Ponderosa pine growth response to soil strength in the volcanic ash soils of central Oregon.

Treesearch

R.T. Parker; D.A. Maguire; D.D. Marshall; P. Cochran

2007-01-01

Mechanical harvesting and associated logging activities have the capacity to compact soil across large portions of harvest units. Two thinning treatments (felled only versus felled and skidded) in 70- to 80-year-old ponderosa pine stands were replicated at three sites with volcanic soils in central Oregon. Growth in diameter, height, and volume of residual trees were...

Susceptibility of volcanic ash-influenced soil in northern Idaho to mechanical compaction

Treesearch

Deborah S. Page-Dumroese

1993-01-01

Timber harvesting and mechanical site preparation can reduce site productivity if they excessively disturb or compact the soil. Volcanic ash-influenced soils with low undisturbed bulk densities and rock content are particularly susceptible. This study evaluates the effects of harvesting and site preparation on changes in the bulk density of ash-influenced forest soils...

Characteristics of Volcanic Soils in Landslide during the 2016 Kumamoto Earthquake, Japan

NASA Astrophysics Data System (ADS)

Hazarika, H.; Fukuoka, H.; Kokusho, T.; Sumartini, O.; Bhoopendra, D.

2017-12-01

There were many seismic subsidence, debris flows, landslides and slope failures, which occurred in Aso area due to the 2016 Kumamoto earthquake, Japan. This research aims to determine the failure mechanism of many mild slopes, and elucidate the strength characteristics of volcanic soils collected from the sites. A series of undrained static and cyclic triaxial tests, ring shear tests and direct shear tests were performed. Also, for further understanding of volcanic soils' material strength, X-ray powder diffraction analysis (XRD), X-ray fluorescence analysis (XRF), and Scanning electron microscope analysis (SEM) were performed. In this paper, preliminary results of the experimental testing program are discussed.

Volcanism and soil mercury on Mars - Consequences for terrestrial microorganisms

NASA Technical Reports Server (NTRS)

Siegel, B. Z.; Siegel, S. M.

1978-01-01

An earth-Mars depletion formula proposed by Anders and Owen for volatiles is used to calculate a range of putative Hg levels for Martian volcanic soils based upon analyzed samples from Hawaii. The range is about 50-150 microgram per kg. When applied either in conventional or special media (e.g., basalt powder), these levels of Hg are effective inhibitors of the growth of earth microorganisms. Taken together with other hostile chemical and physical factors, volcanic toxicants would appear to provide a further deterrent to the accidental establishment of terrestrial microbiota on Mars.

Cemented Volcanic Soils, Martian Spectra and Implications for the Martian Climate

NASA Technical Reports Server (NTRS)

Bishop, J. L.; Schiffman, P.; Drief, A.; Southard, R. J.

2004-01-01

Cemented soils formed via reactions with salts are studied here and provide information about the climate when they formed. Spectroscopic and microprobe studies have been performed on cemented volcanic crusts in order to learn about the composition of these materials, how they formed, and what they can tell us about climatic interactions with surface material on Mars to form cemented soils. These crusts include carbonate, sulfate and opaline components that may all be present in cemented soil units on Mars.

Impacts of Dust on Tropical Volcanic Soil Formation: Insights from Strontium and Uranium-Series Isotopes in Soils from Basse-Terre Island, French Guadeloupe

NASA Astrophysics Data System (ADS)

Pereyra, Y.; Ma, L.; Sak, P. B.; Gaillardet, J.; Buss, H. L.; Brantley, S. L.

2015-12-01

Dust inputs play an important role in soil formation, especially for thick soils developed on tropical volcanic islands. In these regions, soils are highly depleted due to intensive chemical weathering, and mineral nutrients from dusts have been known to be important in sustaining soil fertility and productivity. Tropical volcanic soils are an ideal system to study the impacts of dust inputs on the ecosystem. Sr and U-series isotopes are excellent tracers to identify sources of materials in an open system if the end-members have distinctive isotope signatures. These two isotope systems are particularly useful to trace the origin of atmospheric inputs into soils and to determine rates and timescales of soil formation. This study analyzes major elemental concentrations, Sr and U-series isotope ratios in highly depleted soils in the tropical volcanic island of Basse-Terre in French Guadeloupe to determine atmospheric input sources and identify key soil formation processes. We focus on three soil profiles (8 to 12 m thick) from the Bras-David, Moustique Petit-Bourg, and Deshaies watersheds; and on the adjacent rivers to these sites. Results have shown a significant depletion of U, Sr, and major elements in the deep profile (12 to 4 m) attributed to rapid chemical weathering. The top soil profiles (4 m to the surface) all show addition of elements such as Ca, Mg, U, and Sr due to atmospheric dust. More importantly, the topsoil profiles have distinct Sr and U-series isotope compositions from the deep soils. Sr and U-series isotope ratios of the top soils and sequential extraction fractions confirm that the sources of the dust are from the Saharan dessert, through long distance transport from Africa to the Caribbean region across the Atlantic Ocean. During the transport, some dust isotope signatures may also have been modified by local volcanic ashes and marine aerosols. Our study highlights that dusts and marine aerosols play important roles in element cycles and

Genesis of petroduric and petrocalcic horizons in Latinamerica volcanic soils

NASA Astrophysics Data System (ADS)

Quantin, Paul

2010-05-01

Introduction. In Latinamerica, from Mexico to Chile, there are indurated volcanic soils horizons, named 'tepetate' in Mexico or cangahua in the Andes Mountains. Apart from original volcanic tuffs, these horizons were produced by pedogenesis: either through a former weathering of volcanic ash layers into fragic and later to petrocalcic horizons; or after a former soil formation through a second process of transformation from clayey volcanic soils to silicified petroduric horizons. This oral presentation will briefly deal with the formation of petroduric horizons in Mexico and petrocalcic horizon in Ecuador. Petroduric horizon genesis in Mexico. A soil climato-toposequence, near to Veracruz (Rossignol & Quantin, 1997), shows downwards an evolution from a ferralic Nitisol to a petroduric Durisol. A Durisol profile comports these successive horizons: at the top A and Eg, then columnar Btg-sim, laminar Bt-sim , prismatic Bsim, plinthite Cg, over andesite lava flow. Among its main features are especially recorded: clay mineralogy, microscopy and HRTEM. These data show: an increase in cristobalite at the expenses of 0.7 nm halloysite in Egsiltans, laminar Bt-sim, around or inside the columns or prisms of Btg-sim and Bsimhorizons. HRTEM (Elsass & al 2000) on ultra thin sections reveals an 'epigenesis' of clay sheets by amorphous silica, to form successively A-opal, Ct-opal and microcrystalline cristobalite. From these data and some groundwater chemical analyses, a scenario of duripan formation from a past clayey Nitisol is inferred: clay eluviation-illuviation process? alternate redoximorphy? clay degradation, Al leaching and Si accumulation, to form successively A-opal, Ct-opal and cristobalite. Petrocalcic horizon genesis in Ecuador. A soil climato-toposequence on pyroclastic flows, near to Bolivar in Ecuador (Quantin & Zebrowski, 1997), shows downwards the evolution from fragic-eutric-vitric Cambisols to petrocalcic-vitric Phaeozems, at the piedmont under semi

Atypical soil hardening during the Tohoku earthquake of March 11, 2011 ( M w = 9.0)

NASA Astrophysics Data System (ADS)

Pavlenko, O. V.

2017-10-01

Based on the records of KiK-net vertical arrays, models of soil behavior down to depths of 100-200 m in the near-fault zones during the Tohoku earthquake are examined. In contrast to the regular pattern observed during strong earthquakes, soft soils have not broadly demonstrated nonlinear behavior, or a reduction (with the onset of strong motions) and recovery (after strong motions finished) of the shear modulus in soil layers. At the stations where anomalously high peak ground accelerations were recorded (PGA > 1g), the values of the shear modulus in soil layers increased with the onset of strong motions and reached a maximum when motions were the most intensive, which indicated hardening of soils. Soil behavior was close to linear, here. The values of the shear moduli decrease along with a decrease in intensity of strong ground motions, and at soft soil stations, this was accompanied by a stepwise decrease in the frequency of motion.

Using Nd and Sr isotopes to trace dust and volcanic inputs to soils on French Guadeloupe Island

NASA Astrophysics Data System (ADS)

Guo, J.; Pereyra, Y.; Ma, L.; Gaillardet, J.; Sak, P. B.; Bouchez, J.

2017-12-01

Soil is at the central part of the Critical Zone for its important roles in sustaining ecosystems and agriculture. At French Guadeloupe, a tropical humid volcanic island, previous studies have shown that the mineral nutrient elements such as K, Na, Ca, and Mg are highly depleted in the surface soil. And mineral nutrients introduced by dusts are an important mineral nutrient source for vegetation growth in this area. It is important to understand and quantify the sources of the mineral dust added to surface soils. Nd isotope ratios, due to their distinct signatures between two unique end-members in soils for this area: the young volcanic areas like Guadeloupe and the dust source region from the old continental shields like Sahara Desert, can be a robust tracer to understand this critical process. Nevertheless, Sr isotope ratios can trace the inputs of marine aerosols. Here we present a new Nd isotope study on Guadeloupe soil depth profiles, combined with previous Sr isotope data, to fingerprint the sources of dust and volcanic inputs into soils. Soil samples from three surface profiles (0 - 1000cm deep) at different locations of the Guadeloupe Island were systematically analyzed. The results show distinct depth variations for Nd isotope signature along profiles. For all profiles, deep soils are relatively consisted with bedrock value (ɛNd: 5.05). But in surface soils (0-600cm), unlike Sr isotope ratios that are significantly modified by marine aerosol input, Nd isotope ratios show similar decrease (to ɛNd:-10) and frequent fluctuations toward the surface, suggesting dust is the dominant source of Nd in these soils. This conclusion is further supported by REE and other trace element data. Thus, with a simplified two end-member model, Sahara dust contributes the Nd percentages in soils varying from 10.7% at the deepest profiles to 69.5% on surface, showing a significant amount of Nd on the surface soil came from dust source. The deep soil profiles are also

Development of Soil Bacterial Communities in Volcanic Ash Microcosms in a Range of Climates.

PubMed

Kerfahi, Dorsaf; Tateno, Ryunosuke; Takahashi, Koichi; Cho, HyunJun; Kim, Hyoki; Adams, Jonathan M

2017-05-01

There is considerable interest in understanding the processes of microbial development in volcanic ash. We tested the predictions that there would be (1) a distinctive bacterial community associated with soil development on volcanic ash, including groups previously implicated in weathering studies; (2) a slower increase in bacterial abundance and soil C and N accumulation in cooler climates; and (3) a distinct communities developing on the same substrate in different climates. We set up an experiment, taking freshly fallen, sterilized volcanic ash from Sakurajima volcano, Japan. Pots of ash were positioned in multiple locations, with mean annual temperature (MAT) ranging from 18.6 to -3 °C. Within 12 months, bacteria were detectable by qPCR in all pots. By 24 months, bacterial copy numbers had increased by 10-100 times relative to a year before. C and N content approximately doubled between 12 and 24 months. HiSeq and MiSeq sequencing of the 16S rRNA gene revealed a distinctive bacterial community, different from developed vegetated soils in the same areas, for example in containing an abundance of unclassified bacterial groups. Community composition also differed between the ash pots at different sites, while showing no pattern in relation to MAT. Contrary to our predictions, the bacterial abundance did not show any relation to MAT. It also did not correlate to pH or N, and only C was statistically significant. It appears that bacterial community development on volcanic ash can be a rapid process not closely sensitive to temperature, involving distinct communities from developed soils.

Volcanic emissions from soils at the base of La Fossa volcano, Vulcano island, Italy

NASA Astrophysics Data System (ADS)

Obenholzner, J. H.; Parks, J. L.

2006-12-01

A top-sealed plastic tube with a diameter of ca. 15 cm had been buried vertically at the base of La Fossa volcano, Volcano island, Italy, next to the front of the obsidian flow. The tube had been filled with quartz wool to condense vapors emanating from the soil. At ca. 75 cm below the surface the sample had been exposed to vapors from Sept. 2005 to April 2006. The leached sample had not been in touch with the ground. Another glass wool cushion (ca. 3 cm thick) had been underneath to minimize capillary effects. Leaching of the quartz wool and ICP-MS analysis documented positive values for: Mg, Al, Si, P, K, Ca, Cr, Mn, Ni, Cu, Zn, Cd, Sn, Pb. Leaching with nitric acid documented also V and Fe. Acid leaching produced higher values for all elements, except K and Sn, than leaching with deionized water. Negative values had been obtained for As, Se, Mo. Influence from soil breathing can be excluded as the active fumaroles contain As and Se. This experiment documents for the first time an unknown element transport by vapors/gases through a volcanic edifice interacting with hydrothermal and magmatic gases. It remains unknown if elements detected are entering the atmosphere or are getting adsorbed onto the volcanic ash soil particles derived from reworked surge beds. This question is very important as soils might be an unknown filter medium to filter volcanically polluted air in case of major volcanic crises. Data can be obtained from the authors.

Volcanic Ash on Slopes of Karymsky

NASA Technical Reports Server (NTRS)

2007-01-01

A volcanic eruption can produce gases, lava, bombs of rock, volcanic ash, or any combination of these elements. Of the volcanic products that linger on the land, most of us think of hardened lava flows, but volcanic ash can also persist on the landscape. One example of that persistence appeared on Siberia's Kamchatka Peninsula in spring 2007. On March 25, 2007, the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) on NASA's Terra satellite captured this image of the area around the Karymsky Volcano. In this image, volcanic ash from earlier eruptions has settled onto the snowy landscape, leaving dark gray swaths. The ash stains are confined to the south of the volcano's summit, one large stain fanning out toward the southwest, and another toward the east. At first glance, the ash stain toward the east appears to form a semicircle north of the volcano and sweep back east. Only part of this dark shape, however, is actually volcanic ash. Near the coast, the darker color may result from thicker vegetation. Similar darker coloring appears to the south. Volcanic ash is not really ash at all, but tiny, jagged bits of rock and glass. These jagged particles pose serious health risks to humans and animals who might inhale them. Likewise, the ash poses hazards to animals eating plants that have been coated with ash. Because wind can carry volcanic ash thousands of kilometers, it poses a more far-reaching hazard than other volcanic ejecta. Substantial amounts of ash can even affect climate by blocking sunlight. Karymsky is a stratovolcano composed of alternating layers of solidified ash, hardened lava, and volcanic rocks. It is one of many active volcanoes on Russia's Kamchatka Peninsula, which is part of the 'Ring of Fire' around the Pacific Rim. NASA image created by Jesse Allen, using data provided courtesy of the NASA/GSFC/MITI/ERSDAC/JAROS, and U.S./Japan ASTER Science Team.

Effect of aggregate structure on VOC gas adsorption onto volcanic ash soil.

PubMed

Hamamoto, Shoichiro; Seki, Katsutoshi; Miyazaki, Tsuyoshi

2009-07-15

The understanding of the gaseous adsorption process and the parameters of volatile organic compounds such as organic solvents or fuels onto soils is very important in the analysis of the transport or fate of these chemicals in soils. Batch adsorption experiments with six different treatments were conducted to determine the adsorption of isohexane, a gaseous aliphatic, onto volcanic ash soil (Tachikawa loam). The measured gas adsorption coefficient for samples of Tachikawa loam used in the first three treatments, Control, AD (aggregate destroyed), and AD-OMR (aggregate destroyed and organic matter removed), implied that the aggregate structure of volcanic ash soil as well as organic matter strongly enhanced gas adsorption under the dry condition, whereas under the wet condition, the aggregate structure played an important role in gas adsorption regardless of the insolubility of isohexane. In the gas adsorption experiments for the last three treatments, soils were sieved in different sizes of mesh and were separated into three different aggregate or particle size fractions (2.0-1.0mm, 1.0-0.5mm, and less than 0.5mm). Tachikawa loam with a larger size fraction showed higher gas adsorption coefficient, suggesting the higher contributions of macroaggregates to isohexane gas adsorption under dry and wet conditions.

Volatile metal deposits on lunar soils: Relation to volcanism

NASA Technical Reports Server (NTRS)

Reed, G. W., Jr.; Allen, R. O., Jr.; Jovanovic, S.

1977-01-01

Parallel leaching and volatilization experiments conducted on lunar samples and similar experiments on sphalerite do not supply the information needed to resolve the question of the chemical nature of pb 204, Zn, Bi and Tl deposits on lunar soil surfaces. It is proposed that in Apollo 17 mare and terra soils and fractions of pb 204, Zn and Tl that are insoluble under mild, hot pH 5HNO3, leaching conditions and involatile at 600 C were originally surface deposits which became immobilized by migration into the silicate substrate or by chemisorption. Only Bi is predominantly indigenous. The implication is also that the soils over their respective times of evolution were exposed to heavy metal vapors or that an episodic exposure occurred after they had evolved. A sequence of events is proposed to account for orange 74220 and black 74001 glasses by lava fountaining and for soil 74241 as tephra from an explosive volcanic eruption.

Volatile metal deposits on lunar soils - Relation to volcanism

NASA Technical Reports Server (NTRS)

Reed, G. W., Jr.; Jovanovic, S.; Allen, R. O., Jr.

1977-01-01

Parallel leaching and volatilization experiments conducted on lunar samples and similar experiments on sphalerite do not supply the information needed to resolve the question of the chemical nature of Pb-204, Zn, Bi, and Tl deposits on lunar soil surfaces. It is proposed that in Apollo 17 mare and terra soils the fractions of Pb-204, Zn, and Tl that are insoluble under mild, hot pH 5 HNO3, leaching conditions and involatile at 600 C were originally surface deposits which became immobilized by migration into the silicate substrate or by chemisorption. Most of the Bi does not seem to be the result of such a deposit. The implication is also that the soils, over their respective times of evolution, were exposed to heavy metal vapors or that an episodic exposure occurred after they had evolved. A sequence of events is proposed to account for orange 74220 and black 74001 glasses by lava fountaining and for soil 74241 as tephra from an explosive volcanic eruption.

Construction procedures using self hardening fly ash

NASA Astrophysics Data System (ADS)

Thornton, S. I.; Parker, D. G.

1980-07-01

Fly ash produced in Arkansas from burning Wyoming low sulfur coal is self-hardening and can be effective as a soil stabilizing agent for clays and sands. The strength of soil-self hardening fly ash develops rapidly when compacted immediately after mixing. Seven day unconfined compressive strengths up to 1800 psi were obtained from 20% fly ash and 80% sand mixtures. A time delay between mixing the fly ash with the soil and compaction of the mixture reduced the strength. With two hours delay, over a third of the strength was lost and with four hours delay, the loss was over half. Gypsum and some commercial concrete retarders were effective in reducing the detrimental effect of delayed compaction. Adequate mixing of the soil and fly ash and rapid compaction of the mixtures were found to be important parameters in field construction of stabilized bases.

Soil gas radon and volcanic activity at El Hierro (Canary Islands) before and after the 2011-2012 submarine eruption

NASA Astrophysics Data System (ADS)

Barrancos, J.; Padilla, G.; Hernandez Perez, P. A.; Padron, E.; Perez, N.; Melian Rodriguez, G.; Nolasco, D.; Dionis, S.; Rodriguez, F.; Calvo, D.; Hernandez, I.

2012-12-01

El Hierro is the youngest and southernmost island of the Canarian archipelago and represents the summit of a volcanic shield elevating from the surrounding seafloor at depth of 4000 m to up to 1501 m above sea level. The island is believed to be near the present hotspot location in the Canaries with the oldest subaerial rocks dated at 1.12 Ma. The subaerial parts of the El Hierro rift zones (NE, NW and S Ridges) are characterized by tightly aligned dyke complexes with clusters of cinder cones as their surface expressions. Since July 16, 2011, an anomalous seismicity at El Hierro Island was recorded by IGN seismic network. Volcanic tremor started at 05:15 hours on October 10, followed on the afternoon of October 12 by a green discolouration of seawater, strong bubbling and degassing indicating the initial stage of submarine volcanic eruption at approximately 2 km off the coast of La Restinga, El Hierro. Soil gas 222Rn and 220Rn activities were continuously measured during the period of the recent volcanic unrest occurred at El Hierro, at two different geochemical stations, HIE02 and HIE03. Significant increases in soil 222Rn activity and 222Rn/220Rn ratio from the soil were observed at both stations prior the submarine eruption off the coast of El Hierro, showing the highest increases before the eruption onset and the occurrence of the strongest seismic event (M=4.6). A statistical analysis showed that the long-term trend of the filtered data corresponded closely to the seismic energy released during the volcanic unrest. The observed increases of 222Rn are related to the rock fracturing processes (seismic activity) and the magmatic CO2 outflow increase, as observed in HIE03 station. Under these results, we find that continuous soil radon studies are important for evaluating the volcanic activity of El Hierro and they demonstrate the potential of applying continuous monitoring of soil radon to improve and optimize the detection of early warning signals of future

A study of the effectiveness of the use of gypsum and volcanic ash against the stability of clay soil in terms of UCT and CBR values

NASA Astrophysics Data System (ADS)

Roesyanto; Iskandar, R.; Hastuty, IP; Lubis, AIU

2018-02-01

Soil stabilization is an effort to improve engineering properties of soil. The conventional soil stabilization is by adding additives to the soil such as Portland cement, lime, and bitumen. The clay stabilization research was done by adding gypsum and volcanic ash. The research purposes were to find out the value of engineering properties of clay due to the addition of 2% gypsum and 2% - 15% volcanic ash. The soil was classified as Clay - Low Plasticity (CL) based on USCS and was classified as A-7-6 (10) based on AASHTO classification system. The UCT values of original soil and original soil plus 2% gypsum were 1.40 kg/cm2 and 1.66 kg/cm2 respectively. The CBR soaked and unsoaked values of original soil were 4.44% and 6.28% correspondingly. Meanwhile, CBR soaked and CBR unsoaked values of original soil plus 2% gypsum were 6.74% and 8.02% respectively. The research results showed that the additives materials of gypsum and volcanic ash improved the engineering properties of clay. The UCT result from the stabilized soil by 2% gypsum and 10% volcanic ash gave value of 2.79 kg/cm2 (increased 99.28% from original soil). For CBR test, the most effective mixture were in variation of 2% gypsum and 9% volcanic ash which gave value of 9.07% (104.27% increase from original soil) for CBR soaked and 10.29% (63.85% increase from original soil) for CBR unsoaked. The stabilized soil with 2% gypsum and 9% volcanic ash was classified as CL based on USCS and was classified as A-6 (4) based on AASHTO classification system.

Chemistry of volcanic soils used for agriculture in Brava Island (Cape Verde)

NASA Astrophysics Data System (ADS)

Prudêncio, Maria Isabel; Marques, Rosa; Waerenborgh, João Carlos; José Vieira, Bruno; Dias, Maria Isabel; Rocha, Fernando

2017-04-01

Brava is a small volcanic island located on the south-western part of the Cape Verde archipelago. It is characterized by an irregular plateau between 300 and 976 m above sea level, which is bounded by steep coastal cliffs and cut by fluvial incision in a generally radial drainage pattern. The major volcano-stratigraphic units of the island are: Lower Unit, Middle Unit, Upper Unit, and Sediments. Although Brava is one of the islands with more frequent rainy periods in Cape Verde, the climate is essentially semi-arid, which associated with the rough topography leads to incipient soils. Detailed Fe speciation and chemical composition studies of Cape Verde soils have shown that oxidation is a major weathering mechanism, and high contents of trace elements may occur originated from imbalance of elements in the volcanic parent materials, which can be a threat to the environmental health. The soils mostly used for agriculture in Brava Island are those developed on phonolitic pyroclasts on the plateau and also on sediments. In this work the whole sample (< 2 mm) and the clay-sized fraction (< 2 µm) of these soils were analysed by Mössbauer spectroscopy and neutron activation analysis, aiming to characterize the iron speciation and to determine the concentration and distribution of 30 chemical elements in Brava soils. Mössbauer spectroscopy shows that Fe is more oxidyzed in topsoils developed on sediments (84-87%) than in soils developed on pyroclasts (71-79%). In the clay sized-fraction of all the studied soils only Fe(III) was detected. Iron oxides clearly distinguish the soils derived from the two types of parent materials, hematite being the only Fe oxide present in soils developed on sediments, while maghemite is more abundant in soils developed on pyroclasts. Iron and chromium are depleted in this fine fraction suggesting their occurrence as iron oxides and ferromagnesian minerals present in coarser particles. Among the chemical elements studied, antimony was found

Mechanisms for retention of bioavailable nitrogen in volcanic rainforest soils

NASA Astrophysics Data System (ADS)

Huygens, Dries; Boeckx, Pascal; Templer, Pamela; Paulino, Leandro; van Cleemput, Oswald; Oyarzún, Carlos; Müller, Christoph; Godoy, Roberto

2008-08-01

Nitrogen cycling is an important aspect of forest ecosystem functioning. Pristine temperate rainforests have been shown to produce large amounts of bioavailable nitrogen, but despite high nitrogen turnover rates, loss of bioavailable nitrogen is minimal in these ecosystems. This tight nitrogen coupling is achieved through fierce competition for bioavailable nitrogen by abiotic processes, soil microbes and plant roots, all of which transfer bioavailable nitrogen to stable nitrogen sinks, such as soil organic matter and above-ground forest vegetation. Here, we use a combination of in situ 15N isotope dilution and 15N tracer techniques in volcanic soils of a temperate evergreen rainforest in southern Chile to further unravel retention mechanisms for bioavailable nitrogen. We find three processes that contribute significantly to nitrogen bioavailability in rainforest soils: heterotrophic nitrate production, nitrate turnover into ammonium and into a pool of dissolved organic nitrogen that is not prone to leaching loss, and finally, the decoupling of dissolved inorganic nitrogen turnover and leaching losses of dissolved organic nitrogen. Identification of these biogeochemical processes helps explain the retention of bioavailable nitrogen in pristine temperate rainforests.

The stratigraphic sequence of Scafati (Italy) - An archive of 10,000 years of volcanism, soil formation and land use in the shade of Mount Vesuvius

NASA Astrophysics Data System (ADS)

Maerker, Michael; Vogel, Sebastian; Hoelzmann, Phillip; Rellini, Ivano

2014-05-01

In this study we carried out a detailed lithostratigraphic, pedological and micromorphological analysis at a stratigraphic sequence close to Scafati, about 3 km east of ancient Pompeii. It consists of a multilayered succession of repeated volcanic deposition and pedogenesis caused by several phases of volcanic activity of Somma-Vesuvius and volcanic quiescence. This comprises, at least, the last 10,000 years of sedimentation history, on one hand, reflecting the entire spectrum of eruption types of Somma-Vesuvius from Plinian, sub-Plinian, rather small eruptions to effusive volcanic events and, on the other hand, soil formations of different durations, intensities and soil-forming environments. Furthermore, the paleosols repeatedly reveal clear evidence of anthropogenic activity by means of agriculture. Hence, a landscape evolution model was developed trying to reconstruct the last 10,000 years of volcanic activity, soil formation and land use in the hinterland of Pompeii.

The structural-functional organization of thermotolerant complexes of actinomycetes in desert and volcanic soils

NASA Astrophysics Data System (ADS)

Zenova, G. M.; Kurapova, A. I.; Lysenko, A. M.; Zvyagintsev, D. G.

2009-05-01

It has been found that the number of thermotolerant actinomycetes in strongly heated soils of deserts and volcanic regions is comparable to or exceeds the number of mesophilic actinomycetes. Among the latter group, streptomyces usually predominate; among thermotolerant actinomycetes, representatives of the Micromonospora, Streptosporangium, Actinomadura, Saccharopolyspora, Microtetraspora, and Microbispora genera are identified. Thermotolerant actinomycetes display the full cycle of their development in these soils. The method of fluorescent in situ hybridization has made it possible to determine that mycelial forms predominate among the metabolically active representatives of Actinobacteria; their portion increases with the rise in the temperature of soil incubation.

Ammonia emissions from urea application to permanent pasture on a volcanic soil

NASA Astrophysics Data System (ADS)

Salazar, F.; Martínez-Lagos, J.; Alfaro, M.; Misselbrook, T.

2012-12-01

Agriculture is the largest source of ammonia (NH3) emission to the atmosphere, deriving mainly from livestock urine and manures, but fertilizer applications to pastures and crops also represent an important source. In Chile, where agriculture and cattle production are important activities (accounting for 4.5% of GDP along with the forestry sector), there are very few published data regarding NH3 emissions from pasture and crop fertilization. This study aimed to provide the first empirical field data for Chile on N losses due to NH3 volatilization following urea application to permanent pasture on a volcanic soil and to assess the influence of environmental conditions on emissions. Four field experiments were carried out on a volcanic acid soil using the micrometeorological integrated horizontal flux (IHF) mass balance method. Measurements were made in winter 2005 and 2007, and spring 2007 and 2008 following urea N fertilization to a permanent pasture at a rate equivalent to 100 kg N ha-1. Cumulative NH3 emissions over the measurement period were 1.4 and 7.7 kg N ha-1 for winter applications, and 12.2 and 26.7 kg N ha-1 for spring dressings. These N losses due to NH3 volatilization are within the range of emissions reported elsewhere. Consideration of urea application timing in Chile, with regards to weather and soil conditions, could have important consequences on minimising potential N losses via volatilization with associated financial benefits to farmers.

Development of a low cost and low power consumption system for monitoring CO_{2} soil concentration in volcanic areas.

NASA Astrophysics Data System (ADS)

Awadallah Estévez, Shadia; Moure-García, David; Torres-González, Pedro; Acosta Sánchez, Leopoldo; Domínguez Cerdeña, Itahiza

2017-04-01

Volatiles dissolved in magma are released as gases when pressure or stress conditions change. H2O, CO2, SO2 and H2S are the most abundant gases involved in volcanic processes. Emission rates are related to changes in the volcanic activity. Therefore, in order to predict possible eruptive events, periodic measurements of CO2 concentrations from the soil should be carried out. In the last years, CO2 monitoring has been widespread for many reasons. A direct relationship between changes in volcanic activity and variations in concentration, diffuse flux and isotope ratios of this gas, have been observed prior to some eruptions or unrest processes. All these factors have pointed out the fact that CO2 emission data are crucial in volcanic monitoring programs. In addition, relevant instrumentation development has also taken place: improved accuracy, cost reduction and portability. Considering this, we propose a low cost and a low power consumption system for measuring CO2 concentration in the soil based on Arduino. Through a perforated pick-axe buried at a certain depth, gas samples are periodically taken with the aid of a piston. These samples are injected through a pneumatic circuit in the spectrometer, which measures the CO2 concentration. Simultaneously, the system records the following meteorological parameters: atmospheric pressure, precipitation, relative humidity and air and soil temperature. These parameters are used to correct their possible influence in the CO2 soil concentration. Data are locally stored (SD card) and transmitted via GPRS or WIFI to a data analysis center.

Wing Dike of Hardened Lava in New Mexico

NASA Image and Video Library

2017-01-25

This photograph from northwestern New Mexico shows a ridge roughly 30 feet about 10 meters tall that formed from lava filling an underground fracture then resisting erosion better than the material around it did. The dike extends from a volcanic peak (out of view here) called Shiprock in English and Tsé Bit'a'í, meaning "rock with wings," in the Navajo language. It offers an Earth analog for some larger hardened-lava walls on Mars http://photojournal.jpl.nasa.gov/catalog/PIA21266

Impacts of forest harvest on active carbon and microbial properties of a volcanic ash cap soil in northern Idaho

Treesearch

Deborah S. Page-Dumroese; Matt D. Busse; Steven T. Overby; Brian D. Gardner; Joanne M. Tirocke

2015-01-01

Soil quality assessments are essential for determining impacts on belowground microbial community structure and function. We evaluated the suitability of active carbon (C), a rapid field test, as an indicator of soil biological quality in five paired forest stands (clear cut harvested 40 years prior and unharvested) growing on volcanic ash-cap soils in northern Idaho....

Geochemical and thermodynamic specificity of volcanic, hydrothermal and soil aerosols

NASA Astrophysics Data System (ADS)

Mukhamadiyarova, Renata V.; Alekhin, Yury V.; Karpov, Gennady A.; Makarova, Marina A.

2010-05-01

On the basis of element composition analyses results (ICP-MS) of hydrothermal and soil aerosols condensates, and also results of diagnostics of ultradisperse phases by means of power dispersive x-ray spectrometers features of phase and microelement composition of issue aerosols are discussed. Our researches of streams of polyelement issue from a soil cover and specificity of structure of volcanic aerosols have led us to a conclusion that is geochemistry area practically is not developed in the relation of microelement migration in lithosphere - atmosphere. Nanoaerosol particles (0,001 - 1 microns) submit to laws of gas dynamics and in fluid streams are steady enough. Experimental researches of polyelement emission streams from soils and low-temperature microelements migration have allowed to detail the reasons of rather high values of the soil issue. Complexity of authentic definition of forms of carrying over, structure and dispersion of particles of the gas phase emitting from a soil cover, is substantially connected with absence of methodically well-founded receptions of selection of water condensates, free from aerosol components, and methods of their reliable division in a stationary stage of processes of issue and condensation. Reception of the information on factors of distribution of metals between pore solutions, true gas complexes and mineral phases of soils, an estimation of a role gas electrophoresis at transition to molecular cluster and to water colloid aerosols (0.1 microns and less) have allowed us to clear up estimations of streams of soil issue. The differentiation of a multicomponent gas phase in near surface conditions at powerful Tolbachinsky eruption (PTE) 1975 - 1976 to formation of many native metals - gold, silver, copper, lead, bismuth, tungsten, numerous intermetallic compounds. In eruption ashes of Kamchatka volcanoes - Karymsky, Bezymyanny, Kljuchevskoy and Shivelutch we found not only iron oxides but also numerous grains of native

Soil CO2 efflux measurement network by means of closed static chambers to monitor volcanic activity at Tenerife, Canary Islands

NASA Astrophysics Data System (ADS)

Amonte, Cecilia; García-Merino, Marta; Asensio-Ramos, María; Melián, Gladys; García-Hernández, Rubén; Pérez, Aaron; Hernández, Pedro A.; Pérez, Nemesio M.

2017-04-01

Tenerife (2304 km2) is the largest of the Canary Islands and has developed a central volcanic complex (Cañadas edifice), that started to grow about 3.5 My ago. Coeval with the construction of the Cañadas edifice, shield basaltic volcanism continued until the present along three rift zones oriented NW-SE, NE-SW and NS (hereinafter referred as NW, NE and NS respectively). Main volcanic historical activity has occurred along de NW and NE rift-zones, although summit cone of Teide volcano, in central volcanic complex, is the only area of the island where surface geothermal manifestations are visible. Uprising of deep-seated gases occurs along the aforementioned volcanic structures causing diffuse emissions at the surface environment of the rift-zones. In the last 20 years, there has been considerable interest in the study of diffuse degassing as a powerful tool in volcano monitoring programs. Diffuse degassing studies are even more important volcanic surveillance tool at those volcanic areas where visible manifestations of volcanic gases are absent. Historically, soil gas and diffuse degassing surveys in volcanic environments have focused mainly on CO2 because it is, after water vapor, the most abundant gas dissolved in magma. One of the most popular methods used to determine CO2 fluxes in soil sciences is based on the absorption of CO2 through an alkaline medium, in its solid or liquid form, followed by gravimetric, conductivity, or titration analyses. In the summer of 2016, a network of 31 closed static chambers was installed, covering the three main structural zones of Tenerife (NE, NW and NS) as well as Cañadas Caldera with volcanic surveillance porpoises. 50 cc of 0.1N KOH solution is placed inside the chamber to absorb the CO2 released from the soil. The solution is replaced weekly and the trapped CO2 is then analyzed at the laboratory by titration. The are expressed as weekly integrated CO2 efflux values. The CO2 efflux values ranged from 3.2 to 12.9 gṡm-2�

Soil gas 222Rn and volcanic activity at El Hierro (Canary Islands) before and after the 2011 submarine eruption

NASA Astrophysics Data System (ADS)

Padilla, G.; Hernández, P. A.; Padrón, E.; Barrancos, J.; Melián, G.; Dionis, S.; Rodríguez, F.; Nolasco, D.; Calvo, D.; Hernández, I.; Pereza, M. D.; Pérez, N. M.

2012-04-01

El Hierro (278 km2) is the southwesternmost island of the Canarian archipelago. From June 19, 2011 to January 2012, more than 11,950 seismic events have been detected by the seismic network of IGN. On 10 October 2011 the earthquake swarm changed its behaviour and produced a harmonic tremor due to magma movement, indicating that a submarine eruption located at 2 km south of La Restinga had started which is still in progress. Since 2003, the ITER Environmental Research Division now integrated in the Instituto Volcanológico de Canarias, INVOLCAN, has regularly performed soil gas surveys at El Hierro as a geochemical tool for volcanic surveillance. Among the investigated gases, soil gas radon (222Rn) and thoron (220Rn) have played a special attention. Both gases are characterized to ascend towards the surface mainly through cracks or faults via diffusion or advection, mechanisms dependent of both soil porosity and permeability, which in turn vary as a function of the stress/strain changes at depth. Years before the starts of the volcanic-seismic crisis on July 17, 2011, a volcanic multidisciplinary surveillance program was implemented at El Hierro including discrete and continuous measurements of 222Rn and 220Rn. Two soil gas 222Rn surveys had been carried out at El Hierro in 2003 and 2011, and four continuous geochemical monitoring stations for 222Rn and 220Rn measurements had been installed (HIE02, HIE03, HIE04 and HIE08). Soil gas 222Rn surveys were carried out at the surface environment of El Hierro after selecting 600 sampling observation sites (about 40 cm depth). Geochemical stations measure 222Rn and 220Rn activities by pumping the gas from a PVC pipe inserted 1m in the ground and thermally isolated. The results of the 2003 and 2011 soil gas 222Rn surveys show clearly a relatively higher observed 222Rn activities in the surface environment on 2011 than those observed on 2003 when no anomalous seismicity were taking place beneath El Hierro. The observed

Irrigation model of bleached Kraft mill wastewater through volcanic soil as a pollutants attenuation process.

PubMed

Navia, R; Inostroza, X; Diez, M C; Lorber, K E

2006-05-01

An irrigation process through volcanic soil columns was evaluated for bleached Kraft mill effluent pollutants retention. The system was designed to remove color and phenolic compounds and a simple kinetic model for determining the global mass transfer coefficient and the adsorption rate constant was used. The results clearly indicate that the global mass transfer coefficient values (K(c)a) and the adsorption rate constants are higher for the irrigation processes onto acidified soil. This means that the pretreatment of washing the volcanic soil with an acid solution has a positive effect on the adsorption rate for both pollutant groups. The enhanced adsorption capacity is partially explained by the activation of the metal oxides present in the soil matrix during the acid washing process. Increasing the flow rate from 1.5 to 2.5 ml/min yielded higher (K(c)a) values and adsorption rate constants for both pollutant groups. For instance, regarding color adsorption onto acidified soil, there is an increment of 43% in the (K(c)a) value for the experiment with a flow rate of 2.5 ml/min. Increasing the porosity of the column from 0.55 to 0.59, yielded a decrease in the (K(c)a) values for color and phenolic compounds adsorption processes. Onto natural soil for example, these decreases reached 21% and 24%, respectively. Therefore, the (K(c)a) value is dependent on both the liquid-phase velocity (external resistance) and the soil fraction in the column (internal resistance); making forced convection and diffusion to be the main transport mechanisms involved in the adsorption process. Analyzing the adsorption rate constants (K(c)a)/m, phenolic compounds and color adsorption rates onto acidified soil of 2.25 x 10(-6) and 2.62 x 10(-6) l/mg min were achieved for experiment 1. These adsorption rates are comparable with other adsorption systems and adsorbent materials.

May humic acids or mineral fertilisation mitigate arsenic mobility and availability to carrot plants (Daucus carota L.) in a volcanic soil polluted by As from irrigation water?

PubMed

Caporale, Antonio G; Adamo, Paola; Azam, Shah M G G; Rao, Maria A; Pigna, Massimo

2018-02-01

Carrot (Daucus carota L.) is a widely consumed root vegetable, whose growth and safety might be threatened by growing-medium arsenic (As) contamination. By this work, we evaluated the effects of humic acids from Leonardite and NPK mineral fertilisation on As mobility and availability to carrot plants grown for 60 days in a volcanic soil irrigated with As-contaminated water - representing the most common scenario occurring in As-affected Italian areas. As expected, the irrigation with As-contaminated water caused a serious toxic effect on plant growth and photosynthetic rate; the highest rate of As also inhibited soil enzymatic activity. In contrast, the organic and mineral fertilisation alleviated, at least partially, the toxicity of As, essentially by stimulating plant growth and promoting nutrient uptake. The mobility of As in the volcanic soil and thus its phytoavailability were differently affected by the organic and mineral fertilisers; the application of humic acids mitigated the availability of the contaminant, likely by its partial immobilisation on humic acid sorption sites - thus raising up the intrinsic anionic sorption capacity of the volcanic soil; the mineral fertilisation enhanced the mobility of As in soil, probably due to competition of P for the anionic sorption sites of the soil variable-charge minerals, very affine to available P. These findings hence suggest that a proper soil management of As-polluted volcanic soils and amendment by stable organic matter might mitigate the environmental risk of these soils, thus minimising the availability of As to biota. Copyright © 2017 Elsevier Ltd. All rights reserved.

Soil microbial structure and function post-volcanic eruption on Kasatochi Island and regional controls on microbial heterogeneity

NASA Astrophysics Data System (ADS)

Zeglin, L. H.; Rainey, F.; Wang, B.; Waythomas, C.; Talbot, S. L.

2013-12-01

Microorganisms are abundant and diverse in soil and their integrated activity drives nutrient cycling on the ecosystem scale. Organic matter (OM) inputs from plant production support microbial heterotrophic life, and soil geochemistry constrains microbial activity and diversity. As vegetation and soil develops over time, these factors change, modifying the controls on microbial heterogeneity. Following a volcanic eruption, ash deposition creates new surfaces where both organismal growth and weathering processes are effectively reset. The trajectory of microbial community development following this disturbance depends on both organic matter accumulation and geochemical constraints. Also, dispersal of microbial cells to the sterile ash surface may determine microbial community succession. The Aleutian Islands (Alaska, USA) are a dynamic volcanic region, with active and dormant volcanoes distributed across the volcanic arc. One of these volcanoes, Kasatochi, erupted violently in August 2008, burying a small lush island in pryoclastic flows and fine ash. Since, plants and birds are beginning to re-establish on developing surfaces, including legacy soils exposed by rapid erosion of pyroclastic deposits, suggesting that recovery of microbial life is also proceeding. However, soil microbial diversity and function has not been examined on Kasatochi Island or across the greater Aleutian region. The project goal is to address these questions: How is soil microbial community structure and function developing following the Kasatochi eruption? What is the relative importance of dispersal, soil OM and geochemistry to microbial community heterogeneity across the Aleutians? Surface mineral soil (20-cm depth) samples were collected from Kasatochi Island in summer 2013, five years after the 2008 eruption, and from eight additional Aleutian islands. On Kasatochi, pryoclastic deposits, exposed legacy soils supporting regrowth of remnant dune wild-rye (Leymus mollis) and mesic meadow

Influence of management practices on C stabilization pathways in agricultural volcanic ash soils (Canary Islands, Spain)

NASA Astrophysics Data System (ADS)

Hernandez, Zulimar; María Álvarez, Ana; Carral, Pilar; de Figueiredo, Tomas; Almendros, Gonzalo

2014-05-01

Although C stabilization mechanisms in agricultural soils are still controversial [1], a series of overlapped pathways has been suggested [2] such as: i) insolubilization of low molecular weight precursors of soil organic matter (SOM) with reactive minerals through physical and chemical bonding, ii) selective accumulation of biosynthetic substances which are recalcitrant because of its inherent chemical composition, and iii) preservation and furter diagenetic transformation of particulate SOM entrapped within resistant microaggregates, where diffusion of soil enzymes is largely hampered. In some environments where carbohydrate and N compounds are not readily biodegraded, e.g., with water saturated micropores, an ill-known C stabilization pathway may involve the formation of Maillard's reaction products [3]. In all cases, these pathways converge in the formation of recalcitrant macromolecular substances, sharing several properties with the humic acid (HA) fraction [4]. In template forests, the selective preservation and further microbial reworking of plant biomass has been identified as a prevailing mechanism in the accumulation of recalcitrant SOM forms [5]. However, in volcanic ash soils with intense organomineral interactions, condensation reactions of low molecular weight precursors with short-range minerals may be the main mechanism [6]. In order to shed some light about the effect of agricultural management on soil C stabilization processes on volcanic ash soils, the chemical composition of HA and some structural proxies of SOM informing on its origin and potential resistance to biodegradation, were examined in 30 soils from Canary Islands (Spain) by visible, infrared (IR) and 13C nuclear magnetic resonance (NMR) spectroscopies, elementary analysis and pyrolytic techniques. The results of multivariate treatments, suggested at least three simultaneous C stabilization biogeochemical trends: i) diagenetic alteration of plant biomacromolecules in soils receiving

Spatial variability in depth and landscape of heavy metal contents of volcanic soils of the National Cajas Park in the Azuay Andes (Ecuador)

NASA Astrophysics Data System (ADS)

Bech, Jaume; Roca, Núria; Boluda, Rafael; Gil, Carlos; Ramos-Miras, Joaquín; Rodríguez, Jose A.

2015-04-01

Although the soils in the Azuay Andes are thought to be generally non-contaminated, it is necessary to preserve them from anthropogenic pollution. This area supplies drinking water to Cuenca, the third city of Ecuador. At present, very little information is available on baseline metal concentrations in Latin American soils. Therefore, it is important to establish the baseline of elements in soils as reference values for evaluating potential changes in their concentrations and to be able to define their origins. The objectives of this study are: (1) to show morphological, physical and chemical characteristics of Andisols in the Azuay Andes (Ecuador); (2) to determine the concentrations of six heavy metals (Cd, Cr, Cu, Ni, Pb and Zn) and (3) to evaluate the relationship between metal concentration and soil properties. The study area is located in National Cajas Park in the Paramo area of the Andes at Azuay Province (Ecuador). The geological origin of the National Cajas Park dates back to the Quaternary age. This area is a U-shaped glaciated valley formed over a pre-existing volcanic basement which consists of rhyolite and andesite volcanic tuff. The moraines are covered by discontinuous patches of volcanic ash. The climate is characterized by rather high rainfall, between 1200 to 2000 mm per year, regularly distributed and generally of a low intensity with a yearly average constant temperature (7°C) with high diurnal amplitudes. The paramo is a high altitude neotropical grassland ecosystem, located between the continuous forest border (~3500 m) and the eternal snow line (~5000 m). Seven representative volcanic soil pedons of a toposequence were studied and sampled. All horizons were analysed for physical and chemical properties by standard and specific methods for volcanic soils. Total metal concentrations in soil horizons were determined by ICP-MS spectrometer. The background values were calculated using the 4σ-outlier test. This requires the elimination of

The interaction between parent material, climate and volcanism as the major soil forming factor in the Ecuadorian high Andes region

NASA Astrophysics Data System (ADS)

Buytaert, W.; Duyck, H.; Dercon, G.; Deckers, J.; Wyseure, G.

2003-04-01

The high Andes region of Ecuador and Colombia (>3500m a.s.l.) is covered by the so-called páramo ecosystem, characterised by a cold climate, a typical grass or small shrub vegetation and volcanic soils. Soil profiles of the paramo in the Austro Ecuatoriano, South Ecuador, were studied in order to reveal genetic relationships with geology, volcanic ash deposits, climate and land use. A gradual diminuation of Andic properties was found, related to the distance of the pedon to the active volcanoes of the Northern Volcanic Zone of the Andes. Pedons in the north of the region, closer to these volcanoes (Sangay, Tungurahua) are classified as non-allophanic Histic Andosols. The influence of the vicinity of the volcanoes leads to a higher oxalate extractable aluminium and iron. The genesis of the Andosols seems to be strongly related to the presence and thickness of volcanic ash depositions. The limit of these depositions is situated south of the city of Cuenca. Pedons further to the south are classified as Histosols. However, they also have clear Andic properties. Several differences in chemical properties between the Western and Eastern cordilleras where found, that are most probable related with a difference in mother material, and maybe also a different climatic regime. Correlation of the chemical properties with land use reveals that no chemical differences can be found that are invoked by occupying natural Andosols for agricultural purposes, within the first five years of cultivation. At last, the conclusions were used to revisit the World Reference Base for Soil Resources in order to sharpen up differenciation between Andosols and Histosols.

Iron and aluminum solid phase dynamics and carbon storage across a water balance gradient in volcanic soils

NASA Astrophysics Data System (ADS)

Bateman, J. B.; Fendorf, S. E.; Vitousek, P.

2017-12-01

Iron (Fe) and Aluminum (Al) are major components of volcanic soils, and strongly influence the stability of soil carbon (C). The stability of Fe and Al phases is dictated by the redox conditions and pH of soils, respectively. The water balance of a soil, defined as annual precipitation minus evapotranspiration, ultimately controls pH and redox conditions. Consequently, we hypothesize that water balance influences Fe/Al solid phase dynamics in volcanic soils when the climatic regime has persisted on timescales of 20 ky. To test this hypothesis, we collected soils from a naturally occurring water balance gradient on the windward side of Mauna Kea Volcano in Hawaii, across which water balance ranges from -1270 mm/y to +2000 mm/y. Sampling included complete soil profiles, and 30 cm surface soil samples. We determined the solid phases of Fe/Al with selective extractions and total C via combustion. Extracted Fe/Al were then partitioned into operational pools: organically bound, amorphous, crystalline, primary mineral, primary glass, and residual. All soils in the study were acidic, with pH between 3.4 and 6.4. Soil C varied considerably across the gradient, from <1% C to >15% C by weight. Across sites, soil pH, Fe in primary minerals and glasses, and residual Al are negatively correlated with water balance, while soil C, organic Fe and Al, and crystalline Fe correlated positively with water balance. Organically bound Al increases linearly with water balance, while organically bound Fe is uncorrelated with water balance in soils where water balance is negative and is positively correlated with water balance in wetter sites. These results show that soils developing from the same parent material, though under different water balance regimes, range from lightly weathered ash deposits with little C accumulation in the driest regions, to heavily weathered soils composed of crystalline Fe, organic matter, and organically bound Fe/Al in the wettest regions. Al appears to be the

The Natural Terrestrial Carbon Sequestration Potential of Rocky Mountain Soils Derived From Volcanic Bedrock

NASA Astrophysics Data System (ADS)

Yager, D. B.; Burchell, A.; Johnson, R. H.

2008-12-01

The possible economic and environmental ramifications of climate change have stimulated a range of atmospheric carbon mitigation actions, as well as, studies to understand and quantify potential carbon sinks. However, current carbon management strategies for reducing atmospheric emissions underestimate a critical component. Soils represent between 18 - 30% of the terrestrial carbon sink needed to prevent atmospheric doubling of CO2 by 2050 and a crucial element in mitigating climate change, natural terrestrial sequestration (NTS), is required. NTS includes all naturally occurring, cumulative, biologic and geologic processes that either remove CO2 from the atmosphere or prevent net CO2 emissions through photosynthesis and microbial fixation, soil formation, weathering and adsorption or chemical reactions involving principally alumino- ferromagnesium minerals, volcanic glass and clays. Additionally, NTS supports ecosystem services by improving soil productivity, moisture retention, water purification and reducing erosion. Thus, 'global climate triage' must include the protection of high NTS areas, purposeful enhancement of NTS processes and reclamation of disturbed and mined lands. To better understand NTS, we analyzed soil-cores from Colorado, Rocky Mountain Cordillera sites. North-facing, high-plains to alpine sites in non-wetland environments were selected to represent temperate soils that may be less susceptible to carbon pool declines due to global warming than soils in warmer regions. Undisturbed soils sampled have 2 to 6 times greater total organic soil carbon (TOSC) than global TOSC averages (4 - 5 Wt. %). Forest soils derived from weathering of intermediate to mafic volcanic bedrock have the highest C (34.15 Wt. %), C:N (43) and arylsulfatase (ave. 278, high 461 μg p-nitrophenol/g/h). Intermediate TOSC was identified in soils derived from Cretaceous shale (7.2 Wt. %) and Precambrian, felsic gneiss (6.2 Wt. %). Unreclaimed mine-sites have the lowest C (0

Relations among soil radon, environmental parameters, volcanic and seismic events at Mt. Etna (Italy)

NASA Astrophysics Data System (ADS)

Giammanco, S.; Ferrera, E.; Cannata, A.; Montalto, P.; Neri, M.

2013-12-01

From November 2009 to April 2011 soil radon activity was continuously monitored using a Barasol probe located on the upper NE flank of Mt. Etna volcano (Italy), close both to the Piano Provenzana fault and to the NE-Rift. Seismic, volcanological and radon data were analysed together with data on environmental parameters, such as air and soil temperature, barometric pressure, snow and rain fall. In order to find possible correlations among the above parameters, and hence to reveal possible anomalous trends in the radon time-series, we used different statistical methods: i) multivariate linear regression; ii) cross-correlation; iii) coherence analysis through wavelet transform. Multivariate regression indicated a modest influence on soil radon from environmental parameters (R2 = 0.31). When using 100-day time windows, the R2 values showed wide variations in time, reaching their maxima (~0.63-0.66) during summer. Cross-correlation analysis over 100-day moving averages showed that, similar to multivariate linear regression analysis, the summer period was characterised by the best correlation between radon data and environmental parameters. Lastly, the wavelet coherence analysis allowed a multi-resolution coherence analysis of the time series acquired. This approach allowed to study the relations among different signals either in the time or in the frequency domain. It confirmed the results of the previous methods, but also allowed to recognize correlations between radon and environmental parameters at different observation scales (e.g., radon activity changed during strong precipitations, but also during anomalous variations of soil temperature uncorrelated with seasonal fluctuations). Using the above analysis, two periods were recognized when radon variations were significantly correlated with marked soil temperature changes and also with local seismic or volcanic activity. This allowed to produce two different physical models of soil gas transport that explain the

Controls on carbon storage and weathering in volcanic ash soils across a climate gradient on Mauna Kea, Hawaii

NASA Astrophysics Data System (ADS)

Kramer, M. G.; Chadwick, O.

2017-12-01

Volcanic ash soils retain the largest and most persistent soil carbon pools of any ecosystem. However, the mechanisms governing soil carbon accumulation and weathering during initial phases of weathering are not well understood. We examined soil organic matter dynamics and weathering across a high altitude (3563 - 3013 m) 20 ky climate gradient on Mauna Kea in Hawaii. Four elevation sites were selected ( 250-500 mm rainfall) which range from arid-periglacial to sites which contain a mix of shrubs and grasses. At each site, between 2-3 pits were dug and major diagnostic horizons down to bedrock (in-tact lava) were sampled. Soils were analyzed for particle size, organic C and N, soil pH, exchangeable cations, base saturation, NaF pH, phosphorous sorption and bulk elements. Mass loss and pedogenic metal accumulation (hydroxlamine Fe, Al and Si extractions) were used to measure extent of weathering, leaching, changes in soil mineralogy and carbon accumulation with the short-range-ordered (SRO) minerals. Reactive-phase (SRO) minerals show a general trend of increasing abundance through the soil depth profile with increasing rainfall. However carbon accumulation patterns across the climate gradient are largely decoupled from these trends. The results suggest that after 20ky, pedogenic processes have altered the nature and composition of the volcanic ash such that it is capable of retaining soil C even where organic acid influences from plant material and leaching from rainfall is severely limited. Comparisons with lower elevation soils on Mauna Kea and other moist mesic (2500mm rainfall) sites on Hawaii suggest that these soils have reached only between 1-15 % of their capacity to retain carbon. Our results suggest that in low rainfall and a cold climate, after 20ky, weathering has advanced but is decoupled from soil carbon accumulation patterns and the associated influence of vegetation on soil development. Changes in soil carbon composition and amount across the entire

Ecosystem respiration, vegetation development and soil nitrogen in relation to breeding density of seagulls on a pristine volcanic island, Surtsey, Iceland

NASA Astrophysics Data System (ADS)

Sigurdsson, B. D.; Magnusson, B.

2009-08-01

Since its birth in 1963 by volcanic eruption in the North Atlantic Ocean off Iceland, Surtsey has been a unique natural laboratory on how organisms colonize volcanic islands and form ecosystems with contrasting structure and function. In July, 2004, ecosystem respiration rate, soil properties and surface cover of vascular plants were measured on 21 plots distributed among the main plant communities found 40 years after the primary succession started. The plots could be divided into two groups, inside and outside seagull (Larus sp.) colonies found on the island. Vegetation cover of the plots was strongly related to the density of seagull nests within and around them. The occurrence of seagull nests and increased vegetation also coincided with significant increase in ecosystem respiration, soil carbon and nitrogen, and with significantly lower soil pH and soil temperatures. The ecosystem respiration was high inside the gull colonies, similar to the highest fluxes measured in drained wetlands or agricultural fields in Iceland. The most important factor for vegetation succession and ecosystem function on Surtsey seems to be the amount of nitrogen, which was mainly brought in by the seagulls.

Steels with controlled hardenability for induction hardening

NASA Astrophysics Data System (ADS)

Shepelyakovskii, K. Z.

1980-07-01

Steels of the CH and LH type developed in the Soviet Union permit the use of a new method of induction hardening — bulk-surface hardening — and efficient utilization of the high-strength conditions (σb = 230-250 kgf/mm2). These steels make it possible to improve the structural strength, operating characteristics, service life, and reliability of critical heavily loaded machine parts. At the same time, CH steels make it possible to reduce by a factor of 2-3 the quantity of alloying elements, reduce the electrical energy for heat treatment, and completely exclude the cost of quenching oil for heat treatment in automatic equipment with high labor productivity, while retaining good working conditions. All this leads to substantial savings in production and operation. For example, when transmission gears (cylindrical and conical) are manufactured from LH steels the annual savings amount to more than 700,000 rubles at two automobile plants. Machine parts of CH steels — half axles and bearings in railway cars —have saved respectively six and four million rubles annually. The introduction of controlled-hardenability steels for induction hardening is a necessary condition for technological progress in machine construction and metallurgy.

Controls on carbon storage and weathering in volcanic soils across a high-elevation climate gradient on Mauna Kea, Hawaii.

PubMed

Kramer, Marc G; Chadwick, Oliver A

2016-09-01

Volcanic ash soils retain the largest and most persistent soil carbon pools of any ecosystem. However, the mechanisms governing soil carbon accumulation and weathering during initial phases of ecosystem development are not well understood. We examined soil organic matter dynamics and soil development across a high-altitude (3,560-3,030 m) 20-kyr climate gradient on Mauna Kea in Hawaii. Four elevation sites were selected (~250-500 mm rainfall), which range from sparsely vegetated to sites that contain a mix of shrubs and grasses. At each site, two or three pits were dug and major diagnostic horizons down to bedrock (intact lava) were sampled. Soils were analyzed for particle size, organic C and N, soil pH, exchangeable cations, base saturation, NaF pH, phosphorous sorption, and major elements. Mass loss and pedogenic metal accumulation (hydroxlamine Fe, Al, and Si extractions) were used to measure extent of weathering, leaching, changes in soil mineralogy and carbon accumulation. Reactive-phase (SRO) minerals show a general trend of increasing abundance with increasing rainfall. However carbon accumulation patterns across the climate gradient are largely decoupled from these trends. The results suggest that after 20 kyr, pedogenic processes have altered the nature and composition of the volcanic ash such that it is capable of retaining soil C even where organic acid influences from plant material and leaching from rainfall are severely limited. Carbon storage comparisons with lower-elevation soils on Mauna Kea and other moist mesic (2,500 mm rainfall) sites on Hawaii suggest that these soils have reached only between 1% and 15% of their capacity to retain carbon. Our results suggest that, after 20 kyr in low rainfall and a cold climate, weathering was decoupled from soil carbon accumulation patterns and the associated influence of vegetation on soil development. Overall, we conclude that the rate of carbon supply to the subsoil (driven by coupling of rainfall

Influence of Cooling Condition on the Performance of Grinding Hardened Layer in Grind-hardening

NASA Astrophysics Data System (ADS)

Wang, G. C.; Chen, J.; Xu, G. Y.; Li, X.

2018-02-01

45# steel was grinded and hardened on a surface grinding machine to study the effect of three different cooling media, including emulsion, dry air and liquid nitrogen, on the microstructure and properties of the hardened layer. The results show that the microstructure of material surface hardened with emulsion is pearlite and no hardened layer. The surface roughness is small and the residual stress is compressive stress. With cooling condition of liquid nitrogen and dry air, the specimen surface are hardened, the organization is martensite, the surface roughness is also not changed, but high hardness of hardened layer and surface compressive stress were obtained when grinding using liquid nitrogen. The deeper hardened layer grinded with dry air was obtained and surface residual stress is tensile stress. This study provides an experimental basis for choosing the appropriate cooling mode to effectively control the performance of grinding hardened layer.

Effect of long-term different fertilization on bacterial community structures and diversity in citrus orchard soil of volcanic ash.

PubMed

Joa, Jae Ho; Weon, Hang Yeon; Hyun, Hae Nam; Jeun, Young Chull; Koh, Sang Wook

2014-12-01

This study was conducted to assess bacterial species richness, diversity and community distribution according to different fertilization regimes for 16 years in citrus orchard soil of volcanic ash. Soil samples were collected and analyzed from Compost (cattle manure, 2,000 kg/10a), 1/2 NPK+compost (14-20-14+2,000 kg/10a), NPK+compost (28-40-28+2,000 kg/10a), NPK (28-40-28 kg/10a), 3 NPK (84-120-84 kg/10a), and Control (no fertilization) plot which have been managed in the same manners with compost and different amount of chemical fertilization. The range of pyrosequencing reads and OTUs were 4,687-7,330 and 1,790-3,695, respectively. Species richness estimates such as Ace, Chao1, and Shannon index were higher in 1/2 NPK+compost than other treatments, which were 15,202, 9,112, 7.7, respectively. Dominant bacterial groups at level of phylum were Proteobacteria, Acidobacteria, and Actinobacteria. Those were occupied at 70.9% in 1/2 NPK+compost. Dominant bacterial groups at level of genus were Pseudolabrys, Bradyrhizobium, and Acidobacteria. Those were distributed at 14.4% of a total of bacteria in Compost. Soil pH displayed significantly closely related to bacterial species richness estimates such as Ace, Chao1 (p<0.05) and Shannon index (p<0.01). However, it showed the negative correlation with exchangeable aluminum contents (p<0.05). In conclusion, diversity of bacterial community in citrus orchard soil was affected by fertilization management, soil pH changes and characteristics of volcanic ash.

Tellurium in active volcanic environments: Preliminary results

NASA Astrophysics Data System (ADS)

Milazzo, Silvia; Calabrese, Sergio; D'Alessandro, Walter; Brusca, Lorenzo; Bellomo, Sergio; Parello, Francesco

2014-05-01

Tellurium is a toxic metalloid and, according to the Goldschmidt classification, a chalcophile element. In the last years its commercial importance has considerably increased because of its wide use in solar cells, thermoelectric and electronic devices of the last generation. Despite such large use, scientific knowledge about volcanogenic tellurium is very poor. Few previous authors report result of tellurium concentrations in volcanic plume, among with other trace metals. They recognize this element as volatile, concluding that volcanic gases and sulfur deposits are usually enriched with tellurium. Here, we present some results on tellurium concentrations in volcanic emissions (plume, fumaroles, ash leachates) and in environmental matrices (soils and plants) affected by volcanic emissions and/or deposition. Samples were collected at Etna and Vulcano (Italy), Turrialba (Costa Rica), Miyakejima, Aso, Asama (Japan), Mutnovsky (Kamchatka) at the crater rims by using common filtration techniques for aerosols (polytetrafluoroethylene filters). Filters were both eluted with Millipore water and acid microwave digested, and analyzed by inductively coupled plasma mass spectrometry (ICP-MS). Volcanic ashes emitted during explosive events on Etna and Copahue (Argentina) were analyzed for tellurium bulk composition and after leaching experiments to evaluate the soluble fraction of tellurium. Soils and leaves of vegetation were also sampled close to active volcanic vents (Etna, Vulcano, Nisyros, Nyiragongo, Turrialba, Gorely and Masaya) and investigated for tellurium contents. Preliminary results showed very high enrichments of tellurium in volcanic emissions comparing with other volatile elements like mercury, arsenic, thallium and bismuth. This suggests a primary transport in the volatile phase, probably in gaseous form (as also suggested by recent studies) and/or as soluble salts (halides and/or sulfates) adsorbed on the surface of particulate particles and ashes. First

Payún Volcanic Field

NASA Image and Video Library

2013-01-04

Situated in the southern Andes Mountains, the Payún volcanic field of Argentina is a complex landscape that formed over hundreds of thousands of years. Sprawling over 5,200 square kilometers (2,000 square miles), Payún is a massive shield volcano—a broad formation resembling an ancient warrior shield. This false-color image is a composite of observations acquired on February 7 and March 20, 2001 by the Enhanced Thematic Mapper Plus on the Landsat 7 satellite. It was made from a combination of visible and infrared light, where green indicates vegetation, black indicates lava flows, and orange is bare rock rich in iron oxides. Part of the back-arc volcanism of the Andes, Payún lies about 530 kilometers (330 miles) east from where the Nazca plate subducts below the South America plate. Not surprisingly, a volcanic zone extends over some 1,000 kilometers (600 miles) north-to-south in this region. According to a study published in 2010, the regional geology and chemical composition of the rocks indicate that the volcanic field likely formed within the past 300,000 years. The dominant feature of the volcanic field is Payún Matru, an elliptical caldera measuring roughly 9 by 7 kilometers (6 by 4 miles). Geologists surmise that the caldera formed after the old magma chamber emptied and the summit collapsed. Southwest of the caldera is a stratovolcano composed of alternating layers of compacted ash, hardened lava, and rocks ejected during previous eruptions. This stratovolcano, Payún, rises to 3,680 meters (12,073 feet) above sea level. (The entire volcanic field sits at 2,000 meters, or 6,600 feet.) The stratovolcano may be the most prominent feature in the volcanic field but it is by no means the only one. More than 300 eruptive features litter the shield volcano, most of them occupying an east-west line. West of Payún Matru is an area known as Los Volcanes, a mass of strombolian cones and basaltic lava flows. Image courtesy Michael P. Taylor, Landsat Data

Metsulfuron-methyl sorption/desorption behavior on volcanic ash-derived soils. effect of phosphate and pH.

