s contribution to carbon dioxide emissions is minimal, but it is a substantial contributor to both nitrous oxide and methane emissions. In both grazing and confin...

  14. EVALUATION OF HCL CONTINUOUS EMISSION MONITORS

    EPA Science Inventory

    This report presents the findings obtained from the field evaluation of commercially available HCl monitoring equipment at a municipal waste-fired boiler which was not equipped with HCl emission control equipment. The analyzers were operated continuously during a two-month test p...

  15. Greenhouse gas emissions from dairy farms

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The reduction of greenhouse gas emissions is becoming more important throughout the world. As a result, scientists and policymakers have sought cost-effective methods of reducing global emissions. One such proposed method is to sequester carbon in soil, particularly land used for agriculture. This p...

  16. Emissions from gas fired agricultural burners

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Because of the Federal Clean Air Act, the San Joaquin Valley Unified Air Pollution Control District (SJVUAPCD) began defining Best Available Control Technology (BACT) for NOx emissions from cotton gin drying system gas fired burners in its jurisdiction. The NOx emission levels of conventionally used...

  17. Effect of enhanced leachate recirculated (ELR) landfill operation and gas extraction on greenhouse gas emissions

    NASA Astrophysics Data System (ADS)

    Samir, Sonia

    The bioreactor/ enhanced leachate recirculated (ELR) landfill operation with the addition of moisture/ leachate to the landfill, accelerate the process of landfill waste decomposition; and increase the generation of LFG over a shorter period of time. Since emissions from the landfills are directly related to the gas generation, the increase in gas generation might also increase the emission from the landfill. On the contrary, the presence of gas extraction is suggested to mitigate the fugitive emissions from the landfills. Therefore, the motivation of the current study was to evaluate the effect of ELR operation as well as the gas extraction on the greenhouse gas emissions from the landfill. The current study was conducted in the City of Denton Landfill, Texas. Methane emission was investigated using a portable FID and static flux chamber technique from the landfill surface. Emission was measured from an ELR operated cell (cell 2) as well as a conventional cell (cell 0) in the City of Denton Landfill. Methane emission for cell 2 varied from 9544.3 ppm to 0 ppm while for cell 0, it varied from 0 ppm to 47 ppm. High spatial variations were observed during monitoring from both cells 0 and cell 2 which could be recognized as the variation of gas generation below the cover soil. The comparison between emissions from the slope and surface of the landfill showed that more methane emission occurred from the slopes than the top surface. In addition, the average landfill emission showed an increasing trend with increase in temperature and decreasing trend with increasing precipitation. The effect of ELR operation near the recirculation pipes showed a lag period between the recirculation and the maximum emission near the pipe. The emission near the pipe decreased after 1 day of recirculation and after the initial decrease, the emission started to increase and continued to increase up to 7 days after the recirculation. However, approximately after 10 days of recirculation, the

  18. Aircraft gas turbine emissions challenge

    SciTech Connect

    Koff, B.L. )

    1994-07-01

    The new generation of jet powered aircraft faces a significant challenge to reduce pollutant emissions while increasing fuel efficiency. Carbon monoxide (CO) and unburned hydrocarbon (HC) emissions are already very low and continued control of these pollutants is expected as engine temperatures and pressure ratios are increased. In contrast, significant system design improvements are needed to reduce oxides of nitrogen (NO[sub x]) emissions because of their harmful effect on the earth's ozone layer. This paper discusses the prospects and technical approaches for significant NO[sub x] reductions in current and future subsonic and supersonic aircraft.

  19. A STUDY TO EVALUATE CARBON MONOXIDE AND HYDROGEN SULFIDE CONTINUOUS EMISSION MONITORS AT AN OIL REFINERY

    EPA Science Inventory

    An eleven month field evaluation was done on five hydrogen sulfide and four carbon monoxide monitors located at an oil refinery. The hydrogen sulfide monitors sampled a fuel gas feed line and the carbon monoxide monitors sampled the emissions from a fluid cat cracker (FCC). Two o...

  20. Continuous Emissions Monitoring System Monitoring Plan for the Y-12 Steam Plant

    SciTech Connect

    2003-02-28

    The Oak Ridge Y-12 National Security Complex (Y-12), managed by BWXT, is submitting this Continuous Emissions Monitoring System (CEMS) Monitoring Plan in conformance with the requirements of Title 40 of the U.S. Code of Federal Regulations (CFR) Part 75. The state of Tennessee identified the Y-12 Steam Plant in Oak Ridge, Tennessee, as a non-electrical generation unit (EGU) nitrogen oxides (NO{sub x}) budget source as a result of the NO{sub x} State Implementation Plan (SIP) under the Tennessee Department of Environment and Conservation (TDEC) Rule 1200-3-27. Following this introduction, the monitoring plan contains the following sections: CEMS details, NO{sub x} emissions, and quality assurance (QA)/quality control (QC). The following information is included in the attachments: fuel and flue gas diagram, system layout, data flow diagrams, Electronic Monitoring Plan printouts, vendor information on coal and natural gas feed systems, and the Certification Test Protocol. The Y-12 Steam Plant consists of four Wickes boilers. Each is rated at a maximum heat input capacity of 296.8 MMBtu/hour or 250,000 lb/hour of 250-psig steam. Although pulverized coal is the principal fuel, each of the units can fire natural gas or a combination of coal and gas. Each unit is equipped with a Joy Manufacturing Company reverse air baghouse to control particulate emissions. Flue gases travel out of the baghouse, through an induced draft fan, then to one of two stacks. Boilers 1 and 2 exhaust through Stack 1. Boilers 3 and 4 exhaust through Stack 2. A dedicated CEMS will be installed in the ductwork of each boiler, downstream of the baghouse. The CEMS will be designed, built, installed, and started up by URS Group, Inc. (URS). Data acquisition and handling will be accomplished using a data acquisition and handling system (DAHS) designed, built, and programmed by Environmental Systems Corporation (ESC). The installed CEMS will continuously monitor NO{sub x}, flue gas flowrate, and carbon

  1. 76 FR 17287 - Protocol Gas Verification Program and Minimum Competency Requirements for Air Emission Testing

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-03-28

    ..., the Acid Rain Program, and the Clean Air Interstate Rule. EPA is amending its Protocol Gas... sections of the Acid Rain Program continuous emission monitoring system regulations by adding and..., 2008, revisions to 40 CFR part 75, the Acid Rain Program continuous emission monitoring...

  2. Acoustic emission monitoring of composite containment systems

    NASA Astrophysics Data System (ADS)

    Maguire, John R.

    2011-07-01

    This paper considers two different types of composite containment system, and two different types of acoustic emission (AE) monitoring approach. The first system is a composite reinforced pressure vessel (CRPV) which is monitored both during construction and in-service using a broadband modal acoustic emission (MAE) technique. The second system is a membrane cargo containment system which is monitored using both a global as well as a local AE technique. For the CRPV, the damage assessment is concerned mainly with the integrity of the composite outer layer at the construction stage, and possible fatigue cracking of the inner steel liner at the in-service stage. For the membrane tank, the damage assessment is concerned with locating and quantifying any abnormal porosities that might develop in-service. By comparing and contrasting the different types of structural system and different monitoring approaches inferences are drawn as to what role AE monitoring could take in the damage assessment of other types of composite containment system. (Detailed technical data have not been included, due to client confidentiality constraints.)

  3. Extractive sampling systems for continuous emissions monitors

    NASA Astrophysics Data System (ADS)

    White, John R.

    1991-04-01

    Continuous Emissions Monitoring systems (CEMs) have become an important part of the industrial, municipal, and infectious waste incineration industry. With the promulgation of stringent emissions limits and source emissions monitoring requirements, and with permit approvals and operating penalties dependent upon the accuracy and dependability of the CEM, most new and existing incineration facilities now recognize that the CEM system can often mean the difference between success and failure. Since the early 1980's, extractive sampling systems have been the technology of choice, due to the inherent difficulties in sampling from a typical incineration process. Some of these difficulties include: high temperatures, high particulate levels (dependent on the type of waste fuel being fired), the presence of acid-gases in the sample stream, high moisture levels, and wide fluctuations in the incineration process resulting in significant variations in emissions levels and sampling conditions. In addition, the requirement for lower emissions levels has resulted in the use of new control technologies which can often negatively affect the performance of a CEM system. A good example is the use of ammonia injection (either Selective Catalytic Reduction or Thermal DeNOx processes) for the control of NOx emissions, which results in an ammonia slip which can potentially interfere with the CEM measurement of either NOx or SO2 emissions. Extractive sampling systems, when designed to meet the specific application requirements and when assembled of reliable components constructed of the proper materials, have been proven in most difficult incineration installations. Extractive sampling systems offer the flexibility to overcome even the inherent difficulties usually encountered with industrial, municipal and infectious waste incinerators.

  4. Electrochemical NOx Sensor for Monitoring Diesel Emissions

    SciTech Connect

    Woo, L Y; Glass, R S

    2008-11-14

    Increasingly stringent emissions regulations will require the development of advanced gas sensors for a variety of applications. For example, compact, inexpensive sensors are needed for detection of regulated pollutants, including hydrocarbons (HCs), CO, and NO{sub x}, in automotive exhaust. Of particular importance will be a sensor for NO{sub x} to ensure the proper operation of the catalyst system in the next generation of diesel (CIDI) automobiles. Because many emerging applications, particularly monitoring of automotive exhaust, involve operation in harsh, high-temperature environments, robust ceramic-oxide-based electrochemical sensors are a promising technology. Sensors using yttria-stabilized zirconia (YSZ) as an oxygen-ion-conducting electrolyte have been widely reported for both amperometric and potentiometric modes of operation. These include the well-known exhaust gas oxygen (EGO) sensor. More recently, ac impedance-based (i.e., impedance-metric) sensing techniques using YSZ have been reported for sensing water vapor, hydrocarbons, CO, and NO{sub x}. Typically small-amplitude alternating signal is applied, and the sensor response is measured at a specified frequency. Most impedance-metric techniques have used the modulus (or magnitude) at low frequencies (< 1 Hz) as the sensing signal and attribute the measured response to interfacial phenomena. Work by our group has also investigated using phase angle as the sensing signal at somewhat higher frequencies (10 Hz). The higher frequency measurements would potentially allow for reduced sampling times during sensor operation. Another potential advantage of impedance-metric NO{sub x} sensing is the similarity in response to NO and NO{sub 2} (i.e., total-NO{sub x} sensing). Potentiometric NO{sub x} sensors typically show higher sensitivity to NO2 than NO, and responses that are opposite in sign. However, NO is more stable than NO{sub 2} at temperatures > 600 C, and thermodynamic calculations predict {approx}90

  5. Laboratory Connections. Gas Monitoring Transducers.

    ERIC Educational Resources Information Center

    Powers, Michael H.

    1988-01-01

    Discusses three types of sensors; pressure, gas detection, and relative humidity. Explains their use for laboratory measurements of gas pressure and detection of specific gaseous species. Shows diagrams of devices and circuits along with examples and applications including microcomputer interfacing. (RT)

  6. Mitigating greenhouse gas emissions: Voluntary reporting

    SciTech Connect

    1997-10-01

    The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report on their emissions of greenhouse gases, and on actions taken that have reduced or avoided emissions or sequestered carbon, to the Energy Information Administration (EIA). This, the second annual report of the Voluntary Reporting Program, describes information provided by the participating organizations on their aggregate emissions and emissions reductions, as well as their emissions reduction or avoidance projects, through 1995. This information has been compiled into a database that includes reports from 142 organizations and descriptions of 967 projects that either reduced greenhouse gas emissions or sequestered carbon. Fifty-one reporters also provided estimates of emissions, and emissions reductions achieved, for their entire organizations. The projects described actions taken to reduce emissions of carbon dioxide from energy production and use; to reduce methane and nitrous oxide emissions from energy use, waste management, and agricultural processes; to reduce emissions of halocarbons, such as CFCs and their replacements; and to increase carbon sequestration.

  7. Survey your options: Continuous emissions monitoring

    SciTech Connect

    White, J.R.

    1995-07-01

    In the US the public`s growing concern for air quality over the last twenty-five years has led to a complex patchwork of federal, state and local regulations aimed at controlling the emissions of pollutants from manufacturing facilities, power plants and municipal waste-incineration facilities. Like a shadow on the heels of a sprinter, the continuous emissions monitoring (CEM) industry has developed as a direct result of these regulations. In just two and a half decades, the CEM market has grown from a few specialized instrument firms to a billion-dollar business today--a remarkable feat considering there were few true CEM systems in existence prior to the enactment of the original US Clean Air Act of 1970. Despite the emergence of so many vendors offering so many different monitoring techniques, operators still face a host of complex issues when trying to select the right CEM. For facilities operating in today`s competitive, highly regulated environment, cost and performance pressures are stronger than ever. These pressures have forced CEM developers toward innovation to improve performance while containing capital and plant operating costs. This article provides an overview of the current status of CEM systems, and provides a glimpse at some of the new developments that will affect future monitoring configurations. Noteworthy new techniques include continuous emissions monitoring using Fourier Transform Infrared (FTIR) analyzers, laser-based opacity monitors, and the growing use of software-based, predictive CEMs. Also discussed is a new approach that overcomes the problems associated with measuring SO{sub 2} in fluegas streams downstream of NOx-reduction systems that use ammonia or urea injection.

