Science.gov

Sample records for groundwater quality some examples

  1. Impact of diffuse nitrate pollution sources on groundwater quality--some examples from Czechoslovakia.

    PubMed Central

    Benes, V; Pĕkný, V; Skorepa, J; Vrba, J

    1989-01-01

    In several regions of Czechoslovakia with intensive agricultural production, the correlation between the amount of nitrogen fertilizer applied and the nitrate content in groundwater has been recognized. Nitrate pollution of groundwater is considered to be the most serious source of nonpoint pollution in Czechoslovakia. A program of research into the effects of farming activities on groundwater quality in Czechoslovakia is under way on experimental fields (20 to 30 hectares) and, simultaneously, in regions in which shallow, vulnerable aquifers occur. The importance of the soil organic matter's stability for maintaining the groundwater quality is emphasized. Research based on nitrogen and organic carbon balance has shown that the restoration of a soil-groundwater system is a complicated process that usually requires changes in the extent and intensity of agricultural activities and consistent attention to the effects produced by natural conditions. Regional investigation of the impact of farming on shallow aquifers in the fluvial deposits of the Elbe River in Bohemia has proved the hydrochemical instability and vertical hydrochemical heterogeneity of these aquifers. The WASTEN deterministic model was used for modeling the transport and transformation of various types of inorganic fertilizers. The input data is based on laboratory and field measurements. Special topics are the verification of model calculations and the time and spatial variability of input data with respect to the unsaturated zone. The research results are being used for making regional and national agro-groundwater managerial schemes more precise, as well as for decision-making. PMID:2559844

  2. Impact of diffuse nitrate pollution sources on groundwater quality--some examples from Czechoslovakia

    SciTech Connect

    Benes, V.; Pekny, V.; Skorepa, J.; Vrba, J. )

    1989-11-01

    In several regions of Czechoslovakia with intensive agricultural production, the correlation between the amount of nitrogen fertilizer applied and the nitrate content in groundwater has been recognized. Nitrate pollution of groundwater is considered to be the most serious source of nonpoint pollution in Czechoslovakia. A program of research into the effects of farming activities on groundwater quality in Czechoslovakia is under way on experimental fields (20 to 30 hectares) and, simultaneously, in regions in which shallow, vulnerable aquifers occur. The importance of the soil organic matter's stability for maintaining the groundwater quality is emphasized. Regional investigation of the impact of farming on shallow aquifers in the fluvial deposits of the Elbe River in Bohemia has proved the hydrochemical instability and vertical hydrochemical heterogeneity of these aquifers. The WASTEN deterministic model was used for modeling the transport and transformation of various types of inorganic fertilizers. The input data is based on laboratory and field measurements. Special topics are the verification of model calculations and the time and spatial variability of input data with respect to the unsaturated zone. The research results are being used for making regional and national agro-groundwater managerial schemes more precise, as well as for decision-making.

  3. Motivation of synthesis, with an example on groundwater quality sustainability

    NASA Astrophysics Data System (ADS)

    Fogg, Graham E.; Labolle, Eric M.

    2006-03-01

    Synthesis of ideas and theories from disparate disciplines is necessary for addressing the major problems faced by society. The best motivation for broad, effective synthesis is the "big idea" that is sufficiently important and inspiring to marshal the appropriate collaborative efforts. Groundwater quality sustainability is posed as an example of one such idea that would potentially unify research efforts in both the sciences and social sciences toward a common, pressing objective.

  4. Motivation of synthesis, with an example on groundwater quality sustainability

    NASA Astrophysics Data System (ADS)

    Fogg, G. E.; Labolle, E. M.

    2007-12-01

    Synthesis of ideas and theories from disparate disciplines is necessary for addressing the major problems faced by society. Such integration happens neither via edict nor via lofty declarations of what is needed or what is best. It happens mainly through two mechanisms: limited scope collaborations (e.g., ~2-3 investigators) in which the researchers believe deeply in their need for each other's expertise and much larger scope collaborations driven by the 'big idea.' Perhaps the strongest motivation for broad, effective synthesis is the 'big idea' that is sufficiently important and inspiring to marshal the appropriate collaborative efforts. Examples include the Manhattan Project, the quest for cancer cures, predicting effects of climate change, and groundwater quality sustainability. The latter is posed as an example of a 'big idea' that would potentially unify research efforts in both the sciences and social sciences toward a common, pressing objective.

  5. Impacts of a large Sahelian city on groundwater hydrodynamics and quality: example of Niamey (Niger)

    NASA Astrophysics Data System (ADS)

    Hassane, Aïssata B.; Leduc, Christian; Favreau, Guillaume; Bekins, Barbara A.; Margueron, Thomas

    2016-03-01

    The management of groundwater resources is very important in the semiarid Sahel region, which is experiencing rapid urban development. Impacts of urbanization on groundwater resources were investigated in the unconfined aquifer of the Continental Terminal beneath the city of Niamey, Niger, using water level and chemical data. Hydrodynamic and chemical changes are best described by a combination of factors including the historical development of the city, current land use, water-table depth and topography. Seasonal groundwater recharge occurs with high spatial variability, as indicated by water-level monitoring in all wells, but there was no interannual trend over the 5-year study period. Groundwater salinity shows high spatial variability and a minor rising trend. The highest salinity is in the old city centre, with Na-NO3 dominant, and it increases seasonally with recharge. Salinity is much lower and more variable in the suburbs (Ca-HCO3, Ca-NO3, and Na-NO3 dominant). Nitrate is the main ionic contaminant and is seasonally or permanently above the international guidelines for drinking water quality in 36 % of sampled wells, with a peak value of 112 mg L-1 NO3-N (8 meq L-1). Comparison of urban and rural sites indicates a long-term increase in groundwater recharge and nitrate enrichment in the urban area with serious implications for groundwater management in the region.

  6. Trends in groundwater quality

    NASA Astrophysics Data System (ADS)

    Loftis, Jim C.

    1996-02-01

    The term trend takes on a variety of meanings for groundwater quality in both a temporal and spatial context. Most commonly, trends are thought of as changes over time at either a regional or localized spatial scale. Generally water quality managers are most interested in changes associated with some form of human activity. Carefully defining what is meant by trend is a critical step in trend analysis and may be accomplished by formulating a statistical model which includes a trend component. Although there are a great many regional groundwater studies which provide a snapshot description of water quality conditions over an area at one point in time, there are relatively few which consider changes over time and fewer still which include a statistical analysis of long-term trend. This review covers both regional and localized studies of groundwater quality around the world, including a few snapshots, but focusing primarily on those studies which include an evaluation of temporal changes in groundwater quality. The studies include national assessments, agricultural case studies (the largest group, mostly regional in scope), urban case studies, and point source and hazardous waste case studies.

  7. Systematic reviews. Some examples.

    PubMed Central

    Knipschild, P.

    1994-01-01

    Reviewing the literature is a scientific inquiry that needs a clear design to preclude bias. It is a real enterprise if one aims at completeness of the literature on a certain subject. Going through refereed English language journals is not enough. On line databases are helpful, but mainly as a starting point. This article gives examples of systematic reviews on vitamin C and the common cold, pyridoxine against the premenstrual syndrome, homeopathy, and physiotherapy. Images p720-a PMID:7950526

  8. Systematic reviews. Some examples.

    PubMed

    Knipschild, P

    1994-09-17

    Reviewing the literature is a scientific inquiry that needs a clear design to preclude bias. It is a real enterprise if one aims at completeness of the literature on a certain subject. Going through refereed English language journals is not enough. On line databases are helpful, but mainly as a starting point. This article gives examples of systematic reviews on vitamin C and the common cold, pyridoxine against the premenstrual syndrome, homeopathy, and physiotherapy. PMID:7950526

  9. Trend Analysis for Groundwater Quality at Different Depths for National Groundwater Quality Monitoring Network of Korea

    NASA Astrophysics Data System (ADS)

    An, Hyeonsil; Jeen, Sung-Wook; Hyun, Yunjung; Lee, Soo Jae; Yoon, Heesung; Kim, Rak-Hyeon

    2015-04-01

    appropriate confidence level for the trend analysis to establish a groundwater quality management framework. The results also showed that at some well locations groundwater quality and trends are different with depths, confirming that groundwater quality monitoring and assessment with different depths should be incorporated into a groundwater monitoring system. This study can be used to improve the current groundwater monitoring network and to establish an advanced groundwater quality management framework, particularly in Korea.

  10. Seasonal changes of spatial variation of some groundwater quality variables in a large irrigated coastal Mediterranean region of Turkey.

    PubMed

    Kurunc, Ahmet; Ersahin, Sabit; Sonmez, Namik K; Kaman, Harun; Uz, Ilker; Uz, Buket Y; Aslan, Gulcin E

    2016-06-01

    Soil and groundwater degradations have taken considerable attention, recently. We studied spatial and temporal variations of groundwater table depth and contours, and groundwater pH, electrical conductivity (EC), and nitrate (NO3) content in a large irrigated area in Western Mediterranean region of Turkey. These variables were monitored during 2009 and 2010 in previously constructed 220 monitoring wells. We analyzed the data by geostatistical techniques and GIS. Spatial variation of groundwater table depth (GTD) and groundwater table contours (GTC) remained similar across the four sampling campaigns. The values for groundwater NO3 content, EC, and pH values ranged from 0.01 to 454.1gL(-1), 0.06 to 46.0dSm(-1) and 6.53-9.91, respectively. Greatest geostatistical range (16,964m) occurred for GTC and minimum (960m) for groundwater EC. Groundwater NO3 concentrations varied both spatially and temporally. Temporal changes in spatial pattern of NO3 indicated that land use and farming practices influenced spatial and temporal variation of groundwater NO3. Several hot spots occurred for groundwater NO3 content and EC. These localities should be monitored more frequently and land management practices should be adjusted to avoid soil and groundwater degradation. The results may have important implications for areas with similar soil, land use, and climate conditions across the Mediterranean region. PMID:26950619

  11. Arkansas Groundwater-Quality Network

    USGS Publications Warehouse

    Pugh, Aaron L.; Jackson, Barry T.; Miller, Roger

    2014-01-01

    Arkansas is the fourth largest user of groundwater in the United States, where groundwater accounts for two-thirds of the total water use. Groundwater use in the State increased by 510 percent between 1965 and 2005 (Holland, 2007). The Arkansas Groundwater-Quality Network is a Web map interface (http://ar.water.usgs.gov/wqx) that provides rapid access to the U.S. Geological Survey’s (USGS) National Water Information System (NWIS) and the U.S. Environmental Protection Agency’s (USEPA) STOrage and RETrieval (STORET) databases of ambient water information. The interface enables users to perform simple graphical analysis and download selected water-quality data.

  12. An innovative procedure to assess multi-scale temporal trends in groundwater quality: Example of the nitrate in the Seine-Normandy basin, France

    NASA Astrophysics Data System (ADS)

    Lopez, Benjamin; Baran, Nicole; Bourgine, Bernard

    2015-03-01

    The European Water Framework Directive (WFD) asks Member States to identify trends in contaminant concentrations in groundwater and to take measures to reach a good chemical status by 2015. In this study, carried out in a large hydrological basin (95,300 km2), an innovative procedure is described for the assessment of recent trends in groundwater nitrate concentrations both at sampling point and regional scales. Temporal variograms of piezometric and nitrate concentration time series are automatically calculated and fitted in order to classify groundwater according to their temporal pattern. These results are then coupled with aquifer lithology to map spatial units within which the modes of diffuse transport of contaminants towards groundwater are assumed to be the same at all points. These spatial units are suitable for evaluating regional trends. The stability over time of the time series is tested based on the cumulative sum principle, to determine the time period during which the trend should be sought. The Mann-Kendall and Regional-Kendall nonparametric tests for monotonic trends, coupled with the Sen-slope test, are applied to the periods following the point breaks thus determined at both the sampling point or regional scales. This novel procedure is robust and enables rapid processing of large databases of raw data. It would therefore be useful for managing groundwater quality in compliance with the aims of the WFD.

  13. Groundwater quality in the San Francisco Bay groundwater basins, California

    USGS Publications Warehouse

    Parsons, Mary C.; Kulongoski, Justin T.; Belitz, Kenneth

    2013-01-01

    Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. Selected groundwater basins of the San Francisco Bay area constitute one of the study units being evaluated.

  14. A groundwater quality index map for Namibia

    NASA Astrophysics Data System (ADS)

    Bergmann, Thomas; Schulz, Oliver; Wanke, Heike; Püttmann, Wilhelm

    2016-04-01

    Groundwater quality and contamination is a huge concern for the population of Namibia, especially for those living in remote areas. There, most farmers use their own wells to supply themselves and their animals with drinking water. In many cases, except for a few studies that were done in some areas, the only groundwater quality measurements that took place were taken at the time the well was drilled. These data were collected and are available through the national GROWAS-Database. Information on measurements determining the amount of contaminants such as fluoride, TDS, other major ions and nitrate for several thousand wells are provided there. The aim of this study was I) to check the database for its reliability by comparing it to results from different studies and statistical analysis, II) to analyze the database on groundwater quality using different methods (statistical-, pattern- and correlation analysis) and III) to embed our own field work that took place within a selected Namibian region into that analysis. In order to get a better understanding of the groundwater problems in different areas of Namibia, a groundwater quality index map based on GROWAS was created using GIS processing techniques. This map uses several indicators for groundwater quality in relation to selected guidelines and combines them into an index, thus enabling the assessment of groundwater quality with regard to more than one pollutant. The goal of the groundwater quality map is to help identify where the overall groundwater quality is problematic and to communicate these problems. Additionally, suggestions for an enhancement of the database and for new field surveys will be given. The field work was focusing on three farms within an area known for its problematic nitrate concentration in groundwater. There, 23 wells were probed. In order to identify the sources of the contamination, isotopic measurements were executed for three of these wells with high nitrate concentrations

  15. Integrated groundwater quality management in urban areas

    NASA Astrophysics Data System (ADS)

    Swartjes, F. A.; Otte, P. F.

    2012-04-01

    Traditionally, groundwater assessments and remediations are approached at the scale of individual groundwater plumes. In urban areas, however, this management of individual groundwater plumes is often problematic for technical, practical or financial reasons, since the groundwater quality is often affected by a combination of sources, including (former) industrial activities, spills and leachate from uncontrolled landfills and building materials. As a result, often a whole series of intermingling contamination plumes is found in large volumes of groundwater. In several countries in the world, this led to stagnation of groundwater remediation in urban areas. Therefore, in the Netherlands there is a tendency managing groundwater in urban areas from an integrated perspective and on a larger scale. This so-called integrated groundwater quality management is often more efficient and hence, cheaper, since the organisation of the management of a cluster of groundwater plumes is much easier than it would be if all individual groundwater plumes were managed at different points in time. Integrated groundwater quality management should follow a tailor-made approach. However, to facilitate practical guidance was developed. This guidance relates to the delineation of the domain, the management of sources for groundwater contamination, procedures for monitoring, and (risk-based) assessment of the groundwater quality. Function-specific risk-based groundwater quality criteria were derived to support the assessment of the groundwater quality.

  16. Groundwater Quality in Mura Valley (Slovenia)

    NASA Astrophysics Data System (ADS)

    Zajc Benda, T.; Souvent, P.; Bračič Železnik, B.; Čenčur Curk, B.

    2012-04-01

    Groundwater quality is one of the most important parameters in drinking water supply management. For safe drinking water supply, the quality of groundwater in the water wells on the recharge area has to be controlled. Groundwater quality data will be presented for one test area in the SEE project CC-WaterS (Climate Change and Impacts on Water Supply) Mura valley, which lies in the northeastern part of Slovenia. The Mura valley is a part of the Pannonian basin tectonic unit, which is filled with Tertiary and Quaternary gravel and sand sediments. The porous aquifer is 17 m thick in average and recharges from precipitation (70 %) and from surface waters (30 %). The aquifer is the main source of drinking water in the area for almost 53.000 inhabitants. Most of the aquifer lies beneath the agricultural area what represents the risk of groundwater quality. The major groundwater pollutants in the Mura valley are nitrates, atrazine, desethyl-atrazine, trichloroethane and tetrachloroethene. National groundwater quality monitoring is carried out twice a year, so some polluting events could be missed. The nitrate concentrations in the past were up to 140 mg/l. Concentration trends are decreasing and are now below 60 mg/l. Concentrations of atrazine and desethyl-atrazine, are decreasing as well and are below 0,1 µg/l. Trichloroethene and tetrachloroethene were detected downstream of main city in Mura valley, in the maximum concentrations of 280 μg/l in June 2005 (trichloroethene) and 880 μg/l in October 1997 (tetrachloroethene). So, it can be summarized that the trends for most pollutants in the Mura valley are decreasing, what is a good prediction for the future. Input estimation of the total nitrogen (N) (mineral and organic fertilizers) in the Mura valley shows, that the risk of leaching is enlarged in the areas, where the N input is larger than 250 kg/ha, this is at 6,3 % of all agricultural areas. Prediction for the period 2021-2050 indicates that the leaching of N

  17. Examples of transient sounding from groundwater exploration in sedimentary aquifers

    USGS Publications Warehouse

    Fitterman, D.V.

    1987-01-01

    Examples of the use of transient electromagnetic soundings for three groundwater exploration problems in sedimentary aquifers are given. The examples include: 1) estimating depths to water table and bedrock in an alluvium-filled basin, 2) mapping a confined freshwater aquifer in bedrock sediments, and 3) locating a freshwater/saltwater interface in a glacial-outwash aquifer. -from Author

  18. Chemical substance transport in soils and its effect on groundwater quality.

    PubMed Central

    Khublarian, M G

    1989-01-01

    The problems of chemical substance applications in different spheres of industry and agriculture and their effects on groundwater quality and human health are described. Sources of groundwater contamination from industrial and municipal wastes, agricultural pollutants, etc., are listed. The experience in the application of chemical fertilizers and pesticides in the USSR is described. A brief estimation of groundwater salinity is given for various regions of the USSR where irrigation is practiced, as well as the experience in environmental protection. Special attention is given to methods of simulating water seepage and chemical substance transport in soils. Boundary problems for free-surface seepage and dissolved solids transport in porous media are stated, and methods of solution are described in the example of the hydrodynamic theory of seepage and dispersion. Some results of calculations with this method are presented. The influence of groundwater quality on the morbidity of the population is given and the main diseases and associated medical problems are listed. PMID:2559843

  19. From Airborne EM to Geology, some examples

    NASA Astrophysics Data System (ADS)

    Gunnink, Jan

    2014-05-01

    Introduction Airborne Electro Magnetics (AEM) provide a model of the 3-dimensional distribution of resistivity of the subsurface. These resistivity models were used for delineating geological structures (e.g. Buried Valleys and salt domes) and for geohydrological modeling of aquifers (sandy sediments) and aquitards (clayey sediments). Most of the interpretation of the AEM has been carried out manually, by interpretation of 2 and 3-dimensional resistivity models into geological units by a skilled geologists / geophysicist. The manual interpretation is tiresome, takes a long time and is prone to subjective choices of the interpreter. Therefore, semi-automatic interpretation of AEM resistivity models into geological units is a recent research topic. Two examples are presented that show how resistivity, as obtained from AEM, can be "converted" to useful geological / geohydrolocal models. Statistical relation between borehole data and resistivity In the northeastern part of the Netherlands, the 3D distribution of clay deposits - formed in a glacio-lacustrine environment with buried glacial valleys - was modelled. Boreholes with description of lithology, were linked to AEM resistivity. First, 1D AEM resistivity models from each individual sounding were interpolated to cover the entire study area, resulting in a 3-dimensional model of resistivity. For each interval of clay and sand in the boreholes, the corresponding resistivity was extracted from the 3D resistivity model. Linear regression was used to link the clay and non-clay proportion in each borehole interval to the Ln(resistivity). This regression is then used to "convert" the 3D resistivity model into proportion of clay for the entire study area. This so-called "soft information" is combined with the "hard data" (boreholes) to model the proportion of clay for the entire study area using geostatistical simulation techniques (Sequential Indicator Simulation with collocated co-kriging). 100 realizations of the 3

  20. GROUNDWATER QUALITY PROTECTION: THE ISSUE IN PERSPECTIVE

    EPA Science Inventory

    The importance of protecting groundwater resources cannot be overstated, and many people throughout the world seem anxious to physically and financially support a rational program to this end. Public complacency regarding the quality of groundwater was destroyed with headline-gra...

  1. Groundwater monitoring: Guidelines and methodology for developing and implementing a ground-water quality monitoring program

    SciTech Connect

    Everett, L.G.

    1984-01-01

    The handbook attempts to structure a cost-effective, generic groundwater pollution monitoring methodology that can be applied either on a regional basis or to site-specific, alternative approaches to monitoring the quality of groundwater at a considerable saving of time and money. Extensive detail is given to the relation of groundwater quality to the geohydrologic framework, constituents in the polluted groundwater, sources and causes of pollution, and use of water. Information is also given about groundwater monitoring techniques used in top soil, the vadose zone, ad the saturated zone. The costs of these techniques are described in figures and tables. Groundwater databases and their applicability to water resources information systems are also covered. Comprehensive site-specific examples are given of how to use the material in the handbook to monitoring major sources of groundwater pollution. Included are in-depth models of hazardous waste disposal, brine disposal, landfill leachate control, oxidation ponds and percolation ponds, septic fields, and agricultural return flow, as well as descriptions of cases of multiple-source municipal and agricultural pollution.

  2. Ground-water quality in selected areas of Wisconsin

    USGS Publications Warehouse

    Hindall, S.M.

    1979-01-01

    Analysis of 2,071 ground-water samples from 970 wells throughout Wisconsin indicate large variations in ground-water quality. Ground water in Wisconsin is generally suitable for most uses, but in some areas concentrations of chemical constituents exceed recommended drinking-water standards. Iron, manganese, and nitrate commonly exceed recommended drinking-water standards and dissolved solids, sulfate, heavy metals, and phenolic materials may present local problems. (USGS)

  3. Groundwater.

    ERIC Educational Resources Information Center

    Braids, Olin C.; Gillies, Nola P.

    1978-01-01

    Presents a literature review of groundwater quality covering publications of 1977. This review includes: (1) sources of groundwater contamination; and (2) management of groundwater. A list of 59 references is also presented. (HM)

  4. Model reference adaptive systems some examples.

    NASA Technical Reports Server (NTRS)

    Landau, I. D.; Sinner, E.; Courtiol, B.

    1972-01-01

    A direct design method is derived for several single-input single-output model reference adaptive systems (M.R.A.S.). The approach used helps to clarify the various steps involved in a design, which utilizes the hyperstability concept. An example of a multiinput, multioutput M.R.A.S. is also discussed. Attention is given to the problem of a series compensator. It is pointed out that a series compensator which contains derivative terms must generally be introduced in the adaptation mechanism in order to assure asymptotic hyperstability. Results obtained by the simulation of a M.R.A.S. on an analog computer are also presented.

  5. Groundwater quality in the San Fernando--San Gabriel groundwater basins, California

    USGS Publications Warehouse

    Kulongoski, Justin T.; Belitz, Kenneth

    2012-01-01

    Groundwater provides more than 40 percent of California's drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State's groundwater quality and increases public access to groundwater-quality information. The San Fernando and San Gabriel groundwater basins constitute one of the study units being evaluated.

  6. Importance of mineralogical data for groundwater quality affectedby CO2 leakage

    SciTech Connect

    Xu, Tianfu

    2006-02-13

    Recently, geological storage of CO{sub 2} has been extensively investigated. The impact of leakage from CO{sub 2} storage reservoirs on groundwater quality is one of the concerns. Dissolution of CO{sub 2} in groundwater results in a decrease in pH. Such acidic condition can affect the dissolution and sorption mechanisms of many minerals (Jaffe and Wang, 2004). Some heavy-metal-bearing minerals dissolve under acidic conditions. For example, galena (PbS) can dissolve and increase significantly Pb concentrations and diminish groundwater quality. If calcite is present in the rock, it can buffer the pH and decrease galena dissolution. Therefore, mineralogical composition and distribution in caprock, overlying aquifers, and along the leakage paths are important data that should be obtained from site characterization. Insight into which minerals and compounds are most important for groundwater quality can be obtained from reactive geochemical transport simulations. Here we present results of simulations using the code TOUGHREACT, whose physical and chemical process capabilities have been discussed by Xu et al. (2006). The simulator can be applied to one-, two-, or three-dimensional porous and fractured media with physical and chemical heterogeneity, and can accommodate any number of chemical species present in liquid, gas and solid phases.

  7. Using Cl/Br ratios and other indicators to assess potential impacts on groundwater quality from septic systems: A review and examples from principal aquifers in the United States

    USGS Publications Warehouse

    Katz, B.G.; Eberts, S.M.; Kauffman, L.J.

    2011-01-01

    A detailed review was made of chemical indicators used to identify impacts from septic tanks on groundwater quality. Potential impacts from septic tank leachate on groundwater quality were assessed using the mass ratio of chloride-bromide (Cl/Br), concentrations of selected chemical constituents, and ancillary information (land use, census data, well depth, soil characteristics) for wells in principal aquifers of the United States. Chemical data were evaluated from 1848 domestic wells in 19 aquifers, 121 public-supply wells in 6 aquifers, and associated monitoring wells in four aquifers and their overlying hydrogeologic units. Based on previously reported Cl/Br ratios, statistical comparisons between targeted wells (where Cl/Br ratios range from 400 to 1100 and Cl concentrations range from 20 to 100 mg/L) and non-targeted wells indicated that shallow targeted monitoring and domestic wells (0.5. mg/L) shallow groundwater from target domestic wells, relative to non-target wells (1.5. mg/L), corresponded to significantly higher potassium, boron, chloride, dissolved organic carbon, and sulfate concentrations, which may also indicate the influence of septic-tank effluent. Impacts on groundwater quality from septic systems were most evident for the Eastern Glacial Deposits aquifer and the Northern High Plains aquifer that were associated with the number of housing units using septic tanks, high permeability of overlying sediments, mostly oxic conditions, and shallow wells. Overall, little or no influence from septic systems were found for water samples from the deeper public-supply wells.The Cl/Br ratio is a useful first-level screening tool for assessing possible septic tank influence in water from shallow wells (<20 m) with the range of 400-1100. The use of this ratio would be enhanced with information on other chloride sources, temporal variability of chloride and bromide concentrations in shallow groundwater, knowledge of septic-system age and maintenance, and the

  8. Using Cl/Br ratios and other indicators to assess potential impacts on groundwater quality from septic systems: A review and examples from principal aquifers in the United States

    NASA Astrophysics Data System (ADS)

    Katz, Brian G.; Eberts, Sandra M.; Kauffman, Leon J.

    2011-02-01

    SummaryA detailed review was made of chemical indicators used to identify impacts from septic tanks on groundwater quality. Potential impacts from septic tank leachate on groundwater quality were assessed using the mass ratio of chloride-bromide (Cl/Br), concentrations of selected chemical constituents, and ancillary information (land use, census data, well depth, soil characteristics) for wells in principal aquifers of the United States. Chemical data were evaluated from 1848 domestic wells in 19 aquifers, 121 public-supply wells in 6 aquifers, and associated monitoring wells in four aquifers and their overlying hydrogeologic units. Based on previously reported Cl/Br ratios, statistical comparisons between targeted wells (where Cl/Br ratios range from 400 to 1100 and Cl concentrations range from 20 to 100 mg/L) and non-targeted wells indicated that shallow targeted monitoring and domestic wells (<20 m depth below land surface) had a significantly ( p < 0.05) higher median percentage of houses with septic tanks (1990 census data) than non-targeted wells. Higher ( p = 0.08) median nitrate-N concentration (3.1 mg/L) in oxic (dissolved oxygen concentrations >0.5 mg/L) shallow groundwater from target domestic wells, relative to non-target wells (1.5 mg/L), corresponded to significantly higher potassium, boron, chloride, dissolved organic carbon, and sulfate concentrations, which may also indicate the influence of septic-tank effluent. Impacts on groundwater quality from septic systems were most evident for the Eastern Glacial Deposits aquifer and the Northern High Plains aquifer that were associated with the number of housing units using septic tanks, high permeability of overlying sediments, mostly oxic conditions, and shallow wells. Overall, little or no influence from septic systems were found for water samples from the deeper public-supply wells. The Cl/Br ratio is a useful first-level screening tool for assessing possible septic tank influence in water from

  9. RESEARCH FOR GROUNDWATER QUALITY MANAGEMENT

    EPA Science Inventory

    Ground water is an excellent resource due to its quality and availability. In the United States it is available at almost any location in quantities large enough to provide for domestic needs and over one-third of the Country is underlain by aquifers capable of yielding 100,000 g...

  10. Groundwater Quality and Quantity in a Coastal Aquifer Under High Human Pressure: Understand the Aquifer Functioning and the Social Perception of Water Use for a Better Water Management. Example of Recife (PE, Brazil)

    NASA Astrophysics Data System (ADS)

    Petelet-Giraud, E.; Cary, L.; Bertrand, G.; Alves, L. M.; Cary, P.; Giglio-Jacquemot, A.; Aquilina, L.; Hirata, R.; Montenegro, S.; Aurouet, A.; Franzen, M.; Chatton, E.

    2015-12-01

    The Recife Metropolitan Region is a typical "hot spot" illustrating the problems of southern countries on water issues inducing high pressures on water resources both on quantity and quality in the context of global social and environmental changes. This study is based on an interdisciplinary approach, coupling "hard" geosciences together with "soft" social sciences with the aim to study the human impact on coastal aquifers in a context of overexploitation to improve the existing water management tools. By revisiting the geological and hydrogeological conceptual models, field campaigns of groundwater and surface water sampling and analysis, and of interviews of different actors on the theme of water supply and management in Recife Metropolitan Region, the main results can be summarized as follows: (1) The recharge of the deep strategic confined aquifers is very limited resulting in water level decrease (up to -90m in 25y) due to overexploitation. (2) Groundwater residence time in these deep aquifers is over 10,000 years. (3) The natural upward flux of these confined aquifers is observed inland, but is reversed in the heavily populated areas along the coast leading to mixing with modern groundwater coming from the shallow aquifers. (4) Groundwater salinization is inherited from the Pleistocene marine transgression, only partly diluted by the recharge through the mangroves during the subsequent regression phase. Today, leakage from surficial aquifers induces local salinization. (5) Local climatic scenarios predict a reduction of rainfall volume of 20% together with an increase of sea level (18-59cm by 2100). (5) The Public authorities tend to deny the difficulties that people, especially those in precarious situation, are confronted with regarding water, especially in times of drought. The COQUEIRAL research project is financially supported by ANR (ANR-11-CEPL-012); FACEPE (APQ-0077-3.07/11); FAPESP (2011/50553-0

  11. Assessment of Groundwater Quality by Chemometrics.

    PubMed

    Papaioannou, Agelos; Rigas, George; Kella, Sotiria; Lokkas, Filotheos; Dinouli, Dimitra; Papakonstantinou, Argiris; Spiliotis, Xenofon; Plageras, Panagiotis

    2016-07-01

    Chemometric methods were used to analyze large data sets of groundwater quality from 18 wells supplying the central drinking water system of Larissa city (Greece) during the period 2001 to 2007 (8.064 observations) to determine temporal and spatial variations in groundwater quality and to identify pollution sources. Cluster analysis grouped each year into three temporal periods (January-April (first), May-August (second) and September-December (third). Furthermore, spatial cluster analysis was conducted for each period and for all samples, and grouped the 28 monitoring Units HJI (HJI=represent the observations of the monitoring site H, the J-year and the period I) into three groups (A, B and C). Discriminant Analysis used only 16 from the 24 parameters to correctly assign 97.3% of the cases. In addition, Factor Analysis identified 7, 9 and 8 latent factors for groups A, B and C, respectively. PMID:27329059

  12. Groundwater-quality characteristics for the Wyoming Groundwater-Quality Monitoring Network, November 2009 through September 2012

    USGS Publications Warehouse

    Boughton, Gregory K.

    2014-01-01

    Groundwater samples were collected from 146 shallow (less than or equal to 500 feet deep) wells for the Wyoming Groundwater-Quality Monitoring Network, from November 2009 through September 2012. Groundwater samples were analyzed for physical characteristics, major ions and dissolved solids, trace elements, nutrients and dissolved organic carbon, uranium, stable isotopes of hydrogen and oxygen, volatile organic compounds, and coliform bacteria. Selected samples also were analyzed for gross alpha radioactivity, gross beta radioactivity, radon, tritium, gasoline range organics, diesel range organics, dissolved hydrocarbon gases (methane, ethene, and ethane), and wastewater compounds. Water-quality measurements and concentrations in some samples exceeded numerous U.S. Environmental Protection Agency (EPA) drinking water standards. Physical characteristics and constituents that exceeded EPA Maximum Contaminant Levels (MCLs) in some samples were arsenic, selenium, nitrite, nitrate, gross alpha activity, and uranium. Total coliforms and Escherichia coli in some samples exceeded EPA Maximum Contaminant Level Goals. Measurements of pH and turbidity and concentrations of chloride, sulfate, fluoride, dissolved solids, aluminum, iron, and manganese exceeded EPA Secondary Maximum Contaminant Levels in some samples. Radon concentrations in some samples exceeded the alternative MCL proposed by the EPA. Molybdenum and boron concentrations in some samples exceeded EPA Health Advisory Levels. Water-quality measurements and concentrations also exceeded numerous Wyoming Department of Environmental Quality (WDEQ) groundwater standards. Physical characteristics and constituents that exceeded WDEQ Class I domestic groundwater standards in some samples were measurements of pH and concentrations of chloride, sulfate, dissolved solids, iron, manganese, boron, selenium, nitrite, and nitrate. Measurements of pH and concentrations of chloride, sulfate, dissolved solids, aluminum, iron

  13. Groundwater Quality in Central New York, 2007

    USGS Publications Warehouse

    Eckhardt, David A.V.; Reddy, J.E.; Shaw, Stephen B.

    2009-01-01

    Water samples were collected from 7 production wells and 28 private residential wells in central New York from August through December 2007 and analyzed to characterize the chemical quality of groundwater. Seventeen wells are screened in sand and gravel aquifers, and 18 are finished in bedrock aquifers. The wells were selected to represent areas of greatest groundwater use and to provide a geographical sampling from the 5,799-square-mile study area. Samples were analyzed for 6 physical properties and 216 constituents, including nutrients, major inorganic ions, trace elements, radionuclides, pesticides, volatile organic compounds, phenolic compounds, organic carbon, and 4 types of bacteria. Results indicate that groundwater used for drinking supply is generally of acceptable quality, although concentrations of some constituents or bacteria exceeded at least one drinking-water standard at several wells. The cations detected in the highest concentrations were calcium, magnesium, and sodium; anions detected in the highest concentrations were bicarbonate, chloride, and sulfate. The predominant nutrients were nitrate and ammonia, but no nutrients exceeded Maximum Contaminant Levels (MCLs). The trace elements barium, boron, lithium, and strontium were detected in every sample; the trace elements present in the highest concentrations were barium, boron, iron, lithium, manganese, and strontium. Fifteen pesticides, including seven pesticide degradates, were detected in water from 17 of the 35 wells, but none of the concentrations exceeded State or Federal MCLs. Sixteen volatile organic compounds were detected in water from 15 of the 35 wells. Nine analytes and three types of bacteria were detected in concentrations that exceeded Federal and State drinking-water standards, which typically are identical. One sample had a water color that exceeded the U.S. Environmental Protection Agency (USEPA) Secondary Maximum Contaminant Level (SMCL) and the New York State MCL of 10 color

  14. Groundwater quality in the Antelope Valley, California

    USGS Publications Warehouse

    Dawson, Barbara J. Milby; Belitz, Kenneth

    2012-01-01

    Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. Antelope Valley is one of the study areas being evaluated. The Antelope study area is approximately 1,600 square miles (4,144 square kilometers) and includes the Antelope Valley groundwater basin (California Department of Water Resources, 2003). Antelope Valley has an arid climate and is part of the Mojave Desert. Average annual rainfall is about 6 inches (15 centimeters). The study area has internal drainage, with runoff from the surrounding mountains draining towards dry lakebeds in the lower parts of the valley. Land use in the study area is approximately 68 percent (%) natural (mostly shrubland and grassland), 24% agricultural, and 8% urban. The primary crops are pasture and hay. The largest urban areas are the cities of Palmdale and Lancaster (2010 populations of 152,000 and 156,000, respectively). Groundwater in this basin is used for public and domestic water supply and for irrigation. The main water-bearing units are gravel, sand, silt, and clay derived from surrounding mountains. The primary aquifers in Antelope Valley are defined as those parts of the aquifers corresponding to the perforated intervals of wells listed in the California Department of Public Health database. Public-supply wells in Antelope Valley are completed to depths between 360 and 700 feet (110 to 213 meters), consist of solid casing from the land surface to a depth of 180 to 350 feet (55 to 107 meters), and are screened or perforated below the solid casing. Recharge to the groundwater system is primarily runoff from the surrounding mountains, and by direct infiltration of irrigation and sewer and septic

  15. Uncertainty and Decision Making: Examples of Some Possible New Frontiers

    NASA Astrophysics Data System (ADS)

    Silliman, S. E.; Rodak, C. M.; Bolster, D.; Saavedra, K.; Evans, W.

    2011-12-01

    The concept of decision making under uncertainty for groundwater systems represents an exciting area of research and application. In this presentation, three examples are briefly introduced which represent possible new applications of risk and decision making under uncertainty. In the most classic of the three examples, a probabilistic strategy is considered within the context of management / assessment of proposed changes in land-use in the vicinity of a public water-supply well. Focused on health-risk related to contamination at the well, the analysis includes uncertainties in source location / strength, groundwater flow / transport, human exposure, and human health risk. The second example involves application of Probabilistic Risk Assessment (PRA) to the evaluation of development projects in rural regions of developing countries. PRA combined with Fault Tree Analysis provides a structure for analysis of the impact of data uncertainties on the estimation of health risk resulting from failure of multiple components of new water-resource systems. The third is an extension of the concept of "risk compensation" to the analysis of potential long-term risk associated with new water resource projects. Of direct interest here is the appearance of new risk to the public, such as introduction of new disease pathways or new sources of contamination of the source waters. As a result of limitations on conceptual model and/or limitations on data, this type of risk is often difficult to identify / assess, and is therefore not commonly included in formal decision-making efforts: it may however seriously impact the long-term net benefit of a water resource project. The goal of presenting these three examples is to illustrate the breadth of possible application of uncertainty / risk analyses beyond the more classic applications to groundwater remediation and protection.

  16. Groundwater quality in the North San Francisco Bay groundwater basins, California

    USGS Publications Warehouse

    Kulongoski, Justin T.; Belitz, Kenneth

    2010-01-01

    Groundwater provides more than 40 percent of California's drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State's groundwater quality and increases public access to groundwater-quality information. The basins north of San Francisco constitute one of the study units being evaluated.

  17. Groundwater quality in the South Coast Interior Basins, California

    USGS Publications Warehouse

    Parsons, Mary C.; Belitz, Kenneth

    2014-01-01

    Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s untreated groundwater quality and increases public access to groundwater-quality information. The South Coast Interior Basins constitute one of the study units being evaluated.

  18. Effects of intensive urbanization on the intrusion of shallow groundwater into deep groundwater: examples from Bangkok and Jakarta.

    PubMed

    Onodera, Shin-ichi; Saito, Mitsuyo; Sawano, Misa; Hosono, Takahiro; Taniguchi, Makoto; Shimada, Jun; Umezawa, Yu; Lubis, Rachmat Fajar; Buapeng, Somkid; Delinom, Robert

    2008-10-15

    Asian megacities have severe pollution problems in both coastal and urban areas. In addition, the groundwater potential has decreased and land subsidence has occurred because of intensive groundwater pumping in urban areas. To prevent the adverse effects of urbanization on groundwater quality, it is necessary to confirm the changes in groundwater flow and contaminant transport caused by urbanization. We examined the effects of urbanization on contaminant transport in groundwater. The research areas were located around Bangkok, Thailand, and Jakarta, Indonesia, cities with populations of approximately 8 and 12 million, respectively. Each metropolitan city is located on a river delta and is adjacent to a bay. We measured the water level and collected water samples at boreholes at multiple depths (100 to 200 m) in 2004 and 2006 in Bangkok and Jakarta, respectively. The current hydraulic potential is below sea level in both cities because of prior excess abstraction of groundwater. As a result, the direction of groundwater flow is now downward in the coastal area. The Cl(-) concentration and delta(18)O distributions in groundwater suggest that the decline in hydraulic potential has caused the intrusion of seawater and shallow groundwater into deep groundwater. Concentrations of Mn and NO3(-)-N in groundwater suggest the intrusion of these contaminants from shallow to deep aquifers with downward groundwater flow and implies an accumulation of contaminants in deep aquifers. Therefore, it is important to recognize the possibility of future contaminant transport with the discharge of deep groundwater into the sea after the recovery of groundwater potential in the coastal areas. PMID:18804843

  19. Erratum to "Effects of intensive urbanization on the intrusion of shallow groundwater into deep groundwater: examples from Bangkok and Jakarta".

    PubMed

    Onodera, Shin-ichi; Saito, Mitsuyo; Sawano, Misa; Hosono, Takahiro; Taniguchi, Makoto; Shimada, Jun; Umezawa, Yu; Lubis, Rachmat Fajar; Buapeng, Somkid; Delinom, Robert

    2009-04-15

    Asian megacities have severe pollution problems in both coastal and urban areas. In addition, the groundwater potential has decreased and land subsidence has occurred because of intensive groundwater pumping in urban areas. To prevent the adverse effects of urbanization on groundwater quality, it is necessary to confirm the changes in groundwater flow and contaminant transport caused by urbanization. We examined the effects of urbanization on contaminant transport in groundwater. The research areas were located around Bangkok, Thailand, and Jakarta, Indonesia, cities with populations of approximately 8 and 12 million, respectively. Each metropolitan city is located on a river delta and is adjacent to a bay. We measured the water level and collected water samples at boreholes at multiple depths (100 to 200 m) in 2004 and 2006 in Bangkok and Jakarta, respectively. The current hydraulic potential is below sea level in both cities because of prior excess abstraction of groundwater. As a result, the direction of groundwater flow is now downward in the coastal area. The Cl- concentration and delta18O distributions in groundwater suggest that the decline in hydraulic potential has caused the intrusion of seawater and shallow groundwater into deep groundwater. Concentrations of Mn and NO3--N in groundwater suggest the intrusion of these contaminants from shallow to deep aquifers with downward groundwater flow and implies an accumulation of contaminants in deep aquifers. Therefore, it is important to recognize the possibility of future contaminant transport with the discharge of deep groundwater into the sea after the recovery of groundwater potential in the coastal areas. PMID:19437605

  20. Groundwater-Quality Assessment, Pike County, Pennsylvania, 2007

    USGS Publications Warehouse

    Senior, Lisa A.

    2009-01-01

    Pike County, a 545 square-mile area in northeastern Pennsylvania, has experienced the largest relative population growth of any county in the state from 1990 to 2000 and its population is projected to grow substantially through 2025. This growing population may result in added dependence and stresses on water resources, including the potential to reduce the quantity and degrade the quality of groundwater and associated stream base flow with changing land use. Groundwater is the main source of drinking water in the county and is derived primarily from fractured-rock aquifers (shales, siltstones, and sandstones) and some unconsolidated glacial deposits that are recharged locally from precipitation. The principal land uses in the county as of 2005 were public, residential, agricultural, hunt club/private recreational, roads, and commercial. The public lands cover a third of the county and include national park, state park, and other state lands, much of which are forested. Individual on-site wells and wastewater disposal are common in many residential areas. In 2007, the U.S. Geological Survey, in cooperation with the Pike County Conservation District, began a study to provide current information on groundwater quality throughout the county that will be helpful for water-resource planning. The countywide reconnaissance assessment of groundwater quality documents current conditions with existing land uses and may serve as a baseline of groundwater quality for future comparison. Twenty wells were sampled in 2007 throughout Pike County to represent groundwater quality in the principal land uses (commercial, high-density and moderate-density residential with on-site wastewater disposal, residential in a sewered area, pre-development, and undeveloped) and geologic units (five fractured-rock aquifers and one glacial unconsolidated aquifer). Analyses selected for the groundwater samples were intended to identify naturally occurring constituents from the aquifer or

  1. Effects Of Leaky Sewers On Groundwater Quality

    NASA Astrophysics Data System (ADS)

    Leschik, S.; Musolff, A.; Reinstorf, F.; Strauch, G.; Oswald, S. E.; Schirmer, M.

    2007-12-01

    The impact of urban areas on groundwater quality has become an emerging research field in hydrogeology. Urban subsurface infrastructures like sewer networks are often leaky, so untreated wastewater may enter the urban aquifer. The transport of wastewater into the groundwater is still not well understood under field conditions. In the research platform WASSER Leipzig (Water And Sewershed Study of Environmental Risk in Leipzig- Germany) the effects of leaky sewers on the groundwater quality are investigated. The research is focused on the occurrence and transport of so-called "xenobiotics" such as pharmaceuticals and personal care product additives. Xenobiotics may pose a threat on human health, but can also be considered a marker for an urban impact on water resources. A new test site was established in Leipzig to quantify mass fluxes of xenobiotics into the groundwater from a leaky sewer. Corresponding to the leaks which were detected by closed circuit television inspections, monitoring wells were installed up- and downstream of the sewer. Concentrations of eight xenobiotics (technical-nonylphenol, bisphenol-a, caffeine, galaxolide, tonalide, carbamazepine, phenazone, ethinylestradiol) obtained from first sampling programmes were found to be highly heterogeneous, but a relation between the position of the sampling points and the sewer could not be clearly identified. However, concentrations of sodium, chloride, potassium and nitrate increased significantly downstream of the sewer which may be due to wastewater exfiltration, since no other source is known on the water flowpath from the upstream to the downstream wells. Because of the highly heterogeneous spatial distribution of xenobiotics at the test site, a monitoring concept was developed comprising both high-resolution sampling and an integral approach to obtain representative average concentrations. Direct-push techniques were used to gain insight into the fine-scale spatial distribution of the target compounds

  2. Groundwater quality in West Virginia, 1993-2008

    USGS Publications Warehouse

    Chambers, Douglas B.; Kozar, Mark D.; White, Jeremy S.; Paybins, Katherine S.

    2012-01-01

    ), non-enforceable proposed MCL, or non-enforceable advisory health-based screening level (HBSL), were used as benchmarks against which to compare analytical results. Constituent concentrations were less than the MCLs in most samples. However, some samples exceeded non-enforceable SMCLs, proposed MCLs, or advisory HBSLs. Radon-222 concentrations exceeded the proposed MCL of 300 pCi/L in 45 percent of samples, and iron concentrations exceeded the SMCL of 300 µg/L in 57 percent of samples. Manganese concentrations were greater than the SMCL (50 µg/L) in 62 percent of samples and greater than the HBSL (300 µg/L) in 25 percent of the samples. Other sampled constituents, including organic compounds and trace elements, exceeded drinking-water criteria at much lower frequencies. The radon-222 median concentrations in samples from Cambrian, Ordovician, Silurian, Permian, and Quaternary aquifers exceeded the proposed 300 pCi/L MCL. Although median radon concentrations for wells in Devonian, Mississippian, and Pennsylvanian aquifers were less than the proposed MCL, radon concentrations greater than the proposed MCL were measured in samples from aquifers of all geologic ages. The median iron concentrations for samples from Devonian and Pennsylvanian aquifers were greater than the 300 µg/L SMCL. Iron concentrations exceeded the SMCL in aquifers of all geologic ages, except Cambrian. Median concentrations of manganese exceeded the SMCL in samples from Devonian, Pennsylvanian, and Quaternary aquifers. As with iron, manganese concentrations were found to exceed the SMCL in at least one sample from aquifers of all geologic ages, except Cambrian. Pesticides were detected most frequently and in higher concentrations in limestone-dominated areas. Most of West Virginia’s agriculture is concentrated in those areas. This study, the most comprehensive assessment of West Virginia groundwater quality to date, indicates the water quality of West Virginia’s groundwater is generally good

  3. Methods of Statistical Control for Groundwater Quality Indicators

    NASA Astrophysics Data System (ADS)

    Yankovich, E.; Nevidimova, O.; Yankovich, K.

    2016-06-01

    The article describes the results of conducted groundwater quality control. Controlled quality indicators included the following microelements - barium, manganese, iron, mercury, iodine, chromium, strontium, etc. Quality control charts - X-bar chart and R chart - were built. For the upper and the lower threshold limits, maximum permissible concentration of components in water and the lower limit of their biologically significant concentration, respectively, were selected. The charts analysis has shown that the levels of microelements content in water at the area of study are stable. Most elements in the underground water are contained in concentrations, significant for human organisms consuming the water. For example, such elements as Ba, Mn, Fe have concentrations that exceed maximum permissible levels for drinking water.

  4. Groundwater quality data from the National Water-Quality Assessment Project, May 2012 through December 2013

    USGS Publications Warehouse

    Arnold, Terri L.; Desimone, Leslie A.; Bexfield, Laura M.; Lindsey, Bruce D.; Barlow, Jeannie R.; Kulongoski, Justin T.; Musgrove, Marylynn; Kingsbury, James A.; Belitz, Kenneth

    2016-01-01

    Groundwater-quality data were collected from 748 wells as part of the National Water-Quality Assessment Project of the U.S. Geological Survey National Water-Quality Program from May 2012 through December 2013. The data were collected from four types of well networks: principal aquifer study networks, which assess the quality of groundwater used for public water supply; land-use study networks, which assess land-use effects on shallow groundwater quality; major aquifer study networks, which assess the quality of groundwater used for domestic supply; and enhanced trends networks, which evaluate the time scales during which groundwater quality changes. Groundwater samples were analyzed for a large number of water-quality indicators and constituents, including major ions, nutrients, trace elements, volatile organic compounds, pesticides, and radionuclides. These groundwater quality data are tabulated in this report. Quality-control samples also were collected; data from blank and replicate quality-control samples are included in this report.

  5. Groundwater occurrence in cold environments: examples from Nunavik, Canada

    NASA Astrophysics Data System (ADS)

    Lemieux, Jean-Michel; Fortier, Richard; Talbot-Poulin, Marie-Catherine; Molson, John; Therrien, René; Ouellet, Michel; Banville, David; Cochand, Marion; Murray, Renaud

    2016-04-01

    Water availability and management issues related to the supply of drinking water in northern communities are problematic in Canada. While rivers and lakes are abundant, they are vulnerable to contamination and may become dry in winter due to freezing. Groundwater can often provide a more secure and sustainable water source, however its availability is limited in northern Canada due to the presence of permafrost. Moreover, the exploitation of northern aquifers poses a dual challenge of identifying not only permafrost-free areas, but also permeable areas which will allow groundwater recharge and exploitation. Suitable aquifers are not as common in northern Canada since the shallow subsurface is mostly composed of low-permeability crystalline rocks or unconsolidated sediments of glacial origin that are highly heterogeneous. In order to investigate groundwater occurrence and associated geological contexts in Nunavik (northern Quebec, Canada), along with exploring how these resources will evolve in response to climate change, field and compilation work were conducted in the surroundings of the four villages of Salluit, Kuujjuaq, Umiujaq and Whapmagoostui-Kuujjuarapik. These villages are located in different permafrost zones, ranging from continuous to discontinuous, as well as in different geological environments. It was found that despite the ubiquitous presence of permafrost, unfrozen aquifers could be identified, which suggests that groundwater may be available as a source of drinking water for small communities. Expected climate change, with predicted permafrost thawing and increases in temperature and precipitation, should enhance groundwater availability and may contribute to a more secure source of drinking water for northern communities.

  6. Using the conceptual site model approach to characterize groundwater quality

    SciTech Connect

    Shephard, E.; Glucksberg, N.; Walter, N.

    2007-07-01

    To understand groundwater quality, the first step is to develop a conceptual site model (CSM) that describes the site history, describes the geology and the hydrogeology of the site, identifies potential release areas or sources, and evaluates the fate and transport of site related compounds. After the physical site setting is understood and potential release areas are identified, appropriate and representative groundwater monitoring wells may be used to evaluate groundwater quality at a site and provide a network to assess impacts from potential future releases. To develop the CSM, the first step to understand the different requirements from each of the regulatory stakeholders. Each regulatory agency may have different approaches to site characterization and closure (i.e., different groundwater and soil remediation criteria). For example, the United States Environmental Protection Agency (EPA) and state governments have published guidance documents that proscribe the required steps and information needed to develop a CSM. The Nuclear Regulatory Commission (NRC) has a proscriptive model for the Historical Site Assessment under the Multi-Agency Radiation Survey and Site Investigation Manual (MARSSIM), and contains requirements for developing a conceptual site model in NUREG 1757. Federal and state agencies may also have different closure criteria for potential contaminants of concern. Understanding these differences before starting a groundwater monitoring program is important because the minimum detectable activity (MDA), lowest limit detection (LLD), and sample quantitation limit (SQL) must be low enough so that data may be evaluated under each of the programs. After a Historical Site Assessment is completed a work plan is developed and executed to not only collect physical data that describes the geology and hydrogeology, but to also characterize the soil, groundwater, sediments, and surface water quality of each potentially impacted areas. Although the primary

  7. Spatial assessment of groundwater quality based on minor ions

    NASA Astrophysics Data System (ADS)

    Karthikeyan, B.; Elango, L.

    2011-12-01

    Use of water for domestic, agricultural and industrial purpose depends on the desirable range of concentration of various ions. As the suitability of groundwater for different use depends on concentration of several ions, delineation of a region having groundwater of suitable quality relies on integrating the quality of groundwater with respect to each ion. This can be brought out with the aid of advanced tools such as GIS (geographical information system). This study was carried out with the objective of assessing the groundwater quality based on EC (electrical conductivity), fluoride, bromide and nitrate using GIS techniques and the regions requiring attention for groundwater treatment was identified in a part of Nalgonda district, Andhra Pradesh, southern India. Forty five groundwater samples were collected and their EC, fluoride, nitrate and bromide concentration was analysed. Groundwater was not suitable for consumption in 6.6% of the samples based on EC. Fluoride, nitrate and bromide concentration in groundwater was not permissible as per BIS and WHO standards in 57%, 22% and 11% of the groundwater samples respectively. The areas having groundwater suitable or unsuitable for domestic use was delineated using GIS. The groundwater samples collected from 69% of the locations exceeded the desirable limit for drinking for atleast one parameter. The groundwater was unsuitable for domestic use in the northeastern and southeastern parts of this area. The source for the concentration of these parameters exceeding the limit is different for each parameter. Hence it is important to take a suitable collective measure in improving the groundwater quality. Considering the various options available for redeeming the groundwater quality, artificial recharge of groundwater by rainwater harvesting will be suitable to reduce the concentration of all ions in this area.

  8. Zonal management of multi-purposes groundwater utilization based on water quality and impact on the aquifer.

    PubMed

    Liang, Ching-Ping; Jang, Cheng-Shin; Chen, Ching-Fang; Chen, Jui-Sheng

    2016-07-01

    Groundwater is widely used for drinking, irrigation, and aquaculture in the Pingtung Plain, Southwestern Taiwan. The overexploitation and poor quality of groundwater in some areas of the Pingtung Plain pose great challenges for the safe use and sustainable management of groundwater resources. Thus, establishing an effective management plan for multi-purpose groundwater utilization in the Pingtung Plain is imperative. Considerations of the quality of the groundwater and potential impact on the aquifer of groundwater exploitation are paramount to multi-purpose groundwater utilization management. This study proposes a zonal management plan for the multi-purpose use of groundwater in the Pingtung Plain. The zonal management plan is developed by considering the spatial variability of the groundwater quality and the impact on the aquifer, which is defined as the ratio of the actual groundwater extraction rate to transmissivity. A geostatistical Kriging approach is used to spatially delineate the safe zones based on the water quality standards applied in the three groundwater utilization sectors. Suitable zones for the impact on the aquifer are then spatially determined. The evaluation results showing the safe water quality zones for the three types of utilization demands and suitable zones for the impact on aquifer are integrated to create a zonal management map for multi-purpose groundwater utilization which can help government administrators to establish a water resource management strategy for safe and sustainable use of groundwater to meet multi-purpose groundwater utilization requirements in the Pingtung Plain. PMID:27343131

  9. Groundwater quality in western New York, 2011

    USGS Publications Warehouse

    Reddy, James E.

    2013-01-01

    Water samples collected from 16 production wells and 15 private residential wells in western New York from July through November 2011 were analyzed to characterize the groundwater quality. Fifteen of the wells were finished in sand and gravel aquifers, and 16 were finished in bedrock aquifers. Six of the 31 wells were sampled in a previous western New York study, which was conducted in 2006. Water samples from the 2011 study were analyzed for 147 physiochemical properties and constituents that included major ions, nutrients, trace elements, radionuclides, pesticides, volatile organic compounds (VOCs), and indicator bacteria. Results of the water-quality analyses are presented in tabular form for individual wells, and summary statistics for specific constituents are presented by aquifer type. The results are compared with Federal and New York State drinking-water standards, which typically are identical. The results indicate that groundwater generally is of acceptable quality, although at 30 of the 31 wells sampled, at least one of the following constituents was detected at a concentration that exceeded current or proposed Federal or New York State drinking-water standards: pH (two samples), sodium (eight samples), sulfate (three samples), total dissolved solids (nine samples), aluminum (two samples), arsenic (one sample), iron (ten samples), manganese (twelve samples), radon-222 (sixteen samples), benzene (one sample), and total coliform bacteria (nine samples). Existing drinking-water standards for color, chloride, fluoride, nitrate, nitrite, antimony, barium, beryllium, cadmium, chromium, copper, lead, mercury, selenium, silver, thallium, zinc, gross alpha radioactivity, uranium, fecal coliform, Escherichia coli, and heterotrophic bacteria were not exceeded in any of the samples collected. None of the pesticides analyzed exceeded existing drinking-water standards.

  10. Urbanization effect on groundwater quality (Paleohydrogeological study)

    NASA Astrophysics Data System (ADS)

    Sabri, Raghid; Merkel, Broder; Tichomirowa, Marion

    2015-04-01

    Speleothem growing in caves usually contain hydrological information. Carbonates precipitation growing in tunnels under cities contain information about anthropological influence on water system. Carbonate samples were taken from Roman tunnels in rural and urban area in Nablus district- Palestine. These laminated samples were analyzed for rare earth elements (REE), 13C and 18O. For REE, five samples were examined, each lamination was extracted and diluted with 0.1 ml 65% HNO3 and measured using ICP-MS. Yet, limited number of lamination was used for isotope analysis using Isotope ratio mass spectrometry. Total concentration of rare earth elements were calculated for each of the five samples. In all examined samples, the newer laminations show higher peaks than the older one of each sample. On the other hand, one sample (8 measurements) of 13C show values between -31.6° and -36°. These values mean that the carbonate is from organic origin. In an urban area, wastewater infiltration into groundwater system can be the source of organic matter. 18O measurements show continues enrichments within the growth of the carbonate. This increase of the 18O values reflects drier weather. Our results can be explained by the increase of water consumption in the household in the recent 100 years, rather than the increase of using detergents and cleaning products which have influenced groundwater quality as appeared in the carbonate samples. On the other hand, 18O results could be linked with the expansion of the building up area in the city and subsequently reduction of groundwater recharge

  11. Impacts of Sewer Leaks on Surrounding Groundwater and Surface Water Quality in Singapore

    NASA Astrophysics Data System (ADS)

    Ly, D.; Chui, T. M.

    2011-12-01

    Underground sewers deteriorate over time resulting in cracks and joint defects. Sewage thus leaks out of the sewers and contaminates the surrounding groundwater. Singapore does not directly use groundwater as a water supply. However, contaminated groundwater flows into the drains nearby through weep holes, and subsequently enters water supply reservoirs. This study examines the impacts of sewage leaks on surrounding groundwater and surface water quality by modeling the interactions between leaky sewers, groundwater and drains. It first explores the representations of important yet challenging boundary conditions, namely weep holes and leaky sewers, so that their fluxes vary realistically with water pressure throughout a simulation. It then simulates groundwater flow and contaminant transport from leaky sewers to nearby drains over a period of ten years. It further rehabilitates the sewers and models the attenuation of contamination plume for another ten years. The results of this project contribute to the modeling and understanding of the potential impacts of sewer leaks on surrounding groundwater and surface water quality. For example, groundwater quality changes with hydrologic conditions, and it is highest during heavy rainfall and times of high water table because of the low leakage and high dilution rates. Water quality fluctuates daily or even hourly in the vicinity of the sewers, but is more stable in the flow through the weep holes into the drains. Overall, this study benefits the sewer leak monitoring and sewer rehabilitation in many urban areas worldwide.

  12. Multifunctional composites aircraft applications in Finmeccanica - Some examples

    NASA Astrophysics Data System (ADS)

    Iannone, Michele

    2016-05-01

    Some examples of multifunctional composite materials presently developed by Finmeccanica are described. The basic concept is to modify the material/structure by adding a further function to the structural basic one. The described examples refer to: improvement of processability; self-diagnostic capability; improvement of the allowables, acting on reduction of the knock down factor required to take in account the environmental ageing effects.

  13. Urban waste landfill planning and karstic groundwater resources in developing countries: the example of Lusaka (Zambia)

    NASA Astrophysics Data System (ADS)

    De Waele, J.; Nyambe, I. A.; Di Gregorio, A.; Di Gregorio, F.; Simasiku, S.; Follesa, R.; Nkemba, S.

    2004-06-01

    Lusaka, the capital city of Zambia with more than two million inhabitants, derives approximately 70% of its water requirements from groundwater sourced in the underlying karstic Lusaka aquifer. This water resource is, therefore, extremely important for the future of the population. The characteristics of the aquifer and the shallow water table make the resource vulnerable and in need of protection and monitoring. A joint project between the Geology Departments of the University of Cagliari and the School of Mines of the University of Zambia, to investigate the "Anthropogenic and natural processes in the Lusaka area leading to environmental degradation and their possible mitigation" was carried out in July 2001. The main objective of the study was to evaluate the extent of the present environmental degradation, assessing the vulnerability of the carbonatic aquifer and the degree of pollution of the groundwater and to make proposals to mitigate adverse environmental effects. Analyses of water samples collected during project indicate some areas of concern, particularly with respect to the levels of ammonia, nitrates and some heavy metals. As groundwater quality and quantity are prerogatives for a healthy and sustainable society, the study offers guidelines for consideration by the local and national authorities. Uptake of these guidelines should result in a number of initiatives being taken, including: (a) closure or reclamation of existing waste dumps; (b) upgrading of existing waste dumps to controlled landfills; (c) establishing new urban waste landfills and plants in geo-environmentally suitable sites; (d) local waste management projects in all compounds (residential areas) to prevent and reduce haphazard waste dumping; (e) enlarging sewerage drainage systems to all compounds; (f) enforcing control on groundwater abstraction and pollution, and demarcation of zones of control at existing drill holes; (g) providing the city with new water supplies from outside the

  14. Groundwater sustainability strategies

    USGS Publications Warehouse

    Gleeson, Tom; VanderSteen, Jonathan; Sophocleous, Marios A.; Taniguchi, Makoto; Alley, William M.; Allen, Diana M.; Zhou, Yangxiao

    2010-01-01

    Groundwater extraction has facilitated significant social development and economic growth, enhanced food security and alleviated drought in many farming regions. But groundwater development has also depressed water tables, degraded ecosystems and led to the deterioration of groundwater quality, as well as to conflict among water users. The effects are not evenly spread. In some areas of India, for example, groundwater depletion has preferentially affected the poor. Importantly, groundwater in some aquifers is renewed slowly, over decades to millennia, and coupled climate–aquifer models predict that the flux and/or timing of recharge to many aquifers will change under future climate scenarios. Here we argue that communities need to set multigenerational goals if groundwater is to be managed sustainably.

  15. Strategy Guideline: Quality Management in Existing Homes; Cantilever Floor Example

    SciTech Connect

    Taggart, J.; Sikora, J.; Wiehagen, J.; Wood, A.

    2011-12-01

    This guideline is designed to highlight the QA process that can be applied to any residential building retrofit activity. The cantilevered floor retrofit detailed in this guideline is included only to provide an actual retrofit example to better illustrate the QA activities being presented. The goal of existing home high performing remodeling quality management systems (HPR-QMS) is to establish practices and processes that can be used throughout any remodeling project. The research presented in this document provides a comparison of a selected retrofit activity as typically done versus that same retrofit activity approached from an integrated high performance remodeling and quality management perspective. It highlights some key quality management tools and approaches that can be adopted incrementally by a high performance remodeler for this or any high performance retrofit. This example is intended as a template and establishes a methodology that can be used to develop a portfolio of high performance remodeling strategies.

  16. Optimizing the monitoring scheme for groundwater quality in the Lusatian mining region

    NASA Astrophysics Data System (ADS)

    Zimmermann, Beate; Hildmann, Christian; Haubold-Rosar, Michael

    2014-05-01

    Opencast lignite mining always requires the lowering of the groundwater table. In Lusatia, strong mining activities during the GDR era were associated with low groundwater levels in huge parts of the region. Pyrite (iron sulfide) oxidation in the aerated sediments is the cause for a continuous regional groundwater pollution with sulfates, acids, iron and other metals. The contaminated groundwater poses danger to surface water bodies and may also affect soil quality. Due to the decline of mining activities after the German reunification, groundwater levels have begun to recover towards the pre-mining stage, which aggravates the environmental risks. Given the relevance of the problem and the need for effective remediation measures, it is mandatory to know the temporal and spatial distribution of potential pollutants. The reliability of these space-time models, in turn, relies on a well-designed groundwater monitoring scheme. So far, the groundwater monitoring network in the Lusatian mining region represents a purposive sample in space and time with great variations in the density of monitoring wells. Moreover, groundwater quality in some of the areas that face pronounced increases in groundwater levels is currently not monitored at all. We therefore aim to optimize the monitoring network based on the existing information, taking into account practical aspects such as the land-use dependent need for remedial action. This contribution will discuss the usefulness of approaches for optimizing spatio-temporal mapping with regard to groundwater pollution by iron and aluminum in the Lusatian mining region.

  17. Groundwater quality in central New York, 2012

    USGS Publications Warehouse

    Reddy, James E.

    2014-01-01

    Water samples were collected from 14 production wells and 15 private wells in central New York from August through December 2012 in a study conducted by the U.S. Geological Survey in cooperation with the New York State Department of Environmental Conservation. The samples were analyzed to characterize the groundwater quality in unconsolidated and bedrock aquifers in this area. Fifteen of the wells are finished in sand-and-gravel aquifers, and 14 are finished in bedrock aquifers. Six of the 29 wells were sampled in a previous central New York study, which was conducted in 2007. Water samples from the 2012 study were analyzed for 147 physiochemical properties and constituents, including major ions, nutrients, trace elements, radionuclides, pesticides, volatile organic compounds, dissolved gases (argon, carbon dioxide, methane, nitrogen, oxygen), and indicator bacteria. Results of the water-quality analyses are presented in tabular form for individual wells, and summary statistics for specific constituents are presented by aquifer type. The results are compared with Federal and New York State drinking-water standards, which typically are identical. The results indicate that the groundwater generally is of acceptable quality, although for all of the wells sampled, at least one of the following constituents was detected at a concentration that exceeded current or proposed Federal or New York State drinking-water standards: color (2 samples), pH (7 samples), sodium (9 samples), chloride (2 samples), fluoride (2 samples), sulfate (2 samples), dissolved solids (8 samples), aluminum (4 samples), arsenic (1 sample), iron (9 samples), manganese (13 samples), radon-222 (13 samples), total coliform bacteria (6 samples), and heterotrophic bacteria (2 samples). Drinking-water standards for nitrate, nitrite, antimony, barium, beryllium, cadmium, chromium, copper, lead, mercury, selenium, silver, thallium, zinc, gross alpha radioactivity, uranium, fecal coliform, and

  18. Modeling surface water-groundwater interaction with MODFLOW: some considerations.

    PubMed

    Brunner, Philip; Simmons, Craig T; Cook, Peter G; Therrien, René

    2010-01-01

    The accuracy with which MODFLOW simulates surface water-groundwater interaction is examined for connected and disconnected losing streams. We compare the effect of different vertical and horizontal discretization within MODFLOW and also compare MODFLOW simulations with those produced by HydroGeoSphere. HydroGeoSphere is able to simulate both saturated and unsaturated flow, as well as surface water, groundwater and the full coupling between them in a physical way, and so is used as a reference code to quantify the influence of some of the simplifying assumptions of MODFLOW. In particular, we show that (1) the inability to simulate negative pressures beneath disconnected streams in MODFLOW results in an underestimation of the infiltration flux; (2) a river in MODFLOW is either fully connected or fully disconnected, while in reality transitional stages between the two flow regimes exist; (3) limitations in the horizontal discretization of the river can cause a mismatch between river width and cell width, resulting in an error in the water table position under the river; and (4) because coarse vertical discretization of the aquifer is often used to avoid the drying out of cells, this may result in an error in simulating the height of the groundwater mound. Conditions under which these errors are significant are investigated. PMID:19891721

  19. Some Examples of the Application and Validation of the NUFT Subsurface Flow and Transport Code

    SciTech Connect

    Nitao, J J

    2001-08-01

    This report was written as partial fulfillment of a subcontract from DOD/DOE Strategic Environmental Research and Development Program (SERDP) as part of a project directed by the U.S. Army Engineer Research and Development Center, Waterways Experiment Station (WES), Vicksburg, Mississippi. The report documents examples of field validation of the Non-isothermal Unsaturated-saturated Flow and Transport model (NUFT) code for environmental remediation, with emphasis on soil vapor extraction, and describes some of the modifications needed to integrate the code into the DOD Groundwater Modeling System (GMS, 2000). Note that this report highlights only a subset of the full capabilities of the NUFT code.

  20. Environmental impacts during geothermal development: Some examples from Central America

    SciTech Connect

    Goff, S.; Goff, F.

    1997-04-01

    The impacts of geothermal development projects are usually positive. However, without appropriate monitoring plans and mitigation actions firmly incorporated into the project planning process, there exists the potential for significant negative environmental impacts. The authors present five examples from Central America of environmental impacts associated with geothermal development activities. These brief case studies describe landslide hazards, waste brine disposal, hydrothermal explosions, and air quality issues. Improved Environmental Impact Assessments are needed to assist the developing nations of the region to judiciously address the environmental consequences associated with geothermal development.

  1. Baseline assessment of groundwater quality in Wayne County, Pennsylvania, 2014

    USGS Publications Warehouse

    Senior, Lisa A.; Cravotta, III, Charles A.; Sloto, Ronald A.

    2016-01-01

    The Devonian-age Marcellus Shale and the Ordovician-age Utica Shale, geologic formations which have potential for natural gas development, underlie Wayne County and neighboring counties in northeastern Pennsylvania. In 2014, the U.S. Geological Survey, in cooperation with the Wayne Conservation District, conducted a study to assess baseline shallow groundwater quality in bedrock aquifers in Wayne County prior to potential extensive shale-gas development. The 2014 study expanded on previous, more limited studies that included sampling of groundwater from 2 wells in 2011 and 32 wells in 2013 in Wayne County. Eighty-nine water wells were sampled in summer 2014 to provide data on the presence of methane and other aspects of existing groundwater quality throughout the county, including concentrations of inorganic constituents commonly present at low levels in shallow, fresh groundwater but elevated in brines associated with fluids extracted from geologic formations during shale-gas development. Depths of sampled wells ranged from 85 to 1,300 feet (ft) with a median of 291 ft. All of the groundwater samples collected in 2014 were analyzed for bacteria, major ions, nutrients, selected inorganic trace constituents (including metals and other elements), radon-222, gross alpha- and gross beta-particle activity, selected man-made organic compounds (including volatile organic compounds and glycols), dissolved gases (methane, ethane, and propane), and, if sufficient methane was present, the isotopic composition of methane.Results of the 2014 study show that groundwater quality generally met most drinking-water standards, but some well-water samples had one or more constituents or properties, including arsenic, iron, pH, bacteria, and radon-222, that exceeded primary or secondary maximum contaminant levels (MCLs). Arsenic concentrations were higher than the MCL of 10 micrograms per liter (µg/L) in 4 of 89 samples (4.5 percent) with concentrations as high as 20 µg/L; arsenic

  2. Appraisal of ground-water quality near wastewater-treatment facilities, Glacier National Park, Montana

    USGS Publications Warehouse

    Moreland, Joe A.; Wood, Wayne A.

    1982-01-01

    Water-level and water-quality data were collected from monitoring wells at wastewater-treatment facilities in Glacier National Park. Five additional shallow observation wells were installed at the Glacier Park Headquarters facility to monitor water quality in the shallow ground-water system. Water-level, water-quality, and geologic information indicate that some of the initial monitoring wells are not ideally located to sample ground water most likely to be affected by waste disposal at the sites. Small differences in chemical characteristics between samples from monitor wells indicate that effluent may be affecting ground-water quality but that impacts are not significant. Future monitoring of ground-water quality could be limited to selected wells most likely to be impacted by percolating effluent. Laboratory analyses for common ions could detect future impacts. (USGS)

  3. Hydrogeochemistry of the shallow dutch groundwater: Interpretation of the National Groundwater Quality Monitoring Network

    NASA Astrophysics Data System (ADS)

    Frapporti, G.; Vriend, P.; Van Gaans, P. F. M.