PubMed

Cáceres, Lizethly; Fuentes, Roxana; Escudey, Mauricio; Fuentes, Edwar; Báez, María E

2010-06-09

Metsulfuron-methyl sorption/desorption behavior was studied through batch sorption experiments in three typical volcanic ash-derived soils belonging to Andisol and Ultisol orders. Their distinctive physical and chemical properties are acidic pH and variable surface charge. Organic matter content and mineral composition affected in different ways sorption of metsulfuron-methyl (K(OC) ranging from 113 to 646 mL g(-1)): organic matter and iron and aluminum oxides mainly through hydrophilic rather than hydrophobic interactions in Andisols, and Kaolinite group minerals, as major constituents of Ultisols, and iron and aluminum oxides only through hydrophilic interactions. The Freundlich model described metsulfuron-methyl behavior in all cases (R(2) > 0.992). K(f) values (3.1-14.4 microg(1-1/n) mL(1/n) g(-1)) were higher than those reported for different class of soils including some with variable charge. Hysteresis was more significant in Ultisols. A strong influence of pH and phosphate was established for both kinds of soil, intensive soil fertilization and liming being the most probable scenario for leaching of metsulfuron-methyl, particularly in Ultisols.

Testing hypotheses for the use of Icelandic volcanic ashes as low cost, natural fertilizers

NASA Astrophysics Data System (ADS)

Seward, W.; Edwards, B.

2012-04-01

Andisols are soils derived from tephra/volcanic bedrock and are generally considered to be fertile for plant growth (cf. University of Hawaii at Manoa, CTAHR). However, few studies have been published examining the immediate effects of the addition of volcanic ash to soils immediately after an eruption. Our research is motivated by unpublished accounts from Icelandic farmers that the growing season following the 2010 Eyjafjallajökull eruption ended with unusually high yields in areas that were covered by ash from the eruption early in the spring. To test the hypothesis that addition of volcanic ash to soil would have no immediate effect on plant growth, we conducted a ~6 week growth experiment in at controlled environment at the Dickinson College Farm. The experiment used relatively fast growing grain seeds as a test crop, controlled watering, known quantities of peat as an organic base, and the following general experimental design: peat was mixed in known but systematically differing proportions with 1) commercial quartz sand, 2) basaltic ash from the 2004 Grimsvötn eruption, and 3) trachyandesite ash from the 2010 Eyjafjallajökull eruption. For all experiments, the seeds growing in the simulated soil created with the two different composition volcanic ash had higher germination rates, higher growth rates, and produced plants that were healthier in appearance than the soil made from peat mixed with quartz sand. Some differences were also noted between the germination and grow rates between the basaltic and trachyandesitic ash experiments as well. Working hypotheses to explain these results include (1) shard shapes and vesicles from volcanic ash provide better water retention than quartz, allowing water to be stored longer and increasing average soil moisture, and (2) chemical nutrients from the ash facilitate germination and growth of plants. Documenting the potential benefits of fresh volcanic ash as a fertilizer is important as use of fresh ash fertlizer

Surface Fatigue Resistance with Induction Hardening

NASA Technical Reports Server (NTRS)

Townsend, Dennis; Turza, Alan; Chapman, Mike

1996-01-01

Induction hardening has been used for some years to harden the surface and improve the strength and service life of gears and other components. Many applications that employ induction hardening require a relatively long time to finish the hardening process and controlling the hardness of the surface layer and its depth often was a problem. Other surface hardening methods, ie., carbonizing, take a very long time and tend to cause deformations of the toothing, whose elimination requires supplementary finishing work. In double-frequency induction hardening, one uses a low frequency for the preheating of the toothed wheel and a much higher frequency for the purpose of rapidly heating the surface by way of surface hardening.

Rapid response of a hydrologic system to volcanic activity: Masaya volcano, Nicaragua

USGS Publications Warehouse

Pearson, S.C.P.; Connor, C.B.; Sanford, W.E.

2008-01-01

Hydrologic systems change in response to volcanic activity, and in turn may be sensitive indicators of volcanic activity. Here we investigate the coupled nature of magmatic and hydrologic systems using continuous multichannel time series of soil temperature collected on the flanks of Masaya volcano, Nicaragua, one of the most active volcanoes in Central America. The soil temperatures were measured in a low-temperature fumarole field located 3.5 km down the flanks of the volcano. Analysis of these time series reveals that they respond extremely rapidly, on a time scale of minutes, to changes in volcanic activity also manifested at the summit vent. These rapid temperature changes are caused by increased flow of water vapor through flank fumaroles during volcanism. The soil temperature response, ~5 °C, is repetitive and complex, with as many as 13 pulses during a single volcanic episode. Analysis of the frequency spectrum of these temperature time series shows that these anomalies are characterized by broad frequency content during volcanic activity. They are thus easily distinguished from seasonal trends, diurnal variations, or individual rainfall events, which triggered rapid transient increases in temperature during 5% of events. We suggest that the mechanism responsible for the distinctive temperature signals is rapid change in pore pressure in response to magmatism, a response that can be enhanced by meteoric water infiltration. Monitoring of distal fumaroles can therefore provide insight into coupled volcanic-hydrologic-meteorologic systems, and has potential as an inexpensive monitoring tool.

Physical responses of volcanic soils to land-use intensity in tropical headwater catchments of central Veracruz, Mexico

NASA Astrophysics Data System (ADS)

Looker, N. T.; Kolka, R.; Asbjornsen, H.; Munoz-Villers, L.; Colin, P. O.; Gómez Aguilar, L. R.; Ward, A. B.

2017-12-01

Soil physical properties, such as bulk density (ρb) and penetrability (P), may vary in response to anthropogenic disturbance and are relatively easy to measure. These variables are thus often used as proxies for soil characteristics that more directly govern process rates but are logistically challenging to sample in situ (e.g., hydraulic conductivity). We evaluated within- and among-site variability in the physical condition of the upper soil throughout eight first-order catchments in the volcanic landscape of central Veracruz, Mexico, through nested sampling of ρb, P, and ground cover characteristics. The study catchments spanned a land-use intensity gradient, ranging in dominant cover type from sugarcane to mature cloud forest, with pasture and coffee agroforest as intermediate cover types. Catchments were compared using data collected in forest inventory plots and at points distributed along the topographic position index. Analysis of this hierarchical dataset led to a ranking of catchments in terms of soil physical condition and, importantly, revealed the bias introduced by ignoring the within-catchment variability in response metrics. These results will help optimize soil sampling effort in landscapes with complex topography and land-use/cover distributions.

Sensitivity to volcanic field boundary

NASA Astrophysics Data System (ADS)

Runge, Melody; Bebbington, Mark; Cronin, Shane; Lindsay, Jan; Rashad Moufti, Mohammed

2016-04-01

Volcanic hazard analyses are desirable where there is potential for future volcanic activity to affect a proximal population. This is frequently the case for volcanic fields (regions of distributed volcanism) where low eruption rates, fertile soil, and attractive landscapes draw populations to live close by. Forecasting future activity in volcanic fields almost invariably uses spatial or spatio-temporal point processes with model selection and development based on exploratory analyses of previous eruption data. For identifiability reasons, spatio-temporal processes, and practically also spatial processes, the definition of a spatial region is required to which volcanism is confined. However, due to the complex and predominantly unknown sub-surface processes driving volcanic eruptions, definition of a region based solely on geological information is currently impossible. Thus, the current approach is to fit a shape to the known previous eruption sites. The class of boundary shape is an unavoidable subjective decision taken by the forecaster that is often overlooked during subsequent analysis of results. This study shows the substantial effect that this choice may have on even the simplest exploratory methods for hazard forecasting, illustrated using four commonly used exploratory statistical methods and two very different regions: the Auckland Volcanic Field, New Zealand, and Harrat Rahat, Kingdom of Saudi Arabia. For Harrat Rahat, sensitivity of results to boundary definition is substantial. For the Auckland Volcanic Field, the range of options resulted in similar shapes, nevertheless, some of the statistical tests still showed substantial variation in results. This work highlights the fact that when carrying out any hazard analysis on volcanic fields, it is vital to specify how the volcanic field boundary has been defined, assess the sensitivity of boundary choice, and to carry these assumptions and related uncertainties through to estimates of future activity and

Trace metal contents in wild edible mushrooms growing on serpentine and volcanic soils on the island of Lesvos, Greece.

PubMed

Aloupi, M; Koutrotsios, G; Koulousaris, M; Kalogeropoulos, N

2012-04-01

The objectives of this survey were (1) to assess for the first time the Cd, Cu, Cr, Fe, Mn, Ni, Pb and Zn contents in wild edible mushrooms (Russula delica, Lactarius sanguifluus, Lactarius semisanguifluus, Lactarius deliciosus, Suillus bellinii) from the island of Lesvos, (2) to investigate the metals' variability among the species, as well as in relation to the chemical composition of the underlying soil, comparing mushrooms collected from volcanic and serpentine substrates and (3) to estimate metal intake by the consumption of the mushrooms under consideration. The trace metals in 139 samples were determined by flame or flameless atomic absorption spectroscopy. The median metal concentrations were as follows: Cd: 0.14; Cr: 0.10; Cu: 8.51; Fe: 30.3; Mn: 5.26; Ni: 0.34; Pb: 0.093 and Zn: 64.50, all in mgkg(-1) dry weight. The observed concentrations are among the lowest reported for mushrooms from Europe or Turkey, while Pb and Cd values did not exceed the limits set by the European Union. Significant species- and substrate-related differences in the metal contents were found, but the variability did not follow a uniform pattern for all the metals in all mushroom species. As a general trend, the mushrooms growing in serpentine sites contained higher Cd, Cr and Ni than those from volcanic sites. The calculated bioconcentration factors (BCFs) showed that none of the mushrooms can be regarded as a metal bioaccumulator, although BCF values slightly above unity were found for Zn in the three Lactarius species, and for Cu in R. delica. The studied mushrooms could supply considerable amounts of essential metals such as Zn and Cr. On the other hand, the consumption of R. delica collected from volcanic soils could provide 12% of the Cd daily tolerable intake and as high as 53% when collected from serpentine soils. Nonetheless, our results indicate that the regular consumption of wild edible mushrooms from Lesvos is quite safe for human health. Copyright © 2011 Elsevier

Natural Terrestrial Sequestration Potential of Highplains Prairie to Subalpine Forest and Mined-Lands Soils Derived from Weathering of Tertiary Volcanics

NASA Astrophysics Data System (ADS)

Yager, D. B.; Burchell, A.; Robinson, R.; Odell, S.; Dick, R. P.; Johnson, C. A.; Hidinger, J.; Rathke, D.

2007-12-01

There is now widespread agreement that, if the climate is to be stabilized, then net greenhouse gas emissions must be greatly reduced (IPCC, 2007). The need to reduce net CO2 emissions plus the possible economic and environmental ramifications of not addressing climate change have stimulated important atmospheric carbon mitigation actions, as well as, studies to understand and quantify potential carbon sinks. Soils represent a potentially large and environmentally significant natural carbon reservoir. Increasing the natural terrestrial sequestration potential (NTS) of soils is among the seven, "Sokolow CO2 stabilization wedges' or carbon management strategies needed to thwart doubling of atmospheric CO2. Additionally, high plains to subalpine temperate soils tend to be less susceptible to baseline C pool declines due to global warming than are warmer regions and are important ecosystems in which to quantify soil carbon storage capacity. To examine the potential of magnesium silicate-bearing soils to sequester additional carbon, we sampled 60 high plains prairie to subalpine forest soil horizons derived from weathering of Tertiary-age dacite-andesite- basalt compositions in Colorado, U.S.A.: the San Luis Valley, San Juan Volcanic Field, Grand Mesa, White River- Roan Plateau (Flat Tops), Rocky Mountain National Park, Front Range and propylitically-altered terrain in the western San Juan Volcanic field containing secondary magnesium silicates (chlorite-species). Data for C, N, O (total conc., isotopes), metals, major and trace elements, Hg, S, microbial enzymes (β-glucosidase, arylsulfatase, acid neutralizing capacity (ANC), and 14C radiocarbon dates are reported. Samples demonstrate variable but elevated C relative to average global soil C. In particular, the propylitically-altered rocks have a high instantaneous ANC in laboratory tests (> 20 kg/ton CaCO3 equivalent) and derivative forest soils containing low-temperature charcoal "burn" horizons have high total

Hardening [Chapter 12

Treesearch

Douglass F. Jacobs; Thomas D. Landis

2009-01-01

To promote survival and growth following outplanting, nursery stock must undergo proper hardening. Without proper hardening, plants do not store well over winter and are likely to grow poorly or die on the outplanting site. It is important to understand that native plant nurseries are different from traditional horticultural systems in that native plants must endure an...

System-Level Radiation Hardening

NASA Technical Reports Server (NTRS)

Ladbury, Ray

2014-01-01

Although system-level radiation hardening can enable the use of high-performance components and enhance the capabilities of a spacecraft, hardening techniques can be costly and can compromise the very performance designers sought from the high-performance components. Moreover, such techniques often result in a complicated design, especially if several complex commercial microcircuits are used, each posing its own hardening challenges. The latter risk is particularly acute for Commercial-Off-The-Shelf components since high-performance parts (e.g. double-data-rate synchronous dynamic random access memories - DDR SDRAMs) may require other high-performance commercial parts (e.g. processors) to support their operation. For these reasons, it is essential that system-level radiation hardening be a coordinated effort, from setting requirements through testing up to and including validation.

Biogeochemistry and nitrogen cycling in an Arctic, volcanic ecosystem

NASA Astrophysics Data System (ADS)

Fogel, M. L.; Benning, L.; Conrad, P. G.; Eigenbrode, J.; Starke, V.

2007-12-01

As part of a study on Mars Analogue environments, the biogeochemistry of Sverrefjellet Volcano, Bocfjorden, Svalbard, was conducted and compared to surrounding glacial, thermal spring, and sedimentary environments. An understanding of how nitrogen might be distributed in a landscape that had extinct or very cold adapted, slow- growing extant organisms should be useful for detecting unknown life forms. From high elevations (900 m) to the base of the volcano (sea level), soil and rock ammonium concentrations were uniformly low, typically less than 1- 3 micrograms per gm of rock or soil. In weathered volcanic soils, reduced nitrogen concentrations were higher, and oxidized nitrogen concentrations lower. The opposite was found in a weathered Devonian sedimentary soil. Plants and lichens growing on volcanic soils have an unusually wide range in N isotopic compositions from -5 to +12‰, a range rarely measured in temperate ecosystems. Nitrogen contents and isotopic compositions of volcanic soils and rocks were strongly influenced by the presence or absence of terrestrial herbivores or marine avifauna with higher concentrations of N and elevated N isotopic compositions occurring as patches in areas immediately influenced by reindeer, Arctic fox ( Alopex lagopus), and marine birds. Because of the extreme conditions in this area, ephemeral deposition of herbivore feces results in a direct and immediate N pulses into the ecosystem. The lateral extent and distribution of marine- derived nitrogen was measured on a landscape scale surrounding an active fox den. Nitrogen was tracked from the bones of marine birds to soil to vegetation. Because of extreme cold, slow biological rates and nitrogen cycling, a mosaic of N patterns develops on the landscape scale.

Ecological and Topographic Features of Volcanic Ash-Influenced Forest Soils

Treesearch

Mark Kimsey; Brian Gardner; Alan Busacca

2007-01-01

Volcanic ash distribution and thickness were determined for a forested region of north-central Idaho. Mean ash thickness and multiple linear regression analyses were used to model the effect of environmental variables on ash thickness. Slope and slope curvature relationships with volcanic ash thickness varied on a local spatial scale across the study area. Ash...

Volcanic soils and landslides: a case study of the island of Ischia (southern Italy) and its relationship with other Campania events

NASA Astrophysics Data System (ADS)

Vingiani, S.; Mele, G.; De Mascellis, R.; Terribile, F.; Basile, A.

2015-06-01

An integrated investigation was carried out on the volcanic soils involved in the landslide phenomena that occurred in 2006 at Mt. Vezzi on the island of Ischia (southern Italy). Chemical (soil pH, organic carbon content, exchangeable cations and cation exchange capacity, electrical conductivity, Na adsorption ratio and Al, Fe and Si forms), physical (particle and pore size distribution, pore structure), hydrological (soil water retention, saturated and unsaturated hydraulic conductivity), mineralogical and micromorphological analyses were carried out for three soil profiles selected in two of the main head scarps. The studied soils showed a substantial abrupt discontinuity in all the studied properties at the interface with a buried fine ash layer (namely, the 2C horizon), that was only marginally involved in the sliding surface of the landslide phenomena. When compared to the overlying horizons, 2C showed (i) fine grey ash that is almost pumice free, with the silt content increasing by 20 %; (ii) ks values 1 order of magnitude lower; (iii) a pore distribution concentrated into small (15-30 μm modal class) pores characterised by a very low percolation threshold (approximately 15-25 μm); (iv) the presence of expandable clay minerals; and (v) increasing Na content in the exchange complex. Most of these properties indicated that 2C was a lower permeability horizon compared to the overlying ones. Nevertheless, it was possible to assume this interface to be an impeding layer to vertical water fluxes only by the identification of a thin (6.5 mm) finely stratified ash layer, on top of 2C, and of the hydromorphic features (e.g. Fe / Mn concretions) within and on top of the layer. Although Mt. Vezzi's soil environment has many properties in common with those of other Campania debris-mudflows (e.g. high gradient, north-facing slope, similar forestry, and volcanic origin of the parent material), the results of this study suggest a more complex relationship between soil

Effects of Inter- and Intra-aggregate Pore Space on the Soil-Gas Diffusivity Behavior in Unsaturated, Undisturbed Volcanic Ash Soils

NASA Astrophysics Data System (ADS)

Resurreccion, A. C.; Kawamoto, K.; Komatsu, T.; Moldrup, P.

2006-12-01

Volcanic ash soils (Andisols) have a unique dual porosity structure that results in good drainage and high soil- water retention. Despite of the complicated and highly developed soil structure, recent studies have reported a simple, highly linear relation between the soil-gas diffusion coefficient, Dp, and the soil-air content, ɛ, for several Japanese Andisols. In this study, we explain the linear Dp(ɛ) behavior from the effects of the inter- and intra-aggregate pore-size distributions. We couple the bimodal van Genuchten soil-water retention model with a general Dp(ɛ) model, ɛ^{X}, allowing the tortuosity- connectivity factor X to vary with pF (= log(-ψ; the soil-water matric potential in cm H2O)). Measured data suggest that the tortuosity-connectivity parameter X is at the minimum at pF 3 (where X ~ 2, following Buckingham, 1904), equal to the water retention point where a separation of inter- and intra-aggregate effects on Dp is observed. At pF < 3, the X values increased as pF decreased because of inactive/remote air-filled pore space entrapped by the inter-connected water films between inter-aggregate pore spaces. At pF > 3, X increased to a high value at very dry conditions due to remote air-filled space inside the intra-aggregate pores. By combining the complex dual porosity soil-water retention model with the power- law gas diffusivity model using a parabolic X(pF) function, the surprisingly simple linear behavior of Dp with ɛ was captured while the variation of Dp with pF followed a dual s-shaped curve similar to the water retention curve. A simple linear model to predict Dp(ɛ) is suggested, with slope C and threshold soil-air content, ɛth, calculated from the power-law model ɛ^{X} at pF 2 (near field capacity) and at pF 4.1 (near wilting point) using the same X value (= 2.3) at both pF in agreement with measured data. This linear Dp(ɛ) model performed better, especially at dry conditions, compared to the traditionally-used predictive models when

Contact allergy to epoxy hardeners.

PubMed

Aalto-Korte, Kristiina; Suuronen, Katri; Kuuliala, Outi; Henriks-Eckerman, Maj-Len; Jolanki, Riitta

2014-09-01

Diglycidylether of bisphenol A resin is the most important sensitizer in epoxy systems, but a minority of patients develop concomitant or solitary contact allergy to epoxy hardeners. At the Finnish Institute of Occupational Health, several in-house test substances of epoxy hardeners have been tested in a special epoxy compound patch test series. To analyse the frequency and clinical relevance of allergic reactions to different epoxy hardeners. Test files (January 1991 to March 2013) were screened for contact allergy to different epoxy hardeners, and the clinical records of patients with allergic reactions were analysed for occupation, concomitant allergic reactions, and exposure. The most commonly positive epoxy hardeners were m-xylylenediamine (n = 24), 2,4,6-tris-(dimethylaminomethyl)phenol (tris-DMP; n = 14), isophorone-diamine (n = 12), and diethylenetriamine (n = 9). Trimethylhexamethylenediamine (n = 7), tetraethylenepentamine (n = 4), and triethylenetetramine (n = 2) elicited some reactions, although most patients were found to have no specific exposure. Allergic reactions to hexamethylenetetramine, dimethylaminopropylamine and ethylenediamine dihydrochloride were not related to epoxy products. Tris-DMP is an important sensitizer in epoxy hardeners, and should be included in the patch test series of epoxy chemicals. © 2014 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

Chemical transport during formation and alteration of Martian impact and volcanic deposits

NASA Technical Reports Server (NTRS)

Newsom, H. E.

1992-01-01

Much of the surface of Mars, including volcanic and cratered terrains, probably experienced alteration and degassing processes. These processes may have depleted or enriched many important elements in surface materials, including bedrock, dust, and soils. The composition of the martian soil may represent the best estimate, for some elements, of the average composition of the martian crust, similar to the composition of loess created by glacial action on the Earth. The martian soil may represent the only convenient, globally or regionally averaged sample of the martian crust. In order to understand the composition of the source material for the soil, however, we need to understand the contributions of volcanic vs. impact sources for this material and the chemical fractionations involved in its production. The processes to be addressed include degassing of volcanic deposits, as observed in the Valley of Ten Thousand Smokes at Katmai, Alaska, and degassing of meltbearing impact ejecta as inferred for suevite ejecta sheets at the Ries Crater, and alteration or palagonitization of volcanic deposits, as documented for volcanos in British Columbia and many other volcanic terrains, and impact crater deposits. The process of palagonitization has been the subject of several studies with reference to Mars, and palagonite is a good analogue for the spectroscopic properties of the martian dust. The role of impact in cratering has not been as well studied, although other researchers have established that both degassing and alteration are common features of impact crater deposits. Other relevant sources of experimental data include the extensive literature on the corrosion of nuclear waste glass and leaching of shocked materials.

Radiocaesium transfer from volcanic soils to Swiss chard, cabbage and sweet corn.

PubMed

Schuller, Paulina; Castillo, Alejandra; Voigt, Gabriele; Semioshkina, Natalia

2018-06-18

The root uptake of radiocaesium by different plant parts of Swiss chard (Beta vulgaris L. var. cicla), cabbage (Brassica oleracea L. var. capitata) and sweet corn (Zea mays L. var. saccharata) and the potential influence of K-fertilising on the transfer behaviour was studied in allophanic volcanic soils (umbric andosol and dystric fluvisol) in Chile under temperate climate and heavy rainfall conditions (∼2660 mm y -1 ) over several vegetation periods. The soils were spiked homogeneously to 0.20 m depth with 100 kBq 134 Cs m -2 and activity concentrations measured. The transfer factor (TF, on a dry mass basis) to Swiss chard had a clear exponential decrease within each crop year for both soil types, either K-fertilised or unfertilised. The highest values of the TFs to Swiss chard were at the beginning of the harvests, and the half-times of TF decrease ranged between 52 and 137 d for umbric andosol and between 40 and 164 d for dystric fluvisol. Over the five seasons there was no consistent ageing effect based on TF in either soil types for the three studied crops. The effect of 134 Cs foliar uptake by Swiss chard from resuspended soil was estimated to account for about 70% (external leaves) and 30% (internal leaves) increase in the TF for the K-unfertilised umbric andosol, and showed an ambiguous behaviour for the K-fertilised umbric andosol. Consequently foliar uptake does not explain the 370 and 500% increase of the TF to Swiss chard leaves determined during the third growing period in the umbric andosol without and with K-fertilisation, respectively. Therefore an uncertainty factor of 3-5 is recommended to be taken into account when using this parameter for dose calculations. The TF to Swiss chard was found to be higher than previously reported values. The TF to cabbage and sweet corn plant parts was found to be within the range of previously reported values. Normal K-fertilisation resulted in about 2.4-fold reduction in 134 Cs TF to Swiss chard, 2

Volcanic soil gas 4He/CO2 ratio: a useful geochemical tool for eruption forecasting

NASA Astrophysics Data System (ADS)

Asensio-Ramos, M.; Perez, N. M.; Padron, E.; Melián, G.; Hernandez Perez, P. A.; Padilla, G.; Barrancos, J.; Rodríguez, F.; Sumino, H.; Calvo, D.

2016-12-01

Magmatic gases that percolate through volcano's porous flanks in a non-visible (diffuse) way disturb the chemical composition of soil gases at the surface environment of the volcano, generating enrichments of CO2, He and other gases. Two of the gases which have attracted attention in soil degassing studies are He and CO2 because both species have similar low solubility in silicate melts. However, once they are exsolved from the melts, their movement through the crust towards the surface is very different: CO2, which is a reactive gas, is affected by the occurrence of interfering processes, while interaction of He during its ascent is minimum. Their geochemical differences yield higher relative He/CO2 ratios in the fumarole gases than is actually present in the magma, but it decreases when the magma reservoir reaches enough pressure to generate incipient fracture systems approaching the eruption. In this work, we present quasi daily estimations of diffusive He through the whole surface of El Hierro, the youngest island of the Canarian archipelago, considering He emission data reported in the literature (Padrón et al., 2013. Geology, 41, 539-542), using the same procedure as for diffuse CO2 emission time series (Melián et al., 2014. J. Geophys. Res., 119, 6976-6991). After the occurrence of more than 11,000 seismic events, a shallow submarine eruption about 2 km off the south coast in the southernmost part of El Hierro, started in October 12, 2011 and lasted for 5 month. The herein presented methodology enables the calculation of the diffuse He/CO2 emission ratio of the entire island during the volcanic unrest. Two different emission peaks for both He and CO2, with approximately the same delay between them ( 23 days), were observed. The combination of both time series resulted in a drastic increase in the He/CO2 emission ratio of the island (up to 1.1×10-3) two weeks before the eruption onset. Additionally, a second significant He/CO2 emission peak (up to 5.5×10

Linking tephrochronology and soil characteristics in the Sila and Nebrodi Mountains, Italy

NASA Astrophysics Data System (ADS)

Raab, Gerald; Halpern, Dieter; Scarciglia, Fabio; Raimondi, Salvatore; de Castro Portes, Raquel; Norton, Kevin; Egli, Markus

2017-04-01

Mediterranean soils are an important key to understanding past volcanic events and landscape evolution. The influence and timing of Quaternary volcanic events on soils, however, remains still poorly understood in southern Italy. We used a multi-method approach to explore the origin and age of volcanic deposits (soils) in Sicily and Calabria. By comparing the geochemical signature of the soils with the chemical fingerprint of magmatic effusive rocks in southern Italy, we tried to identify the source material. It seems that the investigated soils on the Nebrodi (Sicily) and Sila (Calabria) mountains were both influenced by volcanic deposits having a high-K calc-alkaline series volcanic background. The Aeolian islands (Lipari and Vulcano) are the most likely sources of origin. Due to weathering processes of the volcanic sediments and the partial mixing with the underlying non-volcanic parent material, a direct relation with the potential source areas was not always straightforward. Immobile elements and their corresponding ratios (e.g. the Nb/Y vs Zr/Ti plot) or trace elements (Co, Th) and rare earth elements gave better hints of the origin of the deposits. Radiocarbon dating of the stable soil organic fraction (H2O2 resistant) indicated a minimum age of 8 - 10 ka of the Nebrodi and Sila soils. The chemical proxy of alteration (CPA) and weathering index according to Parker (WIP) were tested as proxies for an age estimate of the volcanic deposits and duration of soil formation. The soils and, subsequently, landscape are characterized by multiple volcanic depositional phases for the last 30 - 50 ka in the Sila mountains and about 70 ka in the Nebrodi mountains. We show that a multi-method approach (numerical dating, relative dating using weathering indices and the forensic procedure) enabled the identification of potential source areas, gave tentative age estimates of the ash deposits, duration of soil formation and, therefore, improved our understanding of volcanic

Diffuse emissions of Volatile Organic Compounds (VOCs) from soil in volcanic and hydrothermal systems: evidences for the influence of microbial activity on the carbon budget

NASA Astrophysics Data System (ADS)

Venturi, Stefania; Tassi, Franco; Fazi, Stefano; Vaselli, Orlando; Crognale, Simona; Rossetti, Simona; Cabassi, Jacopo; Capecchiacci, Francesco

2017-04-01

Soils in volcanic and hydrothermal areas are affected by anomalously high concentrations of gases released from the deep reservoirs, which consists of both inorganic (mainly CO2 and H2S) and organic (volatile organic compounds; VOCs) species. VOCs in volcanic and hydrothermal fluids are mainly composed of saturated and unsaturated hydrocarbons (alkanes, aromatics, alkenes, and cyclics), with variable concentrations of O- and S-bearing compounds and halocarbons, depending on the physicochemical conditions at depth. VOCs in interstitial soil gases and fumarolic emissions from four volcanic and hydrothermal systems in the Mediterranean area (Solfatara Crater, Poggio dell'Olivo and Cava dei Selci, in Italy, and Nisyros Island, in Greece) evidenced clear compositional differences, suggesting that their behavior is strongly affected by secondary processes occurring at shallow depths and likely controlled by microbial activity. Long-chain saturated hydrocarbons were significantly depleted in interstitial soil gases with respect to those from fumarolic discharges, whereas enrichments in O-bearing compounds (e.g. aldehydes, ketones), DMSO2 and cyclics were commonly observed. Benzene was recalcitrant to degradation processes, whereas methylated aromatics were relatively instable. The chemical and isotopic (δ13C in CO2 and CH4) composition of soil gases collected along vertical profiles down to 50 cm depth at both Solfatara Crater and Poggio dell'Olivo (Italy) showed evidences of relevant oxidation processes in the soil, confirming that microbial activity likely plays a major role in modifying the composition of deep-derived VOCs. Despite their harsh conditions, being typically characterized by high temperatures, low pH, and high toxic gases and metal contents, the variety of habitats characterizing volcanic and hydrothermal environments offers ideal biomes to extremophilic microbes, whose metabolic activity can consume and/or produce VOCs. In the Solfatara Crater, microbial

Chemical composition and Zn bioavailability of the soil solution extracted from Zn amended variable charge soils.

PubMed

Zampella, Mariavittoria; Adamo, Paola

2010-01-01

A study on variable charge soils (volcanic Italian and podzolic Scottish soils) was performed to investigate the influence of soil properties on the chemical composition of soil solution. Zinc speciation, bioavailability and toxicity in the soil solution were examined. The soils were spiked with increasing amounts of Zn (0, 100, 200, 400 and 1000 mg/kg) and the soil solutions were extracted using rhizon soil moisture samplers. The pH, total organic carbon (TOC), base cations, anions, total Zn and free Zn2+ in soil solution were analysed. A rapid bioassay with the luminescent bacterium Escherichia coli HB101 pUCD607 was performed to assess Zn toxicity. The influence of soil type and Zn treatments on the chemical composition of soil solution and on Zn toxicity was considered and discussed. Different trends of total and free Zn concentrations, base cations desorption and luminescence of E. coli HB101 pUCD607 were observed. The soil solution extracted from the volcanic soils had very low total and free Zn concentrations and showed specific Zn2+/Ca2+ exchange. The soil solution from the podzolic soil had much higher total and free Zn concentrations and showed no evidence of specific Zn2+/Ca2+ exchange. In comparison with the subalkaline volcanic soils, the acidic podzol showed enhanced levels of toxic free Zn2+ and consequently stronger effects on E. coli viability.

Properties and Commercial Application of Manual Plasma Hardening

NASA Astrophysics Data System (ADS)

Korotkov, V. A.

2016-11-01

A new method and a device for plasma hardening of various parts are considered. Installation of the new device does not require too much investment (the active mechanical productions are appropriate for its accommodation) and special choice of personnel (welders train to use it without difficulty). Plasma hardening does not deform and worsen the smoothness of the surface, which makes it possible to employ many hardened parts without finishing mechanical treatment required after bulk or induction hardening. The hardened layer (about 1 mm) produced by plasma hardening exhibits better wear resistance than after bulk hardening with tempering, which prolongs the service life of the parts.

Kinematic hardening of a porous limestone

NASA Astrophysics Data System (ADS)

Cheatham, J. B.; Allen, M. B.; Celle, C. C.

1984-10-01

A concept for a kinematic hardening yield surface in stress space for Cordova Cream limestone (Austin Chalk) developed by Celle and Cheatham (1981) has been improved using Ziegler's modification of Prager's hardening rule (Ziegler, 1959). Data to date agree with the formulated concepts. It is shown how kinematic hardening can be used to approximate the yield surface for a wide range of stress states past the initial yield surface. The particular difficulty of identifying the yield surface under conditions of unloading or extension is noted. A yield condition and hardening rule which account for the strain induced anisotropy in Cordova Cream Limestone were developed. Although the actual yield surface appears to involve some change of size and shape, it is concluded that true kinematic hardening provides a basis for engineering calculations.

Radiation Hardened Electronics for Extreme Environments

NASA Technical Reports Server (NTRS)

Keys, Andrew S.; Watson, Michael D.

2007-01-01

The Radiation Hardened Electronics for Space Environments (RHESE) project consists of a series of tasks designed to develop and mature a broad spectrum of radiation hardened and low temperature electronics technologies. Three approaches are being taken to address radiation hardening: improved material hardness, design techniques to improve radiation tolerance, and software methods to improve radiation tolerance. Within these approaches various technology products are being addressed including Field Programmable Gate Arrays (FPGA), Field Programmable Analog Arrays (FPAA), MEMS Serial Processors, Reconfigurable Processors, and Parallel Processors. In addition to radiation hardening, low temperature extremes are addressed with a focus on material and design approaches.

Comparison of soil infiltration rates in burned and unburned mountainous watersheds

USGS Publications Warehouse

Martin, D.A.; Moody, J.A.

2001-01-01

Steady-state infiltration measurements were made at mountainous sites in New Mexico and Colorado, USA, with volcanic and granitic soils after wildfires and at comparable unburned sites. We measured infiltration in the New Mexico volcanic soils under two vegetation types, ponderosa pine and mixed conifer, and in the Colorado granitic soils under ponderosa pine vegetation. These measurements were made within high-severity burn areas using a portable infiltrometer with a 0.017 m2 infiltration area and artificial rainfall rates ranging from 97 to 440 mm h-1. Steady-state infiltration rates were less at all burned sites relative to unburned sites. The volcanic soil with ponderosa pine vegetation showed the greatest difference in infiltration rates with a ratio of steady-state infiltration rate in burned sites to unburned soils equal to 0.15. Volcanic soils with mixed conifer vegetation had a ratio (burned to unburned soils) of at most 0.38, and granitic soils with ponderosa pine vegetation had a ratio of 0.38. Steady-state infiltration rates on unburned volcanic and granitic soils with ponderosa pine vegetation are not statistically different. We present data on the particle-size distribution at all the study sites and examples of wetting patterns produced during the infiltration experiments. Published in 2001 by John Wiley and Sons, Ltd.

Effects of seagulls on ecosystem respiration, soil nitrogen and vegetation cover on a pristine volcanic island, Surtsey, Iceland

NASA Astrophysics Data System (ADS)

Sigurdsson, B. D.; Magnusson, B.

2010-03-01

When Surtsey rose from the North Atlantic Ocean south of Iceland in 1963, it became a unique natural laboratory on how organisms colonize volcanic islands and form ecosystems with contrasting structures and functions. In July, 2004, ecosystem respiration rate (Re), soil properties and surface cover of vascular plants were measured in 21 permanent research plots distributed among the juvenile communities of the island. The plots were divided into two main groups, inside and outside a seagull (Larus spp.) colony established on the island. Vegetation cover of the plots was strongly related to the density of gull nests. Occurrence of nests and increased vegetation cover also coincided with significant increases in Re, soil carbon, nitrogen and C:N ratio, and with significant reductions in soil pH and soil temperatures. Temperature sensitivity (Q10 value) of Re was determined as 5.3. When compared at constant temperature the Re was found to be 59 times higher within the seagull colony, similar to the highest fluxes measured in drained wetlands or agricultural fields in Iceland. The amount of soil nitrogen, mainly brought onto the island by the seagulls, was the critical factor that most influenced ecosystem fluxes and vegetation development on Surtsey. The present study shows how ecosystem activity can be enhanced by colonization of animals that transfer resources from a nearby ecosystem.

Diffuse volcanic emissions of carbon dioxide from Vulcano Island, Italy.

PubMed

Baubron, J C; Allard, P; Toutain, J P

1990-03-01

RECENT investigations on Mount Etna (Sicily)(1-3) have revealed that volcanoes may release abundant carbon dioxide not only from their active craters, but also from their flanks, as diffuse soil emanations. Here we present analyses of soil gases and air in water wells on Vulcano Island which provide further evidence of such lateral degassing. Nearly pure carbon dioxide, enriched in helium and radon, escapes from the slopes of the Fossa active cone, adding a total output of 30 tonnes per day to the fumarolic crater discharge ( 180 tonnes CO(2) per day). This emanation has similar He/CO(2) and (13)C/(12)C ratios to those of the crater fumaroles (300%ndash;500 degrees C) and therefore a similar volcanic origin. Gases rich in carbon dioxide also escape at sea level along the isthmus between the Fossa and Vulcanello volcanic cones, but their depletion in both He and (13)C suggests a distinct source. Diffuse volcanic gas emanations, once their genetic link with central fumarole degassing has been demonstrated, can be used for continuous volcano monitoring, at safe distances from active craters. Such monitoring has been initiated at Vulcano, where soil and well emanations of nearly pure CO(2) themselves represent a threat to the local population.

Lunar highlands volcanism implications from Luna 20 and Apollo 16

USGS Publications Warehouse

Wilshire, H.G.; Wilhelms, D.E.; Howard, K.A.

1974-01-01

Highlands materials sampled at the Apollo 16 and Luna 20 sites represent units of distinctive morphology that are widespread on the lunar nearside. Samples from the Apollo 16 site represent hilly and furrowed materials of the Descartes highlands and Cayley Formation. Materials were collected by Luna 20 from terrain resembling the Descartes terrain. Most photogeologic interpretations of these units favored volcanic origins, but the samples fail to support this interpretation. Luna 20 soil fragments are mainly glassy microbreccia with lithic inclusions of fine-grained hornfels; less than 3 percent of the fragments have textures of volcanic rocks, and most of these are likely crystalline products of impact melting. Apollo 16 soils formed on ejecta derived from a plutonic anorthosite-norite-troctolite suite. The similarity of Luna 20 soils indicates that these too formed as regolith on ejecta of anorthosite-norite-troctolitc composition. Interpretation of the samples from the two locations now suggests that hilly and furrowed terrains, previously thought to be of volcanic origin, are impact ejecta; in view of the plutonic nature of the source rocks and their extensive fusion and metamorphism, it is likely that the ejecta were derived from multiring basins. At one point, the Apollo 16 site, the Cayley Formation is composed of basin ejecta.

Hazardous indoor CO2 concentrations in volcanic environments.

PubMed

Viveiros, Fátima; Gaspar, João L; Ferreira, Teresa; Silva, Catarina

2016-07-01

Carbon dioxide is one of the main soil gases released silently and permanently in diffuse degassing areas, both in volcanic and non-volcanic zones. In the volcanic islands of the Azores (Portugal) several villages are located over diffuse degassing areas. Lethal indoor CO2 concentrations (higher than 10 vol %) were measured in a shelter located at Furnas village, inside the caldera of the quiescent Furnas Volcano (S. Miguel Island). Hazardous CO2 concentrations were detected not only underground, but also at the ground floor level. Multivariate regression analysis was applied to the CO2 and environmental time series recorded between April 2008 and March 2010 at Furnas village. The results show that about 30% of the indoor CO2 variation is explained by environmental variables, namely barometric pressure, soil water content and wind speed. The highest indoor CO2 concentrations were recorded during bad weather conditions, characterized by low barometric pressure together with rainfall periods and high wind speed. In addition to the spike-like changes observed on the CO2 time series, long-term oscillations were also identified and appeared to represent seasonal variations. In fact, indoor CO2 concentrations were higher during winter period when compared to the dry summer months. Considering the permanent emission of CO2 in various volcanic regions of the world, CO2 hazard maps are crucial and need to be accounted by the land-use planners and authorities. Copyright © 2016 Elsevier Ltd. All rights reserved.

The phosphorus status of andisols as influenced by nanoparticles of volcanic ash and rock phosphate

NASA Astrophysics Data System (ADS)

Devnita, Rina; Joy, Benny; Arifin, Mahfud; Setiawan, Ade; Rosniawaty, Santi; Meidina, Felia Shella

2018-02-01

Andisols need to be ameliorated to improve the phosphorus status. The objective of this research is to investigate the effect of nanoparticles of volcanic ash and rock phosphate as ameliorants in Andisols to P-retention, available P and potential P in Andisols. The research used a complete randomized experimental design in factorial with two factors. The first factor was nanoparticle of volcanic ash (a) and the second factor was rock phosphate (p). Both ameliorants consist of four doses on soil weight percentage (0%, 2.5%, 5.0% and 7.5%). The combined treatments were replicated three times. The soil and treatments were mixed and incubated for 4 months. Soil samples were taken after one month and four months of incubation to be analyzed the P-retention, available P and potential P. The results showed that there are interactions between the volcanic ash and rock phosphate on available P and potential P after one month of incubation. However, there were no interactions occurring between the volcanic ash and rock phosphate on P-retention after one and four months of incubation and no interactions on available P and potential P after four months. The best combined treatments in increasing available P and potential P after one month was obtained in 2.5% of volcanic ash and 5% of rock phosphate that increased available P to 405.75 ppm. The 2.5% of volcanic ash and 7.5% of rock phosphate increased potential P to 2190.26 mg/100 g. Independently, 7.5% of volcanic ash and rock phosphate decreased P-retention to 71.49% after one month and 89.74% after four months. Higher effect on the application of nanoparticle of volcanic ash and rock phosphate to the phosphorus status of Andisols recieved after one month of incubation is compared with four months of incubation.

Organic Entrainment and Preservation in Volcanic Glasses

NASA Technical Reports Server (NTRS)

Wilhelm, Mary Beth; Ojha, Lujendra; Brunner, Anna E.; Dufek, Josef D.; Wray, James Joseph

2014-01-01

Unaltered pyroclastic deposits have previously been deemed to have "low" potential for the formation, concentration and preservation of organic material on the Martian surface. Yet volcanic glasses that have solidified very quickly after an eruption may be good candidates for containment and preservation of refractory organic material that existed in a biologic system pre-eruption due to their impermeability and ability to attenuate UV radiation. Analysis using NanoSIMS of volcanic glass could then be performed to both deduce carbon isotope ratios that indicate biologic origin and confirm entrainment during eruption. Terrestrial contamination is one of the biggest barriers to definitive Martian organic identification in soil and rock samples. While there is a greater potential to concentrate organics in sedimentary strata, volcanic glasses may better encapsulate and preserve organics over long time scales, and are widespread on Mars. If volcanic glass from many sites on Earth could be shown to contain biologically derived organics from the original environment, there could be significant implications for the search for biomarkers in ancient Martian environments.

The influence of using quicklime and volcanic ash as stabilizing materials in clay viewed from CBR value

NASA Astrophysics Data System (ADS)

Hastuty, Ika Puji; Sofyan, Tri Alby; Roesyanto

2017-11-01

The condition of the soil in Indonesia in varied, viewed from its bearing capacity. The soil is one of the materials which plays a very important role in a construction or foundation so that it is very necessary to have soil with its adequate technical properties. In reality, often founding inadequate soil properties such as in its compressibility, permeability, and plasticity. The objective of the research was to find out the physical properties, technical properties, CBR value, and stabilization of clay by adding quicklime and volcanic ash as stabilizing materials. The mixing combination is 2%, 4% quicklime, and 2%-24% volcanic ash. The value of Water Content for original soil was 34.33% and Specific Gravity original soil was 2.65. The result of the research showed that the stabilizing materials from quicklime and volcanic ash could improve the physical and mechanical properties of clay. The value of Atterberg Limits decreased from 29.88% to 11.33% in the variation of 4% Q+24% VA, while the most maximal value of CBR was found in the variation of 4% Q+8% VA at 9.01%.

Using Volcanic Ash to Remove Dissolved Uranium and Lead

NASA Technical Reports Server (NTRS)

McKay, David S.; Cuero, Raul G.

2009-01-01

Experiments have shown that significant fractions of uranium, lead, and possibly other toxic and/or radioactive substances can be removed from an aqueous solution by simply exposing the solution, at ambient temperature, to a treatment medium that includes weathered volcanic ash from Pu'u Nene, which is a cinder cone on the Island of Hawaii. Heretofore, this specific volcanic ash has been used for an entirely different purpose: simulating the spectral properties of Martian soil. The treatment medium can consist of the volcanic ash alone or in combination with chitosan, which is a natural polymer that can be produced from seafood waste or easily extracted from fungi, some bacteria, and some algae. The medium is harmless to plants and animals and, because of the abundance and natural origin of its ingredient( s), is inexpensive. The medium can be used in a variety of ways and settings: it can be incorporated into water-filtration systems; placed in contact or mixed with water-containing solids (e.g., soils and sludges); immersed in bodies of water (e.g., reservoirs, lakes, rivers, or wells); or placed in and around nuclear power plants, mines, and farm fields.

Materials science. Modeling strain hardening the hard way.

PubMed

Gumbsch, Peter

2003-09-26

The plastic deformation of metals results in strain hardening, that is, an increase in the stress with increasing strain. Materials engineers can provide a simple approximate description of such deformation and hardening behavior. In his perspective, Gumbsch discusses work by Madec et al. who have undertaken the formidable task of computing the physical basis for the development of strain hardening by individually following the fate of all the dislocations involved. Their simulations show that the collinear dislocation interaction makes a substantial contribution to strain hardening. It is likely that such simulations will play an important role in guiding the development of future engineering descriptions of deformation and hardening.

Strain Hardening of Hadfield Manganese Steel

NASA Astrophysics Data System (ADS)

Adler, P. H.; Olson, G. B.; Owen, W. S.

1986-10-01

The plastic flow behavior of Hadfield manganese steel in uniaxial tension and compression is shown to be greatly influenced by transformation plasticity phenomena. Changes in the stress-strain (σ-ɛ) curves with temperature correlate with the observed extent of deformation twinning, consistent with a softening effect of twinning as a deformation mechanism and a hardening effect of the twinned microstructure. The combined effects give upward curvature to the σ-ɛ curve over extensive ranges of plastic strain. A higher strain hardening in compression compared with tension appears to be consistent with the observed texture development. The composition dependence of stacking fault energy computed using a thermodynamic model suggests that the Hadfield composition is optimum for a maximum rate of deformation twinning. Comparisons of the Hadfield steel with a Co-33Ni alloy exhibiting similar twinning kinetics, and an Fe-21Ni-lC alloy deforming by slip indicate no unusual strain hardening at low strains where deformation is controlled by slip, but an unusual amount of structural hardening associated with the twin formation in the Hadfield steel. A possible mechanism of anomalous twin hardening is discussed in terms of modified twinning behavior (pseudotwinning) in nonrandom solid solutions.

Laser Surface Hardening of Groove Edges

NASA Astrophysics Data System (ADS)

Hussain, A.; Hamdani, A. H.; Akhter, R.; Aslam, M.

2013-06-01

Surface hardening of groove-edges made of 3Cr13 Stainless Steel has been carried out using 500 W CO2 laser with a rectangular beam of 2.5×3 mm2. The processing speed was varied from 150-500 mm/min. It was seen that the hardened depth increases with increase in laser interaction time. A maximum hardened depth of around 1mm was achieved. The microhardness of the transformed zone was 2.5 times the hardness of base metal. The XRD's and microstructural analysis were also reported.

Volcanic hazard management in dispersed volcanism areas

NASA Astrophysics Data System (ADS)

Marrero, Jose Manuel; Garcia, Alicia; Ortiz, Ramon

2014-05-01

Traditional volcanic hazard methodologies were developed mainly to deal with the big stratovolcanoes. In such type of volcanoes, the hazard map is an important tool for decision-makers not only during a volcanic crisis but also for territorial planning. According to the past and recent eruptions of a volcano, all possible volcanic hazards are modelled and included in the hazard map. Combining the hazard map with the Event Tree the impact area can be zoned and defining the likely eruptive scenarios that will be used during a real volcanic crisis. But in areas of disperse volcanism is very complex to apply the same volcanic hazard methodologies. The event tree do not take into account unknown vents, because the spatial concepts included in it are only related with the distance reached by volcanic hazards. The volcanic hazard simulation is also difficult because the vent scatter modifies the results. The volcanic susceptibility try to solve this problem, calculating the most likely areas to have an eruption, but the differences between low and large values obtained are often very small. In these conditions the traditional hazard map effectiveness could be questioned, making necessary a change in the concept of hazard map. Instead to delimit the potential impact areas, the hazard map should show the expected behaviour of the volcanic activity and how the differences in the landscape and internal geo-structures could condition such behaviour. This approach has been carried out in La Palma (Canary Islands), combining the concept of long-term hazard map with the short-term volcanic scenario to show the expected volcanic activity behaviour. The objective is the decision-makers understand how a volcanic crisis could be and what kind of mitigation measurement and strategy could be used.

Assessment of organic matter resistance to biodegradation in volcanic ash soils assisted by automated interpretation of infrared spectra from humic acid and whole soil samples by using partial least squares

NASA Astrophysics Data System (ADS)

Hernández, Zulimar; Pérez Trujillo, Juan Pedro; Hernández-Hernández, Sergio Alexander; Almendros, Gonzalo; Sanz, Jesús

2014-05-01

From a practical viewpoint, the most interesting possibilities of applying infrared (IR) spectroscopy to soil studies lie on processing IR spectra of whole soil (WS) samples [1] in order to forecast functional descriptors at high organizational levels of the soil system, such as soil C resilience. Currently, there is a discussion on whether the resistance to biodegradation of soil organic matter (SOM) depends on its molecular composition or on environmental interactions between SOM and mineral components, such could be the case with physical encapsulation of particulate SOM or organo-mineral derivatives, e.g., those formed with amorphous oxides [2]. A set of about 200 dependent variables from WS and isolated, ash free, humic acids (HA) [3] was obtained in 30 volcanic ash soils from Tenerife Island (Spain). Soil biogeochemical properties such as SOM, allophane (Alo + 1 /2 Feo), total mineralization coefficient (TMC) or aggregate stability were determined in WS. In addition, structural information on SOM was obtained from the isolated HA fractions by visible spectroscopy and analytical pyrolysis (Py-GC/MS). Aiming to explore the potential of partial least squares regression (PLS) in forecasting soil dependent variables, exclusively using the information extracted from WS and HA IR spectral profiles, data were processed by using ParLeS [4] and Unscrambler programs. Data pre-treatments should be carefully chosen: the most significant PLS models from IR spectra of HA were obtained after second derivative pre-treatment, which prevented effects of intrinsically broadband spectral profiles typical in macromolecular heterogeneous material such as HA. Conversely, when using IR spectra of WS, the best forecasting models were obtained using linear baseline correction and maximum normalization pre-treatment. With WS spectra, the most successful prediction models were obtained for SOM, magnetite, allophane, aggregate stability, clay and total aromatic compounds, whereas the PLS

7 CFR 58.622 - Hardening and storage rooms.

Code of Federal Regulations, 2013 CFR

2013-01-01

... 7 Agriculture 3 2013-01-01 2013-01-01 false Hardening and storage rooms. 58.622 Section 58.622....622 Hardening and storage rooms. Hardening and storage rooms for frozen desserts shall be constructed... insure adequate storage temperature (−10° or lower). Air shall be circulated to maintain uniform...

7 CFR 58.622 - Hardening and storage rooms.

Code of Federal Regulations, 2011 CFR

2011-01-01

... 7 Agriculture 3 2011-01-01 2011-01-01 false Hardening and storage rooms. 58.622 Section 58.622....622 Hardening and storage rooms. Hardening and storage rooms for frozen desserts shall be constructed... insure adequate storage temperature (−10° or lower). Air shall be circulated to maintain uniform...

7 CFR 58.622 - Hardening and storage rooms.

Code of Federal Regulations, 2010 CFR

2010-01-01

... 7 Agriculture 3 2010-01-01 2010-01-01 false Hardening and storage rooms. 58.622 Section 58.622....622 Hardening and storage rooms. Hardening and storage rooms for frozen desserts shall be constructed... insure adequate storage temperature (−10° or lower). Air shall be circulated to maintain uniform...

Structural heredity influence upon principles of strain wave hardening

NASA Astrophysics Data System (ADS)

Kiricheck, A. V.; Barinov, S. V.; Yashin, A. V.

2017-02-01

It was established experimentally that by penetration of a strain wave through material hardened not only the technological modes of processing, but also a technological heredity - the direction of the fibers of the original macrostructure have an influence upon the diagram of microhardness. By penetration of the strain wave along fibers, the degree of hardening the material is less, however, a product is hardened throughout its entire section mainly along fibers. In the direction of the strain waves across fibers of the original structure of material, the degree of material hardening is much higher, the depth of the hardened layer with the degree of hardening not less than 50% makes at least 3 mm. It was found that under certain conditions the strain wave can completely change the original structure of the material. Thus, a heterogeneously hardened structure characterized by the interchange of harder and more viscous areas is formed, which is beneficial for assurance of high operational properties of material.

Surface Coatings on Lunar Volcanic Glasses

NASA Technical Reports Server (NTRS)

Wentworth, Susan J.; McKay, D. S.; Thomas,-Keprta, K. L.; Clemett, S. J.

2007-01-01

We are undertaking a detailed study of surface deposits on lunar volcanic glass beads. These tiny deposits formed by vapor condensation during cooling of the gases that drove the fire fountain eruptions responsible for the formation of the beads. Volcanic glass beads are present in most lunar soil samples in the returned lunar collection. The mare-composition beads formed as a result of fire-fountaining approx.3.4-3.7 Ga ago, within the age range of large-scale mare volcanism. Some samples from the Apollo 15 and Apollo 17 landing sites are enriched in volcanic spherules. Three major types of volcanic glass bead have been identified: Apollo 15 green glass, Apollo 17 orange glass, and Apollo 17 "black" glass. The Apollo 15 green glass has a primitive composition with low Ti. The high-Ti compositions of the orange and black glasses are essentially identical to each other but the black glasses are opaque because of quench crystallization. A poorly understood feature common to the Apollo 15 and 17 volcanic glasses is the presence of small deposits of unusual materials on their exterior surfaces. For example, early studies indicated that the Apollo 17 orange glasses had surface enrichments of In, Cd, Zn, Ga, Ge, Au, and Na, and possible Pb- and Zn-sulfides, but it was not possible to characterize the surface features in detail. Technological advances now permit us to examine such features in detail. Preliminary FE-TEM/X-ray studies of ultramicrotome sections of Apollo 15 green glass indicate that the surface deposits are heterogeneous and layered, with an inner layer consisting of Fe with minor S and an outer layer of Fe and no S, and scattered Zn enrichments. Layering in surface deposits has not been identified previously; it will be key to defining the history of lunar fire fountaining.

Modern volcanic activity on the Moon

NASA Astrophysics Data System (ADS)

Vidmachenko, A. P.

2018-05-01

Volcanic activity on the Moon began when its surface cooled, and the nucleus and mantle were clearly separated inside. Fragments of volcanic eruptions were discovered in the lunar soil, which was delivered to the Earth by "Apollo" spacecrafts. As shown by the analysis of some lunar meteorites, the first eruptions occurred 4.35 billion years ago. This is evidenced by the unique composition of the oxygen atoms for the Moon and on the radiocarbon analysis data. Well-visible on its surface, the dark "seas", which emerged shortly after the formation of the Moon, when the lowlands and large old craters were filled by liquid basaltic magma, rich in iron. The lunar "seas" are mostly on the visible side of the Moon, and cover almost a third of it; on the reverse side-the seas occupy less than 2%. Smooth surfaces of the seas mean that the lunar lava was very liquid. Therefore, at low gravity, it easily spread over a large area, almost without creating large cone-shaped peaks, but forming many small cone volcanic systems with an age of 3-4 billion years ago. On the images of the visible side of the Moon obtained with the help of the LRO, evidence is provided that volcanic eruptions on its surface were possible even a few million years ago.

Precipitation and Hardening in Magnesium Alloys

NASA Astrophysics Data System (ADS)

Nie, Jian-Feng

2012-11-01

Magnesium alloys have received an increasing interest in the past 12 years for potential applications in the automotive, aircraft, aerospace, and electronic industries. Many of these alloys are strong because of solid-state precipitates that are produced by an age-hardening process. Although some strength improvements of existing magnesium alloys have been made and some novel alloys with improved strength have been developed, the strength level that has been achieved so far is still substantially lower than that obtained in counterpart aluminum alloys. Further improvements in the alloy strength require a better understanding of the structure, morphology, orientation of precipitates, effects of precipitate morphology, and orientation on the strengthening and microstructural factors that are important in controlling the nucleation and growth of these precipitates. In this review, precipitation in most precipitation-hardenable magnesium alloys is reviewed, and its relationship with strengthening is examined. It is demonstrated that the precipitation phenomena in these alloys, especially in the very early stage of the precipitation process, are still far from being well understood, and many fundamental issues remain unsolved even after some extensive and concerted efforts made in the past 12 years. The challenges associated with precipitation hardening and age hardening are identified and discussed, and guidelines are outlined for the rational design and development of higher strength, and ultimately ultrahigh strength, magnesium alloys via precipitation hardening.

Volcanic Supersites as cross-disciplinary laboratories

NASA Astrophysics Data System (ADS)

Provenzale, Antonello; Beierkuhnlein, Carl; Giamberini, Mariasilvia; Pennisi, Maddalena; Puglisi, Giuseppe

2017-04-01

Volcanic Supersites, defined in the frame of the GEO-GSNL Initiative, are usually considered mainly for their geohazard and geological characteristics. However, volcanoes are extremely challenging areas from many other points of view, including environmental and climatic properties, ecosystems, hydrology, soil properties and biogeochemical cycling. Possibly, volcanoes are closer to early Earth conditions than most other types of environment. During FP7, EC effectively fostered the implementation of the European volcano Supersites (Mt. Etna, Campi Flegrei/Vesuvius and Iceland) through the MED-SUV and FUTUREVOLC projects. Currently, the large H2020 project ECOPOTENTIAL (2015-2019, 47 partners, http://www.ecopotential-project.eu/) contributes to GEO/GEOSS and to the GEO ECO Initiative, and it is devoted to making best use of remote sensing and in situ data to improve future ecosystem benefits, focusing on a network of Protected Areas of international relevance. In ECOPOTENTIAL, remote sensing and in situ data are collected, processed and used for a better understanding of the ecosystem dynamics, analysing and modelling the effects of global changes on ecosystem functions and services, over an array of different ecosystem types, including mountain, marine, coastal, arid and semi-arid ecosystems, and also areas of volcanic origin such as the Canary and La Reunion Islands. Here, we propose to extend the network of the ECOPOTENTIAL project to include active Volcanic Supersites, such as Mount Etna and other volcanic Protected Areas, and we discuss how they can be included in the framework of the ECOPOTENTIAL workflow. A coordinated and cross-disciplinary set of studies at these sites should include geological, biological, ecological, biogeochemical, climatic and biogeographical aspects, as well as their relationship with the antropogenic impact on the environment, and aim at the global analysis of the volcanic Earth Critical Zone - namely, the upper layer of the Earth

Thermal properties and unfrozen water content of frozen volcanic ash as a modelling input parameters in mountainous volcanic areas

NASA Astrophysics Data System (ADS)

Kuznetsova, E.

2016-12-01

Volcanic eruptions are one of the major causes of the burial of ice and snow in volcanic areas. This has been demonstrated on volcanoes, e.g. in Iceland, Russia, USA and Chile, where the combination of a permafrost-favorable climate and a thin layer of tephra is sufficient to reduce the sub-tephra layer snow ablation substantially, even to zero, causing ground ice formation and permafrost aggradation. Many numerical models that have been used to investigate and predict the evolution of cold regions as the result of climatic changes are lacking the accurate data of the thermal properties —thermal conductivity, heat capacity, thermal diffusivity—of soils or debris layers involved. The angular shape of the fragments that make up ash and scoria makes it inappropriate to apply existing models to estimate bulk thermal conductivity. The lack of experimental data on the thermal conductivity of volcanic deposits will hinder the development of realistic models. The decreasing thermal conductivity of volcanic ash in the frozen state is associated with the development and presence of unfrozen water films that may have a direct mechanical impact on the movement or slippage between ice and particle, and thus, change the stress transfer. This becomes particularly significant during periods of climate change when enhanced temperatures and associated melting could weaken polythermal glaciers and affect areas with warm and discontinuous permafrost, and induce ice or land movements, perhaps on a catastrophic scale. In the presentation, we will summarize existing data regarding: (i) the thermal properties and unfrozen water content in frozen volcanic ash and cinder, (ii) the effects of cold temperatures on weathering processes of volcanic glass, (iii) the relationship between the mineralogy of frozen volcanic deposits and their thermal properties —and then discusses their significance in relation to the numerical modelling of glaciers and permafrost's thermal behavior.

High-Performance, Radiation-Hardened Electronics for Space Environments

NASA Technical Reports Server (NTRS)

Keys, Andrew S.; Watson, Michael D.; Frazier, Donald O.; Adams, James H.; Johnson, Michael A.; Kolawa, Elizabeth A.

2007-01-01

The Radiation Hardened Electronics for Space Environments (RHESE) project endeavors to advance the current state-of-the-art in high-performance, radiation-hardened electronics and processors, ensuring successful performance of space systems required to operate within extreme radiation and temperature environments. Because RHESE is a project within the Exploration Technology Development Program (ETDP), RHESE's primary customers will be the human and robotic missions being developed by NASA's Exploration Systems Mission Directorate (ESMD) in partial fulfillment of the Vision for Space Exploration. Benefits are also anticipated for NASA's science missions to planetary and deep-space destinations. As a technology development effort, RHESE provides a broad-scoped, full spectrum of approaches to environmentally harden space electronics, including new materials, advanced design processes, reconfigurable hardware techniques, and software modeling of the radiation environment. The RHESE sub-project tasks are: SelfReconfigurable Electronics for Extreme Environments, Radiation Effects Predictive Modeling, Radiation Hardened Memory, Single Event Effects (SEE) Immune Reconfigurable Field Programmable Gate Array (FPGA) (SIRF), Radiation Hardening by Software, Radiation Hardened High Performance Processors (HPP), Reconfigurable Computing, Low Temperature Tolerant MEMS by Design, and Silicon-Germanium (SiGe) Integrated Electronics for Extreme Environments. These nine sub-project tasks are managed by technical leads as located across five different NASA field centers, including Ames Research Center, Goddard Space Flight Center, the Jet Propulsion Laboratory, Langley Research Center, and Marshall Space Flight Center. The overall RHESE integrated project management responsibility resides with NASA's Marshall Space Flight Center (MSFC). Initial technology development emphasis within RHESE focuses on the hardening of Field Programmable Gate Arrays (FPGA)s and Field Programmable Analog

Rare earth elements distribution in grapevine varieties grown on volcanic soils: an example from Mount Etna (Sicily, Italy).

PubMed

D'Antone, Carmelisa; Punturo, Rosalda; Vaccaro, Carmela

2017-04-01

A geochemical and statistical approach has allowed identifying in rare earth elements (REEs) absorption a good fingerprinting mark for determining the territoriality and the provenance of Vitis vinifera L. in the district of Mount Etna (southern Italy). Our aim is to define the REEs distribution in different parts of the plants which grow in the same volcanic soil and under the same climate conditions, and therefore to assess whether REEs distribution may reflect the composition of the provenance soil or if plants can selectively absorb REEs in order to recognize the fingerprint in the Etna Volcano soils as well as the REEs pattern characteristic of each cultivar of V. vinifera L. The characteristic pattern of REEs has been determined by ICP-MS analyses in the soils and in the selected grapevine varieties for all the following parts: leaves, seeds, juice, skin, and berries. These geochemical criteria, together with the multivariate statistical analysis of the principal component analysis (PCA) and of the linear discriminant analysis (LDA) that can be summarized with the box plot, suggest that leaves mostly absorb REEs than the other parts of the plant. This work investigates the various parts of the plant in order to verify if each grape variety presents a characteristic geochemical pattern in the absorption of REEs in relationship with the geochemical features of the soil so to highlight the individual compositional fingerprint. Based on REE patterns, our study is a useful tool that allows characterizing the differences among the grape varieties and lays the foundation for the use of REEs in the geographic origin of the Mount Etna wine district.

Radiation Hardened DDR2 SDRAM Solution

NASA Astrophysics Data System (ADS)

Wang, Pierre-Xiao; Sellier, Charles

2016-08-01

The Radiation Hardened (RH) DDR2 SDRAM Solution is a User's Friendly, Plug-and-Play and Radiation Hardened DDR2 solution, which includes the radiation tolerant stacking DDR2 modules and a radiation intelligent memory controller (RIMC) IP core. It provides a high speed radiation hardened by design DRAM solution suitable for all space applications such as commercial or scientific geo-stationary missions, earth observation, navigation, manned space vehicles and deep space scientific exploration. The DDR2 module has been guaranteed with SEL immune and TID > 100Krad(Si), on the other hand the RIMC IP core provides a full protection against the DDR2 radiation effects such as SEFI and SEU.

Catastrophic volcanism

NASA Technical Reports Server (NTRS)

Lipman, Peter W.

