Bezdĕk, Michal; Landes, Hermann; Rieder, Alfred; Lerch, Reinhard
Today's most popular technology of ultrasonic flow measurement is based on the transit-time principle. In this paper, a numerical simulation technique applicable to the analysis of transit-time flowmeters is presented. A flowmeter represents a large simulation problem that also requires computation of acoustic fields in moving media. For this purpose, a novel boundary integral method, the Helmholtz integral-ray tracing method (HIRM), is derived and validated. HIRM is applicable to acoustic radiation problems in arbitrary mean flows at low Mach numbers and significantly reduces the memory demands in comparison with the finite-element method (FEM). It relies on an approximate free-space Green's function which makes use of the ray tracing technique. For simulation of practical acoustic devices, a hybrid simulation scheme consisting of FEM and HIRM is proposed. The coupling of FEM and HIRM is facilitated by means of absorbing boundaries in combination with a new, reflection-free, acoustic-source formulation. Using the coupled FEM-HIRM scheme, a full three-dimensional (3-D) simulation of a complete transit-time flowmeter is performed for the first time. The obtained simulation results are in good agreement with measurements both at zero flow and under flow conditions. PMID:17375833
Goman, M. G.; Zagainov, G. I.; Khramtsovsky, A. V.
Applications of global stability and bifurcational analysis methods are presented for different nonlinear flight dynamics problems, such as roll-coupling, stall, spin, etc. Based on the results for different real aircraft, F-4, F-14, F-15, High Incidence Research Model, (HIRM), the general methods developed by many authors are presented. The outline of basic concepts and methods from dynamcal system theory are also introduced.
Gune, Minal; Harshavardhana, B G; Balakrishna, K; Udayashankar, H N; Shankar, R; Manjunatha, B R
We present seasonal rock magnetic data for 48 surficial soil samples collected seasonally around a coal-fired thermal power plant on the southwest coast of India to demonstrate how fly ash from the power plant is transported both spatially and seasonally. Sampling was carried out during pre-monsoon (March), early-monsoon (June), monsoon (September) and post-monsoon (December) seasons. Low- and high-frequency magnetic susceptibility (χlf and χhf), frequency-dependent magnetic susceptibility (χfd), χfd %, isothermal remanent magnetization (IRM), "hard" IRM (HIRM), saturation IRM (SIRM) and inter-parametric ratios were determined for the samples. Scanning electron microscopy (SEM) was used on limited number of samples. NOAA HYSPLIT MODEL backward trajectory analysis and principal component analysis were carried out on the data. Fly ash samples exhibit an average HIRM value (400.07 × 10(-5) Am(2) kg(-1)) that is comparable to that of soil samples. The pre- and post-monsoon samples show a consistent reduction in the concentration of magnetically "hard" minerals with increasing distance from the power plant. These data suggest that fly ash has indeed been transported from the power plant to the sampling locations. Hence, HIRM may perhaps be used as a proxy for tracking fly ash from coal-fired thermal power plants. Seasonal data show that the distribution of fly ash to the surrounding areas is minimum during monsoons. They also point to the dominance of SP magnetite in early-monsoon season, whereas magnetic depletion is documented in the monsoon season. This seasonal difference is attributable to both pedogenesis and anthropogenic activity i.e. operation of the thermal power plant. PMID:27056477
Rosenbaum, J. G.; Dean, W. E.; Colman, S. M.; Reynolds, R. L.
Variations in magnetic properties within an interval of Bear Lake sediments correlative with oxygen isotope stage 2 (OIS 2) and OIS 3 provide a record of glacial flour production for the Uinta Mountains. Like sediments of the same age from Upper Klamath Lake (OR), these Bear Lake sediments have high magnetic susceptibilities (MS) relative to non-glacial-age sediments and contain well-defined millennial-scale variations in magnetic properties. In contrast to glacial flour derived from volcanic rocks surrounding Upper Klamath Lake, glacial flour derived from the Uinta Mountains and deposited in Bear Lake by the Bear River has low magnetite content but high hematite content. The relatively low MS values of younger and older non-glacial-age sediments are due entirely to dilution by non-magnetic endogenic carbonate and to the effects of sulfidic alteration of detrital Fe-oxides. Analysis of samples from streams entering Bear Lake and from along the course of the Bear River demonstrates that, in comparison to other areas of the catchment, sediment derived from the Uinta Mountains is rich in hematite (high HIRM) and aluminum, and poor in magnetite (low MS) and titanium. Within the glacial-age lake sediments, there are strong positive correlations among HIRM, Al/Ti, and fine sediment grain size. MS varies inversely with theses three variables. These relations indicate that the observed millennial-scale variations in magnetic and chemical properties arise from varying proportions of two detrital components: (1) very fine-grained glacial flour derived from Proterozoic metasedimentary rocks in the Uinta Mountains and characterized by high HIRM and low MS, and (2) somewhat coarser material, characterized by higher MS and lower HIRM, derived from widespread sedimentary rocks along the course of the Bear River and around Bear Lake. Measurement of glacial flour incorporated in lake sediments can provide a continuous history of alpine glaciation, because the rate of accumulation
Sediments from ODP site 1063 (Bermuda Rise, North Atlantic) contain a high-resolution record of geomagnetic field behavior during the Brunhes Chron. We present rock magnetic data of the upper 160 mcd (<900 ka) from hole 1063D that show magnetic properties vary in concert with glacial cycles. Magnetite appears to be the main magnetic carrier in the carbonate-dominated interglacial horizons, yet exhibits contrasting grain size distributions depending on the redox state of the horizons. Higher contributions of single domain magnetite exist above the present day sulfate reduction zone (ca. 44 mcd) with relatively higher multidomain magnetite components below that likely arise from the partial dissolution of SD magnetite in the deeper, anoxic horizons. Glacial horizons on the other hand, characterized by enhanced terrigenous deposition, show no evidence for diagenetic dissolution but do indicate the presence of authigenic greigite close to glacial maxima (acquisition of gyro-remanence, strong magnetostatic interactions and SD properties). Glacial horizons contain hematite (maxima in HIRM and S-Ratio consistent with a reddish hue) and exhibit higher ARM anisotropy and pronounced sedimentary fabrics. We infer that post depositional processes affected the magnetic grain size and mineralogy of Bermuda rise sediments deposited during the late Pleistocene. Hematite concentration is interpreted to reflect primary terrigenous input that is likely derived from the Canadian Maritime Provinces. A close correlation between HIRM and magnetic foliation suggests that changes in sediment composition (terrigenous vs. marine biogenic) were accompanied by changes in the depositional processes at the site.