    1993-09-01

    Since 1979 the Dutch National Institute of Public Health and Environmental Protection (RIVM) has been developing the Dutch Groundwater Quality Monitoring Network (LMG). This network presently consists of about 350 monitoring sites. At each site, well screens are placed at two depths: 10 and 25 m below surface level. Samples are collected every year and are analyzed for all macrochemical parameters and some trace elements. Tritium contents were measured in the first sampling round. The geochemistry of Dutch groundwater is complex, due to the different sources (seawater, surface water and rainwater), complicated hydrogeology, and human impact on flow systems and pollution. Structuring or data analysis is required for the interpretation of the large number of hydrogeochemical data from such a monitoring network. An exploratory approach is to look within the data set for homogeneous groups, each with a typical (macro)chemistry. The selection criteria for the location of the monitoring sites of the LMG are mainly based on soil type and land use, and to some extent on the hydrogeological situation. However, a classification based on the two most reliable criteria, soil type and land use, does not result in chemically distinguishable homogeneous groups or water types. Fuzzy c means clustering was successfully used to discern structure and natural groups in the LMG data for 1 year. A seven-cluster model was adopted. The number of clusters was decided heuristically with the aid of nonlinear mapping, on the basis of the geographic distribution, the hydrogeochemical interpretability, and the unimodality of the distribution of the parameters per cluster. The consistency of the model is illustrated by the reproducibility of the clusters in different years. The clusters are related to geochemical processes, natural sources, and anthropogenic input and are designated as follows: (1) "seawater" in coastal areas, (2) "desalinization" in organic-rich Holocene marine and peat

  4. Some Examples of the Relations Between Processing and Damage Tolerance

    NASA Technical Reports Server (NTRS)

    Nettles, Alan T.

    2012-01-01

    Most structures made of laminated polymer matrix composites (PMCs) must be designed to some damage tolerance requirement that includes foreign object impact damage. Thus from the beginning of a part s life, impact damage is assumed to exist in the material and the part is designed to carry the required load with the prescribed impact damage present. By doing this, some processing defects may automatically be accounted for in the reduced design allowable due to these impacts. This paper will present examples of how a given level of impact damage and certain processing defects affect the compression strength of a laminate that contains both. Knowledge of the impact damage tolerance requirements, before processing begins, can broaden material options and processing techniques since the structure is not being designed to pristine properties.

  5. Some unreliable types of ground-water observation wells

    USGS Publications Warehouse

    Remson, Irwin; Fox, G.S.

    1954-01-01

    Several primary requirements must be fulfilled by any observation well that is to be used as an indicator of ground-water levels over considerable distances. First of all, the water level inside the well must be the same as that outside of the well. the water level inside the well must be able to adjust to water -level fluctuations in the aquifer within a certain period of time, that time dependent upon the type of study for which the observations are to be used. Finally, to be of value in most areal studies, the water level outside the well must be representative of the level throughout the aquifer, and not reflect merely some speical local condition. Should any of these requirements remain unsatisfied, the derived data may be misleading. 

  6. Groundwater-quality monitoring program in Chester County, Pennsylvania, 1980-2008

    USGS Publications Warehouse

    Senior, Lisa A.; Sloto, Ronald A.

    2010-01-01

    -water standards. Groundwater in some agricultural areas had concentrations of nitrate and some pesticides that exceeded drinking-water standards. Elevated concentrations of chloride were measured near salt storage areas and highways. Formaldehyde was detected in groundwater near cemeteries. In residential areas with on-site wastewater disposal, effects on groundwater quality included elevated nitrate concentrations and low concentrations of volatile organic compounds and wastewater compounds, such as antibiotics and detergents. Base-flow samples indicated that groundwater discharge to streams carried contaminants such as nitrate, pesticides, wastewater compounds, and other contaminants. Radionuclides, including radium-226, radium-228, radium-224, and radon-222, and gross alpha-particle activity were measured in groundwater at levels above established and proposed drinking-water standards in some geologic units, particularly in quartzite and quartzite schists. Arsenic concentrations above drinking-water standards were measured in a few samples and were most likely to occur in groundwater in the shales and sandstones in the northern part of the county. Other potential natural hazards, such as lead from aquifer materials or leached from plumbing because of pH, were present in concentrations above drinking-water standards infrequently (less than 10 percent of samples). Limited temporal sampling suggested that chloride concentrations in groundwater increased in the county since the program began in 1980 through 2008, reflecting increasing population and urbanization in that period.

  7. Impacts of swine manure pits on groundwater quality

    USGS Publications Warehouse

    Krapac, I.G.; Dey, W.S.; Roy, W.R.; Smyth, C.A.; Storment, E.; Sargent, S.L.; Steele, J.D.

    2002-01-01

    Manure deep-pits are commonly used to store manure at confined animal feeding operations. However, previous to this study little information had been collected on the impacts of deep-pits on groundwater quality to provide science-based guidance in formulating regulations and waste management strategies that address risks to human health and the environment. Groundwater quality has been monitored since January 1999 at two hog finishing facilities in Illinois that use deep-pit systems for manure storage. Groundwater samples were collected on a monthly basis and analyzed for inorganic and bacteriological constituent concentrations. The two sites are located in areas with geologic environments representing different vulnerabilities for local groundwater contamination. One site is underlain by more than 6 m of clayey silt, and 7-36 m of shale. Concentrations of chloride, ammonium, phosphate, and potassium indicated that local groundwater quality had not been significantly impacted by pit leakage from this facility. Nitrate concentrations were elevated near the pit, often exceeding the 10 mg N/l drinking water standard. Isotopic nitrate signatures suggested that the nitrate was likely derived from soil organic matter and fertilizer applied to adjacent crop fields. At the other site, sandstone is located 4.6-6.1 m below land surface. Chloride concentrations and ??15N and ??18O values of dissolved nitrate indicated that this facility may have limited and localized impacts on groundwater. Other constituents, including ammonia, potassium, phosphate, and sodium were generally at or less than background concentrations. Trace- and heavy-metal concentrations in groundwater samples collected from both facilities were at concentrations less than drinking water standards. The concentration of inorganic constituents in the groundwater would not likely impact human health. Fecal streptococcus bacteria were detected at least once in groundwater from all monitoring wells at both sites

  8. Assessing the Groundwater Quality at a Saudi Arabian Agricultural Site and the Occurrence of Opportunistic Pathogens on Irrigated Food Produce.

    PubMed

    Alsalah, Dhafer; Al-Jassim, Nada; Timraz, Kenda; Hong, Pei-Ying

    2015-10-01

    This study examines the groundwater quality in wells situated near agricultural fields in Saudi Arabia. Fruits (e.g., tomato and green pepper) irrigated with groundwater were also assessed for the occurrence of opportunistic pathogens to determine if food safety was compromised by the groundwater. The amount of total nitrogen in most of the groundwater samples exceeded the 15 mg/L permissible limit for agricultural irrigation. Fecal coliforms in densities > 12 MPN/100 mL were detected in three of the groundwater wells that were in close proximity to a chicken farm. These findings, coupled with qPCR-based fecal source tracking, show that groundwater in wells D and E, which were nearest to the chicken farm, had compromised quality. Anthropogenic contamination resulted in a shift in the predominant bacterial phyla within the groundwater microbial communities. For example, there was an elevated presence of Proteobacteria and Cyanobacteria in wells D and E but a lower overall microbial richness in the groundwater perturbed by anthropogenic contamination. In the remaining wells, the genus Acinetobacter was detected at high relative abundance ranging from 1.5% to 48% of the total groundwater microbial community. However, culture-based analysis did not recover any antibiotic-resistant bacteria or opportunistic pathogens from these groundwater samples. In contrast, opportunistic pathogenic Enterococcus faecalis and Pseudomonas aeruginosa were isolated from the fruits irrigated with the groundwater from wells B and F. Although the groundwater was compromised, quantitative microbial risk assessment suggests that the annual risk incurred from accidental consumption of E. faecalis on these fruits was within the acceptable limit of 10(-4). However, the annual risk arising from P. aeruginosa was 9.55 × 10(-4), slightly above the acceptable limit. Our findings highlight that the groundwater quality at this agricultural site in western Saudi Arabia is not pristine and that better

  9. Assessing the Groundwater Quality at a Saudi Arabian Agricultural Site and the Occurrence of Opportunistic Pathogens on Irrigated Food Produce

    PubMed Central

    Alsalah, Dhafer; Al-Jassim, Nada; Timraz, Kenda; Hong, Pei-Ying

    2015-01-01

    This study examines the groundwater quality in wells situated near agricultural fields in Saudi Arabia. Fruits (e.g., tomato and green pepper) irrigated with groundwater were also assessed for the occurrence of opportunistic pathogens to determine if food safety was compromised by the groundwater. The amount of total nitrogen in most of the groundwater samples exceeded the 15 mg/L permissible limit for agricultural irrigation. Fecal coliforms in densities > 12 MPN/100 mL were detected in three of the groundwater wells that were in close proximity to a chicken farm. These findings, coupled with qPCR-based fecal source tracking, show that groundwater in wells D and E, which were nearest to the chicken farm, had compromised quality. Anthropogenic contamination resulted in a shift in the predominant bacterial phyla within the groundwater microbial communities. For example, there was an elevated presence of Proteobacteria and Cyanobacteria in wells D and E but a lower overall microbial richness in the groundwater perturbed by anthropogenic contamination. In the remaining wells, the genus Acinetobacter was detected at high relative abundance ranging from 1.5% to 48% of the total groundwater microbial community. However, culture-based analysis did not recover any antibiotic-resistant bacteria or opportunistic pathogens from these groundwater samples. In contrast, opportunistic pathogenic Enterococcus faecalis and Pseudomonas aeruginosa were isolated from the fruits irrigated with the groundwater from wells B and F. Although the groundwater was compromised, quantitative microbial risk assessment suggests that the annual risk incurred from accidental consumption of E. faecalis on these fruits was within the acceptable limit of 10−4. However, the annual risk arising from P. aeruginosa was 9.55 × 10−4, slightly above the acceptable limit. Our findings highlight that the groundwater quality at this agricultural site in western Saudi Arabia is not pristine and that better

  10. Groundwater Quality Assessment in the Upper East Region of Ghana

    NASA Astrophysics Data System (ADS)

    Apambire, W. B.

    2001-05-01

    In Ghana, West Africa, fluoride occurs as a natural pollutant in some groundwaters, while the presence of isolated high levels of nitrate and arsenic in groundwater is due to human activities such as poor sanitation, garbage disposal and mining practices. The challenge for Ghana is to ensure that groundwater quality and environmental adversities such as water level decline are not compromised by attempts to increase water quantity. Concentrations of groundwater fluoride in the study area range from 0.11 to 4.60 mg/L, with the highest concentrations found in the fluorine-enriched Bongo granitoids. Eighty-five out of 400 wells sampled have fluoride concentrations above the World Health Organization maximum guideline value of 1.5 mg/L and thus causes dental fluorosis in children drinking from the wells. The distribution of fluoride in groundwater is highly related to the distribution of dental fluorosis in the UER. Nitrate concentrations ranged from 0.03 to 211.00 mg/L and the mean value was 16.11 mg/L. Twenty-one samples had concentrations in excess of the guideline value of 45 mg/L. Consumption of water in excess of the guideline value, by infants, may cause an infantile disease known as methaemoglobinaemia. It is inferred that groundwaters with exceptionally high NO3 values have been contaminated principally through human activities such as farming and waste disposal. This is because wells with high nitrate concentrations are all located in and around towns and sizable villages. Also, there is good correlation between Cl and NO3 (r = +0.74), suggesting that both elements come from the same sources of pollution. Only two well waters had concentrations of iron in excess of the guideline value of 0.3 mg/L. These samples come from shallow hand-dug wells. The maximum concentration of iron in groundwaters is 3.5 mg/L. The recommended guideline limit for Al in drinking water is 0.2 mg/L; two wells had Al concentrations of 12.0 and 4.0 mg/L, respectively. Other high

  11. Agricultural conversion of floodplain ecosystems: implications for groundwater quality.

    PubMed

    Schilling, Keith E; Jacobson, Peter J; Vogelgesang, Jason A

    2015-04-15

    With current trends of converting grasslands to row crop agriculture in vulnerable areas, there is a critical need to evaluate the effects of land use on groundwater quality in large river floodplain systems. In this study, groundwater hydrology and nutrient dynamics associated with three land cover types (grassland, floodplain forest and cropland) were assessed at the Cedar River floodplain in southeastern Iowa. The cropland site consisted of newly-converted grassland, done specifically for our study. Our objectives were to evaluate spatial and temporal variations in groundwater hydrology and quality, and quantify changes in groundwater quality following land conversion from grassland to row crop in a floodplain. We installed five shallow and one deep monitoring wells in each of the three land cover types and recorded water levels and quality over a three year period. Crop rotations included soybeans in year 1, corn in year 2 and fallow with cover crops during year 3 due to river flooding. Water table levels behaved nearly identically among the sites but during the second and third years of our study, NO₃-N concentrations in shallow floodplain groundwater beneath the cropped site increased from 0.5 mg/l to more than 25 mg/l (maximum of 70 mg/l). The increase in concentration was primarily associated with application of liquid N during June of the second year (corn rotation), although site flooding may have exacerbated NO₃-N leaching. Geophysical investigation revealed differences in ground conductivity among the land cover sites that related significantly to variations in groundwater quality. Study results provide much-needed information on the effects of different land covers on floodplain groundwater and point to challenges ahead for meeting nutrient reduction goals if row crop land use expands into floodplains. PMID:25687808

  12. Water quality analysis of groundwater in crystalline basement rocks, Northern Ghana

    NASA Astrophysics Data System (ADS)

    Anku, Yvonne S.; Banoeng-Yakubo, Bruce; Asiedu, Daniel K.; Yidana, Sandow M.

    2009-09-01

    Hydrochemical data are presented for groundwater samples, collected from fractured aquifers in parts of northern Ghana. The data was collected to assess the groundwater suitability for domestic and agricultural use. Results of the study reveal that the pH of the groundwater in the area is slightly acidic to slightly alkaline. The electrical conductivity values, total dissolved solids (TDS) values and calcium, magnesium and sodium concentrations in the groundwater are generally below the limit set by the WHO for potable water supply. On the basis of activity diagrams, groundwater from the fractured aquifers appears to be stable within the montmorillonite field, suggesting weathering of silicate minerals. An inverse distance weighting interpolator with a power of 2 was applied to the data points to produce prediction maps for nitrate and fluoride. The distribution maps show the presence of high nitrate concentrations (50-194 mg/l) in some of the boreholes in the western part of the study area indicating anthropogenic impact on the groundwater. Elevated fluoride level (1.5-4 mg/l), higher than the WHO allowable fluoride concentration of 1.5, is recorded in the groundwater underlying the northeastern part of the study area, more specifically Bongo and its surrounding communities of the Upper East region. Results of this study suggest that groundwater from the fractured aquifers in the area exhibit low sodicity-low salinity (S1-C1), low sodicity-medium salinity (S1-C2) characteristics [United States Salinity Laboratory (USSL) classification scheme]. All data points from this study plot within the ‘Excellent to good’ category on a Wilcox diagram. Groundwater in this area thus appears to provide irrigation water of excellent quality. The hydrochemical results indicate that, although nitrate and fluoride concentrations in some boreholes are high, the groundwater in the study area, based on the parameters analyzed, is chemically potable and suitable for domestic and

  13. Assessment of groundwater quality data for the Turtle Mountain Indian Reservation, Rolette County, North Dakota

    USGS Publications Warehouse

    Lundgren, Robert F.; Vining, Kevin C.

    2013-01-01

    The Turtle Mountain Indian Reservation relies on groundwater supplies to meet the demands of community and economic needs. The U.S. Geological Survey, in cooperation with the Turtle Mountain Band of Chippewa Indians, examined historical groundwater-level and groundwater-quality data for the Fox Hills, Hell Creek, Rolla, and Shell Valley aquifers. The two main sources of water-quality data for groundwater were the U.S. Geological Survey National Water Information System database and the North Dakota State Water Commission database. Data included major ions, trace elements, nutrients, field properties, and physical properties. The Fox Hills and Hell Creek aquifers had few groundwater water-quality data. The lack of data limits any detailed assessments that can be made about these aquifers. Data for the Rolla aquifer exist from 1978 through 1980 only. The concentrations of some water-quality constituents exceeded the U.S. Environmental Protection Agency secondary maximum contaminant levels. No samples were analyzed for pesticides and hydrocarbons. Numerous water-quality samples have been obtained from the Shell Valley aquifer. About one-half of the water samples from the Shell Valley aquifer had concentrations of iron, manganese, sulfate, and dissolved solids that exceeded the U.S. Environmental Protection Agency secondary maximum contaminant levels. Overall, the data did not indicate obvious patterns in concentrations.

  14. Hydrogeochemical quality and suitability studies of groundwater in northern Bangladesh.

    PubMed

    Islam, M J; Hakim, M A; Hanafi, M M; Juraimi, Abdul Shukor; Aktar, Sharmin; Siddiqa, Aysha; Rahman, A K M Shajedur; Islam, M Atikul; Halim, M A

    2014-07-01

    Agriculture, rapid urbanization and geochemical processes have direct or indirect effects on the chemical composition of groundwater and aquifer geochemistry. Hydro-chemical investigations, which are significant for assessment of water quality, were carried out to study the sources of dissolved ions in groundwater of Dinajpur district, northern Bangladesh. The groundwater samplish were analyzed for physico-chemical properties like pH, electrical conductance, hardness, alkalinity, total dissolved solids and Ca2+, Mg2+, Na+, K+, CO3(2-), HCO3(-), SO4(2-) and Cl- ions, respectively. Based on the analyses, certain parameters like sodium adsorption ratio, soluble sodium percentage, potential salinity, residual sodium carbonate, Kelly's ratio, permeability index and Gibbs ratio were also calculated. The results showed that the groundwater of study area was fresh, slightly acidic (pH 5.3-6.4) and low in TDS (35-275 mg I(-1)). Ground water of the study area was found suitable for irrigation, drinking and domestic purposes, since most of the parameters analyzed were within the WHO recommended values for drinking water. High concentration of NO3- and Cl- was reported in areas with extensive agriculture and rapid urbanization. Ion-exchange, weathering, oxidation and dissolution of minerals were major geochemical processes governing the groundwater evolution in study area. Gibb's diagram showed that all the samples fell in the rock dominance field. Based on evaluation, it is clear that groundwater quality of the study area was suitable for both domestic and irrigation purposes. PMID:25004765

  15. Surface water / groundwater interactions and their spatial variability, an example from the Avon River, South-East Australia

    NASA Astrophysics Data System (ADS)

    Hofmann, Harald; Cartwright, Ian; Gilfedder, Benjamin

    2013-04-01

    Understanding the interaction between river water and regional groundwater has significant importance for water management and resource allocation. The dynamics of groundwater/surface water interactions also have implications for ecosystems, pollutant transport, and the quality and quantity of water supply for domestic, agriculture and recreational purposes. After general assumptions and for management purposes rivers are classified in loosing or gaining rivers. However, many streams alternate between gaining and loosing conditions on a range of temporal and spatial scales due to factors including: 1) river water levels in relation to groundwater head; 2) the relative response of the groundwater and river system to rainfall; 3) heterogeneities in alluvial sediments that can lead to alternation of areas of exfiltration and infiltration along a river stretch; and 4) differences in near river reservoirs, such parafluvial flow and bank storage. Spatial variability of groundwater discharge to rivers is rarely accounted for as it is assumed that groundwater discharge is constant over river stretches and only changes with the seasonal river water levels. Riverbank storage and parafluvial flow are generally not taken in consideration. Bank storage has short-term cycles and can contribute significantly to the total discharge, especially after flood events. In this study we used hydrogeochemistry to constrain spatial and temporal differences in gaining and loosing conditions in rivers and investigate potential sources. Environmental tracers, such as major ion chemistry, stables isotopes and Radon are useful tools to characterise these sources. Surface water and ground water samples were taken in the Avon River in the Gippsland Basin, Southwest Australia. Increasing TDS along the flow path from 70 to 250 mg/l, show that the Avon is a net gaining stream. The radon concentration along the river is variable and does not show a general increase downstream, but isolated peaks in

  16. Karst groundwater resources in the countries of eastern Mediterranean: the example of Lebanon

    NASA Astrophysics Data System (ADS)

    Bakalowicz, Michel; El Hakim, Massaad; El-Hajj, Ahmad

    2008-04-01

    The hydrogeological study of some karst systems in Lebanon shows important storage capacity, up to 27 billions m3 for Zarka system, the spring of Orontes River. Their geological and morphological settings, as well as their hydrodynamic function, show structures developed below the level of present springs, probably up to several hundreds meters at depth. Since Miocene, those carbonate formations were subject to a remarkable instability of their base levels. Variations of sea level, of which the Messinian salinity crisis is the major phase, and effects of the alpine orogenesis, combined with climate variations to develop complex, multiphased karst systems. Karstification occurs frequently in the whole formation, often deeply below sea level or underneath sediment filling of continental basins. The surface karst landscape is often intensely eroded. Those multiple, superimposed karst phases give the carbonate aquifers their large extension and storage capacity. These karst aquifers show the typical easy restoration of storage. They have the ability to bear large interannual recharge variations and support exploitation under high pumping rates. However, these aquifers have some disadvantages for sustainable management. In some regions, successful boreholes, which allow high pumping rates also induce uncontrolled exploitation. Another consequence is natural seawater intrusion, as well as the submarine discharge of fresh groundwater, in coastal aquifers. Those carbonate aquifers are subject to important economical stress which jeopardizes their durability. The systematic study and understanding of carbonate aquifers in Eastern Mediterranean is a preliminary condition to any integrated and sustainable management of water resources. Studies in progress in Lebanon may serve as examples to the whole region.

  17. Groundwater Quality Assessment for Waste Management Area U: First Determination

    SciTech Connect

    Hodges, Floyd N.; Chou, Charissa J.

    2000-08-04

    As a result of the most recent recalculation one of the indicator parameters, specific conductance, exceeded its background value in downgradient well 299-W19-41, triggering a change from detection monitoring to groundwater quality assessment program. The major contributors to the higher specific conductance are nonhazardous constituents (i.e., sodium, calcium, magnesium, chloride, sulfate, and bicarbonate). Nitrate, chromium, and technetium-99 are present and are increasing; however, they are significantly below their drinking waster standards. Interpretation of groundwater monitoring data indicates that both the nonhazardous constituents causing elevated specific conductance in groundwater and the tank waste constituents present in groundwater at the waste management area are a result of surface water infiltration in the southern portion of the facility. There is evidence for both upgradient and waste management area sources for observed nitrate concentrations. There is no indication of an upgradient source for the observed chromium and technetium-99.

  18. Interests of hydrogeological observatories for characterizing heterogeneous groundwater systems: the example of the Ploemeur hard-rock aquifer (French Brittany)

    NASA Astrophysics Data System (ADS)

    Bour, O.; Le Borgne, T.; Aquilina, L.; Labasque, T.; Lavenant, N.; Boudin, F.; Leray, S.; De Dreuzy, J.; Longuevergne, L.; Hochreutener, R.; Davy, P.

    2012-12-01

    Heterogeneous aquifers are often poorly constrained by the available data. There is a strong need of characterizing at multiple space and time scales heterogeneous groundwater systems to improve model predictions. Here, we present results from the site of Ploemeur (French Brittany) that belongs to the network of hydrogeological sites H+, and where complementarity approaches have been developed for almost fifteen years. This outstandingly heterogeneous crystalline rock aquifer is used for water supply at a rate of about 10^6 m3 per year since 1991. The geology of the area is relatively complex and involves two main structures: a highly fractured contact zone between the Ploemeur's granite and the overlying micaschists, and a steeply dipping fault striking North 20°. The contact zone in itself consists of alternating deformed granitic sheets and enclaves of micaschists, pegmatite and aplite dykes, and locally mylonites and pegmatite-bearing breccias that are often associated with major borehole inflows. At the site scale - typically a square kilometer - and at relatively shallow depth (100 to 150 m), the connectivity of the main flow paths and the hydraulic properties are relatively well constrained and quantified thanks to cross-borehole flowmeter tests and traditional pumping tests. However, such data are relatively limited in explaining the functioning of this confined groundwater system at the regional scale. Groundwater chemistry and groundwater dating permit to go further to identify distinct reservoirs and in particular a relatively deep groundwater component whose age is older than 50 years. Groundwater temperature measurements demonstrate the role of the pumping that influences greatly the spatial distribution of groundwater temperature and quality. Moreover, it suggests that the main water supply comes from a depth of at least 300 meters. This implies relatively deep groundwater circulation that can be achieved only thanks to major permeable fault zone. At

  19. Assessing the potential risks of burial practices on groundwater quality in rural north-central Nigeria.

    PubMed

    Zume, Joseph T

    2011-09-01

    Several cultures of north-central Nigeria do not use community cemeteries. Instead, human remains are buried in and around family compounds, often in shallow and sometimes unmarked graves. At several locations, graves and drinking water wells end up too close to be presumed environmentally safe. This paper reports findings of a pilot study that explored the potential for groundwater contamination from gravesites in some rural settlements of north-central Nigeria. Preliminary results suggest that the long-standing burial practices among some cultures of rural north-central Nigeria may potentially compromise groundwater quality, which is, by far, their most important source of drinking water. PMID:21976208

  20. Hydrogeochemical considerations about the origin of groundwater salinization in some coastal plains of Elba Island (Tuscany, Italy).

    PubMed

    Giménez-Forcada, Elena; Bencini, Alberto; Pranzini, Giovanni

    2010-06-01

    Several coastal plains of the Elba Island (Marina di Campo, Portoferraio, Schiopparello, Mola, Porto Azzurro and Barbarossa plains) in Tuscany (Italy) were studied to determine the causes of decline in groundwater quality, using major ion chemistry to establish the causes of groundwater salinization. The study demonstrates that salinization of coastal plain alluvial aquifers is not simply linked to seawater intrusion but is also intimately related to inflows from adjacent aquifers. Ionic ratios, correlation graphs and distribution value maps were employed as the means to understand the hydrochemistry of the study areas. The Mg/Cl ratio in particular can be considered a good tracer to distinguish the main salinization processes that control groundwater chemistry. Seawater intrusion only partly determines the chemistry of some groundwaters, which generally belong to a chloride facies where the salinity is derived principally from freshwater-seawater mixing and the participation of cation exchange. Proceeding inland groundwater quality seems to be principally determined by the inflow of Mg, Ca-HCO(3) or Ca, Na-HCO(3) waters formed from the weathering of silicate minerals in adjoining aquifers. Hydrolysis of these minerals is of prime importance in controlling groundwater chemistry in adjacent alluvial plains. The lateral recharge flows introduce water with a different chemical composition and this variable of freshwater recharge changes the hydrochemistry as a result of mixing between two or more waters types. This situation is further complicated when seawater and base exchange reactions participate, due to seawater intrusion. PMID:19894127

  1. Identification of dangerous fibers: some examples in Northern Italy

    NASA Astrophysics Data System (ADS)

    Zanetti, Giovanna; Marini, Paola; Giorgis, Ilaria

    2016-04-01

    The presence of asbestiform minerals has to be foreseen in the planning of infrastructural activities: Asbestos can be a component of sedimentary rocks or of mafic and ultra mafic metamorphic rocks. Surveys and core drilling, in addition to providing important information on the quality of the rock and its geotechnical characteristics, allow for a prediction of the presence of asbestiform minerals in the areas affected by mining or infrastructural activities. During the excavation, workers can be exposed to the asbestos risk, therefore, the control of the air quality and of the excavated materials are fundamental for the safety of involved people. In this work some problems we met in the analysis of airborne filters and bulk samples from sites in northern Italy are presented. The asbestos fibers present in rocks as accessory minerals, are often different in habit and dimension from the well-known asbestos fibers used as industrial minerals and moreover can be erroneously identified as minerals morphologically and chemically similar present in the same rock or environment. In the case of tunnel muck it could be contaminated by substances used for the excavation that could modify colours and optical properties of asbestos minerals. In the PCOM (Phase Contrast Optical Microscope) analysis chrysotile, sepiolite and antigorite, due to their different refraction index, when the fibers have dimension > 0,5 micron and aren't contaminated by lubricant can be easely identified even if the morphology of chrysotile is very similar to that of sepiolite. In Electron Scanning Microscope (SEM) the discrimination between chrysotile and antigorite on the airborne filters is not always possible because the fibers of thin dimensions show similar habit and spectrum. In the case of the tremolite amphibole, morphology changes from prismatic to fibrous depending on its origin (p.eg. Monastero, Val Grana, Verrayes, Brachiello). Both prismatic and asbestiform tremolite (Gamble and Gibbs

  2. Ground-Water Quality and Potential Effects of Individual Sewage Disposal System Effluent on Ground-Water Quality in Park County, Colorado, 2001-2004

    USGS Publications Warehouse

    Miller, Lisa D.; Ortiz, Roderick F.

    2007-01-01

    . Currently (2004), there is no federally enforced drinking-water standard for radon in public water-supply systems, but proposed regulations suggest a maximum contaminant level of 300 picocuries per liter (pCi/L) and an alternative maximum contaminant level of 4,000 pCi/L contingent on other mitigating remedial activities to reduce radon levels in indoor air. Radon concentrations in about 91 percent of ground-water samples were greater than or equal to 300 pCi/L, and about 25 percent had radon concentrations greater than or equal to 4,000 pCi/L. Generally, the highest radon concentrations were measured in samples collected from wells completed in the crystalline-rock aquifers. Analyses of ground-water-quality data indicate that recharge from ISDS effluent has affected some local ground-water systems in Park County. Because roughly 90 percent of domestic water used is assumed to be recharged by ISDS's, detections of human-related (wastewater) compounds in ground water in Park County are not surprising; however, concentrations of constituents associated with ISDS effluent generally are low (concentrations near the laboratory reporting levels). Thirty-eight different organic wastewater compounds were detected in 46 percent of ground-water samples, and the number of compounds detected per sample ranged from 1 to 17 compounds. Samples collected from wells with detections of wastewater compounds also had significantly higher (p-value < 0.05) chloride and boron concentrations than samples from wells with no detections of wastewater compounds. ISDS density (average subdivision lot size used to estimate ISDS density) was related to ground-water quality in Park County. Chloride and boron concentrations were significantly higher in ground-water samples collected from wells located in areas that had average subdivision lot sizes of less than 1 acre than in areas that had average subdivision lot sizes greater than or equal to 1 acre. For wells completed in the crystalline-

  3. GROUNDWATER QUALITY MONITORING RECOMMENDATIONS FOR IN SITU OIL SHALE DEVELOPMENT

    EPA Science Inventory

    This study addresses the two primary groups of uncertainties regarding the implementation of a groundwater quality monitoring program for MIS oil shale development such as proposed for Federal Prototype Lease Tracts C-a and C-b. Hydrogeologic characterization, an essential elemen...

  4. Groundwater quality in the Chemung River Basin, New York, 2008

    USGS Publications Warehouse

    Risen, Amy J.; Reddy, James E.

    2011-01-01

    The second groundwater quality study of the Chemung River Basin in south-central New York was conducted as part of the U.S. Geological Survey 305(b) water-quality-monitoring program. Water samples were collected from five production wells and five private residential wells from October through December 2008. The samples were analyzed to characterize the chemical quality of the groundwater. Five of the wells are screened in sand and gravel aquifers, and five are finished in bedrock aquifers. Two of these wells were also sampled for the first Chemung River Basin study of 2003. Samples were analyzed for 6 physical properties and 217 constituents, including nutrients, major inorganic ions, trace elements, radionuclides, pesticides, volatile organic compounds, phenolic compounds, organic carbon, and four types of bacterial analyses. Results of the water-quality analyses for individual wells are presented in tables, and summary statistics for specific constituents are presented by aquifer type. The results are compared with Federal and New York State drinking-water standards, which typically are identical. Water quality in the study area is generally good, but concentrations of some constituents equaled or exceeded current or proposed Federal or New York State drinking-water standards; these were: sodium (one sample), total dissolved solids (one sample), aluminum (one sample), iron (one sample), manganese (four samples), radon-222 (eight samples), trichloroethene (one sample), and bacteria (four samples). The pH of all samples was typically neutral or slightly basic (median 7.5); the median water temperature was 11.0 degrees Celsius (?C). The ions with the highest median concentrations were bicarbonate (median 202 milligrams per liter [mg/L]) and calcium (median 59.0 mg/L). Groundwater in the study area is moderately hard to very hard, but more samples were hard or very hard (121 mg/L as calcium carbonate (CaCO3) or greater) than were moderately hard (61-120 mg/L as Ca

  5. Some Practical Examples of Computer-Adaptive Sequential Testing.

    ERIC Educational Resources Information Center

    Luecht, Richard M.; Nungester, Ronald J.

    1998-01-01

    Describes an integrated approach to test development and administration called computer-adaptive sequential testing (CAST). CAST incorporates adaptive testing methods with automated test assembly. Describes the CAST framework and demonstrates several applications using a medical-licensure example. (SLD)

  6. Regional assessment of groundwater for drinking purpose subject to water-quality parameters

    NASA Astrophysics Data System (ADS)

    Jang, Cheng-Shin

    2010-05-01

    Owing to limited surface water during a long term drought, this work attempted to locate safe groundwater for drinking in aquifers of the Choushui River alluvial fan, Taiwan subject to its water-quality parameters. Because the aquifers contained multiple pollutions, such as the salinity pollution, the organic pollution, the nitrogen pollution and the heavy metal pollution, multiple-variable indicator kriging (MVIK) was adopted to estimate integration of several pollutions in groundwater based on water-quality standards for drinking and to characterize spatial uncertainty. According to probabilities estimated by MVIK, safe scopes were determined for four treatment conditions - no treatment, ammonium-N removal, manganese removal, and ammonium-N and manganese removals. The analyzed results reveal that, because of exceeding the standards of manganese and/or ammonium-N, groundwater in proximal-fan aquifers (a natural recharging zone) has to be treated appropriately, such as dilution and removals with some treatment approaches, before being drunk. The proximal-fan, southeastern and central regions are the best locations to pump clean and safe groundwater for drinking when devices of ammonium-N and manganese removals are available. Deep aquifers of exceeding 200 m depth have wider safe regions to obtain excellent groundwater for drinking than shallow aquifers do. Keywords: Multiple-variable indicator kriging; groundwater; pollution; drinking

  7. Groundwater-quality data in the northern Coast Ranges study unit, 2009: Results from the California GAMA Program

    USGS Publications Warehouse

    Mathany, Timothy M.; Dawson, Barbara J.; Shelton, Jennifer L.; Belitz, Kenneth

    2011-01-01

    This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, untreated groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is served to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwa

  8. [Cytoskeletal actin and its associated proteins. Some examples in Protista].

    PubMed

    Guillén, N; Carlier, M F; Brugerolle, G; Tardieux, I; Ausseil, J

    1998-06-01

    Many processes, cell motility being an example, require cells to remodel the actin cytoskeleton in response to both intracellular and extracellular signals. Reorganization of the actin cytoskeleton involves the rapid disassembly and reassembly of actin filaments, a phenomenon regulated by the action of particular actin-binding proteins. In recent years, an interest in studying actin regulation in unicellular organisms has arisen. Parasitic protozoan are among these organisms and studies of the cytoskeleton functions of these protozoan are relevant related to either cell biology or pathogenicity. To discuss recent data in this field, a symposium concerning "Actin and actin-binding proteins in protists" was held on May 8-11 in Paris, France, during the XXXV meeting of the French Society of Protistology. As a brief summary of the symposium we report here findings concerning the in vitro actin dynamic assembly, as well as the characterization of several actin-binding proteins from the parasitic protozoan Entamoeba histolytica, Trichomonas vaginalis and Plasmodium knowlesi. In addition, localization of actin in non-pathogen protists such as Prorocentrum micans and Crypthecodinium cohnii is also presented. The data show that some actin-binding proteins facilitate organization of filaments into higher order structures as pseudopods, while others have regulatory functions, indicating very particular roles for actin-binding proteins. One of the proteins discussed during the symposium, the actin depolymerizing factor ADF, was shown to enhance the treadmilling rate of actin filaments. In vitro, ADF binds to the ADP-bound forms of G-actin and F-actin, thereby participating in and changing the rate of actin assembly. Biochemical approaches allowed the identification of a protein complex formed by HSP/C70-cap32-34 which might also be involved in depolymerization of F-actin in P. knowlesi. Molecular and cellular approaches were used to identify proteins such as ABP-120 and myosin

  9. Groundwater quality in the Mohawk River Basin, New York, 2011

    USGS Publications Warehouse

    Nystrom, Elizabeth A.; Scott, Tia-Marie

    2013-01-01

    Water samples were collected from 21 production and domestic wells in the Mohawk River Basin in New York in July 2011 to characterize groundwater quality in the basin. The samples were collected and processed using standard U.S. Geological Survey procedures and were analyzed for 148 physiochemical properties and constituents, including dissolved gases, major ions, nutrients, trace elements, pesticides, volatile organic compounds (VOCs), radionuclides, and indicator bacteria. The Mohawk River Basin covers 3,500 square miles in New York and is underlain by shale, sandstone, carbonate, and crystalline bedrock. The bedrock is overlain by till in much of the basin, but surficial deposits of saturated sand and gravel are present in some areas. Nine of the wells sampled in the Mohawk River Basin are completed in sand and gravel deposits, and 12 are completed in bedrock. Groundwater in the Mohawk River Basin was typically neutral or slightly basic; the water typically was very hard. Bicarbonate, chloride, calcium, and sodium were the major ions with the greatest median concentrations; the dominant nutrient was nitrate. Methane was detected in 15 samples. Strontium, iron, barium, boron, and manganese were the trace elements with the highest median concentrations. Four pesticides, all herbicides or their degradates, were detected in four samples at trace levels; three VOCs, including chloroform and two solvents, were detected in four samples. The greatest radon-222 activity, 2,300 picocuries per liter, was measured in a sample from a bedrock well, but the median radon activity was higher in samples from sand and gravel wells than in samples from bedrock wells. Coliform bacteria were detected in five samples with a maximum of 92 colony-forming units per 100 milliliters. Water quality in the Mohawk River Basin is generally good, but concentrations of some constituents equaled or exceeded current or proposed Federal or New York State drinking-water standards. The standards

  10. Assessment of groundwater quality: a fusion of geochemical and geophysical information via Bayesian neural networks.

    PubMed

    Maiti, Saumen; Erram, V C; Gupta, Gautam; Tiwari, Ram Krishna; Kulkarni, U D; Sangpal, R R

    2013-04-01

    Deplorable quality of groundwater arising from saltwater intrusion, natural leaching and anthropogenic activities is one of the major concerns for the society. Assessment of groundwater quality is, therefore, a primary objective of scientific research. Here, we propose an artificial neural network-based method set in a Bayesian neural network (BNN) framework and employ it to assess groundwater quality. The approach is based on analyzing 36 water samples and inverting up to 85 Schlumberger vertical electrical sounding data. We constructed a priori model by suitably parameterizing geochemical and geophysical data collected from the western part of India. The posterior model (post-inversion) was estimated using the BNN learning procedure and global hybrid Monte Carlo/Markov Chain Monte Carlo optimization scheme. By suitable parameterization of geochemical and geophysical parameters, we simulated 1,500 training samples, out of which 50 % samples were used for training and remaining 50 % were used for validation and testing. We show that the trained model is able to classify validation and test samples with 85 % and 80 % accuracy respectively. Based on cross-correlation analysis and Gibb's diagram of geochemical attributes, the groundwater qualities of the study area were classified into following three categories: "Very good", "Good", and "Unsuitable". The BNN model-based results suggest that groundwater quality falls mostly in the range of "Good" to "Very good" except for some places near the Arabian Sea. The new modeling results powered by uncertainty and statistical analyses would provide useful constrain, which could be utilized in monitoring and assessment of the groundwater quality. PMID:22899457

  11. Mapping groundwater quality distinguishing geogenic and anthropogenic contribution using NBL

    NASA Astrophysics Data System (ADS)

    Preziosi, Elisabetta; Ducci, Daniela; Condesso de Melo, Maria Teresa; Parrone, Daniele; Sellerino, Mariangela; Ghergo, Stefano; Oliveira, Joana; Ribeiro, Luis

    2015-04-01

    Groundwaters are threatened by anthropic activities and pollution is interesting a large number of aquifers worldwide. Qualitative and quantitative monitoring is required to assess the status and track its evolution in time and space especially where anthropic pressures are stronger. Up to now, groundwater quality mapping has been performed separately from the assessment of its natural status, i.e. the definition of the natural background level of a particular element in a particular area or groundwater body. The natural background level (NBL) of a substance or element allows to distinguish anthropogenic pollution from contamination of natural origin in a population of groundwater samples. NBLs are the result of different atmospheric, geological, chemical and biological interaction processes during groundwater infiltration and circulation. There is an increasing need for the water managers to have sound indications on good quality groundwater exploitation. Indeed the extension of a groundwater body is often very large, in the order of tens or hundreds of square km. How to select a proper location for good quality groundwater abstraction is often limited to a question of facility for drilling (access, roads, authorizations, etc.) or at the most related to quantitative aspects driven by geophysical exploration (the most promising from a transmissibility point of view). So how to give indications to the administrators and water managers about the exploitation of good quality drinking water? In the case of anthropic contamination, how to define which area is to be restored and to which threshold (e.g. background level) should the concentration be lowered through the restoration measures? In the framework of a common project between research institutions in Italy (funded by CNR) and Portugal (funded by FCT), our objective is to establish a methodology aiming at merging together 1) the evaluation of NBL and 2) the need to take into account the drinking water standards

  12. Status and understanding of groundwater quality in the North San Francisco Bay groundwater basins, 2004

    USGS Publications Warehouse

    Kulongoski, Justin T.; Belitz, Kenneth; Landon, Matthew K.; Farrar, Christopher

    2010-01-01

    Groundwater quality in the approximately 1,000-square-mile (2,590-square-kilometer) North San Francisco Bay study unit was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is located in northern California in Marin, Napa, and Sonoma Counties. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The GAMA North San Francisco Bay study was designed to provide a spatially unbiased assessment of untreated groundwater quality in the primary aquifer systems. The assessment is based on water-quality and ancillary data collected by the USGS from 89 wells in 2004 and water-quality data from the California Department of Public Health (CDPH) database. The primary aquifer systems (hereinafter referred to as primary aquifers) were defined by the depth interval of the wells listed in the CDPH database for the North San Francisco Bay study unit. The quality of groundwater in shallower or deeper water-bearing zones may differ from that in the primary aquifers; shallower groundwater may be more vulnerable to surficial contamination. The first component of this study, the status of the current quality of the groundwater resource, was assessed by using data from samples analyzed for volatile organic compounds (VOC), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. This status assessment is intended to characterize the quality of groundwater resources within the primary aquifers of the North San Francisco Bay study unit, not the treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentration divided by the health- or aesthetic-based benchmark concentration) were used for evaluating groundwater quality for those constituents that have Federal and (or

  13. On Childhood and the Logic of Difference: Some Empirical Examples

    ERIC Educational Resources Information Center

    Dahlbeck, Johan

    2012-01-01

    This article argues that universal documents on children's rights can provide illustrative examples as to how childhood is identified as a unity using difference as an instrument. Using Gille Deleuze's theorising on difference and sameness as a framework, the article seeks to relate the children's rights project with a critique of representation.…

  14. Developing Transferable Skills: Some Examples from Geomorphology Teaching.

    ERIC Educational Resources Information Center

    Mottershead, Derek; Suggitt, Steve

    1996-01-01

    Demonstrates how the development of transferable skills can be promoted as a matter of policy in undergraduate geography programs and implemented throughout individual classes. Defines transferable skills as skills of a widely applicable nature independent of the disciplinary context. Presents two examples of transferable skill development in…

  15. Hydrogeochemistry and groundwater quality assessment along Wadi Al Showat, Khamis Mushiet District, Southwest Saudi Arabia

    NASA Astrophysics Data System (ADS)

    Alhumidan, S. M.; Alfaifi, H. J.; Ibrahim, E. K. E.; Abdel Rahman, K.

    2015-12-01

    In the present study, the hydrochemistry and geologic characteristics of the shallow groundwater aquifer along Wadi Al Showat, Khamis Mushiet District, Southwest Saudi Arabia was evaluated and assessed. Along this wadi the fractured/weathered basement rocks house significant quantity of groundwater that usually used by local people for agricultural and domestic purposes. Assessing and evaluation of the quality of the groundwater in such shallow aquifers is very important; especially the groundwater is generally occurred within the fractured basement rocks at shallow depths, thus exposing the groundwater to surface or near-surface contaminants is expected. For this purpose hydrochemical and biological analysis was conducted for 25 water samples collected from the available shallow dug wells along the studied wadi. The study reveals that the groundwater quality changed due to the agriculture and urbanization practices along the wadi. The effect of domestic waste water and septic tanks was obvious. In addition, the field investigation indicates that the basement rocks in the area is dissected by two main sets of fractures that oriented in the west-northwest and east-west directions. In some places, the basement rocks is intruded by coarse-grained, quartz-rich quartzite grained monzogranite, and pegmatite veins that have a coarse-grained weathering product, therefore, they tend to develop and preserve open joint systems between the granitic blocks. These fracturing system are important from the hydrogeological point of view, as they facilitate the storage, water flow movement through them and also facilitate the vertical infiltration of the surface pollutants. These results led to a better understanding of the groundwater characteristics that is important in groundwater management in the study area.

  16. Groundwater Quality Assessment for Waste Management Area U: First Determination

    SciTech Connect

    FN Hodges; CJ Chou

    2000-08-04

    Waste Management Area U (TWA U) is located in the 200 West Area of the Hanford Site. The area includes the U Tank Farm, which contains 16 single-shell tanks and their ancillary equipment and waste systems. WMA U is regulated under the Resource Conservation and Recovery Act of 1976 (RCRA) as stipulated in 40 CFR Part 265, Subpart F, which is incorporated into the Washington State dangerous waste regulations (WAC 173-303400) by reference. Groundwater monitoring at WMA U has been guided by an interim status indicator evaluation program. As a result of changes in the direction of groundwater flow, background values for the WMA have been recalculated several times during its monitoring history. The most recent recalculation revealed that one of the indicator parameters, specific conductance, exceeded its background value in downgradient well 299-W19-41. This triggered a change from detection monitoring to a groundwater quality assessment program. The major contributors to the higher specific conductance are nonhazardous constituents, such as bicarbonate, calcium, chloride, magnesium, sodium and sulfate. Chromium, nitrate, and technetium-99 are present and are increasing; however, they are significantly below their drinking water standards. The objective of this study is to determine whether the increased concentrations of chromium, nitrate, and technetium-99 in groundwater are from WMA U or from an upgradient source. Interpretation of groundwater monitoring data indicates that both the nonhazardous constituents causing elevated specific conductance in groundwater and the tank waste constituents present in groundwater at the WMA are a result of surface water infiltration in the southern portion of the WMA. There is evidence that both upgradient and WMA sources contribute to the nitrate concentrations that were detected. There is no indication of an upgradient source for the chromium and technetium-99 that was detected. Therefore, a source of contamination appears to

  17. Salinization of groundwater in arid and semi-arid zones: an example from Tajarak, western Iran

    NASA Astrophysics Data System (ADS)

    Jalali, Mohsen

    2007-06-01

    Study of the groundwater samples from Tajarak area, western Iran, was carried out in order to assess their chemical compositions and suitability for agricultural purposes. All of the groundwaters are grouped into two categories: relatively low mineralized of Ca-HCO3 and Na-HCO3 types and high mineralized waters of Na-SO4 and Na-Cl types. The chemical evolution of groundwater is primarily controlled by water-rock interactions mainly weathering of aluminosilicates, dissolution of carbonate minerals and cation exchange reactions. Calculated values of pCO2 for the groundwater samples range from 2.34 × 10-4 to 1.07 × 10-1 with a mean value of 1.41 × 10-2 (atm), which is above the pCO2 of the earth’s atmosphere (10-3.5). The groundwater is oversaturated with respect to calcite, aragonite and dolomite and undersaturated with respect to gypsum, anhydrite and halite. According to the EC and SAR the most dominant classes (C3-S1, C4-S1 and C4-S2) were found. With respect to adjusted SAR (adj SAR), the sodium (Na+) content in 90% of water samples in group A is regarded as low and can be used for irrigation in almost all soils with little danger of the development of harmful levels of exchangeable Na+, while in 40 and 37% of water samples in group B the intensity of problem is moderate and high, respectively. Such water, when used for irrigation will lead to cation exchange and Na+ is adsorbed on clay minerals while calcium (Ca2+) and magnesium (Mg2+) are released to the liquid phase. The salinity hazard is regarded as medium to high and special management for salinity control is required. Thus, the water quality for irrigation is low, providing the necessary drainage to avoid the build-up of toxic salt concentrations.

  18. Relationship of Shallow Groundwater Quality to Hydraulic Fracturing Activities in Antrim and Kalkaska Counties, MI

    NASA Astrophysics Data System (ADS)

    Stefansky, J. N.; Robertson, W. M.; Chappaz, A.; Babos, H.; Israel, S.; Groskreutz, L. M.

    2015-12-01

    Hydraulic fracturing (fracking) of oil and natural gas (O&G) wells is a widely applied technology that can increase yields from tight geologic formations. However, it is unclear how fracking may impact shallow groundwater; previous research into its effects has produced conflicting results. Much of the worry over potential impacts to water quality arises from concerns about the produced water. The water produced from O&G formations is often salty, contains toxic dissolved elements, and can be radioactive. If fracking activities cause or increase connectivity between O&G formations and overlying groundwater, there may be risks to aquifers. As one part of a groundwater quality study in Antrim and Kalkaska Counties, MI, samples were collected from the unconfined glacial aquifer (3-300 m thick) and produced water from the underlying Antrim formation, a shallow (180-670 m deep) natural gas producing black shale. Groundwater samples were collected between 200 to 10,000 m distance from producing Antrim gas wells and from a range of screened intervals (15-95 m). Samples were analyzed for major constituents (e.g., Br, Cl), pH, conductivity, and dissolved oxygen (DO). The specific conductance of groundwater samples ranged from 230-1020 μS/cm; DO ranged from 0.4-100% saturation. Preliminary results show a slight inverse correlation between specific conductance and proximity to producing Antrim wells. The observed range of DO saturation in glacial aquifer groundwater appears to be related to both screened depth of the water wells and proximity to Antrim wells. During sampling, some well owners expressed concerns about the effects of fracking on groundwater quality and reported odd smells and tastes in their water after O&G drilling occurred near their homes. The results of this study and reported observations provide evidence to suggest a potential hydrogeological connection between the Antrim formation and the overlying glacial aquifer in some locations; it also raises

  19. Effect of groundwater quality on sustainability of groundwater resource: A case study in the North China Plain.

    PubMed

    Wu, Ming; Wu, Jianfeng; Liu, Jie; Wu, Jichun; Zheng, Chunmiao

    2015-08-01

    The North China Plain (NCP) is one of the most severe water shortage areas in China. Due to the scarcity of surface water in the NCP, groundwater system is seriously over-exploited and use of nitrogen fertilizers is greatly increasing year by year to improve soil fertility and crop production, causing a variety of environmental issues in the processes of abstracting groundwater. Considering that previous research was limited on approaches to assess sustainability of groundwater through flow modeling and water level decline, this study focuses on addressing the implications of groundwater contaminant for water resource sustainability in the central part of NCP. Based on the previously developed groundwater flow model, a reaction modular code for the reactive transport in three-dimensional aquifers (RT3D) is developed for simulating the reactive process of nitrogen species transport in groundwater system. The management optimization model coupled with the nitrogen reactive transport model under consideration of water quality constraints is then conducted to quantify and improve the sustainability of groundwater utilization in the study area. Thus, the optimal pumping well locations and pumping rates that lead to the maximum total yield or the minimum total management costs subjecting to a series of groundwater level constraints are obtained from the optimization models. Compared with the optimization model without water quality constraints, this study could provide a more useful tool for developing cost-effective strategies for sustainable management of groundwater resource in the NCP, and greatly improve groundwater management level and water quality. PMID:26102477

  20. Groundwater quality assessment using geoelectrical and geochemical approaches: case study of Abi area, southeastern Nigeria

    NASA Astrophysics Data System (ADS)

    Ebong, Ebong D.; Akpan, Anthony E.; Emeka, Chimezie N.; Urang, Job G.

    2016-06-01

    The electrical resistivity technique which involved the Schlumberger depth sounding method and geochemical analyses of water samples collected from boreholes was used to investigate the suitability of groundwater aquifers in Abi for drinking and irrigation purposes. Fifty randomly located electrical resistivity data were collected, modeled, and interpreted after calibration with lithologic logs. Ten borehole water samples were collected and analysed to determine anion, cation concentrations and some physical and chemical parameters, such as water colour, temperature, total dissolved solids, and electrical conductivity. The results show that the lithostratigraphy of the study area is composed of sands, sandstones (fractured, consolidated and loosed), siltstones, shales (compacted and fractured) of the Asu River Group, Eze-Aku Formation which comprises the aquifer units, and the Nkporo Shale Formation. The aquifer conduits are known to be rich in silicate minerals, and the groundwater samples in some locations show a significant amount of Ca2+, Mg2+, and Na+. These cations balanced the consumption of H+ during the hydrolytic alteration of silicate minerals. The geochemical analysis of groundwater samples revealed dominant calcium-magnesium-carbonate-bicarbonate water facies. Irrigation water quality parameters, such as sodium absorption ratio, percentage of sodium, and permeability index, were calculated based on the physico-chemical analyses. The groundwater quality was observed to be influenced by the interaction of some geologic processes but was classified to be good to excellent, indicating its suitability for domestic and irrigation purposes.

  1. Groundwater age for identification of baseline groundwater quality and impacts of land-use intensification - The National Groundwater Monitoring Programme of New Zealand

    NASA Astrophysics Data System (ADS)

    Morgenstern, Uwe; Daughney, Christopher J.

    2012-08-01

    SummaryWe identified natural baseline groundwater quality and impacts caused by land use intensification by relating groundwater chemistry with water age. Tritium, the most direct tracer for groundwater dating, including the time of water passage through the unsaturated zone, was overwhelmed over the recent decades by contamination from bomb-tritium from nuclear weapons testing in the early 1960s. In the Southern Hemisphere, this situation has changed now with the fading of the bomb-tritium, and tritium has become a tool for accurate groundwater dating. Tritium dating will become efficient also in the Northern Hemisphere over the next decade. Plotting hydrochemistry and field parameters versus groundwater age allowed us to identify those parameters that have increasing concentrations with age and are therefore from geological sources. These indicators for natural groundwater evolution are: Na, HCO3, SiO2, F, PO4, the redox-sensitive elements and compounds Fe, Mn, NH4, CH4, and pH and conductivity. In young groundwater that was recharged after the intensification of agriculture, nitrate, sulphate, CFC-11 and CFC-12, and pesticides are the most representative indicators for the impact of land-use intensification on groundwater quality, with 66% of the sites showing such an impact. Elevated concentrations of nitrate in oxic groundwater allowed us to reconstruct the timing and magnitude of the impact of land-use intensification on groundwater which in New Zealand occurred in two stages. Old pristine groundwater reflects the natural baseline quality. A transition to slightly elevated concentration due to low-intensity land-use was observed in groundwater recharged since around 1880. A sharp increase in nitrate and other agrochemicals due to high-intensity agriculture was observed in groundwater recharged since 1955. The threshold concentrations that distinguish natural baseline quality water from low-intensity land-use water, and low-intensity from high intensity land

  2. Hydrogeochemical investigations and groundwater quality assessment of Torbat-Zaveh plain, Khorasan Razavi, Iran.

    PubMed

    Nematollahi, M J; Ebrahimi, P; Razmara, M; Ghasemi, A

    2016-01-01

    Hydrogeochemical investigations of groundwater in Torbat-Zaveh plain have been carried out to assess the water quality for drinking and irrigation purposes. In this study, 190 groundwater samples were collected and analyzed for physicochemical parameters and major ion concentrations. The abundance of major cations and anions was in the following order: Na(+) > Mg(2+) > Ca(2+) > K(+), and Cl(-) > [Formula: see text] > [Formula: see text] > [Formula: see text]. As a result, alkaline element (Na(+)) exceeds alkaline earth elements (Mg(2+) and Ca(2+)), and strong acids (Cl(-) and [Formula: see text]) dominate weak acids ([Formula: see text] and [Formula: see text]) in majority of the groundwater samples. Statistical analyses including Spearman correlation coefficients and factor analysis display good correlation between physicochemical parameters (EC, TDS and TH) and Na(+), Mg(2+), Ca(2+), Cl(-) and [Formula: see text]. The results display that rock-weathering interactions and ion-exchange processes play important role in controlling groundwater chemistry. Saturation index values also indicate that water chemistry is significantly affected by carbonate minerals such as calcite, aragonite and dolomite. US Salinity Laboratory(USSL) and Wilcox diagrams together with permeability index values reveal that most of the groundwater samples are suitable for irrigation purpose. However, in some regions, the water samples do not indicate required irrigational quality. PMID:26627207

  3. Calendar year 1994 groundwater quality report for the Bear Creek hydrogeologic regime, Y-12 Plant, Oak Ridge, Tennessee. 1994 Groundwater quality data interpretations and proposed program modifications

    SciTech Connect

    1995-10-01

    This groundwater quality report (GWQR) contains an evaluation of the groundwater quality data obtained during the 1994 calendar year (CY) at several hazardous and non-hazardous waste management facilities at the US Department of Energy (DOE) Y-12 Plant. These sites lie in Bear Creek Valley (BCV) west of the Y-12 Plant within the boundaries of the Bear Creek Hydrogeologic Regime which is one of three hydrogeologic regimes defined for the purposes of groundwater quality monitoring. The Environmental Management Department manages the groundwater monitoring activities under the auspices of the Y-12 Plant Groundwater Protection Program (GWPP). The purpose of the GWPP is to characterize the hydrogeology and to monitor groundwater quality at the Y-12 Plant and surrounding area to protect local groundwater resources. The annual GWQR for the Bear Creek Regime is completed in two parts. Part 1 consists primarily of data appendices and serves as a reference for the groundwater quality data obtained each CY. Part 2 (this report) contains an evaluation of the data with respect to regime-wide groundwater quality, summarizes the status and findings of ongoing hydrogeologic studies, describes changes in monitoring priorities, and presents planned modifications to the groundwater sampling and analysis activities.

  4. The Impact of Climate Change on Groundwater Resources and Groundwater Quality in the Patcham Catchment, England.

    NASA Astrophysics Data System (ADS)

    Phillips, R. J.; Smith, M.; Pope, D. J.; Gumm, L.

    2012-04-01

    The CLIMAWAT project is an EU-Regional Development Fund Interreg IV funded research programme to study the impacts of climate change on groundwater resources and groundwater quality from the Chalk aquifer of SE England. The use of partially treated wastewater for artificial recharge will also be extensively studied in both the field and laboratory. The Chalk is a major aquifer and regionally supplies 70% of potable water supplies. The long term sustainable use of this resource is of paramount importance and the outcomes of this project will better inform and enhance long term management strategies for this. Project partners include water companies, regulatory bodies and industry consultancies. The four main objectives of the CLIMAWAT project are: i) better improve the prediction of the impact of climate change on this groundwater resource; ii) better understand and quantify how recharge mechanisms will vary due to the uncertainty associated with climate change; iii) better understand the storage mechanisms and fate of contaminants (e.g. nitrates and pesticides) in this aquifer and iv) investigate the impact of using partially treated wastewater for artificial recharge. An extensive field monitoring and data collection programme is underway in the Patcham Catchment (SE of England). Simultaneous monitoring of climatic, unsaturated zone potentiometric, groundwater level and chemistry data will allow for a better understanding of how changes in recharge patterns will effect groundwater quality and quantity. Isoptopic analysis of sampled groundwaters has allowed for interpretations and a better understanding of the storage and movement of water through this aquifer. The laboratory experimental programme is also underway and the results from this will compliment the field based studies to further enhance the understanding of contaminant behaviour in the both unsaturated and saturated zones. Core experiments are being used to investigate how nutrient and other

  5. Groundwater quality in the San Diego Drainages Hydrogeologic Province, California

    USGS Publications Warehouse

    Wright, Michael T.; Belitz, Kenneth

    2011-01-01

    More than 40 percent of California's drinking water is from groundwater. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State's groundwater quality and increases public access to groundwater-quality information. The San Diego Drainages Hydrogeologic Province (hereinafter referred to as San Diego) is one of the study units being evaluated. The San Diego study unit is approximately 3,900 square miles and consists of the Temecula Valley, Warner Valley, and 12 other alluvial basins (California Department of Water Resources, 2003). The study unit also consists of all areas outside defined groundwater basins that are within 3 kilometers of a public-supply well. The study unit was separated, based primarily on hydrogeologic settings, into four study areas: Temecula Valley, Warner Valley, Alluvial Basins, and Hard Rock (Wright and others, 2005). The sampling density for the Hard Rock study area, which consists of areas outside of groundwater basins, was much lower than for the other study areas. Consequently, aquifer proportions for the Hard Rock study area are not used to calculate the aquifer proportions shown by the pie charts. An assessment of groundwater quality for the Hard Rock study area can be found in Wright and Belitz, 2011. The temperatures in the coastal part of the study unit are mild with dry summers, moist winters, and an average annual rainfall of about 10 inches. The temperatures in the mountainous eastern part of the study unit are cooler than in the coastal part, with an annual precipitation of about 45 inches that occurs mostly in the winter. The primary aquifers consist of Quaternary-age alluvium and weathered bedrock in the Temecula Valley, Warner Valley, and Alluvial Basins study areas, whereas in the Hard Rock study area the primary aquifers consist mainly of fractured and

  6. Quality of groundwater in the Denver Basin aquifer system, Colorado, 2003-5

    USGS Publications Warehouse

    Musgrove, MaryLynn; Beck, Jennifer A.; Paschke, Suzanne; Bauch, Nancy J.; Mashburn, Shana L.

    2014-01-01

    -reduction reactions, which are important processes affecting water quality. Major-ion chemistry generally evolved from a calcium-bicarbonate to calcium-sulfate composition, with some sodium-bicarbonate and sodium-sulfate facies in the deeper bedrock aquifers, likely resulting from longer residence times and more extensive water-rock interaction. Oxidation-reduction conditions generally evolved from oxic at the water table to anoxic with increasing depth in the bedrock aquifers. Most samples from the bedrock aquifers were anoxic. Exceedances of drinking-water standards and water-quality benchmarks for the bedrock aquifers occurred in 1 percent or less of samples for nitrate, selenium, or arsenic; there were no exceedances for uranium. Exceedances for total dissolved solids, sulfate, manganese, and iron were generally between about 10 and 20 percent for the bedrock-aquifer samples. Radon concentrations, which were only measured in samples collected from two of the bedrock aquifers, exceeded the lower proposed drinking-water standard for more than 90 percent of samples but exceeded the higher alternative standard for less than 5 percent of samples. Pesticide compounds and volatile organic compounds were detected in 3 and 22 percent, respectively, of bedrock-aquifer samples, all at concentrations that were that were much less than drinking-water standards. Water-quality data were synthesized to evaluate factors that affect spatial and depth variability in water quality and to assess aquifer vulnerability to contaminants from geologic materials and those of human origin. The quality of shallow groundwater in the alluvial aquifer and shallow bedrock aquifer system has been adversely affected by development of agricultural and urban areas. Land use has altered the pattern and composition of recharge. Increased recharge from irrigation water has mobilized dissolved constituents and increased concentrations in the shallow groundwater. Concentrations of most constituents associated with poor

  7. Effects of impurities on surface morphology: some examples

    NASA Astrophysics Data System (ADS)

    Hamouda, Ajmi BH; Stasevich, T. J.; Pimpinelli, Alberto; Einstein, T. L.

    2009-02-01

    Small amounts of impurities are known to have remarkably great influence on surface morphology. We discuss three examples that arise in our research. First, we consider impurities codeposited during epitaxial growth, paying particular attention to Cu(100). After many layers of growth, the impurities can dramatically alter the surface morphology, changing the wavelength of the meandering instability and producing small square-base pyramids. Second, we consider the decoration of both island and vacancy island edges on Ag(111) with C60. We use this system as a prototype to model how edge decoration with impurities can have a striking effect on the shape of the island as well as the dynamics of edge fluctuations. Finally, we show that about one per cent of pentacene quinone impurities alters the size of the critical nucleus in submonolayer pentacene deposition. This provides a platform on which to discuss our recent work characterizing the capture-zone distribution associated with the islands in terms of the generalized Wigner distribution, a simple one-parameter expression in which the characteristic exponent is the size of the smallest stable island.

  8. Examining the contradiction in 'sustainable urban growth': an example of groundwater sustainability

    USGS Publications Warehouse

    Zellner, Moira L.; Reeves, Howard W.

    2012-01-01

    The environmental planning literature proposes a set of 'best management practices' for urban development that assumes improvement in environmental quality as a result of specific urban patterns. These best management practices, however, often do not recognise finite biophysical limits and social impacts that urban patterns alone cannot overcome. To shed light on this debate, we explore the effects of different degrees of urban clustering on groundwater levels using a coupled land-use change and groundwater-flow model. Our simulations show that specific urban forms only slow down the impact on groundwater. As population increases, the pattern in which it is accommodated ceases to matter, and widespread depletion ensues. These results are predictable, yet current planning practice tends to take growth for granted and is reluctant to envision either no-growth scenarios or the prospect of depletion. We propose to use simulations such as those presented here to aid in policy discussions that allow decision makers to question the assumption of sustainable growth and suggest alternative forms of development.

  9. Some examples of image warping for low vision prosthesis

    NASA Technical Reports Server (NTRS)

    Juday, Richard D.; Loshin, David S.

    1988-01-01

    NASA has developed an image processor, the Programmable Remapper, for certain functions in machine vision. The Remapper performs a highly arbitrary geometric warping of an image at video rate. It might ultimately be shrunk to a size and cost that could allow its use in a low-vision prosthesis. Coordinate warpings have been developed for retinitis pigmentosa (tunnel vision) and for maculapathy (loss of central field) that are intended to make best use of the patient's remaining viable retina. The rationales and mathematics are presented for some warpings that we will try in clinical studies using the Remapper's prototype.

  10. Assessing groundwater quality for irrigation using indicator kriging method

    NASA Astrophysics Data System (ADS)

    Delbari, Masoomeh; Amiri, Meysam; Motlagh, Masoud Bahraini

    2014-09-01

    One of the key parameters influencing sprinkler irrigation performance is water quality. In this study, the spatial variability of groundwater quality parameters (EC, SAR, Na+, Cl-, HCO3 - and pH) was investigated by geostatistical methods and the most suitable areas for implementation of sprinkler irrigation systems in terms of water quality are determined. The study was performed in Fasa county of Fars province using 91 water samples. Results indicated that all parameters are moderately to strongly spatially correlated over the study area. The spatial distribution of pH and HCO3 - was mapped using ordinary kriging. The probability of concentrations of EC, SAR, Na+ and Cl- exceeding a threshold limit in groundwater was obtained using indicator kriging (IK). The experimental indicator semivariograms were often fitted well by a spherical model for SAR, EC, Na+ and Cl-. For HCO3 - and pH, an exponential model was fitted to the experimental semivariograms. Probability maps showed that the risk of EC, SAR, Na+ and Cl- exceeding the given critical threshold is higher in lower half of the study area. The most proper agricultural lands for sprinkler irrigation implementation were identified by evaluating all probability maps. The suitable areas for sprinkler irrigation design were determined to be 25,240 hectares, which is about 34 percent of total agricultural lands and are located in northern and eastern parts. Overall the results of this study showed that IK is an appropriate approach for risk assessment of groundwater pollution, which is useful for a proper groundwater resources management.

  11. Ancient-modern concordance in Ayurvedic plants: some examples.

    PubMed Central

    Dev, S

    1999-01-01

    Ayurveda is the ancient (before 2500 b.c.) Indian system of health care and longevity. It involves a holistic view of man, his health, and illness. Ayurvedic treatment of a disease consists of salubrious use of drugs, diets, and certain practices. Medicinal preparations are invariably complex mixtures, based mostly on plant products. Around 1,250 plants are currently used in various Ayurvedic preparations. Many Indian medicinal plants have come under scientific scrutiny since the middle of the nineteenth century, although in a sporadic fashion. The first significant contribution from Ayurvedic materia medica came with the isolation of the hypertensive alkaloid from the sarpagandha plant (Rouwolfia serpentina), valued in Ayurveda for the treatment of hypertension, insomnia, and insanity. This was the first important ancient-modern concordance in Ayurvedic plants. With the gradual coming of age of chemistry and biology, disciplines central to the study of biologic activities of natural products, many Ayurvedic plants have been reinvestigated. Our work on Commiphora wightti gum-resin, valued in Ayurveda for correcting lipid disorders, has been described in some detail; based on these investigations, a modern antihyperlipoproteinemic drug is on the market in India and some other countries. There has also been concordance for a few other Ayurvedic crude drugs such as Asparagus racemosus, Cedrus deodara, and Psoralea corylifolia. Images Figure 1 Figure 2 PMID:10504143

  12. Effects of variations in recharge on groundwater quality

    USGS Publications Warehouse

    Whittemore, D.O.; McGregor, K.M.; Marotz, G.A.

    1989-01-01

    The predominant regional effect of recharge on municipal groundwater quality in Kansas is the dilution of mineralized water in aquifers with relatively shallow water tables. The individual dissolved constituents contributing most to the water-quality variations are sulfate and chloride, and the calcium and sodium accompanying them, which are derived from the dissolution of evaporite minerals within the aquifer or from saline formation water in bedrock underlying the aquifer. The relationship between recharge and groundwater-quality variation can be quantified by associating certain climatic indices, especially the Palmer Drought Index, with quality observations. The response time of the maximum water-quality change relative to the occurrence of drought or substantial recharge ranges from a month to 3 years depending on the aquifer characteristics, and is generally proportional to the saturated thickness and specific yield. The response time is also affected by discharge to and recharge from nearby streams and by the well construction, particularly the placement of the screened interval, and pumping stress. ?? 1989.

  13. A proposed ground-water quality monitoring network for Idaho

    USGS Publications Warehouse

    Whitehead, R.L.; Parliman, D.J.

    1979-01-01

    A ground water quality monitoring network is proposed for Idaho. The network comprises 565 sites, 8 of which will require construction of new wells. Frequencies of sampling at the different sites are assigned at quarterly, semiannual, annual, and 5 years. Selected characteristics of the water will be monitored by both laboratory- and field-analysis methods. The network is designed to: (1) Enable water managers to keep abreast of the general quality of the State 's ground water, and (2) serve as a warning system for undesirable changes in ground-water quality. Data were compiled for hydrogeologic conditions, ground-water quality, cultural elements, and pollution sources. A ' hydrologic unit priority index ' is used to rank 84 hydrologic units (river basins or segments of river basins) of the State for monitoring according to pollution potential. Emphasis for selection of monitoring sites is placed on the 15 highest ranked units. The potential for pollution is greatest in areas of privately owned agricultural land. Other areas of pollution potential are residential development, mining and related processes, and hazardous waste disposal. Data are given for laboratory and field analyses, number of site visits, manpower, subsistence, and mileage, from which costs for implementing the network can be estimated. Suggestions are made for data storage and retrieval and for reporting changes in water quality. (Kosco-USGS)

  14. Some Examples Of Image Warping For Low Vision Prosthesis

    NASA Astrophysics Data System (ADS)

    Juday, Richard D.; Loshin, David S.

    1988-08-01

    NASA and Texas Instruments have developed an image processor, the Programmable Remapper 1, for certain functions in machine vision. The Remapper performs a highly arbitrary geometric warping of an image at video rate. It might ultimately be shrunk to a size and cost that could allow its use in a low-vision prosthesis. We have developed coordinate warpings for retinitis pigmentosa (tunnel vision) and for maculapathy (loss of central field) that are intended to make best use of the patient's remaining viable retina. The rationales and mathematics are presented for some warpings that we will try in clinical studies using the Remapper's prototype. (Recorded video imagery was shown at the conference for the maculapathy remapping.

  15. The effects of urbanization on groundwater quantity and quality in the Zahedan aquifer, southeast Iran

    USGS Publications Warehouse

    Khazaei, E.; Mackay, R.; Warner, J.W.

    2004-01-01

    This paper investigates the impacts of urban growth on groundwater quality and quantity in the Zahedan aquifer, which is the sole source of water supply for the city of Zahedan, Iran. The investigation is based on the collection of available historical data, supplemented by field and laboratory investigations. Groundwater levels in 40 wells were measured in December 2000. In addition, 102 water samples were taken in two periods during November and December 2000. Of these, 43 samples were analyzed for major ions, 32 samples were analyzed for nitrogen and phosphorus and the remainder for bacteriological contamination. The water level data show that there has been a general decline since 1977 due to over-abstraction. The magnitude of this decline has reached about 20 m in some places. However, in one area over the same period, a rise of about 3 m has been observed. This occurs as a result of the local hydrogeological conditions of shallow bedrock and relatively low permeability materials down stream of this area that limits the flow of groundwater towards the northeastern part of the aquifer. The general fall in groundwater levels has been accompanied by a change in the direction of the groundwater flow and an overall reduction of the areal extent of the saturated region of the aquifer. The city now has a serious problem such that even if the abstracted groundwater is rationed, water is not available for long periods because the demand far exceeds the supply. The heavy impact of urbanization on the groundwater quality is shown through the observed high nitrate (up to 295 mg/l as nitrate) and high phosphorus values (about 0.1 mg/l as P). Significant changes in the chloride concentration are also observed in two areas: increasing from 100 mg/l to 1,600 mg/l and from 2,000 mg/l to 4,000 mg/l, respectively. Furthermore, the bacteriological investigations show that 33 percent of the 27 collected groundwater samples are positive for total coliform and 11 percent of the

  16. Factors Controlling Submarine Groundwater Discharge: Examples from the Atlantic Coast, USA

    NASA Astrophysics Data System (ADS)

    Sanford, W. E.