1988-01-01

Since primitive times, catastrophes due to volcanic activity have been vivid in the mind of man, who knew that his activities in many parts of the world were threatened by lava flows, mudflows, and ash falls. Within the present century, increasingly complex interactions between volcanism and the environment, on scales not previously experienced historically, have been detected or suspected from geologic observations. These include enormous hot pyroclastic flows associated with collapse at source calderas and fed by eruption columns that reached the stratosphere, relations between huge flood basalt eruptions at hotspots and the rifting of continents, devastating laterally-directed volcanic blasts and pyroclastic surges, great volcanic-generated tsunamis, climate modification from volcanic release of ash and sulfur aerosols into the upper atmosphere, modification of ocean circulation by volcanic constructs and attendent climatic implications, global pulsations in intensity of volcanic activity, and perhaps triggering of some intense terrestrial volcanism by planetary impacts. Complex feedback between volcanic activity and additional seemingly unrelated terrestrial processes likely remains unrecognized. Only recently has it become possible to begin to evaluate the degree to which such large-scale volcanic processes may have been important in triggering or modulating the tempo of faunal extinctions and other evolutionary events. In this overview, such processes are examined from the viewpoint of a field volcanologist, rather than as a previous participant in controversies concerning the interrelations between extinctions, impacts, and volcanism.

Land use and Hydrological Characteristics of Volcanic Urban Soils for Flood Susceptibility Modeling, Ciudad de Colima (Mexico)

NASA Astrophysics Data System (ADS)

Perez Gonzalez, M. L.; Capra, L.; Borselli, L.; Ortiz, A.

2015-12-01

The fast population rate growth and the unplanned urban development has created an increase of urban floods in the City of Colima. Land use change has transformed the hydrological behavior of the watersheds that participates on the runoff-infiltration processes that governs the pluvial concentrations. After the urban areas enlargement, 13% from 2010 to 2015, rainfall has caused significant damages to the downtown community. Therefore it is important to define the main hydraulic properties of the soils surrounding the city. The soil of the region is derived from the debris avalanche deposits of the Volcano of Colima. The volcanic soil cover is only 10 to 15 cm depth. To test the soils of the region, sampling locations were chosen after making a land use map from a Landsat image. The map was done by selecting and dividing similar surface images patterns into three main classifications: Natural (N1), Agricultural (N5) and Urban (N4) surfaces. Thirty-Three soil samples were collected and grouped in nine out of ten land use subdivisions. The 10thsubdivision, represents the completed urbanized area. The land use model is made using spot 4 1A images from the year 2010 up to year 2015. This land use evolutionary analysis will be a base to evaluate the change of the runoff-infiltration rate, direction, and concentration areas for the future flood susceptibility model. To get the parameters above, several soil analysis were performed. The results were that all the soil samples tested were classified as sandy soils. The water content values were from 7% (N4) to 45% (N1) while bulk density values for the same sample were form 0.65 (N1) to 1.50 (N4) g/cm3. The particle density and the porosity values were from 1.65 g/cm3 /5.5% (N4) - 2.65 g/cm3/ 75.40% (N1). The organic matter content was around 0.1% for urban soils and up to 6% on natural and agricultural soils. Some other test like electric conductivity and pH were performed. The obtained parameters were used to get other

Ammonia emission from a permanent grassland on volcanic soil after the treatment with dairy slurry and urea

NASA Astrophysics Data System (ADS)

Salazar, F.; Martínez-Lagos, J.; Alfaro, M.; Misselbrook, T.

2014-10-01

Ammonia (NH3) is an air pollutant largely emitted from agricultural activities including the application of livestock manures and fertilizers to grassland. This gas has been linked with important negative impacts on natural ecosystems. In southern Chile, the use of inorganic and organic fertilizers (e.g. slurries) has increased in cattle production systems over recent years, heightening the risk of N losses to the wider environment. The objectives of this study were to evaluate on permanent grasslands on a volcanic ash soil in southern Chile: 1) the N loss due to NH3 volatilization following surface application of dairy slurry and urea fertilizer; and 2) the effect of a urease inhibitor on NH3 emissions from urea fertilizer application. Small plot field experiments were conducted over spring, fall, winter and summer seasons, using a system of wind tunnels to measure ammonia emissions. Ammonia losses ranged from 1.8 (winter) to 26.0% (fall) and 3.1 (winter) to 20.5% (summer) of total N applied for urea and slurry, respectively. Based on the readily available N applied (ammoniacal N for dairy slurry and urea N for urea fertilizer), losses from dairy slurry were much greater, at 16.1 and 82.0%, for winter and summer, respectively. The use of a urease inhibitor proved to be an effective option to minimize the N loss due NH3 volatilization from urea fertilizer, with an average reduction of 71% across all seasons. The results of this and other recent studies regarding N losses suggest that ammonia volatilization is the main pathway of N loss from grassland systems in southern Chile on volcanic ash soils when urea and slurry are used as an N source. The use of good management practices, such as the inclusion of a urease inhibitor with urea fertilizer could have a beneficial impact on reducing N losses due NH3 volatilization and the environmental and economic impact of these emissions.

The effect of Sinabung volcanic ash and rock phosphate nanoparticle on CEC (cation exchange capacity) base saturation exchange (K, Na, Ca, Mg) and base saturation at Andisol soils Ciater, West Java

NASA Astrophysics Data System (ADS)

Yuniarti, Anni; Arifin, Mahfud; Sofyan, Emma Trinurasi; Natalie, Betty; Sudirja, Rija; Dahliani, Dewi

2018-02-01

Andisol, soil orders which covers an upland area dominantly. The aim of this research is to know the effect between the ameliorant of Sinabung volcanic ashes with the ameliorant of rock phosphatenanoparticle towards CEC and base saturation exchange (K, Na, Ca, Mg) and the base saturation on Ciater's Andisols, West Java. A randomized complete block design (RCBD) factorial with two factors was used in this research. The first factor is the volcanic ash and the second factor is rock phosphate which consists of four levels each amount of 0%, 2.5%, 5%, 7.5% with three replications. The result showed that there was no interaction between volcanic ash and rock phosphate nanoparticle formed in first month and fourth month towards the improvement of CEC and saturation base exchange rate unless magnesium cation exchange increased in fourth month. There was independent effect of volcanic ash formed nanoparticles towards base saturation exchange increased for 5% dose. There was independent effect of rock phosphate formed nanoparticles towards base saturation exchange and increased for 5% dose. The dose combination of volcanic ashes 7.5% with phosphate rock, 5% increased the base saturation in the first month incubation.

Secular Variations of Soil CO2 Efflux at Santa Ana-Izalco-Coatepeque Volcanic Complex, El Salvador, Central America

NASA Astrophysics Data System (ADS)

Olmos, R.; Barahona, F.; Cartagena, R.; Soriano, T.; Salazar, J.; Hernandez, P.; Perez, N.; Lopez, D.

2002-12-01

The Santa Ana-Izalco-Coatepeque volcanic complex (2,365 m elevation), located 40 Km west of San Salvador, consists of the Coatepeque collapse caldera (a 6.5 x 10.5 Km elliptical depression), the Santa Ana and Izalco stratovolcanoes, as well as numerous cinder cones and explosion craters. The summit of the Santa Ana volcano contains an acid lake where hot springs, gas bubbling and intense fumarolic emissions occur. A volcanic plume, usually driven by the NE trades, may be seen rising up to 500 m from the summit crater of the Santa Ana volcano. The goal of this study is to provide a multidisciplinary approach for the volcanic surveillance by means of performing geochemical continuous monitoring of diffuse CO2 emission rate in addition to seismic monitoring. Temporal variations of soil CO2 efflux measured at Cerro Pacho dome, Coatepeque caldera, by means of the accumulation chamber method and using a CO2 efflux continuous monitoring station developed by WEST Systems (Italy). From May 2001 till May 2002, CO2 efflux ranged from 4.3 to 327 gm-2d-1, with a median value of 98 and a quartile range of 26 gm-2d-1. Two distinct diffuse CO2 degassing periods have been observed: (1) an increasing trend from May to July 2001, and (2) a stationary period from November 2001 to May 2002. The increasing-trend period may be due to the anomalous plume degassing at the Santa Ana volcano during 2001 and soon after the January and February 2001 earthquakes. Temporal variations of CO2 efllux during the second period seem to be coupled with those of barometric pressure and wind speed at different time scales, though most of the variance is contained at diurnal and semi-diurnal frequencies. These observations can help to explain the existence of a persistent behavior (Hurst exponent, H=0.934 +/- 0.0039) within the diffuse CO2 degassing phenomena. However, further observations are in progress to understand the long-term memory of diffuse CO2 degassing at the Santa Ana volcanic complex.

Formation and deposition of volcanic sulfate aerosols on Mars

NASA Technical Reports Server (NTRS)

Settle, M.

1979-01-01

The paper considers the formation and deposition of volcanic sulfate aerosols on Mars. The rate limiting step in sulfate aerosol formation on Mars is the gas phase oxidation of SO2 by chemical reactions with O, OH, and HO2; submicron aerosol particles would circuit Mars and then be removed from the atmosphere by gravitational forces, globally dispersed, and deposited over a range of equatorial and mid-latitudes. Volcanic sulfate aerosols on Mars consist of liquid droplets and slurries containing sulfuric acid; aerosol deposition on a global or hemispheric scale could account for the similar concentrations of sulfur within surficial soils at the two Viking lander sites.

Multi-disciplinary approach in volcanic areas: case study of Kamchatka, Far East of Russia

NASA Astrophysics Data System (ADS)

Kuznetsova, Elena

2017-04-01

Volcanic ash is associated with a considerable proportion of the Earth's land surface. At the same time, it is estimated that 15% of the land surface is affected by permafrost and glacial ice. As a consequences volcanic ash may play an important role in the aggradation and degradation of cold regions (Kellerer-Pirklbauer et al., 2007; Froese et al., 2008). An understanding of the influence of volcanic ash on these frozen areas allows for more accurate prediction of their stability in the future and provides a better knowledge of the factors affecting past climates, soils and soil stability. Vital to making accurate predictions is an understanding of the thermal properties of volcanic ash (Juen et al., 2013). For example, even for the same region of Kamchatka in eastern Russia volcanic ash may have not only different ages, different chemical composition of the glass, but also different weathering stages, mineralogical composition, and water saturation, furthermore, these ashes may be permanently frozen or unfrozen, all of which may affect their thermal properties (Kuznetsova & Motenko, 2014). These differences might be the reason why the critical thickness of tephra, at which the effect on ice and snow is rather insulating than ablative, for the volcanic material from different volcanoes may vary so much. The determined values of critical thickness deviate from 24 mm reported by Driedger (1980) for the glaciers at Mt. St. Helens, USA, and by (Manville et al., 2000) for tephra erupted in 1996 by Mt. Ruapehu, New Zealand, to <5.5 mm for tephra from the 1947 eruption of Hekla volcano and from Villarica volcano, Chile, reported by Kirkbride and Dugmore (2003) and by Brock et al. (2007). So far the reasons of disparity are not known. Ayris and Delmelle (2012) assumed that the particle size and porosity might be the reason. Taking into considerations that during ablation period tephra covering the glaciers is wet, thermal conductivity of this material should not be

7 CFR 58.641 - Hardening and storage.

Code of Federal Regulations, 2011 CFR

2011-01-01

... 7 Agriculture 3 2011-01-01 2011-01-01 false Hardening and storage. 58.641 Section 58.641 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Standards... Procedures § 58.641 Hardening and storage. Immediately after the semifrozen product is placed in its intended...

7 CFR 58.641 - Hardening and storage.

Code of Federal Regulations, 2010 CFR

2010-01-01

... 7 Agriculture 3 2010-01-01 2010-01-01 false Hardening and storage. 58.641 Section 58.641 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Standards... Procedures § 58.641 Hardening and storage. Immediately after the semifrozen product is placed in its intended...

7 CFR 58.641 - Hardening and storage.

Code of Federal Regulations, 2013 CFR

2013-01-01

... 7 Agriculture 3 2013-01-01 2013-01-01 false Hardening and storage. 58.641 Section 58.641 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Standards... Procedures § 58.641 Hardening and storage. Immediately after the semifrozen product is placed in its intended...

Descartes region - Evidence for Copernican-age volcanism.

NASA Technical Reports Server (NTRS)

Head, J. W., III; Goetz, A. F. H.

1972-01-01

A model that suggests that the high-albedo central region of the Descartes Formation was formed by Copernican-age volcanism was developed from Orbiter photography, Apollo 12 multispectral photography, earth-based spectrophotometry, and thermal IR and radar data. The bright surface either is abundant in centimeter-sized rocks or is formed from an insulating debris layer overlying a surface with an abundance of rocks in the 1- to 20-cm size range. On the basis of these data, the bright unit is thought to be a young pyroclastic deposit mantling older volcanic units of the Descartes Formation. Since the Apollo 16 target point is only 50 km NW of the central part of this unit, evidence for material associated with this unique highland formation should be searched for in returned soil and rock samples.

Characterization of Early Microbial Communities on Volcanic Deposits along a Vegetation Gradient on the Island of Miyake, Japan

PubMed Central

Guo, Yong; Fujimura, Reiko; Sato, Yoshinori; Suda, Wataru; Kim, Seok-won; Oshima, Kenshiro; Hattori, Masahira; Kamijo, Takashi; Narisawa, Kazuhiko; Ohta, Hiroyuki

2014-01-01

The 2000 eruption of Mount Oyama on the island of Miyake (Miyake-jima) created a unique opportunity to study the early ecosystem development on newly exposed terrestrial substrates. In this study, bacterial and fungal communities on 9- and 11-year-old volcanic deposits at poorly to fully vegetation-recovered sites in Miyake-jima, Japan, were characterized by conventional culture-based methods and pyrosequencing of 16S rRNA and 18S rRNA genes. Despite the differences in the vegetation cover, the upper volcanic deposit layer samples displayed low among-site variation for chemical properties (pH, total organic carbon, and total nitrogen) and microbial population densities (total direct count and culturable count). Statistical analyses of pyrosequencing data revealed that the microbial communities of volcanic deposit samples were phylogenetically diverse, in spite of very low-carbon environmental conditions, and their diversity was comparable to that in the lower soil layer (buried soil) samples. Comparing with the microbial communities in buried soil, the volcanic deposit communities were characterized by the presence of Betaproteobacteria and Gammaproteobacteria as the main bacterial class, Deinococcus- Thermus as the minor bacterial phyla, and Ascomycota as the major fungal phyla. Multivariate analysis revealed that several bacterial families and fungal classes correlated positively or negatively with plant species. PMID:24463576

Preliminary geologic map of the Sleeping Butte volcanic centers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Crowe, B.M.; Perry, F.V.

1991-07-01

The Sleeping Butte volcanic centers comprise two, spatially separate, small-volume (<0.1 km{sup 3}) basaltic centers. The centers were formed by mildly explosive Strombolian eruptions. The Little Black Peak cone consists of a main scoria cone, two small satellitic scoria mounds, and associated lobate lava flows that vented from sites at the base of the scoria cone. The Hidden Cone center consists of a main scoria cone that developed on the north-facing slope of Sleeping Butte. The center formed during two episodes. The first included the formation of the main scoria cone, and venting of aa lava flows from radial dikesmore » at the northeast base of the cone. The second included eruption of scoria-fall deposits from the summit crater. The ages of the Little Black Peak and the Hidden Cone are estimated to be between 200 to 400 ka based on the whole-rock K-Ar age determinations with large analytical undertainty. This age assignment is consistent with qualitative observations of the degree of soil development and geomorphic degradation of volcanic landforms. The younger episode of the Hidden Cone is inferred to be significantly younger and probably of Late Pleistocene or Holocene age. This is based on the absence of cone slope rilling, the absence of cone-slope apron deposits, and erosional unconformity between the two episodes, the poor horizon- development of soils, and the presence of fall deposits on modern alluvial surfaces. Paleomagnetic data show that the centers record similar but not identical directions of remanent magnetization. Paleomagnetic data have not been obtained for the youngest deposits of the Hidden Cone center. Further geochronology, soils, geomorphic, and petrology studies are planned of the Sleeping Butte volcanic centers 20 refs., 3 figs.« less

Beam hardening and partial beam hardening of the bowtie filter: Effects on dosimetric applications in CT

NASA Astrophysics Data System (ADS)

Lopez-Rendon, X.; Zhang, G.; Bosmans, H.; Oyen, R.; Zanca, F.

2014-03-01

Purpose: To estimate the consequences on dosimetric applications when a CT bowtie filter is modeled by means of full beam hardening versus partial beam hardening. Method: A model of source and filtration for a CT scanner as developed by Turner et. al. [1] was implemented. Specific exposures were measured with the stationary CT X-ray tube in order to assess the equivalent thickness of Al of the bowtie filter as a function of the fan angle. Using these thicknesses, the primary beam attenuation factors were calculated from the energy dependent photon mass attenuation coefficients and used to include beam hardening in the spectrum. This was compared to a potentially less computationally intensive approach, which accounts only partially for beam hardening, by giving the photon spectrum a global (energy independent) fan angle specific weighting factor. Percentage differences between the two methods were quantified by calculating the dose in air after passing several water equivalent thicknesses representative for patients having different BMI. Specifically, the maximum water equivalent thickness of the lateral and anterior-posterior dimension and of the corresponding (half) effective diameter were assessed. Results: The largest percentage differences were found for the thickest part of the bowtie filter and they increased with patient size. For a normal size patient they ranged from 5.5% at half effective diameter to 16.1% for the lateral dimension; for the most obese patient they ranged from 7.7% to 19.3%, respectively. For a complete simulation of one rotation of the x-ray tube, the proposed method was 12% faster than the complete simulation of the bowtie filter. Conclusion: The need for simulating the beam hardening of the bow tie filter in Monte Carlo platforms for CT dosimetry will depend on the required accuracy.

Volcanic Aerosol Phosphorus, Chlorine, and Sulfur at Kilauea, Hawaii

DOE Office of Scientific and Technical Information (OSTI.GOV)

Darzi, M.; Winchester, J.W.

1982-12-20

Aerosol concentrations of P, Cl, S, and major soil-derived elements were measured sequentially at the Hawaiian Volcano Observatory (HVO) from March to September 1979, with 3.7-hour time resolution using a Nucleopore-filter sampler. The filters were analyzed by particle-induced X ray emission (PIXE). Comparison with diurnal variations in the air flow inferred from major soil elements, e.g., Fe, as well as measurements made previously at fumaroles near HVO, indicate that the P, C. and S may be attributed mainly to volcanic emissions from Kilauea. From April 23 to June 30, P was found with concentrations up to 1000 ng m/sup -3/;more » but before and after those dates, P was generally below the detection limit of 50--80 ng m/sup -3/. Cl and S were frequently found over the entire sampling period, also with concentrations up to 1000 ng m/sup -3/. However, when P was found, Cl was almost never detected simultaneously. The mutually exclusive occurrences of P and Cl suggest volatility release of HCl from aerosol particles by reaction with strong acid associated with P. If strong acidity is due to H/sub 2/SO/sub 4/, it is not well predicted by S, which may also include other sulfates or sulfur, since aerosol S concentrations are not well correlated with P or Cl. The behavior of these three elements suggests that the volcanic sources of P are more localized than those of Cl or S. It is significant that concentrations of aerosol P can be as high as aerosol Cl and S, all apparently of primary volcanic origin, indicating that volcanism may be an important, but hitherto unrecognized, process in the atmosphere goechemical cycling of phosphorus.« less

Prediction of soil organic carbon with different parent materials development using visible-near infrared spectroscopy.

PubMed

Liu, Jinbao; Han, Jichang; Zhang, Yang; Wang, Huanyuan; Kong, Hui; Shi, Lei

2018-06-05

The storage of soil organic carbon (SOC) should improve soil fertility. Conventional determination of SOC is expensive and tedious. Visible-near infrared reflectance spectroscopy is a practical and cost-effective approach that has been successfully used SOC concentration. Soil spectral inversion model could quickly and efficiently determine SOC content. This paper presents a study dealing with SOC estimation through the combination of soil spectroscopy and stepwise multiple linear regression (SMLR), partial least squares regression (PLSR), principal component regression (PCR). Spectral measurements for 106 soil samples were acquired using an ASD FieldSpec 4 standard-res spectroradiometer (350-2500 nm). Six types of transformations and three regression methods were applied to build for the quantification of different parent materials development soil. The results show that (1)the basaltic volcanic clastics development of SOC spectral response bands located in 500 nm, 800 nm; Trachyte spectral response of the soil quality, and the volcanic clastics development at 405 nm, 465 nm, 575 nm, 1105 nm. (2) Basaltic volcanic debris soil development, first deviation of maximum correlation coefficient is 0.8898; thick surface soil of the development of rocky volcanic debris from bottom reflectivity logarithm of first deviation of maximum correlation coefficient is 0.9029. (3) Soil organic matter content of basaltic volcanic clastics development optimal prediction model based on spectral reflectance inverse logarithms of first deviation of SMLR. Independent variable number is 7, Rv 2  = 0.9720, RMSEP = 2.0590, sig = 0.003. Trachyte qualitative volcanic clastics developed soil organic matter content of the optimal prediction model based on spectral reflectance inverse logarithms of first deviation of PLSR. Model number of the independent variables Pc = 5, Rc = 0.9872, Rc 2  = 0.9745, RMSEC = 0.4821, SEC = 0.4906, forecasts determine

First application of the WEPP model to predict runoff and erosion risk in fire-affected volcanic areas in Europe

NASA Astrophysics Data System (ADS)

Neris, Jonay; Robichaud, Peter R.; Elliot, William J.; Doerr, Stefan H.; Notario del Pino, Jesús S.; Lado, Marcos

2017-04-01

An estimated that 15% of the world's population lives in volcanic areas. Recent catastrophic erosion events following wildfires in volcanic terrain have highlighted the geomorphological instability of this soil type under disturbed conditions and steep slopes. Predicting the hydrological and erosional response of this soils in the post-fire period is the first step to design and develop adequate actions to minimize risks in the post-fire period. In this work we apply, for the first time, the Water Erosion Prediction Project model for predicting erosion and runoff events in fire-affected volcanic soils in Europe. Two areas affected by wildfires in 2015 were selected in Tenerife (Spain) representative of different fire behaviour (downhill surface fire with long residence time vs uphill crown fire with short residence time), severity (moderate soil burn severity vs light soil burn severity) and climatic conditions (average annual precipitation of 750 and 210 mm respectively). The actual erosion processes were monitored in the field using silt fences. Rainfall and rill simulations were conducted to determine hydrologic, interrill and rill erosion parameters. The soils were sampled and key properties used as model input, evaluated. During the first 18 months after the fire 7 storms produced runoff and erosion in the selected areas. Sediment delivery reached 5.4 and 2.5 Mg ha-1 respectively in the first rainfall event monitored after the fire, figures comparable to those reported for fire-affected areas of the western USA with similar climatic conditions but lower than those showed by wetter environments. The validation of the WEPP model using field data showed reasonable estimates of hillslope sediment delivery in the post-fire period and, therefore, it is suggested that this model can support land managers in volcanic areas in Europe in predicting post-fire hydrological and erosional risks and designing suitable mitigation treatments.

Microscopic Origin of Strain Hardening in Methane Hydrate

PubMed Central

Jia, Jihui; Liang, Yunfeng; Tsuji, Takeshi; Murata, Sumihiko; Matsuoka, Toshifumi

2016-01-01

It has been reported for a long time that methane hydrate presents strain hardening, whereas the strength of normal ice weakens with increasing strain after an ultimate strength. However, the microscopic origin of these differences is not known. Here, we investigated the mechanical characteristics of methane hydrate and normal ice by compressive deformation test using molecular dynamics simulations. It is shown that methane hydrate exhibits strain hardening only if the hydrate is confined to a certain finite cross-sectional area that is normal to the compression direction. For normal ice, it does not present strain hardening under the same conditions. We show that hydrate guest methane molecules exhibit no long-distance diffusion when confined to a finite-size area. They appear to serve as non-deformable units that prevent hydrate structure failure, and thus are responsible for the strain-hardening phenomenon. PMID:27009239

Rates of soil development from four soil chronosequences in the southern Great Basin

USGS Publications Warehouse

Harden, J.W.; Taylor, E.M.; Hill, C.; Mark, R.K.; McFadden, L.D.; Reheis, M.C.; Sowers, J.M.; Wells, S.G.

1991-01-01

Four soil chronosequences in the southern Great Basin were examined in order to study and quantify soil development during the Quaternary. Soils of all four areas are developed in gravelly alluvial fans in semiarid climates with 8 to 40 cm mean annual precipitation. Lithologies of alluvium are granite-gneiss at Silver Lake, granite and basalt at Cima Volcanic Field, limestone at Kyle Canyon, and siliceous volcanic rocks at Fortymile Wash. Ages of the soils are approximated from several radiometric and experimental techniques, and rates are assessed using a conservative mathematical approach. Average rates for Holocene soils at Silver Lake are about 10 times higher than for Pleistocene soils at Kyle Canyon and Fortymile Wash, based on limited age control. Holocene soils in all four areas appear to develop at similar rates, and Pleistocene soils at Kyle Canyon and Fortymile Wash may differ by only a factor of 2 to 4. Over time spans of several millennia, a preferred model for the age curves is not linear but may be exponential or parabolic, in which rates decrease with increasing age. These preliminary results imply that the geographical variation in rates within the southern Great Basin-Mojave region may be much less significant than temporal variation in rates of soil development. The reasons for temporal variation in rates and processes of soil development are complexly linked to climatic change and related changes in water and dust, erosional history, and internally driven chemical and physical processes. ?? 1991.

Sulfate Formation on Mars by Volcanic Aerosols: A New Look

NASA Astrophysics Data System (ADS)

Blaney, D. L.

1996-03-01

Sulfur was measured at both Viking Lander sites in abundances of 5-9 wt % SO3. Because the sulfur was more concentrated in clumps which disintegrated and the general oxidized nature of the Martian soil, these measurements led to the assumption that a sulfate duricrust existed. Two types of models for sulfate formation have been proposed. One is a formation by upwardly migrating ground water. The other is the formation of sulfates by the precipitation of volcanic aerosols. Most investigators have tended to favor the ground water origin of sulfates on Mars. However, evidence assemble since Viking may point to a volcanic aerosol origin.

Technology Developments in Radiation-Hardened Electronics for Space Environments

NASA Technical Reports Server (NTRS)

Keys, Andrew S.; Howell, Joe T.

2008-01-01

The Radiation Hardened Electronics for Space Environments (RHESE) project consists of a series of tasks designed to develop and mature a broad spectrum of radiation hardened and low temperature electronics technologies. Three approaches are being taken to address radiation hardening: improved material hardness, design techniques to improve radiation tolerance, and software methods to improve radiation tolerance. Within these approaches various technology products are being addressed including Field Programmable Gate Arrays (FPGA), Field Programmable Analog Arrays (FPAA), MEMS, Serial Processors, Reconfigurable Processors, and Parallel Processors. In addition to radiation hardening, low temperature extremes are addressed with a focus on material and design approaches. System level applications for the RHESE technology products are discussed.

Thermography of volcanic areas on Piton de la Fournaise, Reunion Island : Mapping surface properties and possible detection of convective air flow within volcanic debris

NASA Astrophysics Data System (ADS)

Antoine, R.; Baratoux, D.; Rabinowicz, M.; Saracco, G.; Bachelery, P.; Staudacher, T.; Fontaine, F.

2007-12-01

We report on the detection of air convection in a couple of quasi circular cavities forming the 300 years old volcanically inactive cone of Formica Leo (Piton de la Fournaise, Reunion Island) [1]. Infrared thermal images of the cone have been acquired in 2006 from a hand held camera at regular time interval during a complete diurnal cycle. During night and dawn, the data display hot rims and cold centers. Both the conductivity contrasts of the highly porous soils filling the cavities and their 30° slopes are unable to explain the systematic rim to center temperature drop. Accordingly, this signal could be attributed to an air convection dipping inside the highly porous material at the center of each cavity, then flowing upslope along the base of the soil layer, before exiting it along the rims. Anemometrical and electrical data acquired in 2007 allow for the first time the direct detection of this air flow on the field: dipping gas velocities are measured at the center of the cone and self-potentials anomalies [2] generated by the humid air flow in the porous medium are detected. To quantify this process, we present 2D/3D numerical models of air convection in a sloped volcanic soil with a surface temperature evolving between day and night and taking into account electrical phenomena created by the air flow. At this present stage, this work constitutes a first step to investigate the deep structure of the active caldera of Bory-Dolomieu. The detection of the air flow at the surface could be of paramount importance for the understanding of volcanic hazards of the Reunion volcano. [1] Antoine et. al, submitted to G-Cubed [2] Darnet, PhD, Université Louis Pasteur (2003)

Monitoring diffuse volcanic degassing during volcanic unrests: the case of Campi Flegrei (Italy).

PubMed

Cardellini, C; Chiodini, G; Frondini, F; Avino, R; Bagnato, E; Caliro, S; Lelli, M; Rosiello, A

2017-07-28

In volcanoes with active hydrothermal systems, diffuse CO 2 degassing may constitute the primary mode of volcanic degassing. The monitoring of CO 2 emissions can provide important clues in understanding the evolution of volcanic activity especially at calderas where the interpretation of unrest signals is often complex. Here, we report eighteen years of CO 2 fluxes from the soil at Solfatara of Pozzuoli, located in the restless Campi Flegrei caldera. The entire dataset, one of the largest of diffuse CO 2 degassing ever produced, is made available for the scientific community. We show that, from 2003 to 2016, the area releasing deep-sourced CO 2 tripled its extent. This expansion was accompanied by an increase of the background CO 2 flux, over most of the surveyed area (1.4 km 2 ), with increased contributions from non-biogenic source. Concurrently, the amount of diffusively released CO 2 increased up to values typical of persistently degassing active volcanoes (up to 3000 t d -1 ). These variations are consistent with the increase in the flux of magmatic fluids injected into the hydrothermal system, which cause pressure increase and, in turn, condensation within the vapor plume feeding the Solfatara emission.

Influences of quaternary climatic changes on processes of soil development on desert loess deposits of the Cima volcanic field, California

USGS Publications Warehouse

McFadden, L.D.; Wells, S.G.; Dohrenwend, J.C.

1986-01-01

Soils formed in loess are evidence of both relict and buried landscapes developed on Pliocene-to-latest Pleistocene basalt flows of the Cima volcanic field in the eastern Mojave Desert, California. The characteristics of these soils change systematically and as functions of the age and surface morphology of the lava flow. Four distinct phases of soil development are recognized: phase 1 - weakly developed soils on flows less than 0.18 M.y. old; phase 2 - strongly developed soils with thick argillic horizons on 0.18 - 0.7 M.y. old flows; phase 3 - strongly developed soils with truncated argillic horizons massively impregnated by carbonate on 0.7 to 1.1 M.y. old flows; and phase 4 - degraded soils with petrocalcic rubble on Pliocene flows. A critical aspect of the development of stage 1 soils is the evolution of a vesicular A horizon which profoundly affects the infiltration characteristics of the loess parent materials. Laboratory studies show that secondary gypsum and possibly other salt accumulation probably occurred during the period of phase 1 soil development. Slight reddening of the interiors of peds from vesicular-A horizons of phase 1 soils and presence of weakly developed B horizons indicates a slight degree of in situ chemical alteration. However, clay and Fe oxide contents of these soils show that these constituents, as well as carbonates and soluble salts, are incorporated as eolian dust. In contrast to phase 1 soils, chemical and mineralogical analysis of argillic horizons of phase 2 soils indicate proportionally greater degrees of in-situ chemical alteration. These data, the abundant clay films, and the strong reddening in the thick argillic horizons suggest that phase 2 and phase 3 soils formed during long periods of time and periodically were subjected to leaching regimes more intense than those that now exist. Flow-age data and soil-stratigraphic evidence also indicate that several major loess-deposition events occurred during the past ??? 1.0 M

Mechanism of work hardening in Hadfield manganese steel

NASA Astrophysics Data System (ADS)

Dastur, Y. N.; Leslie, W. C.

1981-05-01

When Hadfield manganese steel in the single-phase austenitic condition was strained in tension, in the temperature range - 25 to 300 °C, it exhibited jerky (serrated) flow, a negative (inverse) strain-rate dependence of flow stress and high work hardening, characteristic of dynamic strain aging. The strain rate-temperature regime of jerky flow was determined and the apparent activation energies for the appearance and disappearance of serrations were found to be 104 kJ/mol and 146 kJ/mol, respectively. The high work hardening cannot be a result of mechanical twinning because at -50 °C numerous twins were produced, but the work hardening was low and no twins were formed above 225 °C even though work hardening was high. The work hardening decreased above 300 °C because of the cessation of dynamic strain aging and increased again above 400 °C because of precipitation of carbides. An apparent activation energy of 138 kJ/mol was measured for static strain aging between 300 and 400 °C, corresponding closely to the activation energies for the disapperance of serrations and for the volume diffusion of carbon in Hadfield steel. Evidence from the present study, together with the known effect of manganese on the activity of carbon in austenite and previous internal friction studies of high-manganese steels, lead to the conclusion that dynamic strain aging, brought about by the reorientation of carbon members of C-Mn couples in the cores of dislocations, is the principal cause of rapid work hardening in Hadfield steel.

Radiation-Hardened Electronics for the Space Environment

NASA Technical Reports Server (NTRS)

Keys, Andrew S.; Watson, Michael D.

2007-01-01

RHESE covers a broad range of technology areas and products. - Radiation Hardened Electronics - High Performance Processing - Reconfigurable Computing - Radiation Environmental Effects Modeling - Low Temperature Radiation Hardened Electronics. RHESE has aligned with currently defined customer needs. RHESE is leveraging/advancing SOA space electronics, not duplicating. - Awareness of radiation-related activities through out government and industry allow advancement rather than duplication of capabilities.

Work Hardening Behavior of 1020 Steel During Cold-Beating Simulation

NASA Astrophysics Data System (ADS)

CUI, Fengkui; LING, Yuanfei; XUE, Jinxue; LIU, Jia; LIU, Yuhui; LI, Yan

2017-03-01

The present research of cold-beating formation mainly focused on roller design and manufacture, kinematics, constitutive relation, metal flow law, thermo-mechanical coupling, surface micro-topography and microstructure evolution. However, the research on surface quality and performance of workpieces in the process of cold-beating is rare. Cold-beating simulation experiment of 1020 steel is conducted at room temperature and strain rates ranging from 2000 to 4000 s-1 base on the law of plastic forming. According to the experimental data, the model of strain hardening of 1020 steel is established, Scanning Electron Microscopy(SEM) is conducted, the mechanism of the work hardening of 1020 steel is clarified by analyzing microstructure variation of 1020 steel. It is found that the strain rate hardening effect of 1020 steel is stronger than the softening effect induced by increasing temperatures, the process of simulation cold-beating cause the grain shape of 1020 steel significant change and microstructure elongate significantly to form a fibrous tissue parallel to the direction of deformation, the higher strain rate, the more obvious grain refinement and the more hardening effect. Additionally, the change law of the work hardening rate is investigated, the relationship between dislocation density and strain, the relationship between work hardening rate and dislocation density is obtained. Results show that the change trend of the work hardening rate of 1020 steel is divided into two stages, the work hardening rate decreases dramatically in the first stage and slowly decreases in the second stage, finally tending toward zero. Dislocation density increases with increasing strain and strain rate, work hardening rate decreases with increasing dislocation density. The research results provide the basis for solving the problem of improving the surface quality and performance of workpieces under cold-beating formation of 1020 steel.

An Anisotropic Hardening Model for Springback Prediction

NASA Astrophysics Data System (ADS)

Zeng, Danielle; Xia, Z. Cedric

2005-08-01

As more Advanced High-Strength Steels (AHSS) are heavily used for automotive body structures and closures panels, accurate springback prediction for these components becomes more challenging because of their rapid hardening characteristics and ability to sustain even higher stresses. In this paper, a modified Mroz hardening model is proposed to capture realistic Bauschinger effect at reverse loading, such as when material passes through die radii or drawbead during sheet metal forming process. This model accounts for material anisotropic yield surface and nonlinear isotropic/kinematic hardening behavior. Material tension/compression test data are used to accurately represent Bauschinger effect. The effectiveness of the model is demonstrated by comparison of numerical and experimental springback results for a DP600 straight U-channel test.

Geochemical and geophysical monitoring activities in Campo de Calatrava Volcanic Field (Spain)

NASA Astrophysics Data System (ADS)

Luengo-Oroz, Natividad; Villasante-Marcos, Víctor; López-Díaz, Rubén; Calvo, Marta; Albert, Helena; Domínguez Cerdeña, Itahiza

2017-04-01

The Campo de Calatrava Volcanic Field (CCVF) or Spanish Central Volcanic Zone is located in central continental Spain (Ciudad Real province) and covers about 5000 km2. It includes around 240 eruptive centers, mainly monogenetic basaltic cones but also explosive maar structures. According to K-Ar geochronology, its main activity phase occurred during Pliocene and Pleistocene epochs (between 5 and 1.7 Ma) and involved alkaline to ultraalkaline magmas, although an older ultrapotassic phase is dated around 8.7-6.4 Ma. However, some recent works have proposed Holocene ages for some of the volcanic products, opening the possibility of considering the CCVF "active" according to international standards. Responding to this situation, the Instituto Geográfico Nacional (IGN) has initiated geochemical and geophysical monitoring activities in the CCVF. Here, we describe these ongoing efforts and we report results about groundwater geochemistry at several natural highly-gaseous springs in the area (hervideros), as well as soil temperature, CO2 diffuse flux from the soil and electrical self-potential data mapped on a small degassing structure called La Sima. In order to analyze microseismicity or any seismic anomaly in the CCVF, a seismic station has also been installed close to this degassing structure. Physicochemical parameters (temperature, pH, Eh and electric conductivity) were measured in situ in four springs and samples were taken in order to analyze major ions and trace elements. Total composition of dissolved gases and helium isotopic ratios were also determined. To complete soil temperature, self-potential and gas prospections performed in La Sima, soil gases were sampled at the bottom of the structure at a depth of 20 cm. Analysis of the total gas composition found 957400 ppm of CO2. Low values of O2 and N2 were also detected (5600 and 24800 ppm respectively).

Decline in Radiation Hardened Microcircuit Infrastructure

NASA Technical Reports Server (NTRS)

LaBel, Kenneth A.

2015-01-01

Two areas of radiation hardened microcircuit infrastructure will be discussed: 1) The availability and performance of radiation hardened microcircuits, and, and 2) The access to radiation test facilities primarily for proton single event effects (SEE) testing. Other areas not discussed, but are a concern include: The challenge for maintaining radiation effects tool access for assurance purposes, and, the access to radiation test facilities primarily for heavy ion single event effects (SEE) testing. Status and implications will be discussed for each area.

Pb isotope systematics in volcanic river system: Constraints about weathering processes

NASA Astrophysics Data System (ADS)

Negrel, P. J.; Millot, R.; Petelet-Giraud, E.; Guerrot, C.

2012-12-01

We present a series of lead isotopes in soils and sediments developed on volcanic rocks forming a small watershed flowing through the Massif Central (France). The Massif Central volcanic province is a widespread area of Tertiary to Recent continental alkaline volcanism comprising alkali basalts and basanites. The Allanche watershed has an area of 160 km2, a maximum altitude in the watershed of 1400 m (a.s.l.) and the relief between the extreme sampling points of 340 m The river is 29 km long from headwaters to the outlet and from its origin in the Cézallier area to its mouth in the Allagnon river (a tributary of the Allier river), the Allanche river flows through the volcanic terrains of the lava plateau (11 to 2.5 Ma). Main bedrocks are basanites (nepheline or leucitic basalts), with SiO2 around 41-45%, low Na2O + K2O (<5%), and with modal or normative nepheline or leucite and a ground mass of clinopyroxene and plagioclase. Surrounding rocks are feldspatic basalts with SiO2 close to 46-49%, low Na2O + K2O (<5%). The main phase in these basalts is plagioclase with normative nepheline, hyperstene and olivine. Crustal contamination (e.g. by granite, gneiss or metasedimentary granulite, as stated by Downes, 1987, doi: 10.1144/GSL.SP.1987.030.01.25) has occurred in the differentiated magmas of both series, as witnessed by lead isotopic variations in conjunction with Rb/La ratios and lead contents. Using Pb isotope ratios, major and trace elements (from Négrel and Deschamps, 1996, Aquatic Geochemistry, 2, 1-27) we therefore compare sediments and soils evolution over the Allanche river watershed. K and Ca are considered as mobile reference elements and illustrate the weathering state of soils and sediments relative to parent rocks through a large decrease in K and Ca content when compared to Si; the sediments being less depleted than soils. Lead, with regards to Si shows three behaviour with depleted Si content- same lead content that bedrock, depleted Si content- less

Volcanic impediments in the progressive development of pre-Columbian civilizations in the Ecuadorian Andes

NASA Astrophysics Data System (ADS)

Hall, Minard L.; Mothes, Patricia A.

2008-10-01

Archaeological investigations in Ecuador have proposed that there appear to be hiatus or anomalous jumps in the progressive development of pre-Columbian indigenous cultures, based upon the fact that their ceramics and tools demonstrate abrupt advances in their sophistication at several horizons in the soil profile. Because some of these horizons are clearly associated with volcanic ash layers, archaeologists have sought a causal relation with volcanism, that is, the eruptive events or their products severely interfered with the early inhabitants, resulting in their abandonment of certain areas. Geological studies of the young volcanoes in the Ecuadorian Andes carried out during the past two decades now allow us to make a more thorough evaluation of the role of volcanism during the Holocene. This contribution briefly describes the principal Holocene volcanic events and the distribution of the corresponding eruptive products found along the InterAndean Valley, from southern Colombia to central Ecuador. Only those events that were sufficiently large that they could have had a detrimental effect on the valley's early residents are discussed. Dacitic and rhyolitic ash flows, as well as numerous debris flows (lahars) have occurred frequently and their deposits cover many valleys and floodplains, where early inhabitants probably settled. The enormous Chillos Valley lahar, associated with the 4500 yBP eruption of Cotopaxi volcano, buried soils containing ceramics of the early Formative Period. However, the greatest impact upon mankind was probably not these short-lived violent events, but rather the burying of settlements and agricultural fields by ash fallout, the effect of which may have lasted hundreds of years. Ash fall layers are observed in pre-Columbian cultural horizons in the soil profile, occurring in the InterAndean Valley, the lower flanks of the Andes, and along Ecuador's Pacific coast, the oldest corresponding to the 5800 yBP eruption of Cotopaxi. This brief

Carbon stabilization mechanisms in soils in the Andes

NASA Astrophysics Data System (ADS)

Jansen, Boris; Cammeraat, Erik

2015-04-01

The volcanic ash soils of the Andes contain very large stocks of soil organic matter (SOM) per unit area. Consequently, they constitute significant potential sources or sinks of the greenhouse gas CO2. Climate and/or land use change potentially have a strong effect on these large SOM stocks. To clarify the role of chemical and physical stabilisation mechanisms in volcanic ash soils in the montane tropics, we investigated carbon stocks and stabilization mechanisms in the top- and subsoil along an altitudinal transect in the Ecuadorian Andes. The transect encompassed a sequence of paleosols under forest and grassland (páramo), including a site where vegetation cover changed in the last century. We applied selective extraction techniques, performed X-ray diffraction analyses of the clay fraction and estimated pore size distributions at various depths in the top- and subsoil along the transect. In addition, from several soils the molecular composition of SOM was further characterized with depth in the current soil as well as the entire first and the top of the second paleosol using GC/MS analyses of extractable lipids and Pyrolysis-GC/MS analyses of bulk organic matter. Our results show that organic carbon stocks in the mineral soil under forest a páramo vegetation were roughly twice as large as global averages for volcanic ash soils, regardless of whether the first 30cm, 100cm or 200cm were considered. We found the carbon stabilization mechanisms involved to be: i) direct stabilization of SOM in organo-metallic (Al-OM) complexes; ii) indirect protection of SOM through low soil pH and toxic levels of Al; and iii) physical protection of SOM due to a very high microporosity of the soil (Tonneijck et al., 2010; Jansen et al. 2011). When examining the organic carbon at a molecular level, interestingly we found extensive degradation of lignin in the topsoil while extractable lipids were preferentially preserved in the subsoil (Nierop and Jansen, 2009). Both vegetation

Surface hardening of titanium alloys with melting depth controlled by heat sink

DOEpatents

Oden, Laurance L.; Turner, Paul C.

1995-01-01

A process for forming a hard surface coating on titanium alloys includes providing a piece of material containing titanium having at least a portion of one surface to be hardened. The piece having a portion of a surface to be hardened is contacted on the backside by a suitable heat sink such that the melting depth of said surface to be hardened may be controlled. A hardening material is then deposited as a slurry. Alternate methods of deposition include flame, arc, or plasma spraying, electrodeposition, vapor deposition, or any other deposition method known by those skilled in the art. The surface to be hardened is then selectively melted to the desired depth, dependent on the desired coating thickness, such that a molten pool is formed of the piece surface and the deposited hardening material. Upon cooling a hardened surface is formed.

Monitoring diffuse volcanic degassing during volcanic unrests: the case of Campi Flegrei (Italy)

NASA Astrophysics Data System (ADS)

Cardellini, Carlo; Chiodini, Giovanni; Avino, Rosario; Bagnato, Emanuela; Caliro, Stefano; Frondini, Francesco; Lelli, Matteo; Rosiello, Angelo

2017-04-01

Hydrothermal activity at Solfatara of Pozzuoli (Campi Flegrei caldera, Italy) results on a large area of hot soils, diffuse CO2 degassing and numerous fumaroles, releasing at the surface large amounts of gasses and thermal energy. Solfatara is one of the first sites of the world where the techniques for measuring and interpreting soil CO2 diffuse degassing were developed during 1990's and, more recently, it has become a sort of natural laboratory for testing new types of measurements of the CO2 fluxes from hydrothermal sites. The results of 30 diffuse CO2 flux surveys performed at Solfatara from 1998 to 2016 are presented and discussed. CO2 soil fluxes were measured over an area of about 1.2  1.2 km including the Solfatara crater and the hydrothermal site of Pisciarelli using the accumulation chamber technique. Each survey consisted in a number of CO2 flux measurements varying from 372 to 583 resulting in a total of 13158 measurements. This data set is one of the largest dataset ever made in the world on a single degassing volcanic-hydrothermal system. It is particularly relevant in the frame of volcanological sciences because it was acquired during a long period of unrest at Campi Flegrei caldera and because Solfatara release an amount of CO2 comparable to that released by medium-large volcanic plumes. Statistical and geostatistical elaborations of CO2 flux data allowed to characterise the sources of soil diffuse degassing, to define the extent of the area interested by the release of hydrothermal CO2 (Solfatara DDS) and to quantify the total amount of released CO2. During the last eighteen years relevant variations affected Solfatara degassing, and in particular the "background" CO2 emission , the extent of DDS and the total CO2 output, that may reflect variations in the subterraneous gas plume feeding the Solfatara and Pisciarelli emissions. In fact, the most relevant variations in Solfatara diffuse degassing well correlates with steam condensation and

Research on SEU hardening of heterogeneous Dual-Core SoC

NASA Astrophysics Data System (ADS)

Huang, Kun; Hu, Keliu; Deng, Jun; Zhang, Tao

2017-08-01

The implementation of Single-Event Upsets (SEU) hardening has various schemes. However, some of them require a lot of human, material and financial resources. This paper proposes an easy scheme on SEU hardening for Heterogeneous Dual-core SoC (HD SoC) which contains three techniques. First, the automatic Triple Modular Redundancy (TMR) technique is adopted to harden the register heaps of the processor and the instruction-fetching module. Second, Hamming codes are used to harden the random access memory (RAM). Last, a software signature technique is applied to check the programs which are running on CPU. The scheme need not to consume additional resources, and has little influence on the performance of CPU. These technologies are very mature, easy to implement and needs low cost. According to the simulation result, the scheme can satisfy the basic demand of SEU-hardening.

Silicification of holocene soils in northern Monitor Valley, Nevada

NASA Astrophysics Data System (ADS)

Chadwick, O. A.; Hendricks, D. M.; Nettleton, W. D.

1989-02-01

Chemical, physical, and microscopic data for three soils in the northern Monitor Valley are analyzed. The soils ranked in order of increasing age are: Mule, Rotinom, and Nayped. The procedures and techniques used to obtain and study that data are described. It is observed that: (1) redistribution of carbonate is detectable in all soils; (2) clay illuviation is insignificant in the Mule soil, weak but identifiable in the Rotinom soil, and significant in the Nayped soil; and (3) the maximum sodium adsorption ratio (SAR) and electrical conductivity (EC) for the Mule soil is between 64-89 cm, for the Rotinom soil the values are below 100 cm, and for Nayped the maximum SAR values range from 51-117 cm and maximum EC values are between 117-152 cm. The relationship between volcanic glass weathering and the amount of silica cementation in the soils is studied. It is noted that silicification of Monitor Valley holocene soils is due to there being enough moisture to release silica from volcanic glass, but not enough to leach the weathering products from the profile.

Silicification of holocene soils in northern Monitor Valley, Nevada

NASA Technical Reports Server (NTRS)

Chadwick, O. A.; Hendricks, D. M.; Nettleton, W. D.

1989-01-01

Chemical, physical, and microscopic data for three soils in the northern Monitor Valley are analyzed. The soils ranked in order of increasing age are: Mule, Rotinom, and Nayped. The procedures and techniques used to obtain and study that data are described. It is observed that: (1) redistribution of carbonate is detectable in all soils; (2) clay illuviation is insignificant in the Mule soil, weak but identifiable in the Rotinom soil, and significant in the Nayped soil; and (3) the maximum sodium adsorption ratio (SAR) and electrical conductivity (EC) for the Mule soil is between 64-89 cm, for the Rotinom soil the values are below 100 cm, and for Nayped the maximum SAR values range from 51-117 cm and maximum EC values are between 117-152 cm. The relationship between volcanic glass weathering and the amount of silica cementation in the soils is studied. It is noted that silicification of Monitor Valley holocene soils is due to there being enough moisture to release silica from volcanic glass, but not enough to leach the weathering products from the profile.

Radiation-hardened backside-illuminated 512 x 512 charge-coupled device

NASA Astrophysics Data System (ADS)

Bates, Philip A.; Levine, Peter A.; Sauer, Donald J.; Hsueh, Fu-Lung; Shallcross, Frank V.; Smeltzer, Ronald K.; Meray, Grazyna M.; Taylor, Gordon C.; Tower, John R.

1995-04-01

A four-port 512 X 512 charge coupled device (CCD) imager hardened against proton displacement damage and total dose degradation has been fabricated and tested. The device is based upon an established thinned, backside illuminated, triple polysilicon, buried channel CCD process technology. The technology includes buried blooming drains. A three step approach has been taken to hardening the device. The first phase addressed hardening against proton displacement damage. The second phase addressed hardening against both proton displacement damage and total dose degradation. The third phase addresses final optimization of the design. Test results from the first and second phase efforts are presented. Plans for the third phase are discussed.

A geologic and anthropogenic journey from the Precambrian to the new energy economy through the San Juan volcanic field

USGS Publications Warehouse

Yager, Douglas B.; Burchell,; Johnson, Raymond H.

2010-01-01

The San Juan volcanic field comprises 25,000 km2 of intermediate composition mid-Tertiary volcanic rocks and dacitic to rhyolitic calderas including the San Juan–Uncompahgre and La Garita caldera-forming super-volcanoes. The region is famous for the geological, ecological, hydrological, archeological, and climatological diversity. These characteristics supported ancestral Puebloan populations. The area is also important for its mineral wealth that once fueled local economic vitality. Today, mitigating and/or investigating the impacts of mining and establishing the region as a climate base station are the focuses of ongoing research. Studies include advanced water treatment, the acid neutralizing capacity (ANC) of propylitic bedrock for use in mine-lands cleanup, and the use of soil amendments including biochar from beetle-kill pines. Biochar aids soil productivity and revegetation by incorporation into soils to improve moisture retention, reduce erosion, and support the natural terrestrial carbon sequestration (NTS) potential of volcanic soils to help offset atmospheric CO2 emissions. This field trip will examine the volcano-tectonic and cultural history of the San Juan volcanic field as well as its geologic structures, economic mineral deposits and impacts, recent mitigation measures, and associated climate research. Field trip stops will include a visit to (1) the Summitville Superfund site to explore quartz alunite-Au mineralization, and associated alteration and new water-quality mitigation strategies; (2) the historic Creede epithermal-polymetallic–vein district with remarkably preserved resurgent calderas, keystone-graben, and moat sediments; (3) the historic mining town of Silverton located in the nested San Juan–Silverton caldera complex that exhibits base-metal Au-Ag mineralization; and (4) the site of ANC and NTS studies. En route back to Denver, we will traverse Grand Mesa, a high NTS area with Neogene basalt-derived soils and will enjoy a soak

Volcanic Hazards Survey in the Trans Mexican Volcanic Belt

NASA Technical Reports Server (NTRS)

Abrams, Michael; Siebe, Claus; Macias, Jose Luis

1996-01-01

We have assembled a digital mosaic of 11 Landsat Thematic images to serve as a mapping base for reconnaissance activities within the Trans Mexican Volcanic Belt. This will aid us in interpretation and in the evaluation of potential activity of all the volcanic centers there. One result is a volcanic hazards map of the area.

Detection of an organic-non volatile compound in variable-contaminated volcanic soil samples via Time Domain Reflectometry (TDR) technique: Preliminary results

NASA Astrophysics Data System (ADS)

comegna, alessandro; coppola, antonio; dragonetti, giovanna; chaali, nesrine; sommella, angelo

2014-05-01

Hydrocarbons may be present in soils as non-aqueous phase liquids (NAPLs), which means that these organic compounds, exist as a separate and immiscible phase with respect to water and air commonly present in the soil. NAPLs, which can be accidentally introduced in the environment (for example by waste disposal sites, industrial spills, gasoline stations, etc), constitutes a serious geo-environmental problem, given the toxicity level and the high mobility. Time domain reflectometry (TDR) has became, over several decades, an important technique for water estimation in soils. In order to expand the potentiality of the TDR technique, the main objective of this study is to explore the capacity of dielectric response to detect the presence of NAPLs in volcanic soils. In laboratory, soil samples were oven dried at 105° C and passed through a 2 mm sieve. Known quantities of soil, water and NAPL (corn oil, a non-volatile and non-toxic organic compound) were mixed and repacked into plastic cylinders (16 cm high and 9.5 cm in diameter); in order to obtain forty different volumetric combinations of water and oil (i.e. θfg = θwater + θNAPL), with θNAPL varying from 0.05 to 0.40 by 0.05 cm3/cm3 increments. Data collected were employed to implement a multiphase mixing model which permitted conversion from a dielectric permittivity domain into a θf domain and vice versa. The results of this study show that, the TDR device is NAPL-sensitive, especially for θf values greater than 0.20. Further works will be built on this initial study, concentrating on improving the dielectric response-database, in order to: i) enhancing the model efficiency in terms of NAPL capability detention, and ii) validating the developed TDR interpretation tool with field results.

CO2 diffuse emission from maar lake: An example in Changbai volcanic field, NE China

NASA Astrophysics Data System (ADS)

Sun, Yutao; Guo, Zhengfu; Liu, Jiaqi; Du, Jianguo

2018-01-01

Numerous maars and monogenetic volcanic cones are distributed in northeast China, which are related to westward deep subduction of the Pacific Ocean lithosphere, comprising a significant part of the "Pacific Ring of Fire". It is well known that diffuse CO2 emissions from monogenetic volcanoes, including wet (e.g., maar lake) and dry degassing systems (e.g., soil diffuse emission, fault degassing, etc.), may contribute to budget of globally nature-derived greenhouse gases. However, their relationship between wet (e.g., maar lake) and concomitant dry degassing systems (e.g., soil diffuse emission, fault degassing, etc.) related to monogenetic volcanic field is poorly understood. Yuanchi maar, one of the typical monogenetic volcanic systems, is located on the eastern flank of Tianchi caldera in Changbai volcanic field of northeast China, which displays all of three forms of CO2 degassing including the maar lake, soil micro-seepage and fault degassing. Measurements of efflux of CO2 diffusion from the Yuanchi maar system (YMS) indicate that the average values of CO2 emissions from soil micro-seepage, fault degassing and water-air interface diffusion are 24.3 ± 23.3 g m- 2 d- 1, 39.2 ± 22.4 g m- 2 d- 1 and 2.4 ± 1.1 g m- 2 d- 1, respectively. The minimum output of CO2 diffuse emission from the YMS to the atmosphere is about 176.1 ± 88.3 ton/yr, of which 80.4% results from the dry degassing system. Degassing from the fault contributes to the most of CO2 emissions in all of the three forms of degassing in the YMS. Contributions of mantle, crust, air and organic CO2 to the soil gas are 0.01-0.10%, 10-20%, 32-36% and 48-54%, respectively, which are quantitatively constrained by a He-C isotope coupling calculation model. We propose that CO2 exsolves from the upper mantle melting beneath the Tianchi caldera, which migrates to the crustal magma chamber and further transports to the surface of YMS along the deep fault system. During the transportation processes, the emission

Hardening fertilization and nutrient loading of conifer seedlings

Treesearch

R. Kasten Dumroese

2003-01-01

Continuing to fertilize bareroot and container seedlings during the hardening process (from cessation of height growth until lifting) can improve seedling viability. The process of fertilizing during hardening has many names, but in the last decade a new term, nutrient loading, has come into use. The process of nutrient loading seedlings leads to luxury consumption...

Scintillation-Hardened GPS Receiver

NASA Technical Reports Server (NTRS)

Stephens, Donald R.

2015-01-01

CommLargo, Inc., has developed a scintillation-hardened Global Positioning System (GPS) receiver that improves reliability for low-orbit missions and complies with NASA's Space Telecommunications Radio System (STRS) architecture standards. A software-defined radio (SDR) implementation allows a single hardware element to function as either a conventional radio or as a GPS receiver, providing backup and redundancy for platforms such as the International Space Station (ISS) and high-value remote sensing platforms. The innovation's flexible SDR implementation reduces cost, weight, and power requirements. Scintillation hardening improves mission reliability and variability. In Phase I, CommLargo refactored an open-source GPS software package with Kalman filter-based tracking loops to improve performance during scintillation and also demonstrated improved navigation during a geomagnetic storm. In Phase II, the company generated a new field-programmable gate array (FPGA)-based GPS waveform to demonstrate on NASA's Space Communication and Navigation (SCaN) test bed.

Extracting material response from simple mechanical tests on hardening-softening-hardening viscoplastic solids

NASA Astrophysics Data System (ADS)

Mohan, Nisha

Compliant foams are usually characterized by a wide range of desirable mechanical properties. These properties include viscoelasticity at different temperatures, energy absorption, recoverability under cyclic loading, impact resistance, and thermal, electrical, acoustic and radiation-resistance. Some foams contain nano-sized features and are used in small-scale devices. This implies that the characteristic dimensions of foams span multiple length scales, rendering modeling their mechanical properties difficult. Continuum mechanics-based models capture some salient experimental features like the linear elastic regime, followed by non-linear plateau stress regime. However, they lack mesostructural physical details. This makes them incapable of accurately predicting local peaks in stress and strain distributions, which significantly affect the deformation paths. Atomistic methods are capable of capturing the physical origins of deformation at smaller scales, but suffer from impractical computational intensity. Capturing deformation at the so-called meso-scale, which is capable of describing the phenomenon at a continuum level, but with some physical insights, requires developing new theoretical approaches. A fundamental question that motivates the modeling of foams is `how to extract the intrinsic material response from simple mechanical test data, such as stress vs. strain response?' A 3D model was developed to simulate the mechanical response of foam-type materials. The novelty of this model includes unique features such as the hardening-softening-hardening material response, strain rate-dependence, and plastically compressible solids with plastic non-normality. Suggestive links from atomistic simulations of foams were borrowed to formulate a physically informed hardening material input function. Motivated by a model that qualitatively captured the response of foam-type vertically aligned carbon nanotube (VACNT) pillars under uniaxial compression [2011,"Analysis of

P retention and cation exchange as affected by nanoparticle of volcanic ash and application of phosphate solubilizing bacteria on Andisol Ciater, West Java, Indonesia

NASA Astrophysics Data System (ADS)

Fitriatin, Betty Natalie; Arifin, Mahfud; Devnita, Rina; Yuniarti, Anni; Haryanto, Rachmat; Setiabudi, Mariska Amalia

2018-02-01

Andisols is a soil with high retention of phosphate and cannot be absorbed by plants. Some of soil bacteria have the ability to solubilize P and make it available to growing plants are known phosphate solubilizing bacteria (PSB). The research aims to study the effect of nanoparticle volcanic ash and phosphate solubilising bacteria (PSB) on P retention and cation exchangeable (CEC) in Andisol Ciater, West Java. This research was conducted from October 2016 to March 2017. The design of the analysis used was a complete randomized factorial design with two factors. The first factor was nanoparticle volcanic ash (a) consists of four dosages based on weight percentage (0%, 2.5%, 5.0% and 7.5%) and the second factor was PSB (h) consists of two dosages (without biofertilizer and with biofertilizer 1 g/Kg soil). The combination treatments replicated three times were incubated for 4 months. Soil samples were analyzed at first month and fourth month after incubation. The results showed that all dosages of nanoparticle volcanic ash and application of PSB decreased P retention by 75-77% at the first month after incubation. Nanoparticle volcanic ash dosage decreased to 7.5% the P retention reaches 90.36% in the fourth month after incubation. The nanoparticle of volcanic ash dosage 7.5% increased with CEC (24.787 cmol.kg-1 and 16.555 cmol.kg-1) at the first and fourth months after incubation. The application of PSB increased the CEC (28.606 cmol.kg-1) in the first month after incubation.

Work-hardening behaviour of Mg single crystals oriented for basal slip

NASA Astrophysics Data System (ADS)

Bhattacharya, B.; Niewczas, M.

2011-06-01

Work-hardening behaviour of Mg single crystals oriented for basal slip was studied by means of tensile tests carried out at 4, 78 and 295 K. The crystals show critical resolved shear stress values (CRSS) for a {0001} ? basal slip system in the range 1-1.5 MPa. The samples exhibit two-stage work hardening characteristics consisting of a long easy glide stage and a stage of rapid hardening terminated by failure. The onset of the plastic flow up to the point of fracture is accompanied by a low work-hardening rate in the range 5 × 10-5-5 × 10-4 µ, corresponding to the hardening rate in Stage I of copper single crystals. The analysis of thermally activated glide parameters suggests that forest interactions are rate-controlling processes. The very low value of the activation distance found at 4 K, ∼0.047 b, is attributed to zero-point energy effects. The failure of crystals occurs well before their hardening capacity is exhausted by mechanisms which are characteristic of deformation temperature.

Process design of press hardening with gradient material property influence

DOE Office of Scientific and Technical Information (OSTI.GOV)

Neugebauer, R.; Professorship for Machine Tools and Forming Technology, TU Chemnitz; Schieck, F.

Press hardening is currently used in the production of automotive structures that require very high strength and controlled deformation during crash tests. Press hardening can achieve significant reductions of sheet thickness at constant strength and is therefore a promising technology for the production of lightweight and energy-efficient automobiles. The manganese-boron steel 22MnB5 have been implemented in sheet press hardening owing to their excellent hot formability, high hardenability, and good temperability even at low cooling rates. However, press-hardened components have shown poor ductility and cracking at relatively small strains. A possible solution to this problem is a selective increase of steelmore » sheet ductility by press hardening process design in areas where the component is required to deform plastically during crash tests. To this end, process designers require information about microstructure and mechanical properties as a function of the wide spectrum of cooling rates and sequences and austenitizing treatment conditions that can be encountered in production environments. In the present work, a Continuous Cooling Transformation (CCT) diagram with corresponding material properties of sheet steel 22MnB5 was determined for a wide spectrum of cooling rates. Heating and cooling programs were conducted in a quenching dilatometer. Motivated by the importance of residual elasticity in crash test performance, this property was measured using a micro-bending test and the results were integrated into the CCT diagrams to complement the hardness testing results. This information is essential for the process design of press hardening of sheet components with gradient material properties.« less

Process design of press hardening with gradient material property influence

NASA Astrophysics Data System (ADS)

Neugebauer, R.; Schieck, F.; Rautenstrauch, A.

2011-05-01

Press hardening is currently used in the production of automotive structures that require very high strength and controlled deformation during crash tests. Press hardening can achieve significant reductions of sheet thickness at constant strength and is therefore a promising technology for the production of lightweight and energy-efficient automobiles. The manganese-boron steel 22MnB5 have been implemented in sheet press hardening owing to their excellent hot formability, high hardenability, and good temperability even at low cooling rates. However, press-hardened components have shown poor ductility and cracking at relatively small strains. A possible solution to this problem is a selective increase of steel sheet ductility by press hardening process design in areas where the component is required to deform plastically during crash tests. To this end, process designers require information about microstructure and mechanical properties as a function of the wide spectrum of cooling rates and sequences and austenitizing treatment conditions that can be encountered in production environments. In the present work, a Continuous Cooling Transformation (CCT) diagram with corresponding material properties of sheet steel 22MnB5 was determined for a wide spectrum of cooling rates. Heating and cooling programs were conducted in a quenching dilatometer. Motivated by the importance of residual elasticity in crash test performance, this property was measured using a micro-bending test and the results were integrated into the CCT diagrams to complement the hardness testing results. This information is essential for the process design of press hardening of sheet components with gradient material properties.