Liu, Qingsong; Bloemendal, Jan; Torrent, Jose; Deng, Chenglong
The Chinese loess/paleosol sequence provides an excellent record of long-term variations in the East Asian paleomonsoon. For representative loess profiles, paleosol units have enhanced magnetic properties compared to loess units. However, at some depth intervals with special paleoenvironmental conditions, selective depletion of antiferromagnetic (AFM) minerals (hematite and goethite) could occur, resulting in complexities in accurately linking variations in magnetic properties to long-term fluctuations in paleoclimate. To resolve this problem, we directly measured the mass concentrations of these AFM minerals using second-order diffuse reflectance spectroscopy (DRS), and then correlated the DRS results to high-field isothermal remanent magnetization (HIRM) from paleosol unit S5 at the Luochuan profile, central Chinese Loess Plateau. Our results suggest that a low HIRM anomaly just below the sub-paleosol unit S5S1 is caused by fluctuations specifically in goethite content, while the hematite concentration exhibits a maximum over the same depth interval. This appears to rule out significant loss of hematite to reductive dissolution and further indicates that hematite and goethite may respond differently to changes in the paleoclimate conditions.
Klein, Vladislav; Noderer, Keith D.
Aerodynamic equations with unsteady effects were formulated for an aircraft in one-degree-of-freedom, small-amplitude, harmonic motion. These equations were used as a model for aerodynamic parameter estimation from wind tunnel oscillatory data. The estimation algorithm was based on nonlinear least squares and was applied in three examples to the oscillatory data in pitch and roll of 70 deg triangular wing and an X-31 model, and in-sideslip oscillatory data of the High Incidence Research Model 2 (HIRM 2). All three examples indicated that a model using a simple indicial function can explain unsteady effects observed in measured data. The accuracy of the estimated parameters and model verification were strongly influenced by the number of data points with respect to the number of unknown parameters.
Yauk, Kimberly E.
Natural atmospheric dust samples collected from the American southwest and globally were measured using magnetic methods in order to separate remanence attributed to the high coercivity iron oxide and oxyhydroxide minerals hematite and goethite. Dust collected from mountain snow and dust source areas in nearby arid plains were analyzed using traditional room- and low temperature methods. Additional methods were created to better examine the weak, high coercivity components. Combinations of high fields (2.5-9 T), low temperatures (10-300 K), partial AF demagnetization, and thermal demagnetization to 400 K were implemented to separate each component. Percentages of remanence attributed to magnetite, hematite, and goethite were compared to results found by HIRM (hard isothermal remanent magnetization) and Mossbauer spectroscopy with good correlation and to coercivity unmixing methods without correlation. TRM (thermoremanent magnetization) was found to be an important step in magnetizing a greater portion of the goethite fraction. Further procedures for characterizing nano grain sizes would be illuminating.
Reynolds, Richard L.; Cattle, Stephen R.; Moskowitz, Bruce M.; Goldstein, Harland L.; Yauk, Kimberly; Flagg, Cody B.; Berquó, Thelma S.; Kokaly, Raymond F.; Morman, Suzette; Breit, George N.
Iron oxide minerals typically compose only a few weight percent of bulk atmospheric dust but are important for potential roles in forcing climate, affecting cloud properties, influencing rates of snow and ice melt, and fertilizing marine phytoplankton. Dust samples collected from locations across eastern Australia (Lake Cowal, Orange, Hornsby, and Sydney) following the spectacular "Red Dawn" dust storm on 23 September 2009 enabled study of the dust iron oxide assemblage using a combination of magnetic measurements, Mössbauer spectroscopy, reflectance spectroscopy, and scanning electron microscopy. Red Dawn was the worst dust storm to have hit the city of Sydney in more than 60 years, and it also deposited dust into the Tasman Sea and onto snow cover in New Zealand. Magnetization measurements from 20 to 400 K reveal that hematite, goethite, and trace amounts of magnetite are present in all samples. Magnetite concentrations (as much as 0.29 wt%) were much higher in eastern, urban sites than in western, agricultural sites in central New South Wales (0.01 wt%), strongly suggesting addition of magnetite from local urban sources. Variable temperature Mössbauer spectroscopy (300 and 4.2 K) indicates that goethite and hematite compose approximately 25-45% of the Fe-bearing phases in samples from the inland sites of Orange and Lake Cowal. Hematite was observed at both temperatures but goethite only at 4.2 K, thereby revealing the presence of nanogoethite (less than about 20 nm). Similarly, hematite particulate matter is very small (some of it d < 100 nm) on the basis of magnetic results and Mössbauer spectra. The degree to which ferric oxide in these samples might absorb solar radiation is estimated by comparing reflectance values with a magnetic parameter (hard isothermal remanent magnetization, HIRM) for ferric oxide abundance. Average visible reflectance and HIRM are correlated as a group (r2 = 0.24), indicating that Red Dawn ferric oxides have capacity to absorb
Reynolds, R. L.; Goldstein, H. L.; Moskowitz, B. M.; Till, J. L.; Flagg, C.; Kokaly, R. F.; Munson, S.; Landry, C.; Lawrence, C. R.; Hiza, M. M.; D'Odorico, P.; Painter, T. H.