  8. Life-cycle greenhouse gas emissions of shale gas, natural gas, coal, and petroleum.

    PubMed

    Burnham, Andrew; Han, Jeongwoo; Clark, Corrie E; Wang, Michael; Dunn, Jennifer B; Palou-Rivera, Ignasi

    2012-01-17

    The technologies and practices that have enabled the recent boom in shale gas production have also brought attention to the environmental impacts of its use. It has been debated whether the fugitive methane emissions during natural gas production and transmission outweigh the lower carbon dioxide emissions during combustion when compared to coal and petroleum. Using the current state of knowledge of methane emissions from shale gas, conventional natural gas, coal, and petroleum, we estimated up-to-date life-cycle greenhouse gas emissions. In addition, we developed distribution functions for key parameters in each pathway to examine uncertainty and identify data gaps such as methane emissions from shale gas well completions and conventional natural gas liquid unloadings that need to be further addressed. Our base case results show that shale gas life-cycle emissions are 6% lower than conventional natural gas, 23% lower than gasoline, and 33% lower than coal. However, the range in values for shale and conventional gas overlap, so there is a statistical uncertainty whether shale gas emissions are indeed lower than conventional gas. Moreover, this life-cycle analysis, among other work in this area, provides insight on critical stages that the natural gas industry and government agencies can work together on to reduce the greenhouse gas footprint of natural gas. PMID:22107036

  9. Destruction of acid gas emissions

    DOEpatents

    Mathur, Mahendra P.; Fu, Yuan C.; Ekmann, James M.; Boyle, John M.

    1991-01-01

    A method of destroying NO.sub.x and SO.sub.2 in a combustion gas in disclosed. The method includes generating active species by treating stable moleucles in a high temperature plasma. Ammonia, methane, steam, hydrogen, nitrogen or a combination of these gases can be selected as the stable molecules. The gases are subjected to plasma conditions sufficient to create free radicals, ions or excited atoms such as N, NH, NH.sub.2, OH.sup.-, CH and/or CH.sub.2. These active species are injected into a combustion gas at a location of sufficiently high temperature to maintain the species in active state and permit them to react with NO.sub.x and SO.sub.2. Typically the injection is made into the immediate post-combustion gases at temperatures of 475.degree.-950.degree. C.

  10. Destruction of acid gas emissions

    SciTech Connect

    Mathur, M.P.; Fu, Yuan C.; Ekmann, J.M.; Boyle, J.M.

    1990-12-31

    A method of destroying NO{sub x} and SO{sub x} in a combustion gas is disclosed. The method includes generating active species by treating stable molecules in a high temperature plasma. Ammonia, methane, steam, hydrogen, nitrogen or a combustion of these gases can be selected as the stable molecules. The gases are subjected to plasma conditions sufficient to create free radicals, ions or excited atoms such as N, NH, NH{sub 2}, OH, CH and/or CH{sub 2}. These active species are injected into a combustion gas at a location of sufficiently high temperature to maintain the species in active state and permit them to react with NO{sub x} and SO{sub x}. Typically the injection is made into the immediate post-combustion gases at temperatures of 475--950{degrees}C. 1 fig.

  11. Methane Gas Emissions - is Older Infrastructure Leakier?

    NASA Astrophysics Data System (ADS)

    Wendt, L. P.; Caulton, D.; Zondlo, M. A.; Lane, H.; Lu, J.; Golston, L.; Pan, D.

    2015-12-01

    Large gains in natural gas production from hydraulic fracturing is reinvigorating the US energy economy. It is a clean burning fuel with lower emissions than that of coal or oil. Studies show that methane (CH4) leaks from natural gas infrastructure vary widely. A broader question is whether leak rates of methane might offset the benefits of combustion of natural gas. Excess methane (CH4) is a major greenhouse gas with a radiative forcing constant of 25 times that of CO2 when projected over a 100-year period. An extensive field study of 250 wells in the Marcellus Shale conducted in July 2015 examined the emission rates of this region and identifed super-emitters. Spud production data will provide information as to whether older infrastructure is responsible for more of the emissions. Quantifying the emission rate was determined by extrapolating methane releases at a distance from private well pads using an inverse Gaussian plume model. Wells studied were selected by prevailing winds, distance from public roads, and topographical information using commercial (ARCGIS and Google Earth), non-profit (drillinginfo), and government (State of PA) databases. Data were collected from the mobile sensing lab (CH4, CO2 and H2O sensors), as well as from a stationary tower. Emission rates from well pads will be compared to their original production (spud dates) to evaluate whether infrastructure age and total production correlates with the observed leak rates. Very preliminary results show no statistical correlation between well pad production rates and observed leak rates.

  12. Estimating National-scale Emissions using Dense Monitoring Networks

    NASA Astrophysics Data System (ADS)

    Ganesan, A.; Manning, A.; Grant, A.; Young, D.; Oram, D.; Sturges, W. T.; Moncrieff, J. B.; O'Doherty, S.

    2014-12-01

    The UK's DECC (Deriving Emissions linked to Climate Change) network consists of four greenhouse gas measurement stations that are situated to constrain emissions from the UK and Northwest Europe. These four stations are located in Mace Head (West Coast of Ireland), and on telecommunication towers at Ridge Hill (Western England), Tacolneston (Eastern England) and Angus (Eastern Scotland). With the exception of Angus, which currently only measures carbon dioxide (CO2) and methane (CH4), the remaining sites are additionally equipped to monitor nitrous oxide (N2O). We present an analysis of the network's CH4 and N2O observations from 2011-2013 and compare derived top-down regional emissions with bottom-up inventories, including a recently produced high-resolution inventory (UK National Atmospheric Emissions Inventory). As countries are moving toward national-level emissions estimation, we also address some of the considerations that need to be made when designing these national networks. One of the novel aspects of this work is that we use a hierarchical Bayesian inversion framework. This methodology, which has newly been applied to greenhouse gas emissions estimation, is designed to estimate temporally and spatially varying model-measurement uncertainties and correlation scales, in addition to fluxes. Through this analysis, we demonstrate the importance of characterizing these covariance parameters in order to properly use data from high-density monitoring networks. This UK case study highlights the ways in which this new inverse framework can be used to address some of the limitations of traditional Bayesian inverse methods.

  13. Trace gas emissions by plants

    SciTech Connect

    Sharkey, T.D.; Holland, E.A.

    1991-12-31

    The trace gases released or influenced by plants play a key role in atmospheric processes. In the troposphere, methane and carbon monoxide are key species that react with the hydroxyl radical (OH), an effective atmospheric detergent. Carbon monoxide is formed by the oxidation of the biogenic hydrocarbons discussed previously. In the presence of NO, the oxidation of CO, CH{sub 4} and NMHC can lead to the formation of ozone, a tropospheric pollutant. In the stratosphere, methane is an important source of water vapor. Volatile sulfur compounds released by plants may be an important source of cloud condensation nuclei. Collectively, these compounds may directly regulate the earth`s climate because they are radiatively active and influence the radiation balance at the earth`s surface or indirectly regulate the earth`s climate because they influence the concentration of radiatively active gases. The focus of the workshop was on naturally occurring gas fluxes. It is sometimes claimed that the gas fluxes from plants pollute the atmosphere. Our focus was on the natural chemistry occurring at the biosphere-atmosphere interface. Individual reports are processed separately for the data bases.

  14. Trace gas emissions by plants

    SciTech Connect

    Sharkey, T.D. . Dept. of Botany); Holland, E.A. ); Mooney, H.A. . Dept. of Biological Sciences)

    1991-01-01

    The trace gases released or influenced by plants play a key role in atmospheric processes. In the troposphere, methane and carbon monoxide are key species that react with the hydroxyl radical (OH), an effective atmospheric detergent. Carbon monoxide is formed by the oxidation of the biogenic hydrocarbons discussed previously. In the presence of NO, the oxidation of CO, CH[sub 4] and NMHC can lead to the formation of ozone, a tropospheric pollutant. In the stratosphere, methane is an important source of water vapor. Volatile sulfur compounds released by plants may be an important source of cloud condensation nuclei. Collectively, these compounds may directly regulate the earth's climate because they are radiatively active and influence the radiation balance at the earth's surface or indirectly regulate the earth's climate because they influence the concentration of radiatively active gases. The focus of the workshop was on naturally occurring gas fluxes. It is sometimes claimed that the gas fluxes from plants pollute the atmosphere. Our focus was on the natural chemistry occurring at the biosphere-atmosphere interface. Individual reports are processed separately for the data bases.

  15. Acoustic emission monitoring of wind turbine blades

    NASA Astrophysics Data System (ADS)

    Van Dam, Jeremy; Bond, Leonard J.

    2015-03-01

    Damage to wind turbine blades can, if left uncorrected, evolve into catastrophic failures resulting in high costs and significant losses for the operator. Detection of damage, especially in real time, has the potential to mitigate the losses associated with such catastrophic failure. To address this need various forms of online monitoring are being investigated, including acoustic emission detection. In this paper, pencil lead breaks are used as a standard reference source and tests are performed on unidirectional glass-fiber-reinforced-polymer plates. The mechanical pencil break is used to simulate an acoustic emission (AE) that generates elastic waves in the plate. Piezoelectric sensors and a data acquisition system are used to detect and record the signals. The expected dispersion curves generated for Lamb waves in plates are calculated, and the Gabor wavelet transform is used to provide dispersion curves based on experimental data. AE sources using an aluminum plate are used as a reference case for the experimental system and data processing validation. The analysis of the composite material provides information concerning the wave speed, modes, and attenuation of the waveform, which can be used to estimate maximum AE event - receiver separation, in a particular geometry and materials combination. The foundational data provided in this paper help to guide improvements in online structural health monitoring of wind turbine blades using acoustic emission.

  16. A CAVITY RING-DOWN SPECTROSCOPY MERCURY CONTINUOUS EMISSION MONITOR

    SciTech Connect

    Christopher C. Carter, Ph.D.

    2003-04-01

    Accurate reporting of mercury concentration requires a detailed model that includes experimental parameters that vary, such as: pressure, temperature, concentration, absorption cross-section, and isotopic structure etc. During this quarter a theoretical model has been developed to model the 253.7 nm mercury transition. In addition, while testing the interferent species SO{sub 2}, SRD was able to determine the absorption cross-section experimentally and add this to the theoretical model. Assuming that the baseline losses are due to the mirror reflectivity and SO{sub 2}, SRD can now determine the concentrations of both mercury and SO{sub 2} from the data taken. For the CRD instrument to perform as a continuous emission monitor it will be required to monitor mercury concentrations over extended periods of time. The stability of monitoring mercury concentrations over time with the CRD apparatus was tested during the past quarter. During a test which monitored the mercury concentration every 2 seconds it was found that the standard deviation, of a signal from about 1.25 ppb Hg, was only 30 ppt. SRD continued interferent gas testing during this past quarter. This included creating a simulated flue gas composed of the gases tested individually by SRD. The detection limits for mercury, although dependent on the concentration of SO{sub 2} in the simulated gas matrix, remained well below the ppb range. It was determined that for the gases tested the only measurable changes in the baseline level occurred for SO{sub 2} and mercury. Speciation studies continued with mercury chloride (HgCl{sub 2}). This included checking for spectral speciation with both Hg and HgCl{sub 2} present in the CRD cavity. There was no observable spectral shift. Also a pyrolysis oven was incorporated into the gas delivery system both for tests with HgCl{sub 2} as well as atomization of the entire gas stream. The pyrolysis tests conducted have been inconclusive thus far.

  17. Assessing Greenhouse Gas Emissions from University Purchases

    ERIC Educational Resources Information Center

    Thurston, Matthew; Eckelman, Matthew J.

    2011-01-01

    Purpose: A greenhouse gas (GHG) inventory was conducted for Yale University's procurement of goods and services over a one-year period. The goal of the inventory was to identify the financial expenditures resulting in the greatest "indirect" GHG emissions. This project is part of an ongoing effort to quantify and reduce the university's…

  18. Lidar for monitoring methane emission in Siberian permafrost

    NASA Astrophysics Data System (ADS)

    Grishkanich, A. S.; Zhevlakov, A. P.; Sidorov, I.; Elizarov, V. V.; Mak, A. A.; Kascheev, S. V.

    2016-03-01

    Identifying methane anomalies responsible for the temperature increase, by hiking trails in the Arctic requires great human labor .According to the tentative forecast by the year 2100 Arctic permafrost will greatly deteriorate, which will have numerous consequences. Indeed, release of less than 0.1% of the organic carbon stored in the upper 100-meter permafrost level (approximately 10000 ppm of carbon in the CH4 form) can double concentration of atmospheric methane, which is roughly 20 times more potent greenhouse gas than the CO2. Necessary to create a Raman lidar for monitoring of emissions of methane hydrate from the permafrost.

  19. Vendors unveil one-step fugitive emissions monitoring, management

    SciTech Connect

    Walter, M.

    1995-04-01

    An alliance of manufacturers has developed a ``single-source solution`` for fugitive emissions monitoring. The LeakTracker{trademark} system combines barcode scans, and vapor detection and data collection capabilities to help companies comply with leak detection and repair requirements as mandated by the Environmental Protection Agency`s Method 21 guidelines. LeakTracker doubles productivity and helps eliminate human-error factors associated with fugitive emissions monitoring. Two-person teams, clipboard-and-pencil data entry, and manual data transcription are eliminated. By automating the process and integrating all components, a technician can monitor 500 points daily following Method 21 guidelines, compared to about 250 readings per day using other systems. LeakTracker includes a handheld workstation, sampling probe and laser-scan barcode reader that fit in a vest worn by a field technician. The technician points the workstation toward a barcode tag and pulls the trigger, which initiates a barcode read and automatically records the time, date and location. While the detachable probe ``sniffs`` for emissions, an analyzer interface module converts the gas detection signal from analog to digital format, allowing data to be recorded by the workstation. LeakTracker has an accuracy rate of 1 part per million.