Easy Volcanic Aerosol

NASA Astrophysics Data System (ADS)

Toohey, Matthew; Stevens, Bjorn; Schmidt, Hauke; Timmreck, Claudia

2016-04-01

Radiative forcing by stratospheric sulfate aerosol of volcanic origin is one of the strongest drivers of natural climate variability. Transient model simulations attempting to match observed climate variability, such as the CMIP historical simulations, rely on volcanic forcing reconstructions based on observations of a small sample of recent eruptions and coarse proxy data for eruptions before the satellite era. Volcanic forcing data sets used in CMIP5 were provided either in terms of optical properties, or in terms of sulfate aerosol mass, leading to significant inter-model spread in the actual volcanic radiative forcing produced by models and in their resulting climate responses. It remains therefore unclear to what degree inter-model spread in response to volcanic forcing represents model differences or variations in the forcing. In order to isolate model differences, Easy Volcanic Aerosol (EVA) provides an analytic representation of volcanic stratospheric aerosol forcing, based on available observations and aerosol model results, prescribing the aerosol's radiative properties and primary modes of spatial and temporal variability. In contrast to regriddings of observational data, EVA allows for the production of physically consistent forcing for historic and hypothetical eruptions of varying magnitude, source latitude, and season. Within CMIP6, EVA will be used to reconstruct volcanic forcing over the past 2000 years for use in the Paleo-Modeling Intercomparison Project (PMIP), and will provide forcing sets for VolMIP experiments aiming to quantify model uncertainty in the response to volcanic forcing. Here, the functional form of EVA will be introduced, along with illustrative examples including the EVA-based reconstruction of volcanic forcing over the historical period, and that of the 1815 Tambora eruption.

Laser Transformation Hardening of Firing Zone Cutout Cams.

DTIC Science & Technology

1981-06-01

bath nitriding to case harden firing zone cutout cams for the Mk 10 Guided Missile Launcher System (GMLS). These cams, machined of 4340 steel ...salt bath nitriding to case harden firing zone cutout cams for the Mk 10 Guided Missile Launcher System (GMLS). These cams, machined of 4340 steel ...Patterns ........ ................ 8 9 Laser Beam Step Pattern ...... .................. .. 10 10 Hardness Profile, 4340 Steel

Soil CO2 emissions as a proxy for heat and mass flow assessment, Taupō Volcanic Zone, New Zealand

USGS Publications Warehouse

Bloomberg, S.; Werner, Cynthia A.; Rissmann, C.F.; Mazot, A.; Horton, Travis B.; Gravley, D; Kennedy, B.; Oze, C

2014-01-01

The quantification of heat and mass flow between deep reservoirs and the surface is important for understanding magmatic and hydrothermal systems. Here, we use high-resolution measurement of carbon dioxide flux (φCO2) and heat flow at the surface to characterize the mass (CO2 and steam) and heat released to the atmosphere from two magma-hydrothermal systems. Our soil gas and heat flow surveys at Rotokawa and White Island in the Taupō Volcanic Zone, New Zealand, include over 3000 direct measurements of φCO2 and soil temperature and 60 carbon isotopic values on soil gases. Carbon dioxide flux was separated into background and magmatic/hydrothermal populations based on the measured values and isotopic characterization. Total CO2 emission rates (ΣCO2) of 441 ± 84 t d−1 and 124 ± 18 t d−1were calculated for Rotokawa (2.9 km2) and for the crater floor at White Island (0.3 km2), respectively. The total CO2 emissions differ from previously published values by +386 t d−1 at Rotokawa and +25 t d−1 at White Island, demonstrating that earlier research underestimated emissions by 700% (Rotokawa) and 25% (White Island). These differences suggest that soil CO2 emissions facilitate more robust estimates of the thermal energy and mass flux in geothermal systems than traditional approaches. Combining the magmatic/hydrothermal-sourced CO2 emission (constrained using stable isotopes) with reservoir H2O:CO2mass ratios and the enthalpy of evaporation, the surface expression of thermal energy release for the Rotokawa hydrothermal system (226 MWt) is 10 times greater than the White Island crater floor (22.5 MWt).

Volcanic stratigraphy: A review

NASA Astrophysics Data System (ADS)

Martí, Joan; Groppelli, Gianluca; Brum da Silveira, Antonio

2018-05-01

Volcanic stratigraphy is a fundamental component of geological mapping in volcanic areas as it yields the basic criteria and essential data for identifying the spatial and temporal relationships between volcanic products and intra/inter-eruptive processes (earth-surface, tectonic and climatic), which in turn provides greater understanding of the geological evolution of a region. Establishing precise stratigraphic relationships in volcanic successions is not only essential for understanding the past behaviour of volcanoes and for predicting how they might behave in the future, but is also critical for establishing guidelines for exploring economic and energy resources associated with volcanic systems or for reconstructing the evolution of sedimentary basins in which volcanism has played a significant role. Like classical stratigraphy, volcanic stratigraphy should also be defined using a systematic methodology that can provide an organised and comprehensive description of the temporal and spatial evolution of volcanic terrain. This review explores different methods employed in studies of volcanic stratigraphy, examines four case studies that use differing stratigraphic approaches, and recommends methods for using systematic volcanic stratigraphy based on the application of the concepts of traditional stratigraphy but adapted to the needs of volcanological environment.

Strain hardening behavior during manufacturing of tube shapes by hydroforming

NASA Astrophysics Data System (ADS)

Park, Hyun Kyu; Yi, Hyae Kyung; Van Tyne, Chester J.; Moon, Young Hoon

2009-12-01

Safe and robust process design relies on knowledge of the evolution of the mechanical properties in a tube during hydroforming. The manufacturing of tubular shapes generally consists of three main stages: bending, preforming, and expansion. The latter is usually called hydroforming. As a result of these three steps, the final product's strain hardening history is nonlinear. In the present study, the strain hardening behavior during hydroforming was experimentally investigated. The variation of local flow stress and/or local hardness was used as an index of the strain hardening during the various steps and the local flow stress and/or local hardness were used with respective correlations to determine the effective strain. The strain hardening behavior during hydroforming after preforming has been successfully analyzed by using the relationships between hardness, flow stress, and effective strain for variable pre-strains prior to hydroforming. The comparison of predicted hardness with measured hardness confirms that the methodology used in this study is feasible, and that the strain hardening behavior can be quantitatively estimated with good accuracy.

The fate and transport of RDX, HMX, TNT and DNT in the volcanic soils of Hawaii: a laboratory and modeling study.

PubMed

Alavi, Ghasem; Chung, Mel; Lichwa, Joseph; D'Alessio, Matteo; Ray, Chittaranjan

2011-01-30

The adsorption and degradation behavior of RDX, HMX, TNT and DNT and the impact of pH, ionic strength and dissolved organic matter on sorption were examined for two volcanic soils of a former military training area on Hawaii Island, Hawaii, USA. The transport of these chemicals in the soil was also studied in small packed columns and simulated using a water-flow and solute-transport model, HYDRUS_1D. The results show that HMX and RDX are both significantly more mobile than TNT and DNT. The adsorbability of the four chemicals was ranked as: RDXRDX>DNT>TNT. No significant trend was observed for the effect of ionic strength, pH and dissolved organic carbon (DOC) on the adsorption of explosive compounds within the concentrations and pH ranges evaluated. The simulation results show that TNT and DNT would not leach beyond a depth of 30cm soil profile whereas a significant amount of HMX and RDX would pass the 30cm depth. It seems that the risk for contamination of groundwater is much higher for both HMX and RDX than for DNT and TNT as the substratum in this area consists of highly permeable lavas. Copyright © 2010 Elsevier B.V. All rights reserved.

The Origin of Widespread Long-lived Volcanism Across the Galapagos Volcanic Province

NASA Astrophysics Data System (ADS)

O'Connor, J. M.; Stoffers, P.; Wijbrans, J. R.; Worthington, T. J.

2005-12-01

40Ar/39Ar ages for rocks dredged (SO144 PAGANINI expedition) and drilled (DSDP) from the Galapagos Volcanic Province (Cocos, Carnegie, Coiba and Malpelo aseismic ridges and associated seamounts) show evidence of 1) increasing age with distance from the Galapagos Archipelago, 2) long-lived episodic volcanism at many locations, and 3) broad overlapping regions of coeval volcanism. The widespread nature of synchronous volcanism across the Galapagos Volcanic Province (GVP) suggests a correspondingly large Galapagos hotspot melting anomaly (O'Connor et al., 2004). Development of the GVP via Cocos and Nazca plate migration and divergence over this broad melting anomaly would explain continued multiple phases of volcanism over millions of years following the initial onset of hotspot volcanism. The question arising from these observations is whether long-lived GVP episodic volcanism is equivalent to `rejuvenescent' or a `post-erosional' phase of volcanism that occurs hundreds of thousands or million years after the main shield-building phase documented on many mid-plate seamount chains, most notably along the Hawaiian-Emperor Seamount Chain? Thus, investigating the process responsible for long-lived episodic GVP volcanism provides the opportunity to evaluate this little understood process of rejuvenation in a physical setting very different to the Hawaiian-Emperor Chain (i.e. on/near spreading axis versus mid-plate). We consider here timing and geochemical information to test the various geodynamic models proposed to explain the origin of GVP hotspot volcanism, especially the possibility of rejuvenated phases that erupt long after initial shield-building.

Stress Corrosion Cracking Behavior of Hardening-Treated 13Cr Stainless Steel

NASA Astrophysics Data System (ADS)

Niu, Li-Bin; Ishitake, Hisamitsu; Izumi, Sakae; Shiokawa, Kunio; Yamashita, Mitsuo; Sakai, Yoshihiro

2018-03-01

Stress corrosion cracking (SCC) behavior of the hardening-treated materials of 13Cr stainless steel was examined with SSRT tests and constant load tests. In the simulated geothermal water and even in the test water without addition of impurities, the hardening-treated materials showed a brittle intergranular fracture due to the sensitization, which was caused by the present hardening-treatments.

Diffuse Helium Emission as a Precursory Sign of Volcanic Unrest

NASA Astrophysics Data System (ADS)

Padron, E.; Perez, N.; Hernandez Perez, P. A.; Sumino, H.; Melian Rodriguez, G.; Barrancos, J.; Nolasco, D.; Padilla, G.; Dionis, S.; Rodriguez, F.; Hernandez, I.; Calvo, D.; Peraza, M.; Nagao, K.

2012-12-01

Since July 16, 2011, an anomalous seismicity at El Hierro island, the youngest and smallest of the Canary Islands, was recorded by IGN seismic network. After the occurrence of more than 10,000 seismic events, volcanic tremor was recorded since 05:15 of the October 10, by all of the seismic stations on the island, with highest amplitudes recorded in the southernmost station. During the afternoon of October 12 a large light-green coloured area was observed in the sea to the souht of La Restinga village (at the southernmost part of El Hierro island), suggesting the existence of a submarine eruption. Since October 12, frequent episodes of, turbulent gas emission and foaming, and the appearance of steamy lava fragments has been observed on the sea surface. As part of the volcanic surveillance of the island, the Instituto Volcanologico de Canarias (INVOLCAN) geochemical monitoring program is carrying out diffuse helium surveys on the surface environment of El Hierro (soil atmosphere). This nobel gas has been investigated because it has been considered an almost ideal geochemical indicator because it is chemically inert, physically stable, nonbiogenic, sparingly soluble in water under ambient conditions and almost non-adsorbable. At each survey, 600 sampling sites covering the whole island and following an homogeneous distribution are selected for helium measurements in the soil gases, The helium concentration gradients with respect to its value on air (5.24 ppm) allow us to estimate a pure diffusive emission rate of helium throughout the island. The first survey was carried out on the summer of 2003, when the island was on a quiescence period. At this survey, the amount of helium released by the volcanic system of El Hierro was estimated in 6 kg/d. Since the beginning of the seismic unrest, 13 helium emission surveys have been carried out. The helium emission rate has shown an excellent agreement with the evolution of the volcanic crisis of the island, reaching 30 kg

Effect of shot peening on the microstructure of laser hardened 17-4PH

NASA Astrophysics Data System (ADS)

Wang, Zhou; Jiang, Chuanhai; Gan, Xiaoyan; Chen, Yanhua

2010-12-01

In order to investigate the influence of shot peening on microstructure of laser hardened steel and clarify how much influence of initial microstructure induced by laser hardening treatment on final microstructure of laser hardened steel after shot peening treatment, measurements of retained austenite, measurements of microhardness and microstructural analysis were carried out on three typical areas including laser hardened area, transitional area and matrix area of laser hardened 17-4PH steel. The results showed that shot peening was an efficient cold working method to eliminate the retained austenite on the surface of laser hardened samples. The surface hardness increased dramatically when shot peening treatments were carried out. The analyses of microstructure of laser hardened 17-4PH after shot peening treatment were carried out in matrix area and laser hardened area via Voigt method. With the increasing peening intensity, the influence depth of shot peening on hardness and microstructure increased but the surface hardness and microstructure did not change when certain peening intensity was reached. Influence depth of shot peening on hardness was larger than influence depth of shot peening on microstructure due to the kinetic energy loss along the depth during shot peening treatment. From the microstructural result, it can be shown that the shot peening treatment can influence the domain size and microstrain of treated samples but laser hardening treatment can only influence the microstrain of treated samples.

(abstract) Survey of Volcanic Hazards in the Trans Mexican Volcanic Belt

NASA Technical Reports Server (NTRS)

Abrams, M.; Siebe, C.; Macias, J.

1997-01-01

A substantial percentage of the world's population lives in areas vulnerable to the negative effects of future volcanic activity. This is especially true in Mexico, where within the Trans Mexican Volcanic Belt (TMVB) one half of the country's 90 million inhabitants live. The TMVB is a 1 000 by 200 km area, dotted with hundreds of volcanoes and volcanic centers. Most of the area has been poorly studied, and the volcanic history is largely unknown. Our approach is to combine interpretations of satellite images, field work and mapping, laboratory analysis, and age dating to elucidate the volcanic history and evaluate the potential eruptive hazards. Hazards evaluations are done in the form of risk maps.

Monitoring diffuse degassing in monogenetic volcanic field during seismic-volcanic unrest: the case of Tenerife North-West Rift Zone (NWRZ), Canary Islands, Spain

NASA Astrophysics Data System (ADS)

García, E.; Botelho, A. H.; Regnier, G. S. G.; Rodríguez, F.; Alonso Cótchico, M.; Melián, G.; Asensio-Ramos, M.; Padrón, E.; Hernández, P. A.; Pérez, N. M.

2017-12-01

Tenerife North-West Rift-Zone (NWRZ) is the most active volcano of the oceanic active volcanic island of Tenerife and the scenario of three historical eruptions (Boca Cangrejo S. XVI, Arenas Negras 1706 and Chinyero 1909). Since no visible degassing (fumaroles, etc.) at Tenerife NWRZ occurs, a geochemical monitoring program at Tenerife NWRZ was established mainly consisting on performing soil CO2 efflux surveys (50 surveys since 2000) to evaluate the temporal and spatial variations of soil CO2 efflux measurements and the diffuse CO2 emission rate. To do so, about 340 sampling sites were selected for each survey to obtain a homogeneous distribution after taking into consideration the local geology, structure, and accessibility. Measurements of soil CO2 efflux were performed in situ by means of a portable non-dispersive infrared sensor following the accumulation chamber method. The soil CO2 efflux values of the 2017 survey ranged from non-detectable to 46.6 g m-2 d-1. Statistical-graphical analysis of the 2017 data show two different geochemical populations; background (B) and peak (P) represented by 93.3% and 1.9% of the total data, respectively. The geometric means of the B and P populations are 2.4 and 19.1 g m-2 d-1, respectively. Most of the area showed B values while the P values were mainly observed at the N-W side of the volcanic rift. To estimate the diffuse CO2 emission in metric tons per day released from Tenerife NWRZ (75 km2) for the 2017 survey, we ran about 100 sGs simulations. The estimated 2017 diffuse CO2 output released to atmosphere by the Tenerife NWRZ volcano was 297 ± 13 t d-1. This 2017 diffuse CO2 emission rate value is relatively higher than the estimated background value (144 t d-1) and falls within the estimated background range (72 - 321 t d-1) observed for Tenerife NWRZ volcano during the 2000-2017 period. The observed temporal variation in the diffuse CO2 degassing output during this period does not seem to be driven by external

Radiation Hardened Electronics for Space Environments (RHESE)

NASA Technical Reports Server (NTRS)

Keys, Andrew S.; Adams, James H.; Frazier, Donald O.; Patrick, Marshall C.; Watson, Michael D.; Johnson, Michael A.; Cressler, John D.; Kolawa, Elizabeth A.

2007-01-01

Radiation Environmental Modeling is crucial to proper predictive modeling and electronic response to the radiation environment. When compared to on-orbit data, CREME96 has been shown to be inaccurate in predicting the radiation environment. The NEDD bases much of its radiation environment data on CREME96 output. Close coordination and partnership with DoD radiation-hardened efforts will result in leveraged - not duplicated or independently developed - technology capabilities of: a) Radiation-hardened, reconfigurable FPGA-based electronics; and b) High Performance Processors (NOT duplication or independent development).

Volcanic gas impacts on vegetation at Turrialba Volcano, Costa Rica

NASA Astrophysics Data System (ADS)

Teasdale, R.; Jenkins, M.; Pushnik, J.; Houpis, J. L.; Brown, D. L.

2010-12-01

Turrialba volcano is an active composite stratovolcano that is located approximately 40 km east of San Jose, Costa Rica. Seismic activity and degassing have increased since 2005, and gas compositions reflect further increased activity since 2007 peaking in January 2010 with a phreatic eruption. Gas fumes dispersed by trade winds toward the west, northwest, and southwest flanks of Turrialba volcano have caused significant vegetation kill zones, in areas important to local agriculture, including dairy pastures and potato fields, wildlife and human populations. In addition to extensive vegetative degradation is the potential for soil and water contamination and soil erosion. Summit fumarole temperatures have been measured over 200 degrees C and gas emissions are dominated by SO2; gas and vapor plumes reach up to 2 km (fumaroles and gases are measured regularly by OVSICORI-UNA). A recent network of passive air sampling, monitoring of water temperatures of hydrothermal systems, and soil pH measurements coupled with measurement of the physiological status of surrounding plants using gas exchange and fluorescence measurements to: (1) identify physiological correlations between leaf-level gas exchange and chlorophyll fluorescence measurements of plants under long term stress induced by the volcanic gas emissions, and (2) use measurements in tandem with remotely sensed reflectance-derived fluorescence ratio indices to track natural photo inhibition caused by volcanic gas emissions, for use in monitoring plant stress and photosynthetic function. Results may prove helpful in developing potential land management strategies to maintain the biological health of the area.

Comparative Study of Hardening Mechanisms During Aging of a 304 Stainless Steel Containing α'-Martensite

NASA Astrophysics Data System (ADS)

Jeong, S. W.; Kang, U. G.; Choi, J. Y.; Nam, W. J.

2012-09-01

Strain aging and hardening behaviors of a 304 stainless steel containing deformation-induced martensite were investigated by examining mechanical properties and microstructural evolution for different aging temperature and time. Introduced age hardening mechanisms of a cold rolled 304 stainless steel were the additional formation of α'-martensite, hardening of α'-martensite, and hardening of deformed austenite. The increased amount of α'-martensite at an aging temperature of 450 °C confirmed the additional formation of α'-martensite as a hardening mechanism in a cold rolled 304 stainless steel. Additionally, the increased hardness in both α'-martensite and austenite phases with aging temperature proved that hardening of both α'-martensite and austenite phases would be effective as hardening mechanisms in cold rolled and aged 304 stainless steels. The results suggested that among hardening mechanisms, hardening of an α'-martensite phase, including the diffusion of interstitial solute carbon atoms to dislocations and the precipitation of fine carbide particles would become a major hardening mechanism during aging of cold rolled 304 stainless steels.

Atypical soil behavior during the 2011 Tohoku earthquake ( Mw = 9)

NASA Astrophysics Data System (ADS)

Pavlenko, Olga V.

2016-07-01

To understand physical mechanisms of generation of abnormally high peak ground acceleration (PGA; >1 g) during the Tohoku earthquake, models of nonlinear soil behavior in the strong motion were constructed for 27 KiK-net stations located in the near-fault zones to the south of FKSH17. The method of data processing used was developed by Pavlenko and Irikura, Pure Appl Geophys 160:2365-2379, 2003 and previously applied for studying soil behavior at vertical array sites during the 1995 Kobe (Mw = 6.8) and 2000 Tottori (Mw = 6.7) earthquakes. During the Tohoku earthquake, we did not observe a widespread nonlinearity of soft soils and reduction at the beginning of strong motion and recovery at the end of strong motion of shear moduli in soil layers, as usually observed during strong earthquakes. Manifestations of soil nonlinearity and reduction of shear moduli during strong motion were observed at sites located close to the source, in coastal areas. At remote sites, where abnormally high PGAs were recorded, shear moduli in soil layers increased and reached their maxima at the moments of the highest intensity of the strong motion, indicating soil hardening. Then, shear moduli reduced with decreasing the intensity of the strong motion. At soft-soil sites, the reduction of shear moduli was accompanied by a step-like decrease of the predominant frequencies of motion. Evidently, the observed soil hardening at the moments of the highest intensity of the strong motion contributed to the occurrence of abnormally high PGA, recorded during the Tohoku earthquake.

Design and characterization of cellulose nanocrystal-enhanced epoxy hardeners

Treesearch

Shane X. Peng; Robert J. Moon; Jeffrey P. Youngblood

2014-01-01

Cellulose nanocrystals (CNCs) are renewable, sustainable, and abundant nanomaterial widely used as reinforcing fillers in the field of polymer nanocomposites. In this study, two-part epoxy systems with CNC-enhanced hardeners were fabricated. Three types of hardeners, Jeffamine D400 (JD400), diethylenetriamine (DETA), and (±)-trans-1,2- diaminocyclohexane (DACH), were...

Effect of preheating on fatigue resistance of gears in spin induction coil hardening process

NASA Astrophysics Data System (ADS)

Kumar, Pawan; Aggarwal, M. L.

2018-02-01

Spin hardening inductors are typically used for fine-sized teeth gear geometry. With the proper selection of several design parameters, only the gear teeth can be case surface hardened without affecting the other surface of gear. Preheating may be done to reach an adapted high austenitizing temperature in the root circle to avoid overheating of the tooth tip during final heating. The effect of preheating of gear on control of compressive residual stresses and case hardening has been experimentally discussed in this paper. Present work is about analysing single frequency mode, preheat hardening treatment and compressive residual stresses field for hardening process of spur gear using spin hardening inductors.

Analysis of the regimes in the scanner-based laser hardening process

NASA Astrophysics Data System (ADS)

Martínez, S.; Lamikiz, A.; Ukar, E.; Calleja, A.; Arrizubieta, J. A.; Lopez de Lacalle, L. N.

2017-03-01

Laser hardening is becoming a consolidated process in different industrial sectors such as the automotive industry or in the die and mold industry. The key to ensure the success in this process is to control the surface temperature and the hardened layer thickness. Furthermore, the development of reliable scanners, based on moving optics for guiding high power lasers at extremely fast speeds allows the rapid motion of laser spots, resulting on tailored shapes of swept areas by the laser. If a scanner is used to sweep a determined area, the laser energy density distribution can be adapted by varying parameters such us the scanning speed or laser power inside this area. Despite its advantages in terms of versatility, the use of scanners for the laser hardening process has not yet been introduced in the thermal hardening industry because of the difficulty of the temperature control and possible non-homogeneous hardness thickness layers. In the present work the laser hardening process with scanning optics applied to AISI 1045 steel has been studied, with special emphasis on the influence of the scanning speed and the results derived from its variation, the evolution of the hardened layer thickness and different strategies for the control of the process temperature. For this purpose, the hardened material has been studied by measuring microhardness at different points and the shape of the hardened layer has also been evaluated. All tests have been performed using an experimental setup designed to keep a nominal temperature value using a closed-loop control. The tests results show two different regimes depending on the scanning speed and feed rate values. The experimental results conclusions have been validated by means of thermal simulations at different conditions.

Planetary Volcanism

NASA Technical Reports Server (NTRS)

Antonenko, I.; Head, J. W.; Pieters, C. W.

1998-01-01

The final report consists of 10 journal articles concerning Planetary Volcanism. The articles discuss the following topics: (1) lunar stratigraphy; (2) cryptomare thickness measurements; (3) spherical harmonic spectra; (4) late stage activity of volcanoes on Venus; (5) stresses and calderas on Mars; (6) magma reservoir failure; (7) lunar mare basalt volcanism; (8) impact and volcanic glasses in the 79001/2 Core; (9) geology of the lunar regional dark mantle deposits; and (10) factors controlling the depths and sizes of magma reservoirs in Martian volcanoes.

GOSAT/TANSO-FTS Measurement of Volcanic and Geothermal CO2 Emissions

NASA Astrophysics Data System (ADS)

Schwandner, Florian M.; Carn, Simon A.; Newhall, Christopher G.

2010-05-01

Approximately one tenth of the Earth's human population lives in direct reach of volcanic hazards. Being able to provide sufficiently early and scientifically sound warning is a key to volcanic hazard mitigation. Quantitative time-series monitoring of volcanic CO2 emissions will likely play a key role in such early warning activities in the future. Impending volcanic eruptions or any potentially disastrous activity that involves movement of magma in the subsurface, is often preceded by an early increase of CO2 emissions. Conventionally, volcanic CO2 monitoring is done either in campaigns of soil emission measurements (grid of one-time measuring points) that are labor intensive and slow, or by ground-based remote FTIR measurements in emission plumes. These methods are not easily available at all sites of potential activity and prohibitively costly to employ on a large number of volcanoes. In addition, both of these ground-based approaches pose a significant risk to the workers conducting these measurements. Some aircraft-based measurements have been conducted as well in the past, however these are limited by the usually meager funding situation of individual observatories, the hazard such flights pose to equipment and crew, and by the inaccessibility of parts of the plume due to ash hazards. The core motivation for this study is therefore to develop a method for volcanic CO2 monitoring from space that will provide sufficient coverage, resolution, and data quality for an application to quantitative time series monitoring and correlation with other available datasets, from a safe distance and with potentially global reach. In summary, the purpose of the proposed research is to quantify volcanic CO2 emissions using satellite-borne observations. Quantitative estimates will be useful for warning of impending volcanic eruptions, and assessing the contribution of volcanic CO2 to global GHG. Our approach encompasses method development and testing for the detection of

Removal of phosphorus from water by using volcanic ash soil (VAS): batch and column experiments.

PubMed

Nguyen, Huy Van; Maeda, Morihiro

2016-09-01

Using low-cost and naturally available materials is considered an optimal adsorbent for removing phosphorus (P) from water due to its simplicity and economic efficiency. This study examined the removal of P from water using volcanic ash soil (VAS) by batch and column experiments. The maximum adsorption capacity of P was 2.94 mg g -1 , estimated from the batch experiment according to a Langmuir isotherm. The column study showed a higher adsorption capacity of 5.57 mg g -1 . The breakthrough curve showed that influent water containing 2 mg L -1 P was completely purified by VAS within 1,230 pore volumes (PV). The breakthrough and saturation points of the curves were 3,100 PV and 14,875 PV, respectively. After an adsorption column was loaded with 20,508 PV, a regeneration procedure was developed to determine whether an ion exchange of P with chloride occurred or adsorbed P in the columns could be eluted. Approximately 20% of P was recovered from columns by desorption tests, regardless of NaCl solution or deionized water. Specific surface area and mineral concentrations are both important characteristics that improve the adsorption capacity of VAS. The present study suggests that VAS is a promising adsorbent to remove P in water.

Effect of cutting parameters on strain hardening of nickel–titanium shape memory alloy

NASA Astrophysics Data System (ADS)

Wang, Guijie; Liu, Zhanqiang; Ai, Xing; Huang, Weimin; Niu, Jintao

2018-07-01

Nickel–titanium shape memory alloy (SMA) has been widely used as implant materials due to its good biocompatibility, shape memory property and super-elasticity. However, the severe strain hardening is a main challenge due to cutting force and temperature caused by machining. An orthogonal experiment of nickel–titanium SMA with different milling parameters conditions was conducted in this paper. On the one hand, the effect of cutting parameters on work hardening is obtained. It is found that the cutting speed has the most important effect on work hardening. The depth of machining induced layer and the degree of hardening become smaller with the increase of cutting speed when the cutting speed is less than 200 m min‑1 and then get larger with further increase of cutting speed. The relative intensity of diffraction peak increases as the cutting speed increase. In addition, all of the depth of machining induced layer, the degree of hardening and the relative intensity of diffraction peak increase when the feed rate increases. On the other hand, it is found that the depth of machining induced layer is closely related with the degree of hardening and phase transition. The higher the content of austenite in the machined surface is, the higher the degree of hardening will be. The depth of the machining induced layer increases with the degree of hardening increasing.

A preliminary evaluation of ERTS-1 images on the volcanic areas of Southern Italy

NASA Technical Reports Server (NTRS)

Cassinis, R.; Lechi, G. M.

1973-01-01

The test site selected for the investigation covers nearly all the regions of active and quiescent volcanism in southern Italy, i.e. the eastern part of the island of Sicily, the Aeolian Islands and the area of Naples. The three active European volcanoes (Etna, Stromboli and Vesuvius) are included. The investigation is in the frame of a program for the surveillance of active volcanoes by geophysical (including remote sensing thermal methods) and geochemical methods. By the multispectral analysis of ERTS-1 data it is intended to study the spectral behavior of the volcanic materials as well as the major geological lineaments with special reference to those associated with the volcanic region. Secondary objectives are also the determination of the hydrographic network seasonal behavior and the relationship between the vegetation cover and the different type of soils and rocks.

Characteristics of pristine volcanic materials: Beneficial and harmful effects and their management for restoration of agroecosystem.

PubMed

Anda, Markus; Suparto; Sukarman

2016-02-01

Eruption of Sinabung volcano in Indonesia began again in 2010 after resting for 1200 years. The volcano is daily emitting ash and pyroclastic materials since September 2013 to the present, damaging agroecosystems and costing for management restoration. The objective of the study was to assess properties and impacts of pristine volcanic material depositions on soil properties and to provide management options for restoring the affected agroecosytem. Land satellite imagery was used for field studies to observe the distribution, thickness and properties of ashfall deposition. The pristine ashfall deposits and the underlying soils were sampled for mineralogical, soluble salt, chemical, physical and toxic compound analyses. Results showed that uneven distribution of rainfall at the time of violent eruption caused the areas receiving mud ashfall developed surface encrustation, which was not occur in areas receiving dry ashfall. Ashfall damaged the agroecosytem by burning vegetation, forming surface crusts, and creating soil acidity and toxicity. X-ray diffraction (XRD) and scanning electron microscope (SEM) analyses of encrustated layer indicated the presence of gypsum and jarosite minerals. Gypsum likely acted as a cementing agent in the formation of the encrustation layer with extremely low pH (2.9) and extremely high concentrations of Al, Ca and S. Encrustation is responsible for limited water infiltration and root penetration, while the extremely high concentration of Al is responsible for crop toxicity. Mud ashfall and dry ashfall deposits also greatly changed the underlying soil properties by decreasing soil pH and cation exchange capacity and by increasing exchangeable Ca, Al, and S availability. Despite damaging vegetation in the short-term, the volcanic ashfall enriched the soil in the longer term by adding nutrients like Ca, Mg, K, Na, P, Si and S. Suggested management practices to help restore the agroecosystem after volcanic eruptions include: (i) the

Acidic volatiles and the Mars Soil

NASA Astrophysics Data System (ADS)

Banin, A.; Han, F. X.; Kan, I.; Cicelsky, A.

1997-06-01

Large portions of Mars' surface are covered with deposits of fine, homogeneous, weathered dusty-soil material. Nanophase iron oxides, silicate mineraloids, and salts prevail in the soil. The mode of formation of this somewhat peculiar type of soil is still far from being clear. One scenario suggests that weathering took place during early epochs when Mars may have been ``warm and wet.'' The properties of the soil are not easily reconciled with this scenario. We propose another possible scenario that attributes, in part, the peculiar nature of the Martian dust and soil to a relatively ``young'' weathering product formed during the last few hundreds of millions of years in a process that involves acidic volatiles. We tested this hypothesis in an experimental study of the first step of acidolytic weathering of a partly palagonitized volcanic tephra of hawaiitic lava origin, using sulfuric, hydrochloric and nitric acids and their mixtures. The tephra effectively ``neutralize'' the added acidity. The protonic acidity added to the tephra attacks the primary minerals, releasing Fe, Al, and Mg, which control the pH, acting as Lewis-acid species of varying acid strengths. The full amount of acidity added to the tephra is stored in it, but only a very small fraction is preserved as the original protonic acidity. The majority of the added sulfate and chloride were present as salts and easily solubilized minerals. Well-crystallized sulfate salt minerals of aluminum and calcium were detected by powder X ray diffractometry, whereas secondary magnesium and iron minerals were not detected, due probably to lack of crystallinity. The presence of gypsum (CaSO4.2H2O) and alunogen (Al2(SO4)3.17H2O) is probably responsible for the observed increased hygroscopicity of the acidified tephra and their tendency to form hardened crusts. We suggest that if this mechanism is of importance on Mars, then the chemically weathered component of the Martian soil consists of a salt-rich mineral

Hazards in volcanic arcs

NASA Astrophysics Data System (ADS)

Sparks, S. R.

2008-12-01

Volcanic eruptions in arcs are complex natural phenomena, involving the movement of magma to the Earth's surface and interactions with the surrounding crust during ascent and with the surface environment during eruption, resulting in secondary hazards. Magma changes its properties profoundly during ascent and eruption and many of the underlying processes of heat and mass transfer and physical property changes that govern volcanic flows and magmatic interactions with the environment are highly non-linear. Major direct hazards include tephra fall, pyroclastic flows from explosions and dome collapse, volcanic blasts, lahars, debris avalanches and tsunamis. There are also health hazards related to emissions of gases and very fine volcanic ash. These hazards and progress in their assessment are illustrated mainly from the ongoing eruption of the Soufriere Hills volcano. Montserrat. There are both epistemic and aleatory uncertainties in the assessment of volcanic hazards, which can be large, making precise prediction a formidable objective. Indeed in certain respects volcanic systems and hazardous phenomena may be intrinsically unpredictable. As with other natural phenomena, predictions and hazards inevitably have to be expressed in probabilistic terms that take account of these uncertainties. Despite these limitations significant progress is being made in the ability to anticipate volcanic activity in volcanic arcs and, in favourable circumstances, make robust hazards assessments and predictions. Improvements in monitoring ground deformation, gas emissions and seismicity are being combined with more advanced models of volcanic flows and their interactions with the environment. In addition more structured and systematic methods for assessing hazards and risk are emerging that allow impartial advice to be given to authorities during volcanic crises. There remain significant issues of how scientific advice and associated uncertainties are communicated to provide effective

Source identification of soil mercury in the Spanish islands.

PubMed

Rodríguez Martín, José Antonio; Carbonell, Gregoria; Nanos, Nikos; Gutiérrez, Carmen

2013-02-01

This study spatially analysed the relation between mercury (Hg) content in soil and Hg in rock fragment for the purpose of assessing natural soil Hg contribution compared with Hg from human inputs. We present the Hg content of 318 soil and rock fragment samples from 11 islands distributed into two Spanish archipelagos (the volcanic Canary Islands [Canaries] and the Mediterranean Balearic [Balearic] islands). Assumedly both are located far enough away from continental Hg sources to be able to minimise the effects of diffuse pollution. Physical and chemical soil properties were also specified for the samples. Hg contents were significantly greater in the Balearic limestone soils (61 μg kg(-1)) than in the volcanic soils of the Canaries (33 μg kg(-1)). Hg levels were also greater in topsoil than in rocky fragments, especially on the Balearics. The soil-to-rock ratios varied between 1 and 30. Interestingly, the highest topsoil-to-rock Hg ratio (>16 ×) was found in the vicinity of a coal-fired power plant in Majorca, whereas no similar areas in the Canary archipelago were identified.

Skin hardening effect in patients with polymorphic light eruption: comparison of UVB hardening in hospital with a novel home UV-hardening device.

PubMed

Franken, S M; Genders, R E; de Gruijl, F R; Rustemeyer, T; Pavel, S

2013-01-01

An effective prophylactic treatment of patients with polymorphic light eruption (PLE) consists of repeated low, gradually increasing exposures to UVB radiation. This so-called UV(B) hardening induces better tolerance of the skin to sunlight. SunshowerMedical company (Amsterdam) has developed an UV (B) source that can be used during taking shower. The low UV fluence of this apparatus makes it an interesting device for UV hardening. In a group of PLE patients, we compared the effectiveness of the irradiation with SunshowerMedical at home with that of the UVB treatment in the hospital. The PLE patients were randomized for one of the treatments. The hospital treatment consisted of irradiations with broad-band UVB (Waldmann 85/UV21 lamps) twice a week during 6 weeks. The home UV-device was used each day with the maximal irradiation time of 6 min. The outcome assessment was based on the information obtained from patients' dermatological quality of life (DLQI) questionnaires, the ability of both phototherapies to reduce the provocation reaction and from the patients' evaluation of the long-term benefits of their phototherapies. Sixteen patients completed treatment with SunshowerMedical and thirteen completed treatment in hospital. Both types of phototherapy were effective. There was a highly significant improvement in DLQI with either treatment. In most cases, the hardening reduced or even completely suppressed clinical UV provocation of PLE. The patients using SunshowerMedical at home were, however, much more content with the treatment procedure than the patients visiting the dermatological units. Both treatments were equally effective in the induction of skin tolerance to sunlight in PLE patients. However, the home treatment was much better accepted than the treatment in the hospital. © 2011 The Authors. Journal of the European Academy of Dermatology and Venereology © 2011 European Academy of Dermatology and Venereology.

Generation Mechanism of Work Hardened Surface Layer in Metal Cutting

NASA Astrophysics Data System (ADS)

Hikiji, Rikio; Kondo, Eiji; Kawagoishi, Norio; Arai, Minoru

Finish machining used to be carried out in grinding, but it is being replaced by cutting with very small undeformed chip thickness. In ultra precision process, the effects of the cutting conditions and the complicated factors on the machined surface integrity are the serious problems. In this research, work hardened surface layer was dealt with as an evaluation of the machined surface integrity and the effect of the mechanical factors on work hardening was investigated experimentally in orthogonal cutting. As a result, it was found that work hardened surface layer was affected not only by the shear angle varied under the cutting conditions and the thrust force of cutting resistance, but also by the thrust force acting point, the coefficient of the thrust force and the compressive stress equivalent to the bulk hardness. Furthermore, these mechanical factors acting on the depth of the work hardened surface layer were investigated with the calculation model.

Effects of Ce additions on the age hardening response of Mg–Zn alloys

DOE Office of Scientific and Technical Information (OSTI.GOV)

Langelier, Brian, E-mail: langelb@mcmaster.ca; Esmaeili, Shahrzad

2015-03-15

The effects of Ce additions on the precipitation hardening behaviour of Mg–Zn are examined for a series of alloys, with Ce additions at both alloying and microalloying levels. The alloys are artificially aged, and studied using hardness measurement and X-ray diffraction, as well as optical and transmission electron microscopy. It is found that the age-hardening effect is driven by the formation of fine precipitates, the number density of which is related to the Zn content of the alloy. Conversely, the Ce content is found to slightly reduce hardening. When the alloy content of Ce is high, large secondary phase particlesmore » containing both Ce and Zn are present, and remain stable during solutionizing. These particles effectively reduce the amount of Zn available as solute for precipitation, and thereby reduce hardening. Combining hardness results with thermodynamic analysis of alloy solute levels also suggests that Ce can have a negative effect on hardening when present as solutes at the onset of ageing. This effect is confirmed by designing a pre-ageing heat treatment to preferentially remove Ce solutes, which is found to restore the hardening capability of an Mg–Zn–Ce alloy to the level of the Ce-free alloy. - Highlights: • The effects of Ce additions on precipitation in Mg–Zn alloys are examined. • Additions of Ce to Mg–Zn slightly reduce the age-hardening response. • Ce-rich secondary phase particles deplete the matrix of Zn solute. • Hardening is also decreased when Ce is present in solution. • Pre-ageing to preferentially precipitate out Ce restores hardening capabilities.« less

Elemental characterization of Mt. Sinabung volcanic ash, Indonesia by Neutron Activation Analysis

NASA Astrophysics Data System (ADS)

Kusmartini, I.; Syahfitri, W. Y. N.; Kurniawati, S.; Lestiani, D. D.; Santoso, M.

2017-06-01

Mount Sinabung is a volcano located in North Sumatera, Indonesia which has been recorded not erupted since 1600. However in 2013 it has been erupted and cause of black thick smog, rain sand and volcanic ash. Volcanic ash containing trace elements material that can be utilized in various applications but still has potential danger of heavy metals. In order to obtain an elemental composition data of volcanic ash, the characterization of volcanic ash were carried out using Neutron Activation Analysis. The volcanic ash was taken from Mt. Sinabung eruption. Samples were irradiated at the rabbit system in the reactor G.A Siwabessy facilities with neutron flux ˜ 1013 n.cm-2.s-1 and then counted using HPGe detector. Method validation was carried out by SRM NIST Coal Fly Ash 1633b and NIST 2711a Montana II Soil with recovery values were in the range of 96-108% and 95-106% respectively. The results showed that major elements; Al, Na, Ca and Fe, concentrations were 8.7, 1.05, 2.98 and 7.44 %, respectively, minor elements K, Mg, Mn, Ti, V and Zn were 0.87%, 0.78%, 0.18%, 0.62%, 197.13 ppm and 109.35 ppm, respectively, heavy metals; As, Cr, Co and Sb, contents were 4.48, 11.75, 17.13 and 0.35 ppm, respectively while rare earth elements such as Ce, Eu, La, Nd, Sm, Yb were 45.33, 1.22, 19.63, 20.34, 3.86, and 2.57 ppm respectively. The results of the elemental contents of volcanic ash that has been obtained can be used as the scientific based data for volcanic material utilization by considering the economic potential of elements contained and also the danger of the heavy metals content.

Evidence of recent deep magmatic activity at Cerro Bravo-Cerro Machín volcanic complex, central Colombia. Implications for future volcanic activity at Nevado del Ruiz, Cerro Machín and other volcanoes

NASA Astrophysics Data System (ADS)

Londono, John Makario

2016-09-01

In the last nine years (2007-2015), the Cerro Bravo-Cerro Machín volcanic complex (CBCMVC), located in central Colombia, has experienced many changes in volcanic activity. In particular at Nevado del Ruiz volcano (NRV), Cerro Machin volcano (CMV) and Cerro Bravo (CBV) volcano. The recent activity of NRV, as well as increasing seismic activity at other volcanic centers of the CBCMVC, were preceded by notable changes in various geophysical and geochemical parameters, that suggests renewed magmatic activity is occurring at the volcanic complex. The onset of this activity started with seismicity located west of the volcanic complex, followed by seismicity at CBV and CMV. Later in 2010, strong seismicity was observed at NRV, with two small eruptions in 2012. After that, seismicity has been observed intermittently at other volcanic centers such as Santa Isabel, Cerro España, Paramillo de Santa Rosa, Quindío and Tolima volcanoes, which persists until today. Local deformation was observed from 2007 at NRV, followed by possible regional deformation at various volcanic centers between 2011 and 2013. In 2008, an increase in CO2 and Radon in soil was observed at CBV, followed by a change in helium isotopes at CMV between 2009 and 2011. Moreover, SO2 showed an increase from 2010 at NRV, with values remaining high until the present. These observations suggest that renewed magmatic activity is currently occurring at CBCMVC. NRV shows changes in its activity that may be related to this new magmatic activity. NRV is currently exhibiting the most activity of any volcano in the CBCMVC, which may be due to it being the only open volcanic system at this time. This suggests that over the coming years, there is a high probability of new unrest or an increase in volcanic activity of other volcanoes of the CBCMVC.

Identification of β-propeller phytase-encoding genes in culturable Paenibacillus and Bacillus spp. from the rhizosphere of pasture plants on volcanic soils.

PubMed

Jorquera, Milko A; Crowley, David E; Marschner, Petra; Greiner, Ralf; Fernández, María Teresa; Romero, Daniela; Menezes-Blackburn, Daniel; De La Luz Mora, María

2011-01-01

Phytate is one of the most abundant sources of organic phosphorus (P) in soils, but must be mineralized by phytase-producing bacteria to release P for plant uptake. Microbial inoculants based on Bacillus spp. have been developed commercially, but few studies have evaluated the ecology of these bacteria in the rhizosphere or the types of enzymes that they produce. Here, we studied the diversity of aerobic endospore-forming bacteria (EFB) with the ability to mineralize phytate in the rhizosphere of pasture plants grown in volcanic soils of southern Chile. PCR methods were used to detect candidate phytase-encoding genes and to identify EFB bacteria that carry these genes. This study revealed that the phytate-degrading EFB populations of pasture plants included species of Paenibacillus and Bacillus, which carried genes encoding β-propeller phytase (BPP). Assays of enzymatic activity confirmed the ability of these rhizosphere isolates to degrade phytate. The phytase-encoding genes described here may prove valuable as molecular markers to evaluate the role of EFB in organic P mobilization in the rhizosphere. © 2010 Federation of European Microbiological Societies. Published by Blackwell Publishing Ltd. All rights reserved.

Segmentation-free empirical beam hardening correction for CT.

PubMed

Schüller, Sören; Sawall, Stefan; Stannigel, Kai; Hülsbusch, Markus; Ulrici, Johannes; Hell, Erich; Kachelrieß, Marc

2015-02-01

The polychromatic nature of the x-ray beams and their effects on the reconstructed image are often disregarded during standard image reconstruction. This leads to cupping and beam hardening artifacts inside the reconstructed volume. To correct for a general cupping, methods like water precorrection exist. They correct the hardening of the spectrum during the penetration of the measured object only for the major tissue class. In contrast, more complex artifacts like streaks between dense objects need other techniques of correction. If using only the information of one single energy scan, there are two types of corrections. The first one is a physical approach. Thereby, artifacts can be reproduced and corrected within the original reconstruction by using assumptions in a polychromatic forward projector. These assumptions could be the used spectrum, the detector response, the physical attenuation and scatter properties of the intersected materials. A second method is an empirical approach, which does not rely on much prior knowledge. This so-called empirical beam hardening correction (EBHC) and the previously mentioned physical-based technique are both relying on a segmentation of the present tissues inside the patient. The difficulty thereby is that beam hardening by itself, scatter, and other effects, which diminish the image quality also disturb the correct tissue classification and thereby reduce the accuracy of the two known classes of correction techniques. The herein proposed method works similar to the empirical beam hardening correction but does not require a tissue segmentation and therefore shows improvements on image data, which are highly degraded by noise and artifacts. Furthermore, the new algorithm is designed in a way that no additional calibration or parameter fitting is needed. To overcome the segmentation of tissues, the authors propose a histogram deformation of their primary reconstructed CT image. This step is essential for the proposed

Segmentation-free empirical beam hardening correction for CT

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schüller, Sören; Sawall, Stefan; Stannigel, Kai

2015-02-15

Purpose: The polychromatic nature of the x-ray beams and their effects on the reconstructed image are often disregarded during standard image reconstruction. This leads to cupping and beam hardening artifacts inside the reconstructed volume. To correct for a general cupping, methods like water precorrection exist. They correct the hardening of the spectrum during the penetration of the measured object only for the major tissue class. In contrast, more complex artifacts like streaks between dense objects need other techniques of correction. If using only the information of one single energy scan, there are two types of corrections. The first one ismore » a physical approach. Thereby, artifacts can be reproduced and corrected within the original reconstruction by using assumptions in a polychromatic forward projector. These assumptions could be the used spectrum, the detector response, the physical attenuation and scatter properties of the intersected materials. A second method is an empirical approach, which does not rely on much prior knowledge. This so-called empirical beam hardening correction (EBHC) and the previously mentioned physical-based technique are both relying on a segmentation of the present tissues inside the patient. The difficulty thereby is that beam hardening by itself, scatter, and other effects, which diminish the image quality also disturb the correct tissue classification and thereby reduce the accuracy of the two known classes of correction techniques. The herein proposed method works similar to the empirical beam hardening correction but does not require a tissue segmentation and therefore shows improvements on image data, which are highly degraded by noise and artifacts. Furthermore, the new algorithm is designed in a way that no additional calibration or parameter fitting is needed. Methods: To overcome the segmentation of tissues, the authors propose a histogram deformation of their primary reconstructed CT image. This step is essential

A permanent volcanic hazard hiding in diffuse degassing areas

NASA Astrophysics Data System (ADS)

Viveiros, Fátima; Silva, Catarina; Ferreira, Teresa; Pacheco, Joana; Luís Gaspar, João

2017-04-01

Carbon dioxide (CO2) is one of the most abundant volcanic gases and it is released not only during eruptive events, but also during periods of quiescence through fumaroles, springs and soil diffuse degassing areas. In this last case, CO2 is permanently and silently released from the soils and high CO2 concentrations can be measured if the gas accumulates in depressed and non-ventilated areas (such as caves, pits), or even if it enters in buildings. From a public health perspective CO2 is considered an inert asphyxiant gas and may be lethal when present in concentrations higher than 10 vol.%. In the last 30 years several diffuse degassing areas have been identified in different volcanic systems and lethal incidents due to high CO2 concentrations were reported in volcanic environments of Italy (Alban Hills), New Zealand (Rotorua), Cameroon (Lake Nyos and Lake Cameroon), USA (Mammoth Mountain) and Portugal (Azores archipelago). In the Azores volcanic archipelago several villages are located in diffuse degassing areas, where lethal indoor CO2 concentrations (> 20 vol.%) were measured. Recent studies showed that the rate of CO2 emission may change not only during seismo-volcanic unrest, but also due to changes in the meteorological conditions (e.g. barometric pressure, rainfall, wind speed). Few works are available in the literature with permanent monitoring of indoor CO2 in diffuse degassing environments and the monitoring tests are usually applied during a short period of time. This study shows the results of four years (2012-2016) of permanent CO2 monitoring in 12 buildings placed at Caldeiras da Ribeira Grande, an area located in the north flank of Fogo Volcano (São Miguel Island, Azores archipelago), where thermal anomalies and CO2 emissions were detected. CO2 fluxes as high as 20000 g m-2 d-1 are released from the soils and temperature in some sites reaches 100°C. Spike-like and long term variations are observed in the time series recorded by a total of 52

Devices and methods to measure H2 and CO2 concentrations in gases released from soils and low temperature fumaroles in volcanic areas

NASA Astrophysics Data System (ADS)

di Martino, R. M. R.; Camarda, M.; Gurrieri, S.; Valenza, M.

2009-04-01

Hydrogen solubility and diffusion have a great relevance to change the redox state of magmas, usually expressed by oxygen fugacity. This influences many chemical and physical properties, such as oxidation state of multivalent elements, kind and abundance of minerals and gas species. These processes change the phase ratios into the volcanic system and so the magma movement capability toward the earth surface and the eruptive dynamics. In past studies several authors (Carapezza et al., 1980; Sato et al., 1982; Sato and McGee, 1985; Wakita et al., 1980) proposed the application of the fuel cells in order to measure reducing capacity of volcanic gases. Their found some clear correlations between variation peaks and volcanic activity but a few reducing capacity changes showed no correlation with it. In this study we characterize a fuel cell device designed to measure hydrogen concentration in a gas mixture. We present test results obtained in laboratory and in field trip, carried out to verify the major interferences of others reducing gas species, commonly present in volcanic emissions, in the measurement carried out with a hydrogen fuel cell sensor. Tests were performed at controlled temperature ad pressure conditions and at air saturated pressure vapour in the cell cathode. A new device to measure simultaneously hydrogen (H2) and carbon dioxide (CO2) concentrations in soil and in low temperature fumaroles in volcanic areas was proposed. The H2-detector is a hydrogen fuel cell, whereas CO2 is measured using an I.R. spectrometer. To build a continuous monitoring station of volcanic activity both sensors were put in a case together with a data logger. Our device has 0.2 mV ppm-1 sensitivity, accuracy of ± 5 ppm and about 10 ppm resolution whit respect to the hydrogen concentration. These instrumental characteristics were obtained applying a 500 ohm resistor to the external circuit that represents the best compromise between sensitivity, resolution, instrumental

Alloy solution hardening with solute pairs

DOEpatents

Mitchell, John W.

1976-08-24

Solution hardened alloys are formed by using at least two solutes which form associated solute pairs in the solvent metal lattice. Copper containing equal atomic percentages of aluminum and palladium is an example.

Helium-induced hardening effect in polycrystalline tungsten

NASA Astrophysics Data System (ADS)

Kong, Fanhang; Qu, Miao; Yan, Sha; Zhang, Ailin; Peng, Shixiang; Xue, Jianming; Wang, Yugang

2017-09-01

In this paper, helium induced hardening effect of tungsten was investigated. 50 keV He2+ ions at fluences vary from 5 × 1015 cm-2 to 5 × 1017 cm-2 were implanted into polycrystalline tungsten at RT to create helium bubble-rich layers near the surface. The microstructure and mechanical properties of the irradiated specimens were studied by TEM and nano-indentor. Helium bubble rich layers are formed in near surface region, and the layers become thicker with the rise of fluences. Helium bubbles in the area of helium concentration peak are found to grow up, while the bubble density is almost unchanged. Obvious hardening effect is induced by helium implantation in tungsten. Micro hardness increases rapidly with the fluence firstly, and more slowly when the fluence is above 5 × 1016 cm-2. The hardening effect of tungsten can be attributed to helium bubbles, which is found to be in agreement with the Bacon-Orowan stress formula. The growing diameter is the major factor rather than helium bubbles density (voids distance) in the process of helium implantation at fluences below 5 × 1017 cm-2.

Statistical thermodynamics of strain hardening in polycrystalline solids

DOE PAGES

Langer, James S.

2015-09-18

This paper starts with a systematic rederivation of the statistical thermodynamic equations of motion for dislocation-mediated plasticity proposed in 2010 by Langer, Bouchbinder, and Lookman. The paper then uses that theory to explain the anomalous rate-hardening behavior reported in 1988 by Follansbee and Kocks and to explore the relation between hardening rate and grain size reported in 1995 by Meyers et al. A central theme is the need for physics-based, nonequilibrium analyses in developing predictive theories of the strength of polycrystalline materials.

The Effect of Grain Size on the Strain Hardening Behavior for Extruded ZK61 Magnesium Alloy

NASA Astrophysics Data System (ADS)

Zhang, Lixin; Zhang, Wencong; Chen, Wenzhen; Duan, Junpeng; Wang, Wenke; Wang, Erde

2017-12-01

The effects of grain size on the tensile and compressive strain hardening behaviors for extruded ZK61 alloys have been investigated by uniaxial tensile and compressive tests along the extrusion directions. Cylindrical tension and compression specimens of extruded ZK61 alloys with various sized grain were fabricated by annealing treatments. Tensile and compressive tests at ambient temperature were conducted at a strain rate of 0.5 × 10-3 s-1. The results indicate that both tensile strain hardening and compressive strain hardening of ZK61 alloys with different grain sizes have an athermal regime of dislocation accumulation in early deformation. The threshold stress value caused dynamic recovery is predominantly related to grain size in tensile strain hardening, but the threshold stress values for different grain sizes are almost identical in compressive strain hardening. There are obvious transition points on the tensile strain hardening curves which indicate the occurrence of dynamic recrystallization (DRX). The tensile strain hardening rate of the coarse-grained alloy obviously decreases faster than that of fine-grained alloys before DRX and the tensile strain hardening curves of different grain sizes basically tend to parallel after DRX. The compressive strain hardening rate of the fine-grained alloy obviously increases faster than that of coarse-grained alloy for twin-induced strain hardening, but compressive strain hardening curves also tend to parallel after twinning is exhausted.

Microstructural changes and strain hardening effects in abrasive contacts at different relative velocities and temperatures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rojacz, H., E-mail: rojacz@ac2t.at

2016-08-15

Strain hardening is commonly used to reach the full potential of materials and can be beneficial in tribological contacts. 2-body abrasive wear was simulated in a scratch test, aimed at strain hardening effects in various steels. Different working conditions were examined at various temperatures and velocities. Strain hardening effects and microstructural changes were analysed with high resolution scanning electron microscopy (HRSEM), electron backscatter diffraction (EBSD), micro hardness measurements and nanoindentation. Statistical analysing was performed quantifying the influence of different parameters on microstructures. Results show a crucial influence of temperature and velocity on the strain hardening in tribological contacts. Increased velocitymore » leads to higher deformed microstructures and higher increased surface hardness at a lower depth of the deformed zones at all materials investigated. An optimised surface hardness can be achieved knowing the influence of velocity (strain rate) and temperature for a “tailor-made” surface hardening in tribological systems aimed at increased wear resistance. - Highlights: •Hardening mechanisms and their intensity in tribological contacts are dependent on relative velocity and temperature. •Beneficial surface hardened zones are formed at certain running-in conditions; the scientific background is presented here. •Ferritic-pearlitic steels strain hardens via grain size reduction and decreasing interlamellar distances in pearlite. •Austenitic steels show excellent surface hardening (120% hardness increase) by twinning and martensitic transformation. •Ferritic steels with hard phases harden in the ferrite phase as per Hall-Petch equation and degree of deformation.« less

Whole rock major element chemistry of KREEP basalt clasts in lunar breccia 15205: Implications for the petrogenesis of volcanic KREEP basalts

NASA Technical Reports Server (NTRS)

Vetter, Scott K.; Shervais, John W.

1993-01-01

KREEP basalts are a major component of soils and regolith at the Apollo 15 site. Their origin is controversial: both endogenous (volcanic) and exogenous (impact melt) processes have been proposed, but it is now generally agreed that KREEP basalts are volcanic rocks derived from the nearby Apennine Bench formation. Because most pristine KREEP basalts are found only as small clasts in polymict lunar breccias, reliable chemical data are scarce. The primary aim of this study is to characterize the range in chemical composition of pristine KREEP basalt, and to use these data to decipher the petrogenesis of these unique volcanic rocks.

The Strain-Hardening Behavior of TZAV-30 Alloy After Various Heat Treatments

NASA Astrophysics Data System (ADS)

Liang, S. X.; Yin, L. X.; Zheng, L. Y.; Ma, M. Z.; Liu, R. P.

2016-02-01

The Ti-Zr-Al-V series titanium alloys with excellent mechanical properties and low density exhibit tremendous application potential as structural materials in aviation, automotive, and navigation industries. The strain-hardening behavior of Ti-30Zr-5Al-3V (wt.%, TZAV-30) alloy with various heat treatments is investigated in this study. Experimental results show that strain-hardening behavior of the examined alloy depends on the heat treatment process. The average strain-hardening exponent, n, is approximately 0.061 for WA specimen (825 °C/0.5 h/water quenching + 600 °C/4 h/air cooling), 0.068 for FC (850 °C/0.5 h/furnace cooling), 0.121 for AC (850 °C/0.5 h/air cooling), and 0.412 for WQ (850 °C/0.5 h/water quenching). Analysis of strain-hardening rate versus true strain curves indicates that higher n of AC specimen results from the lower degradation rate of strain-hardening rate with strain, and the ultrahigh n of WQ specimen is attributed to the evident increase in strain-hardening rate at the true strain from 0.04 to 0.06. Phase constitution and microstructural analyses reveal that the n of the examined alloy with α + β phases increases with the increase in the relative content of the retained β phase but is independent of average thickness of α plates. The increase in strain-hardening rate in WQ specimen depends on metastable α″ martensite and martensitic transition induced by tensile stress.

Study on the Strain Hardening Behaviors of TWIP/TRIP Steels

NASA Astrophysics Data System (ADS)

Huang, T. T.; Dan, W. J.; Zhang, W. G.

2017-10-01

Due to the complex coupling of twinning-induced plasticity (TWIP), transformation-induced plasticity (TRIP), and dislocation glide in TWIP/TRIP steels, it is difficult as well as essential to build a comprehensive strain hardening model to describe the interactions between different deformation mechanisms ( i.e., deformation twinning, martensitic transformation, and dislocation glide) and the resulted strain hardening behaviors. To address this issue, a micromechanical model is established in this paper to predict the deformation process of TWIP/TRIP steels considering both TWIP and TRIP effects. In the proposed model, the generation of deformation twinning and martensitic transformation is controlled by the stacking fault energy (SFE) of the material. In the thermodynamic calculation of SFE, deformation temperature, chemical compositions, microstrain, and temperature rise during deformation are taken into account. Varied by experimental results, the developed model can predict the stress-strain response and strain hardening behaviors of TWIP/TRIP steels precisely. In addition, the improved strength and enhanced strain hardening in Fe-Mn-C TWIP/TRIP steels due to the increased carbon content is also analyzed, which consists with literature.

Forming an age hardenable aluminum alloy with intermediate annealing

NASA Astrophysics Data System (ADS)

Wang, Kaifeng; Carsley, John E.; Stoughton, Thomas B.; Li, Jingjing; Zhang, Lianhong; He, Baiyan

2013-12-01

A method to improve formability of aluminum sheet alloys by a two-stage stamping process with intermediate annealing was developed for a non-age hardenable Al-Mg alloy where the annealing heat treatment provided recovery of cold work from the initial stamping and recrystallization of the microstructure to enhance the forming limits of the material. This method was extended to an age hardenable, Al-Mg-Si alloy, which is complicated by the competing metallurgical effects during heat treatment including recovery (softening effect) vs. precipitation (hardening effect). An annealing heat treatment process condition was discovered wherein the stored strain energy from an initial plastic deformation can be sufficiently recovered to enhance formability in a second deformation; however, there is a deleterious effect on subsequent precipitation hardening. The improvement in formability was quantified with uniaxial tensile tests as well as with the forming limit diagram. Since strain-based forming limit curves (FLC) are sensitive to pre-strain history, both stress-based FLCs and polar-effective-plastic-strain (PEPS) FLCs, which are path-independent, were used to evaluate the forming limits after preform annealing. A technique was developed to calculate the stress-based FLC in which a residual-effective-plastic-strain (REPS) was determined by overlapping the hardening curve of the pre-strained and annealed material with that of the simply-annealed- material. After converting the strain-based FLCs using the constant REPS method, it was found that the stress-based FLCs and the PEPS FLCs of the post-annealed materials were quite similar and both tools are applicable for evaluating the forming limits of Al-Mg-Si alloys for a two-step stamping process with intermediate annealing.

Validation of Volcanic Ash Forecasting Performed by the Washington Volcanic Ash Advisory Center

NASA Astrophysics Data System (ADS)

Salemi, A.; Hanna, J.

2009-12-01

In support of NOAA’s mission to protect life and property, the Satellite Analysis Branch (SAB) uses satellite imagery to monitor volcanic eruptions and track volcanic ash. The Washington Volcanic Ash Advisory Center (VAAC) was established in late 1997 through an agreement with the International Civil Aviation Organization (ICAO). A volcanic ash advisory (VAA) is issued every 6 hours while an eruption is occurring. Information about the current location and height of the volcanic ash as well as any pertinent meteorological information is contained within the VAA. In addition, when ash is detected in satellite imagery, 6-, 12- and 18-hour forecasts of ash height and location are provided. This information is garnered from many sources including Meteorological Watch Offices (MWOs), pilot reports (PIREPs), model forecast winds, radiosondes and volcano observatories. The Washington VAAC has performed a validation of their 6, 12 and 18 hour airborne volcanic ash forecasts issued since October, 2007. The volcanic ash forecasts are viewed dichotomously (yes/no) with the frequency of yes and no events placed into a contingency table. A large variety of categorical statistics useful in describing forecast performance are then computed from the resulting contingency table.

Comparison of air void content measurements in fresh versus hardened concretes.

DOT National Transportation Integrated Search

1990-01-01

This study compares the air content of freshly mixed and hardened concretes. At the fresh stage, pressure meters (Types A and B) and a volumetric meter were used to determine the air content. At the hardened stage, the air content was calculated usin...

Effect of dissolved organic carbon on the transport and attachment behaviors of Cryptosporidium parvum oocysts and carboxylate-modified microspheres advected through temperate humic and tropical volcanic agricultural soil

USGS Publications Warehouse

Mohanram, Arvind; Ray, Chittaranjan; Metge, David W.; Barber, Larry B.; Ryan, Joseph N.; Harvey, Ronald W.

2012-01-01

Transport of Cryptosporidium parvum oocysts and microspheres in two disparate (a clay- and Fe-rich, volcanic and a temperate, humic) agricultural soils were studied in the presence and absence of 100 mg L–1 of sodium dodecyl benzene sulfonate (SDBS), and Suwannee River Humic Acid (SRHA) at pH 5.0–6.0. Transport of carboxylate-modified, 1.8 μm microspheres in soil columns was highly sensitive to the nature of the dissolved organic carbon (DOC), whereas oocysts transport was more affected by soil mineralogy. SDBS increased transport of microspheres from 48% to 87% through the tropical soil and from 43% to 93% in temperate soil. In contrast, SRHA reduced transport of microspheres from 48% to 28% in tropical soil and from 43% to 16% in temperate soil. SDBS also increased oocysts transport through the temperate soil 5-fold, whereas no oocyst transport was detected in tropical soil. SRHA had only a nominal effect in increasing oocysts transport in tropical soil, but caused a 6-fold increase in transport through the temperate soil. Amendments of only 4 mg L–1 SRHA and SDBS decreased oocyst hydrophobicity from 66% to 20% and from 66% to 5%, respectively. However, SDBS increased microsphere hydrophobicity from 16% to 33%. Soil fines, which includes clays, and SRHA, both caused the oocysts zeta potential (ζ) to become more negative, but caused the highly hydrophilic microspheres to become less negatively charged. The disparate behaviors of the two colloids in the presence of an ionic surfactant and natural organic matter suggest that microspheres may not be suitable surrogates for oocysts in certain types of soils. These results indicate that whether or not DOC inhibits or promotes transport of oocysts and microspheres in agricultural soils and by how much, depends not only on the surface characteristics of the colloid, but the nature of the DOC and the soil mineralogy.

Physico-chemical studies of hardened cement paste structure with micro-reinforcing fibers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Steshenko, Aleksei, E-mail: steshenko.alexey@gmail.com; Kudyakov, Aleksander; Konusheva, Viktoriya

The results of physico-chemical studies of modified hardened cement paste with micro-reinforcing fibers are given in this article. The goal was to study the reasons of the increase of strength properties of modified hardened cement paste by the method of X-ray diffraction and electron microscopy. It is shown that the use of mineral fibers in the production of cement based material has positive effect on its properties. The study found out that the increase in the strength of the hardened cement paste with micro-reinforcing fibers is due to the increase of the rate of hydration of cement without a significantmore » change in the phase composition in comparison with hardened cement paste without additive. The results of microstructure investigation (of control samples and samples of the reinforced hardened cement paste) have shown that introduction of mineral fibers in the amount of 0.1-2 % by weight of cement provides the structure of the homogeneous microporous material with uniform distribution of the crystalline phase provided by densely packed hydrates.« less

Steep spatial gradients of volcanic and marine sulfur in Hawaiian rainfall and ecosystems.