Ferric oxide minerals in atmospheric dust can influence atmospheric temperatures, accelerate melting of snow and ice, stimulate marine phytoplankton productivity, and impact human health. Such effects vary depending on iron mineral type, size, surface area, and solubility. Generally, the presence of ferric oxides in dust is seen in the red, orange, or yellow hues of plumes that originate in North Africa, central and southwest Asia, South America, western North America, and Australia. Despite their global importance, these minerals in source sediments, atmospheric dust, and downwind aeolian deposits remain poorly described with respect to specific mineralogy, particle size and surface area, or presence in far-traveled aerosol compounds. The types and properties of iron minerals in atmospheric dust can be better understood using techniques of rock magnetism (measurements at 5-300 K), Mössbauer and high-resolution visible and near-infrared reflectance spectroscopy; chemical reactivity of iron oxide phases; and electron microscopy for observing directly the ferric oxide coatings and particles. These studies can elucidate the diverse environmental effects of iron oxides in dust and can help to identify dust-source areas. Dust-source sediments from the North American Great Basin and Colorado Plateau deserts and the Kalahari Desert, southern Africa, were used to compare average reflectance values with a magnetic parameter (hard isothermal remanent magnetization, HIRM) for ferric oxide abundance. Lower reflectance values correspond strongly with higher HIRM values, indicating that ferric oxides (hematite or goethite, or both) contribute to absorption of solar radiation in these sediments. Dust deposited to snow cover of the San Juan Mountains (Colorado) and Wasatch Mountains (Utah) was used to characterize dust composition compared with properties of sediments exposed in source-areas identified from satellite retrievals. Results from multiple methods indicate that
Wang, J.; Du, J.; Zhang, W.; Zhang, J.
Submarine surface sediments due to resuspension may return to water column followed by particles sedimentation on the seabed. Therefore, particulate material in estuarine and coastal environments would be typically deposited and resuspended several times before permanent accumulation or transport offshore. The suspension and mobile sediments, referred to be "mobile mud" definated by high water content(≥0.30) and no-decay 210Pbex vertical distribution, play an important role in the biogeochemical cycles in the estuarine/coastal area. In the present work, the spatial and temporal distribution of thickness, grain-size in the mobile mud of the East China Sea were conducted by May and August, 2011. Most mobile mud are distributed along the coast and north offshore, and the thick mud layer (≥2cm) is featured with fine grain size, high water content and TOC, exhibiting the activeness of mobile mud. The total amount of mobile mud in the East China Sea is ten times in comparison with annual sediment discharge from the Changjiang River. The maximum of mobile mud thickness and 7Be activity in May was distributed in the south coast, but that in August was distributed in the north coast. The mobile mud HIRM was relatively large both in May and August, but the north coast HIRM in August was larger than that in May. All these change of mobile mud thickness, nuclides and magnetic properties indicated that the mobile mud formation mechanism has the different patterns in the different region.The north coastal mobile mud formation is dominated by the Changjiang Diluted Water, and in the south is controlled by the monsoon-influenced Zhejiang-Fujian coastal current. The main source of mobile mud near the inshore is predominantly input from the Changjiang River. However, most mobile mud in the north offshore may be originally derived from the Changjiang River and old Huanghe River. Compared south offshore with thin layer of mobile mud, the north offshore mobile mud formation
Performance evaluation of elemental analysis/isotope ratio mass spectrometry methods for the determination of the D/H ratio in tetramethylurea and other compounds--results of a laboratory inter-comparison.
Bréas, Olivier; Thomas, Freddy; Zeleny, Reinhard; Calderone, Giovanni; Jamin, Eric; Guillou, Claude
Tetramethylurea (TMU) with a certified D/H ratio is the internal standard for Site-specific Natural Isotope Fractionation measured by Nuclear Magnetic Resonance (SNIF-NMR) analysis of wine ethanol for detection of possible adulterations (Commission Regulation 2676/90). A new batch of a TMU certified reference material (CRM) is currently being prepared. Whereas SNIF-NMR has been employed up to now, Elemental Analysis/Isotope Ratio Mass Spectrometry ((2)H-EA-IRMS) was envisaged as the method of choice for value assignment of the new CRM, as more precise (better repeatable) data might be obtained, resulting in lower uncertainty of the certified value. In order to evaluate the accuracy and intra- and inter-laboratory reproducibility of (2)H-EA-IRMS methods, a laboratory inter-comparison was carried out by analysing TMU and other organic compounds, as well as some waters. The results revealed that experienced laboratories are capable of generating robust and well comparable data, which highlights the emerging potential of IRMS in food authenticity testing. However, a systematic bias between IRMS and SNIF-NMR reference data was observed for TMU; this lack of data consistency rules out the (2)H-IRMS technique for the characterisation measurement of the new TMU CRM. PMID:17428013
Maher, B.; Karloukovski, V.; Mutch, T.
Haematite (alpha-Fe2O3) and goethite (gamma-FeOOH), both weakly magnetic, high-coercivity minerals, are the two most common and abundant iron oxide/oxyhydroxide minerals in soils. Their transport within windblown dust and deposition in deep-sea sediments has previously been inferred from room temperature, high field magnetic remanence measurements. Dust fluxes may play an active role in amplifying or modulating external climate forcing and thus robust data on dust fluxes are required for each ocean, including mid- to high-latitudes where mineralogical analysis of dust is confounded by the presence of ice-rafted debris (IRD). We describe magnetic methods for differentiating between goethite, SD haematite and SP haematite. Our magnetic measurements identify goethite and SP haematite in the N. African dust plume, potential dust sources and in mid-latitude N Atlantic sediments (the latter dominated magnetically by inputs of ferrimagnetic IRD). We test the magnetic dust proxy against an independent sediment parameter, leaf wax alkanes, of demonstrably terrestrial origin. We also examine the relationships between conventional high field remanences (HIRMs) and af-demagnetised hard remanence measurements.