  20. Remote Real-Time Monitoring of Subsurface Landfill Gas Migration

    PubMed Central

    Fay, Cormac; Doherty, Aiden R.; Beirne, Stephen; Collins, Fiachra; Foley, Colum; Healy, John; Kiernan, Breda M.; Lee, Hyowon; Maher, Damien; Orpen, Dylan; Phelan, Thomas; Qiu, Zhengwei; Zhang, Kirk; Gurrin, Cathal; Corcoran, Brian; O’Connor, Noel E.; Smeaton, Alan F.; Diamond, Dermot

    2011-01-01

    The cost of monitoring greenhouse gas emissions from landfill sites is of major concern for regulatory authorities. The current monitoring procedure is recognised as labour intensive, requiring agency inspectors to physically travel to perimeter borehole wells in rough terrain and manually measure gas concentration levels with expensive hand-held instrumentation. In this article we present a cost-effective and efficient system for remotely monitoring landfill subsurface migration of methane and carbon dioxide concentration levels. Based purely on an autonomous sensing architecture, the proposed sensing platform was capable of performing complex analytical measurements in situ and successfully communicating the data remotely to a cloud database. A web tool was developed to present the sensed data to relevant stakeholders. We report our experiences in deploying such an approach in the field over a period of approximately 16 months. PMID:22163975

  1. Remote real-time monitoring of subsurface landfill gas migration.

    PubMed

    Fay, Cormac; Doherty, Aiden R; Beirne, Stephen; Collins, Fiachra; Foley, Colum; Healy, John; Kiernan, Breda M; Lee, Hyowon; Maher, Damien; Orpen, Dylan; Phelan, Thomas; Qiu, Zhengwei; Zhang, Kirk; Gurrin, Cathal; Corcoran, Brian; O'Connor, Noel E; Smeaton, Alan F; Diamond, Dermot

    2011-01-01

    The cost of monitoring greenhouse gas emissions from landfill sites is of major concern for regulatory authorities. The current monitoring procedure is recognised as labour intensive, requiring agency inspectors to physically travel to perimeter borehole wells in rough terrain and manually measure gas concentration levels with expensive hand-held instrumentation. In this article we present a cost-effective and efficient system for remotely monitoring landfill subsurface migration of methane and carbon dioxide concentration levels. Based purely on an autonomous sensing architecture, the proposed sensing platform was capable of performing complex analytical measurements in situ and successfully communicating the data remotely to a cloud database. A web tool was developed to present the sensed data to relevant stakeholders. We report our experiences in deploying such an approach in the field over a period of approximately 16 months. PMID:22163975

  2. Reducing exhaust gas emissions from Citydiesel busses

    NASA Astrophysics Data System (ADS)

    Mikkonen, Seppo

    The effect of fuel composition and exhaust gas aftertreatment on the emissions was measured from truck and bus engines. Possibilities to measure unregulated emissions (aldehydes, polyaromatic hydrocarbons, mutagenicity) were built. A reformulated diesel fuel 'Citydiesel' was developed. Citydiesel was able to reduce emissions compared to standard diesel fuel as follows: particulates by 10 to 30%, nitrogen oxides by 2 to 10%, sulphur dioxide by 97%, polyaromatic hydrocarbons (PAH) over 50%, mutagenicity of the exhaust particulates clearly, odor of the exhaust, and smoke after a cold start. The use of Citydiesel fuel reduces emissions of the existing vehicles immediately which is a remarkable benefit. The very low sulphur content (below 50 ppm) makes it possible to use oxidation. catalytic converters to reduce emissions of diesel vehicles. The new Euro 2 exhaust regulations coming into force during 1996 can be met with a modern diesel engine, Citydiesel fuel, and exhaust gas aftertreatment. Properties of Citydiesel fuel were verified in a three year field test with 140 city buses. Experience was good; e.g., engine oil change interval could be lengthened. Total value of the exhaust was estimated with different fuels and aftertreatment device in order to find out cheap ways to reduce emissions.

  3. Automated soil gas monitoring chamber

    DOEpatents

    Edwards, Nelson T.; Riggs, Jeffery S.

    2003-07-29

    A chamber for trapping soil gases as they evolve from the soil without disturbance to the soil and to the natural microclimate within the chamber has been invented. The chamber opens between measurements and therefore does not alter the metabolic processes that influence soil gas efflux rates. A multiple chamber system provides for repetitive multi-point sampling, undisturbed metabolic soil processes between sampling, and an essentially airtight sampling chamber operating at ambient pressure.

  4. Continuous emissions monitoring of mixed waste incinerators

    NASA Astrophysics Data System (ADS)

    Quigley, Gerard P.; Bentley, G. E.; Crain, J. S.; Fry, Herbert A.; Funk, David J.; Moore, David S.; Oldenborg, Richard C.; Palmer, Byron A.; Swanson, Basil I.

    1993-03-01

    A system for the real-time monitoring of emissions from incinerators must be developed which can address the needs of the DOE community and others involved in mixed waste incineration. These needs are an outgrowth of the ever-increasing waste storage problems and the growing concern of the public, as witnessed by the stricter compliance requirements of federal and state agencies, that the products of incineration are hazardous to their health and injurious to the environment. This paper focuses on the technologies being developed here at Los Alamos and other laboratories which address the detection of a broad spectrum of toxic and hazardous chemicals.

  5. Silicon Carbide Gas Sensors for Propulsion Emissions and Safety Applications

    NASA Technical Reports Server (NTRS)

    Hunter, G. W.; Xu, J.; Neudeck, P. G.; Lukco, D.; Trunek, A.; Spry, D.; Lampard, P.; Androjna, D.; Makel, D.; Ward, B.

    2007-01-01

    Silicon carbide (SiC) based gas sensors have the ability to meet the needs of a range of aerospace propulsion applications including emissions monitoring, leak detection, and hydrazine monitoring. These applications often require sensitive gas detection in a range of environments. An effective sensing approach to meet the needs of these applications is a Schottky diode based on a SiC semiconductor. The primary advantage of using SiC as a semiconductor is its inherent stability and capability to operate at a wide range of temperatures. The complete SiC Schottky diode gas sensing structure includes both the SiC semiconductor and gas sensitive thin film metal layers; reliable operation of the SiC-based gas sensing structure requires good control of the interface between these gas sensitive layers and the SiC. This paper reports on the development of SiC gas sensors. The focus is on two efforts to better control the SiC gas sensitive Schottky diode interface. First, the use of palladium oxide (PdOx) as a barrier layer between the metal and SiC is discussed. Second, the use of atomically flat SiC to provide an improved SiC semiconductor surface for gas sensor element deposition is explored. The use of SiC gas sensors in a multi-parameter detection system is briefly discussed. It is concluded that SiC gas sensors have potential in a range of propulsion system applications, but tailoring of the sensor for each application is necessary.

  6. Real-time atomic absorption mercury continuous emission monitor

    NASA Astrophysics Data System (ADS)

    Zamzow, Daniel S.; Bajic, Stanley J.; Eckels, David E.; Baldwin, David P.; Winterrowd, Chris; Keeney, Robert

    2003-08-01

    A continuous emission monitor (CEM) for mercury (Hg) in combustor flue gas streams has been designed and tested for the detection of Hg by optical absorption. A sampling system that allows continuous introduction of stack gas is incorporated into the CEM, for the sequential analysis of elemental and total Hg. A heated pyrolysis tube is used in the system to convert oxidized Hg compounds to elemental Hg for analysis of total Hg; the pyrolysis tube is bypassed to determine the elemental Hg concentration in the gas stream. A key component of the CEM is a laboratory-designed and -assembled echelle spectrometer that provides simultaneous detection of all of the emission lines from a Hg pen lamp, which is used as the light source for the optical absorption measurement. This feature allows for on-line spectroscopic correction for interferent gases such as sulfur dioxide and nitrogen dioxide, typically present in combustion stack gas streams, that also absorb at the Hg detection wavelength (253.65 nm). This article provides a detailed description of the CEM system, the characteristics and performance of the CEM, and the results of field tests performed at the Environmental Protection Agency-Rotary Kiln at Research Triangle Park, NC.

  7. 40 CFR 75.11 - Specific provisions for monitoring SO2 emissions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... achieve the performance specifications of this part. (d) Gas-fired and oil-fired units. The owner or... requirements in § 75.10 for an SO2 continuous emission monitoring system and a flow monitoring system for each affected coal-fired unit while the unit is combusting coal and/or any other fuel, except as provided...

  8. Fundamental study on gas monitoring in celss

    NASA Astrophysics Data System (ADS)

    Nishi, I.; Tateishi, T.; Tomizawa, G.; Nitta, K.; Oguchi, M.

    A mass spectrometer and computer system was developed for conducting a fundamental study on gas monitoring in CELSS. Respiration and metabolism of the hamster and photosynthesis of the Spirulina were measured in a combination system consisting of a hamster chamber and a Spirulina cultivator. They are connected through a membrane gas exchanger. Some technical problems were examined. In the mass spectrometric gas monitoring, a simultaneous multi-sample measurement was developed by employing a rotating exchange valve. Long term precise measurement was obtained by employing an automatic calibration system. The membrane gas sampling probe proved to be useful for long term measurement. The cultivation rate of the Spirulina was effectively changed by controlling CO2 and light supply. The experimental results are helpful for improving the hamster-spirulina system.

  9. Fundamental study on gas monitoring in CELSS

    NASA Technical Reports Server (NTRS)

    Nishi, I.; Tateishi, T.; Tomizawa, G.; Nitta, K.; Oguchi, M.

    1987-01-01

    A mass spectrometer and computer system was developed for conducting a fundamental study on gas monitoring in a Controlled Ecological Life Support System. Respiration and metabolism of the hamster and photosynthesis of the Spirulina were measured in a combination system consisting of a hamster chamber and a Spirulina cultivator. They are connected through a membrane gas exchanger. Some technical problems were examined. In the mass spectrometric gas monitoring, a simultaneous multisample measurement was developed by employing a rotating exchange valve. Long term precise measurement was obtained by employing an automatic calibration system. The membrane gas sampling probe proved to be useful for long term measurement. The cultivation rate of the Spirulina was effectively changed by controlling CO2 and light supply. The experimental results are helpful for improving the hamster-spirulina system.

  10. Impact of routine episodic emissions on the expected frequency distribution of emissions from oil and gas production sources.

    NASA Astrophysics Data System (ADS)

    Smith, N.; Blewitt, D.; Hebert, L. B.

    2015-12-01

    In coordination with oil and gas operators, we developed a high resolution (< 1 min) simulation of temporal variability in well-pad oil and gas emissions over a year. We include routine emissions from condensate tanks, dehydrators, pneumatic devices, fugitive leaks and liquids unloading. We explore the variability in natural gas emissions from these individual well-pad sources, and find that routine short-term episodic emissions such as tank flashing and liquids unloading result in the appearance of a skewed, or 'fat-tail' distribution of emissions, from an individual well-pad over time. Additionally, we explore the expected variability in emissions from multiple wells with different raw gas composition, gas/liquids production volumes and control equipment. Differences in well-level composition, production volume and control equipment translate into differences in well-level emissions leading to a fat-tail distribution of emissions in the absence of operational upsets. Our results have several implications for recent studies focusing on emissions from oil and gas sources. Time scale of emission estimates are important and have important policy implications. Fat tail distributions may not be entirely driven by avoidable mechanical failures, and are expected to occur under routine operational conditions from short-duration emissions (e.g., tank flashing, liquid unloading). An understanding of the expected distribution of emissions for a particular population of wells is necessary to evaluate whether the observed distribution is more skewed than expected. Temporal variability in well-pad emissions make comparisons to annual average emissions inventories difficult and may complicate the interpretation of long-term ambient fenceline monitoring data. Sophisticated change detection algorithms will be necessary to identify when true operational upsets occur versus routine short-term emissions.

  11. Monitoring hydraulic fracturing with seismic emission volume

    NASA Astrophysics Data System (ADS)

    Niu, F.; Tang, Y.; Chen, H.; TAO, K.; Levander, A.

    2014-12-01

    Recent developments in horizontal drilling and hydraulic fracturing have made it possible to access the reservoirs that are not available for massive production in the past. Hydraulic fracturing is designed to enhance rock permeability and reservoir drainage through the creation of fracture networks. Microseismic monitoring has been proven to be an effective and valuable technology to image hydraulic fracture geometry. Based on data acquisition, seismic monitoring techniques have been divided into two categories: downhole and surface monitoring. Surface monitoring is challenging because of the extremely low signal-to-noise ratio of the raw data. We applied the techniques used in earthquake seismology and developed an integrated monitoring system for mapping hydraulic fractures. The system consists of 20 to 30 state-of-the-art broadband seismographs, which are generally about hundreds times more sensible than regular geophones. We have conducted two experiments in two basins with very different geology and formation mechanism in China. In each case, we observed clear microseismic events, which may correspond to the induced seismicity directly associated with fracturing and the triggered ones at pre-existing faults. However, the magnitude of these events is generally larger than magnitude -1, approximately one to two magnitudes larger than those detected by downhole instruments. Spectrum-frequency analysis of the continuous surface recordings indicated high seismic energy associated with injection stages. The seismic energy can be back-projected to a volume that surrounds each injection stage. Imaging seismic emission volume (SEV) appears to be an effective way to map the stimulated reservior volume, as well as natural fractures.

  12. 40 CFR 61.55 - Monitoring of emissions and operations.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... for Mercury § 61.55 Monitoring of emissions and operations. (a) Wastewater treatment plant sludge incineration and drying plants. All the sources for which mercury emissions exceed 1.6 kg (3.5 lb) per 24-hour....54, shall monitor mercury emissions at intervals of at least once per year by use of Method 105...

  13. 40 CFR 61.55 - Monitoring of emissions and operations.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... for Mercury § 61.55 Monitoring of emissions and operations. (a) Wastewater treatment plant sludge incineration and drying plants. All the sources for which mercury emissions exceed 1.6 kg (3.5 lb) per 24-hour....54, shall monitor mercury emissions at intervals of at least once per year by use of Method 105...

  14. 40 CFR 61.55 - Monitoring of emissions and operations.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... for Mercury § 61.55 Monitoring of emissions and operations. (a) Wastewater treatment plant sludge incineration and drying plants. All the sources for which mercury emissions exceed 1.6 kg (3.5 lb) per 24-hour....54, shall monitor mercury emissions at intervals of at least once per year by use of Method 105...

  15. 40 CFR 61.55 - Monitoring of emissions and operations.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... for Mercury § 61.55 Monitoring of emissions and operations. (a) Wastewater treatment plant sludge incineration and drying plants. All the sources for which mercury emissions exceed 1.6 kg (3.5 lb) per 24-hour....54, shall monitor mercury emissions at intervals of at least once per year by use of Method 105...