PubMed

Bern, Carleton R; Chadwick, Oliver A; Kendall, Carol; Pribil, Michael J

2015-05-01

Sulfur, a nutrient required by terrestrial ecosystems, is likely to be regulated by atmospheric processes in well-drained, upland settings because of its low concentration in most bedrock and generally poor retention by inorganic reactions within soils. Environmental controls on sulfur sources in unpolluted ecosystems have seldom been investigated in detail, even though the possibility of sulfur limiting primary production is much greater where atmospheric deposition of anthropogenic sulfur is low. Here we measure sulfur isotopic compositions of soils, vegetation and bulk atmospheric deposition from the Hawaiian Islands for the purpose of tracing sources of ecosystem sulfur. Hawaiian lava has a mantle-derived sulfur isotopic composition (δ(34)S VCDT) of -0.8‰. Bulk deposition on the island of Maui had a δ(34)S VCDT that varied temporally, spanned a range from +8.2 to +19.7‰, and reflected isotopic mixing from three sources: sea-salt (+21.1‰), marine biogenic emissions (+15.6‰), and volcanic emissions from active vents on Kilauea Volcano (+0.8‰). A straightforward, weathering-driven transition in ecosystem sulfur sources could be interpreted in the shift from relatively low (0.0 to +2.7‰) to relatively high (+17.8 to +19.3‰) soil δ(34)S values along a 0.3 to 4100 ka soil age-gradient, and similar patterns in associated vegetation. However, sub-kilometer scale spatial variation in soil sulfur isotopic composition was found along soil transects assumed by age and mass balance to be dominated by atmospheric sulfur inputs. Soil sulfur isotopic compositions ranged from +8.1 to +20.3‰ and generally decreased with increasing elevation (0-2000 m), distance from the coast (0-12 km), and annual rainfall (180-5000 mm). Such trends reflect the spatial variation in marine versus volcanic inputs from atmospheric deposition. Broadly, these results illustrate how the sources and magnitude of atmospheric deposition can exert controls over ecosystem sulfur

Induction of a Hardening Phenomenon and Quantitative Changes of Ceramides in Stratum Corneum

PubMed Central

Park, Sook Young; Kim, Jin Hye; Cho, Soo Ick; Kim, Kyeong Il; Cho, Hee Jin; Park, Chun Wook; Lee, Cheol Heon

2014-01-01

Background Hardening phenomenon of human skin after repeated exposure to the irritants is well-known, but the precise mechanism remains elusive. Objective To modify the previous experimental model of hardening phenomenon by repeated applications of two different concentrations of sodium lauryl sulfate (SLS) solutions to Korean healthy volunteers and to investigate the quantitative changes of ceramides in stratum corneum before and after chronic repeated irritation. Methods Eight hundred microliters of distilled water containing 0.1% and 2% SLS was applied for 10 minutes on the forearm of 41 healthy volunteers for 3 weeks. After an intervening 3-week rest, 24-hour patch tests with 1% SLS were conducted on previously irritated sites. Transepidermal water loss (TEWL), erythema index and quantity of ceramide were measured in the stratum corneum before and after irritation. Results TEWL values on the sites preirritated with 2% SLS were lower than those with 0.1% SLS. Hardening phenomenon occurred in 24 volunteers at day 44. The changes in ceramide levels were not significantly higher in the hardened skin than in the non-hardened skin. Conclusion Repetitive stimulation with a higher concentration of SLS can more easily trigger skin hardening. PMID:24648684

Precipitation hardening austenitic superalloys

DOEpatents

Korenko, Michael K.

1985-01-01

Precipitation hardening, austenitic type superalloys are described. These alloys contain 0.5 to 1.5 weight percent silicon in combination with about 0.05 to 0.5 weight percent of a post irradiation ductility enhancing agent selected from the group of hafnium, yttrium, lanthanum and scandium, alone or in combination with each other. In addition, when hafnium or yttrium are selected, reductions in irradiation induced swelling have been noted.

[Sediment transport characteristics at different erosion stages for non-hardened roads of the Shenfu Coalfield, west China].

PubMed

Guo, Ming-ming; Wang, Wen-long; Li, Jian-ming; Huang, Peng-fei; Zhu, Bao-cai; Wang, Zhen; Luo, Ting

2015-02-01

Non-hardened roads formed in the production of the Shenfu Coalfield have a unique condition of underlying surface. The road surface is composed of a regolith layer with a certain thickness resulted from long-term rolling and thus, is characterized by weakened anti-scourabilty and anti-erodibility. In contrast, soil layer below the regolith has a higher bulk density and anti-erodibility. The processes of soil erosion on the non-hardened roads exhibit some differences under rainfall condition. The process of sediment transport and the relationship between sediment transport rate and erosion factors at different erosion stages were studied on non-hardened roads with slope degrees ranging from 3° to 12° (3°, 6°, 9°, 12°) by a field experiment under artificial rainfall. Results showed that the first peak of sediment transport on the regolith surface was observed at the sheet erosion stage. Sheet erosion occurred only at 3° slope degree, with an average variation coefficient of 0.07 for sediment transport rate. Rills in every testing began to develop at slope degrees of 6° to 12° about 15 min after runoff initiation. At the sheet erosion stage, the process of sediment transport fluctuated considerably at rainfall intensities of > 1.5 mm · min(-1), but the differences in its variation were little at the three slope degrees, with average variation coefficients of 0.20, 0.19 and 0.16, respectively. Rainfall intensity had a more significant impact on sediment transport rate than slope degree. The process of sediment transport at the rill erosion stage fluctuated, but the fluctuation was obviously smaller than that at the sheet erosion stage, with average variation coefficients of 0.05, 0.09 and 0.10 at the three slope degrees. Many wide and shallow rills evolved at the rill erosion stage. The sediment transport rate could be well predicted by a power function of rainfall intensity and slope degree at the sheet and rill erosion stages. The stable sediment transport

Volcanic sulfur dioxide index and volcanic explosivity index inferred from eruptive volume of volcanoes in Jeju Island, Korea: application to volcanic hazard mitigation

NASA Astrophysics Data System (ADS)

Ko, Bokyun; Yun, Sung-Hyo

2016-04-01

Jeju Island located in the southwestern part of Korea Peninsula is a volcanic island composed of lavaflows, pyroclasts, and around 450 monogenetic volcanoes. The volcanic activity of the island commenced with phreatomagmatic eruptions under subaqueous condition ca. 1.8-2.0 Ma and lasted until ca. 1,000 year BP. For evaluating volcanic activity of the most recently erupted volcanoes with reported age, volcanic explosivity index (VEI) and volcanic sulfur dioxide index (VSI) of three volcanoes (Ilchulbong tuff cone, Songaksan tuff ring, and Biyangdo scoria cone) are inferred from their eruptive volumes. The quantity of eruptive materials such as tuff, lavaflow, scoria, and so on, is calculated using a model developed in Auckland Volcanic Field which has similar volcanic setting to the island. The eruptive volumes of them are 11,911,534 m3, 24,987,557 m3, and 9,652,025 m3, which correspond to VEI of 3, 3, and 2, respectively. According to the correlation between VEI and VSI, the average quantity of SO2 emission during an eruption with VEI of 3 is 2-8 × 103 kiloton considering that the island was formed under intraplate tectonic setting. Jeju Island was regarded as an extinct volcano, however, several studies have recently reported some volcanic eruption ages within 10,000 year BP owing to the development in age dating technique. Thus, the island is a dormant volcano potentially implying high probability to erupt again in the future. The volcanoes might have explosive eruptions (vulcanian to plinian) with the possibility that SO2 emitted by the eruption reaches stratosphere causing climate change due to backscattering incoming solar radiation, increase in cloud reflectivity, etc. Consequently, recommencement of volcanic eruption in the island is able to result in serious volcanic hazard and this study provides fundamental and important data for volcanic hazard mitigation of East Asia as well as the island. ACKNOWLEDGMENTS: This research was supported by a grant [MPSS

Plant resistance to cold stress: mechanisms and environmental signals triggering frost hardening and dehardening.

PubMed

Beck, Erwin H; Heim, Richard; Hansen, Jens

2004-12-01

This introductory overview shows that cold, in particular frost, stresses a plant in manifold ways and that the plant's response, being injurious or adaptive, must be considered a syndrome rather than a single reaction. In the course of the year perennial plants of the temperate climate zones undergo frost hardening in autumn and dehardening in spring. Using Scots pine (Pinus sylvestris L.) as a model plant the environmental signals inducing frost hardening and dehardening, respectively, were investigated. Over 2 years the changes in frost resistance of Scots pine needles were recorded together with the annual courses of day-length and ambient temperature. Both act as environmental signals for frost hardening and dehardening. Climate chamber experiments showed that short day-length as a signal triggering frost hardening could be replaced by irradiation with far red light, while red light inhibited hardening. The involvement of phytochrome as a signal receptor could be corroborated by respective night-break experiments. More rapid frost hardening than by short day or far red treatment was achieved by applying a short period (6 h) of mild frost which did not exceed the plant's cold resistance. Both types of signals were independently effective but the rates of frost hardening were not additive. The maximal rate of hardening was - 0.93 degrees C per day and frost tolerance of less than < - 72 degrees C was achieved. For dehardening, temperature was an even more effective signal than day-length.

Simulating the influence of scatter and beam hardening in dimensional computed tomography

NASA Astrophysics Data System (ADS)

Lifton, J. J.; Carmignato, S.

2017-10-01

Cone-beam x-ray computed tomography (XCT) is a radiographic scanning technique that allows the non-destructive dimensional measurement of an object’s internal and external features. XCT measurements are influenced by a number of different factors that are poorly understood. This work investigates how non-linear x-ray attenuation caused by beam hardening and scatter influences XCT-based dimensional measurements through the use of simulated data. For the measurement task considered, both scatter and beam hardening are found to influence dimensional measurements when evaluated using the ISO50 surface determination method. On the other hand, only beam hardening is found to influence dimensional measurements when evaluated using an advanced surface determination method. Based on the results presented, recommendations on the use of beam hardening and scatter correction for dimensional XCT are given.

Method for increasing the rate of compressive strength gain in hardenable mixtures containing fly ash

DOEpatents

Liskowitz, John W.; Wecharatana, Methi; Jaturapitakkul, Chai; Cerkanowicz, deceased, Anthony E.

1997-01-01

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention provides a method for increasing the rate of strength gain of a hardenable mixture containing fly ash by exposing the fly ash to an aqueous slurry of calcium oxide (lime) prior to its incorporation into the hardenable mixture. The invention further relates to such hardenable mixtures, e.g., concrete and mortar, that contain fly ash pre-reacted with calcium oxide. In particular, the fly ash is added to a slurry of calcium oxide in water, prior to incorporating the fly ash in a hardenable mixture. The hardenable mixture may be concrete or mortar. In a specific embodiment, mortar containing fly ash treated by exposure to an aqueous lime slurry are prepared and tested for compressive strength at early time points.

Contrasting origin of two clay-rich debris flows at Cayambe Volcanic Complex, Ecuador

NASA Astrophysics Data System (ADS)

Detienne, M.; Delmelle, P.; Guevara, A.; Samaniego, P.; Opfergelt, S.; Mothes, P. A.

2017-04-01

We investigate the sedimentological and mineralogical properties of a debris flow deposit west of Cayambe Volcanic Complex, an ice-clad edifice in Ecuador. The deposit exhibits a matrix facies containing up to 16 wt% of clays. However, the stratigraphic relationship of the deposit with respect to the Canguahua Formation, a widespread indurated volcaniclastic material in the Ecuadorian inter-Andean Valley, and the deposit alteration mineralogy differ depending on location. Thus, two different deposits are identified. The Río Granobles debris flow deposit ( 1 km3) is characterised by the alteration mineral assemblage smectite + jarosite, and sulphur isotopic analyses point to a supergene hydrothermal alteration environment. This deposit probably derives from a debris avalanche initiated before 14-21 ka by collapse of a hydrothermally altered rock mass from the volcano summit. In contrast, the alteration mineralogy of the second debris flow deposit, which may itself comprise more than one unit, is dominated by halloysite + smectite and relates to a shallower and more recent (<13 ky) mass movement of high-altitude (>3200 m) volcanic soils. Our study reinforces the significance of hydrothermal alteration in weakening volcano flanks and in favouring rapid transformation of a volcanic debris avalanche into a clay-rich debris flow. It also demonstrates that mineralogical analysis provides crucial information for resolving the origin of a debris flow deposit in volcanic terrains. Finally, we posit that slope instability, promoted by ongoing subglacial hydrothermal alteration, remains a significant hazard at Cayambe Volcanic Complex.

Assessment of BART Fire-Hardening Programs.

DOT National Transportation Integrated Search

1982-09-01

This report presents the results of an assessment of the Bay Area Rapid Transit District (BART) vehicle fire hardening. The report assesses the overall effort to improve the fire safety of the current BART vehicles through the removal of prospective ...

Developments in Radiation-Hardened Electronics Applicable to the Vision for Space Exploration

NASA Technical Reports Server (NTRS)

Keys, Andrew S.; Frazier, Donald O.; Patrick , Marshall C.; Watson, Michael D.; Johnson, Michael A.; Cressler, John D.; Kolawa, Elizabeth A.

2007-01-01

The Radiation Hardened Electronics for Space Exploration (RHESE) project develops the advanced technologies required to produce radiation hardened electronics, processors, and devices in support of the anticipated requirements of NASA's Constellation program. Methods of protecting and hardening electronics against the encountered space environment are discussed. Critical stages of a spaceflight mission that are vulnerable to radiation-induced interruptions or failures are identified. Solutions to mitigating the risk of radiation events are proposed through the infusion of RHESE technology products and deliverables into the Constellation program's spacecraft designs.

Update on radiation-hardened microcomputers for robotics and teleoperated systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sias, F.R. Jr.; Tulenko, J.S.

1993-12-31

Since many programs sponsored by the Department of Defense are being canceled, it is important to select carefully radiation-hardened microprocessors for projects that will mature (or will require continued support) several years in the future. At the present time there are seven candidate 32-bit processors that should be considered for long-range planning for high-performance radiation-hardened computer systems. For Department of Energy applications it is also important to consider efforts at standardization that require the use of the VxWorks operating system and hardware based on the VMEbus. Of the seven processors, one has been delivered and is operating and other systemsmore » are scheduled to be delivered late in 1993 or early in 1994. At the present time the Honeywell-developed RH32, the Harris RH-3000 and the Harris RHC-3000 are leading contenders for meeting DOE requirements for a radiation-hardened advanced 32-bit microprocessor. These are all either compatible with or are derivatives of the MIPS R3000 Reduced Instruction Set Computer. It is anticipated that as few as two of the seven radiation-hardened processors will be supported by the space program in the long run.« less

Soil genesis on the island of Bermuda in the Quaternary: the importance of African dust transport and deposition

USGS Publications Warehouse

Muhs, Daniel R.; Budahn, James R.; Prospero, Joseph M.; Skipp, Gary; Herwitz, Stanley R.

2012-01-01

The origin of terra rossa, red or reddish-brown, clay-rich soils overlying high-purity carbonate substrates, has intrigued geologists and pedologists for decades. Terra rossa soils can form from accumulation of insoluble residues during dissolution of the host limestones, addition of volcanic ash, or addition of externally derived, long-range-transported (LRT) aeolian particles. We studied soils and paleosols on high-purity, carbonate aeolianites of Quaternary age on Bermuda, where terra rossa origins have been debated for more than a century. Potential soil parent materials on this island include sand-sized fragments of local volcanic bedrock, the LRT, fine-grained (N/YbN, GdN/YbN that can be distinguished from African dust and lower Mississippi River valley loess. Bermuda soils have Sc-Th-La, Cr-Ta-Nd, and Eu/Eu*, LaN/YbN, GdN/YbN that indicate derivation from a combination of LRT dust from Africa and local volcanic bedrock. Our results indicate that soils on islands in a very broad latitudinal belt of the western Atlantic margin have been influenced by African LRT dust inputs over much of the past –500 ka.

Wavelet analysis for the study of the relations among soil radon anomalies, volcanic and seismic events: the case of Mt. Etna (Italy)

NASA Astrophysics Data System (ADS)

Ferrera, Elisabetta; Giammanco, Salvatore; Cannata, Andrea; Montalto, Placido

2013-04-01

From November 2009 to April 2011 soil radon activity was continuously monitored using a Barasol® probe located on the upper NE flank of Mt. Etna volcano, close either to the Piano Provenzana fault or to the NE-Rift. Seismic and volcanological data have been analyzed together with radon data. We also analyzed air and soil temperature, barometric pressure, snow and rain fall data. In order to find possible correlations among the above parameters, and hence to reveal possible anomalies in the radon time-series, we used different statistical methods: i) multivariate linear regression; ii) cross-correlation; iii) coherence analysis through wavelet transform. Multivariate regression indicated a modest influence on soil radon from environmental parameters (R2 = 0.31). When using 100-days time windows, the R2 values showed wide variations in time, reaching their maxima (~0.63-0.66) during summer. Cross-correlation analysis over 100-days moving averages showed that, similar to multivariate linear regression analysis, the summer period is characterised by the best correlation between radon data and environmental parameters. Lastly, the wavelet coherence analysis allowed a multi-resolution coherence analysis of the time series acquired. This approach allows to study the relations among different signals either in time or frequency domain. It confirmed the results of the previous methods, but also allowed to recognize correlations between radon and environmental parameters at different observation scales (e.g., radon activity changed during strong precipitations, but also during anomalous variations of soil temperature uncorrelated with seasonal fluctuations). Our work suggests that in order to make an accurate analysis of the relations among distinct signals it is necessary to use different techniques that give complementary analytical information. In particular, the wavelet analysis showed to be very effective in discriminating radon changes due to environmental influences

Recalibrated mariner 10 color mosaics: Implications for mercurian volcanism

USGS Publications Warehouse

Robinson, M.S.; Lucey, P.G.

1997-01-01

Recalibration of Mariner 10 color image data allows the identification of distinct color units on the mercurian surface. We analyze these data in terms of opaque mineral abundance, iron content, and soil maturity and find color units consistent with the presence of volcanic deposits on Mercury's surface. Additionally, materials associated with some impact craters have been excavated from a layer interpreted to be deficient in opaque minerals within the crust, possibly analogous to the lunar anorthosite crust. These observations suggest that Mercury has undergone complex differentiation like the other terrestrial planets and the Earth's moon.

Effect of strain rate on bake hardening response of BH220 steel

NASA Astrophysics Data System (ADS)

Das, Anindya; Tarafder, Soumitro; Sivaprasad, S.; Chakrabarti, Debalay

2015-09-01

This study aims at understanding the bake hardening ability of ultra low carbon BH220 steel at different strain rates. The as-received material has been pre-strained to four different levels and then deformed in tension under (a) as pre-strained state and (b) after baking at 170 ∘C for 20 minutes, at three different strain rates of 0.001, 0.1 and 100/s. In both the conditions, yield stress increased with pre-strain and strain rate, but bake hardening ability was found to decrease when strain rate was increased. The strain rate sensitivity of the material was also found to decrease with bake hardening. Generation of dislocation forests and their subsequent immobility during baking treatment enables them to act as long range obstacles during further deformation. At higher strain rates, less amount of dislocations are produced which can interact with themselves and produce hardening, because of which bake hardening ability and the strain rate drops. A dislocation based strengthening model, as proposed by Larour et al. 2011 [7], was used to predict the yield stress values obtained at different conditions. The equation produced excellent co-relation with the experimental data.

Cognitive work hardening: a return-to-work intervention for people with depression.

PubMed

Wisenthal, Adeena; Krupa, Terry

2013-01-01

Mental health claims in the workplace are rising, particularly those due to depression. Associated with this is an increase in disability costs for the employer and the disability insurer, but even more important is the human suffering that results. While treatments are available for the depression there is a gap in interventions that specifically target return-to-work preparation. This paper presents cognitive work hardening, a treatment intervention that can bridge this gap by addressing the unique functional issues inherent in depression with a view to increasing return-to-work success. Cognitive work hardening applies the proven principles of classical work hardening (which has typically been applied to people with physical injuries) to the mental health domain. This paper explains how the occupational therapy principle of occupation and the core competency, enablement, are utilized and applied in cognitive work hardening. Key skills of the occupational therapist are also discussed. In addition, the paper considers the relationship of cognitive work hardening to recovery and mental illness, and the role it plays among workplace-based return-to-work interventions in the current movement toward non-clinical return-to-work interventions.

Effect of Plate Hardening Behavior on the Deformation of Stainless Steel Metal Bellows

NASA Astrophysics Data System (ADS)

Hao, Zengliang; Luo, Shuyi; Zhao, He; Zhang, Chunxiang; Luo, Junting

2017-11-01

Tensile tests of original plate samples from three types of stainless steel metal bellows were performed at room temperature. The constitutive equations for the three hardening curves were obtained and fitted. The analysis results of the microstructure and fracture morphology of the tensile specimens show that the grain size of the plate with a high logarithmic-exponential hardening rate is uneven and the dimple of the shear fracture is elongated into an ellipse. By contrast, the grain size of the plate with a relatively low linear hardening rate is even and the dimple of the fracture is uniformly equiaxial. Finite element simulations of the hydraulic bulging and repeated limit bending deformation of the metal bellows of the three types of materials were also conducted. The repeated limit bending deformation process was tested experimentally. Although the effect of the hardening exponent on the residual stress of the metal bellows after hydraulic bulging is minimal, this exponent considerably influences the repeated limit bending deformation of the metal bellows after subsequent use. The trough hardening phenomenon is serious in the repeated limit bending process. Moreover, when the hardening exponent of the original plate is high, the resistance to bending fracture at the trough area is poor.

Two Back Stress Hardening Models in Rate Independent Rigid Plastic Deformation

NASA Astrophysics Data System (ADS)

Yun, Su-Jin

In the present work, the constitutive relations based on the combination of two back stresses are developed using the Armstrong-Frederick, Phillips and Ziegler’s type hardening rules. Various evolutions of the kinematic hardening parameter can be obtained by means of a simple combination of back stress rate using the rule of mixtures. Thus, a wide range of plastic deformation behavior can be depicted depending on the dominant back stress evolution. The ultimate back stress is also determined for the present combined kinematic hardening models. Since a kinematic hardening rule is assumed in the finite deformation regime, the stress rate is co-rotated with respect to the spin of substructure obtained by incorporating the plastic spin concept. A comparison of the various co-rotational rates is also included. Assuming rigid plasticity, the continuum body consists of the elastic deformation zone and the plastic deformation zone to form a hybrid finite element formulation. Then, the plastic deformation behavior is investigated under various loading conditions with an assumption of the J2 deformation theory. The plastic deformation localization turns out to be strongly dependent on the description of back stress evolution and its associated hardening parameters. The analysis for the shear deformation with fixed boundaries is carried out to examine the deformation localization behavior and the evolution of state variables.

Along-strike supply of volcanic rifted margins: Implications for plume-influenced rifting and sudden along-strike transitions between volcanic and non-volcanic rifted margins

NASA Astrophysics Data System (ADS)

Ranero, C. R.; Phipps Morgan, J.

2006-12-01

The existence of sudden along-strike transitions between volcanic and non-volcanic rifted margins is an important constraint for conceptual models of rifting and continental breakup. We think there is a promising indirect approach to infer the maximum width of the region of upwelling that exists beneath a rifted margin during the transition from rifting to seafloor-spreading. We infer this width of ~30km from the minimum length of the ridge-offsets that mark the limits of the `region of influence' of on-ridge plumes on the axial relief, axial morphology, and crustal thickness along the ridge and at the terminations of fossil volcanic rifted margins. We adopt Vogt's [1972] hypothesis for along-ridge asthenospheric flow in a narrow vertical slot beneath the axis of plume-influenced `macro-segments' and volcanic rifted margins. We find that: (1) There is a threshold distance to the lateral offsets that bound plume-influenced macrosegments; all such `barrier offsets' are greater than ~30km, while smaller offsets do not appear to be a barrier to along-axis flow. This pattern is seen in the often abrupt transitions between volcanic and non-volcanic rifted margins; these transitions coincide with >30km ridge offsets that mark the boundary between the smooth seafloor morphology and thick crust of a plume- influenced volcanic margin and a neighboring non-volcanic margin, as recorded in 180Ma rifting of the early N. Atlantic, the 42Ma rifting of the Kerguelen-Broken Ridge, and the 66Ma Seychelles-Indian rifting in the Indian Ocean. (2) A similar pattern is seen in the often abrupt transitions between `normal' and plume-influenced mid- ocean ridge segments, which is discussed in a companion presentation by Phipps Morgan and Ranero (this meeting). (3) The coexistance of adjacent volcanic and non-volcanic rifted margin segments is readily explained in this conceptual framework. If the volcanic margin macrosegment is plume-fed by hot asthenosphere along an axial ridge slot

The response of mulberry trees after seedling hardening to summer drought in the hydro-fluctuation belt of Three Gorges Reservoir Areas.

PubMed

Huang, Xiaohui; Liu, Yun; Li, Jiaxing; Xiong, Xingzheng; Chen, Yang; Yin, Xiaohua; Feng, Dalan

2013-10-01

Interest has developed in the potential of mulberry (Morus alba), a woody perennial, for revegetating the hydro-fluctuation belt of the Three Gorges Reservoir due to its resistance to water-logging stress. To be useful, the trees must also be able to withstand dry conditions in summer when temperatures can be very high and droughts become severe quickly. Here, we report a study in which mulberry seedlings were grown in a greenhouse under a variety of simulated soil water conditions reflecting potential summer scenarios in the hydro-fluctuation belt of the Three Gorges Reservoir Area. We compared the responses of two pretreatment groups of mulberry seedlings to different levels of drought stress. The pretreatment groups differed with respect to drought hardening: the daily-managed (DM) group had relative soil moisture held constant in the range 70-80 %, while the drought-hardened (DH) group had relative soil moisture held constant at 40-50 %. Following the month-long pretreatment of seedlings, the two groups of young trees (DM and DH) were then respectively subjected to three levels of drought stress for a month: normal watering, moderate drought stress, and severe drought stress. A series of measurements comparing the physiological status of the plants in the two groups were then made, and the following results were obtained: (1) As drought stress increased, the heights, base diameters, root surface areas, photosynthetic rates (Pn), stomatal conductances (Gs), and transpiration rates (Tr) of the mulberry trees in both groups (DM and DH) decreased significantly, while the specific root area and abscisic acid (ABA) contents had increasing trends. Root activity and instantaneous water use efficiency of mulberry trees in both groups (DM and DH) were all raised under drought stress conditions than under normal watering, but the root/shoot ratio and leaf water potential were lowered. (2) At the same level of soil water content, the heights, base diameters, root

Method for increasing the rate of compressive strength gain in hardenable mixtures containing fly ash

DOEpatents

Liskowitz, J.W.; Wecharatana, M.; Jaturapitakkul, C.; Cerkanowicz, A.E.

1997-10-28

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention provides a method for increasing the rate of strength gain of a hardenable mixture containing fly ash by exposing the fly ash to an aqueous slurry of calcium oxide (lime) prior to its incorporation into the hardenable mixture. The invention further relates to such hardenable mixtures, e.g., concrete and mortar, that contain fly ash pre-reacted with calcium oxide. In particular, the fly ash is added to a slurry of calcium oxide in water, prior to incorporating the fly ash in a hardenable mixture. The hardenable mixture may be concrete or mortar. In a specific embodiment, mortar containing fly ash treated by exposure to an aqueous lime slurry are prepared and tested for compressive strength at early time points. 2 figs.

Middle Pleistocene volcanic activity dated by red thermoluminescence (RTL) - a case study from Lanzarote (Canary Islands)

NASA Astrophysics Data System (ADS)

von Suchodoletz, H.; Blanchard, H.; Rittner, S.; Radtke, U.; Fuchs, M.; Dietze, M.; Zöller, L.

2009-04-01

On Lanzarote (Canary Islands) soils were baked by Quaternary lava flows. This offers the possibility to date phases of eruptive activity by red thermoluminescence (RTL). We dated soil material baked by two different lava flows originating from the "Las Calderetas de Guatiza" volcanic chain in the northeast of the island by RTL. Furthermore, three samples of Helicidae-mollusk shells overlying one of the lava flows (site Mála) were dated using electron spin resonance (ESR). RTL datings were carried out using quartz grains 63-200 µm from baked material that were originally brought by eolian transport from the nearby Saharan desert. It appears that in spite of a baking temperature < 550°C the RTL-signal was sufficiently annealed and thus dating by RTL was possible. RTL ages of ca. 170 ka show good agreement with each other, however, ESR ages are up to 40 % higher than the corresponding RTL age of the lava flow in Mála. Despite this disagreement these results demonstrate that eruptive activity of the volcanic chain occurred during the Middle Pleistocene rather than during the Early Holocene/Late Pleistocene as supposed based on geomorphologic features. Furthermore, they show that 14C-ages of mollusk shells originating from Mála are underestimating volcanic activity up to a factor of 10, a problem often recorded in arid areas. These results demonstrate the value of luminescence and ESR datings on the semi arid Eastern Canary Islands. The successful dating of lava-baked soils on Lanzarote by RTL thus offers the possibility to further investigate the yet fragmentary Middle and Late Quaternary eruptive history of these islands.

Volcanic Alert System (VAS) developed during the (2011-2013) El Hierro (Canary Islands) volcanic process

NASA Astrophysics Data System (ADS)

Ortiz, Ramon; Berrocoso, Manuel; Marrero, Jose Manuel; Fernandez-Ros, Alberto; Prates, Gonçalo; De la Cruz-Reyna, Servando; Garcia, Alicia

2014-05-01

In volcanic areas with long repose periods (as El Hierro), recently installed monitoring networks offer no instrumental record of past eruptions nor experience in handling a volcanic crisis. Both conditions, uncertainty and inexperience, contribute to make the communication of hazard more difficult. In fact, in the initial phases of the unrest at El Hierro, the perception of volcanic risk was somewhat distorted, as even relatively low volcanic hazards caused a high political impact. The need of a Volcanic Alert System became then evident. In general, the Volcanic Alert System is comprised of the monitoring network, the software tools for the analysis of the observables, the management of the Volcanic Activity Level, and the assessment of the threat. The Volcanic Alert System presented here places special emphasis on phenomena associated to moderate eruptions, as well as on volcano-tectonic earthquakes and landslides, which in some cases, as in El Hierro, may be more destructive than an eruption itself. As part of the Volcanic Alert System, we introduce here the Volcanic Activity Level which continuously applies a routine analysis of monitoring data (particularly seismic and deformation data) to detect data trend changes or monitoring network failures. The data trend changes are quantified according to the Failure Forecast Method (FFM). When data changes and/or malfunctions are detected, by an automated watchdog, warnings are automatically issued to the Monitoring Scientific Team. Changes in the data patterns are then translated by the Monitoring Scientific Team into a simple Volcanic Activity Level, that is easy to use and understand by the scientists and technicians in charge for the technical management of the unrest. The main feature of the Volcanic Activity Level is its objectivity, as it does not depend on expert opinions, which are left to the Scientific Committee, and its capabilities for early detection of precursors. As a consequence of the El Hierro

Volcanic hazards to airports

USGS Publications Warehouse

Guffanti, M.; Mayberry, G.C.; Casadevall, T.J.; Wunderman, R.

2009-01-01

Volcanic activity has caused significant hazards to numerous airports worldwide, with local to far-ranging effects on travelers and commerce. Analysis of a new compilation of incidents of airports impacted by volcanic activity from 1944 through 2006 reveals that, at a minimum, 101 airports in 28 countries were affected on 171 occasions by eruptions at 46 volcanoes. Since 1980, five airports per year on average have been affected by volcanic activity, which indicates that volcanic hazards to airports are not rare on a worldwide basis. The main hazard to airports is ashfall, with accumulations of only a few millimeters sufficient to force temporary closures of some airports. A substantial portion of incidents has been caused by ash in airspace in the vicinity of airports, without accumulation of ash on the ground. On a few occasions, airports have been impacted by hazards other than ash (pyroclastic flow, lava flow, gas emission, and phreatic explosion). Several airports have been affected repeatedly by volcanic hazards. Four airports have been affected the most often and likely will continue to be among the most vulnerable owing to continued nearby volcanic activity: Fontanarossa International Airport in Catania, Italy; Ted Stevens Anchorage International Airport in Alaska, USA; Mariscal Sucre International Airport in Quito, Ecuador; and Tokua Airport in Kokopo, Papua New Guinea. The USA has the most airports affected by volcanic activity (17) on the most occasions (33) and hosts the second highest number of volcanoes that have caused the disruptions (5, after Indonesia with 7). One-fifth of the affected airports are within 30 km of the source volcanoes, approximately half are located within 150 km of the source volcanoes, and about three-quarters are within 300 km; nearly one-fifth are located more than 500 km away from the source volcanoes. The volcanoes that have caused the most impacts are Soufriere Hills on the island of Montserrat in the British West Indies

Radiation-hardened transistor and integrated circuit

DOEpatents

Ma, Kwok K.

2007-11-20

A composite transistor is disclosed for use in radiation hardening a CMOS IC formed on an SOI or bulk semiconductor substrate. The composite transistor has a circuit transistor and a blocking transistor connected in series with a common gate connection. A body terminal of the blocking transistor is connected only to a source terminal thereof, and to no other connection point. The blocking transistor acts to prevent a single-event transient (SET) occurring in the circuit transistor from being coupled outside the composite transistor. Similarly, when a SET occurs in the blocking transistor, the circuit transistor prevents the SET from being coupled outside the composite transistor. N-type and P-type composite transistors can be used for each and every transistor in the CMOS IC to radiation harden the IC, and can be used to form inverters and transmission gates which are the building blocks of CMOS ICs.

The Online GVP/USGS Weekly Volcanic Activity Report: Providing Timely Information About Worldwide Volcanism

NASA Astrophysics Data System (ADS)

Mayberry, G. C.; Guffanti, M. C.; Luhr, J. F.; Venzke, E. A.; Wunderman, R. L.

2001-12-01

The awesome power and intricate inner workings of volcanoes have made them a popular subject with scientists and the general public alike. About 1500 known volcanoes have been active on Earth during the Holocene, approximately 50 of which erupt per year. With so much activity occurring around the world, often in remote locations, it can be difficult to find up-to-date information about current volcanism from a reliable source. To satisfy the desire for timely volcano-related information the Smithsonian Institution and US Geological Survey combined their strengths to create the Weekly Volcanic Activity Report. The Smithsonian's Global Volcanism Program (GVP) has developed a network of correspondents while reporting worldwide volcanism for over 30 years in their monthly Bulletin of the Global Volcanism Network. The US Geological Survey's Volcano Hazards Program studies and monitors volcanoes in the United States and responds (upon invitation) to selected volcanic crises in other countries. The Weekly Volcanic Activity Report is one of the most popular sites on both organization's websites. The core of the Weekly Volcanic Activity Report is the brief summaries of current volcanic activity around the world. In addition to discussing various types of volcanism, the summaries also describe precursory activity (e.g. volcanic seismicity, deformation, and gas emissions), secondary activity (e.g. debris flows, mass wasting, and rockfalls), volcanic ash hazards to aviation, and preventative measures. The summaries are supplemented by links to definitions of technical terms found in the USGS photoglossary of volcano terms, links to information sources, and background information about reported volcanoes. The site also includes maps that highlight the location of reported volcanoes, an archive of weekly reports sorted by volcano and date, and links to commonly used acronyms. Since the Weekly Volcanic Activity Report's inception in November 2000, activity has been reported at

Predicting forest dieback in Maine, USA: a simple model based on soil frost and drought

Treesearch

Allan N.D. Auclair; Warren E. Heilman; Blondel Brinkman

2010-01-01

Tree roots of northern hardwoods are shallow rooted, winter active, and minimally frost hardened; dieback is a winter freezing injury to roots incited by frost penetration in the absence of adequate snow cover and exacerbated by drought in summer. High soil water content greatly increases conductivity of frost. We develop a model based on the sum of z-scores of soil...

Major and trace elements in Boletus aereus and Clitopilus prunulus growing on volcanic and sedimentary soils of Sicily (Italy).

PubMed

Alaimo, M G; Dongarrà, G; La Rosa, A; Tamburo, E; Vasquez, G; Varrica, D

2018-08-15

The aim of this study was to determine and compare the content of 28 elements (Ag, Al, As, Ba, Be, Bi, Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, Pb, Rb, Sb, Se, Sr, Tl, U, V and Zn) in fruiting bodies of Boletus aereus Bull. and Clitopilus prunulus P. Kumm collected from eleven unpolluted sites of Sicily (Italy) and, also to relate the abundance of chemical elements in soil with their concentration in mushrooms. Median concentrations of the most abundant elements in Boletus aereus ranged from 31,290 μg/g (K) to 107 μg/g (Zn) in caps and from 24,009 μg/g (K) to 57 μg/g (Zn) in stalks with the following abundance order: K > Na > Ca > Mg > Fe > Al > Rb > Zn. The same elements, in the whole fruiting body of Clitopilus prunulus samples, varied in the range 54,073-92 μg/g following the abundance order: K > Na > Mg > Ca > Fe > Al > Rb > Zn. Metal contents in Boletus aereus and in the whole fruiting body of Clitopilus prunulus, collected from the same sampling sites, showed statistically significant differences for most elements. In particular, Clitopilus prunulus contained around two to four times more Co, Cr, Fe, Mg, Mo, Pb, U and V than caps and stalks of Boletus aereus species which, in turn, was from two to four times more enriched in Cu, Se and Tl. Thus, the elemental content of Boletus aereus and Clitopilus prunulus appeared to be species-dependent. The distribution of chemical elements in Boletus aereus was not uniform throughout the whole fruiting body as most elements were significantly bioconcentrated in caps. Furthermore, the fruit bodies of Boletus aereus from the volcanic soil differed both in major and minor elements concentrations from those collected from sedimentary soils. Cadmium and lead concentrations were below the threshold limits for wild mushrooms proposed by EU Directives (2008 and 2015). The elemental content was not significantly influenced by soil pH. Copyright © 2018 Elsevier Inc. All rights reserved.

Options for Hardening FinFETS with Flowable Oxide Between Fins

DTIC Science & Technology

2017-03-01

thus hardening by process is needed. Using the methodology of CV measurements on inexpensive experimental blanket oxides we have determined options...NY 10598 Abstract: A methodology using radiation-induced charge measurements by CV techniques on blanket oxides is shown to aid in the choice...of process options for hardening FinFETs. Net positive charge in flowable oxides was reduced by 50 % using a simple non -intrusive process change

Impact of Scaled Technology on Radiation Testing and Hardening

NASA Technical Reports Server (NTRS)

LaBel, Kenneth A.; Cohn, Lewis M.

2005-01-01

This presentation gives a brief overview of some of the radiation challenges facing emerging scaled digital technologies with implications on using consumer grade electronics and next generation hardening schemes. Commercial semiconductor manufacturers are recognizing some of these issues as issues for terrestrial performance. Looking at means of dealing with soft errors. The thinned oxide has indicated improved TID tolerance of commercial products hardened by "serendipity" which does not guarantee hardness or say if the trend will continue. This presentation also focuses one reliability implications of thinned oxides.

The Effects of Stress State on the Strain Hardening Behaviors of TWIP Steel

NASA Astrophysics Data System (ADS)

Liu, F.; Dan, W. J.; Zhang, W. G.

2017-05-01

Twinning-Induced Plasticity (TWIP) steels have received great attention due to their excellent mechanical properties as a result of austenite twinning during straining. In this paper, the effects of stress state on the strain hardening behaviors of Fe-20Mn-1.2C TWIP steel were studied. A twinning model considering stress state was presented based on the shear-band framework, and a strain hardening model was proposed by taking dislocation mixture evolution into account. The models were verified by the experimental results of uniaxial tension, simple shear and rolling processes. The strain hardening behaviors of TWIP steel under different stress states were predicted. The results show that the stress state can improve the austenite twining and benefit the strain hardening of TWIP steel.

Comparison of linear and square superposition hardening models for the surface nanoindentation of ion-irradiated materials

NASA Astrophysics Data System (ADS)

Xiao, Xiazi; Yu, Long

2018-05-01

Linear and square superposition hardening models are compared for the surface nanoindentation of ion-irradiated materials. Hardening mechanisms of both dislocations and defects within the plasticity affected region (PAR) are considered. Four sets of experimental data for ion-irradiated materials are adopted to compare with theoretical results of the two hardening models. It is indicated that both models describe experimental data equally well when the PAR is within the irradiated layer; whereas, when the PAR is beyond the irradiated region, the square superposition hardening model performs better. Therefore, the square superposition model is recommended to characterize the hardening behavior of ion-irradiated materials.

The surface fatigue life of contour induction hardened AISI 1552 gears

NASA Astrophysics Data System (ADS)

Townsend, Dennis P.; Turza, Alan; Chaplin, Mike

1995-07-01

Two groups of spur gears manufactured from two different materials and heat treatments were endurance tested for surface fatigue life. One group was manufactured from AISI 1552 and was finished ground to a 0.4 micron (16 micro-in.) rms surface finish and then dual frequency contour induction hardened. The second group was manufactured from CEVM AISI 9310 and was carburized, hardened, and ground to a 0.4 micron (16 micro-in.) rms surface finish. The gear pitch diameter was 8.89 cm (3.5 in.). Test conditions were a maximum Hertz stress of 1.71 GPa (248 ksi), a bulk gear temperature of approximately 350 K (170 F) and a speed of 10,000 rpm. The lubricant used for the tests was a synthetic paraffinic oil with an additive package. The test results showed that the 10 percent surface fatigue (pitting) life of the contour hardened AISI 1552 test gears was 1.7 times that of the carburized and hardened AISI 9310 test gears. Also there were two early failures of the AISI 1552 gears by bending fatigue.

The Surface Fatigue Life of Contour Induction Hardened AISI 1552 Gears

NASA Technical Reports Server (NTRS)

Townsend, Dennis P.; Turza, Alan; Chaplin, Mike

1995-01-01

Two groups of spur gears manufactured from two different materials and heat treatments were endurance tested for surface fatigue life. One group was manufactured from AISI 1552 and was finished ground to a 0.4 micron (16 micro-in.) rms surface finish and then dual frequency contour induction hardened. The second group was manufactured from CEVM AISI 9310 and was carburized, hardened, and ground to a 0.4 micron (16 micro-in.) rms surface finish. The gear pitch diameter was 8.89 cm (3.5 in.). Test conditions were a maximum Hertz stress of 1.71 GPa (248 ksi), a bulk gear temperature of approximately 350 K (170 F) and a speed of 10,000 rpm. The lubricant used for the tests was a synthetic paraffinic oil with an additive package. The test results showed that the 10 percent surface fatigue (pitting) life of the contour hardened AISI 1552 test gears was 1.7 times that of the carburized and hardened AISI 9310 test gears. Also there were two early failures of the AISI 1552 gears by bending fatigue.

Investigation of radiation hardened SOI wafer fabricated by ion-cut technique

NASA Astrophysics Data System (ADS)

Chang, Yongwei; Wei, Xing; Zhu, Lei; Su, Xin; Gao, Nan; Dong, Yemin

2018-07-01

Total ionizing dose (TID) effect on Silicon-on-Insulator (SOI) wafers due to inherent buried oxide (BOX) is a significant concern as it leads to the degradation of electrical properties of SOI-based devices and circuits, even failures of the systems associated with them. This paper reports the radiation hardening implementation of SOI wafer fabricated by ion-cut technique integrated with low-energy Si+ implantation. The electrical properties and radiation response of pseudo-MOS transistors are analyzed. The results demonstrate that the hardening process can significantly improve the TID tolerance of SOI wafers by generating Si nanocrystals (Si-NCs) within the BOX. The presence of Si-NCs created through Si+ implantation is evidenced by high-resolution transmission electron microscopy (HR-TEM). Under the pass gate (PG) irradiation bias, the anti-radiation properties of H-gate SOI nMOSFETs suggest that the radiation hardened SOI wafers with optimized Si implantation dose can perform effectively in a radiation environment. The radiation hardening process provides an excellent way to reinforce the TID tolerance of SOI wafers.

Safe emergency department removal of a hardened steel penile constriction ring.

PubMed

Peay, Jeremy; Smithson, James; Nelson, James; Witucki, Peter

2009-10-01

Penile constriction devices are used for the enhancement of sexual performance. These devices have the potential to become incarcerated, leading to necrosis and amputation if not removed promptly. This article presents a step-by-step approach for the safe removal of a hardened steel penile constriction device using somewhat unorthodox tools found in a hospital. We present a case of an incarcerated hardened steel penile constriction ring that was not able to be removed with conventional techniques. We describe a novel technique using an electric grinder and laryngoscope blade. The technique described in this article is a valuable and relatively safe technique for the Emergency Physician to facilitate the timely removal of a hardened steel constriction device.

Method and apparatus for welding precipitation hardenable materials

DOEpatents

Murray, Jr., Holt; Harris, Ian D.; Ratka, John O.; Spiegelberg, William D.

1994-01-01

A method for welding together members consisting of precipitation age hardened materials includes the steps of selecting a weld filler material that has substantially the same composition as the materials being joined, and an age hardening characteristic temperature age threshold below that of the aging kinetic temperature range of the materials being joined, whereby after welding the members together, the resulting weld and heat affected zone (HAZ) are heat treated at a temperature below that of the kinetic temperature range of the materials joined, for obtaining substantially the same mechanical characteristics for the weld and HAZ, as for the parent material of the members joined.

Method and apparatus for welding precipitation hardenable materials

DOEpatents

Murray, H. Jr.; Harris, I.D.; Ratka, J.O.; Spiegelberg, W.D.

1994-06-28

A method for welding together members consisting of precipitation age hardened materials includes the steps of selecting a weld filler material that has substantially the same composition as the materials being joined, and an age hardening characteristic temperature age threshold below that of the aging kinetic temperature range of the materials being joined, whereby after welding the members together, the resulting weld and heat affected zone (HAZ) are heat treated at a temperature below that of the kinetic temperature range of the materials joined, for obtaining substantially the same mechanical characteristics for the weld and HAZ, as for the parent material of the members joined. 5 figures.

Process for hardening the surface of polymers

DOEpatents

Mansur, Louis K.; Lee, Eal H.

1992-01-01

Hard surfaced polymers and the method for making them is generally described. Polymers are subjected to simultaneous multiple ion beam bombardment, that results in a hardening of the surface and improved wear resistance.

Modeling volcanic ash dispersal

ScienceCinema

Macedonio, Giovanni

2018-05-22

Explosive volcanic eruptions inject into the atmosphere large amounts of volcanic material (ash, blocks and lapilli). Blocks and larger lapilli follow ballistic and non-ballistic trajectories and fall rapidly close to the volcano. In contrast, very fine ashes can remain entrapped in the atmosphere for months to years, and may affect the global climate in the case of large eruptions. Particles having sizes between these two end-members remain airborne from hours to days and can cover wide areas downwind. Such volcanic fallout entails a serious threat to aircraft safety and can create many undesirable effects to the communities located around the volcano. The assessment of volcanic fallout hazard is an important scientific, economic, and political issue, especially in densely populated areas. From a scientific point of view, considerable progress has been made during the last two decades through the use of increasingly powerful computational models and capabilities. Nowadays, models are used to quantify hazard scenarios and/or to give short-term forecasts during emergency situations. This talk will be focused on the main aspects related to modeling volcanic ash dispersal and fallout with application to the well known problem created by the Eyjafjöll volcano in Iceland. Moreover, a short description of the main volcanic monitoring techniques is presented.

Orchardgrass responses to fertilization of seven surface soils from the central Blue Mountains of Oregon.

Treesearch

Jon M. Geist

1971-01-01

Growth responses to application of all combinations of N, P, and S on four forest and three grassland soils showed that a significant N-S interaction existed for all seven soils. For two grassland soils, a significant response to phosphorus was obtained in combination with nitrogen and sulfur. The volcanic-ash-derived soils and the Klicker soil had the highest...

Secondary hardening steel having improved combination of hardness and toughness

DOEpatents

Parker, Earl R.; Zackay, Victor F.; Bhat, Manjeshwar S.; Garrison, Jr., Warren M.

1979-01-01

A secondary hardening alloy steel composition consisting essentially of about 0.25-0.5% carbon, about 0.5-1.0% manganese, about 1.5-3.0% nickel, about 0-1.0% chromium, about 1.75-2.5% molybdenum, about 0-0.4% vanadium, and an additive selected from about 1-3% aluminum and a combination of at least about 1% aluminum and at least about 1% silicon for a combined Al+Si content of about 2-4%, the balance being iron and impurity elements. The present steel composition has the following characteristics: it exhibits a flat tempering response, it is hardenable upon tempering to a Rockwell C hardness of at least 50, and it has an improved combination of hardness vs. toughness properties after tempering in the secondary hardening range. A method of preparation is also described.

On the Spectral Hardening at gsim300 keV in Solar Flares

NASA Astrophysics Data System (ADS)

Li, G.; Kong, X.; Zank, G.; Chen, Y.

2013-05-01

It has long been noted that the spectra of observed continuum emissions in many solar flares are consistent with double power laws with a hardening at energies gsim300 keV. It is now widely believed that at least in electron-dominated events, the hardening in the photon spectrum reflects an intrinsic hardening in the source electron spectrum. In this paper, we point out that a power-law spectrum of electrons with a hardening at high energies can be explained by the diffusive shock acceleration of electrons at a termination shock with a finite width. Our suggestion is based on an early analytical work by Drury et al., where the steady-state transport equation at a shock with a tanh profile was solved for a p-independent diffusion coefficient. Numerical simulations with a p-dependent diffusion coefficient show hardenings in the accelerated electron spectrum that are comparable with observations. One necessary condition for our proposed scenario to work is that high-energy electrons resonate with the inertial range of the MHD turbulence and low-energy electrons resonate with the dissipation range of the MHD turbulence at the acceleration site, and the spectrum of the dissipation range ~k -2.7. A ~k -2.7 dissipation range spectrum is consistent with recent solar wind observations.

Cenozoic volcanic rocks of Saudi Arabia

USGS Publications Warehouse

Coleman, R.G.; Gregory, R.T.; Brown, G.F.

2016-01-01

The historical record of volcanic activity in Saudi Arabia suggests that volcanism is dormant. The harrats should be evaluated for their potential as volcanic hazards and as sources of geothermal energy. The volcanic rocks are natural traps for groundwater; thus water resources for agriculture may be significant and should be investigated.

Radiation Hardened 10BASE-T Ethernet Physical Layer (PHY)

NASA Technical Reports Server (NTRS)

Lin, Michael R. (Inventor); Petrick, David J. (Inventor); Ballou, Kevin M. (Inventor); Espinosa, Daniel C. (Inventor); James, Edward F. (Inventor); Kliesner, Matthew A. (Inventor)

2017-01-01

Embodiments may provide a radiation hardened 10BASE-T Ethernet interface circuit suitable for space flight and in compliance with the IEEE 802.3 standard for Ethernet. The various embodiments may provide a 10BASE-T Ethernet interface circuit, comprising a field programmable gate array (FPGA), a transmitter circuit connected to the FPGA, a receiver circuit connected to the FPGA, and a transformer connected to the transmitter circuit and the receiver circuit. In the various embodiments, the FPGA, transmitter circuit, receiver circuit, and transformer may be radiation hardened.

Ca, Sr and Ba stable isotopes reveal the fate of soil nutrients along a tropical climosequence

USGS Publications Warehouse

Bullen, Thomas D.; Chadwick, Oliver A.

2016-01-01

Nutrient biolifting is an important pedogenic process in which plant roots obtain inorganic nutrients such as phosphorus (P) and calcium (Ca) from minerals at depth and concentrate those nutrients at the surface. Here we use soil chemistry and stable isotopes of the alkaline earth elements Ca, strontium (Sr) and barium (Ba) to test the hypothesis that biolifting of P has been an important pedogenic process across a soil climosequence developed on volcanic deposits at Kohala Mountain, Hawaii. The geochemical linkage between these elements is revealed as generally positive site-specific relationships in soil mass gains and losses, particularly for P, Ba and Ca, using the ratio of immobile elements titanium and niobium (Ti/Nb) to link individual soil samples to a restricted compositional range of the chemically and isotopically diverse volcanic parent materials. At sites where P is enriched in surface soils relative to abundances in deeper soils, the isotope compositions of exchangeable Ca, Sr and Ba in the shallowest soil horizons (< 10 cm depth) are lighter than those of the volcanic parent materials and trend toward those of plants growing on fresh volcanic deposits. In contrast the isotope composition of exchangeable Ba in deeper soil horizons (> 10 cm depth) at those sites is consistently heavier than the volcanic parent materials. The isotope compositions of exchangeable Ca and Sr trend toward heavier compositions with depth more gradually, reflecting increasing leakiness from these soils in the order Ba < Sr < Ca and downward transfer of light biocycled Ca and Sr to deeper exchange sites. Given the long-term stability of ecosystem properties at the sites where P is enriched in surface soils, a simple box model demonstrates that persistence of isotopically light exchangeable Ca, Sr and Ba in the shallowest soil horizons requires that the uptake flux to plants from those near-surface layers is less than the recycling flux returned to the surface as

Classification problems of Mount Kenya soils

NASA Astrophysics Data System (ADS)

Mutuma, Evans; Csorba, Ádám; Wawire, Amos; Dobos, Endre; Michéli, Erika

2017-04-01

Soil sampling on the agricultural lands covering 1200 square kilometers in the Eastern part of Mount Kenya was carried out to assess the status of soil organic carbon (SOC) as a soil fertility indicator, and to create an up-to-date soil classification map. The geology of the area consists of volcanic rocks and recent superficial deposits. The volcanic rocks are related to the Pliocene time; mainly: lahars, phonolites, tuffs, basalt and ashes. A total of 28 open profiles and 49 augered profiles with 269 samples were collected. The samples were analyzed for total carbon, organic carbon, particle size distribution, percent bases, cation exchange capacity and pH among other parameters. The objective of the study was to evaluate the variability of SOC in different Reference Soil Groups (RGS) and to compare the determined classification units with the KENSOTER database. Soil classification was performed based on the World Reference Base (WRB) for Soil Resources 2014. Based on the earlier surveys, geological and environmental setting, Nitisols were expected to be the dominant soils of the sampled area. However, this was not the case. The major differences to earlier survey data (KENSOTER database) are the presence of high activity clays (CEC value range 27.6 cmol/kg - 70 cmol/kg), high silt content (range 32.6 % - 52.4 %) and silt/clay ratio (range of 0.6 - 1.4) keeping these soils out of the Nitisols RSG. There was good accordance in the morphological features with the earlier survey but failed the silt/clay ratio criteria for Nitisols. This observation calls attention to set new classification criteria for Nitisols and other soils of warm, humid regions with variable rate of weathering to avoid difficulties in interpretation. To address the classification problem, this paper further discusses the taxonomic relationships between the studied soils. On the contrary most of the diagnostic elements (like the presence Umbric horizon, Vitric and Andic properties) and the some

Process for hardening the surface of polymers

DOEpatents

Mansur, L.K.; Lee, E.H.

1992-07-14

Hard surfaced polymers and the method for making them is generally described. Polymers are subjected to simultaneous multiple ion beam bombardment, that results in a hardening of the surface and improved wear resistance. 1 figure.

Sorption kinetics of diuron on volcanic ash derived soils.

PubMed

Cáceres-Jensen, Lizethly; Rodríguez-Becerra, Jorge; Parra-Rivero, Joselyn; Escudey, Mauricio; Barrientos, Lorena; Castro-Castillo, Vicente

2013-10-15

Diuron sorption kinetic was studied in Andisols, Inceptisol and Ultisols soils in view of their distinctive physical and chemical properties: acidic pH and variable surface charge. Two types of kinetic models were used to fit the experimental dates: those that allow to establish principal kinetic parameters and modeling of sorption process (pseudo-first-order, pseudo-second-order), and some ones frequently used to describe solute transport mechanisms of organic compounds on different sorbents intended for remediation purposes (Elovich equation, intraparticle diffusion, Boyd, and two-site nonequilibrium models). The best fit was obtained with the pseudo-second-order model. The rate constant and the initial rate constant values obtained through this model demonstrated the behavior of Diuron in each soil, in Andisols were observed the highest values for both parameters. The application of the models to describe solute transport mechanisms allowed establishing that in all soils the mass transfer controls the sorption kinetic across the boundary layer and intraparticle diffusion into macropores and micropores. The slowest sorption rate was observed on Ultisols, behavior which must be taken into account when the leaching potential of Diuron is considered. Copyright © 2013 Elsevier B.V. All rights reserved.

An investigation of volcanic depressions. Part 4: Origin of Hole-in-the-ground, a maar in Central Oregon

NASA Technical Reports Server (NTRS)

Lorenz, V.

1971-01-01

Hole-in-the-Ground, a volcanic explosion crater, located in central Oregon is described. The morphology of the soil and rocks and the topography of the crater indicate the sequential happenings during the eruption. Geophysical measurements also indicate a domical intrusion below the crater floor, extending upward as a ring dike around the margins of the crater. The volume of ejecta was determined for four major eruptions. Varied analyses were made of the pyroclastic debris, rocks, cinders, and soil.

RHOBOT: Radiation hardened robotics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bennett, P.C.; Posey, L.D.

1997-10-01

A survey of robotic applications in radioactive environments has been conducted, and analysis of robotic system components and their response to the varying types and strengths of radiation has been completed. Two specific robotic systems for accident recovery and nuclear fuel movement have been analyzed in detail for radiation hardness. Finally, a general design approach for radiation-hardened robotics systems has been developed and is presented. This report completes this project which was funded under the Laboratory Directed Research and Development program.

Numerical analysis of drilling hole work-hardening effects in hole-drilling residual stress measurement

NASA Astrophysics Data System (ADS)

Li, H.; Liu, Y. H.

2008-11-01

The hole-drilling strain gage method is an effective semi-destructive technique for determining residual stresses in the component. As a mechanical technique, a work-hardening layer will be formed on the surface of the hole after drilling, and affect the strain relaxation. By increasing Young's modulus of the material near the hole, the work-hardening layer is simplified as a heterogeneous annulus. As an example, two finite rectangular plates submitted to different initial stresses are treated, and the relieved strains are measured by finite element simulation. The accuracy of the measurement is estimated by comparing the simulated residual stresses with the given initial ones. The results are shown for various hardness of work-hardening layer. The influence of the relative position of the gages compared with the thickness of the work-hardening layer, and the effect of the ratio of hole diameter to work-hardening layer thickness are analyzed as well.

Improving precipitation hardening behavior of Mg−Zn based alloys with Ce−Ca microalloying additions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Langelier, B., E-mail: langelb@mcmaster.ca

2016-10-15

The precipitation hardening behavior of newly developed Mg−Zn−Ca−Ce alloys, with modified texture and improved ductility, is studied to delineate the microstructural characteristics that lead to effective hardening upon ageing treatments. Advanced electron microscopy and atom probe techniques are used to analyze the structural characteristics in relevance to the hardening potential. It has been found that the formation of a new basal precipitate phase, which evolves from a single atomic layer GP zone, and is finely distributed in both under-aged and peak-aged microstructures, has a significant impact in the improvement of the hardening response compared with the base Mg−Zn alloys. Itmore » has also been found that the β′{sub 1} rod precipitates, commonly formed during ageing treatments of Mg−Zn alloys, have their size and distribution significantly refined in the Ca−Ce containing alloys. The role of alloy chemistry in the formation of the fine basal plate GP zones and the refinement in β′{sub 1} precipitation and their relationships to the hardening behavior are discussed. It is proposed that Ca microalloying governs the formation of the GP zones and the enhancement of hardening, particularly in the under-aged conditions, but that this is aided by a beneficial effect from Ce. - Highlights: • Ce−Ca microalloying additions improve hardening in Mg−Zn, over Ce or Ca alone. • Improved hardening is due to refined β′{sub 1} rods, and fine basal plate precipitates. • Atom probe tomography identifies Ca in both β′{sub 1} and the fine basal plates. • The fine basal plates originate as ordered monolayer GP zones with 1:1 Zn:Ca (at.%). • With ageing GP zones become more Zn-rich and transform to the fine basal plates.« less

Steep spatial gradients of volcanic and marine sulfur in Hawaiian rainfall and ecosystems

USGS Publications Warehouse

Bern, Carleton R.; Chadwick, Oliver A.; Kendall, Carol; Pribil, Michael J.

2015-01-01

Sulfur, a nutrient required by terrestrial ecosystems, is likely to be regulated by atmospheric processes in well-drained, upland settings because of its low concentration in most bedrock and generally poor retention by inorganic reactions within soils. Environmental controls on sulfur sources in unpolluted ecosystems have seldom been investigated in detail, even though the possibility of sulfur limiting primary production is much greater where atmospheric deposition of anthropogenic sulfur is low. Here we measure sulfur isotopic compositions of soils, vegetation and bulk atmospheric deposition from the Hawaiian Islands for the purpose of tracing sources of ecosystem sulfur. Hawaiian lava has a mantle-derived sulfur isotopic composition (δ34S VCDT) of − 0.8‰. Bulk deposition on the island of Maui had a δ34S VCDT that varied temporally, spanned a range from + 8.2 to + 19.7‰, and reflected isotopic mixing from three sources: sea-salt (+ 21.1‰), marine biogenic emissions (+ 15.6‰), and volcanic emissions from active vents on Kilauea Volcano (+ 0.8‰). A straightforward, weathering-driven transition in ecosystem sulfur sources could be interpreted in the shift from relatively low (0.0 to + 2.7‰) to relatively high (+ 17.8 to + 19.3‰) soil δ34S values along a 0.3 to 4100 ka soil age-gradient, and similar patterns in associated vegetation. However, sub-kilometer scale spatial variation in soil sulfur isotopic composition was found along soil transects assumed by age and mass balance to be dominated by atmospheric sulfur inputs. Soil sulfur isotopic compositions ranged from + 8.1 to + 20.3‰ and generally decreased with increasing elevation (0–2000 m), distance from the coast (0–12 km), and annual rainfall (180–5000 mm). Such trends reflect the spatial variation in marine versus volcanic inputs from atmospheric deposition. Broadly, these results illustrate how the sources and magnitude of atmospheric deposition can exert controls

Modeling volcanic ash dispersal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Macedonio, Giovanni

2010-10-22

Explosive volcanic eruptions inject into the atmosphere large amounts of volcanic material (ash, blocks and lapilli). Blocks and larger lapilli follow ballistic and non-ballistic trajectories and fall rapidly close to the volcano. In contrast, very fine ashes can remain entrapped in the atmosphere for months to years, and may affect the global climate in the case of large eruptions. Particles having sizes between these two end-members remain airborne from hours to days and can cover wide areas downwind. Such volcanic fallout entails a serious threat to aircraft safety and can create many undesirable effects to the communities located around themore » volcano. The assessment of volcanic fallout hazard is an important scientific, economic, and political issue, especially in densely populated areas. From a scientific point of view, considerable progress has been made during the last two decades through the use of increasingly powerful computational models and capabilities. Nowadays, models are used to quantify hazard scenarios and/or to give short-term forecasts during emergency situations. This talk will be focused on the main aspects related to modeling volcanic ash dispersal and fallout with application to the well known problem created by the Eyjafjöll volcano in Iceland. Moreover, a short description of the main volcanic monitoring techniques is presented.« less

The Volcanism Ontology (VO): a model of the volcanic system

NASA Astrophysics Data System (ADS)

Myer, J.; Babaie, H. A.

2017-12-01

We have modeled a part of the complex material and process entities and properties of the volcanic system in the Volcanism Ontology (VO) applying several top-level ontologies such as Basic Formal Ontology (BFO), SWEET, and Ontology of Physics for Biology (OPB) within a single framework. The continuant concepts in BFO describe features with instances that persist as wholes through time and have qualities (attributes) that may change (e.g., state, composition, and location). In VO, the continuants include lava, volcanic rock, and volcano. The occurrent concepts in BFO include processes, their temporal boundaries, and the spatio-temporal regions within which they occur. In VO, these include eruption (process), the onset of pyroclastic flow (temporal boundary), and the space and time span of the crystallization of lava in a lava tube (spatio-temporal region). These processes can be of physical (e.g., debris flow, crystallization, injection), atmospheric (e.g., vapor emission, ash particles blocking solar radiation), hydrological (e.g., diffusion of water vapor, hot spring), thermal (e.g., cooling of lava) and other types. The properties (predicates) relate continuants to other continuants, occurrents to continuants, and occurrents to occurrents. The ontology also models other concepts such as laboratory and field procedures by volcanologists, sampling by sensors, and the type of instruments applied in monitoring volcanic activity. When deployed on the web, VO will be used to explicitly and formally annotate data and information collected by volcanologists based on domain knowledge. This will enable the integration of global volcanic data and improve the interoperability of software that deal with such data.

Effects of TEA·HCl hardening accelerator on the workability of cement-based materials

NASA Astrophysics Data System (ADS)

Pan, Wenhao; Ding, Zhaoyang; Chen, Yanwen

2017-03-01

The aim of the test is to research the influence rules of TEA·HCl on the workability of cement paste and concrete. Based on the features of the new hardening accelerator, an experimental analysis system were established through different dosages of hardening accelerator, and the feasibility of such accelerator to satisfy the need of practical engineering was verified. The results show that adding of the hardening accelerator can accelerate the cement hydration, and what’s more, when the dosage was 0.04%, the setting time was the shortest while the initial setting time and final setting time were 130 min and 180 min, respectively. The initial fluidity of cement paste of adding accelerator was roughly equivalent compared with that of blank. After 30 min, fluidity loss would decrease with the dosage increasing, but fluidity may increase. The application of the hardening accelerator can make the early workability of concrete enhance, especially the slump loss of 30 min can improve more significantly. The bleeding rate of concrete significantly decreases after adding TEA·HCl. The conclusion is that the new hardening accelerator can meet the need of the workability of cement-based materials in the optimum dosage range.