    2011-12-01

    The quantity of fresh water discharging to the ocean affects water, solute, and nutrient budgets for coastal water systems around the world. Submarine groundwater discharge (SGD) has been observed in many locations, and global estimates of SGD by some researchers have suggested that the quantities may rival river discharge, especially in terms of the solute and nutrient discharges to coastal environments. Much of current research in recent years has focused on quantifying SGD at local sites using physical, chemical, and thermal tracer methods. These techniques tend to identify "hot spots" of SGD but do not tend to quantify fluxes in broad regions of low SGD, nor do they provide an explanation for the spatial variability of SGD. In this study, results are presented from regional coastal groundwater models of three locations along the Atlantic Coastal Plain of the United States. From this comparison the spatial and landform factors that control the quantity of SGD versus stream discharge at these sites are clearly identifiable. Two of the sites where SGD has been quantified through groundwater-flow models are along the eastern shoreline of the Chesapeake Bay in Maryland and Virginia. The third site is at Cape Cod, Massachusetts. Model results from the first location in Maryland indicate that only about 5 percent of its discharge to the bay is by SGD, whereas results from Virginia indicate about 25 percent there is by SGD. In contrast, the results from Cape Cod indicate about 65 percent of the discharge is by SGD. A comparison of these sites reveals that topographic relief and sediment permeability are the main controlling factors. In Maryland, relatively low topography and low sediment permeability cause most groundwater to discharge into stream networks before reaching the coastline, whereas in Virginia and Cape Cod higher topographic relief and permeability allow groundwater to travel mostly to the coastline before discharging. SGD is also predicted to be greater

  17. Groundwater quality of porous aquifers in Greece: a synoptic review

    NASA Astrophysics Data System (ADS)

    Daskalaki, P.; Voudouris, K.

    2008-04-01

    Greece is dependent on groundwater resources for its water supply. The main aquifers are within carbonate rocks (karstic aquifers) and coarse grained Neogene and Quaternary deposits (porous aquifers). The use of groundwater resources has become particularly intensive in coastal areas during the last decades with the intense urbanization, tourist development and irrigated land expansion. Sources of groundwater pollution are the seawater intrusion due to over-exploitation of coastal aquifers, the fertilizers from agricultural activities and the disposal of untreated wastewater in torrents or in old pumping wells. In the last decades the total abstractions from coastal aquifers exceed the natural recharge; so the aquifer systems are not used safely. Over-exploitation causes a negative water balance, triggering seawater intrusion. Seawater intrusion phenomena are recorded in coastal aquifer systems. Nitrate pollution is the second major source of groundwater degradation in many areas in Greece. The high levels of nitrate are probably the result of over-fertilization and the lack of sewage systems in some urban areas.

  18. Disequilibrium of uranium isotopes in some Syrian groundwater.

    PubMed

    Abdul-Hadi, A; Alhassanieh, O; Ghafar, M

    2001-07-01

    Uranium concentration in groundwater samples from three areas of Syria was determined using alpha-spectrometry and INAA. It was in the range of 0-6.13 microg/l in the phosphate areas, and lower than 1 ppb in the volcanic areas. The activity ratio of 234U/238U was investigated, and disequilibrium of uranium isotopes was found to occur (234U/238U = 0.52-2.02). The excess of 234U was calculated. This excess can be interpreted by higher mobility of 234U, which more readily forms the soluble (UO2)2+ ion in comparison with 238U, most of which remains in the insoluble 4+ state. This excess increases with increase in uranium concentration. Thorium concentration was measured using INAA, it was found to be in the rang 0-1.15 microg/l. PMID:11339524

  19. Groundwater Quality Modeling with a Small Data Set.

    PubMed

    Sakizadeh, Mohamad; Malian, Abbass; Ahmadpour, Eisa

    2016-01-01

    Seventeen groundwater quality variables collected during an 8-year period (2006 to 2013) in Andimeshk, Iran, were used to implement an artificial neural network (NN) with the purpose of constructing a water quality index (WQI). The method leading to the WQI avoids instabilities and overparameterization, two problems common when working with relatively small data sets. The groundwater quality variables used to construct the WQI were selected based on principal component analysis (PCA) by which the number of variables were decreased to six. To fulfill the goals of this study, the performance of three methods (1) bootstrap aggregation with early stopping; (2) noise injection; and (3) ensemble averaging with early stopping was compared. The criteria used for performance analysis was based on mean squared error (MSE) and coefficient of determination (R(2) ) of the test data set and the correlation coefficients between WQI targets and NN predictions. This study confirmed the importance of PCA for variable selection and dimensionality reduction to reduce the risk of overfitting. Ensemble averaging with early stopping proved to be the best performed method. Owing to its high coefficient of determination (R(2)  = 0.80) and correlation coefficient (r=0.91), we recommended ensemble averaging with early stopping as an accurate NN modeling procedure for water quality prediction in similar studies. PMID:25572437

  20. The vulnerability index calculation for determination of groundwater quality

    SciTech Connect

    Kurtz, D.A.; Parizek, R.R.

    1995-12-01

    Non-point source pollutants, such as pesticides, enter groundwater systems in a variety of means at wide-ranging concentrations. Risks in using groundwater in human consumption vary depending on the amounts of contaminants, the type of groundwater aquifer, and various use factors. We have devised a method of determining the vulnerability of an aquifer towards contamination with the Vulnerability Index. The Index can be used either as a comparative or an absolute index (comparative with a pure water source or aquifer spring or without comparison, assuming no peaks in the compared sample). Data for the calculation is obtained by extraction of a given water sample followed by analysis with a nitrogen/phosphorus detector on gas chromatography. The calculation uses the sum of peak heights as its determination. An additional peak number factor is added to emphasize higher numbers of compounds found in a given sample. Karst aquifers are considered to be highly vulnerable due to the large solution openings in its structure. Examples will be given of Vulnerability Indices taken from springs emanating from karst, intermediate, and diffuse flow aquifers taken at various times of the 1992 sampling year and compared with rainfall during that time. Comparisons will be made of the Index vs. rainfall events and vs. pesticide application data. The risk of using contaminated drinking water sources can be evaluated with the use of this index.

  1. Seawater Intrusion and groundwater quality of the coastal area in Tripoli region, Libya

    NASA Astrophysics Data System (ADS)

    Abdalla, Rashid; Rinder, Thomas; Dietzel, Martin; Leis, Albrecht

    2010-05-01

    In Libya groundwater is the main source of freshwater, providing a vital supplement to surface water sources. Groundwater availability and quality are however, vulnerable both to climate change and over-abstraction. In Libyan cities where the water table has lowered there has been a consequent impact on agricultural activities. Groundwater aquifers are either renewable or non-renewable. The renewable aquifers are those located in the north coastal strip with high precipitation rates. The large non-renewable sedimentary groundwater basins cover extensive areas in the central and southern parts of Libya and contribute large quantities of freshwater for local use, industrial and agricultural development. Seawater intrusion is a problem in the coastal areas of Libya. Most productive agricultural fields are in the northern coastal areas of the country where irrigation predominantly relies on groundwater. Seawater has moved inland because of heavy exploitation of the Miocene-Quaternary aquifer in order to meet the increasing water demand. The physical and chemical parameters of groundwater such as electrical conductivity, pH, temperature and individual ion content were determined. Most of the wells showed high values of electrical conductivity. The increase of water salinity is directly related to the extreme pumping of shallow coastal aquifers and movement of seawater towards inland. In some samples the increase of salinity corresponds to the ions abundant in seawater. In those solutions molar ratios of Cl/Br indicate influence of seawater intrusion. According to mixing calculations between fresh groundwater of the study area and Mediterranean seawater, the estimated concentration of seawater ranges from 10 to 15 wt%.

  2. Groundwater quality assessment for the Chestnut Ridge Hydrogeologic Regime at the Y-12 Plant. 1991 groundwater quality data and calculated rate of contaminant migration

    SciTech Connect

    Not Available

    1992-02-01

    This report contains groundwater quality data obtained during the 1991 calendar year at several hazardous and non-hazardous waste- management facilities associated with the US Department of Energy (DOE) Y-12 Plant (Figure 1). These sites are located south of the Y-12 Plant in the Chestnut Ridge Hydrogeologic Regime (CRHR), which is one of the three regimes defined for the purposes of groundwater quality monitoring and remediation (Figure 2). The Health, Safety, Environment, and Accountability (HSEA) Division of the Y-12 Plant Environmental Management Department manages the groundwater monitoring activities in each regime as part of the Y-12 Plant Groundwater Protection Program (GWPP).

  3. Mechanical Study on the Exploitation of Groundwater Resources in Crystalline Rocks - Examples of Hoping and Kinmen areas, Taiwan

    NASA Astrophysics Data System (ADS)

    WU, Z. W.; Yeh, E. C.; Chen, P. C.; Lin, C. K.; Lin, W.; Huang, S. Y.

    2015-12-01

    Intact crystalline rocks of low porosity possess lower water storage. Conversely, fractured crystalline rocks contain higher groundwater resources. Therefore, knowledge of distribution and characteristics of fractures is essential to the exploitation of groundwater resources in crystalline rocks. This research makes crystalline rocks in Hoping and Kinmen areas of Taiwan as examples to integrates previous studies of distribution and attitude of fractures and in-situ stress from surface survey and underground study for estimating the tendencies of slip and dilation of fractures in terms of geomechanics, understanding the characteristics of potential fluid conduits, and benefiting the exploitation and development of groundwater resources. The formations in downstream area of Hoping River contain late Paleozoic to Mesoic meta-granites and marbles, and few alluvium strata. Kinmen island closed to SE Chain is located in Pingtan-Dongshan Metamorphic Belt of Late Yanshan orogeny. The formations contain Mesozoic granite, gneiss, various dikes, and some alluviums. Previous studies had conducted experiments of anelastic strain recovery on retrieved cores in Hoping. The results show that the maximum principal stress is vertical and the horizontal minimum stress is in NE-SW orientation, indicating a normal faulting stress regime with NE-SW extension. Most fractures are in E-W and N-S orientations. Results of hydraulic fracturing experiments in Kinmen display the maximum and intermediate stress is in NW-SE orientation and vertical, respectively, suggesting strike-slip faulting regime with NE-SW extension. Most fractures are in E-W and NE-SW orientations and some are in other orientations. Because of various attitudes and distributions of fractures, origin of fluid conduits is not easy to investigate and predict. Based on in-situ stress data, strikes of predicted fluid conduits in Hoping area is N-S and NW-SE while in Kinmen area is in N-S. Analysis of well logging data and

  4. Temporal and spatial variation of groundwater in quantity and quality in sand dune at coastal region, Kamisu city, central Japan.

    NASA Astrophysics Data System (ADS)

    Umei, Yohei; Tsujimura, Maki; Sakakibara, Koichi; Watanabe, Yasuto; Minema, Motomitsu

    2016-04-01

    The role of groundwater in integrated water management has become important in recent 10 years, though the surface water is the major source of drinking water in Japan. Especially, it is remarked that groundwater recharge changed due to land cover change under the anthropogenic and climatic condition factors. Therefore, we need to investigate temporal and spatial variation of groundwater in quantity and quality focusing on the change during recent 10-20 years in specific region. We performed research on groundwater level and quality in sand dune at coastal region facing Pacific Ocean, Kamisu city, Ibaraki Prefecture, which have been facing environmental issues, such as land cover change due to soil mining for construction and urbanization. We compared the present situation of groundwater with that in 2000 using existed data to clarify the change of groundwater from 2000 to 2015. The quality of water is dominantly characterized by Ca2+-HCO3‑ in both 2000 and 2015, and nitrate was not observed in 2015, though it was detected in some locations in 2000. This may be caused by improvement of the domestic wastewater treatment. The topography of groundwater table was in parallel with that of ground surface in 2015, same as that in 2000. However, a depletion of groundwater table was observed in higher elevation area in 2015 as compared with that in 2000, and this area corresponds to the locations where the land cover has changed due to soil mining and urbanization between 2015 and 2000. In the region of soil mining, the original soil is generally replaced by impermeable soil after mining, and this may cause a decrease of percolation and net groundwater recharge, thus the depletion of groundwater table occurred after the soil mining.

  5. Surface water-groundwater exchange in transitional coastal environments by airborne electromagnetics: The Venice Lagoon example

    NASA Astrophysics Data System (ADS)

    Viezzoli, A.; Tosi, L.; Teatini, P.; Silvestri, S.

    2010-01-01

    A comprehensive investigation of the mixing between salt/fresh surficial water and groundwater in transitional environments is an issue of paramount importance considering the ecological, cultural, and socio-economic relevance of coastal zones. Acquiring information, which can improve the process understanding, is often logistically challenging, and generally expensive and slow in these areas. Here we investigate the capability of airborne electromagnetics (AEM) at the margin of the Venice Lagoon, Italy. The quasi-3D interpretation of the AEM outcome by the spatially constrained inversion (SCI) methodology allows us to accurately distinguish several hydrogeological features down to a depth of about 200 m. For example, the extent of the saltwater intrusion in coastal aquifers and the transition between the upper salt saturated and the underlying fresher sediments below the lagoon bottom are detected. The research highlights the AEM capability to improve the hydrogeological characterization of subsurface processes in worldwide lagoons, wetlands, deltas.

  6. Groundwater Quality Data in the Mojave Study Unit, 2008: Results from the California GAMA Program

    USGS Publications Warehouse

    Mathany, Timothy M.; Belitz, Kenneth

    2009-01-01

    ground water. In total, over 230 constituents and water-quality indicators (field parameters) were investigated. Three types of quality-control samples (blanks, replicates, and matrix spikes) each were collected at approximately 5-8 percent of the wells, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination was not a significant source of bias in the data for the groundwater samples. Differences between replicate samples generally were within acceptable ranges, indicating acceptable analytical reproducibility. Matrix spike recoveries were within acceptable ranges for most compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, untreated groundwater typically is treated, disinfected, or blended with other waters to maintain water quality. Regulatory thresholds apply to water that is served to the consumer, not to untreated ground water. However, to provide some context for the results, concentrations of constituents measured in the untreated ground water were compared with regulatory and non-regulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH) and thresholds established for aesthetic and technical concerns by CDPH. Comparisons between data collected for this study and thresholds for drinking-water are for illustrative purposes only, and are not indicative of compliance or non-compliance with those thresholds. Most constituents that were detected in groundwater samples in the 59 wells in MOJO were found at concentrations below drinking-water thresholds. In MOJO's 52 grid wells, volatile organic compounds (VOCs) were detected in 40 percent of the wells, and pesticides and pesticide degradates were detected in 23 percent of the grid wel

  7. Index of ground-water quality data for Florida

    USGS Publications Warehouse

    Seaber, P.R.; Williams, O.O.

    1985-01-01

    The Master Water Data Index of the U.S. Geological Survey contains records and information for 13,925 ground-water quality collection sites in Florida as follows: 2,180 active and 11,559 inactive well sites, and 39 active and 147 inactive spring sites. Ground-water quality data have been and are being collected at more sites in Florida than are other types of ground- and surface-water hydrologic data. Information available from the Master Water Data Index includes location (county, hydrologic unit, and latitude-longitude); reporting agency; agency identifying number; period and frequency of record; types of data (parameter sampled); and for wells, the principal aquifer sampled and well depth. This information may be retrieved, upon request, in a variety of formats. This report contains an index of the information available, not the actual water-quality data itself. The actual data may be obtained from the reporting agency that collected and stored the data. (USGS)

  8. Salinization process and coastal groundwater quality in Chaouia, Morocco

    NASA Astrophysics Data System (ADS)

    Najib, Saliha; Fadili, Ahmed; Mehdi, Khalid; Riss, Joëlle; Makan, Abdelhadi; Guessir, Hakima

    2016-03-01

    The coastal aquifer system of Chaouia is recognized as one of the most important aquifers in Morocco that is affected by salinization in the coastal fringe. The purpose of this study is to highlight the origin of salinization by sampling and analyzing groundwater from 44 wells for major elements. This study was carried out in May 2011. The results indicate that, in the central and downstream parts, the dominant facies are Mg2+, Na+ and Cl-, while Ca2+ and HCO3- dominate in the upstream zones. Ion exchange processes, under seawater intrusion, control the concentration of ions such as calcium, magnesium and sodium. Moreover, groundwater is oversaturated with respect to carbonate minerals (calcite and dolomite), and under-saturated with respect to evaporate minerals (gypsum, halite). The contribution of dissolved halite and gypsum in the groundwater mineralization is revealed by their positive correlation between (Na + Cl) and (Ca + SO4), respectively. Furthermore, the comparison of the hydrochemical results to drinking water quality standards by World Health Organization (2008) shows that more than a half of the water sampled is not suitable for drinking purposes, especially with respect to high levels of EC, TDS, Cl- and NO3-. In addition, high mineralization is found to be a consequence of seawater intrusion and anthropogenic activities.

  9. Hydrogeochemistry and Water Quality Index in the Assessment of Groundwater Quality for Drinking Uses.

    PubMed

    Batabyal, Asit Kumar; Chakraborty, Surajit

    2015-07-01

    The present investigation is aimed at understanding the hydrogeochemical parameters and development of a water quality index (WQI) to assess groundwater quality of a rural tract in the northwest of Bardhaman district of West Bengal, India. Groundwater occurs at shallow depths with the maximum flow moving southeast during pre-monsoon season and south in post-monsoon period. The physicochemical analysis of groundwater samples shows the major ions in the order of HCO3>Ca>Na>Mg>Cl>SO4 and HCO3>Ca>Mg>Na>Cl>SO4 in pre- and post-monsoon periods, respectively. The groundwater quality is safe for drinking, barring the elevated iron content in certain areas. Based on WQI values, groundwater falls into one of three categories: excellent water, good water, and poor water. The high value of WQI is because of elevated concentration of iron and chloride. The majority of the area is occupied by good water in pre-monsoon and poor water in post-monsoon period. PMID:26163496

  10. Application of water quality index for groundwater quality assessment: Thirumanimuttar sub-basin, Tamilnadu, India.

    PubMed

    Vasanthavigar, M; Srinivasamoorthy, K; Vijayaragavan, K; Ganthi, R Rajiv; Chidambaram, S; Anandhan, P; Manivannan, R; Vasudevan, S

    2010-12-01

    An attempt has been made to understand the hydrogeochemical parameters to develop water quality index in Thirumanimuttar sub-basin. A total of 148 groundwater samples were collected and analyzed for major cations and anions. The domination of cations and anions was in the order of Na>Mg>Ca>K for cations and Cl>HCO(3) >SO(4) in anions. The hydrogeochemical facies indicate alkalis (Na and K) exceed alkaline earths (Ca and Mg) and strong acids (Cl and SO(4)) exceed weak acid (HCO(3)). Water quality index rating was calculated to quantify overall water quality for human consumption. The PRM samples exhibit poor quality in greater percentage when compared with POM due to effective leaching of ions, over exploitation of groundwater, direct discharge of effluents and agricultural impact. The overlay of WQI with chloride and EC correspond to the same locations indicating the poor quality of groundwater in the study area. SAR, Na%, and TH were noted higher during both the seasons indicating most of the groundwater locations not suitable for irrigation purposes. PMID:20091344

  11. Groundwater Quality in the North San Francisco Bay Groundwater Basins, CA

    NASA Astrophysics Data System (ADS)

    Kulongoski, J. T.; Belitz, K.

    2010-12-01

    Groundwater quality in the ~2,600 km2 North San Francisco Bay groundwater basins was investigated as part of the Priority Basin Project of the GAMA Program, a collaboration of the California State Water Resources Control Board, U.S. Geological Survey and Lawrence Livermore National Laboratory. Samples from 96 wells and 1 hydrothermal spring were analyzed for water chemistry, isotopic abundances, and dissolved gases. The study, designed to provide a spatially unbiased assessment of untreated groundwater quality in the primary aquifer systems, was based on water-quality and ancillary data from 84 of the wells sampled and water-quality data from the California Department of Public Health (CDPH) database. The primary aquifers are defined as those parts of the aquifers corresponding to the perforated intervals of wells listed in the CDPH database. Inorganic constituents with human-health benchmarks were present at high concentrations in 14%, moderate in 35.8%, and low in 50.2% of the primary aquifers. Arsenic, boron, and lead were the trace elements that most frequently occurred at high concentrations. Fluoride is a minor element, and nitrate, a nutrient were present at high concentrations in ~1% of the primary aquifers. In contrast, organic constituents (one or more) with human-health benchmarks were present at high concentrations in 1.4%, moderate in 4.9%, and low in 93.7% (not detected in 64.8%) of the primary aquifers. The high proportion of organic constituents primarily reflected high concentrations of PCE (1.3%), TCE (0.1%), and 1,1-dichloroethene (0.1%). Of the 255 organic constituents analyzed for, 26 constituents were detected. Two organic constituents were frequently detected (detected in 10% or more of samples): the trihalomethane chloroform and the herbicide simazine, but both were detected at low concentrations. In this study, arsenic is the constituent which most frequently exists at high concentrations (about 10%) in the primary aquifers. Natural sources

  12. An Assessment of Peri-Urban Groundwater Quality from Shallow Dug Wells, Mzuzu, Malawi

    NASA Astrophysics Data System (ADS)

    Holm, R.; Felsot, A.

    2012-12-01

    Throughout Malawi, governmental, non-governmental, religious and civic organizations are targeting the human need for water. Diarrheal diseases, often associated with unsafe drinking water, are a leading cause of mortality in children under five in Malawi with over 6,000 deaths per year (World Health Organization, 2010). From January to March 2012, a field study was undertaken in Malawi to study water quality and develop a public health risk communication strategy. The region studied, Area 1B, represents a comparatively new peri-urban area on the edge of Mzuzu city. Area 1B is serviced by a piped municipal water supply, but many shallow dug wells are also used for household water. Groundwater samples were collected from 30 shallow dug well sites and analyzed for nitrate, total coliform, Escherichia coli, total hardness, total alkalinity and pH. In addition to water quality analyses, a structured household questionnaire was administered to address water use, sanitation, health, consumption patterns, and socioeconomics. Results showed that more than half of the groundwater samples would be considered of unacceptable quality based on World Health Organization (WHO) standards for E. coli contamination. Low levels of nitrate were found in groundwater, but only one well exceeded WHO standards. The structured questionnaire revealed that some residents were still consuming groundwater despite the access to safer municipal water. In general, the widespread E. coli contamination was not statistically correlated with well depth, latrine proximity, or surface features. Similarly, nitrate concentrations were not significantly correlated with proximity to latrines. On the other hand, nitrate was correlated with well depth, which is expected given the high potential for leaching of anionic highly water soluble compounds. E. coli was significantly correlated with nitrate concentration. Projects targeting the need for clean water need to recognize that households with access to a

  13. Effects of ground-water chemistry and flow on quality of drainflow in the western San Joaquin Valley, California

    USGS Publications Warehouse

    Fio, John L.; Leighton, David A.

    1994-01-01

    Chemical and geohydrologic data were used to assess the effects of regional ground-water flow on the quality of on-farm drainflows in a part of the western San Joaquin Valley, California. Shallow ground water beneath farm fields has been enriched in stable isotopes and salts by partial evaporation from the shallow water table and is being displaced by irrigation, drainage, and regional ground-water flow. Ground-water flow is primarily downward in the study area but can flow upward in some down- slope areas. Transitional areas exist between the downward and upward flow zones, where ground water can move substantial horizontal distances (0.3 to 3.6 kilometers) and can require 10 to 90 years to reach the downslope drainage systems. Simulation of ground-water flow to drainage systems indicates that regional ground water contributes to about 11 percent of annual drainflow. Selenium concentrations in ground water and drainwater are affected by geologic source materials, partial evaporation from a shallow water table, drainage-system, and regional ground-water flow. Temporal variability in drainflow quality is affected in part by the distribution of chemical constituents in ground water and the flow paths to the drainage systems. The mass flux of selenium in drainflows, or load, generally is proportional to flow, and reductions in drainflow quantity should reduce selenium loads over the short-term. Uncertain changes in the distribution of ground-water quality make future changes in drainflow quality difficult to quantify.

  14. Geochemical evolution of groundwater in southern Bengal Basin: The example of Rajarhat and adjoining areas, West Bengal, India

    NASA Astrophysics Data System (ADS)

    Sahu, Paulami; Sikdar, P. K.; Chakraborty, Surajit

    2016-02-01

    Detailed geochemical analysis of groundwater beneath 1223 km2 area in southern Bengal Basin along with statistical analysis on the chemical data was attempted, to develop a better understanding of the geochemical processes that control the groundwater evolution in the deltaic aquifer of the region. Groundwater is categorized into three types: `excellent', `good' and `poor' and seven hydrochemical facies are assigned to three broad types: `fresh', `mixed' and `brackish' waters. The `fresh' water type dominated with sodium indicates active flushing of the aquifer, whereas chloride-rich `brackish' groundwater represents freshening of modified connate water. The `mixed' type groundwater has possibly evolved due to hydraulic mixing of `fresh' and `brackish' waters. Enrichment of major ions in groundwater is due to weathering of feldspathic and ferro-magnesian minerals by percolating water. The groundwater of Rajarhat New Town (RNT) and adjacent areas in the north and southeast is contaminated with arsenic. Current-pumping may induce more arsenic to flow into the aquifers of RNT and Kolkata cities. Future large-scale pumping of groundwater beneath RNT can modify the hydrological system, which may transport arsenic and low quality water from adjacent aquifers to presently unpolluted aquifer.

  15. Calendar year 1993 groundwater quality report for the Chestnut Ridge Hydrogeologic Regime Y-12 Plant, Oak Ridge, Tennessee. 1993 Groundwater quality data interpretations and proposed program modifications

    SciTech Connect

    1994-09-01

    This groundwater quality report (GWQR) contains an evaluation of the groundwater quality data obtained during the 1993 calendar year (CY) at several hazardous and non-hazardous waste management facilities associated with the US DOE Y-12 Plant located on the DOE Oak Ridge Reservation (ORR) southeast of Oak Ridge, Tennessee. The groundwater quality data are presented in Part 1 of the GWQR submitted by Martin Marietta Energy Systems, Inc. to the Tennessee Department of Environment and Conservation (TDEC) in February 1994. Groundwater quality data evaluated in this report were obtained at several hazardous and non-hazardous waste management sites located within the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Chestnut Ridge Regime encompasses a section of Chestnut Ridge south of the Y-12 Plant and is one of three hydrogeologic regimes defined for the purposes of groundwater quality monitoring at the plant. The Environmental Management Department of the Y-12 Plant Health, Safety, Environment, and Accountability Organization manages the groundwater monitoring activities in each regime as part of the Y-12 Plant Groundwater Protection Program (GWPP). The annual GWQR for the Chestnut Ridge Regime is completed in two parts. Part 1 consists primarily of data appendices and serves as a reference for the groundwater quality data obtained each CY under the lead of the Y-12 Plant GWPP. Because it contains information needed to comply with Resource Conservation and Recovery Act (RCRA) interim status assessment monitoring and reporting requirements, the Part 1 GWQR is submitted to the TDEC by the RCRA reporting deadline (March 1 of the following CY). Part 2 (this report) contains an evaluation of the data with respect to regime-wide groundwater quality, presents the findings and status of ongoing hydrogeologic studies, describes changes in monitoring priorities, and presents planned modifications to the groundwater sampling and analysis activities.

  16. Groundwater seeps in Taylor Valley Antarctica: an example of a subsurface melt event

    NASA Astrophysics Data System (ADS)

    Lyons, W. Berry; Welch, Kathleen A.; Carey, Anne E.; Doran, Peter T.; Wall, Diana H.; Virginia, Ross A.; Fountain, Andrew G.; Csathó, Bea M.; Tremper, Catherine M.

    The 2001/02 austral summer was the warmest summer on record in Taylor Valley, Antarctica, (˜78° S) since continuous records of temperature began in 1985. The highest stream-flows ever recorded in the Onyx River, Wright Valley, were also recorded that year (the record goes back to the 1969/70 austral summer). In early January 2002, a groundwater seep was observed flowing in the southwest portion of Taylor Valley. This flow has been named 'Wormherder Creek' (WHC) and represents an unusual event, probably occurring on a decadal time-scale. The physical characteristics of this feature suggest that it may have flowed at other times in the past. Other groundwater seeps, emanating from the north-facing slope of Taylor Valley, were also observed. Little work has been done previously on these very ephemeral seeps, and the source of water is unknown. These features, resembling recently described features on Mars, represent the melting of subsurface ice. The Martian features have been interpreted as groundwater seeps. In this paper we compare the chemistry of the WHC groundwater seep to that of the surrounding streams that flow every austral summer. The total dissolved solids content of WHC was ˜6 times greater than that of some nearby streams. The Na : Cl and SO4 : Cl ratios of the seep waters are higher than those of the streams, but the Mg : Cl and HCO3 : Cl ratios are lower, indicating different sources of solutes to the seeps compared to the streams. The enrichment of Na and SO4 relative to Cl may suggest significant dissolution of mirabilite within the previously unwetted soil. The proposed occurrence of abundant mirabilite in higher-elevation soils of the dry valley region agrees with geochemical models developed, but not tested, in the late 1970s. The geochemical data demonstrate that these seeps could be important in 'rinsing' the soils by dissolving and redistributing the long-term accumulation of salts, and perhaps improving habitat suitability for soil biota

  17. Calendar year 1994 groundwater quality report for the Chestnut Ridge Hydrogeologic Regime, Y-12 Plant, Oak Ridge, Tennessee. 1994 groundwater quality data and calculated rate of contaminant migration

    SciTech Connect

    1995-02-01

    This annual groundwater quality report (GWQR) contains groundwater quality data obtained during the 1994 calendar year (CY) at several hazardous and non-hazardous waste-management facilities associated with the US Department of Energy (DOE) Y-12 Plant located on the DOE Oak Ridge Reservation (ORR) southeast of Oak Ridge, Tennessee (Figure 1). These sites are located south of the Y-12 Plant in the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime), which is one of three regimes defined for the purposes of groundwater quality monitoring at the Y- 12 Plant. The Environmental Management Department of the Y-12 Plant Health, Safety, Environment, and Accountability (HSEA) Organization manages the groundwater monitoring activities in each regime as part of the Y-12 Plant Groundwater Protection Program (GWPP). The GWQR for the Chestnut Ridge Regime is completed in two-parts: Part 1 (this report) containing the groundwater quality data and Part 2 containing a detailed evaluation of the data. The primary purpose of this report is to serve as a reference containing the groundwater quality data obtained each year under the lead of the Y-12 Plant GWPP. However, because it contains information needed to comply with Resource Conservation and Recovery Act (RCRA) interim status assessment monitoring and reporting requirements, this report is submitted to the Tennessee Department of Environment and Conservation (TDEC) by the RCRA reporting deadline (March 1 of the following CY). Part 2 of the annual groundwater report, to be issued mid-year, will contain a regime-wide evaluation of groundwater quality, present the findings and status of ongoing hydrogeologic studies, describe changes in monitoring priorities, and present planned modifications to the groundwater sampling and analysis activities.

  18. Groundwater Quality Protection in Oakland County: A Sourcebook for Teachers.

    ERIC Educational Resources Information Center

    East Michigan Environmental Action Council, Troy.

    This sourcebook consists of background information and activities related to groundwater protection. The first section focuses on the characteristics of groundwater, the water cycle, stormwater runoff, and uses of groundwater. The second section addresses household hazardous materials--both from a safety standpoint and a groundwater standpoint.…

  19. Multilevel factors affecting quality: examples from the cancer care continuum.

    PubMed

    Zapka, Jane; Taplin, Stephen H; Ganz, Patricia; Grunfeld, Eva; Sterba, Katherine

    2012-05-01

    The complex environmental context must be considered as we move forward to improve cancer care and, ultimately, patient and population outcomes. The cancer care continuum represents several care types, each of which includes multiple technical and communication steps and interfaces among patients, providers, and organizations. We use two case scenarios to 1) illustrate the variability, diversity, and interaction of factors from multiple levels that affect care quality and 2) discuss research implications and provide hypothetical examples of multilevel interventions. Each scenario includes a targeted literature review to illustrate contextual influences upon care and sets the stage for theory-informed interventions. The screening case highlights access issues in older women, and the survivorship case illustrates the multiple transition challenges faced by patients, families, and organizations. Example interventions show the potential gains of implementing intervention strategies that work synergistically at multiple levels. While research examining multilevel intervention is a priority, it presents numerous study design, measurement, and analytic challenges. PMID:22623591

  20. Current situation and regional characteristics of groundwater quality in central part of the Kanto Plain, Japan

    NASA Astrophysics Data System (ADS)

    Hachinohe, S.; Hamamoto, H.; Ishiyama, T.; Hayashi, T.; Miyakoshi, A.; Yasuhara, M.

    2012-12-01

    The Kanto Plain is known as the largest plain in Japan, where a lot of huge cities are located and about 30% of population of Japan is concentrated. In the inland part of the Kanto Plain, dependence on groundwater for water requirements is relatively high; in particular around 40% of the municipal water supply is dependent on groundwater. On the other hand, various kinds of controlled substances such as arsenic, nitrate and nitrite-nitrogen, volatile organic compounds are detected in groundwater in excess of the Japanese environmental standards. Therefore, in order to evaluate current situation and regional characteristics of groundwater quality in the central part of the Kanto Plain, we investigated around 500 wells. These wells are distributed throughout the plain area of Saitama Prefecture, stretching about 80 kilometers from east to west and about 60 kilometers from north to south. Depths of these wells range from 5m to 200m. We analyzed heavy metals and metalloids such as Fe, Mn, Al, As, Pb, using the ICP/AES and ICP/MS and also analyzed major dissolved ions such as Na+, K+, Mg2+, Ca2+, Cl-, SO42-, using the ion chromatograph. As a result of investigation, rate of samples exceeded the Japanese environmental standards of arsenic (0.01 mg/l) in groundwater was about 1%, and the maximum concentration was about 10 times of the environmental standards. Groundwater with a high arsenic concentration was detected in the specific area, such as in the lowlands located upstream from the former shoreline at the Holocene glacial retreat. Taking the land use of surrounding area, well depth and groundwater condition of aquifers into account, detected arsenic is considered to be of natural origin and mainly originate from natural layers. According to the previous studies, the release mechanisms of natural arsenic are summarized in some ways and in case of this research area, it was explained that natural arsenic is released with dissolution of the iron oxide in the reduction

  1. Prediction of Groundwater Quality Changes in Response to CO2 Leakage from Deep Geological Storage

    NASA Astrophysics Data System (ADS)

    Zheng, L.; Apps, J. A.; Zhang, Y.; Xu, T.; Birkholzer, J. T.

    2008-12-01

    If carbon dioxide stored in deep saline aquifers were to leak into overlying aquifer containing potable groundwater, the intruding CO2 would lower groundwater pH and could enhance the solubility of hazardous inorganic constituents present in the aquifer minerals. As an effort to evaluate risks associated with geologic sequestration of CO2, this work assesses these potential effects using reactive transport modeling. A systematic geochemical evaluation of more than 38,000 groundwater quality analyses from aquifers throughout the United States provided the prerequisites for reactive transport modeling. For example, galena (under reducing conditions) and cerussite (under oxidizing conditions) control aqueous Pb (lead) whereas arsenopyrite component in pyrite controls aqueous As (arsenic) generally under reducing conditions. Reactive transport simulations are performed which focus on the chemical evolution of Pb and As in the groundwater after the intrusion of CO2. The simulations use representative mineralogies for shallow potable aquifers in the USA and two measured mineralogies for deep confined aquifers. The resulting concentrations of Pb and As in the groundwater are then compared to the EPA specified health- based limits for drinking water. A significant increase of aqueous Pb and As occurs, although in most situations they remain below health-based limits. Sensitivity studies are also conducted for variation in hydrological, geochemical and mineralogical conditions and several critical parameters. The results indicate that aquifers containing more carbonate (through pH buffer) and clay minerals (by adsorption) are less vulnerable to CO2 intrusion. Adsorption/desorption from minerals surface significantly impact the mobilization of Pb and As. Adsorption dampens the effect of galena and arsenopyrite dissolution by removing Pb and As from aqueous phase under reducing conditions. Under oxidizing condition desorption is primarily responsible for increasing the

  2. 25 CFR 309.10 - What are some sample categories and examples of Indian products?

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 25 Indians 2 2011-04-01 2011-04-01 false What are some sample categories and examples of Indian products? 309.10 Section 309.10 Indians INDIAN ARTS AND CRAFTS BOARD, DEPARTMENT OF THE INTERIOR PROTECTION OF INDIAN ARTS AND CRAFTS PRODUCTS § 309.10 What are some sample categories and examples of Indian products? What constitutes an Indian...

  3. 25 CFR 309.10 - What are some sample categories and examples of Indian products?

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 25 Indians 2 2012-04-01 2012-04-01 false What are some sample categories and examples of Indian products? 309.10 Section 309.10 Indians INDIAN ARTS AND CRAFTS BOARD, DEPARTMENT OF THE INTERIOR PROTECTION OF INDIAN ARTS AND CRAFTS PRODUCTS § 309.10 What are some sample categories and examples of Indian products? What constitutes an Indian...

  4. 25 CFR 309.10 - What are some sample categories and examples of Indian products?

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 25 Indians 2 2013-04-01 2013-04-01 false What are some sample categories and examples of Indian products? 309.10 Section 309.10 Indians INDIAN ARTS AND CRAFTS BOARD, DEPARTMENT OF THE INTERIOR PROTECTION OF INDIAN ARTS AND CRAFTS PRODUCTS § 309.10 What are some sample categories and examples of Indian products? What constitutes an Indian...

  5. 25 CFR 309.10 - What are some sample categories and examples of Indian products?

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 25 Indians 2 2010-04-01 2010-04-01 false What are some sample categories and examples of Indian products? 309.10 Section 309.10 Indians INDIAN ARTS AND CRAFTS BOARD, DEPARTMENT OF THE INTERIOR PROTECTION OF INDIAN ARTS AND CRAFTS PRODUCTS § 309.10 What are some sample categories and examples of Indian products? What constitutes an Indian...

  6. 25 CFR 309.10 - What are some sample categories and examples of Indian products?

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 25 Indians 2 2014-04-01 2014-04-01 false What are some sample categories and examples of Indian products? 309.10 Section 309.10 Indians INDIAN ARTS AND CRAFTS BOARD, DEPARTMENT OF THE INTERIOR PROTECTION OF INDIAN ARTS AND CRAFTS PRODUCTS § 309.10 What are some sample categories and examples of Indian products? What constitutes an Indian...

  7. 36 CFR 51.39 - What are some examples of outfitter and guide concession contracts?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 36 Parks, Forests, and Public Property 1 2013-07-01 2013-07-01 false What are some examples of outfitter and guide concession contracts? 51.39 Section 51.39 Parks, Forests, and Public Property NATIONAL PARK SERVICE, DEPARTMENT OF THE INTERIOR CONCESSION CONTRACTS Determining a Preferred Offeror § 51.39 What are some examples of outfitter...

  8. 12 CFR 557.12 - What are some examples of preempted state laws affecting deposits?

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 12 Banks and Banking 5 2010-01-01 2010-01-01 false What are some examples of preempted state laws affecting deposits? 557.12 Section 557.12 Banks and Banking OFFICE OF THRIFT SUPERVISION, DEPARTMENT OF THE TREASURY DEPOSITS Deposit Activities of Federal Savings Associations § 557.12 What are some examples...

  9. 12 CFR 557.12 - What are some examples of preempted state laws affecting deposits?

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 12 Banks and Banking 6 2014-01-01 2012-01-01 true What are some examples of preempted state laws affecting deposits? 557.12 Section 557.12 Banks and Banking OFFICE OF THRIFT SUPERVISION, DEPARTMENT OF THE TREASURY DEPOSITS Deposit Activities of Federal Savings Associations § 557.12 What are some examples...

  10. Spatial variability analysis of combining the water quality and groundwater flow model to plan groundwater and surface water management in the Pingtung plain

    NASA Astrophysics Data System (ADS)

    Chen, Ching-Fang; Chen, Jui-Sheng; Jang, Cheng-Shin

    2014-05-01

    As a result of rapid economic growth in the Pingtung Plain, the use of groundwater resources has changed dramatically. The groundwater is quite rich in the Pingtung plain and the most important water sources. During the several decades, a substantial amount of groundwater has been pumped for the drinking, irrigation and aquaculture water supplies. However, because the sustainable use concept of groundwater resources is lack, excessive pumping of groundwater causes the occurrence of serious land subsidence and sea water intrusion. Thus, the management and conservation of groundwater resources in the Pingtung plain are considerably critical. This study aims to assess the conjunct use effect of groundwater and surface water in the Pingtung plain on recharge by reducing the amount of groundwater extraction. The groundwater quality variability and groundwater flow models are combined to spatially analyze potential zones of groundwater used for multi-purpose in the Pingtung Plain. First, multivariate indicator kriging (MVIK) is used to analyze spatial variability of groundwater quality based on drinking, aquaculture and irrigation water quality standards, and probabilistically delineate suitable zones in the study area. Then, the groundwater flow model, Processing MODFLOW (PMWIN), is adopted to simulate groundwater flow. The groundwater flow model must be conducted by the calibration and verification processes, and the regional groundwater recovery is discussed when specified water rights are replaced by surface water in the Pingtung plain. Finally, the most suitable zones of reducing groundwater use are determined for multi-purpose according to combining groundwater quality and quantity. The study results can establish a sound and low-impact management plan of groundwater resources utilization for the multi-purpose groundwater use, and prevent decreasing ground water tables, and the occurrence of land subsidence and sea water intrusion in the Pingtung plain.

  11. Resistance absorption of some groundwater tracers in porous media

    NASA Astrophysics Data System (ADS)

    Jafari, Fateme

    2010-05-01

    Absorption of tracer to the aquifer material is among the most important factors which should be considered when a tracing program is considered. In this study, the absorption of the tracer into the porous media is analyzed experimentally for some of the most important and applied tracers as uranine, rhodamine B, eosin, potassium permanganate, sodium chloride and potassium chloride. For each tracer, effect of initial tracer concentration and percentage of fine grain sediments on tracer absorption in porous media is analyzed. According to the final results, rhodamine B and potassium permanganate have the less resistance against absorption to aquifer material, whilst eosin and uranine are the most resistant tracers among the examined ones. Key Words: Tracer, Absorption, Aquifer, Column Method

  12. Groundwater quality in the Genesee River Basin, New York, 2010

    USGS Publications Warehouse

    Reddy, James E.

    2012-01-01

    Water samples collected from eight production wells and eight private residential wells in the Genesee River Basin from September through December 2010 were analyzed to characterize the groundwater quality in the basin. Eight of the wells were completed in sand and gravel aquifers, and eight were finished in bedrock aquifers. Three of the 16 wells were sampled in the first Genesee River Basin study during 2005-2006. Water samples from the 2010 study were analyzed for 147 physiochemical properties and constituents that included major ions, nutrients, trace elements, radionuclides, pesticides, volatile organic compounds (VOCs), and indicator bacteria. Results of the water-quality analyses are presented in tabular form for individual wells, and summary statistics for specific constituents are presented by aquifer type. The results are compared with Federal and New York State drinking-water standards, which typically are identical. The results indicate that groundwater generally is of acceptable quality, although concentrations of the following constituents exceeded current or proposed Federal or New York State drinking-water standards at each of the 16 wells sampled: color (one sample), sodium (three samples), sulfate (three samples), total dissolved solids (four samples), aluminum (one sample), arsenic (two samples), copper (one sample), iron (nine samples), manganese (eight samples), radon-222 (nine samples), and total coliform bacteria (six samples). Existing drinking-water standards for pH, chloride, fluoride, nitrate, nitrite, antimony, barium, beryllium, cadmium, chromium, lead, mercury, selenium, silver, thallium, zinc, gross alpha radioactivity, uranium, fecal coliform, Escherichia coli, and heterotrophic bacteria were not exceeded in any of the samples collected. None of the pesticides and VOCs analyzed exceeded existing drinking-water standards.

  13. Impact of a grout curtain on groundwater regime in karst: the example of the Ðale reservoir (Croatia)

    NASA Astrophysics Data System (ADS)

    Bonacci, Ognjen; Roje-Bonacci, Tanja

    2010-05-01

    Construction of grout curtains in karst terrains is primarily connected with dams and reservoirs. Their role is to increase watertightness and prevent progressive erosion. In this presentation hourly continuous measurement of groundwater level in two deep piezometers near the Đale reservoir is analysed. The Đale reservoir in the Cetina River began operation in 1989. The total length of the grout curtain is 3.9 km. It spreads 120 m bellow the Đale dam. First analysed piezometer A is drilled in the interior part of the system, between the reservoir and the grout curtain, while the second one B is located in its external part. Distance between them is 200 m. In natural conditions, prior the grout curtain construction, groundwater level fluctuation in both of them was similar (practically the same). Construction of the grout curtain extremely changed groundwater behaviour in each of them. During the six month of continuous monitoring, differences between groundwater levels in them range between +19.86 m (groundwater in B is lower than in A) and -12.77 m (groundwater in A is lower than in B). During the 77% of analysed period the groundwater level in interior piezometer A is higher than the groundwater level in external piezometer B. In other 23% of analysed period the groundwater level in outside piezometer B is higher than in inside A. The construction of the grout curtain caused unnaturally high hydrostatic gradients, which can accelerate the dissolutional expansion of karst fractures. As a result, unbearable leakage of the reservoir Đale can occur over its lifetime. Careful analyses of groundwater level behaviour discover some other very important characteristics of karst underground morphology.

  14. Regional monitoring of temporal changes in groundwater quality

    NASA Astrophysics Data System (ADS)

    Broers, Hans Peter; van der Grift, Bas

    2004-08-01

    Changes in agricultural practices are expected to affect groundwater quality by changing the loads of nutrients and salts in recharging groundwater, but regional monitoring networks installed to register the changes often fail to detect them and interpretation of trend analysis results is difficult. This study aims to improve the detection and understanding of groundwater quality changes with time, combining time series information, concentration-depth profiles, age dating and concentration-depth prognoses based on the historical inputs of solutes. For trend detection, a combination of trend analysis on time series at specific depths and time-averaged concentration-depth profiles was used. To reveal trends that have become obscured by chemical reactions, additional conditionally conservative indicators were introduced that are insensitive to those reactions under specific conditions. Detected trends were matched with prognoses of conservative and reactive transport to aid the understanding of trends. Data of the regional networks in 2 area-types with intensive livestock farming in the Dutch province of Noord-Brabant were used to illustrate the approach. The downward movement of the agricultural pollution front was demonstrated for the 2 area-types. However, many targeted contaminants have become retarded or delayed and quality changes were hard to detect for many reactive solutes, including nitrate. Pollution fronts of these targeted chemical components are still limited to the first 15 m of the subsoil. At deeper level, about 20-25 m, the effects of agricultural pollution and acidification were indicated by chemical indicators that have not been considered by others: oxidation capacity, the sum of cations and chloride. Increasing trends of the conditionally conservative indicators 'oxidation capacity' and 'sum of cations' were found at a depth of 18-25 m below surface. Increasing trends for potassium were found at shallower depth (7-13 m), which is explained by

  15. Fluor Hanford, Inc. Groundwater and Technical Integration Support (Master Project) Quality Assurance Management Plan

    SciTech Connect

    Fix, N. J.

    2008-02-20

    The scope of the Fluor Hanford, Inc. Groundwater and Technical Integration Support (Master Project) is to provide technical and integration support to Fluor Hanford, Inc., including operable unit investigations at 300-FF-5 and other groundwater operable units, strategic integration, technical integration and assessments, remediation decision support, and science and technology. This Quality Assurance Management Plan provides the quality assurance requirements and processes that will be followed by the Fluor Hanford, Inc. Groundwater and Technical Integration Support (Master Project).

  16. Ground-Water Quality in Western New York, 2006

    USGS Publications Warehouse

    Eckhardt, David A.V.; Reddy, James E.; Tamulonis, Kathryn L.

    2008-01-01

    Water samples were collected from 7 production wells and 26 private residential wells in western New York from August through December 2006 and analyzed to characterize the chemical quality of ground water. Wells at 15 of the sites were screened in sand and gravel aquifers, and 18 were finished in bedrock aquifers. The wells were selected to represent areas of greatest ground-water use and to provide a geographical sampling from the 5,340-square-mile study area. Samples were analyzed for 5 physical properties and 219 constituents that included nutrients, major inorganic ions, trace elements, radionuclides, pesticides, volatile organic compounds (VOC), phenolic compounds, organic carbon, and bacteria. Results indicate that ground water used for drinking supply is generally of acceptable quality, although concentrations of some constituents or bacteria exceeded at least one drinking-water standard at 27 of the 33 wells. The cations that were detected in the highest concentrations were calcium, magnesium, and sodium; anions that were detected in the highest concentrations were bicarbonate, chloride, and sulfate. The predominant nutrients were nitrate and ammonia; nitrate concentrations were higher in samples from sand and gravel aquifers than in samples from bedrock. The trace elements barium, boron, copper, lithium, nickel, and strontium were detected in every sample; the trace elements with the highest concentrations were barium, boron, iron, lithium, manganese, and strontium. Eighteen pesticides, including 9 pesticide degradates, were detected in water from 14 of the 33 wells, but none of the concentrations exceeded State or Federal Maximum Contaminant Levels (MCLs). Fourteen volatile organic compounds were detected in water from 12 of the 33 wells, but none of the concentrations exceeded MCLs. Eight chemical analytes and three types of bacteria were detected in concentrations that exceeded Federal and State drinking-water standards, which are typically identical

  17. Ground-water quality, Cook Inlet Basin, Alaska, 1999

    USGS Publications Warehouse

    Glass, Roy L.

    2001-01-01

    As part of the U.S. Geological Survey?s National Water-Quality Assessment Program, ground-water samples were collected from 34 existing wells in the Cook Inlet Basin in south-central Alaska during 1999. All ground-water samples were from aquifers composed of glacial or alluvial sediments. The water samples were used to determine the occurrence and distribution of selected major ions, nutrients, trace elements, volatile organic compounds, pesticides, radioisotopes, and environmental isotopes. Of 34 samples, 29 were from wells chosen by using a grid-based random-selection process. Water samples from five major public-supply wells also were collected. Radon-222 and arsenic concentrations exceeded drinking-water standards proposed by the U.S. Environmental Protection Agency in 39 and 18 percent of sampled wells, respectively. The highest radon concentration measured during this study was 610 picocuries per liter; 12 of 31 samples exceeded the proposed maximum contaminant level of 300 picocuries per liter. The highest arsenic concentration was 29 micrograms per liter; 6 of 34 samples exceeded the proposed maximum contaminant level of 10 micrograms per liter. Human activities may be increasing the concen- tration of nitrate in ground water, but nitrate concentrations in all samples were less than the maximum contaminant level of 10 milligrams per liter as nitrogen. Concentrations of nitrate were highest in Anchorage and were as great as 4.8 milligrams per liter as nitrogen. Dissolved-solids concentrations ranged from 77 to 986 milligrams per liter; only 2 of 34 wells yielded water having greater than 500 milligrams per liter. Iron and manganese concentrations exceeded secondary maximum contaminant levels in 18 and 42 percent of samples, respectively. Concentrations of all pesticides and volatile organic compounds detected in ground-water samples were very low, less than 1 microgram per liter. No pesticide or volatile organic compounds were detected at concentrations

  18. Groundwater quality assessment for the Bear Creek Hydrogeologic Regime at the Y-12 Plant: 1991 groundwater quality data and calculated rate of contaminant migration

    SciTech Connect

    Not Available

    1992-02-01

    The report contains groundwater and surface water quality data obtained during the 1991 calendar year at several hazardous and non- hazardous waste management facilities associated with the US Department of Energy (DOE) Y-12 Plant (Figure 1). These sites are southwest of the Y-12 Plant complex within the Bear Creek Hydrogeologic Regime (BCHR), which is one of three regimes defined for the purposes of groundwater and surface-water quality monitoring and remediation (Figure 2). The Environmental Management Department of the Y-12 Plant Health, Safety, Environment, and Accountability (HSEA) Division manages the monitoring activities in each regime as part of the Y-12 Plant Groundwater Protection Program (GWPP).

  19. Assessment of groundwater quality in Puri City, India: an impact of anthropogenic activities.

    PubMed

    Vijay, Ritesh; Khobragade, Puja; Mohapatra, P K

    2011-06-01

    Puri City is situated on the east coast of India and receives water supply only from the groundwater sources demarcated as water fields. The objective of this paper is to assess and evaluate the groundwater quality due to impact of anthropogenic activities in the city. Groundwater samples were collected from the water fields, hand pumps, open wells, and open water bodies during post-monsoon 2006 and summer 2007. Groundwater quality was evaluated with drinking water standards as prescribed by Bureau of Indian Standards and Environmental Protection Agency to assess the suitability. The study indicated seasonal variation of water-quality parameters within the water fields and city area. Groundwater in the water fields was found to be suitable for drinking after disinfection. While in city area, groundwater quality was impacted by onsite sanitary conditions. The study revealed that groundwater quality was deteriorated due to the discharge of effluent from septic tanks, soak pits, pit latrines, discharges of domestic wastewater in leaky drains, and leachate from solid waste dumpsite. Based on observed groundwater quality, various mitigation measures were suggested to protect the water fields and further groundwater contamination in the city. PMID:20714928

  20. Principles and problems of environmental pollution of groundwater resources with case examples from developing countries.

    PubMed Central

    Egboka, B C; Nwankwor, G I; Orajaka, I P; Ejiofor, A O

    1989-01-01

    The principles and problems of environmental pollution and contamination are outlined. Emphasis is given to case examples from developing countries of Africa, Asia, and Latin America with a comparative analysis to developed countries. The problems of pollution/contamination are widespread in developed countries but are gradually spreading from the urban to rural areas in the developing countries. Great efforts in research and control programs to check pollution-loading into the environment have been made in the industrialized countries, but only negligible actions have been taken in developing countries. Pollutants emanate from both point and distributed sources and have adversely affected both surface water and groundwaters. The influences of the geologic and hydrologic cycles that exacerbate the incidences of pollution/contamination have not been well understood by environmental planners and managers. Professionals in the different areas of pollution control projects, particularly in developing countries, lack the integrated multiobjective approaches and techniques in problem solving. Such countries as Nigeria, Kenya, Brazil, and India are now menaced by pollution hazards. Appropriate methods of control are hereby suggested. PMID:2695325

  1. Principles and problems of environmental pollution of groundwater resources with case examples from developing countries

    SciTech Connect

    Egboka, B.C.E.; Orajaka, I.P.; Ejiofor, A.O. ); Nwankwor, G.I. )

    1989-11-01

    The principles and problems of environmental pollution and contamination are outlined. Emphasis is given to case examples from developing countries of Africa, Asia, and Latin America with a comparative analysis to developed countries. The problems of pollution/contamination are widespread in developed countries but are gradually spreading from the urban to rural areas in the developing countries. Great efforts in research and control programs to check pollution-loading into the environment have been made in the industrialized countries, but only negligible actions have been taken in developing countries. Pollutants emanate from both point and distributed sources and have adversely affected both surface water and groundwaters. The influences of the geologic and hydrologic cycles that exacerbate the incidences of pollution/contamination have not been well understood by environmental planners and managers. Professionals in the different areas of pollution control projects, particularly in developing countries, lack the integrated multiobjective approaches and techniques in problem solving. Such countries as Nigeria, Kenya, Brazil, and India are now menaced by pollution hazards. Appropriate methods of control are hereby suggested.

  2. Groundwater-Quality Data in the Madera-Chowchilla Study Unit, 2008: Results from the California GAMA Program

    USGS Publications Warehouse

    Shelton, Jennifer L.; Fram, Miranda S.; Belitz, Kenneth

    2009-01-01

    , oxygen, and carbon, and activities of tritium and carbon-14), and dissolved noble gases also were measured to help identify the sources and ages of the sampled groundwater. In total, approximately 300 constituents and field water-quality indicators were investigated. Three types of quality-control samples (blanks, replicates, and samples for matrix spikes) each were collected at approximately 11 percent of the wells sampled for each analysis, and the results obtained from these samples were used to evaluate the quality of the data for the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that data for the groundwater samples were not compromised by possible contamination during sample collection, handling or analysis. Differences between replicate samples were within acceptable ranges. Matrix spike recoveries were within acceptable ranges for most compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, raw groundwater typically is treated, disinfected, or blended with other waters to maintain water quality. Regulatory thresholds apply to water that is served to the consumer, not to raw groundwater. However, to provide some context for the results, concentrations of constituents measured in the raw groundwater were compared with regulatory and non-regulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and the California Department of Public Health (CDPH), and with aesthetic and technical thresholds established by CDPH. Comparisons between data collected for this study and drinking-water thresholds are for illustrative purposes only, and are not indicative of compliance or non-compliance with regulatory thresholds. The concentrations of most constituents detected in groundwater samples from MADCHOW wells were below drinking-water thresholds. Organic compounds (VOCs and pesticides

  3. Influence of animal waste disposal pits on groundwater quality

    NASA Astrophysics Data System (ADS)

    Lee, Seongwon; Hosaka, Akiko; Tase, Norio

    Since the implementation of the Law on Promoting Proper Management and Use of Livestock Excreta in 1999, the number of the farmers that do not meet the management criteria is on the decline. However, there is a possibility that many of the animal waste disposal pits that have been either abandoned or refilled according to the law have been the potential contamination source. In this study, we discussed the impacts of the abandoned disposal pits to groundwater quality. The results showed that high concentrations of nitrate (above 100mg/L) were observed in the downstream of the disposal pits. It suggests that the abandoned animal waste disposal pits have been the potential pollution source even after the period of 15 years since the termination of use. Implementation of immediate countermeasure is necessary because the animal waste disposal pits are the long-term-sources of high levels of nitrate.

  4. An investigation of shallow ground-water quality near East Fork Poplar Creek, Oak Ridge, Tennessee

    USGS Publications Warehouse

    Carmichael, J.K.

    1989-01-01

    Alluvial soils of the flood plain of East Fork Poplar Creek in Oak Ridge, Tennessee, are contaminated with mercury and other metals, organic compounds, and radio-nuclides originating from the Y-12 Plant, a nuclear-processing facility located within the U.S. Department of Energy 's Oak Ridge Reservation. Observation wells were installed in the shallow aquifer of the flood plain, and water quality samples were collected to determine if contaminants are present in the shallow groundwater. Groundwater in the shallow aquifer occurs under water-table conditions. Recharge is primarily from precipitation and discharge is to East Fork Poplar Creek. Groundwater levels fluctuate seasonally in response to variations in recharge and evapotranspiration. During extremely dry periods, the water table drops below the base of the shallow aquifer in some flood-plain areas. Contaminants found in water samples from several of the wells in concentrations which equaled or exceeded drinking-water standards established by the U.S. Environmental Protection Agency are antimony, chromium, lead, mercury, selenium, phenols, and strontium-90. Total and dissolved uranium concentrations exceeded the analytical detection limit in nearly 70% of the wells in the flood plain. The results of water quality determinations demonstrate that elevated concentrations of most trace metals (and possibly organic compounds and radionuclides) were caused by contaminated sediments in the samples. The presence of contaminated sediment in samples is suspected to be the result of borehole contamination during well installation. (USGS)

  5. Permeable Adsorptive Barrier (PAB) for the remediation of groundwater simultaneously contaminated by some chlorinated organic compounds.

    PubMed

    Erto, A; Bortone, I; Di Nardo, A; Di Natale, M; Musmarra, D

    2014-07-01

    In this paper, a Permeable Reactive Barrier (PRB) made with activated carbon, namely a Permeable Adsorptive Barrier (PAB), is put forward as an effective technique for the remediation of aquifers simultaneously contaminated by some chlorinated organic compounds. A design procedure, based on a computer code and including different routines, is presented as a tool to accurately describe mass transport within the aquifer and adsorption/desorption phenomena occurring inside the barrier. The remediation of a contaminated aquifer near a solid waste landfill in the district of Napoli (Italy), where Tetrachloroethylene (PCE) and Trichloroethylene (TCE) are simultaneously present, is considered as a case study. A complete hydrological and geotechnical site characterization, as well as a number of dedicated adsorption laboratory tests for the determination of activated carbon PCE/TCE adsorption capacity in binary systems, are carried out to support the barrier design. By means of a series of numerical simulations it is possible to determine the optimal barrier location, orientation and dimensions. PABs appear to be an effective remediation tool for the in-situ treatment of an aquifer contaminated by PCE and TCE simultaneously, as the concentration of both compounds flowing out of the barrier is everywhere lower than the regulatory limits on groundwater quality. PMID:24747934

  6. Groundwater quality in the Madera and Chowchilla subbasins of the San Joaquin Valley, California

    USGS Publications Warehouse

    Shelton, Jennifer L.; Fram, Miranda S.; Belitz, Kenneth

    2013-01-01

    Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s untreated groundwater quality and increases public access to groundwater-quality information. The Madera and Chowchilla subbasins of the San Joaquin Valley constitute one of the study units being evaluated. The Madera-Chowchilla study unit is about 860 square miles and consists of the Madera and Chowchilla groundwater subbasins of the San Joaquin Valley Basin (California Department of Water Resources, 2003; Shelton and others, 2009). The study unit has hot, dry summers and cool, moist winters. Average annual rainfall ranges from 11 to 15 inches, most of which occurs between November and February. The main surface-water features in the study unit are the San Joaquin, Fresno, and Chowchilla Rivers, and the Madera and Chowchilla canals. Land use in the study unit is about 69 percent (%) agricultural, 28% natural (mainly grasslands), and 3% urban. The primary crops are orchards and vineyards. The largest urban area is the city of Madera. The primary aquifer system is defined as those parts of the aquifer corresponding to the perforated intervals of wells listed in the California Department of Public Health (CDPH) database. In the Madera-Chowchilla study unit, these wells typically are drilled to depths between 200 and 800 feet, consist of a solid casing from land surface to a depth of about 140 to 400 feet, and are perforated below the solid casing. Water quality in the primary aquifer system may differ from that in the shallower and deeper parts of the aquifer system. The primary aquifer system in the study unit consists of Quaternary-age alluvial-fan and fluvial deposits that were formed by the rivers draining the Sierra Nevada. Sediments consist of gravels, sands

  7. Seismic acquisition and processing methodologies in overthrust areas: Some examples from Latin America

    SciTech Connect

    Tilander, N.G.; Mitchel, R..

    1996-08-01

    Overthrust areas represent some of the last frontiers in petroleum exploration today. Billion barrel discoveries in the Eastern Cordillera of Colombia and the Monagas fold-thrust belt of Venezuela during the past decade have highlighted the potential rewards for overthrust exploration. However the seismic data recorded in many overthrust areas is disappointingly poor. Challenges such as rough topography, complex subsurface structure, presence of high-velocity rocks at the surface, back-scattered energy and severe migration wavefronting continue to lower data quality and reduce interpretability. Lack of well/velocity control also reduces the reliability of depth estimations and migrated images. Failure to obtain satisfactory pre-drill structural images can easily result in costly wildcat failures. Advances in the methodologies used by Chevron for data acquisition, processing and interpretation have produced significant improvements in seismic data quality in Bolivia, Colombia and Trinidad. In this paper, seismic test results showing various swath geometries will be presented. We will also show recent examples of processing methods which have led to improved structural imaging. Rather than focusing on {open_quotes}black box{close_quotes} methodology, we will emphasize the cumulative effect of step-by-step improvements. Finally, the critical significance and interrelation of velocity measurements, modeling and depth migration will be explored. Pre-drill interpretations must ultimately encompass a variety of model solutions, and error bars should be established which realistically reflect the uncertainties in the data.

  8. Ground-water quality beneath solid-waste disposal sites at anchorage, Alaska

    USGS Publications Warehouse

    Zenone, Chester; Donaldson, D.E.; Grunwaldt, J.J.

    1975-01-01

    Studies at three solid-waste disposal sites in the Anchorage area suggest that differences in local geohydrologic conditions influence ground-water quality. A leachate was detected in ground water within and beneath two sites where the water table is very near land surface and refuse is deposited either at or below the water table in some parts of the filled areas. No leachate was detected in ground water beneath a third site where waste disposal is well above the local water table.

  9. Elucidating hydraulic fracturing impacts on groundwater quality using a regional geospatial statistical modeling approach.

    PubMed

    Burton, Taylour G; Rifai, Hanadi S; Hildenbrand, Zacariah L; Carlton, Doug D; Fontenot, Brian E; Schug, Kevin A

    2016-03-01

    Hydraulic fracturing operations have been viewed as the cause of certain environmental issues including groundwater contamination. The potential for hydraulic fracturing to induce contaminant pathways in groundwater is not well understood since gas wells are completed while isolating the water table and the gas-bearing reservoirs lay thousands of feet below the water table. Recent studies have attributed ground water contamination to poor well construction and leaks in the wellbore annulus due to ruptured wellbore casings. In this paper, a geospatial model of the Barnett Shale region was created using ArcGIS. The model was used for spatial analysis of groundwater quality data in order to determine if regional variations in groundwater quality, as indicated by various groundwater constituent concentrations, may be associated with the presence of hydraulically fractured gas wells in the region. The Barnett Shale reservoir pressure, completions data, and fracture treatment data were evaluated as predictors of groundwater quality change. Results indicated that elevated concentrations of certain groundwater constituents are likely related to natural gas production in the study area and that beryllium, in this formation, could be used as an indicator variable for evaluating fracturing impacts on regional groundwater quality. Results also indicated that gas well density and formation pressures correlate to change in regional water quality whereas proximity to gas wells, by itself, does not. The results also provided indirect evidence supporting the possibility that micro annular fissures serve as a pathway transporting fluids and chemicals from the fractured wellbore to the overlying groundwater aquifers. PMID:26745299

  10. Multivariate analysis of groundwater quality and modeling impact of ground heat pump system

    NASA Astrophysics Data System (ADS)

    Thuyet, D. Q.; Saito, H.; Muto, H.; Saito, T.; Hamamoto, S.; Komatsu, T.

    2013-12-01

    The ground source heat pump system (GSHP) has recently become a popular building heating or cooling method, especially in North America, Western Europe, and Asia, due to advantages in reducing energy consumption and greenhouse gas emission. Because of the stability of the ground temperature, GSHP can effectively exchange the excess or demand heat of the building to the ground during the building air conditioning in the different seasons. The extensive use of GSHP can potentially disturb subsurface soil temperature and thus the groundwater quality. Therefore the assessment of subsurface thermal and environmental impacts from the GSHP operations is necessary to ensure sustainable use of GSHP system as well as the safe use of groundwater resources. This study aims to monitor groundwater quality during GSHP operation and to develop a numerical model to assess changes in subsurface soil temperature and in groundwater quality as affected by GSHP operation. A GSHP system was installed in Fuchu city, Tokyo, and consists of two closed double U-tubes (50-m length) buried vertically in the ground with a distance of 7.3 m from each U-tube located outside a building. An anti-freezing solution was circulated inside the U-tube for exchanging the heat between the building and the ground. The temperature at every 5-m depth and the groundwater quality including concentrations of 16 trace elements, pH, EC, Eh and DO in the shallow aquifer (32-m depth) and the deep aquifer (44-m depth) were monitored monthly since 2012, in an observation well installed 3 m from the center of the two U-tubes.Temporal variations of each element were evaluated using multivariate analysis and geostatistics. A three-dimensional heat exchange model was developed in COMSOL Multiphysics4.3b to simulate the heat exchange processes in subsurface soils. Results showed the difference in groundwater quality between the shallow and deep aquifers to be significant for some element concentrations and DO, but

  11. Reactive transport controls on sandy acid sulfate soils and impacts on shallow groundwater quality

    NASA Astrophysics Data System (ADS)

    Salmon, S. Ursula; Rate, Andrew W.; Rengel, Zed; Appleyard, Steven; Prommer, Henning; Hinz, Christoph

    2014-06-01

    Disturbance or drainage of potential acid sulfate soils (PASS) can result in the release of acidity and degradation of infrastructure, water resources, and the environment. Soil processes affecting shallow groundwater quality have been investigated using a numerical code that integrates (bio)geochemical processes with water, solute, and gas transport. The patterns of severe and persistent acidification (pH < 4) in the sandy, carbonate-depleted podzols of a coastal plain could be reproduced without calibration, based on oxidation of microcrystalline pyrite after groundwater level decrease and/or residual groundwater acidity, due to slow vertical solute transport rates. The rate of acidification was limited by gas phase diffusion of oxygen and hence was sensitive to soil water retention properties and in some cases also to oxygen consumption by organic matter mineralization. Despite diffusion limitation, the rate of oxidation in sandy soils was rapid once pyrite-bearing horizons were exposed, even to a depth of 7.5 m. Groundwater level movement was thus identified as an important control on acidification, as well as the initial pyrite content. Increase in the rate of Fe(II) oxidation lead to slightly lower pH and greater accumulation of Fe(III) phases, but had little effect on the overall amount of pyrite oxidized. Aluminosilicate (kaolinite) dissolution had a small pH-buffering effect but lead to the release of Al and associated acidity. Simulated dewatering scenarios highlighted the potential of the model for risk assessment of (bio)geochemical impacts on soil and groundwater over a range of temporal and spatial scales.

  12. Groundwater-Quality Data in the South Coast Interior Basins Study Unit, 2008: Results from the California GAMA Program

    USGS Publications Warehouse

    Mathany, Timothy M.; Kulongoski, Justin T.; Ray, Mary C.; Belitz, Kenneth

    2009-01-01

    ], and radioactive constituents [gross alpha and gross beta radioactivity and radon-222]. Naturally occurring isotopes [stable isotopes of hydrogen, oxygen, and carbon, and activities of tritium and carbon-14] and dissolved noble gases also were measured to help identify the sources and ages of the sampled groundwater. In total, 288 constituents and water-quality indicators (field parameters) were investigated. Three types of quality-control samples (blanks, replicates, and matrix spikes) each were collected at approximately 4-11 percent of the wells, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination was not a significant source of bias in the data obtained from the groundwater samples. Differences between replicate samples generally were less than 10 percent relative standard deviation, indicating acceptable analytical reproducibility. Matrix spike recoveries were within the acceptable range (70 to 130 percent) for most compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, untreated groundwater typically is treated, disinfected, and/or blended with other waters to maintain water quality. Regulatory thresholds apply to water that is served to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and nonregulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH), and to nonregulatory thresholds established for aesthetic and technical concerns by CDPH. Comparisons between data collected for this study and thresholds for drinking water are for illustrative purposes only, and are not indicative of complia

  13. Nitrate contamination in groundwater of some rural areas of Rajasthan, India.

    PubMed

    Suthar, Surindra; Bishnoi, Preeti; Singh, Sushma; Mutiyar, Pravin K; Nema, Arvind K; Patil, Nagraj S

    2009-11-15

    Efforts were made to evaluate the level of nitrate in some agro-economy based rural habitations of northern Rajasthan, India. A total of 64 groundwater samples from 21 different villages/sub-villages of district Sri Ganganagar, India were collected and analyzed for nitrate (as NO(3)(-)), sulphate (as SO(4)(2-)) and few other parameters. NO(3)(-) level in groundwater was 7.10-82.0 mg l(-1) for individual samples. But average NO(3)(-) for total samples was 60.6+/-33.6 (SD) mg l(-1), which indicates the non-suitability of groundwater for drinking purposes, if BIS permissible limit (22.6 mg l(-1)) is considered as reference level. SO(4)(2-) ranged form 28.6 to 660.3 mg l(-1) in this area. The regression analysis indicates the difference sources for NO(3)(-) and SO(4)(2-) contamination in different regions rather than a common source. The point and non-point sources of NO(3)(-) and SO(4)(2-) in groundwater of this region may be N-fertilizer, sewerage, animal waste, organic manure, geology of sub-surface soil layers, pit latrines, etc. Results thus indicated that groundwater of this part of the State is severely polluted due to anthropogenic activities. The continuous consumption of such water may pose serious health hazardous in local residents. PMID:19545944

  14. Influence of Sungun copper mine on groundwater quality, NW Iran

    NASA Astrophysics Data System (ADS)

    Nasrabadi, T.; Nabi Bidhendi, G. R.; Karbassi, A. R.; Hoveidi, H.; Nasrabadi, I.; Pezeshk, H.; Rashidinejad, F.

    2009-08-01

    Sungun mine is the largest open-cast copper mine in northwest of Iran and is in the primary stages of extraction. The influence of mining activity on the quality of regional groundwater has been taken in to consideration in this study. Accordingly, sampling was done from 22 springs in the study area. The concentrations of major anions and cations as well as Al, Cu, Cd, Cr, Fe, Mn, and Zn were determined for all 22 spring samples in mid-August 2005. The results showed that the concentrations of most of these elements were below the USA Environmental Protection Agency (EPA) limits; however, Al and Fe concentrations are considered to be more than limits in a couple of samples. Despite the fact that geological formations are highly weathered and fractured, the dissolution of minerals within the study area is low. This may be justified by the relatively high alkalinity of local underground water which keeps metals in solid phase and does not let them enter dissolved phase. Additionally, this may be attributed to the high velocity of groundwater flows, which do not give enough time for minerals to dissolve. Correlation coefficients among water chemistry components were determined and the weighted-pair group method was chosen for cluster analysis. Accordingly, high correlation among Al, Fe and Cr, Cd ,and Cu, sodium absorption ratio (SAR) and Na as well as total hardness (TH), Ca, and Mg were observed. The chemical characteristics of water compositions on the basis of major ion concentrations were evaluated on a Schoeller and Piper diagram. Accordingly, the dominant type of water in the region is considered to be Ca-HCO3 (calcium-bicarbonate type). However, this type of water is also rich in Na, K, and especially Mg. Regarding Schoeller diagram, the current status of local underground water is good for drinking purposes. By commencing mining excavation with designed capacity in near future, the minerals will come into contact with air and water resulting in dissolution

  15. Ground-water quality beneath irrigated agriculture in the central High Plains aquifer, 1999-2000

    USGS Publications Warehouse

    Bruce, Breton W.; Becker, Mark F.; Pope, Larry M.; Gurdak, Jason J.