  16. 40 CFR 61.55 - Monitoring of emissions and operations.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... for Mercury § 61.55 Monitoring of emissions and operations. (a) Wastewater treatment plant sludge incineration and drying plants. All the sources for which mercury emissions exceed 1.6 kg (3.5 lb) per 24-hour....54, shall monitor mercury emissions at intervals of at least once per year by use of Method 105...

  17. [Greenhouse gas emission from reservoir and its influence factors].

    PubMed

    Zhao, Xiao-jie; Zhao, Tong-qian; Zheng, Hua; Duan, Xiao-nan; Chen, Fa-lin; Ouyang, Zhi-yun; Wang, Xiao-ke

    2008-08-01

    Reservoirs are significant sources of emissions of the greenhouse gases. Discussing greenhouse gas emission from the reservoirs and its influence factors are propitious to evaluate emission of the greenhouse gas accurately, reduce gas emission under hydraulic engineering and hydropower development. This paper expatiates the mechanism of the greenhouse gas production, sums three approaches of the greenhouse gas emission, which are emissions from nature emission of the reservoirs, turbines and spillways and downstream of the dam, respectively. Effects of greenhouse gas emission were discussed from character of the reservoirs, climate, pH of the water, vegetation growing in the reservoirs and so on. Finally, it has analyzed the heterogeneity of the greenhouse gas emission as well as the root of the uncertainty and carried on the forecast with emphasis to the next research. PMID:18839604

  18. A NOx and SO2 gas analyzer using deep-UV and violet light-emitting diodes for continuous emissions monitoring systems

    NASA Astrophysics Data System (ADS)

    Higashi, Ryoichi; Taniguchi, Yu; Akao, Kozo; Koizumi, Kazuhiro; Hirayama, Noritomo; Nakano, Yoshiaki

    2014-02-01

    A nitrogen oxides (NOx) and sulfur dioxide (SO2) gas analyzer using deep ultraviolet (DUV) and violet light- emitting diodes (LEDs) is developed. The LEDs with wavelengths of 280 nm and 400 nm were alternately turned on to detect SO2 and nitrogen dioxide (NO2) absorption. Nitric oxide (NO) was converted to NO2 with an ozonizer. In order to reduce water interference caused by water adsorption onto an inner surface of a gas ow cell, collimating optics reducing re ected lights were designed. As a result, less than 1% by full scale (%F.S.) of uctuation, 2%F.S. of drift and 0.5%F.S. of water interference were achieved in 0-50 ppm concentration range. Conversion efficiency from NO to NO2 was over 95%.

  19. Continuous monitoring of particle emissions during showering.

    PubMed

    Cowen, Kenneth A; Ollison, Will M

    2006-12-01

    Particle formation from showering may be attributed to dissolved mineral aerosols remaining after evaporation of micron-sized satellite droplets produced by the showerhead or from splashing of larger shower water droplets on surfaces. Duplicate continuous particle monitors measured particle size distributions in a ventilated residential bathroom under various showering conditions, using a full-size mannequin in the shower to simulate splashing effects during showering. Particle mass concentrations were estimated from measured shower particle number densities and used to develop emission factors for inhalable particles. Emission source strengths of 2.7-41.3 microg/ m3/min were estimated under the various test conditions using residential tap water in Columbus, OH. Calculated fine particulate matter (PM2.5) concentrations in the bathroom reached several hundred micrograms per cubic meter; calculated coarse particulate matter (PM10) levels approached 1000 microg/m3. Rates of particle formation tended to be highest for coarse shower spray settings with direct impact on the mannequin. No consistent effects of water temperature, water pressure, or spray setting on overall emission rates were apparent, although water temperature and spray setting did have an effect when varied within a single shower sampling run. Salt solutions were injected into the source water during some tests to assess the effects of total dissolved solids on particle emission rates. Injection of salts was shown to increase the PM2.5 particle formation rate by approximately one third, on average, for a doubling in tap water-dissolved solids content; PM10 source strengths approximately doubled under these conditions, because very few particles >10 microm were formed. PMID:17195485

  20. Embodied greenhouse gas emissions in diets.

    PubMed

    Pradhan, Prajal; Reusser, Dominik E; Kropp, Juergen P

    2013-01-01

    Changing food consumption patterns and associated greenhouse gas (GHG) emissions have been a matter of scientific debate for decades. The agricultural sector is one of the major GHG emitters and thus holds a large potential for climate change mitigation through optimal management and dietary changes. We assess this potential, project emissions, and investigate dietary patterns and their changes globally on a per country basis between 1961 and 2007. Sixteen representative and spatially differentiated patterns with a per capita calorie intake ranging from 1,870 to >3,400 kcal/day were derived. Detailed analyses show that low calorie diets are decreasing worldwide, while in parallel diet composition is changing as well: a discernable shift towards more balanced diets in developing countries can be observed and steps towards more meat rich diets as a typical characteristics in developed countries. Low calorie diets which are mainly observable in developing countries show a similar emission burden than moderate and high calorie diets. This can be explained by a less efficient calorie production per unit of GHG emissions in developing countries. Very high calorie diets are common in the developed world and exhibit high total per capita emissions of 3.7-6.1 kg CO(2eq.)/day due to high carbon intensity and high intake of animal products. In case of an unbridled demographic growth and changing dietary patterns the projected emissions from agriculture will approach 20 Gt CO(2eq.)/yr by 2050. PMID:23700408

  1. Continuous blood gas monitoring in femoral arteries

    NASA Astrophysics Data System (ADS)

    Schlain, Les A.; Spar, Steven M.; Dellinger, Bart

    1995-05-01

    Continuous intra-arterial blood gas monitoring is a potentially valuable tool in the surgical and intensive care arenas. Patient oxygenation and acid base status can change rapidly and without warning. The ability to monitor pHa, PaCO2 and PaO2 in arterial blood will be a major medical advance for the anesthesiologist and intensivist. Intra-arterial blood gas sensors are typically placed in radial arteries. In certain patient populations accurate monitoring is not possible in radial arteries due to arterial environmental factors such as hypotension, vasoconstriction and atherosclerotic disease. These same factors can make radial cannulation difficult resulting in traumatic catheter insertion, thereby further compromising flow conditions. In situations where radial artery flow is expected to be compromised, selecting a large vessel for sensor placement is desirable. We report an initial feasibility study of our blood gas monitoring system using the femoral artery as the sensing site. Clinical results are presented as well as potential advantages and disadvantages associated with monitoring in the femoral artery.

  2. The Dairy Greenhouse Gas Emission Model: Reference Manual

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The Dairy Greenhouse Gas Model (DairyGHG) is a software tool for estimating the greenhouse gas emissions and carbon footprint of dairy production systems. A relatively simple process-based model is used to predict the primary greenhouse gas emissions, which include the net emission of carbon dioxide...

  3. 40 CFR 61.93 - Emission monitoring and test procedures.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 9 2014-07-01 2014-07-01 false Emission monitoring and test procedures. 61.93 Section 61.93 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standards for Emissions of Radionuclides Other Than...

  4. HYDROCARBON CONTINUOUS MONITORING SYSTEMS FOR HAZARDOUS WASTE INCINERATOR EMISSIONS MEASUREMENT

    EPA Science Inventory

    The U.S. Environmental Protection Agency has sponsored an extended laboratory and field evaluation of continuous emission monitoring systems available to measure hydrocarbon emissions from hazardous waste incinerators. erformance tests of calibration drift, calibration error, res...

  5. Atmospheric monitoring for fugitive emissions from geological carbon storage

    NASA Astrophysics Data System (ADS)

    Loh, Z. M.; Etheridge, D.; Luhar, A.; Leuning, R.; Jenkins, C.

    2013-12-01

    We present a multi-year record of continuous atmospheric CO2 and CH4 concentration measurements, flask sampling (for CO2, CH4, N2O, δ13CO2 and SF6) and CO2 flux measurements at the CO2CRC Otway Project (http://www.co2crc.com.au/otway/), a demonstration site for geological storage of CO2 in south-western Victoria, Australia. The measurements are used to develop atmospheric methods for operational monitoring of large scale CO2 geological storage. Characterization of emission rates ideally requires concentration measurements upwind and downwind of the source, along with knowledge of the atmospheric turbulence field. Because only a single measurement location was available for much of the measurement period, we develop techniques to filter the record and to construct a ';pseudo-upwind' measurement from our dataset. Carbon dioxide and methane concentrations were filtered based on wind direction, downward shortwave radiation, atmospheric stability and hour-to-hour changes in CO2 flux. These criteria remove periods of naturally high concentration due to the combined effects of biogenic respiration, stable atmospheric conditions and pre-existing sources (both natural and anthropogenic), leaving a reduced data set, from which a fugitive leak from the storage reservoir, the ';(potential) source sector)', could more easily be detected. Histograms of the filtered data give a measure of the background variability in both CO2 and CH4. Comparison of the ';pseudo-upwind' dataset histogram with the ';(potential) source sector' histogram shows no statistical difference, placing limits on leakage to the atmosphere over the preceding two years. For five months in 2011, we ran a true pair of up and downwind CO2 and CH4 concentration measurements. During this period, known rates of gas were periodically released at the surface (near the original injection point). These emissions are clearly detected as elevated concentrations of CO2 and CH4 in the filtered data and in the measured

  6. Sulfur gas emissions from stored flue-gas-desulfurization sludges

    SciTech Connect

    Adams, D.F.; Farwell, S.O.

    1980-01-01

    In field studies conducted for the Electric Power Research Institute by the University of Washington (1978) and the University of Idaho (1979), 13 gas samples from sludge storage sites at coal-burning power plants were analyzed by wall-coated open-tube cryogenic capillary-column gas chromatography with a sulfur-selective flame-photometric detector. Hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide were identified in varying concentrations and ratios in the emissions from both operating sludge ponds and landfills and from FGD sludge surfaces that had been stored in the open for 3-32 mo or longer. Other sulfur compounds, probably propanethiols, were found in emissions from some sludges. Chemical ''stabilization/fixation'' sulfate-sulfite ratio, sludge water content, and temperature were the most significant variables controlling sulfur gas production. The average sulfur emissions from each of the 13 FGD storage sites ranged from 0.01 to 0.26 g/sq m/yr sulfur.

  7. Monitoring, reporting and verifying emissions in the climate economy

    NASA Astrophysics Data System (ADS)

    Bellassen, Valentin; Stephan, Nicolas; Afriat, Marion; Alberola, Emilie; Barker, Alexandra; Chang, Jean-Pierre; Chiquet, Caspar; Cochran, Ian; Deheza, Mariana; Dimopoulos, Christopher; Foucherot, Claudine; Jacquier, Guillaume; Morel, Romain; Robinson, Roderick; Shishlov, Igor

    2015-04-01

    The monitoring, reporting and verification (MRV) of greenhouse-gas emissions is the cornerstone of carbon pricing and management mechanisms. Here we consider peer-reviewed articles and 'grey literature' related to existing MRV requirements and their costs. A substantial part of the literature is the regulatory texts of the 15 most important carbon pricing and management mechanisms currently implemented. Based on a comparison of key criteria such as the scope, cost, uncertainty and flexibility of procedures, we conclude that conventional wisdom on MRV is not often promoted in existing carbon pricing mechanisms. Quantification of emissions uncertainty and incentives to reduce this uncertainty are usually only partially applied, if at all. Further, the time and resources spent on small sources of emissions would be expected to be limited. Although provisions aiming at an effort proportionate to the amount of emissions at stake -- 'materiality' -- are widespread, they are largely outweighed by economies of scale: in all schemes, MRV costs per tonne are primarily driven by the size of the source.

  8. Opportunities for reducing greenhouse gas emissions in tropical peatlands

    PubMed Central

    Murdiyarso, D.; Hergoualc’h, K.; Verchot, L. V.

    2010-01-01

    The upcoming global mechanism for reducing emissions from deforestation and forest degradation in developing countries should include and prioritize tropical peatlands. Forested tropical peatlands in Southeast Asia are rapidly being converted into production systems by introducing perennial crops for lucrative agribusiness, such as oil-palm and pulpwood plantations, causing large greenhouse gas (GHG) emissions. The Intergovernmental Panel on Climate Change Guidelines for GHG Inventory on Agriculture, Forestry, and Other Land Uses provide an adequate framework for emissions inventories in these ecosystems; however, specific emission factors are needed for more accurate and cost-effective monitoring. The emissions are governed by complex biophysical processes, such as peat decomposition and compaction, nutrient availability, soil water content, and water table level, all of which are affected by management practices. We estimate that total carbon loss from converting peat swamp forests into oil palm is 59.4 ± 10.2 Mg of CO2 per hectare per year during the first 25 y after land-use cover change, of which 61.6% arise from the peat. Of the total amount (1,486 ± 183 Mg of CO2 per hectare over 25 y), 25% are released immediately from land-clearing fire. In order to maintain high palm-oil production, nitrogen inputs through fertilizer are needed and the magnitude of the resulting increased N2O emissions compared to CO2 losses remains unclear. PMID:21081702

  9. Quasi-simultaneous in-line flue gas monitoring of NO and NO₂ emissions at a caloric power plant employing mid-IR laser spectroscopy.

    PubMed

    Reidl-Leuthner, Christoph; Viernstein, Alexander; Wieland, Karin; Tomischko, Wolfgang; Sass, Ludwig; Kinger, Gerald; Ofner, Johannes; Lendl, Bernhard

    2014-09-16

    Two pulsed thermoelectrically cooled mid-infrared distributed feedback quantum cascade lasers (QCLs) were used for the quasi-simultaneous in-line determination of NO and NO2 at the caloric power plant Dürnrohr (Austria). The QCL beams were combined using a bifurcated hollow fiber, sent through the flue tube (inside diameter: 5.5 m), reflected by a retro-reflector and recorded using a fast thermoelectrically cooled mercury-cadmium-telluride detector. The thermal chirp during 300 ns pulses was about 1.2 cm(-1) and allowed scanning of rotational vibrational doublets of the analytes. On the basis of the thermal chirp and the temporal resolution of data acquisition, a spectral resolution of approximately 0.02 cm(-1) was achieved. The recorded rotational vibrational absorption lines were centered at 1900 cm(-1) for NO and 1630 cm(-1) for NO2. Despite water content in the range of 152-235 g/m(3) and an average particle load of 15.8 mg/m(3) in the flue gas, in-line measurements were possible achieving limits of detection of 73 ppb for NO and 91 ppb for NO2 while optimizing for a single analyte. Quasi-simultaneous measurements resulted in limits of detection of 219 ppb for NO and 164 ppb for NO2, respectively. Influences of temperature and pressure on the data evaluation are discussed, and results are compared to an established reference method based on the extractive measurements presented. PMID:25131684

  10. Integrated Microfluidic Gas Sensors for Water Monitoring

    NASA Technical Reports Server (NTRS)

    Zhu, L.; Sniadecki, N.; DeVoe, D. L.; Beamesderfer, M.; Semancik, S.; DeVoe, D. L.