The mathematical models needed to represent the various dynamics phenomena have been conceived in many disciplines related to aerospace engineering. Major aerospace companies have developed their own codes to estimate aerodynamic characteristics and aircraft stability in the conceptual phase, in parallel with universities that have developed various codes for educational and research purposes. This paper presents a design tool that includes FDerivatives code, the new weight functions method and the continuity algorithm. FDerivatives code, developed at the LARCASE laboratory, is dedicated to the analytical and numerical calculations of the aerodynamic coefficients and their corresponding stability derivatives in the subsonic regime. It was developed as part of two research projects. The first project was initiated by CAE Inc. and the Consortium for Research and Innovation in Aerospace in Quebec (CRIAQ), and the second project was funded by NATO in the framework of the NATO RTO AVT-161 "Assessment of Stability and Control Prediction Methods for NATO Air and Sea Vehicles" program. Presagis gave the "Best Simulation Award" to the LARCASE laboratory for FDerivatives and data FLSIM applications. The new method, called the weight functions method, was used as an extension of the former project. Stability analysis of three different aircraft configurations was performed with the weight functions method and validated for longitudinal and lateral motions with the root locus method. The model, tested with the continuity algorithm, is the High Incidence Research Aircraft Model (HIRM) developed by the Swedish Defense Research Agency and implemented in the Aero-Data Model In Research Environment (ADMIRE).
Liu, Q.; Subir, B. K.; Jackson, M.; Zhu, R.; Pan, Y.
A new parameter Mfr (the final remanence after a slow hysteretic demagnetization process) for the detection of the concentration of weak antiferromagnetic (AFM) minerals against a strong ferrimagnetic (FM) background is put forward by taking advantage of their sharply different H0 (the critical maximum field that can decrease Mfr to zero) values. For strong FM minerals (magnetite, maghemite), H0 values are less than 0.3 T, while for antiferromagnetic materials (such as hematite) with weak magnetic remanence, H0 is larger than 1 T. With synthetic samples, experiments showed that Mfr has a higher sensitivity to detect AFM minerals than the HIRM method because it has a higher random error caused by the required subtraction of two numbers. The latter requires measurements in the presence of high applied-fields (generally 0.3 to 1T). Mfr, on the other hand, being a remanence, is measured at zero applied fields. Detailed Mfr data for YiChuan (Gansu province, China) loess samples indicate that paleosol unit S1contains a higher concentration of FM but lower concentration of AFM minerals compared to that of the loess units above and below. This suggests the formation of Fe2+ bearing minerals at the cost of Fe3+ bearing AFM minerals during pedogenesis.
Yauk, K.; Ottenfeld, C. F.; Reynolds, R. L.; Goldstein, H.; Cattle, S.; Berquo, T. S.; Moskowitz, B. M.
indicates the presence of nanogoethite and small particle sizes (< 30 nm). Magnetization experiments indicates that some of the nanogoethite has remanence blocking temperatures above 300 K (and hence larger particle sizes) but it must be a small fraction of the total grain distribution considering that goethite was not indicated at 300 K with Mössbauer. Likewise, Mössbauer spectra indicate that the hematite component is still above the Morin transition (TM=265 K) and in its canted antiferromagnetic state even at 4.2 K. Suppression of the Morin transition in hematite can occur due to reduced crystallinity, cation substitution (e.g., Ti4+, Al 3+), or small particle effects (d< 100 nm). Finally, we compared reflectance with a magnetic parameter (hard isothermal remanent magnetization, HIRM) for ferric oxide abundance to assess the degree to which ferric oxide in these samples might absorb solar radiation. In samples for which both parameters were obtained, HIRM and average reflectance over the visible wavelengths are correlated as a group (r2=0.24). These results indicate that the ferric oxide minerals in Red Dawn dust absorb solar radiation. Much of this ferric oxide occurs likely as grain coatings of nanohematite and nanogoethite, thereby providing high surface area to enhance absorption of solar radiation.
Mathias, Grasiane; Trindade, Ricardo; Salvatteci, Renato; Sifeddine, Abdel
The study of the geomagnetic field in the past is made through the fossil magnetization recorded in geological and archeological materials. In sediments the magnetization is acquired during or after deposition (pós-depositional remanent magnetization - pDRM), and the dating of geomagnetic features recorded in this materials depends on the time between deposition and magnetization lock-in and the depth in which the magnetization is mechanically blocked (e.g. Tauxe et al, 2006). Besides these processes, diagenesis (e.g. sulfate reduction) can compromise the paleomagnetic record in sedimentary sequences. Marine sediments are exposed to many different chemical environments which can drive the formation of new magnetic minerals. In presence of H2S, magnetite can be dissolved and iron sulphides be formed, such as greigite a precursor of pyrite in anoxic sulfate-reducing sedimentary environment (Roberts & Weaver, 2005; Rowan et al, 2009; Roberts et al, 2011). The age of magnetization in sediments affected by chemical magnetization (CRM) is much harder to be stablished. Here we performed a detailed magnetic characterization using 'environmagnetic' parameters (χ, ARM, IRM, S-Ratio, HIRM, ARM%) and hysteresis curves for sediments from the equatorial Pacific which were deposited in a strong redox gradient, from oxic to anoxic conditions in the water column. Magnetic mineralogy and SEM images show both authigenic iron sulphide (greigite) and detrital iron oxide (magnetite) all across the core, suggesting that reducing conditions prevailed in pore waters all along the sedimentation history. Scattering in directions are usually associated to intensely altered intervals, where greigite is the dominant magnetic carrier. Yet, besides the presence of greigite all through the analysed cores it is still possible to obtain a reliable geomagnetic field record from most samples after classical paleomagnetic treatment.
Kawamura, N.; Amano, Y.; Ishikawa, N.