    2003-01-01

    In 1999 and 2000, 30 water-quality monitoring wells were installed in the central High Plains aquifer to evaluate the quality of recently recharged ground water in areas of irrigated agriculture and to identify the factors affecting ground-water quality. Wells were installed adjacent to irrigated agricultural fields with 10- or 20-foot screened intervals placed near the water table. Each well was sampled once for about 100 waterquality constituents associated with agricultural practices. Water samples from 70 percent of the wells (21 of 30 sites) contained nitrate concentrations larger than expected background concentrations (about 3 mg/L as N) and detectable pesticides. Atrazine or its metabolite, deethylatrazine, were detected with greater frequency than other pesticides and were present in all 21 samples where pesticides were detected. The 21 samples with detectable pesticides also contained tritium concentrations large enough to indicate that at least some part of the water sample had been recharged within about the last 50 years. These 21 ground-water samples are considered to show water-quality effects related to irrigated agriculture. The remaining 9 groundwater samples contained no pesticides, small tritium concentrations, and nitrate concentrations less than 3.45 milligrams per liter as nitrogen. These samples are considered unaffected by the irrigated agricultural land-use setting. Nitrogen isotope ratios indicate that commercial fertilizer was the dominant source of nitrate in 13 of the 21 samples affected by irrigated agriculture. Nitrogen isotope ratios for 4 of these 21 samples were indicative of an animal waste source. Dissolved-solids concentrations were larger in samples affected by irrigated agriculture, with large sulfate concentrations having strong correlation with large dissolved solids concentrations in these samples. A strong statistical correlation is shown between samples affected by irrigated agriculture and sites with large rates of

  16. Impacts of afforestation on groundwater resources and quality

    NASA Astrophysics Data System (ADS)

    Allen, Alistair; Chapman, Deborah

    2001-07-01

    Plans to double the proportion of land under forest cover in Ireland by the year 2035 have been initiated. The plan, primarily financially driven, ignores potential environmental impacts of forestry, particularly impacts on groundwater resources and quality. Since groundwater supplies almost 25% of Ireland's total potable water, these impacts are important. Field investigations indicate that afforestation leads to a reduction in runoff by as much as 20%, mainly due to interception of rainfall by forest canopies. Clearfelling has the opposite impact. Implications are that uncoordinated forestry practices can potentially exacerbate flooding. Groundwater recharge is affected by forestry, largely due to greater uptake of soil water by trees and to increased water-holding capacity of forest soils, arising from higher organic contents. Recharge rates under forests can be reduced to one tenth that under grass or heathland. Groundwater quality may be affected by enhanced acidification and nitrification under forests, due partly to scavenging of atmospheric pollutants by forest canopies, and partly to greater deposition of highly acid leaf litter. The slower recharge rates of groundwater under forests lead to significant delays in manifestation of deterioration in groundwater quality. Résumé. Des plans sont à l'étude pour doubler la proportion du couvert forestier en Irlande d'ici à 2035. Le plan, primitivement déterminé sur une base financière, ignore les impacts environnementaux potentiels de la foresterie, et particulièrement les impacts sur les ressources en eau souterraine et leur qualité. Du fait que les eaux souterraines satisfont presque 25% du total de l'eau potable de l'Irlande, ces impacts sont importants. Les études de terrain montrent que le reboisement conduit à une réduction du ruissellement d'au moins 20%, principalement à cause d'une interception de la pluie par le couvert forestier. Les coupes ont un impact contraire. Les implications sont

  17. Hydrogeochemical assessment of groundwater quality in a river delta using multivariate statistical techniques

    NASA Astrophysics Data System (ADS)

    Matiatos, Ioannis; Paraskevopoulou, Vasiliki; Botsou, Fotini; Dassenakis, Manolis; Lazogiannis, Konstantinos; Ghionis, George; Poulos, Serafim

    2016-04-01

    The knowledge of the factors controlling the regional groundwater quality regime is important for planning and management of the groundwater resources. This work applies conventional hydrogeochemical and multivariate statistical techniques to identify the main factors and mechanisms controlling the hydrogeochemistry of groundwater in the deltaic environment of River Pinios (Thessaly) as well as possible areas of interactions between groundwater and surface water bodies. Hierarchical Cluster Analysis (HCA) and Principal Components Analysis (PCA) are performed using a data set of physical-chemical parameters from surface water and groundwater sites. Through HCA the paper's objective is to group together surface water and groundwater monitoring sites based on similarities in hydrochemistry in order to indicate areas of groundwater-surface water interaction. On the other hand, PCA aims at indicating factors responsible for the hydrogeochemical characteristics of the water bodies in the river delta (e.g., water-rock interaction, seawater intrusion, anthropogenic activities).

  18. Geohydrology and ground-water quality on Shelter Island, Suffolk County, New York, 1983-84

    USGS Publications Warehouse

    Simmons, D.L.

    1986-01-01

    Shelter Island, with an area of about 11 sq mi, lies between the north and south forks of eastern Long Island in Suffolk County. The thin upper glacial (water table) aquifer contains the lens-shaped freshwater body that is the sole source of freshwater for the Town 's population of about 2,200 year-round and 10,000 summer residents. Chloride concentrations in groundwater above the freshwater/saltwater interface, defined as 40 mg/L Cl-, are relatively constant with depth. Below the interface, however, chloride concentrations increase rapidly--as much as an order of magnitude within 10 ft--until they reach 19 ,000 mg/L, the chloride concentration of seawater. Chloride concentrations in shallow groundwater from wells screened in or near the zone of diffusion may range over two orders of magnitude in response to variations in recharge and groundwater withdrawal. After the summer season of relatively low recharge and peak water demand, the thickness of the freshwater lens is < 20 ft in many nearshore areas. A map showing the configuration of the water table in December 1983 indicates freshwater mounds in the center of the island, in the Mashomack Preserve, on the Dering Harbor-Hay Beach peninsula, and in the area between Shelter Island Heights and West Neck Bay. Areas in which the supply of fresh groundwater is severely limited include all coastal areas, the southernmost part of the West Neck peninsula, and Little Ram Island. Water levels in most locations are < 6 ft above sea level. During 1974-83, seasonal water table fluctuations were greater than variations that occurred from year to year. Groundwater quality on Shelter Island is generally good and usually meets Federal and State drinking water standards. However, many wells contain water that has excessive concentrations of dissolved iron and manganese (up to 5.0 mg/L and 3.0 mg/L, respectively), and elevated chloride and dissolved solids concentrations (up to 310 mg/L and 585 mg/L, respectively) have been found in

  19. Combining groundwater quality analysis and a numerical flow simulation for spatially establishing utilization strategies for groundwater and surface water in the Pingtung Plain

    NASA Astrophysics Data System (ADS)

    Jang, Cheng-Shin; Chen, Ching-Fang; Liang, Ching-Ping; Chen, Jui-Sheng

    2016-02-01

    Overexploitation of groundwater is a common problem in the Pingtung Plain area of Taiwan, resulting in substantial drawdown of groundwater levels as well as the occurrence of severe seawater intrusion and land subsidence. Measures need to be taken to preserve these valuable groundwater resources. This study seeks to spatially determine the most suitable locations for the use of surface water on this plain instead of extracting groundwater for drinking, irrigation, and aquaculture purposes based on information obtained by combining groundwater quality analysis and a numerical flow simulation assuming the planning of manmade lakes and reservoirs to the increase of water supply. The multivariate indicator kriging method is first used to estimate occurrence probabilities, and to rank townships as suitable or unsuitable for groundwater utilization according to water quality standards for drinking, irrigation, and aquaculture. A numerical model of groundwater flow (MODFLOW) is adopted to quantify the recovery of groundwater levels in townships after model calibration when groundwater for drinking and agricultural demands has been replaced by surface water. Finally, townships with poor groundwater quality and significant increases in groundwater levels in the Pingtung Plain are prioritized for the groundwater conservation planning based on the combined assessment of groundwater quality and quantity. The results of this study indicate that the integration of groundwater quality analysis and the numerical flow simulation is capable of establishing sound strategies for joint groundwater and surface water use. Six southeastern townships are found to be suitable locations for replacing groundwater with surface water from manmade lakes or reservoirs to meet drinking, irrigation, and aquaculture demands.

  20. Groundwater quality appraisal and its hydrochemical characterization in Ghaziabad (a region of indo-gangetic plain), Uttar Pradesh, India

    NASA Astrophysics Data System (ADS)

    Singh, Uday Veer; Abhishek, Amar; Singh, Kunwar P.; Dhakate, Ratnakar; Singh, Netra Pal

    2014-06-01

    India's growing population enhances great pressure on groundwater resources. The Ghaziabad region is located in the northern Indo-Gangetic alluvium plain of India. Increased population and industrial activities make it imperative to appraise the quality of groundwater system to ensure long-term sustainability of resources. A total number of 250 groundwater samples were collected in two different seasons, viz., pre-monsoon and post monsoon and analyzed for major physico-chemical parameters. Broad range and great standard deviation occurs for most parameters, indicating chemical composition of groundwater affected by process, including water-rock interaction and anthropogenic effect. Iron was found as predominant heavy metal in groundwater samples followed by copper and lead. An exceptional high concentration of Chromium was found in some locations. Industrial activities as chrome plating and wood preservative are the key source to metal pollution in Ghaziabad region. On the basis of classification the area water shows normal sulfate, chloride and bi-carbonate type, respectively. Base-exchange indices classified 76 % of the groundwater sources was the sodium-bicarbonate type. The meteoric genesis indices demonstrated that 80 % of groundwater sources belong to a shallow meteoric water percolation type. Chadha's diagram suggested that the hydro-chemical faces belong to the HCO3 - dominant Ca2+-Mg2+ type along with Cl--dominant Ca2+-Mg2+-type. There was no significant change in pollution parameters in the selected seasons. Comparison of groundwater quality with Indian standards proves that majority of water samples are suitable for irrigation purposes but not for drinking.

  1. Arid zone groundwater recharge and salinisation processes; an example from the Lake Eyre Basin, Australia

    NASA Astrophysics Data System (ADS)

    Tweed, Sarah; Leblanc, Marc; Cartwright, Ian; Favreau, Guillaume; Leduc, Christian

    2011-10-01

    SummaryIn arid central Australia, the ˜1.14 M km 2 endorheic Lake Eyre Basin (LEB) experiences sporadic floods, and contains saline shallow groundwater. In this basin, where on-ground physical and chemical data are very sparse, new observations of major ion chemistry, stable isotopes (δ 2H, δ 18O, δ 13C), radiogenic isotopes ( 3H, 14C), and remote sensing (MODIS) data were used to investigate groundwater recharge and salinisation processes in 2006-2007. In January 2007 there was a large and intense local rainfall event, followed by flooding to the normally dry Lake Eyre resulting from heavy rainfall in the northern LEB that took ˜2 months to arrive at Lake Eyre. Groundwater chemistry from this study show no evidence of recharge from the floodwaters or the local rainfall; however this does not preclude the process. Low transit times and low infiltrating volumes may mean that the recharge event has not yet been detected. Over the longer term, the stable isotope chemistry indicates that groundwater is predominantly diffusely recharged during heavy local rainfall events (>100-150 mm/month), and radiogenic isotopes reflect an older shallow groundwater efficiently mixing with recent (decadal) recharge. The high total dissolved solids (TDS) of regional shallow groundwater (up to 52.5 g/L) is intrinsically linked with these recharge processes; where infiltrating diffuse rainfall is evaporated, and heavy rainfall events transport saline pore water (saline due to evaporation in the unsaturated zone) to the groundwater system. The high TDS of shallow groundwater beneath the dry Lake Eyre bed (up to 322 g/L) is also controlled by evaporation. However, although evaporite minerals are prolific in the lake area, the non-conservative behaviour of Br in pore water limits analysis of the role of halite mineral dissolution and precipitation reactions controlling groundwater salinity. Evaporation-driven salinisation of shallow groundwater in arid central Australia is distinct

  2. Knowledge, transparency, and refutability in groundwater models, an example from the Death Valley regional groundwater flow system

    NASA Astrophysics Data System (ADS)

    Hill, Mary C.; Faunt, Claudia C.; Belcher, Wayne R.; Sweetkind, Donald S.; Tiedeman, Claire R.; Kavetski, Dmitri

    This work demonstrates how available knowledge can be used to build more transparent and refutable computer models of groundwater systems. The Death Valley regional groundwater flow system, which surrounds a proposed site for a high level nuclear waste repository of the United States of America, and the Nevada National Security Site (NNSS), where nuclear weapons were tested, is used to explore model adequacy, identify parameters important to (and informed by) observations, and identify existing old and potential new observations important to predictions. Model development is pursued using a set of fundamental questions addressed with carefully designed metrics. Critical methods include using a hydrogeologic model, managing model nonlinearity by designing models that are robust while maintaining realism, using error-based weighting to combine disparate types of data, and identifying important and unimportant parameters and observations and optimizing parameter values with computationally frugal schemes. The frugal schemes employed in this study require relatively few (10-1000 s), parallelizable model runs. This is beneficial because models able to approximate the complex site geology defensibly tend to have high computational cost. The issue of model defensibility is particularly important given the contentious political issues involved.

  3. Assessment of Groundwater Quality Using Multivariate Statistical Techniques and Kriging Method

    NASA Astrophysics Data System (ADS)

    Kim, T.; Chung, S.; Kim, B.; Kang, D.

    2008-12-01

    The study area is located at the southern part of Korean Peninsula, and adjacent to the South Sea. 20 chemical components in 64 groundwater samples were used for the assessment of groundwater quality. The groundwater was classified into Ca(HCO3)2 type, NaCl type, NaHCO3 type and CaCl2 type by Piper's trilinear diagram. Cluster analysis divided the groundwater samples into three groups: Group 1 for fresh groundwater, Group 2 for groundwater contaminated by Cl, NO3, and Fe, and Group 3 for groundwater contaminated by NaCl. Discriminant analysis showed that the correctness of cluster analysis was 92%. Ca, Mg, HCO3, Cl, and pH were important factor for the discrimination of cluster analysis. In factor analysis, 3 factors determined the groundwater quality with 80 % in total variance: Factor 1 for the characteristics of fresh water and saline water, Factor 2 for the characteristics of contamination by nitrate, and Factor 3 for the characteristics of contamination by iron (Fe). Factor analysis showed that the groundwater was influenced by seawater intrusion, human activity and geological origin, because the study area was located near the sea and had the urban and rural functions. The contamination of anthropogenic origin was derived from fertilizer, sewage, exhaust gas of vehicles and excrement of livestocks. The geology of the study area was composed of shale, sandstone, andesite, andesitic tuff, biotite granite and amphibole granite. Using ordinary kriging, the distribution maps of 3 factor scores were compared to those of 3 contamination components, i.e., Cl, NO3, and Fe. The distributions of 3 factor scores coincide well with those of 3 contamination components. Cluster analysis and discriminant analysis were very useful for the classification of groundwater samples by groundwater quality. Factor analysis provided valuable aids for the determinations of contamination components and contamination origins. Kriging was very helpful for the assessment of the spatial

  4. Empirical estimation of groundwater quality changes using remote sensing

    NASA Astrophysics Data System (ADS)

    Gibbons, A.; Thomas, B. F.; Famiglietti, J. S.

    2015-12-01

    Recent groundwater availability studies estimate large-scale aquifer depletion rates and aquifer stress using monthly water storage variations from NASA's Gravity Recovery and Climate Experiment (GRACE) mission. To further evaluate available groundwater resources, assessing potability of groundwater is necessary. Statistical relationships are initially developed at individual well locations to discern our ability to predict groundwater geochemistry as a function of groundwater levels. Next, up-scaled multivariate relationships to estimate total dissolved solid (TDS) concentrations as a function of GRACE-derived subsurface storage anomalies, dominant land use, and other physical parameters are developed in two important aquifer systems in the United States: the High Plains aquifer and the Central Valley aquifer. A goodness of fit test was performed to evaluate model strength. Results demonstrate the potential to characterize global groundwater potability variations using remote sensing.

  5. 48 CFR 22.1003-5 - Some examples of contracts covered.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 48 Federal Acquisition Regulations System 1 2013-10-01 2013-10-01 false Some examples of contracts covered. 22.1003-5 Section 22.1003-5 Federal Acquisition Regulations System FEDERAL ACQUISITION REGULATION SOCIOECONOMIC PROGRAMS APPLICATION OF LABOR LAWS TO GOVERNMENT ACQUISITIONS Service Contract Act of 1965, as Amended 22.1003-5 Some...

  6. 48 CFR 22.1003-5 - Some examples of contracts covered.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 48 Federal Acquisition Regulations System 1 2010-10-01 2010-10-01 false Some examples of contracts covered. 22.1003-5 Section 22.1003-5 Federal Acquisition Regulations System FEDERAL ACQUISITION REGULATION SOCIOECONOMIC PROGRAMS APPLICATION OF LABOR LAWS TO GOVERNMENT ACQUISITIONS Service Contract Act of 1965, as Amended 22.1003-5 Some...

  7. On the scope and management of pesticide pollution of Swedish groundwater resources: The Scanian example.

    PubMed

    Åkesson, Maria; Sparrenbom, Charlotte J; Dahlqvist, Peter; Fraser, Stephen J

    2015-04-01

    Twenty-three south-Swedish public supply wells were studied to assess pesticide pollution of regional groundwater resources. Relations between pesticide occurrence, hydrogeology, and land use were analyzed using Kohonen's Self-Organizing Maps approach. Pesticides are demonstrated to be substantially present in regional groundwater, with detections in 18 wells. Concentrations above the drinking water threshold are confirmed for nine wells. Observations indicate considerable urban influence, and lagged effects of past, less restricted use. Modern, oxic waters from shallow, unconfined, unconsolidated or fracture-type bedrock aquifers appear particularly vulnerable. Least affected waters appear primarily associated with deeper wells, anoxic conditions, and more confined sediment aquifers lacking urban influence. Comprehensive, standardized monitoring of pesticides in groundwater need to be implemented nationwide to enable sound assessments of pollution status and trends, and to develop sound groundwater management plans in accordance with the Water Framework Directive. Further, existing water protection areas and associated regulations need to be reassessed. PMID:25168463

  8. Groundwater quality in the Upper Susquehanna River Basin, New York, 2009

    USGS Publications Warehouse

    Reddy, James E.; Risen, Amy J.

    2012-01-01

    Water samples were collected from 16 production wells and 14 private residential wells in the Upper Susquehanna River Basin from August through December 2009 and were analyzed to characterize the groundwater quality in the basin. Wells at 16 of the sites were completed in sand and gravel aquifers, and 14 were finished in bedrock aquifers. In 2004–2005, six of these wells were sampled in the first Upper Susquehanna River Basin study. Water samples from the 2009 study were analyzed for 10 physical properties and 137 constituents that included nutrients, organic carbon, major inorganic ions, trace elements, radionuclides, pesticides, volatile organic compounds, and 4 types of bacterial analyses. Results of the water-quality analyses are presented in tabular form for individual wells, and summary statistics for specific constituents are presented by aquifer type. The results are compared with Federal and New York State drinking-water standards, which typically are identical. The results indicate that groundwater genrally is of acceptable quality, although concentrations of some constituents exceeded at least one drinking-water standard at 28 of the 30 wells. These constituents include: pH, sodium, aluminum, manganese, iron, arsenic, radon-222, residue on evaporation, total and fecal coliform including Escherichia coli and heterotrophic plate count.

  9. Field-scale relationships among soil properties and shallow groundwater quality.

    PubMed

    Derby, Nathan E; Korom, Scott F; Casey, Francis X M

    2013-01-01

    It is important to understand the link between land surface/soil properties and shallow groundwater quality. To that end, soil properties and near-water-table groundwater chemistry of a shallow, unconfined aquifer were measured on a 100-m grid on a 64-ha irrigated field in southeastern North Dakota. Soil properties and hydrochemistry were compared via multivariate analysis that included product-moment correlations and factor analysis/principal component analysis. Topographic low areas where the water table was in close proximity to the soil surface generally had higher apparent electrical conductivity (ECa ) and higher percent silt and clay than higher positions on the landscape. The majority of the groundwater was characterized by Ca- and Mg-HCO3 type water and was associated with topographic high areas with lower ECa and net groundwater recharge. Small topographic depressions were areas of higher ECa (net groundwater discharge) where salts that precipitated via evapotranspiration and evaporative discharge dissolved and leached to the groundwater during short-term depression-focused recharge events. At this site, groundwater quality and soil ECa were related to surface topography. High-resolution topography and EC(a) measurements are necessary to characterize the land surface/soil properties and surficial groundwater quality at the field-scale and to delineate areas where the shallow groundwater is most susceptible to contamination. PMID:22913586

  10. Groundwater quality suitable zones identification: application of GIS, Chittoor area, Andhra Pradesh, India

    NASA Astrophysics Data System (ADS)

    Yammani, Srinivasarao

    2007-09-01

    Due to uneven spatial and temporal distribution of rainfall and lack of sufficient water management technologies, the development activities of the society are totally depending on groundwater resources. In addition to the prevailing drought-prone conditions, the improperly treated and unplanned release of effluents of industry, municipal and domestic into the nearby streams and ponds and the majority usage of groundwater for irrigation are increasing the ionic concentration of the groundwater and making it more saline. The analytical results of the collected groundwater samples show that the groundwater is alkaline, and sodium and bicarbonate are the dominant cation and anion, respectively. Gibbs variation diagram shows that the control of the chemistry of groundwater in the study area is the weathering of granitic gneisses and also the leaching of evaporated and crystallized ions from the topsoil of the irrigated areas and improperly treated industrial effluent ponds. GIS, a potential tool for facilitating the generation and use of thematic information, has been applied and analyzed for identification of groundwater quality suitable zones for domestic and irrigation purposes. 30.06% of the area is with suitable, 67.45% of the area is with moderately suitable and 2.45% of the area is with unsuitable quality of groundwater for domestic purpose. 46% of the area is with suitable, 53.36% of the area is with moderately suitable and 0.64% of the area is with unsuitable quality of groundwater for irrigation purpose.

  11. Assessment of groundwater quality and hydrogeochemistry of Manimuktha River basin, Tamil Nadu, India.

    PubMed

    Kumar, S Krishna; Rammohan, V; Sahayam, J Dajkumar; Jeevanandam, M

    2009-12-01

    Groundwater quality assessment study was carried out around Manimuktha river basin, Tamil Nadu, India. Twenty six bore well samples were analyzed for geochemical variations and quality of groundwater. Four major hydrochemical facies (Ca-HCO(3), Na-Cl, Mixed CaNaHCO(3), and mixed CaMgCl) were identified using a Piper trilinear diagram. Comparison of geochemical results with World Health Organization, United States Environmental Protection Agency, and Indian Standard Institution drinking water standards shows that all groundwater samples except few are suitable for drinking and irrigation purposes. The major groundwater pollutions are nitrate and phosphate ions due to sewage effluents and fertilizer applications. The study reveals that the groundwater quality changed due to anthropogenic and natural influence such as agricultural, natural weathering process. PMID:19089596

  12. Dynamic factor analysis of groundwater quality trends in an agricultural area adjacent to Everglades National Park.

    PubMed

    Muñoz-Carpena, R; Ritter, A; Li, Y C

    2005-11-01

    The extensive eastern boundary of Everglades National Park (ENP) in south Florida (USA) is subject to one of the most expensive and ambitious environmental restoration projects in history. Understanding and predicting the water quality interactions between the shallow aquifer and surface water is a key component in meeting current environmental regulations and fine-tuning ENP wetland restoration while still maintaining flood protection for the adjacent developed areas. Dynamic factor analysis (DFA), a recent technique for the study of multivariate non-stationary time-series, was applied to study fluctuations in groundwater quality in the area. More than two years of hydrological and water quality time series (rainfall; water table depth; and soil, ground and surface water concentrations of N-NO3-, N-NH4+, P-PO4(3-), Total P, F-and Cl-) from a small agricultural watershed adjacent to the ENP were selected for the study. The unexplained variability required for determining the concentration of each chemical in the 16 wells was greatly reduced by including in the analysis some of the observed time series as explanatory variables (rainfall, water table depth, and soil and canal water chemical concentration). DFA results showed that groundwater concentration of three of the agrochemical species studied (N-NO3-, P-PO4(3-)and Total P) were affected by the same explanatory variables (water table depth, enriched topsoil, and occurrence of a leaching rainfall event, in order of decreasing relative importance). This indicates that leaching by rainfall is the main mechanism explaining concentration peaks in groundwater. In the case of N-NH4+, in addition to leaching, groundwater concentration is governed by lateral exchange with canals. F-and Cl- are mainly affected by periods of dilution by rainfall recharge, and by exchange with the canals. The unstructured nature of the common trends found suggests that these are related to the complex spatially and temporally varying land

  13. Dynamic factor analysis of groundwater quality trends in an agricultural area adjacent to Everglades National Park

    NASA Astrophysics Data System (ADS)

    Muñoz-Carpena, R.; Ritter, A.; Li, Y. C.

    2005-11-01

    The extensive eastern boundary of Everglades National Park (ENP) in south Florida (USA) is subject to one of the most expensive and ambitious environmental restoration projects in history. Understanding and predicting the water quality interactions between the shallow aquifer and surface water is a key component in meeting current environmental regulations and fine-tuning ENP wetland restoration while still maintaining flood protection for the adjacent developed areas. Dynamic factor analysis (DFA), a recent technique for the study of multivariate non-stationary time-series, was applied to study fluctuations in groundwater quality in the area. More than two years of hydrological and water quality time series (rainfall; water table depth; and soil, ground and surface water concentrations of N-NO 3-, N-NH 4+, P-PO 43-, Total P, F -and Cl -) from a small agricultural watershed adjacent to the ENP were selected for the study. The unexplained variability required for determining the concentration of each chemical in the 16 wells was greatly reduced by including in the analysis some of the observed time series as explanatory variables (rainfall, water table depth, and soil and canal water chemical concentration). DFA results showed that groundwater concentration of three of the agrochemical species studied (N-NO 3-, P-PO 43-and Total P) were affected by the same explanatory variables (water table depth, enriched topsoil, and occurrence of a leaching rainfall event, in order of decreasing relative importance). This indicates that leaching by rainfall is the main mechanism explaining concentration peaks in groundwater. In the case of N-NH 4+, in addition to leaching, groundwater concentration is governed by lateral exchange with canals. F -and Cl - are mainly affected by periods of dilution by rainfall recharge, and by exchange with the canals. The unstructured nature of the common trends found suggests that these are related to the complex spatially and temporally varying

  14. Groundwater quality & sustainability in Ulaanbaatar, the fast growing Capital of Mongolia

    NASA Astrophysics Data System (ADS)

    Batsaikhan, N.; Woo, N. C.; Nemer, B.

    2011-12-01

    About 40% (1.1 million out of 2.7 million total) of Mongolian population lives in the capital city, Ulaanbaatar. The city's drinking water totally depends on groundwater pumped from the alluvial aquifer along the Tuul River and some private wells for domestic usage. As a measure to evaluate groundwater conditions, a total 55 samples from groundwater and surface waters were collected in the public central well-field and its adjacent area from August 2010 to Feb. 2011, for characteristics of water chemistry and environmental isotopic signatures. The water types were classified with Ca-Mg-HCO3, Ca-Na-HCO3 and Ca-HCO3 in summer, but predominantly Ca-HCO3 in winter. Statistical analysis of water compositions shows two groups of water: group-A waters from the Public central supply well-field with Tuul river waters, and group-B from other area including Ger dwelling areas. In terms of water quality, nitrate concentrations exceeded the WHO Guidelines for drinking-water quality (50 mg/l) in 55% (15 out of 27 samples) of the group-B; it implies that the potential sources of groundwater contamination be domestic waste-disposal practices and underdeveloped sewage systems. Environmental isotopes and water-level monitoring data indicated that shallow wells, showing the depth to water less than 3 m bgs, appear to be directly recharged from rainfalls and river water. In contrast, wells with the depth to water in between 5 and 7 m and located some distance from Tuul River take approximately 2 to 3 months to be recharged in rainy season. Since Ulaanbaatar has been growing fast as the Capital of Mongolia, various types of potential sources of groundwater contamination have also been located inside the city boundary including tanning industries, coal-based thermal power plants, gas stations, etc. Thus, for the sustainable development of the Capitol, it is warranted to develop better management measures with long-term and systematic monitoring to protect water-supply sources.

  15. Groundwater evaporation from salt pans: Examples from the eastern Arabian Peninsula

    NASA Astrophysics Data System (ADS)

    Schulz, Stephan; Horovitz, Marcel; Rausch, Randolf; Michelsen, Nils; Mallast, Ulf; Köhne, Maximilian; Siebert, Christian; Schüth, Christoph; Al-Saud, Mohammed; Merz, Ralf

    2015-12-01

    The major groundwater resources of the Arabian Peninsula are stored in the large sedimentary basins in its eastern part. Evaporation from continental salt pans (playas) is an important process in water resources assessments of its upper principal aquifers - the Upper Mega Aquifer system - as it constitutes a significant sink. However, literature values on evaporation rates vary widely and usually report about coastal salt pans where seawater evaporation is assumed. The present study applies different methods to provide a comprehensive picture of groundwater evaporation from salt pans of the Upper Mega Aquifer system. A remote sensing approach provided the spatial distribution and total salt pan area of about 36,500 km2. Hydrochemical and isotopic investigations revealed that from about 10% (3600 km2 ± 1600 km2) of the mapped salt pan area seawater evaporates. To estimate the groundwater evaporation rate from continental salt pans a laboratory column experiment was set up, implying a mean annual evaporation rate of about 42 mm ± 13 mm. In-situ analysis of water table fluctuations in the field suggested about 3 mm a-1 originate from recently infiltrated rainwater leading to an annual net groundwater evaporation of 39 mm ± 13 mm. Relating this number to the mapped salt pan area, from which groundwater evaporates, provides a total annual groundwater loss of 1.3 km3 ± 0.5 km3 for the Upper Mega Aquifer system.

  16. Chemical weathering fluxes from volcanic islands and the importance of groundwater: The Hawaiian example

    NASA Astrophysics Data System (ADS)

    Schopka, Herdis Helga; Derry, Louis A.

    2012-07-01

    We investigated the products and rates of chemical weathering on the Hawaiian Islands, sampling streams on Kaua'i and both streams and groundwater wells on the island of Hawai'i. Dissolved silica was used to investigate the flowpaths of water drained into streams. We found that flowpaths exert a major control on the observed chemical weathering rates. A strong link exists between the degree of landscape dissection and flowpaths of water through the landscape, with streams in undissected landscapes receiving water mainly from surface runoff and streams in highly dissected landscapes receiving a considerable fraction of their water from groundwater (springs and/or seepage). Total alkalinity in Hawaiian streams and groundwater is produced exclusively by silicate chemical weathering. We find that fluxes of total alkalinity (often called "CO2 consumption rate" in the geochemical literature), from the islands are lower than those observed in basaltic regions elsewhere. Groundwater is, overall, the major transport vector for products of chemical weathering from the Hawaiian Islands. On the youngest and largest island, submarine groundwater discharge (SGD) transports more than an order of magnitude more solutes to the ocean than surface water and on the youngest part of the youngest island, SGD is the only link between the terrestrial weathering system and the ocean. These results suggest that groundwater, and particularly SGD, needs to be included in geochemical weathering budgets of volcanic islands.

  17. Groundwater-Quality Data in the Colorado River Study Unit, 2007: Results from the California GAMA Program

    USGS Publications Warehouse

    Goldrath, Dara A.; Wright, Michael T.; Belitz, Kenneth

    2010-01-01

    approximately 30 percent of the wells, and the results were used to evaluate the quality of the data obtained from the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination was not a significant source of bias in the data. Differences between replicate samples were within acceptable ranges and matrix-spike recoveries were within acceptable ranges for most compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, raw groundwater typically is treated, disinfected, or blended with other waters to maintain acceptable water quality. Regulatory thresholds apply to water that is served to the consumer, not to raw groundwater. However, to provide some context for the results, concentrations of constituents measured in the raw groundwater were compared to regulatory and nonregulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and the California Department of Public Health (CDPH) and to thresholds established for aesthetic concerns by CDPH. Comparisons between data collected for this study and drinking-water thresholds are for illustrative purposes only and do not indicate compliance or noncompliance with those thresholds. The concentrations of most constituents detected in groundwater samples were below drinking-water thresholds. Volatile organic compounds (VOC) were detected in approximately 35 percent of grid well samples; all concentrations were below health-based thresholds. Pesticides and pesticide degradates were detected in about 20 percent of all samples; detections were below health-based thresholds. No concentrations of constituents of special interest or nutrients were detected above health-based thresholds. Most of the major and minor ion constituents sampled do not have health-based thresholds; the exception is chloride. Concentrations of chloride, sulfate, and total dis

  18. Groundwater-Quality Data in the Antelope Valley Study Unit, 2008: Results from the California GAMA Program

    USGS Publications Warehouse

    Schmitt, Stephen J.; Milby Dawson, Barbara J.; Belitz, Kenneth

    2009-01-01

    -control samples (blanks, replicates, and samples for matrix spikes) were collected at 12 percent of the wells, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination was not a noticeable source of bias in the data for the groundwater samples. Differences between replicate samples generally were within acceptable ranges, indicating acceptably low variability. Matrix spike recoveries were within acceptable ranges for most compoundsThis study did not evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, or blended with other waters to maintain water quality. Regulatory thresholds apply to water that is served to the consumer, not to raw groundwater. However, to provide some context for the results, concentrations of constituents measured in the raw groundwater were compared with regulatory and non-regulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH) and thresholds established for aesthetic concerns (secondary maximum contaminant levels, SMCL-CA) by CDPH. Comparisons between data collected for this study and drinking-water thresholds are for illustrative purposes only, and are not indicative of compliance or non-compliance with drinking water standards. Most constituents that were detected in groundwater samples were found at concentrations below drinking-water thresholds. Volatile organic compounds (VOCs) were detected in about one-half of the samples and pesticides detected in about one-third of the samples; all detections of these constituents were below health-based thresholds. Most detections of trace elements and nutrients in samples from ANT wells were below health-based thresholds. Exceptions include: one detection of nitrite plus nitr

  19. Hydrochemical Assessment of Surfacewater and Groundwater Quality at Bank Infiltration Site

    NASA Astrophysics Data System (ADS)

    Shamsuddin, M. K. N.; Suratman, S.; Ramli, M. F.; Sulaiman, W. N. A.; Sefie, A.

    2016-07-01

    Groundwater and surface water quantity and quality are an important factor that contribute for drinking water demand and agriculture use. The water quality analysis was assessed using multivariate statistical analyses based on analytical quantitative data that include Discriminant Analysis (DA) and Principal Component Analysis (PCA), based on 36 water quality parameters from the rivers, lakes, and groundwater sites at Jenderam Hilir, which were collected from 2013 to 2014 (56 observations). The DA identified six significant parameters (pH, NO2-, NO3-, F, Fe2+, and Mn2+) from 36 variables to distinguish between the river, lake, and groundwater groups (classification accuracy = 98%). The PCA had confirmed 10 possible causes of variation in the groundwater quality with an eigenvalue greater than 1, which explained 82.931% of the total variance in the water quality data set.

  20. Lognormal kriging for the assessment of reliability in groundwater quality control observation networks

    USGS Publications Warehouse

    Candela, L.; Olea, R.A.; Custodio, E.

    1988-01-01

    Groundwater quality observation networks are examples of discontinuous sampling on variables presenting spatial continuity and highly skewed frequency distributions. Anywhere in the aquifer, lognormal kriging provides estimates of the variable being sampled and a standard error of the estimate. The average and the maximum standard error within the network can be used to dynamically improve the network sampling efficiency or find a design able to assure a given reliability level. The approach does not require the formulation of any physical model for the aquifer or any actual sampling of hypothetical configurations. A case study is presented using the network monitoring salty water intrusion into the Llobregat delta confined aquifer, Barcelona, Spain. The variable chloride concentration used to trace the intrusion exhibits sudden changes within short distances which make the standard error fairly invariable to changes in sampling pattern and to substantial fluctuations in the number of wells. ?? 1988.

  1. Multivariate Statistical Analysis: a tool for groundwater quality assessment in the hidrogeologic region of the Ring of Cenotes, Yucatan, Mexico.

    NASA Astrophysics Data System (ADS)

    Ye, M.; Pacheco Castro, R. B.; Pacheco Avila, J.; Cabrera Sansores, A.

    2014-12-01

    The karstic aquifer of Yucatan is a vulnerable and complex system. The first fifteen meters of this aquifer have been polluted, due to this the protection of this resource is important because is the only source of potable water of the entire State. Through the assessment of groundwater quality we can gain some knowledge about the main processes governing water chemistry as well as spatial patterns which are important to establish protection zones. In this work multivariate statistical techniques are used to assess the groundwater quality of the supply wells (30 to 40 meters deep) in the hidrogeologic region of the Ring of Cenotes, located in Yucatan, Mexico. Cluster analysis and principal component analysis are applied in groundwater chemistry data of the study area. Results of principal component analysis show that the main sources of variation in the data are due sea water intrusion and the interaction of the water with the carbonate rocks of the system and some pollution processes. The cluster analysis shows that the data can be divided in four clusters. The spatial distribution of the clusters seems to be random, but is consistent with sea water intrusion and pollution with nitrates. The overall results show that multivariate statistical analysis can be successfully applied in the groundwater quality assessment of this karstic aquifer.

  2. Status and understanding of groundwater quality in the Santa Clara River Valley, 2007-California GAMA Priority Basin Project

    USGS Publications Warehouse

    Burton, Carmen A.; Montrella, Joseph; Landon, Matthew K.; Belitz, Kenneth

    2011-01-01

    Groundwater quality in the approximately 460-square-mile Santa Clara River Valley study unit was investigated from April through June 2007 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project is conducted by the U.S. Geological Survey (USGS) in collaboration with the California State Water Resources Control Board and the Lawrence Livermore National Laboratory. The Santa Clara River Valley study unit contains eight groundwater basins located in Ventura and Los Angeles Counties and is within the Transverse and Selected Peninsular Ranges hydrogeologic province. The Santa Clara River Valley study unit was designed to provide a spatially unbiased assessment of the quality of untreated (raw) groundwater in the primary aquifer system. The assessment is based on water-quality and ancillary data collected in 2007 by the USGS from 42 wells on a spatially distributed grid, and on water-quality data from the California Department of Public Health (CDPH) database. The primary aquifer system was defined as that part of the aquifer system corresponding to the perforation intervals of wells listed in the CDPH database for the Santa Clara River Valley study unit. The quality of groundwater in the primary aquifer system may differ from that in shallow or deep water-bearing zones; for example, shallow groundwater may be more vulnerable to surficial contamination. Eleven additional wells were sampled by the USGS to improve understanding of factors affecting water quality.The status assessment of the quality of the groundwater used data from samples analyzed for anthropogenic constituents, such as volatile organic compounds (VOCs) and pesticides, as well as naturally occurring inorganic constituents, such as major ions and trace elements. The status assessment is intended to characterize the quality of untreated groundwater resources in the primary aquifers of the Santa Clara River Valley study unit

  3. Risk Communication of Groundwater Quality in Northern Malawi, Africa

    NASA Astrophysics Data System (ADS)

    Holm, R.

    2011-12-01

    Malawi lies in Africa's Great Rift Valley. Its western border is defined by Lake Malawi, the third largest lake in Africa. Over 80% of Malawians live in rural areas and 90% of the labor force is associated with agriculture. More than half of the population lives below the poverty line. Area characteristics indicate a high likelihood of nitrate and total coliform in community drinking water. Infants exposed to high nitrate are at risk of developing methemoglobinemia. In addition, diarrheal diseases from unsafe drinking water are one of the top causes of mortality in children under five. Without sufficient and sustainable supplies of clean water, these challenges will continue to threaten Malawi's ability to overcome the devastating impact of diarrheal diseases on its population. Therefore, Malawi remains highly dependent on outside assistance and influence to reduce or eliminate the threat posed by unsafe drinking water. This research presents a literature review of nitrate and total coliform groundwater quality and a proposed risk communication plan for drinking water in northern Malawi.

  4. Ground-water quality for Grainger County, Tennessee

    USGS Publications Warehouse

    Weaver, J.D.; Patel, A.R.; Hickey, A.C.

    1994-01-01

    The residents of Grainger County depend on ground water for many of their daily needs including personal consumption and crop irrigation. To address concerns associated with ground-water quality related to domestic use, the U.S. Geological Survey collected water samples from 35 wells throughout the county during the summer 1992. The water samples were analyzed to determine if pesticides, nutrients, bacteria, and other selected constituents were present in the ground water. Wells selected for the study were between 100 and 250 feet deep and yielded 10 to 50 gallons of water per minute. Laboratory analyses of the water found no organic pesticides at concentrations exceeding the primary maximum contaminant levels established by the State of Tennessee for wells used for public supply. However, fecal coliform bacteria were detected at concentrations exceeding the State's maximum contaminant level in water from 15 of the 35 wells sampled. Analyses also indicated several inorganic compounds were present in the water samples at concentrations exceeding the secondary maximum contaminant level.

  5. Role of aquifer heterogeneity in fresh groundwater discharge and seawater recycling: An example from the Carmel coast, Israel

    NASA Astrophysics Data System (ADS)

    Weinstein, Y.; Burnett, W. C.; Swarzenski, P. W.; Shalem, Y.; Yechieli, Y.; Herut, B.

    2007-12-01

    A case study is shown in which the pattern of submarine groundwater discharge and of seawater recycling is controlled by local hydrogeological variability. The coastal aquifer in Dor Bay is composed of two units: a partly confined calcaranitic sandstone (Kurkar) and an overlying loose sand. Groundwater in the Kurkar has elevated activities of 222Rn (˜390 dpm/L) and relatively low 224Ra/223Ra activity ratios (3-4), while the sand groundwater is significantly less radiogenic (6-90 dpm/L) and shows higher 224Ra/223Ra ratios. Groundwater discharging from sand-covered areas of the bay has salinities of 16-31 and an average 222Rn activity of 168 dpm/L, which lies on a mixing line between Rn-rich Kurkar fresh water and Rn-poor seawater. Another key observation is that seawater infiltrates to some extent into onshore sand groundwater, while the fresh water within the submarine Kurkar can be traced up to 40 m offshore. This implies that while fresh water mainly discharges from the Kurkar unit, seawater recycling is limited to the loose sand, and that the discharge from sand-covered areas is a mixture of Kurkar water with recycled seawater. Advection rates from the bay floor were calculated from Rn time series and found to vary between 0 and 36 cm/d, correlating negatively with bay water depth. The average flux was 8.1 cm/d, and it did not seem to change much during March, May, and July 2006. The average amount of fresh water discharging to the bay was 5.0 m3/d per meter of shoreline. Radon activity in the sand groundwater also fluctuates due to influx of Kurkar-type groundwater.

  6. Role of aquifer heterogeneity in fresh groundwater discharge and seawater recycling: An example from the Carmel coast, Israel

    USGS Publications Warehouse

    Weinstein, Y.; Burnett, W.C.; Swarzenski, P.W.; Shalem, Y.; Yechieli, Y.; Herut, B.

    2007-01-01

    A case study is shown in which the pattern of submarine groundwater discharge and of seawater recycling is controlled by local hydrogeological variability. The coastal aquifer in Dor Bay is composed of two units: a partly confined calcaranitic sandstone (Kurkar) and an overlying loose sand. Groundwater in the Kurkar has elevated activities of 222Rn (∼390 dpm/L) and relatively low 224Ra/223Ra activity ratios (3–4), while the sand groundwater is significantly less radiogenic (6–90 dpm/L) and shows higher 224Ra/223Ra ratios. Groundwater discharging from sand-covered areas of the bay has salinities of 16–31 and an average 222Rn activity of 168 dpm/L, which lies on a mixing line between Rn-rich Kurkar fresh water and Rn-poor seawater. Another key observation is that seawater infiltrates to some extent into onshore sand groundwater, while the fresh water within the submarine Kurkar can be traced up to 40 m offshore. This implies that while fresh water mainly discharges from the Kurkar unit, seawater recycling is limited to the loose sand, and that the discharge from sand-covered areas is a mixture of Kurkar water with recycled seawater. Advection rates from the bay floor were calculated from Rn time series and found to vary between 0 and 36 cm/d, correlating negatively with bay water depth. The average flux was 8.1 cm/d, and it did not seem to change much during March, May, and July 2006. The average amount of fresh water discharging to the bay was 5.0 m3/d per meter of shoreline. Radon activity in the sand groundwater also fluctuates due to influx of Kurkar-type groundwater.

  7. On the Quality of Examples in Introductory Java Textbooks

    ERIC Educational Resources Information Center

    Borstler, Jurgen; Nordstrom, Marie; Paterson, James H.

    2011-01-01

    Example programs play an important role in the teaching and learning of programming. Students as well as teachers rank examples as the most important resources for learning to program. Example programs work as role models and must therefore always be consistent with the principles and rules we are teaching. However, it is difficult to find or…

  8. Groundwater quality assessment for the Upper East Fork Poplar Creek Hydrogeologic Regime at the Y-12 Plant. 1991 groundwater quality data and calculated rate of contaminant migration

    SciTech Connect

    Not Available

    1992-02-01

    This report contains groundwater quality data obtained during the 1991 calendar year at several waste management facilities and petroleum fuel underground storage tank (UST) sites associated with the Y-12 Plant. These sites are within the Upper East Fork Poplar Creek Hydrogeologic Regime (UEFPCHR), which is one of three regimes defined for the purposes of groundwater and surface-water quality monitoring and remediation. This report was prepared for informational purposes. Included are the analytical data for groundwater samples collected from selected monitoring wells during 1991 and the results for quality assurance/quality control (QA/QC) samples associated with each groundwater sample. This report also contains summaries of selected data, including ion-charge balances for each groundwater sample, a summary of analytical results for nitrate (a principle contaminant in the UEFPCHR), results of volatile organic compounds (VOCs) analyses validated using the associated QA/QC sample data, a summary of trace metal concentrations which exceeded drinking-water standards, and a summary of radiochemical analyses and associated counting errors.

  9. Elevated atmospheric carbon dioxide in agroecosystems affects groundwater quality

    SciTech Connect

    Torbert, H.A.; Prior, S.A.; Rogers, H.H.; Schlesinger, W.H.; Mullins, G.L.; Runion, G.B.

    1996-07-01

    Increasing atmospheric carbon dioxide (CO{sub 2}) concentration has led to concerns about global changes to the environment. One area of global change that has not been addressed is the effect of elevated atmospheric CO{sub 2} on groundwater quality below agroecosystems. Elevated CO{sub 2} concentration alterations of plant growth and C/N ratios may modify C and N cycling in soil and affect nitrate (NO{sub 3}{sup {minus}}) leaching to groundwater. This study was conducted to examine the effects of a legume (soybean [Glycine max (L.) Merr.]) and a nonlegume (grain sorghum [Sorghum bicolor (L.) Moench]) CO{sub 2}-enriched agroecosystems on NO{sub 3}{sup {minus}} movement below the root zone in a Blanton loamy sand (loamy siliceous, thermic, Grossarenic Paleudults). The study was a split-plot design replicated three times with plant species (soybean and grain sorghum) as the main plots and CO{sub 2} concentration ({approximately}360 and {approximately}720 {mu}L L{sup {minus}1} CO{sub 2}) as subplots using open-top field chambers. Fertilizer application was made with {sup 15}N-depleted NH{sub 4}NO{sub 3} to act as a fertilizer tracer. Soil solution samples were collected weekly at 90-cm depth for a 2-yr period and monitored for NO{sub 3}{sup {minus}}-N concentrations. Isotope analysis of soil solution indicated that the decomposition of organic matter was the primary source of No{sub 3}{sup {minus}}-N in soil solution below the root zone through most of the monitoring period. Significant differences were observed for NO{sub 3}{sup {minus}}-N concentrations between soybean and grain sorghum, with soybean having the higher NO{sub 3}{sup {minus}}-N concentration. Elevated CO{sub 2} increased total dry weight, total N content, and C/N ratio of residue returned to soil in both years. Elevated CO{sub 2} significantly decreased NO{sub 3}{sup {minus}}-N concentrations below the root zone in both soybean and grain sorghum. 37 refs., 2 figs., 2 tabs.

  10. Field demonstration of CO2 leakage detection and potential impacts on groundwater quality at Brackenridge Field Laboratory

    NASA Astrophysics Data System (ADS)

    Zou, Y.; Yang, C.; Guzman, N.; Delgado, J.; Mickler, P. J.; Horvoka, S.; Trevino, R.

    2015-12-01

    carbonates and some silicates and mobilization of heavy metals from the aquifer sediments to groundwater, however, such mobilization posed no risks on groundwater quality at this site. The pulse-like tests have demonstrated it is plausible to use chemical sensors for CO2 leakage detection in groundwater.

  11. Baseline evaluation of groundwater quality in central New York prior to shale gas development

    NASA Astrophysics Data System (ADS)

    McPhillips, L. E.; Creamer, A.; Walter, T.; Rahm, B.

    2012-12-01

    Though New York State has had some conventional natural gas drilling for over a century, new drilling technologies are being considered to access potentially vast natural gas resources in the Marcellus shale formation. In order to economically harvest the gas trapped within this formation, high-volume slickwater hydraulic fracturing ("fracking") technology is being combined with horizontal drilling techniques. Currently this practice is prevented by a moratorium in New York as potential environmental impacts of the process are being considered. One of the biggest concerns is the potential for groundwater contamination by either chemicals used in the hydraulic fracturing process or by methane gas. In the event that this technology is allowed in New York, it is critical that we have baseline water quality data to adequately assess the source of groundwater contamination. We collected such baseline data across Chenango County in central New York. Specifically, we collected groundwater samples from 120 homes across the county and analyzed them for dissolved solids and dissolved gases. We are using geostatistical methods on all sampled constituents to determine the natural baseline patterns observed across the county. We are also regressing analytes with a variety of ancillary characteristics including distance from existing conventional gas wells, topography, etc. Establishing a baseline for the metals and salts in these water samples will allow future assessment of contamination from fracking fluid. Results from dissolved gases provides information on how much methane is currently dissolved in the water as well as its source, which is determined by assessing the δ13C-CH4 composition of the methane. Gathering information such as this is essential to understanding the current state of our groundwater resources and thus being able to better assess any future impacts on these resources from issues such as gas drilling.

  12. Hydrogeochemistry and groundwater quality assessment of Ranipet industrial area, Tamil Nadu, India

    NASA Astrophysics Data System (ADS)

    Rao, G. Tamma; Rao, V. V. S. Gurunadha; Ranganathan, K.

    2013-06-01

    One of the highly polluted areas in India located at Ranipet occupies around 200 tanneries and other small scale chemical industries. Partially treated industrial effluents combined with sewage and other wastes discharged on the surface cause severe groundwater pollution in the industrial belt. This poses a problem of supply of safe drinking water in the rural parts of the country. A study was carried out to assess the groundwater pollution and identify major variables affecting the groundwater quality in Ranipet industrial area. Twenty five wells were monitored during pre- and post-monsoon in 2008 and analyzed for the major physico-chemical variables. The water quality variables such as total dissolved solids (TDS), Iron (Fe2 + ), Hexavalent Chromium (Cr6 + ), at most of the sampling locations exceeded the ISI and WHO guideline levels for drinking water. Multivariate statistical techniques such as factor analysis were applied to identify the major factors (variables) corresponding to the different source of variation in groundwater quality. The water quality of groundwater is influenced by both anthropogenic and chemical weathering. The most serious pollution threat to groundwater is from TDS, Cr6 + and Fe2 + , which are associated with sewage and pollution of tannery waste. The study reveals that the groundwater quality changed due to anthropogenic and natural influences such as agricultural, natural weathering process.

  13. Some special problems in the determination of viable counts of groundwater microorganisms.

    PubMed

    Hirsch, P; Rades-Rohkohl, E

    1988-07-01

    Factors affecting viable cell counts in groundwater or sediments were studied with samples from the Segeberg Forest test area in northern Germany. There was very little variation in results with the season (April, August, November) or depth of sampling; generally there were 10(3)-10(4) aerobic cells per ml or g sediment. Long incubation times resulted in higher cell counts; groundwater samples required 4-5 weeks, and sediment extracts had to be cultured for 7 weeks. Total cell counts in sediment were 10(2)-10(4) cell/g higher than viable cell counts of aerobes. This was explained partly by the additional presence of anaerobes and partly by the observation that some morphotypes may not have grown under our conditions. Viable cell counts were not influenced by cell extraction from the sediment with either Na-pyrophosphate or groundwater extracts. However, iron-precipitating or manganese-oxidizing bacteria were better extracted with sterile groundwater. The microflora of wells was more numerous than that of the free aquifer; consequently it was better to pump off all well water before aquifer water was sampled. The diameter of the well was also important; thinner tubes had higher cell counts than those with wider diameter. For sampling, wells should be at least 1 year old, since young wells contain higher numbers of microorganisms due to underground disturbances from the drilling. Turbid water samples could be clarified by filtration, but this reduced the viable counts by 1-2 orders of magnitude. Two different media inoculated with a sample dilution resulted in the same cell counts, but their microbial diversity was different. Storage of groundwater samples before processing resulted in up to 17-fold increases in cell counts and loss of diversity in the first 24 hours. Cell numbers decreased slowly during longer storage. PMID:24201536

  14. Status and understanding of groundwater quality in the San Diego Drainages Hydrogeologic Province, 2004: California GAMA Priority Basin Project

    USGS Publications Warehouse

    Wright, Michael T.; Belitz, Kenneth

    2011-01-01

    Groundwater quality in the approximately 3,900-square-mile (mi2) San Diego Drainages Hydrogeologic Province (hereinafter San Diego) study unit was investigated from May through July 2004 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is located in southwestern California in the counties of San Diego, Riverside, and Orange. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The GAMA San Diego study was designed to provide a statistically robust assessment of untreated-groundwater quality within the primary aquifer systems. The assessment is based on water-quality and ancillary data collected by the USGS from 58 wells in 2004 and water-quality data from the California Department of Public Health (CDPH) database. The primary aquifer systems (hereinafter referred to as the primary aquifers) were defined by the depth interval of the wells listed in the California Department of Public Health (CDPH) database for the San Diego study unit. The San Diego study unit consisted of four study areas: Temecula Valley (140 mi2), Warner Valley (34 mi2), Alluvial Basins (166 mi2), and Hard Rock (850 mi2). The quality of groundwater in shallow or deep water-bearing zones may differ from that in the primary aquifers. For example, shallow groundwater may be more vulnerable to surficial contamination than groundwater in deep water-bearing zones. This study had two components: the status assessment and the understanding assessment. The first component of this study-the status assessment of the current quality of the groundwater resource-was assessed by using data from samples analyzed for volatile organic compounds (VOC), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. The status assessment is intended to

  15. Waste deposit influences on groundwater quality as a tool for waste type and site selection for final storage quality

    NASA Astrophysics Data System (ADS)

    Arneth, Jan-Dirk; Milde, Gerald; Kerndorff, Helmut; Schleyer, Ruprecht

    Leachates from deposits of wastes may, in the long run, adversely influence groundwater quality. Since tipping still constitutes the most important form of waste disposal, strategies must be developed which are capable of protecting groundwater against contamination from leachates. In the first instance such protective measures must provide for a minimization of contamination by setting up optimal barriers. Since it would seem difficult to reach this goal in a forseeable future, the avoidance of substances with a high potential for groundwater hazards has to be attributed much importance. In former times, little attention was given to impermeability or avoidance of substances with a high potential for groundwater hazards contained in wastes. Therefore, results of the investigation of groundwater near abandoned sites can be used to optimize groundwater protection on future tipping sites. In the present study, the results of chemical investigation of groundwater from the vicinity of 92 waste disposal sites in the Federal Republic of Germany are presented and the changes in groundwater quality owing to the penetration of leachates are discussed separately for inorganic and organic contaminants.

  16. Estimating impacts of land use on groundwater quality using trilinear analysis.

    PubMed

    Ouyang, Ying; Zhang, Jia En; Cui, Lihua

    2014-09-01

    Groundwater is connected to the landscape above and is thus affected by the overlaying land uses. This study evaluated the impacts of land uses upon groundwater quality using trilinear analysis. Trilinear analysis is a display of experimental data in a triangular graph. Groundwater quality data collected from agricultural, septic tank, forest, and wastewater land uses for a 6-year period were used for the analysis. Results showed that among the three nitrogen species (i.e., nitrate and nitrite (NO(x)), dissolved organic nitrogen (DON), and total organic nitrogen (TON)), NO(x) had a high percentage and was a dominant species in the groundwater beneath the septic tank lands, whereas TON was a major species in groundwater beneath the forest lands. Among the three phosphorus species, namely the particulate phosphorus (PP), dissolved ortho phosphorus (PO4(3-)) and dissolved organic phosphorus (DOP), there was a high percentage of PP in the groundwater beneath the septic tank, forest, and agricultural lands. In general, Ca was a dominant cation in the groundwater beneath the septic tank lands, whereas Na was a dominant cation in the groundwater beneath the forest lands. For the three major anions (i.e., F(-), Cl(-), and SO4(2-)), F(-) accounted for <1% of the total anions in the groundwater beneath the forest, wastewater, and agricultural lands. Impacts of land uses on groundwater Cd and Cr distributions were not profound. This study suggests that trilinear analysis is a useful technique to characterize the relationship between land use and groundwater quality. PMID:24802588

  17. Positive and negative impacts of five Austrian gravel pit lakes on groundwater quality.

    PubMed

    Muellegger, Christian; Weilhartner, Andreas; Battin, Tom J; Hofmann, Thilo

    2013-01-15

    Groundwater-fed gravel pit lakes (GPLs) affect the biological, organic, and inorganic parameters of inflowing groundwater through combined effects of bank filtration at the inflow, reactions within the lake, and bank filtration at the outflow. GPLs result from wet dredging for sand and gravel and may conflict with groundwater protection programs by removing the protective soil cover and exposing groundwater to the atmosphere. We have investigated the impact on groundwater of five GPLs with different sizes, ages, and mean residence times, and all having low post-excavation anthropogenic usage. The results revealed highly active biological systems within the lake water, in which primary producers significantly reduced inflowing nitrate concentrations. Decalcification also occurred in lake water, reducing water hardness, which could be beneficial for waterworks in hard groundwater areas. Downgradient groundwater nitrate and calcium concentrations were found to be stable, with only minor seasonal variations. Biological degradation of organic material and organic micropollutants was also observed in the GPLs. For young GPLs adequate sediment deposits may not yet have formed and degradation processes at the outflow may consequently not yet be well established. However, our results showed that within 5 years from the cessation of excavation a protective sediment layer is established that is sufficient to prevent the export of dissolved organic carbon to downgradient groundwater. GPLs can improve groundwater quality in anthropogenically (e.g., pesticides and nitrate) or geologically (e.g., hardness) challenging situations. However, post-excavation usage of GPLs is often dominated by human activities such as recreational activities, water sports, or fish farming. These activities will affect lake and groundwater quality and the risks involved are difficult to predict and monitor and can lead to overall negative impacts on groundwater quality. PMID:23178886

  18. The Soils and Groundwater – EM-20 S&T Roadmap Quality Assurance Project Plan

    SciTech Connect

    Fix, N. J.

    2008-02-11

    The Soils and Groundwater – EM-20 Science and Technology Roadmap Project is a U.S. Department of Energy, Office of Environmental Management-funded initiative designed to develop new methods, strategies and technology for characterizing, modeling, remediating, and monitoring soils and groundwater contaminated with metals, radionuclides, and chlorinated organics. This Quality Assurance Project Plan provides the quality assurance requirements and processes that will be followed by EM-20 Roadmap Project staff.

  19. Groundwater Science

    NASA Astrophysics Data System (ADS)

    McKenna, Sean A.

    A good introductory groundwater textbook must strike a delicate balance in presenting the basics of the physical, chemical, geological, mathematical, and engineering aspects of the groundwater field without being too lengthy or overly detailed. Charles Fitts states that his motivation for writing Groundwater Science was to be able to “…teach concepts and quantitative analyses with a clear, lean, but thorough book.” He has succeeded in striking this balance of having just the right amount of information, and has met his goals of producing a concise book that can be used to teach the concepts and analyses necessary for the study of groundwater.Overall, Groundwater Science would serve well as the text for an introductory groundwater course at the college senior or first-year graduate level. The author and the publisher have made excellent use of two-color, gray and blue-scale images throughout the book. The graphics are crisp and explanatory. Data sets needed to work some of the problems in the book are available as text files from its Web site (http://www.academicpress.com/groundwater). I found these files to be complete and easy to understand. The references are up to date and point the reader to additional information across a wide range of groundwater issues, and also provide a number of examples to illustrate different points made in the book.

  20. An innovative artificial recharge system to enhance groundwater storage in basaltic terrain: example from Maharashtra, India

    NASA Astrophysics Data System (ADS)

    Bhusari, Vijay; Katpatal, Y. B.; Kundal, Pradeep

    2016-08-01

    The management of groundwater poses challenges in basaltic terrain as its availability is not uniform due to the absence of primary porosity. Indiscriminate excessive withdrawal from shallow as well as deep aquifers for meeting increased demand can be higher than natural recharge, causing imbalance in demand and supply and leading to a scarcity condition. An innovative artificial recharge system has been conceived and implemented to augment the groundwater sources at the villages of Saoli and Sastabad in Wardha district of Maharashtra, India. The scheme involves resectioning of a stream bed to achieve a reverse gradient, building a subsurface dam to arrest subsurface flow, and installation of recharge shafts to recharge the deeper aquifers. The paper focuses on analysis of hydrogeological parameters like porosity, specific yield and transmissivity, and on temporal groundwater status. Results indicate that after the construction of the artificial recharge system, a rise of 0.8-2.8 m was recorded in the pre- and post-monsoon groundwater levels in 12 dug wells in the study area; an increase in the yield was also noticed which solved the drinking water and irrigation problems. Spatial analysis was performed using a geographic information system to demarcate the area of influence of the recharge system due to increase in yields of the wells. The study demonstrates efficacy, technical viability and applicability of an innovative artificial recharge system constructed in an area of basaltic terrain prone to water scarcity.

  1. An innovative artificial recharge system to enhance groundwater storage in basaltic terrain: example from Maharashtra, India

    NASA Astrophysics Data System (ADS)

    Bhusari, Vijay; Katpatal, Y. B.; Kundal, Pradeep

    2016-03-01

    The management of groundwater poses challenges in basaltic terrain as its availability is not uniform due to the absence of primary porosity. Indiscriminate excessive withdrawal from shallow as well as deep aquifers for meeting increased demand can be higher than natural recharge, causing imbalance in demand and supply and leading to a scarcity condition. An innovative artificial recharge system has been conceived and implemented to augment the groundwater sources at the villages of Saoli and Sastabad in Wardha district of Maharashtra, India. The scheme involves resectioning of a stream bed to achieve a reverse gradient, building a subsurface dam to arrest subsurface flow, and installation of recharge shafts to recharge the deeper aquifers. The paper focuses on analysis of hydrogeological parameters like porosity, specific yield and transmissivity, and on temporal groundwater status. Results indicate that after the construction of the artificial recharge system, a rise of 0.8-2.8 m was recorded in the pre- and post-monsoon groundwater levels in 12 dug wells in the study area; an increase in the yield was also noticed which solved the drinking water and irrigation problems. Spatial analysis was performed using a geographic information system to demarcate the area of influence of the recharge system due to increase in yields of the wells. The study demonstrates efficacy, technical viability and applicability of an innovative artificial recharge system constructed in an area of basaltic terrain prone to water scarcity.

  2. The precautionary principle and chemicals management: The example of perfluoroalkyl acids in groundwater.

    PubMed

    Cousins, Ian T; Vestergren, Robin; Wang, Zhanyun; Scheringer, Martin; McLachlan, Michael S

    2016-09-01

    Already in the late 1990s microgram-per-liter levels of perfluorooctane sulfonate (PFOS) were measured in water samples from areas where fire-fighting foams were used or spilled. Despite these early warnings, the problems of groundwater, and thus drinking water, contaminated with perfluoroalkyl and polyfluoroalkyl substances (PFASs) including PFOS are only beginning to be addressed. It is clear that this PFAS contamination is poorly reversible and that the societal costs of clean-up will be high. This inability to reverse exposure in a reasonable timeframe is a major motivation for application of the precautionary principle in chemicals management. We conclude that exposure can be poorly reversible; 1) due to slow elimination kinetics in organisms, or 2) due to poorly reversible environmental contamination that leads to continuous exposure. In the second case, which is relevant for contaminated groundwater, the reversibility of exposure is not related to the magnitude of a chemical's bioaccumulation potential. We argue therefore that all PFASs entering groundwater, irrespective of their perfluoroalkyl chain length and bioaccumulation potential, will result in poorly reversible exposures and risks as well as further clean-up costs for society. To protect groundwater resources for future generations, society should consider a precautionary approach to chemicals management and prevent the use and release of highly persistent and mobile chemicals such as PFASs. PMID:27337597

  3. Conceptual Change in Physical Geography and Environmental Sciences through Mental Model Building: The Example of Groundwater

    ERIC Educational Resources Information Center

    Reinfried, Sibylle

    2006-01-01

    This research tested the hypothesis that students' erroneous mental models about groundwater will change towards more valid concepts if they are taught on the basis of a mental model-building strategy that focuses on the clarification of students' misconceptions. To examine the hypothesis a quasi-experimental research design was chosen. The…

  4. Stratabound pathways of preferred groundwater flow: An example from the Copper Ridge Dolomite in East Tennessee

    SciTech Connect

    Lee, R.; Ketelle, D.

    1987-07-14

    The Copper Ridge Dolomite of the Upper Cambrian Knox Group underlies a site at Oak Ridge, Tennessee under consideration by the Department of Energy (DOE) for a below ground waste disposal facility. The Copper Ridge was studied for DOE to understand the influence of lithology on deep groundwater flow. Three facies types are distinguished which comprise laterally continuous, 1 to 4 m thick rock units interpreted to represent upward-shallowing depositional cycles having an apparently significant effect on groundwater flow at depth. Rock core observations indicate one of the recurring facies types is characterized by thin to medium-bedded, fine-grained dolostone with planar cryptalgal laminae and thin shaley partings. Distinctive fracturing in this facies type, that may have resulted from regional structural deformation, it considered to be responsible for weathering at depth and the development of stratabound pathways of preferred groundwater flow. In addition, geophysical data suggest that one occurrence of this weathered facies type coincides with an apparent geochemical interface at depth. Geophysical data also indicate the presence of several fluid invasion horizons, traceable outside the study area, which coincide with the unweathered occurrence of this fine-grained facies type. The subcropping of recurrent zones of preferred groundwater flow at the weathered/unweathered interface may define linear traces of enhanced aquifer recharge paralleling geologic strike. Vertical projection of these zones from the weathered/unweathered rock interface to the ground surface may describe areas of enhanced infiltration. Tests to determine the role of stratigraphic controls on groundwater flow are key components of future investigations on West Chestnut Ridge. 14 refs., 13 figs.

  5. 41 CFR 102-41.210 - What are some examples of drug paraphernalia?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 41 Public Contracts and Property Management 3 2013-07-01 2013-07-01 false What are some examples of drug paraphernalia? 102-41.210 Section 102-41.210 Public Contracts and Property Management Federal... pipes with or without screens, permanent screens, hashish heads, or punctured metal bowls; (b)...

  6. Communicating Comparative Findings from Meta-Analysis in Educational Research: Some Examples and Suggestions

    ERIC Educational Resources Information Center

    Higgins, Steve; Katsipataki, Maria

    2016-01-01

    This article reviews some of the strengths and limitations of the comparative use of meta-analysis findings, using examples from the Sutton Trust-Education Endowment Foundation Teaching and Learning "Toolkit" which summarizes a range of educational approaches to improve pupil attainment in schools. This comparative use of quantitative…

  7. 36 CFR 51.39 - What are some examples of outfitter and guide concession contracts?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... outfitter and guide concession contracts? 51.39 Section 51.39 Parks, Forests, and Public Property NATIONAL... What are some examples of outfitter and guide concession contracts? Outfitter and guide concession... guided conduct of river running, hunting (where otherwise lawful in a park area), fishing,...

  8. Analogies and "Modeling Analogies" in Teaching: Some Examples in Basic Electricity.

    ERIC Educational Resources Information Center

    Dupin, J. J.; Johsua, S.

    1989-01-01

    Investigates the effect of modeling analogy on learning of the concepts of electricity in grade 6, 8, and 10. Describes 2 analogies (train analogy and thermal analogy) with diagrams and examples. Discusses the accessibility, transferability, and difficulty of each analogy. Reports treatment effect and some further implications. (YP)

  9. Evaluation of Groundwater Quality Characteristics in Lagos-City

    NASA Astrophysics Data System (ADS)

    Yusuf, K. A.

    Most of the water requirement for Lagos is met from surface and ground water supplies. Lagos an industrial and highly populated city located in the Southwest Nigeria has urban migration problems and resource limitations. However, as found in many cities, a certain proportion of the population is forced to rely on the well water as sources of drinking water, a poor drinking water quality that may have health consequences. A study was therefore carried out to gain an idea of the inorganic quality of the water in the wells penetrating the shallow (< 20 m thick) alluvial aquifer in the city. Results from this study revealed that some of the ground water quality constituents exceeded the World Health Organization (WHO) standards for drinking water irrespective of the sources of pollution: the total dissolved solids limit in 50%, the conductivity limit in 27.8%, the lead limit in 38.9%, the pH limit in 44.4% and the sodium and calcium limits in 11.1% of the samples. Thus, ground water from some of these wells requires further purification to ensure its fitness for human consumption.

  10. Groundwater levels and water quality during a 96-hour aquifer test in Pickaway County, Ohio, 2012

    USGS Publications Warehouse

    Haefner, Ralph J.; Runkle, Donna L.; Mailot, Brian E.

    2014-01-01

    During October–November 2012, a 96-hour aquifer test was performed at a proposed well field in northern Pickaway County, Ohio, to investigate groundwater with elevated nitrate concentrations. Earlier sampling done by the City of Columbus revealed that some wells had concentrations of nitrate that approached 10 milligrams per liter (mg/L), whereas other wells and the nearby Scioto River had concentrations from 2 to 6 mg/L. The purpose of the current test was to examine potential changes in water quality that may be expected if the site was developed into a public water-supply source; therefore, water-transmitting properties determined during a previous test were not determined a second time. Before and during the test, water-level data and water-quality samples were obtained from observation wells while a test production well was pumped at 1,300 gallons per minute. Before the test, local groundwater levels indicated that groundwater was being discharged to the nearby Scioto River, but during the test, the stream was losing streamflow owing to infiltration. Water levels declined in the pumping well, in adjacent observation wells, and in a nearby streambed piezometer as pumping commenced. The maximum drawdown in the pumping well was 29.75 feet, measured about 95 hours after pumping began. Water-quality data, including analyses for field parameters, major and trace elements, nutrients, and stable isotopes of oxygen and nitrogen in nitrate, demonstrated only small variations before and during the test. Concentrations of nitrate in five samples from the pumping well ranged from about 5.10 to 5.42 mg/L before and during the test, whereas concentrations of nitrate in five samples on or about the same sampling dates and times at a monitoring site on the Scioto River adjacent to the pumping well ranged from 3.46 to 4.97 mg/L. Water from two nearby observation wells had nitrate concentrations approaching 10 mg/L, which is the U.S. Environmental Protection Agency’s Maximum

  11. Hydrochemical characteristics and quality assessment of groundwater along the Manavalakurichi coast, Tamil Nadu, India

    NASA Astrophysics Data System (ADS)

    Srinivas, Y.; Aghil, T. B.; Hudson Oliver, D.; Nithya Nair, C.; Chandrasekar, N.

    2015-09-01

    The present study was carried out to find the groundwater quality of coastal aquifer along Manavalakurichi coast. For this study, a total of 30 groundwater samples were collected randomly from open wells and borewells. The concentration of major ions and other geochemical parameters in the groundwater were analyzed in the laboratory by adopting standard procedures suggested by the American Public Health Association. The order of the dominant cations in the study area was found to be Na+ > Ca2+ > Mg2+ > K+, whereas the sequence of dominant anions was {{Cl}}^{ - } > {{HCO}}3^{ - } > {{SO}}4^{2 - } . The hydrogeochemical facies of the groundwater samples were studied by constructing piper trilinear diagram which revealed the evidence of saltwater intrusion into the study area. The obtained geochemical parameters were compared with the standard permissible limits suggested by the World Health Organization and Indian Standard Institution to determine the drinking water quality in the study area. The analysis suggests that the groundwater from the wells W25 and W26 is unsuitable for drinking. The suitability of groundwater for irrigation was studied by calculating percent sodium, sodium absorption ratio and residual sodium carbonate values. The Wilcox and USSL plots were also prepared. It was found that the groundwater from the stations W1, W25 and W26 is unfit for irrigation. The Gibbs plots were also sketched to study the mechanisms controlling the geochemical composition of groundwater in the study area.