    2003-01-01

    A silicon-based microhotplate tin oxide (SnO2) gas sensor integrated into a polymer-based microfluidic system for monitoring of contaminants in water systems is presented. This device is designed to sample a water source, control the sample vapor pressure within a microchannel using integrated resistive heaters, and direct the vapor past the integrated gas sensor for analysis. The sensor platform takes advantage of novel technology allowing direct integration of discrete silicon chips into a larger polymer microfluidic substrate, including seamless fluidic and electrical interconnects between the substrate and silicon chip.

  11. Application of microturbines to control emissions from associated gas

    DOEpatents

    Schmidt, Darren D.

    2013-04-16

    A system for controlling the emission of associated gas produced from a reservoir. In an embodiment, the system comprises a gas compressor including a gas inlet in fluid communication with an associated gas source and a gas outlet. The gas compressor adjusts the pressure of the associated gas to produce a pressure-regulated associated gas. In addition, the system comprises a gas cleaner including a gas inlet in fluid communication with the outlet of the gas compressor, a fuel gas outlet, and a waste product outlet. The gas cleaner separates at least a portion of the sulfur and the water from the associated gas to produce a fuel gas. Further, the system comprises a gas turbine including a fuel gas inlet in fluid communication with the fuel gas outlet of the gas cleaner and an air inlet. Still further, the system comprises a choke in fluid communication with the air inlet.

  12. Continuous emission monitoring and accounting automated systems at an HPP

    NASA Astrophysics Data System (ADS)

    Roslyakov, P. V.; Ionkin, I. L.; Kondrateva, O. E.; Borovkova, A. M.; Seregin, V. A.; Morozov, I. V.

    2015-03-01

    Environmental and industrial emission monitoring at HPP's is a very urgent task today. Industrial monitoring assumes monitoring of emissions of harmful pollutants and optimization of fuel combustion technological processes at HPP's. Environmental monitoring is a system to assess ambient air quality with respect to a number of separate sources of harmful substances in pollution of atmospheric air of the area. Works on creating an industrial monitoring system are carried out at the National Research University Moscow Power Engineering Institute (MPEI) on the basis of the MPEI combined heat and power plant, and environmental monitoring stations are installed in Lefortovo raion, where the CHPP is located.

  13. Monitoring gas reservoirs by seismic interferometry

    NASA Astrophysics Data System (ADS)

    Grigoli, Francesco; Cesca, Simone; Sens-Schoenfelder, Christoph; Priolo, Enrico

    2014-05-01

    Ambient seismic noise can be used to image spatial anomalies in the subsurface, without the need of recordings from seismic sources, such as earthquakes or explosions. Furthermore, the temporal variation of ambient seismic noise's can be used to infer temporal changes of the seismic velocities in the investigated medium. Such temporal variations can reflect changes of several physical properties/conditions in the medium. For example, they may be consequence of stress changes, variation of hydrogeological parameters, pore pressure and saturation changes due to fluid injection or extraction. Passive image interferometry allows to continuously monitor small temporal changes of seismic velocities in the subsurface, making it a suitable tool to monitor time-variant systems such as oil and gas reservoirs or volcanic environments. The technique does not require recordings from seismic sources in the classical sense, but is based on the processing of noise records. Moreover, it requires only data from one or two seismic stations, their locations constraining the sampled target area. Here we apply passive image interferometry to monitor a gas storage reservoir in northern Italy. The Collalto field (Northern Italy) is a depleted gas reservoir located at 1500 m depth, now used as a gas storage facility. The reservoir experience a significant temporal variation in the amount of stored gas: the injection phases mainly occur in the summer, while the extraction take place mostly in winter. In order to monitor induced seismicity related to gas storage operations, a seismic network (the Collalto Seismic Network) has been deployed in 2011. The Collalto Seismic Network is composed by 10 broadband stations, deployed within an area of about 20 km x 20 km, and provides high-quality continuous data since January 1st, 2012. In this work we present preliminary results from ambient noise interferometry using a two-months sample of continuous seismic data, i.e. from October 1st, 2012, to the

  14. On-line emissions monitoring of chlorobenzene incineration using Fourier transform infrared spectroscopy

    SciTech Connect

    Mao, Zhuoxiong; McIntosh, M.J.; Demirgian, J.C.

    1992-01-01

    Incineration of chlorobenzene in a small laboratory incinerator was monitored by using Fourier transform infrared spectroscopy (FTIR) coupled with a heated long-path cell (LPC) to analyze and quantify flue gas emissions in near real time. The effects of operating conditions under stable and decreasing incineration temperatures on the destruction of chlorobenzene were studied. The results from the decreasing temperature experiments were found to be consistent with those from experiments at stable temperatures. This finding demonstrates that the FTIR/LPC, as a continuous emissions monitor, can effectively detect dynamic changes in the incinerator emissions and can contribute significantly to the safety of incinerators.

  15. On-line emissions monitoring of chlorobenzene incineration using Fourier transform infrared spectroscopy

    SciTech Connect

    Mao, Zhuoxiong; McIntosh, M.J.; Demirgian, J.C.

    1992-06-01

    Incineration of chlorobenzene in a small laboratory incinerator was monitored by using Fourier transform infrared spectroscopy (FTIR) coupled with a heated long-path cell (LPC) to analyze and quantify flue gas emissions in near real time. The effects of operating conditions under stable and decreasing incineration temperatures on the destruction of chlorobenzene were studied. The results from the decreasing temperature experiments were found to be consistent with those from experiments at stable temperatures. This finding demonstrates that the FTIR/LPC, as a continuous emissions monitor, can effectively detect dynamic changes in the incinerator emissions and can contribute significantly to the safety of incinerators.

  16. Effluent emissions monitoring at the DOE Hanford Site

    SciTech Connect

    Vance, L.W.

    1993-05-01

    There are numerous regulatory requirements controlling the effluent emissions monitoring at a U.S. Department of Energy site. This paper defines how these regulatory effluent emissions monitoring requirements and the Quality Assurance oversight of these requirements were implemented by Westinghouse Hanford Company, the operations contractor, at the DOE Hanford Site.

  17. Acoustic emission monitoring of HFIR vessel during hydrostatic testing

    SciTech Connect

    Friesel, M.A.; Dawson, J.F.

    1992-08-01

    This report discusses the results and conclusions reached from applying acoustic emission monitoring to surveillance of the High Flux Isotope Reactor vessel during pressure testing. The objective of the monitoring was to detect crack growth and/or fluid leakage should it occur during the pressure test. The report addresses the approach, acoustic emission instrumentation, installation, calibration, and test results.

  18. 30 CFR 70.1900 - Exhaust Gas Monitoring.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Exhaust Gas Monitoring. 70.1900 Section 70.1900 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY HEALTH STANDARDS-UNDERGROUND COAL MINES DIESEL EXHAUST GAS MONITORING § 70.1900 Exhaust Gas Monitoring. (a) During...

  19. 30 CFR 70.1900 - Exhaust Gas Monitoring.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Exhaust Gas Monitoring. 70.1900 Section 70.1900 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY HEALTH STANDARDS-UNDERGROUND COAL MINES Diesel Exhaust Gas Monitoring § 70.1900 Exhaust Gas Monitoring. (a) During...

  20. Greenhouse Gas Emissions from Brazilian Sugarcane Soils

    NASA Astrophysics Data System (ADS)

    Carmo, J.; Pitombo, L.; Cantarella, H.; Rosseto, R.; Andrade, C.; Martinelli, L.; Gava, G.; Vargas, V.; Sousa-Neto, E.; Zotelli, L.; Filoso, S.; Neto, A. E.

    2012-04-01

    Bioethanol from sugarcane is increasingly seen as a sustainable alternative energy source. Besides having high photosynthetic efficiency, sugarcane is a perennial tropical grass crop that can re-grow up to five or more years after being planted. Brazil is the largest producer of sugarcane in the world and management practices commonly used in the country lead to lower rates of inorganic N fertilizer application than sugarcane grown elsewhere, or in comparison to other feedstocks such as corn. Therefore, Brazilian sugarcane ethanol potentially promotes greenhouse gas savings. For that reason, several recent studies have attempted to assess emissions of greenhouse gases (GHG) during sugarcane production in the tropics. However, estimates have been mainly based on models due to a general lack of field data. In this study, we present data from in situ experiments on emission of three GHG (CO2, N2O, and CH4) in sugarcane fields in Brazil. Emissions are provided for sugarcane in different phases of the crop life cycle and under different management practices. Our results show that the use of nitrogen fertilizer in sugarcane crops resulted in an emission factor for N2O similar to those predicted by IPCC (1%), ranging from 0.59% in ratoon cane to 1.11% in plant cane. However, when vinasse was applied in addition to mineralN fertilizer, emissions of GHG increased in comparison to those from the use of mineral N fertilizer alone. Emissions increased significantly when experiments mimicked the accumulation of cane trash on the soil surface with 14 tons ha-1and 21 tons ha-1, which emission factor were 1.89% and 3.03%, respectively. This study is representative of Brazilian sugarcane systems under specific conditions for key factors affecting GHG emissions from soils. Nevertheless, the data provided will improve estimates of GHG from Brazilian sugarcane, and efforts to assess sugarcane ethanol sustainability and energy balance. Funding provided by the São Paulo Research

  1. 40 CFR 60.5407 - What are the requirements for monitoring of emissions and operations from my sweetening unit...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... monitoring of emissions and operations from my sweetening unit affected facilities at onshore natural gas... Performance for Crude Oil and Natural Gas Production, Transmission and Distribution § 60.5407 What are the... natural gas processing plants? (a) If your sweetening unit affected facility is located at an...

  2. 40 CFR 60.5407 - What are the requirements for monitoring of emissions and operations from my sweetening unit...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... monitoring of emissions and operations from my sweetening unit affected facilities at onshore natural gas... Performance for Crude Oil and Natural Gas Production, Transmission and Distribution § 60.5407 What are the... natural gas processing plants? (a) If your sweetening unit affected facility is located at an...

  3. Performance testing of multi-metal continuous emissions monitors

    SciTech Connect

    Haas, W.J.; French, N.B.; Brown, C.H.; Burns, D.B.; Lemieux, P.M.; Ryan, J.V.; Priebe, S.J.; Waterland, L.R.

    1997-11-17

    Three prototype multi-metals continuous emissions monitors (CEMs) were tested in April 1996 at the Rotary Kiln Incinerator Simulator facility at the US Environmental Protection Agency (EPA) National Risk Management Research Laboratory, Research Triangle Park, North Carolina. The CEM instruments were: Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES); Laser Induced Breakdown Spectrometry-Atomic Emission Spectroscopy (LIBS); and Laser Spark Spectrometry, another LIBS instrument. The three CEMs were tested simultaneously during test periods in which low, medium, and high concentration levels of seven toxic metals -- antimony, arsenic, beryllium, cadmium, chromium, lead, and mercury -- were maintained under carefully controlled conditions. Two methods were used to introduce the test metals into the flue gas: (1) solution atomization, introducing metal-containing aerosol directly into the secondary combustion burner, and (2) injection of fly ash particulates. The testing addressed four measures of CEM performance: relative accuracy (RA), calibration drift, zero drift, and response time. These were accomplished by comparing the toxic metal analyte concentrations reported by the CEMs to the concentrations measured using the EPA reference method (RM) for the same analytes. Overall, the test results showed the prototype nature of the test CEMs and the clear need for further development. None of the CEMs tested consistently achieved RA values of 20% or less as required by the EPA draft performance specification. Instrument size reduction and automation will also likely need additional attention before multi-metal CEMs systems become commercially available for service as envisioned by regulators and citizens.

  4. ANALYSIS OF EMISSIONS FROM RESIDENTIAL NATURAL GAS FURNACES

    EPA Science Inventory

    The paper gives emissions data from residential natural-gas furnaces and compares selected data to emissions data from residential oil furnaces and woodstoves. atural-gas furnace emissions data are given for carbon monoxide (CO), unburned hydrocarbons, aldehydes, volatile and sem...

  5. Apparatus and method for monitoring of gas having stable isotopes

    DOEpatents

    Clegg, Samuel M; Fessenden-Rahn, Julianna E

    2013-03-05

    Gas having stable isotopes is monitored continuously by using a system that sends a modulated laser beam to the gas and collects and transmits the light not absorbed by the gas to a detector. Gas from geological storage, or from the atmosphere can be monitored continuously without collecting samples and transporting them to a lab.

  6. 40 CFR 60.73a - Emissions testing and monitoring.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... and stack gas flow rate, you will determine hourly NOX emissions rate (e.g., lb/hr) and with measured..., and operate a CEMS for measuring and recording the concentration of NOX emissions in accordance with... calculate hourly NOX emissions rates in units of the standard (lb/ton acid) for each hour of...

  7. Is predictive emission monitoring an acceptable low cost alternative to continuous emission monitoring for complying with enhanced monitoring requirements?

    SciTech Connect

    Jernigan, J.R.