Volcanic processes in the solar system

USGS Publications Warehouse

Carr, M.H.

1987-01-01

Eruptions of ammonia, water, and sulfur. These have become some of the concerns of planetary volcanologists as they try to understand volcanic processes on other planetary bodies. As exploration of the Solar System has continues, we have been confronted with more and more exotic forms of volcanism and have come to realize that the types of volcanic activity observed on Earth represent only a fraction of the array of volcanic phenomena that are possible. Some volcanic features of other planets have close terrestrial counterparts and appear to have been formed by similar mechanisms and from similar magmas to those on the Earth. but other features are totally different and appear to have been formed from materials that are not normally associated with volcanism on Earth.

Multi-species beam hardening calibration device for x-ray microtomography

NASA Astrophysics Data System (ADS)

Evershed, Anthony N. Z.; Mills, David; Davis, Graham

2012-10-01

Impact-source X-ray microtomography (XMT) is a widely-used benchtop alternative to synchrotron radiation microtomography. Since X-rays from a tube are polychromatic, however, greyscale `beam hardening' artefacts are produced by the preferential absorption of low-energy photons in the beam path. A multi-material `carousel' test piece was developed to offer a wider range of X-ray attenuations from well-characterised filters than single-material step wedges can produce practically, and optimization software was developed to produce a beam hardening correction by use of the Nelder-Mead optimization method, tuned for specimens composed of other materials (such as hydroxyapatite [HA] or barium for dental applications.) The carousel test piece produced calibration polynomials reliably and with a significantly smaller discrepancy between the calculated and measured attenuations than the calibration step wedge previously in use. An immersion tank was constructed and used to simplify multi-material samples in order to negate the beam hardening effect of low atomic number materials within the specimen when measuring mineral concentration of higher-Z regions. When scanned in water at an acceleration voltage of 90 kV a Scanco AG hydroxyapatite / poly(methyl methacrylate) calibration phantom closely approximates a single-material system, producing accurate hydroxyapatite concentration measurements. This system can then be corrected for beam hardening for the material of interest.

Geochemical Interpretation of Collision Volcanism

NASA Astrophysics Data System (ADS)

Pearce, Julian

2014-05-01

Collision volcanism can be defined as volcanism that takes place during an orogeny from the moment that continental subduction starts to the end of orogenic collapse. Its importance in the Geological Record is greatly underestimated as collision volcanics are easily misinterpreted as being of volcanic arc, extensional or mantle plume origin. There are many types of collision volcanic province: continent-island arc collision (e.g. Banda arc); continent-active margin collision (e.g. Tibet, Turkey-Iran); continent-rear-arc collision (e.g. Bolivia); continent-continent collision (e.g. Tuscany); and island arc-island arc collision (e.g. Taiwan). Superimposed on this variability is the fact that every orogeny is different in detail. Nonetheless, there is a general theme of cyclicity on different time scales. This starts with syn-collision volcanism resulting from the subduction of an ocean-continent transition and continental lithosphere, and continues through post-collision volcanism. The latter can be subdivided into orogenic volcanism, which is related to thickened crust, and post-orogenic, which is related to orogenic collapse. Typically, but not always, collision volcanism is preceded by normal arc volcanism and followed by normal intraplate volcanism. Identification and interpretation of collision volcanism in the Geologic Record is greatly facilitated if a dated stratigraphic sequence is present so that the petrogenic evolution can be traced. In any case, the basis of fingerprinting collision terranes is to use geochemical proxies for mantle and subduction fluxes, slab temperatures, and depths and degrees of melting. For example, syn-collision volcanism is characterized by a high subduction flux relative to mantle flux because of the high input flux of fusible sediment and crust coupled with limited mantle flow, and because of high slab temperatures resulting from the decrease in subduction rate. The resulting geochemical patterns are similar regardless of

Cyclic aggradation and downcutting, fluvial response to volcanic activity, and calibration of soil-carbonate stages in the western Grand Canyon, Arizona

USGS Publications Warehouse

Lucchitta, Ivo; Curtis, Garniss H.; Davis, Marie E.; Davis, Sidney W.; Turrin, Brent

2000-01-01

In the western Grand Canyon, fluvial terraces and pediment surfaces, both associated with a Pleistocene basalt flow, document Quaternary aggradation and downcutting by the Colorado River, illuminate the river's response to overload and the end of overload, and allow calibration of soil-carbonate stages and determination of downcutting rates. Four downcutting-aggradation cycles are present. Each begins with erosion of older deposits to form a new river channel in which a characteristic suite of deposits is laid down. The current cycle (I) started ~700 yr B.P. The oldest (IV) includes the 603,000 ± 8000 to 524,000 ± 7000 yr Black Ledge basalt flow, emplaced when the river channel was ~30 m higher than it is now. The flow is overlain by basalt-cobble gravel and basalt sand. Soils reach the stage V level of carbonate development. Calibrated ages for soil stages are Stage V, ~525,000 yr; stage IV, <525,000 yr, ≥250,000 yr; stage III, <250,000 yr, ≥100,000 yr. The monolithologic basalt sand beds represent overloading by volcanic ash produced by an eruption 30-50 km upstream. The basalt-cobble beds signal breaching and rapid destruction of lava dams and erosion of flows. These deposits show that the Colorado River responds to overload by aggrading vigorously during the overload and then downcutting equally vigorously when the overload ends. The overall downcutting rate for the interval studied is 1.6 cm/1000 yr, much lower than rates upstream. The current downcutting rate, 11-14 m/1000 yr, likely is a response both to the end of late Pleistocene and early Holocene overload and to the reduction of sediment supply caused by Glen Canyon Dam.

Underground barrier construction apparatus with soil-retaining shield

DOEpatents

Gardner, Bradley M.; Smith, Ann Marie; Hanson, Richard W.; Hodges, Richard T.

1998-01-01

An apparatus for building a horizontal underground barrier by cutting through soil and depositing a slurry, preferably one which cures into a hardened material. The apparatus includes a digging means for cutting and removing soil to create a void under the surface of the ground, a shield means for maintaining the void, and injection means for inserting barrier-forming material into the void. In one embodiment, the digging means is a continuous cutting chain. Mounted on the continuous cutting chain are cutter teeth for cutting through soil and discharge paddles for removing the loosened soil. This invention includes a barrier placement machine, a method for building an underground horizontal containment barrier using the barrier placement machine, and the underground containment system. Preferably the underground containment barrier goes underneath and around the site to be contained in a bathtub-type containment.

Temperature influence on water transport in hardened cement pastes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Drouet, Emeline; Poyet, Stéphane, E-mail: stephane.poyet@cea.fr; Torrenti, Jean-Michel

2015-10-15

Describing water transport in concrete is an important issue for the durability assessment of radioactive waste management reinforced concrete structures. Due to the waste thermal output such structures would be submitted to moderate temperatures (up to 80 °C). We have then studied the influence of temperature on water transport within hardened cement pastes of four different formulations. Using a simplified approach (describing only the permeation of liquid water) we characterized the properties needed to describe water transport (up to 80 °C) using dedicated experiments. For each hardened cement paste the results are presented and discussed.

Laser hardening techniques on steam turbine blade and application

NASA Astrophysics Data System (ADS)

Yao, Jianhua; Zhang, Qunli; Kong, Fanzhi; Ding, Qingming

Different laser surface hardening techniques, such as laser alloying and laser solution strengthening were adopted to perform modification treatment on the local region of inset edge for 2Cr13 and 17-4PH steam turbine blades to prolong the life of the blades. The microstructures, microhardness and anti-cavitation properties were investigated on the blades after laser treatment. The hardening mechanism and technique adaptability were researched. Large scale installation practices confirmed that the laser surface modification techniques are safe and reliable, which can improve the properties of blades greatly with advantages of high automation, high quality, little distortion and simple procedure.

Volcanism in Eastern Africa

NASA Technical Reports Server (NTRS)

Cauthen, Clay; Coombs, Cassandra R.

1996-01-01

In 1891, the Virunga Mountains of Eastern Zaire were first acknowledged as volcanoes, and since then, the Virunga Mountain chain has demonstrated its potentially violent volcanic nature. The Virunga Mountains lie across the Eastern African Rift in an E-W direction located north of Lake Kivu. Mt. Nyamuragira and Mt. Nyiragongo present the most hazard of the eight mountains making up Virunga volcanic field, with the most recent activity during the 1970-90's. In 1977, after almost eighty years of moderate activity and periods of quiescence, Mt. Nyamuragira became highly active with lava flows that extruded from fissures on flanks circumscribing the volcano. The flows destroyed vast areas of vegetation and Zairian National Park areas, but no casualties were reported. Mt. Nyiragongo exhibited the same type volcanic activity, in association with regional tectonics that effected Mt. Nyamuragira, with variations of lava lake levels, lava fountains, and lava flows that resided in Lake Kivu. Mt. Nyiragongo, recently named a Decade volcano, presents both a direct and an indirect hazard to the inhabitants and properties located near the volcano. The Virunga volcanoes pose four major threats: volcanic eruptions, lava flows, toxic gas emission (CH4 and CO2), and earthquakes. Thus, the volcanoes of the Eastern African volcanic field emanate harm to the surrounding area by the forecast of volcanic eruptions. During the JSC Summer Fellowship program, we will acquire and collate remote sensing, photographic (Space Shuttle images), topographic and field data. In addition, maps of the extent and morphology(ies) of the features will be constructed using digital image information. The database generated will serve to create a Geographic Information System for easy access of information of the Eastem African volcanic field. The analysis of volcanism in Eastern Africa will permit a comparison for those areas from which we have field data. Results from this summer's work will permit

Development of a Pressure-Dependent Constitutive Model with Combined Multilinear Kinematic and Isotropic Hardening

NASA Technical Reports Server (NTRS)

Allen Phillip A.; Wilson, Christopher D.

2003-01-01

The development of a pressure-dependent constitutive model with combined multilinear kinematic and isotropic hardening is presented. The constitutive model is developed using the ABAQUS user material subroutine (UMAT). First the pressure-dependent plasticity model is derived. Following this, the combined bilinear and combined multilinear hardening equations are developed for von Mises plasticity theory. The hardening rule equations are then modified to include pressure dependency. The method for implementing the new constitutive model into ABAQUS is given.

Preparation of Al-Si Master Alloy by Electrochemical Reduction of Volcanic Rock in Cryolite Molten Salt

NASA Astrophysics Data System (ADS)

Liu, Aimin; Shi, Zhongning; Xu, Junli; Hu, Xianwei; Gao, Bingliang; Wang, Zhaowen

2016-06-01

Volcanic rock found in the Longgang Volcano Group in Jilin Province of China has properties essentially similar to Apollo lunar soils and previously prepared lunar soil simulants, such as Johnson Space Center Lunar simulant and Minnesota Lunar simulant. In this study, an electrochemical method of preparation of Al-Si master alloy was investigated in 52.7 wt.%NaF-47.3 wt.%AlF3 melt adding 5 wt.% volcanic rock at 1233 K. The cathodic electrochemical process was studied by cyclic voltammetry, and the results showed that the cathodic reduction of Si(IV) is a two-step reversible diffusion-controlled reaction. Si(IV) is reduced to Si(II) by two electron transfers at -1.05 V versus platinum quasi-reference electrode in 52.7 wt.%NaF-47.3 wt.%AlF3 molten salt adding 5 wt.% volcanic rock, while the reduction peak at -1.18 V was the co-deposition of aluminum and silicon. In addition, the cathodic product obtained by galvanostatic electrolysis for 4 h was analyzed by means of x-ray diffraction, x-ray fluorescence, scanning electron microscopy and energy dispersive spectrometry. The results showed that the phase compositions of the products are Al, Si, Al5FeSi, and Al3.21Si0.47, while the components are 90.5 wt.% aluminum, 4.4 wt.% silicon, 1.9 wt.% iron, and 0.2 wt.% titanium.

Short-term hot-hardness characteristics of five case hardened steels

NASA Technical Reports Server (NTRS)

Anderson, N. E.; Zaretsky, E. V.

1975-01-01

Short-term hot-hardness studies were performed with carburized and hardened AISI 8620, CBS 1000, CBS 1000M, CBS 600, and Vasco X-2 steels. Case and core hardness measurements were made at temperatures from 294 to 811 K (70 to 1000 F). The data were compared with data for high-speed tool steels and AISI 52100. The materials tested can be ranked as follows in order of decreasing hot-hardness retention: (1) Vasco X-2; equivalent to through-hardened tool steels up to 644 K (700 F) above which Vasco X-2 is inferior; (2) CBS 1000, (3) CBS 1000M; (4) CBS 6000; better hardness retention at elevated temperatures than through-hardened AISI 52100; and (5) AISI 8620. For the carburized steels, the change in hardness with temperature of the case and core are similar for a given material. The short-term hot hardness of these materials can be predicted with + or - 1 point Rockwell C.

Effect of Annealing on Microstructures and Hardening of Helium-Hydrogen-Implanted Sequentially Vanadium Alloys

NASA Astrophysics Data System (ADS)

Jiang, Shaoning; Wang, Zhiming

2018-03-01

The effect of post-irradiation annealing on the microstructures and mechanical properties of V-4Cr-4Ti alloys was studied. Helium-hydrogen-irradiated sequentially V-4Cr-4Ti alloys at room temperature (RT) were undergone post-irradiation annealing at 450 °C over periods of up to 30 h. These samples were carried out by high-resolution transmission electron microscopy (HRTEM) observation and nanoindentation test. With the holding time, large amounts of point defects produced during irradiation at RT accumulated into large dislocation loops and then dislocation nets which promoted the irradiation hardening. Meanwhile, bubbles appeared. As annealing time extended, these bubbles grew up and merged, and finally broke up. In the process, the size of bubbles increased and the number density decreased. Microstructural changes due to post-irradiation annealing corresponded to the change of hardening. Dislocations and bubbles are co-contributed to irradiation hardening. With the holding time up to 30 h, the recovery of hardening is not obvious. The phenomenon was discussed by dispersed barrier hardening model and Friedel-Kroupa-Hirsch relationship.

Drought tolerance and transplanting performance of holm oak (Quercus ilex) seedlings after drought hardening in the nursery.

PubMed

Villar-Salvador, Pedro; Planelles, Rosa; Oliet, Juan; Peñuelas-Rubira, Juan L; Jacobs, Douglass F; González, Magdalena

2004-10-01

Drought stress is the main cause of mortality of holm oak (Quercus ilex L.) seedlings in forest plantations. We therefore assessed if drought hardening, applied in the nursery at the end of the growing season, enhanced the drought tolerance and transplanting performance of holm oak seedlings. Seedlings were subjected to three drought hardening intensities (low, moderate and severe) for 2.5 and 3.5 months, and compared with control seedlings. At the end of the hardening period, water relations, gas exchange and morphological attributes were determined, and survival and growth under mesic and xeric transplanting conditions were assessed. Drought hardening increased drought tolerance primarily by affecting physiological traits, with no effect on shoot/root ratio or specific leaf mass. Drought hardening reduced osmotic potential at saturation and at the turgor loss point, stomatal conductance, residual transpiration (RT) and new root growth capacity (RGC), but enhanced cell membrane stability. Among treated seedlings, the largest response occurred in seedlings subjected to moderate hardening. Severe hardening reduced shoot soluble sugar concentration and increased shoot starch concentration. Increasing the duration of hardening had no effect on water relations but reduced shoot mineral and starch concentrations. Variation in cell membrane stability, RT and RGC were negatively related to osmotic adjustment. Despite differences in drought tolerance, no differences in mortality and relative growth rate were observed between hardening treatments when the seedlings were transplanted under either mesic or xeric conditions.

Geochemical evidence for African dust inputs to soils of western Atlantic islands: Barbados, the Bahamas, and Florida

USGS Publications Warehouse

Muhs, D.R.; Budahn, J.R.; Prospero, J.M.; Carey, S.N.

2007-01-01

We studied soils on high-purity limestones of Quaternary age on the western Atlantic Ocean islands of Barbados, the Florida Keys, and the Bahamas. Potential soil parent materials in this region, external to the carbonate substrate, include volcanic ash from the island of St. Vincent (near Barbados), volcanic ash from the islands of Dominica and St. Lucia (somewhat farther from Barbados), the fine-grained component of distal loess from the lower Mississippi River Valley, and wind-transported dust from Africa. These four parent materials can be differentiated using trace elements (Sc, Cr, Th, and Zr) and rare earth elements that have minimal mobility in the soil-forming environment. Barbados soils have compositions that indicate a complex derivation. Volcanic ash from the island of St. Vincent appears to have been the most important influence, but African dust is a significant contributor, and even Mississippi River valley loess may be a very minor contributor to Barbados soils. Soils on the Florida Keys and islands in the Bahamas appear to have developed mostly from African dust, but Mississippi River valley loess may be a significant contributor. Our results indicate that inputs of African dust are more important to the genesis of soils on islands in the western Atlantic Ocean than previously supposed. We hypothesize that African dust may also be a major contributor to soils on other islands of the Caribbean and to soils in northern South America, central America, Mexico, and the southeastern United States. Dust inputs to subtropical and tropical soils in this region increase both nutrient-holding capacity and nutrient status and thus may be critical in sustaining vegetation. Copyright 2007 by the American Geophysical Union.

Synthesis of a new hardener agent for self-healing epoxy resins

NASA Astrophysics Data System (ADS)

Raimondo, Marialuigia; Guadagno, Liberata; Naddeo, Carlo; Longo, Pasquale; Mariconda, Annaluisa; Agovino, Anna

2014-05-01

Actually, the development of smart composites capable of self-repair in aeronautical structures is still at the planning stage owing to complex issues to overcome. One of the critical points in the development of self-healing epoxy resin is related to the impossibility to employ primary amines as hardeners. In this paper, the synthesis of a new hardener for self-healing resins is shown together with applicability conditions/ranges.

Heavy metals in the volcanic environment and thyroid cancer.

PubMed

Vigneri, R; Malandrino, P; Gianì, F; Russo, M; Vigneri, P

2017-12-05

In the last two decades thyroid cancer incidence has increased worldwide more than any other cancer. Overdiagnosis of subclinical microcarcinomas has certainly contributed to this increase but many evidences indicate that a true increase, possibly due to environmental factors, has also occurred. Thyroid cancer incidence is markedly increased in volcanic areas. Thus, the volcanic environment is a good model to investigate the possible factors favoring thyroid cancer. In the volcanic area of Mt. Etna in Sicily, as well as in other volcanic areas, a non-anthropogenic pollution with heavy metals has been documented, a consequence of gas, ash and lava emission. Soil, water and atmosphere contamination, via the food chain, biocontaminate the residents as documented by high levels in the urines and the scalp hair compared to individuals living in adjacent non-volcanic areas. Trace amounts of metals are essential nutrients but, at higher concentrations, can be toxic for living cells. Metals can behave both as endocrine disruptors, perturbing the hormonal system, and as carcinogens, promoting malignant transformation. Similarly to other carcinogens, the transforming effect of heavy metals is higher in developing organisms as the fetus (contaminated via the mother) and individuals in early childhood. In the last decades environment metal pollution has greatly increased in industrialized countries. Although still within the "normal" limits for each single metal the hormesis effect (heavy metal activity at very low concentration because of biphasic, non linear cell response) and the possible potentiation effect resulting from the mixture of different metals acting synergistically can explain cell damage at very low concentrations. The effect of metals on the human thyroid is poorly studied: for some heavy metals no data are available. The scarce studies that have been performed mainly focus on metal effect as thyroid endocrine disruptors. The metal concentration in tissues has

Deuterium Values from Hydrated Volcanic Glass: A Paleoelevation Proxy for Oregon's Cascade Range

NASA Astrophysics Data System (ADS)

Carlson, T. B.; Bershaw, J. T.; Cassel, E. J.

2017-12-01

Deuterium ratios (δD) of hydrated volcanic glass have been used to reconstruct Cenozoic paleoenvironments. However, the reliability and proper sample preparation protocol have been debated. The Cascades are an excellent location to study the validity of hydrated volcanic glass as a paleoelevation proxy for several reasons. Moisture is largely derived from a single oceanic source and falls as orographic precipitation in the Cascades, leading to a characteristic altitude effect, or inverse relationship between elevation and the isotopic composition of meteoric water (δD). Additionally, past studies have inferred uplift of the Cascades since the Miocene based on changing fossil assemblages, tectonic models, and other isotopic proxies including soil carbonates and fossil teeth. In this study, hydrated volcanic ash samples from the lee of the Cascades were rinsed with hydrochloric acid and sonicated before glass shards were hand-selected and analyzed for δD and wt. % water. These preliminary results exhibited δD values becoming enriched with time, a trend opposite of other paleowater proxy studies in the area. A possible explanation for this trend is contamination due to inadequate removal of materials adhered to shard surfaces that can readily exchange with environmental water. Recent research asserts that hydrofluoric acid (HF) etching during sample preparation is necessary to accurately measure δD values of syndepositional water. Volcanic ash samples were reanalyzed after preparation using HF abrasion and heavy liquid separation. The data from these two subsets are interpreted in the context of modern water across the range, as well as other paleowater proxy and geologic studies to determine the implications of volcanic glass as a paleoelevation proxy in the Pacific Northwest.

Using Uranium-series isotopes to understand processes of rapid soil formation in tropical volcanic settings: an example from Basse-Terre, French Guadeloupe

NASA Astrophysics Data System (ADS)

Ma, Lin

2015-04-01

Lin Ma1, Yvette Pereyra1, Peter B Sak2, Jerome Gaillardet3, Heather L Buss4 and Susan L Brantley5, (1) University of Texas at El Paso, El Paso, TX, United States, (2) Dickinson College, Carlisle, PA, United States, (3) Institute de Physique d Globe Paris, Paris, France, (4) University of Bristol, Bristol, United Kingdom, (5) Pennsylvania State University Main Campus, University Park, PA, United States Uranium-series isotopes fractionate during chemical weathering and their activity ratios can be used to determine timescales and rates of soil formation. Such soil formation rates provide important information to understand processes related to rapid soil formation in tropical volcanic settings, especially with respect to their fertility and erosion. Recent studies also highlighted the use of U-series isotopes to trace and quantify atmospheric inputs to surface soils. Such a process is particularly important in providing mineral nutrients to ecosystems in highly depleted soil systems such as the tropical soils. Here, we report U-series isotope compositions in thick soil profiles (>10 m) developed on andesitic pyroclastic flows in Basse-Terre Island of French Guadeloupe. Field observations have shown heterogeneity in color and texture in these thick profiles. However, major element chemistry and mineralogy show some general depth trends. The main minerals present throughout the soil profile are halloysite and gibbsite. Chemically immobile elements such as Al, Fe, and Ti show a depletion profile relative to Th while elements such as K, Mn, and Si show a partial depletion profile at depth. Mobile elements such as Ca, Mg, and Sr have undergone intensive weathering at depths, and an addition profile near the surface, most likely related to atmospheric inputs. (238U/232Th) activity ratios in one soil profile from the Brad David watershed in this study ranged from 0.374 to 1.696, while the (230Th/232Th) ratios ranged from 0.367 to 1.701. A decrease of (238U/232Th) in the

Microstructure, Tensile Properties and Work Hardening Behavior of GTA-Welded Dual-Phase Steels

NASA Astrophysics Data System (ADS)

Ashrafi, H.; Shamanian, M.; Emadi, R.; Saeidi, N.

2017-03-01

In the present study, microstructure, tensile properties and work hardening behavior of a DP700 steel after gas tungsten arc welding were investigated. Formation of bainite in the fusion zone resulted in a hardness increase compared to that for the base metal (BM), whereas tempering of the pre-existing martensite in the subcritical heat-affected zone (HAZ) led to softening. The GTA-welded joint exhibited a continuous yielding behavior and a yield strength close to that for the BM, while its ultimate tensile strength and total elongation were lower than those for the BM owing to the formation of soft zone in the HAZ. A joint efficiency of about 81% was obtained for the GTA-welded joint, and it failed in the softened HAZ. Analysis of work hardening based on the Kocks-Mecking approach showed one stage of hardening behavior corresponding to the stage III for both the DP700 BM and welded sample. It was also revealed that the DP700 BM has larger values of work hardening exponent and magnitude of work hardening compared with the welded sample. Analysis of fractured surfaces showed that the dominant fracture mode for both the DP700 BM and welded joint was ductile.

Investigation of Thermal Hardening of the FCC Material Containing Strengthening Particles with an L12 Superstructure

NASA Astrophysics Data System (ADS)

Daneyko, O. I.; Kulaeva, N. A.; Kovalevskaya, C. A.; Kolupaeva, S. N.

2015-07-01

A mathematical model of plastic deformation of dispersion-hardened materials with an fcc matrix containing strengthening particles with an L12 superstructure having a coherent relationship with the matrix is presented. The model is based on the balance equations of deformation defects of different types with taking into account their transformation during plastic deformation. The influence of scale characteristics of the hardening phase, temperature, and deformation rate on the evolution of the dislocation subsystem and strain hardening of an alloy with an fcc matrix hardened by particles with an L12 super structure is studied. A temperature anomaly of mechanical properties is found for the materials with different fcc matrices (Al,Cu, Ni). It is shown that the temperature anomaly is more pronounced for the material with larger volume fraction of the hardening phase.

Mechanical interaction between volcanic systems in Libya

NASA Astrophysics Data System (ADS)

Elshaafi, Abdelsalam; Gudmundsson, Agust

2018-01-01

The spatial distributions of monogenetic volcanoes, primarily volcanic craters, within the four principal volcanic provinces of Libya are examined and presented on a volcano-density map. Six main volcanic clusters have been identified, referred to as volcanic systems. Remarkably, the Al Haruj (AHVP) and Nuqay (NVP) volcanic provinces have double-peak volcano-density distributions, while the Gharyan (GVP) and As Sawda (SVP) volcanic provinces have single-peak volcano-density distributions. We interpret each volcano-density peak as corresponding to a separate volcanic system, so that there is a total of six systems in these four provinces. There was an overlap in volcanic activity in these provinces with at least three simultaneously active. We propose that each of the 6 volcanic systems was/is supplied with magma from a large sill-like reservoir - similar in lateral dimensions to the systems/clusters themselves. Numerical results show zones of high tensile and shear stresses between the reservoirs that coincide roughly with the main swarms of extension (dykes and volcanic fissures) and shear (faults) fractures in the areas. The most recent volcanic eruptions in Libya fall within the modelled high-stress concentration zones, primarily eruptions in the volcano Waw an Namus and the Holocene Al Mashaqaq lava flow. There are no known eruptions in Libya in historical time, but some or all the volcanic systems may have had one or more arrested historical dyke injections. In particular, part of the recurrent seismic events in the Hun Graben in the northwest Libya may be related to dyke propagation and arrest. If some of the inferred magma reservoirs are still fluid, as is likely, they pose earthquake and volcanic hazards to parts of Libya, particularly to the city of Gharyan and Zallah town, as well as to many oil-field operations.

Importance of calcium and magnesium in water - water hardening

NASA Astrophysics Data System (ADS)

Barloková, D.; Ilavský, J.; Kapusta, O.; Šimko, V.

2017-10-01

Basic information about importance of calcium and magnesium in water, about their properties, effect to human health, problems what can cause under the lower (< 1 mmol/L) and higher (> 5 mmol/L) concentrations in water supply distribution systems, the most commonly used methods of water hardening are presented. The article contains the water hardening results carried out during the pilot plant experiments in WTP Hriňová and WTP Turček. For water hardening, treated water at the end of the process line, i.e., after coagulation, sedimentation and filtration, saturated with CO2 and filtrated through half-burnt dolomite material (PVD) was used. The results show that the filtration rate is 17.1 m/h in the case of WTP Hriňová and 15.2 m/h in the case of WTP Turček to achieve the recommended concentration of Ca and Mg in the treated water after the addition of CO2 and filtration through PVD. The longer the water contact time with PVD (depending on the CO2 content), the more water is enriched with magnesium, but the calcium concentration has not so much increased.

Anomalous increase of diffuse CO_{2} emission from Brava (Cape Verde): evidence of volcanic unrest or increase gas release from a stationary magma body?

NASA Astrophysics Data System (ADS)

García-Merino, Marta; García-Hernández, Rubén; Montrond, Eurico; Dionis, Samara; Fernandes, Paulo; Silva, Sonia V.; Alfama, Vera; Cabral, Jeremías; Pereira, Jose M.; Padrón, Eleazar; Pérez, Nemesio M.

2017-04-01

Brava (67 km2) is the southwestern most and the smallest inhabited island of the Cape Verde archipelago. It is located 18 km west of Fogo Island and rises 976 m from the sea level. Brava has not any documented historical eruptions, but its Holocene volcanism and relatively high seismic activity clearly indicate that it is an active volcanic island. Since there have been no historic eruptions in Brava, volcanic hazard awareness among the population and the authorities is very low; therefore, its volcano monitoring program is scarce. With the aim of helping to provide a multidisciplinary monitoring program for the volcanic surveillance of the island, diffuse CO2 emission surveys have been carried out since 2010; approximately every 2 years. Soil CO2 efflux measurements are periodically performed at ˜ 275 observation sites all over the island and after taking into consideration their accessibility and the island volcano-structural characteristics. At each sampling site, soil CO2 efflux measurement was performed by means of a portable NDIR sensor according to the accumulation chamber method. To quantify the total diffuse CO2 emission from Brava volcanic system, soil CO2 efflux maps were constructed using sequential Gaussian simulations (sGs). An increase trend of diffuse CO2 emission rate from 42 to 681 t d-1at Brava was observed; just one year prior the 2014-2015 Fogo eruption and almost three years before the anomalous seismic activity recorded on August 2016 with more than 1000 seismic events registered by the INMG on August 1st, 2016 (Bruno Faria, personal communication). Due to this anomalous seismic activity, a diffuse CO2 emission survey at Brava was performed from August 2 to 10, 2016, and the estimated degassing rate yield a value about 72 t d-1; typical background values. An additional survey was carried out from October 22 to November 6, 2016. For this last survey, the estimated diffuse CO2 emission from Brava showed the highest observed value with a

Beam hardening correction for interior tomography based on exponential formed model and radon inversion transform

NASA Astrophysics Data System (ADS)

Chen, Siyu; Zhang, Hanming; Li, Lei; Xi, Xiaoqi; Han, Yu; Yan, Bin

2016-10-01

X-ray computed tomography (CT) has been extensively applied in industrial non-destructive testing (NDT). However, in practical applications, the X-ray beam polychromaticity often results in beam hardening problems for image reconstruction. The beam hardening artifacts, which manifested as cupping, streaks and flares, not only debase the image quality, but also disturb the subsequent analyses. Unfortunately, conventional CT scanning requires that the scanned object is completely covered by the field of view (FOV), the state-of-art beam hardening correction methods only consider the ideal scanning configuration, and often suffer problems for interior tomography due to the projection truncation. Aiming at this problem, this paper proposed a beam hardening correction method based on radon inversion transform for interior tomography. Experimental results show that, compared to the conventional correction algorithms, the proposed approach has achieved excellent performance in both beam hardening artifacts reduction and truncation artifacts suppression. Therefore, the presented method has vitally theoretic and practicable meaning in artifacts correction of industrial CT.

Relic components within the soil cover of Mexico: regional variability

NASA Astrophysics Data System (ADS)

Solleiro Rebolledo, Elizabeth; Sedov, Sergey

2015-04-01

The case of paleosols persisting on the land surface (non-buried paleosols or relict soils) besides paleoecological interest has specific implications for studies of soil geography, ecology and management. In fact these soil bodies form part of the modern soil mantle and provide ecological services for the current (agro)ecosystems but are neither formed nor re-produced by these ecosystems, conforming locally extinct soils (although similar profiles can develop at present under other bioclimatic conditions). In consequence, they are a heritage of past climatic and biotic conditions now extinct, thus presenting a non-restorable component of the present landscape. Mexico has so abundant and diverse paleosols, both surface and buried, that really could be considered to be a "paleopedological paradise". Two groups of factors promote generation of this abundance: Major part of territory of Mexico is occupied by mountainous landscapes with high intensity of tectonic, volcanic and geomorphic processes. These processes create a complex mosaic of geological materials and landforms of different age (like alluvial and lake terraces, eroded slopes, and volcanic deposits of various eruptions). Meanwhile younger landsurfaces are occupied by the recently developed soils, the older ones could bear the relict soil bodies. The same processes produce sedimentary strata (alluvial, colluvial, pyroclastic, etc.) which frequently cover the pre-existing landsurfaces and soils, producing series of buried paleosols. In this work we present three study cases of relict paleosols that are integrated to the modern soil cover of Mexico: the case of reddish-brown soils in the arid landscapes of Sonora (in the north); the pedosediments (tepetates) in central Mexico; and the red soils developed under humid conditions in Yucatan (in the south).

Volcanic gas

USGS Publications Warehouse

McGee, Kenneth A.; Gerlach, Terrance M.

1995-01-01

In Roman mythology, Vulcan, the god of fire, was said to have made tools and weapons for the other gods in his workshop at Olympus. Throughout history, volcanoes have frequently been identified with Vulcan and other mythological figures. Scientists now know that the “smoke" from volcanoes, once attributed by poets to be from Vulcan’s forge, is actually volcanic gas naturally released from both active and many inactive volcanoes. The molten rock, or magma, that lies beneath volcanoes and fuels eruptions, contains abundant gases that are released to the surface before, during, and after eruptions. These gases range from relatively benign low-temperature steam to thick hot clouds of choking sulfurous fume jetting from the earth. Water vapor is typically the most abundant volcanic gas, followed by carbon dioxide and sulfur dioxide. Other volcanic gases are hydrogen sulfide, hydrochloric acid, hydrogen, carbon monoxide, hydrofluoric acid, and other trace gases and volatile metals. The concentrations of these gas species can vary considerably from one volcano to the next.

Modeling the erosion of tropical volcanic ocean islands : The Tahiti island case (French Polynesia)

NASA Astrophysics Data System (ADS)

Ye, F.; Sichoix, L.; Barriot, J.; Dumas, P.

2009-12-01

In this study, we are interested in modeling the erosion of the Tahiti island, with two main objectives: risk assessment (erodibility of terrains with rainfall, catastrophic runoffs) and estimation of subsidence rate. The Tahiti island created around 1.4 Myears ago by an intraplate hotspot (aerial radiometric dating), is divided into two geological units: the main island Tahiti-Nui to northwest (end of volcanism 200,000 years ago) and the subsidiary Tahiti-Iti to the southeast (end of volcanism 380,000 years ago). It is now volcanically inactive and is deeply dissected by erosion. Tahiti Nui is around 30 km in diameter, and Tahiti Iti around 15 km. Both are linked through the isthmus of Taravao. The highest elevation is 2241 m. The two sub-islands are basaltic edifices, with an overwhelming presence of oxisols (down to tens of meters in some places). Slopes can be divided into three classes: 15° for the global slope of the shield volcanoes, 47° for the incision valleys and 2° for the seashore rim. Rainfalls range from 8,000 mm/year on the East side of Tahiti (trade winds) to 2,000 mm/year on the West side, the humid season of a year is summer. This study is conducted to validate the Unit Stream Power Erosion and Deposition (USPED) model, an enrichment to the Universal Soil Loss Equation (USLE) to calculate average annual soil loss per unit land area resulting from rill and sheet erosion. The USPED model differs from other USLE models on how it handles the influence of topography on the erosion process, because USLE consider erosion only along the flow line without the influence of flow convergence/divergence. As the result, the USPED model predicts both erosion and deposition, while most other USLE-based models are limited to predictions of erosion only. The USLE, USPED equation can be written as A=R*K*LS*C*P where A is the soil loss, R the rainfall-runoff erosivity factor, K a soil erodibility factor, L a slope-length factor, S a slope steepness factor, C a

Mainshock-aftershock clustering in volcanic regions

USGS Publications Warehouse

Giron, Ricardo Garza; Brodsky, Emily E.; Prejean, Stephanie

2018-01-01

swarms and mainshock-aftershock sequences. The former is commonly thought to dominate in volcanic and geothermal regions, but aftershock production, including within swarms, is not well studied in volcanic regions. Here we compare mainshock-aftershock clustering in active volcanic regions in Japan to nearby nonvolcanic regions. We find that aftershock production is similar in both areas by two separate metrics: (1) Both volcanic and nonvolcanic regions have similar proportions of areas that cluster into mainshock-aftershock sequences. (2) Volcanic areas with mainshock-aftershock sequences have aftershock productivity at least as high as nonvolcanic regions. We also find that volcano-tectonic events that are precursors to an eruption are more common at volcanoes without mainshock-aftershock clusters than at volcanoes with well-defined mainshock-aftershock clusters. This last finding hints at a strategy to identify volcanic systems where cataloged earthquakes are good predictors of behavior.

Recent developments in turning hardened steels - A review

NASA Astrophysics Data System (ADS)

Sivaraman, V.; Prakash, S.

2017-05-01

Hard materials ranging from HRC 45 - 68 such as hardened AISI H13, AISI 4340, AISI 52100, D2 STL, D3 STEEL Steel etc., need super hard tool materials to machine. Turning of these hard materials is termed as hard turning. Hard turning makes possible direct machining of the hard materials and also eliminates the lubricant requirement and thus favoring dry machining. Hard turning is a finish turning process and hence conventional grinding is not required. Development of the new advanced super hard tool materials such as ceramic inserts, Cubic Boron Nitride, Polycrystalline Cubic Boron Nitride etc. enabled the turning of these materials. PVD and CVD methods of coating have made easier the production of single and multi layered coated tool inserts. Coatings of TiN, TiAlN, TiC, Al2O3, AlCrN over cemented carbide inserts has lead to the machining of difficult to machine materials. Advancement in the process of hard machining paved way for better surface finish, long tool life, reduced tool wear, cutting force and cutting temperatures. Micro and Nano coated carbide inserts, nanocomposite coated PCBN inserts, micro and nano CBN coated carbide inserts and similar developments have made machining of hardened steels much easier and economical. In this paper, broad literature review on turning of hardened steels including optimizing process parameters, cooling requirements, different tool materials etc., are done.

Clay minerals, metallic oxides and oxy-hydroxides and soil organic carbon distribution within soil aggregates in temperate forest soils

NASA Astrophysics Data System (ADS)

Gartzia-Bengoetxea, Nahia; Fernández-Ugalde, Oihane; Virto, Iñigo; Arias-González, Ander

2017-04-01

Soil mineralogy is of primary importance for key environmental services provided by soils like carbon sequestration. However, current knowledge on the effects of clay mineralogy on soil organic carbon (SOC) stabilization is based on limited and conflicting data. In this study, we investigated the relationship between clay minerals, metallic oxides and oxy-hydroxides and SOC distribution within soil aggregates in mature Pinus radiata D.Don forest plantations. Nine forest stands located in the same geographical area of the Basque Country (North of Spain) were selected. These stands were planted on different parent material (3 on each of the following: sandstone, basalt and trachyte). There were no significant differences in climate and forest management among them. Moreover, soils under these plantations presented similar content of clay particles. We determined bulk SOC storage, clay mineralogy, the content of Fe-Si-Al-oxides and oxyhydroxides and the distribution of organic C in different soil aggregate sizes at different soil depths (0-5 cm and 5-20 cm). The relationship between SOC and abiotic factors was investigated using a factor analysis (PCA) followed by stepwise regression analysis. Soils developed on sandstone showed significantly lower concentration of SOC (29 g C kg-1) than soils developed on basalts (97 g C kg-1) and trachytes (119 g C kg-1). The soils on sandstone presented a mixed clay mineralogy dominated by illite, with lesser amounts of hydroxivermiculite, hydrobiotite and kaolinite, and a total absence of interstratified chlorite/vermiculite. In contrast, the major crystalline clay mineral identified in the soils developed on volcanic rocks was interstratified chlorite/vermiculite. Nevertheless, no major differences were observed between basaltic and trachytic soils in the clay mineralogy. The selective extraction of Fe showed that the oxalate extractable iron was significantly lower in soils on sandstone (3.7%) than on basalts (11.2%) and

Gas emission from diffuse degassing structures (DDS) of the Cameroon volcanic line (CVL): Implications for the prevention of CO2-related hazards

NASA Astrophysics Data System (ADS)

Issa; Ohba, T.; Chako Tchamabé, B.; Padrón, E.; Hernández, P.; Eneke Takem, E. G.; Barrancos, J.; Sighomnoun, D.; Ooki, S.; Nkamdjou, Sigha; Kusakabe, M.; Yoshida, Y.; Dionis, S.

2014-08-01

In the mid-1980s, lakes Nyos and Monoun violently released massive gas, mainly magmatic CO2 killing about 1800 people. Subsequent geochemical surveys and social studies indicate that lakes Nyos and Monoun event is cyclic in nature and may occur anywhere in the about 37 other volcanic lakes located in the corridor of the Cameroon volcanic line (CVL). This potential threat motivated us to check if, alike Nyos and Monoun, the internal dynamic of the other lakes is also controlled by inputs of deep-seated-derived CO2 and attempt to measure and provide comprehensive insights on the passive gas emission along the CVL. This knowledge shall contribute to the prevention of volcanic lake-related hazards in Cameroon and the refinement of the Global Carbon Cycle. We used in situ fixation and dry gas phase sampling methods to determine CO2 origin and the concentration, and the accumulation chamber technique to measure diffuse CO2 emission from nine lakes and on soil at Nyos Valley and Mount Manenguba Caldera. The results suggest that, although in minor concentrations (compared to Nyos and Monoun), ranging from 0.56 mmol kg- 1 to 8.75 mmol kg- 1, the bottom waters of some lakes also contain measurable magmatic CO2 with δ13C varies from - 4.42‰ to - 9.16‰ vs. PDB. That finding implies that, under certain circumstances, e.g. increase to volcanic and/or tectonic activities along the CVL, the concerned lakes could develop a Nyos-type behavioural scheme. The diffuse gas emission results indicate that the nine surveyed lakes release approximately 3.69 ± 0.37 kt km- 2 yr- 1 of CO2 to the atmosphere; extrapolation to the approximately 39 volcanic lakes located on the CVL yields an approximate CO2 output of 27.37 ± 0.5 kt km- 2 yr- 1, representing 0.023% of the global CO2 output from volcanic lakes. In addition to the precedent value, the gas removal operation in lakes Nyos and Monoun released approximately 2.52 ± 0.46 × 108 mol km- 2 yr- 1 CO2 to the atmosphere from January

High diversity of methanotrophic bacteria in geothermal soils affected by high methane fluxes

NASA Astrophysics Data System (ADS)

D'Alessandro, Walter; Gagliano, Antonina Lisa; Quatrini, Paola; Parello, Francesco

2014-05-01

Volcanic and geothermal systems emit endogenous gases by widespread degassing from soils, including CH4, a greenhouse gas 25 times as potent as CO2. Recently, it has been demonstrated that volcanic/geothermal soils act as source, but also as biological filter for methane release to the atmosphere. For long time, volcanic/geothermal soils has been considered inhospitable for methanotrophic microorganisms, but new extremophile methanotrophs belonging to Verrucomicrobia were identified in three different areas (Pozzuoli, Italy; Hell's Gate, New Zealand; Kamchatka, Russia), explaining anomalous behaviours in methane leakages of several geothermal/volcanic sites. Our aim was to increase the knowledge of the relationship between methane emissions from volcanic/geothermal areas and biological methane oxidation, by investigating a geothermal site of Pantelleria island (Italy). Pantelleria Island hosts a high enthalpy geothermal system characterized by high temperature, high CH4 and very low H2S fluxes. Such characteristics are reflected in potentially great supply of methane for methanotrophs and scarce presence of inhibitors of their activity (H2S and NH3) in the Pantelleria soils. Potential methanotrophic activity within these soils was already evidenced by the CH4/CO2 ratio of the flux measurements which was lower than that of the respective fumarolic manifestations indicating a loss of CH4 during the gas travel towards the earth's surface. In this study laboratory incubation experiments using soils sampled at Favara Grande, the main hydrothermal area of Pantelleria, showed very high methane consumption rates (up to 9500 ng CH4 h-1 g-1). Furthermore, microbiological and culture-independent molecular analyses allowed to detect the presence of methanotrophs affiliated to Gamma- and Alpha-Proteobacteria and to the newly discovered acidothermophilic methanotrophs Verrucomicrobia. Culturable methanotrophic Alpha-proteobacteria of the genus Methylocystis were isolated by

Volcanic Perspective on Plutonism based on Patterns in Evolution in Long-Lived Continental Volcanic Systems

NASA Astrophysics Data System (ADS)

Grunder, A. L.; Harris, R. N.; Walker, B. A.; Giles, D.; Klemetti, E. W.

2008-12-01

Volcanic rocks represent a biased view of magmatism, but provide critical quenched samples and temporal constraints of magmatic evolution obscured in the plutonic record. We here draw on the records from the Aucanquilcha Volcanic Cluster (AVC; 10 to 0 Ma) in northern Chile and from the mid-Tertiary volcanic field in east-central Nevada (ECNVF; ~40-32 Ma) to consider how evolutionary patterns of intermediate composition volcanic systems bear on the magmatic reworking of the continental crust by plutons and batholiths. Despite disparate tectonic setting (subduction vs extension) and volumes (70 km crust for the ~300 km 3 AVC versus and ~40 km crust for the ~3000 km 3 ECNVF) both volcanic systems share a history of early compositionally diverse volcanism, followed by a stage of more centralized and voluminous dacitic volcanism, which in turn is followed by waning of volcanism. The compositional change and the rapid increase in magma output rate after about half the lifetime of the system is a characteristic pattern of long- lived continental volcanic systems based on a compilation of volume-composition data. The middle, voluminous stage corresponds to the hottest upper crustal conditions, deduced from Al-in-amphibole geothermobarometry and Ti-in-zircon thermometry of the AVC. The middle stage rocks also have textures indicating hybridization of mixed magmas. Simple thermal models of heat input via intraplating readily allow for generation of partially molten crust above the sill, but they do not emulate the rapid increase of magma after some incubation time. We propose that there is a feedback in which a critical thickness of partially molten crust, consisting in part of magmatic precursors, can be readily convectively stirred and mixed with magma of the underplating sill, rapidly creating a large, hybrid and relatively hot body of magma. Stirring facilitates separation of a liquid-enriched extract. The volume of liquid extracted may be small relative to residual

A Study of Soil and Duricrust Models for Mars

NASA Technical Reports Server (NTRS)

Bishop, Janice L.; DeVincenzi, Donald L. (Technical Monitor)

2001-01-01

This project includes analysis of the Mars Pathfinder soil data (spectral, chemical and magnetic) together with analog materials and the products of laboratory alteration experiments in order to describe possible mechanisms for the formation of soil, duricrust and rock coatings on Mars. Soil analog mixtures have been prepared, characterized and tested through wet/dry cycling experiments for changes in binding and spectroscopic properties that are related to what could be expected for duricrusts on Mars. The smectite-based mixture exhibited significantly greater changes (1) in its binding properties throughout the wet/dry cycling experiments than did the palagonite-based mixture, and (2) in its spectral properties following grinding and resieving of the hardened material than did the palagonite-based mixture.

Using Volcanic Lightning Measurements to Discern Variations in Explosive Volcanic Activity

NASA Astrophysics Data System (ADS)

Behnke, S. A.; Thomas, R. J.; McNutt, S. R.; Edens, H. E.; Krehbiel, P. R.; Rison, W.

2013-12-01

VHF observations of volcanic lightning have been made during the recent eruptions of Augustine Volcano (2006, Alaska, USA), Redoubt Volcano (2009, Alaska, USA), and Eyjafjallajökull (2010, Iceland). These show that electrical activity occurs both on small scales at the vent of the volcano, concurrent with an eruptive event and on large scales throughout the eruption column during and subsequent to an eruptive event. The small-scale discharges at the vent of the volcano are often referred to as 'vent discharges' and are on the order of 10-100 meters in length and occur at rates on the order of 1000 per second. The high rate of vent discharges produces a distinct VHF signature that is sometimes referred to as 'continuous RF' radiation. VHF radiation from vent discharges has been observed at sensors placed as far as 100 km from the volcano. VHF and infrasound measurements have shown that vent discharges occur simultaneously with the onset of eruption, making their detection an unambiguous indicator of explosive volcanic activity. The fact that vent discharges are observed concurrent with explosive volcanic activity indicates that volcanic ejecta are charged upon eruption. VHF observations have shown that the intensity of vent discharges varies between eruptive events, suggesting that fluctuations in eruptive processes affect the electrification processes giving rise to vent discharges. These fluctuations may be variations in eruptive vigor or variations in the type of eruption; however, the data obtained so far do not show a clear relationship between eruption parameters and the intensity or occurrence of vent discharges. Further study is needed to clarify the link between vent discharges and eruptive behavior, such as more detailed lightning observations concurrent with tephra measurements and other measures of eruptive strength. Observations of vent discharges, and volcanic lightning observations in general, are a valuable tool for volcano monitoring, providing a

Underground barrier construction apparatus with soil-retaining shield

DOEpatents

Gardner, B.M.; Smith, A.M.; Hanson, R.W.; Hodges, R.T.

1998-08-04

An apparatus is described for building a horizontal underground barrier by cutting through soil and depositing a slurry, preferably one which cures into a hardened material. The apparatus includes a digging means for cutting and removing soil to create a void under the surface of the ground, a shield means for maintaining the void, and injection means for inserting barrier-forming material into the void. In one embodiment, the digging means is a continuous cutting chain. Mounted on the continuous cutting chain are cutter teeth for cutting through soil and discharge paddles for removing the loosened soil. This invention includes a barrier placement machine, a method for building an underground horizontal containment barrier using the barrier placement machine, and the underground containment system. Preferably the underground containment barrier goes underneath and around the site to be contained in a bathtub-type containment. 17 figs.

Elemental Analysis of Soils by Laser Induced Breakdown Spectroscopy

NASA Astrophysics Data System (ADS)

Gondal, Mohammed Ashraf; Dastageer, Mohamed A.

The chemical and elemental composition of soil is very complex as it contains many constituents like minerals, organic matters, living organisms, fossils, air and water. Considering the diversity of soil contents, quality and usability, a systematic scientific study on the elemental and chemical composition of soil is very important. In order to study the chemical composition of soil, Laser induced breakdown spectroscopy (LIBS) has been applied recently. The important features of LIBS system and its applications for the measurement of nutrients in green house soil, on-line monitoring of remediation process of chromium polluted soil, determination of trace elements in volcanic erupted soil samples collected from ancient cenozoic lava eruption sites and detection of toxic metals in Gulf war oil spill contaminated soil using LIBS are described in this chapter.

Volcanic Plume Measurements with UAV (Invited)

NASA Astrophysics Data System (ADS)

Shinohara, H.; Kaneko, T.; Ohminato, T.

2013-12-01

Volatiles in magmas are the driving force of volcanic eruptions and quantification of volcanic gas flux and composition is important for the volcano monitoring. Recently we developed a portable gas sensor system (Multi-GAS) to quantify the volcanic gas composition by measuring volcanic plumes and obtained volcanic gas compositions of actively degassing volcanoes. As the Multi-GAS measures variation of volcanic gas component concentrations in the pumped air (volcanic plume), we need to bring the apparatus into the volcanic plume. Commonly the observer brings the apparatus to the summit crater by himself but such measurements are not possible under conditions of high risk of volcanic eruption or difficulty to approach the summit due to topography etc. In order to overcome these difficulties, volcanic plume measurements were performed by using manned and unmanned aerial vehicles. The volcanic plume measurements by manned aerial vehicles, however, are also not possible under high risk of eruption. The strict regulation against the modification of the aircraft, such as installing sampling pipes, also causes difficulty due to the high cost. Application of the UAVs for the volcanic plume measurements has a big advantage to avoid these problems. The Multi-GAS consists of IR-CO2 and H2O gas analyzer, SO2-H2O chemical sensors and H2 semiconductor sensor and the total weight ranges 3-6 kg including batteries. The necessary conditions of the UAV for the volcanic plumes measurements with the Multi-GAS are the payloads larger than 3 kg, maximum altitude larger than the plume height and installation of the sampling pipe without contamination of the exhaust gases, as the exhaust gases contain high concentrations of H2, SO2 and CO2. Up to now, three different types of UAVs were applied for the measurements; Kite-plane (Sky Remote) at Miyakejima operated by JMA, Unmanned airplane (Air Photo Service) at Shinomoedake, Kirishima volcano, and Unmanned helicopter (Yamaha) at Sakurajima

Nanoparticle amount, and not size, determines chain alignment and nonlinear hardening in polymer nanocomposites

PubMed Central

Varol, H. Samet; Meng, Fanlong; Hosseinkhani, Babak; Malm, Christian; Bonn, Daniel; Bonn, Mischa; Zaccone, Alessio

2017-01-01

Polymer nanocomposites—materials in which a polymer matrix is blended with nanoparticles (or fillers)—strengthen under sufficiently large strains. Such strain hardening is critical to their function, especially for materials that bear large cyclic loads such as car tires or bearing sealants. Although the reinforcement (i.e., the increase in the linear elasticity) by the addition of filler particles is phenomenologically understood, considerably less is known about strain hardening (the nonlinear elasticity). Here, we elucidate the molecular origin of strain hardening using uniaxial tensile loading, microspectroscopy of polymer chain alignment, and theory. The strain-hardening behavior and chain alignment are found to depend on the volume fraction, but not on the size of nanofillers. This contrasts with reinforcement, which depends on both volume fraction and size of nanofillers, potentially allowing linear and nonlinear elasticity of nanocomposites to be tuned independently. PMID:28377517

Developing a new, passive diffusion sampling array to detect helium anomalies associated with volcanic unrest

USGS Publications Warehouse

Dame, Brittany E; Solomon, D Kip; Evans, William C.; Ingebritsen, Steven E.

2015-01-01

Helium (He) concentration and 3 He/ 4 He anomalies in soil gas and spring water are potentially powerful tools for investigating hydrothermal circulation associated with volca- nism and could perhaps serve as part of a hazards warning system. However, in operational practice, He and other gases are often sampled only after volcanic unrest is detected by other means. A new passive diffusion sampler suite, intended to be collected after the onset of unrest, has been developed and tested as a relatively low-cost method of determining He- isotope composition pre- and post-unrest. The samplers, each with a distinct equilibration time, passively record He concen- tration and isotope ratio in springs and soil gas. Once collected and analyzed, the He concentrations in the samplers are used to deconvolve the time history of the He concentration and the 3 He/ 4 He ratio at the collection site. The current suite consisting of three samplers is sufficient to deconvolve both the magnitude and the timing of a step change in in situ con- centration if the suite is collected within 100 h of the change. The effects of temperature and prolonged deployment on the suite ’ s capability of recording He anomalies have also been evaluated. The suite has captured a significant 3 He/ 4 He soil gas anomaly at Horseshoe Lake near Mammoth Lakes, California. The passive diffusion sampler suite appears to be an accurate and affordable alternative for determining He anomalies associated with volcanic unrest.

Diffuse H_{2} emission: a useful geochemical tool to monitor the volcanic activity at El Hierro volcano system

NASA Astrophysics Data System (ADS)

Pérez, Nemesio M.; Melián, Gladys; González-Santana, Judit; Barrancos, José; Padilla, Germán; Rodríguez, Fátima; Padrón, Eleazar; Hernández, Pedro A.

2016-04-01

The occurrence of interfering processes affecting reactive gases as CO2 during its ascent from magmatic bodies or hydrothermal systems toward the surface environment hinders the interpretation of their enrichments in the soil atmosphere and fluxes for volcano monitoring purposes (Marini and Gambardella, 2005). These processes include gas scrubbing by ground-waters and interaction with rocks, decarbonatation processes, biogenic production, etc. Within the rest of the soil gases, particularly interest has been addressed to light and highly mobile gases. They offer important advantages for the detection of vertical permeability structures, because their interaction with the surrounding rocks or fluids during the ascent toward the surface is minimum. H2 is one of the most abundant trace species in volcano-hydrothermal systems and is a key participant in many redox reactions occurring in the hydrothermal reservoir gas (Giggenbach, 1987). Although H2 can be produced in soils by N2-fixing and fertilizing bacteria, soils are considered nowadays as sinks of molecular hydrogen (Smith-Downey et al., 2006). Because of its chemical and physical characteristics, H2 generated within the crust moves rapidly and escapes to the atmosphere. These characteristics make H2 one of the best geochemical indicators of magmatic and geothermal activity at depth. El Hierro is the youngest and the SW-most of the Canary Islands and the scenario of the last volcanic eruption of the archipelago, a submarine eruption that took place 2 km off the southern coast of the island from October 2011 to March 2012. Since at El Hierro Island there are not any surface geothermal manifestations (fumaroles, etc), we have focused our studies on soil degassing surveys. Here we show the results of soil H2 emission surveys that have been carried out regularly since mid-2012. Soil gas samples were collected in ˜600 sites selected based on their accessibility and geological criteria. Soil gases were sampled at ˜40

Mainshock-Aftershock Clustering in Volcanic Regions

NASA Astrophysics Data System (ADS)

Garza-Giron, Ricardo; Brodsky, Emily E.; Prejean, Stephanie G.

2018-02-01

Earthquakes break their general Poissonean behavior through two types of seismic bursts: swarms and mainshock-aftershock sequences. The former is commonly thought to dominate in volcanic and geothermal regions, but aftershock production, including within swarms, is not well studied in volcanic regions. Here we compare mainshock-aftershock clustering in active volcanic regions in Japan to nearby nonvolcanic regions. We find that aftershock production is similar in both areas by two separate metrics: (1) Both volcanic and nonvolcanic regions have similar proportions of areas that cluster into mainshock-aftershock sequences. (2) Volcanic areas with mainshock-aftershock sequences have aftershock productivity at least as high as nonvolcanic regions. We also find that volcano-tectonic events that are precursors to an eruption are more common at volcanoes without mainshock-aftershock clusters than at volcanoes with well-defined mainshock-aftershock clusters. This last finding hints at a strategy to identify volcanic systems where cataloged earthquakes are good predictors of behavior.

Volcanic processes in the Solar System

USGS Publications Warehouse

Carr, M.H.

1987-01-01

This article stresses that terrestrial volcanism represents only part of the range of volcanism in the solar system. Earth processes of volcanicity are dominated by plate tectonics, which does not seem to operate on other planets, except possibly on Venus. Lunar volcanicity is dominated by lava effusion at enormous rates. Mars is similar, with the addition to huge shield volcanoes developed over fixed hotspots. Io, the moon closest to Jupiter, is the most active body in the Solar System and, for example, much sulphur and silicates are emitted. The eruptions of Io are generated by heating caused by tides induced by Jupiter. Europa nearby seems to emit water from fractures and Ganymede is similar. The satellites of Saturn and Uranus are also marked by volcanic craters, but they are of very low temperature melts, possibly of ammonia and water. The volcanism of the solar system is generally more exotic, the greater the distance from Earth. -A.Scarth

Radiation hardening of rare-earth doped fiber amplifiers

NASA Astrophysics Data System (ADS)

Vivona, Marilena; Girard, Sylvain; Marcandella, Claude; Pinsard, Emmanuel; Laurent, Arnaud; Robin, Thierry; Cadier, Benoît; Cannas, Marco; Boukenter, Aziz; Ouerdane, Y.

2017-11-01

We investigated the radiation hardening of optical fiber amplifiers operating in space environments. Through a real-time analysis in active configuration, we evaluated the role of Ce in the improvement of the amplifier performance against ionizing radiations. Ce-codoping is an efficient hardening solution, acting both in the limitation of defects in the host glass matrix of RE-doped optical fibers and in the stabilization of lasing properties of the Er3+-ions. On the one hand, in the near-infrared region, radiation induced attenuation measurements show the absence of radiation induced P-related defect species in host glass matrix of the Ce-codoped active fibers; on the other hand, in the Ce-free fiber, the higher lifetime variation shows stronger local modifications around the Er3+-ions with the absence of Ce.

Multi-MGy Radiation Hardened Camera for Nuclear Facilities

DOE Office of Scientific and Technical Information (OSTI.GOV)

Girard, Sylvain; Boukenter, Aziz; Ouerdane, Youcef

There is an increasing interest in developing cameras for surveillance systems to monitor nuclear facilities or nuclear waste storages. Particularly, for today's and the next generation of nuclear facilities increasing safety requirements consecutive to Fukushima Daiichi's disaster have to be considered. For some applications, radiation tolerance needs to overcome doses in the MGy(SiO{sub 2}) range whereas the most tolerant commercial or prototypes products based on solid state image sensors withstand doses up to few kGy. The objective of this work is to present the radiation hardening strategy developed by our research groups to enhance the tolerance to ionizing radiations ofmore » the various subparts of these imaging systems by working simultaneously at the component and system design levels. Developing radiation-hardened camera implies to combine several radiation-hardening strategies. In our case, we decided not to use the simplest one, the shielding approach. This approach is efficient but limits the camera miniaturization and is not compatible with its future integration in remote-handling or robotic systems. Then, the hardening-by-component strategy appears mandatory to avoid the failure of one of the camera subparts at doses lower than the MGy. Concerning the image sensor itself, the used technology is a CMOS Image Sensor (CIS) designed by ISAE team with custom pixel designs used to mitigate the total ionizing dose (TID) effects that occur well below the MGy range in classical image sensors (e.g. Charge Coupled Devices (CCD), Charge Injection Devices (CID) and classical Active Pixel Sensors (APS)), such as the complete loss of functionality, the dark current increase and the gain drop. We'll present at the conference a comparative study between these radiation-hardened pixel radiation responses with respect to conventional ones, demonstrating the efficiency of the choices made. The targeted strategy to develop the complete radiation hard camera

Volcanism and the atmosphere: the potential role of the atmosphere in unlocking the reactivity of volcanic emissions.

PubMed

Mather, Tamsin A

2008-12-28

Recent measurements of reactive trace gas species in volcanic plumes have offered intriguing hints at the chemistry occurring in the hot environment at volcanic vents. This has led to the recognition that volcanic vents should be regarded not only as passive sources of volcanic gases to the atmosphere, but also as 'reaction vessels' that unlock otherwise inert volcanic and atmospheric gas species. The atypical conditions created by the mixing of ambient atmosphere with the hot gases emitted from magma give rise to elevated concentrations of otherwise unexpected chemical compounds. Rapid cooling of this mixture allows these species to persist into the environment, with important consequences for gas plume chemistry and impacts. This paper discusses some examples of the implications of these high-temperature interactions in terms of nitrogen, halogen and sulphur chemistry, and their consequences in terms of the global fixed nitrogen budget, volcanically induced ozone destruction and particle fluxes to the atmosphere. Volcanically initiated atmospheric chemistry was likely to have been particularly important before biological (and latterly anthropogenic) processes started to dominate many geochemical cycles, with important consequences in terms of the evolution of the nitrogen cycle and the role of particles in modulating the Earth's climate.

Hardened Solar Array High Temperature Adhesive.

DTIC Science & Technology

1981-04-01

SHERWOOO. D SASIU.IS F3361S-0-C-201S UNCLASSI ED 1AC-SCG-IOOIIR AFVAL-TR-OL-201? NLm,,hinii EhhhEE11I1 AFWAL-TR-81- 2017 i : HARDENED SOLAR ARRAY D HIGH...Tg and as a consequence forms a film on the container and also precipitates as tacky waxlike particles, rather than the desired flocullated

Geochemical and Isotopic Estimates of Eolian Dust in Soils of the San Juan Mountains, USA.

NASA Astrophysics Data System (ADS)

Lawrence, C. R.; Neff, J. C.; Farmer, L.; Painter, T. H.; Landry, C.

2007-12-01

Eolian dust deposition in the San Juan Mountain Range in southern Colorado has increased 5-7 fold in the past two centuries. This dust deposition contributes an exogenous supply of biologically relevant elements such as Ca, K, Mg, and P to these alpine ecosystems in the form of fine textured mineral particulates. The deposition of eolian dust may be an underestimated factor of soil formation and soil chemistry in these alpine settings. The importance of eolian dust relative to the weathering of local bedrock likely varies across bedrock types. The San Juan Range is geologically diverse with distinct regions of Meso-proterozic crystalline granites in the Weminuche Wilderness, Mesozoic sedimentary layers near Molas Pass in the San Juan National Forest, and Tertiary volcanic geology found on Red Mountain Pass in the Uncompahgre National Forest. Principle component analysis of element chemistry shows that bedrock and soils from these sites cluster by geology. In addition, these groups are chemically distinct from eolian dust collected from snow in the San Juan Range. Several elements seem to drive the difference of dust from soils and bedrock including Ca, Sr, Cu and Cd. The purpose of this research was to estimate the relative contribution of eolian dust to alpine soil element pools in the San Juan Mountains across a range of local geologic parent material. A calculation of element mass- balance shows that Cu and Cd are enriched in the surface soils of both volcanic and sedimentary soils relative to concentrations in local bedrock. However, Ca is enriched only in volcanic soils. These observations support the notion that eolian dust contributes to soil formation and that the relative contribution of dust across the landscape varies with geology. In addition to element mass-balance estimates we utilize Sr and Nd isotope measurements of soil, bedrock, and dust to further constrain the importance of eolian dust to these alpine soils.

On water in volcanic clouds

NASA Astrophysics Data System (ADS)

Durant, Adam J.