  12. Palaeosol control on groundwater flow and pollutant distribution: the example of arsenic.

    PubMed

    McArthur, John M; Nath, Bibhash; Banerjee, Dhiraj M; Purohit, R; Grassineau, N

    2011-02-15

    The consumption of groundwater polluted by arsenic (As) has a severe and adverse effect on human health, particularly where, as happens in parts of SE Asia, groundwater is supplied largely from fluvial/deltaic aquifers. The lateral distribution of the As-pollution in such aquifers is heterogeneous. The cause of the heterogeneity is obscure. The location and severity of the As-pollution is therefore difficult to predict, despite the importance of such predictions to the protection of consumer health, aquifer remediation, and aquifer development. To explain the heterogeneity, we mapped As-pollution in groundwater using 659 wells across 102 km(2) of West Bengal, and logged 43 boreholes, to reveal that the distribution of As-pollution is governed by subsurface sedimentology. Across 47 km(2) of contiguous palaeo-interfluve, we found that the shallow aquifer (<70 mbgl) is unpolluted by As (<10 μg/L) because it is capped by an impermeable palaeosol of red clay (the last glacial maximum palaeosol, or LGMP, of ref 1 ) at depths between 16 and 24 mbgl. The LGMP protects the aquifer from vertical recharge that might carry As-rich water or dissolved organic matter that might drive reduction of sedimentary iron oxides and so release As to groundwater. In 55 km(2) of flanking palaeo-channels, the palaeosol is absent, so invasion of the aquifer by As and dissolved organic matter can occur, so palaeo-channel groundwater is mostly polluted by As (>50 μg/L). The role of palaeosols and, in particular, the LGMP, has been overlooked as a control on groundwater flow and pollutant movement in deltaic and coastal aquifers worldwide. Models of pollutant infiltration in such environments must include the appreciation that, where the LGMP (or other palaeosols) are present, recharge moves downward in palaeo-channel regions that are separated by palaeo-interfluvial regions where vertical recharge to underlying aquifers cannot occur and where horizontal flow occurs above the LGMP and any

  13. Estimates of tracer-based piston-flow ages of groundwater from selected sites-National Water-Quality Assessment Program, 1992-2005

    USGS Publications Warehouse

    Hinkle, Stephen R.; Shapiro, Stephanie D.; Plummer, L. Niel; Busenberg, Eurybiades; Widman, Peggy K.; Casile, Gerolamo C.; Wayland, Julian E.

    2011-01-01

    This report documents selected age data interpreted from measured concentrations of environmental tracers in groundwater from 1,399 National Water-Quality Assessment (NAWQA) Program groundwater sites across the United States. The tracers of interest were chlorofluorocarbons (CFCs), sulfur hexafluoride (SF6), and tritium/helium-3 (3H/3He). Tracer data compiled for this analysis primarily were from wells representing two types of NAWQA groundwater studies - Land-Use Studies (shallow wells, usually monitoring wells, in recharge areas under dominant land-use settings) and Major-Aquifer Studies (wells, usually domestic supply wells, in principal aquifers and representing the shallow, used resource). Reference wells (wells representing groundwater minimally impacted by anthropogenic activities) associated with Land-Use Studies also were included. Tracer samples were collected between 1992 and 2005, although two networks sampled from 2006 to 2007 were included because of network-specific needs. Tracer data from other NAWQA Program components (Flow System Studies, which are assessments of processes and trends along groundwater flow paths, and various topical studies) were not compiled herein. Tracer data from NAWQA Land-Use Studies and Major-Aquifer Studies that previously had been interpreted and published are compiled herein (as piston-flow ages), but have not been reinterpreted. Tracer data that previously had not been interpreted and published are evaluated using documented methods and compiled with aqueous concentrations, equivalent atmospheric concentrations (for CFCs and SF6), estimates of tracer-based piston-flow ages, and selected ancillary data, such as redox indicators, well construction, and major dissolved gases (N2, O2, Ar, CH4, and CO2). Tracer-based piston-flow ages documented in this report are simplistic representations of the tracer data. Tracer-based piston-flow ages are a convenient means of conceptualizing groundwater age. However, the piston

  14. Evaluating the suitability of groundwater for irrigational purposes in some selected districts of the Upper West region of Ghana

    NASA Astrophysics Data System (ADS)

    Salifu, Musah; Aidoo, Felix; Hayford, Michael Saah; Adomako, Dickson; Asare, Enoch

    2015-03-01

    Groundwater is a very important asset to the people of the Upper West region of the Ghana where majority of them are farmers. Groundwater serves as the most reliable source of water for their domestic and agricultural activities. This study was aimed at assessing the suitability of groundwater for irrigational purposes in some selected communities of five districts where farming activities are very intensive. Twenty-three groundwater samples were collected and analysed for major anions and cations. Physicochemical parameters such as electrical conductivity (EC) and total dissolved solids (TDS) were also measured. From the results of the analyses and measurements, the suitability of the groundwater for irrigation were evaluated based on the TDS, EC, percentage sodium (%Na), sodium adsorption ratio (SAR), permeability index (PI), residual sodium carbonate (RSC), magnesium adsorption ratio (MAR), Kelly's ratio (KR) and chloro-alkaline Indices (CAI). US salinity laboratory diagram and Wilcox diagrams were also applied. The EC results show that the groundwater in the study area can be classified as none and slight to moderate. According to the US salinity diagram, groundwater in the study area falls within the low salinity-low sodium hazard and medium salinity-low sodium hazard class. The %Na and the resulting Wilcox diagram also classify the groundwater as excellent to good and good to permissible. The groundwater in the study area is generally good for irrigation purposes. However, there are few instances which are problematic and would require special irrigation methods.

  15. Groundwater source assessment program for the state of Hawaii, USA: methodology and example application

    NASA Astrophysics Data System (ADS)

    Whittier, Robert B.; Rotzoll, Kolja; Dhal, Sushant; El-Kadi, Aly I.; Ray, Chittaranjan; Chang, Daniel

    2010-05-01

    The 1996 reauthorization of the Safe Drinking Water Act required that each state in the US addresses the protection of public drinking water sources, including the development and implementation of a source-water assessment program. Such a program includes delineating source-water assessment areas, inventorying potential contaminant sources within this area, and determining the water system's susceptibility to contamination. The public was also involved in various phases of the program. Hawaii’s groundwater source assessment program is presented, along with an approach for implementation, which is consistent with federal requirements. The approach integrates groundwater models, aquifer databases, and a geographic information system. Source assessment areas were delineated by using numerical groundwater-flow models that used site-specific data to their fullest availability. The proposed approach is flexible enough to allow easy future updates as more sources are identified or as new information becomes available. The final product includes numerical scores that quantify the relative source susceptibility to contamination. Aquifer models developed in this study are potentially useful for future site-specific protection efforts or for other modeling purposes.

  16. Hydrochemistry of urban groundwater, Seoul, Korea: the impact of subway tunnels on groundwater quality.

    PubMed

    Chae, Gi-Tak; Yun, Seong-Taek; Choi, Byoung-Young; Yu, Soon-Young; Jo, Ho-Young; Mayer, Bernhard; Kim, Yun-Jong; Lee, Jin-Yong

    2008-10-23

    Hydrogeologic and hydrochemical data for subway tunnel seepage waters in Seoul (Republic of Korea) were examined to understand the effect of underground tunnels on the degradation of urban groundwater. A very large quantity of groundwater (up to 63 million m3 year(-1)) is discharged into subway tunnels with a total length of 287 km, resulting in a significant drop of the local groundwater table and the abandonment of groundwater wells. For the tunnel seepage water samples (n = 72) collected from 43 subway stations, at least one parameter among pathogenic microbes (total coliform, heterotrophic bacteria), dissolved Mn and Fe, NH4+, NO3(-), turbidity, and color exceeded the Korean Drinking Water Standards. Locally, tunnel seepage water was enriched in dissolved Mn (avg. 0.70 mg L(-1), max. 5.58 mg L(-1)), in addition to dissolved Fe, NH4+, and pathogenic microbes, likely due to significant inflow of sewage water from broken or leaking sewer pipes. Geochemical modeling of redox reactions was conducted to simulate the characteristic hydrochemistry of subway tunnel seepage. The results show that variations in the reducing conditions occur in urban groundwater, dependent upon the amount of organic matter-rich municipal sewage contaminating the aquifer. The organic matter facilitates the reduction and dissolution of Mn- and Fe-bearing solids in aquifers and/or tunnel construction materials, resulting in the successive increase of dissolved Mn and Fe. The present study clearly demonstrates that locally significant deterioration of urban groundwater is caused by a series of interlinked hydrogeologic and hydrochemical changes induced by underground tunnels. PMID:18725171

  17. Ground-Water Quality Data in the Coachella Valley Study Unit, 2007: Results from the California GAMA Program

    USGS Publications Warehouse

    Goldrath, Dara A.; Wright, Michael T.; Belitz, Kenneth

    2009-01-01

    ground water. A quality-control sample (blank, replicate, or matrix spike) was collected at approximately one quarter of the wells, and the results for these samples were used to evaluate the quality of the data for the ground-water samples. Assessment of the quality-control information resulted in V-coding less than 0.1 percent of the data collected. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, and (or) blended with other waters to maintain acceptable water quality. Regulatory thresholds apply to treated water that is supplied to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and the California Department of Public Health (CDPH) and thresholds established for aesthetic purposes (secondary maximum contaminant levels, SMCL-CA) by CDPH. Most constituents detected in ground-water samples were at concentrations below drinking-water thresholds. Volatile organic compounds, pesticides, and pesticide degradates were detected in less than one-third of the grid well samples collected. All VOC and pesticide concentrations measured were below health-based thresholds. Potential waste-water indicators were detected in less than half of the wells sampled, and no detections were above health-based thresholds. Perchlorate was detected in seven grid wells; concentrations from two wells were above the CDPH maximum contaminant level (MCL-CA). Most detections of trace elements in samples collected from COA Study Unit wells were below water-quality thresholds. Exceptions include five samples of arsenic that were above the USEPA maximum contaminant level (MCL-US), two detections of boron above the CDPH notification level (NL-CA), and two detections of mol

  18. Hydrochemical characteristics and the effects of irrigation on groundwater quality in Harran Plain, GAP Project, Turkey

    NASA Astrophysics Data System (ADS)

    Yesilnacar, M. Irfan; Gulluoglu, M. Said

    2008-03-01

    Improper design, faulty planning, mismanagement and incorrect operation of irrigation schemes are the principle reasons for the deterioration of groundwater quality in a large number of countries, in particular in semi-arid and arid regions. The aim of this study is to determine the dimensions of groundwater quality after surface irrigation was begun in the semi-arid Harran Plain. Physical and chemical parameters of the groundwater including pH, temperature, electrical conductivity (EC), sodium, potassium, calcium, magnesium, chloride, bicarbonate, sulphate, nitrate, nitrite, ammonium, total phosphorus, total organic carbon and turbidity were determined monthly during the 2006 water year. The quality of the groundwater in the study area was assessed hydrochemically in order to determine its suitability for human consumption and agricultural purposes. In the general plain, the EC values measured were considerably above the guide level of 650 μS/cm, while nitrate in particular was found in almost all groundwater samples to be significantly above the maximum admissible concentration of 50 mg/l for the quality of water intended for human consumption as per the international and national standards. Total hardness reveals that a majority of the groundwater samples fall in the very hard water category. Interpretation of analytical data shows that Ca HCO3 and Ca SO4 are the dominant hydrochemical facies in the study area.

  19. Assessment of Groundwater Quality for Irrigation in Coimbatore South Taluk, Coimbatore District, Tamil Nadu.

    PubMed

    Murali, K; Kumar, R D Swasthik; Elangovan, R

    2014-07-01

    The study was conducted to evaluate the suitability of ground water for irrigation purpose at twenty seven locations in Coimbatore South Taluk, Coimbatore District. The analytical result shows that Na and Cl are the dominant cation and anions respectively in the groundwater. The values of TDS and EC exceed the permissible limits at some locations due to increase in ionic concentrations. Based on SAR, RSC, US Salinity diagram and Wilcox diagram it is observed that the water ranges from excellent to good quality in most of the places and can be used for irrigation without any hazard. Gibbs variation diagram indicates that lithology is main controlling factor for water chemistry. However, the high SAR and RSC values at few locations restrict suitability for irrigation purpose. PMID:26563079

  20. Effects of residential wastewater treatment systems on ground-water quality in west-central Jefferson County, Colorado

    USGS Publications Warehouse

    Hall, Dennis C.; Hillier, D.E.; Nickum, Edward; Dorrance, W.G.

    1981-01-01

    The use of residential wastewater-treatment systems in Evergreen Meadows, Marshdale, and Herzman Mesa, Colo., has degraded ground-water quality to some extent in each community. Age of community; average lot size; slope of land surface; composition, permeability, and thickness of surficial material; density, size , and orientation of fractures; maintenance of wastewater-treatment systems; and presence of animals are factors possibly contributing to the degradation of ground-water quality. When compared with effluent from aeration-treatment tanks, effluent fom septic-treatment tanks is characterized by greater biochemical oxygen demand and greater concentrations of detergents. When compared with effluent from septic-treatment tanks, effluent from aeration-treatment tanks is characterized by greater concentrations of dissolved oxygen, nitrite, nitrate, sulfate, and dissolved solids. (USGS)

  1. Ground-water records for eastern Oklahoma, Part 2; water-quality records for wells, test-holes, and springs

    USGS Publications Warehouse

    Havens, John S.

    1978-01-01

    The U. S. Geological Survey has collected data on Oklahoma's ground-water resources since 1934. Most of these data were collected as part of specific ground-water studies conducted in cooperation with various Federal, State, and local agencies. Data on construction, yield, water levels, and other physical well parameters are given in 'Ground-Water Records for Northeastern Oklahoma, Part 1 - Records of Wells, Test Holes, and Springs' and in 'Ground-Water Records for Southeastern Oklahoma, Part 1 - Records of Wells, Test Holes, and Springs.' These reports are available from the U.S. Department of the Interior, Geological Survey, Rm. 621, 201 N.W. Third, Oklahoma City, OK 73102. Although some water-quality data for wells, test-holes, and springs have been published, they are scattered through a variety of reports and are not readily available on a regional basis. Furthermore, a considerable amount of data have never been published and can be obtained only from the files of the Geological Survey. The purpose of this report is to make available both published and unpublished water-quality records for approximately 1,740 wells, test-holes, and springs in 23 counties in northeastern Oklahoma and 16 counties in southeastern Oklahoma. Acknowledgment is extended to the many hundreds of individuals who have provided the data compiled in this report.

  2. Ground-Water Quality Data in the Coastal Los Angeles Basin Study Unit, 2006: Results from the California GAMA Program

    USGS Publications Warehouse

    Mathany, Timothy M.; Land, Michael; Belitz, Kenneth

    2008-01-01

    ] and dissolved noble gases also were measured to help identify the sources and ages of the sampled ground water. Quality-control samples (blanks, replicates, and samples for matrix spikes) were collected at approximately one-fourth of the wells, and the results for these samples were used to evaluate the quality of the data for the ground-water samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination was not a significant source of bias. Differences between replicate samples were within acceptable ranges, indicating acceptably low variability. Matrix spike recoveries were within acceptable ranges for most compounds. Assessment of the quality-control information resulted in applying ?V? codes to approximately 0.1 percent of the data collected for ground-water samples (meaning a constituent was detected in blanks as well as the corresponding environmental data). This study did not attempt to evaluate the quality of drinking water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, and (or) blended with other waters to maintain acceptable drinking-water quality. Regulatory thresholds are applied to the treated drinking water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with regulatory and non-regulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA), California Department of Public Health (CDPH, formerly California Department of Health Services [CADHS]) and thresholds established for aesthetic concerns (secondary maximum contaminant levels, SMCL-CA) by CDPH. Comparisons between data collected for this study and drinking-water thresholds are for illustrative purposes only, and are not indicative of compliance or non-compliance with those thresholds. VOCs were detected in alm

  3. Julius Edgar Lilienfeld Prize: Chaotic Dynamics in the Physical Sciences: Some Comments and Examples

    NASA Astrophysics Data System (ADS)

    Ott, Edward

    2014-03-01

    Chaos was first discovered by Poincare in his famous 1887 work on the motion of N >2 bodies interacting through gravitational attraction. Although steady progress was made by mathematicians following Poincare's work, widespread impact and development of chaos in the physical sciences is only comparatively recent, i.e., approximately starting in the 1970's. This talk will review this history and give some examples illustrating the types of questions, problems and results arising from perspectives resulting from widespread participation of physical scientists.

  4. The CHPRC Groundwater and Technical Integration Support (Master Project) Quality Assurance Management Plan

    SciTech Connect

    Fix, N. J.

    2009-04-03

    The scope of the CH2M Hill Plateau Remediation Company, LLC (CHPRC) Groundwater and Technical Integration Support (Master Project) is for Pacific Northwest National Laboratory staff to provide technical and integration support to CHPRC. This work includes conducting investigations at the 300-FF-5 Operable Unit and other groundwater operable units, and providing strategic integration, technical integration and assessments, remediation decision support, and science and technology. The projects under this Master Project will be defined and included within the Master Project throughout the fiscal year, and will be incorporated into the Master Project Plan. This Quality Assurance Management Plan provides the quality assurance requirements and processes that will be followed by the CHPRC Groundwater and Technical Integration Support (Master Project) and all releases associated with the CHPRC Soil and Groundwater Remediation Project. The plan is designed to be used exclusively by project staff.

  5. Quality of groundwater in the Agbabu oil sands area of the Ondo State, Nigeria

    NASA Astrophysics Data System (ADS)

    Ajayi, Owolabi

    1998-08-01

    The Agbabu area is currently the focus of geological investigations for oil sands by several multinational companies. Mining and associated activities will require substantial quantities of water, hence the aim of this study is to evaluate the groundwater quality in the area. Total dissolved solids in the range 1260-1460 mg I -1 exceed the upper limit of 1000 mg I -1 for fresh water, and indicate brackish, non-potable water. Using relevant indices, the groundwater is found to be not suitable for irrigated agriculture and most industrial uses without further treatment. On the basis of dominant cations and anions, the groundwater is classified as a sodium chloride (NaCl) type. Detailed and systematic hydrogeological study of the entire oil sands area is recommended to provide information on the nature, origin, occurrence and quality characteristics of the groundwater found in this area.

  6. Strategy Guideline: Quality Management in Existing Homes - Cantilever Floor Example

    SciTech Connect

    Taggart, J.; Sikora, J.; Wiehagen, J.; Wood, A.

    2011-12-01

    This guideline is designed to highlight the QA process that can be applied to any residential building retrofit activity. The cantilevered floor retrofit detailed in this guideline is included only to provide an actual retrofit example to better illustrate the QA activities being presented.

  7. Applicability of ELISA-based Determination of Pesticides for Groundwater Quality Monitoring

    NASA Astrophysics Data System (ADS)

    Tsuchihara, Takeo; Yoshimoto, Shuhei; Ishida, Satoshi; Imaizumi, Masayuki

    The principals and procedures of ELISA (Enzyme-linked Immunosorbent Assay)-based determination of pesticides (Fenitrothion) in environmental samples were reviewed, and the applicability of the ELISA method for groundwater quality monitoring were validated through the experimental tracer tests in soil columns and the field test in Okinoerabu Island. The test results showed that the ELISA method could be useful not only for screening but also for quantitative analysis of pesticides. In the experimental tracer tests in soil columns, the retardation of pesticides leaching compared with conservative tracers were observed. In the field test, the contamination of the pesticide was detected in groundwater samples in Okinoerabu Island, even though the targeted pesticide was considered to be applied to the upland field 4 months ago. In order to investigate the transport and fate of pesticides in groundwater taking into account retardation from the field to groundwater table and the residue in groundwater, continuous observations of pesticides in groundwater are in a strong need, and the ELISA method is applicable to the long-term quality groundwater monitoring.

  8. Quality of groundwater in the Coastal Plain Sands aquifer of the Akwa Ibom State, Nigeria

    NASA Astrophysics Data System (ADS)

    Ajayi, Owolabi; Umoh, Obot A.

    1998-08-01

    The Coastal Plain Sands Formation is exploited by most of the population of the Akwa Ibom State in southeastern Nigeria. The aquifer is mostly coarse-grained, pebbly and poorly sorted sands with minor clay intercalations. It is up to 1500 m thick near the coast, but only a few metres thick along the northeastern boundary. Groundwater occurs principally under unconfined conditions. Boreholes penetrating less than 130 m yield over 300 m 3 hr -1. The main groundwater flow direction is seaward from north to south. The probable location of the fresh water-sea water interface is seaward. Forty-two groundwater and two surface water samples were analysed. Groundwater quality meets the WHO standards for potability and is dominated by bicarbonates of Na, Ca and Mg. The Sodium Adsorption Ratio lies between 0.2 and 2.0, indicating that the water is suitable for irrigation. The area has very high annual rainfall exceeding 2000 mm annually. Groundwater recharge should be high, although it is recommended that groundwater levels and quality near the coast be monitored regularly, especially in urban areas with high groundwater abstraction, to detect the onset of sea water intrusion which remains a potential hazard in this area.

  9. Protecting groundwater quality with high frequency subsurface drip irrigation

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Nitrate pollution from agriculture is a significant problem in the groundwater of the San Joaquin Valley of California (SJV). Nitrate is very mobile in water and transport is directly related to both water and fertilizer management on a crop. Surface irrigation is the principal method used in the SJ...

  10. Quality of Working Life (QWL): Some Potential Applications to Education.

    ERIC Educational Resources Information Center

    Koch, E.L.

    1982-01-01

    Describes the emergence of the Quality of Working Life (QWL) approach to work organization. Discusses the benefits that may be gained by implementing this approach in education, for example in the areas of labor management negotiations, stress management, and staff development. (GC)

  11. Characterization of Groundwater Quality Based on Regional Geologic Setting in the Piedmont and Blue Ridge Physiographic Provinces, North Carolina

    USGS Publications Warehouse

    Harden, Stephen L.; Chapman, Melinda J.; Harned, Douglas A.

    2009-01-01

    exceedances, with groundwater from 61 of the 69 sampled wells having activities higher than the U.S. Environmental Protection Agency's proposed maximum contaminant level of 300 picocuries per liter. Overall, the Milton and the Raleigh and Charlotte geozones had the greatest number, eight each, of water-quality properties or constituents that exceeded applicable drinking-water criteria in at least one well. The Eastern Blue Ridge and Felsic intrusive geozones each had seven properties or constituents that exceeded criteria, and the Carolina slate geozone had six. Based on limited data, initial results of statistical comparison tests identified statistically significant differences in concentrations of some groundwater constituents among the geozones. Statistically significant differences in median values of specific conductance and median concentrations of calcium, potassium, sodium, bicarbonate, chloride, silica, ammonia, aluminum, antimony, cadmium, and uranium were identified between one or more geozone pairs. Overall, the groundwater constituents appear to be influenced most significantly by the Inner Piedmont, Carolina slate, and Felsic intrusive geozones. The study data indicate that grouping and evaluating analytical data on the basis of regional geozone setting can be useful for characterizing water-quality conditions in bedrock aquifers of the Piedmont and Blue Ridge Provinces of North Carolina.

  12. Groundwater potentiality mapping of hard-rock terrain in arid regions using geospatial modelling: example from Wadi Feiran basin, South Sinai, Egypt

    NASA Astrophysics Data System (ADS)

    Arnous, Mohamed O.

    2016-04-01

    Identifying a good site for groundwater exploitation in hard-rock terrains is a challenging task. In Sinai, Egypt, groundwater is the only source of water for local inhabitants. Interpretation of satellite data for delineation of lithological units and weathered zones, and for mapping of lineament density and their trends, provides a valuable aid for the location of groundwater promising areas. Complex deformational histories of the wide range of lithological formations add to the difficulty. Groundwater prospect mapping is a systematic approach that considers the major controlling factors which influence the aquifer and quality of groundwater. The presented study aims to delineate, identify, model and map groundwater potential zones in arid South Sinai using remote sensing data and a geographic information system (GIS) to prepare various hydromorphogeological thematic maps such as maps of slope, drainage density, lithology, landforms, structural lineaments, rainfall intensity and plan curvature. The controlling-factor thematic maps are each allocated a fixed score and weight, computed by using a linear equation approach. Furthermore, each weighted thematic map is statistically computed to yield a groundwater potential zone map of the study area. The groundwater potential zones thus obtained were divided into five categories (very poor, poor, moderate, good and very good) and were validated using the relation between the zone and the spatial distribution of productive wells and of previous geophysical investigations from a literature review. The results show the groundwater potential zones in the study area, and create awareness for better planning and management of groundwater resources.

  13. Ground-Water Quality Data in the Kern County Subbasin Study Unit, 2006 - Results from the California GAMA Program

    USGS Publications Warehouse

    Shelton, Jennifer L.; Pimentel, Isabel; Fram, Miranda S.; Belitz, Kenneth

    2008-01-01

    the wells, and the results for these samples were used to evaluate the quality of the data from the ground-water samples. Assessment of the quality-control information resulted in censoring of less than 0.4 percent of the data collected for ground-water samples. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, raw ground water typically is treated, disinfected, or blended with other waters to maintain acceptable water quality. Regulatory thresholds apply, not to the raw ground water, but to treated water that is served to the consumer. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and the California Department of Public Health (CDPH), and as well as with thresholds established for aesthetic concerns (secondary maximum contaminant levels, SMCL-CA) by CDPH. VOCs and pesticides each were detected in approximately 60 percent of the grid wells, and detections of all compounds but one were below health-based thresholds. The fumigant, 1,2-dibromo-3-chloropropane (DBCP), was detected above the USEPA maximum contaminant level (MCL-US) in one sample. Detections of most inorganic constituents were also below health-based thresholds. Constituents detected above health-based thresholds include: nitrate, (MCL-US, 2 samples), arsenic (MCL-US, 2 samples), and vanadium (California notification level, NL-CA, 1 sample). All detections of radioactive constituents were below health-based thresholds, although nine samples had activities of radon-222 above the lower proposed MCL-US. Most of the samples from KERN wells had concentrations of major elements, total dissolved solids, and trace elements below the non-enforceable thresholds set for aesthetic concerns.

  14. The impact of river restoration on the water quality of the surface water and groundwater in an Alpine catchment.

    NASA Astrophysics Data System (ADS)

    Chittoor Viswanathan, V.; Schirmer, M.

    2012-04-01

    The importance of river restoration projects can only be realized upon evaluating their success or failure in a region mainly with regards to water quality, ecological adaptations and flood mitigation. The Thur catchment in North eastern Switzerland is chosen as the study area. The water quality along the entire river reach (with the corresponding groundwater monitoring wells) will be analyzed with regard to the existing land use and a comparison shall be made with the water quality in the restored river sections of the river. A restored river section at Niederneunforn has been heavily monitored as part of the RECORD project and this data shall be vital for the present work. The water quality changes are to be observed by relating to some of the basic parameters like pH, electrical conductivity, dissolved oxygen, total organic carbon (TOC), total inorganic carbon (TIC) , the concentration of ions like chloride, nitrate, nitrite, ortho-phosphate, ammonium and calcium. These are to be measured in both the surface and the groundwater upstream and downstream of the restored section in the study river. Both long-term monitoring as well as localized water sampling campaigns are planned as part of the study. Use of the stable isotopes of oxygen and nitrogen is to be done to trace the possible sources of contamination in the river reach. This study shall aim to answer the following questions: 1. What are the diurnal and seasonal water quality changes in the Thur river; upstream and downstream of the restored section? 2. Are there any links between the different water quality parameters and how does the restored section influence these links? 3. How does the water quality change from the river to the groundwater (due to the recharge) between the restored and the unrestored river sections? 4. How does the land use in the catchment affect / alter the water quality in the river? -Is there high pollutant load from a particular waste water treatment or more agricultural runoff

  15. Estimation of impacts on groundwater quality in an urban area of Ljubljana

    NASA Astrophysics Data System (ADS)

    Janža, Mitja; Prestor, Joerg; Pestotnik, Simona; Jamnik, Brigita

    2016-04-01

    Groundwater is a major source of drinking water supply in many cities worldwide. It is relatively stable and better-protected water resource compared to surface water and will have a vital role in assuring water-supply security in the future. In urbanized catchments numerous human activities (e.g. settling, industry, traffic, agriculture) take place which pose a threat to groundwater quality. For sustainable management of urban groundwater resources an integrated and adaptive approach based on continuous monitoring supported by modeling is needed. The aim of presented study was to develop a model of environmental pressures and impacts on Ljubljansko polje aquifer which is the main source exploited for the public drinking water supply of the city of Ljubljana. It is based on estimation of contaminants emissions from different sources, coupled with numerical transport modelling which is used to assess the impact on groundwater quality. The model was built up on detailed analysis of nitrogen mass balance and validated with monitoring data - concentration measurements of relevant chemical parameters. Based on the model simulations impacts of different sources of pollution on groundwater quality was estimated and priority of measures for improvement of chemical status of groundwater was defined.

  16. Assessment of groundwater quality using geographical information system (GIS), at north-east Cairo, Egypt.

    PubMed

    El-Shahat, M F; Sadek, M A; Mostafa, W M; Hagagg, K H

    2016-04-01

    The present investigation has been conducted to delineate the hydrogeochemical and environmental factors that control the water quality of the groundwater resources in the north-east of Cairo. A complementary approach based on hydrogeochemistry and a geographical information system (GIS) based protectability index has been employed for conducting this work. The results from the chemical analysis revealed that the groundwater of the Quaternary aquifer is less saline than that of the Miocene aquifer and the main factors that control the groundwater salinity in the studied area are primarily related to the genesis of the original recharging water modified after by leaching, dissolution, cation exchange, and fertilizer leachate. The computed groundwater quality index (WQI) falls into two categories: fair for almost all the Miocene groundwater samples, while the Quaternary groundwater samples are all have a good quality. The retarded flow and non-replenishment of the Miocene aquifer compared to the renewable active recharge of the Quaternary aquifer can explain this variation of WQI. The index and overlay approach exemplified by the DUPIT index has been used to investigate the protectability of the study aquifers against diffuse pollutants. Three categories (highly protectable less vulnerable, moderately protectable moderately vulnerable and less protectable highly vulnerable) have been determined and areally mapped. PMID:27105417

  17. Status and understanding of groundwater quality in the South Coast Interior groundwater basins, 2008: California GAMA Priority Basin Project

    USGS Publications Warehouse

    Parsons, Mary C.; Kulongoski, Justin T.; Belitz, Kenneth

    2014-01-01

    Groundwater quality in the approximately 653-square-mile (1,691-square-kilometer) South Coast Interior Basins (SCI) study unit was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The South Coast Interior Basins study unit contains eight priority groundwater basins grouped into three study areas, Livermore, Gilroy, and Cuyama, in the Southern Coast Ranges hydrogeologic province. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The GAMA South Coast Interior Basins study was designed to provide a spatially unbiased assessment of untreated (raw) groundwater quality within the primary aquifer system, as well as a statistically consistent basis for comparing water quality between basins. The assessment was based on water-quality and ancillary data collected by the USGS from 50 wells in 2008 and on water-quality data from the California Department of Public Health (CDPH) database. The primary aquifer system was defined by the depth intervals of the wells listed in the CDPH database for the SCI study unit. The quality of groundwater in the primary aquifer system may be different from that in the shallower or deeper water-bearing zones; shallow groundwater may be more vulnerable to surficial contamination. The first component of this study, the status of the current quality of the groundwater resource, was assessed by using data from samples analyzed for volatile organic compounds (VOCs), pesticides, and naturally occurring inorganic constituents, such as trace elements and minor ions. This status assessment is intended to characterize the quality of groundwater resources within the primary aquifer system of the SCI study unit, not the treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentration

  18. Remote sensing application possibilities on groundwater characterization in arid regions at the example of the Dead Sea

    NASA Astrophysics Data System (ADS)

    Mallast, U.; Siebert, C.; Gloaguen, R.; Wagner, B.; Schwonke, F.; Rödiger, T.; Geyer, S.; Krieg, R.; Sauter, M.; Kühn, F.; Merz, R.

    2012-04-01

    Survey from 60 m), which hinders to accurately delineate spring-caused thermal plumes or to identify small scale springs or even spring types (terrestrial springs and submarine springs) (Mallast et al., 2012). As exactly this fact is important for subsequent studies we pursued an airborne thermal campaign in January, 2011 where technical specifications (0.5 m spatial resolution, flight time at night for higher contrast) were chosen to account for any so far observed spring type and scale. The result confirms the delineated areas from the satellite findings but refines these areas showing numerous and differentiable discharge locations. It also reveals unknown submarine spring locations and a third spring type where groundwater diffusely seeps through high saline Dead Sea sediments in contrast to the other spring types, with rather concentrated flow. The study shows at two application examples how remote sensing can be used for groundwater studies and also points at related advantages and disadvantages. Integrating these information into numerical groundwater modelling or sustainable water management strategies can significantly improve existing approaches and hence, yields a valuable benefits.

  19. Quality of groundwater from shallow wells of selected villages in Blantyre District, Malawi

    NASA Astrophysics Data System (ADS)

    Mkandawire, T.

    Access to adequate and safe drinking water still remains a challenge in developing countries. Some people especially in the rural areas use untreated surface and groundwater. An assessment of groundwater quality from shallow wells was carried out in nine villages in Blantyre district of Malawi. Water samples from nine randomly selected shallow wells (7 covered or protected and 2 open) were analysed for biological (total and faecal coliforms), chemical (hardness, nitrate, nitrite, sulphate, ammonia, pH, electrical conductivity and arsenic) and physical (total dissolved solids and turbidity) parameters of water using a portable water testing kit (Paqualab 50). Sampling was carried out four times during the year, i.e. twice in the dry season (August and October) and twice in the wet season (February and April) to find out if the quality of water changes with season. Results indicate that drinking water from shallow wells is heavily polluted by both total and faecal coliforms. The pollution level was higher in the wet season compared to the dry season. All the samples tested in the wet season did not meet the guideline value of 50 total coliforms (colony forming units) per 100 ml of the sample water (50 cfu/100 ml) set by the Malawi Ministry of Water Development (MoWD) for untreated water for drinking purposes (e.g. groundwater), while 22% of the samples met the guideline during the dry season. The difference in the contamination level between the dry and wet season was not significant for total coliforms ( p = 0.13 > 0.05). All chemical (hardness, nitrate, nitrite, sulphate, ammonia, pH, electrical conductivity and arsenic) and physical (total dissolved solids and turbidity) parameters tested except for turbidity were within the guideline values set by MoWD for untreated water. About 11% of the wells tested failed to meet the turbidity guideline value for the Ministry of Water Development of 25 NTU while about 22% failed to meet the World Health Organisation (WHO) and

  20. Model-based clustering of hydrochemical data to demarcate natural versus human impacts on bedrock groundwater quality in rural areas, South Korea

    NASA Astrophysics Data System (ADS)

    Kim, Kyoung-Ho; Yun, Seong-Taek; Park, Seong-Sook; Joo, Yongsung; Kim, Tae-Seung

    2014-11-01

    Improved evaluation of anthropogenic contamination is required to sustainably manage groundwater resources. In this study, we investigated the hydrochemical measurements of 18 parameters from a total of 102 bedrock groundwater samples from two representative rural areas in South Korea. We used model-based clustering with a normal (Gaussian) mixture model to differentiate the contributions of natural versus anthropogenic processes to the observed groundwater quality. Water samples varied in hydrochemistry from a Ca-Na-HCO3 type to a Ca-HCO3-Cl type. The former type reflected derivation of major ions largely from water-rock interactions, while the latter type recorded varying degrees of anthropogenic contamination. Among the major dissolved ions, fluoride and nitrate were shown to be good indicators of the two types, respectively. The results of model-based clustering showed that the bivariate normal mixture model, which was based on the covariance of nitrate and fluoride, was more robust than multivariate analysis, and provided better discrimination between the anthropogenic and natural groundwater groups. Model-based clustering to measure the degree of cluster membership for each sample also showed a gradual change in groundwater chemistry due to mixing between the two water groups. This study provided an example of the successful application of model-based clustering to evaluate regional groundwater quality and demonstrated that better selection of the dimensional structure (i.e., selection of optimal variables and number of clusters) based on hydrochemistry was crucial in obtaining reasonable clustering results.

  1. Salinity of deep groundwater in California: Water quantity, quality, and protection.

    PubMed

    Kang, Mary; Jackson, Robert B

    2016-07-12

    Deep groundwater aquifers are poorly characterized but could yield important sources of water in California and elsewhere. Deep aquifers have been developed for oil and gas extraction, and this activity has created both valuable data and risks to groundwater quality. Assessing groundwater quantity and quality requires baseline data and a monitoring framework for evaluating impacts. We analyze 938 chemical, geological, and depth data points from 360 oil/gas fields across eight counties in California and depth data from 34,392 oil and gas wells. By expanding previous groundwater volume estimates from depths of 305 m to 3,000 m in California's Central Valley, an important agricultural region with growing groundwater demands, fresh [<3,000 ppm total dissolved solids (TDS)] groundwater volume is almost tripled to 2,700 km(3), most of it found shallower than 1,000 m. The 3,000-m depth zone also provides 3,900 km(3) of fresh and saline water, not previously estimated, that can be categorized as underground sources of drinking water (USDWs; <10,000 ppm TDS). Up to 19% and 35% of oil/gas activities have occurred directly in freshwater zones and USDWs, respectively, in the eight counties. Deeper activities, such as wastewater injection, may also pose a potential threat to groundwater, especially USDWs. Our findings indicate that California's Central Valley alone has close to three times the volume of fresh groundwater and four times the volume of USDWs than previous estimates suggest. Therefore, efforts to monitor and protect deeper, saline groundwater resources are needed in California and beyond. PMID:27354527

  2. Salinity of deep groundwater in California: Water quantity, quality, and protection

    PubMed Central

    Kang, Mary; Jackson, Robert B.

    2016-01-01

    Deep groundwater aquifers are poorly characterized but could yield important sources of water in California and elsewhere. Deep aquifers have been developed for oil and gas extraction, and this activity has created both valuable data and risks to groundwater quality. Assessing groundwater quantity and quality requires baseline data and a monitoring framework for evaluating impacts. We analyze 938 chemical, geological, and depth data points from 360 oil/gas fields across eight counties in California and depth data from 34,392 oil and gas wells. By expanding previous groundwater volume estimates from depths of 305 m to 3,000 m in California’s Central Valley, an important agricultural region with growing groundwater demands, fresh [<3,000 ppm total dissolved solids (TDS)] groundwater volume is almost tripled to 2,700 km3, most of it found shallower than 1,000 m. The 3,000-m depth zone also provides 3,900 km3 of fresh and saline water, not previously estimated, that can be categorized as underground sources of drinking water (USDWs; <10,000 ppm TDS). Up to 19% and 35% of oil/gas activities have occurred directly in freshwater zones and USDWs, respectively, in the eight counties. Deeper activities, such as wastewater injection, may also pose a potential threat to groundwater, especially USDWs. Our findings indicate that California’s Central Valley alone has close to three times the volume of fresh groundwater and four times the volume of USDWs than previous estimates suggest. Therefore, efforts to monitor and protect deeper, saline groundwater resources are needed in California and beyond. PMID:27354527

  3. Groundwater quality in the Borrego Valley, Central Desert, and Low-Use Basins of the Mojave and Sonoran Deserts, California

    USGS Publications Warehouse

    Parsons, Mary C.; Belitz, Kenneth

    2014-01-01

    Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s untreated groundwater quality and increases public access to groundwater-quality information. Selected groundwater basins in the Borrego Valley, Central Desert, and Low-Use Basins of the Mojave and Sonoran Deserts constitute one of the study units being evaluated.

  4. Continuous resistivity profiling to delineate submarine groundwater discharge - Examples and limitations

    USGS Publications Warehouse

    Day-Lewis, F. D.; White, E.A.; Johnson, C.D.; Lane, J.W.; Belaval, M.

    2006-01-01

    Aquifer-ocean interaction, saline intrusion, and submarine groundwater discharge (SGD) are emerging topics in hydrology and oceanography with important implications for water-resource management and estuarine ecology. Although the threat of saltwater intrusion has long been recognized in coastal areas, SGD has, until recently, received much less attention. It is clear that SGD constitutes a major nutrient flux to coastal waters, with implications for estuarine ecology, eutrophication, and loss of coral reefs; however, fundamental questions regarding SGD remain unanswered: What are the spatial and temporal distributions of SGD offshore? How do seasonal and storm-related variations in aquifer recharge affect SGD flux and nutrient loading? What controls do aquifer structure and heterogeneity impose? How are SGD and saline recirculation related? Geophysical methods can provide insights to help answer these questions and improve the understanding of this intriguing and environmentally relevant hydrologic phenomenon. ?? 2006 Society of Exploration Geophysicists.

  5. Examples of Department of Energy Successes for Remediation of Contaminated Groundwater: Permeable Reactive Barrier and Dynamic Underground Stripping ASTD Projects

    SciTech Connect

    Purdy, C.; Gerdes, K.; Aljayoushi, J.; Kaback, D.; Ivory, T.

    2002-02-27

    Since 1998, the Department of Energy's (DOE) Office of Environmental Management has funded the Accelerated Site Technology Deployment (ASTD) Program to expedite deployment of alternative technologies that can save time and money for the environmental cleanup at DOE sites across the nation. The ASTD program has accelerated more than one hundred deployments of new technologies under 76 projects that focus on a broad spectrum of EM problems. More than 25 environmental restoration projects have been initiated to solve the following types of problems: characterization of the subsurface using chemical, radiological, geophysical, and statistical methods; treatment of groundwater contaminated with DNAPLs, metals, or radionuclides; and other projects such as landfill covers, purge water management systems, and treatment of explosives-contaminated soils. One of the major goals of the ASTD Program is to deploy a new technology or process at multiple DOE sites. ASTD projects are encouraged to identify subsequent deployments at other sites. Some of the projects that have successfully deployed technologies at multiple sites focusing on cleanup of contaminated groundwater include: Permeable Reactive Barriers (Monticello, Rocky Flats, and Kansas City), treating uranium and organics in groundwater; and Dynamic Underground Stripping (Portsmouth, and Savannah River), thermally treating DNAPL source zones. Each year more and more new technologies and approaches are being used at DOE sites due to the ASTD program. DOE sites are sharing their successes and communicating lessons learned so that the new technologies can replace the baseline or standard approaches at DOE sites, thus expediting cleanup and saving money.

  6. Assessment of Groundwater Quality in a Typical Rural Settlement in Southwest Nigeria

    PubMed Central

    Adekunle, I. M.; Adetunji, M. T.; Gbadebo, A. M.; Banjoko, O. B.

    2007-01-01

    In most rural settlements in Nigeria, access to clean and potable water is a great challenge, resulting in water borne diseases. The aim of this study was to assess the levels of some physical, chemical, biochemical and microbial water quality parameters in twelve hand – dug wells in a typical rural area (Igbora) of southwest region of the country. Seasonal variations and proximity to pollution sources (municipal waste dumps and defecation sites) were also examined. Parameters were determined using standard procedures. All parameters were detected up to 200 m from pollution source and most of them increased in concentration during the rainy season over the dry periods, pointing to infiltrations from storm water. Coliform population, Pb, NO3− and Cd in most cases, exceeded the World Health Organization recommended thresholds for potable water. Effect of distance from pollution sources was more pronounced on fecal and total coliform counts, which decreased with increasing distance from waste dumps. The qualities of the well water samples were therefore not suitable for human consumption without adequate treatment. Regular monitoring of groundwater quality, abolishment of unhealthy waste disposal practices and introduction of modern techniques are recommended. PMID:18180542

  7. Groundwater quality and hydrochemical properties of Al-Ula Region, Saudi Arabia.

    PubMed

    Toumi, Naji; Hussein, Belal H M; Rafrafi, Sarra; El Kassas, Neama

    2015-03-01

    Groundwater quality monitoring is one of the most important aspects in groundwater studies in arid environments particularly in developing countries, like Saudi Arabia, due to the fast population growth and the expansion of irrigated agriculture and industrial uses. Groundwater samples have been collected from eight locations in Al-Ula in Saudi Arabia during June 2012 and January 2013 in order to investigate the hydrochemical characteristics and the groundwater quality and to understand the sources of dissolved ions. Physicochemical parameters of groundwater such as electrical conductivity, pH, total dissolved solid, and major cations and anions were determined. Chloride was found to be the dominant anion followed by HCO(-) 3 and SO4 (2-). Groundwater of the study area is characterized by the dominance of alkaline earths (Ca(2+) + Mg(2+)) over alkali metals (Na(+) + K(+)). The analytical results show that the groundwater is generally moderately hard and slightly alkaline in nature. The binary relationships of the major ions reveal that water quality of the Al-Ula region is mainly controlled by rock weathering, evaporation, and ion exchange reactions. Piper diagram was constructed to identify hydrochemical facies, and it was found that majority of the samples belong to Ca-Cl and mixed Ca-Mg-Cl facies. Chemical indices like chloro-alkali indices, sodium adsorption ratio, percentage of sodium, residual sodium carbonate, and permeability index were calculated. Also, the results show that the chemical composition of groundwater sources of Al-Ula is strongly influenced by lithology of country rocks rather than anthropogenic activities. PMID:25655124

  8. Ground-Water Quality Data in the Central Sierra Study Unit, 2006 - Results from the California GAMA Program

    USGS Publications Warehouse

    Ferrari, Matthew J.; Fram, Miranda S.; Belitz, Kenneth

    2008-01-01

    the results for these samples were used to evaluate the quality of the data for the ground-water samples. Results from field blanks indicated contamination was not a noticeable source of bias in the data for ground-water samples. Differences between replicate samples were within acceptable ranges, indicating acceptably low variability. Matrix spike recoveries were within acceptable ranges for most constituents. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, or blended with other waters to maintain water quality. Regulatory thresholds apply to water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH), and thresholds established for aesthetic concerns (Secondary Maximum Contaminant Levels, SMCL-CA) by CDPH. Therefore, any comparisons of the results of this study to drinking-water standards only is for illustrative purposes and is not indicative of compliance or non-compliance to those standards. Most constituents that were detected in ground-water samples were found at concentrations below drinking-water standards or thresholds. Six constituents? fluoride, arsenic, molybdenum, uranium, gross-alpha radioactivity, and radon-222?were detected at concentrations higher than thresholds set for health-based regulatory purposes. Three additional constituents?pH, iron and manganese?were detected at concentrations above thresholds set for aesthetic concerns. Volatile organic compounds (VOCs) and pesticides, were detected in less than one-third of the samples and generally at less than one one-hundredth of a health-based threshold.

  9. Ground-water solutes and eolian processes: An example from the High Plains of Texas

    SciTech Connect

    Wood, W.W.; Sanford, W.E. )

    1992-01-01

    Eolian dunes associated with saline-lake basins are important geologic features in arid and semiarid areas. The authors propose that eolian processes may also be important in controlling solute concentration and composition of ground water in these environments. A study of Double Lakes on the Southern High Plains of Texas suggests that approximately 200 megagrams of chloride enters this topographically closed basin from the surrounding water table aquifer, direct precipitation and surface runoff. Solute-transport simulation suggest that approximately 70 of the 200 megagrams of the chloride annually leaves the basin by diffusion and ground-water advection through a 30 meter-thick shale underlying the lake. The remaining 130 megagrams is hypothesized to be removed by eolian processes. Closed water-table contours around the lake and a hydrologic analysis suggest that it is improbable that solutes will reach the surrounding water-table aquifer by ground-water transport from this lake system. The conceptual eolian-transport model is further supported by observed chloride profiles in the unsaturated zone. When analyzed with estimates of recharge fluxes, these profiles suggest that approximately 150 megagrams of chloride enter the unsaturated zone downwind of the lake annually. Thus two independent methods suggest that 130 to 150 megagrams of chloride enter the unsaturated zone downwind of the lake annually. Thus two independent methods suggest that 130 to 150 megagrams of chloride are removed from the basin annually by eolian process and redeposited downwind of the lake. Eolian input to the ground water is consistent with the observed plume shape as well as with the solute and isotopic composition of ground water in the water-table aquifer downwind of the lake basin.

  10. Relict rock glaciers as groundwater storage in alpine catchments - the example of the Seckauer Tauern Range

    NASA Astrophysics Data System (ADS)

    Wagner, Thomas; Pauritsch, Marcus; Winkler, Gerfried

    2015-04-01

    Debris accumulations like relict rock glaciers (RRG) might act as groundwater storages in alpine catchments influencing the discharge dynamics of mountain streams. The degree of influence is related to the hydrometeorological conditions and changes seasonally. Especially during drought and flood events, the storage/buffer abilities of RRGs have an impact on the downstream river network. Stream flow could be assured during low flow periods and peak flows might be dampened during storm events. The assessment of the impact is investigated in the Seckauer Tauern Range, the easternmost subunit of the Niedere Tauern Range. In more detail, the discharge of a spring (Schöneben spring) emerging at the front of a RRG draining a catchment of 0.67 km² and discharges at gauging stations Finsterliesing and Unterwald further downstream with areal extents of 7.26 and 44.10 km² respectively are used as input for a lumped-parameter rainfall-runoff model, a modified version of the GR4J (Perrin et al., 2003). The Schöneben spring is 100% influenced by the RRG groundwater storage, as the whole catchment drains through the RRG. The flow dynamics of the other catchments are influenced only partially by RRGs with 15 and 12% as only headwater sections of it are drained by RRGs. The areal extend of the RRG (sub-) catchments, vegetation, debris in general and bare rock are compared to the storage parameters (routing and production store) of the rainfall-runoff model. As such, the influence of RRGs can be identified even in the overall catchment. It can be concluded that RRGs, due to their storage and buffer capabilities and abundance in the Seckauer Tauern Range are important for stream basin management and as a water resource for the sensitive ecosystem in alpine catchments. References: Perrin, C., Michel, C., Andréassian, V. (2003): Improvement of a parsimonious model for streamflow simulation. Journal of Hydrology 279, 275-289.

  11. Influences on water quality in a groundwater dependent wetland system

    NASA Astrophysics Data System (ADS)

    Shanafield, M.; Rigosi, A.; Wood, C.; White, N.; Liu, Y.; Brookes, J. D.; Cook, P. G.

    2014-12-01

    Ewens Ponds is a unique series of connected wetlands situated within the Gambier Limestone formation in the Gambier Basin on the southeastern coast in South Australia. The system is composed of three consecutive ponds, each with a total depth of 9 to 13 m deep. Groundwater is the sole water source for the ponds, and the clear water, lush flora, and rare indigenous fish that characterize these wetlands typically lure thousands of divers to the Ponds each year. Over the past century, agricultural practices in the area have changed the hydrology of this system in many ways; first with an extensive system of drains on both sides of the Ponds to make the surrounding area viable for agricultural use, subsequently with the dredging of the outflow of the Ponds and addition of synthetic fertilizers, and most recently with heavy aquifer pumping for widespread use of center pivot irrigation systems. Beginning in the 1970s, diebacks in the Ponds' flora were documented, concurrent with spikes in nutrient concentrations. In nearby waters, reductions in key wetland species have been observed during periods of high alkalinity (pH>10). Following these concerns, the current study aims to quantify the water budget within the ponds, identify sources of nutrients, and estimate the age of groundwaters entering the wetlands for correlation with longterm agricultural trends. Groundwater ages were sampled in May 2014 and analysed for Carbon 14 and SF6, in addition to the installation of salinity and water level sensors and flow gaging. Preliminary results show that approximately 70 percent of the water enters the system through groundwater inflow in the first pond, with the remaining water entering within the third pond. A slight increase in the electrical conductivity of the ponds (average 750 μS in the first pond, up to 800 μS in the third pond) also differentiates the water.

  12. Groundwater quality in the Northern Coast Ranges Basins, California

    USGS Publications Warehouse

    Mathany, Timothy M.; Belitz, Kenneth

    2015-01-01

    Recharge to the groundwater system is primarily from mixture of ambient sources, including direct percolation of precipitation and irrigation waters, infiltration of runoff from surrounding hills/areas, seepage from rivers and creeks, and subsurface inflow (from non-alluvial geologic units that bound the alluvial basins). The primary sources of discharge are evaporation, discharge to streams, and water pumped for municipal supply and irrigation.

  13. Quality of our groundwater resources: arsenic and fluoride

    USGS Publications Warehouse

    Nordstrom, D. Kirk

    2011-01-01

    Groundwater often contains arsenic or fluoride concentrations too high for drinking or cooking. These constituents, often naturally occurring, are not easy to remove. The right combination of natural or manmade conditions can lead to elevated arsenic or fluoride which includes continental source rocks, high alkalinity and pH, reducing conditions for arsenic, high phosphate, high temperature and high silica. Agencies responsible for safe drinking water should be aware of these conditions, be prepared to monitor, and treat if necessary.

  14. Groundwater quality assessment/corrective action feasibility plan

    SciTech Connect

    Stejskal, G.F.

    1989-11-15

    The Savannah River Laboratory (SRL) Seepage Basins are located in the northeastern section of the 700 Area at the Savannah River Site. Currently the four basins are out of service and are awaiting closure in accordance with the Consent Decree settled under Civil Act No. 1:85-2583. Groundwater monitoring data from the detection monitoring network around the SRL Basins was recently analyzed using South Carolina Hazardous Waste Management Regulations R.61-79.264.92 methods to determine if groundwater in the immediate vicinity of the SRL Basins had been impacted. Results from the data analysis indicate that the groundwater has been impacted by both volatile organic constituents (VOCs) and inorganic constituents. The VOCs, specifically trichloroethylene and tetrachloroethylene, are currently being addressed under the auspices of the SRS Hazardous Waste Permit Application (Volume III, Section J.6.3). The impacts resulting from elevated levels of inorganic constituent, such as barium, calcium, and zinc in the water table, do not pose a threat to human health and the environment. In order to determine if vertical migration of the inorganic constituents has occurred three detection monitoring wells are proposed for installation in the upper portion of the Congaree Aquifer.

  15. Assessment of the Hydrogeochemistry and Groundwater Quality of the Tarim River Basin in an Extreme Arid Region, NW China

    NASA Astrophysics Data System (ADS)

    Xiao, Jun; Jin, Zhangdong; Wang, Jin

    2014-01-01

    The concentrations of the major and trace elements in the groundwater of the Tarim River Basin (TRB), the largest inland river basin of China, were analyzed before and during rainy seasons to determine the hydrogeochemistry and to assess the groundwater quality for irrigation and drinking purposes. The groundwater within the TRB was slightly alkaline and characterized by high ionic concentrations. The groundwater in the northern sub-basin was fresh water with a Ca2+-HCO3 - water type, whereas the groundwater in the southern and central sub-basins was brackish with a Na+-Cl- water type. Evaporite dissolution and carbonate weathering were the primary and secondary sources of solutes in the groundwater within the basin, whereas silicate weathering played a minor role. The sodium adsorption ratio (SAR), water quality index (WQI), and sodium percentage (%Na) indicated that the groundwater in the northern sub-basin was suitable for irrigation and drinking, but that in the southern and central sub-basins was not suitable. The groundwater quality was slightly better in the wet season than in the dry season. The groundwater could be used for drinking after treatment for B3+, F-, and SO4 2- and for irrigation after control of the sodium and salinity hazards. Considering the high corrosivity ratio of the groundwater in this area, noncorrosive pipes should be used for the groundwater supply. For sustainable development, integrated management of the surface water and the groundwater is needed in the future.

  16. Assessment of the hydrogeochemistry and groundwater quality of the Tarim River Basin in an extreme arid region, NW China.

    PubMed

    Xiao, Jun; Jin, Zhangdong; Wang, Jin

    2014-01-01

    The concentrations of the major and trace elements in the groundwater of the Tarim River Basin (TRB), the largest inland river basin of China, were analyzed before and during rainy seasons to determine the hydrogeochemistry and to assess the groundwater quality for irrigation and drinking purposes. The groundwater within the TRB was slightly alkaline and characterized by high ionic concentrations. The groundwater in the northern sub-basin was fresh water with a Ca(2+)-HCO3(-) water type, whereas the groundwater in the southern and central sub-basins was brackish with a Na(+)-Cl(-) water type. Evaporite dissolution and carbonate weathering were the primary and secondary sources of solutes in the groundwater within the basin, whereas silicate weathering played a minor role. The sodium adsorption ratio (SAR), water quality index (WQI), and sodium percentage (%Na) indicated that the groundwater in the northern sub-basin was suitable for irrigation and drinking, but that in the southern and central sub-basins was not suitable. The groundwater quality was slightly better in the wet season than in the dry season. The groundwater could be used for drinking after treatment for B(3+), F(-), and SO4(2-) and for irrigation after control of the sodium and salinity hazards. Considering the high corrosivity ratio of the groundwater in this area, noncorrosive pipes should be used for the groundwater supply. For sustainable development, integrated management of the surface water and the groundwater is needed in the future. PMID:24221557

  17. Groundwater-quality and quality-control data for two monitoring wells near Pavillion, Wyoming, April and May 2012

    USGS Publications Warehouse

    Wright, Peter R.; McMahon, Peter B.; Mueller, David K.; Clark, Melanie L.

    2012-01-01

    In June 2010, the U.S. Environmental Protection Agency installed two deep monitoring wells (MW01 and MW02) near Pavillion, Wyoming, to study groundwater quality. During April and May 2012, the U.S Geological Survey, in cooperation with the Wyoming Department of Environmental Quality, collected groundwater-quality data and quality-control data from monitoring well MW01 and, following well redevelopment, quality-control data for monitoring well MW02. Two groundwater-quality samples were collected from well MW01—one sample was collected after purging about 1.5 borehole volumes, and a second sample was collected after purging 3 borehole volumes. Both samples were collected and processed using methods designed to minimize atmospheric contamination or changes to water chemistry. Groundwater-quality samples were analyzed for field water-quality properties (water temperature, pH, specific conductance, dissolved oxygen, oxidation potential); inorganic constituents including naturally occurring radioactive compounds (radon, radium-226 and radium-228); organic constituents; dissolved gasses; stable isotopes of methane, water, and dissolved inorganic carbon; and environmental tracers (carbon-14, chlorofluorocarbons, sulfur hexafluoride, tritium, helium, neon, argon, krypton, xenon, and the ratio of helium-3 to helium-4). Quality-control sample results associated with well MW01 were evaluated to determine the extent to which environmental sample analytical results were affected by bias and to evaluate the variability inherent to sample collection and laboratory analyses. Field documentation, environmental data, and quality-control data for activities that occurred at the two monitoring wells during April and May 2012 are presented.

  18. Agriculture-related trends in groundwater quality of the glacial deposits aquifer, central Wisconsin

    USGS Publications Warehouse

    Saad, D.A.

    2008-01-01

    Measuring and understanding trends in groundwater quality is necessary for determining whether changes in land-management practices have an effect on groundwater quality. This paper describes an approach that was used to measure and understand trends using data from two groundwater studies conducted in central Wisconsin as part of the USGS NAWQA program. One of the key components of this approach, determining the age of sampled groundwater, gave a temporal component to the snapshots of water quality that were obtained through synoptic-sampling efforts. This approach can be used at other locations where groundwater quality data are collected, groundwater age can be determined, and associated temporal data are available. Results of these studies indicate measured concentrations of nitrate and atrazine plus deethylatrazine were correlated to historical patterns of fertilizer and atrazine use. Concentrations of nitrate in groundwater have increased over time; concentrations of atrazine plus deethylatrazine increased and then decreased. Concentrations of nitrate also were correlated to screen depth below the water level and concentrations of dissolved O2; concentrations of atrazine plus deethylatrazine were correlated to dissolved O2 and annual precipitation. To measure trends in concentrations of atrazine plus deethylatrazine, the data, collected over a near-decadal period, were adjusted to account for changes in laboratory-reporting levels and analytical recoveries. Only after accounting for these changes was it apparent that the median concentrations of atrazine plus deethylatrazine decreased over the near-decadal interval between sampling efforts. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

  19. Ground-water quality in east-central New Jersey, and a plan for sampling networks

    USGS Publications Warehouse

    Harriman, D.A.; Sargent, B.P.

    1985-01-01

    Groundwater quality was evaluated in seven confined aquifers and the water table aquifer in east-central New Jersey based on 237 analyses of samples collected in 1981-82, and 225 older analyses. Investigation of the effect of land use on water quality and several sampling network proposals for the region are reported. Generally, water in the confined aquifers is of satisfactory quality for human consumption and most other uses. Iron (Fe) and manganese (Mn) concentrations exceed U.S. EPA drinking water standards in some wells screened in the Potomac-Raritan-Magothy aquifer system. Sodium (Na) concentrations in samples from three wells more than 800 ft deep in the Englishtown aquifer exceed the standard. Iron and Mn concentrations in this aquifer may also exceed the standards. Iron concentrations in the Wenonah-Mount Laurel aquifer exceed the standard. Based on 15 analyses of water from the Vincetown aquifer, Mn is the only constituent that exceeds the drinking water standard. In the Manasquan aquifer, 4 of the 16 Na determinations exceed the standard, and 8 of 16 Fe determinations exceed the standard. Water quality in the Atlantic City 800-ft sand is generally satisfactory. However, 12 Fe and 1 of 12 Mn determinations exceed the standards. For the Rio Grande water-bearing zone, 1 of 3 Fe determinations exceed the standard. The Kirkwood-Cohansey aquifer system (the water table aquifer) was the most thoroughly sampled (249 chemical analyses from 209 wells). Dissolved solids, chloride, Fe, nitrate, and Mn concentrations exceed drinking water standards in some areas. The results of chi-square tests of constituent distributions based on analyses from 158 wells in the water table aquifer indicate that calcium is higher in industrial and commercial areas; and Mg, chloride, and nitrate-plus-nitrite is higher in residential areas. (Author 's abstract)

  20. Evaluation of groundwater quality in rural-areas of northern Malawi: Case of Zombwe Extension Planning Area in Mzimba

    NASA Astrophysics Data System (ADS)

    Chidya, Russel C. G.; Matamula, Swithern; Nakoma, Oliver; Chawinga, Charles B. J.

    2016-06-01

    Many people in in the Sub-Saharan region rely on groundwater for drinking and other household uses. Despite this significance, information on the chemical composition of the water in the boreholes and emperical data on groundwater quality is limited in some rural areas of Malawi. This study was conducted to evaluate the physico-chemical quality of water from boreholes (n = 20) in Zombwe Extension Planning Area (EPA), Mzimba in Northern Malawi to ascertain their safety. Desktop studies and participatory approaches were employed to assess the socio-economic activities and water supply regime in the study areas. The water samples were analysed for pH, conductivity (EC), turbidity, water temperature, nitrate (NO3-), magnesium (Mg), calcium (Ca), zinc (Zn), fluoride (F-), and sulphate (SO42-). In-situ and laboratory analyses were carried out using portable meters and standard procedures. The results were compared with national (Malawi Bureau of Standards - MBS) and international standards (World Health Organization - WHO) for drinking water. The following ranges were obtained: pH (6.00-7.80), EC (437-3128 μS/cm), turbidity (0.10-5.80 NTU), water temperature (27.0-30.60 °C), NO3- (0.30-30.00 mg/L), F- (0.10-8.10 mg/L), Mg (31.00-91.00 mg/L), Ca (20.00-197.10 mg/L), SO42- (10.20-190 mg/L), Fe (0.10-3.60 mg/L) and Zn (0.00-5.10 mg/L). Generally, some parameters tested at several sites (>80%, n = 20) complied with both MBS and WHO limits. No significant differences (p > 0.05) was observed for most parameters (>65%, n = 11). Groundwater contamination was not significant in the area despite some parameters like F-, Ca and SO42- showing higher levels at other sites. Some sites registered very hard water (244.60-757.80 mg/L CaCO3) probably due to mineralization influenced by underground rock material. Further studies are needed to ascertain the groundwater quality of other parameters (like F-, and SO42-) which registered higher levels at some sites. Routine monitoring of the

  1. Ground-Water Quality Data in the Southeast San Joaquin Valley, 2005-2006 - Results from the California GAMA Program

    USGS Publications Warehouse

    Burton, Carmen A.; Belitz, Kenneth

    2008-01-01

    for these samples were used to evaluate the quality of the data for the ground-water samples. Assessment of the quality-control data resulted in censoring of less than 1 percent of the detections of constituents measured in ground-water samples. This study did not attempt to evaluate the quality of drinking water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, and (or) blended with other waters to maintain acceptable drinking-water quality. Regulatory thresholds apply to the treated water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with regulatory and other health-based thresholds established by the U.S. Environmental Protection Agency and California Department of Public Health (CDPH) and thresholds established for aesthetic concerns by CDPH. Two VOCs were detected above health-based thresholds: 1,2-dibromo-3-chloropropane (DBCP), and benzene. DBCP was detected above the U.S. Environmental Protections Agency's maximum contaminant level (MCL-US) in three grid wells and five understanding wells. Benzene was detected above the CDPH's maximum contaminant level (MCL-CA) in one grid well. All pesticide detections were below health-based thresholds. Perchlorate was detected above its maximum contaminate level for California in one grid well. Nitrate was detected above the MCL-US in six samples from understanding wells, of which one was a public supply well. Two trace elements were detected above MCLs-US: arsenic and uranium. Arsenic was detected above the MCL-US in four grid wells and two understanding wells; uranium was detected above the MCL-US in one grid well and one understanding well. Gross alpha radiation was detected above MCLs-US in five samples; four of them understanding wells, and uranium isotope activity was greater than the MCL-US for one understanding well

  2. Groundwater contamination in coastal urban areas: Anthropogenic pressure and natural attenuation processes. Example of Recife (PE State, NE Brazil)

    NASA Astrophysics Data System (ADS)

    Bertrand, G.; Hirata, R.; Pauwels, H.; Cary, L.; Petelet-Giraud, E.; Chatton, E.; Aquilina, L.; Labasque, T.; Martins, V.; Montenegro, S.; Batista, J.; Aurouet, A.; Santos, J.; Bertolo, R.; Picot, G.; Franzen, M.; Hochreutener, R.; Braibant, G.

    2016-09-01

    In a context of increasing land use pressure (over-exploitation, surface-water contamination) and repeated droughts, identifying the processes affecting groundwater quality in coastal megacities of the tropical and arid countries will condition their long-term social and environmental sustainability. The present study focuses on the Brazilian Recife Metropolitan Region (RMR), which is a highly urbanized area (3,743,854 inhabitants in 2010) on the Atlantic coast located next to an estuarial zone and overlying a multi-layered sedimentary system featured by a variable sediment texture and organic content. It investigates the contamination and redox status patterns conditioning potential attenuation within the shallow aquifers that constitute the interface between the city and the strategic deeper semi-confined aquifers. These latter are increasingly exploited, leading to high drawdown in potenciometric levels of 20-30 m and up to 70 m in some high well density places, and potentially connected to the surface through leakage. From a multi-tracer approach (major ions, major gases, δ11B, δ18O-SO4, δ34S-SO4) carried out during two field campaigns in September 2012 and March 2013 (sampling of 19 wells and 3 surface waters), it has been possible to assess the contamination sources and the redox processes. The increasing trend for mineralization from inland to coastal and estuarial wells (from 119 to around 10,000 μS/cm) is at first attributed to water-rock interactions combined with natural and human-induced potentiometric gradients. Secondly, along with this trend, one finds an environmental pressure gradient related to sewage and/or surface-channel network impacts (typically depleted δ11B within the range of 10-15‰) that are purveyors of chloride, nitrate, ammonium and sulfate. Nitrate, ammonium and sulfate (ranging from 0 to 1.70 mmol/L, from 0 to 0,65 mmol/L, from 0.03 to 3.91 mmol/L respectively are also potentially produced or consumed through various redox

  3. Groundwater contamination in coastal urban areas: Anthropogenic pressure and natural attenuation processes. Example of Recife (PE State, NE Brazil).

    PubMed

    Bertrand, G; Hirata, R; Pauwels, H; Cary, L; Petelet-Giraud, E; Chatton, E; Aquilina, L; Labasque, T; Martins, V; Montenegro, S; Batista, J; Aurouet, A; Santos, J; Bertolo, R; Picot, G; Franzen, M; Hochreutener, R; Braibant, G

    2016-09-01

    In a context of increasing land use pressure (over-exploitation, surface-water contamination) and repeated droughts, identifying the processes affecting groundwater quality in coastal megacities of the tropical and arid countries will condition their long-term social and environmental sustainability. The present study focuses on the Brazilian Recife Metropolitan Region (RMR), which is a highly urbanized area (3,743,854 inhabitants in 2010) on the Atlantic coast located next to an estuarial zone and overlying a multi-layered sedimentary system featured by a variable sediment texture and organic content. It investigates the contamination and redox status patterns conditioning potential attenuation within the shallow aquifers that constitute the interface between the city and the strategic deeper semi-confined aquifers. These latter are increasingly exploited, leading to high drawdown in potenciometric levels of 20-30m and up to 70m in some high well density places, and potentially connected to the surface through leakage. From a multi-tracer approach (major ions, major gases, δ(11)B, δ(18)O-SO4, δ(34)S-SO4) carried out during two field campaigns in September 2012 and March 2013 (sampling of 19 wells and 3 surface waters), it has been possible to assess the contamination sources and the redox processes. The increasing trend for mineralization from inland to coastal and estuarial wells (from 119 to around 10,000μS/cm) is at first attributed to water-rock interactions combined with natural and human-induced potentiometric gradients. Secondly, along with this trend, one finds an environmental pressure gradient related to sewage and/or surface-channel network impacts (typically depleted δ(11)B within the range of 10-15‰) that are purveyors of chloride, nitrate, ammonium and sulfate. Nitrate, ammonium and sulfate (ranging from 0 to 1.70mmol/L, from 0 to 0,65mmol/L, from 0.03 to 3.91mmol/L respectively are also potentially produced or consumed through various redox

  4. Hydrochemical processes regulating groundwater quality in the coastal plain of Al Musanaah, Sultanate of Oman

    NASA Astrophysics Data System (ADS)

    Askri, Brahim

    2015-06-01

    The Al Batinah coastal aquifer is the principal source of water in northwestern Oman. The rainfall in the Jabal Al Akhdar mountain region recharges the plain with freshwater that allowed agricultural and industrial activities to develop. The over-exploitation of this aquifer since the 1970s for municipal, agricultural and industrial purposes, excessive use of fertilizers in agriculture and leakage from septic tanks led to the deterioration of groundwater quality. The objective of this study was to investigate the hydrochemical processes regulating the groundwater quality in the southwestern section of Al Batinah. From available data collected during the spring of 2010 from 58 wells located in Al Musanaah wilayat, it was determined that the groundwater salinity increased in the direction from the south to the north following the regional flow direction. In addition to salinisation, the groundwater in the upstream and intermediate regions was contaminated with nitrate, while groundwater in the downstream region was affected by fluoride. Calculations of ionic ratios and seawater fraction indicated that seawater intrusion was not dominant in the study area. The primary factors controlling the groundwater chemistry in Al Musanaah appear to be halite dissolution, reverse ion exchange with clay material and anthropogenic pollutants.

  5. Groundwater-quality data in the Klamath Mountains study unit, 2010: results from the California GAMA Program

    USGS Publications Warehouse

    Mathany, Timothy M.; Belitz, Kenneth

    2014-01-01

    radioactivity, and microbial indicators (total coliform and Escherichia coli [E. coli]). Isotopic tracers (stable isotopes of hydrogen and oxygen in water, isotopic ratios of dissolved strontium in water, and stable isotopes of carbon in dissolved inorganic carbon), dissolved noble gases, and age-dating tracers (tritium and carbon-14) were measured to help identify sources and ages of sampled groundwater. Quality-control samples (field blanks, replicate sample pairs, and matrix spikes) were collected at 13 percent of the sites in the KLAM study unit, and the results were used to evaluate the quality of the data from the groundwater samples. Field blank samples rarely contained detectable concentrations of any constituent, indicating that contamination from sample collection or analysis was not a significant source of bias in the data for the groundwater samples. More than 99 percent of the replicate pair samples were within acceptable limits of variability. Matrix-spike sample recoveries were within the acceptable range (70 to 130 percent) for approximately 91 percent of the compounds. This study did not evaluate the quality of water delivered to consumers. After withdrawal, groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is delivered to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory health-based benchmarks established by the U.S. Environmental Protection Agency (USEPA) and CDPH, and to non-health-based benchmarks established for aesthetic concerns by the CDPH. Comparisons between data collected for this study and benchmarks for drinking water are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. All concentrations of organic constituents from grid sites

  6. Using multivariate statistical methods to assess the groundwater quality in an arsenic-contaminated area of Southwestern Taiwan.

    PubMed

    Lu, K-L; Liu, C-W; Jang, C-S

    2012-10-01

    Groundwater is a major water resource in Southwestern Taiwan; hence, long-term monitoring of water quality is essential. The study aims to assess the hydrochemical characteristics of water in the arsenic-contaminated aquifers of Choushui River alluvial fan and Chianan Plain, Taiwan using multivariate statistical methods, namely, factor analysis (FA), cluster analysis (CA), and discriminant analysis (DA). Factor analysis is applied to reveal the processes controlling the hydrochemistry of groundwater. Cluster analysis is applied to spatially categorize the collected water samples based on the water quality. Discriminant analysis is then applied to elucidate key parameters associated with the occurrence of elevated As concentration (>10 μg L(-1)) in groundwater. Major water types are characterized as Na-Ca-Cl and Na-Mg-Cl in the Choushui River alluvial fan and Chianan Plain, respectively. Inorganic species of arsenic (As), particularly As(III), prevail in these two groundwater catchments, and their levels are higher in the Chianan Plain than in the Choushui River alluvial fan. Through FA, three factors, namely, the degree of salination, As reduction, and iron (Fe) reduction, are determined and denoted irrespective of some differences between the factorial compositions. Spatial distribution patterns of factors As reduction and Fe reduction imply that the redox zonation is delineated by As- and Fe-dominance zones separately. The results of CA demonstrate that three main groups can be properly explained by the factors extracted via FA. Three- (Fe(2+), Fe(3+), and NH (4) (+) ) and four-parameters (Fe(2+), Fe(3+), NH (4) (+) , and Ca(2+)) derived from discriminant analysis for Choushui River alluvial fan and Chianan Plain are elucidated as key parameters affecting the distribution of As-contained groundwater. The analytical results indicate that the reductive dissolution of Fe minerals is prerequisite for the mobilization of As, whereas the shift of redox condition from

  7. Groundwater Age in Multi-Level Water Quality Monitor Wells on California Central Valley Dairies

    NASA Astrophysics Data System (ADS)

    Esser, B. K.; Visser, A.; Hillegonds, D. J.; Singleton, M. J.; Moran, J. E.; Harter, T.