    1995-12-01

    Title VII of the 1990 Clean Air Act Amendments (the {open_quotes}Act{close_quotes}) expanded and clarified the Environmental Protection Agency`s (EPA) enforcement capabilities under the Act. Section 702 of the 1990 Amendments clarified EPA`s ability to require sources to provide information. Additionally, Section 702(b) required EPA to promulgate rules on enhanced monitoring and compliance certifications by adding a new section 114(a)(3) of the Act which states in part: {open_quotes}The Administrator shall in the case of any person which is the owner or operator of a major stationary source, and any in the case of any other person, require enhanced monitoring and submission of compliance certifications. Compliance certifications shall include (A) identification of the applicable requirement that is the basis of the certification, (B) the method used for determining the compliance status of the source, (C) the compliance status, (D) whether compliance is continuous or intermittent, (E) such other facts as the Administrator may require...{close_quotes} The 1990 Amendments contained several other changes that either relate directly to section 114(a)(3) or provide additional indications of the intent behind the new section. First, section 504(b) of the Amendments permits the Administrator to promulgate appropriate tests methods and monitoring requirements for determining compliance. That section states that {open_quotes}continuous emissions monitoring need not be required if alternative methods are available that provide sufficiently reliable and timely information for determining compliance.{close_quotes} This paper will describe Predictive Emission Systems (PEMS) and how the applications of PEMS may be a low cost, accurate, and acceptable alternative to Continuous Emission Monitoring Systems (CEMS) for complying with Enhanced Monitoring requirements.

  8. 40 CFR 60.284 - Monitoring of emissions and operations.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... opacity. (2) Continuous monitoring systems to monitor and record the concentration of TRS emissions on a... continuous monitoring system(s) shall be set: (i) At a TRS concentration of 30 ppm for the TRS continuous... the following: (1) Calculate and record on a daily basis 12-hour average TRS concentrations for...

  9. 40 CFR 60.284 - Monitoring of emissions and operations.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... opacity. (2) Continuous monitoring systems to monitor and record the concentration of TRS emissions on a... continuous monitoring system(s) shall be set: (i) At a TRS concentration of 30 ppm for the TRS continuous... the following: (1) Calculate and record on a daily basis 12-hour average TRS concentrations for...

  10. 40 CFR 60.284 - Monitoring of emissions and operations.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... opacity. (2) Continuous monitoring systems to monitor and record the concentration of TRS emissions on a... continuous monitoring system(s) shall be set: (i) At a TRS concentration of 30 ppm for the TRS continuous... the following: (1) Calculate and record on a daily basis 12-hour average TRS concentrations for...

  11. 40 CFR 60.284 - Monitoring of emissions and operations.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... opacity. (2) Continuous monitoring systems to monitor and record the concentration of TRS emissions on a... continuous monitoring system(s) shall be set: (i) At a TRS concentration of 30 ppm for the TRS continuous... the following: (1) Calculate and record on a daily basis 12-hour average TRS concentrations for...

  12. 40 CFR 60.284 - Monitoring of emissions and operations.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... opacity. (2) Continuous monitoring systems to monitor and record the concentration of TRS emissions on a... continuous monitoring system(s) shall be set: (i) At a TRS concentration of 30 ppm for the TRS continuous... the following: (1) Calculate and record on a daily basis 12-hour average TRS concentrations for...

  13. 40 CFR 60.105 - Monitoring of emissions and operations.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... CO continuous monitoring system under § 60.105(a)(2) exceeds 500 ppm. (3) Sulfur dioxide from fuel.... 60.105 Section 60.105 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Petroleum Refineries § 60.105 Monitoring of emissions and operations. (a) Continuous monitoring...

  14. 40 CFR 60.105 - Monitoring of emissions and operations.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... CO continuous monitoring system under § 60.105(a)(2) exceeds 500 ppm. (3) Sulfur dioxide from fuel.... 60.105 Section 60.105 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Petroleum Refineries § 60.105 Monitoring of emissions and operations. (a) Continuous monitoring...

  15. 40 CFR 60.105 - Monitoring of emissions and operations.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... CO continuous monitoring system under § 60.105(a)(2) exceeds 500 ppm. (3) Sulfur dioxide from fuel.... 60.105 Section 60.105 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Petroleum Refineries § 60.105 Monitoring of emissions and operations. (a) Continuous monitoring...

  16. 40 CFR 60.105 - Monitoring of emissions and operations.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... CO continuous monitoring system under § 60.105(a)(2) exceeds 500 ppm. (3) Sulfur dioxide from fuel.... 60.105 Section 60.105 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Petroleum Refineries § 60.105 Monitoring of emissions and operations. (a) Continuous monitoring...

  17. 40 CFR 60.105 - Monitoring of emissions and operations.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... CO continuous monitoring system under § 60.105(a)(2) exceeds 500 ppm. (3) Sulfur dioxide from fuel.... 60.105 Section 60.105 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Petroleum Refineries § 60.105 Monitoring of emissions and operations. (a) Continuous monitoring...

  18. ENVIRONMENTAL TECHNOLOGY VERIFICATION (ETV) TEST OF DIOXIN EMISSION MONITORS

    EPA Science Inventory

    The performance of four dioxin emission monitors including two long-term sampling devices, the DMS (DioxinMonitoringSystem) and AMESA (Adsorption Method for Sampling Dioxins and Furans), and two semi-real-time continuous monitors, RIMMPA-TOFMS (Resonance Ionization with Multi-Mir...

  19. WORKSHOP ON SOURCE EMISSION AND AMBIENT AIR MONITORING OF MERCURY

    EPA Science Inventory

    AN EPA/ORD Workshop on Source Emission and Ambient Air Monitoring of Mercury was held on 9/13-14/99, Bloomington, Minnesota. The purpose of the workshop was to discuss the state-of-the-science in source and ambient air mercury monitoring as well as mercury monitoring research and...

  20. 40 CFR 61.163 - Emission monitoring.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... requirements and procedures contained in Performance Specification 1 of appendix B of 40 CFR part 60. (c...) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Inorganic...

  1. 40 CFR 61.163 - Emission monitoring.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... requirements and procedures contained in Performance Specification 1 of appendix B of 40 CFR part 60. (c...) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Inorganic...

  2. 40 CFR 61.163 - Emission monitoring.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... requirements and procedures contained in Performance Specification 1 of appendix B of 40 CFR part 60. (c...) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Inorganic...

  3. 40 CFR 61.163 - Emission monitoring.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... requirements and procedures contained in Performance Specification 1 of appendix B of 40 CFR part 60. (c...) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Inorganic...

  4. Carbonyl Emissions From Oil and Gas Production Facilities

    NASA Astrophysics Data System (ADS)

    Lyman, S. N.; O'Neil, T.; Tran, T.

    2015-12-01

    A number of recent studies have targeted emissions of methane and other hydrocarbons from oil and gas exploration and production activity. These measurements are greatly increasing understanding of the atmospheric impacts of oil and gas development. Very few measurements exist, however, of emissions of formaldehyde and other carbonyls from oil and gas equipment. Carbonyls are toxic and serve as important ozone precursors, especially during winter ozone episodes in places like Utah's Uintah Basin. Current air quality models are only able to reproduce observed high wintertime ozone if they incorporate emissions inventories with very high carbonyl emissions. We measured carbonyl emissions from oil and gas equipment and facilities—including glycol dehydrators, liquid storage tanks, raw gas leaks, raw gas-burning engines, and produced water surface impoundments—in Rocky Mountain oil and gas fields. Carbonyl emissions from raw gas were below detection, but emissions of formaldehyde, acetaldehyde, and other carbonyls were detected from liquid storage tanks, glycol dehydrators, and other oil and gas equipment. In some cases, carbonyls may be formed from the degradation of methanol and other chemicals used in oil and gas production, but the collected data provide evidence for other non-combustion formation pathways. Raw gas-burning engines also emitted carbonyls. Emissions from all measured sources were a small fraction of total volatile organic compound emissions. We incorporated our measurements into an emissions inventory, used that inventory in an air quality model (WRF-SMOKE-CAMx), and were unable to reproduce observed high wintertime ozone. This could be because (1) emission sources we have not yet measured, including compressors, gas processing plants, and others, are large; (2) non-carbonyl emissions, especially those that quickly degrade into carbonyls during photochemical processing, are underestimated in the inventory; or (3) the air quality model is unable

  5. Greenhouse gas emissions from a managed grassland

    NASA Astrophysics Data System (ADS)

    Jones, S. K.; Rees, R. M.; Skiba, U. M.; Ball, B. C.

    2005-07-01

    Managed grasslands contribute to global warming by the exchange of the greenhouse gases carbon dioxide, nitrous oxide and methane. To reduce uncertainties of the global warming potential of European grasslands and to assess potential mitigation options, an integrated approach quantifying fluxes from all three gases is needed. Greenhouse gas emissions from a grassland site in the SE of Scotland were measured in 2002 and 2003. Closed static chambers were used for N 2O and CH 4 flux measurements, and samples were analysed by gas chromatography. Closed dynamic chambers were used for soil respiration measurements, using infrared gas analysis. Three organic manures and two inorganic fertilizers were applied at a rate of 300 kg N ha -1 a -1 (available N) and compared with a zero-N control on grassland plots in a replicated experimental design. Soil respiration from plots receiving manure was up to 1.6 times larger than CO 2 release from control plots and up to 1.7 times larger compared to inorganic treatments ( p<0.05). A highly significant ( p<0.001) effect of fertilizer and manure treatments on N 2O release was observed. Release of N 2O from plots receiving inorganic fertilizers resulted in short term peaks of up to 388 g N 2O-N ha -1 day -1. However losses from plots receiving organic manures were both longer lasting and greater in magnitude, with an emission of up to 3488 g N 2O-N ha -1 day -1 from the sewage sludge treatments. During the 2002 growing season the cumulative total N 2O flux from manure treatments was 25 times larger than that from mineral fertilizers. CH 4 emissions were only significantly increased ( p<0.001) for a short period following applications of cattle slurry. Although soil respiration in manure plots was high, model predictions and micrometeorological flux measurements at an adjacent site suggest that all plots receiving fertilizer or manure acted as a sink for CO 2. Therefore in terms of global warming potentials the contribution of N 2O from

  6. Inherently safe passive gas monitoring system

    DOEpatents

    Cordaro, Joseph V.; Bellamy, John Stephen; Shuler, James M.; Shull, Davis J.; Leduc, Daniel R.

    2016-09-06

    Generally, the present disclosure is directed to gas monitoring systems that use inductive power transfer to safely power an electrically passive device included within a nuclear material storage container. In particular, the electrically passive device can include an inductive power receiver for receiving inductive power transfer through a wall of the nuclear material storage container. The power received by the inductive power receiver can be used to power one or more sensors included in the device. Thus, the device is not required to include active power generation components such as, for example, a battery, that increase the risk of a spark igniting flammable gases within the container.

  7. Air Monitoring for Hazardous Gas Detection

    NASA Technical Reports Server (NTRS)

    Arkin, C. Richard; Griffin, Timothy P.; Adams, Frederick W.; Naylor, Guy; Haskell, William; Floyd, David; Curley, Charles; Follistein, Duke W.

    2004-01-01

    The Hazardous Gas Detection Lab (HGDL) at Kennedy Space Center is involved in the design and development of instrumentation that can detect and quantify various hazardous gases. Traditionally these systems are designed for leak detection of the cryogenic gases used for the propulsion of the Shuttle and other vehicles. Mass spectrometers are the basis of these systems, which provide excellent quantitation, sensitivity, selectivity, response times and detection limits. A Table lists common gases monitored for aerospace applications. The first five gases, hydrogen, helium, nitrogen, oxygen, and argon are historically the focus of the HGDL.

  8. Sensitivity of detection of fugitive methane emissions from coal seam gas fields

    NASA Astrophysics Data System (ADS)

    Feitz, A. J.; Berko, H.; Wilson, P.; Jenkins, C.; Loh, Z. M.; Etheridge, D.

    2013-12-01

    There is increasing recognition that minimising methane emissions from the oil and gas sector is a key step in reducing global greenhouse gas emissions in the near term. Atmospheric monitoring techniques are likely to play an important future role in measuring the extent of existing emissions and verifying emission reductions. They can be very suitable for monitoring gas fields as they are continuous and integrate emissions from a number of potential point and diffuse sources that may vary in time. Geoscience Australia and CSIRO Marine & Atmospheric Research have collected three years of continuous methane and carbon dioxide measurements at their atmospheric composition monitoring station ('Arcturus') in the Bowen Basin, Australia. Methane signals in the Bowen Basin are likely to be influenced by cattle production, landfill, coal production, and conventional and coal seam gas (CSG) production. Australian CSG is typically 'dry' and is characterised by a mixed thermogenic-biogenic methane source with an absence of C3-C6+ alkanes. The range of δ13C isotopic signatures of the CSG is similar to methane from landfill gas and cattle emissions. The absence of standard in-situ tracers for CSG fugitive emissions suggests that having a comprehensive baseline will be critical for successful measurement of fugitive emissions using atmospheric techniques. In this paper we report on the sensitivity of atmospheric techniques for the detection of fugitive emissions from a simulated new CSG field against a three year baseline signal. Simulation of emissions was performed for a 1-year period using the coupled prognostic meteorological and air pollution model TAPM at different fugitive emission rates (i.e. estimates of <1% to up to 10% of production lost) and distances (i.e. 10 - 50 km) from the station. Emissions from the simulated CSG field are based on well density, production volumes, and field size typical of CSG fields in Australia. The distributions of the perturbed and

  9. 40 CFR 61.68 - Emission monitoring.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... be used to meet the requirements of this section. (c) A daily span check is to be conducted for each... section, except the one for which an emission limit is prescribed in § 61.62(b), the daily span check is... which an emission limit is prescribed in § 61.62(b), the daily span check is to be conducted with...