2007-12-01

Volcanic clouds and tephra fallout present a hazard to aviation, human and animal health (direct inhalation or ingestion, contamination of water supplies), and infrastructure (building collapse, burial of roads and railways, agriculture, abrasive and chemical effects on machinery). Understanding sedimentation processes is a fundamental component in the prediction of volcanic cloud lifetime and fallout at the ground, essential in the mitigation of these hazards. The majority of classical volcanic ash transport and dispersion models (VATDM) are based solely on fluid dynamics. The non-agreement between VATDM and observed regional-scale tephra deposit characteristics is especially obvious at large distances from the source volcano. In meteorology, the processes of hydrometeor nucleation, growth and collection have been long-established as playing a central role in sedimentation and precipitation. Taking this as motivation, the hypothesis that hydrometeor formation drives sedimentation from volcanic clouds was tested. The research objectives of this dissertation are: (1) To determine the effectiveness of tephra particles in the catalysis of the liquid water to ice phase transformation, with application to ice hydrometeor formation in volcanic clouds. (2) To determine the sedimentological characteristics of distal (100s km) tephra fallout from recent volcanic clouds. (3) To assess particle fallout rates from recent volcanic clouds in the context of observed deposit characteristics. (4) To assess the implications of hydrometeor formation on the enhancement of volcanic sedimentation and the potential for cloud destabilization from volcanic hydrometeor sublimation. Dissertation Overview. The following chapters present the analysis, results and conclusions of heterogeneous ice nucleation experiments and sedimentological characterization of several recent tephra deposits. The dissertation is organized in three chapters, each prepared in journal article format. In Chapter 1

Development of Press Hardening Steel with High Resistance to Hydrogen Embrittlement

NASA Astrophysics Data System (ADS)

Bian, Jian; Mohrbacher, Hardy; Lu, Hongzhou; Wang, Wenjun

Press hardening has become the state-of-art technology in the car body manufacturing to enhance safety standard and to reduce CO2 emission of new vehicles. However the delayed cracking due to hydrogen embrittlement remains to be a critical issue. Generally press hardening steel is susceptible to hydrogen embrittlement due to ultra-high strength and martensitic microstructure. The hydrogen charging tests clearly demonstrate that only a few ppm of diffusible hydrogen is sufficient to cause such embrittlement. Currently the hydrogen embrittlement cannot be detected in the press hardened components and the embitteled components could collapse in the crash situation with fatal consequences arisen through dramatic loss in both strength and ductility. This paper introduces a new metallurgical solution to increase the resistance to hydrogen embrittlement of conventional press hardening steel based on 22MnB5 by Nb microalloying. In the hydrogen embrittlement and permeation tests the impact of Nb microalloying on the hydrogen embrittlement behavior was investigated under different hydrogen charging conditions and constant load. The test results revealed that Nb addition increases the resistance to hydrogen embrittlement due to reduced hydrogen diffusivity. The focus of this paper is to investigate the precipitation behavior of microalloying elements by using TEM and STEM and to find out the mechanisms leading to higher performance against hydrogen embrittlement of Nb alloyed steels.

Influence of Microstructural and Load Wave Form Control on Fatigue Crack Growth behavior of Precipitation Hardening Stainless Steels

DTIC Science & Technology

1976-07-01

heating to temperatures below the Acl precipitates a copper -rich phase within the martensite increasing hardness and strength. The stress relieving effect...experimental approach varied the heat treatment of two precipitation hardening martensitic alloys , 17-4 PH1 and 15-b PH. Fatigue-crack growth data was...hardenable by precipitation hardening. Alloys that do harden by this mechanism have only one thing in common, this is, a decreasing solubility for one phase

Nitrogen nutrition and drought hardening exert opposite effects on the stress tolerance of Pinus pinea L. seedlings.

PubMed

Villar-Salvador, Pedro; Peñuelas, Juan L; Jacobs, Douglass F

2013-02-01

Functional attributes determine the survival and growth of planted seedlings in reforestation projects. Nitrogen (N) and water are important resources in the cultivation of forest species, which have a strong effect on plant functional traits. We analyzed the influence of N nutrition on drought acclimation of Pinus pinea L. seedlings. Specifically, we addressed if high N fertilization reduces drought and frost tolerance of seedlings and whether drought hardening reverses the effect of high N fertilization on stress tolerance. Seedlings were grown under two N fertilization regimes (6 and 100 mg N per plant) and subjected to three drought-hardening levels (well-watered, moderate and strong hardening). Water relations, gas exchange, frost damage, N concentration and growth at the end of the drought-hardening period, and survival and growth of seedlings under controlled xeric and mesic outplanting conditions were measured. Relative to low-N plants, high-N plants were larger, had higher stomatal conductance (27%), residual transpiration (11%) and new root growth capacity and closed stomata at higher water potential. However, high N fertilization also increased frost damage (24%) and decreased plasmalemma stability to dehydration (9%). Drought hardening reversed to a great extent the reduction in stress tolerance caused by high N fertilization as it decreased frost damage, stomatal conductance and residual transpiration by 21, 31 and 24%, respectively, and increased plasmalemma stability to dehydration (8%). Drought hardening increased tissue non-structural carbohydrates and N concentration, especially in high-fertilized plants. Frost damage was positively related to the stability of plasmalemma to dehydration (r = 0.92) and both traits were negatively related to the concentration of reducing soluble sugars. No differences existed between moderate and strong drought-hardening treatments. Neither N nutrition nor drought hardening had any clear effect on seedling

The active submarine NW termination of the South Aegean Active Volcanic Arc: The Submarine Pausanias Volcanic Field

NASA Astrophysics Data System (ADS)

Foutrakis, Panagiotis M.; Anastasakis, George

2018-05-01

Methana peninsula shows the longest recorded volcanic history at the western end of the South Aegean Active Volcanic Arc, including volcanic products from the Upper Pliocene to recent times. The volcanic rocks comprise widespread dacite domes and andesite lava flows from several small volcanic centers and are only imprecisely dated. In this paper, the integrated analysis of swath bathymetry, side scan sonar data, and high resolution seismic reflection profiles correlated with core samples, has allowed detailed mapping, characterization and precise chronological identification of the Pausanias submarine volcanic field activity offshore northern Methana. Six volcanic cones or domes are recognized, typically 1-3 km in diameter, some elongated NE-SW and some with a small central crater. On their flanks, the acoustically reflective volcanic rocks pass laterally into incoherent transparent seismic facies interpreted as volcaniclastic deposits, possibly including hyaloclastites, that interfinger with the regional basin sediments. A sea-bottom hummocky field, is interpreted as volcanic avalanche and appears to be the submarine continuation of the volcaniclastic apron of northern Methana peninsula. A robust chronostratigraphic framework has been established, based on the recognition of shoreline progradational units and their connection with Quaternary eustatic sea level cycles. Relative dating of the different phases of submarine volcanic activity during the Upper Quaternary has been achieved by correlating the imaged volcaniclastic flows, interlayered within the chronostratigraphically dated sediments. Dating by stratigraphic position, relative to 2D imaged eustatic sea level clinoform wedges appears to be more precise than radiometric methods on land. Three main submarine Volcanic Events (VE) are recognized: VE3 at 450 ka, a less precisely dated interval at 200-130 ka (VE2), and VE1 at 14 ka. Based on chronostratigraphic constraints, subsidence rates of 0.16 (±0.008) m

Reduction of metal artifacts: beam hardening and photon starvation effects

NASA Astrophysics Data System (ADS)

Yadava, Girijesh K.; Pal, Debashish; Hsieh, Jiang

2014-03-01

The presence of metal-artifacts in CT imaging can obscure relevant anatomy and interfere with disease diagnosis. The cause and occurrence of metal-artifacts are primarily due to beam hardening, scatter, partial volume and photon starvation; however, the contribution to the artifacts from each of them depends on the type of hardware. A comparison of CT images obtained with different metallic hardware in various applications, along with acquisition and reconstruction parameters, helps understand methods for reducing or overcoming such artifacts. In this work, a metal beam hardening correction (BHC) and a projection-completion based metal artifact reduction (MAR) algorithms were developed, and applied on phantom and clinical CT scans with various metallic implants. Stainless-steel and Titanium were used to model and correct for metal beam hardening effect. In the MAR algorithm, the corrupted projection samples are replaced by the combination of original projections and in-painted data obtained by forward projecting a prior image. The data included spine fixation screws, hip-implants, dental-filling, and body extremity fixations, covering range of clinically used metal implants. Comparison of BHC and MAR on different metallic implants was used to characterize dominant source of the artifacts, and conceivable methods to overcome those. Results of the study indicate that beam hardening could be a dominant source of artifact in many spine and extremity fixations, whereas dental and hip implants could be dominant source of photon starvation. The BHC algorithm could significantly improve image quality in CT scans with metallic screws, whereas MAR algorithm could alleviate artifacts in hip-implants and dentalfillings.

The role of mantle CO2 in volcanism

USGS Publications Warehouse

Barnes, I.; Evans, William C.; White, L.D.

1988-01-01

Carbon dioxide is the propellant gas in volcanic eruptions and is also found in mantle xenoliths. It is speculated that CO2 occurs as a free gas phase in the mantle because there is no reason to expect CO2 to be so universally associated with volcanic rocks unless the CO2 comes from the same source as the volcanic rocks and their xenoliths. If correct, the presence of a free gas in the mantle would lead to physical instability, with excess gas pressure providing the cause of both buoyancy of volcanic melts and seismicity in volcanic regions. Convection in the mantle and episodic volcanic eruptions are likely necessary consequences. This suggestion has considerable implications for those responsible for providing warnings of impending disasters resulting from volcanic eruptions and earthquakes in volcanic regions. ?? 1988.

Modeling and Analysis of Deformation for Spiral Bevel Gear in Die Quenching Based on the Hardenability Variation

NASA Astrophysics Data System (ADS)

Zhang, Yingtao; Wang, Gang; Shi, Wankai; Yang, Lin; Li, Zhichao

2017-07-01

Spiral bevel gears are widely used to transmit energy between intersecting axes. The strength and fatigue life of the gears are improved by carburizing and quenching. A die quenching process is used to control the deformation of the gear. The deformation is determined by the variations in the hardenability for a certain die quenching process. The relationship between hardenability, phase transformation and deformation needs to be studied to minimize deformation during the adjustment of the die quenching process parameters. In this paper, material properties for 22CrMoH steel are determined by the results of Jominy tests, dilatometry experiments and static mechanical property tests. The material models were built based on testing results under the consideration of hardenability variation. An finite element analysis model was developed to couple the phase transformation and deformation history of the complete carburizing and die quenching process for the spiral bevel gears. The final microstructures in the gear were bainite for low hardenability steel and a mixture of bainite and ferrite for high hardenability steel. The largest buckling deformation at the gear bottom surface is 0.375 mm at the outer circle for the low hardenability gear and 0.091 mm at the inner circle for the high hardenability gear.

A Review of NASA's Radiation-Hardened Electronics for Space Environments Project

NASA Technical Reports Server (NTRS)

Keys, Andrew S.; Adams, James H.; Patrick, Marshall C.; Johnson, Michael A.; Cressler, John D.

2008-01-01

NASA's Radiation Hardened Electronics for Space Exploration (RHESE) project develops the advanced technologies required to produce radiation hardened electronics, processors, and devices in support of the requirements of NASA's Constellation program. Over the past year, multiple advancements have been made within each of the RHESE technology development tasks that will facilitate the success of the Constellation program elements. This paper provides a brief review of these advancements, discusses their application to Constellation projects, and addresses the plans for the coming year.

Ice in Volcanic Clouds

NASA Astrophysics Data System (ADS)

Few, A. A.

2010-12-01

It is widely recognized that lightning activity in thunderstorm clouds is associated with ice in the clouds. In volcanic plumes the lower electrical discharges near the vent are clearly not associated with ice; however, the electrical discharges from the upper volcanic clouds very likely are associated with ice. There is ample water in volcanic plumes and clouds. The explosive volcanic eruption is produced by volatile components in the rising magma. Researchers estimate that the water content of the volatiles is up to 99% by mole; other gases are mainly sulfur and chlorine species. These volatiles carry with them a wide range of hot magma melts and solids, importantly silicate particles and tephra. The more massive components fall out near the vent carrying with them much of the heat from the plume; these large components are not in thermodynamic equilibrium with the gases, ash, and lapilli; thus the heat removed does not lower the temperature of the materials carried aloft in the plume. Upward motion is initially provided by the thrust from the volcanic eruption, then by buoyancy of the hot plume. The rising plume is cooled by entrainment of environmental air, which contains water, and by adiabatic expansion; the plume transitions into a volcanic cloud. Further lifting and cooling produces supercooled water droplets (T ~ -5 C) in a limited zone (z ~ 9 km) before the fast updraft (~ 60 m/s) rapidly transforms them into ice. Computer models of volcanic clouds that include water and ice microphysics indicate that the latent heat of condensation is not significant in cloud dynamics because it occurs in a region where buoyancy is provided by the original hot plume material. The latent heat of ice formation occurs at higher and colder levels and seems to contribute to the final lifting of the cloud top by ~1.5km. Laboratory results indicate that the fine silicate ash particles, which are abundant, are good ice nuclei, IN. Because of the abundance of the silicate ash

Long-term controls of soil organic carbon with depth and time: a case study from the Cowlitz River Chronosequence, WA USA

USGS Publications Warehouse

Lawrence, Corey R.; Harden, Jennifer W.; Xu, Xiaomei; Schulz, Marjorie S.; Trumbore, Susan E.

2015-01-01

Over timescales of soil development (millennia), the capacity of soils to stabilize soil organic carbon (SOC) is linked to soil development through changes in soil mineralogy and other soil properties. In this study, an extensive dataset of soil profile chemistry and mineralogy is compiled from the Cowlitz River Chronosequence (CRC), WA USA. The CRC soils range in age from 0.25 to 1200 kyr, spanning a developmental gradient encompassing clear changes in soil mineralogy, chemistry, and surface area. Comparison of these and other metrics of soil development with SOC properties reveal several relationships that may be diagnostic of the long-term coupling of soil development and C cycling. Specifically, SOC content was significantly correlated with sodium pyrophosphate extractable metals emphasizing the relevance of organo-metal complexes in volcanic soils. The depth distributions of organo-metals and other secondary weathering products, including the kaolin and short-range order (SRO) minerals, support the so-called “binary composition” of volcanic soils. The formation of organo-metal complexes limits the accumulation of secondary minerals in shallow soils, whereas in deep soils with lower SOC content, secondary minerals accumulate. In the CRC soils, secondary minerals formed in deep soils (below 50 cm) including smectite, allophane, Fe-oxides and dominated by the kaolin mineral halloysite. The abundance of halloysite was significantly correlated with bulk soil surface area and 14C content (a proxy for the mean age of SOC), implying enhanced stability of C in deep soils. Allophane, an SRO mineral commonly associated with SOC storage, was not correlated with SOC content or 14C values in CRC soils. We propose conceptual framework to describe these observations based on a general understanding of pedogenesis in volcanic soils, where SOC cycling is coupled with soil development through the formation of and fate of organo-metal or other mobile weathering products

Soil-plant-microbial relations in hydrothermally altered soils of Northern California

USGS Publications Warehouse

Blecker, S.W.; Stillings, L.L.; DeCrappeo, N.M.; Ippolito, J.A.

2014-01-01

Soils developed on relict hydrothermally altered soils throughout the Western USA present unique opportunities to study the role of geology on above and belowground biotic activity and composition. Soil and vegetation samples were taken at three unaltered andesite and three hydrothermally altered (acid-sulfate) sites located in and around Lassen VolcanicNational Park in northeastern California. In addition, three different types of disturbed areas (clearcut, thinned, and pipeline) were sampled in acid-sulfate altered sites. Soils were sampled (0–15 cm) in mid-summer 2010 from both under-canopy and between-canopy areas within each of the sites. Soils were analyzed for numerous physical and chemical properties along with soil enzyme assays, C and N mineralization potential, microbial biomass-C and C-substrate utilization. Field vegetation measurements consisted of canopy cover by life form (tree, shrub, forb, and grass), tree and shrub density, and above-ground net primary productivity of the understory. Overall, parameters at the clearcut sites were more similar to the unaltered sites, while parameters at the thinned and pipeline sites were more similar to the altered sites. We employed principal components analysis (PCA) to develop two soil quality indices (SQI) to help quantify the differences among the sites: one based on the correlation between soil parameters and canopy cover, and the second based on six sub-indices. Soil quality indices developed in these systems could provide a means for monitoring and identifying key relations between the vegetation, soils, and microorganisms.

MISR Observations of Etna Volcanic Plumes

NASA Technical Reports Server (NTRS)

Scollo, S.; Kahn, R. A.; Nelson, D. L.; Coltelli, M.; Diner, D. J.; Garay, M. J.; Realmuto, V. J.

2012-01-01

In the last twelve years, Mt. Etna, located in eastern Sicily, has produced a great number of explosive eruptions. Volcanic plumes have risen to several km above sea level and created problems for aviation and the communities living near the volcano. A reduction of hazards may be accomplished using remote sensing techniques to evaluate important features of volcanic plumes. Since 2000, the Multiangle Imaging SpectroRadiometer (MISR) on board NASA s Terra spacecraft has been extensively used to study aerosol dispersal and to extract the three-dimensional structure of plumes coming from anthropogenic or natural sources, including volcanoes. In the present work, MISR data from several explosive events occurring at Etna are analyzed using a program named MINX (MISR INteractive eXplorer). MINX uses stereo matching techniques to evaluate the height of the volcanic aerosol with a precision of a few hundred meters, and extracts aerosol properties from the MISR Standard products. We analyzed twenty volcanic plumes produced during the 2000, 2001, 2002-03, 2006 and 2008 Etna eruptions, finding that volcanic aerosol dispersal and column height obtained by this analysis is in good agreement with ground-based observations. MISR aerosol type retrievals: (1) clearly distinguish volcanic plumes that are sulphate and/or water vapor dominated from ash-dominated ones; (2) detect even low concentrations of volcanic ash in the atmosphere; (3) demonstrate that sulphate and/or water vapor dominated plumes consist of smaller-sized particles compared to ash plumes. This work highlights the potential of MISR to detect important volcanic plume characteristics that can be used to constrain the eruption source parameters in volcanic ash dispersion models. Further, the possibility of discriminating sulphate and/or water vapor dominated plumes from ash-dominated ones is important to better understand the atmospheric impact of these plumes.

Volcanism on Mars

NASA Astrophysics Data System (ADS)

Head, J. W.

1981-11-01

Characterization of volcanic activity on Mars is reviewed and comparisons are made with knowledge of terrestrial volcanic history. The high frequency of calderas on earth and low abundance on Mars is taken to indicate a lack of plate tectonic subduction zones and silicic volcanism on Mars. Further characterization is noted to depend on remote sensing from Viking orbital and earth-based spectral and albedo data. Theoretical models of causative mechanisms of terrestrial morphology will be used to establish models of similar processes on Mars, including deposits identification, eruptive conditions, and theories of magma ascent, as well as the role of volatiles from both deep and shallow sources. The importance of returning to Mars with appropriately instrumented spacecraft to test the new theories is stressed. The topics were discussed in papers presented at the Mars colloquium at the California Institute of Technology in August, 1981.

Surface hardening of Al alloys through controlled ball-milling and sintering.

PubMed

Kim, Seek Hyeoun; Kim, Yong Jin; Ahn, Jung-Ho

2012-07-01

One of the drawbacks of aluminum and its alloys is the lack of proper heat-treatment for surface-hardening. In the present work, a new and simple method of hardening the surface of aluminum and its alloys was developed. Low-energy ball-milling using specific process control agents (PCAs) was employed, using subsequent sintering in a controlled atmosphere. The PCAs in the present work were very effective both for milling and the formation of hard nanocrystalline dispersoids during sintering. The residual oxygen in a sintering atmosphere also played an important role in the formation of AIN or Al-O-N dispersoids. Through the proper control of the processing atmosphere and PCAs, the hardness and thickness of the hardened layers could be adjusted. The results of the wear test showed that the present aluminum alloys can be effectively utilized as light-weight components with a good wear resistance. Furthermore, the present method involves a simple forming process of die-compaction and sintering.

Quantitative Studies in Planetary Volcanism

NASA Technical Reports Server (NTRS)

Baloga, Stephen M.

2004-01-01

Proxemy Research has a research grant to perform scientific investigations of volcanism and volcanic-related process on other planets. Part of this research involves mathematical modeling of specific volcanic transport processes and the use of terrestrial analogs. This report contains a summary of activities conducted over the time period indicated. In addition, a synopsis of science research conducted during the period is given. A complete listing of publications and scientific abstracts that were presented at scientific conferences is contained in the report.

Using Lunar Regolith for Organics: Plant Growth Test Using Soil Analogues

NASA Astrophysics Data System (ADS)

Kołodziejczyk, A.; Vos, H. C.; Harasymczuk, M.; Kraiński, M.; Foing, B. H.

2017-05-01

Plant development depends on environmental factors such light, humidity and temperature, seed quality, contaminations, and soil type. We study the use of lunar regolith simulants from Eifel volcanic region on the growth of plants.

Chemistry and Mineralogy of Martian Soils from In-Situ Analyses

NASA Astrophysics Data System (ADS)

Yen, A. S.

2017-12-01

In-situ analyses of typical martian soils by the Spirit, Opportunity and Curiosity rovers have shown remarkable planet-scale similarities in composition. The Alpha Particle X-ray Spectrometer data indicate that fine-grained, basaltic soils analyzed at Gusev Crater, Meridiani Planum and Gale Crater are nearly identical when cross-calibration uncertainties between the individual instruments are considered. Martian soils generally exhibit correlated increases in S, Cl and Zn with finer grain sizes, balanced by decreasing Si and Al from the feldspar component. The trends in S, Cl and Zn are consistent with condensates of volcanic exhalations and indicate minimal aqueous alteration of the soil samples after the accumulation of the volcanic volatiles. The mineralogy established by the CheMin X-ray diffractometer on the Curiosity rover show that soils are dominated by plagioclase feldspar, pyroxenes, olivine, and amorphous material. Minor phases include hematite, magnetite and anhydrite. These results are consistent with the Mössbauer spectrometer data from Spirit and Opportunity which indicate that the iron is contained in olivine, pyroxene, hematite, magnetite, and a nanophase ferric iron oxide/hydroxide. With the exception of the nanophase/amorphous component, typical martian soils are fundamentally basaltic in nature and remain relatively unaltered. Variations from typical basaltic soils have also been observed: Local contributions to the soil are evident in a number of samples which contain characteristic chemical signatures of nearby rocks. Larger sand grains on surfaces of aeolian bedforms have distinct compositions consistent with greater proportions of olivine, and in some cases, magnetite. Extensively altered fine-grained deposits dominated by sulfates and silica at Gusev Crater are distinct from basaltic soils and are consistent with fumarolic origins.

Volcanic alert system (VAS) developed during the 2011-2014 El Hierro (Canary Islands) volcanic process

NASA Astrophysics Data System (ADS)

García, Alicia; Berrocoso, Manuel; Marrero, José M.; Fernández-Ros, Alberto; Prates, Gonçalo; De la Cruz-Reyna, Servando; Ortiz, Ramón

2014-06-01

The 2011 volcanic unrest at El Hierro Island illustrated the need for a Volcanic Alert System (VAS) specifically designed for the management of volcanic crises developing after long repose periods. The VAS comprises the monitoring network, the software tools for analysis of the monitoring parameters, the Volcanic Activity Level (VAL) management, and the assessment of hazard. The VAS presented here focuses on phenomena related to moderate eruptions, and on potentially destructive volcano-tectonic earthquakes and landslides. We introduce a set of new data analysis tools, aimed to detect data trend changes, as well as spurious signals related to instrumental failure. When data-trend changes and/or malfunctions are detected, a watchdog is triggered, issuing a watch-out warning (WOW) to the Monitoring Scientific Team (MST). The changes in data patterns are then translated by the MST into a VAL that is easy to use and understand by scientists, technicians, and decision-makers. Although the VAS was designed specifically for the unrest episodes at El Hierro, the methodologies may prove useful at other volcanic systems.

Lidar sounding of volcanic plumes

NASA Astrophysics Data System (ADS)

Fiorani, Luca; Aiuppa, Alessandro; Angelini, Federico; Borelli, Rodolfo; Del Franco, Mario; Murra, Daniele; Pistilli, Marco; Puiu, Adriana; Santoro, Simone

2013-10-01

Accurate knowledge of gas composition in volcanic plumes has high scientific and societal value. On the one hand, it gives information on the geophysical processes taking place inside volcanos; on the other hand, it provides alert on possible eruptions. For this reasons, it has been suggested to monitor volcanic plumes by lidar. In particular, one of the aims of the FP7 ERC project BRIDGE is the measurement of CO2 concentration in volcanic gases by differential absorption lidar. This is a very challenging task due to the harsh environment, the narrowness and weakness of the CO2 absorption lines and the difficulty to procure a suitable laser source. This paper, after a review on remote sensing of volcanic plumes, reports on the current progress of the lidar system.

Gas measurements from the Costa Rica-Nicaragua volcanic segment suggest possible along-arc variations in volcanic gas chemistry

NASA Astrophysics Data System (ADS)

Aiuppa, A.; Robidoux, P.; Tamburello, G.; Conde, V.; Galle, B.; Avard, G.; Bagnato, E.; De Moor, J. M.; Martínez, M.; Muñóz, A.

2014-12-01

Obtaining accurate estimates of the CO2 output from arc volcanism requires a precise understanding of the potential along-arc variations in volcanic gas chemistry, and ultimately of the magmatic gas signature of each individual arc segment. In an attempt to more fully constrain the magmatic gas signature of the Central America Volcanic Arc (CAVA), we present here the results of a volcanic gas survey performed during March and April 2013 at five degassing volcanoes within the Costa Rica-Nicaragua volcanic segment (CNVS). Observations of the volcanic gas plume made with a multicomponent gas analyzer system (Multi-GAS) have allowed characterization of the CO2/SO2-ratio signature of the plumes at Poás (0.30±0.06, mean ± SD), Rincón de la Vieja (27.0±15.3), and Turrialba (2.2±0.8) in Costa Rica, and at Telica (3.0±0.9) and San Cristóbal (4.2±1.3) in Nicaragua (all ratios on molar basis). By scaling these plume compositions to simultaneously measured SO2 fluxes, we estimate that the CO2 outputs at CNVS volcanoes range from low (25.5±11.0 tons/day at Poás) to moderate (918 to 1270 tons/day at Turrialba). These results add a new information to the still fragmentary volcanic CO2 output data set, and allow estimating the total CO2 output from the CNVS at 2835±1364 tons/day. Our novel results, with previously available information about gas emissions in Central America, are suggestive of distinct volcanic gas CO2/ST (= SO2 + H2S)-ratio signature for magmatic volatiles in Nicaragua (∼3) relative to Costa Rica (∼0.5-1.0). We also provide additional evidence for the earlier theory relating the CO2-richer signature of Nicaragua volcanism to increased contributions from slab-derived fluids, relative to more-MORB-like volcanism in Costa Rica. The sizeable along-arc variations in magmatic gas chemistry that the present study has suggested indicate that additional gas observations are urgently needed to more-precisely confine the volcanic CO2 from the CAVA, and from

Sediment transport dynamics in steep, tropical volcanic catchments

NASA Astrophysics Data System (ADS)

Birkel, Christian; Solano Rivera, Vanessa; Granados Bolaños, Sebastian; Brenes Cambronero, Liz; Sánchez Murillo, Ricardo; Geris, Josie

2017-04-01

significant volumes of material (> 100m3 per year) to the stream network, (ii) rainfall events that exceed a threshold of around 30mm/h rain intensity activate superficial flow pathways with associated mobilization of sediments (laminar erosion). However, the erosion processes are spatially very heterogeneous and mostly linked to finer material properties of the soils that mostly developed on more highly weathered bedrock. (iii) extreme events (return period > 50 years) mainly erode the streambed and banks cutting deeper into the bedrock and re-distribute massive amounts of material in the form of removed old alluvial deposits and new deposits created elsewhere, (iv) recovery after such extreme events in the form of fine material transport even during low intensity rainfall towards pre-event rainfall intensity thresholds takes only about two to three months. We conclude that the study catchment geomorphologically represents a low-resistance, but highly resilient catchment that quickly recovers after the impact of extreme rainfall-runoff events. The latter was indicated by a different pre and post-event hysteretic pattern of sediment-runoff dynamics and associated different material properties. The combined use of high-temporal resolution monitoring with spatially distributed surveys provided new insights into the fluvial geomorphology of steep, volcanic headwater catchments with potential to establish more complete sediment budgets and time-scales of land-forming processes of such highly dynamic environments in the humid tropics.

Volcanic Eruptions on Io

NASA Technical Reports Server (NTRS)

1979-01-01

This dramatic view of Jupiter's satellite Io shows two simultaneously occurring volcanic eruptions. One can be seen on the limb, (at lower right) in which ash clouds are rising more than 150 miles (260 kilometers) above the satellite's surface. The second can be seen on the terminator (shadow between day and night) where the volcanic cloud is catching the rays of the rising sun. The dark hemisphere of Io is made visible by light reflected from Jupiter. Seen in Io's night sky, Jupiter looms almost 40 times larger and 200 times brighter than our own full Moon. This photo was taken by Voyager 1 on March 8, 1979, looking back 2.6 million miles (4.5 million kilometers) at Io, three days after its historic encounter. This is the same image in which Linda A. Morabito, a JPL engineer, discovered the first extraterrestrial volcanic eruption (the bright curved volcanic cloud on the limb). Jet Propulsion Laboratory manages and controls the Voyager project for NASA's Office of Space Science.

Structural control of monogenetic volcanism in the Garrotxa volcanic field (Northeastern Spain) from gravity and self-potential measurements

NASA Astrophysics Data System (ADS)

Barde-Cabusson, S.; Gottsmann, J.; Martí, J.; Bolós, X.; Camacho, A. G.; Geyer, A.; Planagumà, Ll.; Ronchin, E.; Sánchez, A.

2014-01-01

We report new geophysical observations on the distribution of subsurface structures associated with monogenetic volcanism in the Garrotxa volcanic field (Northern Spain). As part of the Catalan Volcanic Zone, this Quaternary volcanic field is associated with the European rifts system. It contains the most recent and best preserved volcanic edifices of the Catalan Volcanic Zone with 38 monogenetic volcanoes identified in the Garrotxa Natural Park. We conducted new gravimetric and self-potential surveys to enhance our understanding of the relationship between the local geology and the spatial distribution of the monogenetic volcanoes. The main finding of this study is that the central part of the volcanic field is dominated by a broad negative Bouguer anomaly of around -0.5 mGal, within which a series of gravity minima are found with amplitudes of up to -2.3 mGal. Inverse modelling of the Bouguer data suggests that surficial low-density material dominates the volcanic field, most likely associated with effusive and explosive surface deposits. In contrast, an arcuate cluster of gravity minima to the NW of the Croscat volcano, the youngest volcano of this zone, is modelled by vertically extended low-density bodies, which we interpret as a complex ensemble of fault damage zones and the roots of young scoria cones. A ground-water infiltration zone identified by a self-potential anomaly is associated with a steep horizontal Bouguer gravity gradient and interpreted as a fault zone and/or magmatic fissure, which fed the most recent volcanic activity in the Garrotxa. Gravimetric and self-potential data are well correlated and indicate a control on the locations of scoria cones by NNE-SSW and NNW-SSE striking tectonic features, which intersect the main structural boundaries of the study area to the north and south. Our interpretation of the data is that faults facilitated magma ascent to the surface. Our findings have major implications for understanding the relationship

Numeric and Relative Luminescence Dating of Volcanic Eruptions in the West Eifel Volcanic Field, Germany

NASA Astrophysics Data System (ADS)

Schmidt, C.; Schaarschmidt, M.; Kolb, T.; Richter, D.; Zöller, L.

2016-12-01

Accurate and precise dating of Holocene and Late Pleistocene volcanic eruptions is important for hazard analysis but still poses a major challenge using existing methods such as the 40Ar/39Ar or 14C techniques. Although luminescence methods are principally suitable for dating the last heating event of quartz and feldspar, working with volcanogenic materials (e.g., basalt or basanite) encounters methodological difficulties, of which anomalous fading is the most serious one. Here, we report on luminescence ages of quartz and polymineral fine grains extracted from volcanically heated native rock in contact with lava and from xenoliths embedded in basanitic scoria from the West Eifel Volcanic Field (WEVF). Combined luminescence methods (red thermoluminescence, optically stimulated and post-infrared infrared stimulated luminescence) provide significantly refined age estimates for the two investigated eruption sites, compared to independent age control. While the last volcanic activity at the Wartgesberg cinder cones took place 33.6 ± 0.4 ka ago, the Facher Höhe scoria cone is substantially younger than previously assumed (15.5 ± 0.5 ka) and represents a formerly undetected phase of young volcanism. Although not appropriate for numeric dating, the luminescence sensitivity of basalt appears to increase with eruptional age. This observation could be employed as a tool to establish a relative eruption chronology of a particular volcanic area. The WEVF, featuring a comparatively homogenous MgO-rich lava composition with many dated eruptions, represents a favorable natural laboratory to test this approach. First results of this attempt to complete the Eifel volcanic record and to chronologically assess previously undated eruptions will be presented in this contribution.

Model Identification and FE Simulations: Effect of Different Yield Loci and Hardening Laws in Sheet Forming

NASA Astrophysics Data System (ADS)

Flores, P.; Duchêne, L.; Lelotte, T.; Bouffioux, C.; El Houdaigui, F.; Van Bael, A.; He, S.; Duflou, J.; Habraken, A. M.

2005-08-01

The bi-axial experimental equipment developed by Flores enables to perform Baushinger shear tests and successive or simultaneous simple shear tests and plane-strain tests. Such experiments and classical tensile tests investigate the material behavior in order to identify the yield locus and the hardening models. With tests performed on two steel grades, the methods applied to identify classical yield surfaces such as Hill or Hosford ones as well as isotropic Swift type hardening or kinematic Armstrong-Frederick hardening models are explained. Comparison with the Taylor-Bishop-Hill yield locus is also provided. The effect of both yield locus and hardening model choice will be presented for two applications: Single Point Incremental Forming (SPIF) and a cup deep drawing.

Volcanic ash in ancient Maya ceramics of the limestone lowlands: implications for prehistoric volcanic activity in the Guatemala highlands

NASA Astrophysics Data System (ADS)

Ford, Anabel; Rose, William I.

1995-07-01

In the spirit of collaborative research, Glicken and Ford embarked on the problem of identifying the source of volcanic ash used as temper in prehistoric Maya ceramics. Verification of the presence of glass shards and associated volcanic mineralogy in thin sections of Maya ceramics was straightforward and pointed to the Guatemala Highland volcanic chain. Considering seasonal wind rose patterns, target volcanoes include those from the area west of and including Guatemala City. Joint field research conducted in 1983 by Glicken and Ford in the limestone lowlands of Belize and neighboring Guatemala, 300 km north of the volcanic zone and 150 km from the nearest identified ash deposits, was unsuccessful in discovering local volcanic ash deposits. The abundance of the ash in common Maya ceramic vessels coupled with the difficulties of long-distance procurement without draft animals lead Glicken to suggest that ashfall into the lowlands would most parsimoniously explain prehistoric procurement; it literally dropped into their hands. A major archaeological problem with this explanation is that the use of volcanic ash occurring over several centuries of the Late Classic Period (ca. 600-900 AD). To accept the ashfall hypothesis for ancient Maya volcanic ash procurement, one would have to demonstrate a long span of consistent volcanic activity in the Guatemala Highlands for the last half of the first millennium AD. Should this be documented through careful petrographic, microprobe and tephrachronological studies, a number of related archaeological phenomena would be explained. In addition, the proposed model of volcanic activity has implications for understanding volcanism and potential volcanic hazards in Central America over a significantly longer time span than the historic period. These avenues are explored and a call for further collaborative research of this interdisciplinary problem is extended in this paper.

Evolution of radiation defect and radiation hardening in heat treated SA508 Gr3 steel

NASA Astrophysics Data System (ADS)

Jin, Hyung-Ha; Kwon, Junhyun; Shin, Chansun

2014-01-01

The formation of radiation defects and corresponding radiation hardening in heat-treated SA508 Gr3 steel after Fe ion irradiation were investigated by means of transmission electron microscopy and a nano-indentation technique. As the residual dislocation density is increased in the matrix, the formation of radiation defects is considerably weakened. Comparison between the characteristics of the radiation defect and an evaluation of radiation hardening indicates that a large dislocation loop contributes little to the radiation hardening in the heat-treated SA508 Gr3 steel.

Laboratory simulations of volcanic ash charging and conditions for volcanic lightning on Venus

NASA Astrophysics Data System (ADS)

Airey, Martin; Warriner-Bacon, Elliot; Aplin, Karen

2017-04-01

Lightning may be important in the emergence of life on Earth and elsewhere, as significant chemical reactions occur in the superheated region around the lightning channel. This, combined with the availability of phosphates in volcanic clouds, suggests that volcanic lightning could have been the catalyst for the formation of biological compounds on the early Earth [1]. In addition to meteorological lightning, volcanic activity also generates electrical discharges within charged ash plumes, which can be a significant contributor to atmospheric electricity on geologically active planets. The physical properties of other planetary atmospheres, such as that of Venus, have an effect on the processes that lead to the generation of volcanic lightning. Volcanism is known to have occurred on Venus in the past, and recent observations made by ESA's Venus Express satellite have provided evidence for currently active volcanism [2-4], and lightning discharges [e.g. 5]. Venusian lightning could potentially be volcanic in origin, since no meteorological mechanisms are known to separate charge effectively in its clouds [6]. The hunt for further evidence for lightning at Venus is ongoing, for example by means of the Lightning and Airglow Camera (LAC) [7] on Akatsuki, the current JAXA mission at Venus. Our laboratory experiments simulate ash generation and measure electrical charging of the ash under typical atmospheric conditions on Earth and Venus. The study uses a 1 litre chamber, which, when pressurised and heated, can simulate the high-pressure, high-temperature, carbon dioxide-dominated atmosphere of Venus at 10 km altitude ( 5 MPa, 650 K). A key finding of previous work [8] is that ash plume-forming eruptions are more likely to occur at higher altitudes such as these on Venus. The chamber contains temperature/pressure monitoring and logging equipment, a rock collision apparatus (based on [9]) to generate the charged rock fragments, and charge measurement electrodes connected

Basaltic ignimbrites in monogenetic volcanism: the example of La Garrotxa volcanic field

NASA Astrophysics Data System (ADS)

Martí, J.; Planagumà, L. l.; Geyer, A.; Aguirre-Díaz, G.; Pedrazzi, D.; Bolós, X.

2017-05-01

Ignimbrites are pyroclastic density current deposits common in explosive volcanism involving intermediate and silicic magmas and in less abundance in eruptions of basaltic central and shield volcanoes. However, they are not widely described in association with monogenetic volcanism, where typical products include lava flows, scoria and lapilli fall deposits, as well as various kinds of pyroclastic density current deposits and explosion breccias. In La Garrotxa basaltic monogenetic volcanic field, part of the Neogene-Quaternary European rift system located in the northeast of the Iberian Peninsula, we have identified a particular group of pyroclastic density current deposits that show similar textural characteristics to silicic ignimbrites, indicating an overlap in transport and depositional processes. These deposits can be clearly distinguished from other pyroclastic density current deposits generated during phreatomagmatic phases that typically correspond to thinly laminated units with planar-to-cross-bedded stratification. The monogenetic ignimbrite deposits correspond to a few meters to several tens of meters thick units rich in lithic- and lapilli scoria fragments, with an abundant ash matrix, and internally massive structure, emplaced along valleys and gullies, with run-out distances up to 6 km and individual volumes ranging from 106 to 1.5 × 107 m3. The presence of flattened scoria and columnar jointing in some of these deposits suggests relatively high emplacement temperatures, coinciding with available paleomagnetic data that suggests an emplacement temperature around 450-500 °C. In this work, we describe the main characteristics of these pyroclastic deposits that were generated by a number of phreatomagmatic episodes. Comparison with similar deposits from silicic eruptions and previous examples of ignimbrites associated with basaltic volcanism allows us to classify them as `basaltic ignimbrites'. The recognition in monogenetic volcanism of such

Short-lived and discontinuous intraplate volcanism in the South Pacific: Hot spots or extensional volcanism?

NASA Astrophysics Data System (ADS)

Koppers, Anthony A. P.; Staudigel, Hubert; Pringle, Malcolm S.; Wijbrans, Jan R.

2003-10-01

South Pacific intraplate volcanoes have been active since the Early Cretaceous. Their HIMU-EMI-EMII mantle sources can be traced back into the West Pacific Seamount Province (WPSP) using plate tectonic reconstructions, implying that these distinctive components are enduring features within the Earth's mantle for, at least, the last 120 Myr. These correlations are eminent on the scale of the WPSP and the South Pacific Thermal and Isotopic Anomaly (SOPITA), but the evolution of single hot spots emerges notably more complicated. Hot spots in the WPSP and SOPITA mantle regions typically display intermittent volcanic activity, longevities shorter than 40 Myr, superposition of hot spot volcanism, and motion relative to other hot spots. In this review, we use 40Ar/39Ar seamount ages and Sr-Nd-Pb isotopic signatures to map out Cretaceous volcanism in the WPSP and to characterize its evolution with respect to the currently active hot spots in the SOPITA region. Our plate tectonic reconstructions indicate cessation of volcanism during the Cretaceous for the Typhoon and Japanese hot spots; whereas the currently active Samoan, Society, Pitcairn and Marquesas hot spots lack long-lived counterparts in the WPSP. These hot spots may have become active during the last 20 Myr only. The other WPSP seamount trails can be only "indirectly" reconciled with hot spots in the SOPITA region. Complex age distributions in the Magellan, Anewetak, Ralik and Ratak seamount trails would necessitate the superposition of multiple volcanic trails generated by the Macdonald, Rurutu and Rarotonga hot spots during the Cretaceous; whereas HIMU-type seamounts in the Southern Wake seamount trail would require 350-500 km of hot spot motion over the last 100 Myr following its origination along the Mangaia-Rurutu "hotline" in the Cook-Austral Islands. These observations, however, violate all assumptions of the classical Wilson-Morgan hot spot hypothesis, indicating that long-lived, deep and fixed mantle

Lung problems and volcanic smog

MedlinePlus

... Saunders; 2016:chap 74. Feldman JN, Tilling RI. Volcanic eruptions, hazards, and mitigations. In: Auerbach PS, ed. Wilderness ... 2011:chap 15. Jay G, King K, Cattamanchi S. Volcanic eruptions. In: Cittione GR, ed. Ciottone's Disaster Medicine . 2nd ...

Seismo-volcanic monitoring at Furnas Volcano (Azores): radon (222Rn) concentration in groundwater

NASA Astrophysics Data System (ADS)

Silva, Catarina; Virgílio Cruz, José; Ferreira, Teresa; Viveiros, Fátima; Freire, Pedro; Allard, Patrick

2017-04-01

The Azores archipelago, located in the middle of the North Atlantic Ocean, is composed of nine volcanic islands that formed at the triple junction of the North American, Eurasian and African (Nubian) tectonic plates. These volcanic islands were the sites of several eruptions and destructive earthquakes since human settlement in the 15th century. S. Miguel Island, the largest and most densely populated island of the Azores, hosts three active strato-volcanoes with calderas. Furnas Volcano is one of these. Its eruptive activity has been essentially explosive, involving magmas with trachytic (s.l.) composition. In the last 5000 years at least 10 explosive eruptions occurred inside the caldera of Furnas. The last one occurred in 1630 and was subplinian in character. Since then an intense hydrothermal activity has persisted, involving four main fumarolic fields, thermal springs, CO2-rich springs, several soil diffuse degassing areas (CO2 and 222Rn), as well as occasional hydrothermal explosions. In the past decade we have developed a radon survey of Furnas hydrothermal manifestations. Here we report on the radon survey of twelve water springs, located inside the caldera, and representative of the different water types encountered at the volcano (orthothermal, thermal and CO2-rich springs). Bimonthly sampling and determination of radon activity and water temperature was performed in the selected springs between years 2007 and 2011. At each sampling point two water samples were collected for radon dosing in laboratory with the RAD7 equipment. A decay correction was applied to each sample. The average radon activities were found to vary between 1.15 Bq/L and 29.77 Bq/L, while water temperatures ranged between 16.5 °C and 76.2 °C. As a whole radon activities inversely correlate with water temperature, with orthothermal springs showing higher radon activity than thermal springs. Temporal variations in both parameters appear to be mainly determined by seasonal variations of

Influences of Sedimentary Environments and Volcanic Sources on Diagenetic Alteration of Volcanic Tuffs in South China.

PubMed

Gong, Nina; Hong, Hanlie; Huff, Warren D; Fang, Qian; Bae, Christopher J; Wang, Chaowen; Yin, Ke; Chen, Shuling

2018-05-16

Permian-Triassic (P-Tr) altered volcanic ashes (tuffs) are widely distributed within the P-Tr boundary successions in South China. Volcanic altered ashes from terrestrial section-Chahe (CH) and marine section-Shangsi (SS) are selected to further understand the influence of sedimentary environments and volcanic sources on diagenetic alterarion on volcanic tuffs. The zircon 206 Pb/ 238 U ages of the corresponding beds between two sections are almost synchronous. Sedimentary environment of the altered tuffs was characterized by a low pH and did not experience a hydrothermal process. The dominant clay minerals of all the tuff beds are illite-smectite (I-S) minerals, with minor chlorite and kaolinite. I-S minerals of CH (R3) are more ordered than SS (R1), suggesting that CH also shows a higher diagenetic grade and more intensive chemical weathering. Besides, the nature of the volcanism of the tuff beds studied is derived from different magma sources. The clay mineral compositions of tuffs have little relation with the types of source volcanism and the depositional environments. Instead, the degree of the mixed-layer clay minerals and the REE distribution are mainly dependent upon the sedimentary environments. Thus, the mixed-layer clay minerals ratio and their geochemical index can be used as the paleoenvironmental indicator.

Modelling ground deformation patterns associated with volcanic processes at the Okataina Volcanic Centre

NASA Astrophysics Data System (ADS)

Holden, L.; Cas, R.; Fournier, N.; Ailleres, L.

2017-09-01

The Okataina Volcanic Centre (OVC) is one of two large active rhyolite centres in the modern Taupo Volcanic Zone (TVZ) in the North Island of New Zealand. It is located in a complex section of the Taupo rift, a tectonically active section of the TVZ. The most recent volcanic unrest at the OVC includes the 1315 CE Kaharoa and 1886 Tarawera eruptions. Current monitoring activity at the OVC includes the use of continuous GPS receivers (cGPS), lake levelling and seismographs. The ground deformation patterns preceding volcanic activity the OVC are poorly constrained and restricted to predictions from basic modelling and comparison to other volcanoes worldwide. A better understanding of the deformation patterns preceding renewed volcanic activity is essential to determine if observed deformation is related to volcanic, tectonic or hydrothermal processes. Such an understanding also means that the ability of the present day cGPS network to detect these deformation patterns can also be assessed. The research presented here uses the finite element (FE) modelling technique to investigate ground deformation patterns associated with magma accumulation and diking processes at the OVC in greater detail. A number of FE models are produced and tested using Pylith software and incorporate characteristics of the 1315 CE Kaharoa and 1886 Tarawera eruptions, summarised from the existing body of research literature. The influence of a simple ring fault structure at the OVC on the modelled deformation is evaluated. The ability of the present-day continuous GPS (cGPS) GeoNet monitoring network to detect or observe the modelled deformation is also considered. The results show the modelled horizontal and vertical displacement fields have a number of key features, which include prominent lobe based regions extending northwest and southeast of the OVC. The results also show that the ring fault structure increases the magnitude of the displacements inside the caldera, in particular in the

Understanding Volcanic Conduit Dynamics: from Experimental Fragmentation to Volcanic Eruptions

NASA Astrophysics Data System (ADS)

Arciniega-Ceballos, A.; Alatorre-Ibarguengoitia, M. A.; Scheu, B.; Dingwell, D. B.

2011-12-01

The investigation of conduit dynamics at high pressure, under controlled laboratory conditions is a powerful tool to understand the physics behind volcanic processes before an eruption. In this work, we analyze the characteristics of the seismic response of an "experimental volcano" focusing on the dynamics of the conduit behavior during the fragmentation process of volcanic rocks. The "experimental volcano" is represented by a shock tube apparatus, which consists of a low-pressure voluminous tank (3 x 0.40 m), for sample recovery; and a high-pressure pipe-like conduit (16.5 x 2,5 cm), which represents the volcanic source mechanism, where rock samples are pressurized and fragmented. These two serial steel pipes are connected and sealed by a set of diaphragms that bear pressures in a range of 4 to 20 MPa. The history of the overall process of an explosion consists of four steps: 1) the slow pressurization of the pipe-like conduit filled with solid pumice and gas, 2) the sudden removal of the diaphragms, 3) the rapid decompression of the system and 4) the ejection of the gas-particle mixture. Each step imprints distinctive features on the microseismic records, reflecting the conduit dynamics during the explosion. In this work we show how features such as waveform characteristics, the three components of the force system acting on the conduit, the independent components of the moment tensor, the volumetric change of the source mechanism, the arrival time of the shock wave and its velocity, are quantified from the experimental microseismic data. Knowing these features, each step of the eruptive process, the conduit conditions and the source mechanism characteristics can be determined. The procedure applied in this experimental approach allows the use of seismic field data to estimate volcanic conduit conditions before an eruption takes place. We state on the hypothesis that the physics behind the pressurization and depressurization process of any conduit is the same

Stress corrosion cracking evaluation of precipitation-hardening stainless steel

NASA Technical Reports Server (NTRS)

Humphries, T. S.; Nelson, E. E.

1970-01-01

Accelerated test program results show which precipitation hardening stainless steels are resistant to stress corrosion cracking. In certain cases stress corrosion susceptibility was found to be associated with the process procedure.

Active Volcanic Plumes on Io

NASA Image and Video Library

1998-03-26

This color image, acquired during NASA Galileo ninth orbit around Jupiter, shows two volcanic plumes on Io. One plume was captured on the bright limb or edge of the moon, erupting over a caldera volcanic depression named Pillan Patera.

Diffuse CO2 degassing monitoring for the volcanic surveillance of Tenerife North-East Rift Zone (NERZ) volcano, Canary Islands

NASA Astrophysics Data System (ADS)

Rodríguez, F.; Thomas, G. E.; Wong, T.; García, E.; Melián, G.; Padron, E.; Asensio-Ramos, M.; Hernández, P. A.; Perez, N. M.

2017-12-01

The North East Rift zone of Tenerife Island (NERZ, 210 km2) is one of the three major volcanic rift-zones of the island. The most recent eruptive activity along the NERZ took place in the 1704-1705 period with eruptions of Siete Fuentes, Fasnia and Arafo volcanoes. Since fumarolic activity is nowadays absent at the NERZ, soil CO2 degassing monitoring represent a potential geochemical tool for its volcanic surveillance. The aim of this study is to report the results of the last CO2 efflux survey performed in June 2017, with 658 sampling sites. In-situ measurements of CO2 efflux from the surface environment of the NERZ were performed by means of a portable non-dispersive infrared spectrophotometer (NDIR) following the accumulation chamber method. To quantify the total CO2 emission, soil CO2 efflux spatial distribution maps were constructed using Sequential Gaussian Simulation (SGS) as interpolation method. The diffuse CO2 emission values ranged between 0 - 41.1 g m-2 d-1. The probability plot technique applied to the data allowed to distinguish two different geochemical populations; background (B) and peak (P) represented by 81.8% and 18.2% of the total data, respectively, with geometric means of 3.9 and 15.0 g m-2 d-1, respectively. The average map constructed with 100 equiprobable simulations showed an emission rate of 1,361±35 t d-1. This value relatively higher than the background average of CO2 emission estimated on 415 t d-1 and slightly higher than the background range of 148 t d-1 (-1σ) and 1,189 t d-1 (+1σ) observed at the NERZ. This study reinforces the importance of performing soil CO2 efflux surveys as an effective surveillance volcanic tool in the NERZ.

Speciation analysis of antimony in extracts of size-classified volcanic ash by HPLC-ICP-MS.

PubMed

Miravet, R; López-Sánchez, J F; Rubio, R; Smichowski, P; Polla, G

2007-03-01

Although there is concern about the presence of toxic elements and their species in environmental matrices, for example water, sediment, and soil, speciation analysis of volcanic ash has received little attention. Antimony, in particular, an emerging element of environmental concern, has been less studied than other potentially toxic trace elements. In this context, a study was undertaken to assess the presence of inorganic Sb species in ash emitted from the Copahue volcano (Argentina). Antimony species were extracted from size-classified volcanic ash (<36 microm, 35-45 microm, 45-150 microm, and 150-300 microm) by use of 1 mol L(-1) citrate buffer at pH 5. Antimony(III) and (V) in the extracts were separated and quantified by high-performance liquid chromatography combined on-line with inductively coupled plasma mass spectrometry (HPLC-ICP-MS). Antimony species concentrations (microg g(-1)) in the four fractions varied from 0.14 to 0.67 for Sb(III) and from 0.02 to 0.03 for Sb(V). The results reveal, for the first time, the occurrence of both inorganic Sb species in the extractable portion of volcanic ash. Sb(III) was always the predominant species.

Geology and geochemistry of volcanic centers within the eastern half of the Sonoma volcanic field, northern San Francisco Bay region, California

USGS Publications Warehouse

Sweetkind, Donald S.; Rytuba, James J.; Langenheim, V.E.; Fleck, Robert J.

2011-01-01

The volcanic fields in the California Coast Ranges north of San Francisco Bay are temporally and spatially associated with the northward migration of the Mendocino triple junction and the transition from subduction and associated arc volcanism to a slab window tectonic environment. Our geochemical analyses from the Sonoma volcanic field highlight the geochemical diversity of these volcanic rocks, allowing us to clearly distinguish these volcanic rocks from those of the roughly coeval ancestral Cascades magmatic arc to the west, and also to compare rocks of the Sonoma volcanic field to rocks from other slab window settings.

Fractography of induction-hardened steel fractured in fatigue and overload

DOE Office of Scientific and Technical Information (OSTI.GOV)

Santos, C.G.; Laird, C.

1997-07-01

The fracture surfaces of induction-hardened steel specimens obtained from an auto axle were characterized, macroscopically and microscopically, after being fractured in fatigue and monotonic overload. Specimens were tested in cyclic three-point bending under load control, and the S-N curve was established for specimens that had been notched by spark machining to facilitate fractography. Scanning electron microscopy of the fractured surfaces obtained for lives spanning the range 17,000 to 418,000 cycles revealed diverse fracture morphologies, including intergranular fracture and transgranular fatigue fracture. The results are being offered to assist in the analysis of complex field failures in strongly hardened steel.

Radiation hardening of components and systems for nuclear rocket vehicle applications

NASA Technical Reports Server (NTRS)

Greenhow, W. A.; Cheever, P. R.

1972-01-01

The results of the analysis of the S-2 and S-4B components, although incomplete, indicate that many Saturn 5 components and subsystems, e.g., pumps, valves, etc., can be radiation hardened to meet NRV requirements by material substitution and minor design modifications. Results of these analyses include (1) recommended radiation tolerance limits for over 100 material applications; (2) design data which describes the components of each system; (3) presentation of radiation hardening examples of systems; and (4) designing radiation effects tests to supply data for selecting materials.

Lunar volcanism in space and time

DOE Office of Scientific and Technical Information (OSTI.GOV)

Head, J.W. III

1976-05-01

Data obtained from lunar orbit and earth-based observations were used to extend the detailed characterizations derived from Apollo and Luna sample return missions to other parts of the moon. Lunar mare and highland volcanism are described including the distribution, volcanic features, the relation of mare morphologic features to the style of volcanic eruption, the characteristics and ages of other mare deposits, and sample results. (JFP)

Age hardening of 6061/alumina-silica fiber composite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Khangaonkar, P.R.; Shamsul, J.B.; Azmi, R.

1994-12-31

Continuous alumina-silica fiber (Altex of Sumitomo) which yields high performance composites with some aluminium alloys was tried for squeeze cast 6061 based composites with volume fractions of 0.5 and 0.32, and the matrix microhardness and resistivity changes during age hardening were studied. The matrix in the composites hardened much more than the unreinforced alloy. Microhardness increases of up to 70 VPN above the solution treated condition at various aging temperatures were observed. The resistivity variation indicated an appreciable state of internal stress which continued to persist even when hardness fell by overaging. Energy dispersive X-ray analysis indicated that the regionsmore » close to the fibers had a higher silicon content than the matrix, and amorphous silica in the fiber may have a role in the formation of an enriched layer which may help the bonding and strength in the composite.« less

The Boring Volcanic Field of the Portland-Vancouver area, Oregon and Washington: tectonically anomalous forearc volcanism in an urban setting

USGS Publications Warehouse

Evarts, Russell C.; Conrey, Richard M.; Fleck, Robert J.; Hagstrum, Jonathan T.; O'Connor, Jim; Dorsey, Rebecca; Madin, Ian P.

2009-01-01

More than 80 small volcanoes are scattered throughout the Portland-Vancouver metropolitan area of northwestern Oregon and southwestern Washington. These volcanoes constitute the Boring Volcanic Field, which is centered in the Neogene Portland Basin and merges to the east with coeval volcanic centers of the High Cascade volcanic arc. Although the character of volcanic activity is typical of many monogenetic volcanic fields, its tectonic setting is not, being located in the forearc of the Cascadia subduction system well trenchward of the volcanic-arc axis. The history and petrology of this anomalous volcanic field have been elucidated by a comprehensive program of geologic mapping, geochemistry, 40Ar/39Ar geochronology, and paleomag-netic studies. Volcanism began at 2.6 Ma with eruption of low-K tholeiite and related lavas in the southern part of the Portland Basin. At 1.6 Ma, following a hiatus of ~0.8 m.y., similar lavas erupted a few kilometers to the north, after which volcanism became widely dispersed, compositionally variable, and more or less continuous, with an average recurrence interval of 15,000 yr. The youngest centers, 50–130 ka, are found in the northern part of the field. Boring centers are generally monogenetic and mafic but a few larger edifices, ranging from basalt to low-SiO2 andesite, were also constructed. Low-K to high-K calc-alkaline compositions similar to those of the nearby volcanic arc dominate the field, but many centers erupted magmas that exhibit little influence of fluids derived from the subducting slab. The timing and compositional characteristics of Boring volcanism suggest a genetic relationship with late Neogene intra-arc rifting.

A Soil Service Index: Potential Soil Services to Society under Scenarios of Human Land Use and Population Growth

NASA Astrophysics Data System (ADS)

Hugelius, G.; Ahlström, A.; Loisel, J.; Harden, J. W.

2017-12-01

Soils provide numerous and indispensable services to ecological systems and human societies. As human populations and human land use changes, the capacity of soils to maintain these services may also change. To investigate this we provide the first global scale study based on the soil service index (SSI; see presentations by Harden et al. and Loisel et al. in this session for more details). In this index multiple soil services are numerically or quantitatively assessed, normalized to a unit-less scale for purposes of intercomparability. Soil services assessed under the SSI include organic matter and/or organic carbon storage; plant productivity; CO2 or GHG exchange with the atmosphere; water storage capacity; and nutrient storage and/or availability. The SSI may be applied at any scale. Here we present a first global application of the SSI and provide broad-scale analyses of soil service spatial distributions. We assess how the SSI will change under projected changes in human societies populations and human land use (following representative concentration pathway scenarios). Present and future potential utilization and vulnerability of soil resources are analyzed in the context of human population distributions and its projected changes. The SSI is designed to be broadly useful across scientific, governance and resource management organizations. To exemplify this, the parameterization of this is global soil service estimate is based on only open source input data.

Volcanism and associated hazards: the Andean perspective

NASA Astrophysics Data System (ADS)

Tilling, R. I.

2009-12-01

Andean volcanism occurs within the Andean Volcanic Arc (AVA), which is the product of subduction of the Nazca Plate and Antarctica Plates beneath the South America Plate. The AVA is Earth's longest but discontinuous continental-margin volcanic arc, which consists of four distinct segments: Northern Volcanic Zone, Central Volcanic Zone, Southern Volcanic Zone, and Austral Volcanic Zone. These segments are separated by volcanically inactive gaps that are inferred to indicate regions where the dips of the subducting plates are too shallow to favor the magma generation needed to sustain volcanism. The Andes host more volcanoes that have been active during the Holocene (past 10 000 years) than any other volcanic region in the world, as well as giant caldera systems that have produced 6 of the 47 largest explosive eruptions (so-called "super eruptions") recognized worldwide that have occurred from the Ordovician to the Pleistocene. The Andean region's most powerful historical explosive eruption occurred in 1600 at Huaynaputina Volcano (Peru). The impacts of this event, whose eruptive volume exceeded 11 km3, were widespread, with distal ashfall reported at distances >1000 km away. Despite the huge size of the Huaynaputina eruption, human fatalities from hazardous processes (pyroclastic flows, ashfalls, volcanogenic earthquakes, and lahars) were comparatively small owing to the low population density at the time. In contrast, lahars generated by a much smaller eruption (<0.05 km3) in 1985 of Nevado del Ruiz (Colombia) killed about 25 000 people - the worst volcanic disaster in the Andean region as well as the second worst in the world in the 20th century. The Ruiz tragedy has been attributed largely to ineffective communications of hazards information and indecisiveness by government officials, rather than any major deficiencies in scientific data. Ruiz's disastrous outcome, however, together with responses to subsequent hazardous eruptions in Chile, Colombia, Ecuador, and

Volcanic rock properties control sector collapse events

NASA Astrophysics Data System (ADS)

Hughes, Amy; Kendrick, Jackie; Lavallée, Yan; Hornby, Adrian; Di Toro, Giulio

2017-04-01

Volcanoes constructed by superimposed layers of varying volcanic materials are inherently unstable structures. The heterogeneity of weak and strong layers consisting of ash, tephra and lavas, each with varying coherencies, porosities, crystallinities, glass content and ultimately, strength, can promote volcanic flank and sector collapses. These volcanoes often exist in areas with complex regional tectonics adding to instability caused by heterogeneity, flank overburden, magma movement and emplacement in addition to hydrothermal alteration and anomalous geothermal gradients. Recent studies conducted on the faulting properties of volcanic rocks at variable slip rates show the rate-weakening dependence of the friction coefficients (up to 90% reduction)[1], caused by a wide range of factors such as the generation of gouge and frictional melt lubrication [2]. Experimental data from experiments conducted on volcanic products suggests that frictional melt occurs at slip rates similar to those of plug flow in volcanic conduits [1] and the bases of mass material movements such as debris avalanches from volcanic flanks [3]. In volcanic rock, the generation of frictional heat may prompt the remobilisation of interstitial glass below melting temperatures due to passing of the glass transition temperature at ˜650-750 ˚C [4]. In addition, the crushing of pores in high porosity samples can lead to increased comminution and strain localisation along slip surfaces. Here we present the results of friction tests on both high density, glass rich samples from Santaguito (Guatemala) and synthetic glass samples with varying porosities (0-25%) to better understand frictional properties underlying volcanic collapse events. 1. Kendrick, J.E., et al., Extreme frictional processes in the volcanic conduit of Mount St. Helens (USA) during the 2004-2008 eruption. J. Structural Geology, 2012. 2. Di Toro, G., et al., Fault lubrication during earthquakes. Nature, 2011. 471(7339): p. 494-498. 3

Volcanism and associated hazards: The Andean perspective

USGS Publications Warehouse

Tilling, R.I.

2009-01-01

Andean volcanism occurs within the Andean Volcanic Arc (AVA), which is the product of subduction of the Nazca Plate and Antarctica Plates beneath the South America Plate. The AVA is Earth's longest but discontinuous continental-margin volcanic arc, which consists of four distinct segments: Northern Volcanic Zone, Central Volcanic Zone, Southern Volcanic Zone, and Austral Volcanic Zone. These segments are separated by volcanically inactive gaps that are inferred to indicate regions where the dips of the subducting plates are too shallow to favor the magma generation needed to sustain volcanism. The Andes host more volcanoes that have been active during the Holocene (past 10 000 years) than any other volcanic region in the world, as well as giant caldera systems that have produced 6 of the 47 largest explosive eruptions (so-called "super eruptions") recognized worldwide that have occurred from the Ordovician to the Pleistocene.

The Andean region's most powerful historical explosive eruption occurred in 1600 at Huaynaputina Volcano (Peru). The impacts of this event, whose eruptive volume exceeded 11 km3, were widespread, with distal ashfall reported at distances >1000 km away. Despite the huge size of the Huaynaputina eruption, human fatalities from hazardous processes (pyroclastic flows, ashfalls, volcanogenic earthquakes, and lahars) were comparatively small owing to the low population density at the time. In contrast, lahars generated by a much smaller eruption (<0.05 km 3) in 1985 of Nevado del Ruiz (Colombia) killed about 25 000 people - the worst volcanic disaster in the Andean region as well as the second worst in the world in the 20th century. The Ruiz tragedy has been attributed largely to ineffective communications of hazards information and indecisiveness by government officials, rather than any major deficiencies in scientific data. Ruiz's disastrous outcome, however, together with responses to subsequent hazardous eruptions in Chile, Colombia

Ammonia-limited conditions cause of Thaumarchaeal dominance in volcanic grassland soil.

PubMed

Daebeler, Anne; Bodelier, Paul L E; Hefting, Mariet M; Laanbroek, Hendrikus J

2015-03-01

The first step of nitrification is carried out by ammonia-oxidizing bacteria (AOB) and archaea (AOA). It is largely unknown, by which mechanisms these microbes are capable of coexistence and how their respective contribution to ammonia oxidation may differ with varying soil characteristics. To determine how different levels of ammonium availability influence the extent of archaeal and bacterial contributions to ammonia oxidation, microcosm incubations with controlled ammonium levels were conducted. Net nitrification was monitored and ammonia-oxidizer communities were quantified. Additionally, the nitrification inhibitor allylthiourea (ATU) was applied to discriminate between archaeal and bacterial contributions to soil ammonia oxidation. Thaumarchaeota, which were the only ammonia oxidizers detectable at the start of the incubation, grew in all microcosms, but AOB later became detectable in ammonium amended microcosms. Low and high additions of ammonium increasingly stimulated AOB growth, while AOA were only stimulated by the low addition. Treatment with ATU had no effect on net nitrification and sizes of ammonia-oxidizing communities suggesting that the effective concentration of ATU to discriminate between archaeal and bacterial ammonia oxidation is not the same in different soils. Our results support the niche-differentiating potential of ammonium concentration for AOA and AOB, and we conclude that ammonium limitation can be a major reason for absence of detectable AOB in soil. © FEMS 2015. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

Identifying Deformation and Strain Hardening Behaviors of Nanoscale Metallic Multilayers Through Nano-wear Testing

DOE PAGES

Economy, David Ross; Mara, Nathan A.; Schoeppner, R.; ...