    2011-12-01

    Dairy farming in California's Central Valley is a significant source of nitrate to underlying aquifers. One approach to mitigation is to implement farm-scale management plans that reduce nutrient loading to groundwater while sustaining crop yield. While the effect of different management practices on crop yield is easily measured, their effect on groundwater quality has only infrequently been evaluated. Documenting and predicting the impact of management on water quality requires a quantitative assessment of transport (including timescale and mixing) through the vadose and saturated zones. In this study, we measured tritium, helium isotopic composition, and noble gas concentrations in groundwater drawn from monitor wells on several dairies in the Lower San Joaquin Valley and Tulare Lake Basin of California's Central Valley in order to predict the timescales on which changes in management may produce observable changes in groundwater quality. These dairies differ in age (from <10 to >100 years old), thickness of the vadose zone (from <10 to 60 m), hydrogeologic setting, and primary source of irrigation water (surface or groundwater). All of the dairies use manure wastewater for irrigation and fertilization. Three of the dairies have implemented management changes designed to reduce nutrient loading and/or water usage. Monitor wells in the southern Tulare Lake Basin dairies were installed by UC-Davis as multi-level nested wells allowing depth profiling of tritium and noble gases at these sites. Tritium/helium-3 groundwater ages, calculated using a simple piston-flow model, range from <2 to >50 years. Initial tritium (the sum of measured tritium and tritiogenic helium-3) is close to or slightly above precipitation in the calculated recharge year for young samples; and significantly above the precipitation curve for older samples. This pattern is consistent with the use of 20-30 year old groundwater recharged before 1980 for irrigation, and illustrates how irrigation

  8. Environmental engineering education: examples of accreditation and quality assurance

    NASA Astrophysics Data System (ADS)

    Caporali, E.; Catelani, M.; Manfrida, G.; Valdiserri, J.

    2013-12-01

    Environmental engineers respond to the challenges posed by a growing population, intensifying land-use pressures, natural resources exploitation as well as rapidly evolving technology. The environmental engineer must develop technically sound solutions within the framework of maintaining or improving environmental quality, complying with public policy, and optimizing the utilization of resources. The engineer provides system and component design, serves as a technical advisor in policy making and legal deliberations, develops management schemes for resources, and provides technical evaluations of systems. Through the current work of environmental engineers, individuals and businesses are able to understand how to coordinate society's interaction with the environment. There will always be a need for engineers who are able to integrate the latest technologies into systems to respond to the needs for food and energy while protecting natural resources. In general, the environment-related challenges and problems need to be faced at global level, leading to the globalization of the engineering profession which requires not only the capacity to communicate in a common technical language, but also the assurance of an adequate and common level of technical competences, knowledge and understanding. In this framework, the Europe-based EUR ACE (European Accreditation of Engineering Programmes) system, currently operated by ENAEE - European Network for Accreditation of Engineering Education can represent the proper framework and accreditation system in order to provide a set of measures to assess the quality of engineering degree programmes in Europe and abroad. The application of the accreditation model EUR-ACE, and of the National Italian Degree Courses Accreditation System, promoted by the Italian National Agency for the Evaluation of Universities and Research Institutes (ANVUR), to the Environmental Engineering Degree Courses at the University of Firenze is presented. In

  9. Groundwater quality assessment in the village of Lutfullapur Nawada, Loni, District Ghaziabad, Uttar Pradesh, India.

    PubMed

    Singh, Vinod K; Bikundia, Devendra Singh; Sarswat, Ankur; Mohan, Dinesh

    2012-07-01

    The groundwater quality for drinking, domestic and irrigation in the village Lutfullapur Nawada, Loni, district Ghaziabad, U.P., India, has been assessed. Groundwater samples were collected, processed and analyzed for temperature, pH, conductivity, salinity, total alkalinity, carbonate alkalinity, bicarbonate alkalinity, total hardness, calcium hardness, magnesium hardness, total solids, total dissolved solids, total suspended solids, nitrate-nitrogen, chloride, fluoride, sulfate, phosphate, silica, sodium, potassium, calcium, magnesium, total chromium, cadmium, copper, iron, nickel, lead and zinc. A number of groundwater samples showed levels of electrical conductivity (EC), alkalinity, chloride, calcium, sodium, potassium and iron exceeding their permissible limits. Except iron, the other metals (Cr, Cd, Cu, Ni, Pb, and Zn) were analyzed below the permissible limits. The correlation matrices for 28 variables were performed. EC, salinity, TS and TDS had significant positive correlations among themselves and also with NO (3) (-) , Cl(-), alkalinity, Na(+), K(+), and Ca(2+). Fluoride was not significantly correlated with any of the parameters. NO (3) (-) was significantly positively correlated with Cl(-), alkalinity, Na(+), K(+) and Ca(2+). Chloride also correlated significantly with alkalinity, Na(+), K(+) and Ca(2+). Sodium showed a strong and positive correlation with K(+) and Ca(2+). pH was negatively correlated with most of the physicochemical parameters. This groundwater is classified as a normal sulfate and chloride type. Base-exchange indices classified 73% of the groundwater sources as the Na(+)-SO (4) (2-) type. The meteoric genesis indices demonstrated that 67% of groundwater sources belong to a deep meteoric water percolation type. Hydrochemical groundwater evaluations revealed that most of the groundwaters belong to the Na(+)-K(+)-Cl(-)-SO (4) (2-) type followed by Na(+)-K(+)-HCO (3) (-) type. Salinity, chlorinity and SAR indices indicated that majority

  10. Assessment of Groundwater quality in Krishnagiri and Vellore Districts in Tamil Nadu, India

    NASA Astrophysics Data System (ADS)

    Shanmugasundharam, A.; Kalpana, G.; Mahapatra, S. R.; Sudharson, E. R.; Jayaprakash, M.

    2015-11-01

    Groundwater quality is important as it is the main factor determining its suitability for drinking, domestic, agricultural and industrial purposes. The suitability of groundwater for drinking and irrigation has been assessed in north and eastern part of Krishnagiri district, South-western part of Vellore district and contiguous with Andhra Pradesh states, India. A total of 31 groundwater samples were collected in the study area. The groundwater quality assessment has been carried out by evaluating the physicochemical parameters such as pH, EC, TDS, HCO3^{ - } , Cl-, SO4^{2 - } , Ca2+, Mg2+, Na+ and K+. The dominant cations are in the order of Na+ > K+ > Ca2+ > Mg2+ while the dominant anions have the trends of Cl- > HCO3^{ - } > SO4^{2 - } > CO3. The quality of the water is evaluated using Wilcox diagram and the results reveals that most of the samples are found to be suitable for irrigation. Based on these parameters, groundwater has been assessed in favor of its suitability for drinking and irrigation purpose.

  11. Assessment of groundwater quality using DEA and AHP: a case study in the Sereflikochisar region in Turkey.

    PubMed

    Kavurmaci, Murat; Üstün, A Korkut

    2016-04-01

    This study investigated the spatial distribution of groundwater quality in Sereflikochisar Basin, in the Central Anatolian region of Turkey using different hydrochemical, statistical, and geostatistical methods. A total of 51 groundwater samples were collected from the observation wells in the study area to evaluate the characteristics of the groundwater quality. As a relatively simple and practical method, a groundwater quality index (GWQI) was developed to evaluate the overall groundwater quality. In this process, complex decision-making techniques such as analytic hierarchy process (AHP) and data envelopment analysis (DEA) were used. Based on these models, two new indices (A-GWQI and D-GWQI) were proposed. According to the D-GWQI score (from 0.6 to 1), water quality was classified in four categories as unsuitable (0.6-0.7), permissible (0.7-0.8), good (0.8-0.9), and excellent (0.9-1). The spatial distribution maps of the groundwater quality were created using the Kriging method. For each map, seven different semivariogram models were tested and the best-fitted model was chosen based on their root mean square standardized error. These maps showed that the areas with high groundwater quality were in the eastern and southern parts of the study area where the D-GWQI scores were greater than 0.8. Depending on the distance from the Salt Lake, the characteristics of groundwater changed from NaCl to NaHCO3 and CaHCO3 facies. This study shows how to determine the spatial distribution of the groundwater quality and identify the impact of salt lakes on the groundwater quality in inland aquifers. The findings of this study can be applied to ensure the quality of groundwater used for drinking and irrigation purposes in the study area. PMID:27034240

  12. Assessment of groundwater quality using DEA and AHP: a case study in the Sereflikochisar region in Turkey.

    PubMed

    Kavurmaci, Murat; Üstün, A Korkut

    2016-04-01

    This study investigated the spatial distribution of groundwater quality in Sereflikochisar Basin, in the Central Anatolian region of Turkey using different hydrochemical, statistical, and geostatistical methods. A total of 51 groundwater samples were collected from the observation wells in the study area to evaluate the characteristics of the groundwater quality. As a relatively simple and practical method, a groundwater quality index (GWQI) was developed to evaluate the overall groundwater quality. In this process, complex decision-making techniques such as analytic hierarchy process (AHP) and data envelopment analysis (DEA) were used. Based on these models, two new indices (A-GWQI and D-GWQI) were proposed. According to the D-GWQI score (from 0.6 to 1), water quality was classified in four categories as unsuitable (0.6–0.7), permissible (0.7–0.8), good (0.8–0.9), and excellent (0.9–1). The spatial distribution maps of the groundwater quality were created using the Kriging method. For each map, seven different semivariogram models were tested and the best-fitted model was chosen based on their root mean square standardized error. These maps showed that the areas with high groundwater quality were in the eastern and southern parts of the study area where the D-GWQI scores were greater than 0.8. Depending on the distance from the Salt Lake, the characteristics of groundwater changed from NaCl to NaHCO3 and CaHCO3 facies. This study shows how to determine the spatial distribution of the groundwater quality and identify the impact of salt lakes on the groundwater quality in inland aquifers. The findings of this study can be applied to ensure the quality of groundwater used for drinking and irrigation purposes in the study area. PMID:27359000

  13. Assessment of shallow ground-water quality in recently urbanized areas of Sacramento, California, 1998

    USGS Publications Warehouse

    Shelton, Jennifer L.

    2005-01-01

    Evidence for anthropogenic impact on shallow ground-water quality beneath recently developed urban areas of Sacramento, California, has been observed in the sampling results from 19 monitoring wells in 1998. Eight volatile organic compounds (VOCs), four pesticides, and one pesticide transformation product were detected in low concentrations, and nitrate, as nitrogen, was detected in elevated concentrations; all of these concentrations were below National and State primary and secondary maximum contaminant levels. VOC results from this study are more consistent with the results from urban areas nationwide than from agricultural areas in the Central Valley, indicating that shallow ground-water quality has been impacted by urbanization. VOCs detected may be attributed to either the chlorination of drinking water, such as trichloromethane (chloroform) detected in 16 samples, or to the use of gasoline additives, such as methyl tert-butyl ether (MTBE), detected in 2 samples. Pesticides detected may be attributed to use on household lawns and gardens and rights-of-way, such as atrazine detected in three samples, or to past agricultural practices, and potentially to ground-water/surface-water interactions, such as bentazon detected in one sample from a well adjacent to the Sacramento River and downstream from where bentazon historically was used on rice. Concentrations of nitrate may be attributed to natural sources, animal waste, old septic tanks, and fertilizers used on lawns and gardens or previously used on agricultural crops. Seven sample concentrations of nitrate, as nitrogen, exceeded 3.0 milligrams per liter, a level that may indicate impact from human activities. Ground-water recharge from rainfall or surface-water runoff also may contribute to the concentrations of VOCs and pesticides observed in ground water. Most VOCs and pesticides detected in ground-water samples also were detected in air and surface-water samples collected at sites within or adjacent to the

  14. Status and understanding of groundwater quality in the northern San Joaquin Basin, 2005

    USGS Publications Warehouse

    Bennett, George L.; Fram, Miranda S.; Belitz, Kenneth; Jurgens, Bryant C.

    2010-01-01

    Groundwater quality in the 2,079 square mile Northern San Joaquin Basin (Northern San Joaquin) study unit was investigated from December 2004 through February 2005 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project was developed in response to the Groundwater Quality Monitoring Act of 2001 that was passed by the State of California and is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The Northern San Joaquin study unit was the third study unit to be designed and sampled as part of the Priority Basin Project. Results of the study provide a spatially unbiased assessment of the quality of raw (untreated) groundwater, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 61 wells in parts of Alameda, Amador, Calaveras, Contra Costa, San Joaquin, and Stanislaus Counties; 51 of the wells were selected using a spatially distributed, randomized grid-based approach to provide statistical representation of the study area (grid wells), and 10 of the wells were sampled to increase spatial density and provide additional information for the evaluation of water chemistry in the study unit (understanding/flowpath wells). The primary aquifer systems (hereinafter, primary aquifers) assessed in this study are defined by the depth intervals of the wells in the California Department of Public Health database for each study unit. The quality of groundwater in shallow or deep water-bearing zones may differ from quality of groundwater in the primary aquifers; shallow groundwater may be more vulnerable to contamination from the surface. Two types of assessments were made: (1) status, assessment of the current quality of the groundwater resource; and (2) understanding, identification of the natural and human factors

  15. Statistical comparisons of ground-water quality underlying different land uses in central Florida

    SciTech Connect

    Rutledge, A.T.; German, E.R. Geological Survey, Altamonte Springs, FL )

    1988-09-01

    Human activities at land surface can affect the quality of water recharging groundwater systems. Because ground water is the principal source of drinking water in many areas, it is necessary to know the relation between land use and ground-water quality. This study is 1 of 7 being made throughout the US as part of the Toxic Waste - Ground-Water Contamination Program of the US Geological Survey. This report documents statistical comparisons of ground-water quality for three test areas in central Florida: (1) a control area where land use is minimal, (2) a citrus-growing area where effects of agriculture may be expected, and (3) a phosphate-mining area where effects of mining activities may be expected. This study addresses water-quality conditions in the surficial aquifer, which consists of sand and shell beds of Pleistocene and Holocene age. The two developed areas are representative of land uses that characterize large areas of Florida, and the control area is representative of near-pristine conditions that exist over a large area, so results of this study may be transferable. The water-quality variables of interest include physical properties, major ions, nutrients, and trace elements.

  16. [Assessment of groundwater quality of different aquifers in Tongzhou area in Beijing Plain and its chemical characteristics analysis].

    PubMed

    Guo, Gao-Xuan; Ju, Yi-Wen; Zhai, Hang; Xu, Liang; Shen, Yuan-Yuan; Ji, Yi-Qun

    2014-06-01

    In order to evaluate the groundwater quality of Tongzhou area in Beijing Plain and to discuss the characteristics of its distribution by the view of hydrochemistry, a total of 151 groundwater samples, collected within study area in the dry period of 2008 according to the geological and hydrogeololgical condition of Tongzhou area, were classified as shallow, middle and deep groundwater, respectively. Based on the data, the groundwater quality was evaluated by the method of F value. The mean and variance of main chemical constituents of groundwater samples were presented. Almost all the quaternary groundwater of Chaobai river pluvial fan belonged to the alkaline water type. The evaluation results based on the analysis results showed that from shallow to deep, the quality of groundwater in Beijing became better. The total areas of groundwater belonging to class IV and V area were 884 km2, 599 km2 and 94 km2 respectively for shallow, middle and deep groundwater. The evaluation results showed that the main exceeding chemical constituents were TDS, hardness, NH4(+), F(-) and total Fe. Most exceeding samples belonged to middle and deep aquifers. The main types of shallow groundwater were HCO2-Ca x Mg- and HCO3 x Cl-Ca x Na x Mg, while the chemical types of mid-deep groundwater were mostly HCO3-Na x Ca- and HCO3 x SO4(2-) -Na x Ca type due to the increased Na(+), SO4(2-) and Cl(-) concentration. Study results showed that the quality of shallow groundwater became worse mainly due to human activities. The deterioration of groundwater quality in mid-deep aquifers was due to both human activities and natural occurrence of poor-quality water. PMID:25158485

  17. Ground-water quality near an inactive landfill and sludge-spreading area, Tallahassee, Florida

    USGS Publications Warehouse

    Berndt, M.P.

    1993-01-01

    Groundwater quality at and near a landfill southwest of Tallahassee, Florida, where sludge from a municipal sewage-treatment plant was also applied, was assessed by sampling 21 monitoring wells and analyzing for various constituents. Water quality in the Upper Floridan aquifer at the site was compared to the water quality of 20 background wells in Leon County. Water quality in all samples from wells at the site was evaluated in relation to the landfill and sludge-spreading and nonsludge- spreading areas. Results from nonparametric statistical tests showed that potassium and nitrate concentrations were significantly different in samples from the Upper Floridan aquifer at the site and in samples from background wells. Median potassium concentrations were 0.7 mg/L in samples collected at the site and 0.4 mg/L in samples collected from background wells, whereas median nitrate concentration was 6.48 mg/L at the site and 0.51 mg/L in background wells. Graphical comparison of concentration distributions in six categories of wells; upgradient, landfill, adjacent to the landfill, downgradient onsite, downgradient offsite, and from background wells in Leon County, indicated that sodium, bicarbonate, sulfate, iron, manganese, dissolved solids, and specific conductance had highest concentrations in water from wells within the landfill. Nitrate concentrations were lowest in samples from wells in the landfill compared to the other categories. Concentrations of trace metals and organic constituents were mostly below detection limits although State maximum contaminant levels of 1.0 microg/L for benzene and vinyl chloride and 3.0 microg/L for tetrachloroethene were exceeded in water from some wells. Nitrate and chloride concentrations were significantly different in sludge-spreading and nonsludge-spreading areas. Median nitrate and chloride concentrations of 6.9 microg/L and 2.9 microg/L were detected in groundwater in sludge-spreading areas compared to 1.1 mg/L and 1.8 mg/L in

  18. Calendar year 1995 groundwater quality report for the Bear Creek Hydrogeologic Regime, Oak Ridge Y-12 Plant, Oak Ridge, Tennessee

    SciTech Connect

    1996-02-01

    This annual groundwater quality report (GWQR) contains groundwater and surface water quality data obtained during the 1995 calendar year (CY) at several hazardous and nonhazardous waste management facilities associated with the Y-12 Plant located on the DOE Oak Ridge Reservation (ORR) southeast of Oak Ridge, Tennessee. The sites addressed by this document are located in Bear Creek Valley (BCV) west of the Y-12 Plant complex within the Bear Creek Hydrogeologic Regime. The Bear Creek Regime is one of three hydrogeologic regimes defined for the purposes of groundwater and surface water quality monitoring at the Y-12 Plant. The purpose of the Groundwater Protection Program (GWPP) is to characterize the hydrogeology and to monitor groundwater quality at the Y-12 Plant and surrounding area to provide for protection of groundwater resources consistent with federal, state, and local requirements. Part 1 (this report) consists primarily of data appendices and serves as a reference for the groundwater quality data obtained each CY under the lead of the Y-12 Plant GWPP. Part 2 of the report, to be issued mid-year, will contain an evaluation of the data with respect to regime-wide groundwater quality, present the findings and status of ongoing hydrogeologic studies, describe changes in monitoring priorities, and present planned modifications to the groundwater sampling and analysis program for the following CY.

  19. Hydrogeology and ground-water quality of Brunswick County, North Carolina

    USGS Publications Warehouse

    Harden, Stephen L.; Fine, Jason M.; Spruill, Timothy B.

    2003-01-01

    Brunswick County is the southernmost coastal county in North Carolina and lies in the southeastern part of the Coastal Plain physiographic province. In this report, geologic, hydrologic, and chemical data were used to investigate and delineate the hydro-geologic framework and ground-water quality of Brunswick County. The major aquifers and their associated confining units delineated in the Brunswick County study area include, from youngest to oldest, the surficial, Castle Hayne, Peedee, Black Creek, upper Cape Fear, and lower Cape Fear aquifers. All of these aquifers, with the exception of the Castle Hayne aquifer, are located throughout Brunswick County. The Castle Hayne aquifer extends across only the southeastern part of the county. Based on available data, the Castle Hayne and Peedee confining units are missing in some areas of Brunswick County, which allows direct hydraulic contact between the surficial aquifer and underlying Castle Hayne or Peedee aquifers. The confining units for the Black Creek, upper Cape Fear, and lower Cape Fear aquifers appear to be continuous throughout Brunswick County. In examining the conceptual hydrologic system for Brunswick County, a generalized water budget was developed to better understand the natural processes, including precipitation, evapotranspiration, and stream runoff, that influence ground-water recharge to the shallow aquifer system in the county. In the generalized water budget, an estimated 11 inches per year of the average annual precipitation of 55 inches per year in Brunswick County is estimated to infiltrate and recharge the shallow aquifer system. Of the 11 inches per year that recharges the shallow system, about 1 inch per year is estimated to recharge the deeper aquifer system. The surficial aquifer in Brunswick County is an important source of water for domestic supply and irrigation. The Castle Hayne aquifer is the most productive aquifer and serves as the principal ground-water source of municipal supply

  20. Ground-water quality and data on wells and springs in Pennsylvania; Volume I, Ohio and St. Lawrence River basins

    USGS Publications Warehouse

    Koester, Harry E.; Miller, Denise R.

    1980-01-01

    Volume I of the Groundwater Quality and Data on Wells and Springs in Pennsylvania presents groundwater quality and physical data on about 1,200 well and spring sites in the Ohio and St. Lawrence River basins. Locations are shown on site-location maps derived from the hydrologic unit map. Codes showing the geologic age and aquifer are provided. (USGS)

  1. An approach to derive groundwater and stream threshold values for total nitrogen and ensure good ecological status of associated aquatic ecosystems - example from a coastal catchment to a vulnerable Danish estuary.

    NASA Astrophysics Data System (ADS)

    Hinsby, Klaus; Markager, Stiig; Kronvang, Brian; Windolf, Jørgen; Sonnenborg, Torben; Sørensen, Lærke

    2015-04-01

    Nitrate, which typically makes up the major part (~>90%) of dissolved inorganic nitrogen in groundwater and surface water, is the most frequent pollutant responsible for European groundwater bodies failing to meet the good status objectives of the European Water Framework Directive generally when comparing groundwater monitoring data with the nitrate quality standard of the Groundwater Directive (50 mg/l = the WHO drinking water standard). Still, while more than 50 % of the European surface water bodies do not meet the objective of good ecological status "only" 25 % of groundwater bodies do not meet the objective of good chemical status according to the river basin management plans reported by the EU member states. However, based on a study on interactions between groundwater, streams and a Danish estuary we argue that nitrate threshold values for aerobic groundwater often need to be significantly below the nitrate quality standard to ensure good ecological status of associated surface water bodies, and hence that the chemical status of European groundwater is worse than indicated by the present assessments. Here we suggest a methodology for derivation of groundwater and stream threshold values for total nitrogen ("nitrate") in a coastal catchment based on assessment of maximum acceptable nitrogen loadings (thresholds) to the associated vulnerable estuary. The applied method use existing information on agricultural practices and point source emissions in the catchment, groundwater, stream quantity and quality monitoring data that all feed data to an integrated groundwater and surface water modelling tool enabling us to conduct an assessment of total nitrogen loads and threshold concentrations derived to ensure/restore good ecological status of the investigated estuary. For the catchment to the Horsens estuary in Denmark we estimate the stream and groundwater thresholds for total nitrogen to be about 13 and 27 mg/l (~ 12 and 25 mg/l of nitrate). The shown example of

  2. [Relationship between groundwater quality index of nutrition element and organic matter in riparian zone and water quality in river].

    PubMed

    Hua-Shan, Xu; Tong-Qian, Zhao; Hong-Q, Meng; Zong-Xue, Xu; Chao-Hon, Ma

    2011-04-01

    Riparian zone hydrology is dominated by shallow groundwater with complex interactions between groundwater and surface water. There are obvious relations of discharge and recharge between groundwater and surface water. Flood is an important hydrological incident that affects groundwater quality in riparian zone. By observing variations of physical and chemical groundwater indicators in riparian zone at the Kouma section of the Yellow River Wetland, especially those took place in the period of regulation for water and sediment at the Xiaolangdi Reservoir, relationship between the groundwater quality in riparian zone and the flood water quality in the river is studied. Results show that there will be great risk of nitrogen, phosphorus, nitrate nitrogen and organic matter permeating into the groundwater if floodplain changes into farmland. As the special control unit of nitrogen pollution between rivers and artificial wetlands, dry fanning areas near the river play a very important role in nitrogen migration between river and groundwater. Farm manure as base fertilizer may he an important source of phosphorus leak and loss at the artificial wetlands. Phosphorus leaks into the groundwater and is transferred along the hydraulic gradient, especially during the period of regulation for water and sediment at the Xiaolangdi Reservoir. The land use types and farming systems of the riparian floodplain have a major impact on the nitrate nitrogen contents of the groundwater. Nitrogen can infiltrate and accumulate quickly at anaerobic conditions in the fish pond area, and the annual nitrogen achieves a relatively balanced state in lotus area. In those areas, the soil is flooded and at anaerobic condition in spring and summer, nitrogen infiltrates and denitrification significantly, but soil is not flooded and at aerobic condition in the autumn and winter, and during these time, a significant nitrogen nitrification process occurs. In the area between 50 m and 200 m from the river

  3. Use of environmental tracers to evaluate ground-water age and water-quality trends in a buried-valley aquifer, Dayton area, southwestern, Ohio

    USGS Publications Warehouse

    Rowe, Gary L.; Shapiro, Stephanie Dunkle; Schlosser, Peter

    1999-01-01

    Chlorofluorocarbons (CFC method) and tritium and helium isotopes (3H-3He method) were used as environmental tracers to estimate ground-water age in conjunction with efforts to develop a regional ground-water flow model of the buried-valley aquifer in the Dayton area, southwestern Ohio. This report describes results of CFC and water-quality sampling, summarizes relevant aspects of previously published work, and describes the use of 3H-3He ages to characterize temporal trends in ground-water quality of the buried-valley aquifer near Dayton, Ohio. Results of CFC sampling indicate that approximately 25 percent of the 137 sampled wells were contaminated with excess CFC's that rendered the ground water unsuitable for age dating. Evaluation of CFC ages obtained for the remaining samples indicated that the CFC compounds used for dating were being affected by microbial degradation. The degradation occurred under anoxic conditions that are found in most parts of the buried-valley aquifer. As a result, ground-water ages derived by the CFC method were too old and were inconsistent with measured tritium concentrations and independently derived 3H-3He ages. Limited data indicate that dissolved methane may play an important role in the degradation of the CFC's. In contrast, the 3H-3He technique was found to yield ground-water ages that were chemically and hydrologically reasonable. Ground-water ages derived by the 3H-3He technique were compared to values for selected water- quality characteristics to evaluate temporal trends in ground-water quality in the buried- valley aquifer. Distinct temporal trends were not identified for pH, alkalinity, or calcium and magnesium because of rapid equilibration of ground-water with calcite and dolomite in aquifer sediments. Temporal trends in which the amount of scatter and the number of outlier concentrations increased as ground-water age decreased were noted for sodium, potassium, boron, bromide, chloride, ammonia, nitrate, phosphate

  4. Ground-water flow and quality beneath sewage-sludge lagoons, and a comparison with the ground-water quality beneath a sludge-amended landfill, Marion County, Indiana

    USGS Publications Warehouse

    Bobay, K.E.

    1988-01-01

    The groundwater beneath eight sewage sludge lagoons, was studied to characterize the flow regime and to determine whether leachate had infiltrated into the glacio-fluvial sediments. Groundwater quality beneath the lagoons was compared with the groundwater quality beneath a landfill where sludge had been applied. The lagoons and landfills overlie outwash sand and gravel deposits separated by discontinuous clay layers. Shallow groundwater flows away from the lagoons and discharges into the White River. Deep groundwater discharges to the White River and flows southwest beneath Eagle Creek. After an accumulation of at least 2 inches of precipitation during 1 week, groundwater flow is temporarily reversed in the shallow aquifer, and all deep flow is along a relatively steep hydraulic gradient to the southwest. The groundwater is predominantly a calcium bicarbonate type, although ammonium accounts for more than 30% of the total cations in water from three wells. Concentrations of sodium, chloride, sulfate, iron, arsenic, boron, chemical oxygen demand, total dissolved solids, and methylene-blue-active substances indicate the presence of leachate in the groundwater. Concentrations of cadmium, chromium, copper, lead, mercury, nickel, selenium, and zinc were less than detection limits. The concentrations of 16 of 19 constituents or properties of groundwater beneath the lagoons are statistically different than groundwater beneath the landfill at the 0.05 level of significance. Only pH and concentrations of dissolved oxygen and bromide are higher in groundwater beneath the landfill than beneath the lagoons. 

  5. Effects of stormwater infiltration on quality of groundwater beneath retention and detention basins

    USGS Publications Warehouse

    Fischer, D.; Charles, E.G.; Baehr, A.L.

    2003-01-01

    Infiltration of storm water through detention and retention basins may increase the risk of groundwater contamination, especially in areas where the soil is sandy and the water table shallow, and contaminants may not have a chance to degrade or sorb onto soil particles before reaching the saturated zone. Groundwater from 16 monitoring wells installed in basins in southern New Jersey was compared to the quality of shallow groundwater from 30 wells in areas of new-urban land use. Basin groundwater contained much lower levels of dissolved oxygen, which affected concentrations of major ions. Patterns of volatile organic compound and pesticide occurrence in basin groundwater reflected the land use in the drainage areas served by the basins, and differed from patterns in background samples, exhibiting a greater occurrence of petroleum hydrocarbons and certain pesticides. Dilution effects and volatilization likely decrease the concentration and detection frequency of certain compounds commonly found in background groundwater. High recharge rates in storm water basins may cause loading factors to be substantial even when constituent concentrations in infiltrating storm water are relatively low.

  6. Geochemical processes controlling the groundwater quality in lower Palar river basin, southern India

    NASA Astrophysics Data System (ADS)

    Senthilkumar, M.; Elango, L.

    2013-04-01

    Hydrogeochemical study of groundwater was carried out in a part of the lower Palar river basin, southern India to determine the geochemical processes controlling the groundwater quality. Thirty-nine groundwater samples were collected from the study area and analysed for pH, Eh, EC, Ca, Mg, Na, K, HCO3, CO3, Cl and SO4. The analysed parameters of the groundwater in the study area were found to be well within the safe range in general with respect to the Bureau of Indian Standards for drinking water except for few locations. The results of these analyses were used to identify the geochemical processes that are taking place in this region. Cation exchange and silicate weathering are the important processes controlling the major ion distribution of the study area. Mass balance reaction model NETPATH was used to assess the ion exchange processes. High concentration of Ca in groundwater of the study area is due to the release of Ca by aquifer material and adsorption of Na due to ion exchange processes. Groundwater of the study area is suitable for drinking and irrigation purposes except for few locations.

  7. Impact of water overstock on groundwater quality of the Bassee plain area (France)

    NASA Astrophysics Data System (ADS)

    Gourcy, L.; Pettenati, M.; Baran, N.; Durand, P. Y.

    2009-04-01

    The project, inspired by the structural flood plain management measures of the Rhine River, consists in the temporal removal of a maximum amount of water from the Seine River in order to leave priority to the water from the River Yonne. Yonne River and the Seine are presenting their maximum water flow usually at a same time. The space located between Bray-sur-Seine and Montereau-Fault-Yonne corresponding to the La Bassée plain (agricultural area of 23 km2) is well adapted to this project of temporary and artificial flood. The objective of the project financed by the Institution Interdépartementale des barrages Réservoirs du Bassin de la Seine (IIBRBS), the BRGM, the Seine-Normandie Water Agency, the European Communauty through the Interreg IIIB SAND project is the evaluation, at a local scale, of the impact on groundwater quality of the temporal Seine water storage. Indeed, the water over storage i) changes hydraulic conditions and therefore modify water and pollutants transfers through the unsaturated and saturated zones and ii) bring at soil surface a water (Seine River) potentially containing contaminants that may move to groundwater and consequently changed physico-chemicals conditions (redox) of groundwater. The estimation of the vulnerability of groundwater to changes and loads needs hydraulic and geochemical modelling of transfer through the unsaturated zone as well as the study of pollutants fate in static conditions. Retention properties of some metals (Pb, Ni, Cu, Cr, Zn) in soils and materials of the unsaturated zone by chemical processes were performed determining adsorption coefficient (Kd) by laboratory experiments. These experiments are showing that nickel mobility is lower in the argillous layers than in the sandy part of the unsaturated zone. Ni mobility is controlled by iron hydroxides and precipitation of other secondary minerals. Its complexation on organic ligands increases its mobility in soils. Copper concentration is influenced by CaCO3

  8. Effects of Stormwater Infiltration on Quality of Groundwater Beneath Retention and Detention Basins

    EPA Science Inventory

    Use of stormwater retention and detention basins has become a popular method for managing urban and suburban stormwater runoff. Infiltration of stormwater through these basins may increase the risk to ground-water quality, especially in areas where the soil is sandy and the wate...

  9. MONITORING GROUNDWATER QUALITY: THE IMPACT OF IN-SITU OIL SHALE RETORTING

    EPA Science Inventory

    This report presents the initial phase of a research program which will develop a planning methodology for the design and implementation of cost-effective groundwater quality monitoring programs for modified in-situ (MIS) oil shale retorting. This initial phase includes (1) a rev...

  10. GROUNDWATER QUALITY MONITORING OF WESTERN OIL SHALE DEVELOPMENT: IDENTIFICATION AND PRIORITY RANKING OF POTENTIAL POLLUTION SOURCES

    EPA Science Inventory

    This report presents the development of a preliminary priority ranking of potential pollution sources with respect to groundwater quality and the associated pollutants for oil shale operations such as proposed for Federal Prototype Leases U-a and U-b in Eastern Utah. The methodol...

  11. GROUNDWATER QUALITY MONITORING OF WESTERN OIL SHALE DEVELOPMENT: MONITORING PROGRAM DEVELOPMENT

    EPA Science Inventory

    This report presents the development of a preliminary design of a groundwater quality monitoring program for oil shale operations, such as proposed for Federal Prototype Lease Tracts U-a and U-b in eastern Utah. A preliminary decision framework for monitoring design for this type...

  12. Calendar year 1993 groundwater quality report for the Upper East Fork Poplar Creek hydrogeologic regime Y-12 Plant, Oak Ridge, Tennessee: 1993 groundwater quality data interpretations and proposed program modifications

    SciTech Connect

    1994-10-01

    This Groundwater Quality Report (GWQR) contains an evaluation of the groundwater quality data obtained during the 1993 calendar year (CY) at the U.S. Department of Energy (DOE) Y-12 Plant located on the DOE Oak Ridge Reservation (ORR) southeast of Oak Ridge, Tennessee (Figure 1). The groundwater quality data are presented in Part 1 of the GWQR submitted by Martin Marietta Energy Systems, Inc. (Energy Systems) to the Tennessee Department of Environment and Conservation (TDEC) in February 1994 (HSW Environmental Consultants, Inc. 1994a). Groundwater quality data evaluated in this report were obtained at several hazardous and non-hazardous waste management facilities and underground storage tanks (USTS) located within the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime). The Environmental Management Department of the Y-12 Plant Health, Safety, Environment, and Accountability Organization manages the groundwater monitoring activities in each regime under the auspices of the Y-12 Plant Groundwater Protection Program (GWPP). The purpose of the GWPP is to characterize the hydrogeology and to monitor groundwater quality at the Y-12 Plant and surrounding area to provide for protection of groundwater resources consistent with federal, state, and local requirements and in accordance with DOE Orders and Energy Systems corporate policy. The annual GWQR for the East Fork Regime is completed in two parts. Part 1 consists primarily of data appendices and serves as a reference for the groundwater quality data obtained each CY under the lead of the Y-12 Plant GWPP. Part 2 (this report) contains an evaluation of the data with respect to regime-wide groundwater quality, presents the findings and status of ongoing hydrogeologic studies, describes changes in monitoring priorities, and presents planned modifications to the groundwater sampling and analysis program for the following calendar year.

  13. Validation of Student Generated Data for Assessment of Groundwater Quality

    ERIC Educational Resources Information Center

    Peckenham, John M.; Thornton, Teresa; Peckenham, Phoebe

    2012-01-01

    As part of a research project to evaluate the effects of sand and gravel mining on water quality, students were trained to analyze their own drinking water for simple quality indicators. Indicators analyzed were pH, conductivity, hardness, nitrate, chloride, and dissolved iron. Approximately 523 analyses were completed by students between 2006 and…

  14. A decision tree model to estimate the value of information provided by a groundwater quality monitoring network

    NASA Astrophysics Data System (ADS)

    Khader, A.; Rosenberg, D.; McKee, M.

    2012-12-01

    methemoglobinemia and bottled water costs of 150 $/person and 0.6 $/baby/day, the decision tree results show that the expected cost of establishing the proposed groundwater quality monitoring network exceeds the expected costs of the uninformed alternatives and there is not value to the information the monitoring system provides. However, the monitoring system will be preferred to ignoring the health risk or using alternative sources if the methemoglobinemia cost rises to 300 $/person or the bottled water cost increases to 2.3 $/baby/day. Similarly, the monitoring system has value if the system can more accurately report actual aquifer concentrations and the public more fully abides by managers' recommendations to use/not use the aquifer. The system also has value if it will serve a larger population or if its installation costs can be reduced, for example using a smaller number of monitoring wells. The VOI analysis shows how monitoring system design, accuracy, installation and operating costs, public awareness of health risks, costs of alternatives, and demographics together affect the value of implementing a system to monitor groundwater quality.

  15. A decision tree model to estimate the value of information provided by a groundwater quality monitoring network

    NASA Astrophysics Data System (ADS)

    Khader, A. I.; Rosenberg, D. E.; McKee, M.

    2013-05-01

    include healthcare for methemoglobinemia, purchase of bottled water, and installation and maintenance of the groundwater monitoring system. At current methemoglobinemia and bottled water costs of 150/person and 0.6/baby/day, the decision tree results show that the expected cost of establishing the proposed groundwater quality monitoring network exceeds the expected costs of the uninformed alternatives and there is no value to the information the monitoring system provides. However, the monitoring system will be preferred to ignoring the health risk or using alternative sources if the methemoglobinemia cost rises to 300/person or the bottled water cost increases to 2.3/baby/day. Similarly, the monitoring system has value if the system can more accurately report actual aquifer concentrations and the public more fully abides by manager recommendations to use/not use the aquifer. The system also has value if it will serve a larger population or if its installation costs can be reduced, for example using a smaller number of monitoring wells. The VOI analysis shows how monitoring system design, accuracy, installation and operating costs, public awareness of health risks, costs of alternatives, and demographics together affect the value of implementing a system to monitor groundwater quality.

  16. Effects of 1992 farming systems on ground-water quality at the management systems evaluation area near Princeton, Minnesota

    USGS Publications Warehouse

    Delin, G.N.; Landon, M.K.; Lamb, J.A.; Dowdy, R.H.

    1995-01-01

    Results indicate that the effects of the 1992 potassium-chloride and N fertilizer applications were reduced compared to the effects of 1991 applications. The most important factors associated with these differences were lower chemical application rates and lower recharge rates during 1992 than during 1991. Some of the chloride and N fertilizer applied to the cropped areas in 1992 likely did not reach the saturated zone in 1993 due to a 60-percent reduction in recharge compared to 1991. Therefore, analysis of data from additional years will be required to fully evaluate the effects of the fanning systems on ground-water quality.

  17. Evaluating the human impact on groundwater quality discharging into a coastal reef lagoon

    NASA Astrophysics Data System (ADS)

    Rebolledo-Vieyra, M.; Hernandez-Terrones, L.; Soto, M.; Lecossec, A.; Monroy-Rios, E.

    2008-12-01

    The Eastern coast of the Yucatan Peninsula has the fastest growth rate in Mexico and groundwater is the only source of drinking water in the region. The consequences of the lack of proper infrastructure to collect and treat wastewater and the impact of human activities on the quality of groundwater are addressed. The groundwater in the coastal aquifer of Quintana Roo (SE Mexico) discharges directly into the ocean. In addition, the coral reef of the Eastern Yucatan Peninsula is part of the Mesoamerican Coral Reef System, one of the largest in the world. The interaction of the reef-lagoon hydraulics with the coastal aquifer of Puerto Morelos (NE Yucatan Peninsula), and a major input of NH4, SO4, SiO2, as a consequence of the use of septic tanks and the lack of modern wastewater treatment plants are presented. No seasonal parameters differences were observed, suggesting that groundwater composition reaching the reef lagoon is not changing seasonally. A conceptual model of the coastal aquifer was developed, in order to explain how the human activities are impacting directly on the groundwater quality that, potentially, will have a direct impact on the coral reef. The protection and conservation of coral reefs must be directly related with a policy of sound management of coastal aquifers and wastewater treatment.

  18. Assessment of human activities impact on groundwater quality discharging into a reef lagoon

    NASA Astrophysics Data System (ADS)

    Rebolledo-Vieyra, M.; Hernandez, L.; Paytan, A.; Merino-Ibarra, M.; Lecossec, A.; Soto, M.

    2010-03-01

    The Eastern coast of the Yucatan Peninsula has the fastest growth rate in Mexico and groundwater is the only source of drinking water in the region. The consequences of the lack of proper infrastructure to collect and treat wastewater and the impact of human activities on the quality of groundwater are addressed. The groundwater in the coastal aquifer of Quintana Roo (SE Mexico) discharges directly into the ocean (Submarine Groundwater Discharges). In addition, the coral reef of the Eastern Yucatan Peninsula is part of the Mesoamerican Coral Reef System, one of the largest in the world. The interaction of the reef-lagoon hydraulics with the coastal aquifer of Puerto Morelos (NE Yucatan Peninsula), and a major input of NH4, SO4, SiO2, as a consequence of the use of septic tanks and the lack of modern wastewater treatment plants are presented. A conceptual model of the coastal aquifer was developed, in order to explain how the human activities are impacting directly on the groundwater quality that, potentially, will have a direct impact on the coral reef. The protection and conservation of coral reefs must be directly related with a policy of sound management of coastal aquifers and wastewater treatment.

  19. Groundwater quality in Imphal West district, Manipur, India, with multivariate statistical analysis of data.

    PubMed

    Singh, Elangbam J K; Gupta, Abhik; Singh, N R

    2013-04-01

    The aim of this paper was to analyze the groundwater quality of Imphal West district, Manipur, India, and assess its suitability for drinking, domestic, and agricultural use. Eighteen physico-chemical variables were analyzed in groundwater from 30 different hand-operated tube wells in urban, suburban, and rural areas in two seasons. The data were subjected to uni-, bi-, and multivariate statistical analysis, the latter comprising cluster analysis (CA), principal component analysis (PCA), and factor analysis (FA). Arsenic concentrations exceed the Indian standard in 23.3% and the WHO limit in 73.3% of the groundwater sources with only 26.7% in the acceptable range. Several variables like iron, chloride, sodium, sulfate, total dissolved solids, and turbidity are also beyond their desirable limits for drinking water in a number of sites. Sodium concentrations and sodium absorption ratio (SAR) are both high to render the water from the majority of the sources unsuitable for agricultural use. Multivariate statistical techniques, especially varimax rotation of PCA data helped to bring to focus the hidden yet important variables and understand their roles in influencing groundwater quality. Widespread arsenic contamination and high sodium concentration of groundwater pose formidable constraints towards its exploitation for drinking and other domestic and agricultural use in the study area, although urban anthropogenic impacts are not yet pronounced. PMID:22935861

  20. Questa baseline and pre-mining ground-water quality investigation. 3. Historical ground-water quality for the Red River Valley, New Mexico

    USGS Publications Warehouse

    LoVetere, Sara H.; Nordstrom, D. Kirk; Maest, Ann S.; Naus, Cheryl A.

    2003-01-01

    Historical ground-water quality data for 100 wells in the Red River Valley between the U.S. Geological Survey streamflow-gaging station (08265000), near Questa, and Placer Creek east of the town of Red River, New Mexico, were compiled and reviewed. The tabulation included 608 water-quality records from 23 sources entered into an electronic database. Groundwater quality data were first collected at the Red River wastewater-treatment facility in 1982. Most analyses, however, were obtained between 1994 and 2002, even though the first wells were developed in 1962. The data were evaluated by considering (a) temporal consistency, (b) quality of sampling methods, (c) charge imbalance, and (d) replicate analyses. Analyses that qualified on the basis of these criteria were modeled to obtain saturation indices for gypsum, calcite, fluorite, gibbsite, manganite, and rhodocrosite. Plots created from the data illustrate that water chemistry in the Red River Valley is predominantly controlled by calcite dissolution, congruent gypsum dissolution, and pyrite oxidation.

  1. Groundwater-quality data in the Cascade Range and Modoc Plateau study unit, 2010-Results from the California GAMA Program

    USGS Publications Warehouse

    Shelton, Jennifer L.; Fram, Miranda S.; Belitz, Kenneth

    2013-01-01

    , radioactive constituents, and microbial indicators. Naturally occurring isotopes and dissolved noble gases also were measured to provide a dataset that will be used to help interpret the sources and ages of the sampled groundwater in subsequent reports. In total, 221 constituents were investigated for this study. Three types of quality-control samples (blanks, replicates, and matrix spikes) were collected at approximately 10 percent of the wells in the CAMP study unit, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Blanks rarely contained detectable concentrations of any constituent, suggesting that contamination from sample collection procedures was not a significant source of bias in the data for the groundwater samples. Replicate samples generally were within the limits of acceptable analytical reproducibility. Matrix-spike recoveries were within the acceptable range (70 to 130 percent) for approximately 90 percent of the compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, untreated groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is served to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory health-based benchmarks established by the U.S. Environmental Protection Agency (USEPA) and CDPH, and to non-regulatory benchmarks established for aesthetic concerns by CDPH. Comparisons between data collected for this study and benchmarks for drinking water are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. All organic constituents and most inorganic constituents that were detected in groundwater samples from the 90 grid wells

  2. An example of groundwater modeling to predict impact of climate change and to support optimization of a new intake

    NASA Astrophysics Data System (ADS)

    Polomcic, D.; Stevanovic, Z.; Ristic Vakanjac, V.; Dokmanovic, P.; Milanovic, S.

    2012-04-01

    scenarios. For the 2070 and 2010 periods, operation of ten pumping wells (? Q = 150 l/s) has been simulated. They are supposed to abstract groundwater along the right bank of the Nišava River where the limestone of Stara Planina comes into close contact with overlying Pliocene sediments. Overall, despite burdened by some uncertainties obtained results from the model indicate a reduction of groundwater reserves in the karst massif of Stara Planina Mt. as a result of a decrease in annual precipitation. Operation of ten simulated wells could be an alternative but in long-term (in 2100) , a more significant decline in groundwater levels in the Pirot basin and karst massif of Stara Planina Mt is to be expected (decrease in the water table for maximal 28 m). Acknowledgements: The activities are conducted as a part of the project CCWaterS under South East Europe programme funded by ERDF and IPA.

  3. Temporal variation in groundwater quality in the Permian Basin of Texas, a region of increasing unconventional oil and gas development.

    PubMed

    Hildenbrand, Zacariah L; Carlton, Doug D; Fontenot, Brian E; Meik, Jesse M; Walton, Jayme L; Thacker, Jonathan B; Korlie, Stephanie; Shelor, C Phillip; Kadjo, Akinde F; Clark, Adelaide; Usenko, Sascha; Hamilton, Jason S; Mach, Phillip M; Verbeck, Guido F; Hudak, Paul; Schug, Kevin A

    2016-08-15

    The recent expansion of natural gas and oil extraction using unconventional oil and gas development (UD) practices such as horizontal drilling and hydraulic fracturing has raised questions about the potential for environmental impacts. Prior research has focused on evaluations of air and water quality in particular regions without explicitly considering temporal variation; thus, little is known about the potential effects of UD activity on the environment over longer periods of time. Here, we present an assessment of private well water quality in an area of increasing UD activity over a period of 13months. We analyzed samples from 42 private water wells located in three contiguous counties on the Eastern Shelf of the Permian Basin in Texas. This area has experienced a rise in UD activity in the last few years, and we analyzed samples in four separate time points to assess variation in groundwater quality over time as UD activities increased. We monitored general water quality parameters as well as several compounds used in UD activities. We found that some constituents remained stable over time, but others experienced significant variation over the period of study. Notable findings include significant changes in total organic carbon and pH along with ephemeral detections of ethanol, bromide, and dichloromethane after the initial sampling phase. These data provide insight into the potentially transient nature of compounds associated with groundwater contamination in areas experiencing UD activity. PMID:27125684

  4. Groundwater-quality data in the Western San Joaquin Valley study unit, 2010 - Results from the California GAMA Program

    USGS Publications Warehouse

    Mathany, Timothy M.; Landon, Matthew K.; Shelton, Jennifer L.; Belitz, Kenneth

    2013-01-01

    ), constituents of special interest (perchlorate, N-nitrosodimethylamine [NDMA], and 1,2,3-trichloropropane [1,2,3-TCP]), and naturally occurring inorganic constituents (trace elements, nutrients, dissolved organic carbon [DOC], major and minor ions, silica, total dissolved solids [TDS], alkalinity, total arsenic and iron [unfiltered] and arsenic, chromium, and iron species [filtered]). Isotopic tracers (stable isotopes of hydrogen, oxygen, and boron in water, stable isotopes of nitrogen and oxygen in dissolved nitrate, stable isotopes of sulfur in dissolved sulfate, isotopic ratios of strontium in water, stable isotopes of carbon in dissolved inorganic carbon, activities of tritium, and carbon-14 abundance), dissolved standard gases (methane, carbon dioxide, nitrogen, oxygen, and argon), and dissolved noble gases (argon, helium-4, krypton, neon, and xenon) were measured to help identify sources and ages of sampled groundwater. In total, 245 constituents and 8 water-quality indicators were measured. Quality-control samples (blanks, replicates, or matrix spikes) were collected at 16 percent of the wells in the WSJV study unit, and the results for these samples were used to evaluate the quality of the data from the groundwater samples. Blanks rarely contained detectable concentrations of any constituent, suggesting that contamination from sample collection procedures was not a significant source of bias in the data for the groundwater samples. Replicate samples all were within acceptable limits of variability. Matrix-spike recoveries were within the acceptable range (70 to 130 percent) for approximately 87 percent of the compounds. This study did not evaluate the quality of water delivered to consumers. After withdrawal, groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is delivered to the consumer, not to untreated groundwater. However, to provide some context for the results

  5. The case for NetCDF as a groundwater model output format using R: Example using USGS MODFLOW

    NASA Astrophysics Data System (ADS)

    Coulibaly, K. M.; Barnes, M.; Barnes, D.

    2011-12-01

    The USGS MODFLOW code has become the most widely used groundwater flow code throughout the world since its release in 1989. Because MODFLOW is a plain FORTRAN code with no graphical user interface (GUI) or visualization capabilities, model results visualization and analysis is usually done with commercial or open-source packages, and self-made FORTRAN snippets. The output format of MODFLOW is a FORTRAN binary which may vary depending on compilers and platforms. NetCDF, on the other hand, is a standardized, sharable and compact format which can be read and visualized with numerous free and commercial packages including R. It is also possible to embed useful geospatial information like coordinates, projection and grid discretization in the NetCDF which are absent in the FORTRAN binary. Using NetCDF as a standard model output format would allow modelers and non-modelers to easily share, visualize and plot model results using readily available software (R, ArcGIS, MS Excel, Paraview, GRASS GIS, SAGA GIS...etc). NetCDF is a particularly good format for storing large, multidimensional datasets. Many NetCDF tools were designed for the climate community, whose datasets are often orders of magnitude larger than datasets typically used in groundwater modeling. In this study R was used to generate a NetCDF file from a MODFLOW binary output and example analyses and visualizations were implemented. R has extensive statistical and plotting capabilities which are available to the user once MODFLOW outputs are available in NetCDF format.

  6. Establishment of Groundwater Arsenic Potential Distribution and Discrimination in Taiwan

    NASA Astrophysics Data System (ADS)

    Tsai, Kuo Sheng; Chen, Yu Ying; Chung Liu, Chih; Lin, Chien Wen

    2016-04-01

    According to the last 10 years groundwater monitoring data in Taiwan, Arsenic concentration increase rapidly in some areas, similar to Bengal and India, the main source of Arsenic-polluted groundwater is geological sediments, through reducing reactions. There are many researches indicate that high concentration of Arsenic in groundwater poses the risk to water safety, for example, the farm lands irrigation water contains Arsenic cause the concentration of Arsenic increase in soil and crops. Based on the management of water usage instead of remediation in the situation of insufficient water. Taiwan EPA has been developed the procedures of Arsenic contamination potential area establishment and source discriminated process. Taiwan EPA use the procedures to determine the management of using groundwater, and the proposing usage of Arsenic groundwater accordance with different objects. Agencies could cooperate with the water quality standard or water needs, studying appropriate water purification methods and the groundwater depth, water consumption, thus achieve the goal of water safety and environmental protection, as a reference of policy to control total Arsenic concentration in groundwater. Keywords: Arsenic; Distribution; Discrimination; Pollution potential area of Arsenic; Origin evaluation of groundwater Arsenic

  7. Assessing Risks of Shallow Riparian Groundwater Quality Near an Oil Sands Tailings Pond.

    PubMed

    Roy, J W; Bickerton, G; Frank, R A; Grapentine, L; Hewitt, L M

    2016-07-01

    The potential discharge of groundwater contaminated by oil sands process-affected water (OSPW) is a concern for aquatic ecosystems near tailings ponds. Groundwater in the area, but unaffected by OSPW, may contain similar compounds, complicating the assessment of potential ecological impacts. In this study, 177 shallow groundwater samples were collected from riparian areas along the Athabasca River and tributaries proximate to oil sands developments. For "pond-site" samples (71; adjacent to study tailings pond), Canadian aquatic life guidelines were exceeded for 11 of 20 assessed compounds. However, "non-pond" samples (54; not near any tailings pond) provided similar exceedances. Statistical analyses indicate that pond-site and non-pond samples were indistinguishable for all but seven parameters assessed, including salts, many trace metals, and fluorescence profiles of aromatic naphthenic acids (ANA). This suggests that, regarding the tested parameters, groundwater adjacent to the study tailings pond generally poses no greater ecological risk than other nearby groundwaters at this time. Multivariate analyses applied to the groundwater data set separated into 11 smaller zones support this conclusion, but show some variation between zones. Geological and potential OSPW influences could not be distinguished based on major ions and metals concentrations. However, similarities in indicator parameters, namely ANA, F, Mo, Se, and Na-Cl ratio, were noted between a small subset of samples from two pond-site zones and two OSPW samples and two shallow groundwater samples documented as likely OSPW affected. This indicator-based screening suggests that OSPW-affected groundwater may be reaching Athabasca River sediments at a few locations. PMID:26743232

  8. Wellbore-wall compression effects on monitored groundwater levels and qualities.

    PubMed

    Eguchi, S; Sawamoto, M; Shiba, M; Iiyama, I; Hasegawa, S

    2013-01-01

    The effects of wellbore-wall compression from rough excavation on monitored groundwater levels and qualities under natural hydraulic gradient conditions were investigated in a shallow clayey Andisol aquifer. Nine wellbores reaching the underlying aquitard at about 2.6-m depth were constructed by dynamic cone penetrometry to mimic rough wellbore construction. Five of these were constructed under wet aquifer soil conditions and the remaining four under dry conditions. A 15-month period monitoring showed that the groundwater levels in the wellbores constructed under wet conditions responded significantly in retard of, and in narrower ranges than, those constructed under dry conditions. The wellbore-wall hydraulic conductivities at the former wellbores were calculated to be more than one to two orders of magnitude lower than those at the latter ones. Furthermore, remarkable nitrate removal attributable to the occurrence of a heterotrophic denitrification was observed in one of the former wellbores. In contrast, the groundwater levels and qualities in the latter wellbores appeared to be generally similar to those monitored in the conventional soil coring and augering-derived wellbores. Our results suggest that the wellbore-wall compression induced by rough excavation under wet and soft aquifer soil conditions leads to a substantial decrease in the wellbore-wall hydraulic conductivity, which in turn can lead to unreliable groundwater levels and qualities. This problem can occur in clayey Andisols whenever the aquifer soil is wet; however, the problem can be largely avoided by constructing the wellbore under dry and hard aquifer soil conditions. PMID:22924593

  9. Ground-water quality at the Management Systems Evaluation Area (MSEA) near Princeton, Minnesota, 1991

    USGS Publications Warehouse

    Landon, M.K.; Delin, G.N.; Lamb, J.A.; Guo, Laodong

    1993-01-01

    The northern cornbelt sand-plains Management Systems Evaluation Area (MSEA) program is a multiagency, multistate initiative to evaluate the effects of modified and prevailing fanning systems on water quality in a sand-plain area in Minnesota and at satellite areas in North and South Dakota, and Wisconsin (Delin and others, 1992). The primary objective of the northern cornbelt sand-plains MSEA is to evaluate the effects of ridge-tillage practices in a corn and soybean farming system on ground-water quality. The Minnesota MSEA program is a cooperative study primarily between the U.S. Department of Agriculture-Agricultural Research Service, the University of Minnesota Soil Science Department, and the U.S. Geological Survey. The Minnesota Pollution Control Agency and the Department of Geology and Geophysics at the University of Minnesota are also cooperating in the evaluation of ground-water quality at the MSEA.

  10. Ground-water quality at the Management Systems Evaluation Area near Princeton, Minnesota, 1991-92

    USGS Publications Warehouse

    Landon, M.K.; Delin, G.N.; Lamb, J.A.; Guo, Lei

    1993-01-01

    The northern cornbelt sand-plains Management Systems Evaluation Area (MSEA) program is a multiagency, multistate initiative to evaluate the effects of modified and prevailing farming systems on water quality in a sand-plain area in Minnesota and at satellite areas in North and South Dakota, and Wisconsin. The primary objective of Minnesota MSEA is to evaluate the effects of ridge-tillage practices in a corn and soybean farming system on ground-water quality. The Minnesota MSEA program is a cooperative study primarily between the U.S. Department of Agriculture Agricultural Research Service, the University of Minnesota Soil Science Department, and the U.S. Geological Survey. The Minnesota Pollution Control Agency and the Department of Geology and Geophysics at the University of Minnesota are also cooperating in the evaluation of groundwater quality at the MSEA.

  11. Ground-water quality in Wisconsin through 1972

    USGS Publications Warehouse

    Skinner, E.L.; Holt, C. L. R., Jr.

    1972-01-01

    Ground water, a plentiful and largely underdeveloped resource of Wisconsin, has good to excellent chemical quality in most places. This resource is readily available in most parts of the State for municipal, industrial, and rural uses. In 1970, about 0.5 billion gallons of ground water a day was pumped in Wisconsin for all uses (Murray and Reeves, 1972). In addition, underground reservoirs discharge an average of 16 billion gallons per day of water of relatively constant temperature and uniform quality, which maintains the base flow of streams and the level of lakes (Holt, 1964).

  12. A Comprehensive Analysis of Groundwater Quality in The Barnett Shale Region.

    PubMed

    Hildenbrand, Zacariah L; Carlton, Doug D; Fontenot, Brian E; Meik, Jesse M; Walton, Jayme L; Taylor, Josh T; Thacker, Jonathan B; Korlie, Stephanie; Shelor, C Phillip; Henderson, Drew; Kadjo, Akinde F; Roelke, Corey E; Hudak, Paul F; Burton, Taylour; Rifai, Hanadi S; Schug, Kevin A

    2015-07-01

    The exploration of unconventional shale energy reserves and the extensive use of hydraulic fracturing during well stimulation have raised concerns about the potential effects of unconventional oil and gas extraction (UOG) on the environment. Most accounts of groundwater contamination have focused primarily on the compositional analysis of dissolved gases to address whether UOG activities have had deleterious effects on overlying aquifers. Here, we present an analysis of 550 groundwater samples collected from private and public supply water wells drawing from aquifers overlying the Barnett shale formation of Texas. We detected multiple volatile organic carbon compounds throughout the region, including various alcohols, the BTEX family of compounds, and several chlorinated compounds. These data do not necessarily identify UOG activities as the source of contamination; however, they do provide a strong impetus for further monitoring and analysis of groundwater quality in this region as many of the compounds we detected are known to be associated with UOG techniques. PMID:26079990

  13. Impact of long-term land application of biosolids on groundwater quality and surface soils

    SciTech Connect

    Surampalli, R.Y.; Lin, K.L.; Banerji, S.K.

    1995-11-01

    A study was conducted to evaluate the long-term land application of Biosolids and its potential impact on groundwater quality and surface soils. For this study, an existing site, that has been in operation for 8--15 years were selected for sampling and analyses. From this site sludge applied soil samples, background soil samples, and groundwater monitoring samples were obtained. The samples were analyzed for the following: pH, conductivity, total solids, fecal coliform, fecal streptococci, nitrate nitrogen, ammonia nitrogen, TKN, arsenic, cadmium, chromium, copper, nickel, lead, and zinc. The results of this study indicate that groundwater at this biosolids application site was not contaminated with heavy metals or pathogens. The bacteriological soil data also indicated that the levels of fecal coliform and fecal streptococci were close to background level with no evidence of contamination. The results also indicate that there is no heavy metals buildup in biosolids-amended soils.

  14. 48 CFR 22.1003-5 - Some examples of contracts covered.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... Standards statute (see 29 CFR 4.130 for additional examples): (a) Motor pool operation, parking, taxicab..., illustrating, graphic arts, stenographic reporting, or mortuary services. (j) Electronic equipment maintenance..., for example, aircraft, engines, electrical motors, vehicles, and electronic, office and...

  15. Calendar year 1995 groundwater quality report for the Chestnut Ridge Hydrogeological Regime, Oak Ridge Y-12 Plant, Oak Ridge, Tennessee. 1995 Groundwater quality data and calculated rate of contaminant migration

    SciTech Connect

    1996-02-01

    This annual groundwater quality report (GWQR) contains groundwater quality data obtained during the 1995 calendar year (CY) at several hazardous and nonhazardous waste management facilities associated with the U.S. Department of Energy (DOE) Y-12 Plant located on the DOE Oak Ridge Reservation (ORR) southeast of Oak Ridge, Tennessee. These sites are located south of the Y-12 Plant in the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime), which is one of three regimes defined for the purposes of groundwater quality monitoring at the Y-12 Plant. The Environmental Management Department of the Y-12 Plant Health, Safety, Environment, and Accountability (HSEA) Organization manages the groundwater monitoring activities in each regime as part of the Y-12 Plant Groundwater Protection Program (GWPP). The U.S. Environmental Protection Agency (EPA) identification number for the Y-12 Plant is TN.

  16. Hydrochemical and microbiological quality of groundwater in West Thrace Region of Turkey

    NASA Astrophysics Data System (ADS)

    Özler, H. Murat; Aydın, Ali

    2008-03-01

    The aim of this study was to do a preliminary assessment of the hydrochemical and microbial groundwater quality of the West Thrace region. Forty samples of groundwater collected from Edirne (Site 1) to Gelibolu (Site 2) were assessed for their suitability for human consumption. As3- was non-detectable in all the groundwater and Zn2+, Pb2+, F-, Cu2+, NH{4/+}, Cn- PO{4/3-} and Cl- were all below their respective European Union drinking water directive (EU-DWD) and Turkish food codex-drinking water directive (TFC-DWD). Maximum Acceptable Concentrations (MAC) Ni2+, Pb2+, Cd2+, Mg2+, Mn2+, and Ca2+ levels were detected in upper maximum acceptable concentrations 77.5, 42.5, 35.0, 50.0, 50.0, and 32.5% of the groundwater samples, respectively. However, in terms of Cr3+, Ni2+ and Pb2+, the differences between groundwaters of Sites 1 and 2 were significant ( p < 0.05). Eight water samples (20%) had HPC exceeding the EU and Turkish water directive limit 20 CFU (Colony Forming Unit)/ml in drinking water and the maximum bacteria count recorded was 44 CFU/ml. Total coliforms, thermotolerant coliforms, E. coli, Enterococcus spp., Salmonella sp., Staphylococcus spp. and P. aeruginosa were detected in 25, 17.5, 15, 47.5, 15, 27.5, and 15% of the groundwater samples, respectively. Furthermore, heavy metals and trace elements were found after chemical analyzes in most samples. The pollution of groundwater come from a variety of sources, Meric and Ergene rivers, including land application of agricultural chemicals and organics wastes, infiltration of irrigation water, septic tanks, and infiltration of effluent from sewage treatment plants, pits, lagoons and ponds used storage.

  17. Assessment of groundwater quality at a MSW landfill site using standard and AHP based water quality index: a case study from Ranchi, Jharkhand, India.

    PubMed

    Chakraborty, Shubhrasekhar; Kumar, R Naresh

    2016-06-01

    Landfill leachate generated from open MSW dumpsite can cause groundwater contamination. The impact of open dumping of MSW on the groundwater of adjacent area was studied. To assess the spatial and temporal variations in groundwater quality, samples were collected around an open MSW dumping site in Ranchi city, Jharkhand, India. Groundwater samples were analysed for various physicochemical and bacteriological parameters for 1 year. Results indicated that the groundwater is getting contaminated due to vertical and horizontal migration of landfill leachate. Extent of contamination was higher in areas closer to the landfill as indicated by high alkalinity, total dissolved solids and ammonia concentration. Metals such as lead, iron, and manganese were present at concentrations of 0.097, 0.97 and 0.36 mg/L, respectively exceeding the Bureau of Indian Standards (BIS) 10,500 for drinking water. Enterobacteriaceae were also detected in several groundwater samples and highest coliform count of 2.1×10(4) CFU/mL was recorded from a dug well. In order to determine the overall groundwater quality, water quality index (WQI) was calculated using weighted arithmetic index method and this index was further modified by coupling with the analytical hierarchy process (AHP) to get specific information. WQI values indicated that the overall groundwater quality of the region came under "poor" category while zone wise classification indicated the extent of impact of landfill leachate on groundwater. PMID:27155859

  18. Deterministic modelling of the cumulative impacts of underground structures on urban groundwater flow and the definition of a potential state of urban groundwater flow: example of Lyon, France

    NASA Astrophysics Data System (ADS)

    Attard, Guillaume; Rossier, Yvan; Winiarski, Thierry; Cuvillier, Loann; Eisenlohr, Laurent

    2016-02-01

    Underground structures have been shown to have a great influence on subsoil resources in urban aquifers. A methodology to assess the actual and the potential state of the groundwater flow in an urban area is proposed. The study develops a three-dimensional modeling approach to understand the cumulative impacts of underground infrastructures on urban groundwater flow, using a case in the city of Lyon (France). All known underground structures were integrated in the numerical model. Several simulations were run: the actual state of groundwater flow, the potential state of groundwater flow (without underground structures), an intermediate state (without impervious structures), and a transient simulation of the actual state of groundwater flow. The results show that underground structures fragment groundwater flow systems leading to a modification of the aquifer regime. For the case studied, the flow systems are shown to be stable over time with a transient simulation. Structures with drainage systems are shown to have a major impact on flow systems. The barrier effect of impervious structures was negligible because of the small hydraulic gradient of the area. The study demonstrates that the definition of a potential urban groundwater flow and the depiction of urban flow systems, which involves understanding the impact of underground structures, are important issues with respect to urban underground planning.

  19. Deterministic modelling of the cumulative impacts of underground structures on urban groundwater flow and the definition of a potential state of urban groundwater flow: example of Lyon, France

    NASA Astrophysics Data System (ADS)

    Attard, Guillaume; Rossier, Yvan; Winiarski, Thierry; Cuvillier, Loann; Eisenlohr, Laurent

    2016-08-01

    Underground structures have been shown to have a great influence on subsoil resources in urban aquifers. A methodology to assess the actual and the potential state of the groundwater flow in an urban area is proposed. The study develops a three-dimensional modeling approach to understand the cumulative impacts of underground infrastructures on urban groundwater flow, using a case in the city of Lyon (France). All known underground structures were integrated in the numerical model. Several simulations were run: the actual state of groundwater flow, the potential state of groundwater flow (without underground structures), an intermediate state (without impervious structures), and a transient simulation of the actual state of groundwater flow. The results show that underground structures fragment groundwater flow systems leading to a modification of the aquifer regime. For the case studied, the flow systems are shown to be stable over time with a transient simulation. Structures with drainage systems are shown to have a major impact on flow systems. The barrier effect of impervious structures was negligible because of the small hydraulic gradient of the area. The study demonstrates that the definition of a potential urban groundwater flow and the depiction of urban flow systems, which involves understanding the impact of underground structures, are important issues with respect to urban underground planning.

  20. Impact of post-methanation distillery effluent irrigation on groundwater quality.

    PubMed

    Jain, N; Bhatia, A; Kaushik, R; Kumar, Sanjeev; Joshi, H C; Pathak, H

    2005-11-01

    Molasses-based distilleries generate large quantities of effluent, which is used for irrigation in many countries including India. The effluent is rich in organic and inorganic ions, which may leach down and pollute the groundwater. An on-farm experiment was conducted to assess the impact of long-term irrigation with post-methanation distillery effluent (PMDE) on nitrate, sulphate, chloride, sodium, potassium, and magnesium contents in the groundwater of two sites in northwest India. Electrical conductivity (EC), pH, total dissolved solids (TDS), sodium adsorption ratio (SAR) and colour were also determined to assess the chemical load in the groundwater. Nitrate content in the groundwater samples ranged from 16.95 mg L(-1) in the unamended fields to 59.81 mg L(-1) in the PMDE-amended fields during the 2-year study (2001-2002). Concentrations of TDS in water samples from tubewell of the amended field was higher by 40.4% over the tubewell water of the unamended field. Colour of the water samples of the amended fields was also darker than that of the unamended fields. The study indicated that the organic and inorganic ions added through the effluent could pose a serious threat to the groundwater quality if applied without proper monitoring. PMID:16308790

  1. Inversion of reservoir quality: An example from the Triassic Buntsandstein, offshore Netherlands

    SciTech Connect

    Purvis, K.; Okkerman, J. )

    1993-09-01

    Sandstones from the Triassic Main Buntsandstein form a major gas reservoir in the Netherlands offshore. The sequence is dominated by siliciclastics deposited in an arid continental setting, and include dune, interdune, sheetsand, and fluvial sandstones. Reduction in reservoir quality is caused primarily by dolomite, halite, and anhydrite cementation, with minor authigenic illite and chlorite. Integration of petrographic and isotopic data has allowed the origins and relative timing of the different cements to be constrained. The carbon and oxygen isotopic composition of dolomite ([delta][sup 13]C = -3.76 to -9.3%, [delta][sup 18]O = -3 to +2.9% PDB) combined with strontium isotopic data (0.7091 to 0.7109 [sup 86]Sr/[sup 87]Sr) suggest that is precipitated from meteoric groundwater. Halite and anhydrite formed from a mixture of meteoric water and saline fluids expelled from underlying evaporites and claystones. Sulfur isotopic data (+4.2 to +12.1 CDT) support6 this interpretation for the origin of the anhydrite. Precipitation of the major authigenic minerals occurred during early diagenesis, prior to burial depths of 500 m. Cementation and groundwater flow followed the zones of highest permeability and caused an inversion of reservoir quality. Sandstones with the highest depositional porosity and permeability (i.e., dune sandstones) are the most cemented, and have poorer reservoir quality compared to the fluvial and interdune sandstones, which originally had lower depositional porosity/permeability. Formation of authigenic illite and chlorite occurred during burial and has significantly reduced permeability. Information on the depositional settings and paleogeography, combined with expected groundwater flow, has helped define potential exploration areas of reduced reservoir quality as a result of extensive early cementation.

  2. Calendar year 1994 groundwater quality report for the Upper East Fork Poplar Creek Hydrogeologic Regime, Y-12 Plant, Oak Ridge, Tennessee: 1994 groundwater quality data and calculated rate of contaminant migration

    SciTech Connect

    1995-02-01

    This annual groundwater quality report (GWQR) contains groundwater and surface water quality data obtained during the 1994 calendar year (CY) at several waste-management facilities and a petroleum fuel underground storage tank (UST) site associated with the US Department of Energy (DOE) Y-12 Plant located on the DOE Oak Ridge Reservation (ORR) southeast of Oak Ridge, Tennessee. The sites addressed by this document are located within the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime). The East Fork Regime, which is one of three hydrogeologic regimes defined for the purposes of groundwater quality monitoring at the Y-12 Plant, encompasses the Y-12 Plant. The regime extends west from a surface water and shallow groundwater divide located near the west end of the plant to Scarboro Road (directions in this report are in reference to the Y-12 Plant grid system unless otherwise noted). The Environmental Management Department of the Y-12 Plant Health, Safety, Environment, and Accountability (HSEA) Organization manages the groundwater monitoring activities in each regime as part of the Y-12 Plant Groundwater Protection Program (GWPP). The purpose of the GWPP is to characterize the hydrogeology and to monitor groundwater quality at the Y-12 Plant and surrounding area to provide for protection of groundwater resources consistent with federal, state, and local requirements and in accordance with DOE Orders and Energy Systems corporate policy.