  10. Greenhouse gas and alcohol emissions from feedlot steers and calves.

    PubMed

    Stackhouse, Kimberly R; Pan, Yuee; Zhao, Yongjing; Mitloehner, Frank M

    2011-01-01

    Livestock's contributions to climate change and smog-forming emissions are a growing public policy concern. This study quantifies greenhouse gas (GHG) and alcohol emissions from calves and feedlot steers. Carbon dioxide (CO) methane (CH), nitrous oxide (NO), ethanol (EtOH), and methanol (MeOH) were measured from a total of 45 Holstein and Angus steers and 9 Holstein calves representative of four different growth stages commonly present on calf ranches and commercial feedlots. Individuals from each animal type were randomly assigned to three equal replicate groups of nine animals per group. Steers were fed a high concentrate diet and calves a milk replacer and grain supplement. Cattle and calves were housed in groups of three animals in an environmental chamber for 24 h. The CO, NO, EtOH, and MeOH concentrations from the air inlet and outlet of the chamber were measured using an INNOVA 1412 monitor and CH using a TEI 55C methane analyzer. Emission rates (g head h) were calculated. The GHGs were mainly produced by enteric fermentation and respiration and differed across life stages of cattle. Compared with dairy cows, feedlot steers produce relatively less GHG. In general, ethanol and methanol, the most important volatile organic compound (VOC) group in the dairy sector, were below the lower limit of detection of the gas analyzer. The present data will be useful to verify models and to enhance GHG emission inventories for enteric fermentation, respiration, and fresh excreta for numerous cattle life stages across the beef industry. PMID:21546675

  11. DEVELOPMENT OF A MONITOR FOR HCN IN MOBILE SOURCE EMISSIONS

    EPA Science Inventory

    Three real-time monitors for measurement of HCN concentrations in mobile source emissions have been designed, built, tested, and delivered to the Environmental Protection Agency (EPA). The important design parameters for these identical instruments were determined during the firs...

  12. A CAVITY RINGDOWN SPECTROSCOPY MERCURY CONTINUOUS EMISSION MONITOR

    SciTech Connect

    Christopher C. Carter, Ph.D.

    2002-01-01

    The first quarter of this project to develop a Cavity Ringdown Spectroscopy mercury continuous emission monitor involved acquisition and verification of the laser system to be used, initial cavity design, and initial software development for signal processing and data acquisition.

  13. Enhanced nighttime gas emissions from a lake

    NASA Astrophysics Data System (ADS)

    Podgrajsek, E.; Sahlée, E.; Rutgersson, A.

    2016-05-01

    Methane (CH4) and carbon dioxide (CO2) are two important greenhouse gases. Previous studies have shown that lakes can be important natural sources of atmospheric CH4 and CO2. It is therefore important to monitor the fluxes of these gases between lakes and the atmosphere in order to understand the processes that govern the exchange. Most previous lake flux studies are based on chamber measurements, by using the eddy covariance method, the resolution in time and in space of the fluxes is increased, which gives more information on the governing processes. Eddy covariance measurements at a Swedish lake show that both methane fluxes (FCH4 ) and carbon dioxide fluxes (FCO2 ) experience high nighttime fluxes for a large part of the data set (largest median FCH4night ≈ 13 nmol m2 s-1 and smallest median FCH4day ≈ 4.0 nmol m-2 s-1, largest median FCO2night ≈ 0.2 μmol m2 s-1 and smallest median FCO2day ≈ 0.02 μmol m-2 s-1, with larger variability during night). For the diel cycle of the CH4 fluxes it is suggested that water side convection could enhance the transfer velocity, transport CH4 rich water to the surface, as well as trigger ebullition. The high nighttime CO2 fluxes could to a large extent be explained with enhanced transfer velocities due to water side convection. If gas fluxes are not measured during nighttime, when water side convection normally is generated, periods of potential high gas flux might be missed and estimations of the total amount of gas released from lakes to the atmosphere will be biased.

  14. Greenhouse gas emissions from constructed wetlands treating dairy wastewater

    NASA Astrophysics Data System (ADS)

    Glass, Vimy M.

    In Nova Scotia, constructed wetland systems are widely considered as effective treatment systems for agricultural wastewater. Although research has examined the water quality treatment attributes, there has been limited focus on the air quality effects of these systems. Six operational pilot-scale constructed wetlands were built with flow-through chambers for quantifying greenhouse gas (GHG) emissions in Truro, NS. Utilized within this facility were three gas analyzers to monitor GHG emissions (CO2, N 2O, CH4) and the gaseous fluxes could then be determined using the mass balance micrometeorological technique. Prior to data collection, the site underwent testing to ensure valid conclusions and replicated responses from the wetland systems. Those wetlands receiving wastewater at a typical HLR (10.6 mm d-1) and with ample vegetation displayed the best concentration reductions. During the growing season (GS), average CO 2 consumption was large (approximately -44 g CO2m -2 d-1) for wetlands with dense vegetation (approximately 100% cover) at the typical loading rate. For those wetlands at higher loading rates, CO2 emissions were observed to be as high as +9.2 g CO 2m-2 d-1. Wetlands with typical loading rates and healthy aquatic vegetation produced average CH4 fluxes of approximately 43 g CO2 eq. m-2d-1, while higher loaded systems with little vegetation approached 90 g CO 2 eq. m-2d-1. During the non-growing season (NGS), all vegetated wetlands exhibited higher CH4 emissions than the non-vegetated systems (˜15 to 20% higher). Vegetation maturity played a strong role in the GHG balance. The average CO2consumption for wetlands with established vegetation was ˜ -36 g CO2 m -2 d-1 during the GS. Wetland 4, which had been newly transplanted in 2004, had the highest single day CO2 consumption of -152 g CO2m-2 d-1 . Methane emissions from wetlands with two-year-old vegetation followed the same pattern but were approximately half of the emissions recorded from 2003. The

  15. Greenhouse Gas Emissions Calculator for Grain and Biofuel Farming Systems

    ERIC Educational Resources Information Center

    McSwiney, Claire P.; Bohm, Sven; Grace, Peter R.; Robertson, G. Philip

    2010-01-01

    Opportunities for farmers to participate in greenhouse gas (GHG) credit markets require that growers, students, extension educators, offset aggregators, and other stakeholders understand the impact of agricultural practices on GHG emissions. The Farming Systems Greenhouse Gas Emissions Calculator, a web-based tool linked to the SOCRATES soil…

  16. 40 CFR 1036.530 - Calculating greenhouse gas emission rates.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... applicable duty cycle as specified in 40 CFR 1065.650. Do not apply infrequent regeneration adjustment... 40 Protection of Environment 34 2013-07-01 2013-07-01 false Calculating greenhouse gas emission... Procedures § 1036.530 Calculating greenhouse gas emission rates. This section describes how to...

  17. Greenhouse gas emissions from traditional and biofuels cropping systems

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Cropping systems can have a tremendous effect on the greenhouse gas emissions from soils. The objectives of this study were to compare greenhouse gas emissions from traditional (continuous corn or corn/soybean rotation) and biomass (miscanthus, sorghum, switchgrass) cropping systems. Biomass croppin...

  18. Life cycle greenhouse gas emissions from bioenergy crops

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Life cycle greenhouse gas emissions from bioenergy crops Bioenergy cropping systems could help offset greenhouse gas emissions from energy use, but quantifying that offset is complex. We conducted a life cycle assessment of a range of bioenergy cropping systems to determine the impact on net greenho...

  19. 40 CFR 60.45 - Emissions and fuel monitoring.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Emissions and fuel monitoring. 60.45 Section 60.45 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS...-Fired Steam Generators for Which Construction Is Commenced After August 17, 1971 § 60.45 Emissions...

  20. 40 CFR 60.45 - Emissions and fuel monitoring.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Emissions and fuel monitoring. 60.45 Section 60.45 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS...-Fired Steam Generators for Which Construction Is Commenced After August 17, 1971 § 60.45 Emissions...

  1. 40 CFR 60.464 - Monitoring of emissions and operations.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Coil Surface Coating § 60.464 Monitoring of emissions and operations. (a) Where compliance with the numerical limit specified in § 60.462(a) (1) or (2) is achieved through the use of low VOC-content coatings without the use of emission control devices or through the use of higher VOC-content coatings...

  2. 40 CFR 63.848 - Emission monitoring requirements.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... and POM emissions from anode bake furnaces. Using the procedures in § 63.847 and in the approved test plan, the owner or operator shall monitor TF and POM emissions from each anode bake furnace on an... owner or operator of a new or existing potline or anode bake furnace shall install, operate,...

  3. 40 CFR 60.703 - Monitoring of emissions and operations.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Monitoring of emissions and operations. 60.703 Section 60.703 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Volatile Organic Compound Emissions From...

  4. 40 CFR 60.613 - Monitoring of emissions and operations.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Monitoring of emissions and operations. 60.613 Section 60.613 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Volatile Organic Compound (VOC) Emissions From...

  5. 40 CFR 60.663 - Monitoring of emissions and operations.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Monitoring of emissions and operations. 60.663 Section 60.663 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Volatile Organic Compound (VOC) Emissions...

  6. Oxygen sensor for monitoring gas mixtures containing hydrocarbons

    DOEpatents

    Ruka, Roswell J.; Basel, Richard A.

    1996-01-01

    A gas sensor measures O.sub.2 content of a reformable monitored gas containing hydrocarbons H.sub.2 O and/or CO.sub.2, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system.

  7. Oxygen sensor for monitoring gas mixtures containing hydrocarbons

    DOEpatents

    Ruka, R.J.; Basel, R.A.

    1996-03-12

    A gas sensor measures O{sub 2} content of a reformable monitored gas containing hydrocarbons, H{sub 2}O and/or CO{sub 2}, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system. 4 figs.

  8. Analysis of carbon dioxide emission of gas fuelled cogeneration plant

    NASA Astrophysics Data System (ADS)

    Nordin, Adzuieen; Amin, M.; Majid, A.

    2013-12-01

    Gas turbines are widely used for power generation. In cogeneration system, the gas turbine generates electricity and the exhaust heat from the gas turbine is used to generate steam or chilled water. Besides enhancing the efficiency of the system, the process assists in reducing the emission of CO2 to the environment. This study analyzes the amount of CO2 emission by Universiti Teknologi Petronas gas fuelled cogeneration system using energy balance equations. The results indicate that the cogeneration system reduces the CO2 emission to the environment by 60%. This finding could encourage the power plant owners to install heat recovery systems to their respective plants.

  9. ETV TEST OF PCDD/F EMISSIONS MONITORING SYSTEMS

    EPA Science Inventory

    Four polychlorinated dibenzodioxin and furan (PCDD/F) emission monitors were tested under the EPA Environmental Technology and Verification (ETV) program. Two long-term sampling devices, the DioxinMonitoringSystem and Adsorption Method for Sampling Dioxins and Furans, and two sem...

  10. Portable spectrometer monitors inert gas shield in welding process

    NASA Technical Reports Server (NTRS)

    Grove, E. L.

    1967-01-01

    Portable spectrometer using photosensitive readouts, monitors the amount of oxygen and hydrogen in the inert gas shield of a tungsten-inert gas welding process. A fiber optic bundle transmits the light from the welding arc to the spectrometer.

  11. Mitigation potential and costs for global agricultural greenhouse gas emissions

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Agricultural activities are a substantial contributor to global greenhouse gas (GHG) emissions, accounting for about 58% of the world’s anthropogenic non-carbon dioxide GHG emissions and 14% of all anthropogenic GHG emissions, and agriculture is often viewed as a potential source of relatively low-c...

  12. USERS MANUAL: LANDFILL GAS EMISSIONS MODEL - VERSION 2.0

    EPA Science Inventory

    The document is a user's guide for a computer model, Version 2.0 of the Landfill Gas Emissions Model (LandGEM), for estimating air pollution emissions from municipal solid waste (MSW) landfills. The model can be used to estimate emission rates for methane, carbon dioxide, nonmet...

  13. EVALUATION OF DIOXIN EMISSIONS MONITORING SYSTEMS

    EPA Science Inventory

    Continuous samplers and real or semi-real-time continuous monitors for polychlorinated dibenzodioxins and furans provide significant advantages relative to conventional methods of extractive sampling. Continuous samplers collect long term samples over a time period of days to wee...

  14. Greenhouse gas emissions from heavy-duty vehicles

    NASA Astrophysics Data System (ADS)

    Graham, Lisa A.; Rideout, Greg; Rosenblatt, Deborah; Hendren, Jill

    This paper summarizes greenhouse gas (GHG) emissions measurements obtained during several recent studies conducted by Environment Canada, Emissions Research and Measurement Division (ERMD). A variety of heavy-duty vehicles and engines operating on a range of different fuels including diesel, biodiesel, compressed natural gas (CNG), hythane (20% hydrogen, 80% CNG), and liquefied natural gas (LNG), and with different advanced aftertreatment technologies were studied by chassis dynamometer testing, engine dynamometer testing or on-road testing. Distance-based emission rates of CO 2, CH 4, and N 2O are reported. Fuel consumption calculated by carbon balance from measured emissions is also reported. The measurement results show, for heavy-duty diesel vehicles without aftertreatment, that while CO 2 emissions dominate, CH 4 emissions account for between 0% and 0.11% and N 2O emissions account for between 0.16% and 0.27% of the CO 2-equivalent GHG emissions. Both of the aftertreatment technologies (diesel oxidation catalyst and active regeneration diesel particle filter) studied increased N 2O emissions compared to engine out emissions while CH 4 emissions remain essentially unchanged. No effect on tailpipe GHG emissions was found with the use of up to 20% biodiesel when the engine was equipped with an oxidation catalyst. Biodiesel use did show some reductions in tailpipe GHG emissions as compared to ULSD without aftertreatment and with the use of a diesel particle filter. Natural gas and hythane also offer decreased GHG emissions (10-20%) at the tailpipe when compared with diesel. Emission factors (g L -1 fuel) for CH 4 and N 2O are suggested for heavy-duty vehicles fueled with diesel-based fuels and natural gas. These emission factors are substantially lower than those recommended for use by IPCC methodologies for developing national inventories.

  15. Lifecycle greenhouse gas emissions of coal, conventional and unconventional natural gas for electricity generation

    EPA Science Inventory

    An analysis of the lifecycle greenhouse gas (GHG) emissions associated with natural gas use recently published by Howarth et al. (2011) stated that use of natural gas produced from shale formations via hydraulic fracturing would generate greater lifecycle GHG emissions than petro...