Frequent outbreaks of red tide caused by dinoflagellate blooms have been reported since 1970 in the Hiroshima bay. Iron is an essential element for dinoflagellates, and is supplied as bivalent or trivalent ions and iron compounds from lands to sea. For damage predictions of red tide, it is important to research the distribution of iron in the bay. In order to investigate the distribution and mode of iron in sediments, suspended solids (SS), and bottom water in the Hiroshima Bay, rock magnetic and geochemical analyses are performed. Sediments of 5 cm in depth and overlying bottom water were taken at three sites in the bay every month. The sediment samples were composed of clayey silt. We measured dissolved iron concentration in bottom waters filtered above 0.45 um grains. The contents of carbon, nitrogen, and sulfur in the sediments are measured. The rock magnetic measurements (magnetic susceptibility, NRM, ARM, IRM, HIRM, S-0.3T, magnetic hysteresis, and high temperature magnetometry) of the sediments and SS are conducted. Concentration dependent rock magnetic parameters of the sediments and SS show relatively high values during spring at the near estuary site. It indicates that relatively larger amount of terrigenous materials are supplied in this season. Magnetic grain size decreases during summer, while iron concentration increases in the bottom waters. Data of oceanographic observations at these sites showed that the temperature of the bottom water increased, whereas DO and pH values decreased during summer. The presence of magnetite (Fe3O4) and hematite (Fe2O3) were recognized in all analyzed samples, whereas greigite (Fe3S4) appeared during summer. The contents of sulfur in the sediments also increase in this period. It is implied that magnetite and hematite were dissolved, and greigite was formed associated with the proceeding of the anoxic condition during summer. It is suggested that irons moves between sediments and bottom water corresponding to seasonal
Maslin, M.; Denison, S.; Ettwein, V.; Boot, C.; Pancost, R.; Evershed, R.; Platzman, E.; Murray, R.; Rosell-Mele, A.
The Intensification of the Northern Hemisphere Glaciation (3.2 to 2.5 Ma) is a key climatic transition in Earth History. Deep-sea sediments recovered from ODP Leg 175 Site 1083 cover this important time period. Site 1083 has the advantage that it monitors both changes in the Benguela Current Upwelling system as well as the adjacent African continent. In this study we have focused on the interglacial (OIS 101) and glacial (OIS 100) periods that make up the final intensification step in this climatic transition. With a resolution of approximately 1 ka, we have reconstructed the following climatic parameters: Global ice volume (benthic foraminifera oxygen isotopes), wind strength and land aridity (HIRM, MS, Al/Ti ratios), upwelling intensity (UK37'-SSTs), surface water productivity (TOC, Chaetoceros resting spores, alkenone abundance, pigments, Ba), surface water nutrient availability (organic nitrogen isotopes), nutrient source (diatom species abundance), and land vegetation type (n-alkane abundance and carbon isotopes). Two conclusions have been drawn from this unique data set: 1. Surface water productivity peaks during glaciation, but is in fact lower during the full glacial than the previous interglacial. It is suggested that this is caused by the antagonistic effects of upwelling intensity and nutrient supply to this area. 2. The carbon isotopic record of n-alkanes, which monitors the relative abundance of C3 (tress and higher plants) vs C4 (tropical grasses) plants, clearly shows that the vegetation of South West Africa during this time period co-varies with precession and is independent of glacial-interglacial cycles. We suggest that this is due to the strong influence of precession on the penetration of the ITCZ-driven North-Central African monsoons (and resultant moisture availability) into the Congo Basin and the rest of SW Africa.
Leng, Wei; von Dobeneck, Tilo
Large-scale glacial meltwater discharge could be widely recognized off the eastern Canadian continental margin. At Laurentian Fan, sub-glacial outburst floods eroded Permian-Carboniferous redbeds at Gulf of St. Lawrence and then delivered the reddish sediments by Laurentian Channel. Sedimentary record from four gravity cores (GeoB18514-2, 18515-1, 18516-2 and 18517-1) at the SW slope of the Grand Banks of Newfoundland revealed the major depositional processes since Heinrich event 2 (ca. 22 ka). In the cores, the upper thick Holocene olive-grey silty mud units overly IRD-rich Heinrich 1 layer, five reddish units are distinguished in the lower part. Reddish units get proportionally thinner along the SW slope at higher and more distal positions; instead, separating olive-grey layers get thicker with height and distance. Reddish and olive grey units have sharp boundaries and no signs of erosion. Mean grain size changes abruptly from coarse in grey layers to fine in reddish layers, terrigenous elements (as Al, K, Ti, Fe) and clays (Al/Si) are highly elevated in reddish layers and low in Heinrich layers, which are instead enriched in detrital continental carbonates. Both Heinrich layers and reddish layers have enhanced magnetic susceptibility, but Heinrich layer have higher ferromagnetic (SIRM) content (mafic rocks), while reddish layers have more hematite (HIRM). These five reddish layers differ from event to event, which seems to reflect different mixing ratios of event-related and background sedimentation. This mixing will allow estimating event-specific sedimentation rates. Using mixing ratio combined with 14C dating data could contribute to estimate the sedimentation rate and duration of outburst floods, which could help to build ice sheet retreat history and find the connection with paleoclimate changes.