  3. Calendar year 1993 groundwater quality report for the Chestnut Ridge Hydrogeologic Regime, Y-12 Plant, Oak Ridge, Tennessee. 1993 groundwater quality data and calculated rate of contaminant migration, Part 1

    SciTech Connect

    Not Available

    1994-02-01

    This annual groundwater report contains groundwater quality data obtained during the 1993 calendar year (CY) at several hazardous and non-hazardous waste-management facilities associated with the US Department of Energy (DOE) Y-12 Plant located on the DOE Oak Ridge Reservation (ORR) southeast of Oak Ridge, Tennessee. These sites are located south of the Y-12 Plant in the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime), which is one of three regimes defined for the purposes of groundwater quality monitoring at the Y-12 Plant. The Environmental Management Department of the Y-12 Plant Health, Safety, Environment, and Accountability Organization manages the groundwater monitoring activities in each regime as part of the Y-12 Plant Groundwater Protection Program (GWPP). The annual groundwater report for the Chestnut Ridge Regime is completed in two-parts; Part 1 (this report) containing the groundwater quality data and Part 2 containing a detailed evaluation of the data. The primary purpose of this report is to serve as a reference for the groundwater quality data obtained each year under the lead of the Y-12 Plant GWPP. However, because it contains information needed to comply with Resource Conservation and Recovery Act (RCRA) interim status assessment monitoring and reporting requirements, this report is submitted to the Tennessee Department of Health and Environment (TDEC) by the RCRA reporting deadline.

  4. Ground-water quality in Bannock, Bear Lake, Caribou, and part of Power counties, southeastern Idaho

    USGS Publications Warehouse

    Seitz, H.R.; Norvitch, R.F.

    1979-01-01

    The 103 wells sampled during the study establish a quasi-network that could be resampled in the future to document and analyze changes in ground-water quality in the southeastern Idaho study area. The main aquifers are categorized as alluvium of Quaternary age, basalt of Quaternary and (or) Tertiary age, rocks of the Salt Lake Formation of Tertiary age, and undifferentiated bedrock of pre-Tertiary age. Dissolved solids, hardness, nitrite plus nitrate as nitrogen, and chloride concentrations in the ground waters ranged from 165 to 1,690; 78 to 1,700; 0 to 29; and 1.9 to 360 milligrams per liter, respectively. The areal distributions of these constituents are shown on maps. The range and median values of these same constituents are tabulated by aquifer occurrence. Some of the most mineralized and hardest waters occur in the basalt aquifer near travertine deposits (or terraces), which are composed of calcium carbonate precipitates from mineral springs. For irrigation purposes, all the waters are classified as having low-sodium hazard. Most have medium- to high-salinity hazard. (Woodard-USGS)

  5. Management of groundwater supply and water quality in the Los Angeles Basin, California

    USGS Publications Warehouse

    Reichard, E.G.; Crawford, S.M.; Land, M.T.; Paybins, K.S.

    1999-01-01

    Water use and water needs in the coastal Los Angeles Basin in California have been very closely tied to the development of the region during the last 150 years. The first water wells were drilled in the mid-1800s. Currently about 40% of the water supply (9.4 m3 s-1) in the region is provided by groundwater. Other sources of water supply include reclaimed water and surface water imported from Owens Valley, the Colorado River, and northern California. Increasing groundwater use in the basin led to over-abstraction and seawater instrusion. Because of this, an important component of water management in the area has been the artificial recharge of local, imported, and reclaimed water which is spread in ponds and injected in wells to recharge the aquifer system and control seawater intrusion. The US Geological Survey (USGS) is working co-operatively with the Water Replenishment District of Southern California to evaluate the hydraulic and water-quality effects of these recharge operations and to assess the potential impacts of alternative water-management strategies, including changes in pumping and increases in the use of reclaimed water. As part of this work, the USGS has developed a geographic information system (GIS), collected water-quality and geohydrological data from new and existing wells, and developed a multi-aquifer regional groundwater flow model. Chemical and isotopic data were used to identify the age and source of recharge to groundwater throughout the study area. This information is key to understanding the fate of artificially recharged water and helps define the three-dimensional groundwater flow system. The geohydrological data, especially the geophysical and geological data collected from 11 newly installed multi-completion monitoring wells, were used to redefine the regional hydrostratigraphy. The groundwater flow model is being used to enhance the understanding of the geohydrological system and to quantitatively evaluate new water

  6. Quality-assurance and data management plan for groundwater activities by the U.S. Geological Survey in Kansas, 2014

    USGS Publications Warehouse

    Putnam, James E.; Hansen, Cristi V.

    2014-01-01

    As the Nation’s principle earth-science information agency, the U.S. Geological Survey (USGS) is depended on to collect data of the highest quality. This document is a quality-assurance plan for groundwater activities (GWQAP) of the Kansas Water Science Center. The purpose of this GWQAP is to establish a minimum set of guidelines and practices to be used by the Kansas Water Science Center to ensure quality in groundwater activities. Included within these practices are the assignment of responsibilities for implementing quality-assurance activities in the Kansas Water Science Center and establishment of review procedures needed to ensure the technical quality and reliability of the groundwater products. In addition, this GWQAP is intended to complement quality-assurance plans for surface-water and water-quality activities and similar plans for the Kansas Water Science Center and general project activities throughout the USGS. This document provides the framework for collecting, analyzing, and reporting groundwater data that are quality assured and quality controlled. This GWQAP presents policies directing the collection, processing, analysis, storage, review, and publication of groundwater data. In addition, policies related to organizational responsibilities, training, project planning, and safety are presented. These policies and practices pertain to all groundwater activities conducted by the Kansas Water Science Center, including data-collection programs, interpretive and research projects. This report also includes the data management plan that describes the progression of data management from data collection to archiving and publication.

  7. Denver's Urban Ground-Water Quality: Nutrients, Pesticides, and Volatile Organic Compounds

    USGS Publications Warehouse

    Bruce, Breton W.

    1995-01-01

    A recent study by the U.S. Geological Survey (USGS) under the National Water-Quality Assessment (NAWQA) program characterized the ground-water quality in a part of the Denver, Colorado, metropolitan area. The study provides an assessment of water-quality conditions in an alluvial aquifer that drains into the South Platte River. Thirty wells randomly distributed in residential, commercial, and industrial land-use settings were sampled once in 1993 for a broad range of compounds. Nutrients, pesticides, and volatile organic compounds (VOC's), all of which are generally associated with human activities, frequently were detected in the urban wells sampled. Nutrients and VOC's occasionally exceeded drinking-water standards.

  8. Seawater Intrusion Impacts on the Water Quality of the Groundwater on theNorthwest Coast of Oman.

    PubMed

    Ahmed, Abdelkader T; Askri, Brahim

    2016-08-01

    The groundwater aquifer in the coastal region of the northwest of Oman has been used extensively since the early 1980s for agricultural, industrial and municipal purposes. The over pumping of this reservoir has led to the intrusion of seawater and therefore to the deterioration of the groundwater quality. In this study, an investigation was carried out in the southern part of this region to identify the quality of groundwater, to understand the main sources of groundwater mineralisation, and to check the suitability of groundwater for drinking and irrigation. The spatial distributions and temporal variations of groundwater level and electrical conductivity were studied for the period from 1982 to 2005 using data collected from 225 wells. In addition, groundwater samples were collected recently in 2012 from eight wells and analysed for pH, EC, and major ions to understand the sources of dissolved ions and assess the chemical quality of the groundwater. The study area was divided into two strips parallel to the coastline, A and B, located in the discharge and recharge parts of the aquifer, respectively. Results showed a significant increase in the degree of water mineralisation in the direction of south to north following the regional flow direction. Results showed also that the groundwater in the last area could be used for irrigation with little danger of exchangeable sodium while this aquifer is unsuitable for irrigation in the discharge area because it presents a very high salinity hazard. PMID:27456143

  9. The impact of on-site wastewater from high density cluster developments on groundwater quality

    NASA Astrophysics Data System (ADS)

    Morrissey, P. J.; Johnston, P. M.; Gill, L. W.

    2015-11-01

    The net impact on groundwater quality from high density clusters of unsewered housing across a range of hydro(geo)logical settings has been assessed. Four separate cluster development sites were selected, each representative of different aquifer vulnerability categories. Groundwater samples were collected on a monthly basis over a two year period for chemical and microbiological analysis from nested multi-horizon sampling boreholes upstream and downstream of the study sites. The field results showed no statistically significant difference between upstream and downstream water quality at any of the study areas, although there were higher breakthroughs in contaminants in the High and Extreme vulnerability sites linked to high intensity rainfall events; these however, could not be directly attributed to on-site effluent. Linked numerical models were then built for each site using HYDRUS 2D to simulate the attenuation of contaminants through the unsaturated zone from which the resulting hydraulic and contaminant fluxes at the water table were used as inputs into MODFLOW MT3D models to simulate the groundwater flows. The results of the simulations confirmed the field observations at each site, indicating that the existing clustered on-site wastewater discharges would only cause limited and very localised impacts on groundwater quality, with contaminant loads being quickly dispersed and diluted downstream due to the relatively high groundwater flow rates. Further simulations were then carried out using the calibrated models to assess the impact of increasing cluster densities revealing little impact at any of the study locations up to a density of 6 units/ha with the exception of the Extreme vulnerability site.

  10. The impact of on-site wastewater from high density cluster developments on groundwater quality.

    PubMed

    Morrissey, P J; Johnston, P M; Gill, L W

    2015-11-01

    The net impact on groundwater quality from high density clusters of unsewered housing across a range of hydro(geo)logical settings has been assessed. Four separate cluster development sites were selected, each representative of different aquifer vulnerability categories. Groundwater samples were collected on a monthly basis over a two year period for chemical and microbiological analysis from nested multi-horizon sampling boreholes upstream and downstream of the study sites. The field results showed no statistically significant difference between upstream and downstream water quality at any of the study areas, although there were higher breakthroughs in contaminants in the High and Extreme vulnerability sites linked to high intensity rainfall events; these however, could not be directly attributed to on-site effluent. Linked numerical models were then built for each site using HYDRUS 2D to simulate the attenuation of contaminants through the unsaturated zone from which the resulting hydraulic and contaminant fluxes at the water table were used as inputs into MODFLOW MT3D models to simulate the groundwater flows. The results of the simulations confirmed the field observations at each site, indicating that the existing clustered on-site wastewater discharges would only cause limited and very localised impacts on groundwater quality, with contaminant loads being quickly dispersed and diluted downstream due to the relatively high groundwater flow rates. Further simulations were then carried out using the calibrated models to assess the impact of increasing cluster densities revealing little impact at any of the study locations up to a density of 6 units/ha with the exception of the Extreme vulnerability site. PMID:26331764

  11. Changes in shallow groundwater quality beneath recently urbanized areas in the Memphis, Tennessee area

    USGS Publications Warehouse

    Barlow, Jeannie R.; Kingsbury, James A.; Coupe, Richard H.

    2012-01-01

    Memphis, the largest city in the state of Tennessee, and its surrounding suburbs depend on a confined aquifer, the Memphis aquifer, for drinking water. Concern over the potential for downward movement of water from an overlying shallow aquifer to the underlying Memphis aquifer provided impetus for monitoring groundwater quality within the shallow aquifer. The occurrence of volatile organic compounds (VOCs), nitrate, and pesticides in samples from the shallow well network indicate a widespread affect on water quality from the overlying urban land use. Total pesticide concentration was generally higher in more recently recharged groundwater indicating that as the proportion of recent water increases, the occurrence of pesticides related to the current urban land use also increases. Groundwater samples with nitrate concentrations greater than 1.5 mg/l and detectable concentrations of the pesticides atrazine and simazine also had higher concentrations of chloroform, a VOC primarily associated with urban land use, than in other samples. The age of the water from these wells indicates that these concentrations are most likely not representative of past agricultural use, but of more recent urban use of these chemicals. Given that the median age of water represented by the shallow well network was 21 years, a lag time likely exists between changes in land use and the occurrence of constituents related to urbanization in shallow groundwater.

  12. Assessment of groundwater quality in the coastal area of Sindh province, Pakistan.

    PubMed

    Alamgir, Aamir; Khan, Moazzam Ali; Schilling, Janpeter; Shaukat, S Shahid; Shahab, Shoaib

    2016-02-01

    Groundwater is a highly important resource, especially for human consumption and agricultural production. This study offers an assessment of groundwater quality in the coastal areas of Sindh province in Pakistan. Fifty-six samples of groundwater were taken at depths ranging from 30 to 50 m. Bacteriological and physico-chemical analyses were performed using the Standard Methods for the Examination of Water and Wastewater. These were supplemented with expert interviews and observations to identify the usage of water and potential sources of pollution. The quality of the groundwater was found to be unsuitable for human consumption, despite being used for this purpose. The concentrations of sulfate and phosphate were well within the tolerance limits. Most critical were the high levels of organic and fecal pollution followed by turbidity and salinity. Metal concentrations (As, Ca, Cr, Cu, Fe, Mg, Mn, Ni, Pb, and Zn) were also determined, and Ni and Pb strongly exceeded health standards. The study stresses the need for significant improvements of the irrigation, sanitation, and sewage infrastructure. PMID:26739008

  13. Quality modeling of drinking groundwater using GIS in rural communities, northwest of Iran

    PubMed Central

    2014-01-01

    Given the importance of groundwater resources in water supply, this work aimed to study quality of drinking groundwater in rural areas in Tabriz county, northwest of Iran. Thirty two groundwater samples from different areas were collected and analyzed in terms of general parameters along with 20 heavy metals (e.g. As, Hg and …). The data of the analyses were applied as an attribute database for preparing thematic maps and showing water quality parameters. Multivariate statistical techniques, including principal component analysis (PCA) and hierarchical cluster analysis (CA) were used to compare and evaluate water quality. The findings showed that hydrochemical faces of the groundwater were of calcium-bicarbonate type. EC values were from 110 to 1750 μs/cm, in which concentration of salts was high in the east and a zone in north of the studied area. Hardness was from 52 to 476 mg/l and CaCO3 with average value of 185.88 ± 106.56 mg/L indicated hard water. Dominant cations and anions were Ca2+ > Na+ > Mg2+ > K+ and HCO3− > Cl− > SO42− > NO32, respectively. In the western areas, arsenic contamination was observed as high as 69 μg/L. Moreover, mercury was above the standard level in one of the villages. Eskandar and Olakandi villages had the lowest quality of drinking water. In terms of CA, sampling sites were classified into four clusters of similar water quality and PCA demonstrated that 3 components could cover 84.3% of the parameters. For investigating arsenic anomaly, conducting a comprehensive study in the western part of studied area is strongly recommended. PMID:25093080

  14. Quality of groundwater on the newly dry bottom of the Aral Sea

    NASA Astrophysics Data System (ADS)

    Medeu, A.; Turtabayev, S.; Kurbaniyazov, A.

    2010-05-01

    Anthropogenic impacts on the groundwater can be quantified through the concentrations of non-organic and organic pollutants. We report results of chemical analyses of the water samples collected recently from groundwater wells on the newly dry bottom of the Aral Sea, a well as the Sea itself, and Amudarya River deltaic region. Of all the contaminants, the most important role in the Aral Sea region belongs to nitrates. The content of nitrates in the groundwater generally spans between 50 and 155 mg/l. At the same time, the water of the Aral Sea itself at different locations contained from 93 to 136 mg/l, while the tributary river (Amudarya) water was characterized by concentrations from 181 to 248 mg/l. The highest concentrations of nitrates were observed in the water sample collected from the nearby Sudochye Lake, i.e., 620 mg/l. These figures point towards very significant pollution resulting from agricultural fertilization. The level of pollution in the groundwater appears to be somewhat lower than that in the surface waters. Pollution of groundwater is also manifested in contents of some microcomponents, namely, Co, Cd, Pb, Mn, and Sr. The respective average contents of these elements in the analyzed groundwater samples were 1.7 mg/l, 0.9 mg/l, 0.16 mg/l, 0.2 mg/l, and 10.0 mg/l. The average mineralization of the groundwater was 65 g/l. The accumulation of heavy metals is likely to have been mainly associated with agricultural chemicals and/or mineral fertilizers. The more mobile components, such as Co and Sr, apparently migrated following the retreat of the Sea's shoreline, while the less mobile ones were mainly accumulated in the areas of irrigation and agriculture.

  15. Mapping of groundwater quality in the Turonian aquifer of Oum Er-Rabia Basin, Morocco: a case study

    NASA Astrophysics Data System (ADS)

    Ettazarini, Said

    2006-08-01

    This study takes the groundwater of the Moroccan limestone aquifer of Oum Er-Rabia as an example of statistical and cartographical approaches in water resources management. Statistical analyses based on frequency distribution and PCA methods revealed the homogeneity of waters with the existence of abnormal points and have helped to assess correlations between the studied variables. The mapping approach illustrated that waters are influenced by the lithology of the surrounding rocks and are of Ca Mg HCO3, Ca Mg Cl SO4, and mixed types according to the Piper classification. The quality of water is of high to medium, north of the basin, but it is of medium to bad, NE and south, due to excessive contents of chloride, sulfate and nitrate. According to the US Salinity Laboratory classification, water used for irrigation in the eastern and the southern parts of the basin should take into consideration the drainage conditions, the nature of plants and the addition of gypsum doses.

  16. Groundwater-surface water interactions and their effects on ecosystem metabolism in a coastal wetland: example from the Florida Everglades

    NASA Astrophysics Data System (ADS)

    Price, R. M.; Zapata, X.; Koch, G. R.

    2013-05-01

    Groundwater typically has higher concentrations of salts and nutrients as compared to surface waters in coastal wetlands affected by saltwater intrusion. Discharge of the nutrient-laden brackish groundwater is expected to influence ecosystem function in the overlying surface water. In the coastal Everglades, elevated concentrations of phosphorus have been observed in the underlying groundwater due to water-rock interactions occurring as seawater intrudes into the coastal carbonate aquifer. The objective of this research was to determine the timing and amount of brackish groundwater discharge to the coastal wetlands of the Everglades and to evaluate the effects of the groundwater discharge on the surface water chemistry and ecosystem metabolism. The timing of groundwater discharge was determined by four techniques including a water balance, hydraulic gradient, temperature, and geochemical tracers. Groundwater discharge rates were quantified from well data using Darcy's Law. Ecosystem metabolism was estimated as daily rates of gross primary production (GPP), ecosystem respiration (R) and net ecosystem production (NEP) from free-water, diel changes in dissolved oxygen. Over 2 years, all four groundwater discharge techniques converged as to the timing of groundwater discharge which was greatest between May and July. Surface water chemistry was fresh from September through February, but became brackish to hypersaline between March and July, concurrent with the times of highest brackish groundwater discharge. Phosphorus concentrations as well as GPP and R were observed to spike in the surface water during the times of greatest groundwater discharge. The results of this research support the conclusions that brackish groundwater discharge effects surface water chemistry and ecosystem function in the coastal Everglades.

  17. Ground-water quality beneath an urban residential and commercial area, Montgomery, Alabama, 1999-2000

    USGS Publications Warehouse

    Robinson, James L.

    2002-01-01

    The Black Warrior River aquifer, which is composed of the Coker, Gordo, and Eutaw Formations, supplies more than 50 percent of the ground water used for public water supply in the Mobile River Basin. The city of Montgomery, Alabama, is partially built upon a recharge area for the Black Warrior River aquifer, and is one of many major population centers that depend on the Black Warrior River aquifer for public water supply. To represent the baseline ground-water quality in the Black Warrior River aquifer, water samples were collected from 30 wells located in a low-density residential or rural setting; 9 wells were completed in the Coker Formation, 9 wells in the Gordo Formation, and 12 wells in the Eutaw Formation. To describe the ground-water quality beneath Montgomery, Alabama, water samples also were collected from 30 wells located in residential and commercial areas of Montgomery, Alabama; 16 wells were completed in the Eutaw Formation, 8 wells in alluvial deposits, and 6 wells in terrace deposits. The alluvial and terrace deposits directly overlie the Eutaw Formation with little or no hydraulic separation. Ground-water samples collected from both the rural and urban wells were analyzed for physical properties, major ions, nutrients, metals, volatile organic compounds, and pesticides. Samples from the urban wells also were analyzed for bacteria, chlorofluorocarbons, dissolved gases, and sulfur hexafluoride. Ground-water quality beneath the urban area was compared to baseline water quality in the Black Warrior River aquifer.Compared to the rural wells, ground-water samples from urban wells contained greater concentrations or more frequent detections of chloride and nitrate, and the trace metals aluminium, chromium, cobalt, copper, nickel, and zinc. Pesticides and volatile organic compounds were detected more frequently and in greater concentrations in ground-water samples collected from urban wells than in ground-water samples from rural wells.The Spearman rho

  18. Calendar Year 1994 Groundwater Quality Report for the Bear Creek Hydrogeologic Regime Y-12 Plant, Oak Ridge, Tennessee

    SciTech Connect

    1995-02-01

    This annual groundwater quality report (GWQR) contains groundwater and surface water quality data obtained during the 1994 calendar year (CY) at several hazardous and non-hazardous waste-management facilities associated with the U.S. Department of Energy (DOE) Y-12 Plant located on the DOE Oak Ridge Reservation (ORR) southeast of Oak Ridge, Tennessee. The sites addressed by this document are located in Bear Creek Valley (BCV) west of the Y-12 Plant complex (directions in this report are in reference to the Y-12 administrative grid system) within the Bear Creek Hydrogeologic Regime (Bear Creek Regime), one of three hydrogeologic regimes defined for the purposes of groundwater and surface water quality monitoring at the Y-12 Plant. The Environmental Management Department of the Y-12 Plant Health, Safety, Environment, and Accountability (HSEA) Organization manages the groundwater monitoring activities in the Bear Creek Regime under the auspices of the Y-12 Plant Groundwater Protection Program (GWPP). The purpose of the GWPP is to characterize the hydrogeology and to monitor groundwater quality at the Y-12 Plant and surrounding area to provide for protection of groundwater resources consistent with federal, state, and local requirements and in accordance with DOE Orders and Martin Marietta Energy Systems, Inc. (Energy Systems) corporate policy. The annual GWQR for the Bear Creek Regime is completed in two parts. Part 1 (this report) consists primarily of data appendices and serves as a reference for the groundwater quality data obtained each CY under the lead of the Y-12 Plant GWPP. Part 2 of the report, to be issued mid-year, will contain an evaluation of the data with respect to regime-wide groundwater quality, present the findings and status of ongoing hydrogeologic studies, describe changes in monitoring priorities, and present planned modifications to the groundwater sampling and analysis program for the following CY.

  19. EFFECTS OF ARTIFICIAL RECHARGE ON GROUND-WATER QUALITY, LONG ISLAND, NEW YORK.

    USGS Publications Warehouse

    Schneider, Brian J.; Ku, Henry F.H.; Oaksford, Edward T.

    1986-01-01

    Artificial-recharge experiments were conducted at East Meadow in central Nassau County, Long Island, N. Y. , from October 1982 through January 1984, to evaluate the degree of ground-water mounding and chemical effects of artificially replenishing the ground-water system with tertiary-treated wastewater. Reclaimed water was provided by the Cedar Creek wastewater-treatment plant in Wantagh. Recharge with reclaimed water increased the concentration of sodium and chloride in ground water but lowered the concentrations of total nitrogen (nitrate plus nitrite) and some low-molecular-weight hydrocarbons. Reclaimed water was well within the New York State effluent standards for ground-water recharge. Specific-conductance measurements and Stiff diagrams of chemical analyses were used to help define the extent and shape of the plume formed by reclaimed water.

  20. Ground-water levels and quality data for Georgia, 1978

    USGS Publications Warehouse

    Clarke, J.S.; Hester, W.G.; O'Byrne, M. P.

    1979-01-01

    Mean water levels in wells across Georgia were from 0.25 foot higher to 11.4 feet lower in 1978 than in 1977, and in some areas were the lowest on record. Water levels in the principal artesian aquifer underwent a long-term decline during the period 1969-78. In some areas water levels dropped more than 10 feet. Wells tapping the Clayton Limestone in the Albany area showed a long-term decline during the period 1969-78, and in some wells water levels dropped more than 20 feet. Water levels in the Cretaceous aquifer system showed little fluctuation during 1978; however, in a well located in Chattahoochee County, water levels declined 4.4 feet during 1969-78. In the Piedmont area mean water levels remained the same to 2.2 feet lower in 1978 than in 1977, and showed no long-term trend. Chloride concentrations in the principal artesian aquifer in the Savannah area remained stable and in the Brunswick area continued to rise during 1978. Daily mean water-level fluctuations and trends for 1978 and fluctuations of the monthly mean water level for the previous 10 years are shown in hydrographs of 33 selected observation wells in Georgia. Chloride concentrations in 11 wells in the Savannah and Brunswick areas are shown in graphs of monthly values over the previous 10 years. A short narrative explains fluctuations and trends in each of the hydrographs and chloride concentration graphs shown. (Woodard-USGS)

  1. Deterioration of coastal groundwater quality in Island and mainland regions of Ramanathapuram District, Southern India.

    PubMed

    Sivasankar, Venkataramann; Ramachandramoorthy, Thiagarajan; Chandramohan, A

    2013-01-01

    A study was carried out in the Island and mainland regions of Ramanathapuram District to characterize the physico-chemical characteristics of 87 groundwater samples in Island and 112 groundwater samples in mainland which include pH, EC, TDS, salinity, total alkalinity, calcium hardness, magnesium hardness, total hardness, chloride and fluoride. Heavy inorganic load in majority of the groundwater samples has been estimated due to the salinity, TDS, TH and chloride beyond the threshold level which substantiates the percolation of sea water into the freshwater confined zones. Although the groundwater sources are available in plenty, the scarcity of potable water is most prevalent in this coastal area. The Water Quality Index (WQI) and Langeleir Saturation Index (LSI) have also been calculated to know the potable and corrosive/incrusting nature of the water samples. The statistical tools such as principal component analysis, box plots and correlation matrix have also been used to explain the influence of different physico-chemical parameters with respect to one another among the groundwater samples. The percentage of groundwater samples in mainland was more than that in Island with respect to the acceptable limit of WHO drinking standard, especially in TDS, CH, TH and chloride but the converse is observed in the case of fluoride. About 8% of the mainland aquifers and 42% of Island aquifers were identified to have fluoride greater than 1.5 mg/l. The signature of salt-water intrusion is observed from the ratio of Cl/CO(3)(2-) + HCO(3) and TA/TH. A proper management plan to cater potable water to the immediate needs of the people is to be envisaged. PMID:22527453

  2. Groundwater quality in the Eastern Lake Ontario Basin of New York, 2008

    USGS Publications Warehouse

    Risen, Amy J.; Reddy, James E.

    2011-01-01

    Water samples were collected from nine production wells and nine private residential wells in the Eastern Lake Ontario Basin of New York from August through October 2008 and analyzed to characterize the chemical quality of groundwater. The wells were selected to provide adequate spatial coverage of the 3,225-square-mile study area; areas of greatest groundwater use were emphasized. Eight of the 18 wells sampled, were screened in sand and gravel aquifers, and 10 were finished in bedrock aquifers. The samples were collected and processed by standard U.S. Geological Survey procedures and were analyzed for 223 physical properties and constituents, including major ions, nutrients, trace elements, radon-222, pesticides, volatile organic compounds (VOCs), and indicator bacteria. Water quality in the study area is generally good, but concentrations of some constituents exceeded current or proposed Federal or New York State drinking-water standards; these were: color (2 samples), pH (1 sample), sodium (5 samples), chloride (1 sample), aluminum (2 samples), iron (5 unfiltered samples), manganese (3 samples), radon-222 (13 samples), and bacteria (4 samples). Dissolved-oxygen concentrations in samples from wells finished in sand and gravel [median 3.8 milligrams per liter (mg/L)] were greater than those from wells finished in bedrock (median less than 0.7 mg/L). The pH of all samples was typically neutral or slightly basic (median 7.4); the median water temperature was 11.3 degrees Celsius. The ions with the highest concentrations were bicarbonate (median 174 mg/L) and calcium (median 24.1 mg/L). Groundwater in the basin ranges from soft to moderately hard [less than or equal to 120 mg/L as CaCO3] and median hardness was 90 mg/L as CaCO3. Concentrations of nitrate plus nitrite in samples from sand and gravel wells (median concentration 0.42 mg/L as nitrogen) were generally higher than those in samples from bedrock wells (median <0.04 mg/L as nitrogen). The trace elements with

  3. Geochemistry of some rare earth elements in groundwater, Vierlingsbeek, The Netherlands.

    PubMed

    Janssen, René P T; Verweij, Wilko

    2003-03-01

    Groundwater samples were taken from seven bore holes at depths ranging from 2 to 41m nearby drinking water pumping station Vierlingsbeek, The Netherlands and analysed for Y, La, Ce, Pr, Nd, Sm and Eu. Shale-normalized patterns were generally flat and showed that the observed rare earth elements (REE) were probably of natural origin. In the shallow groundwaters the REEs were light REE (LREE) enriched, probably caused by binding of LREEs to colloids. To improve understanding of the behaviour of the REE, two approaches were used: calculations of the speciation and a statistical approach. For the speciation calculations, complexation and precipitation reactions including inorganic and dissolved organic carbon (DOC) compounds, were taken into account. The REE speciation showed REE(3+), REE(SO(4))(+), REE(CO(3))(+) and REE(DOC) being the major species. Dissolution of pure REE precipitates and REE-enriched solid phases did not account for the observed REEs in groundwater. Regulation of REE concentrations by adsorption-desorption processes to Fe(III)(OH)(3) and Al(OH)(3) minerals, which were calculated to be present in nearly all groundwaters, is a probable explanation. The statistical approach (multiple linear regression) showed that pH is by far the most significant groundwater characteristic which contributes to the variation in REE concentrations. Also DOC, SO(4), Fe and Al contributed significantly, although to a much lesser extent, to the variation in REE concentrations. This is in line with the calculated REE-species in solution and REE-adsorption to iron and aluminium (hydr)oxides. Regression equations including only pH, were derived to predict REE concentrations in groundwater. External validation showed that these regression equations were reasonably successful to predict REE concentrations of groundwater of another drinking water pumping station in quite different region of The Netherlands. PMID:12598196

  4. An economic value of remote-sensing information—Application to agricultural production and maintaining groundwater quality

    USGS Publications Warehouse

    Forney, William M.; Raunikar, Ronald P.; Bernknopf, Richard L.; Mishra, Shruti K.

    2012-01-01

    Does remote-sensing information provide economic benefits to society, and can a value be assigned to those benefits? Can resource management and policy decisions be better informed by coupling past and present Earth observations with groundwater nitrate measurements? Using an integrated assessment approach, the U.S. Geological Survey (USGS) applied an established conceptual framework to answer these questions, as well as to estimate the value of information (VOI) for remote-sensing imagery. The approach uses moderate-resolution land-imagery (MRLI) data from the Landsat and Advanced Wide Field Sensor satellites that has been classified by the National Agricultural Statistics Service into the Cropland Data Layer (CDL). Within the constraint of the U.S. Environmental Protection Agency's public health threshold for potable groundwater resources, the USGS modeled the relation between a population of the CDL's land uses and dynamic nitrate (NO3-) contamination of aquifers in a case study region in northeastern Iowa. Employing various multiscaled, multitemporal geospatial datasets with MRLI to maximize the value of agricultural production, the approach develops and uses multiple environmental science models to address dynamic nitrogen loading and transport at specified distances from specific sites (wells) and at landscape scales (for example, across 35 counties and two aquifers). In addition to the ecosystem service of potable groundwater, this effort focuses on the use of MRLI for the management of the major land uses in the study region-the production of corn and soybeans, which can impact groundwater quality. Derived methods and results include (1) economic and dynamic nitrate-pollution models, (2) probabilities of the survival of groundwater, and (3) a VOI for remote sensing. For the northeastern Iowa study region, the marginal benefit of the MRLI VOI (in 2010 dollars) is $858 million ±$197 million annualized, which corresponds to a net present value of $38

  5. Regional Evaluation of Groundwater Age Distributions Using Lumped Parameter Models with Large, Sparse Datasets: Example from the Central Valley, California, USA

    NASA Astrophysics Data System (ADS)

    Jurgens, B. C.; Bohlke, J. K.; Voss, S.; Fram, M. S.; Esser, B.

    2015-12-01

    Tracer-based, lumped parameter models (LPMs) are an appealing way to estimate the distribution of age for groundwater because the cost of sampling wells is often less than building numerical groundwater flow models sufficiently complex to provide groundwater age distributions. In practice, however, tracer datasets are often incomplete because of anthropogenic or terrigenic contamination of tracers, or analytical limitations. While age interpretations using such datsets can have large uncertainties, it may still be possible to identify key parts of the age distribution if LPMs are carefully chosen to match hydrogeologic conceptualization and the degree of age mixing is reasonably estimated. We developed a systematic approach for evaluating groundwater age distributions using LPMs with a large but incomplete set of tracer data (3H, 3Hetrit, 14C, and CFCs) from 535 wells, mostly used for public supply, in the Central Valley, California, USA that were sampled by the USGS for the California State Water Resources Control Board Groundwater Ambient Monitoring and Assessment or the USGS National Water Quality Assessment Programs. In addition to mean ages, LPMs gave estimates of unsaturated zone travel times, recharge rates for pre- and post-development groundwater, the degree of age mixing in wells, proportion of young water (<60 yrs), and the depth of the boundary between post-development and predevelopment groundwater throughout the Central Valley. Age interpretations were evaluated by comparing past nitrate trends with LPM predicted trends, and whether the presence or absence of anthropogenic organic compounds was consistent with model results. This study illustrates a practical approach for assessing groundwater age information at a large scale to reveal important characteristics about the age structure of a major aquifer, and of the water supplies being derived from it.

  6. Appraisal of ground-water quality in the Bunker Hill Basin of San Bernardino Valley, California

    USGS Publications Warehouse

    Duell, L.F., Jr.; Schroeder, R.A.

    1989-01-01

    Water samples were collected from 47 wells and analyzed for concentration of major inorganic ions, nitrogen species, and volatile (purgeable) organic priority pollutants to assess groundwater quality in the Bunker Hill basin, California. Data were supplemented with additional analysis of nitrate, tetrachloroethylene, and trichloroethylene made by other agencies. The organic quality of groundwater in the basin generally is suitable for most uses, although fluoride concentration exceeded the California public drinking water standard of 1.4 mg/L in water from 5 of 47 wells. Nitrate (as nitrogen) concentration equaled or exceeded the public drinking water standard of 10 mg/L in water from 13 of 47 wells sampled for this study and in an additional 19 of 120 samples analyzed by other agencies. Concentration generally decreased with increasing depth below land surface. Twenty-four of the 33 volatile organic priority pollutants were detected in water from wells sampled during this study. When supplemental data from other agencies are included, tetrachloroethylene concentration exceeded the standard of 5 micrograms/L in water from 49 of 128 wells. No basinwide relation between contamination by these two chemicals and well depth or land use was discerned. A network of 11 observation wells that could be sampled twice a year would enhance the monitoring of changes groundwater quality in the Bunker Hill basin. (USGS)

  7. Application of multivariate statistical techniques for characterization of groundwater quality in the coastal aquifer of Nador, Tipaza (Algeria)

    NASA Astrophysics Data System (ADS)

    Bouderbala, Abdelkader; Remini, Boualem; Saaed Hamoudi, Abdelamir; Pulido-Bosch, Antonio

    2016-06-01

    The study focuses on the characterization of the groundwater salinity on the Nador coastal aquifer (Algeria). The groundwater quality has undergone serious deterioration due to overexploitation. Groundwater samplings were carried out in high and low waters in 2013, in order to study the evolution of groundwater hydrochemistry from the recharge to the coastal area. Different kinds of statistical analysis were made in order to identify the main hydrogeochemical processes occurring in the aquifer and to discriminate between different groups of groundwater. These statistical methods provide a better understanding of the aquifer hydrochemistry, and put in evidence a hydrochemical classification of wells, showing that the area with higher salinity is located close to the coast, in the first two kilometers, where the salinity gradually increases as one approaches the seaside and suggests the groundwater salinization by seawater intrusion.

  8. GROUND-WATER QUALITY CLASSIFICATION FOR THE VALLEY-FILL AQUIFER IN SPANISH VALLEY, GRAND AND SAN JUAN COUNTIES, UTAH --A BASIS FOR PRESERVING HIGH QUALITY GROUND-WATER RESOURCES, UTAH GEOLOGICAL SURVEY

    EPA Science Inventory

    The proposed study will consist of an evaluation of current ground-water quality using the Utah Water Quality Board's ground-water-quality classification system based mostly on total-dissolved-solids concentrations as follows: class 1A (Pristine), less than 500 mg/L; class 2 (dr...

  9. An evaluation of effects of groundwater exchange on nearshore habitats and water quality of western Lake Erie

    USGS Publications Warehouse

    Haack, Sheridan K.; Neff, Brian P.; Rosenberry, Donald O.; Savino, Jacqueline F.; Lundstrom, Scott C.

    2005-01-01

    Historically, the high potentiometric surface of groundwater in the Silurian/Devonian carbonate aquifer in Monroe County, MI resulted in discharge of highly mineralized, SO4-rich groundwater to the Lake Erie shoreline near both Erie State Game Area (ESGA) and Pointe Mouillee State Game Area (PMSGA). Recently, regional groundwater levels near PMSGA have been drawn down as much as 45 m below lake level in apparent response to quarry dewatering. From August to November of 2003, we conducted preliminary studies of groundwater flow dynamics and chemistry, shallow lake water chemistry, and fish and invertebrate communities at both sites. Consistent with regional observations, groundwater flow direction in the nearshore at ESGA was upward, or toward Lake Erie, and shallow nearshore groundwater chemistry was influenced by regional groundwater chemistry. In contrast, at PMSGA, the groundwater flow potential was downward and lake water, influenced by quarry discharge seeping downward into nearshore sediments, produced a different lake and shallow groundwater chemistry than at ESGA. Although the invertebrate and young fish community was similar at the two sites, taxonomic groups tolerant of degraded water quality were more prevalent at PMSGA. Sensitive taxa were more prevalent at ESGA. We propose a conceptual model, based on well-described models of groundwater/seawater interaction along coastal margins, to describe the interconnection among geologic, hydrologic, chemical, and biological processes in the different nearshore habitats of Lake Erie, and we identify processes that warrant further detailed study in the Great Lakes.

  10. Application of Integral Pumping Tests to estimate the influence of losing streams on groundwater quality

    NASA Astrophysics Data System (ADS)

    Leschik, S.; Musolff, A.; Reinstorf, F.; Strauch, G.; Schirmer, M.

    2009-05-01

    Urban streams receive effluents of wastewater treatment plants and untreated wastewater during combined sewer overflow events. In the case of losing streams substances, which originate from wastewater, can reach the groundwater and deteriorate its quality. The estimation of mass flow rates Mex from losing streams to the groundwater is important to support groundwater management strategies, but is a challenging task. Variable inflow of wastewater with time-dependent concentrations of wastewater constituents causes a variable water composition in urban streams. Heterogeneities in the structure of the streambed and the connected aquifer lead, in combination with this variable water composition, to heterogeneous concentration patterns of wastewater constituents in the vicinity of urban streams. Groundwater investigation methods based on conventional point sampling may yield unreliable results under these conditions. Integral Pumping Tests (IPT) can overcome the problem of heterogeneous concentrations in an aquifer by increasing the sampled volume. Long-time pumping (several days) and simultaneous sampling yields reliable average concentrations Cav and mass flow rates Mcp for virtual control planes perpendicular to the natural flow direction. We applied the IPT method in order to estimate Mex of a stream section in Leipzig (Germany). The investigated stream is strongly influenced by combined sewer overflow events. Four pumping wells were installed up- and downstream of the stream section and operated for a period of five days. The study was focused on four inorganic (potassium, chloride, nitrate and sulfate) and two organic (caffeine and technical-nonylphenol) wastewater constituents with different transport properties. The obtained concentration-time series were used in combination with a numerical flow model to estimate Mcp of the respective wells. The difference of the Mcp's between up- and downstream wells yields Mex of wastewater constituents that increase

  11. Groundwater quality in the Upper Hudson River Basin, New York, 2012

    USGS Publications Warehouse

    Scott, Tia-Marie; Nystrom, Elizabeth A.

    2014-01-01

    Water samples were collected from 20 production and domestic wells in the Upper Hudson River Basin (north of the Federal Dam at Troy, New York) in New York in August 2012 to characterize groundwater quality in the basin. The samples were collected and processed using standard U.S. Geological Survey procedures and were analyzed for 148 physiochemical properties and constituents, including dissolved gases, major ions, nutrients, trace elements, pesticides, volatile organic compounds (VOCs), radionuclides, and indicator bacteria. The Upper Hudson River Basin covers 4,600 square miles in upstate New York, Vermont, and Massachusetts; the study area encompasses the 4,000 square miles that lie within New York. The basin is underlain by crystalline and sedimentary bedrock, including gneiss, shale, and slate; some sandstone and carbonate rocks are present locally. The bedrock in some areas is overlain by surficial deposits of saturated sand and gravel. Eleven of the wells sampled in the Upper Hudson River Basin are completed in sand and gravel deposits, and nine are completed in bedrock. Groundwater in the Upper Hudson River Basin was typically neutral or slightly basic; the water typically was moderately hard. Bicarbonate, chloride, calcium, and sodium were the major ions with the greatest median concentrations; the dominant nutrient was nitrate. Methane was detected in 7 samples. Strontium, iron, barium, boron, and manganese were the trace elements with the highest median concentrations. Two pesticides, an herbicide degradate and an insecticide degredate, were detected in two samples at trace levels; seven VOCs, including chloroform, four solvents, and the gasoline additive methyl tert-butyl ether (MTBE) were detected in four samples. The greatest radon-222 activity, 2,900 picocuries per liter, was measured in a sample from a bedrock well; the median radon activity was higher in samples from bedrock wells than in samples from sand and gravel wells. Coliform bacteria were

  12. Anthropogenic Influence On Groundwater Quality In Jericho and And Adjoining Wadis (Lower Jordan Valley, Palestine)

    NASA Astrophysics Data System (ADS)

    Geyer, S.; Khayat, S.; Roediger, T.; Siebert, C.

    2008-12-01

    vegetable gardening hold the danger to pollute the groundwater via irrigation return flow. This return flow most probably endangers the quality of the water resource, because shallow wells nearby extract it directly from the underground. However, one result of the first screening campaign concerning pesticide remnants in the groundwater wells of Jericho, just traces have been detected. Thus, the higher amount of chemicals is retained by the soil during infiltration of irrigated water. The detected low concentrations in groundwater of the fan may be the result of outleaching from agricultural areas from the mountain range. The flood water of Wadi Qilt infiltrates partly in the fluviatil sediments. The ongoing investigations in the Wadi Qilt-Jericho area include an approach of combined hydrochemical and hydraulic studies to simulate the complex groundwater system at the edge of the graben and to prepare a sustainable groundwater management strategy for the area of Jericho.

  13. Effects of land use on groundwater quality in the East Everglades, Dade County, Florida

    SciTech Connect

    Waller, B.G.

    1983-01-01

    Groundwater quality characteristics of the Biscayne aquifer from September 1978 through June 1979 were determined for seven land use areas within the East Everglades in Dade County, Florida. Four agricultural areas, two low-density residential areas, and Chekika Hammock State Park were investigated. The effects of land use on the groundwater were minimal in all areas; only iron, which occurs naturally in high concentrations in the Everglades, exceeded potable groundwater standards. Potassium and nitrate concentrations in certain samples increase over background concentrations in the agricultural areas. Groundwater at Chekika Hammock State Park and at a citrus grove is contaminated by brackish water flowing from an artesian well. The soil at the agricultural areas had higher concentrations of chromium, copper, and manganese than at the two residential areas or at Chekika Hammock State Park. One residential area (Coopertown) had the highest concentrations of lead and zinc and detectable polychlorinated biphenyls. Chlorinated-hydrocarbon insecticide residues in soil at three agricultural areas were higher than background concentrations. 15 refs., 15 figs., 35 tabs.

  14. Application of integral pumping tests to investigate the influence of a losing stream on groundwater quality

    NASA Astrophysics Data System (ADS)

    Leschik, S.; Musolff, A.; Krieg, R.; Martienssen, M.; Bayer-Raich, M.; Reinstorf, F.; Strauch, G.; Schirmer, M.

    2009-06-01

    Losing streams that are influenced by wastewater treatment plant effluents and combined sewer overflows (CSO's) can be a source of groundwater contamination. Released micropollutants such as pharmaceuticals, endocrine disrupters and other ecotoxicologically relevant substances as well as inorganic wastewater constituents can reach the groundwater, where they may deteriorate groundwater quality. This paper presents a method to quantify exfiltration mass flow rates Mex of wastewater constituents from losing streams by the operation of integral pumping tests (IPT's) up- and downstream of a target section. Due to the large sampled water volume during IPT's the results are more reliable than those from conventional point sampling. We applied the method at a test site in Leipzig (Germany). Wastewater constituents K+ and NO3- showed Mex values of 1241 to 4315 and 749 to 924 mg m-1stream d-1, respectively, while Cl- (16.8 to 47.3 g m-1stream d-1) and SO42- (20.3 to 32.2 g m-1stream d-1) revealed the highest observed Mex values at the test site. The micropollutants caffeine and technical-nonylphenol were dominated by elimination processes in the groundwater between upstream and downstream wells. Additional concentration measurements in the stream and a connected sewer at the test site were performed to identify relevant processes that influence the concentrations at the IPT wells.

  15. Application of integral pumping tests to investigate the influence of a losing stream on groundwater quality

    NASA Astrophysics Data System (ADS)

    Leschik, S.; Musolff, A.; Krieg, R.; Martienssen, M.; Bayer-Raich, M.; Reinstorf, F.; Strauch, G.; Schirmer, M.

    2009-10-01

    Losing streams that are influenced by wastewater treatment plant effluents and combined sewer overflows (CSOs) can be a source of groundwater contamination. Released micropollutants such as pharmaceuticals, endocrine disrupters and other ecotoxicologically relevant substances as well as inorganic wastewater constituents can reach the groundwater, where they may deteriorate groundwater quality. This paper presents a method to quantify exfiltration mass flow rates per stream length unit Mex of wastewater constituents from losing streams by the operation of integral pumping tests (IPTs) up- and downstream of a target section. Due to the large sampled water volume during IPTs the results are more reliable than those from conventional point sampling. We applied the method at a test site in Leipzig (Germany). Wastewater constituents K+ and NO3- showed Mex values of 1241 to 4315 and 749 to 924 mg mstream-1 d-1, respectively, while Cl- (16.8 to 47.3 g mstream-1 d-1) and SO42- (20.3 to 32.2 g mstream-1 d-1) revealed the highest observed Mex values at the test site. The micropollutants caffeine and technical-nonylphenol were dominated by elimination processes in the groundwater between upstream and downstream wells. Additional concentration measurements in the stream and a connected sewer at the test site were performed to identify relevant processes that influence the concentrations at the IPT wells.

  16. Visions for a Pan-European digital data infrastructure for groundwater quantity and quality data relevant for implementation of the Water Framework Directive.

    NASA Astrophysics Data System (ADS)

    Hinsby, Klaus; Broers, Hans Peter

    2014-05-01

    The EU Water Framework and Groundwater Directives stipulate that EU member states (MS) should ensure good groundwater chemical and quantitative by 2015. For the assessment of good chemical status the MS have to establish Natural Background Levels (NBLs) and Threshold Values (TVs) for groundwater bodies at risk and compare current concentration levels to these. In addition the MS shall ensure trend reversals in cases where contaminants or water levels show critical increasing or decreasing trends. The EU MS have to demonstrate that the quantitative and chemical status of its groundwater bodies does not put drinking water, ecosystems or other legitimate uses at risk. Easy on-line access to relevant visualizations of groundwater quality and quantity data of e.g. nitrate, chloride, arsenic and water tables in Europe's major aquifer types compiled from national databases would be of great importance for managers, authorities and scientists conducting risk and status assessments. The Water Resources Expert Group of the EuroGeoSurveys propose to develop Pan-European interactive on-line digital maps and visualizations of concentrations levels and trends, as well as calculated natural background levels and threshold values for the most important aquifer types of Europe mainly derived based on principles established in the former EU project "BRIDGE" - Background cRiteria for the IDentification of Groundwater Thresholds. Further, we propose to develop Pan-European digital and dynamic maps and cross sections in close collaboration with ecologists, which delineate dependent or associated terrestrial and aquatic ecosystems across Europe where groundwater quantity and quality plays a significant role in sustaining good ecological status of the ecosystem, and where the water resources and ecosystems are most vulnerable to climate change. Finally, integrated water resources management requires integrated consideration of both deep and shallow groundwater and surface water issues

  17. Compilation of well and ground-water quality data, Groveland-Collins and surrounding areas near Blackfoot, Bingham County, Idaho

    USGS Publications Warehouse

    Parliman, D.J.

    1986-01-01

    Well-construction, geologic, and water level data from 1978 to 1985 were compiled for 163 sites near Blackfoot, Idaho. Groundwater quality data were compiled for 51 sites for the period 1961-83 and for 54 sites for the period 1984-85. Data were collected in support of the hydrologic and water quality components of the U.S. Geological Survey 's groundwater contamination investigation near Blackfoot. Result of the investigation are presented in an interpretive report, published separately.

  18. Ground-water quality and data on wells and springs in Pennsylvania: Volume II, Susquehanna and Potomac River basins

    USGS Publications Warehouse

    Koester, Harry E.; Miller, Denise R.

    1980-01-01

    Volume II of the Ground-Water Quality and Data on Wells and Springs in Pennsylvania presents ground-water quality and physical data on about 1,400 wells and springs in the Susquehanna and Potomac River basins in Pennsylvania. Locations are shown on site-location maps derived from the hydrologic unit map. Codes showing the geologic age and aquifer are provided. (USGS)

  19. Quality Profiles in Early Childhood: An Example from Virginia's Quality Rating Improvement System

    ERIC Educational Resources Information Center

    Squibb, Kathryn M.

    2013-01-01

    Quality in early childhood settings has emerged as an important factor in determining whether the potential benefits of educational experiences before kindergarten will be realized. Research demonstrates that in order for such interventions to be beneficial to young children's development, the quality of their educational environments and…

  20. 48 CFR 22.1003-5 - Some examples of contracts covered.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... CFR 4.130 for additional examples): (a) Motor pool operation, parking, taxicab, and ambulance services..., stenographic reporting, or mortuary services. (j) Electronic equipment maintenance and operation and..., engines, electrical motors, vehicles, and electronic, office and related business and...

  1. 48 CFR 22.1003-5 - Some examples of contracts covered.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... CFR 4.130 for additional examples): (a) Motor pool operation, parking, taxicab, and ambulance services..., stenographic reporting, or mortuary services. (j) Electronic equipment maintenance and operation and..., engines, electrical motors, vehicles, and electronic, office and related business and...

  2. Evaluation of groundwater quality and its suitability for drinking and agricultural use in Thanjavur city, Tamil Nadu, India.

    PubMed

    Nagarajan, R; Rajmohan, N; Mahendran, U; Senthamilkumar, S

    2010-12-01

    As groundwater is a vital source of water for domestic and agricultural activities in Thanjavur city due to lack of surface water resources, groundwater quality and its suitability for drinking and agricultural usage were evaluated. In this study, 102 groundwater samples were collected from dug wells and bore wells during March 2008 and analyzed for pH, electrical conductivity, temperature, major ions, and nitrate. Results suggest that, in 90% of groundwater samples, sodium and chloride are predominant cation and anion, respectively, and NaCl and CaMgCl are major water types in the study area. The groundwater quality in the study site is impaired by surface contamination sources, mineral dissolution, ion exchange, and evaporation. Nitrate, chloride, and sulfate concentrations strongly express the impact of surface contamination sources such as agricultural and domestic activities, on groundwater quality, and 13% of samples have elevated nitrate content (>45 mg/l as NO(3)). PHREEQC code and Gibbs plots were employed to evaluate the contribution of mineral dissolution and suggest that mineral dissolution, especially carbonate minerals, regulates water chemistry. Groundwater suitability for drinking usage was evaluated by the World Health Organization and Indian standards and suggests that 34% of samples are not suitable for drinking. Integrated groundwater suitability map for drinking purposes was created using drinking water standards based on a concept that if the groundwater sample exceeds any one of the standards, it is not suitable for drinking. This map illustrates that wells in zones 1, 2, 3, and 4 are not fit for drinking purpose. Likewise, irrigational suitability of groundwater in the study region was evaluated, and results suggest that 20% samples are not fit for irrigation. Groundwater suitability map for irrigation was also produced based on salinity and sodium hazards and denotes that wells mostly situated in zones 2 and 3 are not suitable for

  3. Status of groundwater quality in the Upper Santa Ana Watershed, November 2006--March 2007--California GAMA Priority Basin Project

    USGS Publications Warehouse

    Kent, Robert; Belitz, Kenneth

    2012-01-01

    Groundwater quality in the approximately 1,000-square-mile (2,590-square-kilometer) Upper Santa Ana Watershed (USAW) study unit was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is located in southern California in Riverside and San Bernardino Counties. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The GAMA USAW study was designed to provide a spatially unbiased assessment of untreated groundwater quality within the primary aquifer systems in the study unit. The primary aquifer systems (hereinafter, primary aquifers) are defined as the perforation interval of wells listed in the California Department of Public Health (CDPH) database for the USAW study unit. The quality of groundwater in shallower or deeper water-bearing zones may differ from that in the primary aquifers; shallower groundwater may be more vulnerable to surficial contamination. The assessment is based on water-quality and ancillary data collected by the U.S. Geological Survey (USGS) from 90 wells during November 2006 through March 2007, and water-quality data from the CDPH database. The status of the current quality of the groundwater resource was assessed based on data from samples analyzed for volatile organic compounds (VOCs), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. The status assessment is intended to characterize the quality of groundwater resources within the primary aquifers of the USAW study unit, not the treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentration divided by the health- or aesthetic-based benchmark concentration) were used for evaluating groundwater quality for those constituents that have Federal or California regulatory or

  4. Application of a new vertical profiling tool (ESASS) for sampling groundwater quality during hollow-stem auger drilling

    USGS Publications Warehouse

    Harte, Philip T.; Flanagan, Sarah M.

    2011-01-01

    A new tool called ESASS (Enhanced Screen Auger Sampling System) was developed by the U.S. Geological Survey. The use of ESASS, because of its unique U.S. patent design (U.S. patent no. 7,631,705 B1), allows for the collection of representative, depth-specific groundwater samples (vertical profiling) in a quick and efficient manner using a 0.305-m long screen auger during hollow-stem auger drilling. With ESASS, the water column in the flights above the screen auger is separated from the water in the screen auger by a specially designed removable plug and collar. The tool fits inside an auger of standard inner diameter (82.55 mm). The novel design of the system constituted by the plug, collar, and A-rod allows the plug to be retrieved using conventional drilling A-rods. After retrieval, standard-diameter (50.8 mm) observation wells can be installed within the hollow-stem augers. Testing of ESASS was conducted at one waste-disposal site with tetrachloroethylene (PCE) contamination and at two reference sites with no known waste-disposal history. All three sites have similar geology and are underlain by glacial, stratified-drift deposits. For the applications tested, ESASS proved to be a useful tool in vertical profiling of groundwater quality. At the waste site, PCE concentrations measured with ESASS profiling at several depths were comparable (relative percent difference <25%) to PCE concentrations sampled from wells. Vertical profiling with ESASS at the reference sites illustrated the vertical resolution achievable in the profile system; shallow groundwater quality varied by a factor of five in concentration of some constituents (nitrate and nitrite) over short (0.61 m) distances.

  5. Application of a new vertical profiling tool (ESASS) for sampling groundwater quality during hollow-stem auger drilling

    USGS Publications Warehouse

    Harte, P.T.; Flanagan, S.M.

    2011-01-01

    A new tool called ESASS (Enhanced Screen Auger Sampling System) was developed by the U.S. Geological Survey. The use of ESASS, because of its unique U.S. patent design (U.S. patent no. 7,631,705 B1), allows for the collection of representative, depth-specific groundwater samples (vertical profiling) in a quick and efficient manner using a 0.305-m long screen auger during hollow-stem auger drilling. With ESASS, the water column in the flights above the screen auger is separated from the water in the screen auger by a specially designed removable plug and collar. The tool fits inside an auger of standard inner diameter (82.55 mm). The novel design of the system constituted by the plug, collar, and A-rod allows the plug to be retrieved using conventional drilling A-rods. After retrieval, standard-diameter (50.8 mm) observation wells can be installed within the hollow-stem augers. Testing of ESASS was conducted at one waste-disposal site with tetrachloroethylene (PCE) contamination and at two reference sites with no known waste-disposal history. All three sites have similar geology and are underlain by glacial, stratified-drift deposits. For the applications tested, ESASS proved to be a useful tool in vertical profiling of groundwater quality. At the waste site, PCE concentrations measured with ESASS profiling at several depths were comparable (relative percent difference <25%) to PCE concentrations sampled from wells. Vertical profiling with ESASS at the reference sites illustrated the vertical resolution achievable in the profile system; shallow groundwater quality varied by a factor of five in concentration of some constituents (nitrate and nitrite) over short (0.61 m) distances. Ground Water Monitoring & Remediation ?? 2011, National Ground Water Association. No claim to original US government works.

  6. Raft River monitor well potentiometric head responses and water quality as related to the conceptual ground-water flow system

    SciTech Connect

    Allman, D.W.; Tullis, J.A.; Dolenc, M.R.; Thurow, T.L.; Skiba, P.A.

    1982-09-01

    Ground-water monitoring near the Raft River site was initiated in 1974 by the IDWR. This effort consisted of semiannual chemical sampling of 22 irrigation wells near the Raft River geothermal development area. This program yielded useful baseline chemical data; however, several problems were inherent. For example, access to water pumped from the wells is limited to the irrigation season (April through September). All the wells are not continuously pumped; thus, some wells that are sampled one season cannot be sampled the next. In addition, information on well construction, completion, and production is often unreliable or not available. These data are to be supplemented by establishing a series of monitor wells in the proposed geothermal withdrawal and injection area. These wells were to be located and designed to provide data necessary for evaluating and predicting the impact of geothermal development on the Shallow Aquifer system.

  7. A quality-assurance plan for district ground-water activities of the U.S. Geological Survey

    USGS Publications Warehouse

    Brunett, J.O.; Barber, N.L.; Burns, A.W.; Fogelman, R.P.; Gillies, D.C.; Lidwin, R.A.; Mack, Thomas J.

    1997-01-01

    As the Nation's principal earth-science information agency, the U.S. Geological Survey (USGS) is depended upon to collect data of the highest quality. This document provides the framework for collecting, analyzing and reporting ground-water data that are quality assured and quality controlled.

  8. Wastewater application by spray irrigation on a field southeast of Tallahassee, Florida; effects on ground-water quality and quantity, 1980-82

    USGS Publications Warehouse

    Elder, J.F.; Hunn, J.D.; Calhoun, C.W.

    1985-01-01

    A field southeast of Tallahassee, Florida, used for land application of wastewater by spray irrigation was the site of a ground-water monitoring study to determine effects of spray irrigation on water-table elevations and ground-water quality. The study was conducted during 1980-82 in cooperation with the City of Tallahassee. The wastewater has relatively high concentrations of chloride, nitrogen, phosphorus, organic carbon , coliform bacteria, sodium, and potassium. These substances are usually attenuated before they can impact the ground water. However, increases in chloride and nitrate-nitrogen were evident in ground water in some of the monitoring wells during the study. Chloride concentrations increased five-fold or more in some wells directly affected by spray irrigation, and nitrate-nitrogen concentrations increased eight-fold or more. Ground-water levels in the area of the spray field fluctuated over a range of several feet. These fluctuations were affected somewhat by spray irrigation, but the primary control on water levels was rainfall. As of December 1982, constituents introduced to the system by spray irrigation of effluent had not exceeded drinking water standard in the ground water. However, the system had not yet stabilized and more changes in ground-water quality could be expected. (USGS)

  9. Achieving Acceptable Air Quality: Some Reflections on Controlling Vehicle Emissions

    NASA Astrophysics Data System (ADS)

    Calvert, J. G.; Heywood, J. B.; Sawyer, R. F.; Seinfeld, J. H.

    1993-07-01

    Motor vehicle emissions have been and are being controlled in an effort to abate urban air pollution. This article addresses the question: Will the vehicle exhaust emission control and fuel requirements in the 1990 Clean Air Act Amendments and the California Air Resources Board regulations on vehicles and fuels have a significant impact? The effective control of in-use vehicle emissions is the key to a solution to the motor vehicle part of the urban air pollution problem for the next decade or so. It is not necessary, except perhaps in Southern California, to implement extremely low new car emission standards before the end of the 20th century. Some of the proposed gasoline volatility and composition changes in reformulated gasoline will produce significant reductions in vehicle emissions (for example, reduced vapor pressure, sulfur, and light olefin and improved high end volatility), whereas others (such as substantial oxygenate addition and aromatics reduction) will not.

  10. Monitoring-well network and sampling design for ground-water quality, Wind River Indian Reservation, Wyoming

    USGS Publications Warehouse

    Mason, Jon P.; Sebree, Sonja K.; Quinn, Thomas L.

    2005-01-01

    The Wind River Indian Reservation, located in parts of Fremont and Hot Springs Counties, Wyoming, has a total land area of more than 3,500 square miles. Ground water on the Wind River Indian Reservation is a valuable resource for Shoshone and Northern Arapahoe tribal members and others who live on the Reservation. There are many types of land uses on the Reservation that have the potential to affect the quality of ground-water resources. Urban areas, rural housing developments, agricultural lands, landfills, oil and natural gas fields, mining, and pipeline utility corridors all have the potential to affect ground-water quality. A cooperative study was developed between the U.S. Geological Survey and the Wind River Environmental Quality Commission to identify areas of the Reservation that have the highest potential for ground-water contamination and develop a comprehensive plan to monitor these areas. An arithmetic overlay model for the Wind River Indian Reservation was created using seven geographic information system data layers representing factors with varying potential to affect ground-water quality. The data layers used were: the National Land Cover Dataset, water well density, aquifer sensitivity, oil and natural gas fields and petroleum pipelines, sites with potential contaminant sources, sites that are known to have ground-water contamination, and National Pollutant Discharge Elimination System sites. A prioritization map for monitoring ground-water quality on the Reservation was created using the model. The prioritization map ranks the priority for monitoring ground-water quality in different areas of the Reservation as low, medium, or high. To help minimize bias in selecting sites for a monitoring well network, an automated stratified random site-selection approach was used to select 30 sites for ground-water quality monitoring within the high priority areas. In addition, the study also provided a sampling design for constituents to be monitored, sampling

  11. Calendar year 1993 groundwater quality report for the Upper East Fork Poplar Creek Hydrogeologic Regime, Y-12 Plant, Oak Ridge, Tennessee. 1993 groundwater quality data and calculated rate of contaminant migration, Part 1

    SciTech Connect

    Not Available

    1994-02-01

    This report contains groundwater quality data obtained during the 1993 calendar year (CY) at several waste management facilities and petroleum fuel underground storage tank (UST) sites associated with the US Department of Energy (DOE) Y-12 Plant located on the DOE Oak Ridge Reservation (ORR) southeast of Oak Ridge, Tennessee. These sites are within the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), which is one of three regimes defined for the purposes of groundwater and surface-water quality monitoring at the Y-12 Plant. The Environmental Management Department of the Y-12 Plant Health, Safety, Environment, and Accountability Organization manages the groundwater monitoring activities in each regime as part of the Y-12 Plant Groundwater Protection Program (GWPP). The annual groundwater report for the East Fork Regime is completed in two-parts; Part 1 (this report) containing the groundwater quality data and Part 2 containing a detailed evaluation of the data. The primary purpose of this report is to serve as a reference for the groundwater data obtained each year under the lead of the Y-12 Plant GWPP. However, because it contains information needed to comply with the Resource Conservation and Recovery Act (RCRA) interim status assessment monitoring reporting requirements, this report is submitted to the Tennessee Department of Health and Environment (TDEC) by the RCRA reporting deadline.

  12. Suitability assessment of groundwater for drinking, irrigation and industrial use in some North Indian villages.

    PubMed

    Haritash, A K; Kaushik, C P; Kaushik, A; Kansal, Ankur; Yadav, Asheesh Kumar

    2008-10-01

    The study comprised suitability assessment of groundwater for drinking, irrigation, and industrial use. A total of 34 groundwater samples were collected from Rewari town and its perimeter from the land chiefly used for agriculture. Physico-chemical characterization of the samples revealed that groundwater from most of the sources was not fit for drinking owing to a high concentration of calcium, magnesium, hardness and fluoride. Suitability for irrigation, too, was low since most of the sources had high value of sodium adsorption ratio (SAR), residual sodium carbonate (RSC), soluble sodium percentage (SSP) and magnesium hazard which can render salinity and alkali hazard to soils on long term use in irrigation. No source of water was found to be suitable for industrial application since it had high concentration of calcium carbonate which can precipitate very easily. It was observed that sodium, sulphate, and chloride were the chief ions present in water and based on the abundance of ions and their correlation type, most of the groundwater samples are of sodium sulphate and/or sodium chloride type. The high concentration of the chemical constituents is attributed to the lithologic composition of the area. It was observed that the water of deep meteoric percolation type was of sodium sulphate type and the shallow of sodium chloride type. PMID:18202899

  13. Ground-water conditions and quality in the western part of Kenai Peninsula, southcentral Alaska

    USGS Publications Warehouse

    Glass, R.L.

    1996-01-01

    The western part of Kenai Peninsula in southcentral Alaska is bounded by Cook Inlet and the Kenai Mountains. Ground water is the predominant source of water for commercial, industrial, and domestic uses on the peninsula. Mean daily water use in an oil, gas, and chemical processing area north of Kenai is more than 3.5 million gallons. Unconsolidated sediments of glacial and fluvial origin are the most productive aquifers. In the upper (northwestern) peninsula, almost all water used is withdrawn from unconsolidated sediments, which may be as thick as 750 feet. In the lower peninsula, unconsolidated sediments are thinner and are absent on many hills. Water supplies in the lower peninsula are obtained from unconsolidated sediments and bedrock, and a public-water supply in parts of Homer is obtained from Bridge Creek. Throughout the peninsula, ground-water flow occurs primarily as localized flow controlled by permeability of aquifer materials and surface topography. The concentration of constituents analyzed in water from 312 wells indicated that the chemical quality of ground water for human consumption varies from marginal to excellent. Even though the median concentration of dissolved solids is low (152 milligrams per liter), much of the ground water on the peninsula does not meet water-quality regulations for public drinking water established by the U.S. Environmental Protection Agency (USEPA). About 8 percent of wells sampled yielded water having concentrations of dissolved arsenic that exceeded the USEPA primary maximum contaminant level of 50 micrograms per liter. Concentrations of dissolved arsenic were as great as 94 micrograms per liter. Forty-six percent of wells sampled yielded water having concentrations of dissolved iron greater than the USEPA secondary maximum contaminant level of 300 micrograms per liter. Unconsolidated sediments generally yield water having calcium, magnesium, and bicarbonate as its predominant ions. In some areas, ground water at

  14. Assessment of the Microbiological Quality of Groundwater in Three Regions of the Valencian Community (Spain)

    PubMed Central

    Llopis-González, Agustín; Sánchez, Adriana L.; Requena, Pedro Martí; Suárez-Varela, María Morales

    2014-01-01

    Urban groundwater development was traditionally constrained by concerns about its quality. This study was conducted in the regions of La Ribera Alta and Ribera Baja and La Plana de Requena-Utiel of the Valencian Community (Valencia, Spain) where population density, demand for drinking water and agricultural activities are high. Groundwater bodies (GWBs) are regarded as management areas within each territory, and were used to establish protection policies. This study analyzed eleven GWBs. We used two databases with microbiological measurements from 154 wells over a 7-year period (2004–2011), risk factors and groundwater information. Wells were grouped according to frequency of microbiological contamination using E. coli measurements, category <1, or wells with low-frequency microbiological contamination and high-frequency wells or category 1–100, according to World Health Organization (WHO) quality criteria of drinking water. Of all wells, 18.12% showed high-frequency microbiological contamination with a majority distribution in the Ribera Alta region (26.98%, p < 0.001). No significant differences were found between the two risk categories for flow, static level, well depth and distance from population centres. This paper reveals that the vulnerability classes established by the Geological and Mining Institute of Spain (IGME) do not match the microbiological results, and that only eight wells with high-frequency contamination coincide with the high vulnerability areas. PMID:24859678

  15. Ground-Water Quality in the St. Lawrence River Basin, New York, 2005-06

    USGS Publications Warehouse

    Nystrom, Elizabeth A.

    2007-01-01

    The Federal Clean Water Act requires that States monitor and report on the quality of ground water and surface water. To satisfy part of these requirements, the U.S. Geological Survey and New York State Department of Environmental Conservation have developed a program in which ground-water quality is assessed in 2 to 3 of New York State's 14 major river basins each year. To characterize the quality of ground water in the St. Lawrence River Basin in northern New York, water samples were collected from 14 domestic and 11 production wells between August 2005 and January 2006. Eight of the wells were finished in sand and gravel and 17 wells were finished in bedrock. Ground-water samples were collected and processed using standard U.S. Geological Survey procedures and were analyzed for 229 constituents and physical properties, including inorganic constituents, nutrients, trace elements, radon-222, pesticides and pesticide degradates, volatile organic compounds, and bacteria. Sixty-six constituents were detected above laboratory reporting levels. Concentrations of most compounds at most sites were within drinking water standards established by the U.S. Environmental Protection Agency and New York State Department of Health, but a few compounds exceeded drinking water standards at some sites. Water in the basin is generally hard to very hard (hardness equal to 121 mg/L as CaCO3 or greater); hardness and alkalinity were generally higher in the St. Lawrence Valley than in the Adirondack Mountains. The cation with the highest median concentration was calcium; the anion with the highest median concentration was bicarbonate. The concentration of chloride in one sample exceeded the 250 milligrams per liter U.S. Environmental Protection Agency Secondary Drinking Water Standard; the concentration of sulfate in one sample also exceeded the 250 milligrams per liter U.S. Environmental Protection Agency Secondary Drinking Water Standard. Nitrate was the predominant nutrient detected

  16. Hydrogeology, simulated ground-water flow, and ground-water quality, Wright-Patterson Air Force Base, Ohio

    USGS Publications Warehouse

    Dumouchelle, D.H.; Schalk, C.W.; Rowe, G.L.; De Roche, J.T.

    1993-01-01

    percent of the total ground-water flow in the study area. Ground waters in the vicinity of Wright-Patterson Air Force Base can be classified into two compositional groups on the basis of their chemical composition: calcium magnesium bicarbonate-type and sodium chloride-type waters. Calcium magnesium bicarbonate-type waters are found in the glacial deposits and the Brassfield Limestone, whereas the sodium chloride waters are exclusively associated with the shales. Equilibrium speciation calculations indicate that ground water of the glacial drift aquifer is in equilibrium with calcite, dolomite, and chalcedony, but is undersaturated with respect to gypsum and fluorite. Waters from the shales are slightly supersaturated with respect to calcite, dolomite, and siderite but are undersaturated with respect to chalcedony. Simple-mass balance calculations treating boron as a conservative species indicate that little (< 5 percent) or no recharge from the shales to the glacial drift aquifer takes place. Data on the stable isotopes of oxygen and hydrogen indicate a meteoric origin for all ground water beneath Wright-Patterson Air Force Base, but the data were inconclusive with respect to identification of distinct isotopic differences between water collected from the glacial drift and bedrock aquifers. Tritium concentrations used to distinguish waters having a pre-and post-1953 recharge component indicate that most water entered the glacial drift aquifer after 1953. This finding indicates that recharge from shallow to deep parts (greater than 150 feet) of the aquifer takes place over time intervals of a few years or decades. However, the fact that some deep parts of the glacial aquifer did not contain measurable tritium indicates that ground-water flow from recharge zones to these parts of the aquifer takes decades or longer.

  17. Groundwater quality in the Lower Hudson River Basin, New York, 2008

    USGS Publications Warehouse

    Nystrom, Elizabeth A.

    2010-01-01

    Water samples were collected from 32 production and domestic wells in the study area from August through November 2008 to characterize the groundwater quality. The study area, which covers 5,607 square miles, encompasses the part of the Lower Hudson River Basin that lies within New York plus the parts of the Housatonic, Hackensack, Bronx, and Saugatuck River Basins that are in New York. The study area is underlain by mainly clastic bedrock, predominantly shale, with carbonate and crystalline rock present locally. The bedrock is generally overlain by till, but surficial deposits of saturated sand and gravel are present in some areas. Of the 32 wells sampled, 16 were finished in sand and gravel deposits and 16 were finished in bedrock. The samples were collected and processed by standard U.S. Geological Survey procedures and were analyzed for 225 physiochemical properties and constituents, including major ions, nutrients, trace elements, radon-222, pesticides, and volatile organic compounds (VOCs); indicator bacteria were collected and analyzed by New York State Department of Health procedures. Water quality in the study area is generally good, but concentrations of some constituents exceeded current or proposed Federal or New York State primary or secondary drinking-water standards; the standards exceeded were color (2 samples), pH (6 samples), sodium (8 samples), fluoride (1 sample), aluminum (3 samples), arsenic (1 sample), iron (7 samples), manganese (14 samples), radon-222 (17 samples), tetrachloroethene (1 sample), and bacteria (7 samples). The pH of all samples was typically neutral or slightly basic (median 7.2); the median water temperature was 11.8 degrees C. The ions with the highest concentrations were bicarbonate [median 167 milligrams per liter (mg/L)] and calcium (median 38.2 mg/L). Groundwater in the study area ranged from very soft to very hard, but more samples were classified as very hard (181 mg/L as CaCO3 or more) than soft (60 mg/L as CaCO3 or

  18. Groundwater Quality Assessment by Using Hydrogeochemical Methods in the National Capital Territory -Delhi, India

    NASA Astrophysics Data System (ADS)

    Kumar, M.; Ramanathan, A.