2016-01-13

In complex loading conditions (e.g. sliding contact), mechanical properties, such as strain hardening and initial hardness, will dictate the long-term performance of materials systems. With this in mind, the strain hardening behaviors of Cu/Nb nanoscale metallic multilayer systems were examined by performing nanoindentation tests within nanoscratch wear boxes and undeformed, as-deposited regions. Both the architecture and substrate influence were examined by utilizing three different individual layer thicknesses (2, 20, and 100 nm) and two total film thicknesses (1 and 10 μm). After nano-wear deformation, multilayer systems with thinner layers showed less volume loss as measured by laser scanning microscopy. Additionally,more » the hardness of the deformed regions significantly rose with respect to the as-deposited measurements, which further increased with greater wear loads. Strain hardening exponents for multilayers with thinner layers (2 and 20 nm, n ≈ 0.018 and n ≈ 0.022 respectively) were less than was determined for 100 nm systems (n ≈ 0.041). These results suggest that singledislocation based deformation mechanisms observed for the thinner systems limit the extent of achievable strain hardening. This conclusion indicates that impacts of both architecture strengthening and strain hardening must be considered to accurately predict multilayer performance during sliding contact across varying length scales.« less

Unique pioneer microbial communities exposed to volcanic sulfur dioxide

PubMed Central

Fujimura, Reiko; Kim, Seok-Won; Sato, Yoshinori; Oshima, Kenshiro; Hattori, Masahira; Kamijo, Takashi; Ohta, Hiroyuki

2016-01-01

Newly exposed volcanic substrates contain negligible amounts of organic materials. Heterotrophic organisms in newly formed ecosystems require bioavailable carbon and nitrogen that are provided from CO2 and N2 fixation by pioneer microbes. However, the knowledge of initial ecosystem developmental mechanisms, especially the association between microbial succession and environmental change, is still limited. This study reports the unique process of microbial succession in fresh basaltic ash, which was affected by long-term exposure to volcanic sulfur dioxide (SO2). Here we compared the microbial ecosystems among deposits affected by SO2 exposure at different levels. The results of metagenomic analysis suggested the importance of autotrophic iron-oxidizing bacteria, particularly those involved in CO2 and N2 fixation, in the heavily SO2 affected site. Changes in the chemical properties of the deposits after the decline of the SO2 impact led to an apparent decrease in the iron-oxidizer abundance and a possible shift in the microbial community structure. Furthermore, the community structure of the deposits that had experienced lower SO2 gas levels showed higher similarity with that of the control forest soil. Our results implied that the effect of SO2 exposure exerted a selective pressure on the pioneer community structure by changing the surrounding environment of the microbes. PMID:26791101

Effect of MWCNT reinforcement on the precipitation-hardening behavior of AA2219

NASA Astrophysics Data System (ADS)

Thomas, Shijo; Umasankar, V.

2018-01-01

Aluminum alloy matrix composites have found a predominant place in research, and their applications are explored in almost all industries. The aerospace industry has been using precipitation-hardenable alloys in structural applications. However, insufficient literature is available on the influence of multiwalled carbon nanotubes (MWCNTs) on precipitation-hardenable alloy composite materials; thus, this work was designed to elucidate the effect on MWCNT reinforcement on AA2219 with and without precipitation hardening. Reinforcement with MWCNTs has been reported to accelerate precipitation and to achieve greater hardness within a much shorter time. The addition of 0.75wt% MWCNTs resulted in maximal hardness at 90 min, which is approximately 27% of improvement over the maximum hardness achieved by the corresponding monolithic alloy after 10 h of aging. The sample reinforced with 0.75wt% MWCNTs showed an improvement of 82% in hardness by solutionizing and aging compared to that achieved by sintering.

Magma genesis of the acidic volcanism in the intra-arc rift zone of the Izu volcanic arc, Japan

NASA Astrophysics Data System (ADS)

Haraguchi, S.; Tokuyama, H.; Ishii, T.

2010-12-01

The Izu volcanic arc extends over 550 km from the Izu Peninsula, Japan, to the Nishinoshima Trough or Sofugan tectonic line. It is the northernmost segment of the Izu-Bonin-Mariana arc system, which is located at the eastern side of the Philippine Sea Plate. The recent magmatism of the Izu arc is bimodal and characterized by basalt and rhyolite (e.g. Tamura and Tatsumi 2002). In the southern Izu arc, volcanic front from the Aogashima to the Torishima islands is characterized by submarine calderas and acidic volcanisms. The intra-arc rifting, characterized by back-arc depressions, small volcanic knolls and ridges, is active in this region. Volcanic rocks were obtained in 1995 during a research cruise of the R/V MOANA WAVE (Hawaii University, cruise MW9507). Geochemical variation of volcanic rocks and magma genesis was studied by Hochstaedter et al. (2000, 2001), Machida et al (2008), etc. These studies focused magma and mantle dynamics of basaltic volcanism in the wedge mantle. Acidic volcanic rocks were also dredged during the curies MW9507. However, studies of these acidic volcanics were rare. Herein, we present petrographical and chemical analyses of these acidic rocks, and compare these results with those of other acidic rocks in the Izu arc and lab experiments, and propose a model of magma genesis in a context of acidic volcanism. Dredge sites by the cruise MW9507 are 120, and about 50 sites are in the rift zone. Recovered rocks are dominated by the bimodal assemblage of basalt-basaltic andesite and dacite-rhyolite. The most abundant phase is olivine basalt, less than 50 wt% SiO2. Andesites are minor in volume and compositional gap from 56 to 65 wt% SiO2 exists. The across-arc variation of the HFSE contents and ratios, such as Zr/Y and Nb/Zr of rhyolites exhibit depleted in the volcanic front side and enriched in reararc side. This characteristic is similar to basaltic volcanism pointed out by Hochstaedter et al (2000). The petrographical features of rhyolites

Simulation of irradiation hardening of Zircaloy within plate-type dispersion nuclear fuel elements

NASA Astrophysics Data System (ADS)

Jiang, Yijie; Wang, Qiming; Cui, Yi; Huo, Yongzhong; Ding, Shurong

2011-06-01

Within plate-type dispersion nuclear fuel elements, the metal matrix and cladding attacked continuously by fast neutrons undergo irradiation hardening, which might have remarkable effects upon the mechanical behaviors within fuel elements. In this paper, with the irradiation hardening effect of metal materials mainly considered together with irradiation growth effect of the cladding, the three-dimensional large-deformation constitutive relations for the metal matrix and cladding are developed. The method of virtual temperature increase in the previous studies is further developed to model the irradiation swelling of fuel particles; the method of anisotropic thermal expansion is introduced to model irradiation growth of the cladding; and a method of multi-step-temperature loading is proposed to simulate the coupling features of irradiation-induced swelling of the fuel particles together with irradiation growth of the cladding. Above all, based on the developed relationship between irradiation growth at certain burnup and the loaded virtual temperatures, with considering that certain burnup corresponds to certain fast neutron fluence, the time-dependent constitutive relation due to irradiation hardening effect is replaced by the virtual-temperature-dependent one which is introduced into the commercial software to simulate the irradiation hardening effects of the matrix and cladding. Numerical simulations of the irradiation-induced mechanical behaviors are implemented with the finite element method in consideration of the micro-structure of the fuel meat. The obtained results indicate that when the irradiation hardening effects are introduced into the constitutive relations of the metal matrix and cladding: (1) higher maximum Mises stresses for certain burnup at the matrix exist with the equivalent plastic strains remaining almost the same at lower burnups; (2) the maximum Mises stresses for certain burnup at the cladding are enhanced while the maximum equivalent

Synergetics of hardening construction systems

NASA Astrophysics Data System (ADS)

Tolstoy, A. D.; Lesovik, V. S.; Glagolev, E. S.; Krymova, A. I.

2018-03-01

The study of hardening high-strength systems indicates the relation between the potential of synergetics and issues related to structure formation of aggregates produced on the basis of rationally selected construction mixes. The paper considers challenges of the general principles of synergetics and sustainable development of open dissipative systems and their use in industry, as well as their understanding as complete self-regulating nonequilibrium systems. The main objective of the study was to demonstrate that the principles of self-regulating systems development can be applied in construction technology.

A Study on Low-Cost Case Hardening of Mild and Alloy Steels Utilizing Cassava Leaf Media

NASA Astrophysics Data System (ADS)

Gordon, Renee Erica

Conventional case hardening processes have major drawbacks in being expensive and hazardous to perform. A novel cyaniding technique has been developed to case harden steel which involves the use of cassava leaf. Cassava is ideal for use in this process as it contains varying degrees of cyanogenic glucoside (15-1000 mg of HCN per kg of cassava). The entire hardening process involves direct thermal decomposition of the HCN, which produced C and N gas that then diffused into the steel creating a hardened surface. Pulverized cassava leaf was involved in the pack-cyaniding of AISI 1018 and Nitralloy 135 within three varying process atmospheres. The use of barium carbonate (BaCO3) as an energizer was employed at the high temperature regime while barium chloride (BaCl2) was utilized at low temperatures. Vickers microhardness testing, microstructural characterization, and diffraction techniques were utilized for analysis. While no improvement was observed at low temperatures, processing within the high temperature regime showed significant hardening. The addition of BaCO3 to pulverized cassava leaf accelerated the hardening process by substantially increasing the resident surface microhardness while generating a shallow case layer distance. Diffusion theory was used to identify changes experienced with the variation in parameters. The presence of barium carbonate during processing decreased the diffusivity of hardening agents. This manifested in a very large, initial mass transfer of diffusing species localized in the case region followed by a minimum of any further increase in case depths, even as treatment time intervals were increased. The level of influence each parameter delivered was assessed using stepwise regression analysis and a unified model was constructed.

Characterization and Strain-Hardening Behavior of Friction Stir-Welded Ferritic Stainless Steel

NASA Astrophysics Data System (ADS)

Sharma, Gaurav; Dwivedi, Dheerendra Kumar; Jain, Pramod Kumar

2017-12-01

In this study, friction stir-welded joint of 3-mm-thick plates of 409 ferritic stainless steel (FSS) was characterized in light of microstructure, x-ray diffraction analysis, hardness, tensile strength, ductility, corrosion and work hardening properties. The FSW joint made of ferritic stainless steel comprises of three distinct regions including the base metal. In stir zone highly refined ferrite grains with martensite and some carbide precipitates at the grain boundaries were observed. X-ray diffraction analysis also revealed precipitation of Cr23C6 and martensite formation in heat-affected zone and stir zone. In tensile testing of the transverse weld samples, the failure eventuated within the gauge length of the specimen from the base metal region having tensile properties overmatched to the as-received base metal. The tensile strength and elongation of the longitudinal (all weld) sample were found to be 1014 MPa and 9.47%, respectively. However, in potentiodynamic polarization test, the corrosion current density of the stir zone was highest among all the three zones. The strain-hardening exponent for base metal, transverse and longitudinal (all weld) weld samples was calculated using various equations. Both the transverse and longitudinal weld samples exhibited higher strain-hardening exponents as compared to the as-received base metal. In Kocks-Mecking plots for the base metal and weld samples at least two stages of strain hardening were observed.

Microstructural and Mechanical Study of Press Hardening of Thick Boron Steel Sheet

NASA Astrophysics Data System (ADS)

Pujante, J.; Garcia-Llamas, E.; Golling, S.; Casellas, D.

2017-09-01

Press hardening has become a staple in the production of automotive safety components, due to the combination of high mechanical properties and form complexity it offers. However, the use of press hardened components has not spread to the truck industry despite the advantages it confers, namely affordable weight reduction without the use of exotic materials, would be extremely attractive for this sector. The main reason for this is that application of press hardened components in trucks implies adapting the process to the manufacture of thick sheet metal. This introduces an additional layer of complexity, mainly due to the thermal gradients inside the material resulting in though-thickness differences in austenitization and cooling, potentially resulting in complex microstructure and gradient of mechanical properties. This work presents a preliminary study on the press hardening of thick boron steel sheet. First of all, the evolution of the sheet metal during austenitization is studied by means of dilatometry tests and by analysing the effect of furnace dwell time on grain size. Afterwards, material cooled using different cooling strategies, and therefore different effective cooling rates, is studied in terms of microstructure and mechanical properties. Initial results from finite element simulation are compared to experimental results, focusing on the phase composition in through thickness direction. Results show that industrial-equivalent cooling conditions do not lead to gradient microstructures, even in extreme scenarios involving asymmetrical cooling.

Factors contributing to enhanced freezing tolerance in wheat during frost hardening in the light.

PubMed

Janda, Tibor; Szalai, Gabriella; Leskó, Kornélia; Yordanova, Rusina; Apostol, Simona; Popova, Losanka Petrova

2007-06-01

The interaction between light and temperature during the development of freezing tolerance was studied in winter wheat (Triticum aestivum L. var. Mv Emese). Ten-day-old plants were cold hardened at 5 degrees C for 12 days under normal (250 micromol m(-2)s(-1)) or low light (20 micromol m(-2)s(-1)) conditions. Some of the plants were kept at 20/18 degrees C for 12 days at high light intensity (500 micromol m(-2)s(-1)), which also increased the freezing tolerance of winter wheat. The freezing survival rate, the lipid composition, the antioxidant activity, and the salicylic acid content were investigated during frost hardening. The saturation level of hexadecanoic acid decreased not only in plants hardened at low temperature, but also, to a lesser extent, in plants kept under high light irradiation at normal growth temperature. The greatest induction of the enzymes glutathione reductase (EC 1.6.4.2.) and ascorbate peroxidase (EC 1.11.1.11.) occurred when the cold treatment was carried out in normal light, but high light intensity at normal, non-hardening temperature also increased the activity of these enzymes. The catalase (EC 1.11.1.6.) activity was also higher in plants grown at high light intensity than in the controls. The greatest level of induction in the activity of the guaiacol peroxidase (EC 1.11.1.7.) enzyme occurred under cold conditions with low light. The bound ortho-hydroxy-cinnamic acid increased by up to two orders of magnitude in plants that were cold hardened in normal light. Both high light intensity and low temperature hardening caused an increase in the free and bound salicylic acid content of the leaves. This increase was most pronounced in plants that were cold treated in normal light.

An evolving effective stress approach to anisotropic distortional hardening

DOE PAGES

Lester, B. T.; Scherzinger, W. M.

2018-03-11

A new yield surface with an evolving effective stress definition is proposed for consistently and efficiently describing anisotropic distortional hardening. Specifically, a new internal state variable is introduced to capture the thermodynamic evolution between different effective stress definitions. The corresponding yield surface and evolution equations of the internal variables are derived from thermodynamic considerations enabling satisfaction of the second law. A closest point projection return mapping algorithm for the proposed model is formulated and implemented for use in finite element analyses. Finally, select constitutive and larger scale boundary value problems are solved to explore the capabilities of the model andmore » examine the impact of distortional hardening on constitutive and structural responses. Importantly, these simulations demonstrate the tractability of the proposed formulation in investigating large-scale problems of interest.« less

An evolving effective stress approach to anisotropic distortional hardening

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lester, B. T.; Scherzinger, W. M.

A new yield surface with an evolving effective stress definition is proposed for consistently and efficiently describing anisotropic distortional hardening. Specifically, a new internal state variable is introduced to capture the thermodynamic evolution between different effective stress definitions. The corresponding yield surface and evolution equations of the internal variables are derived from thermodynamic considerations enabling satisfaction of the second law. A closest point projection return mapping algorithm for the proposed model is formulated and implemented for use in finite element analyses. Finally, select constitutive and larger scale boundary value problems are solved to explore the capabilities of the model andmore » examine the impact of distortional hardening on constitutive and structural responses. Importantly, these simulations demonstrate the tractability of the proposed formulation in investigating large-scale problems of interest.« less

Paving asphalts : reduction of oxidative hardening of asphalts by treatment with hydrated lime : a mechanistic study

DOT National Transportation Integrated Search

1977-04-01

This study showed that lime treatment removes polar, viscosity-building components and reduces the susceptibility of the asphalt to laboratory oxidative hardening. The beneficial effects of lime treatment in reducing asphalt oxidative hardening were ...

Temporal and Spatial Analysis of Monogenetic Volcanic Fields

NASA Astrophysics Data System (ADS)

Kiyosugi, Koji

Achieving an understanding of the nature of monogenetic volcanic fields depends on identification of the spatial and temporal patterns of volcanism in these fields, and their relationships to structures mapped in the shallow crust and inferred in the deep crust and mantle through interpretation of geochemical, radiometric and geophysical data. We investigate the spatial and temporal distributions of volcanism in the Abu Monogenetic Volcano Group, Southwest Japan. E-W elongated volcano distribution, which is identified by a nonparametric kernel method, is found to be consistent with the spatial extent of P-wave velocity anomalies in the lower crust and upper mantle, supporting the idea that the spatial density map of volcanic vents reflects the geometry of a mantle diapir. Estimated basalt supply to the lower crust is constant. This observation and the spatial distribution of volcanic vents suggest stability of magma productivity and essentially constant two-dimensional size of the source mantle diapir. We mapped conduits, dike segments, and sills in the San Rafael sub-volcanic field, Utah, where the shallowest part of a Pliocene magmatic system is exceptionally well exposed. The distribution of conduits matches the major features of dike distribution, including development of clusters and distribution of outliers. The comparison of San Rafael conduit distribution and the distributions of volcanoes in several recently active volcanic fields supports the use of statistical models, such as nonparametric kernel methods, in probabilistic hazard assessment for distributed volcanism. We developed a new recurrence rate calculation method that uses a Monte Carlo procedure to better reflect and understand the impact of uncertainties of radiometric age determinations on uncertainty of recurrence rate estimates for volcanic activity in the Abu, Yucca Mountain Region, and Izu-Tobu volcanic fields. Results suggest that the recurrence rates of volcanic fields can change by more

BOREAS TGB-12 Soil Carbon and Flux Data of NSA-MSA in Raster Format

NASA Technical Reports Server (NTRS)

Hall, Forrest G. (Editor); Knapp, David E. (Editor); Rapalee, Gloria; Davidson, Eric; Harden, Jennifer W.; Trumbore, Susan E.; Veldhuis, Hugo

2000-01-01

The BOREAS TGB-12 team made measurements of soil carbon inventories, carbon concentration in soil gases, and rates of soil respiration at several sites. This data set provides: (1) estimates of soil carbon stocks by horizon based on soil survey data and analyses of data from individual soil profiles; (2) estimates of soil carbon fluxes based on stocks, fire history, drain-age, and soil carbon inputs and decomposition constants based on field work using radiocarbon analyses; (3) fire history data estimating age ranges of time since last fire; and (4) a raster image and an associated soils table file from which area-weighted maps of soil carbon and fluxes and fire history may be generated. This data set was created from raster files, soil polygon data files, and detailed lab analysis of soils data that were received from Dr. Hugo Veldhuis, who did the original mapping in the field during 1994. Also used were soils data from Susan Trumbore and Jennifer Harden (BOREAS TGB-12). The binary raster file covers a 733-km 2 area within the NSA-MSA.

Group precipitation and age hardening of nanostructured Fe-based alloys with ultra-high strengths

DOE PAGES

Jiao, Z. B.; Luan, J. H.; Miller, M. K.; ...

2016-02-19

The precipitation of nanoparticles plays a key role in determining the properties of many structural materials, and the understanding of their formation and stabilization mechanisms has been a long standing interest in the material field. However, the critical issues involving the group precipitation of various nanoparticles and their cooperative hardening mechanism remain elusive in the newly discovered Fe-based alloys with nanostructures. Here we quantitatively elucidate the nucleation mechanism, evolution kinetics and hardening effects of the group-precipitated nanoparticles in the Fe-Cu-Ni-Al-based alloys by atom probe tomography together with both first-principles and thermodynamic calculations. Our results provide the compelling evidence for twomore » interesting but complex group precipitation pathways of nanoparticles, i.e., the Cu-rich and NiAl-based precipitations. Lastly, the co-existence of the two precipitation pathways plays a key role in age hardening kinetics and ultimately enhances the hardening response, as compared to the single particle type of strengthening, therefore providing an effective new approach for strengthening materials for structural applications.« less

Group precipitation and age hardening of nanostructured Fe-based alloys with ultra-high strengths

PubMed Central

Jiao, Z. B.; Luan, J. H.; Miller, M. K.; Yu, C. Y.; Liu, C. T.

2016-01-01

The precipitation of nanoparticles plays a key role in determining the properties of many structural materials, and the understanding of their formation and stabilization mechanisms has been a long standing interest in the material field. However, the critical issues involving the group precipitation of various nanoparticles and their cooperative hardening mechanism remain elusive in the newly discovered Fe-based alloys with nanostructures. Here we quantitatively elucidate the nucleation mechanism, evolution kinetics and hardening effects of the group-precipitated nanoparticles in the Fe-Cu-Ni-Al-based alloys by atom probe tomography together with both first-principles and thermodynamic calculations. Our results provide the compelling evidence for two interesting but complex group precipitation pathways of nanoparticles, i.e., the Cu-rich and NiAl-based precipitations. The co-existence of the two precipitation pathways plays a key role in age hardening kinetics and ultimately enhances the hardening response, as compared to the single particle type of strengthening, therefore providing an effective new approach for strengthening materials for structural applications. PMID:26892834

Izu-Oshima volcano, Japan: ten years of geochemical monitoring by means of CO2 soil diffuse degassing

NASA Astrophysics Data System (ADS)

Hernandez Perez, P. A.; Mori, T.; Notsu, K.; Morita, M.; Padron, E.; Onizawa, S.; Melián, G.; Sumino, H.; Asensio-Ramos, M.; Nogami, K.; Yamane, K.; Perez, N. M.

2016-12-01

Izu-Oshima is an active volcanic island located around 100 km SSW of Tokyo. The centre of the island is occupied by a caldera complex with a diameter of 3 km. A large post-caldera cone known as Mt. Mihara is located at the south-western quadrant of the caldera. Izu-Oshima has erupted 74 times, consisting mainly in fissure eruptions, both inside and outside of the caldera. The last eruption of Izu-Oshima occurred in 1986. Since 2007, eight soil gas surveys have been carried out to investigate the spatial and temporal evolution of diffuse CO2 emission from this volcanic system and to identify those structures controlling the degassing process. Diffuse CO2 emission surveys were always carried out following the accumulation chamber method. Spatial distribution maps were constructed following the sequential Gaussian simulation (sGs) procedure. The location of the CO2 anomalies has always shown a close relationship with the structural characteristics of Miharayama, with most of the gas discharged from the rim of the summit crater. Temporal evolution of diffuse CO2 emission rate from Mt. Miharayama has shown a good temporal correlation with the main two peaks of seismic activity occur when highest CO diffuse emissions were computed, March 2007, August 2010 and July 2011, may be associated with fluid pressure fluctuations in the volcanic system due stress changes at depth. In order to strength the contribution of deep seated gases, we performed carbon isotopic analysis of soil gas samples at selected sites during 2010, 2013, 2015 and 2016 surveys. At isotopic compositions lighter than - 6‰, the soil CO2 effluxes were always low, while at heavier isotopic compositions an increasing number of points are characterized by relatively high soil CO efflux. Soil CO2 efflux peak values (xB) showed also a good correlation with the observed seismicity, with the largest value computed on June 2013. This parameter is a geochemical expression of the magnitude of the anomalous

Global volcanic emissions: budgets, plume chemistry and impacts

NASA Astrophysics Data System (ADS)

Mather, T. A.

2012-12-01

Over the past few decades our understanding of global volcanic degassing budgets, plume chemistry and the impacts of volcanic emissions on our atmosphere and environment has been revolutionized. Global volcanic emissions budgets are needed if we are to make effective use of regional and global atmospheric models in order to understand the consequences of volcanic degassing on global environmental evolution. Traditionally volcanic SO2 budgets have been the best constrained but recent efforts have seen improvements in the quantification of the budgets of other environmentally important chemical species such as CO2, the halogens (including Br and I) and trace metals (including measurements relevant to trace metal atmospheric lifetimes and bioavailability). Recent measurements of reactive trace gas species in volcanic plumes have offered intriguing hints at the chemistry occurring in the hot environment at volcanic vents and during electrical discharges in ash-rich volcanic plumes. These reactive trace species have important consequences for gas plume chemistry and impacts, for example, in terms of the global fixed nitrogen budget, volcanically induced ozone destruction and particle fluxes to the atmosphere. Volcanically initiated atmospheric chemistry was likely to have been particularly important before biological (and latterly anthropogenic) processes started to dominate many geochemical cycles, with important consequences in terms of the evolution of the nitrogen cycle and the role of particles in modulating the Earth's climate. There are still many challenges and open questions to be addressed in this fascinating area of science.

Multi-scale simulation of radiation damage accumulation and subsequent hardening in neutron-irradiated α-Fe

DOE PAGES

Dunn, Aaron; Dingreville, Remi; Capolungo, Laurent

2015-11-27

A hierarchical methodology is introduced to predict the effects of radiation damage and irradiation conditions on the yield stress and internal stress heterogeneity developments in polycrystalline α-Fe. Simulations of defect accumulation under displacement cascade damage conditions are performed using spatially resolved stochastic cluster dynamics. The resulting void and dislocation loop concentrations and average sizes are then input into a crystal plasticity formulation that accounts for the change in critical resolved shear stress due to the presence of radiation induced defects. The simulated polycrystalline tensile tests show a good match to experimental hardening data over a wide range of irradiation doses.more » With this capability, stress heterogeneity development and the effect of dose rate on hardening is investigated. The model predicts increased hardening at higher dose rates for low total doses. By contrast, at doses above 10 –2 dpa when cascade overlap becomes significant, the model does not predict significantly different hardening for different dose rates. In conclusion, the development of such a model enables simulation of radiation damage accumulation and associated hardening without relying on experimental data as an input under a wide range of irradiation conditions such as dose, dose rate, and temperature.« less

Hardening neutron spectrum for advanced actinide transmutation experiments in the ATR.

PubMed

Chang, G S; Ambrosek, R G

2005-01-01

The most effective method for transmuting long-lived isotopes contained in spent nuclear fuel into shorter-lived fission products is in a fast neutron spectrum reactor. In the absence of a fast test reactor in the United States, initial irradiation testing of candidate fuels can be performed in a thermal test reactor that has been modified to produce a test region with a hardened neutron spectrum. Such a test facility, with a spectrum similar but somewhat softer than that of the liquid-metal fast breeder reactor (LMFBR), has been constructed in the INEEL's Advanced Test Reactor (ATR). The radial fission power distribution of the actinide fuel pin, which is an important parameter in fission gas release modelling, needs to be accurately predicted and the hardened neutron spectrum in the ATR and the LMFBR fast neutron spectrum is compared. The comparison analyses in this study are performed using MCWO, a well-developed tool that couples the Monte Carlo transport code MCNP with the isotope depletion and build-up code ORIGEN-2. MCWO analysis yields time-dependent and neutron-spectrum-dependent minor actinide and Pu concentrations and detailed radial fission power profile calculations for a typical fast reactor (LMFBR) neutron spectrum and the hardened neutron spectrum test region in the ATR. The MCWO-calculated results indicate that the cadmium basket used in the advanced fuel test assembly in the ATR can effectively depress the linear heat generation rate in the experimental fuels and harden the neutron spectrum in the test region.

Effects of simulated nitrogen deposition on ectomycorrhizae community structure in hybrid larch and its parents grown in volcanic ash soil: The role of phosphorous.

PubMed

Wang, Xiaona; Agathokleous, Evgenios; Qu, Laiye; Fujita, Saki; Watanabe, Makoto; Tamai, Yutaka; Mao, Qiaozhi; Koyama, Akihiro; Koike, Takayoshi

2018-03-15

With the rapid industrial development and modern agricultural practices, increasing nitrogen (N) deposition can cause nutrient imbalance in immature volcanic ash soil commonly found in Japan. Larch species, widely distributed in northeast Eurasia, are associated with ectomycorrhizal (ECM) fungi which play a critical role in nutrient acquisition for their hosts. In this study, we investigated species richness and diversity of ECM fungi associated with a hybrid larch (F 1 ) and its parents, Dahurian larch (Larix gmelinii var. japonica) and Japanese larch (L. kaempferi), under simulated N deposition (0 and 100kgha -1 yr -1 ) with/without phosphorous (P) (0 and 50kgha -1 yr -1 ). Seedlings planted in immature volcanic ash with low nutrient availability were subjected to the N and P treatments for fifteen months. We found that response of ECM community structure to the increased nutrient availability depended on host genotypes. Nutrient addition significantly affected ECM structure in Japanese larch, but no such significant effect was found for Dahurian larch. Effects of the nutrient addition to ECM fungal community in F 1 were intermediate. F 1 was tolerant to high N loading, which was due to consistent, relatively high association with Suillus sp. and Hebeloma sp. F 1 showed heterosis in relative biomass, which was most apparent under high N treatments. This co-variation of ECM fungal community structure and F 1 biomass in response to N loading suggest that ECM community structure might play an important role in host growth. The present findings indicate effects of N deposition on ECM fungal community structure can depend on larch species, thus it is challenging to predict general trends. Copyright © 2017 Elsevier B.V. All rights reserved.

Lichen-rock interaction in volcanic environments: evidences of soil-precursor formation

NASA Astrophysics Data System (ADS)

Vingiani, S.; Adamo, P.; Terribile, F.

2012-04-01

The weathering action of the lichens Lecidea fuscoatra (L.) Ach. and Stereocaulon vesuvianum Pers. on basaltic rock collected on the slopes of Mt. Etna (Sicily) at 1550 m a.s.l. has been studied using optical (OM) and electron (SEM) microscopy equipped with microanalytical device (EDS). Biological factors associated with lichen growth play a major role in the weathering of minerals on bare rocks and contribute to the preliminary phases of soil formation. The present work investigates the biogeophysical and biogeochemical weathering associated to the growth of epilithic lichens on lava flows from Mt. Etna (Sicily) and Mt. Vesuvius (Campania). The chosen lichen species were the crustose Lecidea fuscoatra (L.) Ach., the foliose Xanthoparmelia conspersa and the fructicose Stereocaulon vesuvianum Pers. An integrated approach based on the study of both disturbed and undisturbed samples of lichenized rock was applied in order to appreciate the complexity of the rock-lichen interface environment in terms of micromorphological, mineralogical and chemical properties. XRD and XRF analyses coupled to microscopical (OM), submicroscopical (SEM) and microanalitical (EDS) observations were the used techniques. In both study environments, the chemical, mineralogical and micromorphological properties of the uncoherent materials found at the lichen-rock interface suggest they consist of rock fragments eroded from the surroundings and accumulated in cavities and fissures of the rough lava flows. According to the thallus morphology, the lichens colonizing the lava preserve the interface materials from further aeolic and water erosion, provide these materials of organic matter and moisture, entrap allochtonous quartz and clay minerals. The calcium oxalate production by L. fuscoatra and X. conspersa, the Al enrichment around S. vesuvianum hyphae and the occurrence of Fe-oxide phases at the rock-lichen interface are evidences of lichens interaction with the underlying sediments. Indeed

Languages of volcanic landscapes

Treesearch

Frederick J. Swanson

2008-01-01

As a young geologist in 1980, I felt a powerful attraction to volcanoes, and I thought I knew volcanoes rather well. I had studied volcanology. I had climbed volcanic peaks in the Cascades. And I had tried to be an attentive citizen of my volcanic region, the Pacific Northwest. But when I had a chance to go with other scientists to Mount St. Helens within days of its...

Ecosystem recharge by volcanic dust drives broad-scale variation in bird abundance.

PubMed

Gunnarsson, Tómas Grétar; Arnalds, Ólafur; Appleton, Graham; Méndez, Verónica; Gill, Jennifer A

2015-06-01

Across the globe, deserts and volcanic eruptions produce large volumes of atmospheric dust, and the amount of dust is predicted to increase with global warming. The effects of long-distance airborne dust inputs on ecosystem productivity are potentially far-reaching but have primarily been measured in soil and plants. Airborne dust could also drive distribution and abundance at higher trophic levels, but opportunities to explore these relationships are rare. Here we use Iceland's steep dust deposition gradients to assess the influence of dust on the distribution and abundance of internationally important ground-nesting bird populations. Surveys of the abundance of breeding birds at 729 locations throughout lowland Iceland were used to explore the influence of dust deposition on bird abundance in agricultural, dry, and wet habitats. Dust deposition had a strong positive effect on bird abundance across Iceland in dry and wet habitats, but not in agricultural land where nutrient levels are managed. The abundance of breeding waders, the dominant group of terrestrial birds in Iceland, tripled on average between the lowest and highest dust deposition classes in both wet and dry habitats. The deposition and redistribution of volcanic materials can have powerful impacts in terrestrial ecosystems and can be a major driver of the abundance of higher trophic-level organisms at broad spatial scales. The impacts of volcanic ash deposition during eruptions and subsequent redistribution of unstable volcanic materials are strong enough to override effects of underlying variation in organic matter and clay content on ecosystem fertility. Global rates of atmospheric dust deposition are likely to increase with increasing desertification and glacier retreat, and this study demonstrates that the effects on ecosystems are likely to be far-reaching, both in terms of spatial scales and ecosystem components.

SEGR- and SEB-hardened structure with DSPSOI in power MOSFETs

NASA Astrophysics Data System (ADS)

Tang, Zhaohuan; Fu, Xinghua; Yang, Fashun; Tan, Kaizhou; Ma, Kui; Wu, Xue; Lin, Jiexing

2017-12-01

Single event irradiation-hardened power MOSFET is the most important device for DC/DC converter in space environment application. Single event gate rupture (SEGR) and single event burnout (SEB), which will degrade the running safety and reliability of spacecraft, are the two typical failure modes in power MOSFETs. In this paper, based on recombination mechanism of interface between oxide and silicon, a novel hardened power MOSFETs structure for SEGR and SEB is proposed. The structure comprises double stagger partial silicon-on-insulator (DSPSOI) layers. Results show that the safety operation area (SOA) of a 130 V N-channel power MOSFET in single event irradiation environment is enhanced by up to 50% when the linear-energy-transfer value of heavy ion is a constant of 98 MeV·cm2/mg in the whole incident track, and the other parameters are almost maintained at the same value. Thus this novel structure can be widely used in designing single event irradiation-hardened power MOSFETs. Project supported by the National Natural Science Foundation of China (No. 61464002), the Grand Science and Technology Special Project in Guizhou Province of China (No. [2015]6006), and the Ministry of Education Open Foundation for Semiconductor Power Device Reliability (No. 010201).

Slab dehydration in Cascadia and its relationship to volcanism, seismicity, and non-volcanic tremor

NASA Astrophysics Data System (ADS)

Delph, J. R.; Levander, A.; Niu, F.

2017-12-01

The characteristics of subduction beneath the Pacific Northwest (Cascadia) are variable along strike, leading to the segmentation of Cascadia into 3 general zones: Klamath, Siletzia, and Wrangelia. These zones show marked differences in tremor density, earthquake density, seismicity rates, and the locus and amount of volcanism in the subduction-related volcanic arc. To better understand what controls these variations, we have constructed a 3D shear-wave velocity model of the upper 80 km along the Cascadia margin from the joint inversion of CCP-derived receiver functions and ambient noise surface wave data using 900 temporary and permanent broadband seismic stations. With this model, we can investigate variations in the seismic structure of the downgoing oceanic lithosphere and overlying mantle wedge, the character of the crust-mantle transition beneath the volcanic arc, and local to regional variations in crustal structure. From these results, we infer the presence and distribution of fluids released from the subducting slab and how they affect the seismic structure of the overriding lithosphere. In the Klamath and Wrangelia zones, high seismicity rates in the subducting plate and high tremor density correlate with low shear velocities in the overriding plate's forearc and relatively little arc volcanism. While the cause of tremor is debated, intermediate depth earthquakes are generally thought to be due to metamorphic dehydration reactions resulting from the dewatering of the downgoing slab. Thus, the seismic characteristics of these zones combined with rather sparse arc volcanism may indicate that the slab has largely dewatered by the time it reaches sub-arc depths. Some of the water released during earthquakes (and possibly tremor) may percolate into the overriding plate, leading to slow seismic velocities in the forearc. In contrast, Siletzia shows relatively low seismicity rates and tremor density, with relatively higher shear velocities in the forearc

Seismological evidence for a sub-volcanic arc mantle wedge beneath the Denali volcanic gap, Alaska

USGS Publications Warehouse

McNamara, D.E.; Pasyanos, M.E.

2002-01-01

Arc volcanism in Alaska is strongly correlated with the 100 km depth contour of the western Aluetian Wadati-Benioff zone. Above the eastern portion of the Wadati-Benioff zone however, there is a distinct lack of volcanism (the Denali volcanic gap). We observe high Poisson's ratio values (0.29-0.33) over the entire length of the Alaskan subduction zone mantle wedge based on regional variations of Pn and Sn velocities. High Poisson's ratios at this depth (40-70 km), adjacent to the subducting slab, are attributed to melting of mantle-wedge peridotites, caused by fluids liberated from the subducting oceanic crust and sediments. Observations of high values of Poisson's ratio, beneath the Denali volcanic gap suggest that the mantle wedge contains melted material that is unable to reach the surface. We suggest that its inability to migrate through the overlying crust is due to increased compression in the crust at the northern apex of the curved Denali fault.

Radiation hardening of optical fibers and fiber sensors for space applications: recent advances

NASA Astrophysics Data System (ADS)

Girard, S.; Ouerdane, Y.; Pinsard, E.; Laurent, A.; Ladaci, A.; Robin, T.; Cadier, B.; Mescia, L.; Boukenter, A.

2017-11-01

In these ICSO proceedings, we review recent advances from our group concerning the radiation hardening of optical fiber and fiber-based sensors for space applications and compare their benefits to state-of-the-art results. We focus on the various approaches we developed to enhance the radiation tolerance of two classes of optical fibers doped with rare-earths: the erbium (Er)-doped ones and the ytterbium/erbium (Er/Yb)-doped ones. As a first approach, we work at the component level, optimizing the fiber structure and composition to reduce their intrinsically high radiation sensitivities. For the Erbium-doped fibers, this has been achieved using a new structure for the fiber that is called Hole-Assisted Carbon Coated (HACC) optical fibers whereas for the Er/Ybdoped optical fibers, their hardening was successfully achieved adding to the fiber, the Cerium element, that prevents the formation of the radiation-induced point defects responsible for the radiation induced attenuation in the infrared part of the spectrum. These fibers are used as part of more complex systems like amplifiers (Erbium-doped Fiber Amplifier, EDFA or Yb-EDFA) or source (Erbium-doped Fiber Source, EDFS or Yb- EDFS), we discuss the impact of using radiation-hardened fibers on the system radiation vulnerability and demonstrate the resistance of these systems to radiation constraints associated with today and future space missions. Finally, we will discuss another radiation hardening approach build in our group and based on a hardening-by-system strategy in which the amplifier is optimized during its elaboration for its future mission considering the radiation effects and not in-lab.

Volcanic Gases and Hot Spring Water to Evaluate the Volcanic Activity of the Mt. Baekdusan

NASA Astrophysics Data System (ADS)

Yun, S. H.; Lee, S.; Chang, C.

2017-12-01

This study performed the analysis on the volcanic gases and hot spring waters from the Julong hot spring at Mt. Baekdu, also known as Changbaishan on the North Korea(DPRK)-China border, during the period from July 2015 to August 2016. Also, we confirmed the errors that HCO3- concentrations of hot spring waters in the previous study (Lee et al. 2014) and tried to improve the problem. Dissolved CO2 in hot spring waters was analyzed using gas chromatograph in Lee et al.(2014). Improving this, from 2015, we used TOC-IC to analysis dissolved CO2. Also, we analyzed the Na2CO3 standard solutions of different concentrations using GC, and confirmed the correlation between the analytical concentrations and the real concentrations. However, because the analytical results of the Julong hot spring water were in discord with the estimated values based on this correlation, we can't estimate the HCO3-concentrations of 2014 samples. During the period of study, CO2/CH4 ratios in volcanic gases are gradually decreased, and this can be interpreted in two different ways. The first interpretation is that the conditions inside the volcanic edifice are changing into more reduction condition, and carbon in volcanic gases become more favorable to distribute into CH4 or CO than CO2. The second interpretation is that the interaction between volcanic gases and water becomes greater than past, and the concentrations of CO2which have much higher solubility in water decreased, relatively. In general, the effect of scrubbing of volcanic gas is strengthened during the quiet periods of volcanic activity rather than active periods. Meanwhile, the analysis of hot spring waters was done on the anion of acidic gases species, the major cations, and some trace elements (As, Cd, Re).This work was funded by the Korea Meteorological Administration Research and Development Program under Grant KMIPA 2015-3060.

Microstructure-property relationships and constitutive response of plastically graded case hardened steels

NASA Astrophysics Data System (ADS)

Klecka, Michael A.

Case hardened materials, popularly used in many demanding engineering applications such as bearings, gears, and wear/impact surfaces, have high surface hardness and a gradient in material properties (hardness, yield strength, etc.) as a function of depth; therefore, they behave as plastically graded materials. In the current study, two different commercially available case carburized steels along with two through hardened steels are characterized to obtain relationships among the volume fraction of subsurface carbides, indentation hardness, elastic modulus, and yield strength as a function of depth. A variety of methods including microindentation, nanoindentation, ultrasonic measurements, compression testing, rule of mixtures, and upper and lower bound models are used to determine the relationships for elastic modulus and compare the experimental results with model predictions. In addition, the morphology, composition, and properties of the carbide particles are also determined. The gradient in hardness with depth in graded materials is commonly determined using microindentation on the cross-section of the material which contains the gradation in microstructure or composition. In the current study, a novel method is proposed to predict the hardness gradient profile using solely surface indentations at a range of loads. The method does not require the graded material to be sectioned, and has practical utility in the surface heat-treatment industry. For a material with a decreasing gradient in hardness, higher indent loads result in a lower measured hardness due to the influence of the softer subsurface layers. A power-law model is presented which relates the measured surface indentation hardness under increasing load to the subsurface gradient in hardness. A coordinated experimental and numerical study is presented to extract the constitutive response of graded materials, utilizing relationships between hardness, plastic deformation, and strain hardening response

A Comprehensive Expedient Methods Field Manual.

DTIC Science & Technology

1984-09-01

structures. " Revetments may be constructed of sandbags, sod blocks , and other expedients [17:933." Bunkers are emplacements with overhead protective...Lapland Fence............................. 75 19. Hardening: Dimensional Timber (Soil Bin) Revetment ............................................. 76...20. Hardening: Log Bulkhead (Soil Bin) Revetment ... 77 21. Hardening: Landing Mat Bulkhead (Soil Bin) Revetment

Impact of volcanic processes on the cryospheric system of the Peteroa Volcano, Andes of southern Mendoza, Argentina

NASA Astrophysics Data System (ADS)

Liaudat, Dario Trombotto; Penas, Pablo; Aloy, Gustavo

2014-03-01

Soil temperatures of the active Volcanic Complex Peteroa situated in the Cordillera Principal between Chile and Argentina at 35°15‧ S and 70°35‧ W (approximately) were monitored in the area, and local geomorphology (periglacial geomorphology, presence of permafrost, and cryoforms) was studied. The present contribution also resulted in a comparison of two consecutive analyses of the volcano peak carried out with special thermocameras (AGEMA TVH 550, FUR P660) in order to study the thermal range of different hot and cold sites selected in 2009. The thermocameras were used ascending by foot and also during flights with a Cessna 180. A night expedition to the volcanic avalanche caldera, at up to 3900 m asl (approximately), completed the monitoring activity of 2010. Hot zones were associated to present volcanism and cold zones to the presence of glacier ice and shadowy slopes with possible presence of permafrost. Identifying and mapping uncovered and covered ice was possible with the help of monitoring and geomorphological interpretation related to the upper englacement, which is severely affected by volcanism. Glaciers are retreating toward the north or approaching the rims of the volcanic avalanche caldera leaving islands of ice associated with superficial permafrost. The cryogenic area with slope permafrost was identified through active protalus and sedimentary cryogenic slopes. Craters have undergone considerable thermal changes in comparison to the year 2009; and new, much more vigorous fumaroles have appeared in hot areas detected in 2009 following a tendency toward the west. New subaquatic heat columns that appeared in crater 3, crater walls, and glaciated areas vanished, supplying cold water and thus contributing to the formation of a new lake in crater 4. A possible post-seismic shift of the volcanic activity may provide geodynamical evidence of the changes registered in other areas after the earthquake of 27 February 2010.

Shear punch and ball microhardness measurements of 14 MeV neutron irradiation hardening in five metals

NASA Astrophysics Data System (ADS)

Shinohara, K.; Lucas, G. E.; Odette, G. R.

1985-08-01

The irradiation hardening response of five metals irradiated in RTNS-II was investigated using a combination of ball microhardness and shear punch test techniques. The specimens were transmission electron microscopy disks of pure nickel, Ni-5wt%Si, pure iron, solution annealed prime candidate alloy (PCA) for Path A, and 40% cold worked MFE 316 stainless steel. Specimens were irradiated in RTNS-II to fluences in the range 6 × 10 16 to 6 × 10 17 n/cm 2. Only limited ball microhardness data could be obtained because of disk thickness. However, the ball microhardness data obtained were in good agreement with shear punch data. It was found that the pure metals exhibited little hardening after exposure to fluences of ~1 × 10 17 n/cm 2, but Ni-5 Si exhibited significant hardening after 6 × 10 17 n/cm 2. Hardening in PCA was similar to that observed in solution annealed 316 stainless steel; and hardening in 40% cold worked MFE 316 was relatively small after 6 × 10 17 n/cm 2. The Ni-5 Si response may be due to irradiation induced precipitation.

Geomagnetic imprint of the Persani volcanism

NASA Astrophysics Data System (ADS)

Besutiu, Lucian; Seghedi, Ioan; Zlagnean, Luminita; Atanasiu, Ligia; Popa, Razvan-Gabriel; Pomeran, Mihai; Visan, Madalina

2016-04-01

The Persani small volume volcanism is located in the SE corner of the Transylvanian Depression, at the north-western edge of the intra-mountainous Brasov basin. It represents the south-easternmost segment of the Neogene-Quaternary volcanic chain of the East Carpathians. The alkaline basalt monogenetic volcanic field is partly coeval with the high-K calc-alkaline magmatism south of Harghita Mountains (1-1.6 Ma). Its eruptions post-dated the calc-alkaline volcanism in the Harghita Mountains (5.3-1.6 Ma), but pre-dated the high-K calc-alkaline emissions of Ciomadul volcano (1.0-0.03 Ma). The major volcanic forms have been mapped in previous geological surveys. Still, due to the small size of the volcanoes and large extent of tephra deposits and recent sediments, the location of some vents or other volcanic structures has been incompletely revealed. To overcome this problem, the area was subject to several near-surface geophysical investigations, including paleomagnetic research. However, due to their large-scale features, the previous geophysical surveys proved to be an inappropriate approach to the volcanological issues. Therefore, during the summers of 2014 and 2015, based on the high magnetic contrast between the volcanic rocks and the hosting sedimentary formations, a detailed ground geomagnetic survey has been designed and conducted, within central Persani volcanism area, in order to outline the presence of volcanic structures hidden beneath the overlying deposits. Additionally, information on the rock magnetic properties was also targeted by sampling and analysing several outcrops in the area. Based on the acquired data, a detailed total intensity scalar geomagnetic anomaly map was constructed by using the recent IGRF12 model. The revealed pattern of the geomagnetic field proved to be fully consistent with the direction of magnetisation previously determined on rock samples. In order to enhance the signal/noise ratio, the results were further processed by

Role of copper in precipitation hardening of high-alloy Cr-Ni cast steels

NASA Astrophysics Data System (ADS)

Gajewski, Mirosław

2006-02-01

The mechanism of strengthening with second-phase particles that results from heat treatment, i.e., precipitate hardening, plays an important role in modern alloys. The strengthening effect of such particles can result from their coherence with the matrix, inhibition of dislocation slip, inhibition of grain boundary slip, as well as hampering recovery processes due to dislocation network pinning. The results of investigations into high-alloy Cr-Ni-Cu cast steels precipitate hardened with highly dispersed ɛ phase particles are presented within. The influence of heat treatment on changes in microstructure, mechanical properties, and morphology of fracture surfaces obtained under loading have been analyzed. It has been demonstrated that, with the appropriate selection of heat treatment parameters, it is possible to control the precipitation of the hardening ɛ phase and, thus, to change the final mechanical and functional properties.

Recycled grains in lunar soils as an additional, necessary, regolith evolution parameter

NASA Technical Reports Server (NTRS)

Basu, A.

1990-01-01

Recycled lunar soil grains are defined as those soil grains that have been a part of either regolith breccias or agglutinates; thus, mineral grains, rock fragments, older agglutinates, and volcanic glass spherules, if dislodged from an agglutinate or a regolith breccia, would all qualify as recycled grains. This paper shows that it is possible to estimate the proportion of recycled material in lunar soils. Optical data from 12 soils in the Apollo 16 core 64001/2 were collected to estimate the proportion (W) of recycled crystalline grains in each of these soils. The W values show a correspondence with other independently derived parameters and the history of the core soils, indicating that W can be used as a valid soil-evolution parameter.

Elements patterns of soil and river sediments as a tracer of sediment migration

NASA Astrophysics Data System (ADS)

Dordevic, Dragana; Pétursdóttir, Þórunn; Halldórsson, Guðmundur; Sakan, Sanja; Škrivalj, Sandra; Finger, David Christian

2017-04-01

Iceland is the small island on the mid Atlantic ridge, with strong natural catastrophes, such as floods, droughts, landslides, storms and volcanic eruptions that can have devastating impacts on natural and build environment. Rangárvellir area next to Mt Hekla and the glacier Tindfjallajökul has impacted by severe erosion processes but also rich of surface water that play a crucial role in sediment transport processes in the watersheds of the two rivers Eystri-Rangá and Ytri-Rangá. Their sediments consist of various materials originating from volcanoes ash and lava. Difference of contents of various chemical components in sediments and surrounding soil could be bases for identification of erosion processes and watersheds connectivity. River sediment is accumulator of chemical constituents from water in water-sediment interaction, making it as an important material for investigation their migration routes. In order to develop of methods for investigating of sediment migration using their chemical patterns the STSM of Connecteur COST Action ES1306-34336 have been approved. Samples of river sediments and surrounding soils of the Eystri-Rangá and Ytri-Rangá rivers in watersheds of Rangárvellir area as well as primarily volcanic ash from Eyafjallajökull were taken. Sequential extraction of heavy metals and trace elements from collected samples has been applied using the optimized procedure proposed by European Community Bureau of reference (BCR) in the next fractions: 1) soluble in acid - metals that are exchangeable or associated with carbonates; 2) reducible fraction - metals associated with oxides of Fe and Mn; 3) oxidizable fraction - metals associated with organic matter and sulfides and 4) residual fraction - metals strongly associated with the crystalline structure of minerals. Extracted solutions have analyzed by ICP/OES on next elements: Al, As, B, Ba, Be, Bi, Ca, Cd, Co, Cr, Cu, Fe, Hg, K, Li, Mg, Mn, Na, Ni, P, Pb, S, Sb, Si, Sr, V, Zn. Distributions

Timing and compositional evolution of Late Pleistocene to Holocene volcanism within the Harrat Rahat volcanic field, Kingdom of Saudi Arabia

NASA Astrophysics Data System (ADS)

Stelten, M. E.; Downs, D. T.; Dietterich, H. R.

2017-12-01

Harrat Rahat is one of the largest ( 20,000 km2) of 15 active Cenozoic volcanic fields that stretch 3,000 km along the western Arabian Peninsula from Yemen to Syria. The Harrat Rahat volcanic field is 310 km long (N-S) by 75 km wide (E-W), and is dominated by alkalic basalts with minor hawaiite, mugearite, benmoreite, and trachyte eruptives. The timing of volcanism within greater Harrat Rahat is poorly constrained, but field relations and geochronology indicate that northern Harrat Rahat hosted the most recent eruptions. To better constrain the timing and compositional evolution of Harrat Rahat during this recent phase, we present 743 geochemical analyses, 144 40Ar/39Ar ages, and 9 36Cl exposure ages for volcanic strata from northernmost Harrat Rahat. These data demonstrate that volcanism has been ongoing from at least 1.2 Ma to the present, with the most recent eruption known from historical accounts at 1256 CE. Basalt has erupted persistently from 1.2 Ma to the present, but more evolved volcanism has been episodic. Benmoreite erupted at 1.1 Ma and between 550 to 400 ka. Trachytic volcanism has only occurred over the past 150 ka, with the most recent eruption at 5 ka. Aside from the well-documented basaltic eruption at 1256 CE, prior workers interpreted 6 additional basaltic eruptions during the Holocene. However, our 36Cl exposure ages demonstrate that these erupted between 60 to 13 ka. Interestingly, in the northern part of our field area, where the spatial density of volcanic vents is low, young volcanism (<150 ka) is dominated by basaltic eruptions. Conversely, young volcanism in the southern part of our field area, where volcanic vent density is high, is dominated by trachyte. This observation is consistent with a process wherein the time-integrated effects of basaltic influx into the crust in the south produced a mafic intrusive complex, through which younger basaltic magmas cannot ascend. Instead, these magmas stall and produce trachyte, likely through

National volcanic ash operations plan for aviation

USGS Publications Warehouse

,; ,

2007-01-01

The National Aviation Weather Program Strategic Plan (1997) and the National Aviation Weather Initiatives (1999) both identified volcanic ash as a high-priority informational need to aviation services. The risk to aviation from airborne volcanic ash is known and includes degraded engine performance (including flameout), loss of visibility, failure of critical navigational and operational instruments, and, in the worse case, loss of life. The immediate costs for aircraft encountering a dense plume are potentially major—damages up to $80 million have occurred to a single aircraft. Aircraft encountering less dense volcanic ash clouds can incur longer-term costs due to increased maintenance of engines and external surfaces. The overall goal, as stated in the Initiatives, is to eliminate encounters with ash that could degrade the in-flight safety of aircrews and passengers and cause damage to the aircraft. This goal can be accomplished by improving the ability to detect, track, and forecast hazardous ash clouds and to provide adequate warnings to the aviation community on the present and future location of the cloud. To reach this goal, the National Aviation Weather Program established three objectives: (1) prevention of accidental encounters with hazardous clouds; (2) reduction of air traffic delays, diversions, or evasive actions when hazardous clouds are present; and (3) the development of a single, worldwide standard for exchange of information on airborne hazardous materials. To that end, over the last several years, based on numerous documents (including an OFCMsponsored comprehensive study on aviation training and an update of Aviation Weather Programs/Projects), user forums, and two International Conferences on Volcanic Ash and Aviation Safety (1992 and 2004), the Working Group for Volcanic Ash (WG/VA), under the OFCM-sponsored Committee for Aviation Services and Research, developed the National Volcanic Ash Operations Plan for Aviation and Support of the

Climatic impact of volcanic eruptions

NASA Technical Reports Server (NTRS)

Rampino, Michael R.

1991-01-01

Studies have attempted to 'isolate' the volcanic signal in noisy temperature data. This assumes that it is possible to isolate a distinct volcanic signal in a record that may have a combination of forcings (ENSO, solar variability, random fluctuations, volcanism) that all interact. The key to discovering the greatest effects of volcanoes on short-term climate may be to concentrate on temperatures in regions where the effects of aerosol clouds may be amplified by perturbed atmospheric circulation patterns. This is especially true in subpolar and midlatitude areas affected by changes in the position of the polar front. Such climatic perturbation can be detected in proxy evidence such as decrease in tree-ring widths and frost rings, changes in the treeline, weather anomalies, severity of sea-ice in polar and subpolar regions, and poor grain yields and crop failures. In low latitudes, sudden temperature drops were correlated with the passage overhead of the volcanic dust cloud (Stothers, 1984). For some eruptions, such as Tambora, 1815, these kinds of proxy and anectdotal information were summarized in great detail in a number of papers and books (e.g., Post, 1978; Stothers, 1984; Stommel and Stommel, 1986; C. R. Harrington, in press). These studies lead to the general conclusion that regional effects on climate, sometimes quite severe, may be the major impact of large historical volcanic aerosol clouds.

Local seismic hazard assessment in explosive volcanic settings by 3D numerical analyses

NASA Astrophysics Data System (ADS)

Razzano, Roberto; Pagliaroli, Alessandro; Moscatelli, Massimiliano; Gaudiosi, Iolanda; Avalle, Alessandra; Giallini, Silvia; Marcini, Marco; Polpetta, Federica; Simionato, Maurizio; Sirianni, Pietro; Sottili, Gianluca; Vignaroli, Gianluca; Bellanova, Jessica; Calamita, Giuseppe; Perrone, Angela; Piscitelli, Sabatino

2017-04-01

This work deals with the assessment of local seismic response in the explosive volcanic settings by reconstructing the subsoil model of the Stracciacappa maar (Sabatini Volcanic District, central Italy), whose pyroclastic succession records eruptive phases ended about 0.09 Ma ago. Heterogeneous characteristics of the Stracciacappa maar (stratification, structural setting, lithotypes, and thickness variation of depositional units) make it an ideal case history for understanding mechanisms and processes leading to modifications of amplitude-frequency-duration of seismic waves generated at earthquake sources and propagating through volcanic settings. New geological map and cross sections, constrained with recently acquired geotechnical and geophysical data, illustrate the complex geometric relationships among different depositional units forming the maar. A composite interfingering between internal lacustrine sediments and epiclastic debris, sourced from the rim, fills the crater floor; a 45 meters thick continuous coring borehole was drilled in the maar with sampling of undisturbed samples. Electrical Resistivity Tomography surveys and 2D passive seismic arrays were also carried out for constraining the geological model and the velocity profile of the S-waves, respectively. Single station noise measurements were collected in order to define natural amplification frequencies. Finally, the nonlinear cyclic soil behaviour was investigated through simple shear tests on the undisturbed samples. The collected dataset was used to define the subsoil model for 3D finite difference site response numerical analyses by using FLAC 3D software (ITASCA). Moreover, 1D and 2D numerical analyses were carried out for comparison purposes. Two different scenarios were selected as input motions: a moderate magnitude (volcanic event) and a high magnitude (tectonic event). Both earthquake scenarios revealed significant ground motion amplification (up to 15 in terms of spectral acceleration

Comparison of lead attenuation and lead hardening equivalence of materials used in respect of diagnostic X-ray shielding.

PubMed

Okunade, Akintunde Akangbe

2002-12-01

Present interest is in the shielding of diagnostic X-ray units. Numerical comparison has been made of the attenuation and hardening properties of lead and some particular alternative materials: steel, plate glass and gypsum wallboard. Results show, for particular choices of thickness, that lead and steel can be made to provide closely similar attenuation and spectral hardening, values of lead attenuation equivalent (LAE) and lead hardening equivalent (LHE) thicknesses being nearly the same. Significant differences in the attenuation and hardening properties of lead are found in comparison with plate glass and gypsum wallboard. LAE produces better matching of exposure for lead-plate glass and lead-gypsum wallboard than LHE.

Comparison of single and consecutive dual frequency induction surface hardening of gear wheels

NASA Astrophysics Data System (ADS)

Barglik, J.; Ducki, K.; Kukla, D.; Mizera, J.; Mrówka-Nowotnik, G.; Sieniawski, J.; Smalcerz, A.

2018-05-01

Mathematical modelling of single and consecutive dual - frequency induction surface hardening systems are presented and compared. The both models are solved by the 3D FEM-based professional software supported by a number of own numerical procedures. The methodology is illustrated with some examples of surface induction hardening of a gear wheel made of steel 41Cr4. The computations are in a good accordance with experiments provided on the laboratory stand.

AVAL - The ASTER Volcanic Ash Library

NASA Astrophysics Data System (ADS)

Williams, D.; Ramsey, M. S.

2016-12-01

Volcanic ash is a rich data source for understanding the causal mechanisms behind volcanic eruptions. Petrologic and morphometric information can provide direct information on the characteristics of the parent magma. Understanding how erupted ash interacts with the atmosphere can help quantify the effect that explosive volcanism has on the local to regional climate, whereas a measure of the particle size distribution enables more accurate modeling of plume propagation. Remote sensing is regularly employed to monitor volcanic plumes using a suite of high temporal/low spatial resolution sensors. These methods employ radiative transfer modeling with assumptions of the transmissive properties of infrared energy through the plume to determine ash density, particle size and sulfur dioxide content. However, such approaches are limited to the optically-transparent regions, and the low spatial resolution data are only useful for large-scale trends. In a new approach, we are treating the infrared-opaque regions of the plume in a similar way to a solid emitting surface. This allows high spatial resolution orbital thermal infrared data from the dense proximal plume to be modeled using a linear deconvolution approach coupled with a spectral library to extract the particle size and petrology. The newly created ASTER Volcanic Ash Library (AVAL) provides the end member spectral suite, and is comprised of laboratory emission measurements of volcanic ash taken from a variety of different volcanic settings, to obtain a wide range of petrologies. These samples have been further subdivided into particle size fractions to account for spectral changes due to diffraction effects. Once mapped to the ASTER sensor's spectral resolution, this library is applied to image data and the plume deconvolved to estimate composition and particle size. We have analyzed eruptions at the Soufrière Hills Volcano, Montserrat, Chaitén and Puyehue-Cordón Caulle, both Chile, and Eyjafjallajökull, Iceland

A radiation-hardened, computer for satellite applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gaona, J.I. Jr.

1996-08-01

This paper describes high reliability radiation hardened computers built by Sandia for application aboard DOE satellite programs requiring 32 bit processing. The computers highlight a radiation hardened (10 kGy(Si)) R3000 executing up to 10 million reduced instruction set instructions (RISC) per second (MIPS), a dual purpose module control bus used for real-time default and power management which allows for extended mission operation on as little as 1.2 watts, and a local area network capable of 480 Mbits/s. The central processing unit (CPU) is the NASA Goddard R3000 nicknamed the ``Mongoose or Mongoose 1``. The Sandia Satellite Computer (SSC) uses Rational`smore » Ada compiler, debugger, operating system kernel, and enhanced floating point emulation library targeted at the Mongoose. The SSC gives Sandia the capability of processing complex types of spacecraft attitude determination and control algorithms and of modifying programmed control laws via ground command. And in general, SSC offers end users the ability to process data onboard the spacecraft that would normally have been sent to the ground which allows reconsideration of traditional space-grounded partitioning options.« less

Using Satellite Observations to Evaluate the AeroCOM Volcanic Emissions Inventory and the Dispersal of Volcanic SO2 Clouds in MERRA

NASA Technical Reports Server (NTRS)

Hughes, Eric J.; Krotkov, Nickolay; da Silva, Arlindo; Colarco, Peter

2015-01-01

Simulation of volcanic emissions in climate models requires information that describes the eruption of the emissions into the atmosphere. While the total amount of gases and aerosols released from a volcanic eruption can be readily estimated from satellite observations, information about the source parameters, like injection altitude, eruption time and duration, is often not directly known. The AeroCOM volcanic emissions inventory provides estimates of eruption source parameters and has been used to initialize volcanic emissions in reanalysis projects, like MERRA. The AeroCOM volcanic emission inventory provides an eruptions daily SO2 flux and plume top altitude, yet an eruption can be very short lived, lasting only a few hours, and emit clouds at multiple altitudes. Case studies comparing the satellite observed dispersal of volcanic SO2 clouds to simulations in MERRA have shown mixed results. Some cases show good agreement with observations Okmok (2008), while for other eruptions the observed initial SO2 mass is half of that in the simulations, Sierra Negra (2005). In other cases, the initial SO2 amount agrees with the observations but shows very different dispersal rates, Soufriere Hills (2006). In the aviation hazards community, deriving accurate source terms is crucial for monitoring and short-term forecasting (24-h) of volcanic clouds. Back trajectory methods have been developed which use satellite observations and transport models to estimate the injection altitude, eruption time, and eruption duration of observed volcanic clouds. These methods can provide eruption timing estimates on a 2-hour temporal resolution and estimate the altitude and depth of a volcanic cloud. To better understand the differences between MERRA simulations and volcanic SO2 observations, back trajectory methods are used to estimate the source term parameters for a few volcanic eruptions and compared to their corresponding entry in the AeroCOM volcanic emission inventory. The nature of

Catastrophic volcanic collapse: relation to hydrothermal processes.

PubMed

López, D L; Williams, S N

1993-06-18

Catastrophic volcanic collapse, without precursory magmatic activity, is characteristic of many volcanic disasters. The extent and locations of hydrothermal discharges at Nevado del Ruiz volcano, Colombia, suggest that at many volcanoes collapse may result from the interactions between hydrothermal fluids and the volcanic edifice. Rock dissolution and hydrothermal mineral alteration, combined with physical triggers such as earth-quakes, can produce volcanic collapse. Hot spring water compositions, residence times, and flow paths through faults were used to model potential collapse at Ruiz. Caldera dimensions, deposits, and alteration mineral volumes are consistent with parameters observed at other volcanoes.

The role of twinning deformation on the hardening response of polycrystalline magnesium from discrete dislocation dynamics simulations

DOE PAGES

Fan, Haidong; Aubry, Sylvie; Arsenlis, Athanasios; ...

2015-04-13

The mechanical response of micro-twinned polycrystalline magnesium was studied through three-dimensional discrete dislocation dynamics (DDD). A systematic interaction model between dislocations and (1012) tension twin boundaries (TBs) was proposed and introduced into the DDD framework. In addition, a nominal grain boundary (GB) model agreeing with experimental results was also introduced to mimic the GB’s barrier effect. The current simulation results show that TBs act as a strong obstacle to gliding dislocations, which contributes significantly to the hardening behavior of magnesium. On the other hand, the deformation accommodated by twinning plays a softening role. Therefore, the concave shape of the Mgmore » stress-strain curve results from the competition between dislocation-TB induced hardening and twinning deformation induced softening. At low strain levels, twinning deformation induced softening dominates and a decreasing hardening rate is observed in Stage-I. In Stage-II, both the hardening and softening effects decline, but twinning deformation induced softening declines faster, which leads to an increasing hardening rate.« less

Lunar soil and surface processes studies