Horng, Chorng-Shern; Huh, Chih-An
Different lithologies between Taiwan and southeastern China lead to diverse mineralogical composition for weathering products derived from the two shores of the Taiwan Strait. Pyrrhotite and magnetite are respectively the dominant magnetic minerals associated with fluvial sediments from western Taiwan and southeastern China. While magnetite commonly co-exists with pyrrhotite in sediments sourced from Taiwan, pyrrhotite has not been found in sediments sourced from mainland China. Associated with such a distinction are vast differences in magnetic properties, including magnetic susceptibility (χ), SIRM, HIRM and the S-ratio, which can be used to study the provenances of sediments in the Taiwan Strait and adjoining marginal seas. Based on any two of these parameters, the magnetic characteristics of much of the Taiwan Strait sediment can be explained using a two-endmember mixing model. Source-to-sink dispersal of sediments in the Taiwan Strait can then be traced from the distribution of these parameters. The results not only corroborate an earlier study based on radionuclides and particle size distribution ( Huh et al., 2011) but reveal more diagnostic details. Besides spatial distribution based on a large number (216) of surface sediments, we also analyzed temporal variation of magnetic properties in six well-dated cores collected at key sites along the sediment source-to-sink pathways. From profiles of these parameters in cores from the middle of the northern Taiwan Strait, it is calculated that sediment supply from Taiwan has increased substantially in the past five decades, which may very well be related to accelerated land use and increased frequency of intense rainfalls in Taiwan during the same period. The approach described in this work may be extended to other source-to-sink systems around the world and through time, especially the mountainous islands fringing the Pacific and Indian Oceans in southeastern Asia. As with Taiwan, these islands have high
Schmidt, Markus; Maseyk, Kadmiel; Lett, Céline; Biron, Philippe; Richard, Patricia; Bariac, Thierry; Seibt, Ulli
Concern exists about the suitability of laser spectroscopic instruments for the measurement of the (18)O/(16)O and (2)H/(1)H values of liquid samples other than pure water. It is possible to derive erroneous isotope values due to optical interference by certain organic compounds, including some commonly present in ecosystem-derived samples such as leaf or soil waters. Here we investigated the reliability of wavelength-scanned cavity ring-down spectroscopy (CRDS) (18)O/(16)O and (2)H/(1)H measurements from a range of ecosystem-derived waters, through comparison with isotope ratio mass spectrometry (IRMS). We tested the residual of the spectral fit S(r) calculated by the CRDS instrument as a means to quantify the difference between the CRDS and IRMS δ-values. There was very good overall agreement between the CRDS and IRMS values for both isotopes, but differences of up to 2.3‰ (δ(18)O values) and 23‰ (δ(2)H values) were observed in leaf water extracts from Citrus limon and Alnus cordata. The S(r) statistic successfully detected contaminated samples. Treatment of Citrus leaf water with activated charcoal reduced, but did not eliminate, δ(2)H(CRDS) - δ(2)H(IRMS) linearly for the tested range of 0-20% charcoal. The effect of distillation temperature on the degree of contamination was large, particularly for δ(2)H values but variable, resulting in positive, negative or no correlation with distillation temperature. S(r) and δ(CRDS) - δ(IRMS) were highly correlated, in particular for δ(2)H values, across the range of samples that we tested, indicating the potential to use this relationship to correct the δ-values of contaminated plant water extracts. We also examined the sensitivity of the CRDS system to changes in the temperature of its operating environment. We found that temperature changes ≥4 °C for δ(18)O values and ≥10 °C for δ(2)H values resulted in errors larger than the CRDS precision for the respective isotopes and advise the use of such
Lee, T.; Wei, K.; Huh, C.
This study presents paleomagnetic secular variation results of a marine sediment core, named as OR715-21, taken from eastern offshore of Taiwan (121.5°E, 22.7°N, water depth 760 m). The total recovered length is 1.87 meters. Sediments in the core mainly consist of gray clay and silt. Planktonic foraminiferal shells (>250 μm, >6 mg, Globigerinoides spp. and Orbulina universa) were picked from six levels of the core and subjected to AMS 14C dating for constructing the age model. The results indicated that this core could support the information for the last 7000 years. The averaged sedimentation rate is estimated to be of about 26.5 cm/kyr. Psuedo-single domain (PSD) magnetite is identified as the most important magnetic carrier. Alternating field (AF) demagnetization was applied to treat the u-channel samples of the core. The median destructive field of the samples distributed between 15~25 mT. The characteristic remanent magnetization could be resolved after 20 mT cleaning. The paleo-declinations of the samples varied about ±200 around their mean and their paleo-inclinations varied between 300 and 500 . The variation pattern of the paleo-declination is somehow similar to the pattern compiled by Hyoto et al. (1993) based on the lake and marine sediment records from Japan except the varied amplitude is less between 4000 and 5000 yrB.P. Using NRM/ARM after 20 mT cleaning to simulate the paleo-intensity secular variation, our record shows that an increased trend began from 6500 yrB.P. to 3000 yrB.P., but decreased after. Magnetic proxies of this core indicate that 4 stages of environmental changes has happened in the area studied: (1) high magnetite abundance with relative low oxidized magnetic mineral contents occurred during ~6900 to 6200 yrB.P.; (2) a relative low abundance of magnetite with relative high oxidized magnetic minerals during ~6200 to ~5400 yrB.P.; (3) an abnormal low HIRM with relative higher ARM/SIRM could be found during the time period of ~5400
Dinarès-Turell, J.; Hoogakker, B. A. A.; Roberts, A. P.; Rohling, E. J.; Sagnotti, L.
High resolution magnetic measurements on u-channels from Mediterranean piston cores LC07 (3808.72N/1004.73E, length 23.66 m, water depth 488 m) and LC10 (3512.77 N/1634.88E, 19.86 m, 1322 m) are evaluated. The age model for these cores is derived by a two-step approach: firstly, the magnetostratigraphic results which document the upper Jaramillo (990 ka) and the Matuyama/Brunhes (778 ka) transi- tions in both cores and possibly the Punaruu (~1122 ka) and Cobb Mountain (~1.19 ka) in core LC10 permit to derive a preliminary age model by assuming constant sedimentation rates between the astronomically calibrated reversal boundaries (mean sedimentation rates are 1.9 and 2.3 cm/kyr in cores LC10 and LC07, respectively). In a second step, rock magnetic parameters which appear to be climatically controlled are used to derive a precise astronomically tuned age model for the studied interval by cor- relation to a global ice volume model derived from summer insolation at 65N. The final age model is further corroborated by oxygen isotope data from the Tyrrhenian core LC07, which is apparently homogeneous in lithology, and the presence of some sapropel/sapropelitic layers in the Ionian core LC10 that correlate with pronounced insolation maxima peaks. Warm interglacial periods are characterized by relatively small ferrimagnetic grain sizes and cold glacial intervals are dominated by a relatively coarser fraction as indicated by the kARM/k values and by the hysteresis parameters. Also, the relatively lower values of the S-ratio within the glacial periods are indica- tive of an increased high coercivity contribution, that may reflect an enhanced eolian input. High kARM/k values for core LC07 are compatible with stable single-domain (SD) particles of probable bacterial origin. On the other hand, the Pleistocene climatic variability in core LC10 seems to be better expressed by the HIRM parameter which is a measure of the concentration of the high-coercivity magnetic fraction. The
Reynolds, Richard L.; Goldstein, Harland L.; Moskowitz, Bruce M.; Bryant, Ann C.; Skiles, S. McKenzie; Kokaly, Raymond F.; Flagg, Cody B.; Yauk, Kimberly; Berquó, Thelma; Breit, George; Ketterer, Michael; Fernandez, Daniel; Miller, Mark E.; Painter, Thomas H.