    2006-05-01

    Present study has been carried out to assess the real status of groundwater, second major water resource for the drinking water supply in the National Capital Territory (NCT) of India, Delhi. Salinity and nitrate contamination are the two major problems in the area which is alarming for drinking purpose. Various graphical plots and statistical analysis has been carried out to understand the geochemical processes and its relation to the groundwater quality based on the ionic constituents, water types, hydrochemical facies and to understand nutrient chemistry (nitrate, phosphate and potassium) with spatial and seasonal variations in the groundwater nature in the study area. The concentration of nutrients in groundwater acts as an indicator to identify the nature and influence of agricultural and urban runoff on the shallow subsurface environment. Results of the study suggests that leaching from the various unlined landfill sites is the prime cause of nitrate contamination along with other factors like agricultural activities, soil mineralization processes and irrigation return flow. The result also indicates a different source of origin for the nitrate and potassium and not a common source for their origin as it was thought earlier. Local recharge is associated with low salinity of Ca- Mg-HCO3 type which is through rainfall and surface water body especially by west Yamuna canal and Yamuna River. Large lateral variation of conservative elements shows that recharge through lateral flow is not dominant in the area. Highly saline and brackish groundwater in the discharge zones like northwestern and southwestern parts of the area seem to be associated with long history of evaporation and oxidation of sulfur gases in low lying areas. In view of increasing demand of drinking water in the area, present study is vital and suggests the need of immediate management action for landfill sites.

  19. Pit Latrines and Their Impacts on Groundwater Quality: A Systematic Review

    PubMed Central

    Polizzotto, Matthew L.

    2013-01-01

    Background: Pit latrines are one of the most common human excreta disposal systems in low-income countries, and their use is on the rise as countries aim to meet the sanitation-related target of the Millennium Development Goals. There is concern, however, that discharges of chemical and microbial contaminants from pit latrines to groundwater may negatively affect human health. Objectives: Our goals were to a) calculate global pit latrine coverage, b) systematically review empirical studies of the impacts of pit latrines on groundwater quality, c) evaluate latrine siting standards, and d) identify knowledge gaps regarding the potential for and consequences of groundwater contamination by latrines. Methods: We used existing survey and population data to calculate global pit latrine coverage. We reviewed the scientific literature on the occurrence of contaminants originating from pit latrines and considered the factors affecting transport of these contaminants. Data were extracted from peer-reviewed articles, books, and reports identified using Web of ScienceSM, PubMed, Google, and document reference lists. Discussion: We estimated that approximately 1.77 billion people use pit latrines as their primary means of sanitation. Studies of pit latrines and groundwater are limited and have generally focused on only a few indicator contaminants. Although groundwater contamination is frequently observed downstream of latrines, contaminant transport distances, recommendations based on empirical studies, and siting guidelines are variable and not well aligned with one another. Conclusions: In order to improve environmental and human health, future research should examine a larger set of contextual variables, improve measurement approaches, and develop better criteria for siting pit latrines. PMID:23518813

  20. Groundwater Quality Assessment Plan for Single-Shell Tank Waste Management Area U

    SciTech Connect

    Smith, Ronald M.; Hodges, Floyd N.; Williams, Barbara A.

    2001-08-29

    Single-Shell Tank Waste Management Area U (WMA U) is in the 200 West Area on the Hanford Site. The area includes the U Tank Farm that contains 16 underground, single-shell tanks and their ancillary equipment and waste systems. WMA U is regulated under the Resource Conservation and Recovery Act of 1976 (RCRA) as codified in 40 CFR Part 265, Subpart F and Washington's Hazardous Waste Management Act (HWMA, RCW 70.105) and its implementing requirements in the Washington State dangerous waste regulations (WAC 173-303-400). Releases of hazardous wastes from WMA U have contaminated groundwater beneath the area. Therefore, the WMA U is being assessed to determine the rate of movement and extent of the contamination released and to determine the concentrations in groundwater. The original finding of groundwater impact was determined from elevated specific conductance in downgradient well 299-W19-41. The elevated specific conductance was attributed to the nonhazardous constituents calcium, magnesium, sulfate, and chloride. Tank waste constituents nitrate and technetium-99 are also present as co-contaminants and have increased over the past several years; however, at concentrations well below the respective drinking water standards. Chromium concentrations in downgradient wells have generally exceeded background levels, but similar levels were also observed in upgradient well 299-W18-25 in early 2000 before it went dry. The objective of this report is to present the current conceptual model for how and where contaminant releases have reached the water table and how that contamination has dispersed in the groundwater system. These efforts will achieve the requirements of a groundwater quality assessment under RCRA [40 CFR 265.93 (d)(4)]. On that basis, a monitoring schedule with appropriate analytes and proposals for new wells and tests are presented in this document.

  1. Impact of stormwater infiltration basins on groundwater quality, Perth metropolitan region, Western Australia

    NASA Astrophysics Data System (ADS)

    Appleyard, S. J.

    1993-08-01

    Twelve bores were sunk adjacent to three stormwater infiltration basins in the Perth metropolitan area to examine the impact of runoff from a light industrial area, a medium-density residential area, and a major arterial road on groundwater quality, and to examine the hydrological response of the aquifer to runoff recharge. Automatic and manual water level monitoring between April and November 1990 indicated that groundwater levels responded within minutes to recharge from the infiltration basins. Peak water levels of up to 2.5 m above rest levels occurred 6 24 h after the commencement of ponding in the infiltration basins. There was a marked reduction in salinity and increase in dissolved oxygen concentrations in the upper part of the aquifer downgradient of the infiltration basins. Concentrations of toxic metals, nutrients, pesticides, and phenolic compounds in groundwater near the infiltration basins were low and generally well within Australian drinking water guidelines. However, sediment in the base of an infiltration basin draining a major road contained in excess of 3500 ppm of lead. Phthalates, which are US EPA priority pollutants, were detected in all but one bore near the infiltration basins. Their detection may be a sampling artifact, but they may also be derived from the plastic litter that accumulates in the infiltration basins. The concentration of iron in groundwater near the infiltration basins appears to be controlled by dissolved oxygen concentrations, with high iron concentrations occurring where dissolved oxygen concentrations are low. Pumping bores located near infiltration basins may suffer from iron encrustation problems caused by the mixing of shallow, oxygenated groundwater with water containing higher concentrations of iron from deeper in the aquifer.

  2. Groundwater quality assessment plan for single-shell waste management area B-BX-BY at the Hanford Site

    SciTech Connect

    SM Narbutovskih

    2000-03-31

    Pacific Northwest National Laboratory conducted a first determination groundwater quality assessment at the Hanford Site. This work was performed for the US Department of Energy, Richland Operations Office, in accordance with the Federal Facility Compliance Agreement during the time period 1996--1998. The purpose of the assessment was to determine if waste from the Single-Shell Tank (SST) Waste Management Area (WMA) B-BX-BY had entered the groundwater at levels above the drinking water standards (DWS). The resulting assessment report documented evidence demonstrating that waste from the WMA has, most likely, impacted groundwater quality. Based on 40 CFR 265.93 [d] paragraph (7), the owner-operator must continue to make the minimum required determinations of contaminant level and of rate/extent of migrations on a quarterly basis until final facility closure. These continued determinations are required because the groundwater quality assessment was implemented prior to final closure of the facility.

  3. Complex Controls on Groundwater Quality in Growing Mid-sized Cities: A Case Study Focused on Nitrate and Emerging Contaminants

    NASA Astrophysics Data System (ADS)

    Ohr, C. A.; Godsey, S.; Welhan, J. A.; Larson, D. M.; Lohse, K. A.; Finney, B.; Derryberry, D.

    2015-12-01

    Many regions rely on quality groundwater to support urban growth. Groundwater quality often responds in a complex manner to stressors such as land use change, climate change, or policy decisions. Urban growth patterns in mid-sized cities, especially ones that are growing urban centers in water-limited regions in the western US, control and are controlled by water availability and its quality. We present a case study from southeastern Idaho where urban growth over the past 20 years has included significant ex-urban expansion of houses that rely on septic systems rather than city sewer lines for their wastewater treatment. Septic systems are designed to mitigate some contaminants, but not others. In particular, nitrates and emerging contaminants, such as pharmaceuticals, are not removed by most septic systems. Thus, even well-maintained septic systems at sufficiently high densities can impact down gradient water quality. Here we present patterns of nitrate concentrations over the period from 1985-2015 from the Lower Portneuf River Valley in southeastern Idaho. Concentrations vary from 0.03 to 27.09 nitrate-nitrogen mg/L, with average values increasing significantly over the 30 year time period from 3.15 +/- 0.065 to 3.57 +/- 0.43 mg/L. We examine temporal changes in locations of nitrate hotspots, and present pilot data on emerging contaminants of concern. Initial results suggest that high nitrate levels are generally associated with higher septic densities, but that this pattern is influenced by legacy agricultural uses and strongly controlled by underlying aquifer properties. Future work will include more detailed hydrological modeling to predict changes in hotspot locations under potential climate change scenarios.

  4. Baseline groundwater quality from 34 wells in Wayne County, Pennsylvania, 2011 and 2013

    USGS Publications Warehouse

    Sloto, Ronald A.

    2014-01-01

    Wayne County, Pennsylvania, is underlain by the Marcellus Shale, which currently (2014) is being developed elsewhere in Pennsylvania for natural gas. All residents of largely rural Wayne County rely on groundwater for water supply, primarily from bedrock aquifers (shales and sandstones). This study, conducted by the U.S. Geological Survey in cooperation with the Pennsylvania Department of Conservation and Natural Resources, Bureau of Topographic and Geologic Survey (Pennsylvania Geological Survey), provides a groundwater-quality baseline for Wayne County prior to development of the natural gas resource in the Marcellus Shale. Selected wells completed in the Devonian-age Catskill Formation, undifferentiated; the Poplar Gap and Packerton Members of the Catskill Formation, undivided; and the Long Run and Walcksville Members of the Catskill Formation, undivided, were sampled. Water samples were collected once from 34 domestic wells during August 2011 and August and September 2013 and analyzed to characterize their physical and chemical quality. Samples were analyzed for 45 constituents and properties, including nutrients, major ions, metals and trace elements, radioactivity, and dissolved gases, including methane and radon-222. The quality of the sampled groundwater was generally within U.S. Environmental Protection Agency (USEPA) drinking-water standards, although in some samples, the concentrations of a few constituents exceeded USEPA drinking-water standards and health advisories. The pH of water samples ranged from 5.5 to 9.3 with a median of 7.0. The pH was outside the USEPA secondary maximum contaminant level (SMCL) range of 6.5 to 8.5 in water samples from 14 of the 34 wells (41 percent). Eleven samples had a pH less than 6.5, and three samples had a pH greater than 8.5. Dissolved oxygen concentrations ranged from 0.2 to 11.5 milligrams per liter (mg/L) with a median of 4.7 mg/L. The dissolved oxygen concentration was less than 1 mg/L in water samples from 6

  5. The role of wellbore remediation on the evolution of groundwater quality from CO₂ and brine leakage

    DOE PAGESBeta

    Mansoor, Kayyum; Carroll, Susan A.; Sun, Yunwei

    2014-12-31

    Long-term storage of CO₂ in underground reservoirs requires a careful assessment to evaluate risk to groundwater sources. The focus of this study is to assess time-frames required to restore water quality to pre-injection levels based on output from complex reactive transport simulations that exhibit plume retraction within a 200-year simulation period. We examined the relationship between plume volume, cumulative injected CO₂ mass, and permeability. The role of mitigation was assessed by projecting falloffs in plume volumes from their maximum peak levels with a Gaussian function to estimate plume recovery times to reach post-injection groundwater compositions. The results show a strongmore » correlation between cumulative injected CO₂ mass and maximum plume pH volumes and a positive correlation between CO₂ flux, cumulative injected CO₂, and plume recovery times, with secondary dependence on permeability.« less

  6. The role of wellbore remediation on the evolution of groundwater quality from CO₂ and brine leakage

    SciTech Connect

    Mansoor, Kayyum; Carroll, Susan A.; Sun, Yunwei

    2014-12-31

    Long-term storage of CO₂ in underground reservoirs requires a careful assessment to evaluate risk to groundwater sources. The focus of this study is to assess time-frames required to restore water quality to pre-injection levels based on output from complex reactive transport simulations that exhibit plume retraction within a 200-year simulation period. We examined the relationship between plume volume, cumulative injected CO₂ mass, and permeability. The role of mitigation was assessed by projecting falloffs in plume volumes from their maximum peak levels with a Gaussian function to estimate plume recovery times to reach post-injection groundwater compositions. The results show a strong correlation between cumulative injected CO₂ mass and maximum plume pH volumes and a positive correlation between CO₂ flux, cumulative injected CO₂, and plume recovery times, with secondary dependence on permeability.

  7. Sampling and analysis plan for the characterization of groundwater quality in two monitoring wells near Pavillion, Wyoming

    USGS Publications Warehouse

    Wright, Peter R.; McMahon, Peter B.

    2012-01-01

    In June 2010, the U.S. Environmental Protection Agency installed two deep monitoring wells (MW01 and MW02) near Pavillion, Wyoming to study groundwater quality. The U.S Geological Survey, in cooperation with the Wyoming Department of Environmental Quality, designed a plan to collect groundwater data from these monitoring wells. This sampling and analysis plan describes the sampling equipment that will be used, well purging strategy, purge water disposal, sample collection and processing, field and laboratory sample analysis, equipment decontamination, and quality-assurance and quality-control procedures.

  8. Relation of Chlorofluorocarbon Ground-Water Age Dates to Water Quality in Aquifers of West Virginia

    USGS Publications Warehouse

    McCoy; Kurt, J.; Kozar, Mark D.

    2007-01-01

    The average apparent age of ground water in fractured-bedrock aquifers in West Virginia was determined using chlorofluorocarbon (CFC) dating methods. Since the introduction of CFC gases as refrigerants in the late 1930s, atmospheric concentrations have increased until production ceased in the mid-1990s. CFC dating methods are based on production records that date to the early 1940s, and the preservation of atmospheric CFC concentrations in ground water at the time of recharge. As part of the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) and Ambient Ground-Water Monitoring Network (AGN) programs in West Virginia from 1997 to 2005, 80 samples from the Appalachian Plateaus Physiographic Province, 27 samples from the Valley and Ridge Physiographic Province, and 5 samples from the Ohio River alluvial aquifers were collected to estimate ground-water ages in aquifers of West Virginia. Apparent CFC ages of water samples from West Virginia aquifers ranged from 5.8 to 56 years. In the Appalachian Plateaus, topographically driven ground-water flow is evident from apparent ages of water samples from hilltop, hillside, and valley settings (median apparent ages of 12, 14, and 25 years, respectively). Topographic setting was the only factor that was found to be related to apparent ground-water age in the Plateaus at the scale of this study. Similar relations were not found in Valley and Ridge aquifers, indicating that other factors such as bedding or geologic structure may serve larger roles in controlling ground-water flow in that physiographic province. Degradation of CFCs was common in samples collected from methanogenic/anoxic aquifers in the Appalachian Plateaus and suboxic to anoxic aquifers in the Valley and Ridge. CFC contamination was most common in Ohio River alluvial aquifers and carbonate units of the Valley and Ridge, indicating that these highly transmissive surficial aquifers are the most vulnerable to water-quality degradation and may

  9. [Tracing the Fecal Contamination Sources Based on Bacteroides 16S rRNA PCR- DGGE in Karst Groundwater: Taking Laolongdong Underground River System, Nanshan, Chongqing as an Example].

    PubMed

    Zhang, Hong; Jiang, Yong-jun; Zhang, Yuan-zhu; Duan, Yi-fan; Lü, Xian-fu; He, Qiu-fang

    2016-05-15

    Microbial contamination in karst groundwater continually increases and tracing the source researches has become a hot topic for international researchers. In this study, Laolongdong underground river at Nanshan, Chongqing was chosen as an example to adopt filter membrane methods to monitor the fecal microbial contaminations including the total bacterial concentration (TB), the total E. coli concentration (TE), the total fecal coliform (FC) and the total fecal Streptocoocci (FS). Bacteriodes was used as an indicator and PCR-DGGE analysis was used to trace fecal contamination sources in karst groundwater. The results suggested that groundwater in this area was seriously polluted by microbes from feces. The concentrations of microbial parameters exceeded limited levels greatly and the total bacterial amounts ranged 10-2.9 x 10⁷ CFU · mL⁻¹, the concentrations of E. coli were between 4.3-4.0 x 10⁵ CFU · mL⁻¹, the max concentration of FC was 1.1 x 10⁶ CFU · (100 mL)⁻¹ and the max concentration of FS was 1.1 x 10⁵ CFU · (100 mL)⁻¹. The FC/FS ratios were mostly over 2 which suggested that the main fecal source in groundwater was human feces. In addition, PCR-DGGE contrastive analysis of Bacteroides communities showed that the similarities between groundwater samples and human feces were in range of 7. 1% -69. 1% , and the similarity of the groundwater sample from Laolongdong underground river outlet was 69.1% . Bacteroides community similarities between groundwater samples and swine feces were in range of 1.1%-53.4%, and the similarity of Laolongdong underground river outlet was merely 1.5%. The similarity data implied that groundwater contamination resulted mainly from human feces, swine feces contamination composed part of animals' fecal contamination, and other animals' feces participated too. Furthermore, sequencing results of PCR-DGGE products revealed that most Bacteroides in groundwater originated from human intestinal tract and human feces

  10. Assessing the impact of dairy waste lagoons on groundwater quality using a spatial analysis of vadose zone and groundwater information in a coastal phreatic aquifer.

    PubMed

    Baram, S; Kurtzman, D; Ronen, Z; Peeters, A; Dahan, O

    2014-01-01

    Dairy waste lagoons are considered to be point sources of groundwater contamination by chloride (Cl(-)), different nitrogen-species and pathogens/microorganisms. The objective of this work is to introduce a methodology to assess the past and future impacts of such lagoons on regional groundwater quality. The method is based on a spatial statistical analysis of Cl(-) and total nitrogen (TN) concentration distributions in the saturated and the vadose (unsaturated) zones. The method provides quantitative data on the relation between the locations of dairy lagoons and the spatial variability in Cl(-) and TN concentrations in groundwater. The method was applied to the Beer-Tuvia region, Israel, where intensive dairy farming has been practiced for over 50 years above the local phreatic aquifer. Mass balance calculations accounted for the various groundwater recharge and abstraction sources and sinks in the entire region. The mass balances showed that despite the small surface area covered by the dairy lagoons in this region (0.8%), leachates from lagoons have contributed 6.0% and 12.6% of the total mass of Cl(-) and TN (mainly as NO3(-)-N) added to the aquifer. The chemical composition of the aquifer and vadose zone water suggested that irrigated agricultural activity in the region is the main contributor of Cl(-) and TN to the groundwater. A low spatial correlation between the Cl(-) and NO3(-)-N concentrations in the groundwater and the on-land location of the dairy farms strengthened this assumption, despite the dairy waste lagoon being a point source for groundwater contamination by Cl(-) and NO3(-)-N. Mass balance calculations, for the vadose zone of the entire region, indicated that drying of the lagoons would decrease the regional groundwater salinization process (11% of the total Cl(-) load is stored under lagoons). A more considerable reduction in the groundwater contamination by NO3(-)-N is expected (25% of the NO3(-)-N load is stored under lagoons). Results

  11. Impact of the leaked CO2 from deep reservoirs on quality of shallow groundwater

    NASA Astrophysics Data System (ADS)

    Dai, Z.; Keating, E. H.; Viswanathan, H. S.; Pawar, R. J.; Bacon, D. H.; Carroll, S.

    2012-12-01

    One of the areas of concerns for geologic CO2 sequestration is the potential leakage of CO2 and brine from deeper storage reservoirs to shallow groundwater resources. This could lead to changes in shallow groundwater chemistry degrading water quality. As part of the National Risk Assessment Partnership (NRAP) for geologic CO2 sequestration project, we perform experimental and modeling studies to understand the mechanisms of the leaked CO2 and brine flow, transport and reaction with aquifer water and minerals. We have developed a 3-dimensional heterogeneous numerical model for an un-confined shallow aquifer that is being used to simulate the CO2 leakage and the associated geochemical interactions over 200 years. A Monte-Carlo analysis is performed to estimate the probability of plume sizes of the pH less than 6.5 and TDS larger than 500 ppm in the shallow aquifer. The metrics were chosen as proxies that indicate how groundwater quality is affected by leakage. The uncertain parameters in our study include five for describing geologic heterogeneity in the permeability (permeability mean, variance, integral range, anisotropic factor and porosity), one for lateral flow rate and five for defining the CO2 leakage rate in temporal and spatial domains. A global sensitivity analysis is conducted for three outputs (the amount of CO2 leaving the top of aquifer, the plume sizes of pH below 6.5 and TDS over 500 ppm). Finally, we derive one-, two- and three-dimensional response surfaces developed based on the 2000 process modeling results of CO2 and brine reactive transport models. These response surfaces have been incorporated into the system model CO2-PENS in order to calculate risk profiles that consider uncertainty in the sequestration reservoir, leaky wellbore and the shallow groundwater aquifer.

  12. Trend in groundwater quality near FMD burials in agricultural region, South Korea

    NASA Astrophysics Data System (ADS)

    Lim, Jeong-Won; Lee, Kang-Kun

    2015-04-01

    After the nation-wide outbreak of Foot and Mouth Disease (FMD) in winter of 2010-2011, thousands of mass burial site had been built all over the country in Korea. Though the burial pits were partially lined with impermeable material, potential threat of leachate leakage was still in concern. In worry of leachate release from those livestock burials during decomposition of carcasses, groundwater samples from wells near the burials were collected and analyzed in between 2011 and 2013. Among the sample locations, 250 wells with monitoring priorities were chosen and had been watched continuously through the years. For trend analysis of groundwater quality, relations between land use types, distances to burial and nitrate concentrations are studied. Types of land use within 300 m radius of each well were investigated. Nitrate concentrations show proportional relations to the area of agricultural activity and inversely proportional to the area of forest. The proportionality decreased with both agricultural and forest area since 2011. When seasonal variation is concerned, slightly stronger proportionality is shown in dry season for both agricultural and forested area. For a qualitative analysis of the trend, non-parametric Kendall test is applied. Especially, regional Kendall test is implemented to find out spatial feature of nitrate concentration. Nitrate concentrations show slow but statistically significant deceasing trend for every well. When the wells are group according to their distances from the nearest burial pit, decreasing trend of nitrate concentration is shown in all groups. However, there was no consistency in significant factor among the groups. Considering the above mentioned results, the groundwater wells near the burials seem to be influence more from agricultural activities near the wells than from the burial leachate. The slow but significant decreasing trend in nitrate concentration is supposed as the result of an increasing governmental interest in

  13. Atomic and Molecular Processes in the Solar System and Planetary Atmospheres:. AN Overview and Some Examples

    NASA Astrophysics Data System (ADS)

    Cravens, T. E.

    This chapter provides a brief summary of the overall role of atomic and molecular (ATM) processes in solar system environments and a few examples of Alex Dalgarno's contributions. The bulk of the chapter is devoted to the role of ion-neutral collisional processes at comet Halley and at Saturn's satellites Enceladus and Titan.

  14. Spatial Analysis of Groundwater Quality in Karstic Aquifers under Urbanization Stress: A Methodological Assessment

    NASA Astrophysics Data System (ADS)

    Abou Najm, Majdi; Momjian, Nanor; Alameddine, Ibrahim; El-Fadel, Mutasem

    2015-04-01

    Decision makers are increasingly relying on groundwater quality mapping using geospatial / statistical analysis tools coupled with Geographic Information Systems (GIS) that transform monitoring data into more readable maps for informed decisions. These tools are dependent on various interpolation methods that are invariably applied without proper knowledge of underlying assumptions thus often generating non-validated or unreliable maps. This study examines the accuracy of commonly used interpolation schemes with cross-validation using field measurements collected during groundwater sampling campaigns in three coastal cities along the eastern Mediterranean. The performance and accuracy of interpolation methods was scrutinized with multiple cross-checking approaches including (1) the leave-one-out, (2) matching with water quality standardized categories, and (3) cross-checking with the physical vulnerability of tapped aquifers. A total of 380 interpolation scenarios were generated using several combinations of interpolation methods (Inverse Distance Weight (IDW), Kriging and Co-Kriging), semi-variogram models (Spherical and Exponential), data transformation, and several water quality parameters including single and multiple contaminant indicators, in three cities and for different seasons. The results showed that Kriging and Co-Kriging produced relatively better statistical indicators, whereas the IDW matched better the field measurements when a lumped approach of six water quality categories was adopted. While it can be argued that there is no one "best" interpolation method or a semi-variogram model that fits all data, it was evident that the GIS-based interpolation methods exhibited better matching at the three surveyed cities in comparison with groundwater vulnerability assessment models such as DRASTIC and EPIK.

  15. Tracing the Origins and Processes of Groundwater Salinization in Coastal Aquifers with a Multi-isotopes Approach. Example of Recife, Northeast of Brazil

    NASA Astrophysics Data System (ADS)

    Cary, L.; Petelet-Giraud, E.; Bertrand, G.; Kloppmann, W.; Aquilina, L.; Pauwels, H.; Martins, V.; Hirata, R.; Montenegro, S.

    2015-12-01

    The Recife Metropolitan Region (PE, Brazil) is a typical "hot spot" illustrating the problems of southern countries on water issues inducing high pressures on water resources both on quantity and quality in the context of global social and environmental changes. By focusing on the groundwater geochemistry in a costal multilayer aquifer, this work aims at investigating the sources and processes of salinization. Two different Precambrian blocks separated by a large lineament area constitute the site basement. The sedimentary fillings of the two basins present different origins that were distinguished by the Sr isotope composition. The northern deep Beberibe aquifer displays very high 87Sr/86Sr with a large range of values (0.7102-0.7233) illustrating the main continental origin of sediments whereas the southern deep Cabo aquifer showed lower values (0.7097-0.7141) indicating the contribution of the marine sedimentation. Although sulfate isotopes, Electrical Conductivity and Cl contents indicate a mixing with seawater for some samples of the deep Cabo and Beberibe aquifers, all 87Sr/86Sr values are above the present-day seawater composition. This can be related to the complex local history of transgression/regression phases that induced alternatively salinisation and freshening with gains and losses of cations and Sr, together with water-rock interactions. δ18O-δ2H clearly evidence the local present day recharge in the surficial aquifer, some samples being affected by in situ evaporation processes and/or recharge with evaporated water from dams used for water supply. The deep aquifers display a high range of B (20-600µg/L) and δ11B (6.7-68.5‰) with some of the highest values known to date. Multiple sources and processes affect the B behavior, among which mixing with saline water, B sorption on clays/organic matter and mixing with wastewater. The surficial aquifers are locally salinized possibly due to present seawater intrusion, and highly contaminated with

  16. Calendar year 1993 groundwater quality report for the Bear Creek Hydrogeologic Regime, Y-12 Plant, Oak Ridge, Tennessee. 1993 groundwater and surface water quality data and calculated rate of contaminant migration, Part 1

    SciTech Connect

    Not Available

    1994-02-01

    This report contains groundwater and surface-water quality data obtained during the 1993 calendar year (CY) at several hazardous and non-hazardous waste-management facilities associated with the US Department of Energy (DOE) Y-12 Plant located on the DOE Oak ridge Reservation (ORR) southeast of Oak Ridge, Tennessee. These sites are located southwest of the Y-12 Plant complex within the Bear Creek Hydrogeologic Regime (Bear Creek Regime), which is one of three regimes defined for the purposes of groundwater and surface-water quality monitoring at the Y-12 Plant. The Environmental Management Department of the Y-12 Plant Health, Safety, Environment, and Accountability (HSEA) Organization manages the monitoring activities in each regime as part of the Y-12 Plant Groundwater Protection Program (GWPP). The annual groundwater and surface water report for the Bear Creek Regime is completed in two-parts; Part 1 (this report) containing the groundwater and surface-water quality data and Part 2 containing a detailed evaluation of the data. The primary purpose of this report is to serve as a reference for the groundwater and surface-water quality data obtained each year under the lead of the Y-12 Plant GWPP. However, because it contains information needed to comply with Resource Conservation and Recovery Act (RCRA) interim status assessment monitoring reporting requirements, this report is submitted to the Tennessee Department of Health and Environment (TDEC) by the RCRA reporting deadline.

  17. Hydrogeological characterization and assessment of groundwater quality in shallow aquifers in vicinity of Najafgarh drain of NCT Delhi

    NASA Astrophysics Data System (ADS)

    Shekhar, Shashank; Sarkar, Aditya

    2013-02-01

    Najafgarh drain is the biggest drain in Delhi and contributes about 60% of the total wastewater that gets discharged from Delhi into river Yamuna. The drain traverses a length of 51 km before joining river Yamuna, and is unlined for about 31 km along its initial stretch. In recent times, efforts have been made for limited withdrawal of groundwater from shallow aquifers in close vicinity of Najafgarh drain coupled with artificial recharge of groundwater. In this perspective, assessment of groundwater quality in shallow aquifers in vicinity of the Najafgarh drain of Delhi and hydrogeological characterization of adjacent areas were done. The groundwater quality was examined in perspective of Indian as well as World Health Organization's drinking water standards. The spatial variation in groundwater quality was studied. The linkages between trace element occurrence and hydrochemical facies variation were also established. The shallow groundwater along Najafgarh drain is contaminated in stretches and the area is not suitable for large-scale groundwater development for drinking water purposes.

  18. Groundwater Impacts on Urban Surface Water Quality in the Lowland Polder Catchments of the Amsterdam City Area

    NASA Astrophysics Data System (ADS)

    Rozemeijer, J.; Yu, L.; Van Breukelen, B. M.; Broers, H. P.

    2015-12-01

    Surface water quality in the Amsterdam area is suffering from high nutrient levels. The sources and transport mechanisms of these nutrients are unclear due to the complex hydrology of the highly manipulated urban and sub-urban polder catchments. This study aimed at identifying the impact of groundwater on surface water quality in the polder catchments of the greater Amsterdam city area. Therefore, we exploited the dense groundwater and surface water monitoring networks to explain spatial patterns in surface water chemistry and their relations with landscape characteristics and groundwater impact. We selected and statistically analyzed 23 variables for 144 polders, covering a total area of 700 km2. Our dataset includes concentrations of total-N, total-P, ammonium, nitrate, bicarbonate, sulfate, calcium, and chloride in surface water and groundwater, seepage rate, elevation, paved area percentage, surface water area percentage, and soil type (calcite, humus and clay percentages). Our results show that nutrient levels in groundwater were generally much higher than in surface water and often exceeded the surface water Environmental Quality Standards (EQSs). This indicates that groundwater is a large potential source of nutrients in surface water. High correlations (R2 up to 0.88) between solutes in both water compartments and close similarities in their spatial patterns confirmed the large impact of groundwater on surface water quality. Groundwater appeared to be a major source of chloride, bicarbonate and calcium in surface water and for N and P, leading to exceeding of EQSs in surface waters. In dry periods, the artificial redistribution of excess seepage water from deep polders to supply water to infiltrating polders further distributes the N and P loads delivered by groundwater over the area.

  19. Quality Assessment - Example of Digital Products of Fundamental Geographic Information of China

    NASA Astrophysics Data System (ADS)

    Guoqing, D.; Ping, X.

    2013-05-01

    Digital products of fundamental geographic information are the main components of Digital China Geo-spatial Framework (DCGSF for short). More and more mass data were produced and distributed to various users by different agencies and organizations with continuous implementation of fundamental surveying and mapping activities and various specified projects within national Administration of Surveying, Mapping & Geoinformation. Therefore, what about the description and quality assessment used for these products will directly effect the acquisition, delivery, share, and application of data. A quality model, by which quality is assessed through 3 levels of classification of quality elements, quality subelements, and check items, was built in this paper based on ISO 19113 and ISO 19114 so that to make the quality of digital products of fundamental geographic information to be assessed reasonably, and to make the quality assessment tools to be operable in practice. Quality assessment methods respectively for each of quality elements, quality subelements, and check items are presented. Fundamental data of Digital Line Graphs, Digital Elevation Models, Digital Orthophoto Maps, and Digital Raster Maps at the scale of 1:50,000 in DCGSF were used as examples to determine the quality of 9 quality elements, 24 quality subelements, and 68 check items considering the contents and the requirements of various users for these data, as well as the practical experiences in quality assessment. 300 DLGs selected from national key projects of surveying and mapping engineering were used for testing to validate the operability of the results mentioned in this paper. Random sampling is used, when sampling, for each layer, which is layered based on production unit and level of difficulty. Quality checking and quality assessment, and statistical analysis was done for samples in terms of item product and lot products respectively. The results from this test indicated that quality model and

  20. Status and understanding of groundwater quality in the San Francisco Bay groundwater basins, 2007—California GAMA Priority Basin Project

    USGS Publications Warehouse

    Parsons, Mary C.; Kulongoski, Justin T.; Belitz, Kenneth

    2013-01-01

    Groundwater quality in the approximately 620-square-mile (1,600-square-kilometer) San Francisco Bay study unit was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is located in the Southern Coast Ranges of California, in San Francisco, San Mateo, Santa Clara, Alameda, and Contra Costa Counties. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The GAMA San Francisco Bay study was designed to provide a spatially unbiased assessment of the quality of untreated groundwater within the primary aquifer system, as well as a statistically consistent basis for comparing water quality throughout the State. The assessment is based on water-quality and ancillary data collected by the USGS from 79 wells in 2007 and is supplemented with water-quality data from the California Department of Public Health (CDPH) database. The primary aquifer system is defined by the depth interval of the wells listed in the CDPH database for the San Francisco Bay study unit. The quality of groundwater in shallower or deeper water-bearing zones may differ from that in the primary aquifer system; shallower groundwater may be more vulnerable to surficial contamination. The first component of this study, the status of the current quality of the groundwater resource, was assessed by using data from samples analyzed for volatile organic compounds (VOCs), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. Water- quality data from the CDPH database also were incorporated for this assessment. This status assessment is intended to characterize the quality of groundwater resources within the primary aquifer system of the San Francisco Bay study unit, not the treated drinking water delivered to consumers by water

  1. Groundwater recharge in a semi-arid environment under high climatic variability and over-pumping: Ajlun Highlands example, Jordan.

    NASA Astrophysics Data System (ADS)

    Raggad, Marwan; Salameh, Elias; Magri, Fabien; Siebert, Christian; Roediger, Tino; Moller, Peter

    2016-04-01

    Jordan's ground water resources are being exploited up to 190% of the safe yield while rainfall rates are decreasing and highly variable, thereby affecting recharge volumes of the aquifers. The Ajlun highlands, forming the northwestern edge of Jordan are characterized by annual rainfall rates exceeding 500 mm, the highest in the country, which leads to accordingly high replenishment of almost the entire groundwater system in northern Jordan. The high recharge and the NW-wards dipping strata lead to a groundwater flow towards the north and northwest, areas which host the vital aquifers of the region. Limited and degraded groundwater recharge combined with growing over-pumping are the main issues that regard the northern groundwater basins, such as Wadi Arab, Yarmouk and the Jordan Valley side basins. To evaluate the groundwater potential under high recharge variability, groundwater recharge was modeled and compared to different Global Circulation Models (GCMs). Groundwater recharge was calculated based on climatic data covering the time period from 1965 to 2014. Recharge modeling was conducted by applying the J2000 water budget model. The simulation of hydrologic processes uses independent parameters that are calculated prior to simulate the recharge flow. The simulations estimate recharge of 47.6 MCM, which is 12% less than the values given by the Jordanian authorities. The low calculated recharge is likely due to an overestimation of the evapotranspiration in areas with high topographic slopes. To examine the variability of groundwater recharge under current climatic conditions, statistical downscaling of global circulation models was conducted for the time period 1965 - 2000. Data for the time period 2001 - 2014 was used for the model validation. Results indicated a decline of 18.7% in precipitation by the year 2050 with an increase of 1.7 and 2.2 degrees in maximum and minimum temperatures respectively. Accordingly recharge for the year 2050 is 27% less than

  2. Evaluation of groundwater quality and its suitability for drinking and agricultural use in the coastal stretch of Alappuzha District, Kerala, India

    NASA Astrophysics Data System (ADS)

    Sarath Prasanth, S. V.; Magesh, N. S.; Jitheshlal, K. V.; Chandrasekar, N.; Gangadhar, K.

    2012-09-01

    Groundwater is an essential and vital component of any life support system. It is not only the basic need for human existence but also a vital input for all development activities. The present hydro-geochemical study was confined to the coastal belt of Alappuzha district, which lies in the coastal lowland division of Kerala. Groundwater quality and its suitability for irrigation and domestic purpose were examined by various physico-chemical parameters such as pH, electrical conductivity, total dissolved solids, total hardness, calcium, magnesium, sodium, potassium, bicarbonate, sulfate, and chloride. These parameters were used to assess the suitability of groundwater for domestic purpose by comparing with the WHO and Indian standards. TDS, sodium adsorption ratio (SAR), and permeability index were used for irrigation suitability assessment. The sample analysis reveals that the groundwater is not entirely fit for drinking with respect to pH, EC, Ca2+, Mg2+, Na+, and Cl-. In some of the collected samples, the concentrations of these parameters exceed the permissible limits of WHO and ISI standards. Based on TDS and SAR almost all samples are suitable for irrigation purpose except a few locations, which show values beyond the permissible limits. Ca-Mg-HCO3 is the dominant water type in the study area. The sequence of the abundance of the major cations and anions is Ca > Na > Mg > K = HCO3 > Cl > SO4. Based on the total hardness and TDS, 96 % of groundwater samples are found suitable for drinking purpose.

  3. Characterization of Ground-Water Quality, Upper Republican Natural Resources District, Nebraska, 1998-2001

    USGS Publications Warehouse

    Frankforter, Jill D.; Chafin, Daniele T.

    2004-01-01

    Nearly all rural inhabitants and livestock in the Upper Republican Natural Resources District (URNRD) in southwestern Nebraska use ground water that can be affected by elevated nitrate concentrations. The development of ground-water irrigation in this area has increased the vulnerability of ground water to the introduction of fertilizers and other agricultural chemicals. In 1998, the U.S. Geological Survey, in cooperation with the Upper Republican Natural Resources District, began a study to characterize the quality of ground water in the Upper Republican Natural Resources District area with respect to physical properties and concentrations of major ions, coliform bacteria, nitrate, and pesticides, and to assess the presence of nitrogen concentrations in the unsaturated zone. At selected well sites, the ground-water characterization also included tritium and nitrogen-isotope analyses to provide information about the approximate age of the ground water and potential sources of nitrogen detected in ground-water samples, respectively. In 1998, ground-water samples were collected from 101 randomly selected domestic-well sites. Of the 101 samples collected, 26 tested positive for total coliform bacteria, exceeding the U.S. Environmental Protection Agency's Maximum Contaminant Level (MCL) of zero colonies. In 1999, ground-water samples were collected from 31 of the 101 well sites, and 16 tested positive for coliform bacteria. Nitrates were detected in ground water from all domestic-well samples and from all but four of the irrigation-well samples collected from 1998 to 2001. Eight percent of the domestic-well samples and 3 percent of the irrigation-well samples had nitrate concentrations exceeding the U.S. Environmental Protection Agency's MCL for drinking water of 10 milligrams per liter. Areas with nitrate concentrations exceeding 6 milligrams per liter, the URNRD's ground-water management-plan action level, were found predominantly in north-central Chase, western and

  4. Quality-control results for ground-water and surface-water data, Sacramento River Basin, California, National Water-Quality Assessment, 1996-1998

    USGS Publications Warehouse

    Munday, Cathy; Domagalski, Joseph L.

    2003-01-01

    Evaluating the extent that bias and variability affect the interpretation of ground- and surface-water data is necessary to meet the objectives of the National Water-Quality Assessment (NAWQA) Program. Quality-control samples used to evaluate the bias and variability include annual equipment blanks, field blanks, field matrix spikes, surrogates, and replicates. This report contains quality-control results for the constituents critical to the ground- and surface-water components of the Sacramento River Basin study unit of the NAWQA Program. A critical constituent is one that was detected frequently (more than 50 percent of the time in blank samples), was detected at amounts exceeding water-quality standards or goals, or was important for the interpretation of water-quality data. Quality-control samples were collected along with ground- and surface-water samples during the high intensity phase (cycle 1) of the Sacramento River Basin NAWQA beginning early in 1996 and ending in 1998. Ground-water field blanks indicated contamination of varying levels of significance when compared with concentrations detected in environmental ground-water samples for ammonia, dissolved organic carbon, aluminum, and copper. Concentrations of aluminum in surface-water field blanks were significant when compared with environmental samples. Field blank samples collected for pesticide and volatile organic compound analyses revealed no contamination in either ground- or surface-water samples that would effect the interpretation of environmental data, with the possible exception of the volatile organic compound trichloromethane (chloroform) in ground water. Replicate samples for ground water and surface water indicate that variability resulting from sample collection, processing, and analysis was generally low. Some of the larger maximum relative percentage differences calculated for replicate samples occurred between samples having lowest absolute concentration differences and(or) values near

  5. Groundwater-quality data in the Bear Valley and Selected Hard Rock Areas study unit, 2010: Results from the California GAMA Program

    USGS Publications Warehouse

    Mathany, Timothy M.; Belitz, Kenneth

    2013-01-01

    pesticide degradates, pharmaceutical compounds, and wastewater indicator compounds [WICs]), constituents of special interest (perchlorate, N-nitrosodimethylamine [NDMA], and 1,2,3-trichloropropane [1,2,3-TCP]), and inorganic constituents (trace elements, nutrients, dissolved organic carbon [DOC], major and minor ions, silica, total dissolved solids [TDS], alkalinity, and arsenic and iron species), and uranium and other radioactive constituents (radon-222 and activities of tritium and carbon-14). Isotopic tracers (of hydrogen and oxygen in water, of nitrogen and oxygen in dissolved nitrate, of dissolved boron, isotopic ratios of strontium in water, and of carbon in dissolved inorganic carbon) and dissolved noble gases (argon, helium-4, krypton, neon, and xenon) were measured to help identify the sources and ages of sampled groundwater. In total, groundwater samples were analyzed for 289 unique constituents and 8 water-quality indicators in the BEAR study unit. Quality-control samples (blanks, replicate pairs, or matrix spikes) were collected at 13 percent of the sites in the BEAR study unit, and the results for these samples were used to evaluate the quality of the data from the groundwater samples. Blank samples rarely contained detectable concentrations of any constituent, indicating that contamination from sample collection or analysis was not a significant source of bias in the data for the groundwater samples. Replicate pair samples all were within acceptable limits of variability. Matrix-spike sample recoveries were within the acceptable range (70 to 130 percent) for approximately 84 percent of the compounds. This study did not evaluate the quality of water delivered to consumers. After withdrawal, groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is delivered to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations

  6. Maps of the Bonsall area of the San Luis Rey River valley, San Diego County, California, showing geology, hydrology, and ground-water quality

    USGS Publications Warehouse

    Izbicki, John A.

    1985-01-01

    In November 1984, 84 wells and 1 spring in the Bonsall area of the San Luis Rey River valley were inventoried by U.S. Geological Survey personnel. Depth to water in 38 wells ranged from 1.3 to 38 ft and 23 wells had depths to water less than 10 feet. Dissolved solids concentration of water from 29 wells and 1 spring sampled in autumn 1983 and spring 1984 ranged from 574 to 2,370 mgs/L. Groundwater with a dissolved solids concentration less than 1,000 mgs/L was generally restricted to the eastern part of the aquifer. The total volume of alluvial fill in the Bonsall area is 113,000 acre-feet; the amount of groundwater storage available in the alluvial aquifer is 18,000 acre-feet. The alluvial aquifer is, in part, surrounded and underlain by colluvium and weathered crystalline rock that add some additional groundwater storage capacity to the system. Data in this report are presented on five maps showing well locations , thickness of alluvial fill, water level contours in November 1983 and hydrographs of selected wells, groundwater quality in spring 1960 and graphs showing changes in dissolved solids concentrations of water from selected wells with time, and groundwater quality in spring 1984. This report is part of a larger cooperative project between the Rainbow Municipal Irrigation District and the U.S. Geological Survey. The purpose of the larger project is to develop an appropriate groundwater management plan for the Bonsall area of the San Luis Rey River valley. (USGS)

  7. Evaluation of groundwater quality and assessment of scaling potential and corrosiveness of water samples in Kadkan aquifer, Khorasan-e-Razavi Province, Iran.

    PubMed

    Esmaeili-Vardanjani, Mostafa; Rasa, Iraj; Amiri, Vahab; Yazdi, Mohammad; Pazand, Kaveh

    2015-02-01

    The chemical analysis of 129 groundwater samples in the Kadkan area, Khorasan-e-Razavi Province, NE of Iran was evaluated to determine the hydrochemical processes, assessment of groundwater quality for irrigation purposes, corrosiveness, and scaling potential of the groundwater. Accordingly, the suitability of groundwater for irrigation was evaluated based on the sodium adsorption ratio, residual sodium carbonate, sodium percent, salinity hazard, and US Salinity Laboratory hazard diagram. Based on the electrical conductivity and sodium adsorption ratio, the dominant classes are C3-S1, C3-S2, C2-S1, and C4-S2. According to the Wilcox plot, about 50 % of the samples fall in the "Excellent to Good" and "Good to Permissible" classes. Besides, the Langelier saturation index, Ryznar stability index (RSI), Larson-Skold index, and Puckorius scaling index were evaluated for assessing the corrosiveness and scaling potential of the groundwater. Corrosiveness and scaling indices stated that the majority of samples are classified into "Aggressive" and "Very Aggressive" category. In addition, chloride and sulfate interfere in 90 % of the samples. Assessment of hydrochemical characteristics indicates Na-Mg-Cl as the predominant hydrochemical type. Spatial distribution of hydrochemical parameters indicates that hydrochemical processes are influenced by geology and hydrogeology of Kadkan aquifer. The Gibbs plots gave an indication that groundwater chemistry in this area may have acquired the chemistry mainly from evaporation and mineral precipitation. Grouping the samples based on Q-mode hierarchical cluster analysis helped to more separation of similar samples. The R-mode HCA grouped analyzed parameters into two groups based on similarity of hydrochemical characteristics. As a result, the samples collected in northern and southern parts of the study area show the best quality (i.e., lowest salinity) for some purposes such as irrigation and drinking. PMID:25638056

  8. Calendar year 1994 groundwater quality report for the Chestnut Ridge Hydrogeologic Regime, Y-12 Plant, Oak Ridge, Tennessee

    SciTech Connect

    1995-09-01

    This groundwater quality report (GWQR) contains an evaluation of the groundwater quality data obtained during the 1994 calendar year (CY) at several hazardous and non-hazardous waste management facilities associated with the US Department of Energy (DOE) Y-12 Plant located on the DOE Oak Ridge Reservation (ORR) southeast of Oak Ridge, Tennessee (Figure 1). These sites lie within the boundaries of the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime), which is one of three hydrogeologic regimes defined for the purposes of groundwater quality monitoring at the Y-12 Plant (Figure 2). The Environmental Management Department of the Y-12 Plant Health, Safety, Environment, and Accountability (HSEA) Organization manages the groundwater monitoring activities in each regime under the auspices of the Y-12 Plant Groundwater Protection Program (GWPP). The purpose of the GWPP is to characterize the hydrogeology and to monitor groundwater quality at the Y-12 Plant and surrounding area to protect local groundwater resources in accordance with federal, state, and local regulations, DOE Orders, and Lockheed Martin Energy Systems, Inc. (Energy Systems) corporate policy. The annual GWQR for the Chestnut Ridge Regime is completed in two parts. Part 1 consists primarily of data appendices and serves as a reference for the groundwater quality data obtained each CY under the lead of the Y-12 Plant GWPP. Because it contains information needed to comply with reporting requirements of Resource Conservation and Recovery Act (RCRA) interim status assessment monitoring, the Part 1 GWQR is submitted to the Tennessee Department of Environment and Conservation (TDEC) by the RCRA reporting deadline (March 1 of the following CY); Energy Systems submitted the 1994 Part 1 GWQR for the Chestnut Ridge Regime to the TDEC in February 1995 (HSW Environmental Consultants, Inc. 1995a).

  9. The quality of our Nation's waters: groundwater quality in the Columbia Plateau and Snake River Plain basin-fill and basaltic-rock aquifers and the Hawaiian volcanic-rock aquifers, Washington, Idaho, and Hawaii, 1993-2005

    USGS Publications Warehouse

    Rupert, Michael G.; Hunt, Charles D., Jr.; Skinner, Kenneth D.; Frans, Lonna M.; Mahler, Barbara J.

    2015-01-01

    The Columbia Plateau, Snake River Plain, and Hawaii are large volcanic areas in the western United States and mid-Pacific ocean that contain extensive regional aquifers of a hard, gray, volcanic rock called basalt. Residents of the Columbia Plateau, the Snake River Plain, and the island of Oahu depend on groundwater as their primary source of drinking water. Although the depth to the water table can be several hundred feet, the groundwater is highly vulnerable to contamination because the permeable sediments and rocks allow contaminants to move readily down to the water table. Intense agricultural and urban activities occur above the drinking-water supply and are increasing in some areas. Contaminants, such as nitrate, pesticides, and volatile organic compounds, associated with agricultural and urban activities, have adversely affected groundwater quality.

  10. Status of groundwater quality in the San Fernando--San Gabriel study unit, 2005--California GAMA Priority Basin Project

    USGS Publications Warehouse

    Land, Michael; Kulongoski, Justin T.; Belitz, Kenneth

    2012-01-01

    Groundwater quality in the approximately 460-square-mile San Fernando--San Gabriel (FG) study unit was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study area is in Los Angeles County and includes Tertiary-Quaternary sedimentary basins situated within the Transverse Ranges of southern California. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The GAMA FG study was designed to provide a spatially unbiased assessment of the quality of untreated (raw) groundwater in the primary aquifer systems (hereinafter referred to as primary aquifers) throughout California. The assessment is based on water-quality and ancillary data collected in 2005 by the USGS from 35 wells and on water-quality data from the California Department of Public Health (CDPH) database. The primary aquifers were defined by the depth interval of the wells listed in the CDPH database for the FG study unit. The quality of groundwater in primary aquifers may be different from that in the shallower or deeper water-bearing zones; shallow groundwater may be more vulnerable to surficial contamination. This study assesses the status of the current quality of the groundwater resource by using data from samples analyzed for volatile organic compounds (VOCs), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. This status assessment is intended to characterize the quality of groundwater resources in the primary aquifers of the FG study unit, not the treated drinking water delivered to consumers by water purveyors.

  11. Groundwater-Quality Data in the South Coast Range-Coastal Study Unit, 2008: Results from the California GAMA Program

    USGS Publications Warehouse

    Mathany, Timothy M.; Burton, Carmen A.; Land, Michael; Belitz, Kenneth

    2010-01-01

    Groundwater quality in the approximately 766-square-mile South Coast Range-Coastal (SCRC) study unit was investigated from May to December 2008, as part of the Priority Basins Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basins Project was developed in response to legislative mandates (Supplemental Report of the 1999 Budget Act 1999-00 Fiscal Year; and, the Groundwater Quality Monitoring Act of 2001 [Sections 10780-10782.3 of the California Water Code, Assembly Bill 599]) to assess and monitor the quality of groundwater in California, and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The SCRC study unit was the 25th study unit to be sampled as part of the GAMA Priority Basins Project. The SCRC study unit was designed to provide a spatially unbiased assessment of untreated groundwater quality in the primary aquifer systems and to facilitate statistically consistent comparisons of untreated groundwater quality throughout California. The primary aquifer systems (hereinafter referred to as primary aquifers) were defined as that part of the aquifer corresponding to the perforation interval of wells listed in the California Department of Public Health (CDPH) database for the SCRC study unit. The quality of groundwater in shallow or deep water-bearing zones may differ from the quality of groundwater in the primary aquifers; shallow groundwater may be more vulnerable to surficial contamination. In the SCRC study unit, groundwater samples were collected from 70 wells in two study areas (Basins and Uplands) in Santa Barbara and San Luis Obispo Counties. Fifty-five of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells), and 15 wells were selected to aid in evaluation of specific water-quality issues (understanding wells). In addition to

  12. Combining natural background levels (NBLs) assessment with indicator kriging analysis to improve groundwater quality data interpretation and management.

    PubMed

    Ducci, Daniela; de Melo, M Teresa Condesso; Preziosi, Elisabetta; Sellerino, Mariangela; Parrone, Daniele; Ribeiro, Luis

    2016-11-01

    The natural background level (NBL) concept is revisited and combined with indicator kriging method to analyze the spatial distribution of groundwater quality within a groundwater body (GWB). The aim is to provide a methodology to easily identify areas with the same probability of exceeding a given threshold (which may be a groundwater quality criteria, standards, or recommended limits for selected properties and constituents). Three case studies with different hydrogeological settings and located in two countries (Portugal and Italy) are used to derive NBL using the preselection method and validate the proposed methodology illustrating its main advantages over conventional statistical water quality analysis. Indicator kriging analysis was used to create probability maps of the three potential groundwater contaminants. The results clearly indicate the areas within a groundwater body that are potentially contaminated because the concentrations exceed the drinking water standards or even the local NBL, and cannot be justified by geogenic origin. The combined methodology developed facilitates the management of groundwater quality because it allows for the spatial interpretation of NBL values. PMID:27371772

  13. Groundwater quality in the Chemung River, Eastern Lake Ontario, and Lower Hudson River Basins, New York, 2013

    USGS Publications Warehouse

    Scott, Tia-Marie; Nystrom, Elizabeth A.; Reddy, James E.

    2015-01-01

    The Lower Hudson River Basin study area covers 5,607 square miles and encompasses the part of the Lower Hudson River Basin that lies within New York plus the parts of the Housatonic, Hackensack, Bronx, and Saugatuck River Basins that are in New York. Twelve of the wells sampled in the Lower Hudson River Basin are completed in sand-and-gravel deposits, and 13 are completed in bedrock. Groundwater in the Lower Hudson River Basin was generally of good quality, although properties and concentrations of some constituents—pH, sodium, chloride, dissolved solids, arsenic, aluminum, iron, manganese, radon-222, total coliform bacteria, fecal coliform bacteria, Escherichia coli bacteria, and heterotrophic plate count—equaled or exceeded primary, secondary, or proposed drinking-water standards. The constituent most frequently detected in concentrations exceeding drinking-water standards (20 of 25 samples) was radon-222.

  14. Status of groundwater quality in the Coastal Los Angeles Basin, 2006-California GAMA Priority Basin Project

    USGS Publications Warehouse

    Goldrath, Dara; Fram, Miranda S.; Land, Michael; Belitz, Kenneth

    2012-01-01

    Groundwater quality in the approximately 860-square-mile (2,227-square-kilometer) Coastal Los Angeles Basin study unit (CLAB) was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study area is located in southern California in Los Angeles and Orange Counties. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The GAMA CLAB study was designed to provide a spatially unbiased assessment of the quality of untreated (raw) groundwater in the primary aquifer system. The assessment is based on water-quality and ancillary data collected in 2006 by the USGS from 69 wells and on water-quality data from the California Department of Public Health (CDPH) database. The primary aquifer system was defined by the depth interval of the wells listed in the CDPH database for the CLAB study unit. The quality of groundwater in the primary aquifer system may be different from that in the shallower or deeper water-bearing zones; shallow groundwater may be more vulnerable to surficial contamination. This study assesses the status of the current quality of the groundwater resource by using data from samples analyzed for volatile organic compounds (VOCs), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. This status assessment is intended to characterize the quality of groundwater resources in the primary aquifer system of the CLAB study unit, not the treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentration divided by the health- or aesthetic-based benchmark concentration) were used for evaluating groundwater quality for those constituents that have Federal and (or) California regulatory or non-regulatory benchmarks for drinking-water quality. A relative

  15. The Importance of Groundwater in Regulating Stream Water Quantity and Quality in a Claypan Watershed in Missouri

    NASA Astrophysics Data System (ADS)

    Liu, F.; Peters, G.; Lerch, R. N.; Yang, J.

    2015-12-01

    Claypans are a sub-soil horizon of smectitic mineralogy that impedes percolation and promotes surface runoff. These soils, which encompass 33,000 km2 in portions of Missouri and Illinois, have long been thought to restrict contaminant transport into/from groundwater. However, recent studies have shown that claypan watersheds are vulnerable to the loss of agricultural chemicals, particularly nitrate. The purpose of our study was to understand the role of groundwater in regulating stream water quantity and quality in Goodwater Creek Experimental Watershed (GCEW) in northern central Missouri. Samples have been collected since 2011 from precipitation, stream water at three locations along the main stream, groundwater from twenty five wells with depths ranging from 3 to 15 m, and soil water from seven piezometers above the claypan. Mean nitrate concentrations were 4.1 ppm in stream water at the watershed outlet, 1.0 ppm in precipitation, 3.2 ppm in soil water at piezometers, and 18.9 ppm in groundwater. Using diagnostic tools of mixing model and end-member mixing analysis, three natural tracers were determined to be conservative - electric conductivity (EC), Mg2+ and Na+ and three end-members were identified to control stream water - surface runoff (chemically characterized by precipitation), interflow above the claypan (characterized by soil water in piezometers), and groundwater. Interflow and groundwater contributed, on average, 26% and 12% of stream flow at the watershed outlet, respectively. During low flows, however, the contribution of groundwater increased to 30-40%. Also, the mean contribution of groundwater increased to 16% at middle course and 19% at the headwaters. Nitrate concentrations in stream water were dominated by the contributions from groundwater during low flows, ranging from 50 to 90% at all stream sampling locations. This study highlights the vulnerability of groundwater to nitrate contamination, even in runoff-prone watersheds, and demonstrated

  16. Altitude, age, and quality of groundwater, Papio-Missouri River Natural Resources District, eastern Nebraska, 1992 to 2009

    USGS Publications Warehouse

    McGuire, Virginia L.; Ryter, Derek W.; Flynn, Amanda S.

    2012-01-01

    The U.S. Geological Survey, in cooperation with the Papio-Missouri River Natural Resources District (PMRNRD), conducted this study to map the water-level altitude of 2009 within the Elkhorn River Valley, Missouri River Valley, and Platte River Valley alluvial aquifers; to present the predevelopment potentiometric-surface altitude within the Dakota aquifer; and to describe the age and quality of groundwater in the five principal aquifers of the PMRNRD in eastern Nebraska using data collected from 1992 to 2009. In addition, implications of alternatives to the current PMRNRD groundwater-quality monitoring approach are discussed. In the PMRNRD, groundwater altitude, relative to National Geodetic Vertical Datum of 1929, ranged from about 1,080 feet (ft) to 1,180 ft in the Elkhorn River Valley alluvial aquifer and from about 960 ft to 1,080 ft in the Missouri River Valley and Platte River Valley alluvial aquifers. In the PMRNRD, the estimated altitude of the potentiometric surface of the Dakota aquifer, predevelopment, ranged from about 1,100 ft to 1,200 ft. To assess groundwater age and quality, groundwater samples were collected from a total of 217 wells from 1992 to 2009 for analysis of various analytes. Groundwater samples collected in the PMRNRD from 1992 to 2009 and interpreted in this report were analyzed for age-dating analytes (chlorofluorocarbons), dissolved gases, major ions, trace elements, nutrients, stable isotope ratios, pesticides and pesticide degradates, volatile organic compounds, explosives, and 222radon. Apparent groundwater age was estimated from concentrations of chlorofluorocarbons measured in samples collected in 2000. Apparent groundwater-recharge dates ranged from older than 1940 in samples from wells screened in the Missouri River Valley alluvial aquifer to the early 1980s in samples from wells screened in the Dakota aquifer. Concentrations of major ions in the most recent sample per well collected from 1992 to 2009 indicate that the

  17. Groundwater quality analysis using multivariate statistical techniques (case study: Fars province, Iran).

    PubMed

    Noshadi, Masoud; Ghafourian, Amir

    2016-07-01

    This research investigated the quality of groundwater of 298 wells during 10 years, in Fars province, southern Iran, to survey spatial variation of groundwater quality and also major sources of hydro-chemical components for drinking and agricultural uses. To classify the sampling stations in each year, hierarchical cluster analysis, using the Euclidean distances and "Ward" method, was used. According to the results of cluster analysis, there were three quality groups in groundwater of the research area: first group of 170 wells with type of Ca-HCO3, second group of 98 wells with type of Ca-HCO3, and third group of 30 wells with type of Na-Cl. Hydro-chemical parameters were increased from the first to the third group, and on the basis of Schoeller and USSL diagrams, the water of wells of the third group was considered unsuitable for irrigation and drinking. Principal component (PC) analysis and factor analysis reduced the complex and voluminous data matrix into three main components, accounting for more than 80 % of the total variance. The first PC contained TDS, EC, TH, Na(+), Cl(-), Mg(2+), SO4 (2-), Ca(2+), and SAR parameters. Therefore, the first dominant factor was salinity. In PC2, HCO3 and pH were the dominant parameters, which may indicate weathering of silicate minerals. The PC3 contained high loadings for NO2 (2-) and NO3 (-). This factor indicates anthropogenic contaminants that may be caused by improper disposal of domestic wastes or the use of chemical fertilizers in agriculture and leaching of them. PMID:27317054

  18. Impacts of groundwater metal loads from bedrock fractures on water quality of a mountain stream.

    PubMed

    Caruso, Brian S; Dawson, Helen E

    2009-06-01

    Acid mine drainage and metal loads from hardrock mines to surface waters is a significant problem in the western USA and many parts of the world. Mines often occur in mountain environments with fractured bedrock aquifers that serve as pathways for metals transport to streams. This study evaluates impacts from current and potential future groundwater metal (Cd, Cu, and Zn) loads from fractures underlying the Gilt Edge Mine, South Dakota, on concentrations in Strawberry Creek using existing flow and water quality data and simple mixing/dilution mass balance models. Results showed that metal loads from bedrock fractures to the creek currently contribute <1% of total loads. Even if background water quality is achieved upstream in Strawberry Creek, fracture metal loads would be <5%. Fracture loads could increase substantially and cause stream water quality standards exceedances once groundwater with elevated metals concentrations in the aquifer matrix migrates to the fractures and discharges to the stream. Potential future metal loads from an upstream fracture would contribute a small proportion of the total load relative to current loads in the stream. Cd has the highest stream concentrations relative to standards. Even if all stream water was treated to remove 90% of the Cd, the standard would still not be achieved. At a fracture farther downstream, the Cd standard can only be met if the upstream water is treated achieving a 90% reduction in Cd concentrations and the median stream flow is maintained. PMID:18604589

  19. Design of monitor wells, hydrogeology, and ground-water quality beneath Country Pond, Kingston, New Hampshire

    USGS Publications Warehouse

    Mack, Thomas J.

    1995-01-01

    Ten monitoring well were installed in May 1993 to collect data on the hydrogeology and ground-water quality beneath Country Pond, in Kingston, New Hampshire. Monitoring wells were installed 4 to 48 feet beneath the pond surface in stratified drift that was up to 40 feet thick. The stratified drift is overlain by up to 35 feet of fine-grained, predominantly organic, lake-bottom sediment. The potentiometric head in the aquifer was at or above the pond surface and up to 0.8 foot above the pond surface at one location. Water-quality analyses detected numerous volatile organic compounds including chloroethane, benzene, dichlorobenzenes, and 1,1-dichloroethane at maximum concentrations of 110, 43, 54, and 92 mg/L, respectively. The maximum concentration of total volatile organic compounds detected in ground water from a monitoring well was 550 mg/L in November 1993. Ground-water samples with high concentrations of volatile organic compounds also had elevated specific conductances indicating the presence of other non-organic contaminants. Water-quality analyses indicate that a plume of contaminated ground water extends at least 300 feet in a northeast direction beneath the pond.

  20. Ground-water quality in the vicinity of landfill sites, southern Franklin County, Ohio

    USGS Publications Warehouse

    De Roche, J.T.; Razem, A.C.

    1981-01-01

    The hydrogeology and ground-water quality in the vicinity of five landfills in southern Franklin County, Ohio, were investigated by use of data obtained from 46 existing wells, 1 seep, 1 surface-water site, and 1 leachate-collection site. Interpretation was based on data from the wells, a potentiometric-surface map, and chemical analyses. Four of the five landfills are in abandoned sand and gravel pits. Pumping of water from a quarry near the landfills has modified the local ground-water flow pattern, increased the hydraulic gradient, and lowered the water table. Ground water unaffected by the landfills is a hard, calcium bicarbonate type with concentrations of dissolved iron and dissolved sulfate as great as 3.0 milligrams per liter and 200 milligrams per liter, respectively. Water sampled from wells downgradient from two landfills shows an increase in sodium, chloride, and other constituents. The change in water quality cannot be traced directly to the landfills, however, because of well location and the presence of other potential sources of contamination. Chemical analysis of leachate from a collection unit at one landfill shows significant amounts of zinc, chromium, copper, and nickel, in addition to high total organic carbon, biochemical oxygen demand, and organic nitrogen. Concentrations of chloride, iron, lead, manganese and phenolic compounds exceed Ohio Environmental Protection Agency Water Quality Standards for drinking water. Water from unaffected wells within the study area have relatively small amounts of these constituents. (USGS)

  1. Hydrochemical characteristics and quality assessment of deep groundwater from the coal-bearing aquifer of the Linhuan coal-mining district, Northern Anhui Province, China.

    PubMed

    Lin, Man-Li; Peng, Wei-Hua; Gui, He-Rong

    2016-04-01

    There is little information available about the hydrochemical characteristics of deep groundwater in the Linhuan coal-mining district, Northern Anhui Province, China. In this study, we report information about the physicochemical parameters, major ions, and heavy metals of 17 groundwater samples that were collected from the coal-bearing aquifer. The results show that the concentrations of total dissolved solids, electrical conductivity, and potassium and sodium (K(+) + Na(+)) in most of the groundwater samples exceeded the guidelines of the World Health Organization (WHO) and the Chinese National Standards for Drinking Water Quality (GB 5749-2006). The groundwater from the coal-bearing aquifer was dominated by the HCO3·Cl-K + Na and HCO3·SO4-K + Na types. Analysis with a Gibbs plot suggested that the major ion chemistry of the groundwater was primarily controlled by weathering of rocks and that the coal-bearing aquifer in the Linhuan coal-mining district was a relatively closed system. K(+) and Na(+) originated from halite and silicate weathering reactions, while Ca(2+) and Mg(2+) originated from the dissolution of calcite, dolomite, and gypsum or anhydrite. Ion exchange reactions also had an influence on the formation of major ions in groundwater. The concentrations of selected heavy metals decreased in the order Mn > Zn > Cr > Cu > Ni > Pb. In general, the heavy metal concentrations were low; however, the Cr, Mn, and Ni concentrations in some of the groundwater samples exceeded the standards outlined by the WHO, the GB 5749-2006, and the Chinese National Standards for Groundwater (GB/T 14848-93). Analysis by various indices (% Na, SAR, and EC), a USSL diagram, and a Wilcox diagram showed that both the salinity and alkalinity of the groundwater were high, such that the groundwater could not be used for irrigating agricultural land without treatment. These results will be significant for water resource exploiting and utilization in

  2. Evaluation of groundwater quality in a rural community in North Central of Nigeria.

    PubMed

    Sojobi, Adebayo Olatunbosun

    2016-03-01

    Evaluation of water quality of nine boreholes and three open hand-dug wells in a rural community in North Central Nigeria revealed relative abundance of cations Na > k > Ca > Mg > Zn > Pb and anions Cl(-) > PO4(2-) > SO4(2-) > NO3(-) in the boreholes and cations Ca > Na > K > Mg > Pb and anions NO3(-)  > PO4(2-)  > SO4(2-) > Cl(-) in the wells. The major contaminants exceeding SON and WHO permissible limits were NO3(-) , Mg, TH, pH and Mg, Pb, TH, pH and DO in the wells and boreholes, respectively. They are attributable to anthropogenic sources such as domestic waste water and poor waste disposal and natural sources such as mineral dissolution from clayey aquifer which made the acidic groundwater unsuitable for consumption unless they are appropriately treated. Correlation studies revealed existence of three major mineral groups in the aquifer Ca-Fe group, Na-Mg group, Zn-K group, as well as a minor group Pb-group, and they determine the chemical composition of the groundwater and the ionic exchange between the groundwater and mineral-bearing clayey aquifer. In order to curb microbial contamination by Enterobacter aerogenes and Escherichia coli, it is recommended that proper latrines and drainages be provided while domesticated animals should be restricted from boreholes and well. Further, treatment with water guard and pur purifier is recommended. PMID:26915740

  3. Development of water quality criteria for diesel fuel No. 2 for remediating contaminated groundwater

    SciTech Connect

    Kangas, M.J.; Proctor, D.M.; Trowbridge, K.R.

    1994-12-31

    Site-specific ambient water quality criteria (AWQC) were developed as benchmarks for back-calculating safe levels of diesel fuel No. 2 as a petroleum mixture in groundwater that could migrate to Fish Creek north of Butler, Indiana. Three types of AWQC were considered relevant according to State-modified US Environmental Protection Agency procedures: An Acute Aquatic Criterion (AAC); A Chronic Aquatic Criterion (CAC); and A Terrestrial Life Cycle Safe Concentration (TLSC). The AAC is the maximum concentration considered protective for aquatic life exposed in the zone of discharge-induced mixing and outside the zone of initial dilution. The remaining criteria applies to all areas of a stream outside the mixing zone. The CAC is intended to protect aquatic life from chronic toxic effects under a four-day average exposure. The TLSC is developed to protect terrestrial organisms that may experience a four-day average exposure to surface water as a result of consumption of aquatic organisms and water from the creek. Scientifically valid toxicological data on the water soluble fraction of diesel fuel and site-specific resident and surrogate species information were used for criterion development. An AAC of 11.4 mg/L was derived as the benchmark for back-calculating a safe level of diesel fuel in groundwater based on modeled groundwater and surface water flow from the spill area to the creek. Uncertainties and limitations of developing benchmark concentrations for mixtures are presented.

  4. Impact of landfill leachate on the groundwater quality: A case study in Egypt.

    PubMed

    Abd El-Salam, Magda M; I Abu-Zuid, Gaber

    2015-07-01

    Alexandria Governorate contracted an international company in the field of municipal solid waste management for the collection, transport and disposal of municipal solid waste. Construction and operation of the sanitary landfill sites were also included in the contract for the safe final disposal of solid waste. To evaluate the environmental impacts associated with solid waste landfilling, leachate and groundwater quality near the landfills were analyzed. The results of physico-chemical analyses of leachate confirmed that its characteristics were highly variable with severe contamination of organics, salts and heavy metals. The BOD5/COD ratio (0.69) indicated that the leachate was biodegradable and un-stabilized. It was also found that groundwater in the vicinity of the landfills did not have severe contamination, although certain parameters exceeded the WHO and EPA limits. These parameters included conductivity, total dissolved solids, chlorides, sulfates, Mn and Fe. The results suggested the need for adjusting factors enhancing anaerobic biodegradation that lead to leachate stabilization in addition to continuous monitoring of the groundwater and leachate treatment processes. PMID:26199748

  5. Impact of landfill leachate on the groundwater quality: A case study in Egypt

    PubMed Central

    Abd El-Salam, Magda M.; I. Abu-Zuid, Gaber

    2014-01-01

    Alexandria Governorate contracted an international company in the field of municipal solid waste management for the collection, transport and disposal of municipal solid waste. Construction and operation of the sanitary landfill sites were also included in the contract for the safe final disposal of solid waste. To evaluate the environmental impacts associated with solid waste landfilling, leachate and groundwater quality near the landfills were analyzed. The results of physico-chemical analyses of leachate confirmed that its characteristics were highly variable with severe contamination of organics, salts and heavy metals. The BOD5/COD ratio (0.69) indicated that the leachate was biodegradable and un-stabilized. It was also found that groundwater in the vicinity of the landfills did not have severe contamination, although certain parameters exceeded the WHO and EPA limits. These parameters included conductivity, total dissolved solids, chlorides, sulfates, Mn and Fe. The results suggested the need for adjusting factors enhancing anaerobic biodegradation that lead to leachate stabilization in addition to continuous monitoring of the groundwater and leachate treatment processes. PMID:26199748

  6. Spatial and temporal trends in groundwater quantity and quality in urban area

    NASA Astrophysics Data System (ADS)

    Fejes, I.; Farsang, A.

    2012-04-01

    Nowadays one of the most important environmental problems in urban areas is groundwater contamination, since it takes effect on all parts of the urban environment. Therefore in this research the groundwater-system of Szeged (SE Hungary) was monitored and the temporal and spatial changes of heavy metals and other inorganic contaminants were examined. Water quantity and quality investigations twenty-eight sampling wells from the groundwater monitoring network of Szeged were carried out. In the course of well selection, we were about to cov