  16. Long-term flow monitoring of submarine gas emanations

    NASA Astrophysics Data System (ADS)

    Spickenbom, K.; Faber, E.; Poggenburg, J.; Seeger, C.

    2009-04-01

    One of the Carbon Capture and Storage (CCS) strategies currently under study is the sequestration of CO2 in sub-seabed geological formations. Even after a thorough review of the geological setting, there is the possibility of leaks from the reservoirs. As part of the EU-financed project CO2ReMoVe (Research, Monitoring, Verification), which aims to develop innovative research and technologies for monitoring and verification of carbon dioxide geological storage, we are working on the development of submarine long-term gas flow monitoring systems. Technically, however, these systems are not limited to CO2 but can be used for monitoring of any free gas emission (bubbles) on the seafloor. The basic design of the gas flow sensor system was derived from former prototypes developed for monitoring CO2 and CH4 on mud volcanoes in Azerbaijan. This design was composed of a raft floating on the surface above the gas vent to collect the bubbles. Sensors for CO2 flux and concentration and electronics for data storage and transmission were mounted on the raft, together with battery-buffered solar panels for power supply. The system was modified for installation in open sea by using a buoy instead of a raft and a funnel on the seafloor to collect the gas, which is then guided above water level through a flexible tube. Besides some technical problems (condensed water in the tube, movement of the buoys due to waves leading to biased measurement of flow rates), this setup provides a cost-effective solution for shallow waters. However, a buoy interferes with ship traffic, and it is also difficult to adapt this design to greater water depths. These requirements can best be complied by a completely submersed system. To allow unattended long-term monitoring in a submarine environment, such a system has to be extremely durable. Therefore, we focussed on developing a mechanically and electrically as simple setup as possible, which has the additional advantage of low cost. The system

  17. Volcanic Carbon: Global Variations in Gas Emissions

    NASA Astrophysics Data System (ADS)

    Fischer, T. P.; de Moor, M. J.

    2014-12-01

    Magmas degas volatiles during ascent from the mantle and mafic melts with 7 wt% H2O attain volatile saturation at ~15km depth. Magmatic gases are dominated by H2O, CO2 and S species, independent of their tectonic setting. At rift volcanoes, C is sourced from the mantle whereas arc volcanoes sample both mantle and subducted C. Volcanic gases provide detailed information on volatile sources and degassing processes. Comparison of fumarole gases with melt inclusions and volcanic plumes shows that most fumaroles sample degassed magma. Water, CO2 and S vary significantly between tectonic settings. The Kuriles, Japan, and Kamchatka have H2O/CO2 of 40 to 800 while other arcs such as the Cascades, Central America, S. America, Java, and Aeolian have ratios of 1 to 70. Gases from rift volcanoes have H2O/CO2 between 3 and 9. Some of these variations are due to addition of meteoric and subducted water, as evidenced by O and H isotopes. Speciation of H and C in volcanic gases are typically controlled by redox buffer reactions imposed by the Fe3+-Fe2+ (i.e. QFM) rock buffer or the SO2-H2S gas buffer. In more exotic systems such as Poás, hydrothermal S phases such as liquid native S can play a role in high T gas C and H speciation. Arcs dominate the global subaerial volcanic CO2 emission budget and arc total fluxes vary significantly i.e. only about 2 t/yr/km from the Aleutians and about 65 t/yr/km from Central America. Reasons for this are poorly constrained and may include variability in subducted material or slab/mantle conditions at depth. A large uncertainty results from use of generalized arc-wide C/S ratios, used in calculating C fluxes, and the paucity of data for remote arcs. Resolving C fluxes from subducted versus mantle or crustal (assimilated) C relies on C isotope ratios, which can vary spatially and temporally as a function of source or degassing processes. Therefore, when considering the deep C cycle and Cexchange between the interior and surface of the Earth

  18. Can trace gas emission be modified by management scenarios in the northern Corn Belt?

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Field plots were established in 2002 in west central Minnesota to compare tillage, rotation and fertilizer treatments and to identify and develop economically-viable and environmentally- sustainable farming systems. Greenhouse gas emission (nitrous oxide, methane and carbon dioxide) was monitored in...

  19. Greenhouse Gas Emission from Contrasting Management Scenarios in the Northern Corn Belt

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Long-term cropping systems field plots were established in 2002 in west central Minnesota to compare tillage, rotation and fertilizer treatments and to identify and develop economically viable and environmentally sustainable farming systems. Greenhouse gas (GHG) emission was monitored in three scena...

  20. 40 CFR 60.105a - Monitoring of emissions and operations for fluid catalytic cracking units (FCCU) and fluid coking...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... monitoring exhaust gas flow rate in 40 CFR 63.1573(a) of the National Emission Standards for Hazardous Air... to part 60. (ii) The owner or operator shall conduct performance evaluations of each CO2, O2 and CO... part 60, including quarterly accuracy determinations for CO2 and CO monitors, annual...

  1. 40 CFR 60.105a - Monitoring of emissions and operations for fluid catalytic cracking units (FCCU) and fluid coking...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... monitoring exhaust gas flow rate in 40 CFR 63.1573(a) of the National Emission Standards for Hazardous Air... to part 60. (ii) The owner or operator shall conduct performance evaluations of each CO2, O2 and CO... part 60, including quarterly accuracy determinations for CO2 and CO monitors, annual...

  2. Noble gas atmospheric monitoring at reprocessing facilities

    SciTech Connect

    Nakhleh, C.W.; Perry, R.T. Jr.; Poths, J.; Stanbro, W.D.; Wilson, W.B.; Fearey, B.L.

    1997-05-01

    The discovery in Iraq after the Gulf War of the existence of a large clandestine nuclear-weapon program has led to an across-the-board international effort, dubbed Programme 93+2, to improve the effectiveness and efficiency of International Atomic Energy Agency (IAEA) safeguards. One particularly significant potential change is the introduction of environmental monitoring (EM) techniques as an adjunct to traditional safeguards methods. Monitoring of stable noble gas (Kr, Xe) isotopic abundances at reprocessing plant stacks appears to be able to yield information on the burnup and type of the fuel being processed. To estimate the size of these signals, model calculations of the production of stable Kr, Xe nuclides in reactor fuel and the subsequent dilution of these nuclides in the plant stack are carried out for two case studies: reprocessing of PWR fuel with a burnup of 35 GWd/tU, and reprocessing of CAND fuel with a burnup of 1 GWd/tU. For each case, a maximum-likelihood analysis is used to determine the fuel burnup and type from the isotopic data.

  3. Air Monitoring for Hazardous Gas Detection

    NASA Technical Reports Server (NTRS)

    Arkin, C. Richard; Naylor, Guy; Haskell, William; Floyd, David; Curley, Charles; Griffin, Timothy P.; Adams, Frederick; Follistein, Duke

    2003-01-01

    The Hazardous Gas Detection Lab is involved in the design and development of instrumentation that can detect and quantify various hazardous gases. Traditionally these systems are designed for leak detection of the cryogenic gases used for the propulsion of the Shuttle and other vehicles. Mass spectrometers are the basis of these systems, which provide excellent quantitation, sensitivity, selectivity, response and limits of detection. Unfortunately, these systems are large, heavy and expensive. This feature limits the ability to perform gas analysis in certain applications. Smaller and lighter mass spectrometer systems could be used in many more applications primarily due to the portability of the system. Such applications would include air analysis in confined spaces, in-situ environmental analysis and emergency response. In general, system cost is lowered as size is reduced. With a low cost air analysis system, several systems could be utilized for monitoring large areas. These networked systems could be deployed at job-sites for worker safety, throughout a community for pollution warnings, or dispersed in a battlefield for early warning of chemical or biological threats. Presented will be information on the first prototype of this type of system. Included will be field trial data, with this prototype performing air analysis autonomously from an aircraft.

  4. Gas emissions and active tectonics within the submerged section of the North Anatolian Fault zone in the Sea of Marmara

    NASA Astrophysics Data System (ADS)

    Géli, L.; Henry, P.; Zitter, T.; Dupré, S.; Tryon, M.; Çağatay, M. N.; de Lépinay, B. Mercier; Le Pichon, X.; Şengör, A. M. C.; Görür, N.; Natalin, B.; Uçarkuş, G.; Özeren, S.; Volker, D.; Gasperini, L.; Burnard, P.; Bourlange, S.; Marnaut Scientific Party

    2008-09-01

    The submerged section of the North Anatolian fault within the Marmara Sea was investigated using acoustic techniques and submersible dives. Most gas emissions in the water column were found near the surface expression of known active faults. Gas emissions are unevenly distributed. The linear fault segment crossing the Central High and forming a seismic gap - as it has not ruptured since 1766, based on historical seismicity, exhibits relatively less gas emissions than the adjacent segments. In the eastern Sea of Marmara, active gas emissions are also found above a buried transtensional fault zone, which displayed micro-seismic activity after the 1999 events. Remarkably, this zone of gas emission extends westward all along the southern edge of Cinarcik basin, well beyond the zone where 1999 aftershocks were observed. The long term monitoring of gas seeps could hence be highly valuable for the understanding of the evolution of the fluid-fault coupling processes during the earthquake cycle within the Marmara Sea.

  5. A Cavity Ring-Down Spectroscopy Mercury Continuous Emission Monitor

    SciTech Connect

    Christopher C. Carter

    2004-12-15

    The Sensor Research & Development Corporation (SRD) has undertaken the development of a Continuous Emissions Monitor (CEM) for mercury based on the technique of Cavity Ring-Down Spectroscopy (CRD). The project involved building an instrument for the detection of trace levels of mercury in the flue gas emissions from coal-fired power plants. The project has occurred over two phases. The first phase concentrated on the development of the ringdown cavity and the actual detection of mercury. The second phase dealt with the construction and integration of the sampling system, used to carry the sample from the flue stack to the CRD cavity, into the overall CRD instrument. The project incorporated a Pulsed Alexandrite Laser (PAL) system from Light Age Incorporated as the source to produce the desired narrow band 254 nm ultra-violet (UV) radiation. This laser system was seeded with a diode laser to bring the linewidth of the output beam from about 150 GHz to less than 60 MHz for the fundamental beam. Through a variety of non-linear optics the 761 nm fundamental beam is converted into the 254 nm beam needed for mercury detection. Detection of the mercury transition was verified by the identification of the characteristic natural isotopic structure observed at lower cavity pressures. The five characteristic peaks, due to both natural isotopic abundance and hyperfine splitting, provided a unique identifier for mercury. SRD scientists were able to detect mercury in air down below 10 parts-per-trillion by volume (pptr). This value is dependent on the pressure and temperature within the CRD cavity at the time of detection. Sulfur dioxide (SO{sub 2}) absorbs UV radiation in the same spectral region as mercury, which is a significant problem for most mercury detection equipment. However, SRD has not only been able to determine accurate mercury concentrations in the presence of SO{sub 2}, but the CRD instrument can in fact determine the SO{sub 2} concentration as well. Detection of

  6. Measurement of gas and aerosol agricultural emissions

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Studies of air quality indicate that agricultural emissions may impact particulate mass concentrations through both primary and secondary processes. Agriculture impacts can include primary dust emission, on-facility combustion from vehicles or seasonal field burning, and gaseous emissions from waste...

  7. METHANE EMISSIONS FROM THE NATURAL GAS INDUSTRY: PRODUCTION AND TRANSMISSION EMISSIONS

    EPA Science Inventory

    The paper discusses a co-funded, Gas Research Institute/EPA project to quantify methane emissions to the atmosphere resulting from operations in the natural gas industry. tudy results will measure or calculate all methane emissions, from production at the well and up to, but not ...

  8. Acoustic emission monitoring of reinforced and prestressed concrete structures

    NASA Astrophysics Data System (ADS)

    Fowler, Timothy J.; Yepez, Luis O.; Barnes, Charles A.

    1998-03-01

    Acoustic emission is an important global nondestructive test method widely used to evaluate the structural integrity of metals and fiber reinforced plastic structures. However, in concrete, application of the technology is still at the experimental stage. Microcracking and crack growth are the principal sources of emission in concrete. Bond failure, anchor slippage, and crack rubbing are also sources of emission. Tension zone cracking in reinforced concrete is a significant source of emission and has made application of the technique to concrete structures difficult. The paper describes acoustic emission monitoring of full-scale prestressed concrete girders and a reinforced concrete frame during loading. The tests on the prestressed concrete girders showed three sources of emission: shear-induced cracking in the web, flexural cracking at the region of maximum moment, and strand slippage at the anchorage zone. The reinforced concrete frame was monitored with and without concrete shear panels. The research was directed to early detection of the cracks, signature analysis, source location, moment tensor analysis, and development of criteria for acoustic emission inspection of concrete structures. Cracking of concrete in the tension areas of the reinforced concrete sections was an early source of emission. More severe emission was detected as damage levels in the structure increased.

  9. 75 FR 57275 - Information Collection; Supplier Greenhouse Gas Emissions Inventory Pilot

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-09-20

    ... ADMINISTRATION Information Collection; Supplier Greenhouse Gas Emissions Inventory Pilot AGENCY: Federal... Supplier Greenhouse Gas (GHG) Emissions Inventory pilot. Public comments are particularly invited on... Information Collection 3090- 00XX; Supplier Greenhouse Gas Emissions Inventory Pilot, by any of the...

  10. Acoustic emission monitoring of a fatigue crack

    NASA Astrophysics Data System (ADS)

    Granata, D. M.; Scott, W. R.; Davis, J.; Lee, E. U.; Boodey, J. B.; Kulowitch, P.

    AE monitoring is applied to crack detection in materials containing intermetallic compounds that have very small critical flaw sizes. The tests performed are simpler than structural monitoring since the source location is well defined and extraneous sources are limited. A correlation was found between defect propagation and AE events in the two titanium aluminide alloys studied. Because events that are apparently not crack related can occur, and because the number of events detected is threshold and gain-sensitive, the AE count alone is not an absolute measure of crack length. Parameters denoting the portion of the load cycle where events occur are valuable for identifying AE sources and cracking mechanisms. Pattern recognition algorithms can be developed on the basis of stored waveforms and load level parameters.