Dust layers deposited to snow cover of the Wasatch Range (northern Utah) in 2009 and 2010 provide rare samples to determine the relations between their compositions and radiative properties. These studies are required to comprehend and model how such dust-on-snow (DOS) layers affect rates of snow melt through changes in the albedo of snow surfaces. We evaluated several constituents as potential contributors to the absorption of solar radiation indicated by values of absolute reflectance determined from bi-conical reflectance spectroscopy. Ferric oxide minerals and carbonaceous matter appear to be the primary influences on lowering snow-cover albedo. Techniques of reflectance and Mössbauer spectroscopy as well as rock magnetism provide information about the types, amounts, and grain sizes of ferric oxide minerals. Relatively high amounts of ferric oxide, indicated by hard isothermal remanent magnetization (HIRM), are associated with relatively low average reflectance (<0.25) across the visible wavelengths of the electromagnetic spectrum. Mössbauer spectroscopy indicates roughly equal amounts of hematite and goethite, representing about 35% of the total Fe-bearing phases. Nevertheless, goethite (α-FeOOH) is the dominant ferric oxide found by reflectance spectroscopy and thus appears to be the main iron oxide control on absorption of solar radiation. At least some goethite occurs as nano-phase grain coatings less than about 50 nm thick. Relatively high amounts of organic carbon, indicating as much as about 10% organic matter, are also associated with lower reflectance values. The organic matter, although not fully characterized by type, correlates strongly with metals (e.g., Cu, Pb, As, Cd, Mo, Zn) derived from distal urban and industrial settings, probably including mining and smelting sites. This relation suggests anthropogenic sources for at least some of the carbonaceous matter, such as emissions from transportation and industrial activities. The composition of
Kars, M. A. C.; Musgrave, R. J.; Kodama, K.; Jonas, A. S.
In 2014, IODP Expedition 350 drilled a 1806.5 m deep hole at Site U1437 in the Izu Bonin rear arc. The Site presents an unusual deep methanogenesis zone because of a release of sulfate below the sulfate reduction zone (27-83 mbsf) which may buffer methanogenesis by anaerobic methanogens. Methane abundance gradually increases with depth, with significant abundance at ~750-1459 mbsf with a maximum value at 920 mbsf. The rock magnetic study carried out in Hole U1437D from ~775 to ~1000 mbsf shows a drastic change of the magnetic properties at ~850 mbsf coincidently with a stronger release of methane from < 60 ppm at 841 mbsf to ~300 ppm at 854 mbsf. That also corresponds to a depth interval where no core was recovered (~846-854 mbsf). For the sake of clarity, we call hereafter zone A the depth interval above this non-recovered interval (775-846 mbsf) and zone B the interval below (854-1000 mbsf). Both belong to the same lithostratigraphic unit composed of tuffaceous mudstones intercalated with volcanoclastics. In the zone A, NRM, magnetic susceptibility, ARM, SIRM, HIRM display high values. In the zone B, these parameters show much lower values of one order of magnitude less, except for the interval 936-950 mbsf that corresponds to a local maximum (but still lower values than the zone A). Besides, the rock magnetic parameters for grain size and coercivity, such as ARM/χ, S-ratio and Bcr do not show any variations throughout the entire studied interval, although S-ratio displays slightly lower values from ~850 to ~930 mbsf. Grains are low coercivity pseudo-single domain sized. According to the present data, two preliminary hypotheses can be proposed to explain the observations. 1) The non-recovered interval between the zones A and B can be caused by the presence of a sedimentary hiatus and/or a fault, which may be consistent with the observed change in sedimentation rate. 2) No hiatus in the sedimentation. The changes in the magnetic properties can be explained by a
Savian, J. F.; Jovane, L.; Florindo, F.; Lukeneder, A.
magnetization (HIRM=[IRM900+BIRM300]/2), both were used to investigate the magnetic coercivity of the magnetic carriers. The integrated records indicate that the magnetic mineral assemblage is dominated by low-coercivity minerals, probably magnetite and/or low-titanium titanomagnetite for the upper part of the section. There is a mixture of low and high-coercivity materials in the lower part of the section sections, probably magnetite and hematite. The new magnetostratigraphy allows to constrain the age of the sediments and the environmental magnetism provide information that will be helpful to understand the sedimentation processes.
Warrier, Anish Kumar; Shankar, R.; Manjunatha, B. R.; Harshavardhana, B. G.
We have used rock magnetic techniques in this study to assess atmospheric pollution at five stations in and around Mangalore city on the southwestern coast of India. Samples of dust were collected from two suburban areas (Thokkottu and Pumpwell located respectively ~ 10 km and 3 km from the city center), the city center itself (Milagres) and industrial/port areas (Panambur and Mangalore Refinery and Petrochemicals Limited (MRPL)). Low-frequency magnetic susceptibility (χlf), frequency-dependent susceptibility (χfd), susceptibility of anhysteretic remanent magnetization (χARM) and isothermal remanent magnetization (IRM 20 to 1000 mT) were determined on 23 dust samples and inter-parametric ratios calculated. Results show that samples from suburban areas (particularly Thokkottu) are characterized by low χlf (< 314.1 × 10- 8 m3 kg- 1) and up to 6% χfd, suggesting low levels of pollution and the presence of pedogenic magnetite possibly derived from soils by wind erosion. However, the average χlf of Milagres, Panambur and MRPL dust samples is high by factors of 9.2, 3.3 and 2.6 compared to that of the Thokkottu sample. The Milagres sample contains magnetically "soft" minerals like magnetite, possibly indicating its derivation from motor vehicle exhaust. In contrast, the Panambur dust sample is characterized by magnetically "hard" minerals such as hematite and goethite as it has an 8-fold higher HIRM value compared to the Thokkottu sample. This magnetic signature is perhaps the result of dust particles derived from the grinding of hematite-rich iron ore by the Kudremukh Iron Ore Company Limited (KIOCL) at Panambur and its storage and export through the nearby New Mangalore Port. However, the dust sample from MRPL has magnetically "soft" minerals like magnetite. This magnetic mineral may have originated from petroleum refining processes at MRPL. Particulate pollution from industrial activities and motor vehicle exhaust is a threat to human health and is known to
van Peer, Tim; Xuan, Chuang; Lippert, Peter; Wilson, Paul; Liebrand, Diederik
(possibly of biogenic origin) and a coarse-grained non-stoichiometric haematite component as remanence carriers of the sediments. Variations in the magnetic particle concentration, inferred from bulk magnetic susceptibility (χ), qualitatively co-vary with a global stacked oxygen-isotope curve on at least an ~100 kyr scale. The ratios between χ and anhysteretic remanent magnetisation (ARM) and ARM/IRM are typically used to assess bulk magnetite grain size. These ratios, as well as the HIRM ('hard' IRM) component (haematite/goethite) and the L-ratio, decrease approximately by a factor of 2 at the onset of the Mi1 event in Subchron C6Cn.3n. All of these environmental magnetic changes are coincident with an abrupt increase in the Zr/Ti values - a proxy for detrital input, measured by continuous X-Ray Fluorescence core scanning. Collectively, these observations are consistent with shifts in supply or preservation of the non-stoichiometric haematite component throughout the measured section. We tentatively interpret these changes in deep sea magnetic mineralogy to reflect changes in sediment provenance, grain size, or both, which are likely related to changes in DWBC strength and source regions; this hypothesis can be tested by additional magnetic fabric, sediment particle, and geochemical studies. Our work demonstrates that continuous magnetic measurements can reveal important changes in contourite drifts, and hints at how major climatic events such as Mi1 may influence ocean current systems such as the DWBC.
Armbruster, Wolfgang; Lehnert, Katja; Vetter, Walter
purification steps during the isolation of pure lindane from the technical HCH mixture. An even greater difference was observed between the delta2H values of Toxaphene (US product dating from 1978) and Melipax (product from the former East Germany, dating from 1979), which gave delta2H values of -101/1000 and -181/1000, respectively, meaning that both products were easily distinguished via delta2H-IRMS. Fractioning of hydrogen isotopes in the atmospheric water cycle was suggested as one reason for the different values. In this theory, the water (which had different delta2H values depending on where it was taken from) was incorporated during the biosynthesis of camphene, which is the natural product used to produce both products. These results indicate that hydrogen isotope-specific analysis can be a valuable tool for tracing the origins of a compound in certain cases. PMID:16283262
Horng, Chorng-Shern; Huh, Chih-An; Chen, Kuo-Hang; Huang, Pin-Ru; Hsiung, Kan-Hsi; Lin, Hui-Ling
. Down-core profiles of hard isothermal remanent magnetization (HIRM) below the turbidite layer also reveal similar trends to the corresponding magnetic spherule counts, which indicate that the concentration of hematite in the sediments is also closely related to the extent of air pollution. In addition, relatively low values of χARM/ χ, which are indicative of coarse magnetic grains, started to occur when large magnetite spherules became significant during the industrialized period. The air pollution history elucidated from our sediment core data not only reflects the development of Kaohsiung from a small village to a highly industrialized metropolitan area in the 20th century, but it is also consistent with the most recent air pollution trends revealed by real time air quality measurements of PM 10. Our results demonstrate the usefulness of magnetic parameters for delineating the air pollution history of coastal marine sediments down-wind of nearby industrialized regions.
Just, Janna; von Dobeneck, Tilo; Bickert, Torsten; Frederichs, Thomas
The region off Gambia is an interesting study area because of its geographical location in between the ITCZ summer and winter position. We study a sediment core spanning the last 60 kyrs off the Gambia river mouth (W Africa) to identify different sources of the terrigenous sediment components exported to the continental margin. Our aim is the quantification of terrigenous flux rates of fluvial and aeolian load, respectively to improve our understanding of palaeoclimatic conditions and climatic changes in the Sahel and Sahara. It is known that in western Africa arid conditions prevailed during glacials and North Atlantic Heinrich Events. After the Last Glacial Maximum (LGM) a humid climate dominated northern Africa between 5-12 kyrs BP, known as the African Humid Period (AHP). These climatic changes have already been documented in magnetic, chemical, mineralogical and sedimentological proxies, respectively. However, these investigations were mainly carried out in qualitative approaches and lack an integrated multi-proxy validation. We apply a multi-proxy approach using XRF-element data and environmental magnetic parameter analysis on 5 cm interval samples of sediment core GeoB13602-1 (13°32.71 N; 17°50.96 W). Carbonate and biogenic opal content were analysed to estimate the total terrigenous fraction. Environmental magnetic parameters including ARM, IRM, HIRM, SIRM and frequency-dependent susceptibility allow the estimation of magnetic minerals, e.g. magnetite, hematite and goethite. Ratios of these parameters reflect grainsizes of the magnetic minerals which are indicative of transport mechanisms. We performed an End-Member (EM) analysis of IRM acquisition curves, decomposing the bulk sample into different components which represent individual sediment sources. Our approach is to include chemical, sedimentological and magnetic parameters in this EM model to reconstruct the composition as well as the transport pathways of the sediments. Based on an age model